Coal recovery process

DOEpatents

Good, Robert J.; Badgujar, Mohan

1992-01-01

A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly progress report, July--September 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Curtis, C.W.; Gutterman, C.; Chander, S.

The overall objective of this project is to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and carrying out a technical assessment including an economic evaluation. The primary coal of this program, Black Thunder subbituminous coal, can be effectively beneficiated to about 3.5 wt % ash using aqueous sulfurous acid pretreatment. This treated coal can be further beneficiated to about 2 wt % ash usingmore » commercially available procedures. All three coals used in this study (Black Thunder, Burning Star bituminous, and Martin Lake lignite) are effectively swelled by a number of solvents. The most effective solvents are those having hetero-functionality. laboratory- and bench-scale liquefaction experimentation is underway using swelled and catalyst impregnated coal samples. Higher coal conversions were observed for the SO{sub 2}-treated subbituminous coal than the raw coal, regardless of catalyst type. Conversions of swelled coal were highest when Molyvan L, molybdenum naphthenate, and nickel octoate, respectively, were added to the liquefaction solvent. The study of bottoms processing consists of combining the ASCOT process which consists of coupling solvent deasphalting with delayed coking to maximize the production of coal-derived liquids while rejecting solids within the coke drum. The asphalt production phase has been completed; representative product has been evaluated. The solvent system for the deasphalting process has been established. Two ASCOT tests produced overall liquid yields (63.3 wt % and 61.5 wt %) that exceeded the combined liquid yields from the vacuum tower and ROSE process.« less

Development of clean coal and clean soil technologies using advanced agglomeration technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ignasiak, B.; Pawlak, W.; Szymocha, K.

1990-04-01

The specific objectives of the bituminous coal program were to explore and evaluate the application of advanced agglomeration technology for: (1)desulphurization of bituminous coals to sulphur content acceptable within the current EPA SO{sub 2} emission guidelines; (2) deashing of bituminous coals to ash content of less than 10 percent; and (3)increasing the calorific value of bituminous coals to above 13,000 Btu/lb. (VC)

Assessment of Advanced Coal Gasification Processes

NASA Technical Reports Server (NTRS)

McCarthy, John; Ferrall, Joseph; Charng, Thomas; Houseman, John

1981-01-01

This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process; Bell Single-Stage High Mass Flux (HMF) Process; Cities Service/Rockwell (CS/R) Hydrogasification Process; Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic, fluidbed reactor producing all of the raw product methane in the gasifier. The report makes the following assessments: 1) while each process has significant potential as coal gasifiers, the CS/R and Exxon processes are better suited for SNG production; 2) the Exxon process is the closest to a commercial level for near-term SNG production; and 3) the SRT processes require significant development including scale-up and turndown demonstration, char processing and/or utilization demonstration, and reactor control and safety features development.

Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Curtis, C.W.; Chander, S.; Gutterman, C.

Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than didmore » relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.« less

Discards beneficiation in South Africa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Horsfall, D.W.

1995-08-01

The intergrown nature of most South African coals means that in beneficiating them, the preparation engineer rarely has the easy task of carrying out a simple separation between good coal and high density shale or stone. Apart from de-shaling operations, all beneficiation entails rejecting, not only adventitious stone but a large percentage of high ash but strongly combustible middlings material. Typically, a coal preparation plant can only recover about 70-80% of the heat in the run-of-mine coal. The other 20-30% ends up on the discard heap. Over the last decade, extensive studies were carried out to establish the extend tomore » which that discarded heat may be recoverable in marketable grades of coal. Detailed washability studies were carried out on four mines which between them produce almost 60% of the total make of discards. Computer simulations allowed different flowsheet configurations to be assessed to give rewashed coal of various calorific values. The flowsheets were also subjected to factorial establishment of budget capital and operating costs. Finally some initial work was carried out on the potential markets for such products. This paper is concise account of the results of the study for one major mine. Please note that the paper is based almost wholly on the evaluation carried out for the Energy Branch of the Department of Mineral and Energy Affairs (DMEA). The actual work was executed by the van Eck and Lurie Division of E L Bateman and Co. The writer chaired the Beneficiation Sub-Committee set up by the DMEA to oversee and guide the work, and in that capacity was closely connected with the study as it evolved. Other acknowledgements are given at the end of the paper.« less

Pelletizing/reslurrying as a means of distributing and firing clean coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conkle, H.N.; Raghavan, J.K.; Smit, F.J.

1991-11-21

The objective of this study is to develop technology that permits the practical and economic preparation, storage, handling, and transportation of coal pellets, which can be reslurried into Coal water fuels (CWF) suitable for firing in small- and medium-size commercial and industrial boilers, furnaces, and engines. The project includes preparing coal pellets and capsules from wet filter cake that can be economically stored, handled, transported, and reslurried into a CWF that can be suitably atomized and fired at the user site. The wet cakes studied were prepared from ultra-fine (95% -325 mesh) coal beneficiated by advanced froth-flotation techniques. The coalsmore » studied included two eastern bituminous coals, one from Virginia (Elkhorn) and one from Illinois (Illinois No. 6) and one western bituminous coal from Utah (Sky Line coal).« less

A moving baseline for evaluation of advanced coal extraction systems

NASA Technical Reports Server (NTRS)

Bickerton, C. R.; Westerfield, M. D.

1981-01-01

Results from the initial effort to establish baseline economic performance comparators for a program whose intent is to define, develop, and demonstrate advanced systems suitable for coal resource extraction beyond the year 2000 are reported. Systems used were selected from contemporary coal mining technology and from conservation conjectures of year 2000 technology. The analysis was also based on a seam thickness of 6 ft. Therefore, the results are specific to the study systems and the selected seam extended to other seam thicknesses.

Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-05-01

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, andmore » volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.« less

Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oguejiofor, G.C.

Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phasemore » distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.« less

Economic aspects of advanced coal-fired gas turbine locomotives

NASA Technical Reports Server (NTRS)

Liddle, S. G.; Bonzo, B. B.; Houser, B. C.

1983-01-01

Increases in the price of such conventional fuels as Diesel No. 2, as well as advancements in turbine technology, have prompted the present economic assessment of coal-fired gas turbine locomotive engines. A regenerative open cycle internal combustion gas turbine engine may be used, given the development of ceramic hot section components. Otherwise, an external combustion gas turbine engine appears attractive, since although its thermal efficiency is lower than that of a Diesel engine, its fuel is far less expensive. Attention is given to such a powerplant which will use a fluidized bed coal combustor. A life cycle cost analysis yields figures that are approximately half those typical of present locomotive engines.

New cleaning technologies advance coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Onursal, B.

1984-05-01

Alternative options are discussed for reducing sulfur dioxide emissions from coal burning utility and industrial sources. Test results indicate that it may be most advantageous to use the AED Process after coal preparation or on coals that do not need much ash removal. However, the developer claims that research efforts after 1981 have led to process improvements for producing clean coals containing 1.5% to 3% ash. This paper describes the test facility where a full-scale test of the AED Process is underway.

Removal of ash, sulfur, and trace elements of environmental concern from eight selected Illinois coals

USGS Publications Warehouse

Demir, I.

1998-01-01

Release analysis (RA) and float-sink (F-S) data were generated to assess the beneficiation potential of washed coals from selected Illinois coal preparation plants through the use of advanced physical cleaning at -60 mesh size. Generally, the F-S process removed greater amounts of ash, sulfur, and trace elements of environmental concern from the coals than the RA process, indicating that the cleanability of Illinois coals by advanced methods can be estimated best by F-S testing. At an 80%-combustibles recovery, the ash yield in the clean F-S products decreased by 47-75%, relative to the parent coals. Average decreases for the elements As(67%), Cd(78%), Hg(73%), Mn(71%), and P(66%) exceeded the average decrease for ash yield (55%). Average decreases for other elements were: Co(31%), Cr(27%), F(39%), Ni(25%), Pb(50%), S(28%), Sb(20%), Se(39), Th(32%), and U(8%). Only Be was enriched (up to 120%) in the clean products relative to the parent coals. These results suggested that the concentration of elements with relatively high atmospheric mobilities (As, Cd, F, Hg, Pb, and Se) during coal combustion can be reduced substantially in Illinois coals through the use of advanced physical cleaning. Advanced physical cleaning can be effective also for the removal of inorganic S. Environmental risks from the emission of other elements with enrichment or relatively low cleanabilities could be small because these elements generally have very low concentrations in Illinois coals or are largely retained in solid residues during coal combustion. ?? 1998 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint.

Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Run 260 with Black Thunder Mine subbituminous coal: Technical progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This report presents the results of Run 260 performed at the Advanced Coal Liquefaction R&D Facility in Wilsonville. The run was started on July 17, 1990 and continued until November 14, 1990, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). Both thermal/catalytic and catalytic/thermal tests were performed to determine the methods for reducing solids buildup in a subbituminous coal operation, and to improve product yields. A new, smaller interstage separator was tested to reduce solids buildup by increasing the slurry space velocity in the separator. In ordermore » to obtain improved coal and resid conversions (compared to Run 258) full-volume thermal reactor and 3/4-volume catalytic reactor were used. Shell 324 catalyst, 1/16 in. cylindrical extrudate, at a replacement rate of 3 lb/ton of MF coal was used in the catalytic stage. Iron oxide was used as slurry catalyst at a rate of 2 wt % MF coal throughout the run. (TNPS was the sulfiding agent.)« less

Applications study of advanced power generation systems utilizing coal-derived fuels, volume 2

NASA Technical Reports Server (NTRS)

Robson, F. L.

1981-01-01

Technology readiness and development trends are discussed for three advanced power generation systems: combined cycle gas turbine, fuel cells, and magnetohydrodynamics. Power plants using these technologies are described and their performance either utilizing a medium-Btu coal derived fuel supplied by pipeline from a large central coal gasification facility or integrated with a gasification facility for supplying medium-Btu fuel gas is assessed.

Cross flow cyclonic flotation column for coal and minerals beneficiation

DOEpatents

Lai, Ralph W.; Patton, Robert A.

2000-01-01

An apparatus and process for the separation of coal from pyritic impurities using a modified froth flotation system. The froth flotation column incorporates a helical track about the inner wall of the column in a region intermediate between the top and base of the column. A standard impeller located about the central axis of the column is used to generate a centrifugal force thereby increasing the separation efficiency of coal from the pyritic particles and hydrophillic tailings.

Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rader, Jeff; Aguilar, Kelly; Aldred, Derek

2012-03-30

The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbonmore » capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.« less

Production of High Energy Aviation Fuels from Advanced Coal Liquids. Phase 1.

DTIC Science & Technology

1987-04-01

AD-A192 333 PRODUCTION OF HIGH ENERGY AVIATION FUELS FROM RDYANCED 1/1 COAL LIQUIDS PHASE 1(U) STRAT CO SALT LAKE CITY UT J DOWNEN APR 9? AFWRL-TR-87...OF HIGH ENERGY AVIATION FUELS FROM ADVANCED COAL LIQUIDS * JOHN DOWNEN STRAT CO. 4597 JUPITER DRIVE SALT LAKE CITY, UTAH 84124 APRIL 1987 FINAL REPORT...OAU TION NME or dokew AFo Prpulsin LCbrator NOA"TO INACCE1SPONONO II-TTEX Xuc*cait* 65502F 1 3005 I 20 r 63 Production of High Energy Aviation Fuels

The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBTU/hour oil fired boiler to pulverized coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zauderer, B.; Fleming, E.S.

1991-08-30

This work contains to the final report of the demonstration of an advanced cyclone coal combustor. Titles include: Chronological Description of the Clean Coal Project Tests,'' Statistical Analysis of Operating Data for the Coal Tech Combustor,'' Photographic History of the Project,'' Results of Slag Analysis by PA DER Module 1 Procedure,'' Properties of the Coals Limestone Used in the Test Effort,'' Results of the Solid Waste Sampling Performed on the Coal Tech Combustor by an Independent Contractor During the February 1990 Tests.'' (VC)

Flotation and flocculation chemistry of coal and oxidized coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Somasundaran, P.

1990-01-01

The objective of this research project is to understand the fundamentals involved in the flotation and flocculation of coal and oxidized coals and elucidate mechanisms by which surface interactions between coal and various reagents enhance coal beneficiation. An understanding of the nature of the heterogeneity of coal surfaces arising from the intrinsic distribution of chemical moieties is fundamental to the elucidation of mechanism of coal surface modification and its role in interfacial processes such as flotation, flocculation and agglomeration. A new approach for determining the distribution in surface properties of coal particles was developed in this study and various techniquesmore » capable of providing such information were identified. Distributions in surface energy, contact angle and wettability were obtained using novel techniques such as centrifugal immersion and film flotation. Changes in these distributions upon oxidation and surface modifications were monitored and discussed. An approach to the modelling of coal surface site distributions based on thermodynamic information obtained from gas adsorption and immersion calorimetry is proposed. Polyacrylamide and dodecane was used to alter the coal surface. Methanol adsorption was also studied. 62 figs.« less

Coal Research

NASA Technical Reports Server (NTRS)

1986-01-01

Coal slurries are "clean" pulverized coal mixed with oil or water. Significant fuel savings can be realized when using coal slurries. Advanced Fuels Technology (AFT) utilized a COSMIC program, (Calculation of Complex Chemical Equilibrium Compositions), which provides specific capabilities for determining combustion products. The company has developed a cleaning process that removes much of the mineral sulphur and ash from the coals.

The development of coal-based technologies for Department of Defense facilities. Volume 1, Technical report. Semiannual technical progress report, September 28, 1994--March 27, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, B.G.; Bartley, D.A.; Hatcher, P.

1996-10-15

This program is being conducted as a cooperative agreement between the Consortium for Coal Water Mixture Technology and the U.S. Department of Energy. Activities this reporting period are summarized by phase. Phase I is nearly completed. During this reporting period, coal beneficiation/preparation studies, engineering designs and economics for retrofitting the Crane, Indiana boiler to fire coal-based fuels, and a 1,000-hour demonstration of dry, micronized coal were completed. In addition, a demonstration-scale micronized-coal water mixture (MCWM) preparation circuit was constructed and a 1,000-hour demonstration firing MCWM began. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analysesmore » of coal use. Emissions reductions investigations involved literature surveys of NO{sub x}, SO{sub 2}, trace metals, volatile organic compounds, and fine particulate matter capture. In addition, vendors and engineering firms were contacted to identify the appropriate emissions technologies for the installation of commercial NO{sub x} and SO{sub 2} removal systems on the demonstration boiler. Information from the literature surveys and engineering firms will be used to identify, design, and install a control system(s). Work continued on the refinement and optimization of coal grinding and MCWM preparation procedures, and on the development of advanced processes for beneficiating high ash, high sulfur coals. Work also continued on determining the basic cost estimation of boiler retrofits, and evaluating environmental, regulatory, and regional economic impacts. In addition, the feasibility of technology adoption, and the public`s perception of the benefits and costs of coal usage was studied. A coal market analysis was completed. Work in Phase III focused on coal preparation studies, emissions reductions and economic analyses of coal use.« less

Recent advances in large-eddy simulation of spray and coal combustion

NASA Astrophysics Data System (ADS)

Zhou, L. X.

2013-07-01

Large-eddy simulation (LES) is under its rapid development and is recognized as a possible second generation of CFD methods used in engineering. Spray and coal combustion is widely used in power, transportation, chemical and metallurgical, iron and steel making, aeronautical and astronautical engineering, hence LES of spray and coal two-phase combustion is particularly important for engineering application. LES of two-phase combustion attracts more and more attention; since it can give the detailed instantaneous flow and flame structures and more exact statistical results than those given by the Reynolds averaged modeling (RANS modeling). One of the key problems in LES is to develop sub-grid scale (SGS) models, including SGS stress models and combustion models. Different investigators proposed or adopted various SGS models. In this paper the present author attempts to review the advances in studies on LES of spray and coal combustion, including the studies done by the present author and his colleagues. Different SGS models adopted by different investigators are described, some of their main results are summarized, and finally some research needs are discussed.

Pilot Plant Program for the AED Advanced Coal Cleaning System. Phase II. Interim final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1980-08-01

Advanced Energy Dynamics, Inc. (AED), has developed a proprietary coal cleaning process which employs a combination of ionization and electrostatic separation to remove both sulfur and ash from dry pulverized coal. The Ohio Department of Energy sponsored the first part of a program to evaluate, develop, and demonstrate the process in a continuous-flow pilot plant. Various coals used by Ohio electric utilities were characterized and classified, and sulfur reduction, ash reduction and Btu recovery were measured. Sulfur removal in various coals ranged from 33 to 68% (on a Btu basis). Ash removal ranged from 17 to 59% (on a Btumore » basis). Ash removal of particles greater than 53 microns ranged from 46 to 88%. Btu recovery ranged from 90 to 97%. These results, especially the large percentage removal of ash particles greater than 53 microns, suggest that the AED system can contribute materially to improved boiler performance and availability. The study indicated the following potential areas for commercial utilization of the AED process: installation between the pulverizer and boiler of conventional coal-fired power utilities; reclamation of fine coal refuse; dry coal cleaning to supplement, and, if necessary, to take the place of conventional coal cleaning; upgrading coal used in: (1) coal-oil mixtures, (2) gasification and liquefaction processes designed to handle pulverized coal; and (3) blast furnaces for making steel, as a fuel supplement to the coke. Partial cleaning of coking coal blends during preheating may also prove economically attractive. Numerous other industrial processes which use pulverized coal such as the production of activated carbon and direct reduction of iron ore may also benefit from the use of AED coal cleaning.« less

Evaluation of ADAM/1 model for advanced coal extraction concepts

NASA Technical Reports Server (NTRS)

Deshpande, G. K.; Gangal, M. D.

1982-01-01

Several existing computer programs for estimating life cycle cost of mining systems were evaluated. A commercially available program, ADAM/1 was found to be satisfactory in relation to the needs of the advanced coal extraction project. Two test cases were run to confirm the ability of the program to handle nonconventional mining equipment and procedures. The results were satisfactory. The model, therefore, is recommended to the project team for evaluation of their conceptual designs.

Pelletizing/reslurrying as a means of distributing and firing clean coal. Final quarterly technical progress report No. 5, July 1, 1991--September 30, 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conkle, H.N.; Raghavan, J.K.; Smit, F.J.

1991-11-21

The objective of this study is to develop technology that permits the practical and economic preparation, storage, handling, and transportation of coal pellets, which can be reslurried into Coal water fuels (CWF) suitable for firing in small- and medium-size commercial and industrial boilers, furnaces, and engines. The project includes preparing coal pellets and capsules from wet filter cake that can be economically stored, handled, transported, and reslurried into a CWF that can be suitably atomized and fired at the user site. The wet cakes studied were prepared from ultra-fine (95% -325 mesh) coal beneficiated by advanced froth-flotation techniques. The coalsmore » studied included two eastern bituminous coals, one from Virginia (Elkhorn) and one from Illinois (Illinois No. 6) and one western bituminous coal from Utah (Sky Line coal).« less

Methodology for Evaluating Encapsulated Beneficial Uses of Coal Combustion Residuals

EPA Pesticide Factsheets

The primary purpose of this document is to present an evaluation methodology developed by the EPA for making determinations about environmental releases from encapsulated products containing coal combustion residuals.

Formulation of low solids coal water slurry from advanced coal cleaning waste fines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Battista, J.J.; Morrison, J.L.; Lambert, A.

1997-07-01

GPU Genco, the New York State Electric and Gas Corporation (NYSEG), Penn State University and the Homer City Coal Processing Corporation are conducting characterization and formulation tests to determine the suitability of using minus 325 mesh coal waste fines as a low solids coal water slurry (CWS) co-firing fuel. The fine coal is contained in a centrifuge effluent stream at the recently modified Homer City Coal Preparation Plant. Recovering, thickening and then co-firing this material with pulverized coal is one means of alleviating a disposal problem and increasing the Btu recovery for the adjacent power plant. The project team ismore » currently proceeding with the design of a pilot scale system to formulate the effluent into a satisfactory co-firing fuel on a continuous basis for combustion testing at Seward Station. The ultimate goal is to burn the fuel at the pulverized coal units at the Homer City Generating Station. This paper presents the success to date of the slurry characterization and pilot scale design work. In addition, the paper will update GPU Genco`s current status for the low solids coal water slurry co-firing technology and will outline the company`s future plans for the technology.« less

Advanced coal gasifier-fuel cell power plant systems design

NASA Technical Reports Server (NTRS)

Heller, M. E.

1983-01-01

Two advanced, high efficiency coal-fired power plants were designed, one utilizing a phosphoric acid fuel cell and one utilizing a molten carbonate fuel cell. Both incorporate a TRW Catalytic Hydrogen Process gasifier and regenerator. Both plants operate without an oxygen plant and without requiring water feed; they, instead, require makeup dolomite. Neither plant requires a shift converter; neither plant has heat exchangers operating above 1250 F. Both plants have attractive efficiencies and costs. While the molten carbonate version has a higher (52%) efficiency than the phosphoric acid version (48%), it also has a higher ($0.078/kWh versus $0.072/kWh) ten-year levelized cost of electricity. The phosphoric acid fuel cell power plant is probably feasible to build in the near term: questions about the TRW process need to be answered experimentally, such as weather it can operate on caking coals, and how effective the catalyzed carbon-dioxide acceptor will be at pilot scale, both in removing carbon dioxide and in removing sulfur from the gasifier.

Advanced direct coal liquefaction concepts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, D.J.; Parker, R.J.; Simpson, P.L.

During the first quarter of FY 1993, the Project proceeded close to the Project Plan. The analysis of the feed material has been completed as far as possible. Some unplanned distillation was needed to correct the boiling range of the Black Thunder solvent used during the autoclave tests. Additional distillation will be required if the same solvent is to be used for the bench unit tests. A decision on this is still outstanding. The solvent to be used with Illinois No. 6 coal has not yet been defined. As a result, the procurement of the feed and the feed analysismore » is somewhat behind schedule. Agglomeration tests with Black Thunder coal indicates that small agglomerates can be formed. However, the ash removal is quite low (about 10%), which is not surprising in view of the low ash content of the coal. The first series of autoclave tests with Black Thunder coal was completed as planned. Also, additional runs are in progress as repeats of previous runs or at different operating conditions based on the data obtained so far. The results are promising indicating that almost complete solubilization (close to 90%) of Black Thunder coal can be achieved in a CO/H[sub 2]O environment at our anticipated process conditions. The design of the bench unit has been completed. In contrast to the originally planned modifications, the bench unit is now designed based on a computerized control and data acquisition system. All major items of equipment have been received, and prefabrication of assemblies and control panels is proceeding on schedule. Despite a slight delay in the erection of the structural steel, it is anticipated that the bench unit will be operational at the beginning of April 1993.« less

Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Run 262 with Black Thunder subbituminous coal: Technical progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This report presents the results of Run 262 performed at the Advanced Coal Liquefaction R&D Facility in Wilsonville, Alabama. The run started on July 10, 1991 and continued until September 30, 1991, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder Mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). A dispersed molybdenum catalyst was evaluated for its performance. The effect of the dispersed catalyst on eliminating solids buildup was also evaluated. Half volume reactors were used with supported Criterion 324 1/16`` catalyst in the second stage at a catalyst replacement rate of 3 lb/ton of MFmore » coal. The hybrid dispersed plus supported catalyst system was tested for the effect of space velocity, second stage temperature, and molybdenum concentration. The supported catalyst was removed from the second stage for one test period to see the performance of slurry reactors. Iron oxide was used as slurry catalyst at a rate of 2 wt % MF coal throughout the run (dimethyl disulfide (DMDS) was used as the sulfiding agent). The close-coupled reactor unit was on-stream for 1271.2 hours for an on-stream factor of 89.8% and the ROSE-SR unit was on-feed for 1101.6 hours for an on-stream factor of 90.3% for the entire run.« less

ELECTROSTATIC SURFACE STRUCTURES OF COAL AND MINERAL PARTICLES

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

It is the purpose of this research to study electrostatic charging mechanisms related to electrostatic beneficiation of coal with the goal of improving models of separation and the design of electrostatic separators. Areas addressed in this technical progress report are (a) electrostatic beneficiation of Pittsburgh #8 coal powders as a function of grind size and processing atmosphere; (b) the use of fluorescent micro-spheres to probe the charge distribution on the surfaces of coal particles; (c) the use of electrostatic beneficiation to recover unburned carbon from flyash; (d) the development of research instruments for investigation of charging properties of coal. Pittsburghmore » #8 powders were beneficiated as a function of grind size and under three atmosphere conditions: fresh ground in air , after 24 hours of air exposure, or under N2 atmosphere. The feed and processed powders were analyzed by a variety of methods including moisture, ash, total sulfur, and pyritic sulfur content. Mass distribution and cumulative charge of the processed powders were also measured. Fresh ground coal performed the best in electrostatic beneficiation. Results are compared with those of similar studies conducted on Pittsburgh #8 powders last year (April 1, 1997 to September 30, 1997). Polystyrene latex spheres were charged and deposited onto coal particles that had been passed through the electrostatic separator and collected onto insulating filters. The observations suggest bipolar charging of individual particles and patches of charge on the particles which may be associated with particular maceral types or with mineral inclusions. A preliminary investigation was performed on eletrostatic separation of unburned carbon particles from flyash. Approximately 25% of the flyash acquired positive charge in the copper tribocharger. This compares with 75% of fresh ground coal. The negatively charged material had a slightly reduced ash content suggesting some enrichment of carbonaceous

Systems Analysis Of Advanced Coal-Based Power Plants

NASA Technical Reports Server (NTRS)

Ferrall, Joseph F.; Jennings, Charles N.; Pappano, Alfred W.

1988-01-01

Report presents appraisal of integrated coal-gasification/fuel-cell power plants. Based on study comparing fuel-cell technologies with each other and with coal-based alternatives and recommends most promising ones for research and development. Evaluates capital cost, cost of electricity, fuel consumption, and conformance with environmental standards. Analyzes sensitivity of cost of electricity to changes in fuel cost, to economic assumptions, and to level of technology. Recommends further evaluation of integrated coal-gasification/fuel-cell integrated coal-gasification/combined-cycle, and pulverized-coal-fired plants. Concludes with appendixes detailing plant-performance models, subsystem-performance parameters, performance goals, cost bases, plant-cost data sheets, and plant sensitivity to fuel-cell performance.

Advanced gasifier and water gas shift technologies for low cost coal conversion to high hydrogen syngas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kramer, Andrew Kramer

The Gas Technology Institute (GTI) and team members RTI International (RTI), Coanda Research and Development, and Nexant, are developing and maturing a portfolio of technologies to meet the United States Department of Energy (DOE) goals for lowering the cost of producing high hydrogen syngas from coal for use in carbon capture power and coal-to-liquids/chemicals. This project matured an advanced pilot-scale gasifier, with scalable and commercially traceable components, to readiness for use in a first-of-a-kind commercially-relevant demonstration plant on the scale of 500-1,000 tons per day (TPD). This was accomplished through cold flow simulation of the gasifier quench zone transition regionmore » at Coanda and through an extensive hotfire gasifier test program on highly reactive coal and high ash/high ash fusion temperature coals at GTI. RTI matured an advanced water gas shift process and catalyst to readiness for testing at pilot plant scale through catalyst development and testing, and development of a preliminary design basis for a pilot scale reactor demonstrating the catalyst. A techno-economic analysis was performed by Nexant to assess the potential benefits of the gasifier and catalyst technologies in the context of power production and methanol production. This analysis showed an 18%reduction in cost of power and a 19%reduction in cost of methanol relative to DOE reference baseline cases.« less

The Coal-Seq III Consortium. Advancing the Science of CO 2 Sequestration in Coal Seam and Gas Shale Reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koperna, George

The Coal-Seq consortium is a government-industry collaborative that was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO2 sequestration in deep, unmineable coal seams. The consortium’s objective aimed to advancing industry’s understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. Research from this collaborative effort was utilized to produce modules to enhance reservoir simulation and modeling capabilities to assess the technical and economic potential for CO2 storage and enhanced coalbed methane recovery in coal basins. Coal-Seq Phase 3more » expands upon the learnings garnered from Phase 1 & 2, which has led to further investigation into refined model development related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins the extension of the work to gas shale reservoirs, and continued global technology exchange. The first research objective assesses changes in coal and shale properties with exposure to CO2 under field replicated conditions. Results indicate that no significant weakening occurs when coal and shale were exposed to CO2, therefore, there was no need to account for mechanical weakening of coal due to the injection of CO2 for modeling. The second major research objective evaluates cleat, Cp, and matrix, Cm, swelling/shrinkage compressibility under field replicated conditions. The experimental studies found that both Cp and Cm vary due to changes in reservoir pressure during injection and depletion under field replicated conditions. Using laboratory data from this study, a compressibility model was developed to predict the pore-volume compressibility, Cp, and the matrix compressibility, Cm, of coal and shale, which was

Organic coal-water fuel: Problems and advances (Review)

NASA Astrophysics Data System (ADS)

Glushkov, D. O.; Strizhak, P. A.; Chernetskii, M. Yu.

2016-10-01

The study results of ignition of organic coal-water fuel (OCWF) compositions were considered. The main problems associated with investigation of these processes were identified. Historical perspectives of the development of coal-water composite fuel technologies in Russia and worldwide are presented. The advantages of the OCWF use as a power-plant fuel in comparison with the common coal-water fuels (CWF) were emphasized. The factors (component ratio, grinding degree of solid (coal) component, limiting temperature of oxidizer, properties of liquid and solid components, procedure and time of suspension preparation, etc.) affecting inertia and stability of the ignition processes of suspensions based on the products of coaland oil processing (coals of various types and metamorphism degree, filter cakes, waste motor, transformer, and turbine oils, water-oil emulsions, fuel-oil, etc.) were analyzed. The promising directions for the development of modern notions on the OCWF ignition processes were determined. The main reasons limiting active application of the OCWF in power generation were identified. Characteristics of ignition and combustion of coal-water and organic coal-water slurry fuels were compared. The effect of water in the composite coal fuels on the energy characteristics of their ignition and combustion, as well as ecological features of these processes, were elucidated. The current problems associated with pulverization of composite coal fuels in power plants, as well as the effect of characteristics of the pulverization process on the combustion parameters of fuel, were considered. The problems hindering the development of models of ignition and combustion of OCWF were analyzed. It was established that the main one was the lack of reliable experimental data on the processes of heating, evaporation, ignition, and combustion of OCWF droplets. It was concluded that the use of high-speed video recording systems and low-inertia sensors of temperature and gas

500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide emissions from coal-fired boilers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sorge, J.N.; Larrimore, C.L.; Slatsky, M.D.

1997-12-31

This paper discusses the technical progress of a US Department of Energy Innovative Clean Coal Technology project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The primary objectives of the demonstration is to determine the long-term NOx reduction performance of advanced overfire air (AOFA), low NOx burners (LNB), and advanced digital control optimization methodologies applied in a stepwise fashion to a 500 MW boiler. The focus of this paper is to report (1) on the installation of three on-line carbon-in-ash monitors and (2) the design and results to date from the advancedmore » digital control/optimization phase of the project.« less

Technology and development requirements for advanced coal conversion systems

NASA Technical Reports Server (NTRS)

1981-01-01

A compendium of coal conversion process descriptions is presented. The SRS and MC data bases were utilized to provide information paticularly in the areas of existing process designs and process evaluations. Additional information requirements were established and arrangements were made to visit process developers, pilot plants, and process development units to obtain information that was not otherwise available. Plant designs, process descriptions and operating conditions, and performance characteristics were analyzed and requirements for further development identified and evaluated to determine the impact of these requirements on the process commercialization potential from the standpoint of economics and technical feasibility. A preliminary methodology was established for the comparative technical and economic assessment of advanced processes.

Testing of advanced liquefaction concepts in HTI Run ALC-1: Coal cleaning and recycle solvent treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robbins, G.A.; Winschel, R.A.; Burke, F.P.

In 1991, the Department of Energy initiated the Advanced Liquefaction Concepts Program to promote the development of new and emerging technology that has potential to reduce the cost of producing liquid fuels by direct coal liquefaction. Laboratory research performed by researchers at CAER, CONSOL, Sandia, and LDP Associates in Phase I is being developed further and tested at the bench scale at HTI. HTI Run ALC-1, conducted in the spring of 1996, was the first of four planned tests. In Run ALC-1, feed coal ash reduction (coal cleaning) by oil agglomeration, and recycle solvent quality improvement through dewaxing and hydrotreatmentmore » of the recycle distillate were evaluated. HTI`s bench liquefaction Run ALC-1 consisted of 25 days of operation. Major accomplishments were: 1) oil agglomeration reduced the ash content of Black Thunder Mine coal by 40%, from 5.5% to 3.3%; 2) excellent coal conversion of 98% was obtained with oil agglomerated coal, about 3% higher than the raw Black Thunder Mine coal, increasing the potential product yield by 2-3% on an MAF coal basis; 3) agglomerates were liquefied with no handling problems; 4) fresh catalyst make-up rate was decreased by 30%, with no apparent detrimental operating characteristics, both when agglomerates were fed and when raw coal was fed (with solvent dewaxing and hydrotreating); 5) recycle solvent treatment by dewaxing and hydrotreating was demonstrated, but steady-state operation was not achieved; and 6) there was some success in achieving extinction recycle of the heaviest liquid products. Performance data have not been finalized; they will be available for full evaluation in the new future.« less

Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rader, Jeff; Aguilar, Kelly; Aldred, Derek

2012-11-30

This report describes the development of the design of an advanced dry feed system that was carried out under Task 4.0 of Cooperative Agreement DE-FE0007902 with the US DOE, “Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the use of Low- Rank Coal.” The resulting design will be used for the advanced technology IGCC case with 90% carbon capture for sequestration to be developed under Task 5.0 of the same agreement. The scope of work covered coal preparation and feeding up through the gasifier injector. Subcomponents have been broken down into feed preparation (including grindingmore » and drying), low pressure conveyance, pressurization, high pressure conveyance, and injection. Pressurization of the coal feed is done using Posimetric1 Feeders sized for the application. In addition, a secondary feed system is described for preparing and feeding slag additive and recycle fines to the gasifier injector. This report includes information on the basis for the design, requirements for down selection of the key technologies used, the down selection methodology and the final, down selected design for the Posimetric Feed System, or PFS.« less

78 FR 49061 - Valuation of Federal Coal for Advance Royalty Purposes and Information Collection Applicable to...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-12

... use available information technology (for example: Spreadsheet programs, i.e., Microsoft Excel, web...) 231- 3221, or by email at [email protected] . SUPPLEMENTARY INFORMATION: I. Background A. Pre... part 1218, subpart I, titled ``Federal Coal Advance Royalty.'' B. The EPAct On August 8, 2005, the...

Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 March 1995--31 May 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malhotra, V.M.; Wright, M.A.

1995-12-31

The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADM unit1-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM unit1-6), bottom ash, and scrubber sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whosemore » lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}0.5H{sub 2}O) phase. In the second and third quarters the focus of research has been on developing protocols for the formation of advanced brake composites and structural composites. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disks from coal combustion residues. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites.« less

Biosolubilization of coal by Candida in glucose limited cultures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mitter, J.; Guillory, L.; Bose, N.K.

1990-01-01

Coal biodegradation is attracting the attention of many workers because of its significance for efficient bioconversion of coal into useful chemicals. The authors work is based upon the beneficiation of a fungus (candida) on subbituminous coal. Candida was grown on both solid and liquid sabouraud medium and the coal solubilizing activity was studied at varying glucose concentration and temperature. Lower glucose concentration and higher temperature enhanced coal solubilizing activity by this fungus. Preliminary work has begun on analyzing organic extractions (alumina chromatography) of the liquid produced after microbial solubilization, including elemental analysis, solubility, molecular weights and chemical structure. This preliminarymore » work suggests that the candida could metabolize naturally occurring coal as substrate.« less

Naturally Occurring Radioactive Materials in Uranium-Rich Coals and Associated Coal Combustion Residues from China.

PubMed

Lauer, Nancy; Vengosh, Avner; Dai, Shifeng

2017-11-21

Most coals in China have uranium concentrations up to 3 ppm, yet several coal deposits are known to be enriched in uranium. Naturally occurring radioactive materials (NORM) in these U-rich coals and associated coal combustion residues (CCRs) have not been well characterized. Here we measure NORM (Th, U, 228 Ra, 226 Ra, and 210 Pb) in coals from eight U-rich coal deposits in China and the associated CCRs from one of these deposits. We compared NORM in these U-rich coals and associated CCRs to CCRs collected from the Beijing area and natural loess sediments from northeastern China. We found elevated U concentrations (up to 476 ppm) that correspond to low 232 Th/ 238 U and 228 Ra/ 226 Ra activity ratios (≪1) in the coal samples. 226 Ra and 228 Ra activities correlate with 238 U and 232 Th activities, respectively, and 226 Ra activities correlate well with 210 Pb activities across all coal samples. We used measured NORM activities and ash yields in coals to model the activities of CCRs from all U-rich coals analyzed in this study. The activities of measured and modeled CCRs derived from U-rich coals exceed the standards for radiation in building materials, particularly for CCRs originating from coals with U > 10 ppm. Since beneficial use of high-U Chinese CCRs in building materials is not a suitable option, careful consideration needs to be taken to limit potential air and water contamination upon disposal of U- and Ra-rich CCRs.

A Course in Coal Science and Technology.

ERIC Educational Resources Information Center

Wheelock, T. D.

1978-01-01

This course introduces graduate students and advanced undergraduates to coal science and technology. Topics include: (1) the nature and occurrence of coal, (2) its chemical and physical characteristics, (3) methods of cleaning and preparing coal, and (4) processes for converting coal into clean solid, liquid, and gaseous fuels, as well as coke.…

Proceedings of Office of Surface Mining Coal Combustion By-product Government/Regulatory Panel: University of Kentucky international ash utilization symposium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vories, K.C.

2003-07-01

Short papers are given on: the Coal Combustion Program (C2P2) (J. Glenn); regional environmental concerns with disposal of coal combustion wastes at mines (T. FitzGerald); power plant waste mine filling - an environmental perspective (L.G. Evans); utility industry perspective regarding coal combustion product management and regulation (J. Roewer); coal combustion products opportunities for beneficial use (D.C. Goss); state perspective on mine placement of coal combustion by-products (G.E. Conrad); Texas regulations provide for beneficial use of coal combustion ash (S.S. Ferguson); and the Surface Mining Control and Reclamation Act - a response to concerns about placement of CCBs at coal minemore » sites (K.C. Vories). The questions and answers are also included.« less

Enhancement of Operating Efficiency Of The Central Coal-Preparation Plant of "MMK - UGOL" Ltd. Under Current Conditions

NASA Astrophysics Data System (ADS)

Basarygin, Maksim

2017-11-01

In this article the subject of enhancement of operating efficiency of the central coal-preparation plant of OOO "MMK-UGOL" is encompassed. Modern trends in the development of technologies and equipment for coal beneficiation are due to the following requirements: improving competitiveness of coal products, improvement of quality of marketable products, reduction of coal production cost, environmental requirements: polluting emission abatement, prepared coal saving, improvement of the effectiveness of resource conservation; complex mechanization and beneficiation process automation. In the article the contemporary problems of raw coal benefication under current conditions of the increased dilution of withdrawable coals with rock fractions are considered. Comparative analysis of efficiency of application of modern concentrating equipment under the conditions of the CCPP of OOO "MMK-UGOL" is carried out on the basis of research works. Particular attention is paid to dehydration of produced coal concentrate with content of volatile agents of more than 35.0% and content of fine-dispersed particles in flotation concentrate of more than 50.0%. Comparative analysis of the coal concentrate dehydration technologies is conducted.

Leaching behavior of coal combustion products and the environmental implication in road construction.

DOT National Transportation Integrated Search

2011-04-01

Leaching of trace elements may raise environmental concerns when using coal fly ash in road construction. US EPA is in the process : of creating the first national rule on coal ash management, including beneficial use. Meanwhile, driven by the tighte...

Coal Combustion Science quarterly progress report, April--June 1992. Task 1, Coal devolatilization: Task 2, Coal char combustion; Task 3, Fate of mineral matter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hardesty, D.R.; Hurt, R.H.; Baxter, L.L.

1992-09-01

The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: The characterization of the physical and chemical processes that constitute the early devolatilization phase of coal combustion: Characterization of the combustion behavior of selected coals under conditions relevant to industria pulverized coal-fired furnaces; and to establish a quantitative understanding of themore » mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distributions of mineral species in the unreacted coal, and the local gas temperature and composition.« less

Technology for advanced liquefaction processes: Coal/waste coprocessing studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cugini, A.V.; Rothenberger, K.S.; Ciocco, M.V.

1995-12-31

The efforts in this project are directed toward three areas: (1) novel catalyst (supported and unsupported) research and development, (2) study and optimization of major operating parameters (specifically pressure), and (3) coal/waste coprocessing. The novel catalyst research and development activity has involved testing supported catalysts, dispersed catalysts, and use of catalyst testing units to investigate the effects of operating parameters (the second area) with both supported and unsupported catalysts. Several supported catalysts were tested in a simulated first stage coal liquefaction application at 404{degrees}C during this performance period. A Ni-Mo hydrous titanate catalyst on an Amocat support prepared by Sandiamore » National laboratories was tested. Other baseline experiments using AO-60 and Amocat, both Ni-Mo/Al{sub 2}O{sub 3} supported catalysts, were also made. These experiments were short duration (approximately 12 days) and monitored the initial activity of the catalysts. The results of these tests indicate that the Sandia catalyst performed as well as the commercially prepared catalysts. Future tests are planned with other Sandia preparations. The dispersed catalysts tested include sulfated iron oxide, Bayferrox iron oxide (iron oxide from Miles, Inc.), and Bailey iron oxide (micronized iron oxide from Bailey, Inc.). The effects of space velocity, temperature, and solvent-to-coal ratio on coal liquefaction activity with the dispersed catalysts were investigated. A comparison of the coal liquefaction activity of these catalysts relative to iron catalysts tested earlier, including FeOOH-impregnated coal, was made. These studies are discussed.« less

Rosebud SynCoal Partnership, SynCoal{reg_sign} demonstration technology update

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sheldon, R.W.

1997-12-31

An Advanced Coal Conversion Process (ACCP) technology being demonstrated in eastern Montana (USA) at the heart of one of the world`s largest coal deposits is providing evidence that the molecular structure of low-rank coals can be altered successfully to produce a unique product for a variety of utility and industrial applications. The product is called SynCoal{reg_sign} and the process has been developed by the Rosebud SynCoal Partnership (RSCP) through the US Department of Energy`s multi-million dollar Clean Coal Technology Program. The ACCP demonstration process uses low-pressure, superheated gases to process coal in vibrating fluidized beds. Two vibratory fluidized processing stagesmore » are used to heat and convert the coal. This is followed by a water spray quench and a vibratory fluidized stage to cool the coal. Pneumatic separators remove the solid impurities from the dried coal. There are three major steps to the SynCoal{reg_sign} process: (1) thermal treatment of the coal in an inert atmosphere, (2) inert gas cooling of the hot coal, and (3) removal of ash minerals. When operated continuously, the demonstration plant produces over 1,000 tons per day (up to 300,000 tons per year) of SynCoal{reg_sign} with a 2% moisture content, approximately 11,800b Btu/lb and less than 1.0 pound of SO{sub 2} per million Btu. This product is obtained from Rosebud Mine sub-bituminous coal which starts with 25% moisture, 8,600 Btu/lb and approximately 1.6 pounds of SO{sub 2} per million Btu.« less

Development of advanced capitalism: a case study of retired coal miners in southern West Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Legeay, S.P.

1980-01-01

This dissertation develops a critical analysis of changes in American society during the last fifty years. It is focused in particular on the southern West Virginia coal fields, and examines the changes in class structure (specifically, coal miners), the labor process, the union, class consciousness, community and leisure. The study is grounded within a theoretical perspective that is dialectical. It is concerned with the interaction between specific social categories (such as the union) and the greater whole of capitalist development. It is centrally concerned with continuing a research orientation to which the Frankfurt School gave a powerful contribution: the developmentmore » of advanced capitalism in the modern epoch. The study utilizes life-history interviews with retired coal miners, almost all of whom had experience with the exploitive company towns of an earlier time. Thus, techniques for the study of oral history are instrumental in developing an analysis of social developments, inasmuch as they provide data appropriate for an analysis of the transformation from early to late capitalism. Finally, this dissertation examines a problem central to dialectical theory, that of the relation between theory and praxis, by approaching the life histories as exemplifications of collective (i.e., social) experience. It integrates the biographical experience of individual miners with the theoretical dimensions of political economy in early and late capitalism. The current crisis in the coal fields is examined, with a view to possible transformation.« less

Advanced geophysical underground coal gasification monitoring

DOE PAGES

Mellors, Robert; Yang, X.; White, J. A.; ...

2014-07-01

Underground Coal Gasification (UCG) produces less surface impact, atmospheric pollutants and greenhouse gas than traditional surface mining and combustion. Therefore, it may be useful in mitigating global change caused by anthropogenic activities. Careful monitoring of the UCG process is essential in minimizing environmental impact. Here we first summarize monitoring methods that have been used in previous UCG field trials. We then discuss in more detail a number of promising advanced geophysical techniques. These methods – seismic, electromagnetic, and remote sensing techniques – may provide improved and cost-effective ways to image both the subsurface cavity growth and surface subsidence effects. Activemore » and passive seismic data have the promise to monitor the burn front, cavity growth, and observe cavity collapse events. Electrical resistance tomography (ERT) produces near real time tomographic images autonomously, monitors the burn front and images the cavity using low-cost sensors, typically running within boreholes. Interferometric synthetic aperture radar (InSAR) is a remote sensing technique that has the capability to monitor surface subsidence over the wide area of a commercial-scale UCG operation at a low cost. It may be possible to infer cavity geometry from InSAR (or other surface topography) data using geomechanical modeling. The expected signals from these monitoring methods are described along with interpretive modeling for typical UCG cavities. They are illustrated using field results from UCG trials and other relevant subsurface operations.« less

Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Chen

2014-04-01

The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions.

CoalVal-A coal resource valuation program

USGS Publications Warehouse

Rohrbacher, Timothy J.; McIntosh, Gary E.

2010-01-01

CoalVal is a menu-driven Windows program that produces cost-of-mining analyses of mine-modeled coal resources. Geological modeling of the coal beds and some degree of mine planning, from basic prefeasibility to advanced, must already have been performed before this program can be used. United States Geological Survey mine planning is done from a very basic, prefeasibility standpoint, but the accuracy of CoalVal's output is a reflection of the accuracy of the data entered, both for mine costs and mine planning. The mining cost analysis is done by using mine cost models designed for the commonly employed, surface and underground mining methods utilized in the United States. CoalVal requires a Microsoft Windows? 98 or Windows? XP operating system and a minimum of 1 gigabyte of random access memory to perform operations. It will not operate on Microsoft Vista?, Windows? 7, or Macintosh? operating systems. The program will summarize the evaluation of an unlimited number of coal seams, haulage zones, tax entities, or other area delineations for a given coal property, coalfield, or basin. When the reader opens the CoalVal publication from the USGS website, options are provided to download the CoalVal publication manual and the CoalVal Program. The CoalVal report is divided into five specific areas relevant to the development and use of the CoalVal program: 1. Introduction to CoalVal Assumptions and Concepts. 2. Mine Model Assumption Details (appendix A). 3. CoalVal Project Tutorial (appendix B). 4. Program Description (appendix C). 5. Mine Model and Discounted Cash Flow Formulas (appendix D). The tutorial explains how to enter coal resource and quality data by mining method; program default values for production, operating, and cost variables; and ones own operating and cost variables into the program. Generated summary reports list the volume of resource in short tons available for mining, recoverable short tons by mining method; the seam or property being mined

An Evaluation of Coal Water Slurry Fuel Burners and Technology

DTIC Science & Technology

1992-11-01

treatment) processes, such as froth flotation , which reduce ash and pyritic sulphur content (4). Unlike pulverized coal, there is no need for expensive drying...physical beneficiation (froth flotation ) to reduce pyrite , biotechnological and other methods to remove more sulfur (especially the organic portion...of limited effectiveness since only some of the pyritic sulfur (about 40 to 60 percent of the total sulfur) is removed for some coals, since 90 to 95

Co-firing coal and biomass blends and their influence on the post-combustion CO2 capture installation

NASA Astrophysics Data System (ADS)

Więckol-Ryk, Angelika; Smoliński, Adam

2017-10-01

Co-firing of biomass with coal for energy production is a well-known technology and plays an important role in the electricity sector. The post-combustion capture integrated with biomass-fired power plants (Bio-CCS) seems to be a new alternative for reducing greenhouse gas emissions. This study refers to the best known and advanced technology for post-combustion CO2 capture (PCC) based on a chemical absorption in monoethanolamine (MEA). The co-firing of hard coal with four types of biomass was investigated using a laboratory fixed bed reactor system. The comparison of gaseous products emitted from the combustion of coal and different biomass blends were determined using gas chromatography. Research proved that co-firing of biomass in fossil fuel power plants is beneficial for PCC process. It may also reduce the corrosion of CO2 capture installation. The oxygen concentration in the flue gases from hard coal combustion was comparable with the respective value for a fuel blend of biomass content of 20% w/w. It was also noted that an increase in biomass content in a sample from 20 to 40 % w/w increased the concentration of oxygen in the flue gas streams. However, this concentration should not have a significant impact on the rate of amine oxidative degradation.

Separation and Purification of Mineral Salts from Spacecraft Wastewater Processing via Electrostatic Beneficiation

NASA Technical Reports Server (NTRS)

Miles, John D., II; Lunn, Griffin

2013-01-01

Electrostatic separation is a class of material processing technologies commonly used for the sorting of coarse mixtures by means of electrical forces acting on charged or polarized particles. Most if not all of the existing tribo-electrostatic separators had been initially developed for mineral ores beneficiation. It is a well-known process that has been successfully used to separate coal from minerals. Potash (potassium) enrichment where underground salt mines containing large amounts of sodium is another use of this techno logy. Through modification this technology can be used for spacecraft wastewater brine beneficiation. This will add in closing the gap beeen traveling around Earth's Gravity well and long-term space explorations. Food has been brought on all man missions, which is why plant growth for food crops continues to be of interest to NASA. For long-term mission considerations food productions is one of the top priorities. Nutrient recovery is essential for surviving in or past low earth orbit. In our advance bio-regenerative process instead of nitrogen gas produced; soluble nitrate salts that can be recovered for plant fertilizer would be produced instead. The only part missing is the beneficiation of brine to separate the potassium from the sodium. The use of electrostatic beneficiation in this experiment utilizes the electrical charge differences between aluminum and dried brine by surface contact. The helixes within the aluminum tribocharger allows for more surface contact when being agitated. When two materials are in contact, the material with the highest affinity for electrons becomes negatively charged, while the other becomes positively charged. This contact exchange of charge may cause the particles to agglomerate depending on their residence time within the tribocharger, compromising the efficiency of separation. The aim of this experiment is to further the development in electrostatic beneficiation by optimizing the separation of ersatz and

Measurement and modeling of advanced coal conversion processes, Volume II

DOE Office of Scientific and Technical Information (OSTI.GOV)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

1993-06-01

A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

Geochemical database of feed coal and coal combustion products (CCPs) from five power plants in the United States

USGS Publications Warehouse

Affolter, Ronald H.; Groves, Steve; Betterton, William J.; William, Benzel; Conrad, Kelly L.; Swanson, Sharon M.; Ruppert, Leslie F.; Clough, James G.; Belkin, Harvey E.; Kolker, Allan; Hower, James C.

2011-01-01

The principal mission of the U.S. Geological Survey (USGS) Energy Resources Program (ERP) is to (1) understand the processes critical to the formation, accumulation, occurrence, and alteration of geologically based energy resources; (2) conduct scientifically robust assessments of those resources; and (3) study the impacts of energy resource occurrence and (or) their production and use on both the environment and human health. The ERP promotes and supports research resulting in original, geology-based, non-biased energy information products for policy and decision makers, land and resource managers, other Federal and State agencies, the domestic energy industry, foreign governments, non-governmental groups, and academia. Investigations include research on the geology of oil, gas, and coal, and the impacts associated with energy resource occurrence, production, quality, and utilization. The ERP's focus on coal is to support investigations into current issues pertaining to coal production, beneficiation and (or) conversion, and the environmental impact of the coal combustion process and coal combustion products (CCPs). To accomplish these studies, the USGS combines its activities with other organizations to address domestic and international issues that relate to the development and use of energy resources.

Thiophenic Sulfur Compounds Released During Coal Pyrolysis

PubMed Central

Xing, Mengwen; Kong, Jiao; Dong, Jie; Jiao, Haili; Li, Fan

2013-01-01

Abstract Thiophenic sulfur compounds are released during coal gasification, carbonization, and combustion. Previous studies indicate that thiophenic sulfur compounds degrade very slowly in the environment, and are more carcinogenic than polycyclic aromatic hydrocarbons and nitrogenous compounds. Therefore, it is very important to study the principle of thiophenic sulfur compounds during coal conversion, in order to control their emission and promote clean coal utilization. To realize this goal and understand the formation mechanism of thiophenic sulfur compounds, this study focused on the release behavior of thiophenic sulfur compounds during coal pyrolysis, which is an important phase for all coal thermal conversion processes. The pyrolyzer (CDS-5250) and gas chromatography–mass spectrometry (Focus GC-DSQII) were used to analyze thiophenic sulfur compounds in situ. Several coals with different coal ranks and sulfur contents were chosen as experimental samples, and thiophenic sulfur compounds of the gas produced during pyrolysis under different temperatures and heating rates were investigated. Levels of benzothiophene and dibenzothiophene were obtained during pyrolysis at temperatures ranging from 200°C to 1300°C, and heating rates ranging from 6°C/ms to 14°C/ms and 6°C/s to 14°C/s. Moreover, the relationship between the total amount of benzothiophene and dibenzothiophene released during coal pyrolysis and the organic sulfur content in coal was also discussed. This study is beneficial for understanding the formation and control of thiophenic sulfur compounds, since it provides a series of significant results that show the impact that operation conditions and organic sulfur content in coal have on the amount and species of thiophenic sulfur compounds produced during coal pyrolysis. PMID:23781126

Flotation of oil-agglomerated coal for ash and pyrite removal -- Simultaneous grinding and agglomeration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Song, S.; Perkson, A.; Trass, O.

1996-12-31

Oil agglomeration is an excellent technique for the beneficiation of fine coal. For separation of the spherical agglomerates by screening, a high level of oil must be used, however. When the subsequent separation is done by flotation, this disadvantage is eliminated. Better pyrite removal is also possible. In this paper, such a fine coal beneficiation process, also called hydrophobic flocculation-flotation (HFF), is described. It features low non-polar oil consumption, intensive mechanical energy input, and smaller agglomerates or looser flocs. This process can be simplified by grinding the coal in water with small amounts of oil added. The excess grinding energymore » is then used for agglomerating the coal. The Prince coal from Nova Scotia contained 13.3% ash and 3.3% total sulfur, 1.4% pyritic. After four stages of flotation, ash and pyrite removal were 93% and 66% respectively, with 87% combustibles recovery. The parameters affecting the HFF process, such as particle size, dosage of non-polar oil, pH value of the slurry and duration of agitation, were investigated. Simultaneous grinding and agglomeration (SGA) utilizing the Szego Mill was also explored at the very low oil levels used. The intensive agitation/preconditioning step prior to flotation was eliminated. When the other parameters established from the sequential process were used with the SGA process, virtually identical beneficiation results were obtained, but with slightly lower combustibles recovery. While further testing is required to properly optimize the SGA process conditions, significant equipment simplification and energy savings are possible.« less

Arsenic and lead concentrations in the Pond Creek and Fire Clay coal beds, eastern Kentucky coal field

USGS Publications Warehouse

Hower, J.C.; Robertson, J.D.; Wong, A.S.; Eble, C.F.; Ruppert, L.F.

1997-01-01

The Middle Pennsylvanian Breathitt Formation (Westphalian B) Pond Creek and Fire Clay coal beds are the 2 largest producing coal beds in eastern Kentucky. Single channel samples from 22 localities in the Pond Creek coal bed were obtained from active coal mines in Pike and Martin Countries, Kentucky, and a total of 18 Fire Clay coal bed channel samples were collected from localities in the central portion of the coal field. The overall objective of this study was to investigate the concentration and distribution of potentially hazardous elements in the Fire Clay and Pond Creek coal beds, with particular emphasis on As and Pb, 2 elements that are included in the 1990 Clean Air Act Amendments as potential air toxics. The 2 coals are discussed individually as the depositional histories are distinct, the Fire Clay coal bed having more sites where relatively high-S lithologies are encountered. In an effort to characterize these coals, 40 whole channel samples, excluding 1-cm partings, were analyzed for major, minor and trace elements by X-ray fluorescence and proton-induced X-ray emission spectroscopy. Previously analyzed samples were added to provide additional geographic coverage and lithotype samples from one site were analyzed in order to provide detail of vertical elemental trends. The As and Pb levels in the Fire Clay coal bed tend to be higher than in the Pond Creek coal bed. One whole channel sample of the Fire Clay coal bed contains 1156 ppm As (ash basis), with a single lithotype containing 4000 ppm As (ash basis). Most of the As and Pb appears to be associated with pyrite, which potentially can be removed in beneficiation (particularly coarser pyrite). Disseminated finer pyrite may not be completely removable by cleaning. In the examination of pyrite conducted in this study, it does not appear that significant concentration of As or Pb occurs in the finer pyrite forms. The biggest potential problem of As- or Pb-enriched pyrite is, therefore, one of refuse

Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 December 1994--28 February 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malhotra, V.M.; Wright, M.A.

1995-12-31

The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. During the first two quarters of the project, the thrust of the work directed towards characterizing the various coal combustion residues and FGD residue, i.e., scrubber sludge. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADK unit l-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM, unit l-6), bottom ash, and scrubbermore » sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whose lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}.0.5H{sub 2}O) phase. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disk,- from coal combustion residues. This has been achieved. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites. Also, these results along with mechanical behavior of the fabricated disks lead us to believe that the combination of surface altered PCC fly ash and scrubber sludge particles, together ed ash particles are ideal for our composite materials.« less

LIBS Analysis for Coal

NASA Astrophysics Data System (ADS)

E. Romero, Carlos; De Saro, Robert

Coal is a non-uniform material with large inherent variability in composition, and other important properties, such as calorific value and ash fusion temperature. This quality variability is very important when coal is used as fuel in steam generators, since it affects boiler operation and control, maintenance and availability, and the extent and treatment of environmental pollution associated with coal combustion. On-line/in situ monitoring of coal before is fed into a boiler is a necessity. A very few analytical techniques like X-ray fluorescence and prompt gamma neutron activation analysis are available commercially with enough speed and sophistication of data collection for continuous coal monitoring. However, there is still a need for a better on-line/in situ technique that has higher selectivity, sensitivity, accuracy and precision, and that is safer and has a lower installation and operating costs than the other options. Laser induced breakdown spectroscopy (LIBS) is ideal for coal monitoring in boiler applications as it need no sample preparation, it is accurate and precise it is fast, and it can detect all of the elements of concern to the coal-fired boiler industry. LIBS data can also be adapted with advanced data processing techniques to provide real-time information required by boiler operators nowadays. This chapter summarizes development of LIBS for on-line/in situ coal applications in utility boilers.

US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennis, R.A.

1997-05-01

The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systemsmore » has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.« less

Mercury in Eastern Kentucky coals: Geologic aspects and possible reduction strategies

USGS Publications Warehouse

Hower, J.C.; Eble, C.F.; Quick, J.C.

2005-01-01

Mercury emissions from US coal-fired power plants will be regulated by the US Environmental Protection Agency (USEPA) before the end of the decade. Because of this, the control of Hg in coal is important. Control is fundamentally based on the knowledge of the amounts of Hg in mined, beneficiated, and as-fired coal. Eastern Kentucky coals, on a reserve district level, have Hg contents similar to the USA average for coal at mines. Individual coals show greater variation at the bench scale, with Hg enrichment common in the top bench, often associated with enhanced levels of pyritic sulfur. Some of the variation between parts of eastern Kentucky is also based on the position relative to major faults. The Pine Mountain thrust fault appears to be responsible for elemental enrichment, including Hg, in coals on the footwall side of the thrust. Eastern Kentucky coals shipped to power plants in 1999, the year the USEPA requested coal quality information on coal deliveries, indicate that coals shipped from the region have 0.09 ppm Hg, compared to 0.10 ppm for all delivered coals in the USA. On an equal energy basis, and given equal concentrations of Hg, the high volatile bituminous coals from eastern Kentucky would emit less Hg than lower rank coals from other USA regions. ?? 2005 Elsevier B.V. All rights reserved.

500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Public design report (preliminary and final)

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-07-01

This Public Design Report presents the design criteria of a DOE Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of NO{sub x} emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 (500 MW) near Rome, Georgia. The technologies being demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NO{sub x} burner. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NO{submore » x} burners, advanced overfire systems, and digital control system.« less

In Brief: Coal mining regulations

NASA Astrophysics Data System (ADS)

Showstack, Randy

2009-12-01

The U.S. Department of the Interior (DOI) announced on 18 November measures to strengthen the oversight of state surface coal mining programs and to promulgate federal regulations to protect streams affected by surface coal mining operations. DOI's Office of Surface Mining Reclamation and Enforcement (OSM) is publishing an advance notice of a proposed rule about protecting streams from adverse impacts of surface coal mining operations. A rule issued by the Bush administration in December 2008 allows coal mine operators to place excess excavated materials into streams if they can show it is not reasonably possible to avoid doing so. “We are moving as quickly as possible under the law to gather public input for a new rule, based on sound science, that will govern how companies handle fill removed from mountaintop coal seams,” according to Wilma Lewis, assistant secretary for Land and Minerals Management at DOI.

Requirements for the conceptual design of advanced underground coal extraction systems

NASA Technical Reports Server (NTRS)

Gangal, M. D.; Lavin, M. L.

1981-01-01

Conceptual design requirements are presented for underground coal mining systems having substantially improved performance in the areas of production cost and miner safety. Mandatory performance levels are also set for miner health, environmental impact, and coal recovery. In addition to mandatory design goals and constraints, a number of desirable system characteristics are identified which must be assessed in terms of their impact on production cost and their compatibility with other system elements. Although developed for the flat lying, moderately thick seams of Central Appalachia, these requirements are designed to be easily adaptable to other coals.

Optical Tracker For Longwall Coal Shearer

NASA Technical Reports Server (NTRS)

Poulsen, Peter D.; Stein, Richard J.; Pease, Robert E.

1989-01-01

Photographic record yields information for correction of vehicle path. Tracking system records lateral movements of longwall coal-shearing vehicle. System detects lateral and vertical deviations of path of vehicle moving along coal face, shearing coal as it goes. Rides on rails in mine tunnel, advancing on toothed track in one of rails. As vehicle moves, retroreflective mirror rides up and down on teeth, providing series of pulsed reflections to film recorder. Recorded positions of pulses, having horizontal and vertical orientations, indicate vertical and horizontal deviations, respectively, of vehicle.

Prediction of coal grindability from exploration data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gomez, M.; Hazen, K.

1970-08-01

A general prediction model for the Hardgrove grindability index was constructed from 735 coal samples using the proximate analysis, heating value, and sulfur content. The coals used to develop the general model ranged in volatile matter from 12.8 to 49.2 percent, dry basis, and had grindability indexes ranging from 35 to 121. A restricted model applicable to bituminous coals having grindabilities in the 40 to 110 range was developed from the proximate analysis and the petrographic composition of the coal. The prediction of coal grindability within a single seam was also investigated. The results reported support the belief that mechanicalmore » properties of the coal are related to both chemical and petrographic factors of the coal. The mechanical properties coal may be forecast in advance of mining, because the variables used as input to the prediction models can be measured from drill core samples collected during exploration.« less

Congress examines administration's coal research priorities

NASA Astrophysics Data System (ADS)

Showstack, Randy

2011-10-01

While the Obama administration has proposed a shift in coal research funding to further emphasize carbon capture and sequestration (CCS) programs in its fiscal year (FY) 2012 budget request, Republicans and several witnesses at a 13 October hearing of a subcommittee of the House of Representatives' Committee on Science, Space, and Technology questioned those priorities, called for additional federal funding for coal research, and defended the use of coal as a major part of the U.S. energy sector. The administration's FY 2012 budget requests 291.4 million to fund the Department of Energy's (DOE) CCS and power systems program while zeroing out funding for DOE's fuels and power systems program (which includes funding for coal research) and shifting some of its line items to the CCS program. The FY 2011 continuing resolution has funded the fuels and power systems program at 400.2 million, including 142 million for carbon sequestration, 64.8 million for innovations for existing plants, and funding for other subprograms such as advanced integrated gasification combined cycle (52.9 million), fuel cells (49.8 million), and advanced research ($47.6 million).

Method for processing coal-enrichment waste with solid and volatile fuel inclusions

NASA Astrophysics Data System (ADS)

Khasanova, A. V.; Zhirgalova, T. B.; Osintsev, K. V.

2017-10-01

The method relates to the field of industrial heat and power engineering. It can be used in coal preparation plants for processing coal waste. This new way is realized to produce a loose ash residue directed to the production of silicate products and fuel gas in rotary kilns. The proposed method is associated with industrial processing of brown coal beneficiation waste. Waste is obtained by flotation separation of rock particles up to 13 mm in size from coal particles. They have in their composition both solid and volatile fuel inclusions (components). Due to the high humidity and significant rock content, low heat of combustion, these wastes are not used on energy boilers, they are stored in dumps polluting the environment.

Coal Utilization in Schools: Issues and Answers.

ERIC Educational Resources Information Center

Pusey, Robert H.

Coal, at one-third the cost of natural gas and one-fifth the cost of oil, is our cheapest source of energy and is also in abundant supply. Because of significant technological advances, coal-fired equipment now approaches the clean and automatic operational characteristics of gas- and oil-fired boilers. For these reasons, and because schools are…

Fungal degradation of coal as a pretreatment for methane production

USGS Publications Warehouse

Haider, Rizwan; Ghauri, Muhammad A.; SanFilipo, John R.; Jones, Elizabeth J.; Orem, William H.; Tatu, Calin A.; Akhtar, Kalsoom; Akhtar, Nasrin

2013-01-01

Coal conversion technologies can help in taking advantage of huge low rank coal reserves by converting those into alternative fuels like methane. In this regard, fungal degradation of coal can serve as a pretreatment step in order to make coal a suitable substrate for biological beneficiation. A fungal isolate MW1, identified as Penicillium chrysogenum on the basis of fungal ITS sequences, was isolated from a core sample of coal, taken from a well drilled by the US. Geological Survey in Montana, USA. The low rank coal samples, from major coal fields of Pakistan, were treated with MW1 for 7 days in the presence of 0.1% ammonium sulfate as nitrogen source and 0.1% glucose as a supplemental carbon source. Liquid extracts were analyzed through Excitation–Emission Matrix Spectroscopy (EEMS) to obtain qualitative estimates of solubilized coal; these analyses indicated the release of complex organic functionalities. In addition, GC–MS analysis of these extracts confirmed the presence of single ring aromatics, polyaromatic hydrocarbons (PAHs), aromatic nitrogen compounds and aliphatics. Subsequently, the released organics were subjected to a bioassay for the generation of methane which conferred the potential application of fungal degradation as pretreatment. Additionally, fungal-mediated degradation was also prospected for extracting some other chemical entities like humic acids from brown coals with high huminite content especially from Thar, the largest lignite reserve of Pakistan.

World market: A survey of opportunities for advanced coal-fired systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holt, N.A.H.

1995-06-01

Although there is a wide range of forecasts for the future of World energy demand and consumption over the next 25 years, all forecasts show marked increases being required for all forms of fossil fuels even when optimistic projections are made for the future adoption of Nuclear and Renewable energy. It is also generally expected that coal usage will in this period experience its greatest growth (a doubling) in the Asia-Pacific region dominated demographically by China and India. In this paper, energy projections and the extent and nature of the coal reserves available worldwide are examined. While most coal technologiesmore » can handle a variety of feedstocks, there are often economic factors that will determine the preferred selection. The matching of technology to coal type and other factors is examined with particular reference to the Asia Pacific region. Oil usage is similarly forecast to experience a comparable growth in this region. Over 70% of the World`s oil reserves are heavy oils and refinery crudes are increasing in gravity and sulfur content. The clean coal technologies of gasification and fluid bed combustion can also use low value petroleum residuals as feedstocks. There is therefore a nearer term market opportunity to incorporate such technologies into cogeneration and coproduction schemes adjacent to refineries resulting in extremely efficient use of these resources.« less

Coal cleaning: An underutilized solution?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Godfrey, R.L.

1995-12-31

Custom Coals Corporation is based in Pittsburgh, Pennsylvania. It is involved in the construction and operation of advanced coal cleaning facilities. The company has initially chosen to focus on Pennsylvania`s vast reserves of coal, because these coal provide a superior feedstock for the Technology. In a $76 million project co-sponsored by the U.S. Department of Energy, Custom Coals is constructing its first coal cleaning facility. The DOE chose to participate with the company in the project pursuant to a competition it sponsored under Round IV of Its Clean Cod Technology program. Thirty-one companies submitted 33 projects seeking approximately $2.3 billionmore » of funding against the $600 million available. The company`s project was one of nine proposals accepted and was the only pre-combustion cleaning technology awarded. The project includes both the construction of a 500 ton per hour coal cleaning facility utilizing the company`s proprietary technologies and a series of power plant test bums on a variety of U.S. coals during a 12-month demonstration program. Three U.S. coal seams - Sewickley, Lower Freeport and Illinois No. 5 - will supply the initial feedstock for the demonstration project. These seams represent a broad range of raw cod qualifies. The processed coals will then be distributed to a number of generating stations for combustion. The 300 megawatt Martins Creek Plant of Pennsylvania Power & Light Co., near Allentown, Pennsylvania, will burn Carefree Coal, the 60 megawatt Whitewater Valley Power Station of Richmond Power and Light (in Indiana) and the Ashtabula, Ohio unit of Centerior Energy will burn Self-Scrubbing Coal. Following these demonstrations, the plant will begin full-scale commercial operation, providing two million tons of Pennsylvania compliance coals to electric power utilities.« less

Abstracts and research accomplishments of university coal research projects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-06-01

The Principal Investigators of the grants supported by the University Coal Research Program were requested to submit abstracts and highlight accomplishments of their projects in time for distribution at a grantees conference. This book is a compilation of the material received in response to the request. Abstracts discuss the following area: coal science, coal surface science, reaction chemistry, advanced process concepts, engineering fundamentals and thermodynamics, environmental science.

The Wasatch Plateau coal field, Utah

USGS Publications Warehouse

Spieker, Edmund M.

1931-01-01

The Wasatch Plateau, the northeasternmost of the great group of high plateaus in central and southern Utah, is underlain by a succession of Cretaceous rocks that, contain valuable coal beds, and the eastern part of the plateau, in which the coal is accessible, is generally known as the Wasatch Plateau coal field. This field and its continuation east of Price River the Book Cliffs coal field contain excellent coal of bituminous rank and together form the largest and most productive coal area in Utah. Coal from these fields has long been highly esteemed by users of western fuels and commands an important position in the fuel markets of the West.Mining of the coal began in a small way with the earliest settlements in this part of Utah. As population increased and transcontinental railroads were built, large mines were, opened and commercial development has advanced until at the present time most of the places accessible by existing railroads are the scenes of large mining enterprises, and the volume of coal passing out to the fuel-consuming centers of the West has reached an annual average of about 4,800,000 tons. The area now undergoing exploitation, however, is small compared with the part yet undeveloped, and the present examination of the field has shown clearly that the great bulk of its coal remains, constituting a reserve of many millions of tons.

Advanced direct coal liquefaction concepts. Quarterly report, January 1, 1994--March 31, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, D.J.; Parker, R.J.; Simpson, P.L.

A detailed evaluation of the bench unit data on Black Thunder feedstocks was completed. The results show that in a once-through operation using counterflow, reactor technology coal conversions in excess of 90% could be obtained, giving distillable oil yields in the range 60--65 wt % on MAF coal. The remaining non-distillable oil fraction which represents 20--25 wt % on MAF coal is a source of additional distillable oil in further processing, for example, bottoms recycle operation. C{sub 1}-C{sub 3} gas yields were generally in the order of 6--8 wt %. In autoclave studies, Illinois No. 6 coal was found tomore » be much less reactive than Black Thunder coal, and did not respond well to solubilization with carbon monoxide/steam. Process severity was, therefore, increased for bench unit operations on Illinois No. 6 coal, and work has concentrated on the use of hydrogen rather than carbon monoxide for solubilization. Preliminary coking studies on the resid from bench unit runs on Black Thunder coal were also carried out. Distillable liquid yields of 55--60 wt % were obtained. The technical and economic study to be carried out by Kilborn Engineering Company has been initiated.« less

Process for blending coal with water immiscible liquid

DOEpatents

Heavin, Leonard J.; King, Edward E.; Milliron, Dennis L.

1982-10-26

A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

Advanced technology applications for second and third general coal gasification systems

NASA Technical Reports Server (NTRS)

Bradford, R.; Hyde, J. D.; Mead, C. W.

1980-01-01

The historical background of coal conversion is reviewed and the programmatic status (operational, construction, design, proposed) of coal gasification processes is tabulated for both commercial and demonstration projects as well as for large and small pilot plants. Both second and third generation processes typically operate at higher temperatures and pressures than first generation methods. Much of the equipment that has been tested has failed. The most difficult problems are in process control. The mechanics of three-phase flow are not fully understood. Companies participating in coal conversion projects are ordering duplicates of failure prone units. No real solutions to any of the significant problems in technology development have been developed in recent years.

In-plant testing of a novel coal cleaning circuit using advanced technologies. Final technical report, September 1, 1995--August 31, 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Honaker, R.Q.; Reed, S.; Mohanty, M.K.

1997-05-01

A circuit comprised of advanced fine coal cleaning technologies was evaluated in an operating preparation plant to determine circuit performance and to compare the performance with current technologies used to treat -16 mesh fine coal. The circuit integrated a Floatex hydrosizer, a Falcon enhanced gravity concentrator and a Jameson flotation cell. A Packed-Column was used to provide additional reductions in the pyritic sulfur and ash contents by treatment of the Floatex-Falcon-Jameson circuit product. For a low sulfur Illinois No. 5 coal, the pyritic sulfur content was reduced from 0.67% to 0.34% at a combustible recovery of 93.2%. The ash contentmore » was decreased from 27.6% to 5.84%, which equates to an organic efficiency of 95% according to gravity-based washability data. The separation performance achieved on a high sulfur Illinois No. 5 coal resulted in the rejection of 72.7% of the pyritic sulfur and 82.3% of the ash-forming material at a recovery of 8 1 %. Subsequent pulverization of the cleaned product and retreatment in a Falcon concentrator and Packed-Column resulted in overall circuit ash and pyritic sulfur rejections of 89% and 93%, respectively, which yielded a pyritic sulfur content reduction from 2.43% to 0.30%. This separation reduced the sulfur dioxide emission rating of an Illinois No. 5 coal from 6.21 to 1.75 lbs SO{sub 2}/MBTU, which is Phase I compliance coal. A comparison of the results obtained from the Floatex-Falcon-Jameson circuit with those of the existing circuit revealed that the novel fine coal circuit provides 10% to 20% improvement in mass yield to the concentrate while rejecting greater amounts of ash and pyritic sulfur.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, S. P.N.; Peterson, G. R.

Coal beneficiation is a generic term used for processes that prepare run-of-mine coal for specific end uses. It is also referred to as coal preparation or coal cleaning and is a means of reducing the sulfur and the ash contents of coal. Information is presented regarding current and potential coal beneficiation processes. Several of the processes reviewed, though not yet commercial, are at various stages of experimental development. Process descriptions are provided for these processes commensurate with the extent of information and time available to perform the evaluation of these processes. Conceptual process designs, preliminary cost estimates, and economic evaluationsmore » are provided for the more advanced (from a process development hierarchy viewpoint) processes based on production levels of 1500 and 15,000 tons/day (maf) of cleaned product coal. Economic evaluations of the coal preparation plants are conducted for several project financing schemes and at 12 and 15% annual after-tax rates of return on equity capital. A 9% annual interest rate is used on the debt fraction of the plant capital. Cleaned product coal prices are determined using the discounted cash flow procedure. The study is intended to provide information on publicly known coal beneficiation processes and to indicate the relative costs of various coal beneficiation processes. Because of severe timeconstraints, several potential coal beneficiation processes are not evaluated in great detail. It is recommended that an additional study be conducted to complement this study and to more fully appreciate the potentially significant role of coal beneficiation in the clean burning of coal.« less

Coal Combustion Science quarterly progress report, April--June 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hardesty, D.R.; Hurt, R.H.; Baxter, L.L.

1992-09-01

The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: The characterization of the physical and chemical processes that constitute the early devolatilization phase of coal combustion: Characterization of the combustion behavior of selected coals under conditions relevant to industria pulverized coal-fired furnaces; and to establish a quantitative understanding of themore » mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distributions of mineral species in the unreacted coal, and the local gas temperature and composition.« less

Influence of Geological Structure on Coal and Gas Outburst Occurrences in Turkish Underground Coal Mines

NASA Astrophysics Data System (ADS)

Esen, Olgun; Özer, Samet Can; Fişne, Abdullah

2015-04-01

Coal and gas outbursts are sudden and violent releases of gas and in company with coal that result from a complex function of geology, stress regime with gas pressure and gas content of the coal seam. The phenomena is referred to as instantaneous outbursts and have occurred in virtually all the major coal producing countries and have been the cause of major disasters in the world mining industry. All structures from faults to joints and cleats may supply gas or lead to it draining away. Most geological structures influence the way in which gas can drain within coal seams. From among all the geological factors two groups can be distinguished: parameters characterising directly the occurrence and geometry of the coal seams; parameters characterising the tectonic disturbances of the coal seams and neighbouring rocks. Also dykes may act as gas barriers. When the production of the coal seam is advanced in mine working areas, these barriers are failed mostly in the weak and mylonitized zones. Geology also plays a very important role in the outburst process. Coal seams of complex geological structure including faults, folds, and fractured rocks are liable to outbursts if coal seams and neighbouring rocks have high gas content level. The purpose of the study is to enlighten the coal industry in Turkey to improving mine safety in underground coal production and decrease of coal and gas outburst events due to increasing depth of mining process. In Turkey; the years between 1969 and 2013, the number of 90 coal and gas outbursts took place in Zonguldak Hard Coal Basin in both Kozlu and Karadon Collieries. In this study the liability to coal and gas outburst of the coal seams are investigated by measuring the strength of coal and the rock pressure. The correlation between these measurements and the event locations shows that the geological structures resulted in 52 events out of 90 events; 19 events close to the fault zones, 25 events thorough the fault zones and 8 events in

Life Cycle Assessment of Coal-fired Power Production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spath, P. L.; Mann, M. K.; Kerr, D. R.

1999-09-01

Coal has the largest share of utility power generation in the US, accounting for approximately 56% of all utility-produced electricity (US DOE, 1998). Therefore, understanding the environmental implications of producing electricity from coal is an important component of any plan to reduce total emissions and resource consumption. A life cycle assessment (LCA) on the production of electricity from coal was performed in order to examine the environmental aspects of current and future pulverized coal boiler systems. Three systems were examined: (1) a plant that represents the average emissions and efficiency of currently operating coal-fired power plants in the US (thismore » tells us about the status quo), (2) a new coal-fired power plant that meets the New Source Performance Standards (NSPS), and (3) a highly advanced coal-fired power plant utilizing a low emission boiler system (LEBS).« less

The effect of biomass on pollutant emission and burnout in co-combustion with coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kruczek, H.; Raczka, P.; Tatarek, A.

This paper presents experimental and numerical results on the co-combustion of different types of biomass with hard and brown coal. The main aim of this work was to assess the impact of the cocombustion of biomass in brown and hard coal-fired systems on the combustion process itself and on the level of pollutant formation and its dependence on combustion temperature stoichiometry. The experimental results obtained have shown that in general biomass addition leads to decreased NO and SO{sub 2} emissions, except with the hard coal Bogdanka. In addition, the biomass has a beneficial effect on the burnout of the coal/biomassmore » mixture. To help to account for this effect, the behaviour of coal and biomass, the coal/biomass mixture and of fuel-N was studied by thermal analysis, in nitrogen and in air. The results obtained have shown that gas phase interactions are dominant in the combustion of biomass/coal mixtures.« less

Energy Conversion Alternatives Study (ECAS), General Electric Phase 1. Volume 1: Executive summary. [using coal or coal derived fuels

NASA Technical Reports Server (NTRS)

Corman, J. C.

1976-01-01

A data base for the comparison of advanced energy conversion systems for utility applications using coal or coal-derived fuels was developed. Estimates of power plant performance (efficiency), capital cost, cost of electricity, natural resource requirements, and environmental intrusion characteristics were made for ten advanced conversion systems. Emphasis was on the energy conversion system in the context of a base loaded utility power plant. All power plant concepts were premised on meeting emission standard requirements. A steam power plant (3500 psig, 1000 F) with a conventional coal-burning furnace-boiler was analyzed as a basis for comparison. Combined cycle gas/steam turbine system results indicated competitive efficiency and a lower cost of electricity compared to the reference steam plant. The Open-Cycle MHD system results indicated the potential for significantly higher efficiency than the reference steam plant but with a higher cost of electricity.

Coal-fired high performance power generating system. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can bemore » achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.« less

Health effects of coal technologies: research needs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1980-09-01

In this 1977 Environmental Message, President Carter directed the establishment of a joint program to identify the health and environmental problems associated with advanced energy technologies and to review the adequacy of present research programs. In response to the President's directive, representatives of three agencies formed the Federal Interagency Committee on the Health and Environmental Effects of Energy Technologies. This report was prepared by the Health Effects Working Group on Coal Technologies for the Committee. In this report, the major health-related problems associated with conventional coal mining, storage, transportation, and combustion, and with chemical coal cleaning, in situ gasification, fluidizedmore » bed combustion, magnetohydrodynamic combustion, cocombustion of coal-oil mixtures, and cocombustion of coal with municipal solid waste are identified. The report also contains recommended research required to address the identified problems.« less

Coal-Based Fuel-Cell Powerplants

NASA Technical Reports Server (NTRS)

Ferral, J. F.; Pappano, A. W.; Jennings, C. N.

1986-01-01

Report assesses advanced technologyy design alternatives for integrated coal-gasifier/fuel-cell powerplants. Various gasifier, cleanup, and fuelcell options evaluated. Evaluation includes adjustments to assumed performances and costs of proposed technologies where required. Analysis identifies uncertainties remaining in designs and most promising alternatives and research and development required to develop these technologies. Bulk of report summary and detailed analysis of six major conceptual designs and variations of each. All designs for plant that uses Illinois No. 6 coal and produces 675 MW of net power.

Lime helps establish crownvetch on coal-breaker refuse

Treesearch

Miroslaw M. Czapowskyj; Edward A. Sowa

1976-01-01

A study was begun in 1965 to determine the effect of lime fertilizer, and mulch on the establishment and growth of crownvetch crowns planted on anthracite coal-breaker refuse. After 7 years the lime application had by far the strongest effect. Both 2.5 and 5.0 tons per acre increased survival and ground cover manyfold, and both treatments were equally beneficial from...

Advanced direct coal liquefaction concepts. Quarterly report, April 1, 1993--June 30, 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, D.J.; Parker, R.J.; Simpson, P.L.

Construction and commissioning of the bench unit for operation of the first stage of the process was completed. Solubilization of Black Thunder coal using carbon monoxide and steam was successfully demonstrated in the counterflow reactor system. The results were comparable with those obtained in the autoclave with the exception that coal solubilization at the same nominal residence times was slightly lower. The bench unit has now been modified for two stage operation. The Wilsonville process derived solvent for Black Thunder coal (V-1074) was found to be essentially as stable as the previous solvent used in the autoclave runs (V-178 +more » 320) at reactor conditions. This solvent (V-1074) is, therefore, being used in the bench unit tests. Carbon monoxide may be replaced by synthesis gas for the coal solubilization step in the process. However, in autoclave tests, coal conversion was found to be dependent on the amount of carbon monoxide present in the synthesis gas. Coal conversions ranged from 88% for pure carbon monoxide to 67% for a 25:75 carbon monoxide/hydrogen mixture at equivalent conditions. Two stage liquefaction tests were completed in the autoclave using a disposable catalyst (FeS) and hydrogen in the second stage. Increased coal conversion, higher gas and oil and lower asphaltene and preasphaltene yields were observed as expected. However, no hydrogen consumption was observed in the second stage. Other conditions, in particular, alternate catalyst systems will be explored.« less

Advanced direct coal liquefaction concepts. Quarterly report, July 1--September 30, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, D.J.; Parker, R.J.; Simpson, P.L.

All the reports required for completion of the contract were submitted this quarter. A proposal for further work in Phase 2 was also submitted. The technical and economic assessment of the process was completed. The results show that for the base case scenario (25% equity, 15% after tax DCF-ROE) coal derived synthetic crude oil can be produced at just below US $30 per barrel. The study was based on the production of 75,000 BPD of C{sub 4+} synthetic crude oil from Black Thunder coal for subsequent processing in a conventional petroleum refinery from Black Thunder (Wyoming) subbituminous coal.

Conditioning of carbonaceous material prior to physical beneficiation

DOEpatents

Warzinski, Robert P.; Ruether, John A.

1987-01-01

A carbonaceous material such as coal is conditioned by contact with a supercritical fluid prior to physical beneficiation. The solid feed material is contacted with an organic supercritical fluid such as cyclohexane or methanol at temperatures slightly above the critical temperature and pressures of 1 to 4 times the critical pressure. A minor solute fraction is extracted into critical phase and separated from the solid residuum. The residuum is then processed by physical separation such as by froth flotation or specific gravity separation to recover a substantial fraction thereof with reduced ash content. The solute in supercritical phase can be released by pressure reduction and recombined with the low-ash, carbonaceous material.

Advanced technology applications for second and third generation coal gasification systems. Appendix

NASA Technical Reports Server (NTRS)

Bradford, R.; Hyde, J. D.; Mead, C. W.

1980-01-01

Sixteen coal conversion processes are described and their projected goals listed. Tables show the reactants used, products derived, typical operating data, and properties of the feed coal. A history of the development of each process is included along with a drawing of the chemical reactor used.

Mechanism of Rock Burst Occurrence in Specially Thick Coal Seam with Rock Parting

NASA Astrophysics Data System (ADS)

Wang, Jian-chao; Jiang, Fu-xing; Meng, Xiang-jun; Wang, Xu-you; Zhu, Si-tao; Feng, Yu

2016-05-01

Specially thick coal seam with complex construction, such as rock parting and alternative soft and hard coal, is called specially thick coal seam with rock parting (STCSRP), which easily leads to rock burst during mining. Based on the stress distribution of rock parting zone, this study investigated the mechanism, engineering discriminant conditions, prevention methods, and risk evaluation method of rock burst occurrence in STCSRP through setting up a mechanical model. The main conclusions of this study are as follows. (1) When the mining face moves closer to the rock parting zone, the original non-uniform stress of the rock parting zone and the advancing stress of the mining face are combined to intensify gradually the shearing action of coal near the mining face. When the shearing action reaches a certain degree, rock burst easily occurs near the mining face. (2) Rock burst occurrence in STCSRP is positively associated with mining depth, advancing stress concentration factor of the mining face, thickness of rock parting, bursting liability of coal, thickness ratio of rock parting to coal seam, and difference of elastic modulus between rock parting and coal, whereas negatively associated with shear strength. (3) Technologies of large-diameter drilling, coal seam water injection, and deep hole blasting can reduce advancing stress concentration factor, thickness of rock parting, and difference of elastic modulus between rock parting and coal to lower the risk of rock burst in STCSRP. (4) The research result was applied to evaluate and control the risk of rock burst occurrence in STCSRP.

The environmental status of coal ash produced in Israel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Metzger, L.A.

1996-12-31

From the 6.1 million tons of coal ash produced by Israeli power stations during the 1982--95 period, 65% were utilized for cement production, 18% served to construct embankments around the Hadera coastal power station, and the remaining 17% were disposed to the sea, according to permits issued by the governmental authorities. The coal imported to Israel is typically low-sulfur, beneficiated bituminous coal, and ash produced from it is alkaline and characterized by low concentrations of trace elements. According to the results of leaching tests, the potential release of trace elements from the ash is low, thus there is only amore » minor risk of contaminating groundwater under disposal or utilization sites. However, while the annual ash production increases and is planned to reach one million tons in the year 2000, the promotion of ash employment for new applications, for example as a road base material or for shore extension projects, is still prevented by the absence of regulations fixing the environmental status of coal ash.« less

Forecast of long term coal supply and mining conditions: Model documentation and results

NASA Technical Reports Server (NTRS)

1980-01-01

A coal industry model was developed to support the Jet Propulsion Laboratory in its investigation of advanced underground coal extraction systems. The model documentation includes the programming for the coal mining cost models and an accompanying users' manual, and a guide to reading model output. The methodology used in assembling the transportation, demand, and coal reserve components of the model are also described. Results presented for 1986 and 2000, include projections of coal production patterns and marginal prices, differentiated by coal sulfur content.

Evaluating the Use of Tribocharging in the Electrostatic Beneficiation of Lunar Simulant

NASA Technical Reports Server (NTRS)

Trigwell, S.; Captain, J. G.; Arens, E. E.; Captain, J. E.; Quinn, J. W.; Calle, C. I.

2007-01-01

Any future lunar base needs materials to provide thermal and radiation protection. Many factors point to the use of lunar materials as industrial feedstocks. Sintering of full-scale bricks using whole lunar dust has been accomplished. Refinement of soil beneficial before processing means less energy. Triboelectric separation of coal from minerals, quartz from feldspar, and phosphorous from silica and iron ore successively achieved. The Lunar environment ideal for electrostatic separation (1) lack of moisture (2) lower gravitational pull (3) higher voltages in vacuum

Bituminous coal production in the Appalachian Basin; past, present, and future

USGS Publications Warehouse

Milici, R.C.

1999-01-01

This report on Appalachian basin coal production consists of four maps and associated graphs and tables, with links to the basic data that were used to construct the maps. Plate 1 shows the time (year) of maximum coal production, by county. For illustration purposes, the years of maximum production are grouped into decadal units. Plate 2 shows the amount of coal produced (tons) during the year of maximum coal production for each county. Plate 3 illustrates the cumulative coal production (tons) for each county since about the beginning of the 20th century. Plate 4 shows 1996 annual production by county. During the current (third) cycle of coal production in the Appalachian basin, only seven major coal-producing counties (those with more than 500 million tons cumulative production), including Greene County, Pa.; Boone, Kanawha, Logan, Mingo, and Monongalia Counties, W.Va.; and Pike County, Ky., exhibit a general increase in coal production. Other major coal-producing counties have either declined to a small percentage of their maximum production or are annually maintaining a moderate level of production. In general, the areas with current high coal production have large blocks of coal that are suitable for mining underground with highly efficient longwall methods, or are occupied by very large scale, relatively low cost surface mining operations. The estimated cumulative production for combined bituminous and anthracite coal is about 100 billion tons or less for the Appalachian basin. In general, it is anticipated that the remaining resources will be progressively of lower quality, will cost more to mine, and will become economical only as new technologies for extraction, beneficiation, and consumption are developed, and then only if prices for coal increase.

Environmental Impacts Of Zirab Coal Washing Plant, Mazandaran, Iran

NASA Astrophysics Data System (ADS)

Moore, F.; Esmaeili, A.

2009-04-01

Extraction and beneficiation operations associated with coal mining increase the rate of chemical reaction of waste material to air and water media. Zirab coal washing plant is located on the bank of the Cherat stream in Mazandaran province, Iran. coal Mined from central Alborz coalfield mines is not suitable for use in Iranian Steel Corporation. Hence, coal ash content is reduced by physical and chemical processes in this plant. These processes leave a large quantity of liquid and solid wastes that accumulate in waste dump and tailing dam. sediment and water samples taken from Sheshrudbar and Cherat streams and also from Talar river show high concentration of Cd, Mo and As in water samples of coal washing plant and the associated drainage. Eh-pH diagrams revealed the chemical species of elements in water. The enrichment factor and geoaccumulation index show that Cd, Hg, Mo and V are enriched in bottom sediments of the coal washing plant and decrease with increasing distance from the plant. Sequential extraction analysis Results of three sediment samples of Cherat stream show that silicate bound is the major phase in samples taken before and after the plant, but adjacent to the plant, organic bound is dominant. The high concentration of Cd and Mo in the water soluble phase, is noticeable and may result in high mobility and bioavailability of these elements. Mann-Whitney and Wilcoxon tests on six samples, before and after the coal washing plant support the obtained results. Keywords: Zirab; coal washing plant; Sequential extraction analysis; Mann-whitney; Wilcoxon; Enrichment factor; Geoaccumulation index.

Biogeochemistry of microbial coal-bed methane

USGS Publications Warehouse

Strc, D.; Mastalerz, Maria; Dawson, K.; MacAlady, J.; Callaghan, A.V.; Wawrik, B.; Turich, C.; Ashby, M.

2011-01-01

Microbial methane accumulations have been discovered in multiple coal-bearing basins over the past two decades. Such discoveries were originally based on unique biogenic signatures in the stable isotopic composition of methane and carbon dioxide. Basins with microbial methane contain either low-maturity coals with predominantly microbial methane gas or uplifted coals containing older, thermogenic gas mixed with more recently produced microbial methane. Recent advances in genomics have allowed further evaluation of the source of microbial methane, through the use of high-throughput phylogenetic sequencing and fluorescent in situ hybridization, to describe the diversity and abundance of bacteria and methanogenic archaea in these subsurface formations. However, the anaerobic metabolism of the bacteria breaking coal down to methanogenic substrates, the likely rate-limiting step in biogenic gas production, is not fully understood. Coal molecules are more recalcitrant to biodegradation with increasing thermal maturity, and progress has been made in identifying some of the enzymes involved in the anaerobic degradation of these recalcitrant organic molecules using metagenomic studies and culture enrichments. In recent years, researchers have attempted lab and subsurface stimulation of the naturally slow process of methanogenic degradation of coal. Copyright ?? 2011 by Annual Reviews. All rights reserved.

Advanced direct coal liquefaction concepts. Quarterly report, January 1, 1993--March 31, 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, D.J.; Parker, R.J.; Simpson, P.L.

1993-07-01

Five barrels of a Wilsonville process derived solvent (V-1074) from Black Thunder coal were obtained. This material boils within the preferred gas oil range, is more aromatic than previous solvents, and will therefore be used for the bench unit studies. Several repeat runs were performed in the autoclave to confirm the results of the matrix study. In addition, runs were carried out with different catalysts, with agglomerates and with the V-1074 solvent. The results of the autoclave runs were analyzed with respect to coal conversion, CO conversion, oil yield, hydrogen consumption and oxygen removal. It was concluded that the bestmore » operating conditions for the first stage operation was a temperature of at least 390{degrees}C, residence time of at least 30 minutes, cold CO pressure of at least 600 psig and potassium carbonate catalyst (2% wt on total feed). The data also indicated however, that the coal conversion goes through a maximum, and too high a severity leads to retrograde reaction and lower coal solubilization. The scope for increasing temperature and time is therefore limited. Petrographic examination of the THF insoluble resids from the autoclave program indicated a maximum coal conversion of about 90% for Black Thunder coal. The bench unit construction was also essentially completed and the bench unit program to be carded out in the next twelve months was defined.« less

Relevance of Clean Coal Technology for India’s Energy Security: A Policy Perspective

NASA Astrophysics Data System (ADS)

Garg, Amit; Tiwari, Vineet; Vishwanathan, Saritha

2017-07-01

Climate change mitigation regimes are expected to impose constraints on the future use of fossil fuels in order to reduce greenhouse gas (GHG) emissions. In 2015, 41% of total final energy consumption and 64% of power generation in India came from coal. Although almost a sixth of the total coal based thermal power generation is now super critical pulverized coal technology, the average CO2 emissions from the Indian power sector are 0.82 kg-CO2/kWh, mainly driven by coal. India has large domestic coal reserves which give it adequate energy security. There is a need to find options that allow the continued use of coal while considering the need for GHG mitigation. This paper explores options of linking GHG emission mitigation and energy security from 2000 to 2050 using the AIM/Enduse model under Business-as-Usual scenario. Our simulation analysis suggests that advanced clean coal technologies options could provide promising solutions for reducing CO2 emissions by improving energy efficiencies. This paper concludes that integrating climate change security and energy security for India is possible with a large scale deployment of advanced coal combustion technologies in Indian energy systems along with other measures.

Advanced Characterization of Rare Earth Elements in Coal Utilization Byproducts

NASA Astrophysics Data System (ADS)

Verba, C.; Scott, M.; Dieterich, M.; Poston, J.; Collins, K.

2016-12-01

Rare earth elements (REE) in various forms (e.g., crystalline mineral phases; adsorbed/absorbed state on and into organic macerals, neoformed glass from flyash or bottom ash) from domestic feedstocks such as coal deposits to coal utilization byproducts (CUB) have the potential to reduce foreign REE dependence and increase domestic resource security. Characterization is critical for understanding environmental risks related to their fate and transport as well as determining the most practical and economical techniques for concentrating the REE and converting them into chemical stocks for manufacturing. Several complementary electron microscopy (SEM-EDS, EPMA-WDS, FIB-SEM, cathodoluminescence, and XRD) and post image processing techniques were used to understand REE transition from coal to CUB. Sites of interest were identified and imaged and respective elemental x-ray maps acquired and montaged. Pixel classification of SEM imagers was completed using image analysis techniques to quantify the distribution of REE associated features. Quantitative elemental analysis of phases were completed using EMPA-WDS followed by FIB-SEM. The FIB-SEM results were reconstructed into 3D volumes and features of interest (e.g. monazite) were analyzed to determine the structure and volumetric estimation of REEs and thus predict detrital REE phases to ICP-MS results. Trace minerals were identified as pyrite, zircon, REE-phosphates' (monazite, xenotime), and barite within the coal tailings. In CUB, amorphous aluminosilicates, iron oxide cenospheres, and calcium oxides were present; monazite appear to be unaltered and unaffected by the combustion process in these samples. Thermal decomposition may have occurred due to presence of detrital zircon and xenotime and subsequent thin Ca-oxide coating enriched in trace REEs.

Structural features of a bituminous coal and their changes during low-temperature oxidation and loss of volatiles investigated by advanced solid-state NMR spectroscopy

USGS Publications Warehouse

Mao, J.-D.; Schimmelmann, A.; Mastalerz, Maria; Hatcher, P.G.; Li, Y.

2010-01-01

Quantitative and advanced 13C solid-state NMR techniques were employed to investigate (i) the chemical structure of a high volatile bituminous coal, as well as (ii) chemical structural changes of this coal after evacuation of adsorbed gases, (iii) during oxidative air exposure at room temperature, and (iv) after oxidative heating in air at 75 ??C. The solid-state NMR techniques employed in this study included quantitative direct polarization/magic angle spinning (DP/MAS) at a high spinning speed of 14 kHz, cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CH, CH2, and CHn selection, 13C chemical shift anisotropy (CSA) filtering, two-dimensional (2D) 1H-13C heteronuclear correlation NMR (HETCOR), and 2D HETCOR with 1H spin diffusion. With spectral editing techniques, we identified methyl CCH 3, rigid and mobile methylene CCH2C, methine CCH, quaternary Cq, aromatic CH, aromatic carbons bonded to alkyls, small-sized condensed aromatic moieties, and aromatic C-O groups. With direct polarization combined with spectral-editing techniques, we quantified 11 different types of functional groups. 1H-13C 2D HETCOR NMR experiments indicated spatial proximity of aromatic and alkyl moieties in cross-linked structures. The proton spin diffusion experiments indicated that the magnetization was not equilibrated at a 1H spin diffusion time of 5 ms. Therefore, the heterogeneity in spatial distribution of different functional groups should be above 2 nm. Recoupled C-H long-range dipolar dephasing showed that the fraction of large charcoal-like clusters of polycondensed aromatic rings was relatively small. The exposure of this coal to atmospheric oxygen at room temperature for 6 months did not result in obvious chemical structural changes of the coal, whereas heating at 75 ??C in air for 10 days led to oxidation of coal and generated some COO groups. Evacuation removed most volatiles and caused a significant reduction in aliphatic signals in its DP

Health-beneficial nutraceuticals-myth or reality?

PubMed

Sauer, Sascha; Plauth, Annabell

2017-02-01

The modern term nutraceutical sounds extremely promising to the health-conscious consumers and to the broad audience. But what are the scientific foundations of this hybrid between nutrient and pharmaceutical? Still, most compelling evidence for potential health-beneficial effects of nutraceuticals seem to derive from descriptive and correlative epidemiological data. Here, we will take an inventory of the general concepts of research to assess the current plethora of health claims that were made for nutraceutical products. Thereby, we will discuss the limitations of current experimental approaches to advance in establishing mechanistic or causal links to the possible benefits of bioactive dietary molecules. Finally, we aim to provide perspectives to generate potential scientific evidence for the beneficial effects of nutraceuticals on human physiology.

Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karmis, Michael; Luttrell, Gerald; Ripepi, Nino

The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderlessmore » coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NO x, CO 2, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.« less

Petrographic, mineralogical, and chemical characterization of certain Alaskan coals and washability products. Final report, July 11, 1978-October 11, 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, P.D.; Wolff, E.N.

1981-05-01

Petrological, mineralogical and chemical characterization provides basic information needed for proper utilization of coals. Since many of these coals are likely to be beneficiated to reduce ash, the influence of coal washing on the characteristics of the washed product is important. Twenty samples of Alaskan coal seams were used for this study. The coals studied ranged in rank from lignite to high volatile A bituminous with vitrinite/ulminite reflectance ranging from 0.25 to 1.04. Fifteen raw coals were characterized for proximate and ultimate analysis reflectance rank, petrology, composition of mineral matter, major oxides and trace elements in coal ash. Washability productsmore » of three coals from Nenana, Beluga and Matanuska coal fields were used for characterization of petrology, mineral matter and ash composition. Petrological analysis of raw coals and float-sink products showed that humodetrinite was highest in top seam in a stratigraphic sequence« less

The chemical enhancement of the triboelectric separation of coal from pyrite and ash: A novel approach for electrostatic separation of mineral matter from coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gustafson, R.M.; DiMare, S.; Sabatini, J.

1992-02-01

Arthur D. Little, Inc., under contract to the US DOE Pittsburgh Energy Technology Center, has developed a triboelectric separation device for coal beneficiation, that employs an entrained-flow, rotating-cylinder concept. The described apparatus has been used to test the efficacy of chemical pretreatment and in-situ treatment of coal on separation efficiency. Coal particle entrainment is achieved with gaseous carbon dioxide and particle collection is accomplished by an electrostatic plate separator. The triboelectric separation device incorporates instrumentation for the direct measurement of charge in the dilute-phase particle stream. Some of the pretreatment materials investigated under this project to modify the surface chargingmore » characteristics of the coal included oleic acid, sodium oleate, quinoline and dicyclohexylamine. Ammonia and sulfur dioxide at a concentration up to 1000 ppM was used for in-situ treatment of the coal, with carbon dioxide as the carrier/inerting gas. Nitrogen was used earlier in the test program as the carrier/inerting gas for the coal, but a severe arcing problem was encountered in the electrostatic collector with nitrogen as the carrier gas. This problem did not occur when carbon dioxide was used. The report covers the chemical treatment employed, and summarizes and interprets the results achieved. In addition, an economic analysis of a full scale system based on this concept is presented.« less

Overall requirements for an advanced underground coal extraction system. [environment effects, miner health and safety, production cost, and coal conservation

NASA Technical Reports Server (NTRS)

Goldsmith, M.; Lavin, M. L.

1980-01-01

Underground mining systems suitable for coal seams expoitable in the year 2000 are examined with particular relevance to the resources of Central Appalachia. Requirements for such systems may be summarized as follows: (1) production cost; (2)miner safety; (3) miner health; (4) environmental impact; and (5) coal conservation. No significant trade offs between production cost and other performance indices were found.

Longwall top coal caving (LTCC) mining technologies with roof softening by hydraulic fracturing method

NASA Astrophysics Data System (ADS)

Klishin, V.; Nikitenko, S.; Opruk, G.

2018-05-01

The paper discusses advanced top coal caving technologies for thick coal seams and addresses some issues of incomplete coal extraction, which can result in the environmental damage, landscape change, air and water pollution and endogenous fires. The authors put forward a fundamentally new, having no equivalent and ecology-friendly method to difficult-to-cave roof coal – directional hydraulic fracturing and nonexplosive disintegration.

Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stephenson, M.

1994-03-01

Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because ofmore » the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.« less

Nanometre-sized pores in coal: Variations between coal basins and coal origin

USGS Publications Warehouse

Sakurovs, Richard; Koval, Lukas; Grigore, Mihaela; Sokolava, Anna; Ruppert, Leslie F.; Melnichenko, Yuri B.

2018-01-01

We have used small angle neutron scattering (SANS) to investigate the differences in methane and hexane penetration in pores in bituminous coal samples from the U.S., Canada, South Africa, and China, and maceral concentrates from Australian coals. This work is an extension of previous work that showed consistent differences between the extent of penetration by methane into 10–20 nm size pores in inertinite in bituminous coals from Australia, North America and Poland.In this study we have confirmed that there are differences in the response of inertinite to methane and hexane penetration in coals sourced from different coal basins. Inertinite in Permian Australian coals generally has relatively high numbers of pores in the 2.5–250 nm size range and the pores are highly penetrable by methane and hexane; coals sourced from Western Canada had similar penetrability to these Australian coals. However, the penetrability of methane and hexane into inertinite from the Australian Illawarra Coal Measures (also Permian) is substantially less than that of the other Australian coals; there are about 80% fewer 12 nm pores in Illawarra inertinite compared to the other Australian coals examined. The inertinite in coals sourced from South Africa and China had accessibility intermediate between the Illawarra coals and the other Australian coals.The extent of hexane penetration was 10–20% less than CD4 penetration into the same coal and this difference was most pronounced in the 5–50 nm pore size range. Hexane and methane penetrability into the coals showed similar trends with inertinite content.The observed variations in inertinite porosity between coals from different coal regions and coal basins may explain why previous studies differ in their observations of the relationships between gas sorption behavior, permeability, porosity, and maceral composition. These variations are not simply a demarcation between Northern and Southern Hemisphere coals.

Experimental Studies of Coal and Biomass Fuel Synthesis and Flame Characterization for Aircraft Engines

DTIC Science & Technology

2012-03-31

there is a need for fundamental scientific and synergistic research in catalytic biomass fast-hydropyrolysis and advanced coal gasification studies...produce appropriate aviation fuels. 15. SUBJECT TERMS Biomass fast hydropyrolysis, hydrodeoxygenation, and coal gasification 16. SECURITY...22 2.0 Investigation of Coal and Biomass Gasification using In-situ

Geologic considerations in underground coal mining system design

NASA Technical Reports Server (NTRS)

Camilli, F. A.; Maynard, D. P.; Mangolds, A.; Harris, J.

1981-01-01

Geologic characteristics of coal resources which may impact new extraction technologies are identified and described to aid system designers and planners in their task of designing advanced coal extraction systems for the central Appalachian region. These geologic conditions are then organized into a matrix identified as the baseline mine concept. A sample region, eastern Kentucy is analyzed using both the developed baseline mine concept and the traditional geologic investigative approach.

Formation and use of coal combustion residues from three types of power plants burning Illinois coals

USGS Publications Warehouse

Demir, I.; Hughes, R.E.; DeMaris, P.J.

2001-01-01

Coal, ash, and limestone samples from a fluidized bed combustion (FBC) plant, a pulverized coal combustion (PC) plant, and a cyclone (CYC) plant in Illinois were analyzed to determine the combustion behavior of mineral matter, and to propose beneficial uses for the power plant ashes. Pyrite and marcasite in coal were converted during combustion to glass, hematite and magnetite. Calcite was converted to lime and anhydrite. The clay minerals were altered to mullite and glass. Quartz was partially altered to glass. Trace elements in coal were partially mobilized during combustion and, as a result, emitted into the atmosphere or adsorbed on fly ash or on hardware on the cool side of the power plants. Overall, the mobilities of 15 trace elements investigated were lower at the FBC plant than at the other plants. Only F and Mn at the FBC plant, F, Hg, and Se at the PC plant and Be, F, Hg, and Se at the CYC plant had over 50% of their concentrations mobilized. Se and Ge could be commercially recovered from some of the combustion ashes. The FBC ashes could be used as acid neutralizing agents in agriculture and waste treatment, and to produce sulfate fertilizers, gypsum wall boards, concrete, and cement. The PC and CYC fly ashes can potentially be used in the production of cement, concrete, ceramics, and zeolites. The PC and CYC bottom ashes could be used in stabilized road bases, as frits in roof shingles, and perhaps in manufacturing amber glass. ?? 2001 Elsevier Science Ltd. All rights reserved.

The chemical enhancement of the triboelectric separation of coal from pyrite and ash: A novel approach for electrostatic separation of mineral matter from coal. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gustafson, R.M.; DiMare, S.; Sabatini, J.

1992-02-01

Arthur D. Little, Inc., under contract to the US DOE Pittsburgh Energy Technology Center, has developed a triboelectric separation device for coal beneficiation, that employs an entrained-flow, rotating-cylinder concept. The described apparatus has been used to test the efficacy of chemical pretreatment and in-situ treatment of coal on separation efficiency. Coal particle entrainment is achieved with gaseous carbon dioxide and particle collection is accomplished by an electrostatic plate separator. The triboelectric separation device incorporates instrumentation for the direct measurement of charge in the dilute-phase particle stream. Some of the pretreatment materials investigated under this project to modify the surface chargingmore » characteristics of the coal included oleic acid, sodium oleate, quinoline and dicyclohexylamine. Ammonia and sulfur dioxide at a concentration up to 1000 ppM was used for in-situ treatment of the coal, with carbon dioxide as the carrier/inerting gas. Nitrogen was used earlier in the test program as the carrier/inerting gas for the coal, but a severe arcing problem was encountered in the electrostatic collector with nitrogen as the carrier gas. This problem did not occur when carbon dioxide was used. The report covers the chemical treatment employed, and summarizes and interprets the results achieved. In addition, an economic analysis of a full scale system based on this concept is presented.« less

Bench-scale Development of an Advanced Solid Sorbent-based CO 2 Capture Process for Coal-fired Power Plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, Thomas; Kataria, Atish; Soukri, Mustapha

It is increasingly clear that CO 2 capture and sequestration (CCS) must play a critical role in curbing worldwide CO 2 emissions to the atmosphere. Development of these technologies to cost-effectively remove CO 2 from coal-fired power plants is very important to mitigating the impact these power plants have within the world’s power generation portfolio. Currently, conventional CO 2 capture technologies, such as aqueous-monoethanolamine based solvent systems, are prohibitively expensive and if implemented could result in a 75 to 100% increase in the cost of electricity for consumers worldwide. Solid sorbent CO 2 capture processes – such as RTI’s Advancedmore » Solid Sorbent CO 2, Capture Process – are promising alternatives to conventional, liquid solvents. Supported amine sorbents – of the nature RTI has developed – are particularly attractive due to their high CO 2 loadings, low heat capacities, reduced corrosivity/volatility and the potential to reduce the regeneration energy needed to carry out CO 2 capture. Previous work in this area has failed to adequately address various technology challenges such as sorbent stability and regenerability, sorbent scale-up, improved physical strength and attrition-resistance, proper heat management and temperature control, proper solids handling and circulation control, as well as the proper coupling of process engineering advancements that are tailored for a promising sorbent technology. The remaining challenges for these sorbent processes have provided the framework for the project team’s research and development and target for advancing the technology beyond lab- and bench-scale testing. Under a cooperative agreement with the US Department of Energy, and part of NETL’s CO 2 Capture Program, RTI has led an effort to address and mitigate the challenges associated with solid sorbent CO 2 capture. The overall objective of this project was to mitigate the technical and economic risks associated with the scale

Evolution of Submicrometer Organic Aerosols during a Complete Residential Coal Combustion Process.

PubMed

Zhou, Wei; Jiang, Jingkun; Duan, Lei; Hao, Jiming

2016-07-19

In the absence of particulate matter (PM) control devices, residential coal combustion contributes significantly to ambient PM pollution. Characterizing PM emissions from residential coal combustion with high time resolution is beneficial for developing control policies and evaluating the environmental impact of PM. This study reports the evolution of submicrometer organic aerosols (OA) during a complete residential coal combustion process, that is, from fire start to fire extinction. Three commonly used coal types (bituminous, anthracite, and semicoke coals) were evaluated in a typical residential stove in China. For all three types of coal, the OA emission exhibited distinct characteristics in the four stages, that is, ignition, fierce combustion, relatively stable combustion, and ember combustion. OA emissions during the ignition stage accounted for 58.2-85.4% of the total OA emission of a complete combustion process. The OA concentration decreased rapidly during the fierce combustion stage and remained low during the relatively stable combustion stage. During these two stages, a significant ion peak of m/z 73 from organic acids were observed. The degree of oxidation of the OA increased from the first stage to the last stage. Implications for ambient OA source-apportionment and residential PM emission characterization and control are discussed.

The coal-fired gas turbine locomotive - A new look

NASA Technical Reports Server (NTRS)

Liddle, S. G.; Bonzo, B. B.; Purohit, G. P.

1983-01-01

Advances in turbomachine technology and novel methods of coal combustion may have made possible the development of a competitive coal fired gas turbine locomotive engine. Of the combustor, thermodynamic cycle, and turbine combinations presently assessed, an external combustion closed cycle regenerative gas turbine with a fluidized bed coal combustor is judged to be the best suited for locomotive requirements. Some merit is also discerned in external combustion open cycle regenerative systems and internal combustion open cycle regenerative gas turbine systems employing a coal gasifier. The choice of an open or closed cycle depends on the selection of a working fluid and the relative advantages of loop pressurization, with air being the most attractive closed cycle working fluid on the basis of cost.

Royal Society, Discussion on New Coal Chemistry, London, England, May 21, 22, 1980, Proceedings

NASA Astrophysics Data System (ADS)

1981-03-01

A discussion of new coal chemistry is presented. The chemical and physical structure of coal is examined in the first section, including structural studies of coal extracts, metal and metal complexes in coal and coal microporosity. The second section presents new advances in applied coal technology. The development of liquid fuels and chemicals from coal is given especial emphasis, with papers on the Sasol Synthol process, the Shell-Koppers gasification process, liquefaction and gasification in Germany, the Solvent Refined Coal process, the Exxon Donor Solvent liquefaction process and the Mobil Methanol-to-Gasoline process. Finally, some developments that will be part of the future of coal chemistry in the year 2000 are examined in the third section, including coal-based chemical complexes and the use of coal as an alternative source to oil for chemical feedstocks.

Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of catalytic ultrasound oxidation and membrane bioreactor.

PubMed

Jia, Shengyong; Han, Hongjun; Zhuang, Haifeng; Xu, Peng; Hou, Baolin

2015-01-01

Laboratorial scale experiments were conducted to investigate a novel system integrating catalytic ultrasound oxidation (CUO) with membrane bioreactor (CUO-MBR) on advanced treatment of biologically pretreated coal gasification wastewater. Results indicated that CUO with catalyst of FeOx/SBAC (sewage sludge based activated carbon (SBAC) which loaded Fe oxides) represented high efficiencies in eliminating TOC as well as improving the biodegradability. The integrated CUO-MBR system with low energy intensity and high frequency was more effective in eliminating COD, BOD5, TOC and reducing transmembrane pressure than either conventional MBR or ultrasound oxidation integrated MBR. The enhanced hydroxyl radical oxidation, facilitation of substrate diffusion and improvement of cell enzyme secretion were the mechanisms for CUO-MBR performance. Therefore, the integrated CUO-MBR was the promising technology for advanced treatment in engineering applications. Copyright © 2015 Elsevier Ltd. All rights reserved.

Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous catalytic ozonation and biological process.

PubMed

Zhuang, Haifeng; Han, Hongjun; Jia, Shengyong; Hou, Baolin; Zhao, Qian

2014-08-01

Advanced treatment of biologically pretreated coal gasification wastewater (CGW) was investigated employing heterogeneous catalytic ozonation integrated with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process. The results indicated that catalytic ozonation with the prepared catalyst (i.e. MnOx/SBAC, sewage sludge was converted into sludge based activated carbon (SBAC) which loaded manganese oxides) significantly enhanced performance of pollutants removal by generated hydroxyl radicals. The effluent of catalytic ozonation process was more biodegradable and less toxic than that in ozonation alone. Meanwhile, ANMBBR-BAF showed efficient capacity of pollutants removal in treatment of the effluent of catalytic ozonation at a shorter reaction time, allowing the discharge limits to be met. Therefore, the integrated process with efficient, economical and sustainable advantages was suitable for advanced treatment of real biologically pretreated CGW. Copyright © 2014 Elsevier Ltd. All rights reserved.

Concentrated Brine Treatment using New Energy in Coal Mine Evaporation Ponds

NASA Astrophysics Data System (ADS)

Li, Ting; Li, Jingfeng

2017-12-01

Recently, more and more coal mine water is being advanced treated and reused in China. The concentrated brine that results from advanced treatment methods can only be evaporated in an evaporation pond. Because of limited treatment capabilities and winter freezing, evaporation ponds often overflow, causing environment contamination. In this paper, based on analysis of brine water quality and economic-technical feasibility, we present a suitable treatment method for brine in evaporation ponds as electrodialysis using solar energy. In addition, we propose a new system to treat brine in coal mine evaporation ponds, which is powered by solar and wind. The operating efficiency of this treatment system proposed in this paper can meet the concentrated brine treatment demands in most coal mines in western mining areas of China and it places the photovoltaic power generation plates on the surface of the evaporation pond on a fixed floating island, which reduces any risk associated with land acquisition. This system can enhance brine treatment efficiency, requires a reduced evaporation pond area, increases the utilization of coal mine water, and minimizes the risk of environment contamination.

Liquid fuels from coal: analysis of a partial transition from oil to coal; light liquids in Zimbabwe's liquid fuels base

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maya, R.S.

1986-01-01

This study assesses the feasibility of a coal based light liquids program as a way to localize forces that determine the flow of oil into the Zimbabwean economy. Methods in End-use Energy Analysis and Econometrics in which the utilization of petroleum energy is related to economic and industrial activity are used to gain insight into the structure and behavior of petroleum utilization in that country and to forecast future requirements of this resource. The feasibility of coal liquefaction as a substitute for imported oil is assessed by the use of engineering economics in which the technical economics of competing oilmore » supply technologies are analyzed and the best option is selected. Coal conversion technologies are numerous but all except the Fischer-Trosch indirect coal liquefaction technology are deficient in reliability as commercial ventures. The Fischer-Tropsch process by coincidence better matches Zimbabwe's product configuration than the less commercially advanced technologies. Using present value analysis to compare the coal liquefaction and the import option indicates that it is better to continue importing oil than to resort to a coal base for a portion of the oil supplies. An extended analysis taking special consideration of the risk and uncertainty factors characteristic of Zimbabwe's oil supply system indicates that the coal option is better than the import option. The relative infancy of the coal liquefaction industry and the possibility that activities responsible for the risk and uncertainty in the oil supply system will be removed in the future, however, make the adoption of the coal option an unusually risky undertaking.« less

Seal evaluation and confinement screening criteria for beneficial carbon dioxide storage with enhanced coal bed methane recovery in the Pocahontas Basin, Virginia

USGS Publications Warehouse

Grimm, R.P.; Eriksson, K.A.; Ripepi, N.; Eble, C.; Greb, S.F.

2012-01-01

The geological storage of carbon dioxide in Appalachian basin coal seams is one possible sink for sequestration of greenhouse gases, with the added benefit of enhanced-coal bed methane (ECBM) recovery. The Pocahontas Basin (part of the central Appalachian Basin) of southwestern Virginia is a major coal bed methane (CBM) province with production mostly from coal beds in the Lower Pennsylvanian Pocahontas and New River formations. As part of the Southeast Regional Carbon Sequestration Partnership's Phase II research program, a CO 2-injection demonstration well was installed into Lower Pennsylvanian coal bed-methane producing strata in southwest Virginia. Samples of siliciclastic lithologies above coal beds in this Oakwood Field well, and from several other cores in the Nora Field were taken to establish a baseline of the basic confinement properties of overlying strata to test seal competency at local and regional scales.Strata above CBM-producing coal beds in the Pocahontas and New River formations consist of dark-gray shales; silty gray shales; heterolithic siltstones, sandstones, and shales; lithic sandstones, and quartzose sandstones. Standard measurements of porosity, permeability and petrography were used to evaluate potential leakage hazards and any possible secondary storage potential for typical lithologies. Both lithic- and quartz-rich sandstones exhibit only minor porosity, with generally low permeability (<0.042mD). Interconnected porosity and permeability are strongly impacted by diverse cementation types and compaction. Analyzed siliciclastic lithologies are considered tight, with limited primary matrix permeability risks for leakage, providing an ensemble of redundant CO 2-ECBM traps.One of the most promising confining intervals above the major coal bed-methane producing interval is the Hensley Shale Member. Analyses of 1500 geophysical logs in southwest Virginia indicate that this unit is moderately thick (>50ft, 15m), laterally continuous (>3000km 2

Report of activities of the advanced coal extraction systems definition project, 1979 - 1980

NASA Technical Reports Server (NTRS)

Lavin, M. L.; Isenberg, L.

1981-01-01

During this period effort was devoted to: formulation of system performance goals in the areas of production cost, miner safety, miner health, environmental impact, and coal conservation, survey and in depth assessment of promising technology, and characterization of potential resource targets. Primary system performance goals are to achieve a return on incremental investment of 150% of the value required for a low risk capital improvement project and to reduce deaths and disability injuries per million man-hour by 50%. Although these performance goals were developed to be immediately applicable to the Central Appalachian coal resources, they were also designed to be readily adaptable to other coals by appending a geological description of the new resource. The work done on technology assessment was concerned with the performance of the slurry haulage system.

Direct firing of coal for power production

NASA Technical Reports Server (NTRS)

Papay, L. T.

1978-01-01

The use of new technology and advanced emission control hardware to reduce emissions from the direct combustion of coal to produce electricity in California is considered. The technical feasibilty of a demonstration project on an existing 81-MW boiler is demonstrated.

Fireside Corrosion Behavior of HVOF and Plasma-Sprayed Coatings in Advanced Coal/Biomass Co-Fired Power Plants

NASA Astrophysics Data System (ADS)

Hussain, T.; Dudziak, T.; Simms, N. J.; Nicholls, J. R.

2013-06-01

This article presents a systematic evaluation of coatings for advanced fossil fuel plants and addresses fireside corrosion in coal/biomass-derived flue gases. A selection of four candidate coatings: alloy 625, NiCr, FeCrAl and NiCrAlY were deposited onto superheaters/reheaters alloy (T91) using high-velocity oxy-fuel (HVOF) and plasma spraying. A series of laboratory-based fireside corrosion exposures were carried out on these coated samples in furnaces under controlled atmosphere for 1000 h at 650 °C. The tests were carried out using the "deposit-recoat" test method to simulate the environment that was anticipated from air-firing 20 wt.% cereal co-product mixed with a UK coal. The exposures were carried out using a deposit containing Na2SO4, K2SO4, and Fe2O3 to produce alkali-iron tri-sulfates, which had been identified as the principal cause of fireside corrosion on superheaters/reheaters in pulverized coal-fired power plants. The exposed samples were examined in an ESEM with EDX analysis to characterize the damage. Pre- and post-exposure dimensional metrologies were used to quantify the metal damage in terms of metal loss distributions. The thermally sprayed coatings suffered significant corrosion attack from a combination of aggressive combustion gases and deposit mixtures. In this study, all the four plasma-sprayed coatings studied performed better than the HVOF-sprayed coatings because of a lower level of porosity. NiCr was found to be the best performing coating material with a median metal loss of ~87 μm (HVOF sprayed) and ~13 μm (plasma sprayed). In general, the median metal damage for coatings had the following ranking (in the descending order: most to the least damage): NiCrAlY > alloy 625 > FeCrAl > NiCr.

University coal research/historically black colleges and universities and other minority institutions contractors review meeting

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

2006-07-01

A variety of papers/posters were presented on topics concerning power generation, including solid oxide fuel cells, hydrogen production, mercury as a combustion product, carbon dioxide separation from flue gas. A total of 31 presentations in slide/overview/viewgraph form and with a separate abstract are available online (one in abstract form only) and 24 poster papers (text). In addition 41 abstracts only are available. Papers of particular interest include: Hydrogen production from hydrogen sulfide in IGCC power plants; Oxidation of mercury in products of coal combustion; Computer aided design of advanced turbine aerofoil alloys for industrial gas turbines in coal fired environments;more » Developing engineered fuel using flyash and biomass; Conversion of hydrogen sulfide in coal gases to elemental sulfur with monolithic catalysts; Intelligent control via wireless sensor networks for advanced coal combustion systems; and Investment of fly ash and activated carbon obtained from pulverized coal boilers (poster).« less

Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kloosterman, Jeff

2012-12-31

Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baselinemore » CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.« less

CHARACTERIZATION OF MERCURY-ENRICHED COAL COMBUSTION RESIDUES FROM ELECTRIC UTILITIES USING ENHANCED SORBENTS FOR MERCURY CONTROL

EPA Science Inventory

Leaching of mercury and other constituents of potential concern during land disposal or beneficial use of coal combustion residues (CCRs) is the environmental impact pathway evaluated in this report. The specific objectives of the research was to: (1) evaluate mercury, arsenic an...

TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

James T. Cobb, Jr.

2003-09-12

Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatmentmore » with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.« less

Chemical analyses of coal, coal-associated rocks and coal combustion products collected for the National Coal Quality Inventory

USGS Publications Warehouse

Hatch, Joseph R.; Bullock, John H.; Finkelman, Robert B.

2006-01-01

In 1999, the USGS initiated the National Coal Quality Inventory (NaCQI) project to address a need for quality information on coals that will be mined during the next 20-30 years. At the time this project was initiated, the publicly available USGS coal quality data was based on samples primarily collected and analyzed between 1973 and 1985. The primary objective of NaCQI was to create a database containing comprehensive, accurate and accessible chemical information on the quality of mined and prepared United States coals and their combustion byproducts. This objective was to be accomplished through maintaining the existing publicly available coal quality database, expanding the database through the acquisition of new samples from priority areas, and analysis of the samples using updated coal analytical chemistry procedures. Priorities for sampling include those areas where future sources of compliance coal are federally owned. This project was a cooperative effort between the U.S. Geological Survey (USGS), State geological surveys, universities, coal burning utilities, and the coal mining industry. Funding support came from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE).

Coal mine bumps as related to geologic features in the northern part of the Sunnyside District, Carbon County, Utah

USGS Publications Warehouse

Osterwald, Frank W.; Dunrud, C. Richard; Collins, Donley S.

1993-01-01

Coal mine bumps, which are violent, spontaneous, and often catastrophic disruptions of coal and rock, were common in the Sunnyside coal mining district, Utah, before the introduction of protective-engineering methods, modern room-and-pillar retreat mining with continuous mining machines, and particularly modern longwall mining. The coal at Sunnyside, when stressed during mining, fails continuously with many popping, snapping, and banging noises. Although most of the bumps are beneficial because they make mining easier, many of the large ones are dangerous and in the past caused injuries and fatalities, particularly with room- and-pillar mining methods used in the early mining operations. Geologic mapping of underground mine openings revealed many types of deformational features, some pre-mine and some post-mine in age. Stresses resulting from mining are concentrated near the mine openings; if openings are driven at large angles to small pre-mine deformational features, particularly shatter zones in coal, abnormal stress buildups may occur and violent bumps may result. Other geologic features, such as ripple marks, oriented sand grains, intertongued rock contacts, trace fossils, and load casts, also influence the occurrence of bumps by impeding slip of coal and rocks along bedding planes. The stress field in the coal also varies markedly because of the rough ridge and canyon topography. These features may allow excessively large stress components to accumulate. At many places, the stresses that contribute to deformation and failures of mine openings are oriented horizontally. The stratigraphy of the rocks immediately above and below the mined coal bed strongly influences the deformation of the mine openings in response to stress accumulations. Triaxial compressive testing of coal from the Sunnyside No.1 and No.3 Mines indicates that the strength of the coal increases several times as the confining (lateral) stress is increased. Strengths of cores cut from single

Evaluation of selected elastomer O-ring pump seals for service at the Wilsonville, Alabama, Advanced Coal Liquefaction Research and Development Facility. [Ethylenepropylenediene monomer compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skena, C.C.; Keiser, J.R.

1986-08-01

Previous laboratory tests of elastomer O-rings in coal liquefaction solvents conducted at L'Garde, Inc., indicated that certain ethylenepropylenediene monomer (EPDM) compounds provided the best performance when a backup ring was used to limit swelling. Before service testing in a pump at the Wilsonville, Alabama, Advanced Coal Liquefaction Research and Development Facility, tests of six selected elastomers in the appropriate Wilsonville-produced solvent were conducted at Oak Ridge National Laboratory (ORNL). The ORNL tests measured the elastomers' changes in cross section, weight, density, and relative flexibility. Although two perfluoroelastomers showed less degradation of most properties during these tests, it was decided tomore » proceed with service testing of two EPDM elastomers because of their much lower cost. 5 refs., 14 figs., 7 tabs.« less

Economic baselines for current underground coal mining technology

NASA Technical Reports Server (NTRS)

Mabe, W. B.

1979-01-01

The cost of mining coal using a room pillar mining method with continuous miner and a longwall mining system was calculated. Costs were calculated for the years 1975 and 2000 time periods and are to be used as economic standards against which advanced mining concepts and systems will be compared. Some assumptions were changed and some internal model stored data was altered from the original calculations procedure chosen, to obtain a result that more closely represented what was considered to be a standard mine. Coal seam thicknesses were varied from one and one-half feet to eight feet to obtain the cost of mining coal over a wide range. Geologic conditions were selected that had a minimum impact on the mining productivity.

Bio-coal briquettes using low-grade coal

NASA Astrophysics Data System (ADS)

Estiaty, L. M.; Fatimah, D.; Widodo

2018-02-01

The technology in using briquettes for fuel has been widely used in many countries for both domestic and industrial purposes. Common types of briquette used are coal, peat, charcoal, and biomass. Several researches have been carried out in regards to the production and the use of briquettes. Recently, researches show that mixing coal and biomass will result in an environmentally friendly briquette with better combustion and physical characteristics. This type of briquette is known as bio-coal briquettes. Bio-coal briquettes are made from agriculture waste and coal, which are readily available, cheap and affordable. Researchers make these bio-coal briquettes with different aims and objectives, depending on the issues to address, e.g. utilizing agricultural waste as an alternative energy to replace fossil fuels that are depleting its reserves, adding coal to biomass in order to add calorific value to bio-coal briquette, and adding biomass to coal to improve its chemical and physical properties. In our research, biocoal briquettes are made to utilize low grade coal. The biomass we use, however, is different from the ones used in past researches because it has undergone fermentation. The benefits of using such biomass are 1. Fermentation turns the hemi cellulose into a simpler form, so that the burning activation energy decreases while the calorific value increases. 2. Enzym produced will bind to heavy metals from coal as co-factors, forming metals that are environmentally friendly.

Experimental Studies of Coal and Biomass Fuel Synthesis and Flame Characterization for Aircraft Engines (Year Two)

DTIC Science & Technology

2011-03-31

2.1 Experimental Investigation of Coal and Biomass Gasification using In-situ Diagnostics ................ 31  2.2 References...need for fundamental scientific and synergistic research in catalytic biomass fast-hydropyrolysis, advanced coal gasification and liquid fuel...experimental findings will improve the scientific knowledge of catalytic biomass fast-hydropyrolysis, coal/ biomass gasification and liquid fuel combustion

Advanced direct coal liquefaction concepts. Quarterly report, October 1, 1992--December 31, 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, D.J.; Parker, R.J.; Simpson, P.L.

During the first quarter of FY 1993, the Project proceeded close to the Project Plan. The analysis of the feed material has been completed as far as possible. Some unplanned distillation was needed to correct the boiling range of the Black Thunder solvent used during the autoclave tests. Additional distillation will be required if the same solvent is to be used for the bench unit tests. A decision on this is still outstanding. The solvent to be used with Illinois No. 6 coal has not yet been defined. As a result, the procurement of the feed and the feed analysismore » is somewhat behind schedule. Agglomeration tests with Black Thunder coal indicates that small agglomerates can be formed. However, the ash removal is quite low (about 10%), which is not surprising in view of the low ash content of the coal. The first series of autoclave tests with Black Thunder coal was completed as planned. Also, additional runs are in progress as repeats of previous runs or at different operating conditions based on the data obtained so far. The results are promising indicating that almost complete solubilization (close to 90%) of Black Thunder coal can be achieved in a CO/H{sub 2}O environment at our anticipated process conditions. The design of the bench unit has been completed. In contrast to the originally planned modifications, the bench unit is now designed based on a computerized control and data acquisition system. All major items of equipment have been received, and prefabrication of assemblies and control panels is proceeding on schedule. Despite a slight delay in the erection of the structural steel, it is anticipated that the bench unit will be operational at the beginning of April 1993.« less

Characterization of Coal Porosity for Naturally Tectonically Stressed Coals in Huaibei Coal Field, China

PubMed Central

Li, Xiaoshi; Hou, Quanlin; Li, Zhuo; Wei, Mingming

2014-01-01

The enrichment of coalbed methane (CBM) and the outburst of gas in a coal mine are closely related to the nanopore structure of coal. The evolutionary characteristics of 12 coal nanopore structures under different natural deformational mechanisms (brittle and ductile deformation) are studied using a scanning electron microscope (SEM) and low-temperature nitrogen adsorption. The results indicate that there are mainly submicropores (2~5 nm) and supermicropores (<2 nm) in ductile deformed coal and mesopores (10~100 nm) and micropores (5~10 nm) in brittle deformed coal. The cumulative pore volume (V) and surface area (S) in brittle deformed coal are smaller than those in ductile deformed coal which indicates more adsorption space for gas. The coal with the smaller pores exhibits a large surface area, and coal with the larger pores exhibits a large volume for a given pore volume. We also found that the relationship between S and V turns from a positive correlation to a negative correlation when S > 4 m2/g, with pore sizes <5 nm in ductile deformed coal. The nanopore structure (<100 nm) and its distribution could be affected by macromolecular structure in two ways. Interconversion will occur among the different size nanopores especially in ductile deformed coal. PMID:25126601

From in situ coal to the final coal product: A case study of the Danville Coal Member (Indiana)

USGS Publications Warehouse

Mastalerz, Maria; Padgett, P.L.

1999-01-01

A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in the handling process.A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in

The magnetohydrodynamics coal-fired flow facility

NASA Astrophysics Data System (ADS)

1990-12-01

The purpose of this report is to provide the status of a multi-task research and development program in coal fired MHD/steam combined cycle power production (more detailed information on specific topics is presented in topical reports). Current emphasis is on developing technology for the Steam Bottoming Cycle Program. The approach being taken is to design test components that simulate the most important process variables, such as gas temperature, chemical composition, tube metal temperature, particulate loading, etc., to gain test data needed for scale-up to larger size components. This quarter, a 217 hour coal-fired long-duration test was completed as part of the Proof-of-Concept (POC) test program. The aggregate test time is now 1512 hours of a planned 2000 hours on Eastern coal. The report contains results of testing the newly installed automatic ash/seed handling system and the high pressure sootblower system. The conceptual design for the modifications to the coal processing system to permit operation with Western coal is presented. Results of analysis of superheater test module tube removed after 500 hours of coal-fired testing are summarized. The status of the environmental program is reported. Pollutant measurements from remote monitoring trailers that give the dispersion of stack emissions are presented. Results of advanced measurement systems operated by both UTSI and Mississippi State University during the POC test are summarized. Actions to prepare for the installation of a 20MW(sub t) prototype of the TRW slag rejection combustor first stage are discussed. Contract management and administrative actions completed during the quarter are included.

Advances in coalbed methane reservoirs using integrated reservoir characterization and hydraulic fracturing in Karaganda coal basin, Kazakhstan

NASA Astrophysics Data System (ADS)

Ivakhnenko, Aleksandr; Aimukhan, Adina; Kenshimova, Aida; Mullagaliyev, Fandus; Akbarov, Erlan; Mullagaliyeva, Lylia; Kabirova, Svetlana; Almukhametov, Azamat

2017-04-01

Coalbed methane from Karaganda coal basin is considered to be an unconventional source of energy for the Central and Eastern parts of Kazakhstan. These regions are situated far away from the main traditional sources of oil and gas related to Precaspian petroleum basin. Coalbed methane fields in Karaganda coal basin are characterized by geological and structural complexity. Majority of production zones were characterized by high methane content and extremely low coal permeability. The coal reservoirs also contained a considerable natural system of primary, secondary, and tertiary fractures that were usually capable to accommodate passing fluid during hydraulic fracturing process. However, after closing was often observed coal formation damage including the loss of fluids, migration of fines and higher pressures required to treat formation than were expected. Unusual or less expected reservoir characteristics and values of properties of the coal reservoir might be the cause of the unusual occurred patterns in obtained fracturing, such as lithological peculiarities, rock mechanical properties and previous natural fracture systems in the coals. Based on these properties we found that during the drilling and fracturing of the coal-induced fractures have great sensitivity to complex reservoir lithology and stress profiles, as well as changes of those stresses. In order to have a successful program of hydraulic fracturing and avoid unnecessary fracturing anomalies we applied integrated reservoir characterization to monitor key parameters. In addition to logging data, core sample analysis was applied for coalbed methane reservoirs to observe dependence tiny lithological variations through the magnetic susceptibility values and their relation to permeability together with expected principal stress. The values of magnetic susceptibility were measured by the core logging sensor, which is equipped with the probe that provides volume magnetic susceptibility parameters

Coal Tar and Coal-Tar Pitch

Cancer.gov

Learn about coal-tar products, which can raise your risk of skin cancer, lung cancer, and other types of cancer. Examples of coal-tar products include creosote, coal-tar pitch, and certain preparations used to treat skin conditions such as eczema, psoriasis, and dandruff.

Wabash River coal gasification repowering project -- first year operation experience

DOE Office of Scientific and Technical Information (OSTI.GOV)

Troxclair, E.J.; Stultz, J.

1997-12-31

The Wabash River Coal Gasification Repowering Project (WRCGRP), a joint venture between Destec Energy, Inc. and PSI Energy, Inc., began commercial operation in November of 1995. The Project, selected by the United States Department of Energy (DOE) under the Clean Coal Program (Round IV) represents the largest operating coal gasification combined cycle plant in the world. This Demonstration Project has allowed PSI Energy to repower a 1950`s vintage steam turbine and install a new syngas fired combustion turbine to provide 262 MW (net) of electricity in a clean, efficient manner in a commercial utility setting while utilizing locally mined highmore » sulfur Indiana bituminous coal. In doing so, the Project is also demonstrating some novel technology while advancing the commercialization of integrated coal gasification combined cycle technology. This paper discusses the first year operation experience of the Wabash Project, focusing on the progress towards achievement of the demonstration objectives.« less

Coal blending preparation for non-carbonized coal briquettes

NASA Astrophysics Data System (ADS)

Widodo; Fatimah, D.; Estiaty, L. M.

2018-02-01

Referring to the national energy policy targets for the years 2025, the government has launched the use of coal briquettes as an alternative energy replacement for kerosene and firewood. Non-carbonized briquettes in the form of coal briquettes as well as bio-coal briquettes are used in many small-medium industries and households, and are rarely used by large industries. The standard quality of coal briquettes used as raw material for non-carbonized briquettes is a minimum calorific value of 4,400 kcal/kg (adb); total sulfur at a maximum of 1% (adb), and water content at <12% (adb). The formation of coal deposits depends on the origin of the coal-forming materials (plants), the environment of deposition, and the geological conditions of the surrounding area, so that the coal deposits in each region will be different as well as the amount and also the quality. Therefore, the quantity and the quality of coal in each area are different to be eligible in the making of briquettes to do blending. In addition to the coal blending, it is also necessary to select the right materials in the making of coal briquettes and bio-coal briquettes. The formulation of the right mixture of material in the making of briquettes, can be produced of good quality and environmental friendly.

Microfine coal firing results from a retrofit gas/oil-designed industrial boiler

DOE Office of Scientific and Technical Information (OSTI.GOV)

Patel, R.; Borio, R.W.; Liljedahl, G.

1995-12-31

The development of a High Efficiency Advanced Coal Combustor (HEACC) has been in progress since 1987 and the ABB Power Plant Laboratories. The initial work on this concept produced an advanced coal firing system that was capable of firing both water-based and dry pulverized coal in an industrial boiler environment. Economics may one day dictate that it makes sense to replace oil or natural gas with coal in boilers that were originally designed to burn these fuels. The objective of the current program is to demonstrate the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronizedmore » coal. In support of this overall objective, the following specific areas were targeted: A coal handling/preparation system that can meet the technical requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; Maintaining boiler thermal performance in accordance with specifications when burning oil or natural gas; Maintaining NOx emissions at or below 0.6 lb/MBtu; Achieving combustion efficiencies of 98% or higher; and Calculating economic payback periods as a function of key variables. The overall program has consisted of five major tasks: (1) A review of current state-of-the-art coal firing system components; (2) Design and experimental testing of a prototype HEACC burner; (3) Installation and testing of a HEACC system in a commercial retrofit application; (4) Economic evaluation of the HEACC concept for retrofit applications; and (5) Long term demonstration under commercial user demand conditions. This paper will summarize the latest key experimental results (Task 3) and the economic evaluation (Task 4) of the HEACC concept for retrofit applications. 28 figs., 6 tabs.« less

Applications of micellar enzymology to clean coal technology. [Laccase from Polyporus versicolor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walsh, C.T.

1990-07-24

This project is designed to develop methods for pre-combustion coal remediation by implementing recent advances in enzyme biochemistry. The novel approach of this study is incorporation of hydrophilic oxidative enzymes in reverse micelles in an organic solvent. Enzymes from commercial sources or microbial extracts are being investigated for their capacity to remove organic sulfur from coal by oxidation of the sulfur groups, splitting of C-S bonds and loss of sulfur as sulfuric acid. Dibenzothiophen (DBT) and ethylphenylsulfide (EPS) are serving as models of organic sulfur-containing components of coal in initial studies.

Process for coal liquefaction employing selective coal feed

DOEpatents

Hoover, David S.; Givens, Edwin N.

1983-01-01

An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogen-rich gases at elevated temperatures and pressures, following which solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. The selected feed coals comprise washed coals having a substantial amount of mineral matter, preferably from about 25-75%, by weight, based upon run-of-mine coal, removed with at least 1.0% by weight of pyritic sulfur remaining and exhibiting vitrinite reflectance of less than about 0.70%.

Characteristics of Pyrolytic Topping in Fluidized Bed for Different Volatile Coals

NASA Astrophysics Data System (ADS)

Xiong, R.; Dong, L.; Xu, G. W.

Coal is generally combusted or gasified directly to destroy completely the chemical structures, such as aromatic rings containing in volatile coals including bituminite and lignite. Coal topping refers to a process that extracts chemicals with aromatic rings from such volatile coals in advance of combustion or gasification and thereby takes advantage of the value of coal as a kind of chemical structure resource. CFB boiler is the coal utilization facility that can be easily retrofitted to implement coal topping. A critical issue for performing coal topping is the choice of the pyrolytic reactor that can be different types. The present study concerns fluidized bed reactor that has rarely been tested for use in coal topping. Two different types of coals, one being Xiaolongtan (XLT) lignite and the other Shanxi (SX) bituminous, were tested to clarify the yield and composition of pyrolysis liquid and gas under conditions simulating actual operations. The results showed that XLT lignite coals had the maximum tar yield in 823-873K and SX bituminite realized its highest tar yield in 873-923K. Overall, lignite produced lower tar yield than bituminous coal. The pyrolysis gas from lignite coals contained more CO and CO2 and less CH4, H2 and C2+C3 (C2H4, C2H6, C3H6, C3H8) components comparing to that from bituminous coal. TG-FTIR analysis of tars demonstrated that for different coals there are different amounts of typical chemical species. Using coal ash of CFB boiler, instead of quartz sand, as the fluidized particles decreased the yields of both tar and gas for all the tested coals. Besides, pyrolysis in a reaction atmosphere simulating the pyrolysis gas (instead of N2) resulted also in higher production of pyrolysis liquid.

Method of extracting coal from a coal refuse pile

DOEpatents

Yavorsky, Paul M.

1991-01-01

A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons

USGS Publications Warehouse

Warwick, Peter D.

2005-01-01

Coal is an important and required energy source for today's world. Current rates of world coal consumption are projected to continue at approximately the same (or greater) levels well into the twenty-first century. This paper will provide an introduction to the concept of coal systems analysis and the accompanying volume of papers will provide examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Coal systems analysis incorporates the various disciplines of coal geology to provide a complete characterization of the resource. The coal system is divided into four stages: (1) accumulation, (2) preservation-burial, (3) diagenesis-coalification, and (4) coal and hydrocarbon resources. These stages are briefly discussed and key references and examples of the application of coal systems analysis are provided.

New electrostatic coal cleaning method cuts sulfur content by 40%

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-12-01

An emission control system that electrically charges pollutants and coal particles promises to reduce sulfur 40% at half the cost. The dry coal cleaning processes offer superior performance and better economics than conventional flotation cleaning. Advanced Energy Dynamics, Inc. (AED) is developing both fine and ultra fine processes which increase combustion efficiency and boiler reliability and reduced operating costs. The article gives details from the performance tests and comparisons and summarizes the economic analyses. 4 tables.

Ways to Improve Russian Coal-Fired Power Plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tumanovskii, A. G., E-mail: vti@vti.ru; Olkhovsky, G. G.

Coal is an important fuel for the electric power industry of Russia, especially in Ural and the eastern part of the country. It is fired in boilers of large (200 – 800 MW) condensing power units and in many cogeneration power plants with units rated at 50 – 180 MW. Many coal-fired power plants have been operated for more than 40 – 50 years. Though serviceable, their equipment is obsolete and does not comply with the current efficiency, environmental, staffing, and availability standards. It is urgent to retrofit and upgrade such power plants using advanced equipment, engineering and business ideas.more » Russian power-plant engineering companies have designed such advanced power units and their equipment such as boilers, turbines, auxiliaries, process and environmental control systems similar to those produced by the world’s leading manufacturers. Their performance and ways of implementation are discussed.« less

Beneficial uses of radiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fox, M.R.

1991-10-01

An overall decline in technical literacy within the American public has come at a time when technological advances are accelerating in the United States and around the world. This had led to a large communication gulf between the general public and the technologists. Nowhere is this more evident then with the topic of radiation. Regrettably, too few people know about sources of radiation, the pervasiveness, amounts, and variabilities, and do not have a true understanding of the environment in which we live. Nor do many people know that radiation has been used in beneficial ways for decades around the world.more » While the general public does not know of the scientific applications to which radiation has been deployed, it nevertheless had benefited tremendously from these efforts. Thanks to the well know properties of radiation, scientific ingenuity has found many uses of radiation in chemical and agricultural research, biomedical research, in the diagnoses and treatment of hundreds of types of diseases, in industrial applications, food irradiation, and many others. This paper provides a sample of the types of uses to which radiation has been used to help advance the betterment of humankind.« less

Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of three-dimensional catalytic electro-Fenton and membrane bioreactor.

PubMed

Jia, Shengyong; Han, Hongjun; Hou, Baolin; Zhuang, Haifeng

2015-12-01

Laboratorial scale experiments were conducted to investigate a novel system three-dimensional catalytic electro-Fenton (3DCEF, catalyst of sewage sludge based activated carbon which loaded Fe3O4) integrating with membrane bioreactor (3DCEF-MBR) on advanced treatment of biologically pretreated coal gasification wastewater. The results indicated that 3DCEF-MBR represented high efficiencies in eliminating COD and total organic carbon, giving the maximum removal efficiencies of 80% and 75%, respectively. The integrated 3DCEF-MBR system significantly reduced the transmembrane pressure, giving 35% lower than conventional MBR after 30 days operation. The enhanced hydroxyl radical oxidation and bacteria self repair function were the mechanisms for 3DCEF-MBR performance. Therefore, the integrated 3DCEF-MBR was expected to be the promising technology for advanced treatment in engineering applications. Copyright © 2015. Published by Elsevier Ltd.

Cause and cure for high volatile coal and corrosive gases at TXI, Midlothian Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shahid, A.; Bottelberghe, B.; Crowther, J.

2007-07-01

The plant has raw materials which are high in pyritic sulfur. The coal mill uses the preheater exhaust gases, which have elevated amounts of SO{sub 2}. The coal being used is highly volatile. Therefore the coal mill bag filter had few occurrences of smoldered bags causing potentially unsafe conditions. This problem was solved by implementing some operational changes like reducing the mill exit temperature based on dewatering curve of coal and making the system more inert. To achieve this water had to be added into the system. When the mill exit temperature was reduced, the operating temperatures were below themore » sulfuric and hydrochloric acid dew points. Because of this corrosive acid stream in the gas flow, the bag filter started corroding. En route to solving these issues, the plant neutralized the acid by adding the raw meal dust and changing the bag filter into a stainless steel construction. Furthermore, the requirement to spray water in the system was removed by adding a heat exchanger to the coal mill inlet. Also, there were some design changes made to the coal mill bag filter, which helped in stable operation and extended bag life in the bag filter. This paper discusses these issues and how these problems were solved. This paper would be of beneficial use for other plants, which have to deal with high volatile coal and highly corrosive gases.« less

Method for recovering light hydrocarbons from coal agglomerates

DOEpatents

Huettenhain, Horst; Benz, August D.; Getsoian, John

1991-01-01

A method and apparatus for removing light hydrocarbons, such as heptane, from coal agglomerates includes an enclosed chamber having a substantially horizontal perforate surface therein. The coal agglomerates are introduced into a water bath within the chamber. The agglomerates are advanced over the surface while steam is substantially continuously introduced through the surface into the water bath. Steam heats the water and causes volatilization of the light hydrocarbons, which may be collected from the overhead of the chamber. The resulting agglomerates may be collected at the opposite end from the surface and subjected to final draining processes prior to transportation or use.

MECHANISMS OF NITROUS OXIDE FORMATION IN COAL FLAMES

EPA Science Inventory

The paper gives results of a study, using both detailed kinetic modeling and plug-flow simulator experiments, to investigate an unknown mechanism by which N2O is formed in coal flames. This mechanism has considerable importance in determining the influence of common and advanced ...

Variability of Mercury Content in Coal Matter From Coal Seams of The Upper Silesia Coal Basin

NASA Astrophysics Data System (ADS)

Wierzchowski, Krzysztof; Chećko, Jarosław; Pyka, Ireneusz

2017-12-01

The process of identifying and documenting the quality parameters of coal, as well as the conditions of coal deposition in the seam, is multi-stage and extremely expensive. The taking and analyzing of seam samples is the method of assessment of the quality and quantity parameters of coals in deep mines. Depending on the method of sampling, it offers quite precise assessment of the quality parameters of potential commercial coals. The main kind of seam samples under consideration are so-called "documentary seam samples", which exclude dirt bands and other seam contaminants. Mercury content in coal matter from the currently accessible and exploited coal seams of the Upper Silesian Coal Basin (USCB) was assessed. It was noted that the mercury content in coal seams decreases with the age of the seam and, to a lesser extent, seam deposition depth. Maps of the variation of mercury content in selected lithostratigraphic units (layers) of the Upper Silesian Coal Basin have been created.

Interrelating the breakage and composition of mined and drill core coal

NASA Astrophysics Data System (ADS)

Wilson, Terril Edward

Particle size distribution of coal is important if the coal is to be beneficiated, or if a coal sales contract includes particle size specifications. An exploration bore core sample of coal ought to be reduced from its original cylindrical form to a particle size distribution and particle composition that reflects, insofar as possible, a process stream of raw coal it represents. Often, coal cores are reduced with a laboratory crushing machine, the product of which does not match the raw coal size distribution. This study proceeds from work in coal bore core reduction by Australian investigators. In this study, as differentiated from the Australian work, drop-shatter impact breakage followed by dry batch tumbling in steel cylinder rotated about its transverse axis are employed to characterize the core material in terms of first-order and zeroth-order breakage rate constants, which are indices of the propensity of the coal to degrade during excavation and handling. Initial drop-shatter and dry tumbling calibrations were done with synthetic cores composed of controlled low-strength concrete incorporating fly ash (as a partial substitute for Portland cement) in order to reduce material variables and conserve difficult-to-obtain coal cores. Cores of three different coalbeds--Illinois No. 6, Upper Freeport, and Pocahontas No. 5 were subjected to drop-shatter and dry batch tumbling tests to determine breakage response. First-order breakage, characterized by a first-order breakage index for each coal, occurred in the drop-shatter tests. First- and zeroth-order breakage occurred in dry batch tumbling; disappearance of coarse particles and creation of fine particles occurred in a systematic way that could be represented mathematically. Certain of the coal cores available for testing were dry and friable. Comparison of coal preparation plant feed with a crushed bore core and a bore core prepared by drop-shatter and tumbling (all from the same Illinois No.6 coal mining

What component of coal causes coal workers' pneumoconiosis?

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCunney, R.J.; Morfeld, P.; Payne, S.

2009-04-15

The objective was to evaluate the component of coal responsible for coal workers' pneumoconiosis (CWP). A literature search of PubMED was conducted to address studies that have evaluated the risk of CWP based on the components of coal. The risk of CWP (CWP) depends on the concentration and duration of exposure to coal dust. Epidemiology studies have shown inverse links between CWP and quartz content. Coal from the USA and Germany has demonstrated links between iron content and CWP; these same studies indicate virtually no role for quartz. In vitro studies indicate strong mechanistic links between iron content in coalmore » and reactive oxygen species, which play a major role in the inflammatory response associated with CWP. The active agent within coal appears to be iron, not quartz. By identifying components of coal-before mining activities, the risk of developing CWP may be reduced.« less

Status of NO sub x control for coal-fired power plants

NASA Technical Reports Server (NTRS)

Teixeira, D. P.

1978-01-01

The status of technologies for controlling emissions of oxides of nitrogen (NOx) from coal-fired power plants is reviewed. A discussion of current technology as well as future NOx control approaches is presented. Advanced combustion approaches are included as well as post-combustion alternatives such as catalytic and noncatalytic ammonia-bases systems and wet scrubbing. Special emphasis is given to unresolved development issues as they relate to practical applications on coal-fired power plants.

Coal systems analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warwick, P.D.

This collection of papers provides an introduction to the concept of coal systems analysis and contains examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Chapter are: Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons by Peter D. Warwick. Appalachian coal assessment: Defining the coal systems of the Appalachian Basin by Robert C. Milici. Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coalmore » Field, USA by Stephen F. Greb, Cortland F. Eble, and J.C. Hower. Palynology in coal systems analysis The key to floras, climate, and stratigraphy of coal-forming environments by Douglas J. Nichols. A comparison of late Paleocene and late Eocene lignite depositional systems using palynology, upper Wilcox and upper Jackson Groups, east-central Texas by Jennifer M.K. O'Keefe, Recep H. Sancay, Anne L. Raymond, and Thomas E. Yancey. New insights on the hydrocarbon system of the Fruitland Formation coal beds, northern San Juan Basin, Colorado and New Mexico, USA by W.C. Riese, William L. Pelzmann, and Glen T. Snyder.« less

Coal-Powered Electric Generating Unit Efficiency and Reliability Dialogue: Summary Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taylor, Emmanuel

Coal continues to play a critical role in powering the Nation’s electricity generation, especially for baseload power plants. With aging coal generation assets facing decreased performance due to the state of the equipment, and with challenges exacerbated by the current market pressures on the coal sector, there are opportunities to advance early-stage technologies that can retrofit or replace equipment components. These changes will eventually result in significant improvements in plant performance once further developed and deployed by industry. Research and development in areas such as materials, fluid dynamics, fuel properties and preparation characteristics, and a new generation of plant controlsmore » can lead to new components and systems that can help improve the efficiency and reliability of coal-fired power plants significantly, allowing these assets to continue to provide baseload power. Coal stockpiles at electricity generation plants are typically large enough to provide 30 to 60 days of power prior to resupply—significantly enhancing the stability and reliability of the U.S. electricity sector. Falling prices for non-dispatchable renewable energy and mounting environmental regulations, among other factors, have stimulated efforts to improve the efficiency of these coal-fired electric generating units (EGUs). In addition, increased reliance on natural gas and non-dispatchable energy sources has spurred efforts to further increase the reliability of coal EGUs. The Coal Powered EGU Efficiency and Reliability Dialogue brought together stakeholders from across the coal EGU industry to discuss methods for improvement. Participants at the event reviewed performance-enhancing innovations in coal EGUs, discussed the potential for data-driven management practices to increase efficiency and reliability, investigated the impacts of regulatory compliance on coal EGU performance, and discussed upcoming challenges for the coal industry. This report documents

Liquefaction of black thunder coal with counterflow reactor technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parker, R.J.; Simpson, P.L.

There is currently a resurgence of interest in the use of carbon monoxide and water to promote the solubilization of low rank coals in liquefaction processes. The mechanism for the water shift gas reaction (WGSR) is well documented and proceeds via a formate ion intermediate at temperatures up to about 400{degrees}C. Coal solubilization is enhanced by CO/H{sub 2}O and by the solvent effect of the supercritical water. The WGSR is catalyzed by bases (alkali metal carbonates, hydroxides, acetates, aluminates). Many inorganic salts which promote catalytic hydrogenation are rendered inactive in CO/H{sub 2}O, although there is positive evidence for the benefitmore » of using pyrite for both the WGSR and as a hydrogenation catalyst. The temperatures at which coal solubilization occurs are insufficient to promote extensive cracking or upgrading of the solubilized coal. Therefore, a two step process might achieve these two reactions sequentially. Alberta Research Council (ARC) has developed a two-stage process for the coprocessing of low rank coals and petroleum resids/bitumens. This process was further advanced by utilizing the counterflow reactor (CFR) concept pioneered by Canadian Energy Developments (CED) and ARC. The technology is currently being applied to coal liquefaction. The two-stage process employs CO/H{sub 2}O at relatively mid temperature and pressure to solubilize the coal, followed by a more severe hydrocracking step. This paper describes the results of an autoclave study conducted to support a bench unit program on the direct liquefaction of coals.« less

Cultural hitchhiking on the wave of advance of beneficial technologies.

PubMed

Ackland, Graeme J; Signitzer, Markus; Stratford, Kevin; Cohen, Morrel H

2007-05-22

The wave-of-advance model was introduced to describe the spread of advantageous genes in a population. It can be adapted to model the uptake of any advantageous technology through a population, such as the arrival of neolithic farmers in Europe, the domestication of the horse, and the development of the wheel, iron tools, political organization, or advanced weaponry. Any trait that preexists alongside the advantageous one could be carried along with it, such as genetics or language, regardless of any intrinsic superiority. Decoupling of the advantageous trait from other "hitchhiking" traits depends on its adoption by the preexisting population. Here, we adopt a similar wave-of-advance model based on food production on a heterogeneous landscape with multiple populations. Two key results arise from geographic inhomogeneity: the "subsistence boundary," land so poor that the wave of advance is halted, and the temporary "diffusion boundary" where the wave cannot move into poorer areas until its gradient becomes sufficiently large. At diffusion boundaries, farming technology may pass to indigenous people already in those poorer lands, allowing their population to grow and resist encroachment by farmers. Ultimately, this adoption of technology leads to the halt in spread of the hitchhiking trait and establishment of a permanent "cultural boundary" between distinct cultures with equivalent technology.

Coal resource assessments using coal availability and recoverability methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rohrbacher, T.J.

1997-12-01

The U.S. Geological Survey (USGS), in conjunction with state geological surveys and other federal agencies, has initiated a study and developed methodology to reassess the nation`s major coal resources. This study differs from previous coal resource assessments of the USGS, U.S. Bureau of Mines, and the Department of Energy`s Energy Information Administration, because this program: (1) Identifies and characterizes the coal beds and coal zones that will provide the bulk of the nation`s coal-derived energy during the first quarter of the twenty-first century; (2) organizes geologic, chemical, environmental, and geographic information in digital format and makes these data available tomore » the public through the Internet or other digital media, such as CD ROMs; (3) includes coal resource availability and coal recoverability analyses for selected areas; (4) provides economic assessments and coal recoverability analyses for selected areas; (5) provides methodology to perform socio-economic impact analysis related to coal mining in specific geographical areas as small as a county.« less

Refinery Integration of By-Products from Coal-Derived Jet Fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Caroline Clifford; Andre Boehman; Chunshan Song

2008-03-31

commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler

13. Coal ejectors mounted on aft bulkhead of coal bunker. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

13. Coal ejectors mounted on aft bulkhead of coal bunker. Ejectors were used to flush overboard live coals and clinkers from firebed (pipe for carrying coals overboard has been removed from ejector in foreground). Coal doors from bunker appear beside ejector in foreground). Coal doors from bunker appear beside ejectors at deck; note firing shovels in background against hull. - Steamboat TICONDEROGA, Shelburne Museum Route 7, Shelburne, Chittenden County, VT

Appalachian coal assessment: Defining the coal systems of the Appalachian basin

USGS Publications Warehouse

Milici, R.C.

2005-01-01

The coal systems concept may be used to organize the geologic data for a relatively large, complex area, such as the Appalachian basin, in order to facilitate coal assessments in the area. The concept is especially valuable in subjective assessments of future coal production, which would require a detailed understanding of the coal geology and coal chemistry of the region. In addition, subjective assessments of future coal production would be enhanced by a geographical information system that contains the geologic and geochemical data commonly prepared for conventional coal assessments. Coal systems are generally defined as one or more coal beds or groups of coal beds that have had the same or similar genetic history from their inception as peat deposits, through their burial, diagenesis, and epigenesis to their ultimate preservation as lignite, bituminous coal, or anthracite. The central and northern parts of the Appalachian basin contain seven coal systems (Coal Systems A-G). These systems may be defined generally on the following criteria: (1) on the primary characteristics of their paleopeat deposits, (2) on the stratigraphic framework of the Paleozoic coal measures, (3) on the relative abundance of coal beds within the major stratigraphic groupings, (4) on the amount of sulfur related to the geologic and climatic conditions under which paleopeat deposits accumulated, and (5) on the rank of the coal (lignite to anthracite). ??2005 Geological Society of America.

Fundamental modelling of pulverized coal and coal-water slurry combustion in a gas turbine combustor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chatwani, A.; Turan, A.; Hals, F.

1988-06-01

A large portion of world energy resources is in the form of low grade coal. There is need to utilize these resources in an efficient and environmentally clean way. The specific approach under development by us is direct combustion in a multistage slagging combustor, incorrporating control of NO/sub x/, SO/sub x/, and particulates. The toroidal vortex combustor is currently under development through a DOE contract to Westinghouse and subcontract to ARL. This subscale, coal-fired, 6MW combustor will be built and become operational in 1988. The coal fuel is mixed with preheated air, injected through a number of circumferentially-located jets orientedmore » in the radius axis planes. The jets merge at the centerline, forming a vertically directed jet which curves around the combustor dome wall and gives rise to a toroidal shaped vortex. This vortex helps to push the particles radially outward, hit the walls through inertial separation and promote slagging. It also provides a high intensity flow mixing zone to enhance combustion product uniformity, and a primary mechanism for heat feed back to the incoming flow for flame stabilization. The paper describes the essential features of a coal combustion model which is incorporated into a three-dimensional, steady-state, two-phase, turbulent, reactive flow code. The code is a modified and advanced version of INTERN code originally developed at Imperial College which has gone through many stages of development and validation.« less

CAMD studies of coal structure and coal liquefaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Faulon, J.L.; Carlson, G.A.

The macromolecular structure of coal is essential to understand the mechanisms occurring during coal liquefaction. Many attempts to model coal structure can be found in the literature. More specifically for high volatile bituminous coal, the subject of interest the most commonly quoted models are the models of Given, Wiser, Solomon, and Shinn. In past work, the authors`s have used computer-aided molecular design (CAMD) to develop three-dimensional representations for the above coal models. The three-dimensional structures were energy minimized using molecular mechanics and molecular dynamics. True density and micopore volume were evaluated for each model. With the exception of Given`s model,more » the computed density values were found to be in agreement with the corresponding experimental results. The above coal models were constructed by a trial and error technique consisting of a manual fitting of the-analytical data. It is obvious that for each model the amount of data is small compared to the actual complexity of coal, and for all of the models more than one structure can be built. Hence, the process by which one structure is chosen instead of another is not clear. In fact, all the authors agree that the structure they derived was only intended to represent an {open_quotes}average{close_quotes} coal model rather than a unique correct structure. The purpose of this program is further develop CAMD techniques to increase the understanding of coal structure and its relationship to coal liquefaction.« less

Safety evaluation methodology for advanced coal extraction systems

NASA Technical Reports Server (NTRS)

Zimmerman, W. F.

1981-01-01

Qualitative and quantitative evaluation methods for coal extraction systems were developed. The analysis examines the soundness of the design, whether or not the major hazards have been eliminated or reduced, and how the reduction would be accomplished. The quantitative methodology establishes the approximate impact of hazards on injury levels. The results are weighted by peculiar geological elements, specialized safety training, peculiar mine environmental aspects, and reductions in labor force. The outcome is compared with injury level requirements based on similar, safer industries to get a measure of the new system's success in reducing injuries. This approach provides a more detailed and comprehensive analysis of hazards and their effects than existing safety analyses.

43 CFR 3483.4 - Payment of advance royalty in lieu of continued operation.

Code of Federal Regulations, 2014 CFR

2014-10-01

... of the Federal coal will be calculated in accordance with § 3485.2 of this title and this section... coal reserves or the Federal LMU recoverable coal reserves. The advance royalty rate for an LMU shall be deemed to be 8 percent where the Federal LMU recoverable coal reserves contained in the LMU would...

43 CFR 3483.4 - Payment of advance royalty in lieu of continued operation.

Code of Federal Regulations, 2012 CFR

2012-10-01

... of the Federal coal will be calculated in accordance with § 3485.2 of this title and this section... coal reserves or the Federal LMU recoverable coal reserves. The advance royalty rate for an LMU shall be deemed to be 8 percent where the Federal LMU recoverable coal reserves contained in the LMU would...

43 CFR 3483.4 - Payment of advance royalty in lieu of continued operation.

Code of Federal Regulations, 2013 CFR

2013-10-01

... of the Federal coal will be calculated in accordance with § 3485.2 of this title and this section... coal reserves or the Federal LMU recoverable coal reserves. The advance royalty rate for an LMU shall be deemed to be 8 percent where the Federal LMU recoverable coal reserves contained in the LMU would...

43 CFR 3483.4 - Payment of advance royalty in lieu of continued operation.

Code of Federal Regulations, 2011 CFR

2011-10-01

... of the Federal coal will be calculated in accordance with § 3485.2 of this title and this section... coal reserves or the Federal LMU recoverable coal reserves. The advance royalty rate for an LMU shall be deemed to be 8 percent where the Federal LMU recoverable coal reserves contained in the LMU would...

Liquefaction of calcium-containing subbituminous coals and coals of lower rank

DOEpatents

Brunson, Roy J.

1979-01-01

An improved process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation of scale, made up largely of calcium carbonate which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. An oxide of sulfur, in liquid phase, is contacted with a coal feed sufficient to impregnate the pores of the coal. The impregnated coal, in particulate form, can thereafter be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of scale.

Breaking the limits of structural and mechanical imaging of the heterogeneous structure of coal macerals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Collins, L.; Tselev, A.; Jesse, S.

The correlation between local mechanical (elasto-plastic) and structural (composition) properties of coal presents significant fundamental and practical interest for coal processing and the development of rheological models of coal to coke transformations and for advancing novel approaches. Here, we explore the relationship between the local structural, chemical composition and mechanical properties of coal using a combination of confocal micro-Raman imaging and band excitation atomic force acoustic microscopy (BE-AFAM) for a bituminous coal. This allows high resolution imaging (10s of nm) of mechanical properties of the heterogeneous (banded) architecture of coal and correlating them to the optical gap, average crystallite size,more » the bond-bending disorder of sp2 aromatic double bonds and the defect density. This methodology hence allows the structural and mechanical properties of coal components (lithotypes, microlithotypes, and macerals) to be understood, and related to local chemical structure, potentially allowing for knowledge-based modelling and optimization of coal utilization processes.« less

Cultural hitchhiking on the wave of advance of beneficial technologies

PubMed Central

Ackland, Graeme J.; Signitzer, Markus; Stratford, Kevin; Cohen, Morrel H.

2007-01-01

The wave-of-advance model was introduced to describe the spread of advantageous genes in a population. It can be adapted to model the uptake of any advantageous technology through a population, such as the arrival of neolithic farmers in Europe, the domestication of the horse, and the development of the wheel, iron tools, political organization, or advanced weaponry. Any trait that preexists alongside the advantageous one could be carried along with it, such as genetics or language, regardless of any intrinsic superiority. Decoupling of the advantageous trait from other “hitchhiking” traits depends on its adoption by the preexisting population. Here, we adopt a similar wave-of-advance model based on food production on a heterogeneous landscape with multiple populations. Two key results arise from geographic inhomogeneity: the “subsistence boundary,” land so poor that the wave of advance is halted, and the temporary “diffusion boundary” where the wave cannot move into poorer areas until its gradient becomes sufficiently large. At diffusion boundaries, farming technology may pass to indigenous people already in those poorer lands, allowing their population to grow and resist encroachment by farmers. Ultimately, this adoption of technology leads to the halt in spread of the hitchhiking trait and establishment of a permanent “cultural boundary” between distinct cultures with equivalent technology. PMID:17517663

Overview of Advanced Turbine Systems Program

NASA Astrophysics Data System (ADS)

Webb, H. A.; Bajura, R. A.

The US Department of Energy initiated a program to develop advanced gas turbine systems to serve both central power and industrial power generation markets. The Advanced Turbine Systems (ATS) Program will lead to commercial offerings by the private sector by 2002. ATS will be developed to fire natural gas but will be adaptable to coal and biomass firing. The systems will be: highly efficient (15 percent improvement over today's best systems); environmentally superior (10 percent reduction in nitrogen oxides over today's best systems); and cost competitive (10 percent reduction in cost of electricity). The ATS Program has five elements. Innovative cycle development will lead to the demonstration of systems with advanced gas turbine cycles using current gas turbine technology. High temperature development will lead to the increased firing temperatures needed to achieve ATS Program efficiency goals. Ceramic component development/demonstration will expand the current DOE/CE program to demonstrate industrial-scale turbines with ceramic components. Technology base will support the overall program by conducting research and development (R&D) on generic technology issues. Coal application studies will adapt technology developed in the ATS program to coal-fired systems being developed in other DOE programs.

Flash pyrolysis of coal, coal maceral, and coal-derived pyrite with on-line characterization of volatile sulfur compounds

USGS Publications Warehouse

Chou, I.-Ming; Lake, M.A.; Griffin, R.A.

1988-01-01

A Pyroprobe flash pyrolysis-gas chromatograph equipped with a flame photometric detector was used to study volatile sulfur compounds produced during the thermal decomposition of Illinois coal, coal macerals and coal-derived pyrite. Maximum evolution of volatile organic sulfur compounds from all coal samples occurred at a temperature of approximately 700??C. At this temperature, the evolution of thiophene, its alkyl isomers, and short-chain dialkyl sulfide compounds relative to the evolution of benzothiophene and dibenzothiophene compounds was greater from coal high in organic sulfur than from coal low in organic sulfur. The variation in the evolution of sulfur compounds observed for three separate coal macerals (exinite, vitrinite, and inertinite) was similar to that observed for whole coal samples. However, the variation trend for the macerals was much more pronounced. Decomposition of coal-derived pyrite with the evolution of elemental sulfur was detected at a temperature greater than 700??C. The results of this study indicated that the gas chromotographic profile of the volatile sulfur compounds produced during flash pyrolysis of coals and coal macerals varied as a function of the amount of organic sulfur that occurred in the samples. Characterization of these volatile sulfur compounds provides a better understanding of the behavior of sulfur in coal during the thermolysis process, which could be incorporated in the design for coal cleaning using flash pyrolysis techniques. ?? 1988.

Progress in donor assisted coal liquefaction: Hydroaromatic compound formation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kottenstette, R.J.; Stephens, H.P.

1993-12-31

The role of hydrogen donor compounds in coal liquefaction has been extensively investigated since the mid 1960`s using model compounds and process derived hydrogen donor solvents. Our recent research and that of other investigators have shown that two model compounds in particular have great efficacy in solvating low rank coals. 1,2,3,10b tetrahydrofluoranthene (H{sub 4}Fl) and 1,2,3,6,7,8 hexahydropyrene (H{sub 6}Py) have been used to dissolve Wyodak coal to > 95% soluble material as measured by tetrahydrofuran (THF). Although these hydrogen donors are very effective, they may not be found in any significant concentrations in actual liquefaction process recycle solvents. Therefore, studiesmore » with process derived recycle materials are necessary to understand donor solvent chemistry. The objective of this paper is to present results of solvent hydrogenation experiments using heavy distillate solvents produced during testing at the Wilsonville Advanced Coal Liquefaction Test Facility. We evaluated the impact of hydrogenation conditions upon hydrogen donor formation in process derived distillates and compared these process derived solvents with the highly effective H{sub 4}Fl and H{sub 6}Py donors in coal liquefaction tests. This paper presents data on reaction conditions used for distillate hydrotreating and subsequent coal liquefaction, with an aim toward understanding the relationship between reaction conditions and donor solvent quality in recycle distillates.« less

Coal desulfurization by chlorinolysis production and combustion test evaluation of product coals

NASA Technical Reports Server (NTRS)

Kalvinskas, J. J.; Daly, D.

1982-01-01

Laboratory-scale screening tests were carried out on coal from Harrison County, Ohio to establish chlorination and hydrodesulfurization conditions for the batch reactor production of chlorinolysis and chlorinolysis-hydrodesulfurized coals. In addition, three bituminous coals, were treated on the lab scale by the chlorinolysis process to provide 39 to 62% desulfurization. Two bituminous coals and one subbituminous coal were then produced in 11 to 15 pound lots as chlorinolysis and hydrodesulfurized coals. The chlorinolysis coals had a desulfurization of 29-69%, reductions in voltatiles and hydrogen. Hydrodesulfurization provided a much greater desulfurization (56-86%), reductions in volatiles and hydrogen. The three coals were combustion tested in the Penn State ""plane flame furnace'' to determine ignition and burning characteristics. All three coals burned well to completion as: raw coals, chlorinolysis processed coals, and hydrodesulfurized coals. The hydrodesulfurized coals experienced greater ignition delays and reduced burning rates than the other coals because of the reduced volatile content. It is thought that the increased open pore volume in the desulfurized-devolatilized coals compensates in part for the decreased volatiles effect on ignition and burning.

Coal resources, production, and quality in the Eastern kentucky coal field: Perspectives on the future of steam coal production

USGS Publications Warehouse

Hower, J.C.; Hiett, J.K.; Wild, G.D.; Eble, C.F.

1994-01-01

The Eastern Kentucky coal field, along with adjacent portions of Virginia and southern West Virginia, is part of the greatest production concentration of high-heating-value, low-sulfur coal in the United States, accounting for over 27% of the 1993 U.S. production of coal of all ranks. Eastern Kentucky's production is spread among many coal beds but is particularly concentrated in a limited number of highquality coals, notably the Pond Creek coal bed and its correlatives, and the Fire Clay coal bed and its correlatives. Both coals are relatively low ash and low sulfur through the areas of the heaviest concentration of mining activity. We discuss production trends, resources, and the quality of in-place and clean coal for those and other major coals in the region. ?? 1994 Oxford University Press.

Phyto-bioconversion of hard coal in the Cynodon dactylon/coal rhizosphere.

PubMed

Igbinigie, Eric E; Mutambanengwe, Cecil C Z; Rose, Peter D

2010-03-01

Fundamental processes involved in the microbial degradation of coal and its derivatives have been well documented. A mutualistic interaction between plant roots and certain microorganisms to aid growth of plants such as Cynodon dactylon (Bermuda grass) on hard coal dumps has recently been suggested. In the present study coal bioconversion activity of nonmycorrhizal fungi was investigated in the C. dactylon/coal rhizosphere. Fungal growth on 2% Duff-agar, gutation formation on nitric acid treated coal and submerged culture activity in nitrogen-rich and -deficient broth formed part of the screening and selection of the fungi. The selected fungal isolates were confirmed to be found in pristine C. dactylon/coal rhizosphere. To simulate bioconversion, a fungal aliquot of this rhizosphere was used as inoculum for a Perfusate fixed bed bioreactor, packed with coal. The results demonstrate an enhanced coal bioconversion facilitated by low molecular weight organics and the bioconversion of coal may be initiated by an introduction of nitrogen moieties to the coal substrate. These findings suggest a phyto-bioconversion of hard coal involving plant and microbes occurring in the rhizosphere to promote the growth of C. dactylon. An understanding of this relationship can serve as a benchmark for coal dumps rehabilitation as well as for the industrial scale bioprocessing of hard coal.

Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream

DOEpatents

Comolli, Alfred G.; McLean, Joseph B.

1989-01-01

A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

USGS Publications Warehouse

Hackley, P.C.; Martinez, M.

2007-01-01

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It

Subtask 3.9 - Direct Coal Liquefaction Process Development

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aulich, Ted; Sharma, Ramesh

The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha middle distillate stream for upgrading and 2) a recycle stream was completed inmore » May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.« less

Quarterly Coal Distribution

EIA Publications

2017-01-01

The Quarterly Coal Distribution Report (QCDR) provides detailed U.S. domestic coal distribution data by coal origin state, coal destination state, mode of transportation, and consuming sector. Quarterly data for all years are preliminary and will be superseded by the release of the corresponding Annual Coal Distribution Report.

Coal resources of the Sonda coal field, Sindh Province, Pakistan

USGS Publications Warehouse

Thomas, R.E.; Riaz, Khan M.; Ahmed, Khan S.

1993-01-01

Approximately 4.7 billion t of original coal resources, ranging from lignite A to subbituminous C in rank, are estimated to be present in the Sonda coal field. These resources occur in 10 coal zones in the Bara Formation of Paleocene age. The Bara Formation does not out crop in the area covered by this report. Thin discontinuous coal beds also occur in the Sonhari Member of the Laki Formation, of Paleocene and Eocene age, but they are unimportant as a resource of the Sonda coal field. The coal resource assessment was based on 56 exploratory drill holes that were completed in the Sonda field between April 1986 and February 1988. The Sonda coal field is split into two, roughly equal, areas by the southwestward flowing Indus River, a major barrier to the logistics of communications between the two halves. As a result the two halves, called the Sonda East and Sonda West areas, were evaluated at different times by slightlydifferent techniques; but, because the geology is consistent between the two areas, the results of both evaluations have been summarized in this report. The resource estimates for the Sonda East area, approximately 1,700 million t, were based on the thickest coal bed in each zone at each drill hole. This method gives a conservative estimate of the total amount of coal in the Sonda East area. The resource estimates for the Sonda West area, approximately 3,000 million t, were based on cumulative coal bed thicknesses within each coal zone, resulting in a more liberal estimate. In both cases, minimum parameters for qualifying coal were a thickness of 30 cm or greater and no more than 50% ash; partings thicker than 1 cm were excluded. The three most important coal zones in the Sonda field are the Inayatabad, the Middle Sonda and the Lower Sonda. Together, these three coal zones contain 50% of the total resources. Isopachs were constructed for the thickest coal beds in these three coal zones and indicate large variations in thickness over relatively small

Carbon dioxide from coal combustion: Variation with rank of US coal

USGS Publications Warehouse

Quick, J.C.; Glick, D.C.

2000-01-01

Carbon dioxide from combustion of US coal systematically varies with ASTM rank indices, allowing the amount of CO2 produced per net unit of energy to be predicted for individual coals. No single predictive equation is applicable to all coals. Accordingly, we provide one equation for coals above high volatile bituminous rank and another for lower rank coals. When applied to public data for commercial coals from western US mines these equations show a 15% variation of kg CO2 (net GJ)-1. This range of variation suggests reduction of US CO2 emissions is possible by prudent selection of coal for combustion. Maceral and mineral content are shown to slightly affect CO2 emissions from US coal. We also suggest that CO2 emissions increased between 6 and 8% in instances where Midwestern US power plants stopped burning local, high-sulfur bituminous coal and started burning low-sulfur, subbituminous C rank coal from the western US.

High temperature alkali corrosion of ceramics in coal gas: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pickrell, G.R.; Sun, T.; Brown, J.J. Jr.

1994-12-31

There are several ceramic materials which are currently being considered for use as structural elements in coal combustion and coal conversion systems because of their thermal and mechanical properties. These include alumina (refractories, membranes, heat engines); silicon carbide and silicon nitride (turbine engines, internal combustion engines, heat exchangers, particulate filters); zirconia (internal combustion engines, turbine engines, refractories); and mullite and cordierite (particulate filters, refractories, heat exchangers). High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and highmore » efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, and zirconia. The study consists of identification of the alkali reaction products and determination of the kinetics of the alkali reactions as a function of temperature and time. 145 refs., 29 figs., 12 tabs.« less

CoalFleet RD&D augmentation plan for integrated gasification combined cycle (IGCC) power plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

2007-01-15

To help accelerate the development, demonstration, and market introduction of integrated gasification combined cycle (IGCC) and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiative, which facilitates collaborative research by more than 50 organizations from around the world representing power generators, equipment suppliers and engineering design and construction firms, the U.S. Department of Energy, and others. This group advised EPRI as it evaluated more than 120 coal-gasification-related research projects worldwide to identify gaps or critical-path activities where additional resources and expertise could hasten the market introduction of IGCC advances. The resulting 'IGCC RD&D Augmentation Plan' describes such opportunitiesmore » and how they could be addressed, for both IGCC plants to be built in the near term (by 2012-15) and over the longer term (2015-25), when demand for new electric generating capacity is expected to soar. For the near term, EPRI recommends 19 projects that could reduce the levelized cost-of-electricity for IGCC to the level of today's conventional pulverized-coal power plants with supercritical steam conditions and state-of-the-art environmental controls. For the long term, EPRI's recommended projects could reduce the levelized cost of an IGCC plant capturing 90% of the CO{sub 2} produced from the carbon in coal (for safe storage away from the atmosphere) to the level of today's IGCC plants without CO{sub 2} capture. EPRI's CoalFleet for Tomorrow program is also preparing a companion RD&D augmentation plan for advanced-combustion-based (i.e., non-gasification) clean coal technologies (Report 1013221). 7 refs., 30 figs., 29 tabs., 4 apps.« less

VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eric M. Suuberg; Vahur Oja

1997-07-01

This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization whichmore » have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.« less

Coal and Energy.

ERIC Educational Resources Information Center

Bryant, Reba; And Others

This teaching unit explores coal as an energy resource. Goals, student objectives, background information, and activity options are presented for each major section. The sections are: (1) an introduction to coal (which describes how and where coal was formed and explains the types of coal); (2) the mining of coal (including the methods and ways of…

Kinetics of fly ash beneficiation by carbon burnout. [Quarterly report], October 1, 1995--January 30, 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dodoo, J.N.; Okoh, J.M.; Yilmaz, E.

The objective is to investigate the kinetics of beneficiation of fly ash by carbon burnout. The three year project that was proposed is a joint venture between Delmarva Power, a power generating company on the eastern shore of Maryland, and the University of Maryland Eastern Shore. The studies have focused on the beneficiation of fly ash by carbon burnout. The increasing use of coal fly ash as pozzolanic material in Portland cement concrete means that there is the highest economic potential in marketability of large volumes of fly ash. For the concrete industry to consider large scale use the flymore » ash must be of the highest quality. This means that the residual carbon content of the fly ash must have an acceptable loss on ignition (LOI) value, usually between 7--2% residual carbon. The economic gains to be had from low-carbon ash is a fact that is generally accepted by the electricity generating companies. However, since the cost of producing low-carbon in large quantities, based on present technology, far outweighs any financial gains, no electrical power company using coal as its fuel at present considers the effort worthwhile. The concrete industry would use fly ash in cement concrete mix if it can be assured of its LOI value. At present no utility company would give such assurance. Hence with several million tons of fly ash produced by a single power plant per year all that can be done is to dump the fly ash in landfills. The kinetics of fly ash beneficiation have been investigated in the zone II kinetic regime, using a Cahn TG 121 microbalance in the temperature 550--750{degrees}C. The P{sub 02} and total surface area dependence of the reaction kinetics were determined using a vacuum accessory attached to the microbalance and a surface area analyzer (ASAP 2010), respectively.« less

A burner for plasma-coal starting of a boiler

NASA Astrophysics Data System (ADS)

Peregudov, V. S.

2008-04-01

Advanced schemes of a plasma-coal burner with single-and two-stage chambers for thermochemical preparation of fuel are described. The factors causing it becoming contaminated with slag during oil-free starting of a boiler are considered, and methods for preventing this phenomenon are pointed out.

[Coal fineness effect on primary particulate matter features during pulverized coal combustion].

PubMed

Lü, Jian-yi; Li, Ding-kai

2007-09-01

Three kinds of coal differed from fineness were burned in a laboratory-scale drop tube furnace for combustion test, and an 8-stage Andersen particle impactor was employed for sampling the primary particulate matter (PM), in order to study coal fineness effect on primary PM features during pulverized coal combustion. It has been shown that the finer the coal was, the finer the PM produced. PM, emission amount augmented with coal fineness decreased, and the amount of PM10 increased from 13 mg/g to 21 mg/g respectively generated by coarse coal and fine coal. The amount of PM2.5 increased from 2 mg/g to 8 mg/g at the same condition. Constituents and content in bulk ash varied little after three different fineness coal combustion, while the appearance of grading PM differed visibly. The value of R(EE) increased while the coal fineness deceased. The volatility of trace elements which were investigated was Pb > Cr > Zn > Cu > Ni in turn. The concentration of poisonous trace elements was higher which generated from fine coal combustion. The volatilization capacity was influenced little by coal fineness, but the volatilization extent was influenced differently by coal fineness. Fine coal combustion affects worse environment than coarse coal does.

DEVELOPMENT, TESTING, AND DEMONSTRATION OF AN OPTIMAL FINE COAL CLEANING CIRCUIT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steven R. Hadley; R. Mike Mishra; Michael Placha

1999-01-27

The objective of this project was to improve the efficiency of the fine coal froth flotation circuit in commercial coal preparation plants. The plant selected for this project, Cyprus Emerald Coal Preparation Plant, cleans 1200-1400 tph of Pittsburgh seam raw coal and uses conventional flotation cells to clean the minus 100-mesh size fraction. The amount of coal in this size fraction is approximately 80 tph with an average ash content of 35%. The project was carried out in two phases. In Phase I, four advanced flotation cells, i.e., a Jameson cell, an Outokumpu HG tank cell, an open column, andmore » a packed column cell, were subjected to bench-scale testing and demonstration. In Phase II, two of these flotation cells, the Jameson cell and the packed column, were subjected to in-plant, proof-of-concept (POC) pilot plant testing both individually and in two-stage combination in order to ascertain whether a two-stage circuit results in lower levelized production costs. The bench-scale results indicated that the Jameson cell and packed column cell would be amenable to the single- and two-stage flotation approach. POC tests using these cells determined that single-stage coal matter recovery (CMR) of 85% was possible with a product ash content of 5.5-7%. Two-stage operation resulted in a coal recovery of 90% with a clean coal ash content of 6-7.5%. This compares favorably with the plant flotation circuit recovery of 80% at a clean coal ash of 11%.« less

Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vukasinovic-Pesic, V.; Rajakovic, L.J.

2009-07-01

The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn inmore » the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.« less

Coal combustion products

USGS Publications Warehouse

Kalyoncu, R.S.; Olson, D.W.

2001-01-01

Coal-burning powerplants, which supply more than half of U.S. electricity, also generate coal combustion products, which can be both a resource and a disposal problem. The U.S. Geological Survey collaborates with the American Coal Ash Association in preparing its annual report on coal combustion products. This Fact Sheet answers questions about present and potential uses of coal combustion products.

Attitudes toward Women Coal Miners in an Appalachian Coal Community.

ERIC Educational Resources Information Center

Trent, Roger B.; Stout-Wiegand, Nancy

1987-01-01

In a coal mining community, a survey revealed that the level of negative sentiment toward women coal miners was substantial and varied by gender role. Male coal miners were negative toward female co-workers, but they supported women's right to coal mine jobs, while female homemakers did not. (Author/CH)

Health impacts of coal and coal use: Possible solutions

USGS Publications Warehouse

Finkelman, R.B.; Orem, W.; Castranova, V.; Tatu, C.A.; Belkin, H.E.; Zheng, B.; Lerch, H.E.; Maharaj, S.V.; Bates, A.L.

2002-01-01

Coal will be a dominant energy source in both developed and developing countries for at least the first half of the 21st century. Environmental problems associated with coal, before mining, during mining, in storage, during combustion, and postcombustion waste products are well known and are being addressed by ongoing research. The connection between potential environmental problems with human health is a fairly new field and requires the cooperation of both the geoscience and medical disciplines. Three research programs that illustrate this collaboration are described and used to present a range of human health problems that are potentially caused by coal. Domestic combustion of coal in China has, in some cases, severely affected human health. Both on a local and regional scale, human health has been adversely affected by coals containing arsenic, fluorine, selenium, and possibly, mercury. Balkan endemic nephropathy (BEN), an irreversible kidney disease of unknown origin, has been related to the proximity of Pliocene lignite deposits. The working hypothesis is that groundwater is leaching toxic organic compounds as it passes through the lignites and that these organics are then ingested by the local population contributing to this health problem. Human disease associated with coal mining mainly results from inhalation of particulate matter during the mining process. The disease is Coal Worker's Pneumoconiosis characterized by coal dust-induced lesions in the gas exchange regions of the lung; the coal worker's "black lung disease". ?? 2002 Elsevier Science B.V. All rights reserved.

Liquefaction of calcium-containing subbituminous coals and coals of lower rank

DOEpatents

Gorbaty, Martin L.; Taunton, John W.

1980-01-01

A process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation scale, made up largely of calcium carbonate deposits, e.g., vaterite, which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. A solution of a compound or salt characterized by the formula MX, where M is a Group IA metal of the Periodic Table of the Elements, and X is an anion which is capable of forming water-insoluble, thermally stable calcium compounds, is maintained in contact with a particulate coal feed sufficient to impregnate said salt or compound into the pores of the coal. On separation of the impregnated particulate coal from the solution, the coal can be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of vaterite or other forms of calcium carbonate on reactor surfaces, auxiliary equipment and the like; and the Group IA metal which remains within the liquefaction bottoms catalyzes the reaction when the liquefaction bottoms are subjected to a gasification reaction.

Oxidation and carbonisation of coals: a case study of coal fire affected coals from the Wuda coalfield, Inner Mongolia, China

NASA Astrophysics Data System (ADS)

Kus, Jolanta; Meyer, Uwe; Ma, Jianwei; Chen-Brauchler, Dai

2010-05-01

At the coalfield of Wuda (Inner Mongolia, PR China) extensive underground coal fires cause widespread thermal and oxidative effects in coal seams. Within phase B of the Coal Fire Research Project of the Sino-German Initiative, methods for innovative fire-extinguishing technologies were investigated in multifaceted research approaches. Extensive investigations of oxidative and thermally affected coal seams in coal fire zone 18 were conducted in 2008 prior to application of new fire-extinguishing methods. We present results from the outcrop of coal seam No. 4 in the fire zone 18. The coal of seam No. 4 is of Early Permian age and belongs stratigraphically to the Shanxi Formation. The unaffected coal displays a high volatile bituminous A rank with a background value of random vitrinite reflectance ranging from 0.90 to 0.96 % Rr. Coal channel samples were coallected at actively extracted coal faces along multiple profiles with surface temperatures ranging from about 50° to 600°C. Microscopic examinations revealed a variety of products of coal exposure to the fire. Within coal samples, a marked rise in vitrinite reflectance from background values to 5.55% Rr (6.00 % Rmax) is encountered. In addition, a number of coal samples showed suppressed vitrinite reflectances ranging between 0.82 to 0.88% Rr. Further, seemingly heat unaffected coal samples display intensive development of oxidations rims at coal grain edges and cracks as well as shrinkage cracks and formation of iron oxides/hydroxides. Instead, thermally affected coal samples with higher coalification grade are further characterised by development of macropores (devolatilisation pores) in vitrinitic streaks, transformation of liptinite to meta-liptinite and micrinite as well as by natural coke particles of mostly porous nature and fine to coarse grained anisotropic mosaic. Coal petrographic investigations confirmed a hypothesis that both, oxidations as well as low temperature carbonisation govern the thermal

Advanced power assessment for Czech lignite. Task 3.6, Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sondreal, E.A.; Mann, M.D.; Weber, G.W.

1995-12-01

The US has invested heavily in research, development, and demonstration of efficient and environmentally acceptable technologies for the use of coal. The US has the opportunity to use its leadership position to market a range of advanced coal-based technologies internationally. For example, coal mining output in the Czech Republic has been decreasing. This decrease in demand can be attributed mainly to the changing structure of the Czech economy and to environmental constraints. The continued production of energy from indigenous brown coals is a major concern for the Czech Republic. The strong desire to continue to use this resource is amore » challenge. The Energy and Environmental Research Center undertook two major efforts recently. One effort involved an assessment of opportunities for commercialization of US coal technologies in the Czech Republic. This report is the result of that effort. The technology assessment focused on the utilization of Czech brown coals. These coals are high in ash and sulfur, and the information presented in this report focuses on the utilization of these brown coals in an economically and environmentally friendly manner. Sections 3--5 present options for utilizing the as-mined coal, while Sections 6 and 7 present options for upgrading and generating alternative uses for the lignite. Contents include Czech Republic national energy perspectives; powering; emissions control; advanced power generation systems; assessment of lignite-upgrading technologies; and alternative markets for lignite.« less

High pressure rotary piston coal feeder for coal gasification applications

DOEpatents

Gencsoy, Hasan T.

1977-05-24

The subject development is directed to an apparatus for feeding pulverized coal into a coal gasifier operating at relatively high pressures and elevated temperatures. This apparatus is a rotary piston feeder which comprises a circular casing having a coal loading opening therein diametrically opposed from a coal discharge and contains a rotatable discoid rotor having a cylinder in which a reciprocateable piston is disposed. The reciprocation of the piston within the cylinder is provided by a stationary conjugate cam arrangement whereby the pulverized coal from a coal hopper at atmospheric pressure can be introduced into the cylinder cavity and then discharged therefrom into the high-pressure gasifier without the loss of high pressure gases from within the latter.

Integration of advanced preparation with coal liquefaction. Second quarterly technical progress report, January 1-March 31, 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steedman, W.G.; Longanbach, J.R.; Muralidhara, H.S.

Standard reaction conditions of 427 C, 5 minutes reaction time, 2:1 solvent/coal ratio and 1000 psig (r.t.) hydrogen overpressure result in good, but not maximum, conversions to THF soluble with both Illinois No. 6 and Wyodak (upper seam) coals. The cumulative effects of the pretreatment steps were also examined using feedstocks which were dried in a vacuum oven at room temperature under nitrogen before liquefaction to remove the effects of moisture. Chloride removal followed by drying had a positive effect on liquefaction. Oil agglomeration followed by drying also improved liquefaction reactivity significantly. Solvent drying also resulted in a small increasemore » in liquefaction reactivity. The overall reactivity of coal treated in sequence with each pretreatment step was slightly less than that of the dry ground coal. Liquefaction under a high partial pressure of hydrogen sulfide in hydrogen also results in a significant increase in conversion to THF solubles. 1 reference, 12 figures, 7 tables.« less

Coal without carbon: an investment plan for federal action

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pettus, A.; Tatsutani, M.

2009-09-15

This study examines several technologies for CCS that are not currently receiving adequate development support but that could - in the right policy environment - provide the kind of significant cost reductions (and significant improvements in efficiency) that could greatly accelerate broad, economically attractive CCS deployment. Clean Air Task Force selected these technology areas (though not the technologies themselves) and solicited reports from experts in each field to explore how these technologies might fit into a broader CCS deployment strategy. Each expert was asked to develop a research, development, and demonstration (RD&D) 'road map' that could efficiently move each technologymore » from the laboratory into the commercial mainstream. Because the chapter authors are either technical experts or commercial players and are not, for the most part, energy policy experts, subsequent work will translate their RD&D recommendations into actionable policy proposals. The heart of this report consists of four chapters on advanced coal and CCS technologies: underground coal gasification (UCG), written by Julio Friedmann at Lawrence Livermore National Laboratory; Next generation coal gasification (surface-based gasification) led by Eric Redman at Summit Power Group; Advanced technologies for post-combustion capture (PCC) of CO{sub 2}, led by Howard Herzog at Massachusetts Institute of Technology; and RD&D to speed commercialization of geological CO{sub 2} sequestration (GCS), led by Julio Friedmann. 12 refs., 5 figs., 2 tabs.« less

Electricity from Coal Combustion: Improving the hydrophobicity of oxidized coals

NASA Astrophysics Data System (ADS)

Seehra, Mohindar; Singh, Vivek

2011-03-01

To reduce pollution and improve efficiency, undesirable mineral impurities in coals are usually removed in coal preparation plants prior to combustion first by crushing and grinding coals followed by gravity separation using surfactant aided water flotation. However certain coals in the US are not amendable to this process because of their poor flotation characteristics resulting in a major loss of an energy resource. This problem has been linked to surface oxidation of mined coals which make these coals hydrophilic. In this project, we are investigating the surface and water flotation properties of the eight Argonne Premium (AP) coals using x-ray diffraction, IR spectroscopy and zeta potential measurements. The role of the surface functional groups, (phenolic -OH and carboxylic -COOH), produced as a result of chemisorptions of O2 on coals in determining their flotation behavior is being explored. The isoelectric point (IEP) in zeta potential measurements of good vs. poor floaters is being examined in order to improved the hydrophobicity of poor floating coals (e.g. Illinois #6). Results from XRD and IR will be presented along with recent findings from zeta potential measurements, and use of additives to improve hydrophobicity. Supported by USDOE/CAST, Contract #DE-FC26-05NT42457.

Coal desulfurization process

NASA Technical Reports Server (NTRS)

Hsu, G. C.; Gavalas, G. R.; Ganguli, P. S.; Kalfayan, S. H.

1978-01-01

A method for chlorinolysis of coal is an organic solvent at a moderate temperautre and atmospheric pressure has been proven to be effective in removing sulfur, particularly the organic sulfur, from coal. Chlorine gas is bubbled through a slurry of moist coal in chlorinated solvent. The chlorinated coal is separated, hydrolyzed and the dechlorinated. Preliminary results of treating a high sulfutr (4.77%S) bituminous coal show that up to 70% organic sulfur, 90% hyritic sulfur and 76% total sulfur can be removed. The treated coal is dechlorinated by heating at 500 C. The presence of moisture helps to remove organic sulfur.

Apparatus and method for feeding coal into a coal gasifier

DOEpatents

Bissett, Larry A.; Friggens, Gary R.; McGee, James P.

1979-01-01

This invention is directed to a system for feeding coal into a gasifier operating at high pressures. A coal-water slurry is pumped to the desired pressure and then the coal is "dried" prior to feeding the coal into the gasifier by contacting the slurry with superheated steam in an entrained bed dryer for vaporizing the water in the slurry.

Characteristic Study of Shenmu Bituminous Coal Combustion with Online TG-MS-FTIR

NASA Astrophysics Data System (ADS)

Pan, Guanfu

2018-01-01

The combustion characteristics of Shenmu bituminous pulverized coal (SBC) were comprehensively investigated with a combined TG-MS-FTIR system by considering the effect of particle size, heating rate and total flowrate. The combustion products were accurately quantified by normalization and numerical analysis of MS results. The results indicate that the decrease of the particle size, heating rate and total flowrate result in lower ignition and burnout temperatures. The activation energy tends to be lower with smaller particle size, lower heating rate and total flowrate. The MS and FTIR results demonstrate that lower concentrations of different products, such as NO, NO2, HCN, CH4 and SO2 were produced with smaller particle size, slower heating rate and lower total flowrate. The decrease of particle size would lead to more contact area with oxygen and slower heating rate could provide more sufficient time for the diffusion. High total flowrate would reduce the oxygen adsorbability on the coal particle surface and shorten the residence time of oxygen, which makes the ignition difficult to occur. This work will guide to understand the combustion kinetics of pulverized coals and be beneficial to control the formation of pollutants.

15. VIEW OF COAL TRESTLE LOOKING NORTHEAST. COAL DUMPED FROM ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. VIEW OF COAL TRESTLE LOOKING NORTHEAST. COAL DUMPED FROM HOPPER CARS COULD BE CRUSHED AND LOADED ON A CONVEYOR THAT PARALLELED THE TRACK TO THE EAST (LEFT) AND CARRIED IT TO A 1000 TON BUNKER LOCATED ON THE NORTH SIDE OF THE EAST BOILER ROOM. COAL COULD ALSO GO THROUGH THE CRUSHER AND BE DIVERTED TO THE CONVEYOR SHOWN IN THE LEFT FOREGROUND. COAL PILES FORMED UNDER THE CONVEYOR WOULD BE MOVED AND SHAPED BY BULLDOZER. A GROUND LEVEL HOPPER WAS LOCATED TO THE RIGHT OF THE SLOPING HOUSING WHICH EXTENDS FROM THE SOUTH SIDE OF THE COAL TRESTLE. THIS HOPPER FED A CONVEYOR LOCATED WITHIN THE SLOPING HOUSING. COAL DROPPED INTO THE HOPPER WOULD BE CONVEYED INTO THE CRUSHER UNDER THE TRESTLE AND THEN DIVERTED TO THE CONVEYOR WHICH LOADED THE 1000 TON BUNKER. THE COAL HANDLING SYSTEM WAS DESIGNED BY GIBBS AND HILL IN 1947. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

National Coal Utilization Assessment. a preliminary assessment of the health and environmental effects of coal utilization in the Midwest. Volume I. Energy scenarios, technology characterizations, air and water resource impacts, and health effects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1977-01-01

This report presents an initial evaluation of the major health and environmental issues associated with increased coal use in the six midwestern states of Illinois, Indiana, Michigan, Minnesota, Ohio, and Wisconsin. Using an integrated assessment approach, the evaluation proceeds from a base-line scenario of energy demand and facility siting for 1975-2020. Emphasis is placed on impacts from coal extraction, land reclamation, coal combustion for electrical generation, and coal gasification. The range of potential impacts and constraints is illustrated by a second scenario that represents an expected upper limit for coal utilization in Illinois. The following are among the more significantmore » issues identified and evaluated in this study: If environmental and related issues can be resolved, coal will continue to be a major source of energy for the Midwest; existing sulfur emission constraints will increase use of western coal; the resource requirements and environmental impacts of coal utilization will require major significant environmental and economic tradeoffs in site selection; short-term (24-hr) ambient standards for sulfur dioxide will limit the sizes of coal facilities or require advanced control technologies; an impact on public health may result from long-range transport of airborne sulfur emissions from coal facilities in the Midwest; inadequately controlled effluents from coal gasification may cause violations of water-quality standards; the major ecological effects of coal extraction are from pre-mining and post-reclamation land use; and sulfur dioxide is the major potential contributor to effects on vegetation of atmospheric emissions from coal facilities.« less

Coal feed lock

DOEpatents

Pinkel, I. Irving

1978-01-01

A coal feed lock is provided for dispensing coal to a high pressure gas producer with nominal loss of high pressure gas. The coal feed lock comprises a rotor member with a diametral bore therethrough. A hydraulically activated piston is slidably mounted in the bore. With the feed lock in a charging position, coal is delivered to the bore and then the rotor member is rotated to a discharging position so as to communicate with the gas producer. The piston pushes the coal into the gas producer. The rotor member is then rotated to the charging position to receive the next load of coal.

Mercury emission trend influenced by stringent air pollutants regulation for coal-fired power plants in Korea

NASA Astrophysics Data System (ADS)

Pudasainee, Deepak; Kim, Jeong-Hun; Seo, Yong-Chil

2009-12-01

Regulatory control of mercury emission from anthropogenic sources has become a global concern in the recent past. Coal-fired power plants are one of the largest sources of anthropogenic mercury emission into the atmosphere. This paper summarizes the current reducing trend of mercury emission as co-beneficial effect by more stringent regulation changes to control primary air pollutants with introducing test results from the commercial coal-fired facilities and suggesting a guideline for future regulatory development in Korea. On average, mercury emission concentrations ranged 16.3-2.7 μg Sm -3, 2.4-1.1 μg Sm -3, 3.1-0.7 μg Sm -3 from anthracite coal-fired power plants equipped with electrostatic precipitator (ESP), bituminous coal-fired power plants with ESP + flue gas desulphurization (FGD) and bituminous coal-fired power plants with selective catalytic reactor (SCR) + cold side (CS) - ESP + wet FGD, respectively. Among the existing air pollution control devices, the best configuration for mercury removal in coal-fired power plants was SCR + CS - ESP + wet FGD, which were installed due to the stringent regulation changes to control primary air pollutants emission such as SO 2, NOx and dust. It was estimated that uncontrolled and controlled mercury emission from coal-fired power plants as 10.3 ton yr -1 and 3.2 ton yr -1 respectively. After the installation of ESP, FGD and SCR system, following the enforcement of the stringent regulation, 7.1 ton yr -1 of mercury emission has been reduced (nearly 69%) from coal-fired power plants as a co-benefit control. Based on the overall study, a sample guideline including emission limits were suggested which will be applied to develop a countermeasure for controlling mercury emission from coal-fired power plants.

Technical and Energy Performance of an Advanced, Aqueous Ammonia-Based CO2 Capture Technology for a 500 MW Coal-Fired Power Station.

PubMed

Li, Kangkang; Yu, Hai; Feron, Paul; Tade, Moses; Wardhaugh, Leigh

2015-08-18

Using a rate-based model, we assessed the technical feasibility and energy performance of an advanced aqueous-ammonia-based postcombustion capture process integrated with a coal-fired power station. The capture process consists of three identical process trains in parallel, each containing a CO2 capture unit, an NH3 recycling unit, a water separation unit, and a CO2 compressor. A sensitivity study of important parameters, such as NH3 concentration, lean CO2 loading, and stripper pressure, was performed to minimize the energy consumption involved in the CO2 capture process. Process modifications of the rich-split process and the interheating process were investigated to further reduce the solvent regeneration energy. The integrated capture system was then evaluated in terms of the mass balance and the energy consumption of each unit. The results show that our advanced ammonia process is technically feasible and energy-competitive, with a low net power-plant efficiency penalty of 7.7%.

New method of feeding coal - Continuous extrusion of fully plastic coal

NASA Technical Reports Server (NTRS)

Ryason, P. R.; England, C.

1978-01-01

Continuous feeding of coal in a compressing screw extruder is described as a method of introducing coal into pressurized systems. The method utilizes the property of many bituminous coals of softening at temperatures from 350 to 400 C. Coal is then fed much in the manner of common thermoplastics, using screw extruders. Preliminary results show that coals can be extruded at rates of about 3.3 kg/MJ, similar to those for plastics.

Cost-Effectiveness of Coal Workers' Pneumoconiosis Prevention Based on Its Predicted Incidence within the Datong Coal Mine Group in China

PubMed Central

Yuan, Juxiang; Han, Bing; Cui, Kai; Ding, Yu; Fan, Xueyun; Cao, Hong; Yao, Sanqiao; Suo, Xia; Sun, Zhiqian; Yun, Xiang; Hua, Zhengbing; Chen, Jie

2015-01-01

We aimed to estimate the economic losses currently caused by coal workers’ pneumoconiosis (CWP) and, on the basis of these measurements, confirm the economic benefit of preventive measures. Our cohort study included 1,847 patients with CWP and 43,742 coal workers without CWP who were registered in the employment records of the Datong Coal Mine Group. We calculated the cumulative incidence rate of pneumoconiosis using the life-table method. We used the dose-response relationship between cumulative incidence density and cumulative dust exposure to predict the future trend in the incidence of CWP. We calculate the economic loss caused by CWP and economic effectiveness of CWP prevention by a step-wise model. The cumulative incidence rates of CWP in the tunneling, mining, combining, and helping cohorts were 58.7%, 28.1%, 21.7%, and 4.0%, respectively. The cumulative incidence rates increased gradually with increasing cumulative dust exposure (CDE). We predicted 4,300 new CWP cases, assuming the dust concentrations remained at the levels of 2011. If advanced dustproof equipment was adopted, 537 fewer people would be diagnosed with CWP. In all, losses of 1.207 billion Renminbi (RMB, official currency of China) would be prevented and 4,698.8 healthy life years would be gained. Investments in advanced dustproof equipment would be total 843 million RMB, according to our study; the ratio of investment to restored economic losses was 1:1.43. Controlling workplace dust concentrations is critical to reduce the onset of pneumoconiosis and to achieve economic benefits. PMID:26098706

Effects of coal mine subsidence in the Sheridan, Wyoming, area

USGS Publications Warehouse

Dunrud, C. Richard; Osterwald, Frank W.

1980-01-01

Analyses of the surface effects of past underground coal mining in the Sheridan, Wyoming, area suggest that underground mining of strippable coal deposits may damage the environment more over long periods of time than would modern surface mining, provided proper restoration procedures are followed after surface mining. Subsidence depressions and pits are a continuing hazard to the environment and to man's activities in the Sheridan, Wyo., area above abandoned underground mines in weak overburden less than about 60 m thick and where the overburden is less than about 10-15 times the thickness of coal mined. In addition, fires commonly start by spontaneous ignition when water and air enter the abandoned mine workings via subsidence cracks and pits. The fires can then spread to unmined coal as they create more cavities, more subsidence, and more cracks and pits through which air can circulate. In modern surface mining operations the total land surface underlain by minable coal is removed to expose the coal. The coal is removed, the overburden and topsoil are replaced, and the land is regraded and revegetated. The land, although disturbed, can be more easily restored and put back into use than can land underlain by abandoned underground mine workings in areas where the overburden is less than about 60 m thick or less than about 10-15 times the thickness of coal mined. The resource recovery of modern surface mining commonly is much greater than that of underground mining procedures. Although present-day underground mining technology is advanced as compared to that of 25-80 years ago, subsidence resulting from underground mining of thick coal beds beneath overburden less than about 60 m thick can still cause greater damage to surface drainage, ground water, and vegetation than can properly designed surface mining operations. This report discusses (11 the geology and surface and underground effects of former large-scale underground coal mining in a 50-km 2 area 5-20 km

Looking southeast at coal conveyor leading from the coal unloading ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Looking southeast at coal conveyor leading from the coal unloading station to the coal elevator. - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

Fundamental modeling of pulverized coal and coal-water slurry combustion in a gas turbine combustor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chatwani, A.; Turan, A.; Hals, F.

1988-01-01

This work describes the essential features of a coal combustion model which is incorporated into a three-dimensional, steady-state, two-phase, turbulent, reactive flow code. The code is a modified and advanced version of INTERN code originally developed at Imperial College which has gone through many stages of development and validation. Swithenbank et al have reported spray combustion model results for an experimental can combustor. The code has since then been modified by and made public under a US Army program. A number of code modifications and improvements have been made at ARL. The earlier version of code was written for amore » small CDC machine which relied on frequent disk/memory transfer and overlay features to carry the computations resulting in loss of computational speed. These limitations have now been removed. For spray applications, the fuel droplet vaporization generates gaseous fuel of uniform composition; hence the earlier formulation relied upon the use of conserved scalar approximation to reduce the number of species equations to be solved. In applications related to coal fuel, coal pyrolysis leads to the formation of at least two different gaseous fuels and a solid fuel of different composition. The authors have therefore removed the conserved scalar formulation for the sake of generality and easy adaptability to complex fuel situations.« less

Bench-scale performance testing and economic analyses of electrostatic dry coal cleaning. Final report, October 1980-July 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rich, S.R.

1987-02-01

The report gives results of preliminary performance evaluations and economic analyses of the Advanced Energy Dynamics (AED) electrostatic dry coal-cleaning process. Grab samples of coal-feed-product coals were obtained from 25 operating physical coal-cleaning (PCC) plants. These samples were analyzed for ash, sulfur, and energy content and splits of the original samples of feed run-of-mine coal were provided for bench-scale testing in an electrostatic separation apparatus. The process showed superior sulfur-removal performance at equivalent cost and energy-recovery levels. The ash-removal capability of the process was not evaluated completely: overall, ash-removal results indicated that the process did not perform as well asmore » the PCC plants.« less

Annual Coal Distribution

EIA Publications

2016-01-01

The Annual Coal Distribution Report (ACDR) provides detailed information on domestic coal distribution by origin state, destination state, consumer category, and method of transportation. Also provided is a summary of foreign coal distribution by coal-producing state. All data for the report year are final and this report supersedes all data in the quarterly distribution reports.

Organic matter in a coal ball: Peat or coal?

USGS Publications Warehouse

Hatcher, P.G.; Lyons, P.C.; Thompson, C.L.; Brown, F.W.; Maciel, G.E.

1982-01-01

Chemical analyses of morphologically preserved organic matter in a Carboniferous coal ball reveal that the material is coalified to a rank approximately equal to that of the surrounding coal. Hence, the plant tissues in the coal ball were chemically altered by coalification processes and were not preserved as peat. Copyright ?? 1982 AAAS.

Rate of coal hydroliquefaction: correlation to coal structure. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baldwin, R.M.; Voorhees, K.J.; Durfee, S.L.

This report summarizes the research carried out on DOE grant No. FG22-83PC60784. The work was divided into two phases. The first phase consisted of a series of coal liquefaction rate measurements on seven different coals from the Exxon sample bank, followed by correlation with parent coal properties. The second phase involved characterization of the coals by pyrolysis/mass spectrometry and subsequent correlations of the Py/MS patterns with various liquefaction reactivity parameters. The hydroliquefaction reactivities for a suite of 7 bituminous and subbituminous coals were determined on a kinetic basis. These reactivities were correlated fairly successfully with the following parent coal properties:more » volatile matter, H/C and O/C ratios, vitrinite reflectance, and calorific value. The total surface areas of the coals were experimentally determined. Reactivity was shown to be independent of surface area. Following completion of the batch reactor experiments, the seven coals investigated were analyzed by pyrolysis/mass spectrometry. The pyrolysis spectra were then submitted to factor analysis in order to extract significant features of the coal for use in correlational efforts. These factors were then related to a variety of liquefaction reactivity definitions, including both rate and extent of liquefaction to solvent solubility classifications (oils, asphaltenes, preasphaltenes, etc.). In general, extent of reaction was found to correlate best with the Py/MS data. 37 refs., 25 figs., 11 tabs.« less

39. BOILER HOUSE, COAL CONVEYOR LEADING FROM COAL TOWER No. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

39. BOILER HOUSE, COAL CONVEYOR LEADING FROM COAL TOWER No. 1 (WEST) (NOTE: COAL CARS No. 9 & 5 IN BACKGROUND) - Delaware County Electric Company, Chester Station, Delaware River at South end of Ward Street, Chester, Delaware County, PA

35. BOILER HOUSE, TRACK FOR COAL CARS LEADING TO COAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

35. BOILER HOUSE, TRACK FOR COAL CARS LEADING TO COAL TOWER No. 2 (NOTE: SKYLIGHT ABOVE; COAL CARS IN FAR BACKGROUND) - Delaware County Electric Company, Chester Station, Delaware River at South end of Ward Street, Chester, Delaware County, PA

34. BOILER HOUSE, COAL CONVEYOR AND TURNAROUND TRACK FOR COAL ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

34. BOILER HOUSE, COAL CONVEYOR AND TURN-AROUND TRACK FOR COAL CARS (NOTE: COAL CAR No. 6 IN FAR BACK GROUND) - Delaware County Electric Company, Chester Station, Delaware River at South end of Ward Street, Chester, Delaware County, PA

Coals of Hungary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Landis, E.R.; Rohrbacher, T.J.; Gluskoter, H.

1999-07-01

As part of the activities conducted under the U.S. Hungarian Science and Technology Fund, a total of 39 samples from five coal mines in Hungary were selected for standard coal analyses and major, minor and trace elements analysis. The mine areas sampled were selected to provide a spectrum of coal quality information for comparison with other coal areas in central Europe and worldwide. All of the areas are of major importance in the energy budget of Hungary. The five sample sites contain coal in rocks of Jurassic, Cretaceous, Eocene, Miocene, and Pliocene age. The coals, from four underground and onemore » surface mine, range in rank from high volatile bituminous to lignite B. Most of the coal produced from the mines sampled is used to generate electricity. Some of the power plants that utilize the coals also provide heat for domestic and process usage. The standard coal analysis program is based on tests performed in accordance with standards of the American Society for Testing and Materials (ASTM). Proximate and ultimate analyses were supplemented by determinations of the heating value, equilibrium moisture, forms of sulfur, free-swelling index, ash fusion temperatures (both reducing and oxidizing), apparent specific gravity and Hardgrove Grindability index. The major, minor and trace element analyses were performed in accordance with standardized procedures of the U.S. Geological Survey. The analytical results will be available in the International Coal Quality Data Base of the USGS. The results of the program provide data for comparison with test data from Europe and information of value to potential investors or cooperators in the coal industry of Hungary and Central Europe.« less

A life-cycle description of underground coal mining

NASA Technical Reports Server (NTRS)

Lavin, M. L.; Borden, C. S.; Duda, J. R.

1978-01-01

An initial effort to relate the major technological and economic variables which impact conventional underground coal mining systems, in order to help identify promising areas for advanced mining technology is described. The point of departure is a series of investment analyses published by the United States Bureau of Mines, which provide both the analytical framework and guidance on a choice of variables.

Electrical Resistivity Tomography for coal fire mapping over Jharia coal field, India

NASA Astrophysics Data System (ADS)

Pal, S. K.; Kumar, S.; Bharti, A. K.; Pathak, V. K.; Kumar, R.

2016-12-01

Over the decades, coal fires are serious global concern posing grievous hazards to the valuable energy resources, local environments and human life. The coal seam and coal mine fires may be initiated due to improper mining activities, exothermic reactions, lighting, forest fire and other anthropic activities, which burn the coal and may continue underground for decades. The burning of concealed coal seams is a complex process involving numerous ill-defined parameters. Generally, the coal exhibits resistivity of 100 to 500Ωm at normal temperature conditions. During the pyrolysis process, at temperatures greater than 6500C coal became a good conductor with a resistivity of approximately 1 Ωm. The present study deals with the mapping of coal fire over Jharia coal field, India using Electrical Resistivity Tomography (ERT). A state-of-the-art 61-channel 64 electrode FlashRES-Universal ERT data acquisition system has been used for data acquisition in the field. The ERT data have been collected using Gradient array and processed in FlashRES Universal survey data checking program for removing noisy data. Then, filtered output data have been inverted using a 2.5D resistivity inversion program. Low resistivity anomalies over 80m-125m and 320m-390m along the profile are inferred to be active coal fire in seam- XVI at a depth of 25m -35m(Figure 1). High resistivity anomaly over 445m - 510m at a depth of 25m -35m has been delineated, due to void associated with complete combustion of seam- XVI coal, followed by char and ash formation resulting from the coal seam fire. Results prove the efficacy of the ERT study comprising Gradient array for coal fire mapping over, Jharia coal field, India.

Deep-coal potential in the Appalachian Coal Basin, USA: The Kentucky model

USGS Publications Warehouse

Haney, D.C.; Chesnut, D.R.

1997-01-01

The Eastern Kentucky Coal Field is located in the Appalachian Basin of the United States and occupies an area of approximately 15,000 square kilometers. The coal beds range from a few centimeters to several meters in thickness and consist of high-grade bituminous coal. Currently the amount of coal mined by surface methods exceeds underground extraction; however, there is a steady and gradual shift toward underground mining. In the future, as near-surface resources are depleted, this trend toward increased underground mining will continue. Knowledge about deeper coals is essential for future economic development of resources. Preliminary investigations indicate that coal-bearing strata with deep-mining potential exist in several parts of eastern Kentucky, especially along the Eastern Kentucky Syncline. Eastern Kentucky coals are Westphalian A through D; however, current production is from major beds of Westphalian A and B. Because coals that occur above drainage are more easily accessible and are generally of better quality, most of the current mining takes place in formations that are at or near the surface. In the future, however, due to environmental regulations and increased demands, it will be necessary to attempt to utilize deeper coals about which little is known. Future development of deep resources will require data from boreholes and high-resolution geophysical-logging techniques. There is also potential for coal-bed methane from the deeper coals which could be an important resource in the Appalachian Coal Basin where a natural gas distribution system already exists.

Nitrogen in Chinese coals

USGS Publications Warehouse

Wu, D.; Lei, J.; Zheng, B.; Tang, X.; Wang, M.; Hu, Jiawen; Li, S.; Wang, B.; Finkelman, R.B.

2011-01-01

Three hundred and six coal samples were taken from main coal mines of twenty-six provinces, autonomous regions, and municipalities in China, according to the resource distribution and coal-forming periods as well as the coal ranks and coal yields. Nitrogen was determined by using the Kjeldahl method at U. S. Geological Survey (USGS), which exhibit a normal frequency distribution. The nitrogen contents of over 90% Chinese coal vary from 0.52% to 1.41% and the average nitrogen content is recommended to be 0.98%. Nitrogen in coal exists primarily in organic form. There is a slight positive relationship between nitrogen content and coal ranking. ?? 2011 Science Press, Institute of Geochemistry, CAS and Springer Berlin Heidelberg.

Microbial solubilization of coal

DOEpatents

Strandberg, G.W.; Lewis, S.N.

1988-01-21

The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

In-situ study of beneficial utilization of coal fly ash in reactive mine tailings.

PubMed

Lee, Joon Kyu; Shang, Julie Q; Wang, Hongliu; Zhao, Cheng

2014-03-15

Oxidation of reactive mine tailings and subsequent generation of acid mine drainage (AMD) have been long recognized as the largest environmental concern for the mining industry. Laboratory studies on utilization of coal fly ash in management of reactive mine tailings have shown reducing water and oxygen infiltration into tailings matrix, thus preventing oxidation of sulphide minerals and acid generation. However, few data from field studies to evaluate the performance of co-placement of mine tailings and fly ash (CMF hereafter) are reported in the open literature. This paper documents the construction and instrumentation of three CMF systems on the Musselwhite mine located in Ontario, Canada and presents results of 3-year real time monitoring. The field data indicates that the CMFs reduced the ingress of water due to cementation generated by hydration of fly ash. It was also found that the electrical conductivity of leachate from CMFs decreased in the early stage of co-placement, compared to the control. With further study, the principle and approach demonstrated in this paper can be adopted as a sustainable technology in the mine tailings management. Copyright © 2014 Elsevier Ltd. All rights reserved.

Brecciated and mineralized coals in Union County Western Kentucky coal field

USGS Publications Warehouse

Hower, J.C.; Williams, D.A.; Eble, C.F.; Sakulpitakphon, T.; Moecher, D.P.

2001-01-01

Coals from the D-2 and D-3 boreholes in the Grove Center 7 1/2 min quadrangle, Union County, KY, have been found to be highly brecciated and mineralized. The mineralization is dominated by a carbonate assemblage with minor sulfides and sulfates. Included among the secondary minerals is the lead selenide, clausthalite. Overall, the emplacement of secondary vein minerals was responsible for raising the rank of the coals from the 0.6-0.7% Rmax range found in the area to as high as 0.95-0.99% Rmax. A 1.3-m-thick coal found in one of the boreholes is unique among known Western Kentucky coals in having less than 50% vitrinite. Semifusinite and fusinite dominate the maceral assemblages. The coal is also low in sulfur coal, which is unusual for the Illinois Basin. It has an ash yield of less than 10%; much of it dominated by pervasive carbonate veining. The age of the thick coal in core D-2 is similar to that of the Elm Lick coal bed, found elsewhere in the Western Kentucky coalfield. The coals in D-3 are younger, having Stephanian palynomorph assemblages. ?? 2001 Elsevier Science B.V. All rights reserved.

Coal desulfurization

NASA Technical Reports Server (NTRS)

Corcoran, William H. (Inventor); Vasilakos, Nicholas P. (Inventor); Lawson, Daniel D. (Inventor)

1982-01-01

A method for enhancing solubilizing mass transport of reactive agents into and out of carbonaceous materials, such as coal. Solubility parameters of mass transfer and solvent media are matched to individual peaks in the solubility parameter spectrum of coals to enhance swelling and/or dissolution. Methanol containing reactive agent carriers are found particularly effective for removing organic sulfur from coals by chlorinolysis.

Examination of lung toxicity, oxidant/antioxidant status and effect of erdosteine in rats kept in coal mine ambience.

PubMed

Armutcu, Ferah; Gun, Banu Dogan; Altin, Remzi; Gurel, Ahmet

2007-09-01

Occupational exposure to coal dust causes pneumoconiosis and other diseases. Reactive oxygen species (ROS) have been implicated in the pathogenesis of coal dust-induced lung toxicity. In this experimental study, we investigated the oxidant/antioxidant status, nitric oxide (NO) and hydroxyproline (HP) levels in lungs and blood of rats exposed to coal dust in mine ambience. In addition, we also investigated the attenuating effects of erdosteine. At the end of the experiment processes, tissue levels of HP, malondialdehyde (MDA) and NO, as well as the activities of superoxide dismutase, glutathione peroxidase, catalase, xanthine oxidase (XO), myeloperoxidase (MPO) and proinflammatory cytokines (IL-6 and TNF-α) were evaluated in the lung tissues, plasma samples or erythrocytes of rats. Exposure to coal dust resulted in a significant increase in the oxidant parameters (MDA, NO levels, and XO activity) and HP levels, as compared to the controls. A decrease in activities of antioxidant enzymes, and an increase in MPO activity were found in the study group, compared to the controls. Increased NO levels of lung were found in the study groups, that were significantly reduced by erdosteine. Our studies provide evidence that supports the hypothesis for ROS mediated coal workers' pneumoconiosis. Erdosteine may be beneficial in the coal dust-induced lung toxicity via antioxidant and free radical scavenger properties. Copyright © 2007 Elsevier B.V. All rights reserved.

Beneficiation and agglomeration of manganese ore fines (an area so important and yet so ignored)

NASA Astrophysics Data System (ADS)

Sane, R.

2018-01-01

Unpredictable changes in demand and prices varying from very attractive to depressing levels have thrown all Manganese ore mines out of normal operating gear. The supply has to be in time-bound fashion, of dependable quality and continuous. With setting-up of numerous small units and with existing ferro-alloy units, ore supply has become extremely sensitive issue. Due to unpredictable swing in price of Mn ore lumps, furnace operators found it economic and convenient to use fines, even at great risks to furnace equipment and operating persons and therefore risks & damages were conveniently & comfortably ignored. Beneficiation Cost(Operating) approx. - (ferruginous ore) - Roast reduction followed by magnetic separation route-particulars - Water 20/-, Power 490/-, Coal fines-675/-, OH-250/-totaling to Rs.1435/T. (Figures are based on actual data from investigations on Orissa & Karnataka sector ores). Feed Grade Mn- 28 to 32 %, Fe - 14 to 25 %, Concentrate (Beneficiated ore fines)- - Mn- 45 to 48 %, Fe - 6 to 8 %., Recovery - 35 %, Price of 28-30 % Mn ore fines = Rs. 2400/T, Cost of Concentrated fines (45/48% Mn grade) = Rs. 8300/T, Price of 47-48 % Mn Lumpy ore = Rs.11,000/T. Sintering Cost (Operating) - Approx-Rs.1195=00/T Sinter. Therefore cost of Sinter produced from beneficiated concentrate is 9130+1195 = Rs. 10325. The difference in cost of 48%Mn ore Lumps & 48%Mn sintered concentrate = 11000-10325 = Rs.675/T. The main purpose of this paper is to show that establishment of beneficiation unit & Sintering unit is economically feasible. There are many misconcepts, still prevailing, about use of Mn ore sinters. Few of the main misconcepts are- 1)Sinters bring no benefit - technical or economical.2) Sinters are very friable and disintegrate easily into high fines during handling/transportation. 3) Fines below 100 mesh cannot be sintered. 4) Silica increases to high level during sintering, resulting in to high slag volume thereby higher power consumption. All are false

The migration law of overlay rock and coal in deeply inclined coal seam with fully mechanized top coal caving.

PubMed

Liu, Jian; Chen, Shan-Le; Wang, Hua-Jun; Li, Yu-Cheng; Geng, Xiaowei

2015-07-01

In a mine area, some environment geotechnics problems always occure, induced by mined-out region such as the subsidence and cracks at ground level, deformation and destruction of buildings, landslides destruction of water resources and the ecological environment. In order to research the migration of surrounding rock and coal in steeply inclined super high seams which used fully mechanized top coal caving, a working face of a certain mine was made as an example, analyzed the migration law of the overlay rock and coal under different caving ratio of fully mechanized top coal caving with numerical simulation analysis. The results suggest that the laws of overlay rock deformation caused by deeply inclined coal seam were different from horizontal coal seam. On the inclined direction, with an increase of dip angle and caving ratio, the vertical displacement of overlay rock and coal became greater, the asymmetric phenomenon of vertical displacement became obvious. On the trend direction, active region and transition region in goaf became smaller along with the increase of mining and caving ratio. On the contrary, the stable region area became greater. Therefore, there was an essential difference between the mechanism of surface movement deformation with deeply inclined coal seam and that with horizontal coal seam.

Coal-Quality Information - Key to the Efficient and Environmentally Sound Use of Coal

USGS Publications Warehouse

Finkleman, Robert B.

1997-01-01

The rock that we refer to as coal is derived principally from decomposed organic matter (plants) consisting primarily of the element carbon. When coal is burned, it produces energy in the form of heat, which is used to power machines such as steam engines or to drive turbines that produce electricity. Almost 60 percent of the electricity produced in the United States is derived from coal combustion. Coal is an extraordinarily complex material. In addition to organic matter, coal contains water (up to 40 or more percent by weight for some lignitic coals), oils, gases (such as methane), waxes (used to make shoe polish), and perhaps most importantly, inorganic matter (fig. 1). The inorganic matter--minerals and trace elements--cause many of the health, environmental, and technological problems attributed to coal use (fig. 2). 'Coal quality' is the term used to refer to the properties and characteristics of coal that influence its behavior and use. Among the coal-quality characteristics that will be important for future coal use are the concentrations, distribution, and forms of the many elements contained in the coal that we intend to burn. Knowledge of these quality characteristics in U.S. coal deposits may allow us to use this essential energy resource more efficiently and effectively and with less undesirable environmental impact.

Coal resources, reserves and peak coal production in the United States

USGS Publications Warehouse

Milici, Robert C.; Flores, Romeo M.; Stricker, Gary D.

2013-01-01

In spite of its large endowment of coal resources, recent studies have indicated that United States coal production is destined to reach a maximum and begin an irreversible decline sometime during the middle of the current century. However, studies and assessments illustrating coal reserve data essential for making accurate forecasts of United States coal production have not been compiled on a national basis. As a result, there is a great deal of uncertainty in the accuracy of the production forecasts. A very large percentage of the coal mined in the United States comes from a few large-scale mines (mega-mines) in the Powder River Basin of Wyoming and Montana. Reported reserves at these mines do not account for future potential reserves or for future development of technology that may make coal classified currently as resources into reserves in the future. In order to maintain United States coal production at or near current levels for an extended period of time, existing mines will eventually have to increase their recoverable reserves and/or new large-scale mines will have to be opened elsewhere. Accordingly, in order to facilitate energy planning for the United States, this paper suggests that probabilistic assessments of the remaining coal reserves in the country would improve long range forecasts of coal production. As it is in United States coal assessment projects currently being conducted, a major priority of probabilistic assessments would be to identify the numbers and sizes of remaining large blocks of coal capable of supporting large-scale mining operations for extended periods of time and to conduct economic evaluations of those resources.

Comparison Analysis of Coal Biodesulfurization and Coal's Pyrite Bioleaching with Acidithiobacillus ferrooxidans

PubMed Central

Hong, Fen-Fen; He, Huan; Liu, Jin-Yan; Tao, Xiu-Xiang; Zheng, Lei; Zhao, Yi-Dong

2013-01-01

Acidithiobacillus ferrooxidans (A. ferrooxidans) was applied in coal biodesulfurization and coal's pyrite bioleaching. The result showed that A. ferrooxidans had significantly promoted the biodesulfurization of coal and bioleaching of coal's pyrite. After 16 days of processing, the total sulfur removal rate of coal was 50.6%, and among them the removal of pyritic sulfur was up to 69.9%. On the contrary, after 12 days of processing, the coal's pyrite bioleaching rate was 72.0%. SEM micrographs showed that the major pyrite forms in coal were massive and veinlets. It seems that the bacteria took priority to remove the massive pyrite. The sulfur relative contents analysis from XANES showed that the elemental sulfur (28.32%) and jarosite (18.99%) were accumulated in the biotreated residual coal. However, XRD and XANES spectra of residual pyrite indicated that the sulfur components were mainly composed of pyrite (49.34%) and elemental sulfur (50.72%) but no other sulfur contents were detected. Based on the present results, we speculated that the pyrite forms in coal might affect sulfur biooxidation process. PMID:24288464

New projects for CCGTs with coal gasification (Review)

NASA Astrophysics Data System (ADS)

Olkhovskii, G. G.

2016-10-01

Perspectives of using coal in combined-cycle gas turbine units (CCGTs), which are significantly more efficient than steam power plants, have been associated with preliminary coal gasification for a long time. Due to gasification, purification, and burning the resulting synthesis gas at an increased pressure, there is a possibility to intensify the processes occurring in them and reduce the size and mass of equipment. Physical heat evolving from gasification can be used without problems in the steam circuit of a CCGT. The downside of these opportunities is that the unit becomes more complex and expensive, and its competitiveness is affected, which was not achieved for CCGT power plants with coal gasification built in the 1990s. In recent years, based on the experience with these CCGTs, several powerful CCGTs of the next generation, which used higher-output and cost-effective gas-turbine plants (GTPs) and more advanced systems of gasification and purification of synthesis gas, were either built or designed. In a number of cases, the system of gasification includes devices of CO vapor reforming and removal of the emitted CO2 at a high pressure prior to fuel combustion. Gasifiers with air injection instead of oxygen injection, which is common in coal chemistry, also find application. In this case, the specific cost of the power station considerably decreases (by 15% and more). In units with air injection, up to 40% air required for separation is drawn from the intermediate stage of the cycle compressor. The range of gasified coals has broadened. In order to gasify lignites in one of the projects, a transfer reactor was used. The specific cost of a CCGT with coal gasification rose in comparison with the period when such units started being designed, from 3000 up to 5500 dollars/kW.

Similar simulation study on the characteristics of the electric potential response to coal mining

NASA Astrophysics Data System (ADS)

Niu, Yue; Li, Zhonghui; Kong, Biao; Wang, Enyuan; Lou, Quan; Qiu, Liming; Kong, Xiangguo; Wang, Jiali; Dong, Mingfu; Li, Baolin

2018-02-01

An electric potential (EP) can be generated during the failure process of coal and rock. In this article, a similar physical model of coal rock was built and the characteristics of the EP responding to the process of coal mining were studied. The results showed that, at the early mining stage, the structure of coal rock strata were stable in the simulation model, the support stress of overlying coal rock strata was low and the maximum subsidence was little, while the EP change was less. With the advancement of the working face, the support stress of the overlying coal rock strata in the mined-out area changed dramatically, the maximum subsidence increased constantly, the deformation and destruction were aggravated, and cracks expanded continuously. Meanwhile, the EP response was significant with fluctuation. When significant macro damage appeared in coal rock strata, the EP signal fluctuation was violent. The overlying coal rock strata were influenced by gravity and mining activity. During the mining process, the crack growth and the friction, together with slip between coal and rock particles, resulted in the response of EP. The change in EP was closely related to the damage state and stress distribution of the coal rock strata. EP monitoring has the advantages of accurate reflection and strong anti-interference in the field. Therefore, with further study, an EP monitoring method could be applied for monitoring and early warning of coal and rock dynamic disaster, and risk evaluation in the future. The strength of the EP and its fluctuation degree could serve as the key discrimination indexes.

Coal and Coal/Biomass-Based Power Generation

EPA Science Inventory

For Frank Princiotta's book, Global Climate Change--The Technology Challenge Coal is a key, growing component in power generation globally. It generates 50% of U.S. electricity, and criteria emissions from coal-based power generation are being reduced. However, CO2 emissions m...

Process for changing caking coals to noncaking coals

DOEpatents

Beeson, Justin L.

1980-01-01

Caking coals are treated in a slurry including alkaline earth metal hydroxides at moderate pressures and temperatures in air to form noncaking carbonaceous material. Hydroxides such as calcium hydroxide, magnesium hydroxide or barium hydroxide are contemplated for slurrying with the coal to interact with the agglomerating constituents. The slurry is subsequently dewatered and dried in air at atmospheric pressure to produce a nonagglomerating carbonaceous material that can be conveniently handled in various coal conversion and combustion processes.

Quality of economically extractable coal beds in the Gillette coal field as compared with other Tertiary coal beds in the Powder River basin, Wyoming and Montana

USGS Publications Warehouse

Ellis, Margaret S.

2002-01-01

The Powder River Basin, and specifically the Gillette coal field, contains large quantities of economically extractable coal resources. These coal resources have low total sulfur content and ash yield, and most of the resources are subbituminous in rank. A recent U.S Geological Survey study of economically extractable coal in the Gillette coal field focused on five coal beds, the Wyodak rider, Upper Wyodak, Canyon, Lower Wyodak-Werner, and Gates/Kennedy. This report compares the coal quality of these economically extractable coal beds to coal in the Wyodak-Anderson coal zone in the Powder River Basin and in the Gillette coal field (Flores and others, 1999) and other produced coal in the Gillette coal field (Glass, 2000). The Upper Wyodak, Canyon, and Lower Wyodak/Werner beds are within the Wyodak-Anderson coal zone. Compared with all coal in the Wyodak-Anderson coal zone, both throughout the Powder River Basin and just within the Gillette coal field; the thick, persistent Upper Wyodak coal bed in the Gillette coal field has higher mean gross calorific value (8,569 Btu/lb), lower mean ash yield (5.8 percent), and lower mean total sulfur content (0.46 percent).

Advanced Cogeneration Technology Economic Optimization Study (ACTEOS)

NASA Technical Reports Server (NTRS)

Nanda, P.; Ansu, Y.; Manuel, E. H., Jr.; Price, W. G., Jr.

1980-01-01

The advanced cogeneration technology economic optimization study (ACTEOS) was undertaken to extend the results of the cogeneration technology alternatives study (CTAS). Cost comparisons were made between designs involving advanced cogeneration technologies and designs involving either conventional cogeneration technologies or not involving cogeneration. For the specific equipment cost and fuel price assumptions made, it was found that: (1) coal based cogeneration systems offered appreciable cost savings over the no cogeneration case, while systems using coal derived liquids offered no costs savings; and (2) the advanced cogeneration systems provided somewhat larger cost savings than the conventional systems. Among the issues considered in the study included: (1) temporal variations in steam and electric demands; (2) requirements for reliability/standby capacity; (3) availability of discrete equipment sizes; (4) regional variations in fuel and electricity prices; (5) off design system performance; and (6) separate demand and energy charges for purchased electricity.

Experiment and mechanism investigation on advanced reburning for NOx reduction: influence of CO and temperature

PubMed Central

Wang, Zhi-hua; Zhou, Jun-hu; Zhang, Yan-wei; Lu, Zhi-min; Fan, Jian-ren; Cen, Ke-fa

2005-01-01

Pulverized coal reburning, ammonia injection and advanced reburning in a pilot scale drop tube furnace were investigated. Premix of petroleum gas, air and NH3 were burned in a porous gas burner to generate the needed flue gas. Four kinds of pulverized coal were fed as reburning fuel at constant rate of 1g/min. The coal reburning process parameters including 15%~25% reburn heat input, temperature range from 1100 °C to 1400 °C and also the carbon in fly ash, coal fineness, reburn zone stoichiometric ratio, etc. were investigated. On the condition of 25% reburn heat input, maximum of 47% NO reduction with Yanzhou coal was obtained by pure coal reburning. Optimal temperature for reburning is about 1300 °C and fuel-rich stoichiometric ratio is essential; coal fineness can slightly enhance the reburning ability. The temperature window for ammonia injection is about 700 °C~1100 °C. CO can improve the NH3 ability at lower temperature. During advanced reburning, 72.9% NO reduction was measured. To achieve more than 70% NO reduction, Selective Non-catalytic NOx Reduction (SNCR) should need NH3/NO stoichiometric ratio larger than 5, while advanced reburning only uses common dose of ammonia as in conventional SNCR technology. Mechanism study shows the oxidization of CO can improve the decomposition of H2O, which will rich the radical pools igniting the whole reactions at lower temperatures. PMID:15682503

Coal burning issues. [Book - monograph

DOE Office of Scientific and Technical Information (OSTI.GOV)

Green, A.E.S.

1980-01-01

The results of the scoping phase of an interdisciplinary assessment of the impact of the increased use of coal are reported in this monograph. Subject areas include: coal availability and coal mining; an energetics analysis of coal quality; coal transportation; coal burning technology; synthetic fuels from coal; technological innovations; water resources; atmospheric pollution; air pollution dispersion modeling; atmospheric modifications; solid waste and trace element impacts; agriculture; health effects of air pollution resulting from coal combustion; quantitative public policy assessments; financing capacity growth and coal conversions in the electric utility industry; coal and the states - a public choice perspective; andmore » federal regulatory and legal aspects.« less

Process for hydrogenating coal and coal solvents

DOEpatents

Tarrer, Arthur R.; Shridharani, Ketan G.

1983-01-01

A novel process is described for the hydrogenation of coal by the hydrogenation of a solvent for the coal in which the hydrogenation of the coal solvent is conducted in the presence of a solvent hydrogenation catalyst of increased activity, wherein the hydrogenation catalyst is produced by reacting ferric oxide with hydrogen sulfide at a temperature range of 260.degree. C. to 315.degree. C. in an inert atmosphere to produce an iron sulfide hydrogenation catalyst for the solvent. Optimally, the reaction temperature is 275.degree. C. Alternately, the reaction can be conducted in a hydrogen atmosphere at 350.degree. C.

Coal-fired power generaion, new air quality regulations, and future U.S. coal production

USGS Publications Warehouse

Attanasi, E.D.; Root, D.H.

1999-01-01

Tighter new regulation of stack gas emissions and competition in power generation are driving electrical utilities to demand cleaner, lower sulfur coal. Historical data on sulfur content of produced coals shows little variability in coal quality for individual mines and individual coal-producing counties over relatively long periods of time. If coal-using power generators follow the compliance patterns established in Phase I of the 1990 Clean Air Act Amendments, then the industry's response to the tighter Phase II emissions standards will result in large amounts of coal production shifting from higher sulfur areas to areas with lower cost low sulfur coal. One reason this shift will likely occur is that currently only 30% of U.S. coal-fired electrical generating capacity is equipped with flue-gas scrubbers. In 1995, coal mines in the higher sulfur areas of the Illinois Basin and Northern and Central Appalachia employed 78% of all coal miners (>70,000 miners). A substantial geographical redistribution of the nation's coal supplies will likely lead to economic dislocations that will reach beyond local coal-producing areas.

Applications of micellar enzymology to clean coal technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walsh, C.T.

1990-10-26

This project is designed to develop methods for pre-combustion coal remediation by implementing recent advances in enzyme biochemistry. The novel approach of this study is incorporation of hydrophilic oxidative enzymes in reverse micelles in an organic solvent. Enzymes from commercial sources or microbial extracts are being investigated for their capacity to remove organic sulfur from coal by oxidation of the sulfur groups, splitting of C-S bonds and loss of sulfur as sulfuric acid Dibenzothiophene (DBT) and ethlyphenylsulfide (EPS) are serving as models of organic sulfur-containing components of coal in initial studies. A goal of this project is to define amore » reverse micelle system that optimizes the catalytic activity of enzymes toward desulfurization of model compounds and ultimately coal samples. Among the variables which will be examined are the surfactant, the solvent, the water:surfactant ration and the pH and ionic strength of the aqueous phase. Studies were carried out with HRP, Type I RZ=1.2 and Type VI RZ=3.2 and laccase from Polyporus versicolor. Substrates for HRP assays included hydrogen peroxide, DBT, DBT sulfoxide, and DBT sulfone. Buffers included sodium phosphate. For formation of reverse micelle solutions the surfactant AOT, di(2-ethyl-hexyl)sodium sulphosuccinate, was obtained from Sigma Chemical Co. Isooctant was used as organic solvent. 12 refs., 5 figs., 3 tabs.« less

Hydrogeochemistry and coal-associated bacterial populations from a methanogenic coal bed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barnhart, Elliott P.; Weeks, Edwin P.; Jones, Elizabeth J. P.

Biogenic coalbed methane (CBM), a microbially-generated source of natural gas trapped within coal beds, is an important energy resource in many countries. Specific bacterial populations and enzymes involved in coal degradation, the potential rate-limiting step of CBM formation, are relatively unknown. The U.S. Geological Survey (USGS) has established a field site, (Birney test site), in an undeveloped area of the Powder River Basin (PRB), with four wells completed in the Flowers-Goodale coal bed, one in the overlying sandstone formation, and four in overlying and underlying coal beds (Knoblach, Nance, and Terret). The nine wells were positioned to characterize the hydraulicmore » conductivity of the Flowers-Goodale coal bed and were selectively cored to investigate the hydrogeochemistry and microbiology associated with CBM production at the Birney test site. Aquifer-test results indicated the Flowers-Goodale coal bed, in a zone from about 112-120 m below land surface at the test site, had very low hydraulic conductivity (0.005 m/d) compared to other PRB coal beds examined. Consistent with microbial methanogenesis, groundwater in the coal bed and overlying sandstone contain dissolved methane (46 mg/L average) with low δ 13C values (-67‰ average), high alkalinity values (22 meq/kg average), relatively positive δ 13C-DIC values (4‰ average), and no detectable higher chain hydrocarbons, NO 3 -, or SO 4 2-. Bioassay methane production was greatest at the upper interface of the Flowers-Goodale coal bed near the overlying sandstone. Pyrotag analysis identified Aeribacillus as a dominant in situ bacterial community member in the coal near the sandstone and statistical analysis indicated Actinobacteria predominated coal core samples compared to claystone or sandstone cores. These bacteria, which previously have been correlated with hydrocarbon-containing environments such as oil reservoirs, have demonstrated the ability to produce biosurfactants to break down

Hydrogeochemistry and coal-associated bacterial populations from a methanogenic coal bed

DOE PAGES

Barnhart, Elliott P.; Weeks, Edwin P.; Jones, Elizabeth J. P.; ...

2016-05-04

Biogenic coalbed methane (CBM), a microbially-generated source of natural gas trapped within coal beds, is an important energy resource in many countries. Specific bacterial populations and enzymes involved in coal degradation, the potential rate-limiting step of CBM formation, are relatively unknown. The U.S. Geological Survey (USGS) has established a field site, (Birney test site), in an undeveloped area of the Powder River Basin (PRB), with four wells completed in the Flowers-Goodale coal bed, one in the overlying sandstone formation, and four in overlying and underlying coal beds (Knoblach, Nance, and Terret). The nine wells were positioned to characterize the hydraulicmore » conductivity of the Flowers-Goodale coal bed and were selectively cored to investigate the hydrogeochemistry and microbiology associated with CBM production at the Birney test site. Aquifer-test results indicated the Flowers-Goodale coal bed, in a zone from about 112-120 m below land surface at the test site, had very low hydraulic conductivity (0.005 m/d) compared to other PRB coal beds examined. Consistent with microbial methanogenesis, groundwater in the coal bed and overlying sandstone contain dissolved methane (46 mg/L average) with low δ 13C values (-67‰ average), high alkalinity values (22 meq/kg average), relatively positive δ 13C-DIC values (4‰ average), and no detectable higher chain hydrocarbons, NO 3 -, or SO 4 2-. Bioassay methane production was greatest at the upper interface of the Flowers-Goodale coal bed near the overlying sandstone. Pyrotag analysis identified Aeribacillus as a dominant in situ bacterial community member in the coal near the sandstone and statistical analysis indicated Actinobacteria predominated coal core samples compared to claystone or sandstone cores. These bacteria, which previously have been correlated with hydrocarbon-containing environments such as oil reservoirs, have demonstrated the ability to produce biosurfactants to break down

Geophysical examination of coal deposits

NASA Astrophysics Data System (ADS)

Jackson, L. J.

1981-04-01

Geophysical techniques for the solution of mining problems and as an aid to mine planning are reviewed. Techniques of geophysical borehole logging are discussed. The responses of the coal seams to logging tools are easily recognized on the logging records. Cores for laboratory analysis are cut from selected sections of the borehole. In addition, information about the density and chemical composition of the coal may be obtained. Surface seismic reflection surveys using two dimensional arrays of seismic sources and detectors detect faults with throws as small as 3 m depths of 800 m. In geologically disturbed areas, good results have been obtained from three dimensional surveys. Smaller faults as far as 500 m in advance of the working face may be detected using in seam seismic surveying conducted from a roadway or working face. Small disturbances are detected by pulse radar and continuous wave electromagnetic methods either from within boreholes or from underground. Other geophysical techniques which explicit the electrical, magnetic, gravitational, and geothermal properties of rocks are described.

Health and environmental impacts of increased generation of coal ash and FGD sludges. Report to the Committee on Health and Ecological Effects of Increased Coal Utilization.

PubMed Central

Santhanam, C J; Lunt, R R; Johnson, S L; Cooper, C B; Thayer, P S; Jones, J W

1979-01-01

This paper focuses on the incremental impacts of coal ash and flue gas desulfurization (FGD) wastes associated with increased coal usage by utilities and industry under the National Energy Plan (NEP). In the paper, 1985 and 2000 are the assessment points using the baseline data taken from the Annual Environmental Analysis Report (AEAR, September 1977). In each EPA region, the potential mix of disposal options has been broadly estimated and impacts assessed therefrom. In addition, future use of advanced combustion techniques has been taken into account. The quantities of coal ash and FGD wastes depend on ash and sulfur content of the coal, emission regulations, the types of ash collection and FGD systems, and operating conditions of the systems and boiler. The disposal of these wastes is (or will be) subject to Federal and State regulations. The one key legal framework concerning environmental impact on land is the Resource Conservation and Recovery Act (RCRA). RCRA and related Federal and State laws provide a sufficient statutory basis for preventing significant adverse health and environmental impacts from coal ash and FGD waste disposal. However, much of the development and implementation of specific regulations lie ahead. FGD wastes and coal ash and FGD wastes are currently disposed of exclusively on land. The most common land disposal methods are inpoundments (ponds) and landfills, although some mine disposal is also practiced. The potential environmental impacts of this disposal are dependent on the characteristics of the disposal site, characteristics of the coal ash and FGD wastes, control method and the degree of control employed. In general, the major potential impacts are ground and surface water contamination and the "degradation" of large quantities of land. However, assuming land is available for disposal of these wastes, control technology exists for environmentally sound disposal. Because of existing increases in coal use, the possibility of

Economics and coal resource appraisal: strippable coal in the Illinois Basin ( USA).

USGS Publications Warehouse

Attanasi, E.D.; Green, E.K.

1981-01-01

Because coal is expected to provide an increasing part of U.S. energy supply, it is crucial for long term planning that coal-resource appraisals convey sufficient information regarding the degree of economic resource scarcity as coal consumption increases. Argues that coal-resource estimates, as they are now made, will not give warning of future supply difficulties. A method for incorporating an economic dimension into appraisals of strippable coal resources is presented and applied to a major producing region, the Illinois part of the Illinois basin? In particular, a long-run incremental cost function (that is unit costs vs. cumulative reserves extracted) is estimated for strippable coal in Illinois. -from Authors

Continuous coal processing method

NASA Technical Reports Server (NTRS)

Ryason, P. R. (Inventor)

1980-01-01

A coal pump is provided in which solid coal is heated in the barrel of an extruder under pressure to a temperature at which the coal assumes plastic properties. The coal is continuously extruded, without static zones, using, for example, screw extrusion preferably without venting through a reduced diameter die to form a dispersed spray. As a result, the dispersed coal may be continuously injected into vessels or combustors at any pressure up to the maximum pressure developed in the extrusion device. The coal may be premixed with other materials such as desulfurization aids or reducible metal ores so that reactions occur, during or after conversion to its plastic state. Alternatively, the coal may be processed and caused to react after extrusion, through the die, with, for example, liquid oxidizers, whereby a coal reactor is provided.

Comparison of the Eastern and Western Kentucky coal fields (Pennsylvanian), USA-why are coal distribution patterns and sulfur contents so different in these coal fields?

USGS Publications Warehouse

Greb, S.F.; Eble, C.F.; Chesnut, D.R.

2002-01-01

More than 130 Mt of Pennsylvanian coal is produced annually from two coal fields in Kentucky. The Western Kentucky Coal Field occurs in part of the Illinois Basin, an intercratonic basin, and the Eastern Kentucky Coal Field occurs in the Central Appalachian Basin, a foreland basin. The basins are only separated by 140 km, but mined western Kentucky coal beds exhibit significantly higher sulfur values than eastern Kentucky coals. Higher-sulfur coal beds in western Kentucky have generally been inferred to be caused by more marine influences than for eastern Kentucky coals. Comparison of strata in the two coal fields shows that more strata and more coal beds accumulated in the Eastern than Western Kentucky Coal Field in the Early and Middle Pennsylvanian, inferred to represent greater generation of tectonic accommodation in the foreland basin. Eastern Kentucky coal beds exhibit a greater tendency toward splitting and occurring in zones than time-equivalent western Kentucky coal beds, which is also inferred to represent foreland accommodation influences, overprinted by autogenic sedimentation effects. Western Kentucky coal beds exhibit higher sulfur values than their eastern counterparts, but western Kentucky coals occurring in Langsettian through Bolsovian strata can be low in sulfur content. Eastern Kentucky coal beds may increase in sulfur content beneath marine zones, but generally are still lower in sulfur than mined Western Kentucky coal beds, indicating that controls other than purely marine influences must have influenced coal quality. The bulk of production in the Eastern Kentucky Coal Field is from Duckmantian and Bolsovian coal beds, whereas production in the Western Kentucky Coal Field is from Westphalian D coals. Langsettian through Bolsovian paleoclimates in eastern Kentucky were favorable for peat doming, so numerous low-sulfur coals accumulated. These coals tend to occur in zones and are prone to lateral splitting because of foreland tectonic and

Coal Data Browser

EIA Publications

The Coal Data Browser gives users easy access to coal information from EIA's electricity and coal surveys as well as data from the Mine Safety and Health Administration and trade information from the U.S. Census Bureau. Users can also see the shipment data from individual mines that deliver coal to the U.S. electric power fleet, have the ability to track supplies delivered to a given power plant, and to see which mines serve each particular plant.

Gas emissions, minerals, and tars associated with three coal fires, Powder River Basin, USA.

PubMed

Engle, Mark A; Radke, Lawrence F; Heffern, Edward L; O'Keefe, Jennifer M K; Hower, James C; Smeltzer, Charles D; Hower, Judith M; Olea, Ricardo A; Eatwell, Robert J; Blake, Donald R; Emsbo-Mattingly, Stephen D; Stout, Scott A; Queen, Gerald; Aggen, Kerry L; Kolker, Allan; Prakash, Anupma; Henke, Kevin R; Stracher, Glenn B; Schroeder, Paul A; Román-Colón, Yomayra; ter Schure, Arnout

2012-03-15

Ground-based surveys of three coal fires and airborne surveys of two of the fires were conducted near Sheridan, Wyoming. The fires occur in natural outcrops and in abandoned mines, all containing Paleocene-age subbituminous coals. Diffuse (carbon dioxide (CO(2)) only) and vent (CO(2), carbon monoxide (CO), methane, hydrogen sulfide (H(2)S), and elemental mercury) emission estimates were made for each of the fires. Additionally, gas samples were collected for volatile organic compound (VOC) analysis and showed a large range in variation between vents. The fires produce locally dangerous levels of CO, CO(2), H(2)S, and benzene, among other gases. At one fire in an abandoned coal mine, trends in gas and tar composition followed a change in topography. Total CO(2) fluxes for the fires from airborne, ground-based, and rate of fire advancement estimates ranged from 0.9 to 780mg/s/m(2) and are comparable to other coal fires worldwide. Samples of tar and coal-fire minerals collected from the mouth of vents provided insight into the behavior and formation of the coal fires. Published by Elsevier B.V.

Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coal Field, USA

USGS Publications Warehouse

Greb, S.F.; Eble, C.F.; Hower, J.C.

2005-01-01

The Lower Broas-Stockton coal is a heavily mined coal of the Central Appalachian Basin. Coal thickness, distribution, composition, and stratigraphic position were compared with basement structure, gas and oil field trends, and sequence strat- igraphic and paleoclimate interpretations to better understand the geology of the Stockton coal bed in eastern Kentucky. The thickest coal occurs south of the Warfield structural trend and east of the Paint Creek Uplift, two basement-related structures. Along the Warfield trend, coal beds in the underlying Peach Orchard coal zone locally merge with the Stockton coal to form a seam more than 3 m thick. Other areas of thick coal occur in elongate trends. Two pairs of elongate, conjugate trends in Stockton coal thickness are interpreted as regional paleofractures that influenced paleotopography and groundwater during peat accumulation. Compositional group analyses indicate that the Stockton peat infilled depressions in the paleotopography as a topogenous to soligenous mire codominated by tree ferns and lycopsid trees. Flooding from adjacent paleochannels is indicated by partings and seam splits along the margins of the mineable coal body. One or more increments of low-vitrinite coal, dominated by tree ferns and shrubby, Densosporites-producing lycopsids occur at all sample sites. Similar assemblages have been previously used to identify ombrogenous, domed mire origins for Early and Middle Pennsylvanian coals in which ash yields were less than 10%. It is difficult, however, to reconcile ombrogenous conditions with the partings in the Stockton coal in this area. Low-ash, low-vitrinite increments may have been formed in topogenous to soligenous mires with periodic drying or water-table fluctuations, rather than widespread doming. This is consistent with interpretations of increasingly seasonal paleoclimates in the late Middle and Late Pennsylvanian and fracture-influenced groundwater conditions. ??2005 Geological Society of America.

Clean coal initiatives in Indiana

USGS Publications Warehouse

Bowen, B.H.; Irwin, M.W.; Sparrow, F.T.; Mastalerz, Maria; Yu, Z.; Kramer, R.A.

2007-01-01

Purpose - Indiana is listed among the top ten coal states in the USA and annually mines about 35 million short tons (million tons) of coal from the vast reserves of the US Midwest Illinois Coal Basin. The implementation and commercialization of clean coal technologies is important to the economy of the state and has a significant role in the state's energy plan for increasing the use of the state's natural resources. Coal is a substantial Indiana energy resource and also has stable and relatively low costs, compared with the increasing costs of other major fuels. This indigenous energy source enables the promotion of energy independence. The purpose of this paper is to outline the significance of clean coal projects for achieving this objective. Design/methodology/approach - The paper outlines the clean coal initiatives being taken in Indiana and the research carried out at the Indiana Center for Coal Technology Research. Findings - Clean coal power generation and coal for transportation fuels (coal-to-liquids - CTL) are two major topics being investigated in Indiana. Coking coal, data compilation of the bituminous coal qualities within the Indiana coal beds, reducing dependence on coal imports, and provision of an emissions free environment are important topics to state legislators. Originality/value - Lessons learnt from these projects will be of value to other states and countries.

EFFECT OF CONVENTIONAL AND ADVANCED COAL CONVERSION BY-PRODUCTS ON THE PULMONARY SYSTEM

EPA Science Inventory

To evaluate the environmental impact of different energy technologies, fly ash samples collected from a coal-fired and from an oil-fired electric power plant were used in aerosol inhalation exposures of mice. The effects of multiple 3-h exposures to the fly ash particles at 2 and...

Advanced subsidence monitoring using persistent scatterer interferometry for Jharia Coal Field, Dhanbad, India

NASA Astrophysics Data System (ADS)

Thapa, Shailaja; Chatterjee, R. S.; Kumar, Dheeraj; Singh, K. B.; Sengar, Vivek

2017-10-01

This paper presents a spatiotemporal study of surface subsidence over urban area due to coal mining using Persistent scatterer interferometry. In the past few years Differential Interferometric Synthetic Aperture Radar has emerged as a very useful remote sensing technique for measuring land subsidence. It plays a vital role in insitu subsidence prediction of coal mining area. However there are some limitation viz. atmospheric decorrelation, temporal decorrelation and spatial decorrelation with conventional D-InSAR techniques, which can be overcome up to certain extent by using multiinterferogram framework approach. The Persistent Scatterer interferometry technique comprises of more number of SAR datasets, it only concentrates over the pixel which remain coherent over long time period. Persistent Scatterer interferometry makes deformation measurement on permanent scattering location for the targeted ground surface. Mainly, these permanent scatterer are manmade features like metallic bridges, dams, antennae roof of buildings etc. apart that some permanent scatterer may comprise of prominent stable natural targets. The results obtained from PS-InSAR gives more precised measurement of surface deformation. Total eight ALOS PALSAR scenes covering the time period from 2007 to 2010 have been utilized to produce ground deformation map using PSInSAR techniques for Jharia Coal field, Dhanbad. This is proven technique, which helps to identify the persistent land surface movement .The results were analyzed Sijua area in Jharia coalfield. The subsidence fringes were demarcated over the entire study area. The PSInSAR results were validated using precision leveling data provided by mining authorities. The results demonstrates that PSInSAR can be used as potential tool to highlight the subsidence prone area depending upon the spatial and temporal coherency of SAR data.

Hydrogeochemistry and coal-associated bacterial populations from a methanogenic coal bed

USGS Publications Warehouse

Barnhart, Elliott P.; Weeks, Edwin P.; Jones, Elizabeth J.P.; Ritter, Daniel J.; McIntosh, Jennifer C.; Clark, Arthur C.; Ruppert, Leslie F.; Cunningham, Alfred B.; Vinson, David S.; Orem, William H.; Fields, Matthew W.

2016-01-01

Biogenic coalbed methane (CBM), a microbially-generated source of natural gas trapped within coal beds, is an important energy resource in many countries. Specific bacterial populations and enzymes involved in coal degradation, the potential rate-limiting step of CBM formation, are relatively unknown. The U.S. Geological Survey (USGS) has established a field site, (Birney test site), in an undeveloped area of the Powder River Basin (PRB), with four wells completed in the Flowers-Goodale coal bed, one in the overlying sandstone formation, and four in overlying and underlying coal beds (Knoblach, Nance, and Terret). The nine wells were positioned to characterize the hydraulic conductivity of the Flowers-Goodale coal bed and were selectively cored to investigate the hydrogeochemistry and microbiology associated with CBM production at the Birney test site. Aquifer-test results indicated the Flowers-Goodale coal bed, in a zone from about 112 to 120 m below land surface at the test site, had very low hydraulic conductivity (0.005 m/d) compared to other PRB coal beds examined. Consistent with microbial methanogenesis, groundwater in the coal bed and overlying sandstone contain dissolved methane (46 mg/L average) with low δ13C values (−67‰ average), high alkalinity values (22 meq/kg average), relatively positive δ13C-DIC values (4‰ average), and no detectable higher chain hydrocarbons, NO3−, or SO42−. Bioassay methane production was greatest at the upper interface of the Flowers-Goodale coal bed near the overlying sandstone. Pyrotag analysis identified Aeribacillus as a dominant in situbacterial community member in the coal near the sandstone and statistical analysis indicated Actinobacteria predominated coal core samples compared to claystone or sandstone cores. These bacteria, which previously have been correlated with hydrocarbon-containing environments such as oil reservoirs, have demonstrated the ability to produce biosurfactants to break down

Experiment and mechanism investigation on advanced reburning for NO(x) reduction: influence of CO and temperature.

PubMed

Wang, Zhi-Hua; Zhou, Jun-Hu; Zhang, Yan-Wei; Lu, Zhi-Min; Fan, Jian-Ren; Cen, Ke-Fa

2005-03-01

Pulverized coal reburning, ammonia injection and advanced reburning in a pilot scale drop tube furnace were investigated. Premix of petroleum gas, air and NH3 were burned in a porous gas burner to generate the needed flue gas. Four kinds of pulverized coal were fed as reburning fuel at constant rate of 1g/min. The coal reburning process parameters including 15% approximately 25% reburn heat input, temperature range from 1100 degrees C to 1400 degrees C and also the carbon in fly ash, coal fineness, reburn zone stoichiometric ratio, etc. were investigated. On the condition of 25% reburn heat input, maximum of 47% NO reduction with Yanzhou coal was obtained by pure coal reburning. Optimal temperature for reburning is about 1300 degrees C and fuel-rich stoichiometric ratio is essential; coal fineness can slightly enhance the reburning ability. The temperature window for ammonia injection is about 700 degrees C approximately 1100 degrees C. CO can improve the NH3 ability at lower temperature. During advanced reburning, 72.9% NO reduction was measured. To achieve more than 70% NO reduction, Selective Non-catalytic NO(x) Reduction (SNCR) should need NH3/NO stoichiometric ratio larger than 5, while advanced reburning only uses common dose of ammonia as in conventional SNCR technology. Mechanism study shows the oxidization of CO can improve the decomposition of H2O, which will rich the radical pools igniting the whole reactions at lower temperatures.

Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous Fenton oxidation and biological process.

PubMed

Xu, Peng; Han, Hongjun; Zhuang, Haifeng; Hou, Baolin; Jia, Shengyong; Xu, Chunyan; Wang, Dexin

2015-04-01

Laboratorial scale experiments were conducted in order to investigate a novel system integrating heterogeneous Fenton oxidation (HFO) with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process on advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that HFO with the prepared catalyst (FeOx/SBAC, sewage sludge based activated carbon (SBAC) which loaded Fe oxides) played a key role in eliminating COD and COLOR as well as in improving the biodegradability of raw wastewater. The surface reaction and hydroxyl radicals (OH) oxidation were the mechanisms for FeOx/SBAC catalytic reaction. Compared with ANMBBR-BAF process, the integrated system was more effective in abating COD, BOD5, total phenols (TPs), total nitrogen (TN) and COLOR and could shorten the retention time. Therefore, the integrated system was a promising technology for engineering applications. Copyright © 2015 Elsevier Ltd. All rights reserved.

Coal Markets

EIA Publications

2017-01-01

Summarizes spot coal prices by coal commodity regions (i.e., Central Appalachia (CAP), Northern Appalachia (NAP), Illinois Basin (ILB), Power River Basin (PRB), and Uinta Basin (UIB)) in the United States.

Microbial Beneficiation of Salem Iron Ore Using Penicillium purpurogenum

NASA Astrophysics Data System (ADS)

Mishra, M.; Pradhan, M.; Sukla, L. B.; Mishra, B. K.

2011-02-01

High alumina and silica content in the iron ore affects coke rate, reducibility, and productivity in a blast furnace. Iron ore is being beneficiated all around the world to meet the quality requirement of iron and steel industries. Choosing a beneficiation treatment depends on the nature of the gangue present and its association with the ore structure. The advanced physicochemical methods used for the beneficiation of iron ore are generally unfriendly to the environment. Biobeneficiation is considered to be ecofriendly, promising, and revolutionary solutions to these problems. A characterization study of Salem iron ore indicates that the major iron-bearing minerals are hematite, magnetite, and goethite. Samples on average contains (pct) Fe2O3-84.40, Fe (total)-59.02, Al2O3-7.18, and SiO2-7.53. Penicillium purpurogenum (MTCC 7356) was used for the experiment . It removed 35.22 pct alumina and 39.41 pct silica in 30 days in a shake flask at 10 pct pulp density, 308 K (35 °C), and 150 rpm. In a bioreactor experiment at 2 kg scale using the same organism, it removed 23.33 pct alumina and 30.54 pct silica in 30 days at 300 rpm agitation and 2 to 3 l/min aeration. Alumina and silica dissolution follow the shrinking core model for both shake flask and bioreactor experiments.

Estimation of Coal Reserves for UCG in the Upper Silesian Coal Basin, Poland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bialecka, Barbara

One of the prospective methods of coal utilization, especially in case of coal resources which are not mineable by means of conventional methods, is underground coal gasification (UCG). This technology allows recovery of coal energy 'in situ' and thus avoid the health and safety risks related to people which are inseparable from traditional coal extraction techniques.In Poland most mining areas are characterized by numerous coal beds where extraction was ceased on account of technical and economic reasons or safety issues. This article presents estimates of Polish hard coal resources, broken down into individual mines, that can constitute the basis ofmore » raw materials for the gasification process. Five mines, representing more than 4 thousand tons, appear to be UCG candidates.« less

78 FR 28242 - Proposed Information Collection; Cleanup Program for Accumulations of Coal and Float Coal Dusts...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-14

... Program for Accumulations of Coal and Float Coal Dusts, Loose Coal, and Other Combustibles AGENCY: Mine... collection for developing and updating a cleanup program for accumulations of coal and float coal dusts, loose coal, and other combustibles in underground coal mines. DATES: All comments must be postmarked or...

Optical fiber evanescent absorption sensors for high-temperature gas sensing in advanced coal-fired power plants

NASA Astrophysics Data System (ADS)

Buric, Michael P.; Ohodnicky, Paul R.; Duy, Janice

2012-10-01

Modern advanced energy systems such as coal-fired power plants, gasifiers, or similar infrastructure present some of the most challenging harsh environments for sensors. The power industry would benefit from new, ultra-high temperature devices capable of surviving in hot and corrosive environments for embedded sensing at the highest value locations. For these applications, we are currently exploring optical fiber evanescent wave absorption spectroscopy (EWAS) based sensors consisting of high temperature core materials integrated with novel high temperature gas sensitive cladding materials. Mathematical simulations can be used to assist in sensor development efforts, and we describe a simulation code that assumes a single thick cladding layer with gas sensitive optical constants. Recent work has demonstrated that Au nanoparticle-incorporated metal oxides show a potentially useful response for high temperature optical gas sensing applications through the sensitivity of the localized surface plasmon resonance absorption peak to ambient atmospheric conditions. Hence, the simulation code has been applied to understand how such a response can be exploited in an optical fiber based EWAS sensor configuration. We demonstrate that interrogation can be used to optimize the sensing response in such materials.

Hydrodesulfurization of chlorinized coal

NASA Technical Reports Server (NTRS)

Kalvinskas, J. J.; Rohatgi, N. K. (Inventor)

1983-01-01

A method of desulfurization is described in which high sulfur coals are desulfurized by low temperature chlorinolysis of coal in liquid media, preferably water, followed by hydrodesulfurization at a temperature above 500 C. The coals are desulfurized to an extent of up to 90% by weight and simultaneously dechlorinated to a chlorine content below 0.1% by weight. The product coals have lower volatiles loss, lower oxygen and nitrogen content and higher fixed carbon than raw coals treated with hydrogen under the same conditions. Heating the chlorinated coal to a temperature above 500 C. in inert gas such as nitrogen results in significantly less desulfurization.

Coal pump development phase 3

NASA Technical Reports Server (NTRS)

Kushida, R. O.; Sankur, V. D.; Gerbracht, F. G.; Mahajan, V.

1980-01-01

Techniques for achieving continuous coal sprays were studied. Coazial injection with gas and pressure atomization were studied. Coal particles, upon cooling, were found to be porous and fragile. Reactivity tests on the extruded coal showed overall conversion to gases and liquids unchanged from that of the raw coal. The potentials for applications of the coal pump to eight coal conversion processes were examined.

Microbial solubilization of coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Campbell, J.A.; Fredrickson, J.K.; Stewart, D.L.

1988-11-01

Microbial solubilization of coal may serve as a first step in a process to convert low-rank coals or coal-derived products to other fuels or products. For solubilization of coal to be an economically viable technology, a mechanistic understanding of the process is essential. Leonardite, a highly oxidized, low-rank coal, has been solubilized by the intact microorganism, cell-free filtrate, and cell-free enzyme of /ital Coriolus versicolor/. A spectrophotometric conversion assay was developed to quantify the amount of biosolubilized coal. In addition, a bituminous coal, Illinois No. 6, was solubilized by a species of /ital Penicillium/, but only after the coal hadmore » been preoxidized in air. Model compounds containing coal-related functionalities have been incubated with the leonardite-degrading fungus, its cell-free filtrate, and purified enzyme. The amount of degradation was determined by gas chromatography and the degradation products were identified by gas chromatography/mass spectrometry. We have also separated the cell-free filtrate of /ital C. versicolor/ into a <10,000 MW and >10,000 MW fraction by ultrafiltration techniques. Most of the coal biosolubilization activity is contained in the <10,000 MW fraction while the model compound degradation occurs in the >10,000 MW fraction. The >10,000 MW fraction appears to contain an enzyme with laccase-like activity. 10 refs., 8 figs., 5 tabs.« less

Benefits from synergies and advanced technologies for an advanced-technology space station

NASA Technical Reports Server (NTRS)

Garrett, L. Bernard; Ferebee, Melvin J., Jr.; Queijo, Manuel J.; Butterfield, Ansel J.

1991-01-01

A configuration for a second-generation advanced technology space station has been defined in a series of NASA-sponsored studies. Definitions of subsystems specifically addressed opportunities for beneficial synergistic interactions and those potential synergies and their benefits are identified. One of the more significant synergistic benefits involves the multi-function utilization of water within a large system that generates artificial gravity by rotation. In such a system, water not only provides the necessary crew life support, but also serves as counterrotator mass, as moveable ballast, and as a source for propellant gases. Additionally, the synergistic effects between advanced technology materials, operation at reduced artificial gravity, and lower cabin atmospheric pressure levels show beneficial interactions that can be quantified in terms of reduced mass to orbit.

USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edward Levy; Nenad Sarunac; Harun Bilirgen

2005-04-01

This is the ninth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, comparative analyses were performed for lignite and PRB coals to determine how unit performance varies with coal product moisture. Results are given showing how the coal product moisture level and coal rank affect parameters such as boiler efficiency, station service power needed for fans and pulverizers and net unit heat rate. Results are also givenmore » for the effects of coal drying on cooling tower makeup water and comparisons are made between makeup water savings for various times of the year.« less

The Rate of Beneficial Mutations Surfing on the Wave of a Range Expansion

PubMed Central

Lehe, Rémi; Hallatschek, Oskar; Peliti, Luca

2012-01-01

Many theoretical and experimental studies suggest that range expansions can have severe consequences for the gene pool of the expanding population. Due to strongly enhanced genetic drift at the advancing frontier, neutral and weakly deleterious mutations can reach large frequencies in the newly colonized regions, as if they were surfing the front of the range expansion. These findings raise the question of how frequently beneficial mutations successfully surf at shifting range margins, thereby promoting adaptation towards a range-expansion phenotype. Here, we use individual-based simulations to study the surfing statistics of recurrent beneficial mutations on wave-like range expansions in linear habitats. We show that the rate of surfing depends on two strongly antagonistic factors, the probability of surfing given the spatial location of a novel mutation and the rate of occurrence of mutations at that location. The surfing probability strongly increases towards the tip of the wave. Novel mutations are unlikely to surf unless they enjoy a spatial head start compared to the bulk of the population. The needed head start is shown to be proportional to the inverse fitness of the mutant type, and only weakly dependent on the carrying capacity. The precise location dependence of surfing probabilities is derived from the non-extinction probability of a branching process within a moving field of growth rates. The second factor is the mutation occurrence which strongly decreases towards the tip of the wave. Thus, most successful mutations arise at an intermediate position in the front of the wave. We present an analytic theory for the tradeoff between these factors that allows to predict how frequently substitutions by beneficial mutations occur at invasion fronts. We find that small amounts of genetic drift increase the fixation rate of beneficial mutations at the advancing front, and thus could be important for adaptation during species invasions. PMID:22479175

Preliminary investigation on the effects of primary airflow to coal particle distribution in coal-fired boilers

NASA Astrophysics Data System (ADS)

Noor, N. A. W. Mohd; Hassan, H.; Hashim, M. F.; Hasini, H.; Munisamy, K. M.

2017-04-01

This paper presents an investigation on the effects of primary airflow to coal fineness in coal-fired boilers. In coal fired power plant, coal is pulverized in a pulverizer, and it is then transferred to boiler for combustion. Coal need to be ground to its desired size to obtain maximum combustion efficiency. Coarse coal particle size may lead to many performance problems such as formation of clinker. In this study, the effects of primary airflow to coal particles size and coal flow distribution were investigated by using isokinetic coal sampling and computational fluid dynamic (CFD) modelling. Four different primary airflows were tested and the effects to resulting coal fineness were recorded. Results show that the optimum coal fineness distribution is obtained at design primary airflow. Any reduction or increase of air flow rate results in undesirable coal fineness distribution.

Coal-oil slurry preparation

DOEpatents

Tao, John C.

1983-01-01

A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

Experimental and computational study and development of the bituminous coal entrained-flow air-blown gasifier for IGCC

NASA Astrophysics Data System (ADS)

Abaimov, N. A.; Osipov, P. V.; Ryzhkov, A. F.

2016-10-01

In the paper the development of the advanced bituminous coal entrained-flow air- blown gasifier for the high power integrated gasification combined cycle is considered. The computational fluid dynamics technique is used as the basic development tool. The experiment on the pressurized entrained-flow gasifier was performed by “NPO CKTI” JSC for the thermochemical processes submodel verification. The kinetic constants for Kuznetsk bituminous coal (flame coal), obtained by thermal gravimetric analysis method, are used in the model. The calculation results obtained by the CFD model are in satisfactory agreements with experimental data. On the basis of the verified model the advanced gasifier structure was suggested which permits to increase the hydrogen content in the synthesis gas and consequently to improve the gas turbine efficiency. In order to meet the specified requirements vapor is added on the second stage of MHI type gasifier and heat necessary for air gasification is compensated by supplemental heating of the blasting air.

Chemicals to help coal come clean

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thayer, A.M.

Scrubbing methods to capture carbon from power plants are advancing to the demonstration phase. The article gives an update of projects around the world, and the goals and cost of CCS projects. BASF, together with RWE Power and Linde, are working to ensure state of the art integration of the carbon-capture process into a power plant to minimize the penalty in electrical output. A pilot project will test new solvents in an 'advanced amine' system at RWE's power station in Niederaussem, Germany. A pilot unit will soon capture CO{sub 2} from a coal-fired plant of Dow's in South Charleston, WV,more » USA and Dow has also agreed to build an amines demonstration facility in Belchatow, Poland. Other projects in the USA and Canada are reported. 1 fig.« less

Continuous bench-scale slurry catalyst testing direct coal liquefaction rawhide sub-bituminous coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bauman, R.F.; Coless, L.A.; Davis, S.M.

In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263.more » Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.« less

Geomorphology of coal seam fires

NASA Astrophysics Data System (ADS)

Kuenzer, Claudia; Stracher, Glenn B.

2012-02-01

Coal fires occur in underground natural coal seams, in exposed surface seams, and in coal storage or waste piles. The fires ignite through spontaneous combustion or natural or anthropogenic causes. They are reported from China, India, USA, South Africa, Australia, and Russia, as well as many other countries. Coal fires lead to loss of a valuable resource (coal), the emission of greenhouse-relevant and toxic gases, and vegetation deterioration. A dangerous aspect of the fires is the threat to local mines, industries, and settlements through the volume loss underground. Surface collapse in coal fire areas is common. Thus, coal fires are significantly affecting the evolution of the landscape. Based on more than a decade of experience with in situ mapping of coal fire areas worldwide, a general classification system for coal fires is presented. Furthermore, coal seam fire geomorphology is explained in detail. The major landforms associated with, and induced by, these fires are presented. The landforms include manifestations resulting from bedrock surface fracturing, such as fissures, cracks, funnels, vents, and sponges. Further manifestations resulting from surface bedrock subsidence include sinkholes, trenches, depressions, partial surface subsidence, large surface subsidence, and slides. Additional geomorphologic coal fire manifestations include exposed ash layers, pyrometamorphic rocks, and fumarolic minerals. The origin, evolution, and possible future development of these features are explained, and examples from in situ surveys, as well as from high-resolution satellite data analyses, are presented. The geomorphology of coal fires has not been presented in a systematic manner. Knowledge of coal fire geomorphology enables the detection of underground coal fires based on distinct surface manifestations. Furthermore, it allows judgments about the safety of coal fire-affected terrain. Additionally, geomorphologic features are indicators of the burning stage of fires

The fate of mercury in coal utilization byproducts

DOE Office of Scientific and Technical Information (OSTI.GOV)

William Aljoe; Thomas Feeley; James Murphy

2005-05-01

The US Department of Energy National Energy Technology Laboratory's (DOE/NETL's) research has helped to further scientific understanding of the environmental characteristics of coal-utilization by-products (CUBs) in both disposal and beneficial utilization applications. The following general observations can be drawn from results of the research that has been carried out to date: There appears to be only minimal mercury release to the environment in typical disposal or utilization applications for CUBs generated using activated carbon injection (ACI) control technologies; There appears to be only minimal mercury release to the environment in typical disposal and utilization applications for CUBs generated using wetmore » FGD control technologies. The potential release of mercury from wet FGD gypsum during the manufacture of wallboard is still under evaluation; The amount of mercury leached from CUB samples tested by DOE/NETL is significantly lower than the federal drinking water standards and water quality criteria for the protection of aquatic life; in many cases, leachate concentrations were below the standard test method detection limits. DOE/NETL will continue to partner with industry and other key stakeholders in carrying out research to better understand the fate of mercury and other trace elements in the byproducts from coal combustion. 16 refs., 6 tabs.« less

Coal pump

DOEpatents

Bonin, John H.; Meyer, John W.; Daniel, Jr., Arnold D.

1983-01-01

A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

Boiler Briquette Coal versus Raw Coal: Part I-Stack Gas Emissions.

PubMed

Ge, Su; Bai, Zhipeng; Liu, Weili; Zhu, Tan; Wang, Tongjian; Qing, Sheng; Zhang, Junfeng

2001-04-01

Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM 10 and PM 2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM 10 , 0.38 for PM 25 , 20.7 for SO 2 , and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM 10 , 0.30 for PM 2 5 , 7.5 for SO 2 , and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM 10 , 0.87 for PM 25 , 46.7 for SO 2 , and 15 for CO, while those of the BB-coal were 2.51 for PM 10 , 0.79 for PM 2.5 , 19.9 for SO 2 , and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/ steam conversion factors, were 0.23 for PM 10 , 0.12 for PM 2.5 , 6.4 for SO 2 , and 2.0 for CO, while those of the BB-coal were 0.30 for PM 10 , 0.094 for PM 2.5 , 2.4 for SO 2 , and 1.7 for CO. PM 10 and PM 2.5 elemental compositions are also presented for both types of coal tested in the study.

Boiler briquette coal versus raw coal: Part I--Stack gas emissions.

PubMed

Ge, S; Bai, Z; Liu, W; Zhu, T; Wang, T; Qing, S; Zhang, J

2001-04-01

Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM10 and PM2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM10, 0.38 for PM2.5, 20.7 for SO2, and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM10, 0.30 for PM2.5, 7.5 for SO2, and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM10, 0.87 for PM2.5, 46.7 for SO2, and 15 for CO, while those of the BB-coal were 2.51 for PM10, 0.79 for PM2.5, 19.9 for SO2, and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/steam conversion factors, were 0.23 for PM10, 0.12 for PM2.5, 6.4 for SO2, and 2.0 for CO, while those of the BB-coal were 0.30 for PM10, 0.094 for PM2.5, 2.4 for SO2, and 1.7 for CO. PM10 and PM2.5 elemental compositions are also presented for both types of coal tested in the study.

Coal Formation and Geochemistry

NASA Astrophysics Data System (ADS)

Orem, W. H.; Finkelman, R. B.

2003-12-01

Coal is one of the most complex and challenging natural materials to analyze and to understand. Unlike most rocks, which consist predominantly of crystalline mineral grains, coal is largely an assemblage of amorphous, degraded plant remains metamorphosed to various degrees and intermixed with a generous sprinkling of minute syngenetic, diagenetic, epigenetic, and detrital mineral grains, and containing within its structure various amounts of water, oils, and gases. Each coal is unique, having been derived from different plant sources over geologic time, having experienty -45ced different thermal histories, and having been exposed to varying geologic processes. This diversity presents a challenge to constructing a coherent picture of coal geochemistry and the processes that influence the chemical composition of coal.Despite the challenge coal presents to geochemists, a thorough understanding of the chemistry and geology of this complex natural substance is essential because of its importance to our society. Coal is, and will remain for sometime, a crucial source of energy for the US and for many other countries (Figure 1). In the USA, more than half of the electricity is generated by coal-fired power plants, and almost 90% of the coal mined in the USA is sold for electricity generation (Pierce et al., 1996). It is also an important source of coke for steel production, chemicals, pharmaceuticals, and even perfumes ( Schobert, 1987). It may also, in some cases, be an economic source of various mineral commodities. The utilization of coal through mining, transport, storage, combustion, and the disposal of the combustion by-products, also presents a challenge to geochemists because of the wide range of environmental and human health problems arising from these activities. The sound and effective use of coal as a natural resource requires a better understanding of the geochemistry of coal, i.e., the chemical and mineralogical characteristics of the coal that control its

Hydrogen from coal

NASA Technical Reports Server (NTRS)

1975-01-01

Hydrogen production from coal by hydrogasification is described. The process involves the solubilization of coal to form coal liquids, which are hydrogasified to produce synthetic pipeline gas; steam reforming this synthetic gas by a nuclear heat source produces hydrogen. A description is given of the hydrogen plant, its performance, and its effect on the environment.

Relative trace-element concern indexes for eastern Kentucky coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Collins, S.L.

Coal trace elements that could affect environmental quality were studied in 372 samples (collected and analyzed by the Kentucky Geological Survey and the United States Geological Survey) from 36 coal beds in eastern Kentucky. Relative trace-element concern indexes are defined as the weighted sum of standarized (substract mean; divide by standard deviation) concentrations. Index R is calculated from uranium and thorium, index 1 from elements of minor concern (antimony, barium, bromine, chloride, cobalt, lithium, manganese, sodium, and strontium), index 2 from elements of moderate concern (chromium, copper, fluorine, nickel, vanadium, and zinc), and index 4 from elements of greatest concernmore » (arsenic, boron, cadmium, lead, mercury, molybdenum, and selenium). Numericals indicate weights, except that index R is weighted by 1, and index 124 is the unweighted sum of indexes 1, 2, and 4. Contour mapping indexes is valid because all indexes have nonnugget effect variograms. Index 124 is low west of Lee and Bell counties, and in Pike County. Index 124 is high in the area bounded by Boyd, Menifee, Knott, and Martin counties and in Owsley, Clay, and Leslie counties. Coal from some areas of eastern Kentucky is less likely to cause environmental problems than that from other areas. Positive correlations of all indexes with the centered log ratios of ash, and negative correlations with centered log ratios of carbon, hydrogen, nitrogen, oxygen, and sulfur indicate that trace elements of concern are predominantly associated with ash. Beneficiation probably would reduce indexes significantly.« less

The directory of United States coal & technology export resources. Profiles of domestic US corporations, associations and public entities, nationwide, which offer products or services suitable for export, relating to coal and its utilization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-01-01

The purpose of this directory is to provide a listing of available U.S. coal and coal related resources to potential purchasers of those resources abroad. The directory lists business entities within the US which offer coal related resources, products and services for sale on the international market. Each listing is intended to describe the particular business niche or range of product and/or services offered by a particular company. The listing provides addresses, telephones, and telex/fax for key staff in each company committed to the facilitation of international trade. The content of each listing has been formulated especially for this directorymore » and reflects data current as of the date of this edition. The directory listings are divided into four primary classifications: coal resources; technology resources; support services; and financing and resource packaging. The first three of which are subdivided as follows: Coal Resources -- coal derivatives, coal exporters, and coal mining; Technology Resources -- advanced utilization, architects and engineers, boiler equipment, emissions control and waste disposal systems, facility construction, mining equipment, power generation systems, technical publications, and transport equipment; Support Services -- coal transport, facility operations, freight forwarders, sampling services and equipment, and technical consultants. Listings for the directory were solicited on the basis of this industry breakdown. Each of the four sections of this directory begins with a matrix illustrating which companies fall within the particular subclassifications specific to that main classification. A general alphabetical index of companies and an index by product/service classification are provided following the last section of the directory.« less

Microbial conversion of coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bean, R.M.

1989-10-01

The objectives of this project were to describe in detail the degradation of coals by fungi and microbes, to expand the range of applicability of the process to include new microbes and other coal types, to identify the means by which biosolubilization of coal is accomplished, and to explore means to enhance the rates and extent of coal bioconversion. The project was initiated in a response to the discovery by Dr. Martin Cohen at the University of Hartford, of a fungal strain of Coriolus versicolor that would render a solid coal substance, leonardite, into a liquid product. The project hasmore » identified the principal agent of leonardite solubilization as a powerful metal chelator, most likely a fungal-produced siderophore. Another nonlaccase enzyme has also been identified as a unique biosolubilizing agent produced by C. versicolor. Assays were developed for the quantitative determination of biological coal conversion, and for the determination of potency of biosolubilizing agent. Screening studies uncovered several microbial organisms capable of coal biodegradation, and led to the discovery that prolonged heating in air at the moderate temperature of 150{degree}C allowed the biodegradation of Illinois {number sign}6 coal to material soluble in dilute base. Chemical studies showed that leonardite biosolubilization was accompanied by relatively small change in composition, while solubilization of Illinois {number sign}6 coal involves considerable oxidation of the coal. 24 refs., 32 figs., 27 tabs.« less

Underground Coal Thermal Treatment: Task 6 Topical Report, Utah Clean Coal Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, P.J.; Deo, M.; Edding, E.G.

The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand themore » feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. CO 2 storage. In order to help determine the amount of CO 2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.« less

Chemical structures of coal lithotypes before and after CO2 adsorption as investigated by advanced solid-state 13C nuclear magnetic resonance spectroscopy

USGS Publications Warehouse

Cao, X.; Mastalerz, Maria; Chappell, M.A.; Miller, L.F.; Li, Y.; Mao, J.

2011-01-01

Four lithotypes (vitrain, bright clarain, clarain, and fusain) of a high volatile bituminous Springfield Coal from the Illinois Basin were characterized using advanced solid-state 13C nuclear magnetic resonance (NMR) spectroscopy. The NMR techniques included quantitative direct polarization/magic angle spinning (DP/MAS), cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CHn selection, and recoupled C-H long-range dipolar dephasing techniques. The lithotypes that experienced high-pressure CO2 adsorption isotherm analysis were also analyzed to determine possible changes in coal structure as a result of CO2 saturation at high pressure and subsequent evacuation. The main carbon functionalities present in original vitrain, bright clarain, clarain and fusain were aromatic carbons (65.9%-86.1%), nonpolar alkyl groups (9.0%-28.9%), and aromatic C-O carbons (4.1%-9.5%). Among these lithotypes, aromaticity increased in the order of clarain, bright clarain, vitrain, and fusain, whereas the fraction of alkyl carbons decreased in the same order. Fusain was distinct from other three lithotypes in respect to its highest aromatic composition (86.1%) and remarkably small fraction of alkyl carbons (11.0%). The aromatic cluster size in fusain was larger than that in bright clarain. The lithotypes studied responded differently to high pressure CO2 saturation. After exposure to high pressure CO2, vitrain and fusain showed a decrease in aromaticity but an increase in the fraction of alkyl carbons, whereas bright clarain and clarain displayed an increase in aromaticity but a decrease in the fraction of alkyl carbons. Aromatic fused-rings were larger for bright clarain but smaller for fusain in the post-CO2 adsorption samples compared to the original lithotypes. These observations suggested chemical CO2-coal interactions at high pressure and the selectivity of lithotypes in response to CO2 adsorption. ?? 2011 Elsevier B.V.

Coal and Open-pit surface mining impacts on American Lands (COAL)

NASA Astrophysics Data System (ADS)

Brown, T. A.; McGibbney, L. J.

2017-12-01

Mining is known to cause environmental degradation, but software tools to identify its impacts are lacking. However, remote sensing, spectral reflectance, and geographic data are readily available, and high-performance cloud computing resources exist for scientific research. Coal and Open-pit surface mining impacts on American Lands (COAL) provides a suite of algorithms and documentation to leverage these data and resources to identify evidence of mining and correlate it with environmental impacts over time.COAL was originally developed as a 2016 - 2017 senior capstone collaboration between scientists at the NASA Jet Propulsion Laboratory (JPL) and computer science students at Oregon State University (OSU). The COAL team implemented a free and open-source software library called "pycoal" in the Python programming language which facilitated a case study of the effects of coal mining on water resources. Evidence of acid mine drainage associated with an open-pit coal mine in New Mexico was derived by correlating imaging spectrometer data from the JPL Airborne Visible/InfraRed Imaging Spectrometer - Next Generation (AVIRIS-NG), spectral reflectance data published by the USGS Spectroscopy Laboratory in the USGS Digital Spectral Library 06, and GIS hydrography data published by the USGS National Geospatial Program in The National Map. This case study indicated that the spectral and geospatial algorithms developed by COAL can be used successfully to analyze the environmental impacts of mining activities.Continued development of COAL has been promoted by a Startup allocation award of high-performance computing resources from the Extreme Science and Engineering Discovery Environment (XSEDE). These resources allow the team to undertake further benchmarking, evaluation, and experimentation using multiple XSEDE resources. The opportunity to use computational infrastructure of this caliber will further enable the development of a science gateway to continue foundational COAL

National Coal Quality Inventory (NACQI)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robert Finkelman

2005-09-30

The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale,more » and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.« less

Comparison of Mortality Disparities in Central Appalachian Coal- and Non-Coal-Mining Counties.

PubMed

Woolley, Shannon M; Meacham, Susan L; Balmert, Lauren C; Talbott, Evelyn O; Buchanich, Jeanine M

2015-06-01

Determine whether select cause of death mortality disparities in four Appalachian regions is associated with coal mining or other factors. We calculated direct age-adjusted mortality rates and associated 95% confidence intervals by sex and study group for each cause of death over 5-year time periods from 1960 to 2009 and compared mean demographic and socioeconomic values between study groups via two-sample t tests. Compared with non-coal-mining areas, we found higher rates of poverty in West Virginia and Virginia (VA) coal counties. All-cause mortality rates for males and females were higher in coal counties across all time periods. Virginia coal counties had statistically significant excesses for many causes of death. We found elevated mortality and poverty rates in coal-mining compared with non-coal-mining areas of West Virginia and VA. Future research should examine these findings in more detail at the individual level.

Coal: the new black

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tullo, A.H.; Tremblay, J.-F.

2008-03-15

Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is tomore » convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.« less

Geology, coal quality, and resources of the Antaramut-Kurtan-Dzoragukh coal field, north-central Armenia

USGS Publications Warehouse

Pierce, B.S.; Martirosyan, A.; Malkhasian, G.; Harutunian, S.; Harutunian, G.

2001-01-01

The Antaramut-Kurta-Dzoragukh (AKD) coal deposit is a previously unrecognized coal field in north-central Armenia. Coal has been known to exist in the general vicinity since the turn of the century, but coal was thought to be restricted to a small (1 km2) area only near the village of Antaramut. However, through detailed field work and exploratory drilling, this coal deposit has been expanded to at least 20 km2, and thus renamed the Antaramut-Kurtan-Dzoragukh coal field, for the three villages that the coal field encompasses. The entire coal-bearing horizon, a series of tuffaceous sandstones, siltstones, and claystones, is approximately 50 m thick. The AKD coal field contains two coal beds, each greater than 1 m thick, and numerous small rider beds, with a total resource of approximately 31,000,000 metric tonnes. The coals are late Eocene in age, high volatile bituminous in rank, relatively high in ash yield (approximately 40%, as-determined basis) and moderate in sulfur content (approximately 3%, as-determined basis). The two coal beds (No. 1 and No. 2), on a moist, mineral-matter-free basis, have high calorific values of 32.6 MJ/kg (7796 cal/g) and 36.0 MJ/kg (8599 cal/g), respectively. Coal is one of the few indigenous fossil fuel resources occurring in Armenia and thus, the AKD coal field could potentially provide fuel for heating and possibly energy generation in the Armenian energy budget. Published by Elsevier Science B.V.

Coal liquefaction and hydrogenation

DOEpatents

Schindler, Harvey D.; Chen, James M.

1985-01-01

Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

Characterization of the chemical variation of feed coal and coal combustion products from a power plant utilizing low sulfur Powder River Basin coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Affolter, R.H.; Brownfield, M.E.; Cathcart, J.D.

2000-07-01

The US Geological Survey and the University of Kentucky Center for Applied Energy Research, in collaboration with an Indiana utility, are studying a coal-fired power plant burning Powder River Basin coal. This investigation involves a systematic study of the chemical and mineralogical characteristics of feed coal and coal combustion products (CCPs) from a 1,300-megawatt (MW) power unit. The main goal of this study is to characterize the temporal chemical variability of the feed coal, fly ash, and bottom ash by looking at the major-, minor-, and trace-element compositions and their associations with the feed coal mineralogy. Emphasis is also placedmore » on the abundance and modes of occurrence of elements of potential environmental concern that may affect the utilization of these CCPs and coals.« less

Mining geology of the Pond Creek seam, Pikeville Formation, Middle Pennsylvanian, in part of the Eastern Kentucky Coal Field, USA

USGS Publications Warehouse

Greb, S.F.; Popp, J.T.

1999-01-01

The Pond Creek seam is one of the leading producers of coal in the Eastern Kentucky Coal Field. The geologic factors that affect mining were investigated in several underground mines and categorized in terms of coal thickness, coal quality, and roof control. The limits of mining and thick coal are defined by splitting along the margin of the coal body. Within the coal body, local thickness variation occurs because of (1) leader coal benches filling narrow, elongated depressions, (2) rider coal benches coming near to or merging with the main bench, (3) overthrust coal benches being included along paleochannel margins, (4) cutouts occuring beneath paleochannels, and (5) very hard and unusual rock partings occuring along narrow, elongated trends. In the study area, the coal is mostly mined as a compliance product: sulfur contents are less than 1% and ash yields are less than 10%. Local increases in sulfur occur beneath sandstones, and are inferred to represent post-depositional migration of fluids through porous sands into the coal. Run-of-mine quality is also affected by several mine-roof conditions and trends of densely concentrated rock partings, which lead to increased in- and out-of-seam dilution and overall ash content of the mined coal. Roof control is largely a function of a heterolithic facies mosaic of coastal-estuarine origin, regional fracture trends, and unloading stress related to varying mine depth beneath the surface. Lateral variability of roof facies is the rule in most mines. The largest falls occur beneath modern valleys and parallel fractures, along paleochannel margins, within tidally affected 'stackrock,' and beneath rider coals. Shale spalling, kettlebottoms, and falls within other more isolated facies also occur. Many of the lithofacies, and falls related to bedding weaknesses within or between lithofacies, occur along northeast-southwest trends, which can be projected in advance of mining. Fracture-related falls occur independently of

Microgas dispersion for fine-coal cleaning. Technical progress report, March 1, 1981-August 31, 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoon, R.H.; Halsey, G.S.; Sebba, F.

1981-01-01

The results of the flotation tests conducted demonstrate that the use of fine colloidal gas aphrons (CGA) bubbles is beneficial for fine coal flotation. As demonstrated with the ultrafine coal sample, the froth products of CGA flotation are almost twice as clean as those of the conventional flotation tests at 70% yield. The kerosene consumption was considerably higher, however, both in conventional and in CGA flotation. Attempts were made to coat the CGA bubbles with a film of kerosene and use them for flotation, hoping that this would reduce the oil consumption. However, no positive results have yet been obtainedmore » with this process. Another problem associated with CGA flotation is that the ash content of the froth products is relatively high when using a stable CGA, such as that prepared with Dowfroth M150. On the other hand, when using an unstable CGA, as is the case with MIBC, low ash clean coal products can be obtained, but at the expense of the yield. Two approaches are being investigated to correct this problem. A considerable amount of effort has been made to determine the surface charge of the CGA.« less

Mapping and prediction of Coal Workers' Pneumoconiosis with bioavailable iron content in the bituminous coals

USGS Publications Warehouse

Huang, X.; Li, W.; Attfield, M.D.; Nadas, A.; Frenkel, K.; Finkelman, R.B.

2005-01-01

Based on the first National Study of Coal Workers' Pneumoconiosis (CWP) and the U.S. Geological Survey database of coal quality, we show that the prevalence of CWP in seven coal mine regions correlates with levels of bioavailable iron (BAI) in the coals from that particular region (correlation coefficient r = 0.94, p < 0.0015). CWP prevalence is also correlated with contents of pyritic sulfur (r = 0.91, p < 0.0048) or total iron (r = 0.85, p < 0.016) but not with coal rank (r = 0.59, p < 0.16) or silica (r = 0.28, p < 0.54). BAI was calculated using our model, taking into account chemical interactions of pyrite, sulfuric acid, calcite, and total iron. That is, iron present in coals can become bioavailable by pyrite oxidation, which produces ferrous sulfate and sulfuric acid. Calcite is the major component in coals that neutralizes the available acid and inhibits iron's bioavailabiity. Therefore, levels of BAI in the coals are determined by the available amounts of acid after neutralization of calcite and the amount of total iron in the coals. Using the linear fit of CWP prevalence and the calculated BAI in the seven coal mine regions, we have derived and mapped the pneumoconiotic potencies of 7,000 coal samples. Our studies indicate that levels of BAI in the coals may be used to predict coal's toxicity, even before large-scalen mining.

Energy Conversion Alternatives Study (ECAS), Westinghouse phase 1. Volume 1: Introduction and summary and general assumptions. [energy conversion systems for electric power plants using coal - feasibility

NASA Technical Reports Server (NTRS)

Beecher, D. T.

1976-01-01

Nine advanced energy conversion concepts using coal or coal-derived fuels are summarized. They are; (1) open-cycle gas turbines, (2) combined gas-steam turbine cycles, (3) closed-cycle gas turbines, (4) metal vapor Rankine topping, (5) open-cycle MHD; (6) closed-cycle MHD; (7) liquid-metal MHD; (8) advanced steam; and (9) fuel cell systems. The economics, natural resource requirements, and performance criteria for the nine concepts are discussed.

Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huffman, Gerald

2012-12-31

This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation's urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

Cytotoxicity and genotoxicity induced by coal and coal fly ash particles samples in V79 cells.

PubMed

León-Mejía, Grethel; Silva, Luis F O; Civeira, Matheus S; Oliveira, Marcos L S; Machado, Miriana; Villela, Izabel Vianna; Hartmann, Andreas; Premoli, Suziane; Corrêa, Dione Silva; Da Silva, Juliana; Henriques, João Antônio Pêgas

2016-12-01

Exposure to coal and coal ashes can cause harmful effects in in vitro and in vivo systems, mainly by the induction of oxidative damage. The aim of this work was to assess cytotoxic and genotoxic effects using the V79 cell line treated with coal and coal fly ash particles derived from a coal power plant located in Santa Catarina, Brazil. Two coal samples (COAL11 and COAL16) and two coal fly ash samples (CFA11 and CFA16) were included in this study. COAL16 was co-firing with a mixture of fuel oil and diesel oil. The comet assay data showed that exposure of V79 cells to coal and coal fly ash particles induced primary DNA lesions. Application of lesion-specific endonucleases (FPG and ENDO III) demonstrated increased DNA effects indicating the presence of high amounts of oxidative DNA lesions. The cytokinesis-block micronucleus cytome assay analysis showed that exposure of V79 cells to high concentrations of coal and coal fly ash particles induced cytotoxic effects (apoptosis and necrosis) and chromosomal instability (nucleoplasmic bridges, nuclear buds, and micronucleus (MN) formation). These results may be associated with compounds contained in the surface of the particles as hazardous elements, ultrafine/nanoparticles, and polycyclic aromatic hydrocarbons (PAHs) which were detected in the samples. Graphical abstract ᅟ.

Study on HOPE Management Mode of Coal Enterprises Based on Systematic Thinking

NASA Astrophysics Data System (ADS)

Zhaoran, Zhang; Tianzhu, Zhang; Wenjing, Tong

2018-02-01

The extensive management mode of coal enterprises is no longer applicable to the demand of enterprise development under the new economic situation. Combined with the characteristics of coal mine production, based on the system of thinking, integration of lean, people, comprehensive, job management theory, formed HOPE management model, including a core system and three support systems and 18 elements. There are three stages in the development and implementation of this model. To 6S site management for the initial stage to job process reengineering for the intermediate stage to post value process control for the advanced stage. The successful implementation of HOPE model in coal enterprises needs comprehensive control from five aspects: lean culture construction, flattening organizational structure, cost control system, performance appraisal system and lean information management platform. HOPE model can be implemented smoothly and make “win-win” between enterprises and employees.

The Safety Attitudes of Senior Managers in the Chinese Coal Industry

PubMed Central

Zhang, Jiangshi; Chen, Na; Fu, Gui; Yan, Mingwei; Kim, Young-Chan

2016-01-01

Introduction: Senior managers’ attitudes towards safety are very important regarding the safety practices in an organization. The study is to describe the current situation of senior managers′ attitudes towards safety in the Chinese coal industry. Method: We evaluated the changing trends as well as the reasons for these changes in the Chinese coal industry in 2009 and in 2014 with 168 senior manager samples from large Chinese state-owned coal enterprises. Evaluations of 15 safety concepts were performed by means of a questionnaire. Results and Conclusions: Results indicate that, in 2014, three concepts were at a very high level (mean > 4.5), and six were at a relatively high level (4.5 > mean > 4.0). Analyses of changing trends revealed that nine concepts improved significantly, while four greatly declined in 2014 compared to those in 2009. The data reported here suggest that the reasons for the significant improvement with respect to the nine concepts include the improvement in social and legal environments, the improvement of the culture of social safety, workers′ safety demands being met, and scientific and technical advances in the coal industry. The decline of the four concepts seemed to be caused by a poor awareness of managers in the coal industry that safety creates economic benefits, insufficient information on safety, inadequate attention to the development of a safety culture and safety management methods, and safety organizations and workers′ unions not playing their role effectively. Practical Applications: We therefore recommend strengthening the evidence that safety creates economic benefits, providing incentives for employees to encourage their participation in safety management, and paying more attention to the prevention of accidents in coal mines via safety organizations and unions. These results can provide guidelines for workers, industrialists, and government regarding occupational safety in the whole coal industry. PMID:27869654

The Safety Attitudes of Senior Managers in the Chinese Coal Industry.

PubMed

Zhang, Jiangshi; Chen, Na; Fu, Gui; Yan, Mingwei; Kim, Young-Chan

2016-11-17

Introduction: Senior managers' attitudes towards safety are very important regarding the safety practices in an organization. The study is to describe the current situation of senior managers' attitudes towards safety in the Chinese coal industry. Method : We evaluated the changing trends as well as the reasons for these changes in the Chinese coal industry in 2009 and in 2014 with 168 senior manager samples from large Chinese state-owned coal enterprises. Evaluations of 15 safety concepts were performed by means of a questionnaire. Results and Conclusions : Results indicate that, in 2014, three concepts were at a very high level (mean > 4.5), and six were at a relatively high level (4.5 > mean > 4.0). Analyses of changing trends revealed that nine concepts improved significantly, while four greatly declined in 2014 compared to those in 2009. The data reported here suggest that the reasons for the significant improvement with respect to the nine concepts include the improvement in social and legal environments, the improvement of the culture of social safety, workers' safety demands being met, and scientific and technical advances in the coal industry. The decline of the four concepts seemed to be caused by a poor awareness of managers in the coal industry that safety creates economic benefits, insufficient information on safety, inadequate attention to the development of a safety culture and safety management methods, and safety organizations and workers' unions not playing their role effectively. Practical Applications : We therefore recommend strengthening the evidence that safety creates economic benefits, providing incentives for employees to encourage their participation in safety management, and paying more attention to the prevention of accidents in coal mines via safety organizations and unions. These results can provide guidelines for workers, industrialists, and government regarding occupational safety in the whole coal industry.

Continuous bench-scale slurry catalyst testing direct coal liquefaction of rawhide sub-bituminous coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bauman, R.F.; Coless, L.A.; Davis, S.M.

In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263.more » Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.« less

Characterization of coal liquids derived from the H-coal process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holmes, S.A.; Woodward, P.W.; Sturm, G.P. Jr.

1976-11-01

Compositional data of coal liquid products derived from the H-Coal process were obtained. Two overhead products (one from the fuel oil mode of operation and the other from the syncrude mode of operation) were prepared by Hydrocarbon Research, Inc. from Illinois No. 6 coal. The compositional data of these products are tabulated, and characteristics of the materials are discussed. Separation and characterization methods, with slight modification, as developed by the Bureau of Mines-API Research Project 60 for characterizing heavy ends of petroleum, were successfully used in analyzing coal liquid distillates within the boiling range 200/sup 0/ to 540/sup 0/C. Distillatesmore » boiling below 200/sup 0/C were separated and analyzed using chromatographic and spectral techniques.« less

Laboratory Scale Coal And Biomass To Drop-In Fuels (CBDF) Production And Assessment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lux, Kenneth; Imam, Tahmina; Chevanan, Nehru

This Final Technical Report describes the work and accomplishments of the project entitled, “Laboratory Scale Coal and Biomass to Drop-In Fuels (CBDF) Production and Assessment.” The main objective of the project was to fabricate and test a lab-scale liquid-fuel production system using coal containing different percentages of biomass such as corn stover and switchgrass at a rate of 2 liters per day. The system utilizes the patented Altex fuel-production technology, which incorporates advanced catalysts developed by Pennsylvania State University. The system was designed, fabricated, tested, and assessed for economic and environmental feasibility relative to competing technologies.

Application of automated image analysis to coal petrography

USGS Publications Warehouse

Chao, E.C.T.; Minkin, J.A.; Thompson, C.L.

1982-01-01

content M. The volume percentage of each component present is indicated by a subscript. For example, a lithologic unit was determined megascopically to have the composition (V)13(I)1(S)1(X1)83(X2)2. After microscopic analysis of the mixed phases, this composition was expressed as (V)13(I)1(S)1(V63E19I14M4)83(V67E11I13M9)2. Finally, these data were combined in a description of the bulk composition as V67E16I13M3S1. An AIAS can also analyze textural characteristics and can be used for quick and reliable determination of rank (reflectance). Our AIAS is completely software based and incorporates a television (TV) camera that has optimum response characteristics in the range of reflectance less than 5%, making it particularly suitable for coal studies. Analysis of the digitized signal from the TV camera is controlled by a microprocessor having a resolution of 64 gray levels between full illumination and dark current. The processed image is reconverted for display on a TV monitor screen, on which selection of phases or features to be analyzed is readily controlled and edited by the operator through use of a lightpen. We expect that automated image analysis, because it can rapidly provide a large amount of pertinent information, will play a major role in the advancement of coal petrography. ?? 1982.

Radioactivity of coals and ash and slag wastes at coal-fired thermal power plants

NASA Astrophysics Data System (ADS)

Krylov, D. A.; Sidorova, G. P.

2013-04-01

This paper presents an analysis of published data on the content of radioactive nuclides in coals originating from various coal deposits, and in ash and slag wastes produced at coal-fired thermal power plants, as well as in fly ash emitted from thermal power plants into the atmosphere. Problems related to the use of coals with an elevated content of natural radionuclides (NRNs) and methods of their solution implemented at the Urtuyskoe coalfield are dealt with. Data on the analysis of Transbaikal coals for the NRN content, as well as weighted mean content of uranium and thorium in coals from the Siberian Region, are given. In order to reduce irradiation of plant personnel and the population of the areas where coal producers and coal-fired thermal power plants are located, it is necessary to organize very careful control of the NRN content in both coals and products of their combustion that are released into the environment. To solve the problem related to the control of radioactivity, the centralized approach and creation of a proper normative base are needed. Experience gained in developing the Urtuyskoe coalfield shows that it is possible to create an efficient system of coal quality control with respect to the radiation hygiene factor and provide protection of the environment and health of the population.

Atmospheric emission of mercury due to combustion of steam coal and domestic coal in China

NASA Astrophysics Data System (ADS)

Wang, Shaobin; Luo, Kunli

2017-08-01

To study the mercury emission due to the combustion of steam coal and domestic coal in China, we analyzed the mercury contents of coal, fly ash, bottom ash and sluicing water in thermal power plants, steam boilers as well as domestic coal-stoves, in Shaanxi, Shanxi, Shandong and Yunnan Provinces. This study conduct an estimate of the Hg emission rates from steam coal and domestic coal combustion based on the method of mass distribution ratio of fly ash and bottom ash. The results show that the Hg emission rate of coal combustion in thermal power plants is about 50.21% (electrostatic precipitators + wet flue gas desulfurization), and that in heating boilers is about 67.23%, and 92.28% in industrial boilers without flue gas desulphurisation equipment. Furthermore, Hg emission rate is 83.61% due to domestic coal combustion in coal-stoves. The Hg emission amount into the atmosphere from power and heat generation, industrial boilers, domestic coal-stoves and spontaneous combustion of coal gangue is roughly estimated to be 133 ± 4, 100 ± 17, 11 ± 0.1 and 47 ± 26 tons in China in 2014, respectively, and the total Hg emission amount from this paper is estimated at 292 tons. The trends of Hg emission in China from 1991 to 2014 show an accelerating growth after 2002. The proportion of mercury emission due to thermal power, heating generation and industrial energy utilization continuously increased. The atmospheric emission of mercury due to combustion of steam coal, domestic coal and coal gangue accounts nearly 50% in total anthropogenic Hg emissions in China, indicating one of the largest sources of Hg emission in China which should draw more public and scientific attention in the future.

Mercury in coal and the impact of coal quality on mercury emissions from combustion systems

USGS Publications Warehouse

Kolker, A.; Senior, C.L.; Quick, J.C.

2006-01-01

The proportion of Hg in coal feedstock that is emitted by stack gases of utility power stations is a complex function of coal chemistry and properties, combustion conditions, and the positioning and type of air pollution control devices employed. Mercury in bituminous coal is found primarily within Fe-sulfides, whereas lower rank coal tends to have a greater proportion of organic-bound Hg. Preparation of bituminous coal to reduce S generally reduces input Hg relative to in-ground concentrations, but the amount of this reduction varies according to the fraction of Hg in sulfides and the efficiency of sulfide removal. The mode of occurrence of Hg in coal does not directly affect the speciation of Hg in the combustion flue gas. However, other constituents in the coal, notably Cl and S, and the combustion characteristics of the coal, influence the species of Hg that are formed in the flue gas and enter air pollution control devices. The formation of gaseous oxidized Hg or particulate-bound Hg occurs post-combustion; these forms of Hg can be in part captured in the air pollution control devices that exist on coal-fired boilers, without modification. For a given coal type, the capture efficiency of Hg by pollution control systems varies according to type of device and the conditions of its deployment. For bituminous coal, on average, more than 60% of Hg in flue gas is captured by fabric filter (FF) and flue-gas desulfurization (FGD) systems. Key variables affecting performance for Hg control include Cl and S content of the coal, the positioning (hot side vs. cold side) of the system, and the amount of unburned C in coal ash. Knowledge of coal quality parameters and their effect on the performance of air pollution control devices allows optimization of Hg capture co-benefit. ?? 2006 Elsevier Ltd. All rights reserved.

Changing patterns of Pennsylvanian coal-swamp vegetation and implications of climatic control on coal occurrence

USGS Publications Warehouse

Phillips, T.L.; Peppers, R.A.

1984-01-01

Improved regional and interregional stratigraphic correlations of Pennsylvanian strata permit comparisons of vegetational changes in Euramerican coal swamps. The coal-swamp vegetation is known directly from in situ coal-ball peat deposits from more than 65 coals in the United States and Europe. Interpretations of coal-swamp floras on the basis of coal-ball peat studies are extended to broader regional and stratigraphic patterns by use of coal palynology. Objectives of the quantitative analyses of the vegetation in relation to coal are to determine the botanical constituents at the peat stage and their environmental implications for plant growth and peat accumulation. Morphological and paleoecological analyses provide a basis for deducing freshwater regimes of coal swamps. Changes in composition of Pennsylvanian coal-swamp vegetation are quire similar from one paralic coal region to another and show synchrony that is attributable to climate. Paleobotany and paleogeography of the Euramerican province indicate a moist tropical paleoclimate. Rainfall, runoff and evapotranspiration were the variable climatic controls in the distribution of coal-swamp vegetation, peat accumulation and coal resources. In relative terms of climatic wetness the Pennsylvanian Period is divisible into five intervals, which include two relatively drier intervals that developed during the Lower-Middle and Middle-Upper Pennsylvanian transitions. The climate during Early Pennsylvanian time was moderately wet and the median in moisture availability. Early Middle Pennsylvanian was drier, probably seasonally dry-wet; late Middle Pennsylvanian was the wettest in the Midcontinent; early Late Pennsylvanian was the driest; and late Late Pennsylvanian was probably the wettest in the Dunkard Basin. The five climatic intervals represent a general means of dividing coal resources within each region into groups with similar botanical constituents and environments of peat accumulation. Regional differences in

Mapping and Prediction of Coal Workers’ Pneumoconiosis with Bioavailable Iron Content in the Bituminous Coals

PubMed Central

Huang, Xi; Li, Weihong; Attfield, Michael D.; Nádas, Arthur; Frenkel, Krystyna; Finkelman, Robert B.

2005-01-01

Based on the first National Study of Coal Workers’ Pneumoconiosis (CWP) and the U.S. Geological Survey database of coal quality, we show that the prevalence of CWP in seven coal mine regions correlates with levels of bioavailable iron (BAI) in the coals from that particular region (correlation coefficient r = 0.94, p < 0.0015). CWP prevalence is also correlated with contents of pyritic sulfur (r = 0.91, p < 0.0048) or total iron (r = 0.85, p < 0.016) but not with coal rank (r = 0.59, p < 0.16) or silica (r = 0.28, p < 0.54). BAI was calculated using our model, taking into account chemical interactions of pyrite, sulfuric acid, calcite, and total iron. That is, iron present in coals can become bioavailable by pyrite oxidation, which produces ferrous sulfate and sulfuric acid. Calcite is the major component in coals that neutralizes the available acid and inhibits iron’s bioavailability. Therefore, levels of BAI in the coals are determined by the available amounts of acid after neutralization of calcite and the amount of total iron in the coals. Using the linear fit of CWP prevalence and the calculated BAI in the seven coal mine regions, we have derived and mapped the pneumoconiotic potencies of 7,000 coal samples. Our studies indicate that levels of BAI in the coals may be used to predict coal’s toxicity, even before large-scale mining. PMID:16079064

[The effects of foot reflexology on fatigue and insomnia in patients suffering from coal workers' pneumoconiosis].

PubMed

Lee, Young-Mee; Sohng, Kyeong-Yae

2005-12-01

The purpose of this study was to determine the effects of foot reflexology on fatigue and insomnia in patients suffering from coal workers' pneumoconiosis. This study was a quasi-experimental study of pre-test and post-test design in a non-equivalent control group. The subjects of this study consisted of both the experimental group of twenty-nine and the control group of thirty coal workers' pneumoconiosis patients. Data was collected from December 10, 2002 to February 15, 2003. Foot reflexology was performed for 60 minutes twice a week through five weeks in the experimental group, but none in the control group. To evaluate the effects of foot reflexology, the scores of fatigue and insomnia were measured before and after the experiment in both groups. Fatigue was evaluated by Fatigue Symptoms Inventory. Insomnia was measured with the visual analogue scale (VAS). Data of this experiment was analyzed by Chi-square test, t-test, unpaired t-test and Repeated Measures ANOVA with the SAS Program. The scores of fatigue and insomnia decreased in the experimental group but not in the control group. There was a significant difference of fatigue and insomnia between the two groups. It is suggested that foot reflexology might have beneficial effects on reducing fatigue and insomnia in patients suffering from coal workers' pneumoconiosis, and can be recommended as a nursing intervention program for patients with coal workers' pneumoconiosis.

Coal-Sizing Auger

NASA Technical Reports Server (NTRS)

Lewis, E. V.

1985-01-01

Aft end of auger, like forward, face-piercing end, equipped with hard cutting bits such as diamonds. As auger breaks face, pulls broken coal lumps into jaws and forces them into hardened throat section. There, cutting bits chew up lumps: Clearance between throat and auger shaft sets maximum size for coal particles that pass through. Auger motion pushes coal particles into mixing chamber, where paddles combine them with water.

Central Appalachia in advanced capitalism: its coal industry structure and coal operator associations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walls, D.S.

1978-01-01

This study traces the origins of the notion that Appalachia constitutes a unique social-problem region, examines the models of Appalachian problems popularized during the 1960s, proposes an alternative framework for situating the Central Appalachian coalfields, and examines aspects of the coal industry's structure in the Central Appalachian region. The idea of Appalachia as a distinctive social problem region was created between 1890 and 1930 by a social movement affiliated with various Protestant church home mission boards and organizationally focused in the Conference of Southern Mountain Workers and Berea College. The movement stressed an environmental explanation of regional problems. During themore » 1960s, three explanatory models of Appalachian poverty and underdevelopment achieved prominence: the subculture of poverty model, the regional development model, and the internal colonialism model. Each contributed to a regionalized conception of Appalachian problems. Empirical studies show the subculture of poverty model to fail as an explanation of regional underdevelopment. In the absence of a critique of domination and a redistribution of power and wealth, the regional development model serves as a rationalization of existing structures of privilege. The internal colonialism model provides a critique of domination, but not the most appropriate one. This study argues that the above models should not be viewed as mutually exclusive formulations, and that they may be reconstructed to represent different dimensions of social existence.« less

Considerations on coal gasification

NASA Technical Reports Server (NTRS)

Franzen, J. E.

1978-01-01

Commercial processes for the gasification of coal with oxygen are discussed. The Koppers-Totzek process for the gasification of coal dust entrained in a stream of gasifying agents is described in particular detail. The outlook for future applications of coal gasification is presented.

Moist caustic leaching of coal

DOEpatents

Nowak, Michael A.

1994-01-01

A process for reducing the sulfur and ash content of coal. Particulate coal is introduced into a closed heated reaction chamber having an inert atmosphere to which is added 50 mole percent NaOH and 50 mole percent KOH moist caustic having a water content in the range of from about 15% by weight to about 35% by weight and in a caustic to coal weight ratio of about 5 to 1. The coal and moist caustic are kept at a temperature of about 300.degree. C. Then, water is added to the coal and caustic mixture to form an aqueous slurry, which is washed with water to remove caustic from the coal and to produce an aqueous caustic solution. Water is evaporated from the aqueous caustic solution until the water is in the range of from about 15% by weight to about 35% by weight and is reintroduced to the closed reaction chamber. Sufficient acid is added to the washed coal slurry to neutralize any remaining caustic present on the coal, which is thereafter dried to produce desulfurized coal having not less than about 90% by weight of the sulfur present in the coal feed removed and having an ash content of less than about 2% by weight.

Quality of Selected Hungarian Coals

USGS Publications Warehouse

Landis, E.R.; Rohrbacher, T.J.; Gluskoter, H.J.; Fodor, B.; Gombar, G.

2007-01-01

As part of a program conducted jointly by the U.S. Geological Survey and the Hungarian Geological Survey under the auspices of the United States-Hungarian Science and Technology Fund, a total of 39 samples from five coal mines in Hungary were selected for analysis. The mine areas sampled represent most of the coal mined recently in Hungary. Almost all the coal is used to generate electricity. Coals from the five mines (four underground, one surface) reflect differences in age, depositional setting, organic and inorganic components of the original sediments, and deformational history. Classified according to the ranking system of the American Society for Testing and Materials, the coals range in rank from lignite B (Pliocene[?] coals) to high volatile A bituminous (Jurassic coals). With respect to grade classification, based on seam-weighted averages of moisture, ash, and sulfur contents: (1) all contain high moisture (more than 10 percent), (2) all except the Eocene coals are high (more than 15 percent) in ash yield, and (3) two (Jurassic and Eocene coals) are high in sulfur (more than 3 percent) and three (Cretaceous, Miocene, and Pliocene coals) have medium sulfur contents (1 to 3 percent). Average heat values range from 4,000 to 8,650 British thermal units per pound.

Mapping of compositional properties of coal using isometric log-ratio transformation and sequential Gaussian simulation - A comparative study for spatial ultimate analyses data.

PubMed

Karacan, C Özgen; Olea, Ricardo A

2018-03-01

Chemical properties of coal largely determine coal handling, processing, beneficiation methods, and design of coal-fired power plants. Furthermore, these properties impact coal strength, coal blending during mining, as well as coal's gas content, which is important for mining safety. In order for these processes and quantitative predictions to be successful, safer, and economically feasible, it is important to determine and map chemical properties of coals accurately in order to infer these properties prior to mining. Ultimate analysis quantifies principal chemical elements in coal. These elements are C, H, N, S, O, and, depending on the basis, ash, and/or moisture. The basis for the data is determined by the condition of the sample at the time of analysis, with an "as-received" basis being the closest to sampling conditions and thus to the in-situ conditions of the coal. The parts determined or calculated as the result of ultimate analyses are compositions, reported in weight percent, and pose the challenges of statistical analyses of compositional data. The treatment of parts using proper compositional methods may be even more important in mapping them, as most mapping methods carry uncertainty due to partial sampling as well. In this work, we map the ultimate analyses parts of the Springfield coal from an Indiana section of the Illinois basin, USA, using sequential Gaussian simulation of isometric log-ratio transformed compositions. We compare the results with those of direct simulations of compositional parts. We also compare the implications of these approaches in calculating other properties using correlations to identify the differences and consequences. Although the study here is for coal, the methods described in the paper are applicable to any situation involving compositional data and its mapping.

Method for fluorinating coal

DOEpatents

Huston, John L.; Scott, Robert G.; Studier, Martin H.

1978-01-01

Coal is fluorinated by contact with fluorine gas at low pressure. After pial fluorination, when the reaction rate has slowed, the pressure is slowly increased until fluorination is complete, forming a solid fluorinated coal of approximate composition CF.sub.1.55 H.sub.0.15. The fluorinated coal and a solid distillate resulting from vacuum pyrolysis of the fluorinated coal are useful as an internal standard for mass spectrometric unit mass assignments from about 100 to over 1500.

Characterization of feed coal and coal combustion products from power plants in Indiana and Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.

1999-07-01

The US Geological Survey, Kentucky Geological Survey, and the University of Kentucky Center for Applied Energy Research are collaborating with Indiana and Kentucky utilities to determine the physical and chemical properties of feed coal and coal combustion products (CCP) from three coal-fired power plants. These three plants are designated as Units K1, K2, and I1 and burn high-, moderate-, and low-sulfur coals, respectively. Over 200 samples of feed coal and CCP were analyzed by various chemical and mineralogical methods to determine mode of occurrence and distribution of trace elements in the CCP. Generally, feed coals from all 3 Units containmore » mostly well-crystallized kaolinite and quartz. Comparatively, Unit K1 feed coals have higher amounts of carbonates, pyrite and sphalerite. Unit K2 feed coals contain higher kaolinite and illite/muscovite when compared to Unit K1 coals. Unit I1 feed coals contain beta-form quartz and alumino-phosphates with minor amounts of calcite, micas, anatase, and zircon when compared to K1 and K2 feed coals. Mineralogy of feed coals indicate that the coal sources for Units K1 and K2 are highly variable, with Unit K1 displaying the greatest mineralogic variability; Unit I1 feed coal however, displayed little mineralogic variation supporting a single source. Similarly, element contents of Units K1 and K2 feed coals show more variability than those of Unit I1. Fly ash samples from Units K1 and K2 consist mostly of glass, mullite, quartz, and spines group minerals. Minor amounts of illite/muscovite, sulfates, hematite, and corundum are also present. Spinel group minerals identified include magnetite, franklinite, magnesioferrite, trevorite, jacobisite, and zincochromite. Scanning Electron Microscope analysis reveals that most of the spinel minerals are dendritic intergrowths within aluminum silicate glass. Unit I1 fly ash samples contain glass, quartz, perovskite, lime, gehlenite, and apatite with minor amounts of periclase

Dry cleaning of Turkish coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cicek, T.

2008-07-01

This study dealt with the upgrading of two different type of Turkish coal by a dry cleaning method using a modified air table. The industrial size air table used in this study is a device for removing stones from agricultural products. This study investigates the technical and economical feasibility of the dry cleaning method which has never been applied before on coals in Turkey. The application of a dry cleaning method on Turkish coals designated for power generation without generating environmental pollution and ensuring a stable coal quality are the main objectives of this study. The size fractions of 5-8,more » 3-5, and 1-3 mm of the investigated coals were used in the upgrading experiments. Satisfactory results were achieved with coal from the Soma region, whereas the upgrading results of Hsamlar coal were objectionable for the coarser size fractions. However, acceptable results were obtained for the size fraction 1-3 mm of Hsamlar coal.« less

Control strategies of atmospheric mercury emissions from coal-fired power plants in China.

PubMed

Tian, Hezhong; Wang, Yan; Cheng, Ke; Qu, Yiping; Hao, Jiming; Xue, Zhigang; Chai, Fahe

2012-05-01

Atmospheric mercury (Hg) emission from coal is one of the primary sources of anthropogenic discharge and pollution. China is one of the few countries in the world whose coal consumption constitutes about 70% of total primary energy, and over half of coals are burned directly for electricity generation. Atmospheric emissions of Hg and its speciation from coal-fired power plants are of great concern owing to their negative impacts on regional human health and ecosystem risks, as well as long-distance transport. In this paper, recent trends of atmospheric Hg emissions and its species split from coal-fired power plants in China during the period of 2000-2007 are evaluated, by integrating each plant's coal consumption and emission factors, which are classified by different subcategories of boilers, particulate matter (PM) and sulfur dioxide (SO2) control devices. Our results show that the total Hg emissions from coal-fired power plants have begun to decrease from the peak value of 139.19 t in 2005 to 134.55 t in 2007, though coal consumption growing steadily from 1213.8 to 1532.4 Mt, which can be mainly attributed to the co-benefit Hg reduction by electrostatic precipitators/fabric filters (ESPs/FFs) and wet flue gas desulfurization (WFGD), especially the sharp growth in installation of WFGD both in the new and existing power plants since 2005. In the coming 12th five-year-plan, more and more plants will be mandated to install De-NO(x) (nitrogen oxides) systems (mainly selective catalytic reduction [SCR] and selective noncatalytic reduction [SNCR]) for minimizing NO(x) emission, thus the specific Hg emission rate per ton of coal will decline further owing to the much higher co-benefit removal efficiency by the combination of SCR + ESPs/FFs + WFGD systems. Consequently, SCR + ESPs/FFs + WFGD configuration will be the main path to abate Hg discharge from coal-fired power plants in China in the near future. However advanced specific Hg removal technologies are necessary

Using ground and intact coal Samples to evaluate hydrocarbon fate during supercritical CO2 injection into coal beds: effects of particle size and coal moisture

USGS Publications Warehouse

Kolak, Jon; Hackley, Paul C.; Ruppert, Leslie F.; Warwick, Peter D.; Burruss, Robert

2015-01-01

To investigate the potential for mobilizing organic compounds from coal beds during geologic carbon dioxide (CO2) storage (sequestration), a series of solvent extractions using dichloromethane (DCM) and using supercritical CO2 (40 °C and 10 MPa) were conducted on a set of coal samples collected from Louisiana and Ohio. The coal samples studied range in rank from lignite A to high volatile A bituminous, and were characterized using proximate, ultimate, organic petrography, and sorption isotherm analyses. Sorption isotherm analyses of gaseous CO2 and methane show a general increase in gas storage capacity with coal rank, consistent with findings from previous studies. In the solvent extractions, both dry, ground coal samples and moist, intact core plug samples were used to evaluate effects of variations in particle size and moisture content. Samples were spiked with perdeuterated surrogate compounds prior to extraction, and extracts were analyzed via gas chromatography–mass spectrometry. The DCM extracts generally contained the highest concentrations of organic compounds, indicating the existence of additional hydrocarbons within the coal matrix that were not mobilized during supercritical CO2 extractions. Concentrations of aliphatic and aromatic compounds measured in supercritical CO2 extracts of core plug samples generally are lower than concentrations in corresponding extracts of dry, ground coal samples, due to differences in particle size and moisture content. Changes in the amount of extracted compounds and in surrogate recovery measured during consecutive supercritical CO2extractions of core plug samples appear to reflect the transition from a water-wet to a CO2-wet system. Changes in coal core plug mass during supercritical CO2 extraction range from 3.4% to 14%, indicating that a substantial portion of coal moisture is retained in the low-rank coal samples. Moisture retention within core plug samples, especially in low-rank coals, appears to inhibit

Coal Extraction - Environmental Prediction

USGS Publications Warehouse

Cecil, C. Blaine; Tewalt, Susan J.

2002-01-01

Coal from the Appalachian region has supplied energy to the Nation for more than 200 years. Appalachian coal fueled America through a civil war and helped win two world wars. Appalachian coal has also provided fuel for keeping America warm in the winter and cool in the summer and has served as the basis for the steel, automobile, organic chemicals, chlorine, and aluminum industries. These benefits have not come without environmental costs, however. Coal extraction and utilization have had significant environmental impacts.

Coal desulfurization by aqueous chlorination

NASA Technical Reports Server (NTRS)

Kalvinskas, J. J.; Vasilakos, N.; Corcoran, W. H.; Grohmann, K.; Rohatgi, N. K. (Inventor)

1982-01-01

A method of desulfurizing coal is described in which chlorine gas is bubbled through an aqueous slurry of coal at low temperature below 130 degrees C., and at ambient pressure. Chlorinolysis converts both inorganic and organic sulfur components of coal into water soluble compounds which enter the aqueous suspending media. The media is separated after chlorinolysis and the coal dechlorinated at a temperature of from 300 C to 500 C to form a non-caking, low-sulfur coal product.

Classification of Structural Coal-Controlling Styles and Analysis on Structural Coal-Controlling Actions

NASA Astrophysics Data System (ADS)

Zhan, Wen-feng

2017-11-01

Tectonism was the primary geologic factors for controlling the formation, deformation, and occurrence of coal measures. As the core of a new round of prediction and evaluation on the coalfield resource potential, the effect of coal-controlling structure was further strengthened and deepened in related researches. By systematically combing the tectonic coal-controlling effect and structure, this study determined the geodynamical classification basis for coal-controlling structures. According to the systematic analysis and summary on the related research results, the coal-controlling structure was categorized into extensional structure, compressive structure, shearing and rotational structure, inverted structure, as well as the sliding structure, syndepositional structure with coalfield structure characteristics. In accordance with the structure combination and distribution characteristics, the six major classes were further classified into 32 subclasses. Moreover, corresponding mode maps were drawn to discuss the basic characteristics and effect of the coal-controlling structures.

7 CFR 1434.6 - Beneficial interest.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 7 Agriculture 10 2013-01-01 2013-01-01 false Beneficial interest. 1434.6 Section 1434.6... REGULATIONS FOR HONEY § 1434.6 Beneficial interest. (a) To be eligible to receive marketing assistance loans under this part a producer must have the beneficial interest in the honey that is tendered to CCC for a...

7 CFR 1434.6 - Beneficial interest.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REGULATIONS FOR HONEY § 1434.6 Beneficial interest. (a) To be eligible to receive marketing assistance loans under this part a producer must have the beneficial interest in the honey that is tendered to CCC for a loan. The producer must always have had the beneficial interest in the honey unless, before the honey...

Evaluation of an enhanced gravity-based fine-coal circuit for high-sulfur coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mohanty, M.K.; Samal, A.R.; Palit, A.

One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m{sup 2}, an enhanced gravity separator having a bowl diameter of 250 mmmore » and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The 'linear screen + enhanced gravity separator + screen-bowl circuit' provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61 %, respectively.« less

Mechanical Coal-Face Fracturer

NASA Technical Reports Server (NTRS)

Collins, E. R., Jr.

1984-01-01

Radial points on proposed drill bit take advantage of natural fracture planes of coal. Radial fracture points retracted during drilling and impacted by piston to fracture coal once drilling halts. Group of bits attached to array of pneumatic drivers to fracture large areas of coal face.

Testing of the 15-inch air-sparged hydrocyclone for fine coal flotation at the Homer City preparation plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, J.D.; Yi, Y.; Gopalakrishnan, S.

1993-12-31

Previous plant testing had been limited to the processing of minus 100 mesh classifier overflow (Upper Freeport Coal {approximately} 20% ash) with the 6-inch air-sparged hydrocyclone (ASH-6C) as reported at Coal Prep 92. The ASH-6C unit was found to provide separation efficiencies equivalent, or superior, to separations with the ASH-2C system. During the summer of 1992 the construction of the first 15-inch air-sparged hydrocyclone prototype was completed by the Advanced Processing Technologies, Inc. Installation at the Homer City Coal Preparation Plant was accomplished and testing began in October 1992. The ASH-15C unit can operate at a flowrate as high asmore » 1,000 gpm. Experimental results are reported with respect to capacity, combustible recovery and clean coal quality.« less

Coal Activities for Secondary Students.

ERIC Educational Resources Information Center

American Coal Foundation, Washington, DC.

This collection of lesson plans designed for teachers of 4th- through 12th-grade students utilizes an assortment of teaching strategies for topics related to coal and the coal industry. Activities cover the following topics: coal formation; coal identification; "the geologist's dilemma" (a supply and demand activity); geologic time and…

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

Improved coal-slurry pipeline

NASA Technical Reports Server (NTRS)

Dowler, W. L.

1979-01-01

High strength steel pipeline carries hot mixture of powdered coal and coal derived oil to electric-power-generating station. Slurry is processed along way to remove sulfur, ash, and nitrogen and to recycle part of oil. System eliminates hazards and limitations associated with anticipated coal/water-slurry pipelines.

Coal supply for California

NASA Technical Reports Server (NTRS)

Yancik, J. J.

1978-01-01

The potential sources and qualities of coals available for major utility and industrial consumers in California are examined and analyzed with respect to those factors that would affect the reliability of supplies. Other considerations, such as the requirements and assurances needed by the coal producers to enter into long-term contracts and dedicate large reserves of coal to these contracts are also discussed. Present and potential future mining contraints on coal mine operators are identified and analyzed with respect to their effect on availability of supply.

Surfactant-Assisted Coal Liquefaction

NASA Technical Reports Server (NTRS)

Hickey, Gregory S.; Sharma, Pramod K.

1993-01-01

Obtaining liquid fuels from coal which are economically competitive with those obtained from petroleum based sources is a significant challenge for the researcher as well as the chemical industry. Presently, the economics of coal liquefaction are not favorable because of relatively intense processing conditions (temperatures of 430 degrees C and pressures of 2200 psig), use of a costly catalyst, and a low quality product slate of relatively high boiling fractions. The economics could be made more favorable by achieving adequate coal conversions at less intense processing conditions and improving the product slate. A study has been carried out to examine the effect of a surfactant in reducing particle agglomeration and improving hydrodynamics in the coal liquefaction reactor to increase coal conversions...

Sulfur compounds in coal

NASA Technical Reports Server (NTRS)

Attar, A.; Corcoran, W. H.

1977-01-01

The literature on the chemical structure of the organic sulfur compounds (or functional groups) in coal is reviewed. Four methods were applied in the literature to study the sulfur compounds in coal: direct spectrometric and chemical analysis, depolymerization in drastic conditions, depolymerization in mild conditions, and studies on simulated coal. The data suggest that most of the organic sulfur in coal is in the form of thiophenic structures and aromatic and aliphatic sulfides. The relative abundance of the sulfur groups in bituminous coal is estimated as 50:30:20%, respectively. The ratio changes during processing and during the chemical analysis. The main effects are the transformation during processing of sulfides to the more stable thiophenic compounds and the elimination of hydrogen sulfide.

Study on dynamic multi-objective approach considering coal and water conflict in large scale coal group

NASA Astrophysics Data System (ADS)

Feng, Qing; Lu, Li

2018-01-01

In the process of coal mining, destruction and pollution of groundwater in has reached an imminent time, and groundwater is not only related to the ecological environment, but also affect the health of human life. Similarly, coal and water conflict is still one of the world's problems in large scale coal mining regions. Based on this, this paper presents a dynamic multi-objective optimization model to deal with the conflict of the coal and water in the coal group with multiple subordinate collieries and arrive at a comprehensive arrangement to achieve environmentally friendly coal mining strategy. Through calculation, this paper draws the output of each subordinate coal mine. And on this basis, we continue to adjust the environmental protection parameters to compare the coal production at different collieries at different stages under different attitude of the government. At last, the paper conclude that, in either case, it is the first arrangement to give priority to the production of low-drainage, high-yield coal mines.

Technoeconomic Assessment of an Advanced Aqueous Ammonia-Based Postcombustion Capture Process Integrated with a 650-MW Coal-Fired Power Station.

PubMed

Li, Kangkang; Yu, Hai; Yan, Shuiping; Feron, Paul; Wardhaugh, Leigh; Tade, Moses

2016-10-04

Using a rigorous, rate-based model and a validated economic model, we investigated the technoeconomic performance of an aqueous NH 3 -based CO 2 capture process integrated with a 650-MW coal-fired power station. First, the baseline NH 3 process was explored with the process design of simultaneous capture of CO 2 and SO 2 to replace the conventional FGD unit. This reduced capital investment of the power station by US$425/kW (a 13.1% reduction). Integration of this NH 3 baseline process with the power station takes the CO 2 -avoided cost advantage over the MEA process (US$67.3/tonne vs US$86.4/tonne). We then investigated process modifications of a two-stage absorption, rich-split configuration and interheating stripping to further advance the NH 3 process. The modified process reduced energy consumption by 31.7 MW/h (20.2% reduction) and capital costs by US$55.4 million (6.7% reduction). As a result, the CO 2 -avoided cost fell to $53.2/tonne: a savings of $14.1 and $21.9/tonne CO 2 compared with the NH 3 baseline and advanced MEA process, respectively. The analysis of energy breakdown and cost distribution indicates that the technoeconomic performance of the NH 3 process still has great potential to be improved.

Coal from the equator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Darling, P.

1995-10-01

In the mid-1970s PT Rio Tinto Indonesia, a wholly owned subsidiary of CRA of Australia, entered into an agreement with BP of the United Kingdom to explore jointly for coal in Indonesia on a 50:50 basis. In 1978, the government of Indonesia invited tenders from foreign companies for the exploration and development of coal resources in eastern and southern Kalimantan (Borneo). The CRA-BP joint venture was successful in bidding for an area of 7,900 km{sup 2} in two blocks extending 300 km along the coast of eastern Kalimantan. In April 1982, PT Kaltim Prima Coal (KPC) entered into an agreementmore » with the Indonesian State Coal Company whereby it could explore, produce, and market coal from the agreed blocks for a period of 30 years. From 1982 to 1986, detailed exploration led to the delineation of several propsects of which the most promising was near the small town of Sangatta, 200 km north of Balikpapan and less than one degree north of the equator. After this exploration period KPC relinquished all but 1,962 km{sup 2} of the original agreement area. In its simplest form, the mining operation can be described as: a series of open pits, coal preparation facilities, 13.7 km of overland conveyor to the coast, and a marine terminal capable of handling bulk carriers of up to 200K dwt. The remote location necessities a fully supportive infrastructure, including a power station, housing, schools, hospitals, water supply, and recreational facilities. In 1994 the mine produced 10M mt coal of which 70% was Prima coal, one of the highest quality internationally traded thermal coals.« less

Drivers for the renaissance of coal

PubMed Central

Steckel, Jan Christoph; Edenhofer, Ottmar; Jakob, Michael

2015-01-01

Coal was central to the industrial revolution, but in the 20th century it increasingly was superseded by oil and gas. However, in recent years coal again has become the predominant source of global carbon emissions. We show that this trend of rapidly increasing coal-based emissions is not restricted to a few individual countries such as China. Rather, we are witnessing a global renaissance of coal majorly driven by poor, fast-growing countries that increasingly rely on coal to satisfy their growing energy demand. The low price of coal relative to gas and oil has played an important role in accelerating coal consumption since the end of the 1990s. In this article, we show that in the increasingly integrated global coal market the availability of a domestic coal resource does not have a statistically significant impact on the use of coal and related emissions. These findings have important implications for climate change mitigation: If future economic growth of poor countries is fueled mainly by coal, ambitious mitigation targets very likely will become infeasible. Building new coal power plant capacities will lead to lock-in effects for the next few decades. If that lock-in is to be avoided, international climate policy must find ways to offer viable alternatives to coal for developing countries. PMID:26150491

Identifying, Planning, and Financing Beneficial Use Projects Using Dredged Material: Beneficial Use Planning Manual

DTIC Science & Technology

2007-10-01

National Risk Management Research Labo- ratory (NRML), National Exposure Research Laboratory (NERL), and National Center for Environmental Assessment ...Clean Water State Revolving Fund CZMA. . .. .. ..Coastal Zone Management Act EA... .. .. .. .. .environmental assessment EIS. . .. .. .. .. .environmental...proponents will in fact be conducting a National Environmental Policy Act assessment of alternatives. Beneficial Use Planning Manual Beneficial Use

Coal combustion system

DOEpatents

Wilkes, Colin; Mongia, Hukam C.; Tramm, Peter C.

1988-01-01

In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

Methane drainage at the Minerales Monclova mines in the Sabinas coal basin, Coahuila, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brunner, D.J.; Ponce, J.R.

Minerales Monclova S.A. De C.V. (MIMOSA) operates five underground longwall mines in the Gassy Los Olmos Coals of the Sabinas Basin in the state of Coahuila in Northern Mexico. Because of high in-situ gas contents and high cleat and natural fracture permeability, MIMOSA has had to incorporate a system of methane drainage in advance of mining in order to safely and cost effectively exploit their reserves. In the early 1990s Resource Enterprises (REI) conducted reservoir characterization tests, numerical simulations, and Coal Mine Methane (CMM) production tests at a nearby mine property in the same basin. Using this information REI approachedmore » MIMOSA and recommended the mine-wide implementation of a degasification system that involves long in-seam directionally drilled boreholes. REI was contracted to conduct the drilling, and to date has drilled over 26,000 m (85,000 ft) of in-seam borehole in advance of mining developments, reducing gas contents significantly below in-situ values. This paper discusses the basis for the degasification program recommended at the MIMOSA mines, and presents the impact of its mine-wide application on MIMOSA's mining operations over the last six years. The paper focuses on the degasification system's impacts on methane emissions into mine workings, coal production, and ventilation demands. It also presents lessons learned by the degasification planners in implementing in-seam methane drainage. The paper presents actual CMM production data, measurements of methane emissions and advance rates at development sections, and mine methane liberations.« less

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Accumulations of methane and coal dust on... Miscellaneous § 75.1709 Accumulations of methane and coal dust on surface coal-handling facilities. [Statutory Provisions] Adequate measures shall be taken to prevent methane and coal dust from accumulating in excessive...

Relationship between Maceral of Coal and Coal-bed Methane adsorption ability in Sihe Coalmine of Qinshui Basin, China

NASA Astrophysics Data System (ADS)

Wang, M. S.; Zou, G. G.; Zhu, R. B.

2018-05-01

Maceral components and its content of coal were divided based on the microscopic characteristics of coal. The Langmuir volume and the Langmuir pressure were tested, and the Langmuir volume represents the adsorption capacity of coal. The formation of coal bed methane is affected by the partition of the maceral components in coal. Therefore, the relationship between maceral composition and coal bed methane adsorption capacity of coal was analyzed. The results show that the maceral components of coal are dominated by vitrinite and inertinite in the study area, and the content of inertinite is below 32%. The vitrinite group has a negative linear correlation with the Langmuir volume, and the inertia composition has a positive linear correlation with it. The cellular structures in the inertinite are the main site of coal bed methane enrichment. The microstructure of coal affects the coalbed methane content and the stage of hydrocarbon generation in coal. This indicates that the microstructure of coal is one of the important factors influencing the adsorption capacity of coal seam.

Coal worker's pneumoconiosis

MedlinePlus

... this page: //medlineplus.gov/ency/article/000130.htm Coal worker's pneumoconiosis To use the sharing features on this page, please enable JavaScript. Coal worker's pneumoconiosis (CWP) is a lung disease that ...

Fluidized coal combustion

NASA Technical Reports Server (NTRS)

Moynihan, P. I.; Young, D. L.

1979-01-01

Fluidized-bed coal combustion process, in which pulverized coal and limestone are burned in presence of forced air, may lead to efficient, reliable boilers with low sulfur dioxide and nitrogen dioxide emissions.

Indonesian coal mining

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

2008-11-15

The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

Illinois Clean Coal Institute 2005 annual report. Final technical report for the period September 1st, 2004, through August 31, 2005 on projects funded by the Illinois Department of Commerce and Economic Opportunity

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

2005-11-08

This final technical report contains the abstracts and executive summaries of projects funded through the Illinois Clean Coal Institute solicitation entitled 'Request for proposals No. 04-1(ICCI/RFP04-1)'. Support of these projects is by the Office of Coal Development and Department of Commerce and Economic Opportunity. The projects fall into the following categories: advanced coal mining technologies; coal preparation and coal production business practice; management of coal combustion byproducts; commercialization and technology transfer. Final project extensions are also recorded.

Leaching behavior of rare earth elements in Fort Union lignite coals of North America

DOE Office of Scientific and Technical Information (OSTI.GOV)

Laudal, Daniel A.; Benson, Steven A.; Addleman, Raymond Shane

Rare earth elements are crucial materials in an incredible array of consumer goods, energy system components and military defense applications. However, the global production and entire value chain for rare earth elements is dominated by China, with the U.S. currently 100% import reliant for these critical materials. Traditional mineral ores including those previously mined in the U.S., however, have several challenges. Chief among these is that the content of the most critical and valuable of the rare earths are deficient, making mining uneconomical. Further, the supply of these most critical rare earths is nearly 100% produced in China from amore » single resource that is only projected to last another 10 to 20 years. The U.S. currently considers the rare earths market an issue of national security. It is imperative that alternative domestic sources of rare earths be identified and methods developed to produce them. Recently, coal and coal byproducts have been identified as one of these promising alternative resources. This paper details the results of a study on characterization of North Dakota lignite and lignite-related feedstocks as an assessment of their feasibility for rare earth element recovery. The abundance, distribution and modes of occurrence of the rare earth elements in the samples collected were determined in this initial study to inform the selection of appropriate extraction and concentration methods to recover the rare earth elements. Materials investigated include the lignite coals, clay-rich sediments associated with the coal seams, and materials associated with a lignite beneficiation system and power plant. The results show that high rare earth element levels exist both in lignite coals and associated sediments. The form of the rare earth elements in the clay materials is primarily as ultra-fine mineral grains. In the lignite coals, approximately 80-95% of the rare earths content is organically associated, primarily as coordination

Coal ash by-product reutilization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muncy, J.; Miller, B.

1997-09-01

Potomac Electric Power Company (PEPCO) has as part of its vision and value statement that, ``We are responsible stewards of environmental and corporate resources.`` With this moral imperative in mind, a project team was charged with initiating the Coal Pile Liner Project--installing a membrane liner under the existing coal storage pile at the Morgantown Generating Station. The existing coal yard facilities were constructed prior to the current environmental regulations, and it became necessary to upgrade the storage facilities to be environmentally friendly. The project team had two objectives in this project: (1) prevent coal pile leachate from entering the groundwatermore » system; (2) test the viability of using coal ash by-products as an aggregate substitute for concrete applications. Both objectives were met, and two additional benefits were achieved as well: (1) the use of coal ash by-products as a coal liner produced significant cost savings to the project directly; (2) the use of coal ash by-products reduced plant operation and maintenance expenses.« less

Applicability of the mixture of bituminous coal and anthracite to conventional pulverized coal firing boiler

DOE Office of Scientific and Technical Information (OSTI.GOV)

Takano, Shin-Ichi; Kiga, Takashi; Miyamae, Shigehiro

1994-12-31

In some future, it is expected for Japanese power stations to be hard to get a high-grade coal like a bituminous coal. We conducted therefore pilot scale tests of pulverized blends of bituminous coal and anthracite using a 1.2MWt tunnel furnace in order to evaluate the applicability of the blends of bituminous coal and anthracite to conventional pulverized coal firing boilers. One kind of bituminous coal and two kinds of anthracite, one was of low ash content and another was of high ash content, were prepared for the test. Previously to pilot scale tests, coal properties and ash properties ofmore » the blends of bituminous coal and anthracite were analyzed to estimate the characteristics of combustion, ash deposition, and so on. In the test, we investigated the combustion efficiency, NOx emission, characteristics of ignition stability and grindability changing the blend rate of anthracite. Results of our study indicated that the critical restrictions on the blending rate of anthracite were unburnt carbon in fly ash and NOx emission as for coals tested. The acceptable limitation on blending rate of anthracite was 10 and 20%, respectively for two kinds of conventional pulverized coal fired boiler. Concerning to the grindability, it became worse with increasing the blending rate of anthracite from grindability test using a roller mill, while it became better estimating from HGI.« less

Cleaning and dewatering fine coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoon, Roe-Hoan; Eraydin, Mert K.; Freeland, Chad

Fine coal is cleaned of its mineral matter impurities and dewatered by mixing the aqueous slurry containing both with a hydrophobic liquid, subjecting the mixture to a phase separation. The resulting hydrophobic liquid phase contains coal particles free of surface moisture and droplets of water stabilized by coal particles, while the aqueous phase contains the mineral matter. By separating the entrained water droplets from the coal particles mechanically, a clean coal product of substantially reduced mineral matter and moisture contents is obtained. The spent hydrophobic liquid is separated from the clean coal product and recycled. The process can also bemore » used to separate one type of hydrophilic particles from another by selectively hydrophobizing one.« less

Chem I Supplement: The Geochemistry of Coal: I. The Classification and Origin of Coal.

ERIC Educational Resources Information Center

Schobert, Harold H.

1989-01-01

Discusses the composition and properties of various types of coal. Follows the origin of coal and amounts available in the ground. Explores the anaerobic decay needed to produce coal. Touches upon the greenhouse effect. (MVL)

The beneficial role of memory reactivation for language learning during sleep: A review.

PubMed

Schreiner, Thomas; Rasch, Björn

2017-04-01

Sleep is essential for diverse aspects of language learning. According to a prominent concept these beneficial effects of sleep rely on spontaneous reactivation processes. A series of recent studies demonstrated that inducing such reactivation processes by re-exposure to memory cues during sleep enhances foreign vocabulary learning. Building upon these findings, the present article reviews recent models and empirical findings concerning the beneficial effects of sleep on language learning. Consequently, the memory function of sleep, its neural underpinnings and the role of the sleeping brain in language learning will be summarized. Finally, we will propose a working model concerning the oscillatory requirements for successful reactivation processes and future research questions to advance our understanding of the role of sleep on language learning and memory processes in general. Copyright © 2016 Elsevier Inc. All rights reserved.

Demonstration of Advanced CO 2 Capture Process Improvements for Coal-Fired Flue Gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carroll, John

This document summarizes the activities of Cooperative Agreement DE-FE0026590, “Demonstration of Advanced CO 2 Capture Process Improvements for Coal-Fired Flue Gas” during the performance period of October 1, 2015 through May 31, 2017. This project was funded by the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL). Southern Company Services, Inc. (SCS) was the prime contractor and co-funder of the project. Mitsubishi Heavy Industries America (MHIA) and AECOM were project team members. The overall project objective was to improve costs, energy requirements, and performance of an existing amine-based CO 2 capture process. This will occur via improvements inmore » three areas: 1. Reboiler design – The first objective of the program was to demonstrate performance of an integrated stripper/reboiler (termed Built-in Reboiler, or BIR) to reduce footprint, capital costs, and integration issues of the current technology. 2. Particulate management – The second objective was to carry out a Particulate Matter Management (PMM) test. This has the potential to reduce operating costs and capital costs due to the reduced or eliminated need for mechanical filtration. 3. Solvent – The third objective was to carry out a new solvent test plan (referred to as NSL) to demonstrate a new solvent (termed New Solvent A), which is expected to reduce regeneration steam. The bulk price is also expected to be lower than KS-1, which is the current solvent used in this process. NSL testing would include baseline testing, optimization, long term testing, solvent reclamation testing, and final inspection. These combine to form the Advanced Carbon Capture (ACC) technology. Much of this work will be applicable to generic solvent processes, especially in regards to improved reboiler design, and focused to meet or exceed the DOE’s overall carbon capture performance goals of 90% CO 2 capture rate with 95% CO 2 purity at a cost of $40/tonne of CO 2 by 2025 and at

Characteristics of coking coal burnout

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakamura, M.; Bailey, J.G.

An attempt was made to clarify the characteristics of coking coal burnout by the morphological analysis of char and fly ash samples. Laboratory-scale combustion testing, simulating an ignition process, was carried out for three kinds of coal (two coking coals and one non-coking coal for reference), and sampled chars were analyzed for size, shape and type by image analysis. The full combustion process was examined in industrial-scale combustion testing for the same kinds of coal. Char sampled at the burner outlet and fly ash at the furnace exit were also analyzed. The difference between the char type, swelling properties, agglomeration,more » anisotropy and carbon burnout were compared at laboratory scale and at industrial scale. As a result, it was found that coking coals produced chars with relatively thicker walls, which mainly impeded char burnout, especially for low volatile coals.« less

Sulfur evolution in chemical looping combustion of coal with MnFe2O4 oxygen carrier.

PubMed

Wang, Baowen; Gao, Chuchang; Wang, Weishu; Zhao, Haibo; Zheng, Chuguang

2014-05-01

Chemical looping combustion (CLC) of coal has gained increasing attention as a novel combustion technology for its advantages in CO2 capture. Sulfur evolution from coal causes great harm from either the CLC operational or environmental perspective. In this research, a combined MnFe2O4 oxygen carrier (OC) was synthesized and its reaction with a typical Chinese high sulfur coal, Liuzhi (LZ) bituminous coal, was performed in a thermogravimetric analyzer (TGA)-Fourier transform infrared (FT-IR) spectrometer. Evolution of sulfur species during reaction of LZ coal with MnFe2O4 OC was systematically investigated through experimental means combined with thermodynamic simulation. TGA-FTIR analysis of the LZ reaction with MnFe2O4 indicated MnFe2O4 exhibited the desired superior reactivity compared to the single reference oxides Mn3O4 or Fe2O3, and SO2 produced was mainly related to oxidization of H2S by MnFe2O4. Experimental analysis of the LZ coal reaction with MnFe2O4, including X-ray diffraction and X-ray photoelectron spectroscopy analysis, verified that the main reduced counterparts of MnFe2O4 were Fe3O4 and MnO, in good agreement with the related thermodynamic simulation. The obtained MnO was beneficial to stabilize the reduced MnFe2O4 and avoid serious sintering, although the oxygen in MnO was not fully utilized. Meanwhile, most sulfur present in LZ coal was converted to solid MnS during LZ reaction with MnFe2O4, which was further oxidized to MnSO4. Finally, the formation of both MnS and such manganese silicates as Mn2SiO4 and MnSiO3 should be addressed to ensure the full regeneration of the reduced MnFe2O4. Copyright © 2014 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

40. BOILER HOUSE, BEGINNING OF COAL CONVEYOR FROM COAL TOWER ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

40. BOILER HOUSE, BEGINNING OF COAL CONVEYOR FROM COAL TOWER No. 1 (FIFTH FLOOR OR CABLE ROAD FLOOR SHOWN IN DRAWING No. 6 OF 13) - Delaware County Electric Company, Chester Station, Delaware River at South end of Ward Street, Chester, Delaware County, PA

Geochemistry of vanadium (V) in Chinese coals.

PubMed

Liu, Yuan; Liu, Guijian; Qu, Qinyuan; Qi, Cuicui; Sun, Ruoyu; Liu, Houqi

2017-10-01

Vanadium in coals may have potential environmental and economic impacts. However, comprehensive knowledge of the geochemistry of V in coals is lacking. In this study, abundances, distribution and modes of occurrence of V are reviewed by compiling >2900 reported Chinese coal samples. With coal reserves in individual provinces as the weighting factors, V in Chinese coals is estimated to have an average abundance of 35.81 μg/g. Large variation of V concentration is observed in Chinese coals of different regions, coal-forming periods, and maturation ranks. According to the concentration coefficient of V in coals from individual provinces, three regions are divided across Chinese coal deposits. Vanadium in Chinese coals is probably influenced by sediment source and sedimentary environment, supplemented by late-stage hydrothermal fluids. Specifically, hydrothermal fluids have relatively more significant effect on the enrichment of V in local coal seams. Vanadium in coals is commonly associated with aluminosilicate minerals and organic matter, and the modes of V occurrence in coal depend on coal-forming environment and coal rank. The Chinese V emission inventory during coal combustion is estimated to be 4906 mt in 2014, accounting for 50.55 % of global emission. Vanadium emissions by electric power plants are the largest contributor.

Formation and retention of methane in coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seamsmore » and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.« less

Process for improving soluble coal yield in a coal deashing process