Multilevel additive Schwarz method for the h-p version of the Galerkin boundary element method
NASA Astrophysics Data System (ADS)
Heuer, N.; Stephan, E. P.; Tran, T.
1998-04-01
We study a multilevel additive Schwarz method for the h-p version of the Galerkin boundary element method with geometrically graded meshes. Both hypersingular and weakly singular integral equations of the first kind are considered. As it is well known the h-p version with geometric meshes converges exponentially fast in the energy-norm. However, the condition number of the Galerkin matrix in this case blows up exponentially in the number of unknowns M. We prove that the condition number kappa(P) of the multilevel additive Schwarz operator behaves like O(root Mlog(2) M). Asa direct consequence of this we also give the results for the 2-level preconditioner and also for the h-p version with quasi-uniform meshes. Numerical results supporting our theory are presented.
Schwarz and multilevel methods for quadratic spline collocation
Christara, C.C.; Smith, B.
1994-12-31
Smooth spline collocation methods offer an alternative to Galerkin finite element methods, as well as to Hermite spline collocation methods, for the solution of linear elliptic Partial Differential Equations (PDEs). Recently, optimal order of convergence spline collocation methods have been developed for certain degree splines. Convergence proofs for smooth spline collocation methods are generally more difficult than for Galerkin finite elements or Hermite spline collocation, and they require stronger assumptions and more restrictions. However, numerical tests indicate that spline collocation methods are applicable to a wider class of problems, than the analysis requires, and are very competitive to finite element methods, with respect to efficiency. The authors will discuss Schwarz and multilevel methods for the solution of elliptic PDEs using quadratic spline collocation, and compare these with domain decomposition methods using substructuring. Numerical tests on a variety of parallel machines will also be presented. In addition, preliminary convergence analysis using Schwarz and/or maximum principle techniques will be presented.
Newton-Krylov-Schwarz methods in unstructured grid Euler flow
Keyes, D.E.
1996-12-31
Newton-Krylov methods and Krylov-Schwarz (domain decomposition) methods have begun to become established in computational fluid dynamics (CFD) over the past decade. The former employ a Krylov method inside of Newton`s method in a Jacobian-free manner, through directional differencing. The latter employ an overlapping Schwarz domain decomposition to derive a preconditioner for the Krylov accelerator that relies primarily on local information, for data-parallel concurrency. They may be composed as Newton-Krylov-Schwarz (NKS) methods, which seem particularly well suited for solving nonlinear elliptic systems in high-latency, distributed-memory environments. We give a brief description of this family of algorithms, with an emphasis on domain decomposition iterative aspects. We then describe numerical simulations with Newton-Krylov-Schwarz methods on an aerodynamic application emphasizing comparisons with a standard defect-correction approach and subdomain preconditioner consistency.
Schwarz alternating methods for anisotropic problems with prolate spheroid boundaries.
Dai, Zhenlong; Du, Qikui; Liu, Baoqing
2016-01-01
The Schwarz alternating algorithm, which is based on natural boundary element method, is constructed for solving the exterior anisotropic problem in the three-dimension domain. The anisotropic problem is transformed into harmonic problem by using the coordinate transformation. Correspondingly, the algorithm is also changed. Continually, we analysis the convergence and the error estimate of the algorithm. Meanwhile, we give the contraction factor for the convergence. Finally, some numerical examples are computed to show the efficiency of this algorithm. PMID:27625977
Fischer, P.F.; Miller, N.I.; Tufo, H.M.
1998-10-29
As the sound speed is infinite for incompressible flows, computation of the pressure constitutes the stiffest component in the time advancement of unsteady simulations. For complex geometries, efficient solution is dependent upon the availability of fast solvers for sparse linear systems. In this paper we develop a Schwarz preconditioner for the spectral element method using overlapping subdomains for the pressure. These local subdomain problems are derived from tensor products of one-dimensional finite element discretizations and admit use of fast diagonalization methods based upon matrix-matrix products. In addition, we use a coarse grid projection operator whose solution is computed via a fast parallel direct solver. The combination of overlapping Schwarz preconditioning and fast coarse grid solver provides as much as a fourfold reduction in simulation time over previously employed methods based upon deflation for parallel solution of multi-million grid point flow problems.
GetDDM: An open framework for testing optimized Schwarz methods for time-harmonic wave problems
NASA Astrophysics Data System (ADS)
Thierry, B.; Vion, A.; Tournier, S.; El Bouajaji, M.; Colignon, D.; Marsic, N.; Antoine, X.; Geuzaine, C.
2016-06-01
We present an open finite element framework, called GetDDM, for testing optimized Schwarz domain decomposition techniques for time-harmonic wave problems. After a review of Schwarz domain decomposition methods and associated transmission conditions, we discuss the implementation, based on the open source software GetDP and Gmsh. The solver, along with ready-to-use examples for Helmholtz and Maxwell's equations, is freely available online for further testing.
Nonlinear Schwarz-Fas Methods for Unstructured Finite Element Elliptic Problems
Jones, J E; Vassilevski, P S; Woodward, C S
2002-09-30
This paper provides extensions of an element agglomeration AMG method to nonlinear elliptic problems discretized by the finite element method on general unstructured meshes. The method constructs coarse discretization spaces and corresponding coarse nonlinear operators as well as their Jacobians. We introduce both standard (fairly quasi-uniformly coarsened) and non-standard (coarsened away) coarse meshes and respective finite element spaces. We use both kind of spaces in FAS type coarse subspace correction (or Schwarz) algorithms. Their performance is illustrated on a number of model problems. The coarsened away spaces seem to perform better than the standard spaces for problems with nonlinearities in the principal part of the elliptic operator.
Local multiplicative Schwarz algorithms for convection-diffusion equations
NASA Technical Reports Server (NTRS)
Cai, Xiao-Chuan; Sarkis, Marcus
1995-01-01
We develop a new class of overlapping Schwarz type algorithms for solving scalar convection-diffusion equations discretized by finite element or finite difference methods. The preconditioners consist of two components, namely, the usual two-level additive Schwarz preconditioner and the sum of some quadratic terms constructed by using products of ordered neighboring subdomain preconditioners. The ordering of the subdomain preconditioners is determined by considering the direction of the flow. We prove that the algorithms are optimal in the sense that the convergence rates are independent of the mesh size, as well as the number of subdomains. We show by numerical examples that the new algorithms are less sensitive to the direction of the flow than either the classical multiplicative Schwarz algorithms, and converge faster than the additive Schwarz algorithms. Thus, the new algorithms are more suitable for fluid flow applications than the classical additive or multiplicative Schwarz algorithms.
Quasi-Optimal Schwarz Methods for the Conforming Spectral Element Discretization
NASA Technical Reports Server (NTRS)
Casarin, Mario
1996-01-01
Fast methods are proposed for solving the system K(sub N)x = b resulting from the discretization of self-adjoint elliptic equations in three dimensional domains by the spectral element method. The domain is decomposed into hexahedral elements, and in each of these elements the discretization space is formed by polynomials of degree N in each variable. Gauss-Lobatto-Legendre (GLL) quadrature rules replace the integrals in the Galerkin formulation. This system is solved by the preconditioned conjugate gradients method. The conforming finite element space on the GLL mesh consisting of piecewise Q(sub 1) elements produces a stiffness matrix K(sub h) that is spectrally equivalent to the spectral element stiffness matrix K(sub N). The action of the inverse of K(sub h) is expensive for large problems, and is therefore replaced by a Schwarz preconditioner B(sub h) of this finite element stiffness matrix. The preconditioned operator then becomes B(sub h)(exp -l)K(sub N). The technical difficulties stem from the nonregularity of the mesh. Tools to estimate the convergence of a large class of new iterative substructuring and overlapping Schwarz preconditioners are developed. This technique also provides a new analysis for an iterative substructuring method proposed by Pavarino and Widlund for the spectral element discretization.
Fast non-overlapping Schwarz domain decomposition methods for solving the neutron diffusion equation
NASA Astrophysics Data System (ADS)
Jamelot, Erell; Ciarlet, Patrick
2013-05-01
Studying numerically the steady state of a nuclear core reactor is expensive, in terms of memory storage and computational time. In order to address both requirements, one can use a domain decomposition method, implemented on a parallel computer. We present here such a method for the mixed neutron diffusion equations, discretized with Raviart-Thomas-Nédélec finite elements. This method is based on the Schwarz iterative algorithm with Robin interface conditions to handle communications. We analyse this method from the continuous point of view to the discrete point of view, and we give some numerical results in a realistic highly heterogeneous 3D configuration. Computations are carried out with the MINOS solver of the APOLLO3® neutronics code. APOLLO3 is a registered trademark in France.
Fast non-overlapping Schwarz domain decomposition methods for solving the neutron diffusion equation
Jamelot, Erell; Ciarlet, Patrick
2013-05-15
Studying numerically the steady state of a nuclear core reactor is expensive, in terms of memory storage and computational time. In order to address both requirements, one can use a domain decomposition method, implemented on a parallel computer. We present here such a method for the mixed neutron diffusion equations, discretized with Raviart–Thomas–Nédélec finite elements. This method is based on the Schwarz iterative algorithm with Robin interface conditions to handle communications. We analyse this method from the continuous point of view to the discrete point of view, and we give some numerical results in a realistic highly heterogeneous 3D configuration. Computations are carried out with the MINOS solver of the APOLLO3® neutronics code.
Holographic model with a Neveu-Schwarz-Neveu-Schwarz field
Seo, Yunseok; Sin, Sang-jin; Xu, Wei-shui
2009-11-15
We consider a holographic model constructed using the D4/D8-D8 brane configuration with a Neveu-Schwarz-Neveu-Schwarz background field. We study some properties of the effective field theory in this intersecting brane construction and calculate the effects of this Neveu-Schwarz-Neveu-Schwarz background field on some underlying dynamics. We also discuss some other general brane configurations.
Schwarz-Based Algorithms for Compressible Flows
NASA Technical Reports Server (NTRS)
Tidriri, M. D.
1996-01-01
We investigate in this paper the application of Schwarz-based algorithms to compressible flows. First we study the combination of these methods with defect-correction procedures. We then study the effect on the Schwarz-based methods of replacing the explicit treatment of the boundary conditions by an implicit one. In the last part of this paper we study the combination of these methods with Newton-Krylov matrix-free methods. Numerical experiments that show the performance of our approaches are then presented.
NASA Astrophysics Data System (ADS)
Li, Liang; Lanteri, Stéphane; Perrussel, Ronan
2014-01-01
A Schwarz-type domain decomposition method is presented for the solution of the system of 3d time-harmonic Maxwell's equations. We introduce a hybridizable discontinuous Galerkin (HDG) scheme for the discretization of the problem based on a tetrahedrization of the computational domain. The discrete system of the HDG method on each subdomain is solved by an optimized sparse direct (LU factorization) solver. The solution of the interface system in the domain decomposition framework is accelerated by a Krylov subspace method. The formulation and the implementation of the resulting DD-HDG (Domain Decomposed-Hybridizable Discontinuous Galerkin) method are detailed. Numerical results show that the resulting DD-HDG solution strategy has an optimal convergence rate and can save both CPU time and memory cost compared to a classical upwind flux-based DD-DG (Domain Decomposed-Discontinuous Galerkin) approach.
Newton-Krylov-Schwarz: An implicit solver for CFD
NASA Technical Reports Server (NTRS)
Cai, Xiao-Chuan; Keyes, David E.; Venkatakrishnan, V.
1995-01-01
Newton-Krylov methods and Krylov-Schwarz (domain decomposition) methods have begun to become established in computational fluid dynamics (CFD) over the past decade. The former employ a Krylov method inside of Newton's method in a Jacobian-free manner, through directional differencing. The latter employ an overlapping Schwarz domain decomposition to derive a preconditioner for the Krylov accelerator that relies primarily on local information, for data-parallel concurrency. They may be composed as Newton-Krylov-Schwarz (NKS) methods, which seem particularly well suited for solving nonlinear elliptic systems in high-latency, distributed-memory environments. We give a brief description of this family of algorithms, with an emphasis on domain decomposition iterative aspects. We then describe numerical simulations with Newton-Krylov-Schwarz methods on aerodynamics applications emphasizing comparisons with a standard defect-correction approach, subdomain preconditioner consistency, subdomain preconditioner quality, and the effect of a coarse grid.
Semi-Markov Arnason-Schwarz models.
King, Ruth; Langrock, Roland
2016-06-01
We consider multi-state capture-recapture-recovery data where observed individuals are recorded in a set of possible discrete states. Traditionally, the Arnason-Schwarz model has been fitted to such data where the state process is modeled as a first-order Markov chain, though second-order models have also been proposed and fitted to data. However, low-order Markov models may not accurately represent the underlying biology. For example, specifying a (time-independent) first-order Markov process involves the assumption that the dwell time in each state (i.e., the duration of a stay in a given state) has a geometric distribution, and hence that the modal dwell time is one. Specifying time-dependent or higher-order processes provides additional flexibility, but at the expense of a potentially significant number of additional model parameters. We extend the Arnason-Schwarz model by specifying a semi-Markov model for the state process, where the dwell-time distribution is specified more generally, using, for example, a shifted Poisson or negative binomial distribution. A state expansion technique is applied in order to represent the resulting semi-Markov Arnason-Schwarz model in terms of a simpler and computationally tractable hidden Markov model. Semi-Markov Arnason-Schwarz models come with only a very modest increase in the number of parameters, yet permit a significantly more flexible state process. Model selection can be performed using standard procedures, and in particular via the use of information criteria. The semi-Markov approach allows for important biological inference to be drawn on the underlying state process, for example, on the times spent in the different states. The feasibility of the approach is demonstrated in a simulation study, before being applied to real data corresponding to house finches where the states correspond to the presence or absence of conjunctivitis. PMID:26584064
[Oswald Schwarz: a pioneer in psychosomatic urology and sexual medicine].
Berberich, H J; Schultheiss, D; Kieser, B
2015-01-01
Oswald Schwarz, a urologist from Vienna, was a scholar of Anton Ritter von Frisch and Hans Rubritius. As a physician during World War I, he was confronted with numerous bullet wounds to the spinal cord. In 1919, he completed his professorial thesis"Bladder dysfunction as a result of bullet wounds to the spinal cord". Oswald Schwarz was known as a committed surgeon. As an urologist he also treated patients with sexual dysfunction. Besides his practical and scientific urology-related work, he was also interested in psychology and philosophy. He held lectures on both subjects earning himself the nickname, the Urosoph. In the 1920s, Oswald Schwarz belonged to the inner circle of Alfred Adler, the founder of Individual Psychology, and was editor of the first psychosomatic textbook published in German, "Psychological origin and psychotherapy of physical symptoms" (1925). In addition, Schwarz wrote numerous articles and several books on sexual medicine. He also made many valuable contributions to the development of medical anthropology. Altogether, his work includes over 130 publications. Faced with the rise of fascism and National Socialism in Europe, Oswald Schwarz, who was of Jewish origin, emigrated to England in 1934. There he died in 1949. Unfortunately his scientific work has largely been forgotten. The aim of the following article is to remind us of his important contributions to the field. PMID:25537746
Laplacian growth, elliptic growth, and singularities of the Schwarz potential
NASA Astrophysics Data System (ADS)
Lundberg, Erik
2011-04-01
The Schwarz function has played an elegant role in understanding and in generating new examples of exact solutions to the Laplacian growth (or 'Hele-Shaw') problem in the plane. The guiding principle in this connection is the fact that 'non-physical' singularities in the 'oil domain' of the Schwarz function are stationary, and the 'physical' singularities obey simple dynamics. We give an elementary proof that the same holds in any number of dimensions for the Schwarz potential, introduced by Khavinson and Shapiro (1989 Technical Report TRITA-MAT-1989-36 Royal Institute of Technology, Stockholm). An extension is also given for the so-called elliptic growth problem by defining a generalized Schwarz potential. New exact solutions are constructed, and we solve inverse problems of describing the driving singularities of a given flow. We demonstrate, by example, how {C}^n-techniques can be used to locate the singularity set of the Schwarz potential. One of our methods is to prolong available local extension theorems by constructing 'globalizing families'.
Obituary: Hugo Schwarz, 1953-2006
NASA Astrophysics Data System (ADS)
Krisciunas, Kevin
2007-12-01
, p. 430, 2006). One of the projects well along at the time of his death was a collaboration with David Spergel and a number of REU summer students on the measurement of the polarization of 2,000 stars evenly distributed around this sky. This simple set of data being obtained with the NOT, a telescope Hugo helped make fully functional, will, by a factor of two, improve the sensitivity of experiments such as WMAP and Planck to the detection of gravity waves, one of the holy grails of experimental physics. Because of Hugo's sense of humor, enthusiasm, and perspective, he achieved a good balance between work and play. He could play the diplomat and hobnob with politicians and royalty. He also was proud of the fact that his native language, Dutch, is probably the best language for swearing. He often adopted a Glaswegian accent from his time at university, and would ask you a common question of bartenders there: "So, Jimmy, what's yer name?" He loved fine cigars, particularly the flojos (not-so-tightly rolled ones) from his cigar maker in La Palma, which he generously shared with friends. He loved having people over for barbecues, and would often make paella. Which newspaper was used to cover the large pan was important. It had to be left of center politically, but not too far left. On Hugo's fiftieth birthday a temporary addition was built onto the house, carpeting was laid out on the lawn, and there ensued a sit down dinner for 107 people, complete with live musicians, and many broken glasses. Hugo is survived by his wife Claudia Sanhueza, his two children Tamar and Jouke Schwarz, his step-children Maria Josefina and Diego Gomez, and his half-brother James Schwarz. More than anyone I can think of, he also leaves behind many friends who considered him their best friend.
A Refined Cauchy-Schwarz Inequality
ERIC Educational Resources Information Center
Mercer, Peter R.
2007-01-01
The author presents a refinement of the Cauchy-Schwarz inequality. He shows his computations in which refinements of the triangle inequality and its reverse inequality are obtained for nonzero x and y in a normed linear space.
Natural Scherk-Schwarz theories of the weak scale
NASA Astrophysics Data System (ADS)
García, Isabel García; Howe, Kiel; March-Russell, John
2015-12-01
Natural supersymmetric theories of the weak scale are under growing pressure given present LHC constraints, raising the question of whether untuned supersymmetric (SUSY) solutions to the hierarchy problem are possible. In this paper, we explore a class of 5-dimensional natural SUSY theories in which SUSY is broken by the Scherk-Schwarz mechanism. We pedagogically explain how Scherk-Schwarz elegantly solves the traditional problems of 4-dimensional SUSY theories (based on the MSSM and its many variants) that usually result in an unsettling level of fine-tuning. The minimal Scherk-Schwarz set up possesses novel phenomenology, which we briefly outline. We show that achieving the observed physical Higgs mass motivates extra structure that does not significantly affect the level of tuning (always better than ~ 10%) and we explore three qualitatively different extensions: the addition of extra matter that couples to the Higgs, an extra U(1)' gauge group under which the Higgs is charged and an NMSSM-like solution to the Higgs mass problem.
Natural Scherk-Schwarz theories of the weak scale
García, Isabel Garcia; Howe, Kiel; March-Russell, John
2015-12-01
Natural supersymmetric theories of the weak scale are under growing pressure given present LHC constraints, raising the question of whether untuned supersymmetric (SUSY) solutions to the hierarchy problem are possible. In this paper, we explore a class of 5-dimensional natural SUSY theories in which SUSY is broken by the Scherk-Schwarz mechanism. We pedagogically explain how Scherk-Schwarz elegantly solves the traditional problems of 4-dimensional SUSY theories (based on the MSSM and its many variants) that usually result in an unsettling level of fine-tuning. The minimal Scherk-Schwarz set up possesses novel phenomenology, which we briefly outline. In this study, we show that achieving the observed physical Higgs mass motivates extra structure that does not significantly affect the level of tuning (always better than ~10%) and we explore three qualitatively different extensions: the addition of extra matter that couples to the Higgs, an extra U(1)' gauge group under which the Higgs is charged and an NMSSM-like solution to the Higgs mass problem.
Natural Scherk-Schwarz theories of the weak scale
García, Isabel Garcia; Howe, Kiel; March-Russell, John
2015-12-01
Natural supersymmetric theories of the weak scale are under growing pressure given present LHC constraints, raising the question of whether untuned supersymmetric (SUSY) solutions to the hierarchy problem are possible. In this paper, we explore a class of 5-dimensional natural SUSY theories in which SUSY is broken by the Scherk-Schwarz mechanism. We pedagogically explain how Scherk-Schwarz elegantly solves the traditional problems of 4-dimensional SUSY theories (based on the MSSM and its many variants) that usually result in an unsettling level of fine-tuning. The minimal Scherk-Schwarz set up possesses novel phenomenology, which we briefly outline. In this study, we show thatmore » achieving the observed physical Higgs mass motivates extra structure that does not significantly affect the level of tuning (always better than ~10%) and we explore three qualitatively different extensions: the addition of extra matter that couples to the Higgs, an extra U(1)' gauge group under which the Higgs is charged and an NMSSM-like solution to the Higgs mass problem.« less
Parallel Newton-Krylov-Schwarz algorithms for the transonic full potential equation
NASA Technical Reports Server (NTRS)
Cai, Xiao-Chuan; Gropp, William D.; Keyes, David E.; Melvin, Robin G.; Young, David P.
1996-01-01
We study parallel two-level overlapping Schwarz algorithms for solving nonlinear finite element problems, in particular, for the full potential equation of aerodynamics discretized in two dimensions with bilinear elements. The overall algorithm, Newton-Krylov-Schwarz (NKS), employs an inexact finite-difference Newton method and a Krylov space iterative method, with a two-level overlapping Schwarz method as a preconditioner. We demonstrate that NKS, combined with a density upwinding continuation strategy for problems with weak shocks, is robust and, economical for this class of mixed elliptic-hyperbolic nonlinear partial differential equations, with proper specification of several parameters. We study upwinding parameters, inner convergence tolerance, coarse grid density, subdomain overlap, and the level of fill-in in the incomplete factorization, and report their effect on numerical convergence rate, overall execution time, and parallel efficiency on a distributed-memory parallel computer.
Newton-Krylov-Schwarz algorithms for the 2D full potential equation
Cai, Xiao-Chuan; Gropp, W.D.; Keyes, D.E.
1996-12-31
We study parallel two-level overlapping Schwarz algorithms for solving nonlinear finite element problems, in particular, for the full potential equation of aerodynamics discretized in two dimensions with bilinear elements. The main algorithm, Newton-Krylov-Schwarz (NKS), employs an inexact finite-difference Newton method and a Krylov space iterative method, with a two-level overlapping Schwarz method as a preconditioner. We demonstrate that NKS, combined with a density upwinding continuation strategy for problems with weak shocks, can be made robust for this class of mixed elliptic-hyperbolic nonlinear partial differential equations, with proper specification of several parameters. We study upwinding parameters, inner convergence tolerance, coarse grid density, subdomain overlap, and the level of fill-in in the incomplete factorization, and report favorable choices for numerical convergence rate and overall execution time on a distributed-memory parallel computer.
The ten-dimensional Green-Schwarz superstring is a twisted Neveu-Schwarz-Ramond string
NASA Astrophysics Data System (ADS)
Berkovits, Nathan
1994-05-01
An action for the ten-dimensional Green-Schwarz superstring with N = 2 world-sheet superconformal invariance has recently been quantized and used to calculate superstring scattering amplitudes. In this paper, it is shown that the N = 2 stress-energy tensor for this Green-Schwarz action can be constructed out of the stres-energy tensor and ghosts of the Neveu-Schwarz-Ramond action by the standard twisting procedure. In other words, a field redefinition is found from the GS matter fields into the NSR matter and ghost fields which transforms the matter part of the two fermionic GS superconformal generators into the b ghost and shifted BRST current of the NSR string. In light-cone gauge, this field redefinition reduces to the usual one relating the light-cone GS and NSR fields.
Technology Transfer Automated Retrieval System (TEKTRAN)
Two distinctive new species of the Neotropical stingless bee genus Paratrigona Schwarz from Ecuador and Paraguay are described and figured. The Ecuadorian species, P. scapisetosa sp. n., belongs to the haeckeli-lineatifrons group and is easily distinguished from its congeners by the unique shape and...
Studbook of Pan paniscus Schwarz, 1929.
Guzen, A
1975-01-01
On the basis of information provided by various zoos who have, or used to have, Pan paniscus in their collections, as well as information in the International Zoo Yearbook or in the literature, an approximate outline has been given of our knowledge of this animal since the description given in 1929 by Schwarz. The status of species is preferred to that of subspecies. The question whether the bonobo should be regarded as a true dwarf form is considered. It is, however, emphasized that the majority of researchers - and for different reasons - consider the species to be the primate closest to man. PMID:1163394
Bond additivity corrections for quantum chemistry methods
C. F. Melius; M. D. Allendorf
1999-04-01
In the 1980's, the authors developed a bond-additivity correction procedure for quantum chemical calculations called BAC-MP4, which has proven reliable in calculating the thermochemical properties of molecular species, including radicals as well as stable closed-shell species. New Bond Additivity Correction (BAC) methods have been developed for the G2 method, BAC-G2, as well as for a hybrid DFT/MP2 method, BAC-Hybrid. These BAC methods use a new form of BAC corrections, involving atomic, molecular, and bond-wise additive terms. These terms enable one to treat positive and negative ions as well as neutrals. The BAC-G2 method reduces errors in the G2 method due to nearest-neighbor bonds. The parameters within the BAC-G2 method only depend on atom types. Thus the BAC-G2 method can be used to determine the parameters needed by BAC methods involving lower levels of theory, such as BAC-Hybrid and BAC-MP4. The BAC-Hybrid method should scale well for large molecules. The BAC-Hybrid method uses the differences between the DFT and MP2 as an indicator of the method's accuracy, while the BAC-G2 method uses its internal methods (G1 and G2MP2) to provide an indicator of its accuracy. Indications of the average error as well as worst cases are provided for each of the BAC methods.
Bond additivity corrections for quantum chemistry methods
Melius, C.F.; Allendorf, M.D.
2000-03-23
New bond additivity correction (BAC) methods have been developed for the G2 method, BAC-G2, as well as for a hybrid density functional theory (DFT) Moller-Plesset (MP)2 method, BAC-hybrid. These BAC methods use a new form of BAC corrections, involving atomic, molecular, and bond-wise additive terms. These terms enable one to treat positive and negative ions as well as neutrals. The BAC-G2 method reduces errors in the G2 method due to nearest-neighbor bonds. The parameters within the BAC-G2 method only depend on atom types. Thus the BAC-G2 method can be used to determine the parameters needed by BAC methods involving lower levels of theory, such as BAC-hybrid and BAC-MP4. The BAC-hybrid method is expected to scale well for large molecules. The BAC-hybrid method uses the differences between the DFT and MP2 predictions as an indication of the method's accuracy, whereas the BAC-G2 method uses its internal methods (G1 and G2MP2) to accomplish this. A statistical analysis of the error in each of the methods is presented on the basis of calculations performed for large sets (more than 120) of molecules.
A Schwarz alternating procedure for singular perturbation problems
Garbey, M.; Kaper, H.G.
1994-12-31
The authors show that the Schwarz alternating procedure offers a good algorithm for the numerical solution of singular perturbation problems, provided the domain decomposition is properly designed to resolve the boundary and transition layers. They give sharp estimates for the optimal position of the domain boundaries and present convergence rates of the algorithm for various second-order singular perturbation problems. The splitting of the operator is domain-dependent, and the iterative solution of each subproblem is based on a modified asymptotic expansion of the operator. They show that this asymptotic-induced method leads to a family of efficient massively parallel algorithms and report on implementation results for a turning-point problem and a combustion problem.
Digitizing the Neveu-Schwarz model on the lightcone worldsheet
Thorn, Charles B.
2010-09-15
The purpose of this article is to extend the light-cone worldsheet lattice description of string theory to include the Neveu-Schwarz model. We model each component of the fermionic worldsheet field by a critical Ising model. We show that a simple choice of boundary conditions for the Ising variables leads to the half-integer modes required by the model. We identify the G-parity operation within the Ising model and formulate the procedure for projecting onto the even G-parity sector. We construct the lattice version of the three open string vertex, with the necessary operator insertion at the interaction point. We sketch a formalism for summing planar open string multiloop amplitudes, and we discuss prospects for numerically summing them. If successful, the methods described here could provide an alternative to lattice gauge theory for computations in large N QCD.
Effusion plate using additive manufacturing methods
Johnson, Thomas Edward; Keener, Christopher Paul; Ostebee, Heath Michael; Wegerif, Daniel Gerritt
2016-04-12
Additive manufacturing techniques may be utilized to construct effusion plates. Such additive manufacturing techniques may include defining a configuration for an effusion plate having one or more internal cooling channels. The manufacturing techniques may further include depositing a powder into a chamber, applying an energy source to the deposited powder, and consolidating the powder into a cross-sectional shape corresponding to the defined configuration. Such methods may be implemented to construct an effusion plate having one or more channels with a curved cross-sectional geometry.
Obituary: Hugo Schwarz, 1953-2006
NASA Astrophysics Data System (ADS)
Krisciunas, Kevin
2007-12-01
Hugo Schwarz died in a motorcycle accident on 20 October 2006 near his home in La Serena, Chile. At the time of his death he was a staff astronomer at Cerro Tololo Inter-American Observatory and President of IAU Commission 50 (The Protection of Existing and Potential Observatory Sites). After Hugo's half-brother Frans died when Hugo was an infant, he effectively grew up as an only child. One consequence was that Hugo became an avid reader. He once estimated that he had read between 3,000 and 4,000 books. He also moved around a great deal. For most of the first seven years of his life, Hugo lived in Venezuela because his father worked for Shell Oil Company. According to Hugo's count, he had a total of 43 different addresses in his life. This gave him experience with different cultures and a facility with several languages. He was fluent in Dutch, German, Spanish, and English, and knew some French. He was very fond of quoting his father's sayings in Dutch and liked to relate stories filled with Chilean-slang to people who understood neither, providing translations that retained the cleverness of the originals. While on holiday in Scotland in 1974, Hugo decided to enroll in the Glasgow College of Technology, as it was then known. A year later he transferred to the University of Glasgow, where he earned his BSc (1979) and PhD (officially in 1984). From 1982 to 1986 he worked on X-ray detectors for X-ray astronomy at Mullard Space Science Laboratory, south of London. In 1986 Hugo, his first wife Catriona (Cat), and their two children departed for Chile, where Hugo worked as a staff astronomer for the European Southern Observatory. Over the next nine years he spent over 1,300 nights at La Silla. A big change occurred in 1995 when Hugo moved to La Palma in the Canary Islands to be Astronomer in Charge of the Nordic Optical Telescope. He was very proud of having organized a team of astronomers and technicians who made the NOT into a valuable research facility with minimal
Supplier Selection Using Weighted Utility Additive Method
NASA Astrophysics Data System (ADS)
Karande, Prasad; Chakraborty, Shankar
2015-10-01
Supplier selection is a multi-criteria decision-making (MCDM) problem which mainly involves evaluating a number of available suppliers according to a set of common criteria for choosing the best one to meet the organizational needs. For any manufacturing or service organization, selecting the right upstream suppliers is a key success factor that will significantly reduce purchasing cost, increase downstream customer satisfaction and improve competitive ability. The past researchers have attempted to solve the supplier selection problem employing different MCDM techniques which involve active participation of the decision makers in the decision-making process. This paper deals with the application of weighted utility additive (WUTA) method for solving supplier selection problems. The WUTA method, an extension of utility additive approach, is based on ordinal regression and consists of building a piece-wise linear additive decision model from a preference structure using linear programming (LP). It adopts preference disaggregation principle and addresses the decision-making activities through operational models which need implicit preferences in the form of a preorder of reference alternatives or a subset of these alternatives present in the process. The preferential preorder provided by the decision maker is used as a restriction of a LP problem, which has its own objective function, minimization of the sum of the errors associated with the ranking of each alternative. Based on a given reference ranking of alternatives, one or more additive utility functions are derived. Using these utility functions, the weighted utilities for individual criterion values are combined into an overall weighted utility for a given alternative. It is observed that WUTA method, having a sound mathematical background, can provide accurate ranking to the candidate suppliers and choose the best one to fulfill the organizational requirements. Two real time examples are illustrated to prove
Green-Schwarz superstring on the lattice
NASA Astrophysics Data System (ADS)
Bianchi, L.; Bianchi, M. S.; Forini, V.; Leder, B.; Vescovi, E.
2016-07-01
We consider possible discretizations for a gauge-fixed Green-Schwarz action of Type IIB superstring. We use them for measuring the action, from which we extract the cusp anomalous dimension of planar N=4 SYM as derived from AdS/CFT, as well as the mass of the two AdS excitations transverse to the relevant null cusp classical string solution. We perform lattice simulations employing a Rational Hybrid Monte Carlo (RHMC) algorithm and two Wilson-like fermion discretizations, one of which preserves the global SO(6) symmetry the model. We compare our results with the expected behavior at various values of g=√{λ }/4π . For both the observables, we find a good agreement for large g, which is the perturbative regime of the sigma-model. For smaller values of g, the expectation value of the action exhibits a deviation compatible with the presence of quadratic divergences. After their non-perturbative subtraction the continuum limit can be taken, and suggests a qualitative agreement with the non-perturbative expectation from AdS/CFT. Furthermore, we detect a phase in the fermion determinant, whose origin we explain, that for small g leads to a sign problem not treatable via standard reweigthing. The continuum extrapolations of the observables in the two different discretizations agree within errors, which is strongly suggesting that they lead to the same continuum limit. Part of the results discussed here were presented earlier in [1].
A study of Schwarz converters for nuclear powered spacecraft
NASA Technical Reports Server (NTRS)
Stuart, Thomas A.; Schwarze, Gene E.
1987-01-01
High power space systems which use low dc voltage, high current sources such as thermoelectric generators, will most likely require high voltage conversion for transmission purposes. This study considers the use of the Schwarz resonant converter for use as the basic building block to accomplish this low-to-high voltage conversion for either a dc or an ac spacecraft bus. The Schwarz converter has the important assets of both inherent fault tolerance and resonant operation; parallel operation in modular form is possible. A regulated dc spacecraft bus requires only a single stage converter while a constant frequency ac bus requires a cascaded Schwarz converter configuration. If the power system requires constant output power from the dc generator, then a second converter is required to route unneeded power to a ballast load.
A study of Schwarz converters for nuclear powered spacecraft
Stuart, T.A.; Schwarze, G.E.
1994-09-01
High power space systems which use low dc voltage, high current sources such as thermoelectric generators, will most likely require high voltage conversion for transmission purposes. This study considers the use of the Schwarz resonant converter for use as the basic building block to accomplish this low-to-high voltage conversion for either a dc or an ac spacecraft bus. The Schwarz converter has the important assets of both inherent fault tolerance and resonant operation and parallel operation in modular form is possible. A regulated dc spacecraft bus requires only a single stage converter while a constant frequency ac bus requires a cascaded Schwarz converter configuration. If the power system requires constant output power from the dc generator, then a second converter is required to route unneeded power to a ballast load.
On Lie systems and Kummer-Schwarz equations
NASA Astrophysics Data System (ADS)
de Lucas, J.; Sardón, C.
2013-03-01
A Lie system is a system of first-order differential equations admitting a superposition rule, i.e., a map that expresses its general solution in terms of a generic family of particular solutions and certain constants. In this work, we use the geometric theory of Lie systems to prove that the explicit integration of second- and third-order Kummer-Schwarz equations is equivalent to obtaining a particular solution of a Lie system on SL(2,{R}). This same result can be extended to Riccati, Milne-Pinney, and to the here defined generalised Kummer-Schwarz equations, which include several types of Kummer-Schwarz equations as particular cases. We demonstrate that all the above-mentioned equations related to the same Lie system on SL(2,{R}) can be integrated simultaneously, which retrieves and generalizes in a unified and simpler manner previous results appearing in the literature. As a byproduct, we recover various properties of the Schwarzian derivative.
de Sitter symmetry of Neveu-Schwarz spinors
NASA Astrophysics Data System (ADS)
Epstein, Henri; Moschella, Ugo
2016-05-01
We study the relations between Dirac fields living on the 2-dimensional Lorentzian cylinder and the ones living on the double-covering of the 2-dimensional de Sitter manifold, here identified as a certain coset space of the group SL(2 , R). We show that there is an extended notion of de Sitter covariance only for Dirac fields having the Neveu-Schwarz anti-periodicity and construct the relevant cocycle. Finally, we show that the de Sitter symmetry is naturally inherited by the Neveu-Schwarz massless Dirac field on the cylinder.
Observations on supersymmetry breaking by Scherk-Schwarz mechanism
Sengupta, S. )
1991-04-10
This paper considers the 4-dimensional {ital N} = 1 supergravity theory that emerges by generalized dimensional reduction of the {ital d} = 10, {ital N} = 1 supergravity coupled to {ital E}{sub 8} {circle times} {ital E}{sub 8} super-Yang--Mills theory a la Scherk--Schwarz. It is shown that the Scherk--Schwarz mechanism leads to a spontaneously broken {ital N} = 1, {ital D} = 4 locally supersymmetric theory with vanishing cosmological constant only if some non-perturbative mechanism like gaugino condensation takes place in the hidden {ital E}{sub 8} sector.
Globalized Newton-Krylov-Schwarz Algorithms and Software for Parallel Implicit CFD
NASA Technical Reports Server (NTRS)
Gropp, W. D.; Keyes, D. E.; McInnes, L. C.; Tidriri, M. D.
1998-01-01
Implicit solution methods are important in applications modeled by PDEs with disparate temporal and spatial scales. Because such applications require high resolution with reasonable turnaround, "routine" parallelization is essential. The pseudo-transient matrix-free Newton-Krylov-Schwarz (Psi-NKS) algorithmic framework is presented as an answer. We show that, for the classical problem of three-dimensional transonic Euler flow about an M6 wing, Psi-NKS can simultaneously deliver: globalized, asymptotically rapid convergence through adaptive pseudo- transient continuation and Newton's method-, reasonable parallelizability for an implicit method through deferred synchronization and favorable communication-to-computation scaling in the Krylov linear solver; and high per- processor performance through attention to distributed memory and cache locality, especially through the Schwarz preconditioner. Two discouraging features of Psi-NKS methods are their sensitivity to the coding of the underlying PDE discretization and the large number of parameters that must be selected to govern convergence. We therefore distill several recommendations from our experience and from our reading of the literature on various algorithmic components of Psi-NKS, and we describe a freely available, MPI-based portable parallel software implementation of the solver employed here.
Evaluating Three Different Methods of Determining Addition in Presbyopia
Yazdani, Negareh; Khorasani, Abbas Azimi; Moghadam, Hanieh Mirhajian; Yekta, Abbas Ali; Ostadimoghaddam, Hadi; Shandiz, Javad Heravian
2016-01-01
Purpose: To compare three different methods for determining addition in presbyopes. Methods: The study included 81 subjects with presbyopia who aged 40-70 years. Reading addition values were measured using 3 approaches including the amplitude of accommodation (AA), dynamic retinoscopy (DR), and increasing plus lens (IPL). Results: IPL overestimated reading addition relative to other methods. Mean near addition obtained by AA, DR and IPL were 1.31, 1.68 and 1.77, respectively. Our results showed that IPL method could provide 20/20 vision at near in the majority of presbyopic subjects (63.4%). Conclusion: The results were approximately the same for 3 methods and provided comparable final addition; however, mean near additions were higher with increasing plus lens compared with the other two methods. In presbyopic individuals, increasing plus lens is recommended as the least time-consuming method with the range of ±0.50 diopter at the 40 cm working distance. PMID:27621785
10 CFR 2.705 - Discovery-additional methods.
Code of Federal Regulations, 2011 CFR
2011-01-01
... 10 Energy 1 2011-01-01 2011-01-01 false Discovery-additional methods. 2.705 Section 2.705 Energy NUCLEAR REGULATORY COMMISSION RULES OF PRACTICE FOR DOMESTIC LICENSING PROCEEDINGS AND ISSUANCE OF ORDERS Rules for Formal Adjudications § 2.705 Discovery-additional methods. (a) Discovery methods. Parties may obtain discovery by one or more of...
Schwarz-based algorithms for compressible flows
Tidriri, M.D.
1996-12-31
To compute steady compressible flows one often uses an implicit discretization approach which leads to a large sparse linear system that must be solved at each time step. In the derivation of this system one often uses a defect-correction procedure, in which the left-hand side of the system is discretized with a lower order approximation than that used for the right-hand side. This is due to storage considerations and computational complexity, and also to the fact that the resulting lower order matrix is better conditioned than the higher order matrix. The resulting schemes are only moderately implicit. In the case of structured, body-fitted grids, the linear system can easily be solved using approximate factorization (AF), which is among the most widely used methods for such grids. However, for unstructured grids, such techniques are no longer valid, and the system is solved using direct or iterative techniques. Because of the prohibitive computational costs and large memory requirements for the solution of compressible flows, iterative methods are preferred. In these defect-correction methods, which are implemented in most CFD computer codes, the mismatch in the right and left hand side operators, together with explicit treatment of the boundary conditions, lead to a severely limited CFL number, which results in a slow convergence to steady state aerodynamic solutions. Many authors have tried to replace explicit boundary conditions with implicit ones. Although they clearly demonstrate that high CFL numbers are possible, the reduction in CPU time is not clear cut.
Green-Schwarz superstring from type IIB matrix model
Kitazawa, Yoshihisa; Nagaoka, Satoshi
2008-01-15
We construct a Green-Schwarz (GS) light-cone closed superstring theory from the type IIB matrix model. A GS light-cone string action is derived from the two-dimensional N=8 U(n) noncommutative Yang-Mills (NCYM) theory by identifying a noncommutative scale with a string scale. The supersymmetry transformation for the light-cone gauge action is also derived from supersymmetry transformation for the IIB matrix model. By identifying the physical states and interaction vertices, string theory is perturbatively reproduced.
Supersymmetry of Green-Schwarz superstring and matrix string theory
Hyun, Seungjoon; Shin, Hyeonjoon
2001-08-15
We study the dynamics of a Green-Schwarz superstring on the gravitational wave background corresponding to the matrix string theory and the supersymmetry transformation rules of the superstring. The dynamics is obtained in the light-cone formulation and is shown to agree with that derived from matrix string theory. The supersymmetry structure has corrections due to the effect of the background and is identified with that of the low-energy one-loop effective action of matrix string theory in a two superstring background in the weak string coupling limit.
Coordinate system generation for internal flow problems via Schwarz-Christoffel transformation
NASA Astrophysics Data System (ADS)
Sridhar, K. P.
1981-06-01
Accurate grid generation for complex internal flow geometries is explored. Numerical integration of Schwarz-Christoffel transformations for both polygonal and curved surfaces is used. Singularities which occur in the transformation at corners are analytically addressed, and the affects of this treatment on the mapping accuracy are presented. The transformation for curved elements is also described, and the consistency of the assumptions of the method with the accuracy of the integration scheme is discussed. The method shows second order accurately for surfaces described by polygonal elements and fourth order accurately for surfaces described by curved elements. Several calculations related to the mapping procedure are presented. The method directly provides the two dimensional incompressible potential flow solution as well as a simple relation for calculating the grid metric coefficients.
Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-07
... inviting public comment has been given in the Federal Register (74 FR 45612-45613, 9/3/2009) and the... Foreign-Trade Zones Board Grant of Authority for Subzone Status; Schwarz Pharma Manufacturing, Inc... special- purpose subzone at the pharmaceutical manufacturing and distribution facility of Schwarz...
Optimal Multicomponent Analysis Using the Generalized Standard Addition Method.
ERIC Educational Resources Information Center
Raymond, Margaret; And Others
1983-01-01
Describes an experiment on the simultaneous determination of chromium and magnesium by spectophotometry modified to include the Generalized Standard Addition Method computer program, a multivariate calibration method that provides optimal multicomponent analysis in the presence of interference and matrix effects. Provides instructions for…
Domain decomposition based iterative methods for nonlinear elliptic finite element problems
Cai, X.C.
1994-12-31
The class of overlapping Schwarz algorithms has been extensively studied for linear elliptic finite element problems. In this presentation, the author considers the solution of systems of nonlinear algebraic equations arising from the finite element discretization of some nonlinear elliptic equations. Several overlapping Schwarz algorithms, including the additive and multiplicative versions, with inexact Newton acceleration will be discussed. The author shows that the convergence rate of the Newton`s method is independent of the mesh size used in the finite element discretization, and also independent of the number of subdomains into which the original domain in decomposed. Numerical examples will be presented.
NASA Technical Reports Server (NTRS)
Smalheer, C. V.
1973-01-01
The chemistry of lubricant additives is discussed to show what the additives are chemically and what functions they perform in the lubrication of various kinds of equipment. Current theories regarding the mode of action of lubricant additives are presented. The additive groups discussed include the following: (1) detergents and dispersants, (2) corrosion inhibitors, (3) antioxidants, (4) viscosity index improvers, (5) pour point depressants, and (6) antifouling agents.
Additive manufacturing method for SRF components of various geometries
Rimmer, Robert; Frigola, Pedro E; Murokh, Alex Y
2015-05-05
An additive manufacturing method for forming nearly monolithic SRF niobium cavities and end group components of arbitrary shape with features such as optimized wall thickness and integral stiffeners, greatly reducing the cost and technical variability of conventional cavity construction. The additive manufacturing method for forming an SRF cavity, includes atomizing niobium to form a niobium powder, feeding the niobium powder into an electron beam melter under a vacuum, melting the niobium powder under a vacuum in the electron beam melter to form an SRF cavity; and polishing the inside surface of the SRF cavity.
Application of rational functions for the standard addition method.
Gorazda, Katarzyna; Michałowska-Kaczmarczyk, Anna M; Asuero, Agustin G; Michałowski, Tadeusz
2013-11-15
Some rational functions are considered as the basis for calculation of unknown concentration (x0) of an analyte X determined according to the standard addition method (SAM). The correction for dilution of the sample tested during addition of successive increments of standard(ised) solution of X is involved in the related algorithm applied for calculation of the x0 value. The formulae derived were put in context with experimental data, obtained according to the AAS method from Cu-measurements in samples obtained by digestion of an ash obtained from incinerated sludge. It was stated that the use of rational functions for modeling purposes strengthens the robustness of the results thus obtained. PMID:24148496
Methods for detecting additional genes underlying Alzheimer disease
Locke, P.A.; Haines, J.L.; Ter-Minassian, M.
1994-09-01
Alzheimer`s disease (AD) is a complex inherited disorder with proven genetic heterogeneity. To date, genes on chromosome 21 (APP) and 14 (not yet identified) are associated with early-onset familial AD, while the APOE gene on chromosome 19 is associated with both late onset familial and sporadic AD and early onset sporadic AD. Although these genes likely account for the majority of AD, many familial cases cannot be traced to any of these genes. From a set of 127 late-onset multiplex families screened for APOE, 43 (34%) families have at least one affected individual with no APOE-4 allele, suggesting an alternative genetic etiology. Simulation studies indicated that additional loci could be identified through a genomic screen with a 10 cM sieve on a subset of 21 well documented, non-APOE-4 families. Given the uncertainties in the mode of inheritance, reliance on a single analytical method could result in a missed linkage. Therefore, we have developed a strategy of using multiple overlapping yet complementary methods to detect linkage. These include sib-pair analysis and affected-pedigree-member analysis, neither of which makes assumptions about mode of inheritance, and lod score analysis (using two predefined genetic models). In order for a marker to qualify for follow-up, it must fit at least two of three criteria. These are nominal P values of 0.05 or less for the non-parametric methods, and/or a lod score greater than 1.0. Adjacent markers each fulfilling a single criterion also warrant follow-up. To date, we have screened 61 markers on chromosomes 1, 2, 3, 18, 19, 21, and 22. One marker, D2S163, generated a lod score of 1.06 ({theta} = 0.15) and an APMT statistic of 3.68 (P < 0.001). This region is currently being investigated in more detail. Updated results of this region plus additional screening data will be presented.
Method for controlling a laser additive process using intrinsic illumination
NASA Astrophysics Data System (ADS)
Tait, Robert; Cai, Guoshuang; Azer, Magdi; Chen, Xiaobin; Liu, Yong; Harding, Kevin
2015-05-01
One form of additive manufacturing is to use a laser to generate a melt pool from powdered metal that is sprayed from a nozzle. The laser net-shape machining system builds the part a layer at a time by following a predetermined path. However, because the path may need to take many turns, maintaining a constant melt pool may not be easy. A straight section may require one speed and power while a sharp bend would over melt the metal at the same settings. This paper describes a process monitoring method that uses the intrinsic IR radiation from the melt pool along with a process model configured to establish target values for the parameters associated with the manufacture or repair. This model is based upon known properties of the metal being used as well as the properties of the laser beam. An adaptive control technique is then employed to control process parameters of the machining system based upon the real-time weld pool measurement. Since the system uses the heat radiant from the melt pool, other previously deposited metal does not confuse the system as only the melted material is seen by the camera.
The Cauchy-Schwarz Inequality and the Induced Metrics on Real Vector Spaces Mainly on the Real Line
ERIC Educational Resources Information Center
Ramasinghe, W.
2005-01-01
It is very well known that the Cauchy-Schwarz inequality is an important property shared by all inner product spaces and the inner product induces a norm on the space. A proof of the Cauchy-Schwarz inequality for real inner product spaces exists, which does not employ the homogeneous property of the inner product. However, it is shown that a real…
A 2.5 kW cascaded Schwarz converter for 20 kHz power distribution
NASA Technical Reports Server (NTRS)
Shetler, Russell E.; Stuart, Thomas A.
1989-01-01
Because it avoids the high currents in a parallel loaded capacitor, the cascaded Schwarz converter should offer better component utilization than converters with sinusoidal output voltages. The circuit is relatively easy to protect, and it provides a predictable trapezoidal voltage waveform that should be satisfactory for 20-kHz distribution systems. Analysis of the system is enhanced by plotting curves of normalized variables vs. gamma(1), where gamma(1) is proportional to the variable frequency of the first stage. Light-load operation is greatly improved by the addition of a power recycling rectifier bridge that is back biased at medium to heavy loads. Operation has been verified on a 2.5-kW circuit that uses input and output voltages in the same range as those anticipated for certain future spacecraft power systems.
A 2.5 kW cascaded Schwarz converter for 20 kHz power distribution
NASA Astrophysics Data System (ADS)
Shetler, Russell E.; Stuart, Thomas A.
Because it avoids the high currents in a parallel loaded capacitor, the cascaded Schwarz converter should offer better component utilization than converters with sinusoidal output voltages. The circuit is relatively easy to protect, and it provides a predictable trapezoidal voltage waveform that should be satisfactory for 20-kHz distribution systems. Analysis of the system is enhanced by plotting curves of normalized variables vs. gamma(1), where gamma(1) is proportional to the variable frequency of the first stage. Light-load operation is greatly improved by the addition of a power recycling rectifier bridge that is back biased at medium to heavy loads. Operation has been verified on a 2.5-kW circuit that uses input and output voltages in the same range as those anticipated for certain future spacecraft power systems.
Symmetry and singularity properties of the generalised Kummer-Schwarz and related equations
NASA Astrophysics Data System (ADS)
Leach, P. G. L.
2008-12-01
We examine the generalised Kummer-Schwarz equation and some of its generalisations from the viewpoints of symmetry and singularity analyses. We determine the Complete Symmetry Group of the general equation and show that different forms of the fourth-order representative illustrate the three possible classes of Laurent series to be expected in the course of the singularity analysis.
Additives and method for controlling clathrate hydrates in fluid systems
Sloan, E.D. Jr.; Christiansen, R.L.; Lederhos, J.P.; Long, J.P.; Panchalingam, V.; Du, Y.; Sum, A.K.W.
1997-06-17
Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hindrance and/or charge repulsion. Also, polymers having an amide on which a C{sub 1}-C{sub 4} group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.
Additives and method for controlling clathrate hydrates in fluid systems
Sloan, Jr., Earle Dendy; Christiansen, Richard Lee; Lederhos, Joseph P.; Long, Jin Ping; Panchalingam, Vaithilingam; Du, Yahe; Sum, Amadeu Kun Wan
1997-01-01
Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.
A Hybrid, Parallel Krylov Solver for MODFLOW using Schwarz Domain Decomposition
NASA Astrophysics Data System (ADS)
Sutanudjaja, E.; Verkaik, J.; Hughes, J. D.
2015-12-01
In order to support decision makers in solving hydrological problems, detailed high-resolution models are often needed. These models typically consist of a large number of computational cells and have large memory requirements and long run times. An efficient technique for obtaining realistic run times and memory requirements is parallel computing, where the problem is divided over multiple processor cores. The new Parallel Krylov Solver (PKS) for MODFLOW-USG is presented. It combines both distributed memory parallelization by the Message Passing Interface (MPI) and shared memory parallelization by Open Multi-Processing (OpenMP). PKS includes conjugate gradient and biconjugate gradient stabilized linear accelerators that are both preconditioned by an overlapping additive Schwarz preconditioner in a way that: a) subdomains are partitioned using the METIS library; b) each subdomain uses local memory only and communicates with other subdomains by MPI within the linear accelerator; c) is fully integrated in the MODFLOW-USG code. PKS is based on the unstructured PCGU-solver, and supports OpenMP. Depending on the available hardware, PKS can run exclusively with MPI, exclusively with OpenMP, or with a hybrid MPI/OpenMP approach. Benchmarks were performed on the Cartesius Dutch supercomputer (https://userinfo.surfsara.nl/systems/cartesius) using up to 144 cores, for a synthetic test (~112 million cells) and the Indonesia groundwater model (~4 million 1km cells). The latter, which includes all islands in the Indonesian archipelago, was built using publically available global datasets, and is an ideal test bed for evaluating the applicability of PKS parallelization techniques to a global groundwater model consisting of multiple continents and islands. Results show that run time reductions can be greatest with the hybrid parallelization approach for the problems tested.
System and method for high power diode based additive manufacturing
El-Dasher, Bassem S.; Bayramian, Andrew; Demuth, James A.; Farmer, Joseph C.; Torres, Sharon G.
2016-04-12
A system is disclosed for performing an Additive Manufacturing (AM) fabrication process on a powdered material forming a substrate. The system may make use of a diode array for generating an optical signal sufficient to melt a powdered material of the substrate. A mask may be used for preventing a first predetermined portion of the optical signal from reaching the substrate, while allowing a second predetermined portion to reach the substrate. At least one processor may be used for controlling an output of the diode array.
Flux formulation of DFT on group manifolds and generalized Scherk-Schwarz compactifications
NASA Astrophysics Data System (ADS)
du Bosque, Pascal; Hassler, Falk; Lüst, Dieter
2016-02-01
A flux formulation of Double Field Theory on group manifold is derived and applied to study generalized Scherk-Schwarz compactifications, which give rise to a bosonic subsector of half-maximal, electrically gauged supergravities. In contrast to the flux formulation of original DFT, the covariant fluxes split into a fluctuation and a background part. The latter is connected to a 2 D-dimensional, pseudo Riemannian manifold, which is isomorphic to a Lie group embedded into O( D,D). All fields and parameters of generalized diffeomorphisms are supported on this manifold, whose metric is spanned by the background vielbein E A I ∈ GL(2 D). This vielbein takes the role of the twist in conventional generalized Scherk-Schwarz compactifications. By doing so, it solves the long standing problem of constructing an appropriate twist for each solution of the embedding tensor. Using the geometric structure, absent in original DFT, E A I is identified with the left invariant Maurer-Cartan form on the group manifold, in the same way as it is done in geometric Scherk-Schwarz reductions. We show in detail how the Maurer-Cartan form for semisimple and solvable Lie groups is constructed starting from the Lie algebra. For all compact embeddings in O(3 , 3), we calculate E A I .
T-duality of Green-Schwarz superstrings on AdS d × S d × M 10-2 d
NASA Astrophysics Data System (ADS)
Abbott, Michael C.; Murugan, Jeff; Penati, Silvia; Pittelli, Antonio; Sorokin, Dmitri; Sundin, Per; Tarrant, Justine; Wolf, Martin; Wulff, Linus
2015-12-01
We verify the self-duality of Green-Schwarz supercoset sigma models on AdS d × S d backgrounds ( d = 2 , 3 , 5) under combined bosonic and fermionic T-dualities without gauge fixing kappa symmetry. We also prove this property for superstrings on AdS d × S d × S d ( d = 2 , 3) described by supercoset sigma models with the isometries governed by the exceptional Lie supergroups D(2 , 1; α) ( d = 2) and D(2 , 1; α) × D(2 , 1; α) ( d = 3), which requires an additional T-dualisation along one of the spheres. Then, by taking into account the contribution of non-supercoset fermionic modes (up to the second order), we provide evidence for the T-self-duality of the complete type IIA and IIB Green-Schwarz superstring theory on AdS d × S d × T 10-2 d ( d = 2 , 3) backgrounds with Ramond-Ramond fluxes. Finally, applying the Buscher-like rules to T-dualising supergravity fields, we prove the T-self-duality of the whole class of the AdS d × S d × M 10-2 d superbackgrounds with Ramond-Ramond fluxes in the context of supergravity.
ERIC Educational Resources Information Center
Fernandez, Ceneida; Llinares, Salvador; Van Dooren, Wim; De Bock, Dirk; Verschaffel, Lieven
2012-01-01
This study investigates the development of proportional and additive methods along primary and secondary school. In particular, it simultaneously investigates the use of additive methods in proportional word problems and the use of proportional methods in additive word problems. We have also studied the role played by integer and non-integer…
On the use of Schwarz-Christoffel conformal mappings to the grid generation for global ocean models
NASA Astrophysics Data System (ADS)
Xu, S.; Wang, B.; Liu, J.
2015-10-01
In this article we propose two grid generation methods for global ocean general circulation models. Contrary to conventional dipolar or tripolar grids, the proposed methods are based on Schwarz-Christoffel conformal mappings that map areas with user-prescribed, irregular boundaries to those with regular boundaries (i.e., disks, slits, etc.). The first method aims at improving existing dipolar grids. Compared with existing grids, the sample grid achieves a better trade-off between the enlargement of the latitudinal-longitudinal portion and the overall smooth grid cell size transition. The second method addresses more modern and advanced grid design requirements arising from high-resolution and multi-scale ocean modeling. The generated grids could potentially achieve the alignment of grid lines to the large-scale coastlines, enhanced spatial resolution in coastal regions, and easier computational load balance. Since the grids are orthogonal curvilinear, they can be easily utilized by the majority of ocean general circulation models that are based on finite difference and require grid orthogonality. The proposed grid generation algorithms can also be applied to the grid generation for regional ocean modeling where complex land-sea distribution is present.
Ruck, Nora; Slunecko, Thomas
2010-06-01
In his article "Is psychology based on a methodological error?" and based on a quite convincing empirical basis, Michael Schwarz offers a methodological critique of one of mainstream psychology's key test theoretical axioms, i.e., that of the in principle normal distribution of personality variables. It is characteristic of this paper--and at first seems to be a strength of it--that the author positions his critique within a frame of philosophy of science, particularly positioning himself in the tradition of Karl Popper's critical rationalism. When scrutinizing Schwarz's arguments, however, we find Schwarz's critique profound only as an immanent critique of test theoretical axioms. We raise doubts, however, as to Schwarz's alleged 'challenge' to the philosophy of science because the author not at all seems to be in touch with the state of the art of contemporary philosophy of science. Above all, we question the universalist undercurrent that Schwarz's 'bio-psycho-social model' of human judgment boils down to. In contrast to such position, we close our commentary with a plea for a context- and culture sensitive philosophy of science. PMID:20369392
Analysis of generalized Schwarz alternating procedure for domain decomposition
Engquist, B.; Zhao, Hongkai
1996-12-31
The Schwartz alternating method(SAM) is the theoretical basis for domain decomposition which itself is a powerful tool both for parallel computation and for computing in complicated domains. The convergence rate of the classical SAM is very sensitive to the overlapping size between each subdomain, which is not desirable for most applications. We propose a generalized SAM procedure which is an extension of the modified SAM proposed by P.-L. Lions. Instead of using only Dirichlet data at the artificial boundary between subdomains, we take a convex combination of u and {partial_derivative}u/{partial_derivative}n, i.e. {partial_derivative}u/{partial_derivative}n + {Lambda}u, where {Lambda} is some {open_quotes}positive{close_quotes} operator. Convergence of the modified SAM without overlapping in a quite general setting has been proven by P.-L.Lions using delicate energy estimates. The important questions remain for the generalized SAM. (1) What is the most essential mechanism for convergence without overlapping? (2) Given the partial differential equation, what is the best choice for the positive operator {Lambda}? (3) In the overlapping case, is the generalized SAM superior to the classical SAM? (4) What is the convergence rate and what does it depend on? (5) Numerically can we obtain an easy to implement operator {Lambda} such that the convergence is independent of the mesh size. To analyze the convergence of the generalized SAM we focus, for simplicity, on the Poisson equation for two typical geometry in two subdomain case.
Ishiwata, H; Takeda, Y; Kawasaki, Y; Kubota, H; Yamada, T
1996-01-01
The official methods for 'readily oxidizable substances (ROS)' in propionic acid as a food additive were compared. The methods examined were those adopted in the Compendium of Food Additive Specifications (CFAS) by the Joint FAO-WHO Expert Committee on Food Additives, FAO, The Japanese Standards for Food Additives (JSFA) by the Ministry of Health and Welfare, Japan, and the Food Chemicals Codex (FCC) by the National Research Council, USA. The methods given in CFAS and JSFA are the same (potassium permanganate consumption). However, by this method, manganese (VII) in potassium permanganate was readily reduced to colourless manganese(II) with some substances contained in the propionic acid before reacting with aldehydes, which are generally considered as 'readily oxidizable substances', to form brown manganese (IV) oxide. The FCC method (bromine consumption) for 'ROS' could be recommended because it was able to obtain quantitative results of 'ROS', including aldehydes. PMID:8647299
NASA Astrophysics Data System (ADS)
Chaudhuri, Shyamoli
2014-12-01
We derive the Euclidean time formulation for the equilibrium canonical ensemble of the type IIA and type IIB superstrings, and the spin(32 )/Z2 heterotic string. We compactify on R8×T2 , and twist by the Neveu-Schwarz sector antisymmetric 2-form B -field potential, spontaneously breaking supersymmetry at low temperatures, while preserving the tachyon-free low-energy gravitational field theory limit. We verify that the super partners of the massless dilaton-graviton multiplet obtain a mass which is linear in the temperature. In addition, we show that the free energy for the superstring canonical ensemble at weak coupling is always strongly convergent in the ultraviolet, high-temperature, regime dominated by the highest mass level number states. We derive the precise form of the exponential suppression as a linear power of the mass level, which erases the exponential Hagedorn growth of the degeneracies as the square root of mass level number. Finally, we close a gap in previous research giving an unambiguous derivation of the normalization of the one-loop vacuum energy density of the spin(32 )/Z2 perturbative heterotic string theory. Invoking the O(32) type IB-heterotic strong-weak duality, we match the normalization of the one loop vacuum energy densities of the T -dual O(32) type IA open and closed string with that of the spin(32 )/Z2 heterotic string on R9×S1 , for values of the compactification radius, R[O (32 )] , RIB≫ α'1 /2 , with RIA<α'1 /2 . We show that the type IA thermal solitonic winding spectrum is a simple model for finite temperature pure QCD, transitioning above the critical duality phase transformation temperature to the deconfined ensemble of thermally excited IB gluons.
40 CFR 80.8 - Sampling methods for gasoline, diesel fuel, fuel additives, and renewable fuels.
Code of Federal Regulations, 2014 CFR
2014-07-01
... of the Federal Register under 5 U.S.C. 552(a) and 1 CFR part 51. To enforce any edition other than... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Sampling methods for gasoline, diesel... Provisions § 80.8 Sampling methods for gasoline, diesel fuel, fuel additives, and renewable fuels....
Stork, LeAnna M.; Gennings, Chris; Carchman, Richard; Carter, Jr., Walter H.; Pounds, Joel G.; Mumtaz, Moiz
2006-12-01
Several assumptions, defined and undefined, are used in the toxicity assessment of chemical mixtures. In scientific practice mixture components in the low-dose region, particularly subthreshold doses, are often assumed to behave additively (i.e., zero interaction) based on heuristic arguments. This assumption has important implications in the practice of risk assessment, but has not been experimentally tested. We have developed methodology to test for additivity in the sense of Berenbaum (Advances in Cancer Research, 1981), based on the statistical equivalence testing literature where the null hypothesis of interaction is rejected for the alternative hypothesis of additivity when data support the claim. The implication of this approach is that conclusions of additivity are made with a false positive rate controlled by the experimenter. The claim of additivity is based on prespecified additivity margins, which are chosen using expert biological judgment such that small deviations from additivity, which are not considered to be biologically important, are not statistically significant. This approach is in contrast to the usual hypothesis-testing framework that assumes additivity in the null hypothesis and rejects when there is significant evidence of interaction. In this scenario, failure to reject may be due to lack of statistical power making the claim of additivity problematic. The proposed method is illustrated in a mixture of five organophosphorus pesticides that were experimentally evaluated alone and at relevant mixing ratios. Motor activity was assessed in adult male rats following acute exposure. Four low-dose mixture groups were evaluated. Evidence of additivity is found in three of the four low-dose mixture groups.The proposed method tests for additivity of the whole mixture and does not take into account subset interactions (e.g., synergistic, antagonistic) that may have occurred and cancelled each other out.
Domain decomposition methods for nonconforming finite element spaces of Lagrange-type
NASA Technical Reports Server (NTRS)
Cowsar, Lawrence C.
1993-01-01
In this article, we consider the application of three popular domain decomposition methods to Lagrange-type nonconforming finite element discretizations of scalar, self-adjoint, second order elliptic equations. The additive Schwarz method of Dryja and Widlund, the vertex space method of Smith, and the balancing method of Mandel applied to nonconforming elements are shown to converge at a rate no worse than their applications to the standard conforming piecewise linear Galerkin discretization. Essentially, the theory for the nonconforming elements is inherited from the existing theory for the conforming elements with only modest modification by constructing an isomorphism between the nonconforming finite element space and a space of continuous piecewise linear functions.
Comparison of prosthetic models produced by traditional and additive manufacturing methods
Park, Jin-Young; Kim, Hae-Young; Kim, Ji-Hwan; Kim, Jae-Hong
2015-01-01
PURPOSE The purpose of this study was to verify the clinical-feasibility of additive manufacturing by comparing the accuracy of four different manufacturing methods for metal coping: the conventional lost wax technique (CLWT); subtractive methods with wax blank milling (WBM); and two additive methods, multi jet modeling (MJM), and micro-stereolithography (Micro-SLA). MATERIALS AND METHODS Thirty study models were created using an acrylic model with the maxillary upper right canine, first premolar, and first molar teeth. Based on the scan files from a non-contact blue light scanner (Identica; Medit Co. Ltd., Seoul, Korea), thirty cores were produced using the WBM, MJM, and Micro-SLA methods, respectively, and another thirty frameworks were produced using the CLWT method. To measure the marginal and internal gap, the silicone replica method was adopted, and the silicone images obtained were evaluated using a digital microscope (KH-7700; Hirox, Tokyo, Japan) at 140X magnification. Analyses were performed using two-way analysis of variance (ANOVA) and Tukey post hoc test (α=.05). RESULTS The mean marginal gaps and internal gaps showed significant differences according to tooth type (P<.001 and P<.001, respectively) and manufacturing method (P<.037 and P<.001, respectively). Micro-SLA did not show any significant difference from CLWT regarding mean marginal gap compared to the WBM and MJM methods. CONCLUSION The mean values of gaps resulting from the four different manufacturing methods were within a clinically allowable range, and, thus, the clinical use of additive manufacturing methods is acceptable as an alternative to the traditional lost wax-technique and subtractive manufacturing. PMID:26330976
ERIC Educational Resources Information Center
Meester-Delver, Anke; Beelen, Anita; Hennekam, Raoul; Nollet, Frans; Hadders-Algra, Mijna
2007-01-01
The aim of this study was to determine the interrater reliability and stability over time of the Capacity Profile (CAP). The CAP is a standardized method for classifying additional care needs indicated by current impairments in five domains of body functions: physical health, neuromusculoskeletal and movement-related, sensory, mental, and voice…
Releasing-addition method for the flame-photometric determination of calcium in thermal waters
Rowe, J.J.
1963-01-01
Study of the interferences of silica and sulfate in the flame-photometric determination of calcium in thermal waters has led to the development of a method requiring no prior chemical separations. The interference effects of silica, sulfate, potassium, sodium, aluminum, and phosphate are overcome by an addition technique coupled with the use of magnesium as a releasing agent. ?? 1963.
NASA Astrophysics Data System (ADS)
Pagliano, Enea; Meija, Juris
2016-04-01
The combination of isotope dilution and mass spectrometry has become an ubiquitous tool of chemical analysis. Often perceived as one of the most accurate methods of chemical analysis, it is not without shortcomings. Current isotope dilution equations are not capable of fully addressing one of the key problems encountered in chemical analysis: the possible effect of sample matrix on measured isotope ratios. The method of standard addition does compensate for the effect of sample matrix by making sure that all measured solutions have identical composition. While it is impossible to attain such condition in traditional isotope dilution, we present equations which allow for matrix-matching between all measured solutions by fusion of isotope dilution and standard addition methods.
A Modified Time-Delay Addition Method to Extract Resistive Leakage Current of MOSA
NASA Astrophysics Data System (ADS)
Khodsuz, Masume; Mirzaie, Mohammad
2015-06-01
Metal oxide surge arresters are one of the most important equipment for power system protection against switching and lightning over-voltages. High-energy stresses and environmental features are the main factors which degrade surge arresters. In order to verify surge arresters good condition, their monitoring is necessary. The majority of surge arrester monitoring techniques is based on total leakage current decomposition of their capacitive and resistive components. This paper introduces a new approach based on time-delay addition method to extract the resistive current from the total leakage current without measuring voltage signal. Surge arrester model for calculating leakage current has been performed in ATP-EMTP. In addition, the signal processing has been done using MATLAB software. To show the accuracy of the proposed method, experimental tests have been performed to extract resistive leakage current by the proposed method.
Sharma, S.P.; Huo, W.M.; Park, C.
1988-01-01
A theoretical study of vibrational excitations and dissociations of nitrogen undergoing a nonequilibrium relaxation process upon heating and cooling is reported. The rate coefficients for collisional induced vibrational transitions and transitions from a bound vibrational state into a dissociative state have been calculated using an extension of the theory originally proposed by Schwarz (SSH) et al. (1952). High-lying vibrational states and dissociative states were explicitly included but rotational energy transfer was neglected. The transition probabilities calculated from the SSH theory were fed into the master equation, which was integrated numerically to determine the population distribution of the vibrational states as well as bulk thermodynamic properties. The results show that: (1) the transition rates have a minimum near the middle of the bound vibrational levels, causing a bottleneck in the vibrational relaxation and dissociation rates; (2) high vibrational states are always in equilibrium with the dissociative state; (3) for the heating case, only the low vibrational states relax according to the Landau-Teller theory; (4) for the cooling case, vibrational relaxation cannot be described by a rate equation; (5) Park's (1985, 1988) two-temperature model is approximately valid; and (6) the average vibrational energy removed in dissociation is about 30 percent of the dissociation energy. 29 references.
Bogdan, Malgorzata; Ghosh, Jayanta K; Doerge, R W
2004-01-01
The problem of locating multiple interacting quantitative trait loci (QTL) can be addressed as a multiple regression problem, with marker genotypes being the regressor variables. An important and difficult part in fitting such a regression model is the estimation of the QTL number and respective interactions. Among the many model selection criteria that can be used to estimate the number of regressor variables, none are used to estimate the number of interactions. Our simulations demonstrate that epistatic terms appearing in a model without the related main effects cause the standard model selection criteria to have a strong tendency to overestimate the number of interactions, and so the QTL number. With this as our motivation we investigate the behavior of the Schwarz Bayesian information criterion (BIC) by explaining the phenomenon of the overestimation and proposing a novel modification of BIC that allows the detection of main effects and pairwise interactions in a backcross population. Results of an extensive simulation study demonstrate that our modified version of BIC performs very well in practice. Our methodology can be extended to general populations and higher-order interactions. PMID:15238547
Friede, H.; Nass, K.H.; Breuer, H.
1995-06-01
VEAG, the newly founded company for supraregional power generation and distribution in eastern Germany, is retrofitting certain power plants with flue-gas desulfurization (FGD) facilities. Lignite is used almost exclusively as fuel in these power plants. Following German unification, the pollution control regulations in force in the Federal Republic of Germany also apply to the power plants operated by VEAG. The decision was made in principle to only build FGDs which are based on the proven limestone scrubbing process and produce recyclable gypsum as the end product. Experience accumulated with FGDs in lignite-fired power plants resulted in a new concept, which elaborated in cooperation with the commissioned consultants (including Siemens/KWU). This paper will present using the example of a new power plant project with FGD - the 2 x 800-MW power plant Schwarze Pumpe - and an FGD retrofit - the 3 x 1000-MW power plant Janschwalde - the salient features of these facilities (full-metal scrubbers, slurry-carrying pipework and treated-flue-gas ducts made of FRP, flue-gas heat recovery, fine-grained solids separation to improve gypsum quality, use of FGD wastewater for ash moistening and gypsum recycling), an overview of the design as well as construction progress and scheduling. The two FGD facilities are being supplied by KRC/Noell and operate on a two-circuit principle.
Methods of cracking a crude product to produce additional crude products
Mo, Weijian; Roes, Augustinus Wilhelmus Maria; Nair, Vijay
2009-09-08
A method for producing a crude product is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce one or more crude products. At least one of the crude products has a boiling range distribution from 38.degree. C. and 343.degree. C. as determined by ASTM Method D5307. The crude product having the boiling range distribution from 38.degree. C. and 343.degree. C. is catalytically cracked to produce one or more additional crude products. At least one of the additional crude products is a second gas stream. The second gas stream has a boiling point of at most 38.degree. C. at 0.101 MPa.
Pan, W; Coatrieux, G; Cuppens, N; Cuppens, F; Roux, Ch
2010-01-01
In this article, we propose a new additive lossless watermarking scheme which identifies parts of the image that can be reversibly watermarked and conducts message embedding in the conventional Haar wavelet transform coefficients. Our approach makes use of an approximation of the image signal that is invariant to the watermark addition for classifying the image in order to avoid over/underflows. The method has been tested on different sets of medical images and some usual natural test images as Lena. Experimental result analysis conducted with respect to several aspects including data hiding capacity and image quality preservation, shows that our method is one of the most competitive existing lossless watermarking schemes in terms of high capacity and low distortion. PMID:21096246
I like your GRIN: Deign methods for gradient-index progressive addition lenses
NASA Astrophysics Data System (ADS)
Fischer, David J.; Moore, Duncan T.
2002-12-01
Progressive addition lenses (PALs) are vision correction lenses with a continuous change in power, used to treat the physical condition presbyopia. These lenses are currently fabricated using non-rotationally symmetric surfaces to achieve the focal power transition and aberration control. In this research, we consider the use of Gradient-Index (GRIN) designs for providing both power progression and aberration control. The use of B-Spline curves for GRIN representation is explained. Design methods and simulation results for GRIN PALs are presented. Possible uses for the design methods with other lenses, such as unifocal lenses and axicons, are also discussed.
Well cementing method using an am/amps fluid loss additive blend
Boncan, V.G.; Gandy, R.
1986-12-30
A method is described of cementing a wellbore, comprising the steps of: mixing together a hydraulic cement, water in an amount to produce a pumpable slurry, and a non-retarding fluid loss additive blend. The blend comprises a copolymer of acrylamide and 2-acrylamide-2-methylpropane sulfonate, the sodium salt of naphthalene formaldehyde sulfonate, and polyvinylpyrrolidone polymer; pumping the cement slurry to the desired location in the wellbore; and allowing the cement slurry to harden to a solid mass.
The method of manufacture of nylon dental partially removable prosthesis using additive technologies
NASA Astrophysics Data System (ADS)
Kashapov, R. N.; Korobkina, A. I.; Platonov, E. V.; Saleeva, G. T.
2014-12-01
The article is devoted to the topic of creating new methods of dental prosthesis. The aim of this work is to investigate the possibility of using additive technology to create nylon prosthesis. As a result of experimental studies, was made a sample of nylon partially removable prosthesis using 3D printing has allowed to simplify, accelerate and reduce the coat of manufacturing high-precision nylon dentures.
Hybrid Residual Flexibility/Mass-Additive Method for Structural Dynamic Testing
NASA Technical Reports Server (NTRS)
Tinker, M. L.
2003-01-01
A large fixture was designed and constructed for modal vibration testing of International Space Station elements. This fixed-base test fixture, which weighs thousands of pounds and is anchored to a massive concrete floor, initially utilized spherical bearings and pendulum mechanisms to simulate Shuttle orbiter boundary constraints for launch of the hardware. Many difficulties were encountered during a checkout test of the common module prototype structure, mainly due to undesirable friction and excessive clearances in the test-article-to-fixture interface bearings. Measured mode shapes and frequencies were not representative of orbiter-constrained modes due to the friction and clearance effects in the bearings. As a result, a major redesign effort for the interface mechanisms was undertaken. The total cost of the fixture design, construction and checkout, and redesign was over $2 million. Because of the problems experienced with fixed-base testing, alternative free-suspension methods were studied, including the residual flexibility and mass-additive approaches. Free-suspension structural dynamics test methods utilize soft elastic bungee cords and overhead frame suspension systems that are less complex and much less expensive than fixed-base systems. The cost of free-suspension fixturing is on the order of tens of thousands of dollars as opposed to millions, for large fixed-base fixturing. In addition, free-suspension test configurations are portable, allowing modal tests to be done at sites without modal test facilities. For example, a mass-additive modal test of the ASTRO-1 Shuttle payload was done at the Kennedy Space Center launch site. In this Technical Memorandum, the mass-additive and residual flexibility test methods are described in detail. A discussion of a hybrid approach that combines the best characteristics of each method follows and is the focus of the study.
NASA Astrophysics Data System (ADS)
Yan, Beizhan; Kennedy, Daniel; Miller, Rachel L.; Cowin, James P.; Jung, Kyung-hwa; Perzanowski, Matt; Balletta, Marco; Perera, Federica P.; Kinney, Patrick L.; Chillrud, Steven N.
2011-12-01
Exposure of black carbon (BC) is associated with a variety of adverse health outcomes. A number of optical methods for estimating BC on Teflon filters have been adopted but most assume all light absorption is due to BC while other sources of colored particulate matter exist. Recently, a four-wavelength-optical reflectance measurement for distinguishing second hand cigarette smoke (SHS) from soot-BC was developed (Brook et al., 2010; Lawless et al., 2004). However, the method has not been validated for soot-BC nor SHS and little work has been done to look at the methodological issues of the optical reflectance measurements for samples that could have SHS, BC, and other colored particles. We refined this method using a lab-modified integrating sphere with absorption measured continuously from 350 nm to 1000 nm. Furthermore, we characterized the absorption spectrum of additional components of particulate matter (PM) on PM 2.5 filters including ammonium sulfate, hematite, goethite, and magnetite. Finally, we validate this method for BC by comparison to other standard methods. Use of synthesized data indicates that it is important to optimize the choice of wavelengths to minimize computational errors as additional components (more than 2) are added to the apportionment model of colored components. We found that substantial errors are introduced when using 4 wavelengths suggested by Lawless et al. to quantify four substances, while an optimized choice of wavelengths can reduce model-derived error from over 10% to less than 2%. For environmental samples, the method was sensitive for estimating airborne levels of BC and SHS, but not mass loadings of iron oxides and sulfate. Duplicate samples collected in NYC show high reproducibility (points consistent with a 1:1 line, R2 = 0.95). BC data measured by this method were consistent with those measured by other optical methods, including Aethalometer and Smoke-stain Reflectometer (SSR); although the SSR looses sensitivity at
Yan, Beizhan; Kennedy, Daniel; Miller, Rachel L.; Cowin, James P.; Jung, Kyung-hwa; Perzanowski, Matt; Balletta, Marco; Perera, Federica P.; Kinney, Patrick L.; Chillrud, Steven N.
2011-01-01
Exposure of black carbon (BC) is associated with a variety of adverse health outcomes. A number of optical methods for estimating BC on Teflon filters have been adopted but most assume all light absorption is due to BC while other sources of colored particulate matter exist. Recently, a four-wavelength-optical reflectance measurement for distinguishing second hand cigarette smoke (SHS) from soot-BC was developed (Brook et al., 2010; Lawless et al., 2004). However, the method has not been validated for soot-BC nor SHS and little work has been done to look at the methodological issues of the optical reflectance measurements for samples that could have SHS, BC, and other colored particles. We refined this method using a lab-modified integrating sphere with absorption measured continuously from 350 nm to 1000 nm. Furthermore, we characterized the absorption spectrum of additional components of particulate matter (PM) on PM2.5 filters including ammonium sulfate, hematite, goethite, and magnetite. Finally, we validate this method for BC by comparison to other standard methods. Use of synthesized data indicates that it is important to optimize the choice of wavelengths to minimize computational errors as additional components (more than 2) are added to the apportionment model of colored components. We found that substantial errors are introduced when using 4 wavelengths suggested by Lawless et al. to quantify four substances, while an optimized choice of wavelengths can reduce model-derived error from over 10% to less than 2%. For environmental samples, the method was sensitive for estimating airborne levels of BC and SHS, but not mass loadings of iron oxides and sulfate. Duplicate samples collected in NYC show high reproducibility (points consistent with a 1:1 line, R2 = 0.95). BC data measured by this method were consistent with those measured by other optical methods, including Aethalometer and Smoke-stain Reflectometer (SSR); although the SSR looses sensitivity at
Standard addition method for free acid determination in solutions with hydrolyzable ions
Baumann, E.W.
1981-01-01
The free acid content of solutions containing hydrolyzable ions has been determined potentiometrically by a standard addition method. Two increments of acid are added to the sample in a 1M potassium thiocyanate solution. The sample concentration is calculated by solution of three simultaneous Nernst equations. The method has been demonstrated for solutions containing Al/sup 3 +/, Cr/sup 3 +/, Fe/sup 3 +/, Ni/sup 2 +/, Th/sup 4 +/, or UO/sub 2//sup 2 +/ with a metal-to-acid ratio of < 2.5. The method is suitable for determination of 10 ..mu..moles acid in 10 mL total volume. The accuracy is verifiable by reasonable agreement of the Nerst slopes found in the presence and absence of hydrolyzable ions. The relative standard deviation is < 2.5 percent.
External Standards or Standard Addition? Selecting and Validating a Method of Standardization
NASA Astrophysics Data System (ADS)
Harvey, David T.
2002-05-01
A common feature of many problem-based laboratories in analytical chemistry is a lengthy independent project involving the analysis of "real-world" samples. Students research the literature, adapting and developing a method suitable for their analyte, sample matrix, and problem scenario. Because these projects encompass the complete analytical process, students must consider issues such as obtaining a representative sample, selecting a method of analysis, developing a suitable standardization, validating results, and implementing appropriate quality assessment/quality control practices. Most textbooks and monographs suitable for an undergraduate course in analytical chemistry, however, provide only limited coverage of these important topics. The need for short laboratory experiments emphasizing important facets of method development, such as selecting a method of standardization, is evident. The experiment reported here, which is suitable for an introductory course in analytical chemistry, illustrates the importance of matrix effects when selecting a method of standardization. Students also learn how a spike recovery is used to validate an analytical method, and obtain a practical experience in the difference between performing an external standardization and a standard addition.
The Wavelet Element Method. Part 2; Realization and Additional Features in 2D and 3D
NASA Technical Reports Server (NTRS)
Canuto, Claudio; Tabacco, Anita; Urban, Karsten
1998-01-01
The Wavelet Element Method (WEM) provides a construction of multiresolution systems and biorthogonal wavelets on fairly general domains. These are split into subdomains that are mapped to a single reference hypercube. Tensor products of scaling functions and wavelets defined on the unit interval are used on the reference domain. By introducing appropriate matching conditions across the interelement boundaries, a globally continuous biorthogonal wavelet basis on the general domain is obtained. This construction does not uniquely define the basis functions but rather leaves some freedom for fulfilling additional features. In this paper we detail the general construction principle of the WEM to the 1D, 2D and 3D cases. We address additional features such as symmetry, vanishing moments and minimal support of the wavelet functions in each particular dimension. The construction is illustrated by using biorthogonal spline wavelets on the interval.
Dyadyusha, G.G.; Ushomirskii, M.M.
1986-09-01
A method previously proposed for determining the energy structure of a polymethyne dye with any terminal groups is used in considering formulas for the molecularorbital coefficients and the differences in the distribution on the atoms in the polymethyne chain for localized and delocalized energy levels, as well as the accuracy in calculating the molecular-orbital coefficients by means of a finite number of effective additive parameters. It is found that the localized states are important to the electron-density distribution on the chain atoms characteristic of the polymethyne dyes.
A simple method for the addition of rotenone in Arabidopsis thaliana leaves
Maliandi, María V; Rius, Sebastián P; Busi, María V; Gomez-Casati, Diego F
2015-01-01
A simple and reproducible method for the treatment of Arabidopsis thaliana leaves with rotenone is presented. Rosette leaves were incubated with rotenone and Triton X-100 for at least 15 h. Treated leaves showed increased expression of COX19 and BCS1a, 2 genes known to be induced in Arabidopsis cell cultures after rotenone treatment. Moreover, rotenone/Triton X-100 incubated leaves presented an inhibition of oxygen uptake. The simplicity of the procedure shows this methodology is useful for studying the effect of the addition of rotenone to a photosynthetic tissue in situ. PMID:26357865
A simple method for the addition of rotenone in Arabidopsis thaliana leaves.
Maliandi, María V; Rius, Sebastián P; Busi, María V; Gomez-Casati, Diego F
2015-01-01
A simple and reproducible method for the treatment of Arabidopsis thaliana leaves with rotenone is presented. Rosette leaves were incubated with rotenone and Triton X-100 for at least 15 h. Treated leaves showed increased expression of COX19 and BCS1a, 2 genes known to be induced in Arabidopsis cell cultures after rotenone treatment. Moreover, rotenone/Triton X-100 incubated leaves presented an inhibition of oxygen uptake. The simplicity of the procedure shows this methodology is useful for studying the effect of the addition of rotenone to a photosynthetic tissue in situ. PMID:26357865
VizieR Online Data Catalog: Photometry of nova LMC 2012 (Schwarz+, 2015)
NASA Astrophysics Data System (ADS)
Schwarz, G. J.; Shore, S. N.; Page, K. L.; Osborne, J. P.; Beardmore, A. P.; Walter, F. M.; Bode, M. F.; Drake, J. J.; Ness, J.-U.; Starrfield, S.; van Rossum, D. R.; Woodward, C. E.
2015-03-01
Nova LMC 2012 was discovered on March 26.397 UT (MJD56012.897) at a visual magnitude of 10.7 (Seach et al., 2012CBET.3071....1S). After discovery, LMC 2012 was observed by a number of different facilities at a variety of wavelengths. The discovery date is taken as day zero and the shorthand "Dn," where "n" is the number of days after day zero, is used here. Swift is a revolutionary facility for studying novae (see Schwarz et al. 2011, cat. J/ApJS/197/31, for details). Its three instruments cover the γ-ray (BAT), X-ray (XRT), plus UV and optical (UVOT) bandpasses. Swift obtained 74 uvm2 band (λeff=2246Å, FWHM=498Å) observations of LMC 2012 with the UVOT instrument from D1.2 until D671. There were also 12 uvw2 band (λeff=1928Å, FWHM=657Å) and nine uvw1 band (λeff=2600Å, FWHM=693Å) observations which were only obtained early on D1.2 and later during the observations after D300. The UVOT photometry is provided in Table2. LMC 2012 was extensively observed photometrically between D0.6 and D635 with the Small & Moderate Aperture Research Telescope System (SMARTS) at Cerro Tololo (see Walter et al., 2012PASP..124.1057W, for details). We obtained 250 photometric observations in BVRI/JHK from SMARTS. The optical photometry is supplemented with 54 early time CCD BVRI observations from the American Association of Variable Star Observers (AAVSO). The optical and near-infrared photometry is also given in Table2. (2 data files).
NASA Astrophysics Data System (ADS)
Givianrad, M. H.; Saber-Tehrani, M.; Aberoomand-Azar, P.; Mohagheghian, M.
2011-03-01
The applicability of H-point standard additions method (HPSAM) to the resolving of overlapping spectra corresponding to the sulfamethoxazole and trimethoprim is verified by UV-vis spectrophotometry. The results show that the H-point standard additions method with simultaneous addition of both analytes is suitable for the simultaneous determination of sulfamethoxazole and trimethoprim in aqueous media. The results of applying the H-point standard additions method showed that the two drugs could be determined simultaneously with the concentration ratios of sulfamethoxazole to trimethoprim varying from 1:18 to 16:1 in the mixed samples. Also, the limits of detections were 0.58 and 0.37 μmol L -1 for sulfamethoxazole and trimethoprim, respectively. In addition the means of the calculated RSD (%) were 1.63 and 2.01 for SMX and TMP, respectively in synthetic mixtures. The proposed method has been successfully applied to the simultaneous determination of sulfamethoxazole and trimethoprim in some synthetic, pharmaceutical formulation and biological fluid samples.
Evaporation model for beam based additive manufacturing using free surface lattice Boltzmann methods
NASA Astrophysics Data System (ADS)
Klassen, Alexander; Scharowsky, Thorsten; Körner, Carolin
2014-07-01
Evaporation plays an important role in many technical applications including beam-based additive manufacturing processes, such as selective electron beam or selective laser melting (SEBM/SLM). In this paper, we describe an evaporation model which we employ within the framework of a two-dimensional free surface lattice Boltzmann method. With this method, we solve the hydrodynamics as well as thermodynamics of the molten material taking into account the mass and energy losses due to evaporation and the recoil pressure acting on the melt pool. Validation of the numerical model is performed by measuring maximum melt depths and evaporative losses in samples of pure titanium and Ti-6Al-4V molten by an electron beam. Finally, the model is applied to create processing maps for an SEBM process. The results predict that the penetration depth of the electron beam, which is a function of the acceleration voltage, has a significant influence on evaporation effects.
Determination of free acid by standard addition method in potassium thiocyanate
Baumann, E W
1982-06-01
The free acid content of solutions containing hydrolyzable ions has been determined potentiometrically by a standard addition method. Two increments of acid are added to the sample in 1M potassium thiocyanate solution. The sample concentration is calculated by solution of three simultaneous Nernst equations. The method has been demonstrated for solutions containing Al/sup 3 +/, Cr/sup 3 +/, Fe/sup 3 +/, Hg/sup 2 +/, Ni/sup 2 +/, Th/sup 4 +/, or UO/sub 2//sup 2 +/ with a metal-to-acid ratio of < 2.5. The method is suitable for determination of 10 ..mu..moles acid in 10 mL total volume. The accuracy can be judged from the agreement of the Nernst slopes found in the presence and absence of hydrolyzable ions. The relative standard deviation is < 2.5%. The report includes a survey of experiments with thermometric, pH, and Gran plot titrations in a variety of complexants, from which the method was evolved. Also included is a literature survey of sixty references, a discussion of the basic measurements, and a complete analytical procedure.
NASA Astrophysics Data System (ADS)
Liu, Shutian; Li, Quhao; Chen, Wenjiong; Tong, Liyong; Cheng, Gengdong
2015-06-01
Additive manufacturing (AM) technologies, such as selective laser sintering (SLS) and fused deposition modeling (FDM), have become the powerful tools for direct manufacturing of complex parts. This breakthrough in manufacturing technology makes the fabrication of new geometrical features and multiple materials possible. Past researches on designs and design methods often focused on how to obtain desired functional performance of the structures or parts, specific manufacturing capabilities as well as manufacturing constraints of AM were neglected. However, the inherent constraints in AM processes should be taken into account in design process. In this paper, the enclosed voids, one type of manufacturing constraints of AM, are investigated. In mathematics, enclosed voids restriction expressed as the solid structure is simplyconnected. We propose an equivalent description of simply-connected constraint for avoiding enclosed voids in structures, named as virtual temperature method (VTM). In this method, suppose that the voids in structure are filled with a virtual heating material with high heat conductivity and solid areas are filled with another virtual material with low heat conductivity. Once the enclosed voids exist in structure, the maximum temperature value of structure will be very high. Based upon this method, the simplyconnected constraint is equivalent to maximum temperature constraint. And this method can be easily used to formulate the simply-connected constraint in topology optimization. The effectiveness of this description method is illustrated by several examples. Based upon topology optimization, an example of 3D cantilever beam is used to illustrate the trade-off between manufacturability and functionality. Moreover, the three optimized structures are fabricated by FDM technology to indicate further the necessity of considering the simply-connected constraint in design phase for AM.
Determination of free acid by standard addition method in potassium thiocyanate
Not Available
1981-06-01
An analytical method for determination of free acidity in all SRP process solutions has been developed. Free acidity was successfully determined in solutions of nitric acid and the nitrates of aluminum, chromium(III), iron(III), mercury(II), nickel(II), thorium, and uranium(VI), at metal-to-acid ratios <2.5. Sample requirements, instrumentation, and mode of operation are similar to those currently used in the Laboratories Department free acid procedures. The simple procedure would be suitable for automation and microprocessor control. The method consists of two additions of known increments of acid into a solution containing the sample aliquot (10 ..mu..moles free acid) and 10 mL 1M potassium thiocyanate. The potential is determined in the initial solution and after each addition with a glass electrode and pH meter. The sample concentration is calculated by solution of three simultaneous Nernst equations. Two programs for this iterative computation are available: one written for the PDP-15 computer and another for a Hewlett-Packard 67 (or 97) programmable calculator. The accuracy of the result is verified by a slope that approximates the theoretical Nernst value. The relative standard deviation is <2.5%. This memorandum includes a survey of experiments with thermometric, pH, and Gran plot titrations in a variety of complexants, from which this particular system and technique logically evolved. The appendix includes a literature survey of sixty references, a discussion of the basic measurements, and a complete analytical procedure. The final step for completion of this RTA is training and consultation at the convenience of the Laboratories Department for demonstration of the method with process samples.
Method for simultaneous use of a single additive for coal flotation, dewatering, and reconstitution
Wen, Wu-Wey; Gray, McMahan L.; Champagne, Kenneth J.
1995-01-01
A single dose of additive contributes to three consecutive fine coal unit operations, i.e., flotation, dewatering and reconstitution, whereby the fine coal is first combined with water in a predetermined proportion so as to formulate a slurry. The slurry is then mixed with a heavy hydrocarbon-based emulsion in a second predetermined proportion and at a first predetermined mixing speed and for a predetermined period of time. The conditioned slurry is then cleaned by a froth flotation method to form a clean coal froth and then the froth is dewatered by vacuum filtration or a centrifugation process to form reconstituted products that are dried to dust-less clumps prior to combustion.
Method for simultaneous use of a single additive for coal flotation, dewatering and reconstitution
Wen, Wu-Wey; Gray, M.L.; Champagne, K.J.
1993-11-09
A single dose of additive contributes to three consecutive fine coal unit operations, i.e., flotation, dewatering and reconstitution, whereby the fine coal is first combined with water in a predetermined proportion so as to formulate a slurry. The slurry is then mixed with a heavy hydrocarbon-based emulsion in a second predetermined proportion and at a first predetermined mixing speed and for a predetermined period of time. The conditioned slurry is then cleaned by a froth flotation method to form a clean coal froth and then the froth is dewatered by vacuum filtration or a centrifugation process to form reconstituted products that are dried to dust-less clumps prior to combustion.
Anderson, Catherine; Malambo, Dennis Hanjalika; Perez, Maria Eliette Gonzalez; Nobela, Happiness Ngwanamoseka; de Pooter, Lobke; Spit, Jan; Hooijmans, Christine Maria; de Vossenberg, Jack van; Greya, Wilson; Thole, Bernard; van Lier, Jules B; Brdjanovic, Damir
2015-11-01
In this research, three faecal sludge sanitizing methods-lactic acid fermentation, urea treatment and lime treatment-were studied for application in emergency situations. These methods were investigated by undertaking small scale field trials with pit latrine sludge in Blantyre, Malawi. Hydrated lime was able to reduce the E. coli count in the sludge to below the detectable limit within 1 h applying a pH > 11 (using a dosage from 7% to 17% w/w, depending faecal sludge alkalinity), urea treatment required about 4 days using 2.5% wet weight urea addition, and lactic acid fermentation needed approximately 1 week after being dosed with 10% wet weight molasses (2 g (glucose/fructose)/kg) and 10% wet weight pre-culture (99.8% pasteurised whole milk and 0.02% fermented milk drink containing Lactobacillus casei Shirota). Based on Malawian prices, the cost of sanitizing 1 m³ of faecal sludge was estimated to be €32 for lactic acid fermentation, €20 for urea treatment and €12 for hydrated lime treatment. PMID:26528995
Herbold, E. B.; Walton, O.; Homel, M. A.
2015-10-26
This document serves as a final report to a small effort where several improvements were added to a LLNL code GEODYN-L to develop Discrete Element Method (DEM) algorithms coupled to Lagrangian Finite Element (FE) solvers to investigate powder-bed formation problems for additive manufacturing. The results from these simulations will be assessed for inclusion as the initial conditions for Direct Metal Laser Sintering (DMLS) simulations performed with ALE3D. The algorithms were written and performed on parallel computing platforms at LLNL. The total funding level was 3-4 weeks of an FTE split amongst two staff scientists and one post-doc. The DEM simulations emulated, as much as was feasible, the physical process of depositing a new layer of powder over a bed of existing powder. The DEM simulations utilized truncated size distributions spanning realistic size ranges with a size distribution profile consistent with realistic sample set. A minimum simulation sample size on the order of 40-particles square by 10-particles deep was utilized in these scoping studies in order to evaluate the potential effects of size segregation variation with distance displaced in front of a screed blade. A reasonable method for evaluating the problem was developed and validated. Several simulations were performed to show the viability of the approach. Future investigations will focus on running various simulations investigating powder particle sizing and screen geometries.
Li, Yi; Kim, Jong-Joo
2015-01-01
The efficiency of genome-wide association analysis (GWAS) depends on power of detection for quantitative trait loci (QTL) and precision for QTL mapping. In this study, three different strategies for GWAS were applied to detect QTL for carcass quality traits in the Korean cattle, Hanwoo; a linkage disequilibrium single locus regression method (LDRM), a combined linkage and linkage disequilibrium analysis (LDLA) and a BayesCπ approach. The phenotypes of 486 steers were collected for weaning weight (WWT), yearling weight (YWT), carcass weight (CWT), backfat thickness (BFT), longissimus dorsi muscle area, and marbling score (Marb). Also the genotype data for the steers and their sires were scored with the Illumina bovine 50K single nucleotide polymorphism (SNP) chips. For the two former GWAS methods, threshold values were set at false discovery rate <0.01 on a chromosome-wide level, while a cut-off threshold value was set in the latter model, such that the top five windows, each of which comprised 10 adjacent SNPs, were chosen with significant variation for the phenotype. Four major additive QTL from these three methods had high concordance found in 64.1 to 64.9Mb for Bos taurus autosome (BTA) 7 for WWT, 24.3 to 25.4Mb for BTA14 for CWT, 0.5 to 1.5Mb for BTA6 for BFT and 26.3 to 33.4Mb for BTA29 for BFT. Several candidate genes (i.e. glutamate receptor, ionotropic, ampa 1 [GRIA1], family with sequence similarity 110, member B [FAM110B], and thymocyte selection-associated high mobility group box [TOX]) may be identified close to these QTL. Our result suggests that the use of different linkage disequilibrium mapping approaches can provide more reliable chromosome regions to further pinpoint DNA makers or causative genes in these regions. PMID:26104396
Li, Yi; Kim, Jong-Joo
2015-07-01
The efficiency of genome-wide association analysis (GWAS) depends on power of detection for quantitative trait loci (QTL) and precision for QTL mapping. In this study, three different strategies for GWAS were applied to detect QTL for carcass quality traits in the Korean cattle, Hanwoo; a linkage disequilibrium single locus regression method (LDRM), a combined linkage and linkage disequilibrium analysis (LDLA) and a BayesCπ approach. The phenotypes of 486 steers were collected for weaning weight (WWT), yearling weight (YWT), carcass weight (CWT), backfat thickness (BFT), longissimus dorsi muscle area, and marbling score (Marb). Also the genotype data for the steers and their sires were scored with the Illumina bovine 50K single nucleotide polymorphism (SNP) chips. For the two former GWAS methods, threshold values were set at false discovery rate <0.01 on a chromosome-wide level, while a cut-off threshold value was set in the latter model, such that the top five windows, each of which comprised 10 adjacent SNPs, were chosen with significant variation for the phenotype. Four major additive QTL from these three methods had high concordance found in 64.1 to 64.9Mb for Bos taurus autosome (BTA) 7 for WWT, 24.3 to 25.4Mb for BTA14 for CWT, 0.5 to 1.5Mb for BTA6 for BFT and 26.3 to 33.4Mb for BTA29 for BFT. Several candidate genes (i.e. glutamate receptor, ionotropic, ampa 1 [GRIA1], family with sequence similarity 110, member B [FAM110B], and thymocyte selection-associated high mobility group box [TOX]) may be identified close to these QTL. Our result suggests that the use of different linkage disequilibrium mapping approaches can provide more reliable chromosome regions to further pinpoint DNA makers or causative genes in these regions. PMID:26104396
River catchment rainfall series analysis using additive Holt-Winters method
NASA Astrophysics Data System (ADS)
Puah, Yan Jun; Huang, Yuk Feng; Chua, Kuan Chin; Lee, Teang Shui
2016-03-01
Climate change is receiving more attention from researchers as the frequency of occurrence of severe natural disasters is getting higher. Tropical countries like Malaysia have no distinct four seasons; rainfall has become the popular parameter to assess climate change. Conventional ways that determine rainfall trends can only provide a general result in single direction for the whole study period. In this study, rainfall series were modelled using additive Holt-Winters method to examine the rainfall pattern in Langat River Basin, Malaysia. Nine homogeneous series of more than 25 years data and less than 10% missing data were selected. Goodness of fit of the forecasted models was measured. It was found that seasonal rainfall model forecasts are generally better than the monthly rainfall model forecasts. Three stations in the western region exhibited increasing trend. Rainfall in southern region showed fluctuation. Increasing trends were discovered at stations in the south-eastern region except the seasonal analysis at station 45253. Decreasing trend was found at station 2818110 in the east, while increasing trend was shown at station 44320 that represents the north-eastern region. The accuracies of both rainfall model forecasts were tested using the recorded data of years 2010-2012. Most of the forecasts are acceptable.
Anderson, Catherine; Malambo, Dennis Hanjalika; Gonzalez Perez, Maria Eliette; Nobela, Happiness Ngwanamoseka; de Pooter, Lobke; Spit, Jan; Hooijmans, Christine Maria; van de Vossenberg, Jack; Greya, Wilson; Thole, Bernard; van Lier, Jules B.; Brdjanovic, Damir
2015-01-01
In this research, three faecal sludge sanitizing methods—lactic acid fermentation, urea treatment and lime treatment—were studied for application in emergency situations. These methods were investigated by undertaking small scale field trials with pit latrine sludge in Blantyre, Malawi. Hydrated lime was able to reduce the E. coli count in the sludge to below the detectable limit within 1 h applying a pH > 11 (using a dosage from 7% to 17% w/w, depending faecal sludge alkalinity), urea treatment required about 4 days using 2.5% wet weight urea addition, and lactic acid fermentation needed approximately 1 week after being dosed with 10% wet weight molasses (2 g (glucose/fructose)/kg) and 10% wet weight pre-culture (99.8% pasteurised whole milk and 0.02% fermented milk drink containing Lactobacillus casei Shirota). Based on Malawian prices, the cost of sanitizing 1 m3 of faecal sludge was estimated to be €32 for lactic acid fermentation, €20 for urea treatment and €12 for hydrated lime treatment. PMID:26528995
Non-linearity measurements of solar cells with an LED-based combinatorial flux addition method
NASA Astrophysics Data System (ADS)
Hamadani, Behrang H.; Shore, Andrew; Roller, John; Yoon, Howard W.; Campanelli, Mark
2016-02-01
We present a light emitting diode (LED)-based system utilizing a combinatorial flux addition method to investigate the non-linear relationship in solar cells between the output current of the cell and the incident irradiance level. The magnitude of the light flux is controlled by the supplied currents to two LEDs (or two sets of them) in a combinatorial fashion. The signals measured from the cell are arranged within a related overdetermined linear system of equations derived from an appropriately chosen Nth degree polynomial representing the relationship between the measured signals and the incident fluxes. The flux values and the polynomial coefficients are then solved for by linear least squares to obtain the best fit. The technique can be applied to any solar cell, under either monochromatic or broadband spectrum. For the unscaled solution, no reference detectors or prior calibrations of the light flux are required. However, if at least one calibrated irradiance value is known, then the entire curve can be scaled to an appropriate spectral responsivity value. Using this technique, a large number of data points can be obtained in a relatively short time scale over a large signal range.
A study of domain decomposition methods applied to the discretized Helmholtz equation
NASA Astrophysics Data System (ADS)
Tramel, Robert Wallace
2001-09-01
In this work a domain decomposition based preconditioner of the additive Schwarz type is developed and tested on the linear systems which arise out of the application of the Green's Function/Wave Expansion Discretization. (GFD/WED) method to Helmholtz's equation. In order to develop the additive Schwarz preconditioner, use is made of a class of one-sided Artificial Radiation Boundary Conditions (ARBC) developed during the course of this work. These ARBCs are computationally shown to be quite accurate for use on their own. The ARBC's are used to radiatively couple the various sub-domains which are naturally part of domain decomposition based methods in such a manner as to ensure that the system matrix, when restricted to the sub-domains, is non-singular. In addition, the inter-domain ARBC is constructed such that the solution to the global linear system is unaffected by the presence of the artificial boundaries. The efficacy and efficiency of the method is demonstrated on one, two, and three-dimensional test cases.
A habitat suitability model for Chinese sturgeon determined using the generalized additive method
NASA Astrophysics Data System (ADS)
Yi, Yujun; Sun, Jie; Zhang, Shanghong
2016-03-01
The Chinese sturgeon is a type of large anadromous fish that migrates between the ocean and rivers. Because of the construction of dams, this sturgeon's migration path has been cut off, and this species currently is on the verge of extinction. Simulating suitable environmental conditions for spawning followed by repairing or rebuilding its spawning grounds are effective ways to protect this species. Various habitat suitability models based on expert knowledge have been used to evaluate the suitability of spawning habitat. In this study, a two-dimensional hydraulic simulation is used to inform a habitat suitability model based on the generalized additive method (GAM). The GAM is based on real data. The values of water depth and velocity are calculated first via the hydrodynamic model and later applied in the GAM. The final habitat suitability model is validated using the catch per unit effort (CPUEd) data of 1999 and 2003. The model results show that a velocity of 1.06-1.56 m/s and a depth of 13.33-20.33 m are highly suitable ranges for the Chinese sturgeon to spawn. The hydraulic habitat suitability indexes (HHSI) for seven discharges (4000; 9000; 12,000; 16,000; 20,000; 30,000; and 40,000 m3/s) are calculated to evaluate integrated habitat suitability. The results show that the integrated habitat suitability reaches its highest value at a discharge of 16,000 m3/s. This study is the first to apply a GAM to evaluate the suitability of spawning grounds for the Chinese sturgeon. The study provides a reference for the identification of potential spawning grounds in the entire basin.
Possibilities of CT Scanning as Analysis Method in Laser Additive Manufacturing
NASA Astrophysics Data System (ADS)
Karme, Aleksis; Kallonen, Aki; Matilainen, Ville-Pekka; Piili, Heidi; Salminen, Antti
Laser additive manufacturing is an established and constantly developing technique. Structural assessment should be a key component to ensure directed evolution towards higher level of manufacturing. The macroscopic properties of metallic structures are determined by their internal microscopic features, which are difficult to assess using conventional surface measuring methodologies. X-ray microtomography (CT) is a promising technique for three-dimensional non-destructive probing of internal composition and build of various materials. Aim of this study is to define the possibilities of using CT scanning as quality control method in LAM fabricated parts. Since the parts fabricated with LAM are very often used in high quality and accuracy demanding applications in various industries such as medical and aerospace, it is important to be able to define the accuracy of the build parts. The tubular stainless steel test specimens were 3D modelled, manufactured with a modified research AM equipment and imaged after manufacturing with a high-power, high-resolution CT scanner. 3D properties, such as surface texture and the amount and distribution of internal pores, were also evaluated in this study. Surface roughness was higher on the interior wall of the tube, and deviation from the model was systematically directed towards the central axis. Pore distribution showed clear organization and divided into two populations; one following the polygon model seams along both rims, and the other being associated with the concentric and equidistant movement path of the laser. Assessment of samples can enhance the fabrication by guiding the improvement of both modelling and manufacturing process.
Analysis methods for the determination of anthropogenic additions of P to agricultural soils
Technology Transfer Automated Retrieval System (TEKTRAN)
Phosphorus additions and measurement in soil is of concern on lands where biosolids have been applied. Colorimetric analysis for plant-available P may be inadequate for the accurate assessment of soil P. Phosphate additions in a regulatory environment need to be accurately assessed as the reported...
Asadpour-Zeynali, Karim; Saeb, Elhameh; Vallipour, Javad; Bamorowat, Mehdi
2014-01-01
Simultaneous spectrophotometric determination of three neonicotinoid insecticides (acetamiprid, imidacloprid, and thiamethoxam) by a novel method named generalized net analyte signal standard addition method (GNASSAM) in some binary and ternary synthetic mixtures was investigated. For this purpose, standard addition was performed using a single standard solution consisting of a mixture of standards of all analytes. Savings in time and amount of used materials are some of the advantages of this method. All determinations showed appropriate applicability of this method with less than 5% error. This method may be applied for linearly dependent data in the presence of known interferents. The GNASSAM combines the advantages of both the generalized standard addition method and net analyte signal; therefore, it may be a proper alternative for some other multivariate methods. PMID:24672886
Spectral Envelopes and Additive + Residual Analysis/Synthesis
NASA Astrophysics Data System (ADS)
Rodet, Xavier; Schwarz, Diemo
The subject of this chapter is the estimation, representation, modification, and use of spectral envelopes in the context of sinusoidal-additive-plus-residual analysis/synthesis. A spectral envelope is an amplitude-vs-frequency function, which may be obtained from the envelope of a short-time spectrum (Rodet et al., 1987; Schwarz, 1998). [Precise definitions of such an envelope and short-time spectrum (STS) are given in Section 2.] The additive-plus-residual analysis/synthesis method is based on a representation of signals in terms of a sum of time-varying sinusoids and of a non-sinusoidal residual signal [e.g., see Serra (1989), Laroche et al. (1993), McAulay and Quatieri (1995), and Ding and Qian (1997)]. Many musical sound signals may be described as a combination of a nearly periodic waveform and colored noise. The nearly periodic part of the signal can be viewed as a sum of sinusoidal components, called partials, with time-varying frequency and amplitude. Such sinusoidal components are easily observed on a spectral analysis display (Fig. 5.1) as obtained, for instance, from a discrete Fourier transform.
Bifurcated method and apparatus for floating point addition with decreased latency time
Farmwald, Paul M.
1987-01-01
Apparatus for decreasing the latency time associated with floating point addition and subtraction in a computer, using a novel bifurcated, pre-normalization/post-normalization approach that distinguishes between differences of floating point exponents.
ERIC Educational Resources Information Center
Cohen, Ayala; Nahum-Shani, Inbal; Doveh, Etti
2010-01-01
In their seminal paper, Edwards and Parry (1993) presented the polynomial regression as a better alternative to applying difference score in the study of congruence. Although this method is increasingly applied in congruence research, its complexity relative to other methods for assessing congruence (e.g., difference score methods) was one of the…
Thermal D-Brane Boundary States from Type Iib Green-Schwarz Superstring in pp-WAVE Background
NASA Astrophysics Data System (ADS)
Vancea, Ion V.
We construct the thermal boundary states from the type IIB Green-Schwarz superstring in pp-wave background in the light-cone gauge. The superstring is treated in the canonical ensemble and in the TFD formalism which is appropriate to discuss canonically quantized systems. The thermal boundary states are obtained by thermalizing the total boundary states which are the boundary states of the total system that is composed by the superstring modes and the corresponding thermal reservoir modes. That analysis is similar to the one in the flat space-time case.67 However, there are some subtleties concerning the construction of the total string which are discussed. Next, we compute the entropy of thermal boundary state which is defined as the expectation value of the superstring entropy operator in the thermal boundary state.
On the use of Schwarz-Christoffel conformal mappings to the grid generation for global ocean models
NASA Astrophysics Data System (ADS)
Xu, S.; Wang, B.; Liu, J.
2015-02-01
In this article we propose two conformal mapping based grid generation algorithms for global ocean general circulation models (OGCMs). Contrary to conventional, analytical forms based dipolar or tripolar grids, the new algorithms are based on Schwarz-Christoffel (SC) conformal mapping with prescribed boundary information. While dealing with the basic grid design problem of pole relocation, these new algorithms also address more advanced issues such as smoothed scaling factor, or the new requirements on OGCM grids arisen from the recent trend of high-resolution and multi-scale modeling. The proposed grid generation algorithm could potentially achieve the alignment of grid lines to coastlines, enhanced spatial resolution in coastal regions, and easier computational load balance. Since the generated grids are still orthogonal curvilinear, they can be readily utilized in existing Bryan-Cox-Semtner type ocean models. The proposed methodology can also be applied to the grid generation task for regional ocean modeling where complex land-ocean distribution is present.
An Inventory of Methods for the Assessment of Additive Increased Addictiveness of Tobacco Products
van de Nobelen, Suzanne; Kienhuis, Anne S.
2016-01-01
Background: Cigarettes and other forms of tobacco contain the addictive drug nicotine. Other components, either naturally occurring in tobacco or additives that are intentionally added during the manufacturing process, may add to the addictiveness of tobacco products. As such, these components can make cigarette smokers more easily and heavily dependent. Efforts to regulate tobacco product dependence are emerging globally. Additives that increase tobacco dependence will be prohibited under the new European Tobacco Product Directive. Objective: This article provides guidelines and recommendations for developing a regulatory strategy for assessment of increase in tobacco dependence due to additives. Relevant scientific literature is summarized and criteria and experimental studies that can define increased dependence of tobacco products are described. Conclusions: Natural tobacco smoke is a very complex matrix of components, therefore analysis of the contribution of an additive or a combination of additives to the level of dependence on this product is challenging. We propose to combine different type of studies analyzing overall tobacco product dependence potential and the functioning of additives in relation to nicotine. By using a combination of techniques, changes associated with nicotine dependence such as behavioral, physiological, and neurochemical alterations can be examined to provide sufficient information. Research needs and knowledge gaps will be discussed and recommendations will be made to translate current knowledge into legislation. As such, this article aids in implementation of the Tobacco Product Directive, as well as help enable regulators and researchers worldwide to develop standards to reduce dependence on tobacco products. Implications: This article provides an overall view on how to assess tobacco product constituents for their potential contribution to use and dependence. It provides guidelines that help enable regulators worldwide to
Methods and energy storage devices utilizing electrolytes having surface-smoothing additives
Xu, Wu; Zhang, Jiguang; Graff, Gordon L; Chen, Xilin; Ding, Fei
2015-11-12
Electrodeposition and energy storage devices utilizing an electrolyte having a surface-smoothing additive can result in self-healing, instead of self-amplification, of initial protuberant tips that give rise to roughness and/or dendrite formation on the substrate and anode surface. For electrodeposition of a first metal (M1) on a substrate or anode from one or more cations of M1 in an electrolyte solution, the electrolyte solution is characterized by a surface-smoothing additive containing cations of a second metal (M2), wherein cations of M2 have an effective electrochemical reduction potential in the solution lower than that of the cations of M1.
Methods and additives for delaying the release of chemicals in aqueous fluids
Burnham, J.W.; Briscoe, J.E.; Elphingstone, E.A.
1980-05-13
Additives are provided for bringing about the delayed release of a chemical such as a gel breaker or demulsifier in an aqueous fluid such as a gelled oil well hydraulic fracturing or fracture-acidizing fluid. The additives are pelletized solids consisting of the chemical to be released such as sodium laryl sulfate. A gelling agent capable of being hydrated such as a polysaccharide, and a breaker for the gel produced by the gelling agent when hydrated such as a persulfate or an enzyme. 33 claims.
NASA Technical Reports Server (NTRS)
Scialdone, John J.; Miller, Michael K.; Montoya, Alex F.
1996-01-01
The life of a space system may be critically dependent on the lubrication of some of its moving parts. The vapor pressure, the quantity of the available lubricant, the temperature and the exhaust venting conductance passage are important considerations in the selection and application of a lubricant. In addition, the oil additives employed to provide certain properties of low friction, surface tension, antioxidant and load bearing characteristics, are also very important and need to be known with regard to their amounts and vapor pressures. This paper reports on the measurements and analyses carried out to obtain those parameters for two often employed lubricants, the Apiezon(TM)-C and the Krytox(TM) AB. The measurements were made employing an electronic microbalance and a thermogravimetric analyzer (TGA) modified to operate in a vacuum. The results have been compared to other data on these oils when available. The identification of the mass fractions of the additives in the oil and their vapor pressures as a function of the temperature were carried out. These may be used to estimate the lubricant life given its quantity and the system vent exhaust conductance. It was found that the Apiezon(TM)-C has three main components with different rates of evaporation while the Krytox(TM) did not indicate any measurable additive.
Wilczek, Rajmund; Swiątkowski, Maciej; Czepiel, Aleksandra; Sterliński, Maciej; Makowska, Ewa; Kułakowski, Piotr
2011-01-01
We report a case of successful implantation of an additional defibrillation lead into the coronary sinus due to high defibrillation threshold (DFT) in a seriously ill patient with a history of extensive myocardial infarction referred for implantable cardioverter- defibrillator implantation after an episode of unstable ventricular tachycardia. All previous attempts to reduce DFT, including subcutaneous electrode implantation, had been unsuccessful. PMID:22219117
NASA Technical Reports Server (NTRS)
Tuchinsky, L. I.
1986-01-01
The effect of alloying additives to the matrix of a composite on the high temperature solubility rate of a single component fiber was analyzed thermodynamically. With an example of binary Ni alloys, with Group IV-VI transition metals reinforced with W fibers, agreement between the calculated and experimental data was demonstrated.
Activity Approach to the Formation of the Method of Addition and Subtraction in Elementary Students
ERIC Educational Resources Information Center
Maksimov, L. K.; Maksimova, L. V.
2013-01-01
One of the main tasks in teaching mathematics to elementary students is to form calculating methods and techniques. The efforts of teachers and methodologists are aimed at solving this problem. Educational and psychological research is devoted to it. At the same time school teaching experience demonstrates some difficulties in learning methods of…
Technology Transfer Automated Retrieval System (TEKTRAN)
Geophysical methods can provide important information in agricultural settings, and the use of these techniques are becoming more and more widespread. Magnetrometry, self-potential, and seismic are three geophysical methods, all of which have the potential for substantial future use in agriculture, ...
External Standards or Standard Additions? Selecting and Validating a Method of Standardization.
ERIC Educational Resources Information Center
Harvey, David
2002-01-01
Reports an experiment which is suitable for an introductory course in analytical chemistry and which illustrates the importance of matrix effects when selecting a method of standardization. Asserts that students learn how a spike recovery is used to validate an analytical method, and obtain practical experience in the difference between performing…
METHODS FOR IMPROVEMENT OF TRICKLING FILTER PLANT PERFORMANCE. PART II. CHEMICAL ADDITION
An experimental program to explore potential methods for removing phosphorus and generally enhancing trickling filter plant performance was conducted at the Mason Farm Wastewater Treatment Plant, Chapel Hill, North Carolina. Preliminary investigations included jar testing with se...
An analysis method for multistage transonic turbines with coolant mass flow addition
Mildner, F.; Gallus, H.E.
1998-10-01
The subject of this paper is a numerical method for the calculation of the transonic flow field of multistage turbines, taking high coolant flow into account. To reduce the processing time, a throughflow method based on the principles of Wu is used for the hub-to-tip calculation. The flow field is obtained by an iterative solution between a three-dimensional inviscid hyperbolic time-dependent algorithm with an implicit finite volume method for the blade-to-blade calculations using C-meshes and a single representative meridional S{sub 2m}-stream surface. Along the 2{sub 2m}-plane with respect to nonorthogonal curvilinear coordinates, the stream function equation governing fluid flow is established. The cooling air inflow inside the blade passage forbids the assumption of a constant mass flow along the main stream direction. To consider the change of the aerodynamic and thermodynamic behavior, a cooling air model was developed and implemented in the algorithm, which allows the mixing of radially arbitrarily distributed cooling air in the trailing edge section of each blade row. The viscous effects and the influence of cooling air mixing are considered by the use of selected loss correlations for profile, tip leakage, secondary flow and mixing losses in the S{sub 2m}-plane in terms of entropy. The method is applied to the four-stage high-temperature gas turbine Siemens KWU V84.3. The numerical results obtained are in good agreement with the experimental data.
Method for the addition of vulcanized waste rubber to virgin rubber products
Romine, R.A.; Snowden-Swan, L.J.
1997-01-28
The invention is a method of using enzymes from thiophyllic microbes for selectively breaking the sulfur rubber cross-link bonds in vulcanized rubber. The process is halted at the sulfoxide or sulfone step so that a devulcanized layer is reactive with virgin rubber. 8 figs.
Method for the addition of vulcanized waste rubber to virgin rubber products
Romine, Robert A.; Snowden-Swan, Lesley J.
1997-01-01
The invention is a method of using enzymes from thiophyllic microbes for selectively breaking the sulfur rubber cross-link bonds in vulcanized rubber. The process is halted at the sulfoxide or sulfone step so that a devulcanized layer is reactive with virgin rubber.
A Method to Evaluate Additional Waste Forms to Optimize Performance of the HLW Repository
D. Gombert; L. Lauerhass
2006-02-01
The DOE high-level waste (HLW) disposal system is based on decisions made in the 1970s. The de facto Yucca Mountain WAC for HLW, contained in the Waste Acceptance System Requirements Document (WASRD), and the DOE-EM Waste Acceptance Product Specification for Vitrified High Level Waste Forms (WAPS) tentatively describes waste forms to be interred in the repository, and limits them to borosilicate glass (BSG). It is known that many developed waste forms are as durable as or better than environmental assessment or “EA”-glass. Among them are the salt-ceramic and metallic waste forms developed at ANL-W. Also, iron phosphate glasses developed at University of Missouri show promise in stabilizing the most refractory materials in Hanford HLW. However, for any of this science to contribute, the current Total System Performance Assessment model must be able to evaluate the additional waste form to determine potential impacts on repository performance. The results can then support the technical bases required in the repository license application. A methodology is proposed to use existing analysis models to evaluate potential additional waste forms for disposal without gathering costly material specific degradation data. The concept is to analyze the potential impacts of waste form chemical makeup on repository performance assuming instantaneous waste matrix dissolution. This assumption obviates the need for material specific degradation models and is based on the relatively modest fractional contribution DOE HLW makes to the repository radionuclide and hazardous metals inventory. The existing analysis models, with appropriate data modifications, are used to evaluate geochemical interactions and material transport through the repository. This methodology would support early screening of proposed waste forms through simplified evaluation of disposal performance, and would provide preliminary guidance for repository license amendment in the future.
Strantza, Maria; Aggelis, Dimitrios G.; de Baere, Dieter; Guillaume, Patrick; van Hemelrijck, Danny
2015-01-01
During the last decades, structural health monitoring (SHM) systems are used in order to detect damage in structures. We have developed a novel structural health monitoring approach, the so-called “effective structural health monitoring” (eSHM) system. The current SHM system is incorporated into a metallic structure by means of additive manufacturing (AM) and has the possibility to advance life safety and reduce direct operative costs. It operates based on a network of capillaries that are integrated into an AM structure. The internal pressure of the capillaries is continuously monitored by a pressure sensor. When a crack nucleates and reaches the capillary, the internal pressure changes signifying the existence of the flaw. The main objective of this paper is to evaluate the crack detection capacity of the eSHM system and crack location accuracy by means of various non-destructive testing (NDT) techniques. During this study, detailed acoustic emission (AE) analysis was applied in AM materials for the first time in order to investigate if phenomena like the Kaiser effect and waveform parameters used in conventional metals can offer valuable insight into the damage accumulation of the AM structure as well. Liquid penetrant inspection, eddy current and radiography were also used in order to confirm the fatigue damage and indicate the damage location on un-notched four-point bending AM metallic specimens with an integrated eSHM system. It is shown that the eSHM system in combination with NDT can provide correct information on the damage condition of additive manufactured metals. PMID:26506349
Strantza, Maria; Aggelis, Dimitrios G; de Baere, Dieter; Guillaume, Patrick; van Hemelrijck, Danny
2015-01-01
During the last decades, structural health monitoring (SHM) systems are used in order to detect damage in structures. We have developed a novel structural health monitoring approach, the so-called "effective structural health monitoring" (eSHM) system. The current SHM system is incorporated into a metallic structure by means of additive manufacturing (AM) and has the possibility to advance life safety and reduce direct operative costs. It operates based on a network of capillaries that are integrated into an AM structure. The internal pressure of the capillaries is continuously monitored by a pressure sensor. When a crack nucleates and reaches the capillary, the internal pressure changes signifying the existence of the flaw. The main objective of this paper is to evaluate the crack detection capacity of the eSHM system and crack location accuracy by means of various non-destructive testing (NDT) techniques. During this study, detailed acoustic emission (AE) analysis was applied in AM materials for the first time in order to investigate if phenomena like the Kaiser effect and waveform parameters used in conventional metals can offer valuable insight into the damage accumulation of the AM structure as well. Liquid penetrant inspection, eddy current and radiography were also used in order to confirm the fatigue damage and indicate the damage location on un-notched four-point bending AM metallic specimens with an integrated eSHM system. It is shown that the eSHM system in combination with NDT can provide correct information on the damage condition of additive manufactured metals. PMID:26506349
Method for characterizing the coking tendencies of baseoils and additive-treated oils
Dickakian, G.B.
1989-07-18
This patent describes a method of characterizing the coking tendency of baseoil. The method consists the steps of: (a) subjecting the baseoil to conditions which accelerate asphaltene coke precursor formation in the baseoil, and (b) characterizing the coking tendency of the baseoil by determining (i) the onset and progression of asphaltene coke precursor formation as a function of time or (ii) the progression of asphaltene coke precursor formation as a function of time, wherein a faster onset of asphaltene coke precursor formation and a higher rate of asphaltene coke precursor formation or a higher rate of asphaltene coke precursor formation indicates a higher coking tendency of the baseoil than a slower onset of asphaltene coke precursor formation and a lower rate of asphaltene coke precursor formation or a lower rate of asphaltene coke precursor formation.
NASA Astrophysics Data System (ADS)
Alhuzaim, Abdullah F.
The work conducted for this thesis was to investigate the use of plasma arc welding (PAW) and steel shot as a means of additive manufacturing. A robotic PAW system and automatic shot feeder were used to manufacture linear walls approximately 100 mm long by 7 mm wide and 20 mm tall. The walls were built, layer-by-layer, on plain carbon steel substrate by adding individual 2.5 mm diameter plain carbon steel shot. Each layer was built, shot-by-shot, using a pulse of arc current to form a molten pool on the deposit into which each shot was deposited and melted. The deposition rate, a measure of productivity, was approximately 50 g/hour. Three walls were built using the same conditions except for the deposit preheat temperature prior to adding each new layer. The deposit preheat temperature was controlled by allowing the deposit to cool after each layer for an amount of time called the inter-layer wait time. The walls were sectioned and grain size and hardness distribution were measured as a function of wall height. The results indicated that, for all specimens, deposit grain size increased and hardness decreased as wall height increased. Furthermore, average grain size decreased and hardness increased as interlayer wait time increased. An analytical heat flow model was developed to study the influence of interlayer wait time on deposit temperature and therefore grain size and hardness. The results of the model indicated that as wall height increased, the rate of deposit heat removal by conduction to the substrate decreased leading to a higher preheat temperature after a fixed interlayer wait time causing grain size to increase as wall height increased. However, the model results also show that as wall height increased, the deposit surface area from which heat energy is lost via convection and radiation increased. The model also demonstrated that the use of a means of forced convection to rapidly remove heat from the deposit could be an effective way to boost
NASA Astrophysics Data System (ADS)
Compernolle, S.; Ceulemans, K.; Müller, J.-F.
2011-04-01
We present EVAPORATION (Estimation of VApour Pressure of ORganics, Accounting for Temperature, Intramolecular, and Non-additivity effects), a method to predict vapour pressure p0 of organic molecules needing only molecular structure as input. The method is applicable to zero-, mono- and polyfunctional molecules. A simple formula to describe log10p0(T) is employed, that takes into account both a wide temperature dependence and the non-additivity of functional groups. In order to match the recent data on functionalised diacids an empirical modification to the method was introduced. Contributions due to carbon skeleton, functional groups, and intramolecular interaction between groups are included. Molecules typically originating from oxidation of biogenic molecules are within the scope of this method: carbonyls, alcohols, ethers, esters, nitrates, acids, peroxides, hydroperoxides, peroxy acyl nitrates and peracids. Therefore the method is especially suited to describe compounds forming secondary organic aerosol (SOA).
Storage of platelets in additive solutions: a new method for storage using sodium chloride solution.
Gulliksson, H; Sallander, S; Pedajas, I; Christenson, M; Wiechel, B
1992-06-01
The in vitro effect of 6-day storage of platelets prepared from 6 pooled buffy coat (BC) units and stored in a platelet storage medium containing approximately 40 percent CPD-plasma and 60 percent platelet additive solution (PAS) was evaluated. PAS is composed of sodium and potassium chloride, citrate, phosphate, and mannitol. The total count of platelets per pooled unit included in the in vitro studies (n = 25) was 376 +/- 59 x 10(9) (mean +/- SD). The present study included three steps. 1. Evaluation of platelet storage in one (n = 7) and two (n = 6) 1000-mL polyolefin containers using PAS. During storage in one container, significantly lower values were found for pH, pO2, glucose, ATP, and the ratio of ATP to AMP+ADP+ATP. The values for mean platelet volume, pCO2, lactate, and extracellular adenylate kinase activity were significantly higher. These results indicate that storage in only one polyolefin container is not appropriate for maintaining satisfactory platelet quality. During storage in two polyolefin containers, a remarkably decreased lactate production (0.07 +/- 0.02 mmol/day/10(11) platelets) was noted. 2. PAS was substituted for saline during 6-day storage in two 1000-mL polyolefin containers (n = 12). The composition of the platelet preparations was the same in all other respects. Similar in vitro results were noted with PAS and saline, which indicated that PAS has no specific effect on the storage of platelets different from that of saline.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:1626346
NASA Astrophysics Data System (ADS)
Chen, Chuchu; Hong, Jialin; Zhang, Liying
2016-02-01
Stochastic Maxwell equations with additive noise are a system of stochastic Hamiltonian partial differential equations intrinsically, possessing the stochastic multi-symplectic conservation law. It is shown that the averaged energy increases linearly with respect to the evolution of time and the flow of stochastic Maxwell equations with additive noise preserves the divergence in the sense of expectation. Moreover, we propose three novel stochastic multi-symplectic methods to discretize stochastic Maxwell equations in order to investigate the preservation of these properties numerically. We make theoretical discussions and comparisons on all of the three methods to observe that all of them preserve the corresponding discrete version of the averaged divergence. Meanwhile, we obtain the corresponding dissipative property of the discrete averaged energy satisfied by each method. Especially, the evolution rates of the averaged energies for all of the three methods are derived which are in accordance with the continuous case. Numerical experiments are performed to verify our theoretical results.
NASA Astrophysics Data System (ADS)
Krzyżek, Robert
2015-12-01
The paper deals with the problem of surveying buildings in the RTN GNSS mode using modernized indirect methods of measurement. As a result of the classical realtime measurements using indirect methods (intersection of straight lines or a point on a straight line), we obtain a building structure (a building) which is largely deformed. This distortion is due to the inconsistency of the actual dimensions of the building (tie distances) relative to the obtained measurement results. In order to eliminate these discrepancies, and thus to ensure full consistency of the building geometric structure, an innovative solution was applied - the method of vector addition - to modify the linear values (tie distances) of the external face of the building walls. A separate research problem tackled in the article, although not yet fully solved, is the issue of coordinates of corners of a building obtained after the application of the method of vector addition.
NASA Astrophysics Data System (ADS)
Larionova, E. V.; Bulygina, K. A.
2016-02-01
In this work the possibility of simultaneous spectrophotometric determination of chromium (VI) and iron (III) in alloys with help of the mixed organic reagent (diphenylcarbazide and 1,10-phenanthroline) is studied. We have applied H-point standard addition method to determine concentrations of chromium (VI) and iron (III) from the mixture. The pure signals of complexes of chromium (VI) with diphenylcarbazide and iron (III) with the 1,10-phenanthroline and their calibration plots are previously carried out. We established the possibility of simultaneous determination of chromium (VI) and iron (III) in the different concentration ranges by H-point standard addition method. Correctness of determination of concentration by means of the offered technique is proved by "added-found" method for a series of mixtures with different ratios of concentration of chromium (VI) and iron (III). It is founded that the error of determination of concentration doesn't exceed 33%.
NASA Technical Reports Server (NTRS)
Sharma, Surendra P.; Huo, Winifred M.; Park, Chul
1988-01-01
A theoretical study of vibrational excitations and dissociations of nitrogen undergoing a nonequilibrium relaxation process upon heating and cooling is reported. The rate coefficients for collisional induced vibrational transitions and transitions from a bound vibrational state into a dissociative state have been calculated using an extension of the theory originally proposed by Schwarz (SSH) et al. (1952). High-lying vibrational states and dissociative states were explicitly included but rotational energy transfer was neglected. The transition probabilities calculated from the SSH theory were fed into the master equation, which was integrated numerically to determine the population distribution of the vibrational states as well as bulk thermodynamic properties. The results show that: (1) the transition rates have a minimum near the middle of the bound vibrational levels, causing a bottleneck in the vibrational relaxation and dissociation rates; (2) high vibrational states are always in equilibrium with the dissociative state; (3) for the heating case, only the low vibrational states relax according to the Landau-Teller theory; (4) for the cooling case, vibrational relaxation cannot be described by a rate equation; (5) Park's (1985, 1988) two-temperature model is approximately valid; and (6) the average vibrational energy removed in dissociation is about 30 percent of the dissociation energy.
NASA Astrophysics Data System (ADS)
Tilch, Nils; Römer, Alexander; Jochum, Birgit; Schattauer, Ingrid
2014-05-01
. Previous studies show that, especially with radiometric measurements, the two-dimensional spatial variability of the nature of the process-relevant soil, close to the surface can be determined. In addition, the electromagnetic measurements are more important to obtain three-dimensional information of the deeper geological conditions and to improve the area-specific geological knowledge and understanding. The validation of these measurements is done with terrestrial geoelectrical measurements. So both aspects, radiometric and electromagnetic measurements, are important and subsequently, interpretation of the geophysical results can be used as the parameter maps in the modeling of more realistic susceptibility maps with respect to various processes. Within this presentation, results of geophysical measurements, the outcome and the derived parameter maps, as well as first process-oriented susceptibility maps in terms of gravitational soil mass movements will be presented. As an example results which were obtained with a heuristic method in an area in Vorarlberg (Western Austria) will be shown. References: Schwarz, L. & Tilch, N. (2011): Why are good process data so important for the modelling of landslide susceptibility maps?- EGU-Postersession "Landslide hazard and risk assessment, and landslide management" (NH 3.6), Vienna. [http://www.geologie.ac.at/fileadmin/user_upload/dokumente/pdf/poster/poster_2011_egu_schwarz_tilch_1.pdf] Tilch, N. & Schwarz, L. (2011): Spatial and scale-dependent variability in data quality and their influence on susceptibility maps for gravitational mass movements in soil, modelled by heuristic method.- EGU-Postersession "Landslide hazard and risk assessment, and landslide management" (NH 3.6); Vienna. [http://www.geologie.ac.at/fileadmin/user_upload/dokumente/pdf/poster/poster_2011_egu_tilch_schwarz.pdf
Fu, Yanqing; Zhou, Zhihui; Kong, Hongwei; Lu, Xin; Zhao, Xinjie; Chen, Yihui; Chen, Jia; Wu, Zeming; Xu, Zhiliang; Zhao, Chunxia; Xu, Guowang
2016-09-01
Identification of illegal additives in complex matrixes is important in the food safety field. In this study a nontargeted screening strategy was developed to find illegal additives based on ultrahigh-performance liquid chromatography-high-resolution mass spectrometry (UHPLC-HRMS). First, an analytical method for possible illegal additives in complex matrixes was established including fast sample pretreatment, accurate UHPLC separation, and HRMS detection. Second, efficient data processing and differential analysis workflow were suggested and applied to find potential risk compounds. Third, structure elucidation of risk compounds was performed by (1) searching online databases [Metlin and the Human Metabolome Database (HMDB)] and an in-house database which was established at the above-defined conditions of UHPLC-HRMS analysis and contains information on retention time, mass spectra (MS), and tandem mass spectra (MS/MS) of 475 illegal additives, (2) analyzing fragment ions, and (3) referring to fragmentation rules. Fish was taken as an example to show the usefulness of the nontargeted screening strategy, and six additives were found in suspected fish samples. Quantitative analysis was further carried out to determine the contents of these compounds. The satisfactory application of this strategy in fish samples means that it can also be used in the screening of illegal additives in other kinds of food samples. PMID:27480407
[Denoising and assessing method of additive noise in the ultraviolet spectrum of SO2 in flue gas].
Zhou, Tao; Sun, Chang-Ku; Liu, Bin; Zhao, Yu-Mei
2009-11-01
The problem of denoising and assessing method of the spectrum of SO2 in flue gas was studied based on DOAS. The denoising procedure of the additive noise in the spectrum was divided into two parts: reducing the additive noise and enhancing the useful signal. When obtaining the absorption feature of measured gas, a multi-resolution preprocessing method of original spectrum was adopted for denoising by DWT (discrete wavelet transform). The signal energy operators in different scales were used to choose the denoising threshold and separate the useful signal from the noise. On the other hand, because there was no sudden change in the spectra of flue gas in time series, the useful signal component was enhanced according to the signal time dependence. And the standard absorption cross section was used to build the ideal absorption spectrum with the measured gas temperature and pressure. This ideal spectrum was used as the desired signal instead of the original spectrum in the assessing method to modify the SNR (signal-noise ratio). There were two different environments to do the proof test-in the lab and at the scene. In the lab, SO2 was measured several times with the system using this method mentioned above. The average deviation was less than 1.5%, while the repeatability was less than 1%. And the short range experiment data were better than the large range. In the scene of a power plant whose concentration of flue gas had a large variation range, the maximum deviation of this method was 2.31% in the 18 groups of contrast data. The experimental results show that the denoising effect of the scene spectrum was better than that of the lab spectrum. This means that this method can improve the SNR of the spectrum effectively, which is seriously polluted by additive noise. PMID:20101989
Hajian, Reza; Mousavi, Esmat; Shams, Nafiseh
2013-06-01
Net analyte signal standard addition method has been used for the simultaneous determination of sulphadiazine and trimethoprim by spectrophotometry in some bovine milk and veterinary medicines. The method combines the advantages of standard addition method with the net analyte signal concept which enables the extraction of information concerning a certain analyte from spectra of multi-component mixtures. This method has some advantages such as the use of a full spectrum realisation, therefore it does not require calibration and prediction step and only a few measurements require for the determination. Cloud point extraction based on the phenomenon of solubilisation used for extraction of sulphadiazine and trimethoprim in bovine milk. It is based on the induction of micellar organised media by using Triton X-100 as an extraction solvent. At the optimum conditions, the norm of NAS vectors increased linearly with concentrations in the range of 1.0-150.0 μmolL(-1) for both sulphadiazine and trimethoprim. The limits of detection (LOD) for sulphadiazine and trimethoprim were 0.86 and 0.92 μmolL(-1), respectively. PMID:23411170
Yang, Nan; Tian, Yanling; Zhang, Dawei
2015-11-01
Heterogeneous porous scaffolds have important applications in biomedical engineering, as they can mimic the structures of natural tissues to achieve the corresponding properties. Here, we introduce a new and easy to implement real function based method for constructing complex, heterogeneous porous structures, including hybrid structures, stochastic structures, functionally gradient structures, and multi-scale structures, or their combinations (e.g., hybrid multi-scale structures). Based on micro-CT data, a femur-mimetic structure with gradient morphology was constructed using our method and fabricated using stereolithography. Results showed that our method could generate gradient porosity or gradient specific surfaces and be sufficiently flexible for use with micro-CT data and additive manufacturing (AM) techniques. PMID:26320819
NASA Astrophysics Data System (ADS)
Maurer, Simon A.; Lambrecht, Daniel S.; Flaig, Denis; Ochsenfeld, Christian
2012-04-01
A new integral estimate for four-center two-electron integrals is introduced that accounts for distance information between the bra- and ket-charge distributions describing the two electrons. The screening is denoted as QQR and combines the most important features of the conventional Schwarz screening by Häser and Ahlrichs published in 1989 [J. Comput. Chem. 10, 104 (1989), 10.1002/jcc.540100111] and our multipole-based integral estimates (MBIE) introduced in 2005 [D. S. Lambrecht and C. Ochsenfeld, J. Chem. Phys. 123, 184101 (2005), 10.1063/1.2079967]. At the same time the estimates are not only tighter but also much easier to implement, so that we recommend them instead of our MBIE bounds introduced first for accounting for charge-distance information. The inclusion of distance dependence between charge distributions is not only useful at the SCF level but is particularly important for describing electron-correlation effects, e.g., within AO-MP2 theory, where the decay behavior is at least 1/R4 or even 1/R6. In our present work, we focus on studying the efficiency of our QQR estimates within SCF theory and demonstrate the performance for a benchmark set of 44 medium to large molecules, where savings of up to a factor of 2 for exchange integrals are observed for larger systems. Based on the results of the benchmark set we show that reliable tightness of integral estimates is more important for the screening performance than rigorous upper bound properties.
NASA Astrophysics Data System (ADS)
Heriyanto, Heri; Widya Ernayati, K.; Umam, Chairul; Margareta, Nita
2015-12-01
UBC (upgrading brown coal) is a method of improving the quality of coal by using oil as an additive. Through processing in the oil media, not just the calories that increase, but there is also water repellent properties and a decrease in the tendency of spontaneous combustion of coal products produced. The results showed a decrease in the water levels of natural coal bayah reached 69%, increase in calorific value reached 21.2%. Increased caloric value and reduced water content caused by the water molecules on replacing seal the pores of coal by oil and atoms C on the oil that is bound to increase the percentage of coal carbon. As a result of this experiment is, the produced coal has better calorific value, the increasing of this new calorific value up to 23.8% with the additive waste lubricant, and the moisture content reduced up to 69.45%.
NASA Astrophysics Data System (ADS)
Asadpour-Zeynali, Karim; Bastami, Mohammad
2010-02-01
In this work a new modification of the standard addition method called "net analyte signal standard addition method (NASSAM)" is presented for the simultaneous spectrofluorimetric and spectrophotometric analysis. The proposed method combines the advantages of standard addition method with those of net analyte signal concept. The method can be applied for the determination of analyte in the presence of known interferents. The accuracy of the predictions against H-point standard addition method is not dependent on the shape of the analyte and interferent spectra. The method was successfully applied to simultaneous spectrofluorimetric and spectrophotometric determination of pyridoxine (PY) and melatonin (MT) in synthetic mixtures and in a pharmaceutical formulation.
Komatsu, Yoshihiro; Kishigami, Satoshi; Mishina, Yuji
2014-01-01
In situ hybridization is a powerful method for detecting endogenous mRNA sequences in morphologically preserved samples. We provide in situ hybridization methods, which are specifically optimized for mouse embryonic samples as whole mounts and section tissues. Additionally, β-Galactosidase (β-gal) is a popular reporter for detecting the expression of endogenous or exogenous genes. We reveal that 6-chloro-3-indoxyl-β-D-galactopyranoside (S-gal) is a more sensitive substrate for β-gal activity than 5-bromo-4-chloro-3-indolyl-β-D-galactoside (X-gal). S-gal is advantageous where β-gal activity is limited including early stage mouse embryos. As a result of the increased sensitivity as well as the color compatibility of S-gal, we successfully combined β-gal staining using S-gal with in situ hybridization using DIG-labeled probes in both whole mounts and sections. PMID:24318810
NASA Astrophysics Data System (ADS)
Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokić, Miroslav; Maksimović, Vesna
2014-08-01
A method of synthesizing Ni-based catalysts supported on α-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.
Hanh, Vu Thi; Kobayashi, Yutaro; Maebuchi, Motohiro; Nakamori, Toshihiro; Tanaka, Mitsuru; Matsui, Toshiro
2016-01-01
The aim of this study was to establish, through a standard addition method, a convenient quantification assay for dipeptides (GY, YG, SY, YS, and IY) in soybean hydrolysate using 2,4,6-trinitrobenzene sulfonate (TNBS) derivatization-aided LC-TOF-MS. Soybean hydrolysate samples (25.0 mg mL(-1)) spiked with target standards were subjected to TNBS derivatization. Under the optimal LC-MS conditions, five target dipeptides derivatized with TNBS were successfully detected. Examination of the standard addition curves, with a correlation coefficient of r(2) > 0.979, provided a reliable quantification of the target dipeptides, GY, YG, SY, YS, and IY, in soybean hydrolysate to be 424 ± 20, 184 ± 9, 2188 ± 199, 327 ± 16, and 2211 ± 133 μg g(-1) of hydrolysate, respectively. The proposed LC-MS assay is a reliable and convenient assay method, with no interference from matrix effects in hydrolysate, and with no requirement for the use of an isotope labeled internal standard. PMID:26212980
Fetrow, Jacquelyn S.; Siew, Naomi; Di Gennaro, Jeannine A.; Martinez-Yamout, Maria; Dyson, H. Jane; Skolnick, Jeffrey
2001-01-01
A function annotation method using the sequence-to-structure-to-function paradigm is applied to the identification of all disulfide oxidoreductases in the Saccharomyces cerevisiae genome. The method identifies 27 sequences as potential disulfide oxidoreductases. All previously known thioredoxins, glutaredoxins, and disulfide isomerases are correctly identified. Three of the 27 predictions are probable false-positives. Three novel predictions, which subsequently have been experimentally validated, are presented. Two additional novel predictions suggest a disulfide oxidoreductase regulatory mechanism for two subunits (OST3 and OST6) of the yeast oligosaccharyltransferase complex. Based on homology, this prediction can be extended to a potential tumor suppressor gene, N33, in humans, whose biochemical function was not previously known. Attempts to obtain a folded, active N33 construct to test the prediction were unsuccessful. The results show that structure prediction coupled with biochemically relevant structural motifs is a powerful method for the function annotation of genome sequences and can provide more detailed, robust predictions than function prediction methods that rely on sequence comparison alone. PMID:11316881
Cimetiere, Nicolas; Soutrel, Isabelle; Lemasle, Marguerite; Laplanche, Alain; Crocq, André
2013-01-01
The study of the occurrence and fate of pharmaceutical compounds in drinking or waste water processes has become very popular in recent years. Liquid chromatography with tandem mass spectrometry is a powerful analytical tool often used to determine pharmaceutical residues at trace level in water. However, many steps may disrupt the analytical procedure and bias the results. A list of 27 environmentally relevant molecules, including various therapeutic classes and (cardiovascular, veterinary and human antibiotics, neuroleptics, non-steroidal anti-inflammatory drugs, hormones and other miscellaneous pharmaceutical compounds), was selected. In this work, a method was developed using ultra performance liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS) and solid-phase extraction to determine the concentration of the 27 targeted pharmaceutical compounds at the nanogram per litre level. The matrix effect was evaluated from water sampled at different treatment stages. Conventional methods with external calibration and internal standard correction were compared with the standard addition method (SAM). An accurate determination of pharmaceutical compounds in drinking water was obtained by the SAM associated with UPLC-MS/MS. The developed method was used to evaluate the occurrence and fate of pharmaceutical compounds in some drinking water treatment plants in the west of France. PMID:24617062
Krause, R T; August, E M
1983-03-01
Several fruits and vegetables were fortified at a low (0.02-0.5 ppm) and at a high (0.1-5 ppm) level with pesticides and with a synergist, and recoveries were determined. Analyses were performed by using 3 steps of a multiresidue method for determining N-methylcarbamates in crops: methanol extraction followed by removal of plant co-extractives by solvent partitioning and chromatography with a charcoal-silanized Celite column. Eleven compounds were determined by using a high performance liquid chromatograph equipped with a reverse phase column and a fluorescence detector. Twelve additional compounds were determined by using a gas-liquid chromatograph equipped with a nonpolar packed column and an electron capture or flame photometric detector. Recoveries of 10 pesticides (azinphos ethyl, azinphos methyl, azinphos methyl oxygen analog, carbaryl, carbofuran, naphthalene acetamide, naphthalene acetic acid methyl ester, napropamide, phosalone, and phosalone oxygen analog) and the synergist piperonyl butoxide, which were determined by high performance liquid chromatography, averaged 100% (range 86-117) at the low fortification level and 102% (range 93-115) at the high fortification level. Quantitative recovery of naphthalene acetamide through the method required that an additional portion of eluting solution be passed through the charcoal column. Recoveries of 7 additional pesticides (dimethoate, malathion, methyl parathion, mevinphos, parathion, phorate oxygen analog, and pronamide), which were determined by gas-liquid chromatography (GLC), averaged 108% (range 100-120) at the low fortification level and 107% (range 99-122) at the high fortification level. DDT, diazinon, dieldrin, phorate, and pirimiphos ethyl, which were determined by GLC, were not quantitatively recovered. PMID:6853408
Molisani, Andre Luiz; Yoshimura, Humberto Naoyuki
2010-06-15
AlN powders were synthesized at low temperatures (1300 and 1400 {sup o}C) by the carbothermal reduction-nitridation (CRN) method using multicomponent additive systems. The synthesis treatments were conducted in a graphite furnace with flowing nitrogen gas between 1200 and 1500 {sup o}C using powder mixtures with Al{sub 2}O{sub 3}:C molar ratio of 1:3 and 0.5-3 wt% of CaF{sub 2}, Y{sub 2}O{sub 3}, Li{sub 2}CO{sub 3} and/or SrCO{sub 3} as additives. In relation to the conventional CRN process, the use of multicomponent additive systems reduced the synthesis temperature in 200 {sup o}C (CaF{sub 2}-SrCO{sub 3}), 100 {sup o}C (CaF{sub 2}-Li{sub 2}CO{sub 3} and CaF{sub 2}-Y{sub 2}O{sub 3}-Li{sub 2}CO{sub 3}) or <100 {sup o}C (CaF{sub 2}-Y{sub 2}O{sub 3} and CaF{sub 2}-Y{sub 2}O{sub 3}-Li{sub 2}CO{sub 3}-SrCO{sub 3}). X-ray diffraction patterns showed that the additives reacted with the alumina powder forming aluminate phases, which vaporized with the increase of synthesis temperature. The enhanced AlN conversion rate was discussed in terms of the vaporization of aluminates in the reducing atmosphere.
NASA Astrophysics Data System (ADS)
Kuraz, Michal
2016-06-01
Modelling the transport processes in a vadose zone, e.g. modelling contaminant transport or the effect of the soil water regime on changes in soil structure and composition, plays an important role in predicting the reactions of soil biotopes to anthropogenic activity. Water flow is governed by the quasilinear Richards equation. The paper concerns the implementation of a multi-time-step approach for solving a nonlinear Richards equation. When modelling porous media flow with a Richards equation, due to a possible convection dominance and a convergence of a nonlinear solver, a stable finite element approximation requires accurate temporal and spatial integration. The method presented here enables adaptive domain decomposition algorithm together with a multi-time-step treatment of actively changing subdomains.
Hayes, R.B.; Haskell, E.H.; Kenner, G.H.
1996-01-01
Additive dose methods commonly used in electron paramagnetic resonance (EPR) dosimetry are time consuming and labor intensive. We have developed a mathematical approach for determining optimal spacing of applied doses and the number of spectra which should be taken at each dose level. Expected uncertainitites in the data points are assumed to be normally distributed with a fixed standard deviation and linearity of dose response is also assumed. The optimum spacing and number of points necessary for the minimal error can be estimated, as can the likely error in the resulting estimate. When low doses are being estimated for tooth enamel samples the optimal spacing is shown to be a concentration of points near the zero dose value with fewer spectra taken at a single high dose value within the range of known linearity. Optimization of the analytical process results in increased accuracy and sample throughput.
Tsuru, Kanji; Ruslin; Maruta, Michito; Matsuya, Shigeki; Ishikawa, Kunio
2015-10-01
Appropriate setting time is an important parameter that determines the effectiveness of apatite cement (AC) for clinical application, given the issues of crystalline inflammatory response phenomena if AC fails to set. To this end, the present study analyzes the effects of the method of apatite seed crystals addition on the setting reaction of α-tricalcium phosphate (α-TCP) based AC. Two ACs, both consisting of α-TCP and calcium deficient hydroxyapatite (cdHAp), were analyzed in this study. In one AC, cdHAp was added externally to α-TCP and this AC was abbreviated as AC(EA). In the other AC, α-TCP was partially hydrolyzed to form cdHAp on the surface of α-TCP. This AC was referred to as AC(PH). Results indicate a decrease in the setting time of both ACs with the addition of cdHAp. Among them, for the given amount of added cdHAp, AC(PH) showed relatively shorter setting time than AC(EA). Besides, the mechanical strength of the set AC(PH) was also higher than that of set AC(EA). These properties of AC(PH) were attributed to the predominant crystal growth of cdHAp in the vicinity of the α-TCP particle surface. Accordingly, it can be concluded that the partial hydrolysis of α-TCP may be a better approach to add low crystalline cdHAp onto α-TCP based AC. PMID:26411440
Sutcu, Mucahit; Ozturk, Savas; Yalamac, Emre; Gencel, Osman
2016-10-01
Production of porous clay bricks lightened by adding olive mill waste as a pore making additive was investigated. Factors influencing the brick manufacturing process were analyzed by an experimental design, Taguchi method, to find out the most favorable conditions for the production of bricks. The optimum process conditions for brick preparation were investigated by studying the effects of mixture ratios (0, 5 and 10 wt%) and firing temperatures (850, 950 and 1050 °C) on the physical, thermal and mechanical properties of the bricks. Apparent density, bulk density, apparent porosity, water absorption, compressive strength, thermal conductivity, microstructure and crystalline phase formations of the fired brick samples were measured. It was found that the use of 10% waste addition reduced the bulk density of the samples up to 1.45 g/cm(3). As the porosities increased from 30.8 to 47.0%, the compressive strengths decreased from 36.9 to 10.26 MPa at firing temperature of 950 °C. The thermal conductivities of samples fired at the same temperature showed a decrease of 31% from 0.638 to 0.436 W/mK, which is hopeful for heat insulation in the buildings. Increasing of the firing temperature also affected their mechanical and physical properties. This study showed that the olive mill waste could be used as a pore maker in brick production. PMID:27343435
NASA Astrophysics Data System (ADS)
Stavinoha, Joe N.
The process of producing near net-shape components by material deposition is known as additive manufacturing. All additive manufacturing processes are based on the addition of material with the main driving forces being cost reduction and flexibility in both manufacturing and product design. With wire metal deposition, metal is deposited as beads side-by-side and layer-by-layer in a desired pattern to build a complete component or add features on a part. There are minimal waste products, low consumables, and an efficient use of energy and feedstock associated with additive manufacturing processes. Titanium and titanium alloys are useful engineering materials that possess an extraordinary combination of properties. Some of the properties that make titanium advantageous for structural applications are its high strength-to-weight ratio, low density, low coefficient of thermal expansion, and good corrosion resistance. The most commonly used titanium alloy, Ti-6Al-4V, is typically used in aerospace applications, pressure vessels, aircraft gas turbine disks, cases and compressor blades, and surgical implants. Because of the high material prices associated with titanium alloys, the production of near net-shape components by additive manufacturing is an attractive option for the manufacturing of Ti-6Al-4V alloy components. In this thesis, the manufacturing of cylindrical Ti-6Al-4V alloy specimens by wire metal deposition utilizing the plasma arc welding process was demonstrated. Plasma arc welding is a cost effective additive manufacturing technique when compared to other current additive manufacturing methods such as laser beam welding and electron beam welding. Plasma arc welding is considered a high-energy-density welding processes which is desirable for the successful welding of titanium. Metal deposition was performed using a constant current plasma arc welding power supply, flow-purged welding chamber, argon shielding and orifice gas, ERTi-5 filler metal, and Ti-6Al
Alghamdi, Ahmad H
2005-01-01
Square-wave adsorptive stripping voltammetric (AdSV) determinations of trace concentrations of the azo coloring agent Amaranth are described. The analytical methodology used was based on the adsorptive preconcentration of the dye on the hanging mercury drop electrode, followed by initiation of a negative sweep. In a pH 10 carbonate supporting electrolyte, Amaranth gave a well-defined and sensitive AdSV peak at -518 mV. The electroanalytical determination of this azo dye was found to be optimal in carbonate buffer (pH 10) under the following experimental conditions: accumulation time, 120 s; accumulation potential, 0.0 V; scan rate, 600 mV/s; pulse amplitude, 90 mV; and frequency, 50 Hz. Under these optimized conditions the AdSV peak current was proportional over the concentration range 1 x 10(-8)-1.1 x 10(-7) mol/L (r = 0.999) with a detection limit of 1.7 x 10(-9) mol/L (1.03 ppb). This analytical approach possessed enhanced sensitivity, compared with conventional liquid chromatography or spectrophotometry and it was simple and fast. The precision of the method, expressed as the relative standard deviation, was 0.23%, whereas the accuracy, expressed as the mean recovery, was 104%. Possible interferences by several substances usually present as food additive azo dyes (E110, E102), gelatin, natural and artificial sweeteners, preservatives, and antioxidants were also investigated. The developed electroanalyticals method was applied to the determination of Amaranth in soft drink samples, and the results were compared with those obtained by a reference spectrophotometric method. Statistical analysis (paired t-test) of these data showed that the results of the 2 methods compared favorably. PMID:16001853
NASA Astrophysics Data System (ADS)
Kadir, K.; Gao, H.; Payne, A.; Soraghan, J.; Berry, C.
2012-10-01
In this paper an automatic algorithm for the left ventricle (LV) wall segmentation and oedema quantification from T2-weighted cardiac magnetic resonance (CMR) images is presented. The extent of myocardial oedema delineates the ischaemic area-at-risk (AAR) after myocardial infarction (MI). Since AAR can be used to estimate the amount of salvageable myocardial post-MI, oedema imaging has potential clinical utility in the management of acute MI patients. This paper presents a new scheme based on the variational level set method (LSM) with additional shape constraint for the segmentation of T2-weighted CMR image. In our approach, shape information of the myocardial wall is utilized to introduce a shape feature of the myocardial wall into the variational level set formulation. The performance of the method is tested using real CMR images (12 patients) and the results of the automatic system are compared to manual segmentation. The mean perpendicular distances between the automatic and manual LV wall boundaries are in the range of 1-2 mm. Bland-Altman analysis on LV wall area indicates there is no consistent bias as a function of LV wall area, with a mean bias of -121 mm2 between individual investigator one (IV1) and LSM, and -122 mm2 between individual investigator two (IV2) and LSM when compared to two investigators. Furthermore, the oedema quantification demonstrates good correlation when compared to an expert with an average error of 9.3% for 69 slices of short axis CMR image from 12 patients.
NASA Astrophysics Data System (ADS)
Rahman, Taibur; Renaud, Luke; Heo, Deuk; Renn, Michael; Panat, Rahul
2015-10-01
The fabrication of 3D metal-dielectric structures at sub-mm length scale is highly important in order to realize low-loss passives and GHz wavelength antennas with applications in wearable and Internet-of-Things (IoT) devices. The inherent 2D nature of lithographic processes severely limits the available manufacturing routes to fabricate 3D structures. Further, the lithographic processes are subtractive and require the use of environmentally harmful chemicals. In this letter, we demonstrate an additive manufacturing method to fabricate 3D metal-dielectric structures at sub-mm length scale. A UV curable dielectric is dispensed from an Aerosol Jet system at 10-100 µm length scale and instantaneously cured to build complex 3D shapes at a length scale <1 mm. A metal nanoparticle ink is then dispensed over the 3D dielectric using a combination of jetting action and tilted dispense head, also using the Aerosol Jet technique and at a length scale 10-100 µm, followed by the nanoparticle sintering. Simulation studies are carried out to demonstrate the feasibility of using such structures as mm-wave antennas. The manufacturing method described in this letter opens up the possibility of fabricating an entirely new class of custom-shaped 3D structures at a sub-mm length scale with potential applications in 3D antennas and passives.
Aşçı, Bürge; Dinç Zor, Şule; Aksu Dönmez, Özlem
2016-01-01
Box-Behnken design was applied to optimize high performance liquid chromatography (HPLC) conditions for the simultaneous determination of potassium sorbate, sodium benzoate, carmoisine, allura red, ponceau 4R, and caffeine in commercial soft drinks. The experimental variables chosen were pH (6.0–7.0), flow rate (1.0–1.4 mL/min), and mobile phase ratio (85–95% acetate buffer). Resolution values of all peak pairs were used as a response. Stationary phase was Inertsil OctaDecylSilane- (ODS-) 3V reverse phase column (250 × 4.6 mm, 5 μm) dimensions. The detection was performed at 230 nm. Optimal values were found 6.0 pH, 1.0 mL/min flow rate, and 95% mobile phase ratio for the method which was validated by calculating the linearity (r2 > 0.9962), accuracy (recoveries ≥ 95.75%), precision (intraday variation ≤ 1.923%, interday variation ≤ 1.950%), limits of detection (LODs), and limits of quantification (LOQs) parameters. LODs and LOQs for analytes were in the range of 0.10–0.19 μg/mL and 0.33–0.63 μg/mL, respectively. The proposed method was applied successfully for the simultaneous determination of the mixtures of five food additives and caffeine in soft drinks. PMID:26989415
Aşçı, Bürge; Dinç Zor, Şule; Aksu Dönmez, Özlem
2016-01-01
Box-Behnken design was applied to optimize high performance liquid chromatography (HPLC) conditions for the simultaneous determination of potassium sorbate, sodium benzoate, carmoisine, allura red, ponceau 4R, and caffeine in commercial soft drinks. The experimental variables chosen were pH (6.0-7.0), flow rate (1.0-1.4 mL/min), and mobile phase ratio (85-95% acetate buffer). Resolution values of all peak pairs were used as a response. Stationary phase was Inertsil OctaDecylSilane- (ODS-) 3V reverse phase column (250 × 4.6 mm, 5 μm) dimensions. The detection was performed at 230 nm. Optimal values were found 6.0 pH, 1.0 mL/min flow rate, and 95% mobile phase ratio for the method which was validated by calculating the linearity (r (2) > 0.9962), accuracy (recoveries ≥ 95.75%), precision (intraday variation ≤ 1.923%, interday variation ≤ 1.950%), limits of detection (LODs), and limits of quantification (LOQs) parameters. LODs and LOQs for analytes were in the range of 0.10-0.19 μg/mL and 0.33-0.63 μg/mL, respectively. The proposed method was applied successfully for the simultaneous determination of the mixtures of five food additives and caffeine in soft drinks. PMID:26989415
NASA Astrophysics Data System (ADS)
Junaidi, Triyana, Kuwat; Harsojo, Suharyadi, Edi
2016-04-01
We report our investigation on the effect of chloride ions oncontrolling the shapes and properties of silver nanorods(AgNRs) synthesized using a polyol method. In this study, we used polyvinyl alcohol (PVA) as a capping agent and sodium chloride (NaCl) as asalt precursor and performed at the oilbath temperature of 140 °C. The chloride ions originating from the NaCl serve to control the growth of the silver nanorods. Furthermore, the synthesized silver nanorodswere characterized using UV-VIS, XRD, SEM and TEM. The results showed that besides being able to control the growth of AgCl atoms, the chloride ions were also able to control the growth of multi-twinned-particles into the single crystalline silver nanorods by micrometer-length. At an appropriate concentration of NaCl, the diameter of silver nanorodsdecreased significantly compared to that of without chloride ion addition. This technique may be useful since a particular diameter of silver nanorods affects a particular application in the future.
NASA Astrophysics Data System (ADS)
Junaidi, Yunus, Muhammad; Triyana, Kuwat; Harsojo, Suharyadi, Edi
2016-04-01
We report our investigation on the effect of chloride ions on controlling the shapes and properties of silver nanorods (AgNRs) synthesized using a polyol method. In this study, we used polyvinyl alcohol (PVA) as a capping agent and sodium chloride (NaCl) as a salt precursor and performed at the oil bath temperature of 140°C. The chloride ions originating from the NaCl serve to control the growth of the silver nanorods. Furthermore, the synthesized silver nanorods were characterized using SEM and XRD. The results showed that besides being able to control the growth of AgCl atoms, the chloride ions were also able to control the growth of multi-twinned-particles into the single crystalline of silver nanorods by micrometer-length. At an appropriate concentration of NaCl, the diameter of silver nanorods decreased significantly compared to that of without chloride ion addition. This technique may be useful since a particular diameter of silver nanorods affects a particular application in the future.
Harrup, Mason K; Rollins, Harry W
2013-11-26
An additive comprising a phosphazene compound that has at least two reactive functional groups and at least one capping functional group bonded to phosphorus atoms of the phosphazene compound. One of the at least two reactive functional groups is configured to react with cellulose and the other of the at least two reactive functional groups is configured to react with a resin, such as an amine resin of a polycarboxylic acid resin. The at least one capping functional group is selected from the group consisting of a short chain ether group, an alkoxy group, or an aryloxy group. Also disclosed are an additive-resin admixture, a method of treating a wood product, and a wood product.
Barker, Andrew T. Cai Xiaochuan
2010-02-01
We introduce and study numerically a scalable parallel finite element solver for the simulation of blood flow in compliant arteries. The incompressible Navier-Stokes equations are used to model the fluid and coupled to an incompressible linear elastic model for the blood vessel walls. Our method features an unstructured dynamic mesh capable of modeling complicated geometries, an arbitrary Lagrangian-Eulerian framework that allows for large displacements of the moving fluid domain, monolithic coupling between the fluid and structure equations, and fully implicit time discretization. Simulations based on blood vessel geometries derived from patient-specific clinical data are performed on large supercomputers using scalable Newton-Krylov algorithms preconditioned with an overlapping restricted additive Schwarz method that preconditions the entire fluid-structure system together. The algorithm is shown to be robust and scalable for a variety of physical parameters, scaling to hundreds of processors and millions of unknowns.
Doyle, Michael P; Kundu, Kousik; Russell, Albert E
2005-11-10
[reaction: see text] Methyl 3-(trialkylsilanyloxy)-2-diazo-3-butenoate undergoes Lewis acid-catalyzed Mukaiyama aldol addition with aromatic and aliphatic aldehydes in the presence of low catalytic amounts of Lewis acids in nearly quantitative yields. Scandium(III) triflate is the preferred catalyst and, notably, addition proceeds without decomposition of the diazo moiety. Diazoacetoacetate products from reactions with aromatic aldehydes undergo rhodium(II)-catalyzed ring closure to cyclobutanones with high diastereocontrol. Examples of complimentary Mannich-type addition reactions with imines are reported. PMID:16268530
NASA Astrophysics Data System (ADS)
Rubel, Aleksey S.; Lukin, Vladimir V.; Egiazarian, Karen O.
2015-03-01
Results of denoising based on discrete cosine transform for a wide class of images corrupted by additive noise are obtained. Three types of noise are analyzed: additive white Gaussian noise and additive spatially correlated Gaussian noise with middle and high correlation levels. TID2013 image database and some additional images are taken as test images. Conventional DCT filter and BM3D are used as denoising techniques. Denoising efficiency is described by PSNR and PSNR-HVS-M metrics. Within hard-thresholding denoising mechanism, DCT-spectrum coefficient statistics are used to characterize images and, subsequently, denoising efficiency for them. Results of denoising efficiency are fitted for such statistics and efficient approximations are obtained. It is shown that the obtained approximations provide high accuracy of prediction of denoising efficiency.
ERIC Educational Resources Information Center
Emms, Laila; Gardner, Hilary
2010-01-01
The primary purpose of this study was to establish whether contrasting teaching methods had an effect on performance accuracy in the recall of graphic symbols. The secondary purpose was to establish whether the iconicity of symbols had an effect on performance accuracy. A direct symbol-teaching method and a contextual symbol-teaching method were…
Fixed-ratio ray designs have been used for detecting and characterizing interactions of large numbers of chemicals in combination. Single chemical dose-response data are used to predict an “additivity curve” along an environmentally relevant ray. A “mixture curve” is estimated fr...
Shigyo, M; Wako, T; Kojima, A; Yamauchi, N; Tashiro, Y
2003-12-01
Selfed progeny of a complete set of Allium fistulosum - Allium cepa monosomic addition lines (2n = 2x + 1 = 17, FF+1A-FF+8A) were produced to examine the transmission rates of respective alien chromosomes. All eight types of the selfed monosomic additions set germinable seeds. The numbers of chromosomes (2n) in the seedlings were 16, 17, or 18. The eight extra chromosomes varied in transmission rate (%) from 9 (FF+2A) to 49 (FF+8A). The complete set of monosomic additions was reproduced successfully by self-pollination. A reliable way to maintain a set of Allium monosomic additions was developed using a combination of two crossing methods, selfing and female transmission. FF+8A produced two seedlings with 18 chromosomes. Cytogenetical analyses, including GISH, showed that the seedlings were disomic addition plants carrying two entire homologous chromosomes from A. cepa in an integral diploid background of A. fistulosum. Flow cytometry analysis showed that a double dose of the alien 8A chromosome caused fluorescence intensity values spurring in DNA content, and isozyme analysis showed increased glutamate dehydrogenase activity at the gene locus Gdh-1. PMID:14663528
The Effects of Ba-Additive on Growth of a-Plane GaN Single Crystals Using Na Flux Method
NASA Astrophysics Data System (ADS)
Masumoto, Keiko; Someno, Tatsuya; Murakami, Kosuke; Imabayashi, Hiroki; Takazawa, Hideo; Todoroki, Yuma; Matsuo, Daisuke; Kitamoto, Akira; Maruyama, Mihoko; Imade, Mamoru; Yoshimura, Masashi; Kitaoka, Yasuo; Sasaki, Takatomo; Mori, Yusuke
2012-04-01
Large-area nonpolar GaN substrates with high crystallinity are necessary to improve the performance of GaN devices. Nonpolar GaN substrates of 2-in. diameter have been commercially fabricated by growing along the nonpolar direction on heterogeneous substrates. However, the crystallinity of the nonpolar GaN substrates requires improvement. Here, we grew a-plane GaN crystals using the Na flux method and investigated the effects of a Ba-additive on surface morphology and crystallinity. We found that the crystallinity of the crystals grown by the Na flux method was greatly improved compared with that of seed substrates. Moreover, the use of the Ba-additive suppressed the formation of voids that occurred during the Na flux growth without the Ba-additive. As a result, a-plane GaN crystals with high crystallinity were produced using the Na flux method with the Ba-additive.
Abberger, T
2001-12-01
The aim of the study was to investigate melt granulation in a laboratory scale fluid-bed granulator with respect to granule growth, granule properties and resulting tablet properties. The parameters investigated were method of addition of PEG (spray-on or addition as flakes), binder concentration, PEG type (3000, 4000 and 6000, sprayed-on), size (PEG 4000, added as three different sized flakes), powder type (two different sized lactose types and corn starch) and operating conditions (volume air flow and heating temperature). Addition of binder as flakes led to layering as a growth mechanism when the size of the flakes was high. Coalescence occurred when the size was low. Coalescence also occurred when spraying was the method of addition. Due to the greater viscosity of the PEG 6000 melt it produced bigger granules than 3000 or 4000. The influence of volume air flow was moderate and the influence of heating temperature in the range of 70-90 degrees C was very low with both methods of addition. The disintegration time of tablets from granules where PEG was added as flakes was shorter than from granules where PEG was sprayed-on. The latter method of binder addition led to tablets which did not disintegrate but eroded. This was apparently caused by formation of a binder matrix, which could not be destroyed by the disintegrant. PMID:11802658
Food additives are substances that become part of a food product when they are added during the processing or making of that food. "Direct" food additives are often added during processing to: Add nutrients ...
Spencer, Michael
1974-01-01
Food additives are discussed from the food technology point of view. The reasons for their use are summarized: (1) to protect food from chemical and microbiological attack; (2) to even out seasonal supplies; (3) to improve their eating quality; (4) to improve their nutritional value. The various types of food additives are considered, e.g. colours, flavours, emulsifiers, bread and flour additives, preservatives, and nutritional additives. The paper concludes with consideration of those circumstances in which the use of additives is (a) justified and (b) unjustified. PMID:4467857
Griebel, M.
1994-12-31
In recent years, it has turned out that many modern iterative algorithms (multigrid schemes, multilevel preconditioners, domain decomposition methods etc.) for solving problems resulting from the discretization of PDEs can be interpreted as additive (Jacobi-like) or multiplicative (Gauss-Seidel-like) subspace correction methods. The key to their analysis is the study of certain metric properties of the underlying splitting of the discretization space V into a sum of subspaces V{sub j}, j = 1{hor_ellipsis}, J resp. of the variational problem on V into auxiliary problems on these subspaces. Here, the author proposes a modified approach to the abstract convergence theory of these additive and multiplicative Schwarz iterative methods, that makes the relation to traditional iteration methods more explicit. To this end he introduces the enlarged Hilbert space V = V{sub 0} x {hor_ellipsis} x V{sub j} which is nothing else but the usual construction of the Cartesian product of the Hilbert spaces V{sub j} and use it now in the discretization process. This results in an enlarged, semidefinite linear system to be solved instead of the usual definite system. Then, modern multilevel methods as well as domain decomposition methods simplify to just traditional (block-) iteration methods. Now, the convergence analysis can be carried out directly for these traditional iterations on the enlarged system, making convergence proofs of multilevel and domain decomposition methods more clear, or, at least, more classical. The terms that enter the convergence proofs are exactly the ones of the classical iterative methods. It remains to estimate them properly. The convergence proof itself follow basically line by line the old proofs of the respective traditional iterative methods. Additionally, new multilevel/domain decomposition methods are constructed straightforwardly by now applying just other old and well known traditional iterative methods to the enlarged system.
Tada, Yuya; Grossart, Hans-Peter
2014-02-01
In aquatic environments, community dynamics of bacteria, especially actively growing bacteria (AGB), are tightly linked with dissolved organic matter (DOM) quantity and quality. We analyzed the community dynamics of DNA-synthesizing and accordingly AGB by linking an improved bromodeoxyuridine immunocytochemistry approach with fluorescence-activated cell sorting (BrdU-FACS). FACS-sorted cells of even oligotrophic ecosystems in winter were characterized by 16S rRNA gene analysis. In incubation experiments, we examined community shifts of AGB in response to the addition of N-acetyl-glucosamine (NAG), one of the most abundant aminosugars in aquatic systems. Our improved BrdU-FACS analysis revealed that AGB winter communities of oligotrophic Lake Stechlin (northeastern Germany) substantially differ from those of total bacteria and consist of Alpha-, Beta-, Gamma-, Deltaproteobacteria, Actinobacteria, Candidatus OP10 and Chloroflexi. AGB populations with different BrdU-fluorescence intensities and cell sizes represented different phylotypes suggesting that single-cell growth potential varies at the taxon level. NAG incubation experiments demonstrated that a variety of widespread taxa related to Alpha-, Beta-, Gammaproteobacteria, Bacteroidetes, Actinobacteria, Firmicutes, Planctomycetes, Spirochaetes, Verrucomicrobia and Chloroflexi actively grow in the presence of NAG. The BrdU-FACS approach enables detailed phylogenetic studies of AGB and, thus, to identify those phylotypes which are potential key players in aquatic DOM cycling. PMID:23985742
Tada, Yuya; Grossart, Hans-Peter
2014-01-01
In aquatic environments, community dynamics of bacteria, especially actively growing bacteria (AGB), are tightly linked with dissolved organic matter (DOM) quantity and quality. We analyzed the community dynamics of DNA-synthesizing and accordingly AGB by linking an improved bromodeoxyuridine immunocytochemistry approach with fluorescence-activated cell sorting (BrdU-FACS). FACS-sorted cells of even oligotrophic ecosystems in winter were characterized by 16S rRNA gene analysis. In incubation experiments, we examined community shifts of AGB in response to the addition of N-acetyl-glucosamine (NAG), one of the most abundant aminosugars in aquatic systems. Our improved BrdU-FACS analysis revealed that AGB winter communities of oligotrophic Lake Stechlin (northeastern Germany) substantially differ from those of total bacteria and consist of Alpha-, Beta-, Gamma-, Deltaproteobacteria, Actinobacteria, Candidatus OP10 and Chloroflexi. AGB populations with different BrdU-fluorescence intensities and cell sizes represented different phylotypes suggesting that single-cell growth potential varies at the taxon level. NAG incubation experiments demonstrated that a variety of widespread taxa related to Alpha-, Beta-, Gammaproteobacteria, Bacteroidetes, Actinobacteria, Firmicutes, Planctomycetes, Spirochaetes, Verrucomicrobia and Chloroflexi actively grow in the presence of NAG. The BrdU-FACS approach enables detailed phylogenetic studies of AGB and, thus, to identify those phylotypes which are potential key players in aquatic DOM cycling. PMID:23985742
Di Giuseppe, Antonella M A; Giarretta, Nicola; Lippert, Martina; Severino, Valeria; Di Maro, Antimo
2015-02-15
In 2013, following the scandal of the presence of undeclared horse meat in various processed beef products across the Europe, several researches have been undertaken for the safety of consumer health. In this framework, an improved UPLC separation method has been developed to detect the presence of horse myoglobin in raw meat samples. The separation of both horse and beef myoglobins was achieved in only seven minutes. The methodology was improved by preparing mixtures with different composition percentages of horse and beef meat. By using myoglobin as marker, low amounts (0.50mg/0.50g, w/w; ∼0.1%) of horse meat can be detected and quantified in minced raw meat samples with high reproducibility and sensitivity, thus offering a valid alternative to conventional PCR techniques. PMID:25236222
Goud, D Raghavender; Pardasani, Deepak; Purohit, Ajay Kumar; Tak, Vijay; Dubey, Devendra Kumar
2015-07-01
Sulfur monochloride (S2Cl2) and sulfur dichloride (SCl2) are important precursors of the extremely toxic chemical warfare agent sulfur mustard and classified, respectively, into schedule 3.B.12 and 3.B.13 of the Chemical Weapons Convention (CWC). Hence, their detection and identification is of vital importance for verification of CWC. These chemicals are difficult to detect directly using chromatographic techniques as they decompose and do not elute. Until now, the use of gas chromatographic approaches to follow the derivatized sulfur chlorides is not reported in the literature. The electrophilic addition reaction of sulfur monochloride and sulfur dichloride toward 3-hexyne was explored for the development of a novel derivatization protocol, and the products were subjected to gas chromatography-mass spectrometric (GC-MS) analysis. Among various unsaturated reagents like alkenes and alkynes, symmetrical alkyne 3-hexyne was optimized to be the suitable derivatizing agent for these analytes. Acetonitrile was found to be the suitable solvent for the derivatization reaction. The sample preparation protocol for the identification of these analytes from hexane spiked with petrol matrix was also optimized. Liquid-liquid extraction followed by derivatization was employed for the identification of these analytes from petrol matrix. Under the established conditions, the detection and quantification limits are 2.6 μg/mL, 8.6 μg/mL for S2Cl2 and 2.3 μg/mL, 7.7 μg/mL for SCl2, respectively, in selected ion monitoring (SIM) mode. The calibration curve had a linear relationship with y = 0.022x - 0.331 and r(2) = 0.992 for the working range of 10 to 500 μg/mL for S2Cl2 and y = 0.007x - 0.064 and r(2) = 0.991 for the working range of 10 to 100 μg/mL for SCl2, respectively. The intraday RSDs were between 4.80 to 6.41%, 2.73 to 6.44% and interday RSDs were between 2.20 to 7.25% and 2.34 to 5.95% for S2Cl2 and SCl2, respectively. PMID:26054007
NASA Astrophysics Data System (ADS)
Tang, Jing-shi; Liu, Lin
2010-10-01
The perturbation caused by the oscillation of Earth's equator plane must be taken into account when working on the motion of satellite on a low Earth orbit (LEO) in the geocentric celestial coordinate system. Since 1960 s, an intermediate orbit coordinate system using true equator and mean equinox (TEME) is introduced. It effectively solves the problem and has been widely used in various applications till today. But this traditional reference frame is purely conceptual and has always been a headache when performing the transition between these systems especially for those who are unfamiliar with celestial frames. As proved in a previous paper, it is possible to avoid the intermediate TEME frame, and conversions between osculating elements and mean elements can be completed in a consistent geocentric celestial coordinate system where only short-period terms are required. In this paper, after including the improved secular and long-period terms, the quasi-mean-element-method is available to predict the orbit analytically, reaching the accuracy of 10 -6 in Earth's radius. And all these can be done in the same celestial frame. The results suggest that the celestial coordinate system (J2000.0 nowadays) can be used throughout any applications without having to introduce TEME system as intermediate frame any more.
Simplified approaches to some nonoverlapping domain decomposition methods
Xu, Jinchao
1996-12-31
An attempt will be made in this talk to present various domain decomposition methods in a way that is intuitively clear and technically coherent and concise. The basic framework used for analysis is the {open_quotes}parallel subspace correction{close_quotes} or {open_quotes}additive Schwarz{close_quotes} method, and other simple technical tools include {open_quotes}local-global{close_quotes} and {open_quotes}global-local{close_quotes} techniques, the formal one is for constructing subspace preconditioner based on a preconditioner on the whole space whereas the later one for constructing preconditioner on the whole space based on a subspace preconditioner. The domain decomposition methods discussed in this talk fall into two major categories: one, based on local Dirichlet problems, is related to the {open_quotes}substructuring method{close_quotes} and the other, based on local Neumann problems, is related to the {open_quotes}Neumann-Neumann method{close_quotes} and {open_quotes}balancing method{close_quotes}. All these methods will be presented in a systematic and coherent manner and the analysis for both two and three dimensional cases are carried out simultaneously. In particular, some intimate relationship between these algorithms are observed and some new variants of the algorithms are obtained.
ERIC Educational Resources Information Center
Soydan, Sema; Quadir, Seher Ersoy
2013-01-01
Principal aim of this study is to show the effectiveness of the program prepared by researchers in order to enable 6 year-old children attending pre-school educational institutions to effectively gain addition subtraction skills through a drama-related method. The work group in the research comprised of 80 kids who continued their education in…
NASA Astrophysics Data System (ADS)
Al Okab, Riyad Ahmed
2013-02-01
Green analytical methods using Cisapride (CPE) as green analytical reagent was investigated in this work. Rapid, simple, and sensitive spectrophotometric methods for the determination of bromate in water sample, bread and flour additives were developed. The proposed methods based on the oxidative coupling between phenoxazine and Cisapride in the presence of bromate to form red colored product with max at 520 nm. Phenoxazine and Cisapride and its reaction products were found to be environmentally friendly under the optimum experimental condition. The method obeys beers law in concentration range 0.11-4.00 g ml-1 and molar absorptivity 1.41 × 104 L mol-1 cm-1. All variables have been optimized and the presented reaction sequences were applied to the analysis of bromate in water, bread and flour additive samples. The performance of these method was evaluated in terms of Student's t-test and variance ratio F-test to find out the significance of proposed methods over the reference method. The combination of pharmaceutical drugs reagents with low concentration create some unique green chemical analyses.
Al Okab, Riyad Ahmed
2013-02-15
Green analytical methods using Cisapride (CPE) as green analytical reagent was investigated in this work. Rapid, simple, and sensitive spectrophotometric methods for the determination of bromate in water sample, bread and flour additives were developed. The proposed methods based on the oxidative coupling between phenoxazine and Cisapride in the presence of bromate to form red colored product with max at 520 nm. Phenoxazine and Cisapride and its reaction products were found to be environmentally friendly under the optimum experimental condition. The method obeys beers law in concentration range 0.11-4.00 g ml(-1) and molar absorptivity 1.41 × 10(4) L mol(-1)cm(-1). All variables have been optimized and the presented reaction sequences were applied to the analysis of bromate in water, bread and flour additive samples. The performance of these method was evaluated in terms of Student's t-test and variance ratio F-test to find out the significance of proposed methods over the reference method. The combination of pharmaceutical drugs reagents with low concentration create some unique green chemical analyses. PMID:23261631
Berglund, F
1978-01-01
The use of additives to food fulfils many purposes, as shown by the index issued by the Codex Committee on Food Additives: Acids, bases and salts; Preservatives, Antioxidants and antioxidant synergists; Anticaking agents; Colours; Emulfifiers; Thickening agents; Flour-treatment agents; Extraction solvents; Carrier solvents; Flavours (synthetic); Flavour enhancers; Non-nutritive sweeteners; Processing aids; Enzyme preparations. Many additives occur naturally in foods, but this does not exclude toxicity at higher levels. Some food additives are nutrients, or even essential nutritents, e.g. NaCl. Examples are known of food additives causing toxicity in man even when used according to regulations, e.g. cobalt in beer. In other instances, poisoning has been due to carry-over, e.g. by nitrate in cheese whey - when used for artificial feed for infants. Poisonings also occur as the result of the permitted substance being added at too high levels, by accident or carelessness, e.g. nitrite in fish. Finally, there are examples of hypersensitivity to food additives, e.g. to tartrazine and other food colours. The toxicological evaluation, based on animal feeding studies, may be complicated by impurities, e.g. orthotoluene-sulfonamide in saccharin; by transformation or disappearance of the additive in food processing in storage, e.g. bisulfite in raisins; by reaction products with food constituents, e.g. formation of ethylurethane from diethyl pyrocarbonate; by metabolic transformation products, e.g. formation in the gut of cyclohexylamine from cyclamate. Metabolic end products may differ in experimental animals and in man: guanylic acid and inosinic acid are metabolized to allantoin in the rat but to uric acid in man. The magnitude of the safety margin in man of the Acceptable Daily Intake (ADI) is not identical to the "safety factor" used when calculating the ADI. The symptoms of Chinese Restaurant Syndrome, although not hazardous, furthermore illustrate that the whole ADI
NASA Astrophysics Data System (ADS)
John, Christopher; Spura, Thomas; Habershon, Scott; Kühne, Thomas D.
2016-04-01
We present a simple and accurate computational method which facilitates ab initio path-integral molecular dynamics simulations, where the quantum-mechanical nature of the nuclei is explicitly taken into account, at essentially no additional computational cost in comparison to the corresponding calculation using classical nuclei. The predictive power of the proposed quantum ring-polymer contraction method is demonstrated by computing various static and dynamic properties of liquid water at ambient conditions using density functional theory. This development will enable routine inclusion of nuclear quantum effects in ab initio molecular dynamics simulations of condensed-phase systems.
Doytchinova, Irini A; Blythe, Martin J; Flower, Darren R
2002-01-01
A method has been developed for prediction of binding affinities between proteins and peptides. We exemplify the method through its application to binding predictions of peptides with affinity to major histocompatibility complex class I molecule HLA-A*0201. The method is named "additive" because it is based on the assumption that the binding affinity of a peptide could be presented as a sum of the contributions of the amino acids at each position and the interactions between them. The amino acid contributions and the contributions of the interactions between adjacent side chains and every second side chain were derived using a partial least squares (PLS) statistical methodology using a training set of 420 experimental IC50 values. The predictive power of the method was assessed using rigorous cross-validation and using an independent test set of 89 peptides. The mean value of the residuals between the experimental and predicted pIC50 values was 0.508 for this test set. The additive method was implemented in a program for rapid T-cell epitope search. It is universal and can be applied to any peptide-protein interaction where binding data is known. PMID:12645903
Rudolf Keller
2004-08-10
In this project, a concept to improve the performance of aluminum production cells by introducing potlining additives was examined and tested. Boron oxide was added to cathode blocks, and titanium was dissolved in the metal pool; this resulted in the formation of titanium diboride and caused the molten aluminum to wet the carbonaceous cathode surface. Such wetting reportedly leads to operational improvements and extended cell life. In addition, boron oxide suppresses cyanide formation. This final report presents and discusses the results of this project. Substantial economic benefits for the practical implementation of the technology are projected, especially for modern cells with graphitized blocks. For example, with an energy savings of about 5% and an increase in pot life from 1500 to 2500 days, a cost savings of $ 0.023 per pound of aluminum produced is projected for a 200 kA pot.
NASA Astrophysics Data System (ADS)
Ren, Cong; Liu, Tong; Maturavongsadit, Panita; Luckanagul, Jittima Amie; Chen, Fanglin
2015-04-01
Anode-supported micro-tubular solid oxide fuel cells (MT-SOFCs) have been fabricated by phase inversion method. For the anode support preparation, N-methyl-2-pyrrolidone (NMP), polyethersulfone (PESf) and poly ethylene glycol (PEG) were applied as solvent, polymer binder and additive, respectively. The effect of molecular weight and amount of PEG additive on the thermodynamics of the casting solutions was characterized by measuring the coagulation value. Viscosity of the casting slurries was also measured and the influence of PEG additive on viscosity was studied and discussed. The presence of PEG in the casting slurry can significantly influence the final anode support microstructure. Based on the microstructure result and the measured gas permeation value, two anode supports were selected for cell fabrication. For cell with the anode support fabricated using slurry with PEG additive, a maximum cell power density of 704 mW cm-2 is obtained at 750 °C with humidified hydrogen as fuel and ambient air as oxidant; cell fabricated without any PEG additive shows the peak cell power density of 331 mW cm-2. The relationship between anode microstructure and cell performance was discussed.
Hou, Yu-Lan; Wu, Shuang; Wang, Hua; Zhao, Yong; Liao, Peng; Tian, Qing-Qing; Sun, Wen-Jian; Chen, Bo
2013-01-01
A novel rapid method for detection of the illicit beta2-agonist additives in health foods and traditional Chinese patent medicines was developed with the desorption corona beam ionization mass spectrometry (DCBI-MS) technique. The DCBI conditions including temperature and sample volume were optimized according to the resulting mass spectra intensity. Matrix effect on 9 beta2-agonists additives was not significant in the proposed rapid determination procedure. All of the 9 target molecules were detected within 1 min. Quantification was achieved based on the typical fragment ion in MS2 spectra of each analyte. The method showed good linear coefficients in the range of 1-100 mg x L(-1) for all analytes. The relative deviation values were between 14.29% and 25.13%. Ten claimed antitussive and antiasthmatic health foods and traditional Chinese patent medicines from local pharmacies were analyzed. All of them were negative with the proposed DCBI-MS method. Without tedious sample pretreatments, the developed DCBI-MS is simple, rapid and sensitive for rapid qualification and semi-quantification of the illicit beta2-agonist additives in health foods and traditional Chinese patent medicines. PMID:23600151
Yang Kai; Huang, Shih-Ying; Packard, Nathan J.; Boone, John M.
2010-07-15
Purpose: A simplified linear model approach was proposed to accurately model the response of a flat panel detector used for breast CT (bCT). Methods: Individual detector pixel mean and variance were measured from bCT projection images acquired both in air and with a polyethylene cylinder, with the detector operating in both fixed low gain and dynamic gain mode. Once the coefficients of the linear model are determined, the fractional additive noise can be used as a quantitative metric to evaluate the system's efficiency in utilizing x-ray photons, including the performance of different gain modes of the detector. Results: Fractional additive noise increases as the object thickness increases or as the radiation dose to the detector decreases. For bCT scan techniques on the UC Davis prototype scanner (80 kVp, 500 views total, 30 frames/s), in the low gain mode, additive noise contributes 21% of the total pixel noise variance for a 10 cm object and 44% for a 17 cm object. With the dynamic gain mode, additive noise only represents approximately 2.6% of the total pixel noise variance for a 10 cm object and 7.3% for a 17 cm object. Conclusions: The existence of the signal-independent additive noise is the primary cause for a quadratic relationship between bCT noise variance and the inverse of radiation dose at the detector. With the knowledge of the additive noise contribution to experimentally acquired images, system modifications can be made to reduce the impact of additive noise and improve the quantum noise efficiency of the bCT system.
NASA Technical Reports Server (NTRS)
Edwards, P. J.; Huang, X.; Li, Y. Q. (Editor); Wang, Y. Z. (Editor)
1996-01-01
We briefly review quantum mechanical and semi-classical descriptions of experiments which demonstrate the macroscopic violation of the three Cauchy-Schwarz inequalities: g(sup 2)(sub 11)(0) greater than or equal to 1; g(sup 2)(sub 11)(0) greater than or equal to g(sup 2)(sub 11)(t), (t approaches infinity); (the absolute value of g(sup 2)(sub 11)(0))(exp 2) less than or equal to g(sup 2)(sub 11)(0) g(sup 2)(sub 11)(0). Our measurements demonstrate the violation, at macroscopic intensities, of each of these inequalities. We show that their violation, although weak, can be demonstrated through photodetector current covariance measurements on correlated sub-Poissonian Poissonian, and super Poissonian light beams. Such beams are readily generated by a tandem array of infrared-emitting semiconductor junction diodes. Our measurements utilize an electrically coupled array of one or more infrared-emitting diodes, optically coupled to a detector array. The emitting array is operated in such a way as to generate highly correlated beams of variable photon Fano Factor. Because the measurements are made on time scales long compared with the first order coherence time and with detector areas large compared with the corresponding coherence areas, first order interference effects are negligible. The first and second inequalities are violated, as expected, when a sub-Poissonian light beam is split and the intensity fluctuations of the two split beams are measured by two photodetectors and subsequently cross-correlated. The third inequality is violated by bunched (as well as anti-bunched) beams of equal intensity provided the measured cross correlation coefficient exceeds (F - 1)/F, where F is the measured Fano Factor of each beam. We also investigate the violation for the case of unequal beams.
NASA Astrophysics Data System (ADS)
Issa, Mahmoud Mohamed; Nejem, R.'afat Mahmoud; Shanab, Alaa Mohamed Abu; Shaat, Nahed Talab
2013-10-01
Simple, reliable, and sensitive kinetic spectrophotometric method has been developed for the simultaneous determination of diloxanide furoate and metronidazole using H-point standard addition method (HPSAM). The method is based on the oxidation rate difference of diloxanide and metronidazole by potassium permanganate in basic medium. A green color has been developed and measured at 610 nm. Different experimental parameters were carefully optimized. The limiting logarithmic and the initial-rate methods were adopted for the construction of the calibration curve of each individual reaction with potassium permanganate. Under the optimum conditions, Beer's law was obeyed in the range of 1.0-20.0 and 5.0-25.0 μg ml-1 for diloxanide furoate and metronidazole, respectively. The detection limits were 0.22 μg ml-1 for diloxanide furoate and 0.83 μg ml-1 for metronidazole. Correlation coefficients of the regression equations were greater than 0.9970 in all cases. The precision of the method was satisfactory; the maximum value of relative standard deviation did not exceed 1.06% (n = 5). The accuracy, expressed as recovery was between 99.4% and 101.4% with relative error of 0.12 and 0.14 for diloxanide furoate and metronidazole, respectively. The proposed method was successfully applied for the simultaneous determination of both drugs in pharmaceutical dosage forms and human urine samples and compared with alternative HPLC method.
Suebsing, Rungkarn; Kampeera, Jantana; Sirithammajak, Sarawut; Withyachumnarnkul, Boonsirm; Turner, Warren; Kiatpathomchai, Wansika
2015-03-01
Flavobacterium columnare, the causative agent of columnaris disease in fish, affects many economically important freshwater fish species. A colorimetric method of loop-mediated isothermal amplification with the pre-addition of calcein (LAMP-calcein) was developed and used to detect the presence of F. columnare in farmed tilapia (Nile Tilapia Oreochromis niloticus and red tilapia [Nile Tilapia × Mozambique Tilapia O. mossambicus]) and rearing water. The detection method, based on a change in color from orange to green, could be performed within 45 min at 63°C. The method was highly specific, as it had no cross-detections with 14 other bacterial species, including other fish pathogens and two Flavobacterium species. The method has a minimum detection limit of 2.2 × 10(2) F. columnare CFU; thus, it is about 10 times more sensitive than conventional PCR. With this method, F. columnare was detected in gonad, gill, and blood samples from apparently healthy tilapia broodstock as well as in samples of fertilized eggs, newly hatched fry, and rearing water. The bacteria isolated from the blood were further characterized biochemically and found to be phenotypically identical to F. columnare. The amplified products from the LAMP-calcein method had 97% homology with the DNA sequence of F. columnare. PMID:25584663
Heriyanto, Heri; Widya Ernayati, K.; Umam, Chairul; Margareta, Nita
2015-12-29
UBC (upgrading brown coal) is a method of improving the quality of coal by using oil as an additive. Through processing in the oil media, not just the calories that increase, but there is also water repellent properties and a decrease in the tendency of spontaneous combustion of coal products produced. The results showed a decrease in the water levels of natural coal bayah reached 69%, increase in calorific value reached 21.2%. Increased caloric value and reduced water content caused by the water molecules on replacing seal the pores of coal by oil and atoms C on the oil that is bound to increase the percentage of coal carbon. As a result of this experiment is, the produced coal has better calorific value, the increasing of this new calorific value up to 23.8% with the additive waste lubricant, and the moisture content reduced up to 69.45%.
Joo, S.K.; Lee, S.W.; Ihn, T.H. . Dept. of Metallurgy)
1994-08-01
A new process, fluidized bed reduction (FBR) method, was applied for fabrication of uniform W-Cu sintered material. Liquid-phase sintering was carried out to obtain fully densified W-Cu composite, and the effect of cobalt addition on the sintering behavior was investigated. It was found that fully densified material could not be obtained even after sintering at 1,200 C for 4 hours in the case of 75W-25Cu, while more than 96 pct density could be obtained as soon as the sintering temperature reached 1,200 C when 0.5 wt pct cobalt was added prior to the sintering. It has been found that the wetting angle of the liquid copper is reduced significantly by the addition of cobalt, and the formation reaction of Co[sub 7]W[sub 6] intermetallic compound at the surface of the tungsten powder is mainly responsible for the enhancement of the densification process.
NASA Astrophysics Data System (ADS)
Joo, Seung-Ki; Lee, Seok-Woon; Ihn, Tae-Hyoung
1994-08-01
A new process, fluidized bed reduction (FBR) method, was applied for fabrication of uniform W-Cu sintered material. Liquid-phase sintering was carried out to obtain fully densified W-Cu composite, and the effect of cobalt addition on the sintering behavior was investigated. It was found that fully densified material could not be obtained even after sintering at 1200 °C for 4 hours in the case of 75W-25Cu, while more than 96 pct density could be obtained as soon as the sintering temperature reached 1200 °C when 0.5 wt pct cobalt was added prior to the sintering. It has been found that the wetting angle of the liquid copper is reduced significantly by the addition of cobalt, and the formation reaction of Co7W6 intermetallic compound at the surface of the tungsten powder is mainly responsible for the enhancement of the densification process.
NASA Astrophysics Data System (ADS)
Adli, Nisrin; Razak, Nurul Razliana Abdul; Saud, Norainiza
2016-07-01
Due to the toxicity of lead (Pb), the exploration of another possibility for lead-free solder is necessary. Nowadays, SnCu alloys are being established as one of the lead-free solder alternatives. In this study, Sn-0.7Cu lead-free solder with an addition of 1wt% and 5wt% Al were investigated by using powder metallurgy method. The effect of Al addition on the wettability and intermetallic compound thickness (IMC) of Sn-0.7Cu-Al lead-free solder were appraised. Results showed that Al having a high potential to enhance Sn-0.7Cu lead-free solder due to its good wetting and reduction of IMC thickness. The contact angle and IMC of the Sn-0.7Cu-Al lead-free solder were decreased by 14.32% and 40% as the Al content increased from 1 wt% to 5 wt%.
Zhu, Yonghong; Li, Genrong; Duan, Yunpeng; Chen, Shiqi; Zhang, Chun; Li, Yanfei
2008-08-15
A gas chromatography electron capture detector (GC-ECD) using the standard addition method was developed for the determination of acrylamide in heat-processed foods. The method entails extraction of acrylamide with water, filtration, defatting with n-hexane, derivatization with hydrobromic acid and saturated bromine-water, and liquid-liquid extraction with ethyl acetate. The sample pretreatment required no SPE clean-up and concentration steps prior to injection. The final extract was analyzed by GC-ECD. The chromatographic analysis was performed on polar columns, e.g. Supelcowax-10 capillary column, and good retention and peak response of the analyte were achieved under the optimal conditions. The qualification of the analyte was by identifying the peak with same retention time as standard compound 2,3-DBPA and confirmed by GC-MS. GC-MS analysis confirmed that 2,3-DBPA was converted to 2-BPA nearly completely on the polar capillary column, whether or not treated with triethylamine. A four-point standard addition protocol was used to quantify acrylamide in food samples. The limit of detection (LOD) was estimated to be 0.6μg/kg on the basis of ECD technique. Validation and quantification results demonstrated that the method should be regarded as a low-cost, convenient, and reliable alternative for conventional investigation of acrylamide. PMID:26050006
Santos, Inês C; Mesquita, Raquel B R; Bordalo, Adriano A; Rangel, António O S S
2015-02-01
The present work describes the development of a sequential injection standard addition method for iodine speciation in bathing waters and seaweeds extracts without prior sample treatment. Iodine speciation was obtained by assessing the iodide and iodate content, the two inorganic forms of iodine in waters. For the determination of iodide, an iodide ion selective electrode (ISE) was used. The indirect determination of iodate was based on the spectrophotometric determination of nitrite (Griess reaction). For the iodate measurement, a mixing chamber was employed (flow batch approach) to explore the inherent efficient mixing, essential for the indirect determination of iodate. The application of the standard addition method enabled detection limits of 0.14 µM for iodide and 0.02 µM for iodate, together with the direct introduction of the target water samples, coastal and inland bathing waters. The results obtained were in agreement with those obtained by ICP-MS and a colorimetric reference procedure. Recovery tests also confirmed the accuracy of the developed method which was effectively applied to bathing waters and seaweed extracts. PMID:25435219
Afkhami, Abbas; Bahram, Morteza
2004-01-01
A very simple and selective spectrophotometric method for simultaneous determination of Co(II) and Ni(II) by 1-(2-pyridylazo) 2-naphthol (PAN), in micellar media, using H-point standard addition method (HPSAM) is described. The ligand and its metal complexes (Co(II)-PAN and Ni(II)-PAN) were made water-soluble by the neutral surfactant Triton X-100, and therefore, no extraction with organic solvents was required. Formation of both the complexes was complete within 10 min at pH 9 (adjusted by ammonia buffer). The linear range was 0.10-2.00 microg ml(-1) for Co(II) and 0.05-1.50 microg ml(-1) for Ni(II). The relative standard deviation (R.S.D.) for the simultaneous determination of 0.50 microg ml(-1) each of Co(II) and Ni(II) was 2.32 and 3.13%, respectively. Interference effects of common anions and cations were studied and the method was applied to simultaneous determination of Co(II) and Ni(II) in alloy samples. The method was compared with derivative spectrophotometric method. PMID:14670476
Lasekan, Adeseye O; Nayak, Balunkeswar
2016-06-01
This study examines the potential of two buffer additives (Tween 20 and DTT) to improve the solubility of proteins from shrimp subjected to different heat treatments and the allergenicity of tropomyosin in the extracts. The concentration of soluble proteins extracted by all the buffers from processed shrimp was significantly reduced compared with untreated samples. The concentration of total soluble proteins from heat treated shrimp increased significantly when phosphate buffer containing both surfactant and reducing agent was used as the extraction buffer. However, the concentrations of heat-stable proteins in the buffers were mostly similar. The electrophoretic profile of extracted proteins showed that tropomyosin is very stable under the different heat treatment methods used in this study except for high pressure steaming where the intensity of tropomyosin band was reduced. Competitive inhibition ELISA showed that high pressure steaming reduced the allergenicity of tropomyosin compared with other heat treatments methods. PMID:26830572
Christopher, Steven J; Kilpatrick, Eric L; Yu, Lee L; Davis, W Clay; Adair, Blakely M
2012-01-15
NIST has performed preliminary research on applying a calibration methodology based on the method of standard additions to the quantification of peptides via reverse-phase liquid chromatography coupled to inductively coupled plasma mass spectrometry (RPLC-ICP-MS). A microwave-assisted lanthanide labeling procedure was developed and applied to derivatize peptides using the macrocyclic bifunctional chemical chelator DOTA (1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid), which significantly improved the lanthanide labeling yield and reduced reaction times compared to benchtop labeling procedures. Biomolecular MS technologies of matrix-assisted laser desorption ionization (MALDI)-MS and electrospray ionization (ESI)-MS/MS were used in concert with ICP-MS to confirm the results of microwave labeling, sample cleanup and standard additions experiments for several test peptides. The calibration scheme is outlined in detail and contextualized against complementary high accuracy calibration strategies currently employed for ICP-MS detection of biomolecules. Standard additions experiments using native, non-isotopic peptide calibrants confirm the simplicity of the scheme and the potential of applying a blending (recombined sample and spike) procedure, facilitating calibration via co-elution of lanthanide labeled peptides. Ways to improve and fully leverage the analytical methodology are highlighted. PMID:22265570
Zheng, Mingtao; Liu, Yingliang; Xiao, Yong; Dong, Hanwu; Feng, Haobin; Zhang, Haoran; Lei, Bingfu
2013-12-11
Mesocrystals are of great importance owing to their novel hierarchical microstructures and potential applications. In the present work, a simple additive-free method has been developed for the controllable synthesis of manganese monoxide (MnO) mesocrystals, in which cheap manganese acetate (Mn(Ac)2) and ethanol were used as raw materials without involving any other expensive additives such as surfactants, polyelectrolyte, or polymers. The particle size of the resulting MnO mesocrystals is tunable in the range 400-1500 nm by simply altering the concentration of Mn(Ac)2 in ethanol. The percentage yield of the octahedral MnO mesocrystals is about 38 wt % with respect to the starting Mn(Ac)2. The selective adsorption of oligomers, which was resulted from the polymerization of ethanol, acted as an important role for the mesocrystal formation. A mechanism involving the oriented aggregation of MnO nanoparticle subunits and the subsequent ripening process was proposed. Moreover, for the first time, the as-synthesized MnO mesocrystals were employed as a novel template to fabricate functional materials with an octahedral morphology including MnO@C core/shells, carbon, and graphitic hollow octahedrons. This method shows the importance of mesocrystals not only for the field of material research but also for the application in functional materials synthesis. PMID:24274735
NASA Astrophysics Data System (ADS)
Chen, Z.; Jones, C. M.
2002-05-01
Microchemistry of fish otoliths (fish ear bones) is a very useful tool for monitoring aquatic environments and fish migration. However, determination of the elemental composition in fish otolith by ICP-MS has been limited to either analysis of dissolved sample solution or measurement of limited number of trace elements by laser ablation (LA)- ICP-MS due to low sensitivity, lack of available calibration standards, and complexity of polyatomic molecular interference. In this study, a method was developed for in situ determination of trace elements in fish otoliths by laser ablation double focusing sector field ultra high sensitivity Finnigan Element 2 ICP-MS using a solution standard addition calibration method. Due to the lack of matrix-match solid calibration standards, sixteen trace elements (Na, Mg, P, Cr, Mn, Fe, Ni, Cu, Rb, Sr, Y, Cd, La, Ba, Pb and U) were determined using a solution standard calibration with Ca as an internal standard. Flexibility, easy preparation and stable signals are the advantages of using solution calibration standards. In order to resolve polyatomic molecular interferences, medium resolution (M/delta M > 4000) was used for some elements (Na, Mg, P, Cr, Mn, Fe, Ni, and Cu). Both external calibration and standard addition quantification strategies are compared and discussed. Precision, accuracy, and limits of detection are presented.
Liu, Fang; Ren, Dequan; Guo, De-an; Pan, Yifeng; Zhang, Huzhe; Hu, Ping
2008-03-01
In this paper, a new method for liquid chromatographic fingerprint of saponins in Gynostemma pentaphyllum (THUNB.) MAKINO was developed. The G. pentaphyllum powder was defatted by Soxhlet extraction with petroleum ether and then gypenosides were extracted from the residue with methanol by sonicating. Column chromatography with macro pore resin was then used to separate and enrich gypenosides. HPLC fingerprint analysis of gypenosides fraction was performed on a C18 column, with an isocratic elution of 34% acetonitrile for 60 min at 0.8 ml/min, sample injection volume was 20 microl and the wavelength was 203 nm. To cover the lack of standard compounds, the addition of an internal standard of ginsenoside Rb2 was employed in the gypenosides fingerprint profile. The relative retention time (RRT) and relative peak area (RPA) of the gypenosides peaks in the fingerprint were calculated by setting the ginsenoside Rb2 as the marker compound. The relative standard deviation (RSDs) of RRT of five common peaks vs. ginsenoside Rb2 in precision, repeatability and stability test were less than 1%, and the RSDs of RPA were less than 5%. The method validation data proved that the proposed method for the fingerprint with internal standard of G. pentaphyllum saponins is adequate, valid and applicable. Finally, three batches of crude drug samples collected from Shanxi province were tested by following the established method. PMID:18310956
Polyimide processing additives
NASA Technical Reports Server (NTRS)
Pratt, J. R.; St. Clair, T. L.; Burks, H. D.; Stoakley, D. M.
1987-01-01
A method has been found for enhancing the melt flow of thermoplastic polyimides during processing. A high molecular weight 422 copoly(amic acid) or copolyimide was fused with approximately 0.05 to 5 pct by weight of a low molecular weight amic acid or imide additive, and this melt was studied by capillary rheometry. Excellent flow and improved composite properties on graphite resulted from the addition of a PMDA-aniline additive to LARC-TPI. Solution viscosity studies imply that amic acid additives temporarily lower molecular weight and, hence, enlarge the processing window. Thus, compositions containing the additive have a lower melt viscosity for a longer time than those unmodified.
Piatkowska, Marta; Jedziniak, Piotr; Zmudzki, Jan
2016-04-15
A multiclass method was developed for the simultaneous determination of 120 analytes in fresh eggs. The method covers the analytes from the groups of tetracyclines (6), fluoroquinolones (11), sulphonamides (17), nitroimidazoles (9), amphenicols (2), cephalosporins (7), penicillins (8), macrolides (8), benzimidazoles (20), coccidiostats (14), insecticides (3), dyes (12) and others (3). Samples were extracted using 0.1% formic acid in acetonitrile:water (8:2) with the addition of EDTA and cleaned using solid phase extraction with Hybrid SPE cartridges. The chromatographic separation was achieved on C8 column using mobile phase consisting of (A) methanol:acetonitrile (8:2) - (B) 0.1% formic acid in a gradient mode. Validation results according to the Commission Decision 2002/657/EC are as follows: linearity (r⩾0.99), recovery (75-108%), repeatability (CV 1.60-15.9%), reproducibility (CV 2.60-15%), decision limit (CCα 2.25-1156 μg/kg) and detection capability (CCβ 2.04-1316 μg/kg). The presented method was used for analysis of 150 real eggs samples taken from monitoring control program. PMID:26616990
Hasani, Masoumeh; Rezaei, Alireza; Abdollahi, Hamid
2007-11-01
The H-point standard addition method was applied to kinetic data for simultaneous determination of Fe(II) and Fe(III) or selective determination of Fe(II) in the presence of Fe(III). The method is based on the difference in the rate of complex formation between iron in two different oxidation states and methylthymol blue (MTB) at pH 3.5 in mixed cetyltrimethylammonium bromide (CTAB) and Triton X-100 micellar medium. Fe(II) can be determined in the range 0.25-2.5 microg ml(-1) with satisfactory accuracy and precision in the presence of excess Fe(III) and other metal ions that rapidly form complexes with MTB under working condition. The proposed method was successfully applied to the simultaneous determination of Fe(II) and Fe(III) or selective determination of Fe(II) in the presence of Fe(III) in spiked real environmental and synthetic samples with complex composition. PMID:17329160
NASA Astrophysics Data System (ADS)
Mendonça, E. C.; Tenório, Mayara A.; Mecena, S. G.; Zucolotto, B.; Silva, L. S.; Jesus, C. B. R.; Meneses, C. T.; Duque, J. G. S.
2015-12-01
In this work, the effect of addition of different chelating agents on the magnetic properties of cobalt ferrite nanoparticles produced by the combining of both co-precipitation and hydrothermal methods is reported. The Rietveld analyses of X-ray diffraction patterns reveal that our samples are single phase (space group: Fd-3m) with small average sizes. The weight losses observed in the thermogravimetric measurements together with the M×H curves show that the organic contamination coming from chelating agent decomposition can give rise to misinterpretation of the magnetization measurements. Besides, analyses of the zero-field-cooled (ZFC) and field-cooled (FC) magnetization measurements and the M×H curves measured at room temperature allows us to state that both the average blocking temperature and particles size distribution are sensitive to the kind of chelating agent.
Trost, Barry M.; Xie, Jia; Sieber, Joshua D.
2011-01-01
The Pd-catalyzed asymmetric allylic alkylation (AAA) is one of the most useful and versatile methods for asymmetric synthesis known in organometallic chemistry. Development of this reaction over the past 30 years has typically relied on the use of an allylic electrophile bearing an appropriate leaving group to access the reactive Pd(π-allyl) intermediate that goes on to the desired coupling product after attack by the nucleophile present in the reaction. Our group has been interested in developing alternative approaches to access the reactive Pd(π-allyl) intermediate that does not require the use of an activated electrophile, which ultimately generates a stoichiometric byproduct in the reaction that is derived from the leftover leaving group. Along these lines, we have demonstrated that allenes can be used to generate the reactive Pd(π-allyl) intermediate in the presence of an acid cocatalyst, and this system is compatible with nucleophiles to allow for formation of formal AAA products by Pd-catalyzed additions to allenes. This article describes our work regarding the use of oxindoles as carbon-based nucleophiles in a Pd-catalyzed asymmetric addition of oxindoles to allenes (Pd-catalyzed hydrocarbonation of allenes). By using the chiral standard Trost ligand (L1) and 3-aryloxindoles as nucleophiles, this hydrocarbonation reaction provides products with two vicinal stereocenters, with one being quaternary, in excellent chemo-, regio-, diastereo-, and enantioselectivities in high chemical yields. PMID:22070545
Cheng, Yung-Yi; Tsai, Tung-Hu
2016-06-01
Rhodamine B is an illegal and potentially carcinogenic food dye. The aim of this study was to develop a convenient, rapid, and sensitive UHPLC-MS/MS method for pharmacokinetic studies in rats. Rat plasma samples were deproteinized with acetonitrile and separated by UHPLC on a reverse-phase C18e column (100mm×2.1mm, 2μm) using a mobile phase consisting of methanol-5mM ammonium acetate (90:10, v/v). Detection was performed using a triple quadrupole tandem mass spectrometer in the selected reaction monitoring mode at [M](+) ion m/z 443.39→399.28 for rhodamine B and [M+H](+) ion m/z 253.17→238.02 for 5-methoxyflavone as the internal standard. This method was specific and produced linear results over a concentration range of 0.5-100ng/mL, with a lower limit of quantitation of 0.5ng/mL. All validation parameters, including the inter-day, intra-day, matrix effect, recovery, and stability in rat plasma, were acceptable according to the biological method validation guidelines developed by the FDA (2001). This method was successfully applied to a pharmacokinetic study in rats; oral administration of 1mg/kg of rhodamine B yielded a time to maximum concentration (Tmax) of 1.3±0.4h and an elimination half-life of 8.8±1.4h, with a clearance of 229.7±19.4mL/h/kg. These pharmacokinetic results provide a constructive contribution to our understanding of the absorption mechanism of rhodamine B and support additional food safety evaluations. PMID:27131149
Gao, Peng; Yi, Zonglin; Xing, Xiaochen; Ngai, To; Jin, Fan
2016-05-17
The assembly and manipulation of charged colloidal particles at oil/water interfaces represent active areas of fundamental and applied research. Previously, we have shown that colloidal particles can spontaneously generate unstable residual charges at the particle/oil interface when spreading solvent is used to disperse them at an oil/water interface. These residual charges in turn affect the long-ranged electrostatic repulsive forces and packing of particles at the interface. To further uncover the influence arising from the spreading solvents on interfacial particle interactions, in the present study we utilize pure buoyancy to drive the particles onto an oil/water interface and compare the differences between such a spontaneously adsorbed particle monolayer to the spread monolayer based on solvent spreading techniques. Our results show that the solvent-free method could also lead particles to spread well at the interface, but it does not result in violent sliding of particles along the interface. More importantly, this additive-free spreading method can avoid the formation of unstable residual charges at the particle/oil interface. These findings agree well with our previous hypothesis; namely, those unstable residual charges are triboelectric charges that arise from the violently rubbing of particles on oil at the interface. Therefore, if the spreading solvents could be avoided, then we would be able to get rid of the formation of residual charges at interfaces. This finding will provide insight for precisely controlling the interactions among colloidal particles trapped at fluid/fluid interfaces. PMID:27108987
A fast iterative method to compute the flow around a submerged body
Malmliden, J.F.; Petersson, N.A.
1996-07-01
The authors develop an efficient iterative method for computing steady linearized potential flow around a submerged body moving in a liquid of finite constant depth. In this paper they restrict the presentation to the two-dimensional problem, but the method is readily generalizable to the three-dimensional case, i.e., the flow in a canal. The problem is indefinite, which makes the convergence of most iterative methods unstable. To circumvent this difficulty, the authors decompose the problem into two more easily solvable subproblems and form a Schwarz-type iteration to solve the original problem. The first subproblem is definite and can therefore be solved by standard iterative methods. The second subproblem is indefinite but has no body. It is therefore easily and efficiently solvable by separation of variables. The authors prove that the iteration converges for sufficiently small Froude numbers. In addition, they present numerical results for a second-order accurate discretization of the problem. They demonstrate that the iterative method converges rapidly, and that the convergences rate improves when the Froude number decreases. They also verify numerically that the convergence rate is essentially independent of the grid size. 20 refs., 6 figs., 10 tabs.
De Zan, María M; Teglia, Carla M; Robles, Juan C; Goicoechea, Héctor C
2011-07-15
The development, optimization and validation of an ion-pairing high performance liquid chromatography method for the simultaneous determination of both nicarbazin (NIC) components: 4,4'-dinitrocarbanilide (DNC) and 2-hydroxy-4,6-dimethylpyrimidine (HDP) in bulk materials and feed additives are described. An experimental design was used for the optimization of the chromatographic system. Four variables, including mobile phase composition and oven temperature, were analyzed through a central composite design exploring their contribution to analyte separation. Five responses: peak resolutions, HDP capacity factor, HDP tailing and analysis time, were modelled by using the response surface methodology and were optimized simultaneously by implementing the desirability function. The optimum conditions resulted in a mobile phase consisting of 10.0 mmol L(-1) of 1-heptanesulfonate, 20.0 mmol L(-1) of sodium acetate, pH=3.30 buffer and acetonitrile in a gradient system at a flow rate of 1.00 mL min(-1). Column was an INERSTIL ODS-3 (4.6 mm×150 mm, 5 μm particle size) at 40.0°C. Detection was performed at 300 nm by a diode array detector. The validation results of the method indicated a high selectivity and good precision characteristics, with RSD less than 1.0% for both components, both in intra and inter-assay precision studies. Linearity was proved for a range of 32.0-50.0 μg mL(-1) of NIC in sample solution. The recovery, studied at three different fortification levels, varied from 98.0 to 101.4 for HDP and from 99.1 to 100.2 for DNC. The applicability of the method was demonstrated by determining DNC and HDP content in raw materials and commercial formulations used for coccidiosis prevention. Assays results on real samples showed that considerable differences in molecular ratio DNC:HDP exist among them. PMID:21645683
Mojahedian, Mohammad M; Daneshamouz, Saeid; Samani, Soliman Mohammadi; Zargaran, Arman
2013-09-01
Solid Lipid Nanoparticles (SLN) and Nanostructured Lipid Carriers (NLC) are novel medicinal carriers for controlled drug release and drug targeting in different roots of administration such as parenteral, oral, ophthalmic and topical. These carriers have some benefits such as increased drug stability, high drug payload, the incorporation of lipophilic and hydrophilic drugs, and no biotoxicity. Therefore, due to the cost-efficient, proportionally increasable, and reproducible preparation of SLN/NLC and the avoidance of organic solvents used, the warm microemulsion quenching method was selected from among several preparation methods for development in this research. To prepare the warm O/W microemulsion, lipids (distearin, stearic acid, beeswax, triolein alone or in combination with others) were melted at a temperature of 65°C. After that, different ratios of Tween60 (10-22.5%) and glyceryl monostearate (surfactant and co-surfactant) and water were added, and the combination was stirred. Then, 1-butanol (co-surfactant) was added dropwise until a clear microemulsion was formed and titration continued to achieve cloudiness (to obtain the microemulsion zone). The warm o/w microemulsions were added dropwise into 4°C water (1:5 volume ratio) while being stirred at 400 or 600 rpm. Lipid nanosuspensions were created upon the addition of the warm o/w microemulsion to the cold water. The SLN were obtained over a range of concentrations of co-surfactants and lipids and observed for microemulsion stability (clearness). For selected preparations, characterization involved also determination of mean particle size, polydispersity and shape. According to the aim of this study, the optimum formulations requiring the minimum amounts of 1-butanol (1.2%) and lower temperatures for creation were selected. Mono-disperse lipid nanoparticles were prepared in the size range 77 ± 1 nm to 124 ± 21 nm according to a laser diffraction particle size analyzer and transmission electron
ERIC Educational Resources Information Center
Rajabzadeh, Massy
2012-01-01
In this experiment, students learn how to find the unknown concentration of sodium acetate using both the graphical treatment of standard addition and the standard addition equation. In the graphical treatment of standard addition, the peak area of the methyl peak in each of the sodium acetate standard solutions is found by integration using…
NASA Astrophysics Data System (ADS)
Lorin, E.; Yang, X.; Antoine, X.
2016-06-01
The paper is devoted to develop efficient domain decomposition methods for the linear Schrödinger equation beyond the semiclassical regime, which does not carry a small enough rescaled Planck constant for asymptotic methods (e.g. geometric optics) to produce a good accuracy, but which is too computationally expensive if direct methods (e.g. finite difference) are applied. This belongs to the category of computing middle-frequency wave propagation, where neither asymptotic nor direct methods can be directly used with both efficiency and accuracy. Motivated by recent works of the authors on absorbing boundary conditions (Antoine et al. (2014) [13] and Yang and Zhang (2014) [43]), we introduce Semiclassical Schwarz Waveform Relaxation methods (SSWR), which are seamless integrations of semiclassical approximation to Schwarz Waveform Relaxation methods. Two versions are proposed respectively based on Herman-Kluk propagation and geometric optics, and we prove the convergence and provide numerical evidence of efficiency and accuracy of these methods.
Shen, Luan
1995-10-06
This dissertation is focused on three problem areas in the performance of inductively coupled plasma (ICP) source. The noise characteristics of aerosols produced by ICP nebulizers are investigated. A laser beam is scattered by aerosol and detected by a photomultiplier tube and the noise amplitude spectrum of the scattered radiation is measured by a spectrum analyzer. Discrete frequency noise in the aerosol generated by a Meinhard nebulizer or a direct injection nebulizer is primarily caused by pulsation in the liquid flow from the pump. A Scott-type spray chamber suppresses white noise, while a conical, straight-pass spray chamber enhances white noise, relative to the noise seen from the primary aerosol. Simultaneous correction for both spectral interferences and matrix effects in ICP atomic emission spectrometry (AES) can be accomplished by using the generalized standard additions method (GSAM). Results obtained with the application of the GSAM to the Perkin-Elmer Optima 3000 ICP atomic emission spectrometer are presented. The echelle-based polychromator with segmented-array charge-coupled device detectors enables the direct, visual examination of the overlapping lines Cd (1) 228.802 nm and As (1) 228.812 nm. The slit translation capability allows a large number of data points to be sampled, therefore, the advantage of noise averaging is gained. An ICP is extracted into a small quartz vacuum chamber through a sampling orifice in a water-cooled copper plate. Optical emission from the Mach disk region is measured with a new type of echelle spectrometer equipped with two segmented-array charge-coupled-device detectors, with an effort to improve the detection limits for simultaneous multielement analysis by ICP-AES.
Moisen, G.G.; Freeman, E.A.; Blackard, J.A.; Frescino, T.S.; Zimmermann, N.E.; Edwards, T.C., Jr.
2006-01-01
Many efforts are underway to produce broad-scale forest attribute maps by modelling forest class and structure variables collected in forest inventories as functions of satellite-based and biophysical information. Typically, variants of classification and regression trees implemented in Rulequest's?? See5 and Cubist (for binary and continuous responses, respectively) are the tools of choice in many of these applications. These tools are widely used in large remote sensing applications, but are not easily interpretable, do not have ties with survey estimation methods, and use proprietary unpublished algorithms. Consequently, three alternative modelling techniques were compared for mapping presence and basal area of 13 species located in the mountain ranges of Utah, USA. The modelling techniques compared included the widely used See5/Cubist, generalized additive models (GAMs), and stochastic gradient boosting (SGB). Model performance was evaluated using independent test data sets. Evaluation criteria for mapping species presence included specificity, sensitivity, Kappa, and area under the curve (AUC). Evaluation criteria for the continuous basal area variables included correlation and relative mean squared error. For predicting species presence (setting thresholds to maximize Kappa), SGB had higher values for the majority of the species for specificity and Kappa, while GAMs had higher values for the majority of the species for sensitivity. In evaluating resultant AUC values, GAM and/or SGB models had significantly better results than the See5 models where significant differences could be detected between models. For nine out of 13 species, basal area prediction results for all modelling techniques were poor (correlations less than 0.5 and relative mean squared errors greater than 0.8), but SGB provided the most stable predictions in these instances. SGB and Cubist performed equally well for modelling basal area for three species with moderate prediction success
Król, Sylwia; Zabiegała, Bożena; Namieśnik, Jacek
2012-08-01
Monitoring of the environmental fate of polybrominated diphenyl ethers (PBDEs) involves determination of their concentration in air, airborne particles and settled dust. This requires the implementation of appropriate analytical tools like measuring instruments, reference materials and analytical procedures. In this study an analytical procedure was developed for determining PBDEs in samples with a complex matrix composition. The efficiencies of three different extraction techniques - Soxhlet extraction (SE), Accelerated Solvent Extraction (ASE) and Ultrasound Assisted Extraction (UAE) - were compared. The study investigated the possibility of using the standard addition method for estimating PBDEs levels. The GC-μECD system was successfully applied as an alternative to low resolution mass spectrometry (LRMS) for determining BDE-209 in dust samples. The developed analytical procedure was then used to analyze dust samples, collected from houses and computer suites in the Tri-city area (Gdansk, Gdynia and Sopot), in order to detect and quantify the presence of polybrominated diphenyl ethers (PBDEs) in the indoor environment. Concentrations of studied congeners (from triBDE to heptaBDE), obtained by chromatographic analysis of dust samples extracts, performed applying two measurement systems (GC-EIMS and GC-μECD) ranged between 331 and 3102 ng g(-1) for house dust and between
NASA Astrophysics Data System (ADS)
Hartanto, A.; Zen, F. P.; Kosasih, J. S.
2014-03-01
Special condition of Scherk-Schwarz and Orbifold S1/Z2 breakings brings about both the weakly-coupled SU(6) Baby Higgs and the strongly-coupled will-be-SimplestLittleHiggs scalar in the near-brane of SU(3)×SU(3)×U(1). The later produces SU(3) VEVs and Simplest Little-like Higgs after triplet-triplet splitting and, under Uncertainty Principles with Coleman-Weinberg potential, the second yields finally exotic Higgses, the scalar-pair and 3-scalar Higgses in the so-called non-asymptotic and asymptotic states produced successively via one-by-one and collective (just-one) one-time breakings.
Chen Bin; He Yali; Song Xingchang; Zhang Peng
2005-04-15
We construct a one-parameter family of flat currents in AdS{sub 5}xS{sup 1} and AdS{sub 3}xS{sup 3} Green-Schwarz superstrings, which would naturally lead to a hierarchy of classical conserved nonlocal charges. In the former case we rewrite the AdS{sub 5}xS{sup 1} string using a new Z{sub 4}-graded base of the superalgebra su(2,2 vertical bar 2). In both cases the existence of the Z{sub 4} grading in the superalgebras plays a key role in the construction. As a result, we find that the flat currents, when formally written in terms of the G{sub 0}-gauge invariant lowercase 1-forms, take the same form as the one in the AdS{sub 5}xS{sup 5} case.
Lundby, W.
1993-06-29
A method is described of controlling, reducing or eliminating, ozone and related smog resulting from photochemical reactions between ozone and automotive or industrial gases comprising the addition of iodine or compounds of iodine to hydrocarbon-base fuels prior to or during combustion in an amount of about 1 part iodine per 240 to 10,000,000 parts fuel, by weight, to be accomplished by: (a) the addition of these inhibitors during or after the refining or manufacturing process of liquid fuels; (b) the production of these inhibitors for addition into fuel tanks, such as automotive or industrial tanks; or (c) the addition of these inhibitors into combustion chambers of equipment utilizing solid fuels for the purpose of reducing ozone.
Scholze, Martin; Silva, Elisabete; Kortenkamp, Andreas
2014-01-01
Dose addition, a commonly used concept in toxicology for the prediction of chemical mixture effects, cannot readily be applied to mixtures of partial agonists with differing maximal effects. Due to its mathematical features, effect levels that exceed the maximal effect of the least efficacious compound present in the mixture, cannot be calculated. This poses problems when dealing with mixtures likely to be encountered in realistic assessment situations where chemicals often show differing maximal effects. To overcome this limitation, we developed a pragmatic solution that extrapolates the toxic units of partial agonists to effect levels beyond their maximal efficacy. We extrapolated different additivity expectations that reflect theoretically possible extremes and validated this approach with a mixture of 21 estrogenic chemicals in the E-Screen. This assay measures the proliferation of human epithelial breast cancers. We found that the dose-response curves of the estrogenic agents exhibited widely varying shapes, slopes and maximal effects, which made it necessary to extrapolate mixture responses above 14% proliferation. Our toxic unit extrapolation approach predicted all mixture responses accurately. It extends the applicability of dose addition to combinations of agents with differing saturating effects and removes an important bottleneck that has severely hampered the use of dose addition in the past. PMID:24533151
Ambrogio, S.
1989-02-28
This patent describes the method of fuel storage or combustion, wherein the fuel supply contains small amounts of water, the step of adding to the fuel supply an additive comprising a blend of a hydrophilic agent chosen from the group of ethylene glycol, n-butyl alcohol, and cellosolve in the range of 22-37% by weight; ethoxylated nonylphenol in the range of 26-35% by weight; nonylphenol polyethylene glycol ether in the range of 32-43% by weight.
Kao, C; Zheng, M; Rüdisser, S
1999-01-01
DNA templates modified with C2'-methoxyls at the last two nucleotides of the 5' termini dramatically reduced nontemplated nucleotide addition by the T7 RNA polymerase from both single- and double-stranded DNA templates. This strategy was used to generate several different transcripts. Two of the transcripts were demonstrated by nuclear magnetic resonance spectroscopy to be unaffected in their sequence. Transcripts produced from the modified templates can be purified with greater ease and should be useful in a number of applications. PMID:10496227
Kessler, Terrance J.; Bunkenburg, Joachim; Huang, Hu
2007-02-13
A plurality of gratings (G1, G2) are arranged together with a wavefront sensor, actuators, and feedback system to align the gratings in such a manner, that they operate like a single, large, monolithic grating. Sub-wavelength-scale movements in the mechanical mounting, due to environmental influences, are monitored by an interferometer (28), and compensated by precision actuators (16, 18, 20) that maintain the coherently additive mode. The actuators define the grating plane, and are positioned in response to the wavefronts from the gratings and a reference flat, thus producing the interferogram that contains the alignment information. Movement of the actuators is also in response to a diffraction-limited spot on the CCD (36) to which light diffracted from the gratings is focused. The actuator geometry is implemented to take advantage of the compensating nature of the degrees of freedom between gratings, reducing the number of necessary control variables.
Tarazona, Pablo; Feussner, Kirstin; Feussner, Ivo
2015-11-01
Within the lipidome of plants a few bulk molecular species hamper the detection of the rest, which are present at relatively low levels. In addition, low-abundance species are often masked by numerous isobaric interferences, such as those caused by isoelemental species and isotopologues. This scenario not only means that minor species are underrepresented, but also leads to potential misidentifications and limits the structural information gathered by lipidomics approaches. In order to overcome these limitations we have developed a multiplexed liquid chromatography-mass spectrometry lipidomics platform able to achieve an enhanced coverage of plant lipidomes. The platform is based on a single extraction step followed by a series of ultra-performance liquid chromatography separations. Post-column flow is then directed to both a triple quadrupole analyzer for targeted profiling and a time-of-flight analyzer for accurate mass analysis. As a proof of concept, plants were subjected to cold or drought, which are known to trigger widespread remodeling events in plant cell membranes. Analysis of the leaf lipidome yielded 393 molecular species within 23 different lipid classes. This enhanced coverage allowed us to identify lipid molecular species and even classes that are altered upon stress, allowing hypotheses on role of glycosylinositolphosphoceramides (GIPC), steryl glycosides (SG) and acylated steryl glycosides (ASG) in drought stress to be addressed and confirming the findings from numerous previous studies with a single, wide-ranging lipidomics approach. This extended our knowledge on membrane remodeling during the drought response, integrating sphingolipids and sterol lipids into the current glycerolipid-based model. PMID:26340975
Tada, Atsuko; Ishizuki, Kyoko; Yamazaki, Takeshi; Sugimoto, Naoki; Akiyama, Hiroshi
2014-01-01
Natural ester-type gum bases, which are used worldwide as food additives, mainly consist of wax esters composed of long-chain fatty acids and long-chain fatty alcohols. There are many varieties of ester-type gum bases, and thus a useful method for their discrimination is needed in order to establish official specifications and manage their quality control. Herein is reported a rapid and simple method for the analysis of different ester-type gum bases used as food additives by high-temperature gas chromatography/mass spectrometry (GC/MS). With this method, the constituent wax esters in ester-type gum bases can be detected without hydrolysis and derivatization. The method was applied to the determination of 10 types of gum bases, including beeswax, carnauba wax, lanolin, and jojoba wax, and it was demonstrated that the gum bases derived from identical origins have specific and characteristic total ion chromatogram (TIC) patterns and ester compositions. Food additive gum bases were thus distinguished from one another based on their TIC patterns and then more clearly discriminated using simultaneous monitoring of the fragment ions corresponding to the fatty acid moieties of the individual molecular species of the wax esters. This direct high-temperature GC/MS method was shown to be very useful for the rapid and simple discrimination of varieties of ester-type gum bases used as food additives. PMID:25473499
Tada, Atsuko; Ishizuki, Kyoko; Yamazaki, Takeshi; Sugimoto, Naoki; Akiyama, Hiroshi
2014-07-01
Natural ester-type gum bases, which are used worldwide as food additives, mainly consist of wax esters composed of long-chain fatty acids and long-chain fatty alcohols. There are many varieties of ester-type gum bases, and thus a useful method for their discrimination is needed in order to establish official specifications and manage their quality control. Herein is reported a rapid and simple method for the analysis of different ester-type gum bases used as food additives by high-temperature gas chromatography/mass spectrometry (GC/MS). With this method, the constituent wax esters in ester-type gum bases can be detected without hydrolysis and derivatization. The method was applied to the determination of 10 types of gum bases, including beeswax, carnauba wax, lanolin, and jojoba wax, and it was demonstrated that the gum bases derived from identical origins have specific and characteristic total ion chromatogram (TIC) patterns and ester compositions. Food additive gum bases were thus distinguished from one another based on their TIC patterns and then more clearly discriminated using simultaneous monitoring of the fragment ions corresponding to the fatty acid moieties of the individual molecular species of the wax esters. This direct high-temperature GC/MS method was shown to be very useful for the rapid and simple discrimination of varieties of ester-type gum bases used as food additives. PMID:25473499
Bishop, H.
1988-10-18
This patent describes a method of making an additive comprising: (a) adding 2 parts by volume of 3% sodium hypochlorite to 45 parts by volume of diesel oil fuel to form a sulphur free fuel, (b) removing all water and foreign matter formed by the sodium hypochlorite, (c) blending 30 parts by volume of 24% lead naphthanate with 15 parts by volume of the sulphur free fuel, 15 parts by volume of light-weight material oil to form a blended mixture, and (d) heating the blended mixture slowly and uniformly to 152F.
NASA Astrophysics Data System (ADS)
Sari, Intan Permata; Endarko
2016-04-01
Ion-exchange membrane technology has shown a great potential to enhance the desalting efficiency. Ion-exchange membranes are placed in front of the electrodes so that the charged ions can be selectively passed through the membrane layer and captured by the oppositely charged electrode more quickly, so as to increase the efficiency of desalination. In this research, carbon electrodes have been synthesized from an activated carbon (700 - 1400 m2/g) and polyvinyl alcohol (PVA) as a binder using freezing thawing method. A solution with 180 µS/cm NaCl was pumped to the capacitive deionization (CDI) cell using a Boyu Submersible pump (model SP-601) at a flow rate of 25 mL/min and the voltage was set at 2 V. The result showed that the CDI cell with ion-exchange membrane (MCDI) has the salt removal efficiency greater than the CDI cell without ion-exchange membrane. The salt-removal percentage of MCDI was achieved at 66.36%, meanwhile the CDI cell without ion-exchange membrane resulted in 54.4%.
Schrey, Aleksi; Niemi, Tarja; Kinnunen, Ilpo; Minn, Heikki; Vahlberg, Tero; Kalliokoski, Kari; Suominen, Erkki; Grénman, Reidar; Aitasalo, Kalle
2010-02-01
Twelve patients who underwent breast reconstruction with a microvascular flap were monitored postoperatively with continuous partial tissue oxygenation (p(ti)O(2)) measurement. The regional blood flow (BF) of the entire flap was evaluated with positron emission tomography (PET) using oxygen-15-labelled water on the first postoperative (POP) morning to achieve data of the perfusion of the entire flap. A re-exploration was carried out if the p(ti)O(2) value remained lower than 15 mmHg for over 30 min. The mean p(ti)O(2) value of the flaps was 52.9+/-5.5 mmHg, whereas the mean BF values were 3.3+/-1.0 ml per 100 g min(-1). One false-positive result was detected by p(ti)O(2) measurement, resulting in an unnecessary re-exploration. Another re-operation suggested by the low p(ti)O(2) results was avoided due to the normal BF results assessed with PET. Totally, three flaps were re-explored. This prospective study suggests that continuous tissue-oxygen measurement with a polarographic needle probe is reliable for monitoring free breast flaps from one part of the flap, but assessing perfusion of the entire flap requires more complex monitoring methods, for example, PET. Clinical examination by experienced personnel remains important in free-breast-flap monitoring. PET could be useful in assessing free-flap perfusion in selected high-risk patients as an alternative to a re-operation when clinical examination and evaluation by other means are unreliable or present controversial results. PMID:19059818
Functional Generalized Additive Models.
McLean, Mathew W; Hooker, Giles; Staicu, Ana-Maria; Scheipl, Fabian; Ruppert, David
2014-01-01
We introduce the functional generalized additive model (FGAM), a novel regression model for association studies between a scalar response and a functional predictor. We model the link-transformed mean response as the integral with respect to t of F{X(t), t} where F(·,·) is an unknown regression function and X(t) is a functional covariate. Rather than having an additive model in a finite number of principal components as in Müller and Yao (2008), our model incorporates the functional predictor directly and thus our model can be viewed as the natural functional extension of generalized additive models. We estimate F(·,·) using tensor-product B-splines with roughness penalties. A pointwise quantile transformation of the functional predictor is also considered to ensure each tensor-product B-spline has observed data on its support. The methods are evaluated using simulated data and their predictive performance is compared with other competing scalar-on-function regression alternatives. We illustrate the usefulness of our approach through an application to brain tractography, where X(t) is a signal from diffusion tensor imaging at position, t, along a tract in the brain. In one example, the response is disease-status (case or control) and in a second example, it is the score on a cognitive test. R code for performing the simulations and fitting the FGAM can be found in supplemental materials available online. PMID:24729671
Incorporation of additives into polymers
McCleskey, T. Mark; Yates, Matthew Z.
2003-07-29
There has been invented a method for incorporating additives into polymers comprising: (a) forming an aqueous or alcohol-based colloidal system of the polymer; (b) emulsifying the colloidal system with a compressed fluid; and (c) contacting the colloidal polymer with the additive in the presence of the compressed fluid. The colloidal polymer can be contacted with the additive by having the additive in the compressed fluid used for emulsification or by adding the additive to the colloidal system before or after emulsification with the compressed fluid. The invention process can be carried out either as a batch process or as a continuous on-line process.
Method for promoting Michael addition reactions
Shah, Pankaj V.; Vietti, David E.; Whitman, David William
2010-09-21
Homogeneously dispersed solid reaction promoters having an average particle size from 0.01 .mu.m to 500 .mu.m are disclosed for preparing curable mixtures of at least one Michael donor and at least one Michael acceptor. The resulting curable mixtures are useful as coatings, adhesives, sealants and elastomers.
Enantioselective Michael Addition of Water
Chen, Bi-Shuang; Resch, Verena; Otten, Linda G; Hanefeld, Ulf
2015-01-01
The enantioselective Michael addition using water as both nucleophile and solvent has to date proved beyond the ability of synthetic chemists. Herein, the direct, enantioselective Michael addition of water in water to prepare important β-hydroxy carbonyl compounds using whole cells of Rhodococcus strains is described. Good yields and excellent enantioselectivities were achieved with this method. Deuterium labeling studies demonstrate that a Michael hydratase catalyzes the water addition exclusively with anti-stereochemistry. PMID:25529526
Botella, Lucía; Bimbela, Fernando; Martín, Lorena; Arauzo, Jesús; Sánchez, José L.
2014-01-01
In the present work, several fatty acid methyl esters (FAME) have been synthesized from various fatty acid feedstocks: used frying olive oil, pork fat, soybean, rapeseed, sunflower, and coconut. The oxidation stabilities of the biodiesel samples and of several blends have been measured simultaneously by both the Rancimat method, accepted by EN14112 standard, and the PetroOXY method, prEN16091 standard, with the aim of finding a correlation between both methodologies. Other biodiesel properties such as composition, cold filter plugging point (CFPP), flash point (FP), and kinematic viscosity have also been analyzed using standard methods in order to further characterize the biodiesel produced. In addition, the effect on the biodiesel properties of using 4-allyl-2,6-dimethoxyphenol and catechol as additives in biodiesel blends with rapeseed and with soybean has also been analyzed. The use of both antioxidants results in a considerable improvement in the oxidation stability of both types of biodiesel, especially using catechol. Adding catechol loads as low as 0.05% (m/m) in blends with soybean biodiesel and as low as 0.10% (m/m) in blends with rapeseed biodiesel is sufficient for the oxidation stabilities to comply with the restrictions established by the European EN14214 standard. An empirical linear equation is proposed to correlate the oxidation stability by the two methods, PetroOXY and Rancimat. It has been found that the presence of either catechol or 4-allyl-2,6-dimethoxyphenol as additives affects the correlation observed. PMID:25101258
NASA Astrophysics Data System (ADS)
Botella, Lucía; Bimbela, Fernando; Martín, Lorena; Arauzo, Jesús; Sanchez, Jose Luis
2014-07-01
In the present work, several fatty acid methyl esters (FAME) have been synthesized from various fatty acid feedstocks: used frying olive oil, pork fat, soybean, rapeseed, sunflower and coconut. The oxidation stabilities of the biodiesel samples and of several blends have been measured simultaneously by both the Rancimat method, accepted by EN14112 standard, and the PetroOXY method, prEN16091 standard, with the aim of finding a correlation between both methodologies. Other biodiesel properties such as composition, cold filter plugging point (CFPP), flash point (FP) and kinematic viscosity have also been analyzed using standard methods in order to further characterize the biodiesel produced. In addition, the effect on the biodiesel properties of using 4-allyl-2,6-dimetoxiphenol and cathecol as additives in biodiesel blends with rapeseed and with soybean has also been analyzed. The use of both antioxidants results in a considerable improvement in the oxidation stability of both types of biodiesel, especially using cathecol. Adding cathecol loads as low as 0.05 % (m/m) in blends with soybean biodiesel and as low as 0.10 % (m/m) in blends with rapeseed biodiesel is sufficient for the oxidation stabilities to comply with the restrictions established by the European EN14214 standard.An empirical linear equation is proposed to correlate the oxidation stability by the two methods, PetroOXY and Rancimat. It has been found that the presence of either cathecol or 4-allyl-2,6-dimetoxiphenol as additives affects the correlation observed.