Inverse modeling of Texas NOx emissions using space-based and ground-based NO2 observations

NASA Astrophysics Data System (ADS)

Tang, W.; Cohan, D. S.; Lamsal, L. N.; Xiao, X.; Zhou, W.

2013-11-01

Inverse modeling of nitrogen oxide (NOx) emissions using satellite-based NO2 observations has become more prevalent in recent years, but has rarely been applied to regulatory modeling at regional scales. In this study, OMI satellite observations of NO2 column densities are used to conduct inverse modeling of NOx emission inventories for two Texas State Implementation Plan (SIP) modeling episodes. Addition of lightning, aircraft, and soil NOx emissions to the regulatory inventory narrowed but did not close the gap between modeled and satellite-observed NO2 over rural regions. Satellite-based top-down emission inventories are created with the regional Comprehensive Air Quality Model with extensions (CAMx) using two techniques: the direct scaling method and discrete Kalman filter (DKF) with decoupled direct method (DDM) sensitivity analysis. The simulations with satellite-inverted inventories are compared to the modeling results using the a priori inventory as well as an inventory created by a ground-level NO2-based DKF inversion. The DKF inversions yield conflicting results: the satellite-based inversion scales up the a priori NOx emissions in most regions by factors of 1.02 to 1.84, leading to 3-55% increase in modeled NO2 column densities and 1-7 ppb increase in ground 8 h ozone concentrations, while the ground-based inversion indicates the a priori NOx emissions should be scaled by factors of 0.34 to 0.57 in each region. However, none of the inversions improve the model performance in simulating aircraft-observed NO2 or ground-level ozone (O3) concentrations.

Inverse modeling of Texas NOx emissions using space-based and ground-based NO2 observations

NASA Astrophysics Data System (ADS)

Tang, W.; Cohan, D.; Lamsal, L. N.; Xiao, X.; Zhou, W.

2013-07-01

Inverse modeling of nitrogen oxide (NOx) emissions using satellite-based NO2 observations has become more prevalent in recent years, but has rarely been applied to regulatory modeling at regional scales. In this study, OMI satellite observations of NO2 column densities are used to conduct inverse modeling of NOx emission inventories for two Texas State Implementation Plan (SIP) modeling episodes. Addition of lightning, aircraft, and soil NOx emissions to the regulatory inventory narrowed but did not close the gap between modeled and satellite observed NO2 over rural regions. Satellite-based top-down emission inventories are created with the regional Comprehensive Air Quality Model with extensions (CAMx) using two techniques: the direct scaling method and discrete Kalman filter (DKF) with Decoupled Direct Method (DDM) sensitivity analysis. The simulations with satellite-inverted inventories are compared to the modeling results using the a priori inventory as well as an inventory created by a ground-level NO2 based DKF inversion. The DKF inversions yield conflicting results: the satellite-based inversion scales up the a priori NOx emissions in most regions by factors of 1.02 to 1.84, leading to 3-55% increase in modeled NO2 column densities and 1-7 ppb increase in ground 8 h ozone concentrations, while the ground-based inversion indicates the a priori NOx emissions should be scaled by factors of 0.34 to 0.57 in each region. However, none of the inversions improve the model performance in simulating aircraft-observed NO2 or ground-level ozone (O3) concentrations.

Scheduled Civil Aircraft Emission Inventories for 1976 and 1984: Database Development and Analysis

NASA Technical Reports Server (NTRS)

Baughcum, Steven L.; Henderson, Stephen C.; Tritz, Terrance G.

1996-01-01

This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from scheduled commercial aircraft for four months (February, May, August, and November) of 1976 and 1984. Combining this data with earlier published data for 1990 and 1992, trend analyses for fuel burned, NOx, carbon monoxide, and hydrocarbons were calculated for selected regions (global, North America, Europe, North Atlantic, and North Pacific). These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Aviation Project (AEAP) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer altitude grid and delivered to NASA as electronic files.

Top-Down Constraints on Air Quality Model Emissions of NH3, NOx, and SO2 using Surface, Aircraft, and Satellite Data

NASA Astrophysics Data System (ADS)

Alvarado, M. J.; Lonsdale, C. R.; Winijkul, E.; Brodowski, C. M.; Cady-Pereira, K.; Henze, D. K.; Capps, S.

2016-12-01

Accurate modeling of the formation of ozone (O3) and fine particulate matter (PM2.5) requires accurate estimates of the emissions of precursor species such as ammonia (NH3), nitrogen oxides (NOx = NO+NO2) and sulfur dioxide (SO2). Here we present an evaluation of the 2011 EPA National Emission Inventory for NH3, NOx, and SO2 using CMAQv5.0.2 and data from the 2013 NOAA Southeast Nexus (SENEX) field campaign. Model results are compared to surface and aircraft measurements during each campaign, as well as satellite NH3 observations from the NOAA Cross-track Infrared Sounder (CrIS) and satellite observations of NO2 and SO2 from the NASA Ozone Monitoring Instrument (OMI). We also present an evaluation of the California Air Resources Board (CARB) NH3 emissions for 2012 using CMAQ and the CrIS NH3 observations. We discuss the lessons learned in using CrIS NH3 observations in the southeast US, where CMAQ predicts most of the gas-phase NH3 is very close to the surface, and contrast this with the use of CrIS NH3 observations over California. We discuss the use of two methods - a mass balance approach and an approach using the CMAQ adjoint - to optimize these emissions and evaluate the improvement in model performance for gas-phase NH3, NOx, and SO2, as well as for the formation of O3 and PM2.5.

Gas and Particulate Aircraft Emissions Measurements: Impacts on local air quality.

NASA Astrophysics Data System (ADS)

Jayne, J. T.; Onasch, T.; Northway, M.; Canagaratna, M.; Worsnop, D.; Timko, M.; Wood, E.; Miake-Lye, R.; Herndon, S.; Knighton, B.; Whitefield, P.; Hagen, D.; Lobo, P.; Anderson, B.

2007-12-01

Air travel and freight shipping by air are becoming increasingly important and are expected to continue to expand. The resulting increases in the local concentrations of pollutants, including particulate matter (PM), volatile organic compounds (VOCs), and nitrogen oxides (NOX), can have negative impacts on regional air quality, human health and can impact climate change. In order to construct valid emission inventories, accurate measurements of aircraft emissions are needed. These measurements must be done both at the engine exit plane (certification) and downwind following the rapid cooling, dilution and initial atmospheric processing of the exhaust plume. We present here results from multiple field experiments which include the Experiment to Characterize Volatile Aerosol and Trace Species Emissions (EXCAVATE) and the four Aircraft Particle Emissions eXperiments (APEX- 1/Atlanta/2/3) which characterized gas and particle emissions from both stationary or in-use aircraft. Emission indices (EIs) for NOx and VOCs and for particle number concentration, refractory PM (black carbon soot) and volatile PM (primarily sulfate and organic) particles are reported. Measurements were made at the engine exit plane and at several downstream locations (10 and 30 meters) for a number of different engine types and engine thrust settings. A significant fraction of organic particle mass is composed of low volatility oil-related compounds and is not combustion related, potentially emitted by vents or heated surfaces within aircraft engines. Advected plumes measurements from in-use aircraft show that the practice of reduced thrust take-offs has a significant effect on total NOx and soot emitted in the vicinity of the airport. The measurements reported here represent a first observation of this effect and new insights have been gained with respect to the chemical processing of gases and particulates important to the urban airshed.

Aircraft Emission Scenarios Projected in Year 2015 for the NASA Technology Concept Aircraft (TCA) High Speed Civil Transport

NASA Technical Reports Server (NTRS)

Baughcum, Steven L.; Henderson, Stephen C.

1998-01-01

This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from projected fleets of high speed civil transports (HSCTs) on a universal airline network. Inventories for 500 and 1000 HSCT fleets, as well as the concurrent subsonic fleets, were calculated. The HSCT scenarios are calculated using the NASA technology concept airplane (TCA) and update an earlier report. These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Stratospheric Aircraft (AESA) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer pressure altitude grid and delivered to NASA as electronic files.

Water Misting and Injection of Commercial Aircraft Engines to Reduce Airport NOx

NASA Technical Reports Server (NTRS)

Daggett, David L.; Hendricks, Robert C. (Technical Monitor)

2004-01-01

This report provides the first high level look at system design, airplane performance, maintenance, and cost implications of using water misting and water injection technology in aircraft engines for takeoff and climb-out NOx emissions reduction. With an engine compressor inlet water misting rate of 2.2 percent water-to-air ratio, a 47 percent NOx reduction was calculated. Combustor water injection could achieve greater reductions of about 85 percent, but with some performance penalties. For the water misting system on days above 59 F, a fuel efficiency benefit of about 3.5 percent would be experienced. Reductions of up to 436 F in turbine inlet temperature were also estimated, which could lead to increased hot section life. A 0.61 db noise reduction will occur. A nominal airplane weight penalty of less than 360 lb (no water) was estimated for a 305 passenger airplane. The airplane system cost is initially estimated at $40.92 per takeoff giving an attractive NOx emissions reduction cost/benefit ratio of about $1,663/ton.

40 CFR 75.70 - NOX mass emissions provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 17 2012-07-01 2012-07-01 false NOX mass emissions provisions. 75.70... (CONTINUED) CONTINUOUS EMISSION MONITORING NOX Mass Emissions Provisions § 75.70 NOX mass emissions... subpart to the extent that compliance is required by an applicable State or federal NOX mass emission...

Global mortality attributable to aircraft cruise emissions.

PubMed

Barrett, Steven R H; Britter, Rex E; Waitz, Ian A

2010-10-01

Aircraft emissions impact human health though degradation of air quality. The majority of previous analyses of air quality impacts from aviation have considered only landing and takeoff emissions. We show that aircraft cruise emissions impact human health over a hemispheric scale and provide the first estimate of premature mortalities attributable to aircraft emissions globally. We estimate ∼8000 premature mortalities per year are attributable to aircraft cruise emissions. This represents ∼80% of the total impact of aviation (where the total includes the effects of landing and takeoff emissions), and ∼1% of air quality-related premature mortalities from all sources. However, we note that the impact of landing and takeoff emissions is likely to be under-resolved. Secondary H(2)SO(4)-HNO(3)-NH(3) aerosols are found to dominate mortality impacts. Due to the altitude and region of the atmosphere at which aircraft emissions are deposited, the extent of transboundary air pollution is particularly strong. For example, we describe how strong zonal westerly winds aloft, the mean meridional circulation around 30-60°N, interaction of aircraft-attributable aerosol precursors with background ammonia, and high population densities in combination give rise to an estimated ∼3500 premature mortalities per year in China and India combined, despite their relatively small current share of aircraft emissions. Subsidence of aviation-attributable aerosol and aerosol precursors occurs predominantly around the dry subtropical ridge, which results in reduced wet removal of aviation-attributable aerosol. It is also found that aircraft NO(x) emissions serve to increase oxidation of nonaviation SO(2), thereby further increasing the air quality impacts of aviation. We recommend that cruise emissions be explicitly considered in the development of policies, technologies and operational procedures designed to mitigate the air quality impacts of air transportation.

Quantifying the isotopic composition of NOx emission sources: An analysis of collection methods

NASA Astrophysics Data System (ADS)

Fibiger, D.; Hastings, M.

2012-04-01

We analyze various collection methods for nitrogen oxides, NOx (NO2 and NO), used to evaluate the nitrogen isotopic composition (δ15N). Atmospheric NOx is a major contributor to acid rain deposition upon its conversion to nitric acid; it also plays a significant role in determining air quality through the production of tropospheric ozone. NOx is released by both anthropogenic (fossil fuel combustion, biomass burning, aircraft emissions) and natural (lightning, biogenic production in soils) sources. Global concentrations of NOx are rising because of increased anthropogenic emissions, while natural source emissions also contribute significantly to the global NOx burden. The contributions of both natural and anthropogenic sources and their considerable variability in space and time make it difficult to attribute local NOx concentrations (and, thus, nitric acid) to a particular source. Several recent studies suggest that variability in the isotopic composition of nitric acid deposition is related to variability in the isotopic signatures of NOx emission sources. Nevertheless, the isotopic composition of most NOx sources has not been thoroughly constrained. Ultimately, the direct capture and quantification of the nitrogen isotopic signatures of NOx sources will allow for the tracing of NOx emissions sources and their impact on environmental quality. Moreover, this will provide a new means by which to verify emissions estimates and atmospheric models. We present laboratory results of methods used for capturing NOx from air into solution. A variety of methods have been used in field studies, but no independent laboratory verification of the efficiencies of these methods has been performed. When analyzing isotopic composition, it is important that NOx be collected quantitatively or the possibility of fractionation must be constrained. We have found that collection efficiency can vary widely under different conditions in the laboratory and fractionation does not vary

Particle and gaseous emissions from commercial aircraft at each stage of the landing and takeoff cycle.

PubMed

Mazaheri, M; Johnson, G R; Morawska, L

2009-01-15

A novel technique was used to measure emission factors for commonly used commercial aircraft including a range of Boeing and Airbus airframes under real world conditions. Engine exhaust emission factors for particles in terms of particle number and mass (PM2.5), along with those for CO2 and NOx, were measured for over 280 individual aircraft during the various modes of landing/takeoff (LTO) cycle. Results from this study show that particle number, and NOx emission factors are dependent on aircraft engine thrust level. Minimum and maximum emissions factors for particle number, PM2.5, and NOx emissions were found to be in the range of 4.16 x 10(15)-5.42 x 10(16) kg(-1), 0.03-0.72 g.kg(-1), and 3.25-37.94 g.kg(-1), respectively, for all measured airframes and LTO cycle modes. Number size distributions of emitted particles for the naturally diluted aircraft plumes in each mode of LTO cycle showed that particles were predominantly in the range of 4-100 nm in diameter in all cases. In general, size distributions exhibit similar modality during all phases of the LTO cycle. A very distinct nucleation mode was observed in all particle size distributions, except for taxiing and landing of A320 aircraft. Accumulation modes were also observed in all particle size distributions. Analysis of aircraft engine emissions during LTO cycle showed that aircraft thrust level is considerably higher during taxiing than idling suggesting that International Civil Aviation Organization (ICAO) standards need to be modified as the thrust levels for taxi and idle are considered to be the same (7% of total thrust) (Environmental Protection, Annex 16, Vol. II, Aircraft Engine Emissions, 2nd ed.; ICAO--International Civil Aviation Organization: Montreal, 1993).

Triple Oxygen Isotope Measurement of Nitrate to Analyze Impact of Aircraft Emissions

NASA Astrophysics Data System (ADS)

Chan, Sharleen

With 4.9% of total anthropogenic radiative forcing attributed to aircraft emissions, jet engines combust copious amounts of fuel producing gases including: NOx (NO + NO2), SOx, VOC's and fine particles [IPCC (1999), IPCC (2007), Lee et al., 2009]. The tropospheric non-linear relationships between NOx, OH and O3 contribute uncertainties in the ozone budget amplified by poor understanding of the NOx cycle. In a polluted urban environment, interaction of gases and particles produce various new compounds that are difficult to measure with analytical tools available today [Thiemens, 2006]. Using oxygen triple isotopic measurement of NO3 to investigate gas to particle formation and chemical transformation in the ambient atmosphere, this study presents data obtained from aerosols sampled at NASA's Dryden Aircraft Operations Facility (DAOF) in Palmdale, CA during January and February, 2009 and Los Angeles International Airport (LAX) during Fall 2009, Winter 2010, and Spring 2010. The aerosols collected from jet aircraft exhaust in Palmdale exhibit an oxygen isotope anomaly (Delta17O =delta 17O -0.52 delta18O) increase with photochemical age of particles (-0.22 to 26.41‰) while NO3 concentration decreases from 53.76 - 5.35ppm with a radial distance from the jet dependency. Bulk aerosol samples from LAX exhibit seasonal variation with Delta17 O and NO3 concentration peaking in winter suggesting multiple sources and increased fossil fuel burning. Using oxygen triple isotopes of NO3, we are able to distinguish primary and secondary nitrate by aircraft emissions allowing new insight into a portion of the global nitrogen cycle. This represents a new and potentially important means to uniquely identify aircraft emissions on the basis of the unique isotopic composition of jet aircraft emissions.

Direct Final Rule for Control of Air Pollution From Aircraft and Aircraft Engines; Emission Standards and Test Procedures

EPA Pesticide Factsheets

This rule will adopt the current voluntary NOx and CO emissions standards of the United Nations International Civil Aviation Organization (ICAO), bringing the United States aircraft standards into alignment with the international standards.

Estimating NOx emissions and surface concentrations at high spatial resolution using OMI

NASA Astrophysics Data System (ADS)

Goldberg, D. L.; Lamsal, L. N.; Loughner, C.; Swartz, W. H.; Saide, P. E.; Carmichael, G. R.; Henze, D. K.; Lu, Z.; Streets, D. G.

2017-12-01

In many instances, NOx emissions are not measured at the source. In these cases, remote sensing techniques are extremely useful in quantifying NOx emissions. Using an exponential modified Gaussian (EMG) fitting of oversampled Ozone Monitoring Instrument (OMI) NO2 data, we estimate NOx emissions and lifetimes in regions where these emissions are uncertain. This work also presents a new high-resolution OMI NO2 dataset derived from the NASA retrieval that can be used to estimate surface level concentrations in the eastern United States and South Korea. To better estimate vertical profile shape factors, we use high-resolution model simulations (Community Multi-scale Air Quality (CMAQ) and WRF-Chem) constrained by in situ aircraft observations to re-calculate tropospheric air mass factors and tropospheric NO2 vertical columns during summertime. The correlation between our satellite product and ground NO2 monitors in urban areas has improved dramatically: r2 = 0.60 in new product, r2 = 0.39 in operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to re-calculate vertical column data in areas with large spatial heterogeneities in NOx emissions. The methodologies developed in this work can be applied to other world regions and other satellite data sets to produce high-quality region-specific emissions estimates.

Modeling Aircraft Emissions for Regional-scale Air Quality: Adapting a New Global Aircraft Emissions Database for the U.S

NASA Astrophysics Data System (ADS)

Arunachalam, S.; Baek, B. H.; Vennam, P. L.; Woody, M. C.; Omary, M.; Binkowski, F.; Fleming, G.

2012-12-01

Commercial aircraft emit substantial amounts of pollutants during their complete activity cycle that ranges from landing-and-takeoff (LTO) at airports to cruising in upper elevations of the atmosphere, and affect both air quality and climate. Since these emissions are not uniformly emitted over the earth, and have substantial temporal and spatial variability, it is vital to accurately evaluate and quantify the relative impacts of aviation emissions on ambient air quality. Regional-scale air quality modeling applications do not routinely include these aircraft emissions from all cycles. Federal Aviation Administration (FAA) has developed the Aviation Environmental Design Tool (AEDT), a software system that dynamically models aircraft performance in space and time to calculate fuel burn and emissions from gate-to-gate for all commercial aviation activity from all airports globally. To process in-flight aircraft emissions and to provide a realistic representation of these for treatment in grid-based air quality models, we have developed an interface processor called AEDTproc that accurately distributes full-flight chorded emissions in time and space to create gridded, hourly model-ready emissions input data. Unlike the traditional emissions modeling approach of treating aviation emissions as ground-level sources or processing emissions only from the LTO cycles in regional-scale air quality studies, AEDTproc distributes chorded inventories of aircraft emissions during LTO cycles and cruise activities into a time-variant 3-D gridded structure. We will present results of processed 2006 global emissions from AEDT over a continental U.S. modeling domain to support a national-scale air quality assessment of the incremental impacts of aircraft emissions on surface air quality. This includes about 13.6 million flights within the U.S. out of 31.2 million flights globally. We will focus on assessing spatio-temporal variability of these commercial aircraft emissions, and

Application of High Resolution Air-Borne Remote Sensing Observations for Monitoring NOx Emissions

NASA Astrophysics Data System (ADS)

Souri, A.; Choi, Y.; Pan, S.; Curci, G.; Janz, S. J.; Kowalewski, M. G.; Liu, J.; Herman, J. R.; Weinheimer, A. J.

2017-12-01

Nitrogen oxides (NOx=NO+NO2) are one of the air pollutants, responsible for the formation of tropospheric ozone, acid rain and particulate nitrate. The anthropogenic NOx emissions are commonly estimated based on bottom-up inventories which are complicated by many potential sources of error. One way to improve the emission inventories is to use relevant observations to constrain them. Fortunately, Nitrogen dioxide (NO2) is one of the most successful detected species from remote sensing. Although many studies have shown the capability of using space-borne remote sensing observations for monitoring emissions, the insufficient sample number and footprint of current measurements have introduced a burden to constrain emissions at fine scales. Promisingly, there are several air-borne sensors collected for NASA's campaigns providing high spatial resolution of NO2 columns. Here, we use the well-characterized NO2 columns from the Airborne Compact Atmospheric Mapper (ACAM) onboard NASA's B200 aircraft into a 1×1 km regional model to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. Firstly, in order to incorporate the data, we convert the NO2 slant column densities to vertical ones using a joint of a radiative transfer model and the 1x1 km regional model constrained by P3-B aircraft measurements. After conducting an inverse modeling method using the Kalman filter, we find the ACAM observations are resourceful at mitigating the overprediction of model in reproducing NO2 on regular days. Moreover, the ACAM provides a unique opportunity to detect an anomaly in emissions leading to strong air quality degradation that is lacking in previous works. Our study provides convincing evidence that future geostationary satellites with high spatial and temporal resolutions will give us insights into uncertainties associated with the emissions at regional scales.

Scheduled Civil Aircraft Emission Inventories for 1999: Database Development and Analysis

NASA Technical Reports Server (NTRS)

Sutkus, Donald J., Jr.; Baughcum, Steven L.; DuBois, Douglas P.

2001-01-01

This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (NO(x), CO, and hydrocarbons) for the scheduled commercial aircraft fleet for each month of 1999. Global totals of emissions and fuel burn for 1999 are compared to global totals from 1992 and 2015 databases. 1999 fuel burn, departure and distance totals for selected airlines are compared to data reported on DOT Form 41 to evaluate the accuracy of the calculations. DOT Form T-100 data were used to determine typical payloads for freighter aircraft and this information was used to model freighter aircraft more accurately by using more realistic payloads. Differences in the calculation methodology used to create the 1999 fuel burn and emissions database from the methodology used in previous work are described and evaluated.

Verification of NOx emission inventories over North Korea.

PubMed

Kim, Na Kyung; Kim, Yong Pyo; Morino, Yu; Kurokawa, Jun-ichi; Ohara, Toshimasa

2014-12-01

In this study, the top-down NOx emissions estimated from satellite observations of NO2 vertical column densities over North Korea from 1996 to 2009 were analyzed. Also, a bottom-up NOx emission inventory from REAS 1.1 from 1980 to 2005 was analyzed with several statistics. REAS 1.1 was in good agreement with the top-down approach for both trend and amount. The characteristics of NOx emissions in North Korea were quite different from other developed countries including South Korea. In North Korea, emissions from industry sector was the highest followed by transportation sector in the 1980s. However, after 1990, the NOx emissions from other sector, mainly agriculture, became the 2nd highest. Also, no emission centers such as urban areas or industrial areas were distinctively observed. Finally, the monthly NOx emissions were high during the warm season. Copyright © 2014 Elsevier Ltd. All rights reserved.

Impact of Aircraft Emissions on Reactive Nitrogen over the North Atlantic Flight Corridor Region

NASA Technical Reports Server (NTRS)

Koike, M.; Kondo, Y.; Ikeda, H.; Gregory, G. L.; Anderson, B. E.; Sachse, G. W.; Blake, D.; Liu, S. C.; Singh, H. B.; Thompson, A.

1999-01-01

The impact of aircraft emissions on reactive nitrogen in the upper troposphere (UT) and lowermost stratosphere (LS) was estimated using the NO(y)-O3 correlation obtained during the SASS Ozone and NO(x) Experiment (SONEX) carried out over the US continent and North Atlantic Flight Corridor (NAFC) region in October and November 1997. To evaluate the large scale impact, we made a reference NO(y)-O3 relationship in air masses, upon which aircraft emissions were considered to have little impact. For this purpose, the integrated input of NO(x) from aircraft into an air mass along a 10-d back trajectory (DELTA-NO(y)) was calculated based on the ANCAT/EC2 emission inventory. The excess NO(y) (dNO(y)) was calculated from the observed NO(y) and the reference NO(y)-O3 relationship. As a result, a weak positive correlation was found between the dNO(y) and DELTA-NO(y), and dNO(y) and NO(x)/NO(y) values, while no positive correlation between the dNO(y) and CO values was found, suggesting that dNO(y) values can be used as a measure of the NO(x) input from aircraft emissions. The excess NO(y) values calculated from another NO(y)-O3 reference relationship made using in-situ CN data also agreed with these dNO(y) values, within the uncertainties. At the NAFC region (45 N - 60 N), the median value of dNO(y) in the troposphere increased with altitude above 9 km and reached 70 pptv (20% of NO(y)) at 11 km. The excess NO(x) was estimated to be about half of the dNO(y) values, corresponding to 30% of the observed NO(x) level. Higher dNO(y) values were generally found in air masses where O3 = 75 - 125 ppbv, suggesting a more pronounced effect around the tropopause. The median value of dNO(y) in the stratosphere at the NAFC region at 8.5 - 11.5 km was about 120 pptv. The higher dNO(y) values in the LS were probably due to the accumulated effect of aircraft emissions, given the long residence time of affected air in the LS. Similar dNO(y) values were also obtained in air masses sampled over

Impact of aircraft emissions on reactive nitrogen over the North Atlantic Flight Corridor region

NASA Astrophysics Data System (ADS)

Koike, M.; Kondo, Y.; Ikeda, H.; Gregory, G. L.; Anderson, B. E.; Sachse, G. W.; Blake, D. R.; Liu, S. C.; Singh, H. B.; Thompson, A. M.; Kita, K.; Zhao, Y.; Sugita, T.; Shetter, R. E.; Toriyama, N.

2000-02-01

The impact of aircraft emissions on reactive nitrogen in the upper troposphere (UT) and lowermost stratosphere (LS) was estimated using the NOy-O3 correlation obtained during the Subsonic Assessment (SASS) Ozone and Nitrogen Oxide Experiment (SONEX) carried out over the U.S. continent and North Atlantic Flight Corridor (NAFC) region in October and November 1997. To evaluate the large-scale impact, we made a reference NOy-O3 relationship in air masses, upon which aircraft emissions were considered to have little impact. For this purpose, the integrated input of NOx from aircraft into an air mass along a 10-day back trajectory (ΔNOy) was calculated based on the Abatement of Nuisance Caused by Air Traffic/European Commission (ANCAT/EC2) emission inventory. The excess NOy (dNOy) was calculated from the observed NOy and the reference NOy-O3 relationship. As a result, a weak positive correlation was found between the dNOy and ΔNOy, and dNOy and NOx/NOy values, while no positive correlation between the dNOy and CO values was found, suggesting that dNOy values can be used as a measure of the NOx input from aircraft emissions. The excess NOy values calculated from another NOy-O3 reference relationship made using in situ condensation nuclei data also agreed with these dNOy values, within the uncertainties. At the NAFC region (45°N-60°N) the median value of dNOy in the troposphere increased with altitude above 9 km and reached 70 parts per trillion by volume (pptv) (20% of NOy) at 11 km. The excess NOx was estimated to be about half of the dNOy values, corresponding to 30% of the observed NOx level. Higher dNOy values were generally found in air masses where O3 = 75-125 ppbv, suggesting a more pronounced effect around the tropopause. The median value of dNOy in the stratosphere at the NAFC region at 8.5-11.5 km was about 120 pptv. The higher dNOy values in the LS were probably due to the accumulated effect of aircraft emissions, given the long residence time of affected

Spatially resolved flux measurements of NOx from London suggest significantly higher emissions than predicted by inventories.

PubMed

Vaughan, Adam R; Lee, James D; Misztal, Pawel K; Metzger, Stefan; Shaw, Marvin D; Lewis, Alastair C; Purvis, Ruth M; Carslaw, David C; Goldstein, Allen H; Hewitt, C Nicholas; Davison, Brian; Beevers, Sean D; Karl, Thomas G

2016-07-18

To date, direct validation of city-wide emissions inventories for air pollutants has been difficult or impossible. However, recent technological innovations now allow direct measurement of pollutant fluxes from cities, for comparison with emissions inventories, which are themselves commonly used for prediction of current and future air quality and to help guide abatement strategies. Fluxes of NOx were measured using the eddy-covariance technique from an aircraft flying at low altitude over London. The highest fluxes were observed over central London, with lower fluxes measured in suburban areas. A footprint model was used to estimate the spatial area from which the measured emissions occurred. This allowed comparison of the flux measurements to the UK's National Atmospheric Emissions Inventory (NAEI) for NOx, with scaling factors used to account for the actual time of day, day of week and month of year of the measurement. The comparison suggests significant underestimation of NOx emissions in London by the NAEI, mainly due to its under-representation of real world road traffic emissions. A comparison was also carried out with an enhanced version of the inventory using real world driving emission factors and road measurement data taken from the London Atmospheric Emissions Inventory (LAEI). The measurement to inventory agreement was substantially improved using the enhanced version, showing the importance of fully accounting for road traffic, which is the dominant NOx emission source in London. In central London there was still an underestimation by the inventory of 30-40% compared with flux measurements, suggesting significant improvements are still required in the NOx emissions inventory.

Aircraft Emission Inventories Projected in Year 2015 for a High Speed Civil Transport (HSCT) Universal Airline Network

NASA Technical Reports Server (NTRS)

Baughcum, Steven L.; Henderson, Stephen C.

1995-01-01

This report describes the development of a three-dimensional database of aircraft fuel burn and emissions (fuel burned, NOx, CO, and hydrocarbons) from projected fleets of high speed civil transports (HSCT's) on a universal airline network.Inventories for 500 and 1000 HSCT fleets, as well as the concurrent subsonic fleets, were calculated. The objective of this work was to evaluate the changes in geographical distribution of the HSCT emissions as the fleet size grew from 500 to 1000 HSCT's. For this work, a new expanded HSCT network was used and flights projected using a market penetration analysis rather than assuming equal penetration as was done in the earlier studies. Emission inventories on this network were calculated for both Mach 2.0 and Mach 2.4 HSCT fleets with NOx cruise emission indices of approximately 5 and 15 grams NOx/kg fuel. These emissions inventories are available for use by atmospheric scientists conducting the Atmospheric Effects of Stratospheric Aircraft (AESA) modeling studies. Fuel burned and emissions of nitrogen oxides (NOx as NO2), carbon monoxide, and hydrocarbons have been calculated on a 1 degree latitude x 1 degree longitude x 1 kilometer attitude grid and delivered to NASA as electronic files.

NOx emissions in China: historical trends and future perspectives

NASA Astrophysics Data System (ADS)

Zhao, B.; Wang, S. X.; Liu, H.; Xu, J. Y.; Fu, K.; Klimont, Z.; Hao, J. M.; He, K. B.; Cofala, J.; Amann, M.

2013-10-01

Nitrogen oxides (NOx) are key pollutants for the improvement of ambient air quality. Within this study we estimated the historical NOx emissions in China for the period 1995-2010, and calculated future NOx emissions every five years until 2030 under six emission scenarios. Driven by the fast growth of energy consumption, we estimate the NOx emissions in China increased rapidly from 11.0 Mt in 1995 to 26.1 Mt in 2010. Power plants, industry and transportation were major sources of NOx emissions, accounting for 28.4%, 34.0%, and 25.4% of the total NOx emissions in 2010, respectively. Two energy scenarios, a business as usual scenario (BAU) and an alternative policy scenario (PC), were developed to project future energy consumption. In 2030, total energy consumption is projected to increase by 64% and 27% from 2010 level respectively. Three sets of end-of-pipe pollution control measures, including baseline, progressive, and stringent control case, were developed for each energy scenario, thereby constituting six emission scenarios. By 2030, the total NOx emissions are projected to increase (compared to 2010) by 36% in the baseline while policy cases result in reduction up to 61% in the most ambitious case with stringent control measures. More than a third of the reduction achieved by 2030 between least and most ambitious scenario comes from power sector, and more than half is distributed equally between industry and transportation sectors. Selective catalytic reduction dominates the NOx emission reductions in power plants, while life style changes, control measures for industrial boilers and cement production are major contributors to reductions in industry. Timely enforcement of legislation on heavy-duty vehicles would contribute significantly to NOx emission reductions. About 30% of the NOx emission reduction in 2020 and 40% of the NOx emission reduction in 2030 could be treated as the ancillary benefit of energy conservation. Sensitivity analysis was conducted to

Status of NASA aircraft engine emission reduction and upper atmosphere measurement programs

NASA Technical Reports Server (NTRS)

Rudey, R. A.; Lezberg, E. A.

1976-01-01

Advanced emission reduction techniques for five existing aircraft gas turbine engines are evaluated. Progress made toward meeting the 1979 EPA standards in rig tests of combustors for the five engines is reported. Results of fundamental combustion studies suggest the possibility of a new generation of jet engine combustor technology that would reduce oxides-of-nitrogen (NOx) emissions far below levels currently demonstrated in the engine-related programs. The Global Air Sampling Program (GAS) is now in full operation and is providing data on constituent measurements of ozone and other minor upper-atmosphere species related to aircraft emissions.

LOW-CONCENTRATION NOX EMISSIONS MEASUREMENT

EPA Science Inventory

The paper gives results of a recent series of low-concentration nitrogen oxides (NOx) emission measurements, made by Midwest Research Institute (MRI) during U.S. EPA-sponsored Environmental Technology Verification (ETV) test of a NOx control system called Xonon (TM) Cool Combust...

Avco Lycoming/NASA contract status. [on reduction of emissions from aircraft piston engines

NASA Technical Reports Server (NTRS)

Duke, L. C.

1976-01-01

The standards promulgated by the Environmental Protection Agency (EPA) for carbon monoxide (CO), unburned hydrocarbon (HC), and oxides-of-nitrogen (NOx) emissions were the basis in a study of ways to reduce emissions from aircraft piston engines. A variable valve timing system, ultrasonic fuel atomization, and ignition system changes were postulated.

Combining active and passive remote sensing from research aircraft with atmospheric models to evaluate NOx emission fluxes and O3 formation in the Los Angeles Megacity

NASA Astrophysics Data System (ADS)

Baidar, Sunil; Oetjen, Hilke; Senff, Christoph; Alvarez, Raul, II; Hardesty, Michael; Langford, Andrew; Kim, Si-Wan; Trainer, Michael; Volkamer, Rainer

2013-04-01

Ozone (O3) and nitrogen dioxide (NO2) are two important components of air pollution. We have measured vertical column amounts of NO2, and vertical profiles of O3 and wind speed by means of measurements of solar stray light by CU Airborne MAX-DOAS, and active remote sensing using the NOAA TOPAZ lidar, and the University of Leeds Doppler lidar aboard the NOAA Twin Otter research aircraft. A total of 52 flights (up to 4 hours each) were carried out between May 19 and July 19 2010 during the CalNex and CARES field campaigns. These flights cover most of California. The boundary layer height was measured by TOPAZ lidar, and trace gas concentrations of NO2 and O3 were integrated over boundary layer height. These column integrated quantities are then combined with direct wind speed measurements to quantify directly the pollutant flux across the boundary, as defined by the flight track. By tracking the pollution fluxes during transects that are flown upwind and in various distances downwind of a NOx emission source, the NOx emission rate, and the ozone formation rate are quantified. These pollutant fluxes are calculated here for the first time exclusively based on measurements (i.e., without need to infer wind speed from a model). These fluxes provide constraints to quantify localized NOx emissions, and are being compared with WRF-Chem model simulations.

Modelling NOx emissions of single droplet combustion

NASA Astrophysics Data System (ADS)

Moesl, Klaus G.; Schwing, Joachim E.; Sattelmayer, Thomas

2012-02-01

An approach for modelling and simulation of the generation of nitrogen oxide (NOx) in the gas phase surrounding single burning droplets is presented. Assuming spherical symmetry (no gravity, no forced convection), the governing equations are derived first. Then simplifications are introduced and it is proven that they are appropriate. The influences of the initial droplet diameter, the ambient conditions, and the droplet pre-vapourisation on NOx are investigated. The fuel of choice is n-decane (C10H22) as it resembles kerosene and diesel fuel best, and the complexity of the reaction mechanism is manageable. Combinations of C10H22 mechanisms and well-established NOx kinetics are evaluated in detail and validated for their applicability in the context of this work. The conducted simulations of droplet combustion in an atmosphere of hot exhaust gas show that NOx formation (by mass of fuel) increases linearly with the droplet diameter. There is a trade-off between available oxygen and ambient temperature. Increasing the equivalence ratio of the exhaust gas leads to higher NOx emissions in the very lean regime, but to lower emissions if the equivalence ratio exceeds 0.85. Pre-vapourisation of fuel at ambient conditions becomes beneficial with respect to NOx emissions only if the degree of vapourisation is above a minimum limit. If less fuel is vapourised before ignition, the NOx emissions remain almost unaffected.

Near-field commercial aircraft contribution to nitrogen oxides by engine, aircraft type, and airline by individual plume sampling.

PubMed

Carslaw, David C; Ropkins, Karl; Laxen, Duncan; Moorcroft, Stephen; Marner, Ben; Williams, Martin L

2008-03-15

Nitrogen oxides (NOx) concentrations were measured in individual plumes from aircraft departing on the northern runway at Heathrow Airport in west London. Over a period of four weeks 5618 individual plumes were sampled by a chemiluminescence monitor located 180 m from the runway. Results were processed and matched with detailed aircraft movement and aircraft engine data using chromatographic techniques. Peak concentrations associated with 29 commonly used engines were calculated and found to have a good relationship with N0x emissions taken from the International Civil Aviation Organization (ICAO) databank. However, it is found that engines with higher reported NOx emissions result in proportionately lower NOx concentrations than engines with lower emissions. We show that it is likely that aircraft operational factors such as takeoff weight and aircraftthrust setting have a measurable and important effect on concentrations of N0x. For example, NOx concentrations can differ by up to 41% for aircraft using the same airframe and engine type, while those due to the same engine type in different airframes can differ by 28%. These differences are as great as, if not greater than, the reported differences in NOx emissions between different engine manufacturers for engines used on the same airframe.

The effect of incomplete fuel-air mixing on the lean blowout limit, lean stability limit and NO(x) emissions in lean premixed gas turbine combustors

NASA Technical Reports Server (NTRS)

Shih, W.-P.; Lee, J. G.; Santavicca, D. A.

1994-01-01

Gas turbine engines for both land-based and aircraft propulsion applications are facing regulations on NOx emissions which cannot be met with current combustor technology. A number of alternative combustor strategies are being investigated which have the potential capability of achieving ultra-low NOx emissions, including lean premixed combustors, direct injection combustors, rich burn-quick quench-lean burn combustors and catalytic combustors. The research reported in this paper addresses the effect of incomplete fuel-air mixing on the lean limit performance and the NOx emissions characteristics of lean premixed combustors.

Characterization of NOx, SO2, ethene, and propene from industrial emission sources in Houston, Texas

NASA Astrophysics Data System (ADS)

Washenfelder, R. A.; Trainer, M.; Frost, G. J.; Ryerson, T. B.; Atlas, E. L.; de Gouw, J. A.; Flocke, F. M.; Fried, A.; Holloway, J. S.; Parrish, D. D.; Peischl, J.; Richter, D.; Schauffler, S. M.; Walega, J. G.; Warneke, C.; Weibring, P.; Zheng, W.

2010-08-01

The Houston-Galveston-Brazoria urban area contains industrial petrochemical sources that emit volatile organic compounds and nitrogen oxides, resulting in rapid and efficient ozone production downwind. During September to October 2006, the NOAA WP-3D aircraft conducted research flights as part of the second Texas Air Quality Study (TexAQS II). We use measurements of NOx, SO2, and speciated hydrocarbons from industrial sources in Houston to derive source emission ratios and compare these to emission inventories and the first Texas Air Quality Study (TexAQS) in 2000. Between 2000 and 2006, NOx/CO2 emission ratios changed by an average of -29% ± 20%, while a significant trend in SO2/CO2 emission ratios was not observed. We find that high hydrocarbon emissions are routine for the isolated petrochemical facilities. Ethene (C2H4) and propene (C3H6) are the major contributors to ozone formation based on calculations of OH reactivity for organic species including C2-C10 alkanes, C2-C5 alkenes, ethyne, and C2-C5 aldehydes and ketones. Measured ratios of C2H4/NOx and C3H6/NOx exceed emission inventory values by factors of 1.4-20 and 1-24, respectively. We examine trends in C2H4/NOx and C3H6/NOx ratios between 2000 and 2006 for the isolated petrochemical sources and estimate a change of -30% ± 30%, with significant day-to-day and within-plume variability. Median ambient mixing ratios of ethene and propene in Houston show decreases of -52% and -48%, respectively, between 2000 and 2006. The formaldehyde, acetaldehyde, and peroxyacetyl nitrate products produced by alkene oxidation are observed downwind, and their time evolution is consistent with the rapid photochemistry that also produces ozone.

Measurements of aircraft emissions indices at airports passive remote sensing

NASA Astrophysics Data System (ADS)

Schaefer, Klaus; Jahn, Carsten; Sturm, Peter J.; Lechner, Bernhard; Bacher, Michael

2003-04-01

The emission indices of aircraft engine exhausts to calculate precisely the emissions inventories of airports are not available up to now from measurements taken under operating conditions. To determine these data no installations nearby or behind the aircraft are possible at airports. That's why measurements by FTIR emission spectrometry were performed by the IMK-IFU with a spectrometer installed in a van and with total measurement time at one thrust level of about 1 minute to determine CO, NO and CO2. The FTIR instrument telescope was aligned to the engine nozzle exit of standing aircraft. A DOAS and a FTIR spectrometer with globar were used for simultaneous open-path measurements of NO, NO2, CO, CO2 and speciated hydrocarbons behind the aircraft by the TUG-VKMB. Measurement results at the airports Frankfurt/Main, London-Heathrow and Vienna are presented. The methods are evaluated by comparing CO emission indices from passive measurements with open-path data. The measured emission indices of CO show slightly higher values than the International Civil Aviation Organisation data sheets but less values for NOx emissions. A fruitful co-operation with the airlines AUA, BA and DLH as well as the airport authorities in Vienna and London-Heathrow supported this work which is financed from EC.

An Evaluation of Aircraft Emissions Inventory Methodology by Comparisons with Reported Airline Data

NASA Technical Reports Server (NTRS)

Daggett, D. L.; Sutkus, D. J.; DuBois, D. P.; Baughcum, S. L.

1999-01-01

This report provides results of work done to evaluate the calculation methodology used in generating aircraft emissions inventories. Results from the inventory calculation methodology are compared to actual fuel consumption data. Results are also presented that show the sensitivity of calculated emissions to aircraft payload factors. Comparisons of departures made, ground track miles flown and total fuel consumed by selected air carriers were made between U.S. Dept. of Transportation (DOT) Form 41 data reported for 1992 and results of simplified aircraft emissions inventory calculations. These comparisons provide an indication of the magnitude of error that may be present in aircraft emissions inventories. To determine some of the factors responsible for the errors quantified in the DOT Form 41 analysis, a comparative study of in-flight fuel flow data for a specific operator's 747-400 fleet was conducted. Fuel consumption differences between the studied aircraft and the inventory calculation results may be attributable to several factors. Among these are longer flight times, greater actual aircraft weight and performance deterioration effects for the in-service aircraft. Results of a parametric study on the variation in fuel use and NOx emissions as a function of aircraft payload for different aircraft types are also presented.

77 FR 36341 - Control of Air Pollution From Aircraft and Aircraft Engines; Emission Standards and Test Procedures

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-18

...EPA is adopting several new aircraft engine emission standards for oxides of nitrogen (NOX), compliance flexibilities, and other regulatory requirements for aircraft turbofan or turbojet engines with rated thrusts greater than 26.7 kilonewtons (kN). We also are adopting certain other requirements for gas turbine engines that are subject to exhaust emission standards as follows. First, we are clarifying when the emission characteristics of a new turbofan or turbojet engine model have become different enough from its existing parent engine design that it must conform to the most current emission standards. Second, we are establishing a new reporting requirement for manufacturers of gas turbine engines that are subject to any exhaust emission standard to provide us with timely and consistent emission- related information. Third, and finally, we are establishing amendments to aircraft engine test and emissions measurement procedures. EPA actively participated in the United Nations' International Civil Aviation Organization (ICAO) proceedings in which most of these requirements were first developed. These regulatory requirements have largely been adopted or are actively under consideration by its member states. By adopting such similar standards, therefore, the United States maintains consistency with these international efforts.

Correlating Engine NOx Emission with Biodiesel Composition

NASA Astrophysics Data System (ADS)

Jeyaseelan, Thangaraja; Mehta, Pramod Shankar

2017-06-01

Biodiesel composition comprising of saturated and unsaturated fatty acid methyl esters has a significant influence on its properties and hence the engine performance and emission characteristics. This paper proposes a comprehensive approach for composition-property-NOx emission analysis for biodiesel fuels and highlights the pathways responsible for such a relationship. Finally, a procedure and a predictor equation are developed for the assessment of biodiesel NOx emission from its composition details.

NOx Emissions from Oil and Gas Production in the North Sea

NASA Astrophysics Data System (ADS)

Lee, J. D.; Foulds, A.; Purvis, R.; Vaughan, A. R.; Carslaw, D.; Lewis, A. C.

2015-12-01

North Sea oil is a mixture of hydrocarbons, comprising liquid petroleum and natural gas, produced from petroleum reservoirs beneath the North Sea. As of January 2015, the North Sea is the world's most active offshore drilling region with 173 rigs drilling. During the summer of 2015, a series of survey flights took place on the UKs FAAM BAe 146 research aircraft with the primary aim to assess background methane (and other hydrocarbons) levels in the drilling areas of the North Sea. Also measured were Nitrogen Oxides (NO and NO2), which are emitted from almost all combustion processes and are a key air pollutant, both directly and as a precursor to ozone (O3). The oil and gas platforms in the North Sea are often manned and require significant power generation and support vessels for their continued operation, processes that potentially emit significant amounts of NOx into an otherwise relative clean environment. During these flights we were able to measure the NO­­­x (and any subsequently produced O3) emitted from specific rigs, as well as the NOx levels in the wider North Sea oil and gas production region (see figure for example). NOx mixing ratios of <10 ppbv were frequently observed in plumes, with significant perturbation to the wider North Sea background levels. NOx emissions from the rigs are point sources within the UKs National Atmospheric Emission Inventory (NAEI) and the measurements taken in plumes from individual rigs are used to assess the accuracy of these estimates.

Airborne emission measurements of SO2, NOx and particles from individual ships using sniffer technique

NASA Astrophysics Data System (ADS)

Beecken, J.; Mellqvist, J.; Salo, K.; Ekholm, J.; Jalkanen, J.-P.

2013-12-01

A dedicated system for airborne ship emission measurements of SO2, NOx and particles has been developed and used from several small aircrafts. The system has been adapted for fast response measurements at 1 Hz and the use of several of the instruments is unique. The uncertainty of the given data is about 20.3% for SO2 and 23.8% for NOx emission factors. Multiple measurements of 158 ships measured from the air on the Baltic and North Sea during 2011 and 2012 show emission factors of 18.8 ± 6.5 g kgfuel-1, 66.6 ± 23.4 g kgfuel-1, and 1.8 ± 1.3 × 1016 particles kgfuel-1 for SO2, NOx and particle number respectively. The particle size distributions were measured for particle diameters between 15 and 560 nm. The mean sizes of the particles are between 50 and 62 nm dependent on the distance to the source and the number size distribution is mono-modal. Concerning the sulfur fuel content 85% of the ships comply with the IMO limits. The sulfur emission has decreased compared to earlier measurements from 2007 to 2009. The presented method can be implemented for regular ship compliance monitoring.

Commercial aircraft engine emissions characterization of in-use aircraft at Hartsfield-Jackson Atlanta International Airport.

PubMed

Herndon, Scott C; Jayne, John T; Lobo, Prem; Onasch, Timothy B; Fleming, Gregg; Hagen, Donald E; Whitefield, Philip D; Miake-Lye, Richard C

2008-03-15

The emissions from in-use commercial aircraft engines have been analyzed for selected gas-phase species and particulate characteristics using continuous extractive sampling 1-2 min downwind from operational taxi- and runways at Hartsfield-Jackson Atlanta International Airport. Using the aircraft tail numbers, 376 plumes were associated with specific engine models. In general, for takeoff plumes, the measured NOx emission index is lower (approximately 18%) than that predicted by engine certification data corrected for ambient conditions. These results are an in-service observation of the practice of "reduced thrust takeoff". The CO emission index observed in ground idle plumes was greater (up to 100%) than predicted by engine certification data for the 7% thrust condition. Significant differences are observed in the emissions of black carbon and particle number among different engine models/technologies. The presence of a mode at approximately 65 nm (mobility diameter) associated with takeoff plumes and a smaller mode at approximately 25 nm associated with idle plumes has been observed. An anticorrelation between particle mass loading and particle number concentration is observed.

Vehicle NOx emission plume isotopic signatures: Spatial variability across the eastern United States

NASA Astrophysics Data System (ADS)

Miller, David J.; Wojtal, Paul K.; Clark, Sydney C.; Hastings, Meredith G.

2017-04-01

On-road vehicle nitrogen oxide (NOx) sources currently dominate the U.S. anthropogenic emission budgets, yet vehicle NOx emissions have uncertain contributions to oxidized nitrogen (N) deposition patterns. Isotopic signatures serve as a potentially valuable observational tool to trace source contributions to NOx chemistry and N deposition, yet in situ emission signatures are underconstrained. We characterize the spatiotemporal variability of vehicle NOx emission isotopic signatures (δ15N-NOx) representative of U.S. vehicle fleet-integrated emission plumes. A novel combination of on-road mobile and stationary urban measurements is performed using a field and laboratory-verified technique for actively capturing NOx in solution to quantify δ15N-NOx at hourly resolution. On-road δ15N-NOx upwind of Providence, RI, ranged from -7 to -3‰. Simultaneous urban background δ15N-NOx observations showed comparable range and variations with on-road measurements, suggesting that vehicles dominate NOx emissions in the Providence area. On-road spatial δ15N-NOx variations of -9 to -2‰ were observed under various driving conditions in six urban metropolitan areas and rural interstate highways during summer and autumn in the U.S. Northeast and Midwest. Although isotopic signatures were insensitive to on-road driving mode variations, statistically significant correlations were found between δ15N-NOx and NOx emission factor extremes associated with heavy diesel emitter contributions. Overall, these results constrain an isotopic signature of fleet-integrated roadway NOx emission plumes, which have important implications for distinguishing vehicle NOx from other sources and tracking emission contributions to NOx chemistry and N deposition.

40 CFR 75.70 - NOX mass emissions provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... subpart to the extent that compliance is required by an applicable State or federal NOX mass emission...) For purposes of this subpart, the term “affected unit” shall mean any unit that is subject to a State...” shall mean the permitting authority under an applicable State or federal NOX mass emission reduction...

NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

NASA Technical Reports Server (NTRS)

He, Zhuohui J.; Chang, Clarence T.; Follen, Caitlin E.

2015-01-01

Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions. This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio (?) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66% reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50% of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

Emissions of HC, CO, NOx, CO2, and SO2 from civil aviation in China in 2010

NASA Astrophysics Data System (ADS)

Fan, Weiyi; Sun, Yifei; Zhu, Tianle; Wen, Yi

2012-09-01

Civil aviation in China has developed rapidly in recent years, and the effects of civil aviation emissions on the atmospheric environment should not be neglected. The establishment of emission inventories of atmospheric pollutants from civil aviation contributes to related policy formation and pollution control. According to the 2010's China flight schedules, aircraft/engine combination information and revised emission indices from the International Civil Aviation Organization emission data bank based on meteorological data, the fuel consumption and HC, CO, NOx, CO2, SO2 emissions from domestic flights of civil aviation in China (excluding Taiwan Province) in 2010 are estimated in this paper. The results show that fuel consumption in 2010 on domestic flights in China is 12.12 million tons (metric tons), HC, CO, NOx, CO2 and SO2 emissions are 4600 tons, 39,700 tons, 154,100 tons, 38.21 million tons and 9700 tons, respectively. The fuel consumption and pollutant emissions of China Southern Airline are responsible for the largest national proportion of each, accounting for 27% and 25-28%, respectively.

Estimating Lightning NOx Emissions for Regional Air Quality Modeling

NASA Astrophysics Data System (ADS)

Holloway, T.; Scotty, E.; Harkey, M.

2014-12-01

Lightning emissions have long been recognized as an important source of nitrogen oxides (NOx) on a global scale, and an essential emission component for global atmospheric chemistry models. However, only in recent years have regional air quality models incorporated lightning NOx emissions into simulations. The growth in regional modeling of lightning emissions has been driven in part by comparisons with satellite-derived estimates of column NO2, especially from the Ozone Monitoring Instrument (OMI) aboard the Aura satellite. We present and evaluate a lightning inventory for the EPA Community Multiscale Air Quality (CMAQ) model. Our approach follows Koo et al. [2010] in the approach to spatially and temporally allocating a given total value based on cloud-top height and convective precipitation. However, we consider alternate total NOx emission values (which translate into alternate lightning emission factors) based on a review of the literature and performance evaluation against OMI NO2 for July 2007 conditions over the U.S. and parts of Canada and Mexico. The vertical distribution of lightning emissions follow a bimodal distribution from Allen et al. [2012] calculated over 27 vertical model layers. Total lightning NO emissions for July 2007 show the highest above-land emissions in Florida, southeastern Texas and southern Louisiana. Although agreement with OMI NO2 across the domain varied significantly depending on lightning NOx assumptions, agreement among the simulations at ground-based NO2 monitors from the EPA Air Quality System database showed no meaningful sensitivity to lightning NOx. Emissions are compared with prior studies, which find similar distribution patterns, but a wide range of calculated magnitudes.

Real Driving NOx Emissions of European Trucks and Detection of Manipulated Emission Systems

NASA Astrophysics Data System (ADS)

Pöhler, Denis; Adler, Tim; Krufczik, Chsristopher; Horbanski, Martin; Lampel, Johannes; Platt, Ulrich

2017-04-01

Nitrogen dioxide (NO2) is the most problematic pollutant in Europe and many other countries. NO2 has a negative impact for the health and the environment, and in most European cities the currently allowed mean annual limit of 40μg/m3 is exceeded. Vehicles, especially Diesel, are the most relevant source. They emit NOx (NO + NO2), and NO can also be converted to NO2 in the atmosphere. Thus vehicle NOx emissions are regulated in the EU with the EURO Norm Standard (e.g. EURO 6 since 1.1.2013 for trucks with 400mg/kWh). Trucks achieve these low emissions with complex emission after treatment systems. All EURO 6 trucks and almost all EURO 5 trucks use the SCR system consuming AdBlue to reduce the NOx emissions. Since the diesel emission scandal for cars, it is well known that real driving emissions (RDE) can be several times higher that the EURO Norm Standard. The main problem is that RDE are only randomly investigated. Here we present a study of NOx RDE of more than 250 randomly chosen trucks on German highways. The measurements were performed with a newly developed mobile NOx-ICAD + CO2 -instrument applying the plume chasing measurement principle, where the pollutants are investigated in the emission plume and were converted to emission factors to be compared to the EURO standard. For most trucks the brand, the model name, the country of registration and its EURO class could be determined and used in a statistical analysis. The observed NOx emission data show that typical truck RDE are in the range of the expected EURO Norm or slightly higher. However, almost every fourth truck from Eastern Europe show emissions much higher that the EURO Norm. This was not observed for German trucks. As the emissions increase up to a factor of 5 to 10 these view trucks contribute significantly to the air pollution. These high emissions clearly indicate a defect emission treatment system. Most likely it indicates illegal manipulated emissions systems where the AdBlue injection is

NOx Emissions from Diesel Passenger Cars Worsen with Age.

PubMed

Chen, Yuche; Borken-Kleefeld, Jens

2016-04-05

Commonly, the NOx emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NOx unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NOx emissions from all cars and light commercial vehicles in European emission inventories increase by 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. We suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles.

Characteristics of NOx emission from Chinese coal-fired power plants equipped with new technologies

NASA Astrophysics Data System (ADS)

Ma, Zizhen; Deng, Jianguo; Li, Zhen; Li, Qing; Zhao, Ping; Wang, Liguo; Sun, Yezhu; Zheng, Hongxian; Pan, Li; Zhao, Shun; Jiang, Jingkun; Wang, Shuxiao; Duan, Lei

2016-04-01

Coal combustion in coal-fired power plants is one of the important anthropogenic NOx sources, especially in China. Many policies and methods aiming at reducing pollutants, such as increasing installed capacity and installing air pollution control devices (APCDs), especially selective catalytic reduction (SCR) units, could alter NOx emission characteristics (NOx concentration, NO2/NOx ratio, and NOx emission factor). This study reported the NOx characteristics of eight new coal-fired power-generating units with different boiler patterns, installed capacities, operating loads, and coal types. The results showed that larger units produced less NOx, and anthracite combustion generated more NOx than bitumite and lignite combustion. During formation, the NOx emission factors varied from 1.81 to 6.14 g/kg, much lower than those of older units at similar scales. This implies that NOx emissions of current and future units could be overestimated if they are based on outdated emission factors. In addition, APCDs, especially SCR, greatly decreased NOx emissions, but increased NO2/NOx ratios. Regardless, the NO2/NOx ratios were lower than 5%, in accordance with the guidelines and supporting the current method for calculating NOx emissions from coal-fired power plants that ignore NO2.

NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

NASA Technical Reports Server (NTRS)

He, Zhuohui J.; Chang, Clarence T.; Follen, Caitlin E.

2014-01-01

Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions. This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio (phi) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66 percent reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50 percent of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

NASA Technical Reports Server (NTRS)

He, Zhuohui Joe; Chang, Clarence T.; Follen, Caitlin E.

2015-01-01

Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions.This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio(theta) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66 reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50 of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

NASA Technical Reports Server (NTRS)

He, Zhuohui J.; Chang, Clarence T.; Follen, Caitlin E.

2014-01-01

Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions. This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio (?) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66 percent reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50 percent of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

76 FR 45011 - Control of Air Pollution From Aircraft and Aircraft Engines; Proposed Emission Standards and Test...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-27

...This action proposes several new NOX emission standards, compliance flexibilities, and other regulatory requirements for aircraft turbofan or turbojet engines with rated thrusts greater than 26.7 kilonewtons (kN). We also are proposing certain other requirements for gas turbine engines that are subject to exhaust emission standards. First, we are proposing to clarify when the emission characteristics of a new turbofan or turbojet engine model have become different enough from its existing parent engine design that it must conform to the most current emission standards. Second, we are proposing a new reporting requirement for manufacturers of gas turbine engines that are subject to any exhaust emission standard to provide us with timely and consistent emission-related information. Third, and finally, we are proposing amendments to aircraft engine test and emissions measurement procedures. EPA actively participated in the United Nation's International Civil Aviation Organization (ICAO) proceedings in which most of these proposed requirements were first developed. These proposed regulatory requirements have largely been adopted or are actively under consideration by its member states. By adopting such similar standards, therefore, the United States will maintain consistency with these international efforts.

40 CFR 75.19 - Optional SO2, NOX, and CO2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (or group of identical units) equipped with SCR (or SNCR) and uses dry low-NOX technology to control... with add-on NOX emission controls, and for units that use dry low-NOX technology, the owner or operator... mass emissions unit that uses dry low-NOX premix technology to control NOX emissions, proper operation...

Methodology for Airborne Quantification of NOx fluxes over Central London and Comparison to Emission Inventories

NASA Astrophysics Data System (ADS)

Vaughan, A. R.; Lee, J. D.; Lewis, A. C.; Purvis, R.; Carslaw, D.; Misztal, P. K.; Metzger, S.; Beevers, S.; Goldstein, A. H.; Hewitt, C. N.; Shaw, M.; Karl, T.; Davison, B.

2015-12-01

The emission of pollutants is a major problem in today's cities. Emission inventories are a key tool for air quality management, with the United Kingdom's National and London Atmospheric Emission Inventories (NAEI & LAEI) being good examples. Assessing the validity of such inventoried is important. Here we report on the technical methodology of matching flux measurements of NOx over a city to inventory estimates. We used an eddy covariance technique to directly measure NOx fluxes from central London on an aircraft flown at low altitude. NOx mixing ratios were measured at 10 Hz time resolution using chemiluminescence (to measure NO) and highly specific photolytic conversion of NO2 to NO (to measure NO2). Wavelet transformation was used to calculate instantaneous fluxes along the flight track for each flight leg. The transformation allows for both frequency and time information to be extracted from a signal, where we quantify the covariance between the de-trended vertical wind and concentration to derive a flux. Comparison between the calculated fluxes and emission inventory data was achieved using a footprint model, which accounts for contributing source. Using both a backwards lagrangian model and cross-wind dispersion function, we find the footprint extent ranges from 5 to 11 Km in distance from the sample point. We then calculate a relative weighting matrix for each emission inventory within the calculated footprint. The inventories are split into their contributing source sectors with each scaled using up to date emission factors, giving a month; day and hourly scaled estimate which is then compared to the measurement.

Reconciling NOx emissions reductions and ozone trends in ...

EPA Pesticide Factsheets

Dynamic evaluation seeks to assess the ability of photochemical models to replicate changes in air quality as emissions and other conditions change. When a model fails to replicate an observed change, a key challenge is to discern whether the discrepancy is caused by errors in meteorological simulations, errors in emission magnitudes and changes, or inaccurate responses of simulated pollutant concentrations to emission changes. In this study, the Community Multiscale Air Quality (CMAQ) model is applied to simulate the ozone (O3) change after the NOx SIP Call and mobile emission controls substantially reduced nitrogen oxides (NOx) emissions in the eastern U.S. from 2002 to 2006. For both modeled and observed O3, changes in episode average daily maximal 8-h O3 were highly correlated (R2 = 0.89) with changes in the 95th percentile, although the magnitudes of reductions increased nonlinearly at high percentile O3 concentrations. Observed downward changes in mean NOx (−11.6 to −2.5 ppb) and 8-h O3 (−10.4 to −4.7 ppb) concentrations in metropolitan areas in the NOx SIP Call region were under-predicted by 31%–64% and 26%–66%, respectively. The under-predicted O3 improvements in the NOx SIP Call region could not be explained by adjusting for temperature biases in the meteorological input, or by considering uncertainties in the chemical reaction rate constants. However, the under-prediction in O3 improvements could be alleviated by 5%–31% by constraining NO

NOX EMISSION CONTROL OPTIONS FOR COAL-FIRED ELECTRIC UTILITY BOILERS

EPA Science Inventory

The paper reviews NOx control options for coal-fired electric utility boilers. (NOTE: Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, revision of the New Source Performance Standards (NSPS) for NOx emissions from utility sources, and Ozone Transpor...

NO and NO2 emission ratios measured from in-use commercial aircraft during taxi and takeoff.

PubMed

Herndon, Scott C; Shorter, Joanne H; Zahniser, Mark S; Nelson, David D; Jayne, John; Brown, Robert C; Miake-Lye, Richard C; Waitz, Ian; Silva, Phillip; Lanni, Thomas; Demerjian, Ken; Kolb, Charles E

2004-11-15

In August 2001, the Aerodyne Mobile Laboratory simultaneously measured NO, NO2, and CO2 within 350 m of a taxiway and 550 m of a runway at John F. Kennedy Airport. The meteorological conditions were such that taxi and takeoff plumes from individual aircraft were clearly resolved against background levels. NO and NO2 concentrations were measured with 1 s time resolution using a dual tunable infrared laser differential absorption spectroscopy instrument, utilizing an astigmatic multipass Herriott cell. The CO2 measurements were also obtained at 1 s time resolution using a commercial non-dispersive infrared absorption instrument. Plumes were measured from over 30 individual planes, ranging from turbo props to jumbo jets. NOx emission indices were determined by examining the correlation between NOx (NO + NO2) and CO2 during the plume measurements. Several aircraft tail numbers were unambiguously identified, allowing those specific airframe/engine combinations to be determined. The resulting NOx emission indices from positively identified in-service operating airplanes are compared with the published International Civil Aviation Organization engine certification test database collected on new engines in certification test cells.

Parse, simulation, and prediction of NOx emission across the Midwestern United States

NASA Astrophysics Data System (ADS)

Fang, H.; Michalski, G. M.; Spak, S.

2017-12-01

Accurately constraining N emissions in space and time has been a challenge for atmospheric scientists. It has been suggested that 15N isotopes may be a way of tracking N emission sources across various spatial and temporal scales. However, the complexity of multiple N sources that can quickly change in intensity has made this a difficult problem. We have used a SMOKE emission model to parse NOx emission across the Midwestern United States for a one-year simulation. An isotope mass balance methods was used to assign 15N values to road, non-road, point, and area sources. The SMOKE emissions and isotope mass balance were then combined to predict the 15N of NOx emissions (Figure 1). This ^15N of NOx emissions model was then incorporated into CMAQ to assess the role of transport and chemistry would impact the 15N value of NOx due to mixing and removal processes. The predicted 15N value of NOx was compared to those in recent measurements of NOx and atmospheric nitrate.

Aircraft gas turbine low-power emissions reduction technology program

NASA Technical Reports Server (NTRS)

Dodds, W. J.; Gleason, C. C.; Bahr, D. W.

1978-01-01

Advanced aircraft turbine engine combustor technology was used to reduce low-power emissions of carbon monoxide and unburned hydrocarbons to levels significantly lower than those which were achieved with current technology. Three combustor design concepts, which were designated as the hot-wall liner concept, the recuperative-cooled liner concept, and the catalyst converter concept, were evaluated in a series of CF6-50 engine size 40 degree-sector combustor rig tests. Twenty-one configurations were tested at operating conditions spanning the design condition which was an inlet temperature and pressure of 422 K and 304 kPa, a reference velocity of 23 m/s and a fuel-air-ration of 10.5 g/kg. At the design condition typical of aircraft turbine engine ground idle operation, the best configurations of all three concepts met the stringent emission goals which were 10, 1, and 4 g/kg for CO, HC, and Nox, respectively.

NOx emissions from a Central California dairy

NASA Astrophysics Data System (ADS)

Hasson, Alam S.; Ogunjemiyo, Segun O.; Trabue, Steven; Ashkan, Shawn; Scoggin, Kenwood; Steele, Julie; Olea, Catalina; Middala, Srikar; Vu, Kennedy; Scruggs, Austen; Addala, Laxmi R.; Nana, Lucien

2013-05-01

Concentrations of NOx (NO + NO2) were monitored downwind from a Central California dairy facility during 2011 and 2012. NOx concentrations at the dairy were significantly higher than the background levels during August 2011 primarily due to the presence of elevated NO, but were indistinguishable from background concentrations during January and April 2012. A Gaussian plume model (AERMOD) and a Lagrangian back trajectory model (Wind Trax) were used to estimate the flux of NO from the dairy during August 2011 with the assumption that emissions were primarily from animal feed. NO emissions from silage were also directly measured from feed to provide additional insight into the sources. Isolation flux chamber measurements imply an NO flux from the feed of about 1.3 × 10-3 g m-2 h-1, but these relatively low fluxes are inconsistent with the elevated NO concentrations observed during August 2011. This implies that either the flux chamber method grossly underestimates the true NO emissions from feed, or that most of the ambient NO measured at the dairy is from other sources. Emissions from farm machinery may account for the NO concentrations observed. Animal feed thus appears to be a small contributor to NOx emissions within Central California.

The challenge to NOx emission control for heavy-duty diesel vehicles in China

NASA Astrophysics Data System (ADS)

Wu, Y.; Zhang, S. J.; Li, M. L.; Ge, Y. S.; Shu, J. W.; Zhou, Y.; Xu, Y. Y.; Hu, J. N.; Liu, H.; Fu, L. X.; He, K. B.; Hao, J. M.

2012-10-01

China's new "Twelfth Five-Year Plan" set a target for total NOx emission reduction of 10% for the period of 2011-2015. Heavy-duty diesel vehicles (HDDVs) have been considered a major contributor to NOx emissions in China. Beijing initiated a comprehensive vehicle test program in 2008. This program included a sub-task for measuring on-road emission profiles of hundreds of HDDVs using portable emission measurement systems (PEMS). The major finding is that neither the on-road distance-specific (g km-1) nor brake-specific (g kWh-1) NOx emission factors for diesel buses and heavy-duty diesel trucks improved in most cases as emission standards became more stringent. For example, the average NOx emission factors for Euro II, Euro III and Euro IV buses are 11.3 ± 3.3 g km-1, 12.5 ± 1.3 g km-1, and 11.8 ± 2.0 g km-1, respectively. No statistically significant difference in NOx emission factors was observed between Euro II and III buses. Even for Euro IV buses equipped with SCR systems, the NOx emission factors are similar to Euro III buses. The data regarding real-time engine performance of Euro IV buses suggest the engine certification cycles did not reflect their real-world operating conditions. These new on-road test results indicate that previous estimates of total NOx emissions for HDDV fleet may be significantly underestimated. The new estimate in total NOx emissions for the Beijing HDDV fleet in 2009 is 37.0 Gg, an increase of 45% compared to the previous study. Further, we estimate that the total NOx emissions for the national HDDV fleet in 2009 are approximately 4.0 Tg, higher by 1.0 Tg (equivalent to 18% of total NOx emissions for vehicle fleet in 2009) than that estimated in the official report. This would also result in 4% increase in estimation of national anthropogenic NOx emissions. More effective control measures (such as promotion of CNG buses and a new in-use compliance testing program) are urged to secure the goal of total NOx mitigation for the HDDV

[Experimental investigation on emission characteristic of NOx during micropulverized coal oxidation].

PubMed

Jiang, Xiu-Min; Wei, Li-Hong; Huang, Xiang-Yong; Zhang, Chao-Qun

2008-03-01

The combustion experiments of HG micronized coal have been conducted by combining DTG and GC-MS. The effects on NOx emission caused by particle size, oxygen concentration and heating rate were analyzed. The results show that under combustion condition that oxygen concentration is 20%, NOx precipitations of HG coal in difference sizes are single-peaked courses. Particle size impacts NOx emission from coal combustion significantly. Micro-pulverized coal reduces NOx emission. Under heating condition with 5 degrees C/min, 10 degrees C/min and 20 degrees C/min, precipitation of NO and NO2 is increased with heating rate rising, and temperature parallelized with maximum NO precipitation rate is increased with heating rate rising as well. With increasing of oxygen concentration in combustion, NOx precipitation increases correspondingly, and temperature parallelized with maximum NOx precipitation rate is reduced.

Speciation and chemical evolution of nitrogen oxides in aircraft exhaust near airports.

PubMed

Wood, Ezra C; Herndon, Scott C; Timko, Michael T; Yelvington, Paul E; Miake-Lye, Richard C

2008-03-15

Measurements of nitrogen oxides from a variety of commercial aircraft engines as part of the JETS-APEX2 and APEX3 campaigns show that NOx (NOx [triple bond] NO + NO2) is emitted primarily in the form of NO2 at idle thrust and NO at high thrust. A chemical kinetics combustion model reproduces the observed NO2 and NOx trends with engine power and sheds light on the relevant chemical mechanisms. Experimental evidence is presented of rapid conversion of NO to NO2 in the exhaust plume from engines at low thrust. The rapid conversion and the high NO2/NOx emission ratios observed are unrelated to ozone chemistry. NO2 emissions from a CFM56-3B1 engine account for approximately 25% of the NOx emitted below 3000 feet (916 m) and 50% of NOx emitted below 500 feet (153 m) during a standard ICAO (International Civil Aviation Organization) landing-takeoff cycle. Nitrous acid (HONO) accounts for 0.5% to 7% of NOy emissions from aircraft exhaust depending on thrust and engine type. Implications for photochemistry near airports resulting from aircraft emissions are discussed.

NOx Lifetime During WINTER

NASA Astrophysics Data System (ADS)

Kenagy, H. S.; Sparks, T.; Ebben, C. J.; Wooldridge, P. J.; Lopez-Hilfiker, F.; Lee, B. H.; Thornton, J. A.; McDuffie, E. E.; Fibiger, D. L.; Brown, S. S.; Montzka, D. D.; Weinheimer, A. J.; Apel, E. C.; Jaegle, L.; Cohen, R. C.

2017-12-01

The study of the lifetime and fate of NOx (=NO + NO2) is important for understanding its persistence and distribution. This requires an understanding of the balance of NOx sinks. Although urban NOx lifetimes are relatively well understood during summertime conditions, wintertime NOx chemistry has been comparatively less studied. We used measurements of NOx and its oxidation products from the aircraft-based WINTER (Wintertime INvestigation of Transport, Emissions, and Reactivity) campaign over the northeastern US during February-March 2015 to help constrain NOx lifetime during wintertime conditions when days are shorter, actinic flux is reduced, and temperatures are colder. By analyzing the marine outflow from the NYC-DC corridor, we learn that wintertime NOx has a long lifetime, is much longer-lived during the day than at night, and its lifetime is controlled during both periods by NOx conversion to nitric acid (HNO3) as the primary NOx sink. We also employ a two-box model to constrain the wintertime plume dilution rate and HNO3 deposition rate. Additionally, analysis of the nighttime Ox budget suggests that approximately 10% of O3 is lost overnight through N2O5 dark reactions that produce HNO3.

Maritime NOx Emissions Over Chinese Seas Derived From Satellite Observations

NASA Astrophysics Data System (ADS)

Ding, J.; van der A, R. J.; Mijling, B.; Jalkanen, J.-P.; Johansson, L.; Levelt, P. F.

2018-02-01

By applying an inversion algorithm to NOx satellite observations from Ozone Monitoring Instrument, monthly NOx emissions for a 10 year period (2007 to 2016) over Chinese seas are presented for the first time. No effective regulations on NOx emissions have been implemented for ships in China, which is reflected in the trend analysis of maritime emissions. The maritime emissions display a continuous increase rate of about 20% per year until 2012 and slow down to 3% after that. The seasonal cycle of shipping emissions has regional variations, but all regions show lower emissions during winter. Simulations by an atmospheric chemistry transport model show a notable influence of maritime emissions on air pollution over coastal areas, especially in summer. The satellite-derived spatial distribution and the magnitude of maritime emissions over Chinese seas are in good agreement with bottom-up studies based on the Automatic Identification System of ships.

The challenge to NOx emission control for heavy-duty diesel vehicles in China

NASA Astrophysics Data System (ADS)

Wu, Y.; Zhang, S. J.; Li, M. L.; Ge, Y. S.; Shu, J. W.; Zhou, Y.; Xu, Y. Y.; Hu, J. N.; Liu, H.; Fu, L. X.; He, K. B.; Hao, J. M.

2012-07-01

China's new "Twelfth Five-Year Plan" set a target for total NOx emission reduction of 10% for the period of 2011-2015. Heavy-duty diesel vehicles (HDDVs) have been considered a major contributor to NOx emissions in China. Beijing initiated a comprehensive vehicle test program in 2008. This program included a sub-task for measuring on-road emission profiles of hundreds of HDDVs using portable emission measurement systems (PEMS). The major finding is that neither the on-road distance-specific (g km -1) nor brake-specific (g kW h-1) NOx emission factors for diesel buses and heavy-duty diesel trucks improved in most cases as emission standards became more stringent. For example, the average NOx emission factors for Euro II, Euro III and Euro IV buses are 11.3±3.3 g km-1, 12.5± 1.3 g km-1, and 11.8±2.0 g km-1, respectively. No statistically significant difference in NOx emission factors was observed between Euro II and III buses. Even for Euro IV buses equipped with SCR systems, the NOx emission factors are similar to Euro III buses. The data regarding real-time engine performance of Euro IV buses suggest the engine certification cycles did not reflect their real-world operating conditions. These new on-road test results indicate that previous estimates of total NOx emissions for HDDV fleet may be significantly underestimated. The new estimate in total NOx emissions for the Beijing HDDV fleet in 2009 is 37.0 Gg, an increase of 45% compared to the previous study. Further, we estimate that the total NOx emissions for the national HDDV fleet in 2009 are approximately 4.0 Tg, higher by 1.0 Tg (equivalent to 18% of total NOx emissions for vehicle fleet in 2009) than that estimated in the official report. This would also result in 4% increase in estimation of national anthropogenic NOx emissions. More effective control measures (such as promotion of CNG buses and a new in-use compliance testing program) are urged to secure the goal of total NOxmitigation for the HDDV fleet

A plume capture technique for the remote characterization of aircraft engine emissions.

PubMed

Johnson, G R; Mazaheri, M; Ristovski, Z D; Morawska, L

2008-07-01

A technique for capturing and analyzing plumes from unmodified aircraft or other combustion sources under real world conditions is described and applied to the task of characterizing plumes from commercial aircraft during the taxiing phase of the Landing/Take-Off (LTO) cycle. The method utilizes a Plume Capture and Analysis System (PCAS) mounted in a four-wheel drive vehicle which is positioned in the airfield 60 to 180 m downwind of aircraft operations. The approach offers low test turnaround times with the ability to complete careful measurements of particle and gaseous emission factors and sequentially scanned particle size distributions without distortion due to plume concentration fluctuations. These measurements can be performed for individual aircraft movements at five minute intervals. A Plume Capture Device (PCD) collected samples of the naturally diluted plume in a 200 L conductive membrane conforming to a defined shape. Samples from over 60 aircraft movements were collected and analyzed in situ for particulate and gaseous concentrations and for particle size distribution using a Scanning Particle Mobility Sizer (SMPS). Emission factors are derived for particle number, NO(x), and PM2.5 for a widely used commercial aircraft type, Boeing 737 airframes with predominantly CFM56 class engines, during taxiing. The practical advantages of the PCAS include the capacity to perform well targeted and controlled emission factor and size distribution measurements using instrumentation with varying response times within an airport facility, in close proximity to aircraft during their normal operations.

40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS REQUIREMENTS FOR PREPARATION, ADOPTION, AND SUBMITTAL... NOX emissions data as described in this section. (c) Each revision must provide for periodic reporting by the state of NOX emissions data to demonstrate whether the state's emissions are consistent with...

40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS REQUIREMENTS FOR PREPARATION, ADOPTION, AND SUBMITTAL... NOX emissions data as described in this section. (c) Each revision must provide for periodic reporting by the state of NOX emissions data to demonstrate whether the state's emissions are consistent with...

Primary VOC emissions from Commercial Aircraft Jet Engines

NASA Astrophysics Data System (ADS)

Kilic, Dogushan; Huang, Rujin; Slowik, Jay; Brem, Benjamin; Durdina, Lukas; Rindlisbacher, Theo; Baltensperger, Urs; Prevot, Andre

2014-05-01

Air traffic is growing continuously [1]. The increasing number of airplanes leads to an increase of aviation emissions giving rise to environmental concerns globally by high altitude emissions and, locally on air quality at the ground level [2]. The overall impact of aviation emissions on the environment is likely to increase when the growing air transportation trend [2] is considered. The Aviation Particle Regulatory Instrumentation Demonstration Experiment (APRIDE)-5 campaign took place at Zurich Airport in 2013. In this campaign, aircraft exhaust is sampled during engine acceptance tests after engine overhaul at the facilities of SR Technics. Direct sampling from the engine core is made possible due to the unique fixed installation of a retractable sampling probe and the use of a standardized sampling system designed for the new particulate matter regulation in development for aircraft engines. Many of the gas-phase aircraft emissions, e.g. CO2, NOX, CO, SO2, hydrocarbons, and volatile organic compounds (VOC) were detected by the instruments in use. This study, part of the APRIDE-5 campaign, focuses on the primary VOC emissions in order to produce emission factors of VOC species for varying engine operating conditions which are the surrogates for the flight cycles. Previously, aircraft plumes were sampled in order to quantify VOCs by a proton transfer reaction quadrupole mass spectrometer (PTR-MS) [3]. This earlier study provided a preliminary knowledge on the emission of species such as methanol, acetaldehyde, acetone, benzene and toluene by varying engine thrust levels. The new setup was (i) designed to sample from the diluted engine exhaust and the new tool and (ii) used a high resolution time of flight PTR-MS with higher accuracy for many new species, therefore providing a more detailed and accurate inventory. We will present the emission factors for species that were quantified previously, as well as for many additional VOCs detected during the campaign

Lagrangian Hotspots of In-Use NOX Emissions from Transit Buses.

PubMed

Kotz, Andrew J; Kittelson, David B; Northrop, William F

2016-06-07

In-use, spatiotemporal NOX emissions were measured from a conventional powertrain transit bus and a series electric hybrid bus over gradients of route kinetic intensity and ambient temperature. This paper introduces a new method for identifying NOX emissions hotspots along a bus route using high fidelity Lagrangian vehicle data to explore spatial interactions that may influence emissions production. Our study shows that the studied transit buses emit higher than regulated emissions because on-route operation does not accurately represent the range of engine operation tested according to regulatory standards. Using the Lagrangian hotspot detection, we demonstrate that NOX hotspots occurred at bus stops, during cold starts, on inclines, and for accelerations. On the selected routes, bus stops resulted in 3.3 times the route averaged emissions factor in grams/km without significant dependence on bus type or climate. The buses also emitted 2.3 times the route averaged NOX emissions factor at the beginning of each route due to cold selective catalytic reduction aftertreatment temperature. The Lagrangian hotspot detection technique demonstrated here could be employed in future connected vehicles empowered by advances in computational power, data storage capability, and improved sensor technology to optimize emissions as a function of spatial location.

Application of satellite observations for timely updates to global anthropogenic NOx emission inventories

NASA Astrophysics Data System (ADS)

Lamsal, L. N.; Martin, R. V.; Padmanabhan, A.; van Donkelaar, A.; Zhang, Q.; Sioris, C. E.; Chance, K.; Kurosu, T. P.; Newchurch, M. J.

2011-03-01

Anthropogenic emissions of nitrogen oxides (NOx) can change rapidly due to economic growth or control measures. Bottom-up emissions estimated using source-specific emission factors and activity statistics require years to compile and can become quickly outdated. We present a method to use satellite observations of tropospheric NO2 columns to estimate changes in NOx emissions. We use tropospheric NO2 columns retrieved from the SCIAMACHY satellite instrument for 2003-2009, the response of tropospheric NO2 columns to changes in NOx emissions determined from a global chemical transport model (GEOS-Chem), and the bottom-up anthropogenic NOx emissions for 2006 to hindcast and forecast the inventories. We evaluate our approach by comparing bottom-up and hindcast emissions for 2003. The two inventories agree within 6.0% globally and within 8.9% at the regional scale with consistent trends in western Europe, North America, and East Asia. We go on to forecast emissions for 2009. During 2006-2009, anthropogenic NOx emissions over land increase by 9.2% globally and by 18.8% from East Asia. North American emissions decrease by 5.7%.

Advanced Low Emissions Subsonic Combustor Study

NASA Technical Reports Server (NTRS)

Smith, Reid

1998-01-01

Recent advances in commercial and military aircraft gas turbines have yielded significant improvements in fuel efficiency and thrust-to-weight ratio, due in large part to increased combustor operating pressures and temperatures. However, the higher operating conditions have increased the emission of oxides of nitrogen (NOx), which is a pollutant with adverse impact on the atmosphere and environment. Since commercial and military aircraft are the only important direct source of NOx emissions at high altitudes, there is a growing consensus that considerably more stringent limits on NOx emissions will be required in the future for all aircraft. In fact, the regulatory communities have recently agreed to reduce NOx limits by 20 percent from current requirements effective in 1996. Further reductions at low altitude, together with introduction of limits on NOx at altitude, are virtual certainties. In addition, the U.S. Government recently conducted hearings on the introduction of federal fees on the local emission of pollutants from all sources, including aircraft. While no action was taken regarding aircraft in this instance, the threat of future action clearly remains. In these times of intense and growing international competition, the U.S. le-ad in aerospace can only be maintained through a clear technological dominance that leads to a product line of maximum value to the global airline customer. Development of a very low NOx combustor will be essential to meet the future needs of both the commercial and military transport markets, if additional economic burdens and/or operational restrictions are to be avoided. In this report, Pratt & Whitney (P&W) presents the study results with the following specific objectives: Development of low-emissions combustor technologies for advances engines that will enter into service circa 2005, while producing a goal of 70 percent lower NOx emissions, compared to 1996 regulatory levels. Identification of solution approaches to

Probing Emissions of Military Cargo Aircraft: Description of a Joint Field Measurement Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Mengdawn; Corporan, E.; DeWitt, M.

2008-01-01

Direct emissions of NOx, volatile organic compounds, and particulate matter (PM) by aircraft contribute to the pollutant levels found in the atmosphere. Aircraft emissions can be injected at the ground level or directly at the high altitude in flight. Conversion of the precursor gases into secondary PM is one of the pathways for the increased atmospheric PM. Atmospheric PM interacts with solar radiation altering atmospheric radiation balance and potentially contributing to global and regional climate changes. Also, direct emissions of air toxics, ozone precursors and PM from aircraft in and around civilian airports and military air bases can worsen localmore » air quality in non-attainment and/or maintenance areas. These emissions need to be quantified. However, the current EPA methods for particle emission measurements from such sources, modified Method 5 and Conditional Test Method 039, are gravimetric-based, and it is anticipated that these methods will not be suitable for current and future generations of aircraft turbine engines, whose particle mass emissions are low. To evaluate measurement approaches for military aircraft emissions, two complementary projects were initiated in 2005. A joint field campaign between these two programs was executed during the first week of October 2005 at the Kentucky Air National Guard (KYANG) base in Louisville, KY. This campaign represented the first in a series of field studies for each program funded by the DoD Strategic Environmental Research and Development Program (SERDP) and provided the basis for cross-comparison of the sampling approaches and measurement techniques employed by the respective program teams. This paper describes the overall programmatic of the multi-year SERDP aircraft emissions research and presents a summary of the results from the joint field campaign.« less

Characterization of NOx emission in the suburbs of Tokyo based on simultaneous and real-time observations of atmospheric Ox and NOx

NASA Astrophysics Data System (ADS)

Matsumoto, J.

2013-12-01

Nitrogen oxides, NOx (NO, NO2), and volatile organic compounds, VOCs, are important as precursors of photochemical oxidants (tropospheric ozone, O3). To predict and control photochemical oxidants, NOx emission should be captured precisely. In addition, the ratio of NO2/NOx in the exhaust gas is also important as the initial balance between NO and NO2 in the atmosphere. Monitoring the NO2/NOx ratio in the exhaust gases is essential. Especially, the influence of the NOx emission on the real atmosphere should be explored. However, conversion reactions among NO, NO2 and O3 are typically in the time scale of minutes. The NO2/NOx ratio can change rapidly just after emission. Real-time observations of these compounds in the second time scale are essential. In view of photochemical oxidant, near emission sources of NO, ozone concentration can be easily perturbed by reaction with locally emitted NO. As an index of oxidant, the sum of O3 and NO2 (Ox = O3 + NO2) is useful. In this study, a simultaneous and real-time analyzer of atmospheric Ox and NOx has been developed utilizing the dual NO2 detectors based on laser-induced fluorescence technique (LIF), and characterization of NOx emission was explored through the observations of Ox and NOx in the suburbs of Tokyo. The dual LIF detectors consisted of one laser head, two LIF cells, and one common vacuum pump. As the Ox monitor, the excess NO was added to the sample and O3 was converted to NO2, and then the sum of O3 and NO2 in the sample was quantified at the 1st LIF cell. As the NOx monitor, the excess O3 was added to the sample and NO was converted to NO2, and then the sum of NO and NO2 in the sample was quantified at the 2nd LIF cell. Both the ';Ox' and ';NOx' channels in the dual LIF analyzer were simultaneously monitoring Ox and NOx in the sample air, respectively. The temporal resolution of observed data was 1 s. Typical conversion efficiencies of O3 and NO to NO2 were more than 0.98. The lower detection limits were 0

Eddy Covariance Measurements Assessing NOx Emission in London, UK

NASA Astrophysics Data System (ADS)

Drysdale, W. S.; Lee, J. D.; Purvis, R.; Squires, F. A.; Vaughan, A. R.; Metzger, S.

2017-12-01

NOx (the sum of NO + NO2) is emitted during most combustion processes. NO2is a well known air pollutant detrimental to human health, and is regulated in many cities. London often finds itself in breach of these emission regulations. Emission inventories are used in air quality forecast models to predict current and future air pollution levels and to guide abatement strategy. It is therefore crucial that inventories accurately predict emissions; validation can be carried out using direct measurements. Measurements of NO and NO2 at 5 Hz have been made at the BT Tower, 190 m above street level in central London. Eddy covariance calculations have been performed using both classical and "continuous wavelet transformation" method, producing half hour and 1 minute resolved NOx fluxes respectively. We present a first look at these flux data measured in early 2017. A strong diurnal profile for NOx flux is observed, with an increase from 5am to 7am, and remaining constant around 1400 ng m2 m-1 throughout the day, before decreasing to background levels towards midnight. Data is also compared to previous NOx flux measurements over two periods, June-July 2012 and March-April 2013 to examine how emissions have changed over this period. A significant decrease in NOx emissions ( 64%, a mean flux of 2400 ng m2 s-1 in 2012 to a mean 870 ng m2 s-1 in 2017) is observed. When the fluxes are separated by wind flow from the east and west, there is negligible difference in 2017, where 2012 saw lower fluxes from the east, especially in the afternoon. By coupling the measurements with a footprint model we compare the data to emission estimates from the UK's National Atmospheric Emission Inventory (NAEI). In 2012-13 emissions were measured to be twice as high than the NAEI predicted and the latest data shows a much better agreement.

Modelling the spatial distribution of SO2 and NOx emissions in Ireland.

PubMed

de Kluizenaar, Y; Aherne, J; Farrell, E P

2001-01-01

The spatial distributions of sulphur dioxide (SO2) and nitrogen oxides (NOx) emissions are essential inputs to models of atmospheric transport and deposition. Information of this type is required for international negotiations on emission reduction through the critical load approach. High-resolution emission maps for the Republic of Ireland have been created using emission totals and a geographical information system, supported by surrogate statistics and landcover information. Data have been subsequently allocated to the EMEP 50 x 50-km grid, used in long-range transport models for the investigation of transboundary air pollution. Approximately two-thirds of SO2 emissions in Ireland emanate from two grid-squares. Over 50% of total SO2 emissions originate from one grid-square in the west of Ireland, where the largest point sources of SO2 are located. Approximately 15% of the total SO2 emissions originate from the grid-square containing Dublin. SO2 emission densities for the remaining areas are very low, < 1 t km-2 year-1 for most grid-squares. NOx emissions show a very similar distribution pattern. However, NOx emissions are more evenly spread over the country, as about 40% of total NOx emissions originate from road transport.

40 CFR 51.125 - Emissions reporting requirements for SIP revisions relating to budgets for SO2 and NOX emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... SIP revisions relating to budgets for SO2 and NOX emissions. 51.125 Section 51.125 Protection of... SIP revisions relating to budgets for SO2 and NOX emissions. (a) For its transport SIP revision under § 51.123 and/or 51.124, each State must submit to EPA SO2 and/or NOX emissions data as described in...

Alternative control techniques document: NOx emissions from industrial/commercial/institutional (ICI) boilers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-03-01

Industrial, commercial, and institutional (ICI) boilers have been identified as a category that emits more than 25 tons of oxides of nitrogen (NOx) per year. This alternative control techniques (ACT) document provides technical information for use by State and local agencies to develop and implement regulatory programs to control NOx emissions from ICI boilers. Additional ACT documents are being developed for other stationary source categories. Chapter 2 summarizes the findings of this study. Chapter 3 presents information on the ICI boiler types, fuels, operation, and industry applications. Chapter 4 discusses NOx formation and uncontrolled NOx emission factors. Chapter 5 coversmore » alternative control techniques and achievable controlled emission levels. Chapter 6 presents the cost and cost effectiveness of each control technique. Chapter 7 describes environmental and energy impacts associated with implementing the NOx control techniques. Finally, Appendices A through G provide the detailed data used in this study to evaluate uncontrolled and controlled emissions and the costs of controls for several retrofit scenarios.« less

Emissions of an AVCO Lycoming 0-320-DIAD air cooled light aircraft engine as a function of fuel-air ratio, timing, and air temperature and humidity

NASA Technical Reports Server (NTRS)

Meng, P. R.; Skorobatckyi, M.; Cosgrove, D. V.; Kempke, E. E., Jr.

1976-01-01

A carbureted aircraft engine was operated over a range of test conditions to establish the exhaust levels over the EPA seven-mode emissions cycle. Baseline (full rich production limit) exhaust emissions at an induction air temperature of 59 F and near zero relative humidity were 90 percent of the EPA standard for HC, 35 percent for NOx, and 161 percent for CO. Changes in ignition timing around the standard 25 deg BTDC from 30 deg BTDC to 20 deg BTDC had little effect on the exhaust emissions. Retarding the timing to 15 deg BTDC increased both the HC and CO emissions and decreased NOx emissions. HC and CO emissions decreased as the carburetor was leaned out, while NOx emissions increased. The EPA emission standards were marginally achieved at two leanout conditions. Variations in the quantity of cooling air flow over the engine had no effect on exhaust emissions. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased.

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring NOX...

NO(x) Concentrations in the Upper Troposphere as a Result of Lightning

NASA Technical Reports Server (NTRS)

Penner, Joyce E.

1998-01-01

Upper tropospheric NO(x) controls, in part, the distribution of ozone in this greenhouse-sensitive region of the atmosphere. Many factors control NO(x) in this region. As a result it is difficult to assess uncertainties in anthropogenic perturbations to NO from aircraft, for example, without understanding the role of the other major NO(x) sources in the upper troposphere. These include in situ sources (lightning, aircraft), convection from the surface (biomass burning, fossil fuels, soils), stratospheric intrusions, and photochemical recycling from HNO3. This work examines the separate contribution to upper tropospheric "primary" NO(x) from each source category and uses two different chemical transport models (CTMS) to represent a range of possible atmospheric transport. Because aircraft emissions are tied to particular pressure altitudes, it is important to understand whether those emissions are placed in the model stratosphere or troposphere and to assess whether the models can adequately differentiate stratospheric air from tropospheric air. We examine these issues by defining a point-by-point "tracer tropopause" in order to differentiate stratosphere from troposphere in terms of NO(x) perturbations. Both models predict similar zonal average peak enhancements of primary NO(x) due to aircraft (approx. = 10-20 parts per trillion by volume (pptv) in both January and July); however, the placement of this peak is primarily in a region of large stratospheric influence in one model and centered near the level evaluated as the tracer tropopause in the second. Below the tracer tropopause, both models show negligible NO(x) derived directly from the stratospheric source. Also, they predict a typically low background of 1 - 20 pptv NO(x) when tropospheric HNO3 is constrained to be 100 pptv of HNO3. The two models calculate large differences in the total background NO(x) (defined as the source of NO(x) from lightning + stratosphere + surface + HNO3) when using identical loss

MENU OF NOX EMISSION CONTROL OPTIONS FOR COAL-FIRED ELECTRIC UTILITY BOILERS

EPA Science Inventory

The paper reviews NOx control options for coal-fired electric utility boilers. (NOTE: Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, revision of the New Source Performance Standards (NSPS) for NOx emissions from utility sources, and Ozone Transpor...

Sources and distribution of NO(x) in the upper troposphere at northern midlatitudes

NASA Technical Reports Server (NTRS)

Rohrer, Franz; Ehhalt, Dieter H.; Wahner, Andreas

1994-01-01

A simple quasi 2-D model is used to study the zonal distribution of NO(x). The model includes vertical transport in form of eddy diffusion and deep convection, zonal transport by a vertically uniform wind, and a simplified chemistry of NO, NO2 and HNO3. The NO(x) sources considered are surface emissions (mostly from the combustion of fossil fuel), lightning, aircraft emissions, and downward transport from the stratosphere. The model is applied to the latitude band of 40 deg N to 50 deg N during the month of June; the contributions to the zonal NO(x) distribution from the individual sources and transport processes are investigated. The model predicted NO(x) concentration in the upper troposphere is dominated by air lofted from the polluted planetary boundary layer over the large industrial areas of Eastern North America and Europe. Aircraft emissions are also important and contribute on average 30 percent. Stratospheric input is minor about 10 percent, less even than that by lightning. The model provides a clear indication of intercontinental transport of NO(x) and HNO3 in the upper troposphere. Comparison of the modelled NO profiles over the Western Atlantic with those measured during STRATOZ 3 in 1984 shows good agreement at all altitudes.

Prediction of the production of nitrogen oxide (NOx) in turbojet engines

NASA Astrophysics Data System (ADS)

Tsague, Louis; Tsogo, Joseph; Tatietse, Thomas Tamo

Gaseous nitrogen oxides (NO+NO2=NOx) are known as atmospheric trace constituent. These gases remain a big concern despite the advances in low NOx emission technology because they play a critical role in regulating the oxidization capacity of the atmosphere according to Crutzen [1995. My life with O 3, NO x and other YZO x S; Nobel Lecture; Chemistry 1995; pp 195; December 8, 1995] . Aircraft emissions of nitrogen oxides ( NOx) are regulated by the International Civil Aviation Organization. The prediction of NOx emission in turbojet engines by combining combustion operational data produced information showing correlation between the analytical and empirical results. There is close similarity between the calculated emission index and experimental data. The correlation shows improved accuracy when the 2124 experimental data from 11 gas turbine engines are evaluated than a previous semi empirical correlation approach proposed by Pearce et al. [1993. The prediction of thermal NOx in gas turbine exhausts. Eleventh International Symposium on Air Breathing Engines, Tokyo, 1993, pp. 6-9]. The new method we propose predict the production of NOx with far more improved accuracy than previous methods. Since a turbojet engine works in an atmosphere where temperature, pressure and humidity change frequently, a correction factor is developed with standard atmospheric laws and some correlations taken from scientific literature [Swartwelder, M., 2000. Aerospace engineering 410 Term Project performance analysis, November 17, 2000, pp. 2-5; Reed, J.A. Java Gas Turbine Simulator Documentation. pp. 4-5]. The new correction factor is validated with experimental observations from 19 turbojet engines cruising at altitudes of 9 and 13 km given in the ICAO repertory [Middleton, D., 1992. Appendix K (FAA/SETA). Section 1: Boeing Method Two Indices, 1992, pp. 2-3]. This correction factor will enable the prediction of cruise NOx emissions of turbojet engines at cruising speeds. The ICAO

The National Emissions Inventory Significantly Overestimates NOx Emissions: Analysis of CMAQ and in situ observations from DISCOVER-AQ

NASA Astrophysics Data System (ADS)

Anderson, D. C.; Dickerson, R. R.; Loughner, C.

2013-12-01

NOx and CO not only adversely impact human health, but they, along with associated VOCs, are also important precursors for O3 formation. While ambient NOx and CO concentrations have decreased dramatically over the past 10-20 years, O3 has remained a more recalcitrant problem, particularly in the Baltimore/Washington region. Reduction of O3 production requires that emissions inventories, such as the National Emissions Inventory (NEI), accurately capture total emissions of CO and NOx while also correctly apportioning them among different sectors. Previous evaluations of the NEI paint different pictures of its accuracy, with assertions that it overestimates either one or both of CO and NOx from anywhere between 25 percent to a factor of 2. These conflicting claims warrant further investigation. In this study, measurements of NOx and CO taken aboard the NOAA P3B airplane during the 2011 DISCOVER-AQ field campaign were used to determine the NOx/CO emissions ratio at 6 locations in the Washington/Baltimore region. An average molar emissions ratio of 12.8 × 1.2 CO/NOx was found by calculating the change in CO over the change in NOx from vertical concentration profiles in the planetary boundary layer. Ratios showed little variation with location. Observed values were approximately a factor of 1.35 - 1.75 times greater than that predicted by the annual, countywide emissions ratio from the 2008 NEI. When compared to a temporalized, gridded version of the inventory processed by SMOKE, ratio observations were greater than that predicted by inventories by up to a factor of 2. Comparison of the in situ measurements and remotely sensed observations from MOPITT of CO to the Community Multiscale Air Quality (CMAQ) model agree within 10-35 percent, with the model higher on average. Measurements of NOy by two separate analytical techniques, on the other hand, show that CMAQ consistently and significantly overestimates NOy concentrations. Combined with the CO observations, this

Origin of Ozone NO(x) in the Tropical Troposphere: A Photochemical Analysis of Aircraft Observations Over the South Atlantic Basin

NASA Technical Reports Server (NTRS)

Jacob, D. J.; Heikes, B. G.; Fan, S.-M.; Logan, J. A.; Mauzerall, D. L.; Bradshaw, J. D.; Singh, H. B.; Gregory, G. L.; Talbot, R. W.; Blake, D. R.;

High NO2/NOx emissions downstream of the catalytic diesel particulate filter: An influencing factor study.

PubMed

He, Chao; Li, Jiaqiang; Ma, Zhilei; Tan, Jianwei; Zhao, Longqing

2015-09-01

Diesel vehicles are responsible for most of the traffic-related nitrogen oxide (NOx) emissions, including nitric oxide (NO) and nitrogen dioxide (NO2). The use of after-treatment devices increases the risk of high NO2/NOx emissions from diesel engines. In order to investigate the factors influencing NO2/NOx emissions, an emission experiment was carried out on a high pressure common-rail, turbocharged diesel engine with a catalytic diesel particulate filter (CDPF). NO2 was measured by a non-dispersive ultraviolet analyzer with raw exhaust sampling. The experimental results show that the NO2/NOx ratios downstream of the CDPF range around 20%-83%, which are significantly higher than those upstream of the CDPF. The exhaust temperature is a decisive factor influencing the NO2/NOx emissions. The maximum NO2/NOx emission appears at the exhaust temperature of 350°C. The space velocity, engine-out PM/NOx ratio (mass based) and CO conversion ratio are secondary factors. At a constant exhaust temperature, the NO2/NOx emissions decreased with increasing space velocity and engine-out PM/NOx ratio. When the CO conversion ratios range from 80% to 90%, the NO2/NOx emissions remain at a high level. Copyright © 2015. Published by Elsevier B.V.

Evaluation of NOx Emissions and Modeling

NASA Astrophysics Data System (ADS)

Henderson, B. H.; Simon, H. A.; Timin, B.; Dolwick, P. D.; Owen, R. C.; Eyth, A.; Foley, K.; Toro, C.; Baker, K. R.

2017-12-01

Studies focusing on ambient measurements of NOy have concluded that NOx emissions are overestimated and some have attributed the error to the onroad mobile sector. We investigate this conclusion to identify the cause of observed bias. First, we compare DISCOVER-AQ Baltimore ambient measurements to fine-scale modeling with NOy tagged by sector. Sector-based relationships with bias are present, but these are sensitive to simulated vertical mixing. This is evident both in sensitivity to mixing parameterization and the seasonal patterns of bias. We also evaluate observation-based indicators, like CO:NOy ratios, that are commonly used to diagnose emissions inventories. Second, we examine the sensitivity of predicted NOx and NOy to temporal allocation of emissions. We investigate alternative temporal allocations for EGUs without CEMS, on-road mobile, and several non-road categories. These results show some location-specific sensitivity and will lead to some improved temporal allocations. Third, near-road studies have inherently fewer confounding variables, and have been examined for more direct evaluation of emissions and dispersion models. From 2008-2011, the EPA and FHWA conducted near-road studies in Las Vegas and Detroit. These measurements are used to more directly evaluate the emissions and dispersion using site-specific traffic data. In addition, the site-specific emissions are being compared to the emissions used in larger-scale photochemical modeling to identify key discrepancies. These efforts are part of a larger coordinated effort by EPA scientist to ensure the highest quality in emissions and model processes. We look forward to sharing the state of these analyses and expected updates.

Aircraft NOx and O3 measurements during wintertime temperature inversions in Salt Lake City, Utah

NASA Astrophysics Data System (ADS)

Womack, C.; Fibiger, D. L.; McDuffie, E. E.; Franchin, A.; Goldberger, L.; Moravek, A.; Middlebrook, A. M.; Thornton, J. A.; Murphy, J. G.; Baasandorj, M.; Brown, S. S.

2017-12-01

The topography of northern Utah results in several multi-day persistent cold-air pools (PCAPs) each winter, during which a temperature inversion prevents the mix-out of anthropogenic emissions. Pollutant levels rise over the course of several days, resulting in particulate matter (PM2.5) levels exceeding the US National Ambient Air Quality Standard of 35 µg/m3, often reaching 60-70 µg/m3 or higher. However, there is significant variability within individual valleys, whose emissions are predominately urban (as in Salt Lake City Valley), agricultural (as in Cache Valley), or a combination of the two. The Utah Winter Fine Particulate Matter Study (UWFPS 2017) was a ground- and aircraft-based field campaign that took place in Jan-Feb 2017 with the aim of better characterizing the complex chemistry involved in the buildup of PM2.5. On board the NOAA Twin Otter aircraft was a cavity ringdown instrument for measuring nitrogen oxides and ozone, an I- CIMS for gas phase oxidized reactive nitrogen, an AMS that measured particulate phase nitrate, and a mid-infrared absorption instrument for NH3. We report vertical and horizontal distributions of NOx, NOy, and O3, and their variation with meteorological conditions and time of day, in the urban and rural valleys of northern Utah.

Effects of temperature-dependent NOx emissions on continental ozone production

NASA Astrophysics Data System (ADS)

Romer, Paul S.; Duffey, Kaitlin C.; Wooldridge, Paul J.; Edgerton, Eric; Baumann, Karsten; Feiner, Philip A.; Miller, David O.; Brune, William H.; Koss, Abigail R.; de Gouw, Joost A.; Misztal, Pawel K.; Goldstein, Allen H.; Cohen, Ronald C.

2018-02-01

Surface ozone concentrations are observed to increase with rising temperatures, but the mechanisms responsible for this effect in rural and remote continental regions remain uncertain. Better understanding of the effects of temperature on ozone is crucial to understanding global air quality and how it may be affected by climate change. We combine measurements from a focused ground campaign in summer 2013 with a long-term record from a forested site in the rural southeastern United States, to examine how daily average temperature affects ozone production. We find that changes to local chemistry are key drivers of increased ozone concentrations on hotter days, with integrated daily ozone production increasing by 2.3 ppb °C-1. Nearly half of this increase is attributable to temperature-driven increases in emissions of nitrogen oxides (NOx), most likely by soil microbes. The increase of soil NOx emissions with temperature suggests that ozone will continue to increase with temperature in the future, even as direct anthropogenic NOx emissions decrease dramatically. The links between temperature, soil NOx, and ozone form a positive climate feedback.

40 CFR 97.524 - Compliance with TR NOX Ozone Season emissions limitation.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Compliance with TR NOX Ozone Season... TR NOX Ozone Season Trading Program § 97.524 Compliance with TR NOX Ozone Season emissions limitation. (a) Availability for deduction for compliance. TR NOX Ozone Season allowances are available to be...

40 CFR 97.524 - Compliance with TR NOX Ozone Season emissions limitation.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Compliance with TR NOX Ozone Season... TR NOX Ozone Season Trading Program § 97.524 Compliance with TR NOX Ozone Season emissions limitation. (a) Availability for deduction for compliance. TR NOX Ozone Season allowances are available to be...

40 CFR 97.524 - Compliance with TR NOX Ozone Season emissions limitation.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Compliance with TR NOX Ozone Season... TR NOX Ozone Season Trading Program § 97.524 Compliance with TR NOX Ozone Season emissions limitation. (a) Availability for deduction for compliance. TR NOX Ozone Season allowances are available to be...

40 CFR 75.72 - Determination of NOX mass emissions for common stack and multiple stack configurations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Determination of NOX mass emissions... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING NOX Mass Emissions Provisions § 75.72 Determination of NOX mass emissions for common stack and multiple stack...

A mitigation strategy for commercial aviation impact on NOx-related O3 change

NASA Astrophysics Data System (ADS)

Wasiuk, D. K.; Khan, M. A. H.; Shallcross, D. E.; Derwent, R. G.; Lowenberg, M. H.

2016-07-01

An operational mitigation strategy for commercial aircraft impact on atmospheric composition, referred to as the turboprop replacement strategy (TRS), is described in this paper. The global air traffic between 2005 and 2011 was modeled with the TRS in which turbofan powered aircraft were replaced with nine chosen turboprop powered aircraft on all routes up to 1700 nautical miles (NM) in range. The results of this TRS double the global number of departures, as well as global mission distance, while global mission time grows by nearly a factor of 3. However, the global mission fuel and the emissions of aviation CO2, H2O, and SOx remain approximately unchanged, and the total global aviation CO, hydrocarbons (HC), and NOx emissions are reduced by 79%, 21%, and 11% on average between 2005 and 2011. The TRS lowers the global mean cruise altitude of flights up to 1700 NM by 2.7 km which leads to a significant decrease in global mission fuel burn, mission time, distance flown, and the aircraft emissions of CO2, CO, H2O, NOx, SOx, and HC above 9.2 km. The replacement of turbofans with turboprops in regional fleets on a global scale leads to an overall reduction in levels of tropospheric O3 at the current estimated mean cruise altitude near the tropopause where the radiative forcing of O3 is strongest. Further, the replacement strategy results in a reduction of ground-level aviation CO and NOx emissions by 33 and 29%, respectively, between 2005 and 2011.

Impact of Aircraft Emissions on Air Quality in the Vicinity of Airports. Volume II. An Updated Model Assessment of Aircraft Generated Air Pollution at LAX, JFK, and ORD

DTIC Science & Technology

1980-07-01

Lfl 0 0.0 0ř 1𔃺 1ř 2Ŕ 2ř 3Ŕ 35 X (MILES) Figure 8. Map of Aircraf Line Sources at JFK 29 Table 8. Summary of Aircraft Emission for Hour 19 at JFK ... Airport Emissions (103 lbs) Location CO THC NOx Runways 0.08 0.05 0.52 Taxiways 3.94 2.30 0.15 Queue 1.21 0.64 0.05 Terminal 0.60 0.28 0.04 Total on

NOx emission estimates during the 2014 Youth Olympic Games in Nanjing

NASA Astrophysics Data System (ADS)

Ding, J.; van der A, R. J.; Mijling, B.; Levelt, P. F.; Hao, N.

2015-08-01

The Nanjing Government applied temporary environmental regulations to guarantee good air quality during the Youth Olympic Games (YOG) in 2014. We study the effect of those regulations by applying the emission estimate algorithm DECSO (Daily Emission estimates Constrained by Satellite Observations) to measurements of the Ozone Monitoring Instrument (OMI). We improved DECSO by updating the chemical transport model CHIMERE from v2006 to v2013 and by adding an Observation minus Forecast (OmF) criterion to filter outlying satellite retrievals due to high aerosol concentrations. The comparison of model results with both ground and satellite observations indicates that CHIMERE v2013 is better performing than CHIMERE v2006. After filtering the satellite observations with high aerosol loads that were leading to large OmF values, unrealistic jumps in the emission estimates are removed. Despite the cloudy conditions during the YOG we could still see a decrease of tropospheric NO2 column concentrations of about 32 % in the OMI observations when compared to the average NO2 columns from 2005 to 2012. The results of the improved DECSO algorithm for NOx emissions show a reduction of at least 25 % during the YOG period and afterwards. This indicates that air quality regulations taken by the local government have an effect in reducing NOx emissions. The algorithm is also able to detect an emission reduction of 10 % during the Chinese Spring Festival. This study demonstrates the capacity of the DECSO algorithm to capture the change of NOx emissions on a monthly scale. We also show that the observed NO2 columns and the derived emissions show different patterns that provide complimentary information. For example, the Nanjing smog episode in December 2013 led to a strong increase in NO2 concentrations without an increase in NOx emissions. Furthermore, DECSO gives us important information on the non-trivial seasonal relation between NOx emissions and NO2 concentrations on a local scale.

The effect of functional forms of nitrogen on fuel-NOx emissions.

PubMed

Zhang, Linghui; Su, Dagen; Zhong, Mingfeng

2015-01-01

This work explores the effects of different nitrogen functional forms on fuel-NOx emissions at 900 °C. The majority of tests are performed with an excess air coefficient of 1.4. Fuel-NOx is detected by measuring N-(1-naphthyl) ethylenediamine dihydrochloride (C₁₂H₁₆Cl₂N₂) via spectrophotometry. The different functional forms of nitrogen in the raw materials are identified by using X-ray photoelectron spectroscopy (XPS). A reliable density functional theory (DFT) method at the B3LYP/6-311++G** level is employed to investigate the reaction pathways of all functional forms of nitrogen during combustion. The results indicate that the functional forms of nitrogen influence the formation of nitrogen oxides. While under the same experimental conditions, fuel-NOx emissions increase by using less activation energy and nitrogen-containing groups with poor thermal stability. It is determined that fuel-NOx emissions vary in the following order: glycine > pyrrole > pyridine > methylenedi-p-phenylene diisocyanate (MDI). Glycine is the chain structure of amino acids in waste-leather and has low activation energy and poor thermal stability. With these properties, it is noted that glycine produces the most fuel-NOx in all of the raw materials studied. More pyrrole than pyridine in coal lead to high yields of fuel-NOx. The lowest yields of fuel-NO x are obtained using polyurethanes in waste-PU.

CONTROL OF NOX EMISSIONS FROM U.S. COAL-FIRED ELECTRIC UTILITY BOILERS

EPA Science Inventory

The paper discusses the control of nitrogen oxide (NOx) emissions from U.S. coal-fired electric utility boilers. (NOTE: In general, NOx control technologies are categorized as being either primary or secondary control technologies. Primary technologies reduce the amount of NOx pr...

40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this subpart...

40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this subpart...

40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this subpart...

40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this subpart...

40 CFR 60.4320 - What emission limits must I meet for nitrogen oxides (NOX)?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false What emission limits must I meet for nitrogen oxides (NOX)? 60.4320 Section 60.4320 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... nitrogen oxides (NOX)? (a) You must meet the emission limits for NOX specified in Table 1 to this subpart...

40 CFR 75.72 - Determination of NOX mass emissions for common stack and multiple stack configurations.

Code of Federal Regulations, 2012 CFR

2012-07-01

... the affected units as the difference between NOX mass emissions measured in the common stack and NOX... emissions using the maximum potential NOX emission rate, the maximum potential flow rate, and either the maximum potential CO2 concentration or the minimum potential O2 concentration (as applicable). The maximum...

Low modeled ozone production suggests underestimation of precursor emissions (especially NOx) in Europe

NASA Astrophysics Data System (ADS)

Oikonomakis, Emmanouil; Aksoyoglu, Sebnem; Ciarelli, Giancarlo; Baltensperger, Urs; Prévôt, André Stephan Henry

2018-02-01

High surface ozone concentrations, which usually occur when photochemical ozone production takes place, pose a great risk to human health and vegetation. Air quality models are often used by policy makers as tools for the development of ozone mitigation strategies. However, the modeled ozone production is often not or not enough evaluated in many ozone modeling studies. The focus of this work is to evaluate the modeled ozone production in Europe indirectly, with the use of the ozone-temperature correlation for the summer of 2010 and to analyze its sensitivity to precursor emissions and meteorology by using the regional air quality model, the Comprehensive Air Quality Model with Extensions (CAMx). The results show that the model significantly underestimates the observed high afternoon surface ozone mixing ratios (≥ 60 ppb) by 10-20 ppb and overestimates the lower ones (< 40 ppb) by 5-15 ppb, resulting in a misleading good agreement with the observations for average ozone. The model also underestimates the ozone-temperature regression slope by about a factor of 2 for most of the measurement stations. To investigate the impact of emissions, four scenarios were tested: (i) increased volatile organic compound (VOC) emissions by a factor of 1.5 and 2 for the anthropogenic and biogenic VOC emissions, respectively, (ii) increased nitrogen oxide (NOx) emissions by a factor of 2, (iii) a combination of the first two scenarios and (iv) increased traffic-only NOx emissions by a factor of 4. For southern, eastern, and central (except the Benelux area) Europe, doubling NOx emissions seems to be the most efficient scenario to reduce the underestimation of the observed high ozone mixing ratios without significant degradation of the model performance for the lower ozone mixing ratios. The model performance for ozone-temperature correlation is also better when NOx emissions are doubled. In the Benelux area, however, the third scenario (where both NOx and VOC emissions are

Worldwide biogenic soil NOx emission estimates from OMI NO2 observations and the GEOS-Chem model

NASA Astrophysics Data System (ADS)

Vinken, Geert; Boersma, Folkert; Maasakkers, Bram; Martin, Randall

2014-05-01

Bacteria in soils are an important source of biogenic nitrogen oxides (NOx = NO + NO2), which are important precursors for ozone (O3) formation. Furthermore NOx emissions contribute to increased nitrogen deposition and particulate matter formation. Bottom-up estimates of global soil NOx emissions range from 4 to 27 Tg N / yr, reflecting our incomplete knowledge of emission factors and processes driving these emissions. In this study we used, for the first time, OMI NO2 columns on all continents to reduce the uncertainty in soil NOx emissions. Regions and months dominated by soil NOx emissions were identified using a filtering scheme in the GEOS-Chem chemistry transport model. Consequently, we compared OMI observed NO2 observed columns to GEOS-Chem simulated columns and provide constraints for these months in 11 regions. This allows us to provide a top-down emission inventory for 2005 for soil NOx emissions from all continents. Our total global soil NOx emission inventory amounts to 10 Tg N / yr. Our estimate is 4% higher than the GEOS-Chem a priori (Hudman et al., 2012), but substantial regional differences exist (e.g. +20% for Sahel and India; and -40% for mid-USA). We furthermore observed a stronger seasonal cycle in the Sahel region, indicating directions for possible future improvements to the parameterization currently used in GEOS-Chem. We validated NO2 concentrations simulated with this new top-down inventory against surface NO2 measurements from monitoring stations in Africa, the USA and Europe. On the whole, we conclude that simulations with our new top-down inventory better agree with measurements. Our work shows that satellite retrieved NO2 columns can improve estimates of soil NOx emissions over sparsely monitored remote rural areas. We show that the range in previous estimates of soil NOx emissions is too large, and global emissions are most likely around 10 Tg N/yr, in agreement with the most recent parameterizations.

NOx emission trends over Chinese cities estimated from OMI observations during 2005 to 2015

NASA Astrophysics Data System (ADS)

Liu, Fei; Beirle, Steffen; Zhang, Qiang; van der A, Ronald J.; Zheng, Bo; Tong, Dan; He, Kebin

2017-08-01

Satellite nitrogen dioxide (NO2) observations have been widely used to evaluate emission changes. To determine trends in nitrogen oxides (NOx) emission over China, we used a method independent of chemical transport models to quantify the NOx emissions from 48 cities and seven power plants over China, on the basis of Ozone Monitoring Instrument (OMI) NO2 observations from 2005 to 2015. We found that NOx emissions over 48 Chinese cities increased by 52 % from 2005 to 2011 and decreased by 21 % from 2011 to 2015. The decrease since 2011 could be mainly attributed to emission control measures in power sector; while cities with different dominant emission sources (i.e., power, industrial, and transportation sectors) showed variable emission decline timelines that corresponded to the schedules for emission control in different sectors. The time series of the derived NOx emissions was consistent with the bottom-up emission inventories for all power plants (r = 0. 8 on average), but not for some cities (r = 0. 4 on average). The lack of consistency observed for cities was most probably due to the high uncertainty of bottom-up urban emissions used in this study, which were derived from downscaling the regional-based emission data to city level by using spatial distribution proxies.

Atmospheric emission of NOx from mining explosives: A critical review

NASA Astrophysics Data System (ADS)

Oluwoye, Ibukun; Dlugogorski, Bogdan Z.; Gore, Jeff; Oskierski, Hans C.; Altarawneh, Mohammednoor

2017-10-01

High-energy materials such as emulsions, slurries and ammonium-nitrate fuel-oil (ANFO) explosives play crucial roles in mining, quarrying, tunnelling and many other infrastructure activities, because of their excellent transport and blasting properties. These explosives engender environmental concerns, due to atmospheric pollution caused by emission of dust and nitrogen oxides (NOx) from blasts, the latter characterised by the average emission factor of 5 kg (t AN explosive)-1. This first-of-its-kind review provides a concise literature account of the formation of NOx during blasting of AN-based explosives, employed in surface operations. We estimate the total NOx emission rate from AN-based explosives as 0.05 Tg (i.e., 5 × 104 t) N per annum, compared to the total global annual anthropogenic NOx emissions of 41.3 × 106 t N y-1. Although minor in the global sense, the large localised plumes from blasting exhibit high NOx concentration (500 ppm) exceeding up to 3000 times the international standards. This emission has profound consequences at mining sites and for adjacent atmospheric environment, necessitating expensive management of exclusion zones. The review describes different types of AN energetic materials for civilian applications, and summarises the essential properties and terminologies pertaining to their use. Furthermore, we recapitulate the mechanisms that lead to the formation of the reactive nitrogen species in blasting of AN-based explosives, review their implications to atmospheric air pollution, and compare the mechanisms with those experienced in other thermal and combustion operations. We also examine the mitigation approaches, including guidelines and operational-control measures. The review discusses the abatement technologies such as the formulation of new explosive mixtures, comprising secondary fuels, spin traps and other additives, in light of their effectiveness and efficiency. We conclude the review with a summary of unresolved problems

Experimental Assessment of NOx Emissions from 73 Euro 6 Diesel Passenger Cars.

PubMed

Yang, Liuhanzi; Franco, Vicente; Mock, Peter; Kolke, Reinhard; Zhang, Shaojun; Wu, Ye; German, John

2015-12-15

Controlling nitrogen oxides (NOx) emissions from diesel passenger cars during real-world driving is one of the major technical challenges facing diesel auto manufacturers. Three main technologies are available for this purpose: exhaust gas recirculation (EGR), lean-burn NOx traps (LNT), and selective catalytic reduction (SCR). Seventy-three Euro 6 diesel passenger cars (8 EGR only, 40 LNT, and 25 SCR) were tested on a chassis dynamometer over both the European type-approval cycle (NEDC, cold engine start) and the more realistic Worldwide harmonized light-duty test cycle (WLTC version 2.0, hot start) between 2012 and 2015. Most vehicles met the legislative limit of 0.08 g/km of NOx over NEDC (average emission factors by technology: EGR-only 0.07 g/km, LNT 0.04 g/km, and SCR 0.05 g/km), but the average emission factors rose dramatically over WLTC (EGR-only 0.17 g/km, LNT 0.21 g/km, and SCR 0.13 g/km). Five LNT-equipped vehicles exhibited very poor performance over the WLTC, emitting 7-15 times the regulated limit. These results illustrate how diesel NOx emissions are not properly controlled under the current, NEDC-based homologation framework. The upcoming real-driving emissions (RDE) regulation, which mandates an additional on-road emissions test for EU type approvals, could be a step in the right direction to address this problem.

On the Effects of NOx Emission Control and Drought on an Ozone-Polluted Ecosystem

NASA Astrophysics Data System (ADS)

Pusede, S.; Geddes, J.; Buysse, C. E.; Esperanza, A.; Najacht, E.; Anderson, J. F.; Bailey, C. B.; Munyan, J.

2017-12-01

Regulatory emission controls are typically designed to reduce ozone when ozone is highest. However, high ozone concentrations are often asynchronous with periods of the greatest ozone harm to plants and ecosystems, particularly during drought. Because ozone production chemistry is nonlinear, emissions reductions designed to be effective in polluted cities may have a range of effects on downwind ecosystems. Here, we investigate the influence of regional NOx emission controls on ozone pollution in Sequoia National Park (SNP). First, we show that steep declines in NOx throughout the region have had smaller impacts in SNP than in cities upwind, and that these reductions have been least effective at times of day and year when plants are most sensitive to ozone. Second, in recent years (2012-2015), California experienced the worst drought in recorded history. We present observational evidence of the ozone response in SNP to drought conditions, finding that the drought altered the chemical sensitivity of local ozone production to NOx emissions and, hence, the effectiveness of NOx emission controls. We show that drought impacts on the ozone sensitivity to NOx have persisted at least two years since the drought ended.

Top-down NOx and SO2 emissions simultaneously estimated from different OMI retrievals and inversion frameworks

NASA Astrophysics Data System (ADS)

Qu, Z.; Henze, D. K.; Wang, J.; Xu, X.; Wang, Y.

2017-12-01

Quantifying emissions trends of nitrogen oxides (NOx) and sulfur dioxide (SO2) is important for improving understanding of air pollution and the effectiveness of emission control strategies. We estimate long-term (2005-2016) global (2° x 2.5° resolution) and regional (North America and East Asia at 0.5° x 0.667° resolution) NOx emissions using a recently developed hybrid (mass-balance / 4D-Var) method with GEOS-Chem. NASA standard product and DOMINO retrievals of NO2 column are both used to constrain emissions; comparison of these results provides insight into regions where trends are most robust with respect to retrieval uncertainties, and highlights regions where seemingly significant trends are retrieval-specific. To incorporate chemical interactions among species, we extend our hybrid method to assimilate NO2 and SO2 observations and optimize NOx and SO2 emissions simultaneously. Due to chemical interactions, inclusion of SO2 observations leads to 30% grid-scale differences in posterior NOx emissions compared to those constrained only by NO2 observations. When assimilating and optimizing both species in pseudo observation tests, the sum of the normalized mean squared error (compared to the true emissions) of NOx and SO2 posterior emissions are 54-63% smaller than when observing/constraining a single species. NOx and SO2 emissions are also correlated through the amount of fuel combustion. To incorporate this correlation into the inversion, we optimize seven sector-specific emission scaling factors, including industry, energy, residential, aviation, transportation, shipping and agriculture. We compare posterior emissions from inversions optimizing only species' emissions, only sector-based emissions, and both species' and sector-based emissions. In situ measurements of NOx and SO2 are applied to evaluate the performance of these inversions. The impacts of the inversion on PM2.5 and O3 concentrations and premature deaths are also evaluated.

40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the...

40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the...

40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the...

40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the...

40 CFR 76.6 - NOX emission limitations for Group 2 boilers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.6 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the...

Top-down NOX Emissions of European Cities Derived from Modelled and Spaceborne Tropospheric NO2 Columns

NASA Astrophysics Data System (ADS)

Verstraeten, W. W.; Boersma, K. F.; Douros, J.; Williams, J. E.; Eskes, H.; Delcloo, A. W.

2017-12-01

High nitrogen oxides (NOX = NO + NO2) concentrations near the surface impact humans and ecosystems badly and play a key role in tropospheric chemistry. NO2 is an important precursor of tropospheric ozone (O3) which in turn affects the production of the hydroxyl radical controlling the chemical lifetime of key atmospheric pollutants and reactive greenhouse gases. Combustion from industrial, traffic and household activities in large and densely populated urban areas result in high NOX emissions. Accurate mapping of these emissions is essential but hard to do since reported emissions factors may differ from real-time emissions in order of magnitude. Modelled NO2 levels and lifetimes also have large associated uncertainties and overestimation in the chemical lifetime which may mask missing NOX chemistry in current chemistry transport models (CTM's). The simultaneously estimation of both the NO2 lifetime and as well as the concentrations by applying the Exponentially Modified Gaussian (EMG) method on tropospheric NO2 columns lines densities should improve the surface NOX emission estimates. Here we evaluate if the EMG methodology applied on the tropospheric NO2 columns simulated by the LOTOS-EUROS (Long Term Ozone Simulation-European Ozone Simulation) CTM can reproduce the NOX emissions used as model input. First we process both the modelled tropospheric NO2 columns for the period April-September 2013 for 21 selected European urban areas under windy conditions (averaged vertical wind speeds between surface and 500 m from ECMWF > 2 m s-1) as well as the accompanying OMI (Ozone Monitoring Instrument) data providing us with real-time observation-based estimates of midday NO2 columns. Then we compare the top-down derived surface NOX emissions with the 2011 MACC-III emission inventory, used in the CTM as input to simulate the NO2 columns. For cities where NOX emissions can be assumed as originating from one large source good agreement is found between the top-down derived

COMPARISON OF HISTORIC SO2 AND NOX EMISSION DATA SETS

EPA Science Inventory

The report gives results of a comparison of historic SO2 and NOx emission data sets. During the past few years, several research projects have been conducted to reconstruct historic air pollution emission trends in the U.S. The report compares in detail the emission estimates and...

Nitrous oxide pollution from aircraft to increase by 2050

NASA Astrophysics Data System (ADS)

Bhattacharya, Atreyee

2012-09-01

The transportation industry is not only one of the biggest sources of air pollution and a significant player in greenhouse gas-induced global warming, but, as a new study shows, the industry could also be responsible for episodes of ozone (O3 ) pollution, particularly over the United States and northern Europe. Combustion of fuel in cars, shipping vessels, and low-flying aircraft produce nitrogen oxides (NOx), which not only decrease the lifetime of greenhouse gases such as methane but also react with other molecules in the atmosphere to form tropospheric O3, another, more lethal, air pollutant. Hauglustaine and Koff used a global three-dimensional chemistry-climate model to investigate how different components of the transportation industry—cars, ships, and low-flying aircraft—would contribute to NOx pollution over the next few decades under several projected emission scenarios. They found that as road transportation stagnates or even declines due to stricter regulations and congestion, NOx emissions from cars will decrease over time. However, aircraft will increase in number and could contribute between 25% and 48% of NOx emissions, which will be most severe over the United States and Europe—two regions with the highest growth rate in commercial aviation.

Variability in operation-based NO(x) emission factors with different test routes, and its effects on the real-driving emissions of light diesel vehicles.

PubMed

Lee, Taewoo; Park, Junhong; Kwon, Sangil; Lee, Jongtae; Kim, Jeongsoo

2013-09-01

The objective of this study is to quantify the differences in NO(x) emissions between standard and non-standard driving and vehicle operating conditions, and to estimate by how much NO(x) emissions exceed the legislative emission limits under typical Korean road traffic conditions. Twelve Euro 3-5 light-duty diesel vehicles (LDDVs) manufactured in Korea were driven on a chassis dynamometer over the standard New European Driving Cycle (NEDC) and a representative Korean on-road driving cycle (KDC). NO(x) emissions, average speeds and accelerations were calculated for each 1-km trip segment, so called averaging windows. The results suggest that the NO(x) emissions of the tested vehicles are more susceptible to variations in the driving cycles than to those in the operating conditions. Even under comparable operating conditions, the NO(x) control capabilities of vehicles differ from each other, i.e., NO(x) control is weaker for the KDC than for the NEDC. The NO(x) emissions over the KDC for given vehicle operating conditions exceed those over the NEDC by more than a factor of 8. Consequently, on-road NO(x) emission factors are estimated here to exceed the Euro 5 emission limit by up to a factor of 8, 4 and 3 for typical Korean urban, rural, and motorway road traffic conditions, respectively. Our findings support the development of technical regulations for supplementary real-world emission tests for emission certification and the corresponding research actions taken by automotive industries. Copyright © 2013 Elsevier B.V. All rights reserved.

Review of Diesel Combustion Models for NOx and Smoke Emissions

DOT National Transportation Integrated Search

1977-10-01

A comprehensive review of diesel emissions models is presented together with assessments of the pertinent fundamental NOx and soot kinetics. The results of diesel emissions experiments carried out at Southampton are also presented and correlations ar...

Airborne emission measurements of SO2 , NOx and particles from individual ships using a sniffer technique

NASA Astrophysics Data System (ADS)

Beecken, J.; Mellqvist, J.; Salo, K.; Ekholm, J.; Jalkanen, J.-P.

2014-07-01

A dedicated system for airborne ship emission measurements of SO2, NOx and particles has been developed and used from several small aircraft. The system has been adapted for fast response measurements at 1 Hz, and the use of several of the instruments is unique. The uncertainty of the given data is about 20% for SO2 and 24% for NOx emission factors. The mean values with one standard deviation for multiple measurements of 158 ships measured from the air on the Baltic and North Sea during 2011 and 2012 show emission factors of 18.8 ± 6.5 g kg-1 fuel , 66.6 ± 23.4 g kg-1 fuel and 1.8 ± 1.3 1016 particles kg-1 fuel for SO2, NOx and particle number, respectively. The particle size distributions were measured for particle diameters between 15 and 560 nm. The mean sizes of the particles are between 45 and 54 nm dependent on the distance to the source, and the number size distribution is monomodal. Concerning the sulfur fuel content, around 85% of the monitored ships comply with the International Maritime Organization (IMO) limits. The reduction of the sulfur emission control area (SECA) limit from 1.5 to 1% in 2010 appears to have contributed to reduction of sulfur emissions that were measured in earlier studies from 2007 to 2009. The presented method can be implemented for regular ship compliance monitoring.

A process for the quantification of aircraft noise and emissions interdependencies

NASA Astrophysics Data System (ADS)

de Luis, Jorge

The main purpose of this dissertation is to develop a process to improve actual policy-making procedures in terms of aviation environmental effects. This research work expands current practices with physics based publicly available models. The current method uses solely information provided by industry members, and this information is usually proprietary, and not physically intuitive. The process herein proposed provides information regarding the interdependencies between the environmental effects of aircraft. These interdependencies are also tied to the actual physical parameters of the aircraft and the engine, making it more intuitive for decision-makers to understand the impacts to the vehicle due to different policy scenarios. These scenarios involve the use of fleet analysis tools in which the existing aircraft are used to predict the environmental effects of imposing new stringency levels. The aircraft used are reduced to a series of coefficients that represent their performance, in terms of flight characteristics, fuel burn, noise, and emissions. These coefficients are then utilized to model flight operations and calculate what the environmental impacts of those aircraft are. If a particular aircraft does not meet the stringency to be analyzed, a technology response is applied to it, in order to meet that stringency. Depending on the level of reduction needed, this technology response can have an effect on the fuel burn characteristic of the aircraft. Another important point of the current stringency analysis process is that it does not take into account both noise and emissions concurrently, but instead, it considers them separately, one at a time. This assumes that the interdependencies between the two do not exists, which is not realistic. The latest stringency process delineated in 2004 imposed a 2% fuel burn penalty for any required improvements on NOx, no matter the type of aircraft or engine, assuming that no company had the ability to produce a

Study of Nox Emission Characteristics of a 1025t/h Coal-Fired Circulating Fluidized Bed Boiler

NASA Astrophysics Data System (ADS)

Li, Q. Y.; Mi, Z. D.; Zhang, Q. F.

Measurements of emission are carried out in a 1025t/h CFB boiler. The effect of some factors including coal properties, bed temperature, unit load, excess air on the emission of NOx are investigated. The measurement results show that the N concentration in the coal is dominant parameter to predict the NOx emission from a large-scale CFB boiler. NOx emission from the 1025t/h CFB boiler increases with cyclone temperature and upper pressure drop due to post combustion and external cycle.

Continuous reduction of cyclic adsorbed and desorbed NO(x) in diesel emission using nonthermal plasma.

PubMed

Kuwahara, Takuya; Nakaguchi, Harunobu; Kuroki, Tomoyuki; Okubo, Masaaki

2016-05-05

Considering the recent stringent regulations governing diesel NO(x) emission, an aftertreatment system for the reduction of NO(x) in the exhaust gas has been proposed and studied. The proposed system is a hybrid method combining nonthermal plasma and NOx adsorbent. The system does not require precious metal catalysts or harmful chemicals such as urea and ammonia. In the present system, NO(x) in diesel emission is treated by adsorption and desorption by adsorbent as well as nonthermal plasma reduction. In addition, the remaining NO(x) in the adsorbent is desorbed again in the supplied air by residual heat. The desorbed NO(x) in air recirculates into the intake of the engine, and this process, i.e., exhaust gas components' recirculation (EGCR) achieves NO(x) reduction. Alternate utilization of two adsorption chambers in the system can achieve high-efficiency NO(x) removal continuously. An experiment with a stationary diesel engine for electric power generation demonstrates an energy efficiency of 154 g(NO2)/kWh for NO(x) removal and continuous NO(x) reduction of 70.3%. Considering the regulation against diesel emission in Japan, i.e., the new regulation to be imposed on vehicles of 3.5-7.5 ton since 2016, the present aftertreatment system fulfills the requirement with only 1.0% of engine power. Copyright © 2016. Published by Elsevier B.V.

CFD analysis of jet mixing in low NOx flametube combustors

NASA Technical Reports Server (NTRS)

Talpallikar, M. V.; Smith, C. E.; Lai, M. C.; Holdeman, J. D.

1991-01-01

The Rich-burn/Quick-mix/Lean-burn (RQL) combustor was identified as a potential gas turbine combustor concept to reduce NO(x) emissions in High Speed Civil Transport (HSCT) aircraft. To demonstrate reduced NO(x) levels, cylindrical flametube versions of RQL combustors are being tested at NASA Lewis Research Center. A critical technology needed for the RQL combustor is a method of quickly mixing by-pass combustion air with rich-burn gases. Jet mixing in a cylindrical quick-mix section was numerically analyzed. The quick-mix configuration was five inches in diameter and employed twelve radial-inflow slots. The numerical analyses were performed with an advanced, validated 3-D Computational Fluid Dynamics (CFD) code named REFLEQS. Parametric variation of jet-to-mainstream momentum flux ratio (J) and slot aspect ratio was investigated. Both non-reacting and reacting analyses were performed. Results showed mixing and NO(x) emissions to be highly sensitive to J and slot aspect ratio. Lowest NO(x) emissions occurred when the dilution jet penetrated to approximately mid-radius. The viability of using 3-D CFD analyses for optimizing jet mixing was demonstrated.

Comparison of NOx emissions from China III and China IV in-use diesel trucks based on on-road measurements

NASA Astrophysics Data System (ADS)

Yao, Zhiliang; Wu, Bobo; Wu, Yunong; Cao, Xinyue; Jiang, Xi

2015-12-01

To mitigate NOx and other emissions from diesel vehicles, China I, China II, China III and China IV emissions standards for new vehicles have been implemented nationwide. However, recent on-road measurements using a portable emission measurement system (PEMS) have revealed no significant reductions in the NOx emissions factors of diesel trucks due to the change from China II emissions standards to the more stringent China III standards. Thus, it is important to understand the effect of the China IV emissions standard on NOx emissions. In this study, nine China III and nine China IV diesel trucks of three sizes (light-duty diesel trucks (LDDTs), medium-duty diesel trucks (MDDTs) and heavy-duty diesel trucks (HDDTs)) were tested on real roads in Beijing using a PEMS. Compared to the tested China III diesel trucks, the China IV diesel trucks showed significant reductions of the average NOx emissions factors in terms of both distance travelled and fuel consumption. However, the driving conditions had an important impact on the reduction. Under non-highway driving (NHD), several of the tested China IV diesel trucks experienced no reduction or an increase in NOx emissions compared to their China III counterparts. The NOx emissions factors of the 18 tested diesel trucks under NHD were on average 1.5-times greater than those under highway driving (HD), and the effects on NOx emissions removal from China III to China IV diesel trucks were greater under HD than under NHD. In addition, no significant reduction of NOx based on fuel consumption for China IV diesel trucks was observed for MDDTs and HDDTs compared to the test results for similar China II vehicles reported in a previous study. To reduce NOx emissions in China, additional control measures of vehicular NOx emissions should be formulated.

Impacts and mitigation of excess diesel-related NOx emissions in 11 major vehicle markets

NASA Astrophysics Data System (ADS)

Anenberg, Susan C.; Miller, Joshua; Minjares, Ray; Du, Li; Henze, Daven K.; Lacey, Forrest; Malley, Christopher S.; Emberson, Lisa; Franco, Vicente; Klimont, Zbigniew; Heyes, Chris

2017-05-01

Vehicle emissions contribute to fine particulate matter (PM2.5) and tropospheric ozone air pollution, affecting human health, crop yields and climate worldwide. On-road diesel vehicles produce approximately 20 per cent of global anthropogenic emissions of nitrogen oxides (NOx), which are key PM2.5 and ozone precursors. Regulated NOx emission limits in leading markets have been progressively tightened, but current diesel vehicles emit far more NOx under real-world operating conditions than during laboratory certification testing. Here we show that across 11 markets, representing approximately 80 per cent of global diesel vehicle sales, nearly one-third of on-road heavy-duty diesel vehicle emissions and over half of on-road light-duty diesel vehicle emissions are in excess of certification limits. These excess emissions (totalling 4.6 million tons) are associated with about 38,000 PM2.5- and ozone-related premature deaths globally in 2015, including about 10 per cent of all ozone-related premature deaths in the 28 European Union member states. Heavy-duty vehicles are the dominant contributor to excess diesel NOx emissions and associated health impacts in almost all regions. Adopting and enforcing next-generation standards (more stringent than Euro 6/VI) could nearly eliminate real-world diesel-related NOx emissions in these markets, avoiding approximately 174,000 global PM2.5- and ozone-related premature deaths in 2040. Most of these benefits can be achieved by implementing Euro VI standards where they have not yet been adopted for heavy-duty vehicles.

Fuel-Air Mixing Effect on Nox Emissions for a Lean Premixed-Prevaporized Combustion System

NASA Technical Reports Server (NTRS)

Lee, Chi-Ming; Chun, Kue S.; Locke, Randy J.

1995-01-01

The lean premixed-prevaporized (LPP) concept effectively meets low nitrogen oxides (NOx) emission requirements for combustors with the high inlet temperature and pressure typical of the High-Speed Civil Transport (HSCT). For the LPP system fuel-air mixture uniformity is probably the most important factor for low NOx emissions. Previous studies have suggested that the fuel-air mixture uniformity can be severely affected by changing the number and configuration of fuel injection points. Therefore, an experimental study was performed to determine how the number of fuel injection points and their arrangement affect NOx emissions from an LPP system. The NOx emissions were measured by a gas-sampling probe in a flame-tube rig at the following conditions: inlet temperature of 810 K (1000 F), rig pressure of 10 atm, reference velocity of 150 ft/s, and residence time near 0.005 s. Additionally, a focused Schlieren diagnostic technique coupled with a high speed camera was used to provide a qualitative description of the spatial flow field.

40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised NOX...

40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised NOX...

40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised NOX...

40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised NOX...

40 CFR 76.7 - Revised NOX emission limitations for Group 1, Phase II boilers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Revised NOX emission limitations for Group 1, Phase II boilers. 76.7 Section 76.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.7 Revised NOX...

Combustion and NOx emissions in deep-air-staging combustion of char in a circulating fluidized bed

NASA Astrophysics Data System (ADS)

Gong, Zhiqiang; Wang, Zhentong; Wang, Lei; Du, Aixun

2017-10-01

Combustion and NOx emissions in deep-air-staging (with higher level secondary air (SA) injection) combustion of char have been investigated in a CFB test rig. A good fluidized condition and uniform temperature distribution can be achieved with injection of higher level SA. NOx emission decreases with injection of higher level SA and the reduction effect is more obvious at higher temperature. NOx emission decreases with combustion temperature increasing for char combustion.

Nox Emission Reduction in Commercial Jets Through Water Injection

NASA Technical Reports Server (NTRS)

Balepin, Vladimir; Ossello, Chris; Snyder, Chris

2002-01-01

This paper discusses a method of the nitrogen oxides (NOx) emission reduction through the injection of water in commercial turbofan engines during the takeoff and climbout cycles. In addition to emission reduction, this method can significantly reduce turbine temperature during the most demanding operational modes (takeoff and climbout) and increase engine reliability and life.

Evaluation of the impacts of biodiesel and second generation biofuels on NO(x) emissions for CARB diesel fuels.

PubMed

Hajbabaei, Maryam; Johnson, Kent C; Okamoto, Robert A; Mitchell, Alexander; Pullman, Marcie; Durbin, Thomas D

2012-08-21

The impact of biodiesel and second generation biofuels on nitrogen oxides (NO(x)) emissions from heavy-duty engines was investigated using a California Air Resources Board (CARB) certified diesel fuel. Two heavy-duty engines, a 2006 engine with no exhaust aftertreatment, and a 2007 engine with a diesel particle filter (DPF), were tested on an engine dynamometer over four different test cycles. Emissions from soy- and animal-based biodiesels, a hydrotreated renewable diesel, and a gas to liquid (GTL) fuel were evaluated at blend levels from 5 to 100%. NO(x) emissions consistently increased with increasing biodiesel blend level, while increasing renewable diesel and GTL blends showed NO(x) emissions reductions with blend level. NO(x) increases ranged from 1.5% to 6.9% for B20, 6.4% to 18.2% for B50, and 14.1% to 47.1% for B100. The soy-biodiesel showed higher NO(x) emissions increases compared to the animal-biodiesel. NO(x) emissions neutrality with the CARB diesel was achieved by blending GTL or renewable diesel fuels with various levels of biodiesel or by using di-tert-butyl peroxide (DTBP). It appears that the impact of biodiesel on NO(x) emissions might be a more important consideration when blended with CARB diesel or similar fuels, and that some form of NO(x) mitigation might be needed for biodiesel blends with such fuels.

Wide range operation of advanced low NOx combustors for supersonic high-altitude aircraft gas turbines

NASA Technical Reports Server (NTRS)

Roberts, P. B.; Fiorito, R. J.

1977-01-01

An initial rig program tested the Jet Induced Circulation (JIC) and Vortex Air Blast (VAB) systems in small can combustor configurations for NOx emissions at a simulated high altitude, supersonic cruise condition. The VAB combustor demonstrated the capability of meeting the NOx goal of 1.0 g NO2/kg fuel at the cruise condition. In addition, the program served to demonstrate the limited low-emissions range available from the lean, premixed combustor. A follow-on effort was concerned with the problem of operating these lean, premixed combustors with acceptable emissions at simulated engine idle conditions. Various techniques have been demonstrated that allow satisfactory operation on both the JIC and VAB combustors at idle with CO emissions below 20 g/kg fuel. The VAB combustor was limited by flashback/autoignition phenomena at the cruise conditions to a pressure of 8 atmospheres. The JIC combustor was operated up to the full design cruise pressure of 14 atmospheres without encountering an autoignition limitation although the NOx levels, in the 2-3 g NO2/kg fuel range, exceeded the program goal.

NOx emissions from Euro IV busses with SCR systems associated with urban, suburban and freeway driving patterns.

PubMed

Fu, Mingliang; Ge, Yunshan; Wang, Xin; Tan, Jianwei; Yu, Linxiao; Liang, Bin

2013-05-01

NOx and particulate matter (PM) emissions from heavy-duty diesel vehicles (HDVs) have become the most important sources of pollutants affecting urban air quality in China. In recent years, a series of emission control strategies and diesel engine polices have been introduced that require advanced emission control technology. China and Europe mostly have used Selective Catalytic Reduction (SCR) with urea to meet the Euro IV diesel engine emission standard. In this study, two Euro IV busses with SCR were tested by using potable emission measurement system (PEMS) to assess NOx emissions associated with urban, suburban and freeway driving patterns. The results indicated that with the SCR system, the urea injection time for the entire driving period increased with higher vehicle speed. For freeway driving, the urea injection time covered 71%-83% of the driving period; the NOx emission factors from freeway driving were lower than those associated with urban and suburban driving. Unfortunately, the NOx emission factors were 2.6-2.8-, 2.3-2.7- and 2.2-2.3-fold higher than the Euro IV standard limits for urban, suburban and freeway driving, respectively; NOx emission factors (in g/km and g/(kW·h)) from the original vehicles (without SCR) were higher than their corresponding vehicles with SCR for suburban and freeway driving. Compared with the IVE model results, the measured NOx emission factors were 1.60-1.16-, 1.77-1.27-, 2.49-2.44-fold higher than the NOx predicted by the IVE model for urban and suburban driving, respectively. Thus, an adjustment of emission factors is needed to improve the estimation of Euro IV vehicle emissions in China. Copyright © 2013 Elsevier B.V. All rights reserved.

Flame Tube NOx Emissions Using a Lean-Direct-Wall-Injection Combustor Concept

NASA Technical Reports Server (NTRS)

Tacina, Robert R.; Wey, Changlie; Choi, Kyung J.

2001-01-01

A low-NOx emissions combustor concept has been demonstrated in flame tube tests. A lean-direct injection concept was used where the fuel is injected directly into the flame zone and the overall fuel-air mixture is lean. In this concept the air is swirled upstream of a venturi section and the fuel is injected radially inward into the air stream from the throat section using a plain-orifice injector. Configurations have two-, four-, or six-wall fuel injectors and in some cases fuel is also injected from an axially located simplex pressure atomizer. Various orifice sizes of the plain-orifice injector were evaluated for the effect on NOx. Test conditions were inlet temperatures up to 8 1 OK, inlet pressures up to 2760 kPa, and flame temperatures up to 2100 K. A correlation is developed relating the NOx emissions to inlet temperature, inlet pressure, fuel-air ratio and pressure drop. Assuming that 15 percent of the combustion air would be used for liner cooling and using an advanced engine cycle, for the best configuration, the NOx emissions using the correlation is estimated to be <75 percent of the 1996 ICAO standard.

Update of NOx emission temporal profiles using CMAQ-HDDM

NASA Astrophysics Data System (ADS)

Bae, C.; Lee, J. B.; Kim, H. C.; Kim, B. U.; Kim, S.

2017-12-01

This study demonstrates the impact of revised temporal profiles of NOx emissions on air quality simulations in the Seoul Metropolitan Area (SMA), South Korea. Air pollutants such as ozone and nitrogen oxides can be harmful to the human body even with short-term exposure. Since most of air quality models use predefined temporal profiles which are often outdated or taken from different chemical environment, providing accurate temporal variation of emissions are challenging in prediction of correct local air quality. Considering secondary formation of pollutants are important in mega cities and temporal variations of emissions are not coincident with those of resultant concentrations, we utilized CMAQ-HDDM to link emissions and consequential concentrations from different time steps. Base simulations were conducted using WRF, SMOKE, and CMAQ modeling frame using CREATE 2015 and CAPSS 2013 emissions inventories for East Asia and South Korea, respectively. With current modeling system, modeled NOx concentrations underestimate 4% in the daytime (10-16 LST), but overestimate 30% in the nighttime during May to August 2015. Applying revised temporal profiles based on HDDM sensitivities, model performance was improved significantly. We conclude that the proposed temporal allocation method can be useful to reduce the model-observation discrepancies when the activity data for emission sources are difficult to obtain with a bottom-up approach.

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction requirements...

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction requirements...

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction requirements...

Measurements of nitrous acid in commercial aircraft exhaust at the Alternative Aviation Fuel Experiment.

PubMed

Lee, Ben H; Santoni, Gregory W; Wood, Ezra C; Herndon, Scott C; Miake-Lye, Richard C; Zahniser, Mark S; Wofsy, Steven C; Munger, J William

2011-09-15

The Alternative Aviation Fuel Experiment (AAFEX), conducted in January of 2009 in Palmdale, California, quantified aerosol and gaseous emissions from a DC-8 aircraft equipped with CFM56-2C1 engines using both traditional and synthetic fuels. This study examines the emissions of nitrous acid (HONO) and nitrogen oxides (NO(x) = NO + NO(2)) measured 145 m behind the grounded aircraft. The fuel-based emission index (EI) for HONO increases approximately 6-fold from idle to takeoff conditions but plateaus between 65 and 100% of maximum rated engine thrust, while the EI for NO(x) increases continuously. At high engine power, NO(x) EI is greater when combusting traditional (JP-8) rather than Fischer-Tropsch fuels, while HONO exhibits the opposite trend. Additionally, hydrogen peroxide (H(2)O(2)) was identified in exhaust plumes emitted only during engine idle. Chemical reactions responsible for emissions and comparison to previous measurement studies are discussed.

CFD analysis of jet mixing in low NO(x) flametube combustors

NASA Technical Reports Server (NTRS)

Talpallikar, M. V.; Smith, C. E.; Lai, M. C.; Holdeman, J. D.

1991-01-01

The Rich-burn/Quick-mix/Lean-burn (RQL) combustor has been identified as a potential gas turbine combustor concept to reduce NO(x) emissions in High Speed Civil Transport (HSCT) aircraft. To demonstrate reduced NO(x) levels, cylindrical flametube versions of RQL combustors are being tested at NASA Lewis Research Center. A critical technology needed for the RQL combustor is a method of quickly mixing by-pass combustion air with rich-burn gases. Jet mixing in a cylindrical quick-mix section was numerically analyzed. The quick-mix configuration was five inches in diameter and employed twelve radial-inflow slots. The numerical analyses were performed with an advanced, validated 3D Computational Fluid Dynamics (CFD) code named REFLEQS. Parametric variation of jet-to-mainstream momentum flux ratio (J) and slot aspect ratio was investigated. Both non-reacting and reacting analyses were performed. Results showed mixing and NO(x) emissions to be highly sensitive to J and slot aspect ratio. Lowest NO(x) emissions occurred when the dilution jet penetrated to approximately mid-radius. The viability of using 3D CFD analyses for optimizing jet mixing was demonstrated.

40 CFR 75.19 - Optional SO2, NOX, and CO2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2010 CFR

2010-07-01

...), manufacturer and model, and must have the same history of modifications (e.g., have the same controls installed... (or group of identical units) equipped with SCR (or SNCR) and uses dry low-NOX technology to control... with add-on NOX emission controls, and for units that use dry low-NOX technology, the owner or operator...

40 CFR 76.5 - NOX emission limitations for Group 1 boilers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROGRAMS (CONTINUED) ACID RAIN NITROGEN OXIDES EMISSION REDUCTION PROGRAM § 76.5 NOX emission limitations..., the date on which the unit is required to meet Acid Rain emission reduction requirements for SO2, the... subject to section 404(d) of the Act, the date the unit is required to meet Acid Rain emissions reduction...

The Impact of Buoyancy and Flame Structure on Soot, Radiation and NOx Emissions from a Turbulent Diffusion Flame

NASA Technical Reports Server (NTRS)

Kennedy, I. M.; Kollman, W.; VanderWal, R. L.

1999-01-01

It is hypothesized that the spatial structure of a turbulent diffusion flame plays an important role in determining the emissions of radiative energy, soot and NO, from a combustor. This structure, manifested in the two point statistics, is influenced by buoyancy. Radiation, soot and NOx emissions are the cumulative result of processes that occur throughout a flame. For example, radiation fluxes along a line of sight can be found from summing up the contributions from sources in individual pockets of hot soot that emit, and from sinks in cold soot that absorb. Soot and NOx are both the results of slow chemistry and are not equilibrium products. The time that is available for production and burnout is crucial in determining the eventual emissions of these pollutants. Turbulence models generally rely on a single point closure of the appropriate time averaged equations. Hence, spatial information is lost and needs to be modeled using solution variables such as turbulence kinetic energy and dissipation rate, often with the assumption of isotropy. However, buoyancy can affect the physical structure of turbulent flames and can change the spatial extent of soot bearing regions. Theoretical comparisons with models are best done in the limit of infinite Froude number because the inclusion of buoyancy in flow models introduces significant uncertainties. Hence, LII measurements of soot, measurements of radiation fluxes from soot, Particle Imaging Velocimetry (PIV) of the flow field and measurements of post flame NOX will be carried out on the NASA Lewis 2.2 sec drop tower and eventually on the parabolic flight aircraft. The drop rig will be a modified version of a unit that has been successfully used at Lewis in the past.

Origin of tropospheric NO(x) over subarctic eastern Canada in summer

NASA Technical Reports Server (NTRS)

Fan, S.-M; Jacob, D. J.; Mauzerall, D. L.; Bradshaw, J. D.; Sandholm, S. T.; Blake, D. R.; Singh, H. B.; Talbot, R. W.; Gregory, G. L.; Sachse, G. W.

1994-01-01

The original of NO(X) in the summertime troposphere over subarctic eastern Canada is investigated by photochemical modeling of aircraft and ground-based measurements from the Arctic Boundary Layer Expedition (ABLE 3B). It is found that decomposition of peroxyacetyl nitrate (PAN) can account for most of the NO(X) observed between the surface and 6.2 km altitude (aircraft ceiling). Forest fires represent the principal source of PAN in the region, implying the same origin for NO(X). There is, however, evidence for an unidentified source of NO(X) in occasional air masses subsiding from the upper troposphere. Isoprene emissions from boreal forests maintain high NO(X) concentrations in the continental boundary layer over eastern Canada by scavenging OH and NO3, thus slowing down conversion of NO(X) to HNO3, both in the daytime and at night. This effect is partly compensated by the production of CH3CO3 radicals during isoprene oxidation, which slows down the decomposition of PAN subsiding from the free troposphere. The peroxy radical concentrations estimated from concurrent measurements of NO and NO2 concentrations during ABLE 3B are consistent with values computed from our photochemical model below 4 km, but model values are low at higher altitudes. The discrepancy may reflect either a missing radical source in the model or interferences in the NO2 measurement.

NOx Emissions from a Rotating Detonation-wave Engine

NASA Astrophysics Data System (ADS)

Kailasanath, Kazhikathra; Schwer, Douglas

2016-11-01

Rotating detonation-wave engines (RDE) are a form of continuous detonation-wave engines. They potentially provide further gains in performance than an intermittent or pulsed detonation-wave engine (PDE). The overall flow field in an idealized RDE, primarily consisting of two concentric cylinders, has been discussed in previous meetings. Because of the high pressures involved and the lack of adequate reaction mechanisms for this regime, previous simulations have typically used simplified chemistry models. However, understanding the exhaust species concentrations in propulsion devices is important for both performance considerations as well as estimating pollutant emissions. Progress towards addressing this need will be discussed in this talk. In this approach, an induction parameter model is used for simulating the detonation but a more detailed finite-chemistry model including NOx chemistry is used in the expansion flow region, where the pressures are lower and the uncertainties in the chemistry model are greatly reduced. Results show that overall radical concentrations in the exhaust flow are substantially lower than from earlier predictions with simplified models. Results to date show that NOx emissions are not a problem for the RDE due to the short residence times and the nature of the flow field. Furthermore, simulations show that the amount of NOx can be further reduced by tailoring the fluid dynamics within the RDE.

Measurement of In-Flight Aircraft Emissions

NASA Technical Reports Server (NTRS)

Sokoloski, M.; Arnold, C.; Rider, D.; Beer, R.; Worden, H.; Glavich, T.

1995-01-01

Aircraft engine emission and their chemical and physical evolution can be measured in flight using high resolution infrared spectroscopy. The Airborne Emission Spectrometer (AES), designed for remote measure- ments of atmosphere emissions from an airborne platform, is an ideal tool for the evaluation of aircraft emissions and their evolution. Capabilities of AES will be discussed. Ground data will be given.

Greenhouse gas emissions trading in U.S. States: observations and lessons from the OTC NOx Budget Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andrew Aulisi; Alexander E. Farrell; Jonathan Pershing

2005-07-01

A number of U.S. states are considering market-based policies to reduce emissions of greenhouse gases (GHGs). The experience gained from emissions trading for sulfur dioxide and oxides of nitrogen (NOx) offers a useful body of information and data to draw on to design a GHG emissions trading system. This report examines NOx trading under the Ozone Transport Commission (OTC) NOx Budget Program, which resulted principally from the leadership, decisions, and actions by a group of states, ultimately becoming the first multilateral cap-and-trade system for emissions of air pollutants. 72 refs.

Top-down estimates of methane and nitrogen oxide emissions from shale gas production regions using aircraft measurements and a mesoscale Bayesian inversion system together with a flux ratio inversion technique

NASA Astrophysics Data System (ADS)

Cui, Y.; Brioude, J. F.; Angevine, W. M.; McKeen, S. A.; Henze, D. K.; Bousserez, N.; Liu, Z.; McDonald, B.; Peischl, J.; Ryerson, T. B.; Frost, G. J.; Trainer, M.

2016-12-01

Production of unconventional natural gas grew rapidly during the past ten years in the US which led to an increase in emissions of methane (CH4) and, depending on the shale region, nitrogen oxides (NOx). In terms of radiative forcing, CH4 is the second most important greenhouse gas after CO2. NOx is a precursor of ozone (O3) in the troposphere and nitrate particles, both of which are regulated by the US Clean Air Act. Emission estimates of CH4 and NOx from the shale regions are still highly uncertain. We present top-down estimates of CH4 and NOx surface fluxes from the Haynesville and Fayetteville shale production regions using aircraft data collected during the Southeast Nexus of Climate Change and Air Quality (SENEX) field campaign (June-July, 2013) and the Shale Oil and Natural Gas Nexus (SONGNEX) field campaign (March-May, 2015) within a mesoscale inversion framework. The inversion method is based on a mesoscale Bayesian inversion system using multiple transport models. EPA's 2011 National CH4 and NOx Emission Inventories are used as prior information to optimize CH4 and NOx emissions. Furthermore, the posterior CH4 emission estimates are used to constrain NOx emission estimates using a flux ratio inversion technique. Sensitivity of the posterior estimates to the use of off-diagonal terms in the error covariance matrices, the transport models, and prior estimates is discussed. Compared to the ground-based in-situ observations, the optimized CH4 and NOx inventories improve ground level CH4 and O3 concentrations calculated by the Weather Research and Forecasting mesoscale model coupled with chemistry (WRF-Chem).

Increase in NOx emissions from Indian thermal power plants during 1996-2010: unit-based inventories and multisatellite observations.

PubMed

Lu, Zifeng; Streets, David G

2012-07-17

Driven by rapid economic development and growing electricity demand, NO(x) emissions (E) from the power sector in India have increased dramatically since the mid-1990s. In this study, we present the NO(x) emissions from Indian public thermal power plants for the period 1996-2010 using a unit-based methodology and compare the emission estimates with the satellite observations of NO(2) tropospheric vertical column densities (TVCDs) from four spaceborne instruments: GOME, SCIAMACHY, OMI, and GOME-2. Results show that NO(x) emissions from Indian power plants increased by at least 70% during 1996-2010. Coal-fired power plants, NO(x) emissions from which are not regulated in India, contribute ∼96% to the total power sector emissions, followed by gas-fired (∼4%) and oil-fired (<1%) ones. A number of isolated NO(2) hot spots are observed over the power plant areas, and good agreement between NO(2) TVCDs and NO(x) emissions is found for areas dominated by power plant emissions. Average NO(2) TVCDs over power plant areas were continuously increasing during the study period. We find that the ratio of ΔE/E to ΔTVCD/TVCD changed from greater than one to less than one around 2005-2008, implying that a transition of the overall NO(x) chemistry occurred over the power plant areas, which may cause significant impact on the atmospheric environment.

Understanding NOx emission trends in China based on OMI observations

NASA Astrophysics Data System (ADS)

Wang, Y.; Ga, D.; Smeltzer, C. D.; Yi, R.; Liu, Z.

2012-12-01

We analyze OMI observations of NO2 columns over China from 2005 to 2010. Simulations using a regional 3-D chemical transport model (REAM) are used to derive the top-down anthropogenic NOx emissions. The Kendall method is then applied to derive the emission trend. The emission trend is affected by the economic slowdown in 2009. After removing the effect of one year abnormal data, the overall emission trend is 4.35±1.42% per year, which is slower than the linear-regression trend of 5.8-10.8% per year reported for previous years. We find large regional, seasonal, and urban-rural variations in emission trend. The annual emission trends of Northeast China, Central China Plain, Yangtze River Delta and Pearl River Delta are 44.98±1.39%, 5.24±1.63%, 3.31±1.02% and -4.02±1.87%, respectively. The annual emission trends of four megacities, Beijing, Shanghai, Guangzhou and Shenzhen are 0.7±0.27%, -0.75±0.31%, -4.08±1.21% and -6.22±2.85%,, considerably lower than the regional averages. These results appear to suggest that a number of factors, including migration of high-emission industries, vehicle emission regulations, emission control measures of thermal power plants, increased hydro-power usage, have reduced or reversed the increasing trend of NOx emissions in more economically developed megacities and southern coastal regions.

Two-Dimensional Description of Potential Perturbations to the Ozone Layer Due to NOx and H2O Aircraft Emissions,

DTIC Science & Technology

1984-01-01

Perturbations to the Ozone 01aparUNM fe"MAWLayer Due to NOX and H20Arrf Emissions20Araf Office of Environment and Energy Washington, D.C. 20591 uTI LEOU George F...and Energy 14. Sponsorng Agency Code Washington, D.C. 20591 15. Supplementary Notes 1 . Abstroct . This report is divided into two parts. Part I is an...obtained from the work of Louis, et al. (1974), who calculated the circulation patterns by solving the continuity and energy equations using compiled

Integrated assessment of health, crop, and climate impacts of mitigating excess diesel NOx emissions in 11 major vehicle markets

NASA Astrophysics Data System (ADS)

Henze, D. K.; Anenberg, S.; Miller, J.; Vicente, F.; Du, L.; Emberson, L.; Lacey, F.; Malley, C.; Minjares, R. J.

2016-12-01

Vehicle emissions contribute to tropospheric ozone and fine particulate matter (PM2.5), impacting human health, crop yields, and climate worldwide. Diesel cars, trucks, and buses produce 70% of global land transportation emissions of nitrogen oxides (NOx), a key PM2.5 and ozone precursor. Despite progressive tightening of regulated NOx emission limits in leading markets, current diesel vehicles emit far more NOx under real-world operating conditions than during laboratory certification testing. Here we show that real-world diesel NOx emissions in 11 markets representing 80% of global diesel vehicle sales are on average 24% higher than certification limits indicate. This excess NOx contributed an estimated 33,000 additional ozone- and PM2.5-related premature deaths globally in 2015, including 6% of all EU-28 ozone- and PM2.5-related premature deaths. Next-generation diesel NOx standards and in-use compliance (more stringent than Euro 6/VI standards) could avoid 358,000 (5%) of global PM2.5- and ozone-related premature deaths in 2040 and up to 4% of ozone-related crop production loss regionally. Impacts of NOx-induced changes in aerosols, methane, and ozone on the global climate are found to present a small net positive radiative forcing (i.e., climate disbenefit), likely outweighed by the climate benefits of reductions to co-emitted black carbon aerosol. In some markets (Australia, Brazil, China, Mexico, and Russia), Euro 6/VI standards alone can achieve most (72-98%) of these health benefits. In India and the EU-28, reducing Euro 6 real-world NOx emissions through strengthened type-approval and in-use emissions testing programs (including market surveillance and expanded emissions test procedure boundaries) would achieve one-third of the health benefits from adopting next generation standards. Our results indicate that implementing stringent and technically feasible NOx emission regulations for diesel vehicles can substantially improve public health.

Feasibility of Reburning for Controlling NOx Emissions from Air Force Jet Engine Test Cells

DTIC Science & Technology

1989-06-01

the engine exhaust by the augmenter air. For this reason, it is important to examine the effect of inlet NOX concentration on achieved reduction...Schedule at Tinker AFB .... ......... 8 3 Typical Nonafterburning Turbine Engine Emission Trends. . 9 4 Temperature of Diluted Exhaust J-79 Engine ... Exhaust Temperature on Reburner NOX Reduction .......... ......................... . 43 24 Effect of Exhaust Gas Inlet Flow Rate on Reburner NOx

Constraints on Eurasian ship NOx emissions using OMI NO2 observations and GEOS-Chem

NASA Astrophysics Data System (ADS)

Vinken, Geert C. M.; Boersma, Folkert; van Donkelaar, Aaron; Zhang, Lin

2013-04-01

Ships emit large quantities of nitrogen oxides (NOx = NO + NO2), important precursors for ozone (O3) and particulate matter formation. Ships burn low-grade marine heavy fuel due to the limited regulations that exist for the maritime sector in international waters. Previous studies showed that global ship NOx emission inventories amount to 3.0-10.4 Tg N per year (15-30% of total NOx emissions), with most emissions close to land and affecting air quality in densely populated coastal regions. Bottom-up inventories depend on the extrapolation of a relatively small number of measurements that are often unable to capture annual emission changes and can suffer from large uncertainties. Satellites provide long-term, high-resolution retrievals that can be used to improve emission estimates. In this study we provide top-down constraints on ship NOx emissions in major European ship routes, using observed NO2 columns from the Ozone Monitoring Instrument (OMI) and NO2 columns simulated with the nested (0.5°×0.67°) version of the GEOS-Chem chemistry transport model. We use a plume-in-grid treatment of ship NOx emissions to account for in-plume chemistry in our model. We ensure consistency between the retrievals and model simulations by using the high-resolution GEOS-Chem NO2 profiles as a priori. We find evidence that ship emissions in the Mediterranean Sea are geographically misplaced by up to 150 km and biased high by a factor of 4 as compared to the most recent (EMEP) ship emission inventory. Better agreement is found over the shipping lane between Spain and the English Channel. We extend our approach and also provide constraints for major ship routes in the Red Sea and Indian Ocean. Using the full benefit of the long-term retrieval record of OMI, we present a new Eurasian ship emission inventory for the years 2005 to 2010, based on the EMEP and AMVER-ICOADS inventories, and top-down constraints from the satellite retrievals. Our work shows that satellite retrievals can

[Aviation fuels and aircraft emissions. A risk characterization for airport neighbors using Hamburg Airport as an example].

PubMed

Tesseraux, I; Mach, B; Koss, G

1998-06-01

Aviation fuels are well characterised regarding their physical and chemical properties. Health effects of fuel vapours and of liquid fuel are described after occupational exposure and in animal studies. Exposure of the general population (airport visitors and people living in the vicinity of airports) may occur during fuel supply particularly in warm summers (odour). Aircraft emissions vary with the engine type and the kind of fuel. Combustion of aviation fuel results in CO2, H2O, CO, C, NOx and a great number of organic compounds. Among the emitted polyaromatic hydrocarbons (PAH) no compound characteristic for jet engines (tracer) could be detected so far. Hardly any data exist on the toxicology of jet engine emissions. According to analyses of their chemical composition, however, they contain various toxicologically relevant compounds including carcinogenic substances. Measurements in ambient air around the Hamburg Airport show no elevated pollutant levels. However, no such data exist on aldehydes, black smoke or fine particles. Annoying odours have been stated in some areas around the airport, which were mainly attributed to the aircraft engine emissions rather than to fuel vapours.

Exhaust particle and NOx emission performance of an SCR heavy duty truck operating in real-world conditions

NASA Astrophysics Data System (ADS)

Saari, Sampo; Karjalainen, Panu; Ntziachristos, Leonidas; Pirjola, Liisa; Matilainen, Pekka; Keskinen, Jorma; Rönkkö, Topi

2016-02-01

Particle and NOx emissions of an SCR equipped HDD truck were studied in real-world driving conditions using the "Sniffer" mobile laboratory. Real-time CO2 measurement enables emission factor calculation for NOx and particles. In this study, we compared three different emission factor calculation methods and characterised their suitability for real-world chasing experiments. The particle number emission was bimodal and dominated by the nucleation mode particles (diameter below 23 nm) having emission factor up to 1 × 1015 #/kgfuel whereas emission factor for soot (diameter above 23 nm that is consistent with the PMP standard) was typically 1 × 1014 #/kgfuel. The effect of thermodenuder on the exhaust particles indicated that the nucleation particles consisted mainly of volatile compounds, but sometimes there also existed a non-volatile core. The nucleation mode particles are not controlled by current regulations in Europe. However, these particles consistently form under atmospheric dilution in the plume of the truck and constitute a health risk for the human population that is exposed to those. Average NOx emission was 3.55 g/kWh during the test, whereas the Euro IV emission limit over transient testing is 3.5 g NOx/kWh. The on-road emission performance of the vehicle was very close to the expected levels, confirming the successful operation of the SCR system of the tested vehicle. Heavy driving conditions such as uphill driving increased both the NOx and particle number emission factors whereas the emission factor for soot particle number remains rather constant.

Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

NASA Astrophysics Data System (ADS)

Brioude, Jerome; Angevine, Wayne; Ahmadov, Ravan; Kim, Si Wan; Evan, Stephanie; McKeen, Stuart; Hsie, Eirh Yu; Frost, Greg; Neuman, Andy; Pollack, Ilana; Peischl, Jeff; Ryerson, Tom; Holloway, John; Brown, Steeve; Nowak, John; Roberts, Jim; Wofsy, Steeve; Santoni, Greg; Trainer, Michael

2013-04-01

We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in

Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

NASA Astrophysics Data System (ADS)

Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Oda, T.; Trainer, M.

2013-04-01

We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% in LA County and by 37% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% in LA County and by 27% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 Tg yr-1 in SoCAB. A flight during ITCT (Intercontinental Transport and Chemical Transformation) in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% in LA County but decreased by 4% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, a gridded CARB inventory and the posterior

Top-down estimate of surface flux in the Los Angeles Basin using a mesoscale inverse modeling technique: assessing anthropogenic emissions of CO, NOx and CO2 and their impacts

NASA Astrophysics Data System (ADS)

Brioude, J.; Angevine, W. M.; Ahmadov, R.; Kim, S.-W.; Evan, S.; McKeen, S. A.; Hsie, E.-Y.; Frost, G. J.; Neuman, J. A.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; Holloway, J.; Brown, S. S.; Nowak, J. B.; Roberts, J. M.; Wofsy, S. C.; Santoni, G. W.; Trainer, M.

2012-12-01

We present top-down estimates of anthropogenic CO, NOx and CO2 surface fluxes at mesoscale using a Lagrangian model in combination with three different WRF model configurations, driven by data from aircraft flights during the CALNEX campaign in southern California in May-June 2010. The US EPA National Emission Inventory 2005 (NEI 2005) was the prior in the CO and NOx inversion calculations. The flux ratio inversion method, based on linear relationships between chemical species, was used to calculate the CO2 inventory without prior knowledge of CO2 surface fluxes. The inversion was applied to each flight to estimate the variability of single-flight-based flux estimates. In Los Angeles (LA) County, the uncertainties on CO and NOx fluxes were 10% and 15%, respectively. Compared with NEI 2005, the CO posterior emissions were lower by 43% ± 6% in LA County and by 37% ± 10% in the South Coast Air Basin (SoCAB). NOx posterior emissions were lower by 32% ± 10% in LA County and by 27% ± 15% in the SoCAB. NOx posterior emissions were 40% lower on weekends relative to weekdays. The CO2 posterior estimates were 183 ± 18 Tg yr-1 in SoCAB. A flight during ITCT in 2002 was used to estimate emissions in the LA Basin in 2002. From 2002 to 2010, the CO and NOx posterior emissions decreased by 41% and 37%, respectively, in agreement with previous studies. Over the same time period, CO2 emissions increased by 10% ± 14% in LA County but decreased by 4% ± 10% in the SoCAB, a statistically insignificant change. Overall, the posterior estimates were in good agreement with the California Air Resources Board (CARB) inventory, with differences of 15% or less. However, the posterior spatial distribution in the basin was significantly different from CARB for NOx emissions. WRF-Chem mesoscale chemical-transport model simulations allowed an evaluation of differences in chemistry using different inventory assumptions, including NEI 2005, CARB 2010 and the posterior inventories derived in

Experimental Assessment of the Emissions Control Potential of a Rich/Quench/Lean Combustor for High Speed Civil Transport Aircraft Engines

NASA Technical Reports Server (NTRS)

Rosfjord, T. J.; Padget, F. C.; Tacina, Robert R. (Technical Monitor)

2001-01-01

In support of Pratt & Whitney efforts to define the Rich burn/Quick mix/Lean burn (RQL) combustor for the High Speed Civil Transport (HSCT) aircraft engine, UTRC conducted a flametube-scale study of the RQL concept. Extensive combustor testing was performed at the Supersonic Cruise (SSC) condition of a HSCT engine cycle, Data obtained from probe traverses near the exit of the mixing section confirmed that the mixing section was the critical component in controlling combustor emissions. Circular-hole configurations, which produced rapidly-, highly-penetrating jets, were most effective in limiting NOx. The spatial profiles of NOx and CO at the mixer exit were not directly interpretable using a simple flow model based on jet penetration, and a greater understanding of the flow and chemical processes in this section are required to optimize it. Neither the rich-combustor equivalence ratio nor its residence time was a direct contributor to the exit NOx. Based on this study, it was also concluded that (1) While NOx formation in both the mixing section and the lean combustor contribute to the overall emission, the NOx formation in the mixing section dominates. The gas composition exiting the rich combustor can be reasonably represented by the equilibrium composition corresponding to the rich combustor operating condition. Negligible NOx exits the rich combustor. (2) At the SSC condition, the oxidation processes occurring in the mixing section consume 99 percent of the CO exiting the rich combustor. Soot formed in the rich combustor is also highly oxidized, with combustor exit SAE Smoke Number <3. (3) Mixing section configurations which demonstrated enhanced emissions control at SSC also performed better at part-power conditions. Data from mixer exit traverses reflected the expected mixing behavior for off-design jet to crossflow momentum-flux ratios. (4) Low power operating conditions require that the RQL combustor operate as a lean-lean combustor to achieve low CO and

Experimental Assessment of the Emissions Control Potential of a Rich/Quench/ Lean Combustor for High Speed Civil Transport Aircraft Engines

NASA Technical Reports Server (NTRS)

Tacina, Robert R. (Technical Monitor); Rosfjord, T. J.; Padget, F. C.

2001-01-01

In support of Pratt & Whitney efforts to define the Rich burn/Quick mix/Lean burn (RQL) combustor for the High Speed Civil Transport (HSCT) aircraft engine, UTRC conducted a flametube-scale study of the RQL concept. Extensive combustor testing was performed at the Supersonic Cruise (SSC) condition of an HSCT engine cycle. Data obtained from probe traverses near the exit of the mixing section confirmed that the mixing section was the critical component in controlling combustor emissions. Circular-hole configurations, which produced rapidly-, highly-penetrating jets, were most effective in limiting NO(x). The spatial profiles of NO(x) and CO at the mixer exit were not directly interpretable using a simple flow model based on jet penetration, and a greater understanding of the flow and chemical processes in this section are required to optimize it. Neither the rich-combustor equivalence ratio nor its residence time was a direct contributor to the exit NO(x). Based on this study, it was also concluded that: (1) While NO(x) formation in both the mixing section and the lean combustor contribute to the overall emission, the NOx formation in the mixing section dominates. The gas composition exiting the rich combustor can be reasonably represented by the equilibrium composition corresponding to the rich combustor operating condition. Negligible NO(x) exits the rich combustor. (2) At the SSC condition, the oxidation processes occurring in the mixing section consume 99 percent of the CO exiting the rich combustor. Soot formed in the rich combustor is also highly oxidized, with combustor exit SAE Smoke Number <3. (3) Mixing section configurations which demonstrated enhanced emissions control at SSC also performed better at part-power conditions. Data from mixer exit traverses reflected the expected mixing behavior for off-design jet to crossflow momentum-flux ratios. (4) Low power operating conditions require that the RQL combustor operate as a lean-lean combustor to achieve

Jet aircraft emissions during cruise: Present and future

NASA Technical Reports Server (NTRS)

Grobman, J. S.

1975-01-01

Forecasts of engine exhaust emissions that may be practicably achievable for future commercial aircraft operating at high altitude cruise conditions are compared to cruise emission for present day aircraft. The forecasts are based on: (1) knowledge of emission characteristics of combustors and augmentors; (2) combustion research in emission reduction technology, and (3) trends in projected engine designs for advanced subsonic or supersonic commercial aircraft. Recent progress that was made in the evolution of emissions reduction technology is discussed.

Low NOx, Lean Direct Wall Injection Combustor Concept Developed

NASA Technical Reports Server (NTRS)

Tacina, Robert R.; Wey, Changlie; Choi, Kyung J.

2003-01-01

The low-emissions combustor development at the NASA Glenn Research Center is directed toward advanced high-pressure aircraft gas turbine applications. The emphasis of this research is to reduce nitrogen oxides (NOx) at high-power conditions and to maintain carbon monoxide and unburned hydrocarbons at their current low levels at low-power conditions. Low-NOx combustors can be classified into rich burn and lean burn concepts. Lean burn combustors can be further classified into lean-premixed-prevaporized (LPP) and lean direct injection (LDI) combustors. In both concepts, all the combustor air, except for liner cooling flow, enters through the combustor dome so that the combustion occurs at the lowest possible flame temperature. The LPP concept has been shown to have the lowest NOx emissions, but for advanced high-pressure-ratio engines, the possibly of autoignition or flashback precludes its use. LDI differs from LPP in that the fuel is injected directly into the flame zone and, thus, does not have the potential for autoignition or flashback and should have greater stability. However, since it is not premixed and prevaporized, the key is good atomization and mixing of the fuel quickly and uniformly so that flame temperatures are low and NOx formation levels are comparable to those of LPP.

Comparison and evaluation of anthropogenic emissions of SO2 and NOx over China

NASA Astrophysics Data System (ADS)

Li, Meng; Klimont, Zbigniew; Zhang, Qiang; Martin, Randall V.; Zheng, Bo; Heyes, Chris; Cofala, Janusz; Zhang, Yuxuan; He, Kebin

2018-03-01

Bottom-up emission inventories provide primary understanding of sources of air pollution and essential input of chemical transport models. Focusing on SO2 and NOx, we conducted a comprehensive evaluation of two widely used anthropogenic emission inventories over China, ECLIPSE and MIX, to explore the potential sources of uncertainties and find clues to improve emission inventories. We first compared the activity rates and emission factors used in two inventories and investigated the reasons of differences and the impacts on emission estimates. We found that SO2 emission estimates are consistent between two inventories (with 1 % differences), while NOx emissions in ECLIPSE's estimates are 16 % lower than those of MIX. The FGD (flue-gas desulfurization) device penetration rate and removal efficiency, LNB (low-NOx burner) application rate and abatement efficiency in power plants, emission factors of industrial boilers and various vehicle types, and vehicle fleet need further verification. Diesel consumptions are quite uncertain in current inventories. Discrepancies at the sectorial and provincial levels are much higher than those of the national total. We then examined the impacts of different inventories on model performance by using the nested GEOS-Chem model. We finally derived top-down emissions by using the retrieved columns from the Ozone Monitoring Instrument (OMI) compared with the bottom-up estimates. High correlations were observed for SO2 between model results and OMI columns. For NOx, negative biases in bottom-up gridded emission inventories (-21 % for MIX, -39 % for ECLIPSE) were found compared to the satellite-based emissions. The emission trends from 2005 to 2010 estimated by two inventories were both consistent with satellite observations. The inventories appear to be fit for evaluation of the policies at an aggregated or national level; more work is needed in specific areas in order to improve the accuracy and robustness of outcomes at finer spatial

NOx Emissions from Large Point Sources: Variability in Ozone Production, Resulting Health Damages and Economic Costs

NASA Astrophysics Data System (ADS)

Mauzerall, D. L.; Sultan, B.; Kim, N.; Bradford, D.

2004-12-01

We present a proof-of-concept analysis of the measurement of the health damage of ozone (O3) produced from nitrogen oxides (NOx = NO + NO2) emitted by individual large point sources in the eastern United States. We use a regional atmospheric model of the eastern United States, the Comprehensive Air Quality Model with Extensions (CAMx), to quantify the variable impact that a fixed quantity of NOx emitted from individual sources can have on the downwind concentration of surface O3, depending on temperature and local biogenic hydrocarbon emissions. We also examine the dependence of resulting ozone-related health damages on the size of the exposed population. The investigation is relevant to the increasingly widely used "cap and trade" approach to NOx regulation, which presumes that shifts of emissions over time and space, holding the total fixed over the course of the summer O3 season, will have minimal effect on the environmental outcome. By contrast, we show that a shift of a unit of NOx emissions from one place or time to another could result in large changes in the health effects due to ozone formation and exposure. We indicate how the type of modeling carried out here might be used to attach externality-correcting prices to emissions. Charging emitters fees that are commensurate with the damage caused by their NOx emissions would create an incentive for emitters to reduce emissions at times and in locations where they cause the largest damage.

Model Calculations of the Impact of NO(x) from Air Traffic, Lightning and Surface Emissions, Compared with Measurements

NASA Technical Reports Server (NTRS)

Meijer, E. W.; vanVelthoven, P. F. J.; Thompson, A. M.; Pfister, L.; Schlager, H.; Schulte, P.; Kelder, H.

1999-01-01

The impact of NO(x) from aircraft emissions, lightning and surface contributions on atmospheric nitrogen oxides and ozone has been investigated with the three-dimensional global chemistry transport model TM3 by partitioning the nitrogen oxides and ozone according to source category. The results have been compared with POLINAT II and SONEX airborne measurements in the North Atlantic flight corridor in 1997. Various cases have been investigated: measurements during a stagnant anti-cyclone and an almost cut-off low, both with expected high aircraft contributions, a southward bound flight with an expected strong flight corridor gradient and lightning contributions in the South, and a transatlantic flight with expected boundary layer pollution near the U.S. coast. The agreement between modeled results and measurements is reasonably good for NO and ozone. Also, the calculated impact of the three defined sources were consistent with the estimated exposure of the sampled air to these sources, obtained by specialized back-trajectory model products.

Allocating emissions to 4 km and 1 km horizontal spatial resolutions and its impact on simulated NOx and O3 in Houston, TX

NASA Astrophysics Data System (ADS)

Pan, Shuai; Choi, Yunsoo; Roy, Anirban; Jeon, Wonbae

2017-09-01

A WRF-SMOKE-CMAQ air quality modeling system was used to investigate the impact of horizontal spatial resolution on simulated nitrogen oxides (NOx) and ozone (O3) in the Greater Houston area (a non-attainment area for O3). We employed an approach recommended by the United States Environmental Protection Agency to allocate county-based emissions to model grid cells in 1 km and 4 km horizontal grid resolutions. The CMAQ Integrated Process Rate analyses showed a substantial difference in emissions contributions between 1 and 4 km grids but similar NOx and O3 concentrations over urban and industrial locations. For example, the peak NOx emissions at an industrial and urban site differed by a factor of 20 for the 1 km and 8 for the 4 km grid, but simulated NOx concentrations changed only by a factor of 1.2 in both cases. Hence, due to the interplay of the atmospheric processes, we cannot expect a similar level of reduction of the gas-phase air pollutants as the reduction of emissions. Both simulations reproduced the variability of NASA P-3B aircraft measurements of NOy and O3 in the lower atmosphere (from 90 m to 4.5 km). Both simulations provided similar reasonable predictions at surface, while 1 km case depicted more detailed features of emissions and concentrations in heavily polluted areas, such as highways, airports, and industrial regions, which are useful in understanding the major causes of O3 pollution in such regions, and to quantify transport of O3 to populated communities in urban areas. The Integrated Reaction Rate analyses indicated a distinctive difference of chemistry processes between the model surface layer and upper layers, implying that correcting the meteorological conditions at the surface may not help to enhance the O3 predictions. The model-observation O3 bias in our studies (e.g., large over-prediction during the nighttime or along Gulf of Mexico coastline), were due to uncertainties in meteorology, chemistry or other processes. Horizontal grid

Field test of available methods to measure remotely SOx and NOx emissions from ships

NASA Astrophysics Data System (ADS)

Balzani Lööv, J. M.; Alfoldy, B.; Gast, L. F. L.; Hjorth, J.; Lagler, F.; Mellqvist, J.; Beecken, J.; Berg, N.; Duyzer, J.; Westrate, H.; Swart, D. P. J.; Berkhout, A. J. C.; Jalkanen, J.-P.; Prata, A. J.; van der Hoff, G. R.; Borowiak, A.

2014-08-01

Methods for the determination of ship fuel sulphur content and NOx emission factors based on remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, Differential Optical Absorption Spectroscopy (DOAS), UV camera), combined with model-based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the land-based ones because they allow optimizing the sampling conditions and sampling from ships on the open sea. Although optical methods can provide reliable results it was found that at the state of the art level, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

Effect of Air Temperature and Relative Humidity at Various Fuel-Air Ratios on Exhaust Emissions on a Per-Mode Basis of an AVCO Lycoming 0-320 Diad Light Aircraft Engine: Volume 1: Results and Plotted Data

NASA Technical Reports Server (NTRS)

Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempe, E. E., Jr.

1978-01-01

A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions include carburetor lean out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity.

Emissions of NOx, SO2, CO, and HCHO from commercial marine shipping during Texas Air Quality Study (TexAQS) 2006

NASA Astrophysics Data System (ADS)

Williams, E. J.; Lerner, B. M.; Murphy, P. C.; Herndon, S. C.; Zahniser, M. S.

2009-11-01

We report measurements of NOx, SO2, CO, and HCHO mass-based emission factors from more than 200 commercial vessel encounters in the Gulf of Mexico and the Houston-Galveston region of Texas during August and September, 2006. For underway ships, bulk freight carriers have the highest average NOx emissions at ˜87 g NOx (kg fuel)-1, followed by tanker ships at ˜79 g NOx (kg fuel)-1, while container carriers, passenger ships, and tugs all emit an average of about ˜60 g NOx (kg fuel)-1. Emission of NOx from stationary vessels was lower, except for container ships and tugs, and likely reflects use of medium-speed diesel engines. Overall, our mean NOx emission factors are 10-15% lower than published data. Average emission of SO2 was lower for passenger ships and tugs and tows (6-7 g SO2 (kg fuel)-1) than for larger cargo vessels (20-30 g SO2 (kg fuel)-1). Our data for large cargo ships in this region indicate an average residual fuel sulfur content of ˜1.4% which is a factor of two lower than the global average of 2.7%. Emission of CO was low for all categories (7-16 g CO (kg fuel)-1), although our mean overall CO emission factor is about 10% higher than published data. Emission of HCHO was less than 5% that of CO. Despite considerable variability, no functional relationships, such as emissions changes with engine speed or load, could be discerned. Comparison of emission factors from ships to those from other sources suggests ship emissions in this region cannot be ignored.

Impact of Ship Emissions on Marine Boundary Layer NO(x) and SO2 Distributions over the Pacific Basin

NASA Technical Reports Server (NTRS)

Davis, D. D.; Grodzinsky, G.; Kasibhatla, P.; Crawford, J.; Chen, G.; Liu, S.; Bandy, A.; Thornton, D.; Guan, H.; Sandholm, S.

2001-01-01

The impact of ship emissions on marine boundary layer (MBL) NO(x) and SO2 levels over the Pacific Ocean has been explored by comparing predictions (with and without ships) from a global chemical transport model (GCTM) against compiled airborne observations of MBL NO(x) and SO2. For latitudes above 15 N, which define that part of the Pacific having the heaviest shipping, this analysis revealed significant model over prediction for NOx and a modest under prediction for SO2 when ship emissions were considered. Possible reasons for the difference in NO(x) and SO2 were explored using a full-chemistry box model. These results revealed that for an actual plume setting the NO(x) lifetime could be greatly shortened by chemical processes promoted by ship plume emissions themselves. Similar chemical behavior was not found for SO2.

A Low NO(x) Lean-Direct Injection, Multipoint Integrated Module Combuster Concept for Advanced Aircraft Gas Turbines

NASA Technical Reports Server (NTRS)

Tacina, Robert; Wey, Changlie; Laing, Peter; Mansour, Adel

2002-01-01

A low NO(x) emissions combustor has been demonstrated in flame-tube tests. A multipoint, lean-direct injection concept was used. Configurations were tested that had 25- and 36- fuel injectors in the size of a conventional single fuel injector. An integrated-module approach was used for the construction where chemically etched laminates, diffusion bonded together, combine the fuel injectors, air swirlers and fuel manifold into a single element. Test conditions were inlet temperatures up to 810 K, inlet pressures up to 2760 kPa, and flame temperatures up to 2100 K. A correlation was developed relating the NO(x) emissions with the inlet temperature, inlet pressure, fuel-air ratio and pressure drop. Assuming that 10 percent of the combustion air would be used for liner cooling and using a hypothetical engine cycle, the NO(x) emissions using the correlation from flame-tube tests were estimated to be less than 20 percent of the 1996 ICAO standard.

Characterization of emissions from commercial aircraft engines during the Aircraft Particle Emissions eXperiment (APEX) 1 to 3

EPA Science Inventory

The fine particulate matter emissions from aircraft operations at large airports located in areas of the U. S. designated as non-attainment for the National Ambient Air Quality Standard for PM-2.5 are of major environmental concern. PM emissions data for commercial aircraft engin...

Global Partitioning of NOx Sources Using Satellite Observations: Relative Roles of Fossil Fuel Combustion, Biomass Burning and Soil Emissions

NASA Technical Reports Server (NTRS)

Jaegle, Lyatt; Steinberger, Linda; Martin, Randall V.; Chance, Kelly

2005-01-01

This document contains the following abstract for the paper "Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and soil emissions." Satellite observations have been used to provide important new information about emissions of nitrogen oxides. Nitrogen oxides (NOx) are significant in atmospheric chemistry, having a role in ozone air pollution, acid deposition and climate change. We know that human activities have led to a three- to six-fold increase in NOx emissions since pre-industrial times, and that there are three main surface sources of NOx: fuel combustion, large-scale fires, and microbial soil processes. How each of these sources contributes to the total NOx emissions is subject to some doubt, however. The problem is that current NOx emission inventories rely on bottom-up approaches, compiling large quantities of statistical information from diverse sources such as fuel and land use, agricultural data, and estimates of burned areas. This results in inherently large uncertainties. To overcome this, Lyatt Jaegle and colleagues from the University of Washington, USA, used new satellite observations from the Global Ozone Monitoring Experiment (GOME) instrument. As the spatial and seasonal distribution of each of the sources of NOx can be clearly mapped from space, the team could provide independent topdown constraints on the individual strengths of NOx sources, and thus help resolve discrepancies in existing inventories. Jaegle's analysis of the satellite observations, presented at the recent Faraday Discussion on "Atmospheric Chemistry", shows that fuel combustion dominates emissions at northern mid-latitudes, while fires are a significant source in the Tropics. Additionally, she discovered a larger than expected role for soil emissions, especially over agricultural regions with heavy fertilizer use. Additional information is included in the original extended abstract.

Regional Attribution of Ozone Production and Associated Radiative Forcing: a Step to Crediting NOx Emission Reductions

NASA Astrophysics Data System (ADS)

Naik, V.; Mauzerall, D. L.; Horowitz, L.; Schwarzkopf, D.; Ramaswamy, V.; Oppenheimer, M.

2004-12-01

The global distribution of tropospheric ozone (O3) depends on the location of emissions of its precursors in addition to chemical and dynamical factors. The global picture of O3 forcing is, therefore, a sum of regional forcings arising from emissions of precursors from different sources. The Kyoto Protocol does not include ozone as a greenhouse gas, and emission reductions of ozone precursors made under Kyoto or any similar agreement would presently receive no credit. In this study, we quantitatively estimate the contribution of emissions of nitrogen oxides (NOx), the primary limiting O3 precursor in the non-urban atmosphere, from specific countries and regions of the world to global O3 concentration distributions. We then estimate radiative forcing resulting from the regional perturbations of NOx emissions. This analysis is intended as an early step towards incorporating O3 into the Kyoto Protocol or any successor agreement. Under such a system countries could obtain credit for improvements in local air quality that result in reductions of O3 concentrations because of the associated reductions in radiative forcing. We use the global chemistry transport model, MOZART-2, to simulate the global O3 distribution for base year 1990 and perturbations to this distribution caused by a 10% percent reduction in the base emissions of NOx from the United States, Europe, East Asia, India, South America, and Africa. We calculate the radiative forcing for the simulated base and perturbed O3 distributions using the GFDL radiative transfer model. The difference between the radiative forcing from O3 for the base and perturbed distributions provides an estimate of the marginal radiative forcing from a region's emissions of NOx. We will present a quantitative analysis of the magnitude, spatial, and temporal distribution of radiative forcing resulting from marginal changes in the NOx emissions from each region.

Wetting-induced pulses produced unexpectedly high emissions of N2O and NOx in a desert ecosystem

NASA Astrophysics Data System (ADS)

Eberwein, J. R.; Carey, C.; Aronson, E. L.; Jenerette, D.

2015-12-01

Approximately one third of Earth's land surface is subjected to arid conditions, and aridland soils have the potential for significant feedbacks to global climate change drivers, such as anthropogenic nitrogen deposition. This study examined wetting-induced pulses of N2O and NOx along a nitrogen deposition gradient in the Colorado Desert of southern California. Measurements were made before and following water (to simulate a 2 cm rain event) and nitrogen plus water additions (30 kg NH4NO3 ha-1) at 15 minutes, 12 hours and 24 hours post-wetting. We found nitrogenous fluxes that were substantially higher than expected. N2O fluxes, in particular were remarkably high reaching up to 200 ng N2O-N m-2 s-1, similar to agriculture levels and in the range of peat bog emissions. There was a clear transition between N2O emissions, which peaked 15 minutes after wetting, and NOx emissions, which peaked at the 12 hour timepoint. NOx emissions were also considerable, reaching as high as 350 ng NOx-N m-2 s-1. Both N2O and NOx fluxes responded strongly to water additions, demonstrating a clear wetting-induced pulse response. While N2O was not affected by nitrogen additions, NOx fluxes demonstrated a significant increase with nitrogen plus water over water alone (p=0.016). These results suggest that gaseous nitrogen export, particularly N2O emissions, is a greater form of nitrogen loss in arid systems than is currently assumed. This potential for high nitrogen emissions and the capacity for anthropogenic nitrogen deposition to increase these emissions present serious implications for local air quality and significant soil feedbacks to climate change.

Overall evaluation of combustion and NO(x) emissions for a down-fired 600 MW(e) supercritical boiler with multiple injection and multiple staging.

PubMed

Kuang, Min; Li, Zhengqi; Liu, Chunlong; Zhu, Qunyi

2013-05-07

To achieve significant reductions in NOx emissions and to eliminate strongly asymmetric combustion found in down-fired boilers, a deep-air-staging combustion technology was trialed in a down-fired 600 MWe supercritical utility boiler. By performing industrial-sized measurements taken of gas temperatures and species concentrations in the near wing-wall region, carbon in fly ash and NOx emissions at various settings, effects of overfire air (OFA) and staged-air damper openings on combustion characteristics, and NOx emissions within the furnace were experimentally determined. With increasing the OFA damper opening, both fluctuations in NOx emissions and carbon in fly ash were initially slightly over OFA damper openings of 0-40% but then lengthened dramatically in openings of 40-70% (i.e., NOx emissions reduced sharply accompanied by an apparent increase in carbon in fly ash). Decreasing the staged-air declination angle clearly increased the combustible loss but slightly influenced NOx emissions. In comparison with OFA, the staged-air influence on combustion and NOx emissions was clearly weaker. Only at a high OFA damper opening of 50%, the staged-air effect was relatively clear, i.e., enlarging the staged-air damper opening decreased carbon in fly ash and slightly raised NOx emissions. By sharply opening the OFA damper to deepen the air-staging conditions, although NOx emissions could finally reduce to 503 mg/m(3) at 6% O2 (i.e., an ultralow NOx level for down-fired furnaces), carbon in fly ash jumped sharply to 15.10%. For economical and environment-friendly boiler operations, an optimal damper opening combination (i.e., 60%, 50%, and 50% for secondary air, staged-air, and OFA damper openings, respectively) was recommended for the furnace, at which carbon in fly ash and NOx emissions attained levels of about 10% and 850 mg/m(3) at 6% O2, respectively.

Influence of enhanced Asian NOx emissions on ozone in the upper troposphere and lower stratosphere in chemistry-climate model simulations

NASA Astrophysics Data System (ADS)

Roy, Chaitri; Fadnavis, Suvarna; Müller, Rolf; Ayantika, D. C.; Ploeger, Felix; Rap, Alexandru

2017-01-01

The Asian summer monsoon (ASM) anticyclone is the most pronounced circulation pattern in the upper troposphere and lower stratosphere (UTLS) during northern hemispheric summer. ASM convection plays an important role in efficient vertical transport from the surface to the upper-level anticyclone. In this paper we investigate the potential impact of enhanced anthropogenic nitrogen oxide (NOx) emissions on the distribution of ozone in the UTLS using the fully coupled aerosol-chemistry-climate model, ECHAM5-HAMMOZ. Ozone in the UTLS is influenced both by the convective uplift of ozone precursors and by the uplift of enhanced-NOx-induced tropospheric ozone anomalies. We performed anthropogenic NOx emission sensitivity experiments over India and China. In these simulations, covering the years 2000-2010, anthropogenic NOx emissions have been increased by 38 % over India and by 73 % over China with respect to the emission base year 2000. These emission increases are comparable to the observed linear trends of 3.8 % per year over India and 7.3 % per year over China during the period 2000 to 2010. Enhanced NOx emissions over India by 38 % and China by 73 % increase the ozone radiative forcing in the ASM anticyclone (15-40° N, 60-120° E) by 16.3 and 78.5 mW m-2 respectively. These elevated NOx emissions produce significant warming over the Tibetan Plateau and increase precipitation over India due to a strengthening of the monsoon Hadley circulation. However, increase in NOx emissions over India by 73 % (similar to the observed increase over China) results in large ozone production over the Indo-Gangetic Plain and Tibetan Plateau. The higher ozone concentrations, in turn, induce a reversed monsoon Hadley circulation and negative precipitation anomalies over India. The associated subsidence suppresses vertical transport of NOx and ozone into the ASM anticyclone.

Wildfire and soil emissions of NOx and their consequences for ozone observed at a remote mountaintop site in Central California

NASA Astrophysics Data System (ADS)

Asher, E. C. C.; Caputi, D.; Conley, S. A.; Faloona, I. C.

2016-12-01

Nitric oxide (NOx) emissions contribute to the production of tropospheric ozone and the nutrient supply fueling primary production. Current global estimates indicate that biomass burning, including wildfires, and soil emissions represent 15 - 25 % of the total emissions. Yet estimates suggest that in North America during the summer, natural sources, including biomass burning, soil emissions and lightning, are responsible for nearly half of total emissions. Thus, as domestic air quality standards grow stricter and anthropogenic sources more regulated, constraining natural sources of NOx becomes critical. NOx concentrations in wildfire smoke differ based on the age of the plume, fire intensity and vegetation type. NOx soil emissions depend on soil moisture, soil temperature, soil porosity, and nitrogen storage. We present two years of NOx and ozone (O3) measurements from a remote mountaintop monitoring site located on Chews Ridge in the coastal mountains of Central California, airborne observations, and remotely sensed NO2 tropospheric columns retrieved using the Ozone Monitoring Instrument (OMI). We explore controls on NOx concentrations at Chews Ridge, in Monterey County, such as the age of wildfire smoke plumes and wildfire intensity (i.e. burning vs. smoldering), as well as soil moisture and precipitation, which can lead to pulsed NOx fluxes. Most recently our in situ observations fortuitously captured differing amounts of the active plume of the Soberanes wildfire, which to date has burned >45,000 acres and is expected to continue partially contained through August 2016. Implications of these episodic sources of NOx on the regional ozone budget will be discussed.

Implications of near-term coal power plant retirement for SO2 and NOX and life cycle GHG emissions.

PubMed

Venkatesh, Aranya; Jaramillo, Paulina; Griffin, W Michael; Matthews, H Scott

2012-09-18

Regulations monitoring SO(2), NO(X), mercury, and other metal emissions in the U.S. will likely result in coal plant retirement in the near-term. Life cycle assessment studies have previously estimated the environmental benefits of displacing coal with natural gas for electricity generation, by comparing systems that consist of individual natural gas and coal power plants. However, such system comparisons may not be appropriate to analyze impacts of coal plant retirement in existing power fleets. To meet this limitation, simplified economic dispatch models for PJM, MISO, and ERCOT regions are developed in this study to examine changes in regional power plant dispatch that occur when coal power plants are retired. These models estimate the order in which existing power plants are dispatched to meet electricity demand based on short-run marginal costs, with cheaper plants being dispatched first. Five scenarios of coal plant retirement are considered: retiring top CO(2) emitters, top NO(X) emitters, top SO(2) emitters, small and inefficient plants, and old and inefficient plants. Changes in fuel use, life cycle greenhouse gas emissions (including uncertainty), and SO(2) and NO(X) emissions are estimated. Life cycle GHG emissions were found to decrease by less than 4% in almost all scenarios modeled. In addition, changes in marginal damage costs due to SO(2), and NO(X) emissions are estimated using the county level marginal damage costs reported in the Air Pollution Emissions Experiments and Policy (APEEP) model, which are a proxy for measuring regional impacts of SO(2) and NO(X) emissions. Results suggest that location specific parameters should be considered within environmental policy frameworks targeting coal plant retirement, to account for regional variability in the benefits of reducing the impact of SO(2) and NO(X) emissions.

Impact of passenger car NOx emissions and NO2 fractions on urban NO2 pollution - Scenario analysis for the city of Antwerp, Belgium

NASA Astrophysics Data System (ADS)

Degraeuwe, Bart; Thunis, Philippe; Clappier, Alain; Weiss, Martin; Lefebvre, Wouter; Janssen, Stijn; Vranckx, Stijn

2016-02-01

The annual NO2 concentrations in many European cities exceed the established air quality standard. This situation is mainly caused by Diesel cars whose NOx emissions are higher on the road than during type approval in the laboratory. Moreover, the fraction of NO2 in the NOx emissions of modern diesel cars appears to have increased as compared to previous models. In this paper, we assess 1) to which level the distance-specific NOx emissions of Diesel cars should be reduced to meet established air quality standards and 2) if it would be useful to introduce a complementary NO2 emissions limit. We develop a NO2 pollution model that accounts in an analysis of 9 emission scenarios for changes in both, the urban background NO2 concentrations and the local NO2 emissions at street level. We apply this model to the city of Antwerp, Belgium. The results suggest that a reduction in NOx emissions decreases the regional and urban NO2 background concentration; high NO2 fractions increase the ambient NO2 concentrations only in close spatial proximity to the emission source. In a busy access road to the city centre, the average NO2 concentration can be reduced by 23% if Diesel cars emitted 0.35 g NOx/km instead of the current 0.62 g NOx/km. Reductions of 45% are possible if the NOX emissions of Diesel cars decreased to the level of gasoline cars (0.03 g NOx/km). Our findings suggest that the Real-Driving Emissions (RDE) test procedure can solve the problem of NO2 exceedances in cities if it reduced the on-road NOx emissions of diesel cars to the permissible limit of 0.08 g/km. The implementation of a complementary NO2 emissions limit may then become superfluous. If Diesel cars continue to exceed by several factors their NOx emissions limit on the road, a shift of the vehicle fleet to gasoline cars may be necessary to solve persisting air quality problems.

Potential Environmental Effects of Aircraft Emissions.

DTIC Science & Technology

1979-10-15

and fleet projections used by Oliver et al. (1977) in their Table 2-33. The projection used by Oliver et al. (1977) was based on A. D. Little, Inc...than used by A. D. Little, Inc. (1976) for CF6 engines (which Oliver et al., 1977, treated as having the same emissions indexes as JT9D engines). The NO...x emission index for SSrs was assumed to be 20 g NO 2 /kg fuel. In converting the projected emissions in Table 2.33 of Oliver et al. (1977) to a

Airborne Flux Measurements of Volatile Organic Compounds and NOx over a European megacity

NASA Astrophysics Data System (ADS)

Shaw, Marvin; Lee, James; Davison, Brian; Misztal, Pawel; Karl, Thomas; Hewitt, Nick; Lewis, Alistair

2014-05-01

Ground level ozone (O3) and nitrogen dioxide (NO2) are priority pollutants whose concentrations are closely regulated by European Union Air Quality Directive 2008/50/EC. O3 is a secondary pollutant, produced from a complex chemical interplay between oxides of nitrogen (NOx = NO + NO2) and volatile organic compounds (VOCs). Whilst the basic atmospheric chemistry leading to O3 formation is generally well understood, there are substantial uncertainties associated with the magnitude of emissions of both VOCs and NOx. At present our knowledge of O3 precursor emissions in the UK is primarily derived from National Atmospheric Emission inventories (NAEI) that provide spatially disaggregated estimates at 1x1km resolution, and these are not routinely tested at city or regional scales. Uncertainties in emissions propagate through into uncertainties in predictions of air quality in the future, and hence the likely effectiveness of control policies on both background and peak O3 and NO2 concentrations in the UK. The Ozone Precursor Fluxes in the Urban Environment (OPFUE) project aims to quantify emission rates for NOx and selected VOCs in and around the megacity of London using airborne eddy covariance (AEC). The mathematical foundation for AEC has been extensively reviewed and AEC measurements of ozone, dimethyl sulphide, CO2 and VOCs have been previously reported. During the summer of 2013, approximately 30 hours of airborne flux measurements of toluene, benzene, NO and NO2 were obtained from the NERC Airborne Research and Survey Facility's (ARSF) Dornier-228 aircraft. Over SE England, flights involved repeated south west to north east transects of ~50 km each over Greater London and it's surrounding suburbs and rural areas, flying at the aircraft's minimum operating flight altitude and airspeed (~300m, 80m/s). Mixing ratios of benzene and toluene were acquired at 2Hz using a proton transfer reaction mass spectrometer (PTR-MS) and compared to twice hourly whole air canister

New methodology for modeling annual-aircraft emissions at airports

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woodmansey, B.G.; Patterson, J.G.

An as-accurate-as-possible estimation of total-aircraft emissions are an essential component of any environmental-impact assessment done for proposed expansions at major airports. To determine the amount of emissions generated by aircraft using present models it is necessary to know the emission characteristics of all engines that are on all planes using the airport. However, the published data base does not cover all engine types and, therefore, a new methodology is needed to assist in estimating annual emissions from aircraft at airports. Linear regression equations relating quantity of emissions to aircraft weight using a known-fleet mix are developed in this paper. Total-annualmore » emissions for CO, NO[sub x], NMHC, SO[sub x], CO[sub 2], and N[sub 2]O are tabulated for Toronto's international airport for 1990. The regression equations are statistically significant for all emissions except for NMHC from large jets and NO[sub x] and NMHC for piston-engine aircraft. This regression model is a relatively simple, fast, and inexpensive method of obtaining an annual-emission inventory for an airport.« less

Field test of available methods to measure remotely SO2 and NOx emissions from ships

NASA Astrophysics Data System (ADS)

Balzani Lööv, J. M.; Alfoldy, B.; Beecken, J.; Berg, N.; Berkhout, A. J. C.; Duyzer, J.; Gast, L. F. L.; Hjorth, J.; Jalkanen, J.-P.; Lagler, F.; Mellqvist, J.; Prata, F.; van der Hoff, G. R.; Westrate, H.; Swart, D. P. J.; Borowiak, A.

2013-11-01

Methods for the determination of ship fuel sulphur content and NOx emission factors from remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, DOAS, UV camera), combined with model based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat, and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the landbased ones because they allow to optimize the sampling conditions and to sample from ships on the open sea. Although optical methods can provide reliable results, it was found that at the state of the art, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

NOx Emission Reduction and its Effects on Ozone during the 2008 Olympic Games

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Qing; Wang, Yuhang; Zhao, Chun

2011-07-15

We applied a daily-assimilated inversion method to estimate NOx (NO+NO2) emissions for June-September 2007 and 2008 on the basis of the Aura Ozone Monitoring Instrument (OMI) observations of nitrogen dioxide (NO2) and model simulations using the Regional chEmistry and trAnsport Model (REAM). Over urban Beijing, rural Beijing, and the Huabei Plain, OMI column NO2 reductions are approximately 45%, 33%, and 14%, respectively, while the corresponding anthropogenic NOx emission reductions are only 28%, 24%, and 6%, during the full emission control period (July 20 – Sep 20, 2008). The emission reduction began in early July and was in full force bymore » July 20, corresponding to the scheduled implementation of emission controls over Beijing. The emissions did not appear to recover after the emission control period. Meteorological change from summer 2007 to 2008 is the main factor contributing to the column NO2 decreases not accounted for by the emission reduction. Model simulations suggest that the effect of emission reduction on ozone concentrations over Beijing is relatively minor using a standard VOC emission inventory in China. With an adjustment of the model emissions to reflect in situ observations of VOCs in Beijing, the model simulation suggests a larger effect of the emission reduction.« less

40 CFR 75.71 - Specific provisions for monitoring NOX and heat input for the purpose of calculating NOX mass...

Code of Federal Regulations, 2010 CFR

2010-07-01

... and heat input for the purpose of calculating NOX mass emissions. 75.71 Section 75.71 Protection of... MONITORING NOX Mass Emissions Provisions § 75.71 Specific provisions for monitoring NOX and heat input for the purpose of calculating NOX mass emissions. (a) Coal-fired units. The owner or operator of a coal...

PM, NOx and butane emissions from on-road vehicle fleets in Hong Kong and their implications on emission control policy

NASA Astrophysics Data System (ADS)

Ning, Zhi; Wubulihairen, Maimaitireyimu; Yang, Fenhuan

2012-12-01

Vehicular emissions are the major sources of air pollution in urban areas. For metropolitan cities with large population working and living in environments with direct traffic impact, emission control is of great significance to protect public health. Implementation of more stringent emission standards, retrofitting fleet with emission control devices and switching to clearer fuel has been commonly practiced in different cities including Hong Kong. The present study employed a new plume chasing method for effective and quick evaluation of on-road fleet emission factors of particulate matter (PM), nitrogen oxides (NOx), and butane from heavy duty diesel trucks, diesel buses and liquefied petroleum gas (LPG) vehicles. The results showed distinct profiles of the emissions from different fleets with excessive butane emissions from LPG fleet and contrasting PM and NOx emissions from diesel trucks and buses fleets. A cross comparison was also made with emission data from other cities and from historic local studies. The implications of the observed difference on the effectiveness of emission control measures and policy are discussed with recommendations of direction for future research and policy making.

Application of an EGR system in a direct injection diesel engine to reduce NOx emissions

NASA Astrophysics Data System (ADS)

De Serio, D.; De Oliveira, A.; Sodré, J. R.

2016-09-01

This work presents the application of an exhaust gas recirculation (EGR) system in a direct injection diesel engine operating with diesel oil containing 7% biodiesel (B7). EGR rates of up to 10% were applied with the primary aim to reduce oxides of nitrogen (NOx) emissions. The experiments were conducted in a 44 kW diesel power generator to evaluate engine performance and emissions for different load settings. The use of EGR caused a peak pressure reduction during the combustion process and a decrease in thermal efficiency, mainly at high engine loads. A reduction of NOx emissions of up to 26% was achieved, though penalizing carbon monoxide (CO) and total hydrocarbons (THC) emissions.

Analysis of aircraft exhausts with Fourier-transform infrared emission spectroscopy.

PubMed

Heland, J; Schäfer, K

1997-07-20

Because of the worldwide growth in air traffic and its increasing effects on the atmospheric environment, it is necessary to quantify the direct aircraft emissions at all altitudes. In this study Fourier-transform infrared emission spectroscopy as a remote-sensing multi-component-analyzing technique for aircraft exhausts was investigated at ground level with a double pendulum interferometer and a line-by-line computer algorithm that was applied to a multilayer radiative transfer problem. Initial measurements were made to specify the spectral windows for traceable compounds, to test the sensitivity of the system, and to develop calibration and continuum handling procedures. To obtain information about the radial temperature and concentration profiles, we developed an algorithm for the analysis of an axial-symmetric multilayered plume by use of the CO(2) hot band at approximately 2400 cm(-1). Measurements were made with several in-service engines. Effects that were due to engine aging were detected but have to be analyzed systematically in the near future. Validation measurements were carried out with a conventional propane gas burner to compare the results with those obtained with standard measurement equipment. These measurements showed good agreement to within +/-20% for the CO and NO(x) results. The overall accuracy of the system was found to be +/-30%. The detection limits of the system for a typical engine plume (380 degrees C, ? = 50 cm) are below 0.1% for CO(2), ~0.7% for H(2)O, ~20 ppmv (parts per million by volume) for CO, and ~90 ppmv for NO.

Multi-satellite sensor study on precipitation-induced emission pulses of NOx from soils in semi-arid ecosystems

NASA Astrophysics Data System (ADS)

Zörner, Jan; Penning de Vries, Marloes; Beirle, Steffen; Sihler, Holger; Veres, Patrick R.; Williams, Jonathan; Wagner, Thomas

2016-07-01

We present a top-down approach to infer and quantify rain-induced emission pulses of NOx ( ≡ NO + NO2), stemming from biotic emissions of NO from soils, from satellite-borne measurements of NO2. This is achieved by synchronizing time series at single grid pixels according to the first day of rain after a dry spell of prescribed duration. The full track of the temporal evolution several weeks before and after a rain pulse is retained with daily resolution. These are needed for a sophisticated background correction, which accounts for seasonal variations in the time series and allows for improved quantification of rain-induced soil emissions. The method is applied globally and provides constraints on pulsed soil emissions of NOx in regions where the NOx budget is seasonally dominated by soil emissions. We find strong peaks of enhanced NO2 vertical column densities (VCDs) induced by the first intense precipitation after prolonged droughts in many semi-arid regions of the world, in particular in the Sahel. Detailed investigations show that the rain-induced NO2 pulse detected by the OMI (Ozone Monitoring Instrument), GOME-2 and SCIAMACHY satellite instruments could not be explained by other sources, such as biomass burning or lightning, or by retrieval artefacts (e.g. due to clouds). For the Sahel region, absolute enhancements of the NO2 VCDs on the first day of rain based on OMI measurements 2007-2010 are on average 4 × 1014  molec cm-2 and exceed 1 × 1015  molec cm-2 for individual grid cells. Assuming a NOx lifetime of 4 h, this corresponds to soil NOx emissions in the range of 6 up to 65 ng N m-2 s-1, which is in good agreement with literature values. Apart from the clear first-day peak, NO2 VCDs are moderately enhanced (2 × 1014  molec cm-2) compared to the background over the following 2 weeks, suggesting potential further emissions during that period of about 3.3 ng N m-2 s-1

Aircraft measurements of SO2, NOx, CO, and O3 over the coastal and offshore area of Yellow Sea of China.

PubMed

Yang, Xiaoyang; Wang, Xinhua; Yang, Wen; Xu, Jun; Ren, Lihong; He, Youjiang; Liu, Bing; Bai, Zhipeng; Meng, Fan; Hu, Min

2016-09-01

In order to investigate long-range transport of the air pollution in the East Asia, air pollutants, including SO2, NOx, CO, and O3, were observed by aircraft measurement over the coastal and offshore area of Yellow Sea of China in April 2011. NOx and SO2 seemed to become moderate in recent years, and the concentrations during the whole observations ranged from 0.49 to 9.57 ppb and from 0.10 to 16.02 ppb, respectively. The high concentrations of CO were measured with an average value of 0.98 ppm. The measured O3 average concentration was 76.25 ppb, which showed a higher level comparing with the results from some previous studies. Most of the results for the concentration values generally followed the typical characteristic of vertical and spatial distribution, which were "low altitude > high altitude" and "land/coastal > sea," respectively. Transport of polluted air mass from the continent to the aircraft measurement area was confirmed in some days during the observation by the meteorological analysis, while the measurement results supposed to represent the background level of the pollutants in rest days. Additionally, some small-scale air pollution plumes were observed. Significant positive correlations between NOx and SO2 indicated that these two species originated from the same region. On the other hand, good positive correlations between NOx and O3 found during 2-day flight suggested that the O3 formation was probably under "NOx-limited" regime in these days.

Effect of air temperature and relative humidity at various fuel-air ratios on exhaust emissions on a per-mode basis of an Avco Lycoming 0-320 DIAD light aircraft engine. Volume 2: Individual data points

NASA Technical Reports Server (NTRS)

Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempke, E. R.

1976-01-01

A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions included carburetor lean-out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel-air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity. Volume II contains the data taken at each of the individual test points.

Improved NOx emissions and combustion characteristics for a retrofitted down-fired 300-MWe utility boiler.

PubMed

Li, Zhengqi; Ren, Feng; Chen, Zhichao; Liu, Guangkui; Xu, Zhenxing

2010-05-15

A new technique combining high boiler efficiency and low-NO(x) emissions was employed in a 300MWe down-fired boiler as an economical means to reduce NO(x) emissions in down-fired boilers burning low-volatile coals. Experiments were conducted on this boiler after the retrofit with measurements taken of gas temperature distributions along the primary air and coal mixture flows and in the furnace, furnace temperatures along the main axis and gas concentrations such as O(2), CO and NO(x) in the near-wall region. Data were compared with those obtained before the retrofit and verified that by applying the combined technique, gas temperature distributions in the furnace become more reasonable. Peak temperatures were lowered from the upper furnace to the lower furnace and flame stability was improved. Despite burning low-volatile coals, NO(x) emissions can be lowered by as much as 50% without increasing the levels of unburnt carbon in fly ash and reducing boiler thermal efficiency.

Quantifying emissions of CO and NOx using observations from MOPITT, OMI, TES, and OSIRIS

NASA Astrophysics Data System (ADS)

Zhang, X.; Jones, D. B. A.; Keller, M.; Walker, T. W.; Jiang, Z.; Henze, D. K.; Bourassa, A. E.; Degenstein, D. A.; Rochon, Y. J.

2016-12-01

We use the GEOS-Chem four-dimensional variational (4D-var) data assimilation with satellite observations of multiple chemical species to estimate emissions of CO and NOx, as well as the tropospheric concentrations of O3. In doing so, we utilize CO retrievals from The Measurements of Pollution In The Troposphere (MOPITT), O3 retrievals from the Tropospheric Emission Spectrometer (TES), O3 retrievals from the Optical Spectrograph and InfraRed Imager System (OSIRIS), and NO2 columns from the Ozone Monitoring Instrument (OMI). By integrating these data in the 4D-Var scheme, we obtain a chemical state in the model that is consistent with all of the data over the assimilation period. In this context, for example, we find that combining TES and OSIRIS improves O3, particularly in the tropical upper troposphere (by 10-20%), which leads to a reduction in the uncertainty of the NOx emission estimates. However, although assimilating multiple chemical species provides a stronger constraint on the chemical, state, there are still large uncertainties on the CO and NOx emission estimates, due to the dependence of the results on the selection of the assimilation window and how the datasets are weighted in the cost function.

Calculation of odour emissions from aircraft engines at Copenhagen Airport.

PubMed

Winther, Morten; Kousgaard, Uffe; Oxbøl, Arne

2006-07-31

In a new approach the odour emissions from aircraft engines at Copenhagen Airport are calculated using actual fuel flow and emission measurements (one main engine and one APU: Auxiliary Power Unit), odour panel results, engine specific data and aircraft operational data for seven busy days. The calculation principle assumes a linear relation between odour and HC emissions. Using a digitalisation of the aircraft movements in the airport area, the results are depicted on grid maps, clearly reflecting aircraft operational statistics as single flights or total activity during a whole day. The results clearly reflect the short-term temporal fluctuations of the emissions of odour (and exhaust gases). Aircraft operating at low engine thrust (taxiing, queuing and landing) have a total odour emission share of almost 98%, whereas the shares for the take off/climb out phases (2%) and APU usage (0.5%) are only marginal. In most hours of the day, the largest odour emissions occur, when the total amount of fuel burned during idle is high. However, significantly higher HC emissions for one specific engine cause considerable amounts of odour emissions during limited time periods. The experimentally derived odour emission factor of 57 OU/mg HC is within the range of 23 and 110 OU/mg HC used in other airport odour studies. The distribution of odour emission results between aircraft operational phases also correspond very well with the results for these other studies. The present study uses measurement data for a representative engine. However, the uncertainties become large when the experimental data is used to estimate the odour emissions for all aircraft engines. More experimental data is needed to increase inventory accuracy, and in terms of completeness it is recommended to make odour emission estimates also for engine start and the fuelling of aircraft at Copenhagen Airport in the future.

PHOTOCHEMICAL EFFECTS ON NOX AND CO EMISSIONS IN A BRAZILIAN SAVANNA

EPA Science Inventory

Land clearing and burning in the tropics often results in increased solar irradiation of soil and surface organic matter. This increased light exposure may impact the emissions of nitrogen oxides (NOx) and carbon monoxide (CO), trace gases that play an important role in troposph...

Aircraft Engine Emissions. [conference

NASA Technical Reports Server (NTRS)

1977-01-01

A conference on a aircraft engine emissions was held to present the results of recent and current work. Such diverse areas as components, controls, energy efficient engine designs, and noise and pollution reduction are discussed.

Effects of co-processing sewage sludge in cement kiln on NOx, NH3 and PAHs emissions.

PubMed

Lv, Dong; Zhu, Tianle; Liu, Runwei; Lv, Qingzhi; Sun, Ye; Wang, Hongmei; Liu, Yu; Zhang, Fan

2016-09-01

The effects of co-processing sewage sludge in cement kiln on NOx, NH3 and PAHs emissions were systematically investigated in a cement production line in Beijing. The results show that co-processing the sewage sludge was helpful to reduce NOx emission, which primarily depends on the NH3 amount released from the sewage sludge. Meanwhile, NOx and NH3 concentrations in the flue gas have a negative correlation, and the contribution of feeding the sewage sludge to NOx removal decreased with the increase of injection amount of ammonia water in the SNCR system. Therefore, it is suggested that the injection amount of ammonia water in SNCR system may reduce to cut down the operating costs during co-processing the sewage sludge in cement kiln. In addition, the emission of total PAHs seems to increase with the increased amount of the sewage sludge feeding to the cement kiln. However, the distributions of PAHs were barely changed, and lower molecular weight PAHs were mainly distributed in gaseous phase, accounted for the major portion of PAHs when co-processing sewage sludge in cement kiln. Copyright © 2016 Elsevier Ltd. All rights reserved.

Comparisons of MOVES Light-duty Gasoline NOx Emission Rates with Real-world Measurements

NASA Astrophysics Data System (ADS)

Choi, D.; Sonntag, D.; Warila, J.

2017-12-01

Recent studies have shown differences between air quality model estimates and monitored values for nitrogen oxides. Several studies have suggested that the discrepancy between monitored and modeled values is due to an overestimation of NOx from mobile sources in EPA's emission inventory, particularly for light-duty gasoline vehicles. EPA's MOtor Vehicle Emission Simulator (MOVES) is an emission modeling system that estimates emissions for cars, trucks and other mobile sources at the national, county, and project level for criteria pollutants, greenhouse gases, and air toxics. Studies that directly measure vehicle emissions provide useful data for evaluating MOVES when the measurement conditions are properly accounted for in modeling. In this presentation, we show comparisons of MOVES2014 to thousands of real-world NOx emissions measurements from individual light-duty gasoline vehicles. The comparison studies include in-use vehicle emissions tests conducted on chassis dynamometer tests in support of Denver, Colorado's Vehicle Inspection & Maintenance Program and remote sensing data collected using road-side instruments in multiple locations and calendar years in the United States. In addition, we conduct comparisons of MOVES predictions to fleet-wide emissions measured from tunnels. We also present details on the methodology used to conduct the MOVES model runs in comparing to the independent data.

Estimates of ozone response to various combinations of NO(x) and VOC emission reductions in the eastern United States

NASA Technical Reports Server (NTRS)

Roselle, Shawn J.; Schere, Kenneth L.; Chu, Shao-Hang

1994-01-01

There is increasing recognition that controls on NO(x) emissions may be necessary, in addition to existing and future Volatile Organic Compounds (VOC) controls, for the abatement of ozone (O3) over portions of the United States. This study compares various combinations of anthropogenic NO(x) and VOC emission reductions through a series of model simulations. A total of 6 simulations were performed with the Regional Oxidant Model (ROM) for a 9-day period in July 1988. Each simulation reduced anthropogenic NO(x) and VOC emissions across-the-board by different amounts. Maximum O3 concentrations for the period were compared between the simulations. Comparison of the simulations suggests that: (1) NO(x) controls may be more effective than VOC controls in reducing peak O3 over most of the eastern United States; (2) VOC controls are most effective in urban areas having large sources of emissions; (3) NO(x) controls may increase O3 near large point sources; and (4) the benefit gained from increasing the amount of VOC controls may lessen as the amount of NO(x) control is increased. This paper has been reviewed in accordance with the U.S. Environmental Protection Agency's peer and administrative review policies and approved for presentation and publication. Mention of trade names or commercial products does not constitute endorsement or recommendation for use.

Physical characterization of the fine particle emissions from commercial aircraft engines during the Aircraft Particle Emissions Experiment (APEX) 1 to 3

EPA Science Inventory

The f1me particulate matter (PM) emissions from nine commercial aircraft engine models were determined by plume sampling during the three field campaigns of the Aircraft Particle Emissions Experiment (APEX). Ground-based measurements were made primarily at 30 m behind the engine ...

A new modeling approach for assessing the contribution of industrial and traffic emissions to ambient NOx concentrations

NASA Astrophysics Data System (ADS)

Chen, Shimon; Yuval; Broday, David M.

2018-01-01

The Optimized Dispersion Model (ODM) is uniquely capable of incorporating emission estimates, ambient air quality monitoring data and meteorology to provide reliable high-resolution (in both time and space) air quality estimates using non-linear regression. However, it was so far not capable of describing the effects of emissions from elevated sources. We formulated an additional term to extend the ODM such that these sources can be accounted for, and implemented it in modeling the fine spatiotemporal patterns of ambient NOx concentrations over the coastal plain of Israel. The diurnal and seasonal variation in the contribution of industry to the ambient NOx is presented, as well as its spatial features. Although industrial stacks are responsible for 88% of the NOx emissions in the study area, their contribution to ambient NOx levels is generally about 2% with a maximal upper bound of 27%. Meteorology has a major role in this source allocation, with the highest impact of industry in the summer months, when the wind is blowing inland past the coastal stacks and vertical mixing is substantial. The new Optimized Dispersion Model (ODM) out-performs both Inverse-Distance-Weighing (IDW) interpolation and a previous ODM version in predicting ambient NOx concentrations. The performance of the new model is thoroughly assessed.

Mixing and NO(x) Emission Calculations of Confined Reacting Jet Flows in a Cylindrical Duct

NASA Technical Reports Server (NTRS)

Holdeman, James D. (Technical Monitor); Oechsle, Victor L.

2003-01-01

Rapid mixing of cold lateral jets with hot cross-stream flows in confined configurations is of practical interest in gas turbine combustors as it strongly affects combustor exit temperature quality, and gaseous emissions in for example rich-lean combustion. It is therefore important to further improve our fundamental understanding of the important processes of dilution jet mixing especially when the injected jet mass flow rate exceeds that of the cross-stream. The results reported in this report describe some of the main flow characteristics which develop in the mixing process in a cylindrical duct. A 3-dimensional tool has been used to predict the mixing flow field characteristics and NOx emission in a quench section of an RQL combustor, Eighteen configurations have been analyzed in a circular geometry in a fully reacting environment simulating the operating condition of an actual RQL gas turbine combustion liner. The evaluation matrix was constructed by varying three parameters: 1) jet-to-mainstream momentum-flux ratio (J), 2) orifice shape or orifice aspect ratio, and 3) slot slant angle. The results indicate that the mixing flow field significantly varies with the value of the jet penetration and subsequently, slanting elongated slots generally improve the mixing uniformity at high J conditions. Round orifices produce more uniform mixing and low NO(x) emissions at low J due to the strong and adequate jet penetration. No significant correlation was found between the NO(x) production rates and the mixing deviation parameters, however, strong correlation was found between NO(x) formation and jet penetration. In the computational results, most of the NO(x) formation occurred behind the orifice starting at the orifice wake region. Additional NO(x) is formed upstream of the orifice in certain configurations with high J conditions due to the upstream recirculation.

An experimental study on effect of coke ratio on SO2 and NOx emissions in sintering process

NASA Astrophysics Data System (ADS)

Wang, Hui; Zhang, Pu; Yang, Jingling

2018-02-01

By using the sinter cup experiment, the effects of different coke ratios of 0%, 25%, 50%, 75%, and 100% on the formation and total emissions of SO2 and NOx in the sintering process were studied with the Testo350 flue gas analyzer. The experimental results show that the emissions of SO2 and NOx are closely related to sintering process. With the increase of the coke proportion, the sintering temperature changes and the maximum peak time appears earlier. SO2 concentration has a bimodal distribution and NOx concentration has a triple peak. Besides, the both maximum peaks appear at the end of sintering. In addition, due to the increasing of the S and N contents in the fuel with the coke ratios from 0% to 100%, the amounts of SO2 and NOx emissions are raised respectively at 10.82 mg, 11.42 mg, 13.84 mg, 13.69 mg, 20.36 mg and 3.11 mg, 3.39 mg, 4.44 mg, 4.31 mg, 6.16 mg.

40 CFR 75.71 - Specific provisions for monitoring NOX and heat input for the purpose of calculating NOX mass...

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring NOX... MONITORING NOX Mass Emissions Provisions § 75.71 Specific provisions for monitoring NOX and heat input for...-diluent continuous emission monitoring system (consisting of a NOX pollutant concentration monitor, an O2...

40 CFR 75.71 - Specific provisions for monitoring NOX and heat input for the purpose of calculating NOX mass...

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring NOX... MONITORING NOX Mass Emissions Provisions § 75.71 Specific provisions for monitoring NOX and heat input for...-diluent continuous emission monitoring system (consisting of a NOX pollutant concentration monitor, an O2...

40 CFR 75.71 - Specific provisions for monitoring NOX and heat input for the purpose of calculating NOX mass...

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring NOX... MONITORING NOX Mass Emissions Provisions § 75.71 Specific provisions for monitoring NOX and heat input for...-diluent continuous emission monitoring system (consisting of a NOX pollutant concentration monitor, an O2...

On-road assessment of light duty vehicles in Delhi city: Emission factors of CO, CO2 and NOX

NASA Astrophysics Data System (ADS)

Jaiprakash; Habib, Gazala

2018-02-01

This study presents the technology based emission factors of gaseous pollutants (CO, CO2, and NOX) measured during on-road operation of nine passenger cars of diesel, gasoline, and compressed natural gas (CNG). The emissions from two 3-wheelers, and three 2-wheelers were measured by putting the vehicles on jacks and operating them according to Modified Indian Driving Cycle (MIDC) at no load condition. The emission factors observed in the present work were significantly higher than values reported from dynamometer study by Automotive Research Association of India (ARAI). Low CO (0.34 ± 0.08 g km-1) and high NOX (1.0 ± 0.4 g km-1) emission factors were observed for diesel passenger cars, oppositely high CO (2.2 ± 2.6 g km-1) and low NOX (1.0 ± 1.6 g km-1) emission factors were seen for gasoline powered cars. The after-treatment technology in diesel vehicles was effective in CO reduction. While the use of turbocharger in diesel vehicles to generate high combustion temperature and pressure produces more NOx, probably which may not be effectively controlled by after-treatment device. The after-treatment devices in gasoline powered Post-2010, Post-2005 vehicles can be acclaimed for reduced CO emissions compared to Post-2000 vehicles. This work presents a limited data set of emission factors from on-road operations of light duty vehicles, this limitation can be improved by further measurements of emissions from similar vehicles.

New insights from comprehensive on-road measurements of NOx, NO2 and NH3 from vehicle emission remote sensing in London, UK

NASA Astrophysics Data System (ADS)

Carslaw, David C.; Rhys-Tyler, Glyn

2013-12-01

In this paper we report the first direct measurements of nitrogen dioxide (NO2) in the UK using a vehicle emission remote sensing technique. Measurements of NO, NO2 and ammonia (NH3) from almost 70,000 vehicles were made spanning vehicle model years from 1985 to 2012. These measurements were carefully matched with detailed vehicle information data to understand the emission characteristics of a wide range of vehicles in a detailed way. Overall it is found that only petrol fuelled vehicles have shown an appreciable reduction in total NOx emissions over the past 15-20 years. Emissions of NOx from diesel vehicles, including those with after-treatment systems designed to reduce emissions of NOx, have not reduced over the same period of time. It is also evident that the vehicle manufacturer has a strong influence on emissions of NO2 for Euro 4/5 diesel cars and urban buses. Smaller-engined Euro 4/5 diesel cars are also shown to emit less NO2 than larger-engined vehicles. It is shown that NOx emissions from urban buses fitted with Selective Catalytic Reduction (SCR) are comparable to those using Exhaust Gas Recirculation for Euro V vehicles, while reductions in NOx of about 30% are observed for Euro IV and EEV vehicles. However, the emissions of NO2 vary widely dependent on the bus technology used. Almost all the NOx emission from Euro IV buses with SCR is in the form of NO, whereas EEV vehicles (Enhanced Environmentally friendly Vehicle) emit about 30% of the NOx as NO2. We find similarly low amounts of NO2 from trucks (3.5-12t and >12t). Finally, we show that NH3 emissions are most important for older generation catalyst-equipped petrol vehicles and SCR-equipped buses. The NH3 emissions from petrol cars have decreased by over a factor of three from the vehicles manufactured in the late 1990s compared with those manufactured in 2012. Tables of emission factors are presented for NOx, NO2 and NH3 together with uncertainties to assist the development of new emission

High-speed Civil Transport Aircraft Emissions

NASA Technical Reports Server (NTRS)

Miake-Lye, Richard C.; Matulaitis, J. A.; Krause, F. H.; Dodds, Willard J.; Albers, Martin; Hourmouziadis, J.; Hasel, K. L.; Lohmann, R. P.; Stander, C.; Gerstle, John H.

1992-01-01

Estimates are given for the emissions from a proposed high speed civil transport (HSCT). This advanced technology supersonic aircraft would fly in the lower stratosphere at a speed of roughly Mach 1.6 to 3.2 (470 to 950 m/sec or 920 to 1850 knots). Because it would fly in the stratosphere at an altitude in the range of 15 to 23 km commensurate with its design speed, its exhaust effluents could perturb the chemical balance in the upper atmosphere. The first step in determining the nature and magnitude of any chemical changes in the atmosphere resulting from these proposed aircraft is to identify and quantify the chemically important species they emit. Relevant earlier work is summarized, dating back to the Climatic Impact Assessment Program of the early 1970s and current propulsion research efforts. Estimates are provided of the chemical composition of an HSCT's exhaust, and these emission indices are presented. Other aircraft emissions that are not due to combustion processes are also summarized; these emissions are found to be much smaller than the exhaust emissions. Future advances in propulsion technology, in experimental measurement techniques, and in understanding upper atmospheric chemistry may affect these estimates of the amounts of trace exhaust species or their relative importance.

Evaluating the Regional Impact of Aircraft Emissions on Climate

NASA Astrophysics Data System (ADS)

Zhang, J.; Wuebbles, D. J.; Khodayari, A.

2017-12-01

Unlike other transportation sectors where pollutant emissions usually occur only near the Earth's surface, aviation emissions happen primarily at altitudes of 8-12 km above the surface, impacting the upper troposphere and the lower stratosphere (UTLS). At these altitudes, the pollutants can contribute significantly to greenhouse gas (GHGs) concentration and to the formation of secondary aerosols, which can have an impact on climate change. This study examines the regional effects on climate forcing resulting from aviation emissions. Most previous studies have focused on aviation effects on climate using globally-averaged metric values, which do not give information about the spatial variability of the effects. While aviation emissions have significant spatial variability in the sign and magnitude of response, the strength of regional effects is hidden due to the global averaging of climate change effects. In this study, the chemistry-climate Community Atmosphere Model (CAM-chem5) is used in analyses to examine the regional climate effects based on 4 different latitude bands (90oS-28oS, 28oS-28oN, 28oN-60oN, 60oN-90oN) and 3 regions (contiguous United States, Europe and East Asia). The most regionally important aviation emissions are short-lived species, such as black carbon (BC) and sulfates, emitted from aircraft directly, and O3-short induced by NOx emission indirectly. The regionality of these short-lived impacts are explored and compared to the globally-averaged effects. The results indicate that BC and sulfates have more regionality than O3. The radiative forcings for short-lived agents over the United States, Europe and East Asia are around 2-4 times of their corresponding global values. The results also suggest that the climate forcings will be the most underestimated over the United States when using globally-averaged values without considering regional heterogeneity.

Estimates of Power Plant NOx Emissions and Lifetimes from OMI NO2 Satellite Retrievals

NASA Technical Reports Server (NTRS)

de Foy, Benjamin; Lu, Zifeng; Streets, David G.; Lamsal, Lok N.; Duncan, Bryan N.

2015-01-01

Isolated power plants with well characterized emissions serve as an ideal test case of methods to estimate emissions using satellite data. In this study we evaluate the Exponentially-Modified Gaussian (EMG) method and the box model method based on mass balance for estimating known NOx emissions from satellite retrievals made by the Ozone Monitoring Instrument (OMI). We consider 29 power plants in the USA which have large NOx plumes that do not overlap with other sources and which have emissions data from the Continuous Emission Monitoring System (CEMS). This enables us to identify constraints required by the methods, such as which wind data to use and how to calculate background values. We found that the lifetimes estimated by the methods are too short to be representative of the chemical lifetime. Instead, we introduce a separate lifetime parameter to account for the discrepancy between estimates using real data and those that theory would predict. In terms of emissions, the EMG method required averages from multiple years to give accurate results, whereas the box model method gave accurate results for individual ozone seasons.

Estimates of the changes in tropospheric chemistry which result from human activity and their dependence on NO(x) emissions and model resolution

NASA Technical Reports Server (NTRS)

Kanakidou, Maria; Crutzen, Paul J.; Zimmermann, Peter H.

1994-01-01

As a consequence of the non-linear behavior of the chemistry of the atmosphere and because of the short lifetime of nitrogen oxides (NO(x)), two-dimensional models do not give an adequate description of the production and destruction rates of NO(x) and their effects on the distributions of the concentration of ozone and hydroxyl radical. In this study, we use a three-dimensional model to evaluate the contribution of increasing NO(x) emissions from industrial activity and biomass burning to changes in the chemical composition of the troposphere. By comparing results obtained from longitudinally-uniform and longitudinally-varying emissions of NO(x), we demonstrate that the geographical representation of the NO(x) emissions is crucial in simulating tropospheric chemistry.

Top-down quantification of NOx emissions from traffic in an urban area using a high-resolution regional atmospheric chemistry model

NASA Astrophysics Data System (ADS)

Kuik, Friderike; Kerschbaumer, Andreas; Lauer, Axel; Lupascu, Aurelia; von Schneidemesser, Erika; Butler, Tim M.

2018-06-01

With NO2 limit values being frequently exceeded in European cities, complying with the European air quality regulations still poses a problem for many cities. Traffic is typically a major source of NOx emissions in urban areas. High-resolution chemistry transport modelling can help to assess the impact of high urban NOx emissions on air quality inside and outside of urban areas. However, many modelling studies report an underestimation of modelled NOx and NO2 compared with observations. Part of this model bias has been attributed to an underestimation of NOx emissions, particularly in urban areas. This is consistent with recent measurement studies quantifying underestimations of urban NOx emissions by current emission inventories, identifying the largest discrepancies when the contribution of traffic NOx emissions is high. This study applies a high-resolution chemistry transport model in combination with ambient measurements in order to assess the potential underestimation of traffic NOx emissions in a frequently used emission inventory. The emission inventory is based on officially reported values and the Berlin-Brandenburg area in Germany is used as a case study. The WRF-Chem model is used at a 3 km × 3 km horizontal resolution, simulating the whole year of 2014. The emission data are downscaled from an original resolution of ca. 7 km × 7 km to a resolution of 1 km × 1 km. An in-depth model evaluation including spectral decomposition of observed and modelled time series and error apportionment suggests that an underestimation in traffic emissions is likely one of the main causes of the bias in modelled NO2 concentrations in the urban background, where NO2 concentrations are underestimated by ca. 8 µg m-3 (-30 %) on average over the whole year. Furthermore, a diurnal cycle of the bias in modelled NO2 suggests that a more realistic treatment of the diurnal cycle of traffic emissions might be needed. Model problems in simulating the correct mixing in the urban

An Alternative to NOx Cap-and-Trade Programs: An Exploratory Analysis of Charging NOx Emitters for Health Damages

NASA Astrophysics Data System (ADS)

Mauzerall, D. L.; Sultan, B.; Kim, N.; Bradford, D.

2003-12-01

To address the problem of elevated O3 concentrations throughout the northeastern United States in summer, a NOx cap-and-trade program was implemented that reduced NOx emissions from large point sources by nearly 50%. To determine whether this program has been successful, we examine O3, NO and temperature measurements collected in the EPA-AIRS network prior to and after the cap-and-trade program went into effect in 1999. Ambient NO concentrations as measured in the EPA-AIRS network are lower in the post-cap period in all months except July. We find that the upper half of the distribution of O3 concentrations within the region is essentially unchanged (or slightly higher) in May and June, modestly reduced in July and August (except the highest concentrations which are larger in August), and significantly lower in September (ranging from 0-20 ppb lower between the mean and highest concentrations) in the 1999-2001 post-cap period relative to the 1995-1998 pre-cap period. Except for September, the frequency with which the 80ppb 8-hour NAAQS standard for O3 is exceeded has not decreased. Temperatures during the post-cap period were slightly higher in June, July and August, and slightly lower in September - likely contributing to reduced O3 levels during September in the post-cap period. To explore the possibility that trading, or selective emissions over the course of the summer, could influence regional O3 concentrations, we conduct chemical transport modeling experiments using the CAMx regional model. Even within May-September for a single year, demands for electrical power and hence NOx emissions are greater during hot than cool periods. We demonstrate that substantially more O3 is produced from identical NOx emissions from a single power plant on high temperature than on low temperature days in July 1995. Thus a lack of temporal restrictions on when in a single summer month NOx emissions may occur can result in higher O3 levels. We also demonstrate that identical NOx

Impact of passenger car NOX emissions on urban NO2 pollution - Scenario analysis for 8 European cities

NASA Astrophysics Data System (ADS)

Degraeuwe, Bart; Thunis, Philippe; Clappier, Alain; Weiss, Martin; Lefebvre, Wouter; Janssen, Stijn; Vranckx, Stijn

2017-12-01

Residents of large European cities are exposed to NO2 concentrations that often exceed the established air quality standards. Diesel cars have been identified as a major contributor to this situation; yet, it remains unclear to which levels the NOX emissions of diesel cars have to decrease to effectively mitigate urban NO2 pollution across Europe. Here, we take a continental perspective and model urban NO2 pollution in a generic street canyon of 8 major European cities for various NOX emission scenarios. We find that a reduction in the on-road NOX emissions of diesel cars to the Euro 6 level can in general decrease the regional and urban NO2 concentrations and thereby the frequency of exceedances of the NO2 air quality standard. High NO2 fractions in the NOX emissions of diesel cars tend to increase the urban NO2 concentrations only in proximity of intense road traffic typically found on artery roads in large cities like Paris and London. In cities with a low share of diesel cars in the vehicle fleet such as Athens or a high contribution from the NO2 background to the urban NO2 pollution such as Krakow, measures addressing heavy-duty vehicles, and the manufacturing, energy, and mining industry are necessary to decrease urban air pollution. We regard our model results as robust albeit subject to uncertainty resulting from the application of a generic street layout. With small modifications in the input parameters, our model could be used to assess the impact of NOX emissions from road transport on NO2 air pollution in any European city.

Modeling of aircraft exhaust emissions and infrared spectra for remote measurement of nitrogen oxides

NASA Astrophysics Data System (ADS)

Beier, K.; Schreier, F.

1994-10-01

Infrared (IR) molecular spectroscopy is proposed to perform remote measurements of NOx concentrations in the exhaust plume and wake of aircraft. The computer model NIRATAM is applied to simulate the physical and chemical properties of the exhaust plume and to generate low resolution IR spectra and synthetical thermal images of the aircraft in its natural surroundings. High-resolution IR spectra of the plume, including atmospheric absorption and emission, are simulated using the molecular line-by-line radiation model FASCODE2. Simulated IR spectra of a Boeing 747-400 at cruising altitude for different axial and radial positions in the jet region of the exhaust plume are presented. A number of spectral lines of NO can be identified that can be discriminated from lines of other exhaust gases and the natural atmospheric background in the region around 5.2 µm. These lines can be used to determine NO concentration profiles in the plume. The possibility of measuring nitrogen dioxide NO2 is also discussed briefly, although measurements turn out to be substantially less likely than those of NO. This feasibility study compiles fundamental data for the optical and radiometric design of an airborne Fourier transform spectrometer and the preparation of in-flight measurements for monitoring of aircraft pollutants

Ships going slow in reducing their NOx emissions: changes in 2005-2012 ship exhaust inferred from satellite measurements over Europe

NASA Astrophysics Data System (ADS)

Folkert Boersma, K.; Vinken, Geert C. M.; Tournadre, Jean

2015-07-01

We address the lack of temporal information on ship emissions, and report on rapid short-term variations of satellite-derived ship NOx emissions between 2005 and 2012 over European seas. Our inversion is based on OMI observed tropospheric NO2 columns and GEOS-Chem simulations. Average European ship NOx emissions increased by ˜15% from 2005 to 2008. This increase was followed by a reduction of ˜12% in 2009, a direct result of the global economic downturn in 2008-2009, and steady emissions from 2009 to 2012. Observations of ship passages through the Suez Canal and satellite altimeter derived ship densities suggests that ships in the Mediterranean Sea have reduced their speed by more than 30% since 2008. This reduction in ship speed is accompanied by a persistent 45% reduction of average, per ship NOx emission factors. Our results indicate that the practice of ‘slow steaming’, i.e. the lowering of vessel speed to reduce fuel consumption, has indeed been implemented since 2008, and can be detected from space. In spite of the implementation of slow steaming, one in seven of all NOx molecules emitted in Europe in 2012 originated from the shipping sector, up from one in nine in 2005. The growing share of the shipping contributions to the overall European NOx emissions suggests a need for the shipping sector to implement additional measures to reduce pollutant emissions at rates that are achieved by the road transport and energy producing sectors in Europe.

City-level variations in NOx emissions derived from hourly monitoring data in Chicago

NASA Astrophysics Data System (ADS)

de Foy, Benjamin

2018-03-01

Control on emissions of nitrogen oxides (NOx) in the United States of America have led to reductions in concentrations in urban areas by up to a factor of two in the last decade. The Air Quality System monitoring network provides surface measurements of concentrations at hourly resolution over multiple years, revealing variations at the annual, seasonal, day of week and diurnal time scales. A multiple linear regression model was used to estimate the temporal profiles in the NOx concentrations as well as the impact of meteorology, ozone concentrations, and boundary layer heights. The model is applied to data from 2005 to 2016 available at 6 sites in Chicago, Illinois. Results confirm the 50% decrease in NOx over the length of the time series. The weekend effect is found to be stronger in more commercial areas, with 32% reductions on Saturdays and 45% on Sundays and holidays; and weaker in more residential areas with 20% reductions on Saturdays and 30% reductions on Sundays. Weekday diurnal profiles follow a double hump with emission peaks during the morning and afternoon rush hours, but only a shallow drop during the middle day. Difference in profiles from the 6 sites suggest that there are different emission profiles within the urban area. Diurnal profiles on Saturdays have less variation throughout the day and more emissions in the evening. Sundays are very different from both weekdays and Saturdays with a gradual increase until the early evening. The results suggest that in addition to vehicle type and vehicle miles traveled, vehicle speed and congestion must be taken into account to correctly quantify morning rush hour emissions and the weekend effect.

Top-down NOX emissions over European cities from LOTOS-EUROS simulated and OMI observed tropospheric NO2 columns using the Exponentially Modified Gaussian approach

NASA Astrophysics Data System (ADS)

Verstraeten, Willem W.; Folkert Boersma, K.; Douros, John; Williams, Jason E.; Eskes, Henk H.; Delcloo, Andy

2017-04-01

High nitrogen oxides concentrations at the surface (NOX = NO + NO2) impact humans and ecosystem badly and play a key role in tropospheric chemistry. Surface NOX emissions drive major processes in regional and global chemistry transport models (CTM). NOX contributes to the formation of acid rain, act as aerosol precursors and is an important trace gas for the formation of tropospheric ozone (O3). Via tropospheric O3, NOX indirectly affects the production of the hydroxyl radical which controls the chemical lifetime of key atmospheric pollutants and reactive greenhouse gases. High NOX emissions are mainly observed in polluted regions produced by anthropogenic combustion from industrial, traffic and household activities typically observed in large and densely populated urban areas. Accurate NOX inventories are essential, but state-of the- art emission databases may vary substantially and uncertainties are high since reported emissions factors may differ in order of magnitude and more. To date, the modelled NO2 concentrations and lifetimes have large associated uncertainties due to the highly non-linear small-scale chemistry that occurs in urban areas and uncertainties in the reaction rate data, missing nitrogen (N) species and volatile organic compounds (VOC) emissions, and incomplete knowledge of nitrogen oxides chemistry. Any overestimation in the chemical lifetime may mask missing NOX chemistry in current CTM's. By simultaneously estimating both the NO2 lifetime and concentrations, for instance by using the Exponentially Modified Gaussian (EMG), a better surface NOX emission flux estimate can be obtained. Here we evaluate if the EMG methodology can reproduce the emissions input from the tropospheric NO2 columns simulated by the LOTOS-EUROS (Long Term Ozone Simulation-European Ozone Simulation) CTM model. We apply the EMG methodology on LOTOS-EUROS simulated tropospheric NO2 columns for the period April-September 2013 for 21 selected European urban areas under windy

Public health impacts of excess NOx emissions from Volkswagen diesel passenger vehicles in Germany

NASA Astrophysics Data System (ADS)

Chossière, Guillaume P.; Malina, Robert; Ashok, Akshay; Dedoussi, Irene C.; Eastham, Sebastian D.; Speth, Raymond L.; Barrett, Steven R. H.

2017-03-01

In September 2015, the Volkswagen Group (VW) admitted the use of ‘defeat devices’ designed to lower emissions measured during VW vehicle testing for regulatory purposes. Globally, 11 million cars sold between 2008 and 2015 are affected, including about 2.6 million in Germany. On-road emissions tests have yielded mean on-road NOx emissions for these cars of 0.85 g km-1, over four times the applicable European limit of 0.18 g km-1. This study estimates the human health impacts and costs associated with excess emissions from VW cars driven in Germany. A distribution of on-road emissions factors is derived from existing measurements and combined with sales data and a vehicle fleet model to estimate total excess NOx emissions. These emissions are distributed on a 25 by 28 km grid covering Europe, using the German Federal Environmental Protection Agency’s (UBA) estimate of the spatial distribution of NOx emissions from passenger cars in Germany. We use the GEOS-Chem chemistry-transport model to predict the corresponding increase in population exposure to fine particulate matter and ozone in the European Union, Switzerland, and Norway, and a set of concentration-response functions to estimate mortality outcomes in terms of early deaths and of life-years lost. Integrated over the sales period (2008-2015), we estimate median mortality impacts from VW excess emissions in Germany to be 1200 premature deaths in Europe, corresponding to 13 000 life-years lost and 1.9 billion EUR in costs associated with life-years lost. Approximately 60% of mortality costs occur outside Germany. For the current fleet, we estimate that if on-road emissions for all affected VW vehicles in Germany are reduced to the applicable European emission standard by the end of 2017, this would avert 29 000 life-years lost and 4.1 billion 2015 EUR in health costs (median estimates) relative to a counterfactual case with no recall.

Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lammert, M. P.; McCormick, R. L.; Sindler, P.

2012-10-01

Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level hadmore » the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.« less

An Overview of Low-Emission Combustion Research

NASA Technical Reports Server (NTRS)

DelRosario, Ruben

2014-01-01

An overview of research efforts at NASA Glenn Research Center (GRC) in low-emission combustion technology that have made a significant impact on the Nitrogen Oxides (NOx) emission reduction in aircraft propulsion will be presented. The technology advancements and their impact on aircraft emissions will be discussed in the context of NASAs Aeronautics Research Mission Directorate (ARMD) high-level goals in fuel burn, noise and emission reductions. The highlights of the research presented will show how the past and current efforts have laid the foundation for the engines that are flying today as well as how the continued technology advancements will significantly influence the next generation of aviation propulsion system designs.

First Top-Down Estimates of Anthropogenic NOx Emissions Using High-Resolution Airborne Remote Sensing Observations

NASA Astrophysics Data System (ADS)

Souri, Amir H.; Choi, Yunsoo; Pan, Shuai; Curci, Gabriele; Nowlan, Caroline R.; Janz, Scott J.; Kowalewski, Matthew G.; Liu, Junjie; Herman, Jay R.; Weinheimer, Andrew J.

2018-03-01

A number of satellite-based instruments have become an essential part of monitoring emissions. Despite sound theoretical inversion techniques, the insufficient samples and the footprint size of current observations have introduced an obstacle to narrow the inversion window for regional models. These key limitations can be partially resolved by a set of modest high-quality measurements from airborne remote sensing. This study illustrates the feasibility of nitrogen dioxide (NO2) columns from the Geostationary Coastal and Air Pollution Events Airborne Simulator (GCAS) to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. We convert slant column densities to vertical columns using a radiative transfer model with (i) NO2 profiles from a high-resolution regional model (1 × 1 km2) constrained by P-3B aircraft measurements, (ii) the consideration of aerosol optical thickness impacts on radiance at NO2 absorption line, and (iii) high-resolution surface albedo constrained by ground-based spectrometers. We characterize errors in the GCAS NO2 columns by comparing them to Pandora measurements and find a striking correlation (r > 0.74) with an uncertainty of 3.5 × 1015 molecules cm-2. On 9 of 10 total days, the constrained anthropogenic emissions by a Kalman filter yield an overall 2-50% reduction in polluted areas, partly counterbalancing the well-documented positive bias of the model. The inversion, however, boosts emissions by 94% in the same areas on a day when an unprecedented local emissions event potentially occurred, significantly mitigating the bias of the model. The capability of GCAS at detecting such an event ensures the significance of forthcoming geostationary satellites for timely estimates of top-down emissions.

Atmospheric pollution reduction effect and regional predicament: An empirical analysis based on the Chinese provincial NOx emissions.

PubMed

Ding, Lei; Liu, Chao; Chen, Kunlun; Huang, Yalin; Diao, Beidi

2017-07-01

Atmospheric pollution emissions have become a matter of public concern in recent years. However, most of the existing researches on NOx pollution are from the natural science and technology perspective, few studies have been conducted from an economic point, and regional differences have not been given adequate attention. This paper adopts provincial panel data from 2006 to 2013 and the LMDI model to analyze the key driving factors and regional dilemmas of NOx emissions. The results show that significant regional disparities still exit on NO x emissions and its reduction effect 27 provinces didn't accomplish their corresponding reduction targets. Economic development factor is the dominating driving factor of NO x emissions during the study period, while energy efficiency and technology improvement factors offset total NO x emissions in the majority of provinces. In addition, the industrial structure factor plays a more significant role in reducing the NO x emissions after 2011. Therefore, the government should consider all these factors as well as regional heterogeneity in developing appropriate pollution mitigating policies. It's necessary to change NOx emissions control attitude from original key areas control to divided-zone control, not only attaches great importance to the reduction of the original key areas, but also emphasizes the new potential hotspots with high NO x emissions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Intake fraction of PM2.5 and NOX from vehicle emissions in Beijing based on personal exposure data

NASA Astrophysics Data System (ADS)

Du, Xuan; Wu, Ye; Fu, Lixin; Wang, Shuxiao; Zhang, Shaojun; Hao, Jiming

2012-09-01

The intake fraction (iF) is the portion of attributable population intake of a source emissions, and is used to link pollutant emissions and population exposure. This study is the first work that reported individual intake fraction of PM2.5 and NOX from vehicle emissions based on personal exposure data in China. We employed PM2.5 and NOX measurement data from 24-h personal exposure sampling and concentration monitoring in traffic environments in the urban area of Beijing to estimate the individual intake fraction (iFi). iFi distributions are presented in microenvironments (traffic, work, home) for adults and children. The individual results are used to calculate the intake fraction for the children group and the adults group in the urban area of Beijing. The iF of PM2.5 for the whole population of these two groups in Beijing is 153 per million, which is significantly higher than those estimates in the United States (1-50 per million) and Mexico (23-120 per million). The iF of NOX is 70 per million, among which the intake in the traffic micro-environment ranks first compared to the iF in the home and office due to a high accumulation of NOX concentration in vehicles. PM2.5 and NOX intake fraction values from vehicle emissions in this study are from at least several times to one order of magnitude higher than those from other industry sources in China. This strongly suggests the health risk from vehicle emissions is significantly higher. Therefore, to protect human health, especially for the large number of people living in the cities of China, controlling vehicle emissions should be the highest priority.

Measurements of NOx emissions and in-service duty cycle from a towboat operating on the inland river system.

PubMed

Corbett, J J; Robinson, A L

2001-04-01

This paper describes measurements of NOx emissions from one engine on a commercial towboat operating on the Upper Ohio River system around the Port of Pittsburgh. Continuous measurements were made over a one-week period to characterize emissions during normal operations. The average NOx emission factor is 70 +/- 4.2 kg of NOx per t of fuel, similar to that of larger marine engines. A vessel-specific duty cycle is derived to characterize the towboat's operations; more than 50% of the time the vessel engines are at idle. Although recently promulgated EPA regulations apply only to new marine engines, these data provide insight into inland-river operations, which can be used to evaluate these regulations within the inland river context. This vessel operates as a courier service, scheduling pickups and deliveries of single- or multiple-barge loads per customers' requests; as many as 30% of the 277 towboats in the Pittsburgh region operate in this fashion. The EPA-prescribed ISO E3 duty cycle does not accurately describe inland-river operations of this towboat: its application overestimates actual NOx emissions by 14%. Only 41% of this vessel's operations fall within the Not-To-Exceed Zone defined by the EPA regulations, which limits the effectiveness of this component of the regulations to limit emissions from vessels that operate in a similar fashion.

Public Health Impacts of Excess NOX Emissions from Volkswagen Diesel Passenger Vehicles: a comparison between Germany and the United States

NASA Astrophysics Data System (ADS)

Chossiere, G.; Barrett, S. R. H.; Malina, R.; Dedoussi, I. C.; Eastham, S. D.; Ashok, A.

2016-12-01

In September 2015, the Volkswagen Group admitted the use of an illegal emissions control system that activates during vehicle testing for regulatory purposes. Globally, 11 million diesel cars sold between 2008 and 2015 are affected, including about 2.6 million in Germany and 480,000 in the United States. On-road tests suggest that NOx emissions for these cars amount to 0.85 g/km on average, over four times the applicable European limit of 0.18 g/km and more than 20 times the corresponding EPA standard. This study quantifies and compares the human health impacts and costs associated with excess emissions from VW cars driven in Germany and in the United States. A distribution of emissions factors built from existing on-road measurements is combined with sales data and a vehicle fleet model to estimate total excess NOx emissions in each country. In Europe, we used the GEOS-Chem chemistry-transport model to predict the increase in population exposure to fine particulate matter and ozone due to the excess NOx emissions in Germany. The corresponding quantities in the US case were obtained using an adjoint-based air pollution model derived from the GEOS-Chem model. A set of concentration-response functions allowed us to estimate mortality outcomes in terms of early deaths in the US and in Europe. Integrated over the sales period (2008 - 2015), we estimate median mortality impacts from VW excess emissions in Germany to be 1,100 (95% CI: 0 to 3,000) early deaths in Europe, corresponding to 3.9 billion EUR (95% CI: 0 to 10 billion) in associated costs. Another 59 (95% CI: 10 to 150) early deaths is expected in the US as a result of excess emissions released in the country, corresponding to 450 million USD in social costs. We find that excess NOx emissions in Europe have 5 times greater health impacts per kilogram than those in the US due to the higher population density and more NOx-sensitive background conditions in Europe. The gas ratios in the two regions support this

Closed loop engine control for regulating NOx emissions, using a two-dimensional fuel-air curve

DOEpatents

Bourn, Gary D.; Smith, Jack A.; Gingrich, Jess W.

2007-01-30

An engine control strategy that ensures that NOx emissions from the engine will be maintained at an acceptable level. The control strategy is based on a two-dimensional fuel-air curve, in which air manifold pressure (AMP) is a function of fuel header pressure and engine speed. The control strategy provides for closed loop NOx adjustment to a base AMP value derived from the fuel-air curve.

Low NO(x) potential of gas turbine engines

NASA Technical Reports Server (NTRS)

Tacina, Robert R.

1990-01-01

The purpose is to correlate emission levels of gas turbine engines. The predictions of NO(x) emissions are based on a review of the literature of previous low NO(x) combustor programs and analytical chemical kinetic calculations. Concepts included in the literature review consisted of lean-premixed-prevaporized (LPP), rich burn/quick quench/lean burn (RQL), and direct injection. The NO(x) emissions were found to be an exponential function of adiabatic combustion temperature over a wide range of inlet temperatures, pressures and (lean) fuel-air ratios. A simple correlation of NO(x) formation with time was not found. The LPP and direct injection (using gaseous fuels) concepts have the lowest NO(x) emissions of the three concepts. The RQL data has higher values of NO(x) than the LPP concept, probably due to the stoichiometric temperatures and NO(x) production that occur during the quench step. Improvements in the quick quench step could reduce the NO(x) emissions to the LPP levels. The low NO(x) potential of LPP is offset by the operational disadvantages of its narrow stability limits and its susceptibility to autoignition/flashback. The Rich-Burn/Quick-Quench/Lean-Burn (RQL) and the direct injection concepts have the advantage of wider stability limits comparable to conventional combustors.

Alkali- and Sulfur-Resistant Tungsten-Based Catalysts for NOx Emissions Control.

PubMed

Huang, Zhiwei; Li, Hao; Gao, Jiayi; Gu, Xiao; Zheng, Li; Hu, Pingping; Xin, Ying; Chen, Junxiao; Chen, Yaxin; Zhang, Zhaoliang; Chen, Jianmin; Tang, Xingfu

2015-12-15

The development of catalysts with simultaneous resistance to alkalis and sulfur poisoning is of great importance for efficiently controlling NOx emissions using the selective catalytic reduction of NOx with NH3 (SCR), because the conventional V2O5/WO3-TiO2 catalysts often suffer severe deactivation by alkalis. Here, we support V2O5 on a hexagonal WO3 (HWO) to develop a V2O5/HWO catalyst, which has exceptional resistance to alkali and sulfur poisoning in the SCR reactions. A 350 μmol g(-1) K(+) loading and the presence of 1,300 mg m(-3) SO2 do not almost influence the SCR activity of the V2O5/HWO catalyst, and under the same conditions, the conventional V2O5/WO3-TiO2 catalysts completely lost the SCR activity within 4 h. The strong resistance to alkali and sulfur poisoning of the V2O5/HWO catalysts mainly originates from the hexagonal structure of the HWO. The HWO allows the V2O5 to be highly dispersed on the external surfaces for catalyzing the SCR reactions and has the relatively smooth surfaces and the size-suitable tunnels specifically for alkalis' diffusion and trapping. This work provides a useful strategy to develop SCR catalysts with exceptional resistance to alkali and sulfur poisoning for controlling NOx emissions from the stationary source and the mobile source.

40 CFR 51.122 - Emissions reporting requirements for SIP revisions relating to budgets for NOX emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... NOX emissions data as described in this section. (c) Each revision must provide for periodic reporting...) of this section. (3) Through 2011, reports are to be submitted according to the schedule in Table 1... reports are to be submitted each year that a triennial report is not required. Table 1—Schedule for...

Stratospheric emissions effects database development

NASA Technical Reports Server (NTRS)

Baughcum, Steven L.; Henderson, Stephen C.; Hertel, Peter S.; Maggiora, Debra R.; Oncina, Carlos A.

1994-01-01

This report describes the development of a stratospheric emissions effects database (SEED) of aircraft fuel burn and emissions from projected Year 2015 subsonic aircraft fleets and from projected fleets of high-speed civil transports (HSCT's). This report also describes the development of a similar database of emissions from Year 1990 scheduled commercial passenger airline and air cargo traffic. The objective of this work was to initiate, develop, and maintain an engineering database for use by atmospheric scientists conducting the Atmospheric Effects of Stratospheric Aircraft (AESA) modeling studies. Fuel burn and emissions of nitrogen oxides (NO(x) as NO2), carbon monoxide, and hydrocarbons (as CH4) have been calculated on a 1-degree latitude x 1-degree longitude x 1-kilometer altitude grid and delivered to NASA as electronic files. This report describes the assumptions and methodology for the calculations and summarizes the results of these calculations.

Emission of atmospheric pollutants out of Africa - Analysis of CARIBIC aircraft air samples

NASA Astrophysics Data System (ADS)

Thorenz, Ute R.; Baker, Angela K.; Schuck, Tanja; van Velthoven, Peter F. J.; Ziereis, Helmut; Brenninkmeijer, Carl A. M.

2014-05-01

Africa is the single largest continental source of biomass burning (BB) emissions. The burning African savannas and tropical forests are a source for a wide range of chemical species, which are important for global atmospheric chemistry, especially for the pristine Southern Hemisphere. Emitted compounds include carbon monoxide (CO), nitrogen oxides (NOx), hydrocarbons, oxygenated hydrocarbons and particles. Deep convection over Central Africa transports boundary layer emissions to the free troposphere making aircraft-based observations useful for investigation of surface emissions and examination of transport and chemistry processes over Africa The CARIBIC project (Civil Aircraft for the Regular Investigation of the Atmosphere Based on an Instrument Container, www.caribic-atmosphere.com part of IAGOS www.iagos.org) is a long term atmospheric measurement program using an instrument container deployed aboard a Lufthansa Airbus A340-600 for a monthly sequence of long-distance passenger flights. Besides the online measurements mixing ratios of greenhouse gases and a suite of C2-C8 non methane hydrocarbons (NMHCs) are measured from flask samples collected at cruise altitude. During northern hemispheric winter 2010/2011 CARIBIC flights took place from Frankfurt to Cape Town and Johannesburg in South Africa. Several BB tracers like methane, CO and various NMHCs were found to be elevated over tropical Africa. Using tracer-CO- and tracer-NOy-correlations emissions were characterized. The NMHC-CO correlations show monthly changing slopes, indicating a change in burned biomass, major fire stage, source region and/or other factors influencing NMHC emissions. To expand our analysis of emission sources a source region data filter was used, based on backward trajectories calculated along the flight tracks. Taking all CARIBIC samples into account having backward trajectories to the African boundary layer the dataset was enlarged from 77 to 168 samples. For both datasets tracer

Aircraft Particle Emissions eXperiment (APEX)

NASA Technical Reports Server (NTRS)

Wey, C. C.; Anderson, B. E.; Hudgins, C.; Wey, C.; Li-Jones, X.; Winstead, E.; Thornhill, L. K.; Lobo, P.; Hagen, D.; Whitefield, P.

2006-01-01

APEX systematically investigated the gas-phase and particle emissions from a CFM56-2C1 engine on NASA's DC-8 aircraft as functions of engine power, fuel composition, and exhaust plumage. Emissions parameters were measured at 11 engine power, settings, ranging from idle to maximum thrust, in samples collected at 1, 10, and 30 m downstream of the exhaust plane as the aircraft burned three fuels to stress relevant chemistry. Gas-phase emission indices measured at 1 m were in good agreement with the ICAO data and predictions provided by GEAE empirical modeling tools. Soot particles emitted by the engine exhibited a log-normal size distribution peaked between 15 and 40 nm, depending on engine power. Samples collected 30 m downstream of the engine exhaust plane exhibited a prominent nucleation mode.

Design and testing of an independently controlled urea SCR retrofit system for the reduction of NOx emissions from marine diesels.

PubMed

Johnson, Derek R; Bedick, Clinton R; Clark, Nigel N; McKain, David L

2009-05-15

Diesel engine emissions for on-road, stationary and marine applications are regulated in the United States via standards set by the Environmental Protection Agency (EPA). A major component of diesel exhaust that is difficult to reduce is nitrogen oxides (NOx). Selective catalytic reduction (SCR) has been in use for many years for stationary applications, including external combustion boilers, and is promising for NOx abatement as a retrofit for mobile applications where diesel compression ignition engines are used. The research presented in this paper is the first phase of a program focused on the reduction of NOx by use of a stand-alone urea injection system, applicable to marine diesel engines typical of work boats (e.g., tugs). Most current urea SCR systems communicate with engine controls to predict NOx emissions based on signals such as torque and engine speed, however many marine engines in use still employ mechanical injection technology and lack electronic communication abilities. The system developed and discussed in this paper controls NOx emissions independentof engine operating parameters and measures NOx and exhaust flow using the following exhaust sensor inputs: absolute pressure, differential pressure, temperature, and NOx concentration. These sensor inputs were integrated into an independent controller and open loop architecture to estimate the necessary amount of urea needed, and the controller uses pulse width modulation (PWM) to power an automotive fuel injector for airless urea delivery. The system was tested in a transient test cell on a 350 hp engine certified at 4 g/bhp-hr of NOx, with a goal of reducing the engine out NOx levels by 50%. NOx reduction capabilities of 41-67% were shown on the non road transient cycle (NRTC) and ICOMIA E5 steady state cycles with system optimization during testing to minimize the dilute ammonia slip to cycle averages of 5-7 ppm. The goal of 50% reduction of NOx can be achieved dependent upon cycle. Further

Experimental Study on Relationship between NOx Emission and Fuel Consumption of a Diesel Engine

NASA Astrophysics Data System (ADS)

Ning, Ping; Liu, Chunjiang; Feng, Zhiqiang; Xia, Yijiang

2018-01-01

For YC6112 diesel engine assembled Delphl model single fuel pump electric controlled, in the premise of not changing its overall unit structure parameters of other systems, three different types of camshaft for single pumps, two kinds of fuel injectors, two types of superchargers and some phase shifting angle of different camshafts were chosen to match with the engine precisely, the experiments under thirteen kinds of working conditions for the engine with different matching were carried out, the change regulation between NOX emission and fuel consumption for the engine with different kinds of configurations was analyzed. The experiment results show the NOX emission and fuel consumption can be reduced greatly by configuring proper camshaft, fuel injectors and superchargers with YC6112 diesel engine.

THE ACID RAIN NOX PROGRAM

EPA Science Inventory

Between 350,000 and 400,000 tons of annual NOx emissions have been eliminated as a result of Phase I of the Acid Rain NOx Program. As expected. the utilities have chosen emissions averaging as the primary compliance option. This reflects that, in general, NO x reductions have ...

Evaluation of NOx emissions from U.S. wildfires occurring during August-October 2006 using WRF-Chem model simulations and satellite observations

NASA Astrophysics Data System (ADS)

Kim, S.; Brioude, J.; Hilboll, A.; Richter, A.; Gleason, J. F.; Burrows, J. P.; Ryerson, T. B.; Peischl, J. W.; Holloway, J.; Lee, S.; Frost, G. J.; McKeen, S. A.; Trainer, M.

2009-12-01

During August-October 2006, there were many fire events in the U.S., including a month-long fire in Los Padres National Forest in California and numerous fires in the southeastern U.S. The OMI instrument onboard NASA's Aura satellite, the MODIS instrument on NASA's Terra satellite, and instruments on the NOAA GOES satellites clearly detected fire plumes during this period, opening the possibility of using trace gas and aerosol measurements from satellites to improve bottom-up emission estimates from wildfires. WRF-Chem model simulations of U.S. air quality without bottom-up fire emissions underestimated satellite-observed nitrogen dioxide columns substantially over fire-impacted regions during this time period. In this presentation, nitrogen dioxide columns simulated from the model including the wildfire emissions will be compared with the satellite retrievals and uncertainties in the bottom-up fire NOx emissions will be discussed. In addition, the sensitivities of satellite retrievals to aerosols resulting from these fires will be shown. The satellite NO2 columns will also be tested with aircraft observations made over the Texas region during September-October 2006 as part of the TexAQS/GoMACCS field campaign.

Aircraft Piston Engine Exhaust Emission Symposium

NASA Technical Reports Server (NTRS)

1976-01-01

A 2-day symposium on the reduction of exhaust emissions from aircraft piston engines was held on September 14 and 15, 1976, at the Lewis Research Center in Cleveland, Ohio. Papers were presented by both government organizations and the general aviation industry on the status of government contracts, emission measurement problems, data reduction procedures, flight testing, and emission reduction techniques.

Emission characteristics of NOx, CO, NH3 and VOCs from gas-fired industrial boilers based on field measurements in Beijing city, China

NASA Astrophysics Data System (ADS)

Yue, Tao; Gao, Xiang; Gao, Jiajia; Tong, Yali; Wang, Kun; Zuo, Penglai; Zhang, Xiaoxi; Tong, Li; Wang, Chenlong; Xue, Yifeng

2018-07-01

In the past decade, due to the management policies and coal combustion controls in Beijing, the consumption of natural gas has increased gradually. Nevertheless, the research on the emission characteristics of gaseous pollutants emitted from gas-fired industrial boilers, especially considering the influence of low nitrogen (low-NOx) retrofit policy of gas boilers, is scarcely. In this study, based on literature and field investigations, onsite measurements of NOx, CO, NH3 and VOCs (Volatile Organic Compounds) emissions from gas-fired industrial boilers as well as the key factors that affected the emission of gaseous pollutants were discussed. Category-specific emission factors (EFs) of NOx, CO, NH3 and VOCs were obtained from the field measurements of 1107 "low-NOx" retrofitted and unabated gas-fired industrial boilers. Our results showed that operating load and control measures were the two key factors affecting the formation of gaseous pollutants. The EFs of NOx (EFNOx) and CO (EFCO) of atmospheric combustion boilers (ACBs) were much higher than the EFs of chamber combustion boilers (CCBs). The total emissions of NOx, CO, NH3 and VOCs from gas-fired industrial boilers in Beijing in the year of 2015 were estimated at 10489.6 t, 3272.8 t, 196.4 t and 235.4 t, respectively. Alkanes, BTEX, oxygenated VOCs and non-reactive organic matter were the four main chemical components of VOCs. As for the spatial distributions, the emissions of NOx, CO, NH3 and VOCs from gas-fired industrial boilers in Beijing were predominantly concentrated in central six urban districts. In the future, more detailed investigation and field tests for all kinds of gas-fired industrial boilers are still greatly needed to achieve more reliable estimations of atmospheric pollutants from gas-fired industrial boilers.

NOx adsorber and method of regenerating same

DOEpatents

Endicott, Dennis L [Peoria, IL; Verkiel, Maarten [Metamora, IL; Driscoll, James J [Dunlap, IL

2007-01-30

New technologies, such as NOx adsorber catalytic converters, are being used to meet increasingly stringent regulations on undesirable emissions, including NOx emissions. NOx adsorbers must be periodically regenerated, which requires an increased fuel consumption. The present disclosure includes a method of regenerating a NOx adsorber within a NOx adsorber catalytic converter. At least one sensor positioned downstream from the NOx adsorber senses, in the downstream exhaust, at least one of NOx, nitrous oxide and ammonia concentrations a plurality of times during a regeneration phase. The sensor is in communication with an electronic control module that includes a regeneration monitoring algorithm operable to end the regeneration phase when a time rate of change of the at least one of NOx, nitrous oxide and ammonia concentrations is after an expected plateau region begins.

Survey of Aircraft Emissions and Related Instrumentation

DOT National Transportation Integrated Search

1971-03-31

The report presents the preliminary results of a survey of transportation systems emissions monitoring requirements. Emissions of carbon monoxide, hydrocarbons, oxides of nitrogen and particulates from aircraft power plants, with emphasis on gas turb...

Emission factors of air pollutants from CNG-gasoline bi-fuel vehicles: Part II. CO, HC and NOx.

PubMed

Huang, Xiaoyan; Wang, Yang; Xing, Zhenyu; Du, Ke

2016-09-15

The estimation of emission factors (EFs) is the basis of accurate emission inventory. However, the EFs of air pollutants for motor vehicles vary under different operating conditions, which will cause uncertainty in developing emission inventory. Natural gas (NG), considered as a "cleaner" fuel than gasoline, is increasingly being used to reduce combustion emissions. However, information is scarce about how much emission reduction can be achieved by motor vehicles burning NG (NGVs) under real road driving conditions, which is necessary for evaluating the environmental benefits for NGVs. Here, online, in situ measurements of the emissions from nine bi-fuel vehicles were conducted under different operating conditions on the real road. A comparative study was performed for the EFs of black carbon (BC), carbon monoxide (CO), hydrocarbons (HCs) and nitrogen oxides (NOx) for each operating condition when the vehicles using gasoline and compressed NG (CNG) as fuel. BC EFs were reported in part I. The part II in this paper series reports the influence of operating conditions and fuel types on the EFs of CO, HC and NOx. Fuel-based EFs of CO showed good correlations with speed when burning CNG and gasoline. The correlation between fuel-based HC EFs and speed was relatively weak whether burning CNG or gasoline. The fuel-based NOx EFs moderately correlated with speed when burning CNG, but weakly correlated with gasoline. As for HC, the mileage-based EFs of gasoline vehicles are 2.39-12.59 times higher than those of CNG vehicles. The mileage-based NOx EFs of CNG vehicles are slightly higher than those of gasoline vehicles. These results would facilitate a detailed analysis of the environmental benefits for replacing gasoline with CNG in light duty vehicles. Copyright © 2016 Elsevier B.V. All rights reserved.

Overview of Low Emission Combustion Research At NASA Glenn

NASA Technical Reports Server (NTRS)

Reddy, D. R.

2016-01-01

An overview of research efforts at NASA Glenn Research Center (GRC) in low-emission combustion technology that have made a significant impact on the nitrogen oxides (NOx) emission reduction in aircraft propulsion is presented. The technology advancements and their impact on aircraft emissions are discussed in the context of NASA's Aeronautics Research Mission Directorate (ARMD) high-level goals in fuel burn, noise and emission reductions. The highlights of the research presented here show how the past and current efforts laid the foundation for the engines that are flying today as well as how the continued technology advancements will significantly influence the next generation of aviation propulsion system designs.

40 CFR 75.71 - Specific provisions for monitoring NOX and heat input for the purpose of calculating NOX mass...

Code of Federal Regulations, 2011 CFR

2011-07-01

... and heat input for the purpose of calculating NOX mass emissions. 75.71 Section 75.71 Protection of... MONITORING NOX Mass Emissions Provisions § 75.71 Specific provisions for monitoring NOX and heat input for... and for a flow monitoring system and an O2 or CO2 diluent gas monitoring system to measure heat input...

Agriculture is a major source of NOx pollution in California

PubMed Central

Almaraz, Maya; Bai, Edith; Wang, Chao; Trousdell, Justin; Conley, Stephen; Faloona, Ian; Houlton, Benjamin Z.

2018-01-01

Nitrogen oxides (NOx = NO + NO2) are a primary component of air pollution—a leading cause of premature death in humans and biodiversity declines worldwide. Although regulatory policies in California have successfully limited transportation sources of NOx pollution, several of the United States’ worst–air quality districts remain in rural regions of the state. Site-based findings suggest that NOx emissions from California’s agricultural soils could contribute to air quality issues; however, a statewide estimate is hitherto lacking. We show that agricultural soils are a dominant source of NOx pollution in California, with especially high soil NOx emissions from the state’s Central Valley region. We base our conclusion on two independent approaches: (i) a bottom-up spatial model of soil NOx emissions and (ii) top-down airborne observations of atmospheric NOx concentrations over the San Joaquin Valley. These approaches point to a large, overlooked NOx source from cropland soil, which is estimated to increase the NOx budget by 20 to 51%. These estimates are consistent with previous studies of point-scale measurements of NOx emissions from the soil. Our results highlight opportunities to limit NOx emissions from agriculture by investing in management practices that will bring co-benefits to the economy, ecosystems, and human health in rural areas of California. PMID:29399630

Impact of National Airspace Systems (NAS) modernization on aircraft emissions

DOT National Transportation Integrated Search

1998-09-01

The study evaluated the fuel and emission benefits of Free Flight by aircraft type and : phase of flight. Calculations for aircraft emissions were made for pollutants directly produced : within the engine combuster and emitted at a rate depending on ...

Antioxidant (A-tocopherol acetate) effect on oxidation stability and NOx emission reduction in methyl ester of Annona oil operated diesel engine

NASA Astrophysics Data System (ADS)

Senthil, R.; Silambarasan, R.; Pranesh, G.

2017-05-01

There is a major drawback while using biodiesel as a alternate fuel for compression ignition diesel engine due to lower heating value, higher viscosity, higher density and higher oxides of nitrogen emission. To minimize these drawbacks, fuel additives can contribute towards engine performance and exhaust emission reduction either directly or indirectly. In this current work, the test was conducted to investigate the effect of antioxidant additive (A-tocopherol acetate) on oxidation stability and NOx emission in a of Annona methyl ester oil (MEAO) fueled diesel engine. The A-tocopherol acetate is mixed in different concentrations such as 0.01, 0.02, 0.03 and 0.04% with 100% by vol MEAO. It is concluded that the antioxidant additive very effective in increasing the oxidation stability and in controlling the NOx emission. Further, the addition of antioxidant additive is slight increase the HC, CO and smoke emissions. Hence, A-tocopherol acetate is very effective in controlling the NOx emission with MEAO operated diesel engine without any major modification.

NOX AND CO EMISSIONS FROM SOIL AND SURFACE LITTER IN A BRAZILIAN SAVANNA

EPA Science Inventory

Land clearing and burning in the tropics often results in increased solar irradiation of soil and surface organic matter. This increased light exposure and surface heating may impact the emissions of nitrogen oxides (NOx) and carbon monoxide (CO), trace gases that play an importa...

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raymond Drnevich; James Meagher; Vasilis Papavassiliou

2004-08-01

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter,more » and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.« less

An Overview of Low-Emission Combustion Research at NASA Glenn

NASA Technical Reports Server (NTRS)

Reddy, Dhanireddy R.; Lee, Chi-Ming

2016-01-01

An overview of research efforts at NASA Glenn Research Center (GRC) in low-emission combustion technology that have made a significant impact on the nitrogen oxides (NOx) emission reduction in aircraft propulsion is presented. The technology advancements and their impact on aircraft emissions are discussed in the context of NASA's Aeronautics Research Mission Directorate (ARMD) high-level goals in fuel burn, noise and emission reductions. The highlights of the research presented here show how the past and current efforts laid the foundation for the engines that are flying today as well as how the continued technology advancements will significantly influence the next generation of aviation propulsion system designs.

Aircraft LTO emissions regulations and implementations at European airports

NASA Astrophysics Data System (ADS)

Yunos, Siti Nur Mariani Mohd; Ghafir, Mohammad Fahmi Abdul; Wahab, Abas Ab

2017-04-01

Aviation affects the environment via the emission of pollutants from aircraft, impacting human health and ecosystem. Impacts of aircraft operations at lower ground towards local air quality have been recognized. Consequently, various standards and regulations have been introduced to address the related emissions. This paper discussed both environmental regulations by focusing more on the implementations of LTO emissions charges, an incentive-based regulation introduced in Europe as an effort to fill the gap in addressing the environmental issues related to aviation.

Hydrogen/Air Fuel Nozzle Emissions Experiments

NASA Technical Reports Server (NTRS)

Smith, Timothy D.

2001-01-01

The use of hydrogen combustion for aircraft gas turbine engines provides significant opportunities to reduce harmful exhaust emissions. Hydrogen has many advantages (no CO2 production, high reaction rates, high heating value, and future availability), along with some disadvantages (high current cost of production and storage, high volume per BTU, and an unknown safety profile when in wide use). One of the primary reasons for switching to hydrogen is the elimination of CO2 emissions. Also, with hydrogen, design challenges such as fuel coking in the fuel nozzle and particulate emissions are no longer an issue. However, because it takes place at high temperatures, hydrogen-air combustion can still produce significant levels of NOx emissions. Much of the current research into conventional hydrocarbon-fueled aircraft gas turbine combustors is focused on NOx reduction methods. The Zero CO2 Emission Technology (ZCET) hydrogen combustion project will focus on meeting the Office of Aerospace Technology goal 2 within pillar one for Global Civil Aviation reducing the emissions of future aircraft by a factor of 3 within 10 years and by a factor of 5 within 25 years. Recent advances in hydrocarbon-based gas turbine combustion components have expanded the horizons for fuel nozzle development. Both new fluid designs and manufacturing technologies have led to the development of fuel nozzles that significantly reduce aircraft emissions. The goal of the ZCET program is to mesh the current technology of Lean Direct Injection and rocket injectors to provide quick mixing, low emissions, and high-performance fuel nozzle designs. An experimental program is planned to investigate the fuel nozzle concepts in a flametube test rig. Currently, a hydrogen system is being installed in cell 23 at NASA Glenn Research Center's Research Combustion Laboratory. Testing will be conducted on a variety of fuel nozzle concepts up to combustion pressures of 350 psia and inlet air temperatures of 1200 F

Characterization of Industrial Emission Sources and Photochemistry in Houston, Texas

NASA Astrophysics Data System (ADS)

Washenfelder, R. A.; Atlas, E. L.; Degouw, J.; Flocke, F. M.; Fried, A.; Frost, G. J.; Holloway, J.; Richter, D.; Ryerson, T. B.; Schauffler, S.; Trainer, M.; Walega, J.; Warneke, C.; Weibring, P.; Zheng, W.

2009-12-01

The Houston-Galveston urban area contains a number of large industrial petrochemical emission sources that produce volatile organic compounds and nitrogen oxides. These co-located emissions result in rapid and efficient ozone production downwind. Unlike a single large power plant, the industrial complexes consist of numerous sources that can be difficult to quantify in emission inventories. During September - October 2006, the NOAA WP-3 aircraft conducted research flights as part of the second Texas Air Quality Study (TexAQS II). We examine measurements of NOx, SO2, and speciated hydrocarbons from the Houston Ship Channel, which contains a dense concentration of industrial petrochemical sources, and isolated petrochemical facilities. These measurements are used to derive source emission estimates, which are then compared to available emission inventories. We find that high hydrocarbon emissions are typical for the Houston Ship Channel and isolated petrochemical facilities. Ethene and propene are found to be major contributors to ozone formation. Ratios of C2H4 / NOx and C3H6 / NOx exceed emission inventory values by factors of 10 - 50. These findings are consistent with the first TexAQS study in 2000. We examine trends in C2H4 / NOx and C3H6 / NOx ratios between 2000 and 2006, and determine that day-to-day variability and within-plume variability exceeds any long-term reduction in ethene and propene emissions for the isolated petrochemical sources. We additionally examine downwind photochemical products formed by these alkenes.

NASA Project Develops Next-Generation Low-Emissions Combustor Technologies

NASA Technical Reports Server (NTRS)

Lee, Chi-Ming; Chang, Clarence T.; Herbon, John T.; Kramer, Stephen K.

2013-01-01

NASA's Environmentally Responsible Aviation (ERA) Project is working with industry to develop the fuel flexible combustor technologies for a new generation of low-emissions engine targeted for the 2020 timeframe. These new combustors will reduce nitrogen oxide (NOx) emissions to half of current state-of-the-art (SOA) combustors, while simultaneously reducing noise and fuel burn. The purpose of the low NOx fuel-flexible combustor research is to advance the Technology Readiness Level (TRL) and Integration Readiness Level (IRL) of a low NOx, fuel flexible combustor to the point where it can be integrated in the next generation of aircraft. To reduce project risk and optimize research benefit NASA chose to found two Phase 1 contracts. The first Phase 1 contracts went to engine manufactures and were awarded to: General Electric Company, and Pratt & Whitney Company. The second Phase 1 contracts went to fuel injector manufactures Goodrich Corporation, Parker Hannifin Corporation, and Woodward Fuel System Technology. In 2012, two sector combustors were tested at NASA's ASCR. The results indicated 75% NOx emission reduction below the 2004 CAEP/6 regulation level.

Reducing NOx Emissions for a 600 MWe Down-Fired Pulverized-Coal Utility Boiler by Applying a Novel Combustion System.

PubMed

Ma, Lun; Fang, Qingyan; Lv, Dangzhen; Zhang, Cheng; Chen, Yiping; Chen, Gang; Duan, Xuenong; Wang, Xihuan

2015-11-03

A novel combustion system was applied to a 600 MWe Foster Wheeler (FW) down-fired pulverized-coal utility boiler to solve high NOx emissions, without causing an obvious increase in the carbon content of fly ash. The unit included moving fuel-lean nozzles from the arches to the front/rear walls and rearranging staged air as well as introducing separated overfire air (SOFA). Numerical simulations were carried out under the original and novel combustion systems to evaluate the performance of combustion and NOx emissions in the furnace. The simulated results were found to be in good agreement with the in situ measurements. The novel combustion system enlarged the recirculation zones below the arches, thereby strengthening the combustion stability considerably. The coal/air downward penetration depth was markedly extended, and the pulverized-coal travel path in the lower furnace significantly increased, which contributed to the burnout degree. The introduction of SOFA resulted in a low-oxygen and strong-reducing atmosphere in the lower furnace region to reduce NOx emissions evidently. The industrial measurements showed that NOx emissions at full load decreased significantly by 50%, from 1501 mg/m3 (O2 at 6%) to 751 mg/m3 (O2 at 6%). The carbon content in the fly ash increased only slightly, from 4.13 to 4.30%.

Propulsion Investigation for Zero and Near-Zero Emissions Aircraft

NASA Technical Reports Server (NTRS)

Snyder, Christopher A.; Berton, Jeffrey J.; Brown, Gerald v.; Dolce, James L.; Dravid, Marayan V.; Eichenberg, Dennis J.; Freeh, Joshua E.; Gallo, Christopher A.; Jones, Scott M.; Kundu, Krishna P.;

Status of Technological Advancements for Reducing Aircraft Gas Turbine Engine Pollutant Emissions

NASA Technical Reports Server (NTRS)

Rudey, R. A.

1975-01-01

Combustor test rig results indicate that substantial reductions from current emission levels of carbon monoxide (CO), total unburned hydrocarbons (THC), oxides of nitrogen (NOx), and smoke are achievable by employing varying degrees of technological advancements in combustion systems. Minor to moderate modifications to existing conventional combustors produced significant reductions in CO and THC emissions at engine low power (idle/taxi) operating conditions but did not effectively reduce NOx at engine full power (takeoff) operating conditions. Staged combusiton techniques were needed to simultaneously reduce the levels of all the emissions over the entire engine operating range (from idle to takeoff). Emission levels that approached or were below the requirements of the 1979 EPA standards were achieved with the staged combustion systems and in some cases with the minor to moderate modifications to existing conventional combustion systems. Results from research programs indicate that an entire new generation of combustor technology with extremely low emission levels may be possible in the future.

40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... the boiler at a normal or conservatively high excess oxygen level in conjunction with these tests....2Substitute 1.25 times the highest NOX emission rate from the baseline correlation tests for the fuel (or fuel... potential NOX emission rate (MER) (as defined in § 72.2 of this chapter) for each unit operating hour...

40 CFR Appendix E to Part 75 - Optional NOX Emissions Estimation Protocol for Gas-Fired Peaking Units and Oil-Fired Peaking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... the boiler at a normal or conservatively high excess oxygen level in conjunction with these tests....2Substitute 1.25 times the highest NOX emission rate from the baseline correlation tests for the fuel (or fuel... potential NOX emission rate (MER) (as defined in § 72.2 of this chapter) for each unit operating hour...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2010 CFR

2010-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you are...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2011 CFR

2011-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you are...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2012 CFR

2012-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... burning that fuel. Similarly, when your total heat input is greater than 50 percent distillate oil and...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2014 CFR

2014-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... burning that fuel. Similarly, when your total heat input is greater than 50 percent distillate oil and...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2013 CFR

2013-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... burning that fuel. Similarly, when your total heat input is greater than 50 percent distillate oil and...

Prediction of NOx emissions from a simplified biodiesel surrogate by applying stochastic simulation algorithms (SSA)

NASA Astrophysics Data System (ADS)

Omidvarborna, Hamid; Kumar, Ashok; Kim, Dong-Shik

2017-03-01

A stochastic simulation algorithm (SSA) approach is implemented with the components of a simplified biodiesel surrogate to predict NOx (NO and NO2) emission concentrations from the combustion of biodiesel. The main reaction pathways were obtained by simplifying the previously derived skeletal mechanisms, including saturated methyl decenoate (MD), unsaturated methyl 5-decanoate (MD5D), and n-decane (ND). ND was added to match the energy content and the C/H/O ratio of actual biodiesel fuel. The MD/MD5D/ND surrogate model was also equipped with H2/CO/C1 formation mechanisms and a simplified NOx formation mechanism. The predicted model results are in good agreement with a limited number of experimental data at low-temperature combustion (LTC) conditions for three different biodiesel fuels consisting of various ratios of unsaturated and saturated methyl esters. The root mean square errors (RMSEs) of predicted values are 0.0020, 0.0018, and 0.0025 for soybean methyl ester (SME), waste cooking oil (WCO), and tallow oil (TO), respectively. The SSA model showed the potential to predict NOx emission concentrations, when the peak combustion temperature increased through the addition of ultra-low sulphur diesel (ULSD) to biodiesel. The SSA method used in this study demonstrates the possibility of reducing the computational complexity in biodiesel emissions modelling.

Reducing air pollutant emissions at airports by controlling aircraft ground operations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gelinas, C.G.; Fan, H.S.L.

1979-02-01

Average-day carbon monoxide, total hydrocarbon, and NO/sub x/ aircraft emissions and fuel use estimates (apportioned to takeoff, taxi, idle, and landing) for departure and arrival at Los Angeles and San Francisco International Airports were compared with emissions level and fuel use estimates for four emission reduction strategies (tow aircraft between runways and gates, shutdown one engine during taxiing, control departure time, and assign runways to minimize taxiing distance). The best strategy, the shutdown of one engine while taxiing, produces substantial emission reductions, cost benefits owing to fuel savings, and no apparent safety problems; aircraft towing reduced emissions significantly, but introducedmore » a number of safety problems.« less

Aviation NOx-induced CH4 effect: Fixed mixing ratio boundary conditions versus flux boundary conditions

NASA Astrophysics Data System (ADS)

Khodayari, Arezoo; Olsen, Seth C.; Wuebbles, Donald J.; Phoenix, Daniel B.

2015-07-01

Atmospheric chemistry-climate models are often used to calculate the effect of aviation NOx emissions on atmospheric ozone (O3) and methane (CH4). Due to the long (∼10 yr) atmospheric lifetime of methane, model simulations must be run for long time periods, typically for more than 40 simulation years, to reach steady-state if using CH4 emission fluxes. Because of the computational expense of such long runs, studies have traditionally used specified CH4 mixing ratio lower boundary conditions (BCs) and then applied a simple parameterization based on the change in CH4 lifetime between the control and NOx-perturbed simulations to estimate the change in CH4 concentration induced by NOx emissions. In this parameterization a feedback factor (typically a value of 1.4) is used to account for the feedback of CH4 concentrations on its lifetime. Modeling studies comparing simulations using CH4 surface fluxes and fixed mixing ratio BCs are used to examine the validity of this parameterization. The latest version of the Community Earth System Model (CESM), with the CAM5 atmospheric model, was used for this study. Aviation NOx emissions for 2006 were obtained from the AEDT (Aviation Environmental Design Tool) global commercial aircraft emissions. Results show a 31.4 ppb change in CH4 concentration when estimated using the parameterization and a 1.4 feedback factor, and a 28.9 ppb change when the concentration was directly calculated in the CH4 flux simulations. The model calculated value for CH4 feedback on its own lifetime agrees well with the 1.4 feedback factor. Systematic comparisons between the separate runs indicated that the parameterization technique overestimates the CH4 concentration by 8.6%. Therefore, it is concluded that the estimation technique is good to within ∼10% and decreases the computational requirements in our simulations by nearly a factor of 8.

Measurements of NO(x) over the eastern Pacific Ocean and southwestern United States during the spring 1984 NASA GTE aircraft program

NASA Technical Reports Server (NTRS)

Ridley, B. A.; Carroll, M. A.; Dunlap, D. D.; Trainer, M.; Sachse, G. W.; Gregory, G. L.; Condon, E. P.

1989-01-01

Measurements of NO, NO(x) (NO + NO2), O3, and CO are presented from seven aircraft flights made over the eastern Pacific Ocean and the southwestern United States in spring of 1984. The sampling region was characterized by large- and small-scale variability for all of the measurements, likely as a result of vigorous synoptic scale meteorology and the influence of tropopause folds. Median values for NO, NO(x), O3, and CO from the flights made over the ocean in the region of 5.8-7.6 km were 10 parts per trillion by volume (pptv), 32 pptv, 46 parts per billion by volume (ppbv), and 120 ppbv, respectively. Corresponding values from two flights made over the continent at similar altitudes were 16 pptv, 38 pptv, 42 ppbv, and 111 ppbv. There was a strong tendency for NO or NO(x) to be correlated positively with O3 and to be anticorrelated with dew-point/frost-point measurements. No significant overall correlation occurred between NO(x) and CO for the ocean data. The variability of NO(x) was such that regions of net destruction and regions of net production of O(3) were sampled both over the ocean and over the continent. However, in the middle free troposphere over the ocean, net O(3) destruction was predominant.

Eagle Ford Shale BTEX and NOx concentrations are dominated by oil and gas industry emissions

NASA Astrophysics Data System (ADS)

Schade, G. W.; Roest, G. S.

2017-12-01

US shale oil and gas exploration has been identified as a major source of greenhouse gases and non-methane hydrocarbon (NMHC) emissions to the atmosphere. Here, we present a detailed analysis of 2015 air quality data acquired by the Texas Commission on Environmental Quality (TCEQ) at an air quality monitoring station in Karnes County, TX, central to Texas' Eagle Ford shale area. Data include time series of hourly measured NMHCs, nitrogen oxides (NOx), and hydrogen sulfide (H2S) alongside meteorological measurements. The monitor was located in Karnes City, and thus affected by various anthropogenic emissions, including traffic and oil and gas exploration sources. Highest mixing ratios measured in 2015 included nearly 1 ppm ethane, 0.8 ppm propane, alongside 4 ppb benzene. A least-squares minimization non-negative matrix factorization (NMF) analysis, tested with prior data analyzed using standard PMF-2 software, showed six major emission sources: an evaporative and fugitive source, a flaring source, a traffic source, an oil field source, a diesel source, and an industrial manufacturing source, together accounting for more than 95% of data set variability, and interpreted using NMHC composition and meteorological data. Factor scores strongly suggest that NOx emissions are dominated by flaring and associated sources, such as diesel compressor engines, likely at midstream facilities, while traffic in this rural area is a minor NOx source. The results support, but exceed existing 2012 emission inventories estimating that local traffic emitted seven times fewer NOx than oil and gas exploration sources in the county. Sources of air toxics such as the BTEX compounds are also dominated by oil and gas exploration sources, but are more equally distributed between the associated factors. Benzene abundance is only 20-40% associated with traffic sources, and may thus be 2.5-5 times higher now than prior to the shale boom in this area. Although the monitor was located relatively

Impact of excess NOx emissions from diesel cars on air quality, public health and eutrophication in Europe

NASA Astrophysics Data System (ADS)

Jonson, J. E.; Borken-Kleefeld, J.; Simpson, D.; Nyíri, A.; Posch, M.; Heyes, C.

2017-09-01

Diesel cars have been emitting four to seven times more NOx in on-road driving than in type approval tests. These ‘excess emissions’ are a consequence of deliberate design of the vehicle’s after-treatment system, as investigations during the ‘Dieselgate’ scandal have revealed. Here we calculate health and environmental impacts of these excess NOx emissions in all European countries for the year 2013. We use national emissions reported officially under the UNECE Convention for Long-range Transport of Atmospheric Pollutants and employ the EMEP MSC-W Chemistry Transport Model and the GAINS Integrated Assessment Model to determine atmospheric concentrations and resulting impacts. We compare with impacts from hypothetical emissions where light duty diesel vehicles are assumed to emit only as much as their respective type approval limit value or as little as petrol cars of the same age. Excess NO2 concentrations can also have direct health impacts, but these overlap with the impacts from particulate matter (PM) and are not included here. We estimate that almost 10 000 premature deaths from PM2.5 and ozone in the adult population (age >30 years) can be attributed to the NOx emissions from diesel cars and light commercial vehicles in EU28 plus Norway and Switzerland in 2013. About 50% of these could have been avoided if diesel limits had been achieved also in on-road driving; and had diesel cars emitted as little NOx as petrol cars, 80% of these premature deaths could have been avoided. Ecosystem eutrophication impacts (critical load exceedances) from the same diesel vehicles would also have been reduced at similar rates as for the health effects.

40 CFR 75.72 - Determination of NOX mass emissions for common stack and multiple stack configurations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the hourly stack flow rate (in scfh). Only one methodology for determining NOX mass emissions shall be...-diluent continuous emissions monitoring system and a flow monitoring system in the common stack, record... maintain a flow monitoring system and diluent monitor in the duct to the common stack from each unit; or...

REDUCING DIESEL NOX AND SOOT EMISSIONS VIA PARTICLE-FREE EXHAUST GAS RECIRCULATION - PHASE I

EPA Science Inventory

Diesel engines play an important role in the United States economy for power generation and transportation. However, NOx and soot emissions from both stationary and mobile diesel engines are a major contributor to air pollution. Many engine modifications and exhaust-after-t...

Estimates of global biomass burning emissions for reactive greenhouse gases (CO, NMHCs, and NOx) and CO2

NASA Astrophysics Data System (ADS)

Jain, Atul K.; Tao, Zhining; Yang, Xiaojuan; Gillespie, Conor

2006-03-01

Open fire biomass burning and domestic biofuel burning (e.g., cooking, heating, and charcoal making) algorithms have been incorporated into a terrestrial ecosystem model to estimate CO2 and key reactive GHGs (CO, NOx, and NMHCs) emissions for the year 2000. The emissions are calculated over the globe at a 0.5° × 0.5° spatial resolution using tree density imagery, and two separate sets of data each for global area burned and land clearing for croplands, along with biofuel consumption rate data. The estimated global and annual total dry matter (DM) burned due to open fire biomass burning ranges between 5221 and 7346 Tg DM/yr, whereas the resultant emissions ranges are 6564-9093 Tg CO2/yr, 438-568 Tg CO/yr, 11-16 Tg NOx/yr (as NO), and 29-40 Tg NMHCs/yr. The results indicate that land use changes for cropland is one of the major sources of biomass burning, which amounts to 25-27% (CO2), 25 -28% (CO), 20-23% (NO), and 28-30% (NMHCs) of the total open fire biomass burning emissions of these gases. Estimated DM burned associated with domestic biofuel burning is 3,114 Tg DM/yr, and resultant emissions are 4825 Tg CO2/yr, 243 Tg CO/yr, 3 Tg NOx/yr, and 23 Tg NMHCs/yr. Total emissions from biomass burning are highest in tropical regions (Asia, America, and Africa), where we identify important contributions from primary forest cutting for croplands and domestic biofuel burning.

Relationship between VOC and NOx emissions and chemical production of tropospheric ozone in the Aburrá Valley (Colombia).

PubMed

Toro, María Victoria; Cremades, Lázaro V; Calbó, Josep

2006-10-01

Relationship between volatile organic compounds (VOC) and nitrogen oxides (NOx) emissions and the chemical production of tropospheric ozone is studied through mathematical simulation. The study is applied to the Aburrá Valley, in the Colombian Andes, which is a practically unknown area from the point of view of ozone formation. The model used for this application is the European modelling of atmospheric constituents (EUMAC) zooming model (EZM) which consists of a mesoscale prognostic model (MEMO, mesoscale meteorological model) and a chemical reaction model (MUSE, multiscale for the atmospheric dispersion of reactive species), coupled to the chemical mechanism EMEP (European monitoring and evaluation program). The analysis is performed for a real episode that was characterized by high ozone production and that happened during the 23rd and 24th December, 1999 in Medellín (Colombia). From this real scenario, a sensitivity analysis has been carried out in order to assess the influence of VOC and NOx amounts on ozone production and to extract some conclusions for future ozone abatement policies in Andean regions. As far as ozone air quality is concerned, it is shown that in order to keep current levels the emphasis must be put to avoid increasing NOx emissions, or alternatively, to augment VOC emissions in order to have a high VOC/NOx ratio.

Improved Mechanistic Understanding of Natural Gas Methane Emissions from Spatially Resolved Aircraft Measurements

DOE PAGES

Schwietzke, Stefan; Pétron, Gabrielle; Conley, Stephen; ...

2017-06-05

Divergence in recent oil and gas related methane emission estimates between aircraft studies (basin total for a midday window) and emissions inventories (annualized regional and national statistics) indicate the need for better understanding the experimental design, including temporal and spatial alignment and interpretation of results. In our aircraft-based methane emission estimates in a major U.S. shale gas basin resolved from west to east show (i) similar spatial distributions for 2 days, (ii) strong spatial correlations with reported NG production (R 2 = 0.75) and active gas well pad count (R 2 = 0.81), and (iii) 2× higher emissions in themore » western half (normalized by gas production) despite relatively homogeneous dry gas and well characteristics. Operator reported hourly activity data show that midday episodic emissions from manual liquid unloadings (a routine operation in this basin and elsewhere) could explain ~1/3 of the total emissions detected midday by the aircraft and ~2/3 of the west–east difference in emissions. The 22% emission difference between both days further emphasizes that episodic sources can substantially impact midday methane emissions and that aircraft may detect daily peak emissions rather than daily averages that are generally employed in emissions inventories. And while the aircraft approach is valid, quantitative, and independent, this study sheds new light on the interpretation of previous basin scale aircraft studies, and provides an improved mechanistic understanding of oil and gas related methane emissions.« less

Improved Mechanistic Understanding of Natural Gas Methane Emissions from Spatially Resolved Aircraft Measurements.

PubMed

Schwietzke, Stefan; Pétron, Gabrielle; Conley, Stephen; Pickering, Cody; Mielke-Maday, Ingrid; Dlugokencky, Edward J; Tans, Pieter P; Vaughn, Tim; Bell, Clay; Zimmerle, Daniel; Wolter, Sonja; King, Clark W; White, Allen B; Coleman, Timothy; Bianco, Laura; Schnell, Russell C

2017-06-20

Divergence in recent oil and gas related methane emission estimates between aircraft studies (basin total for a midday window) and emissions inventories (annualized regional and national statistics) indicate the need for better understanding the experimental design, including temporal and spatial alignment and interpretation of results. Our aircraft-based methane emission estimates in a major U.S. shale gas basin resolved from west to east show (i) similar spatial distributions for 2 days, (ii) strong spatial correlations with reported NG production (R 2 = 0.75) and active gas well pad count (R 2 = 0.81), and (iii) 2× higher emissions in the western half (normalized by gas production) despite relatively homogeneous dry gas and well characteristics. Operator reported hourly activity data show that midday episodic emissions from manual liquid unloadings (a routine operation in this basin and elsewhere) could explain ∼1/3 of the total emissions detected midday by the aircraft and ∼2/3 of the west-east difference in emissions. The 22% emission difference between both days further emphasizes that episodic sources can substantially impact midday methane emissions and that aircraft may detect daily peak emissions rather than daily averages that are generally employed in emissions inventories. While the aircraft approach is valid, quantitative, and independent, our study sheds new light on the interpretation of previous basin scale aircraft studies, and provides an improved mechanistic understanding of oil and gas related methane emissions.

Improved Mechanistic Understanding of Natural Gas Methane Emissions from Spatially Resolved Aircraft Measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwietzke, Stefan; Pétron, Gabrielle; Conley, Stephen

Divergence in recent oil and gas related methane emission estimates between aircraft studies (basin total for a midday window) and emissions inventories (annualized regional and national statistics) indicate the need for better understanding the experimental design, including temporal and spatial alignment and interpretation of results. In our aircraft-based methane emission estimates in a major U.S. shale gas basin resolved from west to east show (i) similar spatial distributions for 2 days, (ii) strong spatial correlations with reported NG production (R 2 = 0.75) and active gas well pad count (R 2 = 0.81), and (iii) 2× higher emissions in themore » western half (normalized by gas production) despite relatively homogeneous dry gas and well characteristics. Operator reported hourly activity data show that midday episodic emissions from manual liquid unloadings (a routine operation in this basin and elsewhere) could explain ~1/3 of the total emissions detected midday by the aircraft and ~2/3 of the west–east difference in emissions. The 22% emission difference between both days further emphasizes that episodic sources can substantially impact midday methane emissions and that aircraft may detect daily peak emissions rather than daily averages that are generally employed in emissions inventories. And while the aircraft approach is valid, quantitative, and independent, this study sheds new light on the interpretation of previous basin scale aircraft studies, and provides an improved mechanistic understanding of oil and gas related methane emissions.« less

Aircraft HO sub x and NO sub x emission effects on stratospheric ozone and temperature

NASA Technical Reports Server (NTRS)

Glatt, L.; Widhopf, G. F.

1978-01-01

A simplified two-dimensional steady-state photochemical model of the atmosphere was developed. The model was used to study the effect on the thermal and chemical structure of the atmosphere of two types of pollution cases: (1) injection of NOx and HOx from a hypothetical fleet of supersonic and subsonic aircraft and (2) injection of HOx from a hypothetical fleet of liquid-fueled hydrogen aircraft. The results are discussed with regard to stratospheric perturbations in ozone, water vapor and temperature.

Assessment of Non-EGU NOx Emission Controls, Cost of Controls, and Time for Compliance Final TSD

EPA Pesticide Factsheets

The purpose of this Technical Support Document (TSD) is to discuss the currently available information on emissions and control measures for sources of NOX other than electric generating units (EGUs).

Simultaneous NOx and hydrocarbon emissions control for lean-burn engines using low-temperature solid oxide fuel cell at open circuit.

PubMed

Huang, Ta-Jen; Hsu, Sheng-Hsiang; Wu, Chung-Ying

2012-02-21

The high fuel efficiency of lean-burn engines is associated with high temperature and excess oxygen during combustion and thus is associated with high-concentration NO(x) emission. This work reveals that very high concentration of NO(x) in the exhaust can be reduced and hydrocarbons (HCs) can be simultaneously oxidized using a low-temperature solid oxide fuel cell (SOFC). An SOFC unit is constructed with Ni-YSZ as the anode, YSZ as the electrolyte, and La(0.6)Sr(0.4)CoO(3) (LSC)-Ce(0.9)Gd(0.1)O(1.95) as the cathode, with or without adding vanadium to LSC. SOFC operation at 450 °C and open circuit can effectively treat NO(x) over the cathode at a very high concentration in the simulated exhaust. Higher NO(x) concentration up to 5000 ppm can result in a larger NO(x) to N(2) rate. Moreover, a higher oxygen concentration promotes NO conversion. Complete oxidation of HCs can be achieved by adding silver to the LSC current collecting layer. The SOFC-based emissions control system can treat NO(x) and HCs simultaneously, and can be operated without consuming the anode fuel (a reductant) at near the engine exhaust temperature to eliminate the need for reductant refilling and extra heating.

Evaluation of Space-Based Constraints on Global Nitrogen Oxide Emissions with Regional Aircraft Measurements over and Downwind of Eastern North America

NASA Technical Reports Server (NTRS)

Martin, Randall V.; Sioris, Christopher E.; Chance, Kelly; Ryerson, Thomas B.; Flocke, Frank M.; Bertram, Timothy H.; Wooldridge, Paul J.; Cohen, Ronald C.; Neuman, J. Andy; Swanson, Aaron

2006-01-01

We retrieve tropospheric nitrogen dioxide (NO 2) columns for May 2004 to April 2005 from the SCIAMACHY satellite instrument to derive top-down emissions of nitrogen oxides (NO(x) = NO + NO2) via inverse modeling with a global chemical transport model (GEOS-Chem). Simulated NO 2 vertical profiles used in the retrieval are evaluated with airborne measurements over and downwind of North America (ICARTT); a northern midlatitude lightning source of 1.6 Tg N/yr minimizes bias in the retrieval. Retrieved NO2 columns are validated (r2 = 0.60, slope = 0.82) with coincident airborne in situ measurements. The top-down emissions are combined with a priori information from a bottom-up emission inventory with error weighting to achieve an improved a posteriori estimate of the global distribution of surface NOx emissions. Our a posteriori NOx emission inventory for land surface NOx emissions (46.1 Tg N/yr) is 22% larger than the GEIA-based a priori bottom-up inventory for 1998, a difference that reflects rising anthropogenic emissions, especially from East Asia A posteriori NOx emissions for East Asia (9.8 Tg N/yr) exceed those from other continents. The a posteriori inventory improves the GEOS-Chem simulation of NOx, peroxyacetylnitrate, and nitric acid with respect to airborne in situ measurements over and downwind of New York City. The a posteriori is 7% larger than the EDGAR 3.2FT2000 global inventory, 3% larger than the NEI99 inventory for the United States, and 68% larger than a regional inventory for 2000 for eastern Asia. SCIAMACHY NO2 columns over the North Atlantic show a weak plume from lightning NO(x).

Military Aircraft Emissions Research - Case of Hercules Cargo Plane (C-130H) Emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Mengdawn; Corporan, E.; DeWitt, M.

2007-01-01

Tactical airlifter like C-130H has been in use for more than 50 years, and is expected to serve for many years to come. However, the emission characteristics data of the aircraft are scarce. To increase our understanding of turboprop engine emissions, emissions from a military C-130H cargo aircraft were characterized in field conditions in the fall of 2005. Particulate and gaseous pollutants were measured by conventional and advanced instrumentation platforms that were built with in-situ extractive or remote optical sensing technologies. The measurements performed at the C-130H engine exhaust exit showed increased levels of emissions as the engine power settingmore » increased. In contrast, there was no such a relationship found for the C-130H emitted particulate matter (as a function of engine power setting) measured at about 15-m downstream of the engine exhaust plane. The emitted gaseous species measured at both locations were, however, proportional to the engine power setting and comparable (at both locations) when corrected for ambient dilution indicating the lack of particulate emission-power setting relationship at the far field is unique. The result clearly indicates that the aircraft emission factor or index for particulate matter cannot be experimentally determined at a downstream location away from the exhaust exit and has to be determined right at the engine exhaust plane. Emission indices that are needed for air quality modeling will be presented.« less

Impact of supersonic and subsonic aircraft on ozone: Including heterogeneous chemical reaction mechanisms

NASA Technical Reports Server (NTRS)

Kinnison, Douglas E.; Wuebbles, Donald J.

1994-01-01

Preliminary calculations suggest that heterogeneous reactions are important in calculating the impact on ozone from emissions of trace gases from aircraft fleets. In this study, three heterogeneous chemical processes that occur on background sulfuric acid aerosols are included and their effects on O3, NO(x), Cl(x), HCl, N2O5, ClONO2 are calculated.

Enhanced Combustion Low NOx Pulverized Coal Burner

DOE Office of Scientific and Technical Information (OSTI.GOV)

David Towle; Richard Donais; Todd Hellewell

2007-06-30

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, withmore » typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for

Reducing air pollutant emissions at airports by controlling aircraft ground operations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gelinas, C.G.; Fan, H.S.L.

1979-02-01

Potential reductions in air pollutant emissions were determined for four stategies to control aircraft ground operations at two case study airports, Los Angeles and San Francisco International Airports. Safety, cost, and fuel savings associated with strategy implementation were examined. Two strategies, aircraft towing and shutdown of one engine during taxi operations, provided significant emission reductions. However, there are a number of safety problems associated with aircraft towing. The shutdown of one engine while taxiing was found to be the most viable strategy because of substantial emission reductions, cost benefits resulting from fuel savings, and no apparent safety problems.

Characterization of chemical and particulate emissions from aircraft engines

NASA Astrophysics Data System (ADS)

Agrawal, Harshit; Sawant, Aniket A.; Jansen, Karel; Wayne Miller, J.; Cocker, David R.

2008-06-01

This paper presents a series of measurements from four on-wing, commercial aircraft engines, including two newer CFM56-7 engines and two earlier CFM56-3 engines. Samples were collected from each engine using a probe positioned behind the exhaust nozzle of the aircraft, chocked on a concrete testing pad. The emission factors for particulate matter mass, elemental and organic carbon, carbonyls, polycyclic aromatic hydrocarbons, n-alkanes, dioxins, metals and ions are reported for four different engine power setting modes. The emissions indices of particulate matter, elemental and organic carbon are highly power dependent for these engines. Particulate matter emission indices (g kg-1 fuel) are found to increase from 1.1E-02 to 2.05E-01 with increase in power from idle to 85%. The elemental carbon to organic carbon varies from 0.5 to 3.8 with change in power from idle to 85%. The carbonyl emissions are dominated by formaldehyde. The emission index of formaldehyde ranges from 2.3E-01 to 4.8E-01 g kg-1 fuel. The distribution of metals depends on the difference in the various engines. The dioxin emissions from the aircraft engines are observed to be below detection limit.

Evaluation of a Fuel-Based Oil and Gas Inventory of Nitrogen Oxides with Top-Down Emissions

NASA Astrophysics Data System (ADS)

Mcdonald, B. C.; Gorchov Negron, A.; McKeen, S. A.; Peischl, J.; Gilman, J.; Ahmadov, R.; Frost, G. J.; Ryerson, T. B.; Thompson, C. R.; Trainer, M.

2017-12-01

Several studies have highlighted overestimates in anthropogenic emissions of nitrogen oxides (NOx) for the U.S., with particular attention on the mobile source sector. In this study, we explore whether there could be overestimates in the emissions of NOx from oil and gas production regions. We construct a bottom-up inventory using publicly available fuel use records of the industry and emission factors reported in the literature. We compare both the NEI 2011 and the fuel-based inventory with top-down emission fluxes derived by aircraft and ground-based field measurement campaigns by NOAA that occurred in 2012-13, including for basins located in Uintah, Haynesville, Marcellus, and Fayetteville. Compared to the top-down fluxes, the NEI overestimates NOx by a factor of 2 across the four basins. However, the discrepancies are not uniform, reflecting variability in oil and gas engine activity and NOx emission factors. We explore this variability with our fuel-based inventory and perform a Monte Carlo analysis to assess uncertainties in emissions. We find that on average the fuel-based inventory improves the agreement with the top-down emissions, and that the top-down emissions are within the uncertainties of our analysis.

Measurements of HONO, NO, NOy and SO2 in aircraft exhaust plumes at cruise

NASA Astrophysics Data System (ADS)

Jurkat, T.; Voigt, C.; Arnold, F.; Schlager, H.; Kleffmann, J.; Aufmhoff, H.; Schäuble, D.; Schaefer, M.; Schumann, U.

2011-05-01

Measurements of gaseous nitrogen and sulfur oxide emissions in young aircraft exhaust plumes give insight into chemical oxidation processes inside aircraft engines. Particularly, the OH-induced formation of nitrous acid (HONO) from nitrogen oxide (NO) and sulfuric acid (H2SO4) from sulfur dioxide (SO2) inside the turbine which is highly uncertain, need detailed analysis to address the climate impact of aviation. We report on airborne in situ measurements at cruise altitudes of HONO, NO, NOy, and SO2 in 9 wakes of 8 different types of modern jet airliners, including for the first time also an A380. Measurements of HONO and SO2 were made with an ITCIMS (Ion Trap Chemical Ionization Mass Spectrometer) using a new ion-reaction scheme involving SF5- reagent ions. The measured molar ratios HONO/NO and HONO/NOy with averages of 0.038 ± 0.010 and 0.027 ± 0.005 were found to decrease systematically with increasing NOx emission-index (EI NOx). We calculate an average EI HONO of 0.31 ± 0.12 g NO2 kg-1. Using reliable measurements of HONO and NOy, which are less adhesive than H2SO4 to the inlet walls, we derive the OH-induced conversion fraction of fuel sulfur to sulfuric acid $\\varepsilon$ with an average of 2.2 ± 0.5 %. $\\varepsilon$ also tends to decrease with increasing EI NOx, consistent with earlier model simulations. The lowest HONO/NO, HONO/NOy and $\\varepsilon$ was observed for the largest passenger aircraft A380.

Method for control of NOx emission from combustors using fuel dilution

DOEpatents

Schefer, Robert W [Alamo, CA; Keller, Jay O [Oakland, CA

2007-01-16

A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

Sensitivities of NOx transformation and the effects on surface ozone and nitrate

NASA Astrophysics Data System (ADS)

Lei, H.; Wang, J. X. L.

2014-02-01

As precursors to tropospheric ozone and nitrate, nitrogen oxide (NOx) in the present atmosphere and its transformation in response to emission and climate perturbations are studied by using the CAM-Chem model and air quality measurements from the National Emissions Inventory (NEI), Clean Air Status and Trends Network (CASTNET), and Environmental Protection Agency Air Quality System (EPA AQS). It is found that NOx transformations in present atmospheric conditions show different sensitivities over industrial and non-industrial regions. As a result, the surface ozone and nitrate formations can be divided into several regimes associated with the dominant emission types and relative levels of NOx and volatile organic compounds (VOC). Ozone production in industrial regions (the main NOx emission source areas) increases in warmer conditions and slightly decreases following an increase in NOx emissions due to NOx titration, which is opposite to the response in non-industrial regions. The ozone decrease following a temperature increase in non-industrial regions indicates that ozone production in regions that lack NOx emission sources may be sensitive to NOx transformation in remote source regions. The increase in NO2 from NOx titration over industrial regions results in an increase rate of total nitrate that remains higher than the increase rate of NOx emissions. The presented findings indicate that a change in the ozone concentration is more directly affected by changes in climate and precursor emissions, while a change in the nitrate concentration is affected by local ozone production types and their seasonal transfer. The sensitivity to temperature perturbations shows that a warmer climate accelerates the decomposition of odd nitrogen (NOy) during the night. As a result, the transformation rate of NOx to nitrate decreases. Examinations of the historical emissions and air quality records of a typical NOx-limited area, such as Atlanta and a VOC-limited area, such as Los

RFID Transponders' RF Emissions in Aircraft Communication and Navigation Radio Bands

NASA Technical Reports Server (NTRS)

Nguyen, Truong X.; Ely, Jay J.; Koppen Sandra V.; Fersch, Mariatheresa S.

2008-01-01

Radiated emission data in aircraft communication and navigation bands are presented for several active radio frequency identification (RFID) tags. The individual tags are different in design, operation and transmitting frequencies. The process for measuring the tags emissions in a reverberation chamber is discussed. Measurement issues dealing with tag interrogation, low level measurement in the presence of strong transmissions, and tags low duty factors are discussed. The results show strong emissions, far exceeding aircraft emission limits and can be of potential interference risks.

Issues related to aircraft take-off plumes in a mesoscale photochemical model.

PubMed

Bossioli, Elissavet; Tombrou, Maria; Helmis, Costas; Kurtenbach, Ralf; Wiesen, Peter; Schäfer, Klaus; Dandou, Aggeliki; Varotsos, Kostas V

2013-07-01

The physical and chemical characteristics of aircraft plumes at the take-off phase are simulated with the mesoscale CAMx model using the individual plume segment approach, in a highly resolved domain, covering the Athens International Airport. Emission indices during take-off measured at the Athens International Airport are incorporated. Model predictions are compared with in situ point and path-averaged observations (NO, NO₂) downwind of the runway at the ground. The influence of modeling process, dispersion properties and background air composition on the chemical evolution of the aircraft plumes is examined. It is proven that the mixing properties mainly determine the plume dispersion. The initial plume properties become significant for the selection of the appropriate vertical resolution. Besides these factors, the background NOx and O₃ concentration levels control NOx distribution and their conversion to nitrogen reservoir species. Copyright © 2013 Elsevier B.V. All rights reserved.

Impact of aircraft NO x emission on NO x and ozone over China

NASA Astrophysics Data System (ADS)

Liu, Yu; Isaksen, I. S. A.; Sundet, J. K.; Zhou, Xiuji; Ma, Jianzhong

2003-07-01

A three-dimensional global chemistry transport model (OSLO CTM2) is used to investigate the impact of subsonic aircraft NO x emission on NO x and ozone over China in terms of a year 2000 scenario of subsonic aircraft NO x emission. The results show that subsonic aircraft NO x emission significantly affects northern China, which makes NO x at 250 hPa increase by about 50 pptv with the highest percentage of 60% in January, and leading to an ozone increase of 8 ppbv with 5% relative change in April. The NO x increase is mainly attributed to the transport process, but ozone increase is produced by the chemical process. The NO x increases by less than 10 pptv by virtue of subsonic aircraft NO x emission over China, and ozone changes less than 0.4 ppbv. When subsonic aircraft NO x emission over China is doubled, its influence is still relatively small.

INVESTIGATION OF SELECTIVE CATALYTIC REDUCTION IMPACT ON MERCURY SPECIATION UNDER SIMULATED NOX EMISSION CONTROL CONDITIONS

EPA Science Inventory

Selective catalytic reduction (SCR) technology is being increasingly applied for controlling emissions of nitrogen oxides (NOx) from coal-fired boilers. Some recent field and pilot studies suggest that the operation of SCR could affect the chemical form of mercury in the coal com...

Impact of the 2008 Global Recession on Air Quality over the United States: Implications for Surface Ozone Levels from Changes in NOx Emissions

NASA Technical Reports Server (NTRS)

Tong, Daniel; Pan, Li; Chen, Weiwei; Lamsal, Lok; Lee, Pius; Tang, Youhua; Kim, Hyuncheol; Kondragunta, Shobha; Stajner, Ivanka

2016-01-01

Satellite and ground observations detected large variability in nitrogen oxides (NOx) during the 2008 economic recession, but the impact of the recession on air quality has not been quantified. This study combines observed NOx trends and a regional chemical transport model to quantify the impact of the recession on surface ozone (O3) levels over the continental United States. The impact is quantified by simulating O3 concentrations under two emission scenarios: business-as-usual (BAU) and recession. In the BAU case, the emission projection from the Cross-State Air Pollution Rule is used to estimate the would-be NOx emission level in 2011. In the recession case, the actual NO2 trends observed from Air Quality System ground monitors and the Ozone Monitoring Instrument on the Aura satellite are used to obtain realistic changes in NOx emissions. The model prediction with the recession effect agrees better with ground O3 observations over time and space than the prediction with the BAU emission. The results show that the recession caused a 12ppbv decrease in surface O3 concentration over the eastern United States, a slight increase (0.51ppbv) over the Rocky Mountain region, and mixed changes in the Pacific West. The gain in air quality benefits during the recession, however, could be quickly offset by the much slower emission reduction rate during the post-recession period.

Towards Ideal NOx and CO2 Emission Control Technology for Bio-Oils Combustion Energy System Using a Plasma-Chemical Hybrid Process

NASA Astrophysics Data System (ADS)

Okubo, M.; Fujishima, H.; Yamato, Y.; Kuroki, T.; Tanaka, A.; Otsuka, K.

2013-03-01

A pilot-scale low-emission boiler system consisting of a bio-fuel boiler and plasma-chemical hybrid NOx removal system is investigated. This system can achieve carbon neutrality because the bio-fuel boiler uses waste vegetable oil as one of the fuels. The plasma-chemical hybrid NOx removal system has two processes: NO oxidation by ozone produced from plasma ozonizers and NO2 removal using a Na2SO3 chemical scrubber. Test demonstrations of the system are carried out for mixed oils (mixture of A-heavy oil and waste vegetable oil). Stable combustion is achieved for the mixed oil (20 - 50% waste vegetable oil). Properties of flue gas—e.g., O2, CO2 and NOx—when firing mixed oils are nearly the same as those when firing heavy oil for an average flue gas flow rate of 1000 Nm3/h. NOx concentrations at the boiler outlet are 90 - 95 ppm. Furthermore, during a 300-min continuous operation when firing 20% mixed oil, NOx removal efficiency of more than 90% (less than 10 ppm NOx emission) is confirmed. In addition, the CO2 reduction when heavy oil is replaced with waste vegetable oil is estimated. The system comparison is described between the plasma-chemical hybrid NOx removal and the conventional technology.

Effects of NOx control and plume mixing on nighttime chemical processing of plumes from coal-fired power plants

NASA Astrophysics Data System (ADS)

Brown, Steven S.; Dubé, William P.; Karamchandani, Prakash; Yarwood, Greg; Peischl, Jeff; Ryerson, Thomas B.; Neuman, J. Andrew; Nowak, John B.; Holloway, John S.; Washenfelder, Rebecca A.; Brock, Charles A.; Frost, Gregory J.; Trainer, Michael; Parrish, David D.; Fehsenfeld, Frederick C.; Ravishankara, A. R.

2012-04-01

Coal-fired electric power plants produce a large fraction of total U.S. NOx emissions, but NOx from this sector has been declining in the last decade owing to installation of control technology. Nighttime aircraft intercepts of plumes from two different Texas power plants (Oklaunion near Wichita Falls and W. A. Parish near Houston) with different control technologies demonstrate the effect of these reductions on nighttime NOxoxidation rates. The analysis shows that the spatial extent of nighttime-emitted plumes to be quite limited and that mixing of highly concentrated plume NOx with ambient ozone is a determining factor for its nighttime oxidation. The plume from the uncontrolled plant had full titration of ozone through 74 km/2.4 h of downwind transport that suppressed nighttime oxidation of NO2 to higher oxides of nitrogen across the majority of the plume. The plume from the controlled plant did not have sufficient NOx to titrate background ozone, which led to rapid nighttime oxidation of NO2 during downwind transport. A plume model that includes horizontal mixing and nighttime chemistry reproduces the observed structures of the nitrogen species in the plumes from the two plants. The model shows that NOx controls not only reduce the emissions directly but also lead to an additional overnight NOx loss of 36-44% on average. The maximum reduction for 12 h of transport in darkness was 73%. The results imply that power plant NOxemissions controls may produce a larger than linear reduction in next-day, downwind ozone production following nighttime transport.

Procedure for generating global atmospheric engine emissions data from future supersonic transport aircraft. The 1990 high speed civil transport studies

NASA Technical Reports Server (NTRS)

Sohn, R. A.; Stroup, J. W.

1990-01-01

The input for global atmospheric chemistry models was generated for baseline High Speed Civil Transport (HSCT) configurations at Mach 1.6, 2.2, and 3.2. The input is supplied in the form of number of molecules of specific exhaust constituents injected into the atmosphere per year by latitude and by altitude (for 2-D codes). Seven exhaust constituents are currently supplied: NO, NO2, CO, CO2, H2O, SO2, and THC (Trace Hydrocarbons). An eighth input is also supplied, NO(x), the sum of NO and NO2. The number of molecules of a given constituent emitted per year is a function of the total fuel burned by a supersonic fleet and the emission index (EI) of the aircraft engine for the constituent in question. The EIs for an engine are supplied directly by the engine manufacturers. The annual fuel burn of a supersonic fleet is calculated from aircraft performance and economic criteria, both of which are strongly dependent on basic design parameters such as speed and range. The altitude and latitude distribution of the emission is determined based on 10 Intern. Air Transport Assoc. (IATA) regions chosen to define the worldwide route structure for future HSCT operations and the mission flight profiles.

Emission characteristics of kerosene-air spray combustion with plasma assistance

NASA Astrophysics Data System (ADS)

Liu, Xingjian; He, Liming; Zeng, Hao; Jin, Tao; Chen, Yi; Zhang, Yihan; Liu, Pengfei

2015-09-01

A plasma assisted combustion system for combustion of kerosene-air mixtures was developed to study emission levels of O2, CO2, CO, and NOx. The emission measurement was conducted by Testo 350-Pro Flue Gas Analyzer. The effect of duty ratio, feedstock gas flow rate and applied voltage on emission performance has been analyzed. The results show that O2 and CO emissions reduce with an increase of applied voltage, while CO2 and NOx emissions increase. Besides, when duty ratio or feedstock gas flow rate decreases, the same emission results would appear. The emission spectrum of the air plasma of plasma assisted combustion actuator was also registered to analyze the kinetic enhancement effect of plasma, and the generation of ozone was believed to be the main factor that plasma makes a difference in our experiment. These results are valuable for the future optimization of kerosene-fueled aircraft engine when using plasma assisted combustion devices to exert emission control.

RFID Transponders' Radio Frequency Emissions in Aircraft Communication and Navigation Radio Bands

NASA Technical Reports Server (NTRS)

Nguyen, Truong X.; Ely, Jay J.; Williams, Reuben A.; Koppen, Sandra V.; Salud, Maria Theresa P.

2006-01-01

Radiated emissions in aircraft communication and navigation bands are measured from several active radio frequency identification (RFID) tags. The individual tags are different in design and operations. They may also operate in different frequency bands. The process for measuring the emissions is discussed, and includes tag interrogation, reverberation chamber testing, and instrument settings selection. The measurement results are described and compared against aircraft emission limits. In addition, interference path loss for the cargo bays of passenger aircraft is measured. Cargo bay path loss is more appropriate for RFID tags than passenger cabin path loss. The path loss data are reported for several aircraft radio systems on a Boeing 747 and an Airbus A320.

Aircraft Engine Technology for Green Aviation to Reduce Fuel Burn

NASA Technical Reports Server (NTRS)

Hughes, Christopher E.; VanZante, Dale E.; Heidmann, James D.

2013-01-01

The NASA Fundamental Aeronautics Program Subsonic Fixed Wing Project and Integrated Systems Research Program Environmentally Responsible Aviation Project in the Aeronautics Research Mission Directorate are conducting research on advanced aircraft technology to address the environmental goals of reducing fuel burn, noise and NOx emissions for aircraft in 2020 and beyond. Both Projects, in collaborative partnerships with U.S. Industry, Academia, and other Government Agencies, have made significant progress toward reaching the N+2 (2020) and N+3 (beyond 2025) installed fuel burn goals by fundamental aircraft engine technology development, subscale component experimental investigations, full scale integrated systems validation testing, and development validation of state of the art computation design and analysis codes. Specific areas of propulsion technology research are discussed and progress to date.

Final Rule for Control of Air Pollution From Aircraft and Aircraft Engines; Emission Standards and Test Procedures

EPA Pesticide Factsheets

EPA adopted emission standards and related provisions for aircraft gas turbine engines with rated thrusts greater than 26.7 kilonewtons. These engines are used primarily on commercial passenger and freight aircraft.

Control of NOx Emissions from Stationary Combustion Sources

EPA Science Inventory

In general, NOx control technologies are categorized as being either primary control technologies or secondary control technologies. Primary control technologies reduce the formation of NOx in the primary combustion zone. In contrast, secondary control technologies destroy the NO...

Comparison of methodologies estimating emissions of aircraft pollutants, environmental impact assessment around airports

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kurniawan, Jermanto S., E-mail: Jermanto.kurniawan@inrets.fr; Khardi, S., E-mail: Salah.khardi@inrets.f

2011-04-15

Air transportation growth has increased continuously over the years. The rise in air transport activity has been accompanied by an increase in the amount of energy used to provide air transportation services. It is also assumed to increase environmental impacts, in particular pollutant emissions. Traditionally, the environmental impacts of atmospheric emissions from aircraft have been addressed in two separate ways; aircraft pollutant emissions occurring during the landing and take-off (LTO) phase (local pollutant emissions) which is the focus of this study, and the non-LTO phase (global/regional pollutant emissions). Aircraft pollutant emissions are an important source of pollution and directly ormore » indirectly harmfully affect human health, ecosystems and cultural heritage. There are many methods to asses pollutant emissions used by various countries. However, using different and separate methodology will cause a variation in results, some lack of information and the use of certain methods will require justification and reliability that must be demonstrated and proven. In relation to this issue, this paper presents identification, comparison and reviews of some of the methodologies of aircraft pollutant assessment from the past, present and future expectations of some studies and projects focusing on emissions factors, fuel consumption, and uncertainty. This paper also provides reliable information on the impacts of aircraft pollutant emissions in short term and long term predictions.« less

Analysis of Strategies for Multiple Emissions from Electric Power SO2, NOX, CO2, Mercury and RPS

EIA Publications

2001-01-01

At the request of the Subcommittee, the Energy Information Administration prepared an initial report that focused on the impacts of reducing power sector NOx, SO2, and CO2 emissions. The current report extends the earlier analysis to add the impacts of reducing power sector mercury emissions and introducing renewable portfolio standard (RPS) requirements.

Status review of NASA programs for reducing aircraft gas turbine engine emissions

NASA Technical Reports Server (NTRS)

Rudey, R. A.

1976-01-01

Programs initiated by NASA to develop and demonstrate low emission advanced technology combustors for reducing aircraft gas turbine engine pollution are reviewed. Program goals are consistent with urban emission level requirements as specified by the U. S. Environmental Protection Agency and with upper atmosphere cruise emission levels as recommended by the U. S. Climatic Impact Assessment Program and National Research Council. Preliminary tests of advanced technology combustors indicate that significant reductions in all major pollutant emissions should be attainable in present generation aircraft gas turbine engines without adverse effects on fuel consumption. Preliminary test results from fundamental studies indicate that extremely low emission combustion systems may be possible for future generation jet aircraft. The emission reduction techniques currently being evaluated in these programs are described along with the results and a qualitative assessment of development difficulty.

Measurement of NOx fluxes from a tall tower in Beijing

NASA Astrophysics Data System (ADS)

Squires, Freya; Dunmore, Rachel; Lewis, Alastair; Vaughan, Adam; Mullinger, Neil; Nemitz, Eiko; Wild, Oliver; Zhang, Qiang; Hamilton, Jacqueline; Lee, James; Fu, Pingqing

2017-04-01

Nitrogen Oxides (NOx, the sum of nitrogen monoxide (NO) and nitrogen dioxide (NO2)) are significant anthropogenic pollutants emitted from most combustion processes. NOx is a precursor species to the formation of O3 and secondary aerosols and, in high concentrations, NO2 can have adverse effects on human health through action as a respiratory irritant. For these reasons, there has been increased focus on improving NOx emissions inventories, typically developed using 'bottom-up' estimates of emissions from their sources, which are used to predict current and future air quality and to guide abatement strategy. Recent studies have shown a discrepancy between NOx inventories and measured NOx emissions for UK cities, highlighting the limitations of bottom-up emissions inventories and the importance of accurate measurement data to improve the estimates. Similarly, inventories in China are associated with large uncertainties and are rapidly changing with time in response to economic development and new environmental regulation. Here, we present data collected as part of the Air Pollutants in Beijing (AIRPOLL-Beijing) campaign from an urban site located at the Institute of Atmospheric Physics, Chinese Academy of Sciences (IAP, CAS) (39˚ 58'28"N, 116˚ 22'16"E) in central Beijing. NOx concentrations were measured using a state-of-the-art chemiluminescence instrument, sampling from an inlet at 100 metres on a meteorological tower. Measurements at 5 Hz coupled with wind vector data measured by a sonic anemometer located at the same height as the inlet allowed NOx emission fluxes to be calculated using the eddy covariance method. Measurements were made during the period 11/11/2016 - 10/12/2016 and compared to existing emission estimates from The Multi-resolution Emission Inventory for China (MEIC) inventory. It is anticipated that this work will be used to evaluate the accuracy of emissions inventories for Beijing, to develop improved emissions estimates and thus provide

Ozone Trends Across the United States over a Period of Decreasing NOx and VOC Emissions

EPA Science Inventory

In this work, we evaluate ambient ozone trends at urban, suburban, and rural monitoring sites across the United States over a period of decreasing NOx and VOC emissions (1998–2013). We find that decreasing ozone trends generally occur in the summer, in less urbanized areas,...

Comparison of Weekly Cycle of NO2 Satellite Retrievals and NO(x) Emission Inventories for the Continental United States

NASA Technical Reports Server (NTRS)

Kaynak, B.; Hu, Y.; Martin, R. V.; Sioris, C. E.; Russell, A. G.

2009-01-01

Spatially resolved weekly NO2 variations are obtained from 2003 to 2005 Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) tropospheric NO2 columns for three different types of regions: urban, rural, and rural-point (rural with significant electricity generation unit (EGU) emissions). Regions are compared for magnitudes and weekly profiles. Rural regions do not show any weekly pattern, whereas urban areas show a distinct decrease on the weekends. Rural regions with EGUs show a slight decrease on Sundays. When compared with estimated mobile and stationary nitrogen oxides (NO(x)) emissions from the year 2004 for seven cities, the satellite data have greater variation during weekdays (Monday-Friday). Overall comparisons show that SCIAMACHY derived NO2 correlate well with estimated NO(x) emissions for urban and rural but less for rural-point regions.

Dust emissions created by low-level rotary-winged aircraft flight over desert surfaces

NASA Astrophysics Data System (ADS)

Gillies, J. A.; Etyemezian, V.; Kuhns, H.; McAlpine, J. D.; King, J.; Uppapalli, S.; Nikolich, G.; Engelbrecht, J.

2010-03-01

There is a dearth of information on dust emissions from sources that are unique to U.S. Department of Defense testing and training activities. Dust emissions of PM 10 and PM 2.5 from low-level rotary-winged aircraft travelling (rotor-blade ≈7 m above ground level) over two types of desert surfaces (i.e., relatively undisturbed desert pavement and disturbed desert soil surface) were characterized at the Yuma Proving Ground (Yuma, AZ) in May 2007. Fugitive emissions are created by the shear stress of the outflow of high speed air created by the rotor-blade. The strength of the emissions was observed to scale primarily as a function of forward travel speed of the aircraft. Speed affects dust emissions in two ways: 1) as speed increases, peak shear stress at the soil surface was observed to decline proportionally, and 2) as the helicopter's forward speed increases its residence time over any location on the surface diminishes, so the time the downward rotor-generated flow is acting upon that surface must also decrease. The state of the surface over which the travel occurs also affects the scale of the emissions. The disturbed desert test surface produced approximately an order of magnitude greater emission than the undisturbed surface. Based on the measured emission rates for the test aircraft and the established scaling relationships, a rotary-winged aircraft similar to the test aircraft traveling 30 km h -1 over the disturbed surface would need to travel 4 km to produce emissions equivalent to one kilometer of travel by a light wheeled military vehicle also traveling at 30 km h -1 on an unpaved road. As rotary-winged aircraft activity is substantially less than that of off-road vehicle military testing and training activities it is likely that this source is small compared to emissions created by ground-based vehicle movements.

Air Pollution Caused By Aircrafts in LTO-number-Record Breaking Year 2016 at Istanbul Atatürk Airport

NASA Astrophysics Data System (ADS)

Sen, Orhan; Durmus, Onur

2017-04-01

2016 was a record breaking year in terms of LTO numbers at Istanbul Atatürk Airport. The days with maximum LTO (Landing- Take-off) numbers coincides with the beginning or end of national festival days. In this study, air pollutant (HC, NOx, CO, SO2) quantities that are released as a result of LTO activities taking place at Atatürk Airport in 10-months-period of the year 2016 when LTO numbers reached peak point and emission quantities resulting from aircrafts on the days when maximum LTO numbers happened on a daily basis have been calculated with Tier 2 method. In Tier 2 method emission less than 935m (3000ft) of atmosphere during LTO activities related to airplane type without making domestic or international distinction and free from landing/ take-off point play an important role. This approach is used in calculating emissions that are being released to the atmosphere during LTO activities which have a maximum effect on air pollution by taking into account the fuel consumption of each airplane type and with the help of determined emission coefficients. As a result of the calculations between 01.01.2016 and 25.10.2016 at Istanbul Atatürk Airport, 186.986 LTO cycle took place by passenger and cargo aircrafts. And 209.984 tones fuel were consumed. As a result of this fuel consumption 187,2 tones hydrocarbon (HC), 3263,9 tones nitrogen oxide (NOx), 1626,5 tones carbon monoxide (CO) and 210 tones sulphur dioxide (SO2) emission were released as air pollutants. Keyword: LTO, Air pollution, Aircraft

NOx Sensor for Direct Injection Emission Control

DOE Office of Scientific and Technical Information (OSTI.GOV)

Betteridge, William J

2006-02-28

The Electricore/Delphi team continues to leverage the electrochemical planar sensor technology that has produced stoichiometric planar and wide range oxygen sensors as the basis for development of a NOx sensor. Zirconia cell technology with an integrated heater will provide the foundation for the sensor structure. Proven materials and packaging technology will help to ensure a cost-effective approach to the manufacture of this sensor. The electronics technique and interface is considered to be an area where new strategies need to be employed to produce higher S/N ratios of the NOx signal with emphasis on signal stability over time for robustness andmore » durability Both continuous mode and pulse mode control techniques are being evaluated. Packaging the electronics requires careful design and circuit partitioning so that only the necessary signal conditioning electronics are coupled directly in the wiring harness, while the remainder is situated within the ECM for durability and costs reasons. This task continues to be on hold due to the limitation that the definition of the interface electronics was unavailable until very late in the project. The sense element is based on the amperometric method utilizing integrated alumina and zirconia ceramics. Precious metal electrodes are used to form the integrated heater, the cell electrodes and leads. Inside the actual sense cell structure, it is first necessary to separate NOx from the remaining oxygen constituents of the exhaust, without reducing the NOx. Once separated, the NOx will be measured using a measurement cell. Development or test coupons have been used to facilitate material selection and refinement, cell, diffusion barrier, and chamber development. The sense element currently requires elaborate interconnections. To facilitate a robust durable connection, mechanical and metallurgical connections are under investigation. Materials and process refinements continue to play an important role in the development

Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines

NASA Astrophysics Data System (ADS)

Spicer, C. W.; Holdren, M. W.; Riggin, R. M.; Lyon, T. F.

1994-10-01

Assessment of the environmental impact of aircraft emissions is required by planners and policy makers. Seveal areas of concern are: 1. exposure of airport workers and urban residents to toxic chemicals emitted when the engines operate at low power (idle and taxi) on the ground; 2. contributions to urban photochemical air pollution of aircraft volatile organic and nitrogen oxides emissions from operations around airports; and 3. emissions of nitrogen oxides and particles during high-altitude operation. The environmental impact of chemicals emitted from jet aircraft turbine engines has not been firmly established due to lack of data regarding emission rates and identities of the compounds emitted. This paper describes an experimental study of two different aircraft turbine engines designed to determine detailed organic emissions, as well as emissions of inorganic gases. Emissions were measured at several engine power settings. Measurements were made of detailed organic composition from C1 through C17, CO, CO2, NO, NOx, and polycyclic aromatic hydrocarbons. Measurements were made using a multi-port sampling pro be positioned directly behind the engine in the exhaust exit plane. The emission measurements have been used to determine the organic distribution by carbon number and the distribution by compound class at each engine power level. The sum of the organic species was compared with an independent measurement of total organic carbon to assess the carbon mass balance. A portion of the exhaust was captured and irradiated in outdoor smog chambers to assess the photochemical reactivity of the emissions with respect to ozone formation. The reactivity of emissions from the two engines was apportioned by chemical compound class.

Aviation and climate change : aircraft emissions expected to grow, but technological and operational improvements and government policies can help control emissions

DOT National Transportation Integrated Search

2009-06-01

A number of policy options to address aircraft emissions are available to governments and can be part of broader policies to address emissions from many sources including aircraft. Market-based measures can establish a price for emissions and provide...

Fluidized combustion of coal. [to limit SO2 and NOx emissions

NASA Technical Reports Server (NTRS)

Pope, M.

1978-01-01

A combustion technology that permits the burning of low quality coal, and other fuels, while maintaining stack emissions within State and Federal EPA limits is discussed. Low quality fuels can be burned directly in fluidized beds while taking advantage of low furnace temperatures and chemical activity within the bed to limit SO2 and NOx emissions. The excellent heat transfer characteristics of the fluidized beds also result in a reduction of total heat transfer surface requirements. Tests on beds operating at pressures of one to ten atmospheres, at temperatures as high as 1600 F, and with gas velocities in the vicinity of four to twelve feet per second, have proven the concept. The progress that has been made in the development of fluidized bed combustion technology and work currently underway are discussed.

Modeling the weekly cycle of NOx and CO emissions and their impacts on O3 in the Los Angeles-South Coast Air Basin during the CalNex 2010 field campaign

NASA Astrophysics Data System (ADS)

Kim, S.-W.; McDonald, B. C.; Baidar, S.; Brown, S. S.; Dube, B.; Ferrare, R. A.; Frost, G. J.; Harley, R. A.; Holloway, J. S.; Lee, H.-J.; McKeen, S. A.; Neuman, J. A.; Nowak, J. B.; Oetjen, H.; Ortega, I.; Pollack, I. B.; Roberts, J. M.; Ryerson, T. B.; Scarino, A. J.; Senff, C. J.; Thalman, R.; Trainer, M.; Volkamer, R.; Wagner, N.; Washenfelder, R. A.; Waxman, E.; Young, C. J.

2016-02-01

We developed a new nitrogen oxide (NOx) and carbon monoxide (CO) emission inventory for the Los Angeles-South Coast Air Basin (SoCAB) expanding the Fuel-based Inventory for motor-Vehicle Emissions and applied it in regional chemical transport modeling focused on the California Nexus of Air Quality and Climate Change (CalNex) 2010 field campaign. The weekday NOx emission over the SoCAB in 2010 is 620 t d-1, while the weekend emission is 410 t d-1. The NOx emission decrease on weekends is caused by reduced diesel truck activities. Weekday and weekend CO emissions over this region are similar: 2340 and 2180 t d-1, respectively. Previous studies reported large discrepancies between the airborne observations of NOx and CO mixing ratios and the model simulations for CalNex based on the available bottom-up emission inventories. Utilizing the newly developed emission inventory in this study, the simulated NOx and CO mixing ratios agree with the observations from the airborne and the ground-based in situ and remote sensing instruments during the field study. The simulations also reproduce the weekly cycles of these chemical species. Both the observations and the model simulations indicate that decreased NOx on weekends leads to enhanced photochemistry and increase of O3 and Ox (=O3 + NO2) in the basin. The emission inventory developed in this study can be extended to different years and other urban regions in the U.S. to study the long-term trends in O3 and its precursors with regional chemical transport models.

78 FR 65554 - Exhaust Emission Standards for New Aircraft Turbine Engines and Identification Plate for Aircraft...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-01

... DEPARTMENT OF TRANSPORTATION Federal Aviation Administration 14 CFR Parts 34 and 45 [Docket No.: FAA-2012-1333; Amendment No. 34-5A] RIN 2120-AK15 Exhaust Emission Standards for New Aircraft Turbine Engines and Identification Plate for Aircraft Engines Correction In rule document 2013-24712, appearing on...

Impact of aircraft emissions on air quality in the vicinity of airports. Volume II. An updated model assessment of aircraft generated air pollution at LAX, JFK, and ORD. Final report Jan 1978-Jul 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yamartino, R.J.; Smith, D.G.; Bremer, S.A.

1980-07-01

This report documents the results of the Federal Aviation Administration (FAA)/Environmental Protection Agency (EPA) air quality study which has been conducted to assess the impact of aircraft emissions of carbon monoxide (CO), hydrocarbons (HC), and oxides of nitrogen (NOx) in the vicinity of airports. This assessment includes the results of recent modeling and monitoring efforts at Washington National (DCA), Los Angeles International (LAX), Dulles International (IAD), and Lakeland, Florida airports and an updated modeling of aircraft generated pollution at LAX, John F. Kennedy (JFK) and Chicago O'Hare (ORD) airports. The Airport Vicinity Air Pollution (AVAP) model which was designed formore » use at civil airports was used in this assessment. In addition the results of the application of the military version of the AVAP model the Air Quality Assessment Model (AQAM), are summarized. Both the results of the pollution monitoring analyses in Volume I and the modeling studies in Volume II suggest that: maximum hourly average CO concentrations from aircraft are unlikely to exceed 5 parts per million (ppm) in areas of public exposure and are thus small in comparison to the National Ambient Air Quality Standard of 35 ppm; maximum hourly HC concentrations from aircraft can exceed 0.25 ppm over an area several times the size of the airport; and annual average NO2 concentrations from aircraft are estimated to contribute only 10 to 20 percent of the NAAQS limit level.« less

Rain-induced emission pulses of NOx and HCHO from soils in African regions after dry spells as viewed by satellite sensors

NASA Astrophysics Data System (ADS)

Zörner, Jan; Penning de Vries, Marloes; Beirle, Steffen; Veres, Patrick; Williams, Jonathan; Wagner, Thomas

2014-05-01

Outside industrial areas, soil emissions of NOx (stemming from bacterial emissions of NO) represent a considerable fraction of total NOx emissions, and may even dominate in remote tropical and agricultural areas. NOx fluxes from soils are controlled by abiotic and microbiological processes which depend on ambient environmental conditions. Rain-induced spikes in NOx have been observed by in-situ measurements and also satellite observations. However, the estimation of soil emissions over broad geographic regions remains uncertain using bottom-up approaches. Independent, global satellite measurements can help constrain emissions used in chemical models. Laboratory experiments on soil fluxes suggest that significant HCHO emissions from soil can occur. However, it has not been previously attempted to detect HCHO emissions from wetted soils by using satellite observations. This study investigates the evolution of tropospheric NO2 (as a proxy for NOx) and HCHO column densities before and after the first rain fall event following a prolonged dry period in semi-arid regions, deserts as well as tropical regions in Africa. Tropospheric NO2 and HCHO columns retrieved from OMI aboard the AURA satellite, GOME-2 aboard METOP and SCIAMACHY aboard ENVISAT are used to study and inter-compare the observed responses of the trace gases with multiple space-based instruments. The observed responses are prone to be affected by other sources like lightning, fire, influx from polluted air masses, as well measurement errors in the satellite retrieval caused by manifold reasons such as an increased cloud contamination. Thus, much care is taken verify that the observed spikes reflect enhancements in soil emissions. Total column measurements of H2O from GOME-2 give further insight into the atmospheric state and help to explain the increase in humidity before the first precipitation event. The analysis is not only conducted for averages of distinct geographic regions, i.e. the Sahel, but also

Satellite-based observations of rain-induced NOx emissions from soils around Lake Chad in the Sahel