Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

DOE PAGES

Martinez, Jorge L.; Lin, Hsiu-Jung; Lee, Wei-Tsung; ...

2017-09-21

The new iron(IV) nitride complex PhB( iPr 2Im) 3Fe≡N reacts with two equivalents of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB( iPr 2Im) 3Fe(CN)(N 2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne iPr 2N-C≡C-N iPr 2. The iron complex is in equilibrium with an N 2- free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C 6F 5) 3 provides the cyanoborane derivative.

Mean-Square Amplitudes of Vibration and Anisotropic Motion of Metal Atoms in Iron Organometallics

NASA Astrophysics Data System (ADS)

Herber, Rolfe H.; Nowik, Israel

2002-12-01

Mössbauer recoil-free fraction (f) data for ferrocene [(η5-(C5H5)2Fe] over the temperature range 90≤T≤370 K have been used to calculate the mean-square-amplitude-of-vibration (msav) of the iron atom, and these data have been compared to the thermal factors (U ij ) extracted from X-ray diffraction data reported in the literature. The agreement between these two independent data sets is taken as a validation of the interpretation of the Mössbauer data in terms of the mean-square-amplitude-of-vibration of the metal atom in iron organometallic solids. The contribution of three low-frequency IR active modes of ferrocene (ω11, ω21, and ω22) to the f(T) parameter is discussed in detail.

Iron state in iron nanoparticles with and without zirconium

NASA Astrophysics Data System (ADS)

Filippov, V. P.; Khasanov, A. M.; Lauer, Yu. A.

2017-11-01

Mössbauer and X-ray methods are used for investigations of structure, stability and characteristics of pure-iron grain and two iron-zirconium alloys such as Fe + 5 wt.% Zr and Fe + 10 wt.% Zr. The used powder was ground for 24 h in a SPEX Model 8000 mill shaker. Complex nanoparticles are found, which change their properties under milling. Mössbauer spectral parameters are obtained for investigated materials. Milling results in formation of nanosized particles with two states of iron atoms: one main part is pure α-Fe and another part of iron atoms displaced in grain boundaries or defective zones in which hyperfine magnetic splitting decrease to ˜ 30.0 T. In alloys with Zr three iron states are formed in each alloy, main part of iron is in the form of α-Fe and another two states depend on the concentration of Zr and represent iron in grain boundaries with Zr atoms in nearest neighbor. The changing of iron states is discussed.

Controlled Phase and Tunable Magnetism in Ordered Iron Oxide Nanotube Arrays Prepared by Atomic Layer Deposition

NASA Astrophysics Data System (ADS)

Zhang, Yijun; Liu, Ming; Peng, Bin; Zhou, Ziyao; Chen, Xing; Yang, Shu-Ming; Jiang, Zhuang-De; Zhang, Jie; Ren, Wei; Ye, Zuo-Guang

2016-01-01

Highly-ordered and conformal iron oxide nanotube arrays on an atomic scale are successfully prepared by atomic layer deposition (ALD) with controlled oxidization states and tunable magnetic properties between superparamagnetism and ferrimagnetism. Non-magnetic α-Fe2O3 and superparamagnetic Fe3O4 with a blocking temperature of 120 K are in-situ obtained by finely controlling the oxidation reaction. Both of them exhibit a very small grain size of only several nanometers due to the nature of atom-by-atom growth of the ALD technique. Post-annealing α-Fe2O3 in a reducing atmosphere leads to the formation of the spinel Fe3O4 phase which displays a distinct ferrimagnetic anisotropy and the Verwey metal-insulator transition that usually takes place only in single crystal magnetite or thick epitaxial films at low temperatures. The ALD deposition of iron oxide with well-controlled phase and tunable magnetism demonstrated in this work provides a promising opportunity for the fabrication of 3D nano-devices to be used in catalysis, spintronics, microelectronics, data storages and bio-applications.

Reaction of an Iron(IV) Nitrido Complex with Cyclohexadienes: Cycloaddition and Hydrogen-Atom Abstraction

PubMed Central

2015-01-01

The iron(IV) nitrido complex PhB(MesIm)3Fe≡N reacts with 1,3-cyclohexadiene to yield the iron(II) pyrrolide complex PhB(MesIm)3Fe(η5-C4H4N) in high yield. The mechanism of product formation is proposed to involve sequential [4 + 1] cycloaddition and retro Diels–Alder reactions. Surprisingly, reaction with 1,4-cyclohexadiene yields the same iron-containing product, albeit in substantially lower yield. The proposed reaction mechanism, supported by electronic structure calculations, involves hydrogen-atom abstraction from 1,4-cyclohexadiene to provide the cyclohexadienyl radical. This radical is an intermediate in substrate isomerization to 1,3-cyclohexadiene, leading to formation of the pyrrolide product. PMID:25068927

Changes in the state of iron atoms in Zr alloys during corrosion tests in an autoclave

NASA Astrophysics Data System (ADS)

Filippov, V. P.; Bateev, A. B.; Lauer, Yu. A.; Kargin, N. I.; Petrov, V. I.

2014-04-01

Mössbauerinvestigations were carried out on oxide films formed on specimens of zirconium alloys Zr-1.0 %wtFe-1.2 %wtSn-0.5 %wtCr subjected to corrosion in steam-water environment at a temperature of 360 °C and at a pressure of 16.8 MPa with lithium and boron additions, and on Zr-1.4 %wtFe-0.7 %wtCr corroded in steam-water environment at 350 °C and 16.8 MPa as well as in steam-water environment at 500 °C and 10 MPa. In the metal part of the samples, under the oxide film, the iron atoms are in form of intermetallic precipitates of Zr(Fe, Cr)2. The corrosion process decomposes the intermetallic precipitates and particles are formed of metallic iron with inclusions of chromium atoms -Fe(Cr), α-Fe2O3 and Fe3O4 compounds. Part of the iron ions are in divalent and part in trivalent paramagnetic states. It is proposed that some part of the iron containing oxide precipitates in the oxide film may be in the form of nanoparticles which pass from the superparamagnetic to the ferromagnetic state with decreasing temperature.

Axial ligand tuning of a nonheme iron(IV)–oxo unit for hydrogen atom abstraction

PubMed Central

Sastri, Chivukula V.; Lee, Jimin; Oh, Kyungeun; Lee, Yoon Jin; Lee, Junghyun; Jackson, Timothy A.; Ray, Kallol; Hirao, Hajime; Shin, Woonsup; Halfen, Jason A.; Kim, Jinheung; Que, Lawrence; Shaik, Sason; Nam, Wonwoo

2007-01-01

The reactivities of mononuclear nonheme iron(IV)–oxo complexes bearing different axial ligands, [FeIV(O)(TMC)(X)]n+ [where TMC is 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane and X is NCCH3 (1-NCCH3), CF3COO− (1-OOCCF3), or N3− (1-N3)], and [FeIV(O)(TMCS)]+ (1′-SR) (where TMCS is 1-mercaptoethyl-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane), have been investigated with respect to oxo-transfer to PPh3 and hydrogen atom abstraction from phenol OH and alkylaromatic CH bonds. These reactivities were significantly affected by the identity of the axial ligands, but the reactivity trends differed markedly. In the oxidation of PPh3, the reactivity order of 1-NCCH3 > 1-OOCCF3 > 1-N3 > 1′-SR was observed, reflecting a decrease in the electrophilicity of iron(IV)–oxo unit upon replacement of CH3CN with an anionic axial ligand. Surprisingly, the reactivity order was inverted in the oxidation of alkylaromatic CH and phenol OH bonds, i.e., 1′-SR > 1-N3 > 1-OOCCF3 > 1-NCCH3. Furthermore, a good correlation was observed between the reactivities of iron(IV)–oxo species in H atom abstraction reactions and their reduction potentials, Ep,c, with the most reactive 1′-SR complex exhibiting the lowest potential. In other words, the more electron-donating the axial ligand is, the more reactive the iron(IV)–oxo species becomes in H atom abstraction. Quantum mechanical calculations show that a two-state reactivity model applies to this series of complexes, in which a triplet ground state and a nearby quintet excited-state both contribute to the reactivity of the complexes. The inverted reactivity order in H atom abstraction can be rationalized by a decreased triplet-quintet gap with the more electron-donating axial ligand, which increases the contribution of the much more reactive quintet state and enhances the overall reactivity. PMID:18048327

Timing of multiple hydrothermal events in the iron oxide-copper-gold deposits of the Southern Copper Belt, Carajás Province, Brazil

NASA Astrophysics Data System (ADS)

Moreto, Carolina P. N.; Monteiro, Lena V. S.; Xavier, Roberto P.; Creaser, Robert A.; DuFrane, S. Andrew; Melo, Gustavo H. C.; Delinardo da Silva, Marco A.; Tassinari, Colombo C. G.; Sato, Kei

2015-06-01

The Southern Copper Belt, Carajás Province, Brazil, hosts several iron oxide-copper-gold (IOCG) deposits, including Sossego, Cristalino, Alvo 118, Bacuri, Bacaba, Castanha, and Visconde. Mapping and U-Pb sensitive high-resolution ion microprobe (SHRIMP) IIe zircon geochronology allowed the characterization of the host rocks, situated within regional WNW-ESE shear zones. They encompass Mesoarchean (3.08-2.85 Ga) TTG orthogneiss, granites, and remains of greenstone belts, Neoarchean (ca. 2.74 Ga) granite, shallow-emplaced porphyries, and granophyric granite coeval with gabbro, and Paleoproterozoic (1.88 Ga) porphyry dykes. Extensive hydrothermal zones include albite-scapolite, biotite-scapolite-tourmaline-magnetite alteration, and proximal potassium feldspar, chlorite-epidote and chalcopyrite formation. U-Pb laser ablation multicollector inductively coupled mass spectrometry (LA-MC-ICP-MS) analysis of ore-related monazite and Re-Os NTIMS analysis of molybdenite suggest multiple Neoarchean (2.76 and 2.72-2.68 Ga) and Paleoproterozoic (2.06 Ga) hydrothermal events at the Bacaba and Bacuri deposits. These results, combined with available geochronological data from the literature, indicate recurrence of hydrothermal systems in the Southern Copper Belt, including 1.90-1.88-Ga ore formation in the Sossego-Curral ore bodies and the Alvo 118 deposit. Although early hydrothermal evolution at 2.76 Ga points to fluid migration coeval with the Carajás Basin formation, the main episode of IOCG genesis (2.72-2.68 Ga) is related to basin inversion coupled with Neoarchean (ca. 2.7 Ga) felsic magmatism. The data suggest that the IOCG deposits in the Southern Copper Belt and those in the Northern Copper Belt (2.57-Ga Salobo and Igarapé Bahia-Alemão deposits) do not share a common metallogenic evolution. Therefore, the association of all IOCG deposits of the Carajás Province with a single extensive hydrothermal system is precluded.

Energy of the Isolated Metastable Iron-Nickel FCC Nanocluster with a Carbon Atom in the Tetragonal Interstice.

PubMed

Bondarenko, Natalya V; Nedolya, Anatoliy V

2017-12-01

The energy of the isolated iron-nickel nanocluster was calculated by molecular mechanics method using Lennard-Jones potential. The cluster included a carbon atom that drifted from an inside octahedral interstice to a tetrahedral interstice in [Formula: see text] direction and after that in <222> direction to the surface. In addition, one of 14 iron atoms was replaced by a nickel atom, the position of which was changing during simulation.The energy of the nanocluster was estimated at the different interatomic distances. As a result of simulation, the optimal interatomic distances of Fe-Ni-C nanocluster was chosen for the simulation, in which height of the potential barrier was maximal and face-centered cubic (FCC) nanocluster was the most stable.It is shown that there were three main positions of a nickel atom that significantly affected nanocluster's energy.The calculation results indicated that position of the carbon atom in the octahedral interstice was more energetically favorable than tetrahedral interstice in the case of FCC nanocluster. On the other side, the potential barrier was smaller in the direction [Formula: see text] than in the direction <022>.This indicates that there are two ways for carbon atom to drift to the surface of the nanocluster.

Archaean greenstone belts of Sierra Leone with comments on the stratigraphy and metallogeny

NASA Astrophysics Data System (ADS)

Umeji, A. C.

Four belts of weakly metamorphosed volcano-sedimentary material, of about 2700 Ma, are enclosed by older granulites, gneisses and migmatites in the eastern part, and (i) a basal ultramafic unit followed by (ii) mafic to feldspathic differentiate and then (iii) a terminal sedimentary formation has been recognized in all the four belts and their average ratio is ultramafic: mafic (greenstone): sedimentary unit (2:5:3). The belts are linear and tightly folded along N-S to NE-SW axis which is also the regional grain of the structures in the older basement complex that engulfs them. Structural and geochronological evidences suggest that the deformation of these volcano-sedimentary supracrustals began during the Liberian tectonism ( c. 2700 Ma) and culminated at the beginning of the Eburnean (2200 Ma). Diapiric rise of K-rich younger Aechaean granites which sharphy trangressed all the earlier rocks and their structural trends, marked the last geotectonic event in the Archaean of this part of West Africa. Chromite cumulate and asbestiform deposits characterize the layered ultramafic unit. whilst gold and associated base metal sulphides which were derived from the volcanic units became hydrothermally concentrated close to the contact between the volcanic units and the overlying sediments, and also in the fault zones. Iron ore deposits are restricted to the sedimentary units where they occur as banded iron formation. It is only in the huge metasedimetary piles of the Sula-Kangari belt that deposits of iron ore occur in commercially viable quantities. The patterns of distribution, deformation and mineralization in these greenstone belts appear to fit closely into island arc model of plate tectonic theory.

Controlled Phase and Tunable Magnetism in Ordered Iron Oxide Nanotube Arrays Prepared by Atomic Layer Deposition

DOE PAGES

Zhang, Yijun; Liu, Ming; Peng, Bin; ...

2016-01-27

Highly-ordered and conformal iron oxide nanotube arrays on an atomic scale are successfully prepared by atomic layer deposition (ALD) with controlled oxidization states and tunable magnetic properties between superparamagnetism and ferrimagnetism. Non-magnetic α-Fe 2O 3 and superparamagnetic Fe 2O 3with a blocking temperature of 120 K are in-situ obtained by finely controlling the oxidation reaction. Both of them exhibit a very small grain size of only several nanometers due to the nature of atom-by-atom growth of the ALD technique. Post-annealing α-Fe 2O 3 in a reducing atmosphere leads to the formation of the spinel Fe 3O 4 phase which displaysmore » a distinct ferrimagnetic anisotropy and the Verwey metal-insulator transition that usually takes place only in single crystal magnetite or thick epitaxial films at low temperatures. Finally, the ALD deposition of iron oxide with well-controlled phase and tunable magnetism demonstrated in this work provides a promising opportunity for the fabrication of 3D nano-devices to be used in catalysis, spintronics, microelectronics, data storages and bio-applications.« less

Green Belt Europe - borders separate, nature unites

Treesearch

Uwe Friedel

2015-01-01

During the period of the Cold War between 1945 and 1989, a "Green Belt" of valuable pristine landscapes developed along the border line between Eastern and Western Europe, the intensively fortified and guarded so called Iron Curtain. Due to the remoteness of the border areas, a high number of national parks and other large conservation areas can be found...

Interactions of foreign interstitial and substitutional atoms in bcc iron from ab initio calculations

NASA Astrophysics Data System (ADS)

You, Y.; Yan, M. F.

2013-05-01

C and N atoms are the most frequent foreign interstitial atoms (FIAs), and often incorporated into the surface layers of steels to enhance their properties by thermochemical treatments. Al, Si, Ti, V, Cr, Mn, Co, Ni, Cu, Nb and Mo are the most common alloying elements in steels, also can be called foreign substitutional atoms (FSAs). The FIA and FSA interactions play an important role in the diffusion of C and N atoms, and the microstructures and mechanical properties of surface modified layers. Ab initio calculations based on the density functional theory are carried out to investigate FIA interactions with FSA in ferromagnetic bcc iron. The FIA-FSA interactions are analyzed systematically from five aspects, including interaction energies, density of states (DOS), bond populations, electron density difference maps and local magnetic moments.

The Gogebic Iron Range - A Sample of the Northern Margin of the Penokean Fold and Thrust Belt

USGS Publications Warehouse

Cannon, William F.; LaBerge, Gene L.; Klasner, John S.; Schulz, Klaus J.

2008-01-01

The Gogebic iron range is an elongate belt of Paleoproterozoic strata extending from the west shore of Lake Gogebic in the upper peninsula of Michigan for about 125 km westward into northern Wisconsin. It is one of six major informally named iron ranges in the Lake Superior region and produced about 325 million tons of direct-shipping ore between 1887 and 1967. A significant resource of concentrating-grade ore remains in the western and eastern parts of the range. The iron range forms a broad, gently southward-opening arc where the central part of the range exposes rocks that were deposited somewhat north of the eastern and western parts. A fundamental boundary marking both the tectonic setting of deposition and the later deformation within the Penokean orogen lies fortuitously in an east-west direction along the range so that the central part of the range preserves sediments deposited north of that boundary, whereas the eastern and western parts of the range were deposited south of the boundary. Thus, the central part of the range provides a record of sedimentation and very mild deformation in a part of the Penokean orogen farthest from the interior of the orogen to the south. The eastern and western parts of the range, in contrast, exhibit a depositional and deformational style typical of parts closer to the interior of the orogen. A second fortuitous feature of the iron range is that the entire area was tilted from 40° to 90° northward by Mesoproterozoic deformation so that the map view offers an oblique cross section of the Paleoproterozoic sedimentary sequence and structures. Together, these features make the Gogebic iron range a unique area in which to observe (1) the lateral transition from deposition on a stable platform to deposition in a tectonically and volcanically active region, and (2) the transition from essentially undeformed Paleoproterozoic strata to their folded and faulted equivalents.Paleoproterozoic strata in the Gogebic iron range are part

Influence of Plasma Environment on K-Line Emission in Highly Ionized Iron Atoms Evaluated Using a Debye-Huckel Model

NASA Technical Reports Server (NTRS)

Deprince, J.; Fritzsche, S.; Kallman, T. R.; Palmeri, P.; Quinet, P.

2017-01-01

The influence of plasma environment on the atomic parameters associated with the K-vacancy states has been investigated theoretically for several iron ions. To do this, a time-averaged Debye-Huckel potential for both the electron-nucleus and electron-electron interactions has been considered in the framework of relativistic multiconfiguration Dirac-Fock computations. More particularly, the plasma screening effects on ionization potentials, K-thresholds, transition energies, and radiative rates have been estimated in the astrophysical context of accretion disks around black holes. In the present paper, we describe the behavior of those atomic parameters for Ne-, Na-, Ar-, and K-like iron ions.

TIPTOPbase: the Iron Project and the Opacity Project Atomic Database

NASA Astrophysics Data System (ADS)

Mendoza, Claudio; Nahar, Sultana; Pradhan, Anil; Seaton, Micheal; Zeippen, Claude

2001-05-01

The Opacity Project, the IRON Project, and the RmaX Network (The Opacity Project Team, Vol.1,2), IOPP, Bristol (1995,1996); Hummer et al., Astron. Astrophys. 279, 298 (1993) are international computational efforts concerned with the production of high quality atomic data for astrophysical applications. Research groups from Canada, France, Germany, UK, USA and Venezuela are involved. Extensive data sets containing accurate energy levels, f-values, A-values, photoionisation cross sections, collision strengths, recombination rates, and opacitites have been computed for cosmically abundant elements using state-of-the-art atomic physics codes. Their volume, completeness and overall accuracy are presently unmatched in the field of laboratory astrophysics. Some of the data sets have been available since 1993 from a public on-line database service referred to as TOPbase (Cunto et al Astron. Astrophys. 275), L5 (1993), ( http://cdsweb.u-strasbg.fr/OP.html at CDS France, and http://heasarc.gsfc.nasa.gov/topbase, at NSAS USA). We are currently involved in a major effort to scale the existing database services to develop a robust platform for the high-profile dissemination of atomic data to the scientific community within the next 12 months. (Partial support from the NSF and NASA is acknowledged.)

The determination of aluminum, copper, iron, and lead in glycol formulations by atomic absorption spectroscopy

NASA Technical Reports Server (NTRS)

1977-01-01

Initial screening tests and the results obtained in developing procedures to determine Al, Cu, Fe, and Pb in glycol formulations are described. Atomic absorption completion was selected for Cu, Fe and Pb, and after comparison with emission spectroscopy, was selected for Al also. Before completion, carbon, iron, and lead are extracted with diethyl dithio carbamate (DDC) into methyl isobutyl ketone (MIBK). Aluminum was also extracted into MIBK using 8-hydroxyquinoline as a chelating agent. As little as 0.02 mg/l carbon and 0.06 mg/l lead or iron may be determined in glycol formulations. As little as 0.3 mg/l aluminum may be determined.

Automatic control system for uniformly paving iron ore pellets

NASA Astrophysics Data System (ADS)

Wang, Bowen; Qian, Xiaolong

2014-05-01

In iron and steelmaking industry, iron ore pellet qualities are crucial to end-product properties, manufacturing costs and waste emissions. Uniform pellet pavements on the grate machine are a fundamental prerequisite to ensure even heat-transfer and pellet induration successively influences performance of the following metallurgical processes. This article presents an automatic control system for uniformly paving green pellets on the grate, via a mechanism mainly constituted of a mechanical linkage, a swinging belt, a conveyance belt and a grate. Mechanism analysis illustrates that uniform pellet pavements demand the frontend of the swinging belt oscillate at a constant angular velocity. Subsequently, kinetic models are formulated to relate oscillatory movements of the swinging belt's frontend to rotations of a crank link driven by a motor. On basis of kinetic analysis of the pellet feeding mechanism, a cubic B-spline model is built for numerically computing discrete frequencies to be modulated during a motor rotation. Subsequently, the pellet feeding control system is presented in terms of compositional hardware and software components, and their functional relationships. Finally, pellet feeding experiments are carried out to demonstrate that the control system is effective, reliable and superior to conventional methods.

Deviation from Normal Boltzmann Distribution of High-lying Energy Levels of Iron Atom Excited by Okamoto-cavity Microwave-induced Plasmas Using Pure Nitrogen and Nitrogen-Oxygen Gases.

PubMed

Wagatsuma, Kazuaki

2015-01-01

This paper describes several interesting excitation phenomena occurring in a microwave-induced plasma (MIP) excited with Okamoto-cavity, especially when a small amount of oxygen was mixed with nitrogen matrix in the composition of the plasma gas. An ion-to-atom ratio of iron, which was estimated from the intensity ratio of ion to atomic lines having almost the same excitation energy, was reduced by adding oxygen gas to the nitrogen MIP, eventually contributing to an enhancement in the emission intensities of the atomic lines. Furthermore, Boltzmann plots for iron atomic lines were observed in a wide range of the excitation energy from 3.4 to 6.9 eV, indicating that plots of the atomic lines having lower excitation energies (3.4 to 4.8 eV) were well fitted on a straight line while those having more than 5.5 eV deviated upwards from the linear relationship. This overpopulation would result from any other excitation process in addition to the thermal excitation that principally determines the Boltzmann distribution. A Penning-type collision with excited species of nitrogen molecules probably explains this additional excitation mechanism, in which the resulting iron ions recombine with captured electrons, followed by cascade de-excitations between closely-spaced excited levels just below the ionization limit. As a result, these high-lying levels might be more populated than the low-lying levels of iron atom. The ionization of iron would be caused less actively in the nitrogen-oxygen plasma than in a pure nitrogen plasma, because excited species of nitrogen molecule, which can provide the ionization energy in a collision with iron atom, are consumed through collisions with oxygen molecules to cause their dissociation. It was also observed that the overpopulation occurred to a lesser extent when oxygen gas was added to the nitrogen plasma. The reason for this was also attributed to decreased number density of the excited nitrogen species due to collisions with oxygen

An Experimental Concept for Probing Nonlinear Physics in Radiation Belts

NASA Astrophysics Data System (ADS)

Crabtree, C. E.; Ganguli, G.; Tejero, E. M.; Amatucci, B.; Siefring, C. L.

2017-12-01

A sounding rocket experiment, Space Measurement of Rocket-Released Turbulence (SMART), can be used to probe the nonlinear response to a known stimulus injected into the radiation belt. Release of high-speed neutral barium atoms (8- 10 km/s) generated by a shaped charge explosion in the ionosphere can be used as the source of free energy to seed weak turbulence in the ionosphere. The Ba atoms are photo-ionized forming a ring velocity distribution of heavy Ba+ that is known to generate lower hybrid waves. Induced nonlinear scattering will convert the lower hybrid waves into EM whistler/magnetosonic waves. The escape of the whistlers from the ionospheric region into the radiation belts has been studied and their observable signatures quantified. The novelty of the SMART experiment is to make coordinated measurement of the cause and effect of the turbulence in space plasmas and from that to deduce the role of nonlinear scattering in the radiation belts. Sounding rocket will carry a Ba release module and an instrumented daughter section that includes vector wave magnetic and electric field sensors, Langmuir probes and energetic particle detectors. The goal of these measurements is to determine the whistler and lower hybrid wave amplitudes and spectrum in the ionospheric source region and look for precipitated particles. The Ba release may occur at 600-700 km near apogee. Ground based cameras and radio diagnostics can be used to characterize the Ba and Ba+ release. The Van Allen Probes can be used to detect the propagation of the scattering-generated whistler waves and their effects in the radiation belts. By detecting whistlers and measuring their energy density in the radiation belts the SMART mission will confirm the nonlinear generation of whistlers through scattering of lower hybrid along with other nonlinear responses of the radiation belts and their connection to weak turbulence.

Auger electron spectroscopy study of surface segregation in the binary alloys copper-1 atomic percent indium, copper-2 atomic percent tin, and iron-6.55 atomic percent silicon

NASA Technical Reports Server (NTRS)

Ferrante, J.

1973-01-01

Auger electron spectroscopy was used to examine surface segregation in the binary alloys copper-1 at. % indium, copper-2 at. % tin and iron-6.55 at. % silicon. The copper-tin and copper-indium alloys were single crystals oriented with the /111/ direction normal to the surface. An iron-6.5 at. % silicon alloy was studied (a single crystal oriented in the /100/ direction for study of a (100) surface). It was found that surface segregation occurred following sputtering in all cases. Only the iron-silicon single crystal alloy exhibited equilibrium segregation (i.e., reversibility of surface concentration with temperature) for which at present we have no explanation. McLean's analysis for equilibrium segregation at grain boundaries did not apply to the present results, despite the successful application to dilute copper-aluminum alloys. The relation of solute atomic size and solubility to surface segregation is discussed. Estimates of the depth of segregation in the copper-tin alloy indicate that it is of the order of a monolayer surface film.

Electrochemical CO 2 Reduction with Atomic Iron-Dispersed on Nitrogen-Doped Graphene

DOE PAGES

Zhang, Chenhao; Yang, Shize; Wu, Jingjie; ...

2018-03-25

Electrochemical reduction of CO 2 provides an opportunity to reach a carbon-neutral energy recycling regime, in which CO 2 emissions from fuel use are collected and converted back to fuels. The reduction of CO 2 to CO is the first step toward the synthesis of more complex carbon-based fuels and chemicals. Therefore, understanding this step is crucial for the development of high-performance electrocatalyst for CO 2 conversion to higher order products such as hydrocarbons. In this paper, atomic iron dispersed on nitrogen-doped graphene (Fe/NG) is synthesized as an efficient electrocatalyst for CO 2 reduction to CO. Fe/NG has a lowmore » reduction overpotential with high Faradic efficiency up to 80%. The existence of nitrogen-confined atomic Fe moieties on the nitrogen-doped graphene layer is confirmed by aberration-corrected high-angle annular dark-field scanning transmission electron microscopy and X-ray absorption fine structure analysis. The Fe/NG catalysts provide an ideal platform for comparative studies of the effect of the catalytic center on the electrocatalytic performance. Finally, the CO 2 reduction reaction mechanism on atomic Fe surrounded by four N atoms (Fe–N 4) embedded in nitrogen-doped graphene is further investigated through density functional theory calculations, revealing a possible promotional effect of nitrogen doping on graphene.« less

Electrochemical CO 2 Reduction with Atomic Iron-Dispersed on Nitrogen-Doped Graphene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Chenhao; Yang, Shize; Wu, Jingjie

Electrochemical reduction of CO 2 provides an opportunity to reach a carbon-neutral energy recycling regime, in which CO 2 emissions from fuel use are collected and converted back to fuels. The reduction of CO 2 to CO is the first step toward the synthesis of more complex carbon-based fuels and chemicals. Therefore, understanding this step is crucial for the development of high-performance electrocatalyst for CO 2 conversion to higher order products such as hydrocarbons. In this paper, atomic iron dispersed on nitrogen-doped graphene (Fe/NG) is synthesized as an efficient electrocatalyst for CO 2 reduction to CO. Fe/NG has a lowmore » reduction overpotential with high Faradic efficiency up to 80%. The existence of nitrogen-confined atomic Fe moieties on the nitrogen-doped graphene layer is confirmed by aberration-corrected high-angle annular dark-field scanning transmission electron microscopy and X-ray absorption fine structure analysis. The Fe/NG catalysts provide an ideal platform for comparative studies of the effect of the catalytic center on the electrocatalytic performance. Finally, the CO 2 reduction reaction mechanism on atomic Fe surrounded by four N atoms (Fe–N 4) embedded in nitrogen-doped graphene is further investigated through density functional theory calculations, revealing a possible promotional effect of nitrogen doping on graphene.« less

Imaging measurements of atomic iron concentration with laser-induced fluorescence in a nanoparticle synthesis flame reactor

NASA Astrophysics Data System (ADS)

Hecht, C.; Kronemayer, H.; Dreier, T.; Wiggers, H.; Schulz, C.

2009-01-01

The iron-atom concentration distribution as well as the gas-phase temperature was measured via laser-induced fluorescence (LIF) during iron-oxide nanoparticle synthesis in a low-pressure hydrogen/oxygen/argon flame reactor using ironpentacarbonyl (Fe(CO)5) as precursor. Temperature measurements based on multi-line NO-LIF imaging are used to correct for temperature-dependent ground-state populations. The concentration measurement is calibrated based on line-of-sight absorption measurements. The influence of the precursor on the flame is observed at precursor concentrations larger than 70 ppm as the flame front moves closer to the burner surface with increasing Fe(CO)5 concentration.

Geophysical ore guides along the Colorado mineral belt

USGS Publications Warehouse

Case, James E.

1967-01-01

A 40-50-mgal gravity low trends northeast along the Colorado mineral belt between Monarch Pass and Breckenridge, Colorado. The low is probably caused by a silicic Tertiary batholith of lower density than adjacent Precambrian crystalline rocks. Many major mining districts associated with silicic Tertiary intrusives are near the axis of the low. Positive and negative aeromagnetic anomalies are present over the larger silicic Tertiary intrusive bodies. A good correlation exists between the magnetic lows and zones of altered, mineralized porphyry. Apparently, original magnetite in the silicic porphyries has been altered to relatively nonmagnetic pyrite or iron oxides. The regional gravity low aids in defining the limits of the mineral belt, and the magnetic lows over the porphyries indicate specific alteration zones and the possibility of associated mineral deposits.

New laboratory atomic data for neutral, singly and doubly ionised iron group elements for astrophysics applications

NASA Astrophysics Data System (ADS)

Pickering, Juliet C.; Nave, Gillian; Liggins, Florence; Clear, Christian; Ruffoni, Matthew; Sansonetti, Craig

2015-08-01

We present new laboratory spectroscopic measurements to produce atomic data for astrophysically important species: neutral, singly and doubly ionised iron group elements.We use high resolution Fourier Transform Spectrometry (FTS) (resolving power up to 2x106 at 200nm) to measure atomic spectra, giving accurate line wavelengths (to a few parts in 108), atomic energy levels, hyperfine structure splitting and log gfs (accurate to a few %) (Ruffoni et al this meeting). These data are vital for astrophysical spectral analyses for: line identification, spectrum synthesis, elemental abundance determinations [eg 1], and disentangling of blends etc. It is not possible to theoretically calculate these atomic data to the accuracy needed for modern astrophysics applications.At Imperial College we have a unique visible-VUV FT spectrometer with short wavelength cut-off of 135nm. We supplement FTS data at shorter wavelengths with spectra recorded on the NIST 10.7m grating spectrograph (with phosphor image or photographic plates) and at longer wavelengths in the IR we use the NIST IR FT spectrometer.An elemental spectrum may contain thousands of spectral lines from the IR to VUV. We use these wavelengths to correct known atomic energy levels, and search for new atomic levels. The result is a classified linelist and accurate atomic energy levels.We present progress on iron group element atomic energy levels and wavelengths for V I and V II [2,3], Co III [4], Cr I, Mn I and Mn II, and Ni II.This work is supported by STFC(UK), The Leverhulme Trust, The Royal Society and NASA.References[1] Bergemann M, Pickering JC & Gehren T,“NLTE analysis of Co I/Co II lines in spectra of cool stars with new laboratory hyperfine splitting constants",MNRAS 401(2) 1334 (2010)[2] Thorne AP, Pickering JC & Semeniuk J,“The spectrum and term analysis of V II”, ApJS 207,13 (2013)[3] Thorne AP, Pickering JC & Semeniuk J,“The spectrum and term analysis of V I",ApJS 192,11 (2011)[4] Smillie DG

Coherence properties and quantum state transportation in an optical conveyor belt.

PubMed

Kuhr, S; Alt, W; Schrader, D; Dotsenko, I; Miroshnychenko, Y; Rosenfeld, W; Khudaverdyan, M; Gomer, V; Rauschenbeutel, A; Meschede, D

2003-11-21

We have prepared and detected quantum coherences of trapped cesium atoms with long dephasing times. Controlled transport by an "optical conveyor belt" over macroscopic distances preserves the atomic coherence with slight reduction of coherence time. The limiting dephasing effects are experimentally identified, and we present an analytical model of the reversible and irreversible dephasing mechanisms. Our experimental methods are applicable at the single-atom level. Coherent quantum bit operations along with quantum state transport open the route towards a "quantum shift register" of individual neutral atoms.

Outcome of impact disruption of iron meteorites at room temperature

NASA Astrophysics Data System (ADS)

Katsura, T.; Nakamura, A.; Takabe, A.; Okamoto, T.; Sangen, K.; Hasegawa, S.; Liu, X.; Mashimo, T.

2014-07-01

The iron meteorites and some M-class asteroids are generally understood to originate in the cores of differentiated planetesimals or in the local melt pools of primitive bodies. On these primitive bodies and planetesimals, a wide range of collisional events at different mass scales, temperatures, and impact velocities would have occurred. Iron materials have a brittle-ductile transition at a certain temperature, which depends on metallurgical factors such as grain size and purity, and on conditions such as strain-rate and confining pressure [1]. An evolutional scenario of iron meteorite parent bodies was proposed in which they formed in the terrestrial planet region, after which they were scattered into the main belt by collisions, Yarkovsky thermal forces, and resonances [2]. In this case, they may have experienced collisional evolution in the vicinity of the Earth before they were scattered into the main belt. The size distribution of iron bodies in the main belt may therefore have depended on the disruption threshold of iron bodies at temperature above the brittle-ductile transition. This paper presents the results of impact-disruption experiments of iron meteorite and steel specimens mm-cm in size as projectiles or targets conducted at room temperature using three light-gas guns and one powder gun. Our iron specimens were almost all smaller in size than their counterparts (as targets or projectiles, respectively). The fragment size distribution of iron material was different from that of rocks. In iron fragmentation, a higher percentage of the mass is concentrated in larger fragments, i.e., the mass fraction of fine fragments is much less than that of rocks shown in the Figure (left). This is probably due to the ductile nature of the iron materials at room temperature. Furthermore, the Figure (right) shows that the largest fragment mass fraction f is dependent not only on the energy density but also on the size of the specimens. In order to obtain a generalized

Diagnosis of thalassemia and iron deficiency anemia using confocal and atomic force microscopy

NASA Astrophysics Data System (ADS)

Tariq, Saira; Bilal, Muhammad; Shahzad, Shaheen; Firdous, Shamaraz; Aziz, Uzma; Ahmed, Mushtaq

2017-11-01

Anemia is the most prevalent blood disorder, categorized into thalassemia and iron deficiency anemia. In anemia, the morphology of erythrocytes is disturbed, thus leading to abnormal functioning of the erythrocytes. Globally, thalassemia affects 1.3% of individuals and is one of the most widespread monogenic disorders in Pakistan. All over the World, women and children are most frequently affected by a type of nutritional deficiency known as iron deficiency anemia. The morphological changes that occur in erythrocytes due to these diseases are investigated in this study at the nano-scale level. Fifty samples of blood from individuals suffering from thalassemia or iron deficiency anemia were obtained from different hospitals in Rawalpindi and Islamabad. The blood samples were scanned using atomic force microscopy (AFM) and laser scanning confocal microscopy (LSCM) to check the morphological changes in both types of anemia. According to the present study, thalassemia is most prevalent in females in the age group between 5 and 15 years old, and iron deficiency is most prevalent in females in the age groups of 16-25 and 36-45 years old. Erythrocyte morphology is the significant determinant for diagnosing and discriminating between these two types of diseases. The study reports deformed erythrocytes in anemic patients, which were different from the ones that existed in the control. Thalassemia erythrocytes showed a crenated shape, iron deficiency anemia erythrocytes showed an elliptocyte shape and healthy erythrocytes showed a biconcave disk shape when using AFM and LSCM. These techniques seem to be very promising, cheap and less time consuming in determining the structure-function relationship of erythrocytes of thalassemic and iron deficiency anemic patients. The results of LSCM and AFM are quite useful in determining the morphological changes in erythrocytes and to study the disease at the molecular level within short period of time. Hence, we encourage employing

The Iron Project

NASA Technical Reports Server (NTRS)

Pradhan, Anil K.

2000-01-01

Recent advances in theoretical atomic physics have enabled large-scale calculation of atomic parameters for a variety of atomic processes with high degree of precision. The development and application of these methods is the aim of the Iron Project. At present the primary focus is on collisional processes for all ions of iron, Fe I - FeXXVI, and other iron-peak elements; new work on radiative processes has also been initiated. Varied applications of the Iron Project work to X-ray astronomy are discussed, and more general applications to other spectral ranges are pointed out. The IP work forms the basis for more specialized projects such as the RmaX Project, and the work on photoionization/recombination, and aims to provide a comprehensive and self-consistent set of accurate collisional and radiative cross sections, and transition probabilities, within the framework of relativistic close coupling formulation using the Breit-Pauli R-Matrix method. An illustrative example is presented of how the IP data may be utilized in the formation of X-ray spectra of the K alpha complex at 6.7 keV from He-like Fe XXV.

Morphology of the ferritin iron core by aberration corrected scanning transmission electron microscopy

NASA Astrophysics Data System (ADS)

Jian, Nan; Dowle, Miriam; Horniblow, Richard D.; Tselepis, Chris; Palmer, Richard E.

2016-11-01

As the major iron storage protein, ferritin stores and releases iron for maintaining the balance of iron in fauna, flora, and bacteria. We present an investigation of the morphology and iron loading of ferritin (from equine spleen) using aberration-corrected high angle annular dark field scanning transmission electron microscopy. Atom counting method, with size selected Au clusters as mass standards, was employed to determine the number of iron atoms in the nanoparticle core of each ferritin protein. Quantitative analysis shows that the nuclearity of iron atoms in the mineral core varies from a few hundred iron atoms to around 5000 atoms. Moreover, a relationship between the iron loading and iron core morphology is established, in which mineral core nucleates from a single nanoparticle, then grows along the protein shell before finally forming either a solid or hollow core structure.

Iron Atoms in Cr-Mn Antiferromagnetic Matrix

NASA Astrophysics Data System (ADS)

Szymański, K.; Satuła, D.; Dobrzyński, L.; Biernacka, M.; Perzyńska, K.; Zaleski, P.

2002-06-01

The results of the Mössbauer effect measurements on bcc Cr rich Cr-Fe-Mn alloys in temperature range 12-296 K in zero- and in applied magnetic fields are reported. Monochromatic, circularly polarized radiation was used for investigation of iron moments alignment. Strong enhancement of internal hyperfine magnetic field induced by the applied magnetic field was detected and explained as due to dynamical effects. At high temperatures alignment of iron moments in antiferromagnetic phase is weakly magnetic field-dependent. At low temperatures the average hyperfine magnetic field is antiparallel to the net magnetization showing that iron moments are partly ordered by the applied field.

3D polymer hydrogel for high-performance atomic iron-rich catalysts for oxygen reduction in acidic media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qiao, Zhi; Zhang, Hanguang; Karakalos, Stavros

Current platinum group metal (PGM)-free carbon nanocomposite catalysts for the oxygen reduction reaction (ORR) in acidic electrolyte often suffer from rapid degradation associated with carbon corrosion due to the use of large amount of amorphoous carbon black supports. Here, we developed a new concept of using freestanding 3D hydrogel to design support-free Fe-N-C catalysts. A 3D polyaniline (PANI)-based hydrogel was used for preparing a new type of single atomic iron site-rich catalyst, which has exhibited exceptionally enhanced activity and stability compared to conventional Fe-N-C catalysts supported on amorphous carbon blacks. The achieved performance metric on the hydrogel PANI-Fe catalysts ismore » one of the best ever reported PGM-free catalysts, reaching a half-wave potential up to 0.83 V vs. RHE and only leaving 30 mV gap with Pt/C catalysts (60 μgPt/cm2) in challenging acidic media. Remarkable ORR stability was accomplished as well on the same catalyst evidenced by using harsh potential cycling tests. The well dispersion of atomic iron into partially graphitized carbon, featured with dominance of micropores and porous network structures, is capable of accommodating increased number of active sites, strengthening local bonding among iron, nitrogen and carbon, and facilitating mass transfer. The 3D polymer hydrogel approach would be a new pathway to advance PGM-free catalysts.« less

3D polymer hydrogel for high-performance atomic iron-rich catalysts for oxygen reduction in acidic media

DOE PAGES

Qiao, Zhi; Zhang, Hanguang; Karakalos, Stavros; ...

2017-08-03

Current platinum group metal (PGM)-free carbon nanocomposite catalysts for the oxygen reduction reaction (ORR) in acidic electrolyte often suffer from rapid degradation associated with carbon corrosion due to the use of large amount of amorphoous carbon black supports. Here, we developed a new concept of using freestanding 3D hydrogel to design support-free Fe-N-C catalysts. A 3D polyaniline (PANI)-based hydrogel was used for preparing a new type of single atomic iron site-rich catalyst, which has exhibited exceptionally enhanced activity and stability compared to conventional Fe-N-C catalysts supported on amorphous carbon blacks. The achieved performance metric on the hydrogel PANI-Fe catalysts ismore » one of the best ever reported PGM-free catalysts, reaching a half-wave potential up to 0.83 V vs. RHE and only leaving 30 mV gap with Pt/C catalysts (60 μgPt/cm2) in challenging acidic media. Remarkable ORR stability was accomplished as well on the same catalyst evidenced by using harsh potential cycling tests. The well dispersion of atomic iron into partially graphitized carbon, featured with dominance of micropores and porous network structures, is capable of accommodating increased number of active sites, strengthening local bonding among iron, nitrogen and carbon, and facilitating mass transfer. The 3D polymer hydrogel approach would be a new pathway to advance PGM-free catalysts.« less

How Many Atomic Layers of Zinc Are in a Galvanized Iron Coating? An Experiment for General Chemistry Laboratory

ERIC Educational Resources Information Center

Yang, Shui-Ping

2007-01-01

This article describes an experiment using a novel gasometric assembly to determine the thickness and number of atomic layers of zinc coating on galvanized iron substrates. Students solved this problem through three stages. In the first stage, students were encouraged to find a suitable acidic concentration through the guided-inquiry approach. In…

Iron mineralization at the Songhu deposit, Chinese Western Tianshan: a type locality with regional metallogenic implications

NASA Astrophysics Data System (ADS)

Wang, Chun-Long; Wang, Yi-Tian; Dong, Lian-Hui; Qin, Ke-Zhang; Evans, Noreen J.; Zhang, Bing; Ren, Yi

2018-01-01

Hosted by volcaniclastics of the Carboniferous Dahalajunshan Formation, the Songhu iron deposit is located in the central segment of the Awulale metallogenic belt, Chinese Western Tianshan. Mineralization and alteration are structurally controlled by orogen-parallel NWW-striking faults. Integrating with mineralogical and stable isotopic analyses based on paragenetic relationships, two types of iron mineralization have been identified. The deuteric mineralization (Type I) represented by brecciated, banded, and disseminated-vein ores juxtaposed with potassic-calcic alteration in the inner zone, which was formed from a magmatic fluid generated during the late stages of regional volcanism. In contrast, the volcanic-hydrothermal mineralization (Type II) is characterized by hydrothermal features occurring in massive and agglomerated ores with abundant sulfides, and was generated from the magmatic fluid with seawater contamination. Two volcaniclastic samples from the hanging and footwall of the main orebody yield zircon U-Pb ages of 327.8 ± 3.1 and 332.0 ± 2.0 Ma, respectively, which indicate Middle Carboniferous volcanism. Timing for iron mineralization can be broadly placed in the same epoch. By reviewing geological, mineralogical, and geochemical features of the primary iron deposits in the Awulale metallogenic belt, we propose that the two types of iron mineralization in the Songhu iron deposit are representative regionally. A summary of available geochronological data reveals Middle-Late Carboniferous polycyclic ore-related volcanism, and nearly contemporaneous iron mineralization along the belt. Furthermore, petro-geochemistry of volcanic-volcaniclastic host rocks indicates that partial melting of a metasomatized mantle wedge under a continental arc setting could have triggered the continuous volcanic activities and associated metallogenesis.

Intrusive rocks and plutonic belts of southeastern Alaska, U.S.A.

USGS Publications Warehouse

Brew, David A.; Morrell, Robert P.; Roddick, J.A.

1983-01-01

reconstruction of 200 km of right-lateral movement on the Chatham Strait fault does not significantly change the pattern of the major belts but does bring parts of the minor mid-Tertiary and Ordovician(?) belts closer together. The major belts are related to the stratigraphic-tectonic terranes of Berg, Jones, and Coney (1978) as follows: the Fairweather-Baranof belt is largely in the Chugach, Wrangell (Wrangellia), and Alexander terranes; the Muir-Chichagof belt is in the Alexander and Wrangell terranes; the Admiralty-Revillagigedo belt is in the Gravina and Taku terranes; the Klukwan-Duke belt is in the Gravina, Taku, and Alexander terranes; the Coast Plutonic Complex sill belt is probably between the Taku and Tracy Arm terranes; and the Coast Plutonic Complex belts I and II are in the Tracy Arm and Stikine terranes. Significant metallic-mineral deposits are spatially related to certain of these belts, and some deposits may be genetically related. Gold, copper, and molybdenum occurrences may be related to granodiorites of the Fairweather-Baranof belt. Magmatic copper-nickel deposits occur in the layered gabbro within that belt. The Juneau gold belt, which contains gold, silver, copper, lead, and zinc occurrences, parallels and lies close to the Coast Plutonic Complex sill belt; iron deposits occur in the Klukwan-Duke belt; and porphyry molybdenum deposits occur in the Behm Canal belt. The Muir-Chichagof belt of mid-Cretaceous age and the Admiralty-Revillagigedo belt of probable Cretaceous age are currently interpreted as possible magmatic arcs associated with subduction events. In general, the other belts of intrusive rocks are spatially related to structural discontinuities, but genetic relations, if any, are not yet known. The Coast Plutonic Complex sill belt is probably related to a post-Triassic, pre-early Tertiary suture zone that nearly corresponds to the boundary between the Tracy Arm and Taku terranes. The boundary between the Admiralty-Revillagigedo and Muir

The Chemistry of Meteoric Iron

NASA Astrophysics Data System (ADS)

Self, D. E.; Plane, J. M. C.

About 120 tonnes of interplanetary dust enters the earth's atmosphere each day. Iron comprises a large fraction of this dust (12% by mass), and ablation of the particles gives rise to the layer of Fe atoms that occurs globally in the mesosphere around 85 km. Previous work in our laboratory has shown that Fe reacts rapidly with O3 to form FeO, which in turn reacts with O3, O2 and H2O to form FeO2, FeO3 and Fe(OH)2, respectively. The purpose of the present study was to determine which of these com- pounds provide stable reservoirs for iron below the atomic Fe layer, and hence form the "building blocks" of meteoric smoke particles which are implicated in phenomena lower in the atmosphere (e.g., noctilucent clouds and polar stratospheric ozone deple- tion). The reactions of these iron compounds were studied in a fast flow tube using the pulsed laser ablation of a rotating iron rod as the source of Fe atoms in the up- stream section of the tube. Iron compounds were produced by adding reactants further down the tube, and finally atomic O or H was added through a movable injector. At the downstream end of the tube, atomic Fe was detected by laser induced fluorescence at 248 nm. The following reactions were studied: FeO + O, FeO2 + O, FeO3 + O, FeO2 + O3, FeO3 + H2O, FeO3 + H, Fe(OH)2 + H, and FeOH + H. It is clear that the iron reservoir around 80 km is FeO3, which reacts very slowly with atomic O, in agreement with the requirements of a recent atmospheric model. However, Fe(OH)2 and FeO(OH), which are thermodynamically the most stable of these Fe species and eventually form from FeO3, are the likely building blocks of meteoric smoke.

Iron meteorites as remnants of planetesimals formed in the terrestrial planet region.

PubMed

Bottke, William F; Nesvorný, David; Grimm, Robert E; Morbidelli, Alessandro; O'Brien, David P

2006-02-16

Iron meteorites are core fragments from differentiated and subsequently disrupted planetesimals. The parent bodies are usually assumed to have formed in the main asteroid belt, which is the source of most meteorites. Observational evidence, however, does not indicate that differentiated bodies or their fragments were ever common there. This view is also difficult to reconcile with the fact that the parent bodies of iron meteorites were as small as 20 km in diameter and that they formed 1-2 Myr earlier than the parent bodies of the ordinary chondrites. Here we show that the iron-meteorite parent bodies most probably formed in the terrestrial planet region. Fast accretion times there allowed small planetesimals to melt early in Solar System history by the decay of short-lived radionuclides (such as 26Al, 60Fe). The protoplanets emerging from this population not only induced collisional evolution among the remaining planetesimals but also scattered some of the survivors into the main belt, where they stayed for billions of years before escaping via a combination of collisions, Yarkovsky thermal forces, and resonances. We predict that some asteroids are main-belt interlopers (such as (4) Vesta). A select few may even be remnants of the long-lost precursor material that formed the Earth.

Geochemistry of volcanic rocks from the Wawa greenstone belt

NASA Technical Reports Server (NTRS)

Schulz, K. J.; Sylvester, P. J.; Attoh, K.

1983-01-01

The Wawa greenstone belt is located in the District of Algoma and extends east-northeast from Lake Superior to the western part of the Sudbury District in Ontario, Canada. Recent mapping by Attoh has shown that an unconformity at the base of the Dore' Formation and equivalent sedimentary rocks marks a significant stratigraphic break which can be traced throughout the volcanic belt. This break has been used to subdivide the volcanic-sedimentary into pre- and post-Dore' sequences. The pre-Dore' sequence includes at least two cycles of mafic-to-felsic volcanism, each capped by an iron-formation unit. The post-Dore' sequence includes an older mafic-to-felsic unit, which directly overlies sedimentary rocks correlated with the Dore' Formation, and a younger felsic breccia unit interpreted to have formed as debris flows from a felsic volcanic center. In the present study, samples of both the pre-and post-Dore' volcanic sequences were analyzed for major and trace elements, incuding rare earths (REE). This preliminary study is part of an ongoing program to assess the petrogenesis of the volcanic rocks of the Wawa greenstone belt.

Thermogravimetric analysis of the interaction of ferromagnetic metal atom and multiwalled carbon nanotubes.

PubMed

Rawat, Naveen; Gudyaka, Russel; Kumar, Mohit; Joshi, Bharat; Santhanam, Kalathur S V

2008-04-01

This paper describes the thermal oxidative behavior of atomized iron or atomized cobalt in the presence of multiwalled carbon nanotubes (MWCNT). The thermogravimetric analysis shows the atomized iron thermal oxidation starts at about 500 degrees C that is absent when the atomized iron is sintered with multiwalled carbon naonotubes. The thermal oxidation of iron in the sintered samples requires the collapse of the multiwalled carbon nanotubes. A similar behavior is observed with atomized cobalt when its oxidation requires the collapse of the nanotubes. This thermal oxidative shift is interpreted as due to the atomized iron or atomized cobalt atom experiencing extensive overlap and confinement effect with multiwalled carbon nanotubes causing a spin transfer. This confinement effect is suggested to produce a transformation of iron from the outermost electronic distribution of 3d64s2 to an effective configuration of 3d84s0 and for cobalt 3d74s2 to 3d94s0 producing spintronics effect.

Laterally bendable belt conveyor

DOEpatents

Peterson, William J.

1985-01-01

An endless, laterally flexible and bendable belt conveyor particularly adapted for coal mining applications in facilitating the transport of the extracted coal up- or downslope and around corners in a continuous manner is disclosed. The conveying means includes a flat rubber belt reinforced along the middle portion thereof along which the major portion of the belt tension is directed so as to cause rotation of the tubular shaped belt when trammed around lateral turns thus preventing excessive belt bulging distortion between adjacent belt supports which would inhibit belt transport. Pretension induced into the fabric reinforced flat rubber belt by conventional belt take-up means supports the load conveyed when the belt conveyor is making lateral turns. The carrying and return portions of the belt are supported and formed into a tubular shape by a plurality of shapers positioned along its length. Each shaper is supported from above by a monorail and includes clusters of idler rollers which support the belt. Additional cluster rollers in each shaper permit the belt supporting roller clusters to rotate in response to the belt's operating tension imposed upon the cluster rollers by induced lateral belt friction forces. The freely rotating roller clusters thus permit the belt to twist on lateral curves without damage to itself while precluding escape of the conveyed material by effectively enclosing it in the tube-shaped, inner belt transport length.

Support effects in single atom iron catalysts on adsorption characteristics of toxic gases (NO2, NH3, SO3 and H2S)

NASA Astrophysics Data System (ADS)

Gao, Zhengyang; Yang, Weijie; Ding, Xunlei; Lv, Gang; Yan, Weiping

2018-04-01

The effects of support on gas adsorption is crucial for single atom catalysts design and optimization. To gain insight into support effects on gas adsorption characteristics, a comprehensive theoretical study was performed to investigate the adsorption characteristics of toxic gases (NO2, NH3, SO3 and H2S) by utilizing single atom iron catalysts with three graphene-based supports. The adsorption geometry, adsorption energy, electronic and magnetic properties of the adsorption system have been explored. Additionally, the support effects have been analyzed through d-band center and Fermi softness, and thermodynamic analysis has been performed to consider the effect of temperature on gas adsorption. The support effects have a remarkable influence on the adsorption characteristics of four types of toxic gases which is determined by the electronic structure of graphene-based support, and the electronic structure can be characterized by Fermi softness of catalysts. Fermi softness and uplift height of Fe atom could be good descriptors for the adsorption activity of single atom iron catalysts with graphene-based supports. The findings can lay a foundation for the further study of graphene-based support effects in single atom catalysts and provide a guideline for development and design of new graphene-based support materials utilizing the idea of Fermi softness.

Iron Homeostasis and Nutritional Iron Deficiency123

PubMed Central

Theil, Elizabeth C.

2011-01-01

Nonheme food ferritin (FTN) iron minerals, nonheme iron complexes, and heme iron contribute to the balance between food iron absorption and body iron homeostasis. Iron absorption depends on membrane transporter proteins DMT1, PCP/HCP1, ferroportin (FPN), TRF2, and matriptase 2. Mutations in DMT1 and matriptase-2 cause iron deficiency; mutations in FPN, HFE, and TRF2 cause iron excess. Intracellular iron homeostasis depends on coordinated regulation of iron trafficking and storage proteins encoded in iron responsive element (IRE)-mRNA. The noncoding IRE-mRNA structures bind protein repressors, IRP1 or 2, during iron deficiency. Integration of the IRE-RNA in translation regulators (near the cap) or turnover elements (after the coding region) increases iron uptake (DMT1/TRF1) or decreases iron storage/efflux (FTN/FPN) when IRP binds. An antioxidant response element in FTN DNA binds Bach1, a heme-sensitive transcription factor that coordinates expression among antioxidant response proteins like FTN, thioredoxin reductase, and quinone reductase. FTN, an antioxidant because Fe2+ and O2 (reactive oxygen species generators) are consumed to make iron mineral, is also a nutritional iron concentrate that is an efficiently absorbed, nonheme source of iron from whole legumes. FTN protein cages contain thousands of mineralized iron atoms and enter cells by receptor-mediated endocytosis, an absorption mechanism distinct from transport of nonheme iron salts (ferrous sulfate), iron chelators (ferric-EDTA), or heme. Recognition of 2 nutritional nonheme iron sources, small and large (FTN), will aid the solution of iron deficiency, a major public health problem, and the development of new policies on iron nutrition. PMID:21346101

Bioavailable iron in the Southern Ocean: the significance of the iceberg conveyor belt.

PubMed

Raiswell, Rob; Benning, Liane G; Tranter, Martyn; Tulaczyk, Slawek

2008-05-30

Productivity in the Southern Oceans is iron-limited, and the supply of iron dissolved from aeolian dust is believed to be the main source from outside the marine reservoir. Glacial sediment sources of iron have rarely been considered, as the iron has been assumed to be inert and non-bioavailable. This study demonstrates the presence of potentially bioavailable Fe as ferrihydrite and goethite in nanoparticulate clusters, in sediments collected from icebergs in the Southern Ocean and glaciers on the Antarctic landmass. Nanoparticles in ice can be transported by icebergs away from coastal regions in the Southern Ocean, enabling melting to release bioavailable Fe to the open ocean. The abundance of nanoparticulate iron has been measured by an ascorbate extraction. This data indicates that the fluxes of bioavailable iron supplied to the Southern Ocean from aeolian dust (0.01-0.13 Tg yr(-1)) and icebergs (0.06-0.12 Tg yr(-1)) are comparable. Increases in iceberg production thus have the capacity to increase productivity and this newly identified negative feedback may help to mitigate fossil fuel emissions.

Magnetic conveyor belt for transporting and merging trapped atom clouds.

PubMed

Hänsel, W; Reichel, J; Hommelhoff, P; Hänsch, T W

2001-01-22

We demonstrate an integrated magnetic device which transports cold atoms near a surface with very high positioning accuracy. Time-dependent currents in a lithographic conductor pattern create a moving chain of potential wells; atoms are transported in these wells while remaining confined in all three dimensions. We achieve mean fluxes up to 10(6) s(-1) with a negligible heating rate. An extension of this device allows merging of atom clouds by unification of two Ioffe-Pritchard potentials. The unification, which we demonstrate experimentally, can be performed without loss of phase space density. This novel, all-magnetic atom manipulation offers exciting perspectives, such as trapped-atom interferometry.

Zeeman relaxation of cold atomic iron and nickel in collisions with He3

NASA Astrophysics Data System (ADS)

Johnson, Cort; Newman, Bonna; Brahms, Nathan; Doyle, John M.; Kleppner, Daniel; Greytak, Thomas J.

2010-06-01

We have measured the ratio γ of the diffusion cross section to the angular momentum reorientation cross section in the colliding Fe-He3 and Ni-He3 systems. Nickel (Ni) and iron (Fe) atoms are introduced via laser ablation into a cryogenically cooled experimental cell containing cold (<1 K) He3 buffer gas. Elastic collisions rapidly cool the translational temperature of the ablated atoms to the He3 temperature. γ is extracted by measuring the decays of the atomic Zeeman sublevels. For our experimental conditions, thermal energy is comparable to the Zeeman splitting. As a result, thermal excitations between Zeeman sublevels significantly impact the observed decay. To determine γ accurately, we introduce a model of Zeeman-state dynamics that includes thermal excitations. We find γNi-3He=5×103 and γFe-3He⩽3×103 at 0.75 K in a 0.8-T magnetic field. These measurements are interpreted in the context of submerged shell suppression of spin relaxation, as studied previously in transition metals and rare-earth-metal atoms [C. I. Hancox, S. C. Doret, M. T. Hummon, R. V. Krems, and J. M. Doyle, Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.94.013201 94, 013201 (2005); C. I. Hancox, S. C. Doret, M. T. Hummon, L. Luo, and J. M. Doyle, Nature (London)NATUAS0028-083610.1038/nature02938 431, 281 (2004); A. Buchachenko, G. Chaasiski, and M. Szczniak, Eur. Phys. J. DEPJDF61434-606010.1140/epjd/e2006-00263-3 45, 147 (2007)].

30 CFR 75.1731 - Maintenance of belt conveyors and belt conveyor entries.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Maintenance of belt conveyors and belt conveyor....1731 Maintenance of belt conveyors and belt conveyor entries. (a) Damaged rollers, or other damaged belt conveyor components, which pose a fire hazard must be immediately repaired or replaced. All other...

Effectiveness of Ford's belt reminder system in increasing seat belt use

PubMed Central

Williams, A; Wells, J; Farmer, C

2002-01-01

Objectives: The study investigated the effectiveness in increasing seat belt use of Ford's belt reminder system, a supplementary system that provides intermittent flashing lights and chimes for five minutes if drivers are not belted. Methods: Seat belt use of drivers in relatively new cars with and without the reminder system was unobtrusively observed as vehicles were brought to dealerships for service. Results: Overall use rates were estimated at 71% for drivers in vehicles without the reminder system and 76% for drivers in vehicles with belt reminders (p<0.01). Conclusions: Seat belt use is relatively low in the United States. The present study showed that vehicle based reminder systems can be at least modestly effective in increasing belt use, which may encourage further development of such systems. PMID:12460965

Effect of Thermospheric Neutral Density upon Inner Trapped-belt Proton Flux

NASA Technical Reports Server (NTRS)

Wilson, Thomas L.; Lodhi, M. A. K.; Diaz, Abel B.

2007-01-01

We wish to point out that a secular change in the Earth's atmospheric neutral density alters charged-particle lifetime in the inner trapped radiation belts, in addition to the changes recently reported as produced by greenhouse gases. Heretofore, changes in neutral density have been of interest primarily because of their effect on the orbital drag of satellites. We extend this to include the orbital lifetime of charged particles in the lower radiation belts. It is known that the charged-belt population is coupled to the neutral density of the atmosphere through changes induced by solar activity, an effect produced by multiple scattering off neutral and ionized atoms along with ionization loss in the thermosphere where charged and neutral populations interact. It will be shown here that trapped-belt flux J is bivariant in energy E and thermospheric neutral density , as J(E,rho). One can conclude that proton lifetimes in these belts are also directly affected by secular changes in the neutral species populating the Earth s thermosphere. This result is a consequence of an intrinsic property of charged-particle flux, that flux is not merely a function of E but is dependent upon density rho when a background of neutrals is present.

Condition-Based Conveyor Belt Replacement Strategy in Lignite Mines with Random Belt Deterioration

NASA Astrophysics Data System (ADS)

Blazej, Ryszard; Jurdziak, Leszek

2017-12-01

In Polish lignite surface mines, condition-based belt replacement strategies are applied in order to assure profitable refurbishment of worn out belts performed by external firms specializing in belt maintenance. In two of three lignite mines, staff asses belt condition subjectively during visual inspections. Only one mine applies specialized diagnostic device (HRDS) allowing objective magnetic evaluation of belt core condition in order to choose the most profitable moment for the dismantling of worn out belt segments from conveyors and sending them to the maintenance firm which provides their refurbishment. This article describes the advantages of a new diagnostic device called DiagBelt. It was developed at the Faculty of Geoengineering, Mining and Geology, Wroclaw University of Science and Technology. Economic gains from its application are calculated for the lignite mine and for the belt maintenance firm, taking into account random life (durability) of new and reconditioned belts (after the 1st and the 2nd refurbishment). Recursive calculations for following years allow the estimation of the length and costs of replaced, reconditioned and purchased belts on an annual basis, while the use of the Monte Carlo method allows the estimation of their variability caused by random deterioration of belts. Savings are obtained due to better selection of moments (times) for the replacement of belt segments and die to the possibility to qualify worn out belts for refurbishment without the need to remove their covers. In effect, increased belt durability and lowered share of waste belts (which were not qualified for reconditioning) create savings which can quickly cover expenditures on new diagnostic tools and regular belt inspections in the mine.

Iron-based amorphous alloys and methods of synthesizing iron-based amorphous alloys

DOEpatents

Saw, Cheng Kiong; Bauer, William A.; Choi, Jor-Shan; Day, Dan; Farmer, Joseph C.

2016-05-03

A method according to one embodiment includes combining an amorphous iron-based alloy and at least one metal selected from a group consisting of molybdenum, chromium, tungsten, boron, gadolinium, nickel phosphorous, yttrium, and alloys thereof to form a mixture, wherein the at least one metal is present in the mixture from about 5 atomic percent (at %) to about 55 at %; and ball milling the mixture at least until an amorphous alloy of the iron-based alloy and the at least one metal is formed. Several amorphous iron-based metal alloys are also presented, including corrosion-resistant amorphous iron-based metal alloys and radiation-shielding amorphous iron-based metal alloys.

Bio-mimicked atomic-layer-deposited iron oxide-based memristor with synaptic potentiation and depression functions

NASA Astrophysics Data System (ADS)

Wan, Xiang; Gao, Fei; Lian, Xiaojuan; Ji, Xincun; Hu, Ertao; He, Lin; Tong, Yi; Guo, Yufeng

2018-06-01

In this study, an iron oxide (FeO x )-based memristor was investigated for the realization of artificial synapses. An FeO x resistive switching layer was prepared by self-limiting atomic layer deposition (ALD). The movement of oxygen vacancies enabled the device to have history-dependent synaptic functions, which was further demonstrated by device modeling and simulation. Analog synaptic potentiation/depression in conductance was emulated by applying consecutive voltage pulses in the simulation. Our results suggest that the ALD FeO x -based memristor can be used as the basic building block for neural networks, neuromorphic systems, and brain-inspired computers.

ON THE EFFECT OF GIANT PLANETS ON THE SCATTERING OF PARENT BODIES OF IRON METEORITE FROM THE TERRESTRIAL PLANET REGION INTO THE ASTEROID BELT: A CONCEPT STUDY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haghighipour, Nader; Scott, Edward R. D., E-mail: nader@ifa.hawaii.edu

2012-04-20

In their model for the origin of the parent bodies of iron meteorites, Bottke et al. proposed differentiated planetesimals, formed in 1-2 AU during the first 1.5 Myr, as the parent bodies, and suggested that these objects and their fragments were scattered into the asteroid belt as a result of interactions with planetary embryos. Although viable, this model does not include the effect of a giant planet that might have existed or been growing in the outer regions. We present the results of a concept study where we have examined the effect of a planetary body in the orbit ofmore » Jupiter on the early scattering of planetesimals from the terrestrial region into the asteroid belt. We integrated the orbits of a large battery of planetesimals in a disk of planetary embryos and studied their evolutions for different values of the mass of the planet. Results indicate that when the mass of the planet is smaller than 10 M{sub Circled-Plus }, its effects on the interactions among planetesimals and planetary embryos are negligible. However, when the planet mass is between 10 and 50 M{sub Circled-Plus }, simulations point to a transitional regime with {approx}50 M{sub Circled-Plus} being the value for which the perturbing effect of the planet can no longer be ignored. Simulations also show that further increase of the mass of the planet strongly reduces the efficiency of the scattering of planetesimals from the terrestrial planet region into the asteroid belt. We present the results of our simulations and discuss their possible implications for the time of giant planet formation.« less

Alteration mineral mapping for iron prospecting using ETM+ data, Tonkolili iron field, northern Sierra Leone

NASA Astrophysics Data System (ADS)

Mansaray, Lamin R.; Liu, Lei; Zhou, Jun; Ma, Zhimin

2013-10-01

The Tonkolili iron field in northern Sierra Leone has the largest known iron ore deposit in Africa. It occurs in a greenstone belt in an Achaean granitic basement. This study focused mainly on mapping areas with iron-oxide and hydroxyl bearing minerals, and identifying potential areas for haematite mineralization and banded iron formations (BIFs) in Tonkolili. The predominant mineral assemblage at the surface (laterite duricrust) of this iron field is haematitegoethite- limonite ±magnetite. The mineralization occurs in quartzitic banded ironstones, layered amphibolites, granites, schists and hornblendites. In this study, Crosta techniques were applied on Enhanced Thematic Mapper (ETM+) data to enhance areas with alteration minerals and target potential areas of haematite and BIF units in the Tonkolili iron field. Synthetic analysis shows that alteration zones mapped herein are consistent with the already discovered magnetite BIFs in Tonkolili. Based on the overlaps of the simplified geological map and the remote sensing-based alteration mineral maps obtained in this study, three new haematite prospects were inferred within, and one new haematite prospect was inferred outside the tenement boundary of the Tonkolili exploration license. As the primary iron mineral in Tonkolili is magnetite, the study concludes that, these haematite prospects could also be underlain by magnetite BIFs. This study also concludes that, the application of Crosta techniques on ETM+ data is effective not only in mapping iron-oxide and hydroxyl alterations but can also provide a basis for inferring areas of potential iron resources in Algoma-type banded iron formations (BIFs), such as those in the Tonkolili field.

Iron, ferritin, and nutrition.

PubMed

Theil, Elizabeth C

2004-01-01

Ferritin, a major form of endogenous iron in food legumes such as soybeans, is a novel and natural alternative for iron supplementation strategies where effectiveness is limited by acceptability, cost, or undesirable side effects. A member of the nonheme iron group of dietary iron sources, ferritin is a complex with Fe3+ iron in a mineral (thousands of iron atoms inside a protein cage) protected from complexation. Ferritin illustrates the wide range of chemical and biological properties among nonheme iron sources. The wide range of nonheme iron receptors matched to the structure of the iron complexes that occurs in microorganisms may, by analogy, exist in humans. An understanding of the chemistry and biology of each type of dietary iron source (ferritin, heme, Fe2+ ion, etc.), and of the interactions dependent on food sources, genes, and gender, is required to design diets that will eradicate global iron deficiency in the twenty-first century.

Colorimetric and atomic absorption spectrometric determination of mucolytic drug ambroxol through ion-pair formation with iron and thiocyanate.

PubMed

Levent, Abdulkadir; Sentürk, Zühre

2010-09-01

Colorimetric and atomic absorption spectrometric methods have been developed for the determination of mucolytic drug Ambroxol. These procedures depend upon the reaction of iron(III) metal ion with the drug in the presence of thiocyanate ion to form stable ion-pair complex which extractable chloroform. The red-coloured complex was determined either colorimetrically at 510 nm or by indirect atomic absorption spectrometry (AAS) via the determination of the iron content in the formed complex. The optimum experimental conditions for pH, concentrations of Fe(3+) and SCN(-), shaking time, phase ratio, and the number of extractions were determined. Under the proposed conditions, linearity was obeyed in the concentration ranges 4.1x10(-6) - 5.7x10(-5) M (1.7-23.6 µg mL(-1)) using both methods, with detection limits of 4.6x10(-7) M (0.19 µg mL(-1)) for colorimetry and 1.1x10(-6) M (0.46 µg mL(-1)) for AAS. The proposed methods were applied for the determination of Ambroxol in tablet dosage forms. The results obtained were statistically analyzed and compared with those obtained by applying the high-performance liquid chromatographic method with diode-array detection.

Atomic-Scale Design of Iron Fischer-Tropsch Catalysts: A Combined Computational Chemistry, Experimental, and Microkinetic Modeling Approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manos Mavrikakis; James A. Dumesic; Amit A. Gokhale

2006-03-03

Efforts during this second year focused on four areas: (1) continued searching and summarizing of published Fischer-Tropsch synthesis (FTS) mechanistic and kinetic studies of FTS reactions on iron catalysts; (2) investigation of CO adsorption/desorption and temperature programmed hydrogenation (TPH) of carbonaceous species after FTS on unsupported iron and alumina-supported iron catalysts; (3) activity tests of alumina-supported iron catalysts in a fixed bed reactor; (4) sequential design of experiments, for the collection of rate data in a Berty CSTR reactor, and nonlinear-regression analysis to obtain kinetic parameters. Literature sources describing mechanistic and kinetic studies of Fischer-Tropsch synthesis on iron catalysts weremore » compiled in a review. Temperature-programmed desorption/reaction methods (the latter using mass-spectrometry detection and also thermogravimetric analyzer (TGA)) were utilized to study CO adsorption/-desorption on supported and unsupported iron catalysts. Molecular and dissociative adsorptions of CO occur on iron catalysts at 25-150 C. The amounts adsorbed and bond strengths of adsorption are influenced by supports and promoters. That CO adsorbs dissociatively on polycrystalline Fe at temperatures well below those of FT reaction indicates that CO dissociation is facile and unlikely to be the rate-limiting step during FTS. Carbonaceous species formed after FT reaction for only 5 minutes at 200 C were initially hydrogenated under mild, isothermal condition (200 C and 1 atm), followed by TPH to 800 C. During the mild, isothermal hydrogenation, only about 0.1-0.2 mL of atomic carbon is apparently removed, while during TPH to 800 C multilayer equivalents of atomic, polymeric, carbidic, and graphitic carbons are removed. Rates of CO conversion on alumina-supported iron catalysts at 220-260 C and 20 atm are correlated well by a Langmuir-Hinshelwood expression, derived assuming carbon hydrogenation to CH and OH recombination to water

Ferritin accumulation under iron scarcity in Drosophila iron cells.

PubMed

Mehta, A; Deshpande, A; Bettedi, L; Missirlis, F

2009-10-01

Ferritins are highly stable, multi-subunit protein complexes with iron-binding capacities that reach 4500 iron atoms per ferritin molecule. The strict dependence of cellular physiology on an adequate supply of iron cofactors has likely been a key driving force in the evolution of ferritins as iron storage molecules. The insect intestine has long been known to contain cells that are responsive to dietary iron levels and a specialized group of "iron cells" that always accumulate iron-loaded ferritin, even when no supplementary iron is added to the diet. Here, we further characterize ferritin localization in Drosophila melanogaster larvae raised under iron-enriched and iron-depleted conditions. High dietary iron intake results in ferritin accumulation in the anterior midgut, but also in garland (wreath) cells and in pericardial cells, which together filter the circulating hemolymph. Ferritin is also abundant in the brain, where levels remain unaltered following dietary iron chelation, a treatment that depletes ferritin from the aforementioned tissues. We attribute the stability of ferritin levels in the brain to the function of the blood-brain barrier that may shield this organ from systemic iron fluctuations. Most intriguingly, our dietary manipulations demonstrably iron-depleted the iron cells without a concomitant reduction in their production of ferritin. Therefore, insect iron cells may constitute an exception from the evolutionary norm with respect to iron-dependent ferritin regulation. It will be of interest to decipher both the physiological purpose served and the mechanism employed to untie ferritin regulation from cellular iron levels in this cell type.

Storm-time radiation belt electron dynamics: Repeatability in the outer radiation belt

NASA Astrophysics Data System (ADS)

Murphy, K. R.; Mann, I. R.; Rae, J.; Watt, C.; Boyd, A. J.; Turner, D. L.; Claudepierre, S. G.; Baker, D. N.; Spence, H. E.; Reeves, G. D.; Blake, J. B.; Fennell, J. F.

2017-12-01

During intervals of enhanced solar wind driving the outer radiation belt becomes extremely dynamic leading to geomagnetic storms. During these storms the flux of energetic electrons can vary by over 4 orders of magnitude. Despite recent advances in understanding the nature of competing storm-time electron loss and acceleration processes the dynamic behavior of the outer radiation belt remains poorly understood; the outer radiation belt can exhibit either no change, an enhancement, or depletion in radiation belt electrons. Using a new analysis of the total radiation belt electron content, calculated from the Van Allen probes phase space density (PSD), we statistically analyze the time-dependent and global response of the outer radiation belt during storms. We demonstrate that by removing adiabatic effects there is a clear and repeatable sequence of events in storm-time radiation belt electron dynamics. Namely, the relativistic (μ=1000 MeV/G) and ultra-relativistic (μ=4000 MeV/G) electron populations can be separated into two phases; an initial phase dominated by loss followed by a second phase dominated by acceleration. At lower energies, the radiation belt seed population of electrons (μ=150 MeV/G) shows no evidence of loss but rather a net enhancement during storms. Further, we investigate the dependence of electron dynamics as a function of the second adiabatic invariant, K. These results demonstrate a global coherency in the dynamics of the source, relativistic and ultra-relativistic electron populations as function of the second adiabatic invariant K. This analysis demonstrates two key aspects of storm-time radiation belt electron dynamics. First, the radiation belt responds repeatably to solar wind driving during geomagnetic storms. Second, the response of the radiation belt is energy dependent, relativistic electrons behaving differently than lower energy seed electrons. These results have important implications in radiation belt research. In particular

Belt attachment and system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schneider, Abraham D.; Davidson, Erick M.

Disclosed herein is a belt assembly including a flexible belt with an improved belt attachment. The belt attachment includes two crossbars spaced along the length of the belt. The crossbars retain bearings that allow predetermined movement in six degrees of freedom. The crossbars are connected by a rigid body that attaches to the bearings. Implements that are attached to the rigid body are simply supported but restrained in pitching rotation.

Belt attachment and system

DOEpatents

Schneider, Abraham D.; Davidson, Erick M.

2016-02-02

Disclosed herein is a belt assembly including a flexible belt with an improved belt attachment. The belt attachment includes two crossbars spaced along the length of the belt. The crossbars retain bearings that allow predetermined movement in six degrees of freedom. The crossbars are connected by a rigid body that attaches to the bearings. Implements that are attached to the rigid body are simply supported but restrained in pitching rotation.

Iron Carbides in Fischer–Tropsch Synthesis: Theoretical and Experimental Understanding in Epsilon-Iron Carbide Phase Assignment

DOE PAGES

Liu, Xing-Wu; Cao, Zhi; Zhao, Shu; ...

2017-09-11

As active phases in low-temperature Fischer–Tropsch synthesis for liquid fuel production, epsilon iron carbides are critically important industrial materials. However, the precise atomic structure of epsilon iron carbides remains unclear, leading to a half-century of debate on the phase assignment of the ε-Fe 2C and ε’-Fe 2.2C. Here, we resolve this decades-long question by a combining theoretical and experimental investigation to assign the phases unambiguously. First, we have investigated the equilibrium structures and thermal stabilities of ε-Fe xC, (x = 1, 2, 2.2, 3, 4, 6, 8) by first-principles calculations. We have also acquired X-ray diffraction patterns and Mössbauer spectramore » for these epsilon iron carbides, and compared them with the simulated results. These analyses indicate that the unit cell of ε-Fe 2C contains only one type of chemical environment for Fe atoms, while ε’-Fe 2.2C has six sets of chemically distinct Fe atoms.« less

Binding of dinitrogen to an iron-sulfur-carbon site

NASA Astrophysics Data System (ADS)

Čorić, Ilija; Mercado, Brandon Q.; Bill, Eckhard; Vinyard, David J.; Holland, Patrick L.

2015-10-01

Nitrogenases are the enzymes by which certain microorganisms convert atmospheric dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher organisms. The most common nitrogenases reduce atmospheric N2 at the FeMo cofactor, a sulfur-rich iron-molybdenum cluster (FeMoco). The central iron sites that are coordinated to sulfur and carbon atoms in FeMoco have been proposed to be the substrate binding sites, on the basis of kinetic and spectroscopic studies. In the resting state, the central iron sites each have bonds to three sulfur atoms and one carbon atom. Addition of electrons to the resting state causes the FeMoco to react with N2, but the geometry and bonding environment of N2-bound species remain unknown. Here we describe a synthetic complex with a sulfur-rich coordination sphere that, upon reduction, breaks an Fe-S bond and binds N2. The product is the first synthetic Fe-N2 complex in which iron has bonds to sulfur and carbon atoms, providing a model for N2 coordination in the FeMoco. Our results demonstrate that breaking an Fe-S bond is a chemically reasonable route to N2 binding in the FeMoco, and show structural and spectroscopic details for weakened N2 on a sulfur-rich iron site.

49 CFR 393.93 - Seats, seat belt assemblies, and seat belt assembly anchorages.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 49 Transportation 5 2012-10-01 2012-10-01 false Seats, seat belt assemblies, and seat belt assembly anchorages. 393.93 Section 393.93 Transportation Other Regulations Relating to Transportation... § 393.93 Seats, seat belt assemblies, and seat belt assembly anchorages. (a) Buses—(1) Buses...

49 CFR 393.93 - Seats, seat belt assemblies, and seat belt assembly anchorages.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 5 2010-10-01 2010-10-01 false Seats, seat belt assemblies, and seat belt assembly anchorages. 393.93 Section 393.93 Transportation Other Regulations Relating to Transportation... § 393.93 Seats, seat belt assemblies, and seat belt assembly anchorages. (a) Buses—(1) Buses...

49 CFR 393.93 - Seats, seat belt assemblies, and seat belt assembly anchorages.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 5 2011-10-01 2011-10-01 false Seats, seat belt assemblies, and seat belt assembly anchorages. 393.93 Section 393.93 Transportation Other Regulations Relating to Transportation... § 393.93 Seats, seat belt assemblies, and seat belt assembly anchorages. (a) Buses—(1) Buses...

49 CFR 393.93 - Seats, seat belt assemblies, and seat belt assembly anchorages.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 49 Transportation 5 2014-10-01 2014-10-01 false Seats, seat belt assemblies, and seat belt assembly anchorages. 393.93 Section 393.93 Transportation Other Regulations Relating to Transportation... § 393.93 Seats, seat belt assemblies, and seat belt assembly anchorages. (a) Buses—(1) Buses...

49 CFR 393.93 - Seats, seat belt assemblies, and seat belt assembly anchorages.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 49 Transportation 5 2013-10-01 2013-10-01 false Seats, seat belt assemblies, and seat belt assembly anchorages. 393.93 Section 393.93 Transportation Other Regulations Relating to Transportation... § 393.93 Seats, seat belt assemblies, and seat belt assembly anchorages. (a) Buses—(1) Buses...

Missing Fe: hydrogenated iron nanoparticles

NASA Astrophysics Data System (ADS)

Bilalbegović, G.; Maksimović, A.; Mohaček-Grošev, V.

2017-03-01

Although it was found that the FeH lines exist in the spectra of some stars, none of the spectral features in the interstellar medium (ISM) have been assigned to this molecule. We suggest that iron atoms interact with hydrogen and produce Fe-H nanoparticles which sometimes contain many H atoms. We calculate infrared spectra of hydrogenated iron nanoparticles using density functional theory methods and find broad, overlapping bands. Desorption of H2 could induce spinning of these small Fe-H dust grains. Some of hydrogenated iron nanoparticles possess magnetic and electric moments and should interact with electromagnetic fields in the ISM. FenHm nanoparticles could contribute to the polarization of the ISM and the anomalous microwave emission. We discuss the conditions required to form FeH and FenHm in the ISM.

Synaptic ribbon. Conveyor belt or safety belt?

PubMed

Parsons, T D; Sterling, P

2003-02-06

The synaptic ribbon in neurons that release transmitter via graded potentials has been considered as a conveyor belt that actively moves vesicles toward their release sites. But evidence has accumulated to the contrary, and it now seems plausible that the ribbon serves instead as a safety belt to tether vesicles stably in mutual contact and thus facilitate multivesicular release by compound exocytosis.

Ionic liquid-based extraction followed by graphite-furnace atomic absorption spectrometry for the determination of trace heavy metals in high-purity iron metal.

PubMed

Matsumiya, Hiroaki; Kato, Tatsuya; Hiraide, Masataka

2014-02-01

The analysis of high-purity materials for trace impurities is an important and challenging task. The present paper describes a facile and sensitive method for the determination of trace heavy metals in high-purity iron metal. Trace heavy metals in an iron sample solution were rapidly and selectively preconcentrated by the extraction into a tiny volume of an ionic liquid [1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide] for the determination by graphite-furnace atomic absorption spectrometry (GFAAS). A nitrogen-donating neutral ligand, 2,4,6-tris(2-pyridyl)-1,3,5-triazine (TPTZ), was found to be effective in the ionic liquid-based selective extraction, allowing the nearly complete (~99.8%) elimination of the iron matrix. The combination with the optimized GFAAS was successful. The detectability reached sub-μg g(-1) levels in iron metal. The novel use of TPTZ in ionic liquid-based extraction followed by GFAAS was successfully applied to the determination of traces of Co, Ni, Cu, Cd, and Pb in certified reference materials for high-purity iron metal. © 2013 Published by Elsevier B.V.

Comfort and convenience specifications for safety belts : shoulder belt fit, pressure and pullout forces

DOT National Transportation Integrated Search

1980-04-30

A three-part study was conducted to further define comfort requirements for seat belt systems with respect to shoulder belt fit, shoulder belt contact pressure, and 3-point restraint system pullout forces. Objective of the belt-fit portion of the stu...

The empty primordial asteroid belt.

PubMed

Raymond, Sean N; Izidoro, Andre

2017-09-01

The asteroid belt contains less than a thousandth of Earth's mass and is radially segregated, with S-types dominating the inner belt and C-types the outer belt. It is generally assumed that the belt formed with far more mass and was later strongly depleted. We show that the present-day asteroid belt is consistent with having formed empty, without any planetesimals between Mars and Jupiter's present-day orbits. This is consistent with models in which drifting dust is concentrated into an isolated annulus of terrestrial planetesimals. Gravitational scattering during terrestrial planet formation causes radial spreading, transporting planetesimals from inside 1 to 1.5 astronomical units out to the belt. Several times the total current mass in S-types is implanted, with a preference for the inner main belt. C-types are implanted from the outside, as the giant planets' gas accretion destabilizes nearby planetesimals and injects a fraction into the asteroid belt, preferentially in the outer main belt. These implantation mechanisms are simple by-products of terrestrial and giant planet formation. The asteroid belt may thus represent a repository for planetary leftovers that accreted across the solar system but not in the belt itself.

The empty primordial asteroid belt

PubMed Central

Raymond, Sean N.; Izidoro, Andre

2017-01-01

The asteroid belt contains less than a thousandth of Earth’s mass and is radially segregated, with S-types dominating the inner belt and C-types the outer belt. It is generally assumed that the belt formed with far more mass and was later strongly depleted. We show that the present-day asteroid belt is consistent with having formed empty, without any planetesimals between Mars and Jupiter’s present-day orbits. This is consistent with models in which drifting dust is concentrated into an isolated annulus of terrestrial planetesimals. Gravitational scattering during terrestrial planet formation causes radial spreading, transporting planetesimals from inside 1 to 1.5 astronomical units out to the belt. Several times the total current mass in S-types is implanted, with a preference for the inner main belt. C-types are implanted from the outside, as the giant planets’ gas accretion destabilizes nearby planetesimals and injects a fraction into the asteroid belt, preferentially in the outer main belt. These implantation mechanisms are simple by-products of terrestrial and giant planet formation. The asteroid belt may thus represent a repository for planetary leftovers that accreted across the solar system but not in the belt itself. PMID:28924609

Studies of implanted iron in silicon by channeling and Rutherford backscattering

NASA Technical Reports Server (NTRS)

Wang, P. W.; Cheng, H. S.; Gibson, W. M.; Corbett, J. W.

1986-01-01

Different amounts of 100-keV iron ions have been implanted into high-resistivity p-type FZ-silicon samples. The implantation damage, recovery of damage during various annealing periods and temperatures, movement of iron atoms under annealing and oxidation, and the kinds of defects created after implantation, annealing, or oxidation are all investigated by channeling and backscattering measurements. It is found that the critical fluence of 100-keV iron implanted into silicon at room temperature is about 2.5 x 10 to the 14th Fe/sq cm, and that iron atoms are gettered by silicon oxidation. In this supersaturated region, iron atoms diffuse slightly towards bulk silicon during high-temperature annealing (greater than or equal to 1100 C) but not at all during low-temperature annealing (less than or equal to 1000 C) in dry nitrogen ambient.

Safety belt laws and disparities in safety belt use among US high-school drivers.

PubMed

García-España, J Felipe; Winston, Flaura K; Durbin, Dennis R

2012-06-01

We compared reported safety belt use, for both drivers and passengers, among teenagers with learner's permits, provisional licenses, and unrestricted licenses in states with primary or secondary enforcement of safety belt laws. Our data source was the 2006 National Young Driver Survey, which included a national representative sample of 3126 high-school drivers. We used multivariate, log-linear regression analyses to assess associations between safety belt laws and belt use. Teenaged drivers were 12% less likely to wear a safety belt as drivers and 15% less likely to wear one as passengers in states with a secondary safety belt law than in states with a primary law. The apparent reduction in belt use among teenagers as they progressed from learner to unrestricted license holder occurred in only secondary enforcement states. Groups reporting particularly low use included African American drivers, rural residents, academically challenged students, and those driving pickup trucks. The results provided further evidence for enactment of primary enforcement provisions in safety belt laws because primary laws are associated with higher safety belt use rates and lower crash-related injuries and mortality.

Unveiling the high-activity origin of single-atom iron catalysts for oxygen reduction reaction.

PubMed

Yang, Liu; Cheng, Daojian; Xu, Haoxiang; Zeng, Xiaofei; Wan, Xin; Shui, Jianglan; Xiang, Zhonghua; Cao, Dapeng

2018-06-26

It is still a grand challenge to develop a highly efficient nonprecious-metal electrocatalyst to replace the Pt-based catalysts for oxygen reduction reaction (ORR). Here, we propose a surfactant-assisted method to synthesize single-atom iron catalysts (SA-Fe/NG). The half-wave potential of SA-Fe/NG is only 30 mV less than 20% Pt/C in acidic medium, while it is 30 mV superior to 20% Pt/C in alkaline medium. Moreover, SA-Fe/NG shows extremely high stability with only 12 mV and 15 mV negative shifts after 5,000 cycles in acidic and alkaline media, respectively. Impressively, the SA-Fe/NG-based acidic proton exchange membrane fuel cell (PEMFC) exhibits a high power density of 823 mW cm -2 Combining experimental results and density-functional theory (DFT) calculations, we further reveal that the origin of high-ORR activity of SA-Fe/NG is from the Fe-pyrrolic-N species, because such molecular incorporation is the key, leading to the active site increase in an order of magnitude which successfully clarifies the bottleneck puzzle of why a small amount of iron in the SA-Fe catalysts can exhibit extremely superior ORR activity.

Iron hydrides formation in interstellar clouds

NASA Astrophysics Data System (ADS)

Bar-Nun, A.; Pasternak, M.; Barrett, P. H.

1980-07-01

A recent Moessbauer study with Fe-57 in a solid hydrogen or hydrogen-argon matrix demonstrated the formation of an iron hydride molecule (FeH2) at 2.5-5 K. Following this and other studies, the possible existence of iron hydride molecules in interstellar clouds is proposed. In clouds, the iron hydrides FeH and FeH2 would be formed only on grains, by encounters of H atoms or H2 molecules with Fe atoms which are adsorbed on the grains. The other transition metals, Sc, Ti, V, Cr, Mn, Co, N, Cd and also Cu and Ca form hydrides of the type M-H, which could be responsible, at least in part, for the depletion of these metals in clouds.

Mineral resource assessment of the Iron River 1 degree x 2 degrees Quadrangle, Michigan and Wisconsin

USGS Publications Warehouse

Cannon, William F.

1983-01-01

The Iron River 1? x 2? quadrangle contains identified resources of copper and iron. Copper-rich shale beds in the north part of the quadrangle contain 12.2 billion pounds (5.5 billion kilograms) of copper in well-studied deposits including 9.2 billion pounds (4.2 billion kilograms) that are economically minable by 1980 standards. At least several billion pounds of copper probably exist in other parts of the same shale beds, but not enough data are available to measure the amount. A small amount, about 250 million pounds (113 million kilograms), of native copper is known to remain in one abandoned mine, and additional but unknown amounts remain in other abandoned mines. About 13.25 billion tons (12.02 billion metric tons) of banded iron-formation averaging roughly 30 percent iron are known within 500 feet (152.4 meters) of the surface in the Gogebic, Marquette, and Iron River-Crystal Falls districts. A small percentage of that might someday be minable as taconite, but none is now believed to be economic. Some higher grade iron concentrations exist in the same iron-formations. Such material was the basis of former mining of iron in the region, but a poor market for such ore and depletion of many deposits have led to the decline of iron mining in the quadrangle. Iron mines of the quadrangle were not being worked in 1980. Many parts of the quadrangle contain belts of favorable host rocks for mineral deposits. Although deposits are not known in these belts, undiscovered deposits of copper, zinc, lead, silver, uranium, phosphate, nickel, chromium, platinum, gold, and diamonds could exist.

Microstructure and properties of pure iron/copper composite cladding layers on carbon steel

NASA Astrophysics Data System (ADS)

Wan, Long; Huang, Yong-xian; Lü, Shi-xiong; Huang, Ti-fang; Lü, Zong-liang

2016-08-01

In the present study, pure iron/copper composite metal cladding was deposited onto carbon steel by tungsten inert gas welding. The study focused on interfacial morphological, microstructural, and mechanical analyses of the composite cladding layers. Iron liquid-solid-phase zones were formed at copper/steel and iron interfaces because of the melting of the steel substrate and iron. Iron concentrated in the copper cladding layer was observed to exhibit belt, globule, and dendrite morphologies. The appearance of iron-rich globules indicated the occurrence of liquid phase separation (LPS) prior to solidification, and iron-rich dendrites crystallized without the occurrence of LPS. The maximum microhardness of the iron/steel interface was lower than that of the copper/steel interface because of the diffusion of elemental carbon. All samples fractured in the cladding layers. Because of a relatively lower strength of the copper layer, a short plateau region appeared when shear movement was from copper to iron.

Synthesis and isolation of [Fe@Ge(10)](3-): a pentagonal prismatic Zintl ion cage encapsulating an interstitial iron atom.

PubMed

Zhou, Binbin; Denning, Mark S; Kays, Deborah L; Goicoechea, Jose M

2009-03-04

Reaction of an ethylenediamine (en) solution of the Zintl phase precursor K(4)Ge(9) with FeAr(2) (Ar = 2,6-Mes(2)C(6)H(3)) in the presence of 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) yielded the endohedral Zintl ion [Fe@Ge(10)](3-) (1) which was crystallographically characterized as a [K(2,2,2-crypt)](+) salt in [K(2,2,2-crypt)](3)[Fe@Ge(10)]*2en. This unprecedented Zintl ion exhibits a pentagonal prismatic 10-atom germanium cage with an interstitial iron atom in the central cavity. Confirmation of the existence of the cluster anion in solution was corroborated by positive and negative ion mode electrospray mass spectrometry.

belt law

DOT National Transportation Integrated Search

2007-03-01

A 2003 study estimated that if all States had primary seat belt laws from 1995 to 2002, over 12,000 lives would have been saved. Failure to implement a primary seat belt law creates a real cost to a States budget for Medicaid and other State medic...

Safety Belt Laws and Disparities in Safety Belt Use Among US High-School Drivers

PubMed Central

Winston, Flaura K.; Durbin, Dennis R.

2012-01-01

Objectives. We compared reported safety belt use, for both drivers and passengers, among teenagers with learner’s permits, provisional licenses, and unrestricted licenses in states with primary or secondary enforcement of safety belt laws. Methods. Our data source was the 2006 National Young Driver Survey, which included a national representative sample of 3126 high-school drivers. We used multivariate, log-linear regression analyses to assess associations between safety belt laws and belt use. Results. Teenaged drivers were 12% less likely to wear a safety belt as drivers and 15% less likely to wear one as passengers in states with a secondary safety belt law than in states with a primary law. The apparent reduction in belt use among teenagers as they progressed from learner to unrestricted license holder occurred in only secondary enforcement states. Groups reporting particularly low use included African American drivers, rural residents, academically challenged students, and those driving pickup trucks. Conclusions. The results provided further evidence for enactment of primary enforcement provisions in safety belt laws because primary laws are associated with higher safety belt use rates and lower crash-related injuries and mortality. PMID:22515851

[Determination of trace lead and iron in nickel chloride and manganese sulfate by flame atomic absorption spectrometry after coprecipitation with yttrium phosphate].

PubMed

Su, Yao-Dong; Zhu, Wen-Ying; Ma, Hong-Mei; Chen, Long-Wu

2006-09-01

Using yttrium phosphate as the coprecipitation collector for the separation and preconcentration of trace lead and iron in nickel chloride and manganese sulfate, flame atomic absorption spectrometric (FAAS) determination was described in the present paper. Coprecipitation parameters including the pH of the solution, and the amounts of YCl3 and H3 PO4 were discussed. It was found that lead and iron in nickel chloride could be coprecipitated quantitatively in the range of pH 3.0-4.0, and so could be lead in manganese sulfate. The detection limits (3sigma) of lead and iron in 20 mL solution were 1.63 x 10(-2) mg x L(-1) and 4.58 x 10(-2) mg x L(-1) respectively. In NiCl2 solution the standard addition recoveries for lead and iron were 100.91% and 99.73% respectively, and in MnSO4 solution the standard addition recoveries were 99.45% and 98.98% respectively. The method has eliminated the interference of matrix, and the result is satisfied.

Arsenic in groundwaters in the Northern Appalachian Mountain belt: A review of patterns and processes

NASA Astrophysics Data System (ADS)

Peters, Stephen C.

2008-07-01

Naturally occurring arsenic in the bedrock of the Northern Appalachian Mountain belt was first recognized in the late 19th century. The knowledge of the behavior of arsenic in groundwater in this region has lagged behind nearly a century, with the popular press reporting on local studies in the early 1980s, and most peer-reviewed research articles on regional patterns conducted and written in the late 1990s and early 2000s. Research reports have shown that within this high arsenic region, between 6% and 22% of households using private drinking water wells contain arsenic in excess of 10 µg/L, the United States Environmental Protection Agency's maximum contaminant level. In nearly all reports, arsenic in drinking water was derived from naturally occurring geologic sources, typically arsenopyrite, substituted sulfides such as arsenian pyrite, and nanoscale minerals such as westerveldite. In most studies, arsenic concentrations in groundwater were controlled by pH dependent adsorption to mineral surfaces, most commonly iron oxide minerals. In some cases, reductive dissolution of iron minerals has been shown to increase arsenic concentrations in groundwater, more commonly associated with anthropogenic activities such as landfills. Evidence of nitrate reduction promoting the presence of arsenic(V) and iron(III) minerals in anoxic environments has been shown to occur in surface waters, and in this manuscript we show this process perhaps applies to groundwater. The geologic explanation for the high arsenic region in the Northern Appalachian Mountain belt is most likely the crustal recycling of arsenic as an incompatible element during tectonic activity. Accretion of multiple terranes, in particular Avalonia and the Central Maine Terrane of New England appear to be connected to the presence of high concentrations of arsenic. Continued tectonic activity and recycling of these older terranes may also be responsible for the high arsenic observed in the Triassic rift basins

Iron alteration minerals in the visible and near-infrared spectra of low-albedo asteroids

NASA Technical Reports Server (NTRS)

Vilas, Faith; Jarvis, Kandy S.; Gaffey, Michael J.

1994-01-01

Absorption features centered near 0.60-0.65 and 0.80-0.90 micrometers have been identified in the spectra of five low-albedo main-belt and outer-belt asteroids. These absorption features are attributed respectively to the (6)A(sub 1) goes to (4)T(sub 2)(G) and (6)A(sub 1) goes to (4)T(sub 1)(G) charge transfer transitions in minerals such as goethite, hematite, and jarosite that are products of the aqueous alteration of anhydrous silicates. A shoulder near 0.63 micrometers has also been identified in the absorption feature centered near 0.7 micrometers attributed to oxidized iron in phyllosilicates found predominantly in C- and G-class asteroids reflectance spectra. The coexistence of iron oxides with phyllosilicates in asteroids believed to have undergone aqueous alteration would be expected based upon analogy with terrestrial aqueous alteration and the observed mineralogy of carbonaceous chondrites. The number of low-albedo asteroids having only iron alteration absorption features compared to the number of low-albedo asteroids having spectral characteristics indicative of phyllosilicates is small. Either the conditions under which these asteroids formed are rare, or the iron alteration minerals could be formed in the interiors of objects where phyllosilicates dominate the surface mineralogy.

Belt conveyor apparatus

DOEpatents

Oakley, David J.; Bogart, Rex L.

1987-01-01

A belt conveyor apparatus according to this invention defines a conveyance path including a first pulley and at least a second pulley. An endless belt member is adapted for continuous travel about the pulleys and comprises a lower portion which engages the pulleys and an integral upper portion adapted to receive objects therein at a first location on said conveyance path and transport the objects to a second location for discharge. The upper belt portion includes an opposed pair of longitudinally disposed crest-like members, biased towards each other in a substantially abutting relationship. The crest-like members define therebetween a continuous, normally biased closed, channel along the upper belt portion. Means are disposed at the first and second locations and operatively associated with the belt member for urging the normally biased together crest-like members apart in order to provide access to the continuous channel whereby objects can be received into, or discharged from the channel. Motors are in communication with the conveyance path for effecting the travel of the endless belt member about the conveyance path. The conveyance path can be configured to include travel through two or more elevations and one or more directional changes in order to convey objects above, below and/or around existing structures.

Comparison of colorimetry and electrothermal atomic absorption spectroscopy for the quantification of non-transferrin bound iron in human sera.

PubMed

Jittangprasert, Piyada; Wilairat, Prapin; Pootrakul, Pensri

2004-12-01

This paper describes a comparison of two analytical techniques, one employing bathophenanthrolinedisulfonate (BPT), a most commonly-used reagent for Fe (II) determination, as chromogen and an electrothermal atomic absorption spectroscopy (ETAAS) for the quantification of non-transferrin bound iron (NTBI) in sera from thalassemic patients. Nitrilotriacetic acid (NTA) was employed as the ligand for binding iron from low molecular weight iron complexes present in the serum but without removing iron from the transferrin protein. After ultrafiltration the Fe (III)-NTA complex was then quantified by both methods. Kinetic study of the rate of the Fe (II)-BPT complex formation for various excess amounts of NTA ligand was also carried out. The kinetic data show that a minimum time duration (> 60 minutes) is necessary for complete complex formation when large excess of NTA is used. Calibration curves given by colorimetric and ETAAS methods were linear over the range of 0.15-20 microM iron (III). The colorimetric and ETAAS methods exhibited detection limit (3sigma) of 0.13 and 0.14 microM, respectively. The NTBI concentrations from 55 thalassemic serum samples measured employing BPT as chromogen were statistically compared with the results determined by ETAAS. No significant disagreement at 95% confidence level was observed. It is, therefore, possible to select any one of these two techniques for determination of NTBI in serum samples of thalassemic patients. However, the colorimetric procedure requires a longer analysis time because of a slow rate of exchange of NTA ligand with BPT, leading to the slow rate of formation of the colored complex.

Moving belt radiator development status

NASA Technical Reports Server (NTRS)

White, K. Alan

1988-01-01

Development of the Moving Belt Radiator (MBR) as an advanced space radiator concept is discussed. The ralative merits of Solid Belt (SBR), Liquid Belt (LBR), and Hybrid Belt (HBR) Radiators are described. Analytical and experimental efforts related to the dynamics of a rotating belt in microgravity are reviewed. The development of methods for transferring heat to the moving belt is discussed, and the results from several experimental investigations are summarized. Limited efforts related to the belt deployment and stowage, and to fabrication of a hybrid belt, are also discussed. Life limiting factors such as seal wear and micrometeroid resistance are identified. The results from various MBR point design studies for several power levels are compared with advanced Heat Pipe Radiator technology. MBR designs are shown to compare favorable at both 300 and 1000 K temperature levels. However, additional effort will be required to resolve critical technology issues and to demonstrate the advantage of MBR systems.

A Red Carpet for Iron Metabolism

PubMed Central

Muckenthaler, Martina U.; Rivella, Stefano; Hentze, Matthias W.; Galy, Bruno

2017-01-01

200 billion red blood cells (RBCs) are produced every day, requiring more than 2 × 3 1015 iron atoms every second to maintain adequate erythropoiesis. These numbers translate into 20 mL of blood being produced each day, containing 6 g of hemoglobin and 20 mg of iron. These impressive numbers illustrate why the making and breaking of RBCs is at the heart of iron physiology, providing an ideal context to discuss recent progress in understanding the systemic and cellular mechanisms that underlie the regulation of iron homeostasis and its disorders. PMID:28129536

Comparison of the quantitative analysis performance between pulsed voltage atom probe and pulsed laser atom probe.

PubMed

Takahashi, J; Kawakami, K; Raabe, D

2017-04-01

The difference in quantitative analysis performance between the voltage-mode and laser-mode of a local electrode atom probe (LEAP3000X HR) was investigated using a Fe-Cu binary model alloy. Solute copper atoms in ferritic iron preferentially field evaporate because of their significantly lower evaporation field than the matrix iron, and thus, the apparent concentration of solute copper tends to be lower than the actual concentration. However, in voltage-mode, the apparent concentration was higher than the actual concentration at 40K or less due to a detection loss of matrix iron, and the concentration decreased with increasing specimen temperature due to the preferential evaporation of solute copper. On the other hand, in laser-mode, the apparent concentration never exceeded the actual concentration, even at lower temperatures (20K), and this mode showed better quantitative performance over a wide range of specimen temperatures. These results indicate that the pulsed laser atom probe prevents both detection loss and preferential evaporation under a wide range of measurement conditions. Copyright © 2017 Elsevier B.V. All rights reserved.

Seismic crustal structure of the Limpopo mobile belt, Zimbabwe

NASA Astrophysics Data System (ADS)

Stuart, G. W.; Zengeni, T. G.

1987-12-01

A 145 km N-S seismic traverse was deployed to determine the crustal structure of the Limpopo mobile belt in southern Zimbabwe and the nature of its northern boundary with the Zimbabwean craton. Rockbursts from South African gold mines to the south and regional seismicity from the Kariba-South Zambia belt to the north were used as seismic sources. P-wave relative teleseismic residuals were also measured to assess whether any velocity contrast between the craton and the mobile belt extended into the upper mantle. Interpretation of reduced travel times from the local Buchwa iron-ore mine blasts, which were broadside to the traverse, revealed an upper crustal interface in the Limpopo mobile belt at a depth of 5.8 ± 0.6 km, dividing material with a velocity of about 5.8 km/s from that of about 6.4 km/s. On the craton, arrivals from the same source showed a 4.4 ± 0.5 km thick 5.5 km/s layer overlying crust of about velocity 6.5 km/s. P-wave arrivals from the regional seismicity were used to construct a crustal cross-section. Absolute crustal thickness was tentatively estimated from the identification of a Moho reflection on the mine blast recordings. To the south of Rutenga, the crust thins from around 34 km to 29 km in association with a positive gravity anomaly centred over the late-Karoo Nuanetsi Igneous Province and Karoo Tuli Syncline. North of Rutenga to the boundary with the Zimbabwean craton, the crust is about 34 km thick. The craton boundary was found to be a steeply southerly dipping zone associated with high-velocity material, which could either be deep-seated greenstones or mafic material associated with the margin in the region studied. This zone divides cratonic crust, which was found to be about 40 km thick, from that typical of the mobile belt and implies a step in the Moho of around 6 km. Analysis of relative teleseismic residuals showed that the velocity contrasts are not confined to the crust but extend into the uppermost upper mantle with the

Determination of silver in irons and steels by atomic-absorption spectrometry with an induction furnace: Direct analysis of solid samples.

PubMed

Aziz-Alrahman, A M; Headridge, J B

1978-07-01

The silver contents of 17 irons and steels have been determined by dropping 0.5-20mg of millings or turnings of the metals into an induction furnace situated within an atomic-absorption spectrophotometer. The limit of detection was 0.005 mug/g and the relative standard deviations were 12% or better for silver contents of not less than 0.05 mug/g. Samples are added to the furnace at 4-5 min intervals.

Determining the Effect of Environmental Conditions on Iron Corrosion by Atomic Absorption

ERIC Educational Resources Information Center

Malel, Esteban; Shalev, Deborah E.

2013-01-01

Iron corrosion is a complex process that occurs when iron is exposed to oxygen and humidity and is exacerbated by the presence of chloride ions. The deterioration of iron structures or other components can be costly to society and is usually evaluated by following the properties of the corroding material. Here, the iron ions released into solution…

Iron ion and iron hydroxide adsorption to charge-neutral phosphatidylcholine templates

DOE PAGES

Wang, Wenjie; Zhang, Honghu; Feng, Shuren; ...

2016-07-13

Surface-sensitive X-ray scattering and spectroscopy techniques reveal significant adsorption of iron ions and iron-hydroxide (Fe(III)) complexes to a charge-neutral zwitterionic template of phosphatidylcholine (PC). The PC template is formed by a Langmuir monolayer of dipalmitoyl-PC (DPPC) that is spread on the surface of 2 to 40 μM FeCl 3 solutions at physiological levels of KCl (100 mM). At 40 μM of Fe(III) as many as ~3 iron atoms are associated with each PC group. Grazing incidence X-ray diffraction measurements indicate a significant disruption in the in-plane ordering of DPPC molecules upon iron adsorption. The binding of iron-hydroxide complexes to amore » neutral PC surface is yet another example of nonelectrostatic, presumably covalent bonding to a charge-neutral organic template. Furthermore, the strong binding and the disruption of in-plane lipid structure has biological implications on the integrity of PC-derived lipid membranes, including those based on sphingomyelin.« less

Strata-bound Fe-Co-Cu-Au-Bi-Y-REE deposits of the Idaho Cobalt Belt: Multistage hydrothermal mineralization in a magmatic-related iron oxide copper-gold system

USGS Publications Warehouse

Slack, John F.

2012-01-01

Mineralogical and geochemical studies of strata-bound Fe-Co-Cu-Au-Bi-Y-rare-earth element (REE) deposits of the Idaho cobalt belt in east-central Idaho provide evidence of multistage epigenetic mineralization by magmatic-hydrothermal processes in an iron oxide copper-gold (IOCG) system. Deposits of the Idaho cobalt belt comprise three types: (1) strata-bound sulfide lenses in the Blackbird district, which are cobaltite and, less commonly, chalcopyrite rich with locally abundant gold, native bismuth, bismuthinite, xenotime, allanite, monazite, and the Be-rich silicate gadolinite-(Y), with sparse uraninite, stannite, and Bi tellurides, in a gangue of quartz, chlorite, biotite, muscovite, garnet, tourmaline, chloritoid, and/or siderite, with locally abundant fluorapatite or magnetite; (2) discordant tourmalinized breccias in the Blackbird district that in places have concentrations of cobaltite, chalcopyrite, gold, and xenotime; and (3) strata-bound magnetite-rich lenses in the Iron Creek area, which contain cobaltiferous pyrite and locally sparse chalcopyrite or xenotime. Most sulfide-rich deposits in the Blackbird district are enclosed by strata-bound lenses composed mainly of Cl-rich Fe biotite; some deposits have quartz-rich envelopes.Whole-rock analyses of 48 Co- and/or Cu-rich samples show high concentrations of Au (up to 26.8 ppm), Bi (up to 9.16 wt %), Y (up to 0.83 wt %), ∑REEs (up to 2.56 wt %), Ni (up to 6,780 ppm), and Be (up to 1,180 ppm), with locally elevated U (up to 124 ppm) and Sn (up to 133 ppm); Zn and Pb contents are uniformly low (≤821 and ≤61 ppm, respectively). Varimax factor analysis of bulk compositions of these samples reveals geochemically distinct element groupings that reflect statistical associations of monazite, allanite, and xenotime; biotite and gold; detrital minerals; chalcopyrite and sparse stannite; quartz; and cobaltite with sparse selenides and tellurides. Significantly, Cu is statistically separate from Co and As

Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu

To significantly reduce the cost of proton exchange membrane (PEM) fuel cells, current Pt must be replaced by platinum-metal-group (PGM)-free catalysts for the oxygen reduction reaction (ORR) in acid. We report here a new class of high-performance atomic iron dispersed carbon catalysts through controlled chemical doping of iron ions into zinc-zeolitic imidazolate framework (ZIF), a type of metal-organic framework (MOF). The novel synthetic chemistry enables accurate size control of Fe-doped ZIF catalyst particles with a wide range from 20 to 1000 nm without changing chemical properties, which provides a great opportunity to increase the density of active sites that ismore » determined by the particle size. We elucidated the active site formation mechanism by correlating the chemical and structural changes with thermal activation process for the conversion from Fe-N4 complex containing hydrocarbon networks in ZIF to highly active FeNx sites embedded into carbon. A temperature of 800oC was identified as the critical point to start forming pyridinic nitrogen doping at the edge of the graphitized carbon planes. Further increasing heating temperature to 1100oC leads to increase of graphitic nitrogen, generating possible synergistic effect with FeNx sites to promote ORR activity. The best performing catalyst, which has well-defined particle size around 50 nm and abundance of atomic FeNx sites embedded into carbon structures, achieve a new performance milestone for the ORR in acid including a half-wave potential of 0.85 V vs RHE and only 20 mV loss after 10,000 cycles in O2 saturated H2SO4 electrolyte. The new class PGM-free catalyst with approaching activity to Pt holds great promise for future PEM fuel cells.« less

Atomic-scale investigation of point defects and hydrogen-solute atmospheres on the edge dislocation mobility in alpha iron

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhatia, M. A.; Solanki, K. N., E-mail: kiran.solanki@asu.edu; Groh, S.

2014-08-14

In this study, we present atomistic mechanisms of 1/2 [111](11{sup ¯}0) edge dislocation interactions with point defects (hydrogen and vacancies) and hydrogen solute atmospheres in body centered cubic (bcc) iron. In metals such as iron, increases in hydrogen concentration can increase dislocation mobility and/or cleavage-type decohesion. Here, we first investigate the dislocation mobility in the presence of various point defects, i.e., change in the frictional stress as the edge dislocation interacts with (a) vacancy, (b) substitutional hydrogen, (c) one substitutional and one interstitial hydrogen, (d) interstitial hydrogen, (e) vacancy and interstitial hydrogen, and (f) two interstitial hydrogen. Second, we examinemore » the role of a hydrogen-solute atmosphere on the rate of local dislocation velocity. The edge dislocation simulation with a vacancy in the compression side of the dislocation and an interstitial hydrogen atom at the tension side exhibit the strongest mechanical response, suggesting a higher potential barrier and hence, the higher frictional stress (i.e., ∼83% higher than the pure iron Peierls stress). In the case of a dislocation interacting with a vacancy on the compressive side, the vacancy binds with the edge dislocation, resulting in an increase in the friction stress of about 28% when compared with the Peierls stress of an edge dislocation in pure iron. Furthermore, as the applied strain increases, the vacancy migrates through a dislocation transportation mechanism by attaining a velocity of the same order as the dislocation velocity. For the case of the edge dislocation interacting with interstitial hydrogen on the tension side, the hydrogen atom jumps through one layer perpendicular to the glide plane during the pinning-unpinning process. Finally, our simulation of dislocation interactions with hydrogen show first an increase in the local dislocation velocity followed by a pinning of the dislocation core in the atmosphere, resulting in

Theoretical research program to predict the properties of molecules and clusters containing transition metal atoms

NASA Technical Reports Server (NTRS)

Walch, S.

1984-01-01

The primary focus of this research has been the theoretical study of transition metal (TM) chemistry. A major goal of this work is to provide reliable information about the interaction of H atoms with iron metal. This information is needed to understand the effect of H atoms on the processes of embrittlement and crack propagation in iron. The method in the iron hydrogen studies is the cluster method in which the bulk metal is modelled by a finite number of iron atoms. There are several difficulties in the application of this approach to the hydrogen iron system. First the nature of TM-TM and TM-H bonding for even diatomic molecules was not well understood when these studies were started. Secondly relatively large iron clusters are needed to provide reasonable results.

A technique for individual atom delivery into a crossed vortex bottle beam trap using a dynamic 1D optical lattice.

PubMed

Dinardo, Brad A; Anderson, Dana Z

2016-12-01

We describe a system for loading a single atom from a reservoir into a blue-detuned crossed vortex bottle beam trap using a dynamic 1D optical lattice. The lattice beams are frequency chirped using acousto-optic modulators, which causes the lattice to move along its axial direction and behave like an optical conveyor belt. A stationary lattice is initially loaded with approximately 6000 atoms from a reservoir, and the conveyor belt transports them 1.1 mm from the reservoir to a bottle beam trap, where a single atom is loaded via light-assisted collisions. Photon counting data confirm that an atom can be delivered and loaded into the bottle beam trap 13.1% of the time.

Epsilon Eridani Inner Asteroid Belt

NASA Image and Video Library

2017-09-14

SCI2017_0004: Artist's illustration of the Epsilon Eridani system showing Epsilon Eridani b, right foreground, a Jupiter-mass planet orbiting its parent star at the outside edge of an asteroid belt. In the background can be seen another narrow asteroid or comet belt plus an outermost belt similar in size to our solar system's Kuiper Belt. The similarity of the structure of the Epsilon Eridani system to our solar system is remarkable, although Epsilon Eridani is much younger than our sun. SOFIA observations confirmed the existence of the asteroid belt adjacent to the orbit of the Jovian planet. Credit: NASA/SOFIA/Lynette Cook

Continuous Mass Measurement on Conveyor Belt

NASA Astrophysics Data System (ADS)

Tomobe, Yuki; Tasaki, Ryosuke; Yamazaki, Takanori; Ohnishi, Hideo; Kobayashi, Masaaki; Kurosu, Shigeru

The continuous mass measurement of packages on a conveyor belt will become greatly important. In the mass measurement, the sequence of products is generally random. An interesting possibility of raising throughput of the conveyor line without increasing the conveyor belt speed is offered by the use of two or three conveyor belt scales (called a multi-stage conveyor belt scale). The multi-stage conveyor belt scale can be created which will adjust the conveyor belt length to the product length. The conveyor belt scale usually has maximum capacities of less than 80kg and 140cm, and achieves measuring rates of more than 150 packages per minute and more. The output signals from the conveyor belt scale are always contaminated with noises due to vibrations of the conveyor and the product to be measured in motion. In this paper an employed digital filter is of Finite Impulse Response (FIR) type designed under the consideration on the dynamics of the conveyor system. The experimental results on the conveyor belt scale suggest that the filtering algorithms are effective enough to practical applications to some extent.

Safety Belt Use: Traffic Safety Tips

DOT National Transportation Integrated Search

1996-01-01

This fact sheet, NHTSA Facts: Summer 1996, discusses traffic safety tips for wearing seat belts. It describes the correct way to wear a seat belt, how to sit, and differentiates between lap belts and shoulder belts. It points out that air bags provid...

Semiconductor composition containing iron, dysprosium, and terbium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pooser, Raphael C.; Lawrie, Benjamin J.; Baddorf, Arthur P.

An amorphous semiconductor composition includes 1 to 70 atomic percent iron, 15 to 65 atomic percent dysprosium, 15 to 35 atomic percent terbium, balance X, wherein X is at least one of an oxidizing element and a reducing element. The composition has an essentially amorphous microstructure, an optical transmittance of at least 50% in at least the visible spectrum and semiconductor electrical properties.

Use of seatbelts in cars with automatic belts.

PubMed Central

Williams, A F; Wells, J K; Lund, A K; Teed, N J

1992-01-01

Use of seatbelts in late model cars with automatic or manual belt systems was observed in suburban Washington, DC, Chicago, Los Angeles, and Philadelphia. In cars with automatic two-point belt systems, the use of shoulder belts by drivers was substantially higher than in the same model cars with manual three-point belts. This finding was true in varying degrees whatever the type of automatic belt, including cars with detachable nonmotorized belts, cars with detachable motorized belts, and especially cars with nondetachable motorized belts. Most of these automatic shoulder belts systems include manual lap belts. Use of lap belts was lower in cars with automatic two-point belt systems than in the same model cars with manual three-point belts; precisely how much lower could not be reliably estimated in this survey. Use of shoulder and lap belts was slightly higher in General Motors cars with detachable automatic three-point belts compared with the same model cars with manual three-point belts; in Hondas there was no difference in the rates of use of manual three-point belts and the rates of use of automatic three-point belts. PMID:1561301

Variational calculation of ground-state energy of iron atoms and condensed matter in strong magnetic fields. [at neutron star surfaces

NASA Technical Reports Server (NTRS)

Flowers, E. G.; Ruderman, M. A.; Lee, J.-F.; Sutherland, P. G.; Hillebrandt, W.; Mueller, E.

1977-01-01

Variational calculations of the binding energies of iron atoms and condensed matter in strong magnetic fields (greater than 10 to the 12th gauss). These calculations include the electron exchange energy. The cohesive energy of the condensed matter, which is the difference between these two binding energies, is of interest in pulsar theories and in the description of the surfaces of neutron stars. It is found that the cohesive energy ranges from 2.6 keV to 8.0 keV.

Evidence for solar wind origin of energetic heavy ions in the earth's radiation belt

NASA Technical Reports Server (NTRS)

Hovestadt, D.; Klecker, B.; Scholer, M.; Gloeckler, G.; Ipavich, F. M.; Fan, C. Y.; Fisk, L. A.; Ogallagher, J. J.

1978-01-01

Analysis of data from our energetic ion composition experiment on ISEE-1 has revealed the presence of substantial fluxes of carbon, oxygen, and heavier ions above 400 keV/nucleon at L values between approximately 2.5 and 4 earth radii. The measured C/O ratio varies systematically from 1.3 at 450 keV/nucleon to 4.1 at 1.3 MeV/nucleon, and no iron is observed above 200 keV/nucleon. These results provide strong evidence for a solar wind origin for energetic ions in the outer radiation belt. The absence of iron and the increase of the carbon-to-oxygen ratio with energy suggest that the condition for the validity of the first adiabatic invariant may have a strong influence on the trapping of these particles.

Belt separation system under slat in fattening pig housing: effect of belt type and extraction frequency.

PubMed

Alonso, F; Vázquez, J; Ovejero, I; Garcimartín, M A; Mateos, A; Sánchez, E

2010-08-01

The efficiency of manure separation by a conveyor belt under a partially slatted floor for fattening pigs was determined for two types of belts, a flat belt with an incline of up to 6 degrees transversely and a concave belt with an incline of up to 1 degrees longitudinally. A 31.20% and 23.75% dry matter content of the solid fraction was obtained for the flat and concave belt, respectively. The flat belt was more efficient at 6 degrees than other slope angles. The residence time of the manure on the two belt types influenced the separation efficiency from a live weight of 63.00 kg upwards. The quantity of residue produced with this system was reduced to 25-40% with respect to a pit system under slat. This could mean a remarkable reduction in costs of storage, transport and application of manure. (c) 2010 Elsevier Ltd. All rights reserved.

Electronic structure of ruthenium-doped iron chalcogenides

NASA Astrophysics Data System (ADS)

Winiarski, M. J.; Samsel-Czekała, M.; Ciechan, A.

2014-12-01

The structural and electronic properties of hypothetical RuxFe1-xSe and RuxFe1-xTe systems have been investigated from first principles within the density functional theory (DFT). Reasonable values of lattice parameters and chalcogen atomic positions in the tetragonal unit cell of iron chalcogenides have been obtained with the use of norm-conserving pseudopotentials. The well known discrepancies between experimental data and DFT-calculated results for structural parameters of iron chalcogenides are related to the semicore atomic states which were frozen in the used here approach. Such an approach yields valid results of the electronic structures of the investigated compounds. The Ru-based chalcogenides exhibit the same topology of the Fermi surface (FS) as that of FeSe, differing only in subtle FS nesting features. Our calculations predict that the ground states of RuSe and RuTe are nonmagnetic, whereas those of the solid solutions RuxFe1-xSe and RuxFe1-xTe become the single- and double-stripe antiferromagnetic, respectively. However, the calculated stabilization energy values are comparable for each system. The phase transitions between these magnetic arrangements may be induced by slight changes of the chalcogen atom positions and the lattice parameters a in the unit cell of iron selenides and tellurides. Since the superconductivity in iron chalcogenides is believed to be mediated by the spin fluctuations in single-stripe magnetic phase, the RuxFe1-xSe and RuxFe1-xTe systems are good candidates for new superconducting iron-based materials.

Measurement of Iron in Egg Yolk: An Instrumental Analysis Experiment Using Biochemical Principles

ERIC Educational Resources Information Center

Maloney, Kevin M.; Quiazon, Emmanuel M.; Indralingam, Ramee

2008-01-01

The generally accepted method to determine iron content in food is by acid digestion or dry ashing and subsequent flame atomic absorption spectrometry or inductively coupled plasma atomic emission spectrometry. We have developed an experiment that chemically extracts the iron from an egg yolk and quantifies it using UV-vis absorption…

Iberian Pyrite Belt Subsurface Life (IPBSL), a drilling project in a geochemical Mars terrestrial analogue

NASA Astrophysics Data System (ADS)

Amils, R.; Fernández-Remolar, D. C.; Parro, V.; Manfredi, J. A.; Timmis, K.; Oggerin, M.; Sánchez-Román, M.; López, F. J.; Fernández, J. P.; Omoregie, E.; Gómez-Ortiz, D.; Briones, C.; Gómez, F.; García, M.; Rodríguez, N.; Sanz, J. L.

2012-09-01

Iberian Pyrite Belt Subsurface Life (IPBSL) is a drilling project specifically designed to characterize the subsurface ecosystems operating in the Iberian Pyrite Belt (IPB), in the area of Peña de Hierro, and responsible of the extreme acidic conditions existing in the Rio Tinto basin [1]. Rio Tinto is considered a good geochemical terrestrial analogue of Mars [2, 3]. A dedicated geophysical characterization of the area selected two drilling sites (4) due to the possible existence of water with high ionic content (low resistivity). Two wells have been drilled in the selected area, BH11 and BH10, of depths of 340 and 620 meters respectively, with recovery of cores and generation of samples in anaerobic and sterile conditions. Preliminary results showed an important alteration of mineral structures associated with the presence of water, with production of expected products from the bacterial oxidation of pyrite (sulfates and ferric iron). Ion chromatography of water soluble compounds from uncontaminated samples showed the existence of putative electron donors (ferrous iron, nitrite in addition of the metal sulfides), electron acceptors (sulfate, nitrate, ferric iron) as well as variable concentration of metabolic organic acids (mainly acetate, formate, propionate and oxalate), which are strong signals of the presence of active subsurface ecosystem associated to the high sulfidic mineral content of the IPB. The system is driven by oxidants that appear to be provided by the rock matrix, only groundwater is needed to launch microbial metabolism. The geological, geomicrobiological and molecular biology analysis which are under way, should allow the characterization of this ecosystem of paramount interest in the design of an astrobiological underground Mars exploration mission in the near future.

Seat belt use on interstate highways.

PubMed Central

Wells, J K; Williams, A F; Lund, A K

1990-01-01

More than 5,000 miles of limited-access highways in the eastern United States and Canada were traveled to observe seat belt use. Overall belt use was 58 percent in the United States and 79 percent in Canada. The data indicate that belt use in the United States follows a different pattern on interstate highways than on other streets and roads, with relatively high belt use rates (over 50 percent) appearing to be somewhat independent of belt use law provisions. PMID:2343969

Atom-probe tomography and transmission electron microscopy of the kamacite-taenite interface in the fast-cooled Bristol IVA iron meteorite

NASA Astrophysics Data System (ADS)

Rout, Surya S.; Heck, Philipp R.; Isheim, Dieter; Stephan, Thomas; Zaluzec, Nestor J.; Miller, Dean J.; Davis, Andrew M.; Seidman, David N.

2017-12-01

We report the first combined atom-probe tomography (APT) and transmission electron microscopy (TEM) study of a kamacite-tetrataenite (K-T) interface region within an iron meteorite, Bristol (IVA). Ten APT nanotips were prepared from the K-T interface with focused ion beam scanning electron microscopy (FIB-SEM) and then studied using TEM followed by APT. Near the K-T interface, we found 3.8 ± 0.5 wt% Ni in kamacite and 53.4 ± 0.5 wt% Ni in tetrataenite. High-Ni precipitate regions of the cloudy zone (CZ) have 50.4 ± 0.8 wt% Ni. A region near the CZ and martensite interface has <10 nm sized Ni-rich precipitates with 38.4 ± 0.7 wt% Ni present within a low-Ni matrix having 25.5 ± 0.6 wt% Ni. We found that Cu is predominantly concentrated in tetrataenite, whereas Co, P, and Cr are concentrated in kamacite. Phosphorus is preferentially concentrated along the K-T interface. This study is the first precise measurement of the phase composition at high spatial resolution and in 3-D of the K-T interface region in a IVA iron meteorite and furthers our knowledge of the phase composition changes in a fast-cooled iron meteorite below 400 °C. We demonstrate that APT in conjunction with TEM is a useful approach to study the major, minor, and trace elemental composition of nanoscale features within fast-cooled iron meteorites.

Tectonics of some Amazonian greenstone belts

NASA Technical Reports Server (NTRS)

Gibbs, A. K.

1986-01-01

Greenstone belts exposed amid gneisses, granitoid rocks, and less abundant granulites along the northern and eastern margins of the Amazonian Craton yield Trans-Amazonican metamorphic ages of 2.0-2.1 Ga. Early proterozoic belts in the northern region probably originated as ensimatic island arc complexes. The Archean Carajas belt in the southeastern craton probably formed in an extensional basin on older continental basement. That basement contains older Archean belts with pillow basalts and komatiites. Belts of ultramafic rocks warrant investigatijon as possible ophiolites. A discussion follows.

Drivers' assessment of Ford's belt reminder system.

PubMed

Williams, Allan F; Wells, Joann K

2003-12-01

In recent model years, Ford vehicles have been equipped with a supplementary seat belt reminder system that flashes and chimes intermittently for up to 5 min if the driver is unbelted. Sound- and light-based belt reminder systems of various types are beginning to appear in the market place, and it is important to learn about their acceptance and ability to increase belt use. The present study was designed to ascertain consumer reaction and reported belt use regarding the Ford system. Personal interviews were conducted with 405 drivers of vehicles with the reminder system. Among the drivers, 67% said they had activated the belt reminder one or more times, 73% said that the last time this happened they fastened their belts, 46% said their belt use had increased since driving this vehicle, 78% said they liked the reminder system, and 79% said they wanted a reminder system like this in their next vehicle. Five percent had disabled the system. Part-time users were responsive to the reminder, for example, of those who said they currently used belts usually but not on some occasions, 70% said they fastened their seat belts the last time the reminder was activated and 76% said their belt use had increased. Five percent spontaneously mentioned the belt reminder as an especially disliked feature of their new vehicles, and 2% said their belt use had decreased since having it. The 7% of respondents who reported they used belts never or very occasionally were least responsive to the system. Overall, the Ford belt reminder system is being favorably received.

Modeling Solar Atmospheric Phenomena with AtomDB and PyAtomDB

NASA Astrophysics Data System (ADS)

Dupont, Marcus; Foster, Adam

2018-01-01

Taking advantage of the modeling tools made available by PyAtomDB (Foster 2015), we evaluated the impact of changing atomic data on solar phenomena, in particular their effects on models of coronal mass ejections (CME). Intitially, we perform modifications to the canonical SunNEI code (Murphy et al. 2011) in order to include non-equilibrium ionization (NEI) processes that occur in the CME modeled in SunNEI. The methods used involve the consideration of radiaitive cooling as well as ion balance calculations. These calculations were subsequently implemented within the SunNEI simulation. The insertion of aforementioned processes and parameter customizaton produced quite similar results of the original except for the case of iron. These differences were traced to inconsistencies in the recombination rates for Argon-like iron ions between the CHIANTI and AtomDB databases, even though they in theory use the same data. The key finding was that theoretical models are greatly impacted by the relative atomic database update cycles.Following the SunNEI comparison, we then use the AtomDB database to model the time depedencies of intensity flux spikes produced by a coronal shock wave (Ma et al. 2011). We produced a theretical representation for an ionizing plasma that interpolated over the intensity in four Astronomical Imaging Assembly (AIA) filters. Specifically, the 171 A (Fe IX) ,193 A (Fe XII, FeXXIV),211 A (Fe XIV),and 335 A (Fe XVI) wavelengths in order to assess the comparative spectral emissions between AtomDB and the observed data. The results of the theoretical model, in principle, shine light on both the equilibrium conditions before the shock and the non-equilibrium response to the shock front, as well as discrepancies introduced by changing the atomic data.

Monosodium glutamate for simple photometric iron analysis

NASA Astrophysics Data System (ADS)

Prasetyo, E.

2018-01-01

Simple photometric method for iron analysis using monosodium glutamate (MSG) was proposed. The method could be used as an alternative method, which was technically simple, economic, quantitative, readily available, scientifically sound and environmental friendly. Rapid reaction of iron (III) with glutamate in sodium chloride-hydrochloric acid buffer (pH 2) to form red-brown complex was served as a basis in the photometric determination, which obeyed the range of iron (III) concentration 1.6 - 80 µg/ml. This method could be applied to determine iron concentration in soil with satisfactory results (accuracy and precision) compared to other photometric and atomic absorption spectrometry results.

Recent Arecibo Radar Observations of Main-Belt Asteroids.

NASA Astrophysics Data System (ADS)

Shepard, Michael K.; Howell, Ellen; Nolan, Michael; Taylor, Patrick; Springmann, Alessondra; Giorgini, Jon; Benner, Lance; Magri, Christopher

2014-11-01

We recently observed main-belt asteroids 12 Victoria (Tholen S-class, Bus L-class), 246 Asporina (A-class), and 2035 Stearns with the S-band (12 cm) Arecibo radar. Signal-to-noise ratios for Asporina and Stearns were only strong enough for continuous-wave (CW) analysis. Signal-to-noise ratios for Victoria were high enough for delay-Doppler imaging. Stearns exhibited a high radar polarization ratio of unity, higher than any other main-belt E-class, but similar to near-Earth E-class asteroids [Benner et al. Icarus 198, 294-304, 2008; Shepard et al. Icarus 215, 547-551, 2011]. The A-class asteroids show spectral absorption features consistent with olivine and have been suggested as the source of pallasite meteorites or the rare brachinites [Cruikshank and Hartmann, Science 223, 281-283, 1984]. The radar cross-section measured for Asporina leads to a radar albedo estimate of 0.11, suggesting a low near-surface bulk density, and by inference, a low metal content. This suggests that the brachinites are a better analog for Asporina than the iron-rich pallasites. Victoria has been observed by radar in the past and the continuous-wave echoes suggest it has a large concavity or is a contact binary [Mitchell et al. Icarus 118, 105-131, 1995]. Our new imaging observations should determine which is more likely.

Hydrogen Plasma Processing of Iron Ore

NASA Astrophysics Data System (ADS)

Sabat, Kali Charan; Murphy, Anthony B.

2017-06-01

Iron is currently produced by carbothermic reduction of oxide ores. This is a multiple-stage process that requires large-scale equipment and high capital investment, and produces large amounts of CO2. An alternative to carbothermic reduction is reduction using a hydrogen plasma, which comprises vibrationally excited molecular, atomic, and ionic states of hydrogen, all of which can reduce iron oxides, even at low temperatures. Besides the thermodynamic and kinetic advantages of a hydrogen plasma, the byproduct of the reaction is water, which does not pose any environmental problems. A review of the theory and practice of iron ore reduction using a hydrogen plasma is presented. The thermodynamic and kinetic aspects are considered, with molecular, atomic and ionic hydrogen considered separately. The importance of vibrationally excited hydrogen molecules in overcoming the activation energy barriers, and in transferring energy to the iron oxide, is emphasized. Both thermal and nonthermal plasmas are considered. The thermophysical properties of hydrogen and argon-hydrogen plasmas are discussed, and their influence on the constriction and flow in the of arc plasmas is considered. The published R&D on hydrogen plasma reduction of iron oxide is reviewed, with both the reduction of molten iron ore and in-flight reduction of iron ore particles being considered. Finally, the technical and economic feasibility of the process are discussed. It is shown that hydrogen plasma processing requires less energy than carbothermic reduction, mainly because pelletization, sintering, and cokemaking are not required. Moreover, the formation of the greenhouse gas CO2 as a byproduct is avoided. In-flight reduction has the potential for a throughput at least equivalent to the blast furnace process. It is concluded that hydrogen plasma reduction of iron ore is a potentially attractive alternative to standard methods.

Pilot tests of a seat belt gearshift delay on the belt use of commercial fleet drivers.

DOT National Transportation Integrated Search

2009-12-01

the seat belt was buckled. Participants, commercial drivers from the United States and Canada who did not consistently wear their seat belts, could avoid the delay by fastening their seat belts. Unbelted participants experienced a delay of either a c...

Experimental comparative study of doublet and triplet impinging atomization of gelled fuel based on PIV

NASA Astrophysics Data System (ADS)

Yang, Jian-lu; Li, Ning; Weng, Chun-sheng

2016-10-01

Gelled propellant is promising for future aerospace application because of its combination of the advantages of solid propellants and liquid propellants. An effort was made to reveal the atomization properties of gelled fuel by particle image velocimetry (PIV) system. The gelled fuel which was formed by gasoline and Nano-silica was atomized using a like-doublet impingement injector and an axisymmetric like-triplet impingement injector. The orifice diameter and length of the nozzle used in this work were of 0.8mm, 4.8mm, respectively. In the impinging spray process, the impingement angles were set at 90° and 120°, and the injection pressures were of 0.50MPa and 1.00MPa. The distance from the exit of the orifice to the impingement point was fixed at 9.6mm. In this study, high-speed visualization and temporal resolution particle image velocimetry techniques were employed to investigate the impingement atomization characteristics. The experimental investigation demonstrated that a long narrow high speed droplets belt formed around the axis of symmetry in the like-doublet impinging atomization area. However, there was no obvious high-speed belt with impingement angle 2θ = 90° and two high-speed belts appeared with impingement angle 2θ = 120° in the like-doublet impingement spray field. The high droplet velocity zone of the like-doublet impingement atomization symmetrically distributed around the central axis, and that of the like-triplet impingement spray deflected to the left of the central axis - opposite of injector. Although the droplets velocity distribution was asymmetry of like-triplet impingement atomization, the injectors were arranged like axisymmetric conical shape, and the cross section of spray area was similar to a circle rather than a narrow rectangle like the like-doublet impingement atomization.

Seat Belt Sign and Its Significance

PubMed Central

Agrawal, Amit; Inamadar, Praveenkumar Ishwarappa; Subrahmanyam, Bhattara Vishweswar

2013-01-01

Safety belts are the most important safety system in motor vehicles and when worn intend to prevent serious injuries. However, in unusual circumstances (high velocity motor vehicle collisions) these safety measures (seat belts) can be the source and cause of serious injuries. The seat belt syndrome was first described as early by Garrett and Braunste in but the term “seat belt sign” was discussed by Doersch and Dozier. Medical personnel's involved in emergency care of trauma patients should be aware of seat belt sign and there should a higher index of suspicion to rule out underlying organ injuries. PMID:24479100

Ab initio study on the molecular recognition by metalloporphyrins: CO interaction with iron porphyrin

NASA Astrophysics Data System (ADS)

Han, Seungwu; Cho, Kyeongjae; Ihm, Jisoon

1999-02-01

We have performed ab initio pseudopotential calculations to study the effects of structural deformations of iron porphyrin on the configuration of a carbon monoxide (CO) attached to it. We have considered two proximal deformations around the heme group: (i) rotation of a pyrrole ring in the iron porphyrin, and (ii) rotation of the imidazole side chain bound to the iron atom. We have identified induced changes of the atomic geometry and the electronic structure of the iron porphyrin-CO complex, and the results elucidate the microscopic nature of the CO interaction with the iron porphyrin. Implications on the controversies over the binding angle of the CO molecule on the iron porphyrin under different circumstances are discussed. A potential application to the simulation-based chemical sensor design is also discussed.

Archean deep-water depositional system: interbedded and banded iron formation and clastic turbidites in the Barberton Greenstone Belt, South Africa

NASA Astrophysics Data System (ADS)

Zentner, Danielle; Lowe, Donald

2013-04-01

The 3.23 billion year old sediments in the Barberton greenstone belt, South Africa include some of the world's oldest known deep-water deposits. Unique to this locality are turbidites interbedded with banded iron formation (BIF) and banded ferruginous chert (BFC). This unusual association may provide clues for reconstructing Archean deep-water depositional settings. For our study we examined freshly drilled core in addition to measuring ~500 m of outcrop exposures along road cuts. The stacking pattern follows an overall BIF to BFC to amalgamated turbidite succession, although isolated turbidites do occur throughout the sequence. The turbidites are predominately massive, and capped with thin, normally graded tops that include mud rip-ups, chert plates, and ripples. The lack of internal stratification and the amalgamated character suggests emplacement by surging high-density turbidity currents. Large scours and channels are absent and bedding is tabular: the flows were collapsing with little turbulence reaching the bed. In contrast, field evidence indicates the BIF and BFC most likely precipitated directly out of the water column. Preliminary interpretations indicate the deposits may be related to a pro-deltaic setting. (1) Deltaic systems can generate long-lived, high volume turbidity currents. (2) The contacts between the BIF, BFC, and turbidite successions are gradual and inter-fingered, possibly representing lateral facies relationships similar to modern pro-delta environments. (3) Putative fan delta facies, including amalgamated sandstone and conglomerate, exist stratigraphically updip of the basinal sediments.

Pelvic belt effects on sacroiliac joint ligaments: a computational approach to understand therapeutic effects of pelvic belts.

PubMed

Sichting, Freddy; Rossol, Jerome; Soisson, Odette; Klima, Stefan; Milani, Thomas; Hammer, Niels

2014-01-01

The sacroiliac joint is a widely described source of low back pain. Therapeutic approaches to relieve pain include the application of pelvic belts. However, the effects of pelvic belts on sacroiliac joint ligaments as potential pain generators are mostly unknown. The aim of our study was to analyze the influence of pelvic belts on ligament load by means of a computer model. Experimental computer study using a finite element method. A computer model of the human pelvis was created, comprising bones, ligaments, and cartilage. Detailed geometries, material properties of ligaments, and in-vivo pressure distribution patterns of a pelvic belt were implemented. The effects of pelvic belts on ligament strain were computed in the double-leg stance. Pelvic belts increase sacroiliac joint motion around the sagittal axis but decrease motion around the transverse axis. With pelvic belt application, most of the strained sacroiliac joint ligaments were relieved, especially the sacrospinous, sacrotuberous, and the interosseous sacroiliac ligaments. Sacroiliac joint motion and ligament strains were minute. These results agree with validation data from other studies. Assigning homogenous and linear material properties and excluding muscle forces are clear simplifications of the complex reality. Pelvic belts alter sacroiliac joint motion and provide partial relief of ligament strain that is subjectively marked, although minimal in absolute terms. These findings confirm theories that besides being mechanical stabilizers, the sacroiliac joint ligaments are likely involved in neuromuscular feedback mechanisms. The results from our computer model help with unraveling the therapeutic mechanisms of pelvic belts.

Seat belt use-inducing system effectiveness

DOT National Transportation Integrated Search

1975-04-01

Seat belt use inducing system effectiveness was measured in fleet automobiles of a private business and in rental automobiles at a large airport. There were three parts to the activity: 1. Seat belt use inducing systems and seat belt use counting sys...

Small Main-Belt Asteroid Lightcurve Survey

NASA Technical Reports Server (NTRS)

Binzel, Richard P.; Xu, Shui; Bus, Schelte J.; Bowell, Edward

1992-01-01

The Small Main-Belt Asteroid Lightcurve Survey is the first to measure main-belt asteroid lightcurve properties for bodies with diameters smaller than 5 km. Attention is given to CCD lightcurves for 32 small main-belt asteroids. The objects of this sample have a mean rotational frequency which is faster than that of larger main-belt asteroids. All lightcurves were investigated for nonperiodic variations ascribable to free precession; no conclusive detection of this phenomenon has been made, however.

Atomic-scale Visualization of Electronic Nematicity and Cooper Pairing in Iron-based Superconductors

NASA Astrophysics Data System (ADS)

Allan, Milan P.

2013-03-01

The mechanism of high-temperature superconductivity in the relatively novel iron-based high-Tc superconductors is unresolved, both in terms of how the phases evolve with doping, and in terms of the actual Cooper pairing process. To explore these issues, we used spectroscopic-imaging scanning tunneling microscopy to study the electronic structure of CaFe2As2 in the antiferromagnetic-orthorhombic `parent' state from which the superconductivity emerges. We discovered and visualized the now widely studied electronic `nematicity' of this phase, whose suppression is associated with the emergence of superconductivity (Science 327, 181, 2010). As subsequent transport experiments discovered a related anisotropic conductance which increases with dopant concentration, the interplay between the electronic structure surrounding each dopant atom, quasiparticle scattering therefrom, and the transport nematicity has become a pivotal focus of research. We find that substituting Co for Fe atoms in underdoped Ca(Fe1-xCox)2As2 generates a dense population of identical and strongly anisotropic impurity states that are distributed randomly but aligned with the antiferromagnetic a-axis. We also demonstrate, by imaging their surrounding interference patterns, that these impurity states scatter quasiparticles and thus influence transport in a highly anisotropic manner (M.P. Allan et al., 2013). Next, we studied the momentum dependence of the energy gaps of iron-based superconductivity, now focusing on LiFeAs. If strong electron-electron interactions mediate the Cooper pairing, then momentum-space anisotropic superconducting energy gaps Δi (k) were predicted by multiple techniques to appear on the different electronic bands i. We introduced intraband Bogoliubov quasiparticle scattering interference (QPI) techniques for the determination of anisotropic energy gaps to test these hypotheses and discovered the anisotropy, magnitude, and relative orientations of the energy gaps on multiple

Linking the collisional history of the main asteroid belt to its dynamical excitation and depletion

NASA Astrophysics Data System (ADS)

Bottke, William F.; Durda, Daniel D.; Nesvorný, David; Jedicke, Robert; Morbidelli, Alessandro; Vokrouhlický, David; Levison, Harold F.

2005-12-01

of the total mass thought to have existed in the main belt zone during planet formation. The remaining mass was most likely taken up by planetary embryos formed in the same region. Our results suggest that numerous D>200 km planetesimals disrupted early in Solar System history, but only a small fraction of their fragments survived the dynamical depletion event described above. We believe this may explain the limited presence of iron-rich M-type, olivine-rich A-type, and non-Vesta V-type asteroids in the main belt today. The collisional lifetimes determined for main belt asteroids agree with the cosmic ray exposure ages of stony meteorites and are consistent with the limited collisional evolution detected among large Koronis family members. Using the same model, we investigated the near-Earth object (NEO) population. We show the shape of the NEO size distribution is a reflection of the main belt population, with main belt asteroids driven to resonances by Yarkovsky thermal forces. We used our model of the NEO population over the last 3 Gyr, which is consistent with the current population determined by telescopic and satellite data, to explore whether the majority of small craters ( D<0.1-1 km) formed on Mercury, the Moon, and Mars were produced by primary impacts or by secondary impacts generated by ejecta from large craters. Our results suggest that most small craters formed on these worlds were a by-product of secondary rather than primary impacts.

Geochemistry of precambrian carbonates. II. Archean greenstone belts and Archean sea water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Veizer, J.; Hoefs, J.; Lowe, D.R.

1989-04-01

Carbonate rocks with geological attributes of marine sediments are a minor component of the Archean greenstone belts. Despite their relative scarcity, these rocks are important because they record chemical and isotopic properties of coeval oceans. The greenstones containing such carbonates appear to cluster at {approximately}2.8 {plus minus} 0.2 and {approximately}3.5 {plus minus} 0.1 Ga ago. The samples for the younger group are from the Abitibi, Yellowknife, Wabigoon, Michipicoten and Uchi greenstone belts of Canada and the Upper Greenstones of Zimbabwe. The older group includes the Swaziland Supergroup of South Africa, Warrawoona Group of Australia and the Sargur marbles of India.more » Mineralogically, the carbonates of the younger greenstones are mostly limestones and of the older ones, ferroan dolomites (ankerites); the latter with some affinities to hydrothermal carbonates. In mineralized areas with iron ores, the carbonate minerals are siderite {plus minus} ankerite, irrespective of the age of the greenstones. Iron-poor dolomites represent a later phase of carbonate generation, related to post-depositional tectonic faulting. The original mineralogy of limestone sequences appears to have been an Sr-rich aragonite. The Archean carbonates yield near-mantle Sr isotopic values, with ({sup 87}Sr/{sup 86}Sr){sub o} of 0.7025 {plus minus} 0.0015 and 0.7031 {plus minus} 0.0008 for younger and older greenstones, respectively. The mineralogical and chemical attributes of Archean carbonates are consistent with the proposition that the composition of the coeval oceans may have been buffered by a pervasive interaction with the mantle, that is, with the oceanic crust and the coeval ubiquitous volcanosedimentary piles derived from mantle sources.« less

14 CFR 27.1413 - Safety belts.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Safety belts. 27.1413 Section 27.1413 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT AIRWORTHINESS STANDARDS: NORMAL CATEGORY ROTORCRAFT Equipment Safety Equipment § 27.1413 Safety belts. Each safety belt...

14 CFR 27.1413 - Safety belts.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Safety belts. 27.1413 Section 27.1413 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT AIRWORTHINESS STANDARDS: NORMAL CATEGORY ROTORCRAFT Equipment Safety Equipment § 27.1413 Safety belts. Each safety belt...

Persistence of Salmonella on egg conveyor belts is dependent on the belt type but not on the rdar morphotype.

PubMed

Stocki, S L; Annett, C B; Sibley, C D; McLaws, M; Checkley, S L; Singh, N; Surette, M G; White, A P

2007-11-01

Commercial caged layer flocks in Alberta, Canada, are commonly monitored for Salmonella enterica serovar Enteritidis (SE) and S. enterica serovar Typhimurium (ST) by environmental sampling. In one recent case, a SE strain isolated from the egg conveyor belt was a source of persistent infection for the flock. This study was undertaken to examine Salmonella colonization on egg conveyor belts and to determine whether the rdar morphotype, a conserved physiology associated with aggregation and long-term survival, contributed to persistence. Four woven belts constructed of natural or nonnatural fibers and a 1-piece belt made of vinyl were tested with rdar-positive ST and SE strains and a rdar-negative ST DeltaagfD reference strain. The type of egg belt was the most important factor influencing Salmonella colonization and persistence. The vinyl belt, with the least surface area available for colonization, had the fewest Salmonella remaining after washing and disinfection, whereas the hemp-plastic belt, with the greatest surface area, had the most Salmonella remaining. Real-time gene expression indicated that the rdar morphotype was involved in colonizing the egg belt pieces; however, it was not essential for persistence. In addition, rdar-positive and rdar-negative strains were equally similarly to disinfection on the egg belt pieces. The results indicate that Salmonella can persist on a variety of egg belts by mechanisms other than the rdar morphotype, and that using egg conveyer belts with reduced surface area for bacterial colonization can lessen contamination problems.

Iron meteorite fragment studied by atomic and nuclear analytical methods

NASA Astrophysics Data System (ADS)

Cesnek, Martin; Štefánik, Milan; Kmječ, Tomáš; Miglierini, Marcel

2016-10-01

Chemical and structural compositions of a fragment of Sikhote-Alin iron meteorite were investigated by X-ray fluorescence analysis (XRF), neutron activation analysis (NAA) and Mössbauer spectroscopy (MS). XRF and NAA revealed the presence of chemical elements which are characteristic for iron meteorites. XRF also showed a significant amount of Si and Al on the surface of the fragment. MS spectra revealed possible presence of α-Fe(Ni, Co) phase with different local Ni concentration. Furthermore, paramagnetic singlet was detected in Mössbauer spectra recorded at room temperature and at 4.2 K.

Granulite belts of Central India with special reference to the Bhopalpatnam Granulite Belt: Significance in crustal evolution and implications for Columbia supercontinent

NASA Astrophysics Data System (ADS)

Vansutre, Sandeep; Hari, K. R.

2010-11-01

The Central Indian collage incorporates the following major granulite belts: (1) the Balaghat-Bhandara Granulite Belt (BBG), (2) the Ramakona-Katangi Granulite Belt (RKG), (3) the Chhatuabhavna Granulite (CBG) of Bilaspur-Raigarh Belt, (4) the Makrohar Granulite Belt (MGB) of Mahakoshal supracrustals, (5) the Kondagaon Granulite Belt (KGGB), (6) the Bhopalpatnam Granulite Belt (BGB), (7) the Konta Granulite Belt (KTGB) and (8) the Karimnagar Granulite Belt (KNGB) of the East Dharwar Craton (EDC). We briefly synthesize the general geologic, petrologic and geochronologic features of these belts and explain the Precambrian crustal evolution in Central India. On the basis of the available data, a collisional relationship between Bastar craton and the EDC during the Paleo-Mesoproterozoic is reiterated as proposed by the earlier workers. The tectonic evolution of only few of the orogenic belts (BGB in particular) of Central India is related to Columbia.

Reduced fatalities related to rear seat shoulder belts

PubMed Central

Robertson, L.

1999-01-01

Methods—During 1988–96, fatalities to rear outboard seat occupants of passenger cars, classified by age of occupant and vehicle curb weight were matched to data on model year in which shoulder belts became standard equipment. The same data were obtained from the same years on back seat occupants in crashes from the Crashworthiness Data System. Weighted regression was performed on death rates per occupants in crashes by belt equipment, occupant age, and vehicle weight for all occupants and occupants who claimed to be restrained. Results—The risk of death is significantly lower in vehicles equipped with shoulder belts, midsized to larger cars, and among children. Claimed child restraint use is higher in cars with shoulder belts and claimed use of shoulder belts is higher among adolescents and young adults but lower among those 35 and older. However, older occupants have lower death rates in shoulder belt equipped cars. Conclusions—Shoulder belts substantially reduce risk of death relative to lap belts at prevalent use rates in each age group. Belt effectiveness when used cannot be estimated precisely because of invalid claimed use, but the lowered rates among vehicles with shoulder belts indicates that effectiveness given prevalent use is far more efficacious than lap belts without shoulder belts. PMID:10323573

Observed use of automatic seat belts in 1987 cars.

PubMed

Williams, A F; Wells, J K; Lund, A K; Teed, N

1989-10-01

Usage of the automatic belt systems supplied by six large-volume automobile manufacturers to meet the federal requirements for automatic restraints were observed in suburban Washington, D.C., Chicago, Los Angeles, and Philadelphia. The different belt systems studied were: Ford and Toyota (motorized, nondetachable automatic shoulder belt), Nissan (motorized, detachable shoulder belt), VW and Chrysler (nonmotorized, detachable shoulder belt), and GM (nonmotorized detachable lap and shoulder belt). Use of automatic belts was significantly greater than manual belt use in otherwise comparable late-model cars for all manufacturers except Chrysler; in Chrysler cars, automatic belt use was significantly lower than manual belt use. The automatic shoulder belts provided by Ford, Nissan, Toyota, and VW increased use rates to about 90%. Because use rates were lower in Ford cars with manual belts, their increase was greater. GM cars had the smallest increase in use rates; however, lap belt use was highest in GM cars. The other manufacturers supply knee bolsters to supplement shoulder belt protection; all--except VW--also provide manual lap belts, which were used by about half of those who used the automatic shoulder belt. The results indicate that some manufacturers have been more successful than others in providing automatic belt systems that result in high use that, in turn, will mean fewer deaths and injuries in those cars.

14 CFR 31.63 - Safety belts.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Safety belts. 31.63 Section 31.63 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT AIRWORTHINESS STANDARDS: MANNED FREE BALLOONS Design Construction § 31.63 Safety belts. (a) There must be a safety belt...

14 CFR 31.63 - Safety belts.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Safety belts. 31.63 Section 31.63 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT AIRWORTHINESS STANDARDS: MANNED FREE BALLOONS Design Construction § 31.63 Safety belts. (a) There must be a safety belt...

Mandatory seat belt use.

DOT National Transportation Integrated Search

1984-01-01

The purposes of this study were to review mandatory seat belt use laws as they have been used around the world, to forecast the impact of such a law in Virginia, and, if appropriate, to propose a mandatory seat belt law for inclusion in the Code of V...

Modeling the Inner Magnetosphere: Radiation Belts, Ring Current, and Composition

NASA Technical Reports Server (NTRS)

Glocer, Alex

2011-01-01

The space environment is a complex system defined by regions of differing length scales, characteristic energies, and physical processes. It is often difficult, or impossible, to treat all aspects of the space environment relative to a particular problem with a single model. In our studies, we utilize several models working in tandem to examine this highly interconnected system. The methodology and results will be presented for three focused topics: 1) Rapid radiation belt electron enhancements, 2) Ring current study of Energetic Neutral Atoms (ENAs), Dst, and plasma composition, and 3) Examination of the outflow of ionospheric ions. In the first study, we use a coupled MHD magnetosphere - kinetic radiation belt model to explain recent Akebono/RDM observations of greater than 2.5 MeV radiation belt electron enhancements occurring on timescales of less than a few hours. In the second study, we present initial results of a ring current study using a newly coupled kinetic ring current model with an MHD magnetosphere model. Results of a dst study for four geomagnetic events are shown. Moreover, direct comparison with TWINS ENA images are used to infer the role that composition plays in the ring current. In the final study, we directly model the transport of plasma from the ionosphere to the magnetosphere. We especially focus on the role of photoelectrons and and wave-particle interactions. The modeling methodology for each of these studies will be detailed along with the results.

Formation and characterization of iron-binding phosphorylated human-like collagen as a potential iron supplement.

PubMed

Deng, Jianjun; Chen, Fei; Fan, Daidi; Zhu, Chenhui; Ma, Xiaoxuan; Xue, Wenjiao

2013-10-01

Iron incorporated into food can induce precipitation and unwanted interaction with other components in food. Iron-binding proteins represent a possibility to avoid these problems and other side effects, as the iron is protected. However, there are several technical problems associated with protein-iron complex formation. In this paper, the iron-binding phosphorylated human-like collagen (Fe-G6P-HLC) was prepared under physiological conditions through phosphorylated modification. One molecule of Fe-G6P-HLC possesses about 24 atoms of Fe. Spectroscopy analysis, differential scanning calorimetry (DSC) and equilibrium dialysis techniques were employed to investigate the characteristics of the Fe-G6P-HLC. The binding sites (nb) and apparent association constant (Kapp) between iron and phosphorylated HLC were measured at nb=23.7 and log Kapp=4.57, respectively. The amount of iron (Fe(2+) sulfate) binding to phosphorylated HLC was found to be a function of pH and phosphate content. In addition, the solubility and thermal stability of HLC were not significantly affected. The results should facilitate the utilization of HLC as a bioactive iron supplement in the food and medical industry and provide an important theoretical evidence for the application of HLC chelates. © 2013.

46 CFR 169.723 - Safety belts.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 7 2011-10-01 2011-10-01 false Safety belts. 169.723 Section 169.723 Shipping COAST... Control, Miscellaneous Systems, and Equipment § 169.723 Safety belts. Each vessel must carry a harness type safety belt conforming to Offshore Racing Council (ORC) standards for each person on watch or...

46 CFR 169.723 - Safety belts.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Safety belts. 169.723 Section 169.723 Shipping COAST... Control, Miscellaneous Systems, and Equipment § 169.723 Safety belts. Each vessel must carry a harness type safety belt conforming to Offshore Racing Council (ORC) standards for each person on watch or...

30 CFR 77.1107 - Belt conveyors.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Belt conveyors. 77.1107 Section 77.1107 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY... § 77.1107 Belt conveyors. Belt conveyors in locations where fire would create a hazard to personnel...

Seat belt use in cars with air bags.

PubMed Central

Williams, A F; Wells, J K; Lund, A K

1990-01-01

Seat belt use was observed in 1,628 cars with air bags and manual belts and 34,223 cars with manual seat belts only. Sixty-six percent of drivers in cars with air bags wore seat belts compared to 63 percent of drivers in cars with manual belts only. The study found no evidence for the speculation that drivers with air bags will reduce their seat belt use because they believe an air bag alone provides sufficient protection. PMID:2240346

On the brittle-ductile behavior of iron meteorites - New experimental constraints

NASA Technical Reports Server (NTRS)

Matsui, T.; Schultz, P. H.

1984-01-01

Impact trials were performed at the NASA vertical gun range to study low-temperature brittle-ductile transitions in meteoritic, steel and iron targets. The trials were performed to enhance the data base underlying the concept of formation of planetesimals in collisional coagulation. Impact velocities of 1.6-5.5 km/sec were used, as were temperatures from 100-300 K. Spallation was observed in the tests with meteorite samples, even at room temperature, and brittleness was enhanced at temperature below 200 C. Net mass losses were induced at the higher impact velocities. It is suggested that iron meteorite agglomerations could form in the inner solar region during nebular condensation, but would not form in farther-out regions such as the asteroid belt. The protoplanets could have an iron core, with metallicity decreasing with radius from the core, which may have happened with the earth.

Whey Peptide-Iron Complexes Increase the Oxidative Stability of Oil-in-Water Emulsions in Comparison to Iron Salts.

PubMed

Caetano-Silva, Maria Elisa; Barros Mariutti, Lilian Regina; Bragagnolo, Neura; Bertoldo-Pacheco, Maria Teresa; Netto, Flavia Maria

2018-02-28

Food fortification with iron may favor lipid oxidation in both food matrices and the human body. This study aimed at evaluating the effect of peptide-iron complexation on lipid oxidation catalyzed by iron, using oil-in-water (O/W) emulsions as a model system. The extent of lipid oxidation of emulsions containing iron salts (FeSO 4 or FeCl 2 ) or iron complexes (peptide-iron complexes or ferrous bisglycinate) was evaluated during 7 days, measured as primary (peroxide value) and secondary products (TBARS and volatile compounds). Both salts catalyzed lipid oxidation, leading to peroxide values 2.6- to 4.6-fold higher than the values found for the peptide-iron complexes. The addition of the peptide-iron complexes resulted in the formation of lower amounts of secondary volatiles of lipid oxidation (up to 78-fold) than those of iron salts, possibly due to the antioxidant activity of the peptides and their capacity to keep iron apart from the lipid phase, since the iron atom is coordinated and takes part in a stable structure. The peptide-iron complexes showed potential to reduce the undesirable sensory changes in food products and to decrease the side effects related to free iron and the lipid damage of cell membranes in the organism, due to the lower reactivity of iron in the complexed form.

Fabrication of Iron-Containing Carbon Materials From Graphite Fluoride

NASA Technical Reports Server (NTRS)

Hung, Ching-cheh

1996-01-01

Carbon materials containing iron alloy, iron metal, iron oxide or iron halide were fabricated. Typical samples of these metals were estimated to contain 1 iron atom per 3.5 to 5 carbon atoms. Those carbon materials containing iron alloy, iron metal, and/or Fe3O4 were magnetic. The kinetics of the fabrication process were studied by exposing graphite fluoride (CF(0.68)) to FeCl3 over a 280 to 420 C temperature range. Between 280 and 295 C, FeCl3 quickly entered the structure of CF(0.68), broke the carbon-fluorine bonds, and within 10 to 30 min, completely converted it to carbon made up of graphite planes between which particles of crystalline FeF3 and noncrystalline FeCl3 were located. Longer reaction times (e.g., 28 hr) or higher reaction temperatures (e.g., 420 C) produced materials containing graphite, a FeCl3-graphite intercalation compound, FeCl2(center dot)4H2O, and FeCl2(center dot)2H2O. These products were further heat treated to produce iron-containing carbon materials. When the heating temperature was kept in the 750 to 850 C range, and the oxygen supply was kept at the optimum level, the iron halides in the carbon structure were converted to iron oxides. Raising the heat to temperatures higher than 900 C reduced such iron oxides to iron metal. The kinetics of these reactions were used to suggest processes for fabricating carbon materials containing iron alloy. Such processes were then tested experimentally. In one of the successful trial runs, commercially purchased CF(0.7) powder was used as the reactant, and NiO was added during the final heating to 1200 C as a source of both nickel and oxygen. The product thus obtained was magnetic and was confirmed to be a nickel-iron alloy in carbon.

Investigation of Moving Belt Radiator Technology Issues

NASA Technical Reports Server (NTRS)

Teagan, W. Peter; Aguilar, Jerry L.

1994-01-01

The development of an advanced spacecraft radiator technology is reported. The moving belt radiator is a thermal radiator concept with the promise of lower specific mass (per kW rejected) than that afforded by existing technologies. The results of a parametric study to estimate radiator mass for future space power systems is presented. It is shown that this technology can be scaled up to 200 MW for higher rejection temperatures. Several aspects of the design concept are discussed, including the dynamics of a large rotating belt in microgravity. The results of a computer code developed to model the belt dynamics are presented. A series of one-g experiments to investigate the dynamics of small belts is described. A comprehensive test program to investigate belt dynamics in microgravity aboard the NASA KC-135 aircraft is discussed. It was found that the desired circular shape can readily be achieved in microgravity. It is also shown that a rotating belt is stable when subjected to simulated attitude control maneuvers. Heat exchanger design is also investigated. Several sealing concepts were examined experimentally, and are discussed. Overall heat transfer coefficients to the rotating belt are presented. Material properties for various belt materials, including screen meshes, are also presented. The results presented in this report indicate that the moving belt radiator concept is technically feasible.

Quantum coherent tractor beam effect for atoms trapped near a nanowaveguide

PubMed Central

Sadgrove, Mark; Wimberger, Sandro; Nic Chormaic, Síle

2016-01-01

We propose several schemes to realize a tractor beam effect for ultracold atoms in the vicinity of a few-mode nanowaveguide. Atoms trapped near the waveguide are transported in a direction opposite to the guided mode propagation direction. We analyse three specific examples for ultracold 23Na atoms trapped near a specific nanowaveguide (i.e. an optical nanofibre): (i) a conveyor belt-type tractor beam effect, (ii) an accelerator tractor beam effect, and (iii) a quantum coherent tractor beam effect, all of which can effectively pull atoms along the nanofibre toward the light source. This technique provides a new tool for controlling the motion of particles near nanowaveguides with potential applications in the study of particle transport and binding as well as atom interferometry. PMID:27440516

Simple-Cubic Carbon Frameworks with Atomically Dispersed Iron Dopants toward High-Efficiency Oxygen Reduction.

PubMed

Wang, Biwei; Wang, Xinxia; Zou, Jinxiang; Yan, Yancui; Xie, Songhai; Hu, Guangzhi; Li, Yanguang; Dong, Angang

2017-03-08

Iron and nitrogen codoped carbons (Fe-N-C) have attracted increasingly greater attention as electrocatalysts for oxygen reduction reaction (ORR). Although challenging, the synthesis of Fe-N-C catalysts with highly dispersed and fully exposed active sites is of critical importance for improving the ORR activity. Here, we report a new type of graphitic Fe-N-C catalysts featuring numerous Fe single atoms anchored on a three-dimensional simple-cubic carbon framework. The Fe-N-C catalyst, derived from self-assembled Fe 3 O 4 nanocube superlattices, was prepared by in situ ligand carbonization followed by acid etching and ammonia activation. Benefiting from its homogeneously dispersed and fully accessible active sites, highly graphitic nature, and enhanced mass transport, our Fe-N-C catalyst outperformed Pt/C and many previously reported Fe-N-C catalysts for ORR. Furthermore, when used for constructing the cathode for zinc-air batteries, our Fe-N-C catalyst exhibited current and power densities comparable to those of the state-of-the-art Pt/C catalyst.

36 CFR 4.15 - Safety belts.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Safety belts. 4.15 Section 4... TRAFFIC SAFETY § 4.15 Safety belts. (a) Each operator and passenger occupying any seating position of a motor vehicle in a park area will have the safety belt or child restraint system properly fastened at...

36 CFR 4.15 - Safety belts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Safety belts. 4.15 Section 4... TRAFFIC SAFETY § 4.15 Safety belts. (a) Each operator and passenger occupying any seating position of a motor vehicle in a park area will have the safety belt or child restraint system properly fastened at...

Klippen Belt, Flysch Belt and Inner Western Carpathian Paleogene Basin Relations in the Northern Slovakia by Magnetotelluric Imaging

NASA Astrophysics Data System (ADS)

Majcin, Dušan; Bezák, Vladimír; Klanica, Radek; Vozár, Ján; Pek, Josef; Bilčík, Dušan; Telecký, Josef

2018-05-01

The paper presents the interpretation of magnetotelluric measurements along the SW-NE profile near Stará Ľubovňa (Northern Slovakia). The profile passes through the Outer Carpathian Flysch Belt, Klippen Belt and ends in the Inner Western Carpathians Paleogene NW from Ružbachy horst structure. The interpretation of the older measurements from profile Mt4 was utilized and, moreover, the 3-D geoelectrical model of studied region was constructed. The magnetotelluric data interpretations verified the northern inclination of Flysch belt structures and their smaller thickness out of Klippen Belt in direction to the Carpathian electrical conductivity zone axis. We consider this as a consequence of the flower structure—more precisely the southern branch of the suture zone related to mentioned conductivity zone. Northerly from this zone the thickness of the Outer Carpathian Flysch Belt increases and the structures have inclination to the south, i.e. to the subduction zone. The contact of Flysch Belt with Klippen Belt has a fault character and it is subvertical, slightly inclined to the North. The southern boundary between Klippen Belt and Inner Western Carpathians has also fault character and is very steep. We detect the continuation of the Ružbachy horst to the NE in the basement of Inner Western Carpathian Paleogene. The structural discordance between this horst and Klippen Belt direction is a result of younger tectonic processes. According to our results the depth distribution of the pre-Tertiary basement below the Inner Western Carpathian units is non-uniform; the basement is broken to a number of partial blocks—horsts and grabens.

Inner Radiation Belt Dynamics and Climatology

NASA Astrophysics Data System (ADS)

Guild, T. B.; O'Brien, P. P.; Looper, M. D.

2012-12-01

We present preliminary results of inner belt proton data assimilation using an augmented version of the Selesnick et al. Inner Zone Model (SIZM). By varying modeled physics parameters and solar particle injection parameters to generate many ensembles of the inner belt, then optimizing the ensemble weights according to inner belt observations from SAMPEX/PET at LEO and HEO/DOS at high altitude, we obtain the best-fit state of the inner belt. We need to fully sample the range of solar proton injection sources among the ensemble members to ensure reasonable agreement between the model ensembles and observations. Once this is accomplished, we find the method is fairly robust. We will demonstrate the data assimilation by presenting an extended interval of solar proton injections and losses, illustrating how these short-term dynamics dominate long-term inner belt climatology.

Seat belt injuries in impact.

DOT National Transportation Integrated Search

1969-03-01

Although the seat belt has been demonstrated to provide effective reduction of injuries and fatalities in automobile accidents by preventing ejection, a pattern of injuries directly attributable to impingement on the belt itself is becoming evident. ...

Internal iron biomineralization in Imperata cylindrica, a perennial grass: chemical composition, speciation and plant localization.

PubMed

Rodríguez, N; Menéndez, N; Tornero, J; Amils, R; de la Fuente, V

2005-03-01

* The analysis of metal distribution in Imperata cylindrica, a perennial grass isolated from the banks of Tinto River (Iberian Pyritic Belt), an extreme acidic environment with high content in metals, has shown a remarkable accumulation of iron. This property has been used to study iron speciation and its distribution among different tissues and structures of the plant. * Mossbauer (MS) and X-ray diffraction (XRD) were used to determine the iron species, scanning electron microscopy (SEM) to locate iron biominerals among plant tissue structures, and energy-dispersive X-ray microanalysis (EDAX), X-ray fluorescence (TXRF) and inductively coupled plasma emission spectroscopy (ICP-MS) to confirm their elemental composition. * The MS spectral analysis indicated that iron accumulated in this plant mainly as jarosite and ferritin. The presence of jarosite was confirmed by XRD and the distribution of both minerals in structures of different tissues was ascertained by SEM-EDAX analysis. * The convergent results obtained by complementary techniques suggest a complex iron management system in I. cylindrica, probably as a consequence of the environmental conditions of its habitat.

Peculiarities of FeSi phonon spectrum induced by a change of atomic volume

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parshin, P. P., E-mail: Parshin-PP@nrcki.ru, E-mail: neupar45@yandex.ru; Chumakov, A. I.; Alekseev, P. A.

2016-12-15

We analyze in detail the results of experimental investigations of the evolution of the thermal vibration spectra for iron atoms in iron monosilicide FeSi depending on two external parameters, viz., temperature T (in the range 46–297 K at pressure P = 0.1 MPa) and pressure P (in the range 0.1 MPa–43 GPa at temperature T = 297 K), obtained by nuclear inelastic scattering of synchrotron radiation. The decrease of the atomic volume is accompanied by a rearrangement of the phonon spectrum, which is manifested, in particular, in the splitting of the low-energy peak in the spectrum and in an increasemore » of the energy for all phonons. The changes of the average energy of the iron atom vibrational spectrum and of the Debye energy with decreasing atomic volume are analyzed. Different versions of FeSi electron spectrum variation, which can be used to explain the observed phonon anomalies, are considered.« less

Chaos on the conveyor belt.

PubMed

Sándor, Bulcsú; Járai-Szabó, Ferenc; Tél, Tamás; Néda, Zoltán

2013-04-01

The dynamics of a spring-block train placed on a moving conveyor belt is investigated both by simple experiments and computer simulations. The first block is connected by a spring to an external static point and, due to the dragging effect of the belt, the blocks undergo complex stick-slip dynamics. A qualitative agreement with the experimental results can be achieved only by taking into account the spatial inhomogeneity of the friction force on the belt's surface, modeled as noise. As a function of the velocity of the conveyor belt and the noise strength, the system exhibits complex, self-organized critical, sometimes chaotic, dynamics and phase transition-like behavior. Noise-induced chaos and intermittency is also observed. Simulations suggest that the maximum complexity of the dynamical states is achieved for a relatively small number of blocks (around five).

The constitutionality of mandatory seat belt laws.

DOT National Transportation Integrated Search

1986-01-01

Low seat belt usage rates have persisted for years despite efforts to educate people about belts' benefits. There is ample documentation of the contribution of seat belts to saving lives and reducing injury. The emotional and pecuniary toll of the fa...

Atomic-Scale Design of Iron Fischer-Tropsch Catalysts; A Combined Computational Chemistry, Experimental, and Microkinetic Modeling Approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manos Mavrikakis; James Dumesic; Rahul Nabar

2008-09-29

This work focuses on (1) searching/summarizing published Fischer-Tropsch synthesis (FTS) mechanistic and kinetic studies of FTS reactions on iron catalysts; (2) preparation and characterization of unsupported iron catalysts with/without potassium/platinum promoters; (3) measurement of H{sub 2} and CO adsorption/dissociation kinetics on iron catalysts using transient methods; (3) analysis of the transient rate data to calculate kinetic parameters of early elementary steps in FTS; (4) construction of a microkinetic model of FTS on iron, and (5) validation of the model from collection of steady-state rate data for FTS on iron catalysts. Three unsupported iron catalysts and three alumina-supported iron catalysts weremore » prepared by non-aqueous-evaporative deposition (NED) or aqueous impregnation (AI) and characterized by chemisorption, BET, temperature-programmed reduction (TPR), extent-of-reduction, XRD, and TEM methods. These catalysts, covering a wide range of dispersions and metal loadings, are well-reduced and relatively thermally stable up to 500-600 C in H{sub 2} and thus ideal for kinetic and mechanistic studies. Kinetic parameters for CO adsorption, CO dissociation, and surface carbon hydrogenation on these catalysts were determined from temperature-programmed desorption (TPD) of CO and temperature programmed surface hydrogenation (TPSR), temperature-programmed hydrogenation (TPH), and isothermal, transient hydrogenation (ITH). A microkinetic model was constructed for the early steps in FTS on polycrystalline iron from the kinetic parameters of elementary steps determined experimentally in this work and from literature values. Steady-state rate data were collected in a Berty reactor and used for validation of the microkinetic model. These rate data were fitted to 'smart' Langmuir-Hinshelwood rate expressions derived from a sequence of elementary steps and using a combination of fitted steady-state parameters and parameters specified from the transient

Safety belt promotion: theory and practice.

PubMed

Nelson, G D; Moffit, P B

1988-02-01

The purpose of this paper is to provide practitioners a rationale and description of selected theoretically based approaches to safety belt promotion. Theory failure is a threat to the integrity and effectiveness of safety belt promotion. The absence of theory driven programs designed to promote safety belt use is a concern of this paper. Six theoretical models from the social and behavioral sciences are reviewed with suggestions for application to promoting safety belt use and include Theory of Reasoned Action, the Health Belief Model, Fear Arousal, Operant Learning, Social Learning Theory, and Diffusion of Innovations. Guidelines for the selection and utilization of theory are discussed.

Handling of Atomic Data

NASA Astrophysics Data System (ADS)

Rauch, T.; Deetjen, J. L.

2003-01-01

State-of-the-art NLTE model atmosphere codes have arrived at a high level of ``numerical'' sophistication and are an adequate tool to analyze the available high-quality spectra from the infrared to the X-ray wavelength range. The computational capacities allow the calculation which include all elements from hydrogen up to the iron group and the lack of reliable atomic data has become a crucial problem for further progress. We summarize briefly the available sources of atomic data and how these are implemented in the Tübingen Model Atmosphere Package (TMAP).

Effective use of tea to limit dietary iron available to starlings (Sturnus vulgaris).

PubMed

Seibels, Bob; Lamberski, Nadine; Gregory, Christopher R; Slifka, Kerri; Hagerman, Ann E

2003-09-01

Wild-caught starlings (Sturnus vulgaris) were fed an iron-enriched diet, with or without supplemental black tea leaves, to determine whether tea-derived tannins would prevent intestinal iron absorption. Hepatic biopsies were obtained to determine hepatic iron concentrations by atomic absorption spectroscopy. Hepatic iron concentrations increased significantly (P = 0.04) in 21 birds that consumed only the iron-enriched diet for 6 mo but not in the 20 birds that consumed the iron-enriched diet with tea leaf supplementation for the same time period.

Surface structure. Subatomic resolution force microscopy reveals internal structure and adsorption sites of small iron clusters.

PubMed

Emmrich, Matthias; Huber, Ferdinand; Pielmeier, Florian; Welker, Joachim; Hofmann, Thomas; Schneiderbauer, Maximilian; Meuer, Daniel; Polesya, Svitlana; Mankovsky, Sergiy; Ködderitzsch, Diemo; Ebert, Hubert; Giessibl, Franz J

2015-04-17

Clusters built from individual iron atoms adsorbed on surfaces (adatoms) were investigated by atomic force microscopy (AFM) with subatomic resolution. Single copper and iron adatoms appeared as toroidal structures and multiatom clusters as connected structures, showing each individual atom as a torus. For single adatoms, the toroidal shape of the AFM image depends on the bonding symmetry of the adatom to the underlying structure [twofold for copper on copper(110) and threefold for iron on copper(111)]. Density functional theory calculations support the experimental data. The findings correct our previous work, in which multiple minima in the AFM signal were interpreted as a reflection of the orientation of a single front atom, and suggest that dual and triple minima in the force signal are caused by dimer and trimer tips, respectively. Copyright © 2015, American Association for the Advancement of Science.

2003 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2003-08-01

The objective of this study was to establish 2003 safety belt and child safety seat usage rates in Kentucky. The 2003 survey continues to document the results after enactment of a statewide mandatory safety belt law in 1994 and safety belt enforcemen...

2004 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2004-08-01

The objective of this study was to establish 2004 safety belt and child safety seat usage rates in Kentucky. The 2004 survey continues to document the results after enactment of a statewide mandatory safety belt law in 1994 and safety belt enforcemen...

Electronic structure and reactivity of three-coordinate iron complexes.

PubMed

Holland, Patrick L

2008-08-01

[Reaction: see text]. The identity and oxidation state of the metal in a coordination compound are typically thought to be the most important determinants of its reactivity. However, the coordination number (the number of bonds to the metal) can be equally influential. This Account describes iron complexes with a coordination number of only three, which differ greatly from iron complexes with octahedral (six-coordinate) geometries with respect to their magnetism, electronic structure, preference for ligands, and reactivity. Three-coordinate complexes with a trigonal-planar geometry are accessible using bulky, anionic, bidentate ligands (beta-diketiminates) that steer a monodentate ligand into the plane of their two nitrogen donors. This strategy has led to a variety of three-coordinate iron complexes in which iron is in the +1, +2, and +3 oxidation states. Systematic studies on the electronic structures of these complexes have been useful in interpreting their properties. The iron ions are generally high spin, with singly occupied orbitals available for pi interactions with ligands. Trends in sigma-bonding show that iron(II) complexes favor electronegative ligands (O, N donors) over electropositive ligands (hydride). The combination of electrostatic sigma-bonding and the availability of pi-interactions stabilizes iron(II) fluoride and oxo complexes. The same factors destabilize iron(II) hydride complexes, which are reactive enough to add the hydrogen atom to unsaturated organic molecules and to take part in radical reactions. Iron(I) complexes use strong pi-backbonding to transfer charge from iron into coordinated alkynes and N 2, whereas iron(III) accepts charge from a pi-donating imido ligand. Though the imidoiron(III) complex is stabilized by pi-bonding in the trigonal-planar geometry, addition of pyridine as a fourth donor weakens the pi-bonding, which enables abstraction of H atoms from hydrocarbons. The unusual bonding and reactivity patterns of three

Formation of biomineral iron oxides compounds in a Fe hyperaccumulator plant: Imperata cylindrica (L.) P. Beauv.

PubMed

Fuente, V; Rufo, L; Juárez, B H; Menéndez, N; García-Hernández, M; Salas-Colera, E; Espinosa, A

2016-01-01

We report a detailed work of composition and location of naturally formed iron biominerals in plant cells tissues grown in iron rich environments as Imperata cylindrica. This perennial grass grows on the Tinto River banks (Iberian Pyritic Belt) in an extreme acidic ecosystem (pH∼2.3) with high concentration of dissolved iron, sulphate and heavy metals. Iron biominerals were found at the cellular level in tissues of root, stem and leaf both in collected and laboratory-cultivated plants. Iron accumulated in this plant as a mix of iron compounds (mainly as jarosite, ferrihydrite, hematite and spinel phases) was characterized by X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), Mössbauer spectroscopy (MS), magnetometry (SQUID), electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX; TEM-EDX; HRSTEM). A low fraction of phosphorous was detected in this iron hyperaccumulator plant. Root and rhizomes tissues present a high proportion of ferromagnetic iron oxide compounds. Iron oxides-rich zones are localized in electron dense intra and inter-cellular aggregates that appear as dark deposits covering the inner membrane and organelles of the cell. This study aims to contribute to a better understanding of the mechanisms of accumulation, transport, distribution of iron in Imperata cylindrica. Copyright © 2015 Elsevier Inc. All rights reserved.

Teens and seat belt use: What makes them click?

PubMed

Shults, Ruth A; Haegerich, Tamara M; Bhat, Geeta; Zhang, Xinjian

2016-06-01

Motor vehicle crashes kill more adolescents in the United States than any other cause, and often the teen is not wearing a seat belt. Using data from the 2011 Youth Risk Behavior Surveys from 38 states, we examined teens' self-reported seat belt use while riding as a passenger and identified individual characteristics and environmental factors associated with always wearing a seat belt. Only 51% of high school students living in 38 states reported always wearing a seat belt when riding as a passenger; prevalence varied from 32% in South Dakota to 65% in Delaware. Seat belt use was 11 percentage points lower in states with secondary enforcement seat belt laws compared to states with primary enforcement laws. Racial/ethnic minorities, teens living in states with secondary enforcement seat belt laws, and those engaged in substance use were least likely to always wear their seat belts. The likelihood of always being belted declined steadily as the number of substance use behaviors increased. Seat belt use among teens in the United States remains unacceptably low. Results suggest that environmental influences can compound individual risk factors, contributing to even lower seat belt use among some subgroups. This study provides the most comprehensive state-level estimates to date of seat belt use among U.S. teens. This information can be useful when considering policy options to increase seat belt use and for targeting injury prevention interventions to high-risk teens. States can best increase teen seat belt use by making evidence-informed decisions about state policy options and prevention strategies. Published by Elsevier Ltd.

Iron(II)-Catalyzed Iron Atom Exchange and Mineralogical Changes in Iron-rich Organic Freshwater Flocs: An Iron Isotope Tracer Study.

PubMed

ThomasArrigo, Laurel K; Mikutta, Christian; Byrne, James; Kappler, Andreas; Kretzschmar, Ruben

2017-06-20

In freshwater wetlands, organic flocs are often found enriched in trace metal(loid)s associated with poorly crystalline Fe(III)-(oxyhydr)oxides. Under reducing conditions, flocs may become exposed to aqueous Fe(II), triggering Fe(II)-catalyzed mineral transformations and trace metal(loid) release. In this study, pure ferrihydrite, a synthetic ferrihydrite-polygalacturonic acid coprecipitate (16.7 wt % C), and As- (1280 and 1230 mg/kg) and organic matter (OM)-rich (18.1 and 21.8 wt % C) freshwater flocs dominated by ferrihydrite and nanocrystalline lepidocrocite were reacted with an isotopically enriched 57 Fe(II) solution (0.1 or 1.0 mM Fe(II)) at pH 5.5 and 7. Using a combination of wet chemistry, Fe isotope analysis, X-ray absorption spectroscopy (XAS), 57 Fe Mössbauer spectroscopy and X-ray diffraction, we followed the Fe atom exchange kinetics and secondary mineral formation over 1 week. When reacted with Fe(II) at pH 7, pure ferrihydrite exhibited rapid Fe atom exchange at both Fe(II) concentrations, reaching 76 and 89% atom exchange in experiments with 0.1 and 1 mM Fe(II), respectively. XAS data revealed that it transformed into goethite (21%) at the lower Fe(II) concentration and into lepidocrocite (73%) and goethite (27%) at the higher Fe(II) concentration. Despite smaller Fe mineral particles in the coprecipitate and flocs as compared to pure ferrihydrite (inferred from Mössbauer-derived blocking temperatures), these samples showed reduced Fe atom exchange (9-30% at pH 7) and inhibited secondary mineral formation. No release of As was recorded for Fe(II)-reacted flocs. Our findings indicate that carbohydrate-rich OM in flocs stabilizes poorly crystalline Fe minerals against Fe(II)-catalyzed transformation by surface-site blockage and/or organic Fe(II) complexation. This hinders the extent of Fe atom exchange at mineral surfaces and secondary mineral formation, which may consequently impair Fe(II)-activated trace metal(loid) release. Thus, under short

Oxygen Activation at Mononuclear Nonheme Iron Centers: A Superoxo Perspective

PubMed Central

Mukherjee, Anusree; Cranswick, Matthew A.; Chakraborti, Mrinmoy; Paine, Tapan K.; Fujisawa, Kiyoshi; Münck, Eckard; Que, Lawrence

2010-01-01

Dioxygen activation by iron enzymes is responsible for many metabolically important transformations in biology. Often a high-valent iron-oxo oxidant is proposed to form upon dioxygen activation at a mononuclear nonheme iron center, presumably via intervening iron-superoxo and iron-peroxo species. While iron(IV)-oxo intermediates have been trapped and characterized in enzymes and models, less is known of the putative iron(III)-superoxo species. Utilizing a synthetic model for the 2-oxoglutarate-dependent monoiron enzymes, [(TpiPr2)FeII(O2CC(O)CH3)], we have obtained indirect evidence for the formation of the putative iron(III)-superoxo species, which can undergo one-electron reduction, hydrogen-atom transfer, or conversion to an iron(IV)-oxo species, depending on the reaction conditions. These results demonstrate the various roles the iron(III)-superoxo species can play in the course of dioxygen activation at a nonheme iron center. PMID:20380464

Oxygen activation at mononuclear nonheme iron centers: a superoxo perspective.

PubMed

Mukherjee, Anusree; Cranswick, Matthew A; Chakrabarti, Mrinmoy; Paine, Tapan K; Fujisawa, Kiyoshi; Münck, Eckard; Que, Lawrence

2010-04-19

Dioxygen (O(2)) activation by iron enzymes is responsible for many metabolically important transformations in biology. Often a high-valent iron oxo oxidant is proposed to form upon O(2) activation at a mononuclear nonheme iron center, presumably via intervening iron superoxo and iron peroxo species. While iron(IV) oxo intermediates have been trapped and characterized in enzymes and models, less is known of the putative iron(III) superoxo species. Utilizing a synthetic model for the 2-oxoglutarate-dependent monoiron enzymes, [(Tp(iPr2))Fe(II)(O(2)CC(O)CH(3))], we have obtained indirect evidence for the formation of the putative iron(III) superoxo species, which can undergo one-electron reduction, hydrogen-atom transfer, or conversion to an iron(IV) oxo species, depending on the reaction conditions. These results demonstrate the various roles that the iron(III) superoxo species can play in the course of O(2) activation at a nonheme iron center.

1,4-Iron Migration for Expedient Allene Annulations through Iron-Catalyzed C-H/N-H/C-O/C-H Functionalizations.

PubMed

Mo, Jiayu; Müller, Thomas; Oliveira, João C A; Ackermann, Lutz

2018-06-25

C-H activation bears great potential for enabling sustainable molecular syntheses in a step- and atom-economical manner, with major advances having been realized with precious 4d and 5d transition metals. In contrast, we employed earth abundant, nontoxic iron catalysts for versatile allene annulations through a unique C-H/N-H/C-O/C-H functionalization sequence. The powerful iron catalysis occurred under external-oxidant-free conditions even at room temperature, while detailed mechanistic studies revealed an unprecedented 1,4-iron migration regime for facile C-H activations. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Effects of safety belt laws on safety belt use by American High School Seniors, 1986-2000.

PubMed

O'Malley, Patrick M; Wagenaar, Alexander C

2004-01-01

This manuscript evaluates the effects of enactment of state laws that required safety belt use in various U.S. states between 1986 and 2000. Safety belt use was assessed using nationally representative cross-sectional samples of high school seniors; evaluation of the effects of laws used data from over 2,000 high school seniors before and about 3,300 after the laws took effect in 20 states. Belt use was found to increase significantly between 1986 and 2000, and the laws contributed significantly to that increase. Increases were similar for students differing by gender, race/ethnicity, parent education, grades, truancy, evenings out per week, miles driven per week, and an index of illicit drug use. The data show that although the laws have increased belt use, use is not universal and continued efforts are needed. This study shows that many teenagers fail to use belts when there is a secondary use law; an implication is that primary laws would be more efficacious in increasing use among this vulnerable population.

Evidence of a reduction reaction of oxidized iron/cobalt by boron atoms diffused toward naturally oxidized surface of CoFeB layer during annealing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sato, Soshi, E-mail: sato.soshi@cies.tohoku.ac.jp; Honjo, Hiroaki; Niwa, Masaaki

2015-04-06

We have investigated the redox reaction on the surface of Ta/CoFeB/MgO/CoFeB magnetic tunnel junction stack samples after annealing at 300, 350, and 400 °C for 1 h using angle-resolved X-ray photoelectron spectroscopy for precise analysis of the chemical bonding states. At a capping tantalum layer thickness of 1 nm, both the capping tantalum layer and the surface of the underneath CoFeB layer in the as-deposited stack sample were naturally oxidized. By comparison of the Co 2p and Fe 2p spectra among the as-deposited and annealed samples, reduction of the naturally oxidized cobalt and iron atoms occurred on the surface of the CoFeB layer.more » The reduction reaction was more significant at higher annealing temperature. Oxidized cobalt and iron were reduced by boron atoms that diffused toward the surface of the top CoFeB layer. A single CoFeB layer was prepared on SiO{sub 2}, and a confirmatory evidence of the redox reaction with boron diffusion was obtained by angle-resolved X-ray photoelectron spectroscopy analysis of the naturally oxidized surface of the CoFeB single layer after annealing. The redox reaction is theoretically reasonable based on the Ellingham diagram.« less

Nifedipine Increases Iron Content in WKPT-0293 Cl.2 Cells via Up-Regulating Iron Influx Proteins

PubMed Central

Yu, Shuang-Shuang; Jiang, Li-Rong; Ling, Yan; Qian, Zhong-Ming; Zhou, Yu-Fu; Li, Juan; Ke, Ya

2017-01-01

Nifedipine was reported to enhance urinary iron excretion in iron overloaded mice. However, it remains unknown how nifedipine stimulates urinary iron excretion in the kidney. We speculated that nifedipine might inhibit the TfR1/ DMT1 (transferrin receptor 1/divalent metal transporter1)-mediated iron uptake by proximal tubule cells in addition to blocking L-type Ca2+ channels, leading to an increase in iron in lumen-fluid and then urinary iron excretion. To test this hypothesis, we investigated the effects of nifedipine on iron content and expression of TfR1, DMT1 and ferroportin1 (Fpn1) in WKPT-0293 Cl.2 cells of the S1 segment of the proximal tubule in rats, using a graphite furnace atomic absorption spectrophotometer and Western blot analysis, respectively. We demonstrated for the first time that nifedipine significantly enhanced iron content as well as TfR1 and DMT1 expression and had no effect on Fpn1 levels in the cells. We also found that ferric ammonium citrate decreased TfR1 levels, increased Fpn1 expression and had no effect on DMT1 content, while co-treatment with nifedipine and FAC increase TfR1 and DMT1 expression and also had no effect on Fpn1 levels. These findings suggest that the nifedipine-induced increase in cell iron may mainly be due to the corresponding increase in TfR1 and DMT1 expression and also imply that the effects of nifedipine on iron transport in proximal tubule cells can not explain the increase in urinary iron excretion. PMID:28243203

Effectiveness of media and enforcement campaigns in increasing seat belt usage rates in a state with a secondary seat belt law.

PubMed

Vasudevan, Vinod; Nambisan, Shashi S; Singh, Ashok K; Pearl, Traci

2009-08-01

In 2005, in terms of seat belt usage rates, Nevada ranked third nationally and first among states with secondary seat belt use enforcement laws in the United States. An effective combination of a media-based education and enforcement campaign helped in this regard. The objective of this article is to document the effectiveness of enforcement and media-based education and outreach campaigns on the seat belt usage rates in Nevada, a state with a secondary seat belt usage law. Observational data on seat belt usage and passenger fatality data are used to evaluate the effectiveness of enforcement campaigns and media-based education and outreach campaigns. Data based on observations of about 40,000 vehicles in each of the years 2003 to 2005 were analyzed. Statistical analyses show that a significant increase in seat belt usage rates among both drivers and passengers for both genders resulted from the accompanying the media and enforcement campaigns. The results from this study indicate that effective and well-planned media/enforcement campaigns can have a significant impact on seat belt usage rates even in a state where the enforcement of seat belt laws can only be as a secondary violation. They validate and expand on findings from other efforts documented in the literature. These results demonstrate that, if coordinated properly, media and enforcement campaigns work very effectively in increasing seat belt usage rates even in states with secondary seat belt laws.

GAS-ATOMIZED SPRAY SCRUBBER EVALUATION

EPA Science Inventory

The report gives results of fine particle collection efficiency measurements of a gas-atomized spray scrubber, cleaning effluent gas from a No. 7 gray iron cupola. Tests were made at several levels of pressure drop and liquid/gas ratio. Particle size measurements on inlet and out...

Matrix Infrared Spectra of Manganese and Iron Isocyanide Complexes.

PubMed

Chen, Xiuting; Li, Qingnuan; Andrews, Lester; Gong, Yu

2017-11-22

Mono and diisocyanide complexes of manganese and iron were prepared via the reactions of laser-ablated manganese and iron atoms with (CN) 2 in an argon matrix. Product identifications were performed based on the characteristic infrared absorptions from isotopically labeled (CN) 2 experiments as compared with computed values for both cyanides and isocyanides. Manganese atoms reacted with (CN) 2 to produce Mn(NC) 2 upon λ > 220 nm irradiation, during which MnNC was formed mainly as a result of the photoinduced decomposition of Mn(NC) 2 . Similar reaction products FeNC and Fe(NC) 2 were formed during the reactions of Fe and (CN) 2 . All the product molecules together with the unobserved cyanide isomers were predicted to have linear geometries at the B3LYP level of theory. The cyanide complexes of manganese and iron were computed to be more stable than the isocyanide isomers with energy differences between 0.4 and 4 kcal/mol at the CCSD(T) level. Although manganese and iron cyanide molecules are slightly more stable according to the theory, no absorption can be assigned to these isomers in the region above the isocyanides possibly due to their low infrared intensities.

Mandatory seat belt use laws.

DOT National Transportation Integrated Search

1985-01-01

The purposes of this study were to review mandatory seat belt use laws as they have been used around the world, to forecast the impact of such a law in Virginia, and, if appropriate, to propose a mandatory seat belt law for inclusion in the Code of V...

Numerical modeling of fold-and-thrust belts: Applications to Kuqa foreland fold belt, China

NASA Astrophysics Data System (ADS)

Yin, H.; Morgan, J. K.; Zhang, J.; Wang, Z.

2009-12-01

We constructed discrete element models to simulate the evolution of fold-and-thrust belts. The impact of rock competence and decollement strength on the geometric pattern and deformation mechanics of fold-and-thrust belts has been investigated. The models reproduced some characteristic features of fold-and-thrust belts, such as faulted detachment folds, pop-ups, far-traveled thrust sheets, passive-roof duplexes, and back thrusts. In general, deformation propagates farther above a weak decollement than above a strong decollement. Our model results confirm that fold-and-thrust belts with strong frictional decollements develop relatively steep and narrow wedges formed by closely spaced imbricate thrust slices, whereas fold belts with weak decollements form wide low-taper wedges composed of faulted detachment folds, pop-ups, and back thrusts. Far-traveled thrust sheets and passive-roof duplexes are observed in the model with a strong lower decollement and a weak upper detachment. Model results also indicate that the thickness of the weak layer is critical. If it is thick enough, it acts as a ductile layer that is able to flow under differential stress, which helps to partition deformation above and below it. The discrete element modeling results were used to interpret the evolution of Kuqa Cenozoic fold-and-thrust belt along northern Tarim basin, China. Seismic and well data show that the widely distributed Paleogene rock salt has a significant impact on the deformation in this area. Structures beneath salt are closely spaced imbricate thrust and passive-roof duplex systems. Deformation above salt propagates much farther than below the salt. Faults above salt are relatively wide spaced. A huge controversy over the Kuqa fold-and-thrust belt is whether it is thin-skinned or thick-skinned. With the insights from DEM results, we suggest that Kuqa structures are mostly thin-skinned with Paleogene salt as decollement, except for the rear part near the backstop, where the

The application of inverse Broyden's algorithm for modeling of crack growth in iron crystals.

PubMed

Telichev, Igor; Vinogradov, Oleg

2011-07-01

In the present paper we demonstrate the use of inverse Broyden's algorithm (IBA) in the simulation of fracture in single iron crystals. The iron crystal structure is treated as a truss system, while the forces between the atoms situated at the nodes are defined by modified Morse inter-atomic potentials. The evolution of lattice structure is interpreted as a sequence of equilibrium states corresponding to the history of applied load/deformation, where each equilibrium state is found using an iterative procedure based on IBA. The results presented demonstrate the success of applying the IBA technique for modeling the mechanisms of elastic, plastic and fracture behavior of single iron crystals.

Pattern of seat belt wearing in Nanjing, China

PubMed Central

Routley, V; Ozanne‐Smith, J; Li, D; Hu, X; Wang, P; Qin, Y

2007-01-01

Objective To describe the patterns of seat belt wearing in Nanjing, China for drivers, front seat passengers, and rear occupants of motor vehicles. Design Roadside observational study. Setting Four sites in central and northern Nanjing during daylight hours over 1 week in April 2005. Subjects Drivers and passengers of 17 147 cars, taxis, goods vans, and pickups, which traveled in the inside traffic lane. Main outcome measures Percentage seat belt wearing for each of seating position, age/sex, time of day, vehicle type, day of week. Results The rate of seat belt wearing was significantly higher in drivers (67.3%, 95% CI 66.6 to 68.0) than front seat passengers (18.9%, 95% CI, 18.0 to 19.8). It was negligible for second front seat passengers (2.6%, 95% CI 0.3 to 4.9) and rear seat passengers (0.5%, 95% CI 0.3 to 0.7). Belt tampering, such that protection would be reduced in the event of a crash, was observed for 18.5% of taxi drivers. Drivers were most likely to wear seat belts in cars and vans and at a city roundabout; front seat passengers were most likely to wear seat belts in non‐taxi vehicles, during the evening rush hour, if the driver was wearing a belt, and on the local north road. Drivers were least likely to wear a belt in the early morning, in pickups and taxis, on Tuesday (or the following week), and on the local north road; front seat passengers were least likely to wear a belt in taxis and if the driver was not wearing a belt. Conclusions Rates of seat belt wearing by passengers were low despite national legislation and provincial regulations coming into effect several months before the survey. Combined education and enforcement are necessary accompaniments to legislation. PMID:18056315

Iron chalcogenide superconductors at high magnetic fields

PubMed Central

Lei, Hechang; Wang, Kefeng; Hu, Rongwei; Ryu, Hyejin; Abeykoon, Milinda; Bozin, Emil S; Petrovic, Cedomir

2012-01-01

Iron chalcogenide superconductors have become one of the most investigated superconducting materials in recent years due to high upper critical fields, competing interactions and complex electronic and magnetic phase diagrams. The structural complexity, defects and atomic site occupancies significantly affect the normal and superconducting states in these compounds. In this work we review the vortex behavior, critical current density and high magnetic field pair-breaking mechanism in iron chalcogenide superconductors. We also point to relevant structural features and normal-state properties. PMID:27877518

An ab initio study on the effect of iron atom junction on transport characteristics of carbon-silicon mixed chain

NASA Astrophysics Data System (ADS)

Hu, Wei; Zhou, Qinghua; Liu, Wenhua; Liang, Yan; Wang, Tao; Wan, Haiqing

2018-04-01

The effect of iron atom junction on transport characteristics of carbon-silicon mixed chain has been studied from an ab initio study. At zero bias, the Fe(CSi)n system appears to be the decrease of the conductance as the number of the Si-C pairs in the chain increases (n changes). When n > 5, the conductance tends to zero. These changes are independent of the transferring charge of the system, depending on the coupling of the electrodes and the central region. Under bias, the higher the bias voltage, the bigger the transmission coefficient of the system, and the transmission peak moves closer to the Fermi level. The I-V curves of Fe(CSi)2 and Fe (CSi)3 are linear, showing the behavior of metal resistance.

The development of an electronic system to continually monitor, indicate and control, 'belt slippage' in industrial friction 'V' belt drive transmission systems

NASA Astrophysics Data System (ADS)

Brown, R. E.

2012-05-01

Belts have been used for centuries as a mechanism to transfer power from some form of drive system to a variety of load systems. Within industry today, many designs of belts but particularly friction, trapezoidal shaped 'V' belts are used and generally transfer power generated by electrical motors to numerous forms of driven load systems. It is suggested that belt systems, through their simplicity are sadly neglected by maintenance functions and generally are left unattended until high degrees of 'belt slippage' through loss of friction or 'belt breakage' provokes maintenance attention. These circumstances are most often identified through the reduced or loss of manufacturing production or the occurrence of catastrophic circumstances such as fire caused through excessive friction/ high belt slippage conditions. Obviously, these situations incur financial losses to companies and in some cases the near loss of the company's main manufacturing plant. Consequently, a satisfactory, viable solution is currently sought by industry to improve on current labour intensive maintenance practices. This paper will present an account of the development of an industrially robust, accurate and repeatable electronic system which continually monitors and indicates the degree of 'slippage' in a 'V' belt drive transmission system and in the circumstance of belt breakage or high belt slippage will enable and control the switching off the drive motor.

Grinding Glass Disks On A Belt Sander

NASA Technical Reports Server (NTRS)

Lyons, James J., III

1995-01-01

Small machine attached to table-top belt sander makes possible to use belt sander to grind glass disk quickly to specified diameter within tolerance of about plus or minus 0.002 in. Intended to be used in place of production-shop glass grinder. Held on driveshaft by vacuum, glass disk rotated while periphery ground by continuous sanding belt.

Oxidation-Induced Degradable Nanogels for Iron Chelation

NASA Astrophysics Data System (ADS)

Liu, Zhi; Wang, Yan; Purro, Max; Xiong, May P.

2016-02-01

Iron overload can increase cellular oxidative stress levels due to formation of reactive oxygen species (ROS); untreated, it can be extremely destructive to organs and fatal to patients. Since elevated oxidative stress levels are inherent to the condition in such patients, oxidation-induced degradable nanogels for iron chelation were rationally designed by simultaneously polymerizing oxidation-sensitive host-guest crosslinkers between β-cyclodextrin (β-CD) and ferrocene (Fc) and iron chelating moieties composed of deferoxamine (DFO) into the final gel scaffold in reverse emulsion reaction chambers. UV-Vis absorption and atomic absorption spectroscopy (AAS) was used to verify iron chelating capability of nanogels. These materials can degrade into smaller chelating fragments at rates proportional to the level of oxidative stress present. Conjugating DFO reduces the cytotoxicity of the chelator in the macrophage cells. Importantly, the nanogel can effectively reduce cellular ferritin expression in iron overloaded cells and regulate intracellular iron levels at the same time, which is important for maintaining a homeostatic level of this critical metal in cells.

Oxidation-Induced Degradable Nanogels for Iron Chelation

PubMed Central

Liu, Zhi; Wang, Yan; Purro, Max; Xiong, May P.

2016-01-01

Iron overload can increase cellular oxidative stress levels due to formation of reactive oxygen species (ROS); untreated, it can be extremely destructive to organs and fatal to patients. Since elevated oxidative stress levels are inherent to the condition in such patients, oxidation-induced degradable nanogels for iron chelation were rationally designed by simultaneously polymerizing oxidation-sensitive host-guest crosslinkers between β-cyclodextrin (β-CD) and ferrocene (Fc) and iron chelating moieties composed of deferoxamine (DFO) into the final gel scaffold in reverse emulsion reaction chambers. UV-Vis absorption and atomic absorption spectroscopy (AAS) was used to verify iron chelating capability of nanogels. These materials can degrade into smaller chelating fragments at rates proportional to the level of oxidative stress present. Conjugating DFO reduces the cytotoxicity of the chelator in the macrophage cells. Importantly, the nanogel can effectively reduce cellular ferritin expression in iron overloaded cells and regulate intracellular iron levels at the same time, which is important for maintaining a homeostatic level of this critical metal in cells. PMID:26868174

Teaching Science: Seat Belt Science.

ERIC Educational Resources Information Center

Leyden, Michael B.

1994-01-01

Describes activities that will help students understand how car seat belts work, the limited reaction time available to passengers in an automobile accident, and the force of impact in a car collision. These activities will provide students with hands-on experiences that demonstrate the importance of always wearing seat belts while in an…

30 CFR 77.406 - Drive belts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND COAL MINES Safeguards for Mechanical Equipment § 77.406 Drive belts. (a) Drive belts shall not be shifted while in motion unless the...

The Archaen volcanic facies in the Migori segment, Nyanza greenstone belt, Kenya: stratigraphy, geochemistry and mineralisation

NASA Astrophysics Data System (ADS)

Ichang'l, D. W.; MacLean, W. H.

The Migori segment is an 80 by 20 km portion of the Nyanza greenstone belt which forms the northern part of the Archean Tanzanian Craton in western Kenya, northern Tanzania and southeastern Uganda. It consists of two volcanic centres, each with central, proximal and distal volcanic facies, comprising the Migori Group, the Macalder and Lolgorien Subgroups, and eleven volcano-sedimentary formations. The centres are separated by a basin of tuffs and greywacke turbidites. The volcanics are bimodal mafic basalt and dolerite ( Zr/Y = 3.8 - 6.5, La N/Yb N = 1.0 - 2.4) , and felsic calc-alkaline dacite-rhyolite ( Zr/Y = 10 - 21, La N/Yb N = 19 - 42 ) and high-K dacite ( Zr/Y = 9 - 16, La N/Yb N = 21 - 22 ). Felsic units form approximately three-fourths of the volcanic stratigraphy. Basalts, calc-alkaline dacites and rhyolites were deposited in a submarine environment, but the voluminous high-K dacites were erupted subaerially. The turbidites contain units of iron-formations. Granitic intrusions are chemically continuous with the high-K dacites. The felsic volcanics are anologous to those found at modern volcanic arc subduction settings involving continental crust. The Macalder ZnCuAuAg volcanogenic massive sulphide deposits is in central facies basalts-greywacke-rhyolite. Gold mineralisation occurs in proximal facies tuffs and iron formation, and in oblique and semi-conformable quartz veins. Greenstones in the Nyanza belt are dominated by calc-alkaline felsic volcanics in constrast to the komatiite-tholeiitic basalt volcanism in the Kaapvaal Craton of South Africa, and a mixture of the two types in the Zimbabwe Craton.

Effect of a weightlifting belt on spinal shrinkage.

PubMed

Bourne, N D; Reilly, T

1991-12-01

Spinal loading during weightlifting results in a loss of stature which has been attributed to a decrease in height of the intervertebral discs--so-called 'spinal shrinkage'. Belts are often used during the lifting of heavy weights, purportedly to support, stabilize and thereby attenuate the load on the spine. The purpose of this study was to examine the effects of a standard weightlifting belt in attenuating spinal shrinkage. Eight male subjects with a mean age of 24.8 years performed two sequences of circuit weight-training, one without a belt and on a separate occasion with a belt. The circuit training regimen consisted of six common weight-training exercises. These were performed in three sets of ten with a change of exercise after each set of ten repetitions. A stadiometer sensitive to within 0.01 mm was used to record alterations in stature. Measurements of stature were taken before and after completion of the circuit. The absolute visual analogue scale (AVAS) was used to measure the discomfort and pain intensity resulting from each of the two conditions. The circuit weight-training caused stature losses of 3.59mm without the belt and 2.87 mm with the belt (P greater than 0.05). The subjects complained of significantly less discomfort when the belt was worn (P less than 0.05). The degree of shrinkage was significantly correlated (r = 0.752, P less than 0.05) with perceived discomfort but only when the belt was not worn. These results suggest the potential benefits of wearing a weightlifting belt and support the hypothesis that the belt can help in stabilizing the trunk.

Effect of a weightlifting belt on spinal shrinkage.

PubMed Central

Bourne, N D; Reilly, T

1991-01-01

Spinal loading during weightlifting results in a loss of stature which has been attributed to a decrease in height of the intervertebral discs--so-called 'spinal shrinkage'. Belts are often used during the lifting of heavy weights, purportedly to support, stabilize and thereby attenuate the load on the spine. The purpose of this study was to examine the effects of a standard weightlifting belt in attenuating spinal shrinkage. Eight male subjects with a mean age of 24.8 years performed two sequences of circuit weight-training, one without a belt and on a separate occasion with a belt. The circuit training regimen consisted of six common weight-training exercises. These were performed in three sets of ten with a change of exercise after each set of ten repetitions. A stadiometer sensitive to within 0.01 mm was used to record alterations in stature. Measurements of stature were taken before and after completion of the circuit. The absolute visual analogue scale (AVAS) was used to measure the discomfort and pain intensity resulting from each of the two conditions. The circuit weight-training caused stature losses of 3.59mm without the belt and 2.87 mm with the belt (P greater than 0.05). The subjects complained of significantly less discomfort when the belt was worn (P less than 0.05). The degree of shrinkage was significantly correlated (r = 0.752, P less than 0.05) with perceived discomfort but only when the belt was not worn. These results suggest the potential benefits of wearing a weightlifting belt and support the hypothesis that the belt can help in stabilizing the trunk. Images Figure 1 PMID:1810615

Colors of Inner Disk Classical Kuiper Belt Objects

NASA Astrophysics Data System (ADS)

Romanishin, W.; Tegler, S. C.; Consolmagno, G. J.

2010-07-01

We present new optical broadband colors, obtained with the Keck 1 and Vatican Advanced Technology telescopes, for six objects in the inner classical Kuiper Belt. Objects in the inner classical Kuiper Belt are of interest as they may represent the surviving members of the primordial Kuiper Belt that formed interior to the current position of the 3:2 resonance with Neptune, the current position of the plutinos, or, alternatively, they may be objects formed at a different heliocentric distance that were then moved to their present locations. The six new colors, combined with four previously published, show that the ten inner belt objects with known colors form a neutral clump and a reddish clump in B-R color. Nonparametric statistical tests show no significant difference between the B-R color distribution of the inner disk objects compared to the color distributions of Centaurs, plutinos, or scattered disk objects. However, the B-R color distribution of the inner classical Kuiper Belt Objects does differ significantly from the distribution of colors in the cold (low inclination) main classical Kuiper Belt. The cold main classical objects are predominately red, while the inner classical belt objects are a mixture of neutral and red. The color difference may reveal the existence of a gradient in the composition and/or surface processing history in the primordial Kuiper Belt, or indicate that the inner disk objects are not dynamically analogous to the cold main classical belt objects.

COLORS OF INNER DISK CLASSICAL KUIPER BELT OBJECTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Romanishin, W.; Tegler, S. C.; Consolmagno, G. J., E-mail: wromanishin@ou.ed, E-mail: Stephen.Tegler@nau.ed, E-mail: gjc@specola.v

2010-07-15

We present new optical broadband colors, obtained with the Keck 1 and Vatican Advanced Technology telescopes, for six objects in the inner classical Kuiper Belt. Objects in the inner classical Kuiper Belt are of interest as they may represent the surviving members of the primordial Kuiper Belt that formed interior to the current position of the 3:2 resonance with Neptune, the current position of the plutinos, or, alternatively, they may be objects formed at a different heliocentric distance that were then moved to their present locations. The six new colors, combined with four previously published, show that the ten innermore » belt objects with known colors form a neutral clump and a reddish clump in B-R color. Nonparametric statistical tests show no significant difference between the B-R color distribution of the inner disk objects compared to the color distributions of Centaurs, plutinos, or scattered disk objects. However, the B-R color distribution of the inner classical Kuiper Belt Objects does differ significantly from the distribution of colors in the cold (low inclination) main classical Kuiper Belt. The cold main classical objects are predominately red, while the inner classical belt objects are a mixture of neutral and red. The color difference may reveal the existence of a gradient in the composition and/or surface processing history in the primordial Kuiper Belt, or indicate that the inner disk objects are not dynamically analogous to the cold main classical belt objects.« less

Water oxidation: High five iron

NASA Astrophysics Data System (ADS)

Lloret-Fillol, Julio; Costas, Miquel

2016-03-01

The oxidation of water is essential to the sustainable production of fuels using sunlight or electricity, but designing active, stable and earth-abundant catalysts for the reaction is challenging. Now, a complex containing five iron atoms is shown to efficiently oxidize water by mimicking key features of the oxygen-evolving complex in green plants.

OUTER RADIATION BELT AND AURORAS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gorchakov, E.V.

1961-01-01

Data obtained from Sputnik IH were used to determine the high-latitude boundary of the outer radiation belt and to interpret the nature of auroras. At the heights at which the auroras were observed, the outer boundary of the belt (69 deg north geomagnetic latitude) practically coincides with the auroral zone maximum (70 deg north geomagnetic latitude), while the maximum intensity of the outer belt near the earth lies at about 55 deg north geomagnetic latitude, i.e., at latitudes 15 deg below the auroral maximum. Consequently, auroras near the zone of maximum cannot be caused by the penetration into the atmospheremore » of electrons from the outer belt with energies on the order of 0.1 Mev (the mean energy of electrons in the outer belt). Other investigators have reported the detection of lowenergy streams at 55,000 to 75,000 km from the center of the earth in the equatorial plane. Moving toward the surface of the earth along the force lines of the magnetic field, electron streams of this type will reach the earth precisely in the region of the auroral zone maximum. It is considered possible that the electron streams are trapped at these distances from the earth and are at least partially responsible for auroras in the region of maximum. The existence of two maxima in the latitudinal distribution of auroral frequency, which attests to differert mechanisms of aurora formation, favors this hypothesis. In the region of the basic auroral maximum (70 deg north geomagnetic latitude) the auroras are the result of the invasion of belt particles, while in the region of the additional maximum (about 80 deg north geomagnetic latitude) they are caused by the direct penetration of corpuscular streams into the atmosphere. (OTS)« less

ScienceCast 76: The Radiation Belt Storm Probes

NASA Image and Video Library

2012-08-30

This morning NASA launched two heavily-shielded spacecraft directly into the Van Allen Belts. The Radiation Belt Storm Probes are on a two-year mission to study the Van Allen Belts and to unravel the mystery of their unpredictability.

Iron films deposited on porous alumina substrates

NASA Astrophysics Data System (ADS)

Yamada, Yasuhiro; Tanabe, Kenichi; Nishida, Naoki; Kobayashi, Yoshio

2016-12-01

Iron films were deposited on porous alumina substrates using an arc plasma gun. The pore sizes (120 - 250 nm) of the substrates were controlled by changing the temperature during the anodic oxidation of aluminum plates. Iron atoms penetrated into pores with diameters of less than 160 nm, and were stabilized by forming γ-Fe, whereas α-Fe was produced as a flat plane covering the pores. For porous alumina substrates with pore sizes larger than 200 nm, the deposited iron films contained many defects and the resulting α-Fe had smaller hyperfine magnetic fields. In addition, only a very small amount of γ-Fe was obtained. It was demonstrated that the composition and structure of an iron film can be affected by the surface morphology of the porous alumina substrate on which the film is grown.

Effectiveness of safety belt warning and interlock systems

DOT National Transportation Integrated Search

1973-04-01

Rental cars in Fayetteville, N.C., were equipped with four seat belt and warning systems: (Phase I) detachable shoulder and lap belt, no warning system; (Phase II) detachable shoulder and lap belt, warning system (January 1, 1972 standard); (Phase II...

Blood and hair lead in children with different extents of iron deficiency in Karachi

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ataur Rahman, Muhammad; Rahman, Bushra; Saeed Ahmad, Muhammad

Childhood iron deficiency has a high incidence in Pakistan. Some but not all studies have shown that dietary iron deficiency may cause increased absorption of lead as both compete for the same transporters in the small intestine. Therefore, children in Pakistan, residing in heavily polluted cities like Karachi may be prone to lead poisoning. This hypothesis was tested by investigating blood and hair lead concentrations in children from Karachi who were divided into four groups of iron status; normal, borderline iron deficiency, iron deficiency and iron deficiency anaemia. A prospective observational study was conducted where 269 children were categorized intomore » four groups of iron status using the World Health Organization criteria and one based on soluble transferrin receptor measurements. Blood iron status was determined using a full blood count, serum iron, ferritin, transferrin saturation and soluble transferrin receptor measurements. Blood lead was determined by graphite atomic absorption spectroscopy, whereas hair lead was assessed using an inductively coupled plasma atomic emission spectroscopy technique. Blood lead concentrations were significantly higher in children with iron deficiency anaemia (mean [95% confidence intervals] were 24.9 [22.6-27.2] {mu}g/dL) compared to those with normal iron status (19.1 [16.8-21.4] {mu}g/dL) using WHO criteria. In contrast, hair lead content was not significantly different in children of different iron status. Our findings reinforce the importance of not only reducing environmental lead pollution but also the development of national health strategies to reduce childhood iron deficiency in Pakistan.« less

Deviation from Boltzmann distribution in excited energy levels of singly-ionized iron in an argon glow discharge plasma for atomic emission spectrometry

NASA Astrophysics Data System (ADS)

Zhang, Lei; Kashiwakura, Shunsuke; Wagatsuma, Kazuaki

2012-01-01

A Boltzmann plot for many iron ionic lines having excitation energies of 4.7-9.1 eV was investigated in an argon glow discharge plasma when the discharge parameters, such as the voltage/current and the gas pressure, were varied. A Grimm-style radiation source was employed in a DC voltage range of 400-800 V at argon pressures of 400-930 Pa. The plot did not follow a linear relationship over a wide range of the excitation energy, but it yielded a normal Boltzmann distribution in the range of 4.7-5.8 eV and a large overpopulation in higher-lying excitation levels of iron ion. A probable reason for this phenomenon is that excitations for higher excited energy levels of iron ion would be predominantly caused by non-thermal collisions with argon species, the internal energy of which is received by iron atoms for the ionization. Particular intense ionic lines, which gave a maximum peak of the Boltzmann plot, were observed at an excitation energy of ca. 7.7 eV. They were the Fe II 257.297-nm and the Fe II 258.111-nm lines, derived from the 3d54s4p 6P excited levels. The 3d54s4p 6P excited levels can be highly populated through a resonance charge transfer from the ground state of argon ion, because of good matching in the excitation energy as well as the conservation of the total spin before and after the collision. An enhancement factor of the emission intensity for various Fe II lines could be obtained from a deviation from the normal Boltzmann plot, which comprised the emission lines of 4.7-5.8 eV. It would roughly correspond to a contribution of the charge transfer excitation to the excited levels of iron ion, suggesting that the charge-transfer collision could elevate the number density of the corresponding excited levels by a factor of ca.104. The Boltzmann plots give important information on the reason why a variety of iron ionic lines can be emitted from glow discharge plasmas.

Biomechanics of 4-point seat belt systems in frontal impacts.

PubMed

Rouhana, Stephen W; Bedewi, Paul G; Kankanala, Sundeep V; Prasad, Priya; Zwolinski, Joseph J; Meduvsky, Alex G; Rupp, Jonathan D; Jeffreys, Thomas A; Schneider, Lawrence W

2003-01-01

The biomechanical behavior of 4-point seat belt systems was investigated through MADYMO modeling, dummy tests and post mortem human subject tests. This study was conducted to assess the effect of 4-point seat belts on the risk of thoracic injury in frontal impacts, to evaluate the ability to prevent submarining under the lap belt using 4-point seat belts, and to examine whether 4-point belts may induce injuries not typically observed with 3-point seat belts. The performance of two types of 4-point seat belts was compared with that of a pretensioned, load-limited, 3-point seat belt. A 3-point belt with an extra shoulder belt that "crisscrossed" the chest (X4) appeared to add constraint to the torso and increased chest deflection and injury risk. Harness style shoulder belts (V4) loaded the body in a different biomechanical manner than 3-point and X4 belts. The V4 belt appeared to shift load to the clavicles and pelvis and to reduce traction of the shoulder belt across the chest, resulting in a reduction in chest deflection by a factor of two. This is associated with a 5 to 500-fold reduction in thoracic injury risk, depending on whether one assumes 4-point belts apply concentrated or distributed load. In four of six post mortem human subjects restrained by V4 belts during 40 km/h sled tests, chest compression was zero or negative and rib fractures were nearly eliminated. Submarining was not observed in any test with post mortem human subjects. Though lumbar, sacral and pelvic injuries were noted, they are believed to be due to the artificial restraint environment (no knee bolsters, instrument panels, steering systems or airbags). While they show significant potential to reduce thoracic injury risk, there are still many issues to be resolved before 4-point belts can be considered for production vehicles. These issues include, among others, potential effects on hard and soft neck tissues, of interaction with inboard shoulder belts in farside impacts and potential

Electric filter with movable belt electrode

DOEpatents

Bergman, W.

1983-09-20

A method and apparatus for removing airborne contaminants entrained in a gas or airstream includes an electric filter characterized by a movable endless belt electrode, a grounded electrode, and a filter medium sandwiched there between. Inclusion of the movable, endless belt electrode provides the driving force for advancing the filter medium through the filter, and reduces frictional drag on the filter medium, thereby permitting a wide choice of filter medium materials. Additionally, the belt electrode includes a plurality of pleats in order to provide maximum surface area on which to collect airborne contaminants. 4 figs.

Electric filter with movable belt electrode

DOEpatents

Bergman, Werner

1983-01-01

A method and apparatus for removing airborne contaminants entrained in a gas or airstream includes an electric filter characterized by a movable endless belt electrode, a grounded electrode, and a filter medium sandwiched therebetween. Inclusion of the movable, endless belt electrode provides the driving force for advancing the filter medium through the filter, and reduces frictional drag on the filter medium, thereby permitting a wide choice of filter medium materials. Additionally, the belt electrode includes a plurality of pleats in order to provide maximum surface area on which to collect airborne contaminants.

The effect of a gearshift interlock on seat belt use by drivers who do not always use a belt and its acceptance among those who do.

PubMed

Kidd, David G; Singer, Jeremiah; Huey, Richard; Kerfoot, Laura

2018-06-01

Seat belts reduce the risk of fatal injury in a crash, yet in 2015, nearly 10,000 people killed in passenger vehicles were unrestrained. Enhanced seat belt reminders increase belt use, but a gearshift interlock that prevents the vehicle from being placed into gear unless the seat belt is used may prove more effective. Thirty-two people with a recent seat belt citation and who admitted to not always using a seat belt as a driver were recruited as part-time belt users and asked to evaluate two new vehicles. Sixteen drove two vehicles with an enhanced reminder for one week each, and 16 drove a vehicle with an enhanced reminder for one week and a vehicle with a gearshift interlock the following week. Sixteen full-time belt users who reported always using a seat belt drove a vehicle with a gearshift interlock for one week to evaluate acceptance. Relative to the enhanced reminder, the gearshift interlock significantly increased the likelihood that a part-time belt user used a belt during travel time in a trip by 21%, and increased the rate of belt use by 16%; this effect approached significance. Although every full-time belt user experienced the gearshift interlock, their acceptance of the technology reported in a post-study survey was fairly positive and not significantly different from part-time belt users. Six part-time belt users circumvented the gearshift interlock by sitting on a seat belt, waiting for the system to deactivate, or unbuckling during travel. The gearshift interlock increased the likelihood that part-time belt users buckled up and the rate of belt use during travel relative to the enhanced reminder but could be more effective if it prevented circumvention. An estimated 718-942 lives could be saved annually if the belt use of unbuckled drivers and front passengers increased 16-21%. Copyright © 2018 National Safety Council and Elsevier Ltd. All rights reserved.

Biomechanical considerations for abdominal loading by seat belt pretensioners.

PubMed

Rouhana, Stephen W; El-Jawahri, Raed E; Laituri, Tony R

2010-11-01

While seat belts are the most effective safety technology in vehicles today, there are continual efforts in the industry to improve their ability to reduce the risk of injury. In this paper, seat belt pretensioners and current trends towards more powerful systems were reviewed and analyzed. These more powerful systems may be, among other things, systems that develop higher belt forces, systems that remove slack from belt webbing at higher retraction speeds, or both. The analysis started with validation of the Ford Human Body Finite Element Model for use in evaluation of abdominal belt loading by pretensioners. The model was then used to show that those studies, done with lap-only belts, can be used to establish injury metrics for tests done with lap-shoulder belts. Then, previously-performed PMHS studies were used to develop AIS 2+ and AIS 3+ injury risk curves for abdominal interaction with seat belts via logistic regression and reliability analysis with interval censoring. Finally, some considerations were developed for a possible laboratory test to evaluate higher-powered pretensioners.

Hydroxyurea could be a good clinically relevant iron chelator.

PubMed

Italia, Khushnooma; Colah, Roshan; Ghosh, Kanjaksha

2013-01-01

Our previous study showed a reduction in serum ferritin of β-thalassemia patients on hydroxyurea therapy. Here we aimed to evaluate the efficacy of hydroxyurea alone and in combination with most widely used iron chelators like deferiprone and deferasirox for reducing iron from experimentally iron overloaded mice. 70 BALB/c mice received intraperitonial injections of iron-sucrose. The mice were then divided into 8 groups and were orally given hydroxyurea, deferiprone or deferasirox alone and their combinations for 4 months. CBC, serum-ferritin, TBARS, sTfr and hepcidin were evaluated before and after iron overload and subsequently after 4 months of drug therapy. All animals were then killed. Iron staining of the heart and liver tissue was done using Perl's Prussian Blue stain. Dry weight of iron in the heart and liver was determined by atomic absorption spectrometry. Increased serum-ferritin, TBARS, hepcidin and dry weight of iron in the liver and heart showed a significant reduction in groups treated with iron chelators with maximum reduction in the group treated with a combination of deferiprone, deferasirox and hydroxyurea. Thus hydroxyurea proves its role in reducing iron from iron overloaded mice. The iron chelating effect of these drugs can also be increased if given in combination.

Duplex thrusting in the South Dabashan arcuate belt, central China

NASA Astrophysics Data System (ADS)

Li, Wangpeng; Liu, Shaofeng; Wang, Yi; Qian, Tao; Gao, Tangjun

2017-10-01

Due to later tectonic superpositioning and reworking, the South Dabashan arcuate belt extending NW to SE has experienced several episodes of deformation. The earlier deformational style and formation mechanism of this belt remain controversial. Seismic interpretations and fieldwork show that the curved orogen can be divided into three sub-belts perpendicular to the strike of the orogen, the imbricate thrust fault belt, the detachment fold belt and the frontal belt from NE to SW. The imbricate thrust fault belt is characterized by a series of SW-directed thrust faults and nappes. Two regional detachment layers at different depths have been recognized in the detachment fold and frontal belts, and these detachment layers divide the sub-belts into three structural layers: the lower, middle, and upper structural layers. The middle structural layer is characterized by a passive roof duplex structure, which is composed of a roof thrust at the top of the Sinian units, a floor thrust in the upper Lower Triassic units, and horses in between. Apatite fission track dating results and regional structural analyses indicate that the imbricate thrust fault belt may have formed during the latest Early Cretaceous to earliest Paleogene and that the detachment fold belt may have formed during the latest Late Cretaceous to earliest Neogene. Our findings provide important reference values for researching intra-continental orogenic and deformation mechanisms in foreland fold-thrust belts.

A population of comets in the main asteroid belt.

PubMed

Hsieh, Henry H; Jewitt, David

2006-04-28

Comets are icy bodies that sublimate and become active when close to the Sun. They are believed to originate in two cold reservoirs beyond the orbit of Neptune: the Kuiper Belt (equilibrium temperatures of approximately 40 kelvin) and the Oort Cloud (approximately 10 kelvin). We present optical data showing the existence of a population of comets originating in a third reservoir: the main asteroid belt. The main-belt comets are unlike the Kuiper Belt and Oort Cloud comets in that they likely formed where they currently reside and may be collisionally activated. The existence of the main-belt comets lends new support to the idea that main-belt objects could be a major source of terrestrial water.

Tensioning of a belt around a drum using membrane element

NASA Technical Reports Server (NTRS)

Chen, C. H. S.

1980-01-01

An application of the membrane element to the problem of the tensioning of a conveyer belt which wraps around a drum is presented. Two cases were investigated: (1) belt tension increase due to drum edge wear; and (2) material trapped between the drum and the belt. In both cases it was found that the increase in belt tension was due to the additional stretching of the belt resulting from the drum radius change rather than from the transverse deflection of the belt.

Understanding pH Effects on Trichloroethylene and Perchloroethylene Adsorption to Iron in Permeable Reactive Barriers for Groundwater Remediation.

PubMed

Luo, Jing; Farrell, James

2013-01-01

Metallic iron filings are becoming increasing used in permeable reactive barriers for remediating groundwater contaminated by chlorinated solvents. Understanding solution pH effects on rates of reductive dechlorination in permeable reactive barriers is essential for designing remediation systems that can meet treatment objectives under conditions of varying groundwater properties. The objective of this research was to investigate how the solution pH value affects adsorption of trichloroethylene (TCE) and perchloroethylene (PCE) on metallic iron surfaces. Because adsorption is first required before reductive dechlorination can occur, pH effects on halocarbon adsorption energies may explain pH effects on dechlorination rates. Adsorption energies for TCE and PCE were calculated via molecular mechanics simulations using the Universal force field and a self-consistent reaction field charge equilibration scheme. A range in solution pH values was simulated by varying the amount of atomic hydrogen adsorbed on the iron. The potential energies associated TCE and PCE complexes were dominated by electrostatic interactions, and complex formation with the surface was found to result in significant electron transfer from the iron to the adsorbed halocarbons. Adsorbed atomic hydrogen was found to lower the energies of TCE complexes more than those for PCE. Attractions between atomic hydrogen and iron atoms were more favorable when TCE versus PCE was adsorbed to the iron surface. These two findings are consistent with the experimental observation that changes in solution pH affect TCE reaction rates more than those for PCE.

Iron Acquisition in Bacillus cereus: The Roles of IlsA and Bacillibactin in Exogenous Ferritin Iron Mobilization

PubMed Central

Buisson, Christophe; Daou, Nadine; Kallassy, Mireille; Lereclus, Didier; Arosio, Paolo; Bou-Abdallah, Fadi; Nielsen Le Roux, Christina

2014-01-01

In host-pathogen interactions, the struggle for iron may have major consequences on the outcome of the disease. To overcome the low solubility and bio-availability of iron, bacteria have evolved multiple systems to acquire iron from various sources such as heme, hemoglobin and ferritin. The molecular basis of iron acquisition from heme and hemoglobin have been extensively studied; however, very little is known about iron acquisition from host ferritin, a 24-mer nanocage protein able to store thousands of iron atoms within its cavity. In the human opportunistic pathogen Bacillus cereus, a surface protein named IlsA (Iron-regulated leucine rich surface protein type A) binds heme, hemoglobin and ferritin in vitro and is involved in virulence. Here, we demonstrate that IlsA acts as a ferritin receptor causing ferritin aggregation on the bacterial surface. Isothermal titration calorimetry data indicate that IlsA binds several types of ferritins through direct interaction with the shell subunits. UV-vis kinetic data show a significant enhancement of iron release from ferritin in the presence of IlsA indicating for the first time that a bacterial protein might alter the stability of the ferritin iron core. Disruption of the siderophore bacillibactin production drastically reduces the ability of B. cereus to utilize ferritin for growth and results in attenuated bacterial virulence in insects. We propose a new model of iron acquisition in B. cereus that involves the binding of IlsA to host ferritin followed by siderophore assisted iron uptake. Our results highlight a possible interplay between a surface protein and a siderophore and provide new insights into host adaptation of B. cereus and general bacterial pathogenesis. PMID:24550730

Cloud point extraction of iron(III) and vanadium(V) using 8-quinolinol derivatives and Triton X-100 and determination of 10(-7)moldm(-3) level iron(III) in riverine water reference by a graphite furnace atomic absorption spectroscopy.

PubMed

Ohashi, Akira; Ito, Hiromi; Kanai, Chikako; Imura, Hisanori; Ohashi, Kousaburo

2005-01-30

The cloud point extraction behavior of iron(III) and vanadium(V) using 8-quinolinol derivatives (HA) such as 8-quinolinol (HQ), 2-methyl-8-quinolinol (HMQ), 5-butyloxymethyl-8-quinolinol (HO(4)Q), 5-hexyloxymethyl-8-quinolinol (HO(6)Q), and 2-methyl-5-octyloxymethyl-8-quinolinol (HMO(8)Q) and Triton X-100 solution was investigated. Iron(III) was extracted with HA and 4% (v/v) Triton X-100 in the pH range of 1.70-5.44. Above pH 4.0, more than 95% of iron(III) was extracted with HQ, HMQ, and HMO(8)Q. Vanadium(V) was also extracted with HA and 4% (v/v) Triton X-100 in the pH range of 2.07-5.00, and the extractability increased in the following order of HMQ < HQ < HO(4)Q < HO(6)Q. The cloud point extraction was applied to the determination of iron(III) in the riverine water reference by a graphite furnace atomic absorption spectroscopy. When 1.25 x 10(-3)M HMQ and 1% (v/v) Triton X-100 were used, the found values showed a good agreement with the certified ones within the 2% of the R.S.D. Moreover, the effect of an alkyl group on the solubility of 5-alkyloxymethyl-8-quinolinol and 2-methyl-5-alkyloxymethyl-8-quinolinol in 4% (v/v) Triton X-100 at 25 degrees C was also investigated.

Depletion of the Outer Asteroid Belt

PubMed

Liou; Malhotra

1997-01-17

During the early history of the solar system, it is likely that the outer planets changed their distance from the sun, and hence, their influence on the asteroid belt evolved with time. The gravitational influence of Jupiter and Saturn on the orbital evolution of asteroids in the outer asteroid belt was calculated. The results show that the sweeping of mean motion resonances associated with planetary migration efficiently destabilizes orbits in the outer asteroid belt on a time scale of 10 million years. This mechanism provides an explanation for the observed depletion of asteroids in that region.

Depletion of the Outer Asteroid Belt

NASA Technical Reports Server (NTRS)

Liou, Jer-Chyi; Malhotra, Renu

1997-01-01

During the early history of the solar system, it is likely that the outer planets changed their distance from the sun, and hence, their influence on the asteroid belt evolved with time. The gravitational influence of Jupiter and Saturn on the orbital evolution of asteroids in the outer asteroid belt was calculated. The results show that the sweeping of mean motion resonances associated with planetary migration efficiently destabilizes orbits in the outer asteroid belt on a time scale of 10 million years. This mechanism provides an explanation for the observed depletion of asteroids in that region.

Geography of the asteroid belt

NASA Technical Reports Server (NTRS)

Zellner, B. H.

1978-01-01

The CSM classification serves as the starting point on the geography of the asteroid belt. Raw data on asteroid types are corrected for observational biases (against dark objects, for instance) to derive the distribution of types throughout the belt. Recent work on family members indicates that dynamical families have a true physical relationship, presumably indicating common origin in the breakup of a parent asteroid.

30 CFR 57.15020 - Life jackets and belts.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Life jackets and belts. 57.15020 Section 57.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Protection Surface Only § 57.15020 Life jackets and belts. Life jackets or belts shall be worn where there is...

30 CFR 56.15020 - Life jackets and belts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Life jackets and belts. 56.15020 Section 56.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... § 56.15020 Life jackets and belts. Life jackets or belts shall be worn where there is danger from...

30 CFR 57.15020 - Life jackets and belts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Life jackets and belts. 57.15020 Section 57.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Protection Surface Only § 57.15020 Life jackets and belts. Life jackets or belts shall be worn where there is...

30 CFR 56.15020 - Life jackets and belts.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Life jackets and belts. 56.15020 Section 56.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... § 56.15020 Life jackets and belts. Life jackets or belts shall be worn where there is danger from...

30 CFR 57.15020 - Life jackets and belts.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Life jackets and belts. 57.15020 Section 57.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Protection Surface Only § 57.15020 Life jackets and belts. Life jackets or belts shall be worn where there is...

30 CFR 56.15020 - Life jackets and belts.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Life jackets and belts. 56.15020 Section 56.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... § 56.15020 Life jackets and belts. Life jackets or belts shall be worn where there is danger from...

30 CFR 57.15020 - Life jackets and belts.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Life jackets and belts. 57.15020 Section 57.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Protection Surface Only § 57.15020 Life jackets and belts. Life jackets or belts shall be worn where there is...

30 CFR 56.15020 - Life jackets and belts.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Life jackets and belts. 56.15020 Section 56.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... § 56.15020 Life jackets and belts. Life jackets or belts shall be worn where there is danger from...

30 CFR 57.15020 - Life jackets and belts.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Life jackets and belts. 57.15020 Section 57.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Protection Surface Only § 57.15020 Life jackets and belts. Life jackets or belts shall be worn where there is...

30 CFR 56.15020 - Life jackets and belts.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Life jackets and belts. 56.15020 Section 56.15020 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... § 56.15020 Life jackets and belts. Life jackets or belts shall be worn where there is danger from...

Early Clearing of the Asteroid Belt

NASA Astrophysics Data System (ADS)

Ward, Wm. R.

2005-03-01

The ensemble of embryos destined to become the Jovian core may have excited the primordial asteroid belt and initiated a fragmentation cascade there. Thus, the majority of the belt mass may have drifted via gas drag into the terrestrial zone prior to the formation of Jupiter.

Friction and wear of iron-base binary alloys in sliding contact with silicon carbide in vacuum

NASA Technical Reports Server (NTRS)

Miyoshi, K.; Buckley, D. H.

1980-01-01

Multipass sliding friction experiments were conducted with various iron base binary alloys in contact with a single crystal silicon carbide surface in vacuum. Results indicate that the atomic size and concentration of alloy elements play important roles in controlling the transfer and friction properties of iron base binary alloys. Alloys having high solute concentration produce more transfer than do alloys having low solute concentration. The coefficient of friction during multipass sliding generally increases with an increase in the concentration of alloying element. The change of friction with succeeding passes after the initial pass also increases as the solute to iron, atomic radius ratio increases or decreases from unity.

Considerations on Terrestrial Iron Depositing Analogs to Earliest Mars

NASA Technical Reports Server (NTRS)

Brown, Igor I.; Allen, Carlton C.; Sarkisova, S. A.; Garrison, D. H.; McKay, D. S.

2007-01-01

Iron oxide and hydroxide minerals, including hematite, can mineralize and preservemicrofossils and physical biomarkers (Allen at al., 2004). Preserved remnants of phototrophic microorganisms are recognized as biosignatures of past life on Earth (Schopf, 2006). To date, two types of surface iron depositing environments have been studied as analogs to possible habitable environments on earliest Mars: the highly acidified Rio Tinto River (Iberian Belt, Spain) [Gomez Ortis et al., 2007], and the nearneutral iron depositing Chocolate Pots Hot Spring (Yellowstone National Park, US) [Parenteau at al., 2005]. While phototrophs in the Rio Tinto are only represented by eukaryotic algae (Amaral Zettler et all., 2002), Chocolate Pots is mainly populated with cyanobacteria (Pierson et all., 2000; Brown et all., 2007). Which of these environments is the closer analog to a potentially habitable early Mars? Paleobiological data, combined with recent "tree of life" interpretations, suggest that phototrophic eukaryotes evolved not earlier than 2.5 - 2.8 b.y. after Earth s accretion (4.6 b.y.), while cyanobacteria and /or their iron-tolerant predecessors evolved between 1 - 1.5 b.y. after accretion (Brown et al., 2007). Lindsay and Brasier (2002) postulated that microbial life on Mars surface could have lasted no more than 1-1.5 b.y. after Mars accretion (also 4.6 b.y.). Recent multispectral mapping of Mars suggests that near-neutral wet environments prevailed at approximately this time (Bibring, et al., 2006). Thus, near-neutral iron depositing hot springs such as Chocolate Pots Hot Spring seem to be the more likely habitable analogs for earliest Mars.

30 CFR 75.350 - Belt air course ventilation.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Belt air course ventilation. 75.350 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.350 Belt air course ventilation. (a) The belt air course must not be used as a return air course; and except as provided in paragraph...

30 CFR 75.350 - Belt air course ventilation.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Belt air course ventilation. 75.350 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.350 Belt air course ventilation. (a) The belt air course must not be used as a return air course; and except as provided in paragraph...

30 CFR 75.350 - Belt air course ventilation.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Belt air course ventilation. 75.350 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.350 Belt air course ventilation. (a) The belt air course must not be used as a return air course; and except as provided in paragraph...

30 CFR 75.350 - Belt air course ventilation.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Belt air course ventilation. 75.350 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.350 Belt air course ventilation. (a) The belt air course must not be used as a return air course; and except as provided in paragraph...

Site-selective detection of vibrational modes of an iron atom in a trinuclear complex

NASA Astrophysics Data System (ADS)

Faus, Isabelle; Rackwitz, Sergej; Wolny, Juliusz A.; Banerjee, Atanu; Kelm, Harald; Krüger, Hans-Jörg; Schlage, Kai; Wille, Hans-Christian; Schünemann, Volker

2016-12-01

Nuclear inelastic scattering (NIS) experiments on the trinuclear complex [57Fe{L-N4(CH2Fc)2} (CH3CN)2](ClO4)2 have been performed. The octahedral iron ion in the complex was labelled with 57Fe and thereby exclusively the vibrational modes of this iron ion have been detected with NIS. The analysis of nuclear forward scattering (NFS) data yields a ferrous low-spin state for the 57Fe labelled iron ion. The simulation of the partial density of states (pDOS) for the octahedral low-spin iron(II) ion of the complex by density functional theory (DFT) calculations is in excellent agreement with the experimental pDOS of the complex determined from the NIS data obtained at 80 K. Thereby it was possible to assign almost each of the experimentally observed NIS bands to the corresponding molecular vibrational modes.

Hexapole-compensated magneto-optical trap on a mesoscopic atom chip

DOE Office of Scientific and Technical Information (OSTI.GOV)

Joellenbeck, S.; Mahnke, J.; Randoll, R.

2011-04-15

Magneto-optical traps on atom chips are usually restricted to small atomic samples due to a limited capture volume caused primarily by distorted field configurations. Here we present a magneto-optical trap based on a millimeter-sized wire structure which generates a magnetic field with minimized distortions. Together with the loading from a high-flux two-dimensional magneto-optical trap, we achieve a loading rate of 8.4x10{sup 10} atoms/s and maximum number of 8.7x10{sup 9} captured atoms. The wire structure is placed outside of the vacuum to enable a further adaptation to new scientific objectives. Since all magnetic fields are applied locally without the need formore » external bias fields, the presented setup will facilitate parallel generation of Bose-Einstein condensates on a conveyor belt with a cycle rate above 1 Hz.« less

A green analytical method using ultrasound in sample preparation for the flow injection determination of iron, manganese, and zinc in soluble solid samples by flame atomic absorption spectrometry.

PubMed

Yebra, M Carmen

2012-01-01

A simple and rapid analytical method was developed for the determination of iron, manganese, and zinc in soluble solid samples. The method is based on continuous ultrasonic water dissolution of the sample (5-30 mg) at room temperature followed by flow injection flame atomic absorption spectrometric determination. A good precision of the whole procedure (1.2-4.6%) and a sample throughput of ca. 25 samples h(-1) were obtained. The proposed green analytical method has been successfully applied for the determination of iron, manganese, and zinc in soluble solid food samples (soluble cocoa and soluble coffee) and pharmaceutical preparations (multivitamin tablets). The ranges of concentrations found were 21.4-25.61 μg g(-1) for iron, 5.74-18.30 μg g(-1) for manganese, and 33.27-57.90 μg g(-1) for zinc in soluble solid food samples and 3.75-9.90 μg g(-1) for iron, 0.47-5.05 μg g(-1) for manganese, and 1.55-15.12 μg g(-1) for zinc in multivitamin tablets. The accuracy of the proposed method was established by a comparison with the conventional wet acid digestion method using a paired t-test, indicating the absence of systematic errors.

Metamorphic belts of Anatolia

NASA Astrophysics Data System (ADS)

Oberhänsli, Roland; Prouteau, Amaury; Candan, Osman; Bousquet, Romain

2015-04-01

Investigating metamorphic rocks from high-pressure/low-temperature (HP/LT) belts that formed during the closure of several oceanic branches, building up the present Anatolia continental micro-plate gives insight to the palaeogeography of the Neotethys Ocean in Anatolia. Two coherent HP/LT metamorphic belts, the Tavşanlı Zone (distal Gondwana margin) and the Ören-Afyon-Bolkardağ Zone (proximal Gondwana margin), parallel their non-metamorphosed equivalent (the Tauride Carbonate Platform) from the Aegean coast in NW Anatolia to southern Central Anatolia. P-T conditions and timing of metamorphism in the Ören-Afyon-Bolkardağ Zone (>70?-65 Ma; 0.8-1.2 GPa/330-420°C) contrast those published for the overlying Tavşanlı Zone (88-78 Ma; 2.4 GPa/500 °C). These belts trace the southern Neotethys suture connecting the Vardar suture in the Hellenides to the Inner Tauride suture along the southern border of the Kirşehir Complex in Central Anatolia. Eastwards, these belts are capped by the Oligo-Miocene Sivas Basin. Another HP/LT metamorphic belt, in the Alanya and Bitlis regions, outlines the southern flank of the Tauride Carbonate Platform. In the Alanya Nappes, south of the Taurides, eclogites and blueschists yielded metamorphic ages around 82-80 Ma (zircon U-Pb and phengite Ar-Ar data). The Alanya-Bitlis HP belt testifies an additional suture not comparable to the northerly Tavşanlı and Ören-Afyon belts, thus implying an additional oceanic branch of the Neotethys. The most likely eastern lateral continuation of this HP belt is the Bitlis Massif, in SE Turkey. There, eclogites (1.9-2.4 GPa/480-540°C) occur within calc-arenitic meta-sediments and in gneisses of the metamorphic (Barrovian-type) basement. Zircon U-Pb ages revealed 84.4-82.4 Ma for peak metamorphism. Carpholite-bearing HP/LT metasediments representing the stratigraphic cover of the Bitlis Massif underwent 0.8-1.2 GPa/340-400°C at 79-74 Ma (Ar-Ar on white mica). These conditions compares to the Tav

[Primary speciation analysis of iron in edible flowers].

PubMed

Peng, Shan-shan; Huang, Guo-qing

2003-02-01

In this paper seven primary speciations of iron in three edible flowers, i.e. chrysanthemum, cottonrose hibiscus and honeysucker have been studied by atomic absorption spectrometry. Speciation parameters of iron such as extractive rate, residue rate, immerse-residue ratio in the samples were calculated. It was found that the first extractive rates of Fe were higher than the second ones in all three edible flowers, and the immerse-residue ratios of Fe were similar to the extractive rates. But the extraction of iron in all three edible flowers were no more than fifty percent. It is showed that the iron isn't easy to extract by water in the three edible flowers. The recovery was in the range of 96.5%-103.2% and RSD was in the range of 1.2%-3.1%. The results were satisfactory.

14 CFR 125.211 - Seat and safety belts.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Seat and safety belts. 125.211 Section 125... Requirements § 125.211 Seat and safety belts. (a) No person may operate an airplane unless there are available... the airplane who is at least 2 years old; and (2) An approved safety belt for separate use by each...

Overrepresentation of seat belt non-users in traffic crashes

DOT National Transportation Integrated Search

1988-04-01

This study used observations of driver belt use linked with driver history information to conclude that non-users of belts are overrepresented in traffic crashes. Examining average numbers of accidents and violations per observed belted and unbelted ...

Understanding the nanoscale redox-behavior of iron-anodes for rechargeable iron-air batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weinrich, Henning; Come, Jérémy; Tempel, Hermann

Iron-air cells provide a promising and resource-efficient alternative battery concept with superior area specific power density characteristics compared to state-of-the-art Li-air batteries and potentially superior energy density characteristics compared to present Li-ion batteries. Understanding charge-transfer reactions at the anode-electrolyte interface is the key to develop high-performance cells. By employing in-situ electrochemical atomic force microscopy (in-situ EC-AFM), in-depth insight into the electrochemically induced surface reaction processes on iron in concentrated alkaline electrolyte is obtained. The results highlight the formation and growth of the redox-layer on iron over the course of several oxidation/reduction cycles. By this means, a direct correlation between topographymore » changes and the corresponding electrochemical reactions at the nanoscale could unambiguously be established. Here in this paper, the twofold character of the nanoparticulate redox-layer in terms of its passivating character and its contribution to the electrochemical reactions is elucidated. Furthermore, the evolution of single nanoparticles on the iron electrode surface is evaluated in unprecedented and artifact-free detail. Based on the dedicated topography analysis, a detailed structural model for the evolution of the redox-layer which is likewise elementary for corrosion science and battery research is derived.« less

Ultracold collisions between Rb atoms and a Sr+ ion

NASA Astrophysics Data System (ADS)

Meir, Ziv; Sikorsky, Tomas; Ben-Shlomi, Ruti; Dallal, Yehonatan; Ozeri, Roee

2015-05-01

In last decade, a novel field emerged, in which ultracold atoms and ions in overlapping traps are brought into interaction. In contrast to the short ranged atom-atom interaction which scales as r-6, atom-ion potential persists for hundreds of μm's due to its lower power-law scaling - r-4. Inelastic collisions between the consistuents lead to spin and charge transfer and also to molecule formation. Elastic collisions control the energy transfer between the ion and the atoms. The study of collisions at the μK range has thus far been impeded by the effect of the ion's micromotion which limited collision energy to mK scale. Unraveling this limit will allow to investigate few partial wave and even S-wave collisions. Our system is capable of trapping Sr+ ions and Rb and Sr atoms and cooling them to their quantum ground state. Atoms and ions are trapped and cooled in separate chambers. Then, the atoms are transported using an optical conveyer belt to overlap the ions. In contrast to other experiments in this field where the atoms are used to sympathetic cool the ion, our system is also capable of ground state cooling the ion before immersing it into the atom cloud. By this method, we would be able to explore heating and cooling dynamics in the ultracold regime.

Uranium(VI) Scavenging by Amorphous Iron Phosphate Encrusting Sphaerotilus natans Filaments.

PubMed

Seder-Colomina, Marina; Morin, Guillaume; Brest, Jessica; Ona-Nguema, Georges; Gordien, Nilka; Pernelle, Jean-Jacques; Banerjee, Dipanjan; Mathon, Olivier; Esposito, Giovanni; van Hullebusch, Eric D

2015-12-15

U(VI) sorption to iron oxyhydroxides, precipitation of phosphate minerals, as well as biosorption on bacterial biomass are among the most reported processes able to scavenge U(VI) under oxidizing conditions. Although phosphates significantly influence bacterially mediated as well as iron oxyhydroxide mediated scavenging of uranium, the sorption or coprecipitation of U(VI) with poorly crystalline nanosized iron phosphates has been scarcely documented, especially in the presence of microorganisms. Here we show that dissolved U(VI) can be bound to amorphous iron phosphate during their deposition on Sphaerotilus natans filamentous bacteria. Uranium LIII-edge EXAFS analysis reveals that the adsorbed uranyl ions share an equatorial oxygen atom with a phosphate tetrahedron of the amorphous iron phosphate, with a characteristic U-P distance of 3.6 Å. In addition, the uranyl ions are connected to FeO6 octahedra with U-Fe distances at ~3.4 Å and at ~4.0 Å. The shortest U-Fe distance corresponds to a bidentate edge-sharing complex often reported for uranyl adsorption onto iron oxyhydroxides, whereas the longest U-Fe and U-P distances can be interpreted as a bidentate corner-sharing complex, in which two adjacent equatorial oxygen atoms are shared with the vertices of a FeO6 octahedron and of a phosphate tetrahedron. Furthermore, based on these sorption reactions, we demonstrate the ability of an attached S. natans biofilm to remove uranium from solution without any filtration step.

Novel atomic absorption spectrometric and rapid spectrophotometric methods for the quantitation of paracetamol in saliva: application to pharmacokinetic studies.

PubMed

Issa, M M; Nejem, R M; El-Abadla, N S; Al-Kholy, M; Saleh, Akila A

2008-01-01

A novel atomic absorption spectrometric method and two highly sensitive spectrophotometric methods were developed for the determination of paracetamol. These techniques based on the oxidation of paracetamol by iron (III) (method I); oxidation of p-aminophenol after the hydrolysis of paracetamol (method II). Iron (II) then reacts with potassium ferricyanide to form Prussian blue color with a maximum absorbance at 700 nm. The atomic absorption method was accomplished by extracting the excess iron (III) in method II and aspirates the aqueous layer into air-acetylene flame to measure the absorbance of iron (II) at 302.1 nm. The reactions have been spectrometrically evaluated to attain optimum experimental conditions. Linear responses were exhibited over the ranges 1.0-10, 0.2-2.0 and 0.1-1.0 mug/ml for method I, method II and atomic absorption spectrometric method, respectively. A high sensitivity is recorded for the proposed methods I and II and atomic absorption spectrometric method value indicate: 0.05, 0.022 and 0.012 mug/ml, respectively. The limit of quantitation of paracetamol by method II and atomic absorption spectrometric method were 0.20 and 0.10 mug/ml. Method II and the atomic absorption spectrometric method were applied to demonstrate a pharmacokinetic study by means of salivary samples in normal volunteers who received 1.0 g paracetamol. Intra and inter-day precision did not exceed 6.9%.

Jupiter's Colorful Cloud Belts

NASA Image and Video Library

2018-01-12

Colorful swirling cloud belts dominate Jupiter's southern hemisphere in this image captured by NASA's Juno spacecraft. Jupiter appears in this color-enhanced image as a tapestry of vibrant cloud bands and storms. The dark region in the far left is called the South Temperate Belt. Intersecting the belt is a ghost-like feature of slithering white clouds. This is the largest feature in Jupiter's low latitudes that's a cyclone (rotating with clockwise motion). This image was taken on Dec. 16, 2017 at 10:12 PST (1:12 p.m. EST), as Juno performed its tenth close flyby of Jupiter. At the time the image was taken, the spacecraft was about 8,453 miles (13,604 kilometers) from the tops of the clouds of the planet at a latitude of 27.9 degrees south. The spatial scale in this image is 5.6 miles/pixel (9.1 kilometers/pixel). Citizen scientist Kevin M. Gill processed this image using data from the JunoCam imager. https://photojournal.jpl.nasa.gov/catalog/PIA21974

Programmable solid state atom sources for nanofabrication.

PubMed

Han, Han; Imboden, Matthias; Stark, Thomas; del Corro, Pablo G; Pardo, Flavio; Bolle, Cristian A; Lally, Richard W; Bishop, David J

2015-06-28

In this paper we discuss the development of a MEMS-based solid state atom source that can provide controllable atom deposition ranging over eight orders of magnitude, from ten atoms per square micron up to hundreds of atomic layers, on a target ∼1 mm away. Using a micron-scale silicon plate as a thermal evaporation source we demonstrate the deposition of indium, silver, gold, copper, iron, aluminum, lead and tin. Because of their small sizes and rapid thermal response times, pulse width modulation techniques are a powerful way to control the atomic flux. Pulsing the source with precise voltages and timing provides control in terms of when and how many atoms get deposited. By arranging many of these devices into an array, one has a multi-material, programmable solid state evaporation source. These micro atom sources are a complementary technology that can enhance the capability of a variety of nano-fabrication techniques.

Scenarios for the Evolution of Asteroid Belts

NASA Image and Video Library

2012-11-01

This illustration shows three possible scenarios for the evolution of asteroid belts. At the top, a Jupiter-size planet migrates through the asteroid belt, scattering material and inhibiting the formation of life on planets.

Space Weather Effects in the Earth's Radiation Belts

NASA Astrophysics Data System (ADS)

Baker, D. N.; Erickson, P. J.; Fennell, J. F.; Foster, J. C.; Jaynes, A. N.; Verronen, P. T.

2018-02-01

The first major scientific discovery of the Space Age was that the Earth is enshrouded in toroids, or belts, of very high-energy magnetically trapped charged particles. Early observations of the radiation environment clearly indicated that the Van Allen belts could be delineated into an inner zone dominated by high-energy protons and an outer zone dominated by high-energy electrons. The energy distribution, spatial extent and particle species makeup of the Van Allen belts has been subsequently explored by several space missions. Recent observations by the NASA dual-spacecraft Van Allen Probes mission have revealed many novel properties of the radiation belts, especially for electrons at highly relativistic and ultra-relativistic kinetic energies. In this review we summarize the space weather impacts of the radiation belts. We demonstrate that many remarkable features of energetic particle changes are driven by strong solar and solar wind forcings. Recent comprehensive data show broadly and in many ways how high energy particles are accelerated, transported, and lost in the magnetosphere due to interplanetary shock wave interactions, coronal mass ejection impacts, and high-speed solar wind streams. We also discuss how radiation belt particles are intimately tied to other parts of the geospace system through atmosphere, ionosphere, and plasmasphere coupling. The new data have in many ways rewritten the textbooks about the radiation belts as a key space weather threat to human technological systems.

Factors related to nonuse of seat belts in Michigan.

DOT National Transportation Integrated Search

1987-09-01

This study combined direct observation of seat belt use with interview methods to : identify factors related to seat belt use in a state with a mandatory seat belt use law. Trained : observers recorded restraint use for a probability sample of motori...

A study of nighttime seat belt use in Indiana

DOT National Transportation Integrated Search

2007-05-01

Overall belt use rates observed during the daytime and nighttime survey waves are presented in Table 2. Belt use observed during the daytime and nighttime pre-mobilization waves was very similar. During the post-mobilization waves, daytime belt use w...

High-temperature corrosion-resistant iron-aluminide (FeAl) alloys exhibiting improved weldability

DOEpatents

Maziasz, Philip J.; Goodwin, Gene M.; Liu, Chain T.

1996-01-01

This invention relates to improved corrosion-resistant iron-aluminide intermetallic alloys. The alloys of this invention comprise, in atomic percent, from about 30% to about 40% aluminum alloyed with from about 0.1% to about 0.5% carbon, no more than about 0.04% boron such that the atomic weight ratio of boron to carbon in the alloy is in the range of from about 0.01:1 to about 0.08:1, from about 0.01 to about 3.5% of one or more transition metals selected from Group IVB, VB, and VIB elements and the balance iron wherein the alloy exhibits improved resistance to hot cracking during welding.

Effectiveness of high school safety belt instruction

DOT National Transportation Integrated Search

1982-12-01

The Effectiveness of High School Safety Belt Instruction was developed during a two-phased project. In Phase I, Focus Group Activities were conducted to determine whether audiovisual safety belt instructional materials assembled by the National Highw...

Pilot tests of a seat belt gearshift delay on the belt use of commercial fleet drivers : traffic tech.

DOT National Transportation Integrated Search

2010-04-01

Wearing a seat belt has been shown effective in avoiding : or reducing serious injury due to traffic crashes. While : belt use rates in the United States increased from under : 60% in 1994 to 83% in 2008, a substantial number of drivers : still drive...

Jupiter's magnetosphere and radiation belts

NASA Technical Reports Server (NTRS)

Kennel, C. F.; Coroniti, F. V.

1979-01-01

Radioastronomy and Pioneer data reveal the Jovian magnetosphere as a rotating magnetized source of relativistic particles and radio emission, comparable to astrophysical cosmic ray and radio sources, such as pulsars. According to Pioneer data, the magnetic field in the outer magnetosphere is radially extended into a highly time variable disk-shaped configuration which differs fundamentally from the earth's magnetosphere. The outer disk region, and the energetic particles confined in it, are modulated by Jupiter's 10 hr rotation period. The entire outer magnetosphere appears to change drastically on time scales of a few days to a week. In addition to its known modulation of the Jovian decametric radio bursts, Io was found to absorb some radiation belt particles and to accelerate others, and most importantly, to be a source of neutral atoms, and by inference, a heavy ion plasma which may significantly affect the hydrodynamic flow in the magnetosphere. Another important Pioneer finding is that the Jovian outer magnetosphere generates, or permits to escape, fluxes of relativistic electrons of such intensities that Jupiter may be regarded as the dominant source of 1 to 30 MeV cosmic ray electrons in the heliosphere.

The Collisional Evolution of the Main Asteroid Belt

NASA Astrophysics Data System (ADS)

Bottke, W. F.; Brož, M.; O'Brien, D. P.; Campo Bagatin, A.; Morbidelli, A.; Marchi, S.

Collisional and dynamical models of the main asteroid belt allow us to glean insights into planetesimal- and planet-formation scenarios as well as how the main belt reached its current state. Here we discuss many of the processes affecting asteroidal evolution and the constraints that can be used to test collisional model results. We argue the main belt's wavy size-frequency distribution for diameter D < 100-km asteroids is increasingly a byproduct of comminution as one goes to smaller sizes, with its shape a fossil-like remnant of a violent early epoch. Most D > 100-km asteroids, however, are primordial, with their physical properties set by planetesimal formation and accretion processes. The main-belt size distribution as a whole has evolved into a collisional steady state, and it has possibly been in that state for billions of years. Asteroid families provide a critical historical record of main-belt collisions. The heavily depleted and largely dispersed "ghost families," however, may hold the key to understanding what happened in the primordial days of the main belt. New asteroidal fragments are steadily created by both collisions and mass shedding events via YORP spinup processes. A fraction of this population, in the form of D < 30 km fragments, go on to escape the main belt via the Yarkovsky/YORP effects and gravitational resonances, thereby creating a quasi-steady-state population of planet-crossing and near-Earth asteroids. These populations go on to bombard all inner solar system worlds. By carefully interpreting the cratering records they produce, it is possible to constrain how portions of the main-belt population have evolved with time.

An Empirical Planetesimal Belt Radius–Stellar Luminosity Relation

NASA Astrophysics Data System (ADS)

Matrà, L.; Marino, S.; Kennedy, G. M.; Wyatt, M. C.; Öberg, K. I.; Wilner, D. J.

2018-05-01

Resolved observations of millimeter-sized dust, tracing larger planetesimals, have pinpointed the location of 26 Edgeworth–Kuiper Belt analogs. We report that a belt’s distance R to its host star correlates with the star’s luminosity L ⋆, following R\\propto {L}\\star 0.19 with a low intrinsic scatter of ∼17%. Remarkably, our Edgeworth–Kuiper Belt in the solar system and the two CO snow lines imaged in protoplanetary disks lie close to this R–L ⋆ relation, suggestive of an intrinsic relationship between protoplanetary disk structures and belt locations. To test the effect of bias on the relation, we use a Monte Carlo approach and simulate uncorrelated model populations of belts. We find that observational bias could produce the slope and intercept of the R–L ⋆ relation but is unable to reproduce its low scatter. We then repeat the simulation taking into account the collisional evolution of belts, following the steady-state model that fits the belt population as observed through infrared excesses. This significantly improves the fit by lowering the scatter of the simulated R–L ⋆ relation; however, this scatter remains only marginally consistent with the one observed. The inability of observational bias and collisional evolution alone to reproduce the tight relationship between belt radius and stellar luminosity could indicate that planetesimal belts form at preferential locations within protoplanetary disks. The similar trend for CO snow line locations would then indicate that the formation of planetesimals or planets in the outer regions of planetary systems is linked to the volatility of their building blocks, as postulated by planet formation models.

36 CFR 1004.15 - Safety belts.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false Safety belts. 1004.15 Section 1004.15 Parks, Forests, and Public Property PRESIDIO TRUST VEHICLES AND TRAFFIC SAFETY § 1004.15 Safety... administered by the Presidio Trust will have the safety belt or child restraint system properly fastened at all...

36 CFR 1004.15 - Safety belts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Safety belts. 1004.15 Section 1004.15 Parks, Forests, and Public Property PRESIDIO TRUST VEHICLES AND TRAFFIC SAFETY § 1004.15 Safety... administered by the Presidio Trust will have the safety belt or child restraint system properly fastened at all...

Neptune's Eccentricity and the Nature of the Kuiper Belt

NASA Technical Reports Server (NTRS)

Ward, William R.; Hahn, Joseph M.

1998-01-01

The small eccentricity of Neptune may be a direct consequence of apsidal wave interaction with the trans-Neptune population of debris called the Kuiper belt. The Kuiper belt is subject to resonant perturbations from Neptune, so that the transport of angular momentum by density waves can result in orbital evolution of Neptune as well as changes in the structure of the Kuiper belt. In particular, for a belt eroded out to the vicinity of Neptune's 2:1 resonance at about 48 astronomical units, Neptune's eccentricity can damp to its current value over the age of the solar system if the belt contains slightly more than an earth mass of material out to about 75 astronomical units.

Alloy softening in binary iron solid solutions

NASA Technical Reports Server (NTRS)

Stephens, J. R.; Witzke, W. R.

1976-01-01

An investigation was conducted to determine softening and hardening behavior in 19 binary iron-alloy systems. Microhardness tests were conducted at four temperatures in the range 77 to 411 K. Alloy softening was exhibited by 17 of the 19 alloy systems. Alloy softening observed in 15 of the alloy systems was attributed to an intrinsic mechanism, believed to be lowering of the Peierls (lattice friction) stress. Softening and hardening rates could be correlated with the atomic radius ratio of solute to iron. Softening observed in two other systems was attributed to an extrinsic mechanism, believed to be associated with scavenging of interstitial impurities.

Plains tectonism on Venus: The deformation belts of Lavinia Planitia

NASA Technical Reports Server (NTRS)

Squyres, Steven W.; Jankowski, David G.; Simons, Mark; Solomon, Sean C.; Hager, Bradford H.; Mcgill, George E.

1993-01-01

High-resolution radar images from the Magellan spacecraft have revealed the first details of the morphology of the Lavinia Planitia region of Venus. A number of geologic units can be distinguished, including volcanic plains units with a range of ages. Transecting these plains over much of the Lavinia region are two types of generally orthogonal features that we interpret to be compressional wrinkle ridges and extensional grooves. The dominant tectonic features of Lavinia are broad elevated belts of intense deformation that transect the plains with complex geometry. They are many tens to a few hundred kilometers wide, as much as 1000 km long, and elevated hundreds of meters above the surrounding plains. Two classes of deformation belts are seen in the Lavinia region. 'Ridge belts' are composed of parallel ridges, each a few hundred meters in elevation, that we interpret to be folds. Typical fold spacings are 5-10 km. 'Fracture belts' are dominated instead by intense faulting, with faults in some instances paired to form narrow grabens. There is also some evidence for modest amounts of horizontal shear distributed across both ridge and fracture belts. Crosscutting relationships among the belts show there to be a range in belt ages. In western Lavinia, in particular, many ridge and fracture belts appear to bear a relationship to the much smaller wrinkle ridges and grooves on the surrounding plains: ridge morphology tends to dominate belts that lie more nearly parallel to local plains wrinkle ridges, and fracture morphology tends to dominate belts that lie more nearly parallel to local plains grooves. We use simple models to explore the formation of ridge and fracture belts. We show that convective motions in the mantle can couple to the crust to cause horizontal stresses of a magnitude sufficient to induce the formation of deformation belts like those observed in Lavinia. We also use the small-scale wavelengths of deformation observed within individual ridge belts to

New Atomic Data for Doubly Ionized Iron Group Atoms by High Resolution UV Fourier Transform Spectroscopy

NASA Technical Reports Server (NTRS)

Smith, Peter L.; Pickering, Juliet C.; Thorne, A. P.

2002-01-01

Currently available laboratory spectroscopic data of doubly ionized iron-group element were obtained about 50 years ago using spectrographs of modest dispersion, photographic plates, and eye estimates of intensities. The accuracy of the older wavelength data is about 10 mAngstroms at best, whereas wavelengths are now needed to an accuracy of 1 part in 10(exp 6) to 10(exp 7) (0.2 to 2 mAngstroms at 2000 Angstroms). The Fourier transform (FT) spectroscopy group at Imperial College, London, and collaborators at the Harvard College Observatory have used a unique VUV FT spectrometer in a program focussed on improving knowledge of spectra of many neutral and singly and doubly ionized, astrophysically important, iron group elements. Spectra of Fe II and Fe III have been recorded at UV and VUV wavelengths with signal-to-noise ratios of several hundred for the stronger lines. Wavelengths and energy levels for Fe III are an order of magnitude more accurate than previous work; analysis is close to completion. f-values for Fe II have been published.

Adhesion and friction of iron-base binary alloys in contact with silicon carbide in vacuum

NASA Technical Reports Server (NTRS)

Miyoshi, K.; Buckley, D. H.

1980-01-01

Single pass sliding friction experiments were conducted with various iron base binary alloys (alloying elements were Ti, Cr, Mn, Ni, Rh, and W) in contact with a single crystal silicon carbide /0001/ surface in vacuum. Results indicate that atomic size and concentration of alloying elements play an important role in controlling adhesion and friction properties of iron base binary alloys. The coefficient of friction generally increases with an increase in solute concentration. The coefficient of friction increases linearly as the solute to iron atomic radius ratio increases or decreases from unity. The chemical activity of the alloying elements was also an important parameter in controlling adhesion and friction of alloys, as these latter properties are highly dependent upon the d bond character of the elements.

2009 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2009-07-01

The objective of this study was to establish 2009 safety belt and child safety seat usage rates in Kentucky. The 2009 survey continues to document the results after enactment of original "secondary enforcement" statewide mandatory safety belt law in ...

2002 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2002-07-01

The objective of this study was to establish 2002 safety belt and child safety seat usage rates in Kentucky. The 2002 survey continues to document the results after enactment of original "secondary enforcement" statewide mandatory safety belt law in ...

2001 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2001-08-01

The objective of this study was to establish 2001 safety belt and child safety seat usage rates in Kentucky. The 2001 survey continues to document the results after enactment of original "secondary enforcement" statewide mandatory safety belt law in ...

2010 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2010-07-01

The objective of this study was to establish 2010 safety belt and child safety seat usage rates in Kentucky. The 2010 survey continues to document the results after enactment of the original "second enforcement" statewide mandatory safety belt law in...

2007 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2007-08-01

The objective of this study was to establish 2007 safety belt and child safety seat usage rates in Kentucky. The 2007 survey continues to document the results after enactment of the initial "second enforcement" statewide mandatory safety belt law in ...

2006 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2006-08-01

The objective of this study was to establish 2006 safety belt and child safety seat usage rates in Kentucky. The 2006 survey continues to document the results after enactment of the initial "second enforcement" statewide mandatory safety belt law in ...

2008 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2008-08-01

The objective of this study was to establish 2008 safety belt and child safety seat usage rates in Kentucky. The 2008 survey continues to document the results after enactment of the initial "second enforcement" statewide mandatory safety belt law in ...

2005 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2005-08-01

The objective of this study was to establish 2005 safety belt and child safety seat usage rates in Kentucky. The 2005 survey continues to document the results after enactment of the initial "second enforcement" statewide mandatory safety belt law in ...

Wearing an abdominal belt increases diastolic blood pressure.

PubMed

Rafacz, W; McGill, S M

1996-09-01

The purpose of this study was to determine the effect of wearing an abdominal belt on blood pressure (systolic and diastolic) and heart rate during a variety of tasks. The belt was typical of the elastic type with suspenders and Velcro tabs for cinching the belt snug. The tasks performed included sitting at rest, sitting with the torso inclined forward at 45 degrees, standing with the torso inclined forward at 45 degrees (with and without holding an 11-kg weight), a trunk axial rotation task, and squat lifting. Blood pressure was monitored noninvasively with a FINAPRES blood pressure monitor. Twenty healthy men performed each task with and without the abdominal belt. Although no significant increases in mean systolic blood pressure or heart rate were found, there was a significant increase in diastolic blood pressure in all conditions. All people considering wearing an abdominal belt should also consider the risks and liability associated with the additional cardiovascular load, particularly heart attack and stroke.

Survey of current situation in radiation belt modeling

NASA Technical Reports Server (NTRS)

Fung, Shing F.

2004-01-01

The study of Earth's radiation belts is one of the oldest subjects in space physics. Despite the tremendous progress made in the last four decades, we still lack a complete understanding of the radiation belts in terms of their configurations, dynamics, and detailed physical accounts of their sources and sinks. The static nature of early empirical trapped radiation models, for examples, the NASA AP-8 and AE-8 models, renders those models inappropriate for predicting short-term radiation belt behaviors associated with geomagnetic storms and substorms. Due to incomplete data coverage, these models are also inaccurate at low altitudes (e.g., <1000 km) where many robotic and human space flights occur. The availability of radiation data from modern space missions and advancement in physical modeling and data management techniques have now allowed the development of new empirical and physical radiation belt models. In this paper, we will review the status of modern radiation belt modeling. Published by Elsevier Ltd on behalf of COSPAR.

An Effective Belt Conveyor for Underground Ore Transportation Systems

NASA Astrophysics Data System (ADS)

Krol, Robert; Kawalec, Witold; Gladysiewicz, Lech

2017-12-01

Raw material transportation generates a substantial share of costs in the mining industry. Mining companies are therefore determined to improve the effectiveness of their transportation system, focusing on solutions that increase both its energy efficiency and reliability while keeping maintenance costs low. In the underground copper ore operations in Poland’s KGHM mines vast and complex belt conveyor systems have been used for horizontal haulage of the run-of-mine ore from mining departments to shafts. Basing upon a long-time experience in the field of analysing, testing, designing and computing of belt conveyor equipment with regard to specific operational conditions, the improvements to the standard design of an underground belt conveyor for ore transportation have been proposed. As the key elements of a belt conveyor, the energy-efficient conveyor belt and optimised carrying idlers have been developed for the new generation of underground conveyors. The proposed solutions were tested individually on the specially constructed test stands in the laboratory and in the experimental belt conveyor that was built up with the use of prototype parts and commissioned for the regular ore haulage in a mining department in the KGHM underground mine “Lubin”. Its work was monitored and the recorded operational parameters (loadings, stresses and strains, energy dissipation, belt tracking) were compared with those previously collected on a reference (standard) conveyor. These in-situ measurements have proved that the proposed solutions will return with significant energy savings and lower maintenance costs. Calculations made on the basis of measurement results in the specialized belt conveyor designing software allow to estimate the possible savings if the modernized conveyors supersede the standard ones in a large belt conveying system.

Shellwise Mackay transformation in iron nanoclusters.

PubMed

Rollmann, Georg; Gruner, Markus E; Hucht, Alfred; Meyer, Ralf; Entel, Peter; Tiago, Murilo L; Chelikowsky, James R

2007-08-24

Structure and magnetism of iron clusters with up to 641 atoms have been investigated by means of density functional theory calculations including full geometric optimizations. Body-centered cubic (bcc) isomers are found to be lowest in energy when the clusters contain more than about 100 atoms. In addition, another stable conformation has been identified for magic-number clusters, which lies well within the range of thermal energies as compared to the bcc isomers. Its structure is characterized by a close-packed particle core and an icosahedral surface, while intermediate shells are partially transformed along the Mackay path between icosahedral and cuboctahedral geometry. The gradual transformation results in a favorable bcc environment for the subsurface atoms. For Fe55, the shellwise Mackay-transformed morphology is a promising candidate for the ground state.

Aqueous formation and manipulation of the iron-oxo Keggin ion

NASA Astrophysics Data System (ADS)

Sadeghi, Omid; Zakharov, Lev N.; Nyman, May

2015-03-01

There is emerging evidence that growth of synthetic and natural phases occurs by the aggregation of prenucleation clusters, rather than classical atom-by-atom growth. Ferrihydrite, an iron oxyhydroxide mineral, is the common form of Fe3+ in soils and is also in the ferritin protein. We isolated a 10 angstrom discrete iron-oxo cluster (known as the Keggin ion, Fe13) that has the same structural features as ferrihydrite. The stabilization and manipulation of this highly reactive polyanion in water is controlled exclusively by its counterions. Upon dissolution of Fe13 in water with precipitation of its protecting Bi3+-counterions, it rapidly aggregates to ~22 angstrom spherical ferrihydrite nanoparticles. Fe13 may therefore also be a prenucleation cluster for ferrihydrite formation in natural systems, including by microbial and cellular processes.

Factors Influencing Occupant-To-Seat Belt Interaction in Far-Side Crashes

PubMed Central

Douglas, C.A.; Fildes, B.N.; Gibson, T.J.; Boström, O.; Pintar, F.A.

2007-01-01

Seat belt interaction with a far-side occupant’s shoulder and thorax is critical to governing excursion towards the struck-side of the vehicle in side impact. In this study, occupant-to-belt interaction was simulated using a modified MADYMO human model and finite element belts. Quasi-static tests with volunteers and dynamic sled tests with PMHS and WorldSID were used for model validation and comparison. Parameter studies were then undertaken to quantify the effect of impact direction, seat belt geometry and pretension on occupant-to-seat belt interaction. Results suggest that lowering the D-ring and increasing pretension reduces the likelihood of the belt slipping off the shoulder. Anthropometry was also shown to influence restraint provided by the shoulder belt. Furthermore, the belt may slip off the occupant’s shoulder at impact angles greater than 40 degrees from frontal when no pretension is used. However, the addition of pretension allowed the shoulder to engage the belt in all impacts from 30 to 90 degrees. PMID:18184500

Estimating seat belt effectiveness using matched-pair cohort methods.

PubMed

Cummings, Peter; Wells, James D; Rivara, Frederick P

2003-01-01

Using US data for 1986-1998 fatal crashes, we employed matched-pair analysis methods to estimate that the relative risk of death among belted compared with unbelted occupants was 0.39 (95% confidence interval (CI) 0.37-0.41). This differs from relative risk estimates of about 0.55 in studies that used crash data collected prior to 1986. Using 1975-1998 data, we examined and rejected three theories that might explain the difference between our estimate and older estimates: (1) differences in the analysis methods; (2) changes related to car model year; (3) changes in crash characteristics over time. A fourth theory, that the introduction of seat belt laws would induce some survivors to claim belt use when they were not restrained, could explain part of the difference in our estimate and older estimates; but even in states without seat belt laws, from 1986 through 1998, the relative risk estimate was 0.45 (95% CI 0.39-0.52). All of the difference between our estimate and older estimates could be explained by some misclassification of seat belt use. Relative risk estimates would move away from 1, toward their true value, if misclassification of both the belted and unbelted decreased over time, or if the degree of misclassification remained constant, as the prevalence of belt use increased. We conclude that estimates of seat belt effects based upon data prior to 1986 may be biased toward 1 by misclassification.

2017 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2017-08-01

The use of safety belts and child safety seats is a proven means of reducing injuries to motor vehicle occupants involved in traffic crashes. There have been various methods used in efforts to increase safety belt and safety seat usage. Past efforts ...

2016 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2016-08-01

The use of safety belts and child safety seats is a proven means of reducing injuries to motor vehicle occupants involved in traffic crashes. There have been various methods used in efforts to increase safety belt and safety seat usage. Past efforts ...

2015 safety belt usage survey in Kentucky.

DOT National Transportation Integrated Search

2015-08-01

The use of safety belts and child safety seats has been shown to be an effective means of : reducing injuries to motor-vehicle occupants involved in traffic crashes. There have been various : methods used in efforts to increase safety belt and safety...

2001 Safety belt usage survey in Kentucky

DOT National Transportation Integrated Search

2001-08-01

The objective of this study was to establish 2001 safety belt and child safety seat usage rates in Kentucky. The 2001 survey continues to document the results after enactment of a statewide mandatory safety belt law in 1994. It also documented the lo...

2002 safety belt usage survey in Kentucky

DOT National Transportation Integrated Search

2002-07-01

The objective of this study was to establish 2002 safety belt and child safety seat usage rates in Kentucky. The 2002 survey continues to document the results after enactment of a statewide mandatory safety belt law in 1994. Data were collected at 20...

2000 Safety belt usage survey in Kentucky

DOT National Transportation Integrated Search

2000-08-01

The objective of this study was to establish 2000 safety belt and child safety seat usage rates in Kentucky. The 2000 survey continues to document the results after enactment of a statewide mandatory safety belt law in 1994. Data were collected at 20...

The Determination of Trace Metals in Saline Waters and Biological Tissues Using the Heated Graphite Atomizer

NASA Technical Reports Server (NTRS)

Segar, D. A.

1971-01-01

A selective, volatalization technique utilizing the heated graphite atomizer atomic absorption technique has been developed for the analysis of iron in sea water. A similar technique may be used to determine vanadium, copper, nickel and cobalt in saline waters when their concentrations are higher than those normally encountered'in unpolluted sea waters. A preliminary solvent extraction using ammonium pyrolidine dithiocarbamate and methyl iso-butyl ketone permits the determination of a number of elements including iron, copper, zinc, nickel, cobalt and lead in sea water. The heated graphite atomized technique has also been applied to the determination of a range of trace transition elements in marine plant and animal tissues.

Seat belt use, especially among low-use drivers, increases as Florida upgrades to primary seat belt enforcement : traffic tech.

DOT National Transportation Integrated Search

2012-08-01

As a secondary seat belt law State, Florida had worked : for many years to encourage more drivers to wear : their seat belts by participating in annual Click It or : Ticket (CIOT) mobilizations, and by conducting special : programs in rural areas of ...

Use of safety restraints by law enforcement officers following safety belt training and passage of a statewide belt law

DOT National Transportation Integrated Search

1988-04-01

The report describes work performed in 1984-1985 to develop and evaluate a safety belt program designed for the Maryland State Police - Belt Use Campaign for Law Enforcement (BUCLE), and an evaluation conducted in 1987 to determine the impact of the ...

Auxiliary iron-sulfur cofactors in radical SAM enzymes.

PubMed

Lanz, Nicholas D; Booker, Squire J

2015-06-01

A vast number of enzymes are now known to belong to a superfamily known as radical SAM, which all contain a [4Fe-4S] cluster ligated by three cysteine residues. The remaining, unligated, iron ion of the cluster binds in contact with the α-amino and α-carboxylate groups of S-adenosyl-l-methionine (SAM). This binding mode facilitates inner-sphere electron transfer from the reduced form of the cluster into the sulfur atom of SAM, resulting in a reductive cleavage of SAM to methionine and a 5'-deoxyadenosyl radical. The 5'-deoxyadenosyl radical then abstracts a target substrate hydrogen atom, initiating a wide variety of radical-based transformations. A subset of radical SAM enzymes contains one or more additional iron-sulfur clusters that are required for the reactions they catalyze. However, outside of a subset of sulfur insertion reactions, very little is known about the roles of these additional clusters. This review will highlight the most recent advances in the identification and characterization of radical SAM enzymes that harbor auxiliary iron-sulfur clusters. This article is part of a Special Issue entitled: Fe/S proteins: Analysis, structure, function, biogenesis and diseases. Copyright © 2015 Elsevier B.V. All rights reserved.

"Abomination"--life as a Bible belt gay.

PubMed

Barton, Bernadette

2010-01-01

Drawing on observation, autoethnography, and audio-taped interviews, this article explores the religious backgrounds and experiences of Bible Belt gays. In the Bible Belt, Christianity is not confined to Sunday worship. Christian crosses, messages, paraphernalia, music, news, and attitudes permeate everyday settings. Consequently, Christian fundamentalist dogma about homosexuality-that homosexuals are bad, diseased, perverse, sinful, other, and inferior-is cumulatively bolstered within a variety of other social institutions and environments in the Bible Belt. Of the 46 lesbians and gay men interviewed for this study (age 18-74 years), most describe living through spirit-crushing experiences of isolation, abuse, and self-loathing. This article argues that the geographic region of the Bible Belt intersects with religious-based homophobia. Informants explained that negative social attitudes about homosexuality caused a range of harmful consequences in their lives including the fear of going to hell, depression, low self-esteem, and feelings of worthlessness.

A Green Analytical Method Using Ultrasound in Sample Preparation for the Flow Injection Determination of Iron, Manganese, and Zinc in Soluble Solid Samples by Flame Atomic Absorption Spectrometry

PubMed Central

Yebra, M. Carmen

2012-01-01

A simple and rapid analytical method was developed for the determination of iron, manganese, and zinc in soluble solid samples. The method is based on continuous ultrasonic water dissolution of the sample (5–30 mg) at room temperature followed by flow injection flame atomic absorption spectrometric determination. A good precision of the whole procedure (1.2–4.6%) and a sample throughput of ca. 25 samples h–1 were obtained. The proposed green analytical method has been successfully applied for the determination of iron, manganese, and zinc in soluble solid food samples (soluble cocoa and soluble coffee) and pharmaceutical preparations (multivitamin tablets). The ranges of concentrations found were 21.4–25.61 μg g−1 for iron, 5.74–18.30 μg g−1 for manganese, and 33.27–57.90 μg g−1 for zinc in soluble solid food samples and 3.75–9.90 μg g−1 for iron, 0.47–5.05 μg g−1 for manganese, and 1.55–15.12 μg g−1 for zinc in multivitamin tablets. The accuracy of the proposed method was established by a comparison with the conventional wet acid digestion method using a paired t-test, indicating the absence of systematic errors. PMID:22567553

Novel Atomic Absorption Spectrometric and Rapid Spectrophotometric Methods for the Quantitation of Paracetamol in Saliva: Application to Pharmacokinetic Studies

PubMed Central

Issa, M. M.; Nejem, R. M.; El-Abadla, N. S.; Al-Kholy, M.; Saleh, Akila. A.

2008-01-01

A novel atomic absorption spectrometric method and two highly sensitive spectrophotometric methods were developed for the determination of paracetamol. These techniques based on the oxidation of paracetamol by iron (III) (method I); oxidation of p-aminophenol after the hydrolysis of paracetamol (method II). Iron (II) then reacts with potassium ferricyanide to form Prussian blue color with a maximum absorbance at 700 nm. The atomic absorption method was accomplished by extracting the excess iron (III) in method II and aspirates the aqueous layer into air-acetylene flame to measure the absorbance of iron (II) at 302.1 nm. The reactions have been spectrometrically evaluated to attain optimum experimental conditions. Linear responses were exhibited over the ranges 1.0-10, 0.2-2.0 and 0.1-1.0 μg/ml for method I, method II and atomic absorption spectrometric method, respectively. A high sensitivity is recorded for the proposed methods I and II and atomic absorption spectrometric method value indicate: 0.05, 0.022 and 0.012 μg/ml, respectively. The limit of quantitation of paracetamol by method II and atomic absorption spectrometric method were 0.20 and 0.10 μg/ml. Method II and the atomic absorption spectrometric method were applied to demonstrate a pharmacokinetic study by means of salivary samples in normal volunteers who received 1.0 g paracetamol. Intra and inter-day precision did not exceed 6.9%. PMID:20046743

An Icy Kuiper-Belt Around the Young Solar-Type Star HD 181327

NASA Technical Reports Server (NTRS)

Lebreton, J.; Augereau, J.-C.; Thi, W.-F.; Roberge, A.; Donaldson, J.; Schneider, G.; Maddison, S. T.; Menard, F.; Riviere-Marichalar, P.; Mathews, G. S.;

An Icy Kuiper Belt Around the Young Solar-type Star HD 181327

NASA Technical Reports Server (NTRS)

Lebreton, J.; Augereau, J.-C.; Thi, W.-F.; Roberge, A.; Donaldson, J; Schneider, G.; Maddison, S. T.; Menard, F.; Riviere-Marichalar, P.; Matthews, G. S.;

High-temperature corrosion-resistant iron-aluminide (FeAl) alloys exhibiting improved weldability

DOEpatents

Maziasz, P.J.; Goodwin, G.M.; Liu, C.T.

1996-08-13

This invention relates to improved corrosion-resistant iron-aluminide intermetallic alloys. The alloys of this invention comprise, in atomic percent, from about 30% to about 40% aluminum alloyed with from about 0.1% to about 0.5% carbon, no more than about 0.04% boron such that the atomic weight ratio of boron to carbon in the alloy is in the range of from about 0.01:1 to about 0.08:1, from about 0.01 to about 3.5% of one or more transition metals selected from Group IVB, VB, and VIB elements and the balance iron wherein the alloy exhibits improved resistance to hot cracking during welding. 13 figs.

Using haptic feedback to increase seat belt use : traffic tech.

DOT National Transportation Integrated Search

2011-07-01

The legacy of research on increasing seat belt use has : focused on enactment of seat belt legislation, public education, : high-visibility police enforcement, and seat belt : reminder systems. Several behavioral programs have : produced large, susta...

Factors related to increasing safety belt use in states with safety belt use laws : second annual report to Congress

DOT National Transportation Integrated Search

1989-01-01

This report is the second in a series of four annual reports to the Congress on provisions of state safety belt use laws and other programmatic factors related to increasing safety belt use levels. The first Congressional Report reviewed what was kno...

Structure of possible long-lived asteroid belts

NASA Astrophysics Data System (ADS)

Evans, N. W.; Tabachnik, S. A.

2002-06-01

High-resolution simulations are used to map out the detailed structure of two long-lived stable belts of asteroid orbits in the inner Solar system. The Vulcanoid belt extends from 0.09 to 0.20au, though with a gaps at 0.15 and 0.18au corresponding to de-stabilizing mean motion resonances with Mercury and Venus. As collisional evolution proceeds slower at larger heliocentric distances, km-sized or larger Vulcanoids are most likely to be found in the region between 0.16 and 0.18au. The optimum location to search is at geocentric ecliptic longitudes 9°<=|lg|<=10° and latitudes |βg|<1°. Dynamically speaking, the Earth-Mars belt between 1.08 and 1.28au is a stable repository for asteroids on nearly circular orbits. It is interrupted at 1.21au owing to the 3:4 commensurability with the Earth, while secular resonances with Saturn are troublesome beyond 1.17au. These detailed maps of the fine structure of the belts can be used to plan search methodologies. Strategies for detecting members of the belts are discussed, including the use of infrared wide-field imaging with VISTA, and forthcoming European Space Agency satellite missions such as GAIA and BepiColombo.

Exploring the collisional evolution of the asteroid belt

NASA Astrophysics Data System (ADS)

Bottke, W.; Broz, M.; O'Brien, D.; Campo Bagatin, A.; Morbidelli, A.

2014-07-01

The asteroid belt is a remnant of planet-formation processes. By modeling its collisional and dynamical history, and linking the results to constraints, we can probe how the planets and small bodies formed and evolved. Some key model constraints are: (i) The wavy shape of the main-belt size distribution (SFD), with inflection points near 100-km, 10--20-km, 1 to a few km, and ˜0.1-km diameter; (ii) The number of asteroid families created by the catastrophic breakup of large asteroid bodies over the last ˜ 4 Gy, with the number of disrupted D > 100 km bodies as small as ˜20 or as large as 60; (iii) the flux of small asteroids derived from the main belt that have struck the Moon over the last 3.5 Ga --- crater SFDs on lunar terrains with known ages suggest the D < 0.1 km projectile population has not varied appreciably over this interval; (iv) Vesta has an intact basaltic crust with two very large basins, but only two, on its surface. Fits to these parameters allow us to predict the shape of the initial main-belt SFD after accretion and the approximate asteroid disruption scaling law, with the latter consistent with numerical hydrocode simulations. Overall, we find that the asteroid belt probably experienced the equivalent of ˜6--10 Gy of comminution over its history. This value may seem strange, considering the solar system is only 4.56 Gy old. One way to interpret it is that the main belt once had more mass that was eliminated by early dynamical processes between 4--4.56 Ga. This would allow for more early grinding, and it would suggest the main belt's wavy-shaped SFD is a ''fossil'' from a more violent early epoch. Simulations suggest that most D > 100 km bodies have been significantly battered, but only a fraction have been catastrophically disrupted. Conversely, most small asteroids today are byproducts of fragmentation events. These results are consistent with growing evidence that most of the prominent meteorite classes were produced by young asteroid

Review of GEM Radiation Belt Dropout and Buildup Challenges

NASA Astrophysics Data System (ADS)

Tu, Weichao; Li, Wen; Morley, Steve; Albert, Jay

2017-04-01

In Summer 2015 the US NSF GEM (Geospace Environment Modeling) focus group named "Quantitative Assessment of Radiation Belt Modeling" started the "RB dropout" and "RB buildup" challenges, focused on quantitative modeling of the radiation belt buildups and dropouts. This is a community effort which includes selecting challenge events, gathering model inputs that are required to model the radiation belt dynamics during these events (e.g., various magnetospheric waves, plasmapause and density models, electron phase space density data), simulating the challenge events using different types of radiation belt models, and validating the model results by comparison to in situ observations of radiation belt electrons (from Van Allen Probes, THEMIS, GOES, LANL/GEO, etc). The goal is to quantitatively assess the relative importance of various acceleration, transport, and loss processes in the observed radiation belt dropouts and buildups. Since 2015, the community has selected four "challenge" events under four different categories: "storm-time enhancements", "non-storm enhancements", "storm-time dropouts", and "non-storm dropouts". Model inputs and data for each selected event have been coordinated and shared within the community to establish a common basis for simulations and testing. Modelers within and outside US with different types of radiation belt models (diffusion-type, diffusion-convection-type, test particle codes, etc.) have participated in our challenge and shared their simulation results and comparison with spacecraft measurements. Significant progress has been made in quantitative modeling of the radiation belt buildups and dropouts as well as accessing the modeling with new measures of model performance. In this presentation, I will review the activities from our "RB dropout" and "RB buildup" challenges and the progresses achieved in understanding radiation belt physics and improving model validation and verification.

A comparison of muscle activation between back squats and belt squats.

PubMed

Evans, Thomas W; McLester, Cherilyn N; Howard, Jonathan H; McLester, John R; Calloway, Jimmy P

2017-06-08

A machine belt squat is a piece of equipment designed to allow the performance of squats while loading weight on the lifter's hips using a belt. The purpose of this investigation was to determine if belt squats differ from back squats in activation of the primary movers, and to determine the predictive capabilities of back squat load, training status, and anthropometric data on belt squat load. Thirty-one participants (16 males and 15 females) completed anthropometric measurements, a demographic questionnaire, a familiarization visit, and two testing visits, completing a 5 repetition maximum test for back squat and belt squat. Surface electromyography was used to measure muscle activation for the left and right vastus medialis (VMO), vastus lateralis (VLO), rectus femoris (RF), and gluteus maximus (GM). Comparison of muscle activation between the two exercises showed significant differences in the left GM (back squat: 0.84 ± 0.45, belt squat: 0.69 ± 0.22, p=0.015) and right GM (back squat: 0.86 ± 0.45, belt squat: 0.71 ± 0.29, p=0.004). Regression analysis computed significant prediction equations for belt squat load for general population, males, females, and advanced lifters. Overall, results indicate that belt squats may significantly differ in GM activation from back squats. Back squat load, as well as other variables, may be effective in accurately estimating appropriate belt squat load. These findings may help to more appropriately program for training with machine belt squats as a back squat alternative.

States upgrade to primary enforcement seat belt laws : traffic tech.

DOT National Transportation Integrated Search

2011-09-01

States with primary seat belt enforcement laws consistently : have higher observed daytime seat belt use rates than secondary : law States. Secondary belt law States, on the other : hand, consistently have more motor vehicle fatalities who : were not...

Documenting How States Recently Upgraded to Primary Seat Belt Laws

DOT National Transportation Integrated Search

2011-09-01

States with primary seat belt enforcement laws consistently have higher observed daytime belt use rates than : secondary law States. Secondary belt law States, on the other hand, consistently have more occupant fatalities who : were not restrained th...

Asteroid Family Associations of Main-Belt Comets

NASA Astrophysics Data System (ADS)

Hsieh, Henry H.; Novakovic, Bojan; Kim, Yoonyoung; Brasser, Ramon

2016-10-01

We present a population-level analysis of the asteroid family associations of known main-belt comets or main-belt comet candidates (which, to date, have largely just been analyzed on individual bases as they have been discovered). In addition to family associations that have already been reported in the literature, we have identified dynamical relationships between 324P/La Sagra and the Alauda family, P/2015 X6 (PANSTARRS) and the Aeolia family, and P/2016 G1 (PANSTARRS) and the Adeona family. We will discuss the overall implications of these family associations, particularly as they pertain to the hypothesis that members of primitive asteroid family members may be more susceptible to producing observable sublimation-driven dust emission activity, and thus becoming main-belt comets. We will also discuss the significance of other dynamical and physical properties of a family or sub-family as they relate to the likelihood of that family containing one or more currently active main-belt comets.

Testing the Prediction of Iron Alteration Minerals on Low Albedo Asteroids

NASA Technical Reports Server (NTRS)

Jarvis, K. S.; Vilas, Faith; Howell, E.; Kelley, M.; Cochran, A.

1999-01-01

Absorption features centered near 0.60 - 0.65 and 0.80 - 0.90 micron were identified in the spectra of three low-albedo main-belt (165, 368, 877) and two low-albedo outer-belt (225, 334) asteroids (Vilas et al., Icarus, v. 109,274,1994). The absorption features were attributed to charge transfer transitions in iron alteration minerals such as goethite, hematite, and jarosite, all products of aqueous alteration. Concurrently, Jarvis et al. (LPSC XXIV, 715, 1993) presented additional spectra of low-albedo asteroids that had absorption features centered near 0.60 - 0.65 micron without the longer wavelength feature. Since these two features in iron oxides originate from the same ground state, and the longer wavelength feature requires less energy to exist, the single shorter wavelength feature cannot be caused by the iron alteration minerals. In addition, spectra of minerals such as hematite and goethite show a rapid increase in reflectance beginning near 0.5 micron absent in the low-albedo asteroid spectra. The absence of this rise has been attributed to its suppresion from opaques in the surface material. Spectra on more than one night were available for only one of these five asteroids, 225 Henrietta, and showed good repeatability of the 0.65-micron feature. We have acquired additional spectra of all five asteroids in order to test the repeatability of the 0.65-micron feature, and the presence and repeatability of the features centered near 0.8 - 0.9 micron. We specifically will test the possibility that longer wavelength features could be caused by incomplete removal of telluric water. Asteroid 877 Walkure is a member of the Nysa-Hertha family, and will be compared to spectra of other members of that family. Data were acquired in 1996 and 1999 on the 2.1-m telescope with a facility cassegrain spectrograph, McDonald Observatory, Univ. Of Texas, and the 1.5-m telescope with facility cassegrain spectrograph at CTIO. This research is supported by the NASA Planetary

49 CFR 571.210 - Standard No. 210; Seat belt assembly anchorages.

Code of Federal Regulations, 2010 CFR

2010-10-01

... reference point, shall extend forward from that contact point at an angle with the horizontal of not less... torso belt first contacts the uppermost torso belt anchorage.Seat belt anchorage means any component... line from the seating reference point to the nearest contact point of the belt with the anchorage shall...

The southern cape conductive belt (South Africa): Its composition, origin and tectonic significance

NASA Astrophysics Data System (ADS)

De Beer, J. H.; Van Zijl, J. S. V.; Gough, D. I.

1982-03-01

Magnetometer array studies have led to the discovery and mapping of the Southern Cape Conductive Belt (SCCB) crossing the southern tip of Africa from west to southeast coasts. The SCCB lies just south of the Namaqua-Natal Belt of cratonic rocks remobilized about 1000 m.y. B.P. It is shown that it coincides with a zone of weakness which has been exploited by three major geosynclinal accumulations over some 600 m.y. Relationships between the SCCB and the basement geochronology, geology and tectonics are considered in detail. These relationships support the view that the conductive belt was formed by an accumulation of marine sediments and oceanic lithosphere at the top of a Proterozoic subduction which stopped about 1000 to 800 m.y. B.P. Associated with this subduction we propose a Proterozoic range of Andean mountains, whose roots are now exposed in the Namaqua-Natal Belt. Later subduction further south, near the present south coast, is proposed to account for the intrusion, between the south coast and the SCCB, of the Cape Granites in the time interval 600-500 m.y. B.P. There is some evidence for a third, yet more distant, subduction episode off Permian Gondwanaland. After outlining this tectonic history, the paper turns to a closer examination of the hypothesis that the Southern Cape Conductive Belt consists of partly serpentinized basalt accumulated at the top of a Proterozoic subduction. A large static magnetic anomaly, which correlates with the SCCB over most of its length, is well fitted by a model which strongly supports this hypothesis. Bouguer gravity anomalies along western and central profiles likewise support the hypothesis. A discussion follows of the process of formation of the proposed block of serpentinized marine rocks, beginning with serpentinization of the crust near oceanic ridges by reaction of warm, porous, newly-extruded basalt with seawater convecting through it. The serpentinized basalt is stable at crustal temperatures and pressures and so

The Role of the Dynamic Plasmapause on Outer Radiation Belt Electron Flux Enhancement and Three-Belt Structure Formation

NASA Astrophysics Data System (ADS)

Bruff, M.; Jaynes, A. N.; Zhao, H.; Malaspina, D.

2017-12-01

The plasmasphere is a highly dynamic toroidal region of cold, dense plasma around Earth. Plasma waves exist both inside and outside this region and can contribute to the loss and acceleration of high energy outer radiation belt electrons. Early observational studies found an apparent correlation on long time scales between the observed inner edge of the outer radiation belt and the simulated innermost plasmapause location. More recent work using high resolution Van Allen Probe satellite data has found a more complex relationship. The aim of this project was to provide a systematic study of the location and dynamics of the plasmapause compared to the MeV electrons in the outer radiation belt. We used spin-averaged electron flux data from the Relativistic Electron Proton Telescope (REPT) and density data derived from the EFW instrument on the Van Allen Probe satellites. We analyzed these data to determine the standoff distance of the location of peak electron flux of the outer belt MeV electrons from the plasmapause. We found that the location of peak flux was consistently outside but within ΔL=2.5 from the innermost location of the plasmapause at enhancement times, with an average standoff distance ΔL=1.0 +/- 0.5. This is consistent with the current model of chorus enhancement and previous observations of chorus activity. Finally, we identified "three-belt" structure events where a second outer belt formed and found a repeated pattern of plasmapause dynamics associated with specific changes in electron flux required to generate and sustain these structures. This study is significant to improving our understanding of how the plasmasphere under differing conditions can both shield Earth from or worsen the impacts of geomagnetic activity.

The Southeast Asian Tin Belt

NASA Astrophysics Data System (ADS)

Schwartz, M. O.; Rajah, S. S.; Askury, A. K.; Putthapiban, P.; Djaswadi, S.

1995-07-01

The Southeast Asian Tin Belt is a north-south elongate zone 2800 km long and 400 km wide, extending from Burma (Myanmar) and Thailand to Peninsular Malaysia and the Indonesian Tin Islands. Altogether 9.6 million tonnes of tin, equivalent to 54% of the world's tin production is derived from this region. Most of the granitoids in the region can be grouped geographically into elongate provinces or belts, based on petrographic and geochronological features. - The Main Range Granitoid Province in western Peninsular Malaysia, southern Peninsular Thailand and central Thailand is almost entirely made up of biotite granite (184-230 Ma). Tin deposits associated with these granites contributed 55% of the historic tin production of Southeast Asia. - The Northern Granitoid Province in northern Thailand (0.1% of tin production) also has dominant biotite granite (200-269 Ma) but it is distinguished by abundant post-intrusion deformation. - The Eastern Granitoid Province extends from eastern Peninsular Malaysia to eastern Thailand. The Malaysian part is subdivided into the East Coast Belt (220-263 Ma), Boundary Range Belt (197-257 Ma) and Central Belt (79-219 Ma). The granitoids cover a wide compositional range from biotite granite to hornblende-biotite granite/granodiorite and diorite-gabbro. Tin deposits are associated with biotite granite in the East Coast Belt (3% of tin production). The granitoids in the other areas of the Eastern Granitoid Province are barren. - The Western Granitoid Province (22-149 Ma) in northern Peninsular Thailand, western Thailand and Burma has biotite granite and hornblende-biotite granite/granodiorite. Tin deposits are associated with biotite granite, which probably is the dominant phase (14% of tin production). The granitoids of the Indonesian Tin Islands (193-251 Ma) do not permit grouping into geographically distinct units. Main Range-type and Eastern Province-type plutons occur next to each other. Most of the tin deposits are associated with Main

Seat belts and shoulder harnesses : smart protection in small airplanes.

DOT National Transportation Integrated Search

2004-05-01

Seat belts alone will protect you only in minor impacts. : Using shoulder belts in small aircraft would reduce major injuries by 88% and fatalities by 20%. Shoulder belt kits are now available for most airplanes. : Proper use and installation of chil...

Lithium-aluminum-iron electrode composition

DOEpatents

Kaun, Thomas D.

1979-01-01

A negative electrode composition is presented for use in a secondary electrochemical cell. The cell also includes an electrolyte with lithium ions such as a molten salt of alkali metal halides or alkaline earth metal halides that can be used in high-temperature cells. The cell's positive electrode contains a a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent in an alloy of aluminum-iron. Various binary and ternary intermetallic phases of lithium, aluminum and iron are formed. The lithium within the intermetallic phase of Al.sub.5 Fe.sub.2 exhibits increased activity over that of lithium within a lithium-aluminum alloy to provide an increased cell potential of up to about 0.25 volt.

Computational study: Reduction of iron corrosion in lead coolant of fast nuclear reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arkundato, Artoto; Su'ud, Zaki; Abdullah, Mikrajuddin

2012-06-20

In this paper we report molecular dynamics simulation results of iron (cladding) corrosion in interaction with lead coolant of fast nuclear reactor. The goal of this work is to study effect of oxygen injection to the coolant to reduce iron corrosion. By evaluating diffusion coefficients, radial distribution functions, mean-square displacement curves and observation of crystal structure of iron before and after oxygen injection, we concluded that a significant reduction of corrosion can be achieved by issuing about 2% of oxygen atoms into lead coolant.

A Century after Van Allen's Birth: Conclusion of Reconnaissance of Radiation Belts in the Solar System

NASA Astrophysics Data System (ADS)

Krimigis, S. M.

2014-12-01

On May 1, 1958 in the Great Hall of the US National Academy of Sciences, James A. Van Allen, having instrumented Explorer-1 and follow-on satellites with radiation detectors, announced the discovery of intense radiation at high altitudes above Earth. The press dubbed the doughnut-shaped structures "Van Allen Belts" (VAB). Soon thereafter, the search began for VAB at nearby planets. Mariner 2 flew by Venus in 1962 at a distance of 41,000 km, but no radiation was detected. The Mariner 4 mission to Mars did not observe planet-associated increase in radiation, but scaling arguments with Earth's magnetosphere yielded an upper limit to the ratio of magnetic moments of MM/ME < 0.001 (Van Allen et al, 1965). Similarly, the Mariner 5 flyby closer to Venus resulted in a ratio of magnetic moments < 0.001 (Van Allen et al, 1967), dealing a blow to the expectation that all planetary bodies must possess significant VAB. The flyby of Mercury in 1974 by Mariner 10 revealed a weak magnetic field, but the presence of durably trapped higher energy particles remained controversial until MESSENGER in 2011.The first flybys of Jupiter by Pioneers 10, 11 in 1973 and 1974, respectively, measured a plethora of energetic particles in Jupiter's magnetosphere and established the fact that their intensities were rotationally modulated. Later flybys of Jupiter and Saturn by the two Voyagers in 1979 and 1981 revealed that those magnetospheres possessed their own internal plasma source(s) and radiation belts. Subsequent discoveries of Van Allen belts at Uranus and Neptune by Voyager 2 demonstrated that VAB are the rule rather than the exception in planetary environments. We now know from the Voyagers and through Energetic Neutral Atom images from Cassini and IBEX that an immense energetic particle population surrounds the heliosphere itself. Thus, the reconnaissance of radiation belts of our solar system has been completed, some 56 years after the discovery of the Van Allen Belts at Earth.

Gold and gold-iron oxide magnetic glyconanoparticles: synthesis, characterization and magnetic properties.

PubMed

de la Fuente, Jesús M; Alcántara, David; Eaton, Peter; Crespo, Patricia; Rojas, Teresa C; Fernandez, Asunción; Hernando, Antonio; Penadés, Soledad

2006-07-06

The preparation, characterization and the magnetic properties of gold and gold-iron oxide glyconanoparticles (GNPs) are described. Glyconanoparticles were prepared in a single step procedure in the presence of aqueous solution of thiol functionalized neoglycoconjugates and either gold salts or both gold and iron salts. Neoglycoconjugates of lactose and maltose disaccharides with different linkers were used. Iron-free gold or gold-iron oxide GNPs with controlled gold-iron ratios were obtained. The average core-size diameters are in the range of 1.5-2.5 nm. The GNPs are fully characterized by (1)H NMR spectrometry, transmission electron microscopy (TEM), and UV-vis and X-ray absorption (XAS) spectroscopies. Inductive plasma-atomic emission spectrometry (ICP) and elemental analysis gave the average number of neoglycoconjugates per cluster. The magnetic properties were measured in a SQUID magnetometer. The most remarkable results was the observation of a permanent magnetism up to room temperature in the iron-free gold GNPs, that was not present in the corresponding gold-iron oxide GNPs.

Ferromagnetic properties of manganese doped iron silicide

NASA Astrophysics Data System (ADS)

Ruiz-Reyes, Angel; Fonseca, Luis F.; Sabirianov, Renat

We report the synthesis of high quality Iron silicide (FeSi) nanowires via Chemical Vapor Deposition (CVD). The materials exhibits excellent magnetic response at room temperature, especially when doped with manganese showing values of 2.0 X 10-04 emu for the FexMnySi nanowires. SEM and TEM characterization indicates that the synthesized nanowires have a diameter of approximately 80nm. MFM measurements present a clear description of the magnetic domains when the nanowires are doped with manganese. Electron Diffraction and XRD measurements confirms that the nanowires are single crystal forming a simple cubic structure with space group P213. First-principle calculations were performed on (111) FeSi surface using the Vienna ab initio simulation package (VASP). The exchange correlations were treated under the Ceperley-Alder (CA) local density approximation (LDA). The Brillouin Zone was sampled with 8x8x1 k-point grid. A total magnetic moment of about 10 μB was obtained for three different surface configuration in which the Iron atom nearest to the surface present the higher magnetization. To study the effect of Mn doping, Fe atom was replaced for a Mn. Stronger magnetization is presented when the Mn atom is close to the surface. The exchange coupling constant have been evaluated calculating the energy difference between the ferromagnetic and anti-ferromagnetic configurations.

Labeling Efficacy of Superparamagnetic Iron Oxide Nanoparticles to Human Neural Stem Cells: Comparison of Ferumoxides, Monocrystalline Iron Oxide, Cross-linked Iron Oxide (CLIO)-NH2 and tat-CLIO

PubMed Central

Song, Miyeoun; Kim, Yunhee; Lim, Dongyeol; Song, In-Chan; Yoon, Byung-Woo

2007-01-01

Objective We wanted to compare the human neural stem cell (hNSC) labeling efficacy of different superparamagnetic iron oxide nanoparticles (SPIONs), namely, ferumoxides, monocrystalline iron oxide (MION), cross-linked iron oxide (CLIO)-NH2 and tat-CLIO. Materials and Methods The hNSCs (5 × 105 HB1F3 cells/ml) were incubated for 24 hr in cell culture media that contained 25 µg/ml of ferumoxides, MION or CLIO-NH2, and with or without poly-L-lysine (PLL) and tat-CLIO. The cellular iron uptake was analyzed qualitatively with using a light microscope and this was quantified via atomic absorption spectrophotometry. The visibility of the labeled cells was assessed with MR imaging. Results The incorporation of SPIONs into the hNSCs did not affect the cellular proliferations and viabilities. The hNSCs labeled with tat-CLIO showed the longest retention, up to 72 hr, and they contained 2.15 ± 0.3 pg iron/cell, which are 59 fold, 430 fold and six fold more incorporated iron than that of the hNSCs labeled with ferumoxides, MION or CLIO-NH2, respectively. However, when PLL was added, the incorporation of ferumoxides, MION or CLIO-NH2 into the hNSCs was comparable to that of tat-CLIO. Conclusion For MR imaging, hNSCs can be efficiently labeled with tat-CLIO alone or with a combination of ferumoxides, MION, CLIO-NH2 and the transfection agent PLL. PMID:17923778

Monomeric Yeast Frataxin is an Iron-Binding Protein

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cook,J.; Bencze, K.; Jankovic, A.

Friedreich's ataxia, an autosomal cardio- and neurodegenerative disorder that affects 1 in 50 000 humans, is caused by decreased levels of the protein frataxin. Although frataxin is nuclear-encoded, it is targeted to the mitochondrial matrix and necessary for proper regulation of cellular iron homeostasis. Frataxin is required for the cellular production of both heme and iron-sulfur (Fe-S) clusters. Monomeric frataxin binds with high affinity to ferrochelatase, the enzyme involved in iron insertion into porphyrin during heme production. Monomeric frataxin also binds to Isu, the scaffold protein required for assembly of Fe-S cluster intermediates. These processes (heme and Fe-S cluster assembly)more » share requirements for iron, suggesting that monomeric frataxin might function as the common iron donor. To provide a molecular basis to better understand frataxin's function, we have characterized the binding properties and metal-site structure of ferrous iron bound to monomeric yeast frataxin. Yeast frataxin is stable as an iron-loaded monomer, and the protein can bind two ferrous iron atoms with micromolar binding affinity. Frataxin amino acids affected by the presence of iron are localized within conserved acidic patches located on the surfaces of both helix-1 and strand-1. Under anaerobic conditions, bound metal is stable in the high-spin ferrous state. The metal-ligand coordination geometry of both metal-binding sites is consistent with a six-coordinate iron-(oxygen/nitrogen) based ligand geometry, surely constructed in part from carboxylate and possibly imidazole side chains coming from residues within these conserved acidic patches on the protein. On the basis of our results, we have developed a model for how we believe yeast frataxin interacts with iron.« less

Monomeric Yeast Frataxin is an Iron Binding Protein†

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cook, J.; Bencze, K; Jankovic, A

Friedreich's ataxia, an autosomal cardio- and neurodegenerative disorder that affects 1 in 50000 humans, is caused by decreased levels of the protein frataxin. Although frataxin is nuclear-encoded, it is targeted to the mitochondrial matrix and necessary for proper regulation of cellular iron homeostasis. Frataxin is required for the cellular production of both heme and iron-sulfur (Fe-S) clusters. Monomeric frataxin binds with high affinity to ferrochelatase, the enzyme involved in iron insertion into porphyrin during heme production. Monomeric frataxin also binds to Isu, the scaffold protein required for assembly of Fe-S cluster intermediates. These processes (heme and Fe-S cluster assembly) sharemore » requirements for iron, suggesting that monomeric frataxin might function as the common iron donor. To provide a molecular basis to better understand frataxin's function, we have characterized the binding properties and metal-site structure of ferrous iron bound to monomeric yeast frataxin. Yeast frataxin is stable as an iron-loaded monomer, and the protein can bind two ferrous iron atoms with micromolar binding affinity. Frataxin amino acids affected by the presence of iron are localized within conserved acidic patches located on the surfaces of both helix-1 and strand-1. Under anaerobic conditions, bound metal is stable in the high-spin ferrous state. The metal-ligand coordination geometry of both metal-binding sites is consistent with a six-coordinate iron-(oxygen/nitrogen) based ligand geometry, surely constructed in part from carboxylate and possibly imidazole side chains coming from residues within these conserved acidic patches on the protein. On the basis of our results, we have developed a model for how we believe yeast frataxin interacts with iron.« less

Magic Numbers in Small Iron Clusters: A First-Principles Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Eunja; Mohrland, Andrew B.; Weck, Philippe F.

2014-10-03

We perform ab initio spin-polarized density functional calculations of Fen aggregates with n ≤ 17 atoms to reveal the origin of the observed magic numbers, which indicate particularly high stability of clusters with 7, 13 and 15 atoms. Our results clarify the controversy regarding the ground state geometry of clusters such as Fe5and indicate that magnetism plays an important role in determining the stability and magic numbers in small iron clusters.

Factors related to increasing safety belt use in states with safety belt use laws : second annual report to Congress, 1988.

DOT National Transportation Integrated Search

1989-01-01

This report. is the second in a series of four annual reports to the : Congress on provisions of state safety belt use laws and other : programmatic factors related to increasing safety belt use levels. : The first Congressional Report reviewed what ...

Evaluation of safety belt education program for employees

DOT National Transportation Integrated Search

1980-06-01

This research was designed to determine the effectiveness of a nine-month safety belt educational program, utilizing various informational materials developed by NHTSA, in increasing safety belt usage among corporate employees. The materials used inc...

The relationship between the plasmapause and outer belt electrons

NASA Astrophysics Data System (ADS)

Goldstein, J.; Baker, D. N.; Blake, J. B.; De Pascuale, S.; Funsten, H. O.; Jaynes, A. N.; Jahn, J.-M.; Kletzing, C. A.; Kurth, W. S.; Li, W.; Reeves, G. D.; Spence, H. E.

2016-09-01

We quantify the spatial relationship between the plasmapause and outer belt electrons for a 5 day period, 15-20 January 2013, by comparing locations of relativistic electron flux peaks to the plasmapause. A peak-finding algorithm is applied to 1.8-7.7 MeV relativistic electron flux data. A plasmapause gradient finder is applied to wave-derived electron number densities >10 cm-3. We identify two outer belts. Outer belt 1 is a stable zone of >3 MeV electrons located 1-2 RE inside the plasmapause. Outer belt 2 is a dynamic zone of <3 MeV electrons within 0.5 RE of the moving plasmapause. Electron fluxes earthward of each belt's peak are anticorrelated with cold plasma density. Belt 1 decayed on hiss timescales prior to a disturbance on 17 January and suffered only a modest dropout, perhaps owing to shielding by the plasmasphere. Afterward, the partially depleted belt 1 continued to decay at the initial rate. Belt 2 was emptied out by strong disturbance-time losses but restored within 24 h. For global context we use a plasmapause test particle simulation and derive a new plasmaspheric index Fp, the fraction of a circular drift orbit inside the plasmapause. We find that the locally measured plasmapause is (for this event) a good proxy for the globally integrated opportunity for losses in cold plasma. Our analysis of the 15-20 January 2013 time interval confirms that high-energy electron storage rings can persist for weeks or even months if prolonged quiet conditions prevail. This case study must be followed up by more general study (not limited to a 5 day period).

An investigation of safety belt usage and effectiveness

DOT National Transportation Integrated Search

1975-03-01

This interim report contains primarily a theoretical discussion of problems of inference in studies on seat belt utilization and effectiveness. Seat belt effectiveness in accidents is initially discussed from a population paramenter point of, view. T...

A new interpretation for the interference zone between the southern Brasília belt and the central Ribeira belt, SE Brazil

NASA Astrophysics Data System (ADS)

Trouw, Rudolph A. J.; Peternel, Rodrigo; Ribeiro, Andre; Heilbron, Mônica; Vinagre, Rodrigo; Duffles, Patrícia; Trouw, Camilo C.; Fontainha, Marcos; Kussama, Hugo H.

2013-12-01

In southeastern Brazil, the Neoproterozoic NNW-SSE trending southern Brasília belt is apparently truncated by the ENE-WSW central Ribeira belt. Different interpretations in the literature of the transition between these two belts motivated detailed mapping and additional age dating along the contact zone. The result is a new interpretation presented in this paper. The southern Brasília belt resulted from E-W collision between the active margin of the Paranapanema paleocontinent, on the western side, now forming the Socorro-Guaxupé Nappe, with the passive margin of the São Francisco paleocontinent on the eastern side. The collision produced an east vergent nappe stack, the Andrelândia Nappe System, along the suture. At its southern extreme the Brasília belt was thought to be cut off by a shear zone, the "Rio Jaguari mylonites", at the contact with the Embu terrane, pertaining to the Central Ribeira belt. Our detailed mapping revealed that the transition between the Socorro-Guaxupé Nappe (Brasília belt) and the Embu terrane (Ribeira belt) is not a fault but rather a gradational transition that does not strictly coincide with the Rio Jaguari mylonites. A typical Cordilleran type magmatic arc batholith of the Socorro-Guaxupé Nappe with an age of ca. 640 Ma intrudes biotite schists of the Embu terrane and the age of zircon grains from three samples of metasedimentary rocks, one to the south, one to the north and one along the mylonite zone, show a similar pattern of derivation from a Rhyacian source area with rims of 670-600 Ma interpreted as metamorphic overgrowth. We dated by LA-MC-ICPMS laser ablation (U-Pb) zircon grains from a calc-alkaline granite, the Serra do Quebra-Cangalha Batholith, located within the Embu terrane at a distance of about 40 km south of the contact with the Socorro Nappe, yielding an age of 680 ± 13 Ma. This age indicates that the Embu terrane was part of the upper plate (Socorro-Guaxupé Nappe) by this time. Detailed mapping

30 CFR 75.1108 - Approved conveyor belts.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Approved conveyor belts. 75.1108 Section 75.1108 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND... December 31, 2018 all conveyor belts used in underground coal mines shall be approved under Part 14. [73 FR...

Radiation Belts Throughout the Solar System

NASA Astrophysics Data System (ADS)

Mauk, B. H.

2008-12-01

The several preceding decades of deep space missions have demonstrated that the generation of planetary radiation belts is a universal phenomenon. All strongly magnetized planets show well developed radiation regions, specifically Earth, Jupiter, Saturn, Uranus, and Neptune. The similarities occur despite the tremendous differences between the planets in size, levels of magnetization, external environments, and most importantly, in the fundamental processes that power them. Some planets like Jupiter are powered overwhelmingly by planetary rotation, much like astrophysical pulsars, whereas others, like Earth and probably Uranus, are powered externally by the interplanetary environment. Uranus is a particularly interesting case in that despite the peculiarities engendered by its ecliptic equatorial spin axis orientation, its magnetosphere shows dynamical behavior similar to that of Earth as well as radiation belt populations and associated wave emissions that are perhaps more intense than expected based on Earth-derived theories. Here I review the similarities and differences between the radiation regions of radiation belts throughout the solar system. I discuss the value of the comparative approach to radiation belt physics as one that allows critical factors to be evaluated in environments that are divorced from the special complex conditions that prevail in any one environment, such as those at Earth.

The Fossilized Size Distribution of the Main Asteroid Belt

NASA Astrophysics Data System (ADS)

Bottke, W. F.; Durda, D.; Nesvorny, D.; Jedicke, R.; Morbidelli, A.

2003-05-01

At present, we do not understand how the main asteroid belt evolved into its current state. During the planet formation epoch, the primordial main belt (PMB) contained several Earth masses of material, enough to allow the asteroids to accrete on relatively short timescales (e.g., Weidenschilling 1977). The present-day main belt, however, only contains 5e-4 Earth masses of material (Petit et al. 2002). Constraints on this evolution come from (i) the observed fragments of differentiated asteroids, (ii) meteorites collected from numerous differentiated parent bodies, (iii) the presence of ˜ 10 prominent asteroid families, (iv) the "wavy" size-frequency distribution of the main belt, which has been shown to be a by-product of substantial collisional evolution (e.g., Durda et al. 1997), and (v) the still-intact crust of (4) Vesta. To explain the contradictions in the above constraints, we suggest the PMB evolved in this fashion: Planetesimals and planetary embryos accreted (and differentiated) in the PMB during the first few Myr of the solar system. Gravitational perturbations from these embryos dynamically stirred the main belt, enough to initiate fragmentation. When Jupiter reached its full size, some 10 Myr after the solar system's birth, its perturbations, together with those of the embryos, dynamically depleted the main belt region of ˜ 99% of its bodies. Much of this material was sent to high (e,i) orbits, where it continued to pummel the surviving main belt bodies at high impact velocities for more than 100 Myr. While some differentiated bodies in the PMB were disrupted, most were instead scattered; only small fragments from this population remain. This period of comminution and dynamical evolution in the PMB created, among other things, the main belt's wavy size distribution, such that it can be considered a "fossil" from this violent early epoch. From this time forward, however, relatively little collisional evolution has taken place in the main belt

The Fossilized Size Distribution of the Main Asteroid Belt

NASA Astrophysics Data System (ADS)

Bottke, W. F.; Durda, D.; Nesvorny, D.; Jedicke, R.; Morbidelli, A.

2004-05-01

The main asteroid belt evolved into its current state via two processes: dynamical depletion and collisional evolution. During the planet formation epoch, the primordial main belt (PMB) contained several Earth masses of material, enough to allow the asteroids to accrete on relatively short timescales (e.g., Weidenschilling 1977). The present-day main belt, however, only contains 5e-4 Earth masses of material (Petit et al. 2002). To explain this mass loss, we suggest the PMB evolved in the following manner: Planetesimals and planetary embryos accreted (and differentiated) in the PMB during the first few Myr of the solar system. Gravitational perturbations from these embryos dynamically stirred the main belt, enough to initiate fragmentation. When Jupiter reached its full size, some 10 Myr after the solar system's birth, its perturbations, together with those of the embryos, dynamically depleted the main belt region of > 99% of its bodies. Much of this material was sent to high (e,i) orbits, where it continued to pummel the surviving main belt bodies at high impact velocities for more than 100 Myr. While some differentiated bodies in the PMB were disrupted, most were instead scattered; only small fragments from this population remain. This period of comminution and dynamical evolution in the PMB created, among other things, the main belt's wavy size-frequency distribution, such that it can be considered a "fossil" from this violent early epoch. From this time forward, however, relatively little collisional evolution has taken place in the main belt, consistent with the surprising paucity of prominent asteroid families. We will show that the constraints provided by asteroid families and the shape of the main belt size distribution are essential to obtaining a unique solution from our model's initial conditions. We also use our model results to solve for the asteroid disruption scaling law Q*D, a critical function needed in all planet formation codes that include

Belt-MRF for large aperture mirrors.

PubMed

Ren, Kai; Luo, Xiao; Zheng, Ligong; Bai, Yang; Li, Longxiang; Hu, Haixiang; Zhang, Xuejun

2014-08-11

With high-determinacy and no subsurface damage, Magnetorheological Finishing (MRF) has become an important tool in fabricating high-precision optics. But for large mirrors, the application of MRF is restricted by its small removal function and low material removal rate. In order to improve the material removal rate, shorten the processing cycle, we proposed a new MRF concept, named Belt-MRF to expand the application of MRF to large mirrors and made a prototype with a large remove function, using a belt instead of a very large polishing wheel to expand the polishing length. A series of experimental results on Silicon carbide (SiC) and BK 7 specimens and fabrication simulation verified that the Belt-MRF has high material removal rates, stable removal function and high convergence efficiency which makes it a promising technology for processing large aperture optical elements.

Preventive Effects of Seat Belt on Clinical Outcomes for Road Traffic Injuries

PubMed Central

2015-01-01

Proper seat belt use saves lives; however, the use rate decreased in Korea. This study aimed to measure the magnitude of the preventive effect of seat belt on case-fatality across drivers and passengers. We used the Emergency Department based Injury In-depth Surveillance (EDIIS) database from 17 EDs between 2011 and 2012. All of adult injured patients from road traffic injuries (RTI) in-vehicle of less than 10-seat van were eligible, excluding cases with unknown seat belt use and outcomes. Primary and secondary endpoints were in-hospital mortality and intracranial injury. We calculated adjusted odds ratios (AORs) of seat belt use and driving status for study outcomes adjusting for potential confounders. Among 23,698 eligible patients, 15,304 (64.6%) wore seat belts. Driver, middle aged (30-44 yr), male, daytime injured patients were more likely to use seat belts (all P < 0.001). In terms of clinical outcome, no seat belt group had higher proportions of case-fatality and intracranial injury compared to seat belt group (both P < 0.001). Compared to seat belt group, AORs (95% CIs) of no seat belt group were 10.43 (7.75-14.04) for case-fatality and 2.68 (2.25-3.19) for intracranial injury respectively. In the interaction model, AORs (95% CIs) of no seat belt use for case-fatality were 11.71 (8.45-16.22) in drivers and 5.52 (2.83-14.76) in non-driving passengers, respectively. Wearing seat belt has significantly preventive effects on case-fatality and intracranial injury. Public health efforts to increase seat belt use are needed to reduce health burden from RTIs. PMID:26713066

Trapped belt variations and their effects on human space flights

NASA Technical Reports Server (NTRS)

Robbins, Donald E.; Badhwar, Gautam D.

1993-01-01

Variations in the Earth's trapped (Van Allen) belts produced by solar flare particle events are not well understood. This paper reports the existence of a second proton belt and its subsequent decay as measured by a tissue-equivalent proportional counter and a particle spectrometer on five Space Shuttle flights covering an 18-month period. The creation of this second belt is attributed to the injection of particles from a solar particle event which occurred at 2246 UT, March 22, 1991. Comparisons with observations onboard the Russian Mir space station and other unmanned satellites are made. Shuttle measurements and data from other spacecraft are used to determine that the e-folding time of the peak of the second proton belt was ten months. Proton populations in the second belt returned to values of quiescent times within 18 months. The increase in absorbed dose attributed to protons in the second belt was approximately 20 percent. Passive dosimeter measurements were in good agreement with this value.

Functionalization of multi-walled carbon nanotubes with iron phthalocyanine via a liquid chemical reaction for oxygen reduction in alkaline media

NASA Astrophysics Data System (ADS)

Yan, Xiaomei; Xu, Xiao; Liu, Qin; Guo, Jia; Kang, Longtian; Yao, Jiannian

2018-06-01

Iron single-atom catalyst in form of iron-nitrogen-carbon structure possesses the excellent catalytic activity in various chemical reactions. However, exploring a sustainable and stable single-atom metal catalyst still faces a great challenge due to low yield and complicated synthesis. Here, we report a functional multi-wall carbon nanotubes modified with iron phthalocyanine molecules via a liquid chemical reaction and realize the performance of similar single-atom catalysis for oxygen reduction reaction. A serial of characterizations strongly imply the structure change of iron phthalocyanine molecule and its close recombination with multi-wall carbon nanotubes, which are in favor of ORR catalysis. Compared to commercial platinum-carbon catalyst, composites exhibit superior activity for oxygen reduction reaction with higher half-wave potential (0.86 V), lower Tafel slope (38 mV dec-1), higher limiting current density and excellent electrochemical stability. The corresponding Zinc-air battery also presents higher maximum power density and discharge stability. Therefore, these findings provide a facile route to synthesize a highly efficient non-precious metal carbon-based catalyst.

Liquid belt radiator design study

NASA Technical Reports Server (NTRS)

Teagan, W. P.; Fitzgerald, K. F.

1986-01-01

The Liquid Belt Radiator (LBR) is an advanced concept developed to meet the needs of anticipated future space missions. A previous study documented the advantages of this concept as a lightweight, easily deployable alternative to present day space heat rejection systems. The technical efforts associated with this study concentrate on refining the concept of the LBR as well as examining the issues of belt dynamics and potential application of the LBR to intermediate and high temperature heat rejection applications. A low temperature point design developed in previous work is updated assuming the use of diffusion pump oil, Santovac-6, as the heat transfer media. Additional analytical and design effort is directed toward determining the impact of interface heat exchanger, fluid bath sealing, and belt drive mechanism designs on system performance and mass. The updated design supports the earlier result by indicating a significant reduction in system specific system mass as compared to heat pipe or pumped fluid radiator concepts currently under consideration (1.3 kg/sq m versus 5 kg/sq m).

Mössbauer studies of iron hydride at high pressure

NASA Astrophysics Data System (ADS)

Choe, I.; Ingalls, R.; Brown, J. M.; Sato-Sorensen, Y.; Mills, R.

1991-07-01

We have measured in situ Mössbauer spectra of iron hydride made in a diamond anvil cell at high pressure and room temperature. The spectra show a sudden change at 3.5+/-0.5 GPa from a single hyperfine pattern to a superposition of three. The former pattern results from normal α-iron with negligible hydrogen content, and the latter from residual α-iron plus newly formed iron hydride. Between 3.5 and 10.4 GPa, the extra hydride pattern have hyperfine fields for one ranging from 276 to 263 kOe, and the other, from 317 to 309 kOe. Both have isomer shifts of about 0.4 mm/sec, and negligible quadrupole splittings. X-ray studies on quenched samples have shown that iron hydride is of double hexagonal close-packed structure, whose two nonequivalent iron sites may account for the observation of two different patterns. Even allowing for the effect of volume expansion, the observed isomer shifts for the hydride are considerably more positive than those of other metallic phases of iron. At the same time, the hyperfine fields are slightly smaller than that of α-iron. As a possible explanation, one may expect a bonding of hydrogen with iron, which would result in a small reduction of 4s electrons, possibly accompanied by a small increase of 3d electrons compared with the neutral atom in metallic iron. The difference between the hyperfine fields in the two spectra are presumably due to the different symmetry at the two iron sites.

Conveyor belt care.

PubMed

1989-07-08

Nurses, doctors, politicians and public have reacted to the prospect of high-volume hospital bed usage - conveyor belt care - by warning of a future-shock scenario of 'pro[Illegible Word] pea' patients whipped through dehumanising hospital treatment and promptly dumped crutchless into the community.

Biological iron-sulfur storage in a thioferrate-protein nanoparticle

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vaccaro, Brian J.; Clarkson, Sonya M.; Holden, James F.

Iron–sulfur clusters are ubiquitous in biology and function in electron transfer and catalysis. We assembled them from iron and cysteine sulfur on protein scaffolds. Iron is typically stored as iron oxyhydroxide, ferrihydrite, encapsulated in 12 nm shells of ferritin, which buffers cellular iron availability. We have characterized IssA, a protein that stores iron and sulfur as thioferrate, an inorganic anionic polymer previously unknown in biology. IssA forms nanoparticles reaching 300 nm in diameter and is the largest natural metalloprotein complex known. It is a member of a widely distributed protein family that includes nitrogenase maturation factors, NifB and NifX. IssAmore » nanoparticles are visible by electron microscopy as electron-dense bodies in the cytoplasm. Purified nanoparticles appear to be generated from 20 nm units containing B 6,400 Fe atoms and B 170 IssA monomers. In support of roles in both iron–sulfur storage and cluster biosynthesis, IssA reconstitutes the [4Fe-4S] cluster in ferredoxin in vitro.« less

Biological iron-sulfur storage in a thioferrate-protein nanoparticle

DOE PAGES

Vaccaro, Brian J.; Clarkson, Sonya M.; Holden, James F.; ...

2017-07-20

Iron–sulfur clusters are ubiquitous in biology and function in electron transfer and catalysis. We assembled them from iron and cysteine sulfur on protein scaffolds. Iron is typically stored as iron oxyhydroxide, ferrihydrite, encapsulated in 12 nm shells of ferritin, which buffers cellular iron availability. We have characterized IssA, a protein that stores iron and sulfur as thioferrate, an inorganic anionic polymer previously unknown in biology. IssA forms nanoparticles reaching 300 nm in diameter and is the largest natural metalloprotein complex known. It is a member of a widely distributed protein family that includes nitrogenase maturation factors, NifB and NifX. IssAmore » nanoparticles are visible by electron microscopy as electron-dense bodies in the cytoplasm. Purified nanoparticles appear to be generated from 20 nm units containing B 6,400 Fe atoms and B 170 IssA monomers. In support of roles in both iron–sulfur storage and cluster biosynthesis, IssA reconstitutes the [4Fe-4S] cluster in ferredoxin in vitro.« less

The binary Kuiper-belt object 1998 WW31.

PubMed

Veillet, Christian; Parker, Joel Wm; Griffin, Ian; Marsden, Brian; Doressoundiram, Alain; Buie, Marc; Tholen, David J; Connelley, Michael; Holman, Matthew J

2002-04-18

The recent discovery of a binary asteroid during a spacecraft fly-by generated keen interest, because the orbital parameters of binaries can provide measures of the masses, and mutual eclipses could allow us to determine individual sizes and bulk densities. Several binary near-Earth, main-belt and Trojan asteroids have subsequently been discovered. The Kuiper belt-the region of space extending from Neptune (at 30 astronomical units) to well over 100 AU and believed to be the source of new short-period comets-has become a fascinating new window onto the formation of our Solar System since the first member object, not counting Pluto, was discovered in 1992 (ref. 13). Here we report that the Kuiper-belt object 1998 WW31 is binary with a highly eccentric orbit (eccentricity e approximately 0.8) and a long period (about 570 days), very different from the Pluto/Charon system, which was hitherto the only previously known binary in the Kuiper belt. Assuming a density in the range of 1 to 2 g cm-3, the albedo of the binary components is between 0.05 and 0.08, close to the value of 0.04 generally assumed for Kuiper-belt objects.

A collisional-radiative model of iron vapour in a thermal arc plasma

NASA Astrophysics Data System (ADS)

Baeva, M.; Uhrlandt, D.; Murphy, A. B.

2017-06-01

A collisional-radiative model for the ground state and fifty effective excited levels of atomic iron, and one level for singly-ionized iron, is set up for technological plasmas. Attention is focused on the population of excited states of atomic iron as a result of excitation, de-excitation, ionization, recombination and spontaneous emission. Effective rate coefficients for ionization and recombination, required in non-equilibrium plasma transport models, are also obtained. The collisional-radiative model is applied to a thermal arc plasma. Input parameters for the collisional-radiative model are provided by a magnetohydrodynamic simulation of a gas-metal welding arc, in which local thermodynamic equilibrium is assumed and the treatment of the transport of metal vapour is based on combined diffusion coefficients. The results clearly identify the conditions in the arc, under which the atomic state distribution satisfies the Boltzmann distribution, with an excitation temperature equal to the plasma temperature. These conditions are met in the central part of the arc, even though a local temperature minimum occurs here. This provides assurance that diagnostic methods based on local thermodynamic equilibrium, in particular those of optical emission spectroscopy, are reliable here. In contrast, deviations from the equilibrium atomic-state distribution are obtained in the near-electrode and arc fringe regions. As a consequence, the temperatures determined from the ratio of line intensities and number densities obtained from the emission coefficient in these regions are questionable. In this situation, the collisional-radiative model can be used as a diagnostic tool to assist in the interpretation of spectroscopic measurements.

Research on an Active Seat Belt System

NASA Astrophysics Data System (ADS)

Kawashima, Takeshi

In a car crash, permanent injury can be avoided if deformation of an occupant's rib cage is maintained within the allowable value. In order to realize this condition, the occupant's seat belt tension must be instantaneously adjusted by a feedback control system. In this study, a seat belt tension control system based on the active shock control system is proposed. The semi-active control law used is derived from the sliding mode control method. One advantage of this proposed system is that it does not require a large power actuator because the seat belt tension is controlled by a brake mechanism. The effectiveness is confirmed by numerical simulation using general parameters of a human thorax and a passenger car in a collision scenario with a wall at a velocity of 100 km/h. The feasibility is then confirmed with a control experiment using a scale model of about 1/10 scale. The relative displacement of the thorax model approaches the allowable value smoothly along the control reference and settles near this value. Thus, the proposed seat belt tension control system design is established.

Is the Cameron River greenstone belt allochthonous?

NASA Technical Reports Server (NTRS)

Kusky, T. M.

1986-01-01

Many tectonic models for the Slave Province, N.W.T., Canada, and for Archean granite - greenstone terranes in general, are implicitly dependent on the assumption that greenstone belt lithologies rest unconformably upon older gneissic basement. Other models require originally large separations between gneissic terranes and greenstone belts. A key question relating to the tectonics of greenstone belts is therefore the original spatial relationship between the volcanic assemblages and presumed-basement gneisses, and how this relationship has been modified by subsequent deformation. What remains unclear in these examples is the significance of the so-called later faulting of the greenstone - gneiss contacts. Where unconformities between gneisses and overlying sediments are indisputable, such as at Point Lake, the significance of faults which occur below the base of the volcanic succession also needs to be evaluated. As part of an on-going investigation aimed at answering these and other questions, the extremely well-exposed Cameron River Greenstone Belt and the Sleepy Dragon Metamorphic Complex in the vicinity of Webb Lake and Sleepy Dragon Lake was mapped.

Bayesian inference of radiation belt loss timescales.

NASA Astrophysics Data System (ADS)

Camporeale, E.; Chandorkar, M.

2017-12-01

Electron fluxes in the Earth's radiation belts are routinely studied using the classical quasi-linear radial diffusion model. Although this simplified linear equation has proven to be an indispensable tool in understanding the dynamics of the radiation belt, it requires specification of quantities such as the diffusion coefficient and electron loss timescales that are never directly measured. Researchers have so far assumed a-priori parameterisations for radiation belt quantities and derived the best fit using satellite data. The state of the art in this domain lacks a coherent formulation of this problem in a probabilistic framework. We present some recent progress that we have made in performing Bayesian inference of radial diffusion parameters. We achieve this by making extensive use of the theory connecting Gaussian Processes and linear partial differential equations, and performing Markov Chain Monte Carlo sampling of radial diffusion parameters. These results are important for understanding the role and the propagation of uncertainties in radiation belt simulations and, eventually, for providing a probabilistic forecast of energetic electron fluxes in a Space Weather context.

Into the Kuiper Belt: New Horizons Post-Pluto

NASA Astrophysics Data System (ADS)

Harrison Parker, Alex; Spencer, John; Benecchi, Susan; Binzel, Richard; Borncamp, David; Buie, Marc; Fuentes, Cesar; Gwyn, Stephen; Kavelaars, JJ; Noll, Keith; Petit, Jean-Marc; Porter, Simon; Showalter, Mark; Stern, S. Alan; Sterner, Ray; Tholen, David; Verbiscer, Anne; Weaver, Hal; Zangari, Amanda

2015-11-01

New Horizons is now beyond Pluto and flying deeper into the Kuiper Belt. In the summer of 2014, a Hubble Space Telescope Large Program identified two candidate Cold Classical Kuiper Belt Objects (KBOs) that were within reach of New Horizons' remaining fuel budget. Here we present the selection of the Kuiper Belt flyby target for New Horizons' post-Pluto mission, our state of knowledge regarding this target and the potential 2019 flyby, the status of New Horizons' targeting maneuver, and prospects for near-future long-range observations of other KBOs.

The small numbers of large Kuiper Belt objects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwamb, Megan E.; Brown, Michael E.; Fraser, Wesley C., E-mail: mschwamb@asiaa.sinica.edu.tw

2014-01-01

We explore the brightness distribution of the largest and brightest (m(R) < 22) Kuiper Belt Objects (KBOs). We construct a luminosity function of the dynamically excited or hot Kuiper Belt (orbits with inclinations >5°) from the very brightest to m(R) = 23. We find for m(R) ≲ 23, a single slope appears to describe the luminosity function. We estimate that ∼12 KBOs brighter than m(R) ∼ 19.5 are present in the Kuiper Belt today. With nine bodies already discovered this suggests that the inventory of bright KBOs is nearly complete.

Greenstone belts: Their boundaries, surrounding rock terrains and interrelationships

NASA Technical Reports Server (NTRS)

Percival, J. A.; Card, K. D.

1986-01-01

Greenstone belts are an important part of the fragmented record of crustal evolution, representing samples of the magmatic activity that formed much of the Earth's crust. Most belts developed rapidly, in less than 100 Ma, leaving large gaps in the geological record. Surrounding terrains provide information on the context of greenstone belts. The effects of tectonic setting, structural geometry and evolution, associated plutonic activity and sedimentation are discussed.

The relationship between the plasmapause and outer belt electrons

DOE PAGES

Goldstein, J.; Baker, D. N.; Blake, J. B.; ...

2016-09-01

Here, we quantify the spatial relationship between the plasmapause and outer belt electrons for a 5 day period, 15–20 January 2013, by comparing locations of relativistic electron flux peaks to the plasmapause. A peak-finding algorithm is applied to 1.8–7.7 MeV relativistic electron flux data. A plasmapause gradient finder is applied to wave-derived electron number densities >10 cm –3. We identify two outer belts. Outer belt 1 is a stable zone of >3 MeV electrons located 1–2 R E inside the plasmapause. Outer belt 2 is a dynamic zone of <3 MeV electrons within 0.5 R E of the moving plasmapause.more » Electron fluxes earthward of each belt's peak are anticorrelated with cold plasma density. Belt 1 decayed on hiss timescales prior to a disturbance on 17 January and suffered only a modest dropout, perhaps owing to shielding by the plasmasphere. Afterward, the partially depleted belt 1 continued to decay at the initial rate. Belt 2 was emptied out by strong disturbance-time losses but restored within 24 h. For global context we use a plasmapause test particle simulation and derive a new plasmaspheric index F p, the fraction of a circular drift orbit inside the plasmapause. We find that the locally measured plasmapause is (for this event) a good proxy for the globally integrated opportunity for losses in cold plasma. Our analysis of the 15–20 January 2013 time interval confirms that high-energy electron storage rings can persist for weeks or even months if prolonged quiet conditions prevail. This case study must be followed up by more general study (not limited to a 5 day period).« less

Compliance with seat belt use in Benin City, Nigeria.

PubMed

Iribhogbe, Pius Ehiawaguan; Osime, Clement Odigie

2008-01-01

Trauma is a major cause of death and disability worldwide. A quarter of all fatalities due to injury occur due to road traffic crashes with 90% of the fatalities occurring in low- and medium-income countries. Poor compliance with the use of seat belts is a problem in many developing countries. The aim of this study was to evaluate the level of seatbelt compliance in motor vehicles in Benin City, Nigeria. A five-day, observational study was conducted in strategic locations in Benin City. The compliance rates of drivers, front seat passengers, and rear seat passengers in the various categories of vehicles were evaluated, and the data were subjected to statistical processing using the Program for Epidemiology. A total of 369 vehicles were observed. This consisted of 172 private cars, 64 taxis, 114 buses, 15 trucks, and four other vehicles. The seat belt compliance rate for drivers was 52.3%, front seat passengers 18.4%, and rear seat passengers 6.1%. Drivers of all categories of vehicles were more likely to use the seat belt compared to front seat passengers (p = 0.000) and rear seat passengers (p = 0.000). Drivers of private cars were more likely to use seat belts compared to taxi drivers (p = 0.000) and bus drivers (p = 0.000). Front seat passengers in private cars were more likely to use the seat belt compared to front seat passengers in taxis (p = 0.000) and buses (p = 0.000). Rear seat passengers in private cars also were more likely to use seat belts compared to rear seat passengers in taxis (p = 0.000) and buses (p = 0.000). Compliance with seat belt use in Benin City is low. Legislation, educational campaigns, and enforcement of seat belt use are needed.

Deconstructing the conveyor belt.

PubMed

Lozier, M Susan

2010-06-18

For the past several decades, oceanographers have embraced the dominant paradigm that the ocean's meridional overturning circulation operates like a conveyor belt, transporting cold waters equatorward at depth and warm waters poleward at the surface. Within this paradigm, the conveyor, driven by changes in deepwater production at high latitudes, moves deep waters and their attendant properties continuously along western boundary currents and returns surface waters unimpeded to deepwater formation sites. A number of studies conducted over the past few years have challenged this paradigm by revealing the vital role of the ocean's eddy and wind fields in establishing the structure and variability of the ocean's overturning. Here, we review those studies and discuss how they have collectively changed our view of the simple conveyor-belt model.

The levantine amber belt

NASA Astrophysics Data System (ADS)

Nissenbaum, A.; Horowitz, A.

1992-02-01

Amber, a fossil resin, is found in Early Cretaceous sanstones and fine clastics in Lebanon, Jordan, and Israel. The term "Levantine amber belt" is coined for this amber-containing sediment belt. The amber occurs as small nodules of various colors and frequently contains inclusions of macro- and microorganisms. The Lebanese amber contains Lepidoptera and the amber from southern Israel is rich in fungal remains. The source of the amber, based on geochemical and palynological evidence, is assumed to be from a conifer belonging to the Araucariaceae. The resins were produced by trees growing in a tropical near shore environment. The amber was transported into small swamps and was preserved there together with lignite. Later reworking of those deposits resulted in redeposition of the amber in oxidized sandstones.

Papers on adult seat belts : effectiveness and use

DOT National Transportation Integrated Search

1988-06-01

The eight papers in this volume describe analyses of the : effectiveness and use of adult seat belts, based on traffic : accident data. All eight were written between January 1984 and : May 1988. The topics addressed include front seat belt : effecti...

Papers on adult seat belts--effectiveness and use

DOT National Transportation Integrated Search

1988-06-01

The eight papers in the volume describe analyses of the effectiveness and use of adult seat belts, based on traffic accident data. All eight were written between January 1984 and May 1988. The topics addressed include front seat belt effectiveness (e...

Understanding Quaternions and the Dirac Belt Trick

ERIC Educational Resources Information Center

Staley, Mark

2010-01-01

The Dirac belt trick is often employed in physics classrooms to show that a 2n rotation is not topologically equivalent to the absence of rotation whereas a 4n rotation is, mirroring a key property of quaternions and their isomorphic cousins, spinors. The belt trick can leave the student wondering if a real understanding of quaternions and spinors…

Crystal structure of delta9 stearoyl-acyl carrier protein desaturase from castor seed and its relationship to other di-iron proteins.

PubMed Central

Lindqvist, Y; Huang, W; Schneider, G; Shanklin, J

1996-01-01

The three-dimensional structure of recombinant homodimeric delta9 stearoyl-acyl carrier protein desaturase, the archetype of the soluble plant fatty acid desaturases that convert saturated to unsaturated fatty acids, has been determined by protein crystallographic methods to a resolution of 2.4 angstroms. The structure was solved by a combination of single isomorphous replacement, anomalous contribution from the iron atoms to the native diffraction data and 6-fold non-crystallographic symmetry averaging. The 363 amino acid monomer consists of a single domain of 11 alpha-helices. Nine of these form an antiparallel helix bundle. The enzyme subunit contains a di-iron centre, with ligands from four of the alpha-helices in the helix bundle. The iron ions are bound in a highly symmetric environment, with one of the irons forming interactions with the side chains of E196 and H232 and the second iron with the side chains of E105 and H146. Two additional glutamic acid side chains, from E143 and E229, are within coordination distance to both iron ions. A water molecule is found within the second coordination sphere from the iron atoms. The lack of electron density corresponding to a mu-oxo bridge, and the long (4.2 angstroms) distance between the iron ions suggests that this probably represents the diferrous form of the enzyme. A deep channel which probably binds the fatty acid extends from the surface into the interior of the enzyme. Modelling of the substrate, stearic acid, into this channel places the delta9 carbon atom in the vicinity of one of the iron ions. Images PMID:8861937

Crystal structure of delta9 stearoyl-acyl carrier protein desaturase from castor seed and its relationship to other di-iron proteins.

PubMed

Lindqvist, Y; Huang, W; Schneider, G; Shanklin, J

1996-08-15

The three-dimensional structure of recombinant homodimeric delta9 stearoyl-acyl carrier protein desaturase, the archetype of the soluble plant fatty acid desaturases that convert saturated to unsaturated fatty acids, has been determined by protein crystallographic methods to a resolution of 2.4 angstroms. The structure was solved by a combination of single isomorphous replacement, anomalous contribution from the iron atoms to the native diffraction data and 6-fold non-crystallographic symmetry averaging. The 363 amino acid monomer consists of a single domain of 11 alpha-helices. Nine of these form an antiparallel helix bundle. The enzyme subunit contains a di-iron centre, with ligands from four of the alpha-helices in the helix bundle. The iron ions are bound in a highly symmetric environment, with one of the irons forming interactions with the side chains of E196 and H232 and the second iron with the side chains of E105 and H146. Two additional glutamic acid side chains, from E143 and E229, are within coordination distance to both iron ions. A water molecule is found within the second coordination sphere from the iron atoms. The lack of electron density corresponding to a mu-oxo bridge, and the long (4.2 angstroms) distance between the iron ions suggests that this probably represents the diferrous form of the enzyme. A deep channel which probably binds the fatty acid extends from the surface into the interior of the enzyme. Modelling of the substrate, stearic acid, into this channel places the delta9 carbon atom in the vicinity of one of the iron ions.

Thin film lubrication of hexadecane confined by iron and iron oxide surfaces: A crucial role of surface structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ta, D. T.; Tieu, A. K.; Zhu, H. T., E-mail: hongtao@uow.edu.au

2015-10-28

A comparative analysis of thin film lubrication of hexadecane between different iron and its oxide surfaces has been carried out using classical molecular dynamic simulation. An ab initio force-field, COMPASS, was applied for n-hexadecane using explicit atom model. An effective potential derived from density functional theory calculation was utilized for the interfacial interaction between hexadecane and the tribo-surfaces. A quantitative surface parameterization was introduced to investigate the influence of surface properties on the structure, rheological properties, and tribological performance of the lubricant. The results show that although the wall-fluid attraction of hexadecane on pure iron surfaces is significantly stronger thanmore » its oxides, there is a considerable reduction of shear stress of confined n-hexadecane film between Fe(100) and Fe(110) surfaces compared with FeO(110), FeO(111), Fe{sub 2}O{sub 3}(001), and Fe{sub 2}O{sub 3}(012). It was found that, in thin film lubrication of hexadecane between smooth iron and iron oxide surfaces, the surface corrugation plays a role more important than the wall-fluid adhesion strength.« less

Electronic and Spatial Structures of Water-Soluble Dinitrosyl Iron Complexes with Thiol-Containing Ligands Underlying Their Ability to Act as Nitric Oxide and Nitrosonium Ion Donors

PubMed Central

Vanin, Anatoly F.; Burbaev, Dosymzhan Sh.

2011-01-01

The ability of mononuclear dinitrosyl iron commplexes (M-DNICs) with thiolate ligands to act as NO donors and to trigger S-nitrosation of thiols can be explain only in the paradigm of the model of the [Fe+(NO+)2] core ({Fe(NO)2}7 according to the Enemark-Feltham classification). Similarly, the {(RS−)2Fe+(NO+)2}+ structure describing the distribution of unpaired electron density in M-DNIC corresponds to the low-spin (S = 1/2) state with a d7 electron configuration of the iron atom and predominant localization of the unpaired electron on MO(dz2) and the square planar structure of M-DNIC. On the other side, the formation of molecular orbitals of M-DNIC including orbitals of the iron atom, thiolate and nitrosyl ligands results in a transfer of electron density from sulfur atoms to the iron atom and nitrosyl ligands. Under these conditions, the positive charge on the nitrosyl ligands diminishes appreciably, the interaction of the ligands with hydroxyl ions or with thiols slows down and the hydrolysis of nitrosyl ligands and the S-nitrosating effect of the latter are not manifested. Most probably, the S-nitrosating effect of nitrosyl ligands is a result of weak binding of thiolate ligands to the iron atom under conditions favoring destabilization of M-DNIC. PMID:22505886

Electronic and spatial structures of water-soluble dinitrosyl iron complexes with thiol-containing ligands underlying their ability to act as nitric oxide and nitrosonium ion donors.

PubMed

Vanin, Anatoly F; Burbaev, Dosymzhan Sh

2011-01-01

The ability of mononuclear dinitrosyl iron commplexes (M-DNICs) with thiolate ligands to act as NO donors and to trigger S-nitrosation of thiols can be explain only in the paradigm of the model of the [Fe(+)(NO(+))(2)] core ({Fe(NO)(2)}(7) according to the Enemark-Feltham classification). Similarly, the {(RS(-))(2)Fe(+)(NO(+))(2)}(+) structure describing the distribution of unpaired electron density in M-DNIC corresponds to the low-spin (S = 1/2) state with a d(7) electron configuration of the iron atom and predominant localization of the unpaired electron on MO(d(z2)) and the square planar structure of M-DNIC. On the other side, the formation of molecular orbitals of M-DNIC including orbitals of the iron atom, thiolate and nitrosyl ligands results in a transfer of electron density from sulfur atoms to the iron atom and nitrosyl ligands. Under these conditions, the positive charge on the nitrosyl ligands diminishes appreciably, the interaction of the ligands with hydroxyl ions or with thiols slows down and the hydrolysis of nitrosyl ligands and the S-nitrosating effect of the latter are not manifested. Most probably, the S-nitrosating effect of nitrosyl ligands is a result of weak binding of thiolate ligands to the iron atom under conditions favoring destabilization of M-DNIC.

Iron and oxygen isotope fractionation during iron UV photo-oxidation: Implications for early Earth and Mars

NASA Astrophysics Data System (ADS)

Nie, Nicole X.; Dauphas, Nicolas; Greenwood, Richard C.

2017-01-01

Banded iron formations (BIFs) contain appreciable amounts of ferric iron (Fe3+). The mechanism by which ferrous iron (Fe2+) was oxidized into Fe3+ in an atmosphere that was globally anoxic is highly debated. Of the three scenarios that have been proposed to explain BIF formation, photo-oxidation by UV photons is the only one that does not involve life (the other two are oxidation by O2 produced by photosynthesis, and anoxygenic photosynthesis whereby Fe2+ is directly used as electron donor in place of water). We experimentally investigated iron and oxygen isotope fractionation imparted by iron photo-oxidation at a pH of 7.3. The iron isotope fractionation between precipitated Fe3+-bearing lepidocrocite and dissolved Fe2+ follows a Rayleigh distillation with an instantaneous 56Fe/54Fe fractionation factor of + 1.2 ‰. Such enrichment in the heavy isotopes of iron is consistent with the values measured in BIFs. We also investigated the nature of the mass-fractionation law that governs iron isotope fractionation in the photo-oxidation experiments (i.e., the slope of the δ56Fe-δ57Fe relationship). The experimental run products follow a mass-dependent law corresponding to the high-T equilibrium limit. The fact that a ∼3.8 Gyr old BIF sample (IF-G) from Isua (Greenland) falls on the same fractionation line confirms that iron photo-oxidation in the surface layers of the oceans was a viable pathway to BIF formation in the Archean, when the atmosphere was largely transparent to UV photons. Our experiments allow us to estimate the quantum yield of the photo-oxidation process (∼0.07 iron atom oxidized per photon absorbed). This yield is used to model iron oxidation on early Mars. As the photo-oxidation proceeds, the aqueous medium becomes more acidic, which slows down the reaction by changing the speciation of iron to species that are less efficient at absorbing UV-photons. Iron photo-oxidation in centimeter to meter-deep water ponds would take months to years to

Driver hand-held mobile phone use and safety belt use.

PubMed

Eby, David W; Vivoda, Jonathon M

2003-11-01

The purposes of the study were to identify hand-held mobile phone use trends for Michigan and to compare safety belt use between users and nonusers. Mobile phone and safety belt use was investigated by a direct observation survey of drivers at intersections in Michigan. Data were weighted to calculate mobile phone use and safety belt use rates statewide. The study showed 2.7% of Michigan drivers were using a mobile phone at any given daylight time. Safety belt use of current mobile phone users was significantly lower than those not using mobile phones.

Microbial involvement in the formation of Cambrian sea-floor silica-iron oxide deposits, Australia

NASA Astrophysics Data System (ADS)

Duhig, Nathan C.; Davidson, Garry J.; Stolz, Joe

1992-06-01

The Cambrian-Ordovician Mount Windsor volcanic belt in northern Australia is host to stratiform lenses of massive ferruginous chert that are spatially associated with volcanogenic massive sulfide occurrences, in particular the Thalanga zinc-lead-copper-silver deposit. The rocks are composed principally of Fe2O3 and SiO2, with very low concentrations of alkalic elements, and lithogenous elements such as Al, Zr, and Ti; they are interpreted as nearly pure chemical sediments. Textural evidence is documented of the integral role of filamentous bacteria (and/or fungi) in depositing iron from hydrothermal fluids, and of the inorganic precipitation of silica-iron-oxyhydroxide gels that subsequently matured to subcrystalline and crystalline silica forms. At least three distinct iron-accumulating microbial forms are distinguished: networks of septate filaments, nonseptate filament networks, and extremely coarse branching filaments that do not reconnect. Values for δ34S in disseminated pyrite are up to 50‰ lighter than those of contemporaneous Cambrian seawater, suggesting postdepositional colonization of some ironstones by sulfur-reducing bacteria. The site not only preserves the textural interplay of biological and inorganic depositional processes in exhalites, but also extends the oldest known instance of microbial mediation in vent-proximal hydrothermal iron precipitation to at least 500 Ma.

14 CFR 121.311 - Seats, safety belts, and shoulder harnesses.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Seats, safety belts, and shoulder harnesses... § 121.311 Seats, safety belts, and shoulder harnesses. (a) No person may operate an airplane unless... belt and shoulder harness that meets the applicable requirements specified in § 25.785 of this chapter...

14 CFR 121.311 - Seats, safety belts, and shoulder harnesses.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 14 Aeronautics and Space 3 2012-01-01 2012-01-01 false Seats, safety belts, and shoulder harnesses... § 121.311 Seats, safety belts, and shoulder harnesses. (a) No person may operate an airplane unless... belt and shoulder harness that meets the applicable requirements specified in § 25.785 of this chapter...

14 CFR 121.311 - Seats, safety belts, and shoulder harnesses.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 14 Aeronautics and Space 3 2013-01-01 2013-01-01 false Seats, safety belts, and shoulder harnesses... § 121.311 Seats, safety belts, and shoulder harnesses. (a) No person may operate an airplane unless... belt and shoulder harness that meets the applicable requirements specified in § 25.785 of this chapter...

14 CFR 121.311 - Seats, safety belts, and shoulder harnesses.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 14 Aeronautics and Space 3 2014-01-01 2014-01-01 false Seats, safety belts, and shoulder harnesses... § 121.311 Seats, safety belts, and shoulder harnesses. (a) No person may operate an airplane unless... belt and shoulder harness that meets the applicable requirements specified in § 25.785 of this chapter...

14 CFR 121.311 - Seats, safety belts, and shoulder harnesses.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 14 Aeronautics and Space 3 2011-01-01 2011-01-01 false Seats, safety belts, and shoulder harnesses... § 121.311 Seats, safety belts, and shoulder harnesses. (a) No person may operate an airplane unless... belt and shoulder harness that meets the applicable requirements specified in § 25.785 of this chapter...

Characteristics and conditions of teenage safety belt use

DOT National Transportation Integrated Search

1997-07-01

Safety belt use was observed for 7,384 vehicle occupants estimated as 15-19 years old in four states - Texas, Virginia, Idaho, and Mississippi. Age and other pertinent information was obtained from 2,330 teen occupants. Belt use ranged from 19.5% in ...

Interaction of fluorescent sensor with superparamagnetic iron oxide nanoparticles.

PubMed

Karunakaran, Chockalingam; Jayabharathi, Jayaraman; Sathishkumar, Ramalingam; Jayamoorthy, Karunamoorthy

2013-06-01

To sense superparamagnetic iron oxides (Fe2O3 and Fe3O4) nanocrystals a sensitive bioactive phenanthroimidazole based fluorescent molecule, 2-(4-fluorophenyl)-1-phenyl-1H-phenanthro [9,10-d] imidazole has been designed and synthesized. Electronic spectral studies show that phenanthroimidazole is bound to the surface of iron oxide semiconductors. Fluorescent enhancement has been explained on the basis of photo-induced electron transfer (PET) mechanism and apparent binding constants have been deduced. Binding of phenanthroimidazole with iron oxide nanoparticles lowers the HOMO and LUMO energy levels of phenanthroimidazole molecule. Chemical affinity between the nitrogen atom of the phenanthroimidazole and Fe(2+) and Fe(3+) ions on the surface of the nano-oxide may result in strong binding of the phenanthroimidazole derivative with the nanoparticles. The electron injection from the photoexcited phenanthroimidazole to the iron oxides conduction band explains the enhanced fluorescence. Copyright © 2013 Elsevier B.V. All rights reserved.

Enhancement of iron content in spinach plants stimulated by magnetic nano particles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yulianto, Agus; Astuti, Budi; Amalia, Saptaria Rosa

In our previous study, the iron content in spinach plants could be detected by magnetic susceptibility values. In the present work, magnetic nano particles were found from the iron sand. The magnetic nano particles are synthesis by using co-precipitation process and sol-gel technique. The stimulation of magnetic nano particles in the plant has been done by the provision of magnetic nano particles in growing media. After certain time, plant samples was characterized using susceptibility-meter MS2B and atomic absorption spectroscopy to measure the magnetic susceptibility and the amount of iron content that absorbed of the plant, respectively. The iron content inmore » the spinach plants was increased when the magnetic nano particles was injected in the growing media.« less

Participative education for children: an effective approach to increase safety belt use.

PubMed Central

Lehman, G R; Geller, E S

1990-01-01

Vehicle license plate numbers and the shoulder belt use of front-seat occupants were recorded unobtrusively when parents delivered and picked up their children at a Montessori school during 5-day baseline, intervention, and follow-up phases. Practicing and presenting a 15-min safety belt skit increased the safety belt use of those 6 kindergarten children who were not consistent belt users 82% above their preintervention baseline belt use mean of 47%. The belt use of these children's parents (who watched the skit) increased to 56% above their baseline mean of 36%. Also, mean safety belt use of 11 primary school children who watched the skit increased to 70% above their baseline of 28%. Mean safety belt use of the older children's parents (who didn't watch the skit) remained at approximately 31% for each phase, regardless of whether children were vehicle occupants. The follow-up observations, taken 3 months after the intervention, revealed 60% belt use for the kindergartners, 48% for the primary school children, and 71% for the kindergartners' parents when the children were vehicle occupants but only 30% when the parents were driving alone. PMID:2373658

Effect of Initial Iron Content in a Zinc Bath on the Dissolution Rate of Iron During a Hot Dip Galvanizing Process

NASA Astrophysics Data System (ADS)

Lee, Sang Myung; Lee, Suk Kyu; Paik, Doo-Jin; Park, Joo Hyun

2017-04-01

The mechanism of iron dissolution and the effect of initial Fe content in a Zn bath on the dissolution rate of iron were investigated using a finger rotating method (FRM). When the initial iron content, [Fe]°, in the zinc bath was less than the solubility limit, the iron content in the zinc bath showed a rapid increase, whereas a moderate increase was observed when [Fe]° was close to the solubility limit. Based on Eisenberg's kinetic model, the mass transfer coefficient of iron in the present experimental condition was calculated to be k M = 1.2 × 10-5 m/s, which was similar to the results derived by Giorgi et al. under industrial practice conditions. A dissolution of iron occurred even when the initial iron content in the zinc bath was greater than the solubility limit, which was explained by the interfacial thermodynamics in conjunction with the morphology of the surface coating layer. By analyzing the diffraction patterns using TEM, the outermost dendritic-structured coating layer was confirmed as FeZn13 ( ζ). In order to satisfy the local equilibrium based on the Gibbs-Thomson equation, iron in the dendrite-structured phase spontaneously dissolved into the zinc bath, resulting in the enrichment of iron in front of the dendrite tip. Through the diffusion boundary layer in front of the dendritic-structured layer, dissolved Fe atoms diffused out and reacted with Zn and small amounts of Al, resulting in the formation of dross particles such as FeZn10Al x ( δ). It was experimentally confirmed that the smaller the difference between the initial iron content in the zinc bath and the iron solubility limit at a given temperature, the lower the number of formed dross particles.

Inductively coupled plasma atomic fluorescence spectrometric determination of cadmium, copper, iron, lead, manganese and zinc

USGS Publications Warehouse

Sanzolone, R.F.

1986-01-01

An inductively coupled plasma atomic fluorescence spectrometric method is described for the determination of six elements in a variety of geological materials. Sixteen reference materials are analysed by this technique to demonstrate its use in geochemical exploration. Samples are decomposed with nitric, hydrofluoric and hydrochloric acids, and the residue dissolved in hydrochloric acid and diluted to volume. The elements are determined in two groups based on compatibility of instrument operating conditions and consideration of crustal abundance levels. Cadmium, Cu, Pb and Zn are determined as a group in the 50-ml sample solution under one set of instrument conditions with the use of scatter correction. Limitations of the scatter correction technique used with the fluorescence instrument are discussed. Iron and Mn are determined together using another set of instrumental conditions on a 1-50 dilution of the sample solution without the use of scatter correction. The ranges of concentration (??g g-1) of these elements in the sample that can be determined are: Cd, 0.3-500; Cu, 0.4-500; Fe, 85-250 000; Mn, 45-100 000; Pb, 5-10 000; and Zn, 0.4-300. The precision of the method is usually less than 5% relative standard deviation (RSD) over a wide concentration range and acceptable accuracy is shown by the agreement between values obtained and those recommended for the reference materials.

Iron-Virus Interactions in the Oceans

NASA Astrophysics Data System (ADS)

Bonnain, C. C.; Buck, K. N.; Breitbart, M.

2016-02-01

Iron is an essential nutrient in the oceans, with the sub-nanomolar concentrations found in open ocean surface waters often insufficient for supporting biological activity. More than 99.9% of dissolved iron is bound to organic ligands, yet identifying the sources of these ligands in seawater remains a major challenge. A significant portion of iron-binding ligands fall into the colloidal fraction, which is operationally defined as the fraction collected between a 0.02 µm and a 0.45 µm filter. Among the organic ligands in this fraction persists an extremely abundant biological candidate: viruses. On average there are 107 viruses per milliliter of seawater, most of which are phages (viruses that infect bacteria). The impact of viruses on ocean biogeochemistry is often evoked purely through the act of lysing hosts and very few studies have considered the geochemical potential of the viral particles themselves. Recent work in non-marine model systems has revealed the presence of iron atoms within the structure of diverse phages infecting Escherichia coli. Combined with the small size and sheer abundance of phages in the oceans, the inclusion of iron in phage structures would translate into a major factor for cycling of this important trace metal. In addition, iron is so critical for growth that bacteria have evolved multiple uptake systems for assimilating iron, such as siderophores. Certain outer membrane proteins serve a dual function in siderophore uptake and as a phage receptor, suggesting that some of the strategies utilized for iron acquisition make bacteria vulnerable to phage infection. Given the constant arms race between bacteria and phages to develop resistance and counter-resistance, respectively, it is not surprising that phage would have evolved to utilize critical regions of surface-exposed proteins which are indispensable for bacterial growth as receptors. The research presented here explores the potential of marine phages to serve as iron

Benchmark test of neutron transport calculations: indium, nickel, gold, europium, and cobalt activation with and without energy moderated fission neutrons by iron simulating the Hiroshima atomic bomb casing.

PubMed

Iwatani, K; Hoshi, M; Shizuma, K; Hiraoka, M; Hayakawa, N; Oka, T; Hasai, H

1994-10-01

A benchmark test of the Monte Carlo neutron and photon transport code system (MCNP) was performed using a bare- and energy-moderated 252Cf fission neutron source which was obtained by transmission through 10-cm-thick iron. An iron plate was used to simulate the effect of the Hiroshima atomic bomb casing. This test includes the activation of indium and nickel for fast neutrons and gold, europium, and cobalt for thermal and epithermal neutrons, which were inserted in the moderators. The latter two activations are also to validate 152Eu and 60Co activity data obtained from the atomic bomb-exposed specimens collected at Hiroshima and Nagasaki, Japan. The neutron moderators used were Lucite and Nylon 6 and the total thickness of each moderator was 60 cm or 65 cm. Measured activity data (reaction yield) of the neutron-irradiated detectors in these moderators decreased to about 1/1,000th or 1/10,000th, which corresponds to about 1,500 m ground distance from the hypocenter in Hiroshima. For all of the indium, nickel, and gold activity data, the measured and calculated values agreed within 25%, and the corresponding values for europium and cobalt were within 40%. From this study, the MCNP code was found to be accurate enough for the bare- and energy-moderated 252Cf neutron activation calculations of these elements using moderators containing hydrogen, carbon, nitrogen, and oxygen.

Radiation belt seed population and its association with the relativistic electron dynamics: A statistical study: Radiation Belt Seed Population

DOE PAGES

Tang, C. L.; Wang, Y. X.; Ni, B.; ...

2017-05-19

Using the Van Allen Probes data, we study the radiation belt seed population and it associated with the relativistic electron dynamics during 74 geomagnetic storm events. Based on the flux changes of 1 MeV electrons before and after the storm peak, these storm events are divided into two groups of “non-preconditioned” and “preconditioned”. The statistical study shows that the storm intensity is of significant importance for the distribution of the seed population (336 keV electrons) in the outer radiation belt. However, substorm intensity can also be important to the evolution of the seed population for some geomagnetic storm events. Formore » non-preconditioned storm events, the correlation between the peak fluxes and their L-shell locations of the seed population and relativistic electrons (592 keV, 1.0 MeV, 1.8 MeV, and 2.1 MeV) is consistent with the energy-dependent dynamic processes in the outer radiation belt. For preconditioned storm events, the correlation between the features of the seed population and relativistic electrons is not fully consistent with the energy-dependent processes. It is suggested that the good correlation between the radiation belt seed population and ≤1.0 MeV electrons contributes to the prediction of the evolution of ≤1.0 MeV electrons in the Earth’s outer radiation belt during periods of geomagnetic storms.« less

Radiation belt seed population and its association with the relativistic electron dynamics: A statistical study: Radiation Belt Seed Population

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tang, C. L.; Wang, Y. X.; Ni, B.

Using the Van Allen Probes data, we study the radiation belt seed population and it associated with the relativistic electron dynamics during 74 geomagnetic storm events. Based on the flux changes of 1 MeV electrons before and after the storm peak, these storm events are divided into two groups of “non-preconditioned” and “preconditioned”. The statistical study shows that the storm intensity is of significant importance for the distribution of the seed population (336 keV electrons) in the outer radiation belt. However, substorm intensity can also be important to the evolution of the seed population for some geomagnetic storm events. Formore » non-preconditioned storm events, the correlation between the peak fluxes and their L-shell locations of the seed population and relativistic electrons (592 keV, 1.0 MeV, 1.8 MeV, and 2.1 MeV) is consistent with the energy-dependent dynamic processes in the outer radiation belt. For preconditioned storm events, the correlation between the features of the seed population and relativistic electrons is not fully consistent with the energy-dependent processes. It is suggested that the good correlation between the radiation belt seed population and ≤1.0 MeV electrons contributes to the prediction of the evolution of ≤1.0 MeV electrons in the Earth’s outer radiation belt during periods of geomagnetic storms.« less

Discussion on the application of high additional value of high purity and high quality direct reduced iron

NASA Astrophysics Data System (ADS)

Yue, Chongfeng; Bai, Lu; Hong, Yicheng; Xu, Lijun

2018-03-01

The high purity and high quality direct reduced iron(DRI) products which were produced by high grade and high quality iron powder, with a high grade and low impurity characteristics. This article introduced the application of high purity and high quality DRI in the fields of amorphous base material, atomized iron powder, powder superalloy, high purity and ultra-low carbon special metallurgy products, precision casting, super alloy and various iron-based alloys. It provides a reference for the high added value utilization of DRI.

Dillon cutoff-Basement-involved tectonic link between the disturbed belt of west-central Montana and the overthrust belt of extreme southwestern Montana

NASA Astrophysics Data System (ADS)

O'Neill, J. Michael; Schmidt, Christopher J.; Genovese, Paul W.

1990-11-01

The front of the Cordilleran fold and thrust belt in western Montana follows the disturbed belt in the north, merges with the southwest Montana transverse zone in the west-central part of the region, and in southwestern Montana is marked by a broad zone characterized by complex interaction between thrust belt structures and basement uplifts. The front margin of the thrust belt in Montana reflects mainly thin-skinned tectonic features in the north, an east-trending lateral ramp that curves southwest in the central part into the Dillon cutoff, an oblique-slip, thick-skinned displacement transfer zone that cuts through basement rocks of the Lima recess, and a zone of overlap between thin- and thick-skinned thrusts in extreme southwestern Montana. The transverse ramp and basement-involved thrust faults are controlled by Proterozoic structures.

Origin of the Uinta recess, Sevier fold thrust belt, Utah: influence of basin architecture on fold thrust belt geometry

NASA Astrophysics Data System (ADS)

Paulsen, Timothy; Marshak, Stephen

1999-11-01

Structural trends in the Sevier fold-thrust belt define a pronounced concave-to-the-foreland map-view curve, the Uinta recess, in north-central Utah. This recess separates two convex-to-the-foreland curves, the Provo salient on the south and the Wyoming salient on the north. The two limbs of the recess comprise transverse zones (fault zones at a high-angle to the regional trend of the orogen) that border the flanks of the east-west-trending Uinta/Cottonwood arch. Our structural analysis indicates that the transverse zones formed during the Sevier orogeny, and that they differ markedly from each other in structural style. The Charleston transverse zone (CTZ), on the south side of the arch, initiated as a complex sinistral strike-slip fault system that defines the abrupt northern boundary of the Provo salient. The Mount Raymond transverse zone (MRTZ), on the north side of the arch, represents the region in which the southeast-verging southern limb of the gently curving Wyoming salient was tilted northwards during the Laramide phase of uplift of the Uinta/Cottonwood arch. In effect, the MRTZ represents an oblique cross section through a thrust belt. The contrasting architecture of these transverse zones demonstrates how pre-deformation basin geometry influences the geometry of a fold-thrust belt. Analysis of isopach maps indicates that, at the time the Sevier fold-thrust belt formed, the area just north of the present site of the Uinta/Cottonwood arch was a basement high, with a gently dipping north flank, and a steeply dipping south flank. Thus, predeformational sediment thickened abruptly to the south of the high and thickened gradually to the north of the high. As illustrated by sandbox models, the distance that a fold-thrust belt propagates into the foreland depends on the thickness of the sedimentary layer being deformed, so the shape of the salient mimics the longitudinal cross-sectional shape of the sedimentary basin. Where basins taper gradually along strike

Reinventing atomic magnetic simulations with spin-orbit coupling

DOE PAGES

Perera, Meewanage Dilina N.; Eisenbach, Markus; Nicholson, Don M.; ...

2016-02-10

We propose a powerful extension to the combined molecular and spin dynamics method that fully captures the coupling between the atomic and spin subsystems via spin-orbit interactions. Moreover, the foundation of this method lies in the inclusion of the local magnetic anisotropies that arise as a consequence of the lattice symmetry breaking due to phonons or crystallographic defects. By using canonical simulations of bcc iron with the system coupled to a phonon heat bath, we show that our extension enables the previously unachievable angular momentum exchange between the atomic and spin degrees of freedom.

Vega: Two Belts and the Possibility of Planets

NASA Image and Video Library

2013-01-08

In this diagram, the Vega system, which was already known to have a cooler outer belt of comets orange, is compared to our solar system with its asteroid and Kuiper belts. The ring of warm, rocky debris was detected using NASA Spitzer Space Telescope,

Prioritizing Safety with Seat Belts: The Unanswered Question.

ERIC Educational Resources Information Center

Farrell, Elaine

1987-01-01

Reviews conflicting federal and state developments (including liability lawsuits) involving seat belt installation on school buses. The National Highway Traffic Safety Administration and the National Transportation Safety Board differ on this issue, and several states are considering seat belt legislation or crashworthiness studies. Hints are…

Increasing safety belt use by high risk drivers

DOT National Transportation Integrated Search

1991-04-01

The objectives of this study were to: 1) identify groups of non-belt users who are most likely to become involved in highway crashes and 2) develop and test communication programs designed to increase safety belt use by one or more of these groups. T...

Angle stations in or for endless conveyor belts

DOEpatents

Steel, Alan

1987-04-07

In an angle station for an endless conveyor belt, there are presented to each incoming run of the belt stationary curved guide members (18, 19) of the shape of a major segment of a right-circular cylinder and having in the part-cylindrical portion (16 or 17) thereof rectangular openings (15) arranged in parallel and helical paths and through which project small freely-rotatable rollers (14), the continuously-changing segments of the curved surfaces of which projecting through said openings (15) are in attitude to change the direction of travel of the belt (13) through 90.degree. during passage of the belt about the part-cylindrical portion (16 or 17) of the guide member (18 or 19). The rectangular openings (15) are arranged with their longer edges lengthwise of the diagonals representing the mean of the helix but with those of a plurality of the rows nearest to each end of the part-cylindrical portion (16 or 17) slightly out of axial symmetry with said diagonals, being slightly inclined in a direction about the intersections (40) of the diagonals of the main portion of the openings, to provide a "toe-in" attitude in relation to the line of run of the endless conveyor belt.

Dynamics of the Earth's Radiation Belts and Inner Magnetosphere

NASA Astrophysics Data System (ADS)

Schultz, Colin

2013-12-01

Trapped by Earth's magnetic field far above the planet's surface, the energetic particles that fill the radiation belts are a sign of the Sun's influence and a threat to our technological future. In the AGU monograph Dynamics of the Earth's Radiation Belts and Inner Magnetosphere, editors Danny Summers, Ian R. Mann, Daniel N. Baker, and Michael Schulz explore the inner workings of the magnetosphere. The book reviews current knowledge of the magnetosphere and recent research results and sets the stage for the work currently being done by NASA's Van Allen Probes (formerly known as the Radiation Belt Storm Probes). In this interview, Eos talks to Summers about magnetospheric research, whistler mode waves, solar storms, and the effects of the radiation belts on Earth.

The fossilized size distribution of the main asteroid belt

NASA Astrophysics Data System (ADS)

Bottke, William F.; Durda, Daniel D.; Nesvorný, David; Jedicke, Robert; Morbidelli, Alessandro; Vokrouhlický, David; Levison, Hal

2005-05-01

Planet formation models suggest the primordial main belt experienced a short but intense period of collisional evolution shortly after the formation of planetary embryos. This period is believed to have lasted until Jupiter reached its full size, when dynamical processes (e.g., sweeping resonances, excitation via planetary embryos) ejected most planetesimals from the main belt zone. The few planetesimals left behind continued to undergo comminution at a reduced rate until the present day. We investigated how this scenario affects the main belt size distribution over Solar System history using a collisional evolution model (CoEM) that accounts for these events. CoEM does not explicitly include results from dynamical models, but instead treats the unknown size of the primordial main belt and the nature/timing of its dynamical depletion using innovative but approximate methods. Model constraints were provided by the observed size frequency distribution of the asteroid belt, the observed population of asteroid families, the cratered surface of differentiated Asteroid (4) Vesta, and the relatively constant crater production rate of the Earth and Moon over the last 3 Gyr. Using CoEM, we solved for both the shape of the initial main belt size distribution after accretion and the asteroid disruption scaling law QD∗. In contrast to previous efforts, we find our derived QD∗ function is very similar to results produced by numerical hydrocode simulations of asteroid impacts. Our best fit results suggest the asteroid belt experienced as much comminution over its early history as it has since it reached its low-mass state approximately 3.9-4.5 Ga. These results suggest the main belt's wavy-shaped size-frequency distribution is a "fossil" from this violent early epoch. We find that most diameter D≳120 km asteroids are primordial, with their physical properties likely determined during the accretion epoch. Conversely, most smaller asteroids are byproducts of fragmentation

Seat-belt message and the law?

PubMed

Sengupta, S K; Patil, N G; Law, G

1989-09-01

This paper attempts to draw together available information on the use of seat belts, one of the most important safety devices for a person in a car. Considering the high rate of mortality and morbidity due to road traffic accidents in Papua New Guinea the authors strongly feel that seat-belt usage should be made compulsory. When one looks at the history of the implementation of such a successful countermeasure in other countries it seems that legislation is the only answer.

An x-ray absorption study of the iron site in bacterial photosynthetic reaction centers.

PubMed Central

Bunker, G; Stern, E A; Blankenship, R E; Parson, W W

1982-01-01

Measurements were made of the extended x-ray absorption fine structure (EXAFS) of the iron site in photosynthetic reaction centers from the bacterium Rhodopseudomonas sphaeroides. Forms with two quinones, two quinones with added o-phenanthroline, and one quinone were studied. Only the two forms containing two quinones maintained their integrity and were analyzed. The spectra show directly that the added o-phenanthroline does not chelate the iron atom. Further analysis indicates that the iron is octahedrally coordinated by nitrogen and/or oxygen atoms located at various distances, with the average value of about 2.14 A. The analysis suggests that most of the ligands are nitrogens and that three of the nitrogen ligands belong to histidine rings. This interpretation accounts for several unusual features of the EXAFS spectrum. We speculate that the quinones are bound to the histidine rings in some manner. Qualitative features of the absorption edge spectra also are discussed and are related to the Fe-ligand distance. PMID:6977382

Magnetic refrigeration apparatus with belt of ferro or paramagnetic material

DOEpatents

Barclay, John A.; Stewart, Walter F.; Henke, Michael D.; Kalash, Kenneth E.

1987-01-01

A magnetic refrigerator operating in the 12 to 77K range utilizes a belt which carries ferromagnetic or paramagnetic material and which is disposed in a loop which passes through the center of a solenoidal magnet to achieve cooling. The magnetic material carried by the belt, which can be blocks in frames of a linked belt, can be a mixture of substances with different Curie temperatures arranged such that the Curie temperatures progressively increase from one edge of the belt to the other. This magnetic refrigerator can be used to cool and liquefy hydrogen or other fluids.

Magnetic refrigeration apparatus with belt of ferro or paramagnetic material

DOEpatents

Barclay, J.A.; Stewart, W.F.; Henke, M.D.; Kalash, K.E.

1986-04-03

A magnetic refrigerator operating in the 12 to 77 K range utilizes a belt which carries ferromagnetic or paramagnetic material and which is disposed in a loop which passes through the center of a solenoidal magnet to achieve cooling. The magnetic material carried by the belt, which can be blocks in frames of a linked belt, can be a mixture of substances with different Curie temperatures arranged such that the Curie temperatures progressively increase from one edge of the belt to the other. This magnetic refrigerator can be used to cool and liquefy hydrogen or other fluids.

Laboratory experiments on the impact disruption of iron meteorites at temperature of near-Earth space

NASA Astrophysics Data System (ADS)

Katsura, Takekuni; Nakamura, Akiko M.; Takabe, Ayana; Okamoto, Takaya; Sangen, Kazuyoshi; Hasegawa, Sunao; Liu, Xun; Mashimo, Tsutomu

2014-10-01

Iron meteorites and some M-class asteroids are generally understood to be fragments that were originally part of cores of differentiated planetesimals or part of local melt pools on primitive bodies. The parent bodies of iron meteorites may have formed in the terrestrial planet region, from which they were then scattered into the main belt (Bottke, W.F., Nesvorný, D., Grimm, R.E., Morbidelli, A., O'Brien, D.P. [2006]. Nature 439, 821-824). Therefore, a wide range of collisional events at different mass scales, temperatures, and impact velocities would have occurred between the time when the iron was segregated and the impact that eventually exposed the iron meteorites to interplanetary space. In this study, we performed impact disruption experiments of iron meteorite specimens as projectiles or targets at room temperature to increase understanding of the disruption process of iron bodies in near-Earth space. Our iron specimens (as projectiles or targets) were almost all smaller in size than their counterparts (as targets or projectiles, respectively). Experiments of impacts of steel specimens were also conducted for comparison. The fragment mass distribution of the iron material was different from that of rocks. In the iron fragmentation, a higher percentage of the mass was concentrated in larger fragments, probably due to the ductile nature of the material at room temperature. The largest fragment mass fraction f was dependent not only on the energy density but also on the size d of the specimen. We assumed a power-law dependence of the largest fragment mass fraction to initial peak pressure P0 normalized by a dynamic strength, Y, which was defined to be dependent on the size of the iron material. A least squares fit to the data of iron meteorite specimens resulted in the following relationship: f∝∝d, indicating a large size dependence of f. Additionally, the deformation of the iron materials in high-velocity shots was found to be most significant when the

Tunability of room-temperature ferromagnetism in spintronic semiconductors through nonmagnetic atoms

NASA Astrophysics Data System (ADS)

Leedahl, Brett; Abooalizadeh, Zahra; LeBlanc, Kyle; Moewes, Alexander

2017-07-01

The implementation and control of room-temperature ferromagnetism (RTFM) by adding magnetic atoms to a semiconductor's lattice has been one of the most important problems in solid-state physics in the last decade. Herein we report on the mechanism that allows RTFM to be tuned by the inclusion of nonmagnetic aluminum in nickel ferrite. This material, NiFe2 -xAlxO4 (x =0 ,0.5 ,1.5 ), has already shown much promise for magnetic semiconductor technologies, and we are able to add to its versatility technological viability with our results. The site occupancies and valencies of Fe atoms (Fe3 +Td , Fe2 +Oh , and Fe3 +Oh ) can be methodically controlled by including aluminum. Using the fact that aluminum strongly prefers a 3+ octahedral environment, we can selectively fill iron sites with aluminum atoms, and hence specifically tune the magnetic contributions for each of the iron sites, and therefore the bulk material as well. Interestingly, the influence of the aluminum is weak on the electronic structure, allowing one to retain the desirable electronic properties while achieving desirable magnetic properties.

45. July 1974. BLACKSMITH SHOP, VIEW LOOKING NORTHEAST, SHOWING BELT ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

45. July 1974. BLACKSMITH SHOP, VIEW LOOKING NORTHEAST, SHOWING BELT CHASE FOR TWO BELTS FROM THE BASEMENT, THE W. E. & J. BARNES CO. DRILL PRESS, AND THE DRILL PRESS USED FOR REAMING. THE BELT PASSING THROUGH THE WALL POWERS THE SANDER IN THE WOOD SHOP. - Gruber Wagon Works, Pennsylvania Route 183 & State Hill Road at Red Bridge Park, Bernville, Berks County, PA

New Quality Standards of Testing Idlers for Highly Effective Belt Conveyors

NASA Astrophysics Data System (ADS)

Król, Robert; Gladysiewicz, Lech; Kaszuba, Damian; Kisielewski, Waldemar

2017-12-01

The paper presents result of research and analyses carried out into the belt conveyors idlers’ rotational resistance which is one of the key factor indicating the quality of idlers. Moreover, idlers’ rotational resistance is important factor in total resistance to motion of belt conveyor. The evaluation of the technical condition of belt conveyor idlers is carried out in accordance with actual national and international standards which determine the methodology of measurements and acceptable values of measured idlers’ parameters. Requirements defined by the standards, which determine the suitability of idlers to a specific application, despite the development of knowledge on idlers and quality of presently manufactured idlers maintain the same level of parameters values over long periods of time. Nowadays the need to implement new, efficient and economically justified solution for belt conveyor transportation systems characterized by long routes and energy-efficiency is often discussed as one of goals in belt conveyors’ future. One of the basic conditions for achieving this goal is to use only carefully selected idlers with low rotational resistance under the full range of operational loads and high durability. Due to this it is necessary to develop new guidelines for evaluation of the technical condition of belt conveyor idlers in accordance with actual standards and perfecting of existing and development of new methods of idlers testing. The changes in particular should concern updating of values of parameters used for evaluation of the technical condition of belt conveyor idlers in relation to belt conveyors’ operational challenges and growing demands in terms of belt conveyors’ energy efficiency.

Site occupancy of interstitial deuterium atoms in face-centred cubic iron

PubMed Central

Machida, Akihiko; Saitoh, Hiroyuki; Sugimoto, Hidehiko; Hattori, Takanori; Sano-Furukawa, Asami; Endo, Naruki; Katayama, Yoshinori; Iizuka, Riko; Sato, Toyoto; Matsuo, Motoaki; Orimo, Shin-ichi; Aoki, Katsutoshi

2014-01-01

Hydrogen composition and occupation state provide basic information for understanding various properties of the metal–hydrogen system, ranging from microscopic properties such as hydrogen diffusion to macroscopic properties such as phase stability. Here the deuterization process of face-centred cubic Fe to form solid-solution face-centred cubic FeDx is investigated using in situ neutron diffraction at high temperature and pressure. In a completely deuterized specimen at 988 K and 6.3 GPa, deuterium atoms occupy octahedral and tetrahedral interstitial sites with an occupancy of 0.532(9) and 0.056(5), respectively, giving a deuterium composition x of 0.64(1). During deuterization, the metal lattice expands approximately linearly with deuterium composition at a rate of 2.21 Å3 per deuterium atom. The minor occupation of the tetrahedral site is thermally driven by the intersite movement of deuterium atoms along the ‹111› direction in the face-centred cubic metal lattice. PMID:25256789

The Harang discontinuity in auroral belt ionospheric currents.

NASA Technical Reports Server (NTRS)

Heppner, J. P.

1972-01-01

Discussion of the nature of a discontinuity in the ionospheric current of the auroral belt whose existence was suggested by Harang in 1946. Convection characteristics, time variability, and current continuity in the auroral belt are considered in a context of observations and arguments supporting the reality of Harang's discontinuity.

Distribution of Dust from Kuiper Belt Objects

NASA Technical Reports Server (NTRS)

Gorkavyi, Nick N.; Ozernoy, Leonid; Taidakova, Tanya; Mather, John C.; Fisher, Richard (Technical Monitor)

2000-01-01

Using an efficient computational approach, we have reconstructed the structure of the dust cloud in the Solar system between 0.5 and 100 AU produced by the Kuiper belt objects. Our simulations offer a 3-D physical model of the 'kuiperoidal' dust cloud based on the distribution of 280 dust particle trajectories produced by 100 known Kuiper belt objects; the resulting 3-D grid consists of 1.9 x 10' cells containing 1.2 x 10" particle positions. The following processes that influence the dust particle dynamics are taken into account: 1) gravitational scattering on the eight planets (neglecting Pluto); 2) planetary resonances; 3) radiation pressure; and 4) the Poynting-Robertson (P-R) and solar wind drags. We find the dust distribution highly non-uniform: there is a minimum in the kuiperoidal dust between Mars and Jupiter, after which both the column and number densities of kuiperoidal dust sharply increase with heliocentric distance between 5 and 10 AU, and then form a plateau between 10 and 50 AU. Between 25 and 45 AU, there is an appreciable concentration of kuiperoidal dust in the form of a broad belt of mostly resonant particles associated with Neptune. In fact, each giant planet possesses its own circumsolar dust belt consisting of both resonant and gravitationally scattered particles. As with the cometary belts simulated in our related papers, we reveal a rich and sophisticated resonant structure of the dust belts containing families of resonant peaks and gaps. An important result is that both the column and number dust density are more or less flat between 10 and 50 AU, which might explain the surprising data obtained by Pioneers 10 & 11 and Voyager that the dust number density remains approximately distance-independent in this region. The simulated kuiperoidal dust, in addition to asteroidal and cometary dust, might represent a third possible source of the zodiacal light in the Solar system.

Design and implementation of an intelligent belt system using accelerometer.

PubMed

Liu, Botong; Wang, Duo; Li, Sha; Nie, Xuhui; Xu, Shan; Jiao, Bingli; Duan, Xiaohui; Huang, Anpeng

2015-01-01

Activity monitor systems are increasing used recently. They are important for athletes and casual users to manage physical activity during daily exercises. In this paper, we use a triaxial accelerometer to design and implement an intelligent belt system, which can detect the user's step and flapping motion. In our system, a wearable intelligent belt is worn on the user's waist to collect activity acceleration signals. We present a step detection algorithm to detect real-time human step, which has high accuracy and low complexity. In our system, an Android App is developed to manage the intelligent belt. We also propose a protocol, which can guarantee data transmission between smartphones and wearable belt effectively and efficiently. In addition, when users flap the belt in emergency, the smartphone will receive alarm signal sending by the belt, and then notifies the emergency contact person, which can be really helpful for users in danger. Our experiment results show our system can detect physical activities with high accuracy (overall accuracy of our algorithm is above 95%) and has an effective alarm subsystem, which is significant for the practical use.

Cost-benefit analysis of safety belts in Texas school buses.

PubMed

Begley, C E; Biddle, A K

1988-01-01

Although safety belts have been shown to reduce the risk of serious injury or death in automobile crashes, evidence of their effectiveness in school buses is uncertain. In this paper, the potential costs and benefits of mandatory safety belts in Texas school buses are estimated, based on the assumption that their effectiveness is less than or equal to rear seatbelt effectiveness in autos. Costs are based on both retrofitting old buses with belts and installing them in new buses. Benefits include the direct and indirect (forgone earnings) cost-savings from preventable injuries and fatalities. Results indicate that a law mandating safety belts in Texas school buses would not be cost-beneficial. Annual benefits would exceed the annual costs of installing belts in new school buses. However, the benefits would not be large enough to compensate for the five-year costs associated with retrofitting old buses.

Cost-benefit analysis of safety belts in Texas school buses.

PubMed Central

Begley, C E; Biddle, A K

1988-01-01

Although safety belts have been shown to reduce the risk of serious injury or death in automobile crashes, evidence of their effectiveness in school buses is uncertain. In this paper, the potential costs and benefits of mandatory safety belts in Texas school buses are estimated, based on the assumption that their effectiveness is less than or equal to rear seatbelt effectiveness in autos. Costs are based on both retrofitting old buses with belts and installing them in new buses. Benefits include the direct and indirect (forgone earnings) cost-savings from preventable injuries and fatalities. Results indicate that a law mandating safety belts in Texas school buses would not be cost-beneficial. Annual benefits would exceed the annual costs of installing belts in new school buses. However, the benefits would not be large enough to compensate for the five-year costs associated with retrofitting old buses. PMID:3140273

Kuiper Belt Objects Along the Pluto-Express Path

NASA Technical Reports Server (NTRS)

Jewitt, David (Principal Investigator)

1997-01-01

The science objective of this work is to identify objects in the Kuiper Belt which will, in the 5 years following Pluto encounter, be close to the flight path of NASA's Pluto Express. Our hope is that we will find a Kuiper Belt object or objects close enough that a spacecraft flyby will be possible. If we find a suitable object, the science yield of Pluto Express will be substantially enhanced. The density of objects in the Kuiper Belt is such that we are reasonably likely to find an object close enough to the flight path that on-board gas thrusters can effect a close encounter.

Seat belt and child seat use in Lipetskaya Oblast, Russia: frequencies, attitudes, and perceptions.

PubMed

Ma, Sai; Tran, Nhan; Klyavin, Vladimir E; Zambon, Francesco; Hatcher, Kristin W; Hyder, Adnan A

2012-01-01

Despite the importance of understanding seat belt use patterns among drivers and passengers for the purpose of direct interventions or monitoring improvements, no study has described wearing rates for all seat positions in Russia. This study describes observed seat belt use and knowledge, attitudes, and perceptions of seat belt use in Lipetskaya Oblast, Russia. An observational study on the use of seat belts and child restraints in the Lipetskaya region conducted during October 2010 collected data in 6 districts and on 3 different road types. A roadside survey gathered information on knowledge, attitudes, and perceptions toward the use of seat belts from randomly selected drivers. Frequencies of seat belt use by seat position, gender, and road type were calculated. A multivariable logit model disclosed the associations between seat belt use and sociodemographic factors. The study design permitted comparison of observed seat belt use to self-reported seat belt use. A total of 25,795 vehicles and 39,833 drivers and passengers contributed observations. Overall, 55 percent of drivers were observed to be using seat belts. More than half (58%) of front seat passengers wore seat belts and only 9 percent of back seat passengers were observed to be wearing seat belts; 11 percent of cars with children had any type of child safety measure. Drivers on urban roads were less likely to wear seat belts compared to those on main highways and rural roads. Nearly 60 percent of survey respondents mentioned "seat belts save lives," and more than half mentioned law requirements and fines. Although the observed seat belt use in Lipetskaya Oblast is much higher than previous estimates in Russia, overall wearing rates remain far from universal. Rear seat passengers and children are particularly at risk. Because combined education and enforcement has proven to be effective elsewhere, such interventions are needed to improve seat belt use.

Ligandless dispersive liquid--liquid microextraction of iron in biological and foodstuff samples and its determination by Electrothermal atomic absorption spectrometry.

PubMed

Madadizadeh, Mohadeseh; Taher, Mohammad Ali; Ashkenani, Hamid

2013-01-01

A new, simple, and efficient method comprising ligandless dispersive liquid-liquid microextraction combined with electrothermal atomic absorption spectrometry is reported for the preconcentration and determination of ultratrace amounts of Fe(III). Carbon tetrachloride and acetone were used as the extraction and disperser solvents, respectively. Some effective parameters of the microextraction such as choice of extraction and disperser solvents, their volume, extraction time and temperature, salt and surfactant effect, and pH were optimized. Under the optimum conditions, the calibration curve was linear in the range of 0.02 to 0.46 microg/L of Fe(III), with LOD and LOQ of 5.2 and 17.4 ng/L, respectively. The RSD for seven replicated determinations of Fe(IIl) ion at 0.1 microg/L concentration level was 5.2%. Operational simplicity, rapidity, low cost, good repeatability, and low consumption of extraction solvent are the main advantages of the proposed method. The method was successfully applied to the determination of iron in biological, food, and certified reference samples.

Microfluidic magnetic bead conveyor belt.

PubMed

van Pelt, Stijn; Frijns, Arjan; den Toonder, Jaap

2017-11-07

Magnetic beads play an important role in the miniaturization of clinical diagnostics systems. In lab-on-chip platforms, beads can be made to link to a target species and can then be used for the manipulation and detection of this species. Current bead actuation systems utilize complex on-chip coil systems that offer low field strengths and little versatility. We demonstrate a novel system based on an external rotating magnetic field and on-chip soft-magnetic structures to focus the field locally. These structures were designed and optimized using finite element simulations in order to create a number of local flux density maxima. These maxima, to which the magnetic beads are attracted, move over the chip surface in a continuous way together with the rotation of the external field, resulting in a mechanism similar to that of a conveyor belt. A prototype was fabricated using PDMS molding techniques mixed with iron powder for the magnetic structures. In the subsequent experiments, a quadrupole electromagnet was used to create the rotating external field. We observed that beads formed agglomerates that rolled over the chip surface, just above the magnetic structures. Field rotation frequencies between 0.1-50 Hz were tested resulting in magnetic bead speeds of over 1 mm s -1 for the highest frequency. With this, we have shown that our novel concept works, combining a simple design and simple operation with a powerful and versatile method for bead actuation. This makes it a promising method for further research and utilization in lab-on-chip systems.

46 CFR 169.825 - Wearing of safety belts.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Wearing of safety belts. 169.825 Section 169.825 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) NAUTICAL SCHOOLS SAILING SCHOOL VESSELS Operations § 169.825 Wearing of safety belts. The master of each vessel shall ensure that each person wears...

46 CFR 169.825 - Wearing of safety belts.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 7 2011-10-01 2011-10-01 false Wearing of safety belts. 169.825 Section 169.825 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) NAUTICAL SCHOOLS SAILING SCHOOL VESSELS Operations § 169.825 Wearing of safety belts. The master of each vessel shall ensure that each person wears...

Pattern of seat belt use by drivers in Trinidad and Tobago, West Indies

PubMed Central

2011-01-01

Background In Trinidad and Tobago, the law on the mandatory use of seat belts was passed in 1995, but this law is hardly enforced. The objective of this study was to determine the frequency and predictors of seat belt use by motor vehicle drivers in the country. Findings A cross-sectional study of 959 motor vehicle drivers using a self-administered questionnaire. Data analysis included Pearson Chi square test and multinomial logistic regression analysis in order to determine the possible predictors of seat belt use by the drivers in Trinidad and Tobago. A majority of the drivers sometimes (51.8%) or always (31.6%) use a seat belt. About 16.7%, 29% and 54.2% of the drivers perceived that the other drivers use their seat belts more frequently, with the same frequency and less frequently respectively compared to themselves. The main reason for not using seat belt by the drivers was given as frequent stops (40.7%) and the main motivation to use seat belt by the drivers was given as stiffer penalties for non-compliance with the seat belt law (44.5%). The predictors of seat belt use were male driver, no formal or lower level of education, driving for less than 10 years, and the perception that the other drivers use seat belts with the same or higher frequency compared to the respondents. Conclusion Only a small proportion of the drivers in Trinidad and Tobago always use a seat belt when driving. There is the need to enforce the seat belt legislation in the country. PMID:21679410

Planetary Migration and Kuiper Belt Dynamics

NASA Astrophysics Data System (ADS)

Malhotra, Renu

The Kuiper belt holds memory of the dynamical processes that shaped the architecture of the solar system, including the orbital migration history of the giant planets. We propose studies of the orbital dynamics of the Kuiper Belt in order to understand the origin of its complex dynamical structure and its link to the orbital migration history of the giant planets. By means of numerical simulations, statistical tests, as well as analytical calculations we will (1) investigate the origin of resonant Kuiper belt objects to test alternative scenarios of Neptune's migration history, (2) investigate the long term dynamical evolution of the Haumea family of Kuiper Belt objects in order to improve the age estimate of this family, and (3) investigate resonance-sticking behavior and the Kozai-Lidov mechanism and its role in the origin of the extended scattered disk. These studies directly support the goals of the NASA-OSS program by improving our understanding of the origin of the solar system's architecture. Our results will provide constraints on the nature and timing of the dynamical excitation event that is thought to have occurred in early solar system history and to have determined the architecture of the present-day solar system; our results will also provide deeper theoretical understanding of sticky mean motion resonances which contribute greatly to the longevity of many small bodies, improve our understanding of dynamical transport of planetesimals in planetary systems, and help interpret observations of other planetary systems.

Potential Jupiter-Family comet contamination of the main asteroid belt

NASA Astrophysics Data System (ADS)

Hsieh, Henry H.; Haghighipour, Nader

2016-10-01

We present the results of "snapshot" numerical integrations of test particles representing comet-like and asteroid-like objects in the inner Solar System aimed at investigating the short-term dynamical evolution of objects close to the dynamical boundary between asteroids and comets as defined by the Tisserand parameter with respect to Jupiter, TJ (i.e., TJ = 3). As expected, we find that TJ for individual test particles is not always a reliable indicator of initial orbit types. Furthermore, we find that a few percent of test particles with comet-like starting elements (i.e., similar to those of Jupiter-family comets) reach main-belt-like orbits (at least temporarily) during our 2 Myr integrations, even without the inclusion of non-gravitational forces, apparently via a combination of gravitational interactions with the terrestrial planets and temporary trapping by mean-motion resonances with Jupiter. We estimate that the fraction of real Jupiter-family comets occasionally reaching main-belt-like orbits on Myr timescales could be on the order of ∼ 0.1-1%, although the fraction that remain on such orbits for appreciable lengths of time is certainly far lower. For this reason, the number of JFC-like interlopers in the main-belt population at any given time is likely to be small, but still non-zero, a finding with significant implications for efforts to use apparently icy yet dynamically asteroidal main-belt comets as tracers of the primordial distribution of volatile material in the inner Solar System. The test particles with comet-like starting orbital elements that transition onto main-belt-like orbits in our integrations appear to be largely prevented from reaching low eccentricity, low inclination orbits, suggesting that the real-world population of main-belt objects with both low eccentricities and inclinations may be largely free of this potential occasional Jupiter-family comet contamination. We therefore find that low-eccentricity, low-inclination main-belt

New features in the structure of the classical Kuiper Belt

NASA Astrophysics Data System (ADS)

Gladman, Brett; Bannister, Michele T.; Alexandersen, Mike; Chen, Ying-Tung; Gwyn, Stephen; Kavelaars, J. J.; Petit, Jean-Marc; Volk, Kathryn; OSSOS Collaboration

2016-10-01

We report fascinating new dynamical structures emerging from a higher precision view of the classical Kuiper belt (the plentiful non-resonant orbits with semimajor axes in roughly the a=35-60 au range). The classical Kuiper Belt divides into multiple sub-populations: an 'inner' classical belt (a small group of non-resonant objects with a<39.4 au where the 3:2 resonance is located), an abundant 'main' classical belt (between the 3:2 and the 2:1 at a=47.4 au), and a difficult to study outer classical belt beyond the 2:1. We examine the dynamical structure, as precisely revealed in the detections from OSSOS (the Outer Solar System Origin's Survey); the data set is of superb quality in terms of orbital element and numbers of detections (Kavelaars et al, this meeting).The previous CFEPS survey showed that the main classical belt requires a complex dynamical substructure that goes beyond a simple 'hot versus cold' division based primarily on orbital inclination; the 'cold' inclination component requires two sub-components in the semimajor axis and perihelion distance q space (Petit et al 2011). CFEPS modelled this as a 'stirred' component present at all a=40-47 AU semimajor axes, with a dense superposed 'kernel' near a=44 AU at low eccentricity; the first OSSOS data release remained consistent with this (Bannister et al 2016). As with the main asteroid belt, as statistics and orbital quality improve we see additional significant substructure emerging in the classical belt's orbital distribution.OSSOS continues to add evidence that the cold stirred component extends smoothly beyond the 2:1 (Bannister et al 2016). Unexpectedly, the data also reveal the clear existence of a paucity of orbits just beyond the outer edge of the kernel; there are significantly fewer TNOs in the narrow semimajor axis band from a=44.5-45.0 AU. This may be related to the kernel population's creation, or it may be an independent feature created by planet migration as resonances moved in the

Validation of Two Portable Instruments to Measure Iron Concentration in Groundwater in Rural Bangladesh

PubMed Central

Merrill, Rebecca D.; Shamim, Abu Ahmed; Ali, Hasmot; Schulze, Kerry; Rashid, Mahbubur; Christian, Parul; West, Jr., Keith P.

2009-01-01

Iron is ubiquitous in natural water sources used around the world for drinking and cooking. The health impact of chronic exposure to iron through water, which in groundwater sources can reach well above the World Health Organization's defined aesthetic limit of 0.3 mg/L, is not currently understood. To quantify the impact of consumption of iron in groundwater on nutritional status, it is important to accurately assess naturally-occurring exposure levels among populations. In this study, the validity of iron quantification in water was evaluated using two portable instruments: the HACH DR/890 portable colorimeter (colorimeter) and HACH Iron test-kit, Model IR-18B (test-kit), by comparing field-based iron estimates for 25 tubewells located in northwestern Bangladesh with gold standard atomic absorption spectrophotometry analysis. Results of the study suggest that the HACH test-kit delivers more accurate point-of-use results across a wide range of iron concentrations under challenging field conditions. PMID:19507757

Validation of two portable instruments to measure iron concentration in groundwater in rural Bangladesh.

PubMed

Merrill, Rebecca D; Shamim, Abu Ahmed; Labrique, Alain B; Ali, Hasmot; Schulze, Kerry; Rashid, Mahbubur; Christian, Parul; West, Keith P

2009-06-01

Iron is ubiquitous in natural water sources used around the world for drinking and cooking. The health impact of chronic exposure to iron through water, which in groundwater sources can reach well above the World Health Organization's defined aesthetic limit of 0.3 mg/L, is not currently understood. To quantify the impact of consumption of iron in groundwater on nutritional status, it is important to accurately assess naturally-occurring exposure levels among populations. In this study, the validity of iron quantification in water was evaluated using two portable instruments: the HACH DR/890 portable colorimeter (colorimeter) and HACH Iron test-kit, Model IR-18B (test-kit), by comparing field-based iron estimates for 25 tubewells located in northwestern Bangladesh with gold standard atomic absorption spectrophotometry analysis. Results of the study suggest that the HACH test-kit delivers more accurate point-of-use results across a wide range of iron concentrations under challenging field conditions.

49 CFR 571.210 - Standard No. 210; Seat belt assembly anchorages.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 49 Transportation 6 2013-10-01 2013-10-01 false Standard No. 210; Seat belt assembly anchorages... STANDARDS Federal Motor Vehicle Safety Standards § 571.210 Standard No. 210; Seat belt assembly anchorages. S1. Purpose and scope. This standard establishes requirements for seat belt assembly anchorages to...

49 CFR 571.210 - Standard No. 210; Seat belt assembly anchorages.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 6 2011-10-01 2011-10-01 false Standard No. 210; Seat belt assembly anchorages... STANDARDS Federal Motor Vehicle Safety Standards § 571.210 Standard No. 210; Seat belt assembly anchorages. S1. Purpose and scope. This standard establishes requirements for seat belt assembly anchorages to...

49 CFR 571.210 - Standard No. 210; Seat belt assembly anchorages.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 49 Transportation 6 2014-10-01 2014-10-01 false Standard No. 210; Seat belt assembly anchorages... STANDARDS Federal Motor Vehicle Safety Standards § 571.210 Standard No. 210; Seat belt assembly anchorages. S1. Purpose and scope. This standard establishes requirements for seat belt assembly anchorages to...

49 CFR 571.210 - Standard No. 210; Seat belt assembly anchorages.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 49 Transportation 6 2012-10-01 2012-10-01 false Standard No. 210; Seat belt assembly anchorages... STANDARDS Federal Motor Vehicle Safety Standards § 571.210 Standard No. 210; Seat belt assembly anchorages. S1. Purpose and scope. This standard establishes requirements for seat belt assembly anchorages to...

The rock components and structures of Archean greenstone belts: An overview

NASA Technical Reports Server (NTRS)

Lowe, D. R.; Byerly, G. R.

1986-01-01

Knowledge of the character and evolution of the Earth's early crust is derived from the studies of the rocks and structures in Archean greenstone belts. Ability to resolve the petrologic, sedimentological and structural histories of greenstone belts, however, hinges first on an ability to apply the concepts and procedures of classical stratigraphy. Unfortunately, early Precambrian greenstone terrains present particular problems to stratigraphic analysis. Many current controversies of greenstone belt petrogenesis, sedimentology, tectonics and evolution arise more from an inability to develop a clear stratigraphic picture of the belts than from ambiguities in interpretation. Four particular stratigraphic problems that afflict studies of Archean greenstone belts are considered: determination of facing directions, correlation of lithologic units, identification of primary lithologies and discrimination of stratigraphic versus structural contacts.