... BY DC AN AC ELECTROCHEMICAL TECHNIQUES AS COMPARED ... IMPEDANCE DIAGRAMS SHOW THAT A SLIGHTLY ...
DTIC Science & Technology
... Title : APPLYING AC IMPEDANCE ELECTROCHEMICAL METHODS TO CORROSION TESTING COBALT ALLOY MEDIA. Corporate Author : ...
... of a Scanning Electrochemical Impedance Spectroscopy Technique ... This article describes a method of generating ... by driving an ac current between ...
... jUN 0 91994D * F ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY OF ... 16. PRICE COOE ac-Impedance, Chromate, Aluminum Alloys 17. ...
... and DC electrochemical techniques have verified that the low-frequency impedance spectrum obtained from the AC Impedance technique is ...
... and DC electrochemical techniques, have verified that the low-frequency impedance spectrum obtained from the AC Impedance technique is ...
... was examined by applying the methods described below. ... Electrochemical Measurements: Alternating current (AC) impedance measurements were ...
... Abstract : Electrochemical techniques for predicting stress corrosion cracking (SCC ... potentials with continuous recording of the ac impedance in a ...
... Abstract : Two in situ techniques, dynamic imaging ... LEIS is an electrochemical impedance technique that generates local ac impedance data by ...
... CORROSION, CORROSION FATIGUE, AND STRESS CORROSION CRACKING) TO THE USE OF AC IMPEDANCE TECHNIQUES AND A ...
... Assisted DC and AC Techniques in Electrochemical ... data acquisition and calculation method, allows the ... Impedance measurements give the same ...
... electrochemistry of titanium in the LiCl-KCl eutectic melt has been investigated by means of pulse techniques and ac impedance measurements. ...
... Title : AC Impedance Analysis of Corrosion Fatigue in Naval Aircraft Alloys. ... this program is to develop rapid electrochemical methods for evaluating ...
This paper reports on a local electrochemical impedance spectroscopy (LEIS) technique for mapping the ac impedance distribution, as a function of frequency, of an electrode. In LEIS, as in traditional ac impedance methods, a sinusoidal voltage perturbation between the ...
Energy Citations Database
... integrals allows the discussion of a wide range of electrochemical techniques and in this paper we discuss the derivation of the AC impedance of a ...
... the techniques being developed or investigated are NDT methods which include electrochemical (linear polarization, ac impedance, and small ...
... involves the application of a variety of pulses and ac methods with the intention of assigning an aperiodic circuit from electrode impedance analysis ...
... involves the application of a variety of pulse and ac methods with the intention of assigning a periodic circuit from electrode impedance analysis. ...
... presaturated with the corrosion products. An AC impedance technique for the total electrical conductivity, the potentiostatic polarization method for ...
... There are two electrochemical methods that are commonly used to monitor the corrosion behaviour of materials: DC Potential and AC Impedance. ...
... This study is part of a general development of the ac-impedance method for measurement of the properties of coated metals. (Author). ...
... L in hydrazine have also been measured by several electrochemical techniques such as Tafel plots, polarization resistance, and AC Impedance. ...
... systems was necessary. In addition, ways for obtaining corrosion rates from AC impedance methods were investigated. ...
Electrochemical corrosion testing using AC impedance measurement and ellipsometry has been performed on aircraft aluminum 2024-T3 samples. The AC Impedance technique was used to acquire a precise low-frequency impedance signature of corroding painted airc...
National Technical Information Service (NTIS)
In the present investigation, Electrochemical Impedance Spectroscopy (EIS) was used ... range of 100 kHz to 0.01 Hz, with 10 mV AC amplitude. ..... Techniques in the Space Transportation System (Space Shuttle) Launch Environment," ...
NASA Website
Recently, the authors have proposed a method for generating local electrochemical impedance maps of electrodes. In this technique impedance maps, at each frequency of interest, are generated by measuring the ratio of ac solution current density, very near...
The author attended the First International Symposium on Electrochemical Impedance Spectroscopy and presented an invited lecture on the theory of ac impedance of rough electrode-electrolyte interfaces. After the symposium the author spent four days at Ecole Polytechnique, Palaiseau, on the outskirt of Paris to give ...
The investigation of the mechanism of anodic hydrocarbon oxidation involves the application of a variety of pulses and ac methods with the intention of assigning an aperiodic circuit from electrode impedance analysis. The applicability of techniques and m...
The investigation of the mechanism of anodic hydrocarbon oxidation involves the application of a variety of pulse and ac methods with the intention of assigning a periodic circuit from electrode impedance analysis. The applicability of techniques and meth...
... Personal Author(s) : Diaz, Carlos ; Urquidi-Macdonald, Mirna ; Macdonald, Digby D. ; Ramamurthy, AC ; van Ooij, Wim J. Report Date : 1993. ...
... at three rotation speeds (600,1200 and 1800 rpm), using electrochemical small amplitude cyclic voltammetry and AC impedance techniques. ...
Laboratory tests have shown that the a.c. electrochemical technique being developed meets the basic requirements for in situ corrosion monitoring of the secondary side of PWR steam generators. The technique uses two probe electrodes which measure the electrochemical impedance of the corroding surface. The ...
... Title : AC IMPEDANCE MEASUREMENT OF ENVIRONMENTAL ... OF INTERFACIAL IMPEDANCE MEASUREMENT ARE ... OF THE METHOD IN ...
Electrochemical reactions at solid electrolyte-electrode-gas interfaces are being investigated with ac impedance and dc polarization techniques using an unbonded interface cell (UIC). The UIC approach eliminates influence of sample size and interface morp...
... I Capacitive Behavior in Conducting Polymers: AC Impedance and Quartz Crystal Microbalance Studies by ... AC Impedance Analysis - ...
... Title : Simulation of Electrochemical Impedance Spectroscopy Response to Coating Flaws, or A Step Towards Predicting Corrosion. ...
... ELECTROCHEMICAL IMPEDANCE PATTERN RECOGNITION FOR DETECTION OF HIDDEN CHEMICAL CORROSION ON AIRCRAFT ...
... Title : Electrochemical Impedance Pattern Recognition for Detection of Hidden Chemical Corrosion on Aircraft Components. ...
To investigate metal surface corrosion and the breakdown of metal protective coatings, the ac impedance method is applied to six systems of primer coated and primer topcoated 4130 steel. Two primers were used: a zinc-rich epoxy primer and a red lead oxide...
... REPORTED. THE BACKGROUND AND VARIOUS METHODS OF ANALYSIS OF AC IMPEDANCE DATA ARE DISCUSSED. THE ...
... Abstract : Experimental approaches for recording ac impedance data are ... Additional methods for analysis of experimental impedance data are ...
This conference proceedings contains 24 papers, of which 2 are indexed separately. The topics discussed ranged from various aspects of localized corrosion phenomena (such as pitting, crevice corrosion, corrosion fatigue, and stress corrosion cracking) to the use of a-c impedance techniques and a number of special areas usually not discussed in detail ...
Water and ice were investigated by ac impedance with the electrochemical properties cup in an effort to develop an in situ instrument for water characterization. In liquid water, the impedance modulus decreased with the increase in charge carriers. In the ice, the impedance measurements were ...
NASA Astrophysics Data System (ADS)
A scanning electrochemical microscope (SECM) in ac mode is used for the characterisation of the adsorption process during the hydrogen evolution reaction (HER) in sulfuric acid solution. It is shown that this technique allows quantitative analysis of the adsorption process, and measurements of the differential capacitance with the frequency as parameter ...
PubMed
The behavior of zinc-rich primer-coated AISI 1010 steel in 3.5-percent Na-Cl was investigated using electrochemical techniques. The alternating current (ac) method of electrochemical impedance spectroscopy (EIS), in the frequency range of 0.001 to 40,000 ...
The behavior of zinc-rich primer-coated 2219-T87 aluminum in a 3.5-percent Na-Cl was investigated using electrochemical techniques. The alternating current (ac) method of electro-chemical impedance spectroscopy (EIS), in the frequency range of 0.001 to 40...
The behavior of zinc-rich primer-coated 2219-T87 aluminum in a 3. 5-percent Na-Cl was investigated using electrochemical techniques. The alternating current (ac) method of electrochemical impedance spectroscopy (EIS), in the frequency range of 0.001 to 40...
In this study, the electrochemical behavior of nano and femtosecond laser textured titanium alloy for implant surface modification has been researched using the potentiostat equipment. Cp-Ti and Ti-6Al-4V alloy, located on X-Y motorized stage, were irradiated using femtosecond laser. The corrosion properties were examined by a potentiodynamic and AC ...
... study is to determine the viability of electrochemical impedance spectroscopy (EIS) as an accelerated testing procedure for ... ...
NBII National Biological Information Infrastructure
... Title : International Symposium on Electrochemical Impedance Spectroscopy (1st) Held in Paris, France on 22-26 May 1989. ...
Electrochemical impedance spectroscopy (EIS) is a non-destructive technique often used to understand
NASA Technical Reports Server (NTRS)
... Accession Number : ADA229012. Title : Electrochemical Impedance of Organic Coated Steel; Final Report. Correlation ...
... Title : Electrochemical Impedance Pattern Recognition for Detection of Hidden Chemical Corrosion on Aircraft Components. Phase 1. ...
... for Al Alloys Using Electrochemical Impedance Spectroscopy ... Alloys Using Electrochemical Impedance Spectroscopy By..... ...
... Accession Number : ADA142468. Title : Application of Electrochemical and Mechanical Impedance Measurements to Corrosion Induced Failures. ...
This review describes recent advances in electrochemical impedance spectroscopy (EIS) with an emphasis on its novel applications to various electrochemistry-related problems. Section 1 discusses the development of new EIS techniques to reduce measurement time. For this purpose, various forms of multisine EIS techniques were first developed via a noise ...
Recently, the authors have proposed a method for generating local electrochemical impedance maps of electrodes. In this technique impedance maps, at each frequency of interest, are generated by measuring the ratio of ac solution current density, very near the electrode, to the applied potential is measured as a ...
... Title : A Corrosion Monitor Based on Impedance Method,. ... were performed on the impedance characteristics of ... the aid of a new ac corrosion monitor. ...
Electrochemical impedance spectroscopy (EIS) is a non-destructive technique often used to understand ... the measured cell impedance in the form of real and ...
... IS BASED ON AN AC METHOD KNOWN IN ... WHEN AC CURRENT FLOWS THROUGH THE SYSTEM, IT ... LAYER AND AN IMPEDANCE OF THE ...
... Title : AC MAGNETIC FIELDS IN THE ... CALCULATIONS OF THE IMPEDANCE OF A ... IS ACCOMPLISHED BY TWO INDEPENDENT METHODS. ...
Pitting corrosion of stainless steel has been extensively studied by electrochemical impedance spectroscopy (EIS). However, the frequency dependence of the current distribution is much different in the vicinity of a pit than on the passivated part of the surface. Therefore a localized electrochemical impedance ...
The ac impedance measurement has proved to be a useful electrochemical technique for mainly qualitative studies of electrochemical and corrosion systems. Even for complicated systems such as coated metals in corrosive environments this technique has been used with success. The system chosen for the present study is ...
The aim of this paper is to address three issues in solid oxide fuel cells: (1) cross-validation of the polarization of a single cell measured using both dc and ac approaches, (2) the precise determination of the total areal specific resistance (ASR), and (3) understanding cathode polarization with LSCF cathodes. The ASR of a solid oxide fuel cell is a dynamic property, ...
In the present investigation, holographic interferometry was utilized for the first time to measure the alternating current (A.C.) impedance of aluminum samples during the initial stage of anodization processes in aqueous solution without any physical contact. The anodization process (oxidation) of the aluminum samples was carried out chemically in ...
An ac impedance method was used to determine apparent diffusion coefficients associated with the oxidation of polypyrrole. This method was applied to the reduced (nonconductive) form of the polymer, and the polymer remained in the nonconductive state throughout the duration of the experiment. Apparent diffusion coefficients obtained were similar in ...
A series of accelerated corrosion tests were conducted in the simulated marine atmosphere environment to study the corrosion of LY12 aluminum alloy under different Cl- deposition content. The change of corrosion morphology, weight gain and electrochemical parameters (Corrosion Electric Potential, AC Impedance) were inspected in the ...
The results of two surveys (conducted in 1981 and 1984) of users of corrosion monitoring equipment are described. The benefits to be obtained from a well-designed corrosion monitoring system, especially if a corrosion control program is used, are outlined together with the difficulties and barriers that can obstruct successful application. Developing methods such as AC ...
We report the electrode-passivation properties of both fluorinated and unmodified hyperbranched poly(acrylic acid) (PAA) films as a function of pH and the number of PAA layers. Both cyclic voltammetry and ac-impedance spectroscopy show that the extent of ...
The electrochemical activity of [open quotes]as grown[close quotes] boron-doped polycrystalline diamond thin film electrodes has been studied using cyclic voltammetry, chronoamperometry, and ac impedance without external illumination. The resistivity of these materials after doping is ca. 10 ohm-cm. The diamond electrodes possess a low ...
The nondestructive testing (NDT) section begins with a paper that discusses the attributes of neutron radiography and its advantages over other NDT methods. Other techniques examined in this section include ultrasonic test systems, acoustic emission, a computer-based automated system, ultrasonic imaging, and eddy current. Section two begins with a review of electrochemical ...
Contents: Basic of the interpretation of the electrochemical impedance measurements; Validation of impedance spectra; Electrochemical kinetic models - I. Single pathway models with charge transfer steps; Electrochemical kinetic models - II. More complex m...
... TR-2004(8555)-2 AC Impedance Testing on 40-Ah Li-Ion Cells 20 October 2004 ... AC Impedance Testing on 40-Ah Li-on Cells 5b. GRANT NUMBER ...
Jan 22, 2011 ... Title: Electrochemical impedance spectroscopy and its applications to lithium ion cells. Authors: Ratnakumar, B. V.. Smart, M. C. ...
... Accession Number : ADD126883. Title : Electrochemical Impedance Diagrams of Alloy 600 at Active-Passive Transition Potentials,. ...
The assessment of corrosion requires the use of tools able to quantify the corrosion but often times also qualify it. Electrochemical Impedance Spectroscopy (EIS) is a laboratory tool that can provide both qualification and quantification of corrosion. EIS was successfully used to compare the thickness of the corrosion products formed during the ...
An ac electrochemical technique which meets the basic requirements for an in situ localized corrosion monitor within the secondary coolant of PWR steam generators has been investigated. The technique uses two electrodes to measure the electrochemical impedance of a surface in an occluded region with high heat flux. ...
DOE Information Bridge
... Methods of obtaining the complete negative resistance ... amplifier load impedance effects the input impedance. ... be evaluated at the ac frequencies of ...
... inhibition was studied using impedance spectroscopy and potentiodynamic methods. Results obtained from the AC impedance measurements are ...
... of the ac impedance at a metal-electrolyte interface as a function of frequency are depicted, and recently developed measurement techniques are ...
... From the latter, the coil impedance and the ... FIELDS, HALL EFFECT, ELECTRICAL IMPEDANCE, COILS, VOLTAGE, CONDUCTIVITY ...
... Accession Number : ADD854901. Title : Inductance Effect in the AC Impedance of Conducting Polypyrrole Films. Descriptive Note : Journal article,. ...
... TECHNICAL REPORT NATICK/TR-93/019 AD ALTERNATING CURRENT (AC) IMPEDANCE TESTING OF COATED TRAYCANS By Kurt Lawson ...
... Accession Number : ADA261256. Title : Alternating Current (AC) Impedance Testing of Coated Traycans. Descriptive Note : Final rept. ...
... Title : Ac Impedance Investigation of Ta2O5 Film for Use as a Storage Capacitor Dielectric. Descriptive Note : Journal article,. ...
... Abstract : Although ac impedance has come to prominence lately for studying anti ... At first sight this is surprising since the techniques are very ...
... Accession Number : ADA428218. Title : AC Impedance Testing on 40-Ah Li-Ion Cells. Descriptive Note : Technical rept. ...
... Accession Number : ADD854551. Title : AC Impedance Method for High-Resistivity Measurements of Silicon. Descriptive Note : Journal article,. ...
... Title : AC IMPEDANCE INVESTIGATION OF TA(2)O(5) FILM FOR USE AS A STORAGE CAPACITOR DIELECTRIC. Corporate Author : ...
To monitor the real-time corrosion behavior of solar thermal heat exchangers with aqueous thermal transfer media, one seeks an in situ method based on the electrochemical nature of the corroding metal interface. Present methods using DC polarization do not account for changes in solution conductivity brought about by diurnal cycling or the capacitive nature of either the ...
... in the AC Response of an ... LEAST SQUARES METHOD, CHARGE TRANSFER ... COEFFICIENT, EQUATIONS, IMPEDANCE, BINARY COMPOUNDS. ...
... Title : Measurement of Low Corrosion Rates: Comparison of ac Impedance and Thin Layer Activation Methods,. Corporate Author : ...
Alternating current (AC) impedance spectroscopy was applied to measure the degradation of steel coatings previously exposed to corrosive solutions such as tap water and 3% sodium chloride (NaCl). The method used was simple and quick and did not utilize electrochemical (potentiostatic) control. Previously immersed specimens of three ...
A series of cathodes using Pt supported onto graphene sheets with different contents of carbon black in the catalyst layer were prepared and characterized. Carbon black was added as a spacer between two-dimensional graphene sheets in the catalyst layer to study its effect on the performances of proton exchange membrane fuel cell. Electrochemical properties and surface ...
The corrosion behavior of four different preparations of plasma-sprayed hydroxyapatite (HA) coatings on Ti6Al4V substrates in static Hank's balanced salt solution was investigated using dc potentiodynamic and ac impedance techniques. Two different nominal thicknesses, 50 microm and 200 microm, and two different spraying conditions, were considered. The ...
... Electrochemical/mechanical impedance analysis is one of the few techniques with this capability. Our approach was to ...
