Inversion of instantaneous equivalent absorption coefficient and its application
Weihua, W. )
1992-01-01
Absorption coefficient is an important parameter for reservoir description. The major troubles in extracting absorption coefficient from seismic data are amplitude and waveform distortions; they greatly restrict the inversion which is based on reflection amplitude variation or reflection frequency variation. This paper presents a new method which avoids amplitude and uses waveform variation gradient in wave propagation to make the inversion of absorption coefficient. Apparent absorption coefficient and pseudo absorption coefficient are adopted so as to remove the influence which the waveform distortion due to thin bed tuning brings to absorption coefficient extraction. The final instantaneous equivalent absorption coefficient, a true absorption coefficient which reflects real absorptive character of a seismic medium, can be obtained by subtracting the pseudo absorption coefficient (inversely calculated using maximum entropy) from the apparent absorption coefficient the authors have calculated.
NASA Astrophysics Data System (ADS)
Bernhard, G.; Evans, R. D.; Labow, G. J.; Oltmans, S. J.
2005-05-01
The Dobson spectrophotometer is the primary standard instrument for ground-based measurements of total column ozone. The accuracy of its data depends on the knowledge of ozone absorption coefficients used for data reduction. We document an error in the calculations that led to the set of absorption coefficients currently recommended by the World Meteorological Organisation (WMO). This error has little effect because an empirical adjustment was applied to the original calculations before the coefficients were adopted by WMO. We provide evidence that this adjustment was physically sound. The coefficients recommended by WMO are applied in the Dobson network without correction for the temperature dependence of the ozone absorption cross sections. On the basis of data measured by Dobson numbers 80 and 82, which were operated by the National Oceanic and Atmospheric Administration (NOAA) Climate Monitoring and Diagnostics Laboratory at the South Pole, we find that omission of temperature corrections may lead to systematic errors in Dobson ozone data of up to 4%. The standard Dobson ozone retrieval method further assumes that the ozone layer is located at a fixed height. This approximation leads to errors in air mass calculations, which are particularly relevant at high latitudes where ozone measurements are performed at large solar zenith angles (SZA). At the South Pole, systematic errors caused by this approximation may exceed 2% for SZAs larger than 80°. The bias is largest when the vertical ozone distribution is distorted by the "ozone hole" and may lead to underestimation of total ozone by 4% at SZA = 85° (air mass 9). Dobson measurements at the South Pole were compared with ozone data from a collocated SUV-100 UV spectroradiometer and Version 8 overpass data from NASA's Total Ozone Mapping Spectrometer (TOMS). Uncorrected Dobson ozone values tend to be lower than data from the two other instruments when total ozone is below 170 Dobson units or SZAs are larger than
Radiometer gives true absorption and emission coefficients
NASA Technical Reports Server (NTRS)
Fymat, A. L.
1977-01-01
Novel radiometer, unaffected by scattering and polarization, measures true absorption and emmission coefficients for arbitrary mixture of gases and polluting particles. It has potential astronomical, meteorological, and environmental applications, such as determination of radiative heat budget, aerosol relative concentration, and morphology of cloud, haze, and fog formations. Data and temperature can be coupled directly to small computer for online calculation of radiation coefficients.
Determination of absorption coefficients of thin films
Lodenquai, J.F. )
1994-08-01
The equations that are usually presented as those used to determine the absorption coefficients of materials in film form based on measurements of transmission and reflection coefficients are fundamentally incorrect. These equations omit a multiplicative factor arising from the complex nature of the refractive indices of the materials. This factor enters explicitly into the relationship between the transmission and reflection coefficients for such materials and is not necessarily close to unity, although in practice this factor can be approximated by unity at least in the infrared through the optical range of wavelengths.
[Influencing factors in measuring absorption coefficient of suspended particulate matters].
Yu, Xiao-long; Shen, Fang; Zhang, Jin-fang
2013-05-01
Absorption coefficient of suspended particulate matters in natural water is one of the key parameters in ocean color remote sensing. In order to study the influencing factors that affect the measurement, a series of experiments were designed to measure samples using transmittance method (T method), transmittance-reflectance method (T-R method) and absorptance method (A method). The results shows that absorption coefficient measured by the A method has a much lower error compared to the T method and T-R method due to influencing factors,such as filter-to-filter variations, water content of the filter, and homogeneity of filter load and so on. Another factor influence absorption coefficient is path-length amplification induced by multiple scattering inside the filter. To determine the path-length amplification, the true absorption was measured by AC-s (WetLabs). The linear fitting result shows that the mean path-length amplification is much higher for the A method than that of the T-R method and the T method (4.01 versus 2.20 and 2.32), and the corresponding correlation coefficient are 0.90, 0.87 and 0.80. For the A method and the T-R method, higher correlation coefficients are calculated when using polynomial fitting, and the value are 0.95 and 0.94. Analysis of the mean relative error caused by different influencing factors indicates that path-length amplification is the largest error source in measuring the absorption coefficient. PMID:23914523
Aerosol Angstrom Absorption Coefficient Comparisons during MILAGRO.
NASA Astrophysics Data System (ADS)
Marley, N. A.; Marchany-Rivera, A.; Kelley, K. L.; Mangu, A.; Gaffney, J. S.
2007-12-01
aerosol Angstrom absorption exponents by linear regression over the entire UV-visible spectral range. These results are compared to results obtained from the absorbance measurements obtained in the field. The differences in calculated Angstrom absorption exponents between the field and laboratory measurements are attributed partly to the differences in time resolution of the sample collection resulting in heavier particle pileup on the filter surface of the 12-hour samples. Some differences in calculated results can also be attributed to the presence of narrow band absorbers below 400 nm that do not fall in the wavelengths covered by the 7 wavelengths of the aethalometer. 1. Marley, N.A., J.S. Gaffney, J.C. Baird, C.A. Blazer, P.J. Drayton, and J.E. Frederick, "The determination of scattering and absorption coefficients of size-fractionated aerosols for radiative transfer calculations." Aerosol Sci. Technol., 34, 535-549, (2001). This work was conducted as part of the Department of Energy's Atmospheric Science Program as part of the Megacity Aerosol Experiment - Mexico City during MILAGRO. This research was supported by the Office of Science (BER), U.S. Department of Energy Grant No. DE-FG02-07ER64329. We also wish to thank Mexican Scientists and students for their assistance from the Instituto Mexicano de Petroleo (IMP) and CENICA.
Linear and nonlinear optical absorption coefficients of spherical dome shells
NASA Astrophysics Data System (ADS)
Guo, Kangxian; Liu, Guanghui; Huang, Lu; Zheng, Xianyi
2015-08-01
Linear and nonlinear optical absorption coefficients of spherical dome shells are theoretically investigated within analytical wave functions and numerical quantized energy levels. Our results show that the inner radius, the outer radius and the cut-off angle of spherical dome shells have great influences on linear and nonlinear optical absorption coefficients as well as the total optical absorption coefficients. It is found that with the increase of the inner radius and the outer radius, linear and nonlinear optical absorption coefficients exhibit a blueshift and a redshift, respectively. However, with the increase of the cut-off angle, linear and nonlinear optical absorption coefficients do not shift. Besides, the resonant peaks of linear and nonlinear optical absorption coefficients climb up and then decrease with increasing the cut-off angle. The influences of the incident optical intensity on the total optical absorption coefficients are studied. It is found that the bleaching effect occurs at higher incident optical intensity.
Scattering and absorption coefficients of silica-doped alumina aerogels.
Fu, Tairan; Tang, Jiaqi; Chen, Kai; Zhang, Fan
2016-02-01
Alumina-based aerogels are especially useful in many applications due to their excellent stability at high temperatures. This study experimentally analyzed the radiative properties of silica-doped alumina aerogels through spectral directional-hemispherical measurements for wavelengths of 0.38-25 μm. The silica-doped alumina aerogel samples were prepared with a 1.4∶1 molar ratio of silica to alumina. A two-flux model was used to describe the radiation propagation in a 1D scattering absorbing sample to derive expressions for the normal-hemispherical transmittances and reflectances based on the transport approximation. The normal-hemispherical transmittances and reflectances were measured at various spectral wavelengths and sample thicknesses using the integrating sphere method. The spectral absorption and transport scattering coefficients of silica-doped alumina aerogels were then determined from the measured normal-hemispherical data. The absorption and transport scattering coefficients of silica-doped alumina aerogels are (0.1 cm-1, 36 cm-1) and (0.1 cm-1, 112 cm-1) for wavelengths of 0.38-8.0 μm. The spectral transport scattering coefficient varies in the opposite direction from the spectral absorption coefficient for various wavelengths. The radiative properties for silica and alumina aerogels were quite different for the absorption coefficient for wavelengths of 2.5-8.0 μm and for the transport scattering coefficient for wavelengths of 0.38-2.5 and 3.5-6.0 μm. The measured radiative properties were used to predict the spectral normal-hemispherical reflectance and transmittance of the silica-doped alumina aerogels for various sample thicknesses and wavelengths. The predicted values do not change for the sample thicknesses greater than a critical value. The analysis provides valuable reference data for alumina aerogels for high-temperature applications. PMID:26836071
Continuum Absorption Coefficient of Atoms and Ions
NASA Technical Reports Server (NTRS)
Armaly, B. F.
1979-01-01
The rate of heat transfer to the heat shield of a Jupiter probe has been estimated to be one order of magnitude higher than any previously experienced in an outer space exploration program. More than one-third of this heat load is due to an emission of continuum radiation from atoms and ions. The existing computer code for calculating the continuum contribution to the total load utilizes a modified version of Biberman's approximate method. The continuum radiation absorption cross sections of a C - H - O - N ablation system were examined in detail. The present computer code was evaluated and updated by being compared with available exact and approximate calculations and correlations of experimental data. A detailed calculation procedure, which can be applied to other atomic species, is presented. The approximate correlations can be made to agree with the available exact and experimental data.
Dynamic absorption coefficients of CAR and non-CAR resists at EUV
NASA Astrophysics Data System (ADS)
Fallica, Roberto; Stowers, Jason K.; Grenville, Andrew; Frommhold, Andreas; Robinson, Alex P. G.; Ekinci, Yasin
2016-03-01
The dynamic absorption coefficients of several CAR and non-CAR EUV photoresists are measured experimentally using a specifically developed setup in transmission mode at the XIL beamline of the Swiss Light Source. The absorption coefficient α and the Dill parameters ABC were measured with unprecedented accuracy. In general the α of resists match very closely with the theoretical value calculated from elemental densities and absorption coefficients, whereas exceptions are observed. In addition, through the direct measurements of the absorption coefficients and dose-to-clear values, we introduce a new figure of merit called Chemical Sensitivity to account for all the post-absorption chemical reaction ongoing in the resist, which is also predicts a quantitative clearing volume, and respectively clearing radius, due to the photon absorption in the resist. These parameters may help in deeper insight into the underlying mechanisms of EUV concept of clearing volume and clearing radius are then defined and quantitatively calculated.
Effect of applied mechanical stress on absorption coefficient of compounds
Gupta, Manoj Kumar; Singh, Gurinderjeet; Dhaliwal, A. S.; Kahlon, K. S.
2015-08-28
The absorption coefficient of given materials is the parameter required for the basic information. The measurement of absorption coefficient of compounds Al{sub 2}O{sub 3}, CaCO{sub 3}, ZnO{sub 2}, SmO{sub 2} and PbO has been taken at different incident photon energies 26, 59.54, 112, 1173, 1332keV. The studies involve the measurements of absorption coefficient of the self supporting samples prepared under different mechanical stress. This mechanical stress is render in terms of pressure up to 0-6 ton by using hydraulic press. Measurements shows that absorption coefficient of a material is directly proportional to applied mechanical stress on it up to some extent then become independent. Experimentally measured results are in fairly good agreement with in theoretical values obtained from WinXCOM.
Effect of applied mechanical stress on absorption coefficient of compounds
NASA Astrophysics Data System (ADS)
Gupta, Manoj Kumar; Singh, Gurinderjeet; Dhaliwal, A. S.; Kahlon, K. S.
2015-08-01
The absorption coefficient of given materials is the parameter required for the basic information. The measurement of absorption coefficient of compounds Al2O3, CaCO3, ZnO2, SmO2 and PbO has been taken at different incident photon energies 26, 59.54, 112, 1173, 1332keV. The studies involve the measurements of absorption coefficient of the self supporting samples prepared under different mechanical stress. This mechanical stress is render in terms of pressure up to 0-6 ton by using hydraulic press. Measurements shows that absorption coefficient of a material is directly proportional to applied mechanical stress on it up to some extent then become independent. Experimentally measured results are in fairly good agreement with in theoretical values obtained from WinXCOM.
Measurements of the absorption coefficient of stratospheric aerosols
NASA Technical Reports Server (NTRS)
Ogren, J. A.; Ahlquist, N. C.; Clarke, A. D.; Charlson, R. J.
1981-01-01
The absorption coefficients of stratospheric aerosols are measured using a variation on the integrating plate method. The technique is based on the decrease in the transparency of a substrate when an absorbing aerosol is deposited on it. A Lambert scatterer is placed behind the substrate to integrate forward scattered light and minimize the effect of scattering on the measurement. The low pressure in the stratosphere is used for the direct impaction of particles onto a narrow strip of opal glass. The eight samples collected had a median value of 4 x 10 to the -9th m with an uncertainty of + or - 5 x 10 to the -9th m. If this absorption is due to graphitic carbon, then its concentration is estimated at about 0.4 ng/cu m, or about 0.25% of the total aerosol mass concentration. Estimates of the aerosol scattering coefficients based on satellite extinction inversions result in an aerosol single-scattering albedo in the range of 0.96-1.0.
Absorption coefficients of a hydrogen plasma for laser radiation
NASA Technical Reports Server (NTRS)
Stallcop, J. R.
1974-01-01
The formalism for the calculation of the absorption of radiation by a hydrogen plasma at common laboratory conditions is summarized. The hydrogen plasma absorption coefficient for laser radiation has been computed for a wide range of electron densities and temperatures (10,000-40,000 K). The results of this computation are presented in a graphical form that permits a determination of the absorption coefficient for the following laser wavelengths: 0.176, 0.325, 0.337, 0.442, 0.488, 0.515, 0.633, 0.694, 1.06, 1.15, 2.36, 3.39, 5.40 and 10.6 microns. The application of these results and laser radiation absorption measurements to plasma diagnostics is discussed briefly.
Weibel instability due to inverse bremsstrahlung absorption
Bendib, A.; Bendib, K.,; Bendib, A.; Bendib, K.; Sid, A.,; Bendib, K.,
1997-06-01
A new Weibel source due to the inverse bremsstrahlung absorption is presented. It has been shown that in homogeneous plasmas, this mechanism may drive strong collisionless Weibel modes with growth rates of order of {gamma}{approximately}10{sup 11}s{sup {minus}1} and negligible group velocities. In the laser-produced plasmas, for short laser wavelengths ({lambda}{sub L}{lt}1{mu}m) and high laser fluxes (I{gt}10{sup 14}W/cm{sup 2}), this Weibel source is most efficient as the ones due to the heat flux and the plasma expansion. The useful scaling law of the convective e-foldings, with respect to the laser and the plasma parameters, is also derived. {copyright} {ital 1997} {ital The American Physical Society}
A reverberation room round robin on the determination of absorption coefficients
NASA Astrophysics Data System (ADS)
Kath, U.
In ten reverberation rooms with very different volumes and different room shapes, the absorption coefficients for mineral fiber mat were measured. The particular feature of this round robin was that the absorption material was much thicker than in other similar experiments and that it was measured not only with an area of 12 sq m on the floor, but also as a complete surface covering of a small wall in order to avoid the edge effect. The decay curves were evaluated in at least two institutions and the absorption coefficients were calculated using the Eyring equation. The absorption coefficients were quite dispersed from one room to another and also from one-third octave band to the adjacent ones. Errors due to change are small, thus one is dealing with systematic errors.
NASA Astrophysics Data System (ADS)
Li, Xiaoqi; Jiang, Huabei
2013-02-01
We present a study through extensive simulation that considers the impact of inhomogeneous optical scattering coefficient distribution on recovery of optical absorption coefficient maps using tomographic photoacoustic data collected from media mimicking breast tissue. We found that while the impact of scattering heterogeneities/targets is modest on photoacoustic recovery of optical absorption coefficients, the impact of scattering contrast caused by adipose tissue, a layer of normal tissue along the boundary of the breast, is dramatic on reconstruction of optical absorption coefficients using photoacoustic data—up to 25.8% relative error in recovering the absorption coefficient is estimated in such cases. To overcome this problem, we propose a new method to enhance photoacoustic recovery of the optical absorption coefficient in heterogeneous media by considering inhomogeneous scattering coefficient distribution provided by diffuse optical tomography (DOT). Results from extensive simulations show that photoacoustic recovery of absorption coefficient maps can be improved considerably with a priori scattering information from DOT.
Absorption-coefficient-determination method for particulate materials.
Lindberg, J D; Douglass, R E; Garvey, D M
1994-07-01
A method is presented for determining the optical absorption coefficient, or the imaginary refractive index, of particulate material that has been collected from aerosols or hydrosols by means of filtration. The method, based on the Kubelka-Munk theory of diffuse reflectance, is nondestructive and requires no other knowledge of the sample than the amount present, the specific gravity, and an estimate of the real index of refraction. The theoretical development of the method is discussed along with an analysis of photometric and gravimetric errors. We test the method by comparing results obtained for powdered didymium glass with measurements made before the glass was crushed. An example of the method's application to the determination of the absorption coefficient of atmospheric dust at UV, visible, and near-IR wavelengths is also presented. PMID:20935789
A high absorption coefficient DL-MPP imitating owl skin
NASA Astrophysics Data System (ADS)
Guo, Lijun; Zhao, Zhan; Kong, Deyi; Wu, Shaohua; Du, Lidong; Fang, Zhen
2012-11-01
This paper proposes a high absorption coefficient micro-perforated panel (MPP) imitating owl skin structure for acoustic noise reduction. Compared to the traditional micro-perforated panel, this device has two unique characteristics-simulating the owl skin structure, its radius of perforated apertures even can be as small as 55μ, and its material is silicon and fabricated by micro-electrical mechanical system (MEMS) technology; So that its absorption coefficients of acoustic noise for normal incidence sound wave whose frequencies arrange from 1.5 kHz to 6.0 kHz are all above 0.8 which is the owl's hunts sensitivity frequency band. Double leaf MPP fabricated by MEMS technology is an absolutely bionic success in functional-imitation.
Ottink, Marco; Brunskog, Jonas; Jeong, Cheol-Ho; Fernandez-Grande, Efren; Trojgaard, Per; Tiana-Roig, Elisabet
2016-01-01
Absorption coefficients are mostly measured in reverberation rooms or with impedance tubes. Since these methods are only suitable for measuring the random incidence and the normal incidence absorption coefficient, there exists an increasing need for absorption coefficient measurement of finite absorbers at oblique incidence in situ. Due to the edge diffraction effect, oblique incidence methods considering an infinite sample fail to measure the absorption coefficient at large incidence angles of finite samples. This paper aims for the development of a measurement method that accounts for the finiteness of the absorber. A sound field model, which accounts for scattering from the finite absorber edges, assuming plane wave incidence is derived. A significant influence of the finiteness on the radiation impedance and the corresponding absorption coefficient is found. A finite surface method, which combines microphone array measurements over a finite sample with the sound field model in an inverse manner, is proposed. Besides, a temporal subtraction method, a microphone array method, impedance tube measurements, and an equivalent fluid model are used for validation. The finite surface method gives promising agreement with theory, especially at near grazing incidence. Thus, the finite surface method is proposed for further measurements at large incidence angles. PMID:26827003
Optimization of the acoustic absorption coefficients of certain functional absorbents
NASA Technical Reports Server (NTRS)
Pocsa, V.; Biborosch, L.; Veres, A.; Halpert, E.; Lorian, R.; Botos, T.
1974-01-01
The sound absorption coefficients of some functional absorbents (mineral wool plates) are determined by the reverberation chamber method. The influence of the angle of inclination of the sound absorbing material with respect to the surface to be treated is analyzed as well as the influence of the covering index, defined as the ratio of the designed area of a plate and the area of the treated surface belonging to another plate. As compared with the conventional method of applying sound-absorbing plates, the analyzed structures have a higher technological and economical efficiency. The optimum structure corresponds to an angle of inclination of 15 deg and a covering index of 0.8.
A method for monitoring nuclear absorption coefficients of aviation fuels
NASA Technical Reports Server (NTRS)
Sprinkle, Danny R.; Shen, Chih-Ping
1989-01-01
A technique for monitoring variability in the nuclear absorption characteristics of aviation fuels has been developed. It is based on a highly collimated low energy gamma radiation source and a sodium iodide counter. The source and the counter assembly are separated by a geometrically well-defined test fuel cell. A computer program for determining the mass attenuation coefficient of the test fuel sample, based on the data acquired for a preset counting period, has been developed and tested on several types of aviation fuel.
Liu, Qiang; Niu, Ming-Sheng; Wang, Gui-Shi; Cao, Zhen-Song; Liu, Kun; Chen, Wei-Dong; Gao, Xiao-Ming
2013-07-01
In the present paper, the authors focus on the effect of the resonance frequency shift due to the changes in temperature and humidity on the PA signal, present several methods to control the noise derived form gas flow and vibration from the sampling pump. Based on the efforts mentioned above, a detection limit of 1.4 x 10(-8) W x cm(-1) x Hz(-1/2) was achieved for the measurement of atmospheric aerosols absorption coefficient. During the experiments, the PA cell was calibrated with the absorption of standard NO2 gas at 532 nm and the atmospheric aerosols were measured continuously. The measurement results show that the PAS is suitable for the real-time measurement of the absorption coefficient of atmospheric aerosols in their natural suspended state. PMID:24059163
Damping coefficients due to tail surfaces in aircraft
NASA Technical Reports Server (NTRS)
Chu, Lynn
1923-01-01
The object of the investigation described in this report was to compare the damping coefficients of an airfoil as calculated from a knowledge of the static characteristics of the section with those obtained experimentally with an oscillation. The damping coefficients as obtained, according to the conventional notation, can be considered either as due to pitching or as due to yawing, the oscillation in these experiments being so arranged that the surfaces oscillate about a vertical axis. This is in reality the case when the influence is yawing about the standard Z-axis, but it can also be considered as a pitching motion when the model is so rigged that its standard Y-axis becomes vertical. The horizontal oscillation has the advantage of eliminating the gravity action and avoiding the use of counterweights, whose presence in the wind tunnel is undesirable because of their interference with the air flow. The real point of the investigation was to separate the damping due to rotation from that due to translation. By varying the distance between the center of pressure and the center of rotation on the oscillator, the variation of damping moment can be observed and the rotational and translational effects can be separated.
Photoacoustic measurements of black carbon light absorption coefficients in Irbid city, Jordan.
Hamasha, Khadeejeh M; Arnott, W Patrick
2010-07-01
There is a need to recognize air pollution levels by particles, especially in developing countries such as Jordan where data are scarce due to the absence of routine monitoring of ambient air quality. This study aims at studying the air quality in different locations at Irbid, Jordan through the measurement and analysis of the time series of black carbon light absorption coefficients (B (abs)). Black carbon light absorption coefficients were measured with a photoacoustic instrument at a wavelength of 870 nm. The measurements were conducted during July 2007 at six sites in Irbid city, Jordan. Comparisons of black carbon concentrations at various locations were conducted to understand where values tend to be largest. The average value of B (abs) of all sites was 40.4 Mm(-1). The largest value of B (abs) was 61.2 Mm(-1) at Palestine Street which is located at a very crowded street in a highly populated region in the city center. The lowest value was 14.1 Mm(-1) at Thirtieth Street which is located at a main street in an open plain region in the east of the city. The black carbon light absorption coefficients fluctuate above a background level (transported black carbon from the neighboring states), which are almost identical at all sampling sites. The light absorption coefficients will be used as a benchmark in later years as combustion efficiencies and population patterns change. PMID:19479334
Photosensitizer absorption coefficient modeling and necrosis prediction during Photodynamic Therapy.
Salas-García, Irene; Fanjul-Vélez, Félix; Arce-Diego, José Luis
2012-09-01
The development of accurate predictive models for Photodynamic Therapy (PDT) has emerged as a valuable tool to adjust the current therapy dosimetry to get an optimal treatment response, and definitely to establish new personal protocols. Several attempts have been made in this way, although the influence of the photosensitizer depletion on the optical parameters has not been taken into account so far. We present a first approach to predict the spatio-temporal variation of the photosensitizer absorption coefficient during PDT applied to dermatological diseases, taking into account the photobleaching of a topical photosensitizer. This permits us to obtain the photons density absorbed by the photosensitizer molecules as the treatment progresses and to determine necrosis maps to estimate the short term therapeutic effects in the target tissue. The model presented also takes into account an inhomogeneous initial photosensitizer distribution, light propagation in biological media and the evolution of the molecular concentrations of different components involved in the photochemical reactions. The obtained results allow to investigate how the photosensitizer depletion during the photochemical reactions affects light absorption by the photosensitizer molecules as the optical radiation propagates through the target tissue, and estimate the necrotic tumor area progression under different treatment conditions. PMID:22704663
Index of Refraction and Absorption Coefficient Spectra of Paratellurite in the Terahertz Region
NASA Astrophysics Data System (ADS)
Unferdorben, Márta; Buzády, Andrea; Hebling, János; Kiss, Krisztián; Hajdara, Ivett; Kovács, László; Péter, Ágnes; Pálfalvi, László
2016-07-01
Index of refraction and absorption coefficient spectra of pure paratellurite (α-TeO2) crystal as a potential material for terahertz (THz) applications were determined in the 0.25-2 THz frequency range at room temperature by THz time domain spectroscopy (THz-TDS). The investigation was performed with beam polarization both parallel (extraordinary polarization) and perpendicular (ordinary polarization) to the optical axis [001] of the crystal. Similarly to the visible spectral range, positive birefringence was observed in the THz range as well. It was shown that the values of the refractive index for extraordinary polarization are higher and show significantly larger dispersion than for the ordinary one. The absorption coefficient values are also larger for extraordinary polarization. The measured values were fitted by theoretical curves derived from the complex dielectric function containing independent terms of Lorentz oscillators due to phonon-polariton resonances. The results are compared with earlier publications, and the observed significant discrepancies are discussed.
Determination of RW3-to-water mass-energy absorption coefficient ratio for absolute dosimetry.
Seet, Katrina Y T; Hanlon, Peta M; Charles, Paul H
2011-12-01
The measurement of absorbed dose to water in a solid-phantom may require a conversion factor because it may not be radiologically equivalent to water. One phantom developed for the use of dosimetry is a solid water, RW3 white-polystyrene material by IBA. This has a lower mass-energy absorption coefficient than water due to high bremsstrahlung yield, which affects the accuracy of absolute dosimetry measurements. In this paper, we demonstrate the calculation of mass-energy absorption coefficient ratios, relative to water, from measurements in plastic water and RW3 with an Elekta Synergy linear accelerator (6 and 10 MV photon beams) as well as Monte Carlo modeling in BEAMnrc and DOSXYZnrc. From this, the solid-phantom-to-water correction factor was determined for plastic water and RW3. PMID:21960410
NASA Astrophysics Data System (ADS)
Salazar, Agustín; Fuente, Raquel; Apiñaniz, Estibaliz; Mendioroz, Arantza; Celorrio, R.
2011-08-01
The aim of this work is to analyze the ability of modulated photothermal radiometry to retrieve the thermal diffusivity and the optical absorption coefficient of layered materials simultaneously. First, we extend the thermal quadrupole method to calculate the surface temperature of semitransparent multilayered materials. Then, this matrix method is used to evaluate the influence of heat losses by convection and radiation, the influence of the use of thin paint layers on the accuracy of thermal diffusivity measurements, and the effect of lateral heat diffusion due to the use of Gaussian laser beams. Finally, we apply the quadrupole method to retrieve (a) the thermal contact resistance in glass stacks and (b) the thermal diffusivity and optical absorption coefficient depth profiles in heterogeneous materials with continuously varying physical properties, as is the case of functionally graded materials and partially cured dental resins.
Measurement and calculation of the sound absorption coefficient of pine wood charcoal
NASA Astrophysics Data System (ADS)
Suh, Jae Gap; Baik, Kyung min; Kim, Yong Tae; Jung, Sung Soo
2013-10-01
Although charcoal has been widely utilized for physical therapy and as a deodorant, water purifier, etc. due to its porous features, research on its role as a sound-absorbing material is rarely found. Thus, the sound absorption coefficients of pine wood charcoal were measured using an impedance tube and were compared with the theoretical predictions in the frequency range of 500˜ 5000 Hz. The theory developed in the current study only considers the lowest possible mode propagating along the air channels of the charcoal and shows good agreements with the measurements. As the frequency is increased, the sound absorption coefficients of pine wood charcoals also increase, but are lower than those of other commonly-used sound-absorbing materials.
NASA Astrophysics Data System (ADS)
Wichmann, Janine; Janssen, Nicole A. H.; van der Zee, Saskia; Brunekreef, Bert
Population studies indicate that study participants living near major roads are more prone to chronic respiratory symptoms, lung function decrements and hospital admissions for asthma. The majority of the studies used proxy measures, such as distance to major roads or traffic intensity in the surroundings of the home. Few studies have communicated findings of concurrently performed measurements of outdoor, indoor and personal air pollution in urban streets with high- and low-traffic density. Measuring light absorption or reflectance of particulate matter (PM) collected on filters is an alternative method to determine elemental carbon, a marker for particles produced by incomplete combustion, compared to expensive and destructive analytical methods. This study sets out to test the null hypothesis that there is no difference in personal and indoor filter absorption coefficients for participants living along busy and quiet roads in Amsterdam. In one study we measured personal and indoor absorption coefficients in a sample of adults (50-70 years) and, in another study, the indoor levels in a population of adults (50-70 years) and school children (10-12 years). In the first study, the ratios of personal and indoor absorption coefficients in homes along busy roads compared with homes on quiet streets were significantly higher by 29% for personal measurements ( n=16 days, p<0.001), and by 19% for indoor measurements ( n=20, p<0.001), while in the second study, the ratio for the indoor measurements was higher by 26% ( n=25 days, p<0.05). Exposure differences between homes along busy compared to homes along quiet streets remained and significant after adjustment for potential indoor sources (such as cooking and use of unvented heating appliances). This study therefore provides tentative support for the use of the type of road as proxy measure for indoor and personal absorption coefficient measurements in epidemiological studies due to the limitations of the study.
Absorption coefficient at 10.6 microm in CdTe modulator crystals.
Tucker, A W; Birnbaum, M; Montes, H; Fincher, C L
1982-08-15
The bulk and surface absorption coefficients of CdTe modulator crystals at 10.6 microm were compared with those of single-crystal KC1 and NaCl which served to calibrate the laser calorimeter. High-resistivity (>10(7) ohm/cm) CdTe crystals exhibited a bulk absorption coefficient of 0.0014 cm(-1). PMID:20396150
NASA Technical Reports Server (NTRS)
Molina, L. T.; Grant, W. B.
1984-01-01
The absorption spectra of three hydrazines and four of their air-oxidation products were measured in the 9-12-micron spectral region with a Fourier transform infrared (FTIR) spectrometer with a 0.05-kayser resolution to determine absorption coefficients at CO2 and tunable diode laser wavelengths. The measurements agreed well with published CO2 laser determinations for many of the absorption coefficients, except where the published values are thought to be in error. The coefficients were then used to estimate the sensitivity for remote detection of these gases using CO2 and tunable diode lasers in long-path differential absorption measurements.
Measurement of the absorption coefficient of acoustical materials using the sound intensity method
NASA Technical Reports Server (NTRS)
Atwal, Mahabir S.; Crocker, Malcolm J.
1987-01-01
In this study the possibility of using the two-microphone sound intensity technique to measure the normal incidence and the random incidence sound absorption coefficient was investigated. The normal incidence absorption coefficient was determined by measuring the intensity incidence on the sample and the intensity reflected by the sample placed in an anechoic chamber. The random incidence absorption coefficient was determined by measuring the intensity incident on the sample and the intensity reflected by the sample placed in a reverberation chamber. Absorption coefficient results obtained by the sound intensity technique were compared with standard techniques, namely the reverberation chamber and the standing wave tube. The major advantages of using the sound intensity technique are that it permits 'in situ' measurements and the absorption coefficient for a large range of frequencies can be obtained from a single measurement.
Measurement of the absorption coefficient using the sound-intensity technique
NASA Technical Reports Server (NTRS)
Atwal, M.; Bernhard, R.
1984-01-01
The possibility of using the sound intensity technique to measure the absorption coefficient of a material is investigated. This technique measures the absorption coefficient by measuring the intensity incident on the sample and the net intensity reflected by the sample. Results obtained by this technique are compared with the standard techniques of measuring the change in the reverberation time and the standing wave ratio in a tube, thereby, calculating the random incident and the normal incident adsorption coefficient.
Bulk viscosity coefficients due to phonons in superfluid neutron stars
Manuel, Cristina; Tolos, Laura; Tarrús, Jaume E-mail: tarrus@ecm.ub.edu
2013-07-01
We calculate the three bulk viscosity coefficients as arising from the collisions among phonons in superfluid neutron stars. We use effective field theory techniques to extract the allowed phonon collisional processes, written as a function of the equation of state of the system. The solution of the dynamical evolution of the phonon number density allows us to calculate the bulk viscosity coefficients as function of the phonon collisional rate and the phonon dispersion law, which depends on the neutron pairing gap. Our method of computation is rather general, and could be used for different superfluid systems, provided they share the same underlying symmetries. We find that the behavior with temperature of the bulk viscosity coefficients is dominated by the contributions coming from the collinear regime of the 2↔3 phonon processes. For typical star radial pulsation frequencies of ω ∼ 10{sup 4}s{sup −1}, we obtain that the bulk viscosity coefficients at densities n∼>4n{sub 0} are within 10% from its static value for T∼<10{sup 9} K and for the case of strong neutron superfluidity in the core with a maximum value of the {sup 3}P{sub 2} gap above 1 MeV, while, otherwise, the static solution is not a valid approximation to the bulk viscosity coefficients. Compared to previous results from Urca and modified Urca reactions, we conclude that at T ∼ 10{sup 9}K phonon collisions give the leading contribution to the bulk viscosities in the core of the neutron stars, except for n ∼ 2n{sub 0} when the opening of the Urca processes takes place.
NASA Technical Reports Server (NTRS)
Smith, Wm. Hayden; Conner, Charles P.; Baines, Kevin H.
1990-01-01
A novel laser intracavity photoacoustic spectroscopy method allowing high sample control accuracy due to the small sample volume required has been used to obtain absorption coefficients for the CH4 6190 A band as a function of temperature, from 290 to 100 K. The peak absorption coefficient is found to increase from 0.6 to 1.0/cm, and to be accompanied by significant band shape changes. When used to further constrain the Baines and Bergstrahl (1986) standard model of the Uranus atmosphere, the low-temperature data yield an excellent fit to the bandshape near the 6190 A band's minimum.
Smith, WM.H.; Conner, C.P.; Baines, K.H. JPL, Pasadena, CA )
1990-05-01
A novel laser intracavity photoacoustic spectroscopy method allowing high sample control accuracy due to the small sample volume required has been used to obtain absorption coefficients for the CH{sub 4} 6190 A band as a function of temperature, from 290 to 100 K. The peak absorption coefficient is found to increase from 0.6 to 1.0/cm, and to be accompanied by significant band shape changes. When used to further constrain the Baines and Bergstrahl (1986) standard model of the Uranus atmosphere, the low-temperature data yield an excellent fit to the bandshape near the 6190 A band's minimum. 18 refs.
NASA Astrophysics Data System (ADS)
Müller, T.; Schladitz, A.; Massling, A.; Kaaden, N.; Kandler, K.; Wiedensohler, A.
2009-02-01
ABSTRACT During the SAMUM-1 experiment, absorption coefficients and imaginary parts of refractive indices of mineral dust particles were investigated in southern Morocco. Main absorbing constituents of airborne samples were identified to be iron oxide and soot. Spectral absorption coefficients were measured using a spectral optical absorption photometer (SOAP) in the wavelength range from 300 to 800 nm with a resolution of 50 nm. A new method that accounts for a loading-dependent correction of fibre filter based absorption photometers, was developed. The imaginary part of the refractive index was determined using Mie calculations from 350 to 800 nm. The spectral absorption coefficient allowed a separation between dust and soot absorption. A correlation analysis showed that the dust absorption coefficient is correlated (R2 up to 0.55) with the particle number concentration for particle diameters larger than 0.5 μm, whereas the coefficient of determination R2 for smaller particles is below 0.1. Refractive indices were derived for both the total aerosol and a dust aerosol that was corrected for soot absorption. Average imaginary parts of refractive indices of the entire aerosol are 7.4 × 10-3, 3.4 × 10-3 and 2.0 × 10-3 at wavelengths of 450, 550 and 650 nm. After a correction for the soot absorption, imaginary parts of refractive indices are 5.1 × 10-3, 1.6 × 10-3 and 4.5 × 10-4.
NASA Technical Reports Server (NTRS)
Stallcop, J. R.
1974-01-01
The theory for calculating the absorption of laser radiation by hydrogen is outlined for the temperatures and pressures of common laboratory plasmas. Nonhydrogenic corrections for determining the absorption by helium are also included. The coefficients for the absorption of He-Ne laser radiation at the wavelengths of 0.633, 1.15, and 3.39 microns in a H plasma is presented for temperatures in the range from 10,000 to 40,000 K and electron number densities in the range from 10 to the 15th power to 10 to the 18th power per cu cm. The total absorption of a H-He plasma calculated from this theory is compared with the measured absorption. The theoretical composition of the H-He absorption is analyzed with respect to the significant absorption processes, inverse bremsstrahlung, photoionization, resonance excitation, and photodetachment.
Absorption Coefficient Imaging by Near-Field Scanning Optical Microscopy in Bacteria
NASA Astrophysics Data System (ADS)
de Paula, Ana M.; Chaves, Claudilene R.; Silva, Haroldo B.; Weber, Gerald
2003-06-01
We present a method for obtaining a position-dependent absorption coefficient from near-field scanning optical transmission microscopy. We show that the optical transmission intensity can be combined with the topography, resulting into an absorption coefficient that simplifies the analysis of different materials within a sample. The method is tested with the dye rhodamine 6G, and we show some analysis in biological samples such as bacteria Klebsiella pneumoniae and Pseudomonas aeruginosa . The calculated absorption coefficient images show important details of the bacteria, in particular for P. aeruginosa , in which membrane vesicles are clearly seen.
Binary TLBO algorithm assisted for designing plasmonic nano bi-pyramids-based absorption coefficient
NASA Astrophysics Data System (ADS)
Akhlaghi, Majid; Emami, Farzin; Nozhat, Najmeh
2014-07-01
A new efficient binary optimization method based on Teaching-Learning-Based Optimization (TLBO) algorithm is proposed to design an array of plasmonic nano bi-pyramids in order to achieve maximum absorption coefficient spectrum. In binary TLBO, a group of learners consisting of a matrix with binary entries controls the presence ('1') or the absence ('0') of nanoparticles in the array. Simulation results show that absorption coefficient strongly depends on the localized position of plasmonic nanoparticles. Non-periodic structures have more appropriate response in term of absorption coefficient. This approach is useful in optical applications such as solar cells and plasmonic nano antenna.
Absorption coefficients for water vapor at 193 nm from 300 to 1073 K
NASA Technical Reports Server (NTRS)
Kessler, W. J.; Carleton, K. L.; Marinelli, W. J.
1993-01-01
Measurements of the water absorption coefficient at 193 nm from 300 to 1073 K are reported. The measurements were made using broadband VUV radiation and a monochromator-based detection system. The water vapor was generated by a saturator and metered into a flowing, 99 cm absorption cell via a water vapor mass flow meter. The 193 nm absorption coefficient measurements are compared to room temperature and high temperature shock tube measurements with good agreement. The absorption can be parameterized by a nu3 vibrational mode reaction coordinate and the thermal population of the nu3 mode.
NASA Astrophysics Data System (ADS)
Wex, Heike; Neusüß, Christian; Wendisch, Manfred; Stratmann, Frank; Koziar, Christian; Keil, Andreas; Wiedensohler, Alfred; Ebert, Martin
2002-11-01
Comparisons between measured and calculated aerosol scattering, backscattering, and absorption coefficients were made based on in situ, ground-based measurements during the Melpitz INTensive (MINT) and Lindenberg Aerosol Characterization Experiment 1998 (LACE 98) field studies. Furthermore, airborne measurements made with the same type of instruments are reviewed and compared with the ground-based measurements. Agreement between measured and calculated values is on the order of ±20% for scattering and backscattering coefficients. A sensitivity analysis showed a large influence on the calculated particle scattering and backscattering coefficients resulting from sizing uncertainties in the measured number size distributions. Measured absorption coefficients were significantly smaller than the corresponding calculated values. The largest uncertainty for the calculated absorption coefficients resulted from the size-dependent fraction of elemental carbon (EC) of the aerosol. A correction for the measured fractions of EC could significantly improve the agreement between measured and calculated absorption coefficients. The overall uncertainty of the calculated values was investigated with a Monte Carlo method by simultaneously and randomly varying the input parameters of the calculations, where the variation of each parameter was bounded by its uncertainty. The measurements were mostly found to be within the range of uncertainties of the calculations, with uncertainties for the calculated scattering and backscattering coefficients of about ±20% and for the absorption coefficients of about ±30%. Thus, to increase the accuracy of calculated scattering, backscattering, and absorption coefficients, it is crucial to further reduce the error in particle number size distribution measurement techniques. In addition, further improvement of the techniques for measuring absorption coefficients and further investigation of the measurement of the fraction of EC of the aerosol is
Moore, Travis J; Jones, Matthew R
2015-02-20
Knowledge of the spectral absorption coefficient of fused silica optical fibers is important in modeling heat transfer in the processes and applications in which these fibers are used. An experimental method used to measure the spectral absorption coefficient of optical fibers is presented. Radiative energy from a blackbody radiator set at different temperatures is directed through the optical fibers and into an FTIR spectrometer. Spectral instrument response functions are calculated for different fiber lengths. The ratios of the slopes of the instrument response functions for the different lengths of fibers are used to solve for the spectral absorption coefficient of the fibers. The spectral absorption coefficient of low OH pure fused silica optical fibers is measured between the wavelengths 1.5 and 2.5 μm. PMID:25968202
A method for determination mass absorption coefficient of gamma rays by Compton scattering.
El Abd, A
2014-12-01
A method was proposed for determination mass absorption coefficient of gamma rays for compounds, alloys and mixtures. It is based on simulating interaction processes of gamma rays with target elements having atomic numbers from Z=1 to Z=92 using the MCSHAPE software. Intensities of Compton scattered gamma rays at saturation thicknesses and at a scattering angle of 90° were calculated for incident gamma rays of different energies. The obtained results showed that the intensity of Compton scattered gamma rays at saturations and mass absorption coefficients can be described by mathematical formulas. These were used to determine mass absorption coefficients for compound, alloys and mixtures with the knowledge of their Compton scattered intensities. The method was tested by calculating mass absorption coefficients for some compounds, alloys and mixtures. There is a good agreement between obtained results and calculated ones using WinXom software. The advantages and limitations of the method were discussed. PMID:25241360
NASA Technical Reports Server (NTRS)
Billman, K. W.; Rowley, P. D.; Stallcop, J. R.; Presley, L.
1974-01-01
The absorption coefficients of 0.633-, 1.15-, and 3.39-micron laser radiation for a homogeneous H-He plasma have been measured in the temperature range from 12.2 to 21.7 (x 1000 K) and in the electron number density range 0.45 to 6.5 (x 10 to the 17th power per cu cm). Good agreement is found between the experimentally determined total absorption for each of the wavelengths and that calculated from theory. Furthermore, because the 3.39-micron absorption is dominated by inverse bremsstrahlung, while the 0.633-micron absorption is dominated by photoionization and resonance absorption, the experiment indicates a correct assessment by the theory of these individual absorption mechanisms.
NASA Astrophysics Data System (ADS)
Markushev, D. D.; Ordonez-Miranda, J.; Rabasović, M. D.; Galović, S.; Todorović, D. M.; Bialkowski, S. E.
2015-06-01
The open-cell photoacoustic signal measured in the transmission configuration for aluminum thin plates with thicknesses of 280 μm, 197 μm, and 112 μm is experimentally and theoretically analyzed, in the 20 Hz-7 kHz modulation frequency range. It is shown that the observed differences between the predictions of the standard thermoelastic model and the experiment data of both the amplitude and phase of the photoacoustic signal can be overcome by considering the aluminum samples coated with a thin layer of black paint as volume-absorber materials. This new approach provides a quite good agreement with the obtained experimental data, in the whole frequency range, and yields an effective absorption coefficient of (16 ± 2) mm-1, for a 280 μm-thick sample. The introduction of the finite absorption coefficient led to the correct ratio between the thermal diffusion and thermoelastic components of the photoacoustic signal. Furthermore, it is found that the "volume-absorber" approach accurately describes the behavior of the amplitude, but not that of the phase recorded for a 112 μm-thick sample, due to its relatively strong thermoelastic bending, which is not considered by this theory. Within the approximation of the small bending, the proposed "volume-absorber" model provides a reliable description of the photoacoustic signal for Al samples thicker than 112 μm, and extends the applicability of the classical "opaque" approach.
Hoge, F E; Wright, C W; Lyon, P E; Swift, R N; Yungel, J K
1999-12-20
Oceanic radiance model inversion methods are used to develop a comprehensive algorithm for retrieval of the absorption coefficients of phycourobilin (PUB) pigment, type I phycoerythrobilin (PEB) pigment rich in PUB, and type II PEB deficient in PUB pigment (together with the usual "big three" inherent optical properties: the total backscattering coefficient and the absorption coefficients of chromophoric dissolved organic matter (CDOM)-detritus and phytoplankton). This fully modeled inversion algorithm is then simplified to yield a hybrid modeled-unmodeled inversion algorithm in which the phycoerythrin (PE) absorption coefficient is retrieved as unmodeled 488-nm absorption (which exceeds the modeled phytoplankton and the CDOM-detritus absorption coefficients). Each algorithm was applied to water-leaving radiances, but only hybrid modeled-unmodeled inversions yielded viable retrievals of the PE absorption coefficient. Validation of the PE absorption coefficient retrieval was achieved by relative comparison with airborne laser-induced PEB fluorescence. The modeled-unmodeled retrieval of four inherent optical properties by direct matrix inversion is rapid and well conditioned, but the accuracy is strongly limited by the accuracy of the three principal inherent optical property models across all four spectral bands. Several research areas are identified to enhance the radiance-model-based retrievals: (a) improved PEB and PUB absorption coefficient models, (b) PE spectral shifts induced by PUB chromophore substitution at chromophore binding sites, (c) specific absorption-sensitive phytoplankton absorption modeling, (d) total constituent backscattering modeling, (e) unmodeled carotinoid and phycocyanin absorption that are not now accounted for in the chlorophyll-dominated phytoplankton absorption coefficient model, and (f) iterative inversion techniques to solve for six constituents with only five radiances. Although considerable progress has been made toward the
NASA Astrophysics Data System (ADS)
Hoge, Frank E.; Wright, C. Wayne; Lyon, Paul E.; Swift, Robert N.; Yungel, James K.
1999-12-01
Oceanic radiance model inversion methods are used to develop a comprehensive algorithm for retrieval of the absorption coefficients of phycourobilin (PUB) pigment, type I phycoerythrobilin (PEB) pigment rich in PUB, and type II PEB deficient in PUB pigment (together with the usual big three inherent optical properties: the total backscattering coefficient and the absorption coefficients of chromophoric dissolved organic matter (CDOM) detritus and phytoplankton). This fully modeled inversion algorithm is then simplified to yield a hybrid modeled unmodeled inversion algorithm in which the phycoerythrin (PE) absorption coefficient is retrieved as unmodeled 488-nm absorption (which exceeds the modeled phytoplankton and the CDOM detritus absorption coefficients). Each algorithm was applied to water-leaving radiances, but only hybrid modeled unmodeled inversions yielded viable retrievals of the PE absorption coefficient. Validation of the PE absorption coefficient retrieval was achieved by relative comparison with airborne laser-induced PEB fluorescence. The modeled unmodeled retrieval of four inherent optical properties by direct matrix inversion is rapid and well conditioned, but the accuracy is strongly limited by the accuracy of the three principal inherent optical property models across all four spectral bands. Several research areas are identified to enhance the radiance-model-based retrievals: (a) improved PEB and PUB absorption coefficient models, (b) PE spectral shifts induced by PUB chromophore substitution at chromophore binding sites, (c) specific absorption-sensitive phytoplankton absorption modeling, (d) total constituent backscattering modeling, (e) unmodeled carotinoid and phycocyanin absorption that are not now accounted for in the chlorophyll-dominated phytoplankton absorption coefficient model, and (f) iterative inversion techniques to solve for six constituents with only five radiances. Although considerable progress has been made toward the satellite
NASA Astrophysics Data System (ADS)
Hirasawa, T.; Ishihara, M.; Tsujita, K.; Hirota, K.; Irisawa, K.; Kitagaki, M.; Fujita, M.; Kikuchi, M.
2012-02-01
In photo-acoustic (PA) imaging, valuable medical applications based on optical absorption spectrum such as contrast agent imaging and blood oxygen saturation measurement have been investigated. In these applications, there is an essential requirement to determine optical absorption coefficients accurately. In present, PA signal intensities have been commonly used to determine optical absorption coefficients. This method achieves practical accuracy by combining with radiative transfer analysis. However, time consumption of radiative transfer analysis and effects of signal generation efficiencies were problems of this method. In this research, we propose a new method to determine optical absorption coefficients using continuous wavelet transform (CWT). We used CWT to estimate instantaneous frequencies of PA signals which reflects optical absorption distribution. We validated the effectiveness of CWT in determination of optical absorption coefficients through an experiment. In the experiment, planar shaped samples were illuminated to generate PA signal. The PA signal was measured by our fabricated PA probe in which an optical fiber and a ring shaped P(VDFTrFE) ultrasound sensor were coaxially aligned. Optical properties of samples were adjusted by changing the concentration of dye solution. Tunable Ti:Sapphire laser (690 - 1000 nm) was used as illumination source. As a result, we confirmed strong correlation between optical absorption coefficients of samples and the instantaneous frequency of PA signal obtained by CWT. Advantages of this method were less interference of light transfer and signal generation efficiency.
Jacques, S L; McAuliffe, D J
1991-06-01
The explosive vaporization of melanosomes in situ in skin during pulsed laser irradiation (pulse duration less than 1 microsecond) is observed as a visible whitening of the superficial epidermal layer due to stratum corneum disruption. In this study, the ruby laser (694 nm) was used to determine the threshold radiant exposure, H0 (J/cm2), required to elicit whitening for in vitro black (Negroid) human skin samples which were pre-equilibrated at an initial temperature, Ti, of 0, 20, or 50 degrees C. A plot of H0 vs Ti yields a straight line whose x-intercept indicates the threshold temperature of explosive vaporization to be 112 +/- 7 degrees C (SD, N = 3). The slope, delta H0/delta Ti, specifies the internal absorption coefficient, mua, within the melanosome: mua = -rho C/(slope(1 + 7.1 Rd)), where rho C is the product of density and specific heat, and Rd is the total diffuse reflectance from the skin. A summary of the absorption spectrum (mua) for the melanosome interior (351-1064 nm) is presented based on H0 data from this study and the literature. The in vivo absorption spectrum (380-820 nm) for human epidermal melanin was measured by an optical fiber spectrophotometer and is compared with the melanosome spectrum. PMID:1886936
De Roo, Jonathan; Ibáñez, Maria; Geiregat, Pieter; Nedelcu, Georgian; Walravens, Willem; Maes, Jorick; Martins, Jose C; Van Driessche, Isabel; Kovalenko, Maksym V; Hens, Zeger
2016-02-23
Lead halide perovskite materials have attracted significant attention in the context of photovoltaics and other optoelectronic applications, and recently, research efforts have been directed to nanostructured lead halide perovskites. Collodial nanocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit bright photoluminescence, with emission tunable over the entire visible spectral region. However, previous studies on CsPbX3 NCs did not address key aspects of their chemistry and photophysics such as surface chemistry and quantitative light absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface chemistry. In addition, the intrinsic absorption coefficient was determined experimentally by combining elemental analysis with accurate optical absorption measurements. (1)H solution nuclear magnetic resonance spectroscopy was used to characterize sample purity, elucidate the surface chemistry, and evaluate the influence of purification methods on the surface composition. We find that ligand binding to the NC surface is highly dynamic, and therefore, ligands are easily lost during the isolation and purification procedures. However, when a small amount of both oleic acid and oleylamine is added, the NCs can be purified, maintaining optical, colloidal, and material integrity. In addition, we find that a high amine content in the ligand shell increases the quantum yield due to the improved binding of the carboxylic acid. PMID:26786064
Experiment to Determine the Absorption Coefficient of Gamma Rays as a Function of Energy.
ERIC Educational Resources Information Center
Ouseph, P. J.; And Others
1982-01-01
Simpler than x-ray diffractometer experiments, the experiment described illustrates certain concepts regarding the interaction of electromagnetic rays with matter such as the exponential decrease in the intensity with absorber thickness, variation of the coefficient of absorption with energy, and the effect of the K-absorption edge on the…
ERIC Educational Resources Information Center
Cordon, Gabriela B.; Lagorio, M. Gabriela
2007-01-01
A biophysical-chemistry experiment, based on the reflectance spectroscopy for calculating the absorption and scattering coefficients of leaves is described. The results show that different plants species exhibit different values for both the coefficients because of their different pigment composition.
Hoche, S; Hussein, M A; Becker, T
2015-03-01
The accuracy of density, reflection coefficient, and acoustic impedance determination via multiple reflection method was validated experimentally. The ternary system water-maltose-ethanol was used to execute a systematic, temperature dependent study over a wide range of densities and viscosities aiming an application as inline sensor in beverage industries. The validation results of the presented method and setup show root mean square errors of: 1.201E-3 g cm(-3) (±0.12%) density, 0.515E-3 (0.15%) reflection coefficient and 1.851E+3 kg s(-1) m(-2) (0.12%) specific acoustic impedance. The results of the diffraction corrected absorption showed an average standard deviation of only 0.12%. It was found that the absorption change shows a good correlation to concentration variations and may be useful for laboratory analysis of sufficiently pure liquids. The main part of the observed errors can be explained by the observed noise, temperature variation and the low signal resolution of 50 MHz. In particular, the poor signal-to-noise ratio of the second reflector echo was found to be a main accuracy limitation. Concerning the investigation of liquids the unstable properties of the reference material PMMA, due to hygroscopicity, were identified to be an additional, unpredictable source of uncertainty. While dimensional changes can be considered by adequate methodology, the impact of the time and temperature dependent water absorption on relevant reference properties like the buffer's sound velocity and density could not be considered and may explain part of the observed deviations. PMID:25465962
Tunable diode laser measurements of HO2NO2 absorption coefficients near 12.5 microns
NASA Technical Reports Server (NTRS)
May, R. D.; Molina, L. T.; Webster, C. R.
1988-01-01
A tunable diode laser spectrometer has been used to measure absorption coefficients of peroxynitric acid (HO2NO2) near the 803/cm Q branch. HO2NO2 concentrations in a low-pressure flowing gas mixture were determined from chemical titration procedures and UV absorption spectroscopy. The diode laser measured absorption coefficients, at a spectral resolution of better than 0.001/cm, are about 10 percent larger than previous Fourier transform infrared measurements made at a spectral resolution of 0.06/cm.
Hessler, J.P.; Ogren, P.J.
1992-08-31
A technique was developed for determining relative importance and correlation between reactions making up a complex kinetic system. This technique was used to investigate measurements of optical absorption cross sections and the correlation between cross sections and measured rate coefficients. It is concluded that (1) species, initial conditions, and temporal regions may be identified where cross sections may be measured without interference from the kinetic behavior of the observed species and (2) experiments designed to measure rate coefficients will always be correlated with the absorption cross section of the observed species. This correlation may reduce the accuracy of rate coefficient measurements.
Madelin, Guillaume; Grucker, Daniel; Franconi, Jean-Michel; Thiaudiere, Eric
2006-07-01
In this study, magnetic resonance imaging (MRI) is used to visualize acoustic streaming in liquids. A single-shot spin echo sequence (HASTE) with a saturation band perpendicular to the acoustic beam permits the acquisition of an instantaneous image of the flow due to the application of ultrasound. An average acoustic streaming velocity can be estimated from the MR images, from which the ultrasonic absorption coefficient and the bulk viscosity of different glycerol-water mixtures can be deduced. In the same way, this MRI method could be used to assess the acoustic field and time-average power of ultrasonic transducers in water (or other liquids with known physical properties), after calibration of a geometrical parameter that is dependent on the experimental setup. PMID:16650447
Measurements of Soot Mass Absorption Coefficients from 300 to 660 nm
NASA Astrophysics Data System (ADS)
Renbaum-Wolff, Lindsay; Fisher, Al; Helgestad, Taylor; Lambe, Andrew; Sedlacek, Arthur; Smith, Geoffrey; Cappa, Christopher; Davidovits, Paul; Onasch, Timothy; Freedman, Andrew
2016-04-01
Soot, a product of incomplete combustion, plays an important role in the earth's climate system through the absorption and scattering of solar radiation. In particular, the assumed mass absorption coefficient (MAC) of soot and its variation with wavelength presents a significant uncertainty in the calculation of radiative forcing in global climate change models. As part of the fourth Boston College/Aerodyne soot properties measurement campaign, we have measured the mass absorption coefficient of soot produced by an inverted methane diffusion flame over a spectral range of 300-660 nm using a variety of optical absorption techniques. Extinction and absorption were measured using a dual cavity ringdown photoacoustic spectrometer (CRD-PAS, UC Davis) at 405 nm and 532 nm. Scattering and extinction were measured using a CAPS PMssa single scattering albedo monitor (Aerodyne) at 630 nm; the absorption coefficient was determined by subtraction. In addition, the absorption coefficients in 8 wavelength bands from 300 to 660 nm were measured using a new broadband photoacoustic absorption monitor (UGA). Soot particle mass was quantified using a centrifugal particle mass analyzer (CPMA, Cambustion), mobility size with a scanning mobility particle sizer (SMPS, TSI) and soot concentration with a CPC (Brechtel). The contribution of doubly charged particles to the sample mass was determined using a Single Particle Soot Photometer (DMT). Over a mass range of 1-8 fg, corresponding to differential mobility diameters of ~150 nm to 550 nm, the value of the soot MAC proved to be independent of mass for all wavelengths. The wavelength dependence of the MAC was best fit to a power law with an Absorption Ångstrom Coefficient slightly greater than 1.
Wang, J.; Zhang, X. Yu, L.; Zhao, X.
2014-12-15
In tokamaks, fusion generated α particles may absorb lower hybrid (LH) wave energy, thus reducing the LH current drive efficiency. The absorption coefficient γ{sub α} of LH waves due to α particles changing with some typical parameters is calculated in this paper. Results show that γ{sub α} increases with the parallel refraction index n{sub ‖}, while decreases with the frequency of LH waves ω over a wide range. Higher background plasma temperature and toroidal magnetic field will increase the absorption. The absorption coefficient γ{sub α} increases with n{sub e} when n{sub e} ≤ 8 × 10{sup 19} m{sup −3}, while decreases with n{sub e} when n{sub e} becomes larger, and there is a peak value of γ{sub α} when n{sub e} ≈ 8 × 10{sup 19} m{sup −1} for the ITER-like scenario. The influence of spectral broadening in parametric decay instabilities on the absorption coefficient is evaluated. The value of γ{sub α} with n{sub ‖} being 2.5 is almost two times larger than that with n{sub ‖} being 2.0 and is even lager in the case of 2.9, which will obviously increase the absorption of the LH power by alpha particles.
Nonlinear absorption coefficient of pulsed laser deposited MgZnO thin film
Agrawal, Arpana Dar, Tanveer A.; Solanki, Ravi; Sen, Pratima; Phase, D. M.
2015-06-24
We report the imaginary part of 3{sup rd} order nonlinear susceptibility and the nonlinear absorption coefficient of Mg doped ZnO thin film using standard Z-scan technique. The origin of nonlinear absorption is attributed to the two photon absorption followed by the free carrier absorption because of the presence of oxygen vacancy defects. We have also confirmed the experimental results with the theoretical results obtained by considering the steady state response of a two level atom with the monochromatic field models.
Study of the absorption coefficient of alpha particles to lower hybrid waves in tokamak
Wang, Jianbing Zhang, Xianmei Yu, Limin Zhao, Xiang
2014-02-12
Part of the energy of the Lower Hybrid (LH) waves may be absorbed by the α particles via the so-called perpendicular landau damping mechanism, which depends on various parameters of fusion reactors and the LH waves. In this article, we calculate the absorption coefficient γ{sub α} of LH waves due to α particles. Results show that, the γ{sub α} increases with the parallel refraction index n{sub ∥} while deceases with increasing the frequency of LH waves ω{sub LH} over a wide range. Higher background plasma temperature and toroidal magnetic field will increase the absorption, and there is a peak value of γ{sub α} when n{sub e}≈8×10{sup 19}m{sup −3} for ITER-like scenario. The thermal corrections to the cold plasma dispersion relation will change the damping rate to a certain extent under some specific conditions. We have also evaluated the fraction of LH power absorbed by the alpha particles, η ≈ 0.47% and 4.1% for an LH frequency of 5 GHz and 3.7 GHz respectively for ITER-like scenario. This work gives the effective reference for the choice of parameters of future fusion reactors.
NASA Astrophysics Data System (ADS)
Liu, Qiang; Huang, Hong-Hua; Wang, Yao; Wang, Gui-Shi; Cao, Zhen-Song; Liu, Kun; Chen, Wei-Dong; Gao, Xiao-Ming
2014-06-01
The atmospheric aerosol absorption capacity is a critical parameter determining its direct and indirect effects on climate. Accurate measurement is highly desired for the study of the radiative budget of the Earth. A multi-wavelength (405 nm, 532 nm, 780 nm) aerosol absorption meter based on photoacoustic spectroscopy (PAS) invovling a single cylindrical acoustic resonator is developed for measuring the aerosol optical absorption coefficients (OACs). A sensitivity of 1.3 Mm-1 (at 532 nm) is demonstrated. The aerosol absorption meter is successfully tested through measuring the OACs of atmospheric nigrosin and ambient aerosols in the suburbs of Hefei city. The absorption cross section and absorption Ångström exponent (AAE) for ambient aerosol are determined for characterizing the component of the ambient aerosol.
Minority carrier diffusion lengths and absorption coefficients in silicon sheet material
NASA Technical Reports Server (NTRS)
Dumas, K. A.; Swimm, R. T.
1980-01-01
Most of the methods which have been developed for the measurement of the minority carrier diffusion length of silicon wafers require that the material have either a Schottky or an ohmic contact. The surface photovoltage (SPV) technique is an exception. The SPV technique could, therefore, become a valuable diagnostic tool in connection with current efforts to develop low-cost processes for the production of solar cells. The technique depends on a knowledge of the optical absorption coefficient. The considered investigation is concerned with a reevaluation of the absorption coefficient as a function of silicon processing. A comparison of absorption coefficient values showed these values to be relatively consistent from sample to sample, and independent of the sample growth method.
NASA Astrophysics Data System (ADS)
O'Brien, J. J.
2002-09-01
The absorption spectrum of methane has been recorded in the visible to near-IR region using the intracavity laser spectroscopy technique. Spectra are recorded at high spectral resolution for narrow overlapping intervals in the region for room and 77 K temperature methane samples. After spectra are deconvolved for the instrument function, absorption coefficients are derived. These will be presented (750-940 nm for room temperature methane; 850-920 nm for 77 K methane) and compared with results reported by other workers. Future work in this area also will be indicated. Support from NASA's Planetary Atmospheres Program (NAG5-6091 and a Major Equipment Grant) is gratefully acknowledged.
Measurement of nanofluids absorption coefficient by Moiré deflectometry technique
NASA Astrophysics Data System (ADS)
Madanipour, Khosro; Koohian, Ataollah; Shahrabi Farahani, Shahrzad
2015-05-01
Nanoparticles exhibit many unique and interesting optical properties which make them very useful in biomedical applications. In order to employ NPs for disease treatment, comprehensive knowledge of their important properties is crucial. One of these parameters is absorption coefficient. In this work, absorption coefficient of a nanofluid (Au nanoparticles in water) is measured by using Moiré deflectometry technique. Two laser beams are used: a comparatively high intensity laser beam as interacting beam and a low intensity as a probe beam. This method is fast, easy and nonscanning, also insensitive to vibrations.
NASA Astrophysics Data System (ADS)
Brochu, Frederic M.; Joseph, James; Tomaszewski, Michal R.; Bohndiek, Sarah E.
2016-03-01
Optoacoustic Tomography is a fast developing imaging modality, combining the high resolution and penetration depth of ultrasound detection with the high contrast available from optical absorption in tissue. The spectral profile of near infrared excitation light used in optoacoustic tomography instruments is modified by absorption and scattering as it propagates deep into biological tissue. The resulting images therefore provide only qualitative insight into the distribution of tissue chromophores. Knowledge of the spectral profile of excitation light across the mouse is needed for accurate determination of the absorption coefficient in vivo. Under the conditions of constant Grueneisen parameter and accurate knowledge of the light fluence, a linear relationship should exist between the initial optoacoustic pressure amplitude and the tissue absorption coefficient. Using data from a commercial optoacoustic tomography system, we implemented an iterative optimization based on the σ-Eddington approximation to the Radiative Transfer Equation to derive a light fluence map within a given object. We segmented the images based on the positions of phantom inclusions, or mouse organs, and used known scattering coefficients for initialization. Performing the fluence correction in simple phantoms allowed the expected linear relationship between recorded and independently measured absorption coefficients to be retrieved and spectral coloring to be compensated. For in vivo data, the correction resulted in an enhancement of signal intensities in deep tissues. This improved our ability to visualize organs at depth (> 5mm). Future work will aim to perform the optimization without data normalization and explore the need for methodology that enables routine implementation for in vivo imaging.
An analytic formula for heating due to ozone absorption
NASA Technical Reports Server (NTRS)
Lindzen, R. S.; Will, D. I.
1972-01-01
An attempt was made to devise a simple expression or formula to describe radiative heating in the atmosphere by ozone absorption. Such absorption occurs in the Hartley, Huggins, and Chappuis bands and is only slightly temperature and pressure dependent.
Effects of nanosilver on sound absorption coefficients in solid wood species.
Taghiyari, Hamid Reza; Esmailpour, Ayoub; Zolfaghari, Habib
2016-06-01
Sound absorption coefficients (ACs) were determined in five solid woods (poplar, beech, walnut, mulberry, and fir) in the longitudinal and tangential directions at four different frequencies of 800, 1000, 2000, and 4000 Hz. The length of the longitudinal and tangential specimens was 50-mm and 10-mm, respectively. Separate sets of specimens were impregnated with either nanosilver suspension or water. The size range of nanoparticles was 30-80 nm. Results showed that sound ACs were lower in longitudinal specimens because sound waves could penetrate the open ends of vessels more easily, being trapped and damped there. Impregnation with both nanosilver suspension and water resulted in a significant decrease in the sound ACs. The decrease in the ACs was due to the collapsing and accumulation of perforation plates and cell parts, blocking the way through which waves could pass through the vessels. This caused higher damping due to a phenomenon called vibration decay. Correlation between gas permeability versus sound AC is significantly dependant on the porous structure of individual specimens. PMID:27256895
Effects of combined scattering and absorption coefficients on laser speckle contrast imaging values
NASA Astrophysics Data System (ADS)
Khaksari, Kosar; Kirkpatrick, Sean J.
2015-03-01
Laser Speckle contrast imaging (LSCI) is a non-invasive or minimally invasive method for visualizing blood flow and perfusion in biological tissues. In LSCI the motion of scattering particles results in a reduction in global and regional speckle contrast. A variety of parameters can affect the calculated contrast values in LSCI techniques, including the optical properties of the fluid and surrounding tissue. In typical LSCI where the motion of blood is of interests, optical properties are influenced by hematocrit levels. In this work we considered the combined effects of both the scattering and absorption coefficients on LSCI measurements on a flow phantom. Fluid phantoms consisting of various concentrations of neutrally buoyant ~10 micron microspheres and India ink mixed with DI water were formulated to mimic the optical properties of whole blood with various levels of hematocrit. In these flow studies, it was found that an increase in μa and/or μs led to a decrease in contrast values when all other experimental parameters were held constant. The observed reduction in contrast due to optical property changes could easily be confused with a contrast reduction due to increased flow velocity. These results suggest that optical properties need to be considered when using LSCI to make flow estimates.
NASA Astrophysics Data System (ADS)
Ladhaf, Bibifatima M.; Pawar, Pravina P.
2015-04-01
We measured here the mass attenuation coefficients (μ/ρ) of carbohydrates, Esculine (C15H16O9), Sucrose (C12H22O11), Sorbitol (C6H14O6), D-Galactose (C6H12O6), Inositol (C6H12O6), D-Xylose (C5H10O5) covering the energy range from 122 keV up to 1330 keV photon energies by using gamma ray transmission method in a narrow beam good geometry set-up. The gamma-rays were detected using NaI(Tl) scintillation detection system with a resolution of 8.2% at 662 keV. The attenuation coefficient data were then used to obtain the total attenuation cross-section (σtot), molar extinction coefficients (ε), mass-energy absorption coefficients (μen/ρ) and effective (average) atomic energy-absorption cross section (σa,en) of the compounds. These values are found to be in good agreement with the theoretical values calculated based on XCOM data.
The average ion model. Computation of the absorption and emission coefficients in hot plasmas
NASA Astrophysics Data System (ADS)
Gauthier, Jean-Claude; Geindre, Jean-Paul
1988-06-01
A program was developed to evaluate the emission and absorption plasma coefficient variations as a function of the density, temperature and the atomic number of the specimen. The treatment is simplified because of the reduced number of characteristic frequencies which are necessary for the hydrodynamic code. The approach is less efficient when applied to high Z atoms.
NASA Astrophysics Data System (ADS)
Wu, J.; Hong, H.; Shang, S.; Dai, M.; Lee, Z.
2007-05-01
We examined the temporal and spatial variabilities of phytoplankton absorption coefficients (αphλ)) and their relationships with physical processes in the northern South China Sea from two cruise surveys during spring (May 2001) and late autumn (November 2002). A large river plume induced by heavy precipitation in May stimulated a phytoplankton bloom on the inner shelf, causing significant changes in the surface water in αph values and B/R ratios (αph(440)/αph(675)). This was consistent with the observed one order of magnitude elevation of chlorophyll α and a shift from a pico/nano dominated phytoplankton community to one dominated by micro-algae. At the seasonal level, enhanced vertical mixing due to strengthened northeast monsoon in November has been observed to result in higher surface αph(675) (0.002-0.006 m-1 higher) and less pronounced subsurface maximum on the outer shelf/slope in November as compared that in May. Measurements of αph and B/R ratios from three transects in November revealed a highest surface αph(675) immediately outside the mouth of the Pearl River Estuary, whereas lower αph(675) and higher B/R ratios were featured in the outer shelf/slope waters, demonstrating the respective influence of the Pearl River plume and the oligotrophic nature of South China Sea water. The difference in spectral shapes of phytoplankton absorption (measured by B/R ratios and bathochromic shifts) on these three transects infers that picoprocaryotes are the major component of the phytoplankton community on the outer shelf/slope rather than on the inner shelf. In addition, a regional tuning of the phytoplankton absorption spectral model (Carder et al., 1999) demonstrated a greater spatial variation than seasonal variation in the lead parameter a0(λ). These results suggest that phytoplankton absorption properties in a coastal region such as the northern South China Sea are complex and region-based parameterization is mandatory in order for remote sensing
NASA Astrophysics Data System (ADS)
Utry, N.; Ajtai, T.; Pintér, M.; Tombácz, E.; Illés, E.; Bozóki, Z.; Szabó, G.
2014-09-01
Mass specific optical absorption coefficients of various mineral dust components including silicate clays (illite, kaolin and bentonite), oxides (quartz, hematite and rutile), and carbonate (limestone) were determined at wavelengths of 1064, 532, 355 and 266 nm. These values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA) instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. These results are expected to have considerable importance in global radiative forcing calculations. They can also serve as reference for validating calculated wavelength dependent imaginary parts (κ) of complex refractive indices which up to now have been typically deduced from bulk phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk phase measurements.
Temperature- and pressure-dependent absorption coefficients for CO2 and O2 at 193 nm
NASA Astrophysics Data System (ADS)
Hartinger, K. T.; Nord, S.; Monkhouse, P. B.
Absorption of laser radiation at 193 nm by CO2 and O2 was studied at a series of different temperatures up to 1273 K and pressures up to 1 bar. The spectrum for CO2 was found to be broadband, so that absorption could be fitted to a Beer-Lambert law. On the other hand, the corresponding O2 spectrum is strongly structured and parameterisation requires a more complex relation, depending on both temperature and the product (pressure × absorption path length). In this context, the influence of spectral structure on the resulting spectrally integrated absorption coefficients is discussed. Using the fitting parameters obtained, effective transmissions at 193 nm can be calculated for a wide range of experimental conditions. As an illustration of the practical application of these data, the calculation of effective transmission for a typical industrial flue gas is described.
Determination of the diffusion length and the optical self absorption coefficient using EBIC model
NASA Astrophysics Data System (ADS)
Guermazi, S.; Guermazi, H.; Mlik, Y.; El Jani, B.; Grill, C.; Toureille, A.
2001-10-01
We have developed a model of calculation of the induced current due to an electron beam. The expression for the electron beam induced current (EBIC) with an extended generation profile is obtained via the resolution of a steady state continuity equation by the Green function method, satisfying appropriated boundary conditions to the physical model. The generation profile takes into account the lateral diffusion, the effect of defects, dislocations and recombination surfaces besides the number of absorbed electrons and that of diffuse electrons as a function of the depth. In the case of a Schottky diode Au/GaAs obtained by metalorganic vapour phase epitaxy (MOVPE) method, the theoretical induced current profile is compared to the experimental one and to theoretical profiles whose analytical expressions are given by van Roosbroeck and Bresse. The minority carriers diffusion length L_n = 2 μm and the optical self-absorption coefficient a=0.034 μm^{-1} can be deduced from the experimental current profile, measured by scanning electron microscopy. The theoretical curve, obtained from the proposed model is in a good agreement with the experimental one for surface recombination velocity 10^6 cm s^{-1} except for distances far from the depletion layer (x_0 > 2.3 μm) where the photocurrent produced by the multiple process of the reabsorbed recombination radiation is preponderant. Our results are in agreement with those obtained by other experimental techniques on the same samples.
NASA Astrophysics Data System (ADS)
Brochu, Frederic M.; Joseph, James; Tomaszewski, Michal; Bohndiek, Sarah E.
2015-07-01
MultiSpectral Optoacoustic Tomography (MSOT) is a fast developing imaging modality, combining the high resolution and penetration depth of ultrasound with the excellent contrast from optical imaging of tissue. Absorption and scattering of the near infrared excitation light modulates the spectral profile of light as it propagates deep into biological tissue, meaning the images obtained provide only qualitative insight into the distribution of tissue chromophores. The goal of this work is to accurately recover the spectral profile of excitation light by modelling light fluence in the data reconstruction, to enable quantitative imaging. We worked with a commercial small animal MSOT scanner and developed our light fluence correction for its' cylindrical geometry. Optoacoustic image reconstruction pinpoints the sources of acoustic waves detected by the transducers and returns the initial pressure amplitude at these points. This pressure is the product of the dimensionless Grüneisen parameter, the absorption coefficient and the light fluence. Under the condition of constant Grüneisen parameter and well modelled light fluence, there is a linear relationship between the initial pressure amplitude measured in the optoacoustic image and the absorption coefficient. We were able to reproduce this linear relationship in different physical regions of an agarose gel phantom containing targets of known optical absorption coefficient, demonstrating that our light fluence model was working. We also demonstrate promising results of light fluence correction effects on in vivo data.
NASA Astrophysics Data System (ADS)
Goela, P.; Icely, J.; Cristina, S.; Newton, A.
2010-12-01
Variability of particulate absorption coefficients was studied off the south-west coast of Portugal, as part of a validation exercise for the Medium Resolution Image Spectrometer Sensor. Regular sampling campaigns occurred at three stations on a transect from inshore to offshore to compare fluctuations in these coefficients at the local scale. Transmittance-reflectance method with sodium hypochlorite bleaching was used to determine absorption coefficients for phytoplankton and non-algal particles. Photosynthetic pigment concentrations were determined by High Performance Liquid Chromatography. Results show that the absorption of light by particulate matter is almost totally dependent on the phytoplankton, with no significant contribution from non-algal particles, both in coastal and oceanic waters. Specific phytoplankton coefficients show significant fluctuations between seasons and stations, ranging from 0.012 to 0.038 at 678 nm. Particulate absorption is dominant over dissolved absorption. The variations in the coefficients of absorption are analysed as a function of species assemblages.
NASA Astrophysics Data System (ADS)
Yoshida, Kenichiro
2016-08-01
We derived the absorption coefficient ( μ a) and the reduced scattering coefficient ( μ s') using the edge-loss method (ELM) and the video reflectometry method (VRM), and compared the results. In a previous study, we developed the ELM to easily evaluate the lateral spread in the skin; the VRM is a conventional method. The ELM measures the translucency index, which is correlated with μ a and μ s'. To obtain a precise estimation of these parameters, we improved the treatment of a white standard and the surface reflection. For both skin phantoms and actual skin, the values for μ a and μ s' that we obtained using the ELM were similar to those obtained using the VRM, when μ a/ μ s' was less than or equal to 0.05 and the diffusion approximation was applicable. Under this condition, the spectral reflectivity is greater than 0.4. In this study, we considered wavelengths longer than 600 nm for Types III and IV of the Fitzpatrick scale. For skin, the repeatability errors of the parameters obtained with the ELM were smaller than those obtained with the VRM; this can be an advantage in field tests.
NASA Astrophysics Data System (ADS)
Yoshida, Kenichiro
2016-07-01
We derived the absorption coefficient (μ a) and the reduced scattering coefficient (μ s') using the edge-loss method (ELM) and the video reflectometry method (VRM), and compared the results. In a previous study, we developed the ELM to easily evaluate the lateral spread in the skin; the VRM is a conventional method. The ELM measures the translucency index, which is correlated with μ a and μ s'. To obtain a precise estimation of these parameters, we improved the treatment of a white standard and the surface reflection. For both skin phantoms and actual skin, the values for μ a and μ s' that we obtained using the ELM were similar to those obtained using the VRM, when μ a/μ s' was less than or equal to 0.05 and the diffusion approximation was applicable. Under this condition, the spectral reflectivity is greater than 0.4. In this study, we considered wavelengths longer than 600 nm for Types III and IV of the Fitzpatrick scale. For skin, the repeatability errors of the parameters obtained with the ELM were smaller than those obtained with the VRM; this can be an advantage in field tests.
A new photoacoustic method based on the modulation of the light induced absorption coefficient
NASA Astrophysics Data System (ADS)
Engel, S.; Wenisch, C.; Müller, F. A.; Gräf, S.
2016-04-01
The present study reports on a new photoacoustic (PA) measurement method that is suitable for the investigation of light induced absorption effects including e.g. excited state absorption. Contrary to the modulation of the radiation intensity used in conventional PA-methods, the key principle of this novel setup is based on the modulation of the induced absorption coefficient by light. For this purpose, a pump-probe setup with a pulsed pump laser beam and a continuous probe laser beam is utilized. In this regime, the potential influence of heat on the PA-signal is much smaller when compared to arrangements with pulsed probe beam and continuous pump beam. Beyond that, the negative effect of thermal lenses can be neglected. Thus, the measurement technique is well-suited for materials exhibiting a strong absorption at the pump wavelength. The quantitative analysis of the induced absorption coefficient was achieved by the calibration of the additional PA-signal caused by the continuous probe laser to the PA-signal resulting from the pulsed pump laser using thallium bromoiodide (KRS-5) as sample material.
NASA Astrophysics Data System (ADS)
Chrobak, Ł.; Maliński, M.; Pawlak, M.
2014-11-01
This paper presents a method of the measurement of the optical absorption coefficient of the Ar8+ ions implanted layers in the p-type silicon substrate. The absorption coefficient is calculated using a value of the attenuation of amplitudes of a photothermal radiometry (PTR) and/or a modulation free carrier absorption (MFCA) signals and the implanted layer thickness calculated by means of the TRIM program. The proposed method can be used to indicate the amorphization of the ions implanted layers.
Absorption coefficients of GeSn extracted from PIN photodetector response
NASA Astrophysics Data System (ADS)
Ye, Kaiheng; Zhang, Wogong; Oehme, Michael; Schmid, Marc; Gollhofer, Martin; Kostecki, Konrad; Widmann, Daniel; Körner, Roman; Kasper, Erich; Schulze, Jörg
2015-08-01
In this paper the optical absorption of the GeSn PIN photodetector was investigated. The vertical GeSn PIN photodetectors were fabricated by molecular beam epitaxy (MBE) and dry etching. By means of current density-voltage (J-V) and capacity-voltage (C-V) measurements the photodetector device was characterized. The absorption coefficients of GeSn material were finally extracted from the optical response of PIN structure. With further direct bandgap analysis the influences of device structure was proved negligible.
Heat/Mass Transfer Coefficients of an Absorber in Absorption Refrigeration System
NASA Astrophysics Data System (ADS)
Fujita, Isamu; Hihara, Eiji
This paper presents a new method to calculate heat and mass transfer coefficients applicable to the vertical tube or plate type absorber of absorption refrigeration system. Conventional method for calculating the coefficients using logarithmic mean temperature/ concentration differences is criticized for its lacking in the theoretical rationality and usually giving untrue values except some limited situations such that temperature of the solution can be assumed to change linearly along the heat transfer surface. The newly introduced method, which is intended to overcome this difficulty, is verified by numerical simulation and is accompanied by an example applied to the experimental results.
Ren, Yatao; Qi, Hong; Zhao, Fangzhou; Ruan, Liming; Tan, Heping
2016-01-01
A secondary optimization technique was proposed to estimate the temperature-dependent thermal conductivity and absorption coefficient. In the proposed method, the stochastic particle swarm optimization was applied to solve the inverse problem. The coupled radiation and conduction problem was solved in a 1D absorbing, emitting, but non-scattering slab exposed to a pulse laser. It is found that in the coupled radiation and conduction problem, the temperature response is highly sensitive to conductivity but slightly sensitive to the optical properties. On the contrary, the radiative intensity is highly sensitive to optical properties but slightly sensitive to thermal conductivity. Therefore, the optical and thermal signals should both be considered in the inverse problem to estimate the temperature-dependent properties of the transparent media. On this basis, the temperature-dependent thermal conductivity and absorption coefficient were both estimated accurately by measuring the time-dependent temperature, and radiative response at the boundary of the slab. PMID:26912418
Majaron, Boris; Milanic, Matija
2008-01-01
Although photothermal radiometric (PTR) measurements commonly employ broad-band signal acquisition to increase the signal-to-noise ratio, all reported studies apply a fixed infrared (IR) absorption coefficient to simplify the involved signal analysis. In samples with large spectral variation of micro(lambda) in mid-IR, which includes most biological tissues, the selection of the effective IR absorption coefficient value (micro(eff)) can strongly affect the accuracy of the result. We present a novel analytical approach for the determination of optimal micro(eff) from spectral properties of the sample and radiation detector. In extensive numerical simulations of pulsed PTR temperature profiling in human skin using three common IR radiation detectors and several acquisition spectral bands, we demonstrate that our approach produces viable values micro(eff). Two previously used analytical estimations perform much worse in the same comparison. PMID:18182701
NASA Astrophysics Data System (ADS)
Ren, Yatao; Qi, Hong; Zhao, Fangzhou; Ruan, Liming; Tan, Heping
2016-02-01
A secondary optimization technique was proposed to estimate the temperature-dependent thermal conductivity and absorption coefficient. In the proposed method, the stochastic particle swarm optimization was applied to solve the inverse problem. The coupled radiation and conduction problem was solved in a 1D absorbing, emitting, but non-scattering slab exposed to a pulse laser. It is found that in the coupled radiation and conduction problem, the temperature response is highly sensitive to conductivity but slightly sensitive to the optical properties. On the contrary, the radiative intensity is highly sensitive to optical properties but slightly sensitive to thermal conductivity. Therefore, the optical and thermal signals should both be considered in the inverse problem to estimate the temperature-dependent properties of the transparent media. On this basis, the temperature-dependent thermal conductivity and absorption coefficient were both estimated accurately by measuring the time-dependent temperature, and radiative response at the boundary of the slab.
Ren, Yatao; Qi, Hong; Zhao, Fangzhou; Ruan, Liming; Tan, Heping
2016-01-01
A secondary optimization technique was proposed to estimate the temperature-dependent thermal conductivity and absorption coefficient. In the proposed method, the stochastic particle swarm optimization was applied to solve the inverse problem. The coupled radiation and conduction problem was solved in a 1D absorbing, emitting, but non-scattering slab exposed to a pulse laser. It is found that in the coupled radiation and conduction problem, the temperature response is highly sensitive to conductivity but slightly sensitive to the optical properties. On the contrary, the radiative intensity is highly sensitive to optical properties but slightly sensitive to thermal conductivity. Therefore, the optical and thermal signals should both be considered in the inverse problem to estimate the temperature-dependent properties of the transparent media. On this basis, the temperature-dependent thermal conductivity and absorption coefficient were both estimated accurately by measuring the time-dependent temperature, and radiative response at the boundary of the slab. PMID:26912418
Sadler, M.; Charlson, R.J.; Rosen, H.; Novakov, T.
1980-07-01
The absorption coefficients determined by the integrating plate method and the laser transmission method are found to be comparable and highly correlated. Furthermore, a high correlation is found between these absorption coefficients and the carbon content of the aerosol in urbanized regions.
Variability of the propagation coefficients due to rain for microwave links in southern Africa
NASA Astrophysics Data System (ADS)
Mulangu, C. T.; Afullo, T. J.
2009-06-01
We use the Mie scattering approach and the dielectric model of Liebe to determine the propagation coefficients and rain attenuation distribution for four locations in Botswana, southern Africa, using R0.01 = 68.9 mm/h for Gaborone, R0.01 = 137.06 mm/h for Selebi-Phikwe, R0.01 = 86.87 mm/h for Francistown, and R0.01 = 64.4 mm/h for Kasane over the frequency range of 1-1000 GHz. The results show that the extinction coefficients depend more strongly on temperature at lower frequencies than at higher frequencies for lognormal distribution. The absorption coefficient is significant but decreases exponentially with rain temperature at lower microwave frequencies. The application of the proposed model with various distributions is corroborated using practical results for Durban in South Africa.
Absorption coefficient of urban aerosol in Nanjing, west Yangtze River Delta, China
NASA Astrophysics Data System (ADS)
Zhuang, B. L.; Wang, T. J.; Liu, J.; Ma, Y.; Yin, C. Q.; Li, S.; Xie, M.; Han, Y.; Zhu, J. L.; Yang, X. Q.; Fu, C. B.
2015-12-01
Absorbing aerosols can significantly modulate short-wave solar radiation in the atmosphere, affecting regional and global climate. The aerosol absorption coefficient (AAC) is an indicator that assesses the impact of absorbing aerosols on radiative forcing. In this study, the near-surface AAC and absorption Ångström exponent (AAE) in the urban area of Nanjing, China, are characterized on the basis of measurements in 2012 and 2013 using the seven-channel Aethalometer (model AE-31, Magee Scientific, USA). The AAC is estimated with direct and indirect corrections, which result in consistent temporal variations and magnitudes of AAC at 532 nm. The mean AAC at 532 nm is about 43.23 ± 28.13 M m-1 in the urban area of Nanjing, which is much lower than that in Pearl River Delta and the same as in rural areas (Lin'an) in Yangtze River Delta. The AAC in the urban area of Nanjing shows strong seasonality (diurnal variations); it is high in cold seasons (at rush hour) and low in summer (in the afternoon). It also shows synoptic and quasi-2-week cycles in response to weather systems. Its frequency distribution follows a typical log-normal pattern. The 532 nm AAC ranging from 15 to 65 M m-1 dominates, accounting for more than 72 % of the total data samples in the entire study period. Frequent high pollution episodes, such as those observed in June 2012 and in winter 2013, greatly enhanced AAC and altered its temporal variations and frequency distributions. These episodes are mostly due to local emissions and regional pollution. Air masses flowing from northern China to Nanjing can sometimes be highly polluted and lead to high AAC at the site. AAE at 660/470 nm from the Schmid correction (Schmid et al., 2006) is about 1.56, which might be more reasonable than from the Weingartner correction (Weingartner et al., 2003). Low AAEs mainly occur in summer, likely due to high relative humidity (RH) in the season. AAC increases with increasing AAE at a fixed aerosol loading. The RH
NASA Astrophysics Data System (ADS)
Tran, Huong; Du, Wei; Ghetmiri, Seyed A.; Mosleh, Aboozar; Sun, Greg; Soref, Richard A.; Margetis, Joe; Tolle, John; Li, Baohua; Naseem, Hameed A.; Yu, Shui-Qing
2016-03-01
The absorption coefficient and refractive index of Ge1-xSnx alloys (x from 0% to 10%) were characterized for the wavelength range from 1500 to 2500 nm via spectroscopic ellipsometry at room temperature. By applying physical models to fit the obtained data, two empirical formulae with extracted constants and coefficients were developed: (1) Absorption coefficient. The absorption regarding Urbach tail, indirect and direct bandgap transitions were comprehensively taken into account; (2) refractive index. The Sellmeier coefficients associated with dispersion relationship were extracted. In these formulae, the Sn composition and strain percentage were the input parameters, by inputting which the spectral absorption coefficient and spectral refractive index can be obtained. Since the absorption coefficient is key information to determine the performance of the photodetectors including operation wavelength range, responsivity, and specific detectivity, and the refractive index is very useful for the design of the anti-reflection coating for photodetectors and the layer structure for waveguides, the developed formulae could simplify the optoelectronic device design process due to their parameter-based expressions.
Infrared absorption-coefficient data on SF6 applicable to atmospheric remote sensing
NASA Technical Reports Server (NTRS)
Varanasi, P.; Gopalan, A.; Brannon, J. F., Jr.
1992-01-01
Spectral absorption coefficients, k(nu)/cm per atm, of SF6 have been measured in the central Q-branches of the nu(3)-fundamental at 947/cm at various temperature-pressure combinations representing tangent heights in solar-occultation experiments or layers in the atmosphere. The data obtained with the Doppler-limited spectral resolution (about 0.0001/cm) of a tunable-diode laser spectrometer are useful in the atmospheric remote sensing of this trace gas.
Water vapor absorption coefficients in the 8-13-micron spectral region - A critical review
NASA Technical Reports Server (NTRS)
Grant, William B.
1990-01-01
Measurements of water vapor absorption coefficients in the thermal IR atmospheric window (8-13 microns) during the past 20 years obtained by a variety of techniques are reviewed for consistency and compared with computed values based on the AFGL spectral data tapes. The methods of data collection considered were atmospheric long path absorption with a CO2 laser or a broadband source and filters, a White cell and a CO2 laser or a broadband source and a spectrometer, and a spectrophone with a CO2 laser. Advantages and disadvantages of each measurement approach are given as a guide to further research. Continuum absorption has apparently been measured accurately to about the 5-10 percent level in five of the measurements reported.
Khalifah, Peter
2015-02-01
The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles θ_{D} of 0° to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.
Khalifah, Peter
2015-02-01
The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles θD of 0°more » to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.« less
Two-photon interband absorption coefficients in tungstate and molybdate crystals
NASA Astrophysics Data System (ADS)
Lukanin, V. I.; Karasik, A. Ya.
2015-02-01
Two-photon absorption (TPA) coefficients were measured in tungstate and molybdate crystals - BaWO4, KGW, CaMoO4, BaMoO4, CaWO4, PbWO4 and ZnWO4 upon different orientations of excitation polarization with respect to the crystallographic axes. Trains of 25 ps pulses with variable radiation intensities of third (349 nm) harmonics of passively mode-locked 1047 nm Nd:YLF laser were used for interband two-photon excitation of the crystals. It was suggested that in the case, when 349 nm radiation pumping energy exceeds the bandgap width (hν>Eg), the nonlinear excitation process can be considered as two-step absorption. The interband two-photon absorption in all the studied crystals induces the following one-photon absorption from the exited states, which affects the nonlinear process dynamics and leads to a hysteresis in the dependence of the transmission on the excitation intensity. This fact was taken into account under analysis of the experimental dependences of the reciprocal transmission on the excitation intensity. Laser excitation in the transparency region of the crystals caused stimulated Raman scattering (SRS) not for all the crystals studied. The measured nonlinear coefficients allowed us to explain the suppression of SRS in crystals as a result of competition between the SRS and TPA.
NASA Astrophysics Data System (ADS)
Riddick, Caitlin A. L.; Hunter, Peter D.; Tyler, Andrew N.; Martinez-Vicente, Victor; Horváth, Hajnalka; Kovács, Attila W.; Vörös, Lajos; Preston, Tom; Présing, Mátyás.
2015-10-01
In order to improve robustness of remote sensing algorithms for lakes, it is vital to understand the variability of inherent optical properties (IOPs) and their mass-specific representations (SIOPs). In this study, absorption coefficients for particulate and dissolved constituents were measured at 38 stations distributed over a biogeochemical gradient in Lake Balaton, Hungary. There was a large range of phytoplankton absorption (aph(λ)) over blue and red wavelengths (aph(440) = 0.11-4.39 m-1, aph(675) = 0.048-2.52 m-1), while there was less variability in chlorophyll-specific phytoplankton absorption (a*ph(λ)) in the lake (a*ph(440) = 0.022 ± 0.0046 m2 mg-1, a*ph(675) = 0.010 ± 0.0020 m2 mg-1) and adjoining wetland system, Kis-Balaton (a*ph(440) = 0.017 ± 0.0015 m2 mg-1, a*ph(675) = 0.0088 ± 0.0017 m2 mg-1). However, in the UV, a*ph(350) significantly increased with increasing distance from the main inflow (Zala River). This was likely due to variable production of photoprotective pigments (e.g., MAAs) in response to the decreasing gradient of colored dissolved organic matter (CDOM). The slope of CDOM absorption (SCDOM) also increased from west to east due to larger terrestrial CDOM input in the western basins. Absorption by nonalgal particles (aNAP(λ)) was highly influenced by inorganic particulates, as a result of the largely mineral sediments in Balaton. The relative contributions to the absorption budget varied more widely than oceans with a greater contribution from NAP (up to 30%), and wind speed affected the proportion attributed to NAP, phytoplankton, or CDOM. Ultimately, these data provide knowledge of the heterogeneity of (S)IOPs in Lake Balaton, suggesting the full range of variability must be considered for future improvement of analytical algorithms for constituent retrieval in inland waters.
Monochromatic calculations of atmospheric radiative transfer due to molecular line absorption
NASA Technical Reports Server (NTRS)
Chou, M.-D.; Kouvaris, L.
1986-01-01
Sensitivity studies related to the effects of line cutoff, spectral resolution, and temperature and pressure interpolations in radiative transfer have been performed so that a data set of absorption coefficients for water vapor, CO2, and O3 may be created efficiently. Results show that computations of absorption coefficients are affected only slightly by cutting a line off at a wave number 190 times the Lorentz half width from the center, or equivalently, cutting off 0.33 percent of the line intensity from the wings. To achieve a relative cooling rate error smaller than 2 percent, it is sufficient to precompute the absorption coefficient at three temperatures (210, 250, and 290 K) and 19 pressures with Delta (log 10 p) = 0.2. The absorption coefficient at other conditions can be interpolated linearly with pressure and exponentially with a quadratic in temperature. For the spectral resolution the absorption coefficients can be adequately computed at 0.01, 0.002, 0.005, and 0.025/cm intervals in the thermal water vapor, the CO2 and O3 bands, and the solar water vapor bands, respectively, which limits the error to only a few percent in the cooling and heating rates. Using the precomputed absorption coefficients, repeated monochromatic calculations of atmospheric heating/cooling rates for radiation model developments and for comparison with less detailed calculations are no longer difficult.
Absorption coefficient of urban aerosol in Nanjing, west Yangtze River Delta of China
NASA Astrophysics Data System (ADS)
Zhuang, B. L.; Wang, T. J.; Liu, J.; Ma, Y.; Yin, C. Q.; Li, S.; Xie, M.; Han, Y.; Zhu, J. L.; Yang, X. Q.; Fu, C. B.
2015-06-01
Absorbing aerosols can significantly modulate shortwave solar radiation in the atmosphere, affecting regional and global climate. Aerosol absorption coefficient (AAC) is an indicator to assess the impact of absorbing aerosols on radiative forcing. In this study, the near-surface AAC and absorption angstrom exponent (AAE) in urban Nanjing, China, are characterized on the basis of measurements in 2012 and 2013 using the 7-channel Aethalometer (model AE-31, Magee Scientific, USA). The AAC is estimated with direct and indirect corrections, which show consistent temporal variations and magnitudes of AAC at 532 nm. The mean AAC at 532 nm is about 43.23 ± 28.13 M m-1 in urban Nanjing, which is much lower than that in Pearl River Delta and as the same as that in rural areas (Lin'an) in Yangtze River Delta. The AAC in urban Nanjing shows strong seasonality (diurnal variations), high in cold seasons (at rush hours) and low in summer (in afternoon). It also show synoptic and quasi-two-week cycles in response to weather systems. Its frequency distribution follows a typical lognormal pattern. The 532 nm-AAC ranging from 15 to 65 M m-1 dominates, accounting for more than 72% of the total data samples in the entire study period. Frequent high pollution episodes, such as those observed in June 2012 and in winter 2013, greatly enhanced AAC and altered its temporal variations and frequency distributions. These episodes are mostly due to local emissions and regional pollutions. Air masses from northern China to Nanjing can sometimes be highly polluted and lead to high AAC at the site. AAE at 660/470 nm from the Schmid correction (Schmid et al., 2006) is about 1.56, which might be more reasonable compared to that from the Weingartner correction (Weingartner et al., 2003). Low AAEs mainly appear in summer in response to the relative humidity (RH). AAC increases with increasing AAE at a fixed aerosol loading. The RH-AAC relationship is more complex. Overall, AAC peaks around RH values
Parthasarathy, Ranganathan; Misra, Anil; Park, Jonggu; Ye, Qiang; Spencer, Paulette
2012-01-01
The diffusion of water into dentin adhesive polymers and leaching of unpolymerized monomer from the adhesive are linked to their mechanical softening and hydrolytic degradation. Therefore, diffusion coefficient data are critical for the mechanical design of these polymeric adhesives. In this study, diffusion coefficients of water and leachables were obtained for sixteen methacrylate-based crosslinked polymers using absorption experiments. The experimental mass change data was interpreted using numerical solution of the two-dimensional diffusion equations. The calculated diffusion coefficients varied from 1.05 × 10−8 cm2/sec (co-monomer TMTMA) to 3.15 × 10−8 cm2/sec (co-monomer T4EGDMA). Correlation of the diffusion coefficients with crosslink density and hydrophilicity showed an inverse trend (R2 = 0.41). The correlation of diffusion coefficient with crosslink density and hydrophilicity are closer for molecules differing by simple repeat units (R2 = 0.95). These differences in the trends reveal mechanisms of interaction of the diffusing water with the polymer structure. PMID:22430592
Microwave Resonator Measurements of Atmospheric Absorption Coefficients: A Preliminary Design Study
NASA Technical Reports Server (NTRS)
Walter, Steven J.; Spilker, Thomas R.
1995-01-01
A preliminary design study examined the feasibility of using microwave resonator measurements to improve the accuracy of atmospheric absorption coefficients and refractivity between 18 and 35 GHz. Increased accuracies would improve the capability of water vapor radiometers to correct for radio signal delays caused by Earth's atmosphere. Calibration of delays incurred by radio signals traversing the atmosphere has applications to both deep space tracking and planetary radio science experiments. Currently, the Cassini gravity wave search requires 0.8-1.0% absorption coefficient accuracy. This study examined current atmospheric absorption models and estimated that current model accuracy ranges from 5% to 7%. The refractivity of water vapor is known to 1% accuracy, while the refractivity of many dry gases (oxygen, nitrogen, etc.) are known to better than 0.1%. Improvements to the current generation of models will require that both the functional form and absolute absorption of the water vapor spectrum be calibrated and validated. Several laboratory techniques for measuring atmospheric absorption and refractivity were investigated, including absorption cells, single and multimode rectangular cavity resonators, and Fabry-Perot resonators. Semi-confocal Fabry-Perot resonators were shown to provide the most cost-effective and accurate method of measuring atmospheric gas refractivity. The need for accurate environmental measurement and control was also addressed. A preliminary design for the environmental control and measurement system was developed to aid in identifying significant design issues. The analysis indicated that overall measurement accuracy will be limited by measurement errors and imprecise control of the gas sample's thermodynamic state, thermal expansion and vibration- induced deformation of the resonator structure, and electronic measurement error. The central problem is to identify systematic errors because random errors can be reduced by averaging
Spectroscopic method for determination of the absorption coefficient in brain tissue
NASA Astrophysics Data System (ADS)
Johansson, Johannes D.
2010-09-01
I use Monte Carlo simulations and phantom measurements to characterize a probe with adjacent optical fibres for diffuse reflectance spectroscopy during stereotactic surgery in the brain. Simulations and measurements have been fitted to a modified Beer-Lambert model for light transport in order to be able to quantify chromophore content based on clinically measured spectra in brain tissue. It was found that it is important to take the impact of the light absorption into account when calculating the apparent optical path length, lp, for the photons in order to get good estimates of the absorption coefficient, μa. The optical path length was found to be well fitted to the equation lp=a+b ln(Is)+c ln(μa)+d ln(Is)ln(μa), where Is is the reflected light intensity for scattering alone (i.e., zero absorption). Although coefficients a-d calculated in this study are specific to the probe used here, the general form of the equation should be applicable to similar probes.
Sound absorption coefficient in situ: an alternative for estimating soil loss factors.
Freire, Rosane; Meletti de Abreu, Marco Henrique; Okada, Rafael Yuri; Soares, Paulo Fernando; GranhenTavares, Célia Regina
2015-01-01
The relationship between the sound absorption coefficient and factors of the Universal Soil Loss Equation (USLE) was determined in a section of the Maringá Stream basin, Paraná State, by using erosion plots. In the field, four erosion plots were built on a reduced scale, with dimensions of 2.0×12.5m. With respect to plot coverage, one was kept with bare soil and the others contained forage grass (Brachiaria), corn and wheat crops, respectively. Planting was performed without any type of conservation practice in an area with a 9% slope. A sedimentation tank was placed at the end of each plot to collect the material transported. For the acoustic system, pink noise was used in the measurement of the proposed monitoring, for collecting information on incident and reflected sound pressure levels. In general, obtained values of soil loss confirmed that 94.3% of material exported to the basin water came from the bare soil plot, 2.8% from the corn plot, 1.8% from the wheat plot, and 1.1% from the forage grass plot. With respect to the acoustic monitoring, results indicated that at 16kHz erosion plot coverage type had a significant influence on the sound absorption coefficient. High correlation coefficients were found in estimations of the A and C factors of the USLE, confirming that the acoustic technique is feasible for the determination of soil loss directly in the field. PMID:24972796
NASA Astrophysics Data System (ADS)
de Santiago Duran, Oscar Cesar
Experimental identification of fluid film bearing parameters is vital to validate predictions from often restrictive computational fluid film bearing models and is also promising for condition monitoring and troubleshooting. This dissertation presents the analytical bases of two procedures for bearing supports parameter identification with potential for in-situ implementation. Bearing support coefficients are derived from measurements of rotor responses to impact loads and due to calibrated imbalances in characteristic planes. Subsequent implementation of the procedures to measurements performed in a rigid massive rotor traversing two critical speeds provides force coefficients for a novel bearing support comprising a tilting pad bearing (TPJB ) in series with an integral squeeze film damper (SFD). At a constant rotor speed, the first method requires impacts loads exerted along two lateral planes for identification of frequency-dependent force coefficients. Simulation numerical examples show the method is reliable with a reduced sensitivity to noise as the number of impacts increases (frequency averaging). In the experiments, an ad-hoc fixture delivers impacts to the rotor middle disk at speeds of 2,000 and 4,000 rpm. The experimentally identified force coefficients are in close agreement with predicted coefficients for the series support TPJB-SFD. In particular, damping coefficients are best identified around the system first natural frequency. Bearing stiffness are correctly identified in the low frequency range, but show a marked reduction at higher frequencies apparently due to inertial effects not accounted for in the model. Measurements of rotor response to calibrated imbalances allow identification of speed-dependent force coefficients. The procedure requires a minimum of two different imbalance distributions for identification of force coefficients from the two bearing supports. The rotor responses show minimal cross-coupling effects, as also predicted by
Pressure-induced absorption coefficients for radiative transfer calculations in Titan's atmosphere
NASA Technical Reports Server (NTRS)
Courtin, Regis
1988-01-01
The semiempirical theory of Birnbaum and Cohen (1976) is used to calculate the FIR pressure-induced absorption (PIA) spectra of N2, CH4, N2 + Ar, N2 + CH4, and N2 + H2 under conditions like those in the Titan troposphere. The results are presented graphically and compared with published data from laboratory measurements of PIA in the same gases and mixtures (Dagg et al., 1986; Dore et al., 1986). Good agreement is obtained, with only a slight underestimation of PIA at 300-400/cm in the case of CH4. The absorption coefficients are presented in tables, and it is suggested that the present findings are of value for evaluating the effects of tropospheric clouds on the Titan FIR spectrum and studying the greenhouse effect near the Titan surface.
Uzhegov, V.N.; Kozlov, V.S.; Panchenko, M.V.; Pkhalagov, Yu.A.; Pol'kin, V.V.; Terpugova, S.A.; Shmargunov, V.P.; Yausheva, E.P.
2005-03-18
The problem of the choice of the aerosol optical constants and, in particular, imaginary part of the refractive index of particles in visible and infrared (IR) wavelength ranges is very important for calculation of the global albedo of the atmosphere in climatic models. The available models of the aerosol optical constants obtained for the prescribed chemical composition of particles (see, for example, Ivlev et al. 1973; Ivlev 1982; Volz 1972), often are far from real aerosol. It is shown in (Krekov et al. 1982) that model estimates of the optical characteristics of the atmosphere depending on the correctness of real and imaginary parts of the aerosol complex refractive index can differ by some hundreds percent. It is known that the aerosol extinction coefficient {alpha}({lambda}) obtained from measurements on a long horizontal path can be represented as {alpha}({lambda})={sigma}({lambda})+{beta}({lambda}), where {sigma} is the directed light scattering coefficient, and {beta} is the aerosol absorption coefficient. The coefficient {sigma}({lambda}) is measured by means of a nephelometer. Seemingly, if measure the values {alpha}({lambda}) and {sigma}({lambda}), it is easy to determine the value {beta}({lambda}). However, in practice it is almost impossible for a number of reasons. Firstly, the real values {alpha}({lambda}) and {sigma}({lambda}) are very close to each other, and the estimate of the parameter {beta}({lambda}) is concealed by the errors of measurements. Secondly, the aerosol optical characteristics on the long path and in the local volume of nephelometer can be different, that also leads to the errors in estimating {beta}({lambda}). Besides, there are serious difficulties in performing spectral measurements of {sigma}({lambda}) in infrared wavelength range. Taking into account these circumstances, in this paper we consider the statistical technique, which makes it possible to estimate the absorption coefficient of real aerosol on the basis of analysis
A comparison of methods for the measurement of the absorption coefficient in natural waters
NASA Technical Reports Server (NTRS)
Pegau, W. Scott; Cleveland, Joan S.; Doss, W.; Kennedy, C. Dan; Maffione, Robert A.; Mueller, James L.; Stone, R.; Trees, Charles C.; Weidemann, Alan D.; Wells, Willard H.
1995-01-01
In the spring of 1992 an optical closure experiment was conducted at Lake Pend Orielle, Idaho. A primary objective of the experiment was to compare techniques for the measurement of the spectral absorption coefficent and other inherent optical properties of natural waters. Daily averages of absorption coefficents measured using six methods are compared at wavelengths of 456, 488, and 532 nm. Overall agreement was within 40% at 456 nm and improved with increasing wavelength to 25% at 532 nm. These absorption measurements were distributed over the final 9 days of the experiement, when bio-optical conditions in Lake Pend Oreille (as indexed by the beam attenuation coefficent c(sub p)(660) and chlorophyll a fluorescence profiles) were representative of those observed throughout the experiment. However, profiles of stimulated chlorophyll a fluorescence and beam transmission showed that bio-optical properties in the lake varied strongly on all time and space scales. Therefore environmental variabilty contributed significantly to deviations between daily mean absorption coefficients measured using the different techniques.
Mesure de coefficients d'absorption de plasmas créés par laser nanoseconde
NASA Astrophysics Data System (ADS)
Thais, F.; Chenais-Popovics, C.; Eidmann, K.; Bastiani, S.; Blenski, T.; Gilleron, F.
2005-06-01
La mesure des coefficients d'absorption dans les plasmas chauds est particulièrement utile dans le domaine de la fusion par confinement inertiel ainsi que dans divers contextes en astrophysique. Le développement des calculs de physique atomique qui y sont associés repose sur des hypothèses qu'il est nécessaire de vérifier dans la plus large gamme possible de conditions physiques. Nous présentons ici la méthode de mesure et d'analyse employée en nous appuyant sur l'exemple des cibles multicouches nickel/aluminium.
Determination of Absorption Coefficient of a Solution by a Simple Experimental Setup
NASA Astrophysics Data System (ADS)
Gopalakrishnan, Deepak; Akhildev, C.; Sreenivasan, P. V.; Leelamma, K. K.; Joseph, Lyjo K.; Anila, E. I.
2011-10-01
The absorption coefficients of aqueous potassium permanganate (KMnO4) solution at 638.8 nm for various concentrations are determined using a simple experimental set up. The setup consists of He-Ne laser source (Red, 638.8 nm, 10 mW), a glass jar in which the KMnO4 sample is taken, a mirror strip inclined at 45° to direct the laser beam towards the bottom of the glass jar, a traveling microscope to adjust the position of light dependent resistor (LDR) and a digital multimeter to measure the resistance.
NASA Astrophysics Data System (ADS)
Thomas, S. M.
2015-12-01
Minor and trace element chemistry, phase relations, rheology, thermal structure and the role of volatiles and their abundance in the deep Earth mantle are still far from fully explored, but fundamental to understanding the processes involved in Earth formation and evolution. Theory and high pressure experiments imply a significant water storage capacity of nominally anhydrous minerals, such as majoritic garnet, olivine, wadsleyite and ringwoodite, composing the Earth's upper mantle and transition zone to a depth of 660 km. Studying the effect of water incorporation on chemical and physical mineral properties is of importance, because the presence of trace amounts of water, incorporated as OH through charge-coupled chemical substitutions into such nominally anhydrous high-pressure silicates, notably influences phase relations, melting behavior, conductivity, elasticity, viscosity and rheology. Knowledge of absolute water contents in nominally anhydrous minerals is essential for modeling the Earth's interior water cycle. One of the most common and sensitive tools for water quantification is IR spectroscopy for which mineral-specific absorption coefficients are required. Such calibration constants can be derived from hydrogen concentrations determined by independent techniques, such as secondary ion mass spectrometry, Raman spectroscopy or proton-proton(pp)-scattering. Here, analytical advances and mineral-specific IR absorption coefficients for the quantification of H2O in major phases of the Earth's mantle will be discussed. Furthermore, new data from optical absorption measurements in resistively heated diamond-anvil cells at high pressures and temperatures up to 1000 K will be presented. Experiments were performed on synthetic single-crystals of olivine, ringwoodite, majoritic garnet, and Al-bearing phase D with varying iron, aluminum and OH contents to calculate radiative thermal conductivities and study their contribution to heat transfer in the Earth's interior
Theoretical calculations of nonlinear refraction and absorption coefficients of doped graphene
NASA Astrophysics Data System (ADS)
Margulis, Vl A.; Muryumin, E. E.; Gaiduk, E. A.
2014-12-01
In this study, we present the first theoretical predictions concerning the nonlinear refractive and absorptive properties of the doped graphene in which the Fermi energy {{E}F} of charge carriers (noninteracting massless Dirac fermions) is controlled by an external gate voltage. We base our study on the original perturbation theory technique developed by Genkin and Mednis (1968 Sov. Phys. JETP 27 609) for calculating the nonlinear-optical (NLO) response coefficients of bulk crystalline semiconductors with partially filled bands. Using a simple tight-binding model for the π-electron energy bands of graphene, we obtain analytic expressions for the nonlinear refractive index {{n}2}(ω ) and the nonlinear absorption coefficient {{α }2}(ω ) of the doped graphene at photon energies above twice the value of the Fermi energy (\\hbar ω \\gt 2{{E}F}). We show that in this spectral region, both the nonlinear refraction ant the nonlinear absorption are determined predominantly by the combined processes which simultaneously involve intraband and interband motion of π-electrons. Our calculations indicate that extremely large negative values of n2 (of the order of -{{10}-6} cm2 W-1) can be achieved in the graphene at a relatively low doping level (of about 1012 cm-2) provided that the excitation frequency slightly exceeds the threshold frequency corresponding to the onset of interband transitions. With a further increase of the radiation frequency, the {{n}2}(ω ) becomes positive and begins to decrease in its absolute magnitude. The peculiar frequency dispersion of n2 and a negative sign of the {{α }2} (absorption bleaching), as predicted by our theory, suggest that the doped graphene is a prospective NLO material to be used in practical optical switching applications.
NASA Technical Reports Server (NTRS)
Harward, C. N.
1977-01-01
Measurements were performed to determine the pressure and temperature dependence of CFM-12 absorption coefficients for CO2 waveguide laser radiation. The absorption coefficients of CFM-12 for CO2 waveguide laser radiation were found to have no spectral structure within small spectral bandwidths around the CO2 waveguide laser lines in the CO2 spectral band for pressures above 20 torr. All of the absorption coefficients for the CO2 laser lines studied are independent of pressure above 100 torr, except for the P(36) laser CO2 spectral band. The absorption coefficients associated with the P(42) line in the same band showed the greatest change with temperature, and it also has the largest value of all the lines studied.
NASA Astrophysics Data System (ADS)
Zamani, N.; Keshavarz, A.; Nadgaran, H.
2016-06-01
In this paper, we investigate the optical absorption coefficient of hybrid structure consisting of metal nano particle (MNP) coupled to multi-layer spherical quantum dot (MSQD). Energy eigenvalues and eigenfunctions of Schrödinger equation in this structure are obtained by using numerical solution (by the fourth-order Runge-Kutta method). The effect of MNP in the vicinity of MSQD is calculated by considering local field theory. Then the variation of optical absorption coefficient hybrid structure is calculated. The results show that the presence of MNP near MSQD enhances the optical absorption coefficient. Also, by changing the distance between MNP and MSQD and radius of MNP, variation of optical absorption coefficient and refractive index changes are introduced.
Spectral absorption coefficients of argon and silicon and spectral reflectivity of aluminum
NASA Technical Reports Server (NTRS)
Krascella, N. L.
1972-01-01
A theoretical investigation was conducted to estimate the spectral properties of argon as a function of pressure, temperature, and wave number. The spectral characteristics of the argon buffer gas exert a strong influence on radiative energy transfer in the in-reactor test configuration of the nuclear light bulb engine. An existing computer program was modified and used to calculate the spectral absorption coefficients of argon at total pressures of 50, 100, 250, 500, 750 and 1000 atm in the temperature interval between 1000 and 30,000 K. At each pressure and temperature, spectral properties were calculated for forty-seven wave numbers in the interval between 1000 and 1,000,000 cm/1. Estimates of the spectral absorption coefficients of silicon were made as part of an evaluation of silicon vapor as a possible buffer-gas seeding agent for the reference nuclear light bulb engine. Existing cross-section data were used to calculate the spectral characteristics of silicon at twenty-four temperatures in the interval between 2000 and 10,000 K.
Majaron, Boris; Verkruysse, Wim; Tanenbaum, B Samuel; Milner, Thomas E; Nelson, J Stuart
2002-06-01
Pulsed photothermal radiometry can be used for non-invasive depth profiling of optically scattering samples, including biological tissues such as human skin. Computational reconstruction of the laser-induced temperature profile from recorded radiometric signals is sensitive to the value of the tissue absorption coefficient in the infrared detection band (muIR). While assumed constant in reported reconstruction algorithms, muIR of human skin varies by two orders of magnitude in the commonly used 3-5 microm detection band. We analyse the problem of selecting the effective absorption coefficient value to be used with such algorithms. In a numerical simulation of photothermal profiling we demonstrate that results can be markedly impaired, unless the reconstruction algorithm is augmented by accounting for spectral variation muIR(lambda). Alternatively, narrowing the detection band to 4.5-5 microm reduces the spectral variation muIR(lambda) to a level that permits the use of the simpler, unaugmented algorithm. Implementation of the latter approach for depth profiling of port wine stain birthmarks in vivo is presented and discussed. PMID:12108776
NASA Astrophysics Data System (ADS)
Guo, Kangxian; Zhang, Zhongmin; Mou, Sen; Xiao, Bo
2015-05-01
The analytical expressions of linear and nonlinear optical absorption coefficients and refractive index changes in a quantum dot with a hydrogenic impurity are obtained by using the compact-density-matrix approach and iterative method. The wave functions and the energy levels are obtained by using the variational method. Numerical results show that the optical absorption coefficients and refractive index changes are strongly affected by the hydrogenic impurity.
NASA Astrophysics Data System (ADS)
O'Brien, J. J.; Cao, H.
2000-10-01
Methane spectral features are prominent in the reflected sunlight spectra from the outer planets and some of their major satellites and can provide useful information on the atmospheres of those bodies. Methane bands occurring in the visible to near-IR region are particularly important because for many of these planetary bodies, methane bands occurring in the IR are saturated. Spectral observations of these bodies also are being made at increasingly higher resolution. In order to interpret the planetary spectra, laboratory data for methane obtained at appropriate sample conditions and spectral resolution are required. Since the visible to near-IR spectrum of methane is intrinsically weak, sensitive techniques are required to perform the laboratory measurements. We have employed the intracavity laser spectroscopy (ILS) technique to record methane spectrum in the visible to near-IR region. New results for room temperature methane in the 10,635 - 13,300 cm-1 region and for liquid nitrogen temperature (77 K) methane in the 10,860 - 11,605 cm-1 region will be presented. Spectra throughout the more strongly absorbing sections will be shown. These spectra are acquired at a resolution of 400,000 - 500,000 and are calibrated using iodine reference spectra acquired from an extra-cavity cell at nearly the same time as when the methane data are recorded. From the spectra, absorption coefficients are determined and these are presented as averages over 1 Å and 1 cm-1 intervals. In order to obtain the results, spectra are deconvolved for the instrument function using a Fourier transform technique. The validity of the approach is verified from studies of isolated oxygen lines in the A band occurring around 760 nm. Good agreement is observed between the intensity values determined from the FT deconvolution and integration method and those derived by fitting the observed line profiles to Voigt line-shapes convoluted with the instrument function. The methane results are compared
Measuring absorption coefficient of scattering liquids using a tube inside an integrating sphere.
Villanueva, Yolanda; Veenstra, Colin; Steenbergen, Wiendelt
2016-04-10
A method for measuring the absorption coefficient μ_{a} of absorbing and scattering liquid samples is presented. The sample is injected into a small transparent tube mounted through an integrating sphere. Two models for determining the absorption coefficient using the relative optical output signal are described and validated using aqueous ink absorbers of 0.5 vol.% (0.3 mm^{-1}<μ_{a}<1.55 mm^{-1}) and 1.0 vol.% (1.0 mm^{-1}<μ_{a}<4.0 mm^{-1}) concentrations with 1 vol.% (μs'≈1.4 mm^{-1}) and 10 vol.% (μs'≈14 mm^{-1}) Intralipid dilutions. The low concentrations give μ_{a} and μ_{s} values, which are comparable with those of biological tissues. One model assumes a uniform light distribution within the sample, which is valid for low absorption. Another model considers light attenuation that obeys Lambert-Beer's law, which may be used for relatively high absorption. Measurements with low and high scattering samples are done for the wavelength range of 400-900 nm. Measured spectra of purely absorbing samples are within 15% agreement with measurements using standard transmission spectrophotometry. For 0.5 vol.% ink absorbers and at wavelengths below 700 nm, measured μ_{a} values are higher for samples with low scattering and lower for those with high scattering. At wavelengths above 700 nm, measured μ_{a} values do not vary significantly with amount of scattering. For 1.0 vol.% ink absorbers, measured spectra do not change with low scattering. These results indicate that the method can be used for measuring absorption spectra of scattering liquid samples with optical properties similar to biological absorbers, particularly at wavelengths above 700 nm, which is difficult to accomplish with standard transmission spectrophotometry. PMID:27139871
Determination of absorption coefficient based on laser beam thermal blooming in gas-filled tube.
Hafizi, B; Peñano, J; Fischer, R; DiComo, G; Ting, A
2014-08-01
Thermal blooming of a laser beam propagating in a gas-filled tube is investigated both analytically and experimentally. A self-consistent formulation taking into account heating of the gas and the resultant laser beam spreading (including diffraction) is presented. The heat equation is used to determine the temperature variation while the paraxial wave equation is solved in the eikonal approximation to determine the temporal and spatial variation of the Gaussian laser spot radius, Gouy phase (longitudinal phase delay), and wavefront curvature. The analysis is benchmarked against a thermal blooming experiment in the literature using a CO₂ laser beam propagating in a tube filled with air and propane. New experimental results are presented in which a CW fiber laser (1 μm) propagates in a tube filled with nitrogen and water vapor. By matching laboratory and theoretical results, the absorption coefficient of water vapor is found to agree with calculations using MODTRAN (the MODerate-resolution atmospheric TRANsmission molecular absorption database) and HITRAN (the HIgh-resolution atmospheric TRANsmission molecular absorption database). PMID:25090334
The Optical Absorption Coefficient of Bean Seeds Investigated Using Photoacoustic Spectroscopy
NASA Astrophysics Data System (ADS)
Sanchez-Hernandez, G.; Hernandez-Aguilar, C.; Dominguez-Pacheco, A.; Cruz-Orea, A.; Perez-Reyes, M. C. J.; Martinez, E. Moreno
2015-06-01
A knowledge about seed optical parameters is of great relevance in seed technology practice. Such parameters provide information about its absorption and reflectance, which could be useful for biostimulation processes, by light sources, in early stages of seed germination. In the present research photoacoustic spectroscopy (PAS) and the Rosencwaig and Gersho model were used to determine the optical absorption coefficient () of five varieties of bean seeds ( Phaseolus vulgaris L.), of different productive cycles; the seeds were biostimulated by laser treatment to evaluate the effects of biostimulation pre-sowing. It was found that the bean varieties V1, V2, V4, and V5 were optically opaque in the visible spectrum; in the case of the V3 variety, this sample was optically transparent from 680 nm. The varieties of the studied bean seeds showed significant statistical differences in sizes and also in their optical absorption spectra. The biostimulation effects showed that the seed samples with a higher optical penetration length had a positive biostimulation, in the percentage of germination, obtaining an enhancement of 47 % compared to the control sample. The utility of PAS for the optical characterization of seeds has been demonstrated in this study of the laser biostimulation process of this kind of samples.
Absorption coefficients of selected explosives and related compounds in the range of 0.1-2.8 THz.
Chen, Jian; Chen, Yunqing; Zhao, Hongwei; Bastiaans, Glenn J; Zhang, X-C
2007-09-17
We have investigated the absorption spectra of seventeen explosives and related compounds (ERCs) by using terahertz time-domain spectroscopy in the 0.1-2.8 THz region. Most of these substances show characteristic absorption features in this frequency range. The measured absorption coefficients of these ERCs form a database, which is of great importance for biochemical, defense and security related applications. PMID:19547570
NASA Technical Reports Server (NTRS)
Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.
2009-01-01
The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."
Bondarenko, S V; Garanin, Sergey G; Zhidkov, N V; Pinegin, A V; Suslov, N A
2012-01-31
We set forth the data of experimental investigation of X-ray spectral absorption coefficients in the 1.1 - 1.6 keV photon energy range for Al and Ge specimens bulk heated by soft X-ray radiation. Two experimental techniques are described: with the use of one facility channel and the heating of specimens by the X-ray radiation from a plane burnthrough target, as well as with the use of four channels and the heating by the radiation from two cylindrical targets with internal input of laser radiation. The X-ray radiation absorption coefficients were studied by way of transmission absorption spectroscopy using backlighting X-ray radiation from a point source. The results of investigation of X-ray spectral absorption coefficients on the 1s - 2p transitions in Al atoms and the 2p - 3d transitions in Ge atoms are presented.
Spectral absorption-coefficient data on HCFC-22 and SF6 for remote-sensing applications
NASA Technical Reports Server (NTRS)
Varanasi, P.; Li, Z.; Nemtchinov, V.; Cherukuri, A.
1994-01-01
Spectral absorption-coefficients (cross-sections) kappa(sub nu) (/cm/atm) have been measured in the 7.62, 8.97, and 12.3 micrometer bands of HCFC-22 (CHClF2) and the 10.6 micrometer bands of SF6 employing a high-resolution Fourier-transform spectrometer. Temperature and total pressure have been varied to simulate conditions corresponding to tropospheric and stratospheric layers in the atmosphere. The kappa(sub nu) are compared with values measured by us previously using a tunable diode laser spectrometer and with the appropriate entries in HITRAN and GEISA, two of the databases known to the atmospheric scientist. The measured absolute intensities of the bands are compared with previously published values.
NASA Astrophysics Data System (ADS)
Kobayashi, Keiji
1997-05-01
The purpose of this study is to decrease and to remove OH ions and H2O in borosilicate glasses. Fluoride-containing borosilicate glasses followed by dry-air-bubbling showed the significant decrease of OH absorption bands around 3500 cm-1. The decrease of OH absorption bands was elucidated by the use of pyrohydrolysis reactions in these glasses where fluoride ions react with OH ions or H2O during melting. The rates of the decrease of OH absorption bands substantially depend on high valence cations of fluorides. Particularly, the decrease rates of OH absorption coefficients were in the order of ZrF4-containing glass>AlF3-containing glass>ZnF2-containing glass. ZrF4-containing glass treated by dry-air-bubbling showed a good capability to remove OH absorption band. Fluoride-containing glasses showed the low flow point in comparison with fluoride-free glasses.
Oil droplets transport due to irregular waves: Development of large-scale spreading coefficients.
Geng, Xiaolong; Boufadel, Michel C; Ozgokmen, Tamay; King, Thomas; Lee, Kenneth; Lu, Youyu; Zhao, Lin
2016-03-15
The movement of oil droplets due to waves and buoyancy was investigated by assuming an irregular sea state following a JONSWAP spectrum and four buoyancy values. A technique known as Wheeler stretching was used to model the movement of particles under the moving water surface. In each simulation, 500 particles were released and were tracked for a real time of 4.0 h. A Monte Carlo approach was used to obtain ensemble properties. It was found that small eddy diffusivities that decrease rapidly with depth generated the largest horizontal spreading of the plume. It was also found that large eddy diffusivities that decrease slowly with depth generated the smallest horizontal spreading coefficient of the plume. The increase in buoyancy resulted in a decrease in the horizontal spreading coefficient, which suggests that two-dimensional (horizontal) models that predict the transport of surface oil could be overestimating the spreading of oil. PMID:26795121
NASA Astrophysics Data System (ADS)
Dombrovsky, Leonid A.
2016-03-01
A significant uncertainty in the absorption coefficient of highly scattering dispersed materials is typical in the spectral ranges of very weak absorption. The traditional way to identify the main absorption and scattering characteristics of semi-transparent materials is based on spectral measurements of normal-hemispherical reflectance and transmittance for the material sample. Unfortunately this way cannot be used in the case of in vivo measurements of optical properties of biological tissues. A method suggested in the present paper is based on thermal response to the periodic radiative heating of the open surface of a semi-transparent material. It is shown that the period of a variation of the surface temperature is sensitive to the value of an average absorption coefficient in the surface layer. As a result, the monochromatic external irradiation combined with the surface temperature measurements can be used to retrieve the spectral values of absorption coefficient. Possible application of this method to porous semi-transparent ceramics is considered. An example problem is also solved to illustrate the applicability of this method to human skin. The approach suggested enables one to estimate an average absorption coefficient of human skin of a patient just before the thermal processing.
Yuan, Liu; Lu, Kun; Xia, Benzheng; Zhang, Jianqi; Wang, Zhen; Wang, Zaiyu; Deng, Dan; Fang, Jin; Zhu, Lingyun; Wei, Zhixiang
2016-07-01
Acceptor end-capping of oligomeric conjugated molecules is found to be an effective strategy for simultaneous spectral broadening, extinction coefficient enhancement, and energy level optimization, resulting in profoundly enhanced power conversion efficiencies (of 9.25% and 8.91%) compared to the original oligomers. This strategy is effective in overcoming the absorption disadvantage of oligomers and small molecules due to conjugation limitation. PMID:27172541
Wei, Jianwei; Lee, Zhongping
2015-02-01
The light absorption of phytoplankton and colored detrital matter (CDM), which includes contribution of gelbstoff and detrital matters, has distinctive yet overlapping features in the ultraviolet (UV) and visible domain. The CDM absorption (a(dg)) increases exponentially with decreasing wavelength while the absorption coefficient of phytoplankton (a(ph)) generally decreases toward the shorter bands for the range of 350-450 nm. It has long been envisioned that including ocean color measurements in the UV range may help the separation of these two components from the remotely sensed ocean color spectrum. An attempt is made in this study to provide an analytical assessment of this expectation. We started with the development of an absorption decomposition model [quasi-analytical algorithm (QAA)-UV], analogous to the QAA, that partitions the total absorption coefficient using information at bands 380 and 440 nm. Compared to the retrieval results relying on the absorption information at 410 and 440 nm of the original QAA, our analyses indicate that QAA-UV can improve the retrieval of a(ph) and a(dg), although the improvement in accuracy is not significant for values at 440 nm. The performance of the UV-based algorithm is further evaluated with in situ measurements. The limited improvement observed with the field measurements highlights that the separation of a(dg) and a(ph) is highly dependent on the accuracy of the ocean color measurements and the estimated total absorption coefficient. PMID:25967770
NASA Astrophysics Data System (ADS)
Vivacqua, Marco; Espinosa, Daniel; Martins Figueiredo Neto, Antônio
2012-06-01
We investigate the occurrence of the optical Kerr effect and two-photon absorption when an oil-based magnetic Fe3O4 nanoparticles colloidal suspension is illuminated with high intensity femtosecond laser pulses. The frequency of the pulses is controlled and the Z-scan technique is employed in our measurements of the nonlinear optical Kerr coefficient (n2) and two-photon absorption coefficient (β). From these values it was possible to calculate the real and imaginary parts of the third-order susceptibility. We observed that increasing the pulse frequency, additional physical processes take place, increasing artificially the absolute values of n2 and β. The experimental conditions are discussed to assure the obtention of reliable values of these nonlinear optical parameters, which may be useful in all-optical switching and optical power limiting applications.
NASA Astrophysics Data System (ADS)
Cacciani, Marco; Disarra, Alcide; Fiocco, Giorgio
1987-06-01
Instrumentation for the absolute measurement of the ozone absorption coefficient in the Huggins bands at different temperatures was set up. Ozone is produced with an electrical discharge and stored cryogenically; differential absorption measurements are carried out in a slowly evolving mixture of ozone and molecular oxygen. Results in the region 339 to 362 nm at temperatures between minus 30 and plus 40 C are reported. Results support Katayama's (1979) model of the transitions giving rise to the Huggins absorption bands of ozone. For measurements of atmospheric ozone profiles by DIAL techniques, the results on the temperature dependence of the absorption coefficient at the wavelength corresponding to the third harmonic of an NdYAG laser are stressed.
Mass-energy absorption coefficient and backscatter factor ratios for kilovoltage x-ray beams
NASA Astrophysics Data System (ADS)
Ma, C.-M.; Seuntjens, J. P.
1999-01-01
For low-energy (up to 150 kV) x-rays, the ratio of mass-energy absorption coefficients for water to air, , and the backscatter factor B are used in the conversion of air kerma, measured free-in-air, to water kerma on the surface of a water phantom. For clinical radiotherapy, similar conversion factors are needed for the determination of the absorbed dose to biological tissues on (or near) the surface of a human body. We have computed the ratios and B factor ratios for different biological tissues including muscle, soft tissue, lung, skin and bone relative to water. The ratios were obtained by integrating the respective mass-energy absorption coefficients over the in-air primary photon spectra. We have also calculated the ratios at different depths in a water phantom in order to convert the measured in-phantom water kerma to the absorbed dose to various biological tissues. The EGS4/DOSIMETER Monte Carlo code system has been used for the simulation of the energy fluence at different depths in a water phantom irradiated by a kilovoltage x-ray beam of variable beam quality (HVL: 0.1 mm Al-5 mm Cu), field size and source-surface distance (SSD). The same code was also used in the calculation of the B factor ratios, soft tissue to water and bone to water. The results show that the B factor for bone differs from the B factor for water by up to 20% for a 100 kV beam (HVL: 2.65 mm Al) with a 100 field. On the other hand, the difference in the B factor between water and soft tissue is insignificant (well within 1% generally). This means that the B factors for water may be directly used to
Rowley, R.L.; Adams, M.E.; Marshall, T.L.; Oscarson, J.L.; Wilding, W.V.; Anderson, D.J.
1997-03-01
Natural gas processors use amine treating processes to remove the acid gases H{sub 2}S and CO{sub 2} from gas streams. Absorption rates of gaseous CO{sub 2} into aqueous N-methyldiethanolamine (MDEA) solutions were measured in a quiescent, inverted-tube diffusiometer by monitoring the rate of pressure drop. The absorption rate was found to be insensitive to the diffusion coefficient of CO{sub 2} in solution but very sensitive to the diffusion rate of bicarbonate and protonated MDEA ions. Evidence also suggested that chemical reaction equilibrium is rapid relative to diffusion. A numerical model was developed on the basis of these observations. The model was used to regress diffusion coefficients of bicarbonate and protonated amine, which must be equivalent by electroneutrality arguments, from measured absorption rates. Complete modeling of the absorption process also required data for the diffusion coefficient of MDEA in water. These were measured using a Taylor dispersion apparatus. CO{sub 2} absorption rates and diffusion coefficients of bicarbonate and protonated MDEA were obtained at 298.2 K and 318.2 K in solutions containing 20, 35, and 50 mass % MDEA in water.
Majaron, Boris; Milanic, Matija
2007-02-21
Spectral variation of the sample absorption coefficient in mid-infrared (muIR) demands caution in photothermal radiometric measurements, because a constant muIR is regularly assumed in inverse analysis of the acquired signals. Adverse effects of such approximation were recently demonstrated in numerical simulations of pulsed photothermal radiometric (PPTR) temperature profiling in soft biological tissues, utilizing a general-purpose optimization code in the reconstruction process. We present here an original reconstruction code, which combines a conjugate gradient minimization algorithm with non-negativity constraint to the sought temperature vector. For the same test examples as in the former report (hyper-Gaussian temperature profiles, InSb detector with 3-5 microm acquisition band, signal-to-noise ratio SNR=300) we obtain markedly improved reconstruction results, both when using a constant value mueff and when the spectral variation muIR(lambda) is accounted for in the analysis. By comparing the results, we find that the former approach introduces observable artefacts, especially in the superficial part of the profile (z<100 microm). However, the artefacts are much less severe than previously reported and are almost absent in the case of a deeper, single-lobed test profile. We demonstrate that the observed artefacts do not result from sub-optimal selection of mueff, and that they vary with specific realizations of white noise added to the simulated signals. The same holds also for a two-lobed test profile. PMID:17264372
NASA Astrophysics Data System (ADS)
Fuente, Raquel; Apiñaniz, Estibaliz; Mendioroz, Arantza; Salazar, Agustín
2011-08-01
Modulated photothermal radiometry (PTR) has been widely used to measure the thermal diffusivity of bulk materials. The method is based on illuminating the sample with a plane light beam and measuring the infrared emission with an infrared detector. The amplitude and phase of the PTR voltage is recorded as a function of the modulation frequency and then fitted to the theoretical model. In this work, we test the ability of modulated PTR to retrieve simultaneously the thermal diffusivity and the optical absorption coefficient of homogeneous slabs. In order to eliminate the instrumental factor, self-normalization is used, i.e., the ratio of the PTR signal recorded at the rear and front surfaces. The influence of the multiple reflections of the light beam, the heat losses, and the transparency to infrared wavelengths are analyzed. Measurements performed on a wide variety of homogeneous materials, covering the whole range from transparent to opaque, confirm the validity of the method. In Part II of this work, the method is extended to multilayered materials.
Noise-driven optical absorption coefficients of impurity doped quantum dots
NASA Astrophysics Data System (ADS)
Ganguly, Jayanta; Saha, Surajit; Pal, Suvajit; Ghosh, Manas
2016-01-01
We make an extensive investigation of linear, third-order nonlinear, and total optical absorption coefficients (ACs) of impurity doped quantum dots (QDs) in presence and absence of noise. The noise invoked in the present study is a Gaussian white noise. The quantum dot is doped with repulsive Gaussian impurity. Noise has been introduced to the system additively and multiplicatively. A perpendicular magnetic field acts as a source of confinement and a static external electric field has been applied. The AC profiles have been studied as a function of incident photon energy when several important parameters such as optical intensity, electric field strength, magnetic field strength, confinement energy, dopant location, relaxation time, Al concentration, dopant potential, and noise strength take on different values. In addition, the role of mode of application of noise (additive/multiplicative) on the AC profiles has also been analyzed meticulously. The AC profiles often consist of a number of interesting observations such as one photon resonance enhancement, shift of AC peak position, variation of AC peak intensity, and bleaching of AC peak. However, presence of noise alters the features of AC profiles and leads to some interesting manifestations. Multiplicative noise brings about more complexity in the AC profiles than its additive counterpart. The observations indeed illuminate several useful aspects in the study of linear and nonlinear optical properties of doped QD systems, specially in presence of noise. The findings are expected to be quite relevant from a technological perspective.
NASA Astrophysics Data System (ADS)
Clark, Christopher J. R.; Schofield, Simon P.; Gomez, Haley L.; Davies, Jonathan I.
2016-06-01
We use the published photometry and spectroscopy of 22 galaxies in the Herschel Reference Survey to determine that the value of the dust mass absorption coefficient κd at a wavelength of 500 μm is kappa _{500} = 0.051^{+0.070}_{-0.026} m^{2 kg^{-1}}. We do so by taking advantage of the fact that the dust-to-metals ratio in the interstellar medium of galaxies appears to be constant. We argue that our value for κd supersedes that of James et al. - who pioneered this approach for determining κd - because we take advantage of superior data, and account for a number of significant systematic effects that they did not consider. We comprehensively incorporate all methodological and observational contributions to establish the uncertainty on our value, which represents a marked improvement on the oft-quoted `order-of-magnitude' uncertainty on κd. We find no evidence that the value of κd differs significantly between galaxies, or that it correlates with any other measured or derived galaxy properties. We note, however, that the availability of data limits our sample to relatively massive (109.7 < M⋆ < 1011.0 M⊙), high metallicity (8.61 < [ 12 + log_{10} fracOH ] < 8.86) galaxies; future work will allow us to investigate a wider range of systems.
NASA Astrophysics Data System (ADS)
Vuye, Cedric; Vanlanduit, Steve; Guillaume, Patrick
2009-06-01
When using optical measurements of the sound fields inside a glass tube, near the material under test, to estimate the reflection and absorption coefficients, not only these acoustical parameters but also confidence intervals can be determined. The sound fields are visualized using a scanning laser Doppler vibrometer (SLDV). In this paper the influence of different test signals on the quality of the results, obtained with this technique, is examined. The amount of data gathered during one measurement scan makes a thorough statistical analysis possible leading to the knowledge of confidence intervals. The use of a multi-sine, constructed on the resonance frequencies of the test tube, shows to be a very good alternative for the traditional periodic chirp. This signal offers the ability to obtain data for multiple frequencies in one measurement, without the danger of a low signal-to-noise ratio. The variability analysis in this paper clearly shows the advantages of the proposed multi-sine compared to the periodic chirp. The measurement procedure and the statistical analysis are validated by measuring the reflection ratio at a closed end and comparing the results with the theoretical value. Results of the testing of two building materials (an acoustic ceiling tile and linoleum) are presented and compared to supplier data.
NASA Astrophysics Data System (ADS)
Fairuz Budiman, Mohd; Hu, Weiguo; Igarashi, Makoto; Tsukamoto, Rikako; Isoda, Taiga; Itoh, Kohei M.; Yamashita, Ichiro; Murayama, Akihiro; Okada, Yoshitaka; Samukawa, Seiji
2012-02-01
A sub-10 nm, high-density, periodic silicon-nanodisc (Si-ND) array has been fabricated using a new top-down process, which involves a 2D array bio-template etching mask made of Listeria-Dps with a 4.5 nm diameter iron oxide core and damage-free neutral-beam etching (Si-ND diameter: 6.4 nm). An Si-ND array with an SiO2 matrix demonstrated more controllable optical bandgap energy due to the fine tunability of the Si-ND thickness and diameter. Unlike the case of shrinking Si-ND thickness, the case of shrinking Si-ND diameter simultaneously increased the optical absorption coefficient and the optical bandgap energy. The optical absorption coefficient became higher due to the decrease in the center-to-center distance of NDs to enhance wavefunction coupling. This means that our 6 nm diameter Si-ND structure can satisfy the strict requirements of optical bandgap energy control and high absorption coefficient for achieving realistic Si quantum dot solar cells.
Chazel, V; Houpert, P; Paquet, F; Ansoborlo, E
2001-01-01
In the Human Respiratory Tract Model (HRTM) described in ICRP Publication 66, time-dependent dissolution is described by three parameters: the fraction dissolved rapidly, fr, and the rapid and slow dissolution rates sr and ss. The effect of these parameters on the dose coefficient has been studied. A theoretical analysis was carried out to determine the sensitivity of the dose coefficient to variations in the values of these absorption parameters. Experimental values of the absorption parameters and the doses per unit intake (DPUI) were obtained from in vitro dissolution tests, or from in vivo experiments with rats, for five industrial uranium compounds UO2, U3O8, UO4, UF4 and a mixture of uranium oxides. These compounds were classified in terms of absorption types (F, M or S) according to ICRP. The overall result was that the factor which has the greatest influence on the dose coefficient was the slow dissolution rate ss. This was verified experimentally, with a variation of 20% to 55% for the DPUI according to the absorption type of the compound. In contrast, the rapid dissolution rate sr had little effect on the dose coefficient, excepted for Type F compounds. PMID:11487809
Several important optical terms such as "absorbance" and "absorption coefficient" are frequently used ambiguously in the current peer-reviewed literature. Since they are important terms that are required to derive other quantities such as the "apparent quantum yield" of photoprod...
NASA Technical Reports Server (NTRS)
Barstow, M. A.; Lewis, M.; Petre, R.
1983-01-01
Transmittances of thin-film filters fabricated for an extreme-UV astronomy sounding-rocket experiment yield values for the linear absorption coefficient of beryllium in the 50-300-A wavelength range, in which previous measurements are sparse. The inferred values are consistent with the lowest data previously published and may have important consequences for extreme-UV astronomers.
NASA Astrophysics Data System (ADS)
Ebrahimipour, Bahareh Alsadat; Askari, Hassan Ranjbar; Ramezani, Ali Behjat
2016-09-01
The interlevel absorption coefficient of CdSe/ZnS and ZnS/CdSe core-shell Quantum Dot (QD) in luminescent solar concentrators (LSCs) is reported. By considering the quantum confinement effects, the wave functions and eigenenergies of electrons in the nonperturebative system consists of a core-shell QD have been numerically calculated under the frame work of effective-mass approximation by solving a three-dimensional Schrӧdinger equation. And then the absorption coefficient is obtained under density matrix approximation considering in the polymer sheets of the concentrator including the core-shell QDs. The effect of the hetero-structure geometry upon the energy spectrum and absorption coefficient associated to interlevel transitions was also considered. The results show that the core-shell QDs can absorb the photons with higher energy in solar spectrum as compared to the inverted core-shell. And with a small shell layer diameter, the core-shell QDs produce larger linear absorption coefficients and consequently higher efficiency values, however it is inversed for inverted core-shell QDs. The work described here gives a detailed insight into the promise of QD-based LSCs and the optoelectronic devices applications.
NASA Technical Reports Server (NTRS)
Mcpeters, R. D.; Bass, A. M.
1982-01-01
Real structure is revealed, by an analysis of continuous scan data from the solar backscattered UV instrument on Nimbus 7, in the backscattered atmospheric albedo region between 300 and 310 nm where spectral anomalies have been reported in ground-based observation. The spectral anomalies are explainable as structure at the 1-5% level in the ozone absorption coefficient, as measured by Bass and Paur (1981). The new absorption coefficient measurements are judged to approach the 1%-level of accuracy in atmospheric radiation calculation, which should resolve discrepancies between different Dobson wavelength pairs and between different instruments and permit the more accurate analysis of such second-order effects as NO emission, SO2 absorption in polluted atmospheres, and Raman scattering effects.
How to measure and predict the molar absorption coefficient of a protein.
Pace, C. N.; Vajdos, F.; Fee, L.; Grimsley, G.; Gray, T.
1995-01-01
The molar absorption coefficient, epsilon, of a protein is usually based on concentrations measured by dry weight, nitrogen, or amino acid analysis. The studies reported here suggest that the Edelhoch method is the best method for measuring epsilon for a protein. (This method is described by Gill and von Hippel [1989, Anal Biochem 182:319-326] and is based on data from Edelhoch [1967, Biochemistry 6:1948-1954]). The absorbance of a protein at 280 nm depends on the content of Trp, Tyr, and cystine (disulfide bonds). The average epsilon values for these chromophores in a sample of 18 well-characterized proteins have been estimated, and the epsilon values in water, propanol, 6 M guanidine hydrochloride (GdnHCl), and 8 M urea have been measured. For Trp, the average epsilon values for the proteins are less than the epsilon values measured in any of the solvents. For Tyr, the average epsilon values for the proteins are intermediate between those measured in 6 M GdnHCl and those measured in propanol. Based on a sample of 116 measured epsilon values for 80 proteins, the epsilon at 280 nm of a folded protein in water, epsilon (280), can best be predicted with this equation: epsilon (280) (M-1 cm-1) = (#Trp)(5,500) + (#Tyr)(1,490) + (#cystine)(125) These epsilon (280) values are quite reliable for proteins containing Trp residues, and less reliable for proteins that do not. However, the Edelhoch method is convenient and accurate, and the best approach is to measure rather than predict epsilon. PMID:8563639
The absorption coefficient of the liquid N2 2.15-micron band and application to Triton
NASA Technical Reports Server (NTRS)
Grundy, William M.; Fink, Uwe
1991-01-01
The present measurements of the temperature dependence exhibited by the liquid N2 2.15-micron 2-0 collision-induced band's absorption coefficient and integrated absorption show the latter to be smaller than that of the N2 gas, and to decrease with decreasing temperature. Extrapolating this behavior to Triton's nominal surface temperature yields a new estimate of the N2-ice grain size on the Triton south polar cap; a mean N2 grain size of 0.7-3.0 cm is consistent with grain growth rate calculation results.
NASA Astrophysics Data System (ADS)
Andreo, Pedro; Burns, David T.; Salvat, Francesc
2012-04-01
A systematic analysis of the available data has been carried out for mass energy-absorption coefficients and their ratios for air, graphite and water for photon energies between 1 keV and 2 MeV, using representative kilovoltage x-ray spectra for mammography and diagnostic radiology below 100 kV, and for 192Ir and 60Co gamma-ray spectra. The aim of this work was to establish ‘an envelope of uncertainty’ based on the spread of the available data. Type A uncertainties were determined from the results of Monte Carlo (MC) calculations with the PENELOPE and EGSnrc systems, yielding mean values for µen/ρ with a given statistical standard uncertainty. Type B estimates were based on two groupings. The first grouping consisted of MC calculations based on a similar implementation but using different data and/or approximations. The second grouping was formed by various datasets, obtained by different authors or methods using the same or different basic data, and with different implementations (analytical, MC-based, or a combination of the two); these datasets were the compilations of NIST, Hubbell, Johns-Cunningham, Attix and Higgins, plus MC calculations with PENELOPE and EGSnrc. The combined standard uncertainty, uc, for the µen/ρ values for the mammography x-ray spectra is 2.5%, decreasing gradually to 1.6% for kilovoltage x-ray spectra up to 100 kV. For 60Co and 192Ir, uc is approximately 0.1%. The Type B uncertainty analysis for the ratios of µen/ρ values includes four methods of analysis and concludes that for the present data the assumption that the data interval represents 95% confidence limits is a good compromise. For the mammography x-ray spectra, the combined standard uncertainties of (µen/ρ)graphite,air and (µen/ρ)graphite,water are 1.5%, and 0.5% for (µen/ρ)water,air, decreasing gradually down to uc = 0.1% for the three µen/ρ ratios for the gamma-ray spectra. The present estimates are shown to coincide well with those of Hubbell (1977 Rad. Res
Velocity-Space Diffusion Coefficients Due to Full-Wave ICRF Fields in Toroidal Geometry
Harvey, R.W.; Jaeger, F.; Berry, L.A.; Batchelor, D.B.; D'Azevedo, E.; Carter, M.D.; Ershov, N.M.; Smirnov, A.P.; Bonoli, P.; Wright, J.C.; Smithe, D.N.
2005-09-26
Jaeger et al. have calculated bounce-averaged QL diffusion coefficients from AORSA full-wave fields, based on non-Maxwellian distributions from CQL3D Fokker-Planck code. A zero banana-width approximation is employed. Complementing this calculation, a fully numerical calculation of ion velocity diffusion coefficients using the full-wave fields in numerical tokamak equilibria has been implemented to determine the finite orbit width effects. The un-approximated Lorentz equation of motion is integrated to obtain the change in velocity after one complete poloidal transit of the tokamak. Averaging velocity changes over initial starting gyro-phase and toroidal angle gives bounce-averaged diffusion coefficients. The coefficients from the full-wave and Lorentz orbit methods are compared for an ITER DT second harmonic tritium ICRF heating case: the diffusion coefficients are similar in magnitude but reveal substantial finite orbit effects.
I-scan thermal lens experiment in the pulse regime for measuring two-photon absorption coefficient
NASA Astrophysics Data System (ADS)
Rodríguez, L.; Echevarria, L.; Fernandez, A.
2007-09-01
We present a new pump-probe mode-mismatched thermal lens method for pulse excitation aimed to the measurement of nonlinear absorption coefficient in optical materials. We develop a theoretical model based on the Fresnel diffraction approximation and their predictions are verified experimentally with samples of Rhodamine 6G and Rhodamine B in ethanol solution. The principal advantage of this technique is that it does not require any mechanical movement during measurement. Below we perform the new type of thermal lens experiment in the pulse regime for the measurement of nonlinear absorption coefficient in transparent samples and we demonstrate the validity of theoretical predictions using an alternative method to the classical thermal lens technique.
Lawniczak, Michał; Hul, Oleh; Bauch, Szymon; Seba, Petr; Sirko, Leszek
2008-05-01
We present the results of an experimental and numerical study of the distribution of the reflection coefficient P(R) and the distributions of the imaginary P(v) and the real P(u) parts of the Wigner reaction K matrix for irregular fully connected hexagon networks (graphs) in the presence of strong absorption. In the experiment we used microwave networks, which were built of coaxial cables and attenuators connected by joints. In the numerical calculations experimental networks were described by quantum fully connected hexagon graphs. The presence of absorption introduced by attenuators was modeled by optical potentials. The distribution of the reflection coefficient P(R) and the distributions of the reaction K matrix were obtained from measurements and numerical calculations of the scattering matrix S of the networks and graphs, respectively. We show that the experimental and numerical results are in good agreement with the exact analytic ones obtained within the framework of random matrix theory. PMID:18643145
NASA Technical Reports Server (NTRS)
Varanasi, Prasad
1992-01-01
Spectral absorption coefficients k(v) in the atmospheric window are reported for CFC-11 and CFC-12. Data obtained with a grating spectrometer are compared with NCAR cross sections and measurements of k(v) made with a tunable diode laser spectrometer at various temperature-pressure combinations representing tangent heights or layers in the atmosphere are presented. The results are suitable for atmospheric remote sensing and global warming studies.
NASA Technical Reports Server (NTRS)
Wan, Zhengming; Dozier, Jeff
1992-01-01
The effect of temperature-dependent molecular absorption coefficients on thermal infrared spectral signatures measured from satellite sensors is investigated by comparing results from the atmospheric transmission and radiance codes LOWTRAN and MODTRAN and the accurate multiple scattering radiative transfer model ATRAD for different atmospheric profiles. The sensors considered include the operational NOAA AVHRR and two research instruments planned for NASA's Earth Observing System (EOS): MODIS-N (Moderate Resolution Imaging Spectrometer-Nadir-Mode) and ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer). The difference in band transmittance is as large as 6 percent for some thermal bands within atmospheric windows and more than 30 percent near the edges of these atmospheric windows. The effect of temperature-dependent molecular absorption coefficients on satellite measurements of sea-surface temperature can exceed 0.6 K. Quantitative comparison and factor analysis indicate that more accurate measurements of molecular absorption coefficients and better radiative transfer simulation methods are needed to achieve SST accuracy of 0.3 K, as required for global numerical models of climate, and to develop land-surface temperature algorithms at the 1-K accuracy level.
NASA Astrophysics Data System (ADS)
Zhevstovskikh, I. V.; Okulov, V. I.; Gudkov, V. V.; Mayakin, V. Yu.; Sarychev, M. N.; Andriichuk, M. D.; Paranchich, L. D.
2015-05-01
The effects of the interaction of ultrasound with donor d electrons of cobalt impurity atoms at low concentrations in mercury selenide crystals have been investigated. The temperature dependences of the electronic contribution to the absorption coefficient at a frequency of 53 MHz in crystals with cobalt concentrations from 1018 to 1020 cm-3 and in the undoped crystal have been observed experimentally. It has been found that crystals with impurities are characterized by an anomalous nonmonotonic temperature dependence of the absorption coefficient of the slow transverse wave in a narrow temperature range near 10 K. A smooth monotonic temperature dependence has been observed for longitudinal and fast transverse waves. Based on the developed theoretical interpretation, it has been established that the anomaly in the temperature dependence of the absorption coefficient of a slow transverse wave is associated with the hybridization of impurity d states in the conduction band of the crystal. A comparison of the theoretical and experimental dependences has made it possible to determine the parameters characterizing the hybridized electronic states.
Levine, Zachary H.; Grantham, Steven; Tarrio, Charles; Paterson, David J.; McNulty, Ian; Levin, T. M.; Ankudinov, Alexei L.; Rehr, John J.
2003-01-01
The mass absorption coefficients of tungsten and tantalum were measured with soft x-ray photons from 1450 eV to 2350 eV using an undulator source. This region includes the M3, M4, and M5 absorption edges. X-ray absorption fine structure was calculated within a real-space multiple scattering formalism; the predicted structure was observed for tungsten and to a lesser degree tantalum as well. Separately, the effects of dynamic screening were observed as shown by an atomic calculation within the relativistic time-dependent local-density approximation. Dynamic screening effects influence the spectra at the 25 % level and are observed for both tungsten and tantalum. We applied these results to characterize spatially-resolved spectra of a tungsten integrated circuit interconnect obtained using a scanning transmission x-ray microscope. The results indicate tungsten fiducial markers were deposited into silica trenches with a depths of 50 % and 60 % of the markers’ heights.
Baba, Justin S; Koju, Vijay; John, Dwayne O
2016-01-01
The modulation of the state of polarization of photons due to scatter generates associated geometric phase that is being investigated as a means for decreasing the degree of uncertainty in back-projecting the paths traversed by photons detected in backscattered geometry. In our previous work, we established that polarimetrically detected Berry phase correlates with the mean photon penetration depth of the backscattered photons collected for image formation. In this work, we report on the impact of state-of-linear-polarization (SOLP) filtering on both the magnitude and population distributions of image forming detected photons as a function of the absorption coefficient of the scattering sample. The results, based on Berry phase tracking implemented Polarized Monte Carlo Code, indicate that sample absorption plays a significant role in the mean depth attained by the image forming backscattered detected photons.
The Correlation Coefficient as the Ratio of Two Means: An Interpretation Due to Galton and Brogden.
ERIC Educational Resources Information Center
Price, James M.; Nicewander, W. Alan
A standard interpretation of the coefficient of correlation may be obtained from the ratio of two variances. If it is assumed that two variables, X and Y, are bivariate normal and scaled to have zero means and unit variances, it can be shown that the correlation between X and Y is the ratio of two conditional means. Galton's statistical studies of…
Reducing Bias and Error in the Correlation Coefficient Due to Nonnormality
ERIC Educational Resources Information Center
Bishara, Anthony J.; Hittner, James B.
2015-01-01
It is more common for educational and psychological data to be nonnormal than to be approximately normal. This tendency may lead to bias and error in point estimates of the Pearson correlation coefficient. In a series of Monte Carlo simulations, the Pearson correlation was examined under conditions of normal and nonnormal data, and it was compared…
Figueroa, C.; Brizuela, H.; Heluani, S. P.
2014-05-21
The backscattering coefficient is a magnitude whose measurement is fundamental for the characterization of materials with techniques that make use of particle beams and particularly when performing microanalysis. In this work, we report the results of an analytic method to calculate the backscattering and absorption coefficients of electrons in similar conditions to those of electron probe microanalysis. Starting on a five level states ladder model in 3D, we deduced a set of integro-differential coupled equations of the coefficients with a method know as invariant embedding. By means of a procedure proposed by authors, called method of convergence, two types of approximate solutions for the set of equations, namely complete and simple solutions, can be obtained. Although the simple solutions were initially proposed as auxiliary forms to solve higher rank equations, they turned out to be also useful for the estimation of the aforementioned coefficients. In previous reports, we have presented results obtained with the complete solutions. In this paper, we present results obtained with the simple solutions of the coefficients, which exhibit a good degree of fit with the experimental data. Both the model and the calculation method presented here can be generalized to other techniques that make use of different sorts of particle beams.
Bendib, A.; Tahraoui, A.; Bendib, K.; Mohammed El Hadj, K.; Hueller, S.
2005-03-01
The transport coefficients of fully ionized plasmas under the influence of a high-frequency electric field are derived solving numerically the electron Fokker-Planck equation using a perturbation method, parametrized as a function of the electron mean-free-path {lambda}{sub ei} compared to the spatial scales L. The isotropic and anisotropic contributions of the inverse bremsstrahlung heating are considered. Electron-electron collision terms are kept in the analysis, which allows us to consider with sufficient accuracy to describe plasmas with arbitrary atomic number Z. Practical numerical fits of the transport coefficients are proposed as functions of Z and the collisionality parameter {lambda}{sub ei}/L.
Absorption of intense microwaves and ion acoustic turbulence due to heat transport
De Groot, J.S.; Liu, J.M.; Matte, J.P.
1994-02-04
Measurements and calculations of the inverse bremsstrahlung absorption of intense microwaves are presented. The isotropic component of the electron distribution becomes flat-topped in agreement with detailed Fokker-Planck calculations. The plasma heating is reduced due to the flat-topped distributions in agreement with calculations. The calculations show that the heat flux at high microwave powers is very large, q{sub max} {approx} 0.3 n{sub e}v{sub e}T{sub e}. A new particle model to, calculate the heat transport inhibition due to ion acoustic turbulence in ICF plasmas is also presented. One-dimensional PIC calculations of ion acoustic turbulence excited due to heat transport are presented. The 2-D PIC code is presently being used to perform calculations of heat flux inhibition due to ion acoustic turbulence.
NASA Astrophysics Data System (ADS)
Smagin, N. V.; Krutyansky, L. M.; Zelenova, Z. V.; Brysev, A. P.
2014-03-01
Acoustic absorption has been measured in a series of biological tissue specimens—porcine muscle, renal and fat tissues—by the standard insert-substitution method, as well as by ultrasonic phase conjugation. Comparison of the experimental results and revealed differences confirm the promise of using phase conjugate waves to measure acoustic losses in biological objects. It is demonstrated that in inhomogeneous tissues, the phase conjugation method makes it possible to obtain a more reliable estimate of dissipative losses.
NASA Astrophysics Data System (ADS)
Pérez Reyes, Ma. C.; Hernandez-Aguilar, C.; Dominguez-Pacheco, A.; Cruz-Orea, A.; Moreno Martínez, E.
2015-09-01
Laser light as a biostimulator has been applied in agriculture, and some scientific reports evidence its usefulness. A knowledge about seed optical parameters is of great relevance in the biostimulation process, because information can be provided about the light absorption of seeds. Thus, the objective of the present study was to determine the optical absorption coefficient (β ) of barley ( Hordeum vulgare L.) seeds by means of photoacoustic spectroscopy; these seeds were studied in two conditions: seeds in their natural color and seeds dyed with methylene blue. The seeds were biostimulated by a laser beam (650 nm wavelength) to evaluate the effects of pre-sowing biostimulation in natural mycobiota associated with different laser irradiation times (0 s, 60 s, 120 s, 240 s, and 480 s). The results of this research demonstrated changes in the optical parameters (absorption and penetration) that occur in the seeds by changing the natural condition to a dyed condition. The dyed seeds, by the methylene blue photosensitizer, become optically opaque, producing greater optical absorption at 650 nm which causes an increase in the effect of laser stimulation. The experimental results showed that the biggest mycobiota reduction (52 %) corresponded to dyed seeds irradiated with a laser for 120 s.
Absorption coefficients and band strengths for the 703 nm and 727 bands of methane at 77 K
O`Brien, J.J.; Singh, K.
1996-12-31
The technique of intracavity laser spectroscopy has been used to obtain methane absorption spectra for the vibrational overtone bands that occur around 703 nm and 727 nm. Absorption coefficients for the 690-742 nm range have been obtained for a sample temperature of 77 K at a spectral resolution of <0.02 cm{sup -1}. A new method of data analysis is utilized in obtaining the results. It involves deconvolving the many ILS spectral profiles that comprise the absorption bands and summing the results. Values averaged over 1 cm{sup -1} and 1 {Angstrom} intervals are provided. Band strengths also are obtained. The total intensities of the 703 and 727 nm bands are in reasonable agreement with previous laboratory determinations which were obtained for relatively high pressures of methane at room temperature using lower spectral resolution. The methane bands appear in the reflected sunlight spectra from the outer planets. Results averaged over 1 nm intervals are compared with other laboratory studies and with those derived from observations of the outer planets. The band profiles differ considerably from other laboratory results but are in good accord with the planetary observations. Laboratory spectra of methane at appropriate conditions are required for the proper interpretation of the observational data. Absorption spectra can provide some of the most sensitive diagnostic data on the atmospheres of those bodies.
NASA Astrophysics Data System (ADS)
Leid, Terrence Vincent
The emission of electron cyclotron radiation parallel to the magnetic field direction near the fundamental frequency from a fully ionized, multi-component plasma, is investigated for finite (omega)(,p)/(omega)(,c) within the Klimontovich formalism. Each species may have T(,(PARLL)) different from T(,(PERP)) and may possess a loss cone. We use a bi- maxwellian with an analytic loss cone for each component. In addition, the source function for a multi-component plasma is calculated. We find that for a Maxwellian distribution function the emission coefficient is that of a system of shielded charges. It is shown that only in the case of a tenuous Maxwellian plasma is the source function the Rayleigh-Jeans blackbody intensity. For the case of the Maxwellian we present experimental evidence for finite density emission, (omega)('2)(,p)/(omega)('2) >> (beta). We have constructed a computer code that solves the radiative transfer equation. The resulting power spectra are used as an aid in extracting from experimental data the temperature and density of the various components of the TMX-Upgrade end cell plasma. The code compares both the Ellis-Tsakiris scheme for computing the emission coefficient for a multi-component plasma and the finite density multi -component emission coefficient. The Ellis- Tsakiris scheme estimates the emission coefficient by assuming. that each species radiates independently of each other.('1) Results are presented for the case of the TMX -Upgrade tandem mirror device. ('1)R. F. Ellis and G. D. Tsakiris, Nucl. Fusion 23, 1115 (1984).
Enhancement of microbial motility due to speed-dependent nutrient absorption.
Di Salvo, Mario E; Condat, C A
2014-02-01
Marine microorganisms often reach high swimming speeds, either to take advantage of evanescent nutrient patches or to beat Brownian forces. Since this implies that a sizable part of their energetic budget must be allocated to motion, it is reasonable to assume that some fast-swimming microorganisms may increase their nutrient intake by increasing their speed v. We formulate a model to investigate this hypothesis and its consequences, finding the steady-state solutions and analyzing their stability. Surprisingly, we find that even modest increases in nutrient absorption may lead to a significant increase of the microbial speed. In fact, evaluations obtained using realistic parameter values for bacteria indicate that the speed increase due to the enhanced nutrient absorption may be quite large. PMID:24451235
Behavior of Propagation and Heating Due to Absorption of Ultrasound in Medium
NASA Astrophysics Data System (ADS)
Yamaya, Chiaki; Inoue, Hiroshi
2006-05-01
Recently, ultrasound waves have been put to practical use not only in diagnostic equipment but also in thermotherapy that uses the effect of ultrasound waves in a living body. The analysis of temperature rise due to the absorption of ultrasound in a soft tissue medium is an important analyzing object for the clarification of the effect of ultrasound waves in biological tissues and the estimation of medium constants. Three-dimensional simulations by the finite-difference time-domain (FDTD) method which used the equations that considers the absorption attenuation based on acoustic basic equations (ABEs) and the Westervelt equation have been performed. The consistency between the ABEs and the Westervelt equation is confirmed. The results of temperature measurement that uses glycerin as the absorbing medium of ultrasound are compared with those of FDTD simulation. The temperature distribution obtained by FDTD simulation almost corresponds to that obtained by experiment.
Selective spatial damping of propagating kink waves due to resonant absorption
NASA Astrophysics Data System (ADS)
Terradas, J.; Goossens, M.; Verth, G.
2010-12-01
Context. There is observational evidence of propagating kink waves driven by photospheric motions. These disturbances, interpreted as kink magnetohydrodynamic (MHD) waves are attenuated as they propagate upwards in the solar corona. Aims: We show that resonant absorption provides a simple explanation to the spatial damping of these waves. Methods: Kink MHD waves are studied using a cylindrical model of solar magnetic flux tubes, which includes a non-uniform layer at the tube boundary. Assuming that the frequency is real and the longitudinal wavenumber complex, the damping length and damping per wavelength produced by resonant absorption are analytically calculated in the thin tube (TT) approximation, valid for coronal waves. This assumption is relaxed in the case of chromospheric tube waves and filament thread waves. Results: The damping length of propagating kink waves due to resonant absorption is a monotonically decreasing function of frequency. For kink waves with low frequencies, the damping length is exactly inversely proportional to frequency, and we denote this as the TGV relation. When moving to high frequencies, the TGV relation continues to be an exceptionally good approximation of the actual dependency of the damping length on frequency. This dependency means that resonant absorption is selective as it favours low-frequency waves and can efficiently remove high-frequency waves from a broad band spectrum of kink waves. The efficiency of the damping due to resonant absorption depends on the properties of the equilibrium model, in particular on the width of the non-uniform layer and the steepness of the variation in the local Alfvén speed. Conclusions: Resonant absorption is an effective mechanism for the spatial damping of propagating kink waves. It is selective because the damping length is inversely proportional to frequency so that the damping becomes more severe with increasing frequency. This means that radial inhomogeneity can cause solar
Kabi, Sanjib; Perera, A. G. Unil
2015-03-28
The intersublevel absorption peak energy and absorption coefficient of non-uniform quantum dot (QD) ensembles are calculated analytically. The effect of size variations and size distribution of QDs on their energy states is analyzed. The dots are considered as a quantum box with finite potential at the barriers and the size distribution described by a Gaussian function. The influence of the aspect ratio (base to height ratio) of the QDs on the optical transitions is studied. Our model predicts the dot size (height and base) accurately to determine the absorption peaks and corresponding absorption coefficient. We also compute the absorption coefficient of the QD with different size distributions to verify the results calculated using this model with the reported experimental and other theoretical results.
NASA Astrophysics Data System (ADS)
Kim, J. H.; Kim, S. W.; Yoon, S. C.; Park, R.; Ogren, J. A.
2014-12-01
Filter-based instrument, such as aethalometer, is being widely used to measure equivalent black carbon(EBC) mass concentration and aerosol absorption coefficient(AAC). However, many other previous studies have poited that AAC and its aerosol absorption angstrom exponent(AAE) are strongly affected by the multi-scattering correction factor(C) when we retrieve AAC from aethalometer EBC mass concentration measurement(Weingartner et al., 2003; Arnott et al., 2005; Schmid et al., 2006; Coen et al., 2010). We determined the C value using the method given in Weingartner et al. (2003) by comparing 7-wavelngth aethalometer (AE-31, Magee sci.) to 3-wavelength Photo-Acoustic Soot Spectrometer (PASS-3, DMT) at Gosan climate observatory, Korea(GCO) during Cheju ABC plume-asian monsoon experiment(CAPMEX) campaign(August and September, 2008). In this study, C was estimated to be 4.04 ± 1.68 at 532 nm and AAC retrieved with this value was decreased as approximately 100% as than that retrieved with soot case value from Weingartner et al (2003). We compared the AAC determined from aethalomter measurements to that from collocated Continuous Light Absorption Photometer (CLAP) measurements from January 2012 to December 2013 at GCO and found good agreement in both AAC and AAE. This result suggests the determination of site-specific C is crucially needed when we calculate AAC from aethalometer measurements.
NASA Astrophysics Data System (ADS)
Fukutomi, D.; Ishii, K.; Awazu, K.
2015-12-01
Anisotropy factor g, one of the optical properties of biological tissues, is the most important parameter to accurately determine scattering coefficient μs in the inverse Monte Carlo (iMC) simulation. It has been reported that g has wavelength and absorption dependence, however, there are few attempts in order to calculate μs of biological tissue considering the wavelength and absorption dependence of g. In this study, the scattering angular distributions of biological tissue phantoms were measured in order to determine g by using goniometric measurements with three polarization conditions at strongly and weakly absorbing wavelengths of hemoglobin. Then, optical properties, especially, μs were measured by integrating sphere measurements and iMC simulation in order to confirm the influence of measured g on optical properties in comparison of with general value of g (0.9) for soft biological tissue. Consequently, it was found that μs was overestimated at strongly absorbing wavelength, however, μs was underestimated at weakly absorbing wavelength if the g was not considered its wavelength and absorption dependence.
Inverse Bremsstrahlung in Astrophysical Plasmas: The Absorption Coefficients and Gaunt Factors
NASA Astrophysics Data System (ADS)
Mihajlov, A. A.; Srećković, V. A.; Sakan, N. M.
2015-12-01
The electron-ion inverse Bremsstrahlung is considered here as a factor of the influence on the opacity of the different stellar atmospheres and other astrophysical plasmas. It is shown that this process can be successfully described in the frames of cut-off Coulomb potential model within the regions of the electron densities and temperatures. The relevant quantum mechanical method of the calculation of the corresponding spectral coefficient processes is described and discussed. The results obtained for the plasmas with the electron densities from 1014 c m -3 to 2ṡ1019 c m -3 and temperatures from 5ṡ103 K to 3ṡ104 K in the wavelength region 100 nm< λ<3000 nm are presented. Also, these results can be of interest for different laboratory plasmas.
NASA Astrophysics Data System (ADS)
Rosati, B.; Weingartner, E.; Gysel, M.; Tillmann, R.; Mentel, T. F.; Decesari, S.; Marinoni, A.; Gobbi, G. P.; Fierli, F.; Cairo, F.; Bucci, S.; Zanatta, M.; Größ, J.; Baltensperger, U.
2014-12-01
Aerosol particles influence the Earth's radiation budget by interacting with the incoming sunlight. The chemical composition and size of aerosol particles determine their potential to scatter and absorb radiation as well as their capability to take up water (Zieger et al., 2011). If particles are hygroscopic their optical properties will be altered at enhanced relative humidities (RH) due to the increase in size and change in index of refraction. It is known that RH but also the chemical composition of aerosols change with altitude (Morgan et al., 2010) which makes it very important to investigate optical properties at different heights. Within the Pan-European Gas-Aerosols-climate interaction Study (PEGASOS) a set of instruments was installed on a Zeppelin to investigate changes of light scattering and absorption in the planetary boundary layer. In order to obtain the scattering properties, Mie calculations were performed for size distributions recorded with SMPS (scanning mobility particle sizer) and WELAS (optical size spectrometer). The index of refraction and the hygroscopicity of the aerosol particles were measured with the white-light humidified optical particle spectrometer (WHOPS). These measurements further allowed studying the RH-dependence of the optical properties. Moreover, a seven wavelength portable aethalometer was employed to determine the light absorption properties of the aerosol. In this work we will present vertical profiles of scattering and absorption coefficients measured during Zeppelin flights of the PEGASOS campaigns in Italy in 2012. Additionally comparisons with ground based measurements from nephelometers and aethalometers, as well as remote sensing results will be shown. W.T. Morgan et al., Enhancement of the aerosol direct radiative effect by semi-volatile aerosol components: Airborne measurements in North-Western Europe, Atmospheric Chemistry and Physics 10(2010), pp. 8151-8171.P. Zieger et al., Comparison of ambient aerosol
Absorption coefficients of the methane-nitrogen binary ice system: Implications for Pluto
NASA Astrophysics Data System (ADS)
Protopapa, S.; Grundy, W. M.; Tegler, S. C.; Bergonio, J. M.
2015-06-01
The methane-nitrogen phase diagram of Prokhvatilov and Yantsevich (1983. Sov. J. Low Temp. Phys. 9, 94-98) indicates that at temperatures relevant to the surfaces of icy dwarf planets like Pluto, two phases contribute to the methane absorptions: nitrogen saturated with methane N2 ‾ :CH4 and methane saturated with nitrogen CH4 ‾ :N2 . No optical constants are available so far for the latter component limiting construction of a proper model, in compliance with thermodynamic equilibrium considerations. New optical constants for solid solutions of methane diluted in nitrogen (N2 :CH4) and nitrogen diluted in methane (CH4 :N2) are presented at temperatures between 40 and 90 K, in the wavelength range 1.1-2.7 μm at different mixing ratios. These optical constants are derived from transmission measurements of crystals grown from the liquid phase in closed cells. A systematic study of the changes of methane and nitrogen solid mixtures spectral behavior with mixing ratio and temperature is presented.
NASA Astrophysics Data System (ADS)
Montes-Hugo, Martin; Xie, Huxiang
2015-10-01
The inversion of individual inherent optical properties (IOPs) is very challenging in optically complex waters and within the violet spectral range (i.e., 380-450 nm) due to the strong light attenuation caused by chromophoric dissolved organic matter, nonalgal particulates, and phytoplankton. Here we present a technique to better discriminate light absorption contributions due to phytoplankton based on a hybrid model (QAA-hybrid) that combines regional Saint Lawrence System estimates of IOPs derived from a quasi-analytical algorithm (hereafter QAA-SLE) and empirical relationships between salinity and IOPs. Preliminary results in the Saint Lawrence System during May 2000 and April 2001 showed that QAA-hybrid estimates of phytoplankton absorption coefficient at 443 nm have a smaller bias with respect to in situ measurements (root-mean-square deviation, RMSD = 0.156) than those derived from QAA-SLE (RMSD = 0.341). These results were valid for surface waters (i.e., 0-5 m depth) of the lower estuary with a salinity and chlorophyll-a concentration range of 22-28 psu and 2.1-13.8 mg m-3, respectively.
NASA Astrophysics Data System (ADS)
Wróbel, P.; Antosiewicz, T. J.; Stefaniuk, T.; Ciesielski, A.; Iwan, A.; Wronkowska, A. A.; Wronkowski, A.; Szoplik, T.
2015-05-01
In photovoltaic devices, metal nanoparticles embedded in a semiconductor layer allow the enhancement of solar-toelectric energy conversion efficiency due to enhanced light absorption via a prolonged optical path, enhanced electric fields near the metallic inclusions, direct injection of hot electrons, or local heating. Here we pursue the first two avenues. In the first, light scattered at an angle beyond the critical angle for reflection is coupled into the semiconductor layer and confined within such planar waveguide up to possible exciton generation. In the second, light is trapped by the excitation of localized surface plasmons on metal nanoparticles leading to enhanced near-field plasmon-exciton coupling at the peak of the plasmon resonance. We report on results of a numerical experiment on light absorption in polymer- (fullerene derivative) blends, using the 3D FDTD method, where exact optical parameters of the materials involved are taken from our recent measurements. In simulations we investigate light absorption in randomly distributed metal nanoparticles dispersed in polyazomethine-(fullerene derivative) blends, which serve as active layers in bulkheterojunction polymer solar cells. In the study Ag and Al nanoparticles of different diameters and fill factors are diffused in two air-stable aromatic polyazomethines with different chemical structures (abbreviated S9POF and S15POF) mixed with phenyl-C61-butyric acid methyl ester (PCBM) or [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). The mixtures are spin coated on a 100 nm thick Al layer deposited on a fused silica substrate. Optical constants of the active layers are taken from spectroscopic ellipsometry and reflectance measurements using a rotating analyzer type ellipsometer with auto-retarder performed in the wavelength range from 225 nm to 2200 nm. The permittivities of Ag and Al particles of diameters from 20 to 60 nm are assumed to be equal to those measured on 100 to 200 nm thick metal films.
Falcao-Filho, E.L.; Araujo, Cid B. de; Bosco, C.A.C.; Maciel, G.S.; Acioli, L.H.; Nalin, M.; Messaddeq, Y.
2005-01-01
Antimony glasses based on the composition Sb{sub 2}O{sub 3}-SbPO{sub 4} were prepared and characterized. The samples present high refractive index, good transmission from 380 to 2000 nm, and high thermal stability. The nonlinear refractive index, n{sub 2}, of the samples was studied using the optical Kerr shutter technique at 800 nm. The third-order correlation signals between pump and probe pulses indicate ultrafast response (<100 fs) for all compositions. Enhancement of n{sub 2} was observed by adding lead oxide to the Sb{sub 2}O{sub 3}-SbPO{sub 4} composition. Large values of n{sub 2}{approx_equal}10{sup -14} cm{sup 2}/W and negligible two-photon absorption coefficients (smaller than 0.01 cm/GW) were determined for all samples. The glass compositions studied present appropriate figure-of-merit for all-optical switching applications.
NASA Astrophysics Data System (ADS)
McGillen, Max R.; Bernard, François; Fleming, Eric L.; Burkholder, James B.
2015-07-01
HCFC-133a (CF3CH2Cl), an ozone-depleting substance, is primarily removed from the atmosphere by gas-phase reaction with OH radicals and by UV photolysis. The rate coefficient, k, for the OH + HCFC-133a reaction was measured between 233 and 379 K and is given by k(T) = (9.32 ± 0.8) × 10-13 exp(-(1296 ± 28)/T), where k(296 K) was measured to be (1.10 ± 0.02) × 10-14 (cm3 molecule-1 s-1) (2σ precision uncertainty). The HCFC-133a UV absorption spectrum was measured between 184.95 and 240 nm at 213-323 K, and a spectrum parameterization is presented. The HCFC-133a atmospheric loss processes, lifetime, ozone depletion potential, and uncertainties were evaluated using a 2-D atmospheric model. The global annually averaged steady state lifetime and ozone depletion potential (ODP) were determined to be 4.45 (4.04-4.90) years and 0.017 (±0.001), respectively, where the ranges are based solely on the 2σ uncertainty in the kinetic and photochemical parameters. The infrared absorption spectrum of HCFC-133a was measured, and its global warming potential was determined to be 380 on the 100 year time horizon.
NASA Astrophysics Data System (ADS)
Fukutomi, Daichi; Ishii, Katsunori; Awazu, Kunio
2016-04-01
The anisotropy factor g, one of the optical properties of biological tissues, has a strong influence on the calculation of the scattering coefficient μ s in inverse Monte Carlo (iMC) simulations. It has been reported that g has the wavelength and absorption dependence; however, few attempts have been made to calculate μ s using g values by taking the wavelength and absorption dependence into account. In this study, the angular distributions of scattered light for biological tissue phantoms containing hemoglobin as a light absorber were measured by a goniometric optical setup at strongly (405 nm) and weakly (664 nm) absorbing wavelengths to obtain g. Subsequently, the optical properties were calculated with the measured values of g by integrating sphere measurements and an iMC simulation, and compared with the results obtained with a conventional g value of 0.9. The μ s values with measured g were overestimated at the strongly absorbing wavelength, but underestimated at the weakly absorbing wavelength if 0.9 was used in the iMC simulation.
NASA Astrophysics Data System (ADS)
Villanueva, Yolanda; Hondebrink, Erwin; Petersen, Wilma; Steenbergen, Wiendelt
2015-03-01
A method for simultaneously measuring the absorption coefficient μa and Grüneisen parameter Γ of biological absorbers in photoacoustics is designed and implemented using a coupled-integrating sphere system. A soft transparent tube with inner diameter of 0.58mm is used to mount the liquid absorbing sample horizontally through the cavity of two similar and adjacent integrating spheres. One sphere is used for measuring the sample's μa using a continuous halogen light source and a spectrometer fiber coupled to the input and output ports, respectively. The other sphere is used for simultaneous photoacoustic measurement of the sample's Γ using an incident pulsed light with wavelength of 750nm and a flat transducer with central frequency of 5MHz. Absolute optical energy and pressure measurements are not necessary. However, the derived equations for determining the sample's μa and Γ require calibration of the setup using aqueous ink dilutions. Initial measurements are done with biological samples relevant to biomedical imaging such as human whole blood, joint and cyst fluids. Absorption of joint and cyst fluids is enhanced using a contrast agent like aqueous indocyanine green dye solution. For blood sample, measured values of μa = 0.580 +/- 0.016 mm-1 and Γ = 0.166 +/- 0.006 are within the range of values reported in literature. Measurements with the absorbing joint and cyst fluid samples give Γ values close to 0.12, which is similar to that of water and plasma.
NASA Astrophysics Data System (ADS)
Wei, Jianwei; Lee, Zhongping; Ondrusek, Michael; Mannino, Antonio; Tzortziou, Maria; Armstrong, Roy
2016-03-01
The spectral slope of the absorption coefficient of colored dissolved and detrital material (CDM), Scdm (units: nm-1), is an important optical parameter for characterizing the absorption spectral shape of CDM. Although highly variable in natural waters, in most remote sensing algorithms, this slope is either kept as a constant or empirically modeled with multiband ocean color in the visible domain. In this study, we explore the potential of semianalytically retrieving Scdm with added ocean color information in the ultraviolet (UV) range between 360 and 400 nm. Unique features of hyperspectral remote sensing reflectance in the UV-visible wavelengths (360-500 nm) have been observed in various waters across a range of coastal and open ocean environments. Our data and analyses indicate that ocean color in the UV domain is particularly sensitive to the variation of the CDM spectral slope. Here, we used a synthesized dataset to show that adding UV wavelengths to the ocean color measurements will improve the retrieval of Scdm from remote sensing reflectance considerably, while the spectral band settings of past and current satellite ocean color sensors cannot fully account for the spectral variation of remote sensing reflectance. Results of this effort support the concept to include UV wavelengths in the next generation of satellite ocean color sensors.
NASA Astrophysics Data System (ADS)
Zhong, Min; Jang, Myoseon
2011-08-01
A method for measuring an aerosol light absorption coefficient ( B a) has been developed using a conventional UV-visible spectrometer equipped with an integrating sphere covering a wide range of wavelengths (280-800 nm). The feasibility of the proposed method was evaluated in both the transmittance mode (TUV-IS) and the reflective mode (RUV-IS) using the reference aerosol known for the cross-sectional area. The aerosol was collected on a conventional filter and measured for B a values. The resulting RUV-IS method was applied to measure light absorption of secondary organic aerosol (SOA). SOA was produced through photooxidation of different precursor hydrocarbons such as toluene, d-limonene and α-pinene in the presence of NO x (60-70 ppb) and inorganic seed aerosol using a 2-m 3 indoor Teflon film chamber. Of the three precursor hydrocarbons, the B a value of toluene SOA (0.574 m 2 g -1 at 350 nm) was the highest compared with B a values for α-pinene SOA (0.029 m 2 g -1) and d-limonene SOA (0.038 m 2 g -1). When d-limonene SOA or toluene SOA was internally mixed with neutral [(NH 4) 2SO 4] or acidic inorganic seed (NH 4HSO 4:H 2SO 4 = 1:1 by mole), the SOA showed 2-3 times greater B a values at 350 nm than the SOA with no seed. Aerosol aging with a light source for this study reduced B a values of SOA (e.g., on average 10% for toluene SOA and 30% for d-limonene SOA within 4 h). Overall, weak absorption appeared for chamber-generated SOA over wavelengths ranging from 280 to 550 nm, which fall into the sunlight spectrum.
Mean absorption coefficient of H2O-air-MgCl2/CaCl2/NaCl thermal plasmas
NASA Astrophysics Data System (ADS)
Hannachi, R.; Cressault, Y.; Salem, D.; Teulet, Ph; Béji, L.; Ben Lakhdar, Z.
2012-12-01
Under the local thermodynamic equilibrium hypothesis, the mean absorption coefficients (MACs) were calculated for H2O-air-MgCl2/CaCl2/NaCl thermal plasmas in a temperature range from 300 to 30 000 K and at atmospheric pressure. The MACs were computed under the hypothesis of isothermal plasmas which allows a good description of the radiation absorbed in cold regions. In this study, we took into account the absorption radiation resulting from the atomic continuum, molecular continuum, atomic lines and some molecular bands. Free-free transitions (bremsstrahlung) and free-bound (electron-ion recombination and electron attachment) or bound-free transitions in terms of absorption were considered for the calculation of atomic continuum. For bound-bound transitions, natural, resonance, van der Waals, Stark and Doppler effects were taken into account for the line broadenings while the escape factors were used to treat the self-absorption of the resonance lines. Molecular continuum was considered for the main molecules (H2, O2, N2, OH, NO, H2O, N2O, NO2, O3, NO3 and N2O5) whereas we studied only diatomic systems O2, N2, NO and N_2^+ for the absorption of molecular bands. The influence of the proportion of MgCl2, CaCl2 or NaCl in a water-air mixture was analysed as the effect of the strong self-absorbed resonance lines of the alkaline salts (Ca, Ca+, Na, Na+, Mg, Mg+, Cl and Cl+). Our results show that a low concentration of alkaline salts (less than 1% in molar proportions) in the plasma increased the MACs at low temperatures (T < 10 000 K) due to the resonance lines mainly localized in the near-UV and visible spectral regions in opposition to hydrogen, oxygen or nitrogen species for which 90% of them exist in ultraviolet. In addition to the atomic and molecular continuum, the absorption radiation of molecular bands is important at low temperatures.
NASA Astrophysics Data System (ADS)
Huffman, H. Dale
Using the IMPROVE network aerosol data from rural or remote sites across the United States, the ratio of the optically measured light absorption coefficient ( σa) to the elemental carbon measured by Thermal/Optical Reflectance (TOR) analysis consistently indicates an absorption efficiency that is twice the accepted value of 10m 2g -1. Correlations between σa and the TOR carbon strongly suggest that the discrepancy is due to an underevaluation of light-absorbing carbon rather than to an overestimation of σa or a real, higher value of the absorption efficiency. In particular, past doubts about the accuracy and precision of the IMPROVE σa measurement are here shown to be unsupported by the IMPROVE data. The large empirical correction that is applied to this σa measurement, for multiple scattering effects due to filter mass loading, is given a new explanation as the effect of an increasing forward scattering fraction as sample thickness increases. The old explanation of shadowing by overlying particles in the sample is rejected as having just the opposite effect to that needed to explain the correction. The use of a diffuse source rather than a laser beam is indicated as a way to avoid the large empirical correction of σa. Modelling of the light absorption by TOR carbon measurements, at twelve remote sites over a wide portion of the western United States, suggests the following errors in the current interpretation of TOR analysis for these sites: (1) The pyrolysis correction, based upon optical reflectance monitoring, appears to be largely wrong; and (2) The carbon evolving between 450 and 550°C in a pure helium atmosphere, currently interpreted as organic and therefore non-light-absorbing, appears to be as strongly light-absorbing as elemental carbon. However, the present analysis indicates that for a large majority (˜90%) of samples the light-absorbing carbons, as reinterpreted herein, are not only measured accurately by TOR, they are also reasonably well
Time-dependent excitation and ionization modelling of absorption-line variability due to GRB 080310
NASA Astrophysics Data System (ADS)
Vreeswijk, P. M.; Ledoux, C.; Raassen, A. J. J.; Smette, A.; De Cia, A.; Woźniak, P. R.; Fox, A. J.; Vestrand, W. T.; Jakobsson, P.
2013-01-01
We model the time-variable absorption of Fe II, Fe III, Si II, C II and Cr II detected in Ultraviolet and Visual Echelle Spectrograph (UVES) spectra of gamma-ray burst (GRB) 080310, with the afterglow radiation exciting and ionizing the interstellar medium in the host galaxy at a redshift of z = 2.42743. To estimate the rest-frame afterglow brightness as a function of time, we use a combination of the optical VRI photometry obtained by the RAPTOR-T telescope array, which is presented in this paper, and Swift's X-Ray Telescope (XRT) observations. Excitation alone, which has been successfully applied for a handful of other GRBs, fails to describe the observed column density evolution in the case of GRB 080310. Inclusion of ionization is required to explain the column density decrease of all observed Fe II levels (including the ground state 6D9/2) and increase of the Fe III 7S3 level. The large population of ions in this latter level (up to 10% of all Fe III) can only be explained through ionization of Fe II, as a large fraction of the ionized Fe II ions (we calculate 31% using the Flexible Atomic and Cowan codes) initially populate the 7S3 level of Fe III rather than the ground state. This channel for producing a significant Fe III 7S3 level population may be relevant for other objects in which absorption lines from this level, the UV34 triplet, are observed, such as broad absorption line (BAL) quasars and η Carinae. This provides conclusive evidence for time-variable ionization in the circumburst medium, which to date has not been convincingly detected. However, the best-fit distance of the neutral absorbing cloud to the GRB is 200-400 pc, i.e. similar to GRB-absorber distance estimates for GRBs without any evidence for ionization. We find that the presence of time-varying ionization in GRB 080310 is likely due to a combination of the super-solar iron abundance ([Fe/H] = +0.2) and the low H I column density (log N(H i) = 18.7) in the host of GRB 080310. Finally
NASA Astrophysics Data System (ADS)
Yahya, I.; Kusuma, J. I.; Harjana; Kristiani, R.; Hanina, R.
2016-02-01
This paper emphasizes the influence of tubular shaped microresonators phononic crystal insertion on the sound absorption coefficient of profiled sound absorber. A simple cubic and two different bodies centered cubic phononic crystal lattice model were analyzed in a laboratory test procedure. The experiment was conducted by using transfer function based two microphone impedance tube method refer to ASTM E-1050-98. The results show that sound absorption coefficient increase significantly at the mid and high-frequency band (600 - 700 Hz) and (1 - 1.6 kHz) when tubular shaped microresonator phononic crystal inserted into the tested sound absorber element. The increment phenomena related to multi-resonance effect that occurs when sound waves propagate through the phononic crystal lattice model that produce multiple reflections and scattering in mid and high-frequency band which increases the sound absorption coefficient accordingly
NASA Astrophysics Data System (ADS)
Shatsky, A. V.
2016-08-01
We consider the problem of the influence of diffraction effects on the result of measuring the absorption coefficient of ultrasound in weakly absorbing liquids by the pulse method. Diffraction attenuation of an ultrasonic signal in a measuring cell using solid-state delay lines is calculated. It is shown that the use of delay lines of the ultrasonic signal leads to a considerable distortion of the measured absorption coefficient in the low-frequency range from the true value and can either overestimate or underestimate the results.
Prisutova, Jevgenija; Horoshenkov, Kirill; Groby, Jean-Philippe; Brouard, Bruno
2014-12-01
The measurement of acoustic material characteristics using a standard impedance tube method is generally limited to the plane wave regime below the tube cut-on frequency. This implies that the size of the tube and, consequently, the size of the material specimen must remain smaller than a half of the wavelength. This paper presents a method that enables the extension of the frequency range beyond the plane wave regime by at least a factor of 3, so that the size of the material specimen can be much larger than the wavelength. The proposed method is based on measuring of the sound pressure at different axial locations and applying the spatial Fourier transform. A normal mode decomposition approach is used together with an optimization algorithm to minimize the discrepancy between the measured and predicted sound pressure spectra. This allows the frequency and angle dependent reflection and absorption coefficients of the material specimen to be calculated in an extended frequency range. The method has been tested successfully on samples of melamine foam and wood fiber. The measured data are in close agreement with the predictions by the equivalent fluid model for the acoustical properties of porous media. PMID:25480044
NASA Astrophysics Data System (ADS)
Okawa, Shinpei; Hirasawa, Takeshi; Kushibiki, Toshihiro; Ishihara, Miya
2015-03-01
Quantification of the optical properties of the tissues and blood by noninvasive photoacoustic (PA) imaging may provide useful information for screening and early diagnosis of diseases. Linearized 2D image reconstruction algorithm based on PA wave equation and the photon diffusion equation (PDE) can reconstruct the image with computational cost smaller than a method based on 3D radiative transfer equation. However, the reconstructed image is affected by the differences between the actual and assumed light propagations. A quantitative capability of a linearized 2D image reconstruction was investigated and discussed by the numerical simulations and the phantom experiment in this study. The numerical simulations with the 3D Monte Carlo (MC) simulation and the 2D finite element calculation of the PDE were carried out. The phantom experiment was also conducted. In the phantom experiment, the PA pressures were acquired by a probe which had an optical fiber for illumination and the ring shaped P(VDF-TrFE) ultrasound transducer. The measured object was made of Intralipid and Indocyanine green. In the numerical simulations, it was shown that the linearized image reconstruction method recovered the absorption coefficients with alleviating the dependency of the PA amplitude on the depth of the photon absorber. The linearized image reconstruction method worked effectively under the light propagation calculated by 3D MC simulation, although some errors occurred. The phantom experiments validated the result of the numerical simulations.
NASA Astrophysics Data System (ADS)
Fuente, R.; Mendioroz, A.; Apiñaniz, E.; Salazar, A.
2012-11-01
Modulated photothermal radiometry (PTR) and a modulated photopyroelectric (PPE) technique have been widely used to measure the thermal diffusivity of bulk materials. The method is based on illuminating the sample with a plane light beam and measuring the infrared emission with an infrared detector (PTR) or the electric voltage produced by a pyroelectric sensor in contact with the sample (PPE). The amplitude and phase of both photothermal signals are recorded as a function of the modulation frequency and then fitted to the theoretical model. In this work, we compare the ability of modulated PTR and PPE to retrieve simultaneously the thermal diffusivity and the optical absorption coefficient of homogeneous slabs. In order to eliminate the instrumental factor, self-normalization is used, i.e., the ratio of the photothermal signal recorded at the rear and front surfaces. The influence of the multiple reflections of the light beam and the transparency to infrared wavelengths are analyzed. Measurements performed on a wide variety of homogeneous materials, transparent and opaque, good and bad thermal conductors, confirm the validity of the method. The advantages and disadvantages of both techniques are discussed.
Photoacoustic Experimental System to Confirm Infrared Absorption Due to Greenhouse Gases
ERIC Educational Resources Information Center
Kaneko, Fumitoshi; Monjushiro, Hideaki; Nishiyama, Masayoshi; Kasai, Toshio; Harris, Harold H.
2010-01-01
An experimental system for detecting infrared absorption using the photoacoustic (PA) effect is described. It is aimed for use at high-school level to illustrate the difference in infrared (IR) absorption among the gases contained in the atmosphere in connection with the greenhouse effect. The experimental system can be built with readily…
Shitzer, Avraham
2006-03-01
The wind-chill index (WCI), developed in Antarctica in the 1940s and recently updated by the weather services in the USA and Canada, expresses the enhancement of heat loss in cold climates from exposed body parts, e.g., face, due to wind. The index provides a simple and practical means for assessing the thermal effects of wind on humans outdoors. It is also used for indicating weather conditions that may pose adverse risks of freezing at subfreezing environmental temperatures. Values of the WCI depend on a number of parameters, i.e, temperatures, physical properties of the air, wind speed, etc., and on insolation and evaporation. This paper focuses on the effects of various empirical correlations used in the literature for calculating the convective heat transfer coefficients between humans and their environment. Insolation and evaporation are not included in the presentation. Large differences in calculated values among these correlations are demonstrated and quantified. Steady-state wind-chill-equivalent temperatures (WCETs) are estimated by a simple, one-dimensional heat-conducting hollow-cylindrical model using these empirical correlations. Partial comparison of these values with the published "new" WCETs is presented. The variability of the estimated WCETs, due to different correlations employed to calculate them, is clearly demonstrated. The results of this study clearly suggest the need for establishing a "gold standard" for estimating convective heat exchange between exposed body elements and the cold and windy environment. This should be done prior to the introduction and adoption of further modifications to WCETs and indices. Correlations to estimate the convective heat transfer coefficients between exposed body parts of humans in windy and cold environments influence the WCETs and need to be standardized. PMID:16397760
NASA Astrophysics Data System (ADS)
Shitzer, Avraham
2006-03-01
The wind-chill index (WCI), developed in Antarctica in the 1940s and recently updated by the weather services in the USA and Canada, expresses the enhancement of heat loss in cold climates from exposed body parts, e.g., face, due to wind. The index provides a simple and practical means for assessing the thermal effects of wind on humans outdoors. It is also used for indicating weather conditions that may pose adverse risks of freezing at subfreezing environmental temperatures. Values of the WCI depend on a number of parameters, i.e, temperatures, physical properties of the air, wind speed, etc., and on insolation and evaporation. This paper focuses on the effects of various empirical correlations used in the literature for calculating the convective heat transfer coefficients between humans and their environment. Insolation and evaporation are not included in the presentation. Large differences in calculated values among these correlations are demonstrated and quantified. Steady-state wind-chill-equivalent temperatures (WCETs) are estimated by a simple, one-dimensional heat-conducting hollow-cylindrical model using these empirical correlations. Partial comparison of these values with the published “new” WCETs is presented. The variability of the estimated WCETs, due to different correlations employed to calculate them, is clearly demonstrated. The results of this study clearly suggest the need for establishing a “gold standard” for estimating convective heat exchange between exposed body elements and the cold and windy environment. This should be done prior to the introduction and adoption of further modifications to WCETs and indices. Correlations to estimate the convective heat transfer coefficients between exposed body parts of humans in windy and cold environments influence the WCETs and need to be standardized.
Bénilan, Y; Bruston, P; Raulin, F; Courtin, R; Guillemin, J C
1995-01-01
The interpretation of mid-UV albedo spectra of planetary atmospheres, especially that of Titan, is the main goal of the SIPAT (Spectroscopie uv d'Interet Prebiologique dans l'Atmosphere de Titan) research program. This laboratory experiment has been developed in order to systematically determine the absorption coefficients of molecular compounds which are potential absorbers of scattered sunlight in planetary atmospheres, with high spectral resolution, and at various temperatures below room temperature. From photochemical modelling and experimental simulations, we may expect triacetylene (C6H2) to be present in the atmosphere of Titan, even though it has not yet been detected. We present here the first determination of the absolute absorption coefficient of that compound in the 200-300 nm range and at two temperatures (296 K and 233 K). The temperature dependence of the C6H2 absorption coefficient in that wavelength range is compared to that previously observed in the case of cyanoacetylene (HC3N). We then discuss the implications of the present results for the interpretation of Titan UV spectra, where it appears that large uncertainities can be introduced either by the presence of trace impurities in laboratory samples or by the variations of absorption coefficients with temperature. PMID:11538441
NASA Astrophysics Data System (ADS)
sharma, N.; Arnold, I. J.; Moosmuller, H.; Arnott, P.; Mazzoleni, C.
2012-12-01
the Desert Research Institute, measuring absorption and scattering coefficients of kerosene soot and sodium chloride aerosols. As a reference system we used a commercial three-wavelength photoacoustic-nephelometer instrument (DMT Inc.). Here, we present the results of this laboratory intercomparison.
NASA Technical Reports Server (NTRS)
Wilkerson, T. D.; Schwemmer, G.; Gentry, B.; Giver, L. P.
1979-01-01
Intensities and N2 collision-broadening coefficients are measured for 62 water vapor absorption lines between 715 and 732 nm potentially applicable to laser remote sensing of atmospheric water vapor. Absolute line strengths and widths were determined from spectra corrected for instrument resolution, air-path absorption and Lorentz and Doppler broadening for pure water vapor and water vapor-nitrogen mixtures in a multipass absorption cell with a base path length of 25 m (White cell). Line strengths are observed to range from 4 x 10 to the -25th to 4 x 10 to the -23rd kayser/molecule per sq cm, and collision broadening coefficients are found to be approximately equal to 0.1 kayser/atm.
Ashoor, Mansour; Asgari, Afrouz; Khorshidi, Abdollah; Rezaei, Ali
2015-01-01
Purpose: Estimation of Compton attenuation and the photoelectric absorption coefficients were explored at various depths. Methods: A new method was proposed for estimating the depth based on the convolution of two exponential functions, namely convolution of scattering and primary functions (CSPF), which the convolved result will conform to the photopeak region of energy spectrum with the variable energy-window widths (EWWs) and a theory on the scattering cross-section. The triple energy-windows (TEW) and extended triple energy-windows scatter correction (ETEW) methods were used to estimate the scattered and primary photons according to the energy spectra at various depths due to a better performance than the other methods in nuclear medicine. For this purpose, the energy spectra were employed, and a distinct phantom along with a technetium-99 m source was simulated by Monte Carlo method. Results: The simulated results indicate that the EWW, used to calculate the scattered and primary counts in terms of the integral operators on the functions, was proportional to the depth as an exponential function. The depth will be calculated by the combination of either TEW or ETEW and proposed method resulting in the distinct energy-window. The EWWs for primary photons were in good agreement with those of scattered photons at the same as depths. The average errors between these windows for both methods TEW, and ETEW were 7.25% and 6.03% at different depths, respectively. The EWW value for functions of scattered and primary photons was reduced by increasing the depth in the CSPF method. Conclusions: This coefficient may be an index for the scattering cross-section. PMID:26170567
NASA Astrophysics Data System (ADS)
More, Chaitali V.; Lokhande, Rajkumar M.; Pawar, Pravina. P.
2016-05-01
Mass attenuation coefficients of amino acids such as n-acetyl-l-tryptophan, n-acetyl-l-tyrosine and d-tryptophan were measured in the energy range 0.122-1.330 MeV. NaI (Tl) scintillation detection system was used to detect gamma rays with a resolution of 8.2% at 0.662 MeV. The measured attenuation coefficient values were then used to determine the mass energy-absorption coefficients (σa,en) and average atomic energy-absorption cross sections (μen/ρ) of the amino acids. Theoretical values were calculated based on XCOM data. Theoretical and experimental values are found to be in good agreement.
Radiative absorption enhancements due to the mixing state of atmospheric black carbon
Cappa, Christopher D.; Onasch, Timothy B.; Massoli, Paola; Worsnop, Douglas R.; Bates, Timothy S.; Cross, Eben S.; Davidovits, Paul; Hakala, Jani; Hayden, Katherine; Jobson, Bertram Thomas; Kolesar, K. R.; Lack, D. A.; Lerner, Brian M.; Li, Shao-Meng; Mellon, Daniel; Nuaaman, Ibraheem; Olfert, Jason; Petaja, Tuukka; Quinn, P. K.; Song, Chen; Subramanian, R.; Williams, Eric; Zaveri, Rahul A.
2012-08-30
Atmospheric particulate black carbon (BC) leads to warming of the Earth's climate. Many models that include forcing by BC assume that non-BC aerosol species internally mixed with BC enhance BC absorption, often by a factor of {approx}2. However, such model estimates have yet to be clearly validated through atmospheric observations. Here, we report on direct measurements of the absorption enhancement (Eabs) of BC in the atmosphere around California and find that it is negligible at 532 nm and much smaller than predicted from theoretical calculations that are uniquely constrained by observations, suggesting that the warming by BC may be significantly overestimated (factor of 2) in many climate models. Additionally, non-BC particulate matter is found to contribute {approx}10% to the total absorption at 405 nm.
Modeling Ionospheric HF/VHF Radio-Wave Absorption due to Solar Energetic Proton Events
NASA Astrophysics Data System (ADS)
Sauer, H. H.; Wilkinson, D. C.
2007-12-01
Simple, one-parameter, algorithms have been applied to the observed energetic proton flux as provided by the GOES series of satellites to yield estimates of the high latitude HF and VHF radio-wave absorption for both day and night respectively. The twilight response is obtained as a bi-linear function of the solar zenith angle at the observation positions, and the latitude dependence of the absorption region near the edge of the absorbing region (the polar caps) are estimated from extant models of geomagnetic cut-offs and their dependence on geomagnetic activity. The approximate inverse square frequency dependence of ionospheric absorption is used to translate across the HF/VHF range and predictions of the minimum duration of events are determined. Calculations of the polar cap absorption of HF radio waves have been performed for eleven larger Solar Energetic Proton (SEP) events during the period from 1992 through 2002 and the results compared to observations of 30 MHz Riometers operated by the AFGL and located at Thule, Greenland. While discrepancies between the estimated and observed absorption using these procedures occur, especially at low absorption levels, this model has operational value in view of its simplicity and its being the only extant model, to our knowledge, which treats solar-illumination, geomagnetic cutoff variation, and frequency effects, at least to first order. Specimen graphical representations of the north and south polar caps illustrate the output of the model for the peak of the 12 December 2006 solar proton event. Given sufficient interest, improvements to the methodology used here are practicable and could be expected to achieve accuracies to the order of 25% or better.
Absorption lines in the spectrum of Q0248 + 4302 due to a foreground tidal tail
Sargent, W.L.W.; Steidel, C.C. California Univ., Berkeley )
1990-08-01
The strong absorption lines in the spectrum of the quasar Q0248 + 4302 are discussed. The absorption has been shown to be produced in a sinuous tidal tail which emanates from the nearby galaxy pair G0248 + 4302A,B. There is a velocity difference of about 260 km/s between the systemic redshift of the interacting galaxies and the redshift of the tidal tail at a galactocentric distance of about 11/h kpc. The large velocity spread observed in the tail gas is probably responsible for the unusual strength of the interstellar lines. 18 refs.
Hayashi, Masayuki; Onodera, Kazunari; Suzuki, Kengo; Kataoka, Yuko; Tachikawa, Kazushige; Riku, Shigeo; Tanaka, Hiroshi
2011-01-01
An 82-year-old Japanese man had consciousness disturbance due to severe hypothyroidism triggered by percutaneous absorption of iodine from an iodine-containing ointment used in diabetic gangrene treatment. Laboratory data revealed extremely high urinary iodine concentrations, and chronic thyroiditis-induced hypothyroidism. Excess iodine intake can also cause hypothyroidism. It was unlikely that iodine intoxication or Hashimoto's encephalopathy had caused the consciousness disturbance. The patient regained consciousness after discontinuing the use of the ointment and commencing thyroid hormone therapy. We conclude that consciousness disturbance resulted from severe hypothyroidism caused by chronic thyroiditis and excess iodine absorption. PMID:22041370
NASA Technical Reports Server (NTRS)
Giver, L. P.; Gentry, B.; Schwemmer, G.; Wilkerson, T. D.
1982-01-01
Intensities were measured for 97 lines of H2O vapor between 932 and 961 nm. The lines were selected for their potential usefulness for remote laser measurements of H2O vapor in the earth's atmosphere. The spectra were obtained with several different H2O vapor abundances and N2 broadening gas pressures; the spectral resolution was 0.046/cm FWHM. Measured H2O line intensities range from 7 x 10 to the -25th to 7 x 10 to the -22nd/cm per (molecules/sq cm). H2O self-broadening coefficients were measured for 13 of these strongest lines; the mean value was 0.5/cm per atm. N2-collision-broadening coefficients were measured for 73 lines, and the average was 0.11 cm per atm HWHM. Pressure shifts in air were determined for a sample of six lines between 948 and 950 nm; these lines shift to lower frequency by an amount comparable to 0.1 of the collision-broadened widths measured in air or N2. The measured intensities of many lines of 300-000 band are much larger than expected from prior computations, in some cases by over an order of magnitude. Coriolis interactions with the stronger 201-000 band appear to be the primary cause of the enhancement of these line intensities.
Bulk damage and absorption in fused silica due to high-power laser applications
NASA Astrophysics Data System (ADS)
Nürnberg, F.; Kühn, B.; Langner, A.; Altwein, M.; Schötz, G.; Takke, R.; Thomas, S.; Vydra, J.
2015-11-01
Laser fusion projects are heading for IR optics with high broadband transmission, high shock and temperature resistance, long laser durability, and best purity. For this application, fused silica is an excellent choice. The energy density threshold on IR laser optics is mainly influenced by the purity and homogeneity of the fused silica. The absorption behavior regarding the hydroxyl content was studied for various synthetic fused silica grades. The main absorption influenced by OH vibrational excitation leads to different IR attenuations for OH-rich and low-OH fused silica. Industrial laser systems aim for the maximum energy extraction possible. Heraeus Quarzglas developed an Yb-doped fused silica fiber to support this growing market. But the performance of laser welding and cutting systems is fundamentally limited by beam quality and stability of focus. Since absorption in the optical components of optical systems has a detrimental effect on the laser focus shift, the beam energy loss and the resulting heating has to be minimized both in the bulk materials and at the coated surfaces. In collaboration with a laser research institute, an optical finisher and end users, photo thermal absorption measurements on coated samples of different fused silica grades were performed to investigate the influence of basic material properties on the absorption level. High purity, synthetic fused silica is as well the material of choice for optical components designed for DUV applications (wavelength range 160 nm - 260 nm). For higher light intensities, e.g. provided by Excimer lasers, UV photons may generate defect centers that effect the optical properties during usage, resulting in an aging of the optical components (UV radiation damage). Powerful Excimer lasers require optical materials that can withstand photon energy close to the band gap and the high intensity of the short pulse length. The UV transmission loss is restricted to the DUV wavelength range below 300 nm and
NASA Astrophysics Data System (ADS)
Pawlak, M.
2015-01-01
In this paper, a non-contact method that allows to determine the carrier concentration in CdSe crystals is presented. The method relies on the measurement of the effective infrared absorption coefficient by means of the photothermal infrared radiometry (PTR). In order to obtain the effective infrared absorption coefficient and thermal diffusivity, the frequency characteristics of the PTR signal were analyzed in the frame of a one-dimensional heat transport model for infrared semitransparent crystals. The carrier concentrations were estimated using a theory introduced by Ruda and a recently proposed normalization procedure for the PTR signal. The deduced carrier concentrations of the investigated CdSe crystals are in reasonable agreement with those obtained using Hall measurements and infrared spectroscopy. The method presented in this paper can also be applied to other semiconductors with the carrier concentration in the range of 1014-1017 cm-3.
NASA Astrophysics Data System (ADS)
Elperin, Tov; Fominykh, Andrew; Krasovitov, Boris
2016-04-01
We analyze the effects of irreversible chemical reactions of the first and higher orders and aqueous-phase dissociation reactions on the rate of trace gas scavenging by rain in the atmosphere with non-uniform concentration and temperature. We employ an one-dimensional model of precipitation scavenging of chemically active soluble gaseous pollutants that is valid for small gradients of temperature and concentration in the atmosphere. It is demonstrated that transient altitudinal distribution of concentration under the influence of rain is determined by the partial hyperbolic differential equation of the first order. Scavenging coefficients are calculated for wet removal of chlorine, nitrogen dioxide and sulfur dioxide for the exponential and linear initial altitudinal distributions of trace gases concentration in the atmosphere and linear and uniform altitudinal temperature distributions. Theoretical predictions of the dependence of the magnitude of the scavenging coefficient on rain intensity for sulfur dioxide are in a good agreement with the available atmospheric measurements.
Abbas Ghaleb, Khalil; Georges, Joseph
2006-01-01
Two-photon absorption of the solvent under pulsed-laser excitation at 266 nm produces a high background thermal lens signal interfering with the analyte signal. Discrimination of both solvent and analyte signals along with calibration of the photothermal response has allowed the determination of the two-photon absorption coefficient of ethanol. The obtained value, 3.0x10(-10) cm W-1, is close to the literature values obtained from transmittance measurements using picosecond or femtosecond laser pulses. PMID:16454917
NASA Technical Reports Server (NTRS)
Pan, Xiaoju; Mannino, Antonio; Russ, Mary E.; Hooker, Stanford B.
2008-01-01
At present, satellite remote sensing of coastal water quality and constituent concentration is subject to large errors as compared to the capability of satellite sensors in oceanic waters. In this study, field measurements collected on a series of cruises within U.S. southern Middle Atlantic Bight (SMAB) were applied to improve retrievals of satellite ocean color products in order to examine the factors that regulate the bio-optical properties within the continental shelf waters of the SMAB. The first objective was to develop improvements in satellite retrievals of absorption coefficients of phytoplankton (a(sub ph)), colored dissolved organic matter (CDOM) (a(sub g)), non-pigmented particles (a(sub d)), and non-pigmented particles plus CDOM (a(sub dg)), and chlorophyll a concentration ([Chl_a]). Several algorithms were compared to derive constituent absorption coefficients from remote sensing reflectance (R(sub rs)) ratios. The validation match-ups showed that the mean absolute percent differences (MAPD) were typically less than 35%, although higher errors were found for a(sub d) retrievals. Seasonal and spatial variability of satellite-derived absorption coefficients and [Chl_a] was apparent and consistent with field data. CDOM is a major contributor to the bio-optical properties of the SMAB, accounting for 35-70% of total light absorption by particles plus CDOM at 443 nm, as compared to 30-45% for phytoplankton and 0-20% for non-pigmented particles. The overestimation of [Chl_a] from the operational satellite algorithms may be attributed to the strong CDOM absorption in this region. River discharge is important in controlling the bio-optical environment, but cannot explain all of the regional and seasonal variability of biogeochemical constituents in the SMAB.
Kulp, T.J.; Shinn, J.
1995-04-01
The accurate characterization of the latent infrared (IR) absorption in the atmospheric window regions continues to be an area of research interest for the global climate modeling community. In the window between 8 and 14 {mu}m, this absorption can be attributed primarily to water vapor. It consists of (1) weak lines originating from the edge of the water vapor pure rotational band (at low wavenumbers) and the trailing P-branch of the v{sub 2} rovibrational band (at the high-wavenumber boundary of the window); and (2) the water vapor continuum absorption. The goal of our project has been to improve our quantitative and physical understanding of both of these absorption processes. Specifically, our immediate aims are to fill gaps in the experimental radiative transfer databases pertaining to the line parameters (i.e., line intensities and broadening coefficients) and to the self- and foreign-broadened water vapor continuum. To accomplish our goals, we have made long-pathlength absorption measurements using a Fourier transform infrared spectrometer (FTIR) (for the continuum and line measurements, at low resolution) and a tunable diode laser absorption spectrometer (TDLAS) (for the line measurements, at high resolution). These measurements were made on gas samples contained in a 400-m maximum pathlength Horn Pimentel multipass cell designed and constructed for this project.
NASA Technical Reports Server (NTRS)
Temma, T.; Baines, K. H.; Butler, R. A. H.; Brown, L. R.; Sagui, L.; Kleiner, I.
2006-01-01
PH3 exponential sum k coefficients were computed between 2750 and 3550/cm (2.82-3.64 (microns), in view of future application to radiative transfer analyses of Jupiter and Saturn in a phosphine absorption band near 3 microns. The temperature and pressure of this data set cover the ranges from 80 to 350 K and from 10 (exp -3)to 10(exp 1) bars, respectively. Transmission uncertainty incurred by the use of the k coefficients is smaller than a few percent as long as the radiation is confined above an altitude of a few bars in the giant planets. In spectral regions of weak absorption at high pressures close to 10 bars, contributions from far wings of strong absorption lines must be carefully taken into account. Our data set helps map the three-dimensional distribution of PH3 on the giant planets, revealing their global atmospheric dynamics extending down to the deep interior. The complete k coefficient data set of this work is available at the Web site of the NASA Planetary Data System Atmospheres Node.
Tunable Optical Limiting Action due to Non-linear Absorption in ZnO/Ag Nanocomposites
NASA Astrophysics Data System (ADS)
Radhu, S.; Vijayan, C.; Sandeep, Suchand; Philip, Reji
2011-07-01
ZnO/Ag nanocomposites with different silver concentration are successfully synthesized by solvothermal method. The characterization of the as- synthesized samples is done using XRD, UV-visible spectroscopy and HRTEM and the results indicate that the composites consist of silver nanoparticles attached to the ZnO nanoparticles. The optical non-linearity in these samples is studied using open aperture Z-scan technique and the experimental results agree well with a theoretical model involving two- photon absorption. It is found that the parameters of optical limiting can be tuned in a broad band by varying the silver concentration in the samples.
NASA Technical Reports Server (NTRS)
Surinov, Y. A.; Sosnovyy, N. V.
1975-01-01
Local and average radiation functions, which represent purely geometric characteristics of the radiating system, are used to determine the absorptivity in a system of bodies separated by an attenuating medium.
NASA Technical Reports Server (NTRS)
Baines, Kevin H.; West, Robert A.; Giver, Lawrence P.; Moreno, Fernando
1993-01-01
Near-infrared 10/cm resolution spectra of methane obtained at various temperatures, pressures, and abundances are fit to a quasi-random narrow-band model. Exponential-sum absorption coefficients for three temperatures (112, 188, and 295 K), and 20 pressures from 0.0001 to 5.6 bars, applicable to the cold environments of the major planets, are then derived from the band model for the 230 wavelengths measured from 1.6 to 2.5 microns. RMS deviations between the laboratory and the exponential-sum synthetic transmissions are reported for the best fitting 50 wavelengths. Deviations relevant to broadband, 1-percent spectral resolution observations are also presented. The validity of exponential-sum coefficients derived from broadband (10/cm) transmission data is demonstrated via direct comparison with line-by-line calculations. The complete atlas of coefficients is available from the Planetary Data System-Planetary Atmospheres Discipline Node.
NASA Astrophysics Data System (ADS)
Thomas, S.; Koch-Mueller, M.; Reichart, P.; Rhede, D.; Thomas, R.
2007-12-01
Conventionally applied Infrared (IR) calibrations [1, 2] for quantitative water analyses in solids are established on hydrous minerals and glasses with several wt% water. These calibrations are based on a negative correlation between the IR molar absorption coefficient (ɛ) for water and the mean wavenumber of the corresponding OH pattern. The correlation reflects the dependence of the OH band position on the appropriate O- H...O distances and thereby the magnitude of the dipole momentum which is proportional to the band intensity. However, it has been observed that these calibrations can not be adopted to nominally anhydrous minerals (NAMs) [3].To study the potential dependence of ɛ on structure and chemistry in NAMs we synthesized olivine and SiO2 polymorphs with specific isolated hydroxyl point defects, e.g. quartz, coesite and stishovite with B3++H+=Si4+ and/or Al3++H+=Si4+ substitutions. Experiments were performed with water in excess in piston cylinder and multi-anvil presses. Single crystal IR spectra demonstrate that we successfully managed to seperate generally complex OH patterns as e.g. observed in natural quartz and synthetic coesite. We quantified sample water contents of both natural samples and our run products by applying proton-proton-scattering [4], confocal microRaman spectroscopy [5] and Secondary Ion mass spectrometry. Resulting water concentrations were used to calculate new mineral specific ɛs. For olivine with the mean wavenumber of 3517 cm-1 we determined an ɛ value of 41,000±5,000 lmol-1H2Ocm-2. Quantification of olivine with the mean wavenumber of 3550 cm-1 in contrast resulted in an ɛ value of 47,000±1,000 lmol-1H2Ocm-2. Taking into account previous studies [6, 7] there is evidence to suggest a linear wavenumber dependent correlation for olivine, where ɛ increases with decreasing wavenumber. In case of the SiO2 system it turns out that the magnitude of ɛ within one structure type is independent of the liable OH point defect and
Enhancement of microbial motility due to advection-dependent nutrient absorption
NASA Astrophysics Data System (ADS)
Condat, Carlos A.; di Salvo, Mario E.
2014-03-01
In their classical work, Berg and Purcell [Biophys. J. 20, 193 (1977)] concluded that the motion of a small microorganism would not significantly increase its nutrient uptake rate, if the nutrient consisted of high diffusivity particles. As a result, it has been generally assumed that nutrient transport to small microorganisms such as bacteria is dominated by molecular diffusion and that swimming and feeding currents play a negligible role. On the other hand, recent studies have found that flagellar motion may increase advection-mediated uptake. We formulate a model to investigate the hypothesis that fast-moving microbes may enhance their swimming speed by taking advantage of advection to increase nutrient absorption. Surprisingly, using realistic parameter values for bacteria and algae, we find that even modest increases in nutrient absorption may lead to a significant increase of the microbial speed. We also show that, optimally, the rate of effective energy transfer to the microbial propulsion system should be proportional to the speed for slow motion, while it should be proportional to a power of the speed close to two for fast motion. We are grateful to SECyT-UNC and CONICET, Argentina, for financial support.
Changes of color and water-absorption of Hungarian porous limestone due to biomineralization
NASA Astrophysics Data System (ADS)
Juhász, P.; Kopecskó, K.
2013-12-01
Bacteria induced calcium carbonate precipitation nowadays is a widely examined process being a possible alternative for traditional stone conservation methods. While research has been mostly limited to laboratory measurements, application connected, further in situ experiments should be performed in order to evaluate the applicability of the method. In our experiment, several bio-based treating compounds were compared, which have already been analyzed in different laboratories. Method for the treatment was based on the treatment of a French research group, and the compounds were applied on Hungarian porous limestone slabs, in situ. For inoculation bacteria strains Bacillus cereus and Myxococcus xanthus were used, and non-inoculated compounds were also analyzed. After the treatment, specimens were analyzed by means of discoloration effect, water absorption and migration characteristics. Almost all the treating compounds gave favorable or acceptable results for the examined properties, comparing to the properties measured in the non-cured state. Measurements on the chromatic- and on the water absorption aspects gave significant results, while further measurements are running for the more exact evaluation of the migration characteristics, i.e. effective migration depth and wetted volume.
NASA Astrophysics Data System (ADS)
Utry, N.; Ajtai, T.; Pintér, M.; Tombácz, E.; Illés, E.; Bozóki, Z.; Szabó, G.
2015-01-01
Mass-specific optical absorption coefficients (MACs) and the imaginary part (κ) of the refractive indices of various mineral dust components including silicate clays (illite, kaolin and bentonite), oxides (quartz, hematite and rutile), and carbonate (limestone) were determined at the wavelengths of 1064, 532, 355 and 266 nm. The MAC values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA) instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. Values of κ were calculated from the measured and particle-loss-corrected data by using a Mie-theory-based retrieval algorithm. The determined values could be used for comparisons with calculated wavelength-dependent κ values typically deduced from bulk-phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk-phase measurements.
Ivascu, I R; Matei, C E; Patachia, M; Bratu, A M; Dumitras, D C
2016-06-15
Absorption coefficients of the ethanol vapors at atmospheric pressure and room temperature were measured by photoacoustic technique using a cw, line-tunable, frequency-stabilized CO2 laser as radiation source. The spectrum of the employed CO2 laser includes 54 lines with wavelengths in the infrared region of 9.2-10.8μm and power levels up to 4.7W. Measurements revealed a predominant absorption for ethanol within 9.4μm band of the CO2 laser spectrum, where the highest values of the absorption coefficients were recorded: 3.68cm(-1)atm(-1) at 9R(20) line and 3.65cm(-1)atm(-1) at 9R(22) line. The estimated detection range covers six orders of magnitude, from a minimum of 30ppbV to a maximum of 4% concentration of ethanol in nitrogen, which proves the suitability of the photoacoustic technique for accurate measurements of the ethanol concentration in various applications. PMID:27045783
NASA Astrophysics Data System (ADS)
Ivascu, I. R.; Matei, C. E.; Patachia, M.; Bratu, A. M.; Dumitras, D. C.
2016-06-01
Absorption coefficients of the ethanol vapors at atmospheric pressure and room temperature were measured by photoacoustic technique using a cw, line-tunable, frequency-stabilized CO2 laser as radiation source. The spectrum of the employed CO2 laser includes 54 lines with wavelengths in the infrared region of 9.2-10.8 μm and power levels up to 4.7 W. Measurements revealed a predominant absorption for ethanol within 9.4 μm band of the CO2 laser spectrum, where the highest values of the absorption coefficients were recorded: 3.68 cm- 1 atm- 1 at 9R(20) line and 3.65 cm- 1 atm- 1 at 9R(22) line. The estimated detection range covers six orders of magnitude, from a minimum of 30 ppbV to a maximum of 4% concentration of ethanol in nitrogen, which proves the suitability of the photoacoustic technique for accurate measurements of the ethanol concentration in various applications.
NASA Astrophysics Data System (ADS)
Trofimov, Vyacheslav A.; Lysak, Tatiana M.
2016-02-01
We investigate a femtosecond pulse propagation in a medium, containing nanorods, with taking into account the dependence of multi-photon absorption from the aspect ratio of nanorods. Nanorods melting due to the laser energy absorption leads to the non-stationary interaction of laser pulse with the medium and time-dependent nanorod aspect ratio changing. Under certain conditions, we found out the soliton-like mode of a laser pulse propagation and the superluminality effect: acceleration of light (fast light) in comparison with light propagation in a linear medium. We discuss a physical mechanism of superluminality effect for considering laser pulse propagation. Using spatio-temporal analogy, one can see the similarity between the pulse centre evolution along longitudinal coordinate and the beam centre evolution under the infrared optical radiation propagation in a cloud, or fog, which moves across the beam, with taking into account its thermal blooming.
NASA Astrophysics Data System (ADS)
DeMilo, Charles; Brukilacchio, Thomas; Soller, Babs R.; Soyemi, Olusola
2004-06-01
A visible-near IR (500-1,000nm) fiber optic sensor is under development that is intended to non-invasively assess muscle metabolism through the measurement of tissue pH and oxygen partial pressure. These parameters are calculated from the spectra of hemoglobin and myoglobin in muscle. The sensor consists of transmit (illumination) fibers and receive (detection) fibers that are coupled to a spectrometer. Light from the probe must penetrate below the surface of the skin and into a 5-10mm thick layer of muscle. A study was conducted to quantify the relationship between transmit and receive fiber separation and sensor penetration depth below the surface of the skin. A liquid phantom was created to replicate the absorption (μa) and reduced scatter coefficient (μs') profiles typically found in human blood and tissue. The phantom consisted of a solution of Intralipid and India ink in the appropriate concentrations to achieve desired reduced scatter coefficient and absorption profiles. The reduced scatter coefficient of the liquid phantom was achieved to an accuracy of +/-10% compared to previously published data. A fixed illumination fiber and translatable detector fiber were placed in the liquid phantom, and the fiber separation was varied from 3-40mm. Values of μa and μs' varied from 0.03-0.40 cm-1 and 5.0-15.0 cm-1 respectively. Results from the experiment demonstrate a strong correlation between penetration depth and fiber separation. Additionally, it was found that penetration depth was not substantially influenced by absorption and scatter concentration. As signal-to-noise is an important parameter in many non-invasive biomedical applications, the relative signal as a function of fiber separation was determined to follow an exponential relationship.
NASA Technical Reports Server (NTRS)
Lee, Zhong-Ping; Carder, Kendall L.
2001-01-01
A multi-band analytical (MBA) algorithm is developed to retrieve absorption and backscattering coefficients for optically deep waters, which can be applied to data from past and current satellite sensors, as well as data from hyperspectral sensors. This MBA algorithm applies a remote-sensing reflectance model derived from the Radiative Transfer Equation, and values of absorption and backscattering coefficients are analytically calculated from values of remote-sensing reflectance. There are only limited empirical relationships involved in the algorithm, which implies that this MBA algorithm could be applied to a wide dynamic range of waters. Applying the algorithm to a simulated non-"Case 1" data set, which has no relation to the development of the algorithm, the percentage error for the total absorption coefficient at 440 nm a (sub 440) is approximately 12% for a range of 0.012 - 2.1 per meter (approximately 6% for a (sub 440) less than approximately 0.3 per meter), while a traditional band-ratio approach returns a percentage error of approximately 30%. Applying it to a field data set ranging from 0.025 to 2.0 per meter, the result for a (sub 440) is very close to that using a full spectrum optimization technique (9.6% difference). Compared to the optimization approach, the MBA algorithm cuts the computation time dramatically with only a small sacrifice in accuracy, making it suitable for processing large data sets such as satellite images. Significant improvements over empirical algorithms have also been achieved in retrieving the optical properties of optically deep waters.
NASA Astrophysics Data System (ADS)
Degrelle, D.; Mavon, C.; Groetz, J.-E.
2016-04-01
This study presents a numerical method in order to determine the mass attenuation coefficient of a sample with an unknown chemical composition at low energy. It is compared with two experimental methods: a graphic method and a transmission method. The method proposes to realise a numerical absorption calibration curve to process experimental results. Demineralised water with known mass attenuation coefficient (0.2066cm2g-1 at 59.54 keV) is chosen to confirm the method. 0.1964 ± 0.0350cm2g-1 is the average value determined by the numerical method, that is to say less than 5% relative deviation compared to more than 47% for the experimental methods.
NASA Astrophysics Data System (ADS)
Deckers, Elke; Claeys, Claus; Atak, Onur; Groby, Jean-Philippe; Dazel, Olivier; Desmet, Wim
2016-05-01
This paper presents an extension to the Wave Based Method to predict the absorption, reflection and transmission coefficients of a porous material with an embedded periodic set of inclusions. The porous unit cell is described using the Multi-Level methodology and by embedding Bloch-Floquet periodicity conditions in the weighted residual scheme. The dynamic pressure field in the semi-infinite acoustic domains is approximated using a novel wave function set that fulfils the Helmholtz equation, the Bloch-Floquet periodicity conditions and the Sommerfeld radiation condition. The method is meshless and computationally efficient, which makes it well suited for optimisation studies.
NASA Technical Reports Server (NTRS)
Beatty, R. W.; Otosh, T. Y.
1978-01-01
Theoretical equations are derived for calculating the effects of local VSWR and reflection coefficient phase angle drifts on hydrogen maser frequency stability. Sample calculations made for a typical JPL maser show that under special load conditions, a VSWR drift of 0.000075/h or phase angle drive of 0.01 deg/h can produce a frequency drift of (10 to the -14th power f sub 0) Hz/h where f sub 0 is the maser frequency of approximately 1.42 x 10 to the 9th power Hz.
Effect of a drag force due to absorption of solar radiation on solar sail orbital dynamics
NASA Astrophysics Data System (ADS)
Kezerashvili, Roman Ya.; Vázquez-Poritz, Justin F.
2013-03-01
While solar electromagnetic radiation can be used to propel a solar sail, it is shown that the Poynting-Robertson effect related to the absorbed portion of the radiation leads to a drag force in the transversal direction. The Poynting-Robertson effect is considered for escape trajectories, Heliocentric bound orbits and non-Keplerian bound orbits. For escape trajectories, this drag force diminishes the cruising velocity, which has a cumulative effect on the Heliocentric distance. For Heliocentric and non-Keplerian bound orbits, the Poynting-Robertson effect decreases its orbital speed, thereby causing it to slowly spiral towards the Sun. Since the Poynting-Robertson effect is due to the absorbed portion of the electromagnetic radiation, degradation of a solar sail implies that this effect becomes enhanced during a mission.
NASA Astrophysics Data System (ADS)
Pei, Yaling; Graber, Harry L.; Barbour, Randall L.
2001-06-01
In this report, we present a method to reduce the cross-talk problem in optical tomography. The method described is an extension of a previously reported perturbation formulation related to relative detector values, and employs a weight matrix scaling technique together with a constrained CGD method for imaging reconstruction. Results from numerical and experimental studies using DC measurement data demonstrate that the approach can effectively isolate absorption and scattering heterogeneities, even for complex combinations of perturbations in optical properties. The derive method is remarkably stable to errors originating from an insufficiently accurate estimate of properties of the reference medium.
2012-01-01
The linear and nonlinear intraband optical absorption coefficients in GaAs three-dimensional single quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and electric field, applied along the growth direction of the heterostructure, the energies of the ground and first excited states of a donor impurity have been found using the effective mass approximation and a variational method. The energies of these states are examined as functions of the dimensions of the structure, electric field, and hydrostatic pressure. We have also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as a function of incident photon energy for several configurations of the system. It is found that the variation of distinct sizes of the structure leads to either a redshift and/or a blueshift of the resonant peaks of the intraband optical spectrum. In addition, we have found that the application of an electric field leads to a redshift, whereas the influence of hydrostatic pressure leads to a blueshift (in the case of on-ring-center donor impurity position) of the resonant peaks of the intraband optical spectrum. PMID:23021497
NASA Astrophysics Data System (ADS)
Martínez-Orozco, J. C.; Rodríguez-Magdaleno, K. A.; Suárez-López, J. R.; Duque, C. A.; Restrepo, R. L.
2016-04-01
In this work we present theoretical results for the electronic structure as well as for the absorption coefficient and relative refractive index change for an asymmetric double δ-doped like confining potential in the active region of a Multiple Independent Gate Field Effect Transistor (MIGFET) system. We model the potential profile as a double δ-doped like potential profile between two Schottky (parabolic) potential barriers that are just the main characteristics of the MIGFET configuration. We investigate the effect of external electromagnetic fields in this kind of quantum structures, in particular we applied a homogeneous constant electric field in the growth direction z as well as a homogeneous constant magnetic field in the x-direction. In general we conclude that by applying electromagnetic fields we can modulate the resonant peaks of the absorption coefficient as well as their energy position. Also with such probes it is possible to control the nodes and amplitude of the relative refractive index changes related to resonant intersubband optical transitions.
Barseghyan, Manuk G; Restrepo, Ricardo L; Mora-Ramos, Miguel E; Kirakosyan, Albert A; Duque, Carlos A
2012-01-01
: The linear and nonlinear intraband optical absorption coefficients in GaAs three-dimensional single quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and electric field, applied along the growth direction of the heterostructure, the energies of the ground and first excited states of a donor impurity have been found using the effective mass approximation and a variational method. The energies of these states are examined as functions of the dimensions of the structure, electric field, and hydrostatic pressure. We have also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as a function of incident photon energy for several configurations of the system. It is found that the variation of distinct sizes of the structure leads to either a redshift and/or a blueshift of the resonant peaks of the intraband optical spectrum. In addition, we have found that the application of an electric field leads to a redshift, whereas the influence of hydrostatic pressure leads to a blueshift (in the case of on-ring-center donor impurity position) of the resonant peaks of the intraband optical spectrum. PMID:23021497
NASA Astrophysics Data System (ADS)
Consalvi, J. L.; Nmira, F.
2016-03-01
The main objective of this article is to quantify the influence of the soot absorption coefficient-Planck function correlation on radiative loss and flame structure in an oxygen-enhanced propane turbulent diffusion flame. Calculations were run with and without accounting for this correlation by using a standard k-ε model and the steady laminar flamelet model (SLF) coupled to a joint Probability Density Function (PDF) of mixture fraction, enthalpy defect, scalar dissipation rate, and soot quantities. The PDF transport equation is solved by using a Stochastic Eulerian Field (SEF) method. The modeling of soot production is carried out by using a flamelet-based semi-empirical acetylene/benzene soot model. Radiative heat transfer is modeled by using a wide band correlated-k model and turbulent radiation interactions (TRI) are accounted for by using the Optically-Thin Fluctuation Approximation (OTFA). Predicted soot volume fraction, radiant wall heat flux distribution and radiant fraction are in good agreement with the available experimental data. Model results show that soot absorption coefficient and Planck function are negatively correlated in the region of intense soot emission. Neglecting this correlation is found to increase significantly the radiative loss leading to a substantial impact on flame structure in terms of mean and rms values of temperature. In addition mean and rms values of soot volume fraction are found to be less sensitive to the correlation than temperature since soot formation occurs mainly in a region where its influence is low.
NASA Technical Reports Server (NTRS)
Ohi, Nobuaki; Makinen, Carla P.; Mitchell, Richard; Moisan, Tiffany A.
2008-01-01
Ocean color algorithms are based on the parameterization of apparent optical properties as a function of inherent optical properties. WET Labs underwater absorption and attenuation meters (ac-9 and ac-s) measure both the spectral beam attenuation [c (lambda)] and absorption coefficient [a (lambda)]. The ac-s reports in a continuous range of 390-750 nm with a band pass of 4 nm, totaling approximately 83 distinct wavelengths, while the ac-9 reports at 9 wavelengths. We performed the ac-s field measurements at nine stations in the Mid-Atlantic Bight from water calibrations to data analysis. Onboard the ship, the ac-s was calibrated daily using Milli Q-water. Corrections for the in situ temperature and salinity effects on optical properties of water were applied. Corrections for incomplete recovery of the scattered light in the ac-s absorption tube were performed. The fine scale of spectral and vertical distributions of c (lambda) and a (lambda) were described from the ac-s. The significant relationships between a (674) and that of spectrophotometric analysis and chlorophyll a concentration of discrete water samples were observed.
Sabau, Adrian S
2007-01-01
Lubricant spray application experiments were conducted for the die casting process. The heat flux was measured in situ using a differential thermopile sensor for three application techniques. First, the lubricant was applied under a constant flowrate while the nozzle was held in the same position. Second, the lubricant was applied in a pulsed, static manner, in which the nozzle was held over the same surface while it was turned on and off several times. Third, the lubricant was applied in a sweeping manner, in which the nozzle was moved along the die surface while it was held open. The experiments were conducted at several die temperatures and at sweep speeds of 20, 23, and 68 cm/s. The heat flux data, which were obtained with a sensor that was located in the centre of the test plate, were presented and discussed. The sensor can be used to evaluate lubricants, monitor the consistency of die lubrication process, and obtain useful process data, such as surface temperature, heat flux, and heat transfer coefficients. The heat removed from the die surface during lubricant application is necessary for (a) designing the cooling channels in the die, i.e. their size and placement, and (b) performing accurate numerical simulations of the die casting process.
Greening, Gage J; Istfan, Raeef; Higgins, Laura M; Balachandran, Kartik; Roblyer, Darren; Pierce, Mark C; Muldoon, Timothy J
2014-01-01
Optical phantoms are used in the development of various imaging systems. For certain applications, the development of thin phantoms that simulate the physical size and optical properties of tissue is important. Here, we demonstrate a method for producing thin phantom layers with tunable optical properties using poly(dimethylsiloxane) (PDMS) as a substrate material. The thickness of each layer (between 115 and 880 μm) was controlled using a spin coater. The reduced scattering and absorption coefficients were controlled using titanium dioxide and alcohol-soluble nigrosin, respectively. These optical coefficients were quantified at six discrete wavelengths (591, 631, 659, 691, 731, and 851 nm) at varying concentrations of titanium dioxide and nigrosin using spatial frequency domain imaging. From the presented data, we provide lookup tables to determine the appropriate concentrations of scattering and absorbing agents to be used in the design of PDMS-based phantoms with specific optical coefficients. In addition, heterogeneous phantoms mimicking the layered features of certain tissue types may be fabricated from multiple stacked layers, each with custom optical properties. These thin, tunable PDMS optical phantoms can simulate many tissue types and have broad imaging calibration applications in endoscopy, diffuse optical spectroscopic imaging, and optical coherence tomography, etc. PMID:25387084
Dipping in CygnusX-2 in a multi-wavelength campaign due to absorption of extended ADC emission
NASA Astrophysics Data System (ADS)
Bałucińska-Church, M.; Schulz, N. S.; Wilms, J.; Gibiec, A.; Hanke, M.; Spencer, R. E.; Rushton, A.; Church, M. J.
2011-06-01
We report results of one-day simultaneous multiwavelength observations of CygnusX-2 using XMM, Chandra, the European VLBI Network and the XMM Optical Monitor. During the observations, the source did not exhibit Z-track movement, but remained in the vicinity of the soft apex. It was in a radio quiescent/quiet state of <150 μJy. Strong dip events were seen as 25% reductions in X-ray intensity. The use of broadband CCD spectra in combination with narrow-band grating spectra has now demonstrated for the first time that these dipping events in CygnusX-2 are caused by absorption in cool material in quite a unique way. In the band 0.2 - 10 keV, dipping appears to be due to progressive covering of the Comptonized emission of an extended accretion disk corona, the covering factor rising to 40% in deep dipping with an associated column density of 3 × 1023 atom cm-2. Remarkably, the blackbody emission of the neutron star is not affected by these dips, in strong contrast with observations of typical low mass X-ray binary dipping sources. The Chandra and XMM gratings directly measure the optical depths in absorption edges such as Ne K, Fe L, and O K and a comparison of the optical depths in the edges of non-dip and dip data reveals no increase of optical depth during dipping even though the continuum emission sharply decreases. Based on these findings, at orbital phase 0.35, we propose that dipping in this observation is caused by absorption in the outer disk by structures located opposite to the impact bulge of the accretion stream. With an inclination angle >60° these structures can still cover large parts of the extended ADC, without absorbing emission from the central neutral star.
Goulding, A. D.; Forman, W. R.; Jones, C.; Trichas, M.; Alexander, D. M.; Mullaney, J. R.; Bauer, F. E.; Hickox, R. C.
2012-08-10
We explore the origin of mid-infrared (mid-IR) dust extinction in all 20 nearby (z < 0.05) bona fide Compton-thick (N{sub H} > 1.5 Multiplication-Sign 10{sup 24} cm{sup -2}) active galactic nuclei (AGNs) with hard energy (E > 10 keV) X-ray spectral measurements. We accurately measure the silicate absorption features at {lambda} {approx} 9.7 {mu}m in archival low-resolution (R {approx} 57-127) Spitzer Infrared Spectrograph spectroscopy, and show that only a minority ( Almost-Equal-To 45%) of nearby Compton-thick AGNs have strong Si-absorption features (S{sub 9.7} = ln (f{sub int}/f{sub obs}) {approx}> 0.5) which would indicate significant dust attenuation. The majority ( Almost-Equal-To 60%) are star formation dominated (AGN:SB < 0.5) at mid-IR wavelengths and lack the spectral signatures of AGN activity at optical wavelengths, most likely because the AGN emission lines are optically extinguished. Those Compton-thick AGNs hosted in low-inclination-angle galaxies exhibit a narrow range in Si-absorption (S{sub 9.7} {approx} 0-0.3), which is consistent with that predicted by clumpy-torus models. However, on the basis of the IR spectra and additional lines of evidence, we conclude that the dominant contribution to the observed mid-IR dust extinction is dust located in the host galaxy (i.e., due to disturbed morphologies, dust lanes, galaxy inclination angles) and not necessarily a compact obscuring torus surrounding the central engine.
NASA Technical Reports Server (NTRS)
Gao, R. S.; Hall, S. R.; Swartz, W. H.; Spackman, J. R.; Watts, L. A.; Fahey, D. W.; Aikin, K. C.; Shetter, R. E.; Bui, T. P.
2008-01-01
Results for the solar heating rates in ambient air due to absorption by black-carbon (BC) containing particles and ozone are presented as calculated from airborne observations made in the tropical tropopause layer (TTL) in January-February 2006. The method uses airborne in situ observations of BC particles, ozone and actinic flux. Total BC mass is obtained along the flight track by summing the masses of individually detected BC particles in the range 90 to 600-nm volume-equivalent diameter, which includes most of the BC mass. Ozone mixing ratios and upwelling and partial downwelling solar actinic fluxes were measured concurrently with BC mass. Two estimates used for the BC wavelength-dependent absorption cross section yielded similar heating rates. For mean altitudes of 16.5, 17.5, and 18.5 km (0.5 km) in the tropics, average BC heating rates were near 0.0002 K/d. Observed BC coatings on individual particles approximately double derived BC heating rates. Ozone heating rates exceeded BC heating rates by approximately a factor of 100 on average and at least a factor of 4, suggesting that BC heating rates in this region are negligible in comparison.
Fasano, William J; Baer, Kevin N
2006-01-01
Vinyl toluene is one of several methylstyrene monomers that provide improved performance in resins for specialty paints, hydrocarbon resins for adhesives, specialty polymers, and unsaturated polyester resins. The purpose of this study was to determine a permeability coefficient (Kp) and short-term absorption rate for vinyl toluene using human cadaver skin mounted in an in vitro static diffusion cell model with an exposure area of 0.64 cm2. For the Kp determination, vinyl toluene was applied at a rate of 100 microL/cm2 to 6 skin replicates representing 4 human subjects. Serial receptor fluid samples were collected at 1, 2, 4, 8, 12, 24, 36, and 48 h postapplication and analyzed for vinyl toluene by HPLC-UV. Based on the slope at steady-state (203.3 microg cm(-2) h(-1) +/- 120.0 microg cm(-2) h(-1)) and the concentration of the applied dose of vinyl toluene, taken as its density (894,600 microg/cm3), the Kp was calculated to be 2.27 x 10(-4) cm/h (+/-1.34 x 10(-4) cm/h). For the short-term absorption experiments, 12 skin replicates representing 3 human subjects were employed. Following 10- and 60-min exposures to a finite dose of vinyl toluene (10 microL/cm2), the respective short-term absorption rates were calculated to be 66.0 (+/-29.9) and 104.2 (+/-63.0) microg cm(-2) h(-1). These data provide industrial hygienists and safety personnel values to estimate the amount of vinyl toluene that may be absorbed via the dermal exposure route, given a variety of exposure scenarios, and the time it takes (skin absorption time) to reach a body burden equal to the Occupational Safety and Health Administrative permissible exposure level (OSHA PEL) or ACGIH TLV. PMID:16455589
Sopori, Bhushan L.
1995-01-01
A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth's surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO.sub.2 and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO.sub.2 and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO.sub.2 and moisture.
Sopori, B.L.
1995-06-20
A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.
NASA Astrophysics Data System (ADS)
Hoge, Frank E.; Vodacek, Anthony; Swift, Robert N.; Yungel, James K.; Blough, Neil V.
1995-10-01
The absorption coefficient of chromophoric dissolved organic matter (CDOM) at 355 nm has been retrieved from airborne laser-induced and water Raman-normalized CDOM fluorescence. Four combined airborne and ship field experiments have demonstrated that (1) the airborne CDOM fluorescence-to--water Raman ratio is linearly related to concurrent quinine-sulfate-standardized CDOM shipboard fluorescence measurements over a wide range of water masses (coastal to blue water); (2) the vicarious calibration of the airborne fluorosensor in units traceable to a fluorescence standard can be established and then maintained over an extended time period by tungsten lamp calibration; (3) the vicariously calibrated airborne CDOM fluorescence-to-water Raman ratio can be directly applied to previously developed
NASA Astrophysics Data System (ADS)
Mandal, Arkajit; Sarkar, Sucharita; Ghosh, Arghya Pratim; Ghosh, Manas
2015-12-01
We make an extensive investigation of total optical absorption coefficient (TOAC) of impurity doped quantum dots (QDs) in presence and absence of Gaussian white noise. The TOAC profiles have been monitored against incident photon energy with special emphasis on the roles played by the electric field, magnetic field, and the dot confinement potential. Presence of impurity also influences the TOAC profile. In general, presence of noise causes enhancement of TOAC over that of noise-free condition. However, the interplay between the noise and the quantities like electric field, magnetic field, confinement potential and impurity potential bring about rich subtleties in the TOAC profiles. The said subtleties are often manifested by the alterations in TOAC peak intensity, extent of TOAC peak bleaching, and value of saturation intensity. The findings reveal some technologically relevant aspects of TOAC for the doped QD systems, specially in presence of noise.
Dhoubhadel, Mangal S.; Lakshantha, Wickramaarachchige J.; Rout, Bibhudutta; McDaniel, Floyd D.; Lightbourne, Sherard; D’Souza, Francis
2015-07-23
The quest for increased efficiency of solar cells has driven the research in synthesizing photovoltaic cells involving Si based materials. The efficiency of solar cells involving crystalline Si is stalled around 25% for the last decade. Recently Shi et al. had shown that light trapping can be enhanced by fabricating double layers of Ag nanoparticles in silicon based materials. The light trapping is critically important in a photo devices such as solar cells in order to increase light absorption and efficiency. In the present work, we report enhancement in the absorption of light in Ag ion implanted Si substrates. Multiple low energies Ag ions, ranging from ∼80 keV to ∼30 keV, with different fluences ranging from ∼1 × 10{sup 16} to ∼1 × 10{sup 17} atoms/cm{sup 2} were sequentially implanted into commercially available Si (100) substrates followed by post-thermal annealing to create different sizes of Ag nanoclusters (NC) at different depths in the top 100 nm of the Si. The absorbance of light is increased in Ag implanted Si with a significant increase in the current collection in I-V (current-voltage) photo switching measurements. The experimental photovoltaic cells fabricated with the Ag-implanted Si samples were optically characterized under AM (air mass) 1.5 solar radiation conditions (∼1.0 kW/m{sup 2}). An enhancement in the charge collection were measured in the annealed samples, where prominent Ag NCs were formed in the Si matrix compared to the as-implanted samples with amorphous layers. We believe the enhancement of the photo-current density from the samples with Ag NC is due to the improvement of efficiency of charge collection of e{sup −}-h{sup +} pairs produced by the incident light.
NASA Astrophysics Data System (ADS)
Turgut, U.; Simsek, O.; Büyükkasap, E.
2007-08-01
The total mass attenuation coefficients for elements Cr, Co and Fe and compounds CrCl_{2}, CrCl_{3}, Cr_{2}(SO_{4})_{3}K_{2}SO_{4}\\cdot24H_{2}O, CoO, CoCl_{2}, Co(CH_{3}COO)_{2}, FePO_{4}, FeCl_{3}\\cdot6H_{2}O, Fe(SO_{4})_{2}NH_{4}\\cdot12H_{2}O were measured at different energies between 4.508 and 14.142 keV using secondary excitation method. Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr were chosen as secondary exciters. 59.5 keV γ-rays emitted from a ^{241}Am annular source were used to excite a secondary exciter and K_{α}(K-L_{3}, L_{2}) lines emitted by the secondary exciter were counted by a Si(Li) detector with a resolution of 160 eV at 5.9 keV. It was observed that mixture rule method is not a suitable method for determination of the mass attenuation coefficients of compounds, especially at an energy that is near the absorption edge. The obtained values were compared with theoretical values.
Adams, M.E.; Marshall, T.L.; Rowley, R.L.
1998-07-01
Absorption rates of gaseous CO{sub 2} into aqueous blends of N-methyldiethanolamine (MDEA) and diethanolamine (DEA) and of gaseous H{sub 2}S into aqueous MDEA were measured in a quiescent, inverted-tube diffusiometer by monitoring the rate of pressure drop. A numerical model for absorption, diffusion, and reaction of CO{sub 2} and H{sub 2}S in blends of MDEA, DEA, and water was developed. The model was used to regress diffusion coefficients of bicarbonate, carbamate, and MDEAH{sub 2}CO{sub 3} for the case of CO{sub 2} absorption and of bisulfide ion for the case of H{sub 2}S absorption from measured absorption rates. CO{sub 2} absorption rates and diffusion coefficients of bicarbonate, carbamate, and MDEAH{sub 2}CO{sub 3} were obtained at 298.2 K and 318.2 K in aqueous solutions containing 50 mass % total amine at DEA:MDEA mole ratios of 1:20, 1:4, 1L3, and 2:3. H{sub 2}S absorption rates and diffusion coefficients of bisulfide ion were obtained at 298.2 K and 318.2 K in aqueous solutions containing 20, 35, and 50 mass % MDEA.
NASA Astrophysics Data System (ADS)
Eleftheriadis, Konstantinos; Kalogridis, Athina-Cerise; Vratolis, Sterios; Fiebig, Markus
2016-04-01
Light absorbing carbon in atmospheric aerosol plays a critical role in radiative forcing and climate change. Despite the long term measurements across the Arctic, comparing data obtained by a variety of methods across stations requires caution. A method for extracting the aerosol absorption coefficient from data obtained over the decades by filter based instrument is still under development. An IASOA Aerosol working group has been initiated to address this and other cross-site aerosol comparison opportunities. Continuous ambient measurements of EBC/light attenuation by means of a Magee Sci. AE-31 aethalometer operating at the Zeppelinfjellet station (474 m asl; 78°54'N, 11°53'E), Ny Ålesund, Svalbard, have been available since 2001 (Eleftheriadis et al, 2009), while a new aethalometer model (AE33, Drinovec et al, 2014) has been installed to operate in parallel from the same inlet since June 2015. Measurements are recorded by a Labview routine collecting all available parameters reported by the two instrument via RS232 protocol. Data are reported at 1 and 10 minute intervals as averages for EBC (μg m-3) and aerosol absorption coefficients (Mm-1) by means of routine designed to report Near Real Time NRT data at the EBAS WDCA database (ebas.nilu.no) Results for the first 6 month period are reported here in an attempt to evaluate comparative performance of the two instruments in terms of their response with respect to the variable aerosol load of light absorbing carbon during the warm and cold seasons found in the high arctic. The application of available conversion schemes for obtaining the absorption coefficient by the two instruments is found to demonstrate a marked difference in their output. During clean periods of low aerosol load (EBC < 30 ng m-3), the two instruments display a better agreement with regression slope for the 880 nm signal between the two at ~ 0.9 compared to a slope at ~ 0.6 during the period of higher absorbing carbon loads (400< EBC<30 ng m
Optical absorption components of light-modulated absorption spectrum of CdS
NASA Technical Reports Server (NTRS)
Conway, E. J.; Long, E. R.
1975-01-01
The amplitude and decay coefficient of light-induced modulation of absorption (LIMA) was measured as a function of wavelength from 535 to 850 nm for single-crystal CdS. The decay coefficient exhibited a discontinuous resonance at 710 nm which was due to the overlap and cancellation of two opposing absorption changes. A method was developed to separate these opposing absorption changes using the measured decay coefficients. The discrete-level-to-band energy for one absorption change was found to be 1.64 eV. An improved model was developed which contains two associated levels in the band gap separated by 0.32 eV.
Behari, J; Nirala, Jay Prakash
2013-12-01
A specific absorption rate (SAR) measurements system has been developed for compliance testing of personal mobile phone in a brain phantom material contained in a Perspex box. The volume of the box has been chosen corresponding to the volume of a small rat and illuminated by a 3G mobile phone frequency (1718.5 MHz), and the emitted radiation directed toward brain phantom .The induced fields in the phantom material are measured. Set up to lift the plane carrying the mobile phone is run by a pulley whose motion is controlled by a stepper motor. The platform is made to move at a pre-determined rate of 2 degrees per min limited up to 20 degrees. The measured data for induced fields in various locations are used to compute corresponding SAR values and inter comparison obtained. These data are also compared with those when the mobile phone is placed horizontally with respect to the position of the animal. The SAR data is also experimentally obtained by measuring a rise in temperature due to this mobile exposures and data compared with those obtained in the previous set. To seek a comparison with the safety criteria same set of measurements are performed in 10 g phantom material contained in a cubical box. These results are higher than those obtained with the knowledge of induced field measurements. It is concluded that SAR values are sensitive to the angular position of the moving platform and are well below the safety criteria prescribed for human exposure. The data are suggestive of having a fresh look to understand the mode of electromagnetic field -bio interaction. PMID:24579373
Protasenko, Vladimir; Bacinello, Daniel; Kuno, Masaru
2006-12-21
Absorption cross-sections and corresponding molar extinction coefficients of solution-based CdSe and CdTe nanowires (NWs) are determined. Chemically grown semiconductor NWs are made via a recently developed solution-liquid-solid (SLS) synthesis, employing low melting Au/Bi bimetallic nanoparticle "catalysts" to induce one-dimensional (1D) growth. Resulting wires are highly crystalline and have diameters between 5 and 12 nm as well as lengths exceeding 10 microm. Narrow diameters, below twice the corresponding bulk exciton Bohr radius of each material, place CdSe and CdTe NWs within their respective intermediate to weak confinement regimes. Supporting this are solution linear absorption spectra of NW ensembles showing blue shifts relative to the bulk band gap as well as structure at higher energies. In the case of CdSe, the wires exhibit band edge emission as well as strong absorption/emission polarization anisotropies at the ensemble and single-wire levels. Analogous photocurrent polarization anisotropies have been measured in recently developed CdSe NW photodetectors. To further support fundamental NW optical/electrical studies as well as to promote their use in device applications, experimental absorption cross-sections are determined using correlated transmission electron microscopy, UV/visible extinction spectroscopy, and inductively coupled plasma atomic emission spectroscopy. Measured CdSe NW cross-sections for 1 microm long wires (diameters, 6-42 nm) range from 6.93 x 10(-13) to 3.91 x 10(-11) cm2 at the band edge (692-715 nm, 1.73-1.79 eV) and between 3.38 x 10(-12) and 5.50 x 10(-11) cm2 at 488 nm (2.54 eV). Similar values are obtained for 1 microm long CdTe NWs (diameters, 7.5-11.5 nm) ranging from 4.32 x 10(-13) to 5.10 x 10(-12) cm2 at the band edge (689-752 nm, 1.65-1.80 eV) and between 1.80 x 10(-12) and 1.99 x 10(-11) cm2 at 2.54 eV. These numbers compare well with previous theoretical estimates of CdSe/CdTe NW cross-sections far to the blue of the