Sample records for abandoned oil refinery

  1. Refinery Upgrading of Hydropyrolysis Oil From Biomass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Roberts, Michael; Marker, Terry; Ortiz-Toral, Pedro

    Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located nearmore » biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed

  2. Conflicting energy and environmental policies: The portsmouth oil refinery

    NASA Astrophysics Data System (ADS)

    Choi, Yearn Hong

    1984-03-01

    This case study presents the series of decision-making processes surrounding a current environmental issue—the Portsmouth oil refinery in Virginia. Crude oil must be refined before it can be used as fuel. Additionally, some oil must be desulfurized for use other than as gasoline. In 1977, the nation imported about one million barrels of oil a day. Although the US Department of Energy has emphasized the critical need for greater east coast refinery capability, the east coast is to supply only 25% of its refined oil needs. In the same year, the east coast met its demands for petroleum products from three sources: (a) refinery production, 22.7%, (b) product imports, 28.0%, and (c) products from the Gulf Coast, 49.3%.1 The energy program after the Arab oil embargo has an objective of encouraging the construction of oil refineries and petrochemical plants in the United States rather than abroad. The tariff is higher on imports of refined oil products than of crude oil, and new refineries are allowed to import a large proportion of their requirements tarifffree. The US federal government does not directly regulate the locations for oil refineries or methods of desulfurization. The oil import program, however, does influence decisions concerning location of desulfurization facilities and refineries, and air and water pollution standards affect methods of refining, besides making desulfurization necessary.

  3. Indicators of immunotoxicity in populations of cotton rats (Sigmodon hispidus) inhabiting an abandoned oil refinery.

    PubMed

    McMurry, S T; Lochmiller, R L; McBee, K; Qualls, C W

    1999-03-01

    Wildlife species inhabiting contaminated sites are often exposed to complex mixtures of chemicals, many of which have known effects on physiological and biochemical function. Although sensitivity of the immune system to chemical exposure has been documented in laboratory animal and wildlife species, little work has been conducted on feral wildlife populations inhabiting contaminated sites. Immune function was measured in populations of wild cotton rats (Sigmodon hispidus) inhabiting replicated reference and contaminated study sites at an abandoned oil refinery in Oklahoma four times from 1991 to 1992. Several measures of immunocompetence were examined including immune organ mass and cellularity, hematology, in vivo hypersensitivity, macrophage function, killer cell activity, and lymphoproliferative responsiveness. In vitro proliferation of splenocytes, either spontaneous or induced with concanavalin A (Con A), was the most consistent and reliable indicator of immunotoxicity. Spontaneous proliferation of splenocytes was 48 and 24% higher for cotton rats collected from contaminated than reference sites in September 1991 and September 1992, respectively. Likewise, Con A-induced proliferation of splenocytes ranged form 20 to 53% higher in animals collected from contaminated than reference sites in three of four collection periods. The percentage of splenocytes (mean+/-SE) staining positive for Con A receptors was lower on contaminated sites (73.7+/-1.2%) than reference sites (77.0+/-1.4%) in September 1991. Other measures of immune function including macrophage metabolism, hypersensitivity, blood cellularity, and mass and cellularity of immune organs varied between contaminated and reference sites. Copyright 1999 Academic Press.

  4. Smoking habits of oil refinery employees.

    PubMed Central

    Van Peenen, P F; Blanchard, A G; Wolkonsky, P M

    1984-01-01

    Smoking habits of White male employees of a large oil company were analyzed. There were only slight differences in smoking habits between refinery and nonrefinery employees. Salaried employees, both at refineries and elsewhere, smoked much less than hourly employees. PMID:6507698

  5. Environmental nickel exposure from oil refinery emissions: a case study in Ecuador.

    PubMed

    Harari, Raúl; Harari, Florencia; Forastiere, Francesco

    2016-01-01

    Nickel is a strong skin and respiratory sensitizer and a recognized carcinogen. Oil refineries are important sources of atmospheric emissions of toxic pollutants, including nickel. Populations residing close to oil refineries are at potential risk. The aim of this study was to evaluate the exposure to nickel in a population living close to the largest oil refinery in Ecuador, located in the city of Esmeraldas. We recruited 47 workers from the oil refinery as well as 195 students from 4 different schools close to the plant and 94 students from another school 25 km far from the industry. Urinary nickel concentrations were used to assess the exposure to nickel. Students from the school next to the oil refinery showed the highest urinary nickel concentrations while workers from the refinery showed the lowest concentrations. Median nickel concentrations were > 2µg/L in all study groups. The populations living close to the oil refineries are potentially exposed to nickel from atmospheric emissions. Further studies investigating nickel-related health effects in the population residing close to the refinery of Esmeralda are needed.

  6. [Liver enzyme abnormalities among oil refinery workers].

    PubMed

    Carvalho, Fernando Martins; Silvany Neto, Annibal Muniz; Mendes, João Luiz Barberino; Cotrim, Helma Pinchemel; Nascimento, Ana Lísia Cunha; Lima Júnior, Alberto Soares; Cunha, Tatiana Oliveira Bernardo da

    2006-02-01

    Occupational exposure typical of an oil refinery may alter liver function among the workers. Thus, the objective of the study was to identify risk factors for liver enzyme abnormalities among oil refinery workers. The workers at an oil refinery in Northeastern Brazil underwent routine annual medical examination from 1982 to 1998. This case-control study investigated all the 150 cases of individuals with simultaneous gamma-glutamyltransferase and alanine aminotransferase abnormalities of at least 10% above reference levels. As controls, 150 workers without any liver enzyme or bilirubin abnormalities since starting to work there were selected. Odds ratios and the respective 95% confidence intervals were calculated from logistic regression models. In all the production sectors, the risk of liver enzyme abnormalities was significantly higher than in the administrative sector (OR=5.7; 95% CI: 1.7-18.4), even when the effects of alcohol, obesity and medical history of hepatitis were controlled for. During the period from 1992 to 1994, 88 out of the 89 cases occurred among workers from the various production sectors. Occupational exposure plays an important role in causing liver enzyme abnormalities among oil refinery workers. This is in addition to the specifically biological and/or behavioral risk factors such as obesity and alcohol consumption.

  7. Market survey on products from the Tema Oil Refinery carried out as part of the feasibility study on the Tema Oil Refinery expansion project. Export trade information

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-10-01

    The Tema Oil Refinery (TOR), which was commissioned in 1963, is a simple hydroskimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years some of the equipment in the refinery has deteriorated or become obsolete necessitating major rehabilitation. A feasibility study is investigating the modernization and expansion of the refinery to meet projected market demands until the year 2005. The report presents the results of a market survey done on products from TOR.

  8. Potential for reducing air pollution from oil refineries.

    PubMed

    Karbassi, A R; Abbasspour, M; Sekhavatjou, M S; Ziviyar, F; Saeedi, M

    2008-10-01

    Islamic Republic of Iran has to invest 95 billion US$ for her new oil refineries to the year 2045. At present, the emission factors for CO(2), NO( x ) and SO(2) are 3.5, 4.2 and 119 times higher than British refineries, respectively. In order to have a sustainable development in Iranian oil refineries, the government has to set emission factors of European Community as her goal. At present CO(2) per Gross Domestic Production (GDP) in the country is about 2.7 kg CO(2) as 1995's USD value that should be reduced to 1.25 kg CO(2)/GDP in the year 2015. Total capital investment for such reduction is estimated at 346 million USD which is equal to 23 USD/ton of CO(2). It is evident that mitigation of funds set by Clean Development Mechanism (3 to 7 USD/tons of CO(2)) is well below the actual capital investment needs. Present survey shows that energy efficiency promotion potential in all nine Iranian oil refineries is about 165,677 MWh/year through utilization of more efficient pumps and compressors. Better management of boilers in all nine refineries will lead to a saving of 273 million m(3) of natural gas per year.

  9. 75 FR 27641 - Safety Zone; Marathon Oil Refinery Construction, Rouge River, Detroit, MI

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-18

    ...-AA00 Safety Zone; Marathon Oil Refinery Construction, Rouge River, Detroit, MI AGENCY: Coast Guard, DHS... River during the Marathon Oil Refinery Construction project. This temporary safety zone is necessary to... personnel during the setup and offloading of equipment in conjunction with the Marathon Oil Refinery...

  10. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gangwal, Santosh; Meng, Jiajia; McCabe, Kevin

    Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fastmore » pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.« less

  11. Current situation of oil refinery in Bulgaria

    NASA Astrophysics Data System (ADS)

    Vershkova, Elena; Petkova, Petinka; Grinkevich, Anastasia

    2016-09-01

    This article deals with the classification approach for oil refineries in international practices. Criteria of refinery estimation group, including its financial status estimation, have been investigated. The analysis object is “Lukoil Neftochim Bourgas” AD (LNCHB) activity. This company is a leading enterprise in Bulgaria. The analysis of LNCHB operating: energy intensity index; index of operating costs and return on investment index have been performed.

  12. Carbon flow analysis and Carbon emission reduction of FCC in Chinese oil refineries

    NASA Astrophysics Data System (ADS)

    Jia, Fengrui; Wei, Na; Ma, Danzhu; Liu, Guangxin; Wu, Ming; Yue, Qiang

    2017-08-01

    The major problem of the energy production in oil refineries is the high emission of CO2 in China. The fluid catalytic cracking unit (FCC) is the key source of carbon emission in the oil refineries. According to the statistical data, the carbon emission of FCC unit accounts for more than 31% for the typical oil refineries. The carbon flow of FCC in the typical Chinese oil refineries were evaluated and analysed, which aimed at the solution of CO2 emission reduction. The method of substances flow analysis (SFA) and the mathematical programming were used to evaluate the carbon metabolism and optimize the carbon emission. The results indicated that the combustion emission of the reaction-regeneration subsystem (RRS) was the major source of FCC. The quantity of CO2 emission of RSS was more than 90%. The combustion efficiency and the amount of residual oil affected the carbon emission of RRS most according to the optimized analysis of carbon emission reduction. Moreover, the fractionation subsystem (TFS) had the highest environmental efficiency and the absorption-stabilization subsystem (ASS) had the highest resource efficiency (approximately to 1) of carbon.

  13. Ultrasonic oil recovery and salt removal from refinery tank bottom sludge.

    PubMed

    Hu, Guangji; Li, Jianbing; Thring, Ronald W; Arocena, Joselito

    2014-01-01

    The oil recovery and salt removal effects of ultrasonic irradiation on oil refinery tank bottom sludge were investigated, together with those of direct heating. Ultrasonic power, treatment duration, sludge-to-water ratio, and initial sludge-water slurry temperature were examined for their impacts on sludge treatment. It was found that the increased initial slurry temperature could enhance the ultrasonic irradiation performance, especially at lower ultrasonic power level (i.e., 21 W), but the application of higher-power ultrasound could rapidly increase the bulk temperature of slurry. Ultrasonic irradiation had a better oil recovery and salt removal performance than direct heating treatment. More than 60% of PHCs in the sludge was recovered at an ultrasonic power of 75 W, a treatment duration of 6 min, an initial slurry temperature of 25°C, and a sludge-to-water ratio of 1:4, while salt content in the recovered oil was reduced to <5 mg L(-1), thereby satisfying the salt requirement in refinery feedstock oil. In general, ultrasonic irradiation could be an effective method in terms of oil recovery and salt removal from refinery oily sludge, but the separated wastewater still contains relatively high concentrations of PHCs and salt which requires proper treatment.

  14. Lymphohaematopoietic malignancy around all industrial complexes that include major oil refineries in Great Britain.

    PubMed

    Wilkinson, P; Thakrar, B; Walls, P; Landon, M; Falconer, S; Grundy, C; Elliott, P

    1999-09-01

    To examine the incidence of lymphohaematopoietic malignancy around industrial complexes that include major oil refineries in Great Britain after recent public and scientific concern of possible carcinogenic hazards of emissions from the petrochemical industry. Small area study of the incidence of lymphohaematopoietic malignancies, 1974-91, within 7.5 km of all 11 oil refineries (grouped into seven sites) in Great Britain that were operational by the early 1970s and processed more than two million tonnes of crude oil in 1993. Combined analysis of data from all seven sites showed no significant (p < 0.05) increase in risk of these malignancies within 2 km or 7.5 km. Hodgkin's lymphoma, but no other malignancy, showed evidence (p = 0.02) of a decline in risk with distance from refineries, but there was an apparent deficit of cases of multiple myeloma near the refineries (p = 0.04). There was no evidence of association between residence near oil refineries and leukaemias, or non-Hodgkin's lymphoma. A weak positive association was found between risk of Hodgkin's disease and proximity to major petrochemical industry, and a negative association with multiple myeloma, which may be chance findings within the context of multiple statistical testing.

  15. Cancer incidence among Finnish oil refinery workers, 1971-1994.

    PubMed

    Pukkala, E

    1998-08-01

    Cancer incidence between 1971 and 1994 was studied in a cohort of 7,512 men and 1,942 women who had been employed for at least 3 months in a Finnish enterprise that was primarily active in oil refining. The expected numbers of cancer cases were based on the national incidence rates. The standardized incidence ratios (SIR) for overall cancer after 5 years at work was decreased by 12% because of a significant deficit from cancer of the lung in oil refineries (SIR, 0.3; 95% confidence interval [95% CI], 0.1-0.6). There was a significant excess of kidney cancer in males, which was highest among men with at least 5 years of employment in oil refineries (SIR 2.8; 95% CI, 1.6-4.7). Male blue-collar workers had a twofold risk of non-Hodgkin's lymphoma and non-melanocytic skin cancer. Occupational exposure to gasoline may be associated with increased risk of cancer of the kidney.

  16. Oil refinery hazardous effluents minimization by membrane filtration: An on-site pilot plant study.

    PubMed

    Santos, Bruno; Crespo, João G; Santos, Maria António; Velizarov, Svetlozar

    2016-10-01

    Experiments for treating two different types of hazardous oil refinery effluents were performed in order to avoid/minimize their adverse impacts on the environment. First, refinery wastewater was subjected to ultrafiltration using a ceramic membrane, treatment, which did not provide an adequate reduction of the polar oil and grease content below the maximal contaminant level allowed. Therefore the option of reducing the polar oil and grease contamination at its main emission source point in the refinery - the spent caustic originating from the refinery kerosene caustic washing unit - using an alkaline-resistant nanofiltration polymeric membrane treatment was tested. It was found that at a constant operating pressure and temperature, 99.9% of the oil and grease and 97.7% of the COD content were rejected at this emission point. Moreover, no noticeable membrane fouling or permeate flux decrease were registered until a spent caustic volume concentration factor of 3. These results allow for a reuse of the purified permeate in the refinery operations, instead of a fresh caustic solution, which besides the improved safety and environmentally related benefits, can result in significant savings of 1.5 M€ per year at the current prices for the biggest Portuguese oil refinery. The capital investment needed for nanofiltration treatment of the spent caustic is estimated to be less than 10% of that associated with the conventional wet air oxidation treatment of the spent caustic that is greater than 9 M€. The payback period was estimated to be 1.1 years. The operating costs for the two treatment options are similar, but the reuse of the nanofiltration spent caustic concentrate for refinery pH control applications can further reduce the operating expenditures. Overall, the pilot plant results obtained and the process economics evaluation data indicate a safer, environmentally friendly and highly competitive solution offered by the proposed nanofiltration treatment, thus

  17. Feasibility study on the modernization and expansion of the Tema Oil Refinery. Executive Summary. Export trade information

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1992-04-01

    The Tema Oil Refinery (TOR), which was commissioned in 1963, is a simple hydro-skimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years some of the equipment in the refinery has deteriorated or become obsolete necessitating major rehabilitation. A study of the refinery expansion project takes into consideration earlier studies and, equally important, recognizes the extensive work done by TOR in rehabilitating the refinery. The program, carried out in phases because of funding limitations, has addressed the critical repairs and replacements in the process unitsmore » and utilities necessary to prolong the life of the refinery and assure reliability and safe operation. It undertook the task of investigating the feasibility of modernizing and expanding the refinery at Tema, Ghana to meet projected market demands until the year 2005. A process planning study was conducted to select the optimal process and utility configuration which would result in economic benefits to Ghana.« less

  18. Refinery Capacity Report

    EIA Publications

    2017-01-01

    Data series include fuel, electricity, and steam purchased for consumption at the refinery; refinery receipts of crude oil by method of transportation; and current and projected atmospheric crude oil distillation, downstream charge, and production capacities. Respondents are operators of all operating and idle petroleum refineries (including new refineries under construction) and refineries shut down during the previous year, located in the 50 states, the District of Columbia, Puerto Rico, the Virgin Islands, Guam, and other U.S. possessions. The Refinery Capacity Report does not contain working and shell storage capacity data. This data is now being collected twice a year as of March 31 and September 30 on the Form EIA-810, "Monthly Refinery Report", and is now released as a separate report Working and Net Available Shell Storage Capacity.

  19. Stabilization of Bio-Oil Fractions for Insertion into Petroleum Refineries

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brown, Robert C.; Smith, Ryan; Wright, Mark

    This project is part of a collaboration effort between Iowa State University (ISU), University of Oklahoma (OK) and Pacific Northwest National Laboratory (PNNL). The purpose of this project is to stabilize bio-oil fractions and improve their suitability for insertion into petroleum refineries. Bio-oil from fast pyrolysis of biomass is a complex mixture of unstable organic compounds. These organic compounds react under standard room conditions resulting in increases in bio-oil viscosity and water content – both detrimental for bio-oil storage and transportation. This study employed fractionation and upgrading systems to improve the stability of bio-oil. The fractionation system consists of amore » series of condensers, and electrostatic precipitators designed to separate bio-oil into five fractions: soluble carbohydrates (SF1&2), clean phenolic oligomers (CPO) and middle fraction (SF3&4), light oxygenates (SF5). A two-stage upgrading process was designed to process bio-oil stage fractions into stable products that can be inserted into a refinery. In the upgrading system, heavy and middle bio-oil fractions were upgraded into stable oil via cracking and subsequent hydrodeoxygenation. The light oxygenate fraction was steam reformed to provide a portion of requisite hydrogen for hydroprocessing. Hydrotreating and hydrocracking employed hydrogen from natural gas, fuel gas and light oxygenates reforming. The finished products from this study consist of gasoline- and diesel-blend stock fuels.« less

  20. Biodegradation of oil refinery wastes under OPA and CERCLA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gamblin, W.W.; Banipal, B.S.; Myers, J.M.

    1995-12-31

    Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceededmore » under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).« less

  1. Monitoring coastal pollution associated with the largest oil refinery complex of Venezuela

    PubMed Central

    Bone, David; Bastidas, Carolina; Ramos, Ruth

    2016-01-01

    This study evaluated pollution levels in water and sediments of Península de Paraguaná and related these levels with benthic macrofauna along a coastal area where the largest Venezuelan oil refineries have operated over the past 60 years. For this, the concentration of heavy metals, of hydrocarbon compounds and the community structure of the macrobenthos were examined at 20 sites distributed along 40 km of coastline for six consecutive years, which included windy and calm seasons. The spatial variability of organic and inorganic compounds showed considerably high coastal pollution along the study area, across both years and seasons. The southern sites, closest to the refineries, had consistently higher concentrations of heavy metals and organic compounds in water and sediments when compared to those in the north. The benthic community was dominated by polychaetes at all sites, seasons and years, and their abundance and distribution were significantly correlated with physical and chemical characteristics of the sediments. Sites close to the oil refineries were consistently dominated by families known to tolerate xenobiotics, such as Capitellidae and Spionidae. The results from this study highlight the importance of continuing long-term environmental monitoring programs to assess the impact of effluent discharge and spill events from the oil refineries that operate in the western coast of Paraguaná, Venezuela. PMID:27375970

  2. Monitoring coastal pollution associated with the largest oil refinery complex of Venezuela.

    PubMed

    Croquer, Aldo; Bone, David; Bastidas, Carolina; Ramos, Ruth; García, Elia

    2016-01-01

    This study evaluated pollution levels in water and sediments of Península de Paraguaná and related these levels with benthic macrofauna along a coastal area where the largest Venezuelan oil refineries have operated over the past 60 years. For this, the concentration of heavy metals, of hydrocarbon compounds and the community structure of the macrobenthos were examined at 20 sites distributed along 40 km of coastline for six consecutive years, which included windy and calm seasons. The spatial variability of organic and inorganic compounds showed considerably high coastal pollution along the study area, across both years and seasons. The southern sites, closest to the refineries, had consistently higher concentrations of heavy metals and organic compounds in water and sediments when compared to those in the north. The benthic community was dominated by polychaetes at all sites, seasons and years, and their abundance and distribution were significantly correlated with physical and chemical characteristics of the sediments. Sites close to the oil refineries were consistently dominated by families known to tolerate xenobiotics, such as Capitellidae and Spionidae. The results from this study highlight the importance of continuing long-term environmental monitoring programs to assess the impact of effluent discharge and spill events from the oil refineries that operate in the western coast of Paraguaná, Venezuela.

  3. 33 CFR 165.T09-0333 - Safety zone; Marathon Oil Refinery construction, Rouge River, Detroit, MI.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Safety zone; Marathon Oil Refinery construction, Rouge River, Detroit, MI. 165.T09-0333 Section 165.T09-0333 Navigation and Navigable... Coast Guard District § 165.T09-0333 Safety zone; Marathon Oil Refinery construction, Rouge River...

  4. [Occupational accidents in an oil refinery in Brazil].

    PubMed

    Souza, Carlos Augusto Vaz de; Freitas, Carlos Machado de

    2002-10-01

    Work in oil refineries involves the risk of minor to major accidents. National data show the impact of accidents on this industry. A study was carried out to describe accident profile and evaluate the adequacy of accident reporting system. Data on all accidents reported in an oil refinery in the state of Rio de Janeiro for the year 1997 were organized and analyzed. The study population consisted of 153 injury cases, 83 hired and 69 contracted workers. The variables were: type of accident, operation mode and position of the worker injured. Among hired workers, minor accidents predominated (54.2%) and they occurred during regular operation activities (62.9%). Among contracted workers, there also predominated minor accidents (75.5%) in a higher percentage, but they occurred mainly during maintenance activities (96.8%). The study results showed that there is a predominance of accidents in lower hierarchy workers, and these accidents occur mainly during maintenance activities. There is a need to improve the company's accident reporting system and accident investigation procedures.

  5. Quantification of Methane Leaks from Abandoned Oil and Gas Wells in California

    NASA Astrophysics Data System (ADS)

    Lebel, E.; Kang, M.; Lu, H.; Jackson, R. B.

    2016-12-01

    Abandoned oil and gas wells can provide a pathway for subterranean methane and other gases to be emitted to the atmosphere. However, abandoned wells are unaccounted for in greenhouse gas emissions inventories. While relatively little is known about abandoned wells, previous studies have shown that emissions from abandoned wells contribute approximately 4-7% of anthropogenic methane emissions in Pennsylvania (Kang et al. 2014) and <1% of regional methane emissions in oil and gas producing regions of Colorado, Utah, Ohio, and Wyoming (Townsend-Small et al. 2015). Another study (Boothroyd et al. 2016) has shown that 30% of abandoned wells in the UK have a positive surface methane flux. California has a long history of oil and gas production, beginning from the 1860s, and currently ranks third in oil production by state. As a result, there are more than 100,000 wells across the state. Our study uses static flux chambers to measure individual abandoned wells in California to estimate state-wide methane emissions from these wells. In addition to measuring methane concentrations, we measure ethane, propane, isobutane, n-butane, and 13-CH4 to understand whether this methane has a biogenic or thermogenic source. We hope that our research will determine whether or not abandoned oil and gas wells are a significant source of anthropogenic methane emissions in California. Our results along with measurements in other parts of the United States can be used to scale up methane emission estimates to the national level, accounting for the millions of abandoned wells in the country.

  6. Risk-informed selection of a highway trajectory in the neighborhood of an oil-refinery.

    PubMed

    Papazoglou, I A; Nivolianitou, Z; Aneziris, O; Christou, M D; Bonanos, G

    1999-06-11

    A methodology for characterizing alternative trajectories of a new highway in the neighborhood of an oil-refinery with respect to the risk to public health is presented. The approach is based on a quantitative assessment of the risk that the storage facilities of flammable materials of the refinery pose to the users of the highway. Physical phenomena with a potential for detrimental consequences to public health such as BLEVE (Boiling Liquid Expanding Vapor Explosion), Unconfined Vapor Cloud Explosion, flash fire and pool fire are considered. Methodological and procedural steps for assessing the individual risk around the tank farm of the oil-refinery are presented. Based on the individual risk, group risk for each alternative highway trajectory is determined. Copyright 1999 Elsevier Science B.V.

  7. [Evaluation of the demographic situation in a town with oil refinery and chemical industries].

    PubMed

    Ovsiannikova, L B

    2001-01-01

    In recent years the problem of population health has been acquiring the character of a growing threat to national safety. This is grounded first of all on observation of changes in medical demographic indices, especially in ecologically disadvantaged regions among which are the Republic of Bashcortostan and its capital Ufa with large oil refinery and petrochemical enterprises. High population density and numerous oil refineries combined with the unfavorable meteoconditions are the factors of heavy pollution of the area with global and local ecotoxicants. Observations showed that the demographic situation had been turning tougher in urban, especially residential districts in the vicinity of refineries and petrochemical enterprises. Objective data were obtained indicative of aggravation of medical and genetic indices due to the chronically harmful environment, and socio-economic setback.

  8. Feasibility study on the modernization and expansion of the Tema Oil Refinery: Appendix 1, Part A. REFOP reports. Export trade information (Draft)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1992-04-01

    The Tema Oil Refinery, which was commissioned in 1963, is a simple hydroskimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years, some of the equipment in the refinery has deteriorated or become obsolete, necessitating major rehabilitation. A feasibility study is investigating the modernization and expansion of the refinery to meet projected market demands until the year 2005. This report is appendix I, part A to the feasibility study.

  9. Feasibility study on the modernization and expansion of the Tema Oil Refinery: Appendix 1, Part B. REFOP reports (Final report). Export trade information

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1992-04-01

    The Tema Oil Refinery, which was commissioned in 1963, is a simple hydroskimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years, some of the equipment in the refinery has deteriorated or become obsolete, necessitating major rehabilitation. A feasibility study is investigating the modernization and expansion of the refinery to meet projected market demands until the year 2005. This report is appendix I, part B to the feasibility study.

  10. Analysis of snow-cap pollution for air quality assessment in the vicinity of an oil refinery.

    PubMed

    Krastinyte, Viktorija; Baltrenaite, Edita; Lietuvninkas, Arvydas

    2013-01-01

    Snow-cap can be used as a simple and effective indicator of industrial air pollution. In this study snow-cap samples were collected from 11 sites located in the vicinity of an oil refinery in Mazeikiai, a region in the north-west of Lithuania, in the winter of 2011. Analysis of snowmelt water and snow-dust was used to determine anthropogenic pollutants such as: sulphates and chlorides, nitrites, nitrates, ammonium nitrogen, total carbon, total nitrogen; heavy metals: lead (Pb), copper (Cu), chromium (Cr), cadmium (Cd). Concentrations of heavy metals in snow-dust were detected thousands of times higher than those in the snowmelt water. In this study, analysis of heavy metal concentration was conducted considering different distances and the wind direction within the impact zone of the oil refinery. The sequence of heavy metals according to their mean concentrations in the snow-dust samples was the following: Pb > Cr > Cu > Cd. Heavy metals highly correlated among each other. The load of snow-dust was evaluated to determine the pollution level in the study area. The highest daily load of snow-dust was 45.81 +/- 12.35 mg/m2 in the north-western direction from the oil refinery. According to classification of the daily load of snow-dust a lower than medium-risk level of pollution was determined in the vicinity of the oil refinery.

  11. A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater.

    PubMed

    Yang, Ruihong; Zhu, Jianzhong; Li, Yingliu; Zhang, Hui

    2016-04-29

    Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na₂SO₄ additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography-mass spectrometry (GC-MS) used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet-visible spectroscopy (UV-VIS) absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency.

  12. A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater

    PubMed Central

    Yang, Ruihong; ZHU, Jianzhong; Li, Yingliu; Zhang, Hui

    2016-01-01

    Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na2SO4 additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography–mass spectrometry (GC–MS) used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet–visible spectroscopy (UV–VIS) absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency. PMID:27136574

  13. Oil refinery dusts: morphological and size analysis by TEM.

    PubMed

    Sielicki, Przemysław; Janik, Helena; Guzman, Agnieszka; Broniszewski, Mieczysław; Namieśnik, Jacek

    2011-03-01

    The objectives of this work were to develop a means of sampling atmospheric dusts on the premises of an oil refinery for electron microscopic study to carry out preliminary morphological analyses and to compare these dusts with those collected at sites beyond the refinery limits. Carbon and collodion membranes were used as a support for collection of dust particles straight on transmission electron microscopy (TEM) grids. Micrographs of the dust particles were taken at magnifications from ×4,000 to ×80,000 with a Tesla BS500 transmission electron microscope. Four parameters were defined on the basis of the micrographs: surface area, Feret diameter, circumference, and shape coefficient. The micrographs and literature data were used to classify the atmospheric dusts into six groups: particles with an irregular shape and rounded edges; particles with an irregular shape and sharp edges; soot and its aggregates; spherical particles; singly occurring, ultrafine dust particles; and particles not allocated to any of the previous five groups. The types of dusts found in all the samples were similar, although differences did exist between the various morphological parameters. Dust particles with the largest Feret diameter were present in sample 3 (mean, 0.739 μm)-these were collected near the refinery's effluent treatment plant. The particles with the smallest diameter were found in the sample that had been intended to be a reference sample for the remaining results (mean, 0.326 μm). The dust particles collected in the refinery had larger mean Feret diameters, even 100% larger, than those collected beyond it. Particles with diameters from 0.1 to 0.2 μm made up the most numerous group in all the samples collected in the refinery.

  14. Tracking Emissions of Methane Leaks from Abandoned Oil and Gas Wells in California

    NASA Astrophysics Data System (ADS)

    Lebel, E.; Lu, H.; Vielstädte, L.; Kang, M.; Jackson, R. B.

    2017-12-01

    Abandoned oil and gas wells can provide a substantial pathway for subterranean methane and other gases to be emitted to the atmosphere. However, abandoned wells are unaccounted for in greenhouse gas emissions inventories, primarily because monitoring these wells is not mandatory and quantitative data on leakage rates are rare. Here, we focus on California, which has a long history of oil and gas production, beginning from the 1860s, and currently ranks third in oil production by state. As a result, there are more than 100,000 abandoned wells across the state with yet unknown well integrity status. We tested and improved our static flux chamber design to minimize potential errors and designed new chambers with which we measured methane emissions from individual abandoned wells across California (both exposed and buried) and their surrounding soils. We characterized the respective gas source by measuring stable carbon isotopes of methane and the concentration of heavier hydrocarbons. So far, 6 out of 66 measured wells had a statistically significant methane flux >1mg/hr, with higher release rates linked to exposed and unplugged wells, rather than plugged and buried wells. Our results improve the current understanding of abandoned oil and gas wells as a methane emissions source and along with measurements in other parts of the United States can be used to scale up methane emission estimates to the national level, accounting for the millions of abandoned wells in the country.

  15. Spatial Risk Analysis of Hydraulic Fracturing near Abandoned and Converted Oil and Gas Wells.

    PubMed

    Brownlow, Joshua W; Yelderman, Joe C; James, Scott C

    2017-03-01

    Interaction between hydraulically generated fractures and existing wells (frac hits) could represent a potential risk to groundwater. In particular, frac hits on abandoned oil and gas wells could lead to upward leakage into overlying aquifers, provided migration pathways are present along the abandoned well. However, potential risk to groundwater is relatively unknown because few studies have investigated the probability of frac hits on abandoned wells. In this study, actual numbers of frac hits were not determined. Rather, the probability for abandoned wells to intersect hypothetical stimulated reservoir sizes of horizontal wells was investigated. Well data were compiled and analyzed for location and reservoir information, and sensitivity analyses were conducted by varying assumed sizes of stimulated reservoirs. This study used public and industry data for the Eagle Ford Shale play in south Texas, with specific attention paid to abandoned oil and gas wells converted into water wells (converted wells). In counties with Eagle Ford Shale activity, well-data analysis identified 55,720 abandoned wells with a median age of 1983, and 2400 converted wells with a median age of 1954. The most aggressive scenario resulted in 823 abandoned wells and 184 converted wells intersecting the largest assumed stimulated reservoir size. Analysis showed abandoned wells have the potential to be intersected by multiple stimulated reservoirs, and risks for intersection would increase if currently permitted horizontal wells in the Eagle Ford Shale are actually completed. Results underscore the need to evaluate historical oil and gas activities in areas with modern unconventional oil and gas activities. © 2016, National Ground Water Association.

  16. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmentalmore » inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.« less

  17. Personal exposure to benzene and 1,3-butadiene during petroleum refinery turnarounds and work in the oil harbour.

    PubMed

    Akerstrom, M; Almerud, P; Andersson, E M; Strandberg, B; Sallsten, G

    2016-11-01

    Petroleum refinery workers' exposure to the carcinogens benzene and 1,3-butadiene has decreased during normal operations. However, certain occupational groups or events at the refineries still involve a risk of higher exposures. The aim of this study was to examine the personal exposure to benzene and 1,3-butadiene at refinery turnarounds and during work in the oil harbour. Personal exposure measurements of benzene and 1,3-butadiene were taken during work shifts, with a priori assumed higher benzene exposure, using PerkinElmer diffusive samplers filled with Carbopack X. Mean exposure levels were calculated, and repeated exposure measurements, when available, were assessed using mixed effect models. Group and individual compliance with the Swedish occupational exposure limit (OEL) was tested for the different exposure groups. Mean benzene exposure levels for refinery workers during the three measured turnarounds were 150, 610 and 960 µg/m 3 , and mean exposures for oil harbour workers and sewage tanker drivers were 310 and 360 µg/m 3 , respectively. Higher exposures were associated with handling benzene-rich products. Most occupational groups did not comply with the Swedish OEL for benzene nor did the individuals within the groups. The exposure to 1,3-butadiene was very low, between <1 and 3 % of the Swedish OEL. Work within the petroleum refinery industry, with potential exposure to open product streams containing higher fractions of benzene, pose a risk of personal benzene exposures exceeding the OEL. Refinery workers performing these work tasks frequently, such as contractors, sewage tanker drivers and oil harbour workers, need to be identified and protected.

  18. The use of waterworks sludge for the treatment of vegetable oil refinery industry wastewater.

    PubMed

    Basibuyuk, M; Kalat, D G

    2004-03-01

    Water treatment works using coagulation/flocculation in the process stream will generate a waste sludge. This sludge is termed as ferric, alum, or lime sludge based on which coagulant was primarily used. The works in Adana, Turkey uses ferric chloride. The potential for using this sludge for the treatment of vegetable oil refinery industry wastewater by coagulation has been investigated. The sludge acted as a coagulant and excellent oil and grease, COD and TSS removal efficiencies were obtained. The optimum conditions were a pH of 6 and a sludge dose of 1100 mg SS l(-1). The efficiency of sludge was also compared with alum and ferric chloride for the vegetable oil refinery wastewater. At doses of 1300-1900 mg SS l(-1), the sludge was as effective as ferric chloride and alum at removing oil and grease, COD, and TSS. In addition, various combinations of ferric chloride and waterworks sludge were also examined. Under the condition of 12.5 mg l(-1) fresh ferric chloride and 1000 mg SS l(-1) sludge dose, 99% oil and grease 99% TSS and 83% COD removal efficiencies were obtained.

  19. Assessment and control design for steam vent noise in an oil refinery.

    PubMed

    Monazzam, Mohammad Reza; Golmohammadi, Rostam; Nourollahi, Maryam; Momen Bellah Fard, Samaneh

    2011-06-13

    Noise is one of the most important harmful agents in work environment. Noise pollution in oil refinery industries is related to workers' health. This study aimed to determine the overall noise pollution of an oil refinery operation and its frequency analysis to determine the control plan for a vent noise in these industries. This experimental study performed in control unit of Tehran Oil Refinery in 2008. To determine the noise distributions, environmental noise measurements were carried out by lattice method according to basic information and technical process. The sound pressure level and frequency distribution was measured for each study sources subject separately was performed individually. According to the vent's specification, the measured steam noise characteristics reviewed and compared to the theoretical results of steam noise estimation. Eventually, a double expansion muffler was designed. Data analysis and graphical design were carried out using Excel software. The results of environmental noise measurements indicated that the level of sound pressure was above the national permitted level (85 dB (A)). The Mean level of sound pressure of the studied steam jet was 90.3 dB (L). The results of noise frequency analysis for the steam vents showed that the dominant frequency was 4000 Hz. To obtain 17 dB noise reductions, a double chamber aluminum muffler with 500 mm length and 200 mm diameter consisting pipe drilled was designed. The characteristics of steam vent noise were separated from other sources, a double expansion muffler was designed using a new method based on the level of steam noise, and principle sound frequency, a double expansion muffler was designed.

  20. Fate and effect of naphthenic acids on oil refinery activated sludge wastewater treatment systems.

    PubMed

    Misiti, Teresa; Tezel, Ulas; Pavlostathis, Spyros G

    2013-01-01

    Naphthenic acids (NAs) are a complex group of alkyl-substituted acyclic, monocyclic and polycyclic carboxylic acids present in oil sands process waters, crude oil, refinery wastewater and petroleum products. Crude oil, desalter brine, influent, activated sludge mixed liquor and effluent refinery samples were received from six United States refineries. The total acid number (TAN) of the six crudes tested ranged from 0.12 to 1.5 mg KOH/g crude oil and correlated to the total NA concentration in the crudes. The total NA concentration in the desalter brine, influent, activated sludge mixed liquor and effluent samples ranged from 4.2 to 40.4, 4.5 to 16.6, 9.6 to 140.3 and 2.8 to 11.6 mg NA/L, respectively. The NAs in all wastewater streams accounted for less than 16% of the total COD, indicating that many other organic compounds are present and that NAs are a minor component in refinery wastewaters. Susceptibility tests showed that none of the activated sludge heterotrophic microcosms was completely inhibited by NAs up to 400 mg/L. Growth inhibition ranging from 10 to 59% was observed in all microcosms at and above 100 mg NA/L. NAs chronically-sorbed to activated sludge mixed liquor biomass and powdered activated carbon (PAC) were recalcitrant and persistent. More than 80% of the total NAs remained in the solid phase at the end of the 10-day desorption period (five successive desorption steps). Throughout a 90-day incubation period, the total NA concentration decreased by 33 and 51% in PAC-free and PAC-containing mixed liquor microcosms, respectively. The lower molecular weight fraction of NAs was preferentially degraded in both mixed liquors. The persistence of the residual, higher molecular weight NAs is likely a combination of molecular recalcitrance and decreased bioavailability when chronically-sorbed to the biomass and/or PAC. Copyright © 2012 Elsevier Ltd. All rights reserved.

  1. Incidence of Myelodysplastic Syndrome in UK Petroleum Distribution and Oil Refinery Workers, 1995–2011

    PubMed Central

    Sorahan, Tom; Mohammed, Nuredin

    2016-01-01

    The incidence of myelodysplastic syndrome (MDS) experienced by cohorts of 16,467 petroleum distribution workers and 28,554 oil refinery workers has been investigated. Study subjects were all those male employees first employed at one of 476 UK petroleum distribution centres or eight UK oil refineries in the period 1946–1974; all subjects had a minimum of twelve months employment with some employment after 1st January, 1951. Observed numbers (Obs) of MDS cases were compared with expectations based on national incidence rates for the period 1995–2011. The overall standardised registration ratio (SRR) was 73 (Obs = 17) in petroleum distribution workers for the age-range 15–84 years, and 77 (Obs = 21) for the age-range 15–99 years. The overall SRR was 81 (Obs = 29) in oil refinery workers for the age-range 15–84 years, and 83 (Obs = 36) for the age-range 15–99 years. More detailed analyses were carried out in terms of year of registration, period from hire, decade of hire, and duration of employment. The overall SRR findings did not provide clear evidence for the presence of an occupational cancer hazard, and provide no support for the hypothesis that low-level benzene exposure has an important effect on the risks of MDS. PMID:27164123

  2. Regeneration and reuse waste from an edible oil refinery.

    PubMed

    Boukerroui, Abdelhamid; Belhocine, Lydia; Ferroudj, Sonia

    2017-08-21

    A spent bleaching earth (SBE) from an edible oil refinery has been regenerated by thermal processing in oven, followed by washing with a cold solution of hydrochloric acid (1M). Optimal regeneration conditions have been controlled by decolorization tests of degummed and neutralized soybean oil. Optimal values of treatment (temperature 350°C, carbonization time 01 h, and HCl concentration 1M) gave a very efficient material. After bleaching oil by regenerated spent bleaching earth (RSBE), the chlorophyll-a and β-carotenes contained in crude edible oil and observed respectively at 430, 454, and 483 nm, value of λ max , are very much decreased. The results obtained after decolorization of edible oil by RSBE material indicate, that, during the process, the bleaching oil did not undergo any changes in the free fatty acid content. The peroxide value (PV) was reduced from 4.2 to 1.8 meq O 2 /kg, and the color has been improved (Lovibond color yellow/red: from 50/0.5 to 2.7/0.3, respectively). The RSBE material obtained was characterized by several techniques (FTIR, SEM). The results show that the heat treatment did not affect the mineral structure of RSBE, and the regenerated material recovered its porous structure.

  3. Genotoxic evaluation of an industrial effluent from an oil refinery using plant and animal bioassays.

    PubMed

    Rodrigues, Fernando Postalli; Angeli, José Pedro Friedmann; Mantovani, Mário Sérgio; Guedes, Carmen Luisa Barbosa; Jordão, Berenice Quinzani

    2010-01-01

    Polycyclic aromatic hydrocarbons (PAHs) are genotoxic chemicals commonly found in effluents from oil refineries. Bioassays using plants and cells cultures can be employed for assessing environmental safety and potential genotoxicity. In this study, the genotoxic potential of an oil refinery effluent was analyzed by means of micronucleus (MN) testing of Alium cepa, which revealed no effect after 24 h of treatment. On the other hand, primary lesions in the DNA of rat (Rattus norvegicus) hepatoma cells (HTC) were observed through comet assaying after only 2 h of exposure. On considering the capacity to detect DNA damage of a different nature and of these cells to metabolize xenobiotics, we suggest the association of the two bioassays with these cell types, plant (Allium cepa) and mammal (HTC) cells, for more accurately assessing genotoxicity in environmental samples.

  4. Potential and optimization of two-phase anaerobic digestion of oil refinery waste activated sludge and microbial community study

    PubMed Central

    Wang, Qinghong; Liang, Ying; Zhao, Peng; Li, Qing X.; Guo, Shaohui; Chen, Chunmao

    2016-01-01

    Oil refinery waste activated sludge produced from oil wastewater biological treatment is a major industrial sludge. Two-phase anaerobic digestion of oil refinery waste activated sludge was studied for the first time. Thermal pretreatment under 170 °C is effective on sludge solubilization. At the optimum hydrolytic-acidogenic condition which was pH of 6.5, temperature of 55 °C and HRT of 2 days, 2754 mg/L volatile fatty acids (VFAs) were produced and acetic acid and butyric acid were the key components. Comparative studies of single-phase and two-phase anaerobic digestion in terms of organic removal, biogas production and methane concentration were conducted. The cumulative methane production and soluble COD (SCOD) removal efficiency in the two-phase system were 228 mL/g COD added and 77.8%, respectively, which were 1.6 and 2.1 times higher than those in single-phase anaerobic digestion. Such improved performance is attributed to intensification of dominant microbial population in separated reactors. Caloramator, Ureibacillus, Dechloromonas, Petrobacter, and T78 played important roles in hydrolytic-acidification and oil-organics degradation. Syntrophic bacteria in the family Porphyromonadaceae and the genus Anaerobranca provide acetate for methanogen. The results demonstrated the potential and operating condition of two-phase anaerobic digestion in treatment of oil refinery waste activated sludge. PMID:27905538

  5. Potential and optimization of two-phase anaerobic digestion of oil refinery waste activated sludge and microbial community study

    NASA Astrophysics Data System (ADS)

    Wang, Qinghong; Liang, Ying; Zhao, Peng; Li, Qing X.; Guo, Shaohui; Chen, Chunmao

    2016-12-01

    Oil refinery waste activated sludge produced from oil wastewater biological treatment is a major industrial sludge. Two-phase anaerobic digestion of oil refinery waste activated sludge was studied for the first time. Thermal pretreatment under 170 °C is effective on sludge solubilization. At the optimum hydrolytic-acidogenic condition which was pH of 6.5, temperature of 55 °C and HRT of 2 days, 2754 mg/L volatile fatty acids (VFAs) were produced and acetic acid and butyric acid were the key components. Comparative studies of single-phase and two-phase anaerobic digestion in terms of organic removal, biogas production and methane concentration were conducted. The cumulative methane production and soluble COD (SCOD) removal efficiency in the two-phase system were 228 mL/g COD added and 77.8%, respectively, which were 1.6 and 2.1 times higher than those in single-phase anaerobic digestion. Such improved performance is attributed to intensification of dominant microbial population in separated reactors. Caloramator, Ureibacillus, Dechloromonas, Petrobacter, and T78 played important roles in hydrolytic-acidification and oil-organics degradation. Syntrophic bacteria in the family Porphyromonadaceae and the genus Anaerobranca provide acetate for methanogen. The results demonstrated the potential and operating condition of two-phase anaerobic digestion in treatment of oil refinery waste activated sludge.

  6. Electricity generation and wastewater treatment of oil refinery in microbial fuel cells using Pseudomonas putida.

    PubMed

    Majumder, Dip; Maity, Jyoti Prakash; Tseng, Min-Jen; Nimje, Vanita Roshan; Chen, Hau-Ren; Chen, Chien-Cheng; Chang, Young-Fo; Yang, Tsui-Chu; Chen, Chen-Yen

    2014-09-22

    Microbial fuel cells (MFCs) represent a novel platform for treating wastewater and at the same time generating electricity. Using Pseudomonas putida (BCRC 1059), a wild-type bacterium, we demonstrated that the refinery wastewater could be treated and also generate electric current in an air-cathode chamber over four-batch cycles for 63 cumulative days. Our study indicated that the oil refinery wastewater containing 2213 mg/L (ppm) chemical oxygen demand (COD) could be used as a substrate for electricity generation in the reactor of the MFC. A maximum voltage of 355 mV was obtained with the highest power density of 0.005 mW/cm² in the third cycle with a maximum current density of 0.015 mA/cm² in regard to the external resistor of 1000 Ω. A maximum coulombic efficiency of 6 × 10⁻²% was obtained in the fourth cycle. The removal efficiency of the COD reached 30% as a function of time. Electron transfer mechanism was studied using cyclic voltammetry, which indicated the presence of a soluble electron shuttle in the reactor. Our study demonstrated that oil refinery wastewater could be used as a substrate for electricity generation.

  7. Electricity Generation and Wastewater Treatment of Oil Refinery in Microbial Fuel Cells Using Pseudomonas putida

    PubMed Central

    Majumder, Dip; Maity, Jyoti Prakash; Tseng, Min-Jen; Nimje, Vanita Roshan; Chen, Hau-Ren; Chen, Chien-Cheng; Chang, Young-Fo; Yang, Tsui-Chu; Chen, Chen-Yen

    2014-01-01

    Microbial fuel cells (MFCs) represent a novel platform for treating wastewater and at the same time generating electricity. Using Pseudomonas putida (BCRC 1059), a wild-type bacterium, we demonstrated that the refinery wastewater could be treated and also generate electric current in an air-cathode chamber over four-batch cycles for 63 cumulative days. Our study indicated that the oil refinery wastewater containing 2213 mg/L (ppm) chemical oxygen demand (COD) could be used as a substrate for electricity generation in the reactor of the MFC. A maximum voltage of 355 mV was obtained with the highest power density of 0.005 mW/cm2 in the third cycle with a maximum current density of 0.015 mA/cm2 in regard to the external resistor of 1000 Ω. A maximum coulombic efficiency of 6 × 10−2% was obtained in the fourth cycle. The removal efficiency of the COD reached 30% as a function of time. Electron transfer mechanism was studied using cyclic voltammetry, which indicated the presence of a soluble electron shuttle in the reactor. Our study demonstrated that oil refinery wastewater could be used as a substrate for electricity generation. PMID:25247576

  8. Electrochemical removal of phenol from oil refinery wastewater.

    PubMed

    Abdelwahab, O; Amin, N K; El-Ashtoukhy, E-S Z

    2009-04-30

    This study explores the possibility of using electrocoagulation to remove phenol from oil refinery waste effluent using a cell with horizontally oriented aluminum cathode and a horizontal aluminum screen anode. The removal of phenol was investigated in terms of various parameters namely: pH, operating time, current density, initial phenol concentration and addition of NaCl. Removal of phenol during electrocoagulation was due to combined effect of sweep coagulation and adsorption. The results showed that, at high current density and solution pH 7, remarkable removal of 97% of phenol after 2h can be achieved. The rate of electrocoagulation was observed to increase as the phenol concentration decreases; the maximum removal rate was attained at 30 mg L(-1) phenol concentration. For a given current density using an array of closely packed Al screens as anode was found to be more effective than single screen anode, the percentage phenol removal was found to increase with increasing the number of screens per array. After 2h of electrocoagulation, 94.5% of initial phenol concentration was removed from the petroleum refinery wastewater. Energy consumption and aluminum Electrode consumption were calculated per gram of phenol removed. The present study shows that, electrocoagulation of phenol using aluminum electrodes is a promising process.

  9. Bioremediation by composting of heavy oil refinery sludge in semiarid conditions.

    PubMed

    Marín, José A; Moreno, José L; Hernández, Teresa; García, Carlos

    2006-06-01

    The present work attempts to ascertain the efficacy of low cost technology (in our case, composting) as a bioremediation technique for reducing the hydrocarbon content of oil refinery sludge with a large total hydrocarbon content (250-300 g kg(-1)), in semiarid conditions. The oil sludge was produced in a refinery sited in SE Spain The composting system designed, which involved open air piles turned periodically over a period of 3 months, proved to be inexpensive and reliable. The influence on hydrocarbon biodegradation of adding a bulking agent (wood shavings) and inoculation of the composting piles with pig slurry (a liquid organic fertiliser which adds nutrients and microbial biomass to the pile) was also studied. The most difficult part during the composting process was maintaining a suitable level of humidity in the piles. The most effective treatment was the one in which the bulking agent was added, where the initial hydrocarbon content was reduced by 60% in 3 months, compared with the 32% reduction achieved without the bulking agent. The introduction of the organic fertiliser did not significantly improve the degree of hydrocarbon degradation (56% hydrocarbon degraded). The composting process undoubtedly led to the biodegradation of toxic compounds, as was demonstrated by ecotoxicity tests using luminescent bacteria and tests on plants in Petri dishes.

  10. Test plan, the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon. Revision 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Altman, D.J.; Hazen, T.C.; Tien, A.J.

    1997-05-10

    The overall objective of the bioremediation project is to provide a cost effective bioremediation demonstration of petroleum contaminated soil at the Czechowice Oil Refinery. Additional objectives include training of personnel, and transfer of this technology by example to Poland, and the Risk Abatement Center for Central and Eastern Europe (RACE). The goal of the remediation is to reduce the risk of PAH compounds in soil and provide a green zone (grassy area) adjacent to the site boundary. Initial project discussions with the Czechowice Oil Refinery resulted in helping the refinery find an immediate cost effective solution for the dense organicmore » sludge in the lagoons. They found that when mixed with other waste materials, the sludge could be sold as a fuel source to local cement kilns. Thus the waste was incinerated and provided a revenue stream for the refinery to cleanup the lagoon. This allowed the bioremediation project to focus on remediation of contaminated soil that unusable as fuel, less recalcitrant and easier to handle and remediate. The assessment identified 19 compounds at the refinery that represented significant risk and would require remediation. These compounds consisted of metals, PAH`s, and BTEX. The contaminated soil to be remediated in the bioremediation demonstration contains only PAH (BTEX and metals are not significantly above background concentrations). The final biopile design consists of (1) dewatering and clearing lagoon A to clean clay, (2) adding a 20 cm layer of dolomite with pipes for drainage, leachate collection, air injection, and pH adjustment, (3) adding a 1.1 m layer of contaminated soil mixed with wood chips to improve permeability, and (4) completing the surface with 20 cm of top soil planted with grass.« less

  11. Short-term scheduling of crude oil operations in refinery with high-fusion-point oil and two transportation pipelines

    NASA Astrophysics Data System (ADS)

    Wu, NaiQi; Zhu, MengChu; Bai, LiPing; Li, ZhiWu

    2016-07-01

    In some refineries, storage tanks are located at two different sites, one for low-fusion-point crude oil and the other for high one. Two pipelines are used to transport different oil types. Due to the constraints resulting from the high-fusion-point oil transportation, it is challenging to schedule such a system. This work studies the scheduling problem from a control-theoretic perspective. It proposes to use a hybrid Petri net method to model the system. It then finds the schedulability conditions by analysing the dynamic behaviour of the net model. Next, it proposes an efficient scheduling method to minimize the cost of high-fusion-point oil transportation. Finally, it gives a complex industrial case study to show its application.

  12. Direct measurements of methane emissions from abandoned oil and gas wells in Pennsylvania.

    PubMed

    Kang, Mary; Kanno, Cynthia M; Reid, Matthew C; Zhang, Xin; Mauzerall, Denise L; Celia, Michael A; Chen, Yuheng; Onstott, Tullis C

    2014-12-23

    Abandoned oil and gas wells provide a potential pathway for subsurface migration and emissions of methane and other fluids to the atmosphere. Little is known about methane fluxes from the millions of abandoned wells that exist in the United States. Here, we report direct measurements of methane fluxes from abandoned oil and gas wells in Pennsylvania, using static flux chambers. A total of 42 and 52 direct measurements were made at wells and at locations near the wells ("controls") in forested, wetland, grassland, and river areas in July, August, October 2013 and January 2014, respectively. The mean methane flow rates at these well locations were 0.27 kg/d/well, and the mean methane flow rate at the control locations was 4.5 × 10(-6) kg/d/location. Three out of the 19 measured wells were high emitters that had methane flow rates that were three orders of magnitude larger than the median flow rate of 1.3 × 10(-3) kg/d/well. Assuming the mean flow rate found here is representative of all abandoned wells in Pennsylvania, we scaled the methane emissions to be 4-7% of estimated total anthropogenic methane emissions in Pennsylvania. The presence of ethane, propane, and n-butane, along with the methane isotopic composition, indicate that the emitted methane is predominantly of thermogenic origin. These measurements show that methane emissions from abandoned oil and gas wells can be significant. The research required to quantify these emissions nationally should be undertaken so they can be accurately described and included in greenhouse gas emissions inventories.

  13. [Factors of work environment and employment of workers in production of fuels and solvents at the oil refinery].

    PubMed

    Chebotarev, P A; Kharlashova, N V

    2012-01-01

    Factors of the industrial environment and labor activity of workers of manufacture propellants and solvents at the oil refining enterprise. Working conditions of workers at all installations of manufacture No 1 JSC "Naftan" of Novopolotsk of Byelorussia (production of fuels and solvents). Hygienic evaluation of working conditions of persons working in the production of fuels and solvents at the oil refinery. Sanitary description of the production with hygienic analysis of project design and technological documentation, qualitative and quantitative characteristics of conventional methods in the work environment and working process of employees in the workplace for the main modes of operation of the equipment. The working environment of refineries is influenced by a number of simultaneously acting factors, which have different material nature and characteristics of the action on the human body, the workers in production of fuels and solvents at the refinery, are exposed to a variety of hazardous and dangerous factors of production, a chemical factor is prevalent, of course.

  14. Polycyclic aromatic hydrocarbons, brachial artery distensibility and blood pressure among children residing near an oil refinery

    PubMed Central

    Trasande, Leonardo; Urbina, Elaine M.; Khoder, Mamdouh; Alghamdi, Mansour; Shabaj, Ibrahim; Alam, Mohammed S.; Harrison, Roy M.; Shamy, Magdy

    2017-01-01

    Background Polycyclic aromatic hydrocarbons (PAH) are produced by the burning and processing of fuel oils, and have been associated with oxidant stress, insulin resistance and hypertension in adults. Few studies have examined whether adolescents are susceptible to cardiovascular effects of PAHs. Objective To study associations of PAH exposure with blood pressure (BP) and brachial artery distensibility (BAD), an early marker of arterial wall stiffness, in young boys attending three schools in Jeddah, Saudi Arabia in varying proximity to an oil refinery. Methods Air samples collected from the three schools were analyzed for PAHs. PAH metabolites (total hydroxyphenanthrenes and 1-hydroxypyrene) were measured in urine samples from 184 adolescent males, in whom anthropometrics, heart rate, pulse pressure, brachial artery distensibility and blood pressure were measured. Descriptive, bivariate and multivariable analyses were performed to assess relationships of school location and urinary PAH metabolites with cardiovascular measures. Results Total suspended matter was significantly higher (444 ± 143 µg/m3) at the school near the refinery compared to a school located near a ring road (395 ± 65 µg/m3) and a school located away from vehicle traffic (232 ± 137 µg/m3), as were PAHs. Systolic (0.47 SD units, p = 0.006) and diastolic (0.53 SD units, p < 0.001) BP Z-scores were highest at the school near the refinery, with a 4.36-fold increase in prehypertension (p = 0.001), controlling for confounders. No differences in pulse pressure, BAD and heart rate were noted in relationship to school location. Urinary total hydroxyphenanthrenes and 1-hydroxypyrene were not associated with cardiovascular outcomes. Conclusions Proximity to an oil refinery in Saudi Arabia is associated with prehypertension and increases in PAH and particulate matter exposures. Further study including insulin resistance measurements, better control for confounding, and longitudinal measurement is

  15. Polycyclic aromatic hydrocarbons, brachial artery distensibility and blood pressure among children residing near an oil refinery.

    PubMed

    Trasande, Leonardo; Urbina, Elaine M; Khoder, Mamdouh; Alghamdi, Mansour; Shabaj, Ibrahim; Alam, Mohammed S; Harrison, Roy M; Shamy, Magdy

    2015-01-01

    Polycyclic aromatic hydrocarbons (PAH) are produced by the burning and processing of fuel oils, and have been associated with oxidant stress, insulin resistance and hypertension in adults. Few studies have examined whether adolescents are susceptible to cardiovascular effects of PAHs. To study associations of PAH exposure with blood pressure (BP) and brachial artery distensibility (BAD), an early marker of arterial wall stiffness, in young boys attending three schools in Jeddah, Saudi Arabia in varying proximity to an oil refinery. Air samples collected from the three schools were analyzed for PAHs. PAH metabolites (total hydroxyphenanthrenes and 1-hydroxypyrene) were measured in urine samples from 184 adolescent males, in whom anthropometrics, heart rate, pulse pressure, brachial artery distensibility and blood pressure were measured. Descriptive, bivariate and multivariable analyses were performed to assess relationships of school location and urinary PAH metabolites with cardiovascular measures. Total suspended matter was significantly higher (444 ± 143 μg/m(3)) at the school near the refinery compared to a school located near a ring road (395 ± 65 μg/m(3)) and a school located away from vehicle traffic (232 ± 137 μg/m(3)), as were PAHs. Systolic (0.47 S D units, p = 0.006) and diastolic (0.53 SD units, p < 0.001) BP Z-scores were highest at the school near the refinery, with a 4.36-fold increase in prehypertension (p = 0.001), controlling for confounders. No differences in pulse pressure, BAD and heart rate were noted in relationship to school location. Urinary total hydroxyphenanthrenes and 1-hydroxypyrene were not associated with cardiovascular outcomes. Proximity to an oil refinery in Saudi Arabia is associated with prehypertension and increases in PAH and particulate matter exposures. Further study including insulin resistance measurements, better control for confounding, and longitudinal measurement is indicated. Copyright © 2014 Elsevier Inc. All

  16. 2. NORTHEAST CORNER OF LARD REFINERY (CONNECTING BUILDING ON THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. NORTHEAST CORNER OF LARD REFINERY (CONNECTING BUILDING ON THE RIGHT) - Wilson's Oil House, Lard Refinery, & Edible Fats Factory, Lard Refinery, 2801 Southwest Fifteenth Street, Oklahoma City, Oklahoma County, OK

  17. Impact of software and hardware technologies on occupational health and safety policies in Saudi Arabian oil refineries.

    PubMed

    Idreis, Hany M; Siqueira, Carlos E; Levenstein, Charles C

    2006-01-01

    This article seeks to examine the impact of technology importation on occupational health and safety in both Saudi Arabian and U.S. oil refining industries. Technologies imported to the Saudi oil industry take two forms: hardware (sophisticated equipment to run oil facilities) and software (policies and regulations pertaining to workers' health and safety, and employment rights installed by Aramco's founding multinational companies). This study utilizes qualitative, historically oriented, cross-national case studies to compare and assess workers' health, safety, and rights in Saudi Aramco with its U.S. counterpart, Motiva Enterprises. Two facilities were chosen to conduct field research: the Saudi Aramco oil refinery at Jeddah and Motiva's refinery at Port Arthur, Texas. The Jeddah refinery is fully owned by Saudi Aramco, thus, representing Aramco's health and safety policies and regulations. The Port Arthur refinery serves as a reference case study for U.S. oil refining facilities. The aspects of occupational health and safety in Saudi Aramco--ExxonMobil's joint ventures SAMREF and LUBREF--also are discussed to examine workers' health policies in both companies. The American oil industry made a significant contribution in establishing the Saudi oil industry, with the cooperation of the Saudi government. Despite having outstanding employment benefits schemes in Saudi Aramco, the presence of an organized work force better serves employee participation in Motiva than in Aramco. Safety systems such as Process Safety Management (PSM)--applied in Motiva--partially exist in Aramco to operate hardware technologies safely. Motiva training systems are better through PACE's Triangle of Prevention (TOP). Both companies follow the same pattern of handling occupational injuries and diseases; however, Saudi government agencies (GOSI) are responsible for compensating and treating injured workers. Saudi workers expressed conditional support for the worker committee program

  18. Direct measurements of methane emissions from abandoned oil and gas wells in Pennsylvania

    PubMed Central

    Kang, Mary; Kanno, Cynthia M.; Reid, Matthew C.; Zhang, Xin; Mauzerall, Denise L.; Celia, Michael A.; Chen, Yuheng; Onstott, Tullis C.

    2014-01-01

    Abandoned oil and gas wells provide a potential pathway for subsurface migration and emissions of methane and other fluids to the atmosphere. Little is known about methane fluxes from the millions of abandoned wells that exist in the United States. Here, we report direct measurements of methane fluxes from abandoned oil and gas wells in Pennsylvania, using static flux chambers. A total of 42 and 52 direct measurements were made at wells and at locations near the wells (“controls”) in forested, wetland, grassland, and river areas in July, August, October 2013 and January 2014, respectively. The mean methane flow rates at these well locations were 0.27 kg/d/well, and the mean methane flow rate at the control locations was 4.5 × 10−6 kg/d/location. Three out of the 19 measured wells were high emitters that had methane flow rates that were three orders of magnitude larger than the median flow rate of 1.3 × 10−3 kg/d/well. Assuming the mean flow rate found here is representative of all abandoned wells in Pennsylvania, we scaled the methane emissions to be 4–7% of estimated total anthropogenic methane emissions in Pennsylvania. The presence of ethane, propane, and n-butane, along with the methane isotopic composition, indicate that the emitted methane is predominantly of thermogenic origin. These measurements show that methane emissions from abandoned oil and gas wells can be significant. The research required to quantify these emissions nationally should be undertaken so they can be accurately described and included in greenhouse gas emissions inventories. PMID:25489074

  19. 3. FOURTH FLOOR OF LARD REFINERY (NOTICE ORIGINAL WOODEN BEAMS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. FOURTH FLOOR OF LARD REFINERY (NOTICE ORIGINAL WOODEN BEAMS AND UNDATED LARD PRESS AND VATS ON RIGHT SIDE) - Wilson's Oil House, Lard Refinery, & Edible Fats Factory, Lard Refinery, 2801 Southwest Fifteenth Street, Oklahoma City, Oklahoma County, OK

  20. [Polycyclic aromatic hidrocarbons deposition in the Milazzo-Valle del Mela (Sicily Region, Southern Italy) high-risk area following an oil refinery fire].

    PubMed

    Grechi, Daniele; Biggeri, Annibale

    2016-01-01

    On September 2014, a fire began within an oil refinery involving a storage tank containing several hundreds of thousands cubic meters of virgin naphtha. Mayors of neighbouring municipalities asked the Epidemiology and Prevention Society "Giulio A. Maccacaro" to carry out an environmental survey in order to evaluate what was the nature and how dangerous was suspended dust deposited by the fumes. In the following days, after fire had been extinguished we conducted a sample survey on the presence of polycyclic aromatic hydrocarbons (PAH) and metals in particulate deposited on the soil on a radius of five kilometres from the refinery and we engaged the exposed population. The Milazzo-Valle del Mela (Sicily Region, Southern Italy) high-risk area includes several industrial plants; among them, an oil refinery and a fuel powered energy plant. As reference area we selected the Sarroch municipality (Sardinia Region, Southern Italy), in the coast of the Tyrrhenian Sea, which is geographically comparable, where a large oil refinery is located and where an environmental campaign with measurement of PAH and metals in particulate matter was ongoing. Qualitatively, metal composition of particulate matter resulted similar in the Sarroch and Milazzo samples. Instead, a large excess of PAH was documented in the Milazzo samples as compared to the Sarroch ones. In conclusion, the results of the analysis of the samples of particulate matter deposited in the Milazzo area in the days immediately following the oil refinery fire showed a high quantity of PAH, carcinogenic substances which pose major hazard to population health. The greater fall-out was registered in the proximity of the burnt storage tank and the West neighbourhood, and at lesser extent in the Southern neighbourhood. As a consequence, there was a population exposure to carcinogenic substances which could have reached the food chain.

  1. Well-to-refinery emissions and net-energy analysis of China's crude-oil supply

    NASA Astrophysics Data System (ADS)

    Masnadi, Mohammad S.; El-Houjeiri, Hassan M.; Schunack, Dominik; Li, Yunpo; Roberts, Samori O.; Przesmitzki, Steven; Brandt, Adam R.; Wang, Michael

    2018-03-01

    Oil is China's second-largest energy source, so it is essential to understand the country's greenhouse gas emissions from crude-oil production. Chinese crude supply is sourced from numerous major global petroleum producers. Here, we use a per-barrel well-to-refinery life-cycle analysis model with data derived from hundreds of public and commercial sources to model the Chinese crude mix and the upstream carbon intensities and energetic productivity of China's crude supply. We generate a carbon-denominated supply curve representing Chinese crude-oil supply from 146 oilfields in 20 countries. The selected fields are estimated to emit between 1.5 and 46.9 g CO2eq MJ-1 of oil, with volume-weighted average emissions of 8.4 g CO2eq MJ-1. These estimates are higher than some existing databases, illustrating the importance of bottom-up models to support life-cycle analysis databases. This study provides quantitative insight into China's energy policy and the economic and environmental implications of China's oil consumption.

  2. Emissions of coalbed and natural gas methane from abandoned oil and gas wells in the United States

    NASA Astrophysics Data System (ADS)

    Townsend-Small, Amy; Ferrara, Thomas W.; Lyon, David R.; Fries, Anastasia E.; Lamb, Brian K.

    2016-03-01

    Recent work indicates that oil and gas methane (CH4) inventories for the United States are underestimated. Here we present results from direct measurements of CH4 emissions from 138 abandoned oil and gas wells, a source currently missing from inventories. Most abandoned wells do not emit CH4, but 6.5% of wells had measurable CH4 emissions. Twenty-five percent of wells we visited that had not been plugged emitted > 5 g CH4 h-1. Stable isotopes indicate that wells emit natural gas and/or coalbed CH4. We estimate that abandoned wells make a small contribution (<1%) to regional CH4 emissions in our study areas. Additional data are needed to accurately determine the contribution of abandoned wells to national CH4 budgets, particularly measurements in other basins and better characterization of the abundance and regional distribution of high emitters.

  3. Identification and characterization of high methane-emitting abandoned oil and gas wells

    PubMed Central

    Kang, Mary; Christian, Shanna; Celia, Michael A.; Mauzerall, Denise L.; Bill, Markus; Miller, Alana R.; Chen, Yuheng; Conrad, Mark E.; Darrah, Thomas H.; Jackson, Robert B.

    2016-01-01

    Recent measurements of methane emissions from abandoned oil/gas wells show that these wells can be a substantial source of methane to the atmosphere, particularly from a small proportion of high-emitting wells. However, identifying high emitters remains a challenge. We couple 163 well measurements of methane flow rates; ethane, propane, and n-butane concentrations; isotopes of methane; and noble gas concentrations from 88 wells in Pennsylvania with synthesized data from historical documents, field investigations, and state databases. Using our databases, we (i) improve estimates of the number of abandoned wells in Pennsylvania; (ii) characterize key attributes that accompany high emitters, including depth, type, plugging status, and coal area designation; and (iii) estimate attribute-specific and overall methane emissions from abandoned wells. High emitters are best predicted as unplugged gas wells and plugged/vented gas wells in coal areas and appear to be unrelated to the presence of underground natural gas storage areas or unconventional oil/gas production. Repeat measurements over 2 years show that flow rates of high emitters are sustained through time. Our attribute-based methane emission data and our comprehensive estimate of 470,000–750,000 abandoned wells in Pennsylvania result in estimated state-wide emissions of 0.04–0.07 Mt (1012 g) CH4 per year. This estimate represents 5–8% of annual anthropogenic methane emissions in Pennsylvania. Our methodology combining new field measurements with data mining of previously unavailable well attributes and numbers of wells can be used to improve methane emission estimates and prioritize cost-effective mitigation strategies for Pennsylvania and beyond. PMID:27849603

  4. Production and characterization of rhamnolipid using palm oil agricultural refinery waste.

    PubMed

    Radzuan, Mohd Nazren; Banat, Ibrahim M; Winterburn, James

    2017-02-01

    In this research we assess the feasibility of using palm oil agricultural refinery waste as a carbon source for the production of rhamnolipid biosurfactant through fermentation. The production and characterization of rhamnolipid produced by Pseudomonas aeruginosa PAO1 grown on palm fatty acid distillate (PFAD) under batch fermentation were investigated. Results show that P. aeruginosa PAO1 can grow and produce 0.43gL -1 of rhamnolipid using PFAD as the sole carbon source. Identification of the biosurfactant product using mass spectrometry confirmed the presence of monorhamnolipid and dirhamnolipid. The rhamnolipid produced from PFAD were able to reduce surface tension to 29mNm -1 with a critical micelle concentration (CMC) 420mgL -1 and emulsify kerosene and sunflower oil, with an emulsion index up to 30%. Results demonstrate that PFAD could be used as a low-cost substrate for rhamnolipid production, utilizing and transforming it into a value added biosurfactant product. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Determination of the priority indexes for the oil refinery wastewater treatment process

    NASA Astrophysics Data System (ADS)

    Chesnokova, M. G.; Myshlyavtsev, A. V.; Kriga, A. S.; Shaporenko, A. P.; Markelov, V. V.

    2017-08-01

    The wastewater biological treatment intensity and effectiveness are influenced by many factors: temperature, pH, presence and concentration of toxic substances, the biomass concentration et al. Regulation of them allows controlling the biological treatment process. Using the Bayesian theorem the link between changes was determined and the wastewater indexes normative limits exceeding influence for activated sludge characteristics alteration probability was evaluated. The estimation of total, or aposterioric, priority index presence probability, which characterizes the wastewater treatment level, is an important way to use the Bayesian theorem in activated sludge swelling prediction at the oil refinery biological treatment unit.

  6. Test plan: the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Altman, D.J.; Lombard, K.H.; Hazen, T.C.

    1997-03-31

    The remediation strategies that will be applied at the Czechowice Oil Refinery waste lagoon in Czechowice, Poland are designed, managed, and implemented under the direction of the Westinghouse Savannah River Company (WSRC) for the United States Department of Energy (DOE). WSRC will be assisted in the demonstration by The Institute for Ecology of Industrial Areas (IETU). This collaboration between IETU and DOE will provide the basis for international technology transfer of new and innovative remediation technologies that can be applied in Poland and the Eastern European Region as well.

  7. Phytoremediation of abandoned crude oil contaminated drill sites of Assam with the aid of a hydrocarbon-degrading bacterial formulation.

    PubMed

    Yenn, R; Borah, M; Boruah, H P Deka; Roy, A Sarma; Baruah, R; Saikia, N; Sahu, O P; Tamuli, A K

    2014-01-01

    Environmental deterioration due to crude oil contamination and abandoned drill sites is an ecological concern in Assam. To revive such contaminated sites, afield study was conducted to phytoremediate four crude oil abandoned drill sites of Assam (Gelakey, Amguri, Lakwa, and Borholla) with the aid of two hydrocarbon-degrading Pseudomonas strains designated N3 and N4. All the drill sites were contaminated with 15.1 to 32.8% crude oil, and the soil was alkaline in nature (pH8.0-8.7) with low moisture content, low soil conductivity and low activities of the soil enzymes phosphatase, dehydrogenase and urease. In addition, N, P, K, and C contents were below threshold limits, and the soil contained high levels of heavy metals. Bio-augmentation was achieved by applying Pseudomonas aeruginosa strains N3 and N4 followed by the introduction of screened plant species Tectona grandis, Gmelina arborea, Azadirachta indica, and Michelia champaca. The findings established the feasibility of the phytoremediation of abandoned crude oil-contaminated drill sites in Assam using microbes and native plants.

  8. MBBR evaluation for oil refinery wastewater treatment, with post-ozonation and BAC, for wastewater reuse.

    PubMed

    Schneider, E E; Cerqueira, A C F P; Dezotti, M

    2011-01-01

    This work evaluated the performance of a Moving Bed Biofilm Reactor (MBBR) in the treatment of an oil refinery wastewater. Also, it investigated the possibility of reuse of the MBBR effluent, after ozonation in series with a biological activated carbon (BAC) column. The best performance of the MBBR was achieved with a hydraulic retention time (HRT) of 6 hours, employing a bed to bioreactor volume ratio (V(B)/V(R)) of 0.6. COD and N-NH₄(+) MBBR effluent concentrations ranged from 40 to 75 mg L⁻¹ (removal efficiency of 69-89%) and 2 to 6 mg L⁻¹ (removal efficiency of 45-86%), respectively. Ozonation carried out for 15 min with an ozone concentration of 5 mg L⁻¹ was able to improve the treated wastewater biodegradability. The treatment performance of the BAC columns was practically the same for ozonated and non ozonated MBBR effluents. The dissolved organic carbon (DOC) content of the columns of the activated carbon columns (CAG) was in the range of 2.1-3.8 mg L⁻¹, and the corresponding DOC removal efficiencies were comprised between 52 and 75%. The effluent obtained at the end of the proposed treatment presented a quality, which meet the requirements for water reuse in the oil refinery.

  9. A case-control study to investigate the association between exposure to benzene and deaths from leukaemia in oil refinery workers.

    PubMed

    Rushton, L; Alderson, M R

    1981-01-01

    All deaths with a mention of leukaemia on the death certificate, in men employed over a period of 25 years of 8 oil refineries in the U.K. were identified. The potential benzene exposure of these cases was compared with that of two sets of controls selected from the total refinery population. One set of controls was matched for refinery and year of birth, the other set was matched for refinery, year of birth nd length of service. No information was available on measurement of benzene in the work environment but a job history was obtained from refinery personnel records for all cases and controls. This was used to allocate each man to a benzene exposure level of "low", "medium", or "high". There was no overall excess of deaths from leukaemia when compared with the expectation from national rates. There was also no excess of cytological types of leukaemia which have been shown to be particularly associated with benzene exposure. However, the risk for those men with medium or high exposure relative to the risk for those with low benzene exposure approached a significance (P=0.05) when length of service was taken into account. If there were an increased risk of leukaemia due to benzene exposure, it could have only been one that affected a very small proportion of men within the refinery workforce.

  10. Oil refinery wastewater treatment using coupled electrocoagulation and fixed film biological processes

    NASA Astrophysics Data System (ADS)

    Pérez, Laura S.; Rodriguez, Oscar M.; Reyna, Silvia; Sánchez-Salas, José Luis; Lozada, J. Daniel; Quiroz, Marco A.; Bandala, Erick R.

    2016-02-01

    Oil refinery wastewater was treated using a coupled treatment process including electrocoagulation (EC) and a fixed film aerobic bioreactor. Different variables were tested to identify the best conditions using this procedure. After EC, the effluent was treated in an aerobic biofilter. EC was capable to remove over 88% of the overall chemical oxygen demand (COD) in the wastewater under the best working conditions (6.5 V, 0.1 M NaCl, 4 electrodes without initial pH adjustment) with total petroleum hydrocarbon (TPH) removal slightly higher than 80%. Aluminum release from the electrodes to the wastewater was found an important factor for the EC efficiency and closely related with several operational factors. Application of EC allowed to increase the biodegradability of the sample from 0.015, rated as non-biodegradable, up to 0.5 widely considered as biodegradable. The effluent was further treated using an aerobic biofilter inoculated with a bacterial consortium including gram positive and gram negative strains and tested for COD and TPH removal from the EC treated effluent during 30 days. Cell count showed the typical bacteria growth starting at day three and increasing up to a maximum after eight days. After day eight, cell growth showed a plateau which agreed with the highest decrease on contaminant concentration. Final TPHs concentration was found about 600 mgL-1 after 30 days whereas COD concentration after biological treatment was as low as 933 mgL-1. The coupled EC-aerobic biofilter was capable to remove up to 98% of the total TPH amount and over 95% of the COD load in the oil refinery wastewater.

  11. [Biological monitoring in oil refinery workers].

    PubMed

    Valentino, M; Rapisarda, V; Scorcelletti, M; Caldaroni, M; Mariani, F

    2007-01-01

    The effectiveness of t,t-muconic acid (t,t-MA) has been investigated as indicator of benzene exposure in workers of an oil refinery. 196 blue collar workers that operate in the field and 25 white collar workers who work in administration have been studied. Workers had not chronic diseases; all workers resulted fit to work. The environmental monitoring, effected with personal and fixed samplers (141 samplings), has shown that benzene air levels were lower than 170 mcg/m3. Biological monitoring was performed with measurements of blood benzene, urinary t,t-MA and urinary phenols. Each worker has been questioned regarding smoking habit, consumption of food containing sorbic acid and non-occupational exposure to benzene. Values of biological index were: t,t-MA 88 +/- 94.1 mcg/g cr, phenols 17.7 +/- 2.9 mg/g cr, blood benzene 25.4 +/- 4.3 ng/l. No significant differences were found between blue and white collars respect t,t-MA, phenols, blood benzene, non-occupational exposure to benzene, smoking habit, consumption of food containing sorbic acid. A meaningful correlation was found between the t,t-MA and the ingestion of the number of foods containing sorbic acid (r = 0.87). The results confirm that the t,t-MA seems incapable to distinguish occupationally exposed workers, at low levels of benzene exposure, from unexposed.

  12. Refining Field Measurements of Methane Flux Rates from Abandoned Oil and Gas Wells

    NASA Astrophysics Data System (ADS)

    Lagron, C. S.; Kang, M.; Riqueros, N. S.; Jackson, R. B.

    2015-12-01

    Recent studies in Pennsylvania demonstrate the potential for significant methane emissions from abandoned oil and gas wells. A subset of tested wells was high emitting, with methane flux rates up to seven orders of magnitude greater than natural fluxes (up to 105 mg CH4/hour, or about 2.5LPM). These wells contribute disproportionately to the total methane emissions from abandoned oil and gas wells. The principles guiding the chamber design have been developed for lower flux rates, typically found in natural environments, and chamber design modifications may reduce uncertainty in flux rates associated with high-emitting wells. Kang et al. estimate errors of a factor of two in measured values based on previous studies. We conduct controlled releases of methane to refine error estimates and improve chamber design with a focus on high-emitters. Controlled releases of methane are conducted at 0.05 LPM, 0.50 LPM, 1.0 LPM, 2.0 LPM, 3.0 LPM, and 5.0 LPM, and at two chamber dimensions typically used in field measurements studies of abandoned wells. As most sources of error tabulated by Kang et al. tend to bias the results toward underreporting of methane emissions, a flux-targeted chamber design modification can reduce error margins and/or provide grounds for a potential upward revision of emission estimates.

  13. Pemex to acquire interest in Shell Texas refinery

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1992-08-31

    This paper reports that Petroleos Mexicanos and Shell Oil Co. have signed a memorandum of understanding to form a joint refining venture involving Shell's 225,000 b/d Deer Park, Tex., refinery. Under the agreement, Mexico's state owned oil company is to purchase a 50% interest in the refinery, and Shell is to sell Pemex unleaded gasoline on a long term basis. Under the venture, Shell and Pemex plan to add undisclosed conversion and upgrading units tailored to process heavy Mexican crude. The revamp will allow Pemex to place more than 100,000 b/d of Mayan heavy crude on the U.S. market. Mayanmore » accounts for 70% of Mexico's crude oil exports. In turn, Shell will sell Pemex as much as 45,000 b/d of unleaded gasoline to help meet Mexico's rapidly growing demand.« less

  14. Danube refinery operates under complex air regulations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aalund, L.R.

    1994-05-30

    A good example of a major refinery coping with German environmental regulations is the Erdoel-Raffinerie Neustadt GmbH Co. (ERN) refinery near the town of Neustadt a.d. Donau, or Neustadt on the Danube, in lower Bavaria. The 7 million tons/year (144,000 b/d) complex refinery deals regularly with nearly 30 different crude oils, arriving via the Italian port of Trieste and the Trans Alpine Line from the Middle East, North and West Africa, Venezuela, and the North Sea. Table 1 is a listing of these crudes and some of their characteristics that are important in the refinery's environmental program. ERN is inmore » a relatively isolated pastoral setting of fields and forests about 1[1/2] miles south of the Danube. Hops which go into the world famous Bavarian beers are a major crop in the region and the refinery is only 2 miles from a spa popular since the Romans occupied the Danube valley. German physicians still send patients there to relax, drink the waters, and breathe the country air for a variety of ailments. In short, ERN is in a high-profile setting that demands maximum attention be paid to environmental matters. The paper first describes the various German regulations that affect refineries, then discusses the monitoring and waste processing operations being performed by the ERN refinery.« less

  15. Successful performance of a refinery with Eureka unit

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hirotani, Y.; Takeuchi, T.; Miyabuchi, Y.

    1981-03-01

    Since starting in February, 1976, 3,400,000 Kl of vacuum residue (13,000,000 Kl of crude oil equivalent) has been successfully processed in the Eureka unit of Fuji Oil refinery complex and more than 2,500,000 Kl of cracked oil and 1,000,000 tons of pitch have been produced. The operation rate has been 94 to 98% except for the annual shutdown period for inspection. The cracked oil is easily desulfurized to make naphta, diesel oil and a large amount of gas oil (low sulfur fuel oil, 0.1 wt % sulfur). As for the desulfurization of cracked oil, the increase in H/sub 2/ consumptionmore » and the decline of catalyst life are observed. However, the operation conditions do not differ much from those for straight run fractions. Processing both hydrotreated and untreated cracked heavy oil (CHO) with FCC unit has proved to be possible. In case of untreated CHO, however, it causes a slight increase in make up catalyst and coke yield. It is demonstrated that heavy crude oils, such as Bachaquero, can effectively be processed in this system. No additional pollution problems have occurred by introducing an Eureka unit to the refinery, although it is located in the district where the most stringent environmental regulations are urged.« less

  16. Photochemical ozone formation from petroleum refinery emissions

    NASA Astrophysics Data System (ADS)

    Sexton, Ken; Westberg, Hal

    Atmospheric emissions from the Marathon oil refinery at Robinson, Illinois were investigated during June and July 1977. Surface and aerial measurements were used to provide an integrated, three dimensional monitoring network. Concentrations of ozone, oxides of nitrogen, sulfur dioxide, methane, carbon dioxide, individual non-methane hydrocarbons and halocarbons were recorded on a routine basis. In addition, meteorological parameters such as wind speed, wind direction, solar radiation and mixing height were also measured. The field monitoring study focused on three major areas: (1) characterization of gaseous components within the refinery effluent, especially nonmethane hydrocarbons and nitrogen oxides; (2) natural sunlight bag irradiation experiments to examine ozone forming potential of refinery emissions and (3) aerial measurements of changes in plume chemistry during the first six to eight hours of transport. Results indicate levels of hydrocarbons and nitrogen oxides were elevated downwind of the refinery. Concentrations within the effluent exceeded background values by as much as 300- and 10-fold, respectively. Irradiations of captured refinery emissions suggest excess photochemical ozone can be produced in the first 6 h, with amounts varying according to NMHC/NO x, ratios and initial NMHC concentrations. Real-time measurements on board the aircraft documented instances of ozone buildup in the refinery plume as it drifted downwind.

  17. Treatment and disposal of refinery sludges: Indian scenario.

    PubMed

    Bhattacharyya, J K; Shekdar, A V

    2003-06-01

    Crude oil is a major source of energy and feedstock for petrochemicals. Oily sludge, bio-sludge and chemical sludge are the major sludges generated from the processes and effluent treatment plants of the refineries engaged in crude oil refining operations. Refineries in India generate about 28,220 tons of sludge per annum. Various types of pollutants like phenols, heavy metals, etc. are present in the sludges and they are treated as hazardous waste. Oily sludge, which is generated in much higher amount compared to other sludges, contains phenol (90-100 mg/kg), nickel (17-25 mg/kg), chromium (27-80 mg/kg), zinc (7-80 mg/kg), manganese (19-24 mg/kg), cadmium (0.8-2 mg/kg), copper (32-120 mg/kg) and lead (0.001-0.12 mg/ kg). Uncontrolled disposal practices of sludges in India cause degradation of environmental and depreciation of aesthetic quality. Environmental impact due to improper sludge management has also been identified. Salient features of various treatment and disposal practices have been discussed. Findings of a case study undertaken by the authors for Numaligarh Refinery in India have been presented. Various system alternatives have been identified for waste management in Numaligarh Refinery. A ranking exercise has been carried out to evaluate the alternatives and select the appropriate one. A detailed design of the selected waste management system has been presented.

  18. Analyzing Perceptions of Wellbeing in Relation to Refinería Esmeraldas, The Largest Oil Refinery in Ecuador

    NASA Astrophysics Data System (ADS)

    Toledo, K. S.; Valdivia, G.

    2016-12-01

    Refinería Esmeraldas, the largest oil refinery in Ecuador, has a great influence on the wellbeing of the mainly Afro-Ecuadorean neighborhoods that surround it. Understanding the extent of the refinery's influence on the local community is important as it contributes to a more effective planning for the predicted risks of environmental suffering associated with it, some of which may extend for generations to come. The problem of increased environmental burdens in low income communities of color, such as exposure to environmental pollutants, is often linked to improper regulation. Solutions are often framed in terms of stricter government policies, but equally important and more difficult to quantify factors, such as how pollution manifests in everyday life, also need to be addressed. This study uses primarily qualitative data, composed of structured interviews; spatial data; and audiovisual data, all of which was processed using analytic softwares such as Atlas.ti, Tableau, and ArcGIS, to map the experience of pollution and wellbeing in the city of Esmeraldas. The data was collected using a structured sample design, followed by snowball sampling in neighborhoods within the city. The findings indicate that the impacts of the refinery are not always direct, but rather affect various aspects of the life of Esmeraldeños. Several major wellbeing themes include Personal Trajectories, (Dis)able Bodies, and Urban Needs. These themes provide a more holistic understanding of life with pollution and help understand how people see themselves in relation to the refinery and how it affects their wellbeing. Grounded theory, which adopts an inductive approach, was used to analyze the everyday dimensions of the experience of pollution. The findings suggest that there are varying experiences of wellbeing in relation the refinery and that these have health, environmental, social, and physiological roots, which indicate possible connections between epigenetic manifestations and the

  19. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasolinemore » fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible

  20. The guava tree as bioindicator during the process of fuel replacement of an oil refinery.

    PubMed

    Silva, Simone F; Meirelles, Sérgio T; Moraes, Regina M

    2013-05-01

    This study was performed to verify whether the exchange of the fuel used in the boilers of a crude oil refinery located in Cubatão (SE Brazil) would result in alterations on gas exchange, growth and leaf injuries in saplings of Psidium guajava 'Paluma'. The purpose of the refinery was to reduce the SO2 emission, but using natural gas as fuel could increase the concentrations of O3 precursors in the atmosphere. Thus a biomonitoring was performed with a native species sensitive to O3. The plants were exposed in five areas (CM1, CM5, CEPEMA, Centro, and RP) at different distances to the refinery, both before and after the fuel exchange. We performed six exposures under environmental conditions, with length of ca. 90 days each. With the utilization of natural gas, the saplings presented reductions in carbon assimilation rate under saturating light conditions (Asat, μmolCO2m(-2)s(-1)) and the stomatal conductance (gs, molH2Om(-2)s(-1)), and increase in height, number of leaves, and dry mass of leaves and shoots. There were also reductions in root dry mass and in the root/shoot ratio. The saplings also presented O3-induced leaf injuries. The responses of P. guajava 'Paluma' were altered after the fuel exchange as a result of a new combination of pollutants in the atmosphere. The fuel exchange has not resulted in environmental benefit to the surrounding forest; it has only altered the contamination profile of the region. Copyright © 2013 Elsevier Inc. All rights reserved.

  1. Psidium guajava as a bioaccumulator of nickel around an oil refinery, southern Brazil.

    PubMed

    Trindade Perry, Carolina; Divan, Armando Molina; Raya Rodriguez, Maria Teresa; Lúcia Atz, Vera

    2010-05-01

    To evaluate the potential of Psidium guajava as a biological accumulator of air pollutants, saplings were exposed at nine sites receiving atmospheric emissions from an oil refinery (five within, four outside the industrial area) and another reference site located at the Federal University of Rio Grande do Sul, 27 km from the refinery. Exposures lasted about 3 months each, coincided with the seasons, and totaled five exposures between 2005 and 2006. The following parameters were evaluated: dry weight of leaves, stems, and roots, leaf area, rate of relative height increase, Ni and S contents, maximum assimilation rate, and carboxylation efficiency invivo. P. guajava was found to be an efficient accumulator of Ni, since highly significant differences were observed (P<0.001) between sites within the industrial area and the reference site for all periods of exposure and a significant negative correlation between distance from emission source and Ni content. The S content showed significant differences (P<0.05) only at sites within the industrial area for two exposures. The dry weight, leaf area, rate of relative height increase, maximum assimilation rate, and carboxylation efficiency did not present significant differences for any period of exposure. In view of the above, we conclude that P. guajava is a good bioaccumulator for Ni. Copyright 2009 Elsevier Inc. All rights reserved.

  2. A Long-Term United States’ Energy Policy Without Venezuelan Oil

    DTIC Science & Technology

    2009-04-01

    a large majority of petrochemical plants and refineries are located. 65 The U.S. 13 refinery capacity is expected to increase from 16.9 mbd in...increased oil production. The majority of U.S. oil refineries that normally received Venezuelan oil were supplanted with Mexican Maya, Brazil, and West...The effect on the U.S. would be especially felt since its oil refineries would experience higher transportation costs by importing oil from countries

  3. Hazardous Waste Cleanup: Sunoco Incorporated - R&M Eagle Point Refinery in Westville, New Jersey

    EPA Pesticide Factsheets

    Sunoco, Inc. - R&M Eagle Point Refinery is located on Route 295 & 130 in Westville, West Deptford Township, New Jersey. The site is a 1,000-acre oil refinery on the Delaware River, 550 acres of which is an active production area.

  4. Interdisciplinary study of atmospheric processes and constituents of the mid-Atlantic coastal region. Attachment 3: Data set for Craney Island oil refinery installation experiment. [air pollution monitoring

    NASA Technical Reports Server (NTRS)

    Kindle, E. C.; Bandy, A.; Copeland, G.; Blais, R.; Levy, G.; Sonenshine, D.; Adams, D.; Maier, G.

    1975-01-01

    Data tables and maps are presented which include background information and experimental data on the Craney Island oil refinery installation experiment. The experiment was to investigate air pollution effects.

  5. Managing Exposure to Benzene and Total Petroleum Hydrocarbons at Two Oil Refineries 1977-2014.

    PubMed

    Tuomi, Tapani; Veijalainen, Henna; Santonen, Tiina

    2018-01-24

    Air concentrations of and inhalation exposure to total petroleum hydrocarbons (TPH) and benzene was monitored separately at two oil refineries from 1977 to 2014. Prevention policies and control measures that may explain changes were surveyed. The aim was to evaluate how the application of of Occupational Health and Safety Assessment Series OHSAS 18001.04 principles as well as Environmental protection Agency EPA and European Oil Company Organisation for Environment, Health and Safety CONCAWE practices have influenced air concentrations. Benzene air concentrations declined in 11 of 17 units, six of which were associated with declining exposures. Benzene air concentrations declined across all units on average by 46%. This amounts to an average yearly decline of 1.7%. TPH air concentrations declined in 10 of 17 units, seven of which were associated with declining exposures. The average decline in TPH air concentrations was 49%, corresponding to 1.3% per year. As a result, average working day exposure in 10 of 17 units have declined significantly and today, benzene and TPH exposure in most units are well below 10% of the current Occupational Exposure Limit (OEL 8h :s). A decline in air concentrations have coincided with consistent implementation of control measures. Such measures include on-line monitoring of leaks; benzene recovery; floating container roofs; improved valves and seals; hermetic pumps; recovery of loading gases and instalment of torches in terminals; cutback in coke combustion; a new production line spanning directly from the dock to aromatics production; and recovery of loading gases in the doc. Other tools in exposure management include personal leak monitors, on-line measurements, monitoring campaigns, risk assessment, and availability and user training of protective equipment. However, improvements are still needed. Hydrocarbon or benzene air concentrations have not declined in 8 of 17 units, in some of which concentrations exceed 10% of the relevant

  6. The Implementation and Maintenance of a Behavioral Safety Process in a Petroleum Refinery

    ERIC Educational Resources Information Center

    Myers, Wanda V.; McSween, Terry E.; Medina, Rixio E.; Rost, Kristen; Alvero, Alicia M.

    2010-01-01

    A values-centered and team-based behavioral safety process was implemented in a petroleum oil refinery. Employee teams defined the refinery's safety values and related practices, which were used to guide the process design and implementation. The process included (a) a safety assessment; (b) the clarification of safety-related values and related…

  7. A combination of solvent extraction and freeze thaw for oil recovery from petroleum refinery wastewater treatment pond sludge.

    PubMed

    Hu, Guangji; Li, Jianbing; Hou, Haobo

    2015-01-01

    A combination of solvent extraction and freeze thaw was examined for recovering oil from the high-moisture petroleum refinery wastewater treatment pond sludge. Five solvents including cyclohexane (CHX), dichloromethane (DCM), methyl ethyl ketone (MEK), ethyl acetate (EA), and 2-propanol (2-Pro) were examined. It was found that these solvents except 2-Pro showed a promising oil recovery rate of about 40%, but the recycling of DCM solvent after oil extraction was quite low. Three solvents (CHX, MEK and EA) were then selected for examining the effect of freeze/thaw treatment on improving the quality of recovered oil. This treatment increased the total petroleum hydrocarbon (TPH) content in recovered oil from about 40% to 60% for both MEK and EA extractions, but little effect was observed for CHX extraction. Although the solid residue after oil recovery had a significantly decreased TPH content, a high concentration of heavy metals was observed, indicating that this residue may require proper management. In general, the combination of solvent extraction with freeze/thaw is effective for high-moisture oily hazardous waste treatment. Copyright © 2014 Elsevier B.V. All rights reserved.

  8. Effective Recovery of Vanadium from Oil Refinery Waste into Vanadium-Based Metal-Organic Frameworks.

    PubMed

    Zhan, Guowu; Ng, Wei Cheng; Lin, Wenlin Yvonne; Koh, Shin Nuo; Wang, Chi-Hwa

    2018-03-06

    Carbon black waste, an oil refinery waste, contains a high concentration of vanadium(V) leftover from the processing of crude oil. For the sake of environmental sustainability, it is therefore of interest to recover the vanadium as useful products instead of disposing of it. In this work, V was recovered in the form of vanadium-based metal-organic frameworks (V-MOFs) via a novel pathway by using the leaching solution of carbon black waste instead of commercially available vanadium chemicals. Two different types of V-MOFs with high levels of crystallinity and phase purity were fabricated in very high yields (>98%) based on a coordination modulation method. The V-MOFs exhibited well-defined and controlled shapes such as nanofibers (length: > 10 μm) and nanorods (length: ∼270 nm). Furthermore, the V-MOFs showed high catalytic activities for the oxidation of benzyl alcohol to benzaldehyde, indicating the strong potential of the waste-derived V-MOFs in catalysis applications. Overall, our work offers a green synthesis pathway for the preparation of V-MOFs by using heavy metals of industrial waste as the metal source.

  9. Illness absence at an oil refinery and petrochemical plant.

    PubMed

    Tsai, S P; Gilstrap, E L; Colangelo, T A; Menard, A K; Ross, C E

    1997-05-01

    Results from a prospective illness-absence surveillance of refinery and petrochemical workers from 1986 through 1994 are presented. Illness absence data for this study were extracted from the morbidity section of the Shell Oil Company's Health Surveillance System, which includes records of all illness absences in excess of 5 days. The majority of employees (59%) had no illness absence during the 9-year period studied. The 13% of the population who had three or more absences accounted for 63% of the total illness absence episodes and 62% of the total work days lost. Frequency rate and duration of absence increased with increasing age. The increased illness absence was associated with the presence of known health risk factors, such as smoking, elevated blood pressure, high cholesterol, and obesity. For example, obese women had a twofold increased illness absence rate compared with nonobese women and the rate for male smokers doubled that of nonsmoking men. These health risk factors are also more common among employees with three or more absences than those with fewer or no absences. The goal of this analysis is to quantify the impact of illness absence to develop disease prevention strategies to maximize good health in employees and to minimize both the frequency and duration of illness absence.

  10. Genome Sequences of Two Naphthalene-Degrading Strains of Pseudomonas balearica, Isolated from Polluted Marine Sediment and from an Oil Refinery Site.

    PubMed

    Salvà-Serra, Francisco; Jakobsson, Hedvig E; Busquets, Antonio; Gomila, Margarita; Jaén-Luchoro, Daniel; Seguí, Carolina; Aliaga-Lozano, Francisco; García-Valdés, Elena; Lalucat, Jorge; Moore, Edward R B; Bennasar-Figueras, Antoni

    2017-04-06

    The genome sequences of Pseudomonas balearica strains LS401 (CCUG 66666) and st101 (CCUG 66667) have been determined. The strains were isolated as naphthalene degraders from polluted marine sediment and from a sample from an oil refinery site, respectively. These genomes provide essential data about the biodegradation capabilities and the ecological implications of P. balearica . Copyright © 2017 Salvà-Serra et al.

  11. 77 FR 44685 - ConocoPhillips Company, Trainer Refinery, Including On-Site Leased Workers From Shrack, Young...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-30

    ..., Trainer Refinery, Including On-Site Leased Workers From Shrack, Young, and Associates, Inc., and Project... applicable to workers and former workers of ConocoPhillips Company, Trainer Refinery, Trainer, Pennsylvania..., and heavy oil. The subject worker group includes on-site leased workers from Shrack, Young, and...

  12. 76 FR 52556 - Election To Expense Certain Refineries

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-23

    ... the manufacture, construction, or production of self-constructed property must begin before January 1... is entered into prior to the manufacture, construction, or production of the property for use by the... refinery be designed to serve the primary purpose of processing liquid fuel from crude oil or qualified...

  13. Shell Martinez Refinery, Martinez, CA: Consent Agreement and Final Order

    EPA Pesticide Factsheets

    Final executed Consent Agreement and Final Order (CA/FO) negotiated between EPA Region 9, and Shell Oil Products US relating to violations discovered during routine compliance evaluation inspections at the Shell Martinez Refinery in Martinez, California.

  14. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, severalmore » pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.« less

  15. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or which...

  16. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or which...

  17. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or which...

  18. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or which...

  19. Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra

    2010-06-21

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. Asmore » part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design

  20. Element composition of insoluble fraction of aerosols in snow in the vicinity of oil chemistry refinery (Pavlodar City, Kazakhstan) and petrochemical plant (Tomsk City, Russia)

    NASA Astrophysics Data System (ADS)

    Talovskaya, Anna V.; Filimonenko, Ekaterina A.; Yazikov, Egor G.; Shakhova, Tatyana S.; Parygina, Irina A.

    2015-11-01

    Tomsk petrochemical plant (Russia) and Pavlodar oil chemistry refinery (Kazakhstan) are the sources of air contamination in Tomsk and Pavlodar respectively. Therefore, it is very important to study the level of air contamination with particulate matter as well as ultimate composition of these particles. Disposable solid particles fall out to the snow cover, so snow is an accumulator of the particles. The article deals with the study results of dust load and concentrations of Br, Sb, La, Ce, Sm and Nd in insoluble fraction of aerosols in snow in the vicinity of Pavlodar oil chemistry refinery and Tomsk petrochemical plant. The instrumental neutron activation analysis was used for the ultimate composition detection. Results were shown that the dust load in the vicinity of Tomsk petrochemical plant is higher than in Pavlodar. We have detected high concentrations of La, Br and Sm in insoluble fraction of aerosols in snow in the vicinity of Pavlodar refinery and high concentrations of Sb and Ce in Tomsk. Moreover, we have detected high Br concentration in insoluble fraction of aerosols in snow of the vicinity of both plants. Gas burning on the flares of these enterprises is likely a potential source of Br. La to light lanthanoids ratio have shown La is of anthropogenic origin. In addition, enrichment factor estimation reflects an anthropogenic origin of La, Sm, Br, Ce and Sb as well. These elements might be emitted from different production facilities of the plants.

  1. [Analisys of work-related accidents and incidents in an oil refinery in Rio de Janeiro].

    PubMed

    de Souza, Carlos Augusto Vaz; de Freitas, Carlos Machado

    2003-01-01

    Accidents in the chemical industry can have serious consequences for workers, communities, and the environment and are thus highly relevant to public health. This article is the result of an occupational surveillance project involving several public institutions. We analyze 800 work-related accidents that resulted in injuries, environmental damage, or loss of production in 1997 in an oil refinery located in Rio de Janeiro, Brazil. The methodology was based on managerial and organizational approaches to accident investigation, with the European Union reporting system as the reference. The results highlight various limitations in the process of reporting and investigating accidents, as well as a certain hierarchy of accidents, with more attention given to accidents involving loss of production and less to those resulting in injuries, particularly among outsourced workers.

  2. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Caroline Clifford; Andre Boehman; Chunshan Song

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using knownmore » refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to

  3. Integration of biofiltration and advanced oxidation processes for tertiary treatment of an oil refinery wastewater aiming at water reuse.

    PubMed

    Nogueira, A A; Bassin, J P; Cerqueira, A C; Dezotti, M

    2016-05-01

    The combination of biological and chemical oxidation processes is an interesting approach to remove ready, poor, and non-biodegradable compounds from complex industrial wastewaters. In this study, biofiltration followed by H2O2/UV oxidation (or microfiltration) and final reverse osmosis (RO) step was employed for tertiary treatment of an oil refinery wastewater. Biofiltration alone allowed obtaining total organic carbon (TOC), chemical oxygen demand (COD), UV absorbance at 254 nm (UV254), ammonium, and turbidity removal of around 46, 46, 23, 50, and 61 %, respectively. After the combined biological-chemical oxidation treatment, TOC and UV254 removal amounted to 88 and 79 %, respectively. Whereas, the treatment performance achieved with different UV lamp powers (55 and 95 W) and therefore distinct irradiance levels (26.8 and 46.3 mW/cm(2), respectively) were very similar and TOC and UV254 removal rates were highly affected by the applied C/H2O2 ratio. Silt density index (SDI) was effectively reduced by H2O2/UV oxidation, favoring further RO application. C/H2O2 ratio of 1:4, 55 W UV lamp, and 20-min oxidation reaction corresponded to the experimental condition which provided the best cost/benefit ratio for TOC, UV254, and SDI reduction from the biofilter effluent. The array of treatment processes proposed in this study has shown to be adequate for tertiary treatment of the oil refinery wastewater, ensuring the mitigation of membrane fouling problems and producing a final effluent which is suitable for reuse applications.

  4. Refinery Outages: Description and Potential Impact on Petroleum Product Prices

    EIA Publications

    2007-01-01

    This report responds to a July 13, 2006 request from Chairman Jeff Bingaman of the Senate Committee on Energy and Natural Resources requested that the Energy Information Administration conduct a study of the impact that refinery shutdowns have had on the price of oil and gasoline.

  5. Characterization of oily sludge from a Tehran oil refinery.

    PubMed

    Heidarzadeh, Nima; Gitipour, Saeid; Abdoli, Mohammad Ali

    2010-10-01

    In this study, oily sludge samples generated from a Tehran oil refinery (Pond I) were evaluated for their contamination levels and to propose an adequate remediation technique for the wastes. A simple, random, sampling method was used to collect the samples. The samples were analyzed to measure Total petroleum hydrocarbon (TPH), polyaromatic hydrocarbon (PAH) and heavy metal concentrations in the sludge. Statistical analysis showed that seven samples were adequate to assess the sludge with respect to TPH analyses. The mean concentration of TPHs in the samples was 265,600 mg kg⁻¹. A composite sample prepared from a mix of the seven samples was used to determine the sludge's additional characteristics. Composite sample analysis showed that there were no detectable amounts of PAHs in the sludge. In addition, mean concentrations of the selected heavy metals Ni, Pb, Cd and Zn were 2700, 850, 100, 6100 mg kg⁻¹, respectively. To assess the sludge contamination level, the results from the analysis above were compared with soil clean-up levels. Due to a lack of national standards for soil clean-up levels in Iran, sludge pollutant concentrations were compared with standards set in developed countries. According to these standards, the sludge was highly polluted with petroleum hydrocarbons. The results indicated that incineration, biological treatment and solidification/stabilization treatments would be the most appropriate methods for treatment of the sludges. In the case of solidification/stabilization, due to the high organic content of the sludge, it is recommended to use organophilic clays prior to treatment of the wastes.

  6. Preparation of grout for stabilization of abandoned in-situ oil shale retorts

    DOEpatents

    Mallon, Richard G.

    1982-01-01

    A process for the preparation of grout from burned shale by treating the burned shale in steam at approximately 700.degree. C. to maximize the production of the materials alite and larnite. Oil shale removed to the surface during the preparation of an in-situ retort is first retorted on the surface and then the carbon is burned off, leaving burned shale. The burned shale is treated in steam at approximately 700.degree. C. for about 70 minutes. The treated shale is then ground and mixed with water to produce a grout which is pumped into an abandoned, processed in-situ retort, flowing into the void spaces and then bonding up to form a rigid, solidified mass which prevents surface subsidence and leaching of the spent shale by ground water.

  7. OPEC is springing another trap. [Bring on refineries to control petroleum-product market

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cook, J.

    1979-10-29

    Self-appointed authorities assure the American people that there is no oil crisis: just greed on the part of the big oil companies. But the turmoil in the gold market and the continual sinking of the US dollar make mockery of such facile demagoguery. The truth is simple: The US insists on importing more oil than it can pay for with exports, and so the world is flooded with dollars; meanwhile Congress, afraid to face the truth, fails to do anything either to provide alternative sources of energy or to enforce cutbacks on the American people. Consultant George Henry M. Schuler,more » former diplomat and oil company executive, says we are blundering into yet another OPEC trap because we are discouraging the oil industry from expanding refinery capacity in the US. The problem is a combination of import policy and environmental restrictions, he says, in a study recently completed for the consulting firm of Conant and Associates Ltd., Washington, DC. The prospect is that within a few years we will be dependent on OPEC countries for refined products as well as for crude oil - and that dependency will have dire consequences for the US. Congress cannot create oil reserves in this country, but is has total control over creating refineries, through incentives, consultant Schuler says. The situation is leading us straight to war while a whole chorus of voices assures Americans that it's all the oil companies fault. (MCW)« less

  8. Magnetic surveys for locating abandoned wells

    USGS Publications Warehouse

    ,

    1995-01-01

    Abandoned and unrecorded wells may act as conduits for the contamination of groundwater supplies by oil field brines and other pollutants. The casings of abandoned wells eventually develop leaks, which, if not properly plugged, can allow pollutants to reach freshwater aquifers that supply drinking water. Sources of pollutants include brine ponds, landfill sites, agricultural activities, industrial activities, illegal disposal sites, or accidental spills. The problem is particularly acute in regions where there are old petroleum fields or where water wells have been extensively used for agricultural irrigation. Even urban areas can contain wells that were abandoned and concealed during development. Carefully designed ground magnetic or aeromagnetic surveys can be used to locate abandoned wells by mapping the magnetic disturbances or "anomalies" produced by their steel well casings. The U.S. Geological Survey (USGS) can, at the request of other Federal, State, or local agencies, conduct, process, and interpret such surveys, or it can aid in the design and monitoring of contracts for such surveys.

  9. Fingerprinting aliphatic hydrocarbon pollutants over agricultural lands surrounding Tehran oil refinery.

    PubMed

    Bayat, Javad; Hashemi, Seyed Hossein; Khoshbakht, Korros; Deihimfard, Reza

    2016-11-01

    The analysis of aliphatic hydrocarbons, which are composed of n-alkanes as well as branched and cyclic alkanes, can be used to distinguish between the sources of hydrocarbon contamination. In this study, the concentration of aliphatic hydrocarbons, soil pH, and organic matter in agricultural soils located south of Tehran were monitored. Eighty-three soil samples were taken from two depth ranges of 0-30 and 30-60 cm. The results showed that aliphatic compounds ranged from 0.22-68.11 mg kg -1 at the top to 0.33-53.18 mg kg -1 at subsoil. The amount of hydrocarbons increases from the northern parts toward the south, and hydrocarbon pollutants originated from both petroleum and non-petroleum sources. Higher concentrations of aliphatic compounds in the southern parts indicated that, aside from the practice of irrigating with untreated wastewater, leakage from oil refinery storage tanks possibly contributed to soil pollution. The results also showed that several sources have polluted the agricultural soils. It is necessary to develop a new local pollution criterion as a diagnostic index that includes not only hydrocarbons but also other parameters such as heavy metal content in both soil and untreated wastewater, surface runoff, and other irrigation water resources to determine the exact origin of pollution.

  10. Model-centered approach to early planning and design of an eco-industrial park around an oil refinery.

    PubMed

    Zhang, Xiangping; Strømman, Anders H; Solli, Christian; Hertwich, Edgar G

    2008-07-01

    Industrial symbiosis promises environmental and economic gains through a utilization of the waste of some processes as a resource for other processes. Because of the costs and difficulties of transporting some wastes, the largest theoretical potential for industrial symbiosis is given when facilities are colocated in an eco-industrial park (EIP). This study proposes a model-centered approach with an eight-step procedure for the early planning and design of an eco-industrial park considering technical and environmental factors. Chemical process simulation software was used to model the energy and material flows among the prospective members and to quantify the benefits of integration among different firms in terms of energy and resources saved as compared to a reference situation. Process simulation was based on a combination of physical models of industrial processes and empirical models. The modeling allows for the development and evaluation of different collaboration opportunities and configurations. It also enables testing chosen configurations under hypothetical situations or external conditions. We present a case study around an existing oil and gas refinery in Mongstad, Norway. We used the approach to propose the colocation of a number of industrial facilities around the refinery, focused on integrating energy use among the facilities. An EIP with six main members was designed and simulated, matching new hypothetical members in size to the existing operations, modeling material and energy flows in the EIP, and assessing these in terms of carbon and hydrogen flows.

  11. Interdisciplinary study of atmospheric processes and constituents of the mid-Atlantic coastal region. Attachment 4: Data set for background investigation of atmospheric constituents for Nansemond River site. [a proposed oil refinery site

    NASA Technical Reports Server (NTRS)

    Kindle, E. C.; Bandy, E. C.; Copeland, G.; Blais, R.; Levy, G.; Sonenshine, D.; Adams, D.; Maier, G.

    1975-01-01

    Background data was provided for the assessment of the environmental impact of a proposed oil refinery location. Climatic background, particulate data, digitized portrayal of site molecular and meteorological data, graphical portrayal of molecular data, hourly meteorological data, and streamflow charts and radiosonde data are given

  12. A cross-cultural study of organizational factors on safety: Japanese vs. Taiwanese oil refinery plants.

    PubMed

    Hsu, Shang Hwa; Lee, Chun-Chia; Wu, Muh-Cherng; Takano, Kenichi

    2008-01-01

    This study attempts to identify idiosyncrasies of organizational factors on safety and their influence mechanisms in Taiwan and Japan. Data were collected from employees of Taiwanese and Japanese oil refinery plants. Results show that organizational factors on safety differ in the two countries. Organizational characteristics in Taiwanese plants are highlighted as: higher level of management commitment to safety, harmonious interpersonal relationship, more emphasis on safety activities, higher devotion to supervision, and higher safety self-efficacy, as well as high quality of safety performance. Organizational characteristics in Japanese plants are highlighted as: higher level of employee empowerment and attitude towards continuous improvement, more emphasis on systematic safety management approach, efficient reporting system and teamwork, and high quality of safety performance. The casual relationships between organizational factors and workers' safety performance were investigated using structural equation modeling (SEM). Results indicate that the influence mechanisms of organizational factors in Taiwan and Japan are different. These findings provide insights into areas of safety improvement in emerging countries and developed countries respectively.

  13. Review on innovative techniques in oil sludge bioremediation

    NASA Astrophysics Data System (ADS)

    Mahdi, Abdullah M. El; Aziz, Hamidi Abdul; Eqab, Eqab Sanoosi

    2017-10-01

    Petroleum hydrocarbon waste is produced in worldwide refineries in significant amount. In Libya, approximately 10,000 tons of oil sludge is generated in oil refineries (hydrocarbon waste mixtures) annually. Insufficient treatment of those wastes can threaten the human health and safety as well as our environment. One of the major challenges faced by petroleum refineries is the safe disposal of oil sludge generated during the cleaning and refining process stages of crude storage facilities. This paper reviews the hydrocarbon sludge characteristics and conventional methods for remediation of oil hydrocarbon from sludge. This study intensively focuses on earlier literature to describe the recently selected innovation technology in oily hydrocarbon sludge bioremediation process. Conventional characterization parameters or measurable factors can be gathered in chemical, physical, and biological parameters: (1) Chemical parameters are consequently necessary in the case of utilization of topsoil environment when they become relevant to the presence of nutrients and toxic compounds; (2) Physical parameters provide general data on sludge process and hand ability; (3) Biological parameters provide data on microbial activity and organic matter presence, which will be used to evaluate the safety of the facilities. The objective of this research is to promote the bioremediating oil sludge feasibility from Marsa El Hariga Terminal and Refinery (Tobruk).

  14. Health hazard evaluation report HETA 83-248-1515, Arco Philadelphia refinery, Philadelphia, Pennsylvania

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lewis, F.A.; Parrish, G.

    1984-10-01

    A bulk sample of fractionator residue was analyzed for polynuclear aromatic (PNA) compounds at the catalytic cracking unit of ARCO Philadelphia Refinery (SIC-2911), Philadelphia, Pennsylvania in May, 1983. The study was requested by the Atlantic Independent Union to determine if skin rashes and skin irritation occurring among refinery workers were caused by PNA in the fractionators. The authors conclude that a health hazard from exposure to chemicals at the cracking unit may exist. No specific chemical agent can be identified. Dust from the catalyst and oily residues that could contaminate workers shoes and clothing may have contributed to some ofmore » the dermatitis cases. Recommendations include laundering workers coveralls by dry cleaning to insure the removal of oily residues, providing workers with oil resistant or oil proof work boots, and repairing the ventilator in the sample preparation room adjacent to the block house.« less

  15. Bioremediation of wastewater from edible oil refinery factory using oleaginous microalga Desmodesmus sp. S1.

    PubMed

    Mar, Cho Cho; Fan, Yong; Li, Fu-Li; Hu, Guang-Rong

    2016-12-01

    Edible oil industry produced massive wastewater, which requires extensive treatment to remove pungent smell, high phosphate, carbon oxygen demand (COD), and metal ions prior to discharge. Traditional anaerobic and aerobic digestion could mainly reduce COD of the wastewater from oil refinery factories (WEORF). In this study, a robust oleaginous microalga Desmodesmus sp. S1 was adapted to grow in WEORF. The biomass and lipid content of Desmodesmus sp. S1 cultivated in the WEORF supplemented with sodium nitrate were 5.62 g·L(-1) and 14.49%, whereas those in the WEORF without adding nitrate were 2.98 g·L(-1) and 21.95%. More than 82% of the COD and 53% of total phosphorous were removed by Desmodesmus sp. S1. In addition, metal ions, including ferric, aluminum, manganese and zinc were also diminished significantly in the WEORF after microalgal growth, and pungent smell vanished as well. In comparison with the cells grown in BG-11 medium, the cilia-like bulges and wrinkles on the cell surface of Desmodesmus sp. S1 grown in WEORF became out of order, and more polyunsaturated fatty acids were detected due to stress derived from the wastewater. The study suggests that growing microalgae in WEORF can be applied for the dual roles of nutrient removal and biofuel feedstock production.

  16. An Approximation Solution to Refinery Crude Oil Scheduling Problem with Demand Uncertainty Using Joint Constrained Programming

    PubMed Central

    Duan, Qianqian; Yang, Genke; Xu, Guanglin; Pan, Changchun

    2014-01-01

    This paper is devoted to develop an approximation method for scheduling refinery crude oil operations by taking into consideration the demand uncertainty. In the stochastic model the demand uncertainty is modeled as random variables which follow a joint multivariate distribution with a specific correlation structure. Compared to deterministic models in existing works, the stochastic model can be more practical for optimizing crude oil operations. Using joint chance constraints, the demand uncertainty is treated by specifying proximity level on the satisfaction of product demands. However, the joint chance constraints usually hold strong nonlinearity and consequently, it is still hard to handle it directly. In this paper, an approximation method combines a relax-and-tight technique to approximately transform the joint chance constraints to a serial of parameterized linear constraints so that the complicated problem can be attacked iteratively. The basic idea behind this approach is to approximate, as much as possible, nonlinear constraints by a lot of easily handled linear constraints which will lead to a well balance between the problem complexity and tractability. Case studies are conducted to demonstrate the proposed methods. Results show that the operation cost can be reduced effectively compared with the case without considering the demand correlation. PMID:24757433

  17. An approximation solution to refinery crude oil scheduling problem with demand uncertainty using joint constrained programming.

    PubMed

    Duan, Qianqian; Yang, Genke; Xu, Guanglin; Pan, Changchun

    2014-01-01

    This paper is devoted to develop an approximation method for scheduling refinery crude oil operations by taking into consideration the demand uncertainty. In the stochastic model the demand uncertainty is modeled as random variables which follow a joint multivariate distribution with a specific correlation structure. Compared to deterministic models in existing works, the stochastic model can be more practical for optimizing crude oil operations. Using joint chance constraints, the demand uncertainty is treated by specifying proximity level on the satisfaction of product demands. However, the joint chance constraints usually hold strong nonlinearity and consequently, it is still hard to handle it directly. In this paper, an approximation method combines a relax-and-tight technique to approximately transform the joint chance constraints to a serial of parameterized linear constraints so that the complicated problem can be attacked iteratively. The basic idea behind this approach is to approximate, as much as possible, nonlinear constraints by a lot of easily handled linear constraints which will lead to a well balance between the problem complexity and tractability. Case studies are conducted to demonstrate the proposed methods. Results show that the operation cost can be reduced effectively compared with the case without considering the demand correlation.

  18. Characterization of fast-pyrolysis bio-oil distillation residues and their potential applications

    USDA-ARS?s Scientific Manuscript database

    A typical petroleum refinery makes use of the vacuum gas oil by cracking the large molecular weight compounds into light fuel hydrocarbons. For various types of fast pyrolysis bio-oil, successful analogous methods for processing heavy fractions could expedite integration into a petroleum refinery fo...

  19. Towards Understanding Methane Emissions from Abandoned Wells

    EPA Science Inventory

    Reconciliation of large-scale top-down methane measurements and bottom-up inventories requires complete accounting of source types. Methane emissions from abandoned oil and gas wells is an area of uncertainty. This presentation reviews progress to characterize the potential inv...

  20. Bio-refinery approach for spent coffee grounds valorization.

    PubMed

    Mata, Teresa M; Martins, António A; Caetano, Nídia S

    2018-01-01

    Although normally seen as a problem, current policies and strategic plans concur that if adequately managed, waste can be a source of the most interesting and valuable products, among which metals, oils and fats, lignin, cellulose and hemicelluloses, tannins, antioxidants, caffeine, polyphenols, pigments, flavonoids, through recycling, compound recovery or energy valorization, following the waste hierarchy. Besides contributing to more sustainable and circular economies, those products also have high commercial value when compared to the ones obtained by currently used waste treatment methods. In this paper, it is shown how the bio-refinery framework can be used to obtain high value products from organic waste. With spent coffee grounds as a case study, a sequential process is used to obtain first the most valuable, and then other products, allowing proper valorization of residues and increased sustainability of the whole process. Challenges facing full development and implementation of waste based bio-refineries are highlighted. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. The Influence of Soil Characteristics on the Toxicity of Oil Refinery Waste for the Springtail Folsomia candida (Collembola).

    PubMed

    Reinecke, Adriaan J; van Wyk, Mia; Reinecke, Sophie A

    2016-06-01

    We determined the toxicity of oil refinery waste in three soils using the springtail Folsomia candida (Collembola) in bioassays. Sublethal exposure to a concentration series of API-sludge presented EC50's for reproduction of 210 mg/kg in site soil; 880 mg/kg in LUFA2.2- and 3260 mg/kg in OECD-soil. The sludge was the least toxic in the OECD-soil with the highest clay and organic matter content, the highest maximum water holding capacity, and the least amount of sand. It was the most toxic in the reference site soil with the lowest organic matter content and highest sand content. The results emphasized the important role of soil characteristics such as texture and organic matter content in influencing toxicity, possibly by affecting bioavailability of toxicants.

  2. 25 CFR 226.28 - Shutdown, abandonment, and plugging of wells.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... OSAGE RESERVATION LANDS FOR OIL AND GAS MINING Cessation of Operations § 226.28 Shutdown, abandonment... production of oil and/or gas has been demonstrated to the satisfaction of the Superintendent. Lessee shall... the means by which the well bore is to be protected, and the contemplated eventual disposition of the...

  3. 40 CFR 60.693-2 - Alternative standards for oil-water separators.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... for VOC Emissions From Petroleum Refinery Wastewater Systems § 60.693-2 Alternative standards for oil... installation of the floating roof and introduction of refinery wastewater and once every 5 years thereafter. (B... refinery wastewater and once every year thereafter. (iv) The owner or operator shall make necessary repairs...

  4. 40 CFR 60.693-2 - Alternative standards for oil-water separators.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... for VOC Emissions From Petroleum Refinery Wastewater Systems § 60.693-2 Alternative standards for oil... installation of the floating roof and introduction of refinery wastewater and once every 5 years thereafter. (B... refinery wastewater and once every year thereafter. (iv) The owner or operator shall make necessary repairs...

  5. 40 CFR 60.693-2 - Alternative standards for oil-water separators.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... for VOC Emissions From Petroleum Refinery Wastewater Systems § 60.693-2 Alternative standards for oil... installation of the floating roof and introduction of refinery wastewater and once every 5 years thereafter. (B... refinery wastewater and once every year thereafter. (iv) The owner or operator shall make necessary repairs...

  6. 40 CFR 60.693-2 - Alternative standards for oil-water separators.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... for VOC Emissions From Petroleum Refinery Wastewater Systems § 60.693-2 Alternative standards for oil... installation of the floating roof and introduction of refinery wastewater and once every 5 years thereafter. (B... refinery wastewater and once every year thereafter. (iv) The owner or operator shall make necessary repairs...

  7. Co-cracking of bio-oil distillate bottoms with vacuum gas oil for enhanced production of light compounds

    USDA-ARS?s Scientific Manuscript database

    Seamless co-processing of pyrolysis bio-oil within existing petroleum refineries is the most synergistic and economic way to improve biorefinery output. Coprocessing bio-oil with vacuum gas oil (VGO) is one logical pathway. Bio-oil has a viscosity and molecular weight range similar to that of VGO, a...

  8. Numerical Simulation of an Industrial Cumulus Affected by Heat, Moisture, and CCN Released from an Oil Refinery.

    NASA Astrophysics Data System (ADS)

    Guan, S.; Reuter, G. W.

    1996-08-01

    Large oil refineries emit heat, vapor, and cloud condensation nuclei (CCN), all of which can affect the formation of cloud and precipitation. This study quantities the relative contributions of the three factors on cloud development in calm wind conditions using an axisymmetric cloud model. The factor separation technique is applied to isolate the net contributions of waste heat, vapor, and CCN on the rainfall of a cumulus developing in the industrial plume. The mutual-interactive contributions of two or three of the factors are also computed.The simulations for midlatitude and tropical conditions indicate that the sensible heat provides the major stimulus for cloud development and rain formation. The pure contribution of the industrial CCN is to enhance the condensation, causing an increase in the mass of total cloud water. The simulation results indicate that mutual interactions between waste heat and industrial CCN are large for both cases considered.

  9. Preparation of grout for stabilization of abandoned in-situ oil shale retorts. [Patent application

    DOEpatents

    Mallon, R.G.

    1979-12-07

    A process is described for the preparation of grout from burned shale by treating the burned shale in steam at approximately 700/sup 0/C to maximize the production of the materials alite and larnite. Oil shale removed to the surface during the preparation of an in-situ retort is first retorted on the surface and then the carbon is burned off, leaving burned shale. The burned shale is treated in steam at approximately 700/sup 0/C for about 70 minutes. The treated shale is then ground and mixed with water to produce a grout which is pumped into an abandoned, processed in-situ retort, flowing into the void spaces and then bonding up to form a rigid, solidified mass which prevents surface subsidence and leaching of the spent shale by ground water.

  10. Shale Oil Value Enhancement Research

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    James W. Bunger

    2006-11-30

    Raw kerogen oil is rich in heteroatom-containing compounds. Heteroatoms, N, S & O, are undesirable as components of a refinery feedstock, but are the basis for product value in agrochemicals, pharmaceuticals, surfactants, solvents, polymers, and a host of industrial materials. An economically viable, technologically feasible process scheme was developed in this research that promises to enhance the economics of oil shale development, both in the US and elsewhere in the world, in particular Estonia. Products will compete in existing markets for products now manufactured by costly synthesis routes. A premium petroleum refinery feedstock is also produced. The technology is nowmore » ready for pilot plant engineering studies and is likely to play an important role in developing a US oil shale industry.« less

  11. Removal of hydrocarbon from refinery tank bottom sludge employing microbial culture.

    PubMed

    Saikia, Rashmi Rekha; Deka, Suresh

    2013-12-01

    Accumulation of oily sludge is becoming a serious environmental threat, and there has not been much work reported for the removal of hydrocarbon from refinery tank bottom sludge. Effort has been made in this study to investigate the removal of hydrocarbon from refinery sludge by isolated biosurfactant-producing Pseudomonas aeruginosa RS29 strain and explore the biosurfactant for its composition and stability. Laboratory investigation was carried out with this strain to observe its efficacy of removing hydrocarbon from refinery sludge employing whole bacterial culture and culture supernatant to various concentrations of sand-sludge mixture. Removal of hydrocarbon was recorded after 20 days. Analysis of the produced biosurfactant was carried out to get the idea about its stability and composition. The strain could remove up to 85 ± 3 and 55 ± 4.5 % of hydrocarbon from refinery sludge when whole bacterial culture and culture supernatant were used, respectively. Maximum surface tension reduction (26.3 mN m(-1)) was achieved with the strain in just 24 h of time. Emulsification index (E24) was recorded as 100 and 80 % with crude oil and n-hexadecane, respectively. The biosurfactant was confirmed as rhamnolipid containing C8 and C10 fatty acid components and having more mono-rhamnolipid congeners than the di-rhamnolipid ones. The biosurfactant was stable up to 121 °C, pH 2-10, and up to a salinity value of 2-10 % w/v. To our knowledge, this is the first report showing the potentiality of a native strain from the northeast region of India for the efficient removal of hydrocarbon from refinery sludge.

  12. Green ultrasound-assisted extraction of carotenoids based on the bio-refinery concept using sunflower oil as an alternative solvent.

    PubMed

    Li, Ying; Fabiano-Tixier, Anne Sylvie; Tomao, Valérie; Cravotto, Giancarlo; Chemat, Farid

    2013-01-01

    A green, inexpensive and easy-to-use method for carotenoids extraction from fresh carrots assisted by ultrasound was designed in this work. Sunflower oil was applied as a substitute to organic solvents in this green ultrasound-assisted extraction (UAE): a process which is in line with green extraction and bio-refinery concepts. The processing procedure of this original UAE was first compared with conventional solvent extraction (CSE) using hexane as solvent. Moreover, the UAE optimal conditions for the subsequent comparison were optimized using response surface methodology (RSM) and ultra performance liquid chromatography--diode array detector--mass spectroscopy (UPLC-DAD-MS). The results showed that the UAE using sunflower as solvent has obtained its highest β-carotene yield (334.75 mg/l) in 20 min only, while CSE using hexane as solvent obtained a similar yield (321.35 mg/l) in 60 min. The green UAE performed under optimal extraction conditions (carrot to oil ratio of 2:10, ultrasonic intensity of 22.5 W cm(-2), temperature of 40 °C and sonication time of 20 min) gave the best yield of β-carotene. Copyright © 2012 Elsevier B.V. All rights reserved.

  13. Geographic Concentration of Oil Infrastructure: Issues and Options

    DTIC Science & Technology

    2007-03-24

    their homes and plants , and destroy ports and refineries , thereby shattering the U.S. economy. The scope, scale, frequency and location of terrorist...for the above reasons. The corridor along the Mississippi River between Baton Rouge and New Orleans is home to six major refineries . These... refineries process more than 1.7 million barrels of oil per day to produce 775 thousand barrels of motor gasoline and 440 million barrels of distillate fuel

  14. Energy efficiency and greenhouse gas emission intensity of petroleum products at U.S. refineries.

    PubMed

    Elgowainy, Amgad; Han, Jeongwoo; Cai, Hao; Wang, Michael; Forman, Grant S; DiVita, Vincent B

    2014-07-01

    This paper describes the development of (1) a formula correlating the variation in overall refinery energy efficiency with crude quality, refinery complexity, and product slate; and (2) a methodology for calculating energy and greenhouse gas (GHG) emission intensities and processing fuel shares of major U.S. refinery products. Overall refinery energy efficiency is the ratio of the energy present in all product streams divided by the energy in all input streams. Using linear programming (LP) modeling of the various refinery processing units, we analyzed 43 refineries that process 70% of total crude input to U.S. refineries and cover the largest four Petroleum Administration for Defense District (PADD) regions (I, II, III, V). Based on the allocation of process energy among products at the process unit level, the weighted-average product-specific energy efficiencies (and ranges) are estimated to be 88.6% (86.2%-91.2%) for gasoline, 90.9% (84.8%-94.5%) for diesel, 95.3% (93.0%-97.5%) for jet fuel, 94.5% (91.6%-96.2%) for residual fuel oil (RFO), and 90.8% (88.0%-94.3%) for liquefied petroleum gas (LPG). The corresponding weighted-average, production GHG emission intensities (and ranges) (in grams of carbon dioxide-equivalent (CO2e) per megajoule (MJ)) are estimated to be 7.8 (6.2-9.8) for gasoline, 4.9 (2.7-9.9) for diesel, 2.3 (0.9-4.4) for jet fuel, 3.4 (1.5-6.9) for RFO, and 6.6 (4.3-9.2) for LPG. The findings of this study are key components of the life-cycle assessment of GHG emissions associated with various petroleum fuels; such assessment is the centerpiece of legislation developed and promulgated by government agencies in the United States and abroad to reduce GHG emissions and abate global warming.

  15. 3. FOURTH FLOOR OF OIL HOUSE (NOTICE CAST IRON SUPPORT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. FOURTH FLOOR OF OIL HOUSE (NOTICE CAST IRON SUPPORT POSTS AND OIL PRESS IN THE CENTER) - Wilson's Oil House, Lard Refinery, & Edible Fats Factory, Oil House, 2801 Southwest Fifteenth Street, Oklahoma City, Oklahoma County, OK

  16. Influence of Hydraulic Fracturing on Overlying Aquifers in the Presence of Leaky Abandoned Wells.

    PubMed

    Brownlow, Joshua W; James, Scott C; Yelderman, Joe C

    2016-11-01

    The association between hydrocarbon-rich reservoirs and organic-rich source rocks means unconventional oil and gas plays usually occur in mature sedimentary basins-where large-scale conventional development has already taken place. Abandoned wells in proximity to hydraulic fracturing could be affected by increased fluid pressures and corresponding newly generated fractures that directly connect (frac hit) to an abandoned well or to existing fractures intersecting an abandoned well. If contaminants migrate to a pathway hydraulically connected to an abandoned well, upward leakage may occur. Potential effects of hydraulic fracturing on upward flow through a particular type of leaky abandoned well-abandoned oil and gas wells converted into water wells were investigated using numerical modeling. Several factors that affect flow to leaky wells were considered including proximity of a leaky well to hydraulic fracturing, flowback, production, and leaky well abandonment methods. The numerical model used historical records and available industry data for the Eagle Ford Shale play in south Texas. Numerical simulations indicate that upward contaminant migration could occur through leaky converted wells if certain spatial and hydraulic conditions exist. Upward flow through leaky converted wells increased with proximity to hydraulic fracturing, but decreased when flowback and production occurred. Volumetric flow rates ranged between 0 and 0.086 m 3 /d for hydraulic-fracturing scenarios. Potential groundwater impacts should be paired with plausible transport mechanisms, and upward flow through leaky abandoned wells could be unrelated to hydraulic fracturing. The results also underscore the need to evaluate historical activities. © 2016, National Ground Water Association.

  17. Stigmastane and hopanes as conserved biomarkers for estimating oil biodegradation in a former refinery plant-contaminated soil.

    PubMed

    Gagni, Simona; Cam, Darinn

    2007-05-01

    In the last decade, a refinery plant located in Lido Adriano, East Ravenna (Italy) has been subject to mineral oil contamination. The mineral crude oil, extracted from the offshore in Adriatic sea, consisted of 78% aliphatics, cyclic alkanes and saturated polycyclic hydrocarbons, 9% aromatics, polycyclic aromatic hydrocarbons (PAHs) and alkylated derivatives, and 13% of tars/asphaltenes. Analysis of soil after 10 years of natural attenuation revealed a complete depletion of linear (n-C(9)-C(24)), light aromatics (C1-C3/benzenes) and PAHs (C2/naphthalene, C1/phenanthrene); besides a substantial degradation of isoprenoids prystane and phytane, branched and cyclic alkanes. The remaining contaminants which withstood to natural degradation was saturated polycyclic hydrocarbons (perhydro-PAH derivatives), unsaturated polycyclic hydrocarbons (tetrahydro, dihydro-PAH derivatives), terpanes, steranes and unidentified compounds. Such residues resulted in 80% reduction of its concentration after two months of laboratory treatment. Samples were extracted by organic solvents, separated by silica/alumina gel column chromatography and analyzed by gas chromatography-mass selective detector (GC-MSD). Identification and quantification of aliphatic, cyclic alkanes, typical PAHs, terpanes and steranes were carried out to chromatograms of M/Z=85, 83, individual M/Zs, M/Z=191 and 217, respectively. The present work shows that, among numerous biomarkers present in the source oil, stigmastane and two isomers of hopane showed invariable concentrations after laboratory experiments that mimic natural biodegradation in the field, so they can be used as conserved internal biomarkers. These are very useful tools to assess alterations in less stable classes of saturated compounds contained in petroleum. Marked degradation of perhydro, tetrahydro, dihydro-PAH derivatives in the laboratory treatment has been evidenced.

  18. Analysis of the implementation of ergonomic design at the new units of an oil refinery.

    PubMed

    Passero, Carolina Reich Marcon; Ogasawara, Erika Lye; Baú, Lucy Mara Silva; Buso, Sandro Artur; Bianchi, Marcos Cesar

    2012-01-01

    Ergonomic design is the adaptation of working conditions to human limitations and skills in the physical design phase of a new installation, a new working system, or new products or tools. Based on this concept, the purpose of this work was to analyze the implementation of ergonomic design at the new industrial units of an oil refinery, using the method of Ergonomic Workplace Assessment. This study was conducted by a multidisciplinary team composed of operation, maintenance and industrial safety technicians, ergonomists, designers and engineers. The analysis involved 6 production units, 1 industrial wastewater treatment unit, and 3 utilities units, all in the design detailing phase, for which 455 ergonomic requirements were identified. An analysis and characterization of the requirements identified for 5 of the production units, involving a total of 246 items, indicated that 62% were related to difficult access and blockage operations, while 15% were related to difficulties in the circulation of employees inside the units. Based on these data, it was found that the ergonomic requirements identified in the design detailing phase of an industrial unit involve physical ergonomics, and that it is very difficult to identify requirements related to organizational or cognitive ergonomics.

  19. Challenging the immediate causes: A work accident investigation in an oil refinery using organizational analysis.

    PubMed

    Beltran, Sandra Lorena; Vilela, Rodolfo Andrade de Gouveia; de Almeida, Ildeberto Muniz

    2018-01-01

    In many companies, investigations of accidents still blame the victims without exploring deeper causes. Those investigations are reactive and have no learning potential. This paper aims to debate the historical organizational aspects of a company whose policy was incubating an accident. The empirical data are analyzed as part of a qualitative study of an accident that occurred in an oil refinery in Brazil in 2014. To investigate and analyse this case we used one-to-one and group interviews, participant observation, Collective Analyses of Work and a documentary review. The analysis was conducted on the basis of concepts of the Organizational Analysis of the event and the Model for Analysis and Prevention of Work Accidents. The accident had its origin in the interaction of social and organizational factors, among them being: excessively standardized culture, management tools and outcome indicators that give a false sense of safety, the decision to speed up the project, the change of operator to facilitate this outcome and performance management that encourages getting around the usual barriers. The superficial accident analysis conducted by the company that ignored human and organizational factors reinforces the traditional safety culture and favors the occurrence of new accidents.

  20. Assessment of Heavy and Trace Metals in Surface Soil Nearby an Oil Refinery, Saudi Arabia, Using Geoaccumulation and Pollution Indices.

    PubMed

    Alshahri, Fatimh; El-Taher, A

    2018-04-30

    The present study deals with the measurement of heavy and trace metals in the soils of Ras Tanura city nearby one of the oldest and largest oil refineries located on Arabian Gulf, eastern Saudi Arabia. Metals were analyzed in 34 surface soil samples using plasma atomic emission spectrometer (ICPE-9820). The result showed that the mean values of the metals concentrations were in the order: Cd > Mo > Tb > Ce > Hf > Eu > Yb > U > Sm > Rb > Cr > Ni > Pb > Sc > Cs > Zn > Lu > Co. The mean values of Cd (39.9 mg/kg), Mo (13.2 mg/kg), Eu (4.01 mg/kg), Hf (6.09 mg/kg), Tb (8.23 mg/kg), and Yb (3.88) in soil samples were higher than the background values in soil and the world average. The obtained results indicated to elevated levels of Cd and Mo in most samples, with mean concentrations exceeded the background levels by 113 times for Cd and 5 times for Mo. Pollution index (PI) and Geoaccumulation (I geo ) for each metal were calculated to assess the metal contamination level of surface soil in the study area. The assessment results of PI and I geo revealed a significant pollution by Cd, Mo, Eu, Hf, Tb, and Yb in most of sampling sites nearby Ras Tanura refinery.

  1. Application of stabilization/solidification technology on oil refinery sludge contaminated by heavy metals.

    PubMed

    Karamalidis, Athanasios K; Voudrias, Evangelos A

    2004-01-01

    The oily sludge produced by petroleum refineries is classified as a solid hazardous waste, according to European regulations. The objective of this work was to investigate whether stabilization/solidification can be used as a management method for the oily sludge. The sludge samples used originated from a petroleum-storing tank and a centrifuge unit of two Greek refineries. The experiments were designed to study the leachability of the heavy metals Pb, Cr, Cd, Ni, and Cu, which are contained in the sludge, using the Toxicity Characteristic Leaching Procedure (TCLP). Despite the fact that the metals were immobilized in a cement-based environment in the presence of organic load, leaching tests have shown a low metal leachability, less than 5%. Acid Neutralizing Capacity (ANC) tests were employed in order to estimate the acid resistance of the stabilized/solidified waste. In addition to ANC, a sequential TCLP test was employed in order to understand how the pH affects the leachability of Ni from the stabilized/solidified specimen.

  2. [Occupational exposure to methyl tert-butyl ether (MTBE) at an oil refinery].

    PubMed

    Perbellini, L; Pasini, F; Prigioni, P; Rosina, A

    2003-01-01

    Methyl tert-butyl ether (MTBE) is widely used as an additive to gasoline, to increase oxygen content and reduce tailpipe emission of carbon monoxide. Our research dealt with 37 refinery workers in order to measure their occupational exposure to MTBE during two different seasonal periods. They provided blood and urine samples before and after a work shift during which they wore an active charcoal sampler for solvents. All samples were analysed by a gas-chromatograph equipped with a mass spectrometer detector. The concentration in air of MTBE was very low (median: 25 micrograms/m3 in spring and 5 micrograms/m3 in autumn). The blood and urine concentrations of MTBE at the end of the work shift were higher than those found before the shift. The increment in biological samples confirmed a small intake of MTBE by refinery workers: the biological monitoring of occupational exposure to this solvent yielded reliable results. Blood and urinary concentrations of MTBE obtained from workers split in relation to their smoking habit did not give a statistic significance to say that cigarette smoke is not a confusion factor in monitoring exposure to MTBE.

  3. Computer model for refinery operations with emphasis on jet fuel production. Volume 1: Program description

    NASA Technical Reports Server (NTRS)

    Dunbar, D. N.; Tunnah, B. G.

    1978-01-01

    A FORTRAN computer program is described for predicting the flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuel of varying end point and hydrogen content specifications. The program has provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case.

  4. Optimal Renewable Energy Integration into Refinery with CO2 Emissions Consideration: An Economic Feasibility Study

    NASA Astrophysics Data System (ADS)

    Alnifro, M.; Taqvi, S. T.; Ahmad, M. S.; Bensaida, K.; Elkamel, A.

    2017-08-01

    With increasing global energy demand and declining energy return on energy invested (EROEI) of crude oil, global energy consumption by the O&G industry has increased drastically over the past few years. In addition, this energy increase has led to an increase GHG emissions, resulting in adverse environmental effects. On the other hand, electricity generation through renewable resources have become relatively cost competitive to fossil based energy sources in a much ‘cleaner’ way. In this study, renewable energy is integrated optimally into a refinery considering costs and CO2 emissions. Using Aspen HYSYS, a refinery in the Middle East was simulated to estimate the energy demand by different processing units. An LP problem was formulated based on existing solar energy systems and wind potential in the region. The multi-objective function, minimizing cost as well as CO2 emissions, was solved using GAMS to determine optimal energy distribution from each energy source to units within the refinery. Additionally, an economic feasibility study was carried out to determine the viability of renewable energy technology project implementation to overcome energy requirement of the refinery. Electricity generation through all renewable energy sources considered (i.e. solar PV, solar CSP and wind) were found feasible based on their low levelized cost of electricity (LCOE). The payback period for a Solar CSP project, with an annual capacity of about 411 GWh and a lifetime of 30 years, was found to be 10 years. In contrast, the payback period for Solar PV and Wind were calculated to be 7 and 6 years, respectively. This opens up possibilities for integrating renewables into the refining sector as well as optimizing multiple energy carrier systems within the crude oil industry

  5. 76 FR 72675 - Grant of Authority for Subzone Status, Valero Refining Company-California, (Oil Refinery...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-25

    ... by-products (examiner's report, Appendix ``C''); --products for export; --and, products eligible for...: 1. Foreign status (19 CFR 146.41, 146.42) products consumed as fuel for the refinery shall be...

  6. Linking performance benchmarking of refinery process chemicals to refinery key performance indicators

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cook, J.M.; Nieman, L.D.

    In 1977 Solomon Associates, Inc. issued its first study of refining in the US entitled, Comparative Performance Analysis for Fuel Product Refineries, most commonly referred to as the Solomon Study, or the Fuels Study. In late 1993, both the Water and Waste Water Management, and Petroleum Divisions of Nalco Chemical Company came to the same conclusion; that they must have a better understanding of the Solomon Study process, and have some input to this system of measurement. The authors first approached Solomon Associates with the idea that a specific study should be done of specialty chemicals used in the refinery.more » They felt that this would result in two studies, one for water treatment applications, and one for process. The water treatment study came first, and was completed in 1993 with the United States Petroleum Refineries Water Treatment Performance Analysis for Operating Year 1993. The process study, entitled United States Petroleum Refinery Process Treatment Performance Analysis for Operating Years 1994--95 will be issued in the 2nd quarter of this year by Nalco/Exxon Energy Chemicals, L.P, which includes the combined resources of the former Petroleum Division of Nalco Chemical Company (including the petroleum related portions of most of its overseas companies), and the petroleum related specialty chemical operations of Exxon Chemical on a global basis. What follows is a recap of the process study focus, some examples of output, and comment on both the linkage to key refinery operating indicators, as well as the perception of the effect of such measurement on the supplier relationship of the future.« less

  7. 40 CFR 60.692-3 - Standards: Oil-water separators.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards: Oil-water separators. 60.692... Emissions From Petroleum Refinery Wastewater Systems § 60.692-3 Standards: Oil-water separators. (a) Each oil-water separator tank, slop oil tank, storage vessel, or other auxiliary equipment subject to the...

  8. 40 CFR 60.692-3 - Standards: Oil-water separators.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards: Oil-water separators. 60.692... Emissions From Petroleum Refinery Wastewater Systems § 60.692-3 Standards: Oil-water separators. (a) Each oil-water separator tank, slop oil tank, storage vessel, or other auxiliary equipment subject to the...

  9. 40 CFR 60.692-3 - Standards: Oil-water separators.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards: Oil-water separators. 60.692... Emissions From Petroleum Refinery Wastewater Systems § 60.692-3 Standards: Oil-water separators. (a) Each oil-water separator tank, slop oil tank, storage vessel, or other auxiliary equipment subject to the...

  10. 40 CFR 80.1141 - Small refinery exemption.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Renewable Fuel Standard § 80.1141 Small refinery exemption...)), is exempt from the renewable fuel standards of § 80.1105 and the requirements that apply to obligated... refinery application. The application must contain all of the elements required for small refinery...

  11. Mining machinery/equipment/parts/services. Oil and gas field equipment/machinery/parts/supplies (Ecuador). Refinery equipment, parts, and accessories, March 1991. Export trade information

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-03-01

    The petroleum sector in Ecuador brings in about 65 percent of the country's revenue. Three of the refineries are located in the coastal region. The other two, plus the Liquified Petroleum Gas Plant (LPG), are located in the Oriente region (Amazon jungle). The refineries operate at about 85% of their installation capacity. The Petroindustrial and Petropeninsula investment plan for 1991 comtemplates the expansion of the Esmeraldas refinery to 110,000 barrels a day, and the up-grading of the Shushufindi and Libertad refineries located near the city of Guayaquil. The United States is by far the largest supplier of refinery equipment, partsmore » and accessories, controlling about 90% of the total market.« less

  12. Poland petroleum refinery sludge lagoon demonstration project

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Altman, D.J.

    The US Department of Energy and the Institute for Ecology of Industrial Area have been working together to develop mutually beneficial, cost-effective environmental remediation technologies such as the demonstration of bioremediation techniques for the clean up of acidic petroleum sludge impacted soils at an oil refinery in southern Poland. After an expedited site characterization, treatability study, and a risk assessment study, a remediation strategy was devised. The waste material was composed primarily of high molecular weight paraffinic and polynuclear aromatic hydrocarbons. A biopile design which employed a combination of passive and active aeration in conjunction with nutrient and surfactant applicationmore » as used to increase the biodegradation of the contaminants of concern.« less

  13. The discovery and development of the El Dorado (Kansas) oil field

    USGS Publications Warehouse

    Skelton, L.H.

    1997-01-01

    Pioneers named El Dorado, Kansas, in 1857 for the beauty of the site and the promise of future riches but not until 58 years later was black rather than mythical yellow gold discovered when the Stapleton No. 1 oil well came in on October 5, 1915. El Dorado's leaders were envious when nearby towns found huge gas fields and thrived. John Donley, an El Dorado barber, had tried to find either gas or oil in 1878 at a nearby site selected by a spiritualist. He staked out a townsite, spudded a well and drilled 200 feet before running out of money. Wells in 1879 and 1882 produced only brine. In June, 1914, chafed over discovery of oil in nearby Augusta, El Dorado city fathers contracted with Erasmus Haworth, soon to retire from his position as State Geologist, to perform a geological study of the area. His field work outlined the El Dorado Anticline, which unsuccessfully was drilled first in August, 1915. On abandonment, the Wichita Natural Gas Company purchased the lease and drilled the Stapleton No. 1 oil well. More success followed and by 1918, the El Dorado produced 29 million barrels, almost 9% of the nation's oil. Entrepreneurs came and prospered: the Cities Service Oil Company, A.L. Derby, Jack Vickers, and Bill Skelly all became familiar names in Midcontinent oil marketing. Earlier giant fields had hurt the price of crude oil but the El Dorado came in as both World War I and the rapid popularization of motor transport made a market for both light and heavy ends of the refinery stream. The giant gas field never materialized as hoped but in late 1995, the El Dorado Field produced its 300 millionth barrel of oil.

  14. Use of plants to monitor contamination of air by SO2 in and around refinery.

    PubMed

    Abdul-Wahab, Sabah A; Yaghi, Basma

    2004-01-01

    The generation of SO2 from a refinery may affect the surrounding environment. Moreover, SO2 and its by-products are phytotoxic as berg. This study aims to investigate plant responses to SO2. The work has been designed with emphasis on using the plants directly in monitoring the contamination of the atmospheric air by SO2. An assessment was made of the impacts of long-term SO2 emissions from an oil refinery on plants located in nearby areas that are likely to be exposed to emission fallout. Three different plant species (Prosopis cineraria. Azadirachta indica, and Phoenix dactilifera) common to the environment of the Arabian Gulf were selected at different distances and directions from the refinery. The analysis of the sulphate contents of these plants were used as bioindicators for monitoring SO2 concentration levels in and around the refinery. The results of this study showed that the three different plant species responsed differently to SO2 in terms of their sulphate contents. Generally, all three species were found to be sensitive to SO2 exposure. Furthermore, the concentration of sulphate was found to be much higher closer to the refinery. On the basis of this study, it can be stated that even though SO2 levels were lower than the permissible limit values, the sulphate contents accumulated in the plants were likely to cause plant injury especially in the vicinity of the source. This suggests that the present environmental guidelines for SO2 may not protect sensitive plant species.

  15. Health risk assessments for alumina refineries.

    PubMed

    Donoghue, A Michael; Coffey, Patrick S

    2014-05-01

    To describe contemporary air dispersion modeling and health risk assessment methodologies applied to alumina refineries and to summarize recent results. Air dispersion models using emission source and meteorological data have been used to assess ground-level concentrations (GLCs) of refinery emissions. Short-term (1-hour and 24-hour average) GLCs and annual average GLCs have been used to assess acute health, chronic health, and incremental carcinogenic risks. The acute hazard index can exceed 1 close to refineries, but it is typically less than 1 at neighboring residential locations. The chronic hazard index is typically substantially less than 1. The incremental carcinogenic risk is typically less than 10(-6). The risks of acute health effects are adequately controlled, and the risks of chronic health effects and incremental carcinogenic risks are negligible around referenced alumina refineries.

  16. Devise of an exhaust gas heat exchanger for a thermal oil heater in a palm oil refinery plant

    NASA Astrophysics Data System (ADS)

    Chucherd, Panom; Kittisupakorn, Paisan

    2017-08-01

    This paper presents the devise of an exhaust gas heat exchanger for waste heat recovery of the exhausted flue gas of palm oil refinery plant. This waste heat can be recovered by installing an economizer to heat the feed water which can save the fuel consumption of the coal fired steam boiler and the outlet temperature of flue gas will be controlled in order to avoid the acid dew point temperature and protect the filter bag. The decrease of energy used leads to the reduction of CO2 emission. Two designed economizer studied in this paper are gas in tube and water in tube. The gas in tube exchanger refers to the shell and tube heat exchanger which the flue gas flows in tube; this designed exchanger is used in the existing unit. The new designed water in tube refers to the shell and tube heat exchanger which the water flows in the tube; this designed exchanger is proposed for new implementation. New economizer has the overall coefficient of heat transfer of 19.03 W/m2.K and the surface heat transfer area of 122 m2 in the optimized case. Experimental results show that it is feasible to install economizer in the exhaust flue gas system between the air preheater and the bag filter, which has slightly disadvantage effect in the system. The system can raise the feed water temperature from 40 to 104°C and flow rate 3.31 m3/h, the outlet temperature of flue gas is maintained about 130 °C.

  17. 76 FR 50214 - Mandan, Hidatsa and Arikara (MHA) Nation's Refinery, Notice of Availability of the Record of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-12

    ..., gasoline and propane. The NPDES permit will be for surface water discharges associated with the operation.... Since the FEIS was issued, the MHA Nation decided to change the refinery feedstock from synthetic crude oil to the Bakken formation crude. As a result of the feedstock change, EPA evaluated the potential...

  18. Lung cancer incidence among Norwegian nickel-refinery workers 1953-2000.

    PubMed

    Grimsrud, Tom K; Berge, Steinar R; Martinsen, Jan Ivar; Andersen, Aage

    2003-04-01

    Among workers employed at a nickel refinery in Norway between 1910 and 1977 an elevated risk of lung cancer has been demonstrated. A dose-related effect from nickel exposure has been identified, with the strongest gradient for water-soluble nickel. This pattern was recently confirmed in a nested case-control study with adjustment for smoking and potential occupational confounders. In the present study, updated cancer data were used to explore the risk by duration of work at the refinery and by exposure to different forms of nickel. Comparisons were made with the national male population (standardised incidence ratios) as well as internal reference groups (Poisson regression) under adjustment for age and smoking. The results confirmed earlier findings of a strong dose-related risk dependent on duration of work in production departments and cumulative exposure to nickel, most clearly seen for water-soluble nickel. Only slightly elevated risks were found among the unexposed and in the group with no experience from production or maintenance work. The risk associated with exposure to nickel chloride was similar to that for nickel sulfate. Analyses restricted to men exposed after 1967, with estimates based on personal monitoring of nickel in the breathing zone, showed the same risk pattern as for earlier years. Elevated lung cancer incidence was even suggested for workers with their first employment after 1978 when a lot of high exposure jobs were abandoned. The combined effect of exposure to nickel and smoking seemed to be in agreement with a multiplicative risk pattern.

  19. Use of refinery computer model to predict fuel production

    NASA Technical Reports Server (NTRS)

    Flores, F. J.

    1979-01-01

    Several factors (crudes, refinery operation and specifications) that affect yields and properties of broad specification jet fuel were parameterized using the refinery simulation model which can simulate different types of refineries were used to make the calculations. Results obtained from the program are used to correlate yield as a function of final boiling point, hydrogen content and freezing point for jet fuels produced in two refinery configurations, each one processing a different crude mix. Refinery performances are also compared in terms of energy consumption.

  20. Health Risk Assessments for Alumina Refineries

    PubMed Central

    Coffey, Patrick S.

    2014-01-01

    Objective: To describe contemporary air dispersion modeling and health risk assessment methodologies applied to alumina refineries and to summarize recent results. Methods: Air dispersion models using emission source and meteorological data have been used to assess ground-level concentrations (GLCs) of refinery emissions. Short-term (1-hour and 24-hour average) GLCs and annual average GLCs have been used to assess acute health, chronic health, and incremental carcinogenic risks. Results: The acute hazard index can exceed 1 close to refineries, but it is typically less than 1 at neighboring residential locations. The chronic hazard index is typically substantially less than 1. The incremental carcinogenic risk is typically less than 10−6. Conclusions: The risks of acute health effects are adequately controlled, and the risks of chronic health effects and incremental carcinogenic risks are negligible around referenced alumina refineries. PMID:24806721

  1. Computer model for refinery operations with emphasis on jet fuel production. Volume 3: Detailed systems and programming documentation

    NASA Technical Reports Server (NTRS)

    Dunbar, D. N.; Tunnah, B. G.

    1978-01-01

    The FORTRAN computing program predicts flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuels of varying end point and hydrogen content specifications. The program has a provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case.

  2. Speciations of trace metals in the Danube alluvial sediments within an oil refinery.

    PubMed

    Relić, Dubravka; Dordević, Dragana; Popović, Aleksandar; Blagojević, Tamara

    2005-07-01

    A sequential extraction procedure was applied to identify forms of Ni, Zn, Pb and Cu with Fe- and Mn-oxides associated in alluvial sediments of the River Danube within Pancevo Oil Refinery (Serbia). The five steps of the sequential extraction procedure partitioned metals into: CH(3)COONH(4) extractable (S1); NH(2)OH.HCl carbonate extractable and easily reducible (S2); (NH(4))(2)C(2)O(2)/H(2)C(2)O(2) moderately reducible (S3); H(2)O(2)-HNO(3) organic extractable (S4); and HCl acid soluble residue (S5). Extracted concentrations of trace metals, analyzed after all five steps, were found to be (mg kg(-1)) for Mn: 656, Fe: 26734, Ni: 32.3, Zn: 72.8, Pb: 13.4 and Cu: 27.0. Most of the elements were found in acid soluble residue, characterizing stable compounds in sediments. Non-residual fractions of trace metals (sum of the first four fractions) were analyzed because they are more bioavailable than the residual amount. Correlation analysis and two multivariate analysis methods (principal component and cluster analysis) were used to understand and visualize the associations between the non-residual fractions of trace metals and certain forms, more or less crystalline of Fe- and Mn-oxides within the analyzed sediments, since Fe- and Mn-oxides play an important role in trace metal sorption within aquatic systems, especially within the Danube alluvium where the fluctuations of groundwater are very frequent and the level of groundwater could come close to surface.

  3. Carbon monoxide and methane adsorption of crude oil refinery using activated carbon from palm shells as biosorbent

    NASA Astrophysics Data System (ADS)

    Yuliusman; Afdhol, M. K.; Sanal, Alristo

    2018-03-01

    Carbon monoxide and methane gas are widely present in oil refineries. Off-potential gas is used as raw material for the petrochemical industry. In order for this off-gas to be utilized, carbon monoxide and methane must be removed from off-gas. This study aims to adsorb carbon monoxide and methane using activated carbon of palm shells and commercial activated carbon simultaneously. This research was conducted in 2 stages: 1) Preparation and characterization of activated carbon, 2) Carbon monoxide and methane adsorption test. The activation experiments using carbon dioxide at a flow rate of 150 ml/min yielded a surface area of 978.29 m2/g, Nitrogen at flow rate 150 ml/min yielded surface area 1241.48 m2/g, and carbon dioxide and nitrogen at a flow rate 200 ml/min yielded a surface area 300.37 m2/g. Adsorption of carbon monoxide and methane on activated carbon of palm shell systems yielded results in the amount of 0.5485 mg/g and 0.0649 mg/g and using commercial activated carbon yielded results in the amount of 0.5480 mg/g and 0.0650 mg/g

  4. Oil

    USGS Publications Warehouse

    Rocke, T.E.

    1999-01-01

    Each year, an average of 14 million gallons of oil from more than 10,000 accidental spills flow into fresh and saltwater environments in and around the United States. Most accidental oil spills occur when oil is transported by tankers or barges, but oil is also spilled during highway, rail, and pipeline transport, and by nontransportation-related facilities, such as refinery, bulk storage, and marine and land facilities (Fig. 42.1). Accidental releases, however, account for only a small percentage of all oil entering the environment; in heavily used urban estuaries, the total petroleum hydrocarbon contributions due to transportation activities may be 10 percent or less. Most oil is introduced to the environment by intentional discharges from normal transport and refining operations, industrial and municipal discharges, used lubricant and other waste oil disposal, urban runoff, river runoff, atmospheric deposition, and natural seeps. Oil-laden wastewater is often released into settling ponds and wetlands (Fig. 42.2). Discharges of oil field brines are a major source of the petroleum crude oil that enters estuaries in Texas.

  5. Slides for Petroleum Refinery Fenceline Monitoring Data

    EPA Pesticide Factsheets

    These webinars provided an overview of EPA’s 2015 rule to reduce air emissions from petroleum refineries and solicit input on how to display the information collected from fenceline monitors at refineries.

  6. Computer model for refinery operations with emphasis on jet fuel production. Volume 2: Data and technical bases

    NASA Technical Reports Server (NTRS)

    Dunbar, D. N.; Tunnah, B. G.

    1978-01-01

    The FORTRAN computing program predicts the flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuel of varying end point and hydrogen content specifications. The program has provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case. The report has sufficient detail for the information of most readers.

  7. Classification of diesel pool refinery streams through near infrared spectroscopy and support vector machines using C-SVC and ν-SVC.

    PubMed

    Alves, Julio Cesar L; Henriques, Claudete B; Poppi, Ronei J

    2014-01-03

    The use of near infrared (NIR) spectroscopy combined with chemometric methods have been widely used in petroleum and petrochemical industry and provides suitable methods for process control and quality control. The algorithm support vector machines (SVM) has demonstrated to be a powerful chemometric tool for development of classification models due to its ability to nonlinear modeling and with high generalization capability and these characteristics can be especially important for treating near infrared (NIR) spectroscopy data of complex mixtures such as petroleum refinery streams. In this work, a study on the performance of the support vector machines algorithm for classification was carried out, using C-SVC and ν-SVC, applied to near infrared (NIR) spectroscopy data of different types of streams that make up the diesel pool in a petroleum refinery: light gas oil, heavy gas oil, hydrotreated diesel, kerosene, heavy naphtha and external diesel. In addition to these six streams, the diesel final blend produced in the refinery was added to complete the data set. C-SVC and ν-SVC classification models with 2, 4, 6 and 7 classes were developed for comparison between its results and also for comparison with the soft independent modeling of class analogy (SIMCA) models results. It is demonstrated the superior performance of SVC models especially using ν-SVC for development of classification models for 6 and 7 classes leading to an improvement of sensitivity on validation sample sets of 24% and 15%, respectively, when compared to SIMCA models, providing better identification of chemical compositions of different diesel pool refinery streams. Copyright © 2013 Elsevier B.V. All rights reserved.

  8. Occupational exposure to benzene at the ExxonMobil refinery in Baytown, TX (1978-2006).

    PubMed

    Gaffney, Shannon H; Panko, Julie M; Unice, Ken M; Burns, Amanda M; Kreider, Marisa L; Gelatt, Richard H; Booher, Lindsay E; Paustenbach, Dennis J

    2011-01-01

    Although occupational benzene exposure of refinery workers has been studied for decades, no extensive analysis of historical industrial hygiene data has been performed focusing on airborne concentrations at specific refineries and tasks. This study characterizes benzene exposures at the ExxonMobil Baytown, TX, refinery from 1978 to 2006 to understand the variability in workers' exposures over time and during different job tasks. Exposures were grouped by operational status, job title, and tasks. More than 9000 industrial hygiene air samples were evaluated; approximately 4000 non-task (> 3 h) and 1000 task-related (< 3 h) personal samples were considered. Each sample was assigned to one of 27 job titles, 29 work areas, and 16 task bins (when applicable). Process technicians were sampled most frequently, resulting in the following mean benzene concentrations by area: hydrofiner (n=245, mean=1.3 p.p.m.), oil movements (n=286, mean=0.23 p.p.m.), reformer (n=575, mean=0.10 p.p.m.), tank farm (n=9, mean=0.65 p.p.m.), waste treatment (n=446, mean=0.13 p.p.m.), and other areas (n=460, mean=0.062 p.p.m.). The most frequently sampled task was sample collection (n=218, mean=0.40 p.p.m.). Job title and area did not significantly impact task-related exposures. Airborne concentrations were significantly lower after 1990 than before 1990. Results of this task-focused study may be useful when analyzing benzene exposures at other refineries.

  9. 30 CFR 944.20 - Approval of Utah abandoned mine plan.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) Division of Oil, Gas and Mining, Department of Natural Resources, 3 Triad Center, Suite 350, 355 West North... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Approval of Utah abandoned mine plan. 944.20... INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE UTAH § 944.20 Approval of...

  10. 30 CFR 944.20 - Approval of Utah abandoned mine plan.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) Division of Oil, Gas and Mining, Department of Natural Resources, 3 Triad Center, Suite 350, 355 West North... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Approval of Utah abandoned mine plan. 944.20... INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE UTAH § 944.20 Approval of...

  11. 30 CFR 944.20 - Approval of Utah abandoned mine plan.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) Division of Oil, Gas and Mining, Department of Natural Resources, 3 Triad Center, Suite 350, 355 West North... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of Utah abandoned mine plan. 944.20... INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE UTAH § 944.20 Approval of...

  12. 30 CFR 944.20 - Approval of Utah abandoned mine plan.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) Division of Oil, Gas and Mining, Department of Natural Resources, 3 Triad Center, Suite 350, 355 West North... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Approval of Utah abandoned mine plan. 944.20... INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE UTAH § 944.20 Approval of...

  13. 30 CFR 944.20 - Approval of Utah abandoned mine plan.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) Division of Oil, Gas and Mining, Department of Natural Resources, 3 Triad Center, Suite 350, 355 West North... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Approval of Utah abandoned mine plan. 944.20... INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE UTAH § 944.20 Approval of...

  14. Health Risk Assessment for Exposure to Benzene in Petroleum Refinery Environments

    PubMed Central

    Edokpolo, Benjamin; Yu, Qiming Jimmy; Connell, Des

    2015-01-01

    The health risk resulting from benzene exposure in petroleum refineries was calculated using data from the scientific literature from various countries throughout the world. The exposure data was collated into four scenarios from petroleum refinery environments and plotted as cumulative probability distributions (CPD) plots. Health risk was evaluated for each scenario using the Hazard Quotient (HQ) at 50% (CEXP50) and 95% (CEXP95) exposure levels. Benzene levels were estimated to pose a significant risk with HQ50 > 1 and HQ95 > 1 for workers exposed to benzene as base estimates for petroleum refinery workers (Scenario 1), petroleum refinery workers evaluated with personal samplers in Bulgarian refineries (Scenario 2B) and evaluated using air inside petroleum refineries in Bulgarian refineries (Scenario 3B). HQ50 < 1 were calculated for petroleum refinery workers with personal samplers in Italian refineries (Scenario 2A), air inside petroleum refineries (Scenario 3A) and air outside petroleum refineries (Scenario 4) in India and Taiwan indicating little possible adverse health effects. Also, HQ95 was < 1 for Scenario 4 however potential risk was evaluated for Scenarios 2A and 3A with HQ95 > 1. The excess Cancer risk (CR) for lifetime exposure to benzene for all the scenarios was evaluated using the Slope Factor and Overall Risk Probability (ORP) methods. The result suggests a potential cancer risk for exposure to benzene in all the scenarios. However, there is a higher cancer risk at 95% (CEXP95) for petroleum refinery workers (2B) with a CR of 48,000 per 106 and exposure to benzene in air inside petroleum refineries (3B) with a CR of 28,000 per 106. PMID:25588154

  15. Suitability of Scirpus maritimus for petroleum hydrocarbons remediation in a refinery environment.

    PubMed

    Couto, M Nazaré P F S; Basto, M Clara P; Vasconcelos, M Teresa S D

    2012-01-01

    In the ambit of a project searching for appropriate biological approaches for recovering a refinery soil contaminated with petroleum hydrocarbons (PHC), we compared results obtained in the absence and in the presence of the salt marsh plant Scirpus maritimus or Juncus maritimus or an association of these two plants, which were tested in the refinery environment. Synergistic effects caused by addition of a non-ionic surfactant and/or a bioaugmentation product were also investigated. Major challenges of this study were: field conditions and weathered contamination. Transplants of the plants were carried out in individual containers filled with a weathered contaminated soil, which was recontaminated with turbine oil with two purposes: for increasing PHC level and allowing a comparison of the potential of plants for remediation of ancient and recent contamination. Analysis of total PHC led to the conclusion that, after 24-month exposure, neither J. maritimus nor the association caused any improvement in remediation. In contrast, S. maritimus revealed potential for PHC remediation, favoring degradation of both recent and older contamination (which was refractory to natural attenuation). About 15% of remediation improvement was found in the soil layer with higher root density (5-10 cm). A more marked improvement in that layer (28%) was observed when non-ionic surfactant amendment and bioaugmentation were used jointly. The fact that S. maritimus has demonstrated capability for PHC remediation, leads to admit that it has potential to be also used for recovering sediments that have suffered accidental oil spills.

  16. Cement-based stabilization/solidification of oil refinery sludge: Leaching behavior of alkanes and PAHs.

    PubMed

    Karamalidis, Athanasios K; Voudrias, Evangelos A

    2007-09-05

    Stabilization/solidification is a process widely applied for the immobilization of inorganic constituents of hazardous wastes, especially for metals. Cement is usually one of the most common binders for that purpose. However, limited results have been presented on immobilization of hydrocarbons in cement-based stabilized/solidified petroleum solid waste. In this study, real oil refinery sludge samples were stabilized and solidified with various additions of I42.5 and II42.5 cement (Portland and blended cement, respectively) and subject to leaching. The target analytes were total petroleum hydrocarbons, alkanes and 16 polycyclic aromatic hydrocarbons of the EPA priority pollutant list. The experiments showed that the waste was confined in the cement matrix by macroencapsulation. The rapture of the cement structure led to the increase of leachability for most of the hydrocarbons. Leaching of n-alkanes from II42.5 cement-solidified samples was lower than that from I42.5 solidified samples. Leaching of alkanes in the range of n-C(10) to n-C(27) was lower than that of long chain alkanes (>n-C(27)), regardless the amount of cement addition. Generally, increasing the cement content in the solidified waste samples, increased individual alkane leachability. This indicated that cement addition resulted in destabilization of the waste. Addition of I42.5 cement favored immobilization of anthracene, benzo[a]anthracene, benzo[b]fluoroanthene, benzo[k]fluoroanthene, benzo[a]pyrene and dibenzo[a,h]anthracene. However, addition of II42.5 favored 5 out of 16, i.e., naphthalene, anthracene, benzo[b]fluoroanthene, benzo[k]fluoroanthene and dibenzo[a,h]anthracene.

  17. Energy systems research and development for petroleum refineries

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Robertson, J.L.

    1982-08-01

    For the past several years, Exxon Reasearch and Engineering has carried out a specific RandD program aimed at improving refinery energy efficiency through optimization of energy systems. Energy systems include: steam/power systems, heat exchange systems including hot oil and hot water belts and fuel systems, as well as some of the processes. This paper will describe the three major thrusts of this program which are: development of methods to support Site Energy Survey activities; development of energy management methods; and energy system optimization, which includes development of consistent, realistic, economic incentives for energy system improvements. Project selection criteria will alsomore » be discussed. The technique of a site energy survey will also be described briefly.« less

  18. Updated estimation of energy efficiencies of U.S. petroleum refineries.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Palou-Rivera, I.; Wang, M. Q.

    2010-12-08

    Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels suchmore » as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.« less

  19. Implications of Increasing Light Tight Oil Production for U.S. Refining

    EIA Publications

    2015-01-01

    EIA retained Turner, Mason & Company to provide analysis of the implications of increasing domestic light tight oil production for U.S. refining, focusing on regional crude supply/demand balances, refinery crude slates, operations, capital investment, product yields, crude oil exports/imports, petroleum product exports, infrastructure constraints and expansions, and crude oil price relationships.

  20. Refinery suppliers face tough times

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rotman, D.; Walsh, K.

    1997-03-12

    Despite a handful of bright spots in hydroprocessing and petrochemical sectors, economic woes plague much of the refinery and petrochemical catalysts business, as suppliers are feeling the impact of mature markets and refiners` ongoing cost cutting. Industry experts say the doldrums could spur further restructuring in the catalyst business, with suppliers scrambling for market share and jockeying for position in growing sectors. Expect further consolidation over the next several years, says Pierre Bonnifay, president of IFP Enterprises (New York). {open_quotes}There are still too many players for the mature [refinery catalyst] markets.{close_quotes} Others agree. {open_quotes}Only about seven [or] eight major suppliersmore » will survive,{close_quotes} says Robert Allsmiller, v.p./refinery and petrochemical catalysts at United Catalysts Inc. (UCI; Louisville, KY). {open_quotes}Who they [will be] is still up in the air.{close_quotes}« less

  1. Explosives remain preferred methods for platform abandonment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pulsipher, A.; Daniel, W. IV; Kiesler, J.E.

    1996-05-06

    Economics and safety concerns indicate that methods involving explosives remain the most practical and cost-effective means for abandoning oil and gas structures in the Gulf of Mexico. A decade has passed since 51 dead sea turtles, many endangered Kemp`s Ridleys, washed ashore on the Texas coast shortly after explosives helped remove several offshore platforms. Although no relationship between the explosions and the dead turtles was ever established, in response to widespread public concern, the US Minerals Management Service (MMS) and National Marine Fisheries Service (NMFS) implemented regulations limiting the size and timing of explosive charges. Also, more importantly, they requiredmore » that operators pay for observers to survey waters surrounding platforms scheduled for removal for 48 hr before any detonations. If observers spot sea turtles or marine mammals within the danger zone, the platform abandonment is delayed until the turtles leave or are removed. However, concern about the effects of explosives on marine life remains.« less

  2. 40 CFR 80.94 - Requirements for gasoline produced at foreign refineries.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Requirements for gasoline produced at... for gasoline produced at foreign refineries. (a) Definitions. (1) A foreign refinery is a refinery... definition of refiner under § 80.2(i) for foreign refinery. (3) FRGAS means gasoline produced at a foreign...

  3. 40 CFR 80.94 - Requirements for gasoline produced at foreign refineries.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Requirements for gasoline produced at... for gasoline produced at foreign refineries. (a) Definitions. (1) A foreign refinery is a refinery... definition of refiner under § 80.2(i) for foreign refinery. (3) FRGAS means gasoline produced at a foreign...

  4. 40 CFR 80.94 - Requirements for gasoline produced at foreign refineries.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Requirements for gasoline produced at... for gasoline produced at foreign refineries. (a) Definitions. (1) A foreign refinery is a refinery... definition of refiner under § 80.2(i) for foreign refinery. (3) FRGAS means gasoline produced at a foreign...

  5. MERCURY IN CRUDE OIL PROCESSED IN THE UNITED STATES (2004)

    EPA Science Inventory

    The mean and range of concentrations of mercury in crude oil processed in the U.S. were investigated using two analytical methods. The sample ensemble consisted of 329 samples from 170 separate crude oil streams that are processed by U.S. refineries. Samples were retrieved imme...

  6. VOCs emission rate estimate for complicated industrial area source using an inverse-dispersion calculation method: A case study on a petroleum refinery in Northern China.

    PubMed

    Wei, Wei; Lv, Zhaofeng; Yang, Gan; Cheng, Shuiyuan; Li, Yue; Wang, Litao

    2016-11-01

    This study aimed to apply an inverse-dispersion calculation method (IDM) to estimate the emission rate of volatile organic compounds (VOCs) for the complicated industrial area sources, through a case study on a petroleum refinery in Northern China. The IDM was composed of on-site monitoring of ambient VOCs concentrations and meteorological parameters around the source, calculation of the relationship coefficient γ between the source's emission rate and the ambient VOCs concentration by the ISC3 model, and estimation of the actual VOCs emission rate from the source. Targeting the studied refinery, 10 tests and 8 tests were respectively conducted in March and in June of 2014. The monitoring showed large differences in VOCs concentrations between background and downwind receptors, reaching 59.7 ppbv in March and 248.6 ppbv in June, on average. The VOCs increases at receptors mainly consisted of ethane (3.1%-22.6%), propane (3.8%-11.3%), isobutane (8.5%-10.2%), n-butane (9.9%-13.2%), isopentane (6.1%-12.9%), n-pentane (5.1%-9.7%), propylene (6.1-11.1%) and 1-butylene (1.6%-5.4%). The chemical composition of the VOCs increases in this field monitoring was similar to that of VOCs emissions from China's refineries reported, which revealed that the ambient VOCs increases were predominantly contributed by this refinery. So, we used the ISC3 model to create the relationship coefficient γ for each receptor of each test. In result, the monthly VOCs emissions from this refinery were calculated to be 183.5 ± 89.0 ton in March and 538.3 ± 281.0 ton in June. The estimate in June was greatly higher than in March, chiefly because the higher environmental temperature in summer produced more VOCs emissions from evaporation and fugitive process of the refinery. Finally, the VOCs emission factors (g VOCs/kg crude oil refined) of 0.73 ± 0.34 (in March) and 2.15 ± 1.12 (in June) were deduced for this refinery, being in the same order with previous direct

  7. Recovering selenium from copper refinery slimes

    NASA Astrophysics Data System (ADS)

    Hyvärinen, Olli; Lindroos, Leo; Yllö, Erkki

    1989-07-01

    The selenium contained within copper refinery slimes may be recovered advantageously by roasting at about 600°C. While roasting in air is inefficient, roasting in a sulfating atmosphere enables practically complete selenium recovery. Based on laboratory tests, a new selenium recovery process was adopted at Outokumpu Copper Refinery. In this process, sulfation is achieved by feeding sulfur dioxide and oxygen into the roasting furnace.

  8. Oil turmoil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1979-07-01

    A review of US oil production, refining, and retailing reveals the severity of the energy problem and illustrates the confusion over what can be accomplished by decontrolling oil prices. Conflicting statements from members of Congress, the President, and the oil industry have further confused the public. The shortages can be traced to a decline in domestic production incentives and foreign production, a slowdown in refinery expansion because of environmental constraints, competition between home heating oil and gasoline for priority, the failure of states to enforce speed limits, and a national preoccupation with oil profits. Senator Kennedy, for example, advocates continuedmore » price controls with a world-wide drilling program funded by the World Bank, while decontrol advocates feel price controls will only artifically restrain US production. The economic effects of decontrol on inflation are unclear, but conservation efforts, the development of alternative energy sources, and oil development from shale and tar sands are predicted to increase as political rhetoric declines.« less

  9. Impacts of the Venezuelan Crude Oil Production Loss

    EIA Publications

    2003-01-01

    This assessment of the Venezuelan petroleum loss examines two areas. The first part of the analysis focuses on the impact of the loss of Venezuelan crude production on crude oil supply for U.S. refiners who normally run a significant fraction of Venezuelan crude oil. The second part of the analysis looks at the impact of the Venezuelan production loss on crude markets in general, with particular emphasis on crude oil imports, refinery crude oil throughput levels, stock levels, and the changes in price differences between light and heavy crude oils.

  10. 40 CFR 80.1441 - Small refinery exemption.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Renewable Fuel Standard § 80.1441 Small refinery exemption... § 80.1465(a)), is exempt from January 1, 2010 through December 31, 2010 from the renewable fuel... effective upon approval, by EPA, of a small refinery application. The application must contain all of the...

  11. 40 CFR 80.1280 - How are refinery benzene baselines calculated?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false How are refinery benzene baselines... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Averaging, Banking and Trading (abt) Program § 80.1280 How are refinery benzene baselines calculated? (a) A refinery's benzene...

  12. 40 CFR 80.1280 - How are refinery benzene baselines calculated?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false How are refinery benzene baselines... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Averaging, Banking and Trading (abt) Program § 80.1280 How are refinery benzene baselines calculated? (a) A refinery's benzene...

  13. 40 CFR 80.1280 - How are refinery benzene baselines calculated?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How are refinery benzene baselines... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Averaging, Banking and Trading (abt) Program § 80.1280 How are refinery benzene baselines calculated? (a) A refinery's benzene...

  14. 40 CFR 80.1280 - How are refinery benzene baselines calculated?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false How are refinery benzene baselines... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Averaging, Banking and Trading (abt) Program § 80.1280 How are refinery benzene baselines calculated? (a) A refinery's benzene...

  15. 40 CFR 80.1280 - How are refinery benzene baselines calculated?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false How are refinery benzene baselines... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Averaging, Banking and Trading (abt) Program § 80.1280 How are refinery benzene baselines calculated? (a) A refinery's benzene...

  16. Maritime industry : as U.S. single-hull oil vessels are eliminated, few double-hull vessels may replace them

    DOT National Transportation Integrated Search

    2000-04-01

    Ships and barges are a major link in the country's oil transportation network, both for transporting crude oil to U.S. refineries and for transporting refined oil products to market. The Oil Pollution Act of 1990 made extensive changes designed to ma...

  17. Development of Bio-Oil Commodity Fuel as a Refinery Feedstock from High Impact Algae Biomass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kastner, James; Mani, Sudhagar; Das, K. C.

    A two-stage hydrothermal liquefaction (HTL) process was developed to 1) reduce nitrogen levels in algal oil, 2) generate a nitrogen rich stream with limited inhibitors for recycle and algae cultivation, and 3) improve downstream catalytic hydrodenitrogenation and hydrodeoxygenation of the algal oil to refinery intermediates. In the first stage, low temperature HTL was conducted at 125, 175, and 225°C at holding times ranging from 1 to 30 min (time at reaction temperature). A consortium of three algal strains, namely Chlorella sorokiniana, Chlorella minutissima, and Scenedesmus bijuga were used to grow and harvest biomass in a raceway system – this consortiummore » is called the UGA Raceway strain throughout the report. Subsequent analysis of the final harvested product indicated that only two strains predominated in the final harvest - Chlorella sorokiniana and Scenedesmus bijuga. Two additional strains representing a high protein (Spirulina platensis) and high lipid algae (Nannochloropsis) strains were also used in this study. These strains were purchased from suppliers. S. platensis biomass was provided by Earthrise Nutritionals LLC (Calipatria, CA) in dry powder form with defined properties, and was stored in airtight packages at 4°C prior to use. A Nannochloropsis paste from Reed Mariculture was purchased and used in the two-stage HTL/HDO experiments. The solids and liquids from this low temperature HTL pretreatment step were separated and analyzed, leading to the following conclusions. Overall, these results indicate that low temperature HTL (200-250°C) at short residence times (5-15 min) can be used to lyse algae cells and remove/separate protein and nitrogen before subsequent higher temperature HTL (for lipid and other polymer hydrolysis) and HDO. The significant reduction in nitrogen when coupled with low protein/high lipid algae cultivation methods at scale could significantly improve downstream catalytic HDO results. However, significant barriers

  18. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1981-03-01

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project ismore » economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.« less

  19. Nickel refinery dust

    Integrated Risk Information System (IRIS)

    Nickel refinery dust ; no CASRN Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogenic Effect

  20. Oil Fires in Libya

    NASA Image and Video Library

    2016-01-28

    The oil refinery fires in Libya that were started by attacks on oil terminals in Libya in very early January continue. The stream of black smoke that emanates from the refinery has grown tremendously as the fires caused by the initial shelling have spread to giant storage tanks. These fires are reported to be raging in Sidra, on the coast between Sirte and Benghazi. Actively burning areas, detected by MODIS’s thermal bands, are outlined in red. The initial image of the fires taken on January 07, 2016 can be found here for comparison: www.nasa.gov/image-feature/goddard/2016/terra-captures-im... NASA image courtesy Jeff Schmaltz, MODIS Rapid Response Team NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

  1. Calibration and verification of models of organic carbon removal kinetics in Aerated Submerged Fixed-Bed Biofilm Reactors (ASFBBR): a case study of wastewater from an oil-refinery.

    PubMed

    Trojanowicz, Karol; Wójcik, Włodzimierz

    2011-01-01

    The article presents a case-study on the calibration and verification of mathematical models of organic carbon removal kinetics in biofilm. The chosen Harremöes and Wanner & Reichert models were calibrated with a set of model parameters obtained both during dedicated studies conducted at pilot- and lab-scales for petrochemical wastewater conditions and from the literature. Next, the models were successfully verified through studies carried out utilizing a pilot ASFBBR type bioreactor installed in an oil-refinery wastewater treatment plant. During verification the pilot biofilm reactor worked under varying surface organic loading rates (SOL), dissolved oxygen concentrations and temperatures. The verification proved that the models can be applied in practice to petrochemical wastewater treatment engineering for e.g. biofilm bioreactor dimensioning.

  2. Passive soil gas technique for investigating soil and groundwater plume emanating from volatile organic hydrocarbon at Bazian oil refinery site.

    PubMed

    Hamamin, Dara Faeq

    2018-05-01

    The current work is an attempt to illustrate the importance of using passive soil gas as an innovative investigation technique in the assessment of soil and groundwater pollutions that emanates from volatile hydrocarbon activities in newly emerging countries. Bazian Oil Refinery as one of the largest refinery in Iraqi Kurdistan Region produces 40,000 barrels a day and provides a wide range of petroleum products for daily consumption. The types and scale of different process that happen in this industrial site have led to concerns with regard to its impact on both the soil and groundwater the vicinity of the factory. The researcher conducted a combined sampling design with a dual-phased extraction procedure for soil vapor and groundwater samples in order to assess the susceptibility of the subsurface to pollution with hydrocarbon. The aims were to characterize potential source(s), map the areal extent of the site which is at risk to be affected with the identified9 hydrocarbon compounds and vapor. A collection kit from Beacon Environmental Service was used to collect a total number of 50 passive soil vapors in the first step of work. To extrapolate results, five shallow boring for soils and six for water sampling were carefully observed. The selection of the sampling points was based on the results revealed by the PSG survey that showed significant quantities of analyzed organic hydrocarbon for a follow-up investigation. The matrices were analyzed by ALS Laboratory to target more than 40 VOCs and SVOCs. The plan was to make the mass to concentration tie-in for the selected analyzed compounds (Benzene, Toluene, and Total Petroleum Hydrocarbons) from the PSG in mass (nanograms) with both the soil and water samples in concentration. The results revealed that the PSG technique is unique in identifying the source and extent of soil and groundwater pollutions plume. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Catalytic cracking of fast and tail gas reactive pyrolysis bio-oils over HZSM-5

    USDA-ARS?s Scientific Manuscript database

    While hydrodeoxygenation (HDO) of pyrolysis oil is well understood as an upgrading method, the high processing pressures associated with it alone justify the exploration of alternative upgrading solutions, especially those that could adapt pyrolysis oils into the existing refinery infrastructure. Ca...

  4. We Took on the Oil Giant: Good Night, Goliath.

    ERIC Educational Resources Information Center

    Dombrowski, Richard J.

    1988-01-01

    The small school district of Channahon, Illinois challenged the assessed valuation of a local oil refinery, won the appeal, and negotiated a settlement with the company to stabilize the assessed valuation through 1990. (MLF)

  5. Community reappraisal of the perceived health effects of a petroleum refinery.

    PubMed

    Luginaah, Isaac N; Taylor, S Martin; Elliott, Susan J; Eyles, John D

    2002-07-01

    This paper presents results from a study of the community health impacts of a petroleum refinery in Oakville, Ontario in Canada. The research is informed by the environmental stress and coping literatures and the focus is on community reappraisal of the refinery's impacts before and after the implementation of a substantive odour reduction initiative on the part of the refinery operators. Community health surveys were conducted in 1992 (n = 391) and 1997 (n = 427) to examine changes in odour perception and annoyance and self-reported health status attributable to the odour reduction plan. The findings reported here suggest an on-going process of cognitive reappraisal, whereby negative perceptions and concerns decreased between 1992 and 1997. Irrespective of this positive reappraisal of the refinery efforts, those living close to the refinery continue to report negative health impacts. A strong mediating effect of odours on the refinery exposure-symptom reporting relationship was confirmed by our results. While the relationship between odour perception and symptom reporting indicates the importance of odour perception and annoyance as the principal mechanism mediating ill-health reporting, the plausibility of other causal pathways is recognized. Residents' sensitivity to the negative effects of the refinery on their health and the health of their children suggests a psychosocial reaction to the environmental stress associated with perceived and actual refinery emissions.

  6. A Review of the Pollution Abatement Programs Relating to the Petroleum Refinery Industry in the Great Lakes Basin

    DTIC Science & Technology

    1982-11-01

    of spent acids and caustics . The oil content of disposed wastes is 6,200 metric tons per year or approximately .01% of the average crude refinery rate...ALKYLATION "The major discharge from sulfuric acid alkylation are the spent caustics from the neutralization of hydrocarbon streams leaving the sulfuric... spent caustic waste stream. Any leaks or spills that involve loss of fluorides constitute a serious and difficult pollution problem. Formation of

  7. Ghana refinery expansion and modernization project. Export trade information

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1990-11-01

    The U.S. Trade and Development Program (TDP) is considering the provision of funds to the Ghanaian Ministry of Fuel and Power (MFP) to conduct a study of the scope and feasibility of expanding and modernizing its Tema Refinery to meet future demands for gasoline and to minimize heavy fuel oil production. All of the needed licensed process technology and process know-how could be provided by U.S. sources and this, coupled with U.S. equipment and catalyst supply, meets the TDP criteria for funding the feasibility study. Europe aggressively offers alternate licensable technology for some of the processes. U.S. manufacturers of specialtymore » equipment are marginally competitive in the international market, where competition is fierce. The Definitional Mission recommends that full feasibility study be undertaken.« less

  8. 40 CFR 80.295 - How is a refinery sulfur baseline determined?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How is a refinery sulfur baseline... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Abt Program-Baseline Determination § 80.295 How is a refinery sulfur baseline determined? (a) A refinery's gasoline sulfur baseline...

  9. 40 CFR 80.295 - How is a refinery sulfur baseline determined?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false How is a refinery sulfur baseline... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Abt Program-Baseline Determination § 80.295 How is a refinery sulfur baseline determined? (a) A refinery's gasoline sulfur baseline...

  10. 40 CFR 80.295 - How is a refinery sulfur baseline determined?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false How is a refinery sulfur baseline... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Abt Program-Baseline Determination § 80.295 How is a refinery sulfur baseline determined? (a) A refinery's gasoline sulfur baseline...

  11. 40 CFR 80.295 - How is a refinery sulfur baseline determined?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false How is a refinery sulfur baseline... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Abt Program-Baseline Determination § 80.295 How is a refinery sulfur baseline determined? (a) A refinery's gasoline sulfur baseline...

  12. 40 CFR 80.295 - How is a refinery sulfur baseline determined?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false How is a refinery sulfur baseline... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Sulfur Abt Program-Baseline Determination § 80.295 How is a refinery sulfur baseline determined? (a) A refinery's gasoline sulfur baseline...

  13. Removal of Free Fatty Acid from Plant Oil by the Adsorption Process

    NASA Astrophysics Data System (ADS)

    Chung, Tsair-Wang; Wu, Yi-Ling; Hsu, Shih-Hong

    2018-05-01

    The food oil refinery process for deacidification is ususally conducted by the neutralization after degumming. In this study, commercialized resins will be used as adsorbents to remove the free fatty acid (FFA) in food oil without using any solvent. Applying this environmental friendly green process, the energy efficiency will be increased and the waste water will be reduced compared to the traditional process. The selected adsorbent can be reused which may reduce the process cost. Instead of using alkali neutralization, the proposed process may reduce the concern of food oil security. The commercial resins A26OH and IRA900Cl were compared as adsorbents to remove the FFA in deacidification for refinery of food oil without adding any alkali chemicals. This process will be conducted to remove the FFA form peanut oil in this study. Besides, this study will get the adsorption isotherms for one of the better sorbents of A26OH or IRA900Cl to remove FFA from peanut oil under 25, 35, and 45°C. The Langmuir and Freundlich isotherm models were compared to fit the experimental data. The obtained isotherm data is important for the adsorption system design.

  14. 19 CFR Appendix to Part 146 - Guidelines for Determining Producibility and Relative Values for Oil Refinery Zones

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Producibility Showing Manufacturing Periods From Admission t o Removal Within a Calender Month. Volume losses and gains accounted for by weight. Day 1 Receipt into the refinery subzone during a 30-day month: 50... 50,000 pounds of aviation gasoline. The period of manufacture for the aviation gasoline is Day 1 to...

  15. 19 CFR Appendix to Part 146 - Guidelines for Determining Producibility and Relative Values for Oil Refinery Zones

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Producibility Showing Manufacturing Periods From Admission t o Removal Within a Calender Month. Volume losses and gains accounted for by weight. Day 1 Receipt into the refinery subzone during a 30-day month: 50... 50,000 pounds of aviation gasoline. The period of manufacture for the aviation gasoline is Day 1 to...

  16. 19 CFR Appendix to Part 146 - Guidelines for Determining Producibility and Relative Values for Oil Refinery Zones

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... Producibility Showing Manufacturing Periods From Admission to Removal Within a Calendar Month. Volume losses and gains accounted for by weight. Day 1 Receipt into the refinery subzone during a 30-day month: 50,000... pounds of aviation gasoline. The period of manufacture for the aviation gasoline is Day 1 to Day 10. The...

  17. Abandoning wells working group

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    The primary objective of this working group is to identify major technical, regulatory, and environmental issues that are relevant to the abandonment of offshore wellbores. Once the issues have been identified, the working group also has the objective of making recommendations or providing potential solutions for consideration. Areas for process improvement will be identified and {open_quotes}best practices{close_quotes} will be discussed and compared to {open_quotes}minimum standards.{close_quotes} The working group will primarily focus on wellbore abandonment in the Gulf of Mexico. However, workshop participants are encouraged to discuss international issues which may be relevant to wellbore abandonment practices in the Gulf ofmore » Mexico. The Abandoning Wells Group has identified several major areas for discussion that have concerns related to both operators and service companies performing wellbore abandonments in the Gulf of Mexico. The following broad topics were selected for the agenda: (1) MMS minimum requirements and state regulations. (2) Co-existence of best practices, new technology, and P & A economics. (3) Liability and environmental issues relating to wellbore abandonment.« less

  18. An experiment of used palm oil refinery using the value engineering method

    NASA Astrophysics Data System (ADS)

    Sumiati; Waluyo, M.

    2018-01-01

    Palm Oil is one of prime materials which very necessary for Indonesia. In the development of palm oil industry the constraint which faced is raw material availability and the economic crisis that attack Indonesia which cause increasing of cost industry so that the salaes price become very expensive . With using alternative raw material namely used palm oil them be made palm oil design to solve this problems. In the designing which comply the consideration of good pal oil planning aspect be use value engineer study. While the criteria parameter of hygienic palm oil which obtained from the questioner area free fatty acid, water content, Iodine number, peroxide number, odor, taste and the color. The research which use value engineer study is throught any phase that is information phase, analyzes phase, creative phase, development phase and presentation phase. This research began with doing the identification of palm oil demand, continued by methodology development in order to measure oil design. By using creative process could be obtained flow rate position, the amount of adsorbent and the best settling time for palm oil alternative that is in the flow rate 70 ml/sec, 4% of adsorbent and the 70 minute for the settling time with free fatty acid value: 0.299. While the best palm oil alternative are palm oil with free fatty acid value = 0.299, water content = 0.31, Iodine number = 40.08, Peroxide number = 3.72, odor and taste = Normal, the color = Normal. The Evalution which done by value engineer study generate the value from alternative palm oil is 1.330 and market palm oil 1.392. Thus, can be conclude thet the value engineer study can be good implemented in the alternative palm oil planning so that alternative palm oil can be produced largely because they have better value that market palm oil and appropriate for little industries.

  19. Abandoned babies and absent policies.

    PubMed

    Mueller, Joanne; Sherr, Lorraine

    2009-12-01

    Although infant abandonment is a historical problem, we know remarkably little about the conditions or effects of abandonment to guide evidence driven policies. This paper briefly reviews the existing international evidence base with reference to potential mental health considerations before mapping current UK guidelines and procedures, and available incidence data. Limitations arising from these findings are discussed with reference to international practice, and interpreted in terms of future pathways for UK policy. A systematic approach was utilized to gather available data on policy information and statistics on abandoned babies in the UK. A review of the limited literature indicates that baby abandonment continues to occur, with potentially wide-ranging mental health ramifications for those involved. However, research into such consequences is lacking, and evidence with which to understand risk factors or motives for abandonment is scarce. International approaches to the issue remain controversial with outcomes unclear. Our systematic search identified that no specific UK policy relating to baby abandonment exists, either nationally or institutionally. This is compounded by a lack of accurate of UK abandonment statistics. Data that does exist is not comprehensive and sources are incompatible, resulting in an ambiguous picture of UK baby abandonment. Available literature indicates an absence of clear provision, policy and research on baby abandonment. Based on current understanding of maternal and child mental health issues likely to be involved in abandonment, existing UK strategy could be easily adapted to avoid the 'learning from scratch' approach. National policies on recording and handling of baby abandonments are urgently needed, and future efforts should be concentrated on establishing clear data collection frameworks to inform understanding, guide competent practice and enable successfully targeted interventions.

  20. Measuring, managing and maximizing refinery performance

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bascur, O.A.; Kennedy, J.P.

    1996-01-01

    Implementing continuous quality improvement is a confluence of total quality management, people empowerment, performance indicators and information engineering. Supporting information technologies allow a refiner to narrow the gap between management objectives and the process control level. Dynamic performance monitoring benefits come from production cost savings, improved communications and enhanced decision making. A refinery workgroup information flow model helps automate continuous improvement of processes, performance and the organization. The paper discusses the rethinking of refinery operations, dynamic performance monitoring, continuous process improvement, the knowledge coordinator and repository manager, an integrated plant operations workflow, and successful implementation.

  1. Multi objective multi refinery optimization with environmental and catastrophic failure effects objectives

    NASA Astrophysics Data System (ADS)

    Khogeer, Ahmed Sirag

    2005-11-01

    Petroleum refining is a capital-intensive business. With stringent environmental regulations on the processing industry and declining refining margins, political instability, increased risk of war and terrorist attacks in which refineries and fuel transportation grids may be targeted, higher pressures are exerted on refiners to optimize performance and find the best combination of feed and processes to produce salable products that meet stricter product specifications, while at the same time meeting refinery supply commitments and of course making profit. This is done through multi objective optimization. For corporate refining companies and at the national level, Intea-Refinery and Inter-Refinery optimization is the second step in optimizing the operation of the whole refining chain as a single system. Most refinery-wide optimization methods do not cover multiple objectives such as minimizing environmental impact, avoiding catastrophic failures, or enhancing product spec upgrade effects. This work starts by carrying out a refinery-wide, single objective optimization, and then moves to multi objective-single refinery optimization. The last step is multi objective-multi refinery optimization, the objectives of which are analysis of the effects of economic, environmental, product spec, strategic, and catastrophic failure. Simulation runs were carried out using both MATLAB and ASPEN PIMS utilizing nonlinear techniques to solve the optimization problem. The results addressed the need to debottleneck some refineries or transportation media in order to meet the demand for essential products under partial or total failure scenarios. They also addressed how importing some high spec products can help recover some of the losses and what is needed in order to accomplish this. In addition, the results showed nonlinear relations among local and global objectives for some refineries. The results demonstrate that refineries can have a local multi objective optimum that does not

  2. Liquefaction of lignocellulosic biomass: solvent, process parameter, and recycle oil screening.

    PubMed

    van Rossum, Guus; Zhao, Wei; Castellvi Barnes, Maria; Lange, Jean-Paul; Kersten, Sascha R A

    2014-01-01

    The liquefaction of lignocellulosic biomass is studied for the production of liquid (transportation) fuels. The process concept uses a product recycle as a liquefaction medium and produces a bio-oil that can be co-processed in a conventional oil refinery. This all is done at medium temperature (≈ 300 °C) and pressure (≈ 60 bar). Solvent-screening experiments showed that oxygenated solvents are preferred as they allow high oil (up to 93% on carbon basis) and low solid yields (≈ 1-2% on carbon basis) and thereby outperform the liquefaction of biomass in compressed water and biomass pyrolysis. The following solvent ranking was obtained: guaiacol>hexanoic acid ≫ n-undecane. The use of wet biomass results in higher oil yields than dry biomass. However, it also results in a higher operating pressure, which would make the process more expensive. Refill experiments were also performed to evaluate the possibility to recycle the oil as the liquefaction medium. The recycled oil appeared to be very effective to liquefy the biomass and even surpassed the start-up solvent guaiacol, but became increasingly heavy and more viscous after each refill and eventually showed a molecular weight distribution that resembles that of refinery vacuum residue. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Alumina Refinery Wastewater Management: When Zero Discharge Just Isn't Feasible….

    NASA Astrophysics Data System (ADS)

    Martin, Lucy; Howard, Steven

    Management and treatment of liquid effluents are determinant considerations in the design of alumina refineries. Rainfall, evaporation rate, proximity to the coast, process design and layout, ore mineralogy, the local environment, and potential impact on contiguous communities are all integral to the development of an appropriate refinery water management strategy. The goal is to achieve zero discharge of liquid effluent to the environment. However this is not always the most feasible solution under the extreme rainfall conditions in tropical and subtropical locations. This paper will explore the following issues for both inland and coastal refineries: • Methods to reduce and control refinery discharges

  4. World Oil Prices and Production Trends in AEO2010 (released in AEO2010)

    EIA Publications

    2010-01-01

    In Annual Energy Outlook 2010, the price of light, low-sulfur (or "sweet") crude oil delivered at Cushing, Oklahoma, is tracked to represent movements in world oil prices. The Energy Information Administration makes projections of future supply and demand for "total liquids,"" which includes conventional petroleum liquids -- such as conventional crude oil, natural gas plant liquids, and refinery gain -- in addition to unconventional liquids, which include biofuels, bitumen, coal-to-liquids (CTL), gas-to-liquids (GTL), extra-heavy oils, and shale oil.

  5. Refinery Outages

    EIA Publications

    2017-01-01

    EIA's latest analysis of planned refinery outages during the first half of 2017 finds that such outages are not expected to cause a shortfall in the supply of petroleum products including gasoline, jet fuel, and distillate fuel, relative to expected demand, either nationally or within any U.S. region. This result occurs notwithstanding the current high level of U.S. gasoline demand, which in 2016 was as high as or higher than in any past year.

  6. Respiratory symptoms and lung function in alumina refinery employees.

    PubMed

    Musk, A W; de Klerk, N H; Beach, J R; Fritschi, L; Sim, M R; Benke, G; Abramson, M; McNeil, J J

    2000-04-01

    Employees in alumina refineries are known to be exposed to a number of potential respiratory irritants, particularly caustic mist and bauxite and alumina dusts. To examine the prevalence of work related respiratory symptoms and lung function in alumina refinery employees and relate these to their jobs. 2964 current employees of three alumina refineries in Western Australia were invited to participate in a cross sectional study, and 89% responded. Subjects were given a questionnaire on respiratory symptoms, smoking, and occupations with additional questions on temporal relations between respiratory symptoms and work. Forced expiratory volume in 1 second (FEV(1)) and forced vital capacity (FVC) were measured with a rolling seal spirometer. Atopy was assessed with prick skin tests for common allergens. Associations between work and symptoms were assessed with Cox's regression to estimate prevalence ratios, and between work and lung function with linear regression. Work related wheeze, chest tightness, shortness of breath, and rhinitis were reported by 5.0%, 3.5%, 2.5%, and 9.5% of participants respectively. After adjustment for age, smoking, and atopy, most groups of production employees reported a greater prevalence of work related symptoms than did office employees. After adjustment for age, smoking, height, and atopy, subjects reporting work related wheeze, chest tightness, and shortness of breath had significantly lower mean levels of FEV(1) (186, 162, and 272 ml respectively) than subjects without these symptoms. Prevalence of most work related symptoms was higher at refinery 2 than at the other two refineries, but subjects at this refinery had an adjusted mean FEV(1) >60 ml higher than the others. Significant differences in FVC and FEV(1)/FVC ratio, but not FEV(1), were found between different process groups. There were significant differences in work related symptoms and lung function between process groups and refineries, but these were mostly not consistent

  7. Oil recovery from refinery oily sludge via ultrasound and freeze/thaw.

    PubMed

    Zhang, Ju; Li, Jianbing; Thring, Ronald W; Hu, Xuan; Song, Xinyuan

    2012-02-15

    The effective disposal of oily sludge generated from the petroleum industry has received increasing concerns, and oil recovery from such waste was considered as one feasible option. In this study, three different approaches for oil recovery were investigated, including ultrasonic treatment alone, freeze/thaw alone and combined ultrasonic and freeze/thaw treatment. The results revealed that the combined process could achieve satisfactory performance by considering the oil recovery rate and the total petroleum hydrocarbon (TPH) concentrations in the recovered oil and wastewater. The individual impacts of five different factors on the combined process were further examined, including ultrasonic power, ultrasonic treatment duration, sludge/water ratio in the slurry, as well as bio-surfactant (rhamnolipids) and salt (NaCl) concentrations. An oil recovery rate of up to 80.0% was observed with an ultrasonic power of 66 W and an ultrasonic treatment duration of 10 min when the sludge/water ratio was 1:2 without the addition of bio-surfactant and salt. The examination of individual factors revealed that the addition of low concentration of rhamnolipids (<100mg/L) and salt (<1%) to the sludge could help improve the oil recovery from the combined treatment process. The experimental results also indicated that ultrasound and freeze/thaw could promote the efficiency of each other, and the main mechanism of oil recovery enhancement using ultrasound was through enhanced desorption of petroleum hydrocarbons (PHCs) from solid particles. Copyright © 2011 Elsevier B.V. All rights reserved.

  8. Motiva Enterprises LLC Refinery Settlement

    EPA Pesticide Factsheets

    Settlement summary for nine refineries owned by Motiva, Equilon, and the Deer Park Refining Limited Partnership (Shell Deer Park) to assure compliance with major provisions of the Clean Air Act (CAA).

  9. GHGRP Refineries Sector Industrial Profile

    EPA Pesticide Factsheets

    EPA's Greenhouse Gas Reporting Program periodically produces detailed profiles of the various industries that report under the program. The profiles available for download below contain detailed analyses for the Refineries industry.

  10. A Spatial Risk Analysis of Oil Refineries within the United States

    DTIC Science & Technology

    2012-03-01

    regulator and consumer. This is especially true within the energy sector which is composed of electrical power, oil , and gas infrastructure [10...Naphtali, "Analysis of Electrical Power and Oil and Gas Pipeline Failures," in International Federation for Information Processing, E. Goetz and S...61-67, September 1999. [5] J. Simonoff, C. Restrepo, R. Zimmerman, and Z. Naphtali, "Analysis of Electrical Power and Oil and Gas Pipeline Failures

  11. Modeling and Multiresponse Optimization for Anaerobic Codigestion of Oil Refinery Wastewater and Chicken Manure by Using Artificial Neural Network and the Taguchi Method

    PubMed Central

    Hemmat, Abbas; Kafashan, Jalal; Huang, Hongying

    2017-01-01

    To study the optimum process conditions for pretreatments and anaerobic codigestion of oil refinery wastewater (ORWW) with chicken manure, L9 (34) Taguchi's orthogonal array was applied. The biogas production (BGP), biomethane content (BMP), and chemical oxygen demand solubilization (CODS) in stabilization rate were evaluated as the process outputs. The optimum conditions were obtained by using Design Expert software (Version 7.0.0). The results indicated that the optimum conditions could be achieved with 44% ORWW, 36°C temperature, 30 min sonication, and 6% TS in the digester. The optimum BGP, BMP, and CODS removal rates by using the optimum conditions were 294.76 mL/gVS, 151.95 mL/gVS, and 70.22%, respectively, as concluded by the experimental results. In addition, the artificial neural network (ANN) technique was implemented to develop an ANN model for predicting BGP yield and BMP content. The Levenberg-Marquardt algorithm was utilized to train ANN, and the architecture of 9-19-2 for the ANN model was obtained. PMID:29441352

  12. Ergonomics in designing process: dialogue between designers, executors and users in the maintenance activity of radars in an oil refinery.

    PubMed

    Menegon, Fabrício Augusto; Rodrigues, Daniela da Silva; Fontes, Andréa Regina Martins; Menegon, Nilton Luiz

    2012-01-01

    This paper aims to discuss the role of ergonomics in design process using the dialogue developed by designers, implementers and users in an oil refinery. It was possible to identify the need of minimizing the postural constraints, risk of accidents, mechanical shocks and to enlarge safety perception in the access and permanency of the users at the workspace. It has been determined and validated by workers and managers to implement different deadlines depending on programming, viability and execution time for the improvements proposed. In a long-term: it was proposed the substitution of the ladders with time planning according to the maintenance program of the tanks; in a short-time: it was suggested the expansion of the existing platforms, implementation of a walkway connection provided with guardrails between the upper access of the side ladder and the repositioning of radar set and aerial aiming at the usage by workers at the workstation of the new platform. It was also elaborated eight typologies of intervention, according to the request, type of tank, material stored, and its setting place. The design process arises from ergonomics workplace analysis that presents concepts for solutions which was a mediator tool to be settled between users and implementers.

  13. An integrated experiment for identification of best decision styles and teamworks with respect to HSE and ergonomics program: The case of a large oil refinery.

    PubMed

    Azadeh, A; Mokhtari, Z; Sharahi, Z Jiryaei; Zarrin, M

    2015-12-01

    Decision making failure is a predominant human error in emergency situations. To demonstrate the subject model, operators of an oil refinery were asked to answer a health, safety and environment HSE-decision styles (DS) questionnaire. In order to achieve this purpose, qualitative indicators in HSE and ergonomics domain have been collected. Decision styles, related to the questions, have been selected based on Driver taxonomy of human decision making approach. Teamwork efficiency has been assessed based on different decision style combinations. The efficiency has been ranked based on HSE performance. Results revealed that efficient decision styles resulted from data envelopment analysis (DEA) optimization model is consistent with the plant's dominant styles. Therefore, improvement in system performance could be achieved using the best operator for critical posts or in team arrangements. This is the first study that identifies the best decision styles with respect to HSE and ergonomics factors. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Stabilization of Softwood-Derived Pyrolysis Oils for Continuous Bio-oil Hydroprocessing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Olarte, Mariefel V.; Zacher, Alan H.; Padmaperuma, Asanga B.

    The use of fast pyrolysis as a potential renewable liquid transportation fuel alternative to crude oil depends on successful catalytic upgrading to produce a refinery-ready product with oxygen content and qualities (i.e. specific functional group or compound content) that is compatible with the product’s proposed insertion point. Catalytic upgrading of bio-oil requires high temperature and pressure, while similar to crude oil hydrotreating, is not as straightforward for the thermally unstable pyrolysis oil. For years, a two-temperature zone, downflow trickle bed reactor was the state-of-the art for continuous operation. However, pressure excursion due to plug formation still occurred, typically at themore » high temperature transition zone, leading to a process shutdown within 140 h. Recently, a bio-oil pre-treatment process, together with a robust commercial catalyst, was found to be enabling the continuous operation of the two-zone hydroprocessing system. Here, we report the results on pre-treating bio-oil at 413 K and 8.4 MPa of flowing H2 (500 L H2/L bio-oil, 0.5 L bio-oil/L catalyst bed) and the attempts to characterize this oil product to understand the chemistry which enabled the long-term processing of bio-oil.« less

  15. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Abandonment. 157.216 Section 157.216 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... facilities to be abandoned. (5) For any abandonment resulting in earth disturbance, a USGS 71/2-minute-series...

  16. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Abandonment. 157.216 Section 157.216 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... facilities to be abandoned. (5) For any abandonment resulting in earth disturbance, a USGS 71/2-minute-series...

  17. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Abandonment. 157.216 Section 157.216 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... facilities to be abandoned. (5) For any abandonment resulting in earth disturbance, a USGS 71/2-minute-series...

  18. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Abandonment. 157.216 Section 157.216 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... facilities to be abandoned. (5) For any abandonment resulting in earth disturbance, a USGS 71/2-minute-series...

  19. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Abandonment. 157.216 Section 157.216 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... facilities to be abandoned. (5) For any abandonment resulting in earth disturbance, a USGS 71/2-minute-series...

  20. Geospatial Analysis of Oil and Gas Wells in California

    NASA Astrophysics Data System (ADS)

    Riqueros, N. S.; Kang, M.; Jackson, R. B.

    2015-12-01

    California currently ranks third in oil production by U.S. state and more than 200,000 wells have been drilled in the state. Oil and gas wells provide a potential pathway for subsurface migration, leading to groundwater contamination and emissions of methane and other fluids to the atmosphere. Here we compile available public databases on oil and gas wells from the California Department of Conservation's Division of Oil, Gas, and Geothermal Resources, the U.S. Geological Survey, and other state and federal sources. We perform geospatial analysis at the county and field levels to characterize depths, producing formations, spud/completion/abandonment dates, land cover, population, and land ownership of active, idle, buried, abandoned, and plugged wells in California. The compiled database is designed to serve as a quantitative platform for developing field-based groundwater and air emission monitoring plans.

  1. Respiratory symptoms and lung function in alumina refinery employees

    PubMed Central

    Musk, A; de Klerk, N. H; Beach, J.; Fritschi, L.; Sim, M.; Benke, G.; Abramson, M.; McNeil, J.

    2000-01-01

    OBJECTIVES—Employees in alumina refineries are known to be exposed to a number of potential respiratory irritants, particularly caustic mist and bauxite and alumina dusts. To examine the prevalence of work related respiratory symptoms and lung function in alumina refinery employees and relate these to their jobs.
METHODS—2964 current employees of three alumina refineries in Western Australia were invited to participate in a cross sectional study, and 89% responded. Subjects were given a questionnaire on respiratory symptoms, smoking, and occupations with additional questions on temporal relations between respiratory symptoms and work. Forced expiratory volume in 1 second (FEV1) and forced vital capacity (FVC) were measured with a rolling seal spirometer. Atopy was assessed with prick skin tests for common allergens. Associations between work and symptoms were assessed with Cox's regression to estimate prevalence ratios, and between work and lung function with linear regression.
RESULTS—Work related wheeze, chest tightness, shortness of breath, and rhinitis were reported by 5.0%, 3.5%, 2.5%, and 9.5% of participants respectively. After adjustment for age, smoking, and atopy, most groups of production employees reported a greater prevalence of work related symptoms than did office employees. After adjustment for age, smoking, height, and atopy, subjects reporting work related wheeze, chest tightness, and shortness of breath had significantly lower mean levels of FEV1 (186, 162, and 272 ml respectively) than subjects without these symptoms. Prevalence of most work related symptoms was higher at refinery 2 than at the other two refineries, but subjects at this refinery had an adjusted mean FEV1 >60 ml higher than the others. Significant differences in FVC and FEV1/FVC ratio, but not FEV1, were found between different process groups.
CONCLUSIONS—There were significant differences in work related symptoms and lung function between process groups and

  2. 40 CFR 73.90 - Allowance allocations for small diesel refineries.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Allowance allocations for small diesel... PROGRAMS (CONTINUED) SULFUR DIOXIDE ALLOWANCE SYSTEM Small Diesel Refineries § 73.90 Allowance allocations for small diesel refineries. (a) Initial certification of eligibility. The certifying official of a...

  3. 40 CFR 73.90 - Allowance allocations for small diesel refineries.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Allowance allocations for small diesel... PROGRAMS (CONTINUED) SULFUR DIOXIDE ALLOWANCE SYSTEM Small Diesel Refineries § 73.90 Allowance allocations for small diesel refineries. (a) Initial certification of eligibility. The certifying official of a...

  4. Enrichment and characterization of hydrocarbon-degrading bacteria from petroleum refinery waste as potent bioaugmentation agent for in situ bioremediation.

    PubMed

    Sarkar, Poulomi; Roy, Ajoy; Pal, Siddhartha; Mohapatra, Balaram; Kazy, Sufia K; Maiti, Mrinal K; Sar, Pinaki

    2017-10-01

    Intrinsic biodegradation potential of bacteria from petroleum refinery waste was investigated through isolation of cultivable strains and their characterization. Pseudomonas and Bacillus spp. populated the normal cultivable taxa while prolonged enrichment with hydrocarbons and crude oil yielded hydrocarbonoclastic bacteria of genera Burkholderia, Enterobacter, Kocuria, Pandoraea, etc. Strains isolated through enrichment showed assemblages of superior metabolic properties: utilization of aliphatic (C6-C22) and polyaromatic compounds, anaerobic growth with multiple terminal electron acceptors and higher biosurfactant production. Biodegradation of dodecane was studied thoroughly by GC-MS along with detection of gene encoding alkane hydroxylase (alkB). Microcosms bioaugmented with Enterobacter, Pandoraea and Burkholderia strains showed efficient biodegradation (98% TPH removal) well fitted in first order kinetic model with low rate constants and decreased half-life. This study proves that catabolically efficient bacteria resides naturally in complex petroleum refinery wastes and those can be useful for bioaugmentation based bioremediation. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Urinary excretion of platinum from South African precious metals refinery workers.

    PubMed

    Linde, Stephanus J L; Franken, Anja; du Plessis, Johannes L

    2018-03-30

    Urinary platinum (Pt) excretion is a reliable biomarker for occupational Pt exposure and has been previously reported for precious metals refinery workers in Europe but not for South Africa, the world's largest producer of Pt. This study aimed to quantify the urinary Pt excretion of South African precious metals refinery workers. Spot urine samples were collected from 40 workers (directly and indirectly exposed to Pt) at two South African precious metals refineries on three consecutive mornings prior to their shifts. Urine samples were analysed for Pt using inductively coupled plasma-mass spectrometry and were corrected for creatinine content. The urinary Pt excretion of workers did not differ significantly between sampling days. Urinary Pt excretions ranged from <0.1 to 3.0 µg Pt/g creatinine with a geometric mean of 0.21 µg Pt/g creatinine (95% CI 0.17 to 0.26 µg Pt/g creatinine). The work area (P=0.0006; η 2 =0.567) and the number of years workers were employed at the refineries (P=0.003; η 2 =0.261) influenced their urinary Pt excretion according to effect size analyses. Directly exposed workers had significantly higher urinary Pt excretion compared with indirectly exposed workers (P=0.007). The urinary Pt excretion of South African precious metals refinery workers reported in this study is comparable with that of seven other studies conducted in precious metals refineries and automotive catalyst plants in Europe. The Pt body burden of workers is predominantly determined by their work area, years of employment in the refineries and whether they are directly or indirectly exposed to Pt. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

  6. 78 FR 76788 - Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-19

    ...-AS03 Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or... Petroleum Refineries for Which Construction, Reconstruction, or Modification Commenced After May 14, 2007... the standards of performance for petroleum refineries at 40 CFR part 60, subpart Ja. We are proposing...

  7. Impact of Expanded North Slope of Alaska Crude Oil Production on Oil Flows in the Contiguous United States (Summary)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    DeRosa, Sean e.; Flanagan, Tatiana Paz

    Crude oil produced on the North Slope of Alaska (NSA) is primarily transported on the Trans-Alaska Pipeline System (TAPS) to in-state refineries and the Valdez Marine Terminal in southern Alaska. From the Terminal, crude oil is loaded onto tankers and is transported to export markets or to three major locations along the U.S. West Coast: Anacortes-Ferndale area (Washington), San Francisco Bay area, and Los Angeles area. North Slope of Alaska production has decreased about 75% since the 1980s, which has reduced utilization of TAPS.

  8. Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets

    EIA Publications

    2012-01-01

    Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets is an update to a previous Energy Information Administration (EIA) report, Reductions in Northeast Refining Activity: Potential Implications for Petroleum Product Markets, released in December 2011. This update analyzes possible market responses and impacts in the event Sunoco's Philadelphia refinery closes this summer, in addition to the recently idled refineries on the East Coast and in the U.S. Virgin Islands.

  9. How to justify small-refinery info/control system modernization

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Haskins, D.E.

    1993-05-01

    Information and control systems modernization can be justified by successful implementation of advanced process control (APC) in nearly all refineries, even the small ones. However, the small refineries require special solutions to meet the challenges of limited resources in both finance and manpower. Based on a number of case studies, a typical small refinery as it operates today is described. A sample information and control system modernization plan is described and the typical cost and benefits show how the project cost can be justified. Business objectives of an HPI plant are to satisfy customers by providing specific products, to satisfymore » the owners by maximizing profits and to satisfy the public by being safe and environmentally correct. Managers have always tried to meet these objectives with functions for the total plant.« less

  10. Refinery buyers and sellers hunt cash

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gill, D.

    1995-07-01

    There`s a high-risk premium in the petroleum refining business today. The ability to transfer assets is viewed with a high degree of skepticism, and capital is not freely available. There are willing buyers and sellers for refinery assets today, but it is tough to qualify for a loan. Private financing also was responsible for a refinery deal that closed recently - the sale of Kerr-McGee`s 100,000-b/d unit in Corpus Christi, Texas. After nearly 3 years on the market, this unit was finally bought by a deep-pocketed private firm, Koch Industries of Wichita, Kan. The purchase price has not been disclosed,more » but it was probably not rich.« less

  11. 40 CFR 60.692-3 - Standards: Oil-water separators.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Emissions From Petroleum Refinery Wastewater Systems § 60.692-3 Standards: Oil-water separators. (a) Each... wastewater shall, in addition to the requirements in paragraph (a) of this section, be equipped and operated... wastewater which was equipped and operated with a fixed roof covering the entire separator tank or a portion...

  12. 40 CFR 60.692-3 - Standards: Oil-water separators.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Emissions From Petroleum Refinery Wastewater Systems § 60.692-3 Standards: Oil-water separators. (a) Each... wastewater shall, in addition to the requirements in paragraph (a) of this section, be equipped and operated... wastewater which was equipped and operated with a fixed roof covering the entire separator tank or a portion...

  13. 77 FR 47429 - Agency Information Collection Activities; Petroleum Refineries in Foreign Trade Sub-zones

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-08

    ... Activities; Petroleum Refineries in Foreign Trade Sub-zones AGENCY: U.S. Customs and Border Protection (CBP... requirement concerning the Petroleum Refineries in Foreign Trade Sub-zones. This request for comment is being...: Title: Petroleum Refineries in Foreign Trade Sub-zones. OMB Number: 1651-0063. Form Number: None...

  14. Method to upgrade bio-oils to fuel and bio-crude

    DOEpatents

    Steele, Philip H; Pittman, Jr., Charles U; Ingram, Jr., Leonard L; Gajjela, Sanjeev; Zhang, Zhijun; Bhattacharya, Priyanka

    2013-12-10

    This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.

  15. More evidence of unpublished industry studies of lead smelter/refinery workers.

    PubMed

    Sullivan, Marianne

    2015-01-01

    Lead smelter/refinery workers in the US have had significant exposure to lead and are an important occupational group to study to understand the health effects of chronic lead exposure in adults. Recent research found evidence that studies of lead smelter/refinery workers have been conducted but not published. This paper presents further evidence for this contention. To present further evidence of industry conducted, unpublished epidemiologic studies of lead smelter/refinery workers and health outcomes. Historical research relying on primary sources such as internal industry documents and published studies. ASARCO smelter/refinery workers were studied in the early 1980s and found to have increased risk of lung cancer and stroke in one study, but not in another. Because occupational lead exposure is an on-going concern for US and overseas workers, all epidemiologic studies should be made available to evaluate and update occupational health and safety standards.

  16. An epidemiological study of petroleum refinery employees.

    PubMed Central

    Wong, O; Morgan, R W; Bailey, W J; Swencicki, R E; Claxton, K; Kheifets, L

    1986-01-01

    A cohort study of 14179 current and former Chevron USA employees at the Richmond and El Segundo, California, refineries was conducted. The cohort consisted of everyone working at either refinery for a minimum of one year. The observed mortality of the cohort, by cause, was compared with the expected based on the United States mortality rates, standardised for age, race, sex, and calendar time. Analyses by refinery, job category, hire date, duration of employment, and latency were performed. For the entire cohort, mortality from all causes was 72.4% of that expected, a deficit that was statistically significant. In addition, a significantly lower mortality was found for all forms of cancer combined, digestive cancer, lung cancer, heart disease, non-malignant respiratory disease, diseases of the digestive system, and accidents. Only lymphopoietic cancer showed a pattern of increased risk suggestive of a possible relation to an occupational exposure. The excess appears confined to cancer of lymphatic tissue (not leukaemias) at Richmond, and only among those hired before 1948. A follow up case analysis of the deaths from lymphatic cancer failed to identify a common exposure pattern. Images PMID:3947563

  17. Large scale and long term application of bioslurping: the case of a Greek petroleum refinery site.

    PubMed

    Gidarakos, E; Aivalioti, M

    2007-11-19

    This paper presents the course and the remediation results of a 4-year application of bioslurping technology on the subsurface of a Greek petroleum refinery, which is still under full operation and has important and complicated subsurface contamination problems, mainly due to the presence of light non-aqueous phase liquids (LNAPL). About 55 wells are connected to the central bioslurping unit, while a mobile bioslurping unit is also used whenever and wherever is necessary. Moreover, there are about 120 additional wells for the monitoring of the subsurface of the facilities that cover a total area of 1,000,000 m(2). An integrated monitoring program has also been developed and applied on the site, including frequent LNAPL layer depth and thickness measurements, conduction of bail-down and recovery tests, sampling and chemical analysis of the free oil phase, etc., so as to evaluate the remediation technique's efficiency and ensure a prompt tracing of any new potential leak. Despite the occurrence of new leaks within the last 4 years and the observed entrapment of LNAPL in the vadoze zone, bioslurping has managed to greatly restrict the original plume within certain and relatively small parts of the refinery facilities.

  18. Determination of diethanolamine or N-methyldiethanolamine in high ammonium concentration matrices by capillary electrophoresis with indirect UV detection: application to the analysis of refinery process waters.

    PubMed

    Bord, N; Crétier, G; Rocca, J-L; Bailly, C; Souchez, J-P

    2004-09-01

    Alkanolamines such as diethanolamine (DEA) and N-methyldiethanolamine (MDEA) are used in desulfurization processes in crude oil refineries. These compounds may be found in process waters following an accidental contamination. The analysis of alkanolamines in refinery process waters is very difficult due to the high ammonium concentration of the samples. This paper describes a method for the determination of DEA in high ammonium concentration refinery process waters by using capillary electrophoresis (CE) with indirect UV detection. The same method can be used for the determination of MDEA. Best results were achieved with a background electrolyte (BGE) comprising 10 mM histidine adjusted to pH 5.0 with acetic acid. The development of this electrolyte and the analytical performances are discussed. The quantification was performed by using internal standardization, by which triethanolamine (TEA) was used as internal standard. A matrix effect due to the high ammonium content has been highlighted and standard addition was therefore used. The developed method was characterized in terms of repeatability of migration times and corrected peak areas, linearity, and accuracy. Limits of detection (LODs) and quantification (LOQs) obtained were 0.2 and 0.7 ppm, respectively. The CE method was applied to the determination of DEA or MDEA in refinery process waters spiked with known amounts of analytes and it gave excellent results, since uncertainties obtained were 8 and 5%, respectively.

  19. More evidence of unpublished industry studies of lead smelter/refinery workers

    PubMed Central

    2015-01-01

    Background Lead smelter/refinery workers in the US have had significant exposure to lead and are an important occupational group to study to understand the health effects of chronic lead exposure in adults. Recent research found evidence that studies of lead smelter/refinery workers have been conducted but not published. This paper presents further evidence for this contention. Objectives To present further evidence of industry conducted, unpublished epidemiologic studies of lead smelter/refinery workers and health outcomes. Methods Historical research relying on primary sources such as internal industry documents and published studies. Results ASARCO smelter/refinery workers were studied in the early 1980s and found to have increased risk of lung cancer and stroke in one study, but not in another. Conclusions Because occupational lead exposure is an on-going concern for US and overseas workers, all epidemiologic studies should be made available to evaluate and update occupational health and safety standards. PMID:26070220

  20. Correcting systematic bias and instrument measurement drift with mzRefinery

    DOE PAGES

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; ...

    2015-08-04

    Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. In conclusion, we report on availability; the mzRefinery tool is part of msConvert, availablemore » with the ProteoWizard open source package at http://proteowizard.sourceforge.net/« less

  1. Renewable Fuel Solutions for Petroleum Refineries

    DOT National Transportation Integrated Search

    1995-03-01

    This National Renewable Energy Laboratory (NREL) factsheet, one in a series, : BioFacts: Fueling a Stronger Economy, explains how biomass research is helping : to produce new ways to condition synthesis gas (syngas) produced from refinery : byproduct...

  2. Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Goldberg, Marshall

    The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on modelmore » add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.« less

  3. Evaluation of adsorbent and ion exchange resins for removal of organic matter from petroleum refinery wastewaters aiming to increase water reuse.

    PubMed

    de Abreu Domingos, Rodrigo; da Fonseca, Fabiana Valéria

    2018-05-15

    The oil refinery industry seeks solutions to reduce its water uptake and consumption by encouraging the reuse of internal streams and wastewater from treatment systems. After conventional treatment the petroleum refinery wastewater still contains a considerable quantity of recalcitrant organics and the adsorption on activated carbon is currently used in Brazilian refineries, although it is still expensive due to the difficulty of its regeneration. This study evaluated the use of adsorbent and ion exchange resins for the removal of organic matter from refinery wastewater after conventional treatment in order to verify its feasibility, applying successive resin regenerations and comparing the results with those obtained for activated carbon process. Adsorption isotherms experiments were used to evaluate commercial resins, and the most efficient was subjected to column experiments, where absorbance (ABS) and total organic carbon (TOC) removal were measured. The adsorption isotherm of the best resin showed an adsorptive capacity that was 55% lower than that of activated carbon. On the other hand, the column experiments indicated good removal efficiency, and the amount of TOC in the treated wastewater was as good as has been reported in the literature for activated carbon. The regeneration efficiency of the retained organics ranged from 57 to 94%, while regenerant consumption ranged from 12 to 79% above the amount recommended by the resin supplier for the removal of organic material from natural sources, showing the great resistance of these recalcitrant compounds to desorption. Finally, an estimate of the service life of the resin using intermediate regeneration conditions found it to be seven times higher than that of activated carbon when the latter is not regenerated. Copyright © 2018 Elsevier Ltd. All rights reserved.

  4. Identification of the odour and chemical composition of alumina refinery air emissions.

    PubMed

    Coffey, P S; Ioppolo-Armanios, M

    2004-01-01

    Alcoa World Alumina Australia has undertaken comprehensive air emissions monitoring aimed at characterising and quantifying the complete range of emissions to the atmosphere from Bayer refining of alumina at its Western Australian refineries. To the best of our knowledge, this project represents the most complete air emissions inventory of a Bayer refinery conducted in the worldwide alumina industry. It adds considerably to knowledge of air emission factors available for use in emissions estimation required under national pollutant release and transfer registers (NPRTs), such as the Toxic Releases Inventory, USA, and the National Pollutant Inventory, Australia. It also allows the preliminary identification of the key chemical components responsible for characteristic alumina refinery odours and the contribution of these components to the quality, or hedonic tone, of the odours. The strength and acceptability of refinery odours to employees and neighbours appears to be dependent upon where and in what proportion the odorous gases have been emitted from the refineries. This paper presents the results of the programme and develops a basis for classifying the odour properties of the key emission sources in the alumina-refining process.

  5. 40 CFR 80.94 - Requirements for gasoline produced at foreign refineries.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... was not imported into the United States. (f) Load port independent sampling, testing and refinery... FRGAS to the United States; and (v) Determine the date and time the vessel departs the port serving the... departure of the vessel from the port serving the foreign refinery; (ii) Prepare a volume-weighted vessel...

  6. 40 CFR 80.94 - Requirements for gasoline produced at foreign refineries.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... was not imported into the United States. (f) Load port independent sampling, testing and refinery... FRGAS to the United States; and (v) Determine the date and time the vessel departs the port serving the... departure of the vessel from the port serving the foreign refinery; (ii) Prepare a volume-weighted vessel...

  7. Oil outlook

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    DiBona, C.J.

    1979-04-01

    Because the US imports approximately 43% of its oil, and the amount available from the western hemisphere has declined sharply, the US has depended more on the eastern hemisphere members of OPEC, which now supplies >82% of US oil imports. Because of the political unrest in Iran, it has become apparent that domestic energy goals must be considered along with clear air goals. Examples illustrating the compatibility of energy production and environment are described. Questions arising from differences in federal, state, and local regulations are discussed in terms of adjusting the Clean Air Act to allow the implementation of newmore » energy recovery systems, i.e., thermal recovery, and construction of terminals and pipeline to receive and ship Alaskan crude oil and of refineries to produce low-sulfur fuels and unleaded gasoline. The level of air quality that will protect public health, and how can that level be achieved effectively need to be resolved. The concern expressed over the relaxed O/sub 3/ standard is discussed, and arguments supporting the move are presented.« less

  8. Cleaning oil refining drainage waters out of emulsified oil products with thermic treated cedar nut shell

    NASA Astrophysics Data System (ADS)

    Pyatanova, P. A.; Adeeva, L. N.

    2017-08-01

    It was elaborated the ability of the sorbent produced by thermic treatment of cedar nut shell to destruct model and real first kind (direct) emulsions in static and dynamic conditions. In static conditions optimal ratio sorbent-emulsion with the original concentration of oil products 800 mg/l was in the range of 2.0 g per 100 ml of emulsion which corresponds to the level of treatment 94.9%. The time of emulsion destruction was 40 minutes. This sorbent is highly active in dynamic processes of oil-contaminated water treatment, the level of treatment 96.0% is being achieved. Full dynamic sorptive capacity of the sorbent is 0.85 g/g. Sorbent based on the thermic treated cedar nut shell can be elaborated as sorptive filter element of local treatment facilities of oil refining and petrochemical processes. After the treatment with this sorbent of drainage waters of oil refinery in dynamic conditions the concentration of oil products became less than mpc on oil products for waste waters coming to biological treatment.

  9. Forensic fingerprinting of oil-spill hydrocarbons in a methanogenic environment-Mandan, ND and Bemidji, MN

    USGS Publications Warehouse

    Hostettler, F.D.; Wang, Y.; Huang, Y.; Cao, W.; Bekins, B.A.; Rostad, C.E.; Kulpa, C.F.; Laursen, Andrew E.

    2007-01-01

    In recent decades forensic fingerprinting of oil-spill hydrocarbons has emerged as an important tool for correlating oils and for evaluating their source and character. Two long-term hydrocarbon spills, an off-road diesel spill (Mandan, ND) and a crude oil spill (Bemidji, MN) experiencing methanogenic biodegradation were previously shown to be undergoing an unexpected progression of homologous n-alkane and n-alkylated cyclohexane loss. Both exhibited degradative losses proceeding from the high-molecular-weight end of the distributions, along with transitory concentration increases of lower-molecular-weight homologs. Particularly in the case of the diesel fuel spill, these methanogenic degradative patterns can result in series distributions that mimic lower cut refinery fuels or admixture with lower cut fuels. Forensic fingerprinting in this long-term spill must therefore rely on more recalcitrant series, such as polycyclic aromatic hydrocarbon or drimane sesquiterpane profiles, to prove if the spilled oil is single-sourced or whether there is verifiable admixture with other extraneous refinery fuels. Degradation processes impacting n-alkanes and n-alkylated ring compounds, which make these compounds unsuitable for fingerprinting, nevertheless are of interest in understanding methanogenic biodegradation. Copyright ?? Taylor & Francis Group, LLC.

  10. Chad: World Oil Report 1991

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-08-01

    This paper reports on Mango 1, which is an exploration well started in September 1990 on a block adjacent to Lake Chad by Esso, Chevron and Shell was suspended after the coup in that nation's capital later in the year. The small Sedigi oil field, discovered in the 70s, will be developed with a pipeline to a 3,000-bpd refinery. Improved relations with Libya and future internal stability may further open the door to exploration.

  11. Potential air emission impacts of cellulosic ethanol production at seven demonstration refineries in the United States.

    PubMed

    Jones, Donna Lee

    2010-09-01

    This paper reports on the estimated potential air emissions, as found in air permits and supporting documentation, for seven of the first group of precommercial or "demonstration" cellulosic ethanol refineries (7CEDF) currently operating or planning to operate in the United States in the near future. These seven refineries are designed to produce from 330,000 to 100 million gal of ethanol per year. The overall average estimated air emission rates for criteria, hazardous, and greenhouse gas pollutants at the 7CEDF are shown here in terms of tons per year and pounds per gallon of ethanol produced. Water use rates estimated for the cellulosic ethanol refineries are also noted. The air emissions are then compared with similar estimates from a U.S. cellulosic ethanol pilot plant, a commercial Canadian cellulosic ethanol refinery, four commercial U.S. corn ethanol refineries, and U.S. petroleum refineries producing gasoline. The U.S. Environmental Protection Agency (EPA) air pollution rules that may apply to cellulosic ethanol refineries are also discussed. Using the lowest estimated emission rates from these cellulosic ethanol demonstration facilities to project air emissions, EPA's major source thresholds for criteria and hazardous air pollutants might not be exceeded by cellulosic ethanol refineries that produce as high as 25 million gal per year of ethanol (95 ML). Emissions are expected to decrease at cellulosic ethanol refineries as the process matures and becomes more commercially viable.

  12. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... vehicle diesel fuel produced during the most recent calendar year the refinery was in operation after... the U.S. during the most recent calendar year the refinery was in operation after being reactivated... most recent calendar year the refinery was in operation after being reactivated pursuant to § 80.595(c...

  13. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... vehicle diesel fuel produced during the most recent calendar year the refinery was in operation after... the U.S. during the most recent calendar year the refinery was in operation after being reactivated... most recent calendar year the refinery was in operation after being reactivated pursuant to § 80.595(c...

  14. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... vehicle diesel fuel produced during the most recent calendar year the refinery was in operation after... the U.S. during the most recent calendar year the refinery was in operation after being reactivated... most recent calendar year the refinery was in operation after being reactivated pursuant to § 80.595(c...

  15. Care of the abandoned child.

    PubMed

    Raghunath, M

    1991-01-01

    Care of abandoned children in India is discussed in terms of reasons for abandonment, the physical condition of the children, and legal categories. The options available currently are the cottage system, sponsorship programs, foster care, or adoption. Child-care and rehabilitation that may be necessary is specified as is the importance of maintaining records. The gaps in child-care are exposed. The role of nongovernmental organization (NGOs) and new legislation in closing the gaps is presented. Abandonment is usually a direct result of poverty, but it can also be caused by mental or physical handicaps or illegitimacy. The numbers of abandoned children may reach 2 million. 40-60% of abandoned infants die during monsoons and summers. The legal categories are privately abandoned, children on remand, or court-committed children. The cottage system emphasizes deinstitutionalization, but there remains a great demand for care. Sponsorship aims to strengthen the family unit to prevent abandonment. Foster care provides an alternative family substitute, but is known only theoretically. Childcare may involve instant hospitalization, care is an institution, or foster care with a suitable family. Nursery care requires discipline in hygiene, sanitation, maintenance of individual medical records, and a general cheerful atmosphere. Records are important for the child in later life and for adoption. Rehabilitation is a sociolegal process which must be done properly or it can jeopardize a child's future security. Despite the Supreme Court guidelines of 1984, there is no uniform system of adoption practices, and the child's interests are overlooked when adoptions are promoted. NGOs play an important role in making social welfare programs work. However their efforts are of limited help without government support and legislation. There is a lack of proper legislation which is outside the control of political and religious interests; e.g., Hindu law only permits adoption of one child of

  16. Penny-pinching strategy pays off at the gas pumps. [Hudson Oil Co

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nazem, S.G.

    1978-06-05

    Mary Hudson Vandergrift is president and chief executive of Hudson Oil Company. She reigns over the oldest and one of the largest independent gasoline-marketing companies in the U.S., with 300 service stations scattered across thirty-six states, and her own refinery. Her company rang up sales of $230 million last year, and FORTUNE estimates that profits were in the neighborhood of $10 million. Many of Miss Hudson's strategies in gasoline marketing have been getting to be commonplace in the business. She runs a lean operation, cutting costs to the bone. She shuns grease racks and service bays; at each station amore » small, austere kiosk houses only a cash box and rest rooms. Most customers must serve themselves. She undersells the major oil companies by 1 to 2 cents per gallon. Her refinery turns out 450,000 gallons of gasoline daily, enough to fill 50% of Hudson's retail needs and for every barrel of crude it refines, Hudson Oil gets a rebate of about $2 from the government as part of the entitlements program that aims to keep small refiners competitive with the majors. (MCW)« less

  17. Abandoning pipelines working group regulatory issues

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    The history of hydrocarbon development in Louisiana and off its coast is one of the interdependence of technological innovation, entrepreneurial risk-taking, resource management, judicial decisions, legislation, marketing, employee good will, infrastructure and support services, coupled with favorable geologic structures that made early exploration and development relatively easy. Mariners sailing off the coast of Louisiana and Texas in the 1600`s recorded one of the earliest known natural oil seeps. They shrugged it off as unimportant, as there was no market for the substance they witnessed. The seepage, however, provided a tiny clue to the vast storehouse of hydrocarbons trapped in themore » earth`s crust extending from the uplands, through Louisiana`s swamps and marshes, and into the subaqueous habitats of the Gulf of Mexico-the world`s ninth largest body of water. In all cases, each move into a new geographic province required considerable change in operation philosophy and in the science supporting the exploration and development activity. As technology changed, or was developed to meet the industry`s needs, new frontiers were explored. However, with time-as is the case with any nonrenewable resource-fields and wells lost their productive life. They had to be abandoned. In fact, the Minerals Management Service suggests that within the next 10 years the offshore industry will remove 150 platforms per year, or nearly half of the current number of production units. The industry will be asked to dispose of nearly one unit every 2.4 days. If this is the case, abandonment issues are going to continue to surface.« less

  18. Feasibility study on the modernization and expansion of the Tema Oil Refinery: Final report. Export trade information

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1992-04-01

    The study was undertaken in order to serve the Ministry of Energy of Ghana under the terms of the contract with respect to deliverables, cost and schedule. The objectives of the study were: to evaluate the ability of the proposed refinery configuration to meet the demands for petroleum products through the year 2005; to demonstrate sound economics in order to attract financing from leading international agencies such as the World Bank, African Development Bank and Export-Import Bank; and to serve as a basis for meaningful future work by the Ministry.

  19. 7 CFR 767.51 - Property abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... AGRICULTURE SPECIAL PROGRAMS INVENTORY PROPERTY MANAGEMENT Property Abandonment and Personal Property Removal..., manage, and operate the abandoned security property, including marketing perishable security property on...

  20. Archive of GHGRP Refineries Sector Industrial Profile

    EPA Pesticide Factsheets

    EPA's Greenhouse Gas Reporting Program periodically produces detailed profiles of the various industries that report under the program. The profiles available for download below contain detailed analyses for the Refineries industry.

  1. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  2. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized and...

  3. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  4. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized and...

  5. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  6. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized and...

  7. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized and...

  8. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  9. 30 CFR 77.215-4 - Refuse piles; abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Refuse piles; abandonment. 77.215-4 Section 77... MINES Surface Installations § 77.215-4 Refuse piles; abandonment. When a refuse pile is to be abandoned... refuse pile shall be abandoned in accordance with a plan submitted by the operator and approved by the...

  10. Peak oil demand: the role of fuel efficiency and alternative fuels in a global oil production decline.

    PubMed

    Brandt, Adam R; Millard-Ball, Adam; Ganser, Matthew; Gorelick, Steven M

    2013-07-16

    Some argue that peak conventional oil production is imminent due to physical resource scarcity. We examine the alternative possibility of reduced oil use due to improved efficiency and oil substitution. Our model uses historical relationships to project future demand for (a) transport services, (b) all liquid fuels, and (c) substitution with alternative energy carriers, including electricity. Results show great increases in passenger and freight transport activity, but less reliance on oil. Demand for liquids inputs to refineries declines significantly after 2070. By 2100 transport energy demand rises >1000% in Asia, while flattening in North America (+23%) and Europe (-20%). Conventional oil demand declines after 2035, and cumulative oil production is 1900 Gbbl from 2010 to 2100 (close to the U.S. Geological Survey median estimate of remaining oil, which only includes projected discoveries through 2025). These results suggest that effort is better spent to determine and influence the trajectory of oil substitution and efficiency improvement rather than to focus on oil resource scarcity. The results also imply that policy makers should not rely on liquid fossil fuel scarcity to constrain damage from climate change. However, there is an unpredictable range of emissions impacts depending on which mix of substitutes for conventional oil gains dominance-oil sands, electricity, coal-to-liquids, or others.

  11. Bio-Refineries Bioprocess Technologies for Waste-Water Treatment, Energy and Product Valorization

    NASA Astrophysics Data System (ADS)

    Keith Cowan, A.

    2010-04-01

    Increasing pressure is being exerted on communities and nations to source energy from forms other than fossil fuels. Also, potable water is becoming a scarce resource in many parts of the world, and there remains a large divide in the demand and utilization of plant products derived from genetically modified organisms (GMOs) and non-GMOs. The most extensive user and manager of terrestrial ecosystems is agriculture which is also the de facto steward of natural resources. As stated by Miller (2008) no other industry or institution comes close to the comparative advantage held for this vital responsibility while simultaneously providing food, fiber, and other biology-based products, including energy. Since modern commercial agriculture is transitioning from the production of bulk commodities to the provision of standardized products and specific-attribute raw materials for differentiated markets, we can argue that processes such as mass cultivation of microalgae and the concept of bio-refineries be seen as part of a `new' agronomy. EBRU is currently exploring the integration of bioprocess technologies using microalgae as biocatalysts to achieve waste-water treatment, water polishing and endocrine disruptor (EDC) removal, sustainable energy production, and exploitation of the resultant biomass in agriculture as foliar fertilizer and seed coatings, and for commercial extraction of bulk commodities such as bio-oils and lecithin. This presentation will address efforts to establish a fully operational solar-driven microalgae bio-refinery for use not only in waste remediation but to transform waste and biomass to energy, fuels, and other useful materials (valorisation), with particular focus on environmental quality and sustainability goals.

  12. Oil and Gas Wells and Pipelines on U.S. Wildlife Refuges: Challenges for Managers

    PubMed Central

    2015-01-01

    The increased demand for oil and gas places a burden on lands set aside for natural resource conservation. Oil and gas development alters the environment locally and on a much broader spatial scale depending on the intensity and extent of mineral resource extraction. The current increase in oil and gas exploration and production in the United States prompted an update of the number of pipelines and wells associated with oil and gas production on National Wildlife Refuge System (NWRS) lands. We obtained geospatial data on the location of oil and gas wells and pipelines within and close to the boundaries of NWRS lands (units) acquired as fee simple (i.e. absolute title to the surface land) by the U.S. Fish and Wildlife Service. We found that 5,002 wells are located in 107 NWRS units and 595 pipelines transect 149 of the 599 NWRS units. Almost half of the wells (2,196) were inactive, one-third (1,665) were active, and the remainder of the wells were either plugged and abandoned or the status was unknown. Pipelines crossed a total of 2,155 kilometers (1,339 miles) of NWRS fee simple lands. The high level of oil and gas activity warrants follow up assessments for wells lacking information on production type or well status with emphasis on verifying the well status and identifying abandoned and unplugged wells. NWRS fee simple lands should also be assessed for impacts from brine, oil and other hydrocarbon spills, as well as habitat alteration associated with oil and gas, including the identification of abandoned oil and gas facilities requiring equipment removal and site restoration. PMID:25915417

  13. The Abandonment of Social Studies?

    ERIC Educational Resources Information Center

    Griffith, Bryant

    1991-01-01

    Addresses the question of whether the social studies should be abandoned. Discusses Kieran Egan's analysis of the importance of storytelling and Egan's proposal to abandon the social studies curriculum in favor of a pedagogy more consistent with the way children think. Critiques Egan's view and examines implications for educators. (SG)

  14. 75 FR 27192 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-14

    ..., paper mill, saw mill, and oil refinery repairs; casting services for ``grey iron and brass,'' including... surface soil hot spots, sampling of surface water and sediment in the canals, stratigraphic profiling with..., monitor well installation, ground water sampling, and aquifer testing. Foundry operations resulted in...

  15. Petroleum refinery operational planning using robust optimization

    NASA Astrophysics Data System (ADS)

    Leiras, A.; Hamacher, S.; Elkamel, A.

    2010-12-01

    In this article, the robust optimization methodology is applied to deal with uncertainties in the prices of saleable products, operating costs, product demand, and product yield in the context of refinery operational planning. A numerical study demonstrates the effectiveness of the proposed robust approach. The benefits of incorporating uncertainty in the different model parameters were evaluated in terms of the cost of ignoring uncertainty in the problem. The calculations suggest that this benefit is equivalent to 7.47% of the deterministic solution value, which indicates that the robust model may offer advantages to those involved with refinery operational planning. In addition, the probability bounds of constraint violation are calculated to help the decision-maker adopt a more appropriate parameter to control robustness and judge the tradeoff between conservatism and total profit.

  16. Treatment of Refinery Waste Water Using Environmental Friendly Adsorbent

    NASA Astrophysics Data System (ADS)

    Devi, M. Geetha; Al-Moshrafi, Samira Mohammed Khamis; Al Hudaifi, Alaa; Al Aisari, Buthaina Hamood

    2017-12-01

    This research evaluates the effectiveness of activated carbon prepared from walnut shell in the removal of pollutants from refinery waste water by adsorption technique. A series of batch experiments were carried out by varying the effluent solution pH, stirring time, stirring speed and adsorbent dosage in the reduction of pollutants from refinery effluent. Characterization of the adsorbent was performed using Scanning Electron Microscopy (SEM), Brunauer Emmett and Teller (BET) isotherm and Fourier Transform Infrared (FTIR) Spectroscopy. The best quality activated carbon was obtained with a particle size of 0.75 µm, activation temperature of 800 °C and activation time 24 h. The maximum BET surface area obtained was 165.2653 m2/g. The experimental results demonstrates that the highest percentage reduction in COD was 79%, using 0.6 g walnut shell powder at an optimum stirring speed of 100 rpm, at pH 6 and 120 min of contact time. The outcome of the result shows that walnut shell carbon is a potentially useful adsorbent for the removal of pollutants from refinery waste water.

  17. Combined analysis of job and task benzene air exposures among workers at four US refinery operations

    PubMed Central

    Shin, Jennifer (Mi); Unice, Ken M; Gaffney, Shannon H; Kreider, Marisa L; Gelatt, Richard H; Panko, Julie M

    2016-01-01

    Workplace air samples analyzed for benzene at four US refineries from 1976 to 2007 were pooled into a single dataset to characterize similarities and differences between job titles, tasks and refineries, and to provide a robust dataset for exposure reconstruction. Approximately 12,000 non-task (>180 min) personal samples associated with 50 job titles and 4000 task (<180 min) samples characterizing 24 tasks were evaluated. Personal air sample data from four individual refineries were pooled based on a number of factors including (1) the consistent sampling approach used by refinery industrial hygienists over time, (2) the use of similar exposure controls, (3) the comparability of benzene content of process streams and end products, (4) the ability to assign uniform job titles and task codes across all four refineries, and (5) our analysis of variance (ANOVA) of the distribution of benzene air concentrations for select jobs/tasks across all four refineries. The jobs and tasks most frequently sampled included those with highest potential contact with refinery product streams containing benzene, which reflected the targeted sampling approach utilized by the facility industrial hygienists. Task and non-task data were analyzed to identify and account for significant differences within job-area, task-job, and task-area categories. This analysis demonstrated that in general, areas with benzene containing process streams were associated with greater benzene air concentrations compared to areas with process streams containing little to no benzene. For several job titles and tasks analyzed, there was a statistically significant decrease in benzene air concentration after 1990. This study provides a job and task-focused analysis of occupational exposure to benzene during refinery operations, and it should be useful for reconstructing refinery workers’ exposures to benzene over the past 30 years. PMID:26862134

  18. Combined analysis of job and task benzene air exposures among workers at four US refinery operations.

    PubMed

    Burns, Amanda; Shin, Jennifer Mi; Unice, Ken M; Gaffney, Shannon H; Kreider, Marisa L; Gelatt, Richard H; Panko, Julie M

    2017-03-01

    Workplace air samples analyzed for benzene at four US refineries from 1976 to 2007 were pooled into a single dataset to characterize similarities and differences between job titles, tasks and refineries, and to provide a robust dataset for exposure reconstruction. Approximately 12,000 non-task (>180 min) personal samples associated with 50 job titles and 4000 task (<180 min) samples characterizing 24 tasks were evaluated. Personal air sample data from four individual refineries were pooled based on a number of factors including (1) the consistent sampling approach used by refinery industrial hygienists over time, (2) the use of similar exposure controls, (3) the comparability of benzene content of process streams and end products, (4) the ability to assign uniform job titles and task codes across all four refineries, and (5) our analysis of variance (ANOVA) of the distribution of benzene air concentrations for select jobs/tasks across all four refineries. The jobs and tasks most frequently sampled included those with highest potential contact with refinery product streams containing benzene, which reflected the targeted sampling approach utilized by the facility industrial hygienists. Task and non-task data were analyzed to identify and account for significant differences within job-area, task-job, and task-area categories. This analysis demonstrated that in general, areas with benzene containing process streams were associated with greater benzene air concentrations compared to areas with process streams containing little to no benzene. For several job titles and tasks analyzed, there was a statistically significant decrease in benzene air concentration after 1990. This study provides a job and task-focused analysis of occupational exposure to benzene during refinery operations, and it should be useful for reconstructing refinery workers' exposures to benzene over the past 30 years.

  19. Refinery spreadsheet highlights microcomputer process applications

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tucker, M.A.

    1984-01-23

    Microcomputer applications in the process areas at Chevron U.S.A. refineries and at the Chevron Research Co. illustrate how the microcomputer has changed the way we do our jobs. This article will describe major uses of the microcomputer as a personal work tool in Chevron process areas. It will also describe how and why many of Chevron's microcomputer applications were developed and their characteristics. One of our earliest microcomputer applications, developed in late 1981, was an electronic spreadsheet program using a small desktop microcomputer. It was designed to help a refinery planner prepare monthly plans for a small portion of onemore » of our major refineries. This particular microcomputer had a tiny 4-in. screen, and the reports were several strips of print-out from the microcomputer's 3-in.-wide internal printer taped together. In spite of these archaic computing conditions, it was a successful application. It automated what had been very tedious and time-consuming calculations with a pencil, a calculator, and a great deal of erasing. It eliminated filling out large ''horseblanket'' reports. The electronic spreadsheet was also flexible; the planner could easily change the worksheet to match new operating constraints, new process conditions, and new feeds and products. Fortunately, within just a few months, this application graduated to a similar electronic spreadsheet program on a new, more powerful microcomputer. It had a bigger display screen and a letter-size printer. The same application is still in use today, although it has been greatly enhanced and altered to match extensive plant modifications. And there are plans to expand it again onto yet another, more powerful microcomputer.« less

  20. Railroad abandonment.

    DOT National Transportation Integrated Search

    1997-03-25

    Abandonment and discontinuance of railroad service is allowed by federal law which permits a carrier to end its obligation to provide common carrier service over a particular rail line. Although a number of specific reasons may be given for the aband...

  1. Post Oil America and a Renewable Energy Policy Leads to the Abrogation of the Middle East to China

    DTIC Science & Technology

    2009-04-01

    three issues. First is the fear that a terrorist incident on an oil rig or large refinery could disrupt the oil supply. The second is the concern...nuclear plants , wind farms, hydroelectric dams, and large solar arrays. Second, the economic vitality of the global community depends on the major...condensate, but excluding natural gas plant liquids).18 Multiply that amount by the average price of crude in 2006 of $66.4319 per barrel and the oil

  2. Getting cold feet?: Why health care mergers are abandoned.

    PubMed

    Roos, Anne-Fleur; Postma, Jeroen

    2016-01-01

    Despite the frequent occurrence and sizeable consequences of merger abandonment in other sectors, there is no thorough understanding of merger abandonment in health care. The purpose of this study is to improve the understanding of determinants of health care merger abandonment. On the basis of the literature on merger abandonment, we formulated a framework on potential determinants of health care merger abandonment. We then constructed a survey that was sent to 70% of all executives of Dutch health care organizations (response rate = 35%, n = 291). We provide descriptive overviews of open, multiple-response, and multiple-choice questions on merger abandonment and use chi-square tests and Fisher's exact tests to test whether abandoned and completed merger processes differ. About 62% of the respondents were involved in at least one merger process during the period of 2005-2012. Thirty-eight percent of these respondents reported that their last merger case ended prematurely (n = 53). The most frequently mentioned determinants of merger abandonment are changing insights on the desirability and feasibility during merger processes, incompatibilities between executives, and insufficient support for the merger from internal stakeholders. We did not find significant relationships between merger abandonment and executives' previous merger experience, degree of organizational diversification, health care sector, size differences, or other organizational differences. Our findings partially confirm results from previous studies, especially with regard to the importance of changing insights and incompatibilities between the involved executives in merger abandonment. We also find that pressure from internal stakeholders, particularly nonexecutive directors, and distrust, fear, and animosity play an important role in merger abandonment. To minimize the organizational and societal costs of abandoned mergers, we advise executives who engage in mergers to construct backup plans with

  3. 49 CFR 192.727 - Abandonment or deactivation of facilities.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Abandonment or deactivation of facilities. 192.727... Abandonment or deactivation of facilities. (a) Each operator shall conduct abandonment or deactivation of... pipeline facility or each abandoned onshore pipeline facility that crosses over, under or through a...

  4. 49 CFR 195.59 - Abandonment or deactivation of facilities.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Abandonment or deactivation of facilities. 195.59... Abandonment or deactivation of facilities. For each abandoned offshore pipeline facility or each abandoned onshore pipeline facility that crosses over, under or through a commercially navigable waterway, the last...

  5. Metal leaching from refinery waste hydroprocessing catalyst.

    PubMed

    Marafi, Meena; Rana, Mohan S

    2018-05-18

    The present study aims to develop an eco-friendly methodology for the recovery of nickel (Ni), molybdenum (Mo), and vanadium (V) from the refinery waste spent hydroprocessing catalyst. The proposed process has two stages: the first stage is to separate alumina, while the second stage involves the separation of metal compounds. The effectiveness of leaching agents, such as NH 4 OH, (NH 4 ) 2 CO 3 , and (NH 4 ) 2 S 2 O 8 , for the extraction of Mo, V, Ni, and Al from the refinery spent catalyst has been reported as a function of reagent concentration (0.5 to 2.0 molar), leaching time (1 to 6 h), and temperature (35 to 60°C). The optimal leaching conditions were achieved to obtain the maximum recovery of Mo, Ni, and V metals. The effect of the mixture of multi-ammonium salts on the metal extraction was also studied, which showed an adverse effect for Ni and V, while marginal improvement was observed for Mo leaching. The ammonium salts can form soluble metal complexes, in which stability or solubility depends on the nature of ammonium salt and the reaction conditions. The extracted metals and support can be reused to synthesize a fresh hydroprocessing catalyst. The process will reduce the refinery waste and recover the expensive metals. Therefore, the process is not only important from an environmental point of view but also vital from an economic perspective.

  6. Western Abandoned Uranium Mine Region Maps

    EPA Pesticide Factsheets

    Map of the Western Abandoned Uranium Mine (AUM) Region, more than 100 abandoned uranium mine claims generally located along the Little Colorado River and Highway 89 in the Cameron, Coalmine Canyon, Bodaway/Gap, and Leupp Chapters in Northern Arizona.

  7. Oil industry and road traffic fatalities in contemporary Colombia.

    PubMed

    Tasciotti, Luca; Alejo, Didier; Romero, Andrés

    2016-12-01

    This paper studies the effects that oil extraction activities in Colombia have on the number of dead/injured people as a consequence of road-related accidents. Starting in 2004, the increasing exploitation of oil wells in some Colombian departments has worsened the traffic conditions due to the increased presence of trucks transporting crude oil from the wells to the refineries; this phenomenon has not been accompanied by an improvement in the road system with dramatic consequences in terms of road viability. The descriptive and empirical analysis presented here focuses on the period 2004-2011; results from descriptive statistics indicate a positive relationship between the presence of oil extraction activities and the number of either dead/injured people. Panel regressions for the period 2004-2011 confirm that, among other factors, the presence of oil-extraction activities did play a positive and statistical significant role in increasing the number of dead/injured people.

  8. Assessing the compatibility of the management of standardized procedures with the complexity of a sociotechnical system: case study of a control room in an oil refinery.

    PubMed

    Saurin, Tarcisio Abreu; Gonzalez, Santiago Sosa

    2013-09-01

    Although the need for the management of complex socio-technical systems (STS) to be compatible with the nature of those systems is widely recognized, there are few guidelines on how to determine the actual extent of this compatibility. The purpose of this study is to assess how compatible the management of standardized procedures (SPs) is with the nature of a complex STS. To this end, a case study was made of a control room in an oil refinery, involving the following stages: (a) delimitation of the investigated STS; (b) description of the STS according to a set of characteristics of complex STS; (c) application of two types of questionnaires to thirty workers - one of them to assess their perceptions about the applicability of seven principles of SPs management in complex STS and the other to determine their perceptions about the actual use of these principles; and (d) a feedback meeting with workers to discuss the results of the assessment. The assessment is discussed in terms of its limitations, usefulness and ease of use of the data collection and analysis tools. Copyright © 2013 Elsevier Ltd and The Ergonomics Society. All rights reserved.

  9. Can lung cancer risk among nickel refinery workers be explained by occupational exposures other than nickel?

    PubMed

    Grimsrud, Tom K; Berge, Steinar R; Haldorsen, Tor; Andersen, Aage

    2005-03-01

    Exposures in nickel refineries represent complex chemical mixtures, but only the effect of nickel has been evaluated quantitatively in epidemiologic studies of nickel workers. For a Norwegian refinery, time- and department-specific exposure estimates were developed for arsenic, sulfuric acid mists, and cobalt in air on the basis of personal measurements and chemical data on raw materials and process intermediates. Exposure to asbestos, as well as employment in high-risk occupations outside the refinery, were assessed. We conducted a case-control study nested in a cohort of refinery workers, with 213 cases (diagnosed 1952-1995) and 525 age-matched controls. We analyzed lung cancer risk, adjusted for smoking, by cumulative exposure and duration of work. There was a substantial association between cumulative exposure to water-soluble nickel and lung cancer risk. Weaker effects were suggested for exposure to arsenic at the refinery and for occupational exposures outside the refinery for 15 years or more. No detectable excess risk was found for refinery exposure to asbestos or sulfuric acid mists, and no dose-related increase in risk was seen from cobalt. Exposure to water-soluble nickel remained the most likely explanation for the excess lung cancer risk in the cohort. Other occupational exposures did not confound the strong dose-related effect of nickel to any appreciable degree.

  10. Optimal Design of Air Quality Monitoring Network and its Application in an Oil Refinery Plant: An Approach to Keep Health Status of Workers.

    PubMed

    ZoroufchiBenis, Khaled; Fatehifar, Esmaeil; Ahmadi, Javad; Rouhi, Alireza

    2015-01-01

    Industrial air pollution is a growing challenge to humane health, especially in developing countries, where there is no systematic monitoring of air pollution. Given the importance of the availability of valid information on population exposure to air pollutants, it is important to design an optimal Air Quality Monitoring Network (AQMN) for assessing population exposure to air pollution and predicting the magnitude of the health risks to the population. A multi-pollutant method (implemented as a MATLAB program) was explored for configur-ing an AQMN to detect the highest level of pollution around an oil refinery plant. The method ranks potential monitoring sites (grids) according to their ability to represent the ambient concentration. The term of cluster of contiguous grids that exceed a threshold value was used to calculate the Station Dosage. Selection of the best configuration of AQMN was done based on the ratio of a sta-tion's dosage to the total dosage in the network. Six monitoring stations were needed to detect the pollutants concentrations around the study area for estimating the level and distribution of exposure in the population with total network efficiency of about 99%. An analysis of the design procedure showed that wind regimes have greatest effect on the location of monitoring stations. The optimal AQMN enables authorities to implement an effective program of air quality management for protecting human health.

  11. 32 CFR 644.494 - Donation, abandonment or destruction.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Donation, abandonment or destruction. 644.494 Section 644.494 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) REAL... Land) § 644.494 Donation, abandonment or destruction. (a) General. Improvements may be abandoned...

  12. 32 CFR 644.494 - Donation, abandonment or destruction.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 32 National Defense 4 2011-07-01 2011-07-01 false Donation, abandonment or destruction. 644.494 Section 644.494 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) REAL... Land) § 644.494 Donation, abandonment or destruction. (a) General. Improvements may be abandoned...

  13. 32 CFR 644.494 - Donation, abandonment or destruction.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 32 National Defense 4 2012-07-01 2011-07-01 true Donation, abandonment or destruction. 644.494 Section 644.494 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) REAL... Land) § 644.494 Donation, abandonment or destruction. (a) General. Improvements may be abandoned...

  14. 32 CFR 644.494 - Donation, abandonment or destruction.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 4 2013-07-01 2013-07-01 false Donation, abandonment or destruction. 644.494 Section 644.494 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) REAL... Land) § 644.494 Donation, abandonment or destruction. (a) General. Improvements may be abandoned...

  15. 32 CFR 644.494 - Donation, abandonment or destruction.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 32 National Defense 4 2014-07-01 2013-07-01 true Donation, abandonment or destruction. 644.494 Section 644.494 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) REAL... Land) § 644.494 Donation, abandonment or destruction. (a) General. Improvements may be abandoned...

  16. Energy Intensity and Greenhouse Gas Emissions from Oil Production in the Eagle Ford Shale

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yeh, Sonia; Ghandi, Abbas; Scanlon, Bridget R.

    A rapid increase in horizontal drilling and hydraulic fracturing in shale and “tight” formations that began around 2000 has resulted in record increases in oil and natural gas production in the U.S. This study examines energy consumption and greenhouse gas (GHG) emissions from crude oil and natural gas produced from ~8,200 wells in the Eagle Ford Shale in southern Texas from 2009 to 2013. Our system boundary includes processes from primary exploration wells to the refinery entrance gate (henceforth well-to-refinery or WTR). The Eagle Ford includes four distinct production zones—black oil (BO), volatile oil (VO), condensate (C), and dry gasmore » (G) zones—with average monthly gas-to-liquids ratios (thousand cubic feet per barrel—Mcf/bbl) varying from 0.91 in the BO zone to 13.9 in the G zone. Total energy consumed in drilling, extracting, processing, and operating an Eagle Ford well is ~1.5% of the energy content of the produced crude and gas in the BO and VO zones, compared with 2.2% in the C and G zones. On average, the WTR GHG emissions of gasoline, diesel, and jet fuel derived from crude oil produced in the BO and VO zones in the Eagle Ford play are 4.3, 5.0, and 5.1 gCO2e/MJ, respectively. Comparing with other known conventional and unconventional crude production where upstream GHG emissions are in the range 5.9–30 gCO2e/MJ, oil production in the Eagle Ford has lower WTR GHG emissions.« less

  17. Tanker spills Norwegian crude oil off Shetlands

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1993-01-11

    This paper reports that crude oil was spilling last week from the U.S. owned Braer tanker after the 89,000 dwt vessel ran aground on the south end of Scotland's Shetland Islands. Workers were trying to assess the extent of damage to the tanker, shoreline, and wildlife after the January 5 accident. Braer's cargo amounted to 607,000 bbl of Norwegian oil bound for Canada. Braer loaded its cargo and sailed January 3 from Den norske stats oljeselskap AS's Mongstad, Norway, terminal with crude from Gullfaks field in the Norwegian North Sea. The $11 million shipment was destined for Ultramar Canada Inc.'smore » 125,000 b/d refinery at St. Romuald, Que.« less

  18. Reduce oil and grease content in wastewater

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Capps, R.W.; Matelli, G.N.; Bradford, M.L.

    Poor water quality is often blamed on biological oxidation unit malfunction. However, poorly treated water entering the bio-unit is more often the problem. At the microscopic level, oil/water-separation dynamics are influenced by pH, fluid velocity, temperature, and unit volumes. Oily water's physical and chemical properties affect pretreatment systems such as API separators, corrugated plate interception (CPI) separators, air flotation and equalization systems. A better understanding of pretreatment systems' limits and efficiencies can improve wastewater quality before it upsets the biological oxidation (BIOX). Oil contamination in refinery wastewater originates from desalting, steam stripping, product treating, tank drains, sample drains and equipmentmore » washdown. The largest volumetric contributors are cooling tower blowdowns and contaminated stormwater. The paper describes the BIOX process; oil/water separation; oil/water emulsions and colloidal solutions; air flotation; surfactants; DAF (dissolved air flotation) process; IAF (induced air flotation) process; equalization; load factors; salts; and system design.« less

  19. 77 FR 63320 - Agency Information Collection Activities: Petroleum Refineries in Foreign Trade Sub-zones

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-16

    ... Activities: Petroleum Refineries in Foreign Trade Sub-zones AGENCY: U.S. Customs and Border Protection... Budget (OMB) for review and approval in accordance with the Paperwork Reduction Act: Petroleum Refineries... CBP is soliciting comments concerning the following information collection: Title: Petroleum...

  20. 37 CFR 2.66 - Revival of abandoned applications.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Applicants § 2.66 Revival of abandoned applications. (a) The applicant may file a petition to revive an... for filing a petition to revive an application abandoned because the applicant did not timely respond... proposed response. (c) The requirements for filing a petition to revive an application abandoned because...

  1. 40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... average benzene concentration determined? 80.1238 Section 80.1238 Protection of Environment ENVIRONMENTAL... Benzene Gasoline Benzene Requirements § 80.1238 How is a refinery's or importer's average benzene concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported...

  2. 40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... average benzene concentration determined? 80.1238 Section 80.1238 Protection of Environment ENVIRONMENTAL... Benzene Gasoline Benzene Requirements § 80.1238 How is a refinery's or importer's average benzene concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported...

  3. 40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... average benzene concentration determined? 80.1238 Section 80.1238 Protection of Environment ENVIRONMENTAL... Benzene Gasoline Benzene Requirements § 80.1238 How is a refinery's or importer's average benzene concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported...

  4. 40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... average benzene concentration determined? 80.1238 Section 80.1238 Protection of Environment ENVIRONMENTAL... Benzene Gasoline Benzene Requirements § 80.1238 How is a refinery's or importer's average benzene concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported...

  5. 40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... average benzene concentration determined? 80.1238 Section 80.1238 Protection of Environment ENVIRONMENTAL... Benzene Gasoline Benzene Requirements § 80.1238 How is a refinery's or importer's average benzene concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported...

  6. The Impact of Post-Training on Job Performance in Nigera's Oil Industry

    ERIC Educational Resources Information Center

    Aibieyi, Stanley

    2012-01-01

    The Nigeria's oil industry has been criticized for some time now for its inability to render adequate services to the general public. This criticism is predicated on the fact that the standards of productivity in their services are low and that their facilities (i.e. the refineries) are not working up to capacity. This is evident in their…

  7. 37 CFR 1.138 - Express abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 37 Patents, Trademarks, and Copyrights 1 2010-07-01 2010-07-01 false Express abandonment. 1.138 Section 1.138 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF... Patent and Trademark Office. Express abandonment of the application may not be recognized by the Office...

  8. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a motor...

  9. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 32 National Defense 4 2011-07-01 2011-07-01 false Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a motor...

  10. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 32 National Defense 4 2012-07-01 2011-07-01 true Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a motor...

  11. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 32 National Defense 4 2014-07-01 2013-07-01 true Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a motor...

  12. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 4 2013-07-01 2013-07-01 false Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a motor...

  13. Growth enhancement of effective microorganisms for bioremediation of crude oil contaminated waters.

    PubMed

    Mukred, Abdualdaim Mohammed; Abd-Hamid, Aidil; Hamzah, Ainon; Yusoff, Wan Mohtar Wan

    2008-07-01

    The bioremediation of polluted groundwater, wastewater aeration pond and biopond sites was investigated using bacteria isolated from these sites located at the oil refinery Terengganu Malaysia. Out of 62 isolates, only 16 isolates from groundwater (8) and wastewater aeration pond (3) and biopond (5) were chosen based on growth medium containing 1% (v/v) Tapis crude oil. Only four isolates; Acinetobacter faecalis, Staphylococcus sp., Pseudomonas putida and Neisseria elongata showed percentage biodegradation of crude oil more than 50% after 5 days using Mineral Salts Medium (MSM). The effect of physical parameters (temperature, pH and agitation) on growth by all four strains showed a maximum growth in MSM medium with 1% Tapis crude oil at 37 degrees C with pH 7 and agitation of 130 rpm.

  14. Advanced purification of petroleum refinery wastewater by catalytic vacuum distillation.

    PubMed

    Yan, Long; Ma, Hongzhu; Wang, Bo; Mao, Wei; Chen, Yashao

    2010-06-15

    In our work, a new process, catalytic vacuum distillation (CVD) was utilized for purification of petroleum refinery wastewater that was characteristic of high chemical oxygen demand (COD) and salinity. Moreover, various common promoters, like FeCl(3), kaolin, H(2)SO(4) and NaOH were investigated to improve the purification efficiency of CVD. Here, the purification efficiency was estimated by COD testing, electrolytic conductivity, UV-vis spectrum, gas chromatography-mass spectrometry (GC-MS) and pH value. The results showed that NaOH promoted CVD displayed higher efficiency in purification of refinery wastewater than other systems, where the pellucid effluents with low salinity and high COD removal efficiency (99%) were obtained after treatment, and the corresponding pH values of effluents varied from 7 to 9. Furthermore, environment estimation was also tested and the results showed that the effluent had no influence on plant growth. Thus, based on satisfied removal efficiency of COD and salinity achieved simultaneously, NaOH promoted CVD process is an effective approach to purify petroleum refinery wastewater. Copyright 2010 Elsevier B.V. All rights reserved.

  15. 40 CFR 144.63 - Financial assurance for plugging and abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... current plugging and abandonment cost estimate, except as provided in § 144.70(g), divided by the number... days after receiving bills for plugging and abandonment activities, the Regional Administrator will... abandonment activities, the Regional Administrator will determine whether the plugging and abandonment...

  16. Mortality among workers in a nickel refinery and alloy manufacturing plant in West Virginia.

    PubMed

    Enterline, P E; Marsh, G M

    1982-06-01

    Workers from a nickel refinery at Huntington, W. Va., which received a nickel matte from smelters in Ontario, Canada, during 1922-47 were studied for excesses in sinonasal and lung cancers. Other workers who were in a nickel alloy production plant operated in conjunction with the refinery but who did not work in the refinery were also studied. Evidence is presented on the existence of a nasal cancer hazard and possibly a lung cancer hazard among workers employed in the nickel refinery. Two of these workers developed a sinonasal cancer. Evidence of a respiratory cancer hazard in other parts of the plant before or after 1947 is weak, and the observed results could be due to chance variations from the mortality experience of the standard reference populations. Among nonrefinery workers hired while the nickel refinery was in operation, 2 employees had a probable sinonasal cancer. The first employee worked in a high-temperature conversion process where nickel carbonate was decomposed to nickel oxide, and the second employee is believed to have done maintenance work in the plant where this process was used. For both cohorts combined there were slight overall excesses in lung, stomach, and prostate cancers with some evidence of a dose-response relationship for these cancers.

  17. Who Says There Is No Life after Abandonment? A Grounded Theory on the Coping of Abandoned Filipino Elderly in Nursing Homes

    ERIC Educational Resources Information Center

    de Guzman, Allan B.; Lacorte, Jeremy C.; Lacsamana, Andrea Keith G.; Lagac, Mark Lawrence M.; Laguador, Jobel M.; Lapid, Jazminn Jessica R.; Lee, Lyndcie Miriele C.

    2012-01-01

    Cases of abandoned elderly are increasing worldwide. By and large, this group struggles with the sudden change in living arrangement as well as abandonment by their families. Consequently, many elderly are forced into living in nursing homes for the remainder of their lives. Abandonment among these elderly negatively affects how they view…

  18. Desulfovibrio tunisiensis sp. nov., a novel weakly halotolerant, sulfate-reducing bacterium isolated from exhaust water of a Tunisian oil refinery.

    PubMed

    Ben Ali Gam, Zouhaier; Oueslati, Ridha; Abdelkafi, Slim; Casalot, Laurence; Tholozan, Jean Luc; Labat, Marc

    2009-05-01

    A novel weakly halotolerant, sulfate-reducing bacterium, designated strain RB22(T), was isolated from exhaust water of a Tunisian oil refinery. Cells of strain RB22(T) were Gram-negative, motile, vibrio-shaped or sigmoid and non-spore-forming, and occurred singly or in chains. Strain RB22(T) grew between 15 and 45 degrees C (optimum, 37 degrees C) and at pH 4.5 to 9 (optimum, pH 7). NaCl was not required for growth, but the strain tolerated high NaCl concentrations (up to 70 g l(-1)) with an optimum of 40 g l(-1). Sulfate, thiosulfate, sulfite and elemental sulfur served as electron acceptors, but not fumarate. Nitrate and nitrite were not reduced. Strain RB22(T) utilized lactate, formate, fumarate, succinate, glycerol, H(2)+CO(2) and methanol as substrates. The DNA G+C content was found to be 59.6 mol%. Phylogenetic analysis based on the 16S rRNA gene revealed that the isolate was a member of the genus Desulfovibrio, with no close relatives at the species level (16S rRNA gene sequence similarity of less than 95 %). Strain RB22(T) exhibited levels of 16S rRNA gene sequence similarity of 94.6 and 94.12 % to the type strains of the closely related species Desulfovibrio aespoeensis and Desulfovibrio dechloracetivorans, respectively. On the basis of genotypic and phylogenetic characteristics, and significant phenotypic differences, we suggest that strain RB22(T) represents a novel species, for which the name Desulfovibrio tunisiensis sp. nov. is proposed. The type strain is RB22(T) (=NCIMB 14400(T)=JCM 15076(T)=DSM 19275(T)).

  19. Kidney cancer and hydrocarbon exposures among petroleum refinery workers.

    PubMed

    Poole, C; Dreyer, N A; Satterfield, M H; Levin, L; Rothman, K J

    1993-12-01

    To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. To each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of "present" or "absent" were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refinery work history), three groups appeared to be at increased risk: laborers (RR = 1.9, 95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5, 95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9).

  20. Tesoro Los Angeles Refinery Integration and Compliance Project

    EPA Pesticide Factsheets

    EPA Region 9 has two announcements pertaining to the Los Angeles Refinery Integration and Compliance project (LARIC project): permit revisions meet all CAA requirements and federal PSD permitting provisions do not apply to this project.

  1. Crimes and misdemeanours: the case of child abandonment.

    PubMed

    Giordano, S

    2007-01-01

    In 2002, a child was abandoned in a Burger King restaurant in Amsterdam by a Chinese woman, who hoped that the baby would be picked up by someone able to give the child a better life. She was convicted for child abandonment and imprisoned. Whereas some forms of child abandonment are criminalised, others are socially accepted and not even on the ethics agenda. This paper is an invitation to reflect on the inconsistency in the ways in which we prosecute, punish or try to correct some forms of child abandonment and yet make allowances for others.

  2. Experiment on the Effects of Storage Duration of Biodiesel produced from Crude Palm Oil, Waste Cooking oil and Jatropha

    NASA Astrophysics Data System (ADS)

    Nanihar, Nadiarulah; Khalid, Amir; Mustaffa, Norrizal; Jaat, Norrizam; Sapit, Azwan; Razali, Azahari; Sunar, Norshuhaila Mohamed

    2017-10-01

    Biodiesel based on vegetable oil is an alternative that had various advantage in term of sustainability and environmental attractive compare to others conventional diesel. Biodiesel is product of any fat or oil that derived from any organic sources through a refinery process called transesterification process. This research investigates the effects of storage duration and variant ambient condition on the biodiesel properties and characteristics. In this study, there are three types of blending which is 5vol% blends ( 5vol% plant oil 95vol% diesel), 10vol% blending (10vol% plant oil and 90vol% diesel) and 15vol% blending (15vol% plant oil and 85vol% diesel) each called CPO5 (crude palm oil 5vol%), CPO10 (crude palm oil 10vol%),CPO15 (crude palm oil 15vol%), JO5 (jatropha oil 5vol%), JO10 (jatropha oil 10vol%),and JO15 (jatropha oil 15vol%) respectively. Biodiesel samples were stored at indoor condition and outdoor condition for a 3 months period. The fuel properties such as acid value, viscosity, density, water content and flash point are observed with the laboratory instrument. Flash point value and water content increased under both of indoor and outdoor condition and a steady data for viscosity and density. However, acid value at indoor condition nearly constant but increased dramatically for outdoor condition over the time.

  3. Revegetation strategies for bauxite refinery residue: a case study of Alcan Gove in Northern Territory, Australia.

    PubMed

    Wehr, J Bernhard; Fulton, Ian; Menzies, Neal W

    2006-03-01

    Alumina extraction from bauxite ore with strong alkali produces waste bauxite refinery residue consisting of residue sand and red mud. The amount and composition of refinery residue depend on the purity of the bauxite ore and extraction conditions, and differs between refineries. The refinery residue is usually stored in engineered disposal areas that eventually have to be revegetated. This is challenging because of the alkaline and sodic nature of the residue. At Alcan Gove's bauxite refinery in Gove, Northern Territory, Australia, research into revegetation of bauxite residue has been conducted since the mid-1970s. In this review, we discuss approaches taken by Alcan Gove to achieve revegetation outcomes (soil capping of refinery residue) on wet-slurry disposal areas. Problems encountered in the past include poor drainage and water logging during the wet season, and salt scalding and capillary rise during the dry season. The amount of available water in the soil capping is the most important determinant of vegetation survival in the seasonally dry climate. Vegetation cover was found to prevent deterioration of the soil cover by minimising capillary rise of alkalinity from the refinery residue. The sodicity and alkalinity of the residue in old impoundments has diminished slightly over the 25 years since it was deposited. However, development of a blocky structure in red mud, presumably due to desiccation, allows root penetration, thereby supplying additional water to salt and alkali-tolerant plant species. This has led to the establishment of an ecosystem that approaches a native woodland.

  4. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.

    2013-04-01

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotopemore » mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.« less

  5. Biodegradation of oil tank bottom sludge using microbial consortia.

    PubMed

    Gallego, José Luis R; García-Martínez, María Jesús; Llamas, Juan F; Belloch, Carmen; Peláez, Ana I; Sánchez, Jesús

    2007-06-01

    We present a rationale for the selection of a microbial consortia specifically adapted to degrade toxic components of oil refinery tank bottom sludge (OTBS). Sources such as polluted soils, petrochemical waste, sludge from refinery-wastewater plants, and others were used to obtain a collection of eight microorganisms, which were individually tested and characterized to analyze their degradative capabilities on different hydrocarbon families. After initial experiments using mixtures of these strains, we developed a consortium consisting of four microorganisms (three bacteria and one yeast) selected in the basis of their cometabolic effects, emulsification properties, colonization of oil components, and degradative capabilities. Although the specific contribution each of the former parameters makes is not clearly understood, the activity of the four-member consortium had a strong impact not only on linear alkane degradation (100%), but also on the degradation of cycloalkanes (85%), branched alkanes (44%), and aromatic and sulphur-aromatic compounds (31-55%). The effectiveness of this consortium was significantly superior to that obtained by individual strains, commercial inocula or an undefined mixture of culturable and non-culturable microorganisms obtained from OTBS-polluted soil. However, results were similar when another consortium of four microorganisms, previously isolated in the same OTBS-polluted soil, was assayed.

  6. Abandoned Mine Lands

    EPA Pesticide Factsheets

    Abandoned Mine Lands are those lands, waters, and surrounding watersheds where extraction, beneficiation, or processing of ores and minerals (excluding coal) has occurred. These lands also include areas where mining or processing activity is inactive.

  7. The determination of water in crude oil and transformer oil reference materials.

    PubMed

    Margolis, Sam A; Hagwood, Charles

    2003-05-01

    The measurement of the amount of water in oils is of significant economic importance to the industrial community, particularly to the electric power and crude oil industries. The amount of water in transformer oils is critical to their normal function and the amount of water in crude oils affects the cost of the crude oil at the well head, the pipeline, and the refinery. Water in oil Certified Reference Materials (CRM) are essential for the accurate calibration of instruments that are used by these industries. Three NIST Standard Reference Materials (SRMs) have been prepared for this purpose. The water in these oils has been measured by both coulometric and volumetric Karl Fischer methods. The compounds (such as sulfur compounds) that interfere with the Karl Fischer reaction (interfering substances) and inflate the values for water by also reacting with iodine have been measured coulometrically. The measured water content of Reference Material (RM) 8506a Transformer Oil is 12.1+/-1.9 mg kg(-1) (plus an additional 6.2+/-0.9 mg kg(-1) of interfering substances). The measured water content of SRM 2722 Sweet Crude Oil, is 99+/-6 mg kg(-1) (plus an additional 5+/-2 mg kg(-1) of interfering substances). The measured water content of SRM 2721 Sour Crude Oil, is 134+/-18 mg kg(-1) plus an additional 807+/-43 mg kg(-1) of interfering substances. Interlaboratory studies conducted with these oil samples (using SRM 2890, water saturated 1-octanol, as a calibrant) are reported. Some of the possible sources of bias in these measurements were identified, These include: improperly calibrated instruments, inability to measure the calibrant accurately, Karl Fischer reagent selection, and volatilization of the interfering substances in SRM 2721.

  8. Causes, outcome and prevention of abandonment in retinoblastoma in India.

    PubMed

    Kumar, Archana; Moulik, Nirmalya Roy; Mishra, Ravi Krishna; Kumar, Dipak

    2013-05-01

    The high-cure rates of 90% in retinoblastoma are not replicated in developing countries due to late presentation and poor compliance to treatment. The present study takes a closer look at causes of abandonment of therapy and effectiveness of counselling in reducing abandonment. A retrospective study of children with retinoblastoma registered at our centre from March 2008 through August 2011. Fifty (49.50%) of 101 children registered for treatment abandoned therapy. Abandonment rates were significantly higher in rural as compared to urban children (P = 0.02). There was no significant difference in rate of abandonment between stages or laterality of disease and other socio-demographic factors. Telephone calls were more effective than letters in tracing patients (31.2% vs. 2.4%). Major reasons cited behind abandonment were financial problems (30%) and unwillingness to enucleate (20%). Of the 12 children who returned and were retreated 6 (50%) died of progressive disease. Nineteen (73%) of those who did not return died at home. Abandonment rates steadily declined from 71.42% in 2008 to 16.66% in 2011 (P = 0.01) due to effective pre-abandonment counselling by a support team under the National Retinoblastoma Registry of India from 2009. Abandonment rates for children with retinoblastoma continue to be unacceptably high. Rural background, financial constraints and hesitancy to enucleate were important causes behind abandonment. Outcome of patients who abandoned treatment was uniformly dismal. Inclusion of support team and intensified initial counselling helped in improving compliance. Copyright © 2013 Wiley Periodicals, Inc.

  9. Western Abandoned Uranium Mine Region Fact Sheets

    EPA Pesticide Factsheets

    Fact sheets related to Western Abandoned Uranium Mine (AUM) Region, more than 100 abandoned uranium mine claims located along the Little Colorado River and Highway 89, ain the Cameron, Coalmine Canyon, Bodaway/Gap, and Leupp Chapters in Northern Arizona.

  10. NPDES Permit for Chemtrade Refinery Services in Wyoming

    EPA Pesticide Factsheets

    Under NPDES permit WY-0034207, Chemtrade Refinery Services, Inc. is authorized to discharge from its wastewater treatment facility located in Fremont County,Wyoming, to an unnamed drainage way that flows into the Little Wind River near St. Stephens, Wyo.

  11. The USGS Abandoned Mine Lands Initiative: Protecting and restoring the environment near abandoned mine lands

    USGS Publications Warehouse

    ,

    1999-01-01

    The Abandoned Mine Lands (AML) Initiative is part of a larger strategy of the U.S. Department of the Interior and the U.S. Department of Agriculture to clean up Federal lands contaminated by abandoned mines.Thousands of abandond hard-rock metal mines (such as gold, copper, lead, and zinc) have left a dual legacy across the Western United States. They reflect the historic development of the west, yet at the same time represent a possible threat to human health and local ecosystems.Abandoned Mine Lands (AML) are areas adjacent to or affected by abandoned mines. AML's often contain unmined mineral deposits, mine dumps (the ore and rock removed to get to the ore deposits), and tailings (the material left over from the ore processing) that contaminate the surrounding watershed and ecosystem. For example, streams near AML's can contain metals and (or) be so acidic that fish and aquatic insects cannot live in them.Many of these abandoned hard-rock mines are located on or adjacent to public lands administered by the Bureau of Land Management, National Park Service, and U.S. Forest Service. These federal land management agencies and the USGS are committed to mitigating the adverse effects that AML's can have on water quality and stream habitats.The USGS AML Initiative began in 1997 and will continue through 2001 in two pilot watersheds - the Boulder River basin in southwestern Montana and the upper Animas River basin in southwestern Colorado. The USGS is providing a wide range of scientific expertise to help land managers minimize and, where possible, eliminate the adverse environmental effects of AML's. USGS ecologists, geologists, water quality experts, hydrologists, geochemists, and mapping and digital data collection experts are collaborating to provide the scientific knowledge needed for an effective cleanup of AML's.

  12. Optimal Design of Air Quality Monitoring Network and its Application in an Oil Refinery Plant: An Approach to Keep Health Status of Workers

    PubMed Central

    ZoroufchiBenis, Khaled; Fatehifar, Esmaeil; Ahmadi, Javad; Rouhi, Alireza

    2015-01-01

    Background: Industrial air pollution is a growing challenge to humane health, especially in developing countries, where there is no systematic monitoring of air pollution. Given the importance of the availability of valid information on population exposure to air pollutants, it is important to design an optimal Air Quality Monitoring Network (AQMN) for assessing population exposure to air pollution and predicting the magnitude of the health risks to the population. Methods: A multi-pollutant method (implemented as a MATLAB program) was explored for configur­ing an AQMN to detect the highest level of pollution around an oil refinery plant. The method ranks potential monitoring sites (grids) according to their ability to represent the ambient concentration. The term of cluster of contiguous grids that exceed a threshold value was used to calculate the Station Dosage. Selection of the best configuration of AQMN was done based on the ratio of a sta­tion’s dosage to the total dosage in the network. Results: Six monitoring stations were needed to detect the pollutants concentrations around the study area for estimating the level and distribution of exposure in the population with total network efficiency of about 99%. An analysis of the design procedure showed that wind regimes have greatest effect on the location of monitoring stations. Conclusion: The optimal AQMN enables authorities to implement an effective program of air quality management for protecting human health. PMID:26933646

  13. Bioflocculant production and biosorption of zinc and lead by a novel bacterial species, Achromobacter sp. TERI-IASST N, isolated from oil refinery waste.

    PubMed

    Subudhi, Sanjukta; Batta, Neha; Pathak, Mihirjyoti; Bisht, Varsha; Devi, Arundhuti; Lal, Banwari; Al khulifah, Bader

    2014-10-01

    A bioflocculant-producing bacterial isolate designated as 'TERI-IASST N' was isolated from activated sludge samples collected from an oil refinery. This isolate demonstrated maximum bioflocculation activity (74%) from glucose among 15 different bioflocculant-producing bacterial strains isolated from the sludge samples and identified as Achromobacter sp. based on 16S rRNA gene sequence. Optimization of pH and supplementation of urea as nitrogen source in the production medium enhanced the flocculation activity of strain TERI-IASST N to 84% (at pH 6). This strain revealed maximum flocculation activity (90%) from sucrose compared to the flocculation activity observed from other carbon sources as investigated (glucose, lactose, fructose, maltose and starch). Ca(2+) served as the suitable divalent cation for maximum bioflocculation activity of TERI-IASST strain N. Maximum flocculation activity was observed at optimum C/N ratio of 1. Flocculation activity of this strain decreased to 75% in the presence of heavy metals; Zn, Pb, Ni, Cu and Cd. In addition strain N revealed considerable biosorption of Zn (430mgL(-1)) and Pb (30mgL(-1)). Bioflocculant yield of strain N was 10.5gL(-1). Fourier transform infrared spectrum indicated the presence of carboxyl, hydroxyl, and amino groups, typical of glycoprotein. Spectroscopic analysis of bioflocculant by nuclear magnetic resonance revealed that it is a glycoprotein, consisting of 57% total sugar and 13% protein. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Carbon-13 and proton nuclear magnetic resonance analysis of shale-derived refinery products and jet fuels and of experimental referee broadened-specification jet fuels

    NASA Technical Reports Server (NTRS)

    Dalling, D. K.; Bailey, B. K.; Pugmire, R. J.

    1984-01-01

    A proton and carbon-13 nuclear magnetic resonance (NMR) study was conducted of Ashland shale oil refinery products, experimental referee broadened-specification jet fuels, and of related isoprenoid model compounds. Supercritical fluid chromatography techniques using carbon dioxide were developed on a preparative scale, so that samples could be quantitatively separated into saturates and aromatic fractions for study by NMR. An optimized average parameter treatment was developed, and the NMR results were analyzed in terms of the resulting average parameters; formulation of model mixtures was demonstrated. Application of novel spectroscopic techniques to fuel samples was investigated.

  15. 39 CFR 946.11 - Disposition of property declared abandoned.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... DISPOSITION OF STOLEN MAIL MATTER AND PROPERTY ACQUIRED BY THE POSTAL INSPECTION SERVICE FOR USE AS EVIDENCE § 946.11 Disposition of property declared abandoned. Property declared abandoned, including cash, and... 39 Postal Service 1 2010-07-01 2010-07-01 false Disposition of property declared abandoned. 946.11...

  16. 39 CFR 946.11 - Disposition of property declared abandoned.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... DISPOSITION OF STOLEN MAIL MATTER AND PROPERTY ACQUIRED BY THE POSTAL INSPECTION SERVICE FOR USE AS EVIDENCE § 946.11 Disposition of property declared abandoned. Property declared abandoned, including cash, and... 39 Postal Service 1 2011-07-01 2011-07-01 false Disposition of property declared abandoned. 946.11...

  17. Characteristics of volatile organic compounds (VOCs) emitted from a petroleum refinery in Beijing, China

    NASA Astrophysics Data System (ADS)

    Wei, Wei; Cheng, Shuiyuan; Li, Guohao; Wang, Gang; Wang, Haiyan

    2014-06-01

    This study made a field VOCs (volatile organic compounds) measurement for a petroleum refinery in Beijing by determining 56 PAMS VOCs, which are demanded for photochemical assessment in US, and obtained the characteristics of VOCs emitted from the whole refinery and from its inner main devices. During the monitoring period, this refinery brought about an average increase of 61 ppbv in the ambient TVOCs (sum of the PAMS VOCs) at the refinery surrounding area, while the background of TVOCs there was only 10-30 ppbv. In chemical profile, the VOCs emitted from the whole refinery was characteristic by isobutane (8.7%), n-butane (7.9%), isopentane (6.3%), n-pentane (4.9%%), n-hexane (7.6%), C6 branched alkanes (6.0%), propene (12.7%), 1-butene (4.1%), benzene (7.8%), and toluene (5.9%). On the other hand, the measurement for the inner 5 devices, catalytic cracking units (CCU2 and CCU3), catalytic reforming unit (CRU), tank farm (TF), and wastewater treatment(WT), revealed the higher level of VOCs pollutions (about several hundred ppbv of TVOCs), and the individual differences in VOCs chemical profiles. Based on the measured speciated VOCs data at the surrounding downwind area, PMF receptor model was applied to identify the VOCs sources in the refinery. Then, coupling with the VOCs chemical profiles measured at the device areas, we concluded that CCU1/3 contributes to 25.9% of the TVOCs at the surrounding downwind area by volume, followed by CCU2 (24.7%), CRU (18.9%), TF (18.3%) and WT (12.0%), which was accordant with the research of US EPA (2008). Finally, ozone formation potentials of the 5 devices were also calculated by MIR technique, which showed that catalytic cracking units, accounting for about 55.6% to photochemical ozone formation, should be given the consideration of VOCs control firstly.

  18. 33 CFR 165.770 - Security Zone: HOVENSA Refinery, St. Croix, U.S. Virgin Islands.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., St. Croix, U.S. Virgin Islands. 165.770 Section 165.770 Navigation and Navigable Waters COAST GUARD... § 165.770 Security Zone: HOVENSA Refinery, St. Croix, U.S. Virgin Islands. (a) Regulated area. The Coast Guard is establishing a security zone in and around the HOVENSA Refinery on the south coast of St. Croix...

  19. 33 CFR 165.766 - Security Zone: HOVENSA Refinery, St. Croix, U.S. Virgin Islands.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., St. Croix, U.S. Virgin Islands. 165.766 Section 165.766 Navigation and Navigable Waters COAST GUARD... § 165.766 Security Zone: HOVENSA Refinery, St. Croix, U.S. Virgin Islands. (a) Regulated area. The Coast Guard is establishing a security zone in and around the HOVENSA Refinery on the south coast of St. Croix...

  20. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for... rescue gear (slings, baskets, stretchers) and vessel's line-throwing apparatus. (b) An abandon-ship drill...

  1. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for... rescue gear (slings, baskets, stretchers) and vessel's line-throwing apparatus. (b) An abandon-ship drill...

  2. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for... rescue gear (slings, baskets, stretchers) and vessel's line-throwing apparatus. (b) An abandon-ship drill...

  3. Ecofriendly demulsification of water in oil emulsions by an efficient biodemulsifier producing bacterium isolated from oil contaminated environment.

    PubMed

    Sabati, Hoda; Motamedi, Hossein

    2018-05-15

    Water in oil emulsions increase oil processing costs and cause damage to refinery equipment which necessitates demulsification. Since chemical demulsifiers cause environmental pollution, biodemulsifiers have been paid more attention. This study aims to identify biodemulsifier-producing bacteria from petroleum contaminated environments. As a result, several biodemulsifier producing strains were found that Stenotrophomonas sp. strain HS7 (accession number: MF445088) which produced a cell associated biodemulsifier showed the highest demulsifying ratio, 98.57% for water in kerosene and 66.28% for water in crude oil emulsion after 48 h. 35 °C, pH 7, 48 h incubation and ammonium nitrate as nitrogen source were optimum conditions for biodemulsifier production. Furthermore, it was found that hydrophobic carbon sources like as liquid paraffin is not preferred as the sole carbon source while a combination of various carbon sources including liquid paraffin will increase demulsification efficiency of the biodemulsifier. The appropriate potential of this biodemulsifier strengthens the possibility of its application in industries especially petroleum industry.

  4. 40 CFR 80.210 - What sulfur standards apply to gasoline downstream from refineries and importers?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... gasoline downstream from refineries and importers? 80.210 Section 80.210 Protection of Environment... Gasoline Sulfur Gasoline Sulfur Standards § 80.210 What sulfur standards apply to gasoline downstream from refineries and importers? The sulfur standard for gasoline at any point in the gasoline distribution system...

  5. 40 CFR 80.210 - What sulfur standards apply to gasoline downstream from refineries and importers?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... gasoline downstream from refineries and importers? 80.210 Section 80.210 Protection of Environment... Gasoline Sulfur Gasoline Sulfur Standards § 80.210 What sulfur standards apply to gasoline downstream from refineries and importers? The sulfur standard for gasoline at any point in the gasoline distribution system...

  6. 40 CFR 80.210 - What sulfur standards apply to gasoline downstream from refineries and importers?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... gasoline downstream from refineries and importers? 80.210 Section 80.210 Protection of Environment... Gasoline Sulfur Gasoline Sulfur Standards § 80.210 What sulfur standards apply to gasoline downstream from refineries and importers? The sulfur standard for gasoline at any point in the gasoline distribution system...

  7. 40 CFR 80.210 - What sulfur standards apply to gasoline downstream from refineries and importers?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... gasoline downstream from refineries and importers? 80.210 Section 80.210 Protection of Environment... Gasoline Sulfur Gasoline Sulfur Standards § 80.210 What sulfur standards apply to gasoline downstream from refineries and importers? The sulfur standard for gasoline at any point in the gasoline distribution system...

  8. 40 CFR 80.210 - What sulfur standards apply to gasoline downstream from refineries and importers?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... gasoline downstream from refineries and importers? 80.210 Section 80.210 Protection of Environment... Gasoline Sulfur Gasoline Sulfur Standards § 80.210 What sulfur standards apply to gasoline downstream from refineries and importers? The sulfur standard for gasoline at any point in the gasoline distribution system...

  9. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for abandon-ship training must be aboard each vessel. The material must consist of a manual of one or more...

  10. 32 CFR 1618.1 - Abandonment of rights or privileges.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 6 2010-07-01 2010-07-01 false Abandonment of rights or privileges. 1618.1... NOTICE TO REGISTRANTS § 1618.1 Abandonment of rights or privileges. If a registrant fails to claim and exercise any right or privilege within the required time, he shall be deemed to have abandoned the right or...

  11. 76 FR 64943 - Proposed Cercla Administrative Cost Recovery Settlement; ACM Smelter and Refinery Site, Located...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-19

    ... Settlement; ACM Smelter and Refinery Site, Located in Cascade County, MT AGENCY: Environmental Protection... projected future response costs concerning the ACM Smelter and Refinery NPL Site (Site), Operable Unit 1..., Helena, MT 59626. Mr. Sturn can be reached at (406) 457-5027. Comments should reference the ACM Smelter...

  12. Oil recovery from petroleum sludge through ultrasonic assisted solvent extraction.

    PubMed

    Hu, Guangji; Li, Jianbing; Huang, Shuhui; Li, Yubao

    2016-09-18

    The effect of ultrasonic assisted extraction (UAE) process on oil recovery from refinery oily sludge was examined in this study. Two types of UAE treatment including UAE probe (UAEP) system and UAE bath (UAEB) system were investigated. Their oil recovery efficiencies were compared to that of mechanical shaking extraction (MSE). Three solvents including cyclohexane (CHX), ethyl acetate (EA), and methyl ethyl ketone (MEK) were examined as the extraction solvents. The influence of experimental factors on oil and solvent recovery was investigated using an orthogonal experimental design. Results indicated that solvent type, solvent-to-sludge (S/S) ratio, and treatment duration could have significant effects on oil recovery in UAE treatment. Under the optimum conditions, UAEP treatment can obtain an oil recovery of 68.8% within 20 s, which was higher than that (i.e., 62.0%) by MSE treatment after 60 min' extraction. UAEB treatment can also obtain a promising oil recovery within shorter extraction duration (i.e., 15 min) than MSE. UAE was thus illustrated as an effective and improved approach for oily sludge recycling.

  13. Bitumen and heavy oil upgrading in Canada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chrones, J.; Germain, R.R.

    1989-01-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulphur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgradermore » now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional projects, also based on hydrogenation, will use ebullated bed catalyst systems; the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.« less

  14. Bitumen and heavy oil upgrading in Canada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chrones, J.

    1988-06-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulfur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader,more » now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional products, also based on hydrogenation, will use ebullated bed catalyst systems: the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.« less

  15. Alternative Fuels Data Center: Vermont Transportation Data for Alternative

    Science.gov Websites

    Plants 5 Generating Capacity (nameplate, MW) 675 Oil Refineries 0 Oil Refinery Capacity (bbl/day) 0 Recycled Cooking Oil Powers Biodiesel Vehicles in Vermont Recycled Cooking Oil Powers Biodiesel Vehicles in

  16. 77 FR 33716 - Foreign-Trade Zone 70-Detroit, MI; Expansion of Subzone; Marathon Petroleum Company LP, (Oil...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-07

    ... DEPARTMENT OF COMMERCE Foreign-Trade Zones Board [B-42-2012] Foreign-Trade Zone 70--Detroit, MI; Expansion of Subzone; Marathon Petroleum Company LP, (Oil Refinery) Detroit, MI An application has been...., grantee of FTZ 70, requesting an expansion of Subzone 70T, on behalf of Marathon Petroleum Company LP in...

  17. Biocatalytic desulfurization of thiophenic compounds and crude oil by newly isolated bacteria

    PubMed Central

    Mohamed, Magdy El-Said; Al-Yacoub, Zakariya H.; Vedakumar, John V.

    2015-01-01

    Microorganisms possess enormous highly specific metabolic activities, which enable them to utilize and transform nearly every known chemical class present in crude oil. In this context, one of the most studied biocatalytic processes is the biodesulfurization (BDS) of thiophenic sulfur-containing compounds such as benzothiophene (BT) and dibenzothiophene (DBT) in crude oils and refinery streams. Three newly isolated bacterial strains, which were affiliated as Rhodococcus sp. strain SA11, Stenotrophomonas sp. strain SA21, and Rhodococcus sp. strain SA31, were enriched from oil contaminated soil in the presence of DBT as the sole S source. GC-FID analysis of DBT-grown cultures showed consumption of DBT, transient formation of DBT sulfone (DBTO2) and accumulation of 2-hydroxybiphenyl (2-HBP). Molecular detection of the plasmid-borne dsz operon, which codes for the DBT desulfurization activity, revealed the presence of dszA, dszB, and dszC genes. These results point to the operation of the known 4S pathway in the BDS of DBT. The maximum consumption rate of DBT was 11 μmol/g dry cell weight (DCW)/h and the maximum formation rate of 2-HBP formation was 4 μmol/g DCW/h. Inhibition of both cell growth and DBT consumption by 2-HBP was observed for all isolates but SA11 isolate was the least affected. The isolated biocatalysts desulfurized other model DBT alkylated homologs. SA11 isolate was capable of desulfurizing BT as well. Resting cells of SA11 exhibited 10% reduction in total sulfur present in heavy crude oil and 18% reduction in total sulfur present in the hexane-soluble fraction of the heavy crude oil. The capabilities of the isolated bacteria to survive and desulfurize a wide range of S compounds present in crude oil are desirable traits for the development of a robust BDS biocatalyst to upgrade crude oils and refinery streams. PMID:25762990

  18. Infanticide and illegal infant abandonment in Malaysia.

    PubMed

    Razali, Salmi; Kirkman, Maggie; Ahmad, S Hassan; Fisher, Jane

    2014-10-01

    Infant abandonment and infanticide are poorly understood in Malaysia. The information available in the public arena comes predominantly from anecdotal sources. The aim of this study was to describe the prevalence and characteristics of infanticide and illegal infant abandonment in Malaysia and to estimate annual rates for the most recent decade. Summaries of data about infanticide and illegal infant abandonment were gathered from police records; the annual number of live births was ascertained from the national registry. The estimated inferred infanticide rates for Malaysia were compared with the infanticide rates among countries of very high, high, medium, and low rankings on the Human Development, Gender Inequality, and Gini indices. From 1999 to 2011, 1,069 cases of illegal infant abandonment were recorded and 1,147 people were arrested as suspected perpetrators. The estimated inferred infanticide rate fluctuated between 4.82 and 9.11 per 100,000 live births, a moderate rate relative to the infanticide rates of other countries. There are substantial missing data, with details undocumented for about 78-87% of cases and suspected perpetrators. Of the documented cases, it appeared that more boys than girls were victims and that suspected perpetrators were predominantly Malays who were women, usually mothers of the victim; the possibility of arrest bias must be acknowledged. Economic and social inequality, particularly gender inequality, might contribute to the phenomena of infanticide and abandonment. Strategies to reduce rates of infanticide and illegal infant abandonment in Malaysia will require strengthening of the surveillance system and attention to the gender-based inequalities that underpin human development. Copyright © 2014 Elsevier Ltd. All rights reserved.

  19. Improvement in treatment abandonment in pediatric patients with cancer in Guatemala.

    PubMed

    Alvarez, Elysia; Seppa, Midori; Rivas, Silvia; Fuentes, Lucia; Valverde, Patricia; Antillón-Klussmann, Federico; Castellanos, Mauricio; Sweet-Cordero, E Alejandro; Messacar, Kevin; Kurap, John; Bustamante, Marisol; Howard, Scott C; Efron, Bradley; Luna-Fineman, Sandra

    2017-10-01

    Treatment refusal and abandonment are major causes of treatment failure for children with cancer in low- and middle-income countries (LMICs), like Guatemala. This study identified risk factors for and described the intervention that decreased abandonment. This was a retrospective study of Guatemalan children (0-18 years) with cancer treated at the Unidad Nacional de Oncología Pediátrica (UNOP), 2001-2008, using the Pediatric Oncology Network Database. Treatment refusal was a failure to begin treatment and treatment abandonment was a lapse of 4 weeks or longer in treatment. The impact of medicina integral, a multidisciplinary psychosocial intervention team at UNOP was evaluated. Cox proportional hazards analysis identified the effect of demographic and clinical factors on abandonment. Kaplan-Meier analysis estimated the survival. Of 1,789 patients, 21% refused or abandoned treatment. Abandonment decreased from 27% in 2001 to 7% in 2008 following the implementation of medicina integral. Factors associated with increased risk of refusal and abandonment: greater distance to the centre (P < 0.001), younger age (P = 0.017) and earlier year of diagnosis (P < 0.001). Indigenous race/ethnicity (P = 0.002) was associated with increased risk of abandonment alone. Abandonment correlated with decreased overall survival: 0.57 ± 0.02 (survival ± standard error) for those who completed therapy versus 0.06 ± 0.02 for those who abandoned treatment (P < 0.001) at 8.3 years. This study identified distance, age, year of diagnosis and indigenous race/ethnicity as risk factors for abandonment. A multidisciplinary intervention reduced abandonment and can be replicated in other LMICs. © 2017 Wiley Periodicals, Inc.

  20. World Energy Projection System Plus Model Documentation: Refinery Module

    EIA Publications

    2016-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  1. Peroxidase-catalyzed removal of phenols from a petroleum refinery wastewater.

    PubMed

    Wagner, M; Nicell, J A

    2001-01-01

    The phenol content of a petroleum refinery wastewater was reduced below the discharge limit following treatment with horseradish peroxidase and H2O2. Approximately 58% of COD, 78% of BOD5, and 95% of toxicity were removed along with the phenols. As a result of treatment, phenols were transformed into less biodegradable compounds which could be removed by subsequent coagulation and precipitation. Optimization of the peroxide concentration led to 20% enzyme savings. The use of PEG and chitosan as protective additives resulted in 4 and 25-fold reductions in enzyme requirements, respectively. Phenol removal did not appear to be adversely affected by the presence of other hydrocarbons that are frequently present in refinery wastewaters.

  2. Well-to-Wheels Greenhouse Gas Emission Analysis of High-Octane Fuels with Ethanol Blending: Phase II Analysis with Refinery Investment Options

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Han, Jeongwoo; Wang, Michael; Elgowainy, Amgad

    Higher-octane gasoline can enable increases in an internal combustion engine’s energy efficiency and a vehicle’s fuel economy by allowing an increase in the engine compression ratio and/or by enabling downspeeding and downsizing. Producing high-octane fuel (HOF) with the current level of ethanol blending (E10) could increase the energy and greenhouse gas (GHG) emissions intensity of the fuel product from refinery operations. Alternatively, increasing the ethanol blending level in final gasoline products could be a promising solution to HOF production because of the high octane rating and potentially low blended Reid vapor pressure (RVP) of ethanol at 25% and higher ofmore » the ethanol blending level by volume. In our previous HOF well-to-wheels (WTW) report (the so-called phase I report of the HOF WTW analysis), we conducted WTW analysis of HOF with different ethanol blending levels (i.e., E10, E25, and E40) and a range of vehicle efficiency gains with detailed petroleum refinery linear programming (LP) modeling by Jacobs Consultancy and showed that the overall WTW GHG emission changes associated with HOFVs were dominated by the positive impact associated with vehicle efficiency gains and ethanol blending levels, while the refining operations to produce gasoline blendstock for oxygenate blending (BOB) for various HOF blend levels had a much smaller impact on WTW GHG emissions (Han et al. 2015). The scope of the previous phase I study, however, was limited to evaluating PADDs 2 and 3 operation changes with various HOF market share scenarios and ethanol blending levels. Also, the study used three typical configuration models of refineries (cracking, light coking, and heavy coking) in each PADD, which may not be representative of the aggregate response of all refineries in each PADD to various ethanol blending levels and HOF market scenarios. Lastly, the phase I study assumed no new refinery expansion in the existing refineries, which limited E10 HOF production

  3. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false How is a refinery motor vehicle diesel... Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Recordkeeping and Reporting Requirements § 80.596 How is a refinery motor vehicle diesel fuel volume baseline calculated? (a) For purposes...

  4. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How is a refinery motor vehicle diesel... Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Recordkeeping and Reporting Requirements § 80.596 How is a refinery motor vehicle diesel fuel volume baseline calculated? (a) For purposes...

  5. The Oil Industries Fake Abundance Story: Is Distortion of the Truth Ever Appropriate?

    NASA Astrophysics Data System (ADS)

    Murray, J. W.

    2014-12-01

    The oil industries and their cornucopian supporters (press, politicians, energy agencies) promote the story that in the oil is abundant and oil production will increase. The reality is that 1) World crude oil production has been on a plateau since 2005, in spite of new technology (fracking), record high prices (Brent Oil > 100 per barrel) and record spending on exploration and development (5.4 trillion over the past six years) and 2) The price of oil has risen steadily from 1999 to present. Typically when commodities are abundant the price tends to fall. How is this reality being distorted? 1) Resources are being equated with reserves (both are amounts), neither of which can be equated with each other or with production (a rate). 2) Crude oil (the price or which is rigorously defined by API density) has been redefined as total liquids, which includes substances (lease condensates, natural gas liquids, biofuels, refinery gains) which can not be used in the same way oil is or sold for the same price as oil. If what you are selling cannot be sold on the world market as crude oil, then it is not crude oil. 3) The demand for oil remains high, but World production is stagnant and World net-export production has been decreasing since 2005. Thus the price remains high and will only increase in the future. Growth in Global GDP is impacted by high-priced oil. How do you know unethical behavior when you see it? It has to do with intentionality and motivation. "Advocacy science" often reports data to support their cause. Is that unethical? Where is the divide between being an "Issue Advocate" and "Advocacy Science"? If data are reported poorly, is it unethical or just "bad science"? Do the same ethical standards apply to businesses (when profits are involved) and politicians (when elections are at stake)? Why would the definition of oil include NGL, condensates and refinery gains if not trying to inflate the numbers. The standards should be the same, but when there are no

  6. Refinery siting workbook: appendices C to O

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

  7. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 9 2013-04-01 2013-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food... may at any time abandon his right to manufacture all or any part of the quota by filing with the Drug... to manufacture. The Administrator may, in his discretion, allocate the amount among the other...

  8. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 9 2012-04-01 2012-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food... may at any time abandon his right to manufacture all or any part of the quota by filing with the Drug... to manufacture. The Administrator may, in his discretion, allocate the amount among the other...

  9. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 9 2010-04-01 2010-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food... may at any time abandon his right to manufacture all or any part of the quota by filing with the Drug... to manufacture. The Administrator may, in his discretion, allocate the amount among the other...

  10. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 9 2014-04-01 2014-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food... may at any time abandon his right to manufacture all or any part of the quota by filing with the Drug... to manufacture. The Administrator may, in his discretion, allocate the amount among the other...

  11. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 9 2011-04-01 2011-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food... may at any time abandon his right to manufacture all or any part of the quota by filing with the Drug... to manufacture. The Administrator may, in his discretion, allocate the amount among the other...

  12. Wavelength-dependent excess permittivity as indicator of kerosene in diesel oil.

    PubMed

    Kanyathare, Boniphace; Peiponen, Kai-Erik

    2018-04-20

    Adulteration of diesel oil by kerosene is a serious problem because of air pollution resulting from car exhaust gases. The objective of this study was to develop a relatively simple optical measurement and data analysis method to screen low-adulterated diesel oils. For this purpose, we introduce the utilization of refractive index measurement with a refractometer, scanning of visible-near-infrared transmittance, transmittance data inversion using the singly subtractive Kramers-Kronig relation, and exploitation of so-called wavelength-dependent relative excess permittivity. It is shown for three different diesel oil grades, adulterated with kerosene, that the excess permittivity is a powerful measure for screening fake diesel oils. The excess relative permittivity of such binary mixtures also reveals hidden spectral fingerprints that are neither visible in dispersion data alone nor in spectral transmittance measurements alone. We believe that the excess permittivity data are useful in the case of screening adulteration of diesel oil by kerosene and can further be explored for practical sensing solutions, e.g., in quality inspection of diesel oils in refineries.

  13. 19 CFR 19.9 - General order, abandoned, and seized merchandise.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 19 Customs Duties 1 2011-04-01 2011-04-01 false General order, abandoned, and seized merchandise... Provisions § 19.9 General order, abandoned, and seized merchandise. (a) Acceptance of merchandise. The... storing. General order, abandoned, and seized goods and articles shall be recorded and stored in the...

  14. 19 CFR 19.9 - General order, abandoned, and seized merchandise.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false General order, abandoned, and seized merchandise... Provisions § 19.9 General order, abandoned, and seized merchandise. (a) Acceptance of merchandise. The... storing. General order, abandoned, and seized goods and articles shall be recorded and stored in the...

  15. Use of geochemical biomarkers in bottom sediment to track oil from a spill, San Francisco Bay, California

    USGS Publications Warehouse

    Hostettler, F.D.; Rapp, J.B.; Kvenvolden, K.A.

    1992-01-01

    In April 1988, approximately 1500 m3 of a San Joaquin Valley crude oil were accidentally released from a Shell Oil Co. refinery near Martinez, Californa. The oil flowed into Carquinez Strait and Suisun Bay in northern San Francisco Bay Sediment and oil samples were collected within a week and analysed for geochemical marker compounds in order to track the molecular signature of the oil spill in the bottom sediment. Identification of the spilled oil in the sediment was complicated by the degraded nature of the oil and the similarity of the remaining, chromatographically resolvable constituents to those already present in the sediments from anthropogenic petroleum contamination, pyrogenic sources, and urban drainage. Ratios of hopane and sterane biomarkers, and of polycyclic aromatic hydrocarbons and their alkylated derivatives best identified the oil impingement. They showed the oil impact at this early stage to be surficial only, and to be patchy even within an area of heavy oil exposure.

  16. Monitoring of Emissions From a Refinery Tank Farm Using a Combination of Optical Remote Sensing Techniques

    NASA Astrophysics Data System (ADS)

    Polidori, A.; Tisopulos, L.; Pikelnaya, O.; Mellqvist, J.; Samuelsson, J.; Marianne, E.; Robinson, R. A.; Innocenti, F.; Finlayson, A.; Hashmonay, R.

    2016-12-01

    Despite great advances in reducing air pollution, the South Coast Air Basin (SCAB) still faces challenges to attain federal health standards for air quality. Refineries are large sources of ozone precursors and, hence contribute to the air quality problems of the region. Additionally, petrochemical facilities are also sources of other hazardous air pollutants (HAP) that adversely affect human health, for example aromatic hydrocarbons. In order to assure safe operation, decrease air pollution and minimize population exposure to HAP the South Coast Air Quality Management District (SCAQMD) has a number of regulations for petrochemical facilities. However, significant uncertainties still exist in emission estimates and traditional monitoring techniques often do not allow for real-time emission monitoring. In the fall of 2015 the SCAQMD, Fluxsense Inc., the National Physical Laboratory (NPL), and Atmosfir Optics Ltd. conducted a measurement study to characterize and quantify gaseous emissions from the tank farm of one of the largest oil refineries in the SCAB. Fluxsense used a vehicle equipped with Solar Occultation Flux (SOF), Differential Optical Absorption Spectroscopy (DOAS), and Extractive Fourier Transform Infrared (FTIR) spectroscopy instruments. Concurrently, NPL operated their Differential Absorption Lidar (DIAL) system. Both research groups quantified emissions from the entire tank farm and identified fugitive emission sources within the farm. At the same time, Atmosfir operated an Open Path FTIR (OP-FTIR) spectrometer along the fenceline of the tank farm. During this presentation we will discuss the results of the emission measurements from the tank farm of the petrochemical facility. Emission rates resulting from measurements by different ORS methods will be compared and discussed in detail.

  17. Abandoned floodplain plant communities along a regulated dryland river

    USGS Publications Warehouse

    Reynolds, L. V.; Shafroth, Patrick B.; House, P. K.

    2014-01-01

    Rivers and their floodplains worldwide have changed dramatically over the last century because of regulation by dams, flow diversions and channel stabilization. Floodplains no longer inundated by river flows following dam-induced flood reduction comprise large areas of bottomland habitat, but the effects of abandonment on plant communities are not well understood. Using a hydraulic flow model, geomorphic mapping and field surveys, we addressed the following questions along the Bill Williams River, Arizona: (i) What per cent of the bottomland do abandoned floodplains comprise? and (ii) Are abandoned floodplains quantitatively different from adjacent xeric and riparian surfaces in terms of vegetation composition and surface sediment? We found that nearly 70% of active channel and floodplain area was abandoned following dam installation. Abandoned floodplains along the Bill Williams River tend to be similar to each other yet distinct from neighbouring habitats: they have been altered physically from their historic state, leading to distinct combinations of surface sediments, hydrology and plant communities. Abandoned floodplains may transition to xeric communities over time but are likely to retain some riparian qualities as long as there is access to relatively shallow ground water. With expected increases in water demand and drying climatic conditions in many regions, these surfaces and associated vegetation will continue to be extensive in riparian landscapes worldwide

  18. 40 CFR 80.855 - What is the compliance baseline for refineries or importers with insufficient data?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What is the compliance baseline for refineries or importers with insufficient data? 80.855 Section 80.855 Protection of Environment ENVIRONMENTAL... infeasible, on a cost and/or technological basis, for the refinery to comply with the compliance baseline...

  19. 40 CFR 80.855 - What is the compliance baseline for refineries or importers with insufficient data?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false What is the compliance baseline for refineries or importers with insufficient data? 80.855 Section 80.855 Protection of Environment ENVIRONMENTAL... infeasible, on a cost and/or technological basis, for the refinery to comply with the compliance baseline...

  20. 40 CFR 80.855 - What is the compliance baseline for refineries or importers with insufficient data?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false What is the compliance baseline for refineries or importers with insufficient data? 80.855 Section 80.855 Protection of Environment ENVIRONMENTAL... infeasible, on a cost and/or technological basis, for the refinery to comply with the compliance baseline...

  1. 40 CFR 80.855 - What is the compliance baseline for refineries or importers with insufficient data?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false What is the compliance baseline for refineries or importers with insufficient data? 80.855 Section 80.855 Protection of Environment ENVIRONMENTAL... infeasible, on a cost and/or technological basis, for the refinery to comply with the compliance baseline...

  2. 40 CFR 80.855 - What is the compliance baseline for refineries or importers with insufficient data?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false What is the compliance baseline for refineries or importers with insufficient data? 80.855 Section 80.855 Protection of Environment ENVIRONMENTAL... infeasible, on a cost and/or technological basis, for the refinery to comply with the compliance baseline...

  3. Smoking and occupational allergy in workers in a platinum refinery.

    PubMed Central

    Venables, K. M.; Dally, M. B.; Nunn, A. J.; Stevens, J. F.; Stephens, R.; Farrer, N.; Hunter, J. V.; Stewart, M.; Hughes, E. G.; Newman Taylor, A. J.

    1989-01-01

    OBJECTIVE--To test the hypothesis that smoking increases the risk of sensitisation by occupational allergens. DESIGN--Historical prospective cohort study. SETTING--Platinum refinery. SUBJECTS--91 Workers (86 men) who started work between 1 January 1973 and 31 December 1974 and whose smoking habit and atopic state (on skin prick testing with common allergens) had been noted at joining. MAIN OUTCOME MEASURES--Results of skin prick tests with platinum salts carried out routinely every three to six months and records of any respiratory symptoms noted by the refinery's occupational health service. Follow up was until 1980 or until leaving refinery work, whichever was earlier. RESULTS--57 Workers smoked and 29 were atopic; 22 developed a positive result on skin testing with platinum salts and 49 developed symptoms, including all 22 whose skin test result was positive. Smoking was the only significant predictor of a positive result on skin testing with platinum salts and its effect was greater than that of atopy; the estimated relative risks (95% confidence interval) when both were included in the regression model were: smokers versus non-smokers 5.05 (1.68 to 15.2) and atopic versus non-atopic 2.29 (0.88 to 5.99). Number of cigarettes smoked per day was the only significant predictor of respiratory symptoms. CONCLUSION--Smokers are at increased risk of sensitisation by platinum salts. PMID:2508944

  4. "The Giver" and "Shade's Children": Future Views of Child Abandonment and Murder.

    ERIC Educational Resources Information Center

    Gross, Melissa

    1999-01-01

    Examines reasons for child abandonment and murder and how it relates to abandonment in traditional literature. Considers new views of child abandonment and murder (focusing not on overcoming their abandonment, but changing and restructuring their entire society) presented in "The Giver" and "Shade's Children." Discusses the…

  5. Microbial community succession in alkaline, saline bauxite residue: a cross-refinery study

    NASA Astrophysics Data System (ADS)

    Santini, T.; Malcolm, L. I.; Tyson, G. W.; Warren, L. A.

    2015-12-01

    Bauxite residue, a byproduct of the Bayer process for alumina refining, is an alkaline, saline tailings material that is generally considered to be inhospitable to microbial life. In situ remediation strategies promote soil formation in bauxite residue by enhancing leaching of saline, alkaline pore water, and through incorporation of amendments to boost organic matter content, decrease pH, and improve physical structure. The amelioration of chemical and physical conditions in bauxite residue is assumed to support diversification of microbial communities from narrow, poorly functioning microbial communities towards diverse, well-functioning communities. This study aimed to characterise microbial communities in fresh and remediated bauxite residues from refineries worldwide, to identify (a) whether initial microbial communities differed between refineries; (b) major environmental controls on microbial community composition; and (c) whether remediation successfully shifts the composition of microbial communities in bauxite residue towards those found in reference (desired endpoint) soils. Samples were collected from 16 refineries and characterised using 16S amplicon sequencing to examine microbial community composition and structure, in conjunction with physicochemical analyses. Initial microbial community composition was similar across refineries but partitioned into two major groups. Microbial community composition changes slowly over time and indicates that alkalinity and salinity inhibit diversification. Microbially-based strategies for in situ remediation should consider the initial microbial community composition and whether the pre-treatment of chemical properties would optimise subsequent bioremediation outcomes. During in situ remediation, microbial communities become more diverse and develop wider functional capacity, indicating progression towards communities more commonly observed in natural grassland and forest soils.

  6. Localized Detection of Abandoned Luggage

    NASA Astrophysics Data System (ADS)

    Chang, Jing-Ying; Liao, Huei-Hung; Chen, Liang-Gee

    2010-12-01

    Abandoned luggage represents a potential threat to public safety. Identifying objects as luggage, identifying the owners of such objects, and identifying whether owners have left luggage behind are the three main problems requiring solution. This paper proposes two techniques which are "foreground-mask sampling" to detect luggage with arbitrary appearance and "selective tracking" to locate and to track owners based solely on looking only at the neighborhood of the luggage. Experimental results demonstrate that once an owner abandons luggage and leaves the scene, the alarm fires within few seconds. The average processing speed of the approach is 17.37 frames per second, which is sufficient for real world applications.

  7. Spatial and Temporal Characteristics of Historical Oil and Gas Wells in Pennsylvania: Implications for New Shale Gas Resources.

    PubMed

    Dilmore, Robert M; Sams, James I; Glosser, Deborah; Carter, Kristin M; Bain, Daniel J

    2015-10-20

    Recent large-scale development of oil and gas from low-permeability unconventional formations (e.g., shales, tight sands, and coal seams) has raised concern about potential environmental impacts. If left improperly sealed, legacy oil and gas wells colocated with that new development represent a potential pathway for unwanted migration of fluids (brine, drilling and stimulation fluids, oil, and gas). Uncertainty in the number, location, and abandonment state of legacy wells hinders environmental assessment of exploration and production activity. The objective of this study is to apply publicly available information on Pennsylvania oil and gas wells to better understand their potential to serve as pathways for unwanted fluid migration. This study presents a synthesis of historical reports and digital well records to provide insights into spatial and temporal trends in oil and gas development. Areas with a higher density of wells abandoned prior to the mid-20th century, when more modern well-sealing requirements took effect in Pennsylvania, and areas where conventional oil and gas production penetrated to or through intervals that may be affected by new Marcellus shale development are identified. This information may help to address questions of environmental risk related to new extraction activities.

  8. Refinery evaluation of optical imaging to locate fugitive emissions.

    PubMed

    Robinson, Donald R; Luke-Boone, Ronke; Aggarwal, Vineet; Harris, Buzz; Anderson, Eric; Ranum, David; Kulp, Thomas J; Armstrong, Karla; Sommers, Ricky; McRae, Thomas G; Ritter, Karin; Siegell, Jeffrey H; Van Pelt, Doug; Smylie, Mike

    2007-07-01

    Fugitive emissions account for approximately 50% of total hydrocarbon emissions from process plants. Federal and state regulations aiming at controlling these emissions require refineries and petrochemical plants in the United States to implement a Leak Detection and Repair Program (LDAR). The current regulatory work practice, U.S. Environment Protection Agency Method 21, requires designated components to be monitored individually at regular intervals. The annual costs of these LDAR programs in a typical refinery can exceed US$1,000,000. Previous studies have shown that a majority of controllable fugitive emissions come from a very small fraction of components. The Smart LDAR program aims to find cost-effective methods to monitor and reduce emissions from these large leakers. Optical gas imaging has been identified as one such technology that can help achieve this objective. This paper discusses a refinery evaluation of an instrument based on backscatter absorption gas imaging technology. This portable camera allows an operator to scan components more quickly and image gas leaks in real time. During the evaluation, the instrument was able to identify leaking components that were the source of 97% of the total mass emissions from leaks detected. More than 27,000 components were monitored. This was achieved in far less time than it would have taken using Method 21. In addition, the instrument was able to find leaks from components that are not required to be monitored by the current LDAR regulations. The technology principles and the parameters that affect instrument performance are also discussed in the paper.

  9. Sickness absence in a Singapore refinery, 1981-1992.

    PubMed

    Lai, C S

    1994-09-01

    Sickness absence among the unionised staff of the largest petroleum refinery in Singapore was followed up from 1981 to 1992. The changes seen throughout these 12 years were related to national, organisational and personal factors. Initially because of increasing competitiveness in the industry, and later because of a national recession, manpower in the refinery was progressively reduced from 1981 to 1986. This however was not the main cause of the reduction in sickness absence rates from 8.4 working days in 1981 to 5.8 days in 1983. Organisational changes to medical leave entitlements and improved means of supervision of absence were responsible for the early fall in absence rates. Personal factors, such as the increasing age of the population, did not affect the amount of short-term absences, while shift work was associated with higher absences. From 1986 absence rates rose again, eventually to almost 1981 levels by 1992, a reflection of the tendency for sickness absence to increase with time, unless active measures are undertaken for its control.

  10. 17 CFR 230.155 - Integration of abandoned offerings.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 17 Commodity and Securities Exchanges 2 2010-04-01 2010-04-01 false Integration of abandoned... GENERAL RULES AND REGULATIONS, SECURITIES ACT OF 1933 General § 230.155 Integration of abandoned offerings... from integration of private and registered offerings. Because of the objectives of Rule 155 and the...

  11. Feasibility of flare gas reformation to practical energy in Farashband gas refinery: no gas flaring.

    PubMed

    Rahimpour, Mohammad Reaza; Jokar, Seyyed Mohammad

    2012-03-30

    A suggested method for controlling the level of hazardous materials in the atmosphere is prevention of combustion in flare. In this work, three methods are proposed to recover flare gas instead of conventional gas-burning in flare at the Farashband gas refinery. These methods aim to minimize environmental and economical disadvantages of burning flare gas. The proposed methods are: (1) gas to liquid (GTL) production, (2) electricity generation with a gas turbine and, (3) compression and injection into the refinery pipelines. To find the most suitable method, the refinery units that send gas to the flare as well as the required equipment for the three aforementioned methods are simulated. These simulations determine the amount of flare gas, the number of GTL barrels, the power generated by the gas turbine and the required compression horsepower. The results of simulation show that 563 barrels/day of valuable GTL products is produced by the first method. The second method provides 25 MW electricity and the third method provides a compressed natural gas with 129 bar pressure for injection to the refinery pipelines. In addition, the economics of flare gas recovery methods are studied and compared. The results show that for the 4.176MMSCFD of gas flared from the Farashband gas refinery, the electricity production gives the highest rate of return (ROR), the lowest payback period, the highest annual profit and mild capital investment. Therefore, the electricity production is the superior method economically. Copyright © 2012 Elsevier B.V. All rights reserved.

  12. A prospective study of morbidity patterns in a petroleum refinery and chemical plant.

    PubMed Central

    Tsai, S P; Dowd, C M; Cowles, S R; Ross, C E

    1992-01-01

    This study examined the morbidity experience from 1981 to 1988 of a prospective cohort of 3422 refinery and petrochemical plant employees from the Shell Deer Park manufacturing complex. The morbidity data for this study, which include all illness and absence records in excess of five days, were extracted from the morbidity section of the Shell health surveillance system. Standardised morbidity ratios (SMRs) of disease prevalence in this cohort were calculated using an internal comparison group of all manufacturing employees of the Shell Oil Company. Among production employees, the overall morbidity was statistically significantly higher (SMR = 109) than that of the comparison group. Illness due to hypertension (SMR = 144), haemorrhoids (SMR = 149), diseases of the nervous system (SMR = 120), respiratory system (SMR = 108), and digestive system (SMR = 117) were also raised for this group. The increased risk due to these medical conditions does not appear to be associated with occupational factors. Lymphatic and haematopoietic tissue neoplasms were raised (SMR = 124), but were based on only four cases. PMID:1637713

  13. Institute on oil and gas law and taxation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ernst, A.C.

    1979-01-01

    This volume contains discussions, by acknowledged authorities, of important legal and tax problems of the oil and gas industries. The articles were delivered in condensed form as lectures during the Thirtieth Annual Institute on Oil and Gas Law and Taxation held by the Southwest Legal Foundation. The following topics are discussed: crude oil issues; natural gas liquid-selected problems in regulation; recent developments in DOE audits of refiners and marketers; contrasting administrative procedures before the DOE, DOE organization - the limit of regulatory power, current major developments in federal natural gas legislation and regulation; dedication and abandonment - problems under sectionmore » 7(b) of the Natural Gas Act; Natural gas pipelines - their regulation and their current problems, current antitrust developments in oil and gas exploration and production; developments in nonregulatory oil and gas law; recent developments in oil and gas taxation; entity selection - an experience in alchemy - a comparison of corporations, partnerships, and joint ventures; foreign money and US oil and gas - tax considerations; 1978 legislative developments in oil and gas taxation; and recapture of intangibles under section 1254. (DC)« less

  14. Long-term follow-up mortality study of petroleum refinery and chemical plant employees.

    PubMed

    Tsai, S P; Gilstrap, E L; Cowles, S R; Snyder, P J; Ross, C E

    1996-01-01

    A previous report presented the 1948-1983 mortality patterns of the Shell Deer Park Manufacturing Complex employees who were employed for at least 3 months from 1948 through 1972. The present study updates the earlier investigation by extending the vital status follow-up through 1989 and by expanding the cohort to include employees hired after 1972. As in the previous study, the overall mortality and cancer mortality for both refinery and chemical employees were quite favorable compared to residents in the local population. Among refinery workers, cancers for which a suspicion of work-relatedness was raised in the previous study, i.e. leukemia and cancers of the central nervous system and biliary passage/liver, no supportive evidence was found in this update. For both refinery and chemical plant employees, the mortality rate due to cancers of all lymphopoietic tissue increased with increasing duration of employment; this finding was also noted by the original study. This was also evident for lymphoreticulosarcoma in refinery employees and for leukemia in chemical plant employees. However, elevations of cancers of all lymphatic and hematopoietic tissue are primarily confined to employees who started work at the complex before 1946. By contrast, deaths from cancer of all lymphatic and hematopoietic tissue for employees hired after 1945 were 22% lower than the comparison population. Seven deaths with mesothelioma mentioned on the death certificates were identified, with 3.2 deaths expected, resulting in a statistically nonsignificant SMR of 219.

  15. Life Cycle Assessment for the Production of Oil Palm Seeds.

    PubMed

    Muhamad, Halimah; Ai, Tan Yew; Khairuddin, Nik Sasha Khatrina; Amiruddin, Mohd Din; May, Choo Yuen

    2014-12-01

    The oil palm seed production unit that generates germinated oil palm seeds is the first link in the palm oil supply chain, followed by the nursery to produce seedling, the plantation to produce fresh fruit bunches (FFB), the mill to produce crude palm oil (CPO) and palm kernel, the kernel crushers to produce crude palm kernel oil (CPKO), the refinery to produce refined palm oil (RPO) and finally the palm biodiesel plant to produce palm biodiesel. This assessment aims to investigate the life cycle assessment (LCA) of germinated oil palm seeds and the use of LCA to identify the stage/s in the production of germinated oil palm seeds that could contribute to the environmental load. The method for the life cycle impact assessment (LCIA) is modelled using SimaPro version 7, (System for Integrated environMental Assessment of PROducts), an internationally established tool used by LCA practitioners. This software contains European and US databases on a number of materials in addition to a variety of European- and US-developed impact assessment methodologies. LCA was successfully conducted for five seed production units and it was found that the environmental impact for the production of germinated oil palm was not significant. The characterised results of the LCIA for the production of 1000 germinated oil palm seeds showed that fossil fuel was the major impact category followed by respiratory inorganics and climate change.

  16. Microbial enhanced oil recovery: Entering the log phase

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bryant, R.S.

    1995-12-31

    Microbial enhanced oil recovery (MEOR) technology has advanced internationally since 1980 from a laboratory-based evaluation of microbial processes to field applications. In order to adequately support the decline in oil production in certain areas, research on cost-effective technologies such as microbial enhanced oil recovery processes must focus on both near-term and long-term applications. Many marginal wells are desperately in need of an inexpensive improved oil recovery technology today that can assist producers in order to prevent their abandonment. Microbial enhanced waterflooding technology has also been shown to be an economically feasible technology in the United States. Complementary environmental research andmore » development will also be required to address any potential environmental impacts of microbial processes. In 1995 at this conference, the goal is to further document and promote microbial processes for improved oil recovery and related technology for solving environmental problems.« less

  17. Well Abandonment at Various Sites, John F. Kennedy Space Center, Florida

    NASA Technical Reports Server (NTRS)

    Damphousse, Sarah Joan

    2016-01-01

    Between January 29 and March 9, 2016, a total of 23 monitoring wells were properly abandoned-in-place at five KSC sites (OPF-1&2, OPF-3, RDG, SRB, and HSB). The total abandonment encompassed 489.06 linear feet. The wells abandoned were constructed of PVC with diameters ranging from 1-inch to 2-inches. The shallowest well abandoned was measured to be 11.6 ft bls (OPF) and the deepest well abandoned was documented to be 51.45 feet bls (HSB). All aboveground completions were removed and each area was re-graded and/or grouted to surface to match existing surroundings. All materials (concrete pads, well casings, etc.) were disposed of accordingly.

  18. Assessment of Fenton's reagent and ozonation as pre-treatments for increasing the biodegradability of aqueous diethanolamine solutions from an oil refinery gas sweetening process.

    PubMed

    Durán-Moreno, A; García-González, S A; Gutiérrez-Lara, M R; Rigas, F; Ramírez-Zamora, R M

    2011-02-28

    The aim of this work was to evaluate the efficiency of three chemical oxidation processes for increasing the biodegradability of aqueous diethanolamine solutions (aqueous DEA solutions), to be used as pre-treatments before a biological process. The raw aqueous DEA solution, sourced from a sour gas sweetening plant at a Mexican oil refinery, was first characterized by standardized physico-chemical methods. Then experiments were conducted on diluted aqueous DEA solutions to test the effects of Fenton's reagent, ozone and ozone-hydrogen peroxide on the removal of some physicochemical parameters of these solutions. Lastly, biodegradability tests based on Dissolved Organic Carbon Die Away OECD301-A, were carried out on a dilution of the raw aqueous DEA solution and on the treated aqueous DEA solutions, produced by applying the best experimental conditions determined during the aforementioned oxidation tests. Experimental results showed that for aqueous DEA solutions treated with Fenton's reagent, the best degradation rate (70%) was obtained at pH 2.8, with Fe(2+) and H(2)O(2) at doses of 1000 and 10,000 mg/L respectively. In the ozone process, the best degradation (60%) was observed in aqueous DEA solution (100 mg COD/L), using 100 mg O(3)/L at pH 5. In the ozone-hydrogen peroxide process, no COD or DOC removals were observed. The diluted spent diethanolamine solution showed its greatest increase in biodegradability after a reaction period of 28 days when treated with Fenton's reagent, but after only 15 days in the case of ozonation. Copyright © 2011 Elsevier B.V. All rights reserved.

  19. Mesocosm trials of bioremediation of contaminated soil of a petroleum refinery: comparison of natural attenuation, biostimulation and bioaugmentation.

    PubMed

    Couto, M Nazaré P F S; Monteiro, Emanuela; Vasconcelos, M Teresa S D

    2010-08-01

    Contamination with petroleum hydrocarbons (PHC) is a global problem with environmental implications. Physico-chemical treatments can be used for soil cleanup, but they are expensive, and can have implications for soil structure and environment. Otherwise, biological remediation treatments are cost-effective and restore soil structure. Several remediation experiments have been carried out in the lab and in the field; however, there is the challenge to achieve as good or better results in the field as in the laboratory. In the ambit of a project aiming at investigating suitable biological remediation approaches for recovering a refinery contaminated soil, we present here results obtained in bioremediation trials. The approaches biostimulation and bioaugmentation were tested, in parallel, and compared with natural attenuation. For this purpose, mesocosm experiments were carried out inside the refinery area, which constitutes a real asset of this work. Soil contaminated with crude oil was excavated, re-contaminated with turbine oil, homogenised and used to fill several 0.5 m(3) high-density polyethylene containers. The efficiency of procedures as follows: (1) natural attenuation; (2) manual aeration; (3) biostimulation by adding (3.1) only nutrients; and (3.2) nutrients and a non-ionic surfactant; and (4) bioaugmentation in the presence of added (4.1) nutrients or (4.2) nutrients and a non-ionic surfactant were evaluated after a 9-month period of experiment. For bioaugmentation, a commercial bacterial product was used. In addition to physico-chemical characterization, initial and final soil contents in total petroleum hydrocarbons (TPH) (by Fourier transform infrared spectrophotometry) and the total number of bacteria (by total cell counts) were carried out. For TPH degradation evaluation the soil was divided in four fractions corresponding to different depths: 0-5; 5-10; 10-15; and 15-20 cm. Mean values of percentages of PHC degradation varied between 20 and 50% at

  20. 12 CFR 563g.11 - Withdrawal or abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 12 Banks and Banking 5 2010-01-01 2010-01-01 false Withdrawal or abandonment. 563g.11 Section 563g.11 Banks and Banking OFFICE OF THRIFT SUPERVISION, DEPARTMENT OF THE TREASURY SECURITIES OFFERINGS § 563g.11 Withdrawal or abandonment. (a) Any offering circular, amendment, or exhibit may be withdrawn...

  1. Key site abandonment steps in CO2 storage

    NASA Astrophysics Data System (ADS)

    Kühn, M.; Wipki, M.; Durucan, S.; Deflandre, J.-P.; Lüth, S.; Wollenweber, J.; Chadwick, A.; Böhm, G.

    2012-04-01

    CO2CARE is an EU funded project within FP7-research, which started in January 2011 with a funding period of three years. The project objectives will be achieved through an international consortium consisting of 23 partners from Europe, USA, Canada, Japan, and Australia, belonging to universities, research institutes, and energy companies. According to the EC Guidance Document 3, the lifetime of a CO2 storage site can be generally subdivided into 6 phases: 1. assessment, 2. characterisation, 3. development, 4. operation, 5. post-closure/pre-transfer, and 6. post transfer. CO2CARE deals with phases 5 and 6. The main goals of the project are closely linked to the three high-level requirements of the EU Directive 2009/31/EC, Article 18 for CO2 storage which are: (i) absence of any detectable leakage, (ii) conformity of actual behaviour of the injected CO2 with the modelled behaviour, and (iii) the storage site is evolving towards a situation of long-term stability. These criteria have to be fulfilled prior to subsequent transfer of responsibility to the competent authorities, typically 20 or 30 years after site closure. CO2CARE aims to formulate robust procedures for site abandonment which will meet the regulatory requirements and ensure long-term integrity of the storage complex. We present key results from the first year of the project via a report on international regulatory requirements on CO2 geological storage and site abandonment that includes a general overview on the current state-of-the art in abandonment methodologies in the oil and gas industry worldwide. Due to the long time-frames involved in CO2 storage (in the range of several thousands of years), the behaviour of a system with respect to, for example, long-term well stability can be demonstrated only by using long-term predictive modelling tools to study potential leakage pathways. Trapping mechanisms for CO2 are of high interest concerning a quantitative estimation of physically captured, capillary

  2. In Situ Visualization of the Phase Behavior of Oil Samples Under Refinery Process Conditions.

    PubMed

    Laborde-Boutet, Cedric; McCaffrey, William C

    2017-02-21

    To help address production issues in refineries caused by the fouling of process units and lines, we have developed a setup as well as a method to visualize the behavior of petroleum samples under process conditions. The experimental setup relies on a custom-built micro-reactor fitted with a sapphire window at the bottom, which is placed over the objective of an inverted microscope equipped with a cross-polarizer module. Using reflection microscopy enables the visualization of opaque samples, such as petroleum vacuum residues, or asphaltenes. The combination of the sapphire window from the micro-reactor with the cross-polarizer module of the microscope on the light path allows high-contrast imaging of isotropic and anisotropic media. While observations are carried out, the micro-reactor can be heated to the temperature range of cracking reactions (up to 450 °C), can be subjected to H2 pressure relevant to hydroconversion reactions (up to 16 MPa), and can stir the sample by magnetic coupling. Observations are typically carried out by taking snapshots of the sample under cross-polarized light at regular time intervals. Image analyses may not only provide information on the temperature, pressure, and reactive conditions yielding phase separation, but may also give an estimate of the evolution of the chemical (absorption/reflection spectra) and physical (refractive index) properties of the sample before the onset of phase separation.

  3. Artesian Well Abandonment at Launch Complex 39A

    NASA Technical Reports Server (NTRS)

    Morgan, Lindsay; Johansen, Deda

    2015-01-01

    The artesian well tasked for abandonment was located on the LOX side (northwest area) of the launch complex. The exact date of well installation is unknown. The well was no longer in use at the time of the abandonment request, but was previously utilized under St. Johns River Water Management District (SJRWMD) consumptive use permit (No. 50054) for the Floridian Aquifer. The exact construction details of the LOX artesian well were also unknown; however, a similar-type artesian well was previously located on the LH2 side of the site, which was abandoned in 2012. Based on discussions with the NASA RPM and review of the LH2 artesian well abandonment completion report, the LH2 artesian well was reported to be an 8-inch diameter, 330-foot deep well. The NASA RPM communicated that the LOX artesian well was likely to be an 8-inch diameter, 380-foot deep well. This information was used for scoping, and was subsequently confirmed to be substantially accurate. No additional information could be found for the LOX artesian well using the NASA Remediation Information System (RIS).

  4. 40 CFR 80.1240 - How is a refinery's or importer's compliance with the gasoline benzene requirements of this...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... compliance with the gasoline benzene requirements of this subpart determined? 80.1240 Section 80.1240... FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1240 How is a refinery's or importer's compliance with the gasoline benzene requirements of this subpart determined? (a) A refinery's...

  5. 40 CFR 80.1240 - How is a refinery's or importer's compliance with the gasoline benzene requirements of this...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... compliance with the gasoline benzene requirements of this subpart determined? 80.1240 Section 80.1240... FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1240 How is a refinery's or importer's compliance with the gasoline benzene requirements of this subpart determined? (a) A refinery's...

  6. 40 CFR 80.1240 - How is a refinery's or importer's compliance with the gasoline benzene requirements of this...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... compliance with the gasoline benzene requirements of this subpart determined? 80.1240 Section 80.1240... FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1240 How is a refinery's or importer's compliance with the gasoline benzene requirements of this subpart determined? (a) A refinery's...

  7. 40 CFR 80.1240 - How is a refinery's or importer's compliance with the gasoline benzene requirements of this...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... compliance with the gasoline benzene requirements of this subpart determined? 80.1240 Section 80.1240... FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1240 How is a refinery's or importer's compliance with the gasoline benzene requirements of this subpart determined? (a) A refinery's...

  8. 40 CFR 80.1240 - How is a refinery's or importer's compliance with the gasoline benzene requirements of this...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... compliance with the gasoline benzene requirements of this subpart determined? 80.1240 Section 80.1240... FUELS AND FUEL ADDITIVES Gasoline Benzene Gasoline Benzene Requirements § 80.1240 How is a refinery's or importer's compliance with the gasoline benzene requirements of this subpart determined? (a) A refinery's...

  9. Characterization of biosurfactants from indigenous soil bacteria recovered from oil contaminated sites.

    PubMed

    Kumar, Govind; Kumar, Rajesh; Sharma, Anita

    2015-09-01

    Three bacterial isolates (G1, G2 and G3) characterized as Pseudomonas plecoglossicida, Lysinibacillus fusiformis and Bacillus safensis were recovered from contaminated soil of oil refinery. These bacterial isolates produced biosurfactants in MSM medium in stationary phase. Biosurfactants were characterized on the basis of their emulsifying properties with petrol, diesel, mobil oil and petrol engine oil. Reduction in surface tension (below 40 mN m(-1)) and blood hemolysis were also included in biosurfactants characterization. Emulsification indices of G1, G2 and G3 were in the range of 98.82, 23.53 and 58.82 for petrol; 29.411,1.05 and 70.588 for diesel; 35.31, 2.93 and 17.60 for mobil oil and 35.284, 58.82 and 17.647 for petrol engine oil respectively. Dry weight of the extracted biosurfactant was 4.6, 1.4 and 2.4 g I(-1) for G1, G2 and G3 respectively. Structural analysis of the biosurfactants by Fourier Transform Infrared Spectroscopy (FTIR) revealed significant differences in the bonding pattern of individual biosurfactant.

  10. Reuse of refinery's tertiary-treated wastewater in cooling towers: microbiological monitoring.

    PubMed

    Dos Santos, Vera Lúcia; Veiga, Andréa Azevedo; Mendonça, Rafael Silva; Alves, Andrea Lima; Pagnin, Sérgio; Santiago, Vânia M J

    2015-02-01

    The study was planned to quantify the distribution of bacteria between bulk water and biofilm formed on different materials in an industrial scale cooling tower system of an oil refinery operating with clarified and chlorinated freshwater (CCW) or chlorinated tertiary effluent (TRW) as makeup water. The sessile and planktonic heterotrophic bacteria and Pseudomonas aeruginosa densities were significantly higher in the cooling tower supplied with clarified and chlorinated freshwater (CTCW) (p < 0.05). In the two towers, the biofilm density was higher on the surface of glass slides and stainless steel coupons than on the surface of carbon steel coupons. The average corrosion rates of carbon steel coupons (0.4-0.8 millimeters per year (mpy)) and densities of sessile (12-1.47 × 10(3) colony-forming unit (CFU) cm(-1)) and planktonic (0-2.36 × 10(3) CFU mL(-1)) microbiota remained below of the maximum values of reference used by water treatment companies as indicative of efficient microbial control. These data indicate that the strategies of the water treatment station (WTS) (free chlorine) and industrial wastewater treatment station (IWTS) followed by reverse electrodialysis system (RES) (free chlorine plus chloramine) were effective for the microbiological control of the two makeup water sources.

  11. 4. INTERIOR OF ABANDONED SANTA ANA CANAL TUNNEL, SHOWING CEMENT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. INTERIOR OF ABANDONED SANTA ANA CANAL TUNNEL, SHOWING CEMENT TROUGH FLOOR AND UNFINISHED GRANITE ROOF. VIEW TO SOUTHWEST. - Santa Ana River Hydroelectric System, Abandoned Tunnel, Redlands, San Bernardino County, CA

  12. Revitalizing a mature oil play: Strategies for finding and producing oil in Frio Fluvial-Deltaic Sandstone reservoirs of South Texas

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Knox, P.R.; Holtz, M.H.; McRae, L.E.

    Domestic fluvial-dominated deltaic (FDD) reservoirs contain more than 30 Billion barrels (Bbbl) of remaining oil, more than any other type of reservoir, approximately one-third of which is in danger of permanent loss through premature field abandonments. The U.S. Department of Energy has placed its highest priority on increasing near-term recovery from FDD reservoirs in order to prevent abandonment of this important strategic resource. To aid in this effort, the Bureau of Economic Geology, The University of Texas at Austin, began a 46-month project in October, 1992, to develop and demonstrate advanced methods of reservoir characterization that would more accurately locatemore » remaining volumes of mobile oil that could then be recovered by recompleting existing wells or drilling geologically targeted infill. wells. Reservoirs in two fields within the Frio Fluvial-Deltaic Sandstone (Vicksburg Fault Zone) oil play of South Texas, a mature play which still contains 1.6 Bbbl of mobile oil after producing 1 Bbbl over four decades, were selected as laboratories for developing and testing reservoir characterization techniques. Advanced methods in geology, geophysics, petrophysics, and engineering were integrated to (1) identify probable reservoir architecture and heterogeneity, (2) determine past fluid-flow history, (3) integrate fluid-flow history with reservoir architecture to identify untapped, incompletely drained, and new pool compartments, and (4) identify specific opportunities for near-term reserve growth. To facilitate the success of operators in applying these methods in the Frio play, geologic and reservoir engineering characteristics of all major reservoirs in the play were documented and statistically analyzed. A quantitative quick-look methodology was developed to prioritize reservoirs in terms of reserve-growth potential.« less

  13. Biotechnological potential of Bacillus salmalaya 139SI: a novel strain for remediating water polluted with crude oil waste.

    PubMed

    Ismail, Salmah; Dadrasnia, Arezoo

    2015-01-01

    Environmental contamination by petroleum hydrocarbons, mainly crude oil waste from refineries, is becoming prevalent worldwide. This study investigates the bioremediation of water contaminated with crude oil waste. Bacillus salamalaya 139SI, a bacterium isolated from a private farm soil in the Kuala Selangor in Malaysia, was found to be a potential degrader of crude oil waste. When a microbial population of 108 CFU ml-1 was used, the 139SI strain degraded 79% and 88% of the total petroleum hydrocarbons after 42 days of incubation in mineral salt media containing 2% and 1% of crude oil waste, respectively, under optimum conditions. In the uninoculated medium containing 1% crude oil waste, 6% was degraded. Relative to the control, the degradation was significantly greater when a bacteria count of 99 × 108 CFU ml-1 was added to the treatments polluted with 1% oil. Thus, this isolated strain is useful for enhancing the biotreatment of oil in wastewater.

  14. Biotechnological Potential of Bacillus salmalaya 139SI: A Novel Strain for Remediating Water Polluted with Crude Oil Waste

    PubMed Central

    2015-01-01

    Environmental contamination by petroleum hydrocarbons, mainly crude oil waste from refineries, is becoming prevalent worldwide. This study investigates the bioremediation of water contaminated with crude oil waste. Bacillus salamalaya 139SI, a bacterium isolated from a private farm soil in the Kuala Selangor in Malaysia, was found to be a potential degrader of crude oil waste. When a microbial population of 108 CFU ml-1 was used, the 139SI strain degraded 79% and 88% of the total petroleum hydrocarbons after 42 days of incubation in mineral salt media containing 2% and 1% of crude oil waste, respectively, under optimum conditions. In the uninoculated medium containing 1% crude oil waste, 6% was degraded. Relative to the control, the degradation was significantly greater when a bacteria count of 99 × 108 CFU ml-1 was added to the treatments polluted with 1% oil. Thus, this isolated strain is useful for enhancing the biotreatment of oil in wastewater. PMID:25875763

  15. Life Cycle Assessment for the Production of Oil Palm Seeds

    PubMed Central

    Muhamad, Halimah; Ai, Tan Yew; Khairuddin, Nik Sasha Khatrina; Amiruddin, Mohd Din; May, Choo Yuen

    2014-01-01

    The oil palm seed production unit that generates germinated oil palm seeds is the first link in the palm oil supply chain, followed by the nursery to produce seedling, the plantation to produce fresh fruit bunches (FFB), the mill to produce crude palm oil (CPO) and palm kernel, the kernel crushers to produce crude palm kernel oil (CPKO), the refinery to produce refined palm oil (RPO) and finally the palm biodiesel plant to produce palm biodiesel. This assessment aims to investigate the life cycle assessment (LCA) of germinated oil palm seeds and the use of LCA to identify the stage/s in the production of germinated oil palm seeds that could contribute to the environmental load. The method for the life cycle impact assessment (LCIA) is modelled using SimaPro version 7, (System for Integrated environMental Assessment of PROducts), an internationally established tool used by LCA practitioners. This software contains European and US databases on a number of materials in addition to a variety of European- and US-developed impact assessment methodologies. LCA was successfully conducted for five seed production units and it was found that the environmental impact for the production of germinated oil palm was not significant. The characterised results of the LCIA for the production of 1000 germinated oil palm seeds showed that fossil fuel was the major impact category followed by respiratory inorganics and climate change. PMID:27073598

  16. Options for reducing oil content of sludge from a petroleum wastewater treatment plant.

    PubMed

    Kwon, Tae-Soon; Lee, Jae-Young

    2015-10-01

    Wastewater treatment plants at petroleum refineries often produce substantial quantities of sludge with relatively high concentrations of oil. Disposal of this waste is costly, in part because the high oil content requires use of secure disposal methods akin to handling of hazardous wastes. This article examines the properties of oily sludge and evaluates optional methods for reducing the oil content of this sludge to enable use of lower cost disposal methods. To reduce the oil content or break the structure of oily sludge, preliminary lab-scale experiments involving mechanical treatment, surfactant extraction, and oxidation are conducted. By applying surfactants, approximately 36% to 45% of oils are extracted from oily sludge. Of this, about 33% of oils are rapidly oxidised via radiation by an electron beam within 10 s of exposure. The Fenton reaction is effective for destruction of oily sludge. It is also found that 56% of oils were removed by reacting oily sludge with water containing ozone of 0.5 mg l(-1) over a period of 24 h. Oxidation using ozone thus can also be effectively used as a pretreatment for oily sludge. © The Author(s) 2015.

  17. 30 CFR 938.20 - Approval of Pennsylvania abandoned mine land reclamation plan.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of Pennsylvania abandoned mine land... PENNSYLVANIA § 938.20 Approval of Pennsylvania abandoned mine land reclamation plan. The Pennsylvania Abandoned... are available at the following locations: (a) Pennsylvania Department of Environmental Resources...

  18. Determinants of tuberculosis transmission and treatment abandonment in Fortaleza, Brazil.

    PubMed

    Harling, Guy; Lima Neto, Antonio S; Sousa, Geziel S; Machado, Marcia M T; Castro, Marcia C

    2017-05-25

    Tuberculosis (TB) remains a public health problem, despite recent achievements in reducing incidence and mortality rates. In Brazil, these achievements were above the worldwide average, but marked by large regional heterogeneities. In Fortaleza (5th largest city in Brazil), the tuberculosis cure rate has been declining and treatment abandonment has been increasing in the past decade, despite a reduction in incidence and an increase in directly observed therapy (DOT). These trends put efforts to eliminate tuberculosis at risk. We therefore sought to determine social and programmatic determinants of tuberculosis incidence and treatment abandonment in Fortaleza. We analyzed sociodemographic and clinical data for all new tuberculosis cases notified in the Notifiable Diseases Information System (SINAN) from Fortaleza between 2007 and 2014. We calculated incidence rates for 117 neighborhoods in Fortaleza, assessed their spatial clustering, and used spatial regression models to quantify associations between neighborhood-level covariates and incidence rates. We used hierarchical logistic regression models to evaluate how individual- and neighborhood-level covariates predicted tuberculosis treatment abandonment. There were 12,338 new cases reported during the study period. Case rates across neighborhoods were significantly positively clustered in two low-income areas close to the city center. In an adjusted model, tuberculosis rates were significantly higher in neighborhoods with lower literacy, higher sewerage access and homicide rates, and a greater proportion of self-reported black residents. Treatment was abandoned in 1901 cases (15.4%), a rate that rose by 71% between 2007 and 2014. Abandonment was significantly associated with many individual sociodemographic and clinical factors. Notably, being recommended for DOT was protective for those who completed DOT, but associated with abandonment for those who did not. Low socioeconomic status areas have higher tuberculosis

  19. Management of soybean oil refinery wastes through recycling them for producing biosurfactant using Pseudomonas aeruginosa MR01.

    PubMed

    Partovi, Maryam; Lotfabad, Tayebe Bagheri; Roostaazad, Reza; Bahmaei, Manochehr; Tayyebi, Shokoufe

    2013-06-01

    Biosurfactant production through a fermentation process involving the biodegradation of soybean oil refining wastes was studied. Pseudomonas aeruginosa MR01 was able to produce extracellular biosurfactant when it was cultured in three soybean oil refinement wastes; acid oil, deodorizer distillate and soapstock, at different carbon to nitrogen ratios. Subsequent fermentation kinetics in the three types of waste culture were also investigated and compared with kinetic behavior in soybean oil medium. Biodegradation of wastes, biosurfactant production, biomass growth, nitrate consumption and the number of colony forming units were detected in four proposed media, at specified time intervals. Unexpectedly, wastes could stimulate the biodegradation activity of MR01 bacterial cells and thus biosurfactant synthesis beyond that of the refined soybean oil. This is evident from higher yields of biodegradation and production, as revealed in the waste cultures (Ydeg|(Soybean oil) = 53.9 % < Ydeg|(wastes) and YP/S|(wastes) > YP/S|(Soybean oil) = 0.31 g g(-1), respectively). Although production yields were approximately the same in the three waste cultures (YP/S|(wastes) =/~ 0.5 g g(-1)), microbial activity resulted in higher yields of biodegradation (96.5 ± 1.13 %), maximum specific growth rate (μ max = 0.26 ± 0.02 h(-1)), and biosurfactant purity (89.6 %) with a productivity of 14.55 ± 1.10 g l(-1), during the bioconversion of soapstock into biosurfactant. Consequently, applying soybean oil soapstock as a substrate for the production of biosurfactant with commercial value has the potential to provide a combination of economical production with environmental protection through the biosynthesis of an environmentally friendly (green) compound and reduction of waste load entering the environment. Moreover, this work inferred spectrophotometry as an easy method to detect rhamnolipids in the biosurfactant products.

  20. New Yumurtalik to Kirikkale crude-oil pipeline would boost Turkish industrial area

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simonnet, G.

    1982-12-13

    Plans for a crude oil pipeline linking the 101 cm (40 in.) Iraq to Turkey pipeline terminal located in Yumurtalik to the site of a future refinery to be situated near Ankara are described. Designed for fully unattended operation, the ''brain'' of the system will be a telecom/telecontrol telemetry system. Support for data information exchanged between the master and local outstations will be a microwave radio carrier system, also permitting the transfer of telephone and telegraph traffic as well as facsimiles.

  1. Platinum salt sensitivity in refinery workers: incidence and effects of smoking and exposure.

    PubMed Central

    Calverley, A E; Rees, D; Dowdeswell, R J; Linnett, P J; Kielkowski, D

    1995-01-01

    OBJECTIVE--To measure the incidence of platinum salt sensitivity (PSS) in refinery workers and examine the influence of cigarette smoking and exposure to platinum salts on sensitisation. DESIGN--A prospective cohort study with examination of workers at quarterly intervals for 18 months, and again at 24 months. SETTING--A South African primary platinum refinery. SUBJECTS--78 new recruits, selected by the refinery's usual procedure, without apparent atopy and in good respiratory health. RESULTS--After 24 months 32 (41%) subjects had been diagnosed PSS and were subsequently medically separated. Twenty two (28%) cases were confirmed by positive skin prick test to platinum salts, 10 (13%) cases were symptomatic but skin prick negative. Incidence of cases per 100 person-months was 1.9 skin prick positive and 0.8 negative. Risk of sensitisation was about eight times greater for smokers than non-smokers, and six times greater for high exposure than low exposure. CONCLUSION--Smoking and intensity of exposure were definitely associated with development of PSS. Positive responses to platinum salt skin prick test had a 100% positive predictive value for symptoms and signs of PSS if exposure continued. PMID:7489056

  2. 77 FR 35751 - Wisconsin Central Ltd.-Abandonment Exemption-in Manitowoc County, WI

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-14

    ... DEPARTMENT OF TRANSPORTATION Surface Transportation Board [Docket No. AB 303 (Sub-No. 39X)] Wisconsin Central Ltd.--Abandonment Exemption--in Manitowoc County, WI Wisconsin Central Ltd. (WCL) has filed a verified notice of exemption under 49 CFR part 1152 subpart F--Exempt Abandonments to abandon 6...

  3. Final Environmental Impact Statement for Oil Refinery, Georgetown, South Carolina. Volume 2.

    DTIC Science & Technology

    1984-09-01

    at gauging and pumping stations. _adio and telephone communication exists between gaugers and pumping stations or vessels. 2. Describe secondary...thickness gauging . 4. Internal heatingO coil leakage is controlled by one or more of the following control factors: (a) M onitoring the steam return...behavior of sediment and oil emulsions. Journal of Sedimentary Petrology 47(2):671-677. Beam, H.W., South Carolina Coastal Council. [Letter to J.E. Jenkins

  4. Bioactive compounds from palm fatty acid distillate and crude palm oil

    NASA Astrophysics Data System (ADS)

    Estiasih, T.; Ahmadi, K.

    2018-03-01

    Crude palm oil (CPO) and palm fatty acid distillate (PFAD) are rich sources of bioactive compounds. PFAD is a by-product of palm oil refinery that produce palm frying oil. Physical refining of palm oil by deodorization produces palm fatty acid distillate. CPO and PFAD contain some bioactive compounds such as vitamin E (tocopherol and tocotrienols), phytosterol, and squalene. Bioactive compounds of CPO and PFAD are vitamin E, phytosterols, and squalene. Vitamin E of CPO and PFAD mainly comprised of tocotrienols and the remaining is tocopherol. Phytosterols of CPO and PFAD contained beta sitosterol, stigmasterol, and campesterol. Tocotrienols and phytosterols of CPO and PFAD, each can be separated to produce tocotrienol rich fraction and phytosterol rich fraction. Tocotrienol rich fraction from PFAD has both antioxidant and cholesterol lowering properties. Bioactive compounds of PFAD silmultaneously have been proven to improve lipid profile, and have hepatoprotector effect, imunomodulator, antioxidant properties, and lactogenic effect in animal test experiment. It is possible to develop separation of bioactive compounds of CPO and PFAD integratively with the other process that utilizes fatty acid.

  5. Battle of the starches: Insoluble versus soluble at the refinery

    USDA-ARS?s Scientific Manuscript database

    A study using the USDA starch research method has been conducted to evaluate the effects of total, insoluble, and soluble starch on raw sugar filterability and viscosity in international carbonatation refineries. Raw sugar qualities, i.e., pol, color, % invert, ash, and dextran, were also studied in...

  6. Effect of omega-3 and ascorbic acid on inflammation markers in depressed shift workers in Shahid Tondgoyan Oil Refinery, Iran: a randomized double-blind placebo-controlled study

    PubMed Central

    Khajehnasiri, Farahnaz; Mortazavi, Seyed Bagher; Allameh, Abdolamir; Akhondzadeh, Shahin

    2013-01-01

    The present study aimed to assess the effect of supplementation of omega-3 and/or vitamin C on serum interleukin-6 and high sensitivity C-reactive protein concentration and depression scores among shift workers in Shahid Tondgoyan oil refinery. The study design was randomized, double-blind, placebo-controlled, parallel trial. Totally 136 shift workers with a depression score ≥10 in 21-item Beck Depression Rating Scale were randomly assigned to receive omega-3 (180 mg eicosapentaenoate acid and 120 mg docosahexaenoic acid) or/and vitamin C 250 mg or placebo twice daily (with the same taste and shape as omega-3 and vitamin C) for 60 days in four groups. Depression score, interleukin-6 and high sensitivity C-reactive protein were measured at baseline and after 60 days. This study showed that supplementation of omega-3 plus vitamin C is associated with a decrease in depression score (p<0.05). Supplementation of omega-3 without vitamin C, is associated with a reduction in depression score (p<0.0001) and high sensitivity C-reactive protein concentration (p<0.01). Therefore omega-3 supplementation showed a better effect on reducing depression score and high sensitivity C-reactive protein, but supplementation of vitamin C along with omega-3 did not have significant effect on change in C-reactive protein level compared to omega-3 alone. (Registration number: IRCT201202189056N1) PMID:23874068

  7. Synthetic Minor NSR Permit: Chemtrade Refinery Services, Inc. Riverton, Wyoming Facility

    EPA Pesticide Factsheets

    This page contains the response to public comments and final synthetic minor NSR permit for the Chemtrade Refinery Services, Inc. Riverton, Wyoming Facility, operated by Chemtrade Logistics and located on the Wind River Indian Reservation in Fremont County

  8. 32 CFR 635.31 - Lost, abandoned, or unclaimed property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Lost, abandoned, or unclaimed property. 635.31 Section 635.31 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) LAW ENFORCEMENT AND CRIMINAL INVESTIGATIONS LAW ENFORCEMENT REPORTING Offense Reporting § 635.31 Lost, abandoned, or unclaimed property. This is...

  9. 40 CFR 80.205 - How is the annual refinery or importer average and corporate pool average sulfur level determined?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... average and corporate pool average sulfur level determined? 80.205 Section 80.205 Protection of... ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80.205 How is the annual refinery or importer average and corporate pool average sulfur level determined? (a) The annual refinery or importer average and...

  10. 40 CFR 80.205 - How is the annual refinery or importer average and corporate pool average sulfur level determined?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... average and corporate pool average sulfur level determined? 80.205 Section 80.205 Protection of... ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80.205 How is the annual refinery or importer average and corporate pool average sulfur level determined? (a) The annual refinery or importer average and...

  11. 40 CFR 80.205 - How is the annual refinery or importer average and corporate pool average sulfur level determined?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... average and corporate pool average sulfur level determined? 80.205 Section 80.205 Protection of... ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80.205 How is the annual refinery or importer average and corporate pool average sulfur level determined? (a) The annual refinery or importer average and...

  12. 40 CFR 80.205 - How is the annual refinery or importer average and corporate pool average sulfur level determined?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... average and corporate pool average sulfur level determined? 80.205 Section 80.205 Protection of... ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80.205 How is the annual refinery or importer average and corporate pool average sulfur level determined? (a) The annual refinery or importer average and...

  13. Nurses' Attitudes and Knowledge of Their Roles in Newborn Abandonment

    PubMed Central

    Cesario, Sandra K.

    2003-01-01

    The practice of abandoning newborns shortly after birth has always existed. Occurring in primitive and contemporary societies, the motivations for newborn abandonment are varied and dependent upon the social norms of a specific geographic region at a given point in time. Because the desire to abandon an infant has had no support system in American society, such unwanted infants have been abandoned in a manner leading to their deaths. In response, many states have passed safe-haven legislation to save the lives of unwanted newborns. The laws typically specify a mother's ability to “abandon” her child to a medical service provider. However, judgmental attitudes and a lack of accurate information may impede a health care provider's ability to carry out a safe-haven law. The study described here examines a sample of nurses in a state with a safe-haven law. The study revealed no significant correlation between a nurse's knowledge, attitude, and self-perception of preparedness to manage a newborn abandonment event. owever, the outcomes highlight the negative attitudes and lack of knowledge many nurses possess regarding newborn abandonment and the women who commit this act. Educational programs for all health care providers and the community are essential to the efficacy of the legislation that currently exists. Continued multidisciplinary strategizing and general awareness are needed to serve as catalysts to build supports for unwanted newborns and their safe assimilation into the community. PMID:17273338

  14. Mössbauer effect study of corrosion products from a Brazilian oil refinery

    NASA Astrophysics Data System (ADS)

    da Costa, M. I.; Kunrath, J. I.; Moro, J. T.; da Cunha, J. B. M.; Englert, G.; Comparsi, L. U.; Muller, I. L.

    1993-04-01

    Corrosion of an oil refining plant in southern Brazil is controlled by placing metallic coupons in strategic places of the unit. The amount of the corrosion products formed after two months of exposure of the coupons is then obtained by weight loss measurements. To have a better insight of these products an analysis by Conversion Electron and transmission Mössbauer spectroscopies was done on some of the coupons. This paper reports some of the findings.

  15. Lymphohematopoietic cancer mortality and morbidity of workers in a refinery/petrochemical complex in Korea.

    PubMed

    Koh, Dong-Hee; Kim, Tae-Woo; Yoon, Yong-Hoon; Shin, Kyung-Seok; Yoo, Seung-Won

    2011-03-01

    The purpose of this retrospective cohort study was to investigate the relationship between exposure of Korean workers to petrochemicals in the refinery/petrochemical industry and lymphohematopoietic cancers. The cohort consisted of 8,866 male workers who had worked from the 1960s to 2007 at one refinery and six petrochemical companies located in a refinery/petrochemical complex in Korea that produce benzene or use benzene as a raw material. Standardized mortality ratios (SMRs) and standardized incidence ratios (SIRs) were calculated for 1992-2007 and 1997-2005 based on the death rate and cancer incidence rate of the Korean male population according to job title (production, maintenance, laboratory, and office workers). The overall mortality and most cause-specific mortalities were lower among these workers than those of the general Korean population. Increased SMRs were observed for leukemia (4/1.45; SMR 2.77, 95% CI: 0.75-7.09) and lymphohematopoietic cancers (5/2.51; SMR 2, 95% CI: 0.65-4.66) in production workers, and increased SIRs were also observed in leukemia (3/1.34; SIR 2.24, 95% CI: 0.46-6.54) and lymphohematopoietic cancers (5/3.39; SIR 1.47, 95% CI: 0.48-3.44) in production workers, but the results were not statistically significant. The results showed a potential relationship between leukemia and lymphohematopoietic cancers and exposure to benzene in refinery/petrochemical complex workers. This study yielded limited results due to a short observational period; therefore, a follow-up study must be performed to elucidate the relationship between petrochemical exposure and cancer rates.

  16. Resource recycling technique of abandoned TNT-RDX-AL mixed explosive

    NASA Astrophysics Data System (ADS)

    Chen, Siyang; Ding, Yukui

    2017-08-01

    TNT-RDX-AL mixed explosive is a kind of high energy mixed explosive. It has the detonation characteristics even when reaching the scrapping standard. Inappropriate disposal often causes serious accident. Employing the resource recycling technique, the abandoned TNT-RDX-AL mixed explosive can be recycled. This paper summarized the progress of recycling of abandoned mixed explosive. What's more, three kinds of technological process of resource recycling abandoned TNT-RDX-AL mixed explosives are introduced. The author analysis of the current recovery processes and provided a reference for the recycling of the other same type explosive.

  17. Numerical Simulation of Abandoned Gob Methane Drainage through Surface Vertical Wells

    PubMed Central

    Hu, Guozhong

    2015-01-01

    The influence of the ventilation system on the abandoned gob weakens, so the gas seepage characteristics in the abandoned gob are significantly different from those in a normal mining gob. In connection with this, this study physically simulated the movement of overlying rock strata. A spatial distribution function for gob permeability was derived. A numerical model using FLUENT for abandoned gob methane drainage through surface wells was established, and the derived spatial distribution function for gob permeability was imported into the numerical model. The control range of surface wells, flow patterns and distribution rules for static pressure in the abandoned gob under different well locations were determined using the calculated results from the numerical model. PMID:25955438

  18. Mechanism of removal of undesirable residual amylase, insoluble starch, and select colorants from refinery streams by powdered activated carbons

    USDA-ARS?s Scientific Manuscript database

    There is a need in the world-wide sugar industry to find a practical and economical solution to remove or inactivate residual alpha-amylases that are high temperature stable from factory or refinery streams. A survey of refineries that used amylase and had activated carbon systems for decolorization...

  19. Alternative Fuels Data Center: Rhode Island Transportation Data for

    Science.gov Websites

    (million cubic feet) 94,453 Conventional Power Plants 10 Generating Capacity (nameplate, MW) 1,991 Oil Refineries 0 Oil Refinery Capacity (bbl/day) 0 Renewable Power Plants 2 Renewable Power Plant Capacity More Rhode Island Videos on YouTube Video thumbnail for Cooking Oil Powers Biodiesel Vehicles in Rhode

  20. Petroleum Refineries New Source Performance Standards (NSPS) Direct Final Amendments Fact Sheet

    EPA Pesticide Factsheets

    This page contains a December 2013 fact sheet with information regarding the direct final rule for the NSPS for Petroleum Refineries. This document provides a summary of the information for this NSPS.

  1. Detecting abandoned objects using interacting multiple models

    NASA Astrophysics Data System (ADS)

    Becker, Stefan; Münch, David; Kieritz, Hilke; Hübner, Wolfgang; Arens, Michael

    2015-10-01

    In recent years, the wide use of video surveillance systems has caused an enormous increase in the amount of data that has to be stored, monitored, and processed. As a consequence, it is crucial to support human operators with automated surveillance applications. Towards this end an intelligent video analysis module for real-time alerting in case of abandoned objects in public spaces is proposed. The overall processing pipeline consists of two major parts. First, person motion is modeled using an Interacting Multiple Model (IMM) filter. The IMM filter estimates the state of a person according to a finite-state, discrete-time Markov chain. Second, the location of persons that stay at a fixed position defines a region of interest, in which a nonparametric background model with dynamic per-pixel state variables identifies abandoned objects. In case of a detected abandoned object, an alarm event is triggered. The effectiveness of the proposed system is evaluated on the PETS 2006 dataset and the i-Lids dataset, both reflecting prototypical surveillance scenarios.

  2. Abandonment of newborn infants: a Danish forensic medical survey 1997-2008.

    PubMed

    Gheorghe, Alexandra; Banner, Jytte; Hansen, Steen Holger; Stolborg, Uffe; Lynnerup, Niels

    2011-12-01

    Concealment of pregnancy and newborn infant abandonment are closely associated with neonaticide, the killing of an infant within the first 24 h of life or less than 28-30 days depending on the jurisdiction. Abandonment of newborn infants occurs throughout the world and often the outcome for the infant is death. Together with neonaticide it is felt to be one of the least preventable crimes. In this retrospective study we present all forensically known Danish cases of abandoned newborn infant corpses, covering the period from 1997 to 2008. Eleven newborn infant corpses were found; we registered characteristics of the newborn infants and the circumstances of the cases based on autopsy reports. One further newborn infant was included, dating back to 1992, as it was found to be connected with one of the later cases. The mean age of the women who abandoned their newborn infants was 22 years, and five of the autopsied newborn infants were probably alive when abandoned. In two cases the newborn infants were half siblings and abandoned by the same mother. The time span from abandonment to when the newborn infant was found ranged from hours to 7 years. Two-thirds of the newborn infants were girls (66.6%). The most common means of disposal was in a plastic bag (~60%); only one newborn infant was wearing clothes when found. Causes of death were usually given as asphyxia, brain injury or simply undetermined. Two-thirds of the newborn infants showed signs of violence. None of the newborn infants had congenital malformations.

  3. Oil removal from petroleum sludge using bacterial culture with molasses substrate at temperature variation

    NASA Astrophysics Data System (ADS)

    Ni'matuzahroh, Puspitasari, Alvin Oktaviana; Pratiwi, Intan Ayu; Fatimah, Sumarsih, Sri; Surtiningsih, Tini; Salamun

    2016-03-01

    The study aims to reveal the potency of biosurfactant-producing bacterial culture with molasses as substrate growth in releasing oil from the petroleum sludge at temperature variations. Bacteria used consisted of (Acinetobacter sp. P2(1), Pseudomonas putida T1(8), Bacillus subtilis 3KP and Micrococcus sp. L II 61). The treatments were tested at 40°C, 50°C and 60 °C for 7 days of incubation. Synthetic surfactant (Tween 20) was used as a positive control and molasses as a negative control. Release of petroleum hydrocarbons from oil sludge was expressed in percentage of oil removal from oil sludge (%). Data were analyzed statistically using the Analysis of Variance (α = 0.05) and continued with Games-Howell test. The kinds of bacterial cultures, incubation temperature and combination of both affected the percentage of oil removal. The abilities of Bacillus subtilis 3KP and Micrococcus sp. LII 61cultures in oil removal from oil sludge at the temperature exposure of 60°C were higher than Tween 20. Both of bacterial cultures grown on molasses can be proposed as a replacement for synthetic surfactant to clean up the accumulation of oil sludge in a bottom of oil refinery tank.

  4. 41 CFR 109-45.902-2 - Abandonment or destruction without notice.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... UTILIZATION AND DISPOSAL 45-SALE, ABANDONMENT, OR DESTRUCTION OF PERSONAL PROPERTY 45.9-Abandonment or... destruction without public notice of personal property. The OPMO shall review and coordinate on the findings. ...

  5. Effects of light on the cytotoxicity and genotoxicity of benzo(a)pyrene and an oil refinery effluent in the newt

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fernandez, M.; l`Haridon, J.

    1994-12-31

    The genotoxicity and/or toxicity of benzo(a)pyrene (BaP) were evaluated under different lighting conditions in larvae and embryos of the newt Pleurodeles waltl. Visible light alone, UVA alone, or BaP alone had no toxic effects on the larvae. Conversely, toxic effects were observed in animals exposed to BaP + daylight, or BaP + UVA. The genotoxicity of BaP (50 ppb) was halved by its previous exposure to UVA, and was abolished at the lowest concentration (12.5 ppb). In other experiments, the larvae were exposed alternatively to BaP or Irr BaP (18 hours in dark) and UVA (6 hr in water), everymore » day for 8 days. All animals that had accumulated non-irradiated BaP (50 ppb) showed signs of severe toxicity, and 90% died before the end of the test. On the other hand, irradiated BaP (50 ppb) was a 4-fold less toxic and half as genotoxic as non-irradiated BaP. In addition, exposure of the animals to UVA alone for 4 days prior to treatment with BaP did not affect the genotoxicity or toxicity of this hydrocarbon. In the dark, the embryotoxicity of BaP was markedly attenuated by the presence of the jelly coats. Although UVA alone did not affect growth of the embryos, the toxicity of BaP was enhanced by the combined action of the two agents together or in succession (BaP + UVA or BaP then UVA). Larvae were treated with an oil refinery effluent (EF). At 125 ml/l, EF was not found to be genotoxic in the dark. However, in animals exposed to both EF and UVA, there was a progressive increase in level of micronucleated erythrocytes with increasing duration of daily exposure to UVA. Moreover, the genotoxic potential of irradiated EF + UVA was systematically below that of non-irradiated EF + UVA for all durations of exposure to ultraviolet light. Irradiation of this type of effluent might help reduce its harmful effects on aquatic species. Our results also suggest that metabolic activation is not necessary for hydrocarbons to induce toxic effects. 51 refs., 5 tabs., 3 figs.« less

  6. Factors associated with abandonment of therapy by children diagnosed with solid tumors in Peru.

    PubMed

    Vasquez, Liliana; Diaz, Rosdali; Chavez, Sharon; Tarrillo, Fanny; Maza, Ivan; Hernandez, Eddy; Oscanoa, Monica; García, Juan; Geronimo, Jenny; Rossell, Nuria

    2018-06-01

    Abandonment of treatment is a major cause of treatment failure and poor survival in children with cancer in low- and middle-income countries. The incidence of treatment abandonment in Peru has not been reported. The aim of this study was to examine the prevalence of and factors associated with treatment abandonment by pediatric patients with solid tumors in Peru. We retrospectively reviewed the sociodemographic and clinical data of children referred between January 2012 and December 2014 to the two main tertiary centers for childhood cancer in Peru. The definition of treatment abandonment followed the International Society of Paediatric Oncology, Paediatric Oncology in Developing Countries, Abandonment of Treatment recommendation. Data from 1135 children diagnosed with malignant solid tumors were analyzed, of which 209 (18.4%) abandoned treatment. Bivariate logistic regression analysis showed significantly higher abandonment rates in children living outside the capital city, Lima (forest; odds ratio [OR] 3.25; P < 0.001), those living in a rural setting (OR 3.44; P < 0.001), and those whose parent(s) lacked formal employment (OR 4.39; P = 0.001). According to cancer diagnosis, children with retinoblastoma were more likely to abandon treatment compared to children with other solid tumors (OR 1.79; P = 0.02). In multivariate regression analyses, rural origin (OR 2.02; P = 0.001) and lack of formal parental employment (OR 2.88; P = 0.001) were independently predictive of abandonment. Treatment abandonment prevalence of solid tumors in Peru is high and closely related to sociodemographical factors. Treatment outcomes could be substantially improved by strategies that help prevent abandonment of therapy based on these results. © 2018 Wiley Periodicals, Inc.

  7. Study of Water-Oil Emulsion Breaking by Stabilized Solution Consisting of Anionic Surface Acting Agent - Soda Ash - Polymer (ASP)

    NASA Astrophysics Data System (ADS)

    Kulichkov, S. V.; Avtomonov, E. G.; Andreeva, L. V.; Solomennik, S. F.; Nikitina, A. V.

    2018-01-01

    The paper provides a laboratory research of breaking natural water-oil emulsions: - by non-stabilized ASP; by stabilized ASP; by mixture of stabilized and non-stabilized ASP in different proportions and production of refinery water of the required quality with the use of IronGuard 2495 as flocculant. Oil-in-water emulsion is stable. Classic methods are not suitable for residual water treatment: sediment gravity flow; filtration; centrifuge test. Microemulsion formed after ASP application has low boundary tension and high pH. It contributes to transfer of oil phase into a water one, forming oil-in-water emulsion. Alkaline condition has adverse effect on demulsifying ability of agents, flocculation and boundary tension. For breaking of water-oil emulsion at EBU before the interchanger water or water-oil emulsion from the wells that were not APS-treated in ratio of 1:9 shall be delivered. Residual water after EBU must be prepared in water tanks by dilution in great volume.

  8. Application of Ozone MBBR Process in Refinery Wastewater Treatment

    NASA Astrophysics Data System (ADS)

    Lin, Wang

    2018-01-01

    Moving Bed Biofilm Reactor (MBBR) is a kind of sewage treatment technology based on fluidized bed. At the same time, it can also be regarded as an efficient new reactor between active sludge method and the biological membrane method. The application of ozone MBBR process in refinery wastewater treatment is mainly studied. The key point is to design the ozone +MBBR combined process based on MBBR process. The ozone +MBBR process is used to analyze the treatment of concentrated water COD discharged from the refinery wastewater treatment plant. The experimental results show that the average removal rate of COD is 46.0%~67.3% in the treatment of reverse osmosis concentrated water by ozone MBBR process, and the effluent can meet the relevant standard requirements. Compared with the traditional process, the ozone MBBR process is more flexible. The investment of this process is mainly ozone generator, blower and so on. The prices of these items are relatively inexpensive, and these costs can be offset by the excess investment in traditional activated sludge processes. At the same time, ozone MBBR process has obvious advantages in water quality, stability and other aspects.

  9. Book review: old fields: dynamics and restoration of abandoned farmland

    USDA-ARS?s Scientific Manuscript database

    The 2007 volume, “Old Fields: Dynamics and Restoration of Abandoned Farmland”, edited by VA Cramer and RJ Hobbs and published by the Society for Ecological Restoration International (Island Press), is a valuable attempt to synthesize a dozen case studies on agricultural abandonment from all of the ...

  10. 40 CFR 144.62 - Cost estimate for plugging and abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... must revise the plugging and abandonment cost estimate whenever a change in the plugging and... 40 Protection of Environment 23 2011-07-01 2011-07-01 false Cost estimate for plugging and abandonment. 144.62 Section 144.62 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER...

  11. Lymphohematopoietic Cancer Mortality and Morbidity of Workers in a Refinery/Petrochemical Complex in Korea

    PubMed Central

    Kim, Tae-Woo; Yoon, Yong-Hoon; Shin, Kyung-Seok; Yoo, Seung-Won

    2011-01-01

    Objectives The purpose of this retrospective cohort study was to investigate the relationship between exposure of Korean workers to petrochemicals in the refinery/petrochemical industry and lymphohematopoietic cancers. Methods The cohort consisted of 8,866 male workers who had worked from the 1960s to 2007 at one refinery and six petrochemical companies located in a refinery/petrochemical complex in Korea that produce benzene or use benzene as a raw material. Standardized mortality ratios (SMRs) and standardized incidence ratios (SIRs) were calculated for 1992-2007 and 1997-2005 based on the death rate and cancer incidence rate of the Korean male population according to job title (production, maintenance, laboratory, and office workers). Results The overall mortality and most cause-specific mortalities were lower among these workers than those of the general Korean population. Increased SMRs were observed for leukemia (4/1.45; SMR 2.77, 95% CI: 0.75-7.09) and lymphohematopoietic cancers (5/2.51; SMR 2, 95% CI: 0.65-4.66) in production workers, and increased SIRs were also observed in leukemia (3/1.34; SIR 2.24, 95% CI: 0.46-6.54) and lymphohematopoietic cancers (5/3.39; SIR 1.47, 95% CI: 0.48-3.44) in production workers, but the results were not statistically significant. Conclusion The results showed a potential relationship between leukemia and lymphohematopoietic cancers and exposure to benzene in refinery/petrochemical complex workers. This study yielded limited results due to a short observational period; therefore, a follow-up study must be performed to elucidate the relationship between petrochemical exposure and cancer rates. PMID:22953184

  12. 76 FR 1211 - Union Pacific Railroad Company-Abandonment Exemption-In Wright County, IA

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-07

    ... DEPARTMENT OF TRANSPORTATION Surface Transportation Board [Docket No. AB 33 (Sub-No. 293X)] Union Pacific Railroad Company--Abandonment Exemption--In Wright County, IA Union Pacific Railroad Company (UP) filed a verified notice of exemption under 49 CFR 1152 subpart F--Exempt Abandonments to abandon a line...

  13. The global potential of bioenergy on abandoned agriculture lands.

    PubMed

    Campbell, J Elliott; Lobell, David B; Genova, Robert C; Field, Christopher B

    2008-08-01

    Converting forest lands into bioenergy agriculture could accelerate climate change by emitting carbon stored in forests, while converting food agriculture lands into bioenergy agriculture could threaten food security. Both problems are potentially avoided by using abandoned agriculture lands for bioenergy agriculture. Here we show the global potential for bioenergy on abandoned agriculture lands to be less than 8% of current primary energy demand, based on historical land use data, satellite-derived land cover data, and global ecosystem modeling. The estimated global area of abandoned agriculture is 385-472 million hectares, or 66-110% of the areas reported in previous preliminary assessments. The area-weighted mean production of above-ground biomass is 4.3 tons ha(-1) y(-1), in contrast to estimates of up to 10 tons ha(-1) y(-1) in previous assessments. The energy content of potential biomass grown on 100% of abandoned agriculture lands is less than 10% of primary energy demand for most nations in North America, Europe, and Asia, but it represents many times the energy demand in some African nations where grasslands are relatively productive and current energy demand is low.

  14. Characterization of coke, or carbonaceous matter, formed on CoMo catalysts used in hydrodesulfurization unit in oil refinery

    NASA Astrophysics Data System (ADS)

    Kimura, Nobuharu; Iwanami, Yoshimu; Koide, Ryutaro; Kudo, Reiko

    2017-06-01

    When a mixture of light gas oil (LGO) and light cycle oil is fed into an oil refinery’s hydrodesulfurization (HDS) unit to produce diesel fuel, the catalyst in the HDS unit is rapidly deactivated. By contrast, when the feed is LGO mixed with residue desulfurization gas oil, the catalyst is deactivated slowly. Hoping to understand why, the authors focused on the coke formed on the catalysts during the HDS reaction. The result of a comprehensive analysis of the coke suggested that the ways coke formed and grew on the catalysts may differ depending on the feeds used, which in turn could affect the deactivation behaviors of the catalysts.

  15. CENSUS AND STATISTICAL CHARACTERIZATION OF SOIL AND WATER QUALITY AT ABANDONED AND OTHER CENTRALIZED AND COMMERCIAL DRILLING-FLUID DISPOSAL SITES IN LOUISIANA, NEW MEXICO, OKLAHOMA, AND TEXAS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Alan R. Dutton; H. Seay Nance

    2003-06-01

    Commercial and centralized drilling-fluid disposal (CCDD) sites receive a portion of spent drilling fluids for disposal from oil and gas exploration and production (E&P) operations. Many older and some abandoned sites may have operated under less stringent regulations than are currently enforced. This study provides a census, compilation, and summary of information on active, inactive, and abandoned CCDD sites in Louisiana, New Mexico, Oklahoma, and Texas, intended as a basis for supporting State-funded assessment and remediation of abandoned sites. Closure of abandoned CCDD sites is within the jurisdiction of State regulatory agencies. Sources of data used in this study onmore » abandoned CCDD sites mainly are permit files at State regulatory agencies. Active and inactive sites were included because data on abandoned sites are sparse. Onsite reserve pits at individual wells for disposal of spent drilling fluid are not part of this study. Of 287 CCDD sites in the four States for which we compiled data, 34 had been abandoned whereas 54 were active and 199 were inactive as of January 2002. Most were disposal-pit facilities; five percent were land treatment facilities. A typical disposal-pit facility has fewer than 3 disposal pits or cells, which have a median size of approximately 2 acres each. Data from well-documented sites may be used to predict some conditions at abandoned sites; older abandoned sites might have outlier concentrations for some metal and organic constituents. Groundwater at a significant number of sites had an average chloride concentration that exceeded nonactionable secondary drinking water standard of 250 mg/L, or a total dissolved solids content of >10,000 mg/L, the limiting definition for underground sources of drinking water source, or both. Background data were lacking, however, so we did not determine whether these concentrations in groundwater reflected site operations. Site remediation has not been found necessary to date for most

  16. 75 FR 65047 - Union Pacific Railroad Company-Abandonment Exemption-in Pulaski County, AR

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-21

    ... DEPARTMENT OF TRANSPORTATION Surface Transportation Board [Docket No. AB 33 (Sub-No. 289X)] Union Pacific Railroad Company--Abandonment Exemption--in Pulaski County, AR Union Pacific Railroad Company (UP) filed a verified notice of exemption under 49 CFR part 1152 subpart F-Exempt Abandonments to abandon a 4...

  17. Control of occupational exposure to phenol in industrial wastewater treatment plant of a petroleum refinery in Alexandria, Egypt: An intervention application case study.

    PubMed

    Zaki, Gehan R; El-Marakby, Fadia A; Ramadan, Alaa El-Din K; Issa, Ahmed I; Nofal, Faten H

    2016-11-01

    Phenol exposure is one of the hazards in the industrial wastewater treatment basin of any refinery. It additively interacts with hydrogen sulfide emitted from the wastewater basin. Consequently, its concentration should be greatly lower than its threshold limit value. The present study aimed at controlling occupational exposure to phenol in the work environment of wastewater treatment plant in a refinery by reducing phenolic compounds in the industrial wastewater basin. This study was conducted on both laboratory and refinery scales. The first was completed by dividing each wastewater sample from the outlets of different refinery units into three portions; the first was analyzed for phenolic compounds. The second and third were for laboratory scale charcoal and bacterial treatments. The two methods were compared regarding their simplicities, design, and removal efficiencies. Accordingly, bacterial treatment by continuous flow of sewage water containing Pseudomonas Aeruginosa was used for refinery scale treatment. Laboratory scale treatment of phenolic compounds revealed higher removal efficiency of charcoal [100.0(0.0) %] than of bacteria [99.9(0.013) %]. The refinery scale bacterial treatment was [99.8(0.013) %] efficient. Consequently, level of phenol in the work environment after refinery-scale treatment [0.069(0.802) mg/m(3)] was much lower than that before [5.700(26.050) mg/m(3)], with removal efficiency of [99.125(2.335) %]. From the present study, we can conclude that bacterial treatment of phenolic compounds in industrial wastewater of the wastewater treatment plant using continuous flow of sewage water containing Pseudomonas Aeruginosa reduces the workers' exposure to phenol.

  18. Risk Factors For Abandonment of Wilms Tumor Therapy in Kenya

    PubMed Central

    Libes, Jaime; Oruko, Oliver; Abdallah, Fatmah; Githanga, Jessie; Ndung’u, James; Musimbi, Joyce; Njuguna, Festus; Patel, Kirtika; White, John; Axt, Jason R.; O’Neill, James A.; Shrubsole, Martha; Li, Ming; Lovvorn, Harold N.

    2014-01-01

    Background Survival from Wilms tumor (WT) in sub-Saharan Africa remains dismal as a result of on-therapy mortality and treatment abandonment. Review of patients diagnosed from 2008–2011 in our Kenyan Wilms Tumor Registry showed a loss to follow up (LTFU) rate approaching 50 percent. The purpose of this study was to trace those LTFU, estimate the survival rate, and identify risk factors for treatment abandonment. Procedure We administered a comprehensive survey to parents of patients with WT at the two largest referral hospitals in Kenya to identify barriers to care. We also telephoned families who had abandoned care to determine vital status and identify risk factors for treatment abandonment. Results Of 136 registered patients, 77 were confirmed dead (56.7%), 38 remained alive (27.9%), and the vital status of 21 patients remains unknown (15.4%). After contacting 33 of the patients who either abandoned curative treatment (n=34) or did not attend off-therapy visits (n=20), the best estimate of 2-year overall survival of patients with WT in Kenya approaches 36%. Sixty-three percent of parents misunderstood treatment plans and 55% encountered financial barriers. When asked how to increase comfort with the child’s treatment, 27% of parents volunteered improving inefficient services and 26% volunteered reducing drug-unavailability. Conclusions Treatment abandonment remains a significant problem contributing to increased mortality from WT in developing countries. This multi-center survey identified the barriers to treatment completion from the parental perspective to be lack of education about WT and treatment, financial constraints, need for quality improvement, and drug-unavailability. PMID:25382257

  19. Risk of large oil spills: a statistical analysis in the aftermath of Deepwater Horizon.

    PubMed

    Eckle, Petrissa; Burgherr, Peter; Michaux, Edouard

    2012-12-04

    The oil spill in the Gulf of Mexico that followed the explosion of the exploration platform Deepwater Horizon on 20 April 2010 was the largest accidental oil spill so far. In this paper we evaluate the risk of such very severe oil spills based on global historical data from our Energy-Related Severe Accident Database (ENSAD) and investigate if an accident of this size could have been "expected". We also compare the risk of oil spills from such accidents in exploration and production to accidental spills from other activities in the oil chain (tanker ship transport, pipelines, storage/refinery) and analyze the two components of risk, frequency and severity (quantity of oil spilled) separately. This detailed analysis reveals the differences in the structure of the risk between different spill sources, differences in trends over time and it allows in particular assessing the risk of very severe events such as the Deepwater Horizon spill. Such top down risk assessment can serve as an important input to decision making by complementing bottom up engineering risk assessment and can be combined with impact assessment in environmental risk analysis.

  20. Wind Power Potential at Abandoned Mines in Korea

    NASA Astrophysics Data System (ADS)

    jang, M.; Choi, Y.; Park, H.; Go, W.

    2013-12-01

    This study performed an assessment of wind power potential at abandoned mines in the Kangwon province by analyzing gross energy production, greenhouse gas emission reduction and economic effects estimated from a 600 kW wind turbine. Wind resources maps collected from the renewable energy data center in Korea Institute of Energy Research(KIER) were used to determine the average wind speed, temperature and atmospheric pressure at hub height(50 m) for each abandoned mine. RETScreen software developed by Natural Resources Canada(NRC) was utilized for the energy, emission and financial analyses of wind power systems. Based on the results from 5 representative mining sites, we could know that the average wind speed at hub height is the most critical factor for assessing the wind power potential. Finally, 47 abandoned mines that have the average wind speed faster than 6.5 m/s were analyzed, and top 10 mines were suggested as relatively favorable sites with high wind power potential in the Kangwon province.

  1. Petroleum mineral oil refining and evaluation of cancer hazard.

    PubMed

    Mackerer, Carl R; Griffis, Larry C; Grabowski, John S; Reitman, Fred A

    2003-11-01

    Petroleum base oils (petroleum mineral oils) are manufactured from crude oils by vacuum distillation to produce several distillates and a residual oil that are then further refined. Aromatics including alkylated polycyclic aromatic compounds (PAC) are undesirable constituents of base oils because they are deleterious to product performance and are potentially carcinogenic. In modern base oil refining, aromatics are reduced by solvent extraction, catalytic hydrotreating, or hydrocracking. Chronic exposure to poorly refined base oils has the potential to cause skin cancer. A chronic mouse dermal bioassay has been the standard test for estimating carcinogenic potential of mineral oils. The level of alkylated 3-7-ring PAC in raw streams from the vacuum tower must be greatly reduced to render the base oil noncarcinogenic. The processes that can reduce PAC levels are known, but the operating conditions for the processing units (e.g., temperature, pressure, catalyst type, residence time in the unit, unit engineering design, etc.) needed to achieve adequate PAC reduction are refinery specific. Chronic dermal bioassays provide information about whether conditions applied can make a noncarcinogenic oil, but cannot be used to monitor current production for quality control or for conducting research or developing new processes since this test takes at least 78 weeks to conduct. Three short-term, non-animal assays all involving extraction of oil with dimethylsulfoxide (DMSO) have been validated for predicting potential carcinogenic activity of petroleum base oils: a modified Ames assay of a DMSO extract, a gravimetric assay (IP 346) for wt. percent of oil extracted into DMSO, and a GC-FID assay measuring 3-7-ring PAC content in a DMSO extract of oil, expressed as percent of the oil. Extraction with DMSO concentrates PAC in a manner that mimics the extraction method used in the solvent refining of noncarcinogenic oils. The three assays are described, data demonstrating the

  2. Repeated use of an abandoned vehicle by nesting Turkey vultures (Cathartes aura)

    USGS Publications Warehouse

    Igl, L.D.; Peterson, S.L.

    2010-01-01

    Turkey Vultures (Cathartes aura) lay their eggs on an existing substrate in the dark recesses of a variety of natural sites (Kirk and Mossman 1998). Although an important requirement of Turkey Vulture nest-site selection is isolation from human disturbances (Kirk and Mossman 1998), their nests have been reported in abandoned buildings since at least the early 1800s (Nuttall 1832). Depopulation of rural areas in North America in recent decades has resulted in many abandoned buildings within the Turkey Vulture's breeding range (Peck 2003). Increased use of abandoned buildings by nesting Turkey Vultures has been implicated in the species' recent northward range expansion (Peck 2003, Nelson et al. 2005, Houston et al. 2007). Although abandoned or inoperative vehicles also are widespread in rural areas, we found no published literature documenting Turkey Vultures' use of these potential nest sites. Herein, we summarize the first documented incidence of a Turkey Vulture nesting in an abandoned vehicle.

  3. NPDES Permit for Thunder Butte Petroleum Services Inc. Refinery in North Dakota

    EPA Pesticide Factsheets

    Under NPDES permit ND-003098, the Thunder Butte Petroleum Services Inc. refinery is authorized to discharge from its wastewater treatment facilities near Makoti in Ward County, North Dakota, to wetlands tributary to the East Fork of Shell Creek.

  4. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned Mine...

  5. 78 FR 79726 - Norfolk Southern Railway Company-Abandonment Exemption-in Gaston County, NC

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-31

    ... DEPARTMENT OF TRANSPORTATION Surface Transportation Board [Docket No. AB 290 (Sub-No. 339X)] Norfolk Southern Railway Company--Abandonment Exemption--in Gaston County, NC Norfolk Southern Railway Company (NSR) has filed a verified notice of exemption under 49 CFR part 1152 subpart F-Exempt Abandonments to abandon approximately 0.5 miles of rail...

  6. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned Mine...

  7. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned Mine...

  8. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned Mine...

  9. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned Mine...

  10. A preliminary cost analysis of the biotreatment of refinery spent-sulfidic caustic.

    PubMed

    Sublette, K L

    1997-01-01

    Caustics are used in petroleum refining to remove hydrogen sulfide from various hydrocarbon streams. Spent-sulfidic caustics from three refineries have been successfully biotreated on the bench and pilot scale, resulting in neutralization and removal of active Sulfides. Sulfides were completely oxidized to sulfate by Thiobacillus denitrificans strain F. Microbial oxidation of sulfide produced acid, which at least partially neutralized the caustic. A commercial-scale treatment system has been designed that features a bioreactor with a suspended culture of flocculated T. denitrificans, a settler and acid and nutrient storage and delivery systems. A cost analysis has been performed for nine cases representing a range of spent caustic sulfide and hydroxide concentrations at a base treatment rate of 10 gpm. This analysis shows that refinery spent-sulfidic caustic can be biotreated for 4-8.3 cent/gal.

  11. Robust optimization on sustainable biodiesel supply chain produced from waste cooking oil under price uncertainty.

    PubMed

    Zhang, Yong; Jiang, Yunjian

    2017-02-01

    Waste cooking oil (WCO)-for-biodiesel conversion is regarded as the "waste-to-wealthy" industry. This paper addresses the design of a WCO-for-biodiesel supply chain at both strategic and tactical levels. The supply chain of this problem is studied, which is based on a typical mode of the waste collection (from restaurants' kitchen) and conversion in the cities. The supply chain comprises three stakeholders: WCO supplier, integrated bio-refinery and demand zone. Three key problems should be addressed for the optimal design of the supply chain: (1) the number, sizes and locations of bio-refinery; (2) the sites and amount of WCO collected; (3) the transportation plans of WCO and biodiesel. A robust mixed integer linear model with muti-objective (economic, environmental and social objectives) is proposed for these problems. Finally, a large-scale practical case study is adopted based on Suzhou, a city in the east of China, to verify the proposed models. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Hydrothermal Liquefaction Biocrude Compositions Compared to Petroleum Crude and Shale Oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jarvis, Jacqueline M.; Billing, Justin M.; Hallen, Richard T.

    We provide a direct and detailed comparison of the chemical composition of petroleum crude oil (from the Gulf of Mexico), shale oil, and three biocrudes (i.e., clean pine, microalgae Chlorella sp., and sewage sludge feedstocks) generated by hydrothermal liquefaction (HTL). Ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) reveals that HTL biocrudes are compositionally more similar to shale oil than petroleum crude oil and that only a few heteroatom classes (e.g., N1, N2, N1O1, and O1) are common to organic sediment- and biomass-derived oils. All HTL biocrudes contain a diverse range of oxygen-containing compounds when compared tomore » either petroleum crude or shale oil. Overall, petroleum crude and shale oil are compositionally dissimilar to HTL oils, and >85% of the elemental compositions identified within the positive-ion electrospray (ESI) mass spectra of the HTL biocrudes were not present in either the petroleum crude or shale oil (>43% for negative-ion ESI). Direct comparison of the heteroatom classes that are common to both organic sedimentand biomass-derived oils shows that HTL biocrudes generally contain species with both smaller core structures and a lower degree of alkylation relative to either the petroleum crude or the shale oil. Three-dimensional plots of carbon number versus molecular double bond equivalents (with observed abundance as the third dimension) for abundant molecular classes reveal the specific relationship of the composition of HTL biocrudes to petroleum and shale oils to inform the possible incorporation of these oils into refinery operations as a partial amendment to conventional petroleum feeds.« less

  13. Pt-based Bi-metallic Monolith Catalysts for Partial Upgrading of Microalgae Oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lawal, Adeniyi; Manganaro, James; Goodall, Brian

    Valicor’s proprietary wet extraction process in conjunction with thermochemical pre-treatment was performed on algal biomass from two different algae strains, Nannochloropsis Salina (N.S.) and Chlorella to produce algae oils. Polar lipids such as phospholipids were hydrolyzed, and metals and metalloids, known catalyst poisons, were separated into the aqueous phase, creating an attractive “pre-refined” oil for hydrodeoxygenation (HDO) upgrading by Stevens. Oil content and oil extraction efficiency of approximately 30 and 90% respectively were achieved. At Stevens, we formulated a Pt-based bi-metallic catalyst which was demonstrated to be effective in the hydro-treating of the algae oils to produce ‘green’ diesel. Themore » bi-metallic catalyst was wash-coated on a monolith, and in conjunction with a high throughput high pressure (pilot plant) reactor system, was used in hydrotreating algae oils from N.S. and Chlorella. Mixtures of these algae oils and refinery light atmospheric gas oil (LAGO) supplied by our petroleum refiner partner, Marathon Petroleum Corporation, were co-processed in the pilot plant reactor system using the Pt-based bi-metallic monolith catalyst. A 26 wt% N.S. algae oil/74 wt % LAGO mixture hydrotreated in the reactor system was subjected to the ASTM D975 Diesel Fuel Specification Test and it met all the important requirements, including a cetane index of 50.5. An elemental oxygen analysis performed by an independent and reputable lab reported an oxygen content of trace to none found. The successful co-processing of a mixture of algae oil and LAGO will enable integration of algae oil as a refinery feedstock which is one of the goals of DOE-BETO. We have presented experimental data that show that our precious metal-based catalysts consume less hydrogen than the conventional hydrotreating catalyst NiMo Precious metal catalysts favor the hydrodecarbonylation/hydrodecarboxylation route of HDO over the dehydration route preferred by base

  14. Risk factors and reasons for treatment abandonment among children with lymphoma in Malawi.

    PubMed

    Stanley, Christopher C; van der Gronde, Toon; Westmoreland, Kate D; Salima, Ande; Amuquandoh, Amy; Itimu, Salama; Manda, Agness; Mtete, Idah; Butia, Mercy; Mpasa, Atupele; Wachepa, Stella; Fox, Paula; Wasswa, Peter; Kazembe, Peter; El-Mallawany, Nader K; Gopal, Satish

    2018-03-01

    Lymphoma is the commonest pediatric cancer in sub-Saharan Africa (SSA). Frequent treatment abandonment contributes to suboptimal outcomes. We examined risk factors and reasons for treatment abandonment for this population in Malawi. We conducted a mixed methods study among children < 18 years old with newly diagnosed lymphoma, prospectively enrolled during 2013-2016. All children received standardized diagnosis and treatment, and were followed for up to 2 years. Treatment abandonment was defined as failure to attend prescribed chemotherapy within 4 weeks, or post-treatment visit within 3 months. Child, guardian, and household characteristics associated with treatment abandonment were assessed. Semi-structured interviews were conducted with primary caregivers of children experiencing treatment abandonment. Of 121 children with newly diagnosed lymphoma, 72 (60%) had complete information regarding child, guardian, and household characteristics. Of these, 56 (78%) had Burkitt's and 16 (22%) Hodgkin's lymphoma. Forty-nine (68%) were male, median age was 10.6 years (interquartile range [IQR] 7.9-13.0), and 26 (36%) experienced treatment abandonment. Lack of guardian education and travel time ≥ 4 h to clinic were independently associated with treatment abandonment, with adjusted hazard ratio (aHR) 3.8 [95% confidence interval (CI) 1.5-8.9, p = 0.005] and aHR 2.9 (95% CI 1.2-6.9, p = 0.019), respectively. Commonest reasons for treatment abandonment endorsed by 15 guardians were community influence, suboptimal clinic environment, logistical challenges, transport costs, treatment toxicities, loss of hope, alternative healers, and beliefs about cure. These findings highlight families at risk for treatment abandonment, underlying reasons, and opportunities to improve retention in care for pediatric cancer patients in SSA.

  15. Development of a plume-in-grid model for industrial point and volume sources: application to power plant and refinery sources in the Paris region

    NASA Astrophysics Data System (ADS)

    Kim, Y.; Seigneur, C.; Duclaux, O.

    2014-04-01

    Plume-in-grid (PinG) models incorporating a host Eulerian model and a subgrid-scale model (usually a Gaussian plume or puff model) have been used for the simulations of stack emissions (e.g., fossil fuel-fired power plants and cement plants) for gaseous and particulate species such as nitrogen oxides (NOx), sulfur dioxide (SO2), particulate matter (PM) and mercury (Hg). Here, we describe the extension of a PinG model to study the impact of an oil refinery where volatile organic compound (VOC) emissions can be important. The model is based on a reactive PinG model for ozone (O3), which incorporates a three-dimensional (3-D) Eulerian model and a Gaussian puff model. The model is extended to treat PM, with treatments of aerosol chemistry, particle size distribution, and the formation of secondary aerosols, which are consistent in both the 3-D Eulerian host model and the Gaussian puff model. Furthermore, the PinG model is extended to include the treatment of volume sources to simulate fugitive VOC emissions. The new PinG model is evaluated over Greater Paris during July 2009. Model performance is satisfactory for O3, PM2.5 and most PM2.5 components. Two industrial sources, a coal-fired power plant and an oil refinery, are simulated with the PinG model. The characteristics of the sources (stack height and diameter, exhaust temperature and velocity) govern the surface concentrations of primary pollutants (NOx, SO2 and VOC). O3 concentrations are impacted differently near the power plant than near the refinery, because of the presence of VOC emissions at the latter. The formation of sulfate is influenced by both the dispersion of SO2 and the oxidant concentration; however, the former tends to dominate in the simulations presented here. The impact of PinG modeling on the formation of secondary organic aerosol (SOA) is small and results mostly from the effect of different oxidant concentrations on biogenic SOA formation. The investigation of the criteria for injecting

  16. Development of a plume-in-grid model for industrial point and volume sources: application to power plant and refinery sources in the Paris region

    NASA Astrophysics Data System (ADS)

    Kim, Y.; Seigneur, C.; Duclaux, O.

    2013-11-01

    Plume-in-grid (PinG) models incorporating a host Eulerian model and a subgrid-scale model (usually a Gaussian plume or puff model) have been used for the simulations of stack emissions (e.g., fossil fuel-fired power plants and cement plants) for gaseous and particulate species such as nitrogen oxides (NOx), sulfur dioxide (SO2), particulate matter (PM) and mercury (Hg). Here, we describe the extension of a PinG model to study the impact of an oil refinery where volatile organic compound (VOC) emissions can be important. The model is based on a reactive PinG model for ozone (O3), which incorporates a three-dimensional (3-D) Eulerian model and a Gaussian puff model. The model is extended to treat PM, with treatments of aerosol chemistry, particle size distribution, and the formation of secondary aerosols, which are consistent in both the 3-D Eulerian host model and the Gaussian puff model. Furthermore, the PinG model is extended to include the treatment of volume sources to simulate fugitive VOC emissions. The new PinG model is evaluated over Greater Paris during July 2009. Model performance is satisfactory for O3, PM2.5 and most PM2.5 components. Two industrial sources, a coal-fired power plant and an oil refinery, are simulated with the PinG model. The characteristics of the sources (stack height and diameter, exhaust temperature and velocity) govern the surface concentrations of primary pollutants (NOx, SO2 and VOC). O3 concentrations are impacted differently near the power plant than near the refinery, because of the presence of VOC emissions at the latter. The formation of sulfate is influenced by both the dispersion of SO2 and the oxidant concentration; however, the former tends to dominate in the simulations presented here. The impact of PinG modeling on the formation of secondary organic aerosols (SOA) is small and results mostly from the effect of different oxidant concentrations on biogenic SOA formation. The investigation of the criteria for injecting

  17. Records of wells drilled for oil and gas in Montana, June 1, 1951 through December 31, 1953

    USGS Publications Warehouse

    Smith, Howard R.

    1955-01-01

    usage. In the column 'Production or shows of oil and gas' the symbol GS is used for gas shows, OS for oil shows, GOS for shows of both gas and oil, GP for gas production, and OP for oil production. A number following the symbol for a show or production indicates the depth to the top of the zone in which the gas or oil was found. The letter symbol following the number or the hyphen indicates the geologic formation in which the gas or oil occurs. The status and depth of each well is indicated. The letters A, C, and D preceding the date indicate abandoned, completed, or drilling, respectively, in the specified year. Most if not all producing wells that have been abandoned are shown as completed wells. The date of abandonment is the year in which drilling ceased, except for a few wells in which the abandonment was preceded by one or more years of suspended operations. The diagrammatic representation of the succession of geologic formations in Montana (fig. 1) provides identification of the letter symbols used in the tabulation to indicate geologic formations.

  18. Updated epidemiological study of workers at two California petroleum refineries, 1950–95

    PubMed Central

    Satin, K; Bailey, W; Newton, K; Ross, A; Wong, O

    2002-01-01

    Objectives: To further assess the potential role of occupational exposures on mortality, a second update of a cohort study of workers at two petroleum refineries in California was undertaken. Methods: Mortality analyses were based on standardised mortality ratios (SMRs) and 95% confidence intervals (95% CIs) using the general population of California as a reference. Additional analyses of lymphatic and haematopoietic cancer deaths and diseases related to asbestos were undertaken. Results: The update consisted of 18 512 employees, who contributed 456 425 person-years of observation between 1950 and 1995. Both overall mortality and total cancer mortality were significantly lower than expected, as were several site specific cancers and non-malignant diseases. In particular, no significant increases were reported for leukaemia cell types or non-Hodgkin's lymphoma. Mortality excess from multiple myeloma was marginally significant. The excess was confined to employees enrolled before 1949. Furthermore, there was no significant upward trend based on duration of employment, which argues against a causal interpretation relative to employment or exposures at the refineries. No increase was found for diseases related to asbestos: pulmonary fibrosis; lung cancer; or malignant mesothelioma. There was no significant increase in mortality from any other cancers or non-malignant diseases. Conclusion: This second update provides additional reassurance that employment at these two refineries is not associated with increased risk of mortality. PMID:11934952

  19. Biostimulation of Indigenous Microbial Community for Bioremediation of Petroleum Refinery Sludge

    PubMed Central

    Sarkar, Jayeeta; Kazy, Sufia K.; Gupta, Abhishek; Dutta, Avishek; Mohapatra, Balaram; Roy, Ajoy; Bera, Paramita; Mitra, Adinpunya; Sar, Pinaki

    2016-01-01

    Nutrient deficiency severely impairs the catabolic activity of indigenous microorganisms in hydrocarbon rich environments (HREs) and limits the rate of intrinsic bioremediation. The present study aimed to characterize the microbial community in refinery waste and evaluate the scope for biostimulation based in situ bioremediation. Samples recovered from the wastewater lagoon of Guwahati refinery revealed a hydrocarbon enriched [high total petroleum hydrocarbon (TPH)], oxygen-, moisture-limited, reducing environment. Intrinsic biodegradation ability of the indigenous microorganisms was enhanced significantly (>80% reduction in TPH by 90 days) with nitrate amendment. Preferred utilization of both higher- (>C30) and middle- chain (C20-30) length hydrocarbons were evident from GC-MS analysis. Denaturing gradient gel electrophoresis and community level physiological profiling analyses indicated distinct shift in community’s composition and metabolic abilities following nitrogen (N) amendment. High throughput deep sequencing of 16S rRNA gene showed that the native community was mainly composed of hydrocarbon degrading, syntrophic, methanogenic, nitrate/iron/sulfur reducing facultative anaerobic bacteria and archaebacteria, affiliated to γ- and δ-Proteobacteria and Euryarchaeota respectively. Genes for aerobic and anaerobic alkane metabolism (alkB and bssA), methanogenesis (mcrA), denitrification (nirS and narG) and N2 fixation (nifH) were detected. Concomitant to hydrocarbon degradation, lowering of dissolve O2 and increase in oxidation-reduction potential (ORP) marked with an enrichment of N2 fixing, nitrate reducing aerobic/facultative anaerobic members [e.g., Azovibrio, Pseudoxanthomonas and Comamonadaceae members] was evident in N amended microcosm. This study highlighted that indigenous community of refinery sludge was intrinsically diverse, yet appreciable rate of in situ bioremediation could be achieved by supplying adequate N sources. PMID:27708623

  20. Washington's energy mess: after ten years of Federal meddling in the oil business, we're over a barrel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sawyer, J.

    1980-09-01

    New regulations in response to a 1970 call for decontrolling the petroleum industry encouraged foreign production and imports while discouraging domestic exploration. The oil industry was strong enough to profit from government programs, but not enough to prevent pervasive interference in its operations and investments. The result has been supply disruptions and more dependence on foreign oil. The price control system operating during the 1970s had no provision for inflation and was biased toward refineries having access to domestic crude oil. This led to an entitlements program that modified competition further. A review of these and other programs, such asmore » the mandatory crude-oil buy/sell program, shows how they altered the relationships between suppliers and buyers. The 1980 Windfall Profit Tax continues a decade of favoring foreign production, reflecting public aversion to true decontrol, and a public addiction to Federal intervention. (DCK)« less