Science.gov

Sample records for ammonia recycle percolation

  1. PRETREATMENT AND FRACTIONATION OF CORN STOVER BY AMMONIA RECYCLE PERCOLATION PROCESS. (R831645)

    EPA Science Inventory

    Corn stover was pretreated with aqueous ammonia in a flow-through column reactor,
    a process termed as Ammonia Recycle Percolation (ARP). The aqueous ammonia causes
    swelling and efficient delignification of biomass at high temperatures. The ARP
    process solubilizes abou...

  2. Ammonia recycled percolation as a complementary pretreatment to the dilute-acid process

    SciTech Connect

    Wu, Zhangwen, Lee, Y.Y.

    1997-12-31

    A two-stage dilute-acid percolation (DA) was investigated as a pre-treatment method for switchgrass. With use of extremely low acid (0.078 wt% sulfuric acid) under moderate temperature (145-170{degrees}C), hemicellulose in switchgrass was completely solubilized showing no sugar decomposition. The treated switchgrass contained about 70% glucan and 30% lignin. The high lignin content in the treated feedstock raises a concern that it may cause a high enzyme consumption because of irreversible adsorption of cellulose enzymes to lignin. This problem may be amplified in the SSF operation since it is usually run in fed-batch mode and the residual lignin is accumulated. The DA pretreatment was, therefore, combined with the ammonia recycled percolation (ARP) process that has been proven to be effective in delignification. The combined pretreatment essentially fractionated the switchgrass into three major components. The treated feedstock contained about 90% glucan and 10% lignin. The digestibility of these samples was consistently higher than that of DA treated samples. Further study on the interaction of cellulase with xylan and that with lignin has shown that the enzymatic hydrolysis of cellulose is inhibited by lignin as well as xylan. The external xylan was found to be a noncompetitive inhibitor to cellulose hydrolysis. The cellulose used in this study was proven to have the xylanase activity. 23 refs., 8 figs., 4 tabs.

  3. Ammonia recycling enables sustainable operation of bioelectrochemical systems.

    PubMed

    Cheng, Ka Yu; Kaksonen, Anna H; Cord-Ruwisch, Ralf

    2013-09-01

    Ammonium (NH4(+)) migration across a cation exchange membrane is commonly observed during the operation of bioelectrochemical systems (BES). This often leads to anolyte acidification (pH <5.5) and complete inactivation of biofilm electroactivity. Without using conventional pH controls (dosage of alkali or pH buffers), the present study revealed that anodic biofilm activity (current) could be sustained if recycling of ammonia (NH3) was implemented. A simple gas-exchange apparatus was designed to enable continuous recycling of NH3 (released from the catholyte at pH >10) from the cathodic headspace to the acidified anolyte. Results indicated that current (110 mA or 688 Am(-3) net anodic chamber volume) was sustained as long as the NH3 recycling path was enabled, facilitating continuous anolyte neutralization with the recycled NH3. Since the microbial current enabled NH4(+) migration against a strong concentration gradient (~10-fold), a novel way of ammonia recovery from wastewaters could be envisaged. PMID:23774293

  4. Amination of aryl halides with aqueous ammonia catalyzed by green recyclable poly(4-vinylpyridine)-supported copper iodide nanoparticles catalyst.

    PubMed

    Albadi, Jalal; Shiran, Jafar Abbasi; Mansournezhad, Azam

    2014-01-01

    In this research efficient procedure for the amination of aryl halides with aqueous ammonia in the presence of poly(4-vinylpyridine)-supported copper iodide nanoparticles catalyst is reported. A wide range of aryl halides including aryl iodides and aryl bromides are converted into the corresponding aniline derivatives. The experimental procedure with poly(4-vinylpyridine)-supported copper iodide nanoparticles catalyst is quite straightforward and it is recycled up to 3 consecutive runs by simple filtration. PMID:25551733

  5. Pretreatment of Biomass by Aqueous Ammonia for Bioethanol Production

    NASA Astrophysics Data System (ADS)

    Kim, Tae Hyun; Gupta, Rajesh; Lee, Y. Y.

    The methods of pretreatment of lignocellulosic biomass using aqueous ammonia are described. The main effect of ammonia treatment of biomass is delignification without significantly affecting the carbohydrate contents. It is a very effective pretreatment method especially for substrates that have low lignin contents such as agricultural residues and herbaceous feedstock. The ammonia-based pretreatment is well suited for simultaneous saccharification and co-fermentation (SSCF) because the treated biomass retains cellulose as well as hemicellulose. It has been demonstrated that overall ethanol yield above 75% of the theoretical maximum on the basis of total carbohydrate is achievable from corn stover pretreated with aqueous ammonia by way of SSCF. There are two different types of pretreatment methods based on aqueous ammonia: (1) high severity, low contact time process (ammonia recycle percolation; ARP), (2) low severity, high treatment time process (soaking in aqueous ammonia; SAA). Both of these methods are described and discussed for their features and effectiveness.

  6. Ammonia

    Integrated Risk Information System (IRIS)

    Ammonia ; CASRN 7664 - 41 - 7 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogenic Effects

  7. Process modeling of an advanced NH₃ abatement and recycling technology in the ammonia-based CO₂ capture process.

    PubMed

    Li, Kangkang; Yu, Hai; Tade, Moses; Feron, Paul; Yu, Jingwen; Wang, Shujuan

    2014-06-17

    An advanced NH3 abatement and recycling process that makes great use of the waste heat in flue gas was proposed to solve the problems of ammonia slip, NH3 makeup, and flue gas cooling in the ammonia-based CO2 capture process. The rigorous rate-based model, RateFrac in Aspen Plus, was thermodynamically and kinetically validated by experimental data from open literature and CSIRO pilot trials at Munmorah Power Station, Australia, respectively. After a thorough sensitivity analysis and process improvement, the NH3 recycling efficiency reached as high as 99.87%, and the NH3 exhaust concentration was only 15.4 ppmv. Most importantly, the energy consumption of the NH3 abatement and recycling system was only 59.34 kJ/kg CO2 of electricity. The evaluation of mass balance and temperature steady shows that this NH3 recovery process was technically effective and feasible. This process therefore is a promising prospect toward industrial application. PMID:24850444

  8. Recycling.

    ERIC Educational Resources Information Center

    Sinker, Barbara

    1986-01-01

    Discusses the range of benefits resulting from recycling efforts and projects. Presents information and data related to the recycling of metals, cans, paper, fans, and plastics. Suggestions for motivating and involving youth in recycling programs are also offered. (ML)

  9. Recycling

    NASA Astrophysics Data System (ADS)

    Goto, Junya; Santorelli, Michael

    Recycling systems are classified into those employing typically three methods, and the progress of each method is described. In mechanical recycling, powders of phenolic materials are recovered via a mechanical process and reused as fillers or additives in virgin materials. The effects to flowability, curability, and mechanical properties of the materials are explained. In feedstock recycling, monomers, oligomers, or oils are recovered via chemical processes and reused as feedstock. Pyrolysis, solvolysis or hydrolysis, and supercritical or subcritical fluid technology will also be introduced. When using a subcritical fluid of phenol, the recycled material maintains excellent properties similar to the virgin material, and a demonstration plant has been constructed to carry out mass production development. In energy recovery, wastes of phenolic materials are used as an alternative solid fuel to coal because they are combustible and have good calorific value. Industrial wastes of these have been in practical use in a cement plant. Finally, it is suggested that the best recycling method should be selected according to the purpose or situation, because every recycling method has both strengths and weaknesses. Therefore, quantitative and objective evaluation methods in recycling are desirable and should be established.

  10. Simultaneous determination of indoor ammonia pollution and its biological metabolite in the human body with a recyclable nanocrystalline lanthanide-functionalized MOF

    NASA Astrophysics Data System (ADS)

    Hao, Ji-Na; Yan, Bing

    2016-01-01

    A Eu3+ post-functionalized metal-organic framework of nanosized Ga(OH)bpydc(Eu3+@Ga(OH)bpydc, 1a) with intense luminescence is synthesized and characterized. Luminescence measurements reveal that 1a can detect ammonia gas selectively and sensitively among various indoor air pollutants. 1a can simultaneously determine a biological ammonia metabolite (urinary urea) in the human body, which is a rare example of a luminescent sensor that can monitor pollutants in the environment and also detect their biological markers. Furthermore, 1a exhibits appealing features including high selectivity and sensitivity, fast response, simple and quick regeneration, and excellent recyclability.A Eu3+ post-functionalized metal-organic framework of nanosized Ga(OH)bpydc(Eu3+@Ga(OH)bpydc, 1a) with intense luminescence is synthesized and characterized. Luminescence measurements reveal that 1a can detect ammonia gas selectively and sensitively among various indoor air pollutants. 1a can simultaneously determine a biological ammonia metabolite (urinary urea) in the human body, which is a rare example of a luminescent sensor that can monitor pollutants in the environment and also detect their biological markers. Furthermore, 1a exhibits appealing features including high selectivity and sensitivity, fast response, simple and quick regeneration, and excellent recyclability. Electronic supplementary information (ESI) available: Experimental section; XPS spectra; N2 adsorption-desorption isotherms; ICP data; SEM image; PXRD patterns and other luminescence data. See DOI: 10.1039/c5nr06066d

  11. Advanced Life Support Water Recycling Technologies Case Studies: Vapor Phase Catalytic Ammonia Removal and Direct Osmotic Concentration

    NASA Technical Reports Server (NTRS)

    Flynn, Michael

    2004-01-01

    Design for microgravity has traditionally not been well integrated early on into the development of advanced life support (ALS) technologies. NASA currently has a many ALS technologies that are currently being developed to high technology readiness levels but have not been formally evaluated for microgravity compatibility. Two examples of such technologies are the Vapor Phase Catalytic Ammonia Removal Technology and the Direct Osmotic Concentration Technology. This presentation will cover the design of theses two systems and will identify potential microgravity issues.

  12. Elimination of phenols, ammonia and cyanide in wash water from biomass gasification, and nitrogen recycling using planted trickling filters.

    PubMed

    Graber, Andreas; Skvarc, Robert; Junge-Berberović, Ranka

    2009-01-01

    Trickling filters were used to treat wash water from a wood gasifier. This wash water contained toxic substances such as ammonium, cyanide, phenols, and PAH. The goal was to develop a system that degraded toxic substances, and achieved full nitrification of ammonia. A 1 kW model wood gasifier plant delivered wash water for the experiments, which was standardised to a conductivity of 3 mS/cm by dilution. Toxicity was assessed by bacterial luminescence detection, germination test with cress (Lepidium sativum), and pot plants cultivated in a hydroponic setup irrigated continuously with the wastewater. Treatment experiments were done in both planted and unplanted trickling filters. Plant yield was similar to conventional hydroponic production systems. The trickling filters achieved complete detoxification of phenol, PAH and cyanide as well as full nitrification. The specific elimination rates were 100 g m(-3) Leca d(-1) for phenols and 90 g m(-3) Leca d(-1) for ammonium in planted systems. In unplanted trickling filters circulated for 63 h, phenol concentration decreased from 83.5 mg/L to 2.5 mg/L and cyanide concentration from 0.32 mg/L to 0.02 mg/L. PAH concentrations were reduced from 3,050 microg/L to 0.89 microg/L within 68 days. The assays demonstrated the feasibility of using the technique to construct a treatment system in a partially closed circulation for gasifier wash water. The principal advantage is to convert toxic effluents from biomass gasifiers into a non-toxic, nitrogen-rich fertiliser water, enabling subsequent use in plant production and thus income generation. However, the questions of long-term performance and possible accumulation of phenols and heavy metals in the produce still have to be studied. PMID:19955650

  13. Substrate Dependency and Effect of Xylanase Supplementation on Enzymatic Hydrolysis of Ammonia-Treated Biomass

    NASA Astrophysics Data System (ADS)

    Gupta, Rajesh; Kim, Tae Hyun; Lee, Yoon Y.

    Pretreatment based on aqueous ammonia was investigated under two different modes of operation: soaking in aqueous ammonia and ammonia recycle percolation. These processes were applied to three different feedstocks with varied composition: corn stover, high lignin (HL), and low lignin (LL) hybrid poplars. One of the important features of ammonia-based pretreatment is that most of the hemicellulose is retained after treatment, which simplifies the overall bioconversion process and enhances the conversion efficiency. The pretreatment processes were optimized for these feedstocks, taking carbohydrate retention as well as sugar yield in consideration. The data indicate that hybrid poplar is more difficult to treat than corn stover, thus, requires more severe conditions. On the other hand, hybrid poplar has a beneficial property that it retains most of the hemicellulose after pretreatment. To enhance the digestibility of ammonia-treated poplars, xylanase was supplemented during enzymatic hydrolysis. Because of high retention of hemicellulose in treated hybrid poplar, xylanase supplementation significantly improved xylan as well as glucan digestibility. Of the three feedstocks, best results and highest improvement by xylanase addition was observed with LL hybrid poplar, showing 90% of overall sugar yield.

  14. Percolation on Sparse Networks

    NASA Astrophysics Data System (ADS)

    Karrer, Brian; Newman, M. E. J.; Zdeborová, Lenka

    2014-11-01

    We study percolation on networks, which is used as a model of the resilience of networked systems such as the Internet to attack or failure and as a simple model of the spread of disease over human contact networks. We reformulate percolation as a message passing process and demonstrate how the resulting equations can be used to calculate, among other things, the size of the percolating cluster and the average cluster size. The calculations are exact for sparse networks when the number of short loops in the network is small, but even on networks with many short loops we find them to be highly accurate when compared with direct numerical simulations. By considering the fixed points of the message passing process, we also show that the percolation threshold on a network with few loops is given by the inverse of the leading eigenvalue of the so-called nonbacktracking matrix.

  15. Social percolation models

    NASA Astrophysics Data System (ADS)

    Solomon, Sorin; Weisbuch, Gerard; de Arcangelis, Lucilla; Jan, Naeem; Stauffer, Dietrich

    2000-03-01

    We here relate the occurrence of extreme market shares, close to either 0 or 100%, in the media industry to a percolation phenomenon across the social network of customers. We further discuss the possibility of observing self-organized criticality when customers and cinema producers adjust their preferences and the quality of the produced films according to previous experience. Comprehensive computer simulations on square lattices do indeed exhibit self-organized criticality towards the usual percolation threshold and related scaling behaviour.

  16. Ammonia Process by Pressure Swing Adsorption

    SciTech Connect

    Dr Felix Jegede

    2010-12-27

    The overall objective of the project is to design, develop and demonstrate a technically feasible and commercially viable system to produce ammonia along with recovery of the products by adsorption separation methods and significantly decrease the energy requirement in ammonia production. This is achieved through a significantly more efficient ammonia psa recovery system. The new ammonia recovery system receives the reactor effluents and achieves complete ammonia recovery, (which completely eliminates the energy intensive refrigeration and condensation system currently used in ammonia production). It also recovers the unused reactants and recycles them back to the reactor, free of potential reactor contaminants, and without the need for re-compression and re-heat of recycle stream thereby further saving more energy. The result is a significantly lower energy consumption, along with capital cost savings.

  17. Price percolation model

    NASA Astrophysics Data System (ADS)

    Kanai, Yasuhiro; Abe, Keiji; Seki, Yoichi

    2015-06-01

    We propose a price percolation model to reproduce the price distribution of components used in industrial finished goods. The intent is to show, using the price percolation model and a component category as an example, that percolation behaviors, which exist in the matter system, the ecosystem, and human society, also exist in abstract, random phenomena satisfying the power law. First, we discretize the total potential demand for a component category, considering it a random field. Second, we assume that the discretized potential demand corresponding to a function of a finished good turns into actual demand if the difficulty of function realization is less than the maximum difficulty of the realization. The simulations using this model suggest that changes in a component category's price distribution are due to changes in the total potential demand corresponding to the lattice size and the maximum difficulty of realization, which is an occupation probability. The results are verified using electronic components' sales data.

  18. Percolation and Deconfinement

    NASA Astrophysics Data System (ADS)

    Srivastava, Brijesh K.

    2011-07-01

    Possible phase transition of strongly interacting matter from hadron to a Quark-Gluon Plasma (QGP) state have in the past received considerable interest. It has been suggested that this problem might be treated by percolation theory. The Color String Percolation Model (CSPM) is used to determine the equation of state (EOS) of the QGP produced in central Au-Au collisions at RHIC energies. The bulk thermodynamic quantities - energy density, entropy density and the sound velocity - are obtained in the framework of CSPM. It is shown that the results are in excellent agreement with the recent lattice QCD calculations(LQCD).

  19. Ammonia scrubbing

    SciTech Connect

    Epperly, W.R.; Peter-Hoblyn, J.D.; Sullivan, J.C

    1989-05-16

    A process is described for reducing the concentration of ammonia in the effluent from the combustion of a carbonaceous fuel, the process comprising introducing a non-nitrogeneous treatment agent which comprises a paraffinic, olefinic, aromatic oxygenated hydrocarbon into the effluent at a ratio of non-nitrogenous treatment agent to effluent ammonia of about 2:1 to about 200:1 to combine with ammonia present in the effluent, wherein the effluent temperature is about 1350/sup 0/F to about 2000/sup 0/F, and further wherein the non-nitrogenous treatment agent is introduced under conditions effective to perform ammonia scrubbing.

  20. Ammonia Monitor

    NASA Technical Reports Server (NTRS)

    Sauer, Richard L. (Inventor); Akse, James R. (Inventor); Thompson, John O. (Inventor); Atwater, James E. (Inventor)

    1999-01-01

    Ammonia monitor and method of use are disclosed. A continuous, real-time determination of the concentration of ammonia in an aqueous process stream is possible over a wide dynamic range of concentrations. No reagents are required because pH is controlled by an in-line solid-phase base. Ammonia is selectively transported across a membrane from the process stream to an analytical stream to an analytical stream under pH control. The specific electrical conductance of the analytical stream is measured and used to determine the concentration of ammonia.

  1. Unstable supercritical discontinuous percolation transitions

    NASA Astrophysics Data System (ADS)

    Chen, Wei; Cheng, Xueqi; Zheng, Zhiming; Chung, Ning Ning; D'Souza, Raissa M.; Nagler, Jan

    2013-10-01

    The location and nature of the percolation transition in random networks is a subject of intense interest. Recently, a series of graph evolution processes have been introduced that lead to discontinuous percolation transitions where the addition of a single edge causes the size of the largest component to exhibit a significant macroscopic jump in the thermodynamic limit. These processes can have additional exotic behaviors, such as displaying a “Devil's staircase” of discrete jumps in the supercritical regime. Here we investigate whether the location of the largest jump coincides with the percolation threshold for a range of processes, such as Erdős-Rényipercolation, percolation via edge competition and via growth by overtaking. We find that the largest jump asymptotically occurs at the percolation transition for Erdős-Rényiand other processes exhibiting global continuity, including models exhibiting an “explosive” transition. However, for percolation processes exhibiting genuine discontinuities, the behavior is substantially richer. In percolation models where the order parameter exhibits a staircase, the largest discontinuity generically does not coincide with the percolation transition. For the generalized Bohman-Frieze-Wormald model, it depends on the model parameter. Distinct parameter regimes well in the supercritical regime feature unstable discontinuous transitions—a novel and unexpected phenomenon in percolation. We thus demonstrate that seemingly and genuinely discontinuous percolation transitions can involve a rich behavior in supercriticality, a regime that has been largely ignored in percolation.

  2. Electrical Percolation Based Biosensors

    PubMed Central

    Bruck, Hugh Alan; Yang, Minghui; Kostov, Yordan; Rasooly, Avraham

    2013-01-01

    A new approach to label free biosensing has been developed based on the principle of “electrical percolation”. In electrical percolation, long-range electrical connectivity is formed in randomly oriented and distributed systems of discrete elements. By applying this principle to biological interactions, it is possible to measure biological components both directly and electronically. The main element for electrical percolation biosensor is the biological semiconductor (BSC) which is a multi-layer 3-D carbon nanotube-antibody network. In the BSC, molecular interactions, such as binding of antigens to the antibodies, disrupt the network continuity causing increased resistance of the network. BSCs can be fabricated by immobilizing conducting elements, such as pre-functionalized single-walled carbon nanotubes (SWNTs)-antibody complex, directly onto a substrate, such as a Poly(methyl methacrylate) (PMMA) surface (also known as plexi-glass or Acrylic). BSCs have been demonstrated for direct (label-free) electronic measurements of antibody-antigen binding using SWNTs. If the concentration of the SWNT network is slightly above the electrical percolation threshold, then binding of a specific antigen to the pre-functionalized SWNT dramatically increases the electrical resistance due to changes in the tunneling between the SWNTs. Using anti-Staphylococcal enterotoxin B (SEB) IgG as a “gate” and SEB as an “actuator”, it was demonstrated that the BSC was able to detect SEB at concentrations of 1 ng/ml. Based on this concept, an automated configuration for BSCs is described here that enables real time continuous detection. The new BSC configuration may permit assembly of multiple sensors on the same chip to create “Biological Central Processing Units (CPUs)” with multiple biological elements, capable of processing and sorting out information on multiple analytes simultaneously. PMID:24041756

  3. Recycling, Inc.

    ERIC Educational Resources Information Center

    Martin, Amy

    1992-01-01

    Suggestions for creating a successful office recycling system are enumerated from start up plans to waste reduction and paper recycling. Contact information for recycling equipment, potential buyers of recycled materials, recycled products for purchase, and ideas for promotion and education of staff are included. (MCO)

  4. Percolation testing and hydraulic conductivity of soils for percolation areas.

    PubMed

    Mulqueen, J; Rodgers, M

    2001-11-01

    The results of specific percolation tests are expressed in terms of field saturated hydraulic conductivity (Kfs) of the soil. The specific tests comprise the Irish SR 6 and the UK BS 6297 standard tests and the inversed auger hole and square hole tests employed for the design of land drainage. Percolation times from these tests are converted to Kfs values using unit gradient theory and the Elrick and Reynolds (Soil Sci. 142(5) (1986) 308) model which takes into account gravitational, pressure head and matric potential gradients. Kfs is then expressed as the inverse of the percolation rate times a constant, in this way the percolation rate can be directly related to Kfs of the soil. A plot of Kfs against percolation rate for the Irish SR 6 and the UK BS 6297 standard tests is asymptotic at Kfs values less than 0.2 m/d and greater than 0.8 m/d. This behaviour creates difficulty in setting limits for percolation rates in standards. Curves are provided which enable Kfs values to be read off from percolation tests without the restrictions of head range currently enforced, for example in the Irish SR 6 and BS 6297 standards. Experimental measurements of percolation rates and Kfs were carried out on two sands in the laboratory and in the field on two soils. Kfs of these four materials was also measured using a tension infiltrometer and the Guelph permeameter. The saturated hydraulic conductivities (Ks) of the sands were also estimated in a falling head laboratory apparatus and by the Hazen formula. There was good agreement between the different tests for Kfs on each material. Because percolation time continued to increase significantly in consecutive tests in the same test hole while Kfs became constant, the latter is a better measure of the suitability of soils for percolation. PMID:12230173

  5. Recycling endosomes

    PubMed Central

    Goldenring, James R

    2015-01-01

    The endosomal membrane recycling system represents a dynamic conduit for sorting and re-exporting internalized membrane constituents. The recycling system is composed of multiple tubulovesicular recycling pathways that likely confer distinct trafficking pathways for individual cargoes. In addition, elements of the recycling system are responsible for assembly and maintenance of apical membrane specializations including primary cilia and apical microvilli. The existence of multiple intersecting and diverging recycling tracks likely accounts for specificity in plasma membrane recycling trafficking. PMID:26022676

  6. Self Healing Percolation

    NASA Astrophysics Data System (ADS)

    Scala, Antonio

    2015-03-01

    We introduce the concept of self-healing in the field of complex networks modelling; in particular, self-healing capabilities are implemented through distributed communication protocols that exploit redundant links to recover the connectivity of the system. Self-healing is a crucial in implementing the next generation of smart grids allowing to ensure a high quality of service to the users. We then map our self-healing procedure in a percolation problem and analyse the interplay between redundancies and topology in improving the resilience of networked infrastructures to multiple failures. We find exact results both for planar lattices and for random lattices, hinting the role of duality in the design of resilient networks. Finally, we introduce a cavity method approach to study the recovery of connectivity after damage in self-healing networks. CNR-PNR National Project ``Crisis-Lab,'' EU HOME/2013/CIPS/AG/4000005013 project CI2C and EU FET project MULTIPLEX nr.317532.

  7. Weak percolation on multiplex networks.

    PubMed

    Baxter, Gareth J; Dorogovtsev, Sergey N; Mendes, José F F; Cellai, Davide

    2014-04-01

    Bootstrap percolation is a simple but nontrivial model. It has applications in many areas of science and has been explored on random networks for several decades. In single-layer (simplex) networks, it has been recently observed that bootstrap percolation, which is defined as an incremental process, can be seen as the opposite of pruning percolation, where nodes are removed according to a connectivity rule. Here we propose models of both bootstrap and pruning percolation for multiplex networks. We collectively refer to these two models with the concept of "weak" percolation, to distinguish them from the somewhat classical concept of ordinary ("strong") percolation. While the two models coincide in simplex networks, we show that they decouple when considering multiplexes, giving rise to a wealth of critical phenomena. Our bootstrap model constitutes the simplest example of a contagion process on a multiplex network and has potential applications in critical infrastructure recovery and information security. Moreover, we show that our pruning percolation model may provide a way to diagnose missing layers in a multiplex network. Finally, our analytical approach allows us to calculate critical behavior and characterize critical clusters. PMID:24827287

  8. Weak percolation on multiplex networks

    NASA Astrophysics Data System (ADS)

    Baxter, Gareth J.; Dorogovtsev, Sergey N.; Mendes, José F. F.; Cellai, Davide

    2014-04-01

    Bootstrap percolation is a simple but nontrivial model. It has applications in many areas of science and has been explored on random networks for several decades. In single-layer (simplex) networks, it has been recently observed that bootstrap percolation, which is defined as an incremental process, can be seen as the opposite of pruning percolation, where nodes are removed according to a connectivity rule. Here we propose models of both bootstrap and pruning percolation for multiplex networks. We collectively refer to these two models with the concept of "weak" percolation, to distinguish them from the somewhat classical concept of ordinary ("strong") percolation. While the two models coincide in simplex networks, we show that they decouple when considering multiplexes, giving rise to a wealth of critical phenomena. Our bootstrap model constitutes the simplest example of a contagion process on a multiplex network and has potential applications in critical infrastructure recovery and information security. Moreover, we show that our pruning percolation model may provide a way to diagnose missing layers in a multiplex network. Finally, our analytical approach allows us to calculate critical behavior and characterize critical clusters.

  9. Percolation of spatially constraint networks

    NASA Astrophysics Data System (ADS)

    Li, Daqing; Li, Guanliang; Kosmidis, Kosmas; Stanley, H. E.; Bunde, Armin; Havlin, Shlomo

    2011-03-01

    We study how spatial constraints are reflected in the percolation properties of networks embedded in one-dimensional chains and two-dimensional lattices. We assume long-range connections between sites on the lattice where two sites at distance r are chosen to be linked with probability p(r)~r-δ. Similar distributions have been found in spatially embedded real networks such as social and airline networks. We find that for networks embedded in two dimensions, with 2<δ<4, the percolation properties show new intermediate behavior different from mean field, with critical exponents that depend on δ. For δ<2, the percolation transition belongs to the universality class of percolation in Erdös-Rényi networks (mean field), while for δ>4 it belongs to the universality class of percolation in regular lattices. For networks embedded in one dimension, we find that, for δ<1, the percolation transition is mean field. For 1<δ<2, the critical exponents depend on δ, while for δ>2 there is no percolation transition as in regular linear chains.

  10. Development of Vapor-Phase Catalytic Ammonia Removal System

    NASA Technical Reports Server (NTRS)

    Flynn, Michael; Fisher, John; Kiss, Mark; Borchers, Bruce; Tleimat, Badawi; Tleimat, Maher; Quinn, Gregory; Fort, James; Nalette, Tim; Baker, Gale; Genovese, Joseph

    2007-01-01

    A report describes recent accomplishments of a continuing effort to develop the vapor-phase catalytic ammonia removal (VPCAR) process for recycling wastewater for consumption by humans aboard a spacecraft in transit to Mars.

  11. Explosive percolation in thresholded networks

    NASA Astrophysics Data System (ADS)

    Hayasaka, Satoru

    2016-06-01

    Explosive percolation in a network is a phase transition where a large portion of nodes becomes connected with an addition of a small number of edges. Although extensively studied in random network models and reconstructed real networks, explosive percolation has not been observed in a more realistic scenario where a network is generated by thresholding a similarity matrix describing between-node associations. In this report, I examine construction schemes of such thresholded networks, and demonstrate that explosive percolation can be observed by introducing edges in a particular order.

  12. Core percolation on complex networks.

    PubMed

    Liu, Yang-Yu; Csóka, Endre; Zhou, Haijun; Pósfai, Márton

    2012-11-16

    We analytically solve the core percolation problem for complex networks with arbitrary degree distributions. We find that purely scale-free networks have no core for any degree exponents. We show that for undirected networks if core percolation occurs then it is continuous while for directed networks it is discontinuous (and hybrid) if the in- and out-degree distributions differ. We also find that core percolations on undirected and directed networks have completely different critical exponents associated with their critical singularities. PMID:23215509

  13. Ammonia Test

    MedlinePlus

    ... be ordered, along with other tests such as glucose , electrolytes , and kidney and liver function tests , to help diagnose the cause of ... Pages tab.) An increased ammonia level and decreased glucose ... may indicate that severe liver or kidney damage has impacted the body's ability ...

  14. Conductivity of continuum percolating systems

    NASA Astrophysics Data System (ADS)

    Stenull, Olaf; Janssen, Hans-Karl

    2001-11-01

    We study the conductivity of a class of disordered continuum systems represented by the Swiss-cheese model, where the conducting medium is the space between randomly placed spherical holes, near the percolation threshold. This model can be mapped onto a bond percolation model where the conductance σ of randomly occupied bonds is drawn from a probability distribution of the form σ-a. Employing the methods of renormalized field theory we show to arbitrary order in ɛ expansion that the critical conductivity exponent of the Swiss-cheese model is given by tSC(a)=(d-2)ν+max[φ,(1-a)-1], where d is the spatial dimension and ν and φ denote the critical exponents for the percolation correlation length and resistance, respectively. Our result confirms a conjecture that is based on the ``nodes, links, and blobs'' picture of percolation clusters.

  15. Signature of Thermal Rigidity Percolation

    NASA Astrophysics Data System (ADS)

    Huerta, Adrián

    2013-12-01

    To explore the role that temperature and percolation of rigidity play in determining the macroscopic properties, we propose a model that adds translational degrees of freedom to the spins of the well known Ising hamiltonian. In particular, the Ising model illustrate the longstanding idea that the growth of correlations on approach to a critical point could be describable in terms of the percolation of some sort of "physical cluster". For certain parameters of this model we observe two well defined peaks of CV, that suggest the existence of two kinds of "physical percolation", namely connectivity and rigidity percolation. Thermal fluctuations give rise to two different kinds of elementary excitations, i.e. droplets and configuron, as suggested by Angell in the framework of a bond lattice model approach. The later is reflected in the fluctuations of redundant constraints that gives stability to the structure and correlate with the order parameter.

  16. Deep Percolation in Devegetated Hillslopes

    NASA Astrophysics Data System (ADS)

    Ebel, B. A.; Hinckley, E. S.

    2011-12-01

    Deep percolation has recently been recognized as a critical component in hillslope hydrology studies. In devegetated hillslopes where vegetation is killed and, in some cases, removed, deep percolation may be substantially enhanced beyond pre-disturbance magnitudes. We discuss two examples of devegetated hillslopes where water balance partitioning shifted to favor increased deep percolation fluxes for some hydrologic conditions. The first is the Coos Bay Experimental Catchment in Oregon, USA, where commercial forestry resulted in the complete removal of trees. An intensive field campaign in the 1990's resulted in a long term record of precipitation, discharge, piezometric response, and groundwater levels. Hydrologic response modeling confirms hypotheses from the field-data analysis and points to unresolved questions regarding feedbacks between deep percolation and near-surface hydrologic processes. The second example is the area burned by the Fourmile Canyon Fire in Colorado, USA, where a severe wildland fire removed all vegetation from a north-aspect hillslope in 2010. Precipitation, atmospheric conditions, soil-water content, matric potential, and runoff have been measured since the fire devegetated the site. Subsurface sampling of the vadose zone is accomplished using suction lysimeters to capture total nitrate, ammonium, and dissolved organic carbon concentrations. Darcian flux calculations of net infiltration from the shallow soil into fractured granodiorite bedrock are used to estimate solute fluxes to a deeper groundwater system. Virtual experiments using numerical models of unsaturated fluid flow and solute transport further elucidate the temporal dynamics of deep percolation and associated solute fluxes during spring snowmelt and frontal rainstorms, which are the major hydrologic drivers of deep percolation in this fire-impacted system. Together, these examples serve to illustrate the critical importance of deep percolation in disturbed landscapes. The

  17. Conversion of ammonia into hydrogen and nitrogen by reaction with a sulfided catalyst

    DOEpatents

    Matthews, Charles W.

    1977-01-01

    A method is provided for removing ammonia from the sour water stream of a coal gasification process. The basic steps comprise stripping the ammonia from the sour water; heating the stripped ammonia to a temperature from between 400.degree. to 1,000.degree. F; passing the gaseous ammonia through a reactor containing a sulfided catalyst to produce elemental hydrogen and nitrogen; and scrubbing the reaction product to obtain an ammonia-free gas. The residual equilibrium ammonia produced by the reactor is recycled into the stripper. The ammonia-free gas may be advantageously treated in a Claus process to recover elemental sulfur. Iron sulfide or cobalt molybdenum sulfide catalysts are used.

  18. Hanford recycling

    SciTech Connect

    Leonard, I.M.

    1996-09-01

    This paper is a study of the past and present recycling efforts on the Hanford site and options for future improvements in the recycling program. Until 1996, recycling goals were voluntarily set by the waste generators: this year, DOE has imposed goals for all its sites to accomplish by 1999. Hanford is presently meeting the voluntary site goals, but may not be able to meet all the new DOE goals without changes to the program. Most of these new DOE goals are recycling goals: * Reduce the generation of radioactive (low-level) waste from routine operations 50 percent through source reduction and recycling. * Reduce the generation of low-level mixed waste from routine operations 50 percent through source reduction and recycling. * Reduce the generation of hazardous waste from routine operations 50 percent through source reduction and recycling. * Recycle 33 percent of the sanitary waste from all operations. * Increase affirmative procurement of EPA-designated recycled items to 100 percent. The Hanford recycling program has made great strides-there has been a 98 percent increase in the amount of paper recycled since its inception in 1990. Hanford recycles paper, chemicals cardboard, tires, oil, batteries, rags, lead weights, fluorescent tubes, aerosol products, concrete, office furniture, computer software, drums, toner cartridges, and scrap metal. Many other items are recycled or reused by individual groups on a one time basis without a formal contract. Several contracts are closed-loop contracts which involve all parts of the recycle loop. Considerable savings are generated from recycling, and much more is possible with increased attention and improvements to this program. General methods for improving the recycling program to ensure that the new goals can be met are: a Contract and financial changes 0 Tracking database and methods improvements 0 Expanded recycling efforts. Specifically, the Hanford recycling program would be improved by: 0 Establishing one overall

  19. Clique percolation in random graphs.

    PubMed

    Li, Ming; Deng, Youjin; Wang, Bing-Hong

    2015-10-01

    As a generation of the classical percolation, clique percolation focuses on the connection of cliques in a graph, where the connection of two k cliques means that they share at least lpercolation in Erdős-Rényi graphs, which gives not only the exact solutions of the critical point, but also the corresponding order parameter. Based on this, we prove theoretically that the fraction ψ of cliques in the giant clique cluster always makes a continuous phase transition as the classical percolation. However, the fraction ϕ of vertices in the giant clique cluster for l>1 makes a step-function-like discontinuous phase transition in the thermodynamic limit and a continuous phase transition for l=1. More interesting, our analysis shows that at the critical point, the order parameter ϕ(c) for l>1 is neither 0 nor 1, but a constant depending on k and l. All these theoretical findings are in agreement with the simulation results, which give theoretical support and clarification for previous simulation studies of clique percolation. PMID:26565177

  20. Percolation transitions in two dimensions.

    PubMed

    Feng, Xiaomei; Deng, Youjin; Blöte, Henk W J

    2008-09-01

    We investigate bond- and site-percolation models on several two-dimensional lattices numerically, by means of transfer-matrix calculations and Monte Carlo simulations. The lattices include the square, triangular, honeycomb kagome, and diced lattices with nearest-neighbor bonds, and the square lattice with nearest- and next-nearest-neighbor bonds. Results are presented for the bond-percolation thresholds of the kagome and diced lattices, and the site-percolation thresholds of the square, honeycomb, and diced lattices. We also include the bond- and site-percolation thresholds for the square lattice with nearest- and next-nearest-neighbor bonds. We find that corrections to scaling behave according to the second temperature dimension X_{t2}=4 predicted by the Coulomb gas theory and the theory of conformal invariance. In several cases there is evidence for an additional term with the same exponent, but modified by a logarithmic factor. Only for the site-percolation problem on the triangular lattice does such a logarithmic term appear to be small or absent. The amplitude of the power-law correction associated with X_{t2}=4 is found to be dependent on the orientation of the lattice with respect to the cylindrical geometry of the finite systems. PMID:18851022

  1. Percolation transitions in two dimensions

    NASA Astrophysics Data System (ADS)

    Feng, Xiaomei; Deng, Youjin; Blöte, Henk W. J.

    2008-09-01

    We investigate bond- and site-percolation models on several two-dimensional lattices numerically, by means of transfer-matrix calculations and Monte Carlo simulations. The lattices include the square, triangular, honeycomb kagome, and diced lattices with nearest-neighbor bonds, and the square lattice with nearest- and next-nearest-neighbor bonds. Results are presented for the bond-percolation thresholds of the kagome and diced lattices, and the site-percolation thresholds of the square, honeycomb, and diced lattices. We also include the bond- and site-percolation thresholds for the square lattice with nearest- and next-nearest-neighbor bonds. We find that corrections to scaling behave according to the second temperature dimension Xt2=4 predicted by the Coulomb gas theory and the theory of conformal invariance. In several cases there is evidence for an additional term with the same exponent, but modified by a logarithmic factor. Only for the site-percolation problem on the triangular lattice does such a logarithmic term appear to be small or absent. The amplitude of the power-law correction associated with Xt2=4 is found to be dependent on the orientation of the lattice with respect to the cylindrical geometry of the finite systems.

  2. Clique percolation in random graphs

    NASA Astrophysics Data System (ADS)

    Li, Ming; Deng, Youjin; Wang, Bing-Hong

    2015-10-01

    As a generation of the classical percolation, clique percolation focuses on the connection of cliques in a graph, where the connection of two k cliques means that they share at least l percolation in Erdős-Rényi graphs, which gives not only the exact solutions of the critical point, but also the corresponding order parameter. Based on this, we prove theoretically that the fraction ψ of cliques in the giant clique cluster always makes a continuous phase transition as the classical percolation. However, the fraction ϕ of vertices in the giant clique cluster for l >1 makes a step-function-like discontinuous phase transition in the thermodynamic limit and a continuous phase transition for l =1 . More interesting, our analysis shows that at the critical point, the order parameter ϕc for l >1 is neither 0 nor 1, but a constant depending on k and l . All these theoretical findings are in agreement with the simulation results, which give theoretical support and clarification for previous simulation studies of clique percolation.

  3. Recycled roads

    SciTech Connect

    Tarricone, P.

    1993-04-01

    This article examines the efforts of various states in the USA to recycle waste materials in highway construction as fill and pavements. The topics of the article include recycling used tires whole, ground, and shredded, cost of recycling, wood fiber chips as fill material in embankments, and mining wastes used to construct embankments and as coarse aggregates in asphalt pavement.

  4. Clique percolation in random networks.

    PubMed

    Derényi, Imre; Palla, Gergely; Vicsek, Tamás

    2005-04-29

    The notion of k-clique percolation in random graphs is introduced, where k is the size of the complete subgraphs whose large scale organizations are analytically and numerically investigated. For the Erdos-Rényi graph of N vertices we obtain that the percolation transition of k-cliques takes place when the probability of two vertices being connected by an edge reaches the threshold p(c) (k) = [(k - 1)N](-1/(k - 1)). At the transition point the scaling of the giant component with N is highly nontrivial and depends on k. We discuss why clique percolation is a novel and efficient approach to the identification of overlapping communities in large real networks. PMID:15904198

  5. Clique Percolation in Random Networks

    NASA Astrophysics Data System (ADS)

    Derényi, Imre; Palla, Gergely; Vicsek, Tamás

    2005-04-01

    The notion of k-clique percolation in random graphs is introduced, where k is the size of the complete subgraphs whose large scale organizations are analytically and numerically investigated. For the Erdős-Rényi graph of N vertices we obtain that the percolation transition of k-cliques takes place when the probability of two vertices being connected by an edge reaches the threshold pc(k)=[(k-1)N]-1/(k-1). At the transition point the scaling of the giant component with N is highly nontrivial and depends on k. We discuss why clique percolation is a novel and efficient approach to the identification of overlapping communities in large real networks.

  6. Percolation of interaction diffusing particles

    NASA Technical Reports Server (NTRS)

    Selinger, Robin Blumberg; Stanley, H. Eugene

    1990-01-01

    The connectivity properties of systems of diffusing interacting particles with the blind and myopic diffusion rules are studied. It is found that the blind rule case is equivalent to the lattice gas with J = 0 in all dimensions. The connectivity properties of blind rule diffusion are described by random site percolation due to the fact that the density on neighboring sites is uncorrelated.

  7. Proximal tubule-specific glutamine synthetase deletion alters basal and acidosis-stimulated ammonia metabolism.

    PubMed

    Lee, Hyun-Wook; Osis, Gunars; Handlogten, Mary E; Lamers, Wouter H; Chaudhry, Farrukh A; Verlander, Jill W; Weiner, I David

    2016-06-01

    Glutamine synthetase (GS) catalyzes the recycling of NH4 (+) with glutamate to form glutamine. GS is highly expressed in the renal proximal tubule (PT), suggesting ammonia recycling via GS could decrease net ammoniagenesis and thereby limit ammonia available for net acid excretion. The purpose of the present study was to determine the role of PT GS in ammonia metabolism under basal conditions and during metabolic acidosis. We generated mice with PT-specific GS deletion (PT-GS-KO) using Cre-loxP techniques. Under basal conditions, PT-GS-KO increased urinary ammonia excretion significantly. Increased ammonia excretion occurred despite decreased expression of key proteins involved in renal ammonia generation. After the induction of metabolic acidosis, the ability to increase ammonia excretion was impaired significantly by PT-GS-KO. The blunted increase in ammonia excretion occurred despite greater expression of multiple components of ammonia generation, including SN1 (Slc38a3), phosphate-dependent glutaminase, phosphoenolpyruvate carboxykinase, and Na(+)-coupled electrogenic bicarbonate cotransporter. We conclude that 1) GS-mediated ammonia recycling in the PT contributes to both basal and acidosis-stimulated ammonia metabolism and 2) adaptive changes in other proteins involved in ammonia metabolism occur in response to PT-GS-KO and cause an underestimation of the role of PT GS expression. PMID:27009341

  8. Percolation on correlated random networks

    NASA Astrophysics Data System (ADS)

    Agliari, E.; Cioli, C.; Guadagnini, E.

    2011-09-01

    We consider a class of random, weighted networks, obtained through a redefinition of patterns in an Hopfield-like model, and, by performing percolation processes, we get information about topology and resilience properties of the networks themselves. Given the weighted nature of the graphs, different kinds of bond percolation can be studied: stochastic (deleting links randomly) and deterministic (deleting links based on rank weights), each mimicking a different physical process. The evolution of the network is accordingly different, as evidenced by the behavior of the largest component size and of the distribution of cluster sizes. In particular, we can derive that weak ties are crucial in order to maintain the graph connected and that, when they are the most prone to failure, the giant component typically shrinks without abruptly breaking apart; these results have been recently evidenced in several kinds of social networks.

  9. String percolation and the Glasma

    NASA Astrophysics Data System (ADS)

    de Deus, J. Dias; Pajares, C.

    2011-01-01

    We compare string percolation phenomenology to Glasma results on particle rapidity densities, effective string or flux tube intrinsic correlations, the ridge phenomena and long range forward-backward correlations. Effective strings may be a tool to extend the Glasma to the low density QCD regime. A good example is given by the minimum of the negative binomial distribution parameter k expected to occur at low energy/centrality.

  10. Roots at the percolation threshold

    NASA Astrophysics Data System (ADS)

    Kroener, Eva; Ahmed, Mutez Ali; Carminati, Andrea

    2015-04-01

    The rhizosphere is the layer of soil around the roots where complex and dynamic interactions between plants and soil affect the capacity of plants to take up water. The physical properties of the rhizosphere are affected by mucilage, a gel exuded by roots. Mucilage can absorb large volumes of water, but it becomes hydrophobic after drying. We use a percolation model to describe the rewetting of dry rhizosphere. We find that at a critical mucilage concentration the rhizosphere becomes impermeable. The critical mucilage concentration depends on the radius of the soil particle size. Capillary rise experiments with neutron radiography prove that for concentrations below the critical mucilage concentration water could easily cross the rhizosphere, while above the critical concentration water could no longer percolate through it. Our studies, together with former observations of water dynamics in the rhizosphere, suggest that the rhizosphere is near the percolation threshold, where small variations in mucilage concentration sensitively alter the soil hydraulic conductivity. Is mucilage exudation a plant mechanism to efficiently control the rhizosphere conductivity and the access to water?

  11. Electrical percolation of fibre mixtures

    NASA Astrophysics Data System (ADS)

    Xie, Juan; Gordon, Stuart; Long, Hairu; Miao, Menghe

    2015-11-01

    In the development of conductive threads for wearable electronics, nonconductive cotton fibres and conductive stainless steel fibres are mixed to produce composite yarns at a wide range of stainless steel fibre weight fractions. The electrical resistance of the composite yarns is measured at different probe span lengths, ranging from 0.5 to 10 L ss ( L ss = 50 mm is the average length of stainless steel fibres). The percolation threshold and critical exponent are determined for each span length. The critical exponent followed a decreasing trend from 1.87 to 1.17 as the span length was increased. When the conductive fibre loading was expressed in terms of conductive fibre volume fraction, the percolation critical exponent showed a similar trend of change with probe span length. Such a dependence of percolation critical exponent on resistance probe span length has not been previously reported for conductive particle-filled polymer composites, probably because the probe span length used in resistance measurement is orders of magnitude larger than the dimension of the conductive fillers in the composites.

  12. Percolation in dense storage arrays

    NASA Astrophysics Data System (ADS)

    Kirkpatrick, Scott; Wilcke, Winfried W.; Garner, Robert B.; Huels, Harald

    2002-11-01

    As computers and their accessories become smaller, cheaper, and faster the providers of news, retail sales, and other services we now take for granted on the Internet have met their increasing computing needs by putting more and more computers, hard disks, power supplies, and the data communications linking them to each other and to the rest of the wired world into ever smaller spaces. This has created a new and quite interesting percolation problem. It is no longer desirable to fix computers, storage or switchgear which fail in such a dense array. Attempts to repair things are all too likely to make problems worse. The alternative approach, letting units “fail in place”, be removed from service and routed around, means that a data communications environment will evolve with an underlying regular structure but a very high density of missing pieces. Some of the properties of this kind of network can be described within the existing paradigm of site or bond percolation on lattices, but other important questions have not been explored. I will discuss 3D arrays of hundreds to thousands of storage servers (something which it is quite feasible to build in the next few years), and show that bandwidth, but not percolation fraction or shortest path lengths, is the critical factor affected by the “fail in place” disorder. Redundancy strategies traditionally employed in storage systems may have to be revised. Novel approaches to routing information among the servers have been developed to minimize the impact.

  13. Percolation in real interdependent networks

    NASA Astrophysics Data System (ADS)

    Radicchi, Filippo

    2015-07-01

    The function of a real network depends not only on the reliability of its own components, but is affected also by the simultaneous operation of other real networks coupled with it. Whereas theoretical methods of direct applicability to real isolated networks exist, the frameworks developed so far in percolation theory for interdependent network layers are of little help in practical contexts, as they are suited only for special models in the limit of infinite size. Here, we introduce a set of heuristic equations that takes as inputs the adjacency matrices of the layers to draw the entire phase diagram for the interconnected network. We demonstrate that percolation transitions in interdependent networks can be understood by decomposing these systems into uncoupled graphs: the intersection among the layers, and the remainders of the layers. When the intersection dominates the remainders, an interconnected network undergoes a smooth percolation transition. Conversely, if the intersection is dominated by the contribution of the remainders, the transition becomes abrupt even in small networks. We provide examples of real systems that have developed interdependent networks sharing cores of `high quality’ edges to prevent catastrophic failures.

  14. Percolative fragmentation and spontaneous agglomeration

    SciTech Connect

    Hurt, R.; Davis, K.

    1999-03-01

    Captive particle imaging experiments were performed on over 200 coal and char particles in the pulverized size range from four coals of various rank at oxygen concentration from 3--19 mol% and at gas temperatures of about 1250 K. Despite wide variations in single-particle behavior, the data set reveals two clear trends that provide new information on the nature of char combustion. First, the low-rank coal chars are observed to maintain their high reactivity through the late stages of combustion, thus avoiding the near-extinction events and long burnout tails observed for bituminous coal chars. Secondly, percolative fragmentation in the late stages of combustion is a rare event under these conditions. Some particles reach a percolation threshold rate in combustion, but typically undergo spontaneous agglomeration rather than liberation of the incipient fragments. It is concluded that percolative fragmentation behavior in the pulverized size range is determined not only by solid-phase connectivity, but also by a real competition between disruptive and cohesive forces present at the time of formation of the colloidal-sized incipient fragments.

  15. Roots at the percolation threshold.

    PubMed

    Kroener, Eva; Ahmed, Mutez Ali; Carminati, Andrea

    2015-04-01

    The rhizosphere is the layer of soil around the roots where complex and dynamic interactions between plants and soil affect the capacity of plants to take up water. The physical properties of the rhizosphere are affected by mucilage, a gel exuded by roots. Mucilage can absorb large volumes of water, but it becomes hydrophobic after drying. We use a percolation model to describe the rewetting of dry rhizosphere. We find that at a critical mucilage concentration the rhizosphere becomes impermeable. The critical mucilage concentration depends on the radius of the soil particle size. Capillary rise experiments with neutron radiography prove that for concentrations below the critical mucilage concentration water could easily cross the rhizosphere, while above the critical concentration water could no longer percolate through it. Our studies, together with former observations of water dynamics in the rhizosphere, suggest that the rhizosphere is near the percolation threshold, where small variations in mucilage concentration sensitively alter the soil hydraulic conductivity. Is mucilage exudation a plant mechanism to efficiently control the rhizosphere conductivity and the access to water? PMID:25974526

  16. Noise scaling in continuum percolating films

    NASA Astrophysics Data System (ADS)

    Garfunkel, G. A.; Weissman, M. B.

    1985-07-01

    Measurements of the scaling of 1/f noise magnitude versus resistance were made in metal films as the metal was removed by sandblasting. This procedure gives an approximate experimental realization of a Swiss-cheese continuum-percolation model, for which theory indicates some scaling properties very different from lattice percolation. The ratio of the resistance and noise exponents was in strong disagreement with lattice-percolation predictions and agreed approximately with simple continuum predictions.

  17. Semi-directed percolation in two dimensions

    NASA Astrophysics Data System (ADS)

    Knežević, Dragica; Knežević, Milan

    2016-02-01

    We studied a model of semi-directed percolation on finite strips of the square and triangular lattices. Using the transfer-matrix method, combined with phenomenological renormalization group approach, we obtain good numerical estimates for critical probabilities and correlation lengths critical exponents. Our results confirm the conjecture that semi-directed percolation belongs to the universality class of the usual fully-directed percolation model.

  18. Weighted Percolation on Directed Networks

    NASA Astrophysics Data System (ADS)

    Restrepo, Juan G.; Ott, Edward; Hunt, Brian R.

    2008-02-01

    We present and numerically test an analysis of the percolation transition for general node removal strategies valid for locally treelike directed networks. On the basis of heuristic arguments we predict that, if the probability of removing node i is pi, the network disintegrates if pi is such that the largest eigenvalue of the matrix with entries Aij(1-pi) is less than 1, where A is the adjacency matrix of the network. The knowledge or applicability of a Markov network model is not required by our theory, thus making it applicable to situations not covered by previous works.

  19. Bootstrap percolation on spatial networks

    NASA Astrophysics Data System (ADS)

    Gao, Jian; Zhou, Tao; Hu, Yanqing

    2015-10-01

    Bootstrap percolation is a general representation of some networked activation process, which has found applications in explaining many important social phenomena, such as the propagation of information. Inspired by some recent findings on spatial structure of online social networks, here we study bootstrap percolation on undirected spatial networks, with the probability density function of long-range links’ lengths being a power law with tunable exponent. Setting the size of the giant active component as the order parameter, we find a parameter-dependent critical value for the power-law exponent, above which there is a double phase transition, mixed of a second-order phase transition and a hybrid phase transition with two varying critical points, otherwise there is only a second-order phase transition. We further find a parameter-independent critical value around -1, about which the two critical points for the double phase transition are almost constant. To our surprise, this critical value -1 is just equal or very close to the values of many real online social networks, including LiveJournal, HP Labs email network, Belgian mobile phone network, etc. This work helps us in better understanding the self-organization of spatial structure of online social networks, in terms of the effective function for information spreading.

  20. Bootstrap percolation on spatial networks

    PubMed Central

    Gao, Jian; Zhou, Tao; Hu, Yanqing

    2015-01-01

    Bootstrap percolation is a general representation of some networked activation process, which has found applications in explaining many important social phenomena, such as the propagation of information. Inspired by some recent findings on spatial structure of online social networks, here we study bootstrap percolation on undirected spatial networks, with the probability density function of long-range links’ lengths being a power law with tunable exponent. Setting the size of the giant active component as the order parameter, we find a parameter-dependent critical value for the power-law exponent, above which there is a double phase transition, mixed of a second-order phase transition and a hybrid phase transition with two varying critical points, otherwise there is only a second-order phase transition. We further find a parameter-independent critical value around −1, about which the two critical points for the double phase transition are almost constant. To our surprise, this critical value −1 is just equal or very close to the values of many real online social networks, including LiveJournal, HP Labs email network, Belgian mobile phone network, etc. This work helps us in better understanding the self-organization of spatial structure of online social networks, in terms of the effective function for information spreading. PMID:26423347

  1. Bond Percolation on Multiplex Networks

    NASA Astrophysics Data System (ADS)

    Hackett, A.; Cellai, D.; Gómez, S.; Arenas, A.; Gleeson, J. P.

    2016-04-01

    We present an analytical approach for bond percolation on multiplex networks and use it to determine the expected size of the giant connected component and the value of the critical bond occupation probability in these networks. We advocate the relevance of these tools to the modeling of multilayer robustness and contribute to the debate on whether any benefit is to be yielded from studying a full multiplex structure as opposed to its monoplex projection, especially in the seemingly irrelevant case of a bond occupation probability that does not depend on the layer. Although we find that in many cases the predictions of our theory for multiplex networks coincide with previously derived results for monoplex networks, we also uncover the remarkable result that for a certain class of multiplex networks, well described by our theory, new critical phenomena occur as multiple percolation phase transitions are present. We provide an instance of this phenomenon in a multiplex network constructed from London rail and European air transportation data sets.

  2. Textile recycling

    SciTech Connect

    Jablonowski, E. ); Carlton, J.

    1995-01-01

    The most common household textiles include clothing, linens, draperies, carpets, shoes, handbags, and rugs. Old clothing, of course, is the most readily reused and/or recycled residentially generated textile category. State and/or local mandates to recycle a percentage of the waste stream are providing the impetus to add new materials to existing collection programs. Concurrently, the textile industry is aggressively trying to increase its throughput by seeking new sources of material to meet increased world demand for product. As experienced with drop-off programs for traditional materials, a majority of residents will not recycle materials unless the collection programs are convenient, i.e., curbside collection. The tonnage of marketable textiles currently being landfilled provide evidence of this. It is the authors' contention that if textile recycling is made convenient and accessible to every household in a municipality or region, then the waste stream disposed may be reduced in a similar fashion as when traditional recyclables are included in curbside programs.

  3. Percolation in suspensions and de Gennes conjectures

    NASA Astrophysics Data System (ADS)

    Gallier, Stany; Lemaire, Elisabeth; Peters, François; Lobry, Laurent

    2015-08-01

    Dense suspensions display complex flow properties, intermediate between solid and liquid. When sheared, a suspension self-organizes and forms particle clusters that are likely to percolate, possibly leading to significant changes in the overall behavior. Some theoretical conjectures on percolation in suspensions were proposed by de Gennes some 35 years ago. Although still used, they have not received any validations so far. In this Rapid Communication, we use three-dimensional detailed numerical simulations to understand the formation of percolation clusters and assess de Gennes conjectures. We found that sheared noncolloidal suspensions do show percolation clusters occurring at a critical volume fraction in the range 0.3-0.4 depending on the system size. Percolation clusters are roughly linear, extremely transient, and involve a limited number of particles. We have computed critical exponents and found that clusters can be described reasonably well by standard isotropic percolation theory. The only disagreement with de Gennes concerns the role of percolation clusters on rheology which is found to be weak. Our results eventually validate de Gennes conjectures and demonstrate the relevance of percolation concepts in suspension physics.

  4. Emergence of coexisting percolating clusters in networks

    NASA Astrophysics Data System (ADS)

    Faqeeh, Ali; Melnik, Sergey; Colomer-de-Simón, Pol; Gleeson, James P.

    2016-06-01

    It is commonly assumed in percolation theories that at most one percolating cluster can exist in a network. We show that several coexisting percolating clusters (CPCs) can emerge in networks due to limited mixing, i.e., a finite and sufficiently small number of interlinks between network modules. We develop an approach called modular message passing (MMP) to describe and verify these observations. We demonstrate that the appearance of CPCs is an important source of inaccuracy in previously introduced percolation theories, such as the message passing (MP) approach, which is a state-of-the-art theory based on the belief propagation method. Moreover, we show that the MMP theory improves significantly over the predictions of MP for percolation on synthetic networks with limited mixing and also on several real-world networks. These findings have important implications for understanding the robustness of networks and in quantifying epidemic outbreaks in the susceptible-infected-recovered (SIR) model of disease spread.

  5. Emergence of coexisting percolating clusters in networks.

    PubMed

    Faqeeh, Ali; Melnik, Sergey; Colomer-de-Simón, Pol; Gleeson, James P

    2016-06-01

    It is commonly assumed in percolation theories that at most one percolating cluster can exist in a network. We show that several coexisting percolating clusters (CPCs) can emerge in networks due to limited mixing, i.e., a finite and sufficiently small number of interlinks between network modules. We develop an approach called modular message passing (MMP) to describe and verify these observations. We demonstrate that the appearance of CPCs is an important source of inaccuracy in previously introduced percolation theories, such as the message passing (MP) approach, which is a state-of-the-art theory based on the belief propagation method. Moreover, we show that the MMP theory improves significantly over the predictions of MP for percolation on synthetic networks with limited mixing and also on several real-world networks. These findings have important implications for understanding the robustness of networks and in quantifying epidemic outbreaks in the susceptible-infected-recovered (SIR) model of disease spread. PMID:27415281

  6. Tire Recycling

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Cryopolymers, Inc. tapped NASA expertise to improve a process for recycling vehicle tires by converting shredded rubber into products that can be used in asphalt road beds, new tires, hoses, and other products. In conjunction with the Southern Technology Applications Center and Stennis Space Center, NASA expertise in cryogenic fuel-handling needed for launch vehicle and spacecraft operations was called upon to improve the recycling concept. Stennis advised Cryopolymers on the type of equipment required, as well as steps to reduce the amount of liquid nitrogen used in the process. They also guided the company to use more efficient ways to control system hardware. It is estimated that more than 300 million tires nationwide are produced per year. Cryopolymers expects to reach a production rate of 5,000 tires recycled per day.

  7. Global persistence in directed percolation

    NASA Astrophysics Data System (ADS)

    Oerding, K.; van Wijland, F.

    1998-08-01

    We consider a directed percolation process at its critical point. The probability that the deviation of the global order parameter with respect to its average has not changed its sign between 0 and t decays with t as a power law. In space dimensions 0305-4470/31/34/004/img5 the global persistence exponent 0305-4470/31/34/004/img6 that characterizes this decay is 0305-4470/31/34/004/img7 while for d<4 its value is increased to first order in 0305-4470/31/34/004/img8. Combining a method developed by Majumdar and Sire with renormalization group techniques we compute the correction to 0305-4470/31/34/004/img6 to first order in 0305-4470/31/34/004/img10. The global persistence exponent is found to be a new and independent exponent. Finally we compare our results with existing simulations.

  8. Transport on exploding percolation clusters

    NASA Astrophysics Data System (ADS)

    Andrade, José S., Jr.; Herrmann, Hans J.; Moreira, André A.; Oliveira, Cláudio L. N.

    2011-03-01

    We propose a simple generalization of the explosive percolation process [Achlioptas , ScienceSCIEAS0036-807510.1126/science.1167782 323, 1453 (2009)], and investigate its structural and transport properties. In this model, at each step, a set of q unoccupied bonds is randomly chosen. Each of these bonds is then associated with a weight given by the product of the cluster sizes that they would potentially connect, and only that bond among the q set which has the smallest weight becomes occupied. Our results indicate that, at criticality, all finite-size scaling exponents for the spanning cluster, the conducting backbone, the cutting bonds, and the global conductance of the system, change continuously and significantly with q. Surprisingly, we also observe that systems with intermediate values of q display the worst conductive performance. This is explained by the strong inhibition of loops in the spanning cluster, resulting in a substantially smaller associated conducting backbone.

  9. Roots at the Percolation Threshold

    NASA Astrophysics Data System (ADS)

    Kroener, E.; Ahmed, M. A.; Kaestner, A.; Vontobel, P.; Zarebanadkouki, M.; Carminati, A.

    2014-12-01

    Much of the carbon assimilated by plants during photosynthesis is lost to the soil via rhizodepositions. One component of rhizopdeposition is mucilage, a hydrogel that dramatically alters the soil physical properties. Mucilage was assumed to explain unexpectedly low rhizosphere rewetting rates during irrigation (Carminati et al. 2010) and temporarily water repellency in the rhizosphere after severe drying (Moradi et al. 2012).Here, we present an experimental and theoretical study for the rewetting behaviour of a soil mixed with mucilage, which was used as an analogue of the rhizosphere. Our samples were made of two layers of untreated soils separated by a thin layer (ca. 1 mm) of soil treated with mucilage. We prepared soil columns of varying particle size, mucilage concentration and height of the middle layer above the water table. The dry soil columns were re-wetted by capillary rise from the bottom.The rewetting of the middle layer showed a distinct dual behavior. For mucilage concentrations lower than a certain threshold, water could cross the thin layer almost immediately after rewetting of bulk soil. At slightly higher mucilage concentrations, the thin layer was almost impermeable. The mucilage concentration at the threshold strongly depended on particle size: the smaller the particle size the larger the soil specific surface and the more mucilage was needed to cover the entire particle surface and to induce water repellency.We applied a classic pore network model to simulate the experimental observations. In the model a certain fraction of nodes were randomly disconnected to reproduce the effect of mucilage in temporarily blocking the flow. The percolation model could qualitatively reproduce well the threshold characteristics of the experiments. Our experiments, together with former observations of water dynamics in the rhizosphere, suggest that the rhizosphere is near the percolation threshold, where small variations in mucilage concentration sensitively

  10. Rethinking Rice Preparation for Highly Efficient Removal of Inorganic Arsenic Using Percolating Cooking Water

    PubMed Central

    Carey, Manus; Jiujin, Xiao; Gomes Farias, Júlia; Meharg, Andrew A.

    2015-01-01

    A novel way of cooking rice to maximize the removal of the carcinogen inorganic arsenic (Asi) is presented here. In conventional rice cooking water and grain are in continuous contact, and it is known that the larger the water:rice cooking ratio, the more Asi removed by cooking, suggesting that the Asi in the grain is mobile in water. Experiments were designed where rice is cooked in a continual stream of percolating near boiling water, either low in Asi, or Asi free. This has the advantage of not only exposing grain to large volumes of cooking water, but also physically removes any Asi leached from the grain into the water receiving vessel. The relationship between cooking water volume and Asi removal in conventional rice cooking was demonstrated for the rice types under study. At a water-to-rice cooking ratio of 12:1, 57±5% of Asi could be removed, average of 6 wholegrain and 6 polished rice samples. Two types of percolating technology were tested, one where the cooking water was recycled through condensing boiling water steam and passing the freshly distilled hot water through the grain in a laboratory setting, and one where tap water was used to cook the rice held in an off-the-shelf coffee percolator in a domestic setting. Both approaches proved highly effective in removing Asi from the cooking rice, with up to 85% of Asi removed from individual rice types. For the recycled water experiment 59±8% and 69±10% of Asi was removed, on average, compared to uncooked rice for polished (n=27) and wholegrain (n=13) rice, respectively. For coffee percolation there was no difference between wholegrain and polished rice, and the effectiveness of Asi removal was 49±7% across 6 wholegrain and 6 polished rice samples. The manuscript explores the potential applications and further optimization of this percolating cooking water, high Asi removal, discovery. PMID:26200355

  11. Rethinking Rice Preparation for Highly Efficient Removal of Inorganic Arsenic Using Percolating Cooking Water.

    PubMed

    Carey, Manus; Jiujin, Xiao; Gomes Farias, Júlia; Meharg, Andrew A

    2015-01-01

    A novel way of cooking rice to maximize the removal of the carcinogen inorganic arsenic (Asi) is presented here. In conventional rice cooking water and grain are in continuous contact, and it is known that the larger the water:rice cooking ratio, the more Asi removed by cooking, suggesting that the Asi in the grain is mobile in water. Experiments were designed where rice is cooked in a continual stream of percolating near boiling water, either low in Asi, or Asi free. This has the advantage of not only exposing grain to large volumes of cooking water, but also physically removes any Asi leached from the grain into the water receiving vessel. The relationship between cooking water volume and Asi removal in conventional rice cooking was demonstrated for the rice types under study. At a water-to-rice cooking ratio of 12:1, 57±5% of Asi could be removed, average of 6 wholegrain and 6 polished rice samples. Two types of percolating technology were tested, one where the cooking water was recycled through condensing boiling water steam and passing the freshly distilled hot water through the grain in a laboratory setting, and one where tap water was used to cook the rice held in an off-the-shelf coffee percolator in a domestic setting. Both approaches proved highly effective in removing Asi from the cooking rice, with up to 85% of Asi removed from individual rice types. For the recycled water experiment 59±8% and 69±10% of Asi was removed, on average, compared to uncooked rice for polished (n=27) and wholegrain (n=13) rice, respectively. For coffee percolation there was no difference between wholegrain and polished rice, and the effectiveness of Asi removal was 49±7% across 6 wholegrain and 6 polished rice samples. The manuscript explores the potential applications and further optimization of this percolating cooking water, high Asi removal, discovery. PMID:26200355

  12. Utility of Recycled Bedding for Laboratory Rodents

    PubMed Central

    Miyamoto, Toru; Li, Zhixia; Kibushi, Tomomi; Okano, Shinya; Yamasaki, Nakamichi; Kasai, Noriyuki

    2009-01-01

    Animal facilities generate a large amount of used bedding containing excrement as medical waste. We developed a recycling system for used bedding that involves soft hydrothermal processing. In this study, we examined the effects of bedding type on growth, hematologic and serum biochemical values, and organ weights of female and male mice reared on either recycled or fresh bedding from 3 to 33 wk of age. Neither growth nor physiology differed between mice housed on recycled bedding compared with fresh bedding. When 14-wk-old mice were bred, litter size and total number of weaned pups showed no significant differences between animals raised on recycled or fresh bedding. Because bedding type influences the environment within cages and animal rooms, we evaluated particulate and ammonia data from cages and animal rooms. Values were significantly lower from cages and rooms that used recycled bedding than from those using fresh bedding, thus indicating that recycled bedding has the potential to improve the environment within both cages and animal rooms. Overall, this study revealed that recycled bedding is an excellent material for use in housing laboratory rodents. Specifically, recycled bedding may reduce medical waste and maintain healthy environments within cages and animal rooms. PMID:19653951

  13. Toxicity of ammonia in pore-water and in the water column to freshwater benthic invertebrates

    SciTech Connect

    Whiteman, F.W.; Kahl, M.D.; Rau, D.M.; Balcer, M.D.; Ankley, G.T.

    1994-12-31

    Ammonia has been mentioned as both a primary toxicant and a factor that can produce false positive results in laboratory sediment tests using benthic invertebrates. This study developed a sediment dosing system that percolates an ammonia solution through sediment to achieve target porewater ammonia concentrations that remain stable over four and ten day spiked sediment tests. Ten day flow-through water-only tests and ten day spiked sediment tests were used to determine the toxicity of ammonia in the water column and in the sediment pore-water to the oligochaete Lumbriculus variegatus and the midge Chironomus tentans. Four-day tests were run with the amphipod Hyalella azteca. The relationship between water column ammonia toxicity and sediment pore-water ammonia toxicity is influenced by the organism`s association with the sediment. For Lumbriculus variegatus and Chironomus tentans that burrow into the sediment and are in direct contact with the porewater, the pore-water LC50 for ammonia is 30--40% higher than the water-only LC50 for each species. Hyalella azteca is epibenthic and avoids ammonia spiked sediment, thus ammonia in the water column is considerably more toxic than the pore-water ammonia with the porewater LC50 about 800% higher than the water only LC50.

  14. Precipitation Recycling

    NASA Technical Reports Server (NTRS)

    Eltahir, Elfatih A. B.; Bras, Rafael L.

    1996-01-01

    The water cycle regulates and reflects natural variability in climate at the regional and global scales. Large-scale human activities that involve changes in land cover, such as tropical deforestation, are likely to modify climate through changes in the water cycle. In order to understand, and hopefully be able to predict, the extent of these potential global and regional changes, we need first to understand how the water cycle works. In the past, most of the research in hydrology focused on the land branch of the water cycle, with little attention given to the atmospheric branch. The study of precipitation recycling which is defined as the contribution of local evaporation to local precipitation, aims at understanding hydrologic processes in the atmospheric branch of the water cycle. Simply stated, any study on precipitation recycling is about how the atmospheric branch of the water cycle works, namely, what happens to water vapor molecules after they evaporate from the surface, and where will they precipitate?

  15. Coalescence and percolation in thin metal films

    SciTech Connect

    Yu, X.; Duxbury, P.M.; Jeffers, G.; Dubson, M.A. Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824-1116 )

    1991-12-15

    Metals thermally evaporated onto warm insulating substrates evolve to the thin-film state via the morphological sequence: compact islands, elongated islands, percolation, hole filling, and finally the thin-film state. The coverage at which the metal percolates ({ital p}{sub {ital c}}) is often considerably higher than that predicted by percolation models, such as inverse swiss cheese or lattice percolation. Using a simple continuum model, we show that high-{ital p}{sub {ital c}}'s arise naturally in thin films that exhibit a crossover from full coalescence of islands at early stages of growth to partial coalescence at later stages. In this interrupted-coalescence model, full coalescence of islands occurs up to a critical island radius {ital R}{sub {ital c}}, after which islands overlap, but do not fully coalesce. We present the morphology of films and the critical area coverages generated by this model.

  16. Discrete scale invariance in supercritical percolation

    NASA Astrophysics Data System (ADS)

    Schröder, Malte; Chen, Wei; Nagler, Jan

    2016-01-01

    Recently it has been demonstrated that the connectivity transition from microscopic connectivity to macroscopic connectedness, known as percolation, is generically announced by a cascade of microtransitions of the percolation order parameter (Chen et al 2014 Phys. Rev. Lett. 112 155701). Here we report the discovery of macrotransition cascades which follow percolation. The order parameter grows in discrete macroscopic steps with positions that can be randomly distributed even in the thermodynamic limit. These transition positions are, however, correlated and follow scaling laws which arise from discrete scale invariance (DSI) and non self-averaging, both traditionally unrelated to percolation. We reveal the DSI in ensemble measurements of these non self-averaging systems by rescaling of the individual realizations before averaging.

  17. Lateral diffusion and percolation in membranes.

    PubMed

    Sung, Bong June; Yethiraj, Arun

    2006-06-01

    An algorithm based on Voronoi tessellation and percolation theory is presented to study the diffusion of model membrane components (solutes) in the plasma membrane. The membrane is modeled as a two-dimensional space with integral membrane proteins as static obstacles. The Voronoi diagram consists of vertices, which are equidistant from three matrix obstacles, joined by edges. An edge between two vertices is said to be connected if solute particles can pass directly between the two regions. The percolation threshold, pc, determined using this passage criterion is pc approximately equal to 0.53. This is smaller than if the connectivity of edges were assigned randomly, in which case the percolation threshold pr=2/3, where p is the fraction of connected edges. Molecular dynamics simulations show that diffusion is determined by percolation of clusters of edges. PMID:16803348

  18. Percolation of secret correlations in a network

    SciTech Connect

    Leverrier, Anthony; Garcia-Patron, Raul

    2011-09-15

    In this work, we explore the analogy between entanglement and secret classical correlations in the context of large networks--more precisely, the question of percolation of secret correlations in a network. It is known that entanglement percolation in quantum networks can display a highly nontrivial behavior depending on the topology of the network and on the presence of entanglement between the nodes. Here we show that this behavior, thought to be of a genuine quantum nature, also occurs in a classical context.

  19. Photosynthesis of ammonia

    SciTech Connect

    Mallow, W.A.

    1984-09-24

    This study has demonstrated the technical feasibility of producing ammonia using an innovative technique of combining air, water and sunlight. The technique involves passing moist air over a catalyst-doped, open-celled silica foam bed illuminated by concentrated sunlight. A catalytic reaction results in tounts of ammonia. The work summarized in this report included testing of a pilot (small scale) ammonia production system located on the roof of a Southwest Research Institute (SwRI) Laboratory located in San Antonio, Texas. The system consisted of a catalyst foam bed located in a glass tube about three meters long and 5 centimeters in diameter and mounted on the focal line of a parabolic trough solar collector focused at the sun. The primary active ingredient in the catalyst was titanium dioxide. Moist air was blown through the glass tube, over illuminated catalyst foam bed. A catalytic reaction took place in the foam bed resulting in the production of ammonia gas. The ammonia gas was bubbled through a water scrubber where the ammonia was dissolved. The ammonia concentration in the scrubber water was then measured using chemiluminescence and spectrophotometry techniques to determine the ammonia production rate. Thirty-one tests were conducted in the roof top facility. A number of important process parameters were evaluated. The ammonia production rate from these tests varied from several milligrams per hour to a few micrograms per hour. The tests showed that ammonia production was possible although the yields were relatively low. Several aspects of the process could be improved to increase the yield rates. Specifically, better techniques for illuminating the catalyst with concentrated sunlight and for providing moisture at the catalyst surface should enhance the ammonia production rate. 13 references, 7 figures, 1 table.

  20. Multiple-well invasion percolation.

    PubMed

    Araújo, A D; Romeu, M C; Moreira, A A; Andrade, R F S; Andrade, J S

    2008-04-01

    When the invasion percolation model is applied as a simplified model for the displacement of a viscous fluid by a less viscous one, the distribution of displaced mass follows two distinct universality classes, depending on the criteria used to stop the displacement. Here we study the distribution of mass for this process, in the case where four extraction wells are placed around a single injection well in the middle of a square lattice. Our analysis considers the limit where the pressure of the extraction well Pe is zero; in other words, an extraction well is capped as soon as less viscous fluid reaches that extraction well. Our results show that, as expected, the probability of stopping the production with small amounts of displaced mass is greatly reduced. We also investigate whether or not creating extra extraction wells is an efficient strategy. We show that the probability of increasing the amount of displaced fluid by adding an extra extraction well depends on the total recovered mass obtained before adding this well. The results presented here could be relevant to determine efficient strategies in oil exploration. PMID:18517620

  1. A Percolation Model for Fracking

    NASA Astrophysics Data System (ADS)

    Norris, J. Q.; Turcotte, D. L.; Rundle, J. B.

    2014-12-01

    Developments in fracking technology have enabled the recovery of vast reserves of oil and gas; yet, there is very little publicly available scientific research on fracking. Traditional reservoir simulator models for fracking are computationally expensive, and require many hours on a supercomputer to simulate a single fracking treatment. We have developed a computationally inexpensive percolation model for fracking that can be used to understand the processes and risks associated with fracking. In our model, a fluid is injected from a single site and a network of fractures grows from the single site. The fracture network grows in bursts, the failure of a relatively strong bond followed by the failure of a series of relatively weak bonds. These bursts display similarities to micro seismic events observed during a fracking treatment. The bursts follow a power-law (Gutenburg-Richter) frequency-size distribution and have growth rates similar to observed earthquake moment rates. These are quantifiable features that can be compared to observed microseismicity to help understand the relationship between observed microseismicity and the underlying fracture network.

  2. Generalized epidemic process and tricritical dynamic percolation

    NASA Astrophysics Data System (ADS)

    Janssen, Hans-Karl; Müller, Martin; Stenull, Olaf

    2004-08-01

    The renowned general epidemic process describes the stochastic evolution of a population of individuals which are either susceptible, infected, or dead. A second order phase transition belonging to the universality class of dynamic isotropic percolation lies between the endemic and pandemic behavior of the process. We generalize the general epidemic process by introducing a fourth kind of individuals, viz., individuals which are weakened by the process but not yet infected. This weakening gives rise to a mechanism that introduces a global instability in the spreading of the process and therefore opens the possibility of a discontinuous transition in addition to the usual continuous percolation transition. The tricritical point separating the lines of first and second order transitions constitutes an independent universality class, namely, the universality class of tricritical dynamic isotropic percolation. Using renormalized field theory we work out a detailed scaling description of this universality class. We calculate the scaling exponents in an ɛ expansion below the upper critical dimension dc=5 for various observables describing tricritical percolation clusters and their spreading properties. In a remarkable contrast to the usual percolation transition, the exponents β and β' governing the two order parameters, viz., the mean density and the percolation probability, turn out to be different at the tricritical point. In addition to the scaling exponents we calculate for all our static and dynamic observables logarithmic corrections to the mean-field scaling behavior at dc=5 .

  3. Assessing Ammonia Treatment Options

    EPA Science Inventory

    This is the second of three articles to help water system operators understand ammonia and how to monitor and control its effects at the plant and in the distribution system. The first article (Opflow, April 2012) provided an overview of ammonia's chemistry, origins, and water sy...

  4. Method for forming ammonia

    DOEpatents

    Kong, Peter C.; Pink, Robert J.; Zuck, Larry D.

    2008-08-19

    A method for forming ammonia is disclosed and which includes the steps of forming a plasma; providing a source of metal particles, and supplying the metal particles to the plasma to form metal nitride particles; and providing a substance, and reacting the metal nitride particles with the substance to produce ammonia, and an oxide byproduct.

  5. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  6. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  7. Application of percolation theory to microtomography of structured media: Percolation threshold, critical exponents, and upscaling

    NASA Astrophysics Data System (ADS)

    Liu, Jie; Regenauer-Lieb, Klaus

    2011-01-01

    Percolation theory provides a tool for linking microstructure and macroscopic material properties. In this paper, percolation theory is applied to the analysis of microtomographic images for the purpose of deriving scaling laws for upscaling of properties. We have tested the acquisition of quantities such as percolation threshold, crossover length, fractal dimension, and critical exponent of correlation length from microtomography. By inflating or deflating the target phase and percolation analysis, we can get a critical model and an estimation of the percolation threshold. The crossover length is determined from the critical model by numerical simulation. The fractal dimension can be obtained either from the critical model or from the relative size distribution of clusters. Local probabilities of percolation are used to extract the critical exponent of the correlation length. For near-isotropic samples such as sandstone and bread, the approach works very well. For strongly anisotropic samples, such as highly deformed rock (mylonite) and a tree branch, the percolation threshold and fractal dimension can be assessed with accuracy. However, the uncertainty of the correlation length makes it difficult to accurately extract its critical exponents. Therefore, this aspect of percolation theory cannot be reliably used for upscaling properties of strongly anisotropic media. Other methods of upscaling have to be used for such media.

  8. Recycling Lesson Plans.

    ERIC Educational Resources Information Center

    Pennsylvania State Dept. of Environmental Resources, Harrisburg.

    This document contains lesson plans about recycling for teachers in grades K-12. Titles include: (1) "Waste--Where Does It Come From? Where Does It Go?" (2) "Litter Detectives," (3) "Classroom Paper Recycling," (4) "Recycling Survey," (5) "Disposal and Recycling Costs," (6) "Composting Project," (7) Used Motor Oil Recycling," (8) "Unwrapping…

  9. Mathematical Model of Ammonia Handling in the Rat Renal Medulla

    PubMed Central

    Noiret, Lorette; Baigent, Stephen; Jalan, Rajiv; Thomas, S. Randall

    2015-01-01

    The kidney is one of the main organs that produces ammonia and release it into the circulation. Under normal conditions, between 30 and 50% of the ammonia produced in the kidney is excreted in the urine, the rest being absorbed into the systemic circulation via the renal vein. In acidosis and in some pathological conditions, the proportion of urinary excretion can increase to 70% of the ammonia produced in the kidney. Mechanisms regulating the balance between urinary excretion and renal vein release are not fully understood. We developed a mathematical model that reflects current thinking about renal ammonia handling in order to investigate the role of each tubular segment and identify some of the components which might control this balance. The model treats the movements of water, sodium chloride, urea, NH3 and NH4+, and non-reabsorbable solute in an idealized renal medulla of the rat at steady state. A parameter study was performed to identify the transport parameters and microenvironmental conditions that most affect the rate of urinary ammonia excretion. Our results suggest that urinary ammonia excretion is mainly determined by those parameters that affect ammonia recycling in the loops of Henle. In particular, our results suggest a critical role for interstitial pH in the outer medulla and for luminal pH along the inner medullary collecting ducts. PMID:26280830

  10. Surface exponent in percolation and central-force percolation: A test for splay rigidity

    NASA Astrophysics Data System (ADS)

    Roux, Stéphane; Hansen, Alex

    1988-09-01

    We study two related problems: one in the usual percolation and the other in central-force percolation; namely, the probability that a site sitting on the border of a semi-infinite domain belongs to either the infinite cluster in usual percolation or the infinitely rigid cluster in central-force percolation. We study the critical exponents describing the critical behavior of these probabilities by a numerical simulation using a transfer-matrix technique. Our results are consistent with the hypothesis that both critical phenomena belong to the same universality class. In addition, our results suggest that the splay-rigid phase threshold is different from the rigidity threshold in central-force percolation.

  11. Percolation thresholds and percolation conductivities of octagonal and dodecagonal quasicrystalline lattices

    NASA Astrophysics Data System (ADS)

    Babalievski, F.

    1995-02-01

    The octagonal and dodecagonal quaislattices were generated by means of the grid method. Monte Carlo simulation and cluster counting procedure were used for numerical determination of the site and bond percolation thresholds. Two types of connectivity called ferromagnetic and chemical were studied. The estimated site percolation thresholds are 0.5435… and 0.585… for octagonal lattice and 0.617… and 0.628… for dodecagonal lattice respectively. The obtained spanning fraction curves (for site percolation) seem to approach the 50% value at the percolation threshold. The site percolation conductivity for these lattices was studied by means of a transfer-matrix approach. The critical behavior was found to be the same as for the periodic lattices.

  12. Effect of filler alignment on percolation in polymer nanocomposites using tunneling-percolation model

    NASA Astrophysics Data System (ADS)

    Kale, Sohan; Sabet, Fereshteh A.; Jasiuk, Iwona; Ostoja-Starzewski, Martin

    2016-07-01

    In this study, we examine the effect of filler alignment on percolation behavior of polymer nanocomposites using Monte Carlo simulations of monodisperse prolate and oblate hard-core soft-shell ellipsoids representing carbon nanotubes and graphene nanoplatelets, respectively. The percolation threshold is observed to increase with increasing extent of alignment as expected. For a highly aligned system of rod-like fillers, the simulation results are shown to be in good agreement with the second virial approximation based predictions. However, for a highly aligned system of disk-like fillers, the second virial approximation based results are observed to significantly deviate from the simulations, even for higher aspect ratios. The effect of filler alignment on anisotropy in percolation behavior is also studied by predicting the percolation threshold along different directions. The anisotropy in percolation threshold is found to vanish even for highly aligned systems of fillers with increasing system size.

  13. Ammonia Leak Locator Study

    NASA Technical Reports Server (NTRS)

    Dodge, Franklin T.; Wuest, Martin P.; Deffenbaugh, Danny M.

    1995-01-01

    The thermal control system of International Space Station Alpha will use liquid ammonia as the heat exchange fluid. It is expected that small leaks (of the order perhaps of one pound of ammonia per day) may develop in the lines transporting the ammonia to the various facilities as well as in the heat exchange equipment. Such leaks must be detected and located before the supply of ammonia becomes critically low. For that reason, NASA-JSC has a program underway to evaluate instruments that can detect and locate ultra-small concentrations of ammonia in a high vacuum environment. To be useful, the instrument must be portable and small enough that an astronaut can easily handle it during extravehicular activity. An additional complication in the design of the instrument is that the environment immediately surrounding ISSA will contain small concentrations of many other gases from venting of onboard experiments as well as from other kinds of leaks. These other vapors include water, cabin air, CO2, CO, argon, N2, and ethylene glycol. Altogether, this local environment might have a pressure of the order of 10(exp -7) to 10(exp -6) torr. Southwest Research Institute (SwRI) was contracted by NASA-JSC to provide support to NASA-JSC and its prime contractors in evaluating ammonia-location instruments and to make a preliminary trade study of the advantages and limitations of potential instruments. The present effort builds upon an earlier SwRI study to evaluate ammonia leak detection instruments [Jolly and Deffenbaugh]. The objectives of the present effort include: (1) Estimate the characteristics of representative ammonia leaks; (2) Evaluate the baseline instrument in the light of the estimated ammonia leak characteristics; (3) Propose alternative instrument concepts; and (4) Conduct a trade study of the proposed alternative concepts and recommend promising instruments. The baseline leak-location instrument selected by NASA-JSC was an ion gauge.

  14. Percolation on hypergraphs with four-edges

    NASA Astrophysics Data System (ADS)

    Khatib Damavandi, Ojan; Ziff, Robert M.

    2015-10-01

    We study percolation on self-dual hypergraphs that contain hyperedges with four bounding vertices, or ‘four-edges’, using three different generators, each containing bonds or sites with three distinct probabilities p, r, and t connecting the four vertices. We find explicit values of these probabilities that satisfy the self-duality conditions discussed by Bollobás and Riordan. This demonstrates that explicit solutions of the self-duality conditions can be found using generators containing bonds and sites with independent probabilities. These solutions also provide new examples of lattices where exact percolation critical points are known. One of the generators exhibits three distinct criticality solutions (p, r, t). We carry out Monte-Carlo simulations of two of the generators on two different hypergraphs to confirm the critical values. For the case of the hypergraph and uniform generator studied by Wierman et al, we also determine the threshold p = 0.441 374 ± 0.000 001, which falls within the tight bounds that they derived. Furthermore, we consider a generator in which all or none of the vertices can connect, and find a soluble inhomogeneous percolation system that interpolates between site percolation on the union-jack lattice and bond percolation on the square lattice.

  15. Fluid leakage near the percolation threshold

    PubMed Central

    Dapp, Wolf B.; Müser, Martin H.

    2016-01-01

    Percolation is a concept widely used in many fields of research and refers to the propagation of substances through porous media (e.g., coffee filtering), or the behaviour of complex networks (e.g., spreading of diseases). Percolation theory asserts that most percolative processes are universal, that is, the emergent powerlaws only depend on the general, statistical features of the macroscopic system, but not on specific details of the random realisation. In contrast, our computer simulations of the leakage through a seal—applying common assumptions of elasticity, contact mechanics, and fluid dynamics—show that the critical behaviour (how the flow ceases near the sealing point) solely depends on the microscopic details of the last constriction. It appears fundamentally impossible to accurately predict from statistical properties of the surfaces alone how strongly we have to tighten a water tap to make it stop dripping and also how it starts dripping once we loosen it again. PMID:26839261

  16. Fluid leakage near the percolation threshold

    NASA Astrophysics Data System (ADS)

    Dapp, Wolf B.; Müser, Martin H.

    2016-02-01

    Percolation is a concept widely used in many fields of research and refers to the propagation of substances through porous media (e.g., coffee filtering), or the behaviour of complex networks (e.g., spreading of diseases). Percolation theory asserts that most percolative processes are universal, that is, the emergent powerlaws only depend on the general, statistical features of the macroscopic system, but not on specific details of the random realisation. In contrast, our computer simulations of the leakage through a seal—applying common assumptions of elasticity, contact mechanics, and fluid dynamics—show that the critical behaviour (how the flow ceases near the sealing point) solely depends on the microscopic details of the last constriction. It appears fundamentally impossible to accurately predict from statistical properties of the surfaces alone how strongly we have to tighten a water tap to make it stop dripping and also how it starts dripping once we loosen it again.

  17. Fluid leakage near the percolation threshold.

    PubMed

    Dapp, Wolf B; Müser, Martin H

    2016-01-01

    Percolation is a concept widely used in many fields of research and refers to the propagation of substances through porous media (e.g., coffee filtering), or the behaviour of complex networks (e.g., spreading of diseases). Percolation theory asserts that most percolative processes are universal, that is, the emergent powerlaws only depend on the general, statistical features of the macroscopic system, but not on specific details of the random realisation. In contrast, our computer simulations of the leakage through a seal--applying common assumptions of elasticity, contact mechanics, and fluid dynamics--show that the critical behaviour (how the flow ceases near the sealing point) solely depends on the microscopic details of the last constriction. It appears fundamentally impossible to accurately predict from statistical properties of the surfaces alone how strongly we have to tighten a water tap to make it stop dripping and also how it starts dripping once we loosen it again. PMID:26839261

  18. Weakly explosive percolation in directed networks.

    PubMed

    Squires, Shane; Sytwu, Katherine; Alcala, Diego; Antonsen, Thomas M; Ott, Edward; Girvan, Michelle

    2013-05-01

    Percolation, the formation of a macroscopic connected component, is a key feature in the description of complex networks. The dynamical properties of a variety of systems can be understood in terms of percolation, including the robustness of power grids and information networks, the spreading of epidemics and forest fires, and the stability of gene regulatory networks. Recent studies have shown that if network edges are added "competitively" in undirected networks, the onset of percolation is abrupt or "explosive." The unusual qualitative features of this phase transition have been the subject of much recent attention. Here we generalize this previously studied network growth process from undirected networks to directed networks and use finite-size scaling theory to find several scaling exponents. We find that this process is also characterized by a very rapid growth in the giant component, but that this growth is not as sudden as in undirected networks. PMID:23767507

  19. Randomness in fractals, connectivity dimensions, and percolation

    NASA Astrophysics Data System (ADS)

    Perreau, M.; Levy, J. C. S.

    1989-10-01

    The structural properties of random fractals embedded in a d-dimensional Euclidean space are studied by means of transfer-matrix formalism of fractal sets. For d=1, both global and local approaches have been investigated, leading to the definition of a subdimension that is different from the fractal dimension and depends on the probability distribution. This subdimension is shown to be identical for the global and local approaches; then, the scaling corrections involved in this subdimension are the same for both these approaches. For d>1, only the local approach can be generalized, characterizing the connectivity properties of these structures. There are exactly d subdimensions called connectivity dimensions that prove to be useful to describe percolation properties of these fractals. Several percolation thresholds are shown, and the fractal dimension of the sets at the percolation threshold are related to the connectivity dimensions.

  20. The structure of percolating lipid monolayers.

    PubMed

    Risović, D; Frka, S; Kozarac, Z

    2012-05-01

    The lattice structure and in plane molecular organization of Langmuir monolayer of amphiphilic material is usually determined from grazing incidence X-ray diffraction (GIXD) or neutron reflectivity. Here we present results of a different approach for determination of monolayer lattice structure based on application of fractal analysis and percolation theory in combination with Brewster angle microscopy. The considerations of compressibility modulus and fractal dimension dynamics provide information on percolation threshold and consequently by application of percolation theory on the lattice structure of a monolayer. We have applied this approach to determine the monolayer lattice structures of single chain and double chain lipids. The compressibility moduli were determined from measured π-A isotherms and fractal dimensions from corresponding BAM images. The monolayer lattice structures of stearic acid, 1-hexadecanol, DPPC and DPPA, obtained in this way conform to the corresponding lattice structures determined previously by other authors using GIXD. PMID:22209411

  1. Percolation conductivity in hafnium sub-oxides

    SciTech Connect

    Islamov, D. R. Gritsenko, V. A.; Cheng, C. H.; Chin, A.

    2014-12-29

    In this study, we demonstrated experimentally that formation of chains and islands of oxygen vacancies in hafnium sub-oxides (HfO{sub x}, x < 2) leads to percolation charge transport in such dielectrics. Basing on the model of Éfros-Shklovskii percolation theory, good quantitative agreement between the experimental and theoretical data of current-voltage characteristics was achieved. Based on the percolation theory suggested model shows that hafnium sub-oxides consist of mixtures of metallic Hf nanoscale clusters of 1–2 nm distributed onto non-stoichiometric HfO{sub x}. It was shown that reported approach might describe low resistance state current-voltage characteristics of resistive memory elements based on HfO{sub x}.

  2. Percolation conductivity in hafnium sub-oxides

    NASA Astrophysics Data System (ADS)

    Islamov, D. R.; Gritsenko, V. A.; Cheng, C. H.; Chin, A.

    2014-12-01

    In this study, we demonstrated experimentally that formation of chains and islands of oxygen vacancies in hafnium sub-oxides (HfOx, x < 2) leads to percolation charge transport in such dielectrics. Basing on the model of Éfros-Shklovskii percolation theory, good quantitative agreement between the experimental and theoretical data of current-voltage characteristics was achieved. Based on the percolation theory suggested model shows that hafnium sub-oxides consist of mixtures of metallic Hf nanoscale clusters of 1-2 nm distributed onto non-stoichiometric HfOx. It was shown that reported approach might describe low resistance state current-voltage characteristics of resistive memory elements based on HfOx.

  3. Ammonia Release on ISS

    NASA Technical Reports Server (NTRS)

    Macatangay, Ariel

    2009-01-01

    Crew: Approximately 53% metabolic load Product of protein metabolism Limit production of ammonia by external regulation NOT possbile Payloads Potential source Scientific experiments Thorough safety review ensures sufficient levels of containment

  4. Reactor for removing ammonia

    DOEpatents

    Luo, Weifang; Stewart, Kenneth D.

    2009-11-17

    Disclosed is a device for removing trace amounts of ammonia from a stream of gas, particularly hydrogen gas, prepared by a reformation apparatus. The apparatus is used to prevent PEM "poisoning" in a fuel cell receiving the incoming hydrogen stream.

  5. Percolation under noise: Detecting explosive percolation using the second-largest component

    NASA Astrophysics Data System (ADS)

    Viles, Wes; Ginestet, Cedric E.; Tang, Ariana; Kramer, Mark A.; Kolaczyk, Eric D.

    2016-05-01

    We consider the problem of distinguishing between different rates of percolation under noise. A statistical model of percolation is constructed allowing for the birth and death of edges as well as the presence of noise in the observations. This graph-valued stochastic process is composed of a latent and an observed nonstationary process, where the observed graph process is corrupted by type-I and type-II errors. This produces a hidden Markov graph model. We show that for certain choices of parameters controlling the noise, the classical (Erdős-Rényi) percolation is visually indistinguishable from a more rapid form of percolation. In this setting, we compare two different criteria for discriminating between these two percolation models, based on the interquartile range (IQR) of the first component's size, and on the maximal size of the second-largest component. We show through data simulations that this second criterion outperforms the IQR of the first component's size, in terms of discriminatory power. The maximal size of the second component therefore provides a useful statistic for distinguishing between different rates of percolation, under physically motivated conditions for the birth and death of edges, and under noise. The potential application of the proposed criteria for the detection of clinically relevant percolation in the context of applied neuroscience is also discussed.

  6. Ammonia and sediment toxicity

    SciTech Connect

    Ogle, R.S.; Hansen, S.R.

    1994-12-31

    Ammonia toxicity to aquatic organisms has received considerable study, with most of these studies focusing on water column organisms. However, with the development and implementation of sediment (and pore water) toxicity tests, the toxicity of ammonia to benthic infauna and other sediment toxicity test organisms has become important, especially since sediment/porewater ammonia occurs at higher concentrations than in the water column. Unfortunately, there has been very little of this type information, especially for marine/estuarine organisms. This laboratory determined the toxicity of ammonia to three key marine/estuarine test organisms: the amphipod Eohaustorius estuarius, the bivalve Mytilus edulis, and the echinoderm Strongylocentrotus purpuratus. Because sediment/porewater pH can differ substantially from typical seawater pH, the toxicity evaluations covered a range of pH levels (6, 7, 8, and 9). Eohaustorius results indicate that while Total Ammonia increased in toxicity (measured as EC50) as pH increased (from 460 mg/L at pH 6, to 13 mg/L at pH 9), unionized ammonia toxicity decreased from 0.13 mg/L at pH 6 to 2.8 mg/L at pH 9. The amphipod was much less sensitive to ammonia than were the bivalve and echinoderm, with an unionized ammonia EC50 at pH 8 of 2.14 mg/L relative to 0.43 mg/L for the mussel and 0.13 mg/L for the purple urchin. These results are discussed with respect to design and interpretation of sediment toxicity test results, including an interpretation approach based on partitioning of Toxic Units (TU).

  7. Alternative E ammonia feedstock

    SciTech Connect

    Lentz, M.J.; Wright, R.A.

    1999-07-01

    Power plants are using more Ammonia for increasing precipitator and baghouse efficiency, for SCR and SNCR processes, and for controlling acid stack plumes and dewpoint corrosion. These simple systems inject ammonia and air into the furnace or the precipitator or baghouse inlet ductwork. The common feedstocks in use today are Anhydrous ammonia [NH{sub 3}] and Aqueous ammonia [NH{sub 4}OH], both defined as poison gases by US authorities and most Western nations. Storage and handling procedures for these products are strictly regulated. Wilhelm Environmental Technologies Inc. is developing use of solid, formed or prilled Urea [CO(NH{sub 2}){sub 2}] as the feedstock. When heated in moist air, Urea sublimes to ammonia [NH{sub 3}] and carbon dioxide [CO{sub 2}]. Urea is stored and handled without restrictions or environmental concerns. Urea is a more expensive feedstock than NH{sub 3}, but much less expensive than [NH{sub 4}OH]. The design, and operating results, of a pilot system at Jacksonville Electric St. John's River Plant [Unit 2] are described. The pilot plant successfully sublimed Urea up to 100 pounds/hour. Further testing is planned. Very large ammonia use may favor NH{sub 3}, but smaller quantities can be produced at attractive prices with Urea based ammonia systems. Storage costs are far less. Many fluidized-bed boilers can use pastille or solid urea metered directly into the existing cyclones for NO{sub x} control. This is more economical than aqueous ammonia or aqueous urea based technology.

  8. Titan's Ammonia Feature

    NASA Technical Reports Server (NTRS)

    Smythe, W.; Nelson, R.; Boryta, M.; Choukroun, M.

    2011-01-01

    NH3 has long been considered an important component in the formation and evolution of the outer planet satellites. NH3 is particularly important for Titan, since it may serve as the reservoir for atmospheric nitrogen. A brightening seen on Titan starting in 2004 may arise from a transient low-lying fog or surface coating of ammonia. The spectral shape suggests the ammonia is anhydrous, a molecule that hydrates quickly in the presence of water.

  9. Ammonia Clouds on Jupiter

    NASA Technical Reports Server (NTRS)

    2007-01-01

    [figure removed for brevity, see original site] Click on the image for movie of Ammonia Ice Clouds on Jupiter

    In this movie, put together from false-color images taken by the New Horizons Ralph instrument as the spacecraft flew past Jupiter in early 2007, show ammonia clouds (appearing as bright blue areas) as they form and disperse over five successive Jupiter 'days.' Scientists noted how the larger cloud travels along with a small, local deep hole.

  10. Percolation threshold on planar Euclidean Gabriel graphs

    NASA Astrophysics Data System (ADS)

    Norrenbrock, Christoph

    2016-04-01

    In the present article, numerical simulations have been performed to find the bond and site percolation thresholds on two-dimensional Gabriel graphs (GG) for Poisson point processes. GGs belong to the family of "proximity graphs" and are discussed, e.g., in context of the construction of backbones for wireless ad-hoc networks. Finite-size scaling analyses have been performed to find the critical points and critical exponents ν, β and γ. The critical exponents obtained this way verify that the associated universality class is that of standard 2D percolation.

  11. Percolation threshold on planar Euclidean Gabriel graphs

    NASA Astrophysics Data System (ADS)

    Norrenbrock, Christoph

    2016-05-01

    In the present article, numerical simulations have been performed to find the bond and site percolation thresholds on two-dimensional Gabriel graphs (GG) for Poisson point processes. GGs belong to the family of "proximity graphs" and are discussed, e.g., in context of the construction of backbones for wireless ad-hoc networks. Finite-size scaling analyses have been performed to find the critical points and critical exponents ν, β and γ. The critical exponents obtained this way verify that the associated universality class is that of standard 2D percolation.

  12. Percolation systems away from the critical point

    NASA Astrophysics Data System (ADS)

    Dhar, Deepak

    2002-02-01

    This article reviews some effects of disorder in percolation systems away from the critical density pc. For densities below pc, the statistics of large clusters defines the animals problem. Its relation to the directed animals problem and the Lee--Yang edge singularity problem is described. Rare compact clusters give rise to Griffiths singularities in the free energy of diluted ferromagnets, and lead to a very slow relaxation of magnetization. In biased diffusion on percolation clusters, trapping in dead-end branches leads to asymptotic drift velocity becoming zero for strong bias, and very slow relaxation of velocity near the critical bias field.

  13. Recycled pulsars

    NASA Astrophysics Data System (ADS)

    Jacoby, Bryan Anthony

    2005-11-01

    In a survey of ~4,150 square degrees, we discovered 26 previously unknown pulsars, including 7 "recycled" millisecond or binary pulsars. The most significant discovery of this survey is PSR J1909-3744, a 2.95 ms pulsar in an extremely circular 1.5 d orbit with a low-mass white dwarf companion. Though this system is a fairly typical low-mass binary pulsar (LMBP) system, it has several exceptional qualities: an extremely narrow pulse profile and stable rotation have enabled the most precise long-term timing ever reported, and a nearly edge-on orbit gives rise to a strong Shapiro delay which has allowed the most precise measurement of the mass of a millisecond pulsar: m p = (1.438 +/- 0.024) [Special characters omitted.] . Our accurate parallax distance measurement, d p = ([Special characters omitted.] ) kpc, combined with the mass of the optically-detected companion, m c = (0.2038 +/- 0.022) [Special characters omitted.] , will provide an important calibration for white dwarf models relevant to other LMBP companions. We have detected optical counterparts for two intermediate mass binary pulsar (IMBP) systems; taken together with optical detections and non-detections of several similar systems, our results indicate that the characteristic age t = c P /2 P consistently overestimates the time since the end of mass accretion in these recycled systems. We have measured orbital decay in the double neutron star system PSR B2127+11C in the globular cluster M15. This has allowed an improved measurement of the mass of the pulsar, m p = (1.3584 +/- 0.0097) [Special characters omitted.] , and companion, m c = (1.3544 +/- 0.0097) [Special characters omitted.] , as well as a test of general relativity at the 3% level. We find that the proper motions of this pulsar as well as PSR B2127+11A and PSR B2127+11B are consistent with each other and with one published measurement of the cluster proper motion. We have discovered three binary millisecond pulsars in the globular cluster M62

  14. Green Science: Revisiting Recycling

    ERIC Educational Resources Information Center

    Palliser, Janna

    2011-01-01

    Recycling has been around for a long time--people have reused materials and refashioned them into needed items for thousands of years. More recently, war efforts encouraged conservation and reuse of materials, and in the 1970s recycling got its official start when recycling centers were created. Now, curbside recycling programs and recycling…

  15. Ammonia diffusion through Nalophan™ bags.

    PubMed

    Sironi, Selena; Eusebio, Lidia; Dentoni, Licinia; Capelli, Laura; Del Rosso, Renato

    2014-01-01

    The aim of the work is to verify the diffusion rate of ammonia through the Nalophan™ film that constitutes the sampling bag, considering storage times ranging from 1 to 26 h. The ammonia decay over time was evaluated using gas-chromatography for the quantification of ammonia concentration inside the bag. The research assesses the roles of both of ammonia and water concentration gradients at the polymeric film interface on the diffusion process. The results show that both the ammonia concentration gradient and, in a less pronounced way, the water concentration gradient are the main 'engines' of ammonia diffusion. Double bags seem to represent a simple solution for preventing ammonia losses during storage. Another interesting result concerns the role of the bag surface on the ammonia diffusion rate: the higher the surface/volume (S/V) ratio, the higher the ammonia diffusion rate through the polymeric film. PMID:24552718

  16. Generic rigidity percolation in two dimensions

    NASA Astrophysics Data System (ADS)

    Jacobs, D. J.; Thorpe, M. F.

    1996-04-01

    We study rigidity percolation for random central-force networks on the bondand site-diluted generic triangular lattice. Here, each site location is randomly displaced from the perfect lattice, removing any special symmetries. Using the pebble game algorithm, the total number of floppy modes are counted exactly, and exhibit a cusp singularity in the second derivative at the transition from a rigid to a floppy structure. The critical thresholds for bond and site dilution are found to be 0.66020+/-0.0003 and 0.69755+/-0.0003, respectively. The network is decomposed into unique rigid clusters, and we apply the usual percolation scaling theory. From finite size scaling, we find that the generic rigidity percolation transition is second order, but in a different universality class from connectivity percolation, with the exponents α=-0.48+/-0.05, β=0.175+/-0.02, and ν=1.21+/-0.06. The fractal dimension of the spanning rigid clusters and the spanning stressed regions at the critical threshold are found to be df=1.86+/-0.02 and dBB=1.80+/-0.03, respectively.

  17. Crossover from isotropic to directed percolation

    NASA Astrophysics Data System (ADS)

    Zhou, Zongzheng; Yang, Ji; Ziff, Robert M.; Deng, Youjin

    2012-08-01

    We generalize the directed percolation (DP) model by relaxing the strict directionality of DP such that propagation can occur in either direction but with anisotropic probabilities. We denote the probabilities as p↓=ppd and p↑=p(1-pd), with p representing the average occupation probability and pd controlling the anisotropy. The Leath-Alexandrowicz method is used to grow a cluster from an active seed site. We call this model with two main growth directions biased directed percolation (BDP). Standard isotropic percolation (IP) and DP are the two limiting cases of the BDP model, corresponding to pd=1/2 and pd=0,1 respectively. In this work, besides IP and DP, we also consider the 1/2percolation thresholds of the BDP model for pd=0.6 and 0.8, and determine various critical exponents. These exponents are found to be consistent with those for standard DP. We also determine the renormalization exponent associated with the asymmetric perturbation due to pd-1/2≠0 near IP, and confirm that such an asymmetric scaling field is relevant at IP.

  18. Crossover from isotropic to directed percolation.

    PubMed

    Zhou, Zongzheng; Yang, Ji; Ziff, Robert M; Deng, Youjin

    2012-08-01

    We generalize the directed percolation (DP) model by relaxing the strict directionality of DP such that propagation can occur in either direction but with anisotropic probabilities. We denote the probabilities as p(↓) = pp(d) and p(↑) = p(1-p(d)), with p representing the average occupation probability and p(d) controlling the anisotropy. The Leath-Alexandrowicz method is used to grow a cluster from an active seed site. We call this model with two main growth directions biased directed percolation (BDP). Standard isotropic percolation (IP) and DP are the two limiting cases of the BDP model, corresponding to p(d) =1/2 and p(d) = 0,1 respectively. In this work, besides IP and DP, we also consider the 1/2 < p(d) <1 region. Extensive Monte Carlo simulations are carried out on the square and the simple-cubic lattices, and the numerical data are analyzed by finite-size scaling. We locate the percolation thresholds of the BDP model for p(d) = 0.6 and 0.8, and determine various critical exponents. These exponents are found to be consistent with those for standard DP. We also determine the renormalization exponent associated with the asymmetric perturbation due to p(d)-1/2 ≠ 0 near IP, and confirm that such an asymmetric scaling field is relevant at IP. PMID:23005718

  19. Temporal percolation in activity-driven networks

    NASA Astrophysics Data System (ADS)

    Starnini, Michele; Pastor-Satorras, Romualdo

    2014-03-01

    We study the temporal percolation properties of temporal networks by taking as a representative example the recently proposed activity-driven-network model [N. Perra et al., Sci. Rep. 2, 469 (2012), 10.1038/srep00469]. Building upon an analytical framework based on a mapping to hidden variables networks, we provide expressions for the percolation time Tp marking the onset of a giant connected component in the integrated network. In particular, we consider both the generating function formalism, valid for degree-uncorrelated networks, and the general case of networks with degree correlations. We discuss the different limits of the two approaches, indicating the parameter regions where the correlated threshold collapses onto the uncorrelated case. Our analytical predictions are confirmed by numerical simulations of the model. The temporal percolation concept can be fruitfully applied to study epidemic spreading on temporal networks. We show in particular how the susceptible-infected-removed model on an activity-driven network can be mapped to the percolation problem up to a time given by the spreading rate of the epidemic process. This mapping allows us to obtain additional information on this process, not available for previous approaches.

  20. Percolation in a kinetic opinion exchange model

    NASA Astrophysics Data System (ADS)

    Chandra, Anjan Kumar

    2012-02-01

    We study the percolation transition of the geometrical clusters in the square-lattice LCCC model [a kinetic opinion exchange model introduced by Lallouache, Chakrabarti, Chakraborti, and Chakrabarti, Phys. Rev. EPLEEE81539-375510.1103/PhysRevE.82.056112 82, 056112 (2010)] with the change in conviction and influencing parameter. The cluster is comprised of the adjacent sites having an opinion value greater than or equal to a prefixed threshold value of opinion (Ω). The transition point is different from that obtained for the transition of the order parameter (average opinion value) found by Lallouache Although the transition point varies with the change in the threshold value of the opinion, the critical exponents for the percolation transition obtained from the data collapses of the maximum cluster size, the cluster size distribution, and the Binder cumulant remain the same. The exponents are also independent of the values of conviction and influencing parameters, indicating the robustness of this transition. The exponents do not match any other known percolation exponents (e.g., the static Ising, dynamic Ising, and standard percolation). This means that the LCCC model belongs to a separate universality class.

  1. Disinfection of secondary effluents by infiltration percolation.

    PubMed

    Makni, H

    2001-01-01

    Among the most attractive applications of reclaimed wastewater are: irrigation of public parks, sports fields, golf courses and market gardening. These uses require advanced wastewater treatment including disinfection. According to WHO guidelines (1989) and current rules and regulations in Tunisia, faecal coliform levels have to be reduced to < 10(3) or 10(2) CFU/100 mL. In Tunisia, most wastewater plants are only secondary treatment and, in order to meet health related regulations, the effluents need to be disinfected. However, it is usual for secondary effluents to need filtration prior to disinfection. Effectiveness of conventional disinfection processes, such as chlorination and UV radiation, are dependent upon the oxidation level and the levels of suspended solids of the treated water. Ozonation is relatively expensive and energy consuming. The consideration of the advantages and disadvantages of conventional techniques, their reliability, investment needs and operational costs will lead to the use of less sophisticated alternative techniques for certain facilities. Among alternative techniques, soil aquifer treatment and infiltration percolation through sand beds have been studied in Arizona, Israel, France, Spain and Morocco. Infiltration percolation plants have been intermittently fed with secondary or high quality primary effluents which percolated through 1.5-2 m unsaturated coarse sand and were recovered by under-drains. In such infiltration percolation facilities, microorganisms were eliminated through numerous physical, physicochemical and biological inter-related processes (mechanical filtration, adsorption and microbial degradation respectively). Efficiency of faecal coliform removal was dependent upon the water detention times in the filtering medium and on the oxidation of the filtered water. Effluents of Sfax town aerated ponds were infiltrated through 1.5 m deep sand columns in order to determine the performance of infiltration percolation in the

  2. Phase transitions in supercritical explosive percolation

    NASA Astrophysics Data System (ADS)

    Chen, Wei; Nagler, Jan; Cheng, Xueqi; Jin, Xiaolong; Shen, Huawei; Zheng, Zhiming; D'Souza, Raissa M.

    2013-05-01

    Percolation describes the sudden emergence of large-scale connectivity as edges are added to a lattice or random network. In the Bohman-Frieze-Wormald model (BFW) of percolation, edges sampled from a random graph are considered individually and either added to the graph or rejected provided that the fraction of accepted edges is never smaller than a decreasing function with asymptotic value of α, a constant. The BFW process has been studied as a model system for investigating the underlying mechanisms leading to discontinuous phase transitions in percolation. Here we focus on the regime α∈[0.6,0.95] where it is known that only one giant component, denoted C1, initially appears at the discontinuous phase transition. We show that at some point in the supercritical regime C1 stops growing and eventually a second giant component, denoted C2, emerges in a continuous percolation transition. The delay between the emergence of C1 and C2 and their asymptotic sizes both depend on the value of α and we establish by several techniques that there exists a bifurcation point αc=0.763±0.002. For α∈[0.6,αc), C1 stops growing the instant it emerges and the delay between the emergence of C1 and C2 decreases with increasing α. For α∈(αc,0.95], in contrast, C1 continues growing into the supercritical regime and the delay between the emergence of C1 and C2 increases with increasing α. As we show, αc marks the minimal delay possible between the emergence of C1 and C2 (i.e., the smallest edge density for which C2 can exist). We also establish many features of the continuous percolation of C2 including scaling exponents and relations.

  3. Anomalous critical and supercritical phenomena in explosive percolation

    NASA Astrophysics Data System (ADS)

    D'Souza, Raissa M.; Nagler, Jan

    2015-07-01

    The emergence of large-scale connectivity on an underlying network or lattice, the so-called percolation transition, has a profound impact on the system’s macroscopic behaviours. There is thus great interest in controlling the location of the percolation transition to either enhance or delay its onset and, more generally, in understanding the consequences of such control interventions. Here we review explosive percolation, the sudden emergence of large-scale connectivity that results from repeated, small interventions designed to delay the percolation transition. These transitions exhibit drastic, unanticipated and exciting consequences that make explosive percolation an emerging paradigm for modelling real-world systems ranging from social networks to nanotubes.

  4. Reversible first-order transition in Pauli percolation

    NASA Astrophysics Data System (ADS)

    Maksymenko, Mykola; Moessner, Roderich; Shtengel, Kirill

    2015-06-01

    Percolation plays an important role in fields and phenomena as diverse as the study of social networks, the dynamics of epidemics, the robustness of electricity grids, conduction in disordered media, and geometric properties in statistical physics. We analyze a new percolation problem in which the first-order nature of an equilibrium percolation transition can be established analytically and verified numerically. The rules for this site percolation model are physical and very simple, requiring only the introduction of a weight W (n )=n +1 for a cluster of size n . This establishes that a discontinuous percolation transition can occur with qualitatively more local interactions than in all currently considered examples of explosive percolation; and that, unlike these, it can be reversible. This greatly extends both the applicability of such percolation models in principle and their reach in practice.

  5. Reversible first-order transition in Pauli percolation.

    PubMed

    Maksymenko, Mykola; Moessner, Roderich; Shtengel, Kirill

    2015-06-01

    Percolation plays an important role in fields and phenomena as diverse as the study of social networks, the dynamics of epidemics, the robustness of electricity grids, conduction in disordered media, and geometric properties in statistical physics. We analyze a new percolation problem in which the first-order nature of an equilibrium percolation transition can be established analytically and verified numerically. The rules for this site percolation model are physical and very simple, requiring only the introduction of a weight W(n)=n+1 for a cluster of size n. This establishes that a discontinuous percolation transition can occur with qualitatively more local interactions than in all currently considered examples of explosive percolation; and that, unlike these, it can be reversible. This greatly extends both the applicability of such percolation models in principle and their reach in practice. PMID:26172657

  6. Liberation of ammonia by cyanobacteria

    SciTech Connect

    Newton, J.W.

    1986-04-01

    Photoheterotrophic nitrogen-fixing cyanobacteria release ammonia when treated with methionine sulfoximine (MSX) to inhibit nitrogen incorporation into protein. This released ammonia can be derived from recently fixed nitrogen (nitrogen atmosphere) or endogenous reserves (argon atmosphere). Anaerobic ammonia release requires light and is stimulated by the photosystem II herbicides DCMU and Atrazine, regardless of the source of ammonia. As much as one quarter of the total cellular nitrogen can be released as ammonia by cyanbacteria treated with MSX and DCMU under argon in light. Chromatography of cell extracts indicates that virtually all cellular proteins are degraded. DCMU and Atrazine, at very low concentration, inhibit sustained uptake of the ammonia analog /sup 14/C methylamine. These data indicate that the herbicides interrupt ammonia uptake and retention by the cells, and support a role for photosystem II in ammonia metabolism.

  7. The Ammonia-Soda Process.

    ERIC Educational Resources Information Center

    Tingle, M.

    1979-01-01

    This article is a condensed version of a commentary written to accompany a set of slides which describes the ammonia-soda process used by the ammonia-soda plant at Northwich of the United Kingdom. (HM)

  8. The Chemistry of Liquid Ammonia.

    ERIC Educational Resources Information Center

    Lagowski, J. J.

    1978-01-01

    The solvent and chemical properties of liquid ammonia are presented. In a certain sense, ammonia is a more versatile solvent than is water because of its ability to solubilize, without reaction, highly negative or reducing species. (Author/BB)

  9. Recycled Art: Create Puppets Using Recycled Objects.

    ERIC Educational Resources Information Center

    Clearing, 2003

    2003-01-01

    Presents an activity from "Healthy Foods from Healthy Soils" for making puppets using recycled food packaging materials. Includes background information, materials, instructions, literature links, resources, and benchmarks. (NB)

  10. Recycle Used Oil on America Recycles Day.

    ERIC Educational Resources Information Center

    White, Boyd W.

    2000-01-01

    Explains that motor oils can be reused and recycled. Educates students about environmental hazards and oil management and includes classroom activities. Addresses the National Science Education Standards. (YDS)

  11. Ammonia tank failure

    SciTech Connect

    Sweat, M.E.

    1983-04-01

    An ammonia tank failure at Hawkeye Chemical of Clinton, Iowa is discussed. The tank was a double-wall, 27,000 metric-ton tank built in 1968 and commissioned in December 1969. The paper presented covers the cause of the failure, repair, and procedural changes made to prevent recurrence of the failure. (JMT)

  12. On directed interacting animals and directed percolation

    NASA Astrophysics Data System (ADS)

    Knezevic, Milan; Vannimenus, Jean

    2002-03-01

    We study the phase diagram of fully directed lattice animals with nearest-neighbour interactions on the square lattice. This model comprises several interesting ensembles (directed site and bond trees, bond animals, strongly embeddable animals) as special cases and its collapse transition is equivalent to a directed bond percolation threshold. Precise estimates for the animal size exponents in the different phases and for the critical fugacities of these special ensembles are obtained from a phenomenological renormalization group analysis of the correlation lengths for strips of width up to n = 17. The crossover region in the vicinity of the collapse transition is analysed in detail and the crossover exponent φ is determined directly from the singular part of the free energy. We show using scaling arguments and an exact relation due to Dhar that φ is equal to the Fisher exponent σ governing the size distribution of large directed percolation clusters.

  13. Local Directed Percolation Probability in Two Dimensions

    NASA Astrophysics Data System (ADS)

    Inui, Norio; Konno, Norio; Komatsu, Genichi; Kameoka, Koichi

    1998-01-01

    Using the series expansion method and Monte Carlo simulation,we study the directed percolation probability on the square lattice Vn0=\\{ (x,y) \\in {Z}2:x+y=even, 0 ≤ y ≤ n, - y ≤ x ≤ y \\}.We calculate the local percolationprobability Pnl defined as the connection probability between theorigin and a site (0,n). The critical behavior of P∞lis clearly different from the global percolation probability P∞g characterized by a critical exponent βg.An analysis based on the Padé approximants shows βl=2βg.In addition, we find that the series expansion of P2nl can be expressed as a function of Png.

  14. Discontinuous percolation transitions in real physical systems

    NASA Astrophysics Data System (ADS)

    Cho, Y. S.; Kahng, B.

    2011-11-01

    We study discontinuous percolation transitions (PTs) in the diffusion-limited cluster aggregation model of the sol-gel transition as an example of real physical systems, in which the number of aggregation events is regarded as the number of bonds occupied in the system. When particles are Brownian, in which cluster velocity depends on cluster size as vs˜sη with η=-0.5, a larger cluster has less probability to collide with other clusters because of its smaller mobility. Thus, the cluster is effectively more suppressed in growth of its size. Then the giant cluster size increases drastically by merging those suppressed clusters near the percolation threshold, exhibiting a discontinuous PT. We also study the tricritical behavior by controlling the parameter η, and the tricritical point is determined by introducing an asymmetric Smoluchowski equation.

  15. Abrupt percolation in small equilibrated networks

    NASA Astrophysics Data System (ADS)

    Matsoukas, Themis

    2015-05-01

    Networks can exhibit an abrupt transition in the form of a spontaneous self-organization of a sizable fraction of the population into a giant component of connected members. This behavior has been demonstrated in random graphs under suppressive rules that passively or actively attempt to delay the formation of the giant cluster. We show that suppressive rules are not a necessary condition for a sharp transition at the percolation threshold. Rather, a finite system with aggressive tendency to form a giant cluster may exhibit an instability at the percolation threshold that is relieved through an abrupt and discontinuous transition to the stable branch. We develop the theory for a class of equilibrated networks that produce this behavior and find that the discontinuous jump is especially pronounced in small networks but disappears when the size of the system is infinite.

  16. Percolation in Self-Similar Networks

    NASA Astrophysics Data System (ADS)

    Serrano, M. Ángeles; Krioukov, Dmitri; Boguñá, Marián

    2011-01-01

    We provide a simple proof that graphs in a general class of self-similar networks have zero percolation threshold. The considered self-similar networks include random scale-free graphs with given expected node degrees and zero clustering, scale-free graphs with finite clustering and metric structure, growing scale-free networks, and many real networks. The proof and the derivation of the giant component size do not require the assumption that networks are treelike. Our results rely only on the observation that self-similar networks possess a hierarchy of nested subgraphs whose average degree grows with their depth in the hierarchy. We conjecture that this property is pivotal for percolation in networks.

  17. Modified Invasion Percolation Models for Multiphase Processes

    SciTech Connect

    Karpyn, Zuleima

    2015-01-31

    This project extends current understanding and modeling capabilities of pore-scale multiphase flow physics in porous media. High-resolution X-ray computed tomography imaging experiments are used to investigate structural and surface properties of the medium that influence immiscible displacement. Using experimental and computational tools, we investigate the impact of wetting characteristics, as well as radial and axial loading conditions, on the development of percolation pathways, residual phase trapping and fluid-fluid interfacial areas.

  18. Random fracture networks: percolation, geometry and flow

    NASA Astrophysics Data System (ADS)

    Adler, P. M.; Thovert, J. F.; Mourzenko, V. V.

    2015-12-01

    This paper reviews some of the basic properties of fracture networks. Most of the data can only be derived numerically, and to be useful they need to be rationalized, i.e., a large set of numbers should be replaced by a simple formula which is easy to apply for estimating orders of magnitude. Three major tools are found useful in this rationalization effort. First, analytical results can usually be derived for infinite fractures, a limit which corresponds to large densities. Second, the excluded volume and the dimensionless density prove crucial to gather data obtained at intermediate densities. Finally, shape factors can be used to further reduce the influence of fracture shapes. Percolation of fracture networks is of primary importance since this characteristic controls transport properties such as permeability. Recent numerical studies for various types of fracture networks (isotropic, anisotropic, heterogeneous in space, polydisperse, mixture of shapes) are summarized; the percolation threshold rho is made dimensionless by means of the excluded volume. A general correlation for rho is proposed as a function of the gyration radius. The statistical characteristics of the blocks which are cut in the solid matrix by the network are presented, since they control transfers between the porous matrix and the fractures. Results on quantities such as the volume, surface and number of faces are given and semi empirical relations are proposed. The possible intersection of a percolating network and of a cubic cavity is also summarized. This might be of importance for the underground storage of wastes. An approximate reasoning based on the excluded volume of the percolating cluster and of the cubic cavity is proposed. Finally, consequences on the permeability of fracture networks are briefly addressed. An empirical formula which verifies some theoretical properties is proposed.

  19. Generic Rigidity Percolation in Two Dimensions

    NASA Astrophysics Data System (ADS)

    Thorpe, M. F.; Jacobs, D. J.; Day, A. R.

    1996-03-01

    We study rigidity percolation for random central-force networks, using the Pebble Game(D. J. Jacobs and M. F. Thorpe, Phys. Rev. Letts. 75), 4051 (1995) algorithm on the bond and site diluted generic triangular lattice. Here, each site location is randomly displaced from the perfect lattice, removing any special symmetries. The total number of floppy modes are counted exactly, and exhibit a cusp singularity in the second derivative of the number of floppy modes, at the transition from a rigid to a floppy structure. The critical thresholds for bond and site dilution are found to be 0.6602 ± 0.0003 and 0.6976 ± 0.0003 respectively. We find that the generic rigidity percolation transition is second order, but in a different universality class than connectivity percolation, with the exponents; α = -0.48 ± 0.05 , β = 0.175 ± 0.02 and ν = 1.21 ± 0.06 . The fractal dimension of the spanning rigid clusters and the spanning stressed regions at the critical threshold are found to be df = 1.86 ± 0.02 and d_BB = 1.80 ± 0.03 respectively. Some elastic properties of the rigid backbone will be discussed.

  20. Percolation of networks with directed dependency links

    NASA Astrophysics Data System (ADS)

    Niu, Dunbiao; Yuan, Xin; Du, Minhui; Stanley, H. Eugene; Hu, Yanqing

    2016-04-01

    The self-consistent probabilistic approach has proven itself powerful in studying the percolation behavior of interdependent or multiplex networks without tracking the percolation process through each cascading step. In order to understand how directed dependency links impact criticality, we employ this approach to study the percolation properties of networks with both undirected connectivity links and directed dependency links. We find that when a random network with a given degree distribution undergoes a second-order phase transition, the critical point and the unstable regime surrounding the second-order phase transition regime are determined by the proportion of nodes that do not depend on any other nodes. Moreover, we also find that the triple point and the boundary between first- and second-order transitions are determined by the proportion of nodes that depend on no more than one node. This implies that it is maybe general for multiplex network systems, some important properties of phase transitions can be determined only by a few parameters. We illustrate our findings using Erdős-Rényi networks.

  1. Hidden percolation transition in kinetic replication process

    NASA Astrophysics Data System (ADS)

    Timonin, P. N.; Chitov, G. Y.

    2015-04-01

    The one-dimensional kinetic contact process with parallel update is introduced and studied by the mean-field approximation and Monte Carlo (MC) simulations. Contrary to a more conventional scenario with single active phase for 1d models with Ising-like variables, we find two different adjacent active phases in the parameter space of the proposed model with a second-order transition between them and a multiphase point where the active and the absorbing phases meet. While one of the active phases is quite standard with a smooth average filling of the space-time lattice, the second active phase demonstrates a very subtle (hidden) percolating order which becomes manifest only after certain transformation from the original model. We determine the percolation order parameter for active-active phase transition and discuss such hidden orders in other low-dimensional systems. Our MC data demonstrate finite-size critical and near-critical scaling of the order parameter relaxation for the two phase transitions. We find three independent critical indices for them and conclude that they both belong to the directed percolation universality class.

  2. Scaling properties of percolation models for multifragmentation

    NASA Astrophysics Data System (ADS)

    Ngô, H.; Ngô, C.; Ighezou, F. Z.; Desbois, J.; Leray, S.; Zheng, Y.-M.

    1990-03-01

    We have used scaling properties of nuclear multifragmentation, which have been observed with emulsion data, to investigate the properties of some approaches based on percolation. We have studied different percolation models on a cubic lattice and shown that they can rather well reproduce the data except for binary break up. We have described what the mean field approximation would give in this context and showed that it cannot reproduce the experimental results. Most of the paper is focused on the restructured aggregation model introduced earlier which allows to well reproduce the scaling properties observed experimentally. This model has been studied in details and extended to take account of bonds breaking. It is shown that, in some cases, a nucleus can break up in two pieces. This process cannot be obtained in conventional percolation or aggregation but is observed experimentally in the emulsion data. Other features like the dimensionality of the aggregation model, the restructuration of the clusters and a schematic constraint in momentum space have also been investigated.

  3. Percolation properties in a traffic model

    NASA Astrophysics Data System (ADS)

    Wang, Feilong; Li, Daqing; Xu, Xiaoyun; Wu, Ruoqian; Havlin, Shlomo

    2015-11-01

    As a dynamical complex system, traffic is characterized by a transition from free flow to congestions, which is mostly studied in highways. However, despite its importance in developing congestion mitigation strategies, the understanding of this common traffic phenomenon in a city scale is still missing. An open question is how the traffic in the network collapses from a global efficient traffic to isolated local flows in small clusters, i.e. the question of traffic percolation. Here we study the traffic percolation properties on a lattice by simulation of an agent-based model for traffic. A critical traffic volume in this model distinguishes the free state from the congested state of traffic. Our results show that the threshold of traffic percolation decreases with increasing traffic volume and reaches a minimum value at the critical traffic volume. We show that this minimal threshold is the result of longest spatial correlation between traffic flows at the critical traffic volume. These findings may help to develop congestion mitigation strategies in a network view.

  4. Recycling overview in Sweden

    SciTech Connect

    Not Available

    1989-07-01

    This article discusses the recycling programs currently in use in Sweden. Recycling of newspapers, batteries, plastics are all mentioned in this report by the Swedish Association of Public Cleansing and Solid Waste Management.

  5. Recycling Research. Tracking Trash.

    ERIC Educational Resources Information Center

    DeLago, Louise Furia

    1991-01-01

    An activity in which students research the effectiveness of recycling is presented. Students compare the types and amount of litter both before and after recycling is implemented. Directions for the activity and a sample data sheet are included. (KR)

  6. Topology of a percolating soil pore network

    NASA Astrophysics Data System (ADS)

    Capa-Morocho, M.; Ruiz-Ramos, M.; Hapca, S. M.; Houston, A.; Tarquis, A. M.

    2012-04-01

    A connectivity function defined by the 3D-Euler number, is a topological indicator and can be related to hydraulic properties (Vogel and Roth, 2001). This study aims to develop connectivity Euler indexes as indicators of the ability of soils for fluid percolation. The starting point was a 3D grey image acquired by X-ray computed tomography of a soil at bulk density of 1.2 mg cm-3. This image was used in the simulation of 40000 particles following a directed random walk algorithms with 7 binarization thresholds. These data consisted of 7 files containing the simulated end points of the 40000 random walks, obtained in Ruiz-Ramos et al. (2010). MATLAB software was used for computing the frequency matrix of the number of particles arriving at every end point of the random walks and their 3D representation. In a former work (Capa et al., 2011) a criteria for choosing the optimal threshold of grey value was identified: Final positions were divided in two subgroups, cg1 (positions with frequency of the number of particles received greater than the median) and cg2 (frequency lower or equal to median). Images with maximum difference between the Z coordinate of the center of gravity of both subgroups were selected as those with optimal threshold that reflects the major internal differences in soil structure that are relevant to percolation. According to this criterion, the optimal threshold for the soil with density 1.2 mg cm-3 was 24.Thresholds above and below the optimal (23 and 25) were also considered to confirm this selection; therefore the analysis were conducted for three files (1 image with 3 grey threshold values, which have different porosity). Additionally, three random matrix simulations with the same porosity than the selected binaries images were used to test the existence of pore connectivity as a consequence of a non-random soil structure. Therefore, 6 matrix were considered (three structured and three random) for this study. Random matrix presented a normal

  7. Percolation behavior in metallic-insulator composite systems and the filling factor near the percolation threshold

    NASA Astrophysics Data System (ADS)

    Mukherjee, Rupam; Mishra, Debabrata; Huang, Zhifeng; Nadgorny, Boris

    2012-10-01

    We investigate the percolation behavior in various composite metal -- insulator systems including LiCoO2/ CrO2, MgB2/Al2O3, CrO2/Al2O3, CrO2/ CaCO3. The effect of particle size and shapes in these systems has been studied to better understand the geometrical phase transitions. The power law exponent around the percolation threshold has been found to be 2.0±0.04 in all the cases, which agrees well with the theoretical result. Interestingly, the filling factor of these composite systems also exhibits the power law dependence near the percolation threshold with the value found to be dependent on the shape of the insulating particle. The exponent ranges from 0.2 to 0.4 depending on size of particles of a given shape in the composite system.

  8. Recycling and the automobile

    SciTech Connect

    Holt, D.J.

    1993-10-01

    This article examines the current status of automobile recycling and contains a summary of a survey which points out the major drivers and their impacts on automotive recycling. The topics of the article include computerized dismantling, polyurethane, sheet molding compound, polyester, thermoplastic polyester, recycling salvaged parts, vinyl and automotive shredder residue.

  9. The Sustainability of Recycling.

    ERIC Educational Resources Information Center

    Juniper, Christopher

    1993-01-01

    Describes the need for closing the business cycle in the recycling process. Discusses whether the government should mandate or the free market create uses for recycled products. Presents challenges associated with marketing recycled materials including what has been and what needs to be done to stimulate markets, encourage business, and balance…

  10. Rethink, Rework, Recycle.

    ERIC Educational Resources Information Center

    Wrhen, Linda; DiSpezio, Michael A.

    1991-01-01

    Information about the recycling and reuse of plastics, aluminum, steel, glass, and newspapers is presented. The phases of recycling are described. An activity that allows students to separate recyclable materials is included. The objectives, a list of needed materials, and procedure are provided. (KR)

  11. Exploring percolative landscapes: Infinite cascades of geometric phase transitions

    NASA Astrophysics Data System (ADS)

    Timonin, P. N.; Chitov, Gennady Y.

    2016-01-01

    The evolution of many kinetic processes in 1+1 (space-time) dimensions results in 2 D directed percolative landscapes. The active phases of these models possess numerous hidden geometric orders characterized by various types of large-scale and/or coarse-grained percolative backbones that we define. For the patterns originated in the classical directed percolation (DP) and contact process we show from the Monte Carlo simulation data that these percolative backbones emerge at specific critical points as a result of continuous phase transitions. These geometric transitions belong to the DP universality class and their nonlocal order parameters are the capacities of corresponding backbones. The multitude of conceivable percolative backbones implies the existence of infinite cascades of such geometric transitions in the kinetic processes considered. We present simple arguments to support the conjecture that such cascades of transitions are a generic feature of percolation as well as of many other transitions with nonlocal order parameters.

  12. Breaking of the site-bond percolation universality in networks

    PubMed Central

    Radicchi, Filippo; Castellano, Claudio

    2015-01-01

    The stochastic addition of either vertices or connections in a network leads to the observation of the percolation transition, a structural change with the appearance of a connected component encompassing a finite fraction of the system. Percolation has always been regarded as a substrate-dependent but model-independent process, in the sense that the critical exponents of the transition are determined by the geometry of the system, but they are identical for the bond and site percolation models. Here, we report a violation of such assumption. We provide analytical and numerical evidence of a difference in the values of the critical exponents between the bond and site percolation models in networks with null percolation thresholds, such as scale-free graphs with diverging second moment of the degree distribution. We discuss possible implications of our results in real networks, and provide additional insights on the anomalous nature of the percolation transition with null threshold. PMID:26667155

  13. Exploring percolative landscapes: Infinite cascades of geometric phase transitions.

    PubMed

    Timonin, P N; Chitov, Gennady Y

    2016-01-01

    The evolution of many kinetic processes in 1+1 (space-time) dimensions results in 2D directed percolative landscapes. The active phases of these models possess numerous hidden geometric orders characterized by various types of large-scale and/or coarse-grained percolative backbones that we define. For the patterns originated in the classical directed percolation (DP) and contact process we show from the Monte Carlo simulation data that these percolative backbones emerge at specific critical points as a result of continuous phase transitions. These geometric transitions belong to the DP universality class and their nonlocal order parameters are the capacities of corresponding backbones. The multitude of conceivable percolative backbones implies the existence of infinite cascades of such geometric transitions in the kinetic processes considered. We present simple arguments to support the conjecture that such cascades of transitions are a generic feature of percolation as well as of many other transitions with nonlocal order parameters. PMID:26871019

  14. Explosive site percolation and finite-size hysteresis

    NASA Astrophysics Data System (ADS)

    Bastas, Nikolaos; Kosmidis, Kosmas; Argyrakis, Panos

    2011-12-01

    We report the critical point for site percolation for the “explosive” type for two-dimensional square lattices using Monte Carlo simulations and compare it to the classical well-known percolation. We use similar algorithms as have been recently reported for bond percolation and networks. We calculate the explosive site percolation threshold as pc=0.695 and we find evidence that explosive site percolation surprisingly may belong to a different universality class than bond percolation on lattices, providing that the transitions (a) are continuous and (b) obey the conventional finite size scaling forms. Finally, we study and compare the direct and reverse processes, showing that while the reverse process is different from the direct process for finite size systems, the two cases become equivalent in the thermodynamic limit of large L.

  15. Percolation in a Proton Exchange Membrane Fuel Cell Catalyst Layer

    SciTech Connect

    Stacy, Stephen; Allen, Jeffrey

    2012-07-01

    Water management in the catalyst layers of proton exchange membrane fuel cells (PEMFC) is confronted by two issues, flooding and dry out, both of which result in improper functioning of the fuel cell and lead to poor performance and degradation. At the present time, the data that has been reported about water percolation and wettability within a fuel cell catalyst layer is limited. A method and apparatus for measuring the percolation pressure in the catalyst layer has been developed based upon an experimental apparatus used to test water percolation in porous transport layers (PTL). The experimental setup uses a pseudo Hele-Shaw type testing where samples are compressed and a fluid is injected into the sample. Testing the samples gives percolation pressure plots which show trends in increasing percolation pressure with an increase in flow rate. A decrease in pressure was seen as percolation occurred in one sample, however the pressure only had a rising effect in the other sample.

  16. Deformation-assisted fluid percolation in rock salt.

    PubMed

    Ghanbarzadeh, Soheil; Hesse, Marc A; Prodanović, Maša; Gardner, James E

    2015-11-27

    Deep geological storage sites for nuclear waste are commonly located in rock salt to ensure hydrological isolation from groundwater. The low permeability of static rock salt is due to a percolation threshold. However, deformation may be able to overcome this threshold and allow fluid flow. We confirm the percolation threshold in static experiments on synthetic salt samples with x-ray microtomography. We then analyze wells penetrating salt deposits in the Gulf of Mexico. The observed hydrocarbon distributions in rock salt require that percolation occurred at porosities considerably below the static threshold due to deformation-assisted percolation. Therefore, the design of nuclear waste repositories in salt should guard against deformation-driven fluid percolation. In general, static percolation thresholds may not always limit fluid flow in deforming environments. PMID:26612949

  17. Continuum percolation of carbon nanotubes in polymeric and colloidal media

    PubMed Central

    Kyrylyuk, Andriy V.; van der Schoot, Paul

    2008-01-01

    We apply continuum connectedness percolation theory to realistic carbon nanotube systems and predict how bending flexibility, length polydispersity, and attractive interactions between them influence the percolation threshold, demonstrating that it can be used as a predictive tool for designing nanotube-based composite materials. We argue that the host matrix in which the nanotubes are dispersed controls this threshold through the interactions it induces between them during processing and through the degree of connectedness that must be set by the tunneling distance of electrons, at least in the context of conductivity percolation. This provides routes to manipulate the percolation threshold and the level of conductivity in the final product. We find that the percolation threshold of carbon nanotubes is very sensitive to the degree of connectedness, to the presence of small quantities of longer rods, and to very weak attractive interactions between them. Bending flexibility or tortuosity, on the other hand, has only a fairly weak impact on the percolation threshold. PMID:18550818

  18. Ammonia capture and flexible transformation of M-2(INA) (M=Cu, Co, Ni, Cd) series materials.

    PubMed

    Chen, Yang; Li, Libo; Li, Jinping; Ouyang, Kun; Yang, Jiangfeng

    2016-04-01

    With the conflicting problems of pollution due to ammonia emissions and the demand for ammonia, we propose M-2(INA) (M=Cu, Co, Ni, Cd) (INA=isonicotinic acid), a series of materials that exhibit flexible conversion in ammonia adsorption. They can capture both wet and dry ammonia for recycling. The materials were obtained by dehydration of coordination materials M(INA)2(H2O)4 (M=Cu, Co, Ni, Cd) (150°C) at atmospheric pressure for 2h. M-2(INA) could reversibly transform to the stable coordination compounds M(INA)2(H2O)2(NH3)2 by adsorbing ammonia in the presence of moisture. The capacity for pure ammonia could reach 12-13mmol/g. Importantly, these materials could stably retain NH3 at a maximum temperature of 80°C and could regenerate below 150°C with no performance loss. PMID:26780590

  19. Oceanic emissions of ammonia

    NASA Astrophysics Data System (ADS)

    Paulot, F.; Jacob, D. J.; Johnson, M.; Bell, T. G.; Stock, C. A.; Doney, S. C.

    2013-12-01

    Half of natural ammonia (NH3) emissions is thought to originate from the oceans. Such large emissions have implications for the global budget of N and the acidity of marine aerosols. We develop two new inventories of oceanic NH3 emissions based on simulated monthly NH3 seawater concentrations from the GFDL-COBALT and the CESM-BEC ocean models. These new inventories explicitly account for the effect of temperature on the water-atmosphere exchange of NH3. We evaluate these inventory using cruise observations of gas-phase ammonia (AMT cruises) and ammonium (NOAA cruises) as well as seawater measurement of NHx. Implications of atmospheric NHx observations for the exchange of N between ocean and land and ocean N/P limitations are discussed.

  20. Crossover from percolation to self-organized criticality

    NASA Astrophysics Data System (ADS)

    Drossel, Barbara; Clar, Siegfried; Schwabl, Franz

    1994-10-01

    We include immunity against fire into the self-organized critical forest-fire model. When the immunity assumes a critical value, clusters of burnt trees are identical to percolation clusters of random bond percolation. As long as the immunity is below its critical value, the asymptotic critical exponents are those of the original self-organized critical model, i.e., the system performs a crossover from percolation to self-organized criticality. We present a scaling theory and computer simulation results.

  1. Industrial ammonia gassing

    PubMed Central

    Walton, M.

    1973-01-01

    Walton, M. (1972).British Journal of Industrial Medicine,30, 78-86. Industrial ammonia gassing. Seven cases of ammonia gassing are described with follow-up for five years of the six survivors and the post-mortem findings of the fatal case. All the survivors attributed continuing symptoms to the gassing. The study failed to demonstrate permanent ill effects in the one case of mild exposure. Of the more serious cases one has stopped smoking and taken up physical training teaching. He now has above average lung function. Two serious cases who continued to smoke have the lung function abnormalities expected from their smoking. In the other two seriously exposed cases, who also continued to smoke, there is a persistent reduction in ventilation and gas transfer which seems to be due to the ammonia gassing. The post-mortem findings in the fatal case showed acute congestion and oedema of the mucosa of the respiratory tract, the bronchial walls being stripped of their lining epithelium and the alveoli stuffed with red blood cells and oedema fluid. Images PMID:4685304

  2. Connectedness Percolation of Elongated Hard Particles in an External Field

    NASA Astrophysics Data System (ADS)

    Otten, Ronald H. J.; van der Schoot, Paul

    2012-02-01

    A theory is presented of how orienting fields and steric interactions conspire against the formation of a percolating network of, in some sense, connected elongated colloidal particles in fluid dispersions. We find that the network that forms above a critical loading breaks up again at higher loadings due to interaction-induced enhancement of the particle alignment. Upon approach of the percolation threshold, the cluster dimensions diverge with the same critical exponent parallel and perpendicular to the field direction, implying that connectedness percolation is not in the universality class of directed percolation.

  3. Recent advances in percolation theory and its applications

    NASA Astrophysics Data System (ADS)

    Saberi, Abbas Ali

    2015-05-01

    Percolation is the simplest fundamental model in statistical mechanics that exhibits phase transitions signaled by the emergence of a giant connected component. Despite its very simple rules, percolation theory has successfully been applied to describe a large variety of natural, technological and social systems. Percolation models serve as important universality classes in critical phenomena characterized by a set of critical exponents which correspond to a rich fractal and scaling structure of their geometric features. We will first outline the basic features of the ordinary model. Over the years a variety of percolation models has been introduced some of which with completely different scaling and universal properties from the original model with either continuous or discontinuous transitions depending on the control parameter, dimensionality and the type of the underlying rules and networks. We will try to take a glimpse at a number of selective variations including Achlioptas process, half-restricted process and spanning cluster-avoiding process as examples of the so-called explosive percolation. We will also introduce non-self-averaging percolation and discuss correlated percolation and bootstrap percolation with special emphasis on their recent progress. Directed percolation process will be also discussed as a prototype of systems displaying a nonequilibrium phase transition into an absorbing state. In the past decade, after the invention of stochastic Löwner evolution (SLE) by Oded Schramm, two-dimensional (2D) percolation has become a central problem in probability theory leading to the two recent Fields medals. After a short review on SLE, we will provide an overview on existence of the scaling limit and conformal invariance of the critical percolation. We will also establish a connection with the magnetic models based on the percolation properties of the Fortuin-Kasteleyn and geometric spin clusters. As an application we will discuss how percolation

  4. Connectedness percolation of elongated hard particles in an external field.

    PubMed

    Otten, Ronald H J; van der Schoot, Paul

    2012-02-24

    A theory is presented of how orienting fields and steric interactions conspire against the formation of a percolating network of, in some sense, connected elongated colloidal particles in fluid dispersions. We find that the network that forms above a critical loading breaks up again at higher loadings due to interaction-induced enhancement of the particle alignment. Upon approach of the percolation threshold, the cluster dimensions diverge with the same critical exponent parallel and perpendicular to the field direction, implying that connectedness percolation is not in the universality class of directed percolation. PMID:22463580

  5. Atmospheric dispersion of ammonia: an ammonia fog model

    SciTech Connect

    Kansa, E.J.; Rodean, H.C.; Chan, S.T.; Ermak, D.L.

    1983-01-01

    A simplification to the two-phase ammonia vapor-droplet fog problem has been implemented to study the dispersion of a spill of 40 tons of ammonia. We have circumvented the necessity of adding the partial differential equations for mass, momentum, and energy for the ammonia in the liquid phase by certain assumptions. It is assumed that the ammonia fog behaves as an ideal gas including the droplets. A temperature-dependent molecular weight was introduced to simulate the transition from a vapor-droplet cloud to a pure vapor cloud of ammonia. Likewise, the vaporization of ammonia was spread out over a temperature range. Mass, momentum, energy, and total ammonia is conserved rigorously. The observed features of the ammonia spill simulation have pointed out phenomena that could not be predicted in simpler calculations. Perhaps the most obvious feature is the cloud bifurcation due to the strength of the gravity current relative to the ambient wind. The gravity spreading of the denser ammonia fog significantly perturbs the unidirectional windfield in the vicinity of the spill, setting up complex eddy patterns in the cloud which are enhanced by ground heating and warm dry air entrainment. The lower concentrations appear to lift off by a buoyancy-induced flow. The ammonia cloud, rather than being cigar shaped as assumed in simpler models, ranges from pancake shaped to pear shaped, depending upon the ambient windfield. The fact that the ammonia cloud remains cold, very low, and wide is in qualitative agreement with some of the large-scale ammonia spill accidents. 14 figures.

  6. Recovery of ammonia nitrogen in livestock and industrial wastes using gas permeable membranes

    Technology Transfer Automated Retrieval System (TEKTRAN)

    New waste management methods are needed that can protect the environment and allow manure management to switch back to a recycling view of manure handling. We investigated the use of gas-permeable membranes as components of new processes to capture and recover the ammonia in the liquid manures or in...

  7. Epidemic Percolation Networks, Epidemic Outcomes, and Interventions

    DOE PAGESBeta

    Kenah, Eben; Miller, Joel C.

    2011-01-01

    Epidemic percolation networks (EPNs) are directed random networks that can be used to analyze stochastic “Susceptible-Infectious-Removed” (SIR) and “Susceptible-Exposed-Infectious-Removed” (SEIR) epidemic models, unifying and generalizing previous uses of networks and branching processes to analyze mass-action and network-based S(E)IR models. This paper explains the fundamental concepts underlying the definition and use of EPNs, using them to build intuition about the final outcomes of epidemics. We then show how EPNs provide a novel and useful perspective on the design of vaccination strategies.

  8. Percolation Theory and Modern Hydraulic Fracturing

    NASA Astrophysics Data System (ADS)

    Norris, J. Q.; Turcotte, D. L.; Rundle, J. B.

    2015-12-01

    During the past few years, we have been developing a percolation model for fracking. This model provides a powerful tool for understanding the growth and properties of the complex fracture networks generated during a modern high volume hydraulic fracture stimulations of tight shale reservoirs. The model can also be used to understand the interaction between the growing fracture network and natural reservoir features such as joint sets and faults. Additionally, the model produces a power-law distribution of bursts which can easily be compared to observed microseismicity.

  9. Epidemic percolation networks, epidemic outcomes, and interventions.

    PubMed

    Kenah, Eben; Miller, Joel C

    2011-01-01

    Epidemic percolation networks (EPNs) are directed random networks that can be used to analyze stochastic "Susceptible-Infectious-Removed" (SIR) and "Susceptible-Exposed-Infectious-Removed" (SEIR) epidemic models, unifying and generalizing previous uses of networks and branching processes to analyze mass-action and network-based S(E)IR models. This paper explains the fundamental concepts underlying the definition and use of EPNs, using them to build intuition about the final outcomes of epidemics. We then show how EPNs provide a novel and useful perspective on the design of vaccination strategies. PMID:21437002

  10. Tree structure of a percolating Universe.

    PubMed

    Colombi, S; Pogosyan, D; Souradeep, T

    2000-12-25

    We present a numerical study of topological descriptors of initially Gaussian and scale-free density perturbations evolving via gravitational instability in an expanding Universe. The measured Euler number of the excursion set at the percolation threshold, delta(c), is positive and nearly equal to the number of isolated components, suggesting that these structures are trees. Our study of critical point counts reconciles the clumpy appearance of the density field at delta(c) with measured filamentary local curvature. In the Gaussian limit, we measure delta(c)>sigma, where sigma2 is the variance of the density field. PMID:11136035

  11. Modied invasion percolation model for fracking

    NASA Astrophysics Data System (ADS)

    Norris, J.; Turcotte, D. L.; Rundle, J. B.

    2013-12-01

    Recent developments in hydraulic fracturing (fracking) have enabled the recovery of large reserves of natural gas and oil. These developments include a change from low-volume, high-viscosity fluid injection to high-volume, low-viscosity injection. We consider new models of Invasion Percolation, (IP) which are models that were originally introduced to represent the injection of an invading fluid into a fluid filled porous medium. A primary difference between our model and the original model is the elimination of any unbroken bonds whose end sites are both filled with fluid. While the original model was found to have statistics nearly identical to traditional percolation, we find significant statistical differences. In particular, the distribution of broken bond strengths displays a strong roll-over near the critical point. Another difference between traditional percolation clusters and clusters generated using our model is the absence of internal loops. The modified growth rule prevents the formation of internal loops making the growing cluster ramified. Other ramified networks include drainage basins and DLA clusters. The study of drainage basins led to the development of Horton-Strahler and Tokunaga network statistics. We used both Horton-Strahler and Tokunaga network statistics to characterize simulated clusters using and found that the clusters generated by our model are statistically self-similar fractals. In addition to fractal clusters, IP also displays burst dynamics, in which the cluster extends rapidly through a spontaneous extension of percolating bonds. We define a burst to be a consecutive series of broken bonds whose strengths are all below a specified value. Using this definition of bursts we found good agreement with a power-law frequency-area distribution. Our model displays many of the characteristics of an energy landscape, and shows many similarities to DLA, neural networks, ecological landscapes, and the world wide web. We anticipate that this

  12. Atmospheric dispersion of ammonia: an ammonia fog model

    SciTech Connect

    Kansa, E.J.; Ermak, D.L.

    1983-01-01

    Ammonia (NH/sub 3/), a by-product of many chemical processes, is widely used as a fertilizer and as a raw material for many chemical syntheses. The purpose of this paper is to discuss the atmospheric dispersion of ammonia resulting from a high pressure release. The resulting nature of the two-phase cloud of ammonia vapor and droplets has a significant effect on its dispersion characteristics. Our calculations of a 40 ton release show that even under moderately high wind conditions, the resulting ammonia cloud remains negatively buoyant for considerable distances downwind.

  13. Atmospheric dispersion of ammonia: an ammonia fog model

    SciTech Connect

    Kansa, E.J.; Ermak,D.L.

    1983-04-01

    Ammonia (NH/sub 3/), a by-product of many chemical processes, is widely used as a fertilizer and as a raw material for many chemical syntheses. The purpose of this paper is to discuss the atmospheric dispersion of ammonia resulting from a high pressure release. The resulting nature of the two-phase clouds of ammonia vapor and droplets has a significant effect on its dispersion characteristics. Our calculations of a 40 ton release show that even under moderately high wind conditions, the resulting ammonia cloud remains negatively buoyant for considerable distances downwind.

  14. Atmospheric dispersion of ammonia: an ammonia fog model

    SciTech Connect

    Kansa, E.J.; Ermak, D.L.; Chan, S.T.; Rodean, H.C.

    1983-07-01

    Ammonia (NH/sub 3/), a by-product of many chemical processes, is widely used as a fertilizer and as a raw material for many chemical syntheses. The purpose of this paper is to discuss the atmospheric dispersion of ammonia resulting from a high pressure release. The resulting nature of the two-phase cloud of ammonia vapor and droplets has a significant effect on its dispersion characteristics. Our calculations of a 40 ton release show that even under moderately high wind conditions, the resulting ammonia cloud remains negatively buoyant for considerable distances downwind. 10 references, 15 figures.

  15. Ammonia emissions from seabird colonies

    NASA Astrophysics Data System (ADS)

    Blackall, Trevor D.; Wilson, Linda J.; Theobald, Mark R.; Milford, Celia; Nemitz, Eiko; Bull, Jennifer; Bacon, Philip J.; Hamer, Keith C.; Wanless, Sarah; Sutton, Mark A.

    2007-05-01

    Ammonia emissions were measured from two entire seabird colonies with contrasting species assemblages, to ascertain the ammonia volatilisation potentials among seabird species in relation to their nesting behaviour. Emissions were calculated from downwind plume measurements of ammonia concentration using both inverse dispersion and tracer ratio methods. Measured colony emissions ranged 1-90 kg NH3 hour-1, and equated to 16 and 36% volatilization of excreted nitrogen for colonies dominated by ground/burrow nesting and bare rock nesting birds, respectively. The results were applied in a bioenergetics model with a global seabird database. Seabird colonies are found to represent the largest point sources of ammonia globally (up to ~6 Gg NH3 colony-1 year-1). Moreover the largest emissions occur mainly in remote environments with otherwise low NH3 emissions. These ammonia ``hot spots'' explain significant perturbations of the nitrogen cycle in these regions and add ~20% to oceanic ammonia emissions south of latitude 45°S.

  16. Removal of ammonia from contaminated air in a biotrickling filter - denitrifying bioreactor combination system.

    PubMed

    Sakuma, Takeyuki; Jinsiriwanit, Siriwat; Hattori, Toshihiro; Deshusses, Marc A

    2008-11-01

    The removal of gaseous ammonia in a system consisting of a biotrickling filter, a denitrification reactor and a polishing bioreactor for the trickling liquid was investigated. The system allowed sustained treatment of ammonia while preventing biological inhibition by accumulating nitrate and nitrite and avoiding generation of contaminated water. All bioreactors were packed with cattle bone composite ceramics, a porous support with a large interfacial area. Excellent removal of ammonia gas was obtained. The critical loading ranged from 60 to 120 gm(-3)h(-1) depending on the conditions, and loadings below 56 gm(-3)h(-1) resulted in essentially complete removal of ammonia. In addition, concentrations of ammonia, nitrite, nitrate and COD in the recycle liquid of the inlet and outlet of each reactor were measured to determine the fate of nitrogen in the reactor, close nitrogen balances and calculate nitrogen to COD ratios. Ammonia absorption and nitrification occurred in the biotrickling filter; nitrate and nitrite were biologically removed in the denitrification reactor and excess dissolved COD and ammonia were treated in the polishing bioreactor. Overall, ammonia gas was very successfully removed in the bioreactor system and steady state operation with respect to nitrogen species was achieved. PMID:18823641

  17. Bronchiectasis following pulmonary ammonia burn

    SciTech Connect

    Hoeffler, H.B.; Schweppe, H.I.; Greenberg, S.D.

    1982-12-01

    Long-term follow-up of the pulmonary lesions of severe exposure to ammonia in humans has seldom been documented, and development of bronchiectasis continues to be of concern. We studied a previously healthy 30-year-old woman whose lungs at time of necropsy, three years after massive exposure to ammonia fumes, had extensive cylindrical and saccular bronchiectasis. We concluded that massive exposure to ammonia can lead to bronchiectasis. It is not known, however, whether the bronchiectasis resulted from chemical injury by ammonia or from a superimposed bacterial bronchitis.

  18. Percolating plasmonic networks for light emission control.

    PubMed

    Gaio, Michele; Castro-Lopez, Marta; Renger, Jan; van Hulst, Niek; Sapienza, Riccardo

    2015-01-01

    Optical nanoantennas have revolutionised the way we manipulate single photons emitted by individual light sources in a nanostructured photonic environment. Complex plasmonic architectures allow for multiscale light control by shortening or stretching the light wavelength for a fixed operating frequency, meeting the size of the emitter and that of propagating modes. Here, we study self-assembled semi-continuous gold films and lithographic gold networks characterised by large local density of optical state (LDOS) fluctuations around the electrical percolation threshold, a regime where the surface is characterised by large metal clusters with fractal topology. We study the formation of plasmonic networks and their effect on light emission from embedded fluorescent probes in these systems. Through fluorescence dynamics experiments we discuss the role of global long-range interactions linked to the degree of percolation and to the network fractality, as well as the local near-field contributions coming from the local electro-magnetic fields and the topology. Our experiments indicate that local properties dominate the fluorescence modification. PMID:25711923

  19. Reionization through the lens of percolation theory

    NASA Astrophysics Data System (ADS)

    Furlanetto, Steven R.; Oh, S. Peng

    2016-04-01

    The reionization of intergalactic hydrogen has received intense theoretical scrutiny over the past two decades. Here, we approach the process formally as a percolation process and phase transition. Using semi-numeric simulations, we demonstrate that an infinitely large ionized region abruptly appears at an ionized fraction of xi ≈ 0.1 and quickly grows to encompass most of the ionized gas: by xi ˜ 0.3, nearly 90 per cent of the ionized material is part of this region. Throughout most of reionization, nearly all of the intergalactic medium is divided into just two regions, one ionized and one neutral, and both infinite in extent. We also show that the discrete ionized regions that exist before and near this transition point follow a near-power-law distribution in volume, with equal contributions to the total filling factor per logarithmic interval in size up to a sharp cutoff in volume. These qualities are generic to percolation processes, with the detailed behaviour a result of long-range correlations in the underlying density field. These insights will be crucial to understanding the distribution of ionized and neutral gas during reionization and provide precise meaning to the intuitive description of reionization as an `overlap' process.

  20. Spectral Dimension of a Percolation Network

    NASA Astrophysics Data System (ADS)

    Rudra, Jayanta

    2005-03-01

    While the fractal dimension df describes the self-similar static nature of the lattice, the spectral dimension ds dictates the dynamic properties on it. Alexander and Orbach^1 conjectured that the spectral dimension might be exactly 4/3 for percolation networks with embedding euclidian dimension de >= 2. Recent numerical simulations^2, however, could not decisively prove or disprove this conjecture, although there are other indirect evidences that it is true. We believe that the failure of the simulations to decisively check the validity of the conjecture is due to the non-stochastic nature of the methods. Most of these simulations are Monte Carlo Methods based on a random-walk model and, in spite of very large number of walks on huge lattices, the results do not reach the satisfactory level. In this work we apply a stochastic approach^3 to determine the spectral dimension of percolation network for de >= 2 and check the validity of the Alexander-Orbach-conjecture. Due to its stochastic nature this method is numerically superior and more accurate than the conventional Monte Carlo simulations. References: 1. S. Alexander and R. Orbach, J. Phys. Lett. (Paris) 43 (1982) L625. 2. N. Pitsianis, G. Bleris and P. Argyrakis, Phys. Rev. B 39 (1989) 7097. 3. J. Rudra and J. Kozak, Phys. Lett A 151 (1990) 429.

  1. Percolation experiments in complex fractal media

    NASA Astrophysics Data System (ADS)

    Redondo, Jose Manuel; Tarquis, Ana Maria; Cherubini, Claudia; Lopez Gzlez-Nieto, Pilar; Vila, Teresa

    2013-04-01

    Series of flow percolation experiments under gravity were performed in different glass model and real karstic media samples. We present a multifractal characterization of the experiments in several parametric non-dimensional flow descriptors. Using the maximum local multifractal dimension as an additional flow indicator. Also experiments on Non laminar flow and transport conditions in fractured and karstified media were performed at Bari. The investigation on hypothesis of non linear flow and non fickian transport in fractured aquifers led to a distinction on the different role of channels and microchannels and of the presence of vortices and eddy trapping. The dominance of the elongated channels produced early arrival times, with the solute traveling along the high velocity channel network. On the other hand in a lumped structured karstic media, the percolation flow produced long tails with local Eddy mixing, entrapment in eddies, and slow flow out of the eddies. In The laboratory experiments performed in Madrid and in DAMTP Cambridge the role of the initial pressure produced fractal pathway structures even in iniatilly uniform ballotini substrates.

  2. Explosive percolation transitions in growing networks

    NASA Astrophysics Data System (ADS)

    Oh, S. M.; Son, S.-W.; Kahng, B.

    2016-03-01

    Recent extensive studies of the explosive percolation (EP) model revealed that the EP transition is second order with an extremely small value of the critical exponent β associated with the order parameter. This result was obtained from static networks, in which the number of nodes in the system remains constant during the evolution of the network. However, explosive percolating behavior of the order parameter can be observed in social networks, which are often growing networks, where the number of nodes in the system increases as dynamics proceeds. However, extensive studies of the EP transition in such growing networks are still missing. Here we study the nature of the EP transition in growing networks by extending an existing growing network model to a general case in which m node candidates are picked up in the Achiloptas process. When m =2 , this model reduces to the existing model, which undergoes an infinite-order transition. We show that when m ≥3 , the transition becomes second order due to the suppression effect against the growth of large clusters. Using the rate-equation approach and performing numerical simulations, we also show that the exponent β decreases algebraically with increasing m , whereas it does exponentially in a corresponding static random network model. Finally, we find that the hyperscaling relations hold but in different forms.

  3. Electron Percolation In Copper Infiltrated Carbon

    NASA Astrophysics Data System (ADS)

    Krcho, Stanislav

    2015-11-01

    The work describes the dependence of the electrical conductivity of carbon materials infiltrated with copper in a vacuum-pressure autoclave on copper concentration and on the effective pore radius of the carbon skeleton. In comparison with non-infiltrated material the electrical conductivity of copper infiltrated composite increased almost 500 times. If the composite contained less than 7.2 vol% of Cu, a linear dependence of the electrical conductivity upon cupper content was observed. If infiltrated carbon contained more than 7.2 vol% of Cu, the dependence was nonlinear - the curve could be described by a power formula (x - xc)t. This is a typical formula describing the electron percolation process in regions containing higher Cu fraction than the critical one. The maximum measured electrical conductivity was 396 × 104 Ω-1 m-1 for copper concentration 27.6 vol%. Experiments and analysis of the electrical conductivity showed that electron percolation occurred in carbon materials infiltrated by copper when the copper volume exceeded the critical concentration. The analysis also showed a sharp increase of electrical conductivity in composites with copper concentration higher than the threshold, where the effective radius of carbon skeleton pores decreased to 350 nanometres.

  4. Novel percolation transitions and coupled catastrophes

    NASA Astrophysics Data System (ADS)

    D'Souza, Raissa

    Collections of interdependent networks are at the core of modern society, spanning physical, biological and social systems. Simple mathematical models of the structure and function of networks can provide important insights into real-world systems, enhancing our ability to steer and control them. Here our focus is on abrupt changes in networks, due both to phase transitions and to jumping between bi-stable equilibria. We begin with an overview of novel classes of percolation phase transitions that result from repeated, small interventions intended to delay the transition. These new phenomena allow us to extend percolation approaches to modular networks, Brownian motion, and cluster growth dynamics. We then focus on abrupt transitions due to a system jumping between bi-stable equilibria, modeled as a cusp catastrophe in nonlinear dynamics. We show that when systems that each undergo a cusp catastrophe interact, we can observe a new phenomena of catastrophe-hopping leading to non-local cascading failures. Here an intermediate system facilitates the propagation of a sudden change or collapse, and we show that catastrophe hopping is consistent with the outbreak of protests observed during the Arab Spring of 2011.

  5. Percolation on bipartite scale-free networks

    NASA Astrophysics Data System (ADS)

    Hooyberghs, H.; Van Schaeybroeck, B.; Indekeu, J. O.

    2010-08-01

    Recent studies introduced biased (degree-dependent) edge percolation as a model for failures in real-life systems. In this work, such process is applied to networks consisting of two types of nodes with edges running only between nodes of unlike type. Such bipartite graphs appear in many social networks, for instance in affiliation networks and in sexual-contact networks in which both types of nodes show the scale-free characteristic for the degree distribution. During the depreciation process, an edge between nodes with degrees k and q is retained with a probability proportional to (, where α is positive so that links between hubs are more prone to failure. The removal process is studied analytically by introducing a generating functions theory. We deduce exact self-consistent equations describing the system at a macroscopic level and discuss the percolation transition. Critical exponents are obtained by exploiting the Fortuin-Kasteleyn construction which provides a link between our model and a limit of the Potts model.

  6. Percolation effect in thick film superconductors

    SciTech Connect

    Sali, R.; Harsanyi, G.

    1994-12-31

    A thick film superconductor paste has been developed to study the properties of granulated superconductor materials, to observe the percolation effect and to confirm the theory of the conducting mechanism in the superconducting thick films. This paste was also applied to make a superconducting planar transformer. Due to high T{sub c} and advantageous current density properties the base of the paste was chosen to be of Bi(Pb)SrCaCuO system. For contacts a conventional Ag/Pt paste was used. The critical temperature of the samples were between 110 K and 115 K depending on the printed layer thickness. The critical current density at the boiling temperature of the liquid He- was between 200-300 A/cm{sup 2}. The R(T) and V(I) functions were measured with different parameters. The results of the measurements have confirmed the theory of conducting mechanism in the material. The percolation structure model has been built and described. As an application, a superconducting planar thick film transformer was planned and produced. Ten windings of the transformer were printed on one side of the alumina substrate and one winding was printed on the other side. The coupling between the two sides was possible through the substrate. The samples did not need special drying and firing parameters. After the preparation, the properties of the transformer were measured. The efficiency and the losses were determined. Finally, some fundamental advantages and problems of the process were discussed.

  7. Explosive percolation transitions in growing networks.

    PubMed

    Oh, S M; Son, S-W; Kahng, B

    2016-03-01

    Recent extensive studies of the explosive percolation (EP) model revealed that the EP transition is second order with an extremely small value of the critical exponent β associated with the order parameter. This result was obtained from static networks, in which the number of nodes in the system remains constant during the evolution of the network. However, explosive percolating behavior of the order parameter can be observed in social networks, which are often growing networks, where the number of nodes in the system increases as dynamics proceeds. However, extensive studies of the EP transition in such growing networks are still missing. Here we study the nature of the EP transition in growing networks by extending an existing growing network model to a general case in which m node candidates are picked up in the Achiloptas process. When m = 2, this model reduces to the existing model, which undergoes an infinite-order transition. We show that when m ≥ 3, the transition becomes second order due to the suppression effect against the growth of large clusters. Using the rate-equation approach and performing numerical simulations, we also show that the exponent β decreases algebraically with increasing m, whereas it does exponentially in a corresponding static random network model. Finally, we find that the hyperscaling relations hold but in different forms. PMID:27078375

  8. Compact directed percolation with movable partial reflectors

    NASA Astrophysics Data System (ADS)

    Dickman, Ronald; ben-Avraham, Daniel

    2002-09-01

    We study a version of compact directed percolation (CDP) in one dimension in which occupation of a site for the first time requires that a 'mine' or an antiparticle be eliminated. This process is analogous to the variant of directed percolation with a long-time memory, proposed by Grassberger et al (1997 Phys. Rev. E 55 2488) in order to understand spreading at a critical point involving an infinite number of absorbing configurations. The problem is equivalent to that of a pair of random walkers in the presence of movable partial reflectors. The walkers, which are unbiased, start one lattice spacing apart and annihilate on their first contact. Each time one of the walkers tries to visit a new site, it is reflected (with probability r) back to its previous position, while the reflector is simultaneously pushed one step away from the walker. Iteration of the discrete-time evolution equation for the probability distribution yields the survival probability S(t). We find that S(t) ~ t-δ, with δ varying continuously between 1/2 and 1.160 as the reflection probability varies between 0 and 1.

  9. Electrically Percolating Clusters in Sheared Carbon Nanotube Composites

    NASA Astrophysics Data System (ADS)

    Migler, Kalman; Moon, Doyoung; Obrzut, Jan; Douglas, Jack; Lam, Thomas; Sharma, Renu; Liddle, Alex James

    2013-03-01

    The electrical conductivity of polymer nanotube composites can be dramatically modified by processing flows and subsequent annealing. The mechanism is widely believed to be nanotube structural rearrangements that occur during flow and alter the percolating pathways. We seek to directly visualize these flow-induced three-dimensional percolating clusters through three-dimensional confocal microscopy and image analysis.

  10. Benchmarking survey for recycling.

    SciTech Connect

    Marley, Margie Charlotte; Mizner, Jack Harry

    2005-06-01

    This report describes the methodology, analysis and conclusions of a comparison survey of recycling programs at ten Department of Energy sites including Sandia National Laboratories/New Mexico (SNL/NM). The goal of the survey was to compare SNL/NM's recycling performance with that of other federal facilities, and to identify activities and programs that could be implemented at SNL/NM to improve recycling performance.

  11. Charge percolation pathways guided by defects in quantum dot solids.

    PubMed

    Zhang, Yingjie; Zherebetskyy, Danylo; Bronstein, Noah D; Barja, Sara; Lichtenstein, Leonid; Schuppisser, David; Wang, Lin-Wang; Alivisatos, A Paul; Salmeron, Miquel

    2015-05-13

    Charge hopping and percolation in quantum dot (QD) solids has been widely studied, but the microscopic nature of the percolation process is not understood or determined. Here we present the first imaging of the charge percolation pathways in two-dimensional PbS QD arrays using Kelvin probe force microscopy (KPFM). We show that under dark conditions electrons percolate via in-gap states (IGS) instead of the conduction band, while holes percolate via valence band states. This novel transport behavior is explained by the electronic structure and energy level alignment of the individual QDs, which was measured by scanning tunneling spectroscopy (STS). Chemical treatments with hydrazine can remove the IGS, resulting in an intrinsic defect-free semiconductor, as revealed by STS and surface potential spectroscopy. The control over IGS can guide the design of novel electronic devices with impurity conduction, and photodiodes with controlled doping. PMID:25844919

  12. Percolation in one of q colors near criticality

    NASA Astrophysics Data System (ADS)

    Qian, Xiaofeng; Deng, Youjin; Blöte, Henk W. J.

    2005-04-01

    We study bond percolation in two dimensions between random site variables having one out of q colors, using transfer-matrix and Monte Carlo techniques. We determine the percolation threshold as a function of the Potts temperature T in the disordered Potts range Tc⩽T<∞ for several q -state Potts Hamiltonians. For high T , these transitions fit, irrespective of q , in the universality class of the ordinary percolation transitions. However, for T↓Tc , q -dependent crossover phenomena appear. The topology of the phase diagram changes in a qualitative sense at q=2 . For q<2 the Potts critical state appears to enhance percolation, for q>2 it appears to suppress it. Remarkably, for q=2 the percolation line coincides with the only flow line extending to T>Tc from the critical fixed point associated with Potts clusters.

  13. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  14. Ammonia plant designers talk of big energy savings

    SciTech Connect

    Axelrod, L.C.

    1980-08-27

    The ammonia plant that Pullman Kellogg has designed for Sherritt-Gordon Mines Ltd. in Alberta will require < 27 million Btu/ton of ammonia, and save $8.10/ton in energy costs because of improvements involving increased pressure in the primary reformer; more efficient use of the heat from the secondary reformer; carbon dioxide recovery by Allied Chemical Corp.'s Selexol process; the reduction of power requirements in the synthesis recycle loop; and the use of a horizontal reactor. C. F. Braun and Co. claims that its Purifier process will require < 25 million Btu/ton, due to the use of excess air in the secondary reformer. C-E Lummus offers a 1500 ton/day plant which, incorporating cryogenic recovery of hydrogen from purge gas and operation at a lower steam-to-carbon ratio, would require only 26 million Btu/ton; Haldor Topsoe Inc. offers a design rated at 26.3 million Btu/ton. According to L. C. Axelrod of Pullman Kellogg, ammonia plant construction will shift to gas-rich areas outside the U.S. and Europe. The 3% of the U.S. natural gas used by the fertilizer industry accounts for > 95% of ammonia feedstock.

  15. Ammonia caramels: specifications and analysis.

    PubMed

    Patey, A L; Shearer, G; Knowles, M E; Denner, W H

    1985-01-01

    Twenty three UK commercially produced ammonia caramels and eight experimentally produced ammonia caramels have been analysed by a range of physical and chemical tests, which include solids content, nitrogen levels, colour intensity and pH. A statistical treatment of the results is reported. PMID:4018316

  16. Process for removal of ammonia and acid gases from contaminated waters

    DOEpatents

    King, C.J.; Mackenzie, P.D.

    1982-09-03

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  17. Process for removal of ammonia and acid gases from contaminated waters

    DOEpatents

    King, C. Judson; MacKenzie, Patricia D.

    1985-01-01

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  18. Recovery and removal of nutrients from swine wastewater by using a novel integrated reactor for struvite decomposition and recycling

    PubMed Central

    Huang, Haiming; Xiao, Dean; Liu, Jiahui; Hou, Li; Ding, Li

    2015-01-01

    In the present study, struvite decomposition was performed by air stripping for ammonia release and a novel integrated reactor was designed for the simultaneous removal and recovery of total ammonia-nitrogen (TAN) and total orthophosphate (PT) from swine wastewater by internal struvite recycling. Decomposition of struvite by air stripping was found to be feasible. Without supplementation with additional magnesium and phosphate sources, the removal ratio of TAN from synthetic wastewater was maintained at >80% by recycling of the struvite decomposition product formed under optimal conditions, six times. Continuous operation of the integrated reactor indicated that approximately 91% TAN and 97% PT in the swine wastewater could be removed and recovered by the proposed recycling process with the supplementation of bittern. Economic evaluation of the proposed system showed that struvite precipitation cost can be saved by approximately 54% by adopting the proposed recycling process in comparison with no recycling method. PMID:25960246

  19. Recovery and removal of nutrients from swine wastewater by using a novel integrated reactor for struvite decomposition and recycling

    NASA Astrophysics Data System (ADS)

    Huang, Haiming; Xiao, Dean; Liu, Jiahui; Hou, Li; Ding, Li

    2015-05-01

    In the present study, struvite decomposition was performed by air stripping for ammonia release and a novel integrated reactor was designed for the simultaneous removal and recovery of total ammonia-nitrogen (TAN) and total orthophosphate (PT) from swine wastewater by internal struvite recycling. Decomposition of struvite by air stripping was found to be feasible. Without supplementation with additional magnesium and phosphate sources, the removal ratio of TAN from synthetic wastewater was maintained at >80% by recycling of the struvite decomposition product formed under optimal conditions, six times. Continuous operation of the integrated reactor indicated that approximately 91% TAN and 97% PT in the swine wastewater could be removed and recovered by the proposed recycling process with the supplementation of bittern. Economic evaluation of the proposed system showed that struvite precipitation cost can be saved by approximately 54% by adopting the proposed recycling process in comparison with no recycling method.

  20. Clarification of the Bootstrap Percolation Paradox

    NASA Astrophysics Data System (ADS)

    de Gregorio, Paolo; Lawlor, Aonghus; Bradley, Phil; Dawson, Kenneth A.

    2004-07-01

    We study the onset of the bootstrap percolation transition as a model of generalized dynamical arrest. Our results apply to two dimensions, but there is no significant barrier to extending them to higher dimensionality. We develop a new importance-sampling procedure in simulation, based on rare events around “holes”, that enables us to access bootstrap lengths beyond those previously studied. By framing a new theory in terms of paths or processes that lead to emptying of the lattice we are able to develop systematic corrections to the existing theory and compare them to simulations. Thereby, for the first time in the literature, it is possible to obtain credible comparisons between theory and simulation in the accessible density range.

  1. Percolation and permeability of heterogeneous fracture networks

    NASA Astrophysics Data System (ADS)

    Adler, Pierre; Mourzenko, Valeri; Thovert, Jean-François

    2013-04-01

    Natural fracture fields are almost necessarily heterogeneous with a fracture density varying with space. Two classes of variations are quite frequent. In the first one, the fracture density is decreasing from a given surface; the fracture density is usually (but not always see [1]) an exponential function of depth as it has been shown by many measurements. Another important example of such an exponential decrease consists of the Excavated Damaged Zone (EDZ) which is created by the excavation process of a gallery [2,3]. In the second one, the fracture density undergoes some local random variations around an average value. This presentation is mostly focused on the first class and numerical samples are generated with an exponentially decreasing density from a given plane surface. Their percolation status and hydraulic transmissivity can be calculated by the numerical codes which are detailed in [4]. Percolation is determined by a pseudo diffusion algorithm. Flow determination necessitates the meshing of the fracture networks and the discretisation of the Darcy equation by a finite volume technique; the resulting linear system is solved by a conjugate gradient algorithm. Only the flow properties of the EDZ along the directions which are parallel to the wall are of interest when a pressure gradient parallel to the wall is applied. The transmissivity T which relates the total flow rate per unit width Q along the wall through the whole fractured medium to the pressure gradient grad p, is defined by Q = - T grad p/mu where mu is the fluid viscosity. The percolation status and hydraulic transmissivity are systematically determined for a wide range of decay lengths and anisotropy parameters. They can be modeled by comparison with anisotropic fracture networks with a constant density. A heuristic power-law model is proposed which accurately describes the results for the percolation threshold over the whole investigated range of heterogeneity and anisotropy. Then, the data

  2. Percolation of localized attack on complex networks

    NASA Astrophysics Data System (ADS)

    Shao, Shuai; Huang, Xuqing; Stanley, H. Eugene; Havlin, Shlomo

    2015-02-01

    The robustness of complex networks against node failure and malicious attack has been of interest for decades, while most of the research has focused on random attack or hub-targeted attack. In many real-world scenarios, however, attacks are neither random nor hub-targeted, but localized, where a group of neighboring nodes in a network are attacked and fail. In this paper we develop a percolation framework to analytically and numerically study the robustness of complex networks against such localized attack. In particular, we investigate this robustness in Erdős-Rényi networks, random-regular networks, and scale-free networks. Our results provide insight into how to better protect networks, enhance cybersecurity, and facilitate the design of more robust infrastructures.

  3. Percolation of Blast Waves though Sand

    NASA Astrophysics Data System (ADS)

    Proud, William

    2013-06-01

    Previous research has concentrated on the physical processes occurring when samples of sand, of varying moisture content, were shock compressed. In this study quartz sand samples are subjected to blast waves over a range of pressure and duration. Aspects of particle movement are discussed; the global movement of a bed hundreds of particles thick is a fraction of particle width. The main diagnostics used are pressure sensors and high-speed photography. Results are presented for a range of particle sizes, aspect ratio, density and moisture content. While the velocity of the percolation through the bed is primarily controlled by density and porosity the effect of moisture reveals a more complex dependence. The ISP acknowledges the support of the Atomic Weapons Establishment and Imperial College London.

  4. A Percolation Model of the Streamer Discharges

    NASA Astrophysics Data System (ADS)

    Sasaki, Akira; Kato, Susumu; Takahashi, Eiichi; Kanazawa, Seiji

    A percolation model of discharge is presented. The model can reproduce stochastic behaviors of initial partial discharge to the growth of a stepped leader. The model uses macroscopic cells, from which a network of electric circuits is defined, and the spatial and temporal evolutions of the electric field and current in the discharge medium are calculated. For each cell, one of two states, either insulator or conductor, which corresponds to neutral gas or ionized plasmas, respectively, is decided. The decision is made on the basis of probability for each calculation cell at each time step, taking the effects of local electric field and current, which enhance ionization and sustain the discharge channel, respectively, into account.

  5. Explosive Percolation with Multiple Giant Components

    NASA Astrophysics Data System (ADS)

    Chen, Wei; D'Souza, Raissa M.

    2011-03-01

    We generalize the random graph evolution process of Bohman, Frieze, and Wormald [T. Bohman, A. Frieze, and N. C. Wormald, Random Struct. AlgorithmsRSALFD1042-983210.1002/rsa.20038, 25, 432 (2004)]. Potential edges, sampled uniformly at random from the complete graph, are considered one at a time and either added to the graph or rejected provided that the fraction of accepted edges is never smaller than a decreasing function asymptotically approaching the value α=1/2. We show that multiple giant components appear simultaneously in a strongly discontinuous percolation transition and remain distinct. Furthermore, tuning the value of α determines the number of such components with smaller α leading to an increasingly delayed and more explosive transition. The location of the critical point and strongly discontinuous nature are not affected if only edges which span components are sampled.

  6. Temporal percolation of a susceptible adaptive network

    NASA Astrophysics Data System (ADS)

    Valdez, L. D.; Macri, P. A.; Braunstein, L. A.

    2013-09-01

    In the past decades, many authors have used the susceptible-infected-recovered model to study the impact of the disease spreading on the evolution of the infected individuals. However, few authors focused on the temporal unfolding of the susceptible individuals. In this paper, we study the dynamic of the susceptible-infected-recovered model in an adaptive network that mimics the transitory deactivation of permanent social contacts, such as friendship and work-ship ties. Using an edge-based compartmental model and percolation theory, we obtain the evolution equations for the fraction susceptible individuals in the susceptible biggest component. In particular, we focus on how the individual’s behavior impacts on the dilution of the susceptible network. We show that, as a consequence, the spreading of the disease slows down, protecting the biggest susceptible cluster by increasing the critical time at which the giant susceptible component is destroyed. Our theoretical results are fully supported by extensive simulations.

  7. Renal Ammonia Metabolism and Transport

    PubMed Central

    Weiner, I. David; Verlander, Jill W.

    2015-01-01

    Renal ammonia metabolism and transport mediates a central role in acid-base homeostasis. In contrast to most renal solutes, the majority of renal ammonia excretion derives from intrarenal production, not from glomerular filtration. Renal ammoniagenesis predominantly results from glutamine metabolism, which produces 2 NH4+ and 2 HCO3− for each glutamine metabolized. The proximal tubule is the primary site for ammoniagenesis, but there is evidence for ammoniagenesis by most renal epithelial cells. Ammonia produced in the kidney is either excreted into the urine or returned to the systemic circulation through the renal veins. Ammonia excreted in the urine promotes acid excretion; ammonia returned to the systemic circulation is metabolized in the liver in a HCO3−-consuming process, resulting in no net benefit to acid-base homeostasis. Highly regulated ammonia transport by renal epithelial cells determines the proportion of ammonia excreted in the urine versus returned to the systemic circulation. The traditional paradigm of ammonia transport involving passive NH3 diffusion, protonation in the lumen and NH4+ trapping due to an inability to cross plasma membranes is being replaced by the recognition of limited plasma membrane NH3 permeability in combination with the presence of specific NH3-transporting and NH4+-transporting proteins in specific renal epithelial cells. Ammonia production and transport are regulated by a variety of factors, including extracellular pH and K+, and by several hormones, such as mineralocorticoids, glucocorticoids and angiotensin II. This coordinated process of regulated ammonia production and transport is critical for the effective maintenance of acid-base homeostasis. PMID:23720285

  8. AIRCRAFT INDUSTRY WASTEWATER RECYCLING

    EPA Science Inventory

    The feasibility of recycling certain categories of water used in the manufacture of airplanes was demonstrated. Water in four categories was continuously recycled in 380-liter (100-gallon) treatment plants; chemical process rinse water, dye-penetrant crack-detection rinse water, ...

  9. Wee Recyclers Resources.

    ERIC Educational Resources Information Center

    Wisconsin State Dept. of Natural Resources, Madison.

    Hands-on activities in this guide are designed to help preschool children (ages 3-5) understand that reducing, reusing, and recycling preserves natural resources and prolongs the life of landfills. Children sort, match and compare recyclable items and learn to separate some items by number and color. The 29 activities are divided into units that…

  10. The Fermilab recycler ring

    SciTech Connect

    Martin Hu

    2001-07-24

    The Fermilab Recycler is a permanent magnet storage ring for the accumulation of antiprotons from the Antiproton Source, and the recovery and cooling of the antiprotons remaining at the end of a Tevatron store. It is an integral part of the Fermilab III luminosity upgrade. The following paper describes the design features, operational and commissioning status of the Recycler Ring.

  11. Carbon dioxide recycling

    EPA Science Inventory

    The recycling of carbon dioxide to methanol and dimethyl ether is seen to offer a substantial route to renewable and environmentally carbon neutral fuels. One of the authors has championed the “Methanol Economy" in articles and a book. By recycling ambient CO2, the authors argue ...

  12. Design for aluminum recycling

    SciTech Connect

    Not Available

    1993-10-01

    This article describes the increasing use of aluminum in automobiles and the need to recycle to benefit further growth of aluminum applications by assuring an economical, high-quality source of metal. The article emphasizes that coordination of material specifications among designers can raise aluminum scrap value and facilitate recycling. Applications of aluminum in automobile construction are discussed.

  13. Reuse, Reduce, Recycle.

    ERIC Educational Resources Information Center

    Briscoe, Georgia

    1991-01-01

    Discussion of recycling paper in law libraries is also applicable to other types of libraries. Results of surveys of law libraries that investigated recycling practices in 1987 and again in 1990 are reported, and suggestions for reducing the amount of paper used and reusing as much as possible are offered. (LRW)

  14. Recycling at Camp.

    ERIC Educational Resources Information Center

    Cummins, William M.

    1988-01-01

    Outlines a Michigan summer camp's efforts to reduce solid waste disposal by recycling cardboard, tin, glass, aluminum, and plastic milk containers. Points out variables affecting the success of such efforts. Discusses Michigan state funding for the development of recycling programs. (SV)

  15. Percolation in binary and ternary mixtures of patchy colloids.

    PubMed

    Seiferling, Felix; de Las Heras, Daniel; Telo da Gama, Margarida M

    2016-08-21

    We investigate percolation in binary and ternary mixtures of patchy colloidal particles theoretically and using Monte Carlo simulations. Each particle has three identical patches, with distinct species having different types of patch. Theoretically we assume tree-like clusters and calculate the bonding probabilities using Wertheim's first-order perturbation theory for association. For ternary mixtures, we find up to eight fundamentally different percolated states. The states differ in terms of the species and pairs of species that have percolated. The strongest gel is a trigel or tricontinuous gel, in which each of the three species has percolated. The weakest gel is a mixed gel in which all of the particles have percolated, but none of the species percolates by itself. The competition between entropy of mixing and internal energy of bonding determines the stability of each state. Theoretical and simulation results are in very good agreement. The only significant difference is the temperature at the percolation threshold, which is overestimated by the theory due to the absence of correlations between bonds in the theoretical description. PMID:27544122

  16. Multiple percolation tunneling staircase in metal-semiconductor nanoparticle composites

    SciTech Connect

    Mukherjee, Rupam; Huang, Zhi-Feng; Nadgorny, Boris

    2014-10-27

    Multiple percolation transitions are observed in a binary system of RuO{sub 2}-CaCu{sub 3}Ti{sub 4}O{sub 12} metal-semiconductor nanoparticle composites near percolation thresholds. Apart from a classical percolation transition, associated with the appearance of a continuous conductance path through RuO{sub 2} metal oxide nanoparticles, at least two additional tunneling percolation transitions are detected in this composite system. Such behavior is consistent with the recently emerged picture of a quantum conductivity staircase, which predicts several percolation tunneling thresholds in a system with a hierarchy of local tunneling conductance, due to various degrees of proximity of adjacent conducting particles distributed in an insulating matrix. Here, we investigate a different type of percolation tunneling staircase, associated with a more complex conductive and insulating particle microstructure of two types of non-spherical constituents. As tunneling is strongly temperature dependent, we use variable temperature measurements to emphasize the hierarchical nature of consecutive tunneling transitions. The critical exponents corresponding to specific tunneling percolation thresholds are found to be nonuniversal and temperature dependent.

  17. Modeling of heat generation in ammonia-treated solid rocket propellant

    SciTech Connect

    Raun, R.L.; Isom, K.B.

    1995-06-01

    With the end of the Cold War, safe, environmentally sound separation, recycling, and disposal of ingredients in solid rocket propellants and munitions has become a national priority. One approach to demilitarize solid rocket propellants is treatment with ammonia. Ammonia extracts the oxidizers ammonium perchlorate and HMX, yielding a solid reside that is more suitable for incineration and less sensitive to impact and other modes of accidental initiation. Ammonia treatment of nitroglycerin-containing propellants is complicated by an exothermic reaction between ammonia and nitroglycerin. If not removed, the heat generated by this reaction can cause propellant ignition. To help design safe treatment processes, a model for the ammonia-propellant reaction was developed, which integrates transient energy and species conservation equations to simulate ammonia diffusion, heat generation, and heat flow in a propellant and in the solid residue resulting from ammonia treatment. It was calibrated using residue thickness and thermocouple data for one propellant. The calibrated model was used to predict conditions leading to ignition of thin propellant strips. The results agree well with experimental observations.

  18. Advances in plastic recycling. Volume 1: Recycling of polyurethanes

    SciTech Connect

    Frisch, K.C.; Klempner, D.; Prentice, G.

    1999-07-01

    ``Recycling of Polyurethanes'', the first volume in the Advances in Plastics Recycling series, is focused on the physical and chemical recycling of polyurethanes, with attention given to energy conversion. A compilation of the present ongoing studies on recycling of urethane and, in general, isocyanate-based polymers, the focus is on thermosetting urethane polymers. Contents include: Recycling of Polyurethane Plastics in the European Automotive Industry; Present State of Polyurethane Recycling in Europe; Processing Overview of Bonded Polyurethane Foam; Mechanical Recycling of Polyurethane Scrap; Ecostream{trademark}--A Technology Beyond Recycling; Recycling of Flexible polyurethane Foam; General purpose Adhesives Prepared from Chemically Recycled Waste Rigid Polyurethane Foams; and Utilization of Isocyanate Binders in Recycling of Scrap Automotive Headliners.

  19. Ammonia Ice Clouds on Jupiter

    NASA Technical Reports Server (NTRS)

    2007-01-01

    The top cloud layer on Jupiter is thought to consist of ammonia ice, but most of that ammonia 'hides' from spectrometers. It does not absorb light in the same way ammonia does. To many scientists, this implies that ammonia churned up from lower layers of the atmosphere 'ages' in some way after it condenses, possibly by being covered with a photochemically generated hydrocarbon mixture. The New Horizons Linear Etalon Imaging Spectral Array (LEISA), the half of the Ralph instrument that is able to 'see' in infrared wavelengths that are absorbed by ammonia ice, spotted these clouds and watched them evolve over five Jupiter days (about 40 Earth hours). In these images, spectroscopically identified fresh ammonia clouds are shown in bright blue. The largest cloud appeared as a localized source on day 1, intensified and broadened on day 2, became more diffuse on days 3 and 4, and disappeared on day 5. The diffusion seemed to follow the movement of a dark spot along the boundary of the oval region. Because the source of this ammonia lies deeper than the cloud, images like these can tell scientists much about the dynamics and heat conduction in Jupiter's lower atmosphere.

  20. Airborne reduced nitrogen: ammonia emissions from agriculture and other sources.

    PubMed

    Anderson, Natalie; Strader, Ross; Davidson, Cliff

    2003-06-01

    Ammonia is a basic gas and one of the most abundant nitrogen-containing compounds in the atmosphere. When emitted, ammonia reacts with oxides of nitrogen and sulfur to form particles, typically in the fine particle size range. Roughly half of the PM(2.5) mass in eastern United States is ammonium sulfate, according to the US EPA. Results from recent studies of PM(2.5) show that these fine particles are typically deposited deep in the lungs and may lead to increased morbidity and/or mortality. Also, these particles are in the size range that will degrade visibility. Ammonia emission inventories are usually constructed by multiplying an activity level by an experimentally determined emission factor for each source category. Typical sources of ammonia include livestock, fertilizer, soils, forest fires and slash burning, industry, vehicles, the oceans, humans, pets, wild animals, and waste disposal and recycling activities. Livestock is the largest source category in the United States, with waste from livestock responsible for about 3x10(9) kg of ammonia in 1995. Volatilization of ammonia from livestock waste is dependent on many parameters, and thus emission factors are difficult to predict. Despite a seasonal variation in these values, the emission factors for general livestock categories are usually annually averaged in current inventories. Activity levels for livestock are from the USDA Census of Agriculture, which does not give information about animal raising practices such as housing types and grazing times, waste handling systems, and approximate animal slurry spreading times or methods. Ammonia emissions in the United States in 1995 from sources other than livestock are much lower; for example, annual emissions are roughly 8x10(8) kg from fertilizer, 7x10(7) kg from industry, 5x10(7) kg from vehicles and 1x10(8) kg from humans. There is considerable uncertainty in the emissions from soil and vegetation, although this category may also be significant

  1. Isolation of equine peripheral blood mononuclear cells using Percoll.

    PubMed

    May, S A; Hooke, R E; Lees, P

    1991-01-01

    The concentration of Percoll required for isolating equine peripheral blood mononuclear cells has been reinvestigated. A poor cell yield was obtained at the 60 per cent concentration already reported. It is recommended that workers specifically interested in high yields of mononuclear cells, for investigation of lymphocyte and monocyte functions, use a concentration of 65 per cent Percoll. However, workers wishing to isolate pure populations of equine neutrophils might consider a concentration of 70 per cent in the upper layer of Percoll used to retain the mononuclear cells. PMID:1646471

  2. Truncated Long-Range Percolation on Oriented Graphs

    NASA Astrophysics Data System (ADS)

    van Enter, A. C. D.; de Lima, B. N. B.; Valesin, D.

    2016-07-01

    We consider different problems within the general theme of long-range percolation on oriented graphs. Our aim is to settle the so-called truncation question, described as follows. We are given probabilities that certain long-range oriented bonds are open; assuming that the sum of these probabilities is infinite, we ask if the probability of percolation is positive when we truncate the graph, disallowing bonds of range above a possibly large but finite threshold. We give some conditions in which the answer is affirmative. We also translate some of our results on oriented percolation to the context of a long-range contact process.

  3. Percolation Model for Slow Dynamics in Glass-Forming Materials

    NASA Astrophysics Data System (ADS)

    Lois, Gregg; Blawzdziewicz, Jerzy; O'Hern, Corey S.

    2009-01-01

    We identify a link between the glass transition and percolation of regions of mobility in configuration space. We find that many hallmarks of glassy dynamics, for example, stretched-exponential response functions and a diverging structural relaxation time, are consequences of the critical properties of mean-field percolation. Specific predictions of the percolation model include the range of possible stretching exponents 1/3≤β≤1 and the functional dependence of the structural relaxation time τα and exponent β on temperature, density, and wave number.

  4. Fractal atomic-level percolation in metallic glasses.

    PubMed

    Chen, David Z; Shi, Crystal Y; An, Qi; Zeng, Qiaoshi; Mao, Wendy L; Goddard, William A; Greer, Julia R

    2015-09-18

    Metallic glasses are metallic alloys that exhibit exotic material properties. They may have fractal structures at the atomic level, but a physical mechanism for their organization without ordering has not been identified. We demonstrated a crossover between fractal short-range (<2 atomic diameters) and homogeneous long-range structures using in situ x-ray diffraction, tomography, and molecular dynamics simulations. A specific class of fractal, the percolation cluster, explains the structural details for several metallic-glass compositions. We postulate that atoms percolate in the liquid phase and that the percolating cluster becomes rigid at the glass transition temperature. PMID:26383945

  5. AQUEOUS AMMONIA EQUILIBRIUM - TABULATION OF PERCENT UN-IONIZED AMMONIA

    EPA Science Inventory

    The percent of un-ionized ammonia as a function of pH and temperature in aqueous ammonia solutions of zero salinity is presented in tabular form over the following ranges: temperature 0.0 to 40.0 C in increments of 0.2 degree, and pH 5.00 to 12.00 in increments of 0.01 pH unit.

  6. ENGINEERING DESIGN CONFIGURATIONS FOR BIOLOGICAL AMMONIA REMOVAL

    EPA Science Inventory

    Many regions in the United States have excessive levels of nutrients including ammonia in their source waters. For example, farming and agricultural sources of ammonia in the Midwest contribute to relatively high levels of ammonia in many ground waters. Although ammonia in water ...

  7. Solvent recycle/recovery

    SciTech Connect

    Paffhausen, M.W.; Smith, D.L.; Ugaki, S.N.

    1990-09-01

    This report describes Phase I of the Solvent Recycle/Recovery Task of the DOE Chlorinated Solvent Substitution Program for the US Air Force by the Idaho National Engineering Laboratory, EG G Idaho, Inc., through the US Department of Energy, Idaho Operations Office. The purpose of the task is to identify and test recovery and recycling technologies for proposed substitution solvents identified by the Biodegradable Solvent Substitution Program and the Alternative Solvents/Technologies for Paint Stripping Program with the overall objective of minimizing hazardous wastes. A literature search to identify recycle/recovery technologies and initial distillation studies has been conducted. 4 refs.

  8. Fission gas bubble percolation on crystallographically consistent grain boundary networks

    NASA Astrophysics Data System (ADS)

    Sabogal-Suárez, Daniel; David Alzate-Cardona, Juan; Restrepo-Parra, Elisabeth

    2016-07-01

    Fission gas release in nuclear fuels can be modeled in the framework of percolation theory, where each grain boundary is classified as open or closed to the release of the fission gas. In the present work, two-dimensional grain boundary networks were assembled both at random and in a crystallographically consistent manner resembling a general textured microstructure. In the crystallographically consistent networks, grain boundaries were classified according to its misorientation. The percolation behavior of the grain boundary networks was evaluated as a function of radial cracks and radial thermal gradients in the fuel pellet. Percolation thresholds tend to shift to the left with increasing length and number of cracks, especially in the presence of thermal gradients. In general, the topology and percolation behavior of the crystallographically consistent networks differs from those of the random network.

  9. Network robustness and fragility: percolation on random graphs.

    PubMed

    Callaway, D S; Newman, M E; Strogatz, S H; Watts, D J

    2000-12-18

    Recent work on the Internet, social networks, and the power grid has addressed the resilience of these networks to either random or targeted deletion of network nodes or links. Such deletions include, for example, the failure of Internet routers or power transmission lines. Percolation models on random graphs provide a simple representation of this process but have typically been limited to graphs with Poisson degree distribution at their vertices. Such graphs are quite unlike real-world networks, which often possess power-law or other highly skewed degree distributions. In this paper we study percolation on graphs with completely general degree distribution, giving exact solutions for a variety of cases, including site percolation, bond percolation, and models in which occupation probabilities depend on vertex degree. We discuss the application of our theory to the understanding of network resilience. PMID:11136023

  10. Getter materials for cracking ammonia

    DOEpatents

    Boffito, Claudio; Baker, John D.

    1999-11-02

    A method is provided for cracking ammonia to produce hydrogen. The method includes the steps of passing ammonia over an ammonia-cracking catalyst which is an alloy including (1) alloys having the general formula Zr.sub.1-x Ti.sub.x M.sub.1 M.sub.2, wherein M.sub.1 and M.sub.2 are selected independently from the group consisting of Cr, Mn, Fe, Co, and Ni, and x is between about 0.0 and about 1.0 inclusive; and between about 20% and about 50% Al by weight. In another aspect, the method of the invention is used to provide methods for operating hydrogen-fueled internal combustion engines and hydrogen fuel cells. In still another aspect, the present invention provides a hydrogen-fueled internal combustion engine and a hydrogen fuel cell including the above-described ammonia-cracking catalyst.

  11. Compatibility testing with anhydrous ammonia

    NASA Technical Reports Server (NTRS)

    Benner, Steve M.; Schweickart, Russell B.

    1992-01-01

    Anhydrous ammonia has been proposed as the working fluid for a number of two-phase thermal control systems to be used in future space applications, including the Space Station Freedom and the Earth Observing Station (EOS). The compatibility of ammonia with the components in these systems is a major concern due to the corrosive nature of the fluid. Compatibility of ammonia with stainless steel and some aluminum alloys is well documented; however, data on other materials potentially suitable for aerospace use is less common. This paper documents the compatibility testing of nine materials with both gaseous and liquid ammonia. The test procedures are presented along with the resulting measurement data. Tensile strength was the only mechanical property tested that indicated a significant material incompatibility.

  12. Argon recovery from hydrogen depleted ammonia plant purge gas using a HARP Plant

    SciTech Connect

    Krishnamurthy, R.; Lerner, S.L.; Maclean, D.L.

    1987-01-01

    A number of ammonia plants employ membranes or cryogenic hydrogen recovery units to separate hydrogen contained in the purge gas for recycle to the ammonia synthesis loop. The resulting hydrogen depleted purge gas, which is usually used for fuel, is an attractive source of argon. This paper presents the novel features of a process which employs a combination of pressure swing adsorption (PSA) and cryogenic technology to separate the argon from this hydrogen depleted purge gas stream. This new proprietary Hybrid Argon Recovery Progress (HARP) plant is an effective alternative to a conventional all-cryogenic plant.

  13. Satellite Observations of Tropospheric Ammonia

    NASA Astrophysics Data System (ADS)

    Shephard, M. W.; Luo, M.; Rinsland, C. P.; Cady-Pereira, K. E.; Beer, R.; Pinder, R. W.; Henze, D.; Payne, V. H.; Clough, S.; Rodgers, C. D.; Osterman, G. B.; Bowman, K. W.; Worden, H. M.

    2008-12-01

    Global high-spectral resolution (0.06 cm-1) nadir measurements from TES-Aura enable the simultaneous retrieval of a number of tropospheric pollutants and trace gases in addition to the TES standard operationally retrieved products (e.g. carbon monoxide, ozone). Ammonia (NH3) is one of the additional species that can be retrieved in conjunction with the TES standard products, and is important for local, regional, and global tropospheric chemistry studies. Ammonia emissions contribute significantly to several well-known environmental problems, yet the magnitude and seasonal/spatial variability of the emissions are poorly constrained. In the atmosphere, an important fraction of fine particulate matter is composed of ammonium nitrate and ammonium sulfate. These particles are statistically associated with health impacts. When deposited to ecosystems in excess, nitrogen, including ammonia can cause nutrient imbalances, change in ecosystem species composition, eutrophication, algal blooms and hypoxia. Ammonia is also challenging to measure in-situ. Observations of surface concentrations are rare and are particularly sparse in North America. Satellite observations of ammonia are therefore highly desirable. We recently demonstrated that tropospheric ammonia is detectable in the TES spectra and presented some corresponding preliminary retrievals over a very limited range of conditions (Beer et al., 2008). Presented here are results that expand upon these initial TES ammonia retrievals in order to evaluate/validate the retrieval results utilizing in-situ surface observations (e.g. LADCO, CASTNet, EPA /NC State) and chemical models (e.g. GEOS-Chem and CMAQ). We also present retrievals over regions of interest that have the potential to help further understand air quality and the active nitrogen cycle. Beer, R., M. W. Shephard, S. S. Kulawik, S. A. Clough, A. Eldering, K. W. Bowman, S. P. Sander, B. M. Fisher, V. H. Payne, M. Luo, G. B. Osterman, and J. R. Worden, First

  14. Fiber Optic Distributed Temperature Sensing of Recharge Basin Percolation Dynamics

    NASA Astrophysics Data System (ADS)

    Becker, M.; Allen, E. M.; Hutchinson, A.

    2014-12-01

    Infiltration (spreading) basins are a central component of managed aquifer and recovery operations around the world. The concept is simple. Water is percolated into an aquifer where it can be withdrawn at a later date. However, managing infiltration basins can be complicated by entrapped air in sediments, strata of low permeability, clogging of the recharge surface, and biological growth, among other factors. Understanding the dynamics of percolation in light of these complicating factors provides a basis for making management decisions that increase recharge efficiency. As an aid to understanding percolation dynamics, fiber optic distribute temperature sensing (DTS) was used to track heat as a tracer of water movement in an infiltration basin. The diurnal variation of temperature in the basin was sensed at depth. The time lag between the oscillating temperature signal at the surface and at depth indicated the velocity of water percolation. DTS fiber optic cables were installed horizontally along the basin and vertically in boreholes to measure percolation behavior. The horizontal cable was installed in trenches at 0.3 and 1 m depth, and the vertical cable was installed using direct push technology. The vertical cable was tightly wound to produce a factor of 10 increase in spatial resolution of temperature measurements. Temperature was thus measured every meter across the basin and every 10 cm to a depth of 10 m. Data from the trenched cable suggested homogeneous percolation across the basin, but infiltration rates were a function of stage indicating non-ideal percolation. Vertical temperature monitoring showed significant lateral flow in sediments underlying the basin both during saturation and operation of the basin. Deflections in the vertical temperature profile corresponded with fine grained layers identified in core samples indicating a transient perched water table condition. The three-dimensional flow in this relatively homogenous surficial geology calls

  15. Social percolation and the influence of mass media

    NASA Astrophysics Data System (ADS)

    Proykova, Ana; Stauffer, Dietrich

    2002-09-01

    In the marketing model of Solomon and Weisbuch, people buy a product only if their neighbours tell them of its quality, and if this quality is higher than their own quality expectations. Now we introduce additional information from the mass media, which is analogous to the ghost field in percolation theory. The mass media shift the percolative phase transition observed in the model, and decrease the time after which the stationary state is reached.

  16. Transfer-matrix methods and results for directed percolation

    NASA Astrophysics Data System (ADS)

    Ben-Avraham, D.; Bidaux, R.; Schulman, L. S.

    1991-06-01

    For directed percolation, the second nontrivial eigenvalue of the transfer matrix is shown to have its maximum at pc. Using this, we obtain for (1+1)-dimensional directed site percolation pc=0.706 522+/-0.000 005, which agrees within 10-3 with other results, but is nevertheless significantly (in terms of quoted uncertainties) different from them. We also relate other quantities to the transfer-matrix spectrum and eigenfunctions.

  17. On Logarithmic Corrections in Two-Dimensional Percolation

    NASA Astrophysics Data System (ADS)

    Marsili, M.; Jug, G.

    The possibility of unusual leading logarithmic corrections to the asymptotic behavior of the percolation connectedness length ξ in two dimensions is explored through a finite-size transfer-matrix analysis on strips of widths L≤12. It is found that, for both square-site and triangular-site percolation problems, no such corrections arise and the accepted exact value of the critical exponent ν is recovered.

  18. Percolation temperature and the ''instability'' of the effective potential

    SciTech Connect

    Arago de Carvalho, C.; Bazeia, D.; Eboli, O.J.P.; Marques, G.C.; da Silva, A.J.; Ventura, I.

    1985-03-15

    We show that in spontaneously broken lambdaphi/sup 4/ theory the percolation temperature coincides with the temperature at which the semiclassical (loop) expansion of the effective potential (free energy) of the system around a uniform field configuration fails. This allows us to extract the percolation temperature directly from the effective potential. The addition of fermions or gauge fields does not alter the result as long as they are weakly coupled to the scalars. The coincidence holds in the high-temperature limit.

  19. Two exactly soluble models of rigidity percolation

    PubMed Central

    Thorpe, M. F.; Stinchcombe, R. B.

    2014-01-01

    We summarize results for two exactly soluble classes of bond-diluted models for rigidity percolation, which can serve as a benchmark for numerical and approximate methods. For bond dilution problems involving rigidity, the number of floppy modes F plays the role of a free energy. Both models involve pathological lattices with two-dimensional vector displacements. The first model involves hierarchical lattices where renormalization group calculations can be used to give exact solutions. Algebraic scaling transformations produce a transition of the second order, with an unstable critical point and associated scaling laws at a mean coordination 〈r〉=4.41, which is above the ‘mean field’ value 〈r〉=4 predicted by Maxwell constraint counting. The order parameter exponent associated with the spanning rigid cluster geometry is β=0.0775 and that associated with the divergence of the correlation length and the anomalous lattice dimension d is dν=3.533. The second model involves Bethe lattices where the rigidity transition is massively first order by a mean coordination 〈r〉=3.94 slightly below that predicted by Maxwell constraint counting. We show how a Maxwell equal area construction can be used to locate the first-order transition and how this result agrees with simulation results on larger random-bond lattices using the pebble game algorithm. PMID:24379428

  20. The Totem Pole Recycled.

    ERIC Educational Resources Information Center

    Sewall, Susan Breyer

    1991-01-01

    Presents an activity that integrates science, environmental education, art, and social studies. Students identify and research an endangered species and construct a totem pole depicting the species using a recyclable material. (MDH)

  1. A Practical Recycling Project . . .

    ERIC Educational Resources Information Center

    Durant, Raymond H.; Mikuska, James M.

    1973-01-01

    Descirbes a school district's recycling program of aluminum lunch trays that are collected after their use. The trays are used as scrap metal in industrial education workshop and used for sand castings. (PS)

  2. Recycle plastics into feedstocks

    SciTech Connect

    Kastner, H.; Kaminsky, W.

    1995-05-01

    Thermal cracking of mixed-plastics wastes with a fluidized-bed reactor can be a viable and cost-effective means to meet mandatory recycling laws. Strict worldwide environmental statutes require the hydrocarbon processing industry (HPI) to develop and implement product applications and technologies that reuse post-consumer mixed-plastics waste. Recycling or reuse of plastics waste has a broad definition. Recycling entails more than mechanical regranulation and remelting of polymers for film and molding applications. A European consortium of academia and refiners have investigated if it is possible and profitable to thermally crack plastics into feedstocks for refining and petrochemical applications. Development and demonstration of pyrolysis methods show promising possibilities of converting landfill garbage into valuable feedstocks such as ethylene, propylene, BTX, etc. Fluidized-bed reactor technologies offer HPI operators a possible avenue to meet recycling laws, conserve raw materials and yield a profit. The paper describes thermal cracking for feedstocks and pyrolysis of polyolefins.

  3. Understanding the Percolation Characteristics of Nonlinear Composite Dielectrics.

    PubMed

    Yang, Xiao; Hu, Jun; Chen, Shuiming; He, Jinliang

    2016-01-01

    Nonlinear composite dielectrics can function as smart materials for stress control and field grading in all fields of electrical insulations. The percolation process is a significant issue of composite dielectrics. However, the classic percolation theory mainly deals with traditional composites in which the electrical parameters of both insulation matrix and conducting fillers are independent of the applied electric field. This paper measured the nonlinear V-I characteristics of ZnO microvaristors/silicone rubber composites with several filler concentrations around an estimated percolation threshold. For the comparison with the experiment, a new microstructural model is proposed to simulate the nonlinear conducting behavior of the composite dielectrics modified by metal oxide fillers, which is based on the Voronoi network and considers the breakdown feature of the insulation matrix for near percolated composites. Through both experiment and simulation, the interior conducting mechanism and percolation process of the nonlinear composites were presented and a specific percolation threshold was determined as 33%. This work has provided a solution to better understand the characteristics of nonlinear composite dielectrics. PMID:27476998

  4. Phase Diagram of Inhomogeneous Percolation with a Defect Plane

    NASA Astrophysics Data System (ADS)

    Iliev, G. K.; Janse van Rensburg, E. J.; Madras, N.

    2015-01-01

    Let be the -dimensional hypercubic lattice and let be an -dimensional sublattice, with . We consider a model of inhomogeneous bond percolation on at densities and , in which edges in are open with probability , and edges in open with probability . We generalize several classical results of (homogeneous) bond percolation to this inhomogeneous model. The phase diagram of the model is presented, and it is shown that there is a subcritical regime for and (where is the critical probability for homogeneous percolation in ), a bulk supercritical regime for , and a surface supercritical regime for and . We show that is a strictly decreasing function for , with a jump discontinuity at . We extend the Aizenman-Barsky differential inequalities for homogeneous percolation to the inhomogeneous model and use them to prove that the susceptibility is finite inside the subcritical phase. We prove that the cluster size distribution decays exponentially in the subcritical phase, and sub-exponentially in the supercritical phases. For a model of lattice animals with a defect plane, the free energy is related to functions of the inhomogeneous percolation model, and we show how the percolation transition implies a non-analyticity in the free energy of the animal model. Finally, we present simulation estimates of the critical curve.

  5. Percolation theory applied to measures of fragmentation in social networks

    NASA Astrophysics Data System (ADS)

    Chen, Yiping; Paul, Gerald; Cohen, Reuven; Havlin, Shlomo; Borgatti, Stephen P.; Liljeros, Fredrik; Stanley, H. Eugene

    2007-04-01

    We apply percolation theory to a recently proposed measure of fragmentation F for social networks. The measure F is defined as the ratio between the number of pairs of nodes that are not connected in the fragmented network after removing a fraction q of nodes and the total number of pairs in the original fully connected network. We compare F with the traditional measure used in percolation theory, P∞ , the fraction of nodes in the largest cluster relative to the total number of nodes. Using both analytical and numerical methods from percolation, we study Erdős-Rényi and scale-free networks under various types of node removal strategies. The removal strategies are random removal, high degree removal, and high betweenness centrality removal. We find that for a network obtained after removal (all strategies) of a fraction q of nodes above percolation threshold, P∞≈(1-F)1/2 . For fixed P∞ and close to percolation threshold (q=qc) , we show that 1-F better reflects the actual fragmentation. Close to qc , for a given P∞ , 1-F has a broad distribution and it is thus possible to improve the fragmentation of the network. We also study and compare the fragmentation measure F and the percolation measure P∞ for a real social network of workplaces linked by the households of the employees and find similar results.

  6. Understanding the Percolation Characteristics of Nonlinear Composite Dielectrics

    NASA Astrophysics Data System (ADS)

    Yang, Xiao; Hu, Jun; Chen, Shuiming; He, Jinliang

    2016-08-01

    Nonlinear composite dielectrics can function as smart materials for stress control and field grading in all fields of electrical insulations. The percolation process is a significant issue of composite dielectrics. However, the classic percolation theory mainly deals with traditional composites in which the electrical parameters of both insulation matrix and conducting fillers are independent of the applied electric field. This paper measured the nonlinear V-I characteristics of ZnO microvaristors/silicone rubber composites with several filler concentrations around an estimated percolation threshold. For the comparison with the experiment, a new microstructural model is proposed to simulate the nonlinear conducting behavior of the composite dielectrics modified by metal oxide fillers, which is based on the Voronoi network and considers the breakdown feature of the insulation matrix for near percolated composites. Through both experiment and simulation, the interior conducting mechanism and percolation process of the nonlinear composites were presented and a specific percolation threshold was determined as 33%. This work has provided a solution to better understand the characteristics of nonlinear composite dielectrics.

  7. Percolation velocity dependence on local concentration in bidisperse granular flows

    NASA Astrophysics Data System (ADS)

    Jones, Ryan P.; Xiao, Hongyi; Deng, Zhekai; Umbanhowar, Paul B.; Lueptow, Richard M.

    The percolation velocity, up, of granular material in size or density bidisperse mixtures depends on the local concentration, particle size ratio, particle density ratio, and shear rate, γ ˙. Discrete element method computational results were obtained for bounded heap flows with size ratios between 1 and 3 and for density ratios between 1 and 4. The results indicate that small particles percolate downward faster when surrounded by large particles than large particles percolate upward when surrounded by small particles, as was recently observed in shear-box experiments. Likewise, heavy particles percolate downward faster when surrounded by light particles than light particles percolate upward when surrounded by heavy particles. The dependence of up / γ ˙ on local concentration results in larger percolation flux magnitudes at high concentrations of large (or light) particles compared to high concentrations of small (or heavy) particles, while local volumetric flux is conserved. The dependence of up / γ ˙ on local concentration can be incorporated into a continuum model, but the impact on global segregation patterns is usually minimal. Partially funded by Dow Chemical Company and NSF Grant No. CBET-1511450.

  8. Percolation model for selective dissolution of multi-component glasses

    SciTech Connect

    Kale, R.P.; Brinker, C.J.

    1995-03-01

    A percolation model is developed which accounts for most known features of the process of porous glass membrane preparation by selective dissolution of multi-component glasses. The model is founded within tile framework of the classical percolation theory, wherein the components of a glass are represented by random sites on a suitable lattice. Computer simulation is used to mirror the generation of a porous structure during the dissolution process, reproducing many of the features associated with the phenomenon. Simulation results evaluate the effect of the initial composition of the glass on the kinetics of the leaching process as well as the morphology of the generated porous structure. The percolation model establishes the porous structure as a percolating cluster of unreachable constituents in the glass. The simulation algorithm incorporates removal of both, the accessible leachable components in the glass as well as the independent clusters of unreachable components not attached to the percolating cluster. The dissolution process thus becomes limited by the conventional site percolation thresholds of the unreachable components (which restricts the formation of the porous network), as well as the leachable components (which restricts the accessibility of the solvating medium into the glass). The simulation results delineate the range of compositional variations for successful porous glass preparation and predict the variation of porosity, surface area, dissolution rates and effluent composition with initial composition and time. Results compared well with experimental studies and improved upon similar models attempted in die past.

  9. Understanding the Percolation Characteristics of Nonlinear Composite Dielectrics

    PubMed Central

    Yang, Xiao; Hu, Jun; Chen, Shuiming; He, Jinliang

    2016-01-01

    Nonlinear composite dielectrics can function as smart materials for stress control and field grading in all fields of electrical insulations. The percolation process is a significant issue of composite dielectrics. However, the classic percolation theory mainly deals with traditional composites in which the electrical parameters of both insulation matrix and conducting fillers are independent of the applied electric field. This paper measured the nonlinear V-I characteristics of ZnO microvaristors/silicone rubber composites with several filler concentrations around an estimated percolation threshold. For the comparison with the experiment, a new microstructural model is proposed to simulate the nonlinear conducting behavior of the composite dielectrics modified by metal oxide fillers, which is based on the Voronoi network and considers the breakdown feature of the insulation matrix for near percolated composites. Through both experiment and simulation, the interior conducting mechanism and percolation process of the nonlinear composites were presented and a specific percolation threshold was determined as 33%. This work has provided a solution to better understand the characteristics of nonlinear composite dielectrics. PMID:27476998

  10. Percolation theory applied to measures of fragmentation in social networks.

    PubMed

    Chen, Yiping; Paul, Gerald; Cohen, Reuven; Havlin, Shlomo; Borgatti, Stephen P; Liljeros, Fredrik; Stanley, H Eugene

    2007-04-01

    We apply percolation theory to a recently proposed measure of fragmentation F for social networks. The measure F is defined as the ratio between the number of pairs of nodes that are not connected in the fragmented network after removing a fraction q of nodes and the total number of pairs in the original fully connected network. We compare F with the traditional measure used in percolation theory, P(infinity), the fraction of nodes in the largest cluster relative to the total number of nodes. Using both analytical and numerical methods from percolation, we study Erdos-Rényi and scale-free networks under various types of node removal strategies. The removal strategies are random removal, high degree removal, and high betweenness centrality removal. We find that for a network obtained after removal (all strategies) of a fraction q of nodes above percolation threshold, P(infinity) approximately (1-F)1/2. For fixed P(infinity) and close to percolation threshold (q=qc), we show that 1-F better reflects the actual fragmentation. Close to qc, for a given P(infinity), 1-F has a broad distribution and it is thus possible to improve the fragmentation of the network. We also study and compare the fragmentation measure F and the percolation measure P(infinity) for a real social network of workplaces linked by the households of the employees and find similar results. PMID:17500961

  11. Morphology-Driven High-Performance Polymer Transistor-based Ammonia Gas Sensor.

    PubMed

    Yu, Seong Hoon; Cho, Jangwhan; Sim, Kyu Min; Ha, Jae Un; Chung, Dae Sung

    2016-03-01

    Developing high-performance gas sensors based on polymer field-effect transistors (PFETs) requires enhancing gas-capture abilities of polymer semiconductors without compromising their high charge carrier mobility. In this work, cohesive energies of polymer semiconductors were tuned by strategically inserting buffer layers, which resulted in dramatically different semiconductor surface morphologies. Elucidating morphological and structural properties of polymer semiconductor films in conjunction with FET studies revealed that surface morphologies containing large two-dimensional crystalline domains were optimal for achieving high surface areas and creating percolation pathways for charge carriers. Ammonia molecules with electron lone pairs adsorbed on the surface of conjugated semiconductors can serve as efficient trapping centers, which negatively shift transfer curves for p-type PFETs. Therefore, morphology optimization of polymer semiconductors enhances their gas sensing abilities toward ammonia, leading to a facile method of manufacturing high-performance gas sensors. PMID:26927929

  12. Recycling of nonmetallics

    USGS Publications Warehouse

    Amey, E.B.; Kelly, T.D.

    1996-01-01

    The first factor determining recyclability is the composition of the material itself. Metals, for example, can be reused with little or no loss in quality. Paper and rubber, by this criterion, are less recyclable. Each time paper is recycled, some cellulose fibers are broken. Shorter fibers can mean weaker paper of perceived lower quality and value. Vulcanizing is an irreversible chemical process that precludes recycling rubber in its original form. Both materials may be reused in other applications often of lower value than the original one. To be recyclable, the discarded material must have a collection infrastructure at the source of waste generation, at a central collection site, or at curbside. The recovered material must also have a market. If it is priced noncompetitively or no market exists, if it does not meet specifications, or if it requires special technology investments which cannot be recovered through future sales, the recovered material may be stockpiled or discarded rather than recycled. ?? 1996 International Association for Mathematical Geology.

  13. Global Seabird Ammonia Emissions

    NASA Astrophysics Data System (ADS)

    Riddick, S. N.; Blackall, T. D.; Dragosits, U.; Daunt, F. H.; Braban, C. F.; Tang, Y. S.; Trathan, P.; Wanless, S.; Sutton, M. A.

    2010-12-01

    Seabird colonies represent a major source of atmospheric ammonia (NH3) in remote coastal and marine systems in temperate, tropical and polar regions. Previous studies have shown that NH3 emissions from Scottish seabird colonies were substantial - of similar magnitude to the most intensive agricultural point source emissions. The UK data were used to model global seabird NH3 emissions and suggested that penguins are a major source of emissions on and around the Antarctic continent. The largest seabird colonies are in the order of millions of seabirds. Due to the isolation of these colonies from anthropogenic nitrogen sources, they may play a major role in the nitrogen cycle within these ecosystems. A global seabird database was constructed and used in conjunction with a species-specific seabird bioenergetics model to map the locations of NH3 emissions from seabird colonies. The accuracy of the modelled emissions was validated with field data of NH3 emissions measured at key seabird colonies in different climatic regions of the world: temperate (Isle of May, Scotland), tropical (Ascension Island) and polar (Signy Island, South Georgia). The field data indicated good agreement between modelled and measured NH3 emissions. The measured NH3 emissions also showed the variability of emission with climate. Climate dependence of seabird NH3 emissions may have further implications under a changing global climate. Seabird colonies represent NH3 emission ‘hotspots’, often far from anthropogenic sources, and are likely to be the major source of nitrogen input to these remote coastal ecosystems. The direct manuring by seabirds at colony locations may strongly influence species richness and biodiversity. The subsequent volatilisation and deposition of NH3 increases the spatial extent of seabird influence on nitrogen cycling in their local ecosystem. As many seabird populations are fluctuating due to changing food supply, climate change or anthropogenic pressures, these factors

  14. MEASUREMENT OF AMMONIA RELEASE FROM SALTSTONE

    SciTech Connect

    Zamecnik, J; Alex Cozzi, A

    2009-01-15

    SRNL was requested by WSRC Waste Solidification Engineering to characterize the release of ammonia from saltstone curing at 95 C by performing experimental testing. These tests were performed with an MCU-type Tank 50H salt simulant containing 0, 50, and 200 mg/L ammonia. The testing program showed that above saltstone made from the 200 mg/L ammonia simulant, the vapor space ammonia concentration was about 2.7 mg/L vapor at 95 C. An upper 95% confidence value for this concentration was found to be 3.9 mg/L. Testing also showed that ammonia was chemically generated from curing saltstone at 95 C; the amount of ammonia generated was estimated to be equivalent to 121 mg/L additional ammonia in the salt solution feed. Even with chemical generation, the ammonia release from saltstone was found to be lower than its release from salt solution only with 200 mg/L ammonia.

  15. Mono-fermentation of chicken manure: ammonia inhibition and recirculation of the digestate.

    PubMed

    Nie, Hong; Jacobi, H Fabian; Strach, Katrin; Xu, Chunming; Zhou, Hongjun; Liebetrau, Jan

    2015-02-01

    The effects of ammonia concentration on the performance and stability of mono-fermentation of chicken manure were investigated in a lab-scale continuous stirred tank reactor at 40 °C. Technical stripping was performed to remove ammonia from the liquid fraction of digestate, and the entire product was recycled to the fermenter to control ammonia concentration in the fermenter. Organic loading rate (OLR) of 5.3 gVS/(L d) was achieved with an average free ammonia nitrogen (FAN) concentration of 0.77 g/L and a specific gas yield of 0.39 L/gVS. When OLR was increased to 6.0 gVS/(L d), stable operation could be obtained with an average FAN concentration of 0.86 g/L and a specific gas yield of 0.27 L/gVS. Mono-fermentation of chicken manure was successfully carried out at high ammonia concentrations. Controlled recirculation of treated liquid fraction of digestate could be a solution in large-scale application for both: to avoid ammonia inhibition and minimize digestate. PMID:25266688

  16. Percolation model with an additional source of disorder.

    PubMed

    Kundu, Sumanta; Manna, S S

    2016-06-01

    The ranges of transmission of the mobiles in a mobile ad hoc network are not uniform in reality. They are affected by the temperature fluctuation in air, obstruction due to the solid objects, even the humidity difference in the environment, etc. How the varying range of transmission of the individual active elements affects the global connectivity in the network may be an important practical question to ask. Here a model of percolation phenomena, with an additional source of disorder, is introduced for a theoretical understanding of this problem. As in ordinary percolation, sites of a square lattice are occupied randomly with probability p. Each occupied site is then assigned a circular disk of random value R for its radius. A bond is defined to be occupied if and only if the radii R_{1} and R_{2} of the disks centered at the ends satisfy a certain predefined condition. In a very general formulation, one divides the R_{1}-R_{2} plane into two regions by an arbitrary closed curve. One defines a point within one region as representing an occupied bond; otherwise it is a vacant bond. The study of three different rules under this general formulation indicates that the percolation threshold always varies continuously. This threshold has two limiting values, one is p_{c}(sq), the percolation threshold for the ordinary site percolation on the square lattice, and the other is unity. The approach of the percolation threshold to its limiting values are characterized by two exponents. In a special case, all lattice sites are occupied by disks of random radii R∈{0,R_{0}} and a percolation transition is observed with R_{0} as the control variable, similar to the site occupation probability. PMID:27415234

  17. Percolation model with an additional source of disorder

    NASA Astrophysics Data System (ADS)

    Kundu, Sumanta; Manna, S. S.

    2016-06-01

    The ranges of transmission of the mobiles in a mobile ad hoc network are not uniform in reality. They are affected by the temperature fluctuation in air, obstruction due to the solid objects, even the humidity difference in the environment, etc. How the varying range of transmission of the individual active elements affects the global connectivity in the network may be an important practical question to ask. Here a model of percolation phenomena, with an additional source of disorder, is introduced for a theoretical understanding of this problem. As in ordinary percolation, sites of a square lattice are occupied randomly with probability p . Each occupied site is then assigned a circular disk of random value R for its radius. A bond is defined to be occupied if and only if the radii R1 and R2 of the disks centered at the ends satisfy a certain predefined condition. In a very general formulation, one divides the R1-R2 plane into two regions by an arbitrary closed curve. One defines a point within one region as representing an occupied bond; otherwise it is a vacant bond. The study of three different rules under this general formulation indicates that the percolation threshold always varies continuously. This threshold has two limiting values, one is pc(sq) , the percolation threshold for the ordinary site percolation on the square lattice, and the other is unity. The approach of the percolation threshold to its limiting values are characterized by two exponents. In a special case, all lattice sites are occupied by disks of random radii R ∈{0 ,R0} and a percolation transition is observed with R0 as the control variable, similar to the site occupation probability.

  18. Organic reactivity in liquid ammonia.

    PubMed

    Ji, Pengju; Atherton, John; Page, Michael I

    2012-08-14

    Liquid ammonia is a useful solvent for many organic reactions including aliphatic and aromatic nucleophilic substitution and metal-ion catalysed reactions. The acidity of acids is modified in liquid ammonia giving rise to differences from conventional solvents. The ionisation constants of phenols and carbon acids are the product of those for ion-pair formation and dissociation to the free ions. There is a linear relationship between the pK(a) of phenols and carbon acids in liquid ammonia and those in water of slope 1.68 and 0.7, respectively. Aminium ions exist in their unprotonated free base form in liquid ammonia. The rates of solvolysis and aminolysis by neutral amines of substituted benzyl chlorides in liquid ammonia show little or no dependence upon ring substituents, in stark contrast with the hydrolysis rates of substituted benzyl halides in water which vary 10(7) fold. However, the rates of the reaction of phenoxide ions and amine anions with 4-substituted benzyl chlorides gives a Hammett ρ = 1.1 and 0.93, respectively. The second order rate constants for the substitution of benzyl chlorides by neutral and anionic amines show a single Brønsted β(nuc) = 0.21 whereas those for substituted phenoxide ions generate a Brønsted β(nuc) = 0.40. The rates of aromatic nucleophilic substitution reactions in liquid ammonia are much faster than those in protic solvents indicating that liquid ammonia behaves like a typical dipolar aprotic solvent in its solvent effects on organic reactions. Nitrofluorobenzenes (NFB) readily undergo solvolysis in liquid ammonia but oxygen nucleophiles, such as alkoxide and phenoxide ions, displace the fluorine of 4-NFB in liquid ammonia to give the corresponding substitution product with little or no competing solvolysis product. The Brønsted β(nuc) for the reaction of 4-NFB with para-substituted phenoxides is 0.91, indicative that the decomposition of the Meisenheimer σ-intermediate is rate limiting. The aminolysis of 4-NFB occurs

  19. Recycling of Reinforced Plastics

    NASA Astrophysics Data System (ADS)

    Adams, R. D.; Collins, Andrew; Cooper, Duncan; Wingfield-Digby, Mark; Watts-Farmer, Archibald; Laurence, Anna; Patel, Kayur; Stevens, Mark; Watkins, Rhodri

    2014-02-01

    This work has shown is that it is possible to recycle continuous and short fibre reinforced thermosetting resins while keeping almost the whole of the original material, both fibres and matrix, within the recyclate. By splitting, crushing hot or cold, and hot forming, it is possible to create a recyclable material, which we designate a Remat, which can then be used to remanufacture other shapes, examples of plates and tubes being demonstrated. Not only can remanufacturing be done, but it has been shown that over 50 % of the original mechanical properties, such as the E modulus, tensile strength, and interlaminar shear strength, can be retained. Four different forms of composite were investigated, a random mat Glass Fibre Reinforced Plastic (GFRP) bathroom component and boat hull, woven glass and carbon fibre cloth impregnated with an epoxy resin, and unidirectional carbon fibre pre-preg. One of the main factors found to affect composite recyclability was the type of resin matrix used in the composite. Thermoset resins tested were shown to have a temperature range around the Glass Transition Temperature (Tg) where they exhibit ductile behaviour, hence aiding reforming of the material. The high-grade carbon fibre prepreg was found to be less easy to recycle than the woven of random fibre laminates. One method of remanufacturing was by heating the Remat to above its glass transition temperature, bending it to shape, and then cooling it. However, unless precautions are taken, the geometric form may revert. This does not happen with the crushed material.

  20. Viscosity and thermal conductivity of stable graphite suspensions near percolation.

    PubMed

    Ma, Lei; Wang, Jianjian; Marconnet, Amy M; Barbati, Alexander C; McKinley, Gareth H; Liu, Wei; Chen, Gang

    2015-01-14

    Nanofluids have received much attention in part due to the range of properties possible with different combinations of nanoparticles and base fluids. In this work, we measure the viscosity of suspensions of graphite particles in ethylene glycol as a function of the volume fraction, shear rate, and temperature below and above the percolation threshold. We also measure and contrast the trends observed in the viscosity with increasing volume fraction to the thermal conductivity behavior of the same suspensions: above the percolation threshold, the slope that describes the rate of thermal conductivity enhancement with concentration reduces compared to below the percolation threshold, whereas that of the viscosity enhancement increases. While the thermal conductivity enhancement is independent of temperature, the viscosity changes show a strong dependence on temperature and exhibit different trends with respect to the temperature at different shear rates above the percolation threshold. Interpretation of the experimental observations is provided within the framework of Stokesian dynamics simulations of the suspension microstructure and suggests that although diffusive contributions are not important for the observed thermal conductivity enhancement, they are important for understanding the variations in the viscosity with changes of temperature and shear rate above the percolation threshold. The experimental results can be collapsed to a single master curve through calculation of a single dimensionless parameter (a Péclet number based on the rotary diffusivity of the graphite particles). PMID:25469709

  1. Bounds for percolation thresholds on directed and undirected graphs

    NASA Astrophysics Data System (ADS)

    Hamilton, Kathleen; Pryadko, Leonid

    2015-03-01

    Percolation theory is an efficient approach to problems with strong disorder, e.g., in quantum or classical transport, composite materials, and diluted magnets. Recently, the growing role of big data in scientific and industrial applications has led to a renewed interest in graph theory as a tool for describing complex connections in various kinds of networks: social, biological, technological, etc. In particular, percolation on graphs has been used to describe internet stability, spread of contagious diseases and computer viruses; related models describe market crashes and viral spread in social networks. We consider site-dependent percolation on directed and undirected graphs, and present several exact bounds for location of the percolation transition in terms of the eigenvalues of matrices associated with graphs, including the adjacency matrix and the Hashimoto matrix used to enumerate non-backtracking walks. These bounds correspond t0 a mean field approximation and become asymptotically exact for graphs with no short cycles. We illustrate this convergence numerically by simulating percolation on several families of graphs with different cycle lengths. This research was supported in part by the NSF Grant PHY-1416578 and by the ARO Grant W911NF-11-1-0027.

  2. Invasion percolation between two wells in continuous media

    NASA Astrophysics Data System (ADS)

    Lee, Sang Bub

    2016-03-01

    Invasion percolation between two wells was studied in continuous media consisted of overlapping disks and spheres. The invasion percolation between injection and extraction wells occurs when a fluid injected through the injection well invades less pressurized neighboring pores until it reaches the extraction well. Attention was paid to whether the probability distribution of the invading mass m and the fractal dimension of the clusters of invaded pore particles remain similar to those of the lattice model. Our results indicated that the power α characterizing the probability distribution via P( m) ∝ m - α was considerably larger than that of the lattice model for a reduced volume density η = η c of pore particles, η c being the percolation critical density, and that it converged to the value for the lattice model for p e = 0 as η was increased, where p e is the pressure of an extraction site for the lattice model. The fractal dimension of the invaded clusters was found to be similar to that of the ordinary lattice percolation clusters generated at the percolation threshold. The scaling of the invaded clusters was also examined, and it held in both two and three dimensions.

  3. Memory decay and loss of criticality in quorum percolation.

    PubMed

    Renault, Renaud; Monceau, Pascal; Bottani, Samuel

    2013-12-01

    In this paper, we present the effects of memory decay on a bootstrap percolation model applied to random directed graphs (quorum percolation). The addition of decay was motivated by its natural occurrence in physical systems previously described by percolation theory, such as cultured neuronal networks, where decay originates from ionic leakage through the membrane of neurons and/or synaptic depression. Surprisingly, this feature alone appears to change the critical behavior of the percolation transition, where discontinuities are replaced by steep but finite slopes. Using different numerical approaches, we show evidence for this qualitative change even for very small decay values. In experiments where the steepest slopes can not be resolved and still appear as discontinuities, decay produces nonetheless a quantitative difference on the location of the apparent critical point. We discuss how this shift impacts network connectivity previously estimated without considering decay. In addition to this particular example, we believe that other percolation models are worth reinvestigating, taking into account similar sorts of memory decay. PMID:24483413

  4. Two-dimensional percolation threshold in confined Si nanoparticle networks

    NASA Astrophysics Data System (ADS)

    Laube, J.; Gutsch, S.; Wang, D.; Kübel, C.; Zacharias, M.; Hiller, D.

    2016-01-01

    Non-percolating and percolating silicon quantum dot (QD) networks were investigated by plane-view energy filtered transmission electron microscopy (EF-TEM). The Si QD networks were prepared by plasma enhanced chemical vapor deposition on free standing 5 nm Si3N4 membranes, followed by high temperature annealing. The percolation threshold from non-percolating to percolating networks is found to be in between a SiOx stoichiometry of SiO0.5 up to SiO0.7. Using the EF-TEM images, key structural parameters of the Si QD ensemble were extracted and compared, i.e., their size distribution, nearest neighbor distance, and circularity. Increasing the silicon excess within the SiOx layer results in an ensemble of closer spaced, less size-controlled, and less circular Si QDs that give rise to coupling effects. Furthermore, the influence of the structural parameters on the optical and electrical Si QD ensemble properties is discussed.

  5. Who owns the recyclables

    SciTech Connect

    Parker, B.

    1994-05-01

    On March 31, the California Supreme Court decided the much awaited Rancho Mirage'' case (Waste Management of the Desert, Inc., and the City of Rancho Mirage v. Palm Springs Recycling Center, Inc.), and held that the California Integrated Waste Management Act of 1989 does not allow an exclusive franchise for the collection of recyclables not discarded by their owner.'' This ends a three-year slugfest between secondary materials processors in the state and municipalities and their franchised garbage haulers who also collect and process recyclables as part of their exclusive arrangement. Central to this nationally-watched litigation is a most fundamental question in waste management: at what point in time do articles in the solid waste stream become actual or potentially valuable secondary materials

  6. Scrap tire recycling

    SciTech Connect

    Lula, J.W.; Bohnert, G.W.

    1997-03-01

    As the automobile tire technology has grown and met the need for safer and more durable tires, stronger reinforcement and more chemically resistant rubber compounds have made recycling tires more difficult. In an effort to resolve this problem, techniques and equipment were developed to grind tires into small pieces, and new markets were sought to utilize the crumb rubber product streams from ground tires. Industrial combustion processes were modified to accept scrap tires as fuel. These efforts have been beneficial, steadily increasing the percentage of scrap tires recycled to about 10% in 1985, and reaching 72% in 1995. By the end of 1997, fully 100% of tires generated in the U.S. are expected to be recycled.

  7. Catalytic Organometallic Reactions of Ammonia

    PubMed Central

    Klinkenberg, Jessica L.

    2012-01-01

    Until recently, ammonia had rarely succumbed to catalytic transformations with homogeneous catalysts, and the development of such reactions that are selective for the formation of single products under mild conditions has encountered numerous challenges. However, recently developed catalysts have allowed several classes of reactions to create products with nitrogen-containing functional groups from ammonia. These reactions include hydroaminomethylation, reductive amination, alkylation, allylic substitution, hydroamination, and cross-coupling. This Minireview describes examples of these processes and the factors that control catalyst activity and selectivity. PMID:20857466

  8. Molecular Mechanisms of Renal Ammonia Transport

    PubMed Central

    Weiner, I. David; Hamm, L. Lee

    2015-01-01

    Acid-base homeostasis to a great extent relies on renal ammonia metabolism. In the past several years, seminal studies have generated important new insights into the mechanisms of renal ammonia transport. In particular, the theory that ammonia transport occurs almost exclusively through nonionic NH3 diffusion and NH4+ trapping has given way to a model postulating that a variety of proteins specifically transport NH3 and NH4+ and that this transport is critical for normal ammonia metabolism. Many of these proteins transport primarily H+ or K+ but also transport NH4+. Nonerythroid Rh glycoproteins transport ammonia and may represent critical facilitators of ammonia transport in the kidney. This review discusses the underlying aspects of renal ammonia transport as well as specific proteins with important roles in renal ammonia transport. PMID:17002591

  9. Revisiting the percolation phenomena in dielectric composites with conducting fillers

    NASA Astrophysics Data System (ADS)

    Zhang, Lin; Bass, Patrick; Cheng, Z.-Y.

    2014-07-01

    The composition (φ) dependence of the effective dielectric constant (ɛeff) on conductor-dielectric composites is widely described as ɛeff∝(φc-φ)-s. This relationship has been extensively used to fit experimental results for determining the percolation behavior (percolation threshold φc and power constant s). The equation was checked using experimental results from two 0-3 nanocomposite systems with uniform microstructures. It is found that the equation can be used to fit the experimental results, but the fitting constants (φc and s) do not reflect the percolation behavior: the values of both fitting constants are dependent on the frequency (f) and temperature selected. It is also found that the fitting constant φc increases with increasing frequency selected and it is believed that this arises from the critical phenomenon, ɛeff∝fγ-1, for composites close to the φc.

  10. Absorbing-state phase transitions on percolating lattices.

    PubMed

    Lee, Man Young; Vojta, Thomas

    2009-04-01

    We study nonequilibrium phase transitions of reaction-diffusion systems defined on randomly diluted lattices, focusing on the transition across the lattice percolation threshold. To develop a theory for this transition, we combine classical percolation theory with the properties of the supercritical nonequilibrium system on a finite-size cluster. In the case of the contact process, the interplay between geometric criticality due to percolation and dynamical fluctuations of the nonequilibrium system leads to a different universality class. The critical point is characterized by ultraslow activated dynamical scaling and accompanied by strong Griffiths singularities. To confirm the universality of this exotic scaling scenario we also study the generalized contact process with several (symmetric) absorbing states and we support our theory by extensive Monte Carlo simulations. PMID:19518178

  11. Percolation-based precursors of transitions in extended systems

    PubMed Central

    Rodríguez-Méndez, Víctor; Eguíluz M, Víctor M.; Hernández-García, Emilio; Ramasco, José J.

    2016-01-01

    Abrupt transitions are ubiquitous in the dynamics of complex systems. Finding precursors, i.e. early indicators of their arrival, is fundamental in many areas of science ranging from electrical engineering to climate. However, obtaining warnings of an approaching transition well in advance remains an elusive task. Here we show that a functional network, constructed from spatial correlations of the system’s time series, experiences a percolation transition way before the actual system reaches a bifurcation point due to the collective phenomena leading to the global change. Concepts from percolation theory are then used to introduce early warning precursors that anticipate the system’s tipping point. We illustrate the generality and versatility of our percolation-based framework with model systems experiencing different types of bifurcations and with Sea Surface Temperature time series associated to El Niño phenomenon. PMID:27412567

  12. Percolation-based precursors of transitions in extended systems.

    PubMed

    Rodríguez-Méndez, Víctor; Eguíluz M, Víctor M; Hernández-García, Emilio; Ramasco, José J

    2016-01-01

    Abrupt transitions are ubiquitous in the dynamics of complex systems. Finding precursors, i.e. early indicators of their arrival, is fundamental in many areas of science ranging from electrical engineering to climate. However, obtaining warnings of an approaching transition well in advance remains an elusive task. Here we show that a functional network, constructed from spatial correlations of the system's time series, experiences a percolation transition way before the actual system reaches a bifurcation point due to the collective phenomena leading to the global change. Concepts from percolation theory are then used to introduce early warning precursors that anticipate the system's tipping point. We illustrate the generality and versatility of our percolation-based framework with model systems experiencing different types of bifurcations and with Sea Surface Temperature time series associated to El Niño phenomenon. PMID:27412567

  13. Percolation-based precursors of transitions in extended systems

    NASA Astrophysics Data System (ADS)

    Rodríguez-Méndez, Víctor; Eguíluz M, Víctor M.; Hernández-García, Emilio; Ramasco, José J.

    2016-07-01

    Abrupt transitions are ubiquitous in the dynamics of complex systems. Finding precursors, i.e. early indicators of their arrival, is fundamental in many areas of science ranging from electrical engineering to climate. However, obtaining warnings of an approaching transition well in advance remains an elusive task. Here we show that a functional network, constructed from spatial correlations of the system’s time series, experiences a percolation transition way before the actual system reaches a bifurcation point due to the collective phenomena leading to the global change. Concepts from percolation theory are then used to introduce early warning precursors that anticipate the system’s tipping point. We illustrate the generality and versatility of our percolation-based framework with model systems experiencing different types of bifurcations and with Sea Surface Temperature time series associated to El Niño phenomenon.

  14. Conductivity in percolation networks with broad distributions of resistances

    NASA Astrophysics Data System (ADS)

    Machta, J.; Guyer, R. A.; Moore, S. M.

    1986-04-01

    Diluted resistor networks with a broad distribution of resistances are studied near the percolation threshold. A hierarchical model of the backbone of the percolation cluster is employed. Resistor networks are considered where the resistors, R, are chosen from a distribution having a power-law tail such that Prob\\{R>X\\}~X-α as X-->∞, 0<α<1. Such distributions arise naturally in con- tinuum percolation systems. The hierarchical model is studied numerically and using a renormalization-group transformation for the distribution of resistances. The conclusion is that the conductivity exponent t is the greater of to and (d-2)ν+1/α where to is the universal value of the conductivity exponent and ν is the correlation-length exponent. This result is in agreement with Straley's earlier predictions [J. Phys. C 15, 2333 (1982); 15, 2343 (1982)].

  15. Explosive percolation: Unusual transitions of a simple model

    NASA Astrophysics Data System (ADS)

    Bastas, N.; Giazitzidis, P.; Maragakis, M.; Kosmidis, K.

    In this paper we review the recent advances in explosive percolation, a very sharp phase transition first observed by Achlioptas et al. (2009). There a simple model was proposed, which changed slightly the classical percolation process so that the emergence of the spanning cluster is delayed. This slight modification turns out to have a great impact on the percolation phase transition. The resulting transition is so sharp that it was termed explosive, and it was at first considered to be discontinuous. This surprising fact stimulated considerable interest in “Achlioptas processes”. Later work, however, showed that the transition is continuous (at least for Achlioptas processes on Erdös networks), but with very unusual finite size scaling. We present a review of the field, indicate open “problems” and propose directions for future research.

  16. Fast and accurate database searches with MS-GF+Percolator.

    PubMed

    Granholm, Viktor; Kim, Sangtae; Navarro, José C F; Sjölund, Erik; Smith, Richard D; Käll, Lukas

    2014-02-01

    One can interpret fragmentation spectra stemming from peptides in mass-spectrometry-based proteomics experiments using so-called database search engines. Frequently, one also runs post-processors such as Percolator to assess the confidence, infer unique peptides, and increase the number of identifications. A recent search engine, MS-GF+, has shown promising results, due to a new and efficient scoring algorithm. However, MS-GF+ provides few statistical estimates about the peptide-spectrum matches, hence limiting the biological interpretation. Here, we enabled Percolator processing for MS-GF+ output and observed an increased number of identified peptides for a wide variety of data sets. In addition, Percolator directly reports p values and false discovery rate estimates, such as q values and posterior error probabilities, for peptide-spectrum matches, peptides, and proteins, functions that are useful for the whole proteomics community. PMID:24344789

  17. Fast and accurate database searches with MS-GF+Percolator

    SciTech Connect

    Granholm, Viktor; Kim, Sangtae; Navarro, Jose' C.; Sjolund, Erik; Smith, Richard D.; Kall, Lukas

    2014-02-28

    To identify peptides and proteins from the large number of fragmentation spectra in mass spectrometrybased proteomics, researches commonly employ so called database search engines. Additionally, postprocessors like Percolator have been used on the results from such search engines, to assess confidence, infer peptides and generally increase the number of identifications. A recent search engine, MS-GF+, has previously been showed to out-perform these classical search engines in terms of the number of identified spectra. However, MS-GF+ generates only limited statistical estimates of the results, hence hampering the biological interpretation. Here, we enabled Percolator-processing for MS-GF+ output, and observed an increased number of identified peptides for a wide variety of datasets. In addition, Percolator directly reports false discovery rate estimates, such as q values and posterior error probabilities, as well as p values, for peptide-spectrum matches, peptides and proteins, functions useful for the whole proteomics community.

  18. Connectivity percolation in suspensions of attractive square-well spherocylinders

    NASA Astrophysics Data System (ADS)

    Dixit, Mohit; Meyer, Hugues; Schilling, Tanja

    2016-01-01

    We have studied the connectivity percolation transition in suspensions of attractive square-well spherocylinders by means of Monte Carlo simulation and connectedness percolation theory. In the 1980s the percolation threshold of slender fibers has been predicted to scale as the fibers' inverse aspect ratio [Phys. Rev. B 30, 3933 (1984), 10.1103/PhysRevB.30.3933]. The main finding of our study is that the attractive spherocylinder system reaches this inverse scaling regime at much lower aspect ratios than found in suspensions of hard spherocylinders. We explain this difference by showing that third virial corrections of the pair connectedness functions, which are responsible for the deviation from the scaling regime, are less important for attractive potentials than for hard particles.

  19. Connecting core percolation and controllability of complex networks.

    PubMed

    Jia, Tao; Pósfai, Márton

    2014-01-01

    Core percolation is a fundamental structural transition in complex networks related to a wide range of important problems. Recent advances have provided us an analytical framework of core percolation in uncorrelated random networks with arbitrary degree distributions. Here we apply the tools in analysis of network controllability. We confirm analytically that the emergence of the bifurcation in control coincides with the formation of the core and the structure of the core determines the control mode of the network. We also derive the analytical expression related to the controllability robustness by extending the deduction in core percolation. These findings help us better understand the interesting interplay between the structural and dynamical properties of complex networks. PMID:24946797

  20. Correlated percolation models of structured habitat in ecology

    NASA Astrophysics Data System (ADS)

    Huth, Géraldine; Lesne, Annick; Munoz, François; Pitard, Estelle

    2014-12-01

    Percolation offers acknowledged models of random media when the relevant medium characteristics can be described as a binary feature. However, when considering habitat modeling in ecology, a natural constraint comes from nearest-neighbor correlations between the suitable/unsuitable states of the spatial units forming the habitat. Such constraints are also relevant in the physics of aggregation where underlying processes may lead to a form of correlated percolation. However, in ecology, the processes leading to habitat correlations are in general not known or very complex. As proposed by Hiebeler (2000), these correlations can be captured in a lattice model by an observable aggregation parameter q, supplementing the density p of suitable sites. We investigate this model as an instance of correlated percolation. We analyze the phase diagram of the percolation transition and compute the cluster size distribution, the pair-connectedness function C(r) and the correlation function g(r). We find that while g(r) displays a power-law decrease associated with long-range correlations in a wide domain of parameter values, critical properties are compatible with the universality class of uncorrelated percolation. We contrast the correlation structures obtained respectively for the correlated percolation model and for the Ising model, and show that the diversity of habitat configurations generated by the Hiebeler model is richer than the archetypal Ising model. We also find that emergent structural properties are peculiar to the implemented algorithm, leading to questioning the notion of a well-defined model of aggregated habitat. We conclude that the choice of model and algorithm has strong consequences on what insights ecological studies can get using such models of species habitat.

  1. Gas transport through magma near the percolation threshold (Invited)

    NASA Astrophysics Data System (ADS)

    Llewellin, E. W.; Blower, J.; Leslie, D.

    2009-12-01

    Explosive silicic eruptions may simultaneously produce both tube pumice - containing highly-elongate vesicles - and pumice containing sub-spherical vesicles. This has been cited as evidence for strain localization within the volcanic conduit: in a relatively-undeformed axial ‘plug’ bubbles are spherical (regime 1) whilst near the conduit margin rapidly-shearing magma bears elongate bubbles (regime 2). Published numerical studies support this model and indicate that bubbly-magma rheology or viscous heating may be responsible for strain localization. The difference in bubble morphology in these two regimes has important consequences for magma permeability. We present the results of fluid dynamic simulations which quantify the anisotropy of permeability in regime 2 as a function of gas volume fraction and bubble aspect ratio. In this regime, we find that vertical permeability may be many times greater than radial permeability, and that permeability anisotropy is most pronounced near the percolation threshold. We further use a network model to quantify the development of permeability in regime 1. In the case where the predominantly vertical expansion of the magma is slow compared with bubble relaxation time, we find that permeability is, again, anisotropic, but that radial permeability dominates. This effect is also most pronounced near the percolation threshold, and percolation is expected to occur radially before vertical percolation occurs. Our findings imply that gas transport in regime 1 is predominantly radial, whilst vertical gas transport is favoured in regime 2. Consequently, near the percolation threshold, conditions are appropriate for effective degassing of the central magma plug as gas permeates radially to the conduit margin and then vertically upwards. Repeated cycles of percolation, radial gas loss and densification may degas the central magma plug without the development of large gas volume fractions.

  2. Recycling Decisions and Green Design.

    ERIC Educational Resources Information Center

    Lave, Lester B.; And Others

    1994-01-01

    Explores the facts and perceptions regarding recycling, what can be done to make products more environmentally compatible, and how to think about recycling decisions in a more helpful way. (Contains 39 references.) (MDH)

  3. Percolation models for boiling and bubble growth in porous media

    SciTech Connect

    Yortsos, Y.C.

    1991-05-01

    We analyze the liquid-to-vapor phase change in single-component fluids in porous media at low superheats. Conditions typical to steam injection in porous media are taken. We examine nucleation, phase equilibria and their stability, and the growth of vapor bubbles. Effects of pore structure are emphasized. It is shown that at low supersaturations, bubble growth can be described as a percolation process. In the absence of spatial gradients, macroscopic flow properties are calculated in terms of nucleation parameters. A modification of gradient percolation is also proposed in the case of spatial temperature gradients, when solid conduction predominates. 22 refs., 10 figs., 1 tab.

  4. Interaction between a percolation network and a cubic cavity

    NASA Astrophysics Data System (ADS)

    Mourzenko, Valeri; Adler, Pierre; Thovert, Jean Francois; Sangaré, Daouda

    2015-04-01

    The intersection between a percolating network of fractures modeled as polygons and a cubic cavity is important for the safe storage of wastes in a fractured medium. The cavities where the wastes are stored should not intersect the percolating network of fractures which may exist, or these cavities should not enable a fracture network to percolate. The fractures are hexagons inscribed in a circle of radius R which are uniformly distributed in space and isotropically oriented. Nfr is the number of fractures generated in a finite unit cell Omega of size L^3. The fracture density is conveniently represented by the dimensionless density rho ' which is the average number of intersections per fracture with the other fractures [1]. In addition, a cubic cavity C formed by six squares inscribed in a circle of radius Rs is randomly located in Omega. N spatially periodic networks are generated. Generally, N is equal to 500. Among these N networks, Np percolate and the cavity intersects one or more fractures in Nrc realizations; no fracture-cavity intersection occurs in Nnrc realizations. Moreover, when the network alone does not percolate (which occurs in Nnp realisations), the set composed by the hexagons and the cavity percolates Nnpc times. These quantities and the corresponding probabilities were systematically calculated as functions of L' = L/R , R' s = R_s/R and rho'. An important quantity is the conditional probability Pic that the percolating cluster intersects the cavity when it exists. It could be extrapolated to an infinite cell size L'. This conditional probability is an increasing function of rho' and of R' _s. The probability Pi that an object X intersects the fracture network with the density rho is given by the expression Pi=1-exp(- rho V) where V is the excluded volume for the object X and a fracture. This quantity is obtained for a cube. This prediction is in good agreement with the conditional probability Pic for large rho' or small R_s. However, Pi and

  5. Scaling of the spanning threshold in gradient percolation

    NASA Astrophysics Data System (ADS)

    Paterson, Lincoln

    2015-02-01

    A simple and fast way to apply correlations in percolation simulations is to apply a uniform gradient to the occupancy probabilities. For small networks, exact results are presented here for the spanning thresholds in site percolation with a gradient for networks up to 4 ×4 in two dimensions and 2 ×2 ×2 in three dimensions. Numerical results are provided for larger networks that extrapolate to a linear modification of the threshold proportional to the gradient for moderate values of the gradient.

  6. Truncated Connectivities in a Highly Supercritical Anisotropic Percolation Model

    NASA Astrophysics Data System (ADS)

    Couto, Rodrigo G.; de Lima, Bernardo N. B.; Sanchis, Rémy

    2013-12-01

    We consider an anisotropic bond percolation model on , with p=( p h , p v )∈[0,1]2, p v > p h , and declare each horizontal (respectively vertical) edge of to be open with probability p h (respectively p v ), and otherwise closed, independently of all other edges. Let with 0< x 1< x 2, and . It is natural to ask how the two point connectivity function behaves, and whether anisotropy in percolation probabilities implies the strict inequality . In this note we give an affirmative answer in the highly supercritical regime.

  7. Directed compact percolation near a damp wall with biased growth

    NASA Astrophysics Data System (ADS)

    Lonsdale, H.; Owczarek, A. L.

    2012-11-01

    The model of directed compact percolation near a damp wall is generalized to allow for a bias in the growth of a cluster, either towards or away from the wall. The percolation probability for clusters beginning with seed width m, any distance from the wall, is derived exactly by solving the associated recurrences. It is found that the general biased case near a damp wall leads to a critical exponent β = 1, in line with the dry biased case, which differs from the unbiased damp/dry exponent β = 2.

  8. Remnant percolative disorder in highly-cured networks

    SciTech Connect

    Adolf, D.; Hance, B.; Martin, J.E. )

    1993-05-24

    The authors have previously reported viscoelastic measurements demonstrating that fully-cured networks and critical gels exhibit similar relaxation spectra, implying that fully-cured networks are somewhat ill- connected. Here, they present restricted valence percolation simulations of networks well beyond the percolation transition that explicitly display remnant disorder over length scales less than the correlation length of the network. They conclude that the topology of highly-cured networks is not well described by a regular three- dimensional tennis net but is ill-connected over length scales that correspond to relaxation modes of practical interest.

  9. Flux pinning and percolation in high-Tc oxide superconductors

    NASA Astrophysics Data System (ADS)

    Matsushita, Teruo; Ni, Baorong; Yamafuji, Kaoru

    Critical current characteristics in quench and melt growth (QMG) processed Y-Ba-Cu-O are investigated by ac inductive measurements. The critical current in these samples is percolative as is observed in sintered materials. However, this percolative behavior is not caused by weak-link grain boundaries but seems to be mainly attributed to layers of nonsuperconducting solidified melt. The experimental result of magnetization critical current density is compared with the theoretical estimate from the effective medium theory. It is also found that the shielding current with very high density flows locally inside the sample. Candidates for the dominant pinning centers in QMG processed samples are also discussed.

  10. Accurate and Sensitive Peptide Identification with Mascot Percolator

    PubMed Central

    Brosch, Markus; Yu, Lu; Hubbard, Tim; Choudhary, Jyoti

    2009-01-01

    Sound scoring methods for sequence database search algorithms such as Mascot and Sequest are essential for sensitive and accurate peptide and protein identifications from proteomic tandem mass spectrometry data. In this paper, we present a software package that interfaces Mascot with Percolator, a well performing machine learning method for rescoring database search results, and demonstrate it to be amenable for both low and high accuracy mass spectrometry data, outperforming all available Mascot scoring schemes as well as providing reliable significance measures. Mascot Percolator can be readily used as a stand alone tool or integrated into existing data analysis pipelines. PMID:19338334

  11. Mirrorless lasing from light emitters in percolating clusters

    NASA Astrophysics Data System (ADS)

    Burlak, Gennadiy; Rubo, Y. G.

    2015-07-01

    We describe the lasing effect in the three-dimensional percolation system, where the percolating cluster is filled by active media composed by light emitters excited noncoherently. We show that, due to the presence of a topologically nontrivial photonic structure, the stimulated emission is modified with respect to both conventional and random lasers. The time dynamics and spectra of the lasing output are studied numerically with finite-difference time-domain approach. The Fermat principle and Monte Carlo approach are applied to characterize the optimal optical path and interconnection between the radiating emitters. The spatial structure of the laser mode is found by a long-time FDTD simulation.

  12. Multifractality of self-avoiding walks on percolation clusters.

    PubMed

    Blavatska, Viktoria; Janke, Wolfhard

    2008-09-19

    We consider self-avoiding walks on the backbone of percolation clusters in space dimensions d=2,3,4. Applying numerical simulations, we show that the whole multifractal spectrum of singularities emerges in exploring the peculiarities of the model. We obtain estimates for the set of critical exponents that govern scaling laws of higher moments of the distribution of percolation cluster sites visited by self-avoiding walks, in a good correspondence with an appropriately summed field-theoretical epsilon=6-d expansion [H.-K. Janssen and O. Stenull, Phys. Rev. E 75, 020801(R) (2007)10.1103/PhysRevE.75.020801]. PMID:18851389

  13. Helium-Recycling Plant

    NASA Technical Reports Server (NTRS)

    Cook, Joseph

    1996-01-01

    Proposed system recovers and stores helium gas for reuse. Maintains helium at 99.99-percent purity, preventing water vapor from atmosphere or lubricating oil from pumps from contaminating gas. System takes in gas at nearly constant low back pressure near atmospheric pressure; introduces little or no back pressure into source of helium. Concept also extended to recycling of other gases.

  14. Recycled Insect Models

    ERIC Educational Resources Information Center

    Rule, Audrey C.; Meyer, Mary Ann

    2007-01-01

    This article presents an engaging activity in which high school students use a dichotomous key to guide the creation and classification of model insects from recycled plastic lids and containers. Besides teaching the use of a dichotomous key and the effect of evolutionary descent upon groupings of organisms, this activity focuses on an…

  15. RECYCLABILITY INDEX FOR AUTOMOBILES

    EPA Science Inventory

    The project's purpose is to create a rating system for the ecological impacts of vehicles at the end of their life based on recyclability, toxic material content, and ultimate disposal. Each year, 10-11 million vehicles are retired from service in the United States. The vehi...

  16. Fuels from Recycling Systems

    ERIC Educational Resources Information Center

    Tillman, David A.

    1975-01-01

    Three systems, operating at sufficient scale, produce fuels that may be alternatives to oil and gas. These three recycling systems are: Black Clawson Fiberclaim, Franklin, Ohio; Union Carbide, South Charleston, West Virginia; and Union Electric, St. Louis, Missouri. These produce a wet fuel, a pyrolytic gas, and a dry fuel, respectively. (BT)

  17. Recycling Study Guide.

    ERIC Educational Resources Information Center

    Hallowell, Anne; And Others

    This study guide was designed to help teachers and students understand the problems surrounding solid wastes. It includes an overview of solid waste and recycling, a glossary, suggested activities and a list of resource publications, audiovisual materials and organizations. There are 19 activity suggestions included in this guide designed for use…

  18. The Recycle Team.

    ERIC Educational Resources Information Center

    Scott, Roger; And Others

    This guide provides lessons that enable students to learn how important it is for each of us to take care of the environment by minimizing the problems caused by too much trash. In the 10 lessons included here, students and their families learn how they can be part of the solution by practicing source reduction and by reusing, recycling, and…

  19. Ammonia emissions from cattle feeding operations.

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Ammonia is a colorless gas with an pungent odor that occurs naturally in trace amounts in the atmosphere, where it is the dominant base. Ammonia is produced during the decomposition of livestock manure. There is concern about atmospheric ammonia because of its potential effects on air quality, wat...

  20. 46 CFR 154.1760 - Liquid ammonia.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Liquid ammonia. 154.1760 Section 154.1760 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR....1760 Liquid ammonia. The master shall ensure that no person sprays liquid ammonia into a cargo...

  1. 46 CFR 154.1760 - Liquid ammonia.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Liquid ammonia. 154.1760 Section 154.1760 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR....1760 Liquid ammonia. The master shall ensure that no person sprays liquid ammonia into a cargo...

  2. 46 CFR 154.1760 - Liquid ammonia.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Liquid ammonia. 154.1760 Section 154.1760 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR....1760 Liquid ammonia. The master shall ensure that no person sprays liquid ammonia into a cargo...

  3. 46 CFR 154.1760 - Liquid ammonia.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Liquid ammonia. 154.1760 Section 154.1760 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR....1760 Liquid ammonia. The master shall ensure that no person sprays liquid ammonia into a cargo...

  4. 46 CFR 154.1760 - Liquid ammonia.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Liquid ammonia. 154.1760 Section 154.1760 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR....1760 Liquid ammonia. The master shall ensure that no person sprays liquid ammonia into a cargo...

  5. 27 CFR 21.96 - Ammonia, aqueous.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Ammonia, aqueous. 21.96 Section 21.96 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT... Ammonia, aqueous. (a) Alkalinity. Strongly alkaline to litmus. (b) Ammonia content. 27 to 30 percent...

  6. Update on cerebral uptake of blood ammonia.

    PubMed

    Sørensen, Michael

    2013-06-01

    Ammonia is believed to play a key role in the development of hepatic encephalopathy (HE) with increased formation of glutamine playing a central role. It has been debated whether blood ammonia enters the brain by passive diffusion and/or active transport by ion-transporters and that changes in blood pH could affect the blood-to-brain transfer of ammonia. It has also been proposed that the permeability-surface area product for ammonia across the blood-brain barrier (PSBBB) should be increased in cirrhosis and HE. In the present paper it is argued that changes in blood pH does not alter PSBBB for ammonia and the question of passive diffusion versus active transport of ammonia remains unresolved. Furthermore, recent studies do not find evidence for increased PSBBB for ammonia in cirrhosis. The main determent for cerebral uptake of blood ammonia (i.e. flux) is the arterial blood ammonia concentration. This means that the only way to protect the brain from hyperammonemia is by lowering blood ammonia, inhibit cerebral uptake of ammonia, or by manipulating cerebral ammonia metabolism so that less glutamine is produced. PMID:23479402

  7. Inhibiting Wet Oxidation of Ammonia

    NASA Technical Reports Server (NTRS)

    Onisko, D. B. L.

    1985-01-01

    Simple modification of wet-oxidation process for treating organicwaste reduces loss of fixed nitrogen, potentially valuable byproduct of process. Addition of sufficient sulfuric acid to maintain reaction pH below 3 greatly reduces oxidation of ammonia to free nitrogen. No equipment modification required.

  8. Hydrogen production using ammonia borane

    SciTech Connect

    Hamilton, Charles W; Baker, R. Thomas; Semelsberger, Troy A; Shrestha, Roshan P

    2013-12-24

    Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.

  9. Ammonia excretion by Azobacter chroococcum

    SciTech Connect

    Narula, N.; Lakshminarayana, K.; Tauro, P.

    1981-02-01

    In recent years, research has focused attention on the development of biological systems for nitrogen fixation. In this report, two strains of Azotobacter chroococcum are identified which can excrete as much as 45 mg ammonia/ml of the culture broth in a sucrose supplemented synthetic medium.

  10. Recycling Behavior: A Multidimensional Approach

    ERIC Educational Resources Information Center

    Meneses, Gonzalo Diaz; Palacio, Asuncion Beerli

    2005-01-01

    This work centers on the study of consumer recycling roles to examine the sociodemographic and psychographic profile of the distribution of recycling tasks and roles within the household. With this aim in mind, an empirical work was carried out, the results of which suggest that recycling behavior is multidimensional and comprises the undertaking…

  11. Recycling of the #5 polymer.

    PubMed

    Xanthos, Marino

    2012-08-10

    Polypropylene (PP) is a widely used plastic with consumer applications ranging from food packaging to automotive parts, including car battery casings. To differentiate it from other recyclable plastics, it is designated as #5. Here, the factors contributing to PP recycling rates are briefly reviewed. Considerations include collection and separation efficiency, processing chemistry, and market dynamics for the products derived from recyclates. PMID:22879510

  12. Tunable Percolation in Semiconducting Binary Polymer Nanoparticle Glasses.

    PubMed

    Renna, Lawrence A; Bag, Monojit; Gehan, Timothy S; Han, Xu; Lahti, Paul M; Maroudas, Dimitrios; Venkataraman, D

    2016-03-10

    Binary polymer nanoparticle glasses provide opportunities to realize the facile assembly of disparate components, with control over nanoscale and mesoscale domains, for the development of functional materials. This work demonstrates that tunable electrical percolation can be achieved through semiconducting/insulating polymer nanoparticle glasses by varying the relative percentages of equal-sized nanoparticle constituents of the binary assembly. Using time-of-flight charge carrier mobility measurements and conducting atomic force microscopy, we show that these systems exhibit power law scaling percolation behavior with percolation thresholds of ∼24-30%. We develop a simple resistor network model, which can reproduce the experimental data, and can be used to predict percolation trends in binary polymer nanoparticle glasses. Finally, we analyze the cluster statistics of simulated binary nanoparticle glasses, and characterize them according to their predominant local motifs as (p(i), p(1-i))-connected networks that can be used as a supramolecular toolbox for rational material design based on polymer nanoparticles. PMID:26854924

  13. Percolation thresholds on planar Euclidean relative-neighborhood graphs

    NASA Astrophysics Data System (ADS)

    Melchert, O.

    2013-04-01

    In the present article, statistical properties regarding the topology and standard percolation on relative neighborhood graphs (RNGs) for planar sets of points, considering the Euclidean metric, are put under scrutiny. RNGs belong to the family of “proximity graphs”; i.e., their edgeset encodes proximity information regarding the close neighbors for the terminal nodes of a given edge. Therefore they are, e.g., discussed in the context of the construction of backbones for wireless ad hoc networks that guarantee connectedness of all underlying nodes. Here, by means of numerical simulations, we determine the asymptotic degree and diameter of RNGs and we estimate their bond and site percolation thresholds, which were previously conjectured to be nontrivial. We compare the results to regular 2D graphs for which the degree is close to that of the RNG. Finally, we deduce the common percolation critical exponents from the RNG data to verify that the associated universality class is that of standard 2D percolation.

  14. Comment on the conductivity exponent in continuum percolation

    NASA Astrophysics Data System (ADS)

    Machta, J.

    1988-05-01

    The field theory introduced by Lubensky and Tremblay [Phys. Rev. B 34, 3408 (1986)] for continuum percolation is reanalyzed. Dynamical exponents are found which agree with those found by Straley [J. Phys. C 15, 2343 (1982)] and Machta et al. [Phys. Rev. B 33, 4818 (1986)] using a nodes-links-blobs approach.

  15. A Simple Soil Percolation Test Device for Field Environmentalists

    ERIC Educational Resources Information Center

    Smith, William H.; Stark, Phillip E.

    1977-01-01

    A primary responsibility of field environmental health workers is evaluation of individual sewage disposal system sites. The authors of this article developed a practical, accurate, and inexpensive measurement device for obtaining reliable percolation test results. Directions for the construction and use of the device are detailed. Drawings…

  16. The Use of Percolating Filters in Teaching Ecology.

    ERIC Educational Resources Information Center

    Gray, N. F.

    1982-01-01

    Using percolating filters (components of sewage treatment process) reduces problems of organization, avoids damage to habitats, and provides a local study site for field work or rapid collection of biological material throughout the year. Component organisms are easily identified and the habitat can be studied as a simple or complex system.…

  17. Water-network percolation transitions in hydrated yeast

    NASA Astrophysics Data System (ADS)

    Sokołowska, Dagmara; Król-Otwinowska, Agnieszka; Mościcki, Józef K.

    2004-11-01

    We discovered two percolation processes in succession in dc conductivity of bulk baker’s yeast in the course of dehydration. Critical exponents characteristic for the three-dimensional network for heavily hydrated system, and two dimensions in the light hydration limit, evidenced a dramatic change of the water network dimensionality in the dehydration process.

  18. The transport exponent in percolation models with additional loops

    NASA Astrophysics Data System (ADS)

    Babalievski, F.

    1994-10-01

    Several percolation models with additional loops were studied. The transport exponents for these models were estimated numerically by means of a transfer-matrix approach. It was found that the transport exponent has a drastically changed value for some of the models. This result supports some previous numerical studies on the vibrational properties of similar models (with additional loops).

  19. The persistent percolation of single-stream voids

    NASA Astrophysics Data System (ADS)

    Falck, B.; Neyrinck, M. C.

    2015-07-01

    We study the nature of voids defined as single-stream regions that have not undergone shell-crossing. We use ORIGAMI to determine the cosmic web morphology of each dark matter particle in a suite of cosmological N-body simulations, which explicitly calculates whether a particle has crossed paths with others along multiple sets of axes and does not depend on a parameter or smoothing scale. The theoretical picture of voids is that of expanding underdensities with borders defined by shell-crossing. We find instead that locally underdense single-stream regions are not bounded on all sides by multi-stream regions, thus they percolate, filling the simulation volume; we show that the set of multi-stream particles also percolates. This percolation persists to high resolution, where the mass fraction of single-stream voids is low, because the volume fraction remains high; we speculate on the fraction of collapsed mass in the continuum limit of infinite resolution. By introducing a volume threshold parameter to define underdense void `cores', we create a catalogue of ORIGAMI voids which consist entirely of single-stream particles and measure their percolation properties, volume functions, and average densities.

  20. Beyond the locally treelike approximation for percolation on real networks

    NASA Astrophysics Data System (ADS)

    Radicchi, Filippo; Castellano, Claudio

    2016-03-01

    Theoretical attempts proposed so far to describe ordinary percolation processes on real-world networks rely on the locally treelike ansatz. Such an approximation, however, holds only to a limited extent, because real graphs are often characterized by high frequencies of short loops. We present here a theoretical framework able to overcome such a limitation for the case of site percolation. Our method is based on a message passing algorithm that discounts redundant paths along triangles in the graph. We systematically test the approach on 98 real-world graphs and on synthetic networks. We find excellent accuracy in the prediction of the whole percolation diagram, with significant improvement with respect to the prediction obtained under the locally treelike approximation. Residual discrepancies between theory and simulations do not depend on clustering and can be attributed to the presence of loops longer than three edges. We present also a method to account for clustering in bond percolation, but the improvement with respect to the method based on the treelike approximation is much less apparent.

  1. Percolation induced heat transfer in deep unsaturated zones

    USGS Publications Warehouse

    Lu, N.; LeCain, G.D.

    2003-01-01

    Subsurface temperature data from a borehole located in a desert wash were measured and used to delineate the conductive and advective heat transfer regimes, and to estimate the percolation quantity associated with the 1997-1998 El Ni??no precipitation. In an arid environment, conductive heat transfer dominates the variation of shallow subsurface temperature most of the time, except during sporadic precipitation periods. The subsurface time-varying temperature due to conductive heat transfer is highly correlated with the surface atmospheric temperature variation, whereas temperature variation due to advective heat transfer is strongly correlated with precipitation events. The advective heat transfer associated with precipitation and infiltration is the focus of this paper. Disruptions of the subsurface conductive temperature regime, associated with the 1997-1998 El Ni??no precipitation, were detected and used to quantify the percolation quantity. Modeling synthesis using a one-dimensional coupled heat and unsaturated flow model indicated that a percolation per unit area of 0.7 to 1.3 m height of water in two weeks during February 1998 was responsible for the observed temperature deviations down to a depth of 35.2 m. The reported study demonstrated quantitatively, for the first time, that the near surface temperature variation due to advective heat transfer can be significant at a depth greater than 10 m in unsaturated soils and can be used to infer the percolation amount in thick unsaturated soils.

  2. Network representation of pore scale imagery for percolation models

    NASA Astrophysics Data System (ADS)

    Klise, K. A.; McKenna, S. A.; Read, E.; Karpyn, Z. T.; Celauro, J.

    2012-12-01

    Multiphase flow under capillary dominated flow regimes is driven by an intricate relationship between pore geometry, material and fluid properties. In this research, high-resolution micro-computed tomography (CT) imaging experiments are used to investigate structural and surface properties of bead packs, and how they influence percolation pathways. Coreflood experiments use a mix of hydrophilic and hydrophobic beads to track the influence of variable contact angle on capillary flow. While high-resolution CT images can render micron scale representation of the pore space, data must be upscaled to capture pore and pore throat geometry for use in percolation models. In this analysis, the pore space is upscaled into a network representation based on properties of the medial axis. Finding the medial axis using micron scale images is computationally expensive. Here, we compare the efficiency and accuracy of medial axes using erosion-based and watershed algorithms. The resulting network representation is defined as a ball-and-stick model which represents pores and pore throats. The ball-and-stick model can be further reduced by eliminating sections of the network that fall below a capillary pressure threshold. In a system of mixed hydrophilic and hydrophobic beads, capillary pressure can change significantly throughout the network based on the interaction between surface and fluid properties. The upscaled network representations are used in percolation models to estimate transport pathway. Current results use a basic percolation model that sequentially fills neighboring pores with the highest potential. Future work will expand the percolation model to include additional mechanics, such as trapping, vacating pores, and viscous fingering. Results from the coreflood experiments will be used to validate upscaling techniques and percolation models. Preliminary results show that the relative strength of water-wet and oil-wet surfaces has a significant impact on percolation

  3. Percolation exponents and thresholds obtained from the nearly ideal continuum percolation system graphite-boron nitride

    SciTech Connect

    Wu, J.; McLachlan, D.S.

    1997-07-01

    Compressed disks made from graphite and, its mechanical but not electrical isomorph, boron nitride as well as graphite-boron nitride powders, undergoing compression, are nearly ideal continuum percolation systems, as the ratio of their conductivities is nearly 10{sup {minus}18} and the scatter of the experimental points near the critical volume fraction {phi}{sub c} is very small. The following measurements, with the characteristic exponent(s) in brackets, are made on some or all of the samples in (axial) and at right angles (radial) to the direction of compression, as a function of the volume fraction of graphite ({phi}); dc conductivity (s and t), dielectric constant (s), magnetoresistivity (t{sub {perpendicular}}), and noise power (K). The noise power is also measured as function of resistance (w) and volume (b{sup {prime}}). The {phi}{sub c}{close_quote}s obtained for all measurements are consistent and explicable. The results for the exponents are less well understood but, where possible, these results are compared with theoretical predictions and previous experiments. The reasons for the nonuniversality of t are clarified. {copyright} {ital 1997} {ital The American Physical Society}

  4. Conductive paint-filled cement paste sensor for accelerated percolation

    NASA Astrophysics Data System (ADS)

    Laflamme, Simon; Pinto, Irvin; Saleem, Hussam S.; Elkashef, Mohamed; Wang, Kejin; Cochran, Eric

    2015-04-01

    Cementitious-based strain sensors can be used as robust monitoring systems for civil engineering applications, such as road pavements and historic structures. To enable large-scale deployments, the fillers used in creating a conductive material must be inexpensive and easy to mix homogeneously. Carbon black (CB) particles constitute a promising filler due to their low cost and ease of dispersion. However, a relatively high quantity of these particles needs to be mixed with cement in order to reach the percolation threshold. Such level may influence the physical properties of the cementitious material itself, such as compressive and tensile strengths. In this paper, we investigate the possibility of utilizing a polymer to create conductive chains of CB more quickly than in a cementitious-only medium. This way, while the resulting material would have a higher conductivity, the percolation threshold would be reached with fewer CB particles. Building on the principle that the percolation threshold provides great sensing sensitivity, it would be possible to fabricate sensors using less conducting particles. We present results from a preliminary investigation comparing the utilization of a conductive paint fabricated from a poly-Styrene-co-Ethylene-co-Butylene-co-Styrene (SEBS) polymer matrix and CB, and CB-only as fillers to create cementitious sensors. Preliminary results show that the percolation threshold can be attained with significantly less CB using the SEBS+CB mix. Also, the study of the strain sensing properties indicates that the SEBS+CB sensor has a strain sensitivity comparable to the one of a CB-only cementitious sensor when comparing specimens fabricated at their respective percolation thresholds.

  5. COPPER CABLE RECYCLING TECHNOLOGY

    SciTech Connect

    Chelsea Hubbard

    2001-05-01

    The United States Department of Energy (DOE) continually seeks safer and more cost-effective technologies for use in deactivation and decommissioning (D&D) of nuclear facilities. The Deactivation and Decommissioning Focus Area (DDFA) of the DOE's Office of Science and Technology (OST) sponsors large-scale demonstration and deployment projects (LSDDPs). At these LSDDPs, developers and vendors of improved or innovative technologies showcase products that are potentially beneficial to the DOE's projects and to others in the D&D community. Benefits sought include decreased health and safety risks to personnel and the environment, increased productivity, and decreased costs of operation. The Idaho National Engineering and Environmental Laboratory (INEEL) generated a list of statements defining specific needs and problems where improved technology could be incorporated into ongoing D&D tasks. One such need is to reduce the volume of waste copper wire and cable generated by D&D. Deactivation and decommissioning activities of nuclear facilities generates hundreds of tons of contaminated copper cable, which are sent to radioactive waste disposal sites. The Copper Cable Recycling Technology separates the clean copper from contaminated insulation and dust materials in these cables. The recovered copper can then be reclaimed and, more importantly, landfill disposal volumes can be reduced. The existing baseline technology for disposing radioactively contaminated cables is to package the cables in wooden storage boxes and dispose of the cables in radioactive waste disposal sites. The Copper Cable Recycling Technology is applicable to facility decommissioning projects at many Department of Energy (DOE) nuclear facilities and commercial nuclear power plants undergoing decommissioning activities. The INEEL Copper Cable Recycling Technology Demonstration investigated the effectiveness and efficiency to recycle 13.5 tons of copper cable. To determine the effectiveness of separating

  6. Fluorographene based Ultrasensitive Ammonia Sensor

    PubMed Central

    Tadi, Kiran Kumar; Pal, Shubhadeep; Narayanan, Tharangattu N.

    2016-01-01

    Single molecule detection using graphene can be brought by tuning the interactions via specific dopants. Electrostatic interaction between the most electronegative element fluorine (F) and hydrogen (H) is one of the strong interactions in hydrogen bonding, and here we report the selective binding of ammonia/ammonium with F in fluorographene (FG) resulting to a change in the impedance of the system. Very low limit of detection value of ~0.44 pM with linearity over wide range of concentrations (1 pM–0.1 μM) is achieved using the FG based impedance sensor, andthisscreen printed FG sensor works in both ionized (ammonium) and un-ionized ammonia sensing platforms. The interaction energies of FG and NH3/NH4+ are evaluated using density functional theory calculations and the interactions are mapped. Here FGs with two different amounts of fluorinecontents −~5 atomic% (C39H16F2) and ~24 atomic% (C39H16F12) - are theoretically and experimentally studied for selective, high sensitive and ultra-low level detection of ammonia. Fast responding, high sensitive, large area patternable FG based sensor platform demonstrated here can open new avenues for the development of point-of-care devices and clinical sensors. PMID:27142522

  7. Planar waveguide sensor of ammonia

    NASA Astrophysics Data System (ADS)

    Rogoziński, Roman; Tyszkiewicz, Cuma; Karasiński, Paweł; Izydorczyk, Weronika

    2015-12-01

    The paper presents the concept of forming ammonia sensor based on a planar waveguide structure. It is an amplitude sensor produced on the basis of the multimode waveguide. The technological base for this kind of structure is the ion exchange method and the sol-gel method. The planar multimode waveguide of channel type is produced in glass substrate (soda-lime glass of Menzel-Glaser company) by the selective Ag+↔Na+ ion exchange. On the surface of the glass substrate a porous (~40%) silica layer is produced by the sol-gel method. This layer is sensitized to the presence of ammonia in the surrounding atmosphere by impregnation with Bromocresol Purple (BCP) dye. Therefore it constitutes a sensor layer. Spectrophotometric tests carried out showed about 50% reduction of cross-transmission changes of such sensor layer for a wave λ=593 nm caused by the presence of 25% ammonia water vapor in its ambience. The radiation source used in this type of sensor structure is a light emitting diode LED. The gradient channel waveguide is designed for frontal connection (optical glue) with a standard multimode telecommunications waveguide 62.5/125μm.

  8. Fluorographene based Ultrasensitive Ammonia Sensor

    NASA Astrophysics Data System (ADS)

    Tadi, Kiran Kumar; Pal, Shubhadeep; Narayanan, Tharangattu N.

    2016-05-01

    Single molecule detection using graphene can be brought by tuning the interactions via specific dopants. Electrostatic interaction between the most electronegative element fluorine (F) and hydrogen (H) is one of the strong interactions in hydrogen bonding, and here we report the selective binding of ammonia/ammonium with F in fluorographene (FG) resulting to a change in the impedance of the system. Very low limit of detection value of ~0.44 pM with linearity over wide range of concentrations (1 pM–0.1 μM) is achieved using the FG based impedance sensor, andthisscreen printed FG sensor works in both ionized (ammonium) and un-ionized ammonia sensing platforms. The interaction energies of FG and NH3/NH4+ are evaluated using density functional theory calculations and the interactions are mapped. Here FGs with two different amounts of fluorinecontents ‑~5 atomic% (C39H16F2) and ~24 atomic% (C39H16F12) - are theoretically and experimentally studied for selective, high sensitive and ultra-low level detection of ammonia. Fast responding, high sensitive, large area patternable FG based sensor platform demonstrated here can open new avenues for the development of point-of-care devices and clinical sensors.

  9. Fiber-Optic Ammonia Sensors

    NASA Technical Reports Server (NTRS)

    Carter, Michael T.

    2003-01-01

    Reversible, colorimetric fiber-optic sensors are undergoing development for use in measuring concentrations of ammonia in air at levels relevant to human health [0 to 50 parts per million (ppm)]. A sensor of this type includes an optical fiber that has been modified by replacing a portion of its cladding with a polymer coat that contains a dye that reacts reversibly with ammonia and changes color when it does so. The change in color is measured as a change in the amount of light transmitted from one end of the fiber to the other. Responses are reversible and proportional to the concentration of ammonia over the range from 9 to 175 ppm and in some cases the range of reversibility extends up to 270 ppm. The characteristic time for the response of a sensor to rise from 10 to 90 percent of full scale is about 25 seconds. These sensors are fully operational in pure carbon dioxide and are not adversely affected by humidity. This work was done by Michael T. Carter

  10. Fluorographene based Ultrasensitive Ammonia Sensor.

    PubMed

    Tadi, Kiran Kumar; Pal, Shubhadeep; Narayanan, Tharangattu N

    2016-01-01

    Single molecule detection using graphene can be brought by tuning the interactions via specific dopants. Electrostatic interaction between the most electronegative element fluorine (F) and hydrogen (H) is one of the strong interactions in hydrogen bonding, and here we report the selective binding of ammonia/ammonium with F in fluorographene (FG) resulting to a change in the impedance of the system. Very low limit of detection value of ~0.44 pM with linearity over wide range of concentrations (1 pM-0.1 μM) is achieved using the FG based impedance sensor, andthisscreen printed FG sensor works in both ionized (ammonium) and un-ionized ammonia sensing platforms. The interaction energies of FG and NH3/NH4(+) are evaluated using density functional theory calculations and the interactions are mapped. Here FGs with two different amounts of fluorinecontents -~5 atomic% (C39H16F2) and ~24 atomic% (C39H16F12) - are theoretically and experimentally studied for selective, high sensitive and ultra-low level detection of ammonia. Fast responding, high sensitive, large area patternable FG based sensor platform demonstrated here can open new avenues for the development of point-of-care devices and clinical sensors. PMID:27142522

  11. Reactions of dehydrodiferulates with ammonia.

    PubMed

    Azarpira, Ali; Lu, Fachuang; Ralph, John

    2011-10-01

    Lignocellulosic materials derived from forages and agricultural residues are potential sustainable resources for production of bioethanol or other liquid biofuels. However, the natural recalcitrance of such materials to enzymatic hydrolysis is a major obstacle in their efficient utilization. In grasses, much of the recalcitrance is associated with ferulate cross-linking in the cell wall, i.e., with polysaccharide-polysaccharide cross-linking that results from ferulate dehydrodimerization or with lignin-polysaccharide cross-linking that results from the incorporation of (polysaccharide-bound) ferulates or diferulates into lignin, mainly via free-radical coupling reactions. Many pretreatment methods have been developed to address recalcitrance, with ammonia pretreatments in general, and the AFEX (Ammonia Fiber Expansion) process in particular, among the more promising methods. In order to understand the polysaccharide liberating reactions involved in the cleavage of diferulate cell wall cross-links during AFEX pretreatment, reaction products from five esters modeling the major diferulates in grass cell walls treated under AFEX-like conditions were separated and characterized by NMR and HR-MS. Results from this study indicate that, beyond the anticipated amide products, a range of degradation products derive from an array of cleavage and substitution reactions, and reveal various pathways for incorporating ammonia-based nitrogen into biomass. PMID:21853208

  12. Municipal solid waste recycling issues

    SciTech Connect

    Lave, L.B.; Hendrickson, C.T.; Conway-Schempf, N.M.; McMichael, F.C.

    1999-10-01

    Municipal solid waste (MSW) recycling targets have been set nationally and in many states. Unfortunately, the definitions of recycling, rates of recycling, and the appropriate components of MSW vary. MSW recycling has been found to be costly for most municipalities compared to landfill disposal. MSW recycling policy should be determined by the cost to the community and to society more generally. In particular, recycling is a good policy only if environmental impacts and the resources used to collect, sort, and recycle a material are less than the environmental impacts and resources needed to provide equivalent virgin material plus the resources needed to dispose of the postconsumer material safely. From a review of the existing economic experience with recycling and an analysis of the environmental benefits (including estimation of external social costs), the authors find that, for most communities, curbside recycling is only justifiable for some postconsumer waste, such as aluminum and other metals. They argue that alternatives to curbside recycling collection should be explored, including product takeback for products with a toxic content (such as batteries) or product redesign to permit more effective product remanufacture.

  13. Influence of carbon nanotube dimensions on the percolation characteristics of carbon nanotube/polymer composites

    NASA Astrophysics Data System (ADS)

    Shehzad, Khurram; Ahmad, Mirza Nadeem; Hussain, Tajamal; Mumtaz, Muhammad; Shah, Asma Tufail; Mujahid, Adnan; Wang, Chao; Ellingsen, Josef; Dang, Zhi-Min

    2014-08-01

    The effect of carbon nanotube aspect ratio (AR) on the percolation characteristics of their polymer composites was investigated by melt blending the multi-wall carbon nanotubes (MWCNTs) with different AR with a thermoplastic elastomer. Previously, most studies reported the effect of aspect ratio of MWCNTs only in the context of achieving the maximum electrical conductivity at lower percolation thresholds in the polymer composites. In this study, our results indicate that aspect ratio can also influence other percolation properties such as the pre-percolation conductivity, percolation conductivity and post-percolation conductivity, shape of the percolation curve, and the width of the insulator-conductor transition. We have established that AR can be used to tailor the percolation curves from sharp to quasi-linear ones, which can help us fabricate the percolative composites with stable electrical properties. Experimental results suggested that the mathematically calculated nominal AR of the MWCNTs was an unclear parameter to correlate with the percolation characteristics of the composites. Instead, an approach taking into consideration the nominal length (l) and the diameter (d) of the MWCNTs individually rather than as a combined AR (l/d) parameter gave a better explanation of the relation between MWCNT dimensions and percolation characteristics.

  14. Understanding recycling behavior in Kentucky: Who recycles and why

    NASA Astrophysics Data System (ADS)

    Morgan, Fred W.; Hughes, Margaret V.

    2006-08-01

    Recycling behavior and the motivations behind recycling are being analyzed in a collaborative study between the Sloan Industry Center for a Sustainable Aluminum Industry, the Center for Aluminum Technology, Secat, and the Gatton College of Business and Economics at the University of Kentucky in Lexington. The goals of this study are to determine why people recycle and to find ways to motivate people to recycle more, using Fayette County, Kentucky, as a sample study. It is hoped that the information gathered through educational and motivational efforts in this county can be used on a larger scale in communities throughout the United States.

  15. Why recycle? A comparison of recycling motivations in four communities

    NASA Astrophysics Data System (ADS)

    Vining, Joanne; Linn, Nancy; Burdge, Rabel J.

    1992-11-01

    Four Illinois communities with different sociode-mographic compositions and at various stages of planning for solid waste management were surveyed to determine the influence of sociodemographic variables and planning stages on the factors that motivate recycling behavior. A factor analysis of importance ratings of reasons for recycling and for not recycling yielded five factors interpreted as altruism, personal inconvenience, social influences, economic incentives, and household storage. The four communities were shown to be significantly different in multivariate analyses of the five motivational factors. However, attempts to explain these community differences with regression analyses, which predicted the motivational factors with dummy codes for planning stages, a measure of self-reported recycling behavior, and sociodemographic measures were unsatisfactory. Contrary to expectation, the solid waste management planning stages of the cities (curbside pickup, recycling dropoff center, and planning in progress) contributed only very slightly to the prediction of motivational factors for recycling. Community differences were better explained by different underlying motivational structures among the four communities. Altruistic reasons for recycling (e.g., conserving resources) composed the only factor which was similar across the four communities. This factor was also perceived to be the most important reason for recycling by respondents from all four communities. The results of the study supported the notion that convenient, voluntary recycling programs that rely on environmental concern and conscience for motivation are useful approaches to reducing waste.

  16. A MOF-derived Co-CoO@N-doped porous carbon for efficient tandem catalysis: dehydrogenation of ammonia borane and hydrogenation of nitro compounds.

    PubMed

    Ma, Xiao; Zhou, Yu-Xiao; Liu, Hang; Li, Yang; Jiang, Hai-Long

    2016-06-01

    The one-step pyrolysis of a zeolite-type metal-organic framework, Co(2-methylimidazole)2 (ZIF-67), produces an N-doped porous carbon incorporating well-dispersed Co/CoO nanoparticles, which exhibit excellent catalytic activity, chemoselectivity and magnetic recyclability for the tandem dehydrogenation of ammonia borane and hydrogenation of nitro compounds at room temperature. PMID:27241630

  17. How Inhomogeneous Site Percolation Works on Bethe Lattices: Theory and Application

    NASA Astrophysics Data System (ADS)

    Ren, Jingli; Zhang, Liying; Siegmund, Stefan

    2016-03-01

    Inhomogeneous percolation, for its closer relationship with real-life, can be more useful and reasonable than homogeneous percolation to illustrate the critical phenomena and dynamical behaviour of complex networks. However, due to its intricacy, the theoretical framework of inhomogeneous percolation is far from being complete and many challenging problems are still open. In this paper, we first investigate inhomogeneous site percolation on Bethe Lattices with two occupation probabilities, and then extend the result to percolation with m occupation probabilities. The critical behaviour of this inhomogeneous percolation is shown clearly by formulating the percolation probability with given occupation probability p, the critical occupation probability , and the average cluster size where p is subject to . Moreover, using the above theory, we discuss in detail the diffusion behaviour of an infectious disease (SARS) and present specific disease-control strategies in consideration of groups with different infection probabilities.

  18. How Inhomogeneous Site Percolation Works on Bethe Lattices: Theory and Application

    PubMed Central

    Ren, Jingli; Zhang, Liying; Siegmund, Stefan

    2016-01-01

    Inhomogeneous percolation, for its closer relationship with real-life, can be more useful and reasonable than homogeneous percolation to illustrate the critical phenomena and dynamical behaviour of complex networks. However, due to its intricacy, the theoretical framework of inhomogeneous percolation is far from being complete and many challenging problems are still open. In this paper, we first investigate inhomogeneous site percolation on Bethe Lattices with two occupation probabilities, and then extend the result to percolation with m occupation probabilities. The critical behaviour of this inhomogeneous percolation is shown clearly by formulating the percolation probability with given occupation probability p, the critical occupation probability , and the average cluster size where p is subject to . Moreover, using the above theory, we discuss in detail the diffusion behaviour of an infectious disease (SARS) and present specific disease-control strategies in consideration of groups with different infection probabilities. PMID:26926785

  19. Percolation effects on entangled polymer rheology and the glass transition

    NASA Astrophysics Data System (ADS)

    Wool, Richard P.

    2012-07-01

    Current thinking on the fundamentals of entangled polymer melt rheology suggests that stress relaxation in the terminal zone occurs via Reptation, chain-end fluctuation and (convective) constraint release. This scenario is not correct. It is shown through a series of experiments with selectively deuterated model polymers that relaxation occurs through a percolation process which permits large clusters of entangled polymers to stress relax before their conformations are fully relaxed. The percolation model of entanglements (R.P. Wool, Macromolecules 26, 1564, 1993) makes unique predictions regarding the dynamics of polymer chains in the terminal relaxation zone. These include: (a) Reptating homopolymer chains with molecular weight M >> Mc appear to be non-Reptating as their ends and centers relax at the same rate in a Rouse-like manner during percolation. (b) The mechanical relaxation time τ(M) is related to the Reptation time Tr˜ M3 by τ(M) = Tr[(1-Mc/M)Me/Mc]2, which is the origin of the zero shear viscosity behaving as ηo˜M3.4 (c) The biggest surprise is that during stress relaxation, the random coil dimensions Rg(//) and Rg(⊥) are not fully relaxed when the stress and birefringence relax to zero. (d) Matrix molecular weight P effects on relaxation time τ(M) of the probe chain M are as follows: When the probe chain M>>P, the matrix P-chains percolate and Rouse-like dynamics is observed for the M-Reptating chains with τ(M) ˜ P1M2. (e) When the matrix P>>M, percolation does not occur for the M-chain and the relaxation time of the probe chain τ(M) ˜ PoM3 is in accord with DeGennes Reptation theory. These unusual results predicted by entanglement percolation are supported by extensive experimental data (NR, SANS, DSIMS, FTIR, BR) from selectively deuterated polystyrene chains HDH, DHD, HPS and DPS. These results clearly suggest that current notions of polymer rheology need to be reconsidered. Near Tg, a new perspective on the Glass Transition of amorphous

  20. Emulsified industrial oils recycling

    SciTech Connect

    Gabris, T.

    1982-04-01

    The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

  1. Recycler barrier RF buckets

    SciTech Connect

    Bhat, C.M.; /Fermilab

    2011-03-01

    The Recycler Ring at Fermilab uses a barrier rf systems for all of its rf manipulations. In this paper, I will give an overview of historical perspective on barrier rf system, the longitudinal beam dynamics issues, aspects of rf linearization to produce long flat bunches and methods used for emittance measurements of the beam in the RR barrier rf buckets. Current rf manipulation schemes used for antiproton beam stacking and longitudinal momentum mining of the RR beam for the Tevatron collider operation are explained along with their importance in spectacular success of the Tevatron luminosity performance.

  2. PFC concentration and recycle

    SciTech Connect

    Tom, G.M.; McManus, J.; Knolle, W.; Stoll, I.

    1994-12-31

    The semiconductor industry uses PFC gases such as CF{sub 4} and C{sub 2}F{sub 6} as etchant and cleaning gases during plasma processes. The gases do not fully react within the reactor chamber. The unused gases enter the atmosphere through the process effluent. These gases have long persistence in the atmosphere and absorb infrared radiation. The PFC gases are, therefore, potential global warming gases. A method is described that will recover and recycle PFC gases. The method that the authors have employed to trap and concentrate the PFC gases is based on a dual bed adsorber. The adsorption material is activated carbon.

  3. Recycled rubber roads

    SciTech Connect

    Not Available

    1989-02-01

    The paper describes several innovative approaches for recycling old tires in the construction of roads. In one, 18 inches of shredded tire chips (2 X 2 inches) were used on top of 6-8 inches of small stone to construct a road across a sanitary landfill. No compacting or linders were needed. In another application, sidewall mats linked together with steel strapping were used as a sub-base for a road across a swampy area. A third application uses 1/2 inch bits of groundup rubber tires as a replacement for aggregate in an asphalt road base.

  4. Polyaniline-based optical ammonia detector

    DOEpatents

    Duan, Yixiang; Jin, Zhe; Su, Yongxuan

    2002-01-01

    Electronic absorption spectroscopy of a polyaniline film deposited on a polyethylene surface by chemical oxidation of aniline monomer at room temperature was used to quantitatively detect ammonia gas. The present optical ammonia gas detector was found to have a response time of less than 15 s, a regeneration time of less than 2 min. at room temperature, and a detection limit of 1 ppm (v/v) for ammonia, with a linear dynamic range from 180 ppm to 18,000 ppm.

  5. Adsorption of ammonia on multilayer iron phthalocyanine

    SciTech Connect

    Isvoranu, Cristina; Knudsen, Jan; Ataman, Evren; Andersen, Jesper N.; Schnadt, Joachim; Schulte, Karina; Wang Bin; Bocquet, Marie-Laure

    2011-03-21

    The adsorption of ammonia on multilayers of well-ordered, flat-lying iron phthalocyanine (FePc) molecules on a Au(111) support was investigated by x-ray photoelectron spectroscopy. We find that the electron-donating ammonia molecules coordinate to the metal centers of iron phthlalocyanine. The coordination of ammonia induces changes of the electronic structure of the iron phthalocyanine layer, which, in particular, lead to a modification of the FePc valence electron spin.

  6. Price of anarchy is maximized at the percolation threshold.

    PubMed

    Skinner, Brian

    2015-05-01

    When many independent users try to route traffic through a network, the flow can easily become suboptimal as a consequence of congestion of the most efficient paths. The degree of this suboptimality is quantified by the so-called price of anarchy (POA), but so far there are no general rules for when to expect a large POA in a random network. Here I address this question by introducing a simple model of flow through a network with randomly placed congestible and incongestible links. I show that the POA is maximized precisely when the fraction of congestible links matches the percolation threshold of the lattice. Both the POA and the total cost demonstrate critical scaling near the percolation threshold. PMID:26066138

  7. The price of anarchy is maximized at the percolation threshold

    NASA Astrophysics Data System (ADS)

    Skinner, Brian

    2015-03-01

    When many independent users try to route traffic through a network, the flow can easily become suboptimal as a consequence of congestion of the most efficient paths. The degree of this suboptimality is quantified by the so-called ``price of anarchy'' (POA), but so far there are no general rules for when to expect a large POA in a random network. Here I address this question by introducing a simple model of flow through a network with randomly-placed ``congestible'' and ``incongestible'' links. I show that the POA is maximized precisely when the fraction of congestible links matches the percolation threshold of the lattice. Both the POA and the total cost demonstrate critical scaling near the percolation threshold.

  8. Price of anarchy is maximized at the percolation threshold

    NASA Astrophysics Data System (ADS)

    Skinner, Brian

    2015-05-01

    When many independent users try to route traffic through a network, the flow can easily become suboptimal as a consequence of congestion of the most efficient paths. The degree of this suboptimality is quantified by the so-called price of anarchy (POA), but so far there are no general rules for when to expect a large POA in a random network. Here I address this question by introducing a simple model of flow through a network with randomly placed congestible and incongestible links. I show that the POA is maximized precisely when the fraction of congestible links matches the percolation threshold of the lattice. Both the POA and the total cost demonstrate critical scaling near the percolation threshold.

  9. Colloidal suspensions of C-particles: Entanglement, percolation and microrheology

    NASA Astrophysics Data System (ADS)

    Hoell, Christian; Löwen, Hartmut

    2016-05-01

    We explore structural and dynamical behavior of concentrated colloidal suspensions made up by C-shape particles using Brownian dynamics computer simulations and theory. In particular, we focus on the entanglement process between nearby particles for almost closed C-shapes with a small opening angle. Depending on the opening angle and the particle concentration, there is a percolation transition for the cluster of entangled particles which shows the classical scaling characteristics. In a broad density range below the percolation threshold, we find a stretched exponential function for the dynamical decorrelation of the entanglement process. Finally, we study a setup typical in microrheology by dragging a single tagged particle with constant speed through the suspension. We measure the cluster connected to and dragged with this tagged particle. In agreement with a phenomenological theory, the size of the dragged cluster depends on the dragging direction and increases markedly with the dragging speed.

  10. Stochastic Loewner evolution relates anomalous diffusion and anisotropic percolation

    NASA Astrophysics Data System (ADS)

    Credidio, Heitor F.; Moreira, André A.; Herrmann, Hans J.; Andrade, José S.

    2016-04-01

    We disclose the origin of anisotropic percolation perimeters in terms of the stochastic Loewner evolution (SLE) process. Precisely, our results from extensive numerical simulations indicate that the perimeters of multilayered and directed percolation clusters at criticality are the scaling limits of the Loewner evolution of an anomalous Brownian motion, being superdiffusive and subdiffusive, respectively. The connection between anomalous diffusion and fractal anisotropy is further tested by using long-range power-law correlated time series (fractional Brownian motion) as the driving functions in the evolution process. The fact that the resulting traces are distinctively anisotropic corroborates our hypothesis. Under the conceptual framework of SLE, our study therefore reveals different perspectives for mathematical and physical interpretations of non-Markovian processes in terms of anisotropic paths at criticality and vice versa.

  11. Finite-size effects and percolation properties of Poisson geometries.

    PubMed

    Larmier, C; Dumonteil, E; Malvagi, F; Mazzolo, A; Zoia, A

    2016-07-01

    Random tessellations of the space represent a class of prototype models of heterogeneous media, which are central in several applications in physics, engineering, and life sciences. In this work, we investigate the statistical properties of d-dimensional isotropic Poisson geometries by resorting to Monte Carlo simulation, with special emphasis on the case d=3. We first analyze the behavior of the key features of these stochastic geometries as a function of the dimension d and the linear size L of the domain. Then, we consider the case of Poisson binary mixtures, where the polyhedra are assigned two labels with complementary probabilities. For this latter class of random geometries, we numerically characterize the percolation threshold, the strength of the percolating cluster, and the average cluster size. PMID:27575099

  12. Percolation mechanism drives actin gels to the critically connected state

    NASA Astrophysics Data System (ADS)

    Lee, Chiu Fan; Pruessner, Gunnar

    2016-05-01

    Cell motility and tissue morphogenesis depend crucially on the dynamic remodeling of actomyosin networks. An actomyosin network consists of an actin polymer network connected by cross-linker proteins and motor protein myosins that generate internal stresses on the network. A recent discovery shows that for a range of experimental parameters, actomyosin networks contract to clusters with a power-law size distribution [J. Alvarado, Nat. Phys. 9, 591 (2013), 10.1038/nphys2715]. Here, we argue that actomyosin networks can exhibit a robust critical signature without fine-tuning because the dynamics of the system can be mapped onto a modified version of percolation with trapping (PT), which is known to show critical behavior belonging to the static percolation universality class without the need for fine-tuning of a control parameter. We further employ our PT model to generate experimentally testable predictions.

  13. Fractal structure of equipotential curves on a continuum percolation model

    NASA Astrophysics Data System (ADS)

    Matsutani, Shigeki; Shimosako, Yoshiyuki; Wang, Yunhong

    2012-12-01

    We numerically investigate the electric potential distribution over a two-dimensional continuum percolation model between the electrodes. The model consists of overlapped conductive particles on the background with an infinitesimal conductivity. Using the finite difference method, we solve the generalized Laplace equation and show that in the potential distribution, there appear quasi-equipotential clusters which approximately and locally have the same values as steps and stairs. Since the quasi-equipotential clusters have the fractal structure, we compute the fractal dimension of equipotential curves and its dependence on the volume fraction over [0,1]. The fractal dimension in [1.00, 1.246] has a peak at the percolation threshold pc.

  14. The September 11 attack: A percolation of individual passive support

    NASA Astrophysics Data System (ADS)

    Galam, S.

    2002-04-01

    A model to terrorism is presented using the theory of percolation. Terrorism power is related to the spontaneous formation of random backbones of people who are sympathetic to terrorism but without being directly involved in it. They just don't oppose in case they could. In the past such friendly-to-terrorism backbones have been always existing but were of finite size and localized to a given geographical area. The September 11 terrorist attack on the US has revealed for the first time the existence of a world wide spread extension. It is argued to have result from a sudden world percolation of otherwise unconnected and dormant world spread backbones of passive supporters. The associated strategic question is then to determine if collecting ground information could have predict and thus avoid such a transition. Our results show the answer is no, voiding the major criticism against intelligence services. To conclude the impact of military action is discussed.

  15. Concurrent enhancement of percolation and synchronization in adaptive networks

    NASA Astrophysics Data System (ADS)

    Eom, Young-Ho; Boccaletti, Stefano; Caldarelli, Guido

    2016-06-01

    Co-evolutionary adaptive mechanisms are not only ubiquitous in nature, but also beneficial for the functioning of a variety of systems. We here consider an adaptive network of oscillators with a stochastic, fitness-based, rule of connectivity, and show that it self-organizes from fragmented and incoherent states to connected and synchronized ones. The synchronization and percolation are associated to abrupt transitions, and they are concurrently (and significantly) enhanced as compared to the non-adaptive case. Finally we provide evidence that only partial adaptation is sufficient to determine these enhancements. Our study, therefore, indicates that inclusion of simple adaptive mechanisms can efficiently describe some emergent features of networked systems’ collective behaviors, and suggests also self-organized ways to control synchronization and percolation in natural and social systems.

  16. Effect of threshold disorder on the quorum percolation model.

    PubMed

    Monceau, Pascal; Renault, Renaud; Métens, Stéphane; Bottani, Samuel

    2016-07-01

    We study the modifications induced in the behavior of the quorum percolation model on neural networks with Gaussian in-degree by taking into account an uncorrelated Gaussian thresholds variability. We derive a mean-field approach and show its relevance by carrying out explicit Monte Carlo simulations. It turns out that such a disorder shifts the position of the percolation transition, impacts the size of the giant cluster, and can even destroy the transition. Moreover, we highlight the occurrence of disorder independent fixed points above the quorum critical value. The mean-field approach enables us to interpret these effects in terms of activation probability. A finite-size analysis enables us to show that the order parameter is weakly self-averaging with an exponent independent on the thresholds disorder. Last, we show that the effects of the thresholds and connectivity disorders cannot be easily discriminated from the measured averaged physical quantities. PMID:27575157

  17. Many-body localization as percolation in d >1

    NASA Astrophysics Data System (ADS)

    Chandran, Anushya; Laumann, Chris; Gottesman, Daniel

    2015-03-01

    Statistical mechanics is the framework that connects thermodynamics to the microscopic world. It hinges on the assumption of equilibration. Isolated quantum systems need not equilibrate; this is the phenomenon of many-body localization (MBL). While a detailed understanding of MBL and the associated delocalization transition is beginning to emerge in one dimension, relatively little is known about higher dimensions. In this work, we present a minimal tractable model for MBL in all spatial dimensions. Specifically, we analyze a disordered Floquet circuit composed of Clifford gates. In one dimension, the system is always localized, while in higher dimensions, it exhibits both delocalized and localized phases. The localized phase consists of well-defined metallic puddles embedded in an insulating matrix. When the puddles percolate, the system delocalizes; this maps the dynamical transition to critical percolation. We also comment on the stability of the phases to generic perturbations away from the Clifford class.

  18. Randomness versus deterministic chaos: Effect on invasion percolation clusters

    NASA Astrophysics Data System (ADS)

    Peng, Chung-Kang; Prakash, Sona; Herrmann, Hans J.; Stanley, H. Eugene

    1990-10-01

    What is the difference between randomness and chaos \\? Although one can define randomness and one can define chaos, one cannot easily assess the difference in a practical situation. Here we compare the results of these two antipodal approaches on a specific example. Specifically, we study how well the logistic map in its chaotic regime can be used as quasirandom number generator by calculating pertinent properties of a well-known random process: invasion percolation. Only if λ>λ*1 (the first reverse bifurcation point) is a smooth extrapolation in system size possible, and percolation exponents are retrieved. If λ≠1, a sequential filling of the lattice with the random numbers generates a measurable anisotropy in the growth sequence of the clusters, due to short-range correlations.

  19. Correlated Percolation Models of Jamming and Glass Transitions

    NASA Astrophysics Data System (ADS)

    Jeng, Monwhea; Schwarz, Jennifer

    2007-03-01

    Toninelli, Biroli, and Fisher recently introduced a model of correlated percolation called the Knight model, which they claimed to prove underwent a dynamical glass transition. This transition had novel properties, with a discontinuous jump in the order parameter, but with diverging time scales and correlation lengths. We show that their proof misidentified the critical point, so that these properties are currently unproven for this model. However, we show that these novel properties can in fact be proven for suitably modified models of correlated percolation, with qualitatively similar culling rules. We discuss the features of the models necessary for a rigorous proof to be possible. We also discuss properties of models such as the force balance model and the original Knight model, which appear to undergo novel transitions despite the lack of a rigorous proof of such a transition.

  20. Finite-size effects and percolation properties of Poisson geometries

    NASA Astrophysics Data System (ADS)

    Larmier, C.; Dumonteil, E.; Malvagi, F.; Mazzolo, A.; Zoia, A.

    2016-07-01

    Random tessellations of the space represent a class of prototype models of heterogeneous media, which are central in several applications in physics, engineering, and life sciences. In this work, we investigate the statistical properties of d -dimensional isotropic Poisson geometries by resorting to Monte Carlo simulation, with special emphasis on the case d =3 . We first analyze the behavior of the key features of these stochastic geometries as a function of the dimension d and the linear size L of the domain. Then, we consider the case of Poisson binary mixtures, where the polyhedra are assigned two labels with complementary probabilities. For this latter class of random geometries, we numerically characterize the percolation threshold, the strength of the percolating cluster, and the average cluster size.

  1. Continuous percolation transition in suppressed random cluster growth model

    NASA Astrophysics Data System (ADS)

    Roy, Bappaditya; Santra, S. B.

    2016-05-01

    A new suppressed cluster growth model on 2D square lattice combining Hoshen-Kopelman and Leath approaches is studied here. The lattice sites are initially occupied randomly with probability (ρ). The empty perimeter sites of the clusters of occupied sites are grown with a cluster size dependent probability. The growth probability is then lowest for the largest cluster and highest for the smallest cluster. At the end of growth process all the cluster related quantities are estimated and they are found to display power law scaling as in percolation transition. However, the values of the critical exponents vary continuously with ρ, the initial seed concentration. At higher values of ρ, the model belongs the percolation universality class.

  2. Quantum walk coherences on a dynamical percolation graph

    NASA Astrophysics Data System (ADS)

    Elster, Fabian; Barkhofen, Sonja; Nitsche, Thomas; Novotný, Jaroslav; Gábris, Aurél; Jex, Igor; Silberhorn, Christine

    2015-08-01

    Coherent evolution governs the behaviour of all quantum systems, but in nature it is often subjected to influence of a classical environment. For analysing quantum transport phenomena quantum walks emerge as suitable model systems. In particular, quantum walks on percolation structures constitute an attractive platform for studying open system dynamics of random media. Here, we present an implementation of quantum walks differing from the previous experiments by achieving dynamical control of the underlying graph structure. We demonstrate the evolution of an optical time-multiplexed quantum walk over six double steps, revealing the intricate interplay between the internal and external degrees of freedom. The observation of clear non-Markovian signatures in the coin space testifies the high coherence of the implementation and the extraordinary degree of control of all system parameters. Our work is the proof-of-principle experiment of a quantum walk on a dynamical percolation graph, paving the way towards complex simulation of quantum transport in random media.

  3. Vulnerability of networks: Fractional percolation on random graphs

    NASA Astrophysics Data System (ADS)

    Shang, Yilun

    2014-01-01

    We present a theoretical framework for understanding nonbinary, nonindependent percolation on networks with general degree distributions. The model incorporates a partially functional (PF) state of nodes so that both intensity and extensity of error are characterized. Two connected nodes in a PF state cannot sustain the load and therefore break their link. We give exact solutions for the percolation threshold, the fraction of giant cluster, and the mean size of small clusters. The robustness-fragility transition point for scale-free networks with a degree distribution pk∝k-α is identified to be α =3. The analysis reveals that scale-free networks are vulnerable to targeted attack at hubs: a more complete picture of their Achilles' heel turns out to be not only the hubs themselves but also the edges linking them together.

  4. Colloidal suspensions of C-particles: Entanglement, percolation and microrheology.

    PubMed

    Hoell, Christian; Löwen, Hartmut

    2016-05-01

    We explore structural and dynamical behavior of concentrated colloidal suspensions made up by C-shape particles using Brownian dynamics computer simulations and theory. In particular, we focus on the entanglement process between nearby particles for almost closed C-shapes with a small opening angle. Depending on the opening angle and the particle concentration, there is a percolation transition for the cluster of entangled particles which shows the classical scaling characteristics. In a broad density range below the percolation threshold, we find a stretched exponential function for the dynamical decorrelation of the entanglement process. Finally, we study a setup typical in microrheology by dragging a single tagged particle with constant speed through the suspension. We measure the cluster connected to and dragged with this tagged particle. In agreement with a phenomenological theory, the size of the dragged cluster depends on the dragging direction and increases markedly with the dragging speed. PMID:27155650

  5. Minimal spanning trees at the percolation threshold: a numerical calculation.

    PubMed

    Sweeney, Sean M; Middleton, A Alan

    2013-09-01

    The fractal dimension of minimal spanning trees on percolation clusters is estimated for dimensions d up to d=5. A robust analysis technique is developed for correlated data, as seen in such trees. This should be a robust method suitable for analyzing a wide array of randomly generated fractal structures. The trees analyzed using these techniques are built using a combination of Prim's and Kruskal's algorithms for finding minimal spanning trees. This combination reduces memory usage and allows for simulation of larger systems than would otherwise be possible. The path length fractal dimension d_{s} of MSTs on critical percolation clusters is found to be compatible with the predictions of the perturbation expansion developed by T. S. Jackson and N. Read [Phys. Rev. E 81, 021131 (2010)]. PMID:24125235

  6. Effect of threshold disorder on the quorum percolation model

    NASA Astrophysics Data System (ADS)

    Monceau, Pascal; Renault, Renaud; Métens, Stéphane; Bottani, Samuel

    2016-07-01

    We study the modifications induced in the behavior of the quorum percolation model on neural networks with Gaussian in-degree by taking into account an uncorrelated Gaussian thresholds variability. We derive a mean-field approach and show its relevance by carrying out explicit Monte Carlo simulations. It turns out that such a disorder shifts the position of the percolation transition, impacts the size of the giant cluster, and can even destroy the transition. Moreover, we highlight the occurrence of disorder independent fixed points above the quorum critical value. The mean-field approach enables us to interpret these effects in terms of activation probability. A finite-size analysis enables us to show that the order parameter is weakly self-averaging with an exponent independent on the thresholds disorder. Last, we show that the effects of the thresholds and connectivity disorders cannot be easily discriminated from the measured averaged physical quantities.

  7. Random geometric graph description of connectedness percolation in rod systems

    NASA Astrophysics Data System (ADS)

    Chatterjee, Avik P.; Grimaldi, Claudio

    2015-09-01

    The problem of continuum percolation in dispersions of rods is reformulated in terms of weighted random geometric graphs. Nodes (or sites or vertices) in the graph represent spatial locations occupied by the centers of the rods. The probability that an edge (or link) connects any randomly selected pair of nodes depends upon the rod volume fraction as well as the distribution over their sizes and shapes, and also upon quantities that characterize their state of dispersion (such as the orientational distribution function). We employ the observation that contributions from closed loops of connected rods are negligible in the limit of large aspect ratios to obtain percolation thresholds that are fully equivalent to those calculated within the second-virial approximation of the connectedness Ornstein-Zernike equation. Our formulation can account for effects due to interactions between the rods, and many-body features can be partially addressed by suitable choices for the edge probabilities.

  8. Concurrent enhancement of percolation and synchronization in adaptive networks.

    PubMed

    Eom, Young-Ho; Boccaletti, Stefano; Caldarelli, Guido

    2016-01-01

    Co-evolutionary adaptive mechanisms are not only ubiquitous in nature, but also beneficial for the functioning of a variety of systems. We here consider an adaptive network of oscillators with a stochastic, fitness-based, rule of connectivity, and show that it self-organizes from fragmented and incoherent states to connected and synchronized ones. The synchronization and percolation are associated to abrupt transitions, and they are concurrently (and significantly) enhanced as compared to the non-adaptive case. Finally we provide evidence that only partial adaptation is sufficient to determine these enhancements. Our study, therefore, indicates that inclusion of simple adaptive mechanisms can efficiently describe some emergent features of networked systems' collective behaviors, and suggests also self-organized ways to control synchronization and percolation in natural and social systems. PMID:27251577

  9. Concurrent enhancement of percolation and synchronization in adaptive networks

    PubMed Central

    Eom, Young-Ho; Boccaletti, Stefano; Caldarelli, Guido

    2016-01-01

    Co-evolutionary adaptive mechanisms are not only ubiquitous in nature, but also beneficial for the functioning of a variety of systems. We here consider an adaptive network of oscillators with a stochastic, fitness-based, rule of connectivity, and show that it self-organizes from fragmented and incoherent states to connected and synchronized ones. The synchronization and percolation are associated to abrupt transitions, and they are concurrently (and significantly) enhanced as compared to the non-adaptive case. Finally we provide evidence that only partial adaptation is sufficient to determine these enhancements. Our study, therefore, indicates that inclusion of simple adaptive mechanisms can efficiently describe some emergent features of networked systems’ collective behaviors, and suggests also self-organized ways to control synchronization and percolation in natural and social systems. PMID:27251577

  10. Electrochemical process combined with UV light irradiation for synergistic degradation of ammonia in chloride-containing solutions.

    PubMed

    Xiao, Shuhu; Qu, Jiuhui; Zhao, Xu; Liu, Hujuan; Wan, Dongjin

    2009-03-01

    An electrochemical process combined with ultraviolet light irradiation (UPE) using nonphotoactive dimensionally stable anodes (DSAs) like RuO2/Ti and IrO2/Ti in the presence of chlorides was investigated for ammonia degradation. In this process, the in situ electrogenerated active chlorine and in situ photogenerated chlorine radicals were responsible for the high efficiency of ammonia degradation. More than 97% of ammonia was converted to nitrogen and a significantly synergistic effect was confirmed. Compared with the single electrochemical (E) and photochemical (P) process, the degradation rates of ammonia and the average current efficiencies (ACEs) of the UPE process increased by 1.5 and 1.7 times using RuO2/Ti and IrO2/Ti electrodes, respectively. On the basis of the linear voltammograms, Electrochemical Impedance Spectra (EIS), UV-vis spectra, Electron Spin Resonance (ESR) analysis and a series of experiments designed, the synergistic mechanism was investigated. In addition, this unique process succeeded in transferring the reaction from the electrode surface to the bulk of the solution compared with the conventional photoelectrocatalytic (PEC) process. The loss of chloride decreased from 21.0% to 7.2% and the recycle of chloride was accelerated in the UPE process. Finally the effects of initial pH, current density and ammonia-nitrogen concentration were discussed. Results indicated that pH and ammonia concentration exerted little influences on the degradation rates and current density was the "rate-determining" factor. PMID:19135227

  11. Reversible intercalation of ammonia molecules into a layered double hydroxide structure without exchanging nitrate counter-ions

    SciTech Connect

    Carbajal Arizaga, Gregorio Guadalupe; Wypych, Fernando; Castillon Barraza, Felipe; Contreras Lopez, Oscar Edel

    2010-10-15

    A zinc/aluminum LDH was precipitated with recycled ammonia from a chemical vapor deposition reaction. The LDH presented a crystalline phase with basal distance of 8.9 A, typical for nitrate-containing LDHs, and another phase with a basal distance of 13.9 A. Thermal treatment at 150 {sup o}C eliminated the phase with the bigger basal distance leaving only the anhydrous nitrate-intercalated LDH structure with 8.9 A. Intense N-H stretching modes in the FTIR spectra suggested that the expansion was due to intercalation of ammonia in the form of [NH{sub 4}(NH{sub 3}){sub n}]{sup +} species. When additional samples were precipitated with pure ammonia, the conventional LDH nitrate structure was obtained (8.9 A basal distance) at pH=7, as well as a pure crystalline phase with 13.9 A basal distance at pH=10 due to ammonia intercalation that can be removed by heating at 150 {sup o}C or by stirring in acetone, confirming a unusual sensu stricto intercalation process into a LDH without exchanging nitrate ions. - Graphical abstract: LDH-nitrate precipitated with ammonia expands the interlayer space if ammonia is bubbled up to pH 10. The basal distance decreased when the compound was heated at 150 {sup o}C or stirred in acetone. Nitrate ions are not exchanged.

  12. Ammonia removal by sweep gas membrane distillation.

    PubMed

    Xie, Zongli; Duong, Tuan; Hoang, Manh; Nguyen, Cuong; Bolto, Brian

    2009-04-01

    Wastewater containing low levels of ammonia (100 mg/L) has been simulated in experiments with sweep gas membrane distillation at pH 11.5. The effects of feed temperature, gas flow rate and feed flow rate on ammonia removal, permeate flux and selectivity were investigated. The feed temperature is a crucial operating factor, with increasing feed temperature increasing the permeate flux significantly, but reducing the selectivity. The best-performing conditions of highest temperature and fastest gas flow rate resulted in 97% removal of the ammonia, to give a treated water containing only 3.3 mg/L of ammonia. PMID:19195677

  13. Microwave study of superconducting Sn films above and below percolation

    NASA Astrophysics Data System (ADS)

    Beutel, Manfred H.; Ebensperger, Nikolaj G.; Thiemann, Markus; Untereiner, Gabriele; Fritz, Vincent; Javaheri, Mojtaba; Nägele, Jonathan; Rösslhuber, Roland; Dressel, Martin; Scheffler, Marc

    2016-08-01

    The electronic properties of superconducting Sn films ({T}{{c}}≈ 3.8 {{K}}) change significantly when reducing the film thickness down to a few {nm}, in particular close to the percolation threshold. The low-energy electrodynamics of such Sn samples can be probed via microwave spectroscopy, e.g. with superconducting stripline resonators. Here we study Sn thin films, deposited via thermal evaporation—ranging in thickness between 38 and 842 {nm}—which encompasses the percolation transition. We use superconducting Pb stripline resonators to probe the microwave response of these Sn films in a frequency range between 4 and 20 {GHz} at temperatures from 7.2 down to 1.5 {{K}}. The measured quality factor of the resonators decreases with rising temperature due to enhanced losses. As a function of the sample thickness we observe three regimes with significantly different properties: samples below percolation, i.e. ensembles of disconnected superconducting islands, exhibit dielectric properties with negligible losses, demonstrating that macroscopic current paths are required for appreciable dynamical conductivity of Sn at GHz frequencies. Thick Sn films, as the other limit, lead to low-loss resonances both above and below T c of Sn, as expected for bulk conductors. But in an intermediate thickness regime, just above percolation and with labyrinth-like morphology of the Sn, we observe a quite different behavior: the superconducting state has a microwave response similar to the thicker, completely covering films with low microwave losses; but the metallic state of these Sn films is so lossy that resonator operation is suppressed completely.

  14. Tritium percolation, convection, and permeation in fusion solid breeder blankets

    SciTech Connect

    Billone, M.C.; Liu, Y.Y.

    1985-01-01

    Models are developed to describe the percolation of released tritium through the breeder interconnected porosity to the purge stream, convection of tritium by the helium purge stream, and leakage or permeation of tritium through the structural material to the primary coolant system. Important parameters in the models are tritium generation rate, breeder microstructure, tritium species in the gas phase, temperatures, tritium diffusivities and permeabilities, and effectiveness of oxide barriers.

  15. Cell Invasion in Collagen Scaffold Architectures Characterized by Percolation Theory.

    PubMed

    Ashworth, Jennifer C; Mehr, Marco; Buxton, Paul G; Best, Serena M; Cameron, Ruth E

    2015-06-24

    The relationship between biological scaffold interconnectivity and cell migration is an important but poorly understood factor in tissue regeneration. Here a scale-independent technique for characterization of collagen scaffold interconnectivity is presented, using a combination of X-ray microcomputed tomography and percolation theory. Confocal microscopy of connective tissue cells reveals this technique as highly relevant for determining the extent of cell invasion. PMID:25881025

  16. Behaviour of Recycled Coarse Aggregate Concrete: Age and Successive Recycling

    NASA Astrophysics Data System (ADS)

    Sahoo, Kirtikanta; Pathappilly, Robin Davis; Sarkar, Pradip

    2016-05-01

    Recycled Coarse Aggregate (RCA) concrete construction technique can be called as `green concrete', as it minimizes the environmental hazard of the concrete waste disposal. Indian standard recommends target mean compressive strength of the conventional concrete in terms of water cement ratio (w/c). The present work is an attempt to study the behaviour of RCA concrete from two samples of parent concrete having different age group with regard to the relationship of compressive strength with water cement ratios. Number of recycling may influence the mechanical properties of RCA concrete. The influence of age and successive recycling on the properties such as capillary water absorption, drying shrinkage strain, air content, flexural strength and tensile splitting strength of the RCA concrete are examined. The relationship between compressive strength at different w/c ratios obtained experimentally is investigated for the two parameters such as age of parent concrete and successive recycling. The recycled concrete using older recycled aggregate shows poor quality. While the compressive strength reduces with successive recycling gradually, the capillary water absorption increases abruptly, which leads to the conclusion that further recycling may not be advisable.

  17. Behaviour of Recycled Coarse Aggregate Concrete: Age and Successive Recycling

    NASA Astrophysics Data System (ADS)

    Sahoo, Kirtikanta; Pathappilly, Robin Davis; Sarkar, Pradip

    2016-06-01

    Recycled Coarse Aggregate (RCA) concrete construction technique can be called as `green concrete', as it minimizes the environmental hazard of the concrete waste disposal. Indian standard recommends target mean compressive strength of the conventional concrete in terms of water cement ratio ( w/ c). The present work is an attempt to study the behaviour of RCA concrete from two samples of parent concrete having different age group with regard to the relationship of compressive strength with water cement ratios. Number of recycling may influence the mechanical properties of RCA concrete. The influence of age and successive recycling on the properties such as capillary water absorption, drying shrinkage strain, air content, flexural strength and tensile splitting strength of the RCA concrete are examined. The relationship between compressive strength at different w/ c ratios obtained experimentally is investigated for the two parameters such as age of parent concrete and successive recycling. The recycled concrete using older recycled aggregate shows poor quality. While the compressive strength reduces with successive recycling gradually, the capillary water absorption increases abruptly, which leads to the conclusion that further recycling may not be advisable.

  18. The Fermi paradox: An approach based on percolation theory

    NASA Technical Reports Server (NTRS)

    Landis, Geoffrey A.

    1993-01-01

    If even a very small fraction of the hundred billion stars in the galaxy are home to technological civilizations which colonize over interstellar distances, the entire galaxy could be completely colonized in a few million years. The absence of such extraterrestrial civilizations visiting Earth is the Fermi paradox. A model for interstellar colonization is proposed using the assumption that there is a maximum distance over which direct interstellar colonization is feasible. Due to the time lag involved in interstellar communications, it is assumed that an interstellar colony will rapidly develop a culture independent of the civilization that originally settled it. Any given colony will have a probability P of developing a colonizing civilization, and a probability (1-P) that it will develop a non-colonizing civilization. These assumptions lead to the colonization of the galaxy occuring as a percolation problem. In a percolation problem, there will be a critical value of percolation probability, P(sub c). For P less than P(sub c), colonization will always terminate after a finite number of colonies. Growth will occur in 'clusters', with the outside of each cluster consisting of non-colonizing civilizations. For P greater than P(sub c), small uncolonized voids will exist, bounded by non-colonizing civilizations. For P approximately = to P(sub c), arbitrarily large filled regions exist, and also arbitrarily large empty regions.

  19. Transport pathways within percolating pore space networks of granular materials

    NASA Astrophysics Data System (ADS)

    Vo, Kevin; Walker, David M.; Tordesillas, Antoinette

    2013-06-01

    Granular media can be regarded as a mixture of two components: grains and the material filling the voids or pores between the grains. Pore properties give rise to a range of applications such as modelling ground water flow, carbon capture and sequestration. The grains within a dense granular material respond to deformation (e.g., shearing or compression) by rearranging to create local zones of compression and zones of dilatation (i.e., regions of high pore space). Descriptions of the deformation are typically focused on analysis of the solid skeleton via topology of physical contact networks of grains but an alternative perspective is to consider network representations of the evolving anisotropic pore space. We demonstrate how to construct pore space networks that express the local size of voids about a grain through network edge weights. We investigate sectors of the loading history when a percolating giant component of the pore space network exists. At these states the grains are in a configuration more prone to the efficient transport of material (e.g., fluid flow, mineral/gas deposits). These pathways can be found through examination of the weighted shortest paths percolating the boundaries of the material. In particular, network weights biased towards large void space results in efficient percolating pathways traversing the shear band in the direction of principal stress within a 2D granular assembly subject to high strains.

  20. Analysis of Cavity Volumes in Proteins Using Percolation Theory

    NASA Astrophysics Data System (ADS)

    Green, Sheridan; Jacobs, Donald; Farmer, Jenny

    Molecular packing is studied in a diverse set of globular proteins in their native state ranging in size from 34 to 839 residues An new algorithm has been developed that builds upon the classic Hoshen-Kopelman algorithm for site percolation combined with a local connection criterion that classifies empty space within a protein as a cavity when large enough to hold a spherical shaped probe of radius, R, otherwise a microvoid. Although microvoid cannot fit an object (e.g. molecule or ion) that is the size of the probe or larger, total microvoid volume is a major contribution to protein volume. Importantly, the cavity and microvoid classification depends on probe radius. As probe size decreases, less microvoid forms in favor of more cavities. As probe size is varied from large to small, many disconnected cavities merge to form a percolating path. For fixed probe size, microvoid, cavity and solvent accessible boundary volume properties reflect conformational fluctuations. These results are visualized on three-dimensional structures. Analysis of the cluster statistics within the framework of percolation theory suggests interconversion between microvoid and cavity pathways regulate the dynamics of solvent penetration during partial unfolding events important to protein function.

  1. Onsite synthesis of thermally percolated nanocomposite for thermal interface material

    NASA Astrophysics Data System (ADS)

    Obori, Masanao; Nita, Satoshi; Miura, Asuka; Shiomi, Junichiro

    2016-02-01

    To solve the problem of lack of thermal percolation in thermal interface materials (TIM), we propose a two-step synthesis method to realize thermally percolated nanofiber network in polymer matrix. First, by packing vapor grown carbon fibers (VGCFs) on top of aluminum heat sink and integrally sintering the whole material, the aluminum partially melts and connects the VGCF network, forming a continuous thermal path, i.e., realizing thermal percolation. Second, the pores in the hybrid network are filled by Silicone oil to obtain a polymer nanocomposite. The direct synthesis of VGCF-aluminum network on the heat sink (onsite synthesis) omits pasting process of the TIM, and thus, removes the restriction on the network morphology. By this onsite synthesis method, we reinforce thermal contact not only between the nanofibers but also between nanofibers and the heat sink. By testing the developed TIM for thermal contact to silicon surface, we demonstrate the potential to significantly reduce thermal contact resistance from what can be achieved by a conventional TIM.

  2. Cities and regions in Britain through hierarchical percolation

    PubMed Central

    Arcaute, Elsa; Molinero, Carlos; Hatna, Erez; Murcio, Roberto; Vargas-Ruiz, Camilo; Masucci, A. Paolo; Batty, Michael

    2016-01-01

    Urban systems present hierarchical structures at many different scales. These are observed as administrative regional delimitations which are the outcome of complex geographical, political and historical processes which leave almost indelible footprints on infrastructure such as the street network. In this work, we uncover a set of hierarchies in Britain at different scales using percolation theory on the street network and on its intersections which are the primary points of interaction and urban agglomeration. At the larger scales, the observed hierarchical structures can be interpreted as regional fractures of Britain, observed in various forms, from natural boundaries, such as National Parks, to regional divisions based on social class and wealth such as the well-known North–South divide. At smaller scales, cities are generated through recursive percolations on each of the emerging regional clusters. We examine the evolution of the morphology of the system as a whole, by measuring the fractal dimension of the clusters at each distance threshold in the percolation. We observe that this reaches a maximum plateau at a specific distance. The clusters defined at this distance threshold are in excellent correspondence with the boundaries of cities recovered from satellite images, and from previous methods using population density. PMID:27152211

  3. Loopless nontrapping invasion-percolation model for fracking.

    PubMed

    Norris, J Quinn; Turcotte, Donald L; Rundle, John B

    2014-02-01

    Recent developments in hydraulic fracturing (fracking) have enabled the recovery of large quantities of natural gas and oil from old, low-permeability shales. These developments include a change from low-volume, high-viscosity fluid injection to high-volume, low-viscosity injection. The injected fluid introduces distributed damage that provides fracture permeability for the extraction of the gas and oil. In order to model this process, we utilize a loopless nontrapping invasion percolation previously introduced to model optimal polymers in a strongly disordered medium and for determining minimum energy spanning trees on a lattice. We performed numerical simulations on a two-dimensional square lattice and find significant differences from other percolation models. Additionally, we find that the growing fracture network satisfies both Horton-Strahler and Tokunaga network statistics. As with other invasion percolation models, our model displays burst dynamics, in which the cluster extends rapidly into a connected region. We introduce an alternative definition of bursts to be a consecutive series of opened bonds whose strengths are all below a specified value. Using this definition of bursts, we find good agreement with a power-law frequency-area distribution. These results are generally consistent with the observed distribution of microseismicity observed during a high-volume frack. PMID:25353434

  4. Cities and regions in Britain through hierarchical percolation.

    PubMed

    Arcaute, Elsa; Molinero, Carlos; Hatna, Erez; Murcio, Roberto; Vargas-Ruiz, Camilo; Masucci, A Paolo; Batty, Michael

    2016-04-01

    Urban systems present hierarchical structures at many different scales. These are observed as administrative regional delimitations which are the outcome of complex geographical, political and historical processes which leave almost indelible footprints on infrastructure such as the street network. In this work, we uncover a set of hierarchies in Britain at different scales using percolation theory on the street network and on its intersections which are the primary points of interaction and urban agglomeration. At the larger scales, the observed hierarchical structures can be interpreted as regional fractures of Britain, observed in various forms, from natural boundaries, such as National Parks, to regional divisions based on social class and wealth such as the well-known North-South divide. At smaller scales, cities are generated through recursive percolations on each of the emerging regional clusters. We examine the evolution of the morphology of the system as a whole, by measuring the fractal dimension of the clusters at each distance threshold in the percolation. We observe that this reaches a maximum plateau at a specific distance. The clusters defined at this distance threshold are in excellent correspondence with the boundaries of cities recovered from satellite images, and from previous methods using population density. PMID:27152211

  5. The membrane skeleton of erythrocytes. A percolation model.

    PubMed Central

    Saxton, M J

    1990-01-01

    The spectrin network on the cytoplasmic surface of the erythrocyte membrane is modeled as a triangular lattice of spectrin tetramers. This network obstructs lateral diffusion of proteins and provides mechanical reinforcement to the membrane. These effects are treated in a systematic and unified manner in terms of a percolation model. The diffusion coefficient is obtained as a function of the fraction of normal spectrin tetramers for both static and fluctuating barriers. The elasticity of the network is calculated as a function of the fraction of normal spectrin and the ratio of bending to stretching energies. For static barriers, elasticity and lateral diffusion are incompatible: if a network is connected enough to be elastic, it is connected enough to block long-range lateral diffusion. The elasticity and the force required for mechanical breakdown go to zero at the percolation threshold; experimental evidence suggests the existence of a stability threshold at or near the percolation threshold. The model is qualitatively applicable to other cells with membrane skeletons, such as epithelial cells, in which localization of membrane proteins is essential to differentiation. PMID:2393702

  6. Length scale effects on percolation of geometrically complex nanocomposites

    NASA Astrophysics Data System (ADS)

    Hoffman, T. J.; Stevens, D. R.; Roberts, W. A.; Gorga, R. E.; Clarke, L. I.

    2008-10-01

    With growing interest in materials that include nanostructures the focus on nanocomposites (a polymer-based matrix that is enhanced by a nanometer sized particle) has grown. Electrospun nanocomposites contain a complex geometry including fiber sizes of 200 nm arranged in a random mat with a porosity of >= 70%. Composites utilize connected paths of particles throughout the sample to enhance the mechanical and electrical properties of the matrix. Previous literature has shown, in the case of continuous films, that this percolation phenomenon is affected by the sample size. This work aims to investigate these length scale effects within a complex morphology, such as a nanofiber mat. For a clear understanding of the change in percolation vs. length scale we fabricated interdigitated electrodes (IDEs) with a finger spacing of 10 to 100 μm, electrospun mats onto the IDEs, and performed electrical conductance measurements. In addition, computation simulations of the experimental systems were undertaken. I will discuss our results and the role sample size/shape plays on 1) the percolation threshold and 2) the conductivity vs. doping fraction curve.

  7. Loopless nontrapping invasion-percolation model for fracking

    NASA Astrophysics Data System (ADS)

    Norris, J. Quinn; Turcotte, Donald L.; Rundle, John B.

    2014-02-01

    Recent developments in hydraulic fracturing (fracking) have enabled the recovery of large quantities of natural gas and oil from old, low-permeability shales. These developments include a change from low-volume, high-viscosity fluid injection to high-volume, low-viscosity injection. The injected fluid introduces distributed damage that provides fracture permeability for the extraction of the gas and oil. In order to model this process, we utilize a loopless nontrapping invasion percolation previously introduced to model optimal polymers in a strongly disordered medium and for determining minimum energy spanning trees on a lattice. We performed numerical simulations on a two-dimensional square lattice and find significant differences from other percolation models. Additionally, we find that the growing fracture network satisfies both Horton-Strahler and Tokunaga network statistics. As with other invasion percolation models, our model displays burst dynamics, in which the cluster extends rapidly into a connected region. We introduce an alternative definition of bursts to be a consecutive series of opened bonds whose strengths are all below a specified value. Using this definition of bursts, we find good agreement with a power-law frequency-area distribution. These results are generally consistent with the observed distribution of microseismicity observed during a high-volume frack.

  8. General and exact approach to percolation on random graphs

    NASA Astrophysics Data System (ADS)

    Allard, Antoine; Hébert-Dufresne, Laurent; Young, Jean-Gabriel; Dubé, Louis J.

    2015-12-01

    We present a comprehensive and versatile theoretical framework to study site and bond percolation on clustered and correlated random graphs. Our contribution can be summarized in three main points. (i) We introduce a set of iterative equations that solve the exact distribution of the size and composition of components in finite-size quenched or random multitype graphs. (ii) We define a very general random graph ensemble that encompasses most of the models published to this day and also makes it possible to model structural properties not yet included in a theoretical framework. Site and bond percolation on this ensemble is solved exactly in the infinite-size limit using probability generating functions [i.e., the percolation threshold, the size, and the composition of the giant (extensive) and small components]. Several examples and applications are also provided. (iii) Our approach can be adapted to model interdependent graphs—whose most striking feature is the emergence of an extensive component via a discontinuous phase transition—in an equally general fashion. We show how a graph can successively undergo a continuous then a discontinuous phase transition, and preliminary results suggest that clustering increases the amplitude of the discontinuity at the transition.

  9. Scaling of clusters near discontinuous percolation transitions in hyperbolic networks

    NASA Astrophysics Data System (ADS)

    Singh, Vijay; Boettcher, Stefan

    2014-07-01

    We investigate the onset of the discontinuous percolation transition in small-world hyperbolic networks by studying the systems-size scaling of the typical largest cluster approaching the transition, p ↗pc. To this end, we determine the average size of the largest cluster ˜NΨ (p) in the thermodynamic limit using real-space renormalization of cluster-generating functions for bond and site percolation in several models of hyperbolic networks that provide exact results. We determine that all our models conform to the recently predicted behavior regarding the growth of the largest cluster, which found diverging, albeit subextensive, clusters spanning the system with finite probability well below pc and at most quadratic corrections to unity in Ψ (p) for p ↗pc. Our study suggests a large universality in the cluster formation on small-world hyperbolic networks and the potential for an alternative mechanism in the cluster formation dynamics at the onset of discontinuous percolation transitions.

  10. Can percolation theory be applied to the stock market?

    NASA Astrophysics Data System (ADS)

    Stauffer, Dietrich

    1998-11-01

    The fluctuations of the stock market - the price changes per unit time - seem to deviate from Gaussians for short time steps. Power laws, exponentials, and multifractal descriptions have been offered to explain this short-time behavior. Microscopic models dealing with the decisions of single traders on the market have tried to reproduce this behavior. Possibly the simplest of these models is the herding approach of Cont and Bouchaud. Here a total of Nt traders cluster together randomly as in percolation theory. Each cluster randomly decides by buy or sell an amount proportional to its size, or not to trade. Monte Carlo simulations in two to seven dimensions at the percolation threshold depend on the number N of clusters trading within one time step. For N 1, the changes follow a power law; for 1 N Nt they are bell-shaped with power-law tails; for N Nt they crossover to a Gaussian. The correlations in the absolute value of the change decay slowly with time. Thus percolation not only describes the origin of life or the boiling of your breakfast egg, but also explains why we are not rich.

  11. Percolative theories of strongly disordered ceramic high-temperature superconductors

    PubMed Central

    Phillips, J. C.

    2010-01-01

    Optimally doped ceramic superconductors (cuprates, pnictides, etc.) exhibit transition temperatures T c much larger than strongly coupled metallic superconductors like Pb (T c = 7.2 K, E g/kT c = 4.5) and exhibit many universal features that appear to contradict the Bardeen, Cooper, and Schrieffer theory of superconductivity based on attractive electron-phonon pairing interactions. These complex materials are strongly disordered and contain several competing nanophases that cannot be described effectively by parameterized Hamiltonian models, yet their phase diagrams also exhibit many universal features in both the normal and superconductive states. Here we review the rapidly growing body of experimental results that suggest that these anomalously universal features are the result of marginal stabilities of the ceramic electronic and lattice structures. These dual marginal stabilities favor both electronic percolation of a dopant network and rigidity percolation of the deformed lattice network. This “double percolation” model has previously explained many features of the normal-state transport properties of these materials and is the only theory that has successfully predicted strict lowest upper bounds for T c in the cuprate and pnictide families. Here it is extended to include Coulomb correlations and percolative band narrowing, as well as an angular energy gap equation, which rationalizes angularly averaged gap/T c ratios, and shows that these are similar to those of conventional strongly coupled superconductors. PMID:20080578

  12. Saccharification of newspaper waste after ammonia fiber expansion or extractive ammonia

    DOE PAGESBeta

    Montella, Salvatore; Balan, Venkatesh; da Costa Sousa, Leonardo; Gunawan, Christa; Giacobbe, Simona; Pepe, Olimpia; Faraco, Vincenza

    2016-03-02

    Here, the lignocellulosic fractions of municipal solid waste (MSW) can be used as renewable resources due to the widespread availability, predictable and low pricing and suitability for most conversion technologies. In particular, after the typical paper recycling loop, the newspaper waste (NW) could be further valorized as feedstock in biorefinering industry since it still contains up to 70 % polysaccharides. In this study, two different physicochemical methods— ammonia fiber expansion (AFEX) and extractive ammonia (EA) were tested for the pretraetment of NW. Furthermore, based on the previously demonstrated ability of the recombinant enzymes endocellulase rCelStrep, α-larabinofuranosidase rPoAbf and its evolvedmore » variant rPoAbf F435Y/Y446F to improve the saccharification of different lignocellulosic pretreated biomasses (such as corn stover and Arundo donax), in this study these enzymes were tested for the hydrolysis of pretreated NW, with the aim of valorizing the lignocellulosic fractions of the MSW. In particular, a mixture of purified enzymes containing cellulases, xylanases and accessory hemicellulases, was chosen as reference mix and rCelStrep and rPoAbf or its variant were replaced to EGI and Larb. The results showed that these enzymatic mixes are not suitable for the hydrolysis of NW after AFEX or EA pretreatment. On the other hand, when the enzymes rCelStrep, rPoAbf and rPoAbf F435Y/Y446F were tested for their effect in hydrolysis of pretreated NW by addition to a commercial enzyme mixture, it was shown that the total polysaccharides conversion yield reached 37.32 % for AFEX pretreated NW by adding rPoAbf to the mix whilst the maximum sugars conversion yield for EA pretreated NW was achieved 40.80 % by adding rCelStrep. The maximum glucan conversion yield obtained (45.61 % for EA pretreated NW by adding rCelStrep to the commercial mix) is higher than or comparable to those reported in recent manuscripts adopting hydrolysis conditions similar to

  13. Saccharification of newspaper waste after ammonia fiber expansion or extractive ammonia.

    PubMed

    Montella, Salvatore; Balan, Venkatesh; da Costa Sousa, Leonardo; Gunawan, Christa; Giacobbe, Simona; Pepe, Olimpia; Faraco, Vincenza

    2016-03-01

    The lignocellulosic fractions of municipal solid waste (MSW) can be used as renewable resources due to the widespread availability, predictable and low pricing and suitability for most conversion technologies. In particular, after the typical paper recycling loop, the newspaper waste (NW) could be further valorized as feedstock in biorefinering industry since it still contains up to 70 % polysaccharides. In this study, two different physicochemical methods-ammonia fiber expansion (AFEX) and extractive ammonia (EA) were tested for the pretraetment of NW. Furthermore, based on the previously demonstrated ability of the recombinant enzymes endocellulase rCelStrep, α-L-arabinofuranosidase rPoAbf and its evolved variant rPoAbf F435Y/Y446F to improve the saccharification of different lignocellulosic pretreated biomasses (such as corn stover and Arundo donax), in this study these enzymes were tested for the hydrolysis of pretreated NW, with the aim of valorizing the lignocellulosic fractions of the MSW. In particular, a mixture of purified enzymes containing cellulases, xylanases and accessory hemicellulases, was chosen as reference mix and rCelStrep and rPoAbf or its variant were replaced to EGI and Larb. The results showed that these enzymatic mixes are not suitable for the hydrolysis of NW after AFEX or EA pretreatment. On the other hand, when the enzymes rCelStrep, rPoAbf and rPoAbf F435Y/Y446F were tested for their effect in hydrolysis of pretreated NW by addition to a commercial enzyme mixture, it was shown that the total polysaccharides conversion yield reached 37.32 % for AFEX pretreated NW by adding rPoAbf to the mix whilst the maximum sugars conversion yield for EA pretreated NW was achieved 40.80 % by adding rCelStrep. The maximum glucan conversion yield obtained (45.61 % for EA pretreated NW by adding rCelStrep to the commercial mix) is higher than or comparable to those reported in recent manuscripts adopting hydrolysis conditions similar to those used

  14. TOMATO CLEANING AND WATER RECYCLE

    EPA Science Inventory

    A full-scale dump tank water recycle system was developed and demonstrated. A false bottom-ejector transport system removed soil from the water. Clarified water was either recycled back to the dump tank or discharged to the sewer. A vacuum belt was developed for dewatering the mu...

  15. Garbage project on recycling behavior

    SciTech Connect

    McGuire, R.H.; Hughes, W.W.; Rathje, W.L.

    1982-02-01

    Results are presented of a study undertaken to determine the factors which are most effective in motivating different socio-economic groups to change their recycling behaviors and participate in recycling programs. Four types of data were collected and analyzed in Tucson: (1) purchase data from local recyclers, (2) traditional interview-survey data on recycling behavior, (3) long-term and short-term household refuse data, and (4) combined interview-garbage data. Findings reveal that disposal patterns for newspapers and aluminum cans are tuse data, and (4) combined interview-garbage data. Findings reveal that disposal patterns for newspapers and aluminum cans are the same across census tracts with significantly different socio-economic characteristics. Further, analysis of interview and garbage data matched by household reaffirm that what people say about recycling and how they dispose of recyclable materials are two different things. Thus, interview reports of newspaper recycling correlate with higher income informants, but their interview reports do not correlate with what is thrown into their garbage cans. Money is concluded to be the most powerful incentive toward recycling.

  16. The Dynamic Earth: Recycling Naturally!

    ERIC Educational Resources Information Center

    Goldston, M. Jenice; Allison, Elizabeth; Fowler, Lisa; Glaze, Amanda

    2013-01-01

    This article begins with a thought-provoking question: What do you think of when you hear the term "recycle?" Many think about paper, glass, aluminum cans, landfills, and reducing waste by reusing some of these materials. How many of us ever consider the way the systems of Earth dynamically recycle its materials? In the following…

  17. Information Sources on Rural Recycling.

    ERIC Educational Resources Information Center

    Notess, Greg; Kuske, Jodee

    1992-01-01

    Provides resources for rural recycling operations with the principle aim of assisting rural government officials, planners, residents, and educators to encourage recycling as an integral part of an individual's or community's solid waste management plan. Sources range from bibliographies, directories, and government documents to case studies. (49…

  18. American Art of Conspicuous Recycling.

    ERIC Educational Resources Information Center

    Gomez, Aurelia

    1999-01-01

    Characterizes the use of recycling "junk" as a means for creating art by exploring various recycling traditions that are present in the United States. Demonstrates to students that "junk" can be fashioned into beautiful works of art. Offers four works of art and provides discussion questions and project ideas for each artwork. (CMK)

  19. Recycling Study Guide [Resource Packet].

    ERIC Educational Resources Information Center

    Wisconsin State Dept. of Natural Resources, Madison.

    This resource packet contains six documents developed by the Wisconsin Department of Natural Resources in order to help teachers infuse the environmental education topics of recycling and solid waste into social studies, art, English, health, mathematics, science, and environmental education classes. "Recycling Study Guide" contains 19 activities…

  20. Recycling Solid Waste in Chattanooga

    ERIC Educational Resources Information Center

    Vredeveld, Ruth; Martin, Robin

    1973-01-01

    Students undertook a group project in collaboration with city officials to study garbage types in the community and possibilities of recycling solid wastes. Data collected from various sources revealed that public attitude was favorable for recycling efforts and that it was feasible economically. (PS)

  1. Training Governments to Buy Recycled.

    ERIC Educational Resources Information Center

    Keller, Richard

    1995-01-01

    Describes a program developed by the Northeast Maryland Waste Disposal Authority to teach government buyers how to buy recycled materials. The program consists of a hands-on training seminar and a manual that offers step-by-step instructions for setting up a buy-recycled purchasing program. (LZ)

  2. Is recycling worth the trouble

    SciTech Connect

    Boltz, C.M.

    1995-03-01

    A panel of waste industry experts met recently at a Washington, DC, conference to discuss and debate the costs, benefits, and economics of recycling solid waste. The nearly unanimous conclusion from some of the speakers--that recycling, as it is implemented today, has costs that far outweigh its benefits--is evidence of a growing backlash among solid waste officials against a recycling movement they feel has been grossly over-inflated by environmental groups as a solution to a non-existent problem known as the garbage crisis. The public should not place such a strong emphasis on recycling as a cure-all for environmental problems, according to the panel of four waste management policy analysts at The State of Garbage'' session held in mid-January at the 1995 US/Canadian Federation Solid Waste Management Conference. Moreover, some panel members said, recycling should take place only if it makes economic sense.

  3. Study of an ammonia-based wet scrubbing process in a continuous flow system

    SciTech Connect

    Mao, James X.; Lee, Anita S.; Kitchin, John R.; Nulwala, Hunaid B.; Luebke, David R.; Damodaran, Krishnan

    2013-01-01

    A continuous gas and liquid flow, regenerative scrubbing process for CO{sub 2} capture was demonstrated at the bench-scale level. An aqueous ammonia-based solution captures CO{sub 2} from simulated flue gas in an absorber and releases a nearly pure stream of CO{sub 2} in the regenerator. After the regeneration, the solution of ammonium compounds is recycled to the absorber. The design of a continuous flow unit was based on earlier exploratory results from a semi-batch reactor, where a CO{sub 2} and N{sub 2} simulated flue gas mixture flowed through a well-mixed batch of ammonia-based solution. During the semi-batch tests, the solution was cycled between absorption and regeneration steps to measure the carrying capacity of the solution at various initial ammonia concentrations and temperatures. Consequentially, a series of tests were conducted on the continuous unit to observe the effect of various parameters on CO{sub 2} removal efficiency and regenerator effectiveness within the flow system. The parameters that were studied included absorber temperature, regenerator temperature, initial NH{sub 3} concentration, simulated flue gas flow rate, liquid solvent inventory in the flow system, and height of the packed-bed absorber. From this testing and subsequent testing, ammonia losses from both the absorption and regeneration steps were quantified, and attempts were made to maintain steady state during operations. Implications of experimental results with respect to process design are discussed.

  4. Critical litter moisture maximizes ammonia generation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The natural breakdown of litter (bedding material mixed with deposits of feces, feathers, spilled feed and water) generates ammonia in poultry houses. Good management practices can reduce ammonia concentrations in poultry houses. Findings from a recent publication indicate there is a critical litt...

  5. AMMONIA: POSSIBLE USE FOR PRESERVING FISH.

    PubMed

    SUBRAHMANYAN, V; LAHIRY, N L; MOORJANI, M N; BALAKRISHNANNAIR, R; KRISHNASWAMY, M A

    1963-10-11

    Eviscerated oil sardines (Sardinella longiceps) that have been treated with ammonia can be stored at a temperature of 25 degrees to 30 degrees C for more than 2 months without deterioration of their nutritive value. There is no measurable residue of ammonia in the final product. PMID:14057369

  6. Ammonia Production Using Pressure Swing Adsorption

    SciTech Connect

    2009-02-01

    This factsheet describes a research project whose overall objective is to develop and demonstrate a technically feasible and commercially viable system that integrates reaction to produce ammonia along with recovery of the products by adsorption separation methods and significantly decrease the energy requirement in ammonia production.

  7. CHRONIC TOXICITY OF AMMONIA OF RAINBOW TROUT

    EPA Science Inventory

    The chronic effects of ammonia to rainbow trout Salmo gairdneri were studied in a laboratory test conducted over a 5-year period. Fish were tested at five concentrations over the range 0.01-0.07 mg/liter un-ionized ammonia; the mean pH of the test water was 7.7, and the mean temp...

  8. Decontaminating Aluminum/Ammonia Heat Pipes

    NASA Technical Reports Server (NTRS)

    Jones, J. A.

    1985-01-01

    Internal gas slugs reduced or eliminated. Manufacturing method increases efficiency of aluminum heat pipes in which ammonia is working fluid by insuring pipe filled with nearly pure charge of ammonia. In new process heat pipe initially closed with stainless-steel valve instead of weld so pipe put through several cycles of filling, purging, and accelerated aging.

  9. Poultry litter moisture management to reduce ammonia

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Ammonia generation in poultry houses results from the natural breakdown of litter (bedding material mixed with deposits of feces, feathers, spilled feed and water). Good management practices can reduce ammonia concentrations in poultry houses. This factsheet relates findings from a recent publicat...

  10. Ammonia Solubility in High Concentration Salt Solutions

    SciTech Connect

    HEDENGREN, D.C.

    2000-02-01

    Solubility data for ammonia in water and various dilute solutions are abundant in the literature. However, there is a noticeable lack of ammonia solubility data for high salt, basic solutions of various mixtures of salts including those found in many of the Hanford Washington underground waste tanks. As a result, models based on solubility data for dilute salt solutions have been used to extrapolate to high salt solutions. These significant extrapolations need to be checked against actual laboratory data. Some indirect vapor measurements have been made. A more direct approach is to determine the ratio of solubility of ammonia in water to its solubility in high salt solutions. In various experiments, pairs of solutions, one of which is water and the other a high salt solution, are allowed to come to equilibrium with a common ammonia vapor pressure. The ratio of concentrations of ammonia in the two solutions is equal to the ratio of the respective ammonia solubilities (Henry's Law constants) at a given temperature. This information can then be used to refine the models that predict vapor space compositions of ammonia. Ammonia at Hanford is of concern because of its toxicity in the environment and its contribution to the flammability of vapor space gas mixtures in waste tanks.

  11. Measuring ammonia from space: limits and possibilities

    NASA Astrophysics Data System (ADS)

    Cady-Pereira, K. E.; Pinder, R. W.; Walker, J. T.; Bash, J. O.; Luo, M.; Henze, D. K.; Shephard, M. W.; Zhu, J.; Rinsland, C.

    2010-12-01

    Ammonia (NH3) is an important component in local, regional, and global tropospheric chemistry. Ammonia contributes significantly to several well-known environmental problems: excess deposition in terrestrial ecosystems can lead to soil acidification and loss of plant diversity, while in coastal ecosystems, it can cause eutrophication, algal blooms, and loss of fish and shellfish. In the atmosphere NH3 can combine with sulfates and nitric acid to form ammonium nitrate and ammonium sulfate, which constitute a substantial fraction of fine particulate matter (PM2.5). Nevertheless, there is great uncertainty in the magnitude and in the spatial/seasonal variability of ammonia concentrations and emissions. Retrievals of ammonia from spectra obtained from the Tropospheric Emission Spectrometer (TES) flying on the AURA satellite have the potential of significantly increasing our knowledge of the spatial and temporal variability of ammonia and of providing constraints on ammonia emissions through the use of inverse models at both the regional and global scales. We will present an updated evaluation of the TES ammonia retrievals using sensitivity studies, simulations, and in situ observations. We will demonstrate TES’ capability to discern spatial gradients and temporal variability in ammonia concentrations, with results from the TES transects over the Central Valley and North Carolina, as well as monthly means from TES global surveys. We will also show an example of using TES NH3 measurements to constrain surface emissions over North America.

  12. Regeneration of ammonia borane from polyborazylene

    DOEpatents

    Sutton, Andrew; Gordon, John C; Ott, Kevin C; Burrell, Anthony K

    2013-02-05

    Method of producing ammonia borane, comprising providing a reagent comprising a dehydrogenated material in a suitable solvent; and combining the reagent with a reducing agent comprising hydrazine, a hydrazine derivative, or combinations thereof, in a reaction which produces a mixture comprising ammonia borane.

  13. Method for releasing hydrogen from ammonia borane

    SciTech Connect

    Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

    2013-02-19

    A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

  14. Evaluation of ammonia emissions from broiler litter

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Ammonia emissions from poultry litter results in air pollution and can cause high levels of ammonia in poultry houses, which negatively impacts bird performance. The objectives of this study were to: (1) conduct a nitrogen (N) mass balance in broiler houses by measuring the N inputs (bedding, chick...

  15. Ammonia emissions from land application of manures

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Ammonia volatilization can be a major nitrogen (N) loss process for surface-applied manures. There is concern that current manure management practices are contributing to ammonia losses in the Mid-Atlantic region with subsequent reductions in air quality and increases in N losses to streams and est...

  16. Ammonia and hydrogen sulfide removal using biochar

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Reducing ammonia and hydrogen sulfide emissions from livestock facilities is an important issue for many communities and livestock producers. Ammonia has been regarded as odorous, precursor for particulate matter (PM), and contributed to livestock mortality. Hydrogen sulfide is highly toxic at elev...

  17. 21 CFR 573.180 - Anhydrous ammonia.

    Code of Federal Regulations, 2012 CFR

    2003-04-01

    ... 21 Food and Drugs 6 2003-04-01 2003-04-01 false Anhydrous ammonia. 573.180 Section 573.180 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES PERMITTED IN FEED AND DRINKING WATER OF ANIMALS Food Additive Listing § 573.180 Anhydrous ammonia....

  18. 27 CFR 21.96 - Ammonia, aqueous.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Ammonia, aqueous. 21.96 Section 21.96 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL FORMULAS FOR DENATURED ALCOHOL AND RUM Specifications for Denaturants § 21.96 Ammonia, aqueous. (a) Alkalinity....

  19. Dynamics of Ammonia Borane Using Neutron Scattering

    SciTech Connect

    Brown, Craig; Jacques, Teresa; Hess, Nancy J.; Daemen, Luke L.; Mamontov, Eugene; Linehan, John C.; Stowe, Ashley C.; Autrey, Thomas

    2006-11-15

    We have used both the backscattering (HFBS) and time-of-flight (DCS) neutron spectrometers to investigate the proton dynamics in ammonia borane, a compound of intense interest as a model for 'chemical hydrogen storage' materials. Results indicate that the deposition of ammonia borane on a mesoporous silicate results in longer proton residence times and lower energy barriers for proton motion compared to bulk ammonia borane. The reduced activation energy for proton motions may partly explain the improved thermolysis and lowering the activation barrier for the loss of the first equivalent of H2. In addition, the phonon density of states for neat ammonia borane compares well with other spectroscopic results, with the intense peak at 22 meV assigned to the librational NH3 and BH3 modes, whereas ammonia borane on MCM-41 displays a broad, featureless spectrum indicating a poorly crystalline material.

  20. Graphene liquid crystal retarded percolation for new high-k materials.

    PubMed

    Yuan, Jinkai; Luna, Alan; Neri, Wilfrid; Zakri, Cécile; Schilling, Tanja; Colin, Annie; Poulin, Philippe

    2015-01-01

    Graphene flakes with giant shape anisotropy are extensively used to establish connectedness electrical percolation in various heterogeneous systems. However, the percolation behaviour of graphene flakes has been recently predicted to be far more complicated than generally anticipated on the basis of excluded volume arguments. Here we confirm experimentally that graphene flakes self-assemble into nematic liquid crystals below the onset of percolation. The competition of percolation and liquid crystal transition provides a new route towards high-k materials. Indeed, near-percolated liquid-crystalline graphene-based composites display unprecedented dielectric properties with a dielectric constant improved by 260-fold increase as compared with the polymer matrix, while maintaining the loss tangent as low as 0.4. This performance is shown to depend on the structure of monodomains of graphene liquid-crystalline phases. Insights into how the liquid crystal phase transition interferes with percolation transition and thus alters the dielectric constant are discussed. PMID:26567720

  1. Graphene liquid crystal retarded percolation for new high-k materials

    NASA Astrophysics Data System (ADS)

    Yuan, Jinkai; Luna, Alan; Neri, Wilfrid; Zakri, Cécile; Schilling, Tanja; Colin, Annie; Poulin, Philippe

    2015-11-01

    Graphene flakes with giant shape anisotropy are extensively used to establish connectedness electrical percolation in various heterogeneous systems. However, the percolation behaviour of graphene flakes has been recently predicted to be far more complicated than generally anticipated on the basis of excluded volume arguments. Here we confirm experimentally that graphene flakes self-assemble into nematic liquid crystals below the onset of percolation. The competition of percolation and liquid crystal transition provides a new route towards high-k materials. Indeed, near-percolated liquid-crystalline graphene-based composites display unprecedented dielectric properties with a dielectric constant improved by 260-fold increase as compared with the polymer matrix, while maintaining the loss tangent as low as 0.4. This performance is shown to depend on the structure of monodomains of graphene liquid-crystalline phases. Insights into how the liquid crystal phase transition interferes with percolation transition and thus alters the dielectric constant are discussed.

  2. Graphene liquid crystal retarded percolation for new high-k materials

    PubMed Central

    Yuan, Jinkai; Luna, Alan; Neri, Wilfrid; Zakri, Cécile; Schilling, Tanja; Colin, Annie; Poulin, Philippe

    2015-01-01

    Graphene flakes with giant shape anisotropy are extensively used to establish connectedness electrical percolation in various heterogeneous systems. However, the percolation behaviour of graphene flakes has been recently predicted to be far more complicated than generally anticipated on the basis of excluded volume arguments. Here we confirm experimentally that graphene flakes self-assemble into nematic liquid crystals below the onset of percolation. The competition of percolation and liquid crystal transition provides a new route towards high-k materials. Indeed, near-percolated liquid-crystalline graphene-based composites display unprecedented dielectric properties with a dielectric constant improved by 260-fold increase as compared with the polymer matrix, while maintaining the loss tangent as low as 0.4. This performance is shown to depend on the structure of monodomains of graphene liquid-crystalline phases. Insights into how the liquid crystal phase transition interferes with percolation transition and thus alters the dielectric constant are discussed. PMID:26567720

  3. Continuum percolation on nonorientable surfaces: the problem of permeable disks on a Klein bottle

    NASA Astrophysics Data System (ADS)

    Borman, V. D.; Grekhov, A. M.; Tronin, V. N.; Tronin, I. V.

    2015-11-01

    The percolation threshold and wrapping probability (R ∞) for the two-dimensional problem of continuum percolation on the surface of a Klein bottle have been calculated by the Monte Carlo method with the Newman-Ziff algorithm for completely permeable disks. It has been shown that the percolation threshold of disks on the Klein bottle coincides with the percolation threshold of disks on the surface of a torus, indicating that this threshold is topologically invariant. The scaling exponents determining corrections to the wrapping probability and critical concentration owing to the finite-size effects are also topologically invariant. At the same time, the quantities R ∞ are different for percolation on the torus and Klein bottle and are apparently determined by the topology of the surface. Furthermore, the difference between the R ∞ values for the torus and Klein bottle means that at least one of the percolation clusters is degenerate.

  4. Clinical utility of breath ammonia for evaluation of ammonia physiology in healthy and cirrhotic adults

    PubMed Central

    Spacek, Lisa A; Mudalel, Matthew; Tittel, Frank; Risby, Terence H; Solga, Steven F

    2016-01-01

    Blood ammonia is routinely used in clinical settings to assess systemic ammonia in hepatic encephalopathy and urea cycle disorders. Despite its drawbacks, blood measurement is often used as a comparator in breath studies because it is a standard clinical test. We sought to evaluate sources of measurement error and potential clinical utility of breath ammonia compared to blood ammonia. We measured breath ammonia in real time by quartz enhanced photoacoustic spectrometry and blood ammonia in 10 healthy and 10 cirrhotic participants. Each participant contributed 5 breath samples and blood for ammonia measurement within 1 h. We calculated the coefficient of variation (CV) for 5 breath ammonia values, reported medians of healthy and cirrhotic participants, and used scatterplots to display breath and blood ammonia. For healthy participants, mean age was 22 years (±4), 70% were men, and body mass index (BMI) was 27 (±5). For cirrhotic participants, mean age was 61 years (±8), 60% were men, and BMI was 31 (±7). Median blood ammonia for healthy participants was within normal range, 10 μmol L−1 (interquartile range (IQR), 3–18) versus 46 μmol L−1 (IQR, 23–66) for cirrhotic participants. Median breath ammonia was 379 pmol mL−1 CO2 (IQR, 265–765) for healthy versus 350 pmol mL−1 CO2 (IQR, 180–1013) for cirrhotic participants. CV was 17 ± 6%. There remains an important unmet need in the evaluation of systemic ammonia, and breath measurement continues to demonstrate promise to fulfill this need. Given the many differences between breath and blood ammonia measurement, we examined biological explanations for our findings in healthy and cirrhotic participants. We conclude that based upon these preliminary data breath may offer clinically important information this is not provided by blood ammonia. PMID:26658550

  5. Magnetically separable and recyclable urchin-like Co-P hollow nanocomposites for catalytic hydrogen generation

    NASA Astrophysics Data System (ADS)

    Guo, Huizhang; Liu, Xiang; Hou, Yuhui; Xie, QingShui; Wang, Laisen; Geng, Hao; Peng, Dong-Liang

    2014-08-01

    One-pot well-controlled synthetic strategy was developed to achieve urchin-like Co-P hollow nanocomposites with tailorable magnetic properties which enable them to perform as magnetically recyclable nanocatalysts in a "quasi-homogeneous" system for the catalytic hydrogen generation via hydrolysis of Ammonia-Borane (AB). The key point of this strategy was that ferromagnetic Co nanoparticles (NPs) were embedded into paramagnetic Co2P matrix to form magnetic nanocomposites. The as-prepared Co-P NPs showed appreciable catalytic activity, recyclability and durability in hydrolysis of AB. Moreover, the chemical regeneration of AB from the "hydrolyzate" may also benefit from these magnetically recyclable catalysts. We further highlighted the excellent high-temperature resistance of Co-P NPs by calcining them at 300 °C and 600 °C. Our research may facilitate the practical application of AB as a sustainable hydrogen storage material for hydrogen-based energy.

  6. Regeneration of ammonia borane spent fuel

    SciTech Connect

    Sutton, Andrew David; Davis, Benjamin L; Gordon, John C

    2009-01-01

    A necessary target in realizing a hydrogen (H{sub 2}) economy, especially for the transportation sector, is its storage for controlled delivery, presumably to an energy producing fuel cell. In this vein, the U.S. Department of Energy's Centers of Excellence (CoE) in Hydrogen Storage have pursued different methodologies, including metal hydrides, chemical hydrides, and sorbents, for the expressed purpose of supplanting gasoline's current > 300 mile driving range. Chemical H{sub 2} storage has been dominated by one appealing material, ammonia borane (H{sub 3}N-BH{sub 3}, AB), due to its high gravimetric capacity of H{sub 2} (19.6 wt %) and low molecular weight (30.7 g mol{sup -1}). In addition, AB has both hydridic and protic moieties, yielding a material from which H{sub 2} can be readily released in contrast to the loss of H{sub 2} from C{sub 2}H{sub 6} which is substantially endothermic. As such, a number of publications have described H{sub 2} release from amine boranes, yielding various rates depending on the method applied. The viability of any chemical H{sub 2} storage system is critically dependent on efficient recyclability, but reports on the latter subject are sparse, invoke the use of high energy reducing agents, and suffer from low yields. Our group is currently engaged in trying to find and fully demonstrate an energy efficient regeneration process for the spent fuel from H{sub 2} depleted AB with a minimum number of steps. Although spent fuel composition depends on the dehydrogenation method, we have focused our efforts on the spent fuel resulting from metal-based catalysis, which has thus far shown the most promise. Metal-based catalysts have produced the fastest rates for a single equivalent of H{sub 2} released from AB and up to 2.5 equiv. of H{sub 2} can be produced within 2 hours. While ongoing work is being carried out to tailor the composition of spent AB fuel, a method has been developed for regenerating the predominant product, polyborazylene

  7. Spatial and temporal variations in percolation fluxes in a tropical Andosol influenced by banana cropping patterns

    NASA Astrophysics Data System (ADS)

    Cattan, P.; Voltz, M.; Cabidoche, Y.-M.; Lacas, J.-G.; Sansoulet, J.

    2007-03-01

    SummarySpatial variability in percolation fluxes was studied in field plots cropped with banana plants, which induce very heterogeneous rainfall partitioning at the soil surface, with high subsequent infiltration in Andosols. Percolation fluxes were measured for just over a year at 1-7 day intervals in eight wick (WL) and gravity lysimeters (GL) that had been buried in the soil at a depth of 60 cm. The results revealed that WL captured unsaturated fluxes while GL only functioned after ponding occurred. The percolation flux measurements were highly biased with both systems, i.e. overpercolation with WL and underpercolation with GL. Percolation fluxes seemed, however, to be mainly unsaturated in the soil types studied. High percolation flux variability was noted on a plot scale, which could be explained by the vegetation structure: total percolation flux (WL) was 2.1-fold higher under banana plants; saturated percolation flux (GL) was 7-fold higher under banana plants and almost absent between banana plants. Eighty-eight per cent of the total variance in percolation flux could be explained by the rainfall intensity under the banana canopy, calculated while taking the rainfall partitioning by the vegetation and the initial water status into account. The number of lysimeters required for assessing percolation flux in a field plot can be reduced by taking the spatial patterns of the flux boundary conditions into account.

  8. Series Expansion Method for Asymmetrical Percolation Models with Two Connection Probabilities

    NASA Astrophysics Data System (ADS)

    Inui, Norio; Komatsu, Genichi; Kameoka, Koichi

    2000-01-01

    In order to study the solvability of the percolation model based on Guttmann and Enting's conjecture, the power series for the percolation probability in the form of ∑nHn(q)pn is examined. Although the power series is given by calculating inverse of the transfer-matrix in principle, it is very hard to obtain the inverse matrix containing many complex polynomials as elements. We introduce a new series expansion technique which does not necessitate inverse operation for the transfer-matrix.By using the new procedure, we derive the series of the asymmetrical percolation probability including the isotropic percolation probability as a special case.

  9. Two percolation thresholds and remarkably high dielectric permittivity in pristine carbon nanotube/elastomer composites

    NASA Astrophysics Data System (ADS)

    Shehzad, Khurram; Hakro, Ayaz Ali; Zeng, You; Yao, Shang-Hong; Xiao-Hong, Yi; Mumtaz, Muhammad; Nadeem, Kashif; Khisro, Nasir Said; Dang, Zhi-Min

    2015-11-01

    Pristine carbon nanotube (CNT)/elastomer composites were fabricated using pristine multi-walled carbon nanotubes and a thermoplastic elastomer. These composites exhibited a unique phenomenon of two electrical percolation thresholds that invoked very high dielectric values for the resulting composites. The first percolation was associated with a relatively low dielectric constant value of about 100, while in the vicinity of the second percolation threshold a very high dielectric constant value of 8,000 was achieved. The presence of two percolation thresholds was attributed to the unique distribution patterns of CNTs that ensued in a CNT/elastomer composite system with unique electrical properties.

  10. Percolation in spatial evolutionary prisoner's dilemma game on two-dimensional lattices

    NASA Astrophysics Data System (ADS)

    Choi, Woosik; Yook, Soon-Hyung; Kim, Yup

    2015-11-01

    We study the spatial evolutionary prisoner's dilemma game with updates of imitation max on triangular, hexagonal, and square lattices. We use the weak prisoner's dilemma game with a single parameter b . Due to the competition between the temptation value b and the coordination number z of the base lattice, a greater variety of percolation properties is expected to occur on the lattice with the larger z . From the numerical analysis, we find six different regimes on the triangular lattice (z =6 ). Regardless of the initial densities of cooperators and defectors, cooperators always percolate in the steady state in two regimes for small b . In these two regimes, defectors do not percolate. In two regimes for the intermediate value of b , both cooperators and defectors undergo percolation transitions. The defector always percolates in two regimes for large b . On the hexagonal lattice (z =3 ), there exist two distinctive regimes. For small b , both the cooperators and the defectors undergo percolation transitions while only defectors always percolate for large b . On the square lattice (z =4 ), there exist three regimes. Combining with the finite-size scaling analyses, we show that all the observed percolation transitions belong to the universality class of the random percolation. We also show how the detailed growth mechanism of cooperator and defector clusters decides each regime.

  11. Plastics recycling: challenges and opportunities

    PubMed Central

    Hopewell, Jefferson; Dvorak, Robert; Kosior, Edward

    2009-01-01

    Plastics are inexpensive, lightweight and durable materials, which can readily be moulded into a variety of products that find use in a wide range of applications. As a consequence, the production of plastics has increased markedly over the last 60 years. However, current levels of their usage and disposal generate several environmental problems. Around 4 per cent of world oil and gas production, a non-renewable resource, is used as feedstock for plastics and a further 3–4% is expended to provide energy for their manufacture. A major portion of plastic produced each year is used to make disposable items of packaging or other short-lived products that are discarded within a year of manufacture. These two observations alone indicate that our current use of plastics is not sustainable. In addition, because of the durability of the polymers involved, substantial quantities of discarded end-of-life plastics are accumulating as debris in landfills and in natural habitats worldwide. Recycling is one of the most important actions currently available to reduce these impacts and represents one of the most dynamic areas in the plastics industry today. Recycling provides opportunities to reduce oil usage, carbon dioxide emissions and the quantities of waste requiring disposal. Here, we briefly set recycling into context against other waste-reduction strategies, namely reduction in material use through downgauging or product reuse, the use of alternative biodegradable materials and energy recovery as fuel. While plastics have been recycled since the 1970s, the quantities that are recycled vary geographically, according to plastic type and application. Recycling of packaging materials has seen rapid expansion over the last decades in a number of countries. Advances in technologies and systems for the collection, sorting and reprocessing of recyclable plastics are creating new opportunities for recycling, and with the combined actions of the public, industry and governments it

  12. Plastics recycling: challenges and opportunities.

    PubMed

    Hopewell, Jefferson; Dvorak, Robert; Kosior, Edward

    2009-07-27

    Plastics are inexpensive, lightweight and durable materials, which can readily be moulded into a variety of products that find use in a wide range of applications. As a consequence, the production of plastics has increased markedly over the last 60 years. However, current levels of their usage and disposal generate several environmental problems. Around 4 per cent of world oil and gas production, a non-renewable resource, is used as feedstock for plastics and a further 3-4% is expended to provide energy for their manufacture. A major portion of plastic produced each year is used to make disposable items of packaging or other short-lived products that are discarded within a year of manufacture. These two observations alone indicate that our current use of plastics is not sustainable. In addition, because of the durability of the polymers involved, substantial quantities of discarded end-of-life plastics are accumulating as debris in landfills and in natural habitats worldwide. Recycling is one of the most important actions currently available to reduce these impacts and represents one of the most dynamic areas in the plastics industry today. Recycling provides opportunities to reduce oil usage, carbon dioxide emissions and the quantities of waste requiring disposal. Here, we briefly set recycling into context against other waste-reduction strategies, namely reduction in material use through downgauging or product reuse, the use of alternative biodegradable materials and energy recovery as fuel. While plastics have been recycled since the 1970s, the quantities that are recycled vary geographically, according to plastic type and application. Recycling of packaging materials has seen rapid expansion over the last decades in a number of countries. Advances in technologies and systems for the collection, sorting and reprocessing of recyclable plastics are creating new opportunities for recycling, and with the combined actions of the public, industry and governments it

  13. Performance Testing of the Vapor Phase Catalytic Ammonia Removal Engineering Development Unit

    NASA Technical Reports Server (NTRS)

    Flynn, Michael; Tleimat, Maher; Nalette, Tim; Quinn, Gregory

    2005-01-01

    This paper describes the results of performance testing of the Vapor Phase Catalytic Ammonia Removal (VPCAR) technology. The VPCAR technology is currently being developed by NASA as a Mars transit vehicle water recycling system. NASA has recently completed-a grant-to develop a next generation VPCAR system. This grant concluded with the shipment of the final deliverable to NASA on 8/31/03. This paper presents the results of mass, power, volume, and acoustic measurements for the delivered system. Product water purity analysis for a Mars transit mission and a simulated planetary base wastewater ersatz are also provided.

  14. Vapor Phase Catalytic Ammonia Reduction

    NASA Technical Reports Server (NTRS)

    Flynn, Michael T.; Harper, Lynn D. (Technical Monitor)

    1994-01-01

    This paper discusses the development of a Vapor Phase Catalytic Ammonia Reduction (VPCAR) teststand and the results of an experimental program designed to evaluate the potential of the technology as a water purification process. In the experimental program the technology is evaluated based upon product water purity, water recovery rate, and power consumption. The experimental work demonstrates that the technology produces high purity product water and attains high water recovery rates at a relatively high specific power consumption. The experimental program was conducted in 3 phases. In phase I an Igepon(TM) soap and water mixture was used to evaluate the performance of an innovative Wiped-Film Rotating-Disk evaporator and associated demister. In phase II a phenol-water solution was used to evaluate the performance of the high temperature catalytic oxidation reactor. In phase III a urine analog was used to evaluate the performance of the combined distillation/oxidation functions of the processor.

  15. Rigidity percolation in dispersions with a structured viscoelastic matrix

    NASA Astrophysics Data System (ADS)

    Wilbrink, M. W. L.; Michels, M. A. J.; Vellinga, W. P.; Meijer, H. E. H.

    2005-03-01

    This paper deals with rigidity percolation in composite materials consisting of a dispersion of mineral particles in a microstructured viscoelastic matrix. The viscoelastic matrix in this specific case is a hydrocarbon refinery residue. In a set of model random composites the mean interparticle surface-to-surface distance was controlled, changing particle volume fraction φ and particle number density independently. This was achieved by mixing two sets of monodisperse particles with widely differing radii ( 0.35μm and 17.5μm ) with the matrix. A scaling exponent of 3.9±0.6 for the storage modulus G' vs φ-φc was observed above a threshold φc , in good agreement with theoretical values for rigidity percolation. It is found that at the rigidity-percolation threshold the pore structure, as characterized by the mean surface-to-surface distance for the filler, rather than the filler volume fraction, is similar for different types of composites. This behavior is explained from the internal structure of the viscoelastic matrix, which consists of fractal solid aggregates dissolved in a viscous medium; the effective radius of these aggregates and the mean surface-to-surface distance together determine whether or not the aggregates are capable of providing rigidity to the composite. The explanation is further supported by a qualitative comparison with effective-medium calculations. These indicate that the observed breakdown of time-temperature superposition near φc is due to the appearance of a time scale characteristic for the mechanical interplay between the viscous binder phase and the purely elastic solid particles.

  16. Predicting deep percolation with eddy covariance under mulch drip irrigation

    NASA Astrophysics Data System (ADS)

    Ming, Guanghui; Tian, Fuqiang; Hu, Hongchang

    2016-04-01

    Water is essential for the agricultural development and ecological sustainability of the arid and semi-arid oasis with rare precipitation input and high evaporation demand. Deep percolation (DP) defined as excess irrigation water percolating below the plant root zone will reduce irrigation water use efficiency (WUE). But the DP was often ignored in mulch drip irrigation (MDI) which has reached the area of 1.6 million hectares in Xinjiang, the northwest of China. In this study DP experiments were conducted at an agricultural experiment station located within an irrigation district in the Tarim River Basin for four cotton growing periods. First it was detected the irrigation water infiltrated into the soil layers below 100cm and the groundwater level responded to the irrigation events well. Then DP below 100cm soil layers was calculated using the soil water balance method with the aid of eddy covariance (with the energy balance closure of 0.72). The negative DP (groundwater contribution to the crop-water use through capillary rising) at the seedling and harvesting stages can reach 77mm and has a good negative correlation with the groundwater level and positive correlation with potential evaporation. During the drip irrigation stage approximately 45% of the irrigation became DP and resulted in the low irrigation WUE of 0.6. The DP can be 164mm to 270mm per year which was positive linearly correlated to irrigation depth and negative linear correlated to irrigation interval. It is better to establish the irrigation schedule with small irrigation depth and given frequently to reduce deep percolation and meet crop needs.

  17. Limited-path-length entanglement percolation in quantum complex networks

    NASA Astrophysics Data System (ADS)

    Cuquet, Martí; Calsamiglia, John

    2011-03-01

    We study entanglement distribution in quantum complex networks where nodes are connected by bipartite entangled states. These networks are characterized by a complex structure, which dramatically affects how information is transmitted through them. For pure quantum state links, quantum networks exhibit a remarkable feature absent in classical networks: it is possible to effectively rewire the network by performing local operations on the nodes. We propose a family of such quantum operations that decrease the entanglement percolation threshold of the network and increase the size of the giant connected component. We provide analytic results for complex networks with an arbitrary (uncorrelated) degree distribution. These results are in good agreement with numerical simulations, which also show enhancement in correlated and real-world networks. The proposed quantum preprocessing strategies are not robust in the presence of noise. However, even when the links consist of (noisy) mixed-state links, one can send quantum information through a connecting path with a fidelity that decreases with the path length. In this noisy scenario, complex networks offer a clear advantage over regular lattices, namely, the fact that two arbitrary nodes can be connected through a relatively small number of steps, known as the small-world effect. We calculate the probability that two arbitrary nodes in the network can successfully communicate with a fidelity above a given threshold. This amounts to working out the classical problem of percolation with a limited path length. We find that this probability can be significant even for paths limited to few connections and that the results for standard (unlimited) percolation are soon recovered if the path length exceeds by a finite amount the average path length, which in complex networks generally scales logarithmically with the size of the network.

  18. Coal liquefaction with preasphaltene recycle

    DOEpatents

    Weimer, Robert F.; Miller, Robert N.

    1986-01-01

    A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

  19. Recycling and Life Cycle Issues

    SciTech Connect

    Das, Sujit

    2010-01-01

    This chapter addresses recycling and life cycle considerations related to the growing use of lightweight materials in vehicles. The chapter first addresses the benefit of a life cycle perspective in materials choice, and the role that recycling plays in reducing energy inputs and environmental impacts in a vehicle s life cycle. Some limitations of life cycle analysis and results of several vehicle- and fleet-level assessments are drawn from published studies. With emphasis on lightweight materials such as aluminum, magnesium, and polymer composites, the status of the existing recycling infrastructure and technological challenges being faced by the industry also are discussed.

  20. From damage percolation to crack nucleation through finite size criticality.

    PubMed

    Shekhawat, Ashivni; Zapperi, Stefano; Sethna, James P

    2013-05-01

    We present a unified theory of fracture in disordered brittle media that reconciles apparently conflicting results reported in the literature. Our renormalization group based approach yields a phase diagram in which the percolation fixed point, expected for infinite disorder, is unstable for finite disorder and flows to a zero-disorder nucleation-type fixed point, thus showing that fracture has a mixed first order and continuous character. In a region of intermediate disorder and finite system sizes, we predict a crossover with mean-field avalanche scaling. We discuss intriguing connections to other phenomena where critical scaling is only observed in finite size systems and disappears in the thermodynamic limit. PMID:23683218

  1. Inequality for the infinite-cluster density in Bernoulli percolation

    SciTech Connect

    Chayes, J.T.; Chayes, L.

    1986-04-21

    Under a certain assumption (which is satisfied whenever there is a dense infinite cluster in the half-space), we prove a differential inequality for the infinite-cluster density, P/sub infinity/(p), in Bernoulli percolation. The principal implication of this result is that if P/sub infinity/(p) vanishes with critical exponent ..beta.., then ..beta.. obeys the mean-field bound ..beta..< or =1. As a corollary, we also derive an inequality relating the backbone density, the truncated susceptibility, and the infinite-cluster density.

  2. Tight Lower Bound for Percolation Threshold on an Infinite Graph

    NASA Astrophysics Data System (ADS)

    Hamilton, Kathleen E.; Pryadko, Leonid P.

    2014-11-01

    We construct a tight lower bound for the site percolation threshold on an infinite graph, which becomes exact for an infinite tree. The bound is given by the inverse of the maximal eigenvalue of the Hashimoto matrix used to count nonbacktracking walks on the original graph. Our bound always exceeds the inverse spectral radius of the graph's adjacency matrix, and it is also generally tighter than the existing bound in terms of the maximum degree. We give a constructive proof for existence of such an eigenvalue in the case of a connected infinite quasitransitive graph, a graph-theoretic analog of a translationally invariant system.

  3. Percolation, sliding, localization and relaxation in topologically closed circuits

    PubMed Central

    Hurowitz, Daniel; Cohen, Doron

    2016-01-01

    Considering a random walk in a random environment in a topologically closed circuit, we explore the implications of the percolation and sliding transitions for its relaxation modes. A complementary question regarding the “delocalization” of eigenstates of non-hermitian Hamiltonians has been addressed by Hatano, Nelson, and followers. But we show that for a conservative stochastic process the implied spectral properties are dramatically different. In particular we determine the threshold for under-damped relaxation, and observe “complexity saturation” as the bias is increased. PMID:26961586

  4. Percolation and coarsening in the bidimensional voter model

    NASA Astrophysics Data System (ADS)

    Tartaglia, Alessandro; Cugliandolo, Leticia F.; Picco, Marco

    2015-10-01

    We study the bidimensional voter model on a square lattice with numerical simulations. We demonstrate that the evolution takes place in two distinct dynamic regimes; a first approach towards critical site percolation and a further approach towards full consensus. We calculate the time dependence of the two growing lengths, finding that they are both algebraic but with different exponents (apart from possible logarithmic corrections). We analyze the morphology and statistics of clusters of voters with the same opinion. We compare these results to the ones for curvature driven two-dimensional coarsening.

  5. Percolation Theory for the Distribution and Abundance of Species

    NASA Astrophysics Data System (ADS)

    He, Fangliang; Hubbell, Stephen P.

    2003-11-01

    We develop and test new models that unify the mathematical relationships among the abundance of a species, the spatial dispersion of the species, the number of patches occupied by the species, the edge length of the occupied patches, and the scale on which the distribution of species is mapped. The models predict that species distributions will exhibit percolation critical thresholds, i.e., critical population abundances at which the fragmented patches (as measured by the number of patches and edge length) start to coalesce to form large patches.

  6. RAPID COMMUNICATION: Percolation modelling for highly aligned polycrystalline superconducting tapes

    NASA Astrophysics Data System (ADS)

    Rutter, N. A.; Glowacki, B. A.; Evetts, J. E.

    2000-11-01

    Surface and bulk texture measurements have been carried out on highly aligned NiFe tapes, suitable for use as coated conductor substrates. Data from small-area electron backscatter diffraction measurements are compared with those from bulk x-ray analysis in the development of a two-dimensional percolation model, and the two are shown to give very similar results. No evidence of grain-to-grain correlation is found. The model is then developed to assess how the properties of a superconducting layer grown epitaxially on buffered tapes will depend on parameters such as sample size, grain size and the extent of grain alignment.

  7. Fixed-energy sandpiles belong generically to directed percolation.

    PubMed

    Basu, Mahashweta; Basu, Urna; Bondyopadhyay, Sourish; Mohanty, P K; Hinrichsen, Haye

    2012-07-01

    Fixed-energy sandpiles with stochastic update rules are known to exhibit a nonequilibrium phase transition from an active phase into infinitely many absorbing states. Examples include the conserved Manna model, the conserved lattice gas, and the conserved threshold transfer process. It is believed that the transitions in these models belong to an autonomous universality class of nonequilibrium phase transitions, the so-called Manna class. Contrarily, the present numerical study of selected (1+1)-dimensional models in this class suggests that their critical behavior converges to directed percolation after very long time, questioning the existence of an independent Manna class. PMID:23031115

  8. Percolation in insect nest networks: Evidence for optimal wiring

    NASA Astrophysics Data System (ADS)

    Valverde, Sergi; Corominas-Murtra, Bernat; Perna, Andrea; Kuntz, Pascale; Theraulaz, Guy; Solé, Ricard V.

    2009-06-01

    Optimization has been shown to be a driving force for the evolution of some biological structures, such as neural maps in the brain or transport networks. Here we show that insect networks also display characteristic traits of optimality. By using a graph representation of the chamber organization of termite nests and a disordered lattice model, it is found that these spatial nests are close to a percolation threshold. This suggests that termites build efficient systems of galleries spanning most of the nest volume at low cost. The evolutionary consequences are outlined.

  9. Ammonia synthesis using magnetic induction method (MIM)

    NASA Astrophysics Data System (ADS)

    Puspitasari, P.; Razak, J. Abd; Yahya, N.

    2012-09-01

    The most challenging issues for ammonia synthesis is to get the high yield. New approach of ammonia synthesis by using Magnetic Induction Method (MIM) and the Helmholtz Coils has been proposed. The ammonia detection was done by using Kjeldahl Method and FTIR. The system was designed by using Autocad software. The magnetic field of MIM was vary from 100mT-200mT and the magnetic field for the Helmholtz coils was 14mT. The FTIR result shows that ammonia has been successfully formed at stretching peaks 1097,1119,1162,1236, 1377, and 1464 cm-1. UV-VIS result shows the ammonia bond at 195nm of wavelength. The ammonia yield was increase to 244.72μmole/g.h by using the MIM and six pairs of Helmholtz coils. Therefore this new method will be a new promising method to achieve the high yield ammonia at ambient condition (at 25δC and 1atm), under the Magnetic Induction Method (MIM).

  10. INFRARED SPECTRA OF AMMONIA-WATER ICES

    SciTech Connect

    Zheng Weijun; Jewitt, David; Kaiser, Ralf I. E-mail: ralfk@hawaii.edu

    2009-03-15

    We conducted a systematic study of the near-IR and mid-IR spectra of ammonia-water ices at various NH{sub 3}/H{sub 2}O ratios. The differences between the spectra of amorphous and crystalline ammonia-water ices were also investigated. The 2.0 {mu}m ammonia band central wavelength is a function of the ammonia/water ratio. It shifts from 2.006 {+-} 0.003 {mu}m (4985 {+-} 5 cm{sup -1}) to 1.993 {+-} 0.003 {mu}m (5018 {+-} 5 cm{sup -1}) as the percentage of ammonia decreases from 100% to 1%. The 2.2 {mu}m ammonia band center shifts from 2.229 {+-} 0.003 {mu}m (4486 {+-} 5 cm{sup -1}) to 2.208 {+-} 0.003 {mu}m (4528 {+-} 5 cm{sup -1}) over the same range. Temperature-dependent shifts of those bands are below the uncertainty of the measurement, and therefore are not detectable. These results are important for comparison with astronomical observations as well as for estimating the concentration of ammonia in outer solar system ices.

  11. Highly compressed ammonia forms an ionic crystal.

    PubMed

    Pickard, Chris J; Needs, R J

    2008-10-01

    Ammonia is an important compound with many uses, such as in the manufacture of fertilizers, explosives and pharmaceuticals. As an archetypal hydrogen-bonded system, the properties of ammonia under pressure are of fundamental interest, and compressed ammonia has a significant role in planetary physics. We predict new high-pressure crystalline phases of ammonia (NH(3)) through a computational search based on first-principles density-functional-theory calculations. Ammonia is known to form hydrogen-bonded solids, but we predict that at higher pressures it will form ammonium amide ionic solids consisting of alternate layers of NH(4)(+) and NH(2)(-) ions. These ionic phases are predicted to be stable over a wide range of pressures readily obtainable in laboratory experiments. The occurrence of ionic phases is rationalized in terms of the relative ease of forming ammonium and amide ions from ammonia molecules, and the volume reduction on doing so. We also predict that the ionic bonding cannot be sustained under extreme compression and that, at pressures beyond the reach of current static-loading experiments, ammonia will return to hydrogen-bonded structures consisting of neutral NH(3) molecules. PMID:18724375

  12. From Earth to Space: Application of Biological Treatment for the Removal of Ammonia from Water

    NASA Technical Reports Server (NTRS)

    Ghosh, Amlan; Seidel, Chad; Adam, Niklas; Pickering, Karen; White, Dawn

    2014-01-01

    Managing ammonia is often a challenge in both drinking water and wastewater treatment facilities. Ammonia is unregulated in drinking water, but its presence may result in numerous water quality issues in the distribution system such as loss of residual disinfectant, nitrification, and corrosion. Ammonia concentrations need to be managed in wastewater effluent to sustain the health of receiving water bodies. Biological treatment involves the microbiological oxidation of ammonia to nitrate through a two-step process. While nitrification is common in the environment, and nitrifying bacteria can grow rapidly on filtration media, appropriate conditions, such as the presence of dissolved oxygen and required nutrients, need to be established. This presentation will highlight results from two ongoing research programs - one at NASA's Johnson Space Center, and the other at a drinking water facility in California. Both programs are designed to demonstrate nitrification through biological treatment. The objective of NASA's research is to be able to recycle wastewater to potable water for spaceflight mission. To this end, a biological water processor (BWP) has been integrated with a forward osmosis secondary treatment system (FOST). Bacteria mineralize organic carbon to carbon dioxide as well as ammonia-nitrogen present in the wastewater to nitrogen gas, through a combination of nitrification and denitrification. The effluent from the BWP system is low in organic contaminants, but high in total dissolved solids. The FOST system, integrated downstream of the BWP, removes dissolved solids through a combination of concentration-driven forward osmosis and pressure driven reverse osmosis. The integrated system testing planned for this year is expected to produce water that requires only a polishing step to meet potable water requirements for spaceflight. The pilot study in California is being conducted on Golden State Water Company's Yukon wellsthat have hydrogen sulfide odor

  13. From Earth to Space: Application of Biological Treatment for the Removal of Ammonia from Water

    NASA Technical Reports Server (NTRS)

    Pickering, Karen; Adam, Niklas; White, Dawn; Ghosh, Amlan; Seidel, Chad

    2014-01-01

    Managing ammonia is often a challenge in both drinking water and wastewater treatment facilities. Ammonia is unregulated in drinking water, but its presence may result in numerous water quality issues in the distribution system such as loss of residual disinfectant, nitrification, and corrosion. Ammonia concentrations need to be managed in wastewater effluent to sustain the health of receiving water bodies. Biological treatment involves the microbiological oxidation of ammonia to nitrate through a two-step process. While nitrification is common in the environment, and nitrifying bacteria can grow rapidly on filtration media, appropriate conditions, such as the presence of dissolved oxygen and required nutrients, need to be established. This presentation will highlight results from two ongoing research programs - one at NASA's Johnson Space Center, and the other at a drinking water facility in California. Both programs are designed to demonstrate nitrification through biological treatment. The objective of NASA's research is to be able to recycle wastewater to potable water for spaceflight missions. To this end, a biological water processor (BWP) has been integrated with a forward osmosis secondary treatment system (FOST). Bacteria mineralize organic carbon to carbon dioxide as well as ammonia-nitrogen present in the wastewater to nitrogen gas, through a combination of nitrification and denitrification. The effluent from the BWP system is low in organic contaminants, but high in total dissolved solids. The FOST system, integrated downstream of the BWP, removes dissolved solids through a combination of concentration-driven forward osmosis and pressure driven reverse osmosis. The integrated system testing planned for this year is expected to produce water that requires only a polishing step to meet potable water requirements for spaceflight. The pilot study in California is being conducted on Golden State Water Company's Yukon wells that have hydrogen sulfide odor

  14. Progress reported in PET recycling

    SciTech Connect

    Not Available

    1989-06-01

    The Goodyear Polyester Division has demonstrated its ability to break down polyethylene terephthalate (PET) from recycled plastic soft drink bottles and remanufacture the material into PET suitable for containers. Most people are familiar with PET in the form of lightweight, shatter resistant beverage bottles. About 20 percent of these beverage containers currently are being recycled. The recycled PET is currently used in many applications such as carpeting, pillow stuffing, sleeping bag filling, insulation for water heaters and non-food containers. This is the first step of Goodyear's increased efforts to recycle PET from containers into a material suitable for food packing. The project is extremely complex, involving sophisticated understanding of the chemical reactions involved, PET production and the technology testing protocols necessary to design a process that addresses all the technical, safety, and regulatory concerns. The research conducted so far indicated that additional processing beyond simply cleaning the shredded material, called flake, will be required to assure a quality polymer.

  15. New approaches to recycling tires

    SciTech Connect

    Spencer, R.

    1991-03-01

    Steel-belted radial tires are potentially one of the most recyclable products created by modern industry, although the potential has been barely tapped. Discarded tires pile up at an astonishing rate each year - 234 million in the US and 26 million passenger tire equivalents in Canada. They represent a mother lode of raw material waiting for modern day miners to transform them into recycled rubber, steel, fiber and energy. The tremendous increase in use of steel belted radials since the early 1970s has complicated their recyclability compared to the bias ply tire, but it has also accomplished waste reduction by tripling tire service life. Part one of this report describes processes being developed to convert tires to crumb rubber, as well as some potential uses of recycled rubber. Part two, to appear next month, will examine such uses as rubberized athletic tracks and highway asphalt.

  16. Operating A Recycling Program: A Citizen's Guide.

    ERIC Educational Resources Information Center

    Mulligan, Kevin; Powell, Jerry

    Presented are recycling program alternatives, procedures for handling and marketing recyclable materials, and suggestions for financing and publicizing a recycling operation. This publication offers a general overview of the possibilities and potential pitfalls of recycling efforts, thereby serving as a catalyst and guide for organizations wishing…

  17. You're a "What"? Recycling Coordinator

    ERIC Educational Resources Information Center

    Torpey, Elka Maria

    2011-01-01

    Recycling coordinators supervise curbside and dropoff recycling programs for municipal governments or private firms. Today, recycling is mandatory in many communities. And advancements in collection and processing methods have helped to increase the quantity of materials for which the recycling coordinator is responsible. In some communities,…

  18. The Three Rs: Reduce, Reuse, Recycle.

    ERIC Educational Resources Information Center

    Science Activities, 1991

    1991-01-01

    A student hand-out for a recycling unit defines the terms reduce, recycle, and reuse as they relate to solid waste management. Presents the characteristics of recyclable items such as yard wastes, metals, glass, and paper. Lists organizations through which more information about recycling can be obtained. (MCO)

  19. Agglomerative percolation on the Bethe lattice and the triangular cactus

    NASA Astrophysics Data System (ADS)

    Chae, Huiseung; Yook, Soon-Hyung; Kim, Yup

    2013-08-01

    Agglomerative percolation (AP) on the Bethe lattice and the triangular cactus is studied to establish the exact mean-field theory for AP. Using the self-consistent simulation method based on the exact self-consistent equations, the order parameter P∞ and the average cluster size S are measured. From the measured P∞ and S, the critical exponents βk and γk for k = 2 and 3 are evaluated. Here, βk and γk are the critical exponents for P∞ and S when the growth of clusters spontaneously breaks the Zk symmetry of the k-partite graph. The obtained values are β2 = 1.79(3), γ2 = 0.88(1), β3 = 1.35(5) and γ3 = 0.94(2). By comparing these exponents with those for ordinary percolation (β∞ = 1 and γ∞ = 1), we also find β∞ < β3 < β2 and γ∞ > γ3 > γ2. These results quantitatively verify the conjecture that the AP model belongs to a new universality class if the Zk symmetry is broken spontaneously, and the new universality class depends on k.

  20. Neural networks, field theory, directed percolation, and critical branching

    NASA Astrophysics Data System (ADS)

    Buice, Michael A.

    We describe the dynamics of neural activity using field-theoretic methods for non-equilibrium statistical processes. Using a Markov assumption, we introduce the "spike model". The spike model permits a characterization of both neural fluctuations and response, presenting a tractable way to extend the mean field (Wilson-Cowan) equations used in much of theoretical and computational neuroscience. We also demonstrate the formalism's application to the Cowan models, one of which is equivalent to the forest fire model with immune trees. We argue that neural activity under mild conditions exhibits a dynamical phase transition which is in the universality class of directed percolation (DP). Owing to the spatial extent of neural interactions, there is a region in which the critical behavior is that of a branching process before crossing over into the DP region, consistent with measurements in cortical slice preparations. From the perspective of theoretical neuroscience, a principal contribution of this work is the connection of the problem of non-linear, non-Gaussian systems with the problem of dealing with infrared singularities in field theory. This work suggests a general characterization of epilepsy as a manifestation of a directed percolation phase transition.

  1. Rubber elasticity for percolation network consisting of Gaussian chains

    NASA Astrophysics Data System (ADS)

    Nishi, Kengo; Noguchi, Hiroshi; Sakai, Takamasa; Shibayama, Mitsuhiro

    2015-11-01

    A theory describing the elastic modulus for percolation networks of Gaussian chains on general lattices such as square and cubic lattices is proposed and its validity is examined with simulation and mechanical experiments on well-defined polymer networks. The theory was developed by generalizing the effective medium approximation (EMA) for Hookian spring network to Gaussian chain networks. From EMA theory, we found that the ratio of the elastic modulus at p, G to that at p = 1, G0, must be equal to G/G0 = (p - 2/f)/(1 - 2/f) if the position of sites can be determined so as to meet the force balance, where p is the degree of cross-linking reaction. However, the EMA prediction cannot be applicable near its percolation threshold because EMA is a mean field theory. Thus, we combine real-space renormalization and EMA and propose a theory called real-space renormalized EMA, i.e., REMA. The elastic modulus predicted by REMA is in excellent agreement with the results of simulations and experiments of near-ideal diamond lattice gels.

  2. Rubber Elasticity for percolation network consisting of Gaussian Chains

    NASA Astrophysics Data System (ADS)

    Nishi, Kengo; Shibayama, Mitsuhiro; Sakai, Takamasa

    A theory describing the elastic modulus for percolation networks of Gaussian chains on general lattices such as square and cubic lattices is proposed and its validity is examined with simulation and mechanical experiments on well-defined polymer networks. The theory was developed by generalizing the effective medium approximation for Hookian spring network (EMA) to Gaussian chain networks. From EMA theory, we found that the ratio of the elastic modulus at p, G to that at p = 1 ,G0, must be equal to G /G0 = (p - 2 / f) / (1 - 2 / f) if the position of sites can be determined so as to meet the force balance, where p is the degree of cross-linking reaction. However, the EMA prediction cannot be applicable near its percolation threshold because EMA is a mean field theory. Thus, we combine real-space renormalization and EMA, and propose a theory called real-space renormalized EMA, i.e., REMA. The elastic modulus predicted by REMA is in excellent agreement with the results of simulations and experiments of near-ideal diamond lattice gels.

  3. Quantum walk coherences on a dynamical percolation graph

    PubMed Central

    Elster, Fabian; Barkhofen, Sonja; Nitsche, Thomas; Novotný, Jaroslav; Gábris, Aurél; Jex, Igor; Silberhorn, Christine

    2015-01-01

    Coherent evolution governs the behaviour of all quantum systems, but in nature it is often subjected to influence of a classical environment. For analysing quantum transport phenomena quantum walks emerge as suitable model systems. In particular, quantum walks on percolation structures constitute an attractive platform for studying open system dynamics of random media. Here, we present an implementation of quantum walks differing from the previous experiments by achieving dynamical control of the underlying graph structure. We demonstrate the evolution of an optical time-multiplexed quantum walk over six double steps, revealing the intricate interplay between the internal and external degrees of freedom. The observation of clear non-Markovian signatures in the coin space testifies the high coherence of the implementation and the extraordinary degree of control of all system parameters. Our work is the proof-of-principle experiment of a quantum walk on a dynamical percolation graph, paving the way towards complex simulation of quantum transport in random media. PMID:26311434

  4. Rubber elasticity for percolation network consisting of Gaussian chains

    SciTech Connect

    Nishi, Kengo E-mail: sakai@tetrapod.t.u-tokyo.ac.jp Noguchi, Hiroshi; Shibayama, Mitsuhiro E-mail: sakai@tetrapod.t.u-tokyo.ac.jp; Sakai, Takamasa E-mail: sakai@tetrapod.t.u-tokyo.ac.jp

    2015-11-14

    A theory describing the elastic modulus for percolation networks of Gaussian chains on general lattices such as square and cubic lattices is proposed and its validity is examined with simulation and mechanical experiments on well-defined polymer networks. The theory was developed by generalizing the effective medium approximation (EMA) for Hookian spring network to Gaussian chain networks. From EMA theory, we found that the ratio of the elastic modulus at p, G to that at p = 1, G{sub 0}, must be equal to G/G{sub 0} = (p − 2/f)/(1 − 2/f) if the position of sites can be determined so as to meet the force balance, where p is the degree of cross-linking reaction. However, the EMA prediction cannot be applicable near its percolation threshold because EMA is a mean field theory. Thus, we combine real-space renormalization and EMA and propose a theory called real-space renormalized EMA, i.e., REMA. The elastic modulus predicted by REMA is in excellent agreement with the results of simulations and experiments of near-ideal diamond lattice gels.

  5. Accelerating Gas Adsorption on 3D Percolating Carbon Nanotubes

    NASA Astrophysics Data System (ADS)

    Li, Hui; Wen, Chenyu; Zhang, Youwei; Wu, Dongping; Zhang, Shi-Li; Qiu, Zhi-Jun

    2016-02-01

    In the field of electronic gas sensing, low-dimensional semiconductors such as single-walled carbon nanotubes (SWCNTs) can offer high detection sensitivity owing to their unprecedentedly large surface-to-volume ratio. The sensitivity and responsivity can further improve by increasing their areal density. Here, an accelerated gas adsorption is demonstrated by exploiting volumetric effects via dispersion of SWCNTs into a percolating three-dimensional (3D) network in a semiconducting polymer. The resultant semiconducting composite film is evaluated as a sensing membrane in field effect transistor (FET) sensors. In order to attain reproducible characteristics of the FET sensors, a pulsed-gate-bias measurement technique is adopted to eliminate current hysteresis and drift of sensing baseline. The rate of gas adsorption follows the Langmuir-type isotherm as a function of gas concentration and scales with film thickness. This rate is up to 5 times higher in the composite than only with an SWCNT network in the transistor channel, which in turn results in a 7-fold shorter time constant of adsorption with the composite. The description of gas adsorption developed in the present work is generic for all semiconductors and the demonstrated composite with 3D percolating SWCNTs dispersed in functional polymer represents a promising new type of material for advanced gas sensors.

  6. Experimental and computational investigation of percolation in complex polymer nanocomposites

    NASA Astrophysics Data System (ADS)

    Stevens, Derrick; Downen, Lori; Gorga, Russell; Clarke, Laura

    2009-03-01

    The continuing development of polymer nanocomposites has led to increasingly complex morphology, such as the mats of composite nanofibers formed from electrospinning. The formation of particle networks within the composite volume that leads to enhanced properties, such as electrical conductivity, may be influenced by this complex sample geometry. In this work, experimental and computational efforts are utilized to understand and predict the percolation threshold (critical volume fraction) for two cases: single ultra-high aspect ratio fibers (where fiber diameter can be similar to the particle dimensions) and these same fibers arranged in a random mat with up to 80% porosity. 2D and 3D Monte Carlo simulations, modeled on the actual parameters of our experimental system [1], are utilized and the results are compared with our experimental findings. In particular, confinement to fibers increases the percolation threshold; however the multi-fiber pathways available in mats partially reduce this constraint [2]. [1] S.S. Ojha, D.R. Stevens, K. Stano, T. Hoffman, L.I. Clarke, R.E. Gorga, Macromolecules 41, 2509 (2008). [2] D.R. Stevens, L.N. Downen, L.I. Clarke, Phys. Rev. B in press (2008).

  7. High volumetric capacitance near the insulator-metal percolation transition

    NASA Astrophysics Data System (ADS)

    Efros, A. L.

    2011-10-01

    I propose a new type of capacitor with a very high volumetric capacitance. It is based on the known phenomenon of the sharp increase of the dielectric constant of a metal-insulator composite in the vicinity of the percolation threshold on the insulator side. The optimization suggests that the sizes of the metallic particles should fall within the nanoscale. The distance between planar electrodes should be somewhat larger than the correlation length of the percolation theory and ≈10-20 times larger than the size of the particles while the area of the electrodes could be unlimited. The random electric field in the capacitor is calculated and is shown to be larger than the average field corresponding to the potential difference of the electrodes. This random field is potentially responsible for the dielectric breakdown. The estimated breakdown voltage of the capacitor shows that the stored energy density might be significantly larger than that of electrolytic capacitors while the volumetric capacitances might be comparable. The charging and discharging times should be significantly smaller than the corresponding times of batteries and even electrolytic capacitors.

  8. Accelerating Gas Adsorption on 3D Percolating Carbon Nanotubes

    PubMed Central

    Li, Hui; Wen, Chenyu; Zhang, Youwei; Wu, Dongping; Zhang, Shi-Li; Qiu, Zhi-Jun

    2016-01-01

    In the field of electronic gas sensing, low-dimensional semiconductors such as single-walled carbon nanotubes (SWCNTs) can offer high detection sensitivity owing to their unprecedentedly large surface-to-volume ratio. The sensitivity and responsivity can further improve by increasing their areal density. Here, an accelerated gas adsorption is demonstrated by exploiting volumetric effects via dispersion of SWCNTs into a percolating three-dimensional (3D) network in a semiconducting polymer. The resultant semiconducting composite film is evaluated as a sensing membrane in field effect transistor (FET) sensors. In order to attain reproducible characteristics of the FET sensors, a pulsed-gate-bias measurement technique is adopted to eliminate current hysteresis and drift of sensing baseline. The rate of gas adsorption follows the Langmuir-type isotherm as a function of gas concentration and scales with film thickness. This rate is up to 5 times higher in the composite than only with an SWCNT network in the transistor channel, which in turn results in a 7-fold shorter time constant of adsorption with the composite. The description of gas adsorption developed in the present work is generic for all semiconductors and the demonstrated composite with 3D percolating SWCNTs dispersed in functional polymer represents a promising new type of material for advanced gas sensors. PMID:26888337

  9. Ultralow percolation threshold in aerogel and cryogel templated composites.

    PubMed

    Irin, Fahmida; Das, Sriya; Atore, Francis O; Green, Micah J

    2013-09-10

    We demonstrate a novel concept for preparing percolating composites with ultralow filler content by utilizing nanofiller-loaded aerogel and cryogels as a conductive template. This concept is investigated for several porous systems, including resorcinol-formaldehyde (RF), silica, and polyacrylamide (PAM) gels, and both graphene and carbon nanotubes are utilized as nanofiller. In each case, a stable, aqueous nanofiller dispersion is mixed with a sol-gel precursor and polymerized to form a hydrogel, which can then be converted to an aerogel by critical point drying or cryogel by freeze-drying. Epoxy resin is infused into the pores of the gels by capillary action without disrupting the monolithic structure. We show that conductive graphene/epoxy composites are formed with a very low graphene loading; a percolation threshold as low as 0.012 vol % is obtained for graphene-RF cryogel/epoxy composite. This is the lowest reported threshold of any graphene-based nanocomposites. Similar values are achieved in other aerogel and nanofiller systems, which demonstrates the versatility of this method. PMID:23927050

  10. Percolation transition in dynamical traffic network with evolving critical bottlenecks

    PubMed Central

    Li, Daqing; Fu, Bowen; Wang, Yunpeng; Lu, Guangquan; Berezin, Yehiel; Stanley, H. Eugene; Havlin, Shlomo

    2015-01-01

    A critical phenomenon is an intrinsic feature of traffic dynamics, during which transition between isolated local flows and global flows occurs. However, very little attention has been given to the question of how the local flows in the roads are organized collectively into a global city flow. Here we characterize this organization process of traffic as “traffic percolation,” where the giant cluster of local flows disintegrates when the second largest cluster reaches its maximum. We find in real-time data of city road traffic that global traffic is dynamically composed of clusters of local flows, which are connected by bottleneck links. This organization evolves during a day with different bottleneck links appearing in different hours, but similar in the same hours in different days. A small improvement of critical bottleneck roads is found to benefit significantly the global traffic, providing a method to improve city traffic with low cost. Our results may provide insights on the relation between traffic dynamics and percolation, which can be useful for efficient transportation, epidemic control, and emergency evacuation. PMID:25552558

  11. Ultrasensitive photodetectors exploiting electrostatic trapping and percolation transport

    PubMed Central

    Zhang, Yingjie; Hellebusch, Daniel J.; Bronstein, Noah D.; Ko, Changhyun; Ogletree, D. Frank; Salmeron, Miquel; Alivisatos, A. Paul

    2016-01-01

    The sensitivity of semiconductor photodetectors is limited by photocarrier recombination during the carrier transport process. We developed a new photoactive material that reduces recombination by physically separating hole and electron charge carriers. This material has a specific detectivity (the ability to detect small signals) of 5 × 1017 Jones, the highest reported in visible and infrared detectors at room temperature, and 4–5 orders of magnitude higher than that of commercial single-crystal silicon detectors. The material was fabricated by sintering chloride-capped CdTe nanocrystals into polycrystalline films, where Cl selectively segregates into grain boundaries acting as n-type dopants. Photogenerated electrons concentrate in and percolate along the grain boundaries—a network of energy valleys, while holes are confined in the grain interiors. This electrostatic field-assisted carrier separation and percolation mechanism enables an unprecedented photoconductive gain of 1010 e− per photon, and allows for effective control of the device response speed by active carrier quenching. PMID:27323904

  12. Percolation theory and fragmentation measures in social networks

    NASA Astrophysics Data System (ADS)

    Chen, Yiping; Paul, Gerald; Cohen, Reuven; Havlin, Shlomo; Borgatti, Stephen P.; Liljeros, Fredrik; Eugene Stanley, H.

    2007-05-01

    We study the statistical properties of a recently proposed social networks measure of fragmentation F after removal of a fraction q of nodes or links from the network. The measure F is defined as the ratio of the number of pairs of nodes that are not connected in the fragmented network to the total number of pairs in the original fully connected network. We compare this measure with the one traditionally used in percolation theory, P∞, the fraction of nodes in the largest cluster relative to the total number of nodes. Using both analytical and numerical methods, we study Erdős-Rényi (ER) and scale-free (SF) networks under various node removal strategies. We find that for a network obtained after removal of a fraction q of nodes above criticality, P∞≈(1-F). For fixed P∞ and close to criticality, we show that 1-F better reflects the actual fragmentation. For a given P∞, 1-F has a broad distribution and thus one can improve significantly the fragmentation of the network. We also study and compare the fragmentation measure F and the percolation measure P∞ for a real national social network of workplaces linked by the households of the employees and find similar results.

  13. Electron percolation in realistic models of carbon nanotube networks

    NASA Astrophysics Data System (ADS)

    Simoneau, Louis-Philippe; Villeneuve, Jérémie; Rochefort, Alain

    2015-09-01

    The influence of penetrable and curved carbon nanotubes (CNT) on the charge percolation in three-dimensional disordered CNT networks have been studied with Monte-Carlo simulations. By considering carbon nanotubes as solid objects but where the overlap between their electron cloud can be controlled, we observed that the structural characteristics of networks containing lower aspect ratio CNT are highly sensitive to the degree of penetration between crossed nanotubes. Following our efficient strategy to displace CNT to different positions to create more realistic statistical models, we conclude that the connectivity between objects increases with the hard-core/soft-shell radii ratio. In contrast, the presence of curved CNT in the random networks leads to an increasing percolation threshold and to a decreasing electrical conductivity at saturation. The waviness of CNT decreases the effective distance between the nanotube extremities, hence reducing their connectivity and degrading their electrical properties. We present the results of our simulation in terms of thickness of the CNT network from which simple structural parameters such as the volume fraction or the carbon nanotube density can be accurately evaluated with our more realistic models.

  14. Rubber elasticity for percolation network consisting of Gaussian chains.

    PubMed

    Nishi, Kengo; Noguchi, Hiroshi; Sakai, Takamasa; Shibayama, Mitsuhiro

    2015-11-14

    A theory describing the elastic modulus for percolation networks of Gaussian chains on general lattices such as square and cubic lattices is proposed and its validity is examined with simulation and mechanical experiments on well-defined polymer networks. The theory was developed by generalizing the effective medium approximation (EMA) for Hookian spring network to Gaussian chain networks. From EMA theory, we found that the ratio of the elastic modulus at p, G to that at p = 1, G0, must be equal to G/G0 = (p - 2/f)/(1 - 2/f) if the position of sites can be determined so as to meet the force balance, where p is the degree of cross-linking reaction. However, the EMA prediction cannot be applicable near its percolation threshold because EMA is a mean field theory. Thus, we combine real-space renormalization and EMA and propose a theory called real-space renormalized EMA, i.e., REMA. The elastic modulus predicted by REMA is in excellent agreement with the results of simulations and experiments of near-ideal diamond lattice gels. PMID:26567682

  15. Percolation Thresholds in Angular Grain media: Drude Directed Infiltration

    NASA Astrophysics Data System (ADS)

    Priour, Donald

    Pores in many realistic systems are not well delineated channels, but are void spaces among grains impermeable to charge or fluid flow which comprise the medium. Sparse grain concentrations lead to permeable systems, while concentrations in excess of a critical density block bulk fluid flow. We calculate percolation thresholds in porous materials made up of randomly placed (and oriented) disks, tetrahedrons, and cubes. To determine if randomly generated finite system samples are permeable, we deploy virtual tracer particles which are scattered (e.g. specularly) by collisions with impenetrable angular grains. We hasten the rate of exploration (which would otherwise scale as ncoll1 / 2 where ncoll is the number of collisions with grains if the tracers followed linear trajectories) by considering the tracer particles to be charged in conjunction with a randomly directed uniform electric field. As in the Drude treatment, where a succession of many scattering events leads to a constant drift velocity, tracer displacements on average grow linearly in ncoll. By averaging over many disorder realizations for a variety of systems sizes, we calculate the percolation threshold and critical exponent which characterize the phase transition.

  16. Low-field Hall effect near the percolation threshold

    NASA Astrophysics Data System (ADS)

    Marianer, S.; Bergman, D. J.

    1989-06-01

    We use a random-resistor-network model to study the critical behavior of the low-field Hall constant in a three-dimensional (3D) metal-insulator composite near the percolation threshold. The transfer-matrix method, which was originally introduced for calculating conductivity, is generalized to be applicable to the calculation of the Hall constant and the magnetoresistance as well. We then use this generalized method to perform a renormalization-group calculation for a cubic random resistor network and two simulations of random resistor networks at the percolation threshold: one of cubes and the other of long (3D) strips. Fitting an expression RH~(p-pc)-g to the effective Hall constant RH of the network, we find a divergent Hall constant both from the renormalization-group calculation (g=0.625) and from the simulation of cubes (g=0.25), while the long-strips simulation yields one that is concentration independent, i.e., g=0.

  17. Percolation transition in dynamical traffic network with evolving critical bottlenecks

    NASA Astrophysics Data System (ADS)

    Li, Daqing

    A critical phenomenon is an intrinsic feature of traffic dynamics, during which transition between isolated local flows and global flows occurs. However, very little attention has been given to the question of how the local flows in the roads are organized collectively into a global city flow. Here we characterize this organization process of traffic as ``traffic percolation,'' where the giant cluster of local flows disintegrates when the second largest cluster reaches its maximum. We find in real-time data of city road traffic that global traffic is dynamically composed of clusters of local flows, which are connected by bottleneck links. This organization evolves during a day with different bottleneck links appearing in different hours, but similar in the same hours in different days. A small improvement of critical bottleneck roads is found to benefit significantly the global traffic, providing a method to improve city traffic with low cost. Our results may provide insights on the relation between traffic dynamics and percolation, which can be useful for efficient transportation, epidemic control, and emergency evacuation.

  18. Percolation behavior of tritiated water into a soil packed bed

    SciTech Connect

    Honda, T.; Katayama, K.; Uehara, K.; Fukada, S.; Takeishi, T.

    2015-03-15

    A large amount of cooling water is used in a D-T fusion reactor. The cooling water will contain tritium with high concentration because tritium can permeate metal walls at high temperature easily. A development of tritium handling technology for confining tritiated water in the fusion facility is an important issue. In addition, it is also important to understand tritium behavior in environment assuming severe accidents. In this study, percolation experiments of tritiated water in soil packed bed were carried out and tritium behavior in soil was discussed. Six soil samples were collected in Hakozaki campus of Kyushu University. These particle densities were of the same degree as that of general soils and moisture contents were related to BET surface area. For two soil samples used in the percolation experiment of tritiated water, saturated hydraulic conductivity agreed well with the estimating value by Creager. Tritium retention ratio in the soil packed bed was larger than water retention. This is considered to be due to an effect of tritium sorption on the surface of soil particles. The isotope exchange capacity estimated by assuming that H/T ratio of supplied tritiated water and H/T ratio of surface water of soil particle was equal was comparable to that on cement paste and mortar which were obtained by exposure of tritiated water vapor. (authors)

  19. Ultrasensitive photodetectors exploiting electrostatic trapping and percolation transport.

    PubMed

    Zhang, Yingjie; Hellebusch, Daniel J; Bronstein, Noah D; Ko, Changhyun; Ogletree, D Frank; Salmeron, Miquel; Alivisatos, A Paul

    2016-01-01

    The sensitivity of semiconductor photodetectors is limited by photocarrier recombination during the carrier transport process. We developed a new photoactive material that reduces recombination by physically separating hole and electron charge carriers. This material has a specific detectivity (the ability to detect small signals) of 5 × 10(17) Jones, the highest reported in visible and infrared detectors at room temperature, and 4-5 orders of magnitude higher than that of commercial single-crystal silicon detectors. The material was fabricated by sintering chloride-capped CdTe nanocrystals into polycrystalline films, where Cl selectively segregates into grain boundaries acting as n-type dopants. Photogenerated electrons concentrate in and percolate along the grain boundaries-a network of energy valleys, while holes are confined in the grain interiors. This electrostatic field-assisted carrier separation and percolation mechanism enables an unprecedented photoconductive gain of 10(10) e(-) per photon, and allows for effective control of the device response speed by active carrier quenching. PMID:27323904

  20. Electron percolation in realistic models of carbon nanotube networks

    SciTech Connect

    Simoneau, Louis-Philippe Villeneuve, Jérémie Rochefort, Alain

    2015-09-28

    The influence of penetrable and curved carbon nanotubes (CNT) on the charge percolation in three-dimensional disordered CNT networks have been studied with Monte-Carlo simulations. By considering carbon nanotubes as solid objects but where the overlap between their electron cloud can be controlled, we observed that the structural characteristics of networks containing lower aspect ratio CNT are highly sensitive to the degree of penetration between crossed nanotubes. Following our efficient strategy to displace CNT to different positions to create more realistic statistical models, we conclude that the connectivity between objects increases with the hard-core/soft-shell radii ratio. In contrast, the presence of curved CNT in the random networks leads to an increasing percolation threshold and to a decreasing electrical conductivity at saturation. The waviness of CNT decreases the effective distance between the nanotube extremities, hence reducing their connectivity and degrading their electrical properties. We present the results of our simulation in terms of thickness of the CNT network from which simple structural parameters such as the volume fraction or the carbon nanotube density can be accurately evaluated with our more realistic models.

  1. Accelerating Gas Adsorption on 3D Percolating Carbon Nanotubes.

    PubMed

    Li, Hui; Wen, Chenyu; Zhang, Youwei; Wu, Dongping; Zhang, Shi-Li; Qiu, Zhi-Jun

    2016-01-01

    In the field of electronic gas sensing, low-dimensional semiconductors such as single-walled carbon nanotubes (SWCNTs) can offer high detection sensitivity owing to their unprecedentedly large surface-to-volume ratio. The sensitivity and responsivity can further improve by increasing their areal density. Here, an accelerated gas adsorption is demonstrated by exploiting volumetric effects via dispersion of SWCNTs into a percolating three-dimensional (3D) network in a semiconducting polymer. The resultant semiconducting composite film is evaluated as a sensing membrane in field effect transistor (FET) sensors. In order to attain reproducible characteristics of the FET sensors, a pulsed-gate-bias measurement technique is adopted to eliminate current hysteresis and drift of sensing baseline. The rate of gas adsorption follows the Langmuir-type isotherm as a function of gas concentration and scales with film thickness. This rate is up to 5 times higher in the composite than only with an SWCNT network in the transistor channel, which in turn results in a 7-fold shorter time constant of adsorption with the composite. The description of gas adsorption developed in the present work is generic for all semiconductors and the demonstrated composite with 3D percolating SWCNTs dispersed in functional polymer represents a promising new type of material for advanced gas sensors. PMID:26888337

  2. Short-range correlations in percolation at criticality

    NASA Astrophysics Data System (ADS)

    Hu, Hao; Blöte, Henk W. J.; Ziff, Robert M.; Deng, Youjin

    2014-10-01

    We derive the critical nearest-neighbor connectivity gn as 3/4, 3(7-9pctri)/4(5-4pctri), and 3(2+7pctri)/4(5-pctri) for bond percolation on the square, honeycomb, and triangular lattice, respectively, where pctri=2sin(π/18) is the percolation threshold for the triangular lattice, and confirm these values via Monte Carlo simulations. On the square lattice, we also numerically determine the critical next-nearest-neighbor connectivity as gnn=0.6875000(2), which confirms a conjecture by Mitra and Nienhuis [J. Stat. Mech. (2004) P10006, 10.1088/1742-5468/2004/10/P10006], implying the exact value gnn=11/16. We also determine the connectivity on a free surface as gnsurf=0.6250001(13) and conjecture that this value is exactly equal to 5/8. In addition, we find that at criticality, the connectivities depend on the linear finite size L as ˜Lyt-d, and the associated specific-heat-like quantities Cn and Cnn scale as ˜L2yt-dln(L /L0), where d is the lattice dimensionality, yt=1/ν the thermal renormalization exponent, and L0 a nonuniversal constant. We provide an explanation of this logarithmic factor within the theoretical framework reported recently by Vasseur et al. [J. Stat. Mech. (2012) L07001, 10.1088/1742-5468/2012/07/L07001].

  3. Corporate America urges consumers to buy recycled

    SciTech Connect

    Rabasca, L.

    1995-04-01

    The National Recycling Coalition`s (NRC, Washington, DC) buy Recycled Business Alliance (BRBA), the US EPA`s WasteWi$e program, and the US Conference of Mayors` (Washington, DC) buy-recycled program are just a few of the national groups that have formed since 1990 to encourage the purchase of products made from recyclables. Indeed, corporate America and governments are buying recycled. More than $1 billion worth of recycled-content products have been bought by McDonald`s Corp. since 1990. The nearly 950 members of the BRBA reported spending $9.1 billion on recycled-content products in 1993. State governments reported in 1993 that they had spent more than $600 million on recycled products. Several states, cities, and counties have adopted buy-recycled executive orders. Now, many of these companies and government officials are urging consumers to use their own purchasing power to spur markets for recyclables.

  4. Ammonia measurement with a pH electrode in the ammonia/urea-SCR process

    NASA Astrophysics Data System (ADS)

    Kröcher, Oliver; Elsener, Martin

    2007-03-01

    The selective catalytic reduction of nitrogen oxides with ammonia (ammonia SCR) and urea (urea SCR), respectively, is a widespread process to clean flue and diesel exhaust gases due to its simplicity and efficiency. The main challenge of the process is to minimize the ammonia emissions downstream of the SCR catalyst. We found that ammonia emissions of >10 ppm can reliably be detected with a simple pH electrode in the presence of CO2, SOx, NOx, and moderately weak organic acids. 10-20 ppm of ammonia in the exhaust gas are sufficient to neutralize the acids and to increase the pH value from 3 to 6. On this basis a continuous measuring method for ammonia was developed, which was used to control the dosage of urea in the SCR process. While keeping the ammonia emissions after the SCR catalyst at 5-30 ppm an average NOx removal efficiency (DeNOx) of >95% were achieved at a diesel test rig. The method can also be applied for exhaust gases with higher acid contents, if a basic pre-filter is added adsorbing the acidic exhaust components. Compared to water as absorption solution, more precise ammonia measurements are possible, if a 0.1 M NH4Cl absorption solution is applied, whose pH value is changing as a Nernst function of the ammonia concentration.

  5. INVESTIGATION OF THE ORION RESEARCH AMMONIA MONITOR

    EPA Science Inventory

    The Orion Research ammonia monitor was investigated using the Orion specifications and environmental considerations as a guide. Laboratory tests under controlled environmental conditions showed the electronic stability (drift) to be well within + or - 10 percent of reading over t...

  6. DEVELOPMENT AND SELECTION OF AMMONIA EMISSION FACTORS

    EPA Science Inventory

    This report compiles recent literature on ammonia (NH') emission factors for application in the United States. ost of the recent research supports acid deposition studies in the European community (specifically, the Netherlands, Great Britain, and Scandinavia) but some research h...

  7. Assimilation of ammonia in Paracoccus denitrificans.

    PubMed

    Mikes, V; Chválová, H; Mátlová, L

    1991-01-01

    Two pathways serve for assimilation of ammonia in Paracoccus denitrificans. Glutamate dehydrogenase (NADP+) catalyzes the assimilation at a high NH4+ concentration. If nitrate serves as the nitrogen source, glutamate is synthesized by glutamate-ammonia ligase and glutamate synthase (NADPH). At a very low NH4+ concentration, all three enzymes are synthesized simultaneously. No direct relationship exists between glutamate dehydrogenase (NADP+) and glutamate-ammonia ligase in P. denitrificans, while the glutamate synthase (NADPH) activity changes in parallel with that of the latter enzyme. Ammonia does not influence the induction or repression of glutamate dehydrogenase (NADP+). The inner concentration of metabolites indicates a possible repression of glutamate dehydrogenase (NADP+) by the high concentration of glutamine or its metabolic products as in the case when NH4+ is formed by assimilative nitrate reduction. No direct effect of the intermediates of nitrate assimilation on the synthesis of glutamate dehydrogenase (NADP+) was observed. PMID:1688163

  8. Ultrafast Dynamics of Electrons in Ammonia

    NASA Astrophysics Data System (ADS)

    Vöhringer, Peter

    2015-04-01

    Solvated electrons were first discovered in solutions of metals in liquid ammonia. The physical and chemical properties of these species have been studied extensively for many decades using an arsenal of electrochemical, spectroscopic, and theoretical techniques. Yet, in contrast to their hydrated counterpart, the ultrafast dynamics of ammoniated electrons remained completely unexplored until quite recently. Femtosecond pump-probe spectroscopy on metal-ammonia solutions and femtosecond multiphoton ionization spectroscopy on the neat ammonia solvent have provided new insights into the optical properties and the reactivities of this fascinating species. This article reviews the nature of the optical transition, which gives the metal-ammonia solutions their characteristic blue appearance, in terms of ultrafast relaxation processes involving bound and continuum excited states. The recombination processes following the injection of an electron via photoionization of the solvent are discussed in the context of the electronic structure of the liquid and the anionic defect associated with the solvated electron.

  9. Ammonia Affects Astroglial Proliferation in Culture

    PubMed Central

    Bodega, Guillermo; Segura, Berta; Ciordia, Sergio; Mena, María del Carmen; López-Fernández, Luis Andrés; García, María Isabel; Trabado, Isabel; Suárez, Isabel

    2015-01-01

    Primary cultures of rat astroglial cells were exposed to 1, 3 and 5 mM NH4Cl for up to 10 days. Dose- and time-dependent reductions in cell numbers were seen, plus an increase in the proportion of cells in the S phase. The DNA content was reduced in the treated cells, and BrdU incorporation diminished. However, neither ammonia nor ammonia plus glutamine had any effect on DNA polymerase activity. iTRAQ analysis showed that exposure to ammonia induced a significant reduction in histone and heterochromatin protein 1 expression. A reduction in cell viability was also noted. The ammonia-induced reduction of proliferative activity in these cultured astroglial cells seems to be due to a delay in the completion of the S phase provoked by the inhibition of chromatin protein synthesis. PMID:26421615

  10. Ultrafast dynamics of electrons in ammonia.

    PubMed

    Vöhringer, Peter

    2015-04-01

    Solvated electrons were first discovered in solutions of metals in liquid ammonia. The physical and chemical properties of these species have been studied extensively for many decades using an arsenal of electrochemical, spectroscopic, and theoretical techniques. Yet, in contrast to their hydrated counterpart, the ultrafast dynamics of ammoniated electrons remained completely unexplored until quite recently. Femtosecond pump-probe spectroscopy on metal-ammonia solutions and femtosecond multiphoton ionization spectroscopy on the neat ammonia solvent have provided new insights into the optical properties and the reactivities of this fascinating species. This article reviews the nature of the optical transition, which gives the metal-ammonia solutions their characteristic blue appearance, in terms of ultrafast relaxation processes involving bound and continuum excited states. The recombination processes following the injection of an electron via photoionization of the solvent are discussed in the context of the electronic structure of the liquid and the anionic defect associated with the solvated electron. PMID:25493716

  11. Deep Recycling of Carbon

    NASA Astrophysics Data System (ADS)

    Schmidt, M. W.

    2012-12-01

    While most of the subducted H2O is recycled at shallow and subarc depths, carbon is less readily mobilized and susceptive to complex redox processes involving CO2 in solids, fluids and melts, elemental carbon, Fe- and Si- carbides, and methane. Here I review the various ways of recycling carbon during subduction and present a spectrum of possible reaction products in the mantle. Metamorphic reactions liberate <20% of the subducted CO2 to the subarc region (Connolly 2005, EPSL). Larger amounts might be mobilized through (sediment) melting. Although the wet pelite solidus is only shifted by 30-50 oC (at 3 GPa) with carbonates, the latter remain stable with melts that are saturated in a H2O+CO2-fluid. Complete dissolution of carbonates requires temperatures above any predicted subduction geotherm. Carbonated sediments yield CO2-rich phonolites to 5 GPa but carbonatites at higher pressures. The silicate melts become increasingly potassic with pressure, while the alkali-rich carbonatites have their highest K/Na at 8 GPa, slightly decreasing to 13 GPa and become sodic with the disappearance of residual cpx at ~16 GPa. What may happen when carbonated pelite derived melts migrate into the mantle is illustrated in Central Italy: in this case, it can be experimentally demonstrated that hybridization of ultrapotassic phonolitic melts with ~2 wt% H2O and ~6 wt% CO2 in the mantle results in the primitive parents of the ultrapotassic kamafugite suites which have ~43 wt% SiO2. Hence, despite a crustal isotopic signature of C, O, and Sr in these rocks, the CO2 of the Italian magmatism does not stem from assimilation in the crust but from melts derived from subducted marine carbonates mixed with pelagic clays and then reacted in the mantle. The migration of CO2-bearing fluids and melts into the mantle may lead to a redox-shock. Where high liquid/mantle ratios prevail, carbonatites rest in their oxidized form and may only freeze in relatively cold lithospheric keels where they form

  12. Rethinking Recycling in Arcs

    NASA Astrophysics Data System (ADS)

    Kelemen, P.; Behn, M. D.; Jagoutz, O.

    2012-12-01

    Hacker et al EPSL 2011 and Behn et al Nature Geosci 2011 investigated pathways for return of buoyant, subducted material to arc crust. These include (1) diapirs rising into the hot mantle wedge, with extensive melts adding a component to arc magmas, (2) flow of material back up a relatively cold "subduction channel", adding solids to the lower crust and small-degree partial melts to the upper crust, (3) flow from the forearc along the base of arc crust, and (4) imbrication of forearc material into arc crust. These processes add felsic, incompatible-element-rich components to arc crust. The flux of incompatible elements such as Th in arc lavas, thought to be mainly recycled from subducted sediments, is > sediment subduction flux. There are large uncertainties: arc crustal growth rates are imprecise; young, primitive arc lavas may not be representative of magmatic flux into arc crust; sediment subduction flux may have varied. Nevertheless, this result is found for all arcs examined, using recently published growth rates. Perhaps arc growth rates that include subduction erosion are systematically overestimated. Instead or in addition, maybe significant Th comes from material other than sediments. Here, we consider the implications of pathways 1-4 for arc growth rates and incompatible element enrichment, in the context of subduction erosion and arc-arc collision. Subducting arc lithologies can become separated, with only felsic components returned to arc crust. Buoyant lithologies are mobile in viscous instabilities at > 700-800°C. Whereas thin layers such as sediments may become mobile all at once, instabilities may periodically strip the hottest parts from the top of thick buoyant layers, replacing them with hot mantle. In arc-arc collision, the top of a subducting plate starts at about 0°C on the seafloor, so heating is slow. In subduction erosion, forearc material in the subducting package can be > 200°C before erosion so buoyant lithologies reach 700-800

  13. Combustion Byproducts Recycling Consortium

    SciTech Connect

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F

  14. Predicting Saturated Hydraulic Conductivity from Percolation Test Results in Layered Silt Loam Soils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The size of on-site waste disposal systems is usually determined by one or more percolation tests performed on the proposed site. The objectives of this study were to develop an empirical relationship between the saturated hydraulic conductivity (Ks) of layered soils and their percolation times (PT)...

  15. Carbon materials with quasi-graphene layers: The dielectric, percolation properties and the electronic transport mechanism

    NASA Astrophysics Data System (ADS)

    Lu, Ming-Ming; Yuan, Jie; Wen, Bo; Liu, Jia; Cao, Wen-Qiang; Cao, Mao-Sheng

    2013-03-01

    We investigate the dielectric properties of multi-walled carbon nanotubes (MWCNTs) and graphite filling in SiO2 with the filling concentration of 2-20 wt.% in the frequency range of 102-107 Hz. MWCNTs and graphite have general electrical properties and percolation phenomena owing to their quasi-structure made up of graphene layers. Both permittivity ɛ and conductivity σ exhibit jumps around the percolation threshold. Variations of dielectric properties of the composites are in agreement with the percolation theory. All the percolation phenomena are determined by hopping and migrating electrons, which are attributed to the special electronic transport mechanism of the fillers in the composites. However, the twin-percolation phenomenon exists when the concentration of MWCNTs is between 5-10 wt.% and 15-20 wt.% in the MWCNTs/SiO2 composites, while in the graphite/SiO2 composites, there is only one percolation phenomenon in the graphite concentration of 10-15 wt.%. The unique twin-percolation phenomenon of MWCNTs/SiO2 is described and attributed to the electronic transfer mechanism, especially the network effect of MWCNTs in the composites. The network formation plays an essential role in determining the second percolation threshold of MWCNTs/SiO2.

  16. Crossover phenomena of percolation transition in evolution networks with hybrid attachment.

    PubMed

    Chen, Xiaolong; Yang, Chun; Zhong, Linfeng; Tang, Ming

    2016-08-01

    A first-order percolation transition, called explosive percolation, was recently discovered in evolution networks with random edge selection under a certain restriction. For many real world networks, the mechanism of preferential attachment plays a significant role in the formation of heterogeneous structures, but the network percolation in evolution process with preferential attachment has not yet been concerned. We propose a tunable network percolation model by introducing a hybrid mechanism of edge selection into the Bohman-Frieze-Wormald model, in which a parameter adjusts the relative weights between random and preferential selections. A large number of simulations indicate that there exist crossover phenomena of percolation transition by adjusting the parameter in the evolution processes. When the strategy of selecting a candidate edge is dominated by random selection, a single discontinuous percolation transition occurs. When a candidate edge is selected more preferentially based on nodes degree, the size of the largest component undergoes multiple discontinuous jumps, which exhibits a peculiar difference from the network percolation of random selection with a certain restriction. Besides, the percolation transition becomes continuous when the candidate edge is selected completely preferentially. PMID:27586610

  17. Recycling of base metals from metal wastes of brass foundries

    SciTech Connect

    Nesbitt, C.C.; Xue, S.

    1995-07-01

    A process has been developed to recover and recycle metals from wastes of brass foundries which contain copper, zinc and lead in various quantities. Tests were conducted to evaluate several leachants, including sulfuric acid, ammonia, hydrochloric acid, cyanide and acetic acid, and to determine the optimum leaching conditions, such as air flow rate, initial copper ion concentration, temperature, and agitation strength. Sulfuric acid containing copper sulfate with dissolved oxygen is the most successful leachant. More than 99% of the copper and zinc originally present in the waste was dissolved, while only 0.5% of the lead entered the solution after 14 hours of leaching. The leaching mechanisms of copper, zinc, and lead are proposed. The copper and zinc can be recovered from the solution by electrolytic processing. The unleached residue may be converted to a lead carbonate which can be converted to litharge at 400--450 C and to massicot at temperature above 500 C by calcination.

  18. Variation of the critical percolation threshold with the method of preparation of the system

    NASA Astrophysics Data System (ADS)

    Giazitzidis, Paraskevas; Avramov, Isak; Argyrakis, Panos

    2015-12-01

    In the present work we propose a model in which one may vary at will the critical threshold p c of the percolation transition, by probing one candidate site (or bond) at a time. This is realised by implementing an attractive (repulsive) rule when building up the lattice, so that newly added sites are either attracted or repelled by the already existing clusters. We use a tuning parameter k, which is the number of attempts for a site to be occupied, leading to a continuous change of the percolation threshold while the new percolation process still belongs to the same universality class as the ordinary random percolation. We find that by increasing the value of the tuning parameter k, p c decreases until it reaches a minimum value where nucleation effects are now more pronounced than the percolation process. Such results are useful for the explanation of several new experimental systems that have recently appeared.

  19. Estimation of percolation flux from borehole temperature data at Yucca Mountain, Nevada.

    PubMed

    Bodvarsson, G S; Kwicklis, E; Shan, C; Wu, Y S

    2003-01-01

    Temperature data from the unsaturated zone (UZ) at Yucca Mountain are analyzed to estimate percolation-flux rates and overall heat flux. A multilayer, one-dimensional analytical solution is presented for determining percolation flux from temperature data. Case studies have shown that the analytical solution agrees very well with results from the numerical code, TOUGH2. The results of the analysis yield percolation fluxes in the range from 0 to 20 mm/year for most of the deep boreholes. This range is in good agreement with the results of infiltration studies at Yucca Mountain. Percolation flux for the shallower boreholes, however, cannot be accurately determined from temperature data alone because large gas flow in the shallow system alters the temperature profiles. Percolation-flux estimates for boreholes located near or intersecting major faults are significantly higher than those for other boreholes. These estimates may be affected by gas flow in the faults. PMID:12714282

  20. Ammonia chemistry in a flameless jet

    SciTech Connect

    Zieba, Mariusz; Schuster, Anja; Scheffknecht, Guenter; Brink, Anders; Hupa, Mikko

    2009-10-15

    In this paper, the nitrogen chemistry in an ammonia (NH{sub 3}) doped flameless jet is investigated using a kinetic reactor network model. The reactor network model is used to explain the main differences in ammonia chemistry for methane (CH{sub 4})-containing fuels and methane-free fuels. The chemical pathways of nitrogen oxides (NO{sub x}) formation and destruction are identified using rate-of-production analysis. The results show that in the case of natural gas, ammonia reacts relatively late at fuel lean condition leading to high NO{sub x} emissions. In the pre-ignition zone, the ammonia chemistry is blocked due to the absence of free radicals which are consumed by methane-methyl radical (CH{sub 3}) conversion. In the case of methane-free gas, the ammonia reacted very rapidly and complete decomposition was reached in the fuel rich region of the jet. In this case the necessary radicals for the ammonia conversion are generated from hydrogen (H{sub 2}) oxidation. (author)