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Sample records for alumina scale spallation

  1. Moisture-Induced Alumina Scale Spallation: The Hydrogen Factor

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2010-01-01

    For some time the oxidation community has been concerned with interfacial spallation of protective alumina scales, not just upon immediate cool down, but as a time-delayed phenomenon. Moisture-induced delayed spallation (MIDS) and desktop spallation (DTS) of thermal barrier coatings (TBCs) refer to this process. It is most apparent for relatively adherent alumina scales that have survived initial cool down in a dry environment, have built up considerable thickness and strain energy, and have been somewhat damaged, such as by cyclic oxidation cracking. Indeed, a "sensitive zone" can be described that maximizes the observed effect as a function of all the relevant factors. Moisture has been postulated to serve as a source of interfacial hydrogen embrittlement. Hydrogen is derived from reaction with aluminum in the alloy at an exposed interface. The purpose of this monograph is to trace the close analogy of this phenomenon to other hydrogen-induced effects, such as embrittlement of aluminides and blistering of alloys and anodic alumina films. A formalized, top-down, logic-tree structure is presented as a guide to this discussion. A theoretical basis for interfacial weakening by hydrogen is first cited, as are demonstrations of hydrogen detection as a reaction product or interfacial species. Further support is provided by critical experiments that recreate the moisture effect, but by isolating hydrogen from other potential causative factors. These experiments include tests in H 2-containing atmospheres or cathodic hydrogen charging. Accordingly, they strongly indicate that interfacial hydrogen, derived from moisture, is the key chemical species accounting for delayed alumina scale spallation.

  2. Moisture-Induced Alumina Scale Spallation: The Hydrogen Factor

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2009-01-01

    For some time our community has been concerned with interfacial spallation of protective alumina scales, not just upon immediate cooldown, but as a time-delayed phenomenon. Moisture-induced delayed spallation (MIDS) and desktop spallation (DTS) of TBC's refer to this process. It is most apparent for relatively adherent alumina scales that have survived cool down in a dry environment, built up considerable thickness and strain energy, and have been somewhat damaged, such as by cyclic oxidation cracking. Indeed, a "sweet zone" can be defined that maximizes the observed effect as a function of all the relevant factors. Moisture has been postulated to serve as a source of interfacial hydrogen embrittlement derived from reaction with aluminum in the alloy at an exposed interface. The purpose of this monograph is to trace the close analogy of this phenomenon to other hydrogen effects, such as embrittlement of aluminides and blistering of alloys and anodic alumina films. A formalized, top-down, logic tree structure is presented as a guide to this discussion. A theoretical basis for interfacial weakening by hydrogen is first cited, as are demonstrations of hydrogen as a reaction product or detected interfacial species. Further support is provided by critical experiments that produce the same moisture effect, but by isolating hydrogen from other potential causative factors. These experiments include tests in H2-containing atmospheres or cathodic hydrogen charging.

  3. Sulfur and Moisture Effects on Alumina Scale and TBC Spallation

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2007-01-01

    It has been well established that a few ppmw sulfur impurity may segregate to the interface of thermally grown alumina scales and the underlying substrate, resulting in bond degradation and premature spallation. This has been shown for NiAl and NiCrAl-based alloys, bare single crystal superalloys, or coated superalloys. The role of reactive elements (especially Y) has been to getter the sulfur in the bulk and preclude interfacial segregation. Pt additions are also very beneficial, however a similar thermodynamic explanation does not apply. The purpose of the present discussion is to highlight some observations of these effects on Rene'142, Rene'N5, PWA1480, and PWA1484. For PWA1480, we have mapped cyclic oxidation and spallation in terms of potential sulfur interfacial layers and found that a cumulative amount of about one monolayer is sufficient to degrade long term adhesion. Depending on substrate thickness, optimum performance occurs if sulfur is reduced below about 0.2-0.5 ppmw. This is accomplished in the laboratory by hydrogen annealing or commercially by melt-fluxing. Excellent 1150 C cyclic oxidation is thus demonstrated for desulfurized Rene'142, Rene'N5, and PWA1484. Alternatively, a series of N5 alloys provided by GE-AE have shown that as little as 15 ppmw of Y dopant was effective in providing remarkable scale adhesion. In support of a Y-S gettering mechanism, hydrogen annealing was unable to desulfurize these alloys from their initial level of 5 ppmw S. This impurity and critical doping level corresponds closely to YS or Y2S3 stoichiometry. In many cases, Y-doped alloys or alloys with marginal sulfur levels exhibit an oxidative sensitivity to the ambient humidity called Moisture-Induced Delayed Spallation (MIDS). After substantial scale growth, coupled with damage from repeated cycling, cold samples may spall after a period of time, breathing on them, or immersing them in water. While stress corrosion arguments may apply, we propose that the underlying

  4. Moisture-Induced Spallation and Interfacial Hydrogen Embrittlement of Alumina Scales

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2005-01-01

    Thermal expansion mismatch stresses and interfacial sulfur activity are the major factors producing primary Al2O3 scale spallation on high temperature alloys. However, moisture-induced delayed spallation appears as a secondary, but often dramatic, illustration of an additional mechanistic detail. A historical review of delayed failure of alumina scales and TBC s on superalloys is presented herein. Similarities with metallic phenomena suggest that hydrogen embrittlement from ambient humidity, resulting from the reaction Al+3H2O=Al(OH)3+3H(+)+3e(-), is the operative mechanism. This proposal was tested by standard cathodic hydrogen charging in 1N H2SO4, applied to Rene N5 pre-oxidized at 1150 C for 1000 1-hr cycles, and monitored by weight change, induced current, and microstructure. Here cathodic polarization at -2.0 V abruptly stripped mature Al2O3 scales at the oxide-metal interface. Anodic polarization at +2.0 V, however, produced alloy dissolution. Finally, with no applied voltage, the electrolyte alone produced neither scale spallation nor alloy dissolution. These experiments thus highlight the detrimental effects of hydrogen charging on alumina scale adhesion. It is proposed that interfacial hydrogen embrittlement is produced by moist air and is the root cause of both moisture-induced, delayed scale spallation and desktop TBC failures.

  5. Moisture-Induced Delayed Alumina Scale Spallation on a Ni(Pt)Al Coating

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2009-01-01

    Delayed interfacial scale failure takes place after cooling for samples of a Ni(Pt)Al-coated CMSX4 single crystal superalloy, cycled at 1150 C for up to 2000 hr. One sample exhibited premature coating grain boundary wrinkling, alumina scale spallation to bare metal, and a final weight loss of 3.3 mg/cm2 . Spallation under ambient conditions was monitored with time after cooldown and was found to continue for 24 hr. This produced up to 0.05 mg/cm2 additional loss for each hold, accumulating 0.7 mg/cm 2 (20 percent of the total) over the course of the test. After test termination, water immersion produced an additional 0.15 mg/cm2 loss. (A duplicate sample produced much less wrinkling and time dependent spalling, maintaining a net weight gain.) The results are consistent with the general phenomena of moisture-induced delayed spallation (MIDS) of mature, distressed alumina scales formed on oxidation resistant M-Al alloys. Relative ambient humidity is discussed as the factor controlling adsorbed moisture, reaction with the substrate, and hydrogen effects on interface strength.

  6. Delayed Alumina Scale Spallation on Rene'n5+y: Moisture Effects and Acoustic Emission

    NASA Technical Reports Server (NTRS)

    Smialek, James L.; Morscher, Gregory N.

    2001-01-01

    The single crystal superalloy Rene'N5 (with or without Y-doping and hydrogen annealing) was cyclically oxidized at 1150 C for 1000 hours. After considerable scale growth (>= 500 hours), even the adherent alumina scales formed on Y-doped samples exhibited delayed interfacial spallation during subsequent water immersion tests, performed up to one year after oxidation. Spallation was characterized by weight loss, the amount of spalled area, and acoustic emission response. Hydrogen annealing (prior to oxidation) reduced spallation both before and after immersion, but without measurably reducing the bulk sulfur content of the Y-doped alloys. The duration and frequency of sequential, co-located acoustic emission events implied an interfacial crack growth rate at least 10(exp -3) m/s, but possibly higher than 10(exp 2) m/s. This is much greater than classic moisture-assisted slow crack growth rates in bulk alumina (10(exp -6) to 10(exp -3) m/s), which may still have occurred undetected by acoustic emission. An alternative failure sequence is proposed: an incubation process for preferential moisture ingress leads to a local decrease in interfacial toughness, thus allowing fast fracture driven by stored strain energy.

  7. Moisture-induced delayed spallation and interfacial hydrogen embrittlement of alumina scales

    NASA Astrophysics Data System (ADS)

    Smialek, James L.

    2006-01-01

    While interfacial sulfuris the primary chemical factor affecting Al2O3 scale adhesion, moisture-induced delayed spallation appears as a secondary, but impressive, mechanistic detail. Similarities with bulk metallic phenomena suggest that hydrogen embrittlement from ambient humidity, resulting from the reaction Alalloy+3(H2O)air=Al(OH)- 3+3H+ may be the operative mechanism. This proposal was tested on pre-oxidized René N5 by standard cathodic hydrogen charging in 1N H2SO4, as monitored by weight change, induced current, and microstructure. Cathodic polarization at -2.0 V abruptly stripped mature Al2O3 scales at the oxide-metal interface. Anodic polarization at +2.0V, however, produced alloy dissolution. Finally, with no applied voltage, the acid electrolyte produced neither scale spallation nor alloy dissolution. Thus, hydrogen charging was detrimental to alumina scale adhesion. Moisture-induced interfacial hydrogen embrittlement is concluded to be the cause of delayed scale spallation and desktop thermal barrier coating failures.

  8. Moisture-Induced Delayed Spallation and Interfacial Hydrogen Embrittlement of Alumina Scales

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2008-01-01

    While interfacial sulfur is the primary chemical factor affecting Al2O3 scale adhesion, moisture-induced delayed spallation appears as a secondary, but impressive, mechanistic detail. Similarities with bulk metallic phenomena suggest that hydrogen embrittlement from ambient humidity, resulting from the reaction Al(sub alloy)+3(H2O)(sub air) = Al(OH)(-) (sub 3) +3H(+) may be the operative mechanism. This proposal was tested on pre-oxidized Rene N5 by standard cathodic hydrogen charging in 1N H2SO4, as monitored by weight change, induced current, and microstructure. Cathodic polarization at -2.0 V abruptly stripped mature Al2O3 scales at the oxide-metal interface. Anodic polarization at +2.0 V, however, produced alloy dissolution. Finally, with no applied voltage, the acid electrolyte produced neither scale spallation nor alloy dissolution. Thus, hydrogen charging was detrimental to alumina scale adhesion. Moisture-induced interfacial hydrogen embrittlement is concluded to be the cause of delayed scale spallation and desktop thermal barrier coating failures.

  9. Surface modification to prevent oxide scale spallation

    DOEpatents

    Stephens, Elizabeth V; Sun, Xin; Liu, Wenning; Stevenson, Jeffry W; Surdoval, Wayne; Khaleel, Mohammad A

    2013-07-16

    A surface modification to prevent oxide scale spallation is disclosed. The surface modification includes a ferritic stainless steel substrate having a modified surface. A cross-section of the modified surface exhibits a periodic morphology. The periodic morphology does not exceed a critical buckling length, which is equivalent to the length of a wave attribute observed in the cross section periodic morphology. The modified surface can be created using at least one of the following processes: shot peening, surface blasting and surface grinding. A coating can be applied to the modified surface.

  10. Stress determination in thermally grown alumina scales using ruby luminescence

    SciTech Connect

    Renusch, D.; Veal, B.W.; Koshelev, I.; Natesan, K.; Grimsditch; Hou, P.Y.

    1996-06-01

    By exploiting the strain dependence of the ruby luminescence line, we have measured the strain in alumina scales thermally grown on Fe-Cr- Al alloys. Results are compared and found to be reasonably consistent with strains determined using x rays. Oxidation studies were carried out on alloys Fe - 5Cr - 28Al and Fe - 18Cr - 10Al (at.%). Significantly different levels of strain buildup were observed in scales on these alloys. Results on similar alloys containing a ``reactive element`` (Zr or Hf) in dilute quantity are also presented. Scales on alloys containing a reactive element (RE) can support significantly higher strains than scales on RE-free alloys. With the luminescence technique, strain relief associated with spallation thresholds is readily observed.

  11. Sulfur Impurities and the Microstructure of Alumina Scales

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    1997-01-01

    The relationship between the microstructure of alumina scales, adhesion, and sulfur content was examined through a series of nickel alloys oxidized in 1100 to 1200 deg. C cyclic or isothermal exposures in air. In cyclic tests of undoped NiCrAl, adhesion was produced when the sulfur content was reduced, without any change in scale microstructure. Although interfacial voids were not observed in cyclic tests of NiCrAl, they were promoted by long-term isothermal exposures, by sulfur doping, and in most exposures of NiAl. Two single crystal superalloys, PWA 1480 and Rene' N5, were also tested, either in the as-received condition or after the sulfur content had been reduced to less than 1 ppmw by hydrogen annealing. The unannealed alloys always exhibited spalling to bare metal, but interfacial voids were not observed consistently. Desulfurized PWA 1480 and Rene' N5 exhibited remarkable adhesion and no voidage for either isothermal or cyclic exposures. The most consistent microstructural feature was that, for the cases where voids did form, the scale undersides exhibited corresponding areas with ridged oxide grain boundaries. Voids were not required for spallation nor were other microstructural features essential for adhesion. These observations are consistent with the model whereby scale spallation is controlled primarily by interfacial sulfur segregation and the consequent degradation of oxide-metal bonding.

  12. Strain measurements in thermally grown alumina scales using ruby fluorescence

    SciTech Connect

    Veal, B.W.; Natesan, K.; Koshelev, I.; Grimsditch, M.; Renusch, D. Hou, P.Y.

    1996-12-31

    We have measured strains in alumina scales thermally grown on Fe-Cr- Al alloys by exploiting the strain dependence of the ruby luminescence line. Measurements were done on Fe-5Cr-28Al and Fe-18Cr-10Al (at.%, bal. Fe) oxidized between 300-1300 C with periodic cycling to room temperature. Significantly different levels of strain buildup were observed in scales on these alloys. Results on similar alloys containing a dilute reactive element (Zr or Hf) are also presented. We observe that scales on alloys containing a reactive element (RE) can support higher strains than scales on RE-free alloys. With the luminescence technique, strain relief associated with spallation thresholds is readily observed. In early stage oxidation, the evolution of transition phases is monitored using Raman and fluorescence spectroscopies. The fluorescence technique also provides a sensitive probe of early stage formation of {alpha}-Al{sub 2}O{sub 3}. It appears that, in presence of Cr{sub 2}O{sub 3} or Fe{sub 2}O{sub 3}, the {alpha}-alumina phase can form at anomalously low temperatures.

  13. GRAIN-SCALE FAILURE IN THERMAL SPALLATION DRILLING

    SciTech Connect

    Walsh, S C; Lomov, I; Roberts, J J

    2012-01-19

    Geothermal power promises clean, renewable, reliable and potentially widely-available energy, but is limited by high initial capital costs. New drilling technologies are required to make geothermal power financially competitive with other energy sources. One potential solution is offered by Thermal Spallation Drilling (TSD) - a novel drilling technique in which small particles (spalls) are released from the rock surface by rapid heating. While TSD has the potential to improve drilling rates of brittle granitic rocks, the coupled thermomechanical processes involved in TSD are poorly described, making system control and optimization difficult for this drilling technology. In this paper, we discuss results from a new modeling effort investigating thermal spallation drilling. In particular, we describe an explicit model that simulates the grain-scale mechanics of thermal spallation and use this model to examine existing theories concerning spalling mechanisms. We will report how borehole conditions influence spall production, and discuss implications for macro-scale models of drilling systems.

  14. Chemical and microstructural characterization of thermally grown alumina scales

    SciTech Connect

    Natesan, K.; Richier, C.; Veal, B.W.

    1995-09-01

    An experimental program has been initiated to evaluate the chemical, microstructural, and mechanical integrity of thermally grown oxide scales to establish requirements for improved corrosion performance in terms of composition, structure, and properties. Iron aluminides of several compositions were selected for the study. Oxidation studies were conducted in air and oxygen environments at 1000{degrees}C. The results showed that the scaling kinetics followed a parabolic rate law but that the rates in early stages of oxidation were significantly greater than in later stages; the difference could be attributed to the presence of fast-growing transient iron oxides in the layer during the early stages. Further, scale failure occurred via gross spallation, scale cracking, and nodule formation and was influenced by alloy composition. Auger electron spectroscopy of Ar-exposed specimens of ternary Fe-Cr-Al alloy showed sulfur on the gas/scale side of the interface; the sulfur decreased as the exposure time increased. Raman spectroscopy and ruby fluorescence were used to examine the scale development as a function of oxidation temperature. Ruby-line shift is used to examine phase transformations in alumina and to calculate compressive strains in thermally grown scales.

  15. Multiple-Scale Geomechanical Models for Thermal Spallation Drilling.

    NASA Astrophysics Data System (ADS)

    Lomov, I.; Walsh, S. D.; Roberts, J. J.

    2011-12-01

    Widespread adoption of geothermal energy will require access to deeply buried geothermal sources in granitic basement rocks at high temperatures and pressures. Exploiting these resources necessitates novel methods for drilling, stimulation, and maintenance, under operating conditions difficult or impossible to test in laboratory settings. Physically rigorous numerical modeling tools are vital to highlight potential risks, guide process optimization and reduce the uncertainties involved in these developing technologies. In this presentation, we discuss a numerical modeling effort investigating the multiscale mechanics of thermal spallation drilling (TSD) - a technique in which rock is fragmented into small flakes by a high temperature fluid jet. This process encompasses interconnected phenomena on several length and time scales: from system-scale fluid dynamics to grain-scale thermomechanics of spallation. Here we describe how these disperate scales are simulated using GEODYN, a parallel Eulerian compressible solid and fluid dynamics code with adaptive mesh refinement (AMR) capabilities. GEODYN is able to simulate materials under extremely large deformations, resolve details of wave propagation within grains, and uses a continuum damage mechanics approach to represent fracture. We will present results from both system- and grain-scale simulations describing the transfer of heat from the high temperature jet to the rock face, and the effect of grain-scale properties such as incipient flaw distribution, grain size and grain size distribution, heat flux, applied temperature and material heterogeneity on the onset of spallation. Detailed computer modeling helps to address several of the uncertainties surrounding TSD: 1) What rock compositions are drillable with TSD? 2) How do grain size and grain size distribution affect TSD and drilling rates? 3) What combination of macroscopic (Poisson ratio, heat capacity and thermal conductivity) and microscopic (flaw distribution

  16. The mechanical reliability of alumina scales and coatings

    SciTech Connect

    Alexander, K.B.; Pruebner, K.; Tortorelli, P.F.

    1996-08-01

    The mechanical integrity of oxide scales ultimately determines their ability to protect materials from corrosion and other environmental effects arising from deleterious reactions with gases and condensable products. The microstructure and mechanical behavior of alumina products thermally grown or deposited on Fe-28 at.% Al intermetallic alloys are being characterized in order to develop the knowledge and means to control the mechanical reliability of alumina scales by microstructural manipulation through design and processing. Mechanical characterization involved gravimetric data from cyclic oxidation experiments, in-situ observation of oxidized specimens undergoing flexural loading in a scanning electron microscope, and measurements of hardness, elastic modulus and cracking resistance by nanoindentation. Values of cracking thresholds for Al{sub 2}O{sub 3} scales were consistent with other measurements for surface and bulk alumina. The oxidation behavior of Fe{sub 3}Al alloys coated with a thin (0.5 - 1 {mu}m) alumina film deposited by plasma synthesis has been studied. During exposure in the oxidizing environment, new oxide was formed between the coating and the substrate. The presence of the deposited amorphous oxide inhibited the subsequent thermal oxidation of the metal. Because the thermally grown alumina forms under the deposit, the adherence of the coating is controlled by the strength of the metal/oxide interface that develops during oxidation.

  17. Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells

    SciTech Connect

    Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-07-01

    In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

  18. Ionic Segregation on Grain Boundaries in Thermally Grown Alumina Scales

    SciTech Connect

    Pint, Bruce A; Unocic, Kinga A

    2012-01-01

    This study first examined segregation behaviour in the alumina scale formed after 100 h at 1100 C on bare and MCrAlYHfSi-coated single-crystal superalloys with {approx}10 ppma La and Y. For the bare superalloy, Hf and Ti were detected on the grain boundaries of the inner columnar alumina layer. Increasing the oxidation temperature to 1200 C for 2 h did not change the segregation behavior. With the bond coating, both Y and Hf were segregated to the grain boundaries as expected. However, there was evidence of Ti-rich oxide particles near the gas interface suggesting that Ti diffused from the superalloy through the coating. To further understand these segregation observations with multiple dopants, other alumina-forming systems were examined. Alumina scale grain boundary co-segregation of Ti with Y is common for FeCrAl alloys. Co-segregation of Hf and Ti was observed in the scale formed on co-doped NiAl. No La segregation was detected in the scale formed on NiCrAl with only a 19 ppma La addition, however, the scale was adherent.

  19. Atomic scale insights on chlorinated gamma-alumina surfaces.

    PubMed

    Digne, Mathieu; Raybaud, Pascal; Sautet, Philippe; Guillaume, Denis; Toulhoat, Hervé

    2008-08-20

    The thermochemistry of chlorinated gamma-alumina surfaces is explored by means of density functional calculations as a function of relevant reaction conditions used in experiments and in high-octane fuel production in the refining industry such as hydrocarbon isomerization and reforming. The role of chlorine as a dope of the Brønsted acidity of gamma-alumina surfaces is investigated at an atomic scale. Combining infrared spectroscopy and density functional theory calculations, the most favorable location of chlorine atoms on the (110), (100) and (111) surfaces of gamma-alumina is found to result either from direct adsorption or from the exchange of basic hydroxyl groups. Moreover, the modification of the hydrogen bond network upon chlorine adsorption is put forward as a key parameter for changing the Brønsted acidity. In a second step, we use a thermodynamic approach based on DFT total energy calculations corrected by the chemical potentials of HCl and H2O to determine the adsorption isotherms of chlorine and the relative surface concentration of hydroxyl groups and chlorine species on the gamma-alumina surfaces. The determination of chlorine content as a function of temperature and partial pressures of H2O and HCl offers new quantitative data required for optimizing the state of the support surface in industrial conditions. The mechanisms of chlorination are also discussed as a function of reaction conditions. PMID:18646849

  20. Conduction in alumina with atomic scale copper filaments

    SciTech Connect

    Xu, Xu; Liu, Jie; Anantram, M. P.

    2014-10-28

    The conductance of atomic scale filaments with three and seven Cu atoms in α-alumina are calculated using ab initio density functional theory. We find that the filament with 3 Cu atoms is sufficient to increase the conductance of 1.3 nm thick alumina film by more than 10{sup 3} times in linear response. As the applied voltage increases, the current quickly saturates and differential resistance becomes negative. Compared to the filament with three Cu atoms, while the conductance of the filament with seven Cu atoms is comparable in linear response, they carry as much as twenty times larger current at large biases. The electron transport is analyzed based on local density of states, and the negative differential resistance in the seven Cu filaments occurs due to their narrow bandwidth.

  1. A fine-scale nanostructure in γ-alumina

    NASA Astrophysics Data System (ADS)

    Paglia, Gianluca; Bozin, Emil; Billinge, Simon

    2006-03-01

    Despite the preeminent industrial importance of γ-alumina in catalysis, details of the structure remain unresolved due to its 15-30˜nm domain nanocrystalline nature. Diffraction patterns are broad and single crystals are not available making accurate structural solution difficult using conventional crystallographic methods. We have applied a local structural technique, the atomic pair distribution function (PDF) analysis of powder diffraction, to obtain a quantitative structure. This is a total scattering technique that incorporates both Bragg and diffuse scattering information in the PDF, allowing all diffracted intensities from the XRD pattern to be equally considered. Surprisingly, we find a previously unknown fine-scale nanostructure with a domain size ˜ 1 nm. Within these nanodomains the oxygen sublattice is modified from the average structure and retains aspects of the boehmite precursor. This results in a novel and unexpected view of the γ-alumina structure since earlier controversies about it centered on the arrangement of Al ions among different cation sites, whereas the oxygen sublattice arrangement was not usually questioned.

  2. Mitigation and Prediction of Spallation of Oxide Scales on Ferritic Stainless Steel

    SciTech Connect

    Chou, Y. S.; Stephens, Elizabeth V.; Xu, Zhijie; Xu, Wei; Koeppel, Brian J.; Stevenson, Jeffry W.

    2015-02-04

    This report summarizes results from experimental and modeling studies performed by researchers at Pacific Northwest National Laboratory on behalf of the Solid-State Energy Conversion Alliance (SECA) Core Technology Program. The results indicate that application of physical surface modifications, such as surface blasting, prior to application of protective surface coatings can substantially increase oxide scale spallation resistance during long-term exposure to elevated temperatures (e.g., 800-850ºC). To better understand and predict the benefits of surface modification, an integrated modeling framework was developed and applied to the obtained experimental results.

  3. Corrosion performance of alumina scales in coal gasification environments

    SciTech Connect

    Natesan, K.

    1997-02-01

    Corrosion of metallic structural materials in complex gas environments of coal gasification is a potential problem. The corrosion process is dictated by concentrations of two key constituents: sulfur as H{sub 2}S and Cl as HCl. This paper examines the corrosion performance of alumina scales that are thermally grown on Fe-base alloys during exposure to O/S mixed-gas environments. The results are compared with the performance of chromia-forming alloys in similar environments. The paper also discusses the available information on corrosion performance of alloys whose surfaces were enriched with Al by the pack-diffusion process, by the electrospark deposition process, or by weld overlay techniques.

  4. Lightweight alumina refractory aggregate. Phase 2, Pilot scale development

    SciTech Connect

    Swansiger, T.G.; Pearson, A.

    1994-11-01

    Kilogram quantities of refractory aggregate were prepared from both a paste and a pelletized form of extruder feed material in both bench and pilot-scale equipment. The 99{sup +} % alumina aggregate exhibited a bulk density approaching 2.5 g/cm{sup 3} and a fired strength slightly lower than fused alumina. Based on initial evaluation by two refractory manufacturers in brick or castable applications, the new aggregate offered adequate strength with thermal conductivity reductions up to 34%, depending on the temperature and application of the new aggregate in these initial trials. The new aggregate was simply substituted for Tabular{trademark} in the refractory formulation. Thus, there is room for improvement through formulation optimization with the lightweight aggregate. The new aggregate offers a unique combination of density, strength, and thermal properties not available in current aggregate. To this point in time, technical development has led to a pelletized formulation with borderline physical form leaving the Eirich mixer. The formulation requires further development to provide more latitude for the production of pelletized material without forming paste, while still reducing the bulk density slightly to reach the 2.5 g/cm{sup 3} target. The preferred, pelletized process flowsheet was outlined and a preliminary economic feasibility study performed based on a process retrofit into Alcoa`s Arkansas tabular production facilities. Based on an assumed market demand of 20,000 mt/year and an assumed selling price of $0.65/lb (25% more than the current selling price of Tabular{trademark}, on a volume basis), economics were favorable. Decision on whether to proceed into Phase 3 (full- scale demonstration) will be based on a formal market survey in 1994 October.

  5. Diffusivity in Alumina Scales Grown on Al-MAX Phases

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2014-01-01

    Ti3AlC2, Ti2AlC, and Cr2AlC are oxidation resistant MAX phase compounds distinguished by the formation of protective Al2O3 scales with well controlled kinetics. A modified Wagner treatment was used to obtain interfacial grain boundary diffusivity, deltaD(sub gb,O,int.), from scale growth rates and corresponding grain size. It is based on the p(O2)(exp -1/6) dependency of the double charged oxygen vacancy and oxygen diffusivity, coupled with the effective diffusion constant for short circuit grain boundary paths. Data from the literature for MAX phases was analyzed accordingly, and deltaD(sub gb,O,int.) was found to nearly coincide with the Arrhenius line developed for Zr-doped FeCrAl, where: deltaD(sub gb,O,int.) = 1.8x10(exp -10) exp(-375 kJ/RT) cubic meters/s. Furthermore, this oxidation relation suggests the more general format applicable to bulk samples under ambient conditions: deltaD(sub gb,O) = 7.567x10(exp -8) exp(-544 kJ/RT) p(O2)(exp -1/6) cubic meters/[s x Pa(exp -1/6)]. Data from many other FeCrAl(X) studies were similarly assessed to show general agreement with the relation for deltaD(sub gb,O,int.). This analysis reinforces the view that protective alumina scales grow by similar mechanisms for these Al-MAX phases and oxidation resistant FeCrAl alloys.

  6. Lightweight alumina refractory aggregate: Phase 3, Full-scale demonstration

    SciTech Connect

    Swansiger, T.G.; Pearson, A.

    1996-07-16

    Technical problems (higher than target fired density, and poor intermediate strength after burnout but before sintering) were addressed and solved; solution involved use of large loading of CP-5 alumina (controlled pore, rehydratable), increased loading of one of the binders, and a steam aging step. Resistance of the lightweight aggregate in a brick formulation to steel slag penetration was assessed in a preliminary test and found to be almost as good as that of T-64. Pelletized process economic feasibility study was updated, based on production levels of 10,000 and 20,000 mt/year, the most up- to-date raw material costs, and the assumption of a retrofit into the Arkansas plant tabular production facility. For the 10,000 mt/y production level, the required selling price of 35% more than the T- 64 selling price exceeds the {le}25% objective. The market survey will determine whether to proceed with the full scale demonstration that will produce at least 54.4 mt (120,000 lb) of the aggregate for incorporation into products, followed by end-user testing and evaluation.

  7. Microstructural and mechanical characterization of alumina scales thermally developed on iron aluminide alloys

    SciTech Connect

    Natesan, K.; Klug, K.L.; Renusch, D.; Grimsditch, M.; Veal, B.W.

    1996-05-01

    Several alumina-forming Fe-Al intermetallic alloys have been oxidized in oxygen for 100 h at 1000 C to understand the scaling kinetics, scale morphology, scale adhesion, and strain accommodation in the scales. Oxidation studies were conducted by thermogravimetry, followed by analyses of the surfaces of oxide scales. In addition, samples were cooled to 77 K and then fractured; then, their scale/metal interfaces were analyzed. Some of the scales were adhesion-tested by applying a tensile load to pull the scale away from the substrate. Finally, ruby fluorescence was used to measure in-plane strains in the oxide scales and values correlated with scale microstructures.

  8. Rapid fabrication of self-ordered porous alumina with 10-/sub-10-nm-scale nanostructures by selenic acid anodizing.

    PubMed

    Nishinaga, Osamu; Kikuchi, Tatsuya; Natsui, Shungo; Suzuki, Ryosuke O

    2013-01-01

    Anodic porous alumina has been widely investigated and used as a nanostructure template in various nanoapplications. The porous structure consists of numerous hexagonal cells perpendicular to the aluminum substrate and each cell has several tens or hundreds of nanoscale pores at its center. Because the nanomorphology of anodic porous alumina is limited by the electrolyte during anodizing, the discovery of additional electrolytes would expand the applicability of porous alumina. In this study, we report a new self-ordered nanoporous alumina formed by selenic acid (H2SeO4) anodizing. By optimizing the anodizing conditions, anodic alumina possessing 10-nm-scale pores was rapidly assembled (within 1 h) during selenic acid anodizing without any special electrochemical equipment. Novel sub-10-nm-scale spacing can also be achieved by selenic acid anodizing and metal sputter deposition. Our new nanoporous alumina can be used as a nanotemplate for various nanostructures in 10-/sub-10-nm-scale manufacturing. PMID:24067318

  9. Moisture-Induced TBC Spallation on Turbine Blade Samples

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2011-01-01

    Delayed failure of TBCs is a widely observed laboratory phenomenon, although many of the early observations went unreported. "The weekend effect" or "DeskTop Spallation" (DTS) is characterized by initial survival of a TBC after accelerated laboratory thermal cycling, then failure by exposure to ambient humidity or water. Once initiated, failure can occur quite dramatically in less than a second. To this end, the water drop test and digital video recordings have become useful techniques in studies at NASA (Smialek, Zhu, Cuy), DECHMA (Rudolphi, Renusch, Schuetze), and CNRS Toulouse/SNECMA (Deneux, Cadoret, Hervier, Monceau). In the present study the results for a commercial turbine blade, with a standard EB-PVD 7YSZ TBC top coat and Pt-aluminide diffusion bond monitored by weight change and visual appearance. Failures were distributed widely over a 5-100 hr time range, depending on temperature. At some opportune times, failure was captured by video recording, documenting the appearance and speed of the moisture-induced spallation process. Failure interfaces exhibited alumina scale grains, decorated with Ta-rich oxide particles, and alumina inclusions as islands and streamers. The phenomenon is thus rooted in moisture-induced delayed spallation (MIDS) of the alumina scale formed on the bond coat. In that regard, many studies show the susceptibility of alumina scales to moisture, as long as high strain energy and a partially exposed interface exist. The latter conditions result from severe cyclic oxidation conditions, which produce a highly stressed and partially damaged scale. In one model, it has been proposed that moisture reacts with aluminum in the bond coat to release hydrogen atoms that 'embrittle' the interface. A negative synergistic effect with interfacial sulfur is also invoked.

  10. Moisture-Induced TBC Spallation on Turbine Blade Samples

    NASA Technical Reports Server (NTRS)

    Smialek, James

    2011-01-01

    Delayed failure of TBCs is a widely observed laboratory phenomenon, although many of the early observations went unreported. The weekend effect or DeskTop Spallation (DTS) is characterized by initial survival of a TBC after accelerated laboratory thermal cycling, then failure by exposure to ambient humidity or water. Once initiated, failure can occur quite dramatically in less than a second. To this end, the water drop test and digital video recordings have become useful techniques in studies at NASA (Smialek, Zhu, Cuy), DECHMA (Rudolphi, Renusch, Schuetze), and CNRS Toulouse/SNECMA (Deneux, Cadoret, Hervier, Monceau). In the present study the results for a commercial turbine blade, with a standard EB-PVD 7YSZ TBC top coat and Pt-aluminide diffusion bond coat are reported. Cut sections were intermittently oxidized at 1100, 1150, and 1200 C and monitored by weight change and visual appearance. Failures were distributed widely over a 5-100 hr time range, depending on temperature. At some opportune times, failure was captured by video recording, documenting the appearance and speed of the moisture-induced spallation process. Failure interfaces exhibited alumina scale grains, decorated with Ta-rich oxide particles, and alumina inclusions as islands and streamers. The phenomenon is thus rooted in moisture-induced delayed spallation (MIDS) of the alumina scale formed on the bond coat. In that regard, many studies show the susceptibility of alumina scales to moisture, as long as high strain energy and a partially exposed interface exist. The latter conditions result from severe cyclic oxidation conditions, which produce a highly stressed and partially damaged scale. In one model, it has been proposed that moisture reacts with aluminum in the bond coat to release hydrogen atoms that embrittle the interface. A negative synergistic effect with interfacial sulfur is also invoked.

  11. FEG-SEM investigation of α-alumina scales formed on FeCrAlY alloys oxidised at 1200° C

    NASA Astrophysics Data System (ADS)

    Al-Badairy, H.; Tatlock, G.; Fawcett, S.; Beahan, P.; Hunt, J.

    2005-05-01

    This work is part of an ongoing European funded project, “SMILER”, with the aim of improving the performance of alumina forming Fe-20Cr-5Al-Y alloys for high temperature industrial applications. One aspect of the project is to investigate the influence of additives on the oxidation behaviour of these alloys. During this study a LEO 1550 FESEM (field emission scanning electron microscope), equipped with INCA X-ray microanalysis facilities was used. Ultra-high-purity model alloys, where the levels of additives (Hf, Zr, Ti, Si, La and Y) were carefully controlled, and two commercial Aluchrom YHfAl and Kanthal AMPT alloys were oxidised at 1200° C for up to 3100h (100h/cycle). The YHfAl, (Y+Ti+Zr)- and (Y+Zr+Hf)-containing alloys showed the highest oxidation rates when oxidised, whereas the La-containing alloy showed the lowest oxidation rate. However, the La-containing alloy spalled the most, while the (Y+Zr+Hf)-containing and YHfAl alloys showed little spallation, and the additives appeared to have a major influence on the spallation of the α -alumina scale formed. On the alloys with La and Si respectively, the scale spalled at the scale/metal interface (adhesively), whereas on alloys containing (Y+Hf+Ti) and (Y+Hf+Zr) and the YHfAl alloy, the scale spalled mainly in a cohesive manner (within the scale). Also, the added elements affected the scale topography. In general the scale had a columnar structure at the scale/metal interface, whereas the grains were equiaxed at the scale/gas interface. However, in the case of YHfAl and (Y+Zr+Hf)-containing alloys, a sunflower type structure was observed in both fractured samples, in the regions where the scale spalled cohesively. Preliminary EDX analyses revealed that, in the case of YHfAl, for example, the center of the sunflower structure was rich in Mg. This suggests that there may be inhomogeneities in the metal substrate, prior to oxidation, where high concentrations of Mg increase the local oxide growth rate.

  12. Finite element modeling of the effect of interface anomalies on thermal stresses in alumina scales

    SciTech Connect

    Wright, J.K.; Williamson, R.L.; Hou, P.Y.; Cannon, R.M.; Renusch, D.; Veal, B.; Grimsditch, M.

    1998-07-01

    The scales that grow from oxidation often develop a convoluted morphology or interface pores. High thermal stresses can develop locally and are potentially detrimental to the scale or interface integrity. Finite element simulations are used to examine residual thermal stresses and strains that result when these deviations from a flat interface have formed, and the resulting geometry is subsequently cooled to room temperature. A variety of geometries will be considered for alumina scales on a FeCrAl substrate.

  13. Finite element modeling of the effect of interface anomalies on thermal stresses in alumina scales.

    SciTech Connect

    Wright, J. K.

    1998-06-10

    The scales that grow from oxidation often develop a convoluted morphology or interface pores. High thermal stresses can develop locally and are potentially detrimental to the scale or interface integrity. Finite element simulations are used to examine residual thermal stresses and strains that result when these deviations from a flat interface have formed, and the resulting geometry is subsequently cooled to room temperature. A variety of geometries will be considered for alumina scales on a FeCrAl substrate.

  14. Microscopic mechanisms of laser spallation and ablation of metal targets from large-scale molecular dynamics simulations

    NASA Astrophysics Data System (ADS)

    Wu, Chengping; Zhigilei, Leonid V.

    2014-01-01

    The microscopic mechanisms of femtosecond laser ablation of an Al target are investigated in large-scale massively parallel atomistic simulations performed with a computational model combining classical molecular dynamics technique with a continuum description of the laser excitation and subsequent relaxation of conduction band electrons. The relatively large lateral size of the computational systems used in the simulations enables a detailed analysis of the evolution of multiple voids generated in a sub-surface region of the irradiated target in the spallation regime, when the material ejection is driven by the relaxation of laser-induced stresses. The nucleation, growth, and coalescence of voids take place within a broad (100 nm) region of the target, leading to the formation of a transient foamy structure of interconnected liquid regions and eventual separation (or spallation) of a thin liquid layer from the bulk of the target. The thickness of the spalled layer is decreasing from the maximum of 50 nm while the temperature and ejection velocity are increasing with increasing fluence. At a fluence of 2.5 times the spallation threshold, the top part of the target reaches the conditions for an explosive decomposition into vapor and small clusters/droplets, marking the transition to the phase explosion regime of laser ablation. This transition is signified by a change in the composition of the ablation plume from large liquid droplets to a mixture of vapor-phase atoms and clusters/droplets of different sizes. The clusters of different sizes are spatially segregated in the expanding ablation plume, where small/medium size clusters present in the middle of the plume are followed by slower (velocities of less than 3 km/s) large droplets consisting of more than 10,000 atoms. The similarity of some of the characteristics of laser ablation of Al targets (e.g., evolution of voids in the spallation regime and cluster size distributions in the phase explosion regime) to the

  15. The mechanical reliability of alumina scales and coatings

    SciTech Connect

    Alexander, K.B.; Pruebner, K.; Tortorelli, P.F.

    1996-06-01

    In many high-temperature fossil energy systems, corrosion and deleterious reactions with gases and condensable products in the operating environment often compromise materials performance. The presence of a stable surface oxide (either as thermally-grown scales or deposited coatings) can effectively protect the materials from these reactions if the oxides are slow-growing, dense and adherent to the substrate. The protection these brittle oxide films provide has long been a critical issue, particularly for applications involving severe high-temperature thermal cycles or very aggressive (for example, sulfidizing) environments. The various factors which control the scale/coating integrity and adherence are not well understood. The present multilaboratory collaborative work is intended to define the relationships between substrate characteristics (composition, microstructure, and mechanical behavior) and the structure and protective properties of deposited oxide coatings and/or thermally grown scales. Through such studies, the ultimate goal is to assure environmental protection through effective processing and materials selection leading to the development of corrosion-resistant, high-temperature materials for improved energy and environmental control systems.

  16. Development and Exploratory Scale-Up of Alumina-Forming Austenitic (AFA) Stainless Steels

    SciTech Connect

    Brady, Michael P; Magee, John H; Yamamoto, Yukinori; Maziasz, Philip J; Santella, Michael L; Pint, Bruce A; Bei, Hongbin

    2009-01-01

    This paper presents the results of the continued development of creep-resistant, alumina-forming austenitic (AFA) stainless steel alloys, which exhibit a unique combination of excellent oxidation resistance via protective alumina (Al2O3) scale formation and high-temperature creep strength through the formation of stable nano-scale MC carbides and intermetallic precipitates. Efforts in fiscal year 2009 focused on the characterization and understanding of long-term oxidation resistance and tensile properties as a function of alloy composition and microstructure. Computational thermodynamic calculations of the austenitic matrix phase composition and the volume fraction of MC, B2-NiAl, and Fe2(Mo,Nb) base Laves phase precipitates were used to interpret oxidation behavior. Of particular interest was the enrichment of Cr in the austenitic matrix phase by additions of Nb, which aided the establishment and maintenance of alumina. Higher levels of Nb additions also increased the volume fraction of B2-NiAl precipitates, which served as an Al reservoir during long-term oxidation. Ageing studies of AFA alloys were conducted at 750C for times up to 2000 h. Ageing resulted in near doubling of yield strength at room temperature after only 50 h at 750C, with little further increase in yield strength out to 2000 h of ageing. Elongation was reduced on ageing; however, levels of 15-25% were retained at room temperature after 2000 h of total ageing.

  17. Dispersion Caused by Carbon Dioxide During Secondary Alumina Dissolution: A Lab-Scale Research

    NASA Astrophysics Data System (ADS)

    Yang, Youjian; Gao, Bingliang; Wang, Zhaowen; Shi, Zhongning; Hu, Xianwei; Yu, Jiangyu

    2014-06-01

    Secondary alumina is the byproduct of dry scrubbing in aluminum smelting. Secondary alumina has superior dissolution characteristics to primary alumina. Secondary alumina dissolves in pieces in molten cryolite, which results in larger contact area and better diffusion kinetics. In this work, the dissolution phenomenon of primary alumina, secondary alumina, and primary alumina doped with sodium carbonate or calcium carbonate (mass ratio = 10:1, 20:1) was observed and compared to estimate carbon-induced dispersion in industrial secondary alumina. Temperature fluctuations during sample dissolution were measured to evaluate the benefits of preheating on alumina dissolution. It was found that carbon mixed in secondary alumina significantly influences the dispersion of alumina particles at the moment of feeding, and thermodynamic analysis also shows that the combustion heat from carbon facilitates dispersion.

  18. Ultra-high density single nanometer-scale anodic alumina nanofibers fabricated by pyrophosphoric acid anodizing.

    PubMed

    Kikuchi, Tatsuya; Nishinaga, Osamu; Nakajima, Daiki; Kawashima, Jun; Natsui, Shungo; Sakaguchi, Norihito; Suzuki, Ryosuke O

    2014-01-01

    Anodic oxide fabricated by anodizing has been widely used for nanostructural engineering, but the nanomorphology is limited to only two oxides: anodic barrier and porous oxides. Therefore, the discovery of an additional anodic oxide with a unique nanofeature would expand the applicability of anodizing. Here we demonstrate the fabrication of a third-generation anodic oxide, specifically, anodic alumina nanofibers, by anodizing in a new electrolyte, pyrophosphoric acid. Ultra-high density single nanometer-scale anodic alumina nanofibers (10(10) nanofibers/cm(2)) consisting of an amorphous, pure aluminum oxide were successfully fabricated via pyrophosphoric acid anodizing. The nanomorphologies of the anodic nanofibers can be controlled by the electrochemical conditions. Anodic tungsten oxide nanofibers can also be fabricated by pyrophosphoric acid anodizing. The aluminum surface covered by the anodic alumina nanofibers exhibited ultra-fast superhydrophilic behavior, with a contact angle of less than 1°, within 1 second. Such ultra-narrow nanofibers can be used for various nanoapplications including catalysts, wettability control, and electronic devices. PMID:25491282

  19. Ultra-High Density Single Nanometer-Scale Anodic Alumina Nanofibers Fabricated by Pyrophosphoric Acid Anodizing

    NASA Astrophysics Data System (ADS)

    Kikuchi, Tatsuya; Nishinaga, Osamu; Nakajima, Daiki; Kawashima, Jun; Natsui, Shungo; Sakaguchi, Norihito; Suzuki, Ryosuke O.

    2014-12-01

    Anodic oxide fabricated by anodizing has been widely used for nanostructural engineering, but the nanomorphology is limited to only two oxides: anodic barrier and porous oxides. Therefore, the discovery of an additional anodic oxide with a unique nanofeature would expand the applicability of anodizing. Here we demonstrate the fabrication of a third-generation anodic oxide, specifically, anodic alumina nanofibers, by anodizing in a new electrolyte, pyrophosphoric acid. Ultra-high density single nanometer-scale anodic alumina nanofibers (1010 nanofibers/cm2) consisting of an amorphous, pure aluminum oxide were successfully fabricated via pyrophosphoric acid anodizing. The nanomorphologies of the anodic nanofibers can be controlled by the electrochemical conditions. Anodic tungsten oxide nanofibers can also be fabricated by pyrophosphoric acid anodizing. The aluminum surface covered by the anodic alumina nanofibers exhibited ultra-fast superhydrophilic behavior, with a contact angle of less than 1°, within 1 second. Such ultra-narrow nanofibers can be used for various nanoapplications including catalysts, wettability control, and electronic devices.

  20. Ultra-High Density Single Nanometer-Scale Anodic Alumina Nanofibers Fabricated by Pyrophosphoric Acid Anodizing

    PubMed Central

    Kikuchi, Tatsuya; Nishinaga, Osamu; Nakajima, Daiki; Kawashima, Jun; Natsui, Shungo; Sakaguchi, Norihito; Suzuki, Ryosuke O.

    2014-01-01

    Anodic oxide fabricated by anodizing has been widely used for nanostructural engineering, but the nanomorphology is limited to only two oxides: anodic barrier and porous oxides. Therefore, the discovery of an additional anodic oxide with a unique nanofeature would expand the applicability of anodizing. Here we demonstrate the fabrication of a third-generation anodic oxide, specifically, anodic alumina nanofibers, by anodizing in a new electrolyte, pyrophosphoric acid. Ultra-high density single nanometer-scale anodic alumina nanofibers (1010 nanofibers/cm2) consisting of an amorphous, pure aluminum oxide were successfully fabricated via pyrophosphoric acid anodizing. The nanomorphologies of the anodic nanofibers can be controlled by the electrochemical conditions. Anodic tungsten oxide nanofibers can also be fabricated by pyrophosphoric acid anodizing. The aluminum surface covered by the anodic alumina nanofibers exhibited ultra-fast superhydrophilic behavior, with a contact angle of less than 1°, within 1 second. Such ultra-narrow nanofibers can be used for various nanoapplications including catalysts, wettability control, and electronic devices. PMID:25491282

  1. Rapid fabrication of self-ordered porous alumina with 10-/sub-10-nm-scale nanostructures by selenic acid anodizing

    PubMed Central

    Nishinaga, Osamu; Kikuchi, Tatsuya; Natsui, Shungo; Suzuki, Ryosuke O.

    2013-01-01

    Anodic porous alumina has been widely investigated and used as a nanostructure template in various nanoapplications. The porous structure consists of numerous hexagonal cells perpendicular to the aluminum substrate and each cell has several tens or hundreds of nanoscale pores at its center. Because the nanomorphology of anodic porous alumina is limited by the electrolyte during anodizing, the discovery of additional electrolytes would expand the applicability of porous alumina. In this study, we report a new self-ordered nanoporous alumina formed by selenic acid (H2SeO4) anodizing. By optimizing the anodizing conditions, anodic alumina possessing 10-nm-scale pores was rapidly assembled (within 1 h) during selenic acid anodizing without any special electrochemical equipment. Novel sub-10-nm-scale spacing can also be achieved by selenic acid anodizing and metal sputter deposition. Our new nanoporous alumina can be used as a nanotemplate for various nanostructures in 10-/sub-10-nm-scale manufacturing. PMID:24067318

  2. Oxygen Permeability and Grain-Boundary Diffusion Applied to Alumina Scales

    NASA Technical Reports Server (NTRS)

    Smialek, James L.; Jacobson, Nathan S.; Gleeson, Brian; Hovis, David B.; Heuer, Arthur H.

    2013-01-01

    High-temperature oxygen permeability measurements had determined grain-boundary diffusivities (deltaD(sub gb)) in bulk polycrystalline alumina (Wada, Matsudaira, and Kitaoka). They predict that oxygen deltaD(sub gb,O) varies with oxygen pressure as P(O2)(sup -1/6) at low pressure whereas aluminum deltaD(sub gb),Al varies with P(O2)(sup +3/16) at high pressure. These relations were used to evaluate alumina scale growth in terms of diffusivity and grain size. A modified Wagner treatment for dominant inward oxygen growth produces the concise solution: ?(sub i) = k(sub p,i)×G(sub i) = 12 deltaD(sub gb,O,int), where ?(sub i) is a constant and k(sub p,i) and G(sub i) refer to instantaneous values of the scale parabolic growth constant and grain size, respectively. A commercial FeCrAl(Zr) alloy was oxidized at 1100 to 1400 degC to determine k(sub p,i), interfacial grain size, ?, and thus deltaD(sub gb,O,int). The deltaD(sub gb,O,int) values predicted from oxidation at (375 kJ/mole) were about 20 times less than those obtained above (at 298 kJ/mole), but closer than extrapolations from high-temperature bulk measurements. The experimental oxidation results agree with similar FeCrAl(X) studies, especially where both k(sub p,i) and G(sub i) were characterized. This complete approach accounts for temperature-sensitive oxidation effects of grain enlargement, equilibrium interface pressure variation, and grain-boundary diffusivity.

  3. Growth strains and stress relaxation in alumina scales during high temperature oxidation

    SciTech Connect

    Hou, P.Y.; Paulikas, A.P.; Veal, B.W.

    2004-03-23

    A novel X-ray technique was used, exploiting synchrotron radiation at the Advanced Photon Source at Argonne National Laboratory, to investigate the growth stresses in {alpha}-Al{sub 2}O{sub 3}. In-situ measurements of Debye-Scherrer diffraction patterns from the scale were recorded during oxidation and cooling, and the elliptical distortion of the diffraction rings was analyzed to yield the in-plane strain. Fe-28Al, Fe-40Al, Fe-40Al-0.2Hf, Fe-20Cr-10Al and Ni-50Al (at. %) were studied. Data were acquired in air at temperatures between 950-1100 C and during cool down. In all cases, the steady stage growth strain was relatively low (<0.1%) and was either tensile or compressive depending on the alloy. A higher tensile strain often existed during the initial oxidation period when transition alumina was present. Thermal stresses imposed on NiAl by reducing the sample temperature to 950 C for a period of time showed noticeable stress relaxation by creep. Different degrees of relaxation were also found during cooling depending on alloy composition and scale microstructure. On all Fe-based alloys, the first formed {alpha}-Al{sub 2}O{sub 3} was highly textured with the degree of texture decreasing with further oxidation. The relationships between stress development, scale wrinkling, oxide phase changes, and the effect of reactive element addition on growth stresses are discussed. Results are compared with other reports of growth stresses in Al{sub 2}O{sub 3} scales.

  4. Highly efficient and large-scale fabrication of superhydrophobic alumina surface with strong stability based on self-congregated alumina nanowires.

    PubMed

    Peng, Shan; Tian, Dong; Yang, Xiaojun; Deng, Wenli

    2014-04-01

    In this study, a large-area superhydrophobic alumina surface with a series of superior properties was fabricated via an economical, simple, and highly effective one-step anodization process, and subsequently modified with low-surface-energy film. The effects of the anodization parameters including electrochemical anodization time, current density, and electrolyte temperature on surface morphology and surface wettability were investigated in detail. The hierarchical alumina pyramids-on-pores (HAPOP) rough structure which was produced quickly through the one-step anodization process together with a low-surface-energy film deposition [1H,1H,2H,2H-perfluorodecyltriethoxysilane (PDES) and stearic acid (STA)] confer excellent superhydrophobicity and an extremely low sliding angle. Both the PDES-modified superhydrophobic (PDES-MS) and the STA-modified superhydrophobic (STA-MS) surfaces present fascinating nonwetting and extremely slippery behaviors. The chemical stability and mechanical durability of the PDES-MS and STA-MS surfaces were evaluated and discussed. Compared with the STA-MS surface, the as-prepared PDES-MS surface possesses an amazing chemical stability which not only can repel cool liquids (water, HCl/NaOH solutions, around 25 °C), but also can show excellent resistance to a series of hot liquids (water, HCl/NaOH solutions, 30-100 °C) and hot beverages (coffee, milk, tea, 80 °C). Moreover, the PDES-MS surface also presents excellent stability toward immersion in various organic solvents, high temperature, and long time period. In particular, the PDES-MS surface achieves good mechanical durability which can withstand ultrasonication treatment, finger-touch, multiple fold, peeling by adhesive tape, and even abrasion test treatments without losing superhydrophobicity. The corrosion resistance and durability of the diverse-modified superhydrophobic surfaces were also examined. These fascinating performances makes the present method suitable for large-scale

  5. European Spallation Source

    NASA Astrophysics Data System (ADS)

    Eshraqi, Mohammad; McGinnis, David; Lindroos, Mats

    The following sections are included: * Neutron usage and historical background * Spallation * History of spallation sources * The ESS facility * The ESS linac * Beam physics * The front-end and the normal conducting linac * Superconducting linac * RF sources * Summary * References

  6. TEM and SNMS studies of protective alumina scales on NiCrAlY-alloys.

    PubMed

    Clemens, D; Vosberg, V; Hobbs, W; Breuer, U; Quadakkers, W J; Nickel, H

    1996-06-01

    The effect of Si addition on the oxidation behaviour of NiCrAlY alloys in the temperature range 950 bis 1100 degrees C has been investigated. During isothermal oxidation oxide growth rates were practically independent of the Si-content. However during cyclic oxidation Si additions were beneficial. Si additions of 1-2(m)/(0) appeared to shift the onset for spallation to longer times. It was found that Si stabilizes the beta-phase and probably it suppresses the formation of metastable Al(2)O(3) modifications. PMID:15045347

  7. Spallator - accelerator breeder

    SciTech Connect

    Steinberg, M.

    1985-01-01

    The concept involves the use of spallation neutrons produced by interaction of a high energy proton (1 to 2 GeV) from a linear accelerator (LINAC) with a heavy metal target (uranium). The principal spallator concept is based on generating fissile fuel for use in LWR nuclear power plants. The spallator functions in conjunction with a reprocessing plant to regenerate and produce the Pu-239 or U-233 for fabrication into fresh LWR reactor fuel elements. Advances in proton accelerator technology has provided a solid base for predicting performance and optimizing the design of a reliable, continuous wave, high-current LINAC required by a fissile fuel production machine.

  8. Formation of α-alumina scales in the Fe-Al(Cr) diffusion coating on China low activation martensitic steel

    NASA Astrophysics Data System (ADS)

    Zhan, Qin; Zhao, Weiwei; Yang, Hongguang; Hatano, Yuji; Yuan, Xiaoming; Nozaki, Teo; Zhu, Xinxin

    2015-09-01

    To study the formation mechanism of stable α-Al2O3 scales, the oxidation behavior of Fe-Al(Cr) diffusion coating on China low activation martensitic steel has been investigated under the oxygen partial pressure ranging from 1 to 20,000 Pa at 1253 K. A single, continuous Al2O3 scale with the maximum thickness of about 2000 nm was formed on the Fe-Al(Cr) diffusion layer. The phase transformation of alumina scales on the surface of Fe-Al(Cr) layer was studied at different oxidation times ranging from 3 to 180 min. With the increase in oxygen partial pressure, the phase transformation time of α-Al2O3 is decreased. The metastable γ-Al2O3 and transition α-(Al0.948Cr0.052)2O3 phases were formed in the earlier oxidation process and finally transformed to the stable α-Al2O3 phase, which were detected by grazing incidence angle X-ray diffraction and confirmed by transmission electron microscopy. This implies that Cr shows the third element effect and serves as a template for the nucleation of the stable α-Al2O3.

  9. Towards large scale preparation of graphene in molten salts and its use in the fabrication of highly toughened alumina ceramics.

    PubMed

    Kamali, Ali Reza; Feighan, John; Fray, Derek J

    2016-08-15

    Highly crystalline graphene nanosheets were reproducibly generated by the electrochemical exfoliation of graphite electrodes in molten LiCl containing protons. The graphene product has been successfully applied in several applications. This paper discusses the effect of molten salt produced graphene on the microstructures and mechanical properties of alumina articles produced by slip casting and pressureless sintering, which is one of the most convenient methods for the commercial production of alumina ceramics. In addition to graphene, graphite powder and multi-walled carbon nanotubes (CNTs) were also used to prepare alumina articles for comparative purposes. A graphene strengthening effect was realized through microstructural refinement and by influencing the formation of alumina nanorods during the sintering of α-Al2O3 articles. The fracture toughness of the sintered alumina articles increased to an impressive value of 6.98 MPa m(1/2) by adding 0.5 wt% graphene nanosheets. This was attributed to the unique microstructure obtained, comprised of micrometer sized alumina grains separated by alumina nanorods. PMID:27231211

  10. Spallation modeling in tantalum

    SciTech Connect

    Tonks, D.L.; Hixson, R.; Zurek, A.K.; Thissell, W.

    1997-09-01

    A gas gun plate impact spallation experiment has been performed on commercial purity rolled tantalum. The shock pressure achieved was about 7 Gpa and was sufficient to induce incipient spallation. The particle velocity was measured at the free surface of the spalled plate, and the spalled sample was recovered and examined metallographically using image analysis. The quantitative image analysis results are being used to develop a damage model. The model is micromechanically based and involves novel void growth and coalescence processes. The 1D characteristics code CHARADE has been used in a preliminary simulation of the VISAR free surface particle velocity record. Implications for ductile damage modeling will be discussed.

  11. Feasibility and process scale-up low cost alumina fibers for advanced Re-usable Surface Insulation (RSI)

    NASA Technical Reports Server (NTRS)

    Pearson, A.

    1975-01-01

    The objective of this program was to establish feasibility of a process to produce low cost aluminum oxide fibers having sufficient strength, flexibility, and thermal stability for multiple re-use at temperatures to 1480 C in advanced RSI type heat shields for reentry vehicles. Using bench-scale processing apparatus, the Alcoa 'Saphiber' process was successfully modified to produce nominally 8 microns diameter polycrystalline alpha-alumina fiber. Thermal stability was demonstrated in vacuum reheating tests to 1371 C and in atmospheric reheating to 1483 C. Individual fiber properties of strength, modulus, and flexibility were not determined because of friability and short length of the fiber. Rigidized tile produced from fiber of nominally 8, 20 and 40 micron diameter had thermal conductivities significantly higher than those of RSI SiO2 or mullite at relatively low temperature but became comparable above about 1000 C. Tile densities were high due to short fiber length, especially in the coarser diameter fiber. No significant effect of fiber diameter on thermal properties could be determined form the data. Mechanical properties of tiles deteriorated as fiber diameter increased.

  12. Enigmatic Moisture Effects on Al2O3 Scale and TBC Adhesion

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2008-01-01

    Alumina scale adhesion to high temperature alloys is known to be affected primarily by sulfur segregation and reactive element additions. However adherent scales can become partially compromised by excessive strain energy and cyclic cracking. With time, exposure of such scales to moisture can lead to spontaneous interfacial decohesion, occurring while the samples are maintained at ambient conditions. Examples of this Moisture-Induced Delayed Spallation (MIDS) are presented for NiCrAl and single crystal superalloys, becoming more severe with sulfur level and cyclic exposure conditions. Similarly, delayed failure or Desk Top Spallation (DTS) results are reviewed for TBC s, culminating in the water drop failure test. Both phenomena are discussed in terms of moisture effects on bulk alumina and bulk aluminides. A mechanism is proposed based on hydrogen embrittlement and is supported by a cathodic hydrogen charging experiment. Hydroxylation of aluminum from the alloy interface appears to be the relevant basic reaction.

  13. Enigmatic Moisture Effects on Al2O3 Scale and TBC Adhesion

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2008-01-01

    Alumina scale adhesion to high temperature alloys is known to be affected primarily by sulfur segregation and reactive element additions. However, adherent scales can become partially compromised by excessive strain energy and cyclic cracking. With time, exposure of such scales to moisture can lead to spontaneous interfacial decohesion, occurring while the samples are maintained at ambient conditions. Examples of this Moisture-Induced Delayed Spallation (MIDS) are presented for NiCrAl and single crystal superalloys, becoming more severe with sulfur level and cyclic exposure conditions. Similarly, delayed failure or Desk Top Spallation (DTS) results are reviewed for thermal barrier coatings (TBCs), culminating in the water drop failure test. Both phenomena are discussed in terms of moisture effects on bulk alumina and bulk aluminides. A mechanism is proposed based on hydrogen embrittlement and is supported by a cathodic hydrogen charging experiment. Hydroxylation of aluminum from the alloy interface appears to be the relevant basic reaction.

  14. Tip-like anodic alumina

    NASA Astrophysics Data System (ADS)

    Sun, Q. W.; Ding, G. Q.; Li, Y. B.; Zheng, M. J.; Shen, W. Z.

    2007-05-01

    Porous anodic alumina membranes and various nanotips have been demonstrating individually their unique usefulness in current nanotechnology. We present a one-step electrochemical approach to fabricate nanoscale alumina tips (tip-like anodic alumina, TAA) in order to combine the benefits of porous anodic alumina and a nanoscale tip array. The realized TAA has an ordered tip surface with controllable aspect ratio and high sheet density of ~1011 cm-2. The formation of alumina nanotips is due to the heat-driven dissolution of the nanopore surface. We have further shown that the surface nanostructure in TAA leads to the wettability reversal, and preferred nucleation and growth during material deposition. The easy and large-scale fabrication of TAA makes it possible for novel nanodevice applications.

  15. Pulsed spallation Neutron Sources

    SciTech Connect

    Carpenter, J.M.

    1994-12-31

    This paper reviews the early history of pulsed spallation neutron source development at Argonne and provides an overview of existing sources world wide. A number of proposals for machines more powerful than currently exist are under development, which are briefly described. The author reviews the status of the Intense Pulsed Neutron Source, its instrumentation, and its user program, and provides a few examples of applications in fundamental condensed matter physics, materials science and technology.

  16. Pulsed spallation neutron sources

    SciTech Connect

    Carpenter, J.M.

    1996-05-01

    This paper reviews the early history of pulsed spallation neutron source development ar Argonne and provides an overview of existing sources world wide. A number of proposals for machines more powerful than currently exist are under development, which are briefly described. The author reviews the status of the Intense Pulsed Neutron Source, its instrumentation, and its user program, and provide a few examples of applications in fundamental condensed matter physics, materials science and technology.

  17. The European Spallation Source

    SciTech Connect

    Peggs, S; Eshraqi, M; Hahn, H; Jansson, A; Lindroos, M; Ponton, A; Rathsman, K; Trahern, G; Bousso, S; Calaga, R; Devanz, G; Duperrier, R D; Eguia, J; Gammino, S; Moller, S P; Oyon, C; Ruber, R.J.M.Y.; Satogata, T

    2011-03-01

    The European Spallation Source (ESS) is a 5 MW, 2.5 GeV long pulse proton linac, to be built and commissioned in Lund, Sweden. The Accelerator Design Update (ADU) project phase is under way, to be completed at the end of 2012 by the delivery of a Technical Design Report. Improvements to the 2003 ESS design will be summarised, and the latest design activities will be presented.

  18. The European Spallation Source

    NASA Astrophysics Data System (ADS)

    Lindroos, M.; Bousson, S.; Calaga, R.; Danared, H.; Devanz, G.; Duperrier, R.; Eguia, J.; Eshraqi, M.; Gammino, S.; Hahn, H.; Jansson, A.; Oyon, C.; Pape-Møller, S.; Peggs, S.; Ponton, A.; Rathsman, K.; Ruber, R.; Satogata, T.; Trahern, G.

    2011-12-01

    In 2003 the joint European effort to design a European Spallation Source (ESS) resulted in a set of reports, and in May 2009 Lund was agreed to be the ESS site. The ESS Scandinavia office has since then worked on setting all the necessary legal and organizational matters in place so that the Design Update and construction can be started in January 2011, in collaboration with European partners. The Design Update phase is expected to end in 2012, to be followed by a construction phase, with first neutrons expected in 2018-2019.

  19. Microstructure and Residual Stress of Alumina Scale Formed on Ti2AlC at High Temperature in Air

    SciTech Connect

    Byeon, J; Liu, j; Hopkins, m; Fischer, W; Park, K; Brady, Michael P; Radovic, Miladin; Sohn, Yong Ho

    2007-01-01

    Ti2AlC ternary carbide is being explored for various high temperature applications owing to its high strength at high temperatures, excellent thermal-shock resistance, and high electrical conductivity. In this study, isothermal oxidation at 1000 XC, 1200 XC, and 1400 XC for up to 25 hours, as well as 1,000 1-hour cyclic oxidation at 1200 XC were performed in air to examine the oxidation behavior of Ti2AlC. Characteristics of the oxide scale developed in air, including mass change, residual stress in the -Al2O3 scale, phase constituents and microstructure, were examined as functions of time and temperature by thermogravimetry, photostimulated luminescence, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy via focused ion beam in-situ lift-out. A continuous and adherent -Al2O3 scale underneath a discontinuous-transient rutile-TiO2 scale was identified in the oxide scale developed at 1000 XC and 1200 XC. At 1400 XC, Al2TiO5 was identified as the discontinuous-transient scale above the continuous and adherent -Al2O3 scale. The -Al2O3 scale thickened to more than 15 m after 25 hours of isothermal oxidation at 1400 XC, and after 1,000 1-hour cyclic oxidation at 1200 XC, yet remained adherent and protective. The compressive residual stress determined by photoluminescence for the -Al2O3 scale remained under 0.65 GPa for the specimens oxidized up to 1400 XC for 25 hours. The small magnitude of the compressive residual stress may impart the high spallation-resistance of the protective -Al2O3 scale developed on Ti2AlC.

  20. Developing a Small-scale De-fluoridation Filter for use in Rural Northern Ghana with Activated Alumina as the Sorbent

    NASA Astrophysics Data System (ADS)

    Craig, L.; Stillings, L. L.; Decker, D.; Thomas, J.

    2013-12-01

    reaction time). The F- loading onto activated alumina did not change with grain size. However time to equilibrium increased dramatically with a decrease in grain size - after one hour of reaction time, the larger grain size adsorbed only 59% of F-, while at the finer grain size 90% was adsorbed. Future work will determine the volume of high F- water that can be treated before activated alumina needs to be regenerated or changed. These data will be incorporated into the design of a small-scale F-1 adsorption filter in the study area, and will predict the longevity of activated alumina as the sorbent.

  1. Developing a Small-Scale De-Fluoridation Filter for Use in Rural Northern Ghana with Activated Alumina As the Sorbent

    NASA Astrophysics Data System (ADS)

    Craig, L.; Stillings, L. L.

    2014-12-01

    reaction time, the larger grain size adsorbed only 59% of F-, while at the finer grain size 90% was adsorbed. Future work will determine the volume of high F- water that can be treated before activated alumina needs to be regenerated or changed. These data will aid in the design of a small-scale F- adsorption filter in the study area, and will predict the longevity of activated alumina as the sorbent.

  2. Further considerations of spallation effects

    NASA Technical Reports Server (NTRS)

    Dyer, C.

    1973-01-01

    Trapped photon and cosmic ray effects on spallation in the UK-5 (hard X ray telescope) central crystal were measured. Both low dose and high dose effects were considered. Decay results are presented in tables.

  3. The thermal spallation drilling process

    SciTech Connect

    Williams, R.E.

    1986-01-01

    Holes can be produced in very hard rock more easily and less expensively by thermal spallation than by conventional means. This drilling process has been used for producing blast holes in the taconite iron mines and for quarrying granite. It is potentially valuable for drilling holes in very hard rock for the exploitation of geothermal energy and the storage of various commodities. However, investigation and development of the thermal spallation drilling process is proceeding slowly.

  4. Oxide growth stress measurements and relaxation mechanisms for alumina scales grown on FeCrAlY: Oxide growth stress measurements and relaxation mechanisms

    SciTech Connect

    Tortorelli, P. F.; Specht, E. D.; More, K. L.; Hou, P. Y.

    2012-08-08

    Early-stage tensile stress evolution in α-Al2O3 scales during oxidation of FeCrAlY at 1000, 1050, 1100, and 1200 °C was monitored in situ by use of synchrotron radiation. Tensile stress development as a function of oxidation temperature indicated a dynamic interplay between stress generation and relaxation. An analysis of the time dependence of the data indicated that the observed relaxation of the initial tensile stress in the oxide scales at 1100 and 1200°C is dominated by creep in the α-Al2O3. A thin layer of a (Fe,Cr,Al) oxide was observed at the oxide-gas interface, consistent with a mechanism whereby the conversion of (Fe,Cr,Al)2O3 to α-Al2O3 produces an initial tensile stress in the alumina scale.

  5. Ductile-to-brittle transition in spallation of metallic glasses

    SciTech Connect

    Huang, X.; Ling, Z.; Dai, L. H.

    2014-10-14

    In this paper, the spallation behavior of a binary metallic glass Cu{sub 50}Zr{sub 50} is investigated with molecular dynamics simulations. With increasing the impact velocity, micro-voids induced by tensile pulses become smaller and more concentrated. The phenomenon suggests a ductile-to-brittle transition during the spallation process. Further investigation indicates that the transition is controlled by the interaction between void nucleation and growth, which can be regarded as a competition between tension transformation zones (TTZs) and shear transformation zones (STZs) at atomic scale. As impact velocities become higher, the stress amplitude and temperature rise in the spall region increase and micro-structures of the material become more unstable. Therefore, TTZs are prone to activation in metallic glasses, leading to a brittle behavior during the spallation process.

  6. Materials for spallation neutron sources

    SciTech Connect

    Sommer, W.F.; Daemen, L.L.

    1996-03-01

    The Workshop on Materials for Spallation Neutron Sources at the Los Alamos Neutron Science Center, February 6 to 10, 1995, gathered scientists from Department of Energy national laboratories, other federal institutions, universities, and industry to discuss areas in which work is needed, successful designs and use of materials, and opportunities for further studies. During the first day of the workshop, speakers presented overviews of current spallation neutron sources. During the next 3 days, seven panels allowed speakers to present information on a variety of topics ranging from experimental and theoretical considerations on radiation damage to materials safety issues. An attempt was made to identify specific problems that require attention within the context of spallation neutron sources. This proceedings is a collection of summaries from the overview sessions and the panel presentations.

  7. Nano-scale topography of bearing surface in advanced alumina/zirconia hip joint before and after severe exposure in water vapor environment.

    PubMed

    Pezzotti, Giuseppe; Saito, Takuma; Padeletti, Giuseppina; Cossari, Pierluigi; Yamamoto, Kengo

    2010-06-01

    The aim of this study was to perform a surface morphology assessment with nanometer scale resolution on femoral heads made of an advanced zirconia toughened alumina (ZTA) composite. Femoral heads were characterized to a degree of statistical accuracy in the as-received state and after exposures up to 100 h in severe vapor-moist environment. Surface screening was made using an atomic force microscope (AFM). Scanning was systematically repeated on portions of surface as large as several tens of micrometers, randomly selected on the head surface, to achieve sufficient statistical reliability without lowering the nanometer-scale spatial resolution of the roughness measurement. No significant difference was found in the recorded values of surface roughness after environmental exposure (at 134 degrees C, under 2 bar), which was always comparable to that of the as-received head. Surface roughness safely lay <10 nm after environmental exposures up to 100 h, which corresponded to an exposure time in vivo of several human lifetimes (i.e., according to an experimentally derived thermal activation energy). In addition, the roughness results were significantly (about one order of magnitude) lower as compared to those recorded on femoral heads made of monolithic zirconia tested under the same conditions. PMID:20058275

  8. Neutron spallation sources in Europe

    NASA Astrophysics Data System (ADS)

    Bryant, P. J.

    1996-11-01

    After a brief general and historical discussion, the main design features of spallation sources are described. At the present time, Europe not only has the world-leading pulsed neutron spallation source, the SNS-ISIS at RAL, UK, but it is on the point of commissioning a world-leading continuous cyclotron-driven source, the SINQ at PSI, Switzerland. Looking to the future, yet more powerful pulsed sources are actively under study and the difficult problem of high-power target design (>250 kW) is leading to a new technology for liquid targets. The accelerator designs, although basically classical, require custom-built solutions that are often at the limit of present day accelerator technology.

  9. Neutron spallation sources in Europe

    NASA Astrophysics Data System (ADS)

    Bryant, P. J.

    1996-11-01

    After a brief general and historical discussion, the main design features of spallation sources are described. At the present time, Europe not only has the world-leading pulsed neutron spallation source, the SNS-ISIS at RAL, UK, but it is on the point of commissioning a world-leading continuous cyclotron-driven source, the SINQ at PSI, Switzerland. Looking to the future, yet more powerful pulsed sources are actively under study and the difficult problem of high-power target design (>250 kW) is leading to a new technology for liquid targets. The accelerator designs, although basically classical, require custom-built solutions that are often at the limit of presentday accelerator technology.

  10. Spallation radiation effects in materials

    SciTech Connect

    Mansur, L.K.; Farrell, K.; Wechsler, M.S.

    1996-06-01

    Spallation refers to the process whereby particles (chiefly neutrons) are ejected from nuclei upon bombardment by high-energy protons. Spallation neutron sources (SNS`s) use these neutrons for neutron scattering and diffraction research, and SNS`s are proposed as the basis for systems for tritium production and transmutation of nuclear waste. Materials in SNS`s are exposed to the incident proton beam (energies typically about 1000 MeV) and to the spallation neutrons (spectrum of energies extending up to about 1000 MeV). By contrast the fission neutrons in nuclear reactors have an average energy of only about 2 MeV, and the neutrons in fusion reactors would have energies below about 14 MeV. Furthermore, the protons and neutrons in SNS`s for scattering and diffraction research are pulsed at frequencies of about 10 to 60 Hz, from which significant changes in the kinetics of point and extended defects may be expected. In addition, much higher transmutation rates occur in SNS-irradiated materials, On the whole, then, significant differences in microstructural development and macroscopic properties may result upon exposure in SNS systems, as compared with fission and fusion irradiations. In a more general sense, subjecting materials to new radiation environments has almost routinely led to new discoveries. To the extent that data are avaiable, however, the spallation environment appears to increase the degree of damage without introducing totally new effects. The first part of this presentation is an overview of radiation effects in materials, outlining essential concepts and property changes and their physical bases. This background is followed by a description of SNS irradiation environments and the effects on materials of exposure to these environments. A special discussion is given of the selection of target (e.g., liquid mercury), container (e.g., austenitic stainless steel or ferritic/martensitic steel), and structural materials in SNS systems.

  11. Large Scale Laser Crystallization of Solution-based Alumina-doped Zinc Oxide (AZO) Nanoinks for Highly Transparent Conductive Electrode

    PubMed Central

    Nian, Qiong; Callahan, Michael; Saei, Mojib; Look, David; Efstathiadis, Harry; Bailey, John; Cheng, Gary J.

    2015-01-01

    A new method combining aqueous solution printing with UV Laser crystallization (UVLC) and post annealing is developed to deposit highly transparent and conductive Aluminum doped Zinc Oxide (AZO) films. This technique is able to rapidly produce large area AZO films with better structural and optoelectronic properties than most high vacuum deposition, suggesting a potential large-scale manufacturing technique. The optoelectronic performance improvement attributes to UVLC and forming gas annealing (FMG) induced grain boundary density decrease and electron traps passivation at grain boundaries. The physical model and computational simulation developed in this work could be applied to thermal treatment of many other metal oxide films. PMID:26515670

  12. Large Scale Laser Crystallization of Solution-based Alumina-doped Zinc Oxide (AZO) Nanoinks for Highly Transparent Conductive Electrode.

    PubMed

    Nian, Qiong; Callahan, Michael; Saei, Mojib; Look, David; Efstathiadis, Harry; Bailey, John; Cheng, Gary J

    2015-01-01

    A new method combining aqueous solution printing with UV Laser crystallization (UVLC) and post annealing is developed to deposit highly transparent and conductive Aluminum doped Zinc Oxide (AZO) films. This technique is able to rapidly produce large area AZO films with better structural and optoelectronic properties than most high vacuum deposition, suggesting a potential large-scale manufacturing technique. The optoelectronic performance improvement attributes to UVLC and forming gas annealing (FMG) induced grain boundary density decrease and electron traps passivation at grain boundaries. The physical model and computational simulation developed in this work could be applied to thermal treatment of many other metal oxide films. PMID:26515670

  13. Large Scale Laser Crystallization of Solution-based Alumina-doped Zinc Oxide (AZO) Nanoinks for Highly Transparent Conductive Electrode

    NASA Astrophysics Data System (ADS)

    Nian, Qiong; Callahan, Michael; Saei, Mojib; Look, David; Efstathiadis, Harry; Bailey, John; Cheng, Gary J.

    2015-10-01

    A new method combining aqueous solution printing with UV Laser crystallization (UVLC) and post annealing is developed to deposit highly transparent and conductive Aluminum doped Zinc Oxide (AZO) films. This technique is able to rapidly produce large area AZO films with better structural and optoelectronic properties than most high vacuum deposition, suggesting a potential large-scale manufacturing technique. The optoelectronic performance improvement attributes to UVLC and forming gas annealing (FMG) induced grain boundary density decrease and electron traps passivation at grain boundaries. The physical model and computational simulation developed in this work could be applied to thermal treatment of many other metal oxide films.

  14. The characteristics of alumina scales formed on HVOF-sprayed MCrAlY coatings[High Velocity Oxygen Fuel

    SciTech Connect

    Toma, D.; Brandl, W.; Koester, U.

    2000-02-01

    HVOF MCrAlY (M = Ni, Co) coatings were isothermally oxidized in synthetic air between 850 and 1050 C for times up to 167 hr. During thermal spraying, aluminum and yttrium oxidized to form a fine oxide dispersion. The HVOF MCrAlY coatings exhibited a microstructure similar to ODS alloys. The fine dispersion consisted of Al{sub 2}O{sub 3} and aluminum-yttrium oxides. The oxidation experiments showed that the oxidation rate of HVOF coatings was two times slower than the oxidation rate of VPS MCrAlY coatings. The oxidation mechanism changed mainly in the transient-stage (no metastable modification of Al{sub 2}O{sub 3} formed) and it was assumed that the oxide dispersion hindered diffusion of various elements from the bulk material during oxidation. The formation of the fine oxide dispersion also influenced the adherence of the oxide scale. The microstructures of the transient oxide scales were examined by X-ray diffraction (XRD) scanning electron microscopy (SEM), and transmission electron microscopy (TEM).

  15. Bauxite and alumina

    USGS Publications Warehouse

    Bray, E.L.

    2009-01-01

    The article provides information on bauxite and alumina mining. U.S. states like Alabama, Arkansas and Georgia produced small amounts of bauxite and bauxitic clays for nonmetallurgical uses. Total metallurgical-grade bauxite imports in 2008 is cited. The leading suppliers of bauxite to the U.S. are Jamaica, Guinea and Brazil. The estimated domestic production of alumina in 2008 is mentioned. It also discusses consumption and prices of both bauxite and alumina.

  16. Porous Alumina Films with Width-Controllable Alumina Stripes

    PubMed Central

    2010-01-01

    Porous alumina films had been fabricated by anodizing from aluminum films after an electropolishing procedure. Alumina stripes without pores can be distinguished on the surface of the porous alumina films. The width of the alumina stripes increases proportionally with the anodizing voltage. And the pores tend to be initiated close to the alumina stripes. These phenomena can be ascribed to the electric field distribution in the alumina barrier layer caused by the geometric structure of the aluminum surface. PMID:21170406

  17. Porous Alumina Films with Width-Controllable Alumina Stripes.

    PubMed

    Huang, Kai; Huang, Shi-Ming; Pu, Lin; Shi, Yi; Wu, Zhi-Ming; Ji, Li; Kang, Jun-Yong

    2010-01-01

    Porous alumina films had been fabricated by anodizing from aluminum films after an electropolishing procedure. Alumina stripes without pores can be distinguished on the surface of the porous alumina films. The width of the alumina stripes increases proportionally with the anodizing voltage. And the pores tend to be initiated close to the alumina stripes. These phenomena can be ascribed to the electric field distribution in the alumina barrier layer caused by the geometric structure of the aluminum surface. PMID:21170406

  18. Porous Alumina Films with Width-Controllable Alumina Stripes

    NASA Astrophysics Data System (ADS)

    Huang, Kai; Huang, Shi-Ming; Pu, Lin; Shi, Yi; Wu, Zhi-Ming; Ji, Li; Kang, Jun-Yong

    2010-12-01

    Porous alumina films had been fabricated by anodizing from aluminum films after an electropolishing procedure. Alumina stripes without pores can be distinguished on the surface of the porous alumina films. The width of the alumina stripes increases proportionally with the anodizing voltage. And the pores tend to be initiated close to the alumina stripes. These phenomena can be ascribed to the electric field distribution in the alumina barrier layer caused by the geometric structure of the aluminum surface.

  19. A model for astrophysical spallation reactions

    NASA Technical Reports Server (NTRS)

    Schmitt, W. F.; Ayres, C. L.; Merker, M.; Shen, B. S. P.

    1974-01-01

    A Monte-Carlo model (RENO) for spallation reactions is described which can treat both the spallations induced by a free nucleon and those induced by a complex nucleus. It differs from other such models in that it employs a discrete-nucleon representation of the nucleus and allows clusters of nucleons to form and to participate in the reaction. The RENO model is particularly suited for spallations involving the relatively light nuclei of astrophysical and cosmic-ray interest.

  20. Tensile property changes of metals irradiated to low doses with fission, fusion and spallation neutrons

    SciTech Connect

    Heinisch, H.L.; Hamilton, M.L.; Sommer, W.F.; Ferguson, P.D.

    1991-11-01

    Radiation effects due to low doses of spallation neutrons are compared directly to those produced by fission and fusion neutrons. Yield stress changes of pure Cu, alumina-dispersion-strengthened Cu and AISI 316 stainless steel irradiated at 36--55{degrees}C in the Los Alamos Spallation Radiation Effects Facility (LASREF) are compared with earlier results of irradiations at 90{degrees}C using 14 MeV D-T fusion neutrons at the Rotating Target Neutron Source and fission reactor neutrons in the Omega West Reactor. At doses up to 0.04 displacements per atom (dpa), the yield stress changes due to the three quite different neutron spectra correlate well on the basis of dpa in the stainless steel and the Cu alloy. However, in pure Cu, the measured yield stress changes due to spallation neutrons were anomalously small and should be verified by additional irradiations. With the exception of pure Cu, the low dose, low temperature experiments reveal no fundamental differences in radiation hardening by fission, fusion or spallation neutrons when compared on the basis of dpa.

  1. Microporous alumina ceramic membranes

    DOEpatents

    Anderson, M.A.; Guangyao Sheng.

    1993-05-04

    Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

  2. Microporous alumina ceramic membranes

    DOEpatents

    Anderson, Marc A.; Sheng, Guangyao

    1993-01-01

    Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

  3. Spallation performance of extracorporeal membrane oxygenation tubing.

    PubMed

    Peek, G J; Thompson, A; Killer, H M; Firmin, R K

    2000-09-01

    During the prolonged roller pump use of extracorporeal membrane oxygenation (ECMO), tubing wear generates spallation. The spallation performance of Tygon S-65-HL was measured and compared with a potential new ECMO tubing, LVA (Portex 800-500-575). Spallation was measured by on-line laser diode particle counting (HIAC) during simulated ECMO. The effects of differing levels of occlusion and pump speed were examined, as was the effect of spallation over time. The spallation produced by Tygon S-65-HL was less than that seen with LVA during 24 h of simulated ECMO (p < 0.001), and after 72 h had fallen almost to zero. Spallation with Tygon tubing increases with increasing pump speed and decreases over time. There appears to be only a weak correlation with occlusion, which is surprising. The spallation performance of Tygon S-65-HL was variable and under some conditions exceeded that of LVA. Overall, however, Tygon S-65-HL produced less spallation than LVA. Therefore, LVA cannot be recommended for clinical ECMO use. PMID:11001170

  4. PREFACE: Neutrino physics at spallation neutron sources

    NASA Astrophysics Data System (ADS)

    Avignone, F. T.; Chatterjee, L.; Efremenko, Y. V.; Strayer, M.

    2003-11-01

    Unique because of their super-light masses and tiny interaction cross sections, neutrinos combine fundamental physics on the scale of the miniscule with macroscopic physics on the scale of the cosmos. Starting from the ignition of the primal p-p chain of stellar and solar fusion reactions that signal star-birth, these elementary leptons (neutrinos) are also critical players in the life-cycles and explosive deaths of massive stars and the production and disbursement of heavy elements. Stepping beyond their importance in solar, stellar and supernova astrophysics, neutrino interactions and properties influence the evolution, dynamics and symmetries of the cosmos as a whole. Further, they serve as valuable probes of its material content at various levels of structure from atoms and nuclei to valence and sea quarks. In the light of the multitude of physics phenomena that neutrinos influence, it is imperative to enhance our understanding of neutrino interactions and properties to the maximum. This is accentuated by the recent evidence of finite neutrino mass and flavour mixing between generations that reverberates on the plethora of physics that neutrinos influence. Laboratory experiments using intense neutrino fluxes would allow precision measurements and determination of important neutrino reaction rates. These can then complement atmospheric, solar and reactor experiments that have enriched so valuably our understanding of the neutrino and its repertoire of physics applications. In particular, intermediate energy neutrino experiments can provide critical information on stellar and solar astrophysical processes, along with advancing our knowledge of nuclear structure, sub-nuclear physics and fundamental symmetries. So where should we look for such intense neutrino sources? Spallation neutron facilities by their design are sources of intense neutrino pulses that are produced as a by-product of neutron spallation. These neutrino sources could serve as unique laboratories

  5. Spallator: a new option for nuclear power

    SciTech Connect

    Steinberg, M.; Grand, P.; Takahashi, H.; Powell, J.R.; Kouts, H.J.

    1983-06-01

    The principles of the spallator reactor are reviewed. Advances in linear accelerator technology allow the design and construction of high current (hundreds of mA) continuous wave high energy (thousands of MeV) proton machines in the near term. Spallation neutronic calculations building on existing experimental results, indicate substantial neutron yields on uranium targets. Spallator target assembly designs based on water cooled reactor technology indicate operable efficient systems. Fuel cycles are presented which supply fissile material to thermal power reactors and reduce fission product waste. Preliminary comparative analysis indicates an economically competitive system in which a single purpose self-sufficient spallator supplies fuel to a number of LWRs. The spallator assures a long-term LWR power reactor economy. International interest in advancing the technology is indicated.

  6. Reuse of activated alumina

    SciTech Connect

    Hobensack, J.E.

    1991-12-31

    Activated alumina is used as a trapping media to remove trace quantities of UF{sub 6} from process vent streams. The current uranium recovery method employs concentrated nitric acid which destroys the alumina pellets and forms a sludge which is a storage and disposal problem. A recently developed technique using a distilled water rinse followed by three dilute acid rinses removes on average 97% of the uranium, and leaves the pellets intact with crush strength and surface area values comparable with new material. Trapping tests confirm the effectiveness of the recycled alumina as UF{sub 6} trapping media.

  7. Alumina from oil shale

    SciTech Connect

    Smith, J.W.

    1980-01-01

    Dawsonite-bearing oil shale of Colorado's Green River Formation offers a unique and vast (6.5 billion tons of Al/sub 2/O/sub 3/) resource of easily extractable alumina. The processing methods required by the thermal reactions of dawsonite and its oil-shale carrier also require production of shale oil, soda ash, and nahcolite as marketable coproducts. These production methods are presented. The alumina production process is contrasted with the Bayer process to describe technical advantages of extraction of alumina from oil shale which may offset the problems associated with processing a relatively lean ore. While alumina production from oil shale requires development of new technology, the technical problems appear solvable. Only the political problems arising from the now onerous and completely unnecessary Federal oil-shale withdrawal appear less solvable.

  8. Bauxite and alumina

    USGS Publications Warehouse

    Bray, E.L.

    2011-01-01

    The article discusses the latest developments in the bauxite and alumina industry, particularly in the U.S., as of June 2011. It claims that the U.S. mainly relies on imports for its bauxite consumption. Several states, including Alabama, Arkansas and Georgia, however, produce small amounts of bauxite and bauxitic clays for nonmetallurgical purposes. The major exporters of alumina to the U.S. include Australia, Brazil and Jamaica.

  9. Alumina fiber strength improvement

    NASA Technical Reports Server (NTRS)

    Pepper, R. T.; Nelson, D. C.

    1982-01-01

    The effective fiber strength of alumina fibers in an aluminum composite was increased to 173,000 psi. A high temperature heat treatment, combined with a glassy carbon surface coating, was used to prevent degradation and improve fiber tensile strength. Attempts to achieve chemical strengthening of the alumina fiber by chromium oxide and boron oxide coatings proved unsuccessful. A major problem encountered on the program was the low and inconsistent strength of the Dupont Fiber FP used for the investigation.

  10. Spallation Neutron Source reaches megawatt power

    ScienceCinema

    Dr. William F. Brinkman

    2010-01-08

    The Department of Energy's Spallation Neutron Source (SNS), already the world's most powerful facility for pulsed neutron scattering science, is now the first pulsed spallation neutron source to break the one-megawatt barrier. "Advances in the materials sciences are fundamental to the development of clean and sustainable energy technologies. In reaching this milestone of operating power, the Spallation Neutron Source is providing scientists with an unmatched resource for unlocking the secrets of materials at the molecular level," said Dr. William F. Brinkman, Director of DOE's Office of Science.

  11. Dose measurements around spallation neutron sources.

    PubMed

    Fragopoulou, M; Stoulos, S; Manolopoulou, M; Krivopustov, M; Zamani, M

    2008-01-01

    Neutron dose measurements and calculations around spallation sources appear to be of great importance in shielding research. Two spallation sources were irradiated by high-energy proton beams delivered by the Nuclotron accelerator (JINR), Dubna. Neutrons produced by the spallation sources were measured by using solid-state nuclear track detectors. In addition, neutron dose was calculated after polyethylene and concrete, using a phenomenological model based on empirical relations applied in high-energy physics. The study provides an analytical and experimental neutron benchmark analysis using the transmission factor and a comparison between the experimental results and calculations. PMID:18957519

  12. Spallation Neutron Source reaches megawatt power

    SciTech Connect

    Dr. William F. Brinkman

    2009-09-30

    The Department of Energy's Spallation Neutron Source (SNS), already the world's most powerful facility for pulsed neutron scattering science, is now the first pulsed spallation neutron source to break the one-megawatt barrier. "Advances in the materials sciences are fundamental to the development of clean and sustainable energy technologies. In reaching this milestone of operating power, the Spallation Neutron Source is providing scientists with an unmatched resource for unlocking the secrets of materials at the molecular level," said Dr. William F. Brinkman, Director of DOE's Office of Science.

  13. New head picked for European Spallation Source

    NASA Astrophysics Data System (ADS)

    Banks, Michael

    2016-06-01

    The UK physicist John Womersley is to become the next director-general of the €1.8bn European Spallation Source (ESS), which is currently being built in Lund, Sweden, by a 17-member consortium of European countries.

  14. Physics and technology of spallation neutron sources

    NASA Astrophysics Data System (ADS)

    Bauer, G. S.

    2001-05-01

    A substantial body of research is necessary in order to be able to make reliable predictions on the performance and safety of Accelerator Driven Systems (ADS), in particular of their spallation targets. So far, practical experience has resulted from the development of research neutron sources only. Next to fission and fusion, spallation is an efficient process for releasing neutrons from nuclei. Unlike the other two reactions, it is an endothermal process and can, therefore, not be used per se in energy generation. In order to sustain a spallation reaction, an energetic beam of particles, most commonly protons, must be supplied onto a heavy target. Spallation can, however, play an important role as a source of neutrons whose flux can be easily controlled via the driving beam. Although sophisticated Monte Carlo codes exist to compute all aspects of a spallation facility, many features can be understood on the basis of simple physics arguments. Technically a spallation facility is very demanding, not only because a reliable and economic accelerator of high power is needed to drive the reaction, but also, and in particular, because high levels of radiation and heat are generated in the target which are difficult to cope with. Radiation effects in a spallation environment are different from those commonly encountered in a reactor and are probably even more temperature dependent than the latter because of the high gas production rate. A commonly favored solution is the use of molten heavy metal targets. While radiation damage is not a problem in this case, except for the container, other issues need to be considered. R&D carried out for the development of spallation neutron sources will thus be beneficial also directly for ADS.

  15. European Spallation Source and Neutron Science

    NASA Astrophysics Data System (ADS)

    Yeck, James

    2014-03-01

    International collaborations in large-scale scientific projects can link Sciences and Society. Following this goal, the European Spallation Source (ESS) is a multi-disciplinary research centre under design and construction in Lund, Sweden. This new facility is funded by a collaboration of 17 European countries. Scandinavia is providing 50 percent of the construction cost whilst the other member states are providing financial support mainly via in-kind contribution from institutes, laboratories or industries of the given countries. Scientists and engineers from 35 different countries are members of the workforce in Lund who participate in its design and construction. The ESS will enable new opportunities for researchers in fields of life sciences, energy, environmental technology, cultural heritage and fundamental physics by producing very high flux neutrons to study condensed matter physics, chemistry, biology, nuclear physics and materials science. The ESS will be up to 30 times brighter than today's leading facilities and neutron sources. A tungsten target and a 5 MW long pulse proton accelerator, composed mainly of superconducting Radio-Frequency components, are used to achieve these goals.

  16. Large pore alumina

    SciTech Connect

    Ternan, M. )

    1994-04-01

    Earlier the authors reported preparation conditions for an alumina material which contained large diameter macropores (0.1-100 [mu]). The preparation variable that caused the formation of the uncommonly large macropores was the large acid/alumina ratios which were very much greater than the ones used in the preparation of conventional porous aluminas. The alumina material had large BET surface areas (200 m[sup 2]/g) and small mercury porosimetry surface areas (1 m[sup 2]/g). This indicated that micropores (d[sub MIP]<2 nm) were present in the alumina, since they were large enough for nitrogen gas molecules to enter, but too small for mercury to enter. As a result they would be too small for significant diffusion rates of residuum molecules. In earlier work, the calcining temperature was fixed at 500[degrees]C. In the current work, variations in both calcining temperature and calcining time were used in an attempt to convert some of the micropores into mesopores. 12 refs., 2 figs., 1 tab.

  17. Alumina Technology Roadmap

    SciTech Connect

    none,

    2002-02-01

    The Alumina Technology Roadmap outlines a comprehensive long-term research and development plan that defines the industry's collective future and establishes a clear pathway forward. It emphasizes twelve high-priority R&D areas deemed most significant in addressing the strategic goals.

  18. Bauxite and alumina

    USGS Publications Warehouse

    Bray, E.L.

    2010-01-01

    The article reports on the global market performance of bauxite and alumina in 2009 and presents an outlook for their 2010 performance. There were only several U.S. states that could produce bauxite and bauxitic clays including Georgia, Arkansas, and Alabama. The prices for imported refractory-grade calcined bauxite ranged between 426 U.S. dollars and 554 dollars per ton.

  19. Prediction of alumina penetration

    SciTech Connect

    Mandell, D A

    1993-02-01

    The MESA hydrocode was used to predict two-dimensional tests of L/D 10 and L/D 15 tungsten rods impacting AD 90 alumina with a steel backing. The residual penetration into the steel is the measured quantity in these experiments conducted at the Southwest Research Institute (SWR). The interface velocity as a function of time between an alumina target and a lithium fluoride window, impacted by an alumina disk at velocities between 544 m/s and 2329 m/s, was also predicted. These one-dimensional flyer plate experiments were conducted at Sandia National Laboratories using Coors AD 995 alumina. The material strength and fracture models are important in the prediction of ceramic experiments. The models used in these predictions are discussed. The penetrations in the two-dimensional tests were predicted to 11.4 percent or better. In five of the six experiments, the predicted penetration depth was deeper than the measured value. This trend is expected since the calculation is based on ideal conditions. The results show that good agreement between the 1-D flyer plate data and the MESA predictions exists at the lower impact velocities, but the maximum velocity is overpredicted as the flyer plate velocity increases. At a flyer plate velocity of 2329 m/s the code overpredicted the data by 12.3 percent.

  20. Solid Lubricant For Alumina

    NASA Technical Reports Server (NTRS)

    Dellacorte, Christopher; Pepper, Stephen V.; Honecy, Frank S.

    1993-01-01

    Outer layer of silver lubricates, while intermediate layer of titanium ensures adhesion. Lubricating outer films of silver deposited on thin intermediate films of titanium on alumina substrates found to reduce sliding friction and wear. Films provide effective lubrication for ceramic seals, bearings, and other hot sliding components in advanced high-temperature engines.

  1. Spallation of the Galileo probe heat shield

    NASA Astrophysics Data System (ADS)

    Lundell, J. H.

    1982-06-01

    The Galileo probe heat shield will encounter severe radiative and convective heating during entry into Jupiter's atmosphere. The shield is made of two different carbon phenolic composites; one is chopped-molded, and the other is tape-wrapped, both of which tend to spall under intense heating conditions. To characterize this phenomenon, an experimental program, using a gasdynamic laser, was initiated. Tests were performed at a variety of radiation intensities, and both the total and spallation mass-loss rates were measured and correlated with intensity. These correlations were then applied to calculated flight heating conditions for two model atmospheres. Entry of a 310-kg probe into the nominal atmosphere would result in a spallation mass loss of 6.3 kg, or 7.4% of the expected thermochemical mass loss. Similarly, entry of that probe into the cool-dense atmosphere would result in 11.9 kg of spallation, or about 10% of the expected thermochemical mass loss.

  2. Spallation of the Galileo probe heat shield

    NASA Technical Reports Server (NTRS)

    Lundell, J. H.

    1982-01-01

    The Galileo probe heat shield will encounter severe radiative and convective heating during entry into Jupiter's atmosphere. The shield is made of two different carbon phenolic composites; one is chopped-molded, and the other is tape-wrapped, both of which tend to spall under intense heating conditions. To characterize this phenomenon, an experimental program, using a gasdynamic laser, was initiated. Tests were performed at a variety of radiation intensities, and both the total and spallation mass-loss rates were measured and correlated with intensity. These correlations were then applied to calculated flight heating conditions for two model atmospheres. Entry of a 310-kg probe into the nominal atmosphere would result in a spallation mass loss of 6.3 kg, or 7.4% of the expected thermochemical mass loss. Similarly, entry of that probe into the cool-dense atmosphere would result in 11.9 kg of spallation, or about 10% of the expected thermochemical mass loss.

  3. Alumina forming iron base superalloy

    SciTech Connect

    Yamamoto, Yukinori; Muralidharan, Govindarajan; Brady, Michael P.

    2014-08-26

    An austenitic stainless steel alloy, consists essentially of, in weight percent 2.5 to 4 Al; 25 to 35 Ni; 12 to 19 Cr; at least 1, up to 4 total of at least one element selected from the group consisting of Nb and Ta; 0.5 to 3 Ti; less than 0.5 V; 0.1 to 1 of at least on element selected from the group consisting of Zr and Hf; 0.03 to 0.2 C; 0.005 to 0.1 B; and base Fe. The weight percent Fe is greater than the weight percent Ni. The alloy forms an external continuous scale including alumina, and contains coherent precipitates of .gamma.'-Ni.sub.3Al, and a stable essentially single phase FCC austenitic matrix microstructure. The austenitic matrix is essentially delta-ferrite-free and essentially BCC-phase-free.

  4. Deformation Behaviour of Coarse Grain Alumina under Shock Loading

    NASA Astrophysics Data System (ADS)

    Gupta, Satish

    2013-06-01

    To develop better understanding of the shock wave induced deformation behavior of coarse grain alumina ceramics, and for measurement of its Hugoniot Elastic Limit (HEL), in-situ and recovery gas gun experiments have been carried out on coarse grain alumina (grain size ~ 10 μm), prepared in the form of discs (>99.9% TMD) by pressure-less sintering of alpha alumina powder at 1583 K. The HEL value of 1.9 GPa has been determined from the kink in the pressure history recorded using piezoresistance gauge and also from the free surface velocity history of the sample shocked to 9 GPa. The nano-indentation measurements on the alumina samples shocked to 6.5 GPa showed hardness value 15% lower than 21.3 GPa for unshocked alumina, and strong Indentation Size Effect (ISE); the hardness value was still lower and the ISE was stronger for the sample shocked to 12 GPa. The XRD measurements showed reduced particle size and increased microstrains in the shocked alumina fragments. SEM, FESEM and TEM measurements on shock treated samples showed presence of grain localized micro- and nano-scale deformations, micro-cleavages, grain-boundary microcracks, extensive shear induced deformations, and localized micro-fractures, etc. These observations led to the development of a qualitative model for the damage initiation and its subsequent growth mechanisms in shocked alumina. The work performed in collaboration with K.D. Joshi of BARC and A.K. Mukhopadhyay of CGCRI.

  5. High Temperature Stability of Potassium Beta Alumina

    NASA Technical Reports Server (NTRS)

    Williams, R. M.; Kisor, A.; Ryan, M. A.

    1996-01-01

    None. From Objectives section: Evaluate the stability of potassium beta alumina under potassium AMTEC operating conditions. Evaluate the stability regime in which potassium beta alumina can be fabricated.

  6. Alumina reduction cell

    SciTech Connect

    Tabereaux, A.T.; Gunnip, F.L.

    1987-06-16

    An alumina reduction cell is described having a cathode and an anode. The anode is formed of a carbonaceous paste and baked during operation of cell and the anode having rows of anode pins on opposing faces. The pins are positioned by passing the pins through openings in anode channels vertically stacked along the opposing faces of the anode. The lowermost row of anode pins carries current through the anode; the improvement positions the anode pins passing through along a line of constant current distribution in the anode.

  7. Bauxite Mining and Alumina Refining

    PubMed Central

    Frisch, Neale; Olney, David

    2014-01-01

    Objective: To describe bauxite mining and alumina refining processes and to outline the relevant physical, chemical, biological, ergonomic, and psychosocial health risks. Methods: Review article. Results: The most important risks relate to noise, ergonomics, trauma, and caustic soda splashes of the skin/eyes. Other risks of note relate to fatigue, heat, and solar ultraviolet and for some operations tropical diseases, venomous/dangerous animals, and remote locations. Exposures to bauxite dust, alumina dust, and caustic mist in contemporary best-practice bauxite mining and alumina refining operations have not been demonstrated to be associated with clinically significant decrements in lung function. Exposures to bauxite dust and alumina dust at such operations are also not associated with the incidence of cancer. Conclusions: A range of occupational health risks in bauxite mining and alumina refining require the maintenance of effective control measures. PMID:24806720

  8. Heat Deposit Calculation in Spallation Unit

    NASA Astrophysics Data System (ADS)

    Karmanov, F. I.; Travleev, A. A.; Latysheva, L. N.; Vecchi, M.

    2001-11-01

    The present study concerns the calculation of the heat deposition in one of the EAP-80 basic units - the spallation module including the beam window, lead-bismuth spallation target and primary liquid metal cooling system. It is assumed that the model of sub-critical reactor under investigation is based on ANSALDO-INFN-ENEA-CRS4 reference configuration1. The calculation have been done by means of a couple computer codes: INCC 2 and GEANT3.21 3. These codes have been preliminary tested on the experimental data obtained in 4 for the case of interaction of proton beam and lead-bismuth targets at the energy Ep= 800MeV which is close to energy range relevant for ADS configuration.

  9. Calculation of improved spallation cross sections

    NASA Technical Reports Server (NTRS)

    Tsao, C. H.; Silberberg, R.; Letaw, J. R.

    1985-01-01

    Several research groups have recently carried out highly precise measurements (to about 10 percent) of high-energy nuclear spallation cross sections. These measurements, above 5 GeV, cover a broad range of elements: V, Fe, Cu, Ag, Ta and Au. Even the small cross sections far off the peak of the isotopic distribution curves have been measured. The semiempirical calculations are compared with the measured values. Preliminary comparisons indicate that the parameters of our spallation relations (Silberberg and Tsao, 1973) for atomic numbers 20 to 83 need modifications, e.g. a reduced slope of the mass yield distribution, broader isotopic distributions, and a shift of the isotopic distribution toward the neutron-deficient side. The required modifications are negligible near Fe and Cu, but increase with increasing target mass.

  10. Branchy alumina nanotubes

    NASA Astrophysics Data System (ADS)

    Zou, Jianping; Pu, Lin; Bao, Ximao; Feng, Duan

    2002-02-01

    Branchy alumina nanotubes (bANTs) have been shown to exist in aluminum oxide. Electron-beam evaporated 400 nm Al film on Si substrate is stepwise anodized in dilute sulfuric acid under the constant dc voltage 40 V at 10.0 °C. This electrochemical-anodizing route resulted in the formation of individual bANTs. Transmission electron microscopy showed that the length of the bANTs was around 450 nm, and the inner diameter was around 10-20 nm. We deduced that the bANTs, the completely detached multibranchy cells of anodic porous alumina (APA) film, should be evolved from the stagnant cells of the APA mother film. The bANTs may be used as templates in fabrication of individual branchy nanoscale cables, jacks, and heterojunctions. The proposed formation mechanisms of the bANTs and the stagnant cells should give some insights into the long-standing problem of APA film, i.e., the self-ordering mechanism of the cells arrangement in porous anodization of aluminum.

  11. INJECTION CHOICE FOR SPALLATION NEUTRON SOURCE RING.

    SciTech Connect

    WEI,J.; BEEBE-WANG,J.; BLASKIEWICZ,M.; BRODOWSKI,J.; FEDOTOV,A.; GARDNER,C.; LEE,Y.Y.; RAPARIA,D.; DANILOV,V.; HOLMES,J.; PRIOR,C.; REES,G.; MACHIDA,S.

    2001-06-18

    Injection is key in the low-loss design of high-intensity proton facilities like the Spallation Neutron Source (SNS). During the design of both the accumulator and the rapid-cycling-synchrotron version of the SNS, extensive comparison has been made to select injection scenarios that satisfy SNS's low-loss design criteria. This paper presents issues and considerations pertaining to the final choice of the SNS injection systems.

  12. COHERENT at the Spallation Neutron Source

    NASA Astrophysics Data System (ADS)

    Raybern, Justin; Scholberg, Kate

    2015-04-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory, Tennessee, provides an intense isotropic flux of neutrinos in the few tens-of-MeV range, with a sharply-pulsed timing structure which is beneficial for background rejection. This talk will describe how the SNS source can be used for a measurement of coherent elastic neutrino-nucleus scattering (CEvNS), the physics reach of such a measurement, and the status of COHERENT, the planned experimental program.

  13. COHERENT at the Spallation Neutron Source

    NASA Astrophysics Data System (ADS)

    Scholberg, Kate; Coherent Collaboration

    2016-03-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory, Tennessee, provides an intense isotropic flux of neutrinos in the few tens-of-MeV range, with a sharply-pulsed timing structure which is beneficial for background rejection. This talk will describe aspects of COHERENT, the experimental program underway to measure CEvNS (Coherent Elastic Neutrino-Nucleus Scattering) using low-energy nuclear recoil detectors.

  14. Linac-driven spallation-neutron source

    SciTech Connect

    Jason, A.J.

    1995-05-01

    Strong interest has arisen in accelerator-driven spallation-neutron sources that surpass existing facilities (such as ISIS at Rutherford or LANSCE at Los Alamos) by more than an order of magnitude in beam power delivered to the spallation target. The approach chosen by Los Alamos (as well as the European Spallation Source) provides the full beam energy by acceleration in a linac as opposed to primary acceleration in a synchrotron or other circular device. Two modes of neutron production are visualized for the source. A short-pulse mode produces 1 MW of beam power (at 60 pps) in pulses, of length less than 1 ms, by compression of the linac macropulse through multi-turn injection in an accumulator ring. A long-pulse mode produces a similar beam power with 1-ms-long pulses directly applied to a target. This latter mode rivals the performance of existing reactor facilities to very low neutron energies. Combination with the short-pulse mode addresses virtually all applications.

  15. Rate-dependent spallation properties of tantalum

    SciTech Connect

    Johnson, J.N.; Hixson, R.S.; Tonks, D.L.; Zurek, A.K.

    1995-09-01

    Spallation experiments are conducted on high-purity tantalum using VISAR instrumentation for impact stresses of 9.5 GPa and 6.0 GPa. The high-amplitude experiment exhibits very rapid initial spall separation, while the low-amplitude shot is only slightly above the threshold for void growth and thus exhibits distinct rate-dependent spallation behavior. These experiments are analyzed in terms of simple tensile fracture criteria, a standard rate-dependent void-growth model, and a rate-dependent void growth model in which the expected plastic volume strain makes no contribution to the relaxation of the mean stress. Recovery tests and VISAR measurements suggest an additional resistance to spallation that follows the rapid coalescence of voids; this effect is termed the secondary spall resistance and is due to the convoluted nature of the spall plane and the resulting interlocking fracture pattern that is developed and for which the stress remains unrelieved until the spall planes have separated several hundred microns.

  16. Xenon spallation systematics in Angra dos Reis. [meteoritic evolution

    NASA Technical Reports Server (NTRS)

    Hohenberg, C. M.; Hudson, B.; Kennedy, B. M.; Podosek, F. A.

    1981-01-01

    Literature Xe data for the Angra dos Reis meteorite have been resolved into constituent spallation, fission and trapped components. The spallation Xe compositions vary over a range wider than observed in any other samples, including lunar samples. These variations are due to the mixing of spallation Xe from Ba and rare earth element targets. It is possible to infer the Ba and rare earth spallation Xe compositions. Angra dos Reis spallation Xe compositions are systematically different from those observed in lunar samples, possibly because of differences in the irradiation conditions (geometry and shielding). Thus the Angra dos Reis data appear to be superior to lunar data for predicting spallation Xe compositions in other meteorites.

  17. Spallation target cryogenic cooling design challenges at the European Spallation Source

    NASA Astrophysics Data System (ADS)

    Jurns, J.; Ringnér, J.; Quack, H.; Arnold, P.; Weisend, J. G., II; Lyngh, D.

    2015-12-01

    The European Spallation Source (ESS) project is a neutron spallation source research facility currently being designed and built outside of Lund, Sweden. A linear accelerator delivers a 5 MW, 2.0 GeV, 62.5 mA proton beam to a spallation target to generate fast neutrons. Supercritical hydrogen circulates through two moderators surrounding the target, and transforms the fast neutrons emitted into slow neutrons, which are the final form of useful radiation. The supercritical hydrogen is in turn cooled from a helium cryogenic plant operating at 15-20 K. The supercritical cryogenic hydrogen circuit is a dynamic system, subject to significant changes in heat load. Proper pressure control of this system is critical to assure safe operation. The interaction between the hydrogen system and helium cryoplant poses unique challenges. This paper investigates the impact of the hydrogen system constraints on operation and control of the helium cryoplant, and suggests design options for the helium circuit.

  18. Production and characterization of alumina-titania biocomposite

    NASA Astrophysics Data System (ADS)

    Cetiner, B. N.; Erkmen, Z. E.

    2015-03-01

    Alumina is a biomaterial of choice for more than 20 years due to its high hardness accompanied by low friction, wear and inertness to in vivo environment. It has been reported that titanium oxidized to the rutile phase is bioactive. This is a property discovered for certain ceramics such as Bioglass and sintered hydroxylapatite (HA). But the combination of alumina and titania forming tialite (Aluminium titanate-50 mol % Al2O3 and 50 mol % TiO2) is a new challenge. In this work we made firstly the beneficiation of the Seydişehir alumina by leaching it in the acidic solution "the Aqua Regia" followed by preparation of batches containing 2,5 wt %, 3,5 wt % and 4,5 wt % of MgO as the sintering aid, 1 wt % of SiO2 and the balance; the alumina and titania powder mixture (1:1 mole). After sintering these batches at 1600°C for about 12 h, their mechanical properties (the compression and hardness testings) and phase ratios (the XRD analysis) were analyzed and compared with the control group containing the laboratory scale alumina instead of the Seydişehir alumina. Following the characterization (the SEM and the EDS analysis) of the substrate material, the comparison of two different materials was carried out.

  19. Prototype Spallation Neutron Source Rotating Target Assembly Final Test Report

    SciTech Connect

    McManamy, Thomas J; Graves, Van; Garmendia, Amaia Zarraoa; Sorda, Fernando; Etxeita, Borja; Rennich, Mark J

    2011-01-01

    A full-scale prototype of an extended vertical shaft, rotating target assembly based on a conceptual target design for a 1 to 3-MW spallation facility was built and tested. Key elements of the drive/coupling assembly implemented in the prototype include high integrity dynamic face seals, commercially available bearings, realistic manufacturing tolerances, effective monitoring and controls, and fail-safe shutdown features. A representative target disk suspended on a 3.5 meter prototypical shaft was coupled with the drive to complete the mechanical tests. Successful operation for 5400 hours confirmed the overall mechanical feasibility of the extended vertical shaft rotating target concept. The prototype system showed no indications of performance deterioration and the equipment did not require maintenance or relubrication.

  20. Impedance measurements of the Spallation Neutron Source extraction kicker system

    NASA Astrophysics Data System (ADS)

    Hahn, H.

    2004-10-01

    Transverse coupling impedance measurements of the Spallation Neutron Source (SNS) beam extraction system were performed and the results are here reported. The SNS beam extraction system is composed from 14 subsystems, each of which consists of a vertical kicker magnet plus a pulse forming network (PFN). Impedance bench measurements were performed on one large and one small aperture magnet, stand-alone as well as assembled with the first-article production PFN. The impedance measuring methods to cover the interesting frequency range from below 1 to 100MHz are described in considerable detail. The upper frequency range is properly covered by the conventional twin-wire method but it had to be supplemented at the low-frequency end by a direct input impedance measurement at the magnet busbar. Required modifications of the PFN to maintain the impedance budget are discussed. The total impedance estimate was finally obtained by quadratic scaling with vertical aperture from the two tested kicker subsystems.

  1. Progress for the European spallation source in Scandinavia

    NASA Astrophysics Data System (ADS)

    Vettier, Christian; Carlile, Colin J.; Carlsson, Patrik

    2009-02-01

    The proposal for the European Spallation Source (ESS) is still awaiting a decision to start construction. Nevertheless, there appears to be renewed interest and consensus in Europe to build a next-generation neutron source. The current understanding is that the ESS project will be based on a 5 MW linear proton beam accelerator and a long-pulse target station, feeding 22 neutron instruments. Several sites in Europe have submitted expressions of interest to host ESS and are preparing their final bids. Furthermore, the site selection process and discussions on potential partnerships within Europe have started. Key factors for site selection include the potential for scientific environment and proximity to other European large-scale research facilities. The Swedish proposal to construct ESS in Lund in the region Skåne will make ESS a vibrant scientific site.

  2. A Compendium of Scale Surface Microstructures: Ni(pt)al Coatings Oxidized at 1150 C for 2000 1-h Cycles

    NASA Technical Reports Server (NTRS)

    Smialek, James L.; Garg, Anita

    2010-01-01

    The surface structure of scales formed on Ni(Pt)Al coatings was characterized by SEM/EDS/BSE in plan view. Two nominally identical {100} samples of aluminide coated CMSX4 single crystal were oxidized at 1150 C for 2000 1-h cycles and were found to produce somewhat disparate behavior. One sample, with less propensity for coating grain boundary ridge deformation, presented primarily alpha-Al2O3 scale structures, with minimal weight loss and spallation. The original scale structure, still retained over most of the sample, consisted of the classic theta-alpha transformation-induced ridge network structure, with approx. 25 nm crystallographic steps and terraces indicative of surface rearrangement to low energy alumina planes. The scale grain boundary ridges were often decorated with a fine, uniform distribution of (Hf,Ti)O2 particles. Another sample, producing steady state weight losses, exhibited much interfacial spallation and a complex assortment of different structures. Broad areas of interfacial spalling, crystallographically-faceted (Ni,Co)(Al,Cr)2O4 spinel, with an alpha-Al2O3 base scale, were the dominant features. Other regions exhibited nodular spinel grains, with fine or (Ta,Ti)-rich (rutile) particles decorating or interspersed with the spinel. While these features were consistent with a coating that presented more deformation at extruded grain boundaries, the root cause of the different behavior between the duplicate samples could not be conclusively identified.

  3. Gelcasting Polycrystalline Alumina

    SciTech Connect

    Janney, M.A.; Zuk, K.J.; Wei, G.C.

    2000-01-01

    OSRAM SYLVANIA INC. is a major U.S. manufacturer of high-intensity lighting. Among its products is the Lumalux TM line of high-pressure sodium vapor arc lamps, which are used for industrial, highway, and street lighting. The key to the performance of these lamps is the polycrystalline alumina (PCA) tube that is used to contain the plasma that is formed in the electric arc. That plasma consists of ionized sodium, mercury, and xenon vapors. The key attributes of the PCA tubes are their transparency ({approximately}97% total transmittance in the visible), their refractoriness (inner wall temperature can reach l2OOC), and their chemical resistance (sodium and mercury vapor are extremely corrosive). The current efficiency of the lamps is very high, up to 100 initial lumens per watt. (Compare incandescent lamps 10-20 lumens per watt, fluorescent lamps 25-90 lumens per watt.)

  4. Alumina-forming Austenitic Alloys for Advanced Recuperators

    SciTech Connect

    Pint, Bruce A; Shingledecker, John P; Brady, Michael P; Maziasz, Philip J

    2007-01-01

    Materials selection for thin-walled recuperators has been extensively investigated over the past decade. In the latest generation of recuperated turbine engines, type 347 stainless steel has been replaced by higher alloyed steels and Ni-base chromia-forming alloys. However, high (linear) rates of chromia evaporation in exhaust gas fundamentally limits the oxidation lifetime of these chromia-forming alloys. One solution is to use alumina-forming alloys that are more resistant to this environment. The lower scale growth kinetics and resistance to evaporation in the presence of water vapor suggests an order of magnitude increase in lifetime for alumina-forming alloys. A significant problem with this strategy was the large drop in creep strength with the addition of sufficient Al to form an external alumina scale. However, new Fe-base austenitic compositions have been developed with sufficient strength for this application above 700 C.

  5. Alumina-Reinforced Zirconia Composites

    NASA Technical Reports Server (NTRS)

    Choi, Sung R.; Bansal, Narottam P.

    2003-01-01

    Alumina-reinforced zirconia composites, used as electrolyte materials for solid oxide fuel cells, were fabricated by hot pressing 10 mol percent yttria-stabilized zirconia (10-YSZ) reinforced with two different forms of alumina particulates and platelets each containing 0 to 30 mol percent alumina. Major mechanical and physical properties of both particulate and platelet composites including flexure strength, fracture toughness, slow crack growth, elastic modulus, density, Vickers microhardness, thermal conductivity, and microstructures were determined as a function of alumina content either at 25 C or at both 25 and 1000 C. Flexure strength and fracture toughness at 1000 C were maximized with 30 particulate and 30 mol percent platelet composites, respectively, while resistance to slow crack growth at 1000 C in air was greater for 30 mol percent platelet composite than for 30 mol percent particulate composites.

  6. Mechanical characterization of thin film structures using a laser spallation technique

    NASA Astrophysics Data System (ADS)

    Wu, Jianxin

    The laser spallation technique has been developed to measure the interface strength between different materials, especially thin film structures. In this work, it is refined and applied to various material systems. With these advances, the laser spallation technique is now fully mature for applications not only to measurement of material interface strength, but also to the study of laser-material interaction, dynamic fracture mechanics, as well as to the measurement of material bulk properties. In the first part of this work, the laser spallation technique was examined quantitatively for signal processing and stress wavefield recovery. It is shown that the short time Fourier transformation is another appropriate means for recovering the free surface displacement from the acquired optical signal. Two methods have been chosen to recover the stress field inside the sample. When the displacement of the coating's free surface is recorded directly, it is convenient to use a special finite difference strategy. When the free surface displacement is recorded on the bare substrate surface, it is more convenient to use the finite element method to calculate the interface strength. The application work includes several topics. The first one was the evaluation of the effect of substrate orientation and deposition mode on the interface strength of Nb-sapphire interfaces. The interface strength is higher for the sapphire substrate with prismatic orientation, and RF deposition mode yields higher interface strength than the DC mode. The second application estimated the effect of substrate roughness on the interface strength of Nb-alumina system. The effect of chemical composition of thin films on the interface strength was also investigated. The final application investigated the dynamic fracture mechanics of thin film structures. The purpose of this chapter is to clarify the controversial topic regarding the limit speed of bimaterial interface crack propagation. We were successful

  7. Gelcast zirconia-alumina composites

    SciTech Connect

    Omatete, O.O.; Bleier, A.; Westmoreland, C.G.; Young, A.C.

    1991-01-01

    Near net-shaped parts of zirconia-alumina composites have been successfully formed by gelcasting, a technique which utilizes in situ polymerization of acrylamide monomers. The high solids loading required for gelcasting ({approximately}50 vol %) was obtained by controlling the pH-dependent stability of the aqueous zirconia-alumina suspensions. A strong correspondence was found among the surface charges on the particles, colloidal stability, and the maximum solids loading. 14 refs., 3 figs., 2 tabs.

  8. Basic physics with spallation-neutron sources

    SciTech Connect

    Michaudon, A.F.

    1994-05-01

    The neutron has unique intrinsic properties widely used in basic and applied sciences. The neutron plays a well-known role in applied sciences and technology and is a unique probe well suited for the exploration of condensed-matter properties. But the neutron is also used for many other basic-physics studies, including nuclear physics, particle physics, fundamental physics, astrophysics, and cosmology. These last studies are briefly reviewed in this paper. Spallation-neutron sources today have unmatched neutron-beam properties for such studies and have great potential in future technological developments whereby these studies could be carried out under much improved conditions.

  9. Spallation neutron source beam loss monitor system

    NASA Astrophysics Data System (ADS)

    Gassner, D.; Witkover, R.; Cameron, P.; Power, J.

    2000-11-01

    The Spallation Neutron Source facility to be built at ORNL is designed to accumulate 2×1014 protons at 1.0 GeV and deliver them to the experimental target in one bunch at 60 Hz. To achieve this goal and protect the machine from excessive radiation activation, an uncontrolled loss criteria of 1 part in 104 (1 W/m) has been specified. Measured losses will be conditioned to provide machine tuning data, a beam abort trigger, and logging of loss history. The design of the distributed loss monitor system utilizing argon-filled glass ionization chambers and scintillator-photomultipliers will be presented.

  10. Calculation of astrophysical spallation reactions using the RENO model

    NASA Technical Reports Server (NTRS)

    Ayres, C. L.; Schmitt, W. F.; Merker, M.; Shen, B. S. P.

    1974-01-01

    The RENO model for the Monte-Carlo treatment of astrophysical spallation reactions has been used to generate preliminary cross-sections for the purpose of illustrating the discrete-nucleon approach to spallation modeling and to exhibit differences between two versions of RENO. Comparisons with experimental, theoretical, and semiempirical data demonstrate the practicability of the discrete-nucleon approach.-

  11. NOBLE GAS PRODUCTION FROM MERCURY SPALLATION AT SNS

    SciTech Connect

    DeVore, Joe R; Lu, Wei; Schwahn, Scott O

    2013-01-01

    Calculations for predicting the distribution of the products of spallation reactions between high energy protons and target materials are well developed and are used for design and operational applications in many projects both within DOE and in other arenas. These calculations are based on theory and limited experimental data that verifies rates of production of some spallation products exist. At the Spallation Neutron Source, a helium stream from the mercury target flows through a system to remove radioactivity from this mercury target offgas. The operation of this system offers a window through which the production of noble gases from mercury spallation by protons may be observed. This paper describes studies designed to measure the production rates of twelve noble gas isotopes within the Spallation Neutron Source mercury target.

  12. Spallation recoil II: Xenon evidence for young SiC grains

    NASA Astrophysics Data System (ADS)

    Ott, U.; Altmaier, M.; Herpers, U.; Kuhnhenn, J.; Merchel, S.; Michel, R.; Mohapatra, R. K.

    2005-11-01

    We have determined the recoil range of spallation xenon produced by irradiation of Ba glass targets with ˜1190 and ˜268 MeV protons, using a catcher technique, where spallation products are measured in target and catcher foils. The inferred range for 126Xe produced in silicon carbide is ˜0.19 μm, which implies retention of ˜70% for 126Xe produced in "typical" presolar silicon carbide grains of 1 μm size. Recoil loss of spallation xenon poses a significantly smaller problem than loss of the spallation neon from SiC grains. Ranges differ for the various Xe isotopes and scale approximately linearly as function of the mass difference between the target element, Ba, and the product. As a consequence, SiC grains of various sizes will have differences in spallation Xe composition. In an additional experiment at ˜66 MeV, where the recoil ranges of 22Na and 127Xe produced on Ba glass were determined using γ-spectrometry, we found no evidence for recoil ranges being systematically different at this lower energy. We have used the new data to put constraints on the possible presolar age of the SiC grains analyzed for Xe by Lewis et al. (1994). Uncertainties in the composition of the approximately normal Xe component in SiC (Xe-N) constitute the most serious problem in determining an age, surpassing remaining uncertainties in Xe retention and production rate. A possible interpretation is that spallation contributions are negligible and that trapped 124Xe/126Xe is ˜5% lower in Xe-N than in Q-Xe. But also for other reasonable assumptions for the 124Xe/126Xe ratio in Xe-N (e.g., as in Q-Xe), inferred exposure ages are considerably shorter than theoretically expected lifetimes for interstellar grains. A short presolar age is in line with observations by others (appearance, grain size distribution) that indicate little processing in the interstellar medium (ISM) of surviving (crystalline) SiC. This may be due to amorphization of SiC in the ISM on a much shorter time scale

  13. Spallation studies on shock loaded uranium

    SciTech Connect

    Tonks, D.L.; Hixson, R.; Gustavsen, R.L.; Vorthman, J.E.; Kelly, A.; Zurek, A.K.; Thissel, W.R.

    1997-12-31

    Uranium samples at two different purity levels were used for spall strength measurements at three different stress levels. A 50 mm single-stage gas-gun was used to produce planar impact conditions using Z-cut quartz impactors. Samples of depleted uranium were taken from very high purity material and from material that had 300 ppm of carbon added. A pair of shots was done for each impact strength, one member of the pair with VISAR diagnostics and the second with soft recovery for metallographical examination. A series of increasing final stress states were chosen to effectively freeze the microstructural damage at three places in the development to full spall separation. This allowed determination of the dependence of spall mechanisms on stress level and sample purity. This report will discuss both the results of the metallurgical examination of soft recovered samples and the modeling of the free surface VISAR data. The micrographs taken from the recovered samples show brittle cracking as the spallation failure mechanism. Deformation induced twins are plentiful and obviously play a role in the spallation process. The twins are produced in the initial shock loading and, so, are present already before the fracture process begins. The 1 d characteristics code CHARADE has been used to model the free surface VISAR data.

  14. Status Report on the Spallation Neutron Source

    SciTech Connect

    Gabriel, T.A.

    1998-10-12

    The purpose of the Spallation Neutron Source Project (SNS) is to generate low-energy neutrons (ambient [{approximately}200 meV] and cold [{approximately}50 meV]) which can be used by up to 18 neutron beam lines to study the structure and functionality of materials. The neutrons are generated by the spallation process initiated by the interactions of 1-GeV protons with a Hg target. These neutrons are reflected by a Pb reflector and are moderated by 2 water (ambient) and 2 super critical hydrogen (cryogenic) moderators. The pulse structure for the 1 MW proton beam is 60 Hertz and < 0.7 {micro}s/pulse. The facility must be upgradable to higher power levels (2- and 4- MW) with minimal operational interruptions. Although not included in the current funding or baseline, a second target station and associated support structure which will be designed to utilize cold neutrons is also considered to be an upgrade that must be incorporated with minimal impact on operations.

  15. Using spallation neutron sources for defense research

    SciTech Connect

    Pynn, R.; Sterbenz, S.M.; Weinacht, D.J.

    1996-12-31

    Advanced characterization techniques and accelerated simulation are the cornerstones of the Energy Department`s science-based program to maintain confidence in the safety, reliability, and performance of the US nuclear deterrent in an era of no nuclear testing. Neutrons and protons provided by an accelerator-based facility have an important role to play in this program, impacting several of the key stockpile stewardship and management issues identified by the Department of Defense. Many of the techniques used for defense research at a spallation source have been used for many years for the basic research community, and to a lesser extent by industrial scientists. By providing access to a broad spectrum of researchers with different backgrounds, a spallation source such as the Los Alamos Neutron Science Center is able to promote synergistic interaction between defense, basic and industrial researchers. This broadens the scientific basis of the stockpile stewardship program in the short term and will provide spin-off to industrial and basic research in the longer term.

  16. Management of tritium European Spallation Source

    SciTech Connect

    Ene, D.; Andersson, K.; Jensen, M.; Nielsen, S.; Severin, G.

    2015-03-15

    The European Spallation Source (ESS) will produce tritium via spallation and activation processes during operational activities. Within the location of ESS facility in Lund, Sweden site it is mandatory to demonstrate that the management strategy of the produced tritium ensures the compliance with the country regulation criteria. The aim of this paper is to give an overview of the different aspects of the tritium management in ESS facility. Besides the design parameter study of the helium coolant purification system of the target the consequences of the tritium releasing into the environment were also analyzed. Calculations show that the annual release of tritium during the normal operations represents a small fraction from the estimated total dose. However, more refined calculations of migration of activated-groundwater should be performed for higher hydraulic conductivities, with the availability of the results on soil examinations. With the assumption of 100% release of tritium to the atmosphere during the occurring of the extreme accidents, it was found as well that the total dose complies with the constraint. (authors)

  17. Development of a gas layer to mitigate cavitation damage in liquid mercury spallation targets

    SciTech Connect

    Felde, David K; Wendel, Mark W; Riemer, Bernie

    2008-01-01

    Establish of a gas layer between the flowing liquid and container wall is proposed for mitigating the effects of cavitation in mercury spallation targets. Previous work has shown an order of magnitude decrease in damage for a gas layer developed in a stagnant mercury target for an in-beam experiment. This work is aimed at extending these results to the more complex conditions introduced by a flowing mercury target system. A water-loop has been fabricated to provide initial insights on potential gas injection methods into a flowing liquid. An existing full-scale flow loop designed to simulate the Spallation Neutron Source target system will be used to extend these studies to mercury. A parallel analytical effort is being conducted using computational fluid dynamics (CFD) modeling to provide direction to the experimental effort. Some preliminary simulations of gas injection through a single hole have been completed and show behavior of the models that is qualitatively meaningful.

  18. Influence of Alumina Reaction Tube Impurities on the Oxidation of Chemically-Vapor-Deposited Silicon Carbide

    NASA Technical Reports Server (NTRS)

    Opila, Elizabeth

    1995-01-01

    Pure coupons of chemically vapor deposited (CVD) SiC were oxidized for 100 h in dry flowing oxygen at 1300 C. The oxidation kinetics were monitored using thermogravimetry (TGA). The experiments were first performed using high-purity alumina reaction tubes. The experiments were then repeated using fused quartz reaction tubes. Differences in oxidation kinetics, scale composition, and scale morphology were observed. These differences were attributed to impurities in the alumina tubes. Investigators interested in high-temperature oxidation of silica formers should be aware that high-purity alumina can have significant effects on experiment results.

  19. Gelcasting polycrystalline alumina

    SciTech Connect

    Janney, M.A.

    1997-04-01

    This work is being done as part of a CRADA with Osram-Sylvania, Inc. (OSI) OSI is a major U.S. manufacturer of high-intensity lighting. Among its products is the Lumalux{reg_sign} line of high-pressure sodium vapor arc lamps, which are used for industrial, highway, and street lighting. The key to the performance of these lamps is the polycrystalline alumina (PCA) tube that is used to contain the plasma that is formed in the electric arc. That plasma consists of ionized sodium, mercury, and xenon vapors. The key attributes of the PCA tubes are their transparency (95% total transmittance in the visible region), their refractoriness (inner wall temperature can reach 1400{degrees}C), and their chemical resistance (sodium and mercury vapor are extremely corrosive). The current efficiency of the lamps is very high, on the order of several hundred lumens / watt. (Compare - incandescent lamps -13 lumens/watt fluorescent lamps -30 lumens/watt.) Osram-Sylvania would like to explore using gelcasting to form PCA tubes for Lumalux{reg_sign} lamps, and eventually for metal halide lamps (known as quartz-halogen lamps). Osram-Sylvania, Inc. currently manufactures PCA tubes by isostatic pressing. This process works well for the shapes that they presently use. However, there are several types of tubes that are either difficult or impossible to make by isostatic pressing. It is the desire to make these new shapes and sizes of tubes that has prompted Osram-Sylvania`s interest in gelcasting. The purpose of the CRADA is to determine the feasibility of making PCA items having sufficient optical quality that they are useful in lighting applications using gelcasting.

  20. Porous alumina scaffold produced by sol-gel combined polymeric sponge method

    NASA Astrophysics Data System (ADS)

    Hasmaliza, M.; Fazliah, M. N.; Shafinaz, R. J.

    2012-09-01

    Sol gel is a novel method used to produce high purity alumina with nanometric scale. In this study, three-dimensional porous alumina scaffold was produced using sol-gel polymeric sponge method. Briefly, sol gel alumina was prepared by evaporation and polymeric sponge cut to designated sizes were immersed in the sol gel followed by sintering at 1250 and 1550°C. In order to study the cell interaction, the porous alumina scaffold was sterilized using autoclave prior to Human Mesenchymal Stem Cells (HMSCs) seeding on the scaffold and the cell proliferation was assessed by alamarBlue® assay. SEM results showed that during the 21 day period, HMSCs were able to attach on the scaffold surface and the interconnecting pores while maintaining its proliferation. These findings suggested the potential use of the porous alumina produced as a scaffold for implantation procedure.

  1. Determination of spallation neutron flux through spectral adjustment techniques

    NASA Astrophysics Data System (ADS)

    Mosby, M. A.; Engle, J. W.; Jackman, K. R.; Nortier, F. M.; Birnbaum, E. R.

    2016-08-01

    The Los Alamos Isotope Production Facility (IPF) creates medical isotopes using a proton beam impinged on a target stack. Spallation neutrons are created in the interaction of the beam with target. The use of these spallation neutrons to produce additional radionuclides has been proposed. However, the energy distribution and magnitude of the flux is not well understood. A modified SAND-II spectral adjustment routine has been used with radioactivation foils to determine the differential neutron fluence for these spallation neutrons during a standard IPF production run.

  2. SPALLATION STUDIES ON SHOCK LOADED U-6 WT PCT NB.

    SciTech Connect

    D. TONKS; ET AL

    2001-01-10

    Several spallation experiments have been performed on the 6 wt pct alloy of uranium using gas gun driven normal plate impacts with VISAR instrumentation and soft recovery. The nominal shock pressures achieved were 28, 34, 42, 50, 55, and 82 kbar. This paper will focus on spallation modeling, e.g. using the 1 D characteristics code CHARADE to simulate the free surface particle velocity. The spallation model involves the ductile growth and coalescence of voids. Metallographical examination of recovered samples and details of the experimental apparatus are discussed in a separate paper.

  3. Nickel in high-alumina basalts

    USGS Publications Warehouse

    Hedge, C.E.

    1971-01-01

    New analyses of high-alumina basalts reveal an average nickel content higher than previously indicated. Ni in high-alumina basalts correlates with magnesium in the same way as it does in other basalt types. There is therefore no reason, based on Ni contents, to hypothesize a special origin for high-alumina basalts and it is permissible (based on Ni contents) to form andesites by fractional crystallization from high-alumina basalts. ?? 1971.

  4. SPALLATION NEUTRON SOURCE BEAM CURRENT MONITOR ELECTRONICS.

    SciTech Connect

    KESSELMAN,M.; DAWSON,W.C.

    2002-05-06

    This paper will discuss the present electronics design for the beam current monitor system to be used throughout the Spallation Neutron Source (SNS) under construction at Oak Ridge National Laboratory. The beam is composed of a micro-pulse structure due to the 402.5MHz RF, and is chopped into mini-pulses of 645ns duration with a 300ns gap, providing a macro-pulse of 1060 mini-pulses repeating at a 60Hz rate. Ring beam current will vary from about 15ma peak during studies, to about 50Amps peak (design to 100 amps). A digital approach to droop compensation has been implemented and initial test results presented.

  5. BNL feasibility studies of spallation neutron sources

    SciTech Connect

    Lee, Y.Y.; Ruggiero, A.G.; Van Steenbergen, A.; Weng, W.T.

    1995-12-01

    This paper is the summary of conceptual design studies of a 5 MW Pulsed Spallation Neutron Source (PSNS) conducted by an interdepartmental study group at Brookhaven National Laboratory. The study was made of two periods. First, a scenario based on the use of a 600 MeV Linac followed by two fast-cycling 3.6 GeV Synchrotrons was investigated. Then, in a subsequent period, the attention of the study was directed toward an Accumulator scenario with two options: (1) a 1.25 GeV normal conducting Linac followed by two Accumulator Rings, and (2) a 2.4 GeV superconducting Linac followed by a single Accumulator Ring. The study did not make any reference to a specific site.

  6. Spallation UCN Production for nEDM

    NASA Astrophysics Data System (ADS)

    Masuda, Yasuhiro; Hatanaka, Kichiji; Jeong, Sun-Chan; Kawasaki, Shinsuke; Matsumiya, Ryohei; Matsuta, Kensaku; Mihara, Mototsugu; Watanabe, Yutaka

    A new superthermal UCN production in He-II, which is placed in a spallation neutron source, is discussed. In the new UCN source, the production rate is expected to be 200 UCN/cm3/s at a proton beam power of 500 MeV×40 μA and the UCN maximum energy of Ec = 210 neV. The γ heating in the He-II can be removed by means of 3He pumping according to calculations. For an EDM measurement, UCN are extracted from a He-II bottle through an aluminum window by using a superconducting magnet. The possibility of a 129Xe magnetometer for the EDM measurement is also discussed.

  7. Laser-Induced Spallation of Microsphere Monolayers.

    PubMed

    Hiraiwa, Morgan; Stossel, Melicent; Khanolkar, Amey; Wang, Junlan; Boechler, Nicholas

    2016-08-01

    The detachment of a semiordered monolayer of polystyrene microspheres adhered to an aluminum-coated glass substrate is studied using a laser-induced spallation technique. The microsphere-substrate adhesion force is estimated from substrate surface displacement measurements obtained using optical interferometry, and a rigid-body model that accounts for the inertia of the microspheres. The estimated adhesion force is compared with estimates obtained using an adhesive contact model together with interferometric measurements of the out-of-plane microsphere contact resonance, and with estimated work of adhesion values for the polystyrene-aluminum interface. Scanning electron microscope images of detached monolayer regions reveal a unique morphology, namely, partially detached monolayer flakes composed of single hexagonal close packed crystalline domains. This work contributes to the fields of microsphere adhesion and contact dynamics, and demonstrates a unique monolayer delamination morphology. PMID:27409715

  8. Impact cratering experiments into quartzite, sandstone and tuff: The effects of projectile size and target properties on spallation

    NASA Astrophysics Data System (ADS)

    Poelchau, Michael H.; Kenkmann, Thomas; Hoerth, Tobias; Schäfer, Frank; Rudolf, Michael; Thoma, Klaus

    2014-11-01

    Impact cratering experiments were performed on quartzite, tuff, and dry and water-saturated sandstones in the framework of the MEMIN research unit. 2.5-12 mm diameter projectiles were accelerated to ∼5 km/s. Evaluation of the resulting craters shows that crater volumes and crater efficiencies of large-scale experiments are greater than predicted by strength scaling laws. A method to approximate the transient crater volume shows that this effect is largely due to an increase in spallation. Strength scaling laws are used to determine the reduction of tensile strength in large-scale experiments and show a decrease by a factor of 1.8-3.6. This strength reduction can be correlated with a decrease in strain rate for larger projectiles, and with the Weibull theory of strength reduction for larger rock sample sizes. Further variations in spallation are observed between different target materials; a decrease in spall is suggested to be controlled by increased porosity.

  9. The European scene regarding spallation neutron sources

    SciTech Connect

    Bauer, G.S.

    1996-06-01

    In Europe, a short pulse spallation neutron source, ISIS, has been operating for over 10 years, working its way up to a beam power level of 200 kW. A continuous source, SINQ, designed for a beam power of up to 1 MW, is scheduled to start operating at the end of 1996, and a detailed feasibility study has been completed for a 410 kW short pulse source, AUSTRON. Each of these sources seems to have settled for a target concept which is at or near the limits of its feasibility: The ISIS depleted uranium plate targets, heavy water cooled and Zircaloy clad, have so far not shown satisfactory service time and operation is likely to continue with a Ta-plate target, which, in the past has been used successfully for the equivalent of one full-beam-year before it was taken out of service due to degrading thermal properties. SINQ will initially use a rod target, made of Zircaloy only, but plans exist to move on to clad lead rods as quickly as possible. Apart from the not yet explored effect of hydrogen and helium production, there are also concerns about the generation of 7-Be in the cooling water from the spallation of oxygen, which might result in undesirably high radioactivity in the cooling plant room. A Liquid metal target, also under investigation for SINQ, would not only reduce this problem to a level of about 10 %, but would also minimize the risk of radiolytic corrosion in the beam interaction zone. Base on similar arguments, AUSTRON has been designed for edge cooled targets, but thermal and stress analyses show, that this concept is not feasible at higher power levels.

  10. Strain rate effects for spallation of concrete

    NASA Astrophysics Data System (ADS)

    Häussler-Combe, Ulrich; Panteki, Evmorfia; Kühn, Tino

    2015-09-01

    Appropriate triaxial constitutive laws are the key for a realistic simulation of high speed dynamics of concrete. The strain rate effect is still an open issue within this context. In particular the question whether it is a material property - which can be covered by rate dependent stress strain relations - or mainly an effect of inertia is still under discussion. Experimental and theoretical investigations of spallation of concrete specimen in a Hopkinson Bar setup may bring some evidence into this question. For this purpose the paper describes the VERD model, a newly developed constitutive law for concrete based on a damage approach with included strain rate effects [1]. In contrast to other approaches the dynamic strength increase is not directly coupled to strain rate values but related to physical mechanisms like the retarded movement of water in capillary systems and delayed microcracking. The constitutive law is fully triaxial and implemented into explicit finite element codes for the investigation of a wide range of concrete structures exposed to impact and explosions. The current setup models spallation experiments with concrete specimen [2]. The results of such experiments are mainly related to the dynamic tensile strength and the crack energy of concrete which may be derived from, e.g., the velocity of spalled concrete fragments. The experimental results are compared to the VERD model and two further constitutive laws implemented in LS-Dyna. The results indicate that both viscosity and retarded damage are required for a realistic description of the material behaviour of concrete exposed to high strain effects [3].

  11. Spallation nucleosynthesis by accelerated charged-particles

    SciTech Connect

    Goriely, S.

    2008-05-12

    Recent observations have suggested the presence of radioactive elements, such as Pm and 84{<=}Z{<=}99 elements) at the surface of the magnetic star HD101065, also known as Przybylski's star. This star is know to be a chemically peculiar star and its anomalous 38spallation processes resulting from the interaction of the stellar material with stellar energetic particle can by themselves only explain the abundances determined by observation at the surface of HD101065. We show that specific parametric simulations can explain many different observational aspects, and in particular that a significant production of Z>30 heavy elements can be achieved. In this nucleosynthesis process, the secondary-neutron captures play a crucial role. The most attractive feature of the spallation process is the systematic production of Pm and Tc and the possible synthesis of actinides and sub-actinides.Based on such a parametric model, it is also shown that intense fluences of accelerated charged-particles interacting with surrounding material can efficiently produce elements heavier than iron. Different regimes are investigated and shown to be at the origin of p- and s-nuclei in the case of high-fluence low-flux events and r-nuclei for high-fluence high-flux irradiations. The possible existence of such irradiation events need to be confirmed by hydrodynamics simulations, but most of all by spectroscopic observations through the detection of short-lived radio-elements.

  12. Attrition resistant gamma-alumina catalyst support

    DOEpatents

    Singleton, Alan H.; Oukaci, Rachid; Goodwin, James G.

    2006-03-14

    A .gamma.-alumina catalyst support having improved attrition resistance produced by a method comprising the steps of treating a particulate .gamma.-alumina material with an acidic aqueous solution comprising water and nitric acid and then, prior to adding any catalytic material thereto, calcining the treated .gamma.-alumina.

  13. Proceedings of the international workshop on spallation materials technology

    SciTech Connect

    Mansur, L.K.; Ullmaier, H.

    1996-10-01

    This document contains papers which were presented at the International Workshop on Spallation Materials Technology. Topics included: overviews and thermal response; operational experience; materials experience; target station and component design; particle transport and damage calculations; neutron sources; and compatibility.

  14. Alumina-Enhanced Thermal Barrier

    NASA Technical Reports Server (NTRS)

    Smith, Marnell; Leiser, Dan; Goldstein, Howard

    1989-01-01

    Rigid, fibrous ceramic tile material called "alumina-enhanced thermal barrier" (AETB) extends temperature capability of insulating materials. Material has obvious potential for terrestrial use in kilns, furnaces, heat engines, and other applications in which light weight and high operating temperature are specified. Three kinds of ceramic fibers are blended, molded, and sintered to make refractory tiles.

  15. Deexcitation Modes in Spallation Nuclear Reactions

    NASA Astrophysics Data System (ADS)

    Velasco, F. G.; Guzmán, F.; Rodriguez, O.; Tumbarell, O.; Souza, D. A.; Samana, A. R.; Andrade-II, E.; Bernal Castillo, J. L.; Deppman, A.

    2016-08-01

    Spallation nuclear reactions in the range of 0.2 to 1.2 GeV are studied using the CRISP code. A new approach for the deexcitation stage of the compound nucleus was introduced. For the calculations of the level densities, this approach is based on the Back-shifted Fermi gas model (BSFG), which takes into account pairing effects and shell corrections, whereas the calculation of the fission barriers were performed by means of the Extended Thomas-Fermi plus Strutinsky Integral (ETFSI) method, which is a high-speed approximation to the Hartree-Fock method with pairing correlations treated as in the usual BCS plus blocking approach. This procedure is more appropriate to calculate level densities for exotic nuclei. Satisfactory results were obtained and compared with experimental data obtained in the GSI experiments. As another important result, we highlight some directions for the development of a qualitatively superior version of the CRISP code with the implementation of more realistic and suitable physical models to be applied in stable and exotic nuclei that participate in the process. This new version of the code includes several substantial changes in the decay of the hot compound nucleus which allow satisfactory agreement with the experimental data and a reduction of the adjustment parameters.

  16. Synchrotron based spallation neutron source concepts

    SciTech Connect

    Cho, Y.

    1998-07-01

    During the past 20 years, rapid-cycling synchrotrons (RCS) have been used very productively to generate short-pulse thermal neutron beams for neutron scattering research by materials science communities in Japan (KENS), the UK (ISIS) and the US (IPNS). The most powerful source in existence, ISIS in the UK, delivers a 160-kW proton beam to a neutron-generating target. Several recently proposed facilities require proton beams in the MW range to produce intense short-pulse neutron beams. In some proposals, a linear accelerator provides the beam power and an accumulator ring compresses the pulse length to the required {approx} 1 {micro}s. In others, RCS technology provides the bulk of the beam power and compresses the pulse length. Some synchrotron-based proposals achieve the desired beam power by combining two or more synchrotrons of the same energy, and others propose a combination of lower and higher energy synchrotrons. This paper presents the rationale for using RCS technology, and a discussion of the advantages and disadvantages of synchrotron-based spallation sources.

  17. Cryogenics at the European Spallation Source

    NASA Astrophysics Data System (ADS)

    Weisend, J. G., II; Arnold, P.; Hees, J. Fydrych. W.; Jurns, J. M.; Wang, X. L.

    Cryogenics plays an important role at the European Spallation Source, a world class neutron science center, currently under construction in Lund, Sweden. Three principal applications of cryogenics are found at ESS. The SRF cryomodules of the ESS proton linac require cooling at 2 K, 4.5 K and 40 K; the hydrogenmoderator surrounding the target that produces neutrons, requires cooling via 16.5 K helium and LHe is required for many of the scientific instruments. These needs will be met by a set of three cryogenic refrigeration/liquefaction plants and an extensive cryogenic distribution system. Significant progress has been made on the ESS cryogenic system in preparation for the expected first beam on target in 2019. This work includes: funding of industry studies for the accelerator cryoplant, preliminary design of the cryogenic distribution system, investigation of possible in kind contributors and release of the invitation to tender for the accelerator cryoplant.This paper describes the requirements, design solutions and current status of the ESS cryogenic system. The planned recovery of waste heat from the cryogenic plants, a unique aspect of ESS, is described. The procurement of the cryogenic system, expected to be done via a combination of purchase via competitive bids and in kind contributions is also discussed.

  18. The Spallation Neutron Source accelerator system design

    NASA Astrophysics Data System (ADS)

    Henderson, S.; Abraham, W.; Aleksandrov, A.; Allen, C.; Alonso, J.; Anderson, D.; Arenius, D.; Arthur, T.; Assadi, S.; Ayers, J.; Bach, P.; Badea, V.; Battle, R.; Beebe-Wang, J.; Bergmann, B.; Bernardin, J.; Bhatia, T.; Billen, J.; Birke, T.; Bjorklund, E.; Blaskiewicz, M.; Blind, B.; Blokland, W.; Bookwalter, V.; Borovina, D.; Bowling, S.; Bradley, J.; Brantley, C.; Brennan, J.; Brodowski, J.; Brown, S.; Brown, R.; Bruce, D.; Bultman, N.; Cameron, P.; Campisi, I.; Casagrande, F.; Catalan-Lasheras, N.; Champion, M.; Champion, M.; Chen, Z.; Cheng, D.; Cho, Y.; Christensen, K.; Chu, C.; Cleaves, J.; Connolly, R.; Cote, T.; Cousineau, S.; Crandall, K.; Creel, J.; Crofford, M.; Cull, P.; Cutler, R.; Dabney, R.; Dalesio, L.; Daly, E.; Damm, R.; Danilov, V.; Davino, D.; Davis, K.; Dawson, C.; Day, L.; Deibele, C.; Delayen, J.; DeLong, J.; Demello, A.; DeVan, W.; Digennaro, R.; Dixon, K.; Dodson, G.; Doleans, M.; Doolittle, L.; Doss, J.; Drury, M.; Elliot, T.; Ellis, S.; Error, J.; Fazekas, J.; Fedotov, A.; Feng, P.; Fischer, J.; Fox, W.; Fuja, R.; Funk, W.; Galambos, J.; Ganni, V.; Garnett, R.; Geng, X.; Gentzlinger, R.; Giannella, M.; Gibson, P.; Gillis, R.; Gioia, J.; Gordon, J.; Gough, R.; Greer, J.; Gregory, W.; Gribble, R.; Grice, W.; Gurd, D.; Gurd, P.; Guthrie, A.; Hahn, H.; Hardek, T.; Hardekopf, R.; Harrison, J.; Hatfield, D.; He, P.; Hechler, M.; Heistermann, F.; Helus, S.; Hiatt, T.; Hicks, S.; Hill, J.; Hill, J.; Hoff, L.; Hoff, M.; Hogan, J.; Holding, M.; Holik, P.; Holmes, J.; Holtkamp, N.; Hovater, C.; Howell, M.; Hseuh, H.; Huhn, A.; Hunter, T.; Ilg, T.; Jackson, J.; Jain, A.; Jason, A.; Jeon, D.; Johnson, G.; Jones, A.; Joseph, S.; Justice, A.; Kang, Y.; Kasemir, K.; Keller, R.; Kersevan, R.; Kerstiens, D.; Kesselman, M.; Kim, S.; Kneisel, P.; Kravchuk, L.; Kuneli, T.; Kurennoy, S.; Kustom, R.; Kwon, S.; Ladd, P.; Lambiase, R.; Lee, Y. Y.; Leitner, M.; Leung, K.-N.; Lewis, S.; Liaw, C.; Lionberger, C.; Lo, C. C.; Long, C.; Ludewig, H.; Ludvig, J.; Luft, P.; Lynch, M.; Ma, H.; MacGill, R.; Macha, K.; Madre, B.; Mahler, G.; Mahoney, K.; Maines, J.; Mammosser, J.; Mann, T.; Marneris, I.; Marroquin, P.; Martineau, R.; Matsumoto, K.; McCarthy, M.; McChesney, C.; McGahern, W.; McGehee, P.; Meng, W.; Merz, B.; Meyer, R.; Meyer, R.; Miller, B.; Mitchell, R.; Mize, J.; Monroy, M.; Munro, J.; Murdoch, G.; Musson, J.; Nath, S.; Nelson, R.; Nelson, R.; O`Hara, J.; Olsen, D.; Oren, W.; Oshatz, D.; Owens, T.; Pai, C.; Papaphilippou, I.; Patterson, N.; Patterson, J.; Pearson, C.; Pelaia, T.; Pieck, M.; Piller, C.; Plawski, T.; Plum, M.; Pogge, J.; Power, J.; Powers, T.; Preble, J.; Prokop, M.; Pruyn, J.; Purcell, D.; Rank, J.; Raparia, D.; Ratti, A.; Reass, W.; Reece, K.; Rees, D.; Regan, A.; Regis, M.; Reijonen, J.; Rej, D.; Richards, D.; Richied, D.; Rode, C.; Rodriguez, W.; Rodriguez, M.; Rohlev, A.; Rose, C.; Roseberry, T.; Rowton, L.; Roybal, W.; Rust, K.; Salazer, G.; Sandberg, J.; Saunders, J.; Schenkel, T.; Schneider, W.; Schrage, D.; Schubert, J.; Severino, F.; Shafer, R.; Shea, T.; Shishlo, A.; Shoaee, H.; Sibley, C.; Sims, J.; Smee, S.; Smith, J.; Smith, K.; Spitz, R.; Staples, J.; Stein, P.; Stettler, M.; Stirbet, M.; Stockli, M.; Stone, W.; Stout, D.; Stovall, J.; Strelo, W.; Strong, H.; Sundelin, R.; Syversrud, D.; Szajbler, M.; Takeda, H.; Tallerico, P.; Tang, J.; Tanke, E.; Tepikian, S.; Thomae, R.; Thompson, D.; Thomson, D.; Thuot, M.; Treml, C.; Tsoupas, N.; Tuozzolo, J.; Tuzel, W.; Vassioutchenko, A.; Virostek, S.; Wallig, J.; Wanderer, P.; Wang, Y.; Wang, J. G.; Wangler, T.; Warren, D.; Wei, J.; Weiss, D.; Welton, R.; Weng, J.; Weng, W.-T.; Wezensky, M.; White, M.; Whitlatch, T.; Williams, D.; Williams, E.; Wilson, K.; Wiseman, M.; Wood, R.; Wright, P.; Wu, A.; Ybarrolaza, N.; Young, K.; Young, L.; Yourd, R.; Zachoszcz, A.; Zaltsman, A.; Zhang, S.; Zhang, W.; Zhang, Y.; Zhukov, A.

    2014-11-01

    The Spallation Neutron Source (SNS) was designed and constructed by a collaboration of six U.S. Department of Energy national laboratories. The SNS accelerator system consists of a 1 GeV linear accelerator and an accumulator ring providing 1.4 MW of proton beam power in microsecond-long beam pulses to a liquid mercury target for neutron production. The accelerator complex consists of a front-end negative hydrogen-ion injector system, an 87 MeV drift tube linear accelerator, a 186 MeV side-coupled linear accelerator, a 1 GeV superconducting linear accelerator, a 248-m circumference accumulator ring and associated beam transport lines. The accelerator complex is supported by ~100 high-power RF power systems, a 2 K cryogenic plant, ~400 DC and pulsed power supply systems, ~400 beam diagnostic devices and a distributed control system handling ~100,000 I/O signals. The beam dynamics design of the SNS accelerator is presented, as is the engineering design of the major accelerator subsystems.

  19. Spallation reactions: A successful interplay between modeling and applications

    NASA Astrophysics Data System (ADS)

    David, J.-C.

    2015-06-01

    The spallation reactions are a type of nuclear reaction which occur in space by interaction of the cosmic rays with interstellar bodies. The first spallation reactions induced with an accelerator took place in 1947 at the Berkeley cyclotron (University of California) with 200MeV deuterons and 400MeV alpha beams. They highlighted the multiple emission of neutrons and charged particles and the production of a large number of residual nuclei far different from the target nuclei. In the same year, R. Serber described the reaction in two steps: a first and fast one with high-energy particle emission leading to an excited remnant nucleus, and a second one, much slower, the de-excitation of the remnant. In 2010 IAEA organized a workshop to present the results of the most widely used spallation codes within a benchmark of spallation models. If one of the goals was to understand the deficiencies, if any, in each code, one remarkable outcome points out the overall high-quality level of some models and so the great improvements achieved since Serber. Particle transport codes can then rely on such spallation models to treat the reactions between a light particle and an atomic nucleus with energies spanning from few tens of MeV up to some GeV. An overview of the spallation reactions modeling is presented in order to point out the incomparable contribution of models based on basic physics to numerous applications where such reactions occur. Validations or benchmarks, which are necessary steps in the improvement process, are also addressed, as well as the potential future domains of development. Spallation reactions modeling is a representative case of continuous studies aiming at understanding a reaction mechanism and which end up in a powerful tool.

  20. Charge-induced reversible bending in nanoporous alumina-aluminum composite

    NASA Astrophysics Data System (ADS)

    Cheng, Chuan; Ngan, A. H. W.

    2013-05-01

    Upon electrical charging, reversible bending was found in nanoporous anodic alumina-aluminum foil composites, as directly observed by an optical microscope and detected by in situ nanoindentation. The bending is thought to be the result of charge-induced surface stresses in the nanoporous alumina. The results suggest the possibility of a type of composite foil materials for applications as micro-scale actuators to transform electrical energy into mechanical energy.

  1. Alumina as a Thermoluminescent Material

    SciTech Connect

    Uzun, Erdem; Yarar, Yasemin

    2007-04-23

    Thermoluminescence dosimeters are extensively used for quantitative dose measurements in various irradiation fields. They are also important for environmental monitoring after nuclear accident and weapon tests. In this work, the principles of TLD dosimeter and characteristics of several TLD materials are presented. Besides, taken into account the importance as a raw material, the utilization of domestic alumina (Al2O3) in TLDs as a thermoluminescent material is discussed.

  2. Packed Alumina Absorbs Hypergolic Vapors

    NASA Technical Reports Server (NTRS)

    Thomas, J. J.; Mauro, D. M.

    1984-01-01

    Beds of activated alumina effective as filters to remove hypergolic vapors from gas streams. Beds absorb such substances as nitrogen oxides and hydrazines and may also absorb acetylene, ethylene, hydrogen sulfide, benzene, butadiene, butene, styrene, toluene, and xoylene. Bed has no moving parts such as pumps, blowers and mixers. Reliable and energy-conservative. Bed readily adapted to any size from small portable units for use where little vapor release is expected to large stationary units for extensive transfer operations.

  3. Comparison between experiments and molecular dynamic simulations of spallation induced by ultra-short laser shock on micrometric Tantalum targets

    NASA Astrophysics Data System (ADS)

    Cuq-Lelandais, Jean-Paul; Boustie, Michel; Soulard, Laurent; Berthe, Laurent; Sollier, Arnaud; Bontaz-Carion, Joelle; Combis, Patrick; de Resseguier, Thibaut; Lescoute, Emilien

    2009-06-01

    Shock wave propagation and the spallation within materials induced by laser shock have been investigated for roughly two decades. With the latest laser technologies evolution, one can access to shorter regimes in durations, going below the picosecond range. Shots performed with the LULI 100TW facility evidence the possibility to obtain spallation in a few microns thick metallic target. Such conditions provide an experimental data layout directly comparable with molecular dynamic simulations accessible to these scales. Molecular dynamic simulations on a single crystal of Tantalum have been performed with the CEA TERA 10 computer. First, the Hugoniot calculated by the equilibrium molecular dynamics has been compared with experimental data to check the potential (EAM) relevance to reproduce the shock wave propagation. Then, a large scale simulation on a micrometric target has been performed. We have observed the microscopic ductile damage process, the pore apparition and their time and space evolution. The results are compared with experimental results and classical one- dimensional hydrodynamic simulations.

  4. Tagging spallation backgrounds with showers in water Cherenkov detectors

    NASA Astrophysics Data System (ADS)

    Li, Shirley Weishi; Beacom, John F.

    2015-11-01

    Cosmic-ray muons and especially their secondaries break apart nuclei ("spallation") and produce fast neutrons and beta-decay isotopes, which are backgrounds for low-energy experiments. In Super-Kamiokande, these beta decays are the dominant background in 6-18 MeV, relevant for solar neutrinos and the diffuse supernova neutrino background. In a previous paper, we showed that these spallation isotopes are produced primarily in showers, instead of in isolation. This explains an empirical spatial correlation between a peak in the muon Cherenkov light profile and the spallation decay, which Super-Kamiokande used to develop a new spallation cut. However, the muon light profiles that Super-Kamiokande measured are grossly inconsistent with shower physics. We show how to resolve this discrepancy and how to reconstruct accurate profiles of muons and their showers from their Cherenkov light. We propose a new spallation cut based on these improved profiles and quantify its effects. Our results can significantly benefit low-energy studies in Super-Kamiokande, and will be especially important for detectors at shallower depths, like the proposed Hyper-Kamiokande.

  5. Optimal conditions for alumina coating formation on the MA956 superalloy for prosthetic bearing applications.

    PubMed

    Ruiz, J; Escudero, M L; Canahua, H; García-Alonso, M C

    1999-08-01

    An experimental study of the oxidation treatment at high temperature of the ODS MA956 superalloy was conducted in an attempt to achieve a protective alumina scale for biomedical applications. A quadratic response-surface model was developed in order to study the effects of treatment time and temperature (in the range of 1000 degrees C to 1250 degrees C) on scale thickness. The obtained model adequately represents the experimental response and shows that the thickness gradients of the layer increase with the temperature for each exposure time and decrease steadily to zero as the treatment time increases. The microstructural characterization reveals that the alumina scale formed at or above 1000 degrees C consists of an alpha-alumina phase. Treatments at temperatures above 1150 degrees C give rise to an alumina scale with some defect probability. An increase in the temperature up to 1200 degrees C gives rise to the appearance of some blistering of the superficial scale. An oxidation treatment of 100 h at 1100 degrees C was found to be the best for guaranteeing the formation of a defect-free, compact, adherent, and continuous alpha-alumina scale thick enough to support satisfactory wear and biological conditions. PMID:10379995

  6. Method for preparing Pb-. beta. ''-alumina ceramic

    DOEpatents

    Hellstrom, E.E.

    1984-08-30

    A process is disclosed for preparing impermeable, polycrystalline samples of Pb-..beta..''-alumina ceramic from Na-..beta..''-alumina ceramic by ion exchange. The process comprises two steps. The first step is a high-temperature vapor phase exchange of Na by K, followed by substitution of Pb for K by immersing the sample in a molten Pb salt bath. The result is a polycrystalline Pb-..beta..''-alumina ceramic that is substantially crack-free.

  7. Physical chemistry of carbothermic reduction of alumina

    SciTech Connect

    Frank, Robert A.

    1985-09-01

    Production of aluminium, by means of carbothermic reduction of alumina, is discussed. By employing a solvent metal bath to absorb the alumina metal, carbothermic reduction of alumina was accomplished at temperatures 300/degree/C lower than the temperatures reported in the literature. Reduction occurred without the formation of intermediate compounds and without the high volatilization of aluminum bearing species. Reduction of alumina immersed in a solvent bath appeared to be rate limited by chemical reaction control. The rates seemed to be a function of the activity of aluminum in the solvent metal bath. Reduction of alumina particles, above the surface of the bath, seemed to occur via vapor transport with carbon in the particles or in the crucible walls. Mass transport in the gas phase appeared to be rate limiting. The rates seemed to be a function of the distance separating the alumina and carbon sources. With both submerged alumina and alumina particles, increasing the surface area of the alumina increased the rate of reduction. 58 refs., 65 figs., 9 tabs.

  8. Microwave sintering of large alumina bodies

    SciTech Connect

    Blake, R.D.; Katz, J.D.

    1993-05-01

    The application of microwaves as an energy source for materials processing of large alumina bodies at elevated temperatures has been limited to date. Most work has concerned itself with small laboratory samples. The nonuniformity of the microwave field within a cavity subjects large alumina bodies to areas of concentrated energy, resulting in uneven heating and subsequent cracking. Smaller bodies are not significantly affected by field nonuniformity due to their smaller mass. This work will demonstrate a method for microwave sintering of large alumina bodies while maintaining their structural integrity. Several alumina configurations were successfully sintered using a method which creates an artificial field or environment within the microwave cavity.

  9. Microwave sintering of large alumina bodies

    SciTech Connect

    Blake, R.D.; Katz, J.D.

    1993-01-01

    The application of microwaves as an energy source for materials processing of large alumina bodies at elevated temperatures has been limited to date. Most work has concerned itself with small laboratory samples. The nonuniformity of the microwave field within a cavity subjects large alumina bodies to areas of concentrated energy, resulting in uneven heating and subsequent cracking. Smaller bodies are not significantly affected by field nonuniformity due to their smaller mass. This work will demonstrate a method for microwave sintering of large alumina bodies while maintaining their structural integrity. Several alumina configurations were successfully sintered using a method which creates an artificial field or environment within the microwave cavity.

  10. China Spallation Neutron Source: Design, R&D, and outlook

    NASA Astrophysics Data System (ADS)

    Wei, Jie; Chen, Hesheng; Chen, Yanwei; Chen, Yuanbo; Chi, Yunlong; Deng, Changdong; Dong, Haiyi; Dong, Lan; Fang, Shouxian; Feng, Ji; Fu, Shinian; He, Lunhua; He, Wei; Heng, Yuekun; Huang, Kaixi; Jia, Xuejun; Kang, Wen; Kong, Xiangcheng; Li, Jian; Liang, Tianjiao; Lin, Guoping; Liu, Zhenan; Ouyang, Huafu; Qin, Qing; Qu, Huamin; Shi, Caitu; Sun, Hong; Tang, Jingyu; Tao, Juzhou; Wang, Chunhong; Wang, Fangwei; Wang, Dingsheng; Wang, Qingbin; Wang, Sheng; Wei, Tao; Xi, Jiwei; Xu, Taoguang; Xu, Zhongxiong; Yin, Wen; Yin, Xuejun; Zhang, Jing; Zhang, Zong; Zhang, Zonghua; Zhou, Min; Zhu, Tao

    2009-02-01

    The China Spallation Neutron Source (CSNS) is an accelerator based multidiscipline user facility planned to be constructed in Dongguan, Guangdong, China. The CSNS complex consists of an negative hydrogen linear accelerator, a rapid cycling proton synchrotron accelerating the beam to 1.6 GeV energy, a solid tungsten target station, and instruments for spallation neutron applications. The facility operates at 25 Hz repetition rate with an initial design beam power of 120 kW and is upgradeable to 500 kW. The primary challenge is to build a robust and reliable user's facility with upgrade potential at a fraction of "world standard" cost. We report the status, design, R&D, and upgrade outlook including applications using spallation neutron, muon, fast neutron, and proton, as well as related programs including medical therapy and accelerator-driven sub-critical reactor (ADS) programs for nuclear waste transmutation.

  11. Split-target neutronics and the MLNSC spallation target system

    SciTech Connect

    Russell, G.J.; Ferguson, P.D.; Pitcher, E.J.; Court, J.D.

    1996-12-31

    The Manuel Lujan, Jr., Neutron Scattering Center (MLNSC) at the Los Alamos National Laboratory is one of four operating Short-Pulse Spallation Sources worldwide. The MLNSC target system (composed of targets, moderators, and reflectors) was first installed in 1985. The target system employs a split tungsten spallation target with a void space in between (the flux-trap gap); this target system will be upgraded in 1998. The ability to efficiently split a spallation target allowed us to introduce the concept of flux-trap moderators and ultimately the notion of backscattering and upstream moderators. The upgraded MLNSC target system will employ both flux-trap and upstream/backscattering moderators to simultaneously service 16 neutron flight paths with high-intensity neutron beams for materials science research.

  12. Monte Carlo modeling of spallation targets containing uranium and americium

    NASA Astrophysics Data System (ADS)

    Malyshkin, Yury; Pshenichnov, Igor; Mishustin, Igor; Greiner, Walter

    2014-09-01

    Neutron production and transport in spallation targets made of uranium and americium are studied with a Geant4-based code MCADS (Monte Carlo model for Accelerator Driven Systems). A good agreement of MCADS results with experimental data on neutron- and proton-induced reactions on 241Am and 243Am nuclei allows to use this model for simulations with extended Am targets. It was demonstrated that MCADS model can be used for calculating the values of critical mass for 233,235U, 237Np, 239Pu and 241Am. Several geometry options and material compositions (U, U + Am, Am, Am2O3) are considered for spallation targets to be used in Accelerator Driven Systems. All considered options operate as deep subcritical targets having neutron multiplication factor of k∼0.5. It is found that more than 4 kg of Am can be burned in one spallation target during the first year of operation.

  13. Modeling of water radiolysis at spallation neutron sources

    SciTech Connect

    Daemen, L.L.; Kanner, G.S.; Lillard, R.S.; Butt, D.P.; Brun, T.O.; Sommer, W.F.

    1998-12-01

    In spallation neutron sources neutrons are produced when a beam of high-energy particles (e.g., 1 GeV protons) collides with a (water-cooled) heavy metal target such as tungsten. The resulting spallation reactions produce a complex radiation environment (which differs from typical conditions at fission and fusion reactors) leading to the radiolysis of water molecules. Most water radiolysis products are short-lived but extremely reactive. When formed in the vicinity of the target surface they can react with metal atoms, thereby contributing to target corrosion. The authors will describe the results of calculations and experiments performed at Los Alamos to determine the impact on target corrosion of water radiolysis in the spallation radiation environment. The computational methodology relies on the use of the Los Alamos radiation transport code, LAHET, to determine the radiation environment, and the AEA code, FACSIMILE, to model reaction-diffusion processes.

  14. Neutron scattering instrumentation for biology at spallation neutron sources

    SciTech Connect

    Pynn, R.

    1994-12-31

    Conventional wisdom holds that since biological entities are large, they must be studied with cold neutrons, a domain in which reactor sources of neutrons are often supposed to be pre-eminent. In fact, the current generation of pulsed spallation neutron sources, such as LANSCE at Los Alamos and ISIS in the United Kingdom, has demonstrated a capability for small angle scattering (SANS) - a typical cold- neutron application - that was not anticipated five years ago. Although no one has yet built a Laue diffractometer at a pulsed spallation source, calculations show that such an instrument would provide an exceptional capability for protein crystallography at one of the existing high-power spoliation sources. Even more exciting is the prospect of installing such spectrometers either at a next-generation, short-pulse spallation source or at a long-pulse spallation source. A recent Los Alamos study has shown that a one-megawatt, short-pulse source, which is an order of magnitude more powerful than LANSCE, could be built with today`s technology. In Europe, a preconceptual design study for a five-megawatt source is under way. Although such short-pulse sources are likely to be the wave of the future, they may not be necessary for some applications - such as Laue diffraction - which can be performed very well at a long-pulse spoliation source. Recently, it has been argued by Mezei that a facility that combines a short-pulse spallation source similar to LANSCE, with a one-megawatt, long-pulse spallation source would provide a cost-effective solution to the global shortage of neutrons for research. The basis for this assertion as well as the performance of some existing neutron spectrometers at short-pulse sources will be examined in this presentation.

  15. VITESS 3 - Virtual Instrumentation Tool for the European Spallation Source

    NASA Astrophysics Data System (ADS)

    Zendler, C.; Lieutenant, K.; Nekrassov, D.; Fromme, M.

    2014-07-01

    VITESS is a software widely used for simulation of neutron scattering experiments. Although originally motivated by instrument design for the European Spallation Source, all major neutron sources are available. Existing as well as future instruments on reactor or spallation sources can be designed and optimized, or simulated in a virtual experiment to prepare a measurement, including basic data evaluation. This note gives an overview of the VITESS software concept and usage. New developments are presented, including a 3D visualization of instruments and neutron trajectories, a numerical optimization routine and a parallelization tool allowing to split VITESS simulations on a computer cluster.

  16. BEAM LOSS MITIGATION IN THE OAK RIDGE SPALLATION NEUTRON SOURCE

    SciTech Connect

    Plum, Michael A

    2012-01-01

    The Oak Ridge Spallation Neutron Source (SNS) accelerator complex routinely delivers 1 MW of beam power to the spallation target. Due to this high beam power, understanding and minimizing the beam loss is an ongoing focus area of the accelerator physics program. In some areas of the accelerator facility the equipment parameters corresponding to the minimum loss are very different from the design parameters. In this presentation we will summarize the SNS beam loss measurements, the methods used to minimize the beam loss, and compare the design vs. the loss-minimized equipment parameters.

  17. A National Spallation Neutron Source for neutron scattering

    SciTech Connect

    Appleton, B.R.

    1996-10-01

    The National Spallation Neutron Source is a collaborative project or perform the conceptual design for a next generation neutron source for the Department of Energy. This paper reviews the need and justification for a new neutron source, the origins and structure of the collaboration formed to address this need, and the community input leading up to the current design approach. A reference design is presented for an accelerator based spallation neutron source that would begin operation at about 1 megawatt of power but designed so that it could be upgraded to significantly higher powers in the future. The technology approach, status, and progress on the conceptual design to date are presented.

  18. Detection of supernova neutrinos at spallation neutron sources

    NASA Astrophysics Data System (ADS)

    Huang, Ming-Yang; Guo, Xin-Heng; Young, Bing-Lin

    2016-07-01

    After considering supernova shock effects, Mikheyev-Smirnov-Wolfenstein effects, neutrino collective effects, and Earth matter effects, the detection of supernova neutrinos at the China Spallation Neutron Source is studied and the expected numbers of different flavor supernova neutrinos observed through various reaction channels are calculated with the neutrino energy spectra described by the Fermi-Dirac distribution and the “beta fit” distribution respectively. Furthermore, the numerical calculation method of supernova neutrino detection on Earth is applied to some other spallation neutron sources, and the total expected numbers of supernova neutrinos observed through different reactions channels are given. Supported by National Natural Science Foundation of China (11205185, 11175020, 11275025, 11575023)

  19. RESULTS FROM CAVITATION DAMAGE EXPERIMENTS WITH MERCURY SPALLATION TARGETS AT THE LANSCE WNR IN 2008

    SciTech Connect

    Riemer, Bernie; Abdou, Ashraf A; Felde, David K; Sangrey, Robert L; Wendel, Mark W

    2010-01-01

    Damage assessment from proton beam induced cavitation experiments on mercury spallation targets done at the LANSCE WNR facility has been completed. The experiments investigated two key questions for the Spallation Neutron Source target, namely, how damage is affected by flow velocity in the SNS coolant channel geometry, and how damage scales with proton beam intensity at a given constant charge per pulse. With regard to the former question, prior in-beam experiments indicated that the coolant channel geometry with stagnant mercury was especially vulnerable to damage which might warrant a design change. Yet other results indicated a reduction in damage with the introduction of flow. Using more prototypic to the SNS, the 2008 experiment damage results show the channel is less vulnerable than the bulk mercury side of the vessel wall. They also show no benefit from increasing channel flow velocity beyond nominal SNS speeds. The second question probed a consensus belief that damage scales with beam intensity (protons per unit area) by a power law dependence with exponent of around 4. Results from a 2005 experiment did not support this power law dependence but some observations were inconsistent and unexplained. These latest results show weaker damage dependence.

  20. Perfluoropolyalkylether decomposition on catalytic aluminas

    NASA Technical Reports Server (NTRS)

    Morales, Wilfredo

    1994-01-01

    The decomposition of Fomblin Z25, a commercial perfluoropolyalkylether liquid lubricant, was studied using the Penn State Micro-oxidation Test, and a thermal gravimetric/differential scanning calorimetry unit. The micro-oxidation test was conducted using 440C stainless steel and pure iron metal catalyst specimens, whereas the thermal gravimetric/differential scanning calorimetry tests were conducted using catalytic alumina pellets. Analysis of the thermal data, high pressure liquid chromatography data, and x-ray photoelectron spectroscopy data support evidence that there are two different decomposition mechanisms for Fomblin Z25, and that reductive sites on the catalytic surfaces are responsible for the decomposition of Fomblin Z25.

  1. Development of Alumina-Forming Austenitic Stainless Steels

    SciTech Connect

    Brady, Michael P; Yamamoto, Yukinori; Bei, Hongbin; Santella, Michael L; Maziasz, Philip J

    2009-01-01

    This paper presents the results of the continued development of creep-resistant, alumina-forming austenitic (AFA) stainless steel alloys, which exhibit a unique combination of excellent oxidation resistance via protective alumina (Al2O3) scale formation and high-temperature creep strength through the formation of stable nano-scale MC carbides and intermetallic precipitates. Efforts in fiscal year 2009 focused on the characterization and understanding of long-term oxidation resistance and tensile properties as a function of alloy composition and microstructure. Computational thermodynamic calculations of the austenitic matrix phase composition and the volume fraction of MC, B2-NiAl, and Fe2(Mo,Nb) base Laves phase precipitates were used to interpret oxidation behavior. Of particular interest was the enrichment of Cr in the austenitic matrix phase by additions of Nb, which aided the establishment and maintenance of alumina. Higher levels of Nb additions also increased the volume fraction of B2-NiAl precipitates, which served as an Al reservoir during long-term oxidation. Ageing studies of AFA alloys were conducted at 750 C for times up to 2000 h. Ageing resulted in near doubling of yield strength at room temperature after only 50 h at 750 C, with little further increase in yield strength out to 2000 h of ageing. Elongation was reduced on ageing; however, levels of 15-25% were retained at room temperature after 2000 h of total ageing.

  2. Formation of alumina-nickel-molybdenum catalysts

    SciTech Connect

    Erofeev, V.I.; Basov, V.G.; Vagin, A.I.; Kalechits, I.V.

    1982-06-01

    On the basis of the results obtained in physical and chemical studies of alumina-nickel-molybdenum oxide catalysts as well as binary system and the individual oxides, the conclusions show that the commercial catalyst consists mainly of nickel and aluminium molybdates, aluminium molybdates, molybdenum oxide, and the alumina support. 4 figures.

  3. Effects of Impurities on Alumina-Niobium InterfacialMicrostructures

    SciTech Connect

    McKeown, Joseph T.; Sugar, Joshua D.; Gronsky, Ronald; Glaeser,Andreas M.

    2005-06-20

    Optical microscopy, scanning electron microscopy, and transmission electron microscopy were employed to examine the interfacial microstructural effects of impurities in alumina substrates used to fabricate alumina-niobium interfaces via liquid-film-assisted joining. Three types of alumina were used: undoped high-purity single-crystal sapphire; a high-purity, high-strength polycrystalline alumina; and a lower-purity, lower-strength polycrystalline alumina. Interfaces formed between niobium and both the sapphire and high-purity polycrystalline alumina were free of detectable levels of impurities. In the lower-purity alumina, niobium silicides were observed at the alumina-niobium interface and on alumina grain boundaries near the interface. These silicides formed in small-grained regions of the alumina and were found to grow from the interface into the alumina along grain boundaries. Smaller silicide precipitates found on grain boundaries are believed to form upon cooling from the bonding temperature.

  4. Opportunities for Neutrino Physics at the Spallation Neutron Source (SNS)

    SciTech Connect

    Efremenko, Yuri; Hix, William Raphael

    2009-01-01

    In this paper we discuss opportunities for a neutrino program at the Spallation Neutrons Source (SNS) being commissioning at ORNL. Possible investigations can include study of neutrino-nuclear cross sections in the energy rage important for supernova dynamics and neutrino nucleosynthesis, search for neutrino-nucleus coherent scattering, and various tests of the standard model of electro-weak interactions.

  5. Post irradiation examination of the Spallation Neutron Source target vessels

    SciTech Connect

    McClintock, David A; Ferguson, Phillip D; Mansur, Louis K

    2010-01-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory is an accelerator-based pulsed neutron source that produces high-energy spallation neutrons by bombarding liquid mercury flowing through a stainless steel target vessel. During operation the proton beam and spallation neutrons produce radiation damage in the AISI 316L austenitic stainless steel target vessel and water-cooled shroud. The beam pulses also cause rapid heating of the liquid mercury, which may produce cavitation erosion damage on the inner surface of the target vessel. The cavitation erosion rate is thought to be highly sensitive to beam power and predicted to be the primary life-limiting factor of target vessel. Though mitigation of cavitation erosion and radiation damage to the target vessel will be a critical for successful high-power operation of the SNS facility, the effects of radiation damage and cavitation erosion to target vessels in liquid metal spallation systems are not well known. Therefore preparations are being undertaken to perform post irradiation examination (PIE) of the liquid mercury target vessel and water-cooled shroud after end-of-life occurs. An overview of the planned PIE for the SNS target vessel is presented here, including proposed techniques for specimen acquisition and subsequent material properties characterization.

  6. The Spallation Neutron Source and the Neutrino Physics Program

    SciTech Connect

    Stancu, Ion

    2008-02-21

    In this paper we describe the recently-completed Spallation Neutron Source (SNS) at the Oak Ridge National Laboratory (ORNL), along with a proposed long-term neutrino physics program to study neutrino-nucleus cross-sections and neutrino oscillations.

  7. Neutrino Cross-Section Measurements at the Spallation Neutron Source

    SciTech Connect

    Stancu, Ion

    2008-02-21

    In this paper we discuss the proposal to build a neutrino facility at the recently-completed Spallation Neutron Source (SNS) at the Oak Ridge National Laboratory (ORNL). This facility can host an extensive, long-term program to study neutrino-nucleus cross-sections in the range of interest for nuclear astrophysics and nuclear theory.

  8. Neutron science opportunities at pulsed spallation neutron sources

    SciTech Connect

    Carpenter, J.M.

    1996-12-31

    Using the IPNS Upgrade plan developed at Argonne National Laboratory as a worked example of the design of a pulsed spallation neutron source, this paper explores some of the scientific applications of an advanced facility for materials science studies and the instrumentation for those purposes.

  9. Neutrino Cross-Section Measurements at the Spallation Neutron Source

    NASA Astrophysics Data System (ADS)

    Stancu, Ion

    2008-02-01

    In this paper we discuss the proposal to build a neutrino facility at the recently-completed Spallation Neutron Source (SNS) at the Oak Ridge National Laboratory (ORNL). This facility can host an extensive, long-term program to study neutrino-nucleus cross-sections in the range of interest for nuclear astrophysics and nuclear theory.

  10. Gamma ray line production from cosmic ray spallation reactions

    NASA Technical Reports Server (NTRS)

    Silberberg, R.; Tsao, C. H.; Letaw, J. R.

    1985-01-01

    The gamma ray line intensities due to cosmic ray spallation reactions in clouds, the galactic disk and accreting binary pulsars are calculated. With the most favorable plausible assumptions, only a few lines may be detectable to the level of 0.0000001 per sq. cm per sec. The intensities are compared with those generated in nuclear excitation reactions.

  11. Investigation of GEV Proton-Induced Spallation Reactions

    NASA Astrophysics Data System (ADS)

    Hilscher, D.; Herbach, C.-M.; Jahnke, U.; Tishchenko, V. G.; Galin, J.; Lott, B.; Letourneau, A.; Peghaire, A.; Filges, D.; Goldenbaum, F.; Nünighoff, K.; Schaal, H.; Sterzenbach, G.; Wohlmuther, M.; Pienkowski, L.; Schröder, W. U.; Toke, J.

    2004-09-01

    A reliable modeling of GeV proton-induced spallation reactions is indispensable for the design of the spallation module and the target station of future accelerator driven hybrid reactors (ADS) or spallation neutron sources (ESS), in particular, to provide precise predictions for the neutron production, the radiation damage of materials (window), and the production of radioactivity (3H, 7Be etc.) in the target medium. Detailed experimental nuclear data are needed for sensitive validations and improvements of the models, whose predictive power is strongly dependent on the correct physical description of the three main stages of a spallation reaction: (i) the Intra-Nuclear-Cascade (INC) with the fast heating of the target nucleus, (ii) the de-excitation due to pre-equilibrium emission including the possibility of multi-fragmentation, and (iii) the statistical decay of thermally excited nuclei by evaporation of light particles and fission in the case of heavy nuclei. Key experimental data for this endeavor are absolute production cross sections and energy spectra for neutrons and light charged-particles (LCPs), emission of composite particles prior and post to the attainment of an equilibrated system, distribution of excitation energies deposited in the nuclei after the INC, and fission probabilities. Systematic measurements of such data are furthermore needed over large ranges of target nuclei and incident proton energies. Such data has been measured with the NESSI detector. An overview of new and previous results will be given.

  12. Electrochemically replicated smooth aluminum foils for anodic alumina nanochannel arrays.

    PubMed

    Biring, Sajal; Tsai, Kun-Tong; Sur, Ujjal Kumar; Wang, Yuh-Lin

    2008-01-01

    A fast electrochemical replication technique has been developed to fabricate large-scale ultra-smooth aluminum foils by exploiting readily available large-scale smooth silicon wafers as the masters. Since the adhesion of aluminum on silicon depends on the time of surface pretreatment in water, it is possible to either detach the replicated aluminum from the silicon master without damaging the replicated aluminum and master or integrate the aluminum film to the silicon substrate. Replicated ultra-smooth aluminum foils are used for the growth of both self-organized and lithographically guided long-range ordered arrays of anodic alumina nanochannels without any polishing pretreatment. PMID:21730530

  13. HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE.

    SciTech Connect

    SHAPIRO,S.M.; ZALIZNYAK,I.A.

    2002-12-30

    This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual

  14. Characterization and application of electrospun alumina nanofibers

    PubMed Central

    2014-01-01

    Alumina nanofibers were prepared by a technique that combined the sol–gel and electrospinning methods. The solution to be electrospun was prepared by mixing aluminum isopropoxide (AIP) in ethanol, which was then refluxed in the presence of an acid catalyst and polyvinylpyrolidone (PVP) in ethanol. The characterization results showed that alumina nanofibers with diameters in the range of 102 to 378 nm were successfully prepared. On the basis of the results of the XRD and FT-IR, the alumina nanofibers calcined at 1,100°C were identified as comprising the α-alumina phase, and a series of phase transitions such as boehmite → γ-alumina → α-alumina were observed from 500°C to 1,200°C. The pore size of the obtained γ-alumina nanofibers is approximately 8 nm, and it means that they are mesoporous materials. The kinetic study demonstrated that MO adsorption on alumina nanofibers can be seen that the pseudo-second-order kinetic model fits better than the pseudo-first-order kinetic model. PMID:24467944

  15. Monitoring Transport Across Modified Nanoporous Alumina Membranes

    PubMed Central

    Penumetcha, Sai S.; Kona, Ravikanth; Hardin, Jonathan L.; Molder, Andrew L.; Steinle, Erich D.

    2007-01-01

    This paper describes the use of several characterization methods to examine alumina nanotubule membranes that have been modified with specific silanes. The function of these silanes is to alter the transport properties through the membrane by changing the local environment inside the alumina nanotube. The presence of alkyl groups, either long (C18) or short and branched (isopropyl) hydrocarbon chains, on these silanes significantly decreases the rate of transport of permeant molecules through membranes containing alumina nanotubes as monitored via absorbance spectroscopy. The presence of an ionic surfactant can alter the polarity of these modified nanotubes, which correlates to an increased transport of ions. Fluorescent spectroscopy is also utilized to enhance the sensitivity of detecting these permeant molecules. Confirmation of the alkylsilane attachment to the alumina membrane is achieved with traditional infrared spectroscopy, which can also examine the lifetime of the modified membrane. The physical parameters of these silane-modified porous alumina membranes are studied via scanning electron microscopy. The alumina nanotubes are not physically closed off or capped by the silanes that are attached to the alumina surfaces.

  16. Deformation mechanisms and damage in α-alumina under hypervelocity impact loading

    NASA Astrophysics Data System (ADS)

    Zhang, Cheng; Kalia, Rajiv K.; Nakano, Aiichiro; Vashishta, Priya; Branicio, Paulo S.

    2008-04-01

    Deformation mechanisms in α-alumina under hypervelocity impact are investigated using molecular dynamics simulations containing 540×106 atoms. A cylindrical projectile impacting normal to the (0001) surface at 18km/s generates large temperature and pressure gradients around the impact face, and consequently local amorphization of the substrate in a surrounding hemispherical region is produced. Away from the impact face, a wide range of deformations emerge and disappear as a function of time under the influence of local stress fields, e.g., basal and pyramidal slips and basal and rhombohedral twins, all of which show good agreement with the experimental and theoretical results. New deformation modes are observed, such as twins along {01¯11}, which propagate at a roughly constant speed of 8km/s and nucleate a large amount of defects where subsequent fractures initiate. The relation between deformation patterns and local stress levels is investigated. During unloading, we observe that microcracks nucleate extensively at the intersections of previous deformations within an hourglass-shaped volume that connects top and bottom free surfaces. From the simulation, the fracture toughness of alumina is estimated to be 2.0±0.5MPa√m. The substrate eventually fails along the surface of the hourglass region during spallation when clusters of substrate material are ejected from both free surfaces.

  17. Laser carbonitriding of alumina surface

    NASA Astrophysics Data System (ADS)

    Yilbas, B. S.; Akhtar, S. S.; Karatas, C.

    2011-03-01

    Laser carbonitriding of alumina surfaces is examined. Temperature and stress fields developed during the laser heating of the substrate surface are predicted using the finite element method in line with the experimental conditions. The formation of Al(C, N) and AlN compounds in the surface region of irradiated workpiece is examined using X-ray Photoelectron Spectroscopy (XPS) and X-ray Diffraction (XRD). The microstructural and morphological changes in the laser irradiated region are examined using Scanning Electron Microscope (SEM). The microhardness of the resulting surface is measured and compared with the base material hardness. It is found that high temperature gradient is developed in the irradiated region, which in turn, results in high residual stress levels in this region. XPS and XRD data reveal the presence of Al (C, N) and AlN compounds in the surface region. The microhardness in the surface region of the laser treated workpiece increases significantly.

  18. Dissolution Kinetics of Alumina Calcine

    SciTech Connect

    Batcheller, Thomas Aquinas

    2001-09-01

    Dissolution kinetics of alumina type non-radioactive calcine was investigated as part of ongoing research that addresses permanent disposal of Idaho High Level Waste (HLW). Calcine waste was produced from the processing of nuclear fuel at the Idaho Nuclear Technology and Engineering Center (INTEC). Acidic radioactive raffinates were solidified at ~500°C in a fluidized bed reactor to form the dry granular calcine material. Several Waste Management alternatives for the calcine are presented in the Idaho High Level Waste Draft EIS. The Separations Alternative addresses the processing of the calcine so that the HLW is ready for removal to a national geological repository by the year 2035. Calcine dissolution is the key front-end unit operation for the separations alternative.

  19. Fabrication of thin layer beta alumina

    NASA Technical Reports Server (NTRS)

    Tennenhouse, G. J.

    1977-01-01

    Beta alumina tubes having walls 700 microns, 300 microns, and 140 microns were processed by extrusion and sintering utilizing Ford proprietary binder and fabrication systems. Tubes prepared by this method have properties similar to tubes prepared by isostatic pressing and sintering, i.e. density greater than 98% of theoretical and a helium leak rate less than 3 x 10 to the -9th power cc/sq cm/sec. Ford ultrasonic bonding techniques were used for bonding beta alumina end caps to open ended beta -alumina tubes prior to sintering. After sintering, the bond was hermetic, and the integrity of the bonded area was comparable to the body of the tube.

  20. Cast alumina forming austenitic stainless steels

    DOEpatents

    Muralidharan, Govindarajan; Yamamoto, Yukinori; Brady, Michael P

    2013-04-30

    An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.

  1. High-Power Linac for the Spallation Neutron Source

    NASA Astrophysics Data System (ADS)

    Rej, D. J.

    2002-04-01

    The Spallation Neutron Source (SNS) will be the world’s most intense source of neutrons for fundamental science and industrial applications. Design and construction of this facility, located at Oak Ridge, is a joint venture between six DOE laboratories. Construction began in 1999 and is currently ahead of the scheduled 2006 completion date. Injecting a high-power, pulsed proton beam into a mercury target produces neutrons. In this talk, we review the physics requirements, design, and status of the construction of the 1-GeV, 1.4-MW average power RF linac for SNS. The accelerator consists of a drift tube linac (DTL), a coupled-cavity linac (CCL), and a superconducting rf (SRF) linac. The phase and quadrupole settings are set to avoid structure and parametric resonances, with coherent resonances posing minimal risk for emittance growth. The DTL is 37 m long and accelerates the ions to 87 MeV. The CCL is 55 m long and accelerates the ions to 186 MeV. The rf structure design and stability for both the DTL and CCL have been validated with scale models. The SRF linac has a modular design to accelerate ions to 1000 MeV, with a straightforward upgrade to 1.3 GeV at a later date. 3D particle-in-cell simulations of beam dynamics are performed to validate performance. The accelerator utilizes 93 MW of pulsed power operating continuously at 60-Hz with an 8factor. Approximately one hundred 402.5 or 805-MHz klystrons, with outputs between 0.55 and 5 MW, are used. The klystrons are powered by a novel converter-modulator that takes advantage of recent advances in IGBT switch plate assemblies and low-loss material cores for boost transformer. Beam diagnostics include position, phase, profile, and current monitors. They are designed to enable accurate beam steering and matching, and to minimize beam loss that would lead to activation and prevent hands-on maintenance.

  2. Corrosion Behaviour of Sputtered Alumina Thin Films

    NASA Astrophysics Data System (ADS)

    Reddy, I. Neelakanta; Dey, Arjun; Sridhara, N.; Anoop, S.; Bera, Parthasarathi; Rani, R. Uma; Anandan, Chinnasamy; Sharma, Anand Kumar

    2015-10-01

    Corrosion studies of sputtered alumina thin films grown on stainless steel (SS) 304 were carried out by linear polarization and electrochemical impedance spectroscopy. Noticeable changes were not observed in morphology and surface roughness of films after carrying out the corrosion test. Corrosion current density (icorr) of alumina coated SS decreased up to 10-10 A cm-2 while icorr value in the range of 10-5-10-6 A cm-2 was observed for bare SS. The direct sputtered film showed superior corrosion resistance behaviour than the reactive sputtered film. This might be attributed to the difference in thickness of the films sputtered by direct and reactive methods. The electronic structure of deposited alumina films was studied both before and after corrosion test by X-ray photoelectron spectroscopy technique which also confirmed no structural changes of alumina film after exposing it to corrosive environment.

  3. Loss tangent measurements on unirradiated alumina

    SciTech Connect

    Zinkle, S.J.; Goulding, R.H.

    1996-04-01

    Unirradiated room temperature loss tangent for sapphire and several commercial grades of polycrystalline alumina are complied for frequencies between 10{sup 5} and 4x10{sup 11} Hz. Sapphire exhibits significantly lower values for the loss tangent at frequencies up to 10{sup 11} Hz. The loss tangents of 3 different grades of Wesgo alumina (AL300, AL995, AL998) and 2 different grades of Coors alumina (AD94, AD995) have typical values near {approx}10{sup -4} at a frequency of 10{sup 8} Hz. On the other hand, the loss tangent of Vitox alumina exhibits a large loss peak tan d{approx} 5x10{sup -3} at this frequency.

  4. Processing of Alumina-Toughened Zirconia Composites

    NASA Technical Reports Server (NTRS)

    Bansal, Narottam P.; Choi, Sung R.

    2003-01-01

    Dense and crack-free 10-mol%-yttria-stabilized zirconia (10YSZ)-alumina composites, containing 0 to 30 mol% of alumina, have been fabricated by hot pressing. Release of pressure before onset of cooling was crucial in obtaining crack-free material. Hot pressing at 1600 C resulted in the formation of ZrC by reaction of zirconia with grafoil. However, no such reaction was observed at 1500 C. Cubic zirconia and -alumina were the only phases detected from x-ray diffraction indicating no chemical reaction between the composite constituents during hot pressing. Microstructure of the composites was analyzed by scanning electron microscopy and transmission electron microscopy. Density and elastic modulus of the composites followed the rule-of-mixtures. Addition of alumina to 10YSZ resulted in lighter, stronger, and stiffer composites by decreasing density and increasing strength and elastic modulus.

  5. Studies of Plasma-Sprayed Alumina

    NASA Astrophysics Data System (ADS)

    Ilavsky, Jan

    1994-05-01

    Phase transformations and porosity of the plasma sprayed alumina deposits were examined. The dependence of the phase transformations on deposit chemistry was established. Porosity changes during heat treatment were studied and a model for the porosity is proposed. A novel technique in the field of plasma sprayed deposits--small-angle neutron scattering (SANS)--was successfully applied. Deposits were manufactured using the water-stabilized plasma spray system, PAL160, with an input of 160 kW. Phase transformations of the plasma sprayed alumina deposits were studied using XRD and DTA. The deposits were manufactured from 99.9% alumina, alumina-chromia (1.5% Cr_2O_3), gray alumina (3.7% TiO_2) and alumina -titania (17% TiO_2). The addition of chromia increases the temperature of the alpha phase formation by about 40^circ C and the addition of TiO_2 reduces this temperature by about 150^circ C for gray alumina and by about 175^ circC for alumina-titania. The amount of metastable theta phase was found to depend on the chemistry of the feedstock. Porosities of the deposits, made from alumina and gray alumina, were studied using mercury intrusion porosimetry, weighing method (Archimedean porosimetry), image analysis and SANS. Samples were studied in the as -sprayed condition and after heat treatment for 2 hours at 1300^circC and 1500 ^circC. Porosity depends on the deposit chemistry and on the heat treatment and varies from 5% to about 11%. Different porosity measurement techniques yield different results. Surface areas of 1.5 to 7.5 times 10^4 cm^2 /cm^3 (times 10^6 m^{ -1}) were measured using SANS and depend on heat treatment and on the deposit chemistry. The phase transformations can be associated with an increase in pore surface area and decrease in surface area at 1500 ^circC can be associated with sintering. The effective pore radius, R_{ rm eff}, as measured by SANS is a measure of the pore sizes in the 0.08 to 10 μm size range. The R_{rm eff} depends on deposit

  6. Current status of JAERI spallation target material program

    NASA Astrophysics Data System (ADS)

    Kikuchi, K.; Sasa, T.; Ishikura, S.; Mukugi, K.; Kai, T.; Ouchi, N.; Ioka, I.

    2001-07-01

    In the joint project of spallation neutron source between JAERI and KEK, material technology has been developed for the mercury target in the neutron source facility, the lead-bismuth target in the transmutation test facility, superconducting accelerator, post-irradiation examination and the ion beam test. Design of target system is progressing for the mercury spallation target: a pressure test of moderator, an impacting test in mercury and a corrosion test have been carried out. For nuclear transmutation with ADS an engineering facility is proposed. A material corrosion test loop is built-up and SS316 and F82H steels are to be tested in a flowing Pb-Bi. Fracture toughness of superconducting cavity material was found to be considerably large at 4 K. Irradiated samples at SINQ are to be transported to JAERI Hot Laboratory. For simulating radiation damage small disk specimens were irradiated in single, dual and triple ion beam modes.

  7. Target Operational Experience at the Spallation Neutron Source

    SciTech Connect

    Riemer, Bernie; Janney, Jim G; Kaminskas, Saulius; McClintock, David A; Rosenblad, Peter M

    2013-01-01

    The Spallation Neutron Source (SNS) at the Oak Ridge National Laboratory (ORNL) has operated at unprecedented power levels for a short-pulse spallation source. Target operations have been successful but not without difficulties. Three targets out of the eight used to date have ended life unexpectedly causing interruptions to the neutron science users. The first of a kind mercury target design experiences beam-pulse induced cavitation damage that is suspected in one of the target leaks. The two other targets suffered early failures due to defective welds. Diagnosing the causes of target leaks and understanding of the progression of cavitation erosion and radiation damage effects has made use of post-irradiation examination (PIE) capabilities. As a result of PIE, review of quality assurance practices and related investigations, design changes are being implemented and manufacturing oversight improved. This paper describes SNS target operating experience, including the more important observations and lessons learned.

  8. Spallation processes and nuclear interaction products of cosmic rays

    NASA Technical Reports Server (NTRS)

    Silberberg, R.; Tsao, C. H.

    1990-01-01

    Most cosmic-ray nuclei heavier than helium have suffered nuclear collisions in the interstellar gas, with transformation of nuclear composition. The isotopic and elemental composition at the sources has to be inferred from the observed composition near the Earth. The source composition permits tests of current ideas on sites of origin, nucleosynthesis in stars, evolution of stars, the mixing and composition of the interstellar medium and injection processes prior to acceleration. The effects of nuclear spallation, production of radioactive nuclides and the time dependence of their decay provide valuable information on the acceleration and propagation of cosmic rays, their nuclear transformations, and their confinement time in the Galaxy. The formation of spallation products that only decay by electron capture and are relatively long-lived permits an investigation of the nature and density fluctuations (like clouds) of the interstellar medium. Since nuclear collisions yield positrons, antiprotons, gamma rays and neutrinos, we shall discuss these topics briefly.

  9. Preparation and Characterization of Electrospun Alumina Nanofibers

    NASA Astrophysics Data System (ADS)

    Pinti, Marie J.; Tacastacas, Stephen N.; Stojilovic, Nenad; O'Brien, John P.; Pischera, Anna; Espe, Matthew P.

    2008-10-01

    Alumina nanofibers are promising materials for use in high- temperature applications since they are chemically inert up to very high temperatures. Applications include use as catalyst support in high-temperature chemical reactions, fire protection materials, and as a high-temperature insulator. Electrospinning is a relatively simple and inexpensive method for obtaining nanometer-size fibers and has become a popular technique for producing metal-oxide nanofibers in recent years. The electrospinning mixture for the production of alumina nanofibers typically contains aluminum acetate stabilized with boric acid as the alumina precursor; but the observed presence of boron and sodium on the surface of these nanofibers may affect their use as catalytic supports. We have produced alumina nanofibers from an aluminum reagent devoid of the boric acid stabilizer and calcined the fibers at different temperatures to produce nanofibers with different phases of alumina. Characterization of the fibers by TGA, FE-SEM equipped with the XEDS, powder XRD, DRIFTS, and SSNMR methods to determine the fate of the precursors, fiber morphology and the composition and structure of the calcined alumina nanofibers.

  10. Neutronic moderator design for the Spallation Neutron Source (SNS)

    SciTech Connect

    Charlton, L.A.; Barnes, J.M.; Johnson, J.O.; Gabriel, T.A.

    1998-11-01

    Neutronics analyses are now in progress to support the initial selection of moderator design parameters for the Spallation Neutron Source (SNS). The results of the initial optimization studies involving moderator poison plate location, moderator position, and premoderator performance for the target system are presented in this paper. Also presented is an initial study of the use of a composite moderator to produce a liquid methane like spectrum.

  11. Spallation neutron source and other high intensity froton sources

    SciTech Connect

    Weiren Chou

    2003-02-06

    This lecture is an introduction to the design of a spallation neutron source and other high intensity proton sources. It discusses two different approaches: linac-based and synchrotron-based. The requirements and design concepts of each approach are presented. The advantages and disadvantages are compared. A brief review of existing machines and those under construction and proposed is also given. An R&D program is included in an appendix.

  12. Spallation and fracture resulting from reflected and intersecting stress waves.

    NASA Technical Reports Server (NTRS)

    Kinslow, R.

    1973-01-01

    Discussion of the effects of stress waves produced in solid by explosions or high-velocity impacts. These waves rebound from free surfaces in the form of tensile waves that are capable of causing internal fractures or spallation of the material. The high-speed framing camera is shown to be an important tool for observing the stress waves and fracture in transparent targets, and its photographs provide valuable information on the mechanics of fracture.

  13. SPALLATION NEUTRON SOURCE OPERATIONAL EXPERIENCE AT 1 MW

    SciTech Connect

    Galambos, John D

    2011-01-01

    The Spallation Neutron Source (SNS) has been operating at the MW level for about one year. Experience in beam loss control and machine activation at this power level is presented. Also experience with machine protection systems is reviewed, which is critical at this power level. One of the most challenging operational aspects of high power operation has been attaining high availability, which is also discussed

  14. Decommissioning and PIE of the MEGAPIE spallation target

    SciTech Connect

    Latge, C.; Henry, J.; Wohlmuther, M.; Dai, Y.; Gavillet, D.; Hammer, B.; Heinitz, S.; Neuhausen, J.; Schumann, D.; Thomsen, K.; Tuerler, A.; Wagner, W.; Gessi, A.; Guertin, A.; Konstantinovic, M.; Lindau, R.; Maloy, S.; Saito, S.

    2013-07-01

    A key experiment in the Accelerated Driven Systems roadmap, the MEGAwatt PIlot Experiment (MEGAPIE) (1 MW) was initiated in 1999 in order to design and build a liquid lead-bismuth spallation target, then to operate it into the Swiss spallation neutron facility SINQ at Paul Scherrer Institute. The target has been designed, manufactured, and tested during integral tests, before irradiation carried out end of 2006. During irradiation, neutron and thermo hydraulic measurements were performed allowing deep interpretation of the experiment and validation of the models used during design phase. The decommissioning, Post Irradiation Examinations and waste management phases were defined properly. The phases dedicated to cutting, sampling, cleaning, waste management, samples preparation and shipping to various laboratories were performed by PSI teams: all these phases constitute a huge work, which allows now to perform post-irradiation examination (PIE) of structural material, irradiated in relevant conditions. Preliminary results are presented in the paper, they concern chemical characterization. The following radio-nuclides have been identified by γ-spectrometry: {sup 60}Co, {sup 101}Rh, {sup 102}Rh, {sup 108m}Ag, {sup 110m}Ag, {sup 133}Ba, {sup 172}Hf/Lu, {sup 173}Lu, {sup 194}Hg/Au, {sup 195}Au, {sup 207}Bi. For some of these nuclides the activities can be easily evaluated from γ-spectrometry results ({sup 207}Bi, {sup 194}Hg/Au), while other nuclides can only be determined after chemical separations ({sup 108m}Ag, {sup 110m}Ag, {sup 195}Au, {sup 129}I, {sup 36}Cl and α-emitting {sup 208-210}Po). The concentration of {sup 129}I is lower than expected. The chemical analysis already performed on spallation and corrosion products in the lead-bismuth eutectic (LBE) are very relevant for further applications of LBE as a spallation media and more generally as a coolant.

  15. Fission of 232Th in a spallation neutron field

    NASA Astrophysics Data System (ADS)

    Yurevich, V. I.; Nikolaev, V. A.; Yakovlev, R. M.

    2016-03-01

    The spatial distributions of thorium fission reaction rate in a spallation neutron field of thick lead target bombarded by protons or deuterons with energy between 1.0 and 3.7 GeV were measured. Approximately a linear dependence of the thorium fission rate on the beam energy is observed. The mean fission cross section of 232Th <σ f > ≈ 123 mb and it does not depend on energy and type of the beam particles.

  16. Material issues relating to high power spallation neutron sources

    NASA Astrophysics Data System (ADS)

    Futakawa, M.

    2015-02-01

    Innovative researches using neutrons are being performed at the Materials and Life Science Experimental Facility (MLF) at the Japan Proton Accelerator Research Complex (J-PARC), in which a mercury target system is installed for MW-class pulse spallation neutron sources. In order to produce neutrons by the spallation reaction, proton beams are injected into the mercury target. At the moment, when the intense proton beam hits the target, pressure waves are generated in mercury because of the abrupt heat deposition. The pressure waves interact with the target vessel, leading to negative pressure that may cause cavitation along the vessel wall, i.e. on the interface between liquid and solid metals. On the other hand, the structural materials are subjected to irradiation damage due to protons and neutrons, very high cycle fatigue damages and so-called "liquid metal embrittlement". That is, the structural materials must be said to be exposed to the extremely severe environments. In the paper, research and development relating to the material issues in the high power spallation neutron sources that has been performed so far at J-PARC is summarized.

  17. Astrophysical Li-7 as a product of big bang nucleosynthesis and galactic cosmic-ray spallation

    NASA Technical Reports Server (NTRS)

    Olive, Keith A.; Schramm, David N.

    1992-01-01

    The astrophysical Li-7 abundance is considered to be largely primordial, while the Be and B abundances are thought to be due to galactic cosmic ray (GCR) spallation reactions on top of a much smaller big bang component. But GCR spallation should also produce Li-7. As a consistency check on the combination of big bang nucleosynthesis and GCR spallation, the Be and B data from a sample of hot population II stars is used to subtract from the measured Li-7 abundance an estimate of the amount generated by GCR spallation for each star in the sample, and then to add to this baseline an estimate of the metallicity-dependent augmentation of Li-7 due to spallation. The singly reduced primordial Li-7 abundance is still consistent with big bang nucleosynthesis, and a single GCR spallation model can fit the Be, B, and corrected Li-7 abundances for all the stars in the sample.

  18. The effect of delta T /oxidizing temperature minus cooling temperature/ on oxide spallation

    NASA Technical Reports Server (NTRS)

    Deadmore, D. L.; Lowell, C. E.

    1977-01-01

    Several alloys (one iron base and five nickel base) were cyclically oxidized in a series of tests in which the higher temperature (1100 or 1200 C) of the cycle was fixed at a level to allow ample oxidation in reasonable time and the lower temperature was variable to allow cycle temperature differences of up to 1400 C. For all nickel alloys, as delta T increased the extent of spallation increased. This effect was attributed to thermal expansion mismatches between the oxide and the nickel substrate. The FeCrAl alloy was not sensitive to delta T and resisted spalling at delta T levels to 1400 C. FeCrAl, and the Al2O3 scale which forms on it, have thermal expansion coefficients which are substantially more alike than any of the other oxide-metal combinations tested.

  19. Rationale for a spallation neutron source target system test facility at the 1-MW Long-Pulse Spallation Source

    SciTech Connect

    Sommer, W.F.

    1995-12-01

    The conceptual design study for a 1-MW Long-Pulse Spallation Source at the Los Alamos Neutron Science Center has shown the feasibility of including a spallation neutron test facility at a relatively low cost. This document presents a rationale for developing such a test bed. Currently, neutron scattering facilities operate at a maximum power of 0.2 MW. Proposed new designs call for power levels as high as 10 MW, and future transmutation activities may require as much as 200 MW. A test bed will allow assessment of target neutronics; thermal hydraulics; remote handling; mechanical structure; corrosion in aqueous, non-aqueous, liquid metal, and molten salt systems; thermal shock on systems and system components; and materials for target systems. Reliable data in these areas are crucial to the safe and reliable operation of new high-power facilities. These tests will provide data useful not only to spallation neutron sources proposed or under development, but also to other projects in accelerator-driven transmutation technologies such as the production of tritium.

  20. Thirty years of experience with alumina-on-alumina bearings in total hip arthroplasty.

    PubMed

    Hannouche, Didier; Zaoui, Amine; Zadegan, Frédéric; Sedel, Laurent; Nizard, Rémy

    2011-02-01

    Alumina-on-alumina bearings in total hip arthroplasty have been developed in an attempt to minimise debris and the occurrence of osteolytic lesions. The outstanding tribological properties of this bearing system are explained by low surface roughness, high hardness for major scratch resistance, and high wettability. Since the 1970s, technological improvements in the manufacturing process of alumina components together with a better understanding of Morse taper technology have provided a surgical grade material with high density, high purity and small grains. Published studies on the outcome of total hip arthroplasty performed with this new generation of implants showed high survivorship especially in young and active patients, with survival rates free of revision of 90.8% to 97.4% at ten years. However, concern remains over ceramic liner fracture and squeaking, which has been noted recently with increasing prevalence. This review will discuss the current knowledge on the use of alumina-on-alumina bearings. PMID:21191579

  1. Thirty years of experience with alumina-on-alumina bearings in total hip arthroplasty

    PubMed Central

    Zaoui, Amine; Zadegan, Frédéric; Sedel, Laurent; Nizard, Rémy

    2010-01-01

    Alumina-on-alumina bearings in total hip arthroplasty have been developed in an attempt to minimise debris and the occurrence of osteolytic lesions. The outstanding tribological properties of this bearing system are explained by low surface roughness, high hardness for major scratch resistance, and high wettability. Since the 1970s, technological improvements in the manufacturing process of alumina components together with a better understanding of Morse taper technology have provided a surgical grade material with high density, high purity and small grains. Published studies on the outcome of total hip arthroplasty performed with this new generation of implants showed high survivorship especially in young and active patients, with survival rates free of revision of 90.8% to 97.4% at ten years. However, concern remains over ceramic liner fracture and squeaking, which has been noted recently with increasing prevalence. This review will discuss the current knowledge on the use of alumina-on-alumina bearings. PMID:21191579

  2. Study of Mechanical Properties and Fracture Mode of Alumina-Silicon Carbide Nanocomposites

    NASA Astrophysics Data System (ADS)

    Rahimnezhad Yazdi, A.; Baharvandi, H. R.; Abdizadeh, H.; Ehsani, N.

    In this study Al2O3-SiC nanocomposites have been fabricated by mixing of alumina and silicon carbide nano powders, followed by hot pressing at 1700°C. The mechanical properties and fracture mode of Al2O3-SiC nanocomposites containing different volume fractions (5, 10 and 15%) of nano scale SiC particles were investigated and compared with those of alumina. Al2O3-SiC powders were prepared by planetary milling in isopropanol. Fracture mode of specimens was investigated by means of scanning electron microscopy. Nanocomposites were tougher than alumina when they were hot pressed at the same temperature, and the values of nanocomposite's flexural strength and hardness were higher than those of alumina. Flexural strength, hardness and fracture toughness of the nanocomposites increase by increasing the volume percent of SiC up to 10% and then decrease slightly. The Scanning electron microscopy observations showed that fracture mode changes from intergranular for alumina to transgranular for nanocomposites. Finally X-ray diffraction analysis couldn't detect any chemical reactions between Al2O3 and SiC particles.

  3. Enhanced gas separation factors of microporous polymer constrained in the channels of anodic alumina membranes

    NASA Astrophysics Data System (ADS)

    Chernova, Ekaterina; Petukhov, Dmitrii; Boytsova, Olga; Alentiev, Alexander; Budd, Peter; Yampolskii, Yuri; Eliseev, Andrei

    2016-08-01

    New composite membranes based on porous anodic alumina films and polymer of intrinsic microporosity (PIM-1) have been prepared using a spin-coating technique. According to scanning electron microscopy, partial penetration of polymer into the pores of alumina supports takes place giving rise to selective polymeric layers with fiber-like microstructure. Geometric confinement of rigid PIM-1 in the channels of anodic alumina causes reduction of small-scale mobility in polymeric chains. As a result, transport of permanent gases, such as CH4, becomes significantly hindered across composite membranes. Contrary, the transport of condensable gases (CO2, С4H10), did not significantly suffer from the confinement due to high solubility in the polymer matrix. This strategy enables enhancement of selectivity towards CO2 and C4H10 without significant loss of the membrane performance and seems to be prospective for drain and sweetening of natural gas.

  4. Enhanced gas separation factors of microporous polymer constrained in the channels of anodic alumina membranes.

    PubMed

    Chernova, Ekaterina; Petukhov, Dmitrii; Boytsova, Olga; Alentiev, Alexander; Budd, Peter; Yampolskii, Yuri; Eliseev, Andrei

    2016-01-01

    New composite membranes based on porous anodic alumina films and polymer of intrinsic microporosity (PIM-1) have been prepared using a spin-coating technique. According to scanning electron microscopy, partial penetration of polymer into the pores of alumina supports takes place giving rise to selective polymeric layers with fiber-like microstructure. Geometric confinement of rigid PIM-1 in the channels of anodic alumina causes reduction of small-scale mobility in polymeric chains. As a result, transport of permanent gases, such as CH4, becomes significantly hindered across composite membranes. Contrary, the transport of condensable gases (CO2, С4H10), did not significantly suffer from the confinement due to high solubility in the polymer matrix. This strategy enables enhancement of selectivity towards CO2 and C4H10 without significant loss of the membrane performance and seems to be prospective for drain and sweetening of natural gas. PMID:27498607

  5. Enhanced gas separation factors of microporous polymer constrained in the channels of anodic alumina membranes

    PubMed Central

    Chernova, Ekaterina; Petukhov, Dmitrii; Boytsova, Olga; Alentiev, Alexander; Budd, Peter; Yampolskii, Yuri; Eliseev, Andrei

    2016-01-01

    New composite membranes based on porous anodic alumina films and polymer of intrinsic microporosity (PIM-1) have been prepared using a spin-coating technique. According to scanning electron microscopy, partial penetration of polymer into the pores of alumina supports takes place giving rise to selective polymeric layers with fiber-like microstructure. Geometric confinement of rigid PIM-1 in the channels of anodic alumina causes reduction of small-scale mobility in polymeric chains. As a result, transport of permanent gases, such as CH4, becomes significantly hindered across composite membranes. Contrary, the transport of condensable gases (CO2, С4H10), did not significantly suffer from the confinement due to high solubility in the polymer matrix. This strategy enables enhancement of selectivity towards CO2 and C4H10 without significant loss of the membrane performance and seems to be prospective for drain and sweetening of natural gas. PMID:27498607

  6. Evaluation of Alumina-Forming Austenitic Foil for Advanced Recuperators

    SciTech Connect

    Pint, Bruce A; Brady, Michael P; Yamamoto, Yukinori; Santella, Michael L; Maziasz, Philip J; Matthews, Wendy

    2011-01-01

    A corrosion- and creep-resistant austenitic stainless steel has been developed for advanced recuperator applications. By optimizing the Al and Cr contents, the alloy is fully austenitic for creep strength while allowing the formation of a chemically stable external alumina scale at temperatures up to 900 C. An alumina scale eliminates long-term problems with the formation of volatile Cr oxy-hydroxides in the presence of water vapor in exhaust gas. As a first step in producing foil for primary surface recuperators, three commercially cast heats have been rolled to 100 m thick foil in the laboratory to evaluate performance in creep and oxidation testing. Results from initial creep testing are presented at 675 C and 750 C, showing excellent creep strength compared with other candidate foil materials. Laboratory exposures in humid air at 650 800 C have shown acceptable oxidation resistance. A similar oxidation behavior was observed for sheet specimens of these alloys exposed in a modified 65 kW microturbine for 2871 h. One composition that showed superior creep and oxidation resistance has been selected for the preparation of a commercial batch of foil. DOI: 10.1115/1.4002827

  7. Dielectric Performance of a High Purity HTCC Alumina at High Temperatures - a Comparison Study with Other Polycrystalline Alumina

    NASA Technical Reports Server (NTRS)

    Chen, Liangyu

    2014-01-01

    A very high purity (99.99+%) high temperature co-fired ceramic (HTCC) alumina has recently become commercially available. The raw material of this HTCC alumina is very different from conventional HTCC alumina, and more importantly there is no glass additive in this alumina material for co-firing processing. Previously, selected HTCC and LTCC (low temperature co-fired ceramic) alumina materials were evaluated at high temperatures as dielectric and compared to a regularly sintered 96% polycrystalline alumina (96% Al2O3), where 96% alumina was used as the benchmark. A prototype packaging system based on regular 96% alumina with Au thickfilm metallization successfully facilitated long term testing of high temperature silicon carbide (SiC) electronic devices for over 10,000 hours at 500 C. In order to evaluate this new high purity HTCC alumina for possible high temperature packaging applications, the dielectric properties of this HTCC alumina substrate were measured and compared with those of 96% alumina and a previously tested LTCC alumina from room temperature to 550 C at frequencies of 120 Hz, 1 KHz, 10 KHz, 100 KHz, and 1 MHz. A parallel-plate capacitive device with dielectric of the HTCC alumina and precious metal electrodes were used for measurements of the dielectric constant and dielectric loss of the co-fired alumina material in the temperature and frequency ranges. The capacitance and AC parallel conductance of the capacitive device were directly measured by an AC impedance meter, and the dielectric constant and parallel AC conductivity of the dielectric were calculated from the capacitance and conductance measurement results. The temperature and frequency dependent dielectric constant, AC conductivity, and dissipation factor of the HTCC alumina substrate are presented and compared to those of 96% alumina and a selected LTCC alumina. Other technical advantages of this new co-fired material for possible high packaging applications are also discussed.

  8. Long-term results of alumina-on-alumina hip arthroplasty for osteonecrosis.

    PubMed

    Nich, Christophe; Sariali, El-Hadi; Sari Ali, El-Hadi; Hannouche, Didier; Nizard, Rémy; Witvoet, Jacques; Sedel, Laurent; Bizot, Pascal

    2003-12-01

    Alumina-on-alumina bearings in THR may, in theory, provide an effective answer to osteolysis in young patients with ON of the femoral head. The purpose of this retrospective study was to report the long-term results of a series of 52 consecutive alumina THAs (41 patients) done for ON. The mean age of the patients at surgery was 41 years (range, 22-79 years). Cemented femoral stems with a 32-mm alumina head were used. Plain alumina cups were used and were either cemented (39 hips) or press-fit (13 hips). No patients were lost to followup. Sixteen hips have been revised. Aseptic loosening of the socket was the main cause of failure. At an average 16-year followup (range, 11-23.65 years), 26 hips were rated excellent and one hip was rated good. No osteolysis was observed and wear was undetectable. If revision for aseptic loosening was the end point, the rate of survival was 88.5% at 10 years for the socket and 100% at 10 years for the stem. With the alumina-on-alumina hip replacement done for ON, absence of osteolysis can be expected for as many as 24 years after the operation. New methods of socket fixation now are being explored. PMID:14646707

  9. Characterization of vitrified ICPP alumina waste calcine

    SciTech Connect

    Cole, H.S.; Brotzman, J.R.; Simpson, G.G.

    1980-08-01

    The properties of one borosilicate and two borophosphate glasses previously developed to vitrify an ICPP alumina nuclear waste calcine are determined. Based on melt viscosity at 1100/sup 0/C and leach rate, the maximum permissible calcine contents in the borophosphate and borosilicate formulations are 26 and 16 mol%, respectively. Glasses containing lesser amounts of calcine do not develop crystalline compounds upon annealing. Based upon the same viscosity and leach rate criteria, 40 wt % CaO or zirconia calcine can be substituted for alumina calcine in the borophosphate glasses. Ten wt % of either additive can be substituted for alumina calcine in the borosilicate glass. Minor modifications of the alkali or cupric oxide content in the borophosphate glasses does not alter glass characteristics.

  10. Towards detectors for next generation spallation neutron sources

    NASA Astrophysics Data System (ADS)

    Gebauer, B.

    2004-12-01

    Neutron scattering and diffraction methods are of utmost importance for probing the structure and dynamics of condensed matter at an atomic, molecular and mesoscopic level. However, today's experiments, using either wavelength-selected cw beams from steady-state reactor or spallation sources or, on the other hand, comparatively weak pulsed spallation source beams (with the exception of the pulsed IBR-2 reactor in Dubna), suffer from relatively low source strengths, e.g. compared to synchrotron-radiation investigations. Therefore, neutron scattering methods can greatly benefit from next generation pulsed spallation neutron sources with 1-10 MW average proton beam power, which will allow analyzing wavelengths by time-of-flight (TOF) and thus utilizing in an experiment simultaneously a large fraction of the full wavelength band. However, the improved instantaneous flux will pose great challenges on the detection systems, since for instance for ESS, the strongest of the projected sources, the peak thermal neutron flux will be higher by nearly two orders of magnitude than at the presently strongest sources. Owing to current improvements in neutron optics and spectrometer design, the fluxes impinging on the samples will be further enhanced by another factor 5-10; however, this will be compensated for by the tendency to investigate smaller samples becoming accessible due to smaller foci and higher beam fluxes. Hence, thermal neutron detectors with up to two orders of magnitude higher peak count rate capacity in conjunction with microsecond TOF and for some applications sub-millimeter position resolutions are required, in addition to other characteristics like e.g. high long-term stability and low sensitivity to photon background. In this review article an overview will be given on the current state-of-the-art and on currently investigated novel solutions for thermal neutron detectors for very high rate and resolution time-resolved experiments, comprising silicon

  11. Fourier transform infrared photoacoustic spectroscopy of pyridine adsorbed on silica-alumina and. gamma. -alumina

    SciTech Connect

    Riseman, S.M.; Massoth, F.E.; Dhar, G.M.; Eyring, E.M.

    1982-05-13

    Relative numbers of Bronsted acid to Lewis acid sites on silica-alumina have been determined photoacoustically by an infrared analysis of chemisorbed pyridine compared to similar adsorption of ..gamma..-alumina that has only Lewis sites. Results are similar to those obtained by earlier IR transmission studies that suggested the use of framework vibrations of silica as an internal reference standard. The 20% coverage of the silica-alumina surface by pyridine adsorbed at Bronsted sites found photoacoustically is in good agreement with a previous value of 17% estimated from transmission spectroscopic data. Reproducibility of the photoacoustic measurements is excellent.

  12. SPALLATION NEUTRON SOURCE RING-DESIGN AND CONSTRUCTION SUMMARY.

    SciTech Connect

    WEI,J.

    2005-05-16

    After six years, the delivery of components for the Spallation Neutron Source (SNS) accumulator ring (AR) and the transport lines was completed in Spring 2005. Designed to deliver 1.5 MW beam power (1.5 x 10{sup 14} protons of 1 GeV kinetic energy at a repetition rate of 60 Hz), stringent measures were implemented in the fabrication, test, and assembly to ensure the quality of the accelerator systems. This paper summarizes the design, R&D, and construction of the ring and transport systems.

  13. Emittance characterization of the spallation neutron source H- injector

    NASA Astrophysics Data System (ADS)

    Han, B. X.; Stockli, M. P.; Welton, R. F.; Murray, S. N., Jr.; Pennisi, T. R.; Santana, M.

    2013-02-01

    The H- injector for the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory consists of a RF H- ion source and a compact electrostatic low-energy beam transport (LEBT) section. Up to 5 ion sources and up to 4 LEBT assemblies are alternated for the SNS beam operations. The beam current and emittance of the H- beam exiting the LEBT were characterized on the test-stand for different sources and LEBT assemblies in order to understand and minimize their performance variations.

  14. Beginnings of remote handling at the RAL Spallation Neutron Source

    SciTech Connect

    Liska, D.J.; Hirst, J.

    1985-01-01

    Expenditure of funds and resources for remote maintenance systems traditionally are delayed until late in an accelerator's development. However, simple remote-surveillance equipment can be included early in facility planning to set the stage for future remote-handling needs and to identify appropriate personnel. Some basic equipment developed in the UK at the Spallation Neutron Source (SNS) that serves this function and that has been used to monitor beam loss during commissioning is described. A photograph of this equipment, positioned over the extractor septum magnet, is shown. This method can serve as a pattern approach to the problem of initiating remote-handling activities in other facilities.

  15. VESPA: The vibrational spectrometer for the European Spallation Source

    NASA Astrophysics Data System (ADS)

    Fedrigo, Anna; Colognesi, Daniele; Bertelsen, Mads; Hartl, Monika; Lefmann, Kim; Deen, Pascale P.; Strobl, Markus; Grazzi, Francesco; Zoppi, Marco

    2016-06-01

    VESPA, Vibrational Excitation Spectrometer with Pyrolytic-graphite Analysers, aims to probe molecular excitations via inelastic neutron scattering. It is a thermal high resolution inverted geometry time-of-flight instrument designed to maximise the use of the long pulse of the European Spallation Source. The wavelength frame multiplication technique was applied to provide simultaneously a broad dynamic range (about 0-500 meV) while a system of optical blind choppers allows to trade flux for energy resolution. Thanks to its high flux, VESPA will allow the investigation of dynamical and in situ experiments in physical chemistry. Here we describe the design parameters and the corresponding McStas simulations.

  16. Spallation neutron source target station design, development, and commissioning

    NASA Astrophysics Data System (ADS)

    Haines, J. R.; McManamy, T. J.; Gabriel, T. A.; Battle, R. E.; Chipley, K. K.; Crabtree, J. A.; Jacobs, L. L.; Lousteau, D. C.; Rennich, M. J.; Riemer, B. W.

    2014-11-01

    The spallation neutron source target station is designed to safely, reliably, and efficiently convert a 1 GeV beam of protons to a high flux of about 1 meV neutrons that are available at 24 neutron scattering instrument beam lines. Research and development findings, design requirements, design description, initial checkout testing, and results from early operation with beam are discussed for each of the primary target subsystems, including the mercury target, neutron moderators and reflector, surrounding vessels and shielding, utilities, remote handling equipment, and instrumentation and controls. Future plans for the mercury target development program are also briefly discussed.

  17. Study of accelerator neutrino detection at a spallation source

    NASA Astrophysics Data System (ADS)

    Huang, Ming-Yang

    2016-06-01

    We study the detection of accelerator neutrinos produced at the China Spallation Neutron Source (CSNS). Using the code FLUKA, we have simulated the production of neutrinos in a proton beam on a tungsten target and obtained the yield efficiency, numerical flux, and average energy of different flavors of neutrinos. Furthermore, detection of these accelerator neutrinos is investigated in two reaction channels: neutrino-electron reactions and neutrino-carbon reactions. The expected numbers of different flavors of neutrinos have also been calculated. Supported by National Natural Science Foundation of China (11205185, 11175020)

  18. Optical model methods of predicting nuclide production from spallation reactions

    NASA Technical Reports Server (NTRS)

    Ramsey, C. R.; Townsend, L. W.; Tripathi, R. K.; Cucinotta, F. A.; Wilson, J. W. (Principal Investigator)

    1998-01-01

    Quantum mechanical optical model methods for calculating isotope production cross sections from the spallation of heavy nuclei by high-energy protons are developed from a modified abrasion-ablation collision formalism. The abrasion step is treated quantum-mechanically as a knockout process which leaves the residual prefragment nucleus in an excited state. In ablation the prefragment deexcites to produce the final fragment. The excitation energies of the prefragments are estimated from a combination of liquid drop and frictional-spectator interaction considerations. Estimates of elemental and isotopic production cross sections are in good agreement with recently published cross section measurements.

  19. POWER SUPPLY CONTROL FOR THE SPALLATION NEUTRON SOURCE.

    SciTech Connect

    LAMBIASE, R.F.; OERTER, B.; SMITH, J.

    2000-06-30

    Brookhaven National Laboratory is currently constructing an accumulator ring as part of a six laboratory collaboration to build the Spallation Neutron Source (SNS) that will be located in Oak Ridge, Tennessee. Control of the power supplies will be implemented using a simple integrated system that provides all functions (setpoint, readback, control and status) with a single board at the power converter. Communication between the power supply interface and the VME control card is through a pair of fibers that also provides electrical isolation. This paper describes the power supply control system and it's impact on the SNS.

  20. AN ALTERNATIVE LATTICE FOR THE SPALLATION NEUTRON SOURCE ACCUMULATOR RING.

    SciTech Connect

    GARDNER,C.J.; LEE,Y.Y.; TSOUPAS,N.; WEI,J.

    1999-03-29

    As a key component of the Spallation Neutron Source (SNS) Project, the Accumulator Ring will collect the proton beam from the SNS LINAC at an intensity of 2 x 10{sup 14} per pulse at 60 Hz for a total power of 2 MW, exceeding present performance value of existing facilities. Requirements of minimum beam loss for hands-on maintenance and flexibility for future upgrade are essential for the lattice design. In this paper, we study an alternative lattice emphasizing various injection schemes and flexibility for future upgrade. Working points, sextupole families for chromaticity control, and alternate extraction schemes are also considered.

  1. Evaluation of mechanical properties and biological response of an alumina-forming Ni-free ferritic alloy.

    PubMed

    González-Carrasco, J L; Ciapetti, G; Montealegre, M A; Pagani, S; Chao, J; Baldini, N

    2005-06-01

    PM 2000 is a Ni-free oxide dispersion strengthened Fe-20Cr-5Al alloy able to develop a fine, dense and tightly adherent alpha-alumina scale during high-temperature oxidation. Despite the high temperature involved during thermal oxidation (1100 degrees C), microstructural changes in the candidate material, a hot rolled product, hardly occurs. Consequently, the good mechanical properties of the as-received material are not significantly affected. Moreover, due to the high compressive residual stresses at the alumina scale, an increase in the fatigue limit from 500 to 530 MPa is observed. Such stresses also account for the high capability of the coating/metal system to withstand more than 1% tensile deformation without cracking. The biocompatibility of the alloy was assessed in comparison to commercial alumina. Saos-2 osteoblast-like cells were either challenged with PM 2000 particles, or seeded onto PM 2000 (with and without scale) solid samples. Viability, growth, and ALP release from cells were assessed after 3 or 7 days, while mineralization was checked at 18 days. This study has demonstrated that PM 2000 with and without scale are capable of supporting in vitro growth and function of osteoblast-like cells over a period of 18 days. Results from this study suggest that the resulting alumina/alloy system combines the good mechanical properties of the alloy with the superior biocompatibility of the alpha-alumina, for which there is very good clinical experience. PMID:15626434

  2. Workshop: Research and development plans for high power spallation neutron testing at BNL

    SciTech Connect

    1996-08-05

    This report consists of vugraphs from presentations at the meeting. The papers covered the following topics: (1) APS as a proton source; (2) target status for NSNS (National Spallation Neutron Source); (3) spallation neutron source in Japan; (4) liquid LiBi flow loop; and (5) research and development plans for high power tests at the AGS.

  3. Laser Ablation of Alumina in Water

    SciTech Connect

    Musaev, O.; Midgley, A; Wrobel, J; Kruger, M

    2010-01-01

    Bulk {alpha}-alumina immersed in distilled water was ablated by pulsed UV laser radiation. The resulting colloidal solution contained micron and submicron size particles. X-ray diffraction and Raman spectra of the ablated and original material are similar. Hence, most of the ablated material is {alpha}-alumina. From transmission electron microscope images, most of the submicron and all of the micron-sized particles have sharp edges and do not have spherical shapes, indicating that the dominant ablation mechanism is due to crack propagation. Some spherical particles of diameter less than 100 nm are observed, indicating that they were formed from the liquid state.

  4. Chlorination of alumina in kaolinitic clay

    NASA Astrophysics Data System (ADS)

    Grob, B.; Richarz, W.

    1984-09-01

    The chlorination of alumina in kaolinitic clay with Cl2 and CO gas mixtures was studied gravimetrically. The effects of the calcination method and of NaCl addition on the reactivity of the clay were examined. Fast reaction rates were achieved only with samples previously exposed to a sulfating treatment. Optimum conditions, with maximum yield and selectivity to A1C13 and minimum SiO2 conversion, were found between 770 and 970 K. At higher temperatures the SiCl4 formed poisons the reactive alumina surface by selective chemisorption with a marked decrease of the reaction rate.

  5. Nanomechanical humidity detection through porous alumina cantilevers

    PubMed Central

    Klimenko, Alexey; Lebedev, Vasiliy; Lukashin, Alexey; Eliseev, Andrey

    2015-01-01

    Summary We present here the behavior of the resonance frequency of porous anodic alumina cantilever arrays during water vapor adsorption and emphasize their possible use in the micromechanical sensing of humidity levels at least in the range of 10–22%. The sensitivity of porous anodic aluminium oxide cantilevers (Δf/Δm) and the humidity sensitivity equal about 56 Hz/pg and about 100 Hz/%, respectively. The approach presented here for the design of anodic alumina cantilever arrays by the combination of anodic oxidation and photolithography enables easy control over porosity, surface area, geometric and mechanical characteristics of the cantilever arrays for micromechanical sensing. PMID:26199836

  6. Structural transformations in reactively sputtered alumina films

    SciTech Connect

    Nayar, P. Khanna, A.

    2014-04-24

    Thin films of amorphous alumina of thickness ∼350 nm were prepared on silicon wafer by DC cathode reactive sputtering. The effects of thermal annealing on the structural properties were investigated at annealing temperatures of 600°C, 800°C, 1100°C and 1220°C. X-ray diffraction showed that crystallization starts at 800°C and produces δ and θ alumina phases, the latter phase grows with heat treatment and the film was predominantly δ-phase with small amount of a-phase after annealing at 1220°C. AFM studies found that the surface of thin films smoothened upon crystallization.

  7. 40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Siloxane modified alumina... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this...

  8. 21 CFR 73.1010 - Alumina (dried aluminum hydroxide).

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 1 2013-04-01 2013-04-01 false Alumina (dried aluminum hydroxide). 73.1010... GENERAL LISTING OF COLOR ADDITIVES EXEMPT FROM CERTIFICATION Drugs § 73.1010 Alumina (dried aluminum hydroxide). (a) Identity. (1) The color additive alumina (dried aluminum hydroxide) is a white,...

  9. 21 CFR 73.1010 - Alumina (dried aluminum hydroxide).

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 1 2012-04-01 2012-04-01 false Alumina (dried aluminum hydroxide). 73.1010... GENERAL LISTING OF COLOR ADDITIVES EXEMPT FROM CERTIFICATION Drugs § 73.1010 Alumina (dried aluminum hydroxide). (a) Identity. (1) The color additive alumina (dried aluminum hydroxide) is a white,...

  10. 21 CFR 73.1010 - Alumina (dried aluminum hydroxide).

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Alumina (dried aluminum hydroxide). 73.1010... GENERAL LISTING OF COLOR ADDITIVES EXEMPT FROM CERTIFICATION Drugs § 73.1010 Alumina (dried aluminum hydroxide). (a) Identity. (1) The color additive alumina (dried aluminum hydroxide) is a white,...

  11. 21 CFR 73.1010 - Alumina (dried aluminum hydroxide).

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 1 2011-04-01 2011-04-01 false Alumina (dried aluminum hydroxide). 73.1010... GENERAL LISTING OF COLOR ADDITIVES EXEMPT FROM CERTIFICATION Drugs § 73.1010 Alumina (dried aluminum hydroxide). (a) Identity. (1) The color additive alumina (dried aluminum hydroxide) is a white,...

  12. 21 CFR 73.1010 - Alumina (dried aluminum hydroxide).

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 1 2014-04-01 2014-04-01 false Alumina (dried aluminum hydroxide). 73.1010... GENERAL LISTING OF COLOR ADDITIVES EXEMPT FROM CERTIFICATION Drugs § 73.1010 Alumina (dried aluminum hydroxide). (a) Identity. (1) The color additive alumina (dried aluminum hydroxide) is a white,...

  13. 40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Siloxane modified alumina... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this...

  14. 40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Siloxane modified alumina... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this...

  15. REMOVING RADIUM FROM WATER BY PLAIN AND TREATED ACTIVATED ALUMINA

    EPA Science Inventory

    The research determined the feasibility of using BaSO4-impregnated activated alumina and plain activated alumina for radium removal from groundwater by fixed-bed adsorption. The major factors influencing radium adsorption onto the two types of alumina were identified. The radium ...

  16. The effects of water vapor on the oxidation behavior of alumina forming austenitic stainless steels

    DOE PAGESBeta

    Yanar, N. M.; Lutz, B. S.; Garcia-Fresnillo, L.; Brady, Michael P.; Meier, G. H.

    2015-08-19

    The isothermal oxidation behavior of three alumina forming austenitic (AFA) stainless steels with varying composition was studied at 650 and 800 °C in dry air and gases which contained water vapor. The AFA alloys exhibited better oxidation resistance than a “good chromia former” at 650 °C, particularly in H2O-containing atmospheres by virtue of alumina-scale formation. Although the AFA alloys were more resistant than chromia formers, their oxidation resistance was degraded at 650 °C in the presence of water vapor. In dry air the AFA alloys formed, thin continuous alumina scales, whereas in Ar–4%H2–3%H2O the areas of continuous alumina were reducedmore » and Fe oxide-rich nodules and regions of Cr, Mn-rich oxides formed. In some regions internal oxidation of the aluminum occurred in the H2O-containing gas. The alloy OC8 had slightly better resistance than OC4 or OC5 in this atmosphere. The alumina-forming capability of the AFA alloys decreases with increasing temperature and, at 800 °C, they are borderline alumina formers, even in dry air. The oxidation resistance of all three alloys was degraded at 800 °C in atmospheres, which contained water vapor (Air–10%H2O, Ar–3%H2O and Ar–4%H2–3%H2O). The areas, which formed continuous alumina, were reduced in these atmospheres and areas of internal oxidation occurred. However, as a result of the borderline alumina-forming capability of the AFA alloys it was not possible to determine which of the H2O-containing atmospheres was more severe or to rank the alloys in terms of their performance. The experimental results indicate that the initial microstructure of the AFA alloys also plays a role in their oxidation performance. Less protective oxides formed at 800 °C when alloy OC8 was equilibrated before exposure rather than being exposed in the as-processed condition. As a result, the reason for this is the presence of different phases in the bulk of the two specimens.« less

  17. The effects of water vapor on the oxidation behavior of alumina forming austenitic stainless steels

    SciTech Connect

    Yanar, N. M.; Lutz, B. S.; Garcia-Fresnillo, L.; Brady, Michael P.; Meier, G. H.

    2015-08-19

    The isothermal oxidation behavior of three alumina forming austenitic (AFA) stainless steels with varying composition was studied at 650 and 800 °C in dry air and gases which contained water vapor. The AFA alloys exhibited better oxidation resistance than a “good chromia former” at 650 °C, particularly in H2O-containing atmospheres by virtue of alumina-scale formation. Although the AFA alloys were more resistant than chromia formers, their oxidation resistance was degraded at 650 °C in the presence of water vapor. In dry air the AFA alloys formed, thin continuous alumina scales, whereas in Ar–4%H2–3%H2O the areas of continuous alumina were reduced and Fe oxide-rich nodules and regions of Cr, Mn-rich oxides formed. In some regions internal oxidation of the aluminum occurred in the H2O-containing gas. The alloy OC8 had slightly better resistance than OC4 or OC5 in this atmosphere. The alumina-forming capability of the AFA alloys decreases with increasing temperature and, at 800 °C, they are borderline alumina formers, even in dry air. The oxidation resistance of all three alloys was degraded at 800 °C in atmospheres, which contained water vapor (Air–10%H2O, Ar–3%H2O and Ar–4%H2–3%H2O). The areas, which formed continuous alumina, were reduced in these atmospheres and areas of internal oxidation occurred. However, as a result of the borderline alumina-forming capability of the AFA alloys it was not possible to determine which of the H2O-containing atmospheres was more severe or to rank the alloys in terms of their performance. The experimental results indicate that the initial microstructure of the AFA alloys also plays a role in their oxidation performance. Less protective oxides formed at 800 °C when alloy OC8 was equilibrated before exposure rather than being exposed in the as-processed condition. As a result, the reason for this is the presence of different

  18. Dielectric breakdown of polycrystalline alumina: A weakest-link failure analysis

    NASA Astrophysics Data System (ADS)

    Block, Benjamin

    The effects of varying electrode geometry (ball and ring) and size (radius), dielectric media (castor oil and DialaRTM oil), specimen thickness, and concentration of defects on the dielectric breakdown strength of commercial-grade alumina and high-purity fine-grained (HPFG) alumina were investigated. The breakdown strength was expressed in terms of the maximum electric field in the ceramic at the breakdown voltage calculated by finite element analysis (FEA). The breakdown strength decreased systematically with increasing electrode radius and specimen thickness. The breakdown strength increased with decreasing concentration of defects. The breakdown strength was higher in the Diala RTM oil (dielectric constant, epsilonr = 2.3 +/- 0.12) as compared to the castor oil (epsilonr = 4.59 +/- 0.06). The breakdown strength was higher for the HPFG alumina as compared to the commercial- grade alumina. These effects of the electrode geometry, specimen thickness, concentration of defects, and of the dielectric media were analyzed with a weakest-link failure model employing the Laplace and Weibull distributions for a population of defects in the material. The measured size or scaling effects of the electrodes, specimen thickness, concentration of defects, and of the liquid media on breakdown strength were in better agreement with the Laplace distribution for the population. The measured concentration of surface defects was in good agreement with the concentration of surface defects estimated from the surface area scaling of the breakdown field with the Laplace distribution.

  19. Comparison Between Experiments and Molecular Dynamic Simulations of Spallation Induced by Ultra-Short Laser Shock on Micrometric Tantalum Targets

    NASA Astrophysics Data System (ADS)

    Cuq-Lelandais, J.-P.; Boustie, M.; Soulard, L.; Berthe, L.; Sollier, A.; Bontaz-Carion, J.; Combis, P.; de Rességuier, T.; Lescoute, E.

    2009-12-01

    Shock wave propagation and the spallation within materials induced by laser shock have been investigated for roughly two decades. With the latest laser technologies evolution, one can access to shorter regimes in durations, going below the picosecond range. Shots performed with the LULI 100 TW facility evidence the possibility to obtain spallation in a few microns thick metallic target. Such conditions provide an experimental data layout which may be directly comparable with molecular dynamic simulations reachable to these scales. Molecular dynamic simulations on a single crystal of Tantalum have been performed with the CEA TERA 10 computer. First, the Hugoniot calculated by the equilibrium molecular dynamics has been compared with experimental data to check the potential (EAM) relevance to reproduce the shock wave propagation. Then, large scale simulations on a micrometric target have been performed. We have observed the microscopic ductile damage process, the pore apparition and their time and space evolution. The results are compared with experimental results and classical one-dimensional hydrodynamic simulations.

  20. Oak Ridge Spallation Neutron Source (ORSNS) target station design integration

    SciTech Connect

    McManamy, T.; Booth, R.; Cleaves, J.; Gabriel, T.

    1996-06-01

    The conceptual design for a 1- to 3-MW short pulse spallation source with a liquid mercury target has been started recently. The design tools and methods being developed to define requirements, integrate the work, and provide early cost guidance will be presented with a summary of the current target station design status. The initial design point was selected with performance and cost estimate projections by a systems code. This code was developed recently using cost estimates from the Brookhaven Pulsed Spallation Neutron Source study and experience from the Advanced Neutron Source Project`s conceptual design. It will be updated and improved as the design develops. Performance was characterized by a simplified figure of merit based on a ratio of neutron production to costs. A work breakdown structure was developed, with simplified systems diagrams used to define interfaces and system responsibilities. A risk assessment method was used to identify potential problems, to identify required research and development (R&D), and to aid contingency development. Preliminary 3-D models of the target station are being used to develop remote maintenance concepts and to estimate costs.

  1. Slow neutron leakage spectra from spallation neutron sources

    SciTech Connect

    Das, S.G.; Carpenter, J.M.; Prael, R.E.

    1980-02-01

    An efficient technique is described for Monte Carlo simulation of neutron beam spectra from target-moderator-reflector assemblies typical of pulsed spallation neutron sources. The technique involves the scoring of the transport-theoretical probability that a neutron will emerge from the moderator surface in the direction of interest, at each collision. An angle-biasing probability is also introduced which further enhances efficiency in simple problems. These modifications were introduced into the VIM low energy neutron transport code, representing the spatial and energy distributions of the source neutrons approximately as those of evaporation neutrons generated through the spallation process by protons of various energies. The intensity of slow neutrons leaking from various reflected moderators was studied for various neutron source arrangements. These include computations relating to early measurements on a mockup-assembly, a brief survey of moderator materials and sizes, and a survey of the effects of varying source and moderator configurations with a practical, liquid metal cooled uranium source Wing and slab, i.e., tangential and radial moderator arrangements, and Be vs CH/sub 2/ reflectors are compared. Results are also presented for several complicated geometries which more closely represent realistic arrangements for a practical source, and for a subcritical fission multiplier such as might be driven by an electron linac. An adaptation of the code was developed to enable time dependent calculations, and investigated the effects of the reflector, decoupling and void liner materials on the pulse shape.

  2. Mercury Cavitation Phenomenon in Pulsed Spallation Neutron Sources

    SciTech Connect

    Futakawa, Masatoshi; Naoe, Takashi; Kawai, Masayoshi

    2008-06-24

    Innovative researches will be performed at Materials and Life Science Experimental Facility in J-PARC, in which a mercury target system will be installed as MW-class pulse spallation neutron sources. Proton beams will be injected into mercury target to induce the spallation reaction. At the moment the intense proton beam hits the target, pressure waves are generated in the mercury because of the abrupt heat deposition. The pressure waves interact with the target vessel leading to negative pressure that may cause cavitation along the vessel wall. Localized impacts by micro-jets and/or shock waves which are caused by cavitation bubble collapse impose pitting damage on the vessel wall. The pitting damage which degrades the structural integrity of target vessels is a crucial issue for high power mercury targets. Micro-gas-bubbles injection into mercury may be useful to mitigate the pressure wave and the pitting damage. The visualization of cavitation-bubble and gas-bubble collapse behaviors was carried out by using a high-speed video camera. The differences between them are recognized.

  3. Separation of spallation and terrestrial C-14 in chondrites

    NASA Technical Reports Server (NTRS)

    Cresswell, R. G.; Beukens, R. P.; Rucklidge, J. C.

    1993-01-01

    Weathering products and contamination severely hamper our ability to accurately measure the C-14 spallation component in meteorites, but can give insights into a sample's terrestrial history. A procedure was developed to measure the C-14 in these components using CO and CO2 separations from temperature extractions from 200-500 mg of material. The Bruderheim (L6) chondrite was chosen as a standard following the practice of previous researchers, crosschecked against Peace River (L6), Abee (EH4), and Juvinas (EUC). Low temperature fractions (less than 900 C) give C-14 signatures consistent with a modern terrestrial C-14 source; melt fractions show elevated levels attesting to a spallogenic origin. Higher yields of CO in the melt fraction are less affected by the low levels of experimental contamination than the CO2. This fraction gave a mean CO:CO2 ratio in Bruderheim of 81.6 +/- 7.7; the ratio of the spallation component is 79.8 +/- 8.1. These values suggest equilibrium release of gases on the olivine-silica-pyroxene-iron buffer. This is corroborated by approximately equal release of the two components at 900 C. The chondrites gave an average saturation level of 54.3 +/- 2.9 dpm/kg; the achondrite gave 49.6 +/- 2.0 dpm/kg. No clear correlation with oxygen content is apparent, though shielding effects have yet to be evaluated. A further evaluation of this subject matter is given.

  4. Generic guide concepts for the European Spallation Source

    NASA Astrophysics Data System (ADS)

    Zendler, C.; Martin Rodriguez, D.; Bentley, P. M.

    2015-12-01

    The construction of the European Spallation Source (ESS) faces many challenges from the neutron beam transport point of view: the spallation source is specified as being driven by a 5 MW beam of protons, each with 2 GeV energy, and yet the requirements in instrument background suppression relative to measured signal vary between 10-6 and 10-8. The energetic particles, particularly above 20 MeV, which are expected to be produced in abundance in the target, have to be filtered in order to make the beamlines safe, operational and provide good quality measurements with low background. We present generic neutron guides of short and medium length instruments which are optimised for good performance at minimal cost. Direct line of sight to the source is avoided twice, with either the first point out of line of sight or both being inside the bunker (20 m) to minimise shielding costs. These guide geometries are regarded as a baseline to define standards for instruments to be constructed at ESS. They are used to find commonalities and develop principles and solutions for common problems. Lastly, we report the impact of employing the over-illumination concept to mitigate losses from random misalignment passively, and that over-illumination should be used sparingly in key locations to be effective. For more widespread alignment issues, a more direct, active approach is likely to be needed.

  5. Method of making nanocrystalline alpha alumina

    DOEpatents

    Siegel, Richard W.; Hahn, Horst; Eastman, Jeffrey A.

    1992-01-01

    Method of making selected phases of nanocrystalline ceramic materials. Various methods of controlling the production of nanocrystalline alpha alumina and titanium oxygen phases are described. Control of the gas atmosphere and use of particular oxidation treatments give rise to the ability to control the particular phases provided in the aluminum/oxygen and titanium/oxygen system.

  6. Scales

    MedlinePlus

    Scales are a visible peeling or flaking of outer skin layers. These layers are called the stratum ... Scales may be caused by dry skin, certain inflammatory skin conditions, or infections. Eczema , ringworm , and psoriasis ...

  7. Thermal Conductivity of Alumina-Toughened Zirconia Composites

    NASA Technical Reports Server (NTRS)

    Bansal, Narottam P.; Zhu, Dong-Ming

    2003-01-01

    10-mol% yttria-stabilized zirconia (10YSZ)-alumina composites containing 0 to 30 mol% alumina were fabricated by hot pressing at 1500 C in vacuum. Thermal conductivity of the composites, determined at various temperatures using a steady-state laser heat flux technique, increased with increase in alumina content. Composites containing 0, 5, and 10-mol% alumina did not show any change in thermal conductivity with temperature. However, those containing 20 and 30-mol% alumina showed a decrease in thermal conductivity with increase in temperature. The measured values of thermal conductivity were in good agreement with those calculated from simple rule of mixtures.

  8. Dielectric Performance of High Purity HTCC Alumina at High Temperatures - A Comparison Study with Other Polycrystalline Alumina

    NASA Technical Reports Server (NTRS)

    Chen, Liang-Yu

    2012-01-01

    A very high purity (99.99+) high temperature co-fired ceramic (HTCC) alumina has recently become commercially available. The raw material of this HTCC alumina is very different from conventional HTCC alumina, and more importantly there is no glass additive in this co-fired material. Previously, selected HTCC and LTCC (low temperature co-fired ceramic) alumina materials were evaluated at high temperatures as dielectric and compared to a regularly sintered 96 polycrystalline alumina (96 Al2O3), where 96 alumina was used as the benchmark. A prototype packaging system based on regular 96 alumina with Au thick-film metallization successfully facilitated long term testing of high temperature silicon carbide (SiC) electronic devices for over 10,000 hours at 500C. In order to evaluate this new HTCC alumina for possible high temperature packaging applications, the dielectric properties of this HTCC alumina substrate were measured and compared with those of 96 alumina and a LTCC alumina from room temperature to 550C at frequencies of 120 Hz, 1 KHz, 10 KHz, 100 KHz, and 1 MHz. A parallel-plate capacitive device with dielectric of the HTCC alumina and precious metal electrodes were used for measurements of the dielectric constant and dielectric loss of the co-fired alumina material in the temperature and frequency ranges. The capacitance and AC parallel conductance of the capacitive device were directly measured by an AC impedance meter, and the dielectric constant and parallel AC conductivity of the dielectric were calculated from the capacitance and conductance measurement results. The temperature and frequency dependent dielectric constant, AC conductivity, and dissipation factor of the HTCC alumina substrate are presented and compared to those of 96 alumina. Other technical advantages of this new co-fired material for possible high packaging applications are also discussed.

  9. Study of alumina-trichite reinforcement of a nickel-based matric by means of powder metallurgy

    NASA Technical Reports Server (NTRS)

    Walder, A.; Hivert, A.

    1982-01-01

    Research was conducted on reinforcing nickel based matrices with alumina trichites by using powder metallurgy. Alumina trichites previously coated with nickel are magnetically aligned. The felt obtained is then sintered under a light pressure at a temperature just below the melting point of nickel. The halogenated atmosphere technique makes it possible to incorporate a large number of additive elements such as chromium, titanium, zirconium, tantalum, niobium, aluminum, etc. It does not appear that going from laboratory scale to a semi-industrial scale in production would create any major problems.

  10. Alumina-on-alumina total hip prostheses in patients 40 years of age or younger.

    PubMed

    Bizot, P; Banallec, L; Sedel, L; Nizard, R

    2000-10-01

    To avoid the consequences of polyethylene wear in a high-risk population, 128 alumina-on-alumina total hip arthroplasties have been done in 104 consecutive patients. The maximum age of patients was 40 years. The main preoperative diagnoses were osteonecrosis and sequellae of congenital hip dislocation (71% of the hips). The same titanium alloy cemented stem was implanted in all of the hips. Four types of alumina acetabular component fixations were used: a cemented plain alumina socket (41 hips), a screw-in ring with an alumina insert (22 hips), a press-fit plain alumina socket (32 hips), and a press-fit titanium metal back with an alumina insert (33 hips). Eight patients (11 hips) died during the followup period. Sixteen revisions have been documented, 12 for acetabular aseptic loosening, three for bipolar loosening (two of which were septic), and one for unexplained pain. Eighty-eight hips in 74 patients have been followed up radiologically for 2 to 22 years. Wear was unmeasurable. Four additional sockets showed definite migration. The respective survival rates after 7 years were 94.1% for the cemented cup, 88.8% for the screw-in ring, 95.1% for cementless press-fit plain alumina socket and 94.3% for the metal-back press-fit component. The 10-year survival rate was 90.4% for the cemented socket and 88.8% for the screw-in ring. The 15-year survival rate was 78.9% for the cemented socket. Grafting was the only prognostic factor, with a survival rate of 62.6% after 10 years for the hips with a bone graft and of 90.1% for hips without a graft. The alumina-on-alumina bearing surfaces seem to be a valuable alternative to the standard metal-on-polyethylene system for young patients. However, an improvement in socket fixation is required to lengthen the life span of the prosthesis to match the life expectancy of this demanding population. PMID:11039794

  11. Rheological Properties of Aqueous Nanometric Alumina Suspensions

    SciTech Connect

    Chuanping Li

    2004-12-19

    Colloidal processing is an effective and reliable approach in the fabrication of the advanced ceramic products. Successful colloidal processing of fine ceramic powders requires accurate control of the rheological properties. The accurate control relies on the understanding the influences of various colloidal parameters on the rheological properties. Almost all research done on the rheology paid less attention to the interactions of particle and solvent. However, the interactions of the particles are usually built up through the media in which the particles are suspended. Therefore, interactions of the particle with the media, the adsorbed layers on the particle surface, and chemical and physical properties of media themselves must influence the rheology of the suspension, especially for the dense suspensions containing nanosized particles. Relatively little research work has been reported in this area. This thesis addresses the rheological properties of nanometric alumina aqueous suspensions, and paying more attention to the interactions between particle and solvent, which in turn influence the particle-particle interactions. Dense nanometric alumina aqueous suspensions with low viscosity were achieved by environmentally-benign fructose additives. The rheology of nanometric alumina aqueous suspensions and its variation with the particle volume fraction and concentration of fructose were explored by rheometry. The adsorptions of solute (fructose) and solvent (water) on the nanometric alumina particle surfaces were measured and analyzed by TG/DSC, TOC, and NMR techniques. The mobility of water molecules in the suspensions and its variation with particle volume fractions and fructose additive were determined by the {sup 17}O NMR relaxation method. The interactions between the nanometric alumina particles in water and fructose solutions were investigated by AFM. The results indicated that a large number of water layers were physically bound on the particles' surfaces

  12. Stability domain of alumina thermally grown on Fe-Cr-Al-based model alloys and modified surface layers exposed to oxygen-containing molten Pb

    NASA Astrophysics Data System (ADS)

    Jianu, A.; Fetzer, R.; Weisenburger, A.; Doyle, S.; Bruns, M.; Heinzel, A.; Hosemann, P.; Mueller, G.

    2016-03-01

    The paper gives experimental results concerning the morphology, composition, structure and thickness of the oxide scales grown on Fe-Cr-Al-based bulk alloys during exposure to oxygen-containing molten lead. The results are discussed and compared with former results obtained on Al-containing surface layers, modified by melting with intense pulsed electron beam and exposed to similar conditions. The present and previous results provide the alumina stability domain and also the criterion of the Al/Cr ratio for the formation of a highly protective alumina layer on the surface of Fe-Cr-Al-based alloys and on modified surface layers exposed to molten lead with 10-6 wt.% oxygen at 400-600 °C. The protective oxide scales, grown on alumina-forming Fe-Cr-Al alloys under the given experimental conditions, were transient aluminas, namely, kappa-Al2O3 and theta-Al2O3.

  13. The Spallation Neutron Source Beam Commissioning and Initial Operations

    SciTech Connect

    Henderson, Stuart; Aleksandrov, Alexander V.; Allen, Christopher K.; Assadi, Saeed; Bartoski, Dirk; Blokland, Willem; Casagrande, F.; Campisi, I.; Chu, C.; Cousineau, Sarah M.; Crofford, Mark T.; Danilov, Viatcheslav; Deibele, Craig E.; Dodson, George W.; Feshenko, A.; Galambos, John D.; Han, Baoxi; Hardek, T.; Holmes, Jeffrey A.; Holtkamp, N.; Howell, Matthew P.; Jeon, D.; Kang, Yoon W.; Kasemir, Kay; Kim, Sang-Ho; Kravchuk, L.; Long, Cary D.; McManamy, T.; Pelaia, II, Tom; Piller, Chip; Plum, Michael A.; Pogge, James R.; Purcell, John David; Shea, T.; Shishlo, Andrei P; Sibley, C.; Stockli, Martin P.; Stout, D.; Tanke, E.; Welton, Robert F; Zhang, Y.; Zhukov, Alexander P

    2015-09-01

    The Spallation Neutron Source (SNS) accelerator delivers a one mega-Watt beam to a mercury target to produce neutrons used for neutron scattering materials research. It delivers ~ 1 GeV protons in short (< 1 us) pulses at 60 Hz. At an average power of ~ one mega-Watt, it is the highest-powered pulsed proton accelerator. The accelerator includes the first use of superconducting RF acceleration for a pulsed protons at this energy. The storage ring used to create the short time structure has record peak particle per pulse intensity. Beam commissioning took place in a staged manner during the construction phase of SNS. After the construction, neutron production operations began within a few months, and one mega-Watt operation was achieved within three years. The methods used to commission the beam and the experiences during initial operation are discussed.

  14. BEAM INSTRUMENTATION FOR THE SPALLATION NEUTRON SOURCE RING.

    SciTech Connect

    WITKOVER,R.L.; CAMERON,P.R.; SHEA,T.J.; CONNOLLY,R.C.; KESSELMAN,M.

    1999-03-29

    The Spallation Neutron Source (SNS) will be constructed by a multi-laboratory collaboration with BNL responsible for the transfer lines and ring. [1] The 1 MW beam power necessitates careful monitoring to minimize un-controlled loss. This high beam power will influence the design of the monitors in the high energy beam transport line (HEBT) from linac to ring, in the ring, and in the ring-to-target transfer line (RTBT). The ring instrumentation must cover a 3-decade range of beam intensity during accumulation. Beam loss monitoring will be especially critical since un-controlled beam loss must be kept below 10{sup -4}. A Beam-In-Gap (BIG) monitor is being designed to assure out-of-bucket beam will not be lost in the ring.

  15. SPALLATION NEUTRON SOURCE HIGH-POWER PROTECTION MODULE TEST STAND

    SciTech Connect

    Lee, Sung-Woo; Ball, Jeffrey Allen; Crofford, Mark T; Davidson Jr, Taylor L; Jones, Stacey L; Hardek, Thomas W

    2010-01-01

    The Spallation Neutron Source (SNS) High-Power Protection Module (HPM) provides interlocks and fast shutdown for the radio frequency (RF) system to protect the accelerating structures and high power RF (HPRF) Distribution System. The HPM has required some functional upgrades since the start of beam operations and an upgrade to the HPM test stand was required to support these added features. The HPM test stand currently verifies functionality, RF channel calibration, and measurement of the speed of shutdown to ensure the specifications are met. The upgraded test stand was implemented in a Field Programmable Gate Array (FPGA) to allow for future growth and flexibility. Work is currently progressing on automation of the test stand to better perform the required module calibration schedule.

  16. THE SPALLATION NEUTRON SOURCE CRYOMODULE TEST STAND RF SYSTEM

    SciTech Connect

    Crofford, Mark T; Ball, Jeffrey Allen; Davidson Jr, Taylor L; Hardek, Thomas W; Heidenreich, Dale A; Kasemir, Kay; Kim, Sang-Ho; Kang, Yoon

    2008-01-01

    The Spallation Neutron Source (SNS) has recently commissioned a cryomodule test facility for the repair and testing of the super-conducting radio-frequency (SRF) cavities. This facility utilizes the original 402.5/805 MHz Radio Frequency (RF) Klystron Test Stand as its power source along with dual Low Level RF (LLRF) control systems. One control system is based on the standard SNS Linac LLRF controls with a second system for open-loop only control. The system is designed to allow simultaneous testing of devices in the test cave and other devices which can be tested outside of the enclosure. Initial tests have shown good results; some improvements are yet to be implemented.

  17. STATUS OF THE SPALLATION NEUTRON SOURCE SUPERCONDUCTING RF FACILITIES

    SciTech Connect

    Stout, Daniel S; Assadi, Saeed; Campisi, Isidoro E; Casagrande, Fabio; Crofford, Mark T; DeVan, Bill; Hardek, Thomas W; Henderson, Stuart D; Howell, Matthew P; Kang, Yoon W; Geng, Xiaosong; Stone Jr, William C; Strong, William Herb; Williams, Derrick C; Wright, Paul Alan

    2007-01-01

    The Spallation Neutron Source (SNS) project was completed with only limited superconducting RF (SRF) facilities installed as part of the project. A concerted effort has been initiated to install the infrastructure and equipment necessary to maintain and repair the superconducting Linac, and to support power upgrade research and development (R&D). Installation of a Class10/100/10,000 cleanroom and outfitting of the test cave with RF, vacuum, controls, personnel protection and cryogenics systems is underway. A horizontal cryostat, which can house a helium vessel/cavity and fundamental power coupler for full power, pulsed testing, is being procured. Equipment for cryomodule assembly and disassembly is being procured. This effort, while derived from the experience of the SRF community, will provide a unique high power test capability as well as long term maintenance capabilities. This paper presents the current status and the future plans for the SNS SRF facilities.

  18. CONSTRUCTION STATUS AND ISSUES OF THE SPALLATION NEUTRON SOURCE RING.

    SciTech Connect

    WEI,J.

    2004-07-05

    The Spallation Neutron Source (SNS) ring is designed to accumulate beam pulses of 1.5 x 10{sup 14} protons of 1 GeV kinetic energy at a repetition rate of 60 Hz [1]. At such beam intensity and power, key design challenges include control of beam loss and radio-activation, construction of high-quality large-aperture magnets and power supplies, design of robust injection and extraction systems, minimization of beam-coupling impedances, and mitigation of electron-cloud effects. This paper discusses the status of the ring systems with emphasis on technical challenges and issues, and presents future perspectives towards a next-generation high-intensity facility.

  19. Electron-cloud mitigation in the spallation neutron source ring

    SciTech Connect

    Wei, J.; Blaskiewicz, M.; Brodowski, J.; Cameron, P.; Davino, D.; Fedotov, A.; He, P.; Hseuh, H.; Lee, Y.Y.; Meng, W.; Raparia, D.; Tuozzolo, J.; Zhang, S.Y.; Danilov, V.; Henderson, S.; Furman, M.; Pivi, M.; Macek, R.

    2003-05-01

    The Spallation Neutron Source (SNS) accumulator ring is designed to accumulate, via H- injection, protons of 2 MW beam power at 1 GeV kinetic energy at a repetition rate of 60 Hz [1]. At such beam intensity, electron cloud is expected to be one of the intensity-limiting mechanisms that complicate ring operations. This paper summarizes mitigation strategy adopted in the design, both in suppressing electron-cloud formation and in enhancing Landau damping, including tapered magnetic field and monitoring system for the collection of stripped electrons at injection, TiN coated beam chamber for suppression of the secondary yield, clearing electrodes dedicated for the injection region and parasitic on BPMs around the ring, solenoid windings in the collimation region, and planning of vacuum systems for beam scrubbing upon operation.

  20. Preliminary Numerical and Experimental Analysis of the Spallation Phenomenon

    NASA Technical Reports Server (NTRS)

    Martin, Alexandre; Bailey, Sean C. C.; Panerai, Francesco; Davuluri, Raghava S. C.; Vazsonyi, Alexander R.; Zhang, Huaibao; Lippay, Zachary S.; Mansour, Nagi N.; Inman, Jennifer A.; Bathel, Brett F.; Splinter, Scott C.; Danehy, Paul M.

    2015-01-01

    The spallation phenomenon was studied through numerical analysis using a coupled Lagrangian particle tracking code and a hypersonic aerothermodynamics computational fluid dynamics solver. The results show that carbon emission from spalled particles results in a significant modification of the gas composition of the post shock layer. Preliminary results from a test-campaign at the NASA Langley HYMETS facility are presented. Using an automated image processing of high-speed images, two-dimensional velocity vectors of the spalled particles were calculated. In a 30 second test at 100 W/cm2 of cold-wall heat-flux, more than 1300 particles were detected, with an average velocity of 102 m/s, and most frequent observed velocity of 60 m/s.

  1. Neutronic Design Studies for the National Spallation Neutron Source (NSNS)

    SciTech Connect

    Charlton, LA

    2001-08-01

    Neutronics analyses are now in progress to support initial selection of target system design features, materials, geometry, and component sizes for the proposed Spallation Neutron Source (SNS). Calculations have been performed to determine the neutron, proton, heavy ion, and gamma-ray flux spectra as a function of time, energy, and space for the major components of the target station (target, moderators, reflectors, etc.). These analyses were also performed to establish an initial set of performance characteristics for the neutron source. The methodology, reference performance characteristics, and results of initial optimization studies involving moderator poison plate location, target material performance, reflector performance, moderator position and premoderator performance for the target system are presented in this paper.

  2. The Spallation Neutron Source: A powerful tool for materials research

    SciTech Connect

    Mason, Thom; Anderson, Ian S; Ankner, John Francis; Egami, Takeshi; Ekkebus, Allen E; Herwig, Kenneth W; Hodges, Jason P; Horak, Charlie M; Horton, Linda L; Klose, Frank Richard; Mesecar, Andrew D.; Myles, Dean A A; Ohl, M.; Zhao, Jinkui

    2006-01-01

    When completed in 2006, the Spallation Neutron Source (SNS) will use an accelerator to produce the most intense beams of pulsed neutrons in the world. This unique facility is being built by a collaboration of six US Department of Energy laboratories and will serve a diverse community of users drawn from academia, industry, and government labs. The project continues on schedule and within budget, with commissioning and installation of all systems going well. Installation of 14 state-of-the-art instruments is under way, and design work is being completed for several others. These new instruments will enable inelastic and elastic-scattering measurements across a broad range of science such as condensed-matter physics, chemistry, engineering materials, biology, and beyond. Neutron Science at SNS will be complemented by research opportunities at several other facilities under way at Oak Ridge National Laboratory.

  3. COMMISSIONING OF THE SPALLATION NEUTRON SOURCE ACCELERATOR SYSTEMS

    SciTech Connect

    Plum, Michael A

    2007-01-01

    The Spallation Neutron Source accelerator complex consists of a 2.5 MeV H- front-end injector system, a 186 MeV normal-conducting linear accelerator, a 1 GeV superconducting linear accelerator, an accumulator ring, and associated beam transport lines. The linac was commissioned in five discrete runs, starting in 2002 and completed in 2005. The accumulator ring and associated beam transport lines were commissioned in two runs from January to April 2006. With the completed commissioning of the SNS accelerator, the facility has begun initial low-power operations. In the course of beam commissioning, most beam performance parameters and beam intensity goals have been achieved at low duty factor. A number of beam dynamics measurements have been performed, including emittance evolution, transverse coupling in the ring, beam instability thresholds, and beam distributions on the target. The commissioning results, achieved beam performance and initial operating experience of the SNS will be discussed

  4. Mesoscale polycrystal calculations of damage in spallation in metals

    SciTech Connect

    Tonks, Davis L; Bingert, John F; Livescu, Veronica; Luo, Shengnian; Bronkhorst, C A

    2010-01-01

    The goal of this project is to produce a damage model for spallation in metals informed by the polycrystalline grain structure at the mesoscale. Earlier damage models addressed the continuwn macroscale in which these effects were averaged out. In this work we focus on cross sections from recovered samples examined with EBSD (electron backscattered diffraction), which reveal crystal grain orientations and voids. We seek to understand the loading histories of specific sample regions by meshing up the crystal grain structure of these regions and simulating the stress, strain, and damage histories in our hydro code, FLAG. The stresses and strain histories are the fundamental drivers of damage and must be calculated. The calculated final damage structures are compared with those from the recovered samples to validate the simulations.

  5. Electron Cloud Mitigation in the Spallation Neutron Source Ring

    SciTech Connect

    Wei, J.; Blaskiewicz, Michael; Brodowski, J.; Cameron, P.; Davino, Daniele; Fedotov, A.; He, P.; Hseuh, H.; Lee, Y.Y.; Ludewig, H.; Meng, W.; Raparia, D.; Tuozzolo, J.; Zhang, S.Y.; Catalan-Lasheras, N.; Macek, R.J.; Furman, Miguel A.; Aleksandrov, A.; Cousineau, S.; Danilov, V.; Henderson, S.; /Brookhaven /CERN /LANL, Ctr. for Nonlinear Studies /LBL, Berkeley /Oak Ridge /SLAC

    2008-03-17

    The Spallation Neutron Source (SNS) accumulator ring is designed to accumulate, via H{sup -} injection, protons of 2 MW beam power at 1 GeV kinetic energy at a repetition rate of 60 Hz [1]. At such beam intensity, electron-cloud is expected to be one of the intensity-limiting mechanisms that complicate ring operations. This paper summarizes mitigation strategy adopted in the design, both in suppressing electron-cloud formation and in enhancing Landau damping, including tapered magnetic field and monitoring system for the collection of stripped electrons at injection, TiN coated beam chamber for suppression of the secondary yield, clearing electrodes dedicated for the injection region and parasitic on BPMs around the ring, solenoid windings in the collimation region, and planning of vacuum systems for beam scrubbing upon operation.

  6. Spallation neutron source cryomodule heat loads and thermal design

    SciTech Connect

    E. F. Daly; V. Ganni; C. H. Rode; W. J. Schneider; K. M. Wilson; M. A. Wiseman

    2002-05-10

    When complete, the Spallation Neutron Source (SNS) will provide a 1 GeV, 2 MW beam for experiments. One portion of the machine's linac consists of over 80 Superconducting Radio Frequency (SRF) 805 MHz cavities housed in a minimum of 23 cryomodules operating at a saturation temperature of 2.1 K. Minimization of the total heat load is critical to machine performance and for efficient operation of the system. The total heat load of the cryomodules consists of the fixed static load and the dynamic load, which is proportional to the cavity performance. The helium refrigerator supports mainly the cryomodule loads and to a lesser extent the distribution system loads. The estimated heat loads and calculated thermal performance are discussed along with two unique features of this design: the helium heat exchanger housed in the cryomodule return end can and the helium gas cooled fundamental power coupler.

  7. The Fundamental Neutron Physics Beamline at the Spallation Neutron Source

    PubMed Central

    Greene, Geoffrey; Cianciolo, Vince; Koehler, Paul; Allen, Richard; Snow, William Michael; Huffman, Paul; Gould, Chris; Bowman, David; Cooper, Martin; Doyle, John

    2005-01-01

    The Spallation Neutron Source (SNS), currently under construction at Oak Ridge National Laboratory with an anticipated start-up in early 2006, will provide the most intense pulsed beams of cold neutrons in the world. At a projected power of 1.4 MW, the time averaged fluxes and fluences of the SNS will approach those of high flux reactors. One of the flight paths on the cold, coupled moderator will be devoted to fundamental neutron physics. The fundamental neutron physics beamline is anticipated to include two beam-lines; a broad band cold beam, and a monochromatic beam of 0.89 nm neutrons for ultracold neutron (UCN) experiments. The fundamental neutron physics beamline will be operated as a user facility with experiment selection based on a peer reviewed proposal process. An initial program of five experiments in neutron decay, hadronic weak interaction and time reversal symmetry violation have been proposed. PMID:27308112

  8. VESPA: The vibrational spectrometer for the European Spallation Source.

    PubMed

    Fedrigo, Anna; Colognesi, Daniele; Bertelsen, Mads; Hartl, Monika; Lefmann, Kim; Deen, Pascale P; Strobl, Markus; Grazzi, Francesco; Zoppi, Marco

    2016-06-01

    VESPA, Vibrational Excitation Spectrometer with Pyrolytic-graphite Analysers, aims to probe molecular excitations via inelastic neutron scattering. It is a thermal high resolution inverted geometry time-of-flight instrument designed to maximise the use of the long pulse of the European Spallation Source. The wavelength frame multiplication technique was applied to provide simultaneously a broad dynamic range (about 0-500 meV) while a system of optical blind choppers allows to trade flux for energy resolution. Thanks to its high flux, VESPA will allow the investigation of dynamical and in situ experiments in physical chemistry. Here we describe the design parameters and the corresponding McStas simulations. PMID:27370491

  9. Target station shielding issues at the spallation neutron source.

    PubMed

    Ferguson, P D; Gallmeier, F X; Iverson, E B; Popova, I I

    2005-01-01

    Recent spallation neutron source shielding activities in support of the neutron beam shutters and the hot cell walls are presented. Existing neutron beam shutters can be replaced with concrete at low power or with concrete and steel at approximately 500 kW of beam power. Potential voids in the hot cell walls are analysed to determine the impact on dose rates as a function of void size. A change in the type of shielding work is noted as the project moved from the early design stages as a 'green field' site to the current stage as a construction project nearing completion, where issues to be addressed are approaching retrofit-type analyses. PMID:16381707

  10. Radiological Hazard of Spallation Products in Accelerator-Driven System

    SciTech Connect

    Saito, M.; Stankovskii, A.; Artisyuk, V.; Korovin, Yu.; Shmelev, A.; Titarenko, Yu.

    2002-09-15

    The central issue underlying this paper is related to elucidating the hazard of radioactive spallation products that might be an important factor affecting the design option of accelerator-driven systems (ADSs). Hazard analysis based on the concept of Annual Limit on Intake identifies alpha-emitting isotopes of rare earths (REs) (dysprosium, gadolinium, and samarium) as the dominant contributors to the overall toxicity of traditional (W, Pb, Pb-Bi) targets. The matter is addressed from several points of view: code validation to simulate their yields, choice of material for the neutron producing targets, and challenging the beam type. The paper quantitatively determines the domain in which the toxicity of REs exceeds that of polonium activation products broadly discussed now in connection with advertising lead-bismuth technology for the needs of ADSs.

  11. A multitask neutron beam line for spallation neutron sources

    NASA Astrophysics Data System (ADS)

    Pietropaolo, A.; Festa, G.; Grazzi, F.; Barzagli, E.; Scherillo, A.; Schooneveld, E. M.; Civita, F.

    2011-08-01

    Here we present a new concept for a time-of-flight neutron scattering instrument allowing for simultaneous application of three different techniques: time-of-flight neutron diffraction, neutron resonance capture analysis and Bragg edge transmission analysis. The instrument can provide average resolution neutron radiography too. The potential of the proposed concept was explored by implementing the necessary equipment on INES (Italian Neutron Experimental Station) at the ISIS spallation neutron source (UK). The results obtained show the effectiveness of the proposed instrument to acquire relevant quantitative information in a non-invasive way on a historical metallurgical sample, namely a Japanese hand guard (tsuba). The aforementioned neutron techniques simultaneously exploited the extended neutron energy range available from 10 meV to 1 keV. This allowed a fully satisfactory characterization of the sample in terms of metal components and their combination in different phases, and forging and assembling methods.

  12. Core Vessel Insert Handling Robot for the Spallation Neutron Source

    SciTech Connect

    Graves, Van B; Dayton, Michael J

    2011-01-01

    The Spallation Neutron Source provides the world's most intense pulsed neutron beams for scientific research and industrial development. Its eighteen neutron beam lines will eventually support up to twenty-four simultaneous experiments. Each beam line consists of various optical components which guide the neutrons to a particular instrument. The optical components nearest the neutron moderators are the core vessel inserts. Located approximately 9 m below the high bay floor, these inserts are bolted to the core vessel chamber and are part of the vacuum boundary. They are in a highly radioactive environment and must periodically be replaced. During initial SNS construction, four of the beam lines received Core Vessel Insert plugs rather than functional inserts. Remote replacement of the first Core Vessel Insert plug was recently completed using several pieces of custom-designed tooling, including a highly complicated Core Vessel Insert Robot. The design of this tool are discussed.

  13. Overview of the Conceptual Design of the Future VENUS Neutron Imaging Beam Line at the Spallation Neutron Source

    NASA Astrophysics Data System (ADS)

    Bilheux, Hassina; Herwig, Ken; Keener, Scott; Davis, Larry

    VENUS (Versatile Neutron Imaging Beam line at the Spallation Neutron Source) will be a world-class neutron-imaging instrument that will uniquely utilize the Spallation Neutron Source (SNS) time-of-flight (TOF) capabilities to measure and characterize objects across several length scales (mm to μm). When completed, VENUS will provide academia, industry and government laboratories with the opportunity to advance scientific research in areas such as energy, materials, additive manufacturing, geosciences, transportation, engineering, plant physiology, biology, etc. It is anticipated that a good portion of the VENUS user community will have a strong engineering/industrial research focus. Installed at Beam line 10 (BL10), VENUS will be a 25-m neutron imaging facility with the capability to fully illuminate (i.e., umbra illumination) a 20 cm x 20 cm detector area. The design allows for a 28 cm x 28 cm field of view when using the penumbra to 80% of the full illumination flux. A sample position at 20 m will be implemented for magnification measurements. The optical components are comprised of a series of selected apertures, T0 and bandwidth choppers, beam scrapers, a fast shutter to limit sample activation, and flight tubes filled with Helium. Techniques such as energy selective, Bragg edge and epithermal imaging will be available at VENUS.

  14. Cementless bulk alumina socket: preliminary results at 6 years.

    PubMed

    Hamadouche, M; Nizard, R S; Meunier, A; Bizot, P; Sedel, L

    1999-09-01

    To avoid polyethylene wear observed in total hip replacement, an alumina-alumina combination has been used since 1977. The aim of this study is to report the results of a hybrid alumina-alumina total hip arthroplasty with a cementless press-fit bulk alumina socket and a cemented titanium alloy stem in 55 patients (62 hips) operated on between 1982 and 1990. The bearing surfaces were a 32-mm alumina head articulating within the alumina socket. Four failures occurred: 3 aseptic loosenings of the socket and 1 femoral head fracture. Considering aseptic loosening as the endpoint, the survival rate was 93.2% after 6 years. At a mean of 72.1 months' follow-up, 92.4% of the surviving hips were graded as very good or good using the Merle d'Aubigné-Postel hip score. Radiolucent lines were observed on the acetabular side in 68.1 of the hips. The future of this interface, which is probably fibrous, remains questionable. With the exception of 1 femoral head fracture, all revisions were related to failure of the bony fixation of the socket, and no problem was encountered related to the alumina-alumina friction coupling. Alumina sockets with other types of cementless fixation have therefore been designed and are presently under clinical investigation. PMID:10512442

  15. Simulation of a beam rotation system for a spallation source

    NASA Astrophysics Data System (ADS)

    Reiss, Tibor; Reggiani, Davide; Seidel, Mike; Talanov, Vadim; Wohlmuther, Michael

    2015-04-01

    With a nominal beam power of nearly 1 MW on target, the Swiss Spallation Neutron Source (SINQ), ranks among the world's most powerful spallation neutron sources. The proton beam transport to the SINQ target is carried out exclusively by means of linear magnetic elements. In the transport line to SINQ the beam is scattered in two meson production targets and as a consequence, at the SINQ target entrance the beam shape can be described by Gaussian distributions in transverse x and y directions with tails cut short by collimators. This leads to a highly nonuniform power distribution inside the SINQ target, giving rise to thermal and mechanical stresses. In view of a future proton beam intensity upgrade, the possibility of homogenizing the beam distribution by means of a fast beam rotation system is currently under investigation. Important aspects which need to be studied are the impact of a rotating proton beam on the resulting neutron spectra, spatial flux distributions and additional—previously not present—proton losses causing unwanted activation of accelerator components. Hence a new source description method was developed for the radiation transport code MCNPX. This new feature makes direct use of the results from the proton beam optics code TURTLE. Its advantage to existing MCNPX source options is that all phase space information and correlations of each primary beam particle computed with TURTLE are preserved and transferred to MCNPX. Simulations of the different beam distributions together with their consequences in terms of neutron production are presented in this publication. Additionally, a detailed description of the coupling method between TURTLE and MCNPX is provided.

  16. Spallation recoil and age of presolar grains in meteorites

    NASA Astrophysics Data System (ADS)

    Ott, U.; Begemann, F.

    2000-01-01

    We have determined the recoil losses from silicon carbide grain size fractions of spallation neon produced by irradiation with 1.6 GeV protons. During the irradiation the SiC grains were dispersed in paraffin wax in order to avoid re-implantation into neighboring grains. Analysis for spallogenic 21Ne of grain size separates in the size range 0.3 μm to 6 μm and comparison with the 22Na activity of the SiC+paraffin mixture indicates an effective recoil range of 2-3 μm with no apparent effect from acid treatments such as routinely used in the isolation of meteoritic SiC grains. Our results indicate that the majority of presolar SiC grains in primitive meteorites, which are ~μm-sized, will have lost essentially all spallogenic Ne produced by cosmic ray interaction in the interstellar medium. This argues against the validity of previously published presolar ages of Murchison SiC (~10 to ~130 Ma; increasing with grain size; Lewis et al., 1994), where recoil losses had been based on calculated recoil energies. It is argued that the observed variations in meteoritic SiC grain size fractions of 21Ne/22Ne ratios are more likely due to the effects of nucleosynthesis in the He burning shell of the parent AGB stars which imposes new boundary conditions on nuclear parameters and stellar models. It is suggested that spallation-Xe produced on the abundant Ba and REE in presolar SiC, rather than spallogenic Ne, may be a promising approach to the presolar age problem. There is a hint in the currently available Xe data (Lewis et al., 1994) that the large (>1 μm) grains may be younger than the smaller (<1 μm) ones.

  17. Li + ion diffusion in nanoscale alumina coatings

    NASA Astrophysics Data System (ADS)

    Johannes, Michelle; Bernstein, Noam

    Nanoscale coatings of alumina are used to stabilize surfaces for a variety of technologies. Diffusion of ions through these coatings is of primary importance: in some cases, diffusion is unwanted (e.g. corrosion) and in others (e.g. electrode materials), it is necessary. In this work DFT and AIMD calculations are used to investigate Li+ ion diffusion through a nano-layer of alumina, examining the phase (alpha, gamma, and amorphous), ion concentration, and electron count dependence. We look at the role of the surface itself in promoting diffusion. One of our main findings is that as the number of ions or charge increases, the diffusivity rises. We show how our data can explain electrochemical data from coated LiCoO2 cathodes and may point toward better and more efficient coatings for stabilizing electrodes.

  18. Fracture toughness and strength of 96% alumina

    SciTech Connect

    Price, D.B.; Chinn, R.E.; McNerney, K.R.; Brog, T.K.; Kim, C.Y.; Krutyholowa, M.W.; Chen, N.W.; Haun, M.J.

    1997-05-01

    There exists a need to understand the controlling factors that simultaneously impact strength and toughness in 96% alumina. The enhancement of both strength and toughness enables designers to extend the use limits and reliability for structural ceramics. This article presents mechanical property results from a group study examining the use of different alkaline-earth aluminosilicate intergranular compositions containing magnesium, calcium and strontium oxides (RO) in 96% alumina. Principal results address trends in indentation strength toughness and modulus of rupture. Trends in the data are presented relative to existing theories of thermal expansion mismatch toughening, grain-bridging crack-wake effect and crack deflection mechanisms. Strength is addressed in terms of strength after indentation, crack growth of indentation flaws and Weibull characterization for the strength distribution.

  19. Impact of AD995 alumina rods

    SciTech Connect

    Chhabildas, L.C.; Furnish, M.D.; Reinhart, W.D.; Grady, D.E.

    1997-10-01

    Gas guns and velocity interferometric techniques have been used to determine the loading behavior of an AD995 alumina rod 19 mm in diameter by 75 mm and 150 mm long, respectively. Graded-density materials were used to impact both bare and sleeved alumina rods while the velocity interferometer was used to monitor the axial-velocity of the free end of the rods. Results of these experiments demonstrate that (1) a time-dependent stress pulse generated during impact allows an efficient transition from the initial uniaxial strain loading to a uniaxial stress state as the stress pulse propagates through the rod, and (2) the intermediate loading rates obtained in this configuration lie between split Hopkinson bar and shock-loading techniques.

  20. Health Risk Assessments for Alumina Refineries

    PubMed Central

    Coffey, Patrick S.

    2014-01-01

    Objective: To describe contemporary air dispersion modeling and health risk assessment methodologies applied to alumina refineries and to summarize recent results. Methods: Air dispersion models using emission source and meteorological data have been used to assess ground-level concentrations (GLCs) of refinery emissions. Short-term (1-hour and 24-hour average) GLCs and annual average GLCs have been used to assess acute health, chronic health, and incremental carcinogenic risks. Results: The acute hazard index can exceed 1 close to refineries, but it is typically less than 1 at neighboring residential locations. The chronic hazard index is typically substantially less than 1. The incremental carcinogenic risk is typically less than 10−6. Conclusions: The risks of acute health effects are adequately controlled, and the risks of chronic health effects and incremental carcinogenic risks are negligible around referenced alumina refineries. PMID:24806721

  1. Activation of consolidation processes of alumina ceramics

    NASA Astrophysics Data System (ADS)

    Matrenin, S. V.; Zenin, B. S.; Tayukin, R. V.

    2016-02-01

    The methods for activating sintering ceramics based on Al2O3 by mechanical activation in the planetary mill, by adding in the mixture of nanopowders (NP) Al, Al2O3, and submicron powder TiO2, and by applying the technology of spark plasma sintering (SPS) are developed. It has been shown that adding the nanopowder up to 20 wt. % Al2O3 in a coarse powder α-Al2O3 activates the sintering process resulting in increased density and hardness of the sintered alumina ceramics. Substantial effect of increasing density of alumina ceramics due to adding the submicron powder TiO2 in the compound of initial powder mixtures has been established.

  2. Fast Glazing of Alumina/Silica Tiles

    NASA Technical Reports Server (NTRS)

    Creedon, J. F.; Gzowski, E. R.; Wheeler, W. H.

    1986-01-01

    Technique for applying ceramic coating to fibrous silica/alumina insulation tiles prevents cracks and substantially reduces firing time. To reduce thermal stresses in tile being coated, high-temperature, shorttime firing schedule implemented. Such schedule allows coating to mature while substrate remains at relatively low temperature, reducing stress differential between coating and substrate. Technique used to repair tiles with damaged coatings and possibly used in heat-treating objects made of materials having different thermal-expansion coefficients.

  3. High contrast laser marking of alumina

    NASA Astrophysics Data System (ADS)

    Penide, J.; Quintero, F.; Riveiro, A.; Fernández, A.; del Val, J.; Comesaña, R.; Lusquiños, F.; Pou, J.

    2015-05-01

    Alumina serves as raw material for a broad range of advanced ceramic products. These elements should usually be identified by some characters or symbols printed directly on them. In this sense, laser marking is an efficient, reliable and widely implemented process in industry. However, laser marking of alumina still leads to poor results since the process is not able to produce a dark mark, yielding bad contrast. In this paper, we present an experimental study on the process of marking alumina by three different lasers working in two wavelengths: 1064 nm (Near-infrared) and 532 nm (visible, green radiation). A colorimetric analysis has been carried out in order to compare the resulting marks and its contrast. The most suitable laser operating conditions were also defined and are reported here. Moreover, the physical process of marking by NIR lasers is discussed in detail. Field Emission Scanning Electron Microscopy, High Resolution Transmission Electron Microscopy and X-ray Photoelectron Spectroscopy were also employed to analyze the results. Finally, we propose an explanation for the differences of the coloration induced under different atmospheres and laser parameters. We concluded that the atmosphere is the key parameter, being the inert one the best choice to produce the darkest marks.

  4. Compression Testing of Alumina Fiber Insulation

    NASA Technical Reports Server (NTRS)

    Vaughn, Wallace L.

    2006-01-01

    A series of tests were conducted to measure the response of alumina fiber insulation to compression loading. The alumina fiber insulation is a candidate gasket material for the Space Shuttle Government Furnished Equipment (GFE) Tile Overlay Repair. Tests were conducted at room temperature and 2300 F. The alumina fiber insulation is a fibrous insulation blanket which was supplied to Langley in two forms, a nominal 3 lb/ft3 version and a nominal 9 lb/ft3 version. The 3 lb/ft3 material was tested as sheets 0.15 and 0.25 inches thick and the 9 lb/ft3 material in sheets 1 inch thick. The material showed very non-linear compression behavior with the compressive resistance of the material increasing as the material was compressed. The 3 lb/ft3 0.15-inch thick material required 4.1 psi to reach the nominal installation thickness of 0.045 inches and retain a load of 2.1 lbs during unloading. Testing at 2300 F resulted in a stiffer more board-like material. The 3 lb/ft3 0.15-inch thick material retained 1 psi of compressive resistance after a 10 minute hold at 2300 F and 0.045 inches thickness.

  5. Initial observations of cavitation-induced erosion of liquid metal spallation target vessels at the Spallation Neutron Source

    SciTech Connect

    McClintock, David A; Riemer, Bernie; Ferguson, Phillip D; Carroll, Adam J; Dayton, Michael J

    2012-01-01

    During operation of the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory the mechanical properties of the AISI 316L target module are altered by high-energy neutron and proton radiation. The interior surfaces of the target vessel are also damaged by cavitation-induced erosion, which results from repetitive rapid heating of the liquid mercury by high-energy proton beam pulses. Until recently no observations of cavitation-induced erosion were possible for conditions prototypical to the SNS. Post irradiation examination (PIE) of the first and second operational SNS targets was performed to gain insight into the radiation-induced changes in mechanical properties of the 316L target material and the extent of cavitation-induced erosion to the target vessel inner surfaces. Observations of cavitation-induced erosion of the first and second operational SNS target modules are presented here, including images of the target vessel interiors and specimens removed from the target beam-entrance regions.

  6. Technology and science at a high-power spallation source: Proceedings

    SciTech Connect

    Not Available

    1994-01-01

    These proceedings cover many aspects of the usefulness of spallation neutrons. Nine different areas are considered: surfaces and interfaces, engineering, materials science, polymers and complex fluids, chemistry, structural biology, nuclear engineering and radiation effects, condensed matter physics and fundamental physics.

  7. Rear surface spallation on single-crystal silicon in nanosecond laser micromachining

    NASA Astrophysics Data System (ADS)

    Ren, Jun; Orlov, Sergei S.; Hesselink, Lambertus

    2005-05-01

    Rear surface spallation of single-crystal silicon under 5-ns laser pulse ablation at intensities of 0.6-60GW/cm2 is studied through postablation examination of the ablated samples. The spallation threshold energy and the spallation depth's dependences on the energy and target thickness are measured. From the linear relation between the spallation threshold energy and the target thickness, an estimation of the material spall strength around 1.4GPa is obtained, in reasonable agreement with the spall strength estimation of 0.8-1.2GPa at a strain rate of 107s-1 using Grady's model for brittle materials. The experiment reveals the internal fracturing process over an extended zone in silicon, which is controlled by the competition between the shock pressure load and the laser ablation rate. The qualities of the laser microstructuring and micromachining results are greatly improved by using an acoustic impedance matching approach.

  8. A proposal for a long-pulse spallation source at Los Alamos National Laboratory

    SciTech Connect

    Pynn, R.; Weinacht, D.

    1995-12-01

    Los Alamos National Laboratory is proposing a new spallation neutron source that will provide the US with an internationally competitive facility for neutron science and technology that can be built in approximately three years for less than $100 million. The establishment of a 1-MW, long-pulse spallation source (LPSS) at the Los Alamos Neutron Science Center (LANSCE) will meet many of the present needs of scientists in the neutron scattering community and provide a significant boost to neutron research in the US. The new facility will support the development of a future, more intense spallation neutron source, that is planned by DOE`s Office of Energy Research. Together with the existing short pulse spallation source (SPSS) at the Manual Lujan, Jr. Neutron Scattering Center (MLNSC) at Los Alamos, the new LPSS will provide US scientists with a complementary pair of high-performance neutron sources to rival the world`s leading facilities in Europe.

  9. Synthesis and properties of high-purity alumina

    SciTech Connect

    Martin, E.S.; Weaver, M.L. . Chemical Systems Div.)

    1993-07-01

    High-purity alumina is intended primarily for the high-pressure sodium-vapor lamp envelope market and other specialty alumina applications such as abrasives, catalysts, and structural ceramics. High-purity alumina must calcine to Al[sub 2]O[sub 3] with minimal metal impurities ([>=]99.99% Al[sub 2]O[sub 3]). Sulfate and chloride impurities are also undesirable. High-purity alumina should have less than 20ppm alkali and alkaline-earth metals, and less than 10 ppm each in transition-metal impurities. A process for synthesizing alumina by converting pure aluminum metal to aluminum hydroxide and the resultant alumina properties are described.

  10. A simple procedure to prepare spherical {alpha}-alumina powders

    SciTech Connect

    Liu Hongyu; Ning Guiling Gan Zhihong; Lin Yuan

    2009-04-02

    Spherical {alpha}-alumina powders were prepared by the controlled hydrolysis of aluminum isopropoxide in a hydrolysis system consisting of octanol and acetonitrile. Diverse solvents to dissolve reactant formed diverse hydrolysis systems and affected particle shape of {alpha}-alumina powders. The precursors crystallized to {gamma}-alumina at 1000 deg. C and converted to {alpha}-alumina at 1150 deg. C without intermediate phases. The particle morphology of precursor was retained after it crystallized to {alpha}-alumina. The heating rate influenced the particle shape and the state of agglomeration during calcination process. The thermal properties of the precursors were characterized by thermal gravimetric and differential thermal analysis. X-ray diffraction technique was used to confirm the conversion of crystalline phase of alumina powders from amorphous to {alpha}-phase. Transmission electron microscopy was used to investigate the morphologies and size of the precursors and products.

  11. New experience with alumina-on-alumina ceramic bearings for total hip arthroplasty.

    PubMed

    D'Antonio, James; Capello, William; Manley, Michael; Bierbaum, Benjamin

    2002-06-01

    A major challenge for total hip arthroplasty is to minimize wear and osteolysis in young, active patients. Alumina ceramic bearings have shown superior wear resistance and lubrication and do not carry the risk of ion release. In a prospective randomized study, 514 hips were implanted. All patients (average age, 53 years) received the same press-fit hydroxyapatite coated femoral stem; two thirds (345 hips) received alumina ceramic bearings, and one third (169 hips) received a cobalt-chrome-on-polyethylene bearing. At a mean follow-up of 35.2 months (range, 24-48 months), there was no significant difference in clinical performance between the patient cohorts. No ceramic fracture or alumina ceramic bearing failure occurred. This new experience involves the use of improved ceramic materials and new design considerations that eliminate the risks and complications of past experiences with ceramic implants and provides a safe bearing option for young patients. PMID:12066265

  12. Free-standing alumina nanobottles and nanotubes pre-integrated into nanoporous alumina membranes

    NASA Astrophysics Data System (ADS)

    Fang, Jinghua; Levchenko, Igor; (Ken Ostrikov, Kostya

    2014-08-01

    A novel interfacial structure consisting of long (up to 5 μm), thin (about 300 nm), highly-ordered, free-standing, highly-reproducible aluminum oxide nanobottles and long tubular nanocapsules attached to a rigid, thin (less than 1 μm) nanoporous anodic alumina membrane is fabricated by simple, fast, catalyst-free, environmentally friendly voltage-pulse anodization. A growth mechanism is proposed based on the formation of straight channels in alumina membrane by anodization, followed by neck formation due to a sophisticated voltage control during the process. This process can be used for the fabrication of alumina nanocontainers with highly controllable geometrical size and volume, vitally important for various applications such as material and energy storage, targeted drug and diagnostic agent delivery, controlled drug and active agent release, gene and biomolecule reservoirs, micro-biologically protected platforms, nano-bioreactors, tissue engineering and hydrogen storage.

  13. Quantitative analysis of damage clustering and void linking for spallation modeling in tantalum

    SciTech Connect

    Tonks, D.L.; Zurek, A.K.; Thissell, W.R.; Hixson, R.

    1997-05-01

    In a companion paper in this volume by Zurek et al, micrographs of incipient spallation damage in rolled tantalum were numerically analyzed using image analysis techniques. Void sizes, locations, and overall porosity were measured and tabulated. In this paper, we extend this analysis to include void clusters and examine the correlation between cluster size and the ranges of local instabilities between voids visible in the micrographs. The implications for spallation modeling will be given.

  14. Alumina Solubility and Diffusion Coefficient of the Dissolved Alumina Species in Low-Temperature Fluoride Electrolytes

    NASA Astrophysics Data System (ADS)

    Frazer, E. J.; Thonstad, J.

    2010-06-01

    The solubility of alumina was measured by rotating an alumina cylinder (~500 rpm) in a high-purity melt for ~3 to 6 hours, crushing and sampling the frozen melt, and determining the oxygen content in a Leco analyzer. The alumina solubilities determined were as follows: (1) 3.2 ± 0.3 wt pct in NaF-AlF3 eutectic at 1023 K (750 °C); (2) 3.0 ± 0.3 wt pct in NaF-AlF3-CaF2 (5 wt pct) at 1023 K (750 °C); and (3) 5.2 ± 0.5 wt pct in a KF-AlF3 eutectic at 1003 K (730 °C). The alumina solubility in the KF-AlF3 eutectic was 2 wt pct more than in the sodium analogue, offering the possibility of operating a low-temperature aluminum smelting cell without the need for an alumina slurry. The diffusion coefficient of the dissolved alumina species was determined in the NaF-AlF3 eutectic at 1023 K (750 °C) using the rotating disc method and applying the Levich equation. Through a limited range of rotation rates, the system seemed to be mass-transfer controlled, and the diffusion coefficient was estimated to be in the range 1.8 to 2.2 × 10-6 cm2 s-1. This value is about five times lower than the values encountered at traditional aluminum smelting temperatures (~1233 K (960 °C)) and would result in relatively low mass transfer coefficients.

  15. Method for preparing Pb-.beta."-alumina ceramic

    DOEpatents

    Hellstrom, Eric E.

    1986-01-01

    A process is disclosed for preparing impermeable, polycrystalline samples of Pb-.beta."-alumina ceramic from Na-.beta."-alumina ceramic by ion exchange. The process comprises two steps. The first step is a high-temperature vapor phase exchange of Na by K, followed by substitution of Pb for K by immersing the sample in a molten Pb salt bath. The result is a polycrystalline Pb-.beta."-alumina ceramic that is substantially crack-free.

  16. Sintering of beta-type alumina bodies using alpha-alumina encapsulation

    DOEpatents

    McEntire, Bryan J.; Virkar, Anil V.

    1981-01-01

    A method of sintering a shaped green, beta-type alumina body comprising: (A) inserting said body into an open chamber prepared by exposing the interior surface of a container consisting essentially of at least about 50 weight percent of alpha-alumina and a remainder of other refractory material to a sodium oxide or sodium oxide producing environment; (B) sealing the chamber; and heating the chamber with the shaped body encapsulated therein to a temperature and for a time necessary to sinter said body to the desired density. The encapsulation chamber prepared as described above is also claimed.

  17. Porous Alumina Prepared from Diethylaluminum Amide, Acetone, and Water

    SciTech Connect

    Wilcox, Lize; Burnside, Gaylen G.; Kiranga, Beatrice; Shekhawat, Ritu; Mazumder, Malay K.; Hawk, Roger M.; Lindquist, David A.; Burton, Sarah D.)

    2003-01-14

    Mesoporous aluminas are valued catalysts because they exhibit a combination of properties that allow both long life and activity. The surface area, acidity, stability, and pore size of the alumina directly influence lifetime and activity. Increased surface area and acidity, along with decreased pore size, lead to increased activity. However, these same characteristics also decrease lifetime. The properties of alumina are mutually dependent, and can be mutually opposed. Aluminas with better activity and longer life will result from a better understanding of these trends given the preparative method and thermal history.

  18. Modelling the initial stage of porous alumina growth during anodization

    NASA Astrophysics Data System (ADS)

    Aryslanova, E. M.; Alfimov, A. V.; Chivilikhin, S. A.

    2013-05-01

    Artificially on the surface of aluminum there may be build a thick layer of Al2O3, which has a porous structure. In this paper we present a model of growth of porous alumina in the initial stage of anodizing, identifying dependencies anodizing parameters on the rate of growth of the film and the distance between the pores and as a result of the created model equations were found for changes in the disturbance of alumina for the initial stage of anodizing aluminum oxide porous border aluminum-alumina and alumina-electrolyte, with the influence of surface diffusion of aluminum oxide.

  19. Design and Testing of a Prototype Spallation Neutron Source Rotating Target Assembly

    SciTech Connect

    Rennich, Mark J; McManamy, Thomas J; Graves, Van; Garmendia, Amaia Zarraoa; Sorda, Fernando

    2010-01-01

    The mechanical aspects of an extended vertical shaft rotating target have been evaluated in a full-scale mockup test. A prototype assembly based on a conceptual target design for a 1 to 3-MW spallation facility was built and tested. Key elements of the drive/coupling assembly implemented in the prototype include high integrity dynamic face seals, commercially available bearings, realistic manufacturing tolerances, effective monitoring and controls, and fail-safe shutdown features. A representative target disk suspended on a 3.5 meter prototypical shaft was coupled with the drive to complete the mechanical tests. After1800 hours of operation the test program has confirmed the overall mechanical feasibility of the extended vertical shaft rotating target concept. Precision alignment of the suspended target disk; successful containment of the water and verification of operational stability over the full speed range of 30 to 60 rpm were primary indications the proposed mechanical design is valid for use in a high power target station.

  20. Laser wire beam profile monitor in the spallation neutron source (SNS) superconducting linac

    NASA Astrophysics Data System (ADS)

    Liu, Y.; Aleksandrov, A.; Assadi, S.; Blokland, W.; Deibele, C.; Grice, W.; Long, C.; Pelaia, T.; Webster, A.

    2010-01-01

    The spallation neutron source (SNS) at Oak Ridge National Laboratory is an accelerator-based, neutron-scattering facility. SNS uses a large-scale, high-energy superconducting linac (SCL) to provide high beam power utilizing hydrogen ion (H -) beams. For the diagnostics of high-brightness H - beams in the SCL, nonintrusive methods are preferred. This paper describes design, implementation, theoretical analysis, and experimental demonstration of a nonintrusive profile monitor system based on photodetachment, also known as laser wire, installed in the SNS SCL. The SNS laser wire system is the world's largest of its kind with a capability of measuring horizontal and vertical profiles of an operational H - beam at each of the 23 cryomodule stations along the SCL beam line by employing a single light source. Presently 9 laser wire stations have been commissioned that measure profiles of the H - beam at energy levels from 200 MeV to 1 GeV. The laser wire diagnostics has no moving parts inside the beam pipe, causes no contamination on the superconducting cavity, and can be run parasitically on an operational neutron production H - beam.

  1. Scale

    ERIC Educational Resources Information Center

    Schaffhauser, Dian

    2009-01-01

    The common approach to scaling, according to Christopher Dede, a professor of learning technologies at the Harvard Graduate School of Education, is to jump in and say, "Let's go out and find more money, recruit more participants, hire more people. Let's just keep doing the same thing, bigger and bigger." That, he observes, "tends to fail, and fail…

  2. Damping Behavior of Alumina Epoxy Nano-Composites

    NASA Astrophysics Data System (ADS)

    Katiyar, Priyanka; Kumar, Anand

    2016-05-01

    Polymer nano composites, consisting of a polymer matrix with nanoparticle filler, have been predicted to be one of the most beneficial applications of nanotechnology. Addition of nano particulates to a polymer matrix enhances its performance by capitalizing on the nature and properties of the nano-scale fillers. The damping behavior of composites with nano structured phases is significantly different from that of micro structured materials. Viscoelastic homopolymer exhibit a high material damping response over a relatively narrow range of temperature and frequencies. In many practical situations, a polymeric structure is required to possess better strength and stiffness properties together with a reasonable damping behavior. Viscoelastic polymers show higher loss factor beyond the glassy region which comes with a significant drop in the specific modulus. Addition of nano alumina particles to epoxy leads to improved strength and stiffness properties with an increase in glass transition temperature while retaining its damping capability. Experimental investigations are carried out on composite beam specimen fabricated with different compositions of alumina nano particles in epoxy to evaluate loss factor, tan δ. Impact damping method is used for time response analysis. A single point Laser is used to record the transverse displacement of a point on the composite beam specimen. The experimental results are compared with theoretical estimation of loss factor using Voigt estimation. The effect of inter phase is included in theoretical estimation of loss factor. The result reveals that the study of interface properties is very important in deriving the overall loss factor of the composite since interface occupies a significant volume fraction in the composite.

  3. Materials Compatibility Studies for the Spallation Neutron Source

    SciTech Connect

    DiStefano, J.R.; Manneschmidt, E.T.; Pawel, S.J.

    1998-09-01

    The Spallation Neutron Source (SNS) is a high power facility for producing neutrons that utilizes flowing liquid mercury inside an austenitic stainless steel container as the target for a 1.0 GeV proton beam. The energy deposited in the target is transported by two separate mercury flow streams: one to transport heat in the interior target region and one to cool the stainless steel container. Three-dimensional computational fluid dynamics simulations have been performed to predict temperature, velocity, and pressure distributions in the target. Results have generally shown that the power deposited in the bulk mercury can be effectively transported with reasonable flow rates and the bulk mercury temperature should not exceed 160{deg}C. Assuming good thermal contact, the maximum stainless steel wall temperature should be 130 {deg}C. Type 316 SS has been selected as the container material for the mercury and consequences of exposure of 316 SS to radiation, thermal shock, thermal stress, cavitation and hot, flowing mercury are all being addressed by R&D programs. In addition, corrosion studies include evaluation of Inconel 718 because it has been successfully used in previous water cooled spallation neutron systems as a window material. With type 316 SS selected to contain the mercury target of the SNS, two types of compatibility issues have been examined: LME and temperature gradient mass transfer. Studies have shown that mercury does not easily wet type 316 SS below 275{deg}C. In the LME experiments, attempts were made to promote wetting of the steel by mercury either by adding gallium to the mercury or coating the specimen with a tin-silver solder that the mercury easily wets. The latter proved more reliable in establishing wetting, but there was no evidence of LME in any of the constant extension rate tensile tests either at 23 or 100 {deg}C. Inconel 718 also showed no change in room temperature properties when tested in mercwy or mercury-gallium. However, there

  4. Segregation phenomena at growing alumina/alloy interfaces

    SciTech Connect

    Hou, Peggy Y.

    2005-03-30

    The chemistry and structure at the scale/alloy interface are important factors governing scale adhesion. The chemical changes can occur from segregation of impurities in the alloy, such as sulphur and carbon, or alloying elements such as chromium, aluminium and reactive elements. This paper reviews studies of the changes of interfacial composition with oxidation time for Al{sub 2}O{sub 3} formed on several model alumina-forming alloys, and tries to relate that to the interfacial strength. Results show that sulphur segregation to oxide/metal interfaces can indeed occur, but the type and amount of segregants at the interface depend on the alloy composition and the interface structure. Co-segregation of impurities with alloying elements can also occur, resulting in multi-layer segregants at the interface. Sulphur-containing interfaces are indeed weaker, but the major role of sulphur is to enhance interfacial void formation. Reactive elements in the alloy not only gather sulfur but also exert an additional positive effect on scale adhesion.

  5. 196Pt(n,xn yp γ) reactions using spallation neutrons from En=1 to 250 MeV

    NASA Astrophysics Data System (ADS)

    Tavukcu, E.; Bernstein, L. A.; Hauschild, K.; Becker, J. A.; Garrett, P. E.; McGrath, C. A.; McNabb, D. P.; Younes, W.; Chadwick, M. B.; Nelson, R. O.; Johns, G. D.; Mitchell, G. E.

    2001-11-01

    Neutron-induced reactions on 196Pt were studied over the neutron energy range from 1 to 250 MeV. A ``white'' neutron beam was provided by the spallation neutron source of the Weapons Neutron Research facility at the Los Alamos Neutron Science Center. The prompt reaction γ rays were measured with the large-scale Compton-suppressed Ge spectrometer GEANIE. The incident neutron energy was determined by the time-of-flight technique. Excitation functions for γ-ray transitions in 184,186,188,190-196Pt and 189,191,193Ir isotopes are compared with enhanced Hauser-Feshbach reaction modeling, as implemented in the reaction code GNASH. Overall, the model predictions agree well with the measured γ-ray yields. Discrepancies appear, however, due to inadequate discrete-level information in the calculations describing the preequilibrium process.

  6. Anisotropic shrinkage characteristics of tape cast alumina

    NASA Astrophysics Data System (ADS)

    Patwardhan, Jaideep Suresh

    Dimensional control during sintering is a major issue in ceramics processing to avoid high post-sintering costs associated with machining of the fired ceramic part to desired tolerances and dimensions. Ceramic forming processes such as tape casting, injection molding, and extrusion involve shear of anisotropic particles resulting in preferential alignment of the particles in the green body. This preferential alignment causes directionality in mechanical, electrical, optical, and magnetic properties and most importantly warpage or distortion during sintering. A large effort has been devoted to synthesizing ceramic green bodies with minimal density gradients and uniform packing and modeling the sintering behavior evolution but little effort has been devoted to characterizing orientation of particles and the effect of preferential alignment on sintering shrinkage anisotropy. A systematic study was initiated to study the effect of processing variables such as shear rate, solids loading, temperature, and binder content on aqueous tape cast alumina. Three different alumina systems: A16-SG, Baikowski RC-UFX DBM and RC-LS DBM were investigated. Aqueous tapes of high solids loading alumina (56 vol. %) were tape cast at various speeds and thicknesses and assuming plane Couette flow a shear rate regime of 21--270 s-1 was investigated. Higher shear rates and high solids loading resulted in higher in-plane anisotropy whereas the anisotropy in the thickness direction was higher for low solids loading systems. The anisotropy was found to be fairly constant above a certain critical shear rate (˜100 s-1) irrespective of the temperature and the solids loading and this correlated with the viscosity-shear rate relationship of the cast slips. The higher shrinkage anisotropy in the thickness direction for the low solids loading systems (35 and 45 vol. %) was attributed to the higher amount of organics in the slip required to sustain the suitable viscosity for tape casting and

  7. Intercalation of water into lithium. beta. -alumina

    SciTech Connect

    Dudney, N J; Bates, J B; Wang, J C; Brown, G M; Larson, B C; Engstrom, H

    1981-01-01

    Infrared absorption, neutron diffraction and weight loss techniques have been used to investigate the hydration of single crystals of Li ..beta..-alumina. The hydration is a reversible intercalation reaction. Up to approximately two water molecules per formula unit can penetrate the conduction plane. Other protonated species are formed from the dissociation of the molecular water. The rate of hydration is controlled by the diffusion of water in the conduction plane. A likely diffusion mechanism requires dissociation of the water and an interstitialcy motion of the oxygen.

  8. Porosity in plasma sprayed alumina coatings

    SciTech Connect

    Ilavsky, J.; Herman, H.; Berndt, C.C.; Goland, A.N.; Long, G.G.; Krueger, S.; Allen, A.J.

    1994-03-01

    Small-angle neutron scattering (SANS) was used to study the porosity of plasma sprayed deposits of alumina in as-sprayed and heat-treated conditions. SANS results were compared with mercury intrusion porosimetry (MIP) and water immersion techniques. Multiple small-angle neutron scattering yields a volume-weighted effective pore radius (R{sub eff}), for pores with sizes between 0.08 and 10{mu}m, the pore volume in this size region, and from the Porod region, the surface area of pores of all sizes.

  9. Crack growth resistance of textured alumina

    NASA Technical Reports Server (NTRS)

    Salem, Jonathan A.; Shannon, John L., Jr.; Bradt, Richard C.

    1989-01-01

    The crack growth resistance of a textured, extruded alumina body was compared with that of anisotropic, isopressed body of similar grain size, density, and chemistry. R-curve levels reflected the preferred orientation; however, R-curve slopes were the same in all instances, implying a similar crack growth-resistive mechanism. Three orthogonal orientations of crack growth in the two structures exhibited similar forms of K(IR) versus Delta-a curves, for which a schematic diagram for polycrystalline ceramics is proposed.

  10. Conduction mechanism of single-crystal alumina

    NASA Technical Reports Server (NTRS)

    Will, Fritz G.; Delorenzi, Horst G.; Janora, Kevin H.

    1992-01-01

    The fully guarded three-terminal technique was used to perform conductivity measurements on single-crystal alumina at temperatures of 400-1300 C. The conductivity was also determined as a function of time at various temperatures and applied fields. Further, the fractions of the current carried by Al and O ions (ionic transference numbers) were determined from long-term transference experiments in the temperature range 1100-1300 C. A mathematical model of the conduction mechanism is proposed, and model predictions are compared with experimental results.

  11. Improved Synthesis Of Potassium Beta' '-Alumina

    NASA Technical Reports Server (NTRS)

    Williams, Roger M.; Jeffries-Nakamura, Barbara; Ryan, Margaret A.; O'Connor, Dennis E.; Kisor, Adam; Underwood, Mark

    1996-01-01

    Improved formulations of precursor materials synthesize nearly-phase-pure potassium beta' '-alumina solid electrolyte (K-BASE) powder. Materials are microhomogeneous powders (or, alternatively, gels) containing K(+,) Mg(2+), and Al(3+). K-BASE powder produced used in potassium-working-fluid alkali-metal thermal-to-electric conversion (K-AMTEC), in which heat-input and heat-rejection temperatures lower than sodium-working-fluid AMTEC (Na-AMTEC). Additional potential use lies in purification of pottassium by removal of sodium and calcium.

  12. Neutron diffractometers for structural biology at spallation neutron sources

    SciTech Connect

    Schoenborn, B.P.; Pitcher, E.

    1994-12-31

    Spallation neutron sources are ideal for diffraction studies of proteins and oriented molecular complexes. With spoliation neutrons and their time dependent wavelength structure, it is easy to electronically select data with an optimal wavelength bandwidth and cover the whole Laue spectrum as time (wavelength) resolved snapshots. This optimized data quality with best peak-to-background ratios and provides adequate spatial and energy resolution to eliminate peak overlaps. The application of this concept will use choppers to select the desired Laue wavelength spectrum and employ focusing optics and large cylindrical {sup 3}He detectors to optimize data collection rates. Such a diffractometer will cover a Laue wavelength range from 1 to 5{Angstrom} with a flight path length of 10m and an energy resolution of 0.25{Angstrom}. Moderator concepts for maximal flux distribution within this energy range will be discussed using calculated flux profiles. Since the energy resolution required for such timed data collection in this super Laue techniques is not very high, the use of a linac only (LAMPF) spoliation target is an exciting possibility with an order of magnitude increase in flux.

  13. rf improvements for Spallation Neutron Source H- ion sourcea)

    NASA Astrophysics Data System (ADS)

    Kang, Y. W.; Fuja, R.; Goulding, R. H.; Hardek, T.; Lee, S.-W.; McCarthy, M. P.; Piller, M. C.; Shin, K.; Stockli, M. P.; Welton, R. F.

    2010-02-01

    The Spallation Neutron Source at Oak Ridge National Laboratory is ramping up the accelerated proton beam power to 1.4 MW and just reached 1 MW. The rf-driven multicusp ion source that originates from the Lawrence Berkeley National Laboratory has been delivering ˜38 mA H- beam in the linac at 60 Hz, 0.9 ms. To improve availability, a rf-driven external antenna multicusp ion source with a water-cooled ceramic aluminum nitride (AlN) plasma chamber is developed. Computer modeling and simulations have been made to analyze and optimize the rf performance of the new ion source. Operational statistics and test runs with up to 56 mA medium energy beam transport beam current identify the 2 MHz rf system as a limiting factor in the system availability and beam production. Plasma ignition system is under development by using a separate 13 MHz system. To improve the availability of the rf power system with easier maintenance, we tested a 70 kV isolation transformer for the 80 kW, 6% duty cycle 2 MHz amplifier to power the ion source from a grounded solid-state amplifier.

  14. Spallation Neutron Source Operating Experience and Outlook for Upgrades

    NASA Astrophysics Data System (ADS)

    Henderson, Stuart

    2010-03-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory is a MW-class accelerator-driven pulsed neutron source. The SNS began formal operations in October 2006. Since then, the beam power has been increased to 1 MW, the number of operating hours per year has increased to nearly 5000, the availability has increased to 85%, and the number of operating neutron scattering instruments has increased to 13. Plans are in place to increase the beam power and availability to their design values of 1.4 MW and 90% over the next two years, and to continue the build-out of instruments to 16 by 2012. Two upgrade projects are in the planning stages. In the first, the beam power of the SNS is increased to at least 2 MW by raising the beam energy from 1.0 to 1.3 GeV and the beam current by 60%. In the second, a Second Target Station is constructed, and is powered by sharing beam pulses with the first target station. The operating experience will be described, as will the challenges that have been met along the path toward 1 MW beam power. The strategy for upgrades will also be presented.

  15. rf improvements for Spallation Neutron Source H-ion source

    SciTech Connect

    Kang, Yoon W; Fuja, Raymond E; Goulding, Richard Howell; Hardek, Thomas W; Lee, Sung-Woo; McCarthy, Mike; Piller, Chip; Shin, Ki; Stockli, Martin P; Welton, Robert F

    2010-01-01

    The Spallation Neutron Source at Oak Ridge National Laboratory is ramping up the accelerated proton beam power to 1.4 MW and just reached 1 MW. The rf-driven multicusp ion source that originates from the Lawrence Berkeley National Laboratory has been delivering 38 mA H beam in the linac at 60 Hz, 0.9 ms. To improve availability, a rf-driven external antenna multicusp ion source with a water-cooled ceramic aluminum nitride AlN plasma chamber is developed. Computer modeling and simulations have been made to analyze and optimize the rf performance of the new ion source. Operational statistics and test runs with up to 56 mA medium energy beam transport beam current identify the 2 MHz rf system as a limiting factor in the system availability and beam production. Plasma ignition system is under development by using a separate 13 MHz system. To improve the availability of the rf power system with easier maintenance, we tested a 70 kV isolation transformer for the 80 kW, 6% duty cycle 2 MHz amplifier to power the ion source from a grounded solid-state amplifier. 2010 American Institute of Physics.

  16. Spallative production of Li, Be and B in superbubbles

    NASA Astrophysics Data System (ADS)

    Parizot, Etienne

    We investigate the spallative production of the light elements (Li, Be and B) associated with the evolution of a superbubble (SB) blown by repeated supernova explosions in an OB association. It is shown that if about ten percent of the SN energy can power the acceleration of particles from the material inside the SB, the observed abundances of LiBeB in halo stars, as a function of O, can be explained in a fully consistent way over several decades of metallicity. We investigate two different energy spectra for the EPs: the standard cosmic ray source spectrum and a specific `SB spectrum' as results from Bykov's SB acceleration mechanism. We find that the latter spectrum is more efficient in producing LiBeB, and that the SNR spectrum can be reconciled with the observational data if an imperfect mixing of the SN ejecta with the rest of the SB material and/or a selective acceleration is invoked (enhancing the C and O abundance amongst the EPs by a factor of ˜ 6). One consequence of the model is that the observed linear growth of Be and B abundances as a function of the metallicity expresses a dilution line rather than a continuous, monotonic increase throughout the Galaxy. We also find that the recent 6 Li observations in halo stars fit equally well in the framework of the SB model (see Parizot & Drury, 1999c, for more details).

  17. Spallation Neutron Source Accident Terms for Environmental Impact Statement Input

    SciTech Connect

    Devore, J.R.; Harrington, R.M.

    1998-08-01

    This report is about accidents with the potential to release radioactive materials into the environment surrounding the Spallation Neutron Source (SNS). As shown in Chap. 2, the inventories of radioactivity at the SNS are dominated by the target facility. Source terms for a wide range of target facility accidents, from anticipated events to worst-case beyond-design-basis events, are provided in Chaps. 3 and 4. The most important criterion applied to these accident source terms is that they should not underestimate potential release. Therefore, conservative methodology was employed for the release estimates. Although the source terms are very conservative, excessive conservatism has been avoided by basing the releases on physical principles. Since it is envisioned that the SNS facility may eventually (after about 10 years) be expanded and modified to support a 4-MW proton beam operational capability, the source terms estimated in this report are applicable to a 4-MW operating proton beam power unless otherwise specified. This is bounding with regard to the 1-MW facility that will be built and operated initially. See further discussion below in Sect. 1.2.

  18. Mechanical Engineering of the Linac for the Spallation Neutron Source

    SciTech Connect

    Bultman, N.K.; Chen, Z.; Collier, M.; Erickson, J.L.; Guthrie, A.; Hunter, W.T.; Ilg, T.; Meyer, R.K.; Snodgrass, N.L.

    1999-03-29

    The linac for the Spallation Neutron Source (SNS) Project will accelerate an average current of 1 mA of H{sup {minus}} ions from 20 MeV to 1GeV for injection into an accumulator ring. The linac will be an intense source of H{sup {minus}} ions and as such requires advanced design techniques to meet project technical goals as well as to minimize costs. The DTL, CCDTL and CCL are 466m long and operate at 805 MHz with a maximum H{sup {minus}} input current of 28 mA and 7% rf duty factor. The Drift Tube Linac is a copper-plated steel structure using permanent magnetic quadrupoles. The Coupled-Cavity portions are brazed copper structures and use electromagnetic quads. RF losses in the copper are 80 MW, with total rf power supplied by 52 klystrons. Additionally, the linac is to be upgraded to the 2- and 4-MW beam power levels with no increase in duty factor. The authors give an overview of the linac mechanical engineering effort and discuss the special challenges and status of the effort.

  19. Superconducting Prototype Cavities for the Spallation Neutron Source (SNS) Project

    SciTech Connect

    Peter Kneisel; John Brawley; Richard Bundy; Gianluigi Ciovati; Kurt Macha; Danny Machie; John Mammosser; Ron Sundelin; Larry Turlington; Katherine Wilson; J. Sekutowicz; D. Barni; C. Pagani; R. Parodi; P. Pierini; D. Schrage; M. Doleans; S.H. Kim; D. Mangra; P. Ylae-Oijala

    2001-06-01

    The Spallation Neutron Source project includes a superconducting linac section in the energy range from 192 MeV to 1000 MeV. For this energy range two types of cavities are needed with geometrical beta - values of beta = 0.61 and beta = 0.81. An aggressive cavity prototyping program is being pursued at Jlab, which calls for fabricating and testing of four beta = 0.61 cavities and two beta = 0.81 cavities. Both types consist of six cells made from high purity niobium and feature one HOM coupler of the TESLA type on each beam pipe and a port for a high power coaxial input coupler. Three of the four beta = 0.61 cavities will be used for a cryomodule test at the end of the year 2001. At this time two cavities of each type have been fabricated and the first tests on the beta = 0.61 cavity exceeded the design values for gradient and Q - value: Eacc = 10.3 MV/m and Q = 6.5 x 10{sup 9} at 2.1K. This paper will describe the cavity design with respect to electrical and mechanical features, the fabrication efforts and the results obtained with the different cavities existing at the time of the conference.

  20. The cryomodule test stand at the European Spallation Source

    SciTech Connect

    Hees, W.; Weisend II, J. G.; Wang, X. L.; Köttig, T.

    2014-01-29

    The European Spallation Source (ESS) is an intergovernmental project building a multidisciplinary research laboratory based upon the world's most powerful neutron source to be built in Lund, Sweden. The ESS will use a linear accelerator which will deliver protons with 5 MW of power to the target at 2.5 GeV with a nominal current of 50 mA. The superconducting part of the linac consists of over 150 niobium cavities cooled with superfluid helium at 2 K. A dedicated cryoplant will supply the cryomodules with single phase helium through an external cryogenic transfer line. The elliptical cavity cryomodules will undergo their site acceptance tests at the ESS cryomodule test stand in Lund. This test stand will use a 4.5 K cryoplant and warm sub-atmospheric compression to supply the 2 K helium. We will show the requirements for the test stand, a layout proposal and discuss the factors determining the required cryogenic capacity, test sequence and schedule.

  1. rf improvements for Spallation Neutron Source H- ion source.

    PubMed

    Kang, Y W; Fuja, R; Goulding, R H; Hardek, T; Lee, S-W; McCarthy, M P; Piller, M C; Shin, K; Stockli, M P; Welton, R F

    2010-02-01

    The Spallation Neutron Source at Oak Ridge National Laboratory is ramping up the accelerated proton beam power to 1.4 MW and just reached 1 MW. The rf-driven multicusp ion source that originates from the Lawrence Berkeley National Laboratory has been delivering approximately 38 mA H(-) beam in the linac at 60 Hz, 0.9 ms. To improve availability, a rf-driven external antenna multicusp ion source with a water-cooled ceramic aluminum nitride (AlN) plasma chamber is developed. Computer modeling and simulations have been made to analyze and optimize the rf performance of the new ion source. Operational statistics and test runs with up to 56 mA medium energy beam transport beam current identify the 2 MHz rf system as a limiting factor in the system availability and beam production. Plasma ignition system is under development by using a separate 13 MHz system. To improve the availability of the rf power system with easier maintenance, we tested a 70 kV isolation transformer for the 80 kW, 6% duty cycle 2 MHz amplifier to power the ion source from a grounded solid-state amplifier. PMID:20192394

  2. Investigation of the optimal material type and dimension for spallation targets using simulation methods

    NASA Astrophysics Data System (ADS)

    Feghhi, Seyed Amir Hossein; Gholamzadeh, Zohreh; Tenreiro, Claudio

    2014-01-01

    Accelerator-driven systems are extensively developed to generate neutron sources for research, industrial, and medical plans. Different heavy elements are utilized as spallation targets to produce spallation neutrons. Computational methods are efficiently utilized to simulate neutronic behavior of a spallation target. MCNPX 2.6.0 is used as a powerful code based on Monte Carlo stochastic techniques for spallation process computation. This code has the ability to transport different particles using different physical models. In this paper, MCNPX has been utilized to calculate the leaked neutron yield from Pb, lead-bismuth eutectic (LBE), W, Ta, Hg, U, Th, Sn, and Cu cylindrical heavy targets. The effects of the target thickness and diameter on neutron yield value have been investigated via the thickness and diameter variations between 5 to 30 cm and 5 to 20 cm, respectively. Proton-induced radionuclide production into the targets as well as leaked neutron spectra from the targets has been calculated for the targets of an optimum determined dimension. The 1-GeV proton particle has been selected to induce spallation process inside the targets. The 2-mm spatial FWHM distribution has been considered for the 1-mA proton beam. Uranium target produced the highest leaked neutron yield with a 1.32 to 3.7 factor which overweighs the others. A dimension of 15 × 60 cm is suggested for all the cylindrical studied spallation targets. Th target experienced the highest alpha emitter radionuclide production while lighter elements such as Cu and Sn bore the lowest radiotoxicity. LBE liquid spallation target competes with the investigated solid targets in neutronic point of view while has surpass than volatile liquid Hg target.

  3. Investigation of the optimal material type and dimension for spallation targets using simulation methods

    NASA Astrophysics Data System (ADS)

    Feghhi, S. A. H.; Gholamzadeh, Z.; Tenreiro, C.

    2014-03-01

    Accelerator-driven systems are extensively developed to generate neutron sources for research, industrial and medical plans. Different heavy elements are utilized as spallation targets to produce spallation neutrons. Computational methods are efficiently utilized to simulate neutronic behavior of a spallation target. MCNPX 2.6.0 is used as a powerful code based on Monte Carlo stochastic techniques for spallation process computation. This code has the ability to transport different particles using different physical models. In this paper, MCNPX has been utilized to calculate the leaked neutron yield from Pb, LBE, W, Ta, Hg, U, Th, Sn and Cu cylindrical heavy targets. Effects of the target thickness and diameter on neutron yield value have been investigated via the thickness and diameter variations between 5-30 and 5-20 cm, respectively. Proton-induced radionuclide production into the targets as well as leaked neutron spectra from the targets has been calculated for the targets of an optimum determined dimension. 1 GeV proton particle has been selected to induce spallation process inside the targets. 2 mm spatial FWHM distribution has been considered for the 1 mA proton beam. Uranium target produced the highest leaked neutron yield with a 1.32-3.7 factor overweigh the others. Dimension of 15 × 60 cm is suggested for all the cylindrical studied spallation targets. Th target experienced the highest alpha-emitter radionuclide production while lighter elements such as Cu and Sn bore the lowest radio-toxicity. LBE liquid spallation target competes with the investigated solid targets in neutronic point of view while has surpass than volatile liquid Hg target.

  4. Electrochemical characterization of chromia- and alumina-forming nickel-based superalloys in molten silicates

    NASA Astrophysics Data System (ADS)

    Abdullah, Tuti Katrina; Petitjean, Carine; Panteix, Pierre-Jean; Mathieu, Stéphane; Rapin, Christophe; Vilasi, Michel; Hussain, Zuhailawati; Rahim, Afidah Abdul

    2016-01-01

    A comparison of the corrosion behaviour of simplified chromia- and alumina-forming alloys (Ni-30Cr and Ni-8Al-28Cr) in molten glass is performed via electrochemical methods. A pre-oxidation treatment in air prior to immersion ensured the formation of a 2-μm-thick oxide scale of Cr2O3 or Al2O3. The lifetime of Ni-30Cr depended on the competition between the oxide growth and its dissolution in the melt. For Ni-8Al-28Cr, the high solubility of alumina in the melt studied here led to severe aluminium loss in a few minutes and clearly demonstrated the higher efficiency of chromia-forming alloys for molten glass applications.

  5. Direct Visualization of the Hydration Layer on Alumina Nanoparticles with the Fluid Cell STEM in situ

    PubMed Central

    Firlar, Emre; Çınar, Simge; Kashyap, Sanjay; Akinc, Mufit; Prozorov, Tanya

    2015-01-01

    Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration layer on alumina nanoparticles in water was hypothesized, but never observed experimentally. We report here on the direct visualization of aqueous suspensions of alumina with the fluid cell in situ. We observe the hydration layer formed over the particle aggregates and show that such hydrated aggregates constitute new particle assemblies and affect the flow behavior of the suspensions. We discuss how these hydrated nanoclusters alter the effective solid content and the viscosity of nanostructured suspensions. Our findings elucidate the source of high viscosity observed for nanoparticle suspensions and are of direct relevance to many industrial sectors including materials, food, cosmetics, pharmaceutical among others employing colloidal slurries with nanometer-scale particles. PMID:25996055

  6. Microstructural and Mechanical Characterization of Actively Brazed Alumina Specimens

    SciTech Connect

    Hosking, F.M.; Cadden, C.H.; Stephens, J.J.; Glass, S.J.; Yang, N.Y.C.; Vianco, P.V.; Walker, C.A.

    1999-08-26

    Alumina (94 and 99.8% grade compositions) was brazed directly to itself with gold-based active brazing alloys (ABA's) containing vanadium additions of 1,2 and 3 weight percent. The effects of brazing conditions on the joint properties were investigated. Wetting behavior, interfacial reactions, microstructure, hermeticity and tensile strength were determined. Wetting was fair to good for the ABA and base material combinations. Microanalysis identified a discontinuous Al-V-O spinel reaction product at the alumina-braze interface. Tensile strength results for 94% alumina were uniformly good and generally not sensitive to the vanadium concentration, with tensile values of 85-105 MPa. There was more variability in the 99.8% alumina strength results, with values ranging from 25-95 MPa. The highest vanadium concentration (3 wt. %) yielded the highest joint strength for the brazed 99.8% alumina. Failures in the 99.8% alumina samples occurred at the braze-alumina interface, while the 94% alumina specimens exhibited fracture of the ceramic substrate.

  7. Dynamic compressive and tensile strengths of spark plasma sintered alumina

    NASA Astrophysics Data System (ADS)

    Girlitsky, I.; Zaretsky, E.; Kalabukhov, S.; Dariel, M. P.; Frage, N.

    2014-06-01

    Fully dense submicron grain size alumina samples were manufactured from alumina nano-powder using Spark Plasma Sintering and tested in two kinds of VISAR-instrumented planar impact tests. In the first kind, samples were loaded by 1-mm tungsten impactors, accelerated to a velocity of about 1 km/s. These tests were aimed at studying the Hugoniot elastic limit (HEL) of Spark Plasma Sintering (SPS)-processed alumina and the decay, with propagation distance, of the elastic precursor wave. In the tests of the second kind, alumina samples of 3-mm thickness were loaded by 1-mm copper impactors accelerated to 100-1000 m/s. These tests were aimed at studying the dynamic tensile (spall) strength of the alumina specimens. The tensile fracture of the un-alloyed alumina shows a monotonic decline of the spall strength with the amplitude of the loading stress pulse. Analysis of the decay of the elastic precursor wave allowed determining the rate of the irreversible (inelastic) strains in the SPS-processed alumina at the initial stages of the shock-induced inelastic deformation and to clarify the mechanisms responsible for the deformation. The 1-% addition of Cr2O3 decreases the HEL of the SPS-processed alumina by 5-% and its spall strength by 50% but barely affects its static properties.

  8. Depositing Adherent Ag Films On Ti Films On Alumina

    NASA Technical Reports Server (NTRS)

    Honecy, Frank S.

    1995-01-01

    Report discusses cleaning of ceramic (principally, alumina) substrates in preparation for sputter deposition of titanium intermediate films on substrates followed by sputter deposition of outer silver films. Principal intended application, substrates sliding parts in advanced high-temperature heat engines, and outer silver films serve as solid lubricants: lubricating properties described in "Solid Lubricant for Alumina" (LEW-15495).

  9. Dynamic compressive and tensile strengths of spark plasma sintered alumina

    SciTech Connect

    Girlitsky, I.; Zaretsky, E.; Kalabukhov, S.; Dariel, M. P.; Frage, N.

    2014-06-28

    Fully dense submicron grain size alumina samples were manufactured from alumina nano-powder using Spark Plasma Sintering and tested in two kinds of VISAR-instrumented planar impact tests. In the first kind, samples were loaded by 1-mm tungsten impactors, accelerated to a velocity of about 1 km/s. These tests were aimed at studying the Hugoniot elastic limit (HEL) of Spark Plasma Sintering (SPS)-processed alumina and the decay, with propagation distance, of the elastic precursor wave. In the tests of the second kind, alumina samples of 3-mm thickness were loaded by 1-mm copper impactors accelerated to 100–1000 m/s. These tests were aimed at studying the dynamic tensile (spall) strength of the alumina specimens. The tensile fracture of the un-alloyed alumina shows a monotonic decline of the spall strength with the amplitude of the loading stress pulse. Analysis of the decay of the elastic precursor wave allowed determining the rate of the irreversible (inelastic) strains in the SPS-processed alumina at the initial stages of the shock-induced inelastic deformation and to clarify the mechanisms responsible for the deformation. The 1-% addition of Cr{sub 2}O{sub 3} decreases the HEL of the SPS-processed alumina by 5-% and its spall strength by 50% but barely affects its static properties.

  10. Process for the recovery of alumina from fly ash

    DOEpatents

    Murtha, M.J.

    1983-08-09

    An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

  11. 40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this...

  12. 40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this...

  13. Scales

    ScienceCinema

    Murray Gibson

    2010-01-08

    Musical scales involve notes that, sounded simultaneously (chords), sound good together. The result is the left brain meeting the right brain ? a Pythagorean interval of overlapping notes. This synergy would suggest less difference between the working of the right brain and the left brain than common wisdom would dictate. The pleasing sound of harmony comes when two notes share a common harmonic, meaning that their frequencies are in simple integer ratios, such as 3/2 (G/C) or 5/4 (E/C).

  14. Scales

    SciTech Connect

    Murray Gibson

    2007-04-27

    Musical scales involve notes that, sounded simultaneously (chords), sound good together. The result is the left brain meeting the right brain — a Pythagorean interval of overlapping notes. This synergy would suggest less difference between the working of the right brain and the left brain than common wisdom would dictate. The pleasing sound of harmony comes when two notes share a common harmonic, meaning that their frequencies are in simple integer ratios, such as 3/2 (G/C) or 5/4 (E/C).

  15. Determination and evaluation of organic balances of alumina refineries

    SciTech Connect

    Solymar, K.; Gimpel-Kazar, M.; Molnar, E.

    1996-10-01

    The adequate measures to control the organic level and especially that of humates and oxalate need the determination and evaluation of the organic balance of the given alumina plant. The organic materials of the different alumina refineries have special compositions, therefore it is very difficult and limited to draw general and common conclusions for all alumina refineries concerning the role and control of organics. The methodology of the determination of the organic balance of an alumina plant will be discussed. The qualitative and quantitative determination of organic materials has been performed by means of gas-chromatography of the esterized organic materials. The organic balances of three different alumina refineries will be compared and evaluated relating to the total organic and oxalate contents.

  16. Morphology and transmittance of porous alumina on glass substrate

    NASA Astrophysics Data System (ADS)

    Peitao, Guo; Zhilin, Xia; Yiyu, Xue; Caihua, Huang; Lixin, Zhao

    2011-02-01

    The porous optical film has higher threshold of laser-induced damage than densified films, for the study of mechanism of laser-induced damage of porous optical film with ordered pore structure. Porous anodic alumina (PAA) film with high transmittance on glass substrate has been prepared. Aluminum film was deposited on glass substrate by means of resistance and electron beam heat (EBH) evaporation. Porous alumina was prepared in oxalic acid solution under different anodizing conditions. At normal incidence, the optical transmittance spectrum over 300-1000 nm spectra region was obtained by spectrophotometer. SEM was introduced to analysis the morphology of the porous alumina film. The pore aperture increased with the increase of anodizing voltage, which resulted in a rapid decrease of the pore concentration and the optical thickness of porous alumina film. Damage morphology of porous alumina film is found to be typically defects initiated, and the defect is the pore presented on the film.

  17. The mineralogy of bauxite for producing smelter-grade alumina

    NASA Astrophysics Data System (ADS)

    Authier-Martin, M.; Forte, G.; Ostap, S.; See, J.

    2001-12-01

    Aluminum-producing companies rely on low-cost, high-purity, smelter-grade alumina (aluminum oxide), and alumina production utilizes the bulk of bauxites mined world-wide. The mineralogy of the bauxites has a significant impact on the operation of the Bayer process for alumina production. Typically, the Bayer process produces smelter-grade alumina of 99.5% Al2O3, starting from bauxite containing 30% to 60% Al2O3. The main objective of the Bayer process is to extract the maximum amount of aluminum from the bauxite at as high an aluminate concentration in solution as possible, while limiting any troublesome side reactions. Only with a better understanding of the chemistry of the mineral species and a strict control of the operating/processing conditions can the Bayer process produce efficiently, a low cost, high-quality alumina with minimum detrimental environmental impact.

  18. Thermal Conductivity of Alumina-reinforced Zirconia Composites

    NASA Technical Reports Server (NTRS)

    Bansal, Narottam P.

    2005-01-01

    10-mol% yttria-stabilized zirconia (10SZ) - alumina composites containing 0-30 mol% alumina were fabricated by hot pressing at 1500 C in vacuum. Thermal conductivity was determined at various temperatures using a steady-state laser heat flux technique. Thermal conductivity of the composites increased with increase in alumina content. Composites containing 0, 5, and 10-mol% alumina did not show any change in thermal conductivity with temperature. However, those containing 20 and 30-mol% alumina showed a decrease in thermal conductivity with increase in temperature. The measured values of thermal conductivity were in good agreement with those calculated from the Maxwell-Eucken model where one phase is uniformly dispersed within a second major continuous phase.

  19. Properties of Transition Metal Doped Alumina

    NASA Astrophysics Data System (ADS)

    Nykwest, Erik; Limmer, Krista; Brennan, Ray; Blair, Victoria; Ramprasad, Rampi

    Crystallographic texture can have profound effects on the properties of a material. One method of texturing is through the application of an external magnetic field during processing. While this method works with highly magnetic systems, doping is required to couple non-magnetic systems with the external field. Experiments have shown that low concentrations of rare earth (RE) dopants in alumina powders have enabled this kind of texturing. The magnetic properties of RE elements are directly related to their f orbital, which can have as many as 7 unpaired electrons. Since d-block elements can have as many as 5 unpaired electrons the effects of substitutional doping of 3d transition metals (TM) for Al in alpha (stable) and theta (metastable) alumina on the local structure and magnetic properties, in addition to the energetic cost, have been calculated by performing first-principles calculations based on density functional theory. This study has led to the development of general guidelines for the magnetic moment distribution at and around the dopant atom, and the dependence of this distribution on the dopant atom type and its coordination environment. It is anticipated that these findings can aid in the selection of suitable dopants help to guide parallel experimental efforts. This project was supported in part by an internship at the Army Research Laboratory, administered by the Oak Ridge Institute for Science and Education, along with a grant of computer time from the DoD High Performance Computing Modernization Program.

  20. Combination for electrolytic reduction of alumina

    DOEpatents

    Brown, Craig W.; Brooks, Richard J.; Frizzle, Patrick B.; Juric, Drago D.

    2002-04-30

    An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises molten electrolyte having the following ingredients: AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound is, a fluoride; oxide, or carbonate. The metal is nickel, iron, copper, cobalt, or molybdenum. The bath is employed in a combination including a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the instant bath during electrolytic reduction of alumina to aluminum improves the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode.

  1. Initial observations of cavitation-induced erosion of liquid metal spallation target vessels at the Spallation Neutron Source

    NASA Astrophysics Data System (ADS)

    McClintock, D. A.; Riemer, B. W.; Ferguson, P. D.; Carroll, A. J.; Dayton, M. J.

    2012-12-01

    During operation of the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory the mechanical properties of the AISI 316L target module are altered by high-energy neutron and proton radiation. The interior surfaces of the target vessel are also damaged by cavitation-induced erosion, which results from repetitive rapid heating of the liquid mercury by high-energy proton beam pulses. Until recently no observations of cavitation-induced erosion were possible for conditions fully prototypic to the SNS. Post-Irradiation Examination (PIE) of the first and second operational SNS targets was performed to gain insight into the radiation-induced changes in mechanical properties of the 316L target material and the extent of cavitation-induced erosion to the mercury vessel inner surfaces. Observations of cavitation-induced erosion of the first and second operational SNS target modules are presented here, including images of the target vessel interiors and specimens removed from the target beam-entrance regions.

  2. Parsing abnormal grain growth in specialty aluminas

    NASA Astrophysics Data System (ADS)

    Lawrence, Abigail Kremer

    Grain growth in alumina is strongly affected by the impurities present in the material. Certain impurity elements are known to have characteristic effects on abnormal grain growth in alumina. Specialty alumina powders contain multiple impurity species including MgO, CaO, SiO2, and Na 2O. In this work, sintered samples made from alumina powders containing various amounts of the impurities in question were characterized by their grain size and aspect ratio distributions. Multiple quantitative methods were used to characterize and classify samples with varying microstructures. The grain size distributions were used to partition the grain size population into subpopulations depending on the observed deviation from normal behavior. Using both grain size and aspect ratio a new visual representation for a microstructure was introduced called a morphology frequency map that gives a fingerprint for the material. The number of subpopulations within a sample and the shape of the distribution on the morphology map provided the basis for a classification scheme for different types of microstructures. Also using the two parameters a series of five metrics were calculated that describe the character of the abnormal grains in the sample, these were called abnormal character values. The abnormal character values describe the fraction of grains that are considered abnormal, the average magnitude of abnormality (including both grain size and aspect ratio), the average size, and variance in size. The final metric is the correlation between grain size and aspect ratio for the entire population of grains. The abnormal character values give a sense of how different from "normal" the sample is, given the assumption that a normal sample has a lognormal distribution of grain size and a Gaussian distribution of aspect ratios. In the second part of the work the quantified measures of abnormality were correlated with processing parameters such as composition and heat treatment conditions. A

  3. Final report on the application of chaos theory to an alumina sensor for aluminum reduction cells

    SciTech Connect

    Williford, R.E.; Windisch, C.F. Jr.

    1992-03-01

    Four chaos-related digital signal analysis (DSA) methods were applied to the analysis of voltage and current signals collected from aluminum electrolysis cells. Two separate data bases were analyzed: bench-scale laboratory experiments and a pilot-scale test. The objective was to assess the feasibility of using these types of data and analysis methods as the basis for a non-intrusive sensor to measure the alumina content in the electrolysis bath. This was the first time chaos theory approaches have been employed to analyze aluminum electrolysis cells.

  4. Finite element simulation of the film spallation process induced by the pulsed laser peening

    NASA Astrophysics Data System (ADS)

    Zhou, M.; Zeng, D. Y.; Kan, J. P.; Zhang, Y. K.; Cai, L.; Shen, Z. H.; Zhang, X. R.; Zhang, S. Y.

    2003-09-01

    The laser spallation technique for measuring the interface strength between a coating and a substrate is similar to laser shock peening, in which the stress wave induced by laser shock cause debond on the interface between a hard coating with micron thickness and a metal substrate. According to the modified experiment setup of the laser spallation technique, finite element analysis simulated the process of the film spallation by taking the laser loading as a direct input. We presented a numerical model of finite element that the laser spallation process includes two related, but uncoupled procedures. One was transient heat transfer in a two-layer medium. The other was the related transient elastic wave propagation in the same two-layer media, which was the result of the thermal misfit by transient heating. Based on the threshold of film spallation, we analyzed the process of laser shocking to study the propagation of stress wave and evaluate the spall resistance of sputtered films. The analysis result showed the dynamic adhesive strength of the interface between the TiN coating and the 304 stainless steel substrate was 193.0 MPa.

  5. 5 MW pulsed spallation neutron source, Preconceptual design study

    SciTech Connect

    Not Available

    1994-06-01

    This report describes a self-consistent base line design for a 5 MW Pulsed Spallation Neutron Source (PSNS). It is intended to establish feasibility of design and as a basis for further expanded and detailed studies. It may also serve as a basis for establishing project cost (30% accuracy) in order to intercompare competing designs for a PSNS not only on the basis of technical feasibility and technical merit but also on the basis of projected total cost. The accelerator design considered here is based on the objective of a pulsed neutron source obtained by means of a pulsed proton beam with average beam power of 5 MW, in {approx} 1 {mu}sec pulses, operating at a repetition rate of 60 Hz. Two target stations are incorporated in the basic facility: one for operation at 10 Hz for long-wavelength instruments, and one operating at 50 Hz for instruments utilizing thermal neutrons. The design approach for the proton accelerator is to use a low energy linear accelerator (at 0.6 GeV), operating at 60 Hz, in tandem with two fast cycling booster synchrotrons (at 3.6 GeV), operating at 30 Hz. It is assumed here that considerations of cost and overall system reliability may favor the present design approach over the alternative approach pursued elsewhere, whereby use is made of a high energy linear accelerator in conjunction with a dc accumulation ring. With the knowledge that this alternative design is under active development, it was deliberately decided to favor here the low energy linac-fast cycling booster approach. Clearly, the present design, as developed here, must be carried to the full conceptual design stage in order to facilitate a meaningful technology and cost comparison with alternative designs.

  6. The COHERENT Experiment at the Spallation Neutron Source

    SciTech Connect

    Elliott, Steven Ray

    2015-09-30

    The COHERENT collaboration's primary objective is to measure coherent elastic neutrino- nucleus scattering (CEvNS) using the unique, high-quality source of tens-of-MeV neutrinos provided by the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL). In spite of its large cross section, the CEvNS process has never been observed, due to tiny energies of the resulting nuclear recoils which are out of reach for standard neutrino detectors. The measurement of CEvNS has now become feasible, thanks to the development of ultra-sensitive technology for rare decay and weakly-interacting massive particle (dark matter) searches. The CEvNS cross section is cleanly predicted in the standard model; hence its measurement provides a standard model test. It is relevant for supernova physics and supernova-neutrino detection, and enables validation of dark-matter detector background and detector-response models. In the long term, precision measurement of CEvNS will address questions of nuclear structure. COHERENT will deploy multiple detector technologies in a phased approach: a 14-kg CsI[Na] scintillating crystal, 15 kg of p-type point-contact germanium detectors, and 100 kg of liquid xenon in a two-phase time projection chamber. Following an extensive background measurement campaign, a location in the SNS basement has proven to be neutron-quiet and suitable for deployment of the COHERENT detector suite. The simultaneous deployment of the three COHERENT detector subsystems will test the N=2 dependence of the cross section and ensure an unambiguous discovery of CEvNS. This document describes concisely the COHERENT physics motivations, sensitivity and plans for measurements at the SNS to be accomplished on a four-year timescale.

  7. Modeling astatine production in liquid lead-bismuth spallation targets

    NASA Astrophysics Data System (ADS)

    David, J. C.; Boudard, A.; Cugnon, J.; Ghali, S.; Leray, S.; Mancusi, D.; Zanini, L.

    2013-03-01

    Astatine isotopes can be produced in liquid lead-bismuth eutectic targets through proton-induced double charge exchange reactions on bismuth or in secondary helium-induced interactions. Models implemented into the most common high-energy transport codes generally have difficulties to correctly estimate their production yields as was shown recently by the ISOLDE Collaboration, which measured release rates from a lead-bismuth target irradiated by 1.4 and 1 GeV protons. In this paper, we first study the capability of the new version of the Liège intranuclear cascade model, INCL4.6, coupled to the deexcitation code ABLA07 to predict the different elementary reactions involved in the production of such isotopes through a detailed comparison of the model with the available experimental data from the literature. Although a few remaining deficiencies are identified, very satisfactory results are found, thanks in particular to improvements brought recently on the treatment of low-energy helium-induced reactions. The implementation of the models into MCNPX allows identifying the respective contributions of the different possible reaction channels in the ISOLDE case. Finally, the full simulation of the ISOLDE experiment is performed, taking into account the likely rather long diffusion time from the target, and compared with the measured diffusion rates for the different astatine isotopes, at the two studied energies, 1.4 and 1 GeV. The shape of the isotopic distribution is perfectly reproduced as well as the absolute release rates, assuming in the calculation a diffusion time between 5 and 10hours. This work finally shows that our model, thanks to the attention paid to the emission of high-energy clusters and to low-energy cluster induced reactions, can be safely used within MCNPX to predict isotopes with a charge larger than that of the target by two units in spallation targets, and, probably, more generally to isotopes created in secondary reactions induced by composite

  8. Superconducting Prototype Cavities for the Spallation Neutron Source (SNS) Project

    SciTech Connect

    Gianluigi Ciovati

    2001-09-01

    The Spallation Neutron Source project includes a superconducting linac section in the energy range from 186 MeV to 1000 MeV. For this energy range two types of cavities are needed with geometrical {beta} values of {beta} = 0.61 and {beta} = 0.81. An aggressive cavity prototyping program is being pursued at Jefferson Lab, which calls for fabricating and testing four {beta} = 0.61 cavities and two {beta} = 0.81 cavities. Both types consist of six cells made from high purity niobium and feature one HOM coupler on each beam pipe and a port for a high power coaxial input coupler. Three of the four {beta} = 0.61 cavities will be used for a cryomodule test in early 2002. At this time four medium beta cavities and one high beta cavity have been completed at JLab. The first tests on the {beta} = 0.61 and {beta} = 0.81 exceeded the design values for gradient and Q value: E{sub acc} = 10.1 MV/m and Q = 5 x 10{sup 9} at 2.1K for the {beta} = 0.61 and E{sub acc} = 12.3 MV/m and Q = 5 x 10{sup 9} at 2.1 K for the {beta} = 0.81. One of the medium beta cavities has been equipped with an integrated helium vessel and measurements of the static Lorentz force detuning have been done and compared to the ''bare'' cavities. In addition two single cell cavities have been fabricated, equipped with welded-on HOM couplers. They are being used to evaluate the HOM couplers with respect to multipacting, fundamental mode rejection and HOM damping as far as possible in a single cell. This paper describes the cavity design with respect to electromagnetic and mechanical features, the fabrication efforts and the results obtained with the different cavities existing at the time of this workshop.

  9. H- radio frequency source development at the Spallation Neutron Source

    SciTech Connect

    Welton, Robert F; Pennisi, Terry R; Roseberry, Ron T; Stockli, Martin P

    2012-01-01

    The Spallation Neutron Source (SNS) now routinely operates nearly 1 MW of beam power on target with a highly persistent {approx}38 mA peak current in the linac and an availability of {approx}90%. H{sup -} beam pulses ({approx}1 ms, 60 Hz) are produced by a Cs-enhanced, multicusp ion source closely coupled with an electrostatic low energy beam transport (LEBT), which focuses the 65 kV beam into a radio frequency quadrupole accelerator. The source plasma is generated by RF excitation (2 MHz, {approx}60 kW) of a copper antenna that has been encased with a thickness of {approx}0.7 mm of porcelain enamel and immersed into the plasma chamber. The ion source and LEBT normally have a combined availability of {approx}99%. Recent increases in duty-factor and RF power have made antenna failures a leading cause of downtime. This report first identifies the physical mechanism of antenna failure from a statistical inspection of {approx}75 antennas which ran at the SNS, scanning electron microscopy studies of antenna surface, and cross sectional cuts and analysis of calorimetric heating measurements. Failure mitigation efforts are then described which include modifying the antenna geometry and our acceptance/installation criteria. Progress and status of the development of the SNS external antenna source, a long-term solution to the internal antenna problem, are then discussed. Currently, this source is capable of delivering comparable beam currents to the baseline source to the SNS and, an earlier version, has briefly demonstrated unanalyzed currents up to {approx}100 mA (1 ms, 60 Hz) on the test stand. In particular, this paper discusses plasma ignition (dc and RF plasma guns), antenna reliability, magnet overheating, and insufficient beam persistence.

  10. H- radio frequency source development at the Spallation Neutron Sourcea)

    NASA Astrophysics Data System (ADS)

    Welton, R. F.; Dudnikov, V. G.; Gawne, K. R.; Han, B. X.; Murray, S. N.; Pennisi, T. R.; Roseberry, R. T.; Santana, M.; Stockli, M. P.; Turvey, M. W.

    2012-02-01

    The Spallation Neutron Source (SNS) now routinely operates nearly 1 MW of beam power on target with a highly persistent ˜38 mA peak current in the linac and an availability of ˜90%. H- beam pulses (˜1 ms, 60 Hz) are produced by a Cs-enhanced, multicusp ion source closely coupled with an electrostatic low energy beam transport (LEBT), which focuses the 65 kV beam into a radio frequency quadrupole accelerator. The source plasma is generated by RF excitation (2 MHz, ˜60 kW) of a copper antenna that has been encased with a thickness of ˜0.7 mm of porcelain enamel and immersed into the plasma chamber. The ion source and LEBT normally have a combined availability of ˜99%. Recent increases in duty-factor and RF power have made antenna failures a leading cause of downtime. This report first identifies the physical mechanism of antenna failure from a statistical inspection of ˜75 antennas which ran at the SNS, scanning electron microscopy studies of antenna surface, and cross sectional cuts and analysis of calorimetric heating measurements. Failure mitigation efforts are then described which include modifying the antenna geometry and our acceptance/installation criteria. Progress and status of the development of the SNS external antenna source, a long-term solution to the internal antenna problem, are then discussed. Currently, this source is capable of delivering comparable beam currents to the baseline source to the SNS and, an earlier version, has briefly demonstrated unanalyzed currents up to ˜100 mA (1 ms, 60 Hz) on the test stand. In particular, this paper discusses plasma ignition (dc and RF plasma guns), antenna reliability, magnet overheating, and insufficient beam persistence.

  11. Terbium luminescence in alumina xerogel fabricated in porous anodic alumina matrix under various excitation conditions

    SciTech Connect

    Gaponenko, N. V.; Kortov, V. S.; Orekhovskaya, T. I.; Nikolaenko, I. A.; Pustovarov, V. A.; Zvonarev, S. V.; Slesarev, A. I.; Prislopski, S. Ya.

    2011-07-15

    Terbium-doped alumina xerogel layers are synthesized by the sol-gel method in pores of a porous anodic alumina film 1 {mu}m thick with a pore diameter of 150-180 nm; the film is grown on a silicon substrate. The fabricated structures exhibit terbium photoluminescence with bands typical of trivalent terbium terms. Terbium X-ray luminescence with the most intense band at 542 nm is observed for the first time for such a structure. Morphological analysis of the structure by scanning electron microscopy shows the presence of xerogel clusters in pore channels, while the main pore volume remains unfilled and pore mouths remain open. The data obtained confirm the promising applications of fabricated structures for developing matrix converters of X-rays and other ionizing radiations into visible light. The possibilities of increasing luminescence intensity in the matrix converter are discussed.

  12. On the material and the tribology of alumina-alumina couplings for hip joint prostheses.

    PubMed

    Walter, A

    1992-09-01

    The yearly sphericity deviation ranged from 0.03 mu to 3.7 mm in 48 retrieved implants with alumina--alumina bearing balls and cups. Excessive amounts of wear are predominantly design dependent or caused by malalignment. But the abrasion phenomena occurring in the cup centers and in the corresponding ball areas are related to unfavorable function zones. The influence of the lubricating gap geometry as studied in laboratory tests shows the form of sphericity deviations to be of decisive importance for wear and friction, if extended over small angles. Then, the contact stresses attributable to the actual effective curvatures of the bearing exceed the resistance to abrasion of the material under boundary lubrication conditions. There are remarkable differences between the early and actual material quality. Based on the state of knowledge of material aspects of wear criteria for the optimization of material and design, promising tolerable wear rates may be achieved. PMID:1516324

  13. Processing and mechanical characterization of alumina laminates

    NASA Astrophysics Data System (ADS)

    Montgomery, John K.

    2002-08-01

    Single-phase ceramics that combine property gradients or steps in monolithic bodies are sought as alternatives to ceramic composites made of dissimilar materials. This work describes novel processing methods to produce stepped-density (or laminated) alumina single-phase bodies that maintain their mechanical integrity. One arrangement consists of a stiff, dense bulk material with a thin, flaw tolerant, porous exterior layer. Another configuration consists of a lightweight, low-density bulk material with a thin, hard, wear resistant exterior layer. Alumina laminates with strong interfaces have been successfully produced in this work using two different direct-casting processes. Gelcasting is a useful near-net shape processing technique that has been combined with several techniques, such as reaction bonding of aluminum oxide and the use of starch as a fugative filler, to successfully produced stepped-density alumina laminates. The other direct casting process that has been developed in this work is thermoreversible gelcasting (TRG). This is a reversible gelation process that has been used to produce near-net shape dense ceramic bodies. Also, individual layers can be stacked together and heated to produce laminates. Bilayer laminate samples were produced with varied thickness of porous and dense layers. It was shown that due to the difference in modulus and hardness, transverse cracking is found upon Hertzian contact when the dense layer is on the exterior. In the opposite arrangement, compacted damage zones formed in the porous material and no damage occurred in the underlying dense layer. Flaw tolerant behavior of the porous exterior/dense underlayer was examined by measuring biaxial strength as a function of Vickers indentation load. It was found that the thinnest layer of porous material results in the greatest flaw tolerance. Also, higher strength was exhibited at large indentation loads when compared to dense monoliths. The calculated stresses on the surfaces

  14. Oxidative Recession, Sulfur Release, and Al203 Spallation for Y-Doped Alloys

    NASA Technical Reports Server (NTRS)

    Smialek, James L.

    2001-01-01

    Second-order spallation phenomena have been noted for Y-doped Rene'N5 after long term oxidation at 1150 degrees C. The reason for this behavior has not been conclusively identified. A mass equivalence analysis has shown that the surface recession resulting from oxidation has the potential of releasing about 0.15 monolayer of sulfur for every 1 mg/sq cm of oxygen reacted for an alloy containing 5 ppmw of sulfur. This amount is significant in comparison to levels that have been shown to result in first-order spallation behavior for undoped alloys. Oxidative recession is therefore speculated to be a contributing source of sulfur and second-order spallation for Y-doped alloys.

  15. Fracture of the alumina-bearing couple delta ceramic liner.

    PubMed

    Taheriazam, Afshin; Mohajer, Mohammad Azizbaig; Aboulghasemian, Mansoour; Hajipour, Babak

    2012-01-01

    The fracture rate of third-generation ceramic liners is greatly reduced compared with first- and second-generation liners because of improvements in the design and manufacturing process. Fractures of the alumina-bearing couple are rare for the same reason.This article describes a case of a fracture of an alumina-bearing couple delta ceramic liner without trauma history that was treated with ceramic-on-polyethylene revision total hip arthroplasty. A 57-year-old man was admitted to the hip ward because of an alumina-bearing couple delta ceramic liner fracture. He underwent hip replacement by anterior approach 18 months previously in the same center because of left hip primary osteoarthritis. He received a 54×36-mm modular press-fit cup ceramic alumina-bearing couple delta insert. Probable causes of such fractures are manufacture production failure and edge loading based on cup inclination, but in our patient, inacceptable range of motion, failure of the locking mechanism during implantation insertion, or cracking were possible causes of fracture.Although the fracture rate of third-generation alumina-bearing couples is low, we believe that it may not be possible to eliminate the actual risk of alumina head fracture. Patients should be informed about the potential for this complication before receiving an alumina-bearing couple. PMID:22229622

  16. Essentials of specifications for activated alumina in defluoridation technology.

    PubMed

    Misra, S K

    2006-10-01

    Worldwide, fluoride occurs naturally in some aquifers at concentrations above the WHO guideline values or Bureau of Indian Standards or CPHEEO - MUD - GOI parametric values. Fluoride in excess of the permissible limits in drinking water causes a number of endemic conditions referred to collectively as "fluorosis". Endemic fluorosis remains a challenging national health problem in India and Rajasthan is one of the worst affected states in India though a wide range of chemical and physical defluoridation systems were evolved and tried. Still activated alumina is one of the most widely used and liked defluoridation material currently available. Boom in the advanced and versatile alumina technology has opened new vistas to avail the strong potential of selective alumina adsorbents which are application-specific. Non-regenerable and specialty alumina offer tremendous scope to defluoridate drinking water. Indian industries are manufacturing regenerable activated alumina for defluoridation of drinking water. In order to ensure application of an adsorbent, which caters the desired results with minimum interferences, health risks and long service life span, it is inevitable to draw out dimensions which define precisely the attributes of activated alumina. Specifications for activated alumina intended for defluoridation of drinking water, specific operating and performance requirements, and limitations expressed by critical analysis of cardinal characteristics pave way for adoption of acceptable specifications and code of practice at national level. PMID:18179116

  17. Interfacial fracture toughness of alumina/niobium systems

    SciTech Connect

    Stout, M.G. ); O'Dowd, N.P.; Shih, C.F. . Div. of Engineering)

    1991-01-01

    The interfacial fracture toughness of an alumina/niobium composite has been measured as a function of phase angle. The interface was formed by solid-state bonding bulk Coor's AD-999 fine-grain alumina with a commercial purity niobium at 1600{degrees}C for 0.5 hr under a pressure of 10.5 MPa. The alumina/niobium system has a number of features which makes it ideal for an investigation of interfacial fracture toughness. From HREM data we estimate that the width of the interface is no more than 10 atomic planes. Furthermore the thermal expansion coefficients of the two materials differ by less than 5% so residual stresses due to the bonding process are small. Using symmetric and asymmetric four point bend specimens we have measured the fracture toughness of homogenous alumina and that of the alumina/niobium bimaterial in combinations of in-plane shear and tension. The fracture toughness of the homogenous alumina is relatively insensitive to the loading phase. The measured fracture toughness K{sub c} of the interface, however, depended strongly on phase angle. We were unable to obtain valid alumina/niobium interfacial toughness data at negative phase angles as the fracture initiates in the alumina and not at the interface. In symmetric bending at a phase angle {approx}5{degrees}, we measured a nominal interface toughness of 4.0 MPa{radical}m, comparable to the homogeneous alumina. We found that the toughness increased with loading phase angle to a value of K{sub c} {approx} 9 MPa{radical}m at a phase between 25{degrees} and 40{degrees}. Preliminary calculations and experiments suggest that this effect is due to an asymmetric stress distribution, with respect to the interface, and plastic deformation in the niobium. 12 refs., 9 figs., 1 tab.

  18. Scattering and absorption coefficients of silica-doped alumina aerogels.

    PubMed

    Fu, Tairan; Tang, Jiaqi; Chen, Kai; Zhang, Fan

    2016-02-01

    Alumina-based aerogels are especially useful in many applications due to their excellent stability at high temperatures. This study experimentally analyzed the radiative properties of silica-doped alumina aerogels through spectral directional-hemispherical measurements for wavelengths of 0.38-25 μm. The silica-doped alumina aerogel samples were prepared with a 1.4∶1 molar ratio of silica to alumina. A two-flux model was used to describe the radiation propagation in a 1D scattering absorbing sample to derive expressions for the normal-hemispherical transmittances and reflectances based on the transport approximation. The normal-hemispherical transmittances and reflectances were measured at various spectral wavelengths and sample thicknesses using the integrating sphere method. The spectral absorption and transport scattering coefficients of silica-doped alumina aerogels were then determined from the measured normal-hemispherical data. The absorption and transport scattering coefficients of silica-doped alumina aerogels are (0.1  cm-1, 36  cm-1) and (0.1  cm-1, 112  cm-1) for wavelengths of 0.38-8.0 μm. The spectral transport scattering coefficient varies in the opposite direction from the spectral absorption coefficient for various wavelengths. The radiative properties for silica and alumina aerogels were quite different for the absorption coefficient for wavelengths of 2.5-8.0 μm and for the transport scattering coefficient for wavelengths of 0.38-2.5 and 3.5-6.0 μm. The measured radiative properties were used to predict the spectral normal-hemispherical reflectance and transmittance of the silica-doped alumina aerogels for various sample thicknesses and wavelengths. The predicted values do not change for the sample thicknesses greater than a critical value. The analysis provides valuable reference data for alumina aerogels for high-temperature applications. PMID:26836071

  19. Dermal Toxicity of Flake-Like α-Alumina Pigments.

    PubMed

    Kwon, TaeWoo; Seo, HyunJeong; Jang, Seongwan; Lee, Sang-Geun; Park, Sungkyun; Park, Kang Hyun; Youn, BuHyun

    2015-02-01

    Aluminum is one of the most widely used nonferrous metals and an important industrial material, especially for automotive coatings. However, potential toxicity caused by aluminum in humans limits the used of this metal. α-alumina is the most stable form of aluminum in various phases. Although the results of studies evaluating the dermal toxicity of α-alumina remained unclear, this compound can still be used as a pigment in cosmetics for humans. In the current study, we further evaluated the dermal cytotoxic effects of α-alumina on human skin cells and an in vivo mouse model. We also measured the in vitro penetration profile of flake-like α-alumina in porcine skin and assessed the degree of cellular metabolic disorders. Our findings demonstrated that treatment with flake-like α-alumina did not significantly affect cell viability up to 24 h. This compound was found to have a non-penetration profile based on a Franz modified diffusion cell assay. In addition, flake-like α-alumina was not found to induce dermal inflammation as assessed by histology of epidermal architecture, hyperplasia, and the expression of Interleukin-1β and Cyclooxygenase-2. Results of the cellular metabolic disorder assay indicated that flake-like α-alumina does not exert a direct effect on human skin cells. Taken together, our findings provided not only evidence that flake-like α-alumina may serve as a pearlescent pigment in cosmetics but also experimental basis utilizing α-alumina for human application. Our results also obviously provide new insight of the further toxicity study to aluminum based nanoparticles for skin. PMID:26353706

  20. Application of micro-indentation to irradiated alumina and vanadium/alumina joints

    NASA Astrophysics Data System (ADS)

    Hasegawa, A.; Kawamura, Y.; Satou, M.; Abe, K.

    1996-10-01

    The micro-indentation test as a method to introduce interface crack and to investigate the bonding strength of metal/ceramics joints is examined. Micro-indentation test was carried out using Vickers hardness tester at room temperature on joints of poly- or single-crystal alumina and vanadium or vanadium alloys. The vanadium/alumina (V/Al 2O 3) joints, unirradiated and irradiated in FFTF/MOTA in a helium-filled capsule at 693 K, were tested. The irradiation damage of the joint was about 40 dpa. Micro-indentation on the unirradiated joint interface showed several types of deformation and crack propagation behavior depending on the bonding strength of the joints. Irradiation hardening and brittle behavior were observed on the alumina side of the irradiated V/Al 2O 3 joints. Results of micro-indentation test at the V/Al 2O 3 interface showed the possibility of irradiation-induced strengthening of the interface caused by irradiation-induced mixing at the interface.

  1. Is wear debris responsible for failure in alumina-on-alumina implants?

    PubMed Central

    Baldini, Nicola; Ciapetti, Gabriela; Pellacani, Andrea; Giunti, Armando

    2009-01-01

    Background and purpose Ceramic-on-ceramic articulation is an attractive alternative to metal-on-polyethylene (PE) bearings, but little is known about the in vivo effects induced by dissemination of alumina wear debris in the periprosthetic tissues. We hypothesized that wear debris is not the main factor responsible for loosening and failure of the implant but that mechanical problems caused by incorrect surgical technique, prosthetic design, or trauma, may cause instability of the implants and result in production of wear debris. Patients and methods Clinical, radiographic, laboratory, and microbiological data from 30 consecutive patients with failed alumina-on-alumina arthroplasties, 19 with screwed socket and 11 with press-fit socket, were systematically collected and evaluated. Retrieved peri-implant tissues and prosthesis wear were also analyzed. Results and Interpretation Loosening was due to malpositioning, primary mechanical instability, trauma, or infection. Bone stock was generally preserved, even if screwed implants showed higher levels of osteolysis. Variable implant wear and tissue macrophage reaction were present but activation of giant cells/osteoclasts was not induced, and no correlation between histocytic reaction and the level of osteolysis was found. These findings indicate that, in contrast to the situation with metal-on-PE bearings, wear debris and occasional osteolysis were the effect rather than the cause of failure of ceramic-on-ceramic implants, and that press-fit socket fixation was the socket fixation design of preference. PMID:19404796

  2. Microstructural Models of Alumina Nanotubes and Anodic Porous Alumina Film Formed in Sulphuric Acid

    NASA Astrophysics Data System (ADS)

    Pu, Lin; Chen, Zhi-Qiang; Tan, Chao; Yang, Zheng; Zou, Jian-Ping; Bao, Xi-Mao; Feng, Duan; Shi, Yi; Zheng, You-Dou

    2002-03-01

    Electrochemical stepwise anodization of aluminium in dilute sulphuric acid results in the formation of alumina nanotubes (ANTs) due to the hexagonal split of the anodic porous alumina (APA) film along the cell boundaries containing many voids; that is, the ANTs are the completely detached cell of the APA film. The inner diameters of the ANTs are in the range of 10-20 nm, and the aspect ratio (inner diameter/length) of the ANTs can be about 80. The relations found for pore diameter, cell diameter and barrier layer thickness are around 1, 2.7 and 0.85 nm/V, respectively. Transmission electron microscopy (TEM) reveals that the ANT wall has a three-shell structure: an outer shell (metal/oxide interface) consisting of pure alumina oxide, a middle shell of the hydrated oxide or/and hydroxide and an inner shell (oxide/electrolyte interface) of anion incorporated oxide with the thickness ratio of 1:1:2. The structural change of ANTs induced by e-beam irradiation in TEM indicates that the thermal instability of the hydrated oxide or/and hydroxide within the cell wall might be an alternative origin contributing to the self-organization of the cells, leading to a densely packed triangular cell lattice of the APA film.

  3. Alumina-alumina hip replacement in patients younger than 50 years old.

    PubMed

    Sedel, L; Nizard, R S; Kerboull, L; Witvoet, J

    1994-01-01

    From April 1977 to December 1990, 131 total hip arthroplasties were performed on 113 patients younger than 50 years of age (median, 41 years); 64 were men and 49 women. The majority were active people. Sixty-six hips had no previous operations, and 33 had at least one previous arthroplasty. The femoral component was a cemented collared titanium alloy stem, and alumina socket was cemented for 99 hips and press-fit for 32. The mean follow-up period was five years, with 32 hips followed for more than ten years. Revision arthroplasty was considered as a failure. Survivorship analysis depicted a 97.5% rate of survival at five years, an 89.4% rate at ten years, and an 86.2% at 11 years. Nine revisions were performed: one experienced a femoral head rupture after three years, one had bipolar loosening, one experienced femoral cystic formation, and six were revised for acetabular cup loosening, all from the cemented group. Two revisions occurred on the same patient. No stem revision was necessary before ten years. Only one of these revisions was required in patients aged 40 or younger (64 patients). Alumina-alumina friction is an extremely interesting phenomenon in young patients, and could be related to the low wear debris production. PMID:8118972

  4. NON-DESTRUCTIVE TBC SPALLATION DETECTION BY A MICRO-INDENTATION METHOD

    SciTech Connect

    J. M. Tannenbaum; B.S.-J. Kang; M.A. Alvin

    2010-06-18

    In this research, a load-based depth-sensing micro-indentation method for spallation detection and damage assessment of thermal barrier coating (TBC) materials is presented. A non-destructive multiple loading/partial unloading testing methodology was developed where in stiffness responses of TBC coupons subjected to various thermal cyclic loading conditions were analyzed to predict the spallation site and assess TBC degradation state. The measured stiffness responses at various thermal loading cycles were used to generate time-series color maps for correlation with accumulation of TBC residual stress states. The regions with higher stiffness responses can be linked to a rise in out-of-plane residual stress located near or at the yttria stabilized zirconia (YSZ)/thermally grown oxide (TGO) interface, which is ultimately responsible for initiating TBC spallation failure. A TBC thermal exposure testing plan was carried out where time-series cross-sectional microstructural analyses of damage accumulation and spallation failure associated with the evolution of bond coat/TGO/top coat composite (e.g. thickness, ratcheting, localized oxidations, etc.) of air plasma sprayed (APS) TBCs were evaluated and correlated to the measured stiffness responses at various thermal cycles. The results show that the load-based micro-indentation test methodology is capable of identifying the spallation site(s) before actual occurrence. This micro-indentation technique can be viewed as a viable non-destructive evaluation (NDE) technique for determining as-manufactured and process-exposed TBCs. This technique also shows promise for the development of a portable instrument for on-line, in-situ spallation detection/prediction of industrial-size TBC turbine components.

  5. Detection of the multiple spallation parameters and the internal structure of a particle cloud during shock-wave loading of a metal

    NASA Astrophysics Data System (ADS)

    Fedorov, A. V.; Mikhailov, A. L.; Finyushin, S. A.; Kalashnikov, D. A.; Chudakov, E. A.; Butusov, E. I.; Gnutov, I. S.

    2016-04-01

    The results of experiments on studying spallation and the ejection of particles from the surfaces of copper and lead samples are presented. A laser interferometry method is used to detect the particle cloud velocity and the multiple spallation parameters. Angular detectors are used to detect the depth profile of the particle cloud velocity dispersion and the structure of metal spallation.

  6. Residual Stress Predictions in Polycrystalline Alumina

    SciTech Connect

    VEDULA,VENKATA R.; GLASS,S. JILL; SAYLOR,DAVID M.; ROHRER,GREGORY S.; CARTER,W. CRAIG; LANGER,STEPHEN A.

    1999-12-13

    Microstructure-level residual stresses arise in polycrystalline ceramics during processing as a result of thermal expansion anisotropy and crystallographic disorientation across the grain boundaries. Depending upon the grain size, the magnitude of these stresses can be sufficiently high to cause spontaneous microcracking during the processing of these materials. They are also likely to affect where cracks initiate and propagate under macroscopic loading. The magnitudes of residual stresses in untextured and textured alumina samples were predicted using object oriented finite (OOF) element analysis and experimentally determined grain orientations. The crystallographic orientations were obtained by electron-backscattered diffraction (EBSD). The residual stresses were lower and the stress distributions were narrower in the textured samples compared to those in the untextured samples. Crack initiation and propagation were also simulated using the Griffith fracture criterion. The grain boundary to surface energy ratios required for computations were estimated using AFM groove measurements.

  7. Compositional characterization of atomic layer deposited alumina

    SciTech Connect

    Philip, Anu; Thomas, Subin; Kumar, K. Rajeev

    2014-01-28

    As the microelectronic industry demands feature size in the order of few and sub nanometer regime, the film composition and other film properties become critical issues and ALD has emerged as the choice of industry. Aluminum oxide is a material with wide applications in electronic and optoelectronic devices and protective and ion barrier layers. Al{sub 2}O{sub 3} is an excellent dielectric because of its large band gap (8.7eV), large band offsets with silicon. We have deposited thin layers of alumina on silicon wafer (p-type) for gate dielectric applications by ALD technique and compositional characterizations of the deposited thin films were done using EDS, XPS and FTIR spectra.

  8. Tensile creep behavior of polycrystalline alumina fibers

    NASA Technical Reports Server (NTRS)

    Yun, H. M.; Goldsby, J. C.

    1993-01-01

    Tensile creep studies were conducted on polycrystalline Nextel 610 and Fiber FP alumina fibers with grain sizes of 100 and 300 nm, respectively. Test conditions were temperatures from 800 to 1050 C and stresses from 60 to 1000 MPa. For both fibers, only a small primary creep portion occurred followed by steady-state creep. The stress exponents for steady-state creep of Nextel 610 and Fiber FP were found to be about 3 and 1, respectively. At lower temperatures, below 1000 C, the finer grained Nextel 610 had a much higher 0.2 percent creep strength for 100 hr than the Fiber FP; while at higher temperatures, Nextel 610 had a comparable creep strength to the Fiber FP. The stress and grain size dependencies suggest Nextel 610 and Fiber FP creep rates are due to grain boundary sliding controlled by interface reaction and Nabarro-Herring mechanisms, respectively.

  9. Crystallography of Alumina-YAG-Eutectic

    NASA Technical Reports Server (NTRS)

    Farmer, Serene C.; Sayir, Ali; Dickerson, Robert M.; Matson, Lawrence E.

    2000-01-01

    Multiple descriptions of the alumina-YAG eutectic crystallography appear in the ceramic literature. The orientation between two phases in a eutectic system has direct impact on residual stress, morphology, microstructural stability, and high temperature mechanical properties. A study to demonstrate that the different crystallographic relationships can be correlated with different growth constraints was undertaken. Fibers produced by Laser-Heated Float Zone (LHFZ) and Edge-defined Film-fed Growth (EFG) were examined. A map of the orientation relationship between Al2O3 and Y3Al5O12 and their relationship to the fiber growth axis as a function of pull rate are presented. Regions in which a single orientation predominates are identified.

  10. Optimized alumina coagulants for water treatment

    SciTech Connect

    Nyman, May D.; Stewart, Thomas A.

    2012-02-21

    Substitution of a single Ga-atom or single Ge-atom (GaAl.sub.12 and GeAl.sub.12 respectively) into the center of an aluminum Keggin polycation (Al.sub.13) produces an optimal water-treatment product for neutralization and coagulation of anionic contaminants in water. GaAl.sub.12 consistently shows .about.1 order of magnitude increase in pathogen reduction, compared to Al.sub.13. At a concentration of 2 ppm, GaAl.sub.12 performs equivalently to 40 ppm alum, removing .about.90% of the dissolved organic material. The substituted GaAl.sub.12 product also offers extended shelf-life and consistent performance. We also synthesized a related polyaluminum chloride compound made of pre-hydrolyzed dissolved alumina clusters of [GaO.sub.4Al.sub.12(OH).sub.24(H.sub.2O).sub.12].sup.7+.

  11. Alumina Paste Sublimation Suppression Barrier for Thermoelectric Device

    NASA Technical Reports Server (NTRS)

    Paik, Jong-Ah (Inventor); Caillat, Thierry (Inventor)

    2014-01-01

    Alumina as a sublimation suppression barrier for a Zintl thermoelectric material in a thermoelectric power generation device operating at high temperature, e.g. at or above 1000K, is disclosed. The Zintl thermoelectric material may comprise Yb.sub.14MnSb.sub.11. The alumina may be applied as an adhesive paste dried and cured on a substantially oxide free surface of the Zintl thermoelectric material and polished to a final thickness. The sublimation suppression barrier may be finalized by baking out the alumina layer on the Zintl thermoelectric material until it becomes substantially clogged with ytterbia.

  12. Porous alumina based ordered nanocomposite coating for wear resistance

    NASA Astrophysics Data System (ADS)

    Yadav, Arti; Muthukumar, M.; Bobji, M. S.

    2016-08-01

    Uniformly dispersed nanocomposite coating of aligned metallic nanowires in a matrix of amorphous alumina is fabricated by pulsed electrodeposition of copper into the pores of porous anodic alumina. Uniform deposition is obtained by controlling the geometry of the dendritic structure at the bottom of pores through stepwise voltage reduction followed by mild etching. The tribological behaviour of this nanocomposite coating is evaluated using a ball on flat reciprocating tribometer under the dry contact conditions. The nanocomposite coating has higher wear resistance compared to corresponding porous alumina coating. Wear resistant nanocomposite coating has wide applications especially in protecting the internal surfaces of aluminium internal combustion engines.

  13. Processing of silicon nitride and alumina nanosize powders

    SciTech Connect

    Gonzalez, E.J.; Piermarini, G.; Hockey, B.; Malghan, S.G.

    1995-08-01

    The effects of pressure on the compaction and subsequent processing of nanosize {gamma} alumina powders were studied. A 3 mm diameter piston/cylinder die was used to compact the nanosize powders to pressures of 1 and 2.5 GPa. The green bodies were sintered at temperatures up to 1600{degrees}C. Results show that green body density can be increased by higher compaction pressures. It appears that as a result of the {gamma}-to-{alpha} transformation in alumina, higher green density does not necessarily produce a higher density sintered alumina body. The microstructures of the sintered bodies are described in terms of porosity and phase content.

  14. Alumina as a dopant in optical fiber by OVD

    NASA Astrophysics Data System (ADS)

    Wang, Ji

    2014-08-01

    Alumina is an indispensable dopant in modern optical fiber technology, particularly due to its important role played in the recent developments of optical fiber amplifiers and high-power fiber lasers over the last decade or so, which have revolutionized the telecommunication systems, and the industrial laser landscapes, respectively. In this paper, Alumina-doped optical fibers advanced through the outside vapor deposition process and their key attributes in the respective applications are reviewed, with Alumina both as a sole dopant for its potential use in the low-loss transmission lines and as a co-dopant for active use in the high-brightness, high-power fiber laser applications.

  15. Aluminum-Alloy-Matrix/Alumina-Reinforcement Composites

    NASA Technical Reports Server (NTRS)

    Kashalikar, Uday; Rozenoyer, Boris

    2004-01-01

    Isotropic composites of aluminum-alloy matrices reinforced with particulate alumina have been developed as lightweight, high-specific-strength, less-expensive alternatives to nickel-base and ferrous superalloys. These composites feature a specific gravity of about 3.45 grams per cubic centimeter and specific strengths of about 200 MPa/(grams per cubic centimeter). The room-temperature tensile strength is 100 ksi (689 MPa) and stiffness is 30 Msi (206 GPa). At 500 F (260 C), these composites have shown 80 percent retention in strength and 95 percent retention in stiffness. These materials also have excellent fatigue tolerance and tribological properties. They can be fabricated in net (or nearly net) sizes and shapes to make housings, pistons, valves, and ducts in turbomachinery, and to make structural components of such diverse systems as diesel engines, automotive brake systems, and power-generation, mining, and oil-drilling equipment. Separately, incorporation of these metal matrix composites within aluminum gravity castings for localized reinforcement has been demonstrated. A composite part of this type can be fabricated in a pressure infiltration casting process. The process begins with the placement of a mold with alumina particulate preform of net or nearly net size and shape in a crucible in a vacuum furnace. A charge of the alloy is placed in the crucible with the preform. The interior of the furnace is evacuated, then the furnace heaters are turned on to heat the alloy above its liquidus temperature. Next, the interior of the furnace is filled with argon gas at a pressure about 900 psi (approximately equal to 6.2 MPa) to force the molten alloy to infiltrate the preform. Once infiltrated, the entire contents of the crucible can be allowed to cool in place, and the composite part recovered from the mold.

  16. A time-of-flight backscattering spectrometer at the Spallation Neutron Source, BASIS

    SciTech Connect

    Mamontov, E.; Herwig, K. W.

    2011-08-15

    We describe the design and current performance of the backscattering silicon spectrometer (BASIS), a time-of-flight backscattering spectrometer built at the spallation neutron source (SNS) of the Oak Ridge National Laboratory (ORNL). BASIS is the first silicon-based backscattering spectrometer installed at a spallation neutron source. In addition to high intensity, it offers a high-energy resolution of about 3.5 {mu}eV and a large and variable energy transfer range. These ensure an excellent overlap with the dynamic ranges accessible at other inelastic spectrometers at the SNS.

  17. Parametric study of spallation targets for the MYRRHA reactor using MCNPX simulations

    NASA Astrophysics Data System (ADS)

    Rebello, A. L. P.; Martinez, A. S.; Gonçalves, A. C.

    2014-06-01

    The present work aims to evaluate the behavior of neutron multiplicity in a spallation target using MCNPX simulations, focusing on its application in the MYRRHA reactor. It was studied the two types of spallation target proposed for the MYRRHA project, windowless and windows target, in order to compare them and find saturation boundaries. Some saturation boundaries were found and the windowless target proved to be as viable as the windows one. Each one produced nearly the same number of neutrons per incident proton. Using the concept of neutron cost, it was also observed that the optimum conditions on neutron production occur at about 1GeV, for both target designs.

  18. CNO destruction by spallation and type I X-ray bursts

    NASA Technical Reports Server (NTRS)

    Tillett, Jason C.; Macdonald, James

    1992-01-01

    Recent work on the surface boundary conditions of accreting neutron stars indicates that appreciable amounts of CNO elements can be destroyed by spallation. Previous authors assume an accretion of near-solar-abundance material which is not altered by boundary effects. Steady state models of accreting neutron stars are constructed assuming all but traces of metals are destroyed due to spallation in the surface layers. Models with solar accretion for comparison are also constructed. The models are compared with Exosat observations of 4U/MXB 1636 - 53. It is found that the simplifications introduced by assuming CNO destruction does not bring theory closer to describing what is observed.

  19. Target station design for a 1 MW pulsed spallation neutron source

    SciTech Connect

    Russell, G.J.; Baker, G.D.; Brewton, R.J.

    1993-12-31

    Target stations are vital components of the 1 MW, next generation spallation neutron source proposed for LANSCE. By and large, target stations design determines the overall performance of the facility. Many traditional concepts will probably have to be rethought, and many new concepts will have to be put forward to meet the 1 MW challenge. This article gives a brief overview of the proposed neutron spallation source from the target station viewpoint, as well as the general philosophy adopted for the design of the LANSCE-II target stations. Some of the saliant concepts and features envisioned for LANSCE-II are briefly described.

  20. Flattening and Cooling of Millimeter- and Micrometer-Sized Alumina Drops

    NASA Astrophysics Data System (ADS)

    Goutier, S.; Vardelle, M.; Labbe, J. C.; Fauchais, P.

    2011-01-01

    An experimental setup was developed to produce fully melted, millimeter-sized, ceramic or metallic drops with impact velocities up to 10 m/s. Such impact velocities allow achievement of impact Weber numbers, close to those of the plasma spray process ( We = 2300) with droplets in the tens of micrometer size range. A fast camera (4000 image/s) combined with a fast pyrometer (4000 Hz), allowed the flattening of the drop to be followed. To study the flattening of micrometer-sized droplets, a direct-current (dc) plasma torch was used to melt alumina particles (around 45 μm in diameter). The experimental setup was composed of a fast (50 ns) two-color pyrometer and two fast (at best an exposure time of 2 μs) charge-coupled device cameras (one orthogonal and other tangential to the substrate). The flattening behaviors of millimeter- and micrometer-sized particles were compared. First, impacts of alumina drops (millimeter-sized) with velocities up to 10 m/s were studied. Results were then compared with micrometer-sized alumina particles (about 45 μm in diameter) sprayed with the dc plasma torch. A correlation was found between both flattening scales, and, in spite of the lower impact velocity at the millimeter scale, droplet ejections were also found as obtained at the micrometer scale. This work shows that for a sound comparison of phenomena at the two different scales it is mandatory to have Weber numbers as close as possible in both cases.

  1. Effects of ball milling and sintering on alumina and alumina-boron compounds

    NASA Astrophysics Data System (ADS)

    Cross, Thomas

    Alumina has a wide variety of applications, but the processing of alumina based materials can be costly. Mechanically milling alumina has been shown to enhance the sintering properties while decreasing the sintering temperature. Additions of boron have also proven to increase sintering properties of alumina. These two processes, mechanical milling and boron additions, will be combined to test the sintering properties and determine if they are improved upon even further compared to the individual processes. Multiple samples of pure alumina, 0.2 weight percent boron, and 1.0 weight percent boron are batched and processed in a ball mill for different time intervals. These samples are then characterized to observe the structure and properties of the samples after milling but before sintering. Pellets are dry pressed from the milled powders, sintered at 1200°C for one to 10 hours, and characterized to determine the impact of processing. X-ray diffractometry (XRD) was used on each sample to determine crystallite size and lattice parameters at different stages throughout the experiment. XRD was also used to identify any samples with an aluminum borate phase. Scanning electron microscopy (SEM) was used to observe the powder and pellet morphology and to measure bulk chemical composition. Samples were sputter coated with an Au-Pd coating observed in the SEM to characterize the topography as a function of variables such as milling time, boron composition, and sintering time. Additionally, porosity and change in diameter were measured to track the sintering process. Milling sample for longer periods of time would be unnecessary due to the crystallite size leveling off between 10 and 12 hours of milling time. Samples of alumina with 0.2 weight percent boron prove to have very little effect on the sintering properties. At 1.0 weight percent boron, there are changes in diffraction patterns and topography after being sintered for one hour. The porosities of all of the sintered

  2. Alumina-Forming MAX Phases in Turbine Material Systems

    NASA Technical Reports Server (NTRS)

    Smialek, James L.; Harder, Bryan J.; Garg, Arnita; Nesbitt, James A.

    2015-01-01

    Coatings for high temperature turbine components are based on low conductivity YSZ thermal barriers and protective NiAl, NiCoCrAlY bond coats. Good oxidation hot corrosion resistance, intermediate CTE, and strain tolerance of Ti2AlC and Cr2AlC MAX phases are thus of special interest. Their alumina scale growth follows a cubic law in accord with FeCrAlY alloys, with oxygen grain boundary diffusivity: Dgb 1.8 x 10-10 exp(-375 kJmole) m3s. Protective cubic kinetics are also found in high pressure burner rig (6 atm., 25 ms) and TGA tests of MAXthal 211Ti2AlC. The initial portion (0.1 hr) is dominated by fast TiO2 growth (with little evidence of scale volatility in high pressure water vapor, as found for SiO2 scales). Bulk Ti2AlC and Cr2AlC substrates show promise as potential bond coats for YSZ TBCs in 1000-1200 C furnace life (500 h) tests. Cr2AlC is proving to be very resistant to 700-900 C Na2SO4 hot corrosion and is of interest for disk alloys. Preliminary diffusion bonded Cr2AlC-superalloy hybrid couples have survived 1000 hr interrupted furnace tests at 800C with no indication of cracking or debonding. Diffusion zones of -NiAl+Cr7C3 were produced in these above 1000 C, but did not grow to any great extent after 1000 hr at 800 C. Processing as coatings presents challenges, however the basic properties of MAX phases provide novel opportunities for high temperature turbine components.

  3. Precompound emission of energetic light fragments in spallation reactions

    NASA Astrophysics Data System (ADS)

    Kerby, Leslie Marie

    Emission of light fragments (LF) from nuclear reactions is an open question. Different reaction mechanisms contribute to their production; the relative roles of each, and how they change with incident energy, mass number of the target, and the type and emission energy of the fragments is not completely understood. None of the available models are able to accurately predict emission of LF from arbitrary reactions. However, the ability to describe production of LF (especially at energies ~ 30 MeV) from many reactions is important for different applications, such as cosmic-ray-induced Single Event Upsets (SEUs), radiation protection, and cancer therapy with proton and heavy-ion beams, to name just a few. The Cascade-Exciton Model (CEM) version 03.03 and the Los Alamos version of the Quark-Gluon String Model (LAQGSM) version 03.03 event generators in Monte Carlo N-Particle Transport Code version 6 (MCNP6) describe quite well the spectra of fragments with sizes up to 4He across a broad range of target masses and incident energies (up to ~ 5 GeV for CEM and up to ~1 TeV/A for LAQGSM). However, they do not predict the high-energy tails of LF spectra heavier than 4He well. Most LF with energies above several tens of MeV are emitted during the precompound stage of a reaction. The current versions of the CEM and LAQGSM event generators do not account for precompound emission of LF larger than 4He. The aim of our work is to extend the precompound model in them to include such processes, leading to an increase of predictive power of LF-production in MCNP6. This entails upgrading the Modified Exciton Model currently used at the preequilibrium stage in CEM and LAQGSM. It also includes expansion and examination of the coalescence and Fermi break-up models used in the precompound stages of spallation reactions within CEM and LAQGSM. Extending our models to include emission of fragments heavier than 4He at the precompound stage has indeed provided results that have much better

  4. Dissertation: Precompound Emission of Energetic Light Fragments in Spallation Reactions

    SciTech Connect

    Kerby, Leslie Marie

    2015-08-04

    Emission of light fragments (LF) from nuclear reactions is an open question. Different reaction mechanisms contribute to their production; the relative roles of each, and how they change with incident energy, mass number of the target, and the type and emission energy of the fragments is not completely understood. None of the available models are able to accurately predict emission of LF from arbitrary reactions. However, the ability to describe production of LF (especially at energies ≳ 30 MeV) from many reactions is important for different applications, such as cosmic-ray-induced Single Event Upsets (SEUs), radiation protection, and cancer therapy with proton and heavy-ion beams, to name just a few. The Cascade-Exciton Model (CEM) version 03.03 and the Los Alamos version of the Quark-Gluon String Model (LAQGSM) version 03.03 event generators in Monte Carlo N-Particle Transport Code version 6 (MCNP6) describe quite well the spectra of fragments with sizes up to ⁴He across a broad range of target masses and incident energies (up to ~ 5 GeV for CEM and up to ~ 1 TeV/A for LAQGSM). However, they do not predict the high energy tails of LF spectra heavier than ⁴He well. Most LF with energies above several tens of MeV are emitted during the precompound stage of a reaction. The current versions of the CEM and LAQGSM event generators do not account for precompound emission of LF larger than ⁴He. The aim of our work is to extend the precompound model in them to include such processes, leading to an increase of predictive power of LF-production in MCNP6. This entails upgrading the Modified Exciton Model currently used at the preequilibrium stage in CEM and LAQGSM. It also includes expansion and examination of the coalescence and Fermi break-up models used in the precompound stages of spallation reactions within CEM and LAQGSM. Extending our models to include emission of fragments heavier than ⁴He at the precompound stage has indeed provided results that have much

  5. Preparation and Testing of Corrosion and Spallation-Resistant Coatings

    SciTech Connect

    Hurley, John

    2015-11-01

    with the Rene 80. One-inch-diameter buttons were machined from each of the bonded blocks and sent to Siemens for standard oxidation, spallation, and corrosion testing, which should be complete in the spring of 2016.

  6. Superconducting Prototype Cavities for the Spallation Neutron Source (SNS) Project

    SciTech Connect

    G. Ciovati; P. Kneisel; K. Davis; K. Macha; J. Mammosser

    2002-06-01

    The Spallation Neutron Source project includes a superconducting linac section in the energy range from 186 MeV to 1000 MeV operating at a frequency of 805 MHz at 2.1 K. For this energy range two types of cavities are needed with geometrical Beta-values of Beta=0.61 and Beta=0.81. An aggressive cavity prototyping program is being pursued at JLab, which calls for fabricating and testing of four Beta=0.61 cavities and two Beta=0.81 cavities. Both types consist of six cells made from high purity niobium and feature one HOM coupler of the TESLA type on each beam pipe and a port for a high power coaxial input coupler. Three of the four Beta=0.61 cavities will be used for a cryomodule test in early 2002. At this time, four medium beta cavities and one high beta cavity have been completed and tested at JLab. In addition, the three medium beta cavities for the prototype cryomodule have been equipped with the integrated Ti-Helium vessel, successfully retested and will be assembled into a cavity string. Results from the cryo-module test should be available by the time of the conference. The tests on the Beta=0.61 cavity and the Beta=0.81 cavity exceeded the design values for gradient and Q - value: E{sub acc} =10.1 MV/m and Q = 5 x 10{sup 9} at 2.1K for Beta=0.61 and E{sub acc} = 12.3 MV/m and Q=5 x 10{sup 9} at 2.1K for Beta = 0.81. The medium beta cavities reached gradients between E{sub acc} = 15 MV/m and 21 MV/m. This paper will describe the test results obtained with the various cavities, some aspects of the HOM damping at cryogenic temperatures, results from microphonics and Lorentz force detuning tests and the cavity string assembly at the time of this workshop.

  7. Superconducting Prototype Cavities for the Spallation Neutron Source (SNS) Project

    SciTech Connect

    G. Ciovati, P. Kneisel , J. Brawley, R. Bundy, I. Campisi, K. Davis; K. Macha; D. Machie; J. Mammosser; S. Morgan; R. Sundelin; L. Turlington; K. Wilson; M. Doleans; S.H. Kim; D. Barni; C. Pagani; P. Pierini; K. Matsumoto; R. Mitchell; D. Schrage; R. Parodi; J. Sekutowicz; P. Ylae-Oijala

    2001-09-01

    The Spallation Neutron Source project includes a superconducting linac section in the energy range from 192 MeV to 1000 MeV, operating at a frequency of 805 MHz at 2.1 K. For this energy range two types of cavities are needed with geometrical beta - values of beta= 0.61 and beta= 0.81. An aggressive cavity prototyping program is being pursued at Jlab, which calls for fabricating and testing of four beta= 0.61 cavities and two beta= 0.81 cavities. Both types consist of six cells made from high purity niobium and feature one HOM coupler on each beam pipe and a port for a high power coaxial input coupler. Three of the four beta= 0.61 cavities will be used for a cryomodule test in early 2002. At this time four medium beta cavities and one high beta cavity have been completed at JLab. The first tests on the beta=0.61 cavity and the beta= 0.81 exceeded the design values for gradient and Q - value: E{sub acc} = 1 0.3 MV/m and Q = 5 x 10{sup 9} at 2.1K for beta= 0.61 and E{sub acc} = 12.3 MV/m and Q = 5 x 10{sup 9} at 2.1K for beta= 0.81. One of the medium beta cavities has been equipped with an integrated helium vessel and measurements of the static and dynamic Lorentz force detuning will be done and compared to the ''bare'' cavities. In addition two single cell cavities have been fabricated, equipped with welded-on HOM couplers. They are being used to evaluate the HOM couplers with respect to multipacting, fundamental mode rejection and HOM damping as far as possible in a single cell. This paper will describe the cavity design with respect to electrical and mechanical features, the fabrication efforts and the results obtained with the different cavities existing at the time of this workshop.

  8. Anodisation with dynamic current control for tailored alumina coatings

    NASA Astrophysics Data System (ADS)

    Sieber, M.; Althöfer, I.; Höhlich, D.; Scharf, I.; Böttger, D.; Böttger, S.; Böttger, E.; Lampke, T.

    2016-03-01

    The anodic oxidation process is commonly used to refine the surface of aluminium and its alloys. Compared to the substrate, the alumina layers produced by anodising exhibit an increased hardness and chemical resistance. Thus, the corrosion and wear resistance are generally improved. The coatings are also electrically isolating and may serve decorative purposes. Applying a time-variant, dynamic electrical process control by pulse-current or current-steps is a promising approach to improve the coating properties, which is partially deployed in an industrial scale. In the present work, the influence of dynamic electrical process control on the coating properties is examined by means of a design of experiments (DOE). The effects of various electrolyte compositions and temperatures as well as processing time are considered with regard to coating thickness, hardness, wear resistance and the electrical energy consumption during the formation of the coatings. Information about the statistical significance of the effects of the parameters on the considered properties is obtained by an analysis of variance (ANOVA).

  9. Fabrication of whisker-toughened alumina tubes. Final report

    SciTech Connect

    Loutfy, R.O.

    1993-09-01

    A process has been developed to fabricate whisker toughened alumina composites by slip casting dense colloidal suspensions of Al{sub 2}O{sub 3}-15% SiC{sub w}. Optimum processing parameters for slip casting we developed with slip viscosity of 60--70 centipoise and solids content 78--79 wt %. Slip-cast parts with green densities 65 to 68% theoretical were achieved. Composite parts were pressureless sintered to 96--97% theoretical density with <1% open porosity. The composites exhibited strengths of 500 MPa, toughness of 6.5 MPa m{sup 1/2}, and hardness of 17.26 GPa (1765 kg/mm{sup 2}). High temperature strength retention was maintained up to 1200C. Good thermal shock resistance with {Delta}T{sub cr} = 500C was also achieved. The process technology was transferred into pilot scale for producing prototype heat exchanger tubing up to 4 inches in diameter at the facilities of Vesuvius/McDanel.

  10. Ultrafast excited state deactivation of doped porous anodic alumina membranes

    NASA Astrophysics Data System (ADS)

    Makhal, Abhinandan; Sarkar, Soumik; Pal, Samir Kumar; Yan, Hongdan; Wulferding, Dirk; Cetin, Fatih; Lemmens, Peter

    2012-08-01

    Free-standing, bi-directionally permeable and ultra-thin anodic aluminum oxide (AAO) membranes establish attractive templates (host) for the synthesis of nano-dots and rods of various materials (guest). This is due to their chemical and structural integrity and high periodicity on length scales of 5-150 nm which are often used to host photoactive nano-materials for various device applications including dye-sensitized solar cells. In the present study, AAO membranes are synthesized by using electrochemical methods and a detailed structural characterization using FEG-SEM, XRD and TGA confirms the porosity and purity of the material. Defect-mediated photoluminescence quenching of the porous AAO membrane in the presence of an electron accepting guest organic molecule (benzoquinone) is studied by means of steady-state and picosecond/femtosecond-resolved luminescence measurements. Using time-resolved luminescence transients, we have also revealed light harvesting of complexes of porous alumina impregnated with inorganic quantum dots (Maple Red) or gold nanowires. Both the Förster resonance energy transfer and the nano-surface energy transfer techniques are employed to examine the observed quenching behavior as a function of the characteristic donor-acceptor distances. The experimental results will find their relevance in light harvesting devices based on AAOs combined with other materials involving a decisive energy/charge transfer dynamics.

  11. VERITAS: a high-flux neutron reflectometer with vertical sample geometry for a long pulse spallation source

    NASA Astrophysics Data System (ADS)

    Mattauch, S.; Ioffe, A.; Lott, D.; Menelle, A.; Ott, F.; Medic, Z.

    2016-04-01

    An instrument concept of a reflectometer with a vertical sample geometry fitted to the long pulse structure of a spallation source, called “VERITAS” at the ESS, is presented. It focuses on designing a reflectometer with high intensity at the lowest possible background following the users' demand to investigate thin layers or interfacial areas in the sub-nanometer length scale. The high intensity approach of the vertical reflectometer fits very well to the long pulse structure of the ESS. Its main goal is to deliver as much usable intensity as possible at the sample position and be able to access a reflectivity range of 8 orders of magnitude and more. The concept assures that the reflectivity measurements can be performed in its best way to maximize the flux delivered to the sample. The reflectometer is optimized for studies of (magnetic) layers having thicknesses down to 5Å and a surface area of 1x1cm2. With reflectivity measurements the depth-resolved, laterally averaged chemical and magnetic profile can be investigated. By using polarised neutrons, additional vector information on the in-plane magnetic correlations (off-specular scattering at the pm length scale, GISANS at the nm length scale) can be studied. The full polarisation analysis could be used for soft matter samples to correct for incoherent scattering which is presently limiting neutron reflectivity studies to a reflectivity range on the order of 10-6.

  12. A method for decomposition of hexachlorobenzene by gamma-alumina.

    PubMed

    Zhang, Lifei; Zheng, Minghui; Liu, Wenbin; Zhang, Bing; Su, Guijin

    2008-02-11

    A method of decomposing hexachlorobenzene (HCB) by gamma-alumina was investigated at low temperature of 300 degrees C. It was found that HCB was rather quickly decomposed under such a condition. Decomposition efficiency (DE) increases with increasing the surface area of gamma-alumina. Pretreated gamma-alumina has a better performance for the decomposition reaction. A high decomposition efficiency within the short reactive time of 60 min was achieved to be 94.2%, which was obtained by preheating gamma-alumina with the surface area of 220 m(2)g(-1) at 450 degrees C for 2 h. High surface area and appropriate pretreatment temperature probably provide more reactive sites such as the isolated OH groups and Al(3+) sites surrounded by O(2-) sites. These sites may induce the decomposition of HCB via a main ring-cracking process. The present study, hopefully, holds the promise for the eliminating of HCB contained hazardous materials in industrial application. PMID:18037236

  13. Alumina microstructural sample preparation using a borate glaze

    SciTech Connect

    Scott, C.; Hill, S.; Hosmer, K.

    1986-03-01

    A method was developed for preparing alumina surfaces for microstructural analysis. Samples were polished using a sodium borate glaze, which produced a smooth surface with the grain boundaries accented.

  14. Removing Fluoride Ions with Continously Fed Activated Alumina.

    ERIC Educational Resources Information Center

    Wu, Yeun C.; Itemaking, Isara Cholapranee

    1979-01-01

    Discussed is the mathematical basis for determining fluoride removal during water treatment with activated alumina. The study indicates that decreasing particle size decreases the pore diffusion effect and increases fluoride removal. (AS)

  15. Aluminum microstructures on anodic alumina for aluminum wiring boards.

    PubMed

    Jha, Himendra; Kikuchi, Tatsuya; Sakairi, Masatoshi; Takahashi, Hideaki

    2010-03-01

    The paper demonstrates simple methods for the fabrication of aluminum microstructures on the anodic oxide film of aluminum. The aluminum sheets were first engraved (patterned) either by laser beam or by embossing to form deep grooves on the surface. One side of the sheet was then anodized, blocking the other side by using polymer mask to form the anodic alumina. Because of the lower thickness at the bottom part of the grooves, the part was completely anodized before the complete oxidation of the other parts. Such selectively complete anodizing resulted in the patterns of metallic aluminum on anodic alumina. Using the technique, we fabricated microstructures such as line patterns and a simple wiring circuit-board-like structure on the anodic alumina. The aluminum microstructures fabricated by the techniques were embedded in anodic alumina/aluminum sheet, and this technique is promising for applications in electronic packaging and devices. PMID:20356280

  16. Fabrication method produces high-grade alumina crucibles

    NASA Technical Reports Server (NTRS)

    Palmour, H.

    1965-01-01

    Alumina-binder mixture, which has been dry pressed in a die using a mating punch, forms crucibles of various configurations and after firing results in a ceramic structure for use in diffusion experiments.

  17. Thermophysical Properties of Sodium (Beta)-Alumina Polycrystalline Ceramic

    NASA Technical Reports Server (NTRS)

    Ryan, M. A.; Williams, R. M.; Allevato, C. E.; Vining, C. B.; Lowe-Ma, C. K.; Robie, S. B.

    1994-01-01

    Teh thermal diffusivity, heat capacity and thermal conductivity of solid samples of new, Li-stabilized, sodium (Beta)-alumina polycrystalline ceramic have been determined in the temperature range 500-1200 K.

  18. Use of surfactants in alumina precipitation in the bayer process

    SciTech Connect

    Owen, D.O.; Davis, D.C.

    1988-04-12

    In the method for producing alumina trihydrate crystals by crystallization of alumina trihydrate from a hot, caustic pregnant Bayer process liquor, to obtain a reduced percent of small size crystals -325 mesh fraction thereby to increase the yield of crystals coarser than -325 mesh subsequently to be processed to yield aluminum, the improvement is described comprising the addition to the pregnant liquor, after red mud separation and immediately prior to crystallization of alumina trihydrate, of two mutually soluble components (A) and (B) in an amount effective to increase the yield of the coarser crystals, component (A) being a surfactant which will disperse component (B) in the pregnant liquor and component (B) being an oil in which the surfactant is dissolved and having a boiling point above the temperature prevailing alumina hydrate crystallization.

  19. Potassium Beta-Alumina/Molybdenum/Potassium Electrochemical Cells

    NASA Technical Reports Server (NTRS)

    Williams, R.; Kisor, A.; Ryan, M.; Nakamura, B.; Kikert, S.; O'Connor, D.

    1994-01-01

    potassium alkali metal thermal-to-electric converter (K-AMTEC) cells utilizing potassium beta alumina solid electrolyte (K-BASE) are predicted to have improved properties for thermal to electric conversion at somewhat lower temperatures than sodium AMTEC's.

  20. Carbon dioxide pressure swing adsorption process using modified alumina adsorbents

    DOEpatents

    Gaffney, Thomas Richard; Golden, Timothy Christopher; Mayorga, Steven Gerard; Brzozowski, Jeffrey Richard; Taylor, Fred William

    1999-01-01

    A pressure swing adsorption process for absorbing CO.sub.2 from a gaseous mixture containing CO.sub.2 comprising introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100.degree. C. and 500.degree. C. to adsorb CO.sub.2 to provide a CO.sub.2 laden alumina adsorbent and a CO.sub.2 depleted gaseous mixture and contacting the CO.sub.2 laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO.sub.2 from the CO.sub.2 laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100.degree. C. and 600.degree. C., is not degraded by high concentrations of water under process operating conditions.

  1. Carbon dioxide pressure swing adsorption process using modified alumina adsorbents

    DOEpatents

    Gaffney, T.R.; Golden, T.C.; Mayorga, S.G.; Brzozowski, J.R.; Taylor, F.W.

    1999-06-29

    A pressure swing adsorption process for absorbing CO[sub 2] from a gaseous mixture containing CO[sub 2] comprises introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100 C and 500 C to adsorb CO[sub 2] to provide a CO[sub 2] laden alumina adsorbent and a CO[sub 2] depleted gaseous mixture and contacting the CO[sub 2] laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO[sub 2] from the CO[sub 2] laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100 C and 600 C, is not degraded by high concentrations of water under process operating conditions. 1 fig.

  2. Superhydrophobic surfaces fabricated by surface modification of alumina particles

    NASA Astrophysics Data System (ADS)

    Richard, Edna; Aruna, S. T.; Basu, Bharathibai J.

    2012-10-01

    The fabrication of superhydrophobic surfaces has attracted intense interest because of their widespread potential applications in various industrial fields. Recently, some attempts have been carried out to prepare superhydrophobic surfaces using metal oxide nanoparticles. In the present work, superhydrophobic surfaces were fabricated with low surface energy material on alumina particles with different sizes. It was found that particle size of alumina is an important factor in achieving stable superhydrophobic surface. It was possible to obtain alumina surface with water contact angle (WCA) of 156° and a sliding angle of <2°. Superhydrophobicity of the modified alumina is attributed to the combined effect of the micro-nanostructure and low surface energy of fatty acid on the surface. The surface morphology of the alumina powder and coatings was determined by FESEM. The stability of the coatings was assessed by conducting water immersion test. Effect of heat treatment on WCA of the coating was also studied. The transition of alumina from hydrophilic to superhydrophobic state was explained using Wenzel and Cassie models. The method is shown to have potential application for creating superhydrophobic surface on cotton fabrics.

  3. Wetting and strength issues at Al/alpha-alumina interfaces

    SciTech Connect

    Saiz, Eduardo; Tomsia, Antoni P.; Suganuma, Katsuaki

    2003-04-15

    The wetting behavior and strength at aluminum/alumina interfaces has been an active subject of research. Al/alumina applications include ceramic-metal composites and several applications for electronic industries. In this paper the interface strength and microstructure of Al/alpha-alumina was investigated. We discovered that in a solid-state joining, the strength of the joint increases with increasing joining temperature. In a liquid-state joining, the strength of the joint gradually decreases due to the formation of unbonded areas. The strength, sigma sub b, is expressed by the following equation as a function of unbonded area, A: sigma sub b = 2.22 A + 143 (70 percent {le} A {le} 100 percent). The highest strength reached 400 MPa when the interface was formed at around the melting temperature of aluminum. An aluminum layer close to the interface became a single crystal when it was bonded to a sapphire. The following crystallographic orientation relationship is established: (1{bar 1}1){sub Al}//(001){sub {alpha}}-Al{sub 2} O{sub 3}, (110){sub Al}//<100>{sub {alpha}}-Al{sub 2}O{sub 3}. Amorphous alumina islands were formed at the interface. In the amorphous alumina, gamma-alumina nanocrystals grew from the sapphire, with the same orientation relationship to sapphire as above.

  4. Molecular dynamics simulations of ablation and spallation of gold irradiated by femtosecond laser

    NASA Astrophysics Data System (ADS)

    Demaske, Brian; Zhakhovsky, Vasily; Inogamov, Nail; Oleynik, Ivan

    2010-03-01

    The dynamics of material response to irradiation of thin gold foils by a femtosecond laser pulse is examined by molecular dynamics simulations. The major physical phenomena include ablation - the removal of material from irradiated surface and spallation - the ejection of a thin layer of material from the rear of the film. In order to reproduce the physical processes that occur under experimental conditions, we simulated 1 μm thick foils containing up to 170,000,000 atoms. Such thick foils are also needed to prevent the ablation and spallation zones from overlapping. In this presentation, we discuss the major physics of laser ablation and spallation observed in MD simulations: heating of a narrow region beneath the surface of the foil, its transformation to a metastable stress-confined state, and the rapid decomposition of this state into a strong rarefaction and compression wave. At some critical absorbed laser fluence, the rarefaction wave results in nucleation and growth of voids leading to ablation of the frontal surface. At higher absorbed fluences, the compression wave causes rear-side spallation of crystalline gold. Quantitative data such as the absorbed fluence thresholds, crater depths, and cavitation strength of gold are obtained from simulation and compared to experimental data.

  5. Comparison of Different INC Physical Models of MCNPX to Compute Spallation Neutronics of LBE Target

    NASA Astrophysics Data System (ADS)

    Feghhi, Seyed Amir Hossein; Gholamzadeh, Zohreh; Tenreiro, Claudio; Alipoor, Zahra

    2015-04-01

    Spallation particles can utilize in different fields such as neutron scattering studies, external source for burning spent fuel as well as running subcritical reactors. Different computational particle transport codes are widely used to model spallation process into the heavy targets. Among these codes, MCNPX 2.6.0 comprises various intra nuclear cascade models for spallation calculations. Impact of different intra nuclear cascade models on calculation of neutronic parameters of LBE target has been evaluated in this work. Escaped neutron yield, energy deposition and residual nuclei production in the spallation target has been calculated using the physical models. A comparison between the computational and experimental has been carried out to validate the computational data. The simulation data showed there is a good conformity between the obtained data from Bertini/Drenser and Isabel/Drenser. The data achieved by Bertini/Abla and Isabel/Abla models are close to each other for the studied parameters as well. Among the studied models, CEM showed more discrepancies with experimental and other computational data. According to the obtained data, INCL4/Drenser, INCL4/Abla and Isabel/Drenser models can meet more agreements with experimental data.

  6. Multimaterial lamination as a means of retarding penetration and spallation failures in plates

    NASA Technical Reports Server (NTRS)

    Dibattista, J. D.; Humes, D. H.

    1972-01-01

    Experimental data are presented which show that hypervelocity impact spallation and penetration failures of a single solid aluminum plate and of a solid aluminum plate spaced a distance behind a Whipple meteor bumper may be retarded by replacing the solid aluminum plate with a laminated plate. Four sets of experiments were conducted. The first set of experiments was conducted with projectile mass and velocity held constant and with polycarbonate cylinders impacted into single plates of different construction. The second set of experiments was done with single plates of various construction and aluminum spherical projectiles of similar mass but different velocities. These two experiments showed that a laminated plate of aluminum and polycarbonate or aluminum and methyl methacrylate could prevent spallation and penetration failures with a lower areal density than either an all-aluminum laminated plate or a solid aluminum plate. The aluminum laminated plate was in turn superior to the solid aluminum plate in resisting spallation and penetration failures. In addition, through an example of 6061-T6 aluminum and methyl methacrylate, it is shown that a laminated structure ballistically superior to its parent materials may be built. The last two sets of experiments were conducted using bumper-protected main walls of solid aluminum and of laminated aluminum and polycarbonate. Again, under hypervelocity impact conditions, the laminated main walls were superior to the solid aluminum main walls in retarding spallation and penetration failures.

  7. Post-irradiation examination of the Spallation Neutron Source target module

    NASA Astrophysics Data System (ADS)

    McClintock, D. A.; Ferguson, P. D.; Mansur, L. K.

    2010-03-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory is an accelerator-based pulsed neutron source that produces high-energy spallation neutrons by bombarding liquid mercury flowing through a stainless steel target vessel. During operation the proton beam and spallation neutrons produce radiation damage in the AISI 316L austenitic stainless steel target vessel and water-cooled shroud. The beam pulses also cause rapid heating of the liquid mercury, which may produce cavitation erosion damage on the inner surface of the target vessel. The cavitation erosion rate is thought to be highly sensitive to beam power and predicted to be the primary life-limiting factor of the target module. Though cavitation erosion and radiation damage to the target vessel are expected to dictate its lifetime, the effects of radiation damage and cavitation erosion to target vessels in liquid metal spallation systems are not well known. Therefore preparations are being undertaken to perform post-irradiation examination (PIE) of the liquid mercury target vessel and water-cooled shroud after end-of-life occurs. An overview of the planned PIE for the SNS target vessel is presented here, including proposed techniques for specimen acquisition and subsequent material properties characterization.

  8. BEAM-LOSS DRIVEN DESIGN OPTIMIZATION FOR THE SPALLATION NEUTRON SOURCE (SNS) RING.

    SciTech Connect

    WEI,J.; BEEBE-WANG,J.; BLASKIEWICZ,M.; CAMERON,P.; DANBY,G.; GARDNER,C.J.; JACKSON,J.; LEE,Y.Y.; LUDEWIG,H.; MALITSKY,N.; RAPARIA,D.; TSOUPAS,N.; WENG,W.T.; ZHANG,S.Y.

    1999-03-29

    This paper summarizes three-stage design optimization for the Spallation Neutron Source (SNS) ring: linear machine design (lattice, aperture, injection, magnet field errors and misalignment), beam core manipulation (painting, space charge, instabilities, RF requirements), and beam halo consideration (collimation, envelope variation, e-p issues etc.).

  9. A facility for neutrino-nucleus cross-section measurements at the spallation neutron source

    NASA Astrophysics Data System (ADS)

    Efremenko, Yu.

    2005-01-01

    In this paper we discuss the possibility of building a neutrino facility at the Spallation Neutron Source presently under construction at ORNL. At such a facility an extensive long-term program can be established to study neutrino nucleus cross-sections in the range of interest for nuclear astrophysics and nuclear theory.

  10. INFLUENCE OF MICROSTRUCTURAL ANISOTROPY ON THE SPALLATION OF 1080 EUTECTOID STEEL

    SciTech Connect

    G.T. GRAY; M.F. LOPEZ; ET AL

    2001-06-01

    While the influence of crystallographic texture on elastic and plastic constitutive response has seen extensive investigation in recent years, the influence of texture on the dynamic fracture of engineering materials remains less extensively explored. In particular, the influence of anisotropy, both textural and morphological, on the spallation behavior of materials remains poorly quantified. In this study, the spallation response of 1080-steel has been studied as a function of microstructural morphological anisotropy. In this study the influence of elongated MnS stringers, resident within a crystallographically isotropic eutectoid steel, on the spallation response of 1080 steel was investigated. That of a fully-pearlitic 1080 steel loaded to 5 GPa was found to be dominated by the heterogeneous nucleation of damage normal and orthogonal to the MnS stringers. Delamination between the matrix pearlitic microstructure and the MnS stringers was seen to correlate to a significantly lower pull-back signal during transverse loading than to that parallel to the stringer axis. The ''pull-back'' signals and post-spallation metallographic observations are discussed with reference to the influence of microstructural anisotropy on void nucleation and growth.

  11. Influence of microstructural anisotropy on the spallation of 1080 eutectoid steel

    SciTech Connect

    Bourne, N. K.; Millett, J. C. F.; Lopez, M. F.; Vecchio, K. S.; Gray, G. T. , III

    2001-01-01

    While the influence of crystallographic texture on elastic and plastic constitutive response has seen extensive investigation in recent years, the influence of texture on the dynamic fracture of engineering materials remains less extensively explored. In particular, the influence of anisotropy, both textural and morphological, on the spallation behavior of materials remains poorly quantified. In this study, the spallation response of 1080-steel has been studied as a function of microstructural morphological anisotropy. In this study the influence of elongated MnS stringers, resident within a crystallographically isotropic eutectoid steel, on the spallation response of 1080 steel was investigated. That of a fully-pearlitic 1080 steel loaded to 5 GPa was found to be dominated by the heterogeneous nucleation of damage normal and orthogonal to the MnS stringers. Delamination between the matrix pearlitic microstructure and the MnS stringers was seen to correlate to a significantly lower pull-back signal during transverse loading than to that parallel to the stringer axis. The 'pull-back' signals and post-spallation metallographic observations are discussed with reference to the influence of microstructural anisotropy on void nucleation and growth.

  12. Decay heat calculations for a 500 kW W-Ta spallation target

    NASA Astrophysics Data System (ADS)

    Yu, Quanzhi; Lu, Youlian; Hu, Zhiliang; Zhou, Bin; Yin, Wen; Liang, Tianjiao

    2015-05-01

    The China Spallation Neutron Source (CSNS) is a short-pulsed neutron scattering facility. The beam power is designed to be 100 kW in Phase I, with the capability of upgrading to 500 kW. Tantalum (Ta)-cladded tungsten (W) was chosen as the spallation target due to its high neutron yield. Ta claddings can solve the problem of the corrosiveness of W plates, although they produce high decay heat after intense irradiation. This paper presents the decay heat distributions and evolutions for the future upgraded 500 kW W-Ta spallation target. The calculations are performed using the MCNPX2.5 Monte Carlo code and the CINDER'90 activation code. The decay heat distributions show that for the W plates, decay heat is mainly produced via the spallation reaction process, whereas for the Ta claddings, it is mainly produced via the neutron capture process. An effective method of reducing the decay heat in the W-Ta target is also presented and discussed.

  13. A calorimetric measurement of the heat deposition in the vicinity of a spallation neutron target

    SciTech Connect

    Fischer, W.E.; Moritz, L.; Spitzer, H.; Thorson, I.M.

    1986-07-01

    An experiment to measure the heat deposition in various materials in the vicinity of a spallation neuron target is described. This experiment has been performed at the Thermal Neutron Facility, TRIUMF. In the analysis of the data, the contributions to the heat deposition from (n,..gamma..) capture processes, fast neutron, and prompt gamma-ray scattering are separated.

  14. Effects of Etching Time and NaOH Concentration on the Production of Alumina Nanowires Using Porous Anodic Alumina Template

    NASA Astrophysics Data System (ADS)

    Sadeghpour-Motlagh, M.; Mokhtari-Zonouzi, K.; Aghajani, H.; Kakroudi, M. Ghassemi

    2014-06-01

    In this work, two-step anodizing of commercial aluminum foil in acid oxalic solution was applied for producing alumina film. Then the anodic alumina film was etched in sodium hydroxide (NaOH) solution resulting dense and aligned alumina nanowires. This procedure leads to splitting of alumina nanotubes. Subsequently nanowires are produced. The effects of NaOH solution concentration (0.2-1 mol/L) and etching time (60-300 s) at constant temperature on characteristic of nanotubes and produced nanowires were investigated using scanning electron microscopy. The results show that an increase in NaOH solution concentration increases the rate of nanowires production and in turn the manipulation process will be more specific.

  15. Structure, stoichiometry and stability in magnetoplumbite and [beta]-alumina type ceramics

    SciTech Connect

    Cormack, A.N.; Park, J.G.

    1992-12-01

    Work has continued on the computer simulation of atomic scale defect complexes in polyaluminates with the magnetoplumbate and [beta]-alumina structures. More stringent criteria have been developed for determining the viability of interatomic potential models for these complex structured materials, details of the cation coordination having been found to be important. It appears that the energetics of point defect complex formation is the reason why Ba hexa-aluminate does not adopt the magnetoplumbate structure, in contrast to Sr hexa-aluminate, which does.

  16. Structure, stoichiometry and stability in magnetoplumbite and {beta}-alumina type ceramics. Technical progress report

    SciTech Connect

    Cormack, A.N.; Park, J.G.

    1992-12-01

    Work has continued on the computer simulation of atomic scale defect complexes in polyaluminates with the magnetoplumbate and {beta}-alumina structures. More stringent criteria have been developed for determining the viability of interatomic potential models for these complex structured materials, details of the cation coordination having been found to be important. It appears that the energetics of point defect complex formation is the reason why Ba hexa-aluminate does not adopt the magnetoplumbate structure, in contrast to Sr hexa-aluminate, which does.

  17. A technical and economic evaluation of thermal spallation drilling technology

    SciTech Connect

    1984-07-10

    Thermal spallation of rock may be defined as a type of progressive rock failure caused by the creation of thermal stresses induced by a sudden application of heat from a high temperature source. This technology is applicable to only certain types of hard rock, such as dolomite, taconite, and granite. In 1981 and 1982, the deepest holes ever drilled by this process were drilled in granite to depths of 1086 feet and 425 feet respectively. Penetration rates at the bottom of the deeper hole reached a maximum of 100 ft/hr. Because of these high rates, considerable interest was generated concerning the use of this technology for the drilling of deep holes. Based on this interest, this study was undertaken to evaluate the technical and economic aspects of the technology in general. This methodology has been used for blasthole drilling, the cutting of chambers at the bottom of drilled holes, and the cutting of narrow grooves in rock. However, because of the very high temperatures generated by the flame jet and the application of the technology to only certain types of rock, other areas of use have been very limited. In this report, evaluation of the technology was performed by conceptually designing and costing a theoretical flame jet drilling rig. The design process reviews a number of different concepts of the various components needed, and then chooses those pieces of equipment that best suit the needs of the system and have the best chance of being properly developed. The final concept consists of a flexible umbilical hose containing several internal hoses for carrying the various required fluids. An evaluation of this system was then made to determine its operational characteristics. The drilling capabilities and the economics of this rig were then compared to a conventional rotary drilling rig by theoretically drilling two holes of approximately 15,000 feet in depth. This comparison was done by use of a spread sheet type computer program. The results of this study

  18. Effect of alumina composition and surface integrity in alumina/epoxy composites on the ultrasonic attenuation properties.

    PubMed

    Cho, Eikhyun; Park, Gwanwoo; Lee, Jae-Wan; Cho, Sung-Min; Kim, Taekyung; Kim, Joongeok; Choi, Wonjoon; Ohm, Won-Suk; Kang, Shinill

    2016-03-01

    We report a method of fabricating backing blocks for ultrasonic imaging transducers, using alumina/epoxy composites. Backing blocks contain scatterers such as alumina particles interspersed in the epoxy matrix for the effective scattering and attenuation of ultrasound. Here, the surface integrity can be an issue, where the composite material may be damaged during machining because of differences in strength, hardness and brittleness of the hard alumina particles and the soft epoxy matrix. Poor surface integrity results in the formation of air cavities between the backing block and the piezoelectric element upon assembly, hence the increased reflection off the backing block and the eventual degradation in image quality. Furthermore, with an issue of poor surface integrity due to machining, it is difficult to increase alumina as scatterers more than a specific mass fraction ratio. In this study, we increased the portion of alumina within epoxy matrix by obtaining an enhanced surface integrity using a net shape fabrication method, and verified that this method could allow us to achieve higher ultrasonic attenuation. Backing blocks were net-shaped with various mass fractions of alumina to characterize the formability and the mechanical properties, including hardness, surface roughness and the internal micro-structure, which were compared with those of machined backing blocks. The ultrasonic attenuation property of the backing blocks was also measured. PMID:26585217

  19. Ultrathin Alumina Film Al-Sublattice Structure, Metal Island Nucleation at Terrace Point Defects, and How Hydroxylation Affects Wetting

    SciTech Connect

    Bogicevic, A.; Jennison, D.R.

    1999-08-09

    In this paper, we include for discussion three topics of current interest in metal oxide surface science. Using first principles density functional theory (DFT) [1] calculations, we have investigated: (1) the atomic-scale structure of experimentally-relevant ultrathin alumina films, (2) the role of common point defects in metal island nucleation on oxide terraces, and (3) the growth and morphology of metals on oxide surfaces which have high concentrations of a common impurity.

  20. Modelling mesoporous alumina microstructure with 3D random models of platelets.

    PubMed

    Wang, H; Pietrasanta, A; Jeulin, D; Willot, F; Faessel, M; Sorbier, L; Moreaud, M

    2015-12-01

    This work focuses on a mesoporous material made up of nanometric alumina 'platelets' of unknown shape. We develope a 3D random microstructure to model the porous material, based on 2D transmission electron microscopy (TEM) images, without prior knowledge on the spatial distribution of alumina inside the material. The TEM images, acquired on samples with thickness 300 nm, a scale much larger than the platelets's size, are too blurry and noisy to allow one to distinguish platelets or platelets aggregates individually. In a first step, the TEM images correlation function and integral range are estimated. The presence of long-range fluctuations, due to the TEM inhomogeneous detection, is detected and corrected by filtering. The corrected correlation function is used as a morphological descriptor for the model. After testing a Boolean model of platelets, a two-scale model of microstructure is introduced to replicate the statistical dispersion of platelets observed on TEM images. Accordingly, a set of two-scale Boolean models with varying physically admissible platelets shapes is proposed. Upon optimization, the model takes into account the dispersion of platelets in the microstructure as observed on TEM images. Comparing it to X-ray diffraction and nitrogen porosimetry data, the model is found to be in good agreement with the material in terms of specific surface area. PMID:26280446

  1. Dopant effect of yttrium and the growth and adherence of alumina on nickel-aluminum alloys

    NASA Technical Reports Server (NTRS)

    Anderson, A. B.; Mehandru, S. P.; Smialek, J. L.

    1985-01-01

    The atom superposition and electron delocalization molecular orbital theory and large cluster models have been employed to study cation vacancy diffusion in alpha-Al2O3 and the bonding of alpha-Al2O3 to nickel, aluminum, and yttrium surfaces. Al(3+) diffusion barriers in alpha-Al2O3 by the vacancy mechanism are in reasonable agreement with experiment. The barrier to Y(3+) diffusion is predicted to be much higher. Since addition of yttrium to transition metal alloys is known to reduce the growth rate and stress convolutions in protective alumina scales, this result suggests the rate-limiting step in scale growth is cation vacancy diffusion. This may partially explain the beneficial effect of yttrium dopants on scale adhesion. The theory also predicts a very strong bonding between alumina and yttrium at the surface of the alloy. This may also be important to the adhesion phenomenon. It is also found that aluminum and yttrium atoms bond very strongly to nickel because of charge transfer from their higher lying valence orbitals to the lower lying nickel s-d band.

  2. Thermal Conductivity of Alumina and Silica Nanofluids

    NASA Astrophysics Data System (ADS)

    Castellanos, Julian G. Bernal

    This thesis studies the effects of the base fluid, particle type/size, and volumetric concentration on the thermal conductivity of Alumina and Silica nanofluids. The effects of base fluid were observed by preparing samples using ethylene glycol (EG), water, and mixtures of EG/water as the base fluid and Al2O3 (10 nm) nanoparticles. The particles type/size and volumetric concentration effects were tested by preparing samples of nanofluids using Al2O3 (10nm), Al2O3 (150nm), SiO2 (15 nm), and SiO2 (80 nm) nanoparticles and ionized water as base fluid at different volumetric concentrations. All samples were mixed using a sonicator for 30 minutes and a water circulator to maintain the sample at room temperature. The thermal conductivity was measured using a Thermtest Transient Plane Source TPS 500S. The effects of gravity, Brownian motion and thermophoresis were also studied. EG produced the highest thermal conductivity enhancement out of all base fluids tested. Smaller particle size produced a higher enhancement of thermal conductivity, while the volumetric concentration did not have a significant effect in the thermal conductivity enhancement. Finally, gravity, Brownian diffusion and thermophoresis effects played a role in the total enhancement of the thermal conductivity. The nanoparticles were observed to settle rapidly after sonication suggesting gravity effects may play a significant role.

  3. Mechanical properties of alumina porcelain during heating

    NASA Astrophysics Data System (ADS)

    Šín, Peter; Podoba, Rudolf; ŠtubÅa, Igor; Trník, Anton

    2014-11-01

    The mechanical strength and Young's modulus of green alumina porcelain (50 wt. % of kaolin, 25 wt. % of Al2O3, and 25 wt. % of feldspar) were measured during heating up to 900 °C and 1100 °C, respectively. To this end, we used the three point-bending method and modulated force thermomechanical analysis (mf-TMA). The loss liberation - of the physically bound water (20 - 250 °C) strengthens the sample and Young's modulus increases its values significantly. The dehydroxylation that takes place in the range of 400 - 650 °C causes a slight decrease in Young's modulus. On the other hand, the mechanical strength slightly increases in this temperature range, although it has a sudden drop at 420 °C. Beyond the dehydroxylation range, above 650 °C, both Young's modulus and mechanical strength increase. Above 950 °C, a sharp increase of Young's modulus is caused by the solid-state sintering and the new structure created by the high-temperature reactions in metakaolinite.

  4. Annealing Would Improve beta" - Alumina Solid Electrolyte

    NASA Technical Reports Server (NTRS)

    Williams, Roger; Homer, Margie; Ryan, Margaret; Cortez, Roger; Shields, Virgil; Kisor, Adam

    2003-01-01

    A pre-operational annealing process is under investigation as a potential means of preventing a sudden reduction of ionic conductivity in a Beta"-alumina solid electrolyte (BASE) during use. On the basis of tests, the sudden reduction of ionic conductivity, followed by a slow recovery, has been found to occur during testing of the solid electrolyte and electrode components of an alkali metal thermal-to-electric converter (AMTEC) cell. At this time, high-temperature tests of limited duration have indicated the superiority of the treated BASE, but reproducible tests over thousands of hours are necessary to confirm that microcracking has been eliminated. The ionic conductivity of the treated BASE is also measured to be higher than untreated BASE at 1,073 K in low-pressure sodium vapor. Microcracking resulting in loss of conductivity was not observed with treated BASE in one high-temperature experiment, but this result must be duplicated over very long testing times to be sure of the effect. Shorter annealing times (10 to 20 hours) were found to result in significantly less loss of mass; it may be necessary for the packed powder mixture to evolve some Na2O before the Na2O can leave the ceramic.

  5. The Neutron Science TeraGrid Gateway, a TeraGrid Science Gateway to Support the Spallation Neutron Source

    SciTech Connect

    Cobb, John W; Geist, Al; Kohl, James Arthur; Miller, Stephen D; Peterson, Peter F; Pike, Gregory; Reuter, Michael A; Swain, William; Vazhkudai, Sudharshan S; Vijayakumar, Nithya N

    2006-01-01

    The National Science Foundation's (NSF's) Extensible Terascale Facility (ETF), or TeraGrid [1] is entering its operational phase. An ETF science gateway effort is the Neutron Science TeraGrid Gateway (NSTG.) The Oak Ridge National Laboratory (ORNL) resource provider effort (ORNL-RP) during construction and now in operations is bridging a large scale experimental community and the TeraGrid as a large-scale national cyberinfrastructure. Of particular emphasis is collaboration with the Spallation Neutron Source (SNS) at ORNL. The U.S. Department of Energy's (DOE's) SNS [2] at ORNL will be commissioned in spring of 2006 as the world's brightest source of neutrons. Neutron science users can run experiments, generate datasets, perform data reduction, analysis, visualize results; collaborate with remotes users; and archive long term data in repositories with curation services. The ORNL-RP and the SNS data analysis group have spent 18 months developing and exploring user requirements, including the creation of prototypical services such as facility portal, data, and application execution services. We describe results from these efforts and discuss implications for science gateway creation. Finally, we show incorporation into implementation planning for the NSTG and SNS architectures. The plan is for a primarily portal-based user interaction supported by a service oriented architecture for functional implementation.

  6. Effect of Zirconia and Alumina Fillers on the Microstructure and Mechanical Strength of Dental Glass Ionomer Cements

    PubMed Central

    Souza, Júlio C. M.; Silva, Joel B.; Aladim, Andrea; Carvalho, Oscar; Nascimento, Rubens M.; Silva, Filipe S.; Martinelli, Antonio E.; Henriques, Bruno

    2016-01-01

    Background: Glass-ionomer cements perform a protective effect on the dentin-pulp complex considering the F ions release and chemical bonding to the dental structures. On the other hand, those materials have poor physic-mechanical properties in comparison with the restorative resin composite. The main aim of this work was to evaluate the influence of zirconia and/or alumina fillers on the microstructure and strength of a resin modified glass-ionomer cement after thermal cycling. Methods: An in vitro experimental study was carried out on 9 groups (n = 10) of cylindrical samples (6 x 4 mm) made from resin modified glass-ionomer (Vitremer, 3M, USA) with different contents of alumina and/or zirconia fillers. A nano-hybrid resin composite was tested as a control group. Samples were mechanically characterized by axial compressive tests and electron scanning microscopy (SEM) coupled to energy dispersive X-ray spectrophotometry (EDS), before and after thermal cycling. Thermal cycling procedures were performed at 3000, 6000 and 10000 cycles in Fusayama´s artificial saliva at 5 and 60 oC. Results: An improvement of compressive strength was noticed on glass-ionomer reinforced with alumina fillers in comparison with the commercial glass ionomer. SEM images revealed the morphology and distribution of alumina or zirconia in the microstructure of glass-ionomers. Also, defects such as cracks and pores were detected on the glass-ionomer cements. The materials tested were not affected by thermal cycling in artificial saliva. Conclusion: Addition of inorganic particles at nano-scale such as alumina can increase the mechanical properties of glass-ionomer cements. However, the presence of cracks and pores present in glass-ionomer can negatively affect the mechanical properties of the material because they are areas of stress concentration. PMID:27053969

  7. Examination of particle/particle interactions and their impact on rheology and mixedness of an alumina/titania system

    NASA Astrophysics Data System (ADS)

    August, Cari R.

    In the manufacturing of ceramic particulate composites, improved manufacturing efficiency means two things, ease of production and increased performance. The effect of mixedness on the rheology of alumina-titania blends has been evaluated. Alumina and titania starting powders that have been examined ranged in particle size from nanoscale (50-200 nm) to micron scale (1-5 microm). Nano and micro-alumina powders have been combined individually with macro and micro-titania powders to determine how the nano/micro structure affects rheological properties and the mixedness of the final blended compositions. The effects of varying the mixing and processing techniques used to create the compositions; such as ball milling, wet mixing, high shear mixing, and varied mixing time, has been analyzed. The effect of varying surfactant additions (sodium stearate) on the mixedness and rheology of the alumina-titania blends has also been evaluated. The range of surfactant concentrations covers the measured adsorption limits of the particles in the blend, allowing sodium stearate to act not only as surfactant, but also as bulk lubricant. Rheological evaluation of these blends included torque, dynamic stress, and capillary rheometry. Dynamic stress rheometry measures and compares the viscous modulus and the shear modulus of a blend, allowing determination of its dynamic yield stress. Capillary rheometry was used to evaluate the extrusion pressures of the alumina-titania batches, for analysis with a Benbow-Bridgewater model, yielding information on extrusion wall stresses and extrudate bulk strength. The mixedness was evaluated by SEM-EDS method, which created a compositional map of a cross-sectional area of extrudate for distributional evaluation by nearest neighbor and standard deviation calculations. It was found that the use of nano-alumina and macro-titania increased processing requirements such as mixing energy and extrusion pressure, but produced extrudates with minimal flaws

  8. Processing and Characterizing Alumina/Aluminum Composites with Tailored Microstructures Formed by Reactive Metal Penetration

    SciTech Connect

    Corral, E.; Ellerby, D.; Ewsuk, K.; Fahrenholtz, B.; Loehman, R.

    1999-01-28

    In industry, the need to maximize energy efficiency depends on the availability of suitable advanced materials. Ceramic composites are exemplary materials for many advanced engineering applications because they exhibit good thermal stability, oxidation resistance and enhanced toughness. Presently, ceramic composite fabrication processes are costly, often requiring high temperatures and pressures to achieve reasonable densities. Our research is focused on developing a processing technique, that will allow production of alumina/aluminum composites using relatively low temperatures and without the application of an external force, thus reducing the processing costs. Our composites were formed using Reactive Metal Penetration (RMP), which is a process involving the reaction of molten Al with a dense ceramic preform. The result is a near net shape ceramic/metal composite with interpenetrating phases. The volume fraction of metal in the composites was varied by doping an aluminosilicate ceramic preform with silica. For this study we fabricated composites using pure mullite and mullite doped with 23 and 42 weight percent silica, yielding 18, 25, and 30 volume percent metal in the composites, respectively. Optical and Scanning Electron Microscopy were used to characterize the homogeneity and scale of the microstructure. The scale of the microstructure varied with preform composition, the reaction temperature and with secondary heat treatments. Four-point bend testing was used to evaluate the influence of microstructure on strength and reliability. During these studies a gradient in the microstructure was observed, which we further characterized using microhardness testing. Alumina/aluminum composites formed by RMP show higher toughness then monolithic alumina and have the potential for improved reliability when compared to monolithic ceramics.

  9. Ion polarization behavior in alumina under pulsed gate bias stress

    SciTech Connect

    Liu, Yu; Diallo, Abdou Karim; Katz, Howard E.

    2015-03-16

    Alkali metal ion incorporation in alumina significantly increases alumina capacitance by ion polarization. With high capacitance, ion-incorporated aluminas become promising high dielectric constant (high-k) gate dielectric materials in field-effect transistors (FETs) to enable reduced operating voltage, using oxide or organic semiconductors. Alumina capacitance can be manipulated by incorporation of alkali metal ions, including potassium (K{sup +}), sodium (Na{sup +}), and lithium (Li{sup +}), having different bond strengths with oxygen. To investigate the electrical stability of zinc tin oxide-based transistors using ion incorporated alumina as gate dielectrics, pulsed biases at different duty cycles (20%, 10%, and 2% representing 5 ms, 10 ms, and 50 ms periods, respectively) were applied to the gate electrode, sweeping the gate voltage over series of these cycles. We observed a particular bias stress-induced decrease of saturation field-effect mobility accompanied by threshold voltage shifts (ΔV{sub th}) in potassium and sodium-incorporated alumina (abbreviated as PA and SA)-based FETs at high duty cycle that persisted over multiple gate voltage sweeps, suggesting a possible creation of new defects in the semiconductor. This conclusion is also supported by the greater change in the mobility-capacitance (μC) product than in capacitance itself. Moreover, a more pronounced ΔV{sub th} over shorter times was observed in lithium-incorporated alumina (abbreviated as LA)-based transistors, suggesting trapping of electrons in existing interfacial states. ΔV{sub th} from multiple gate voltage sweeps over time were fit to stretched exponential forms. All three dielectrics show good stability using 50-ms intervals (20-Hz frequencies), corresponding to 2% duty cycles.

  10. Fatigue properties of atomic-layer-deposited alumina ultra-barriers and their implications for the reliability of flexible organic electronics

    NASA Astrophysics Data System (ADS)

    Baumert, E. K.; Pierron, O. N.

    2012-12-01

    The fatigue degradation properties of atomic-layer-deposited alumina, with thickness ranging from 4.2 to 50 nm, were investigated using a silicon micro-resonator on which the coatings were deposited and strained in a static or cyclic manner, with strain amplitudes up to 2.2%, in controlled environments. Based on the measured resonant frequency evolution, post-test scanning electron microscopy observations, and finite element models, it is shown that cracks in the alumina nucleate and propagate under cyclic loading, and that the crack growth rates scale with the strain energy release rates for crack channeling. The implications for the reliability of flexible electronics are discussed.

  11. Fatigue properties of atomic-layer-deposited alumina ultra-barriers and their implications for the reliability of flexible organic electronics

    SciTech Connect

    Baumert, E. K.; Pierron, O. N.

    2012-12-17

    The fatigue degradation properties of atomic-layer-deposited alumina, with thickness ranging from 4.2 to 50 nm, were investigated using a silicon micro-resonator on which the coatings were deposited and strained in a static or cyclic manner, with strain amplitudes up to 2.2%, in controlled environments. Based on the measured resonant frequency evolution, post-test scanning electron microscopy observations, and finite element models, it is shown that cracks in the alumina nucleate and propagate under cyclic loading, and that the crack growth rates scale with the strain energy release rates for crack channeling. The implications for the reliability of flexible electronics are discussed.

  12. Ultrafine alumina coated silicon carbide particles for alumina-silicon carbide nanocomposites

    SciTech Connect

    Warrier, K.G.K.; Hareesh, U.S.; Damodaran, A.D.

    1996-12-31

    Aluminum oxide, toughened by fine and uniform dispersion of silicon carbide particles has been found to possess interesting high temperature properties of high toughness and strength. Recent reports suggest that the finer the silicon carbide size, the better would be the fracture toughness. By addition of as few as 5 vol% submicron SiC particles strengthened Al{sub 2}O{sub 3} from 350 MPa to 1 GPa, with toughness as high as 4.7 Mpa m{sup {1/2}}. The mechanism of such high extent of fracture toughness has been investigated to be due to crack deflection and microcracking introduced by thermal expansion mismatch between particles and matrix grains, although the real contributions from the silicon carbide nanoparticles are still under investigation. In all these cases the primary requirement for most effective composite is the fine, uniform size of the particles and their homogeneous dispersion in the alumina matrix. Usual methods adopted for the preparation of composites such as physical mixing of alumina and silicon carbide particles often result in localized agglomerations and inhomogeneity making the composite inferior in properties.

  13. Adsorption and reaction of sulfur dioxide on alumina and sodium-impregnated alumina

    SciTech Connect

    Mitchell, M.B.; Sheinker, V.N.; White, M.G.

    1996-05-02

    The adsorption and oxidation of SO{sub 2} on alumina and sodium-impregnated alumina has been examined using thermogravimetric analysis and diffuse reflectance infrared Fourier transform spectroscopy. Sulfur dioxide chemisorbs initially at basic sites to form an adsorbed sulfite, which is quantitatively converted to sulfate on oxidation. It has been observed that at low coverages, nearly 2.6 {mu}mol/m{sup 2}, sodium acts as a promoter for the formation of an adsorbed sulfite and sulfate which have structures similar to those of aluminum sulfite and sulfate, respectively. At higher sodium loadings, a second type of adsorbed SO{sub 2} is formed, similar to sodium sulfite and sulfate. The species with the aluminum sulfate structure appears to be more easily decomposed than does the sodium sulfate species and accounts for the regenerable adsorption capacity. Formation of the sodium sulfate species appears to account for the loss of adsorption capacity as the number of adsorption/regeneration cycles increases. Oxidation of the sulfite form to the sulfate form can occur in the absence of added oxygen, but it is an activated process and begins to occur in measurable amounts at temperatures between 150 and 300{degree}C. Partitioning of adsorbed SO{sub 2} between aluminum and sodium forms is not a function of temperature and depends on only sodium loading. 32 refs., 14 figs., 1 tab.

  14. Biocompatibility of atomic layer-deposited alumina thin films.

    PubMed

    Finch, Dudley S; Oreskovic, Tammy; Ramadurai, Krishna; Herrmann, Cari F; George, Steven M; Mahajan, Roop L

    2008-10-01

    Presented in this paper is a study of the biocompatibility of an atomic layer-deposited (ALD) alumina (Al2O3) thin film and an ALD hydrophobic coating on standard glass cover slips. The pure ALD alumina coating exhibited a water contact angle of 55 degrees +/- 5 degrees attributed, in part, to a high concentration of -OH groups on the surface. In contrast, the hydrophobic coating (tridecafluoro-1,1,2,2-tetrahydro-octyl-methyl-bis(dimethylamino)silane) had a water contact angle of 108 degrees +/- 2 degrees. Observations using differential interference contrast microscopy on human coronary artery smooth muscle cells showed normal cell proliferation on both the ALD alumina and hydrophobic coatings when compared to cells grown on control substrates. These observations suggested good biocompatibility over a period of 7 days in vitro. Using a colorimetric assay technique to assess cell viability, the cellular response between the three substrates can be differentiated to show that the ALD alumina coating is more biocompatible and that the hydrophobic coating is less biocompatible when compared to the control. These results suggest that patterning a substrate with hydrophilic and hydrophobic groups can control cell growth. This patterning can further enhance the known advantages of ALD alumina, such as conformality and excellent dielectric properties for bio-micro electro mechanical systems (Bio-MEMS) in sensors, actuators, and microfluidics devices. PMID:18085647

  15. Luminescence and IR characterization of acid sites on alumina

    SciTech Connect

    Shen, Yan-Fei; Suib, S.L. ); Deeba, M.; Koermer, G.S. )

    1994-04-01

    Luminescence and infrared (IR) spectroscopies of pyridine and ammonia adsorption have been used to measure acidities of [gamma]-alumina. Neither luminescence nor IR spectra of pyridine adsorption show an Bronsted acidity on [gamma]-alumina pretreated to 400[degrees]C. However, luminescence emission data reveal four weak OH bands even when pretreatment is done at 600[degrees]C. Pyridine and subsequent water adsorption yield six luminescence emission bands. A red shift of the pyridine emission band is found when pretreatment or desorption temperature is increased. IR spectra of ammonia on alumina pretreated at 400[degrees]C show three deformation bands at 1452, 1465, and 1485 cm[sup [minus]1]. The first band is also observed together with a band at 1554 cm[sup [minus]1] even for pretreatment at 950[degrees]C, and it corresponds to NH[sup +][sub 4] formed from dissociative adsorption of ammonia, while the other two bands are assigned to ammonia adsorbed on Bronsted acid sites. These two bands disappear along with the appearance of a new band at 1429 cm[sup [minus]1], when deuterated alumina is pretreated at 400[degrees]C and subsequently subjected to ammonia. This new band at 1429 cm[sup [minus]1] is due to NH[sub 3]D[sup +] formed from ammonia adsorbed on acidic OD sites. Consequently, ammonia IR results demonstrate the existence of Bronsted acid sites on alumina pretreated at 400[degrees]C. 38 refs., 9 figs., 2 tabs.

  16. Aluminas with dispersoids. Tribologic properties and in vivo aging.

    PubMed

    Mandrino, A; Moyen, B; Ben Abdallah, A; Treheux, D; Orange, D

    1990-07-01

    Three base alumina ceramics with dispersoids: monoclinic zirconia alumina (A5Z), tetragonal zirconia alumina (A20Z) and aluminalon (Aa20) have been investigated because of their improved mechanical properties with reference to pure alumina (AI203). Bending strength and fracture toughness are twice higher than alumina for the most toughened. These two parameters were measured by four-points bending tests after 1 week, 1, 2, 3, 6, 12 months of non loaded in vivo aging in wistar rats. They showed a little decrease for AI203 and Aa20 and a total stability for A5Z and A20Z even after one year. For tribologic study of the ceramic/polyethylene combination, cylinder against plane and pin on flat tests were conducted on an alternative movement with hip parameters of speed and load in presence of ringer solution. For the most representative test (pin on disk), the friction coefficients were nearly the same for all materials but UHMWPE wear volume was twice lower against A20Z than against AI203. A20Z/UHMWPE combination would be very interesting as new friction couple for total hip arthroplasty. Further studies are currently conducted. PMID:2397268

  17. The nature of hydrogen in γ-alumina

    SciTech Connect

    Li, Yunguo Lousada, Cláudio M. Korzhavyi, Pavel A.

    2014-05-28

    Gibbs free energy models are derived from the calculated electronic and phonon structure of two possible models of γ-alumina, a defective spinel phase and a hydrogenated spinel phase. The intrinsic vacancies and hydrogen in the two structural models give rise to a considerable configurational (residual) entropy and significantly contribute to thermodynamic stability and physical-chemical properties of γ-alumina, which was neglected in previous studies but considered in this work. The electronic densities of states, calculated using a hybrid functional for the two structural models of γ-alumina, are presented. The dynamic stability of the two phases is confirmed by full-spectrum phonon calculations. The two phases share many similarities in their electronic structure, but can be distinguished by their vibrational spectra and specific heat. The defective spinel is found to be the ground state of γ-alumina, while the hydrogenated spinel to be a metastable phase. However, dehydration of the metastable phase into the ground state is expected to be slow due to the low diffusion rate of H, which leaves hydrogen as a locked-in impurity in γ-alumina.

  18. Design of a horizontal neutron reflectometer for the European Spallation Source

    NASA Astrophysics Data System (ADS)

    Nekrassov, D.; Trapp, M.; Lieutenant, K.; Moulin, J.-F.; Strobl, M.; Steitz, R.

    2014-08-01

    A design study of a horizontal neutron reflectometer adapted to the general baseline of the long pulse European Spallation Source (ESS) is presented. The instrument layout comprises advanced solutions for the neutron guide, high-resolution pulse shaping and beam bending onto a sample surface being thoroughly adjusted to the properties of the ESS. The length of this instrument is roughly 55 m, enabling δλ/λ resolutions from 0.5% to 10%. The incident beam is focused in horizontal plane to boost measurements of sample sizes of 1×1 cm2 and smaller with potential beam deflection in both downward and upward directions. The primary range of neutron wavelengths utilized by the instrument is 2-7.1 Å. If the wavelength range needs to be extended, then this is possible by utilizing only every second (third, fourth) pulse by suppressing all other pulses by the chopper system and thus increase the longest usable wavelength to 12.2 (17.3, 22.4) Å. Angles of incidence can be set between 0° and 9° with a total accessible q-range from 4×10-3 Å-1 up to 1 Å-1, while the δθ/θ resolution can be freely set. The instrument operates in both θ/θ (free liquid surfaces) and θ/2θ (solid-liquid, air-solid interfaces) geometries. The experimental setup will in particular enable direct studies on ultrathin films (d ≈10 Å) and buried monolayers to multilayered structures of up to 3000 Å total thickness. The horizontal reflectometer will further foster investigations of hierarchical systems from nanometer to micrometer length scale (the latter by off-specular scattering), as well as their kinetics and dynamical properties, in particular under load (shear, pressure, external fields). Polarization and polarization analysis as well as the GISANS option are designed as potential modules to be implemented in the generic instrument layout. The instrument is highly flexible and offers a variety of different measurement modes. With respect to its mechanical components the instrument

  19. Lower Permittivity Characteristic of Mesoporous-Alumina/Epoxy Composite due to Particle Porosity

    NASA Astrophysics Data System (ADS)

    Kurimoto, Muneaki; Murakami, Yoshinobu; Nagao, Masayuki

    Introduction of metal oxide nanoparticles to polymer composite material is known to have unique dielectric behavior and significant advantage in the electrical insulation performance of electrical power apparatus. This paper presents an attempt to derive the dielectric characteristics of polymer composite filled with the metal oxide particle which has mesoporous structure. Experiments were carried out in the epoxy composites filled with alumina microparticles which have the mesoporous structure (mesoporous-alumina/epoxy composites) with different particle content. Based on the measurement of the specific gravity of mesoporous-alumina/epoxy composites, the porosity of mesoporous-alumina particle in the epoxy matrix was found to be higher than that of nonporous-alumina particle. Furthermore, we evaluated relative permittivity of mesoporous-alumina/epoxy composites by measuring the capacitance of its specimens. As the results, we verified that the permittivity of mesoporous-alumina/epoxy composites was lower than that of nonporous-alumina/epoxy composites due to the particle porosity.

  20. Improving Fatigue Damage Resistance of Alumina through Surface Grading

    PubMed Central

    Ren, L.; Liu, L.; Bhowmick, S.; Gerbig, Y.B.; Janal, M.N.; Thompson, V.P.; Zhang, Y.

    2011-01-01

    Porcelain-veneered alumina crown restorations often fail from bulk fracture resulting from radial cracks that initiate at the cementation surface with repeated flexure of the stiffer crown layers on the soft dentin support. We hypothesized that bulk fracture may be substantially mitigated by grading the elastic modulus at the crown surfaces. In this study, we fabricated graded structures by infiltrating glass into dense alumina plates, resulting in a diminished modulus at the surface layers. The plates were then bonded to polycarbonate substrates and subjected to fatigue loading in water. Tests were terminated when fracture occurred at the cementation tensile surface or at the fatigue endurance limit (1 million cycles). Infiltrated specimens showed a significant increase in fatigue fracture loads over non-infiltrated controls. Our results indicate that controlled elastic gradients at the surface could be highly beneficial in the design of fracture-resistant alumina crowns. PMID:21555776

  1. Modifying alumina red mud to support a revegetation cover

    NASA Astrophysics Data System (ADS)

    Xenidis, A.; Harokopou, A. D.; Mylona, E.; Brofas, G.

    2005-02-01

    Alumina red mud, a fine-textured, iron-rich, alkaline residue, is the major waste product of bauxite digestion with caustic soda to remove alumina. The high alkalinity and salinity as well as the poor nutrient status are considered to be the major constraints of red mud revegetation. This research was conducted to evaluate the ameliorating effect of gypsum, sewage sludge, ferrous sulfate, ammonium sulfate, ammonium nitrate, and calcium phosphate on alumina red mud. The effectiveness of the mixtures was evaluated by applying extraction tests and performing experiments using six plant species. Gypsum amendment significantly reduced the pH, electrical conductivity, and sodium and aluminum content of red mud. Sewage sludge application had an extended effect in improving both the soil structure and the nutrient status of the gypsum-amended red mud. Together with the gypsum and sewage sludge, calcium phosphate application into red mud enhanced plant growth and gave the most promising results.

  2. Characteristics of alumina particles in dispersion-strengthened copper alloys

    NASA Astrophysics Data System (ADS)

    Zhang, Xue-hui; Li, Xiao-xian

    2014-11-01

    Two types of alumina dispersion-strengthened copper (ADSC) alloys were fabricated by a novel in-situ reactive synthesis (IRS) and a traditional internal oxidation (IO) process. The features of alumina dispersoids in these ADSC alloys were investigated by X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy. It is found that nano-sized γ-Al2O3 particles of approximately 10 nm in diameter are homogeneously distributed in the IRS-ADSC composites. Meanwhile, larger-sized, mixed crystal structure alumina with rod-shaped morphology is embedded in the IO-ADSC alloy. The IRS-ADSC composites can obtain better mechanical and physical properties than the IO-ADSC composites; the tensile strength of the IRS-ADSC alloy can reach 570 MPa at room temperature, its electrical conductivity is 85% IACS, and the Rockwell hardness can reach 86 HRB.

  3. Dynamic fragmentation of cellular, ice-templated alumina scaffolds

    NASA Astrophysics Data System (ADS)

    Tan, Yi Ming; Cervantes, Octavio; Nam, SeanWoo; Molitoris, John D.; Hooper, Joseph P.

    2016-01-01

    We examine the dynamic failure of ice-templated freeze-cast alumina scaffolds that are being considered as biomimetic hierarchical structures. Three porosities of alumina freeze-cast structures were fabricated, and a systematic variation in microstructural properties such as lamellar width and thickness was observed with changing porosity. Dynamic impact tests were performed in a light-gas gun to examine the failure properties of these materials under high strain-rate loading. Nearly complete delamination was observed following impact, along with characteristic cracking across the lamellar width. Average fragment size decreases with increasing porosity, and a theoretical model was developed to explain this behavior based on microstructural changes. Using an energy balance between kinetic, strain, and surface energies within a single lamella, we are able to accurately predict the characteristic fragment size using only standard material properties of bulk alumina.

  4. The surface reaction kinetics of salicylate on alumina

    SciTech Connect

    Wang, Z.; Ainsworth, C.C.; Friedrich, D.M.; Joly, A.G.; Gassman, P.L.

    1997-12-31

    The kinetics of reaction of salicylate with colloidal alumina in aqueous suspension and with Al(III) in homogeneous aqueous solution were studied by stopped-flow laser fluorescence spectroscopy. The emission spectra confirmed the formation of both monodentate complexes and more stable bidentate chelates. Temporal evolution of the spectra indicated that the reaction was fast (within first few minutes) for both the homogeneous and heterogeneous reactions but slowed down afterwards for the latter. Reactions completed within 10 minutes in homogeneous phase at pH 3.3 but took more than 12 hours in alumina suspension. Analysis of the fluorescence intensity within first four minutes showed that in homogeneous phase the reaction followed a single pseudo-first-order kinetics. In alumina suspension log plots were nonlinear and characteristic of multiple heterogeneous reaction paths. The kinetics are interpreted in terms of the simultaneous formation of multiple species as well as subsequent conversion between species.

  5. Fabrication of porous alumina templates for electrochemical synthesis of nanowires

    NASA Astrophysics Data System (ADS)

    Saidin, N. U.; Kok, Y. K.; Ng, I. K.; Ahmad Bustamam, F. K.; Zali, N. Mat; Zainal Abidin, S. S.

    2012-07-01

    Porous alumina membranes are often used as templates for synthesizing nanowire arrays due to their welldefined pore structures and uniform pore sizes. In this study, one-dimensional metallic nanowire arrays with wellcontrolled dimensions and structures were synthesized via template-directed electrodeposition using in-house fabricated alumina membranes as scaffolds. Porous alumina membranes with uniform nanoscale pore diameters and interpore distances were fabricated by a two-step anodisation technique. Pore diameters, depths as well as spacings between adjacent pores were carefully controlled by the anodizing conditions used. The morphologies and structures of the templates and the nanowires produced were reported using scanning electron microscopy (SEM) and X-ray diffraction for characterization.

  6. Molecular dynamics studies of interfacial water at the alumina surface.

    SciTech Connect

    Argyris, Dr. Dimitrios; Ho, Thomas; Cole, David

    2011-01-01

    Interfacial water properties at the alumina surface were investigated via all-atom equilibrium molecular dynamics simulations at ambient temperature. Al-terminated and OH-terminated alumina surfaces were considered to assess the structural and dynamic behavior of the first few hydration layers in contact with the substrates. Density profiles suggest water layering up to {approx}10 {angstrom} from the solid substrate. Planar density distribution data indicate that water molecules in the first interfacial layer are organized in well-defined patterns dictated by the atomic terminations of the alumina surface. Interfacial water exhibits preferential orientation and delayed dynamics compared to bulk water. Water exhibits bulk-like behavior at distances greater than {approx}10 {angstrom} from the substrate. The formation of an extended hydrogen bond network within the first few hydration layers illustrates the significance of water?water interactions on the structural properties at the interface.

  7. Plastic deformation and sintering of alumina under high pressure

    SciTech Connect

    Liu, Fangming; Liu, Pingping; Wang, Haikuo; Xu, Chao; Yin, Shuai; Yin, Wenwen; Li, Yong; He, Duanwei

    2013-12-21

    Plastic deformation of alumina (Al{sub 2}O{sub 3}) under high pressure was investigated by observing the shape changes of spherical particles, and the near fully dense transparent bulks were prepared at around 5.5 GPa and 900 °C. Through analyzing the deformation features, densities, and residual micro-strain of the Al{sub 2}O{sub 3} compacts prepared under high pressures and temperatures (2.0–5.5 GPa and 600–1200 °C), the effects of plastic deformation on the sintering behavior of alumina have been demonstrated. Under compression, the microscopic deviatoric stress caused by grain-to-grain contact could initiate the plastic deformation of individual particles, eliminate pores of the polycrystalline samples, and enhance the local atomic diffusion at the grain boundaries, thus produced transparent alumina bulks.

  8. Characterisation of alumina hip-joint wear by FIB Microscopy

    NASA Astrophysics Data System (ADS)

    Zeng, Peng; Inkson, Beverley J.; Rainforth, W. Mark

    2006-02-01

    The wear of hip-joints is a significant clinical problem, which causes adverse tissue reactions leading to bone absorption and consequent loosening of the fixation. Artificial hip joints retrieved after use and tested on simulators typically exhibit a 'stripe' wear area on the surface of the alumina bearing components. Focused Ion Beam (FIB) microscopy has been used to investigate the sub-surface damage mechanisms in worn alumina hip-joints for the first time. The alumina acetabular cup, both inside and outside the 'stripe' wear trace, has been cross-sectioned by FIB milling. The sub-surface microstructures revealed by the FIB machining, outside, inside and at the edge of the 'stripe' have been imaged by SEM and FIB and are compared with the microstructure of unworn bulk material. The advantage of this technique is that it enables site specific selected areas of the worn surface to be analysed.

  9. Thermal and Electrical Characterization of Alumina Substrate for Microelectronic Applications

    SciTech Connect

    Ahmad, S.; Ibrahim, A.; Alias, R.; Shapee, S. M.; Ambak, Z.; Zakaria, S. Z.; Yahya, M. R.; Mat, A. F. A.

    2010-03-11

    This paper reports the effect of sintering temperature on thermal and electrical properties of alumina material as substrate for microelectronic devices. Alumina materials in the form of green sheet with 1 mm thickness were sintered at 1100 deg. C, 1300 deg. C and 1500 deg. C for about 20 hours using heating and cooling rates of 2 deg. C/min. The densities were measured using densitometer and the microstructures of the samples were analyzed using SEM micrographs. Meanwhile thermal and electrical properties of the samples were measured using flash method and impedance analyzer respectively. It was found that thermal conductivity and thermal diffusivity of the substrate increases as sintering temperature increases. It was found also that the dielectric constant of alumina substrate increases as the sintering temperature increases.

  10. Studies on synthesis of alumina nanopowder from synthetic Bayer liquor

    SciTech Connect

    Mazloumi, Mahyar; Arami, Hamed; Khalifehzadeh, Razieh; Sadrnezhaad, S.K. . E-mail: sadrnezh@sharif.edu

    2007-06-05

    Procedure for synthesis of alumina nanopowder from Bayer liquor (synthetic sodium aluminate solution) is investigated. Cooling, ageing and then addition of 3 ml/l Tiron (1,2-dihydroxy-3,5-benzene disulfonic acid disodium salt) to the supersaturated liquor affect purity and fineness of the nanopowder product. X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray (EDAX) analyses indicate that purity of the alumina nanopowder increases with the aging time. Experimental observations show that highly pure alumina nanopowders could be produced by direct calcination of cold gelatinous sodium aluminate solution followed by careful washing at a Tiron concentration of 3 ml/l NaOH.

  11. Sodium-beta Alumina Batteries: Status and Challenges

    SciTech Connect

    Lu, XC; Lemmon, JP; Sprenkle, V; Yang, ZG

    2010-09-01

    This paper provides a review of materials and designs for sodium-beta alumina battery technology and discusses the challenges ahead for further technology improvement. Sodium-beta alumina batteries have been extensively developed in recent years and encouraging progress in performance and cycle life has been achieved. The battery is composed of an anode, typically molten sodium, and a cathode that can be molten sulfur (Na-S battery) or a transition metal halide incorporated with a liquid phase secondary electrolyte (e.g.. ZEBRA battery). In most cases the electrolyte is a dense solid beta ''-Al(2)O(3), sodium ion-conducting membrane. The issues' prohibiting widespread commercialization of sodium-beta alumina technology are rekited to the materials and methods of manufacturing that impact cost, safety, and performance characteristics.

  12. Origin of high-alumina basalt, andesite, and dacite magmas

    USGS Publications Warehouse

    Hamilton, W.

    1964-01-01

    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it.

  13. Origin of High-Alumina Basalt, Andesite, and Dacite Magmas.

    PubMed

    Hamilton, W

    1964-10-30

    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it. PMID:17794034

  14. Alumina composites for oxide/oxide fibrous monoliths

    SciTech Connect

    Cruse, T. A.; Polzin, B. J.; Picciolo, J. J.; Singh, D.; Tsaliagos, R. N.; Goretta, K. C.

    2000-03-01

    Most work on ceramic fibrous monoliths (FMs) has focused on the Si{sub 3}N{sub 4}/BN system. In an effort to develop oxidation-resistant FMs, several oxide systems have recently been examined. Zirconia-toughened alumina and alumina/mullite appear to be good candidates for the cell phase of FMs. These composites offer higher strength and toughness than pure alumina and good high-temperature stability. By combining these oxides, possibly with a weaker high-temperature oxide as the cell-boundary phase, it should be possible to product a strong, resilient FM that exhibits graceful failure. Several material combinations have been examined. Results on FM fabrication and microstructural development are presented.

  15. Nanoscale electrochemical metallization memories based on amorphous (La, Sr)MnO3 using ultrathin porous alumina masks

    NASA Astrophysics Data System (ADS)

    Liu, Dongqing; Zhang, Chaoyang; Wang, Guang; Shao, Zhengzheng; Zhu, Xuan; Wang, Nannan; Cheng, Haifeng

    2014-02-01

    Nanoscale electrochemical metallization (ECM) memories based on amorphous La1-xSrxMnO3 (a-LSMO) were fabricated using ultrathin porous alumina masks. The ultrathin alumina masks, with thicknesses of about 200 nm and pore diameters of about 80 nm, were fabricated through a typical two-step anodization electrochemical procedure and transferred onto conductive Pt/Ti/SiO2/Si substrates. Resistive switching (RS) properties of the individual Ag/a-LSMO/Pt ECM cell were directly measured using a conductive atomic force microscope. The cells exhibited typical RS characteristics and the OFF/ON resistance ratio is as high as 102. Reproducible RS behaviours on the same ECM cell and the I-V cycles obtained from different ECM cells ensured that the RS properties in nanoscale Ag/a-LSMO/Pt cells are reproducible and reliable. This work provides an effective approach for the preparation of nanostructured large-scale ordered ECM memories or memristors.

  16. Systematic neutron guide misalignment for an accelerator-driven spallation neutron source

    NASA Astrophysics Data System (ADS)

    Zendler, C.; Bentley, P. M.

    2016-08-01

    The European Spallation Source (ESS) is a long pulse spallation neutron source that is currently under construction in Lund, Sweden. A considerable fraction of the 22 planned instruments extend as far as 75-150 m from the source. In such long beam lines, misalignment between neutron guide segments can decrease the neutron transmission significantly. In addition to a random misalignment from installation tolerances, the ground on which ESS is built can be expected to sink with time, and thus shift the neutron guide segments further away from the ideal alignment axis in a systematic way. These systematic errors are correlated to the ground structure, position of buildings and shielding installation. Since the largest deformation is expected close to the target, even short instruments might be noticeably affected. In this study, the effect of this systematic misalignment on short and long ESS beam lines is analyzed, and a possible mitigation by overillumination of subsequent guide sections investigated.

  17. THERMAL HYDRAULIC ANALYSIS OF A LIQUID-METAL-COOLED NEUTRON SPALLATION TARGET

    SciTech Connect

    W. GREGORY; R. MARTIN; T. VALACHOVIC

    2000-07-01

    We have carried out numerical simulations of the thermal hydraulic behavior of a neutron spallation target where liquid metal lead-bismuth serves as both coolant and as a neutron spallation source. The target is one of three designs provided by the Institute of Physics and Power Engineering (IPPE) in Russia. This type of target is proposed for Accelerator-driven Transmutation of Waste (ATW) to eliminate plutonium from hazardous fission products. The thermal hydraulic behavior was simulated by use of a commercial CFD computer code called CFX. Maximum temperatures in the diaphragm window and in the liquid lead were determined. In addition the total pressure drop through the target was predicted. The results of the CFX analysis were close to those results predicted by IPPE in their preliminary analysis.

  18. Negative pressures and spallation in water drops subjected to nanosecond shock waves

    DOE PAGESBeta

    Stan, Claudiu A.; Willmott, Philip R.; Stone, Howard A.; Koglin, Jason E.; Liang, Mengning; Aquila, Andrew L.; Robinson, Joseph S.; Gumerlock, Karl L.; Blaj, Gabriel; Sierra, Raymond G.; et al

    2016-05-16

    Most experimental studies of cavitation in liquid water at negative pressures reported cavitation at tensions significantly smaller than those expected for homogeneous nucleation, suggesting that achievable tensions are limited by heterogeneous cavitation. We generated tension pulses with nanosecond rise times in water by reflecting cylindrical shock waves, produced by X-ray laser pulses, at the internal surface of drops of water. Depending on the X-ray pulse energy, a range of cavitation phenomena occurred, including the rupture and detachment, or spallation, of thin liquid layers at the surface of the drop. When spallation occurred, we evaluated that negative pressures below –100 MPamore » were reached in the drops. As a result, we model the negative pressures from shock reflection experiments using a nucleation-and-growth model that explains how rapid decompression could outrun heterogeneous cavitation in water, and enable the study of stretched water close to homogeneous cavitation pressures.« less

  19. Spallation Model for the Titanium-Rich Supernova Remnant Cassiopeia A

    SciTech Connect

    Ouyed, Rachid; Leahy, Denis; Ouyed, Amir; Jaikumar, Prashanth

    2011-10-07

    Titanium-rich subluminous supernovae are rare and challenge current SN nucleosynthesis models. We present a model in which ejecta from a standard supernova is impacted by a second explosion of the neutron star (a quark nova), resulting in spallation reactions that lead to {sup 56}Ni destruction and {sup 44}Ti creation under the right conditions. Basic calculations of the spallation products shows that a delay between the two explosions of {approx}5 days reproduces the observed abundance of {sup 44}Ti in Cas A and explains its low luminosity as a result of the destruction of {sup 56}Ni. Our results could have important implications for light curves of subluminous as well as superluminous supernovae.

  20. A neutron resonance capture analysis experimental station at the ISIS spallation source.

    PubMed

    Pietropaolo, Antonino; Gorini, Giuseppe; Festa, Giulia; Reali, Enzo; Grazzi, Francesco; Schooneveld, Erik M

    2010-09-01

    Neutron resonance capture analysis (NRCA) is a nuclear technique that is used to determine the elemental composition of materials and artifacts (e.g., bronze objects) of archaeological interest. NRCA experiments are mostly performed at the GELINA facility in Belgium, a pulsed neutron source operating with an electron linear accelerator. Very intense fluxes of epithermal neutrons are also provided by spallation neutron sources, such as the ISIS spallation neutron source in the United Kingdom. In the present study, the suitability of the Italian Neutron Experimental Station (INES) beam line for NRCA measurements is assessed using a compact (n, γ) resonance detector made of a Yttrium-Aluminum-Perovskite (YAP) scintillation crystal coupled with a silicon photomultiplier (SiPM) readout. The measurements provided a qualitative recognition of the composition of the standard sample, a lower limit for the sensitivity for NRCA for almost-in-traces elements, and an estimation of the relative isotopic concentration in the sample. PMID:20828445

  1. Spallation model for the titanium-rich supernova remnant cassiopeia A.

    PubMed

    Ouyed, Rachid; Leahy, Denis; Ouyed, Amir; Jaikumar, Prashanth

    2011-10-01

    Titanium-rich subluminous supernovae are rare and challenge current SN nucleosynthesis models. We present a model in which ejecta from a standard supernova is impacted by a second explosion of the neutron star (a quark nova), resulting in spallation reactions that lead to (56)Ni destruction and (44)Ti creation under the right conditions. Basic calculations of the spallation products shows that a delay between the two explosions of ∼5  days reproduces the observed abundance of (44)Ti in Cas A and explains its low luminosity as a result of the destruction of (56)Ni. Our results could have important implications for light curves of subluminous as well as superluminous supernovae. PMID:22107282

  2. Challenges and design solutions of the liquid hydrogen circuit at the European Spallation Source

    SciTech Connect

    Gallimore, S.; Nilsson, P.; Sabbagh, P.; Takibayev, A.; Weisend II, J. G.; Beßler, Y.; Klaus, M.

    2014-01-29

    The European Spallation Source (ESS), Lund, Sweden will be a 5MW long-pulse neutron spallation research facility and will enable new opportunities for researchers in the fields of life sciences, energy, environmental technology, cultural heritage and fundamental physics. Neutrons are produced by accelerating a high-energy proton beam into a rotating helium-cooled tungsten target. These neutrons pass through moderators to reduce their energy to an appropriate range (< 5 meV for cold neutrons); two of which will use liquid hydrogen at 17 K as the moderating and cooling medium. There are several technical challenges to overcome in the design of a robust system that will operate under such conditions, not least the 20 kW of deposited heat. These challenges and the associated design solutions will be detailed in this paper.

  3. Generation of negative pressures and spallation phenomena in diamond exposed to a picosecond laser pulse

    SciTech Connect

    Abrosimov, S A; Bazhulin, A P; Bol'shakov, A P; Konov, V I; Krasyuk, I K; Pashinin, P P; Ral'chenko, V G; Semenov, A Yu; Sovyk, D N; Stuchebryukhov, I A; Khomich, A A; Fortov, V E; Khishchenko, K V

    2014-06-30

    The spallation phenomena in poly- and single-crystal synthetic diamonds have been experimentally investigated. A shockwave impact on a target was implemented using a 70-ps laser pulse in the Kamerton-T facility. The ablation pressure of 0.66 TPa on the front target surface was formed by pulsed radiation of a neodymium phosphate glass laser (second harmonic λ = 0.527 mm, pulse energy 2.5 J) with an intensity as high as 2 × 10{sup 13} W cm{sup -2}. The maximum diamond spall strength σ* ≈ 16.5 GPa is found to be 24% of the theoretical ultimate strength. Raman scattering data indicate that a small amount of crystalline diamond in the spallation region on the rear side of the target is graphitised. (extreme light fields and their applications)

  4. Negative Pressures and Spallation in Water Drops Subjected to Nanosecond Shock Waves.

    PubMed

    Stan, Claudiu A; Willmott, Philip R; Stone, Howard A; Koglin, Jason E; Liang, Mengning; Aquila, Andrew L; Robinson, Joseph S; Gumerlock, Karl L; Blaj, Gabriel; Sierra, Raymond G; Boutet, Sébastien; Guillet, Serge A H; Curtis, Robin H; Vetter, Sharon L; Loos, Henrik; Turner, James L; Decker, Franz-Josef

    2016-06-01

    Most experimental studies of cavitation in liquid water at negative pressures reported cavitation at tensions significantly smaller than those expected for homogeneous nucleation, suggesting that achievable tensions are limited by heterogeneous cavitation. We generated tension pulses with nanosecond rise times in water by reflecting cylindrical shock waves, produced by X-ray laser pulses, at the internal surface of drops of water. Depending on the X-ray pulse energy, a range of cavitation phenomena occurred, including the rupture and detachment, or spallation, of thin liquid layers at the surface of the drop. When spallation occurred, we evaluated that negative pressures below -100 MPa were reached in the drops. We model the negative pressures from shock reflection experiments using a nucleation-and-growth model that explains how rapid decompression could outrun heterogeneous cavitation in water, and enable the study of stretched water close to homogeneous cavitation pressures. PMID:27182751

  5. The possible use of a spallation neutron source for neutron capture therapy with epithermal neutrons

    SciTech Connect

    Grusell, E.; Conde, H.; Larsson, B.; Roennqvist, T.; Sornsuntisook, O.; Crawford, J.; Reist, H.; Dahl, B.; Sjoestrand, N.G.; Russel, G. . Dept. of Radiation Sciences; Paul Scherrer Inst. , Villigen; Chalmers Univ. of Tech., Goeteborg . Dept. of Reactor Physics; Los Alamos National Lab., NM )

    1989-01-01

    Spallation is induced in a heavy material by 72 MeV protons. The hereby produced neutrons with essentially an evaporation spectrum with a peak energy of less than 2 MeV are moderated in two steps, first in iron, and then in carbon. Results from neutron fluence measurements in a perspex phantom placed close to the moderator are presented. Monte Carlo calculations of neutron fluence in a water phantom are also presented under some chosen configurations of spallation source and moderator. The calculations and measurements show a good agreement and also show that useful thermal neutron fluences are attainable in the depth of the brain, at proton currents of less than 0.5 mA. 3 refs., 5 figs., 4 tabs.

  6. Status of R&D on mitigating the effects of pressure waves for the Spallation Neutron Source mercury target

    NASA Astrophysics Data System (ADS)

    Riemer, Bernard W.; Wendel, Mark W.; Felde, David K.; Abdou, Ashraf A.; McClintock, David A.

    2012-12-01

    The Spallation Neutron Source (SNS) at the Oak Ridge National Laboratory has been conducting R&D on mitigating the effects of pressure waves in mercury spallation targets since 2001. More precisely, cavitation damage of the target vessel caused by the short beam pulse threatens to limit its lifetime more severely than radiation damage as well as limit its ultimate power capacity - and hence its neutron intensity performance. The R&D program has moved from verification of the beam-induced damage phenomena to study of material and surface treatments for damage resistance to the current emphasis on gas injection techniques for damage mitigation. Two techniques are being worked on: injection of small dispersed gas bubbles that mitigate the pressure waves volumetrically; and protective gas walls that isolate the vessel from the damaging effects of collapsing cavitation bubbles. The latter has demonstrated good damage mitigation during in-beam testing with limited pulses, and adequate gas wall coverage at the beam entrance window has been demonstrated with the SNS mercury target flow configuration using a full scale mercury test loop. A question on the required area coverage remains which depends on results from SNS target post irradiation examination. The small gas bubble technique has been less effective during past in-beam tests but those results were with un-optimized and un-verified bubble populations. Another round of in-beam tests with small gas bubbles is planned for 2011. The first SNS target was removed from service in mid 2009 and samples were cut from two locations at the target's beam entrance window. Through-wall damage was observed at the innermost mercury vessel wall (not a containment wall). The damage pattern suggested correlation with the local mercury flow condition which is nearly stagnant at the peak damage location. Detailed post irradiation examination of the samples is under way that will assess the erosion and measure irradiation-induced changes

  7. Status of R&D on Mitigating the Effects of Pressure Waves for the Spallation Neutron Source Mercury Target

    SciTech Connect

    Riemer, Bernie; Wendel, Mark W; Felde, David K; Abdou, Ashraf A; McClintock, David A

    2012-01-01

    The Spallation Neutron Source (SNS) at the Oak Ridge National Laboratory has been conducting R&D on mitigating the effects of pressure waves in mercury spallation targets since 2001. More precisely, cavitation damage of the target vessel caused by the short beam pulse threatens to limit its lifetime more severely than radiation damage as well as limit its ultimate power capacity and hence its neutron intensity performance. The R&D program has moved from verification of the beam-induced damage phenomena to study of material and surface treatments for damage resistance to the current emphasis on gas injection techniques for damage mitigation. Two techniques are being worked on: injection of small dispersed gas bubbles that mitigate the pressure waves volumetrically; and protective gas walls that isolate the vessel from the damaging effects of collapsing cavitation bubbles. The latter has demonstrated good damage mitigation during in-beam testing with limited pulses, and adequate gas wall coverage at the beam entrance window has been demonstrated with the SNS mercury target flow configuration using a full scale mercury test loop. A question on the required area coverage remains which depends on results from SNS target post irradiation examination. The small gas bubble technique has been less effective during past in-beam tests but those results were with un-optimized and un-verified bubble populations. Another round of in-beam tests with small gas bubbles is planned for 2011. The first SNS target was removed from service in mid 2009 and samples were cut from two locations at the target s beam entrance window. Through-wall damage was observed at the innermost mercury vessel wall (not a containment wall). The damage pattern suggested correlation with the local mercury flow condition which is nearly stagnant at the peak damage location. Detailed post irradiation examination of the samples is under way that will assess the erosion and measure irradiation-induced changes

  8. Alumina over-coating on Pd nanoparticle catalysts by atomic layer deposition : enhanced stability and reactivity.

    SciTech Connect

    Feng, H.; Lu, J.; Stair, P. C.; Elam, J. W.

    2011-04-01

    ALD Alumina was utilized as a protective layer to inhibit the sintering of supported nano-sized ALD Pd catalysts in the methanol decomposition reaction carried out at elevated temperatures. The protective ALD alumina layers were synthesized on Pd nanoparticles (1-2 nm) supported on high surface area alumina substrates. Up to a certain over-coat thickness, the alumina protective layers preserved or even slightly enhanced the catalytic activity and prevented sintering of the Pd nanoparticles up to 500 C.

  9. Hydrogen removal from e-beam deposited alumina thin films by oxygen ion beam

    SciTech Connect

    Das, Arijeet Mukharjee, C. Rajiv, K. Bose, Aniruddha Singh, S. D. Rai, S. K.; Ganguli, Tapas; Joshi, S. C.; Deb, S. K.; Phase, D. M.

    2014-04-24

    Hydrogen interstitials and oxygen vacancies defects create energy levels in the band gap of alumina. This limits the application of alumina as a high-k dielectric. A low thermal budget method for removal of hydrogen from alumina is discussed. It is shown that bombardment of alumina films with low energy oxygen ion beam during electron beam evaporation deposition decreases the hydrogen concentration in the film significantly.

  10. Factors contributing to the breakdown of sodium beta-alumina

    SciTech Connect

    Buechele, A.C.

    1982-05-01

    Clarification of the breakdown process occurring during charge transfer in sodium beta alumina solid electrolytes was derived from: (1) studying the effects of molten sodium contact at 350/sup 0/C on single crystal sodium beta alumina and polycrystalline sodium beta alumina; (2) determination of critical current density by monitoring acoustic emissions accompanying crack growth in sodium/sodium beta alumina/sodium cells subjected to linear current ramping at 1 mA cm/sup -2/ sec/sup -1/; (3) failure analysis conducted on cycled electrolytes, some from commercial sodium/sulfur cells, which had been subjected to up to 703 Ahr cm/sup -2/ of charge transfer. Gray coloration developing in beta aluminas in contact with molten sodium was found to be a consequence of formation, through reduction by sodium, of oxygen vacancies charge compensated by electrons. Electronic conductivity of the electrolyte increases as a result. No second phase formation was detected. Colored electrolytes from sodium/sulfur cells show evidence of a newly recognized degradation mechanism in which fracture occurs when sodium is reduced and deposited internally under pressure as metal in regions where an electronic conductivity gradient exists. Heating colored beta aluminas in air produces reoxidation and bleaching. Kinetics and other properties of the coloration and bleaching processes were determined. Critical current density was found to bear an inverse relation to average electrolyte grain size. Evidence was found in the cycled electrolytes for a slow crack growth mechanism and a progressive mode of degradation advancing from the sulfur electrode interface. Implications of the findings for the construction and operation of sodium/sulfur battery systems are discussed.

  11. Microseparation and stripe wear in alumina-on-alumina hip implants.

    PubMed

    Affatato, Saverio; Traina, Francesco; Toni, Aldo

    2011-06-01

    The combination of materials that still has highest wear resistance for total hip replacement is ceramic-on-ceramic. However, brittleness is a major concern for ceramics: in vivo and in vitro studies on ceramic hip prostheses correlate microseparation with hip noise, ceramic wear, or ceramic liner damage. Ceramic microseparation can lead to edge load, ceramic head wear, and squeaking. The aim of this in vitro study was to investigate whether different angles of inclination influence the wear pattern of alumina-on-alumina hip joints with micro-separation during the swing phase. We also evaluated the wear rate obtained from this in vitro investigation with retrieval specimens obtained at 13 years' mean follow-up. The study was performed using a 12-station hip joint wear simulator (Shore Western, Monrovia, CA, USA) under bovine calf serum used as lubricant. Wear was evaluated by the gravimetric method and the test length was set at two million cycles. After two million cycles, a volumetric loss of 0.11 ±0.03 mm3 and 0.12 ±0.06 mm3 was observed, respectively, for 23° and 63° angles of inclination. In particular, the results obtained in this work revealed an increase of about 12-fold compared to previous results without microseparation conditions. No significant differences were observed between the two different inclinations on the wear patterns of the acetabular cups with a level of significance of a = 0.5. The location and general shape of the stripes wear were similar for the retrieved and simulator balls. PMID:21725932

  12. Process technology and effects of spallation products: Circuit components, maintenance, and handling

    SciTech Connect

    Sigg, B.; Haines, S.J.; Dressler, R.; McManamy, T.

    1996-06-01

    Working Session D included an assessment of the status of the technology and components required to: (1) remove impurities from the liquid metal (mercury or Pb-Bi) target flow loop including the effects of spallation products, (2) provide the flow parameters necessary for target operations, and (3) maintain the target system. A series of brief presentations were made to focus the discussion on these issues. The subjects of these presentations, and presenters were: (1) Spallation products and solubilities - R. Dressler; (2) Spallation products for Pb-Bi - Y. Orlov; (3) Clean/up/impurity removal components - B. Sigg; (4) {open_quotes}Road-Map{close_quotes} and remote handling needs - T. McManamy; (5) Remote handling issues and development - M. Holding. The overall conclusion of this session was that, with the exception of (i) spallation product related processing issues, (ii) helium injection and clean-up, and (iii) specialized remote handling equipment, the technology for all other circuit components (excluding the target itself) exists. Operating systems at the Institute of Physics in Riga, Latvia (O. Lielausis) and at Ben-Gurion University in Beer Shiva, Israel (S. Lesin) have demonstrated that other liquid metal circuit components including pumps, heat exchangers, valves, seals, and piping are readily available and have been reliably used for many years. In the three areas listed above, the designs and analysis are not judged to be mature enough to determine whether and what types of technology development are required. Further design and analysis of the liquid metal target system is therefore needed to define flow circuit processing and remote handling equipment requirements and thereby identify any development needs.

  13. Fundamental neutron physics beamline at the spallation neutron source at ORNL

    DOE PAGESBeta

    Fomin, N.; Greene, G. L.; Allen, R. R.; Cianciolo, V.; Crawford, C.; Tito, T. M.; Huffman, P. R.; Iverson, E. B.; Mahurin, R.; Snow, W. M.

    2014-11-04

    In this paper, we describe the Fundamental Neutron Physics Beamline (FnPB) facility located at the Spallation Neutron Source at Oak Ridge National Laboratory. The FnPB was designed for the conduct of experiments that investigate scientific issues in nuclear physics, particle physics, astrophysics and cosmology using a pulsed slow neutron beam. Finally, we present a detailed description of the design philosophy, beamline components, and measured fluxes of the polychromatic and monochromatic beams.

  14. The spin-echo spectrometer at the Spallation Neutron Source (SNS)

    NASA Astrophysics Data System (ADS)

    Ohl, M.; Monkenbusch, M.; Arend, N.; Kozielewski, T.; Vehres, G.; Tiemann, C.; Butzek, M.; Soltner, H.; Giesen, U.; Achten, R.; Stelzer, H.; Lindenau, B.; Budwig, A.; Kleines, H.; Drochner, M.; Kaemmerling, P.; Wagener, M.; Möller, R.; Iverson, E. B.; Sharp, M.; Richter, D.

    2012-12-01

    A novel neutron spin-echo spectrometer with superconducting main coils enabling enclosure by a double walled μ-metal magnetic shielding chamber has been built and set into operation at the spallation neutron source in Oak Ridge. The layout of the spectrometer is described. Performance with emphasis on the superconducting main solenoids and the time-of-flight operation is described. Data on resolution, stability and first experiments are shown.

  15. Spallation backgrounds in Super-Kamiokande are made in muon-induced showers

    NASA Astrophysics Data System (ADS)

    Li, Shirley Weishi; Beacom, John F.

    2015-05-01

    Crucial questions about solar and supernova neutrinos remain unanswered. Super-Kamiokande has the exposure needed for progress, but detector backgrounds are a limiting factor. A leading component is the beta decays of isotopes produced by cosmic-ray muons and their secondaries, which initiate nuclear spallation reactions. Cuts of events after and surrounding muon tracks reduce this spallation decay background by ≃ 90 % (at a cost of ≃ 20 % deadtime), but its rate at 6-18 MeV is still dominant. A better way to cut this background was suggested in a Super-Kamiokande paper by Bays et al. [Phys. Rev. D 85, 052007 (2012)] on a search for the diffuse supernova neutrino background. They found that spallation decays above 16 MeV were preceded near the same location by a peak in the apparent Cherenkov light profile from the muon; a more aggressive cut was applied to a limited section of the muon track, leading to decreased background without increased deadtime. We put their empirical discovery on a firm theoretical foundation. We show that almost all spallation decay isotopes are produced by muon-induced showers and that these showers are rare enough and energetic enough to be identifiable. This is the first such demonstration for any detector. We detail how the physics of showers explains the peak in the muon Cherenkov light profile and other Super-K observations. Our results provide a physical basis for practical improvements in background rejection that will benefit multiple studies. For solar neutrinos, in particular, it should be possible to dramatically reduce backgrounds at energies as low as 6 MeV.

  16. Automatic beam position control at Los Alamos Spallation Radiation Effects Facility (LASREF)

    SciTech Connect

    Oothoudt, M.; Pillai, C.; Zumbro, M.

    1997-08-01

    Historically the Los Alamos Spallation Radiation Effects Facility (LASREF) has used manual methods to control the position of the 800 kW, 800 MeV proton beam on targets. New experiments, however, require more stringent position control more frequently than can be done manually for long periods of time. Data from an existing harp is used to automatically adjust steering magnets to maintain beam position to required tolerances.

  17. Coherent Scattering Investigations at the Spallation Neutron Source: a Snowmass White Paper

    SciTech Connect

    Akimov, D.; Bernstein, A.; BarbeauP.,; Barton, P. J.; Bolozdynya, A.; Cabrera-Palmer, B.; Cavanna, F.; Cianciolo, Vince; Collar, J.; Cooper, R. J.; Dean, D. J.; Efremenko, Yuri; Etenko, A.; Fields, N.; Foxe, M.; Figueroa-Feliciano, E.; Fomin, N.; Gallmeier, F.; Garishvili, I.; Gerling, M.; Green, M.; Greene, Geoffrey; Hatzikoutelis, A.; Henning, Reyco; Hix, R.; Hogan, D.; Hornback, D.; Jovanovic, I.; Hossbach, T.; Iverson, Erik B; Klein, S. R.; Khromov, A.; Link, J.; Louis, W.; Lu, W.; Mauger, C.; Marleau, P.; Markoff, D.; Martin, R. D.; Mueller, Paul Edward; Newby, J.; Orrell, John L.; O'Shaughnessy, C.; Penttila, Seppo; Patton, K.; Poon, A. W.; Radford, David C; Reyna, D.; Ray, H.; Scholberg, K.; Sosnovtsev, V.; Tayloe, R.; Vetter, K.; Virtue, C.; Wilkerson, J.; Yoo, J.; Yu, Chang-Hong

    2013-01-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory, Tennessee, provides an intense flux of neutrinos in the few tens-of-MeV range, with a sharply-pulsed timing structure that is beneficial for background rejection. In this white paper, we describe how the SNS source can be used for a measurement of coherent elastic neutrino-nucleus scattering (CENNS), and the physics reach of different phases of such an experimental program (CSI: Coherent Scattering Investigations at the SNS).

  18. Behavior of structural and target materials irradiated in spallation neutron environments

    SciTech Connect

    Stubbins, J.F.; Wechsler, M.; Borden, M.; Sommer, W.F.

    1995-05-01

    This paper describes considerations for selection of structural and target materials for accelerator-driven neutron sources. Due to the operating constraints of proposed accelerator-driven neutron sources, the criteria for selection are different than those commonly applied to fission and fusion systems. Established irradiation performance of various alloy systems is taken into account in the selection criteria. Nevertheless, only limited materials performance data are available which specifically related to neutron energy spectra anticipated for spallation sources.

  19. RESULTS OF BACKGROUND SUBTRACTION TECHNIQUES ON THE SPALLATION NEUTRON SOURCE BEAM LOSS MONITORS

    SciTech Connect

    Pogge, James R; Zhukov, Alexander P

    2010-01-01

    Recent improvements to the Spallation Neutron Source (SNS) beam loss monitor (BLM) designs have been made with the goal of significantly reducing background noise. This paper outlines this effort and analyzes the results. The significance of this noise reduction is the ability to use the BLM sensors [1], [2], [3] distributed throughout the SNS accelerator as a method to monitor activation of components as well as monitor beam losses.

  20. Benchmarking shielding simulations for an accelerator-driven spallation neutron source

    NASA Astrophysics Data System (ADS)

    Cherkashyna, Nataliia; DiJulio, Douglas D.; Panzner, Tobias; Rantsiou, Emmanouela; Filges, Uwe; Ehlers, Georg; Bentley, Phillip M.

    2015-08-01

    The shielding at an accelerator-driven spallation neutron facility plays a critical role in the performance of the neutron scattering instruments, the overall safety, and the total cost of the facility. Accurate simulation of shielding components is thus key for the design of upcoming facilities, such as the European Spallation Source (ESS), currently in construction in Lund, Sweden. In this paper, we present a comparative study between the measured and the simulated neutron background at the Swiss Spallation Neutron Source (SINQ), at the Paul Scherrer Institute (PSI), Villigen, Switzerland. The measurements were carried out at several positions along the SINQ monolith wall with the neutron dosimeter WENDI-2, which has a well-characterized response up to 5 GeV. The simulations were performed using the Monte-Carlo radiation transport code geant4, and include a complete transport from the proton beam to the measurement locations in a single calculation. An agreement between measurements and simulations is about a factor of 2 for the points where the measured radiation dose is above the background level, which is a satisfactory result for such simulations spanning many energy regimes, different physics processes and transport through several meters of shielding materials. The neutrons contributing to the radiation field emanating from the monolith were confirmed to originate from neutrons with energies above 1 MeV in the target region. The current work validates geant4 as being well suited for deep-shielding calculations at accelerator-based spallation sources. We also extrapolate what the simulated flux levels might imply for short (several tens of meters) instruments at ESS.