air-sf6-air incident shock: Topics by Science.gov

Measurement of cardiac output using improved chromatographic analysis of sulfur hexafluoride (SF6).

Tian, B.

2017-12-01

The Coupled Model Intercomparison Project (CMIP) has become a central element of national and international assessments of climate change. The CMIP Phase 6 (CMIP6) model experiments will be the foundation for the Intergovernmental Panel on Climate Change (IPCC) Sixth Assessment Report (AR6), scheduled for publication around 2021. To increase the fidelity of the IPCC AR6, the CMIP6 model experiments need rigorous evaluation. The "Observations for Model Intercomparison Projects" (Obs4MIPs) collects, organizes and publishes various well-established satellite data sets for CMIP model evaluation. The Atmospheric Infrared Sounder (AIRS) and Advanced Microwave Sounding Unit (AMSU), the NASA's temperature and humidity sounding system on the Aqua satellite, has provided over a decade-long high-quality tropospheric temperature and moisture sounding data. Under the current support of the NASA Data for Operation and Assessment (NDOA) program, we are generating and publishing the AIRS Obs4MIPs V2 data set including the monthly mean tropospheric air temperature, specific humidity, and relative humidity profiles from September 2002 to September 2016. This will provide the latest AIRS data in Obs4MIPs and assist the climate modeling community to better use the AIRS data for CMIP (including CMIP3, CMIP5, and CMIP6) model evaluation. In this presentation, we will discuss the AIRS Obs4MIPs V2 data set and their possible use for CMIP6 climate model evaluation.

A novel method to decompose two potent greenhouse gases: photoreduction of SF6 and SF5CF3 in the presence of propene.

Klocke, F J; Roberts, D L; Farhi, E R; Naughton, B J; Sekovski, B; Klocke, R A

1977-06-01

A constant current variable frequency pulsed electron capture detector has been incorporated into the gas chromatographic analysis of trace amounts of sulfur hexafluoride (SF6) in water and blood. The resulting system offers a broader effective operating range than more conventional electron capture units and has been utilized for measurements of cardiac output employing constant-rate infusion of dissolved SF6. The SF6 technique has been validated against direct volumetric measurements of cardiac output in a canine right-heart bypass preparation and used subsequently for rapidly repeated measurements in conscious animals and man.

Air-Based Remediation Workshop - Section 6 Thermal Systems

Huang, Li; Shen, Yan; Dong, Wenbo; Zhang, Renxi; Zhang, Jianliang; Hou, Huiqi

2008-03-01

SF5CF3 and SF6 are the most effective greenhouse gases on a per molecule basis in the atmosphere. Original laboratory trial for photoreduction of them by use of propene as a reactant was performed to develop a novel technique to destroy them. The highly reductive radicals produced during the photolysis of propene at 184.9 nm, such as .CH3, .C2H3, and .C3H5, could efficiently decompose SF6 and SF5CF3 to CH4, elemental sulfur and trace amounts of fluorinated organic compounds. It was further demonstrated that the destruction and removal efficiency (DRE) of SF5X (X represented F or CF3) was highly dependent on the initial propene-to-SF5X ratio. The addition of certain amounts of oxygen and water vapor not only enhanced the DRE but avoided the generation of deposits. In both systems, employment nitrogen as dilution gas lessened the DRE slightly. Given the advantage of less toxic products, the technique might contribute to SF5X remediation.

EPA Science Inventory

Pursuant to the EPA-AIT Implementing Arrangement 7 for Technical Environmental Collaboration, Activity 11 "Remediation of Contaminated Sites," the USEPA Office of International Affairs Organized a Forced Air Remediation Workshop in Taipei to deliver expert training to the Environ...

High Lapse Rates in AIRS Retrieved Temperatures in Cold Air Outbreaks

IR spectroscopic study of the displacement of an SF6 monolayer on graphite by Xe

Fetzer, Eric J.; Kahn, Brian; Olsen, Edward T.; Fishbein, Evan

2004-01-01

The Atmospheric Infrared Sounder (AIRS) experiment, on NASA's Aqua spacecraft, uses a combination of infrared and microwave observations to retrieve cloud and surface properties, plus temperature and water vapor profiles comparable to radiosondes throughout the troposphere, for cloud cover up to 70%. The high spectral resolution of AIRS provides sensitivity to important information about the near-surface atmosphere and underlying surface. A preliminary analysis of AIRS temperature retrievals taken during January 2003 reveals extensive areas of superadiabatic lapse rates in the lowest kilometer of the atmosphere. These areas are found predominantly east of North America over the Gulf Stream, and, off East Asia over the Kuroshio Current. Accompanying the high lapse rates are low air temperatures, large sea-air temperature differences, and low relative humidities. Imagery from a Visible / Near Infrared instrument on the AIRS experiment shows accompanying clouds. These lines of evidence all point to shallow convection in the bottom layer of a cold air mass overlying warm water, with overturning driven by heat flow from ocean to atmosphere. An examination of operational radiosondes at six coastal stations in Japan shows AIRS to be oversensitive to lower tropospheric lapse rates due to systematically warm near-surface air temperatures. The bias in near-surface air temperature is seen to be independent of sea surface temperature, however. AIRS is therefore sensitive to air-sea temperature difference, but with a warm atmospheric bias. A regression fit to radiosondes is used to correct AIRS near-surface retrieved temperatures, and thereby obtain an estimate of the true atmosphere-ocean thermal contrast in five subtropical regions across the north Pacific. Moving eastward, we show a systematic shift in this air-sea temperature differences toward more isothermal conditions. These results, while preliminary, have implications for our understanding of heat flow from ocean to

IR spectroscopic study of the displacement of an SF6 monolayer on graphite by Xe.

Hess, G. B.; Xia, Yu

2017-09-01

We report a study of displacement by xenon of a monolayer of sulphur hexafluoride initially condensed on a graphite surface. Earlier work showed that, below 112 K, Xe displaces SF6 almost completely in a first-order transition. Working at higher temperatures, we show that this system has a simple eutectic-like phase diagram, at least for SF6 not too dilute. In our experiment, both adsorbates are in equilibrium with their respective vapors in a cold cell. In our infrared reflection-absorption spectroscopy measurements, the SF6 coverage on the surface is monitored by the frequency shift due to dynamic dipole coupling of the collective mode of the strong SF6 ν3 vibrational resonance. Simulations relate this frequency shift to the SF6 areal density. Below T ≈ 134 K, with increasing Xe pressure, a small amount Xe dissolves in the solid SF6 monolayer preceding its displacement by a solid predominantly Xe monolayer in a first-order transition. Above 134 K, there is a weaker first-order transition to a mixed liquid monolayer, followed by continuous increase in Xe concentration. If the initial SF6 monolayer is near its melting line, the melting transition on adding Xe appears to become continuous.

Theoretical and Experimental Investigation of Heat Conduction in Air, Including Effects of Oxygen Dissociation

Hess, G B; Xia, Yu

2017-09-07

We report a study of displacement by xenon of a monolayer of sulphur hexafluoride initially condensed on a graphite surface. Earlier work showed that, below 112 K, Xe displaces SF 6 almost completely in a first-order transition. Working at higher temperatures, we show that this system has a simple eutectic-like phase diagram, at least for SF 6 not too dilute. In our experiment, both adsorbates are in equilibrium with their respective vapors in a cold cell. In our infrared reflection-absorption spectroscopy measurements, the SF 6 coverage on the surface is monitored by the frequency shift due to dynamic dipole coupling of the collective mode of the strong SF 6 ν 3 vibrational resonance. Simulations relate this frequency shift to the SF 6 areal density. Below T ≈ 134 K, with increasing Xe pressure, a small amount Xe dissolves in the solid SF 6 monolayer preceding its displacement by a solid predominantly Xe monolayer in a first-order transition. Above 134 K, there is a weaker first-order transition to a mixed liquid monolayer, followed by continuous increase in Xe concentration. If the initial SF 6 monolayer is near its melting line, the melting transition on adding Xe appears to become continuous.

Angular dependence of etch rates in the etching of poly-Si and fluorocarbon polymer using SF6, C4F8, and O2 plasmas

Hansen, C. Frederick; Early, Richard A.; Alzofon, Frederick E.; Witteborn, Fred C.

1959-01-01

Solutions are presented for the conduction of beat through a semi-infinite gas medium having a uniform initial temperature and a constant boundary temperature. The coefficients of thermal conductivity and diffusivity are treated as variables, and the solutions are extended to the case of air at temperatures where oxygen dissociation occurs. These solutions are used together with shock-tube measurements to evaluate the integral of thermal conductivity for air as a function of temperature.

The role of Environmental Health System air quality monitors in Space Station Contingency Operations

Min, Jae-Ho; Lee, Gyeo-Re; Lee, Jin-Kwan; Moon, Sang Heup; Kim, Chang-Koo

2004-05-01

The dependences of etch rates on the angle of ions incident on the substrate surface in four plasma/substrate systems that constitute the advanced Bosch process were investigated using a Faraday cage designed for the accurate control of the ion-incident angle. The four systems, established by combining discharge gases and substrates, were a SF6/poly-Si, a SF6/fluorocarbon polymer, an O2/fluorocarbon polymer, and a C4F8/Si. In the case of SF6/poly-Si, the normalized etch rates (NERs), defined as the etch rates normalized by the rate on the horizontal surface, were higher at all angles than values predicted from the cosine of the ion-incident angle. This characteristic curve shape was independent of changes in process variables including the source power and bias voltage. Contrary to the earlier case, the NERs for the O2/polymer decreased and eventually reached much lower values than the cosine values at angles between 30° and 70° when the source power was increased and the bias voltage was decreased. On the other hand, the NERs for the SF6/polymer showed a weak dependence on the process variables. In the case of C4F8/Si, which is used in the Bosch process for depositing a fluorocarbon layer on the substrate surface, the deposition rate varied with the ion incident angle, showing an S-shaped curve. These characteristic deposition rate curves, which were highly dependent on the process conditions, could be divided into four distinct regions: a Si sputtering region, an ion-suppressed polymer deposition region, an ion-enhanced polymer deposition region, and an ion-free polymer deposition region. Based on the earlier characteristic angular dependences of the etch (or deposition) rates in the individual systems, ideal process conditions for obtaining an anisotropic etch profile in the advanced Bosch process are proposed. .

Changes in U.S. Regional-Scale Air Quality at 2030 Simulated Using RCP 6.0

Limero, Thomas F.; Wilson, Steve; Perlot, Susan; James, John

1992-01-01

This paper describes the Space Station Freedom (SSF) Environmental Health System's air-quality monitoring strategy and instrumentation. A two-tier system has been developed, consisting of first-alert instruments that warn the crew of airborne contamination and a volatile organic analyzer that can identify volatile organic contaminants in near-real time. The strategy for air quality monitoring on SSF is designed to provide early detection so that the contamination can be confined to one module and so that crew health and safety can be protected throughout the contingency event. The use of air-quality monitors in fixed and portable modes will be presented as a means of following the progress of decontamination efforts and ensuring acceptable air quality in a module after an incident. The technology of each instrument will be reviewed briefly; the main focus of this paper, however, will be the use of air-quality monitors before, during, and after contingency incidents.

Hydrogen /Hydride/-air secondary battery

Nolte, C. G.; Otte, T.; Pinder, R. W.; Faluvegi, G.; Shindell, D. T.

2012-12-01

Recent improvements in air quality in the United States have been due to significant reductions in emissions of ozone and particulate matter (PM) precursors, and these downward emissions trends are expected to continue in the next few decades. To ensure that planned air quality regulations are robust under a range of possible future climates and to consider possible policy actions to mitigate climate change, it is important to characterize and understand the effects of climate change on air quality. Recent work by several research groups using global and regional models has demonstrated that there is a "climate penalty," in which climate change leads to increases in surface ozone levels in polluted continental regions. One approach to simulating future air quality at the regional scale is via dynamical downscaling, in which fields from a global climate model are used as input for a regional climate model, and these regional climate data are subsequently used for chemical transport modeling. However, recent studies using this approach have encountered problems with the downscaled regional climate fields, including unrealistic surface temperatures and misrepresentation of synoptic pressure patterns such as the Bermuda High. We developed a downscaling methodology and showed that it now reasonably simulates regional climate by evaluating it against historical data. In this work, regional climate simulations created by downscaling the NASA/GISS Model E2 global climate model are used as input for the Community Multiscale Air Quality (CMAQ) model. CMAQ simulations over the continental United States are conducted for two 11-year time slices, one representing current climate (1995-2005) and one following Representative Concentration Pathway 6.0 from 2025-2035. Anthropogenic emissions of ozone and PM precursors are held constant at year 2006 levels for both the current and future periods. In our presentation, we will examine the changes in ozone and PM concentrations, with

ERIC Educational Resources Information Center

Sarradin, J.; Bronoel, G.; Percheron-Guegan, A.; Achard, J. C.

1979-01-01

The use of metal hydrides as negative electrodes in a hydrogen-air secondary battery seems promising. However, in an unpressurized cell, more stable hydrides that LaNi5H6 must be selected. Partial substitutions of nickel by aluminium or manganese increase the stability of hydrides. Combined with an air reversible electrode, a specific energy close to 100 Wh/kg can be expected.

Air Pollution.

Gilpin, Alan

A summary of one of our most pressing environmental problems, air pollution, is offered in this book by the Director of Air Pollution Control for the Queensland (Australia) State Government. Discussion of the subject is not restricted to Queensland or Australian problems and policies, however, but includes analysis of air pollution the world over.…

Indoor air humidity, air quality, and health - An overview.