The fabrication of plastic cages for suspension in mass air flow racks.

PubMed

Nielsen, F H; Bailey, B

1979-08-01

A cage for suspension in mass air flow racks was constructed of plastic and used to house rats. Little or no difficulty was encountered with the mass air flow rack-suspended cage system during the 4 years it was used for the study of trace elements.

The Use of Red Green Blue Air Mass Imagery to Investigate the Role of Stratospheric Air in a Non-Convective Wind Event

NASA Technical Reports Server (NTRS)

Berndt, E. B.; Zavodsky, B. T.; Moltham, A. L.; Folmer, M. J.; Jedlovec, G. J.

2014-01-01

The investigation of non-convective winds associated with passing extratropical cyclones and the formation of the sting jet in North Atlantic cyclones that impact Europe has been gaining interest. Sting jet research has been limited to North Atlantic cyclones that impact Europe because it is known to occur in Shapiro-Keyser cyclones and theory suggests it does not occur in Norwegian type cyclones. The global distribution of sting jet cyclones is unknown and questions remain as to whether cyclones with Shapiro-Keyser characteristics that impact the United States develop features similar to the sting jet. Therefore unique National Aeronautics and Space Administration (NASA) products were used to analyze an event that impacted the Northeast United States on 09 February 2013. Moderate Resolution Imaging Spectroradiometer (MODIS) Red Green Blue (RGB) Air Mass imagery and Atmospheric Infrared Sounder (AIRS) ozone data were used in conjunction with NASA's global Modern Era-Retrospective Analysis for Research and Applications (MERRA) reanalysis and higher-resolution regional 13-km Rapid Refresh (RAP) data to analyze the role of stratospheric air in producing high winds. The RGB Air Mass imagery and a new AIRS ozone anomaly product were used to confirm the presence of stratospheric air. Plan view and cross sectional plots of wind, potential vorticity, relative humidity, omega, and frontogenesis were used to analyze the relationship between stratospheric air and high surface winds during the event. Additionally, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to plot trajectories to determine the role of the conveyor belts in producing the high winds. Analyses of new satellite products, such as the RGB Air Mass imagery, show the utility of future GOES-R products in forecasting non-convective wind events.

A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

NASA Technical Reports Server (NTRS)

Berndt, E. B.; Folmer, Michael; Dunion, Jason

2014-01-01

The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

Mass spectrometer characterization of halogen gases in air at atmospheric pressure.

PubMed

Ivey, Michelle M; Foster, Krishna L

2005-03-01

We have developed a new interface for a commercial ion trap mass spectrometer equipped with APCI capable of real-time measurements of gaseous compounds with limits of detection on the order of pptv. The new interface has been tested using the detection of Br2 and Cl2 over synthetic seawater ice at atmospheric pressure as a model system. A mechanical pump is used to draw gaseous mixtures through a glass manifold into the corona discharge area, where the molecules are ionized. Analysis of bromine and chlorine in dry air show that ion intensity is affected by the pumping rate and the position of the glass manifold. The mass spectrometer signals for Br2 are linear in the 0.1-10.6 ppbv range, and the estimated 3sigma detection limit is 20 pptv. The MS signals for Cl2 are linear in the 0.2-25 ppbv range, and the estimated 3sigma detection limit is 1 ppbv. This new interface advances the field of analytical chemistry by introducing a practical modification to a commercially available ion trap mass spectrometer that expands the available methods for performing highly specific and sensitive measurements of gases in air at atmospheric pressure.

On the origin and destination of atmospheric moisture and air mass over the Tibetan Plateau

NASA Astrophysics Data System (ADS)

Chen, Bin; Xu, Xiang-De; Yang, Shuai; Zhang, Wei

2012-12-01

The Tibet Plateau (TP) is a key region that imposes profound impacts on the atmospheric water cycle and energy budget of Asia, even the global climate. In this work, we develop a climatology of origin (destination) of air mass and moisture transported to (from) the TP using a Lagrangian moisture diagnosis combined with the forward and backward atmospheric tracking schemes. The climatology is derived from 6-h particle positions based on 5-year (2005-2009) seasonal summer trajectory dataset from the Lagrangian particle dispersion model FLEXPART using NCEP/GFS data as input, where the regional model atmosphere was globally filled with particles. The results show that (1) the dominant origin of the moisture supplied to the TP is a narrow tropical-subtropical band in the extended Arabian Sea covering a long distance from the Indian subcontinent to the Southern Hemisphere. Two additional moisture sources are located in the northwestern part of TP and the Bay of Bengal and play a secondary role. This result indicates that the moisture transporting to the TP more depends on the Indian summer monsoon controlled by large-scale circulation. (2) The moisture departing from the TP can be transported rapidly to East Asia, including East China, Korea, Japan, and even East Pacific. The qualitative similarity between the regions of diagnosed moisture loss and the pattern of the observed precipitation highlights the robustness of the role of the TP on precipitation over East Asia. (3) In contrast to the moisture origin confined in the low level, the origin and fate of whole column air mass over the TP is largely controlled by a strong high-level Asian anticyclone. The results show that the TP is a crossroad of air mass where air enters mainly from the northwest and northeast and continues in two separate streams: one goes southwestwards over the Indian Ocean and the other southeastwards through western North Pacific. Both of them partly enter the trade wind zone, which manifests the

Water vapor mass balance method for determining air infiltration rates in houses

Treesearch

David R. DeWalle; Gordon M. Heisler

1980-01-01

A water vapor mass balance technique that includes the use of common humidity-control equipment can be used to determine average air infiltration rates in buildings. Only measurements of the humidity inside and outside the home, the mass of vapor exchanged by a humidifier/dehumidifier, and the volume of interior air space are needed. This method gives results that...

Experimental evaluation of refrigerant mass charge and ambient air temperature effects on performance of air-conditioning systems

NASA Astrophysics Data System (ADS)

Deymi-Dashtebayaz, Mahdi; Farahnak, Mehdi; Moraffa, Mojtaba; Ghalami, Arash; Mohammadi, Nima

2018-03-01

In this paper the effects of refrigerant charge amount and ambient air temperature on performance and thermodynamic condition of refrigerating cycle in the split type air-conditioner have been investigated. Optimum mass charge is the point at which the energy efficiency ratio (EER) of refrigeration cycle becomes the maximum. Experiments have been conducted over a range of refrigerant mass charge from 540 to 840 g and a range of ambient temperature from 27 to 45 °C, in a 12,000 Btu/h split air-conditioner as case study. The various parameters have been considered to evaluate the cooling rate, energy efficiency ratio (EER), mass charge effect and thermodynamic cycle of refrigeration system with R22 refrigerant gas. Results confirmed that the lack of appropriate refrigerant mass charge causes the refrigeration system not to reach its maximum cooling capacity. The highest cooling capacity achieved was 3.2 kW (11,000 Btu/h). The optimum mass charge and corresponding EER of studied system have been obtained about 640 g and 2.5, respectively. Also, it is observed that EER decreases by 30% as ambient temperature increases from 27 °C to 45 °C. By optimization of the refrigerant mass charge in refrigerating systems, about 785 GWh per year of electric energy can be saved in Iran's residential sector.

The mass and speed dependence of meteor air plasma temperatures

NASA Technical Reports Server (NTRS)

Jenniskens, Peter; Laux, Christophe O.; Wilson, Michael A.; Schaller, Emily L.

2004-01-01

The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

The mass and speed dependence of meteor air plasma temperatures.

PubMed

Jenniskens, Peter; Laux, Christophe O; Wilson, Michael A; Schaller, Emily L

2004-01-01

The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

Estimation of air-to-grass mass interception factors for iodine.

PubMed

Karunakara, N; Ujwal, P; Yashodhara, I; Sudeep Kumara, K; Mohan, M P; Bhaskar Shenoy, K; Geetha, P V; Dileep, B N; James, Joshi P; Ravi, P M

2018-06-01

Air-to-grass mass interception factors for radionuclide are important basic input parameter for the estimation of radiation dose to the public around a nuclear power plant. In this paper, we present the determination of air-to- grass mass interception factors for iodine using a 2 m × 2 m × 2 m (l × b × h) size environmental chamber. The temperature, humidity, and rainfall inside the environmental chamber was controlled to required values to simulate different environmental conditions. Grass (Pennisetum purpureum, Schum), grown in pots, was kept inside the environmental chamber and stable iodine in elemental form was sublimed quickly inside the chamber to simulate an accidental release of iodine to the environment. The concentration of iodine in the air was measured periodically by drawing air through a bubbling setup, containing 1% sodium carbonate solution. The mass interception factor for dry deposition varied in the range of 0.25-7.7 m 2  kg -1 with mean value of 2.2 m 2  kg -1 with respect to fresh weight of grass, and that due to wet deposition varied in the range of 0.6-4.8 m 2  kg -1 with mean value of 2.3 m 2  kg -1 . The mass interception factor was inversely correlated with the total iodine deposited through dry deposition as well as with the rainfall. Copyright © 2017. Published by Elsevier Ltd.

122. View in subway showing air filters for unit turbinegenerator ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

122. View in subway showing air filters for unit turbine-generator unit no. 3; looking north. To the left is opening through wall which brings fresh air into the filters; this opening is above the tailrace. Photo by Jet Lowe, HAER, 1989. - Puget Sound Power & Light Company, White River Hydroelectric Project, 600 North River Avenue, Dieringer, Pierce County, WA

Defining Winter and Identifying Synoptic Air Mass Change in the Northeast and Northern Plains U.S. since 1950

NASA Astrophysics Data System (ADS)

Chapman, C. J.; Pennington, D.; Beitscher, M. R.; Godek, M. L.

2017-12-01

Understanding and forecasting the characteristics of winter weather change in the northern U.S. is vital to regional economy, agriculture, tourism and resident life. This is especially true in the Northeast and Northern Plains where substantial changes to the winter season have already been documented in the atmospheric science and biological literature. As there is no single established definition of `winter', this research attempts to identify the winter season in both regions utilizing a synoptic climatological approach with air mass frequencies. The Spatial Synoptic Classification is used to determine the daily air mass/ weather type conditions since 1950 at 40 locations across the two regions. Annual frequencies are first computed as a baseline reference. Then winter air mass frequencies and departures from normal are calculated to define the season along with the statistical significance. Once the synoptic winter is established, long-term regional changes to the season and significance are explored. As evident global changes have occurred after 1975, an Early period of years prior to 1975 and a Late set for all years following this date are compared. Early and Late record synoptic changes are then examined to assess any thermal and moisture condition changes of the regional winter air masses over time. Cold to moderately dry air masses dominate annually in both regions. Northeast winters are also characterized by cold to moderate dry air masses, with coastal locations experiencing more Moist Polar types. The Northern Plains winters are dominated by cold, dry air masses in the east and cold to moderate dry air masses in the west. Prior to 1975, Northeast winters are defined by an increase in cooler and wetter air masses. Dry Tropical air masses only occur in this region after 1975. Northern Plains winters are also characterized by more cold, dry air masses prior to 1975. More Dry Moderate and Moist Moderate air masses have occurred since 1975. These results

Winter air-mass-based synoptic climatological approach and hospital admissions for myocardial infarction in Florence, Italy.

PubMed

Morabito, Marco; Crisci, Alfonso; Grifoni, Daniele; Orlandini, Simone; Cecchi, Lorenzo; Bacci, Laura; Modesti, Pietro Amedeo; Gensini, Gian Franco; Maracchi, Giampiero

2006-09-01

The aim of this study was to evaluate the relationship between the risk of hospital admission for myocardial infarction (MI) and the daily weather conditions during the winters of 1998-2003, according to an air-mass-based synoptic climatological approach. The effects of time lag and 2-day sequences with specific air mass types were also investigated. Studies concerning the relationship between atmospheric conditions and human health need to take into consideration simultaneous effects of many weather variables. At the moment few studies have surveyed these effects on hospitalizations for MI. Analyses were concentrated on winter, when the maximum peak of hospitalization occurred. An objective daily air mass classification by means of statistical analyses based on ground meteorological data was carried out. A comparison between air mass classification and hospital admissions was made by the calculation of a MI admission index, and to detect significant relationships the Mann-Whitney U test, the analysis of variance, and the Bonferroni test were used. Significant increases in hospital admissions for MI were evident 24h after a day characterized by an anticyclonic continental air mass and 6 days after a day characterized by a cyclonic air mass. Increased risk of hospitalization was found even when specific 2-day air mass sequences occurred. These results represent an important step in identifying reliable linkages between weather and health.

CONTROL BUILDING, WEST FRONT SHOWING ENTRANCE Edwards Air Force ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

CONTROL BUILDING, WEST FRONT SHOWING ENTRANCE - Edwards Air Force Base, X-15 Engine Test Complex, Firing Control Building, Rogers Dry Lake, east of runway between North Base & South Base, Boron, Kern County, CA

U.S. Civil Air Show Crashes, 1993 to 2013: Burden, Fatal Risk Factors, and Evaluation of a Risk Index for Aviation Crashes.

PubMed

Ballard, Sarah-Blythe; Osorio, Victor B

2015-01-01

This study provides new public health data about U.S. civil air shows. Risk factors for fatalities in civil air show crashes were analyzed. The value of the FIA score in predicting fatal outcomes was evaluated. With the use of the FAA's General Aviation and Air Taxi Survey and the National Transportation Safety Board's data, the incidence of civil air show crashes from 1993 to 2013 was calculated. Fatality risk factors for crashes were analyzed by means of regression methods. The FIA index was validated to predict fatal outcomes by using the factors of fire, instrument conditions, and away-from-airport location, and was evaluated through receiver operating characteristic (ROC) curves. The civil air show crash rate was 31 crashes per 1,000 civil air events. Of the 174 civil air show crashes that occurred during the study period, 91 (52%) involved at least one fatality; on average, 1.1 people died per fatal crash. Fatalities were associated with four major risk factors: fire [adjusted odds ratio (AOR) = 7.1, 95% confidence interval (CI) = 2.4 to 20.6, P < .001], pilot error (AOR = 5.2, 95% CI = 1.8 to 14.5, P = .002), aerobatic flight (AOR = 3.6, 95% CI = 1.6 to 8.2, P = .002), and off-airport location (AOR = 3.4, 95% CI = 1.5 to 7.5, P = .003). The area under the FIA score's ROC curve was 0.71 (95% CI = 0.64 to 0.78). Civil air show crashes were marked by a high risk of fatal outcomes to pilots in aerobatic performances but rare mass casualties. The FIA score was not a valid measurement of fatal risk in civil air show crashes.

77 FR 40798 - Safety Zone; Nautical City Festival Air Show, Rogers City MI

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-11

...-AA00 Safety Zone; Nautical City Festival Air Show, Rogers City MI AGENCY: Coast Guard, DHS. ACTION...; Nautical City Festival Air Show, Rogers City MI; in the Federal Register (77 FR 29932). We received no... Nautical City Festival will be celebrating Calcite's 100th Anniversary. As part of that celebration, an air...

DNAPL REMOVAL MECHANISMS AND MASS TRANSFER CHARACTERISTICS DURING COSOLVENT-AIR FLOODING

EPA Science Inventory

The concurrent injection of cosolvent and air, a cosolvent-air (CA) flood was recently suggested for a dense nonaqueous phase liquid (DNAPL) remediation technology. The objectives of this study were to elucidate the DNAPL removal mechanisms of the CA flood and to quantify mass t...

77 FR 13522 - Safety Zone; Baltimore Air Show, Patapsco River, Baltimore, MD

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-07

... Register. Background and Purpose The U.S. Navy History & Heritage Command, Office of Commemorations, is... public event will consist of military and civilian aircraft performing low-flying, high-speed precision... Harbor. In addition to the air show dates, military and civilian aircraft performing in the air show will...

On the Influence of Air Mass Origin on Low-Cloud Properties in the Southeast Atlantic

NASA Astrophysics Data System (ADS)

Fuchs, Julia; Cermak, Jan; Andersen, Hendrik; Hollmann, Rainer; Schwarz, Katharina

2017-10-01

This study investigates the impact of air mass origin and dynamics on cloud property changes in the Southeast Atlantic (SEA) during the biomass burning season. The understanding of clouds and their determinants at different scales is important for constraining the Earth's radiative budget and thus prominent in climate system research. In this study, the thermodynamically stable SEA stratocumulus cover is observed not only as the result of local environmental conditions but also as connected to large-scale meteorology by the often neglected but important role of spatial origins of air masses entering this region. In order to assess to what extent cloud properties are impacted by aerosol concentration, air mass history, and meteorology, a Hybrid Single-Particle Lagrangian Integrated Trajectory cluster analysis is conducted linking satellite observations of cloud properties (Spinning-Enhanced Visible and Infrared Imager), information on aerosol species (Monitoring Atmospheric Composition and Climate), and meteorological context (ERA-Interim reanalysis) to air mass clusters. It is found that a characteristic pattern of air mass origins connected to distinct synoptical conditions leads to marked cloud property changes in the southern part of the study area. Long-distance air masses are related to midlatitude weather disturbances that affect the cloud microphysics, especially in the southwestern subdomain of the study area. Changes in cloud effective radius are consistent with a boundary layer deepening and changes in lower tropospheric stability (LTS). In the southeastern subdomain cloud cover is controlled by a generally higher LTS, while air mass origin plays a minor role. This study leads to a better understanding of the dynamical drivers behind observed stratocumulus cloud properties in the SEA and frames potentially interesting conditions for aerosol-cloud interactions.

Aerosol concentration measurements and correlations with air mass trajectories at the Pierre Auger Observatory

NASA Astrophysics Data System (ADS)

Micheletti, M. I.; Louedec, K.; Freire, M.; Vitale, P.; Piacentini, R. D.

2017-06-01

Aerosols play an important role in radiative transfer processes involved in different fields of study. In particular, their influence is crucial in the attenuation of light at astronomical and astrophysical observatories, and has to be taken into account in light transfer models employed to reconstruct the signals. The Andean Argentinean region is increasingly being considered as a good candidate to host such facilities, as well as the ones for solar-energy resources, and an adequate knowledge of aerosols characteristics there is needed, but it is not always possible due to the vast area involved and the scarce atmospheric data at ground. The aim of this work is to find correlations between aerosol data and particle trajectories that can give an insight into the origin and behaviour of aerosols in this zone and can be employed in situations in which one does not have local aerosol measurements. For this purpose, an aerosol spectrometer and dust monitor (Grimm 1.109) was installed at the Pierre Auger Observatory of ultra-high-energy cosmic rays, to record aerosol concentrations in different size intervals, at surface level. These measurements are analysed and correlated with air mass trajectories obtained from HYSPLIT (NOAA) model calculations. High aerosol concentrations are registered predominantly when air masses have travelled mostly over continental areas, mainly from the NE direction, while low aerosol concentrations are found in correspondence with air masses coming from the Pacific Ocean, from the NW direction. Different size distribution patterns were found for the aerosols depending on their origin: marine or continental. This work shows for the first time the size distribution of aerosols registered at the Pierre Auger Observatory. The correlations found between mass and particle concentrations (total and for different size ranges) and HYSPLIT air mass trajectories, confirm that the latter can be employed as a useful tool to infer the sources, evolution

Spatial variability of hailfalls in France: an analysis of air mass retro-trajectories

NASA Astrophysics Data System (ADS)

Hermida, Lucía; Merino, Andrés; Sánchez, José Luis; Berthet, Claude; Dessens, Jean; López, Laura; Fernández-González, Sergio; Gascón, Estíbaliz; García-Ortega, Eduardo

2014-05-01

Hail is the main meteorological risk in south-west France, with the strongest hailfalls being concentrated in just a few days. Specifically, this phenomenon occurs most often and with the greatest severity in the Midi-Pyrénées area. Previous studies have revealed the high spatial variability of hailfall in this part of France, even leading to different characteristics being recorded on hailpads that were relatively close together. For this reason, an analysis of the air mass trajectories was carried out at ground level and at altitude, which subsequently led to the formation of the hail recorded by these hailpads. It is already known that in the study zone, the trajectories of the storms usually stretch for long distances and are oriented towards the east, leading to hailstones with diameters in excess of 3 cm, and without any change in direction above 3 km. We analysed different days with hail precipitation where there was at least one stone with a diameter of 3 cm or larger. Using the simulations from these days, an analysis of the backward trajectories of the air masses was carried out. We used the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) to determine the origin of the air masses, and tracked them toward each of the hailpads that were hit during the day studied. The height of the final points was the height of the impacted hailpads. Similarly, the backward trajectories for different heights were also established. Finally, the results show how storms that affect neighbouring hailpads come from very different air masses; and provide a deeper understanding of the high variability that affects the characteristics of hailfalls. Acknowledgements The authors would like to thank the Regional Government of Castile-León for its financial support through the project LE220A11-2. This study was supported by the following grants: GRANIMETRO (CGL2010-15930); MICROMETEO (IPT-310000-2010-22).

Relationship between air mass type and emergency department visits for migraine headache across the Triangle region of North Carolina

NASA Astrophysics Data System (ADS)

Elcik, Christopher; Fuhrmann, Christopher M.; Mercer, Andrew E.; Davis, Robert E.

2017-12-01

An estimated 240 million people worldwide suffer from migraines. Because migraines are often debilitating, understanding the mechanisms that trigger them is crucial for effective prevention and treatment. Synoptic air mass types and emergency department (ED) visits for migraine headaches were examined over a 7-year period within a major metropolitan area of North Carolina to identify potential relationships between large-scale meteorological conditions and the incidence of migraine headaches. Barometric pressure changes associated with transitional air masses, or changing weather patterns, were also analyzed for potential relationships. Bootstrapping analysis revealed that tropical air masses (moist and dry) resulted in the greatest number of migraine ED visits over the study period, whereas polar air masses led to fewer. Moist polar air masses in particular were found to correspond with the fewest number of migraine ED visits. On transitional air mass days, the number of migraine ED visits fell between those of tropical air mass days and polar air mass days. Transitional days characterized by pressure increases exhibited a greater number of migraine ED visits than days characterized by pressure decreases. However, no relationship was found between migraine ED visits and the magnitude of barometric pressure changes associated with transitional air masses.

77 FR 50019 - Safety Zone; Cocoa Beach Air Show, Atlantic Ocean, Cocoa Beach, FL

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-20

... 1625-AA00 Safety Zone; Cocoa Beach Air Show, Atlantic Ocean, Cocoa Beach, FL AGENCY: Coast Guard, DHS... waters of the Atlantic Ocean located east of Cocoa Beach, Florida during the Cocoa Beach Air Show. The Cocoa Beach Air Show will include aircraft engaging in aerobatic maneuvers. The event is scheduled to...

75 FR 23589 - Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-04

... Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA AGENCY: Coast Guard, DHS... Washington, WA for the annual Seafair Blue Angels Air Show from 10 a.m. on August 5, 2010 to 6 p.m. on August... Washington for the annual Seafair Blue Angels Air Show Performance. The Coast Guard will enforce the safety...

76 FR 34867 - Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-15

... Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA AGENCY: Coast Guard, DHS... Blue Angels Air Show safety zone on Lake Washington, Seattle, WA from 9 a.m. on August 4, 2011 to 4 p.m... Seafair Blue Angels Air Show Performance safety zone in 33 CFR 165.1319 daily from 9 a.m. until 4 p.m...

76 FR 31235 - Safety Zone; Ocean City Air Show, Atlantic Ocean, Ocean City, MD

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-31

...-AA00 Safety Zone; Ocean City Air Show, Atlantic Ocean, Ocean City, MD AGENCY: Coast Guard, DHS. ACTION... in the vicinity of Ocean City, MD to support the Ocean City Air Show. This action is necessary to provide for the safety of life on navigable waters during the Ocean City Air Show. This action is intended...

X-31 Unloading Returning from Paris Air Show

NASA Technical Reports Server (NTRS)

1995-01-01

After being flown in the Paris Air Show in June 1995, the X-31 Enhanced Fighter Maneuverability Technology Demonstrator Aircraft, based at the NASA Dryden Flight Research Center, Edwards Air Force Base, California, is off-loaded from an Air Force Reserve C-5 transport after the ferry flight back to Edwards. At the air show, the X-31 demonstrated the value of using thrust vectoring (directing engine exhaust flow) coupled with advanced flight control systems to provide controlled flight at very high angles of attack. The X-31 Enhanced Fighter Maneuverability (EFM) demonstrator flew at the Ames- Dryden Flight Research Facility, Edwards, California (redesignated the Dryden Flight Research Center in 1994) from February 1992 until 1995 and before that at the Air Force's Plant 42 in Palmdale, California. The goal of the project was to provide design information for the next generation of highly maneuverable fighter aircraft. This program demonstrated the value of using thrust vectoring (directing engine exhaust flow) coupled with an advanced flight control system to provide controlled flight to very high angles of attack. The result was a significant advantage over most conventional fighters in close-in combat situations. The X-31 flight program focused on agile flight within the post-stall regime, producing technical data to give aircraft designers a better understanding of aerodynamics, effectiveness of flight controls and thrust vectoring, and airflow phenomena at high angles of attack. Stall is a condition of an airplane or an airfoil in which lift decreases and drag increases due to the separation of airflow. Thrust vectoring compensates for the loss of control through normal aerodynamic surfaces that occurs during a stall. Post-stall refers to flying beyond the normal stall angle of attack, which in the X-31 was at a 30-degree angle of attack. During Dryden flight testing, the X-31 aircraft established several milestones. On November 6, 1992, the X-31 achieved

On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

NASA Technical Reports Server (NTRS)

Perliski, Lori M.; Solomon, Susan

1993-01-01

The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

Liquid phase mass production of air-stable black phosphorus/phospholipids nanocomposite with ultralow tunneling barrier

NASA Astrophysics Data System (ADS)

Zhang, Qiankun; Liu, Yinan; Lai, Jiawei; Qi, Shaomian; An, Chunhua; Lu, Yao; Duan, Xuexin; Pang, Wei; Zhang, Daihua; Sun, Dong; Chen, Jian-Hao; Liu, Jing

2018-04-01

Few-layer black phosphorus (FLBP), a recently discovered two-dimensional semiconductor, has attracted substantial attention in the scientific and technical communities due to its great potential in electronic and optoelectronic applications. However, reactivity of FLBP flakes with ambient species limits its direct applications. Among various methods to passivate FLBP in ambient environment, nanocomposites mixing FLBP flakes with stable matrix may be one of the most promising approaches for industry applications. Here, we report a simple one-step procedure to mass produce air-stable FLBP/phospholipids nanocomposite in liquid phase. The resultant nanocomposite is found to have ultralow tunneling barrier for charge carriers which can be described by an Efros-Shklovskii variable range hopping mechanism. Devices made from such mass-produced FLBP/phospholipids nanocomposite show highly stable electrical conductivity and opto-electrical response in ambient conditions, indicating its promising applications in both electronic and optoelectronic applications. This method could also be generalized to the mass production of nanocomposites consisting of other air-sensitive 2D materials, such as FeSe, NbSe2, WTe2, etc.

7. INTERIOR VIEW, SHOWING LASER LABORATORY. WrightPatterson Air Force ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. INTERIOR VIEW, SHOWING LASER LABORATORY. - Wright-Patterson Air Force Base, Area B, Building 71A, Propulsion Research Laboratory, Seventh Street between D & G Streets, Dayton, Montgomery County, OH

75 FR 35296 - Safety Zones; 2010 Muskegon Summer Celebration Air Show, Muskegon Lake, Muskegon, MI

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-22

...-AA00 Safety Zones; 2010 Muskegon Summer Celebration Air Show, Muskegon Lake, Muskegon, MI AGENCY: Coast... portions of Muskegon Lake due to the 2010 Muskegon Summer Celebration Air Show. These temporary safety... 2010 Muskegon Summer Celebration Air Show. The Captain of the Port, Sector Lake Michigan, has...

77 FR 44470 - Safety Zone; Seafair Blue Angels Air Show Performance, Seattle, WA

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-30

... 1625-AA00 Safety Zone; Seafair Blue Angels Air Show Performance, Seattle, WA AGENCY: Coast Guard, DHS... the safety hazards associated with the Seafair Blue Angels Air Show Performance which include low... Coast Guard is establishing this rule because the current regulation associated with the Seafair Blue...

Particle growth in an isoprene-rich forest: Influences of urban, wildfire, and biogenic air masses

NASA Astrophysics Data System (ADS)

Gunsch, Matthew J.; Schmidt, Stephanie A.; Gardner, Daniel J.; Bondy, Amy L.; May, Nathaniel W.; Bertman, Steven B.; Pratt, Kerri A.; Ault, Andrew P.

2018-04-01

Growth of freshly nucleated particles is an important source of cloud condensation nuclei (CCN) and has been studied within a variety of environments around the world. However, there remains uncertainty regarding the sources of the precursor gases leading to particle growth, particularly in isoprene-rich forests. In this study, particle growth events were observed from the 14 total events (31% of days) during summer measurements (June 24 - August 2, 2014) at the Program for Research on Oxidants PHotochemistry, Emissions, and Transport (PROPHET) tower within the forested University of Michigan Biological Station located in northern Michigan. Growth events were observed within long-range transported air masses from urban areas, air masses impacted by wildfires, as well as stagnant, forested/regional air masses. Growth events observed during urban-influenced air masses were prevalent, with presumably high oxidant levels, and began midday during periods of high solar radiation. This suggests that increased oxidation of biogenic volatile organic compounds (BVOCs) likely contributed to the highest observed particle growth in this study (8 ± 2 nm h-1). Growth events during wildfire-influenced air masses were observed primarily at night and had slower growth rates (3 ± 1 nm h-1). These events were likely influenced by increased SO2, O3, and NO2 transported within the smoke plumes, suggesting a role of NO3 oxidation in the production of semi-volatile compounds. Forested/regional air mass growth events likely occurred due to the oxidation of regionally emitted BVOCs, including isoprene, monoterpenes, and sesquiterpenes, which facilitated multiday growth events also with slower rates (3 ± 2 nm h-1). Intense sulfur, carbon, and oxygen signals in individual particles down to 20 nm, analyzed by transmission electron microscopy with energy dispersive X-ray spectroscopy (TEM-EDX), suggest that H2SO4 and secondary organic aerosol contributed to particle growth. Overall, aerosol

Influence of power ultrasound application on mass transport and microstructure of orange peel during hot air drying

NASA Astrophysics Data System (ADS)

Ortuño, Carmen; Pérez-Munuera, Isabel; Puig, Ana; Riera, Enrique; Garcia-Perez, J. V.

2010-01-01

Power ultrasound application on convective drying of foodstuffs may be considered an emergent technology. This work deals with the influence of power ultrasound on drying of natural materials addressing the kinetic as well as the product's microstructure. Convective drying kinetics of orange peel slabs (thickness 5.95±0.41 mm) were carried out at 40 ∘C and 1 m/s with (US) and without (AIR) power ultrasound application. A diffusion model considering external resistance to mass transfer was considered to describe drying kinetics. Fresh, US and AIR dried samples were analyzed using Cryo-SEM. Results showed that drying kinetics of orange peel were significantly improved by the application of power ultrasound. From modeling, it was observed a significant (p¡0.05) increase in both mass transfer coefficient and effective moisture diffusivity. The effects on mass transfer properties were confirmed from microestructural observations. In the cuticle surface, the pores were obstructed by wax components scattering, which evidence the ultrasonic effects on the interfaces. The cells of the flavedo were compressed and large intercellular air spaces were generated in the albedo facilitating water transfer through it.

78 FR 31840 - Safety Zone; USO Patriotic Festival Air Show, Atlantic Ocean; Virginia Beach, VA

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-28

...-AA00 Safety Zone; USO Patriotic Festival Air Show, Atlantic Ocean; Virginia Beach, VA AGENCY: Coast... provide for the safety of life on navigable waters during the USO Patriotic Festival Air Show. This action... Patriotic Festival Air Show, Atlantic Ocean; Virginia Beach, VA. (a) Regulated Area. The following area is a...

View of building 11070 showing vents and forced air system ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

View of building 11070 showing vents and forced air system on east side, looking southwest. - Naval Ordnance Test Station Inyokern, China Lake Pilot Plant, Maintenance Shop, C Street, China Lake, Kern County, CA

75 FR 56467 - Safety Zone; Ocean City Beachfront Air Show, Ocean City, NJ

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-16

...-AA00 Safety Zone; Ocean City Beachfront Air Show, Ocean City, NJ AGENCY: Coast Guard, DHS. ACTION... Atlantic Ocean, Ocean City, NJ. The temporary safety zone will restrict vessel traffic from a portion of the Atlantic Ocean during the Ocean City Beachfront Air Show, which is an aerial demonstration to be...

On the relationship between Arctic ice clouds and polluted air masses over the North Slope of Alaska in April 2008

NASA Astrophysics Data System (ADS)

Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

2014-02-01

Recently, two types of ice clouds (TICs) properties have been characterized using the Indirect and Semi-Direct Aerosol Campaign (ISDAC) airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (< 10 L-1) and larger (> 110 μm) ice crystals, and a larger ice supersaturation (> 15%) compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of ice nuclei (IN) through acidification, resulting in a smaller concentration of larger ice crystals and leading to precipitation (e.g., cloud regime TIC-2B). Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from three potential SO2 emission sources into Alaska: eastern China and Siberia where anthropogenic and biomass burning emissions, respectively, are produced, and the volcanic region of the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China and Siberia over Alaska, most probably with the contribution of acidic volcanic aerosol during the TIC-2B period. Observation Monitoring Instrument (OMI) satellite observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results support the hypothesis that acidic coating on IN could be at the origin of the formation of TIC-2B.

19. INTERIOR VIEW INSIDE BUNKER SHOWING NITROGEN TANKS, 'MOBILE AIR ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

19. INTERIOR VIEW INSIDE BUNKER SHOWING NITROGEN TANKS, 'MOBILE AIR MONITOR' EQUIPMENT, MAN. INEL PHOTO NUMBER 65-6183, TAKEN NOVEMBER 10, 1965. - Idaho National Engineering Laboratory, Advanced Reentry Vehicle Fusing System, Scoville, Butte County, ID

78 FR 39594 - Safety Zone; Seafair Blue Angels Air Show Performance, Seattle, WA

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-02

... Zone; Seafair Blue Angels Air Show Performance, Seattle, WA AGENCY: Coast Guard, DHS. ACTION: Notice of enforcement of regulation. SUMMARY: The Coast Guard will enforce the annual Seafair Blue Angels Air Show.... This safety zone is being enforced for the Patriots Jet Team, which will be flying in place of the Blue...

78 FR 32556 - Safety Zone; 2013 Ocean City Air Show, Atlantic Ocean; Ocean City, MD

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-31

...-AA00 Safety Zone; 2013 Ocean City Air Show, Atlantic Ocean; Ocean City, MD AGENCY: Coast Guard, DHS... navigable waters of the Atlantic Ocean in the vicinity of Ocean City, MD to support the Ocean City Air Show... June 9, 2013, Ocean City, MD will host an air show event between Talbot Street and 33rd Street over the...

75 FR 18778 - Safety Zone; Ocean City Air Show 2010, Atlantic Ocean, Ocean City, MD

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-13

...-AA00 Safety Zone; Ocean City Air Show 2010, Atlantic Ocean, Ocean City, MD AGENCY: Coast Guard, DHS... zone on the Atlantic Ocean in the vicinity of Ocean City, Maryland to support the Ocean City Air Show..., 5, and 6, 2010 Ocean City, Maryland will host an air show event on the Atlantic Ocean between Talbot...

77 FR 29932 - Safety Zone; Nautical City Festival Air Show, Rogers City, MI

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-21

...-AA00 Safety Zone; Nautical City Festival Air Show, Rogers City, MI AGENCY: Coast Guard, DHS. ACTION... City Festival will be celebrating Calcite's 100th Anniversary. As part of that celebration, an air show will be launched to the east of the Rogers City marina. The Captain of the Port Sault Sainte Marie has...

4. VENTILATION FAN SHOWING RELATIVE POSITION IN THE AIR TUNNEL. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. VENTILATION FAN SHOWING RELATIVE POSITION IN THE AIR TUNNEL. - Hot Springs National Park, Bathhouse Row, Ozark Bathhouse: Mechanical & Piping Systems, State Highway 7, 1 mile north of U.S. Highway 70, Hot Springs, Garland County, AR

77 FR 49349 - Safety Zone; Chicago Air and Water Show, Lake Michigan, Chicago, IL

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-16

... Zone; Chicago Air and Water Show, Lake Michigan, Chicago, IL AGENCY: Coast Guard, DHS. ACTION... Water Show safety zone on Lake Michigan near Lincoln Park. This action is necessary to accurately reflect the enforcement dates and times for this safety zone due to changes made in this year's air show...

Exposure chamber measurements of mass transfer and partitioning at the plant/air interface.

PubMed

Maddalena, Randy L; McKone, Thomas E; Kado, Norman Y

2002-08-15

Dynamic measures of air and vegetation concentrations in an exposure chamber and a two-box mass balance model are used to quantify factors that control the rate and extent of chemical partitioning between vegetation and the atmosphere. A continuous stirred flow-through exposure chamber was used to investigate the gas-phase transfer of pollutants between air and plants. A probabilistic two-compartment mass balance model of plant/air exchange within the exposure chamber was developed and used with measured concentrations from the chamber to simultaneously evaluate partitioning (Kpa), overall mass transfer across the plant/air interface (Upa), and loss rates in the atmosphere (Ra) and aboveground vegetation (Rp). The approach is demonstrated using mature Capsicum annuum (bell pepper) plants exposed to phenanthrene (PH), anthracene (AN), fluoranthene (FL) and pyrene (PY). Measured values of log Kpa (V[air]/V[fresh plant]) were 5.7, 5.7, 6.0, and 6.2 for PH, AN, FL, and PY, respectively. Values of Upa (m d(-1)) under the conditions of this study ranged from 42 for PH to 119 for FL. After correcting for wall effects, the estimated reaction half-lives in air were 3, 9, and 25 h for AN, FL and PY. Reaction half-lives in the plant compartment were 17, 6, 17, and 5 d for PH, AN, FL, and PY, respectively. The combined use of exposure chamber measurements and models provides a robust tool for simultaneously measuring several different transfer factors that are important for modeling the uptake of pollutants into vegetation.

On the relationship between Arctic ice clouds and polluted air masses over the north slope of Alaska in April 2008

NASA Astrophysics Data System (ADS)

Jouan, C.; Pelon, J.; Girard, E.; Ancellet, G.; Blanchet, J. P.; Delanoë, J.

2013-02-01

Recently, two Types of Ice Clouds (TICs) properties have been characterized using ISDAC airborne measurements (Alaska, April 2008). TIC-2B were characterized by fewer (<10 L-1) and larger (>110 μm) ice crystals, a larger ice supersaturation (>15%) and a fewer ice nuclei (IN) concentration (<2 order of magnitude) when compared to TIC-1/2A. It has been hypothesized that emissions of SO2 may reduce the ice nucleating properties of IN through acidification, resulting to a smaller concentration of larger ice crystals and leading to precipitation (e.g. cloud regime TIC-2B) because of the reduced competition for the same available moisture. Here, the origin of air masses forming the ISDAC TIC-1/2A (1 April 2008) and TIC-2B (15 April 2008) is investigated using trajectory tools and satellite data. Results show that the synoptic conditions favor air masses transport from the three potentials SO2 emission areas to Alaska: eastern China and Siberia where anthropogenic and biomass burning emission respectively are produced and the volcanic region from the Kamchatka/Aleutians. Weather conditions allow the accumulation of pollutants from eastern China/Siberia over Alaska, most probably with the contribution of acid volcanic aerosol during the TIC-2B period. OMI observations reveal that SO2 concentrations in air masses forming the TIC-2B were larger than in air masses forming the TIC-1/2A. Airborne measurements show high acidity near the TIC-2B flight where humidity was low. These results strongly support the hypothesis that acidic coating on IN are at the origin of the formation of TIC-2B.

Seasonal and air mass trajectory effects on dissolved organic matter of bulk deposition at a coastal town in south-western Europe.

PubMed

Santos, Patrícia S M; Santos, Eduarda B H; Duarte, Armando C

2013-01-01

Rainwater contains a complex mixture of organic compounds which may influence climate, terrestrial and maritime ecosystems and thus human health. In this work, the characteristics of DOM of bulk deposition at a coastal town on the southwest of Europe were assessed by UV-visible and three-dimensional excitation-emission matrix fluorescence spectroscopies and by dissolved organic carbon (DOC) content. The seasonal and air mass trajectory effects on dissolved organic matter (DOM) of bulk deposition were evaluated. The absorbance at 250 nm (UV(250 nm)) and integrated fluorescence showed to be positively correlated with each other, and they were also positively correlated to the DOC in bulk deposition, which suggest that a constant fraction of DOM is likely to fluoresce. There was more chromophoric dissolved organic matter (CDOM) present in summer and autumn seasons than in winter and spring. Bulk deposition associated with terrestrial air masses contained a higher CDOM content than bulk deposition related to marine air masses, thus highlighting the contribution of terrestrial/anthropogenic sources.

Atmospheric pollutants in Chiang Mai (Thailand) over a five-year period (2005-2009), their possible sources and relation to air mass movement

NASA Astrophysics Data System (ADS)

Chantara, Somporn; Sillapapiromsuk, Sopittaporn; Wiriya, Wan

2012-12-01

Monitoring and analysis of the chemical composition of air pollutants were conducted over a five-year period (2005-2009) in the sub-urban area of Chiang Mai, Thailand. This study aims to determine the seasonal variation of atmospheric ion species and gases, examine their correlations, identify possible sources and assess major air-flow patterns to the receptor. The dominant gas and particulate pollutants were NH3 (43-58%) and SO42- (39-48%), respectively. The annual mean concentrations of NH3 (μg m-3) in descending order were 4.08 (2009) > 3.32 (2007) > 2.68 (2008) > 2.47 (2006) and 1.87 (2005), while those of SO42- (μg m-3) were 2.60 (2007) > 2.20 (2006) > 1.95 (2009) > 1.75 (2008) and 1.26 (2005). Concentrations of particulate ions were analyzed by principle component analysis to find out the possible sources of air pollutants in this area. The first component of each year had a high loading of SO42- and NH4+, which probably came from fuel combustion and agricultural activity, respectively. K+, a tracer of biomass burning, also contributed to the first or the second components of each year. Concentrations of NH4+ and SO42- were well correlated (r > 0.777, p < 0.01), which lead to the conclusion that (NH4)2SO4 was a major compound present in this area. The 3-day backward trajectories of air mass arriving at Chiang Mai from 2005 to 2009 were analyzed using the hybrid single particle langrangian integrated trajectory (HYSPLIT) model and grouped by cluster analysis. The air mass data was analyzed for the dry season (n = 18; 100%). The trajectory of air mass in 2005 mainly originated locally (67%). In 2006, the recorded data showed that 56% of air mass was emitted from the western continental region of Thailand. In 2007, the percent ratios from the western and eastern continental areas were equal (39%). In 2008, 67% originated from the western continental area. In 2009, the recorded air mass mainly came from the western continental area (72%). In conclusion, the

Detail of interior of compressed air chamber showing top of ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Detail of interior of compressed air chamber showing top of working chamber and tie rods that strengthen the outer shell plates of the compression chamber. - Sub Marine Explorer, Located along the beach of Isla San Telmo, Pearl Islands, Isla San Telmo, Former Panama Canal Zone, CZ

76 FR 29647 - Safety Zone; Big Rock Blue Marlin Air Show; Bogue Sound, Morehead City, NC

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-23

...-AA00 Safety Zone; Big Rock Blue Marlin Air Show; Bogue Sound, Morehead City, NC AGENCY: Coast Guard... for the ``Big Rock Blue Marlin Air Show,'' an aerial demonstration to be held over the waters of Bogue... notice of proposed rulemaking (NPRM) entitled Safety Zone; Big Rock Blue Marlin Air Show; Bogue Sound...

Markers for Chinese and Korean Air Masses: Halocarbons and Other Trace Gases Measured During KORUS-AQ

NASA Astrophysics Data System (ADS)

Blake, N. J.; Blake, D. R.; Meinardi, S.; Simpson, I. J.; Hughes, S.; Barletta, B.; Fleming, L.; Vizenor, N.; Schroeder, J.; Emmons, L. K.; Knote, C. J.

2017-12-01

The UC-Irvine Whole Air Sampler (WAS) collected a total of 2650 samples aboard the NASA DC-8 aircraft in support of the May-June 2016 field deployment phase of the KORUS-AQ mission: An International Cooperative Air Quality Field Study in Korea. Here we employ our trace gas measurements, along with CAM-chem tracers and back-trajectories to identify source regions during KORUS-AQ, with a focus on air masses which indicate Chinese and/or Korean origin. During KORUS-AQ we flew mostly over and around the Korean Peninsula with the intent of characterising Korean sources, but Chinese influence was observed offshore near the surface of the West Sea during several KORUS-AQ flights - in accord with forecast predictions from CAM-chem model runs. Unlike previous missions in the Asian region such as TRACE-P (2001), we found that halon-1211 (H-1211) is no longer a useful indicator of air masses from China because of production decline. By contrast, mixing ratios of the long-lived halocarbons carbon tetrachloride (CCl4) and chlorofluorocarbon-113 (CFC-113) were more strongly enhanced in air masses intercepted from China compared to Korea. We will use these tracers, the shorter-lived halocarbons, dichloromethane (CH2Cl2) and methyl chloride (CH3Cl), as well as the sulfur gas carbonyl sulfide (COS) and others, to characterize different regional air mass origins and their sources.

Influence of relative air/water flow velocity on oxygen mass transfer in gravity sewers.

PubMed

Carrera, Lucie; Springer, Fanny; Lipeme-Kouyi, Gislain; Buffiere, Pierre

2017-04-01

Problems related to hydrogen sulfide may be serious for both network stakeholders and the public in terms of health, sustainability of the sewer structure and urban comfort. H 2 S emission models are generally theoretical and simplified in terms of environmental conditions. Although air transport characteristics in sewers must play a role in the fate of hydrogen sulfide, only a limited number of studies have investigated this issue. The aim of this study was to better understand H 2 S liquid to gas transfer by highlighting the link between the mass transfer coefficient and the turbulence in the air flow and the water flow. For experimental safety reasons, O 2 was taken as a model compound. The oxygen mass transfer coefficients were obtained using a mass balance in plug flow. The mass transfer coefficient was not impacted by the range of the interface air-flow velocity values tested (0.55-2.28 m·s -1 ) or the water velocity values (0.06-0.55 m·s -1 ). Using the ratio between k L,O 2 to k L,H 2 S , the H 2 S mass transfer behavior in a gravity pipe in the same hydraulic conditions can be predicted.

Origin of atmospheric aerosols at the Pierre Auger Observatory using studies of air mass trajectories in South America

NASA Astrophysics Data System (ADS)

Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; Pȩkala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcău, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Curci, G.

2014-11-01

The Pierre Auger Observatory is making significant contributions towards understanding the nature and origin of ultra-high energy cosmic rays. One of its main challenges is the monitoring of the atmosphere, both in terms of its state variables and its optical properties. The aim of this work is to analyse aerosol optical depth τa(z) values measured from 2004 to 2012 at the observatory, which is located in a remote and relatively unstudied area of Pampa Amarilla, Argentina. The aerosol optical depth is in average quite low - annual mean τa(3.5 km) ∼ 0.04 - and shows a seasonal trend with a winter minimum - τa(3.5 km) ∼ 0.03 -, and a summer maximum - τa(3.5 km) ∼ 0.06 -, and an unexpected increase from August to September - τa(3.5 km) ∼ 0.055. We computed backward trajectories for the years 2005 to 2012 to interpret the air mass origin. Winter nights with low aerosol concentrations show air masses originating from the Pacific Ocean. Average concentrations are affected by continental sources (wind-blown dust and urban pollution), whilst the peak observed in September and October could be linked to biomass burning in the northern part of Argentina or air pollution coming from surrounding urban areas.

75 FR 57857 - Safety Zone; Blue Angels at Kaneohe Bay Air Show, Oahu, HI

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-23

... DEPARTMENT OF HOMELAND SECURITY Coast Guard 33 CFR Part 165 [Docket No. USCG-2010-0705] RIN 1625-AA00 Safety Zone; Blue Angels at Kaneohe Bay Air Show, Oahu, HI AGENCY: Coast Guard, DHS. ACTION...; Blue Angels at Kaneohe Bay Air Show, Oahu, HI in the Federal Register (75 FR 159). We received no...

75 FR 32664 - Safety Zone; Milwaukee Air and Water Show, Lake Michigan, Milwaukee, WI

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-09

.... ACTION: Temporary final rule. SUMMARY: The Coast Guard is establishing a safety zone on Lake Michigan... of Lake Michigan due to a large-scale air show and a fireworks display. This temporary safety zone is... air show and fireworks display. DATES: This regulation is effective from 12:01 a.m. on June 10, 2010...

Measurement of the oxygen mass transfer through the air-water interface.

PubMed

Mölder, Erik; Mashirin, Alelxei; Tenno, Toomas

2005-01-01

Gas mass transfer through the liquid-gas interface has enormous importance in various natural and industrial processes. Surfactants or insoluble compounds adsorbed onto an interface will inhibit the gas mass transfer through the liquid-gas surface. This study presents a technique for measuring the oxygen mass transfer through the air-water interface. Experimental data obtained with the measuring device were incorporated into a novel mathematical model, which allowed one to calculate diffusion conduction of liquid surface layer and oxygen mass transfer coefficient in the liquid surface layer. A special measurement cell was constructed. The most important part of the measurement cell is a chamber containing the electrochemical oxygen sensor inside it. Gas exchange between the volume of the chamber and the external environment takes place only through the investigated surface layer. Investigated liquid was deoxygenated, which triggers the oxygen mass transfer from the chamber through the liquid-air interface into the liquid phase. The decrease of oxygen concentration in the cell during time was measured. By using this data it is possible to calculate diffusional parameters of the water surface layer. Diffusion conduction of oxygen through the air-water surface layer of selected wastewaters was measured. The diffusion conduction of different wastewaters was about 3 to 6 times less than in the unpolluted water surface. It was observed that the dilution of wastewater does not have a significant impact on the oxygen diffusion conduction through the wastewater surface layer. This fact can be explained with the presence of the compounds with high surface activity in the wastewater. Surfactants achieved a maximum adsorption and, accordingly, the maximum decrease of oxygen permeability already at a very low concentration of surfactants in the solution. Oxygen mass transfer coefficient of the surface layer of the water is found to be Ds/ls = 0.13 x 10(-3) x cm/s. A simple

Measurement of the mass energy-absorption coefficient of air for x-rays in the range from 3 to 60 keV.

PubMed

Buhr, H; Büermann, L; Gerlach, M; Krumrey, M; Rabus, H

2012-12-21

For the first time the absolute photon mass energy-absorption coefficient of air in the energy range of 10 to 60 keV has been measured with relative standard uncertainties below 1%, considerably smaller than those of up to 2% assumed for calculated data. For monochromatized synchrotron radiation from the electron storage ring BESSY II both the radiant power and the fraction of power deposited in dry air were measured using a cryogenic electrical substitution radiometer and a free air ionization chamber, respectively. The measured absorption coefficients were compared with state-of-the art calculations and showed an average deviation of 2% from calculations by Seltzer. However, they agree within 1% with data calculated earlier by Hubbell. In the course of this work, an improvement of the data analysis of a previous experimental determination of the mass energy-absorption coefficient of air in the range of 3 to 10 keV was found to be possible and corrected values of this preceding study are given.

An Air Mass Based Approach to the Establishment of Spring Season Synoptic Characteristics in the Northeast United States

NASA Astrophysics Data System (ADS)

Zander, R.; Messina, A.; Godek, M. L.

2012-12-01

The spring season is indicative of marked meteorological, ecological, and biological changes across the Northeast United States. The onset of spring coincides with distinct meteorological phenomena including an increase in severe weather events and snow meltwaters that can cause localized flooding and other costly damages. Increasing and variable springtime temperatures also influence Northeast tourist operations and agricultural productivity. Even with the vested interest of industry in the season and public awareness of the dynamic characteristics of spring, the definition of spring remains somewhat arbitrary. The primary goal of this research is to obtain a synoptic meteorological definition of the spring season through an assessment of air mass frequency over the past 60 years. A secondary goal examines the validity of recent speculations that the onset and termination of spring has changed in recent decades, particularly since 1975. The Spatial Synoptic Classification is utilized to define daily air masses over the region. Annual and seasonal baseline frequencies are identified and their differences are acquired to characterize the season. Seasonal frequency departures of the early and late segments of the period of record around 1975 are calculated and examined for practical and statistical significance. The daily boundaries of early and late spring are then isolated and frequencies are obtained for these periods. Boundary frequencies are assessed across the period of record to identify important changes in the season's initiation and termination through time. Results indicate that the Northeast spring season is dominated by dry air masses, mainly the Dry Moderate and Dry Polar types. Significant differences in seasonal air mass frequency are also observed through time. Prior to 1975, higher frequencies of polar air mass types are detected while after 1975 there is an increase in the frequencies of both moderate and tropical types. This finding is also

Characterising terrestrial influences on Antarctic air masses using Radon-222 measurements at King George Island

NASA Astrophysics Data System (ADS)

Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

2014-09-01

We report on one year of high-precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late-summer to 44 mBq m-3 in late winter and early spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

Characterising terrestrial influences on Antarctic air masses using radon-222 measurements at King George Island

NASA Astrophysics Data System (ADS)

Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

2014-05-01

We report on one year of high precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late summer to 44 mBq m-3 in late-winter and early-spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

Transport Regimes of Air Masses Affecting the Tropospheric Composition of the Canadian and European Arctic During RACEPAC 2014 and NETCARE 2014/2015

NASA Astrophysics Data System (ADS)

Bozem, H.; Hoor, P. M.; Koellner, F.; Kunkel, D.; Schneider, J.; Schulz, C.; Herber, A. B.; Borrmann, S.; Wendisch, M.; Ehrlich, A.; Leaitch, W. R.; Willis, M. D.; Burkart, J.; Thomas, J. L.; Abbatt, J.

2015-12-01

The Arctic is warming much faster than any other place in the world and undergoes a rapid change dominated by a changing climate in this region. The impact of polluted air masses traveling to the Arctic from various remote sources significantly contributes to the observed climate change, in contrast there are additional local emission sources contributing to the level of pollutants (trace gases and aerosol). Processes affecting the emission and transport of these pollutants are not well understood and need to be further investigated. We present aircraft based trace gas measurements in the Arctic during RACEPAC (2014) and NETCARE (2014 and 2015) with the Polar 6 aircraft of Alfred Wegener Institute (AWI) covering an area from 134°W to 17°W and 68°N to 83°N. We focus on cloud, aerosol and general transport processes of polluted air masses into the high Arctic. Based on CO and CO2 measurements and kinematic 10-day back trajectories we analyze the transport regimes prevalent during spring (RACEPAC 2014 and NETCARE 2015) and summer (NETCARE 2014) in the observed region. Whereas the eastern part of the Canadian Arctic is affected by air masses with their origin in Asia, in the central and western parts of the Canadian and European Arctic air masses from North America are predominant at the time of the measurement. In general the more northern parts of the Arctic were relatively unaffected by pollution from mid-latitudes since air masses mostly travel within the polar dome, being quite isolated. Associated mixing ratios of CO and CO2 fit into the seasonal cycle observed at NOAA ground stations throughout the Arctic, but show a more mid-latitudinal characteristic at higher altitudes. The transition is remarkably sharp and allows for a chemical definition of the polar dome. At low altitudes, synoptic disturbances transport polluted air masses from mid-latitudes into regions of the polar dome. These air masses contribute to the Arctic pollution background, but also

NASA AIRS Movies Show Evolution of U.S. 2011 Heat Wave

NASA Image and Video Library

2011-07-26

NASA Aqua spacecraft has illustrated surface air and skin temperature for the period from July 16-24, showing movement of a dome of heat across the eastern two-thirds of the country. See More Details for the movies.

Seasonal air and water mass redistribution effects on LAGEOS and Starlette

NASA Technical Reports Server (NTRS)

Gutierrez, Roberto; Wilson, Clark R.

1987-01-01

Zonal geopotential coefficients have been computed from average seasonal variations in global air and water mass distribution. These coefficients are used to predict the seasonal variations of LAGEOS' and Starlette's orbital node, the node residual, and the seasonal variation in the 3rd degree zonal coefficient for Starlette. A comparison of these predictions with the observed values indicates that air pressure and, to a lesser extent, water storage may be responsible for a large portion of the currently unmodeled variation in the earth's gravity field.

Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger

NASA Astrophysics Data System (ADS)

Dugaria, S.; Moro, L.; Del, D., Col

2015-11-01

The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.

17. ROOM 32, SHOWING THE ORIGINAL LOCATION OF THE MASS ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

17. ROOM 32, SHOWING THE ORIGINAL LOCATION OF THE MASS SPECTROMETER AND EXTRACTION LINES, LOOKING SOUTH. - U.S. Geological Survey, Rock Magnetics Laboratory, 345 Middlefield Road, Menlo Park, San Mateo County, CA

Characterization of key aerosol, trace gas and meteorological properties and particle formation and growth processes dependent on air mass origins in coastal Southern Spain

NASA Astrophysics Data System (ADS)

Diesch, J.; Drewnick, F.; Sinha, V.; Williams, J.; Borrmann, S.

2011-12-01

acid was found to be the main particle formation contributor. The AMS analysis showed inorganic sulfate species being substantially higher during the growth stages of urban compared to continentally influenced events that are characterized by lower PM1 mass concentrations mainly composed of oxidized organics. The lowest average PM1 mass and number concentrations (2 μg m-3, 1000 cm-3) were found in marine air mass types characterized by the highest sulfate PM1-fraction (54%, 0.91 μg m-3) and volume size distributions probably dominated by sodium chloride particles from sea spray. Two to five times higher submicron aerosol mass concentrations were observed in continental (2.5 μg m-3) and urban (4.2 μg m-3) air mass types mainly consisting of organic species that were further evaluated using Positive Matrix Factorization (PMF). Zhang, Q. et al. (2004), Environ. Sci. Technol., 38, 4797-4809.

Photochemical aging of aerosol particles in different air masses arriving at Baengnyeong Island, Korea

NASA Astrophysics Data System (ADS)

Kang, Eunha; Lee, Meehye; Brune, William H.; Lee, Taehyoung; Park, Taehyun; Ahn, Joonyoung; Shang, Xiaona

2018-05-01

Atmospheric aerosol particles are a serious health risk, especially in regions like East Asia. We investigated the photochemical aging of ambient aerosols using a potential aerosol mass (PAM) reactor at Baengnyeong Island in the Yellow Sea during 4-12 August 2011. The size distributions and chemical compositions of aerosol particles were measured alternately every 6 min from the ambient air or through the highly oxidizing environment of a potential aerosol mass (PAM) reactor. Particle size and chemical composition were measured by using the combination of a scanning mobility particle sizer (SMPS) and a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). Inside the PAM reactor, O3 and OH levels were equivalent to 4.6 days of integrated OH exposure at typical atmospheric conditions. Two types of air masses were distinguished on the basis of the chemical composition and the degree of aging: air transported from China, which was more aged with a higher sulfate concentration and O : C ratio, and the air transported across the Korean Peninsula, which was less aged with more organics than sulfate and a lower O : C ratio. For both episodes, the particulate sulfate mass concentration increased in the 200-400 nm size range when sampled through the PAM reactor. A decrease in organics was responsible for the loss of mass concentration in 100-200 nm particles when sampled through the PAM reactor for the organics-dominated episode. This loss was especially evident for the m/z 43 component, which represents less oxidized organics. The m/z 44 component, which represents further oxidized organics, increased with a shift toward larger sizes for both episodes. It is not possible to quantify the maximum possible organic mass concentration for either episode because only one OH exposure of 4.6 days was used, but it is clear that SO2 was a primary precursor of secondary aerosol in northeast Asia, especially during long-range transport from China. In addition

33 CFR 165.1319 - Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA. 165.1319 Section 165.1319 Navigation and Navigable... Thirteenth Coast Guard District § 165.1319 Safety Zone Regulations, Seafair Blue Angels Air Show Performance...

33 CFR 165.1319 - Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA. 165.1319 Section 165.1319 Navigation and Navigable... Thirteenth Coast Guard District § 165.1319 Safety Zone Regulations, Seafair Blue Angels Air Show Performance...

33 CFR 165.1319 - Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA. 165.1319 Section 165.1319 Navigation and Navigable... Thirteenth Coast Guard District § 165.1319 Safety Zone Regulations, Seafair Blue Angels Air Show Performance...

33 CFR 165.1319 - Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA. 165.1319 Section 165.1319 Navigation and Navigable... Thirteenth Coast Guard District § 165.1319 Safety Zone Regulations, Seafair Blue Angels Air Show Performance...

Establishing Lagrangian Connections between Observations within Air Masses Crossing the Atlantic during the ICARTT Experiment

NASA Technical Reports Server (NTRS)

Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D.; Reeves, C.;

Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall

PubMed Central

Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

2014-01-01

Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005–2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination. PMID:24722630

Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall.

PubMed

Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

2014-11-01

Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005-2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination.

78 FR 48315 - Safety Zone; North Hero Air Show; North Hero, VT

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-08

... FR Federal Register NPRM Notice of Proposed Rulemaking A. Regulatory History and Information The... During this air show there will be low flying planes conducting aerobatic maneuvers east of North Hero...

77 FR 22523 - Safety Zone; 2012 Ocean City Air Show; Atlantic Ocean, Ocean City, MD

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-16

...-AA00 Safety Zone; 2012 Ocean City Air Show; Atlantic Ocean, Ocean City, MD AGENCY: Coast Guard, DHS... the navigable waters of the Atlantic Ocean in Ocean City, MD. This action is necessary to provide for the safety of life on navigable waters during the 2012 Ocean City Air Show. This action is intended to...

Enhancement of acidic gases in biomass burning impacted air masses over Canada

NASA Technical Reports Server (NTRS)

Lefer, B. L.; Talbot, R. W.; Harriss, R. C.; Bradshaw, J. D.; Sandholm, S. T.; Olson, J. O.; Sachse, G. W.; Collins, J.; Shipham, M. A.; Blake, D. R.

1994-01-01

Biomass-burning impacted air masses sampled over central and eastern Canada during the summer of 1990 as part of ABLE 3B contained enhanced mixing ratios of gaseous HNO3, HCOOH, CH3COOH, and what appears to be (COOH)2. These aircraft-based samples were collected from a variety of fresh burning plumes and more aged haze layers from different source regions. Values of the enhancement factor, delta X/delta CO, where X represents an acidic gas, for combustion-impacted air masses sampled both near and farther away from the fires, were relatively uniform. However, comparison of carboxylic acid emission ratios measured in laboratory fires to field plume enhancement factors indicates significant in-plume production of HCOOH. Biomass-burning appears to be an important source of HNO3, HCOOH, and CH3COOH to the troposphere over subarctic Canada.

Occupational Exposure to Cobalt and Tungsten in the Swedish Hard Metal Industry: Air Concentrations of Particle Mass, Number, and Surface Area

PubMed Central

Bryngelsson, Ing-Liss; Pettersson, Carin; Husby, Bente; Arvidsson, Helena; Westberg, Håkan

2016-01-01

Exposure to cobalt in the hard metal industry entails severe adverse health effects, including lung cancer and hard metal fibrosis. The main aim of this study was to determine exposure air concentration levels of cobalt and tungsten for risk assessment and dose–response analysis in our medical investigations in a Swedish hard metal plant. We also present mass-based, particle surface area, and particle number air concentrations from stationary sampling and investigate the possibility of using these data as proxies for exposure measures in our study. Personal exposure full-shift measurements were performed for inhalable and total dust, cobalt, and tungsten, including personal real-time continuous monitoring of dust. Stationary measurements of inhalable and total dust, PM2.5, and PM10 was also performed and cobalt and tungsten levels were determined, as were air concentration of particle number and particle surface area of fine particles. The personal exposure levels of inhalable dust were consistently low (AM 0.15mg m−3, range <0.023–3.0mg m−3) and below the present Swedish occupational exposure limit (OEL) of 10mg m−3. The cobalt levels were low as well (AM 0.0030mg m−3, range 0.000028–0.056mg m−3) and only 6% of the samples exceeded the Swedish OEL of 0.02mg m−3. For continuous personal monitoring of dust exposure, the peaks ranged from 0.001 to 83mg m−3 by work task. Stationary measurements showed lower average levels both for inhalable and total dust and cobalt. The particle number concentration of fine particles (AM 3000 p·cm−3) showed the highest levels at the departments of powder production, pressing and storage, and for the particle surface area concentrations (AM 7.6 µm2·cm−3) similar results were found. Correlating cobalt mass-based exposure measurements to cobalt stationary mass-based, particle area, and particle number concentrations by rank and department showed significant correlations for all measures except for particle

16. WEST ELEVATION. MONOMOY POINT LT. STATION, MASS., SHOWING PROPOSED ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

16. WEST ELEVATION. MONOMOY POINT LT. STATION, MASS., SHOWING PROPOSED ALTERATION AND IMPROVEMENT OF DWELLING. No. 1343. SHEET 3 of 5. July 1899. - Monomoy Point Light Station, Approximately 3500 feet Northeast Powder Hole Pond, Monomoy National Wildlife Refuge, Chatham, Barnstable County, MA

17. WEST ELEVATION. MONOMOY POINT LT. STATION, MASS., SHOWING PROPOSED ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

17. WEST ELEVATION. MONOMOY POINT LT. STATION, MASS., SHOWING PROPOSED ALTERATION AND IMPROVEMENT OF DWELLING. No. 1343. Sheet 4 of 5. July 1899. - Monomoy Point Light Station, Approximately 3500 feet Northeast Powder Hole Pond, Monomoy National Wildlife Refuge, Chatham, Barnstable County, MA

14. FIRST FLOOR PLAN. MONOMOY POINT LT. STATION, MASS., SHOWING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

14. FIRST FLOOR PLAN. MONOMOY POINT LT. STATION, MASS., SHOWING PROPOSED ALTERATION AND IMPROVEMENT OF DWELLING. No. 1343. SHEET 1 of 5. July 1899. - Monomoy Point Light Station, Approximately 3500 feet Northeast Powder Hole Pond, Monomoy National Wildlife Refuge, Chatham, Barnstable County, MA

15. SECOND FLOOR PLAN. MONOMOY POINT LT. STATION, MASS., SHOWING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. SECOND FLOOR PLAN. MONOMOY POINT LT. STATION, MASS., SHOWING PROPOSED ALTERATION AND IMPROVEMENT OF DWELLING. No. 1343. SHEET 2 OF 5. July 1899. - Monomoy Point Light Station, Approximately 3500 feet Northeast Powder Hole Pond, Monomoy National Wildlife Refuge, Chatham, Barnstable County, MA

Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

USGS Publications Warehouse

Friedman, I.; Harris, J.M.; Smith, G.I.; Johnson, C.A.

2002-01-01

Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the

Chemical composition of air masses transported from Asia to the U.S. West Coast during ITCT 2K2: Fossil fuel combustion versus biomass-burning signatures

NASA Astrophysics Data System (ADS)

de Gouw, J. A.; Cooper, O. R.; Warneke, C.; Hudson, P. K.; Fehsenfeld, F. C.; Holloway, J. S.; Hübler, G.; Nicks, D. K., Jr.; Nowak, J. B.; Parrish, D. D.; Ryerson, T. B.; Atlas, E. L.; Donnelly, S. G.; Schauffler, S. M.; Stroud, V.; Johnson, K.; Carmichael, G. R.; Streets, D. G.

2004-12-01

As part of the Intercontinental Transport and Chemical Transformation experiment in 2002 (ITCT 2K2), a National Oceanic and Atmospheric Administration (NOAA) WP-3D research aircraft was used to study the long-range transport of Asian air masses toward the west coast of North America. During research flights on 5 and 17 May, strong enhancements of carbon monoxide (CO) and other species were observed in air masses that had been transported from Asia. The hydrocarbon composition of the air masses indicated that the highest CO levels were related to fossil fuel use. During the flights on 5 and 17 May and other days, the levels of several biomass-burning indicators increased with altitude. This was true for acetonitrile (CH3CN), methyl chloride (CH3Cl), the ratio of acetylene (C2H2) to propane (C3H8), and, on May 5, the percentage of particles measured by the particle analysis by laser mass spectrometry (PALMS) instrument that were attributed to biomass burning based on their carbon and potassium content. An ensemble of back-trajectories, calculated from the U.S. west coast over a range of latitudes and altitudes for the entire ITCT 2K2 period, showed that air masses from Southeast Asia and China were generally observed at higher altitudes than air from Japan and Korea. Emission inventories estimate the contribution of biomass burning to the total emissions to be low for Japan and Korea, higher for China, and the highest for Southeast Asia. Combined with the origin of the air masses versus altitude, this qualitatively explains the increase with altitude, averaged over the whole ITCT 2K2 period, of the different biomass-burning indicators.

The Analysis of PPM Levels of Gases in Air by Photoionization Mass Spectrometry

ERIC Educational Resources Information Center

Driscoll, John N.; Warneck, Peter

1973-01-01

Discusses analysis of trace gases in air by photoionization mass spectrometer. It is shown that the necessary sensitivity can be obtained by eliminating the UV monochromator and using direct ionization with a hydrogen light source. (JP)

Technical note: Air compared to nitrogen as nebulizing and drying gases for electrospray ionization mass spectrometry.

PubMed

Mielczarek, P; Silberring, J; Smoluch, M

In the present study we tested the application of compressed air instead of pure nitrogen as the nebulizing and drying gas, and its influence on the quality of electrospray ionization (ESI) mass spectra. The intensities of the signals corresponding to protonated molecules were significantly (twice) higher when air was used. Inspection of signal-to-noise (S/N) ratios revealed that, in both cases, sensitivity was comparable. A higher ion abundance after the application of compressed air was followed by a higher background. Another potential risk of using air in the ESI source is the possibility for sample oxidation due to the presence of oxygen. To test this, we selected five easily oxidizing compounds to verify their susceptibility to oxidation. In particular, the presence of methionine was of interest. For all the compounds studied, no oxidation was observed. Amodiaquine oxidizes spontaneously in water solutions and its oxidized form can be detected a few hours after preparation. Direct comparison of the spectra where nitrogen was used with the corresponding spectra obtained when air was applied did not show significant differences. The only distinction was slightly different patterns of adducts when air was used. The difference concerns acetonitrile, which forms higher signals when air is the nebulizing gas. It is also important that the replacement of nitrogen with air does not affect quantitative data. The prepared calibration curves also visualize an intensity twice as high (independent of concentration within tested range) of the signal where air was applied. We have used our system continuously for three months with air as the nebulizing and drying gas and have not noticed any unexpected signal deterioration caused by additional source contamination from the air. Moreover, compressed air is much cheaper and easily available using oil-free compressors or pumps.

Ring waves as a mass transport mechanism in air-driven core-annular flows.

PubMed

Camassa, Roberto; Forest, M Gregory; Lee, Long; Ogrosky, H Reed; Olander, Jeffrey

2012-12-01

Air-driven core-annular fluid flows occur in many situations, from lung airways to engineering applications. Here we study, experimentally and theoretically, flows where a viscous liquid film lining the inside of a tube is forced upwards against gravity by turbulent airflow up the center of the tube. We present results on the thickness and mean speed of the film and properties of the interfacial waves that develop from an instability of the air-liquid interface. We derive a long-wave asymptotic model and compare properties of its solutions with those of the experiments. Traveling wave solutions of this long-wave model exhibit evidence of different mass transport regimes: Past a certain threshold, sufficiently large-amplitude waves begin to trap cores of fluid which propagate upward at wave speeds. This theoretical result is then confirmed by a second set of experiments that show evidence of ring waves of annular fluid propagating over the underlying creeping flow. By tuning the parameters of the experiments, the strength of this phenomenon can be adjusted in a way that is predicted qualitatively by the model.

Influence of trans-boundary biomass burning impacted air masses on submicron particle number concentrations and size distributions

NASA Astrophysics Data System (ADS)

Betha, Raghu; Zhang, Zhe; Balasubramanian, Rajasekhar

2014-08-01

Submicron particle number concentration (PNC) and particle size distribution (PSD) in the size range of 5.6-560 nm were investigated in Singapore from 27 June 2009 through 6 September 2009. Slightly hazy conditions lasted in Singapore from 6 to 10 August. Backward air trajectories indicated that the haze was due to the transport of biomass burning impacted air masses originating from wild forest and peat fires in Sumatra, Indonesia. Three distinct peaks in the morning (08:00-10:00), afternoon (13:00-15:00) and evening (16:00-20:00) were observed on a typical normal day. However, during the haze period no distinct morning and afternoon peaks were observed and the PNC (39,775 ± 3741 cm-3) increased by 1.5 times when compared to that during non-haze periods (26,462 ± 6017). The morning and afternoon peaks on the normal day were associated with the local rush hour traffic while the afternoon peak was induced by new particle formation (NPF). Diurnal profiles of PNCs and PSDs showed that primary particle peak diameters were large during the haze (60 nm) period when compared to that during the non-haze period (45.3 nm). NPF events observed in the afternoon period on normal days were suppressed during the haze periods due to heavy particle loading in atmosphere caused by biomass burning impacted air masses.

76 FR 18672 - Safety Zone; Big Rock Blue Marlin Air Show; Bogue Sound, Morehead City, NC

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-05

...-AA00 Safety Zone; Big Rock Blue Marlin Air Show; Bogue Sound, Morehead City, NC AGENCY: Coast Guard... Safety Zone for the ``Big Rock Blue Marlin Air Show'', an aerial demonstration to be held over the waters... Register. Basis and Purpose On June 11, 2011 from 7 p.m. to 8 p.m., the Big Rock Blue Marlin Tournament...

Variability of aerosol, gaseous pollutants and meteorological characteristics associated with changes in air mass origin at the SW Atlantic coast of Iberia

NASA Astrophysics Data System (ADS)

Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

2012-04-01

Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean, a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol (NR-PM1) was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition, small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions, could be identified in the particle phase

Variation in airborne 137Cs peak levels with altitude from high-altitude locations across Europe after the arrival of Fukushima-labeled air masses

NASA Astrophysics Data System (ADS)

Masson, Olivier; Bieringer, Jacqueline; Dalheimer, Axel; Estier, Sybille; Evrard, Olivier; Penev, Ilia; Ringer, Wolfgang; Schlosser, Clemens; Steinkopff, Thomas; Tositti, Laura; de Vismes-Ott, Anne

2015-04-01

During the Fukushima Daiichi nuclear power plant (FDNPP) accident, a dozen of high-altitude aerosol sampling stations, located between 850 and 3,454 m above sea level (a.s.l.), provided airborne activity levels across Europe (Fig. 1). This represents at most 5% of the total number of aerosol sampling locations that delivered airborne activity levels (at least one result) in Europe, in connection with this nuclear accident. High altitude stations are typically equipped with a high volume sampler that collects aerosols on filters. The Fukushima-labeled air mass arrival and the peak of airborne cesium-137 (137Cs) activity levels were registered in Europe at different dates depending on the location, with differences up to a factor of six on a regional scale. Besides this statement related to lowland areas, we have compared the maximum airborne levels registered at high-altitude European locations (850 m < altitudes < 3450 m) with what was observed at the closest lowland location. The vertical distribution of 137Cs peak level was not uniform even after a long travel time/distance from Japan. This being true at least in the atmospheric boundary layer and in the lower free troposphere. Moreover the relation '137Csmax vs. altitude' shows a decreasing trend (Fig. 2). Results and discussion : Comparison of 137Cs and 7Be levels shows simultaneous increases at least when the 137Cs airborne level rose for the first time (Fig. 3). Zugspitze and Jungfraujoch stations attest of a time shift between 7Be and 137Cs peak that can be due to the particular dynamic of air movements at such high altitudes. After the 137Cs peak value, the plume concentration decreased whatever the 7Be level. Due to the cosmogenic origin of 7Be, its increase in the ground-level air is usually associated with downwind air movements, i.e. stratospheric air intrusions or at least air from high-tropospheric levels, into lower atmospheric layers. This means that Fukushima-labeled air masses registered at ground

A Comparison of the Red Green Blue (RGB) Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles and NOAA G-IV Dropsondes

NASA Technical Reports Server (NTRS)

Berndt, Emily; Folmer, Michael; Dunion, Jason

2014-01-01

RGB air mass imagery is derived from multiple channels or paired channel differences. The combination of channels and channel differences means the resulting imagery does not represent a quantity or physical parameter such as brightness temperature in conventional single channel imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles and NOAA G-IV dropsondes provide insight about the vertical structure of the air mass represented on the RGB air mass imagery and are a first step to validating the imagery.

Analysis of volatile compounds by open-air ionization mass spectrometry.

PubMed

Meher, Anil Kumar; Chen, Yu-Chie

2017-05-08

This study demonstrates a simple method for rapid and in situ identification of volatile and endogenous compounds in culinary spice samples through mass spectrometry (MS). This method only requires a holder for solid spice sample (2-3 mm) that is placed close to a mass spectrometer inlet, which is applied with a high voltage. Volatile species responsible for the aroma of the spice samples can be readily detected by the mass spectrometer. Sample pretreatment is not required prior to MS analysis, and no solvent was used during MS analysis. The high voltage applied to the inlet of the mass spectrometer induces the ionization of volatile compounds released from the solid spice samples. Furthermore, moisture in the air also contributes to the ionization of volatile compounds. Dried spices including cinnamon and cloves are used as the model sample to demonstrate this straightforward MS analysis, which can be completed within few seconds. Furthermore, we also demonstrate the suitability of the current method for rapid screening of cinnamon quality through detection of the presence of a hepatotoxic agent, i.e. coumarin. Copyright © 2017 Elsevier B.V. All rights reserved.

Variability of aerosol, gaseous pollutants and meteorological characteristics associated with continental, urban and marine air masses at the SW Atlantic coast of Iberia

NASA Astrophysics Data System (ADS)

Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

2011-12-01

Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions could be identified in the particle phase. In all

75 FR 37720 - Safety Zone; New Bern Air Show, Neuse River, NC

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-30

... would be contrary to public interest, since immediate action is needed to ensure the safety of human life and property from the hazards associated with air show operations. Basis and Purpose Coast Guard... effect on the human environment. This rule is categorically excluded, under figure 2-1, paragraph (34)(g...

Large-Scale Air Mass Characteristics Observed Over the Remote Tropical Pacific Ocean During March-April 1999: Results from PEM-Tropics B Field Experiment

NASA Technical Reports Server (NTRS)

Browell, Edward V.; Fenn, Marta A.; Butler, Carolyn F.; Grant, William B.; Ismail, Syed; Ferrare, Richard A.; Kooi, Susan A.; Brackett, Vincent G.; Clayton, Marian B.; Avery, Melody A.

2001-01-01

data from each flight were binned by altitude according to air mass type, and these results showed the relative observational frequency of the different air masses as a function of altitude in seven regions over the Pacific. The average chemical composition of the major air mass types was determined from in situ measurements in the NH and SH, and these results provided insight into the origin, lifetime, and chemistry of the air in these regions.

78 FR 37966 - Safety Zone; National Cherry Festival Air Show and Fireworks Display, West Grand Traverse Bay...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-25

...-AA00 Safety Zone; National Cherry Festival Air Show and Fireworks Display, West Grand Traverse Bay... the hazards associated with fireworks displays and aircraft involved in the National Cherry Festival... Festival fireworks display and air show. At the close of the comment period, no comments were received in...

Southeast Atlantic Cloud Properties in a Multivariate Statistical Model - How Relevant is Air Mass History for Local Cloud Properties?

NASA Astrophysics Data System (ADS)

Fuchs, Julia; Cermak, Jan; Andersen, Hendrik

2017-04-01

This study aims at untangling the impacts of external dynamics and local conditions on cloud properties in the Southeast Atlantic (SEA) by combining satellite and reanalysis data using multivariate statistics. The understanding of clouds and their determinants at different scales is important for constraining the Earth's radiative budget, and thus prominent in climate-system research. In this study, SEA stratocumulus cloud properties are observed not only as the result of local environmental conditions but also as affected by external dynamics and spatial origins of air masses entering the study area. In order to assess to what extent cloud properties are impacted by aerosol concentration, air mass history, and meteorology, a multivariate approach is conducted using satellite observations of aerosol and cloud properties (MODIS, SEVIRI), information on aerosol species composition (MACC) and meteorological context (ERA-Interim reanalysis). To account for the often-neglected but important role of air mass origin, information on air mass history based on HYSPLIT modeling is included in the statistical model. This multivariate approach is intended to lead to a better understanding of the physical processes behind observed stratocumulus cloud properties in the SEA.

Ozone Modulation/Membrane Introduction Mass Spectrometry for Analysis of Hydrocarbon Pollutants in Air

NASA Astrophysics Data System (ADS)

Atkinson, D. B.

2001-12-01

Modulation of volatile hydrocarbons in two-component mixtures is demonstrated using an ozonolysis pretreatment with membrane introduction mass spectrometry (MIMS). The MIMS technique allows selective introduction of volatile and semivolatile analytes into a mass spectrometer via processes known collectively as pervaporation [Kotiaho and Cooks, 1992]. A semipermeable polymer membrane acts as an interface between the sample (vapor or solution) and the vacuum of the mass spectrometer. This technique has been demonstrated to allow for sensitive analysis of hydrocarbons and other non-polar volatile organic compounds (VOC`s) in air samples[Cisper et al., 1995] . The methodology has the advantages of no sample pretreatment and short analysis time, which are promising for online monitoring applications but the chief disadvantage of lack of a separation step for the different analytes in a mixture. Several approaches have been investigated to overcome this problem including use of selective chemical ionization [Bier and Cooks, 1987] and multivariate calibration techniques[Ketola et al., 1999] . A new approach is reported for the quantitative measurement of VOCs in complex matrices. The method seeks to reduce the complexity of mass spectra observed in hydrocarbon mixture analysis by selective pretreatment of the analyte mixture. In the current investigation, the rapid reaction of ozone with alkenes is used, producing oxygenated compounds which are suppressed by the MIMS system. This has the effect of removing signals due to unsaturated analytes from the compound mass spectra, and comparison of the spectra before and after the ozone treatment reveals the nature of the parent compounds. In preliminary investigations, ozone reacted completely with cyclohexene from a mixture of cylohexene and cyclohexane, and with β -pinene from a mixture of toluene and β -pinene, suppressing the ion signals from the olefins. A slight attenuation of the cyclohexane and toluene in those

Diode laser-based air mass flux sensor for subsonic aeropropulsion inlets

NASA Astrophysics Data System (ADS)

Miller, Michael F.; Kessler, William J.; Allen, Mark G.

1996-08-01

An optical air mass flux sensor based on a compact, room-temperature diode laser in a fiber-coupled delivery system has been tested on a full-scale gas turbine engine. The sensor is based on simultaneous measurements of O 2 density and Doppler-shifted velocity along a line of sight across the inlet duct. Extensive tests spanning engine power levels from idle to full afterburner demonstrate accuracy and precision of the order of 1 2 of full scale in density, velocity, and mass flux. The precision-limited velocity at atmospheric pressure was as low as 40 cm s. Multiple data-reduction procedures are quantitatively compared to suggest optimal strategies for flight sensor packages.

78 FR 25407 - Safety Zones; National Cherry Festival Air Show and Fireworks Display; West Grand Traverse Bay...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-01

...-AA00 Safety Zones; National Cherry Festival Air Show and Fireworks Display; West Grand Traverse Bay... National Cherry Festival in Traverse City, MI will host an air show over the West Arm of Grand Traverse Bay. At the conclusion of the National Cherry Festival on July 6, 2013, fireworks will be launched in...

Small-size mass spectrometer for determining gases and volatile compounds in air during breathing

NASA Astrophysics Data System (ADS)

Kogan, V. T.; Kozlenok, A. V.; Chichagov, Yu. V.; Antonov, A. S.; Lebedev, D. S.; Bogdanov, A. A.; Moroshkin, V. S.; Berezina, A. V.; Viktorova-Leclerc, O. S.; Vlasov, S. A.; Tubol'tsev, Yu. V.

2015-10-01

We describe an automated mass spectrometer for diagnostics of deceases from the composition of exhaled air. It includes a capillary system, which performs a rapid direct feeding of the sample to the instrument without changing substantially its composition and serves for studying the dynamics of variation of the ratio between various components of exhaled air. The membrane system for introducing the sample is intended for determining low concentrations of volatile organic compounds which are biomarkers of pathologies. It is characterized by selective transmittance and ensures the detection limits of target compounds at the parts per million-parts per billion (ppm-ppb) level. A static mass analyzer operating on permanent magnets possesses advantages important for mobile devices as compared to its dynamic analogs: it is more reliable in operation, has a larger dynamic range, and can be used for determining the concentration of components in the mixture one-by-one or simultaneously. The curvilinear output boundary of the magnetic lens of the mass analyzer makes it possible to reduce its weight and size by 2.5 times without deteriorating the mass resolution. We report on the results of testing of the instrument and consider the possibility of its application for early detection of deceases of respiratory and blood circulation system, gastrointestinal tract, and endocrine system.

Drop size distribution and air velocity measurements in air assist swirl atomizer sprays

NASA Technical Reports Server (NTRS)

Mao, C.-P.; Oechsle, V.; Chigier, N.

1987-01-01

Detailed measurements of mean drop size (SMD) and size distribution parameters have been made using a Fraunhofer diffraction particle sizing instrument in a series of sprays generated by an air assist swirl atomizer. Thirty-six different combinations of fuel and air mass flow rates were examined with liquid flow rates up to 14 lbm/hr and atomizing air flow rates up to 10 lbm/hr. Linear relationships were found between SMD and liquid to air mass flow rate ratios. SMD increased with distance downstream along the center line and also with radial distance from the axis. Increase in obscuration with distance downstream was due to an increase in number density of particles as the result of deceleration of drops and an increase in the exposed path length of the laser beam. Velocity components of the atomizing air flow field measured by a laser anemometer show swirling jet air flow fields with solid body rotation in the core and free vortex flow in the outer regions.

Uncertainty evaluation of mass values determined by electronic balances in analytical chemistry: a new method to correct for air buoyancy.

PubMed

Wunderli, S; Fortunato, G; Reichmuth, A; Richard, Ph

2003-06-01

A new method to correct for the largest systematic influence in mass determination-air buoyancy-is outlined. A full description of the most relevant influence parameters is given and the combined measurement uncertainty is evaluated according to the ISO-GUM approach [1]. A new correction method for air buoyancy using an artefact is presented. This method has the advantage that only a mass artefact is used to correct for air buoyancy. The classical approach demands the determination of the air density and therefore suitable equipment to measure at least the air temperature, the air pressure and the relative air humidity within the demanded uncertainties (i.e. three independent measurement tasks have to be performed simultaneously). The calculated uncertainty is lower for the classical method. However a field laboratory may not always be in possession of fully traceable measurement systems for these room climatic parameters.A comparison of three approaches applied to the calculation of the combined uncertainty of mass values is presented. Namely the classical determination of air buoyancy, the artefact method, and the neglecting of this systematic effect as proposed in the new EURACHEM/CITAC guide [2]. The artefact method is suitable for high-precision measurement in analytical chemistry and especially for the production of certified reference materials, reference values and analytical chemical reference materials. The method could also be used either for volume determination of solids or for air density measurement by an independent method.

AUTOMATED DECONVOLUTION OF COMPOSITE MASS SPECTRA OBTAINED WITH AN OPEN-AIR IONIZATIONS SOURCE BASED ON EXACT MASSES AND RELATIVE ISOTIPIC ABUNDANCES

EPA Science Inventory

Chemicals dispersed by accidental, deliberate, or weather-related events must be rapidly identified to assess health risks. Mass spectra from high levels of analytes obtained using rapid, open-air ionization by a Direct Analysis in Real Time (DART®) ion source often contain

77 FR 43517 - Safety Zone; Flying Magazine Air Show, Lake Winnebago, Oshkosh, WI

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-25

... the hazards associated with an air show and associated pyrotechnics, which are discussed further below... associated pyrotechnics will be held over Lake Winnebago in Oshkosh WI. The Captain of the Port, Sector Lake Michigan, has determined that an aircraft executing acrobatic maneuvers with associated pyrotechnics...

Airborne mass spectrometers: four decades of atmospheric and space research at the Air Force research laboratory.

PubMed

Viggiano, A A; Hunton, D E

1999-11-01

Mass spectrometry is a versatile research tool that has proved to be extremely useful for exploring the fundamental nature of the earth's atmosphere and ionosphere and in helping to solve operational problems facing the Air Force and the Department of Defense. In the past 40 years, our research group at the Air Force Research Laboratory has flown quadrupole mass spectrometers of many designs on nearly 100 sounding rockets, nine satellites, three Space Shuttles and many missions of high-altitude research aircraft and balloons. We have also used our instruments in ground-based investigations of rocket and jet engine exhaust, combustion chemistry and microwave breakdown chemistry. This paper is a review of the instrumentation and techniques needed for space research, a summary of the results from many of the experiments, and an introduction to the broad field of atmospheric and space mass spectrometry in general. Copyright 1999 John Wiley & Sons, Ltd.

An objective classification system of air mass types for Szeged, Hungary, with special attention to plant pollen levels.

PubMed

Makra, László; Juhász, Miklós; Mika, János; Bartzokas, Aristides; Béczi, Rita; Sümeghy, Zoltán

2006-07-01

This paper discusses the characteristic air mass types over the Carpathian Basin in relation to plant pollen levels over annual pollination periods. Based on the European Centre for Medium-Range Weather Forecasts dataset, daily sea-level pressure fields analysed at 00 UTC were prepared for each air mass type (cluster) in order to relate sea-level pressure patterns to pollen levels in Szeged, Hungary. The database comprises daily values of 12 meteorological parameters and daily pollen concentrations of 24 species for their pollination periods from 1997 to 2001. Characteristic air mass types were objectively defined via factor analysis and cluster analysis. According to the results, nine air mass types (clusters) were detected for pollination periods of the year corresponding to pollen levels that appear with higher concentration when irradiance is moderate while wind speed is moderate or high. This is the case when an anticyclone prevails in the region west of the Carpathian Basin and when Hungary is under the influence of zonal currents (wind speed is high). The sea level pressure systems associated with low pollen concentrations are mostly similar to those connected to higher pollen concentrations, and arise when wind speed is low or moderate. Low pollen levels occur when an anticyclone prevails in the region west of the Carpathian Basin, as well as when an anticyclone covers the region with Hungary at its centre. Hence, anticyclonic or anticyclonic ridge weather situations seem to be relevant in classifying pollen levels.

Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

NASA Astrophysics Data System (ADS)

Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

2016-05-01

An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

NASA Astrophysics Data System (ADS)

Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J.; Healy, R.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; Ehn, M.; Mikkilä, J.; Kulmala, M.; O'Dowd, C. D.

2010-09-01

As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June, 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the N. E. Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water soluble organic carbon, which, in turn, was dominated by methanesulphonic acid (MSA). Sulphate concentrations were

Decomposing the profile of PM in two low polluted German cities--mapping of air mass residence time, focusing on potential long range transport impacts.

PubMed

Dimitriou, Konstantinos; Kassomenos, Pavlos

2014-07-01

This paper aims to decompose the profile of particulates in Karlsruhe and Potsdam (Germany), focusing on the localization of PM potential transboundary sources. An air mass cluster analysis was implemented, followed by a study of air mass residence time on a grid of a 0.5° × 0.5° resolution. Particulate/gaseous daily air pollution and meteorological data were used to indicate PM local sources. Four Principal Component Analysis (PCA) components were produced: traffic, photochemical, industrial/domestic and particulate. PM2.5/PM10 ratio seasonal trends, indicated production of PMCOARSE (PM10-PM2.5) from secondary sources in Potsdam during warm period (WP). The residing areas of incoming slow moving air masses are potential transboundary PM sources. For Karlsruhe those areas were mainly around the city. An air mass residence time secondary peak was observed over Stuttgart. For Potsdam, areas with increased dwelling time of the arriving air parcels were detected particularly above E/SE Germany. Copyright © 2014 Elsevier Ltd. All rights reserved.

Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

NASA Astrophysics Data System (ADS)

Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J. C.; Sodeau, J. R.; Healy, R. M.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; O'Dowd, C. D.

2009-12-01

As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the NE Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Black carbon concentrations in polluted air were between 300-400 ng m-3, and in clean marine air were less than 50 ng m-3. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water

Extratropical Stratosphere-Troposphere Mass Exchange

NASA Technical Reports Server (NTRS)

Schoeberl, Mark R.

2004-01-01

Understanding the exchange of gases between the stratosphere and the troposphere is important for determining how pollutants enter the stratosphere and how they leave. This study does a global analysis of that the exchange of mass between the stratosphere and the troposphere. While the exchange of mass is not the same as the exchange of constituents, you can t get the constituent exchange right if you have the mass exchange wrong. Thus this kind of calculation is an important test for models which also compute trace gas transport. In this study I computed the mass exchange for two assimilated data sets and a GCM. The models all agree that amount of mass descending from the stratosphere to the troposphere in the Northern Hemisphere extra tropics is approx. 10(exp 10) kg/s averaged over a year. The value for the Southern Hemisphere by about a factor of two. ( 10(exp 10) kg of air is the amount of air in 100 km x 100 km area with a depth of 100 m - roughly the size of the D.C. metro area to a depth of 300 feet.) Most people have the idea that most of the mass enters the stratosphere through the tropics. But this study shows that almost 5 times more mass enters the stratosphere through the extra-tropics. This mass, however, is quickly recycled out again. Thus the lower most stratosphere is a mixture of upper stratospheric air and tropospheric air. This is an important result for understanding the chemistry of the lower stratosphere.

The effect of long-range air mass transport pathways on PM10 and NO2 concentrations at urban and rural background sites in Ireland: Quantification using clustering techniques.

PubMed

Donnelly, Aoife A; Broderick, Brian M; Misstear, Bruce D

2015-01-01

The specific aims of this paper are to: (i) quantify the effects of various long range transport pathways nitrogen dioxide (NO2) and particulate matter with diameter less than 10μm (PM10) concentrations in Ireland and identify air mass movement corridors which may lead to incidences poor air quality for application in forecasting; (ii) compare the effects of such pathways at various sites; (iii) assess pathways associated with a period of decreased air quality in Ireland. The origin of and the regions traversed by an air mass 96h prior to reaching a receptor is modelled and k-means clustering is applied to create air-mass groups. Significant differences in air pollution levels were found between air mass cluster types at urban and rural sites. It was found that easterly or recirculated air masses lead to higher NO2 and PM10 levels with average NO2 levels varying between 124% and 239% of the seasonal mean and average PM10 levels varying between 103% and 199% of the seasonal mean at urban and rural sites. Easterly air masses are more frequent during winter months leading to higher overall concentrations. The span in relative concentrations between air mass clusters is highest at the rural site indicating that regional factors are controlling concentration levels. The methods used in this paper could be applied to assist in modelling and forecasting air quality based on long range transport pathways and forecast meteorology without the requirement for detailed emissions data over a large regional domain or the use of computationally demanding modelling techniques.

Mass measurement of 1 kg silicon spheres to establish a density standard

NASA Astrophysics Data System (ADS)

Mizushima, S.; Ueki, M.; Fujii, K.

2004-04-01

Air buoyancy causes a significant systematic effect in precision mass determination of 1 kg silicon spheres. In order to correct this effect accurately, mass measurement of the silicon sphere was conducted using buoyancy artefacts; additionally, in order to stabilize atmospheric conditions, we used a vacuum chamber in which a mass comparator had been installed. The silicon sphere was also weighed in vacuum to verify the air buoyancy correction. Mass differences measured in air and in vacuum showed good agreement with each other in spite of the desorption effect from weight surfaces. Furthermore, the result of weighing under vacuum conditions demonstrated better repeatability than that obtained in air.

Measuring air-water interfacial area for soils using the mass balance surfactant-tracer method.

PubMed

Araujo, Juliana B; Mainhagu, Jon; Brusseau, Mark L

2015-09-01

There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. Copyright © 2015 Elsevier Ltd. All rights reserved.

SAM-CAAM: A Concept for Acquiring Systematic Aircraft Measurements to Characterize Aerosol Air Masses.

PubMed

Kahn, Ralph A; Berkoff, Tim A; Brock, Charles; Chen, Gao; Ferrare, Richard A; Ghan, Steven; Hansico, Thomas F; Hegg, Dean A; Martins, J Vanderlei; McNaughton, Cameron S; Murphy, Daniel M; Ogren, John A; Penner, Joyce E; Pilewskie, Peter; Seinfeld, John H; Worsnop, Douglas R

2017-10-01

A modest operational program of systematic aircraft measurements can resolve key satellite-aerosol-data-record limitations. Satellite observations provide frequent, global aerosol-amount maps, but offer only loose aerosol property constraints needed for climate and air quality applications. We define and illustrate the feasibility of flying an aircraft payload to measure key aerosol optical, microphysical, and chemical properties in situ . The flight program could characterize major aerosol air-mass types statistically, at a level-of-detail unobtainable from space. It would: (1) enhance satellite aerosol retrieval products with better climatology assumptions, and (2) improve translation between satellite-retrieved optical properties and species-specific aerosol mass and size simulated in climate models to assess aerosol forcing, its anthropogenic components, and other environmental impacts. As such, Systematic Aircraft Measurements to Characterize Aerosol Air Masses (SAM-CAAM) could add value to data records representing several decades of aerosol observations from space, improve aerosol constraints on climate modeling , help interrelate remote-sensing, in situ, and modeling aerosol-type definitions , and contribute to future satellite aerosol missions. Fifteen Required Variables are identified, and four Payload Options of increasing ambition are defined, to constrain these quantities. "Option C" could meet all the SAM-CAAM objectives with about 20 instruments, most of which have flown before, but never routinely several times per week, and never as a group. Aircraft integration, and approaches to data handling, payload support, and logistical considerations for a long-term, operational mission are discussed. SAM-CAAM is feasible because, for most aerosol sources and specified seasons, particle properties tend to be repeatable , even if aerosol loading varies.

Quantifying energy and mass transfer in crop canopies: sensors for measurement of temperature and air velocity

NASA Technical Reports Server (NTRS)

Bugbee, B.; Monje, O.; Tanner, B.

1996-01-01

Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.

Remote mass spectrometric sampling of electrospray- and desorption electrospray-generated ions using an air ejector.

PubMed

Dixon, R Brent; Bereman, Michael S; Muddiman, David C; Hawkridge, Adam M

2007-10-01

A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data are presented.

Characterization of NOx-Ox relationships during daytime interchange of air masses over a mountain pass in the Mexico City megalopolis

NASA Astrophysics Data System (ADS)

García-Yee, J. S.; Torres-Jardón, R.; Barrera-Huertas, H.; Castro, T.; Peralta, O.; García, M.; Gutiérrez, W.; Robles, M.; Torres-Jaramillo, J. A.; Ortínez-Álvarez, A.; Ruiz-Suárez, L. G.

2018-03-01

The role of the Tenango del Aire mountain pass, located southeast of the Mexico City Metropolitan Area (MCMA), in venting the city's air pollution has already been studied from a meteorological standpoint. To better understand the transport of gaseous air pollutants through the Tenango del Aire Pass (TAP), and its influence on the air quality of the MCMA, three mobile air quality monitoring units were deployed during a 31-day field campaign between February and March of 2011. Surface O3, NOx, and meteorological variables were continuously measured at the three sites. Vertical profiles of O3 and meteorological variables were also obtained at one of the sites using a tethered balloon. Days were classified as being under low pressure synoptic systems (LPS, 13 days), high pressure synoptic systems (HPS, 13 days), or as transition days (TR). The Mexican ozone standards at the Pass were not exceeded during LPS days, but were exceeded on almost all HPS days. A detailed analysis was performed using data from two typical days, one representative of LPS and the other of HPS. In both cases, morning vertical profiles of O3 showed a strong thermal inversion layer and near-surface O3 titration due to fresh NOx. In the LPS early morning, a single O3 layer of close to 45 ppb was observed from 150 to 700 magl. In the HPS early morning, 50 ppb was observed from 150 to 400 magl followed by a 400-m-thick layer with up to 80 ppb. These layers were the source of the morning increase of O3, with a simultaneous sharp decrease of NOx and CO as the mixing layer started to rise. During the LPS day, a southerly wind dominated throughout most of the daytime, with surface O3 lower than 60 ppb. The same was observed for the well-mixed midday and afternoon vertical profiles. Under HPS, northerly winds transported photochemically active air masses from the MCMA all morning, as observed by a smoother increase of Ox and O3, reaching 110 ppb of O3. Just after midday, the wind shifted back, carrying

Airborne survey of major air basins in California

NASA Technical Reports Server (NTRS)

Gloria, H. R.; Bradburn, G.; Reinisch, R. F.; Pitts, J. N., Jr.; Behar, J. V.; Zafonte, L.

1974-01-01

An instrumented aircraft was used to study the chemical and transport properties of air pollution in two major urban centers in California and to survey certain aspects of air pollution within this state. State-of-the-art measurement techniques and sampling procedures are discussed. It is found that meteorological transport mechanisms are better portrayed by vertical pollutant profiles. Airborne measurements define the nature of the mixing layer for atmospheric pollutants. Results show that the pollutants are found to be concentrated in distinct layers up to at least 18,000 feet and the O3 buildup occurring in advected air masses is a result of a continuous photochemical aging of air mass.

Influence of air mass origin on aerosol properties at a remote Michigan forest site

NASA Astrophysics Data System (ADS)

VanReken, T. M.; Mwaniki, G. R.; Wallace, H. W.; Pressley, S. N.; Erickson, M. H.; Jobson, B. T.; Lamb, B. K.

2015-04-01

The northern Great Lakes region of North America is a large, relatively pristine area. To date, there has only been limited study of the atmospheric aerosol in this region. During summer 2009, a detailed characterization of the atmospheric aerosol was conducted at the University of Michigan Biological Station (UMBS) as part of the Community Atmosphere-Biosphere Interactions Experiment (CABINEX). Measurements included particle size distribution, water-soluble composition, and CCN activity. Aerosol properties were strongly dependent on the origin of the air masses reaching the site. For ∼60% of the study period, air was transported from sparsely populated regions to the northwest. During these times aerosol loadings were low, with mean number and volume concentrations of 1630 cm-3 and 1.91 μm3 cm-3, respectively. The aerosol during clean periods was dominated by organics, and exhibited low hygroscopicities (mean κ = 0.18 at s = 0.3%). When air was from more populated regions to the east and south (∼29% of the time), aerosol properties reflected a stronger anthropogenic influence, with 85% greater particle number concentrations, 2.5 times greater aerosol volume, six times more sulfate mass, and increased hygroscopicity (mean к = 0.24 at s = 0.3%). These trends are have the potential to influence forest-atmosphere interactions and should be targeted for future study.

Influence of air mass origin on aerosol properties at a remote Michigan forest site

DOE PAGES

VanReken, T. M.; Mwaniki, G. R.; Wallace, H. W.; ...

2015-02-10

The northern Great Lakes region of North America is a large, relatively pristine area. To date, there has only been limited study of the atmospheric aerosol in this region. During summer 2009, a detailed characterization of the atmospheric aerosol was conducted at the University of Michigan Biological Station (UMBS) as part of the Community Atmosphere–Biosphere Interactions Experiment (CABINEX). Measurements included particle size distribution, water-soluble composition, and CCN activity. Aerosol properties were strongly dependent on the origin of the air masses reaching the site. For ~60% of the study period, air was transported from sparsely populated regions to the northwest. Duringmore » these times aerosol loadings were low, with mean number and volume concentrations of 1630 cm -3 and 1.91 μm 3 cm -3, respectively. The aerosol during clean periods was dominated by organics, and exhibited low hygroscopicities (mean κ = 0.18 at s = 0.3%). When air was from more populated regions to the east and south (~29% of the time), aerosol properties reflected a stronger anthropogenic influence, with 85% greater particle number concentrations, 2.5 times greater aerosol volume, six times more sulfate mass, and increased hygroscopicity (mean к = 0.24 at s = 0.3%). Furthermore, these trends are have the potential to influence forest–atmosphere interactions and should be targeted for future study.« less

Condensation of atmospheric moisture from tropical maritime air masses as a freshwater resource.

PubMed

Gerard, R D; Worzel, J L

1967-09-15

A method is proposed whereby potable water may be obtained by condensing moisture from the atmosphere in suitable seashore or island areas. Deep, cold, offshore seawater is used as a source of cold and is pumped to condensers set up on shore to intercept the flow of highly humid, tropical, maritime air masses. This air, when cooled, condenses moisture, which is conducted away and stored for use as a water supply. Windmill-driven generators would supply low-cost power for the operation. Side benefits are derived by using the nutritious deep water to support aquiculture in nearby lagoons or to enhance the productivity of the outfall area. Additional benefits are derived from the condenser as an air-conditioning device for nearby residents. The islands of the Caribbean are used as an example of a location in the trade-winds belt where nearly optimum conditions for the operation of this system can be found.

Remote Mass Spectrometric Sampling of Electrospray- and Desorption Electrospray-Generated Ions Using an Air Ejector

PubMed Central

Dixon, R. Brent; Bereman, Michael S.; Muddiman, David C.; Hawkridge, Adam M.

2007-01-01

A commercial air ejector was coupled to an electrospray ionization linear ion trap mass spectrometer (LTQ) to transport remotely generated ions from both electrospray (ESI) and desorption electrospray ionization (DESI) sources. We demonstrate the remote analysis of a series of analyte ions that range from small molecules and polymers to polypeptides using the AE-LTQ interface. The details of the ESI-AE-LTQ and DESI-AE-LTQ experimental configurations are described and preliminary mass spectrometric data is presented. PMID:17716909

Air-mass flux measurement system using Doppler-shifted filtered Rayleigh scattering

NASA Technical Reports Server (NTRS)

Shirley, John A.; Winter, Michael

1993-01-01

An optical system has been investigated to measure mass flux distributions in the inlet of a high speed air-breathing propulsion system. Rayleigh scattered light from air is proportional to the number density of molecules and hence can be used to ascertain the gas density in a calibrated system. Velocity field measurements are achieved by spectrally filtering the elastically-scattered Doppler-shifted light with an absorbing molecular filter. A novel anamorphic optical collection system is used which allows optical rays from different scattering angles, that have different Doppler shifts, to be recorded separately. This is shown to obviate the need to tune the laser through the absorption to determine velocities, while retaining the ability to make spatially-resolved measurements along a line. By properly selecting the laser tuning and filter parameters, simultaneous density measurements can be made. These properties are discussed in the paper and experiments demonstrating the velocimetry capability are described.

Estimation of whole lemon mass transfer parameters during hot air drying using different modelling methods

NASA Astrophysics Data System (ADS)

Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza

2015-08-01

To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.

Toward a better understanding of the impact of mass transit air pollutants on human health

USDA-ARS?s Scientific Manuscript database

Modern mass transit systems, based on roads, rail, water, and air, generate toxic airborne pollutants throughout the developed world. This has become one of the leading concerns about the use of modern transportation, particularly in densely-populated urban areas where their use is enormous and inc...

Cluster Analysis of the Organic Peaks in Bulk Mass Spectra Obtained During the 2002 New England Air Quality Study with an Aerodyne Aerosol Mass Spectrometer

NASA Astrophysics Data System (ADS)

Marcolli, C.; Canagaratna, M. R.; Worsnop, D. R.; Bahreini, R.; de Gouw, J. A.; Warneke, C.; Goldan, P. D.; Kuster, W. C.; Williams, E. J.; Lerner, B. M.; Roberts, J. M.; Meagher, J. F.; Fehsenfeld, F. C.; Marchewka, M.; Bertman, S. B.; Middlebrook, A. M.

2006-12-01

We applied hierarchical cluster analysis to an Aerodyne aerosol mass spectrometer (AMS) bulk mass spectral dataset collected aboard the NOAA research vessel R. H. Brown during the 2002 New England Air Quality Study off the east coast of the United States. Emphasizing the organic peaks, the cluster analysis yielded a series of categories that are distinguishable with respect to their mass spectra and their occurrence as a function of time. The differences between the categories mainly arise from relative intensity changes rather than from the presence or absence of specific peaks. The most frequent category exhibits a strong signal at m/z 44 and represents oxidized organic matter probably originating from both anthropogenic as well as biogenic sources. On the basis of spectral and trace gas correlations, the second most common category with strong signals at m/z 29, 43, and 44 contains contributions from isoprene oxidation products. The third through the fifth most common categories have peak patterns characteristic of monoterpene oxidation products and were most frequently observed when air masses from monoterpene rich regions were sampled. Taken together, the second through the fifth most common categories represent on average 17% of the total organic mass that stems likely from biogenic sources during the ship's cruise. These numbers have to be viewed as lower limits since the most common category was attributed to anthropogenic sources for this calculation. The cluster analysis was also very effective in identifying a few contaminated mass spectra that were not removed during pre-processing. This study demonstrates that hierarchical clustering is a useful tool to analyze the complex patterns of the organic peaks in bulk aerosol mass spectra from a field study.

Characterization of ion processes in a GC/DMS air quality monitor by integration of the instrument to a mass spectrometer.

PubMed

Limero, T F; Nazarov, E G; Menlyadiev, M; Eiceman, G A

2015-02-07

The air quality monitor (AQM), which included a portable gas chromatograph (GC) and a detector was interfaced to a mass spectrometer (MS) by introducing flow from the GC detector to the atmospheric pressure ion source of the MS. This small GC system, with a gas recirculation loop for carrier and detector make-up gases, comprised an inlet to preconcentrate volatile organic compounds (VOCs) in air, a thermal desorber before the GC column, a differential mobility spectrometer (DMS), and another DMS as an atmospheric pressure ionization source for the MS. Return flow to the internally recirculated air system of the AQM's DMS was replenished using purified air. Although ions and unreacted neutral vapors flowed from the detector through Viton® tubing into the source of the MS, ions were not detected in the MS without the auxillary ion source, (63)Ni as in the mobility detector. The GC-DMS-MS instrument provided a 3-D measurement platform (GC, DMS, and MS analysis) to explore the gas composition inside the GC-DMS recirculation loop and provide DMS-MS measurement of the components of a complex VOC mixture with performance significantly enhanced by mass-analysis, either with mass spectral scans or with an extracted ion chromatogram. This combination of a mobility spectrometer and a mass spectrometer was possible as vapors and ions are carried together through the DMS analyzer, thereby preserving the chromatographic separation efficiency. The critical benefit of this instrument concept is that all flows in and through the thoroughly integrated GC-DMS analyzer are kept intact allowing a full measure of the ion and vapor composition in the complete system. Performance has been evaluated using a synthetic air sample and a sample of airborne vapors in a laboratory. Capabilities and performance values are described using results from AQM-MS analysis of purified air, ambient air from a research laboratory in a chemistry building, and a sample of synthetic air of known composition

Centrifugal study of zone of influence during air-sparging.

PubMed

Hu, Liming; Meegoda, Jay N; Du, Jianting; Gao, Shengyan; Wu, Xiaofeng

2011-09-01

Air sparging (AS) is one of the groundwater remediation techniques for remediating volatile organic compounds (VOCs) in saturated soil. However, in spite of the success of air sparging as a remediation technique for the cleanup of contaminated soils, to date, the fundamental mechanisms or the physics of air flow through porous media is not well understood. In this study, centrifugal modeling tests were performed to investigate air flow rates and the evolution of the zone of influence during the air sparging under various g-levels. The test results show that with the increase in sparging pressure the mass flow rate of the air sparging volume increases. The air mass flow rate increases linearly with the effective sparging pressure ratio, which is the difference between sparging pressure and hydrostatic pressure normalized with respect to the effective overburden pressure at the sparging point. Also the slope of mass flow rate with effective sparging pressure ratio increases with higher g-levels. This variation of the slope of mass flow rate of air sparging volume versus effective sparging pressure ratio, M, is linear with g-level confirming that the air flow through soil for a given effective sparging pressure ratio only depends on the g-level. The test results also show that with increasing sparging pressure, the zone of influence (ZOI), which consists of the width at the tip of the cone or lateral intrusion and the cone angle, will lead to an increase in both lateral intrusion and the cone angle. With a further increase in air injection pressure, the cone angle reaches a constant value while the lateral intrusion becomes the main contributor to the enlargement of the ZOI. However, beyond a certain value of effective sparging pressure ratio, there is no further enlargement of the ZOI.

Cluster analysis of the organic peaks in bulk mass spectra obtained during the 2002 New England Air Quality Study with an Aerodyne aerosol mass spectrometer

NASA Astrophysics Data System (ADS)

Marcolli, C.; Canagaratna, M. R.; Worsnop, D. R.; Bahreini, R.; de Gouw, J. A.; Warneke, C.; Goldan, P. D.; Kuster, W. C.; Williams, E. J.; Lerner, B. M.; Roberts, J. M.; Meagher, J. F.; Fehsenfeld, F. C.; Marchewka, M. L.; Bertman, S. B.; Middlebrook, A. M.

2006-06-01

We applied hierarchical cluster analysis to an Aerodyne aerosol mass spectrometer (AMS) bulk mass spectral dataset collected aboard the NOAA research vessel Ronald H. Brown during the 2002 New England Air Quality Study off the east coast of the United States. Emphasizing the organic peaks, the cluster analysis yielded a series of categories that are distinguishable with respect to their mass spectra and their occurrence as a function of time. The differences between the categories mainly arise from relative intensity changes rather than from the presence or absence of specific peaks. The most frequent category exhibits a strong signal at m/z 44 and represents oxidized organic matter most probably originating from both, anthropogenic as well as biogenic sources. On the basis of spectral and trace gas correlations, the second most common category with strong signals at m/z 29, 43, and 44 contains contributions from isoprene oxidation products. The third through the fifth most common categories have peak patterns characteristic of monoterpene oxidation products and were most frequently observed when air masses from monoterpene rich regions were sampled. Taken together, the second through the fifth most common categories represent as much as 5 µg/m3 organic aerosol mass - 17% of the total organic mass - that can be attributed to biogenic sources. These numbers have to be viewed as lower limits since the most common category was attributed to anthropogenic sources for this calculation. The cluster analysis was also very effective in identifying a few contaminated mass spectra that were not removed during pre-processing. This study demonstrates that hierarchical clustering is a useful tool to analyze the complex patterns of the organic peaks in bulk aerosol mass spectra from a field study.

Desert Dust Aerosol Air Mass Mapping in the Western Sahara, Using Particle Properties Derived from Space-Based Multi-Angle Imaging

NASA Technical Reports Server (NTRS)

Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Esselborn, Michael; Fiebig, Marcus; Heese, Birgit; Knippertz, Peter; Mueller, Detlef;

Spatial and Temporal Patterns in the Carbon Isotopic Signal of Leaf Wax Aerosols in Continental Air Masses: Linkages with Ecosystem Discrimination

NASA Astrophysics Data System (ADS)

Weber, J.; Conte, M. H.

2006-12-01

Temporal and spatial variations in the concentration and isotopic composition of atmospheric carbon dioxide can be used to estimate the relative magnitudes of the terrestrial and oceanic carbon sinks. An important model parameter is the terrestrial photosynthetic carbon isotopic fractionation of CO2 (Δ), yet estimating Δ over the large spatial scales required by models remains problematic. Epiculticular leaf waxes appear to closely reflect the plant's carbon isotopic discrimination; therefore, the ablated wax aerosols present in well-mixed continental air masses may be used as a proxy to estimate the magnitude of Δ integrated over large (subcontinental) spatial scales. Over the last several years, we have been conducting time-series studies of wax aerosol molecular and isotopic composition at strategically located sites (Maine, northern Alaska, Florida, Bermuda, Barbados) which receive continental air masses passing over major terrestrial biomes (northern temperate/ecotonal boreal forests, tundra, southern US pine/hardwood forests, North American and north African). In this presentation, we describe and contrast patterns of wax aerosol-derived estimates of Δ at these sites. In North American air masses, estimates of Δ range from 14.5-20.5 using the concentration-weighted average δ13C of wax n-acids and from 13.5-19.5 for the wax n-alcohols. Seasonal trends observed in the Florida (southern US) and Bermuda samples (mixed North American air masses) indicate maximum discrimination in early spring and minimum discrimination during the summer dry season. In northern US and high latitude air masses, seasonal trends are less pronounced but in general temporally offset with highest discrimination occurring during late summer. At Barbados, which is dominated by north African air masses passing over regions largely comprised of arid C4 grasslands, estimated Δ for the wax n-acids is significantly lower (14.0-15.5 per mil), consistent with a higher predominance of C4

PM2.5 chemical composition at a rural background site in Central Europe, including correlation and air mass back trajectory analysis

NASA Astrophysics Data System (ADS)

Schwarz, Jaroslav; Cusack, Michael; Karban, Jindřich; Chalupníčková, Eva; Havránek, Vladimír; Smolík, Jiří; Ždímal, Vladimír

2016-07-01

PM2.5 mass concentrations and chemical compositions sampled over a 13-month period at a Central European rural background site (Košetice) are presented in this work. A comprehensive chemical analysis of PM2.5 was performed, which provided elemental composition (Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, and Pb) and the concentration of water-soluble inorganic anions (SO42 -, NO3-. Cl-, NO2-, Br-, and H2PO4-) and cations (Na+, NH4+, K+, Ca2 +, and Mg2 +), elemental and organic carbon (EC and OC), and levoglucosan. Spearman correlation coefficients between individual chemical species and particle number concentrations were calculated for the following six size ranges: 10-25 nm (N10-25), 25-50 nm (N25-50), 50-80 nm (N50-80), 80-150 nm (N80-150), 150-300 nm (N150-300), and 300-800 nm (N300-800). Average concentrations of individual species were comparable with concentrations reported from similar sites across Central Europe. Organic matter (OM) accounted for 45% of the PM2.5 mass (calculated from OC by a factor of 1.6), while the second most common component were secondary aerosols (SO42 -: 19%, NO3-: 14%, NH4+: 10%), which accounted for 43% of the mass. Based on levoglucosan analysis, 31% of OM was attributed to emissions associated with biomass burning (OMBB). EC concentrations, determined using the EUSAAR_2 thermal optical protocol, contributed 4% to PM2.5 mass. A total of 1% of the mass was attributed to a mineral matter source, while the remaining 6% was from an undetermined mass. Seasonal variations showed highest concentrations of NO3- and OMBB in winter, nitrate share in spring, and an increase in percentage of SO42 - and mineral matter in summer. The largest seasonal variation was found for species associated with wood and coal combustion (levoglucosan, K+, Zn, Pb, As), which had clear maxima during winter. Correlation analysis of different size fraction particle number concentrations was used to distinguish the influence

Desert Dust Air Mass Mapping in the Western Sahara, using Particle Properties Derived from Space-based Multi-angle Imaging

NASA Technical Reports Server (NTRS)

Kahn, Ralph; Petzold, Andreas; Wendisch, Manfred; Bierwirth, Eike; Dinter, Tilman; Fiebig, Marcus; Schladitz, Alexander; von Hoyningen-Huene, Wolfgang

2008-01-01

Coincident observations made over the Moroccan desert during the SAhara Mineral dUst experiMent (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from Multi-angle Imaging SpectroRadiometer (MISR) observations, and to place the sub-orbital aerosol measurements into the satellite's larger regional context. On three moderately dusty days for which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05 to 0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR's ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape, and single-scattering albedo. For the three study days, the satellite observations (a) highlight regional gradients in the mix of dust and background spherical particles, (b) identify a dust plume most likely part of a density flow, and (c) show an air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometers away.

75 FR 50952 - Safety Zone; Blue Angels at Kaneohe Bay Air Show, Oahu, HI

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-18

... DEPARTMENT OF HOMELAND SECURITY Coast Guard 33 CFR Part 165 [Docket No. USCG-2010-0705] RIN 1625-AA00 Safety Zone; Blue Angels at Kaneohe Bay Air Show, Oahu, HI AGENCY: Coast Guard, DHS. ACTION: Notice of proposed rulemaking. SUMMARY: The Coast Guard proposes two temporary safety zones while the U.S...

77 FR 56549 - Safety Zone; Blue Angels at Kaneohe Bay Air Show, Oahu, HI

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-13

... DEPARTMENT OF HOMELAND SECURITY Coast Guard 33 CFR Part 165 [Docket Number USCG-2012-0739] RIN 1625-AA00 Safety Zone; Blue Angels at Kaneohe Bay Air Show, Oahu, HI AGENCY: Coast Guard, DHS. ACTION: Temporary final rule. SUMMARY: The Coast Guard is establishing a temporary safety zone while the U.S. Navy...

Buoyancy contribution to uncertainty of mass, conventional mass and force

NASA Astrophysics Data System (ADS)

Malengo, Andrea; Bich, Walter

2016-04-01

The conventional mass is a useful concept introduced to reduce the impact of the buoyancy correction in everyday mass measurements, thus avoiding in most cases its accurate determination, necessary in measurements of ‘true’ mass. Although usage of conventional mass is universal and standardized, the concept is considered as a sort of second-choice tool, to be avoided in high-accuracy applications. In this paper we show that this is a false belief, by elucidating the role played by covariances between volume and mass and between volume and conventional mass at the various stages of the dissemination chain and in the relationship between the uncertainties of mass and conventional mass. We arrive at somewhat counter-intuitive results: the volume of the transfer standard plays a comparatively minor role in the uncertainty budget of the standard under calibration. In addition, conventional mass is preferable to mass in normal, in-air operation, as its uncertainty is smaller than that of mass, if covariance terms are properly taken into account, and the uncertainty over-stating (typically) resulting from neglecting them is less severe than that (always) occurring with mass. The same considerations hold for force. In this respect, we show that the associated uncertainty is the same using mass or conventional mass, and, again, that the latter is preferable if covariance terms are neglected.

Toward a better understanding of the impact of mass transit air pollutants on human health.

PubMed

Kim, Ki-Hyun; Kumar, Pawan; Szulejko, Jan E; Adelodun, Adedeji A; Junaid, Muhammad Faisal; Uchimiya, Minori; Chambers, Scott

2017-05-01

Globally, modern mass transport systems whether by road, rail, water, or air generate airborne pollutants in both developing and developed nations. Air pollution is the primary human health concern originating from modern transportation, particularly in densely-populated urban areas. This review will specifically focus on the origin and the health impacts of carbonaceous traffic-related air pollutants (TRAP), including particulate matter (PM), volatile organic compounds (VOCs), and elemental carbon (EC). We conclude that the greatest current challenge regarding urban TRAP is understanding and evaluating the human health impacts well enough to set appropriate pollution control measures. Furthermore, we provide a detailed discussion regarding the effects of TRAP on local environments and pedestrian health in low and high traffic-density environments. Copyright © 2017 Elsevier Ltd. All rights reserved.

Heat Transfer of Confined Impinging Air-water Mist Jet

NASA Astrophysics Data System (ADS)

Chang, Shyy Woei; Su, Lo May

This paper describes the detailed heat transfer distributions of an atomized air-water mist jet impinging orthogonally onto a confined target plate with various water-to-air mass-flow ratios. A transient technique was used to measure the full field heat transfer coefficients of the impinging surface. Results showed that the high momentum mist-jet interacting with the water-film and wall-jet flows created a variety of heat transfer contours on the impinging surface. The trade-off between the competing influences of the different heat transfer mechanisms involving in an impinging mist jet made the nonlinear variation tendency of overall heat transfer against the increase of water-to-air mass-flow ratio and extended the effective cooling region. With separation distances of 10, 8, 6 and 4 jet-diameters, the spatially averaged heat transfer values on the target plate could respectively reach about 2.01, 1.83, 2.43 and 2.12 times of the equivalent air-jet values, which confirmed the applicability of impinging mist-jet for heat transfer enhancement. The optimal choices of water-to-air mass-flow ratio for the atomized mist jet required the considerations of interactive and combined effects of separation distance, air-jet Reynolds number and the water-to-air mass-flow ratio into the atomized nozzle.

Development of a particle-trap preconcentration-soft ionization mass spectrometric technique for the quantification of mercury halides in air.

PubMed

Deeds, Daniel A; Ghoshdastidar, Avik; Raofie, Farhad; Guérette, Élise-Andrée; Tessier, Alain; Ariya, Parisa A

2015-01-01

Measurement of oxidized mercury, Hg(II), in the atmosphere poses a significant analytical challenge as Hg(II) is present at ultra-trace concentrations (picograms per cubic meter air). Current technologies are sufficiently sensitive to measure the total Hg present as Hg(II) but cannot determine the chemical speciation of Hg(II). We detail here the development of a soft ionization mass spectrometric technique coupled with preconcentration onto nano- or microparticle-based traps prior to analysis for the measurement of mercury halides in air. The current methodology has comparable detection limits (4-11 pg m(-3)) to previously developed techniques for the measurement of total inorganic mercury in air while allowing for the identification of HgX2 in collected samples. Both mercury chloride and mercury bromide have been sporadically detected in Montreal urban and indoor air using atmospheric pressure chemical ionization-mass spectrometry (APCI-MS). We discuss limitations and advantages of the current technique and discuss potential avenues for future research including quantitative trace measurements of a larger range of mercury compounds.

New Directions: Questions surrounding suspended particle mass used as a surrogate for air quality and for regulatory control of ambient urban air pollution

NASA Astrophysics Data System (ADS)

Hoare, John L.

2014-07-01

The original choice of particulate matter mass (PM) as a realistic surrogate for gross air pollution has gradually evolved into routine use nowadays of epidemiologically-based estimates of the monetary and other benefits expected from regulating urban air quality. Unfortunately, the statistical associations facilitating such calculations usually are based on single indices of air pollution whereas the health effects themselves are more broadly based causally. For this and other reasons the economic benefits of control tend to be exaggerated. Primarily because of their assumed inherently inferior respirability, particles ≥10 μm are generally excluded from such considerations. Where the particles themselves are chemically heterogeneous, as in an urban context, this may be inappropriate. Clearly all air-borne particles, whether coarse or fine, are susceptible to inhalation. Hence, the possibility exists for any adhering potentially harmful semi-volatile substances to be subsequently de-sorbed in vivo thereby facilitating their transport deeper into the lungs. Consequently, this alone may be a sufficient reason for including rather than rejecting during air quality monitoring the relatively coarse 10-100 μm particle fraction, ideally in conjunction with routine estimation of the gaseous co-pollutants thereby facilitating a multi-pollutant approach apropos regulation.

High-Altitude Air Mass Zero Calibration of Solar Cells

NASA Technical Reports Server (NTRS)

Woodyard, James R.; Snyder, David B.

2005-01-01

Air mass zero calibration of solar cells has been carried out for several years by NASA Glenn Research Center using a Lear-25 aircraft and Langley plots. The calibration flights are carried out during early fall and late winter when the tropopause is at the lowest altitude. Measurements are made starting at about 50,000 feet and continue down to the tropopause. A joint NASA/Wayne State University program called Suntracker is underway to explore the use of weather balloon and communication technologies to characterize solar cells at elevations up to about 100 kft. The balloon flights are low-cost and can be carried out any time of the year. AMO solar cell characterization employing the mountaintop, aircraft and balloon methods are reviewed. Results of cell characterization with the Suntracker are reported and compared with the NASA Glenn Research Center aircraft method.

Mass casualty tracking with air traffic control methodologies.

PubMed

Hoskins, Jason D; Graham, Ross F; Robinson, Duane R; Lutz, Clifford C; Folio, Les R

2009-06-01

An intrahospital casualty throughput system modeled after air traffic control (ATC) tracking procedures was tested in mass casualty exercises. ATC uses a simple tactile process involving informational progress strips representing each aircraft, which are held in bays representing each stage of flight to prioritize and manage aircraft. These strips can be reordered within the bays to indicate a change in priority of aircraft sequence. In this study, a similar system was designed for patient tracking. We compared the ATC model and traditional casualty tracking methods of paper and clipboard in 18 four-hour casualty scenarios, each with 5 to 30 mock casualties. The experimental and control groups were alternated to maximize exposure and minimize training effects. Results were analyzed with Mann-Whitney statistical analysis with p value < 0.05 (two-sided). The ATC method had significantly (p = 0.017) fewer errors in critical patient data (eg, name, social security number, diagnosis). Specifically, the ATC method better tracked the mechanism of injury, working diagnosis, and disposition of patients. The ATC method also performed considerably better with patient accountability during mass casualty scenarios. Data strips were comparable with the control method in terms of ease of use. In addition, participants preferred the ATC method to the control (p = 0.003) and preferred using the ATC method (p = 0.003) to traditional methods in the future. The ATC model more effectively tracked patient data with fewer errors when compared with the clipboard method. Application of these principles can enhance trauma management and can have application in civilian and military trauma centers and emergency rooms.

The influence of polarization on box air mass factors for UV/vis nadir satellite observations

NASA Astrophysics Data System (ADS)

Hilboll, Andreas; Richter, Andreas; Rozanov, Vladimir V.; Burrows, John P.

2015-04-01

Tropospheric abundances of pollutant trace gases like, e.g., NO2, are often derived by applying the differential optical absorption spectroscopy (DOAS) method to space-borne measurements of back-scattered and reflected solar radiation. The resulting quantity, the slant column density (SCD), subsequently has to be converted to more easily interpretable vertical column densities by means of the so-called box air mass factor (BAMF). The BAMF describes the ratio of SCD and VCD within one atmospheric layer and is calculated by a radiative transfer model. Current operational and scientific data products of satellite-derived trace gas VCDs do not include the effect of polarization in their radiative transfer models. However, the various scattering processes in the atmosphere do lead to a distinctive polarization pattern of the observed Earthshine spectra. This study investigates the influence of these polarization patterns on box air mass factors for satellite nadir DOAS measurements of NO2 in the UV/vis wavelength region. NO2 BAMFs have been simulated for a multitude of viewing geometries, surface albedos, and surface altitudes, using the radiative transfer model SCIATRAN. The results show a potentially large influence of polarization on the BAMF, which can reach 10% and more close to the surface. A simple correction for this effect seems not to be feasible, as it strongly depends on the specific measurement scenario and can lead to both high and low biases of the resulting NO2 VCD. We therefore conclude that all data products of NO2 VCDs derived from space-borne DOAS measurements should include polarization effects in their radiative transfer model calculations, or at least include the errors introduced by using linear models in their uncertainty estimates.

33 CFR 165.1319 - Safety Zone Regulations, Seafair Blue Angels Air Show Performance, Seattle, WA.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Safety Zone Regulations, Seafair... Thirteenth Coast Guard District § 165.1319 Safety Zone Regulations, Seafair Blue Angels Air Show Performance... Federal Register. (b) Location. The following is a safety zone: All waters of Lake Washington encompassed...

An anthropometric model to estimate neonatal fat mass using air displacement plethysmography

PubMed Central

2012-01-01

Background Current validated neonatal body composition methods are limited/impractical for use outside of a clinical setting because they are labor intensive, time consuming, and require expensive equipment. The purpose of this study was to develop an anthropometric model to estimate neonatal fat mass (kg) using an air displacement plethysmography (PEA POD® Infant Body Composition System) as the criterion. Methods A total of 128 healthy term infants, 60 females and 68 males, from a multiethnic cohort were included in the analyses. Gender, race/ethnicity, gestational age, age (in days), anthropometric measurements of weight, length, abdominal circumference, skin-fold thicknesses (triceps, biceps, sub scapular, and thigh), and body composition by PEA POD® were collected within 1-3 days of birth. Backward stepwise linear regression was used to determine the model that best predicted neonatal fat mass. Results The statistical model that best predicted neonatal fat mass (kg) was: -0.012 -0.064*gender + 0.024*day of measurement post-delivery -0.150*weight (kg) + 0.055*weight (kg)2 + 0.046*ethnicity + 0.020*sum of three skin-fold thicknesses (triceps, sub scapular, and thigh); R2 = 0.81, MSE = 0.08 kg. Conclusions Our anthropometric model explained 81% of the variance in neonatal fat mass. Future studies with a greater variety of neonatal anthropometric measurements may provide equations that explain more of the variance. PMID:22436534

Surface analysis using a new plasma assisted desorption/ionisation source for mass spectrometry in ambient air

NASA Astrophysics Data System (ADS)

Bowfield, A.; Barrett, D. A.; Alexander, M. R.; Ortori, C. A.; Rutten, F. M.; Salter, T. L.; Gilmore, I. S.; Bradley, J. W.

2012-06-01

The authors report on a modified micro-plasma assisted desorption/ionisation (PADI) device which creates plasma through the breakdown of ambient air rather than utilising an independent noble gas flow. This new micro-PADI device is used as an ion source for ambient mass spectrometry to analyse species released from the surfaces of polytetrafluoroethylene, and generic ibuprofen and paracetamol tablets through remote activation of the surface by the plasma. The mass spectra from these surfaces compare favourably to those produced by a PADI device constructed using an earlier design and confirm that the new ion source is an effective device which can be used to achieve ambient mass spectrometry with improved spatial resolution.

77 FR 27120 - Safety Zone; Virginia Beach Oceanfront Air Show, Atlantic Ocean, Virginia Beach, VA

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-09

... restriction of vessel traffic is necessary to protect life, property and the environment during the fireworks... property and could cause significant injury or death to mariners observing the air shows. Due to the need... the Federal Register. The commenter suggested that the Coast Guard add a chart to the regulation to...

Characteristics of vertical air motion in isolated convective clouds

DOE PAGES

Yang, Jing; Wang, Zhien; Heymsfield, Andrew J.; ...

2016-08-11

The vertical velocity and air mass flux in isolated convective clouds are statistically analyzed using aircraft in situ data collected from three field campaigns: High-Plains Cumulus (HiCu) conducted over the midlatitude High Plains, COnvective Precipitation Experiment (COPE) conducted in a midlatitude coastal area, and Ice in Clouds Experiment-Tropical (ICE-T) conducted over a tropical ocean. The results show that small-scale updrafts and downdrafts (<  500 m in diameter) are frequently observed in the three field campaigns, and they make important contributions to the total air mass flux. The probability density functions (PDFs) and profiles of the observed vertical velocity are provided. The PDFsmore » are exponentially distributed. The updrafts generally strengthen with height. Relatively strong updrafts (>  20 m s −1) were sampled in COPE and ICE-T. The observed downdrafts are stronger in HiCu and COPE than in ICE-T. The PDFs of the air mass flux are exponentially distributed as well. The observed maximum air mass flux in updrafts is of the order 10 4 kg m −1 s −1. The observed air mass flux in the downdrafts is typically a few times smaller in magnitude than that in the updrafts. Since this study only deals with isolated convective clouds, and there are many limitations and sampling issues in aircraft in situ measurements, more observations are needed to better explore the vertical air motion in convective clouds.« less

High Lapse Rates in AIRS Retrieved Temperatures in Cold Air Outbreaks

NASA Technical Reports Server (NTRS)

Fetzer, Eric J.; Kahn, Brian; Olsen, Edward T.; Fishbein, Evan

2004-01-01

The Atmospheric Infrared Sounder (AIRS) experiment, on NASA's Aqua spacecraft, uses a combination of infrared and microwave observations to retrieve cloud and surface properties, plus temperature and water vapor profiles comparable to radiosondes throughout the troposphere, for cloud cover up to 70%. The high spectral resolution of AIRS provides sensitivity to important information about the near-surface atmosphere and underlying surface. A preliminary analysis of AIRS temperature retrievals taken during January 2003 reveals extensive areas of superadiabatic lapse rates in the lowest kilometer of the atmosphere. These areas are found predominantly east of North America over the Gulf Stream, and, off East Asia over the Kuroshio Current. Accompanying the high lapse rates are low air temperatures, large sea-air temperature differences, and low relative humidities. Imagery from a Visible / Near Infrared instrument on the AIRS experiment shows accompanying clouds. These lines of evidence all point to shallow convection in the bottom layer of a cold air mass overlying warm water, with overturning driven by heat flow from ocean to atmosphere. An examination of operational radiosondes at six coastal stations in Japan shows AIRS to be oversensitive to lower tropospheric lapse rates due to systematically warm near-surface air temperatures. The bias in near-surface air temperature is seen to be independent of sea surface temperature, however. AIRS is therefore sensitive to air-sea temperature difference, but with a warm atmospheric bias. A regression fit to radiosondes is used to correct AIRS near-surface retrieved temperatures, and thereby obtain an estimate of the true atmosphere-ocean thermal contrast in five subtropical regions across the north Pacific. Moving eastward, we show a systematic shift in this air-sea temperature differences toward more isothermal conditions. These results, while preliminary, have implications for our understanding of heat flow from ocean to

Stability of reference masses: VII. Cleaning methods in air and vacuum applied to a platinum mass standard similar to the international and national kilogram prototypes

NASA Astrophysics Data System (ADS)

Cumpson, Peter J.; Sano, Naoko; Barlow, Anders J.; Portoles, Jose F.

2013-10-01

Mercury contamination and the build-up of carbonaceous contamination are two contributing factors to the instability observed in kilogram prototype masses. The kilogram prototypes that lie at the core of the dissemination of the SI base unit were manufactured in the late 19th century, and have polished surfaces. In papers IV and V of this series we developed a method for cleaning noble metal mass standards in air to remove carbonaceous contamination. At the core of this ‘UVOPS’ protocol is the application of UV light and ozone gas generated in situ in air. The precise nature of the carbonaceous contamination that builds up on such surfaces is difficult to mimic demonstrably or quickly on new test surfaces, yet data from such tests are needed to provide the final confidence to allow UVOPS to be applied to a real 19th century kilogram prototype. Therefore, in the present work we have applied the UVOPS method to clean a platinum avoirdupois pound mass standard, ‘RS2’, manufactured in the mid-19th century. This is thought to have been polished in a similar manner to the kilogram prototypes. To our knowledge this platinum surface has not previously been cleaned by any method. We used x-ray photoelectron spectroscopy to identify organic contamination, and weighing to quantify the mass lost at each application of the UVOPS procedure. The UVOPS procedure is shown to be very effective. It is likely that the redefinition of the kilogram will require mass comparisons in vacuum in the years to come. Therefore, in addition to UVOPS a cleaning method for use in vacuum will also be needed. We introduce and evaluate gas cluster ion-beam (GCIB) treatment as a potential method for cleaning reference masses in vacuum. Again, application of this GCIB cleaning to a real artefact, RS2, allows us to make a realistic evaluation of its performance. While it has some attractive features, we cannot recommend it for cleaning mass standards in its present form.

Neonatal Presentation of an Air-Filled Neck Mass that Enlarges with Valsalva: A Case Report

PubMed Central

Patel, Jasminkumar Bharatbhai; Kilbride, Howard; Paulson, Lorien

2015-01-01

Branchial cleft cysts are common causes of congenital neck masses in the pediatric population. However, neonatal presentation of branchial cleft cysts is uncommon, but recognizable secondary to acute respiratory distress from airway compression or complications secondary to infection. We report a 1-day-old infant presenting with an air-filled neck mass that enlarged with Valsalva and was not associated with respiratory distress. The infant was found to have a third branchial cleft cyst with an internal opening into the pyriform sinus. The cyst was conservatively managed with endoscopic surgical decompression and cauterization of the tract and opening. We review the embryology of branchial cleft cysts and current management. PMID:26495186

EPA Air Method, Toxic Organics - 15 (TO-15): Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially-Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS)

EPA Pesticide Factsheets

Method T)-15 describes procedures for for preparation and analysis of air samples containing volatile organic compounds collected in specially-prepared canisters, using gas chromatography-mass spectrometry.

Economic impact and market analysis of a special event: The Great New England Air Show

Treesearch

Rodney B. Warnick; David C. Bojanic; Atul Sheel; Apurv Mather; Deepak Ninan

2010-01-01

We conducted a post-event evaluation for the Great New England Air Show to assess its general economic impact and to refine economic estimates where possible. In addition to the standard economic impact variables, we examined travel distance, purchase decision involvement, event satisfaction, and frequency of attendance. Graphic mapping of event visitors' home ZIP...

Structure and Composition of Air-Plane Soots and Surrogates Analyzed by Raman Spectroscopy and Laser/Ions Desorption Mass Spectrometry

NASA Astrophysics Data System (ADS)

Ortega, Ismael; Chazallon, Bertrand; Carpentier, Yvain; Irimiea, Cornelia; Focsa, Cristian; Ouf, François-Xavier; Salm, François; Delhaye, David; Gaffié, Daniel; Yon, Jérôme

2015-04-01

Aviation alters the composition of the atmosphere globally and can thus drive climate change and ozone depletion [1]. An aircraft exhaust plume contains species emitted by the engines, species formed in the plume from the emitted species and atmospheric species that become entrained into the plume. The majority of emitted species (gases and soot particles) are produced by the combustion of kerosene with ambient air in the combustion chamber of the engine. Emissions of soot particles by air-planes produce persistent contrails in the upper troposphere in ice-supersaturated air masses that contribute to cloudiness and impact the radiative properties of the atmosphere. These aerosol-cloud interactions represent one of the largest sources of uncertainty in global climate models [2]. Though the formation of atmospheric ice particles has been studied since many years [3], there are still numerous opened questions on nucleation properties of soot particles [4], as the ice nucleation experiments showed a large spread in results depending on the nucleation mode chosen and origin of the soot produced. Most likely one of the reasons behind these discrepancies resides in the different physico-chemical properties (composition, structure) of soot particles produced in different conditions, e.g. with respect to fuel or combustion techniques. In this work, we use Raman microscopy (266, 514 and 785 nm excitation) and ablation techniques (SIMS, Secondary Ions Mass Spectrometry, and Laser Desorption Mass Spectrometry) to characterize soot particles produced from air-plane at different engine regimes simulating a landing and taking-off (LTO) cycle. First, the spectral parameters of the first-order Raman band of various soot samples, collected from three different sources in the frame of the MERMOSE project (http://mermose.onera.fr/): PowerJet SaM-146 turbofan (four engine regimes), CAST generator (propane fuel, four different global equivalence ratios), and Kerosene laboratory flame

Biological Monitoring of Air Pollutants and Its Influence on Human Beings

PubMed Central

Cen, Shihong

2015-01-01

Monitoring air pollutants via plants is an economic, convenient and credible method compared with the traditional ways. Plants show different damage symptoms to different air pollutants, which can be used to determine the species of air pollutants. Besides, pollutants mass concentration scope can be estimated by the damage extent of plants and the span of polluted time. Based on the domestic and foreign research, this paper discusses the principles, mechanism, advantages and disadvantages of plant-monitoring, and exemplifies plenty of such plants and the minimum mass concentration and pollution time of the plants showing damage symptoms. Finally, this paper introduced the human health effects of air pollutants on immune function of the body, such as decrease of the body's immune function, decline of lung function, respiratory and circulatory system changes, inducing and promoting human allergic diseases, respiratory diseases and other diseases. PMID:26628931

Evidence for widespread tropospheric Cl chemistry in free tropospheric air masses from the South China Sea

NASA Astrophysics Data System (ADS)

Baker, Angela K.; Sauvage, Carina; Thorenz, Ute R.; Brenninkmeijer, Carl A. M.; Oram, David E.; van Velthoven, Peter; Zahn, Andreas; Williams, Jonathan

2015-04-01

While the primary global atmospheric oxidant is the hydroxyl radical (OH), under certain circumstances chlorine radicals (Cl) can compete with OH and perturb the oxidative cycles of the troposphere. During flights between Bangkok, Thailand and Kuala Lumpur, Malaysia conducted over two fall/winter seasons (November 2012 - March 2013 and November 2013 - January 2014) the IAGOS-CARIBIC (www.caribic-atmospheric.com) observatory consistently encountered free tropospheric air masses (9-11 km) originating over the South China Sea which had non-methane hydrocarbon (NMHC) signatures characteristic of processing by Cl. These signatures were observed in November and December of both years, but were not seen in other months, suggesting that oxidation by Cl is a persistent seasonal feature in this region. These Cl signatures were observed over a range of ~1500 km indicating a large-scale phenomenon. In this region, where transport patterns facilitate global redistribution of pollutants and persistent deep convection creates a fast-track for cross-tropopause transport, there exists the potential for regional chemistry to have impacts further afield. Here we use observed relationships between NMHCs to estimate the significance and magnitude of Cl oxidation in this region. From the relative depletions of NMHCs in these air masses we infer OH to Cl ratios of 83±28 to 139±40 [OH]/[Cl], which we believe represents an upper limit, based on the technique employed. At a predicted average [OH] of 1.5×106 OH cm-3 this corresponds to an average (minimum) [Cl] exposure of 1-2×104 Cl cm-3 during air mass transport. Lastly, in addition to estimating Cl abundances we have used IAGOS-CARIBIC observations to elucidate whether the origin of this Cl is predominantly natural or anthropogenic.

Relationship Between Chronic Obstructive Pulmonary Disease and Air Pollutants Depending on the Origin and Trajectory of Air Masses in the North of Spain.

PubMed

Santurtún, Ana; Rasilla, Domingo F; Riancho, Leyre; Zarrabeitia, María T

2017-11-01

Chronic obstructive pulmonary disease (COPD) is a common respiratory condition and one of the leading causes of death. Our aim was to analyze the association between emergency room visits due to this disease and meteorological variables and atmospheric contaminant levels in Santander, depending on the origin and trajectory of air masses. Data from emergency room visits at Hospital Marqués de Valdecilla were collected on a daily basis during an 8-year period. Data on concentrations of the main atmospheric pollutants and meteorological variables were also recorded.Retrotrajectories leading to Santander at a height of1,500 meters above sea level were then calculated. Finally, a correlation model was produced to evaluate the effect of the contaminants on emergency visitsdue to COPD. There is a direct association between PM 10 levels and the number of visits to the emergency room due to COPD. For every 10μg/m3 increase in pollutantlevels, emergency visitsincrease by3.34% (p=0.00005), and thiseffect is enhanced in individualsover 74 years of age. This effect is heightened when PM10 levels depend on air masses from the South and when air recirculation occurs. There is no association betweenother pollutants and the number of visits to the emergency room. Exposure to high levels of PM10 causes exacerbations in COPD patients. By studying the atmospheric circulation pattern, we can predict whether PM10 levels will be inappropriately high, and we can also obtain information about the particle components. Copyright © 2017 SEPAR. Publicado por Elsevier España, S.L.U. All rights reserved.

Establishing Lagrangian connections between observations within air masses crossing the Atlantic during the International Consortium for Atmospheric Research on Transport and Transformation experiment

NASA Astrophysics Data System (ADS)

Methven, J.; Arnold, S. R.; Stohl, A.; Evans, M. J.; Avery, M.; Law, K.; Lewis, A. C.; Monks, P. S.; Parrish, D. D.; Reeves, C. E.; Schlager, H.; Atlas, E.; Blake, D. R.; Coe, H.; Crosier, J.; Flocke, F. M.; Holloway, J. S.; Hopkins, J. R.; McQuaid, J.; Purvis, R.; Rappenglück, B.; Singh, H. B.; Watson, N. M.; Whalley, L. K.; Williams, P. I.

2006-12-01

The ITCT-Lagrangian-2K4 (Intercontinental Transport and Chemical Transformation) experiment was conceived with an aim to quantify the effects of photochemistry and mixing on the transformation of air masses in the free troposphere away from emissions. To this end, attempts were made to intercept and sample air masses several times during their journey across the North Atlantic using four aircraft based in New Hampshire (USA), Faial (Azores) and Creil (France). This article begins by describing forecasts from two Lagrangian models that were used to direct the aircraft into target air masses. A novel technique then identifies Lagrangian matches between flight segments. Two independent searches are conducted: for Lagrangian model matches and for pairs of whole air samples with matching hydrocarbon fingerprints. The information is filtered further by searching for matching hydrocarbon samples that are linked by matching trajectories. The quality of these "coincident matches" is assessed using temperature, humidity and tracer observations. The technique pulls out five clear Lagrangian cases covering a variety of situations and these are examined in detail. The matching trajectories and hydrocarbon fingerprints are shown, and the downwind minus upwind differences in tracers are discussed.

Aerosols in polluted versus nonpolluted air masses Long-range transport and effects on clouds

NASA Technical Reports Server (NTRS)

Pueschel, R. F.; Van Valin, C. C.; Castillo, R. C.; Kadlecek, J. A.; Ganor, E.

1986-01-01

To assess the influence of anthropogenic aerosols on the physics and chemistry of clouds in the northeastern United States, aerosol and cloud-drop size distributions, elemental composition of aerosols as a function of size, and ionic content of cloud water were measured on Whiteface Mountain, NY, during the summers of 1981 and 1982. In several case studies, the data were cross-correlated with different air mass types - background continental, polluted continental, and maritime - that were advected to the sampling site. The results are the following: (1) Anthropogenic sources hundreds of kilometers upwind cause the small-particle (accumulation) mode number to increase from hundreds of thousands per cubic centimeter and the mass loading to increase from a few to several tens of micrograms per cubic meter, mostly in the form of sulfur aerosols. (2) A significant fraction of anthropogenic sulfur appears to act as cloud condensation nuclei (CCN) to affect the cloud drop concentration. (3) Clouds in Atlantic maritime air masses have cloud drop spectra that are markedly different from those measured in continental clouds. The drop concentration is significantly lower, and the drop size spectra are heavily skewed toward large drops. (4) Effects of anthropogenic pollutants on cloud water ionic composition are an increase of nitrate by a factor of 50, an increase of sulfate by more than one order of magnitude, and an increase of ammonium ion by a factor of 7. The net effect of the changes in ionic concentrations is an increase in cloud water acidity. An anion deficit even in maritime clouds suggests an unknown, possibly biogenic, source that could be responsible for a pH below neutral, which is frequently observed in nonpolluted clouds.

Potential sources of the air masses leading to warm and cold anomalies in Moscow in summer

NASA Astrophysics Data System (ADS)

Shukurov, K. A.; Semenov, V. A.

2017-11-01

For summer (June-July-August) days in 1949-2016, using the NOAA trajectory model HYSPLIT_4, the 5-day backward trajectories of the air parcels (elementary air particles) were calculated. Using the daily surface air temperatures (SAT) in summer in Moscow in 1949-2016 and the results of the backward trajectories modeling by PSCF (potential source contribution function) and CWT (concentration weighted trajectories) methods the regions where the air masses most probably hit to before its arrive into the Moscow region at the days of 20%, 10%, 5% and 2% of the strongest positive and negative anomalies of SAT in summer in Moscow. For composites of days with SAT in summer in Moscow above 90th and below the 10th percentile of the distribution function of the SAT, the field of the anomaly of atmospheric pressure at sea level relative to 1981-2010 climatology and the field of average SAT in Eurasia north of 30° N are calculated. The peculiarities of the fields associated with the strong positive and negative anomalies of SAT in summer seasons in Moscow are identified. The fields of potential sources of air parcels, mean air temperature on the path of the movement of air parcels and the average height of the backward trajectory for days with strong anomalies of SAT in summer in Moscow are compared. Possible atmospheric circulation drivers of the highest and lowest anomalies of SAT in winter in Moscow are found out.

Comb-push ultrasound shear elastography of breast masses: initial results show promise.

PubMed

Denis, Max; Mehrmohammadi, Mohammad; Song, Pengfei; Meixner, Duane D; Fazzio, Robert T; Pruthi, Sandhya; Whaley, Dana H; Chen, Shigao; Fatemi, Mostafa; Alizad, Azra

2015-01-01

To evaluate the performance of Comb-push Ultrasound Shear Elastography (CUSE) for classification of breast masses. CUSE is an ultrasound-based quantitative two-dimensional shear wave elasticity imaging technique, which utilizes multiple laterally distributed acoustic radiation force (ARF) beams to simultaneously excite the tissue and induce shear waves. Female patients who were categorized as having suspicious breast masses underwent CUSE evaluations prior to biopsy. An elasticity estimate within the breast mass was obtained from the CUSE shear wave speed map. Elasticity estimates of various types of benign and malignant masses were compared with biopsy results. Fifty-four female patients with suspicious breast masses from our ongoing study are presented. Our cohort included 31 malignant and 23 benign breast masses. Our results indicate that the mean shear wave speed was significantly higher in malignant masses (6 ± 1.58 m/s) in comparison to benign masses (3.65 ± 1.36 m/s). Therefore, the stiffness of the mass quantified by the Young's modulus is significantly higher in malignant masses. According to the receiver operating characteristic curve (ROC), the optimal cut-off value of 83 kPa yields 87.10% sensitivity, 82.61% specificity, and 0.88 for the area under the curve (AUC). CUSE has the potential for clinical utility as a quantitative diagnostic imaging tool adjunct to B-mode ultrasound for differentiation of malignant and benign breast masses.

Highly sensitive determination of polycyclic aromatic hydrocarbons in ambient air dust by gas chromatography-mass spectrometry after molecularly imprinted polymer extraction.

PubMed

Krupadam, Reddithota J; Bhagat, Bhagyashree; Khan, Muntazir S

2010-08-01

A method based on solid--phase extraction with a molecularly imprinted polymer (MIP) has been developed to determine five probable human carcinogenic polycyclic aromatic hydrocarbons (PAHs) in ambient air dust by gas chromatography-mass spectrometry (GC-MS). Molecularly imprinted poly(vinylpyridine-co-ethylene glycol dimethacrylate) was chosen as solid-phase extraction (SPE) material for PAHs. The conditions affecting extraction efficiency, for example surface properties, concentration of PAHs, and equilibration times were evaluated and optimized. Under optimum conditions, pre-concentration factors for MIP-SPE ranged between 80 and 93 for 10 mL ambient air dust leachate. PAHs recoveries from MIP-SPE after extraction from air dust were between 85% and 97% and calibration graphs of the PAHs showed a good linearity between 10 and 1000 ng L(-1) (r = 0.99). The extraction efficiency of MIP for PAHs was compared with that of commercially available SPE materials--powdered activated carbon (PAC) and polystyrene-divinylbenzene resin (XAD)--and it was shown that the extraction capacity of the MIP was better than that of the other two SPE materials. Organic matter in air dust had no effect on MIP extraction, which produced a clean extract for GC-MS analysis. The detection limit of the method proposed in this article is 0.15 ng L(-1) for benzo[a]pyrene, which is a marker molecule of air pollution. The method has been applied to the determination of probable carcinogenic PAHs in air dust of industrial zones and satisfactory results were obtained.

International system of units traceable results of Hg mass concentration at saturation in air from a newly developed measurement procedure.

PubMed

Quétel, Christophe R; Zampella, Mariavittoria; Brown, Richard J C; Ent, Hugo; Horvat, Milena; Paredes, Eduardo; Tunc, Murat

2014-08-05

Data most commonly used at present to calibrate measurements of mercury vapor concentrations in air come from a relationship known as the "Dumarey equation". It uses a fitting relationship to experimental results obtained nearly 30 years ago. The way these results relate to the international system of units (SI) is not known. This has caused difficulties for the specification and enforcement of limit values for mercury concentrations in air and in emissions to air as part of national or international legislation. Furthermore, there is a significant discrepancy (around 7% at room temperature) between the Dumarey data and data calculated from results of mercury vapor pressure measurements in the presence of only liquid mercury. As an attempt to solve some of these problems, a new measurement procedure is described for SI traceable results of gaseous Hg concentrations at saturation in milliliter samples of air. The aim was to propose a scheme as immune as possible to analytical biases. It was based on isotope dilution (ID) in the liquid phase with the (202)Hg enriched certified reference material ERM-AE640 and measurements of the mercury isotope ratios in ID blends, subsequent to a cold vapor generation step, by inductively coupled plasma mass spectrometry. The process developed involved a combination of interconnected valves and syringes operated by computer controlled pumps and ensured continuity under closed circuit conditions from the air sampling stage onward. Quantitative trapping of the gaseous mercury in the liquid phase was achieved with 11.5 μM KMnO4 in 2% HNO3. Mass concentrations at saturation found from five measurements under room temperature conditions were significantly higher (5.8% on average) than data calculated from the Dumarey equation, but in agreement (-1.2% lower on average) with data based on mercury vapor pressure measurement results. Relative expanded combined uncertainties were estimated following a model based approach. They ranged from 2

Operational performance of a low cost, air mass 2 solar simulator

NASA Technical Reports Server (NTRS)

Yass, K.; Curtis, H. B.

1975-01-01

Modifications and improvements on a low cost air mass 2 solar simulator are discussed. The performance characteristics of total irradiance, uniformity of irradiance, spectral distribution, and beam subtense angle are presented. The simulator consists of an array of tungsten halogen lamps hexagonally spaced in a plane. A corresponding array of plastic Fresnel lenses shapes the output beam such that the simulator irradiates a 1.2 m by 1.2 m area with uniform collimated irradiance. Details are given concerning individual lamp output measurements and placement of the lamps. Originally, only the direct component of solar irradiance was simulated. Since the diffuse component may affect the performance of some collectors, the capability to simulate it is being added. An approach to this diffuse addition is discussed.

Progress Toward a Global, EOS-Era Aerosol Air Mass Type Climatology

NASA Technical Reports Server (NTRS)

Kahn, Ralph A.

2012-01-01

The MISR and MODIS instruments aboard the NASA Earth Observing System's Terra Satellite have been collecting data containing information about the state of Earth's atmosphere and surface for over eleven years. Data from these instruments have been used to develop a global, monthly climatology of aerosol amount that is widely used as a constraint on climate models, including those used for the 2007 IPCC assessment report. The next frontier in assessing aerosol radiative forcing of climate is aerosol type, and in particular, the absorption properties of major aerosol air masses. This presentation will focus on the prospects for constraining aerosol type globally, and the steps we are taking to apply a combination of satellite and suborbital data to this challenge.

Comb-Push Ultrasound Shear Elastography of Breast Masses: Initial Results Show Promise

PubMed Central

Song, Pengfei; Fazzio, Robert T.; Pruthi, Sandhya; Whaley, Dana H.; Chen, Shigao; Fatemi, Mostafa

2015-01-01

Purpose or Objective To evaluate the performance of Comb-push Ultrasound Shear Elastography (CUSE) for classification of breast masses. Materials and Methods CUSE is an ultrasound-based quantitative two-dimensional shear wave elasticity imaging technique, which utilizes multiple laterally distributed acoustic radiation force (ARF) beams to simultaneously excite the tissue and induce shear waves. Female patients who were categorized as having suspicious breast masses underwent CUSE evaluations prior to biopsy. An elasticity estimate within the breast mass was obtained from the CUSE shear wave speed map. Elasticity estimates of various types of benign and malignant masses were compared with biopsy results. Results Fifty-four female patients with suspicious breast masses from our ongoing study are presented. Our cohort included 31 malignant and 23 benign breast masses. Our results indicate that the mean shear wave speed was significantly higher in malignant masses (6 ± 1.58 m/s) in comparison to benign masses (3.65 ± 1.36 m/s). Therefore, the stiffness of the mass quantified by the Young’s modulus is significantly higher in malignant masses. According to the receiver operating characteristic curve (ROC), the optimal cut-off value of 83 kPa yields 87.10% sensitivity, 82.61% specificity, and 0.88 for the area under the curve (AUC). Conclusion CUSE has the potential for clinical utility as a quantitative diagnostic imaging tool adjunct to B-mode ultrasound for differentiation of malignant and benign breast masses. PMID:25774978

Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

NASA Technical Reports Server (NTRS)

Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

2012-01-01

During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

Hygroscopic growth of particles nebulized from water-soluble extracts of PM2.5 aerosols over the Bay of Bengal: Influence of heterogeneity in air masses and formation pathways.

PubMed

Boreddy, S K R; Kawamura, Kimitaka; Bikkina, Srinivas; Sarin, M M

2016-02-15

Hygroscopic properties of water-soluble matter (WSM) extracted from fine-mode aerosols (PM2.5) in the marine atmospheric boundary layer of the Bay of Bengal (BoB) have been investigated during a cruise from 27th December 2008 to 30th January 2009. Hygroscopic growth factors were measured on particles generated from the WSM using an H-TDMA system with an initial dry size of 100 nm in the range of 5-95% relative humidity (RH). The measured hygroscopic growth of WSM at 90% RH, g(90%)WSM, were ranged from 1.11 to 1.74 (mean: 1.43 ± 0.19) over the northern BoB and 1.12 to 1.38 (mean: 1.25 ± 0.09) over the southern BoB. A key finding is that distinct hygroscopic growth factors are associated with the air masses from the Indo-Gangetic plains (IGP), which are clearly distinguishable from those associated with air masses from Southeast Asia (SEA). We found higher (lower) g(90%)WSM over the northern (southern) BoB, which were associated with an IGP (SEA) air masses, probably due the formation of high hygroscopic salts such as (NH4)2SO4. On the other hand, biomass burning influenced SEA air masses confer the low hygroscopic salts such as K2SO4, MgSO4, and organic salts over the southern BoB. Interestingly, mass fractions of water-soluble organic matter (WSOM) showed negative and positive correlations with g(90%)WSM over the northern and southern BoB, respectively, suggesting that the mixing state of organic and inorganic fractions could play a major role on the g(90%)WSM over the BoB. Further, WSOM/SO4(2-) mass ratios suggest that SO4(2-) dominates the g(90%)WSM over the northern BoB whereas WSOM fractions were important over the southern BoB. The present study also suggests that aging process could significantly alter the hygroscopic growth of aerosol particles over the BoB, especially over the southern BoB. Copyright © 2015 Elsevier B.V. All rights reserved.

[Influence of atmospheric transport on air pollutant levels at a mountain background site of East China].

PubMed

Su, Bin-Bin; Xu, Ju-Yang; Zhang, Ruo-Yu; Ji, Xian-Xin

2014-08-01

Transport characteristics of air pollutants transported to the background atmosphere of East China were investigated using HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory) 4.8 model driven by NCEP reanalysis data during June 2011 to May 2012. Based on the air pollutants monitoring data collected at the National atmospheric background monitoring station (Wuyishan station) in Fujian Province, characteristics of different clustered air masses as well as the origins of highly polluted air masses were further examined. The results showed that 65% of all the trajectories, in which air masses mainly passed over highly polluted area of East China, Jiangxi province and upper air in desert areas of Northwest China, carried polluted air to the station, while the rest of trajectories (35%) with air masses originated from ocean could effectively remove air pollutants at the Wuyishan station. However, the impact on the air pollutants for each air mass group varied with seasons. Elevated SO2 concentrations observed at the background station were mainly influenced by coal burning activities in Northern China during heating season. The high CO concentrations were likely associated with the pollutants emission in the process of coal production and consumption in Anhui province. The elevated NO(x), O3, PM10 and PM2.5 concentrations were mostly impacted by East China with high levels of air pollutants.

Air-sea fluxes of momentum and mass in the presence of wind waves

NASA Astrophysics Data System (ADS)

Zülicke, Christoph

2010-05-01

An air-sea interaction model (ASIM) is developed including the effect of wind waves on momentum and mass transfer. This includes the derivation of profiles of dissipation rate, flow speed and concentration from a certain height to a certain depth. Simplified assumptions on the turbulent closure, skin - bulk matching and the spectral wave model allow for an analytic treatment. Particular emphasis was put on the inclusion of primary (gravity) waves and secondary (capillary-gravity) waves. The model was tuned to match wall-flow theory and data on wave height and slope. Growing waves reduce the air-side turbulent stress and lead to an increasing drag coefficient. In the sea, breaking waves inject turbulent kinetic energy and accelerate the transfer. Cross-reference with data on wave-related momentum and energy flux, dissipation rate and transfer velocity was sufficient. The evaluation of ASIM allowed for the analytical calculation of bulk formulae for the wind-dependent gas transfer velocity including information on the air-side momentum transfer (drag coefficient) and the sea-side gas transfer (Dalton number). The following regimes have been identified: the smooth waveless regime with a transfer velocity proportional to (wind) × (diffusion)2-3, the primary wave regime with a wind speed dependence proportional to (wind)1-4 × (diffusion)1-2-(waveage)1-4 and the secondary wave regime including a more-than-linear wind speed dependence like (wind)15-8 × (diffusion)1-2 × (waveage)5-8. These findings complete the current understanding of air-sea interaction for medium winds between 2 and 20 m s^-1.

Fullerene Soot in Eastern China Air: Results from Soot Particle-Aerosol Mass Spectrometer

NASA Astrophysics Data System (ADS)

Wang, J.; Ge, X.; Chen, M.; Zhang, Q.; Yu, H.; Sun, Y.; Worsnop, D. R.; Collier, S.

2015-12-01

In this work, we present for the first time, the observation and quantification of fullerenes in ambient airborne particulate using an Aerodyne Soot Particle - Aerosol Mass Spectrometer (SP-AMS) deployed during 2015 winter in suburban Nanjing, a megacity in eastern China. The laser desorption and electron impact ionization techniques employed by the SP-AMS allow us to differentiate various fullerenes from other aerosol components. Mass spectrum of the identified fullerene soot is consisted by a series of high molecular weight carbon clusters (up to m/z of 2000 in this study), almost identical to the spectral features of commercially available fullerene soot, both with C70 and C60 clusters as the first and second most abundant species. This type of soot was observed throughout the entire study period, with an average mass loading of 0.18 μg/m3, accounting for 6.4% of the black carbon mass, 1.2% of the total organic mass. Temporal variation and diurnal pattern of fullerene soot are overall similar to those of black carbon, but are clearly different in some periods. Combining the positive matrix factorization, back-trajectory and analyses of the meteorological parameters, we identified the petrochemical industrial plants situating upwind from the sampling site, as the major source of fullerene soot. In this regard, our findings imply the ubiquitous presence of fullerene soot in ambient air of industry-influenced area, especially the oil and gas production regions. This study also offers new insights into the characterization of fullerenes from other environmental samples via the advanced SP-AMS technique.

Non-proximate mass spectrometry using a heated 1-m long PTFE tube and an air-tight APCI ion source.

PubMed

Usmanov, Dilshadbek T; Hiraoka, Kenzo; Wada, Hiroshi; Matsumura, Masaya; Sanada-Morimura, Sachiyo; Nonami, Hiroshi; Yamabe, Shinichi

2017-06-22

Direct and rapid trace-level gas analysis is highly needed in various fields such as safety and security, quality control, food analysis, and forensic medicine. In many cases, the real samples are bulky and are not accessible to the space-limited ion source of the mass spectrometer. In order to circumvent this problem, we developed an airtight atmospheric-pressure chemical ionization (APCI) ion source equipped with a flexible 1-m-long, 2-mm-i.d. PTFE sniffing tube. The ambient air bearing sample gas was sucked into the heated PTFE tube (130 °C) and was transported to the air-tight ion source without using any extra pumping system or a Venturi device. Analytes were ionized by an ac corona discharge located at 1.5 mm from the inlet of the mass spectrometer. By using the airtight ion source, all the ionized gas in the ion source was introduced into the vacuum of the mass spectrometer via only the evacuation of the mass spectrometer (1.6 l min -1 ). Sub-pg limits of detection were obtained for carbaryl and trinitrotoluene. Owing to its flexibility and high sensitivity, the sniffing tube coupled with a mass spectrometer can be used as the stethoscope for the high-sensitive gas analysis. The experimental results obtained for drugs, hydrogen peroxide and small alkanes were discussed by DFT calculations. Copyright © 2017 Elsevier B.V. All rights reserved.

A Comparison of Two Methods for Initiating Air Mass Back Trajectories

NASA Astrophysics Data System (ADS)

Putman, A.; Posmentier, E. S.; Faiia, A. M.; Sonder, L. J.; Feng, X.

2014-12-01

Lagrangian air mass tracking programs in back cast mode are a powerful tool for estimating the water vapor source of precipitation events. The altitudes above the precipitation site where particle's back trajectories begin influences the source estimation. We assume that precipitation comes from water vapor in condensing regions of the air column, so particles are placed in proportion to an estimated condensation profile. We compare two methods for estimating where condensation occurs and the resulting evaporation sites for 63 events at Barrow, AK. The first method (M1) uses measurements from a 35 GHz vertically resolved cloud radar (MMCR), and algorithms developed by Zhao and Garrett1 to calculate precipitation rate. The second method (M2) uses the Global Data Assimilation System reanalysis data in a lofting model. We assess how accurately M2, developed for global coverage, will perform in absence of direct cloud observations. Results from the two methods are statistically similar. The mean particle height estimated by M2 is, on average, 695 m (s.d. = 1800 m) higher than M1. The corresponding average vapor source estimated by M2 is 1.5⁰ (s.d. = 5.4⁰) south of M1. In addition, vapor sources for M2 relative to M1 have ocean surface temperatures averaging 1.1⁰C (s.d. = 3.5⁰C) warmer, and reported ocean surface relative humidities 0.31% (s.d. = 6.1%) drier. All biases except the latter are statistically significant (p = 0.02 for each). Results were skewed by events where M2 estimated very high altitudes of condensation. When M2 produced an average particle height less than 5000 m (89% of events), M2 estimated mean particle heights 76 m (s.d. = 741 m) higher than M1, corresponding to a vapor source 0.54⁰ (s.d. = 4.2⁰) south of M1. The ocean surface at the vapor source was an average of 0.35⁰C (s.d. = 2.35⁰C) warmer and ocean surface relative humidities were 0.02% (s.d. = 5.5%) wetter. None of the biases was statistically significant. If the vapor source

Physico-chemical characterization of grain dust in storage air of Bangalore.

PubMed

Mukherjee, A K; Nag, D P; Kakde, Y; Babu, K R; Prdkash, M N; Rao, S R

1998-06-01

An Anderson personal cascade impactor was used to study the particle mass size distribution in the storage air of two major grain storage centers in Bangalore. Dust levels in storage air as well as the personal exposures of workers were determined along with a detailed study on the particle size distribution. Protein and carbohydrate content of the dust were also determined respectively in the phosphate buffer saline (PBS) and water extracts by using the standard analytical techniques. Personal exposures in both of the grain storage centers have been found to be much above the limit prescribed by ACGIH (1995-96). But the results of particle size analysis showed a higher particle mass distribution in the non-respirable size range. The mass median diameters (MMD) of the storage air particulate of both the centers were found to be beyond the respirable range. Presence of protein and carbohydrate in the storage air dust is indicative of the existence of glyco-proteins, mostly of membrane origin.

Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures, phase 2

NASA Technical Reports Server (NTRS)

Hovel, H.; Woodall, J. M.

1976-01-01

Crystal growth procedures, fabrication techniques, and theoretical analysis were developed in order to make GaAlAs-GaAs solar cell structures which exhibit high performance at air mass 0 illumination and high temperature conditions.

Boundary layers at a dynamic interface: air-sea exchange of heat and mass

NASA Astrophysics Data System (ADS)

Szeri, Andrew

2017-11-01

Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and man-made gases involved in climate change. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble non-reactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity and gas concentration differences are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither of these quantities can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from remote measurements, which allows one to determine the gas transfer velocity, or gas flux per unit area if overall concentration differences are known. The approach is illustrated with conceptual examples.

Development of portable mass spectrometer with electron cyclotron resonance ion source for detection of chemical warfare agents in air.

PubMed

Urabe, Tatsuya; Takahashi, Kazuya; Kitagawa, Michiko; Sato, Takafumi; Kondo, Tomohide; Enomoto, Shuichi; Kidera, Masanori; Seto, Yasuo

2014-01-01

A portable mass spectrometer with an electron cyclotron resonance ion source (miniECRIS-MS) was developed. It was used for in situ monitoring of trace amounts of chemical warfare agents (CWAs) in atmospheric air. Instrumental construction and parameters were optimized to realize a fast response, high sensitivity, and a small body size. Three types of CWAs, i.e., phosgene, mustard gas, and hydrogen cyanide were examined to check if the mass spectrometer was able to detect characteristic elements and atomic groups. From the results, it was found that CWAs were effectively ionized in the miniECRIS-MS, and their specific signals could be discerned over the background signals of air. In phosgene, the signals of the 35Cl+ and 37Cl+ ions were clearly observed with high dose-response relationships in the parts-per-billion level, which could lead to the quantitative on-site analysis of CWAs. A parts-per-million level of mustard gas, which was far lower than its lethal dosage (LCt50), was successfully detected with a high signal-stability of the plasma ion source. It was also found that the chemical forms of CWAs ionized in the plasma, i.e., monoatomic ions, fragment ions, and molecular ions, could be detected, thereby enabling the effective identification of the target CWAs. Despite the disadvantages associated with miniaturization, the overall performance (sensitivity and response time) of the miniECRIS-MS in detecting CWAs exceeded those of sector-type ECRIS-MS, showing its potential for on-site detection in the future. Copyright © 2013 Elsevier B.V. All rights reserved.

Effects of water-contaminated air on blowoff limits of opposed jet hydrogen-air diffusion flames

NASA Technical Reports Server (NTRS)

Pellett, Gerald L.; Jentzen, Marilyn E.; Wilson, Lloyd G.; Northam, G. Burton

1988-01-01

The effects of water-contaminated air on the extinction and flame restoration of the central portion of N2-diluted H2 versus air counterflow diffusion flames are investigated using a coaxial tubular opposed jet burner. The results show that the replacement of N2 contaminant in air by water on a mole for mole basis decreases the maximum sustainable H2 mass flow, just prior to extinction, of the flame. This result contrasts strongly with the analogous substitution of water for N2 in a relatively hot premixed H2-O2-N2 flame, which was shown by Koroll and Mulpuru (1986) to lead to a significant, kinetically controlled increase in laminar burning velocity.

Spatial and temporal characteristics of air quality and air pollutants in 2013 in Beijing.

PubMed

Yan, Shujun; Cao, Hui; Chen, Ying; Wu, Chengzhen; Hong, Tao; Fan, Hailan

2016-07-01

Air pollution has become an ever more critical issue in Beijing in more recent years. In this study, we use the air quality index (AQI), corresponding primary pollutant types and meteorological data which are collected at 16 monitoring stations in Beijing between January 2013 and December, 2013 studying the spatial and temporal variations of air quality and air pollutants. The results show that PM2.5 was the most serious pollutant, followed by O3. The average PM2.5 mass concentration was 119.5 ± 13.8 μg m(-3) in Beijing. In addition, the air quality varies across different seasons. More specifically, winter season showed the worst air quality. Moreover, while particulate matter (PM2.5 and PM10) concentrations were relatively higher in the spring and winter seasons, gaseous pollutants (O3 and NO2) were more serious in the summer and autumn. In terms of spatial heterogeneity, the findings showed that AQI and PM2.5 concentrations were higher in south and lower in the north of the city, and the O3 showed exactly a pattern with the opposite direction-higher in the north and lower in the south. NO2 was found to have a greater impact on the central region compared with that in other regions. Furthermore, PM2.5 was found to be positively correlated with the relative humidity, but negatively correlated with wind speed and atmospheric pressure (P < 0.01). However, the dominant meteorological factors that influence the PM2.5 concentrations varied in different seasons. The results in this paper provide additional information for the effective control of the air pollution in Beijing.

Measurements of ozone and nonmethane hydrocarbons at Chichi-jima island, a remote island in the western Pacific: long-range transport of polluted air from the Pacific rim region

NASA Astrophysics Data System (ADS)

Kato, Shungo; Pochanart, Pakpong; Kajii, Yoshizumi

Chichi-jima island is located in the Pacific about 1000 km from the Japanese main island and is an ideal remote observatory from which to assess the long-range transport of polluted air from East Asia. The ozone concentration was measured from August 1997 to August 1998. Owing to the air mass change, the seasonal variation of ozone shows a distinct character: low concentration (about 13 ppbv) for the maritime air mass during the summer, and high concentration (about 40 ppbv) for the continental air mass during the winter. To assess the contribution of the long-range transport of polluted air during winter, nonmethane hydrocarbons were also measured in December 1999. Using backward trajectory analysis, the transport time of the air mass from the source area in the Pacific rim region was calculated for each sample. The concentration of hydrocarbons shows a clear negative correlation against the transport time. This analysis clearly shows the transport of polluted air, emitted in East Asia, to the Pacific during the winter. The plots of suitable hydrocarbon pairs showed that the decrease of hydrocarbon concentrations during winter is mainly caused by the mixing with clean background air.

Interrelationships Between Walkability, Air Pollution, Greenness, and Body Mass Index.

PubMed

James, Peter; Kioumourtzoglou, Marianthi-Anna; Hart, Jaime E; Banay, Rachel F; Kloog, Itai; Laden, Francine

2017-11-01

Recent studies have linked urban environmental factors and body mass index (BMI); however, such factors are often examined in isolation, ignoring correlations across exposures. Using data on Nurses' Health Study participants living in the Northeastern United States in 2006, we estimated associations between neighborhood walkability (a composite of population density, street connectivity, and business access), greenness (from satellite imagery), and ambient air pollution (from satellite-based spatiotemporally resolved PM2.5 predictions and weighted monthly average concentrations of NO2 from up to five nearest monitors) and self-reported BMI using generalized additive models, allowing for deviations from linearity using penalized splines. Among 23,435 women aged 60-87 years, we observed nonlinear associations between walkability and BMI and between PM2.5 and BMI in single-exposure models adjusted for age, race, and individual- and area-level socioeconomic status. When modeling all exposures simultaneously, only the association between walkability and BMI remained nonlinear and nonmonotonic. Increasing walkability was associated with increasing BMI at lower levels of walkability (walkability index <1.8), while increasing walkability was linked to lower BMI in areas of higher walkability (walkability index >1.8). A 10 percentile increase in walkability, right above 1.8 was associated with a 0.84% decrease in log BMI. The relationship between walkability and BMI existed only among younger participants (<71 years old). Neighborhood walkability was nonlinearly linked to lower BMI independent of air pollution and greenness. Our findings highlight the importance of accounting for nonlinear confounding by interrelated urban environmental factors when investigating associations between the environment and BMI.

Acute posttraumatic stress symptoms and depression after exposure to the 2005 Saskatchewan Centennial Air Show disaster: prevalence and predictors.

PubMed

Taylor, Steven; Asmundson, Gordon J G; Carleton, R Nicholas; Brundin, Peter

2007-01-01

The purpose of this study was to determine the prevalence of acute distress-that is, clinically significant posttraumatic stress symptoms (PTSS) and depression-and to identify predictors of each in a sample of people who witnessed a fatal aircraft collision at the 2005 Saskatchewan Centennial Air Show. Air Show attendees (N = 157) were recruited by advertisements in the local media and completed an Internet-administered battery of questionnaires. Based on previously established cut-offs, 22 percent respondents had clinically significant PTSS and 24 percent had clinically significant depressive symptoms. Clinically significant symptoms were associated with posttrauma impairment in social and occupational functioning. Acute distress was associated with several variables, including aspects of Air Show trauma exposure, severity of prior trauma exposure, low posttrauma social support (ie, negative responses by others), indices of poor coping (eg, intolerance of uncertainty, rumination about the trauma), and elevated scores on anxiety sensitivity, the personality trait of absorption, and dissociative tendencies. Results suggest that clinically significant acute distress is common in the aftermath of witnessed trauma. The statistical predictors (correlates) of acute distress were generally consistent with the results of studies of other forms of trauma. People with elevated scores on theoretical vulnerability factors (eg, elevated anxiety sensitivity) were particularly likely to develop acute distress.

Determination of trichloroanisole and trichlorophenol in wineries' ambient air by passive sampling and thermal desorption-gas chromatography coupled to tandem mass spectrometry.

PubMed

Camino-Sánchez, F J; Bermúdez-Peinado, R; Zafra-Gómez, A; Ruíz-García, J; Vílchez-Quero, J L

2015-02-06

The present paper describes the calibration of selected passive samplers used in the quantitation of trichlorophenol and trichloroanisole in wineries' ambient air, by calculating the corresponding sampling rates. The method is based on passive sampling with sorbent tubes and involves thermal desorption-gas chromatography-triple quadrupole mass spectrometry analysis. Three commercially available sorbents were tested using sampling cartridges with a radial design instead of axial ones. The best results were found for Tenax TA™. Sampling rates (R-values) for the selected sorbents were determined. Passive sampling was also used for accurately determining the amount of compounds present in the air. Adequate correlation coefficients between the mass of the target analytes and exposure time were obtained. The proposed validated method is a useful tool for the early detection of trichloroanisole and its precursor trichlorophenol in wineries' ambient air while avoiding contamination of wine or winery facilities. Copyright © 2015 Elsevier B.V. All rights reserved.

Rural southeast Texas air quality measurements during the 2006 Texas Air Quality Study.

PubMed

Schade, Gunnar W; Khan, Siraj; Park, Changhyoun; Boedeker, Ian

2011-10-01

The authors conducted air quality measurements of the criteria pollutants carbon monoxide, nitrogen oxides, and ozone together with meteorological measurements at a park site southeast of College Station, TX, during the 2006 Texas Air Quality Study II (TexAQS). Ozone, a primary focus of the measurements, was above 80 ppb during 3 days and above 75 ppb during additional 8 days in summer 2006, suggestive of possible violations of the ozone National Ambient Air Quality Standard (NAAQS) in this area. In concordance with other air quality measurements during the TexAQS II, elevated ozone mixing ratios coincided with northerly flows during days after cold front passages. Ozone background during these days was as high as 80 ppb, whereas southerly air flows generally provided for an ozone background lower than 40 ppb. Back trajectory analysis shows that local ozone mixing ratios can also be strongly affected by the Houston urban pollution plume, leading to late afternoon ozone increases of as high as 50 ppb above background under favorable transport conditions. The trajectory analysis also shows that ozone background increases steadily the longer a southern air mass resides over Texas after entering from the Gulf of Mexico. In light of these and other TexAQS findings, it appears that ozone air quality is affected throughout east Texas by both long-range and regional ozone transport, and that improvements therefore will require at least a regionally oriented instead of the current locally oriented ozone precursor reduction policies.

In situ mass analysis of particles by surface ionization mass spectrometry

NASA Technical Reports Server (NTRS)

Lassiter, W. S.; Moen, A. L.

1974-01-01

A qualitative study of the application of surface ionization and mass spectrometry to the in situ detection and constituent analysis of atmospheric particles was conducted. The technique consists of mass analysis of ions formed as a result of impingement of a stream of particles on a hot filament where, it is presumed, surface ionization takes place. Laboratory air particles containing K, Ca, and possibly hydrocarbons were detected. Other known particles such as Al2O3, Pb(NO3)2, and Cr2O3 were analyzed by detecting the respective metal atoms making up the particles. In some cases, mass numbers indicative of compounds making up the particles were detected showing surface ionization of particles sometimes leads to chemical analysis as well as to elemental analysis. Individual particles were detected, and it was shown that the technique is sensitive to Al2O3 particles with a mass of a few nanograms.

Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

PubMed

Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

2015-12-01

Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air.

Identification of PM10 air pollution origins at a rural background site

NASA Astrophysics Data System (ADS)

Reizer, Magdalena; Orza, José A. G.

2018-01-01

Trajectory cluster analysis and concentration weighted trajectory (CWT) approach have been applied to investigate the origins of PM10 air pollution recorded at a rural background site in North-eastern Poland (Diabla Góra). Air mass back-trajectories used in this study have been computed with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model for a 10-year period of 2006-2015. A cluster analysis grouped back-trajectories into 7 clusters. Most of the trajectories correspond to fast and moderately moving westerly and northerly flows (45% and 25% of the cases, respectively). However, significantly higher PM10 concentrations were observed for slow moving easterly (11%) and southerly (20%) air masses. The CWT analysis shows that high PM10 levels are observed at Diabla Góra site when air masses are originated and passed over the heavily industrialized areas in Central-Eastern Europe located to the south and south-east of the site.

Measurement of formaldehyde in clean air

NASA Astrophysics Data System (ADS)

Neitzert, Volker; Seiler, Wolfgang

1981-01-01

A method for the measurement of small amounts of formaldehyde in air has been developed. The method is based on the derivatization of HCHO with 2.4-Dinitrophenylhydrazine, forming 2.4-Dinitrophenylhydrazone, measured with GC-ECD-technique. HCHO is preconcentrated using a cryogenic sampling technique. The detection limit is 0.05 ppbv for a sampling volume of 200 liter. The method has been applied for measurements in continental and marine air masses showing HCHO mixing ratios of 0.4 - 5.0 ppbv and 0.2 - 1.0 ppbv, respectively. HCHO mixing ratios show diurnal variations with maximum values during the early afternoon and minimum values during the early morning. In continental air, HCHO mixing ratios are positively correlated with CO and SO2, indicating anthropogenic HCHO sources which are estimated to be 6-11 × 1012g/year-1 on a global scale.

Effect of real-time boundary wind conditions on the air flow and pollutant dispersion in an urban street canyon—Large eddy simulations

NASA Astrophysics Data System (ADS)

Zhang, Yun-Wei; Gu, Zhao-Lin; Cheng, Yan; Lee, Shun-Cheng

2011-07-01

Air flow and pollutant dispersion characteristics in an urban street canyon are studied under the real-time boundary conditions. A new scheme for realizing real-time boundary conditions in simulations is proposed, to keep the upper boundary wind conditions consistent with the measured time series of wind data. The air flow structure and its evolution under real-time boundary wind conditions are simulated by using this new scheme. The induced effect of time series of ambient wind conditions on the flow structures inside and above the street canyon is investigated. The flow shows an obvious intermittent feature in the street canyon and the flapping of the shear layer forms near the roof layer under real-time wind conditions, resulting in the expansion or compression of the air mass in the canyon. The simulations of pollutant dispersion show that the pollutants inside and above the street canyon are transported by different dispersion mechanisms, relying on the time series of air flow structures. Large scale air movements in the processes of the air mass expansion or compression in the canyon exhibit obvious effects on pollutant dispersion. The simulations of pollutant dispersion also show that the transport of pollutants from the canyon to the upper air flow is dominated by the shear layer turbulence near the roof level and the expansion or compression of the air mass in street canyon under real-time boundary wind conditions. Especially, the expansion of the air mass, which features the large scale air movement of the air mass, makes more contribution to the pollutant dispersion in this study. Comparisons of simulated results under different boundary wind conditions indicate that real-time boundary wind conditions produces better condition for pollutant dispersion than the artificially-designed steady boundary wind conditions.

A 100g Mass Comparator with an Improved Readability and Measuring Environment

NASA Astrophysics Data System (ADS)

Ueki, Masaaki; Sun, Jian-Xin; Ueda, Kazunaga

In order to achieve higher accuracy of the mass standard in the mass range equal to or less than 100g, it is necessary for a mass comparator in the range to have a relative sensitivity of the order of 1×10-9. For this purpose, a 111g capacity fully-automatic mass comparator has been renovated so that its readability is improved from 1 to 0.1µg. The mass comparator is also installed in an air-tight chamber originally developed by the NMIJ, so that it can be kept in stable environment, especially in the air of constant density. With these renovations, standard deviation of the mass comparisons is reduced and uncertainty of the air buoyancy corrections is lessened. This paper reports the features of the improved 100g mass comparator, the empirical method to evaluate its performance and the obtained results. As a result, the standard deviations of the mass difference measurements have been greatly improved to 0.22µg in the average with the chamber closed, compared with 0.97µg with the one open. The linearity of the comparator has been also verified by the mass difference measurements of weights at the six masses of 10, 20, 30, 50, 70 and 100g, and it confirms that the non-linearity errors of the comparator are within 0.28µg, showing good measuring performance.

Characteristics of tyre dust in polluted air: Studies by single particle mass spectrometry (ATOFMS)

NASA Astrophysics Data System (ADS)

Dall'Osto, Manuel; Beddows, David C. S.; Gietl, Johanna K.; Olatunbosun, Oluremi A.; Yang, Xiaoguang; Harrison, Roy M.

2014-09-01

There is a paucity of quantitative knowledge on the contributions of non-exhaust (abrasion and re-suspension) sources to traffic emissions. Abrasive emissions can be broadly categorised as tyre wear, brake wear and road dust/road surface wear. Current research often considers road dust and tyre dust as externally mixed particles, the former mainly composed of mineral matter and the latter solely composed of mainly organic matter and some trace elements. The aim of this work was to characterise tyre wear from both laboratory and field studies by using Aerosol Time-Of-Flight Mass Spectrometry (ATOFMS). Real-time single particle chemical composition was obtained from a set of rubber tyres rotating on a metal surface. Bimodal particle number size distributions peaking at 35 nm and 85 nm were obtained from SMPS/APS measurements over the range 6-20,000 nm. ATOFMS mass spectra of tyre wear in the particle size range 200-3000 nm diameter show peaks due to exo-sulphur compounds, nitrate, Zn and ions of high molecular weight (m/z > 100) attributed to organic polymers. Two large ATOFMS datasets collected from a number of outdoor studies were examined. The former was constituted of 48 road dust samples collected on the roads of London. The latter consisted of ATOFMS ambient air field studies from Europe, overall composed of more than 2,000,000 single particle mass spectra. The majority (95%) of tyre wear particles present in the road dust samples and atmospheric samples are internally mixed with metals (Li, Na, Ca, Fe, Ti), as well as phosphate. It is concluded that the interaction of tyres with the road surface creates particles internally mixed from two sources: tyre rubber and road surface materials. Measurements of the tyre rubber component alone may underestimate the contribution of tyre wear to concentrations of airborne particulate matter. The results presented are especially relevant for urban aerosol source apportionment and PM2.5 exposure assessment.

Columnar aerosol optical and radiative properties according to season and air mass transport pattern over East Asia.

PubMed

Noh, Young M; Müller, Detlef; Lee, Hanlim; Lee, Kwonho; Kim, Young Joon

2012-08-01

The column-integrated optical and radiative properties of aerosols in the downwind area of East Asia were investigated based on sun/sky radiometer measurements performed from February 2004 to June 2005 at Gwangju (35.23° N, 126.84° E) and Anmyeon (36.54° N, 126.33° E), Korea. The observed aerosol data were analyzed for differences among three seasons: spring (March-May), summer (June-August), and autumn/winter (September-February). The data were also categorized into five types depending on the air mass origin in arriving in the measurement sites: (a) from a northerly direction in spring (S(N)), (b) from a westerly direction in spring (S(W)), (c) cases with a low Ångström exponent (<0.8) in spring (dust), (d) from a northerly direction in autumn/winter (AW(N)), and (e) from a westerly direction during other seasons (AW(W)). The highest Ångström exponents (α) at Gwangju and Anmyeon were 1.43 ± 0.30 and 1.49 ± 0.20, respectively, observed in summer. The lowest column-mean single-scattering albedo (ω) at 440 nm observed at Gwangju and Anmyeon were 0.89 ± 0.02 and 0.88 ± 0.02, respectively, during a period marked by the advection of dust from the Asian continent. The highest ω values at Gwangju and Anmyeon were 0.95 ± 0.02 and 0.96 ± 0.02, respectively, observed in summer. Variations in the aerosol radiative-forcing efficiency (β) were related to the conditions of the air mass origin. The forcing efficiency in summer was -131.7 and -125.6 W m(-2) at the surface in Gwangju and Anmyeon, respectively. These values are lower than those under the atmospheric conditions of spring and autumn/winter. The highest forcing efficiencies in autumn/winter were -214.3 and -255.9 W m(-2) at the surface in Gwangju and Anmyeon, respectively, when the air mass was transported from westerly directions.

Investigating Local and Remote Terrestrial Influence on Air Masses at Contrasting Antarctic Sites Using Radon-222 and Back Trajectories

NASA Astrophysics Data System (ADS)

Chambers, S. D.; Choi, T.; Park, S.-J.; Williams, A. G.; Hong, S.-B.; Tositti, L.; Griffiths, A. D.; Crawford, J.; Pereira, E.

2017-12-01

We report on the first summer of high-sensitivity radon measurements from a two-filter detector at Jang Bogo Station (Terra Nova Bay) and contrast them with simultaneous observations at King Sejong Station (King George Island). King Sejong radon concentrations were characteristic of a marine baseline station (0.02-0.3 Bq m-3), whereas Jang Bogo values were highly variable (0.06-5.2 Bq m-3), mainly due to emissions from exposed coastal ground (estimated mean flux 0.09-0.11 atoms cm-2 s-1) and shallow atmospheric mixing depths. For wind speeds of ≤3.5 m s-1 the influence of local radon emissions became increasingly more prominent at both sites. A cluster analysis of back trajectories from King Sejong (62°S) revealed a fairly even distribution between air masses that had passed recently over South America, the Southern Ocean, and Antarctica, whereas at Jang Bogo (75°S) 80% of events had recently passed over the Ross Ice Shelf and West Antarctica, 12% were synoptically forced over Cape Adare, and 8% were associated with subsidence over the Antarctic interior and katabatic flow to the station. When cross-checked against radon concentrations, only half of the back trajectories ending at Jang Bogo that had indicated distant contact with nonpolar southern hemisphere continents within the past 10 days showed actual signs of terrestrial influence. A simple-to-implement technique based on high-pass filtered absolute humidity is developed to distinguish between predominantly katabatic, oceanic, and near-coastal air masses for characterization of trace gas and aerosol measurements at coastal East Antarctic sites.

Heat and mass transfer analogy for condensation of humid air in a vertical channel

NASA Astrophysics Data System (ADS)

Desrayaud, G.; Lauriat, G.

This study examines energy transport associated with liquid film condensation in natural convection flows driven by differences in density due to temperature and concentration gradients. The condensation problem is based on the thin-film assumptions. The most common compositional gradient, which is encountered in humid air at ambient temperature is considered. A steady laminar Boussinesq flow of an ideal gas-vapor mixture is studied for the case of a vertical parallel plate channel. New correlations for the latent and sensible Nusselt numbers are established, and the heat and mass transfer analogy between the sensible Nusselt number and Sherwood number is demonstrated.

Carbonaceous aerosols in the air masses transported from Indochina to Taiwan: Long-term observation at Mt. Lulin

NASA Astrophysics Data System (ADS)

Chuang, Ming-Tung; Lee, Chung-Te; Chou, Charles C.-K.; Lin, Neng-Huei; Sheu, Guey-Rong; Wang, Jia-Lin; Chang, Shuenn-Chin; Wang, Sheng-Hsiang; Chi, Kai Hsien; Young, Chea-Yuan; Huang, Hill; Chen, Horng-Wen; Weng, Guo-Hau; Lai, Sin-Yu; Hsu, Shao-Peng; Chang, Yu-Jia; Chang, Jia-Hon; Wu, Xyue-Chang

2014-06-01

Eight carbonaceous fractions from aerosols were resolved using the Interagency Monitoring of Protected Visual Environments (IMPROVE) protocol (Chow et al., 1993). The aerosols were collected at the Mountain Lulin Atmospheric Background Station (Mt. Lulin, 2862 m a.s.l.) in Central Taiwan from April 2003 to April 2012. The monthly and yearly levels of organic carbon (OC) and elemental carbon (EC) varied consistently with PM2.5 mass concentrations during biomass burning (BB) period. The highest monthly carbonaceous content was observed in March and the highest yearly carbonaceous concentration was observed in 2007. This finding is consistent with the BB activity in Indochina and indicates that carbonaceous content is a major component of BB aerosols. Lee et al. (2011) classified four trajectory groups from the air masses transported to Mt. Lulin during the aerosol collection period. For the air masses transported from the BB area (the BB group) in Indochina, the carbonaceous content was greater than the water-soluble ions in PM2.5, and the OC/EC ratio (4.8 ± 1.5) was high. With EC as the indicator of primary emission sources, the air masses of the BB group were found to contain more primary than secondary OC. The Anthropogenic group (from the local and free troposphere below the 700-hPa pressure level over the Asian continent) probably contained more secondary than primary OC or the sources of OC and EC could be quite diverse. The average char-EC/soot-EC (low-temperature EC/high-temperature EC) ratios were 3.9 ± 3.5, 0.4 ± 0.4, 0.9 ± 0.8, and 0.3 ± 0.4 for the trajectory groups BB, SNBB (from BB source areas during the non-BB period), Anthropogenic, and FT (from the oceanic area and the free troposphere above the 700-hPa pressure level over the Asian continent), respectively. The presence of a high char-EC/soot-EC ratio confirmed the correct classification of the BB group, whereas the low ratios from the other groups indicated the strong influence of vehicle

Analysis of enantiomeric and non-enantiomeric monoterpenes in plant emissions using portable dynamic air sampling/solid-phase microextraction (PDAS-SPME) and chiral gas chromatography/mass spectrometry

NASA Astrophysics Data System (ADS)

Yassaa, Noureddine; Williams, Jonathan

A portable dynamic air sampler (PDAS) using a porous polymer solid-phase microextraction (SPME) fibre has been validated for the determination of biogenic enantiomeric and non-enantiomeric monoterpenes in air. These compounds were adsorbed in the field, and then thermally desorbed at 250 °C in a gas chromatograph injector port connected via a β-cyclodextrin capillary separating column to a mass spectrometer. The optimized method has been applied for investigating the emissions of enantiomeric monoterpenes from Pseudotsuga menziesii (Douglas-fir), Rosmarinus officinalis (Rosemary) and Lavandula lanata (Lavender) which were selected as representative of coniferous trees and aromatic plants, respectively. The enantiomers of α-pinene, sabinene, camphene, δ-3-carene, β-pinene, limonene, β-phellandrene, 4-carene and camphor were successfully determined in the emissions from the three plants. While Douglas-fir showed a strong predominance toward (-)-enantiomers, Rosemary and Lavender demonstrated a large variation in enantiomeric distribution of monoterpenes. The simplicity, rapidity and sensitivity of dynamic sampling with porous polymer coated SPME fibres coupled to chiral capillary gas chromatography/mass spectrometry (GC/MS) makes this method potentially useful for in-field investigations of atmosphere-biosphere interactions and studies of optically explicit atmospheric chemistry.

Cyclic organic peroxides identification and trace analysis by Raman microscopy and open-air chemical ionization mass spectrometry

NASA Astrophysics Data System (ADS)

Pena-Quevedo, Alvaro Javier

The persistent use of cyclic organic peroxides in explosive devices has increased the interest in study these compounds. Development of methodologies for the detection of triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD) has become an urgent priority. However, differences in physical properties between cyclic organic peroxides make difficult the development of a general method for peroxide analysis and detection. Following this urgency, the first general technique for the analysis of any peroxide, regarding its structural differences is reported. Characterization and detection of TATP and HMTD was performed using an Open-Air Chemical Ionization High-Resolution Time-of-Flight Mass Spectrometer. The first spectrometric analysis for tetramethylene diperoxide dicarbamide (TMDD) and other nitrogen based peroxides using Raman Microscopy and Mass Spectrometry is reported. Analysis of cyclic peroxides by GC-MS was also conducted to compare results with OACI-HRTOF data. In the OACI mass spectrum, HMTD showed a clear signal at m/z 209 MH + and a small adduct peak at m/z 226 [M+NH4]+ that allowed its detection in commercial standard solutions and lab made standards. TMDD presented a molecular peak of m/z 237 MH+ and an adduct peak of m/z 254 [M+NH4]+. TATP showed a single peak at m/z 240 [M+NH4]+, while the peak of m/z 223 or 222 was completely absent. This evidence suggests that triperoxides are stabilized by the ammonium ion. TATP samples with deuterium enrichment were analyzed to compare results that could differentiate from HMTD. Raman microscopy was used as a complementary characterization method and was an essential tool for cyclic peroxides identification, particularly for those which could not be extensively purified. All samples were characterized by Raman spectroscopy to confirm the Mass Spectrometry results. Peroxide O-O vibrations were observed around 750-970 cm-1. D18-TATP studies had identified ketone triperoxide nu(O-O) vibration around

Remediation of saturated soil contaminated with petroleum products using air sparging with thermal enhancement.

PubMed

Mohamed, A M I; El-menshawy, Nabil; Saif, Amany M

2007-05-01

Pollutants in the form of non-aqueous phase liquids (NAPLs), such as petroleum products, pose a serious threat to the soil and groundwater. A mathematical model was derived to study the unsteady pollutant concentrations through water saturated contaminated soil under air sparging conditions for different NAPLs and soil properties. The comparison between the numerical model results and the published experimental results showed acceptable agreement. Furthermore, an experimental study was conducted to remove NAPLs from the contaminated soil using the sparging air technique, considering the sparging air velocity, air temperature, soil grain size and different contaminant properties. This study showed that sparging air at ambient temperature through the contaminated soil can remove NAPLs, however, employing hot air sparging can provide higher contaminant removal efficiency, by about 9%. An empirical correlation for the volatilization mass transfer coefficient was developed from the experimental results. The dimensionless numbers used were Sherwood number (Sh), Peclet number (Pe), Schmidt number (Sc) and several physical-chemical properties of VOCs and porous media. Finally, the estimated volatilization mass transfer coefficient was used for calculation of the influence of heated sparging air on the spreading of the NAPL plume through the contaminated soil.

[Determination of short-chain chlorinated paraffins in ambient air using high-volume sampling combined with high resolutimi gas chromatography-electron capture negative ion-low resolution mass spectrometry].

PubMed

Shi, Loimeng; Gao, Yuan; Hou, Xiaohong; Zhang, Haijun; Zhang, Yichi; Chen, Jiping

2016-02-01

An analytical method for quantifying short-chain chlorinated paraffins (SCCPs) in ambient air using high-volume sampling combined with high resolution gas chromatography-electron capture negative ion-low resolution mass spectrometry ( HRGC-ECNI-LRMS) was developed. An acidified silica gel column and a basic alumina column were used to optimize the cleanup procedures. The results showed a good linearity (R2>0. 99) between the total response factors and the degree of chlorination of SCCPs in the content range of 58. 1%-63. 3%. The limits of detection (S/N ≥3) and the limits of quantification (S/N ≥ 10) were 4. 2 and 12 µg, respectively. The method detection limit (MDL) for SCCPs was 0. 34 ng/m3 (n = 7). The recoveries of SCCPs in air samples were in the range of 81. 9% to 94. 2%. It is demonstrated that the method is suitable for the quantitative analysis of SCCPs in air samples.

SAM-CAAM: A Concept for Acquiring Systematic Aircraft Measurements to Characterize Aerosol Air Masses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kahn, Ralph A.; Berkoff, Tim A.; Brock, Charles

A modest operational program of systematic aircraft measurements can resolve key satellite aerosol data record limitations. Satellite observations provide frequent global aerosol amount maps but offer only loose aerosol property constraints needed for climate and air quality applications. In this paper, we define and illustrate the feasibility of flying an aircraft payload to measure key aerosol optical, microphysical, and chemical properties in situ. The flight program could characterize major aerosol airmass types statistically, at a level of detail unobtainable from space. It would 1) enhance satellite aerosol retrieval products with better climatology assumptions and 2) improve translation between satellite-retrieved opticalmore » properties and species-specific aerosol mass and size simulated in climate models to assess aerosol forcing, its anthropogenic components, and other environmental impacts. As such, Systematic Aircraft Measurements to Characterize Aerosol Air Masses (SAM-CAAM) could add value to data records representing several decades of aerosol observations from space; improve aerosol constraints on climate modeling; help interrelate remote sensing, in situ, and modeling aerosol-type definitions; and contribute to future satellite aerosol missions. Fifteen required variables are identified and four payload options of increasing ambition are defined to constrain these quantities. “Option C” could meet all the SAM-CAAM objectives with about 20 instruments, most of which have flown before, but never routinely several times per week, and never as a group. Aircraft integration and approaches to data handling, payload support, and logistical considerations for a long-term, operational mission are discussed. Finally, SAM-CAAM is feasible because, for most aerosol sources and specified seasons, particle properties tend to be repeatable, even if aerosol loading varies.« less

SAM-CAAM: A Concept for Acquiring Systematic Aircraft Measurements to Characterize Aerosol Air Masses

DOE PAGES

Kahn, Ralph A.; Berkoff, Tim A.; Brock, Charles; ...

2017-10-30

A modest operational program of systematic aircraft measurements can resolve key satellite aerosol data record limitations. Satellite observations provide frequent global aerosol amount maps but offer only loose aerosol property constraints needed for climate and air quality applications. In this paper, we define and illustrate the feasibility of flying an aircraft payload to measure key aerosol optical, microphysical, and chemical properties in situ. The flight program could characterize major aerosol airmass types statistically, at a level of detail unobtainable from space. It would 1) enhance satellite aerosol retrieval products with better climatology assumptions and 2) improve translation between satellite-retrieved opticalmore » properties and species-specific aerosol mass and size simulated in climate models to assess aerosol forcing, its anthropogenic components, and other environmental impacts. As such, Systematic Aircraft Measurements to Characterize Aerosol Air Masses (SAM-CAAM) could add value to data records representing several decades of aerosol observations from space; improve aerosol constraints on climate modeling; help interrelate remote sensing, in situ, and modeling aerosol-type definitions; and contribute to future satellite aerosol missions. Fifteen required variables are identified and four payload options of increasing ambition are defined to constrain these quantities. “Option C” could meet all the SAM-CAAM objectives with about 20 instruments, most of which have flown before, but never routinely several times per week, and never as a group. Aircraft integration and approaches to data handling, payload support, and logistical considerations for a long-term, operational mission are discussed. Finally, SAM-CAAM is feasible because, for most aerosol sources and specified seasons, particle properties tend to be repeatable, even if aerosol loading varies.« less

Size-Segregated Aerosol Composition and Mass Loading of Atmospheric Particles as Part of the Pacific Northwest 2001(PNW2001) Air Quality Study In Puget Sound

NASA Astrophysics Data System (ADS)

Disselkamp, R. S.; Barrie, L. A.; Shutthanadan, S.; Cliff, S.; Cahill, T.

2001-12-01

In mid-August, 2001, an aircraft-based air-quality study was performed in the Puget Sound, WA, area entitled PNW2001 (http://www.pnl.gov/pnw2001). The objectives of this field campaign were the following: 1. reveal information about the 3-dimensional distribution of ozone, its gaseous precursors and fine particulate matter during weather conditions favoring air pollution; 2. derive information about the accuracy of urban and biogenic emissions inventories that are used to drive the air quality forecast models; and 3. examine the accuracy of modeled ozone concentration with that observed. In support of these efforts, we collected time-averaged ( { ~}10 minute averages), size-segregated, aerosol composition and mass-loading information using ex post facto analysis techniques of synchrotron x-ray fluorescence (s-XRF), proton induced x-ray emissions(PIXE), proton elastic scattering (PESA), and scanning transmission ion microscopy (STIM). This is the first time these analysis techniques have been used together on samples collected from aircraft using an optimized 3-stage rotating drum impactor. In our presentation, we will discuss the aerosol components in three aerosol size fractions as identified by statistical analysis of multielemental data (including total mass, H, Na, Mg, Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Pb) and relate variations in these components to physical aerosol properties, other gaseous trace constituents and to air mass origin.

Dependence of air masses type on PBL vertical structure retrieved at the Mace Head station during EUCAARI campaign.

NASA Astrophysics Data System (ADS)

Milroy, Conor; Martucci, Giovanni; O'Dowd, Colin

2010-05-01

During the EUCAARI Intensive Observing Period held at the Mace Head GAW station from mid-May to mid-June, 2008, the PBL depth has been continuously measured by two ceilometers (Vaisala CL31 and Jenoptik CHM15K) and a microwave radiometer (RPG-HATPRO). The Lidar-Ceilometer, through the gradients in aerosol backscatter profiles, and the microwave profiler, through gradients in the specific humidity profiles, were used to remotely-sense the boundary layer structure. An automatic, newly developed Temporal Height-Tracking (THT) algorithm (Martucci et al., 2010) have been applied to both type of instruments data to retrieve the 2-layered structure of the local marine boundary layer. The two layers are defined as a lower, well mixed layer, i.e. the surface mixed layer, and the layer occupying the region below the free Troposphere inversion, i.e. the decoupled residual or convective layer. A categorization of the incoming air masses has been performed based on their origins and been used to asses the correlation with the PBL depths. The study confirmed the dependence of PBL vertical structure on different air masses and different type of advected aerosol.

Simulation of heat and mass transfer processes in the experimental section of the air-condensing unit of Scientific Production Company "Turbocon"

NASA Astrophysics Data System (ADS)

Artemov, V. I.; Minko, K. B.; Yan'kov, G. G.; Kiryukhin, A. V.

2016-05-01

A mathematical model was developed to be used for numerical analysis of heat and mass transfer processes in the experimental section of the air condenser (ESAC) created in the Scientific Production Company (SPC) "Turbocon" and mounted on the territory of the All-Russia Thermal Engineering Institute. The simulations were performed using the author's CFD code ANES. The verification of the models was carried out involving the experimental data obtained in the tests of ESAC. The operational capability of the proposed models to calculate the processes in steam-air mixture and cooling air and algorithms to take into account the maldistribution in the various rows of tube bundle was shown. Data on the influence of temperature and flow rate of the cooling air on the pressure in the upper header of ESAC, effective heat transfer coefficient, steam flow distribution by tube rows, and the dimensions of the ineffectively operating zones of tube bundle for two schemes of steam-air mixture flow (one-pass and two-pass ones) were presented. It was shown that the pressure behind the turbine (in the upper header) increases significantly at increase of the steam flow rate and reduction of the flow rate of cooling air and its temperature rise, and the maximum value of heat transfer coefficient is fully determined by the flow rate of cooling air. Furthermore, the steam flow rate corresponding to the maximum value of heat transfer coefficient substantially depends on the ambient temperature. The analysis of the effectiveness of the considered schemes of internal coolant flow was carried out, which showed that the two-pass scheme is more effective because it provides lower pressure in the upper header, despite the fact that its hydraulic resistance at fixed flow rate of steam-air mixture is considerably higher than at using the one-pass schema. This result is a consequence of the fact that, in the two-pass scheme, the condensation process involves the larger internal surface of tubes

Analysis of air-, moisture- and solvent-sensitive chemical compounds by mass spectrometry using an inert atmospheric pressure solids analysis probe.

PubMed

Mosely, Jackie A; Stokes, Peter; Parker, David; Dyer, Philip W; Messinis, Antonis M

2018-02-01

A novel method has been developed that enables chemical compounds to be transferred from an inert atmosphere glove box and into the atmospheric pressure ion source of a mass spectrometer whilst retaining a controlled chemical environment. This innovative method is simple and cheap to implement on some commercially available mass spectrometers. We have termed this approach inert atmospheric pressure solids analysis probe ( iASAP) and demonstrate the benefit of this methodology for two air-/moisture-sensitive chemical compounds whose characterisation by mass spectrometry is now possible and easily achieved. The simplicity of the design means that moving between iASAP and standard ASAP is straightforward and quick, providing a highly flexible platform with rapid sample turnaround.

Air-Adapted Methanosarcina acetivorans Shows High Methane Production and Develops Resistance against Oxygen Stress

PubMed Central

Jasso-Chávez, Ricardo; Santiago-Martínez, M. Geovanni; Lira-Silva, Elizabeth; Pineda, Erika; Zepeda-Rodríguez, Armando; Belmont-Díaz, Javier; Encalada, Rusely; Saavedra, Emma; Moreno-Sánchez, Rafael

2015-01-01

Methanosarcina acetivorans, considered a strict anaerobic archaeon, was cultured in the presence of 0.4–1% O2 (atmospheric) for at least 6 months to generate air-adapted cells; further, the biochemical mechanisms developed to deal with O2 were characterized. Methane production and protein content, as indicators of cell growth, did not change in air-adapted cells respect to cells cultured under anoxia (control cells). In contrast, growth and methane production significantly decreased in control cells exposed for the first time to O2. Production of reactive oxygen species was 50 times lower in air-adapted cells versus control cells, suggesting enhanced anti-oxidant mechanisms that attenuated the O2 toxicity. In this regard, (i) the transcripts and activities of superoxide dismutase, catalase and peroxidase significantly increased; and (ii) the thiol-molecules (cysteine + coenzyme M-SH + sulfide) and polyphosphate contents were respectively 2 and 5 times higher in air-adapted cells versus anaerobic-control cells. Long-term cultures (18 days) of air-adapted cells exposed to 2% O2 exhibited the ability to form biofilms. These data indicate that M. acetivorans develops multiple mechanisms to contend with O2 and the associated oxidative stress, as also suggested by genome analyses for some methanogens. PMID:25706146

Cumulative ventilation air drying potential as an indication of dry mass content in wastewater sludge in a thin-layer solar drying facility

NASA Astrophysics Data System (ADS)

Krawczyk, Piotr

2013-12-01

Controlling low-temperature drying facilities which utilise nonprepared air is quite difficult, due to very large variability of ventilation air parameters - both in daily and seasonal cycles. The paper defines the concept of cumulative drying potential of ventilation air and presents experimental evidence that there is a relation between this parameter and condition of the dried matter (sewage sludge). Knowledge on current dry mass content in the dried matter (sewage sludge) provides new possibilities for controlling such systems. Experimental data analysed in the paper was collected in early 2012 during operation of a test solar drying facility in a sewage treatment plant in Błonie near Warsaw, Poland.

Community air monitoring for pesticides-part 2: multiresidue determination of pesticides in air by gas chromatography, gas chromatography-mass spectrometry, and liquid chromatography-mass spectrometry.

PubMed

Hengel, Matt; Lee, P

2014-03-01

Two multiresidue methods were developed to determine pesticides in air collected in California. Pesticides were trapped using XAD-4 resin and extracted with ethyl acetate. Based on an analytical method from the University of California Davis Trace Analytical Laboratory, pesticides were detected by analyzing the extract by gas chromatography-mass spectrometry (GC-MS) to determine chlorothalonil, chlorthal-dimethyl, cycloate, dicloran, dicofol, EPTC, ethalfluralin, iprodione, mefenoxam, metolachlor, PCNB, permethrin, pronamide, simazine, trifluralin, and vinclozolin. A GC with a flame photometric detector was used to determine chlorpyrifos, chlorpyrifos oxon, diazinon, diazinon oxon, dimethoate, dimethoate oxon, fonophos, fonophos oxon, malathion, malathion oxon, naled, and oxydemeton. Trapping efficiencies ranged from 78 to 92 % for low level (0.5 μg) and 37-104 % for high level (50 and 100 μg) recoveries. Little to no degradation of compounds occurred over 31 days; recoveries ranged from 78 to 113 %. In the California Department of Food and Agriculture (CDFA) method, pesticides were detected by analyzing the extract by GC-MS to determine chlorothalonil, chlorpyrifos, cypermethrin, dichlorvos, dicofol, endosulfan 1, endosulfan sulfate, oxyfluorfen, permethrin, propargite, and trifluralin. A liquid chromatograph coupled to a MS was used to determine azinphos-methyl, chloropyrifos oxon, DEF, diazinon, diazinon oxon, dimethoate, dimethoate oxon, diuron, EPTC, malathion, malathion oxon, metolachlor, molinate, norflurazon, oryzalin, phosmet, propanil, simazine and thiobencarb. Trapping efficiencies for compounds determined by the CDFA method ranged from 10 to 113, 22 to 114, and 56 to 132 % for 10, 5, and 2 μg spikes, respectively. Storage tests yielded 70-170 % recovery for up to 28 days. These multiresidue methods represent flexible, sensitive, accurate, and cost-effective ways to determine residues of various pesticides in ambient air.

Development and validation of a sensitive thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method for the determination of phosgene in air samples.

PubMed

Juillet, Y; Dubois, C; Bintein, F; Dissard, J; Bossée, A

2014-08-01

A new rapid, sensitive and reliable method was developed for the determination of phosgene in air samples using thermal desorption (TD) followed by gas chromatography-mass spectrometry (GC-MS). The method is based on a fast (10 min) active sampling of only 1 L of air onto a Tenax® GR tube doped with 0.5 mL of derivatizing mixture containing dimercaptotoluene and triethylamine in hexane solution. Validation of the TD-GC-MS method showed a low limit of detection (40 ppbv), acceptable repeatability, intermediate fidelity (relative standard deviation within 12 %) and excellent accuracy (>95%). Linearity was demonstrated for two concentration ranges (0.04 to 2.5 ppmv and 2.5 to 10 ppmv) owing to variation of derivatization recovery between low and high concentration levels. Due to its simple on-site implementation and its close similarity with recommended operating procedure (ROP) for chemical warfare agents vapour sampling, the method is particularly useful in the process of verification of the Chemical Weapons Convention.

Air-sea heat flux control on the Yellow Sea Cold Water Mass intensity and implications for its prediction

NASA Astrophysics Data System (ADS)

Zhu, Junying; Shi, Jie; Guo, Xinyu; Gao, Huiwang; Yao, Xiaohong

2018-01-01

The Yellow Sea Cold Water Mass (YSCWM), which occurs during summer in the central Yellow Sea, plays an important role in the hydrodynamic field, nutrient cycle and biological species. Based on water temperature observations during the summer from 1978 to 1998 in the western Yellow Sea, five specific YSCWM years were identified, including two strong years (1984 and 1985), two weak years (1989 and 1995) and one normal year (1992). Using a three-dimensional hydrodynamic model, the YSCWM formation processes in these five years were simulated and compared with observations. In general, the YSCWM began forming in spring, matured in summer and gradually disappeared in autumn of every year. The 8 °C isotherm was used to indicate the YSCWM boundary. The modelled YSCWM areas in the two strong years were approximately two times larger than those in the two weak years. Based on the simulations in the weak year of 1995, ten numerical experiments were performed to quantify the key factors influencing the YSCWM intensity by changing the initial water condition in the previous autumn, air-sea heat flux, wind, evaporation, precipitation and sea level pressure to those in the strong year of 1984, respectively. The results showed that the air-sea heat flux was the dominant factor influencing the YSCWM intensity, which contributed about 80% of the differences of the YSCWM average water temperature at a depth of 50 m. In addition, the air-sea heat flux in the previous winter had a determining effect, contributing more than 50% of the differences between the strong and weak YSCWM years. Finally, a simple formula for predicting the YSCWM intensity was established by using the key influencing factors, i.e., the sea surface temperature before the cooling season and the air-sea heat flux during the cooling season from the previous December to the current February. With this formula, instead of a complicated numerical model, we were able to roughly predict the YSCWM intensity for the

Measurement of spatial and temporal variation in volatile hazardous air pollutants in Tacoma, Washington, using a mobile membrane introduction mass spectrometry (MIMS) system.

PubMed

Davey, Nicholas G; Fitzpatrick, Cole T E; Etzkorn, Jacob M; Martinsen, Morten; Crampton, Robert S; Onstad, Gretchen D; Larson, Timothy V; Yost, Michael G; Krogh, Erik T; Gilroy, Michael; Himes, Kathy H; Saganić, Erik T; Simpson, Christopher D; Gill, Christopher G

2014-09-19

The objective of this study was to use membrane introduction mass spectrometry (MIMS), implemented on a mobile platform, in order to provide real-time, fine-scale, temporally and spatially resolved measurements of several hazardous air pollutants. This work is important because there is now substantial evidence that fine-scale spatial and temporal variations of air pollutant concentrations are important determinants of exposure to air pollution and adverse health outcomes. The study took place in Tacoma, WA during periods of impaired air quality in the winter and summer of 2008 and 2009. Levels of fine particles were higher in winter compared to summer, and were spatially uniform across the study area. Concentrations of vapor phase pollutants measured by membrane introduction mass spectrometry (MIMS), notably benzene and toluene, had relatively uniform spatial distributions at night, but exhibited substantial spatial variation during the day-daytime levels were up to 3-fold higher at traffic-impacted locations compared to a reference site. Although no direct side-by-side comparison was made between the MIMS system and traditional fixed site monitors, the MIMS system typically reported higher concentrations of specific VOCs, particularly benzene, ethylbenzene and naphthalene, compared to annual average concentrations obtained from SUMA canisters and gas chromatographic analysis at the fixed sites.

Performance analysis of an air drier for a liquid dehumidifier solar air conditioning system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Queiroz, A.G.; Orlando, A.F.; Saboya, F.E.M.

1988-05-01

A model was developed for calculating the operating conditions of a non-adiabatic liquid dehumidifier used in solar air conditioning systems. In the experimental facility used for obtaining the data, air and triethylene glycol circulate countercurrently outside staggered copper tubes which are the filling of an absorption tower. Water flows inside the copper tubes, thus cooling the whole system and increasing the mass transfer potential for drying air. The methodology for calculating the mass transfer coefficient is based on the Merkel integral approach, taking into account the lowering of the water vapor pressure in equilibrium with the water glycol solution.

Transparent air filter for high-efficiency PM2.5 capture.

PubMed

Liu, Chong; Hsu, Po-Chun; Lee, Hyun-Wook; Ye, Meng; Zheng, Guangyuan; Liu, Nian; Li, Weiyang; Cui, Yi

2015-02-16

Particulate matter (PM) pollution has raised serious concerns for public health. Although outdoor individual protection could be achieved by facial masks, indoor air usually relies on expensive and energy-intensive air-filtering devices. Here, we introduce a transparent air filter for indoor air protection through windows that uses natural passive ventilation to effectively protect the indoor air quality. By controlling the surface chemistry to enable strong PM adhesion and also the microstructure of the air filters to increase the capture possibilities, we achieve transparent, high air flow and highly effective air filters of ~90% transparency with >95.00% removal of PM2.5 under extreme hazardous air-quality conditions (PM2.5 mass concentration >250 μg m(-3)). A field test in Beijing shows that the polyacrylonitrile transparent air filter has the best PM2.5 removal efficiency of 98.69% at high transmittance of ~77% during haze occurrence.

Transparent air filter for high-efficiency PM2.5 capture

NASA Astrophysics Data System (ADS)

Liu, Chong; Hsu, Po-Chun; Lee, Hyun-Wook; Ye, Meng; Zheng, Guangyuan; Liu, Nian; Li, Weiyang; Cui, Yi

2015-02-01

Particulate matter (PM) pollution has raised serious concerns for public health. Although outdoor individual protection could be achieved by facial masks, indoor air usually relies on expensive and energy-intensive air-filtering devices. Here, we introduce a transparent air filter for indoor air protection through windows that uses natural passive ventilation to effectively protect the indoor air quality. By controlling the surface chemistry to enable strong PM adhesion and also the microstructure of the air filters to increase the capture possibilities, we achieve transparent, high air flow and highly effective air filters of ~90% transparency with >95.00% removal of PM2.5 under extreme hazardous air-quality conditions (PM2.5 mass concentration >250 μg m-3). A field test in Beijing shows that the polyacrylonitrile transparent air filter has the best PM2.5 removal efficiency of 98.69% at high transmittance of ~77% during haze occurrence.

Identification of aerosol types over an urban site based on air-mass trajectory classification

NASA Astrophysics Data System (ADS)

Pawar, G. V.; Devara, P. C. S.; Aher, G. R.

2015-10-01

Columnar aerosol properties retrieved from MICROTOPS II Sun Photometer measurements during 2010-2013 over Pune (18°32‧N; 73°49‧E, 559 m amsl), a tropical urban station in India, are analyzed to identify aerosol types in the atmospheric column. Identification/classification is carried out on the basis of dominant airflow patterns, and the method of discrimination of aerosol types on the basis of relation between aerosol optical depth (AOD500 nm) and Ångström exponent (AE, α). Five potential advection pathways viz., NW/N, SW/S, N, SE/E and L have been identified over the observing site by employing the NOAA-HYSPLIT air mass back trajectory analysis. Based on AE against AOD500 nm scatter plot and advection pathways followed five major aerosol types viz., continental average (CA), marine continental average (MCA), urban/industrial and biomass burning (UB), desert dust (DD) and indeterminate or mixed type (MT) have been identified. In winter, sector SE/E, a representative of air masses traversed over Bay of Bengal and Eastern continental Indian region has relatively small AOD (τpλ = 0.43 ± 0.13) and high AE (α = 1.19 ± 0.15). These values imply the presence of accumulation/sub-micron size anthropogenic aerosols. During pre-monsoon, aerosols from the NW/N sector have high AOD (τpλ = 0.61 ± 0.21), and low AE (α = 0.54 ± 0.14) indicating an increase in the loading of coarse-mode particles over Pune. Dominance of UB type in winter season for all the years (i.e. 2010-2013) may be attributed to both local/transported aerosols. During pre-monsoon seasons, MT is the dominant aerosol type followed by UB and DD, while the background aerosols are insignificant.

33 CFR 100.736 - Annual Fort Myers Beach air show; Fort Myers Beach, FL.

Code of Federal Regulations, 2010 CFR

2010-07-01

...°59′15″ W. All coordinates referenced use datum: NAD 83. (2) Air Box Area. The air box area is... coordinates referenced use datum: NAD 83. (b) Special local regulations. (1) Vessels and persons are... referenced use datum: NAD 83. (c) Dates. This section will be enforced annually on the second consecutive...

Massive Ischemic Stroke Due to Pulmonary Barotrauma and Cerebral Artery Air Embolism During Commercial Air Travel

PubMed Central

Zarabi, Sara Farshchi; Parotto, Matteo; Katznelson, Rita; Downar, James

2017-01-01

Patient: Male, 65 Final Diagnosis: Air emboli Symptoms: Short of breath Medication: — Clinical Procedure: — Specialty: Anesthesiology Objective: Unusual setting of medical care Background: Air embolism into the systemic arterial circulation secondary to pulmonary barotrauma has rarely been reported. Herein, we report the clinical course of an extremely rare presentation of cerebral air embolism likely due to ruptured pulmonary bullae during commercial air travel. Case Report: A 65-year-old man suddenly became unconscious during an airplane descent. Upon landing, he was immediately transferred to the nearest emergency department where he was intubated for airway protection. His head CT angiogram showed multiple air pockets in the right parietal lobe suspicious for multiple air emboli. His chest CT scan showed multiple large bullae in the left upper and lower lobes as well as diffusely emphysematous lung tissue. After initial stabilization, he underwent emergent hyperbaric oxygen treatment (HBOT) in the multiplace chamber at 2.8 atmospheres. The patient tolerated HBOT well with no complications. However, his neurologic status deteriorated in the following 24 hours due to progression of his cerebral edema and mass effects. The patient’s clinical status was discussed with his family and the decision was made to withdraw life-sustaining measures. He died shortly after withdrawal of life support. Post-mortem examination confirmed the presence of very large bullae in the lungs bilaterally. Conclusions: Spontaneous cerebral air embolism is a possible complication of ruptured pulmonary bullae during air travel. HBOT is well-tolerated and may be used with caution even in the presence of emphysematous bullae. PMID:28607332

Modeling the chemistry of plasma polymerization using mass spectrometry.

PubMed

Ihrig, D F; Stockhaus, J; Scheide, F; Winkelhake, Oliver; Streuber, Oliver

2003-04-01

The goal of the project is a solvent free painting shop. The environmental technologies laboratory is developing processes of plasma etching and polymerization. Polymerized thin films are first-order corrosion protection and primer for painting. Using pure acetylene we get very nice thin films which were not bonded very well. By using air as bulk gas it is possible to polymerize, in an acetylene plasma, well bonded thin films which are stable first-order corrosion protections and good primers. UV/Vis spectroscopy shows nitrogen oxide radicals in the emission spectra of pure nitrogen and air. But nitrogen oxide is fully suppressed in the presence of acetylene. IR spectroscopy shows only C=O, CH(2) and CH(3) groups but no nitrogen species. With the aid of UV/Vis spectra and the chemistry of ozone formation it is possible to define reactive traps and steps, molecule depletion and processes of proton scavenging and proton loss. Using a numerical model it is possible to evaluate these processes and to calculate theoretical mass spectra. Adjustment of theoretical mass spectra to real measurements leads to specific channels of polymerization which are driven by radicals especially the acetyl radical. The estimated theoretical mass spectra show the specific channels of these chemical processes. It is possible to quantify these channels. This quantification represents the mass flow through this chemical system. With respect to these chemical processes it is possible to have an idea of pollutant production processes.

Brief Communication: Upper Air Relaxation in RACMO2 Significantly Improves Modelled Interannual Surface Mass Balance Variability in Antarctica

NASA Technical Reports Server (NTRS)

van de Berg, W. J.; Medley, B.

2016-01-01

The Regional Atmospheric Climate Model (RACMO2) has been a powerful tool for improving surface mass balance (SMB) estimates from GCMs or reanalyses. However, new yearly SMB observations for West Antarctica show that the modelled interannual variability in SMB is poorly simulated by RACMO2, in contrast to ERA-Interim, which resolves this variability well. In an attempt to remedy RACMO2 performance, we included additional upper-air relaxation (UAR) in RACMO2. With UAR, the correlation to observations is similar for RACMO2 and ERA-Interim. The spatial SMB patterns and ice-sheet-integrated SMB modelled using UAR remain very similar to the estimates of RACMO2 without UAR. We only observe an upstream smoothing of precipitation in regions with very steep topography like the Antarctic Peninsula. We conclude that UAR is a useful improvement for regional climate model simulations, although results in regions with steep topography should be treated with care.

Opposed jet diffusion flames of nitrogen-diluted hydrogen vs air - Axial LDA and CARS surveys; fuel/air rates at extinction

NASA Technical Reports Server (NTRS)

Pellett, G. L.; Northam, G. B.; Wilson, L. G.; Jarrett, Olin, Jr.; Antcliff, R. R.

1989-01-01

An experimental study of H-air counterflow diffusion flames (CFDFs) is reported. Coaxial tubular opposed jet burners were used to form dish-shaped CFDFs centered by opposing laminar jets of H2/N2 and air in an argon bath at 1 atm. Jet velocities for extinction and flame restoration limits are shown versus input H2 concentration. LDA velocity data and CARS temperature and absolute N2, O2 density data give detailed flame structure on the air side of the stagnation point. The results show that air jet velocity is a more fundamental and appropriate measure of H2-air CFDF extinction than input H2 mass flux or fuel jet velocity. It is proposed that the observed constancy of air jet velocity for fuel mixtures containing 80 to 100 percent H2 measure a maximum, kinetically controlled rate at which the CFDF can consume oxygen in air. Fuel velocity mainly measures the input jet momentum required to center an H2/N2 versus air CFDF.

REAL TIME, ON-LINE CHARACTERIZATION OF DIESEL GENERATOR AIR TOXIC EMISSIONS BY RESONANCE ENHANCED MULTI-PHOTON IONIZATION TIME OF FLIGHT MASS SPECTROMETRY

EPA Science Inventory

The laser based resonance, enhanced multi-photon ionization time-of-flight mass spectrometry (REMPI-TOFMS) technique has been applied to the exhaust gas stream of a diesel generator to measure, in real time, concentration levels of aromatic air toxics. Volatile organic compounds ...

Light extinction by fine atmospheric particles in the White Mountains region of New Hampshire and its relationship to air mass transport.

PubMed

Slater, John F; Dibb, Jack E; Keim, Barry D; Talbot, Robert W

2002-03-27

Chemical, optical, and physical measurements of fine aerosols (aerodynamic diameter < or = 2.5 microm) have been performed at a mountaintop location adjacent to the White Mountain National Forest in northern NH, USA. A 1-month long sampling campaign was conducted at Cranmore Mountain during spring 2000. We report on the apportionment of light extinction by fine aerosols into its major chemical components, and relationships between variations in aerosol parameters and changes in air mass origin. Filter-based, 24-h integrated samples were collected and analyzed for major inorganic ions, as well as organic (OC), elemental (EC), and total carbon. Light scattering and light absorption coefficients were measured at 5-min intervals using an integrating nephelometer and a light absorption photometer. Fine particle number density was measured with a condensation particle counter. Air mass origins and transport patterns were investigated through the use of 3-day backward trajectories and a synoptic climate classification system. Two distinct transport regimes were observed: (1) flow from the north/northeast (N/NE) occurred during 9 out of 18 sample-days; and (2) flow from the west/southwest (W/SW) occurred 8 out of 18 sample-days. All measured and derived aerosol and meteorological parameters were separated into two categories based on these different flow scenarios. During W/SW flow, higher values of aerosol chemical concentration, absorption and scattering coefficients, number density, and haziness were observed compared to N/NE flow. The highest level of haziness was associated with the climate classification Frontal Atlantic Return, which brought polluted air into the region from the mid-Atlantic corridor. Fine particle mass scattering efficiencies of (NH4)2SO4 and OC were 5.35 +/- 0.42 m2 g(-1) and 1.56 +/- 0.40 m2 g(-1), respectively, when transport was out of the N/NE. When transport was from the W/SW the values were 4.94 +/- 0.68 m2 g(-1) for (NH4)2SO4 and 2.18 +/- 0

Synthetic optimization of air turbine for dental handpieces.

PubMed

Shi, Z Y; Dong, T

2014-01-01

A synthetic optimization of Pelton air turbine in dental handpieces concerning the power output, compressed air consumption and rotation speed in the mean time is implemented by employing a standard design procedure and variable limitation from practical dentistry. The Pareto optimal solution sets acquired by using the Normalized Normal Constraint method are mainly comprised of two piecewise continuous parts. On the Pareto frontier, the supply air stagnation pressure stalls at the lower boundary of the design space, the rotation speed is a constant value within the recommended range from literature, the blade tip clearance insensitive to while the nozzle radius increases with power output and mass flow rate of compressed air to which the residual geometric dimensions are showing an opposite trend within their respective "pieces" compared to the nozzle radius.

Regional Air Pollutions in Three Different Regions of Asia From a Transcontinental Transport Perspective

NASA Astrophysics Data System (ADS)

Pochanart, P.; Kanaya, Y.; Komazaki, Y.; Liu, Y.; Akimoto, H.

2007-12-01

Asia is known as one of the regions with the fastest rate of growing in industrialization and urbanization. As a result, the rapid increases of large-scale air pollution in Asia emerge as a serious concern at both domestic and international levels. Apart from the problems of air quality degradation, emission control, environmental risk, and health effect in a domestic level, evidences from scientific studies indicate that by the long-range transport, Asian air pollution is becoming a global problem. Observations and model studies confirm that air pollution from Asia could be transported to North America or farther. In this work, we investigate the Asian air pollutions, in particular ozone and some other atmospheric components such as carbon monoxide and black carbon, from the ground- based observations in the three different regions, namely 1) background region of Siberia and central Asia, 2) highly anthropogenic region in eastern China, and 3) the rim region of the Asia-Pacific. In a transcontinental transport perspective, these regions are regarded as the inflow region, source region, and outflow region of Asia, respectively. From the results, it is found that the influences from large-scale emission in East Asia are observed clearly in the source region, and to the significant extent in the outflow region. For the inflow region of Asia, our data in Siberia and Kyrgyzstan indicate that air masses in this region are mostly intact from large-scale anthropogenic emission, and remain much of the global background atmospheric pollution characteristic. When the air masses are transported to source region, the air pollutants level increased sharply and frequent episodes of extremely high pollutions have been observed. Our results show good correlation between the residence time of air masses over the source region in eastern China and the observed levels of air pollutants verifying the strong enhancements by anthropogenic emissions from industrialization and

Elbow mass flow meter

DOEpatents

McFarland, Andrew R.; Rodgers, John C.; Ortiz, Carlos A.; Nelson, David C.

1994-01-01

Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

Facility monitoring of chemical warfare agent simulants in air using an automated, field-deployable, miniature mass spectrometer.

PubMed

Smith, Jonell N; Noll, Robert J; Cooks, R Graham

2011-05-30

Vapors of four chemical warfare agent (CWA) stimulants, 2-chloroethyl ethyl sulfide (CEES), diethyl malonate (DEM), dimethyl methylphosphonate (DMMP), and methyl salicylate (MeS), were detected, identified, and quantitated using a fully automated, field-deployable, miniature mass spectrometer. Samples were ionized using a glow discharge electron ionization (GDEI) source, and ions were mass analyzed with a cylindrical ion trap (CIT) mass analyzer. A dual-tube thermal desorption system was used to trap compounds on 50:50 Tenax TA/Carboxen 569 sorbent before their thermal release. The sample concentrations ranged from low parts per billion [ppb] to two parts per million [ppm]. Limits of detection (LODs) ranged from 0.26 to 5.0 ppb. Receiver operating characteristic (ROC) curves are presented for each analyte. A sample of CEES at low ppb concentration was combined separately with two interferents, bleach (saturated vapor) and diesel fuel exhaust (1%), as a way to explore the capability of detecting the simulant in an environmental matrix. Also investigated was a mixture of the four CWA simulants (at concentrations in air ranging from 270 to 380 ppb). Tandem mass (MS/MS) spectral data were used to identify and quantify the individual components. Copyright © 2011 John Wiley & Sons, Ltd.

A study of air breathing rockets. 3: Supersonic mode combustors

NASA Astrophysics Data System (ADS)

Masuya, G.; Chinzel, N.; Kudo, K.; Murakami, A.; Komuro, T.; Ishii, S.

An experimental study was made on supersonic mode combustors of an air breathing rocket engine. Supersonic streams of room-temperature air and hot fuel-rich rocket exhaust were coaxially mixed and burned in a concially diverging duct of 2 deg half-angle. The effect of air inlet Mach number and excess air ratio was investigated. Axial wall pressure distribution was measured to calculate one dimensional change of Mach number and stagnation temperature. Calculated results showed that supersonic combustion occurred in the duct. At the exit of the duct, gas sampling and Pitot pressure measurement was made, from which radial distributions of various properties were deduced. The distribution of mass fraction of elements from rocket exhaust showed poor mixing performance in the supersonic mode combustors compared with the previously investigated cylindrical subsonic mode combustors. Secondary combustion efficiency correlated well with the centerline mixing parameter, but not with Annushkin's non-dimensional combustor length. No major effect of air inlet Mach number or excess air ratio was seen within the range of conditions under which the experiment was conducted.

Microwave-Driven Air Plasma Studies for Drag Reduction and Power Extraction in Supersonic Air

DTIC Science & Technology

2004-10-15

called spillage occurs, and the air mass capture decreases (Fig. 3). To avoid performance penalties at off-design Mach numbers, a variable geometry inlet...AND SUBTITLE 5. FUNDING NUMBERS Microwave-Driven Air Plasma Studies for Drag Reduction and Power Extraction in Supersonic Air 6. AUTHOR(S) Richard B...MONITORING AGENCY REPORT NUMBER Air Force Office of Scientific Research/NA (John Schmisseur, Program Manager) 801 N. Randolph St., Room 732 Arlington

Optical volume and mass measurements show that mammalian cells swell during mitosis

PubMed Central

Zlotek-Zlotkiewicz, Ewa; Monnier, Sylvain; Cappello, Giovanni; Le Berre, Mael

2015-01-01

The extent, mechanism, and function of cell volume changes during specific cellular events, such as cell migration and cell division, have been poorly studied, mostly because of a lack of adequate techniques. Here we unambiguously report that a large range of mammalian cell types display a significant increase in volume during mitosis (up to 30%). We further show that this increase in volume is tightly linked to the mitotic state of the cell and not to its spread or rounded shape and is independent of the presence of an intact actomyosin cortex. Importantly, this volume increase is not accompanied by an increase in dry mass and thus corresponds to a decrease in cell density. This mitotic swelling might have important consequences for mitotic progression: it might contribute to produce strong pushing forces, allowing mitotic cells to round up; it might also, by lowering cytoplasmic density, contribute to the large change of physicochemical properties observed in mitotic cells. PMID:26598614

Composition of air masses in Fuerteventura (Canary Islands) according to their origins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Patier, R.F.; Diez Hernandez, P.; Diaz Ramiro, E.

1994-12-31

The Centro Nacional de Sanidad Ambiental has among their duties the background atmospheric pollution monitoring in Spain. To do so, the laboratory has set up 6 field stations in the Iberian Peninsula. In these stations, both gaseous and particulate pollutants are currently analyzed. However, there is a lack of data about the atmospheric pollution in the Canary, where they are a very strong influence of natural emissions from sea and the Saharan desert, mixed with anthropogenic ones. Therefore, during the ASTEX/MAGE project the CNSA established a station in Fuerteventura island, characterized by the nonexistence of man-made emissions, to measure somemore » atmospheric pollutants, in order to foresee their origins. In this study, the authors analyzed some pollutants that are used to obtain a clue about the sources of air masses such as gaseous ozone and metallic compounds (vanadium, iron and manganese) in the atmospheric aerosol fractionated by size.« less

The effect of secondary inorganic aerosols, soot and the geographical origin of air mass on acute myocardial infarction hospitalisations in Gothenburg, Sweden during 1985–2010: a case-crossover study

PubMed Central

2014-01-01

Background The relative importance of different sources of air pollution for cardiovascular disease is unclear. The aims were to compare the associations between acute myocardial infarction (AMI) hospitalisations in Gothenburg, Sweden and 1) the long-range transported (LRT) particle fraction, 2) the remaining particle fraction, 3) geographical air mass origin, and 4) influence of local dispersion during 1985–2010. Methods A case-crossover design was applied using lag0 (the exposure the same day as hospitalisation), lag1 (exposure one day prior hospitalisation) and 2-day cumulative average exposure (CA2) (mean of lag0 and lag1). The LRT fractions included PMion (sum of sulphate, nitrate and ammonium) and soot measured at a rural site. The difference between urban PM10 (particulate matter with an aerodynamic diameter smaller than 10 μm) and rural PMion was a proxy for locally generated PM10 (PMrest). The daily geographical origin of air mass was estimated as well as days with limited or effective local dispersion. The entire year was considered, as well as warm and cold periods, and different time periods. Results In total 28 215 AMI hospitalisations occurred during 26 years. PM10, PMion, PMrest and soot did not influence AMI for the entire year. In the cold period, the association was somewhat stronger for PMrest than for urban PM10; the strongest associations were observed during 1990–2000 between AMI and CA2 of PMrest (6.6% per inter-quartile range (IQR), 95% confidence interval 2.1 to 11.4%) and PM10 (4.1%, 95% CI 0.2% − 8.2%). Regarding the geographical air mass origins there were few associations. Days with limited local dispersion showed an association with AMI in the cold period of 2001–2010 (6.7%, 95% CI 0.0% − 13.0%). Conclusions In the cold period, locally generated PM and days with limited local dispersion affected AMI hospitalisations, indicating importance of local emissions from e.g. traffic. PMID:25069830

Ontogenetic changes and developmental adjustments in lactate dehydrogenase isozymes of an obligate air-breathing fish Channa punctatus during deprivation of air access.

PubMed

Ahmad, Riaz; Hasnain, Absar-Ul

2005-02-01

In air-breathing snakehead Channa punctatus, Ldh-B is expressed at all ontogenetic and developmental stages, while Ldh-A is expressed temporally in pre-hatchlings 12-13 days ahead of bimodal respiration marked by air-breathing. Remarkable differences are observed in the LDH isozyme expression among various ontogenetic and developmental stages upon denying air access. When denied air access, water-breathing larvae show two distinct characteristics: (i) they survive longer than transitory air-breathers due to independence from air-breathing and (ii) there is more transient induction of Ldh-B than Ldh-A. Transition to bimodal breathing, which occurred post-hatching in 15-day old larvae, is coincidental with inducibility of Ldh-A and concomitant down-regulation of Ldh-B. Heart tissue from air-breathing adults denied air access shows a preferential expression of LDH-A subunit and slight down-regulation of LDH-B. Heterotetramers of A and B subunits participate in adjusting LDH levels among those stages which either precede air-breathing switchover, or are subsequent to this transition. The contribution of heterotetramers depends on the stage-specific levels of LDH homotetramers A(4) or B(4). Scaling of muscle mass during growth, tolerance to extended deprivation of air access and induction of Ldh-A are correlated. Response to restoring air contact indicated that advanced air-breathing stages of C. punctatus possess an inherent capacity to sense surface air. In kinetic properties, LDH isozymes of C. punctatus are teleost-like but species specificity is displayed in oxidative potential by cardiac muscle and in L-lactate reduction by skeletal muscle.

Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean

USGS Publications Warehouse

Garrison, Virginia H.; Majewski, Michael S.; Foreman, William T.; Genualdi, Susan A.; Mohammed, Azad; Massey Simonich, Stacy L.

2014-01-01

Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9–126 ng/m3 (mean = 25 ± 34) at source and 0.05–0.71 ng/m3 (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1–3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses.

Two-axis gimbal for air-to-air and air-to-ground laser communications

NASA Astrophysics Data System (ADS)

Talmor, Amnon G.; Harding, Harvard; Chen, Chien-Chung

2016-03-01

For bi-directional links between high-altitude-platforms (HAPs) and ground, and air-to-air communication between such platforms, a hemispherical +30°C field-of-regard and low-drag low-mass two-axis gimbal was designed and prototyped. The gimbal comprises two servo controlled non-orthogonal elevation over azimuth axis, and inner fast steering mirrors for fine field-of-regard adjustment. The design encompasses a 7.5cm diameter aperture refractive telescope in its elevation stage, folded between two flat mirrors with an exit lens leading to a two mirrors miniature Coude-path fixed to the azimuth stage. Multiple gimbal configurations were traded prior to finalizing a selection that met the requirements. The selected design was manifested onboard a carbon fiber and magnesium composite structure, motorized by custom-built servo motors, and commutated by optical encoders. The azimuth stage is electrically connected to the stationary base via slip ring while the elevation stage made of passive optics. Both axes are aligned by custom-built ceramic-on-steel angular contact duplex bearings, and controlled by embedded electronics featuring a rigid-flex PCB architecture. FEA analysis showed that the design is mechanically robust over a temperature range of +60°C to -80°C, and with first mode of natural frequencies above 400Hz. The total mass of the prototyped gimbal is 3.5kg, including the inner optical bench, which contains fast steering mirrors (FSMs) and tracking sensors. Future version of this gimbal, in prototyping stage, shall weigh less than 3.0kg.

Open issues in hadronic interactions for air showers

NASA Astrophysics Data System (ADS)

Pierog, Tanguy

2017-06-01

In detailed air shower simulations, the uncertainty in the prediction of shower observables for different primary particles and energies is currently dominated by differences between hadronic interaction models. With the results of the first run of the LHC, the difference between post-LHC model predictions has been reduced to the same level as experimental uncertainties of cosmic ray experiments. At the same time new types of air shower observables, like the muon production depth, have been measured, adding new constraints on hadronic models. Currently no model is able to consistently reproduce all mass composition measurements possible within the Pierre Auger Observatory for instance. Comparing the different models, and with LHC and cosmic ray data, we will show that the remaining open issues in hadronic interactions in air shower development are now in the pion-air interactions and in nuclear effects.

Who should take responsibility for decisions on internationally recommended datasets? The case of the mass concentration of mercury in air at saturation

NASA Astrophysics Data System (ADS)

Brown, Richard J. C.; Brewer, Paul J.; Ent, Hugo; Fisicaro, Paola; Horvat, Milena; Kim, Ki-Hyun; Quétel, Christophe R.

2015-10-01

This paper considers how decisions on internationally recommended datasets are made and implemented and, further, how the ownership of these decisions comes about. Examples are given of conventionally agreed data and values where the responsibility is clear and comes about through official designation or by common usage and practice over long time periods. The example of the dataset describing the mass concentration of mercury in air at saturation is discussed in detail. This is a case where there are now several competing datasets that are in disagreement with each other, some with historical authority and some more recent but, arguably, with more robust metrological traceability to the SI. Further, it is elaborated that there is no body charged with the responsibility to make a decision on an international recommendation for such a dataset. This has led to the situation where several competing datasets are in use simultaneously. Close parallels are drawn with the current debate over changes to the ozone absorption cross section, which has equal importance to the measurement of ozone amount fraction in air and to subsequent compliance with air quality legislation. It is noted that in the case of the ozone cross section there is already a committee appointed to deliberate over any change. We make the proposal that a similar committee, under the auspices of IUPAC or the CIPM’s CCQM (if it adopted a reference data function) could be formed to perform a similar role for the mass concentration of mercury in air at saturation.

Seasonal origins of air masses transported to Mount Wrangell, Alaska, and comparison with the past atmospheric dust and tritium variations in its ice core

NASA Astrophysics Data System (ADS)

Yasunari, T. J.; Shiraiwa, T.; Kanamori, S.; Fujii, Y.; Igarashi, M.; Yamazaki, K.; Benson, C. S.; Hondoh, T.

2006-12-01

The North Pacific region is subject to various climatic phenomena such as the Pacific Decadal Oscillation (PDO), the El Niño-Southern Oscillation (ENSO), and the Arctic Oscillation (AO), significantly affecting the ocean and the atmosphere. Additionally, material circulation is also very active in this region such as spring dust storms in the desert and arid regions of East Asia and forest fires in Siberia and Alaska. Understanding the complex connections among the climatic phenomena and the material circulation would help in attempts to predict future climate changes. For this subject, we drilled a 50-m ice core at the summit of Mount Wrangell, which is located near the coast of Alaska (62°162'170"162°171'N, 144°162'170"162;°171'W, and 4100-m). We analyzed dust particle number density, tritium concentration, and 171 171 171 171 170 162 171 D in the core. The ice core spanned the years from 1992 to 2002 and we finally divided the years into five parts (early-spring; late-spring; summer; fall; winter). Dust and tritium amounts varied annually and intra-annually. For further understanding of the factors on those variations, we should know the origins of the seasonal dust and tritium. Hence, we examined their origins by the calculation of everyday 10-days backward trajectory analysis from January 1992 to August 2002 with 3-D wind data of the European Center for Medium-Range Weather Forecast (ECMWF). In early spring, the air mass from East Asia increased and it also explained dust increases in springtime, although the air contribution in winter increased too. In late spring, the air mass from the stratosphere increased, and it also corresponded to the stratospheric tritium increase in the ice core. The air masses from Siberia and the North Pacific in the mid-latitude always significantly contributed to Mount Wrangell, although those maximum contributions were fall and summer, respectively. The air mass originating in the interior of Alaska and North America did

Experimental study of heat transfer and thermal performance with longitudinal fins of solar air heater

PubMed Central

Chabane, Foued; Moummi, Noureddine; Benramache, Said

2013-01-01

The thermal performance of a single pass solar air heater with five fins attached was investigated experimentally. Longitudinal fins were used inferior the absorber plate to increase the heat exchange and render the flow fluid in the channel uniform. The effect of mass flow rate of air on the outlet temperature, the heat transfer in the thickness of the solar collector, and the thermal efficiency were studied. Experiments were performed for two air mass flow rates of 0.012 and 0.016 kg s−1. Moreover, the maximum efficiency values obtained for the 0.012 and 0.016 kg s−1 with and without fins were 40.02%, 51.50% and 34.92%, 43.94%, respectively. A comparison of the results of the mass flow rates by solar collector with and without fins shows a substantial enhancement in the thermal efficiency. PMID:25685486

Experimental study of heat transfer and thermal performance with longitudinal fins of solar air heater.

PubMed

Chabane, Foued; Moummi, Noureddine; Benramache, Said

2014-03-01

The thermal performance of a single pass solar air heater with five fins attached was investigated experimentally. Longitudinal fins were used inferior the absorber plate to increase the heat exchange and render the flow fluid in the channel uniform. The effect of mass flow rate of air on the outlet temperature, the heat transfer in the thickness of the solar collector, and the thermal efficiency were studied. Experiments were performed for two air mass flow rates of 0.012 and 0.016 kg s(-1). Moreover, the maximum efficiency values obtained for the 0.012 and 0.016 kg s(-1) with and without fins were 40.02%, 51.50% and 34.92%, 43.94%, respectively. A comparison of the results of the mass flow rates by solar collector with and without fins shows a substantial enhancement in the thermal efficiency.

Air Intake Performance of Air Breathing Ion Engines

NASA Astrophysics Data System (ADS)

Fujita, Kazuhisa

The air breathing ion engine (ABIE) is a new type of electric propulsion system which can be used to compensate the aerodynamic drag of the satellite orbiting at extremely low altitudes. In this propulsion system, the low-density atmosphere surrounding the satellite is taken in and used as the propellant of ion engines to reduce the propellant mass for a long operation lifetime. Since feasibility and performance of the ABIE are subject to the compression ratio and the air intake efficiency, a numerical analysis has been conducted by means of the direct-simulation Monte-Carlo method to clarify the characteristics of the air-intake performance in highly rarefied flows. Influences of the flight altitude, the aspect-ratio of the air intake duct, the angle of attack, and the wall conditions are investigated.

Modelling bioaccumulation of semi-volatile organic compounds (SOCs) from air in plants based on allometric principles.

PubMed

Steyaert, Nils L L; Hauck, Mara; Van Hulle, Stijn W H; Hendriks, A Jan

2009-10-01

A model was developed for gaseous plant-air exchange of semi-volatile organic compounds. Based on previous soil-plant modelling, uptake and elimination kinetics were scaled as a function of plant mass and octanol-air partition ratios. Exchange of chemicals was assumed to be limited by resistances encountered during diffusion through a laminar boundary layer of air and permeation through the cuticle of the leaf. The uptake rate constant increased and the elimination rate constant decreased with the octanol-air partition ratio both apparently levelling off at high values. Differences in kinetics between species could be explained by their masses. Validation on independent data showed that bio-concentration factors of PCBs, chlorobenzenes and other chemicals were predicted well by the model. For pesticides, polycyclic aromatic hydrocarbons and dioxins deviations occurred.

In-Line Ozonation for Sensitive Air-Monitoring of a Mustard-Gas Simulant by Atmospheric Pressure Chemical Ionization Mass Spectrometry

NASA Astrophysics Data System (ADS)

Okumura, Akihiko

2015-09-01

A highly sensitive method for real-time air-monitoring of mustard gas (bis(2-chloroethyl) sulfide, HD), which is a lethal blister agent, is proposed. Humidified air containing a HD simulant, 2-chloroethyl ethyl sulfide (2CEES), was mixed with ozone and then analyzed by using an atmospheric pressure chemical ionization ion trap tandem mass spectrometer. Mass-spectral ion peaks attributable to protonated molecules of intact, monooxygenated, and dioxygenated 2CEES (MH+, MOH+, and MO2H+, respectively) were observed. As ozone concentration was increased from zero to 30 ppm, the signal intensity of MH+ sharply decreased, that of MOH+ increased once and then decreased, and that of MO2H+ sharply increased until reaching a plateau. The signal intensity of MO2H+ at the plateau was 40 times higher than that of MH+ and 100 times higher than that of MOH+ in the case without in-line ozonation. Twenty-ppm ozone gas was adequate to give a linear calibration curve for 2CEES obtained by detecting the MO2H+ signal in the concentration range up to 60 μg/m3, which is high enough for hygiene management. In the low concentration range lower than 3 μg/m3, which is equal to the short-term exposure limit for HD, calibration plots unexpectedly fell off the linear calibration curve, but 0.6-μg/m3 vapor was actually detected with the signal-to-noise ratio of nine. Ozone was generated from instrumentation air by using a simple and inexpensive home-made generator. 2CEES was ozonated in 1-m extended sampling tube in only 1 s.

Modeling validation and control analysis for controlled temperature and humidity of air conditioning system.

PubMed

Lee, Jing-Nang; Lin, Tsung-Min; Chen, Chien-Chih

2014-01-01

This study constructs an energy based model of thermal system for controlled temperature and humidity air conditioning system, and introduces the influence of the mass flow rate, heater and humidifier for proposed control criteria to achieve the controlled temperature and humidity of air conditioning system. Then, the reliability of proposed thermal system model is established by both MATLAB dynamic simulation and the literature validation. Finally, the PID control strategy is applied for controlling the air mass flow rate, humidifying capacity, and heating, capacity. The simulation results show that the temperature and humidity are stable at 541 sec, the disturbance of temperature is only 0.14 °C, 0006 kg(w)/kg(da) in steady-state error of humidity ratio, and the error rate is only 7.5%. The results prove that the proposed system is an effective controlled temperature and humidity of an air conditioning system.

Modeling Validation and Control Analysis for Controlled Temperature and Humidity of Air Conditioning System

PubMed Central

Lee, Jing-Nang; Lin, Tsung-Min

2014-01-01

This study constructs an energy based model of thermal system for controlled temperature and humidity air conditioning system, and introduces the influence of the mass flow rate, heater and humidifier for proposed control criteria to achieve the controlled temperature and humidity of air conditioning system. Then, the reliability of proposed thermal system model is established by both MATLAB dynamic simulation and the literature validation. Finally, the PID control strategy is applied for controlling the air mass flow rate, humidifying capacity, and heating, capacity. The simulation results show that the temperature and humidity are stable at 541 sec, the disturbance of temperature is only 0.14°C, 0006 kgw/kgda in steady-state error of humidity ratio, and the error rate is only 7.5%. The results prove that the proposed system is an effective controlled temperature and humidity of an air conditioning system. PMID:25250390

Miniature Distillation Column for Producing LOX From Air

NASA Technical Reports Server (NTRS)

Rozzi, Jay C.

2006-01-01

The figure shows components of a distillation column intended for use as part of a system that produces high-purity liquid oxygen (LOX) from air by distillation. (The column could be easily modified to produce high-purity liquid nitrogen.) Whereas typical industrial distillation columns for producing high-purity liquid oxygen and/or nitrogen are hundreds of feet tall, this distillation column is less than 3 ft (less than about 0.9 m) tall. This column was developed to trickle-charge a LOX-based emergency oxygen system (EOS) for a large commercial aircraft. A description of the industrial production of liquid oxygen and liquid nitrogen by distillation is prerequisite to a meaningful description of the present miniaturized distillation column. Typically, such industrial production takes place in a chemical processing plant in which large quantities of high-pressure air are expanded in a turboexpander to (1) recover a portion of the electrical power required to compress the air and (2) partially liquefy the air. The resulting two-phase flow of air is sent to the middle of a distillation column. The liquid phase is oxygen-rich, and its oxygen purity increases as it flows down the column. The vapor phase is nitrogen-rich and its nitrogen purity increases as it flows up the column. A heater or heat exchanger, commonly denoted a reboiler, is at the bottom of the column. The reboiler is so named because its role is to reboil some of the liquid oxygen collected at the bottom of the column to provide a flow of oxygen-rich vapor. As the oxygen-rich vapor flows up the column, it absorbs the nitrogen in the down-flowing liquid by mass transfer. Once the vapor leaves the lower portion of the column, it interacts with down-flowing nitrogen liquid that has been condensed in a heat exchanger, commonly denoted a condenser, at the top of the column. Liquid oxygen and liquid nitrogen products are obtained by draining some of the purified product at the bottom and top of the column

This photograph shows a stream in the La Selva region of the Costa Rican rain forest, taken during NASA's AirSAR 2004 campaign

NASA Image and Video Library

2004-03-05

This photograph shows a stream in the La Selva region of the Costa Rican rain forest, taken during NASA's AirSAR 2004 campaign. AirSAR 2004 Mesoamerica is a three-week expedition by an international team of scientists that uses an all-weather imaging tool, called the Airborne Synthetic Aperture Radar (AirSAR) which is located onboard NASA's DC-8 airborne laboratory. Scientists from many parts of the world including NASA's Jet Propulsion Laboratory are combining ground research done in several areas in Central America with NASA's AirSAR technology to improve and expand on the quality of research they are able to conduct. The radar, developed by NASA's Jet Propulsion Laboratory, can penetrate clouds and also collect data at night. Its high-resolution sensors operate at multiple wavelengths and modes, allowing AirSAR to see beneath treetops, through thin sand, and dry snow pack. AirSAR's 2004 campaign is a collaboration of many U.S. and Central American institutions and scientists, including NASA; the National Science Foundation; the Smithsonian Institution; National Geographic; Conservation International; the Organization of Tropical Studies; the Central American Commission for Environment and Development; and the Inter-American Development Bank.

Working characteristics of variable intake valve in compressed air engine.

PubMed

Yu, Qihui; Shi, Yan; Cai, Maolin

2014-01-01

A new camless compressed air engine is proposed, which can make the compressed air energy reasonably distributed. Through analysis of the camless compressed air engine, a mathematical model of the working processes was set up. Using the software MATLAB/Simulink for simulation, the pressure, temperature, and air mass of the cylinder were obtained. In order to verify the accuracy of the mathematical model, the experiments were conducted. Moreover, performance analysis was introduced to design compressed air engine. Results show that, firstly, the simulation results have good consistency with the experimental results. Secondly, under different intake pressures, the highest output power is obtained when the crank speed reaches 500 rpm, which also provides the maximum output torque. Finally, higher energy utilization efficiency can be obtained at the lower speed, intake pressure, and valve duration angle. This research can refer to the design of the camless valve of compressed air engine.

Passive air sampling theory for semivolatile organic compounds.

PubMed

Bartkow, Michael E; Booij, Kees; Kennedy, Karen E; Müller, Jochen F; Hawker, Darryl W

2005-07-01

The mathematical modelling underlying passive air sampling theory can be based on mass transfer coefficients or rate constants. Generally, these models have not been inter-related. Starting with basic models, the exchange of chemicals between the gaseous phase and the sampler is developed using mass transfer coefficients and rate constants. Importantly, the inter-relationships between the approaches are demonstrated by relating uptake rate constants and loss rate constants to mass transfer coefficients when either sampler-side or air-side resistance is dominating chemical exchange. The influence of sampler area and sampler volume on chemical exchange is discussed in general terms and as they relate to frequently used parameters such as sampling rates and time to equilibrium. Where air-side or sampler-side resistance dominates, an increase in the surface area of the sampler will increase sampling rates. Sampling rates are not related to the sampler/air partition coefficient (K(SV)) when air-side resistance dominates and increase with K(SV) when sampler-side resistance dominates.

Spatiotemporal Patterns of Ice Mass Variations and the Local Climatic Factors in the Riparian Zone of Central Valley, California

NASA Astrophysics Data System (ADS)

Inamdar, P.; Ambinakudige, S.

2016-12-01

Californian icefields are natural basins of fresh water. They provide irrigation water to the farms in the central valley. We analyzed the ice mass loss rates, air temperature and land surface temperature (LST) in Sacramento and San Joaquin basins in California. The digital elevation models from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) were used to calculate ice mass loss rate between the years 2002 and 2015. Additionally, Landsat TIR data were used to extract the land surface temperature. Data from local weather stations were analyzed to understand the spatiotemporal trends in air temperature. The results showed an overall mass recession of -0.8 ± 0.7 m w.e.a-1. We also noticed an about 60% loss in areal extent of the glaciers in the study basins between 2000 and 2015. Local climatic factors, along with the global climate patterns might have influenced the negative trends in the ice mass loss. Overall, there was an increase in the air temperature by 0.07± 0.02 °C in the central valley between 2000 and 2015. Furthermore, LST increased by 0.34 ± 0.4 °C and 0.55± 0.1 °C in the Sacramento and San Joaquin basins. Our preliminary results show the decrease in area and mass of ice mass in the basins, and changing agricultural practices in the valley.

Numerical simulation for the influence of laser-induced plasmas addition on air mass capture of hypersonic inlet

NASA Astrophysics Data System (ADS)

Zhao, Wei; Dou, Zhiguo; Li, Qian

2012-03-01

The theory of laser-induced plasmas addition to hypersonic airflow off a vehicle to increase air mass capture and improve the performance of hypersonic inlets at Mach numbers below the design value is explored. For hypersonic vehicles, when flying at mach numbers lower than the design one, we can increase the mass capture ratio of inlet through laser-induced plasmas injection to the hypersonic flow upstream of cowl lip to form a virtual cowl. Based on the theory, the model of interaction between laser-induced plasmas and hypersonic flow was established. The influence on the effect of increasing mass capture ratio was studied at different positions of laser-induced plasmas region for the external compression hypersonic inlet at Mach 5 while the design value is 6, the power of plasmas was in the range of 1-8mJ. The main results are as follows: 1. the best location of the plasma addition region is near the intersection of the nose shock of the vehicle with the continuation of the cowl line, and slightly below that line. In that case, the shock generated by the heating is close to the shock that is a reflection of the vehicle nose shock off the imaginary solid surface-extension of the cowl. 2. Plasma addition does increase mass capture, and the effect becomes stronger as more energy is added, the peak value appeared when the power of plasma was about 4mJ, when the plasma energy continues to get stronger, the mass capture will decline slowly.

Numerical simulation for the influence of laser-induced plasmas addition on air mass capture of hypersonic inlet

NASA Astrophysics Data System (ADS)

Zhao, Wei; Dou, Zhiguo; Li, Qian

2011-11-01

The theory of laser-induced plasmas addition to hypersonic airflow off a vehicle to increase air mass capture and improve the performance of hypersonic inlets at Mach numbers below the design value is explored. For hypersonic vehicles, when flying at mach numbers lower than the design one, we can increase the mass capture ratio of inlet through laser-induced plasmas injection to the hypersonic flow upstream of cowl lip to form a virtual cowl. Based on the theory, the model of interaction between laser-induced plasmas and hypersonic flow was established. The influence on the effect of increasing mass capture ratio was studied at different positions of laser-induced plasmas region for the external compression hypersonic inlet at Mach 5 while the design value is 6, the power of plasmas was in the range of 1-8mJ. The main results are as follows: 1. the best location of the plasma addition region is near the intersection of the nose shock of the vehicle with the continuation of the cowl line, and slightly below that line. In that case, the shock generated by the heating is close to the shock that is a reflection of the vehicle nose shock off the imaginary solid surface-extension of the cowl. 2. Plasma addition does increase mass capture, and the effect becomes stronger as more energy is added, the peak value appeared when the power of plasma was about 4mJ, when the plasma energy continues to get stronger, the mass capture will decline slowly.

An automated gas chromatography time-of-flight mass spectrometry instrument for the quantitative analysis of halocarbons in air

NASA Astrophysics Data System (ADS)

Obersteiner, F.; Bönisch, H.; Engel, A.

2016-01-01

We present the characterization and application of a new gas chromatography time-of-flight mass spectrometry instrument (GC-TOFMS) for the quantitative analysis of halocarbons in air samples. The setup comprises three fundamental enhancements compared to our earlier work (Hoker et al., 2015): (1) full automation, (2) a mass resolving power R = m/Δm of the TOFMS (Tofwerk AG, Switzerland) increased up to 4000 and (3) a fully accessible data format of the mass spectrometric data. Automation in combination with the accessible data allowed an in-depth characterization of the instrument. Mass accuracy was found to be approximately 5 ppm in mean after automatic recalibration of the mass axis in each measurement. A TOFMS configuration giving R = 3500 was chosen to provide an R-to-sensitivity ratio suitable for our purpose. Calculated detection limits are as low as a few femtograms by means of the accurate mass information. The precision for substance quantification was 0.15 % at the best for an individual measurement and in general mainly determined by the signal-to-noise ratio of the chromatographic peak. Detector non-linearity was found to be insignificant up to a mixing ratio of roughly 150 ppt at 0.5 L sampled volume. At higher concentrations, non-linearities of a few percent were observed (precision level: 0.2 %) but could be attributed to a potential source within the detection system. A straightforward correction for those non-linearities was applied in data processing, again by exploiting the accurate mass information. Based on the overall characterization results, the GC-TOFMS instrument was found to be very well suited for the task of quantitative halocarbon trace gas observation and a big step forward compared to scanning, quadrupole MS with low mass resolving power and a TOFMS technique reported to be non-linear and restricted by a small dynamical range.

Multiday production of condensing organic aerosol mass in urban and forest outflow

DOE PAGES

Lee-Taylor, J.; Hodzic, A.; Madronich, S.; ...

2014-07-03

Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for several days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (∼50%) and of shorter duration (1–2 days). The production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction products ofmore » both aromatics and alkanes. In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. The results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.« less

The influence of continental air masses on the aerosols and nutrients deposition over the western North Pacific

NASA Astrophysics Data System (ADS)

Fu, Jiangping; Wang, Bo; Chen, Ying; Ma, Qingwei

2018-01-01

The air masses transported from East Asia have a strong impact on the aerosol properties and deposition in the marine boundary layer of the western North Pacific (WNP) during winter and spring. We joined a cruise between 17 Mar. and 22 Apr. 2014 and investigated the changes of aerosol composition and size distribution over the remote WNP and marginal seas. Although the secondary aerosol species (SO42-, NO3- and NH4+) in remote WNP were influenced significantly by the continental transport, NH4+ concentrations were lower than 2.7 μg m-3 in most sampling days and not correlated with non-sea-salt (nss)-SO42- suggesting that the ocean could be a primary source of NH4+. Moderate Cl- depletion (23%) was observed in remote WNP, and the inverse relationship between Cl- depletion percentages and nss-K+ in aerosols suggested that the transport of biomass burning smoke from East Asia might be a vital extra source of Cl-. Both Asian dust and haze events were encountered during the cruise. Asian dust carried large amounts of crustal elements such as Al and Ti to the WNP, and the dusty Fe deposition may double its background concentration in seawater. Differently, a dramatic increase of dry deposition flux of dissolved particulate inorganic nitrogen was observed during the haze event. Our study reveals that the transport of different continental air masses may have distinct biogeochemical impacts on the WNP by increasing the fluxes of different nutrient elements and potentially changing the nutrient stoichiometry.

Combining Experiments and Simulation of Gas Absorption for Teaching Mass Transfer Fundamentals: Removing CO2 from Air Using Water and NaOH

ERIC Educational Resources Information Center

Clark, William M.; Jackson, Yaminah Z.; Morin, Michael T.; Ferraro, Giacomo P.

2011-01-01

Laboratory experiments and computer models for studying the mass transfer process of removing CO2 from air using water or dilute NaOH solution as absorbent are presented. Models tie experiment to theory and give a visual representation of concentration profiles and also illustrate the two-film theory and the relative importance of various…

Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morrison, Glenn Charles

1999-12-01

were 10 -7, 10 -5, and 10 -5 respectively. To understand how internal surface area influences the equivalent reaction probability of whole carpet, a model of ozone diffusion into and reaction with internal carpet components was developed. This was then used to predict apparent reaction probabilities for carpet. He combines this with a modified model of turbulent mass transfer developed by Liu, et al. to predict deposition rates and indoor ozone concentrations. The model predicts that carpet should have an equivalent reaction probability of about 10 -5, matching laboratory measurements of the reaction probability. For both carpet and duct materials, surfaces become progressively quenched (aging), losing the ability to react or otherwise take up ozone. He evaluated the functional form of aging and find that the reaction probability follows a power function with respect to the cumulative uptake of ozone. To understand ozone aging of surfaces, he developed several mathematical descriptions of aging based on two different mechanisms. The observed functional form of aging is mimicked by a model which describes ozone diffusion with internal reaction in a solid. He shows that the fleecy nature of carpet materials in combination with the model of ozone diffusion below a fiber surface and internal reaction may explain the functional form and the magnitude of power function parameters observed due to ozone interactions with carpet. The ozone induced aldehyde emissions, measured from duct materials, were combined with an indoor air quality model to show that concentrations of aldehydes indoors may approach odorous levels. He shows that ducts are unlikely to be a significant sink for ozone due to the low reaction probability in combination with the short residence time of air in ducts.« less

Analysis of air mass trajectories to explain observed variability of tritium in precipitation at the Southern Sierra Critical Zone Observatory, California, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Visser, Ate; Thaw, Melissa; Esser, Brad

Understanding the behavior of tritium, a radioactive isotope of hydrogen, in the environment is important to evaluate the exposure risk of anthropogenic releases, and for its application as a tracer in hydrology and oceanography. To understand and predict the variability of tritium in precipitation, HYSPLIT air mass trajectories were analyzed for 16 aggregate precipitation samples collected over a 2 year period at irregular intervals at a research site located at 2000 m elevation in the southern Sierra Nevada (California, USA). Attributing the variation in tritium to specific source areas confirms the hypothesis that higher latitude or inland sources bring highermore » tritium levels in precipitation than precipitation originating in the lower latitude Pacific Ocean. In this case, the source of precipitation accounts for 79% of the variation observed in tritium concentrations. In conclusion, air mass trajectory analysis is a promising tool to improve the predictions of tritium in precipitation at unmonitored locations and thoroughly understand the processes controlling transport of tritium in the environment.« less

Analysis of air mass trajectories to explain observed variability of tritium in precipitation at the Southern Sierra Critical Zone Observatory, California, USA

DOE PAGES

Visser, Ate; Thaw, Melissa; Esser, Brad

2017-11-20

Understanding the behavior of tritium, a radioactive isotope of hydrogen, in the environment is important to evaluate the exposure risk of anthropogenic releases, and for its application as a tracer in hydrology and oceanography. To understand and predict the variability of tritium in precipitation, HYSPLIT air mass trajectories were analyzed for 16 aggregate precipitation samples collected over a 2 year period at irregular intervals at a research site located at 2000 m elevation in the southern Sierra Nevada (California, USA). Attributing the variation in tritium to specific source areas confirms the hypothesis that higher latitude or inland sources bring highermore » tritium levels in precipitation than precipitation originating in the lower latitude Pacific Ocean. In this case, the source of precipitation accounts for 79% of the variation observed in tritium concentrations. In conclusion, air mass trajectory analysis is a promising tool to improve the predictions of tritium in precipitation at unmonitored locations and thoroughly understand the processes controlling transport of tritium in the environment.« less

The Potential of The Synergy of Sunphotometer and Lidar Data to Validate Vertical Profiles of The Aerosol Mass Concentration Estimated by An Air Quality Model

NASA Astrophysics Data System (ADS)

Siomos, N.; Filioglou, M.; Poupkou, A.; Liora, N.; Dimopoulos, S.; Melas, D.; Chaikovsky, A.; Balis, D. S.

2016-06-01

Vertical profiles of the aerosol mass concentration derived by the Lidar/Radiometer Inversion Code (LIRIC), that uses combined sunphotometer and lidar data, were used in order to validate the aerosol mass concentration profiles estimated by the air quality model CAMx. Lidar and CIMEL measurements performed at the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki, Greece (40.5N, 22.9E) from the period 2013-2014 were used in this study.

Characteristics of particle number and mass emissions during heavy-duty diesel truck parked active DPF regeneration in an ambient air dilution tunnel

NASA Astrophysics Data System (ADS)

Yoon, Seungju; Quiros, David C.; Dwyer, Harry A.; Collins, John F.; Burnitzki, Mark; Chernich, Donald; Herner, Jorn D.

2015-12-01

Diesel particle number and mass emissions were measured during parked active regeneration of diesel particulate filters (DPF) in two heavy-duty diesel trucks: one equipped with a DPF and one equipped with a DPF + SCR (selective catalytic reduction), and compliant with the 2007 and 2010 emission standards, respectively. The emission measurements were conducted using an ambient air dilution tunnel. During parked active regeneration, particulate matter (PM) mass emissions measured from a 2007 technology truck were significantly higher than the emissions from a 2010 technology truck. Particle number emissions from both trucks were dominated by nucleation mode particles having a diameter less than 50 nm; nucleation mode particles were orders of magnitude higher than accumulation mode particles having a diameter greater than 50 nm. Accumulation mode particles contributed 77.8 %-95.8 % of the 2007 truck PM mass, but only 7.3 %-28.2 % of the 2010 truck PM mass.

Sensitive and comprehensive detection of chemical warfare agents in air by atmospheric pressure chemical ionization ion trap tandem mass spectrometry with counterflow introduction.

PubMed

Seto, Yasuo; Sekiguchi, Hiroshi; Maruko, Hisashi; Yamashiro, Shigeharu; Sano, Yasuhiro; Takayama, Yasuo; Sekioka, Ryoji; Yamaguchi, Shintaro; Kishi, Shintaro; Satoh, Takafumi; Sekiguchi, Hiroyuki; Iura, Kazumitsu; Nagashima, Hisayuki; Nagoya, Tomoki; Tsuge, Kouichiro; Ohsawa, Isaac; Okumura, Akihiko; Takada, Yasuaki; Ezawa, Naoya; Watanabe, Susumu; Hashimoto, Hiroaki

2014-05-06

A highly sensitive and specific real-time field-deployable detection technology, based on counterflow air introduction atmospheric pressure chemical ionization, has been developed for a wide range of chemical warfare agents (CWAs) comprising gaseous (two blood agents, three choking agents), volatile (six nerve gases and one precursor agent, five blister agents), and nonvolatile (three lachrymators, three vomiting agents) agents in air. The approach can afford effective chemical ionization, in both positive and negative ion modes, for ion trap multiple-stage mass spectrometry (MS(n)). The volatile and nonvolatile CWAs tested provided characteristic ions, which were fragmented into MS(3) product ions in positive and negative ion modes. Portions of the fragment ions were assigned by laboratory hybrid mass spectrometry (MS) composed of linear ion trap and high-resolution mass spectrometers. Gaseous agents were detected by MS or MS(2) in negative ion mode. The limits of detection for a 1 s measurement were typically at or below the microgram per cubic meter level except for chloropicrin (submilligram per cubic meter). Matrix effects by gasoline vapor resulted in minimal false-positive signals for all the CWAs and some signal suppression in the case of mustard gas. The moisture level did influence the measurement of the CWAs.

Air Support Control Officer Individual Position Training Simulation

DTIC Science & Technology

2017-06-01

Analysis design development implementation evaluation ASCO Air support control officer ASLT Air support liaison team ASNO Air support net operator...Instructional system design LSTM Long-short term memory MACCS Marine Air Command and Control System MAGTF Marine Air Ground Task Force MASS Marine Air...information to designated MACCS agencies. ASCOs play an important part in facilitating the safe and successful conduct of air operations in DASC- controlled

[Air pollution in an urban area nearby the Rome-Ciampino city airport].

PubMed

Di Menno di Bucchianico, Alessandro; Cattani, Giorgio; Gaeta, Alessandra; Caricchia, Anna Maria; Troiano, Francesco; Sozzi, Roberto; Bolignano, Andrea; Sacco, Fabrizio; Damizia, Sesto; Barberini, Silvia; Caleprico, Roberta; Fabozzi, Tina; Ancona, Carla; Ancona, Laura; Cesaroni, Giulia; Forastiere, Francesco; Gobbi, Gian Paolo; Costabile, Francesca; Angelini, Federico; Barnaba, Francesca; Inglessis, Marco; Tancredi, Francesco; Palumbo, Lorenzo; Fontana, Luca; Bergamaschi, Antonio; Iavicoli, Ivo

2014-01-01

to assess air pollution spatial and temporal variability in the urban area nearby the Ciampino International Airport (Rome) and to investigate the airport-related emissions contribute. the study domain was a 64 km2 area around the airport. Two fifteen-day monitoring campaigns (late spring, winter) were carried out. Results were evaluated using several runs outputs of an airport-related sources Lagrangian particle model and a photochemical model (the Flexible Air quality Regional Model, FARM). both standard and high time resolution air pollutant concentrations measurements: CO, NO, NO2, C6H6, mass and number concentration of several PM fractions. 46 fixed points (spread over the study area) of NO2 and volatile organic compounds concentrations (fifteen days averages); deterministic models outputs. standard time resolution measurements, as well as model outputs, showed the airport contribution to air pollution levels being little compared to the main source in the area (i.e. vehicular traffic). However, using high time resolution measurements, peaks of particles associated with aircraft takeoff (total number concentration and soot mass concentration), and landing (coarse mass concentration) were observed, when the site measurement was downwind to the runway. the frequently observed transient spikes associated with aircraft movements could lead to a not negligible contribute to ultrafine, soot and coarse particles exposure of people living around the airport. Such contribute and its spatial and temporal variability should be investigated when assessing the airports air quality impact.

Effects of air and water temperatures on resting metabolism of auklets and other diving birds.

PubMed

Richman, Samantha E; Lovvorn, James R

2011-01-01

For small aquatic endotherms, heat loss while floating on water can be a dominant energy cost, and requires accurate estimation in energetics models for different species. We measured resting metabolic rate (RMR) in air and on water for a small diving bird, the Cassin's auklet (Ptychoramphus aleuticus), and compared these results to published data for other diving birds of diverse taxa and sizes. For 8 Cassin's auklets (~165 g), the lower critical temperature was higher on water (21 °C) than in air (16 °C). Lowest values of RMR (W kg⁻¹) averaged 19% higher on water (12.14 ± 3.14 SD) than in air (10.22 ± 1.43). At lower temperatures, RMR averaged 25% higher on water than in air, increasing with similar slope. RMR was higher on water than in air for alcids, cormorants, and small penguins but not for diving ducks, which appear exceptionally resistant to heat loss in water. Changes in RMR (W) with body mass either in air or on water were mostly linear over the 5- to 20-fold body mass ranges of alcids, diving ducks, and penguins, while cormorants showed no relationship of RMR with mass. The often large energetic effects of time spent floating on water can differ substantially among major taxa of diving birds, so that relevant estimates are critical to understanding their patterns of daily energy use.

A study of photochemical againg of ambient air using Potential Aerosol Mass (PAM) chamber under the different sources and types of emissions

NASA Astrophysics Data System (ADS)

Lee, T.; Son, J.; Kim, J.; Kim, S.; Sung, K.; Park, G.; Link, M.; Park, T.; Kim, K.; Kang, S.; Ban, J.; Kim, D. S.

2016-12-01

Recent research proposed that Secondary Aerosol (SA) is important class of predicting future climate change scenarios, health effect, and a general air quality. However, there has been lack of studies to investigate SA formation all over the world. This study tried to focus on understanding potential secondary aerosol formation and its local impact by the photochemical aging of inorganic and organic aerosols in the ambient air using the Potential Aerosol Mass (PAM) chamber under the different sources and types of emissions. PAM chamber manufactured by Aerodyne make an oxidizing environment that simulates oxidation processes on timescales of 12-15 hrs in the atmosphere. Chemical compositions of ambient aerosol and aerosol that was aged in the PAM chamber were alternately measured every 2-minutes using the High Resolution-Time of Flight-Aerosol Mass Spectrometer (HR-ToF-AMS). HR-ToF-AMS provides non-refractory aerosol mass concentrations including nitrate, sulfate, hydrocarbon-like and oxygenated organic aerosol in real time. This study includes a residence area of mixture of sources, a forest site of dominant source of biogenic VOCs, an underground parking lot of dominant vehicle emission, and laboratory experiment of vehicle emissions under different fuels and speeds using the chassis dynamometer. As a result, it was revealed that gasoline and LPG vehicle relatively made more potential SA than diesel vehicle.

Extreme weather and air pollution effects on cardiovascular and respiratory hospital admissions in Cyprus.

PubMed

Tsangari, H; Paschalidou, A K; Kassomenos, A P; Vardoulakis, S; Heaviside, C; Georgiou, K E; Yamasaki, E N

2016-01-15

In many regions of the world, climatic change is associated with increased extreme temperatures, which can have severe effects on mortality and morbidity. In this study, we examine the effect of extreme weather on hospital admissions in Cyprus, for inland and coastal areas, through the use of synoptic weather classifications (air mass types). In addition, the effect of particulate air pollution (PM10) on morbidity is examined. Our results show that two air mass types, namely (a) warm, rainy days with increased levels of water vapour in the atmosphere and (b) cold, cloudy days with increased levels of precipitation, were associated with increased morbidity in the form of hospital admissions. This was true both for cardiovascular and respiratory conditions, for all age groups, but particularly for the elderly, aged over 65. Particulate air pollution was also associated with increased morbidity in Cyprus, where the effect was more pronounced for cardiovascular diseases. Copyright © 2015 Elsevier B.V. All rights reserved.

Air quality implications of the Deepwater Horizon oil spill.

PubMed

Middlebrook, Ann M; Murphy, Daniel M; Ahmadov, Ravan; Atlas, Elliot L; Bahreini, Roya; Blake, Donald R; Brioude, Jerome; de Gouw, Joost A; Fehsenfeld, Fred C; Frost, Gregory J; Holloway, John S; Lack, Daniel A; Langridge, Justin M; Lueb, Rich A; McKeen, Stuart A; Meagher, James F; Meinardi, Simone; Neuman, J Andrew; Nowak, John B; Parrish, David D; Peischl, Jeff; Perring, Anne E; Pollack, Ilana B; Roberts, James M; Ryerson, Thomas B; Schwarz, Joshua P; Spackman, J Ryan; Warneke, Carsten; Ravishankara, A R

2012-12-11

During the Deepwater Horizon (DWH) oil spill, a wide range of gas and aerosol species were measured from an aircraft around, downwind, and away from the DWH site. Additional hydrocarbon measurements were made from ships in the vicinity. Aerosol particles of respirable sizes were on occasions a significant air quality issue for populated areas along the Gulf Coast. Yields of organic aerosol particles and emission factors for other atmospheric pollutants were derived for the sources from the spill, recovery, and cleanup efforts. Evaporation and subsequent secondary chemistry produced organic particulate matter with a mass yield of 8 ± 4% of the oil mixture reaching the water surface. Approximately 4% by mass of oil burned on the surface was emitted as soot particles. These yields can be used to estimate the effects on air quality for similar events as well as for this spill at other times without these data. Whereas emission of soot from burning surface oil was large during the episodic burns, the mass flux of secondary organic aerosol to the atmosphere was substantially larger overall. We use a regional air quality model to show that some observed enhancements in organic aerosol concentration along the Gulf Coast were likely due to the DWH spill. In the presence of evaporating hydrocarbons from the oil, NO(x) emissions from the recovery and cleanup operations produced ozone.

Air quality implications of the Deepwater Horizon oil spill

PubMed Central

Middlebrook, Ann M.; Murphy, Daniel M.; Ahmadov, Ravan; Atlas, Elliot L.; Bahreini, Roya; Blake, Donald R.; Brioude, Jerome; de Gouw, Joost A.; Fehsenfeld, Fred C.; Frost, Gregory J.; Holloway, John S.; Lack, Daniel A.; Langridge, Justin M.; Lueb, Rich A.; McKeen, Stuart A.; Meagher, James F.; Meinardi, Simone; Neuman, J. Andrew; Nowak, John B.; Parrish, David D.; Peischl, Jeff; Perring, Anne E.; Pollack, Ilana B.; Roberts, James M.; Ryerson, Thomas B.; Schwarz, Joshua P.; Spackman, J. Ryan; Warneke, Carsten; Ravishankara, A. R.

2012-01-01

During the Deepwater Horizon (DWH) oil spill, a wide range of gas and aerosol species were measured from an aircraft around, downwind, and away from the DWH site. Additional hydrocarbon measurements were made from ships in the vicinity. Aerosol particles of respirable sizes were on occasions a significant air quality issue for populated areas along the Gulf Coast. Yields of organic aerosol particles and emission factors for other atmospheric pollutants were derived for the sources from the spill, recovery, and cleanup efforts. Evaporation and subsequent secondary chemistry produced organic particulate matter with a mass yield of 8 ± 4% of the oil mixture reaching the water surface. Approximately 4% by mass of oil burned on the surface was emitted as soot particles. These yields can be used to estimate the effects on air quality for similar events as well as for this spill at other times without these data. Whereas emission of soot from burning surface oil was large during the episodic burns, the mass flux of secondary organic aerosol to the atmosphere was substantially larger overall. We use a regional air quality model to show that some observed enhancements in organic aerosol concentration along the Gulf Coast were likely due to the DWH spill. In the presence of evaporating hydrocarbons from the oil, NOx emissions from the recovery and cleanup operations produced ozone. PMID:22205764

Boundary layers at a dynamic interface: Air-sea exchange of heat and mass

NASA Astrophysics Data System (ADS)

Szeri, Andrew J.

2017-04-01

Exchange of mass or heat across a turbulent liquid-gas interface is a problem of critical interest, especially in air-sea transfer of natural and anthropogenic gases involved in the study of climate. The goal in this research area is to determine the gas flux from air to sea or vice versa. For sparingly soluble nonreactive gases, this is controlled by liquid phase turbulent velocity fluctuations that act on the thin species concentration boundary layer on the liquid side of the interface. If the fluctuations in surface-normal velocity w' and gas concentration c' are known, then it is possible to determine the turbulent contribution to the gas flux. However, there is no suitable fundamental direct approach in the general case where neither w' nor c' can be easily measured. A new approach is presented to deduce key aspects about the near-surface turbulent motions from measurements that can be taken by an infrared (IR) camera. An equation is derived with inputs being the surface temperature and heat flux, and a solution method developed for the surface-normal strain experienced over time by boundary layers at the interface. Because the thermal and concentration boundary layers experience the same near-surface fluid motions, the solution for the surface-normal strain determines the gas flux or gas transfer velocity. Examples illustrate the approach in the cases of complete surface renewal, partial surface renewal, and insolation. The prospects for use of the approach in flows characterized by sheared interfaces or rapid boundary layer straining are explored.

5. Credit BG. This interior view shows the weigh room, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. Credit BG. This interior view shows the weigh room, looking west (240°): Electric lighting and scale read-outs (boxes with circular windows on the wall) are fitted with explosion-proof enclosures; these enclosures prevent malfunctioning electrical parts from sparking and starting fires or explosions. One marble table and scale have been removed at the extreme left of the view. Two remaining scales handle small and large quantities of propellants and additives. Marble tables do not absorb chemicals or conduct electricity; their mass also prevents vibration from upsetting the scales. The floor has an electrically conductive coating to dissipate static electric charges, thus preventing sparks which might ignite propellants. - Jet Propulsion Laboratory Edwards Facility, Weigh & Control Building, Edwards Air Force Base, Boron, Kern County, CA

Elbow mass flow meter

DOEpatents

McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

1994-08-16

The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

Working Characteristics of Variable Intake Valve in Compressed Air Engine

PubMed Central

Yu, Qihui; Shi, Yan; Cai, Maolin

2014-01-01

A new camless compressed air engine is proposed, which can make the compressed air energy reasonably distributed. Through analysis of the camless compressed air engine, a mathematical model of the working processes was set up. Using the software MATLAB/Simulink for simulation, the pressure, temperature, and air mass of the cylinder were obtained. In order to verify the accuracy of the mathematical model, the experiments were conducted. Moreover, performance analysis was introduced to design compressed air engine. Results show that, firstly, the simulation results have good consistency with the experimental results. Secondly, under different intake pressures, the highest output power is obtained when the crank speed reaches 500 rpm, which also provides the maximum output torque. Finally, higher energy utilization efficiency can be obtained at the lower speed, intake pressure, and valve duration angle. This research can refer to the design of the camless valve of compressed air engine. PMID:25379536

33 CFR 165.151 - Safety Zones; Fireworks Displays, Air Shows and Swim Events in the Captain of the Port Long...

Code of Federal Regulations, 2012 CFR

2012-07-01

....22″ W (NAD 83). 7.33Clam Shell Foundation Fireworks • Location: Waters of Three Mile Harbor, East..., Air Shows and Swim Events in the Captain of the Port Long Island Sound Zone. 165.151 Section 165.151... Swim Events in the Captain of the Port Long Island Sound Zone. (a) Regulations. (1) The general...

The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mernild, Sebastian Haugard; Liston, Glen

2009-01-01

In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of airmore » temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w

Material Properties Governing Co-Current Flame Spread: The Effect of Air Entrainment

NASA Technical Reports Server (NTRS)

Coutin, Mickael; Rangwala, Ali S.; Torero, Jose L.; Buckley, Steven G.

2003-01-01

A study on the effects of lateral air entrainment on an upward spreading flame has been conducted. The fuel is a flat PMMA plate of constant length and thickness but variable width. Video images and surface temperatures have allowed establishing the progression of the pyrolyis front and on the flame stand-off distance. These measurements have been incorporated into a theoretical formulation to establish characteristic mass transfer numbers ("B" numbers). The mass transfer number is deemed as a material related parameter that could be used to assess the potential of a material to sustain co-current flame spread. The experimental results show that the theoretical formulation fails to describe heat exchange between the flame and the surface. The discrepancies seem to be associated to lateral air entrainment that lifts the flame off the surface and leads to an over estimation of the local mass transfer number. Particle Image Velocimetry (PIV) measurements are in the process of being acquired. These measurements are intended to provide insight on the effect of air entrainment on the flame stand-off distance. A brief description of the methodology to be followed is presented here.

Modeling 3D conjugate heat and mass transfer for turbulent air drying of Chilean papaya in a direct contact dryer

NASA Astrophysics Data System (ADS)

Lemus-Mondaca, Roberto A.; Vega-Gálvez, Antonio; Zambra, Carlos E.; Moraga, Nelson O.

2017-01-01

A 3D model considering heat and mass transfer for food dehydration inside a direct contact dryer is studied. The k- ɛ model is used to describe turbulent air flow. The samples thermophysical properties as density, specific heat, and thermal conductivity are assumed to vary non-linearly with temperature. FVM, SIMPLE algorithm based on a FORTRAN code are used. Results unsteady velocity, temperature, moisture, kinetic energy and dissipation rate for the air flow are presented, whilst temperature and moisture values for the food also are presented. The validation procedure includes a comparison with experimental and numerical temperature and moisture content results obtained from experimental data, reaching a deviation 7-10 %. In addition, this turbulent k- ɛ model provided a better understanding of the transport phenomenon inside the dryer and sample.

Non-Methane Hydrocarbon Measurements Aboard the NOAA Research Vessel Ronald H. Brown during the 2002 New England Air Quality Study (NEAQS 2002)

NASA Astrophysics Data System (ADS)

Goldan, P. D.; Kuster, W. C.; Williams, E.; Fehsenfeld, F. C.

2003-12-01

During the NEAQS 2002 study, in-situ NMHC measurements were made aboard the NOAA research vessel Ronald H. Brown by a two channel automated gas chromatograph using both flame ionization and mass-spectrometric detection techniques. Five minute average samples were cryogenically trapped each 1/2 hour and analyzed immediately for C2 through C10 alkanes, C2 through C5 alkenes, C6 through C9 aromatics, C2 through C8 aldehydes and ketones, C1 through C5 alcohols and a variety of compounds of biogenic origin including 6 monoterpenes, isoprene and its primary oxidation products methacrolein and methylvinyl ketone. The relative contributions of these classes of compounds to OH photochemistry has been determined for air masses ranging from those showing significant anthropogenic influence to clean marine air. For the most anthropogenically influenced air masses, alkenes were observed to play a dominant role whereas oxy-hydrocarbons, principally acetaldehyde, were observed to dominate under clean marine conditions. Both the NMHC measurements and back trajectory analyses indicated periods of significant influx into the New England coastal region of urban air masses showing elevated ozone levels from the Boston/Providence urban corridor. About as frequently, less photochemically mature air masses, depleted in ozone but laden with light reactive alkenes, were observed coming from the Portsmouth NH/Kittery ME coastal urban complex. Even in the presence of these anthropogenic plumes, biogenic hydrocarbons appear to dominate OH photochemistry in the New England region much of the time. Data demonstrating all of these conclusions will be shown.

Medical and psychological aspects of mass air transportation.

DOT National Transportation Integrated Search

1971-03-01

The increase in air transportation depends not only on the technological progress and the availability of more and larger aircraft, but also on the corresponding increase in flight safety. Since, in most of the aircraft accidents, pilot error is a co...

Properties of air-aluminum thermal plasmas

NASA Astrophysics Data System (ADS)

Cressault, Y.; Gleizes, A.; Riquel, G.

2012-07-01

We present the calculation and the main results of the properties of air-aluminum thermal plasmas, useful for complete modelling of arc systems involving aluminum contacts. The properties are calculated assuming thermal equilibrium and correspond to the equilibrium composition, thermodynamic functions, transport coefficients including diffusion coefficients and net emission coefficient representing the divergence of the radiative flux in the hottest plasma regions. The calculation is developed in the temperature range between 2000 and 30 000 K, for a pressure range from 0.1 to 1 bar and for several metal mass proportions. As in the case of other metals, the presence of aluminum vapours has a strong influence on three properties at intermediate temperatures: the electron number density, the electrical conductivity and the net emission coefficient. Some comparisons with other metal vapour (Cu, Fe and Ag) properties are made and show the original behaviour for Al-containing mixtures: mass density at high temperatures is low due to the low Al atomic mass; high electrical conductivity at T < 10 000 K due to low ionization potential (around 2 V less for Al than for the other metals); very strong self-absorption of ionized aluminum lines, leading to a net emission coefficient lower than that of pure air when T > 10 000 K, in contrast to copper or iron radiation.

Investigation of air stream from combustor-liner air entry holes, 3

NASA Technical Reports Server (NTRS)

Aiba, T.; Nakano, T.

1979-01-01

Jets flowing from air entry holes of the combustor liner of a gas turbine were investigated. Cold air was supplied through the air entry holes into the primary hot gas flows. The mass flow of the primary hot gas and issuing jets was measured, and the behavior of the air jets was studied by the measurement of the temperature distribution of the gas mixture. The air jets flowing from three circular air entry holes, single streamwise long holes, and two opposing circular holes, parallel to the primary flow were studied along with the effects of jet and gas stream velocities, and of gas temperature. The discharge coefficient, the maximum penetration of the jets, the jet flow path, the mixing of the jets, and temperature distribution across the jets were investigated. Empirical expressions which describe the characteristics of the jets under the conditions of the experiments were formulated.

The Air Blast Wave from a Nuclear Explosion

NASA Astrophysics Data System (ADS)

Reines, Frederick

The sudden, large scale release of energy in the explosion of a nuclear bomb in air gives rise, in addition to nuclear emanations such as neutrons and gamma rays, to an extremely hot, rapidly expanding mass of air.** The rapidly expanding air mass has an initial temperature in the vicinity of a few hundred thousand degrees and for this reason it glows in its early stages with an intensity of many suns. It is important that the energy density in this initial "ball of fire" is of the order of 3 × 103 times that found in a detonating piece of TNT and hence that the initial stages of the large scale air motion produced by a nuclear explosion has no counterpart in an ordinary. H. E. explosion. Further, the relatively low temperatures ˜2,000°C associated with the initial stages of an H. E. detonation implies that the thermal radiation which it emits is a relatively insignificant fraction of the total energy involves. This point is made more striking when it is remembered that the thermal energy emitted by a hot object varies directly with the temperature in the Rayleigh Jeans region appropriate to the present discussion. The expansion of the air mass heated by the nuclear reaction produces, in qualitatively the same manner as in an H.E. explosion or the bursting of a high pressure balloon, an intense sharp pressure pulse, a shock wave, in the atmosphere. As the pressure pulse spreads outward it weakens due to the combined effects of divergence and the thermodynamically irreversible nature of the shock wave. The air comprising such a pressure pulse or blast wave moves first radially outward and then back towards the center as the blast wave passes. Since a permanent outward displacement of an infinite mass of air would require unlimited energy, the net outward displacement of the air distant from an explosion must approach zero with increasing distance. As the distance from the explosion is diminished the net outward displacement due to irreversible shock heating of

An air-mass trajectory study of the transport of radioactivity from Fukushima to Thessaloniki, Greece and Milan, Italy

NASA Astrophysics Data System (ADS)

Ioannidou, A.; Giannakaki, E.; Manolopoulou, M.; Stoulos, S.; Vagena, E.; Papastefanou, C.; Gini, L.; Manenti, S.; Groppi, F.

2013-08-01

Analyses of 131I, 137Cs and 134Cs in airborne aerosols were carried out in daily samples at two different sites of investigation: Thessaloniki, Greece (40° N) and Milan, Italy (45° N) after the Fukushima accident during the period of March-April, 2011. The radionuclide concentrations were determined and studied as a function of time. The 131I concentration in air over Milan and Thessaloniki peaked on April 3-4, 2011, with observed activities 467 μBq m-3 and 497 μBq m-3, respectively. The 134Cs/137Cs activity ratio values in air were around 1 in both regions, related to the burn-up history of the damaged nuclear fuel of the destroyed nuclear reactor. The high 131I/137Cs ratio, observed during the first days after the accident, followed by lower values during the following days, reflects not only the initial release ratio but also the different volatility, attachment and removal of the two isotopes during transportation due to their different physico-chemical properties. No artificial radionuclides could be detected in air after April 28, 2011 in both regions of investigation. The different maxima of airborne 131I and 134,137Cs in these two regions were related to long-range air mass transport from Japan, across the Pacific and to Central Europe. Analysis of backward trajectories was used to confirm the arrival of artificial radionuclides following atmospheric transport and processing. HYSPLIT backward trajectories were applied for the interpretation of activity variations of measured radionuclides.

Caucasian children's fat mass: routine anthropometry v. air-displacement plethysmography.

PubMed

Michels, Nathalie; Huybrechts, Inge; Bammann, Karin; Lissner, Lauren; Moreno, Luis; Peeters, Maarten; Sioen, Isabelle; Vanaelst, Barbara; Vyncke, Krishna; De Henauw, Stefaan

2013-04-28

The present paper will use fat mass percentage (FM%) obtained via BOD POD® air-displacement plethysmography (FMADP%) to examine the relative validity of (1) anthropometric measurements/indices and (2) of FM% assessed with equations (FMeq%) based on skinfold thickness and bioelectrical impedance (BIA). In 480 Belgian children (aged 5-11 years) weight, height, skinfold thickness (triceps and subscapular), body circumferences (mid-upper arm, waist and hip), foot-to-foot BIA (Tanita®) and FMADP% were measured. Anthropometric measurements and calculated indices were compared with FMADP%. Next, published equations were used to calculate FMeq% using impedance (equations of Tanita®, Tyrrell, Shaefer and Deurenberg) or skinfold thickness (equations of Slaughter, Goran, Dezenberg and Deurenberg). Both indices and equations performed better in girls than in boys. For both sexes, the sum of skinfold thicknesses resulted in the highest correlation with FMADP%, followed by triceps skinfold, arm fat area and subscapular skinfold. In general, comparing FMeq% with FMADP% indicated mostly an age and sex effect, and an increasing underestimation but less dispersion with increasing FM%. The Tanita® impedance equation and the Deurenberg skinfold equation performed the best, although none of the used equations were interchangeable with FMADP%. In conclusion, the sum of triceps and subscapular skinfold thickness is recommended as marker of FM% in the absence of specialised technologies. Nevertheless, the higher workload, cost and survey management of an immobile device like the BOD POD® remains justified.

Overlooked diagnosis of infected paratracheal air cysts in patients with respiratory symptoms: Case report.

PubMed

Bae, Kyungsoo; Jeon, Kyung N; Park, Mi J; Lee, Seung J; Kim, Ho C; Cha, Seung I; Byun, Joung H; Kim, Jong W

2017-07-01

Infected paratracheal air cysts as the focus of respiratory symptoms can be overlooked in practice because of nonspecific symptoms and physician's scant knowledge for this entity. We report 2 cases of infected paratracheal air cyst diagnosed at chest computed tomography (CT) and bronchoscopy/endobronchial ultrasound. Two patients visited our hospital with respiratory symptoms, including cough, sputum, and fever. Chest CT showed paratracheal cystic lesions with air-fluid level in the thoracic inlet. In the first patient, endobronchial ultrasound revealed a right paratracheal hypoechoic mass corresponding to the lesion on CT scan. In the second patient, bronchoscopy revealed purulent discharge from a dimpling at posterolateral wall of trachea, which was the opening of communication between the trachea and infected paratracheal air cyst. Both patients received antibiotic treatment. After medical treatment, the patients' symptoms were improved. Follow-up chest CT scans showed air-filled paratracheal air cysts without internal fluid or rim enhancement. A physician should pay attention to paratracheal air cyst in patients with respiratory symptoms when their lungs are clear on CT scan.

Sensing the flux of volatile chemicals through the air-water interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mackay, D.; Schroeder, W.H.; Ooijen, H. von

1997-12-31

There are several situations in which there is a need to assess the direction and magnitude of the flux across the air-water interface. Contaminants may be evaporating or absorbing in wastewater treatment systems in natural lake, river, estuarine and marine systems, and any attempt to compile a mass balance must include this process. In this study the authors review the theory underlying air-water exchange, then describe and discuss a sparging approach by which the direction and magnitude of the flux can be ascertained. The principle of the method is that a known flow rate of air is bubbled through themore » sparger and allowed to equilibrate with the water. The gas exiting the water surface is passed through a sorbent trap and later analyzed. The concentration, and hence the fugacity, of the contaminant in the sparged air can be deduced. In parallel, a similar flow of air from the atmosphere above the water is drawn through another sparger at a similar flow rate for a similar time and the trapped chemical analyzed giving the concentration and fugacity in the air. These data show the direction of air-water exchange (i.e. from high to low fugacity) and with information on the mass transfer coefficients and area, the flux. Successful tests were conducted of the system in a laboratory tank, in Lake Ontario and in Hamilton Harbour. Analyses of the traps showed a large number of peaks on the chromatogram many of which are believed to be of petroleum origin from fuels and vessel exhaust. The system will perform best under conditions where concentrations of specific contaminants are large, as occurs in waste water treatment systems. The approach has the potential to contribute to more accurate assessment of air-water fluxes. It avoids the problems of different analytical methodologies and the effect of sorption in the water column.« less

Multiday production of condensing organic aerosol mass in urban and forest outflow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee-Taylor, J.; Hodzic, A.; Madronich, S.

2015-01-16

Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for multiple days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (~50%) and of shorter duration (1–2 days). The multiday production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction productsmore » of both aromatics and alkanes, especially those with relatively low carbon numbers (C4–15). In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions and different vapor pressure schemes, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. The results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.« less

Multiday production of condensing organic aerosol mass in urban and forest outflow

DOE PAGES

Lee-Taylor, J.; Hodzic, A.; Madronich, S.; ...

2015-01-16

Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for multiple days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (~50%) and of shorter duration (1–2 days). The multiday production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction productsmore » of both aromatics and alkanes, especially those with relatively low carbon numbers (C4–15). In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions and different vapor pressure schemes, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. Here, the results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.« less

MEMBRANE BIOTREATMENT OF VOC-LADEN AIR

EPA Science Inventory

The paper discusses membrane biotreatment of air laden with volatile organic compounds (VOCs). Microporous flat-sheet and hollow-fiber membrane contactors were used to support air-liquid mass transfer interfaces. These modules were used in a two-step process to transfer VOCs fr...

Characterization of VOC Sources during the Texas Air Quality Study 2000 Using Proton-Transfer-Reaction Mass Spectrometry

NASA Astrophysics Data System (ADS)

Karl, T.; Jobson, T.; William, K.; Williams, E.; Stutz, J.; Goldan, P.; Fall, R.; Fehsenfeld, F.; Lindinger, W.

2002-12-01

We used Proton-Transfer-Reaction Mass Spectrometry (PTR-MS) for continuous real-time monitoring of volatile organic compounds (VOCs) at a site near the Houston Ship Channel during the Texas Air Quality Study 2000. Anthropogenic aromatics, alkenes, methanol, acetaldehyde, formaldehyde, acetone/propanal, a C7-Ketone, HCN and acrylonitrile were the most prominent compounds observed. Propene was the most abundant light-weight hydrocarbon detected by this technique, and was highly correlated with its oxidation products, formaldehyde and acetaldehyde, with typical propene-acetaldehyde ratios close to 1 in propene-dominated plumes. In the case of aromatic species the high time resolution of the obtained dataset helped in identifying different anthropogenic sources (e.g. industrial from urban emissions) and testing current emission inventories. In addition, a comparison with results from complimentary techniques (gas chromatography, differential optical absorption spectroscopy) was used to assess the selectivity of this on-line technique in a complex urban and industrial VOC matrix and give an interpretation of mass scans obtained by `soft' chemical ionization using proton-transfer via H3O+.

Demonstration of AIRS Total Ozone Products to Operations to Enhance User Readiness

NASA Technical Reports Server (NTRS)

Berndt, Emily; Zavodsky, Bradley; Jedlovec, Gary

2014-01-01

Cyclogenesis is a key forecast challenge at operational forecasting centers such as WPC and OPC, so these centers have a particular interest in unique products that can identify key storm features. In some cases, explosively developing extratropical cyclones can produce hurricane force, non-convective winds along the East Coast and north Atlantic as well as the Pacific Ocean, with the potential to cause significant damage to life and property. Therefore, anticipating cyclogenesis for these types of storms is crucial for furthering the NOAA goal of a "Weather Ready Nation". Over the last few years, multispectral imagery (i.e. RGB) products have gained popularity among forecasters. The GOES-R satellite champion at WPC/OPC has regularly evaluated the Air Mass RGB products from GOES Sounder, MODIS, and SEVIRI to aid in forecasting cyclogenesis as part of ongoing collaborations with SPoRT within the framework of the GOES-R Proving Ground. WPC/OPC has used these products to identify regions of stratospheric air associated with tropopause folds that can lead to cyclogenesis and hurricane force winds. RGB products combine multiple channels or channel differences into multi-color imagery in which different colors represent a particular cloud or air mass type. Initial interaction and feedback from forecasters evaluating the legacy Air Mass RGBs revealed some uncertainty regarding what physical processes the qualitative RGB products represent and color interpretation. To enhance forecaster confidence and interpretation of the Air Mass RGB, NASA SPoRT has transitioned a total column ozone product from AIRS retrievals to the WPC/OPC. The use of legacy AIRS demonstrates future JPSS capabilities possible with CrIS or OMPS. Since stratospheric air can be identified by anomalous potential vorticity and warm, dry, ozone-rich air, hyperspectral infrared sounder ozone products can be used in conjunction with the Air Mass RGB for identifying the role of stratospheric air in explosive

Accretion in Radiative Equipartition (AiRE) Disks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yazdi, Yasaman K.; Afshordi, Niayesh, E-mail: yyazdi@pitp.ca, E-mail: nafshordi@pitp.ca

2017-07-01

Standard accretion disk theory predicts that the total pressure in disks at typical (sub-)Eddington accretion rates becomes radiation pressure dominated. However, radiation pressure dominated disks are thermally unstable. Since these disks are observed in approximate steady state over the instability timescale, our accretion models in the radiation-pressure-dominated regime (i.e., inner disk) need to be modified. Here, we present a modification to the Shakura and Sunyaev model, where the radiation pressure is in equipartition with the gas pressure in the inner region. We call these flows accretion in radiative equipartition (AiRE) disks. We introduce the basic features of AiRE disks andmore » show how they modify disk properties such as the Toomre parameter and the central temperature. We then show that the accretion rate of AiRE disks is limited from above and below, by Toomre and nodal sonic point instabilities, respectively. The former leads to a strict upper limit on the mass of supermassive black holes as a function of cosmic time (and spin), while the latter could explain the transition between hard and soft states of X-ray binaries.« less

Accretion in Radiative Equipartition (AiRE) Disks

NASA Astrophysics Data System (ADS)

Yazdi, Yasaman K.; Afshordi, Niayesh

2017-07-01

Standard accretion disk theory predicts that the total pressure in disks at typical (sub-)Eddington accretion rates becomes radiation pressure dominated. However, radiation pressure dominated disks are thermally unstable. Since these disks are observed in approximate steady state over the instability timescale, our accretion models in the radiation-pressure-dominated regime (I.e., inner disk) need to be modified. Here, we present a modification to the Shakura & Sunyaev model, where the radiation pressure is in equipartition with the gas pressure in the inner region. We call these flows accretion in radiative equipartition (AiRE) disks. We introduce the basic features of AiRE disks and show how they modify disk properties such as the Toomre parameter and the central temperature. We then show that the accretion rate of AiRE disks is limited from above and below, by Toomre and nodal sonic point instabilities, respectively. The former leads to a strict upper limit on the mass of supermassive black holes as a function of cosmic time (and spin), while the latter could explain the transition between hard and soft states of X-ray binaries.

Mobile selected ion flow tube mass spectrometry (SIFT-MS) devices and their use for pollution exposure monitoring in breath and ambient air-pilot study.

PubMed

Storer, Malina; Salmond, Jennifer; Dirks, Kim N; Kingham, Simon; Epton, Michael

2014-09-01

Studies of health effects of air pollution exposure are limited by inability to accurately determine dose and exposure of air pollution in field trials. We explored the feasibility of using a mobile selected ion flow tube mass spectrometry (SIFT-MS) device, housed in a van, to determine ambient air and breath levels of benzene, xylene and toluene following exercise in areas of high motor vehicle traffic. The breath toluene, xylene and benzene concentration of healthy subjects were measured before and after exercising close to a busy road. The concentration of the volatile organic compounds (VOCs), in ambient air were also analysed in real time. Exercise close to traffic pollution is associated with a two-fold increase in breath VOCs (benzene, xylene and toluene) with levels returning to baseline within 20 min. This effect is not seen when exercising away from traffic pollution sources. Situating the testing device 50 m from the road reduced any confounding due to VOCs in the inspired air prior to the breath testing manoeuvre itself. Real-time field testing for air pollution exposure is possible using a mobile SIFT-MS device. This device is suitable for exploring exposure and dose relationships in a number of large scale field test scenarios.

Air Superiority at Red Flag: Mass, Technology, and Winning the Next War

DTIC Science & Technology

2009-10-01

NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Air University,Air Force Research Institute,Maxwell AFB,AL,36112 8 . PERFORMING...REPORT unclassified b. ABSTRACT unclassified c. THIS PAGE unclassified Standard Form 298 (Rev. 8 -98) Prescribed by ANSI Std Z39-18 Air University...27 8 Attrition variation versus threat aircraft . . . . . . . 30 vi Figure Page 9 Threat weapon and

[Microbial air purity in hospitals. Operating theatres with air conditioning system].

PubMed

Krogulski, Adam; Szczotko, Maciej

2010-01-01

The aim of this study was to show the influence of air conditioning control for microbial contamination of air inside the operating theatres equipped with correctly working air-conditioning system. This work was based on the results of bacteria and fungi concentration in hospital air obtained since 2001. Assays of microbial air purity conducted on atmospheric air in parallel with indoor air demonstrated that air filters applied in air-conditioning systems worked correctly in every case. To show the problem of fluctuation of bacteria concentration more precisely, every sequences of single results from successive measure series were examined independently.

Shock wave treatment shows dose-dependent enhancement of bone mass and bone strength after fracture of the femur.

PubMed

Wang, Ching-Jen; Yang, Kuender D; Wang, Feng-Sheng; Hsu, Chia-Chen; Chen, Hsiang-Ho

2004-01-01

Shock wave treatment is believed to improve bone healing after fracture. The purpose of this study was to evaluate the effect of shock wave treatment on bone mass and bone strength after fracture of the femur in a rabbit model. A standardized closed fracture of the right femur was created with a three-point bending method in 24 New Zealand white rabbits. Animals were randomly divided into three groups: (1) control (no shock wave treatment), (2) low-energy (shock wave treatment at 0.18 mJ/mm2 energy flux density with 2000 impulses), and (3) high-energy (shock wave treatment at 0.47 mJ/mm2 energy flux density with 4000 impulses). Bone mass (bone mineral density (BMD), callus formation, ash and calcium contents) and bone strength (peak load, peak stress and modulus of elasticity) were assessed at 12 and 24 weeks after shock wave treatment. While the BMD values of the high-energy group were significantly higher than the control group (P = 0.021), the BMD values between the low-energy and control groups were not statistically significant (P = 0.358). The high-energy group showed significantly more callus formation (P < 0.001), higher ash content (P < 0.001) and calcium content (P = 0.003) than the control and low-energy groups. With regard to bone strength, the high-energy group showed significantly higher peak load (P = 0.012), peak stress (P = 0.015) and modulus of elasticity (P = 0.011) than the low-energy and control groups. Overall, the effect of shock wave treatment on bone mass and bone strength appears to be dose dependent in acute fracture healing in rabbits.

This photograph shows a stream in the La Selva region of the Costa Rican rain forest, taken during NASA's AirSAR 2004 Mesoamerica campaign

NASA Image and Video Library

2004-03-04

This photograph shows a stream in the La Selva region of the Costa Rican rain forest, taken during NASA's AirSAR 2004 Mesoamerica campaign. AirSAR 2004 Mesoamerica is a three-week expedition by an international team of scientists that will use an all-weather imaging tool, called the Airborne Synthetic Aperture Radar (AirSAR) which is located onboard NASA's DC-8 airborne laboratory. Scientists from many parts of the world including NASA's Jet Propulsion Laboratory are combining ground research done in several areas in Central America with NASA's AirSAR technology to improve and expand on the quality of research they are able to do. NASA's AIRSAR technolgy provides two essential elements to the ground-based scientists. First, it tests and provides accurate measurements of the forest structure. Secondly, AirSAR can study a larger area of the forest versus the smaller area that can be tested and plotted by the ground scientists. It also provides a unique one-of-a-kind system of measurement that obtains important information for the scientists, such as where forests are located and what exactly is in them.

Mass and heat transfer model of Tubular Solar Still

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahsan, Amimul; Fukuhara, Teruyuki

2010-07-15

In this paper, a new mass and heat transfer model of a Tubular Solar Still (TSS) was proposed incorporating various mass and heat transfer coefficients taking account of the humid air properties inside the still. The heat balance of the humid air and the mass balance of the water vapor in the humid air were formulized for the first time. As a result, the proposed model enabled to calculate the diurnal variations of the temperature, water vapor density and relative humidity of the humid air, and to predict the hourly condensation flux besides the temperatures of the water, cover andmore » trough, and the hourly evaporation flux. The validity of the proposed model was verified using the field experimental results carried out in Fukui, Japan and Muscat, Oman in 2008. The diurnal variations of the calculated temperatures and water vapor densities had a good agreement with the observed ones. Furthermore, the proposed model can predict the daily and hourly production flux precisely. (author)« less

Characterisation of a smartphone image sensor response to direct solar 305nm irradiation at high air masses.

PubMed

Igoe, D P; Amar, A; Parisi, A V; Turner, J

2017-06-01

This research reports the first time the sensitivity, properties and response of a smartphone image sensor that has been used to characterise the photobiologically important direct UVB solar irradiances at 305nm in clear sky conditions at high air masses. Solar images taken from Autumn to Spring were analysed using a custom Python script, written to develop and apply an adaptive threshold to mitigate the effects of both noise and hot-pixel aberrations in the images. The images were taken in an unobstructed area, observing from a solar zenith angle as high as 84° (air mass=9.6) to local solar maximum (up to a solar zenith angle of 23°) to fully develop the calibration model in temperatures that varied from 2°C to 24°C. The mean ozone thickness throughout all observations was 281±18 DU (to 2 standard deviations). A Langley Plot was used to confirm that there were constant atmospheric conditions throughout the observations. The quadratic calibration model developed has a strong correlation between the red colour channel from the smartphone with the Microtops measurements of the direct sun 305nm UV, with a coefficient of determination of 0.998 and very low standard errors. Validation of the model verified the robustness of the method and the model, with an average discrepancy of only 5% between smartphone derived and Microtops observed direct solar irradiances at 305nm. The results demonstrate the effectiveness of using the smartphone image sensor as a means to measure photobiologically important solar UVB radiation. The use of ubiquitous portable technologies, such as smartphones and laptop computers to perform data collection and analysis of solar UVB observations is an example of how scientific investigations can be performed by citizen science based individuals and groups, communities and schools. Copyright © 2017 Elsevier B.V. All rights reserved.

Remediation of Chlorinated Solvent Plumes Using In-Situ Air Sparging—A 2-D Laboratory Study

PubMed Central

Adams, Jeffrey A.; Reddy, Krishna R.; Tekola, Lue

2011-01-01

In-situ air sparging has evolved as an innovative technique for soil and groundwater remediation impacted with volatile organic compounds (VOCs), including chlorinated solvents. These may exist as non-aqueous phase liquid (NAPL) or dissolved in groundwater. This study assessed: (1) how air injection rate affects the mass removal of dissolved phase contamination, (2) the effect of induced groundwater flow on mass removal and air distribution during air injection, and (3) the effect of initial contaminant concentration on mass removal. Dissolved-phase chlorinated solvents can be effectively removed through the use of air sparging; however, rapid initial rates of contaminant removal are followed by a protracted period of lower removal rates, or a tailing effect. As the air flow rate increases, the rate of contaminant removal also increases, especially during the initial stages of air injection. Increased air injection rates will increase the density of air channel formation, resulting in a larger interfacial mass transfer area through which the dissolved contaminant can partition into the vapor phase. In cases of groundwater flow, increased rates of air injection lessened observed downward contaminant migration effect. The air channel network and increased air saturation reduced relative hydraulic conductivity, resulting in reduced groundwater flow and subsequent downgradient contaminant migration. Finally, when a higher initial TCE concentration was present, a slightly higher mass removal rate was observed due to higher volatilization-induced concentration gradients and subsequent diffusive flux. Once concentrations are reduced, a similar tailing effect occurs. PMID:21776228

Remediation of chlorinated solvent plumes using in-situ air sparging--a 2-D laboratory study.

PubMed

Adams, Jeffrey A; Reddy, Krishna R; Tekola, Lue

2011-06-01

In-situ air sparging has evolved as an innovative technique for soil and groundwater remediation impacted with volatile organic compounds (VOCs), including chlorinated solvents. These may exist as non-aqueous phase liquid (NAPL) or dissolved in groundwater. This study assessed: (1) how air injection rate affects the mass removal of dissolved phase contamination, (2) the effect of induced groundwater flow on mass removal and air distribution during air injection, and (3) the effect of initial contaminant concentration on mass removal. Dissolved-phase chlorinated solvents can be effectively removed through the use of air sparging; however, rapid initial rates of contaminant removal are followed by a protracted period of lower removal rates, or a tailing effect. As the air flow rate increases, the rate of contaminant removal also increases, especially during the initial stages of air injection. Increased air injection rates will increase the density of air channel formation, resulting in a larger interfacial mass transfer area through which the dissolved contaminant can partition into the vapor phase. In cases of groundwater flow, increased rates of air injection lessened observed downward contaminant migration effect. The air channel network and increased air saturation reduced relative hydraulic conductivity, resulting in reduced groundwater flow and subsequent downgradient contaminant migration. Finally, when a higher initial TCE concentration was present, a slightly higher mass removal rate was observed due to higher volatilization-induced concentration gradients and subsequent diffusive flux. Once concentrations are reduced, a similar tailing effect occurs.

Back-trajectory modelling and DNA-based species-specific detection methods allow tracking of fungal spore transport in air masses.

PubMed

Grinn-Gofroń, Agnieszka; Sadyś, Magdalena; Kaczmarek, Joanna; Bednarz, Aleksandra; Pawłowska, Sylwia; Jedryczka, Malgorzata

2016-11-15

Recent advances in molecular detection of living organisms facilitate the introduction of novel methods to studies of the transport of fungal spores over large distances. Monitoring the migration of airborne fungi using microscope based spore identification is limited when different species produce very similar spores. In our study, DNA-based monitoring with the use of species-specific probes allowed us to track the aerial movements of two important fungal pathogens of oilseed rape (Brassica napus L.), i.e., Leptosphaeria maculans and Leptosphaeria biglobosa, which have identical spore shape and size. The fungi were identified using dual-labelled fluorescent probes that were targeted to a β-tubulin gene fragment of either Leptosphaeria species. Spore identification by Real-Time PCR techniques capable of detecting minute amounts of DNA of selected fungal species was combined with back-trajectory analysis, allowing the tracking of past movements of air masses using the Hybrid Single Particle Lagrangian Integrated Trajectory model. Over a study period spanning the previous decade (2006-2015) we investigated two specific events relating to the long distance transport of Leptosphaeria spp. spores to Szczecin in North-West Poland. Based on the above mentioned methods and the results obtained with the additional spore sampler located in nearby Szczecin, and operating at the ground level in an oilseed rape field, we have demonstrated that on both occasions the L. biglobosa spores originated from the Jutland Peninsula. This is the first successful attempt to combine analysis of back-trajectories of air masses with DNA-based identification of economically important pathogens of oilseed rape in Europe. In our studies, the timing of L. biglobosa ascospore dispersal in the air was unlikely to result in the infection of winter oilseed rape grown as a crop plant. However, the fungus could infect other host plants, such as vegetable brassicas, cruciferous weeds, spring rapeseed

Lidar derived properties of air-masses advected from Ukraine, Sahara and Carpathian mountains to Warsaw, Poland on 9 - 11 August 2015

NASA Astrophysics Data System (ADS)

Janicka, Lucja; Szczepanik, Dominika; Borek, Karolina; Heese, Birgit; Stachlewska, Iwona S.

2018-04-01

The aerosol layers of different origin, suspended in the atmosphere on 9-11 August 2015 were observed with the PollyXT-UW lidar in Warsaw, Poland. The HYSPLIT ensemble backward trajectories indicate that the observed air-masses attribute to a few different sources, among others, possible transport paths from Ukraine, Slovakia, and Africa. In this paper, we attempt to analyse and discuss the properties of aerosol particles of different origin that were suspended over Warsaw during this event.

Synthesis and Mass Spectrometric Characterization of Organic Nitrates

NASA Astrophysics Data System (ADS)

Grünert, A.; Woidich, S.; Ballschmiter, K.

2003-04-01

Organic nitrates, as trace constituents in urban air, can be analyzed by adsorptive low volume sampling (LVS) as well as by adsorptive high volume sampling (HVS). Air samples ranging from 25 L to 100 L for the LVS and 100 m3 to 500 m3 for the (HVS) were collected, respectively. Analysis is performed by thermodesorption (LVS) or solvent elution combined with group separation (HVS) using normal-phase HPLC and high resolution capillary gas chromatography with electron capture detection (HRGC-ECD) and mass selective detection (HRGC-MSD). For identification and quantification available reference compounds are required for both methods (1;2). Following numbers of congeners of organic nitrate have been synthesized: 77 monoalkyl nitrates (C1-C16), 43 dialkyl nitrates (C2-C10), 37 hydroxy alkyl nitrates (C2-C8) and 41 carbonyl alkyl nitrates (C3-C12). Alkanes, alkenes, alcohols, ketones and halocarbons have been used as precursors. Characterisation of the reference compounds by retention-data and mass-spectra was performed by high resolution capillary gas chromatography with mass selective detection in the EI- and the NCI (CH4) mode (1-3). EI-ionization leads to the dominating indicator ion NO2+ for organic nitrates with m/z = 46 u. The characteristic fragments with NCI (CH4) show ions at m/z = 46 u and m/z = 62 u, corresponding to NO2- and NO3-. The use of flame ionisation detection (HRGC-FID) and the principle of the molar response for carbon allows the quantitation of reference solutions as the final tool for the determination of the levels and patterns of organic nitrates in urban air samples. (1) J. Kastler: "Analytik, Massenspektrometrie und Vorkommen multifunktioneller Alkylnitrate in belasteter und unbelasteter Atmosphäre" Dr.rer.nat.-Thesis, University of Ulm (1999) (2) G. Werner, J. Kastler, R. Looser, K. Ballschmiter: "Organic Nitrates of Isoprenes as Atmospheric Trace Compounds" Angew. Chem. Int. Ed. (1999) 38(11): 1634-1637 (3) S.Woidich, O. Froscheis, O

On the importance of the heat and mass transfer resistances in internally-cooled liquid desiccant dehumidifiers and regenerators

DOE PAGES

Woods, Jason; Kozubal, Eric

2018-02-06

Liquid desiccant heat and mass exchangers are a promising technology for efficient humidity control in buildings. Many researchers have investigated these exchangers, often using numerical models to predict their performance. However, there is a lack of information in the literature on the magnitude of the heat and mass transfer resistances, both for the dehumidifier (which absorbs moisture from the air) and the regenerator (which heats the liquid desiccant to re-concentrate it). This article focuses on internally-cooled, 3-fluid exchangers in a parallel plate geometry. Water heats or cools a desiccant across a plate, and the desiccant absorbs or releases water intomore » an airstream through a membrane. A sensitivity analysis was used to estimate the importance of each of the heat and mass transfer resistances (air, membrane, desiccant, plate, water), and how it changes with different design geometries. The results show that, for most designs, the latent and sensible heat transfer of the dehumidifier is dominated by the air mass transfer resistance and air heat transfer resistance, respectively. The air mass transfer resistance is also important for the regenerator, but much less so; the change in the desiccant equilibrium humidity ratio due to a change in either temperature or desiccant mass fraction is much higher at the regenerator's higher temperatures. This increases the importance of (1) getting heat from the water to the desiccant/membrane interface, and (2) diffusing salt ions quickly away from the desiccant/membrane interface. The membrane heat transfer and water heat transfer resistances were found to be the least important. These results can help inform decisions about what simplifying assumptions to make in numerical models, and can also help in designing these exchangers by understanding which resistances are most important.« less

On the importance of the heat and mass transfer resistances in internally-cooled liquid desiccant dehumidifiers and regenerators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woods, Jason; Kozubal, Eric

Liquid desiccant heat and mass exchangers are a promising technology for efficient humidity control in buildings. Many researchers have investigated these exchangers, often using numerical models to predict their performance. However, there is a lack of information in the literature on the magnitude of the heat and mass transfer resistances, both for the dehumidifier (which absorbs moisture from the air) and the regenerator (which heats the liquid desiccant to re-concentrate it). This article focuses on internally-cooled, 3-fluid exchangers in a parallel plate geometry. Water heats or cools a desiccant across a plate, and the desiccant absorbs or releases water intomore » an airstream through a membrane. A sensitivity analysis was used to estimate the importance of each of the heat and mass transfer resistances (air, membrane, desiccant, plate, water), and how it changes with different design geometries. The results show that, for most designs, the latent and sensible heat transfer of the dehumidifier is dominated by the air mass transfer resistance and air heat transfer resistance, respectively. The air mass transfer resistance is also important for the regenerator, but much less so; the change in the desiccant equilibrium humidity ratio due to a change in either temperature or desiccant mass fraction is much higher at the regenerator's higher temperatures. This increases the importance of (1) getting heat from the water to the desiccant/membrane interface, and (2) diffusing salt ions quickly away from the desiccant/membrane interface. The membrane heat transfer and water heat transfer resistances were found to be the least important. These results can help inform decisions about what simplifying assumptions to make in numerical models, and can also help in designing these exchangers by understanding which resistances are most important.« less

Mass Airflow Cabinet for Control of Airborne Infection of Laboratory Rodents

PubMed Central

McGarrity, Gerard J.; Coriell, Lewis L.

1973-01-01

A mass airflow cabinet for handling and housing of laboratory rodents has been developed and tested. The unit consists of a high-efficiency particulate air filter and uniform distribution of air at a vertical velocity of 19 cm per s. Animals are maintained without bedding in mesh-bottomed cages that rest on rollers for rotation inside the cabinet. There is an air barrier of 90 cm per s separating the cabinet air from room air. Sampling for airborne bacteria yielded an average of 0.03 colony-forming units (CFU) per ft3 of air inside the cabinet, whereas 28.8 CFU per ft3 was simultaneously detected outside the cabinet during housekeeping, a reduction of almost three logs. The efficiency of the air barrier was tested by aerosolization of T3 phage. When phage was aerosolized 5 cm outside the cabinet, no phage could be detected 5 cm inside when the fans were operating; with the fans off an average of 1.6 × 104 plaque-forming units (PFU) per ft3 was detected in six tests. Aerosolization of phage inside the cabinet yielded an average of 9 × 10 PFU per ft3 outside; an average of 4.1 × 106 PFU per ft3 were detected with the fans not in operation, a reduction of more than four logs. In-use studies on effectiveness showed that the cabinet significantly reduced the incidence of mice originally titer-free to Reo-3 virus. Hemagglutination inhibition antibodies to Reo-3 were detected in 9/22 (42%) mice housed in a conventionally ventilated animal laboratory while no seroconversion was detected in any of 22 mice housed in the mass air flow cabinet in the same laboratory. Images PMID:4355261

Mass airflow cabinet for control of airborne infection of laboratory rodents.

PubMed

McGarrity, G J; Coriell, L L

1973-08-01

A mass airflow cabinet for handling and housing of laboratory rodents has been developed and tested. The unit consists of a high-efficiency particulate air filter and uniform distribution of air at a vertical velocity of 19 cm per s. Animals are maintained without bedding in mesh-bottomed cages that rest on rollers for rotation inside the cabinet. There is an air barrier of 90 cm per s separating the cabinet air from room air. Sampling for airborne bacteria yielded an average of 0.03 colony-forming units (CFU) per ft(3) of air inside the cabinet, whereas 28.8 CFU per ft(3) was simultaneously detected outside the cabinet during housekeeping, a reduction of almost three logs. The efficiency of the air barrier was tested by aerosolization of T3 phage. When phage was aerosolized 5 cm outside the cabinet, no phage could be detected 5 cm inside when the fans were operating; with the fans off an average of 1.6 x 10(4) plaque-forming units (PFU) per ft(3) was detected in six tests. Aerosolization of phage inside the cabinet yielded an average of 9 x 10 PFU per ft(3) outside; an average of 4.1 x 10(6) PFU per ft(3) were detected with the fans not in operation, a reduction of more than four logs. In-use studies on effectiveness showed that the cabinet significantly reduced the incidence of mice originally titer-free to Reo-3 virus. Hemagglutination inhibition antibodies to Reo-3 were detected in 9/22 (42%) mice housed in a conventionally ventilated animal laboratory while no seroconversion was detected in any of 22 mice housed in the mass air flow cabinet in the same laboratory.

STEAM PLANT, TRA609. SECTION A SHOWS FEATURES OF NORTH/SOUTH AXIS: ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

STEAM PLANT, TRA-609. SECTION A SHOWS FEATURES OF NORTH/SOUTH AXIS: STEAM GENERATOR AND CATWALK, STACK, DEGREASER FEED WATER HEATER IN PENTHOUSE, MEZZANINE, SURGE TANK PIT (BELOW GROUND LEVEL). UTILITY ROOM SHOWS DIESEL ENGINE GENERATORS, AIR TANKS, STARTING AIR COMPRESSORS. OUTSIDE SOUTH END ARE EXHAUST MUFFLER, AIR INTAKE OIL FILTER, RADIATOR COOLING UNIT, AIR SURGE TANK. SECTION B CROSSES WEST TO EAST NEAR SOUTH END OF BUILDING TO SHOW ARRANGEMENT OF DIESEL ENGINE GENERATOR, AIR DRIER, AFTER COOLER, AIR COMPRESSOR, AND BLOWDOWN TANK. BLAW-KNOX 3150-9-2, 6/1950. INL INDEX NO. 431-0609-00-098-100018, REV. 3. - Idaho National Engineering Laboratory, Test Reactor Area, Materials & Engineering Test Reactors, Scoville, Butte County, ID

Monitoring an air pollution episode in Shenzhen by combining MODIS satellite images and the HYSPLIT model

NASA Astrophysics Data System (ADS)

Li, Lili; Liu, Yihong; Wang, Yunpeng

2017-07-01

Urban air pollution is influenced not only by local emission sources including industry and vehicles, but also greatly by regional atmospheric pollutant transportation from the surrounding areas, especially in developed city clusters, like the Pearl River Delta (PRD). Taking an air pollution episode in Shenzhen as an example, this paper investigates the occurrence and evolution of the pollution episode and identifies the transport pathways of air pollutants in Shenzhen by combining MODIS satellite images and HYSPLIT back trajectory analysis. Results show that this pollution episode is mainly caused by the local emission of pollutants in PRD and oceanic air masses under specific weather conditions.

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 33 2011-07-01 2011-07-01 false Dilution air background emission...

40 CFR 1065.667 - Dilution air background emission correction.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.667 Dilution air background emission correction. (a) To determine the mass of background emissions to subtract... 40 Protection of Environment 34 2012-07-01 2012-07-01 false Dilution air background emission...

Mass, height of burst, and source–receiver distance constraints on the acoustic coda phase delay method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Albert, Sarah; Bowman, Daniel; Rodgers, Arthur

Here, this research uses the acoustic coda phase delay method to estimate relative changes in air temperature between explosions with varying event masses and heights of burst. It also places a bound on source–receiver distance for the method. Previous studies used events with different shapes, height of bursts, and masses and recorded the acoustic codas at source–receiver distances less than 1 km. This research further explores the method using explosions that differ in mass (by up to an order of magnitude) and are placed at varying heights. Source–receiver distances also cover an area out to 7 km. Relative air temperaturemore » change estimates are compared to complementary meteorological observations. Results show that two explosions that differ by an order of magnitude cannot be used with this method because their propagation times in the near field and their fundamental frequencies are different. These differences are expressed as inaccuracies in the relative air temperature change estimates. An order of magnitude difference in mass is also shown to bias estimates higher. Small differences in height of burst do not affect the accuracy of the method. Finally, an upper bound of 1 km on source–receiver distance is provided based on the standard deviation characteristics of the estimates.« less

Mass, height of burst, and source–receiver distance constraints on the acoustic coda phase delay method

DOE PAGES

Albert, Sarah; Bowman, Daniel; Rodgers, Arthur; ...

2018-04-23

Here, this research uses the acoustic coda phase delay method to estimate relative changes in air temperature between explosions with varying event masses and heights of burst. It also places a bound on source–receiver distance for the method. Previous studies used events with different shapes, height of bursts, and masses and recorded the acoustic codas at source–receiver distances less than 1 km. This research further explores the method using explosions that differ in mass (by up to an order of magnitude) and are placed at varying heights. Source–receiver distances also cover an area out to 7 km. Relative air temperaturemore » change estimates are compared to complementary meteorological observations. Results show that two explosions that differ by an order of magnitude cannot be used with this method because their propagation times in the near field and their fundamental frequencies are different. These differences are expressed as inaccuracies in the relative air temperature change estimates. An order of magnitude difference in mass is also shown to bias estimates higher. Small differences in height of burst do not affect the accuracy of the method. Finally, an upper bound of 1 km on source–receiver distance is provided based on the standard deviation characteristics of the estimates.« less

Inter-annual variability of air mass and acidified pollutants transboundary exchange in the north-eastern part of the EANET region

NASA Astrophysics Data System (ADS)

Gromov, Sergey A.; Trifonova-Yakovleva, Alisa; Gromov, Sergey S.

2016-04-01

Anthropogenic emissions, be it exhaust gases or aerosols, stem from multitude of sources and may survive long-range transport within the air masses they were emitted into. So they follow regional and global transport pathways varying under different climatological regimes. Transboundary transfer of pollutants occurs this way and has a significant impact on the ecological situation of the territories neighbouring those of emission sources, as found in a few earlier studies examining the environmental monitoring data [1]. In this study, we employ a relatively facile though robust technique for estimating the transboundary air and concomitant pollutant fluxes using actual or climatological meteorological and air pollution monitoring data. Practically, we assume pollutant transfer being proportional to the horizontal transport of air enclosed in the lower troposphere and to the concentration of the pollutant of interest. The horizontal transport, in turn, is estimated using the mean layer wind direction and strength, or their descriptive statistics at the individual transects of the boundary of interest. The domain of our interest is the segment of Russian continental border in East Asia spanning from 88° E (southern Middle Siberia) to 135° E (Far East at Pacific shore). The data on atmospheric pollutants concentration are available from the Russian monitoring sites of the region-wide Acid Deposition Monitoring Network in East Asia (EANET, http://www.eanet.asia/) Mondy (Baikal area) and Primorskaya (near Vladivostok). The data comprises multi-year continuous measurement of gas-phase and particulate species abundances in air with at least biweekly sampling rate starting from 2000. In the first phase of our study, we used climatological dataset on winds derived from the aerological soundings at Russian stations along the continental border for the 10-year period (1961-1970) by the Research Institute of Hydrometeorological Information - World Data Centre (RIHMI-WDC) [3

Six years of surface remote sensing of stratiform warm clouds in marine and continental air over Mace Head, Ireland

NASA Astrophysics Data System (ADS)

Preißler, Jana; Martucci, Giovanni; Saponaro, Giulia; Ovadnevaite, Jurgita; Vaishya, Aditya; Kolmonen, Pekka; Ceburnis, Darius; Sogacheva, Larisa; de Leeuw, Gerrit; O'Dowd, Colin

2016-12-01

A total of 118 stratiform water clouds were observed by ground-based remote sensing instruments at the Mace Head Atmospheric Research Station on the west coast of Ireland from 2009 to 2015. Microphysical and optical characteristics of these clouds were studied as well as the impact of aerosols on these properties. Microphysical and optical cloud properties were derived using the algorithm SYRSOC (SYnergistic Remote Sensing Of Clouds). Ground-based in situ measurements of aerosol concentrations and the transport path of air masses at cloud level were investigated as well. The cloud properties were studied in dependence of the prevailing air mass at cloud level and season. We found higher cloud droplet number concentrations (CDNC) and smaller effective radii (reff) with greater pollution. Median CDNC ranged from 60 cm-3 in marine air masses to 160 cm-3 in continental air. Median reff ranged from 8 μm in polluted conditions to 10 μm in marine air. Effective droplet size distributions were broader in marine than in continental cases. Cloud optical thickness (COT) and albedo were lower in cleaner air masses and higher in more polluted conditions, with medians ranging from 2.1 to 4.9 and 0.22 to 0.39, respectively. However, calculation of COT and albedo was strongly affected by liquid water path (LWP) and departure from adiabatic conditions. A comparison of SYRSOC results with MODIS (Moderate-Resolution Imaging Spectroradiometer) observations showed large differences for LWP and COT but good agreement for reff with a linear fit with slope near 1 and offset of -1 μm.

Is PM(10) mass measurement a reliable index for air quality assessment? An environmental study in a geographical area of north-eastern Italy.

PubMed

Cozzi, F; Adami, G; Barbieri, P; Reisenhofer, E; Bovenzi, M

2008-09-01

The aim of this study was to measure the concentration of some metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Ti) in PM(10) samples collected in one urban and one industrial site and to assess that PM(10) total mass measurement may be not sufficient as air quality index due to its complex composition. Metals were determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and differential pulsed anodic stripping voltammetry (DPASV). The measured concentrations were used to calculate the content of metals in the PM(10) total mass, and to estimate the enrichment factors and the correlations between PM(10), metal concentrations and meteorological data for the two sites. The mean PM10 concentration during the sampling period in the urban site exceeded the annual European Union (EU) standard (40 microg/m(3)) and, for some sampling days, the daily EU standard (50 microg/m(3)) was also exceeded. In opposite, both EU standards were never exceeded in the industrial site. The overall metal content was nearly double in the industrial site compared to the urban one, and the mean Ni concentration exceeded the EU annual limit value (10 ng/m(3)). The metals with the highest enrichment factor were Cd, Cu, Ni and Pb for both sites, suggesting a dominant anthropogenic source for these metals. Metal concentrations were very low and typical of rural background during Christmas holidays, when factories were closed. PM(10) total mass measurement is not a sufficient air quality index since the metal content of PM(10) is not related to its total mass, especially in sites with industrial activities. This measurement should be associated with the analysis of toxic metals.

Evaluation of automotive mass airflow sensors for animal environment research and control

USDA-ARS?s Scientific Manuscript database

Mass air flow is an important parameter to consider in animal research applications, especially for the generation of heat and moisture production data. The high flow rates and low operating pressures in animal research facilities present a unique and costly challenge for measurement of mass air fl...

Mass and Ozone Fluxes from the Lowermost Stratosphere

NASA Technical Reports Server (NTRS)

Schoeberl, Mark R.; Olsen, Mark A.

2004-01-01

Net mass flux from the stratosphere to the troposphere can be computed from the heating rate along the 380K isentropic surface and the time rate of change of the mass of the lowermost stratosphere (the region between the tropopause and the 380K isentrope). Given this net mass flux and the cross tropopause diabatic mass flux, the residual adiabatic mass flux across the tropopause can also be estimated. These fluxes have been computed using meteorological fields from a free-running general circulation model (FVGCM) and two assimilation data sets, FVDAS, and UKMO. The data sets tend to agree that the annual average net mass flux for the Northern Hemisphere is about 1P10 kg/s. There is less agreement on the southern Hemisphere flux that might be half as large. For all three data sets, the adiabatic mass flux is computed to be from the upper troposphere into the lowermost stratosphere. This flux will dilute air entering from higher stratospheric altitudes. The mass fluxes are convolved with ozone mixing ratios from the Goddard 3D CTM (which uses the FVGCM) to estimate the cross-tropopause transport of ozone. A relatively large adiabatic flux of tropospheric ozone from the tropical upper troposphere into the extratropical lowermost stratosphere dilutes the stratospheric air in the lowermost stratosphere. Thus, a significant fraction of any measured ozone STE may not be ozone produced in the higher Stratosphere. The results also illustrate that the annual cycle of ozone concentration in the lowermost stratosphere has as much of a role as the transport in the seasonal ozone flux cycle. This implies that a simplified calculation of ozone STE mass from air mass and a mean ozone mixing ratio may have a large uncertainty.

Survey and Experimental Testing of Nongravimetric Mass Measurement Devices

NASA Technical Reports Server (NTRS)

Oakey, W. E.; Lorenz, R.

1977-01-01

Documentation presented describes the design, testing, and evaluation of an accelerated gravimetric balance, a low mass air bearing oscillator of the spring-mass type, and a centrifugal device for liquid mass measurement. A direct mass readout method was developed to replace the oscillation period readout method which required manual calculations to determine mass. A protoype 25 gram capacity micro mass measurement device was developed and tested.

Evaluation of Long-term Performance of Enhanced Anaerobic Source Zone Bioremediation using mass flux

NASA Astrophysics Data System (ADS)

Haluska, A.; Cho, J.; Hatzinger, P.; Annable, M. D.

2017-12-01

Chlorinated ethene DNAPL source zones in groundwater act as potential long term sources of contamination as they dissolve yielding concentrations well above MCLs, posing an on-going public health risk. Enhanced bioremediation has been applied to treat many source zones with significant promise, but long-term sustainability of this technology has not been thoroughly assessed. This study evaluated the long-term effectiveness of enhanced anaerobic source zone bioremediation at chloroethene contaminated sites to determine if the treatment prevented contaminant rebound and removed NAPL from the source zone. Long-term performance was evaluated based on achieving MCL-based contaminant mass fluxes in parent compound concentrations during different monitoring periods. Groundwater concertation versus time data was compiled for 6-sites and post-remedial contaminant mass flux data was then measured using passive flux meters at wells both within and down-gradient of the source zone. Post-remedial mass flux data was then combined with pre-remedial water quality data to estimate pre-remedial mass flux. This information was used to characterize a DNAPL dissolution source strength function, such as the Power Law Model and the Equilibrium Stream tube model. The six-sites characterized for this study were (1) Former Charleston Air Force Base, Charleston, SC; (2) Dover Air Force Base, Dover, DE; (3) Treasure Island Naval Station, San Francisco, CA; (4) Former Raritan Arsenal, Edison, NJ; (5) Naval Air Station, Jacksonville, FL; and, (6) Former Naval Air Station, Alameda, CA. Contaminant mass fluxes decreased for all the sites by the end of the post-treatment monitoring period and rebound was limited within the source zone. Post remedial source strength function estimates suggest that decreases in contaminant mass flux will continue to occur at these sites, but a mass flux based on MCL levels may never be exceeded. Thus, site clean-up goals should be evaluated as order

Precision Determination of Adsorption Layers on Stainless Steel Mass Standards by Mass Comparison and Ellipsometry: Part I: Adsorption Isotherms in Air

NASA Astrophysics Data System (ADS)

Schwartz, R.

1994-01-01

Adsorption layers on stainless steel mass standards (OIML classes E1 and E2) have been determined directly and precisely by the optical method of ellipsometry as a function of relative humidity in the range 0,03 <= h <= 0,77, the relevant influencing factors being surface cleanliness, roughness, steel composition and ambient temperature. Under the same environmental conditions, two pairs of 1 kg artefacts, having geometrical surfaces differing in area by about δ A = 390 cm2, but the same material properties and surface finish as the mass standards, have been compared on a 1 kg mass comparator. The two independent measuring techniques yield strongly correlated results, the standard uncertainties of the measured surface coverings being mass standards is mainly influenced by the degree of surface cleanliness: uncleaned standards with an absolute surface covering of μ' >= 0,7 μg cm-2 show sorption-induced mass variations which are greater by about a factor of 2,5 relative to the clean surfaces.

7. DETAIL SHOWING BLAST SHIELDED WINDOWS, WEST SIDE. Edwards ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. DETAIL SHOWING BLAST SHIELDED WINDOWS, WEST SIDE. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Instrumentation & Control Building, Test Area 1-115, northwest end of Saturn Boulevard, Boron, Kern County, CA

Vacuum Technology Considerations For Mass Metrology

PubMed Central

Abbott, Patrick J.; Jabour, Zeina J.

2011-01-01

Vacuum weighing of mass artifacts eliminates the necessity of air buoyancy correction and its contribution to the measurement uncertainty. Vacuum weighing is also an important process in the experiments currently underway for the redefinition of the SI mass unit, the kilogram. Creating the optimum vacuum environment for mass metrology requires careful design and selection of construction materials, plumbing components, pumping, and pressure gauging technologies. We review the vacuum technology1 required for mass metrology and suggest procedures and hardware for successful and reproducible operation. PMID:26989593

On-line monitoring of benzene air concentrations while driving in traffic by means of isotopic dilution gas chromatography/mass spectrometry.

PubMed

Davoli, E; Cappellini, L; Moggi, M; Ferrari, S; Fanelli, R

1996-01-01

There is no shortage of information about the average benzene concentrations in urban air, but there is very little about microenvironmental exposure, such as in-vehicle concentrations while driving in various traffic conditions, while refuelling, or while in a parking garage. The main reason for this lack of data is that no analytical instrumentation has been available to measure on-line trace amounts of benzene in such situations. We have recently proposed a highly accurate, high-speed cryofocusing gas chromatography/mass spectrometry (GC/MS) system for monitoring benzene concentrations in air. Accuracy of the analytical data is achieved by enrichment of the air sample before trapping, with a stable isotope permeation tube system. The same principles have been applied to a new instrument, specifically designed for operation on an electric vehicle (Ducato Elettra, Fiat). The zero emission vehicle and the fully transportable, battery-operated GC/MS system provide a unique possibility of monitoring benzene exposure in real everyday situations such as while driving, refuelling, or repairing a car. All power consumptions have been reduced so as to achieve a battery-operated GC/MS system. Liquid nitrogen cryofocusing has been replaced by a packed, inductively heated, graphitized charcoal microtrap. The instrument has been mounted on shock absorbers and installed in the van. The whole system has been tested in both fixed and mobile conditions. The maximum monitoring period without external power supply is 6 h. The full analytical cycle is 4 min, allowing close to real-time monitoring, and the minimum detectable level is 1 microgram/m3 for benzene. In-vehicle monitoring showed that, when recirculation was off and ventilation on, i.e., air from outside the vehicle was blown inside, concentrations varied widely in different driving conditions: moving from a parking lot into normal traffic on an urban traffic condition roadway yielded an increase in benzene concentration

An assessment of hopanes in settled dust and air as indicators of exposure to traffic-related air pollution in Windsor, Ontario

NASA Astrophysics Data System (ADS)

Curran, Jason

Traffic-related air pollution (TRAP) has been linked with several adverse health effects. We investigated hopanes, markers of primary particle emissions from gasoline and diesel engines, in house dust as an alternative approach for assessing exposure to TRAP in Windsor, Ontario. Settled house dust was collected from the homes of 28 study participants (10 -- 13 yrs). The dust was then analyzed for a suite of hopanes by gas chromatography-mass spectrometry. We calculated correlations between dust hopane concentrations and estimates of annual average NO2 concentrations derived from an existing LUR model. Hopanes were consistently present in detectable quantities in house dust. Annual average outdoor NO2 estimated was moderately correlated with hopanes in house dust (r = 0.46; p<0.05). The correlations did not vary by infiltration efficiency or the presence of an attached garage. Hopanes measured in settled house dust show promise as an indicator of long-term exposure to traffic-related air pollution. Keywords: hopane; air pollution; traffic; dust; exposure; TRAP.

Nitro-polycyclic aromatic hydrocarbons - gas-particle partitioning, mass size distribution, and formation along transport in marine and continental background air

NASA Astrophysics Data System (ADS)

Lammel, Gerhard; Mulder, Marie D.; Shahpoury, Pourya; Kukučka, Petr; Lišková, Hana; Přibylová, Petra; Prokeš, Roman; Wotawa, Gerhard

2017-05-01

Nitro-polycyclic aromatic hydrocarbons (NPAH) are ubiquitous in polluted air but little is known about their abundance in background air. NPAHs were studied at one marine and one continental background site, i.e. a coastal site in the southern Aegean Sea (summer 2012) and a site in the central Great Hungarian Plain (summer 2013), together with the parent compounds, PAHs. A Lagrangian particle dispersion model was used to track air mass history. Based on Lagrangian particle statistics, the urban influence on samples was quantified for the first time as a fractional dose to which the collected volume of air had been exposed. At the remote marine site, the 3-4-ring NPAH (sum of 11 targeted species) concentration was 23.7 pg m-3 while the concentration of 4-ring PAHs (6 species) was 426 pg m-3. The most abundant NPAHs were 2-nitrofluoranthene (2NFLT) and 3-nitrophenanthrene. Urban fractional doses in the range of < 0.002-5.4 % were calculated. At the continental site, the Σ11 3-4-ring NPAH and Σ6 4-ring PAH were 58 and 663 pg m-3, respectively, with 9-nitroanthracene and 2NFLT being the most concentrated amongst the targeted NPAHs. The NPAH levels observed in the marine background air are the lowest ever reported and remarkably lower, by more than 1 order of magnitude, than 1 decade before. Day-night variation of NPAHs at the continental site reflected shorter lifetime during the day, possibly because of photolysis of some NPAHs. The yields of formation of 2NFLT and 2-nitropyrene (2NPYR) in marine air seem to be close to the yields for OH-initiated photochemistry observed in laboratory experiments under high NOx conditions. Good agreement is found for the prediction of NPAH gas-particle partitioning using a multi-phase poly-parameter linear free-energy relationship. Sorption to soot is found to be less significant for gas-particle partitioning of NPAHs than for PAHs. The NPAH levels determined in the south-eastern outflow of Europe confirm intercontinental transport

Ice-atmosphere interactions in the Canadian High Arctic: Implications for the thermo-mechanical evolution of terrestrial ice masses

NASA Astrophysics Data System (ADS)

Wohlleben, Trudy M. H.

Canadian High Arctic terrestrial ice masses and the polar atmosphere evolve codependently, and interactions between the two systems can lead to feedbacks, positive and negative. The two primary positive cryosphere-atmosphere feedbacks are: (1) The snow/ice-albedo feedback (where area changes in snow and/or ice cause changes in surface albedo and surface air temperatures, leading to further area changes in snow/ice); and (2) The elevation - mass balance feedback (where thickness changes in terrestrial ice masses cause changes to atmospheric circulation and precipitation patterns, leading to further ice thickness changes). In this thesis, numerical experiments are performed to: (1) quantify the magnitudes of the two feedbacks for chosen Canadian High Arctic terrestrial ice masses; and (2) to examine the direct and indirect consequences of surface air temperature changes upon englacial temperatures with implications for ice flow, mass flux divergence, and topographic evolution. Model results show that: (a) for John Evans Glacier, Ellesmere Island, the magnitude of the terrestrial snow/ice-albedo feedback can locally exceed that of sea ice on less than decadal timescales, with implications for glacier response times to climate perturbations; (b) although historical air temperature changes might be the direct cause of measured englacial temperature anomalies in various glacier and ice cap accumulation zones, they can also be the indirect cause of their enhanced diffusive loss; (c) while the direct result of past air temperature changes has been to cool the interior of John Evans Glacier, and its bed, the indirect result has been to create and maintain warm (pressure melting point) basal temperatures in the ablation zone; and (d) for Devon Ice Cap, observed mass gains in the northwest sector of the ice cap would be smaller without orographic precipitation and the mass balance---elevation feedback, supporting the hypothesis that this feedback is playing a role in the

Field Observations of Coastal Air-Sea Interaction

NASA Astrophysics Data System (ADS)

Ortiz-Suslow, D. G.; Haus, B. K.; Williams, N. J.; Graber, H. C.

2016-12-01

In the nearshore zone wind, waves, and currents generated from different forcing mechanisms converge in shallow water. This can profoundly affect the physical nature of the ocean surface, which can significantly modulate the exchange of momentum, heat, and mass across the air-sea interface. For decades, the focus of air-sea interaction research has been on the open ocean while the shallow water regime has been relatively under-explored. This bears implications for efforts to understand and model various coastal processes, such as mixing, surface transport, and air-sea gas flux. The results from a recent study conducted at the New River Inlet in North Carolina showed that directly measured air-sea flux parameters, such as the atmospheric drag coefficient, are strong functions of space as well as the ambient conditions (i.e. wind speed and direction). The drag is typically used to parameterize the wind stress magnitude. It is generally assumed that the wind direction is the direction of the atmospheric forcing (i.e. wind stress), however significant wind stress steering off of the azimuthal wind direction was observed and was found to be related to the horizontal surface current shear. The authors have just returned from a field campaign carried out within Monterey Bay in California. Surface observations made from two research vessels were complimented by an array of beach and inland flux stations, high-resolution wind forecasts, and satellite image acquisitions. This is a rich data set and several case studies will be analyzed to highlight the importance of various processes for understanding the air-sea fluxes. Preliminary findings show that interactions between the local wind-sea and the shoaling, incident swell can have a profound effect on the wind stress magnitude. The Monterey Bay coastline contains a variety of topographical features and the importance of land-air-sea interactions will also be investigated.

Thermal conditions and perceived air quality in an air-conditioned auditorium

NASA Astrophysics Data System (ADS)

Polednik, Bernard; Guz, Łukasz; Skwarczyński, Mariusz; Dudzińska, Marzenna R.

2016-07-01

The study reports measurements of indoor air temperature (T) and relative humidity (RH), perceived air quality (PAQ) and CO2, fine aerosol particle number (PN) and mass (PM1) concentrations in an air conditioned auditorium. The measurements of these air physical parameters have been carried out in the unoccupied auditorium with the air conditioning system switched off (AC off mode) and in the unoccupied and occupied auditorium with the air conditioning system switched off during the night and switched on during the day (AC on/off mode). The average indoor air thermal parameters, CO2 concentration and the PAQ value (in decipols) were elevated, while average PM1 concentration was lower in the AC on/off mode. A statistically significant (p < 0.001) positive correlation has been observed between T and PAQ values and CO2 concentrations (r = 0.66 and r = 0.59, respectively) in that AC mode. A significant negative correlation has been observed between T and PN and PM1 concentrations (r = -0.38 and r = -0.49, respectively). In the AC off mode the above relations between T and the particle concentrations were not that unequivocal. These findings may be of importance as they indicate that in certain AC operation modes the indoor air quality deteriorates along with the variation of the indoor air microclimate and room occupation. This, in turn, may adversely affect the comfort and productivity of the users of air conditioned premises.

Aerosol optical extinction during the Front Range Air Pollution and Photochemistry Éxperiment (FRAPPÉ) 2014 summertime field campaign, Colorado, USA

NASA Astrophysics Data System (ADS)

Dingle, Justin H.; Vu, Kennedy; Bahreini, Roya; Apel, Eric C.; Campos, Teresa L.; Flocke, Frank; Fried, Alan; Herndon, Scott; Hills, Alan J.; Hornbrook, Rebecca S.; Huey, Greg; Kaser, Lisa; Montzka, Denise D.; Nowak, John B.; Reeves, Mike; Richter, Dirk; Roscioli, Joseph R.; Shertz, Stephen; Stell, Meghan; Tanner, David; Tyndall, Geoff; Walega, James; Weibring, Petter; Weinheimer, Andrew

2016-09-01

Summertime aerosol optical extinction (βext) was measured in the Colorado Front Range and Denver metropolitan area as part of the Front Range Air Pollution and Photochemistry Éxperiment (FRAPPÉ) campaign during July-August 2014. An Aerodyne cavity attenuated phase shift particle light extinction monitor (CAPS-PMex) was deployed to measure βext (at average relative humidity of 20 ± 7 %) of submicron aerosols at λ = 632 nm at 1 Hz. Data from a suite of gas-phase instrumentation were used to interpret βext behavior in various categories of air masses and sources. Extinction enhancement ratios relative to CO (Δβext / ΔCO) were higher in aged urban air masses compared to fresh air masses by ˜ 50 %. The resulting increase in Δβext / ΔCO for highly aged air masses was accompanied by formation of secondary organic aerosols (SOAs). In addition, the impacts of aerosol composition on βext in air masses under the influence of urban, natural oil and gas operations (O&G), and agriculture and livestock operations were evaluated. Estimated non-refractory mass extinction efficiency (MEE) values for different air mass types ranged from 1.51 to 2.27 m2 g-1, with the minimum and maximum values observed in urban and agriculture-influenced air masses, respectively. The mass distribution for organic, nitrate, and sulfate aerosols presented distinct profiles in different air mass types. During 11-12 August, regional influence of a biomass burning event was observed, increasing the background βext and estimated MEE values in the Front Range.

Sound transmission through finite lightweight multilayered structures with thin air layers.

PubMed

Dijckmans, A; Vermeir, G; Lauriks, W

2010-12-01

The sound transmission loss (STL) of finite lightweight multilayered structures with thin air layers is studied in this paper. Two types of models are used to describe the vibro-acoustic behavior of these structures. Standard transfer matrix method assumes infinite layers and represents the plane wave propagation in the layers. A wave based model describes the direct sound transmission through a rectangular structure placed between two reverberant rooms. Full vibro-acoustic coupling between rooms, plates, and air cavities is taken into account. Comparison with double glazing measurements shows that this effect of vibro-acoustic coupling is important in lightweight double walls. For infinite structures, structural damping has no significant influence on STL below the coincidence frequency. In this frequency region, the non-resonant transmission or so-called mass-law behavior dominates sound transmission. Modal simulations suggest a large influence of structural damping on STL. This is confirmed by experiments with double fiberboard partitions and sandwich structures. The results show that for thin air layers, the damping induced by friction and viscous effects at the air gap surfaces can largely influence and improve the sound transmission characteristics.

Associations between Prenatal traffic-related air pollution exposure and birth weight: Modification by sex and maternal pre-pregnancy body mass index

PubMed Central

Coull, Brent A.; Just, Allan C.; Maxwell, Sarah L.; Schwartz, Joel; Gryparis, Alexandros; Kloog, Itai; Wright, Rosalind J.; Wright, Robert O.

2015-01-01

Background Prenatal traffic-related air pollution exposure is linked to adverse birth outcomes. However, modifying effects of maternal body mass index (BMI) and infant sex remain virtually unexplored. Objectives We examined whether associations between prenatal air pollution and birth weight differed by sex and maternal BMI in 670 urban ethnically mixed mother-child pairs. Methods Black carbon (BC) levels were estimated using a validated spatio-temporal land-use regression (LUR) model; fine particulate matter (PM2.5) was estimated using a hybrid LUR model incorporating satellite-derived Aerosol Optical Depth measures. Using stratified multivariable-adjusted regression analyses, we examined whether associations between prenatal air pollution and calculated birth weight for gestational age (BWGA) z-scores varied by sex and maternal pre-pregnancy BMI. Results Median birth weight was 3.3±0.6 kg; 33% of mothers were obese (BMI ≥30 kg/m3). In stratified analyses, the association between higher PM2.5 and lower birth weight was significant in males of obese mothers (−0.42 unit of BWGA z-score change per IQR increase in PM2.5, 95%CI: −0.79 to −0.06) ( PM2.5 × sex × obesity Pinteraction=0.02). Results were similar for BC models (Pinteraction=0.002). Conclusions Associations of prenatal exposure to traffic-related air pollution and reduced birth weight were most evident in males born to obese mothers. PMID:25601728

Tracking hazardous air pollutants from a refinery fire by applying on-line and off-line air monitoring and back trajectory modeling.

PubMed

Shie, Ruei-Hao; Chan, Chang-Chuan

2013-10-15

The air monitors used by most regulatory authorities are designed to track the daily emissions of conventional pollutants and are not well suited for measuring hazardous air pollutants that are released from accidents such as refinery fires. By applying a wide variety of air-monitoring systems, including on-line Fourier transform infrared spectroscopy, gas chromatography with a flame ionization detector, and off-line gas chromatography-mass spectrometry for measuring hazardous air pollutants during and after a fire at a petrochemical complex in central Taiwan on May 12, 2011, we were able to detect significantly higher levels of combustion-related gaseous and particulate pollutants, refinery-related hydrocarbons, and chlorinated hydrocarbons, such as 1,2-dichloroethane, vinyl chloride monomer, and dichloromethane, inside the complex and 10 km downwind from the fire than those measured during the normal operation periods. Both back trajectories and dispersion models further confirmed that high levels of hazardous air pollutants in the neighboring communities were carried by air mass flown from the 22 plants that were shut down by the fire. This study demonstrates that hazardous air pollutants from industrial accidents can successfully be identified and traced back to their emission sources by applying a timely and comprehensive air-monitoring campaign and back trajectory air flow models. Copyright © 2013 The Authors. Published by Elsevier B.V. All rights reserved.

Air and Surface Sampling Method for Assessing Exposures to Quaternary Ammonium Compounds Using Liquid Chromatography Tandem Mass Spectrometry.

PubMed

LeBouf, Ryan F; Virji, Mohammed Abbas; Ranpara, Anand; Stefaniak, Aleksandr B

2017-07-01

This method was designed for sampling select quaternary ammonium (quat) compounds in air or on surfaces followed by analysis using ultraperformance liquid chromatography tandem mass spectrometry. Target quats were benzethonium chloride, didecyldimethylammonium bromide, benzyldimethyldodecylammonium chloride, benzyldimethyltetradecylammonium chloride, and benzyldimethylhexadecylammonium chloride. For air sampling, polytetrafluoroethylene (PTFE) filters are recommended for 15-min to 24-hour sampling. For surface sampling, Pro-wipe® 880 (PW) media was chosen. Samples were extracted in 60:40 acetonitrile:0.1% formic acid for 1 hour on an orbital shaker. Method detection limits range from 0.3 to 2 ng/ml depending on media and analyte. Matrix effects of media are minimized through the use of multiple reaction monitoring versus selected ion recording. Upper confidence limits on accuracy meet the National Institute for Occupational Safety and Health 25% criterion for PTFE and PW media for all analytes. Using PTFE and PW analyzed with multiple reaction monitoring, the method quantifies levels among the different quats compounds with high precision (<10% relative standard deviation) and low bias (<11%). The method is sensitive enough with very low method detection limits to capture quats on air sampling filters with only a 15-min sample duration with a maximum assessed storage time of 103 days before sample extraction. This method will support future exposure assessment and quantitative epidemiologic studies to explore exposure-response relationships and establish levels of quats exposures associated with adverse health effects. © The Author 2017. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.

Assessment of air pollution of settlement areas in Ulaanbaatar city, Mongolia

NASA Astrophysics Data System (ADS)

Ch, Sonomdagva; Ch, Byambatseren; Batdelger, B.

2017-05-01

The purpose of this study is to analyses mass concentration varied by its measurement of air pollution in Ulaanbaatar city, Mongolia. Ulaanbaatar city will have been increasing air pollution due to rapidly expanding vehicular population, growing industrial sector in last 10 years ago. In addition, people use to heat the carbon from 10 month in every year. This becomes a base cause of air pollution in Ulaanbaatar. We studied a change of mass concentration an air pollution elements in Ulaanbaatar, Mongolia. To research work, we used information that based on data of my measurements of air pollution and Metropolitan air quality agency until 2006 to 2016. This research important result is air pollution levels are limited to the areas around Ulaanbaatar areas are the most polluted in the center of city are the least polluted areas whereas Tolgoit, Sapporo, 1st Khoroolol, Amgalan, Shar Khad are moderately polluted and the areas around Baruun 4 zam, Factory, Zaisan, Nisekh are normally polluted. The results of pollution are illustrated four zones. By dividing the polluted areas into such zones, we are trying to make it easier to take preventive measures against the pollution itself and protective measures for safeguarding the health of mass population.

Ultrahigh-Capacity Lithium-Oxygen Batteries Enabled by Dry-Pressed Holey Graphene Air Cathodes.

PubMed

Lin, Yi; Moitoso, Brandon; Martinez-Martinez, Chalynette; Walsh, Evan D; Lacey, Steven D; Kim, Jae-Woo; Dai, Liming; Hu, Liangbing; Connell, John W

2017-05-10

Lithium-oxygen (Li-O 2 ) batteries have the highest theoretical energy density of all the Li-based energy storage systems, but many challenges prevent them from practical use. A major obstacle is the sluggish performance of the air cathode, where both oxygen reduction (discharge) and oxygen evolution (charge) reactions occur. Recently, there have been significant advances in the development of graphene-based air cathode materials with a large surface area and catalytically active for both oxygen reduction and evolution reactions, especially with additional catalysts or dopants. However, most studies reported so far have examined air cathodes with a limited areal mass loading rarely exceeding 1 mg/cm 2 . Despite the high gravimetric capacity values achieved, the actual (areal) capacities of those batteries were far from sufficient for practical applications. Here, we present the fabrication, performance, and mechanistic investigations of high-mass-loading (up to 10 mg/cm 2 ) graphene-based air electrodes for high-performance Li-O 2 batteries. Such air electrodes could be easily prepared within minutes under solvent-free and binder-free conditions by compression-molding holey graphene materials because of their unique dry compressibility associated with in-plane holes on the graphene sheet. Li-O 2 batteries with high air cathode mass loadings thus prepared exhibited excellent gravimetric capacity as well as ultrahigh areal capacity (as high as ∼40 mAh/cm 2 ). The batteries were also cycled at a high curtailing areal capacity (2 mAh/cm 2 ) and showed a better cycling stability for ultrathick cathodes than their thinner counterparts. Detailed post-mortem analyses of the electrodes clearly revealed the battery failure mechanisms under both primary and secondary modes, arising from the oxygen diffusion blockage and the catalytic site deactivation, respectively. These results strongly suggest that the dry-pressed holey graphene electrodes are a highly viable

CHEMICAL MASS BALANCE MODEL: EPA-CMB8.2

EPA Science Inventory

The Chemical Mass Balance (CMB) method has been a popular approach for receptor modeling of ambient air pollutants for over two decades. For the past few years the U.S. Environmental Protection Agency's Office of Research and Development (ORD) and Office of Air Quality Plannin...

Evaluation of indoor air composition time variation in air-tight occupied spaces during night periods

NASA Astrophysics Data System (ADS)

Markov, Detelin

2012-11-01

This paper presents an easy-to-understand procedure for prediction of indoor air composition time variation in air-tight occupied spaces during the night periods. The mathematical model is based on the assumptions for homogeneity and perfect mixing of the indoor air, the ideal gas model for non-reacting gas mixtures, mass conservation equations for the entire system and for each species, a model for prediction of basal metabolic rate of humans as well as a model for prediction of O2 consumption rate and both CO2 and H2O generation rates by breathing. Time variation of indoor air composition is predicted at constant indoor air temperature for three scenarios based on the analytical solution of the mathematical model. The results achieved reveal both the most probable scenario for indoor air time variation in air-tight occupied spaces as well as the cause for morning tiredness after having a sleep in a modern energy efficient space.

Epidemiologic evidence for asthma and exposure to air toxics: linkages between occupational, indoor, and community air pollution research.

PubMed Central

Delfino, Ralph J

2002-01-01

Outdoor ambient air pollutant exposures in communities are relevant to the acute exacerbation and possibly the onset of asthma. However, the complexity of pollutant mixtures and etiologic heterogeneity of asthma has made it difficult to identify causal components in those mixtures. Occupational exposures associated with asthma may yield clues to causal components in ambient air pollution because such exposures are often identifiable as single-chemical agents (e.g., metal compounds). However, translating occupational to community exposure-response relationships is limited. Of the air toxics found to cause occupational asthma, only formaldehyde has been frequently investigated in epidemiologic studies of allergic respiratory responses to indoor air, where general consistency can be shown despite lower ambient exposures. The specific volatile organic compounds (VOCs) identified in association with occupational asthma are generally not the same as those in studies showing respiratory effects of VOC mixtures on nonoccupational adult and pediatric asthma. In addition, experimental evidence indicates that airborne polycyclic aromatic hydrocarbon (PAH) exposures linked to diesel exhaust particles (DEPs) have proinflammatory effects on airways, but there is insufficient supporting evidence from the occupational literature of effects of DEPs on asthma or lung function. In contrast, nonoccupational epidemiologic studies have frequently shown associations between allergic responses or asthma with exposures to ambient air pollutant mixtures with PAH components, including black smoke, high home or school traffic density (particularly truck traffic), and environmental tobacco smoke. Other particle-phase and gaseous co-pollutants are likely causal in these associations as well. Epidemiologic research on the relationship of both asthma onset and exacerbation to air pollution is needed to disentangle effects of air toxics from monitored criteria air pollutants such as particle mass

Influence of Earth-directed Coronal Mass Ejections on the Sun’s Shadow Observed by the Tibet-III Air Shower Array

NASA Astrophysics Data System (ADS)

Amenomori, M.; Bi, X. J.; Chen, D.; Chen, T. L.; Chen, W. Y.; Cui, S. W.; Danzengluobu; Ding, L. K.; Feng, C. F.; Feng, Zhaoyang; Feng, Z. Y.; Gou, Q. B.; Guo, Y. Q.; He, H. H.; He, Z. T.; Hibino, K.; Hotta, N.; Hu, Haibing; Hu, H. B.; Huang, J.; Jia, H. Y.; Jiang, L.; Kajino, F.; Kasahara, K.; Katayose, Y.; Kato, C.; Kawata, K.; Kozai, M.; Labaciren; Le, G. M.; Li, A. F.; Li, H. J.; Li, W. J.; Liu, C.; Liu, J. S.; Liu, M. Y.; Lu, H.; Meng, X. R.; Miyazaki, T.; Munakata, K.; Nakajima, T.; Nakamura, Y.; Nanjo, H.; Nishizawa, M.; Niwa, T.; Ohnishi, M.; Ohta, I.; Ozawa, S.; Qian, X. L.; Qu, X. B.; Saito, T.; Saito, T. Y.; Sakata, M.; Sako, T. K.; Shao, J.; Shibata, M.; Shiomi, A.; Shirai, T.; Sugimoto, H.; Takita, M.; Tan, Y. H.; Tateyama, N.; Torii, S.; Tsuchiya, H.; Udo, S.; Wang, H.; Wu, H. R.; Xue, L.; Yamamoto, Y.; Yamauchi, K.; Yang, Z.; Yuan, A. F.; Zhai, L. M.; Zhang, H. M.; Zhang, J. L.; Zhang, X. Y.; Zhang, Y.; Zhang, Yi; Zhang, Ying; Zhaxisangzhu; Zhou, X. X.; Tibet ASγ Collaboration

2018-06-01

We examine the possible influence of Earth-directed coronal mass ejections (ECMEs) on the Sun’s shadow in the 3 TeV cosmic-ray intensity observed by the Tibet-III air shower (AS) array. We confirm a clear solar-cycle variation of the intensity deficit in the Sun’s shadow during ten years between 2000 and 2009. This solar-cycle variation is overall reproduced by our Monte Carlo (MC) simulations of the Sun’s shadow based on the potential field model of the solar magnetic field averaged over each solar rotation period. We find, however, that the magnitude of the observed intensity deficit in the Sun’s shadow is significantly less than that predicted by MC simulations, particularly during the period around solar maximum when a significant number of ECMEs is recorded. The χ 2 tests of the agreement between the observations and the MC simulations show that the difference is larger during the periods when the ECMEs occur, and the difference is reduced if the periods of ECMEs are excluded from the analysis. This suggests the first experimental evidence of the ECMEs affecting the Sun’s shadow observed in the 3 TeV cosmic-ray intensity.

Development of a short path thermal desorption-gas chromatography/mass spectrometry method for the determination of polycyclic aromatic hydrocarbons in indoor air.

PubMed

Li, Yingjie; Xian, Qiming; Li, Li

2017-05-12

Polycyclic aromatic hydrocarbons (PAHs) are present in petroleum based products and are combustion by-products of organic matters. Determination of levels of PAHs in the indoor environment is important for assessing human exposure to these chemicals. A new short path thermal desorption (SPTD) gas chromatography/mass spectrometry (GC/MS) method for determining levels of PAHs in indoor air was developed. Thermal desorption (TD) tubes packed with glass beads, Carbopack C, and Carbopack B in sequence, were used for sample collection. Indoor air was sampled using a small portable pump over 7 days at 100ml/min. Target PAHs were thermally released and introduced into the GC/MS for analysis through the SPTD unit. During tube desorption, PAHs were cold trapped (-20°C) at the front end of the GC column. Thermal desorption efficiencies were 100% for PAHs with 2 and 3 rings, and 99-97% for PAHs with 4-6 rings. Relative standard deviation (RSD) values among replicate samples spiked at three different levels were around 10-20%. The detection limit of this method was at or below 0.1μg/m 3 except for naphthalene (0.61μg/m 3 ), fluorene (0.28μg/m 3 ) and phenanthrene (0.35μg/m 3 ). This method was applied to measure PAHs in indoor air in nine residential homes. The levels of PAHs in indoor air found in these nine homes are similar to indoor air values reported by others. Copyright © 2017 Elsevier B.V. All rights reserved.

Indoor air quality in university classrooms and relative environment in terms of mass concentrations of particulate matter.

PubMed

Gaidajis, George; Angelakoglou, Komninos

2009-10-01

The mass concentrations of coarse (PM10) and fine (PM2.5) particulate matter were measured in different classrooms and relevant indoors areas of Democritus University, School of Engineering, Xanthi, with portable aerosol monitoring equipment. Two sampling campaigns were conducted in different seasons. The results indicated that the average concentrations in classrooms ranged from 32-188 microg/m3 and 25-151 microg/m3 for PM10 and PM2.5, respectively. Concentration levels above 300 microg/m3 were usually recorded, while the PM2.5/PM10 ratio was about 0.8. As expected, PM10 and PM2.5 average concentrations were significantly higher in the open-access meeting place of common use, indicating the significance of student trespassing and occasional smoking in the deterioration of indoors air quality.

AIR COOLED NEUTRONIC REACTOR

DOEpatents

Fermi, E.; Szilard, L.

1958-05-27

A nuclear reactor of the air-cooled, graphite moderated type is described. The active core consists of a cubicle mass of graphite, approximately 25 feet in each dimension, having horizontal channels of square cross section extending between two of the opposite faces, a plurality of cylindrical uranium slugs disposed in end to end abutting relationship within said channels providing a space in the channels through which air may be circulated, and a cadmium control rod extending within a channel provided in the moderator. Suitable shielding is provlded around the core, as are also provided a fuel element loading and discharge means, and a means to circulate air through the coolant channels through the fuel charels to cool the reactor.

Mass Spectrometer Containing Multiple Fixed Collectors

NASA Technical Reports Server (NTRS)

Moskala, Robert; Celo, Alan; Voss, Guenter; Shaffer, Tom

2008-01-01

A miniature mass spectrometer that incorporates features not typically found in prior mass spectrometers is undergoing development. This mass spectrometer is designed to simultaneously measure the relative concentrations of five gases (H2, He, N2, O2, and Ar) in air, over the relative-concentration range from 10(exp -6) to 1, during a sampling time as short as 1 second. It is intended to serve as a prototype of a product line of easy-to-use, portable, lightweight, highspeed, relatively inexpensive instruments for measuring concentrations of multiple chemical species in such diverse applications as detecting explosive or toxic chemicals in air, monitoring and controlling industrial processes, measuring concentrations of deliberately introduced isotopes in medical and biological investigations, and general environmental monitoring. The heart of this mass spectrometer is an integral combination of a circular cycloidal mass analyzer, multiple fixed ion collectors, and two mass-selective ion sources. By circular cycloidal mass analyzer is meant an analyzer that includes (1) two concentric circular cylindrical electrodes for applying a radial electric field and (2) a magnet arranged to impose a magnetic flux aligned predominantly along the cylindrical axis, so that ions, once accelerated into the annulus between the electrodes, move along circular cycloidal trajectories. As in other mass analyzers, trajectory of each ion is determined by its mass-to-charge ratio, and so ions of different species can be collected simultaneously by collectors (Faraday cups) at different locations intersected by the corresponding trajectories (see figure). Unlike in other mass analyzers, the installation of additional collectors to detect additional species does not necessitate increasing the overall size of the analyzer assembly.

Particulate Matter Mass Concentration in Residential Prefabricated Buildings Related to Temperature and Moisture

NASA Astrophysics Data System (ADS)

Kraus, Michal; Juhásová Šenitková, Ingrid

2017-10-01

Building environmental audit and the assessment of indoor air quality (IAQ) in typical residential buildings is necessary process to ensure users’ health and well-being. The paper deals with the concentrations on indoor dust particles (PM10) in the context of hygrothermal microclimate in indoor environment. The indoor temperature, relative humidity and air movement are basic significant factors determining the PM10 concentration [μg/m3]. The experimental measurements in this contribution represent the impact of indoor physical parameters on the concentration of particulate matter mass concentration. The occurrence of dust particles is typical for the almost two-thirds of interiors of the buildings. Other parameters indoor environment, such as air change rate, volume of the room, roughness and porosity of the building material surfaces, static electricity, light ions and others, were set constant and they are not taken into account in this study. The mass concentration of PM10 is measured during summer season in apartment of residential prefabricated building. The values of global temperature [°C] and relative humidity of indoor air [%] are also monitored. The quantity of particulate mass matter is determined gravimetrically by weighing according to CSN EN 12 341 (2014). The obtained results show that the temperature difference of the internal environment does not have a significant effect on the concentration PM10. Vice versa, the difference of relative humidity exhibits a difference of the concentration of dust particles. Higher levels of indoor particulates are observed for low values of relative humidity. The decreasing of relative air humidity about 10% caused 10µg/m3 of PM10 concentration increasing. The hygienic limit value of PM10 concentration is not exceeded at any point of experimental measurement.

Clean Air Markets - Part 75 Emissions Monitoring Policy Manual

EPA Pesticide Factsheets

Learn about monitoring mass sulfur dioxide and mass carbon dioxide emissions, nitrogen oxide emission rate, and heat input by units affected by the Acid Rain Program and the Clean Air Interstate Rule.

Heat and mass transfer in a dissociated laminar boundary layer of air with consideration of the finite rate of chemical reaction

NASA Technical Reports Server (NTRS)

Oyegbesan, A. O.; Algermissen, J.

1986-01-01

A numerical investigation of heat and mass transfer in a dissociated laminar boundary layer of air on an isothermal flat plate is carried out for different degrees of cooling of the wall. A finite-difference chemical model is used to study elementary reactions involving NO2 and N2O. The analysis is based on equations of continuity, momentum, energy, conservation and state for the two-dimensional viscous flow of a reacting multicomponent mixtures. Attention is given to the effects of both catalyticity and noncatalyticity of the wall.

Effects of elastic seats on seated body apparent mass responses to vertical whole body vibration.

PubMed

Dewangan, K N; Rakheja, S; Marcotte, Pierre; Shahmir, A

2015-01-01

Apparent mass (AM) responses of the body seated with and without a back support on three different elastic seats (flat and contoured polyurethane foam (PUF) and air cushion) and a rigid seat were measured under three levels of vertical vibration (overall rms acceleration: 0.25, 0.50 and 0.75 m/s(2)) in the 0.5 to 20 Hz range. A pressure-sensing system was used to capture biodynamic force at the occupant-seat interface. The results revealed strong effects of visco-elastic and vibration transmissibility characteristics of seats on AM. The response magnitudes with the relatively stiff air seat were generally higher than those with the PUF seats except at low frequencies. The peak magnitude decreased when sitting condition was changed from no back support to a vertical support; the reduction however was more pronounced with the air seat. Further, a relatively higher frequency shift was evident with soft seat compared with stiff elastic seat with increasing excitation. The effects of visco-elastic properties of the body-seat interface on the apparent mass responses of the seated body are measured under vertical vibration. The results show considerable effects of the coupling stiffness on the seated body apparent mass, apart from those of excitation magnitude and back support.

Interaction of clothing and body mass index affects validity of air-displacement plethysmography in adults.

PubMed

Shafer, Kimberly J; Siders, William A; Johnson, LuAnn K; Lukaski, Henry C

2008-02-01

We determined the effect of clothing type on the validity of air-displacement plethysmography (ADP) to estimate percentage of body fat (%BF) and ascertain if these effects differ by body mass index (BMI). The %BF by dual x-ray absorptiometry (DXA) and %BF, density, and body volume by ADP were assessed in 132 healthy adults classified by normal (N; 18.5-24.9 kg/m2), overweight (OW; 25-29.9 kg/m2), and obese (OB; 30-39.9 kg/m2) BMIs. Compared with DXA, ADP underestimated (P < 0.0001) %BF from scrubs (SC) and t-shirt/shorts (TS) in N (11.4%; 8.6%) and OW (6.8%; 4.9%) BMI groups, respectively. ADP compared with DXA overestimated (P < 0.0006) %BF in the OW group (1.2%), but underestimated (P < 0.0001) it in the N group (2.4%). ADP also overestimated (P < 0.006) %BF in the OB group wearing spandex (SP; 4.8%), but not in those wearing SC (0.7%; P = 0.10) and TS (0.5%; P = 0.22) versus DXA. All three clothing types showed significant error in estimating %BF with ADP compared with DXA in N and OW BMI. Use of spandex provided the least error and is the preferred attire to obtain valid body composition results when testing N and OW subjects. However, SP provided the greatest error in the OB group. Error in ADP %BF in OB was minimal in SC and TS and similar to the within-subject variability in %BF estimates with ADP. Thus, TS and SC are acceptable alternatives to SP in adults with excess body weight.

High-energy metal air batteries

DOEpatents

Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

2014-07-01

Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

High-energy metal air batteries

DOEpatents

Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

2013-07-09

Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

Molecular composition of boreal forest aerosol from Hyytiälä, Finland, using ultrahigh resolution mass spectrometry.

PubMed

Kourtchev, Ivan; Fuller, Stephen; Aalto, Juho; Ruuskanen, Taina M; McLeod, Matthew W; Maenhaut, Willy; Jones, Rod; Kulmala, Markku; Kalberer, Markus

2013-05-07

Organic compounds are important constituents of fine particulate matter (PM) in the troposphere. In this study, we applied direct infusion nanoelectrospray (nanoESI) ultrahigh resolution mass spectrometry (UHR-MS) and liquid chromatography LC/ESI-UHR-MS for the analysis of the organic fraction of PM1 aerosol samples collected over a two week period at a boreal forest site (Hyytiälä), southern Finland. Elemental formulas (460-730 in total) were identified with nanoESI-UHR-MS in the negative ionization mode and attributed to organic compounds with a molecular weight below 400. Kendrick Mass Defect and Van Krevelen approaches were used to identify compound classes and mass distributions of the detected species. The molecular composition of the aerosols strongly varied between samples with different air mass histories. An increased number of nitrogen, sulfur, and highly oxygenated organic compounds was observed during the days associated with continental air masses. However, the samples with Atlantic air mass history were marked by a presence of homologous series of unsaturated and saturated C12-C20 fatty acids suggesting their marine origin. To our knowledge, we show for the first time that the highly detailed chemical composition obtained from UHR-MS analyses can be clearly linked to meteorological parameters and trace gases concentrations that are relevant to atmospheric oxidation processes. The additional LC/ESI-UHR-MS analysis revealed 29 species, which were mainly attributed to oxidation products of biogenic volatile compounds BVOCs (i.e., α,β-pinene, Δ3-carene, limonene, and isoprene) supporting the results from the direct infusion analysis.

What's All the Talc About? Air Entrainment in Dilute Pyroclastic Density Currents

NASA Astrophysics Data System (ADS)

Marshall, B. J.; Andrews, B. J.; Fauria, K.

2015-12-01

A quantitative understanding of air entrainment is critical to predicting the behaviors of dilute Pyroclastic Density Currents (PDCs), including runout distance, liftoff, and mass fractionation into co-PDC plumes. We performed experiments in an 8.5x6x2.6 meter tank using 20 micron talc powder over a range of conditions to describe air entrainment as a function of temperature, duration and mass flux. The experiments are reproducible and are scaled with respect to the densimetric and thermal Richardson numbers (Ri and RiT), Froude number, thermal to kinetic energy density ratio (TEb/KE), Stokes number, and Settling number, such that they are dynamically similar to natural dilute PDCs. Experiments are illuminated with a swept laser sheet and imaged at 1000 Hz to create 3D reconstructions of the currents, with ~1-2 cm resolution, at up to 1.5 Hz. An array of 30 high-frequency thermocouples record the precise temperature in the currents at 3 Hz. Bulk entrainment rates are calculated based on measured current volumes, surface areas, temperatures and velocities. Entrainment rates vary from ~0-0.9 and do not show simple variation with TEb/KE, Ri, or RiT. Entrainment does, however, increase with decreasing eruption duration and increasing mass flux. Our results suggest that current heads entrain air more efficiently than current bodies (>0.5 compared to ~0.1). Because shorter duration currents have proportionally larger heads, their bulk entrainment rates are controlled by those heads, whereas longer duration currents are dominated by their bodies. Our experiments demonstrate that air entrainment, which exerts a fundamental control on PDC runout and liftoff, varies spatially and temporally within PDCs.

Cooling Characteristics of an Experimental Tail-pipe Burner with an Annular Cooling-air Passage

NASA Technical Reports Server (NTRS)

Kaufman, Harold R; Koffel, William K

1952-01-01

The effects of tail-pipe fuel-air ratio (exhaust-gas temperatures from approximately 3060 degrees to 3825 degrees R), radial distributiion of tail-pipe fuel flow, and mass flow of combustion gas and the inside wall were determined for an experimental tail-pipe burner cooled by air flowing through and insulated cooling-air to combustion gas mass flow from 0.066 to 0.192 were also determined.

Telephone equipment room, showing channel terminal bank with vacuum tubes. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Telephone equipment room, showing channel terminal bank with vacuum tubes. View to east - March Air Force Base, Strategic Air Command, Combat Operations Center, 5220 Riverside Drive, Moreno Valley, Riverside County, CA

Updated polychlorinated biphenyl mass budget for Lake Michigan

EPA Science Inventory

This study revisits and updates the Lake Michigan Mass Balance Project (LMMBP) for polychlorinated biphenyls (PCBs) that was conducted in 1994-1995. This work uses recent concentrations of PCBs in tributary and open lake water, air, and sediment to calculate an updated mass budg...

Identification of water-soluble polar organics in air and vehicular emitted particulate matter using ultrahigh resolution mass spectrometry and Capillary electrophoresis - mass spectrometry.

NASA Astrophysics Data System (ADS)

Schmitt-Kopplin, P.; Yassine, M.; Gebefugi, I.; Hertkorn, N.; Dabek-Zlotorzynska, E.

2009-04-01

The effects of aerosols on human health, atmospheric chemistry, and climate are among the central topics in current environmental health research. Detailed and accurate measurements of the chemical composition of air particulate matter (PM) represent a challenging analytical task. Minute sample amounts are usually composed of several main constituents and hundreds of minor and trace constituents. Moreover, the composition of individual particles can be fairly uniform or very different (internally or externally mixed aerosols), depending on their origin and atmospheric aging processes (coagulation, condensation / evaporation, chemical reaction). The aim of the presentation was the characterization of the organic matter (OM) fraction of environmental aerosols which is not accessible by GC-methods, either because of their high molecular weight, their polarity or due to thermal instability. We also describe the main chemical characteristics of complexe oligomeric organic fraction extracted from different aerosols collected in urban and rural area in Germany and Canada. Mass spectrometry (MS) became an essential tool used by many prominent leaders of the biological research community and the importance of MS to the future of biological research is now clearly evident as in the fields of Proteomics and Metabolomics. Especially Fourier Transform Ion Cyclotron Mass Spectrometry (ICR-FT/MS) is an ultrahigh resolution MS that allows new approach in the analysis of complex mixtures. The mass resolution (< 200 ppb) allowed assigning the elemental composition (C, H, O, N, S…) to each of the obtained mass peaks and thus already a description of the mixture in terms of molecular composition. This possibility is used by the authors together with a high resolution separation method of charged compounds: capillary electrophoresis. A CE-ESI-MS method using an ammonium acetate based background electrolyte (pH 4.7) was developed for the determination of isomeric benzoic acids in

Development of analysis of volatile polyfluorinated alkyl substances in indoor air using thermal desorption-gas chromatography-mass spectrometry.

PubMed

Wu, Yaoxing; Chang, Victor W-C

2012-05-18

The study attempts to utilize thermal desorption (TD) coupled with gas chromatography-mass spectrometry (GC-MS) for determination of indoor airborne volatile polyfluorinated alkyl substances (PFASs), including four fluorinated alcohols (FTOHs), two fluorooctane sulfonamides (FOSAs), and two fluorooctane sulfonamidoethanols (FOSEs). Standard stainless steel tubes of Tenax/Carbograph 1 TD were employed for low-volume sampling and exhibited minimal breakthrough of target analytes in sample collection. The method recoveries were in the range of 88-119% for FTOHs, 86-138% for FOSAs, exhibiting significant improvement compared with other existing air sampling methods. However, the widely reported high method recoveries of FOSEs were also observed (139-210%), which was probably due to the structural differences between FOSEs and internal standards. Method detection limit, repeatability, linearity, and accuracy were reported as well. The approach has been successfully applied to routine quantification of targeted PFASs in indoor environment of Singapore. The significantly shorter sampling time enabled the observation of variations of concentrations of targeted PFASs within different periods of a day, with higher concentration levels at night while ventilation systems were shut off. This indicated the existence of indoor sources and the importance of building ventilation and air conditioning system. Copyright © 2012 Elsevier B.V. All rights reserved.

27 CFR 30.66 - Table 6, showing respective volumes of alcohol and water and the specific gravity in both air and...

Code of Federal Regulations, 2012 CFR

2012-04-01

... respective volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor... volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor. This... gallon of water in air by the specific gravity in air of the spirits—8.32823 by 0.88862—the product (7...

27 CFR 30.66 - Table 6, showing respective volumes of alcohol and water and the specific gravity in both air and...

Code of Federal Regulations, 2010 CFR

2010-04-01

... respective volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor... volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor. This... gallon of water in air by the specific gravity in air of the spirits—8.32823 by 0.88862—the product (7...

27 CFR 30.66 - Table 6, showing respective volumes of alcohol and water and the specific gravity in both air and...

Code of Federal Regulations, 2011 CFR

2011-04-01

... respective volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor... volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor. This... gallon of water in air by the specific gravity in air of the spirits—8.32823 by 0.88862—the product (7...

27 CFR 30.66 - Table 6, showing respective volumes of alcohol and water and the specific gravity in both air and...

Code of Federal Regulations, 2013 CFR

2013-04-01

... respective volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor... volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor. This... gallon of water in air by the specific gravity in air of the spirits—8.32823 by 0.88862—the product (7...

27 CFR 30.66 - Table 6, showing respective volumes of alcohol and water and the specific gravity in both air and...

Code of Federal Regulations, 2014 CFR

2014-04-01

... respective volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor... volumes of alcohol and water and the specific gravity in both air and vacuum of spirituous liquor. This... gallon of water in air by the specific gravity in air of the spirits—8.32823 by 0.88862—the product (7...

67. COPY OF UNDATED OBLIQUE AERIAL PHOTOGRAPH SHOWING WEAPONS STORAGE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

67. COPY OF UNDATED OBLIQUE AERIAL PHOTOGRAPH SHOWING WEAPONS STORAGE AREA, FROM MASTER PLAN OF CARIBOU AFS. PHOTOGRAPH, PROBABLY TAKEN IN THE 1960'S LOCATED AT AIR FORCE BASE CONVERSION AGENCY, LORING AIR FORCE BASE, MAINE. - Loring Air Force Base, Weapons Storage Area, Northeastern corner of base at northern end of Maine Road, Limestone, Aroostook County, ME

Sensitivity of glacier mass balance and equilibrium line altitude to climatic change on King George Island, Antarctic Peninsula.

NASA Astrophysics Data System (ADS)

Falk, Ulrike; Lopez, Damian; Silva-Busso, Adrian

2017-04-01

The South Shetland Islands are located at the northern tip of the Antarctic Peninsula which is among the fastest warming regions on Earth. Surface air temperature increases (ca. 3 K in 50 years) are concurrent with retreating glacier fronts, an increase in melt areas, ice surface lowering and rapid break-up and disintegration of ice shelves. Observed surface air temperature lapse rates show a high variability during winter months (standard deviations up to ±1.0 K/100 m), and a distinct spatial heterogeneity reflecting the impact of synoptic weather patterns especially during winter glacial mass accumulation periods. The increased mesocyclonic activity during the winter time in the study area results in intensified advection of warm, moist air with high temperatures and rain, and leads to melt conditions on the ice cap, fixating surface air temperatures to the melting point. The impact on winter accumulation results in even more negative mass balance estimates. Six years of glaciological measurements on mass balance stake transects are used with a glacier melt model to assess changes in melt water input to the coastal waters, glacier surface mass balance and the equilibrium line altitude. The average equilibrium line altitude (ELA) calculated from own glaciological observations for KGI over the time period 2010 - 2015 amounts to ELA=330±100 m. Published studies suggest rather stable condition slightly negative glacier mass balance until the mid 80's with an ELA of approx. 150 m. The calculated accumulation area ratio suggests rather dramatic changes in extension of the inland ice cap for the South Shetland Islands until an equilibrium with concurrent climate conditions is reached.

On-line analysis of ambient air aerosols using laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Carranza, J. E.; Fisher, B. T.; Yoder, G. D.; Hahn, D. W.

2001-06-01

Laser-induced breakdown spectroscopy is developed for the detection of aerosols in ambient air, including quantitative mass concentration measurements and size/composition measurements of individual aerosol particles. Data are reported for ambient air aerosols containing aluminum, calcium, magnesium and sodium for a 6-week sampling period spanning the Fourth of July holiday period. Measured mass concentrations for these four elements ranged from 1.7 parts per trillion (by mass) to 1.7 parts per billion. Ambient air concentrations of magnesium and aluminum revealed significant increases during the holiday period, which are concluded to arise from the discharge of fireworks in the lower atmosphere. Real-time conditional data analysis yielded increases in analyte spectral intensity approaching 3 orders of magnitude. Analysis of single particles yielded composition-based aerosol size distributions, with measured aerosol diameters ranging from 100 nm to 2 μm. The absolute mass detection limits for single particle analysis exceeded sub-femtogram values for calcium-containing particles, and was on the order of 2-3 femtograms for magnesium and sodium-based particles. Overall, LIBS-based analysis of ambient air aerosols is a promising technique for the challenging issues associated with the real-time collection and analysis of ambient air particulate matter data.

A High-Latitude Winter Continental Low Cloud Feedback Suppresses Arctic Air Formation in Warmer Climates

NASA Astrophysics Data System (ADS)

Cronin, T.; Tziperman, E.; Li, H.

2015-12-01

High latitude continents have warmed much more rapidly in recent decades than the rest of the globe, especially in winter, and the maintenance of warm, frost-free conditions in continental interiors in winter has been a long-standing problem of past equable climates. It has also been found that the high-latitude lapse rate feedback plays an important role in Arctic amplification of climate change in climate model simulations, but we have little understanding of why lapse rates at high latitudes change so strongly with warming. To better understand these problems, we study Arctic air formation - the process by which a high-latitude maritime air mass is advected over a continent during polar night, cooled at the surface by radiation, and transformed into a much colder continental polar air mass - and its sensitivity to climate warming. We use a single-column version of the WRF model to conduct two-week simulations of the cooling process across a wide range of initial temperature profiles and microphysics schemes, and find that a low cloud feedback suppresses Arctic air formation in warmer climates. This cloud feedback consists of an increase in low cloud amount with warming, which shields the surface from radiative cooling, and increases the continental surface air temperature by roughly two degrees for each degree increase of the initial maritime surface air temperature. The time it takes for the surface air temperature to drop below freezing increases nonlinearly to ~10 days for initial maritime surface air temperatures of 20 oC. Given that this is about the time it takes an air mass starting over the Pacific to traverse the north American continent, this suggests that optically thick stratus cloud decks could help to maintain frost-free winter continental interiors in equable climates. We find that CMIP5 climate model runs show large increases in cloud water path and surface cloud longwave forcing in warmer climates, consistent with the proposed low-cloud feedback

Numerical analysis of heat and mass transfer for water recovery in an evaporative cooling tower

NASA Astrophysics Data System (ADS)

Lee, Hyunsub; Son, Gihun

2017-11-01

Numerical analysis is performed for water recovery in an evaporative cooling tower using a condensing heat exchanger, which consists of a humid air channel and an ambient dry air channel. The humid air including water vapor produced in an evaporative cooling tower is cooled by the ambient dry air so that the water vapor is condensed and recovered to the liquid water. The conservation equations of mass, momentum, energy and vapor concentration in each fluid region and the energy equation in a solid region are simultaneously solved with the heat and mass transfer boundary conditions coupled to the effect of condensation on the channel surface of humid air. The present computation demonstrates the condensed water film distribution on the humid air channel, which is caused by the vapor mass transfer between the humid air and the colder water film surface, which is coupled to the indirect heat exchange with the ambient air. Computations are carried out to predict water recovery rate in parallel, counter and cross-flow type heat exchangers. The effects of air flow rate and channel interval on the water recovery rate are quantified.

Seasonal Fluctuations in Air Pollution in Dazaifu, Japan, and Effect of Long-Range Transport from Mainland East Asia.

PubMed

Coulibaly, Souleymane; Minami, Hiroki; Abe, Maho; Hasei, Tomohiro; Sera, Nobuyuki; Yamamoto, Shigekazu; Funasaka, Kunihiro; Asakawa, Daichi; Watanabe, Masanari; Honda, Naoko; Wakabayashi, Keiji; Watanabe, Tetsushi

2015-01-01

To clarify the seasonal fluctuations in air pollution and the effect of long-range transport, we collected airborne particles (n=118) at Dazaifu in Fukuoka, Japan, from June 2012 to May 2013 and measured Pb and SO4(2-), which are indicators of the long-range transport of anthropogenic air pollutants, as well as their mutagenicity, and other factors. The levels of airborne particles, Pb, and SO4(2-) were very high on March 4, 8, 9, and 19, and May 13, 21, and 22, 2013. The backward trajectories indicated that air masses had arrived from the Gobi Desert and northern China on those days. The mutagenicity of airborne particles was examined using the Ames test on Salmonella typhimurium YG1024. Highly mutagenic airborne particles were mostly collected in winter, and most of them showed high activity both with and without S9 mix. High levels of polycyclic aromatic hydrocarbons (PAHs) were found in many samples that showed high mutagenicity. For the samples collected on January 30, February 21, and March 4, the levels of Pb, SO4(2-), PAHs, and mutagenicity were high, and the backward trajectories indicated that air masses present on those days had passed through northern or central China. The Japan Meteorological Agency registered Asian dust events at Fukuoka on March 8, 9, and 19, 2013. The results of the present study suggest that high levels of anthropogenic air pollutants were transported with Asian dust. Similarly, long-range transport of air pollutants including mutagens occurred on days when Asian dust events were not registered.

The AIRE -230Y Polymorphism Affects AIRE Transcriptional Activity: Potential Influence on AIRE Function in the Thymus

PubMed Central

Lovewell, Thomas R. J.; McDonagh, Andrew J.; Messenger, Andrew G.; Azzouz, Mimoun; Tazi-Ahnini, Rachid

2015-01-01

Background The autoimmune regulator (AIRE) is expressed in the thymus, particularly in thymic medullary epithelial cells (mTECs), and is required for the ectopic expression of a diverse range of peripheral tissue antigens by mTECs, facilitating their ability to perform negative selection of auto-reactive immature T-cells. The expression profile of peripheral tissue antigens is affected not only by AIRE deficiency but also with variation of AIRE activity in the thymus. Method and Results Therefore we screened 591bp upstream of the AIRE transcription start site including AIRE minimal promoter for single nucleotide polymorphism (SNPs) and identified two SNPs -655R (rs117557896) and -230Y (rs751032) respectively. To study the effect of these variations on AIRE promoter activity we generated a Flp-In host cell line which was stably transfected with a single copy of the reporter vector. Relative promoter activity was estimated by comparing the luciferase specific activity for lysates of the different reporter AIRE promoter-reporter gene constructs including AIRE-655G AIRE-230C, AIRE-655G AIRE-230T and AIRE-655A AIRE-230C. The analysis showed that the commonest haplotype AIRE-655G AIRE-230C has the highest luciferase specific activity (p<0.001). Whereas AIRE-655G AIRE-230T has a luciferase specific activity value that approaches null. Both AIRE promoter polymorphic sites have one allele that forms a CpG methylation site which we determined can be methylated in methylation assays using the M.SssI CpG methyltransferase. Conclusion AIRE-230Y is in a conserved region of the promoter and is adjacent to a predicted WT1 transcription factor binding site, suggesting that AIRE-230Y affects AIRE expression by influencing the binding of biochemical factors to this region. Our findings show that AIRE-655GAIRE-230T haplotype could dramatically alter AIRE transcription and so have an effect on the process of negative selection and affect susceptibility to autoimmune conditions. PMID

The AIRE -230Y Polymorphism Affects AIRE Transcriptional Activity: Potential Influence on AIRE Function in the Thymus.

PubMed

Lovewell, Thomas R J; McDonagh, Andrew J; Messenger, Andrew G; Azzouz, Mimoun; Tazi-Ahnini, Rachid

2015-01-01

The autoimmune regulator (AIRE) is expressed in the thymus, particularly in thymic medullary epithelial cells (mTECs), and is required for the ectopic expression of a diverse range of peripheral tissue antigens by mTECs, facilitating their ability to perform negative selection of auto-reactive immature T-cells. The expression profile of peripheral tissue antigens is affected not only by AIRE deficiency but also with variation of AIRE activity in the thymus. Therefore we screened 591bp upstream of the AIRE transcription start site including AIRE minimal promoter for single nucleotide polymorphism (SNPs) and identified two SNPs -655R (rs117557896) and -230Y (rs751032) respectively. To study the effect of these variations on AIRE promoter activity we generated a Flp-In host cell line which was stably transfected with a single copy of the reporter vector. Relative promoter activity was estimated by comparing the luciferase specific activity for lysates of the different reporter AIRE promoter-reporter gene constructs including AIRE-655G AIRE-230C, AIRE-655G AIRE-230T and AIRE-655A AIRE-230C. The analysis showed that the commonest haplotype AIRE-655G AIRE-230C has the highest luciferase specific activity (p<0.001). Whereas AIRE-655G AIRE-230T has a luciferase specific activity value that approaches null. Both AIRE promoter polymorphic sites have one allele that forms a CpG methylation site which we determined can be methylated in methylation assays using the M.SssI CpG methyltransferase. AIRE-230Y is in a conserved region of the promoter and is adjacent to a predicted WT1 transcription factor binding site, suggesting that AIRE-230Y affects AIRE expression by influencing the binding of biochemical factors to this region. Our findings show that AIRE-655GAIRE-230T haplotype could dramatically alter AIRE transcription and so have an effect on the process of negative selection and affect susceptibility to autoimmune conditions.

Calibration of nozzle for air mass flow measurement

NASA Astrophysics Data System (ADS)

Uher, Jan; Kanta, Lukáš

2017-09-01

The effort to make calibration measurement of mass flow through a nozzle was not satisfying. Traversing across the pipe radius with Pitot probe was done. The presence of overshoot behind the bend in the pipe was found. The overshoot led to an asymmetric velocity profile.

Physical and chemical processes of air masses in the Aegean Sea during Etesians: Aegean-GAME airborne campaign.

PubMed

Tombrou, M; Bossioli, E; Kalogiros, J; Allan, J D; Bacak, A; Biskos, G; Coe, H; Dandou, A; Kouvarakis, G; Mihalopoulos, N; Percival, C J; Protonotariou, A P; Szabó-Takács, B

2015-02-15

High-resolution measurements of gas and aerosols' chemical composition along with meteorological and turbulence parameters were performed over the Aegean Sea (AS) during an Etesian outbreak in the framework of the Aegean-GAME airborne campaign. This study focuses on two distinct Etesian patterns, with similarities inside the Marine Atmospheric Boundary Layer (MABL) and differences at higher levels. Under long-range transport and subsidence the pollution load is enhanced (by 17% for CO, 11% for O3, 28% for sulfate, 62% for organic mass, 47% for elemental carbon), compared to the pattern with a weaker synoptic system. Sea surface temperature (SST) was a critical parameter for the MABL structure, turbulent fluxes and pollutants' distribution at lower levels. The MABL height was below 500 m asl over the eastern AS (favoring higher accumulation), and deeper over the western AS. The most abundant components of total PM1 were sulfate (40-50%) and organics (30-45%). Higher average concentrations measured over the eastern AS (131 ± 76 ppbv for CO, 62.5 ± 4.1 ppbv for O3, 5.0 ± 1.1 μg m(-3) for sulfate, 4.7 ± 0.9 μg m(-3) for organic mass and 0.5 ± 0.2 μg m(-3) for elemental carbon). Under the weaker synoptic system, cleaner but more acidic air masses prevailed over the eastern part, while distinct aerosol layers of different signature were observed over the western part. The Aitken and accumulation modes contributed equally during the long-range transport, while the Aitken modes dominated during local or medium range transport. Copyright © 2014 Elsevier B.V. All rights reserved.

Peripubertal female athletes in high-impact sports show improved bone mass acquisition and bone geometry.

PubMed

Maïmoun, Laurent; Coste, Olivier; Philibert, Pascal; Briot, Karine; Mura, Thibault; Galtier, Florence; Mariano-Goulart, Denis; Paris, Françoise; Sultan, Charles

2013-08-01

Intensive physical training may have a sport-dependent effect on bone mass acquisition. This cross-sectional study evaluated bone mass acquisition in girls practicing sports that put different mechanical loads on bone. Eighty girls from 10.7 to 18.0 years old (mean 13.83 ± 1.97) were recruited: 20 artistic gymnasts (AG; high-impact activity), 20 rhythmic gymnasts (RG; medium-impact activity), 20 swimmers (SW, no-impact activity), and 20 age-matched controls (CON; leisure physical activity <3h/wk). Areal bone mineral density (aBMD) was determined using DEXA. Hip structural analysis applied at the femur evaluated cross-sectional area (CSA, cm(2)), section modulus (Z, cm(3)), and buckling ratio. Bone turnover markers and OPG/RANKL levels were analyzed. AG had higher aBMD than SW and CON at all bone sites and higher values than RG in the lumbar spine and radius. RG had higher aBMD than SW and CON only in the femoral region. CSA and mean cortical thickness were significantly higher and the buckling ratio was significantly lower in both gymnast groups compared with SW and CON. In RG only, endocortical diameter and width were reduced, while Z was only increased in AG compared with SW and CON. Reduced bone remodeling was observed in RG compared with AG only when groups were subdivided according to menarcheal status. All groups showed similar OPG concentrations, while RANKL concentrations increased with age and were decreased in SW. High-impact activity clearly had a favorable effect on aBMD and bone geometry during the growth period, although the bone health benefits seem to be more marked after menarche. Copyright © 2013 Elsevier Inc. All rights reserved.

A rocket-borne mass analyzer for charged aerosol particles in the mesosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knappmiller, Scott; Robertson, Scott; Sternovsky, Zoltan

2008-10-15

An electrostatic mass spectrometer for nanometer-sized charged aerosol particles in the mesosphere has been developed and tested. The analyzer is mounted on the forward end of a rocket and has a slit opening for admitting a continuous sample of air that is exhausted through ports at the sides. Within the instrument housing are two sets of four collection plates that are biased with positive and negative voltages for the collection of negative and positive aerosol particles, respectively. Each collection plate spans about an order of magnitude in mass which corresponds to a factor of 2 in radius. The number densitymore » of the charge is calculated from the current collected by the plates. The mean free path for molecular collisions in the mesosphere is comparable to the size of the instrument opening; thus, the analyzer performance is modeled by a Monte Carlo computer code that finds the aerosol particles trajectories within the instrument including both the electrostatic force and the forces from collisions of the aerosol particles with air molecules. Mass sensitivity curves obtained using the computer models are near to those obtained in the laboratory using an ion source. The first two flights of the instrument returned data showing the charge number densities of both positive and negative aerosol particles in four mass ranges.« less

Methods, fluxes and sources of gas phase alkyl nitrates in the coastal air.

PubMed

Dirtu, Alin C; Buczyńska, Anna J; Godoi, Ana F L; Favoreto, Rodrigo; Bencs, László; Potgieter-Vermaak, Sanja S; Godoi, Ricardo H M; Van Grieken, René; Van Vaeck, Luc

2014-10-01

The daily and seasonal atmospheric concentrations, deposition fluxes and emission sources of a few C3-C9 gaseous alkyl nitrates (ANs) at the Belgian coast (De Haan) on the Southern North Sea were determined. An adapted sampler design for low- and high-volume air-sampling, optimized sample extraction and clean-up, as well as identification and quantification of ANs in air samples by means of gas chromatography mass spectrometry, are reported. The total concentrations of ANs ranged from 0.03 to 85 pptv and consisted primarily of the nitro-butane and nitro-pentane isomers. Air mass backward trajectories were calculated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to determine the influence of main air masses on AN levels in the air. The shorter chain ANs have been the most abundant in the Atlantic/Channel/UK air masses, while longer chain ANs prevailed in continental air. The overall mean N fluxes of the ANs were slightly higher for summer than those for winter-spring, although their contributions to the total nitrogen flux were low. High correlations between AN and HNO₂ levels were observed during winter/spring. During summer, the shorter chain ANs correlated well with precipitation. Source apportionment by means of principal component analysis indicated that most of the gas phase ANs could be attributed to traffic/combustion, secondary photochemical formation and biomass burning, although marine sources may also have been present and a contributing factor.