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1
Combined thermodynamic and rare earth element modelling of garnet growth during subduction: Examples from ultrahigh-pressure eclogite of the Western Gneiss

involved the ZAF algorithm. Trace element contents were measured with the laser ablation ICP MS system-ICP-MS quality controls in eclogitic assemblages see Zack et al., 2002. Note that REEs lighter than Eu were discussions about the topic of this work. Matthias Barth is thanked for help at the ...

E-print Network

2
NASA Technical Reports Server

... with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) , allowing a combination of high sensitivity and good spatial resolution. ...

NASA Website

3
Abstract - NASA

Jun 20, 2008... several basaltic lunar samples using a combination of solution and laser ablation inductively coupled plasma mass spectrometry (ICP-MS). ...

NASA Website

4
7 - NASA Technical Reports Server

Mar 1, 2011... and 2) analysis of run products with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), allowing a combination of ...

NASA Website

5
Lithium elemental and isotopic disequilibrium in minerals from peridotite xenoliths from far-east Russia

concentrations obtained by laser-ablation inductively coupled mass-spectrometry (LA-ICP-MS) in olivine concentrations were measured in situ by laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS measured by the sample- standard bracketing method using a Nu Plasma multi- collector ...

E-print Network

6
doi:10.1016/j.gca.2003.11.007 Formation of metal in the CH chondrites ALH 85085 and PCA 91467

) 91467 and ALH 85085 by laser ablation ICP-MS (LA-ICP-MS). Arguments for or against the origins-subtracted and then corrected for the instrumental sensitivity factors. Laser ablation ICP-MS requires an internal calibrant) silicate veins in them. 3.2. LA-ICP-MS Analyses of ...

E-print Network

7
Rutile crystals as potential trace element and isotope mineral standards for microanalysis

(centimeter size) rutile grains. Methods employed are SIMS, EMP, LA-ICP-MS, ID-MC-ICP-MS and TIMS. For most ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), secondary ion mass spectrometry (SIMS�rho�z and PAP, Pouchou and Pichoir, 1984; Heinrich and Newbury, 1991), both ...

E-print Network

8
Small-Volume U-Pb Zircon Geochronology by Laser Ablation ...
2008-11-03

Page 1. Small-volume U�Pb zircon geochronology by laser ablation- multicollector-ICP-MS ... Keywords: U�Pb geochronology Zircon LA-ICP-MS ...

DTIC Science & Technology

9
Title: The validation of Cryogenic Laser Ablation ICP-MS (CLA-ICP-MS) methods by comparison to laser ablation (LA)-ICP-MS and solution based ICP-MS methods, for the analysis of metals in biological tissues
2009-12-01

ICP-MS and laser ablation ICP-MS (LA-ICP-MS) are well established techniques for the analysis of metals in geological and environmental samples. LA-ICP-MS is commonly used in geological applications to determine the spatial distribution of metal concentrations at small sampling intervals (as ...

NASA Astrophysics Data System (ADS)

10
Inter-element fractionation and correction in laser ablation inductively coupled plasma mass spectrometry

-element fractionation in laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis is one is close to 1. Since laser ablation inductively coupled plasma mass spectro- metry (LA-ICP-MS) was �rst) are commonly used as an internal standard for in situ multi-element ...

E-print Network

11
A Compilation of New and Published Major and Trace Element Data for NIST SRM 610

(such as ion probe or laser ablation ICP-MS) are hampered by a lack of well characterized, homogeneous micro-analyses d'�l�ments en trace (par sonde ionique ou ICP-MS avec ablation laser) sont g�n�es par l during laser ablation inductively coupled plasma-mass spectrometry ...

E-print Network

12
GEOSTANDARDS NEWSLETTER

-Pb Laser Ablation ICP-MS Zircon Dating using Matrix-Matched Calibration Samples with a Frequency Quadrupled of laser ablation (LA) ICP-MS to the in situ analysis of 207Pb/206Pb and 206Pb/238U isotopic ratios analyses, LA-ICP-MS results on reference materials (UQ-Z1 and G91500) indicated ...

E-print Network

13
Abstract This paper describes the automated in situ trace element analysis of solid materials by laser ablation (LA)

by laser ablation (LA) inductively coupled plasma mass spectrometry (ICP-MS). A compact computer-MS and the LA via serial RS-232 port. Each LA-ICP-MS analysis at a defined point includes a 60 s pre solution auto-sampler ICP-MS analysis. Each analytical cycle consists of four standards, one control

E-print Network

14
5. TL RESULTS 5.1 Introduction

of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to investigate the chemical or exposure to sunlight. 5.2.1 LA-ICP-MS The concentrations of many trace elements in the zircon samples were determined by single-grain analyses using laser ablation inductively coupled plasma mass spectrometry ...

E-print Network

15
Inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation ICP-MS for isotope analysis of long-lived radionuclides
2005-04-01

For a few years now inductively coupled plasma mass spectrometry has been increasingly used for precise and accurate determination of isotope ratios of long-lived radionuclides at the trace and ultratrace level due to its excellent sensitivity, good precision and accuracy. At present, ICP-MS and also laser ablation ICP-MS are applied ...

NASA Astrophysics Data System (ADS)

16
Vesicular Mare Basalt - NASA

technique: (a) XRF, (b) INAA, (c ) ICP-MS. References for 15529 ... L.A. (2008) A laser-ablation ICP-MS study of Apollo 15 low-titanium olivine-normative ...

NASA Website

17
NAI: Year 4 Annual Report

Do paleosols constrain the CO2 level of the Archean atmosphere? ..... A combined laser ablation-resonance ionization mass spectrometer for ...... Pseudocraters on Mars: A consequence of lava-ground ice interaction. ...... High precision iron isotope measurements of meteoritical material by cold plasma ICP-MS. ...

NASA Website

18
Characterization of nuclear fuels by ICP mass-spectrometric techniques.
2007-10-09

Isotopic analyses of radioactive materials such as irradiated nuclear fuel are of major importance for the optimization of the nuclear fuel cycle and for safeguard aspects. Among the mass-spectrometric techniques available, inductively coupled plasma mass spectrometry (ICP-MS) and thermal ionization mass spectrometry are the most frequently applied methods for nuclear ...

PubMed

19
Laserinduzierte Elementmuster zur Zertifizierung der Fundorte

: Details zu den Eigenschaften von Mineralen � Kasten 2: Optimierung der LA-ICP-MS-Methode � Kasten 3: Edle ICP MS) gelang es, die Elementzusammensetzung von Edelsteinen aus f�nf Sch�rfminen eindeutig und" ("zerst�rende") Analysenmethoden ausgewichen und schliesslich auf die LA-ICP-MS (Laser ...

E-print Network

20
Ancestral Polynesian Pottery Production and Exchange Analysis Using LA-ICP-MS
2009-06-09

This thesis examines the production and distribution of ancestral Polynesian pottery on Tutuila Island, American Samoa and evaluates the extent of intra-island interactions. Currently, very little is known about ceramic production and exchange in Samoa. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is used to source clay and ...

E-print Network

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21
GCA Educational Activities - NASA

LA-ICP-MS, The Laser-Ablation Inductively Coupled Mass Spectrometer Lab was part of the Maryland Geology tour. Drs. Jason Dworkin and Joeseph Nuth, July 8, ...

NASA Website

22
AMN SEPT08

laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), focused ion beam extractions (FIB), secondary ion mass spectrometry or ion ...

NASA Website

23
A Henry's Law Test for Experimental Partitioning Studies of Iron Meteorites
2001-01-01

Low-level doped solid metal/liquid metal experiments analyzed by laser ablation ICP-MS allow Henry's

NASA Technical Reports Server (NTRS)

24
Matrix Independent Standardization by LA-ICP-MS
2008-12-01

LA-ICP-MS analysis combines laser ablation with inductively coupled plasma mass spectrometry for the rapid chemical analyses of solid samples at spatial resolution better than 100 ?m. Standardization in LA-ICP- MS involves both internal and external calibration, and is limited by the small ...

NASA Astrophysics Data System (ADS)

25
Inductively Coupled Plasma: Fundamental Particle Investigations with Laser Ablation and Applications in Magnetic Sector Mass Spectrometry, (Thesis/Dissertation).
2008-01-01

Particle size effects and elemental fractionation in laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) are investigated with nanosecond and femtosecond laser ablation, differential mobility analysis, and magnetic sector ICP-MS. Laser...

National Technical Information Service (NTIS)

26
Application of nanosecond-UV laser ablation - Inductively Coupled Plasma - Mass Spectrometry for the isotopic analysis of single sub-micrometer-size uranium particles.
2011-08-29

For the first time, laser ablation - Inductively Coupled Plasma - Mass Spectrometry (LA-ICP-MS) was used to carry out isotopic measurement on single sub-micrometer-size uranium particles. The analytical procedure was applied on two particle-containing samples already analyzed in the same laboratory by established techniques for particle analysis: ...

PubMed

27
Recovery of temperature records from slow-growing corals by fine scale sampling of skeletons

. [1] We used laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) to analyze Sr laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) to analyze Sr/Ca ratios along of 6 #12;0.3-mm alumina suspension. Tissue was not removed. We assayed Sr/Ca ratios using LA ...

E-print Network

28
Nordisk kernesikkerhedsforskning Norr�nar kjarn�ryggisranns�knir

-MS. It also includes a short training course consisting of five exercises. Key words ICP-MS, Mass spectrometry and introduction technique which makes the use of ICP- MS a rather complicated issue when it comes to optimizing spectrometers are frequently used for the high-resolution ICP-MS instruments. This is ...

E-print Network

29
Imaging of metals, metalloids, and non-metals by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) in biological tissues.
2010-01-01

The determination of the localization and distribution of essential and beneficial metals (e.g., Cu, Fe, Zn, Mn, Co, Ti, Al, Ca, K, Na, Cr and others), toxic metals (like Cd, Pb, Hg, U), metalloids (e.g., As, Se, Sb), and non-metals (such as C, S, P, Cl, I) in biological tissues is a challenging task for life science studies. Over the past few years, the development and application of mass ...

PubMed

30
Inductively coupled plasma mass spectrometry with a twin quadrupole instrument using laser ablation sample introduction and monodisperse dried microparticulate injection.
1997-01-01

The focus of this dissertation is the use of a twin quadrupole inductively coupled plasma mass spectrometer (ICP-MS) for the simultaneous detection of two m/z values. The twin quadrupole ICP-MS is used with laser ablation sample introduction in both the s...

National Technical Information Service (NTIS)

31
FINAL REPORT. PARTICLE GENERATION BY LASER ABLATION IN SUPPORT OF CHEMICAL ANALYSIS OF HIGH LEVEL MIXED WASTE FROM PLUTONIUM PRODUCTION OPERATIONS

We investigate particles produced by laser irradiation and their analysis by Laser Ablation Inductively Coupled Plasma Mass Spectroscopy (LA/ICP-MS), with a view towards optimizing particle production for analysis of high level waste materials and waste glass. LA/ICP-MS has consi...

EPA Science Inventory

32
Imaging mass spectrometry in biological tissues by laser ablation inductively coupled plasma mass spectrometry.
2007-01-01

Of all the inorganic mass spectrometric techniques, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) plays a key role as a powerful and sensitive microanalytical technique enabling multi- element trace analysis and isotope ratio measurements at trace and ultratrace level. LA-ICP-MS was used to produce images of ...

PubMed

33
Cooling and Denudation History of the Rokko Area, Southwest Japan, Based on Fission-track Thermochronology

rate, Rokko area, LA- ICP-MSlaser ablation inductively coupled plasma mass spectrometry LA-ICP-MS with a Microlas Excimer laser abla- tion system; Ishida et al., 2004; Morishita et al., 2005 LA-ICP- MS 2 , 2007; Hasebe et al., 2009 FT LA-ICP-MS 43 Ca 29 Si 238 U NIST 610Pearce et al., 1997 ...

E-print Network

34
Biogeosciences, 4, 195�203, 2007 www.biogeosciences.net/4/195/2007/

- erful High Resolution ICP-MS, the spatial resolution could be improved down to 5 to 10 �m crater size- files performed by laser ablation ICP-MS from five arago- nitic shells of Pleiodon (Cameronia) spekii-mass spectrometer (LA-ICP-MS, PQ2+, laser 266 nm; operating conditions in Lazareth et al., 2003). Data were

E-print Network

35
Abstract Trace-element signatures in otolith-growth bands provide a powerful tool for fish biologists to track

-coupled-plasma mass spectrometer (ICP-MS) for analysis of trace elements in biogenic carbonates, such as corals-ablation sector-field inductively-coupled- plasma mass spectrometry (SF-ICP-MS) Cynthia M. Jones1 and Zhongxing Norfolk, Virginia 23529, USA Key words: ICP-MS, otolith, trace-elements, preservation The ...

E-print Network

36
Shipley, T.H., Ogawa, Y., Blum, P., and Bahr, J.M. (Eds.), 1997 Proceedings of the Ocean Drilling Program, Scientific Results, Vol. 156

were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS; VG Plasma Quad2+), which ICP-MS Titrn ICP-MS IC AES ICP-MS AAS ICP-MS ICP-MS ICP-MS ICP-MS ICP-MS ICP-MS ...

E-print Network

37
UV and IR laser ablation for inductively coupled plasma mass spectrometry.
1993-01-01

Laser ablation particle plume compositions are characterized using inductively coupled plasma mass spectrometry (ICP/MS). This study evaluates the mass response characteristics peculiar to ICP/MS detection as a function of laser fluence and frequency. Eva...

National Technical Information Service (NTIS)

38
Small-Volume U-Pb Zircon Geochronology by Laser Ablation ...
2008-11-03

... Accession Number : ADA515753. Title : Small-Volume U-Pb Zircon Geochronology by Laser Ablation-Multicollector-ICP-MS. ...

DTIC Science & Technology

39
Spatial inhomogeneity of metals in particulate matter on ambient air filters determined by LA-ICP-MS and comparison with acid digestion ICP-MS.
2009-08-28

Laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) has been used to examine the spatial distribution of metals in particulate matter on ambient air filters. The implications of the inhomogeneous distribution observed for the sub-sampling of such filters for multiple analyses have been discussed. It has been shown that large biases in ...

PubMed

40
Solid sampling with 193-nm excimer laser ablation
2007-03-01

Reproducible and sensitive elemental analysis of solid samples is a crucial task in areas of geology (e.g. microanalysis of fluid inclusions), material sciences, industrial quality control as well as in environmental, forensic and biological studies. To date the most versatile detection method is mass-spectroscopic multi-element analysis. In order to obtain reproducible results, this requires ...

NASA Astrophysics Data System (ADS)

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41
Quantitative solid sample analysis by ArF excimer laser ablation
2005-06-01

Reproducible and sensitive elemental analysis of solid samples is a crucial task in areas of geology (e.g. microanalysis of fluid inclusions), material sciences, industrial quality control as well as in environmental, forensic and biological studies. To date the most versatile detection method is mass-spectroscopic multi-element analysis. In order to obtain reproducible results, this requires ...

NASA Astrophysics Data System (ADS)

42
Zirconium and hafnium in meteorites
2010-07-01

The ratio of the two refractory trace elements zirconium (Zr) and hafnium (Hf) in meteorites has been proposed to be uniform. The most precise value available is 34.3+/-0.2 (1?). It was obtained by isotope dilution ICP-MS applied to 15 chondrites, most of which were carbonaceous chondrites, and six achondrites. We reinvestigated the case and determined Zr/Hf ratios of a broad ...

NASA Astrophysics Data System (ADS)

43
USING LASER ABLATION-INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY (LA-ICP-MS) TO EXPLORE GEOCHEMICAL TAPHONOMY OF ...

... spectrometry (LA-ICP-MS) was used to determine rare earth element (REE) content of 76 fossil bones collected ... have documented the uptake of the lanthanide series rare earth elements (REE) in vertebrate...

NBII National Biological Information Infrastructure

44
Quantitative multi-element mapping of ancient glass using a simple and robust LA-ICP-MS rastering procedure in combination with image analysis.
2011-06-03

The surface of two glass artefacts in mosaic style, probably fragments of conglomerate glass bowls dating back two millennia, was investigated by laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS). By rastering with the laser beam over a selected area of the surface of the glass artefacts, elemental oxide maps were generated. ...

PubMed

45
As-Deposited Thin-Film Battery Cathode Layers

determined using a combination RBS, ICP-MS,. EELS, and PIGE. The electrochemical performance of the layers (both in liquid ...

NASA Website

46
Bioimaging of metals in brain tissue by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and metallomics.
2009-10-28

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been developed and established as an emerging technique in the generation of quantitative images of metal distributions in thin tissue sections of brain samples (such as human, rat and mouse brain), with applications in research related to neurodegenerative disorders. A new ...

PubMed

47
Tubular textures in pillow lavas from a Caledonian west Norwegian ophiolite: A combined TEM, LA�ICP�MS, and STXM study
2011-02-01

Tubular alteration textures, mineralized by titanite, in glassy rims of pillow lavas from a Norwegian ophiolite (Solund-Stavfjord ophiolite complex (SSOC)) are described and characterized by a multimethod approach. Tubular alteration textures, mineralized by titanite, have been previously proposed to result from bioalteration. The microstructure of the titanite and the tubes is investigated using ...

NASA Astrophysics Data System (ADS)

48
Subscriber access provided by Missouri S&T Library Energy & Fuels is published by the American Chemical Society. 1155 Sixteenth

-AES),26 and ICP-mass spectro- metry (ICP-MS).22,27 The combination of HPLC with ICP-MS has high and acidified with 1% HNO3 before analysis using ICP-MS for total As and Se concentrations. The pH was measured. The filtered samples were then transferred to polypropylene tubes and sealed for speciation analysis using ...

E-print Network

49
Chemical taggant detection and analysis by laser-induced breakdown spectroscopy
2008-11-01

A commercially available chemical identification taggant that imparts a unique elemental fingerprint to any object and can be analytically distinguished from billions of possible combinations has been developed. The liquid tag is easily applied and, once dry, can be removed and analyzed by laser ablation inductively coupled plasma mass spectrometry ...

Energy Citations Database

50
Absolute quantification of human serum transferrin by species-specific isotope dilution laser ablation ICP-MS.
2011-06-08

We report for the first time the absolute quantification of a metalloprotein separated by nondenaturing gel electrophoresis (GE) using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) in combination with species-specific isotope dilution mass spectrometry (IDMS). The proposed method is based on the use of an ...

PubMed

51
RECONSTRUCTING PALEOCATCHMENTS BY INTEGRATING STABLE ISOTOPE RECORDS, SEDIMENTOLOGY, AND TAPHONOMY: A LATE CRETACEOUS ...

... Thole, J.T., and Williams, J., 2010, Using laser ablation-inductively couple plasma-mass spectrometry (LA-ICP-MS) to explore geochemical ... ...

NBII National Biological Information Infrastructure

52
Investigation of Orthopyroxene Diversity in Howardite Meteorites
2011-03-01

Integration of laser ablation ICP-MS analysis of eight howardite samples with XRF data, EMPA data points, noble gas abundance results, and petrographic descriptions provides some preliminary interpretations of regolithic classification.

NASA Astrophysics Data System (ADS)

53
Geochemical and Sulfur-Isotopic Signatures of Volcanogenic Massive...
2011-08-13

age. This study presents geochemical data on sulfide-rich samples, in situ laser-ablation inductively coupled plasma mass spectrometry (LA�ICP�MS) of sulfide minerals, and...

Science.gov Websites

54
COMPLEMENTARY MOLECULAR AND ELEMENTAL DETECTION OF SPECIATED THIOARSENICALS USING ESI-MS IN COMBINATION WITH A XENON-BASED COLLISION-CELL ICP-MS WITH APPLICATION TO FORTIFIED NIST FREEZE-DRIED URINE

The simultaneous detection of arsenic and sulfur in thio-arsenicals was achieved using xenonbased collision cell ICP-MS in combination with HPLC. In an attempt to minimize the 16O16O+ interference at m/z 32, both sample introduction and collision cell experimental parameters were...

EPA Science Inventory

55
Isotopic dating of accessory minerals by laser ablation ICP-MS: a mature technique?
2006-05-01

Laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) is a newly established technique that is capable of in-situ U(Th)-Pb dating of accessory minerals in a wide range of rock types and geological environments. LA ICP-MS emerged in 1985 and rapidly became an important analytical tool for trace element determinations ...

NASA Astrophysics Data System (ADS)

56
Simultaneous determination of trace metals in Saudi Arabian crude oil products by inductively coupled plasma mass spectroscopy (ICP/MS)
1988-08-01

The inductively coupled plasma in combination with a mass spectrometer (ICP/MS) has been used for the determination of metals in different Saudi Arabian crude oils (Arab Berri, Arab heavy, Arab medium and Arab light). A previously investigated extraction method has been applied in the determination of metals in oil to the sub ppm level.

Energy Citations Database

57
Representative sampling using single-pulse laser ablation withinductively coupled plasma mass spectroscopy
2001-04-02

Single pulse laser ablation sampling with inductively coupled plasma mass spectrometry (ICP-MS) was assessed for accurate chemical analysis. Elemental fractionation (e.g. Pb/U), the quantity of ablated mass (crater volume), ICP-MS intensity and the particle contribution (spike signal) during single pulse ...

Energy Citations Database

58
Association of glass fragments by their trace elemental content using ICP-MS and LA-ICP-MS in the analysis scheme
2002-08-01

The importance of glass as evidence of association between a crime event and a suspect has been recognized for some time. Glass is a fragile material that is often found at the scenes of crimes such as burglaries, hit-and-run accidents and violent crime offenses. The physical and chemical properties of glass can be used to differentiate between possible sources and as evidence of association ...

NASA Astrophysics Data System (ADS)

59
Matrix-Independent Calibration of Laser Ablation Microanalysis by High Resolution ICP- MS
2008-05-01

The combination of laser ablation and inductively coupled plasma mass spectrometry (LA-ICPMS) allows for rapid chemical analysis of solid samples at high spatial resolution. Calibration of the technique is limited by the small number of reliable standards available and by the diversity of solid matrices, including silicates, oxides, sulfides, carbonates, ...

NASA Astrophysics Data System (ADS)

60
EMSP Annual Report, June 15, 1999. Improved Analytical Characterization of Solid Waste-Forms by Fundamental Development of Laser Ablation Technology.
1999-01-01

Laser ablation (LA) with inductively coupled plasma mass spectrometry (ICP-MS) has been demonstrated as a viable technology for sample characterization within the EM complex. Laser ablation systems have been set up at the Hanford Site, Savannah River Plan...

National Technical Information Service (NTIS)

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61
Mapping of titanium particles in peri-implant oral mucosa by Laser Ablation Inductively Coupled Plasma Mass Spectrometry and high-resolution optical darkfield microscopy.
2010-10-24

The present study examines the quantity, size, element signatures and distribution of titanium particles in normal oral mucosal tissue and in oral mucosa exposed to a titanium implant. Tissue samples from six healthy patients were obtained by a full thickness biopsy taken from the edge of the oral mucosa when inserting a titanium dental implant. At the abutment insertion 6 months later, a punch ...

PubMed

62
Combined application of a laser ablation-ICP-MS assay for screening and ESI-FTICR-MS for identification of a Cd-binding protein in Spinacia oleracea L. after exposure to Cd.
2011-08-17

We have studied the binding of the toxic element Cd to plant proteins and have used for this purpose spinach (Spinacia oleracea L.) plants treated with 50 ?M Cd(ii) as a model system. Laser ablation ICP-MS has been applied for the screening of Cd-binding proteins after separation by native anodal polyacrylamide gel electrophoresis (AN-PAGE) and ...

PubMed

63
A rapid isotope ratio analysis protocol for nuclear solid materials using nano-second laser-ablation time-of-flight ICP-MS.
2009-08-27

The analysis of the isotopic composition of nuclear or non-nuclear solid materials is performed in a variety of fields, e.g., for quality assurance in the production of nuclear fuels, as signatures in forensics, nuclear safeguards, and non-proliferation control, in material characterization, geology, and archeology. We have investigated the capability of laser ablation (New ...

PubMed

64
A new approach for calibration of laser ablation inductively coupled plasma mass spectrometry using thin layers of spiked agarose gels as references.
2010-11-24

Calibration of analytical methods using laser ablation for sample introduction is often problematic. The availability of matrix-adapted standard materials is a crucial factor in the analysis of biological samples in particular. In this work a method for preparation of thin-film references for LA-ICP-MS is presented which is inexpensive, relatively simple and generally ...

PubMed

65
Laser ablation ICP-MS profiling and semiquantitative determination of trace element concentrations in desert tortoise shells: documenting the uptake of elemental toxicants.
2005-03-01

The outer keratin layer (scute) of desert tortoise shells consists of incrementally grown laminae in which various bioaccumulated trace elements are sequestered during scute deposition. Laser ablation ICP-MS examination of laminae in scutes of dead tortoises revealed patterns of trace elemental distribution from which the chronology of elemental uptake can ...

PubMed

66
Solids sampling using double-pulse laser ablation inductivelycoupled plasma mass spectrometry
2003-07-01

This paper describes the use of double-pulse laser ablation to improve ICP-MS internal precision (temporal relative standard deviation, %TRSD). Double pulse laser ablation offers reduced fractionation, increased sensitivity, and improved signal to noise ratios. The first pulse is used to ablate a large quantity of ...

Energy Citations Database

67
New analysis technique for microsamples.
1989-01-01

For many decades, isotopic analysis of Uranium or Plutonium has been performed by mass spectrometry. The most recent analytical techniques, using the counting method or a plasma torch combined with a mass spectrometer (ICP.MS) have not yet to reach a grea...

National Technical Information Service (NTIS)

68
Laser ablation ICP-mass spectrometry determination of Th(sup 230) in soils at the Gunnison, Colorado UMTRA site.
1994-01-01

This report describes an innovative technology, laser ablation-inductively couple plasma-mass spectrometry (LA-ICP-MS), operated in a mobile laboratory, to rapidly detect thorium 230 activity levels in soil samples. This technology was demonstrated on-sit...

National Technical Information Service (NTIS)

69
Comparison of Time-Of-Flight and Multicollector ICP Mass Spectrometers for Measuring Actinides in Small Samples Using Single Shot Laser Ablation.
2005-01-01

The objective of these experiments is to evaluate the performance of two types of ICP-MS device for measurement of actinide isotopes by laser ablation (LA) ICP-MS. The key advantage of ICP-MS compared to monitoring of radioactive decay is that the element...

National Technical Information Service (NTIS)

70
Inductively Coupled Plasma: Fundamental Particle Investigations with Laser Ablation and Applications in Magnetic Sector Mass Spectrometry
2008-08-18

Particle size effects and elemental fractionation in laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) are investigated with nanosecond and femtosecond laser ablation, differential mobility analysis, and magnetic sector ICP-MS. Laser pulse width was found to have a significant influence on the ...

Energy Citations Database

71
Evolving Pb isotope signatures of London airborne particulate matter (PM 10)-constraints from on-filter and solution-mode MC-ICP-MS.
2008-06-04

Pb isotope compositions of biologically significant PM(10) atmospheric particulates from a busy roadside location in London UK were measured using solution- and laser ablation-mode MC-ICP-MS. The solution-mode data for PM(10) sampled between 1998-2001 document a dramatic shift to increasingly radiogenic compositions as leaded petrol was phased out. ...

PubMed

72
Trace elemental analysis of glass and paint samples of forensic interest by ICP-MS using laser ablation solid sample introduction
2003-09-01

The importance of small amounts of glass and paint evidence as a means to associate a crime event to a suspect or a suspect to another individual has been demonstrated in many cases. Glass is a fragile material that is often found at the scenes of crimes such as burglaries, hit-and-run accidents and violent crime offenses. Previous work has demonstrated the utility of elemental analysis by ...

NASA Astrophysics Data System (ADS)

73
Particle Generation by Laser Ablation in Support of Chemical Analysis of High Level Mixed Waste from Plutonium Production Operations
2001-11-30

Investigate particles produced by laser irradiation and their analysis by Laser Ablation Inductively Coupled Plasma Mass Spectroscopy (LA/ICP-MS), with a view towards optimizing particle production for analysis of high level waste materials and waste glass. LA/ICP-MS has considerable potential to increase the safety and speed of ...

Energy Citations Database

74
LA-ICP-MS analysis of African glass beads: Laboratory inter-comparison with an emphasis on the impact of corrosion on data interpretation
2009-07-01

A comparison between the compositions determined by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) from two different laboratories on 52 ancient beads recovered in Africa was undertaken. Single point and raster samplings by the laser ablation systems were used. Although similar results were obtained using the ...

NASA Astrophysics Data System (ADS)

75
Bioimaging of metals in brain tissue from micrometre to nanometre scale by laser ablation inductively coupled plasma mass spectrometry: State of the art and perspectives
2010-01-01

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) with multi-element capability is well established for the trace and ultratrace analysis of metals, metalloids and selected non-metals (such as C, P, S) in biological and clinical samples. Nowadays LA-ICP-MS is employed as a sensitive elemental mass spectrometric ...

NASA Astrophysics Data System (ADS)

76
Determination of vanadium in Saudi Arabian crude oil by inductively coupled plasma-mass spectrometry (ICP/MS)
1990-01-01

Vanadium, among other elements which deposit on a cracking catalyst, affects the catalyst activity. The inductively coupled plasma as an ion source, when combined with a mass analyzer, resulted in a sensitive tool for elemental analysis (ICP/MS) at parts per billion levels in solution. This technique has ben applied for the determination of vanadium in ...

Energy Citations Database

77
A two-stage exhumation of the Variscan crust: U�Pb LA-ICP-MS and Rb�Sr ages from Greater Kabylia, Maghrebides

present LA-ICP-MS U�Pb results from monazites and Rb� Sr analyses from biotites extracted from a major of deep crustal levels. LA-ICPMS U�Pb dating of monazites, combined with Rb�Sr analyses of biotites, from and the subsequent exhumation of deep crustal levels in the internal zones of the Maghrebides. Monazites give an age

E-print Network

78
Improved Analytical Characterization of Solid Wastes-Forms by Fundamental Development of Laser Ablation Technology
1999-06-01

Laser ablation (LA) with inductively coupled plasma mass spectrometry (ICP-MS) has been demonstrated as a viable technology for sample characterization within the EM complex. Laser ablation systems have been set up at the Hanford Site, Savannah River Plant, the Pu immobilization program (MD), Los Alamos, and at numerous other DOE ...

Energy Citations Database

79
Multiplexed immunohistochemical detection of tumor markers in breast cancer tissue using laser ablation inductively coupled plasma mass spectrometry.
2011-09-18

We optimized multiplexed immunohistochemistry (IHC) on breast cancer tissue. Up to 20 tumor markers are routinely evaluated for one patient and thus, a common analysis results in a series of time consuming staining procedures. As an alternative, we used lanthanides for labeling of primary antibodies, which are applied in IHC. Laser ablation (LA) ICP ...

PubMed

80
Solution and laser ablation inductively coupled plasma�mass spectrometry measurements of Br, I, Pb, Mn, Cd, Zn, and B in the organic skeleton of soft corals and black corals
2011-03-01

Proxy records can be derived from soft corals and black corals using minor and trace element measurements of the organic skeleton of these corals. Here, concentrations of Br, I, Pb, Mn, Cd, Zn, and B in the organic skeleton were determined using solution inductively coupled plasma�mass spectrometry (ICP-MS) in one black coral from 5 m depth and two soft corals from 85 and ...

NASA Astrophysics Data System (ADS)

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81
Measurement of longitudinal sulfur isotopic variations by laser ablation MC-ICP-MS in single human hair strands.
2009-02-06

A new method for the measurement of longitudinal variations of sulfur isotope amount ratios in single hair strands using a laser ablation system coupled to a multicollector inductively coupled plasma mass spectrometer (LA-MC-ICP-MS) is reported here for the first time. Ablation parameters have been optimized for the measurement of ...

PubMed

82
Characterization Of Nuclear Materials Using Time-Of-Flight ICP-MS
2006-10-01

The investigation of illicit trafficking of nuclear materials, nuclear safeguards analysis, and non-proliferation control requires sensitive and isotope-selective detection methods to gain crucial nuclear forensic information like isotope 'fingerprints' and multi-element signatures. The advantage of time-of-flight (TOF) mass spectrometry - quasi-simultaneous multi-mass analysis - ...

Energy Citations Database

83
Strontium isotope ratios (87Sr/86Sr) of tooth enamel: a comparison of solution and laser ablation multicollector inductively coupled plasma mass spectrometry methods.
2008-10-01

Strontium isotope ratios (87Sr/86Sr) in tooth enamel provide a means to investigate migration and landscape use in humans and other animals. Established methods for measuring (87)Sr/(86)Sr in teeth use bulk sampling (5-20 mg) and labor-intensive elemental purification procedures before analysis by either thermal ionization mass spectrometry (TIMS) or multicollector inductively coupled plasma mass ...

PubMed

84
Imaging of nutrient elements in the leaves of Elsholtzia splendens by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS).
2008-11-13

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was used for the quantitative imaging of nutrient elements (such as K, Mg, Mn, Cu, P, S and B) in the leaves of Elsholtzia splendens. The plant leaves were scanned directly with a focused Nd:YAG laser in the laser ablation chamber. The ablated ...

PubMed

85
The potential of external IBA and LA-ICP-MS for obsidian elemental characterization
2004-11-01

Combined external Ion Beam Analysis (IBA) measurements, consisting of Proton Induced X-ray Emission-Proton Induced Gamma-ray Emission-Rutherford Back-Scattering (PIXE-PIGE-RBS) have been performed on several obsidian fragments with archaeological significance at the Rossendorf tandem accelerator using a 3.85 MeV proton beam. A comparison was made between these external IBA ...

NASA Astrophysics Data System (ADS)

86
Detrital Zircon U-Pb Ages of Late Silurian and Early Devonian Sedimentary Sequences From Northwestern Svalbard, Implications for Regional Correlations in the Arctic Caledonides
2008-12-01

In the North Atlantic region, Caledonian and Grenvillian terrains are exposed on Svalbard, Greenland, Great Britain, Canada and Scandinavia. Reconstructing the original configuration of these terrains depends partly on determining the age and provenance of the sedimentary rocks overlying the basement. Provenance investigations using detrital zircon U-Pb ages are a powerful tool to explore the ...

NASA Astrophysics Data System (ADS)

87
Characterization and identification of local defects in glass.

The most relevant defects in glasses are categorized and investigated by appropriate microanalytical techniques. Since these defects very often present a real challenge because of complex chemical and mineralogical properties, a multimethod approach is necessary to supplement or confirm the findings from scanning techniques. The combination of electron probe ...

PubMed

88
Absolute quantification of superoxide dismutase (SOD) using species-specific isotope dilution analysis.
2010-08-01

Here we report for the first time the use of species-specific isotope dilution mass spectrometry for the absolute quantification of a metalloprotein using nondenaturing gel electrophoresis laser ablation inductively coupled plasma mass spectrometry (GE-LA-ICP-MS). The concept utilises the intrinsic metals of the metalloprotein for labelling of the ...

PubMed

89
Study of essential element accumulation in the leaves of a Cu-tolerant plant Elsholtzia splendens after Cu treatment by imaging laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS).
2008-11-30

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was used for the quantitative imaging of Cu and other essential elements (such as K, Mg, Mn, P, S and B) in the leaves of a Cu-tolerant plant Elsholtzia splendens treated with the enriched (65)Cu isotope tracer (isotope abundance of 89.2%). The leaves (newly formed, fully grown and ...

PubMed

90
Particle generation by laser ablation in support of chemical analysis of high level mixed waste from plutonium production operations. 1998 annual progress report.
1998-01-01

The authors goal is to provide fundamental mechanistic studies of laser produced particulate formation in support of the use of Laser Assisted- Inductively Coupled Plasma-Mass Spectroscopy (LA-ICP-MS) to be used for analysis of radioactive/toxic materials...

National Technical Information Service (NTIS)

91
Particle Generation by Laser Ablation in Support of Chemical Analysis of High Level Mixed Waste from Plutonium Production Operations
2000-06-01

To provide fundamental mechanistic studies of laser-produced particulate formation in support of the analysis of radioactive and/or toxic materials by Laser Assisted-Inductively Coupled Plasma Mass Spectroscopy (LA/ICP-MS).

Energy Citations Database

92
Particle Generation by Laser Ablation in Support of Chemical Analysis of High Level Mixed Waste from Plutonium Production Operations
1999-06-01

To provide fundamental mechanistic studies of laser-produced particulate formation in support of the analysis of radioactive and/or toxic materials by Laser Assisted-Inductively Coupled Plasma Mass Spectroscopy (LA-ICP-MS).

Energy Citations Database

93
Mg Isotopes in Melilite, Fassaite and Spinels in CAIs: Evidence for Evaporation, Equilibration and Late Stage Alteration
2002-03-01

High precision laser ablation MC-ICP-MS of Mg isotopes shows uniform initial Mg and Al-Mg systematics in a Leoville Type B CAI. Part of the inclusion underwent complete resetting after complete decay of 26Al.

NASA Astrophysics Data System (ADS)

94
Analysis of Enriched and Depleted Uranium Oxide Powders by LA-ICP-MS.
2005-01-01

The objective of this work is to demonstrate the analysis of ensembles of small samples on filter media by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Spatially resolved analysis of particulate samples collected on gelatin-bas...

National Technical Information Service (NTIS)

95
Recent applications on isotope ratio measurements by ICP-MS and LA-ICP-MS on biological samples and single particles
2008-02-01

Inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation ICP-MS (LA-ICP-MS) have proved themselves to be powerful and sensitive inorganic mass spectrometric techniques for analysing stable and radioactive isotopes in different application fields because of their high sensitivity, low detection ...

NASA Astrophysics Data System (ADS)

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