Sample records for bio-diesel initiatives potential

  1. [Particle emission characteristics of diesel bus fueled with bio-diesel].

    PubMed

    Lou, Di-Ming; Chen, Feng; Hu, Zhi-Yuan; Tan, Pi-Qiang; Hu, Wei

    2013-10-01

    With the use of the Engine Exhaust Particle Sizer (EEPS), a study on the characteristics of particle emissions was carried out on a China-IV diesel bus fueled with blends of 5% , 10% , 20% , 50% bio-diesel transformed from restaurant waste oil and China-IV diesel (marked separately by BD5, BD10, BD20, BD50), pure bio-diesel (BD100) and pure diesel (BD0). The results indicated that particulate number (PN) and mass (PM) emissions of bio-diesel blends increased with the increase in bus speed and acceleration; with increasing bio-diesel content, particulate emissions displayed a relevant declining trend. In different speed ranges, the size distribution of particulate number emissions (PNSD) was bimodal; in different acceleration ranges, PNSD showed a gradual transition from bimodal shape to unimodal when bus operation was switched from decelerating to accelerating status. Bio-diesel blends with higher mixture ratios showed significant reduction in PN emissions for accumulated modes, and the particulate number emission peaks moved towards smaller sizes; but little change was obtained in PN emissions for nuclei modes; reduction also occurred in particle geometric diameter (Dg).

  2. Life Cycle Assessment of Bio-diesel Production—A Comparative Analysis

    NASA Astrophysics Data System (ADS)

    Chatterjee, R.; Sharma, V.; Mukherjee, S.; Kumar, S.

    2014-04-01

    This work deals with the comparative analysis of environmental impacts of bio-diesel produced from Jatropha curcas, Rapeseed and Palm oil by applying the life cycle assessment and eco-efficiency concepts. The environmental impact indicators considered in the present paper include global warming potential (GWP, CO2 equivalent), acidification potential (AP, SO2 equivalent) and eutrophication potential (EP, NO3 equivalent). Different weighting techniques have been used to present and evaluate the environmental characteristics of bio-diesel. With the assistance of normalization values, the eco-efficiency was demonstrated in this work. The results indicate that the energy consumption of bio-diesel production is lowest in Jatropha while AP and EP are more in case of Jatropha than that of Rapeseed and Palm oil.

  3. Performance Evaluation of Diesel Engine with Preheated Bio Diesel with Additives

    NASA Astrophysics Data System (ADS)

    Ram Vajja, Sai; Murali, R. B. V.

    2016-09-01

    This paper mainly reviews about the usage of preheated bio diesel added with 0.5% Etchant as an alternative fuel and evaluates its performance for various blends with different loads. Bio diesel is added with Etchant for rapid combustion as for the bio diesel, the cetane number is high that results in shorter delay of ignition and the mixture is preheated to raise its temperature to improve the combustion process. Analysis of the parameters required to define the combustion characteristics such as IP, BP, ηbth, ηm, ISFC, BSFC, IMEP, MFC, Exhaust Gas Temperature, Heat Release and heat balance is necessary as these values are significant to assess the performance of engine and its emissions of preheated bio diesel.

  4. Feasibility study of utilizing jatropha curcas oil as bio-diesel in an oil firing burner system

    NASA Astrophysics Data System (ADS)

    Shaiful, A. I. M.; Jaafar, M. N. Mohd; Sahar, A. M.

    2017-09-01

    Jatropha oil derived from the Jatropha Curcas Linnaeus is one of the high potential plants to be use as bio-diesel. The purpose of this research is to carry out a feasibility study of using jatropha oil as bio-diesel on oil firing burner system. Like other bio-diesels, jatropha oil can also be used in any combustion engine and the performance and emissions such as NOx, SO2, CO and CO2 as well as unburned hydocarbon (UHC) from the engine will vary depending on the bio-diesel blends. The properties of Conventional Diesel Fuel (CDF) obtained will be used as baseline and the jatropha oil properties will be compared as well as other bio-diesels. From several researches, the properties of jatropha oil was found to be quite similar with other bio-diesel such as palm oil, neem, keranja and pongamia bio-diesel and complying with the ASTM standard for bio-diesel. Still, there are factors and issues concerning the use of jatropha oil such as technology, economy, legislation and resource. Plus, there several challenges to the growth of bio-diesel industry development since the world right now do not totally depend on the bio-diesel.

  5. Preparation and characterization of bio-diesels from various bio-oils.

    PubMed

    Lang, X; Dalai, A K; Bakhshi, N N; Reaney, M J; Hertz, P B

    2001-10-01

    Methyl, ethyl, 2-propyl and butyl esters were prepared from canola and linseed oils through transesterification using KOH and/ or sodium alkoxides as catalysts. In addition, methyl and ethyl esters were prepared from rapeseed and sunflower oils using the same catalysts. Chemical composition of the esters was determined by HPLC for the class of lipids and by GC for fatty acid compositions. The bio-diesel esters were characterized for their physical and fuel properties including density, viscosity, iodine value, acid value, cloud point, pure point, gross heat of combustion and volatility. Methyl and ethyl esters prepared from a particular vegetable oil had similar viscosities, cloud points and pour points, whereas methyl, ethyl, 2-propyl and butyl esters derived from a particular vegetable oil had similar gross heating values. However, their densities, which were 2 7% higher than those of diesel fuels, statistically decreased in the order of methyl approximately 2-propyl > ethyl > butyl esters. Butyl esters showed reduced cloud points (-6 degrees C to -10 degrees C) and pour points (-13 degrees C to -16 degrees C) similar to those of summer diesel fuel having cloud and pour points of -8 degrees C and -15 degrees C, respectively. The viscosities of bio-diesels (3.3-7.6 x 10(-4) Pa s at 40 degrees C) were much less than those of pure oils (22.4-45.1 x 10(-4) Pa s at 40 degrees C) and were twice those of summer and winter diesel fuels (3.50 and 1.72 x 10(-4) Pa s at 40 degrees C), and their gross heat contents of approximately 40 MJ/kg were 11% less than those of diesel fuels (approximately 45 MJ/kg). For different esters from the same vegetable oil, methyl esters were the most volatile, and the volatility decreased as the alkyl group grew bulkier. However, the bio-diesels were considerably less volatile than the conventional diesel fuels.

  6. Mathematical Modeling Of Production Of Bio-surfactant Through Bio-desulfurization Of Hydrotreated Diesel In A Fermenter

    NASA Astrophysics Data System (ADS)

    Bandyopadhyay, Sujaya; Chowdhury, Ranjana; Bhattacharjee, Chiranjib

    2010-10-01

    The conventional deep desulfurization must be followed by a suitable desulfurization process to achieve ultra low sulfur diesel (ULSD) with 10-15 ppm sulfur level which satisfies the strict environmental regulations. Bio-desulfurization is one of the potential routes for the above mentioned purpose. In this present investigation our major concern is production of Ultra Low sulfur diesel (ULSD) and production of biosurfactant simultaneously using Rhodococcus sp. The substituted benzothiophenes (BTs) and dibenzothiophenes (DBTs) get converted to 2-hydroxy biphenyl, which is a potential bio-surfactant. Kinetics of biodesulfurisation of deep desulfurized diesel using Rhodococcus sp. has been studied with special reference to removal of organo-sulfur compounds in diesel and production of 2-hydroxy biphenyl. The sulfur concentration of feed diesel is in the range of 200-540 mg/L. Aqueous phase to diesel ratios have been varied in the range of 9:1 to 1:9. The optimum ratio has been found to be 1:4 and the maximum conversion of sulfur of 95% has been achieved. The values of Monod kinetic parameters, μmax, maximum specific growth rate and Ks, saturation constant of the microbial growth and Yield coefficient of surfactant have been measured to be 0.096 h-1, 71 mg/L, and 17 μmol/g dry cell weights respectively by conducting batch type experiments. A deterministic mathematical model has been developed using the kinetic parameters and the experimental data have been compared with simulated ones satisfactorily.

  7. DSC studies to evaluate the impact of bio-oil on cold flow properties and oxidation stability of bio-diesel.

    PubMed

    Garcia-Perez, Manuel; Adams, Thomas T; Goodrum, John W; Das, K C; Geller, Daniel P

    2010-08-01

    This paper describes the use of Differential Scanning Calorimetry (DSC) to evaluate the impact of varying mix ratios of bio-oil (pyrolysis oil) and bio-diesel on the oxidation stability and on some cold flow properties of resulting blends. The bio-oils employed were produced from the semi-continuous Auger pyrolysis of pine pellets and the batch pyrolysis of pine chips. The bio-diesel studied was obtained from poultry fat. The conditions used to prepare the bio-oil/bio-diesel blends as well as some of the fuel properties of these blends are reported. The experimental results suggest that the addition of bio-oil improves the oxidation stability of the resulting blends and modifies the crystallization behavior of unsaturated compounds. Upon the addition of bio-oil an increase in the oxidation onset temperature, as determined by DSC, was observed. The increase in bio-diesel oxidation stability is likely to be due to the presence of hindered phenols abundant in bio-oils. A relatively small reduction in DSC characteristic temperatures which are associated with cold flow properties was also observed but can likely be explained by a dilution effect. (c) 2010 Elsevier Ltd. All rights reserved.

  8. Recycling used palm oil and used engine oil to produce white bio oil, bio petroleum diesel and heavy fuel

    NASA Astrophysics Data System (ADS)

    Al-abbas, Mustafa Hamid; Ibrahim, Wan Aini Wan; Sanagi, Mohd. Marsin

    2012-09-01

    Recycling waste materials produced in our daily life is considered as an additional resource of a wide range of materials and it conserves the environment. Used engine oil and used cooking oil are two oils disposed off in large quantities as a by-product of our daily life. This study aims at providing white bio oil, bio petroleum diesel and heavy fuel from the disposed oils. Toxic organic materials suspected to be present in the used engine oil were separated using vacuum column chromatography to reduce the time needed for the separation process and to avoid solvent usage. The compounds separated were detected by gas chromatography-mass spectrometry (GC-MS) and found to contain toxic aromatic carboxylic acids. Used cooking oils (thermally cracked from usage) were collected and separated by vacuum column chromatography. White bio oil produced was examined by GC-MS. The white bio oil consists of non-toxic hydrocarbons and is found to be a good alternative to white mineral oil which is significantly used in food industry, cosmetics and drugs with the risk of containing polycyclic aromatic compounds which are carcinogenic and toxic. Different portions of the used cooking oil and used engine were mixed to produce several blends for use as heavy oil fuels. White bio oil was used to produce bio petroleum diesel by blending it with petroleum diesel and kerosene. The bio petroleum diesel produced passed the PETRONAS flash point and viscosity specification test. The heat of combustion of the two blends of heavy fuel produced was measured and one of the blends was burned to demonstrate its burning ability. Higher heat of combustion was obtained from the blend containing greater proportion of used engine oil. This study has provided a successful recycled alternative for white bio oil, bio petroleum fuel and diesel which can be an energy source.

  9. Storage Tanks and Dispensers for E85 and Bio-Diesel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Webster, Michael; Frederick, Justin

    2014-02-10

    Project objective is to improve the District's alternative fueling infrastructure by installing storage tanks and dispensers for E-85 and Bio-Diesel at the existing Blackwell Forest Preserve Alternative Fuel Station. The addition of E-85 and Bio-Diesel at this station will continue to reduce our dependency on foreign oil, while promoting the use of clean burning, domestically produced, renewable alternative fuels. In addition, this station will promote strong intergovernmental cooperation as other governmental agencies have expressed interest in utilizing this station.

  10. [Determination of lead in microemulsified rapeseed oil and bio-diesel oil by GFAAS].

    PubMed

    Li, Sheng-qing; He, Xiao-min; Du, Ping; Wang, Min; Chen, Hao; Wu, Mou-cheng

    2008-10-01

    Bio-diesel oil has attracted much attention as a substitutable energy sources for its renewable and eco-friendly property. However, problems of lead contamination in fuel are also emphasized increasingly at present. So it was of quite significance to determine the contents of lead in bio-diesel oil and its raw material rapeseed oil. An effective method was developed for the rapid determination of lead in rapeseed oil and bio-diesel oil by graphite furnace atomic absorption spectrometry (GFAAS) after their stabilization as microemulsions. In this research work, polyethyleneglycol octyl phenyl ether and n-butanol were used for emulsifier and auxiliary emulsifying agent, respectively. For Pb, efficient thermal stabilization was obtained using NH4H2PO4 as matrix modifier. Sample stabilization was necessary because of evident analyte losses that occurred immediately after sampling. Excellent long-term sample stabilization and the influence of the microemulsion composition on the GFAAS response were observed by mixing different organic solvents. The ashing and atomization temperature and ramp rate influenced the sensitivity obtained for Ph. Take this into account, the optimum conditions of the graphite furnace atomic absorption spectrometric determination of Pb in rapeseed oil and bio-diesel oil samples were investigated. The results showed that the microemulsion was quite stable when the value of V(20% polyethyleneglycol octyl phenyl ether), V(n-butanol), V(oil) and V(water) was 0.1: 8.9: 0.5: 0.5, without matrix interference effect. The determination limit of the proposed method was 126.2 microg x L(-1) for Pb, comfortably below the values found in the analyzed samples. The recoveries were from 81.8% to 109.0%, which performed using the addition of different concentrations of lead to bio-diesel oil, rapeseed oil and petrochemical diesel samples. The relative standard deviation of determination was 5.84%. This work showed the great efficiency of the microemulsion

  11. Development of a Laminar Flame Test Facility for Bio-Diesel Characterization

    NASA Astrophysics Data System (ADS)

    Tan, Giam

    2009-11-01

    The relevance of applying testing standards established for diesel fuels to evaluate bio-diesel fuels motivates the design and fabrication of a vertical combustion chamber to be able to measure flame speeds of the varying strains of bio-diesel fuels and to attain more detailed kinetics information for biodiesel fuel. Extensive research is ongoing to understand the impact of fundamental combustion properties such as ignition characteristics, laminar flame speed, strain sensitivity and extinction strain rates on emission and stability characteristics of the combustor. It is envisioned that further flame studies will provide key kinetics validation data for biodiesel-like molecules -- the current test rig was developed with provisions for optical access and for future spectroscopic measurements. The current work focuses on laminar flame speeds since this important parameter contains fundamental information regarding reactivity, diffusivity, and exothermicity of the fuel mixture. It has a significant impact upon the propensity of a flame to flashback and blowoff and also serves as a key scaling parameter for other important combustion characteristics, such as the turbulent flame structure, turbulent flame speed and flame's spatial distribution etc. The flame experiments are challenging as the tested bio-fuel must be uniformly atomized and uniformly dispersed.

  12. Bio-diesel production directly from the microalgae biomass of Nannochloropsis by microwave and ultrasound radiation.

    PubMed

    Koberg, Miri; Cohen, Moshe; Ben-Amotz, Ami; Gedanken, Aharon

    2011-03-01

    This work offers an optimized method for the direct conversion of harvested Nannochloropsis algae into bio-diesel using two novel techniques. The first is a unique bio-technology-based environmental system utilizing flue gas from coal burning power stations for microalgae cultivation. This method reduces considerably the cost of algae production. The second technique is the direct transesterification (a one-stage method) of the Nannochloropsis biomass to bio-diesel production using microwave and ultrasound radiation with the aid of a SrO catalyst. These two techniques were tested and compared to identify the most effective bio-diesel production method. Based on our results, it is concluded that the microwave oven method appears to be the most simple and efficient method for the one-stage direct transesterification of the as-harvested Nannochloropsis algae. Copyright © 2010 Elsevier Ltd. All rights reserved.

  13. Midwest Clean Diesel Initiative

    EPA Pesticide Factsheets

    The Midwest Clean Diesel Initiative (MCDI) is a collaboration of federal, state and local agencies, along with communities, non-profit organizations and private companies working together by reducing exposure to emissions from diesel engines

  14. Compatibility Assessment of Fuel System Elastomers with Bio-oil and Diesel Fuel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kass, Michael D.; Janke, Christopher J.; Connatser, Raynella M.

    Bio-oil derived via fast pyrolysis is being developed as a renewable fuel option for petroleum distillates. The compatibility of neat bio-oil with six elastomer types was evaluated against the elastomer performance in neat diesel fuel, which served as the baseline. The elastomers included two fluorocarbons, six acrylonitrile butadiene rubbers (NBRs), and one type each of fluorosilicone, silicone, styrene butadiene rubber (SBR), polyurethane, and neoprene. Specimens of each material were exposed to the liquid and gaseous phases of the test fuels for 4 weeks at 60 degrees C, and properties in the wetted and dried states were measured. Exposure to bio-oilmore » produced significant volume expansion in the fluorocarbons, NBRs, and fluorosilicone; however, excessive swelling (over 80%) was only observed for the two fluorocarbons and two NBR grades. The polyurethane specimens were completely degraded by the bio-oil. In contrast, both silicone and SBR exhibited lower swelling levels in bio-oil compared to neat diesel fuel. The implication is that, while polyurethane and fluorocarbon may not be acceptable seal materials for bio-oils, silicone may offer a lower cost alternative.« less

  15. Compatibility Assessment of Fuel System Elastomers with Bio-oil and Diesel Fuel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kass, Michael D.; Janke, Christopher J.; Connatser, Raynella M.

    Here we report that bio-oil derived via fast pyrolysis is being developed as a renewable fuel option for petroleum distillates. The compatibility of neat bio-oil with six elastomer types was evaluated against the elastomer performance in neat diesel fuel, which served as the baseline. The elastomers included two fluorocarbons, six acrylonitrile butadiene rubbers (NBRs), and one type each of fluorosilicone, silicone, styrene butadiene rubber (SBR), polyurethane, and neoprene. Specimens of each material were exposed to the liquid and gaseous phases of the test fuels for 4 weeks at 60 °C, and properties in the wetted and dried states were measured.more » Exposure to bio-oil produced significant volume expansion in the fluorocarbons, NBRs, and fluorosilicone; however, excessive swelling (over 80%) was only observed for the two fluorocarbons and two NBR grades. The polyurethane specimens were completely degraded by the bio-oil. In contrast, both silicone and SBR exhibited lower swelling levels in bio-oil compared to neat diesel fuel. The implication is that, while polyurethane and fluorocarbon may not be acceptable seal materials for bio-oils, silicone may offer a lower cost alternative.« less

  16. Compatibility Assessment of Fuel System Elastomers with Bio-oil and Diesel Fuel

    DOE PAGES

    Kass, Michael D.; Janke, Christopher J.; Connatser, Raynella M.; ...

    2016-07-12

    Here we report that bio-oil derived via fast pyrolysis is being developed as a renewable fuel option for petroleum distillates. The compatibility of neat bio-oil with six elastomer types was evaluated against the elastomer performance in neat diesel fuel, which served as the baseline. The elastomers included two fluorocarbons, six acrylonitrile butadiene rubbers (NBRs), and one type each of fluorosilicone, silicone, styrene butadiene rubber (SBR), polyurethane, and neoprene. Specimens of each material were exposed to the liquid and gaseous phases of the test fuels for 4 weeks at 60 °C, and properties in the wetted and dried states were measured.more » Exposure to bio-oil produced significant volume expansion in the fluorocarbons, NBRs, and fluorosilicone; however, excessive swelling (over 80%) was only observed for the two fluorocarbons and two NBR grades. The polyurethane specimens were completely degraded by the bio-oil. In contrast, both silicone and SBR exhibited lower swelling levels in bio-oil compared to neat diesel fuel. The implication is that, while polyurethane and fluorocarbon may not be acceptable seal materials for bio-oils, silicone may offer a lower cost alternative.« less

  17. Optimization of bio-diesel production from soybean and wastes of cooked oil: combining dielectric microwave irradiation and a SrO catalyst.

    PubMed

    Koberg, Miri; Abu-Much, Riam; Gedanken, Aharon

    2011-01-01

    This work offers an optimized method in the transesterification of pristine (soybean) oil and cooked oil to bio-diesel, based on microwave dielectric irradiation as a driving force for the transesterification reaction and SrO as a catalyst. This combination has demonstrated excellent catalytic activity and stability. The transesterification was carried out with and without stirring. According to 1H NMR spectroscopy and TLC results, this combination accelerates the reaction (to less than 60 s), maintaining a very high conversion (99%) and high efficiency. The catalytic activity of SrO under atmospheric pressure in the presence of air and under the argon atmosphere is demonstrated. The optimum conversion of cooked oil (99.8%) is achieved under MW irradiation of 1100 W output with magnetic stirring after only 10 s. The optimum method decreases the cost of bio-diesel production and has the potential for industrial application in the transesterification of cooked oil to bio-diesel. Copyright © 2010 Elsevier Ltd. All rights reserved.

  18. Compatibility Assessment of Fuel System Infrastructure Plastics with Bio-oil and Diesel Fuel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kass, Michael D.; Janke, Christopher James; Connatser, Raynella M.

    We report that bio-oil derived via fast pyrolysis is being developed as a renewable fuel option for petroleum distillates. The compatibility of neat bio-oil with 18 plastic types was evaluated using neat diesel fuel as the baseline. The plastic materials included polyphenylene sulfide (PPS), polyethylene terephthalate (PET), polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyoxymethylene (POM), POM copolymer, high density polyethylene (HDPE), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene terephthalate glycol (PETG), polythiourea (PTU), four nylon grades, and four thermosetting resins. Specimens of each material were immersed in the test fuels for a period of 16 weeks to achieve full saturation. Except formore » PP and HDPE, the plastic materials underwent higher volume expansion in bio-oil than in the baseline diesel (which was negligible in most cases). This volume increase corresponds to the higher polarity of the bio-oil. PPS, PET, and PTFE were unaffected by bio-oil exposure, but modest swelling (between 2 and 5%) occurred for the two acetals (POM and POM copolymer), Nylon-12, PBT, PETG, and the four resin grades. More moderate swelling (8–15%) was noted for Nylon-6, Nylon-6/6, and Nylon-11, and excessive swell (>40%) occurred for PTU. The nonpolar nature of PP and HDPE matches that of diesel, leading to higher solubility (swell) in this fuel type. Finally, the relatively low volume expansion following exposure indicates that many of the existing infrastructure plastics (excluding PTU) should be suitable for use with bio-oil.« less

  19. Experimental studies on natural aspirated diesel engine fuelled with corn seed oil methyl ester as a bio-diesel.

    NASA Astrophysics Data System (ADS)

    Rama Krishna Reddy, E.; Dhana Raju, V.

    2018-03-01

    This paper evaluates the possibilities of using corn seed oil methyl ester as a fuel for compression ignition engines. The biodiesels are contained high oxygen content, and high Cetane number, due to this properties efficiency of biodiesel is higher than diesel fuel. The experiments were conducted with different biodiesel blends of (B10, B15, B20 and B25) corn seed oil on single cylinder four stroke natural aspirated diesel engines. Performance parameters and exhaust emissions are investigated in this experimental with the blends of the corn seed oil methyl ester and diesel fuel. The test results showed that the bio-diesel blends gives improved results for brake thermal efficiency and specific fuel consumption when compared with the diesel fuel. The emissions of corn seed methyl esters follow the same trend of diesel but the smoke opacity was reduces for all blends. From the investigation, corn seed methyl ester is also having the properties similar to diesel fuel; it is biodegradable and renewable fuel, so it will be used as an alternative for diesel fuel.

  20. Saving energy and reducing emissions of both polycyclic aromatic hydrocarbons and particulate matter by adding bio-solution to emulsified diesel.

    PubMed

    Lin, Yuan-Chung; Lee, Wen-Jhy; Chen, Chun-Chi; Chen, Chung-Bang

    2006-09-01

    Development of emulsified diesel has been driven by the need to reduce emissions from diesel engines and to save energy. Emulsification technology and bio-solution (NOE-7F) were used to produce emulsified diesel in this study. The experimental results indicated that there were no significant separation layers in W13 (13 wt % water + 87 wt % PDF), W16 (16 wt % water + 84 wt % PDF), W19 (19 wt % water + 81 wt % PDF), E13 (13 wt % NOE-7F water + 87 wt % PDF), E16 (16 wt % NOE-7F water + 83 wt % PDF), and E19 (19 wt % NOE-7F water + 81 wt % PDF) after premium diesel fuel (PDF) was emulsified for more than 30 days. In addition, there was no significant increase in damage from using these six emulsified fuels after the operation of the diesel generator for more than one year. The energy saving and reduction of particulate matter (PM) and total polycyclic aromatic hydrocarbons (PAHs) for W13, W16, W19, E13, E16 and E19, respectively, were 3.90%, 30.9%, 27.6%; 3.38%, 37.0%, 34.9%; 2.17%, 22.2%, 15.4%; 5.87%, 38.6%, 49.3%; 5.88%, 57.8%, 58.0%; and 4.75%, 31.1%, 47.3%, compared with PDF. The above results revealed that the bio-solution (NOE-7F) had a catalytic effect which elevated the combustion efficiency and decreased pollutant emissions during the combustion process. Furthermore, bio-solution (NOE-7F) can stabilize the emulsified fuels and enhance energy saving. Thus, emulsified fuels are highly suitable for use as alternative fuels. Due to the increasing price of diesel, emulsified diesel containing NOE-7F has potential for commercial application.

  1. Diesel reformulation using bio-derived propanol to control toxic emissions from a light-duty agricultural diesel engine.

    PubMed

    Thillainayagam, Muthukkumar; Venkatesan, Krishnamoorthy; Dipak, Rana; Subramani, Saravanan; Sethuramasamyraja, Balaji; Babu, Rajesh Kumar

    2017-07-01

    In the Indian agricultural sector, millions of diesel-driven pump-sets were used for irrigation purposes. These engines produce carcinogenic diesel particulates, toxic nitrogen oxides (NOx), and carbon monoxide (CO) emissions which threaten the livelihood of large population of farmers in India. The present study investigates the use of n-propanol, a less-explored high carbon bio-alcohol that can be produced by sustainable pathways from industrial and crop wastes that has an attractive opportunity for powering stationary diesel engines meant for irrigation and rural electrification. This study evaluates the use of n-propanol addition in fossil diesel by up to 30% by vol. and concurrently reports the effects of exhaust gas recirculation (EGR) on emissions of an agricultural DI diesel engine. Three blends PR10, PR20, and PR30 were prepared by mixing 10, 20, and 30% by vol. of n-propanol with fossil diesel. Results when compared to baseline diesel case indicated that smoke density reduced with increasing n-propanol fraction in the blends. PR10, PR20, and PR30 reduced smoke density by 13.33, 33.33, and 60%, respectively. NOx emissions increased with increasing n-propanol fraction in the blends. Later, three EGR rates (10, 20, and 30%) were employed. At any particular EGR rate, smoke density remained lower with increasing n-propanol content in the blends under increasing EGR rates. NOx reduced gradually with EGR. At 30% EGR, the blends PR10, PR20, and PR30 reduced NOx emissions by 43.04, 37.98, and 34.86%, respectively when compared to baseline diesel. CO emissions remained low but hydrocarbon (HC) emissions were high for n-propanol/diesel blends under EGR. Study confirmed that n-propanol could be used by up to 30% by vol. with diesel and the blends delivered lower soot density, NOx, and CO emissions under EGR.

  2. Black Carbon Diesel Initiative in the Russian Arctic

    EPA Pesticide Factsheets

    Mobile and stationary diesel engines are among the largest sources of black carbon emissions in the Arctic. To address this challenge, EPA is leading the Black Carbon Diesel Initiative under the Arctic Black Carbon Initiative (ABCI).

  3. Effects of Alumina Nano Metal Oxide Blended Palm Stearin Methyl Ester Bio-Diesel on Direct Injection Diesel Engine Performance and Emissions

    NASA Astrophysics Data System (ADS)

    Krishna, K.; Kumar, B. Sudheer Prem; Reddy, K. Vijaya Kumar; Charan Kumar, S.; Kumar, K. Ravi

    2017-08-01

    The Present Investigation was carried out to study the effect of Alumina Metal Oxide (Al2O3) Nano Particles as additive for Palm Stearin Methyl Ester Biodiesel (B 100) and their blends as an alternate fuel in four stroke single cylinder water cooled, direct injection diesel engine. Alumina Nano Particles has high calorific value and relatively high thermal conductivity (30-1 W m K-1) compare to diesel, which helps to promote more combustion in engines due to their higher thermal efficiency. In the experimentation Al2O3 were doped in various proportions with the Palm Stearin Methyl Ester Biodiesel (B-100) using an ultrasonicator and a homogenizer with cetyl trimethyl ammonium bromide (CTAB) as the cationic surfactant. The test were performed on a Kirsloskar DI diesel engine at constant speed of 1500 rpm using different Nano Biodiesel Fuel blends (psme+50 ppm, psme+150 ppm, and psme+200 ppm) and results were compared with those of neat conventional diesel and Palm Stearin Methyl Ester Bio diesel. It was observed that for Nano Biodiesel Fuel blend (psme+50ppm) there is an significant reduction in carbon monoxide (CO) emissions and Nox emissions compared to diesel and the brake thermal efficiency for (psme+50ppm) was almost same as diesel.

  4. Montana BioDiesel Initiative

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Peyton, Brent

    This initiative funding helped put Montana State University (MSU) in a position to help lead in the development of biodiesel production strategies. Recent shortages in electrical power and rising gasoline prices have focused much attention on the development of alternative energy sources that will end our dependence on fossil fuels. In addition, as the concern for environmental impact of utilizing fossil fuels increases, effective strategies must be implemented to reduce emissions or the increased regulations imposed on fossil fuel production will cause economic barriers for their use to continue to increase. Biodiesel has been repeatedly promoted as a more environmentallymore » sound and renewable source of fuel and may prove to be a highly viable solution to provide, at the least, a proportion of our energy needs. Currently there are both practical and economic barriers to the implementation of alternative energy however the advent of these technologies is inevitable. Since many of the same strategies for the storage, transport, and utilization of biodiesel are common with that of fossil fuels, the practical barriers for biodiesel are comparatively minimal. Strategies were developed to harness the CO 2 as feedstock to support the growth of biodiesel producing algae. The initiative funding led to the successful funding of highly rated projects in competitive national grant programs in the National Science Foundation and the Department of Energy. This funding put MSU in a key position to develop technologies to utilize the CO 2 rich emissions produced in fossil fuel utilization and assembled world experts concerning the growth characteristics of photosynthetic microorganisms capable of producing biodiesel.« less

  5. Air Permitting Implications of a Biorefinery Producing Raw Bio-Oil in Comparison with Producing Gasoline and Diesel Blendstocks

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bhatt, Arpit H; Zhang, Yi Min

    A biorefinery, considered a chemical process plant under the Clean Air Act permitting program, could be classified as a major or minor source based on the size of the facility and magnitude of regulated pollutants emitted. Our previous analysis indicates that a biorefinery using fast pyrolysis conversion process to produce finished gasoline and diesel blendstocks with a capacity of processing 2,000 dry metric tons of biomass per day would likely be classified as a major source because several regulated pollutants (such as particulate matter, sulfur dioxide, nitrogen oxide) are estimated to exceed the 100 tons per year (tpy) major sourcemore » threshold, applicable to chemical process plants. Being subject to a major source classification could pose additional challenges associated with obtaining an air permit in a timely manner before the biorefinery can start its construction. Recent developments propose an alternative approach to utilize bio-oil produced via the fast pyrolysis conversion process by shipping it to an existing petroleum refinery, where the raw bio-oil can be blended with petroleum-based feedstocks (e.g., vacuum gas oil) to produce gasoline and diesel blendstocks with renewable content. Without having to hydro-treat raw bio-oil, a biorefinery is likely to reduce its potential-to-emit to below the 100 tpy major source threshold, and therefore expedite its permitting process. We compare the PTE estimates for the two biorefinery designs with and without hydrotreating of bio-oils and examine the air permitting implications on potential air permit classification and discuss the best available control technology requirements for the major source biorefinery utilizing hydrotreating operation. Our analysis is expected to provide useful information to new biofuel project developers to identify opportunities to overcome challenges associated with air permitting.« less

  6. Construction of combustion models for rapeseed methyl ester bio-diesel fuel for internal combustion engine applications.

    PubMed

    Golovitchev, Valeri I; Yang, Junfeng

    2009-01-01

    Bio-diesel fuels are non-petroleum-based diesel fuels consisting of long chain alkyl esters produced by the transesterification of vegetable oils, that are intended for use (neat or blended with conventional fuels) in unmodified diesel engines. There have been few reports of studies proposing theoretical models for bio-diesel combustion simulations. In this study, we developed combustion models based on ones developed previously. We compiled the liquid fuel properties, and the existing detailed mechanism of methyl butanoate ester (MB, C(5)H(10)O(2)) oxidation was supplemented by sub-mechanisms for two proposed fuel constituent components, C(7)H(16) and C(7)H(8)O (and then, by mp2d, C(4)H(6)O(2) and propyne, C(3)H(4)) to represent the combustion model for rapeseed methyl ester described by the chemical formula, C(19)H(34)O(2) (or C(19)H(36)O(2)). The main fuel vapor thermal properties were taken as those of methyl palmitate C(19)H(36)O(2) in the NASA polynomial form of the Burcat database. The special global reaction was introduced to "crack" the main fuel into its constituent components. This general reaction included 309 species and 1472 reactions, including soot and NO(x) formation processes. The detailed combustion mechanism was validated using shock-tube ignition-delay data under diesel engine conditions. For constant volume and diesel engine (Volvo D12C) combustion modeling, this mechanism could be reduced to 88 species participating in 363 reactions.

  7. Subcritical hydrothermal liquefaction of cattle manure to bio-oil: Effects of conversion parameters on bio-oil yield and characterization of bio-oil.

    PubMed

    Yin, Sudong; Dolan, Ryan; Harris, Matt; Tan, Zhongchao

    2010-05-01

    In this study, cattle manure was converted to bio-oil by subcritical hydrothermal liquefaction in the presence of NaOH. The effects of conversion temperature, process gas, initial conversion pressure, residence time and mass ratio of cattle manure to water on the bio-oil yield were studied. The bio-oil was characterized in terms of elemental composition, higher heating value, ultraviolet-visible (UV/Vis) spectroscopy, Fourier transform infrared spectroscopy (FTIR), gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). Results showed that the bio-oil yield depended on the conversion temperature and the process gas. Higher initial conversion pressure, longer residence time and larger mass ratio of cattle manure to water, however, had negative impacts on the bio-oil yield. The higher heating value of bio-oil was 35.53MJ/kg on average. The major non-polar components of bio-oil were toluene, ethyl benzene and xylene, which are components of crude oil, gasoline and diesel. Copyright 2010 Elsevier Ltd. All rights reserved.

  8. Optimization of Biomass Gasification Process for F-T Bio-Diesel Synthesys

    NASA Astrophysics Data System (ADS)

    Song, Jae Hun; Sung, Yeon Kyung; Yu, Tae U.; Choi, Young Tae; Lee, Uen Do

    The characteristics of biomass steam gasification were investigated to make an optimum syngas for Fischer Tropsch (F-T) synthesis of bio-diesel. Korean pine wood chip was used as a fuel and the experiment was conducted in a lab scale bubbling fluidized bed (0.1m LD. x 3.Omheight). Gas composition was evaluated by changing operating parameters such as gasifier temperature, and steam to fuel ratio. Major syngas was monitored by on-line gas analyzer (ND-IR spectroscopy) and gas chromatography (GC). As the temperature of gasifier increases hydrogen in the syngas increases while CO in the product gas decreases. The low concentration of sulfur compound and nitrogen in the product gas shows the potential advantages in the purification process of the syngas for F-T process. Optimum operating condition of the gasifier was found concerning the following gas cleaning and F-T process; H2-CO ratio and total gas yield increase while decreasing methane and CO2 concentrations in the syngas.

  9. Short term endurance results on a single cylinder diesel engine fueled with upgraded bio oil biodiesel emulsion

    NASA Astrophysics Data System (ADS)

    Prakash, R.; Murugan, S.

    2017-11-01

    This paper deliberates the endurance test outcomes obtained from a single cylinder, diesel engine fueled with an upgraded bio oil biodiesel emulsion. In this investigation a bio oil obtained by pyrolysis of woody biomass was upgraded with acid treatment. The resulted bio oil was emulsified with addition of biodiesel and suitable surfactant which is termed as ATJOE15. The main objective of the endurance test was to evaluate the wear characteristics of the engine components and lubrication oil properties, when the engine is fueled with the ATJOE15 emulsion. The photographic views taken before and after the end of 100 hrs endurance test, and visual inspection of the engine components, wear and carbon deposit results, are discussed in this paper.

  10. Potential of Sagittaria trifolia for Phytoremediation of Diesel.

    PubMed

    Zhang, Xinying; Wang, Jun; Liu, Xiaoyan; Gu, Lingfeng; Hou, Yunyun; He, Chiquan; Chen, Xueping; Liang, Xia

    2015-01-01

    The phytoremediation potential and responses of Sagittaria trifolia to diesel were investigated. In order to elucidate the biochemical and physiological responses of S. trifolia to diesel, the chlorophyll content, root vitality, soluble protein content and antioxidant enzymes activity (peroxidase (POD), catalase (CAT) and antioxidant enzymes superoxide dismutase (SOD)) were determined in the plant tissues after 50 d of diesel treatment. The results showed the presence of S. trifolia significantly improved the removal ratios of diesel, from 21∼36% in the control soils to 54∼85% in the planted soils. The chlorophyll content, root vitality and soluble protein content all increased at low diesel concentration, then decreased at high diesel concentration. The activities of CAT and POD exhibited peak values at 5 g·kg(-1) diesel treatment and declined at higher diesel concentrations. However, the activity of SOD kept stable at lower diesel concentration (1 and 5 g·kg(-1)), and also declined at higher diesel concentration. Collectively, S. trifolia had the ability to tolerate certain amount of diesel, but when the concentration was up to 10 g·kg(-1), the growth of S. trifolia would be restrained. The results also showed that variation of antioxidant enzyme activity was an important response in plants to diesel pollution.

  11. Potential hazards associated with combustion of bio-derived versus petroleum-derived diesel fuel

    PubMed Central

    Bünger, Jürgen; Krahl, Jürgen; Schröder, Olaf; Schmidt, Lasse; Westphal, Götz A.

    2012-01-01

    Fuels from renewable resources have gained worldwide interest due to limited fossil oil sources and the possible reduction of atmospheric greenhouse gas. One of these fuels is so called biodiesel produced from vegetable oil by transesterification into fatty acid methyl esters (FAME). To get a first insight into changes of health hazards from diesel engine emissions (DEE) by use of biodiesel scientific studies were reviewed which compared the combustion of FAME with common diesel fuel (DF) for legally regulated and non-regulated emissions as well as for toxic effects. A total number of 62 publications on chemical analyses of DEE and 18 toxicological in vitro studies were identified meeting the criteria. In addition, a very small number of human studies and animal experiments were available. In most studies, combustion of biodiesel reduces legally regulated emissions of carbon monoxide, hydrocarbons, and particulate matter. Nitrogen oxides are regularly increased. Among the non-regulated emissions aldehydes are increased, while polycyclic aromatic hydrocarbons are lowered. Most biological in vitro assays show a stronger cytotoxicity of biodiesel exhaust and the animal experiments reveal stronger irritant effects. Both findings are possibly caused by the higher content of nitrogen oxides and aldehydes in biodiesel exhaust. The lower content of PAH is reflected by a weaker mutagenicity compared to DF exhaust. However, recent studies show a very low mutagenicity of DF exhaust as well, probably caused by elimination of sulfur in present DF qualities and the use of new technology diesel engines. Combustion of vegetable oil (VO) in common diesel engines causes a strongly enhanced mutagenicity of the exhaust despite nearly unchanged regulated emissions. The newly developed fuel “hydrotreated vegetable oil” (HVO) seems to be promising. HVO has physical and chemical advantages compared to FAME. Preliminary results show lower regulated and non-regulated emissions and a

  12. Potential hazards associated with combustion of bio-derived versus petroleum-derived diesel fuel.

    PubMed

    Bünger, Jürgen; Krahl, Jürgen; Schröder, Olaf; Schmidt, Lasse; Westphal, Götz A

    2012-10-01

    Fuels from renewable resources have gained worldwide interest due to limited fossil oil sources and the possible reduction of atmospheric greenhouse gas. One of these fuels is so called biodiesel produced from vegetable oil by transesterification into fatty acid methyl esters (FAME). To get a first insight into changes of health hazards from diesel engine emissions (DEE) by use of biodiesel scientific studies were reviewed which compared the combustion of FAME with common diesel fuel (DF) for legally regulated and non-regulated emissions as well as for toxic effects. A total number of 62 publications on chemical analyses of DEE and 18 toxicological in vitro studies were identified meeting the criteria. In addition, a very small number of human studies and animal experiments were available. In most studies, combustion of biodiesel reduces legally regulated emissions of carbon monoxide, hydrocarbons, and particulate matter. Nitrogen oxides are regularly increased. Among the non-regulated emissions aldehydes are increased, while polycyclic aromatic hydrocarbons are lowered. Most biological in vitro assays show a stronger cytotoxicity of biodiesel exhaust and the animal experiments reveal stronger irritant effects. Both findings are possibly caused by the higher content of nitrogen oxides and aldehydes in biodiesel exhaust. The lower content of PAH is reflected by a weaker mutagenicity compared to DF exhaust. However, recent studies show a very low mutagenicity of DF exhaust as well, probably caused by elimination of sulfur in present DF qualities and the use of new technology diesel engines. Combustion of vegetable oil (VO) in common diesel engines causes a strongly enhanced mutagenicity of the exhaust despite nearly unchanged regulated emissions. The newly developed fuel "hydrotreated vegetable oil" (HVO) seems to be promising. HVO has physical and chemical advantages compared to FAME. Preliminary results show lower regulated and non-regulated emissions and a

  13. Analytical characterization of products obtained from slow pyrolysis of Calophyllum inophyllum seed cake: study on performance and emission characteristics of direct injection diesel engine fuelled with bio-oil blends.

    PubMed

    Rajamohan, Sakthivel; Kasimani, Ramesh

    2018-04-01

    This paper aims to analyse the characteristics and properties of the fractions obtained from slow pyrolysis of non-edible seed cake of Calophyllum inophyllum (CI). The gas, bio-oil and biochar obtained from the pyrolysis carried out at 500 °C in a fixed bed batch type reactor at a heating rate of 30 °C/min were characterized by various analytical techniques. Owing to the high volatile content of CI biomass (72.61%), it was selected as the raw material in this present investigation. GC-MS and FT-IR analysis of bio-oil showed the presence of higher amount of oxygenated compounds, phenol derivatives, esters, acid and furans. The physicochemical properties of the bio-oil were tested as per ASTM norms which imply that bio-oil is a highly viscous liquid with lower heating value as compared to that of diesel fuel. The chemical composition of evolved gas was analysed by using GC testing which revealed the presence of combustible components. The FT-IR characterization of biochar showed the presence of aliphatic and aromatic hydrocarbons whereas the elevated amount of carbon in biochar indicates its potential to be used as solid fuel. The performance and emission characteristics of CI engine were assessed with different CI bio-oil blends and compared with baseline diesel fuel. The results showed that addition of bio-oil leads to decreased brake thermal efficiency and increased brake specific energy consumption. Meanwhile, increase in blend ratio reduces harmful pollutants such as oxides of nitrogen and smoke in the exhaust. From the engine testing, it is suggested to employ 20% of CI bio-oil blends in CI engine to obtain better operation.

  14. Experimental assessment of toxic phytochemicals in Jatropha curcas: oil, cake, bio-diesel and glycerol.

    PubMed

    Pradhan, Subhalaxmi; Naik, S N; Khan, M Ashhar I; Sahoo, P K

    2012-02-01

    Jatropha curcas seed is a rich source of oil; however, it can not be utilised for nutritional purposes due to presence of toxic and anti-nutritive compounds. The main objective of the present study was to quantify the toxic phytochemicals present in Indian J. curcas (oil, cake, bio-diesel and glycerol). The amount of phorbol esters is greater in solvent extracted oil (2.8 g kg⁻¹) than in expeller oil (2.1 g kg⁻¹). Liquid chromatography-mass spectroscopy analysis of the purified compound from an active extract of oil confirmed the presence of phorbol esters. Similarly, the phorbol esters content is greater in solvent extracted cake (1.1 g kg⁻¹) than in cake after being expelled (0.8 g kg⁻¹). The phytate and trypsin inhibitory activity of the cake was found to be 98 g kg⁻¹ and 8347 TIU g⁻¹ of cake, respectively. Identification of curcin was achieved by sodium dodecyl sulfate-polyacrylamide gel electrophoresis and the concentration of curcin was 0.95 g L⁻¹ of crude concentrate obtained from cake. Higher amounts of phorbol esters are present in oil than cake but bio-diesel and glycerol are free of phorbol esters. The other anti-nutritional components such as trypsin inhibitors, phytates and curcin are present in cake, so the cake should be detoxified before being used for animal feed. Copyright © 2011 Society of Chemical Industry.

  15. Microbial bio-fuels: a solution to carbon emissions and energy crisis.

    PubMed

    Kumar, Arun; Kaushal, Sumit; Saraf, Shubhini A; Singh, Jay Shankar

    2018-06-01

    Increasing energy demand, limited fossil fuel resources and climate change have prompted development of alternative sustainable and economical fuel resources such as crop-based bio-ethanol and bio-diesel. However, there is concern over use of arable land that is used for food agriculture for creation of biofuel. Thus, there is a renewed interest in the use of microbes particularly microalgae for bio-fuel production. Microbes such as micro-algae and cyanobacteria that are used for biofuel production also produce other bioactive compounds under stressed conditions. Microbial agents used for biofuel production also produce bioactive compounds with antimicrobial, antiviral, anticoagulant, antioxidant, antifungal, anti-inflammatory and anticancer activity. Because of importance of such high-value compounds in aquaculture and bioremediation, and the potential to reduce carbon emissions and energy security, the biofuels produced by microbial biotechnology might substitute the crop-based bio-ethanol and bio-diesel production.

  16. Maximizing the stability of pyrolysis oil/diesel fuel emulsions

    USDA-ARS?s Scientific Manuscript database

    Several emulsions consisting of biomass pyrolysis oil (bio-oil) in diesel fuel were produced and analyzed for stability over time. An ultrasonic probe was used to generate microscopic droplets of bio-oil suspended in diesel fuel, and this emulsion was stabilized using surfactant chemicals. The most...

  17. Performance and emission characteristics of a low heat rejection engine with different air gap thicknesses with Jatropha oil based bio-diesel.

    PubMed

    Murali Krishna, M V S; Sarita, G; Seshagiri Rao, V V R; Chowdary, R P; Ramana Reddy, Ch V

    2010-04-01

    The research work on alternate fuels has been the topic of wider interest in the context of depletion of fossil fuels and increasing of pollution levels of the engines with conventional fossil fuels. Alcohols and vegetable oils are considered to replace diesel fuels as they are renewable in nature. However, use of alcohols in internal combustion engines is limited in India, as these fuels are diverted to PetroChemical industries and hence much emphasis is given to the non-edible vegetable oils as alternate fuels in internal combustion engines. However, the drawbacks of low volatility and high viscosity associated with non-edible vegetable oils call for hot combustion chamber, provided by low heat rejection (LHR) diesel engine. Investigations are carried out on a LHR diesel engine with varied air gap thicknesses and injection pressures with jatropha oil based bio-diesel at normal temperature. Performance is improved with high degree of insulation with LHR engine with vegetable oil in comparison with conventional engine (CE) with pure diesel operation.

  18. Performance of biomorphic Silicon Carbide as particulate filter in diesel boilers.

    PubMed

    Orihuela, M Pilar; Gómez-Martín, Aurora; Becerra, José A; Chacartegui, Ricardo; Ramírez-Rico, Joaquín

    2017-12-01

    Biomorphic Silicon Carbide (bioSiC) is a novel porous ceramic material with excellent mechanical and thermal properties. Previous studies have demonstrated that it may be a good candidate for its use as particle filter media of exhaust gases at medium or high temperature. In order to determine the filtration efficiency of biomorphic Silicon Carbide, and its adequacy as substrate for diesel particulate filters, different bioSiC-samples have been tested in the flue gases of a diesel boiler. For this purpose, an experimental facility to extract a fraction of the boiler exhaust flow and filter it under controlled conditions has been designed and built. Several filter samples with different microstructures, obtained from different precursors, have been tested in this bench. The experimental campaign was focused on the measurement of the number and size of particles before and after placing the samples. Results show that the initial efficiency of filters made from natural precursors is severely determined by the cutting direction and associated microstructure. In biomorphic Silicon Carbide derived from radially cut wood, the initial efficiency of the filter is higher than 95%. Nevertheless, when the cut of the wood is axial, the efficiency depends on the pore size and the permeability, reaching in some cases values in the range 70-90%. In this case, the presence of macropores in some of the samples reduces their efficiency as particle traps. In continuous operation, the accumulation of particles within the porous media leads to the formation of a soot cake, which improves the efficiency except in the case when extra-large pores exist. For all the samples, after a few operation cycles, capture efficiency was higher than 95%. These experimental results show the potential for developing filters for diesel boilers based on biomorphic Silicon Carbide. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Sustainable Energy Production from Jatropha Bio-Diesel

    NASA Astrophysics Data System (ADS)

    Yadav, Amit Kumar; Krishna, Vijai

    2012-10-01

    The demand for petroleum has risen rapidly due to increasing industrialization and modernization of the world. This economic development has led to a huge demand for energy, where the major part of that energy is derived from fossil sources such as petroleum, coal and natural gas. Continued use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies. There is a growing interest in using Jatropha curcas L. oil as the feedstock for biodiesel production because it is non-edible and thus does not compromise the edible oils, which are mainly used for food consumption. Further, J. curcas L. seed has a high content of free fatty acids that is converted in to biodiesel by trans esterification with alcohol in the presence of a catalyst. The biodiesel produced has similar properties to that of petroleum-based diesel. Biodiesel fuel has better properties than petro diesel fuel; it is renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. Biodiesel seems to be a realistic fuel for future. Biodiesel has the potential to economically, socially, and environmentally benefit communities as well as countries, and to contribute toward their sustainable development.

  20. Assessment of bio-fuel options for solid oxide fuel cell applications

    NASA Astrophysics Data System (ADS)

    Lin, Jiefeng

    Rising concerns of inadequate petroleum supply, volatile crude oil price, and adverse environmental impacts from using fossil fuels have spurred the United States to promote bio-fuel domestic production and develop advanced energy systems such as fuel cells. The present dissertation analyzed the bio-fuel applications in a solid oxide fuel cell-based auxiliary power unit from environmental, economic, and technological perspectives. Life cycle assessment integrated with thermodynamics was applied to evaluate the environmental impacts (e.g., greenhouse gas emission, fossil energy consumption) of producing bio-fuels from waste biomass. Landfill gas from municipal solid wastes and biodiesel from waste cooking oil are both suggested as the promising bio-fuel options. A nonlinear optimization model was developed with a multi-objective optimization technique to analyze the economic aspect of biodiesel-ethanol-diesel ternary blends used in transportation sectors and capture the dynamic variables affecting bio-fuel productions and applications (e.g., market disturbances, bio-fuel tax credit, policy changes, fuel specification, and technological innovation). A single-tube catalytic reformer with rhodium/ceria-zirconia catalyst was used for autothermal reformation of various heavy hydrocarbon fuels (e.g., diesel, biodiesel, biodiesel-diesel, and biodiesel-ethanol-diesel) to produce a hydrogen-rich stream reformates suitable for use in solid oxide fuel cell systems. A customized mixing chamber was designed and integrated with the reformer to overcome the technical challenges of heavy hydrocarbon reformation. A thermodynamic analysis, based on total Gibbs free energy minimization, was implemented to optimize the operating environment for the reformations of various fuels. This was complimented by experimental investigations of fuel autothermal reformation. 25% biodiesel blended with 10% ethanol and 65% diesel was determined to be viable fuel for use on a truck travelling with

  1. Potential of Diesel Engine, Diesel Engine Design Concepts, Control Strategy and Implementation

    DOT National Transportation Integrated Search

    1980-03-01

    Diesel engine design concepts and control system strategies are surveyed with application to passenger cars and light trucks. The objective of the study is to indicate the fuel economy potential of the technologies investigated. The engine design par...

  2. Combustion Performance and Exhaust Emission of DI Diesel Engine Using Various Sources of Waste Cooking Oil

    NASA Astrophysics Data System (ADS)

    Afiq, Mohd; Azuhairi, Mohd; Jazair, Wira

    2010-06-01

    In Malaysia, more than 200-tone of cooking oil are used by domestic users everyday. After frying process, about a quarter of these cooking oil was remained and drained into sewage system. This will pollutes waterways and affects the ecosystem. The use of waste cooking oil (WCO) for producing bio-diesel was considered in economical factor which current production cost of bio-diesel production is higher in Malaysia due to higher price of palm oil. Thus, the aim of this study is to investigate the most suitable source of WCO to become a main source of bio-diesel for bio-diesel production in this country. To perform this research, three type of WCO were obtained from house's kitchen, cafeteria and mamak's restaurant. In this study, prospect of these bio-diesel source was evaluated based on its combustion performance and exhaust emissions operated in diesel engine in the form of waste cooking oil methyl ester (WCOME) and have been compared with pure diesel fuel. A 0.6 liter, single-cylinder, air-cooled direct injection diesel engine was used to perform this experiment. Experiment was done at variable engine loads and constant engine speed. As the result, among three stated WCOMEs, the one collected from house's kitchen gives the best performance in term of brake specific fuel consumption (bsfc) and brake power (BP) with lowest soot emission.

  3. Worldwide wind/diesel hybrid power system study: Potential applications and technical issues

    NASA Astrophysics Data System (ADS)

    King, W. R.; Johnson, B. L., III

    1991-04-01

    The world market potential for wind/diesel hybrid technology is a function of the need for electric power, the availability of sufficient wind resource to support wind/diesel power, and the existence of buyers with the financial means to invest in the technology. This study includes data related to each of these three factors. This study does not address market penetration, which would require analysis of application specific wind/diesel economics. Buyer purchase criteria, which are vital to assessing market penetration, are discussed only generally. Countries were screened for a country-specific market analysis based on indicators of need and wind resource. Both developed countries and less developed countries (LDCs) were screened for wind/diesel market potential. Based on the results of the screening, ten countries showing high market potential were selected for more extensive market analyses. These analyses provide country-specific market data to guide wind/diesel technology developers in making design decisions that will lead to a competitive product. Section 4 presents the country-specific data developed for these analyses, including more extensive wind resource characterization, application-specific market opportunities, business conditions, and energy market characterizations. An attempt was made to identify the potential buyers with ability to pay for wind/diesel technology required to meet the application-specific market opportunities identified for each country. Additionally, the country-specific data are extended to corollary opportunities in countries not covered by the study. Section 2 gives recommendations for wind/diesel research based on the findings of the study.

  4. Co-cracking of real MSW into bio-oil over natural kaolin

    NASA Astrophysics Data System (ADS)

    Gandidi, I. M.; Susila, M. D.; Pambudi, N. A.

    2017-03-01

    Municipal solid waste (MSW) is a potential material that can be converted into bio-oil through thermal degradation process or pyrolysis. The efficiency and productivity of pyrolysis can be increased with the use of natural catalyst like kaolin. The addition of catalyst also reduces the overall cost of conversion process. In this study conversion of MSW into Bio Fuel using Pyrolysis in the presence of of natural kaolin as catalyst has been investigated for 60 min at 400°C temperature. During the process 0.5 w/w catalyst to MSW ratio was maintained. Gas chromatography-mass spectrometry (GC-MS) was used to analyse the chemical composition of bio fuel. It is found that bio-oil production increases substantially with the use of catalyst. It is observed that the production of bio-oil is 23.6 % with the use of catalyst in process, which was only 15.2 % without the use of catalyst. The hydrocarbon range distribution of oil produced through pyrolysis reveals that gasoline and diesel fuel (C5-C20) are its main constituents. The functional group detected in bio-oil by GC-MS analysis is similar to that of diesel-48 in which paraffin and olefin are major mass species.

  5. Experimental investigation of performance and emissions of a VCR diesel engine fuelled with n-butanol diesel blends under varying engine parameters.

    PubMed

    Nayyar, Ashish; Sharma, Dilip; Soni, Shyam Lal; Mathur, Alok

    2017-09-01

    The continuous rise in the cost of fossil fuels as well as in environmental pollution has attracted research in the area of clean alternative fuels for improving the performance and emissions of internal combustion (IC) engines. In the present work, n-butanol is treated as a bio-fuel and investigations have been made to evaluate the feasibility of replacing diesel with a suitable n-butanol-diesel blend. In the current research, an experimental investigation was carried out on a variable compression ratio CI engine with n-butanol-diesel blends (10-25% by volume) to determine the optimum blending ratio and optimum operating parameters of the engine for reduced emissions. The best results of performance and emissions were observed for 20% n-butanol-diesel blend (B20) at a higher compression ratio as compared to diesel while keeping the other parameters unchanged. The observed deterioration in engine performance was within tolerable limits. The reductions in smoke, nitrogen oxides (NO x ), and carbon monoxide (CO) were observed up to 56.52, 17.19, and 30.43%, respectively, for B20 in comparison to diesel at rated power. However, carbon dioxide (CO 2 ) and hydrocarbons (HC) were found to be higher by 17.58 and 15.78%, respectively, for B20. It is concluded that n-butanol-diesel blend would be a potential fuel to control emissions from diesel engines. Graphical abstract ᅟ.

  6. Hypercholesterolemia potentiates aortic endothelial response to inhaled diesel exhaust

    PubMed Central

    Maresh, J. Gregory; Campen, Matthew J.; Reed, Matthew D.; Darrow, April L.; Shohet, Ralph V.

    2012-01-01

    Background Inhalation of diesel exhaust induces vascular effects including impaired endothelial function and increased atherosclerosis. Objective To examine the in vivo effects of subchronic diesel exhaust exposure on endothelial cell transcriptional responses in the presence of hypercholesterolemia. Methods ApoE (−/−) and ApoE (+/+) mice inhaled diesel exhaust diluted to particulate matter levels of 300 or 1000 μg/m3 vs. filtered air. After 30 days, endothelial cells were harvested from dispersed aortic cells by fluorescent-activated cell sorting (FACS). Relative mRNA abundance was evaluated by microarray analysis to measure strain-specific transcriptional responses in mice exposed to dilute diesel exhaust vs. filtered air. Results Forty-nine transcripts were significantly dysregulated by >2.8-fold in the endothelium of ApoE (−/−) mice receiving diesel exhaust at 300 or 1000 μg/m3. These included transcripts with roles in plasminogen activation, endothelial permeability, inflammation, genomic stability, and atherosclerosis; similar responses were not observed in ApoE (+/+) mice. Conclusions The potentiation of diesel exhaust-related endothelial gene regulation by hypercholesterolemia helps to explain air pollution-induced vascular effects in animals and humans. The observed regulated transcripts implicate pathways important in the acceleration of atherosclerosis by air pollution. PMID:21222557

  7. Testing and preformance measurement of straight vegetable oils as an alternative fuel for diesel engines

    NASA Astrophysics Data System (ADS)

    Lakshminarayanan, Arunachalam

    Rising fuel prices, growing energy demand, concerns over domestic energy security and global warming from greenhouse gas emissions have triggered the global interest in bio-energy and bio-fuel crop development. Backlash from these concerns can result in supply shocks of traditional fossil fuels and create immense economic pressure. It is thus widely argued that bio-fuels would particularly benefit developing countries by off-setting their dependencies on imported petroleum. Domestically, the transportation sector accounts for almost 40% of liquid fuel consumption, while on-farm application like tractors and combines for agricultural purposes uses close to an additional 18%. It is estimated that 40% of the farm budget can be attributed to the fuel costs. With the cost of diesel continuously rising, farmers are now looking at using Straight Vegetable Oil (SVO) as an alternative fuel by producing their own fuel crops. This study evaluates conventional diesel compared to the use of SVO like Camelina, Canola and Juncea grown on local farms in Colorado for their performance and emissions on a John Deere 4045 Tier-II engine. Additionally, physical properties like density and viscosity, metal/mineral content, and cold flow properties like CFPP and CP of these oils were measured using ASTM standards and compared to diesel. It was found that SVOs did not show significant differences compared to diesel fuel with regards to engine emissions, but did show an increase in thermal efficiency. Therefore, this study supports the continued development of SVO production as a viable alternative to diesel fuels, particularly for on-farm applications. The need for providing and developing a sustainable, economic and environmental friendly fuel alternative has taken an aggressive push which will require a strong multidisciplinary education in the field of bio-energy. Commercial bio-energy development has the potential to not only alleviate the energy concerns, but also to give renewed

  8. Ethanol-diesel fuel blends -- a review.

    PubMed

    Hansen, Alan C; Zhang, Qin; Lyne, Peter W L

    2005-02-01

    Ethanol is an attractive alternative fuel because it is a renewable bio-based resource and it is oxygenated, thereby providing the potential to reduce particulate emissions in compression-ignition engines. In this review the properties and specifications of ethanol blended with diesel fuel are discussed. Special emphasis is placed on the factors critical to the potential commercial use of these blends. These factors include blend properties such as stability, viscosity and lubricity, safety and materials compatibility. The effect of the fuel on engine performance, durability and emissions is also considered. The formulation of additives to correct certain key properties and maintain blend stability is suggested as a critical factor in ensuring fuel compatibility with engines. However, maintaining vehicle safety with these blends may entail fuel tank modifications. Further work is required in specifying acceptable fuel characteristics, confirming the long-term effects on engine durability, and ensuring safety in handling and storing ethanol-diesel blends.

  9. Dry electrode bio-potential recordings.

    PubMed

    Gargiulo, Gaetano; Bifulco, Paolo; McEwan, Alistair; Nasehi Tehrani, Joubin; Calvo, Rafael A; Romano, Maria; Ruffo, Mariano; Shephard, Richard; Cesarelli, Mario; Jin, Craig; Mohamed, Armin; van Schaik, André

    2010-01-01

    As wireless bio-medical long term monitoring moves towards personal monitoring it demands very high input impedance systems capable to extend the reading of bio-signal during the daily activities offering a kind of "stress free", convenient connection, with no need for skin preparation. In particular we highlight the development and broad applications of our own circuits for wearable bio-potential sensor systems enabled by the use of an FET based amplifier circuit with sufficiently high impedance to allow the use of passive dry electrodes which overcome the significant barrier of gel based contacts. In this paper we present the ability of dry electrodes in long term monitoring of ECG, EEG and fetal ECG.

  10. Extraction of medium chain fatty acids from organic municipal waste and subsequent production of bio-based fuels.

    PubMed

    Kannengiesser, Jan; Sakaguchi-Söder, Kaori; Mrukwia, Timo; Jager, Johannes; Schebek, Liselotte

    2016-01-01

    This paper provides an overview on investigations for a new technology to generate bio-based fuel additives from bio-waste. The investigations are taking place at the composting plant in Darmstadt-Kranichstein (Germany). The aim is to explore the potential of bio-waste as feedstock in producing different bio-based products (or bio-based fuels). For this investigation, a facultative anaerobic process is to be integrated into the normal aerobic waste treatment process for composting. The bio-waste is to be treated in four steps to produce biofuels. The first step is the facultative anaerobic treatment of the waste in a rotting box namely percolate to generate a fatty-acid rich liquid fraction. The Hydrolysis takes place in the rotting box during the waste treatment. The organic compounds are then dissolved and transferred into the waste liquid phase. Browne et al. (2013) describes the hydrolysis as an enzymatically degradation of high solid substrates to soluble products which are further degraded to volatile fatty acids (VFA). This is confirmed by analytical tests done on the liquid fraction. After the percolation, volatile and medium chain fatty acids are found in the liquid phase. Concentrations of fatty acids between 8.0 and 31.5 were detected depending on the nature of the input material. In the second step, a fermentation process will be initiated to produce additional fatty acids. Existing microorganism mass is activated to degrade the organic components that are still remaining in the percolate. After fermentation the quantity of fatty acids in four investigated reactors increased 3-5 times. While fermentation mainly non-polar fatty acids (pentanoic to octanoic acid) are build. Next to the fermentation process, a chain-elongation step is arranged by adding ethanol to the fatty acid rich percolate. While these investigations a chain-elongation of mainly fatty acids with pair numbers of carbon atoms (acetate, butanoic and hexanoic acid) are demonstrated. After

  11. Study on performance of blended fuel PPO - Diesel at generator

    NASA Astrophysics Data System (ADS)

    Prasetyo, Joni; Prasetyo, Dwi Husodo; Murti, S. D. Sumbogo; Adiarso, Priyanto, Unggul

    2018-02-01

    Bio-energy is renewable energy made from plant. Biomass-based energy sources are potentially CO2 neutral and recycle the same carbon atoms. In order to reduce pollution caused by fossil fuel combustion either for mechanical or electrical energy generation, the performance characteristic of purified palm oil blends are analyzed at various ratios. Bio-energy, Pure Plant Oil, represent a sustainable solution.A generator has been modified due to adapt the viscosity ofblended fuel, PPO - diesel, by pre-heating. Several PPO - diesel composition and injection timing were tested in order to investigate the characteristic of mixed fuel with and without pre-heating. The term biofuel refers to liquid or gaseous fuels for the internal combustion engines that are predominantly produced fro m biomass. Surprising result showed that BSFC of blended PPO - diesel was more efficient when injection timing set more than 15° BTDC. The mixed fuel produced power with less mixed fuel even though the calorie content of diesel is higher than PPO. The most efficient was 20% PPO in diesel with BSFC 296 gr fuel / kwh rather than 100% diesel with BSFC 309 gr fuel / kwh at the same injection timing 18° BTDC with pre-heating. The improvement of BSFC is caused by heating up of mixed fuel which it added calorie in the mixed fuel. Therefore, the heating up of blended PPO - diesel is not only to adapt the viscosity but also improving the efficiency of fuel usage representing by lower BSFC. In addition, torque of the 20% PPO was also as smooth as 100% diesel representing by almost the same torqueat injection timing 15° BTDC. The AIP Proceedings article template has many predefined paragraph styles for you to use/apply as you write your paper. To format your abstract, use the Microsoft Word template style: Abstract. Each paper must include an abstract. Begin the abstract with the word "Abstract" followed by a period in bold font, and then continue with a normal 9 point font.

  12. Potential of Diesel Engine, 1979 Summary Source Document

    DOT National Transportation Integrated Search

    1980-03-01

    This document assesses the fuel economy potential of diesel engines in future passenger cars and light trucks. The primary technologies evaluated include: (1) engine control strategy and implementation, (2) the engine design variables, (3) emissions ...

  13. Evaluation Tests of Select Fuel Additives for Potential Use in U.S. Army Corps of Engineers Diesel Engines

    DTIC Science & Technology

    2016-07-01

    DOER) program, diesel fuel additives were tested to evaluate their potential for reducing diesel fuel consumption and cost. Four fuel additives were...tested to evaluate their potential for reducing diesel fuel consumption and cost: • An ethanol injection system • Envirofuels Diesel Fuel Catalyst...reduction in select operation conditions, only the ethanol injection system consistently showed potential to reduce diesel fuel consumption , which may be

  14. Combination of bioremediation and electrokinetics for the in-situ treatment of diesel polluted soil: A comparison of strategies.

    PubMed

    Mena Ramírez, Esperanza; Villaseñor Camacho, José; Rodrigo, Manuel A; Cañizares, Pablo

    2015-11-15

    The aim of this work is to compare different strategies based on electrokinetic soil flushing and bioremediation for the remediation of diesel-polluted soil. Four options were tested at the laboratory scale: single bioremediation (Bio), performed as a control test; a direct combination of electrokinetic soil flushing and biological technologies (EKSF-Bio); EKSF-Bio with daily polarity reversal of the electric field (PR-EKSF-Bio); and a combination of electrokinetic soil flushing and a permeable reactive biological barrier (EKSF-BioPRB). Four batch experiments of 14 days duration were carried out for comparing technologies at room temperature with an electric field of 1.0 V cm(-1) (in EKSF). A diesel degrading microbial consortium was used. The experimental procedure and some specific details, such as the flushing fluids used, varied depending on the strategy. When using the EKSF-Bio option, a high buffer concentration was required to control the pH, causing soil heating, which negatively affected the biological growth and thus the diesel removal. The PR-EKSF-Bio and the EKSF-BioPRB options attained suitable operating conditions and improved the transport processes for biological growth. Polarity reversal was an efficient option for pH, moisture and temperature control. Homogeneous microbial growth was observed, and approximately 20% of the diesel was removed. The BioPRB option was not as efficient as PR-EKSF-Bio in controlling the operating conditions, but the central biobarrier protected the biological activity. Microbial growth was observed not only in the biobarrier but also in a large portion of the soil, and 29% of the diesel was removed in the short remediation test. Copyright © 2015 Elsevier B.V. All rights reserved.

  15. Performance and emission parameters of single cylinder diesel engine using castor oil bio-diesel blended fuels

    NASA Astrophysics Data System (ADS)

    Rahimi, A.; Ghobadian, B.; Najafi, G.; Jaliliantabar, F.; Mamat, R.

    2015-12-01

    The purpose of this study is to investigate the performance and emission parameters of a CI single cylinder diesel engine operating on biodiesel-diesel blends (B0, B5, B10, B15 and E20: 20% biodiesel and 80% diesel by volume). A reactor was designed, fabricated and evaluated for biodiesel production. The results showed that increasing the biodiesel content in the blend fuel will increase the performance parameters and decrease the emission parameters. Maximum power was detected for B0 at 2650 rpm and maximum torque was belonged to B20 at 1600 rpm. The experimental results revealed that using biodiesel-diesel blended fuels increased the power and torque output of the engine. For biodiesel blends it was found that the specific fuel consumption (sfc) was decreased. B10 had the minimum amount for sfc. The concentration of CO2 and HC emissions in the exhaust pipe were measured and found to be decreased when biodiesel blends were introduced. This was due to the high oxygen percentage in the biodiesel compared to the net diesel fuel. In contrast, the concentration of CO and NOx was found to be increased when biodiesel is introduced.

  16. Comparative mutagenicity and genotoxicity of particles and aerosols emitted by the combustion of standard vs. rapeseed methyl ester supplemented bio-diesel fuels: impact of after treatment devices: oxidation catalyst and particulate filter.

    PubMed

    André, V; Barraud, C; Capron, D; Preterre, D; Keravec, V; Vendeville, C; Cazier, F; Pottier, D; Morin, J P; Sichel, F

    2015-01-01

    Diesel exhausts are partly responsible for the deleterious effects on human health associated with urban pollution, including cardiovascular diseases, asthma, COPD, and possibly lung cancer. Particulate fraction has been incriminated and thus largely investigated for its genotoxic properties, based on exposure conditions that are, however, not relevant for human risk assessment. In this paper, original and more realistic protocols were used to investigate the hazards induced by exhausts emitted by the combustion of standard (DF0) vs. bio-diesel fuels (DF7 and DF30) and to assess the impact of exhaust treatment devices (DOC and DPF). Mutagenicity and genotoxicity were evaluated for (1) resuspended particles ("off line" exposure that takes into account the bioavailability of adsorbed chemicals) and for (2) the whole aerosols (particles+gas phase components) under continuous flow exposure ("on line" exposure). Native particles displayed mutagenic properties associated with nitroaromatic profiles (YG1041), whereas PAHs did not seem to be involved. After DOC treatment, the mutagenicity of particles was fully abolished. In contrast, the level of particle deposition was low under continuous flow exposure, and the observed mutagenicity in TA98 and TA102 was thus attributable to the gas phase. A bactericidal effect was also observed in TA102 after DOC treatment, and a weak but significant mutagenicity persisted after DPF treatment for bio-diesel fuels. No formation of bulky DNA-adducts was observed on A549 cells exposed to diesel exhaust, even in very drastic conditions (organic extracts corresponding to 500 μg equivalent particule/mL, 48 h exposure). Taken together, these data indicate that the exhausts issued from the bio-diesel fuels supplemented with rapseed methyl ester (RME), and generated by current diesel engines equipped with after treatment devices are less mutagenic than older ones. The residual mutagenicity is linked to the gas phase and could be due to pro

  17. Biofuel by isomerizing metathesis of rapeseed oil esters with (bio)ethylene for use in contemporary diesel engines

    PubMed Central

    Pfister, Kai F.; Baader, Sabrina; Baader, Mathias; Berndt, Silvia; Goossen, Lukas J.

    2017-01-01

    Rapeseed oil methyl ester (RME) and (bio)ethylene are converted into biofuel with an evenly rising boiling point curve, which fulfills the strict boiling specifications prescribed by the fuel standard EN 590 for modern (petro)diesel engines. Catalyzed by a Pd/Ru system, RME undergoes isomerizing metathesis in a stream of ethylene gas, leading to a defined olefin, monoester, and diester blend. This innovative refining concept requires negligible energy input (60°C) and no solvents and does not produce waste. It demonstrates that the pressing challenge of increasing the fraction of renewables in engine fuel may be addressed purely chemically rather than by motor engineering. PMID:28630908

  18. Biofuel by isomerizing metathesis of rapeseed oil esters with (bio)ethylene for use in contemporary diesel engines.

    PubMed

    Pfister, Kai F; Baader, Sabrina; Baader, Mathias; Berndt, Silvia; Goossen, Lukas J

    2017-06-01

    Rapeseed oil methyl ester (RME) and (bio)ethylene are converted into biofuel with an evenly rising boiling point curve, which fulfills the strict boiling specifications prescribed by the fuel standard EN 590 for modern (petro)diesel engines. Catalyzed by a Pd/Ru system, RME undergoes isomerizing metathesis in a stream of ethylene gas, leading to a defined olefin, monoester, and diester blend. This innovative refining concept requires negligible energy input (60°C) and no solvents and does not produce waste. It demonstrates that the pressing challenge of increasing the fraction of renewables in engine fuel may be addressed purely chemically rather than by motor engineering.

  19. Influence of High Temperature and Duration of Heating on the Sunflower Seed Oil Properties for Food Use and Bio-diesel Production.

    PubMed

    Giuffrè, Angelo Maria; Capocasale, Marco; Zappia, Clotilde; Poiana, Marco

    2017-01-01

    Two important problems for the food industry are oil oxidation and oil waste after frying. Sunflower seed oil is one of the vegetable oils most commonly used in the food industry. Two variables were applied to the low oleic sunflower seed oil in this work i.e. heating temperature (180-210-240°C) and time of heating (15-30-60-120 minutes), to study from the edible point of view the variations of its physico-chemical properties. After 120 minutes heating at 240°C the following was found: refractive index (1.476), free acidity (0.35%), K232 (2.87), K270 (3.71), antiradical activity (45.90% inhibition), total phenols (523 mg kg -1 ), peroxide value (17.00 meq kg -1 ), p-anisidine value (256.8) and Totox (271.7), all of which showed a constant deterioration. In relation to the use as a feedstock for bio-diesel production, after 120 minutes heating at 240℃ the following was found: acid value 0.70 mg KOH g -1 oil, iodine value 117.83 g I 2 100 g -1 oil, oil stability index 0.67 h, kinematic viscosity (at 40°C) 77.85 mm 2 s -1 , higher heating value 39.86 MJ kg -1 , density 933.34 kg/m 3 and cetane number 67.04. The parameters studied in this work were influenced, in different ways, by the applied variables. Heating temperature between 180 and 210°C and 120 min heating duration were found to be the most appropriate conditions for sunflower seed oil both from the deep frying point of view and from a subsequent use as feedstock for bio-diesel production. In light of the vegetable oils' International standards for an edible use and for a bio-diesel production, findings of this work can be used to set heating temperature and heating duration to preserve as long possible the physico-chemical properties of a low oleic sunflower seed oil for both its edible use as a fat during cooking and for its re-use after frying.

  20. Experimental Investigations on Conventional and Semi-Adiabatic Diesel Engine Using Simarouba Biodiesel as Fuel

    NASA Astrophysics Data System (ADS)

    Ravi, M. U.; Reddy, C. P.; Ravindranath, K.

    2013-04-01

    In view of fast depletion of fossil fuels and the rapid rate at which the fuel consumption is taking place all over the world, scientists are searching for alternate fuels for maintaining the growth industrially and economically. Hence search for alternate fuel(s) has become imminent. Out of the limited options for internal combustion engines, the bio diesel fuel appears to be the best. Many advanced countries are implementing several biodiesel initiatives and developmental programmes in order to become self sufficient and reduce the import bills. Biodiesel is biodegradable and renewable fuel with the potential to enhance the performance and reduce engine exhaust emissions. This is due to ready usage of existing diesel engines, fuel distribution pattern, reduced emission profiles, and eco-friendly properties of biodiesel. Simarouba biodiesel (SBD), the methyl ester of Simarouba oil is one such alternative fuel which can be used as substitute to conventional petro-diesel. The present work involves experimental investigation on the use of SBD blends as fuel in conventional diesel engine and semi-adiabatic diesel engine. The oil was triple filtered to eliminate particulate matter and then transesterified to obtain biodiesel. The project envisaged aims at conducting analysis of diesel with SBD blends (10, 20, 30 and 40 %) in conventional engine and semi-adiabatic engine. Also it was decided to vary the injection pressure (180, 190 and 200 bar) and observe its effect on performance and also suggest better value of injection pressure. The engine was made semi adiabatic by coating the piston crown with partially stabilized zirconia (PSZ). Kirloskar AV I make (3.67 kW) vertical, single cylinder, water cooled diesel engine coupled to an eddy current dynamometer with suitable measuring instrumentation/accessories used for the study. Experiments were initially carried out using pure diesel fuel to provide base line data. The test results were compared based on the performance

  1. Using mobile distributed pyrolysis facilities to deliver a forest residue resource for bio-fuel production

    NASA Astrophysics Data System (ADS)

    Brown, Duncan

    Distributed mobile conversion facilities using either fast pyrolysis or torrefaction processes can be used to convert forest residues to more energy dense substances (bio-oil, bio-slurry or torrefied wood) that can be transported as feedstock for bio-fuel facilities. All feedstock are suited for gasification, which produces syngas that can be used to synthesise petrol or diesel via Fischer-Tropsch reactions, or produce hydrogen via water gas shift reactions. Alternatively, the bio-oil product of fast pyrolysis may be upgraded to produce petrol and diesel, or can undergo steam reformation to produce hydrogen. Implementing a network of mobile facilities reduces the energy content of forest residues delivered to a bio-fuel facility as mobile facilities use a fraction of the biomass energy content to meet thermal or electrical demands. The total energy delivered by bio-oil, bio-slurry and torrefied wood is 45%, 65% and 87% of the initial forest residue energy content, respectively. However, implementing mobile facilities is economically feasible when large transport distances are required. For an annual harvest of 1.717 million m3 (equivalent to 2000 ODTPD), transport costs are reduced to less than 40% of the total levelised delivered feedstock cost when mobile facilities are implemented; transport costs account for up to 80% of feedstock costs for conventional woodchip delivery. Torrefaction provides the lowest cost pathway of delivering a forest residue resource when using mobile facilities. Cost savings occur against woodchip delivery for annual forest residue harvests above 2.25 million m3 or when transport distances greater than 250 km are required. Important parameters that influence levelised delivered costs of feedstock are transport distances (forest residue spatial density), haul cost factors, thermal and electrical demands of mobile facilities, and initial moisture content of forest residues. Relocating mobile facilities can be optimised for lowest cost

  2. Green engineering: Green composite material, biodiesel from waste coffee grounds, and polyurethane bio-foam

    NASA Astrophysics Data System (ADS)

    Cheng, Hsiang-Fu

    In this thesis we developed several ways of producing green materials and energy resources. First, we developed a method to fabricate natural fibers composites, with the purpose to develop green textile/woven composites that could potentially serve as an alternative to materials derived from non-renewable sources. Flax and hemp fabrics were chosen because of their lightweight and exceptional mechanical properties. To make these textile/woven composites withstand moist environments, a commercially available marine resin was utilized as a matrix. The tensile, three-point bending, and edgewise compression strengths of these green textile/woven composites were measured using ASTM protocols. Secondly, we developed a chemical procedure to obtain oil from waste coffee grounds; we did leaching and liquid extractions to get liquid oil from the solid coffee. This coffee oil was used to produce bio-diesel that could be used as a substitute for petroleum-based diesel. Finally, polyurethane Bio-foam formation utilized glycerol that is the by-product from the biodiesel synthesis. A chemical synthesis procedure from the literature was used as the reference system: a triol and isocynate are mixed to produce polyurethane foam. Moreover, we use a similar triol, a by-product from bio-diesel synthesis, to reproduce polyurethane foam.

  3. Implementation of direct LSC method for diesel samples on the fuel market.

    PubMed

    Krištof, Romana; Hirsch, Marko; Kožar Logar, Jasmina

    2014-11-01

    The European Union develops common EU policy and strategy on biofuels and sustainable bio-economy through several documents. The encouragement of biofuel's consumption is therefore the obligation of each EU member state. The situation in Slovenian fuel market is presented and compared with other EU countries in the frame of prescribed values from EU directives. Diesel is the most common fuel for transportation needs in Slovenia. The study was therefore performed on diesel. The sampling net was determined in accordance with the fuel consumption statistics of the country. 75 Sampling points were located on different types of roads. The quantity of bio-component in diesel samples was determined by direct LSC method through measurement of C-14 content. The measured values were in the range from 0 up to nearly 6 mass percentage of bio-component in fuel. The method has proved to be appropriate, suitable and effective for studies on the real fuel market. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. A critical assessment of studies on the carcinogenic potential of diesel exhaust.

    PubMed

    Hesterberg, Thomas W; Bunn, William B; Chase, Gerald R; Valberg, Peter A; Slavin, Thomas J; Lapin, Charles A; Hart, Georgia A

    2006-10-01

    After decades of research involving numerous epidemiologic studies and extensive investigations in laboratory animals, a causal relationship between diesel exhaust (DE) exposure and lung cancer has not been conclusively demonstrated. Epidemiologic studies of the transportation industry (trucking, busing, and railroad) show a small elevation in lung cancer incidence (relative risks [RRs] generally below 1.5), but a dose response for DE is lacking. The studies are also limited by a lack of quantitative concurrent exposure data and inadequate or lack of controls for potential confounders, particularly tobacco smoking. Furthermore, prior to dieselization, similar elevations in lung cancer incidence have been reported for truck drivers, and in-cab diesel particulate matter (DPM) exposures of truck drivers were comparable to ambient highway exposures. Taken together, these findings suggest that an unidentified occupational agent or lifestyle factor might be responsible for the low elevations in lung cancer reported in the transportation studies. In contrast, underground miners, many of whom experience the highest occupational DPM exposures, generally do not show elevations in lung cancer. Laboratory studies must be interpreted with caution with respect to predicting the carcinogenic potential of DE in humans. Tumors observed in rats following lifetime chronic inhalation of very high levels of DPM may be attributed to species-specific overload mechanisms that lack relevance to humans. Increased tumor incidence was not observed in other species (hamsters or mice) exposed to DPM at very high levels or in rats exposed at lower levels (

  5. Potential of Diesel Engines, Fuels and Lubrication Technology

    DOT National Transportation Integrated Search

    1980-03-01

    The chemical and physical properties of diesel fuel are reviewed along with their relationships to the fuel economy and emissions of diesel powered automobiles and light trucks. The fuels considered include both conventional and alternative diesel fu...

  6. Joint BioEnergy Institute

    ScienceCinema

    Keasling, Jay; Simmons, Blake; Tartaglino, Virginia; Baidoo, Edward; Kothari, Ankita

    2018-05-11

    The Joint BioEnergy Institute (JBEI) is a U.S. Department of Energy (DOE) Bioenergy Research Center dedicated to developing advanced biofuels—liquid fuels derived from the solar energy stored in plant biomass that can replace gasoline, diesel and jet fuels.

  7. Influence of bio-additives on combustion of liquid fuels

    NASA Astrophysics Data System (ADS)

    Patsch, Marek; Durčanský, Peter

    2016-06-01

    In this contribution there are analyses of the course of the pressure curves, which were measured in the diesel engine MD UR IV, which is often used in cogeneration units. The results of the analyses confront the properties and quality of fuels. The measuring was realized with a constant rotation speed of the engine and by using different fuels. The fuels were pure diesel fuels and diesel fuel with bio-additives of hydrogenate RO (rape oil), FAME, and bioethanol.

  8. Tailpipe emissions and engine performance of a light-duty diesel engine operating on petro- and bio-diesel fuel blends.

    DOT National Transportation Integrated Search

    2014-06-01

    This report summarizes the experimental apparatus developed in the Transportation Air Quality Laboratory (TAQ Lab) at the University of Vermont to compare light-duty diesel engine performance and exhaust emissions when operating on petroleum diesel (...

  9. A perspective on the potential development of environmentally acceptable light-duty diesel vehicles.

    PubMed Central

    Hammerle, R; Schuetzle, D; Adams, W

    1994-01-01

    Between 1979 and 1985, an international technical focus was placed upon potential human health effects associated with exposure to diesel emissions. A substantial data base was developed on the composition of diesel emissions; the fate of these emissions in the atmosphere; and the effects of whole particles and their chemical constituents on microorganisms, cells, and animals. Since that time, a number of significant developments have been made in diesel engine technology that require a new look at the future acceptability of introducing significant numbers of light-duty diesel automobiles into the European and American markets. Significant engineering improvements have been made in engine design, catalysts, and traps. As a result, particle emissions and particle associated organic emissions have been reduced by about 10 and 30 times, respectively, during the past 10 years. Research studies to help assess the environmental acceptability of these fuel-efficient engines include the development of an emissions data base for current and advanced diesel engines, the effect of diesel emissions on urban ozone formation and atmospheric particle concentrations, the effect of fuel composition, e.g., lower sulfur and additives on emissions, animal inhalation toxicology studies, and fundamental molecular biology studies. PMID:7529704

  10. Characterization and degradation potential of diesel-degrading bacterial strains for application in bioremediation.

    PubMed

    Balseiro-Romero, María; Gkorezis, Panagiotis; Kidd, Petra S; Van Hamme, Jonathan; Weyens, Nele; Monterroso, Carmen; Vangronsveld, Jaco

    2017-10-03

    Bioremediation of polluted soils is a promising technique with low environmental impact, which uses soil organisms to degrade soil contaminants. In this study, 19 bacterial strains isolated from a diesel-contaminated soil were screened for their diesel-degrading potential, biosurfactant (BS) production, and biofilm formation abilities, all desirable characteristics when selecting strains for re-inoculation into hydrocarbon-contaminated soils. Diesel-degradation rates were determined in vitro in minimal medium with diesel as the sole carbon source. The capacity to degrade diesel range organics (DROs) of strains SPG23 (Arthobacter sp.) and PF1 (Acinetobacter oleivorans) reached 17-26% of total DROs after 10 days, and 90% for strain GK2 (Acinetobacter calcoaceticus). The amount and rate of alkane degradation decreased significantly with increasing carbon number for strains SPG23 and PF1. Strain GK2, which produced BSs and biofilms, exhibited a greater extent, and faster rate of alkane degradation compared to SPG23 and PF1. Based on the outcomes of degradation experiments, in addition to BS production, biofilm formation capacities, and previous genome characterizations, strain GK2 is a promising candidate for microbial-assisted phytoremediation of diesel-contaminated soils. These results are of particular interest to select suitable strains for bioremediation, not only presenting high diesel-degradation rates, but also other characteristics which could improve rhizosphere colonization.

  11. Potential gases emissions from the combustion of municipal solid waste by bio-drying.

    PubMed

    Zhang, Dong-Qing; He, Pin-Jing; Shao, Li-Ming

    2009-09-15

    One aerobic and two combined hydrolytic-aerobic processes were set up to investigate the influence of bio-drying on the potential emissions of combustion gases and the quantitative relationships of potential emissions with organics degradation. Results showed that the bio-drying would result in the increase of the HCl and SO(2) emissions and potential for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) formation, but the decrease of NO(x) emissions in the combustion. The potential emissions of combustion gases were correlated with organics degradation (correlation coefficient, r=0.67 for HCl, r=0.96 for SO(2), r=0.91 for PCDD/Fs and r=-0.60 for NO(x)). Interestingly, the total emissions of combustion gases based on input waste could be minimized by bio-drying. The bio-drying caused a reduction of NO(x) emissions but a negligible variation of total emissions of HCl and SO(2) as well as the potential for total PCDD/Fs formation. Moreover, the bio-drying could significantly improve the ratio of gas emissions to low heating values. The mixed waste after bio-drying was more favorable for combustion and the combined process with insufficient aeration during the hydrolytic stage was proposed for the bio-drying operation.

  12. Effect of dilution and ash supplement on the bio-methane potential of palm oil mill effluent (POME)

    NASA Astrophysics Data System (ADS)

    Jijai, Sunwanee; Muleng, Saina; Siripatana, Chairat

    2017-08-01

    This study aimed to evaluate the bio-methane potential of POME at different dilutions (100, 80, 60, 40, and 20 percent of initial POME) and different pH dues to different levels of ash supplement. Five different amounts of ash were added to digesters (0, 2, 4, 6, and 8 grams of ash were added to 170 ml of POME respectively). The digesters were operated in batch anaerobic digestion systems at room temperature (28-30 °C) and the experiments were performed in duplicate manner. The results showed that POME without dilution gave highest cumulative biogas (950 ml). However, 80% dilution from original POME gave the highest methane yield (45.83 mL CH4/ gCODadded or 103.13 mL CH4/ gCODremoved). Finally, the results of experiment 2, this adding ash into POME increased pH as well as enhanced the biogas production. It was found that adding ash at the ash:POME ratio of 2 g: 170 ml gave the highest both the cumulative biogas and methane yield (1,520 mL and 218.79 mL CH4/ gCODremoved respectively). The addition of ash in the raw waste of POME gave the pH in the range of criteria and highest bio-methane potential. The modified Gompertz equation, Schnute as well as Monod kinetic models were used to compare the data from the experiments. It was found that the factors that affected included, the bio-methane production and the kinetic parameters (the maximum specific methane production rates (Rm ml/day) and the methane production potential (P, mL)), initial COD, nutrients, levels of dilution, and initial pH (by adding different level of ash). However, λ (lag phase period) was not affected by initial COD and other factors. While Monod kinetics provides valuable insight in explaining what could happen behind the systematic trends.

  13. Comparison of the toxicity of diesel exhaust produced by bio- and fossil diesel combustion in human lung cells in vitro

    NASA Astrophysics Data System (ADS)

    Steiner, Sandro; Czerwinski, Jan; Comte, Pierre; Popovicheva, Olga; Kireeva, Elena; Müller, Loretta; Heeb, Norbert; Mayer, Andreas; Fink, Alke; Rothen-Rutishauser, Barbara

    2013-12-01

    Alternative fuels are increasingly combusted in diesel- and gasoline engines and the contribution of such exhausts to the overall air pollution is on the rise. Recent findings on the possible adverse effects of biodiesel exhaust are contradictive, at least partly resulting from the various fuel qualities, engine types and different operation conditions that were tested. However, most of the studies are biased by undesired interactions between the exhaust samples and biological culture media. We here report how complete, freshly produced exhausts from fossil diesel (B0), from a blend of 20% rapeseed-methyl ester (RME) and 80% fossil diesel (B20) and from pure rapeseed methyl ester (B100) affect a complex 3D cellular model of the human airway epithelium in vitro by exposing the cells at the air-liquid interface. The induction of pro-apoptotic and necrotic cell death, cellular morphology, oxidative stress, and pro-inflammatory responses were assessed. Compared to B0 exhaust, B20 exhaust decreased oxidative stress and pro-inflammatory responses, whereas B100 exhaust, depending on exposure duration, decreased oxidative stress but increased pro-inflammatory responses. The effects are only very weak and given the compared to fossil diesel higher ecological sustainability of biodiesel, it appears that - at least RME - can be considered a valuable alternative to pure fossil diesel.

  14. Preliminary assessment of Malaysian micro-algae strains for the production of bio jet fuel

    NASA Astrophysics Data System (ADS)

    Chen, J. T.; Mustafa, E. M.; Vello, V.; Lim, P.; Nik Sulaiman, N. M.; Majid, N. Abdul; Phang, S.; Tahir, P. Md.; Liew, K.

    2016-10-01

    Malaysia is the main hub in South-East Asia and has one of the highest air traffic movements in the region. Being rich in biodiversity, Malaysia has long been touted as country rich in biodiversity and therefore, attracts great interests as a place to setup bio-refineries and produce bio-fuels such as biodiesel, bio-petrol, green diesel, and bio-jet fuel Kerosene Jet A-1. Micro-algae is poised to alleviate certain disadvantages seen in first generation and second generation feedstock. In this study, the objective is to seek out potential micro-algae species in Malaysia to determine which are suitable to be used as the feedstock to enable bio-jet fuel production in Malaysia. From 79 samples collected over 30 sites throughout Malaysia, six species were isolated and compared for their biomass productivity and lipid content. Their lipid contents were then used to derived the require amount of micro-algae biomass to yield 1 kg of certifiable jet fuel via the HEFA process, and to meet a scenario where Malaysia implements a 2% alternative (bio-) jet fuel requirement.

  15. The Impact of Diesel Oil Pollution on the Hydrophobicity and CO2 Efflux of Forest Soils.

    PubMed

    Hewelke, Edyta; Szatyłowicz, Jan; Hewelke, Piotr; Gnatowski, Tomasz; Aghalarov, Rufat

    2018-01-01

    The contamination of soil with petroleum products is a major environmental problem. Petroleum products are common soil contaminants as a result of human activities, and they are causing substantial changes in the biological (particularly microbiological) processes, chemical composition, structure and physical properties of soil. The main objective of this study was to assess the impact of soil moisture on CO 2 efflux from diesel-contaminated albic podzol soils. Two contamination treatments (3000 and 9000 mg of diesel oil per kg of soil) were prepared for four horizons from two forest study sites with different initial levels of soil water repellency. CO 2 emissions were measured using a portable infrared gas analyser (LCpro+, ADC BioScientific, UK) while the soil samples were drying under laboratory conditions (from saturation to air-dry). The assessment of soil water repellency was performed using the water drop penetration time test. An analysis of variance (ANVOA) was conducted for the CO 2 efflux data. The obtained results show that CO 2 efflux from diesel-contaminated soils is higher than efflux from uncontaminated soils. The initially water-repellent soils were found to have a bigger CO 2 efflux. The non-linear relationship between soil moisture content and CO 2 efflux only existed for the upper soil horizons, while for deeper soil horizons, the efflux is practically independent of soil moisture content. The contamination of soil by diesel leads to increased soil water repellency.

  16. Effects of Nano Additives in engine emission Characteristics using Blends of Lemon Balm oil with Diesel

    NASA Astrophysics Data System (ADS)

    Senthil kumar, J.; Ganesan, S.; Sivasaravanan, S.; Padmanabhan, S.; Krishnan, L.; Aniruthan, V. C.

    2017-05-01

    Economic growth in developing countries has led to enormous increase in energy demand. In India the energy demand is increasing at a rate of 6.5% every year. The crude oil demand of country is meet by bring in of about 70%. Thus the energy safety measures have become key issue for our country. Bio diesel an eco-friendly and renewable fuel alternate for diesel has been getting the consideration of researcher’s entire world. The main aim of this paper is to evaluate the engine parameters using blend of pure lemon balm oil with diesel. Also nano Additives is used as a catalyst with blends of bio fuel to enhance the Emission Characteristics of various effective gases like CO2, NOx, CO and UHC with various levels of engine process parameters.

  17. [Polycyclic aromatic hydrocarbons in ultrafine particles of diesel exhaust fumes--the use of ultrafast liquid chromatography].

    PubMed

    Małgorzata Szewczyńska; Małgorzata Pośniak

    2014-01-01

    The article presents the results of the determination of polycyclic aromatic hydrocarbons (PAHs) in the fine par ticles fraction emitted from 3 types of diesel fuels using ultra-high pressure liquid chromatography. Samples of diesel Eco, Verwa and Bio exhaust combustion fumes were generated at the model station which consisted of a diesel engine from the 2007 Diesel TDI 2.0. Personal Cascade Sioutas Impactor (IPCSI) with Teflon filters was used to collect samples of exhaust fume ultrafine particles. PAHs adsorbed on particulate fractions were analyzed by ultra-high pressure liquid chromatography with fluorescence detection (UHPLC/FL). Phenanthrene, fluoranthene, pyrene and chrysene present the highest concentration in the particulate matter emitted by an engine. The total contents of fine particles collected during engine operation on fuels Eco, Verwa and Bio were 134.2 μg/g, 183.8 μg/g and 153.4 μg/g, respectively, which makes 75%, 90% and 83% of the total PAHs, respectively. The highest content of benzo(a)pyrene determined in particles emitted during the combustion of fuels Eco and Bio was 1.5 μg/g and 1 μg/g, respectively. The study of the PAH concentration in the particles of fine fraction below 0.25 μm emitted from different fuels designed for diesel engines indicate that the exhaust gas content of carcinogens, including PAHs deposited on particulates, is still significant, regardless of the fuel. Application of ultrahigh pressure liquid chromatography with fluorescence detection for the analysis ofPAHs in the particles emitted in the fine fraction of diesel exhaust allowed to shorten the analysis time from 35 min to 8 min.

  18. Experimental Investigation of Performance and emission characteristics of Various Nano Particles with Bio-Diesel blend on Di Diesel Engine

    NASA Astrophysics Data System (ADS)

    Karthik, N.; Goldwin Xavier, X.; Rajasekar, R.; Ganesh Bairavan, P.; Dhanseelan, S.

    2017-05-01

    Present study provides the effect of Zinc Oxide (ZnO) and Cerium Oxide (CeO2) nanoparticles additives on the Performance and emission uniqueness of Jatropha. Jatropha blended fuel is prepared by the emulsification technique with assist of mechanical agitator. Nano particles (Zinc Oxide (ZnO)) and Cerium Oxide (CeO2)) mixed with Jatropha blended fuel in mass fraction (100 ppm) with assist of an ultrasonicator. Experiments were conducted in single cylinder constant speed direct injection diesel engine for various test fuels. Performance results revealed that Brake Thermal Efficiency (BTE) of Jatropha blended Cerium Oxide (B20CE) is 3% and 11% higher than Jatropha blended zinc oxide (B20ZO) and Jatropha blended fuel (B20) and 4% lower than diesel fuel (D100) at full load conditions. Emission result shows that HC and CO emissions of Jatropha blended Cerium Oxide (B20CE) are (6%, 22%, 11% and 6%, 15%, 12%) less compared with Jatropha blended Zinc Oxide (B20ZO), diesel (D100) and Jatropha blended fuel (B20) at full load conditions. NOx emissions of Jatropha blended Cerium Oxide is 1 % higher than diesel fuel (D100) and 2% and 5% lower than Jatropha blended Zinc Oxide, and jatropha blended fuel.

  19. The global technical potential of bio-energy in 2050 considering sustainability constraints

    PubMed Central

    Haberl, Helmut; Beringer, Tim; Bhattacharya, Sribas C; Erb, Karl-Heinz; Hoogwijk, Monique

    2010-01-01

    Bio-energy, that is, energy produced from organic non-fossil material of biological origin, is promoted as a substitute for non-renewable (e.g., fossil) energy to reduce greenhouse gas (GHG) emissions and dependency on energy imports. At present, global bio-energy use amounts to approximately 50 EJ/yr, about 10% of humanity's primary energy supply. We here review recent literature on the amount of bio-energy that could be supplied globally in 2050, given current expectations on technology, food demand and environmental targets (‘technical potential’). Recent studies span a large range of global bio-energy potentials from ≈30 to over 1000 EJ/yr. In our opinion, the high end of the range is implausible because of (1) overestimation of the area available for bio-energy crops due to insufficient consideration of constraints (e.g., area for food, feed or nature conservation) and (2) too high yield expectations resulting from extrapolation of plot-based studies to large, less productive areas. According to this review, the global technical primary bio-energy potential in 2050 is in the range of 160–270 EJ/yr if sustainability criteria are considered. The potential of bio-energy crops is at the lower end of previously published ranges, while residues from food production and forestry could provide significant amounts of energy based on an integrated optimization (‘cascade utilization’) of biomass flows. PMID:24069093

  20. 77 FR 59458 - Regulation of Fuels and Fuel Additives: 2013 Biomass-Based Diesel Renewable Fuel Volume

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-27

    ... Consumption A. Demand for Biomass-Based Diesel B. Availability of Feedstocks To Produce 1.28 Billion Gallons of Biodiesel 1. Grease and Rendered Fats 2. Corn Oil 3. Soybean Oil 4. Effects on Food Prices 5. Other Bio-Oils C. Production Capacity D. Consumption Capacity E. Biomass-Based Diesel Distribution...

  1. Cyanobacteria: A Precious Bio-resource in Agriculture, Ecosystem, and Environmental Sustainability

    PubMed Central

    Singh, Jay Shankar; Kumar, Arun; Rai, Amar N.; Singh, Devendra P.

    2016-01-01

    Keeping in view, the challenges concerning agro-ecosystem and environment, the recent developments in biotechnology offers a more reliable approach to address the food security for future generations and also resolve the complex environmental problems. Several unique features of cyanobacteria such as oxygenic photosynthesis, high biomass yield, growth on non-arable lands and a wide variety of water sources (contaminated and polluted waters), generation of useful by-products and bio-fuels, enhancing the soil fertility and reducing green house gas emissions, have collectively offered these bio-agents as the precious bio-resource for sustainable development. Cyanobacterial biomass is the effective bio-fertilizer source to improve soil physico-chemical characteristics such as water-holding capacity and mineral nutrient status of the degraded lands. The unique characteristics of cyanobacteria include their ubiquity presence, short generation time and capability to fix the atmospheric N2. Similar to other prokaryotic bacteria, the cyanobacteria are increasingly applied as bio-inoculants for improving soil fertility and environmental quality. Genetically engineered cyanobacteria have been devised with the novel genes for the production of a number of bio-fuels such as bio-diesel, bio-hydrogen, bio-methane, synga, and therefore, open new avenues for the generation of bio-fuels in the economically sustainable manner. This review is an effort to enlist the valuable information about the qualities of cyanobacteria and their potential role in solving the agricultural and environmental problems for the future welfare of the planet. PMID:27148218

  2. Cyanobacteria: A Precious Bio-resource in Agriculture, Ecosystem, and Environmental Sustainability.

    PubMed

    Singh, Jay Shankar; Kumar, Arun; Rai, Amar N; Singh, Devendra P

    2016-01-01

    Keeping in view, the challenges concerning agro-ecosystem and environment, the recent developments in biotechnology offers a more reliable approach to address the food security for future generations and also resolve the complex environmental problems. Several unique features of cyanobacteria such as oxygenic photosynthesis, high biomass yield, growth on non-arable lands and a wide variety of water sources (contaminated and polluted waters), generation of useful by-products and bio-fuels, enhancing the soil fertility and reducing green house gas emissions, have collectively offered these bio-agents as the precious bio-resource for sustainable development. Cyanobacterial biomass is the effective bio-fertilizer source to improve soil physico-chemical characteristics such as water-holding capacity and mineral nutrient status of the degraded lands. The unique characteristics of cyanobacteria include their ubiquity presence, short generation time and capability to fix the atmospheric N2. Similar to other prokaryotic bacteria, the cyanobacteria are increasingly applied as bio-inoculants for improving soil fertility and environmental quality. Genetically engineered cyanobacteria have been devised with the novel genes for the production of a number of bio-fuels such as bio-diesel, bio-hydrogen, bio-methane, synga, and therefore, open new avenues for the generation of bio-fuels in the economically sustainable manner. This review is an effort to enlist the valuable information about the qualities of cyanobacteria and their potential role in solving the agricultural and environmental problems for the future welfare of the planet.

  3. Functional Group Analysis for Diesel-like Mixing-Controlled Compression Ignition Combustion Blendstocks

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gaspar, Daniel J.; McCormick, Robert L.; Polikarpov, Evgueni

    This report addresses the suitability of hydrocarbon and oxygenate functional groups for use as a diesel-like fuel blending component in an advanced, mixing-controlled, compression ignition combustion engine. The functional groups are chosen from those that could be derived from a biomass feedstock, and represent a full range of chemistries. This first systematic analysis of functional groups will be of value to all who are pursuing new bio-blendstocks for diesel-like fuels.

  4. Performance and emission analysis on blends of diesel, restaurant yellow grease and n-pentanol in direct-injection diesel engine.

    PubMed

    Ravikumar, J; Saravanan, S

    2017-02-01

    Yellow grease from restaurants is typically waste cooking oil (WCO) free from suspended food particles with free fatty acid (FFA) content less than 15%. This study proposes an approach to formulate a renewable, eco-friendly fuel by recycling WCO with diesel (D) and n-pentanol (P) to improve fuel-spray characteristics. Three ternary blends (D50-WCO45-P5, D50-WCO40-P10 and D50-WCO30-P20) were selected based on the stability tests and prepared with an objective to substitute diesel by 50% with up to 45% recycled component (WCO) and up to 20% bio-component (n-pentanol) by volume. The fuel properties of these ternary blends were measured and compared. The emission impacts of these blends on a diesel engine were analysed in comparison with diesel and D50-WCO50 (50% of diesel + 50% of WCO) under naturally articulated and EGR (exhaust gas recirculation) approaches. Doping of n-pentanol showed improved fuel properties when compared to D50-WCO50. Viscosity is reduced up to 45%. Cetane number and density were comparable to that of diesel. Addition of n-pentanol to D50-WCO50 presented improved brake specific fuel consumption (BSFC) for all ternary blends. Brake thermal efficiency (BTE) of D50-WCO30-P20 blend is comparable to diesel due to improved atomization. Smoke opacity reduced, HC emissions increased and CO emissions remained unchanged with doping n-pentanol in the WCO. NOx emission increases with increase in n-pentanol and remained lower than diesel and all load conditions. However, NOx can be decreased by up to threefold using EGR. By adopting this approach, WCO can be effectively reused as a clean energy source by negating environmental hazards before and after its use in diesel engines, instead of being dumped into sewers and landfills.

  5. Effects of three biodiesels and a low sulfur diesel in male rats--a pilot 4-week oral study.

    PubMed

    Poon, R; Chu, I; Valli, V E; Graham, L; Yagminas, A; Hollebone, B; Rideout, G; Fingas, M

    2007-10-01

    Because of the accessible and renewable nature of feedstock and the potential for the reduction of harmful combustion emissions and greenhouse gases, biodiesels have received increasing interest as an alternate fuel. Oral exposure to biodiesels is a concern because of contact during refuelling, accidental ingestion and exposure through ground water contamination. Although biodiesels from various feedstock are in use commercially and experimentally, very little is known about their potential adverse effects and no data is available on their potential for ground water contamination. A study was performed on male rats following oral treatment with experimental biodiesels (dissolved in corn oil) derived from canola oil (Bio-C), soy oil (Bio-S) and fish oil (Bio-F), at 500 mg/kg body weight/day, 5 days per week, for 4 weeks. Separate groups of animals were treated with low sulfur diesel (LSD) for comparison purpose, and with corn oil alone to serve as control. The potential for ground water contamination by biodiesels was investigated by the preparation of water-accommodated fractions (WAF) followed by gas chromatographic analysis. WAF from Bio-F and Bio-S was found to have the highest level of dichloromethane extractable materials. Gas chromatographic analysis indicated that the extractable materials from biodiesels contained much higher proportion of C15-C30 materials than LSD. Increased liver weight was observed in animal treated with Bio-C, Bio-S and LSD and decreased thymus weight was found in those treated with Bio-S. Histopathological changes typical of male-rat specific hyaline-droplet nephropathy were detected in kidney tubules of animals treated with LSD, Bio-S and Bio-C. Mild adaptive changes were observed in thyroids of animals treated with LSD, Bio-S and Bio-F. Clinical chemical and biochemical changes were confined to Bio-S and LSD treated rats and included elevation in some hepatic phase-I and phase-II drug metabolizing enzymes and hepatic palmitoyl Co

  6. Potential of Diesel Engine, Emission Technology

    DOT National Transportation Integrated Search

    1980-03-01

    This report surveys diesel engine emission technologies applicable to passenger cars and light trucks. The general design and operating features are presented and discussed. Current and state-of-the-art concepts are reviewed with the focus on control...

  7. Diesel production from lignocellulosic feed: the bioCRACK process

    PubMed Central

    Ritzberger, J.; Schwaiger, N.; Pucher, P.; Siebenhofer, M.

    2017-01-01

    The bioCRACK process is a promising technology for the production of second generation biofuels. During this process, biomass is pyrolized in vacuum gas oil and converted into gaseous, liquid and solid products. In cooperation with the Graz University of Technology, the liquid phase pyrolysis process was investigated by BDI – BioEnergy International AG at an industrial pilot plant, fully integrated in the OMV refinery in Vienna/Schwechat. The influence of various biogenous feedstocks and the influence of the temperature on the product distribution in the temperature range of 350°C to 390°C was studied. It was shown that the temperature has a major impact on the product formation. With rising temperature, the fraction of liquid products, namely liquid CHO-products, reaction water and hydrocarbons, increases and the fraction of biochar decreases. At 390°C, 39.8 wt% of biogenous carbon was transferred into a crude hydrocarbon fractions. The type of lignocellulosic feedstock has a minor impact on the process. The biomass liquefaction concept of the bioCRACK process was in pilot scale compatible with oil refinery processes. PMID:29291098

  8. Fuel Property Determination of Biodiesel-Diesel Blends By Terahertz Spectrum

    NASA Astrophysics Data System (ADS)

    Zhao, Hui; Zhao, Kun; Bao, Rima

    2012-05-01

    The frequency-dependent absorption characteristics of biodiesel and its blends with conventional diesel fuel have been researched in the spectral range of 0.2-1.5 THz by the terahertz time-domain spectroscopy (THz-TDS). The absorption coefficient presented a regular increasing with biodiesel content. A nonlinear multivariate model that correlating cetane number and solidifying point of bio-diesel blends with absorption coefficient has been established, making the quantitative analysis of fuel properties simple. The results made the cetane number and solidifying point prediction possible by THz-TDS technology and indicated a bright future in practical application.

  9. FROM FIELD TO FUEL TANK: EXPLORING THE IMPLEMENTATION OF BIODIESEL AS A SUSTAINABLE ALTERNATIVE TO PETROLEUM DIESEL IN OREGON'S WILLAMETTE VALLEY

    EPA Science Inventory

    The technical challenge is to demonstrate the feasibility of the production and use of a renewable bio-based diesel fuel as an alternative to petroleum-based diesel. The innovative objectives of the project are to:

    • Demonstrate the engineering and economic feasib...

  10. Effects of Aftermarket Control Technologies on Gas and Particle Phase Oxidative Potential from Diesel Engine Emissions.

    PubMed

    Pavlovic, Jelica; Holder, Amara L; Yelverton, Tiffany L B

    2015-09-01

    Particulate matter (PM) originating from diesel combustion is a public health concern due to its association with adverse effects on respiratory and cardiovascular diseases and lung cancer. This study investigated emissions from three stationary diesel engines (gensets) and varying power output (230 kW, 400 kW, and 600 kW) at 50% and 90% load to determine concentrations of gaseous (GROS) and PM reactive oxygen species (PMROS). In addition, the influence of three modern emission control technologies on ROS emissions was evaluated: active and passive diesel particulate filters (A-DPF and P-DPF) and a diesel oxidation catalyst (DOC). PMROS made up 30-50% of the total ROS measured without aftermarket controls. All applied controls removed PMROS by more than 75% on average. However, the oxidative potential of PM downstream of these devices was not diminished at the same rate and particles surviving the A-PDF had an even higher oxidative potential on a per PM mass basis compared to the particles emitted by uncontrolled gensets. Further, the GROS as compared to PMROS emissions were not reduced with the same efficiency (<36%). GROS concentrations were highest with the DOC in use, indicating continued formation of GROS with this control. Correlation analyses showed that PMROS and to a lesser extent GROS have a good correlation with semivolatile organic carbon (OC1) subfraction. In addition, results suggest that chemical composition, rather than PM size, is responsible for differences in the PM oxidative potential.

  11. Characterization and Catalytic Upgrading of Crude Bio-oil Produced by Hydrothermal Liquefaction of Swine Manure and Pyrolysis of Biomass

    NASA Astrophysics Data System (ADS)

    Cheng, Dan

    The distillation curve of crude bio-oil from glycerol-assisted hydrothermal liquefaction of swine manure was measured using an advanced distillation apparatus. The crude bio-oil had much higher distillation temperatures than diesel and gasoline and was more distillable than the bio-oil produced by the traditional liquefaction of swine manure and the pyrolysis of corn stover. Each 10% volumetric fraction was analyzed from aspects of its chemical compositions, chemical and physical properties. The appearance of hydrocarbons in the distillates collected at the temperature of 410.9°C and above indicated that the thermal cracking at a temperature from 410°C to 500°C may be a proper approach to upgrade the crude bio-oil produced from the glycerol-assisted liquefaction of swine manure. The effects of thermal cracking conditions including reaction temperature (350-425°C), retention time (15-60 min) and catalyst loadings (0-10 wt%) on the yield and quality of the upgraded oil were analyzed. Under the optimum thermal cracking conditions at 400°C, a catalyst loading of 5% by mass and the reaction time of 30 min, the yield of bio-oil was 46.14% of the mass of the crude bio-oil and 62.5% of the energy stored in the crude bio-oil was recovered in the upgraded bio-oil. The upgraded bio-oil with a heating value of 41.4 MJ/kg and viscosity of 3.6 cP was comparable to commercial diesel. In upgrading crude bio-oil from fast pyrolysis, converting organic acids into neutral esters is significant and can be achieved by sulfonated activated carbon/bio-char developed from fermentation residues. Acitivated carbon and bio-char were sulfonated by concentrated sulfuric acid at 150°C for 18 h. Sulfonation helped activated carbon/bio-char develop acid functional groups. Sulfonated activated carbon with BET surface area of 349.8 m2/g, was effective in converting acetic acid. Acetic acid can be effectively esterified by sulfonated activated carbon (5 wt%) at 78°C for 60 min with the

  12. Dependence of the pour point of diesel fuels on the properties of the initial components

    NASA Technical Reports Server (NTRS)

    Ostashov, V. M.; Bobrovskiy, S. A.

    1979-01-01

    An analytical expression is obtained for the dependence of the pour point of diesel fuels on the pour point and weight relationship of the initial components. For determining the pour point of a multicomponent fuel mixture, it is assumed that the mixture of two components has the pour point of a separate equivalent component, then calculating the pour point of this equivalent component mixed with a third component, etc.

  13. Reducing emissions of persistent organic pollutants from a diesel engine by fueling with water-containing butanol diesel blends.

    PubMed

    Chang, Yu-Cheng; Lee, Wen-Jhy; Yang, Hsi-Hsien; Wang, Lin-Chi; Lu, Jau-Huai; Tsai, Ying I; Cheng, Man-Ting; Young, Li-Hao; Chiang, Chia-Jui

    2014-05-20

    The manufacture of water-containing butanol diesel blends requires no excess dehydration and surfactant addition. Therefore, compared with the manufacture of conventional bio-alcohols, the energy consumption for the manufacture of water-containing butanol diesel blends is reduced, and the costs are lowered. In this study, we verified that using water-containing butanol diesel blends not only solves the tradeoff problem between nitrogen oxides (NOx) and particulate matter emissions from diesel engines, but it also reduces the emissions of persistent organic pollutants (POPs), including polycyclic aromatic hydrocarbons, polychlorinated dibenzo-p-dioxins and dibenzofurans, polychlorinated biphenyls, polychlorinated diphenyl ethers, polybrominated dibenzo-p-dioxins and dibenzofurans, polybrominated biphenyls and polybrominated diphenyl ethers. After using blends of B2 with 10% and 20% water-containing butanol, the POP emission factors were decreased by amounts in the range of 22.6%-42.3% and 38.0%-65.5% on a mass basis, as well as 18.7%-78.1% and 51.0%-84.9% on a toxicity basis. The addition of water-containing butanol introduced a lower content of aromatic compounds and most importantly, lead to more complete combustion, thus resulting in a great reduction in the POP emissions. Not only did the self-provided oxygen of butanol promote complete oxidation but also the water content in butanol diesel blends could cause a microexplosion mechanism, which provided a better turbulence and well-mixed environment for complete combustion.

  14. Dielectrophoretic separation of Bacillus subtilis spores from environmental diesel particles.

    PubMed

    Fatoyinbo, Henry O; Hughes, Michael P; Martin, Stacey P; Pashby, Paul; Labeed, Fatima H

    2007-01-01

    Isolation of pathogenic bacteria from non-biological material of similar size is a vital sample preparation step in the identification of such organisms, particularly in the context of detecting bio-terrorist attacks. However, many detection methods are impeded by particulate contamination from the environment such as those from engine exhausts. In this paper we use dielectrophoresis--the induced motion of particles in non-uniform fields--to successfully remove over 99% of diesel particulates acquired from environmental samples, whilst letting bacterial spores of B. subtilis pass through the chamber largely unimpeded. We believe that such a device has tremendous potential as a precursor to a range of detection methods, improving the signal-to-noise ratio and ultimately improving detection rates.

  15. Genotoxic potential and heart rate disorders in the Mediterranean mussel Mytilus galloprovincialis exposed to Superdispersant-25 and dispersed diesel oil.

    PubMed

    Martinović, Rajko; Kolarević, Stoimir; Kračun-Kolarević, Margareta; Kostić, Jovana; Marković, Sandra; Gačić, Zoran; Kljajić, Zoran; Vuković-Gačić, Branka

    2015-07-01

    The effects of ex situ exposure of Mytilus galloprovincialis to Superdispersant-25 (S-25), diesel oil and dispersed diesel oil mixtures were studied by the impact on level of DNA damage in haemocytes (comet assay) and the cardiac activity patterns of mussels. Specimens were exposed for 72 h in a static system to diesel oil (100 μL/L and 1 mL/L), S-25 (5 and 50 μL/L), and dispersed diesel oil mixtures M1 (diesel oil 100 μL/L + S-25 5 μL/L) and M2 (diesel oil 1 mL/L + S-25 50 μL/L). For positive control 40 μM CdCl2 was used. The comet assay results indicated genotoxic potential of S-25 while the effects of diesel oil alone were not observed. The highest response was detected for M1 while the effects of M2 were not detected. The heart rate disorders were recorded for the diesel oil (1 mL/L), S-25 (50 μL/L) and both dispersed diesel oil mixtures. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. 78 FR 38027 - Novo BioPower LLC; Supplemental Notice That Initial Market-Based Rate Filing Includes Request for...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-25

    ... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. ER13-1665-000] Novo BioPower LLC; Supplemental Notice That Initial Market-Based Rate Filing Includes Request for Blanket Section 204 Authorization This is a supplemental notice in the above-referenced proceeding, of Novo BioPower...

  17. Evaluation of carcinogenic hazard of diesel engine exhaust needs to consider revolutionary changes in diesel technology.

    PubMed

    McClellan, Roger O; Hesterberg, Thomas W; Wall, John C

    2012-07-01

    Diesel engines, a special type of internal combustion engine, use heat of compression, rather than electric spark, to ignite hydrocarbon fuels injected into the combustion chamber. Diesel engines have high thermal efficiency and thus, high fuel efficiency. They are widely used in commerce prompting continuous improvement in diesel engines and fuels. Concern for health effects from exposure to diesel exhaust arose in the mid-1900s and stimulated development of emissions regulations and research to improve the technology and characterize potential health hazards. This included epidemiological, controlled human exposure, laboratory animal and mechanistic studies to evaluate potential hazards of whole diesel exhaust. The International Agency for Research on Cancer (1989) classified whole diesel exhaust as - "probably carcinogenic to humans". This classification stimulated even more stringent regulations for particulate matter that required further technological developments. These included improved engine control, improved fuel injection system, enhanced exhaust cooling, use of ultra low sulfur fuel, wall-flow high-efficiency exhaust particulate filters, exhaust catalysts, and crankcase ventilation filtration. The composition of New Technology Diesel Exhaust (NTDE) is qualitatively different and the concentrations of particulate constituents are more than 90% lower than for Traditional Diesel Exhaust (TDE). We recommend that future reviews of carcinogenic hazards of diesel exhaust evaluate NTDE separately from TDE. Copyright © 2012 Elsevier Inc. All rights reserved.

  18. Evaluation of humic fractions potential to produce bio-oil through catalytic hydroliquefaction.

    PubMed

    Lemée, L; Pinard, L; Beauchet, R; Kpogbemabou, D

    2013-12-01

    Humic substances were extracted from biodegraded lignocellulosic biomass (LCBb) and submitted to catalytic hydroliquefaction. The resulting bio-oils were compared with those of the initial biomass. Compared to fulvic and humic acids, humin presented a high conversion rate (74 wt.%) and the highest amount of liquid fraction (66 wt.%). Moreover it represented 78% of LCBb. Humin produced 43 wt.% of crude oil and 33 wt.% of hexane soluble fraction containing hydrocarbons which is a higher yield than those from other humic substances as well as from the initial biomass. Hydrocarbons were mainly aromatics, but humin produces the highest amount of aliphatics. Considering the quantity, the quality and the molecular composition of the humic fractions, a classification of the potential of the latter to produce fuel using hydroliquefaction process can be assess: Hu>AF>AH. The higher heating value (HHV) and oxygen content of HSF from humin were fully compatible with biofuel characteristics. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Experimental assessment of the potential to decrease diesel NOx emissions beyond minimum requirements for Euro 6 Real Drive Emissions (RDE) compliance.

    PubMed

    Triantafyllopoulos, Georgios; Katsaounis, Dimitrios; Karamitros, Dimitrios; Ntziachristos, Leonidas; Samaras, Zissis

    2018-03-15

    The objective of this study was to test the potential for NO x emissions improvements on a typical Euro 6 diesel vehicle, following modifications to its emissions control system, under Real Drive Emissions (RDE) testing conditions. A commercially available car was selected and was first measured in its original configuration according to RDE on the road and an initial conformity factor (CF) of 5.4 was determined. Subsequent engine calibration and installation of a Selective Catalytic Reduction (SCR) device were conducted and tested on a fully transient engine dyno setup, which precisely reproduced the engine operation under the on-road RDE test. The NO x reduction achieved with those upgrades was 90%, leading to a CF of 0.53, with no CO 2 or fuel consumption penalty. These findings demonstrate that diesel vehicles can reach low NO x levels under real world driving conditions, when well-designed modern exhaust aftertreatment components are installed and properly calibrated. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. Variability in Bioreactivity Linked to Changes in Size and Zeta Potential of Diesel Exhaust Particles in Human Immune Cells

    PubMed Central

    Sarkar, Srijata; Zhang, Lin; Subramaniam, Prasad; Lee, Ki-Bum; Garfunkel, Eric; Strickland, Pamela A. Ohman.; Mainelis, Gediminas; Lioy, Paul J.; Tetley, Teresa D.; Chung, Kian Fan; Zhang, Junfeng; Ryan, Mary; Porter, Alex; Schwander, Stephan

    2014-01-01

    Acting as fuel combustion catalysts to increase fuel economy, cerium dioxide (ceria, CeO2) nanoparticles have been used in Europe as diesel fuel additives (Envirox™). We attempted to examine the effects of particles emitted from a diesel engine burning either diesel (diesel exhaust particles, DEP) or diesel doped with various concentrations of CeO2 (DEP-Env) on innate immune responses in THP-1 and primary human peripheral blood mononuclear cells (PBMC). Batches of DEP and DEP-Env were obtained on three separate occasions using identical collection and extraction protocols with the aim of determining the reproducibility of particles generated at different times. However, we observed significant differences in size and surface charge (zeta potential) of the DEP and DEP-Env across the three batches. We also observed that exposure of THP-1 cells and PBMC to identical concentrations of DEP and DEP-Env from the three batches resulted in statistically significant differences in bioreactivity as determined by IL-1β, TNF-α, IL-6, IFN-γ, and IL-12p40 mRNA (by qRT-PCR) and protein expression (by ELISPOT assays). Importantly, bioreactivity was noted in very tight ranges of DEP size (60 to 120 nm) and zeta potential (−37 to −41 mV). Thus, these physical properties of DEP and DEP-Env were found to be the primary determinants of the bioreactivity measured in this study. Our findings also point to the potential risk of over- or under- estimation of expected bioreactivity effects (and by inference of public health risks) from bulk DEP use without taking into account potential batch-to-batch variations in physical (and possibly chemical) properties. PMID:24825358

  1. Adsorption-synergic biodegradation of diesel oil in synthetic seawater by acclimated strains immobilized on multifunctional materials.

    PubMed

    Wang, Xin; Wang, Xuejiang; Liu, Mian; Bu, Yunjie; Zhang, Jing; Chen, Jie; Zhao, Jianfu

    2015-03-15

    Using enrichment culture technique, three isolates marked as ODB-1, ODB-2 and ODB-3, were selected from oil contaminated seawater. 16S rDNA gene sequencing indicated that ODB-1 affiliated with Pseudomonas sp. while ODB-2 and ODB-3 affiliated with Brevundimonas sp. Subsequently, the bacterial cells were immobilized on the surface of expanded graphite (EG), expanded perlite (EP) and bamboo charcoal (BC). Among the three isolates, ODB-1 showed a strong binding to the bio-carriers through extracellular polysaccharides, while ODB-2 and ODB-3 made the adhesion to bio-carrier through direct physical adsorption. The immobilized bacteria exhibited good salinity tolerance compared with the planktonic bacteria. Their total diesel oil removal rates were more than 85% after 6 days' incubation. Adsorption-biodegradation process played an important role in the oil-pollution remediation. EG-bacteria system was treated as a promising remediation method, which achieved nearly 100% removal of diesel oil. Thereinto, over 83% removal of diesel oil owed to biodegradation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Freeman, Charles J.; Jones, Susanne B.; Padmaperuma, Asanga B.

    2013-04-01

    In order to meet U.S. biofuel objectives over the coming decade the conversion of a broad range of biomass feedstocks, using diverse processing options, will be required. Further, the production of both gasoline and diesel biofuels will employ biomass conversion methods that produce wide boiling range intermediate oils requiring treatment similar to conventional refining processes (i.e. fluid catalytic cracking, hydrocracking, and hydrotreating). As such, it is widely recognized that leveraging existing U.S. petroleum refining infrastructure is key to reducing overall capital demands. This study examines how existing U.S. refining location, capacities and conversion capabilities match in geography and processing capabilitiesmore » with the needs projected from anticipated biofuels production.« less

  3. Role of fuel additives on reduction of NOX emission from a diesel engine powered by camphor oil biofuel.

    PubMed

    Subramanian, Thiyagarajan; Varuvel, Edwin Geo; Ganapathy, Saravanan; Vedharaj, S; Vallinayagam, R

    2018-06-01

    The present study intends to explore the effect of the addition of fuel additives with camphor oil (CMO) on the characteristics of a twin-cylinder compression ignition (CI) engine. The lower viscosity and boiling point of CMO when compared to diesel could improve the fuel atomization, evaporation, and air/fuel mixing process. However, the lower cetane index of CMO limits its use as a drop in fuel for diesel in CI engine. In general, NO X emission increases for less viscous and low cetane (LVLC) fuels due to pronounced premixed combustion phase. To improve the ignition characteristics and decrease NO X emissions, fuel additives such as diglyme (DGE)-a cetane enhancer, cumene (CU)-an antioxidant, and eugenol (EU) and acetone (A)-bio-additives, are added 10% by volume with CMO. The engine used for the experimentation is a twin-cylinder tractor engine that runs at a constant speed of 1500 rpm. The engine was operated with diesel initially to attain warm-up condition, which facilitates the operation of neat CMO. At full load condition, brake thermal efficiency (BTE) for CMO is higher (29.6%) than that of diesel (28.1%), while NO X emission is increased by 9.4%. With DGE10 (10% DGE + 90% CMO), the ignition characteristics of CMO are improved and BTE is increased to 31.7% at full load condition. With EU10 (10% EU + 90% CMO) and A10 (10% A + 90% CMO), NO X emission is decreased by 24.6 and 17.8% when compared to diesel, while BTE is comparable to diesel. While HC and CO emission decreased for DGE10 and CU10, they increased for EU10 and A10 when compared to baseline diesel and CMO.

  4. Measuring the Effect of Fuel Structures and Blend Distribution on Diesel Emissions Using Isotope Tracing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cheng, A S; Mueller, C J; Buchholz, B A

    2004-02-10

    Carbon atoms occupying specific positions within fuel molecules can be labeled and followed in emissions. Renewable bio-derived fuels possess a natural uniform carbon-14 ({sup 14}C) tracer several orders of magnitude above petroleum-derived fuels. These fuels can be used to specify sources of carbon in particulate matter (PM) or other emissions. Differences in emissions from variations in the distribution of a fuel component within a blend can also be measured. Using Accelerator Mass Spectrometry (AMS), we traced fuel components with biological {sup 14}C/C levels of 1 part in 10{sup 12} against a {sup 14}C-free petroleum background in PM and CO{sub 2}.more » Different carbon atoms in the ester structure of the diesel oxygenate dibutyl maleate displayed far different propensities to produce PM. Homogeneous cosolvent and heterogeneous emulsified ethanol-in-diesel blends produced significantly different PM despite having the same oxygen content in the fuel. Emulsified blends produced PM with significantly more volatile species. Although ethanol-derived carbon was less likely to produce PM than diesel fuel, it formed non-volatile structures when it resided in PM. The contribution of lubrication oil to PM was determined by measuring an isotopic difference between 100% bio-diesel and the PM it produced. Data produced by the experiments provides validation for combustion models.« less

  5. Continuous Time Level Crossing Sampling ADC for Bio-Potential Recording Systems

    PubMed Central

    Tang, Wei; Osman, Ahmad; Kim, Dongsoo; Goldstein, Brian; Huang, Chenxi; Martini, Berin; Pieribone, Vincent A.

    2013-01-01

    In this paper we present a fixed window level crossing sampling analog to digital convertor for bio-potential recording sensors. This is the first proposed and fully implemented fixed window level crossing ADC without local DACs and clocks. The circuit is designed to reduce data size, power, and silicon area in future wireless neurophysiological sensor systems. We built a testing system to measure bio-potential signals and used it to evaluate the performance of the circuit. The bio-potential amplifier offers a gain of 53 dB within a bandwidth of 200 Hz-20 kHz. The input-referred rms noise is 2.8 µV. In the asynchronous level crossing ADC, the minimum delta resolution is 4 mV. The input signal frequency of the ADC is up to 5 kHz. The system was fabricated using the AMI 0.5 µm CMOS process. The chip size is 1.5 mm by 1.5 mm. The power consumption of the 4-channel system from a 3.3 V supply is 118.8 µW in the static state and 501.6 µW with a 240 kS/s sampling rate. The conversion efficiency is 1.6 nJ/conversion. PMID:24163640

  6. 40 CFR 73.90 - Allowance allocations for small diesel refineries.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Allowance allocations for small diesel... PROGRAMS (CONTINUED) SULFUR DIOXIDE ALLOWANCE SYSTEM Small Diesel Refineries § 73.90 Allowance allocations for small diesel refineries. (a) Initial certification of eligibility. The certifying official of a...

  7. 40 CFR 73.90 - Allowance allocations for small diesel refineries.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Allowance allocations for small diesel... PROGRAMS (CONTINUED) SULFUR DIOXIDE ALLOWANCE SYSTEM Small Diesel Refineries § 73.90 Allowance allocations for small diesel refineries. (a) Initial certification of eligibility. The certifying official of a...

  8. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gangwal, Santosh; Meng, Jiajia; McCabe, Kevin

    Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fastmore » pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.« less

  9. Use of Water-Fuel Mixture in Diesel Engines at Fishing Vessels

    NASA Astrophysics Data System (ADS)

    Klyus, Oleg; Bezyukov, O.

    2017-06-01

    The paper presents the laboratory test results determining physical parameters of fuel mixture made up of petroleum diesel oil, rapeseed oil methyl esters (up to 20%) and water (up to 2.5%). The obtained parameters prove that adding bio-components (rapeseed oil methyl esters) and water to fuel does not result in deterioration of their physical and chemical properties and are comparable to base fuel parameters, namely petroleum diesel oil. The mixture was a subject of bench testing with the use of a self-ignition engine by means of pre-catalytic fuel treatment. The treatment process consisted in fuel - catalytically active material direct contact on the atomizer body. At the comparable operational parameters for the engine, the obtained exhaust gases opacity was lower up to 60% due to the preliminary fuel mixture treatment in relation to the factory-made fuel injection system using petroleum diesel oil.

  10. Toxicological characterization of diesel engine emissions using biodiesel and a closed soot filter

    NASA Astrophysics Data System (ADS)

    Kooter, Ingeborg M.; van Vugt, Marcel A. T. M.; Jedynska, Aleksandra D.; Tromp, Peter C.; Houtzager, Marc M. G.; Verbeek, Ruud P.; Kadijk, Gerrit; Mulderij, Mariska; Krul, Cyrille A. M.

    2011-03-01

    This study was designed to determine the toxicity (oxidative stress, cytotoxicity, genotoxicity) in extracts of combustion aerosols. A typical Euro III heavy truck engine was tested over the European Transient Cycle with three different fuels: conventional diesel EN590, biodiesel EN14214 as B100 and blends with conventional diesel (B5, B10, and B20) and pure plant oil DIN51605 (PPO). In addition application of a (wall flow) diesel particulate filter (DPF) with conventional diesel EN590 was tested. The use of B100 or PPO as a fuel or the DPF reduced particulate matter (PM) mass and numbers over 80%. Similarly, significant reduction in the emission of chemical constituents (EC 90%, (oxy)-PAH 70%) were achieved. No significant changes in nitro-PAH were observed. The use of B100 or PPO led to a NOx increase of about 30%, and no increase for DPF application. The effects of B100, PPO and the DPF on the biological test results vary strongly from positive to negative depending on the biological end point. The oxidative potential, measured via the DTT assay, of the B100 and PPO or DPF emissions is reduced by 95%. The cytotoxicity is increased for B100 by 200%. The measured mutagenicity, using the Ames assay test with TA98 and YG1024 strains of Salmonella typhimurium indicate a dose response for the nitroarene sensitive YG1024 strain for B100 and PPO (fold induction: 1.6). In summary B100 and PPO have good potential for the use as a second generation biofuel resulting in lower PM mass, similar to application of a DPF, but caution should be made due to potential increased toxicity. Besides regulation via mass, the biological reactivity of exhaust emissions of new (bio)fuels and application of new technologies, needs attention. The different responses of different biological tests as well as differences in results between test laboratories underline the need for harmonization of test methods and international cooperation.

  11. A bio-molecular inspired electronic architecture: bio-based device concepts for enhanced sensing (Invited Paper)

    NASA Astrophysics Data System (ADS)

    Woolard, Dwight L.; Luo, Ying; Gelmont, Boris L.; Globus, Tatiana; Jensen, James O.

    2005-05-01

    A biological(bio)-molecular inspired electronic architecture is presented that offers the potential for defining nanoscale sensor platforms with enhanced capabilities for sensing terahertz (THz) frequency bio-signatures. This architecture makes strategic use of integrated biological elements to enable communication and high-level function within densely-packed nanoelectronic systems. In particular, this architecture introduces a new paradigm for establishing hybrid Electro-THz-Optical (ETO) communication channels where the THz-frequency spectral characteristics that are uniquely associated with the embedded bio-molecules are utilized directly. Since the functionality of this architecture is built upon the spectral characteristics of bio-molecules, this immediately allows for defining new methods for enhanced sensing of THz bio-signatures. First, this integrated sensor concept greatly facilitates the collection of THz bio-signatures associated with embedded bio-molecules via interactions with the time-dependent signals propagating through the nanoelectronic circuit. Second, it leads to a new Multi-State Spectral Sensing (MS3) approach where bio-signature information can be collected from multiple metastable state conformations. This paper will also introduce a new class of prototype devices that utilize THz-sensitive bio-molecules to achieve molecular-level sensing and functionality. Here, new simulation results are presented for a class of bio-molecular components that exhibit the prescribed type of ETO characteristics required for realizing integrated sensor platforms. Most noteworthy, this research derives THz spectral bio-signatures for organic molecules that are amenable to photo-induced metastable-state conformations and establishes an initial scientific foundation and design blueprint for an enhanced THz bio-signature sensing capability.

  12. Design and Development of Non-Contact Bio-Potential Electrodes for Pervasive Health Monitoring Applications.

    PubMed

    Portelli, Anthony J; Nasuto, Slawomir J

    2017-01-01

    For the advent of pervasive bio-potential monitoring, it will be necessary to utilize a combination of cheap, quick to apply, low-noise electrodes and compact electronics with wireless technologies. Once available, all electrical activity resulting from the processes of the human body could be actively and constantly monitored without the need for cumbersome application and maintenance. This could significantly improve the early diagnosis of a range of different conditions in high-risk individuals, opening the possibility for new treatments and interventions as conditions develop. This paper presents the design and implementation of compact, non-contact capacitive bio-potential electrodes utilising a low impedance current-to-voltage configuration and a bootstrapped voltage follower, demonstrating results applicable to research applications for capacitive electrocardiography and capacitive electromyography. The presented electrodes use few components, have a small surface area and are capable of acquiring a range of bio-potential signals.

  13. Design and Development of Non-Contact Bio-Potential Electrodes for Pervasive Health Monitoring Applications

    PubMed Central

    Portelli, Anthony J.; Nasuto, Slawomir J.

    2017-01-01

    For the advent of pervasive bio-potential monitoring, it will be necessary to utilize a combination of cheap, quick to apply, low-noise electrodes and compact electronics with wireless technologies. Once available, all electrical activity resulting from the processes of the human body could be actively and constantly monitored without the need for cumbersome application and maintenance. This could significantly improve the early diagnosis of a range of different conditions in high-risk individuals, opening the possibility for new treatments and interventions as conditions develop. This paper presents the design and implementation of compact, non-contact capacitive bio-potential electrodes utilising a low impedance current-to-voltage configuration and a bootstrapped voltage follower, demonstrating results applicable to research applications for capacitive electrocardiography and capacitive electromyography. The presented electrodes use few components, have a small surface area and are capable of acquiring a range of bio-potential signals. PMID:28045439

  14. High-Fidelity Simulations of Electrically-Charged Atomizing Diesel-Type Jets

    NASA Astrophysics Data System (ADS)

    Gaillard, Benoit; Owkes, Mark; van Poppel, Bret

    2015-11-01

    Combustion of liquid fuels accounts for over a third of the energy usage today. Improving efficiency of combustion systems is critical to meet the energy needs while limiting environmental impacts. Additionally, a shift away from traditional fossil fuels to bio-derived alternatives requires fuel injection systems that can atomize fuels with a wide range of properties. In this work, the potential benefits of electrically-charged atomization is investigated using numerical simulations. Particularly, the electrostatic forces on the hydrodynamic jet are quantified and the impact of the forces is analyzed by comparing simulations of Diesel-type jets at realistic flow conditions. The simulations are performed using a state-of-the-art numerical framework that globally conserves mass, momentum, and the electric charge density even at the gas-liquid interface where discontinuities exist.

  15. Bioremediation potential of diesel-contaminated Libyan soil.

    PubMed

    Koshlaf, Eman; Shahsavari, Esmaeil; Aburto-Medina, Arturo; Taha, Mohamed; Haleyur, Nagalakshmi; Makadia, Tanvi H; Morrison, Paul D; Ball, Andrew S

    2016-11-01

    Bioremediation is a broadly applied environmentally friendly and economical treatment for the clean-up of sites contaminated by petroleum hydrocarbons. However, the application of this technology to contaminated soil in Libya has not been fully exploited. In this study, the efficacy of different bioremediation processes (necrophytoremediation using pea straw, bioaugmentation and a combination of both treatments) together with natural attenuation were assessed in diesel contaminated Libyan soils. The addition of pea straw was found to be the best bioremediation treatment for cleaning up diesel contaminated Libyan soil after 12 weeks. The greatest TPH degradation, 96.1% (18,239.6mgkg(-1)) and 95% (17,991.14mgkg(-1)) were obtained when the soil was amended with pea straw alone and in combination with a hydrocarbonoclastic consortium respectively. In contrast, natural attenuation resulted in a significantly lower TPH reduction of 76% (14,444.5mgkg(-1)). The presence of pea straw also led to a significant increased recovery of hydrocarbon degraders; 5.7log CFU g(-1) dry soil, compared to 4.4log CFUg(-1) dry soil for the untreated (natural attenuation) soil. DGGE and Illumina 16S metagenomic analyses confirm shifts in bacterial communities compared with original soil after 12 weeks incubation. In addition, metagenomic analysis showed that original soil contained hydrocarbon degraders (e.g. Pseudoxanthomonas spp. and Alcanivorax spp.). However, they require a biostimulant (in this case pea straw) to become active. This study is the first to report successful oil bioremediation with pea straw in Libya. It demonstrates the effectiveness of pea straw in enhancing bioremediation of the diesel-contaminated Libyan soil. Copyright © 2016 Elsevier Inc. All rights reserved.

  16. Clean-Burning Diesel Engines.

    DTIC Science & Technology

    1986-03-01

    Dietzmann L.R. Smith Engines, Emissions, and Vehicle Research Division Southwest Research Institute San Antonio, Texas Prepared for Belvoir Fuels and...replacing the currently used electric forklift with diesel engine-powered forklifts in handling hazardous materials. Electric -powered forklifts have no...diesel engines considered as potential candidates for forklift vehicles used to handle hazardous materials. The first program was conducted to

  17. Electrifying white biotechnology: engineering and economic potential of electricity-driven bio-production.

    PubMed

    Harnisch, Falk; Rosa, Luis F M; Kracke, Frauke; Virdis, Bernardino; Krömer, Jens O

    2015-03-01

    The production of fuels and chemicals by electricity-driven bio-production (i.e., using electric energy to drive biosynthesis) holds great promises. However, this electrification of white biotechnology is particularly challenging to achieve because of the different optimal operating conditions of electrochemical and biochemical reactions. In this article, we address the technical parameters and obstacles to be taken into account when engineering microbial bioelectrochemical systems (BES) for bio-production. In addition, BES-based bio-production processes reported in the literature are compared against industrial needs showing that a still large gap has to be closed. Finally, the feasibility of BES bio-production is analysed based on bulk electricity prices. Using the example of lysine production from sucrose, we demonstrate that there is a realistic market potential as cost savings of 8.4 % (in EU) and 18.0 % (in US) could be anticipated, if the necessary yields can be obtained. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Mobility of diesel versus non-diesel coal miners: some evidence on the healthy worker effect.

    PubMed Central

    Ames, R G; Trent, B

    1984-01-01

    Workers who are particularly susceptible to the effects of their occupational exposure, from the perspective of the healthy worker effect, soon leave the workplace. The result of this mobility, called survival bias, is that cross sectional studies based on the survivors underestimate the true risk of occupational exposures. Two questions are addressed in this empirical study of the "survival bias" component of the "healthy worker" effect. Do miners with respiratory impairment or symptoms disproportionately leave jobs that have a potentially harmful respiratory exposure? And does the presence of an additional potentially harmful respiratory exposure, in this case diesel emissions, accelerate the rate of mobility for miners with respiratory impairment or symptoms? No confirmation was found for the survival effect in a study of 738 diesel and 420 non-diesel US underground coal miners. No additional increment in mobility was associated with exposure to both coal mine dust and diesel emissions. PMID:6722047

  19. A low-power bio-potential acquisition system with flexible PDMS dry electrodes for portable ubiquitous healthcare applications.

    PubMed

    Chen, Chih-Yuan; Chang, Chia-Lin; Chang, Chih-Wei; Lai, Shin-Chi; Chien, Tsung-Fu; Huang, Hong-Yi; Chiou, Jin-Chern; Luo, Ching-Hsing

    2013-03-04

    This work describes a bio-potential acquisition system for portable ubiquitous healthcare applications using flexible polydimethylsiloxane dry electrodes (FPDEs) and a low-power recording circuit. This novel FPDE used Au as the skin contact layer, which was made using a CO2 laser and replica method technology. The FPDE was revised from a commercial bio-potential electrode with a conductive snap using dry electrodes rather than wet electrodes that proposed reliable and robust attachment for the purpose of measurement, and attaching velcro made it wearable on the forearm for bio-potential applications. Furthermore, this study proposes a recording device to store bio-potential signal data and provides portability and low-power consumption for the proposed acquisition system. To acquire differential bio-potentials, such as electrocardiogram (ECG) signals, the proposed recording device includes a low-power front-end acquisition chip fabricated using a complementary metal-oxide-semiconductor (CMOS) process, a commercial microcontroller (MSP430F149), and a secure digital (SD) card for portable healthcare applications. The proposed system can obtain ECG signals efficiently and are comfortable to the skin. The power consumption of the system is about 85 mW for continuous working over a 3 day period with two AA batteries. It can also be used as a compact Holter ECG system.

  20. A Low-Power Bio-Potential Acquisition System with Flexible PDMS Dry Electrodes for Portable Ubiquitous Healthcare Applications

    PubMed Central

    Chen, Chih-Yuan; Chang, Chia-Lin; Chang, Chih-Wei; Lai, Shin-Chi; Chien, Tsung-Fu; Huang, Hong-Yi; Chiou, Jin-Chern; Luo, Ching-Hsing

    2013-01-01

    This work describes a bio-potential acquisition system for portable ubiquitous healthcare applications using flexible polydimethylsiloxane dry electrodes (FPDEs) and a low-power recording circuit. This novel FPDE used Au as the skin contact layer, which was made using a CO2 laser and replica method technology. The FPDE was revised from a commercial bio-potential electrode with a conductive snap using dry electrodes rather than wet electrodes that proposed reliable and robust attachment for the purpose of measurement, and attaching velcro made it wearable on the forearm for bio-potential applications. Furthermore, this study proposes a recording device to store bio-potential signal data and provides portability and low-power consumption for the proposed acquisition system. To acquire differential bio-potentials, such as electrocardiogram (ECG) signals, the proposed recording device includes a low-power front-end acquisition chip fabricated using a complementary metal-oxide-semiconductor (CMOS) process, a commercial microcontroller (MSP430F149), and a secure digital (SD) card for portable healthcare applications. The proposed system can obtain ECG signals efficiently and are comfortable to the skin. The power consumption of the system is about 85 mW for continuous working over a 3 day period with two AA batteries. It can also be used as a compact Holter ECG system. PMID:23459390

  1. Comparative Toxicity of Biodiesel Exhaust and Petroleum Diesel Exhaust Particulate Matter Using WKY Rat Alveolar Machrophages

    EPA Science Inventory

    Exposure to fine ambient particulate matter <2.5um (PM2.5) can induce airway inflammation, cardiopulmonary morbidity and mortality. Combustion of petroleum diesel and biodiesel contributes to PM2.5. Possible toxicity caused by inhalation of biodiesel emission particles (BioDEP) h...

  2. Examining porous bio-active glass as a potential osteo-odonto-keratoprosthetic skirt material.

    PubMed

    Huhtinen, Reeta; Sandeman, Susan; Rose, Susanna; Fok, Elsie; Howell, Carol; Fröberg, Linda; Moritz, Niko; Hupa, Leena; Lloyd, Andrew

    2013-05-01

    Bio-active glass has been developed for use as a bone substitute with strong osteo-inductive capacity and the ability to form strong bonds with soft and hard tissue. The ability of this material to enhance tissue in-growth suggests its potential use as a substitute for the dental laminate of an osteo-odonto-keratoprosthesis. A preliminary in vitro investigation of porous bio-active glass as an OOKP skirt material was carried out. Porous glass structures were manufactured from bio-active glasses 1-98 and 28-04 containing varying oxide formulation (1-98, 28-04) and particle size range (250-315 μm for 1-98 and 28-04a, 315-500 μm for 28-04b). Dissolution of the porous glass structure and its effect on pH was measured. Structural 2D and 3D analysis of porous structures were performed. Cell culture experiments were carried out to study keratocyte adhesion and the inflammatory response induced by the porous glass materials. The dissolution results suggested that the porous structure made out of 1-98 dissolves faster than the structures made from glass 28-04. pH experiments showed that the dissolution of the porous glass increased the pH of the surrounding solution. The cell culture results showed that keratocytes adhered onto the surface of each of the porous glass structures, but cell adhesion and spreading was greatest for the 98a bio-glass. Cytokine production by all porous glass samples was similar to that of the negative control indicating that the glasses do not induce a cytokine driven inflammatory response. Cell culture results support the potential use of synthetic porous bio-glass as an OOKP skirt material in terms of limited inflammatory potential and capacity to induce and support tissue ingrowth.

  3. Lightweight, low compression aircraft diesel engine. [converting a spark ignition engine to the diesel cycle

    NASA Technical Reports Server (NTRS)

    Gaynor, T. L.; Bottrell, M. S.; Eagle, C. D.; Bachle, C. F.

    1977-01-01

    The feasibility of converting a spark ignition aircraft engine to the diesel cycle was investigated. Procedures necessary for converting a single cylinder GTS10-520 are described as well as a single cylinder diesel engine test program. The modification of the engine for the hot port cooling concept is discussed. A digital computer graphics simulation of a twin engine aircraft incorporating the diesel engine and Hot Fort concept is presented showing some potential gains in aircraft performance. Sample results of the computer program used in the simulation are included.

  4. Biodegradation of potential diesel oxygenate additives: dibutyl maleate (DBM), and tripropylene glycol methyl ether (TGME).

    PubMed

    Marchetti, Alfredo A; Knize, Mark G; Chiarappa-Zucca, Marina L; Pletcher, Ronald J; Layton, David W

    2003-08-01

    The addition of oxygen-bearing compounds to diesel fuel considerably reduces particulate emissions. TGME and DBM have been identified as possible diesel additives based on their physicochemical characteristics and performance in engine tests. Although these compounds will reduce particulate emissions, their potential environmental impacts are unknown. As a means of characterizing their persistence in environmental media such as soil and groundwater, we conducted a series of biodegradation tests of DBM and TGME. Benzene and methyl tertiary butyl ether (MTBE) were also tested as reference compounds. Primary degradation of DBM fully occurred within 3 days, while TGME presented a lag phase of approximately 8 days and was not completely degraded by day 28. Benzene primary degradation occurred completely by day 3 and MTBE did not degrade at all. The total mineralized fractions of DBM and TGME achieved constant values as a function of time of approximately 65% and approximately 40%, respectively. Transport predictions show that, released to the environment, DBM and TGME would concentrate mostly in soils and waters with minimal impact to air. From an environmental standpoint, these results combined with the transport predictions indicate that DBM is a better choice than TGME as a diesel additive.

  5. Efficiency of Respirator Filter Media against Diesel Particulate Matter: A Comparison Study Using Two Diesel Particulate Sources.

    PubMed

    Burton, Kerrie A; Whitelaw, Jane L; Jones, Alison L; Davies, Brian

    2016-07-01

    Diesel engines have been a mainstay within many industries since the early 1900s. Exposure to diesel particulate matter (DPM) is a major issue in many industrial workplaces given the potential for serious health impacts to exposed workers; including the potential for lung cancer and adverse irritant and cardiovascular effects. Personal respiratory protective devices are an accepted safety measure to mitigate worker exposure against the potentially damaging health impacts of DPM. To be protective, they need to act as effective filters against carbon and other particulates. In Australia, the filtering efficiency of respiratory protective devices is determined by challenging test filter media with aerosolised sodium chloride to determine penetration at designated flow rates. The methodology outlined in AS/NZS1716 (Standards Australia International Ltd and Standards New Zealand 2012. Respiratory protective devices. Sydney/Wellington: SAI Global Limited/Standards New Zealand) does not account for the differences between characteristics of workplace contaminants like DPM and sodium chloride such as structure, composition, and particle size. This study examined filtering efficiency for three commonly used AS/NZS certified respirator filter models, challenging them with two types of diesel emissions; those from a diesel generator and a diesel engine. Penetration through the filter media of elemental carbon (EC), total carbon (TC), and total suspended particulate (TSP) was calculated. Results indicate that filtering efficiency assumed by P2 certification in Australia was achieved for two of the three respirator models for DPM generated using the small diesel generator, whilst when the larger diesel engine was used, filtering efficiency requirements were met for all three filter models. These results suggest that the testing methodology specified for certification of personal respiratory protective devices by Standards Australia may not ensure adequate protection for

  6. Experimental Investigations on Diesel engine using Methyl esters of Jatropha oil and fish oil

    NASA Astrophysics Data System (ADS)

    Karthikeyan, A.; Jayaprabakar, J.; Dude Williams, Richard

    2017-05-01

    The aim of the study is to use fish oil methyl ester (FME) and Jatropha oil methyl ester (JME) as a substitute for diesel in compression ignition engine. Experiments were conducted when the engine was fuelled with Diesel, Fish oil methyl ester and Jatropha oil methyl ester. The experiment covered a range of loads. An AVL smoke meter was used to measure the smoke density in HSU (Hatridge Smoke Unit). The exhaust emissions were measured using exhaust gas analyzer. High volume sampler was employed to measure the particulate matter in exhaust. The performance of the engine was evaluated in terms of brake specific fuel consumption, brake thermal efficiency. The combustion characteristics of the engine were studied in terms of cylinder pressure with respect to crank angle. The emissions of the engine were studied in terms of concentration of CO, NOx, particulate matter and smoke density. The results obtained for Fish oil methyl ester, Jatropha oil methyl ester, were compared with the results of diesel. Bio-diesel, which can be used as an alternate diesel fuel, is made from vegetable oil and animal fats. It is renewable, non-toxic and possesses low emission profiles.

  7. Diesel exhaust, diesel fumes, and laryngeal cancer.

    PubMed

    Muscat, J E; Wynder, E L

    1995-03-01

    A hospital-based, case-control study of 235 male patients with laryngeal cancer and 205 male control patients was conducted to determine the effects of exposure to diesel engine exhaust and diesel fumes and the risk of laryngeal cancer. All patients were interviewed directly in the hospital with a standardized questionnaire that gathered information on smoking habits, alcohol consumption, employment history, and occupational exposures. Occupations that involve substantial exposure to diesel engine exhaust include mainly truck drivers, as well as mine workers, firefighters, and railroad workers. The odds ratio for laryngeal cancer associated with these occupations was 0.96 (95% confidence interval, 0.5 to 1.8). The odds ratio for self-reported exposure to diesel exhaust was 1.47 (95% confidence interval, 0.5 to 4.1). An elevated risk was found for self-reported exposure to diesel fumes (odds ratio, 6.4; 95% confidence interval, 1.8 to 22.6). No association was observed between jobs that entail exposure to diesel fumes, such as automobile mechanics, and the risk of laryngeal cancer. These results show that diesel engine exhaust is unrelated to laryngeal cancer risk. The different findings for self-reported diesel fumes and occupations that involve exposure to diesel fumes could reflect a recall bias.

  8. Catalytic upgrading of bio-oil produced from hydrothermal liquefaction of Nannochloropsis sp.

    PubMed

    Shakya, Rajdeep; Adhikari, Sushil; Mahadevan, Ravishankar; Hassan, El Barbary; Dempster, Thomas A

    2018-03-01

    Upgrading of bio-oil obtained from hydrothermal liquefaction (HTL) of algae is necessary for it to be used as a fuel. In this study, bio-oil obtained from HTL of Nannochloropsis sp. was upgraded using five different catalysts (Ni/C, ZSM-5, Ni/ZSM-5, Ru/C and Pt/C) at 300 °C and 350 °C. The upgraded bio-oil yields were higher at 300 °C; however, higher quality upgraded bio-oils were obtained at 350 °C. Ni/C gave the maximum upgraded bio-oil yield (61 wt%) at 350 °C. However, noble metal catalysts (Ru/C and Pt/C) gave the better upgraded bio-oils in terms of acidity, heating values, and nitrogen values. The higher heating value of the upgraded bio-oils ranged from 40 to 44 MJ/kg, and the nitrogen content decreased from 5.37 to 1.29 wt%. Most of the upgraded bio-oils (35-40 wt%) were in the diesel range. The major components present in the gaseous products were CH 4 , CO, CO 2 and lower alkanes. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Disrupting the immune system by diesel pollution

    EPA Science Inventory

    For 25 years, clinical, animal and epidemiological studies have shown associations between diesel exhaust and allergic disease. Diesel particles have the potential to increase allergic symptoms, increase cellular inflammation enhance allergic antibodies and prime allergic sensit...

  10. Thermal lens spectroscopy for the differentiation of biodiesel-diesel blends

    NASA Astrophysics Data System (ADS)

    Ventura, M.; Simionatto, E.; Andrade, L. H. C.; Lima, S. M.

    2012-04-01

    Thermal lens (TL) spectroscopy was applied to biofuels to test its potential to distinguish diesel from biodiesel in blended fuels. Both the heat and mass diffusion effects observed using a TL procedure provide significant information about biodiesel concentrations in blended fuels. The results indicate that the mass diffusivity decreases 32% between diesel and the blend with 10% biodiesel added to the diesel. This simple TL procedure has the potential to be used for in loco analyses to certify the mixture and quality of biodiesel-diesel blends.

  11. Enrichment of bio-oil after hydrothermal liquefaction (HTL) of microalgae C. vulgaris grown in wastewater: Bio-char and post HTL wastewater utilization studies.

    PubMed

    Arun, Jayaseelan; Varshini, Padmanabhan; Prithvinath, P Kamath; Priyadarshini, Venkataramani; Gopinath, Kannappan Panchamoorthy

    2018-08-01

    In this study, bio-oil was produced through hydrothermal liquefaction (HTL) of C. vulgaris biomass cultivated in wastewater and was enriched into transportation fuels. Bio-oil yield was 29.37% wt at 300 °C, 60 min, at 15 g/200 mL biomass loading rate with 3% wt nano ZnO catalyst loading. Applying catalyst reduced oxygen and nitrogen content in bio-oil and increased its calorific value (19.6 ± 0.8 MJ/Kg). Bio-oil was enriched through liquid-liquid extraction (LLE) and higher yield was obtained at 30 °C for dichloromethane solvent (18.2% wt). Compounds of enriched oil were within the petro-diesel range (C 8 -C 21 ). Bio-char after HTL process was activated and used as adsorbent in wastewater treatment process to remove organic pollutants (COD, NO 3 , NH 3 and PO 4 ). Treated wastewater can be supplied as growth medium for microalgae cultivation in further experiments. Nearly 3-4 times the nanocatalyst can be reused in the HTL process. Copyright © 2018 Elsevier Ltd. All rights reserved.

  12. Stabilization of Bio-Oil Fractions for Insertion into Petroleum Refineries

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brown, Robert C.; Smith, Ryan; Wright, Mark

    This project is part of a collaboration effort between Iowa State University (ISU), University of Oklahoma (OK) and Pacific Northwest National Laboratory (PNNL). The purpose of this project is to stabilize bio-oil fractions and improve their suitability for insertion into petroleum refineries. Bio-oil from fast pyrolysis of biomass is a complex mixture of unstable organic compounds. These organic compounds react under standard room conditions resulting in increases in bio-oil viscosity and water content – both detrimental for bio-oil storage and transportation. This study employed fractionation and upgrading systems to improve the stability of bio-oil. The fractionation system consists of amore » series of condensers, and electrostatic precipitators designed to separate bio-oil into five fractions: soluble carbohydrates (SF1&2), clean phenolic oligomers (CPO) and middle fraction (SF3&4), light oxygenates (SF5). A two-stage upgrading process was designed to process bio-oil stage fractions into stable products that can be inserted into a refinery. In the upgrading system, heavy and middle bio-oil fractions were upgraded into stable oil via cracking and subsequent hydrodeoxygenation. The light oxygenate fraction was steam reformed to provide a portion of requisite hydrogen for hydroprocessing. Hydrotreating and hydrocracking employed hydrogen from natural gas, fuel gas and light oxygenates reforming. The finished products from this study consist of gasoline- and diesel-blend stock fuels.« less

  13. PM, carbon, and PAH emissions from a diesel generator fuelled with soy-biodiesel blends.

    PubMed

    Tsai, Jen-Hsiung; Chen, Shui-Jen; Huang, Kuo-Lin; Lin, Yuan-Chung; Lee, Wen-Jhy; Lin, Chih-Chung; Lin, Wen-Yinn

    2010-07-15

    Biodiesels have received increasing attention as alternative fuels for diesel engines and generators. This study investigates the emissions of particulate matter (PM), total carbon (TC), e.g., organic/elemental carbons, and polycyclic aromatic hydrocarbons (PAHs) from a diesel generator fuelled with soy-biodiesel blends. Among the tested diesel blends (B0, B10 (10 vol% soy-biodiesel), B20, and B50), B20 exhibited the lowest PM emission concentration despite the loads (except the 5 kW case), whereas B10 displayed lower PM emission factors when operating at 0 and 10 kW than the other fuel blends. The emission concentrations or factors of EC, OC, and TC were the lowest when B10 or B20 was used regardless of the loading. Under all tested loads, the average concentrations of total-PAHs emitted from the generator using the B10 and B20 were lower (by 38% and 28%, respectively) than those using pure petroleum diesel fuel (B0), while the emission factors of total-PAHs decreased with an increasing ratio of biodiesel to premium diesel. With an increasing loading, although the brake specific fuel consumption decreased, the energy efficiency increased despite the bio/petroleum diesel ratio. Therefore, soy-biodiesel is promising for use as an alternative fuel for diesel generators to increase energy efficiency and reduce the PM, carbon, and PAH emissions. 2010 Elsevier B.V. All rights reserved.

  14. Computational Methods to Assess the Production Potential of Bio-Based Chemicals.

    PubMed

    Campodonico, Miguel A; Sukumara, Sumesh; Feist, Adam M; Herrgård, Markus J

    2018-01-01

    Elevated costs and long implementation times of bio-based processes for producing chemicals represent a bottleneck for moving to a bio-based economy. A prospective analysis able to elucidate economically and technically feasible product targets at early research phases is mandatory. Computational tools can be implemented to explore the biological and technical spectrum of feasibility, while constraining the operational space for desired chemicals. In this chapter, two different computational tools for assessing potential for bio-based production of chemicals from different perspectives are described in detail. The first tool is GEM-Path: an algorithm to compute all structurally possible pathways from one target molecule to the host metabolome. The second tool is a framework for Modeling Sustainable Industrial Chemicals production (MuSIC), which integrates modeling approaches for cellular metabolism, bioreactor design, upstream/downstream processes, and economic impact assessment. Integrating GEM-Path and MuSIC will play a vital role in supporting early phases of research efforts and guide the policy makers with decisions, as we progress toward planning a sustainable chemical industry.

  15. Stop and Smell the Fries: Collaborative Bio-Fuel Research in the Community College

    ERIC Educational Resources Information Center

    Mojock, Charles; Keefer, Robert; Summer, David

    2008-01-01

    Our project was to provide a community college undergraduate an authentic research opportunity in a science discipline. To do this, students who have completed a two-semester sequence in chemistry or physics were recruited to investigate the technical aspects of producing economically viable bio-diesel fuel from donated discarded restaurant…

  16. Philippine refiner completes diesel desulfurization project

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Candido, S.S.; Crisostomo, E.V.

    1997-01-27

    In anticipation of tightening sulfur specifications on diesel fuel, Petron Corp. built a new 18,000 b/sd gas oil desulfurization unit (GODU) at its refinery in Bataan, Philippines. The GODU gives Petron sufficient diesel oil desulfurization capacity to meet demand for lower-sulfur diesel in the country. The project places the refinery in a pacesetter position to comply with the Philippine government`s moves to reduce air pollution, especially in urban centers, by reducing the sulfur specification for diesel to 0.5 wt% in 1996 from 0.7 wt% at the start of the project. Performance tests and initial operations of the unit have revealedmore » a desulfurization efficiency of 91% vs. a guaranteed efficiency of 90%. A feed sulfur content of 1.33 wt% is reduced to 0.12 wt% at normal operating conditions. Operating difficulties during start-up were minimized through use of a detailed prestartup check conducted during the early stages of construction work.« less

  17. Selected physical properties of various diesel blends

    NASA Astrophysics Data System (ADS)

    Hlaváčová, Zuzana; Božiková, Monika; Hlaváč, Peter; Regrut, Tomáš; Ardonová, Veronika

    2018-01-01

    The quality determination of biofuels requires identifying the chemical and physical parameters. The key physical parameters are rheological, thermal and electrical properties. In our study, we investigated samples of diesel blends with rape-seed methyl esters content in the range from 3 to 100%. In these, we measured basic thermophysical properties, including thermal conductivity and thermal diffusivity, using two different transient methods - the hot-wire method and the dynamic plane source. Every thermophysical parameter was measured 100 times using both methods for all samples. Dynamic viscosity was measured during the heating process under the temperature range 20-80°C. A digital rotational viscometer (Brookfield DV 2T) was used for dynamic viscosity detection. Electrical conductivity was measured using digital conductivity meter (Model 1152) in a temperature range from -5 to 30°C. The highest values of thermal parameters were reached in the diesel sample with the highest biofuel content. The dynamic viscosity of samples increased with higher concentration of bio-component rapeseed methyl esters. The electrical conductivity of blends also increased with rapeseed methyl esters content.

  18. Hydrodeoxygenation of water-insoluble bio-oil to alkanes using a highly dispersed Pd-Mo catalyst.

    PubMed

    Duan, Haohong; Dong, Juncai; Gu, Xianrui; Peng, Yung-Kang; Chen, Wenxing; Issariyakul, Titipong; Myers, William K; Li, Meng-Jung; Yi, Ni; Kilpatrick, Alexander F R; Wang, Yu; Zheng, Xusheng; Ji, Shufang; Wang, Qian; Feng, Junting; Chen, Dongliang; Li, Yadong; Buffet, Jean-Charles; Liu, Haichao; Tsang, Shik Chi Edman; O'Hare, Dermot

    2017-09-19

    Bio-oil, produced by the destructive distillation of cheap and renewable lignocellulosic biomass, contains high energy density oligomers in the water-insoluble fraction that can be utilized for diesel and valuable fine chemicals productions. Here, we show an efficient hydrodeoxygenation catalyst that combines highly dispersed palladium and ultrafine molybdenum phosphate nanoparticles on silica. Using phenol as a model substrate this catalyst is 100% effective and 97.5% selective for hydrodeoxygenation to cyclohexane under mild conditions in a batch reaction; this catalyst also demonstrates regeneration ability in long-term continuous flow tests. Detailed investigations into the nature of the catalyst show that it combines hydrogenation activity of Pd and high density of both Brønsted and Lewis acid sites; we believe these are key features for efficient catalytic hydrodeoxygenation behavior. Using a wood and bark-derived feedstock, this catalyst performs hydrodeoxygenation of lignin, cellulose, and hemicellulose-derived oligomers into liquid alkanes with high efficiency and yield.Bio-oil is a potential major source of renewable fuels and chemicals. Here, the authors report a palladium-molybdenum mixed catalyst for the selective hydrodeoxygenation of water-insoluble bio-oil to mixtures of alkanes with high carbon yield.

  19. Simultaneous determination of hydrocarbon renewable diesel, biodiesel and petroleum diesel contents in diesel fuel blends using near infrared (NIR) spectroscopy and chemometrics.

    PubMed

    Alves, Julio Cesar Laurentino; Poppi, Ronei Jesus

    2013-11-07

    Highly polluting fuels based on non-renewable resources such as fossil fuels need to be replaced with potentially less polluting renewable fuels derived from vegetable or animal biomass, these so-called biofuels, are a reality nowadays and many countries have started the challenge of increasing the use of different types of biofuels, such as ethanol and biodiesel (fatty acid alkyl esters), often mixed with petroleum derivatives, such as gasoline and diesel, respectively. The quantitative determination of these fuel blends using simple, fast and low cost methods based on near infrared (NIR) spectroscopy combined with chemometric methods has been reported. However, advanced biofuels based on a mixture of hydrocarbons or a single hydrocarbon molecule, such as farnesane (2,6,10-trimethyldodecane), a hydrocarbon renewable diesel, can also be used in mixtures with biodiesel and petroleum diesel fuel and the use of NIR spectroscopy for the quantitative determination of a ternary fuel blend of these two hydrocarbon-based fuels and biodiesel can be a useful tool for quality control. This work presents a development of an analytical method for the quantitative determination of hydrocarbon renewable diesel (farnesane), biodiesel and petroleum diesel fuel blends using NIR spectroscopy combined with chemometric methods, such as partial least squares (PLS) and support vector machines (SVM). This development leads to a more accurate, simpler, faster and cheaper method when compared to the standard reference method ASTM D6866 and with the main advantage of providing the individual quantification of two different biofuels in a mixture with petroleum diesel fuel. Using the developed PLS model the three fuel blend components were determined simultaneously with values of root mean square error of prediction (RMSEP) of 0.25%, 0.19% and 0.38% for hydrocarbon renewable diesel, biodiesel and petroleum diesel, respectively, the values obtained were in agreement with those suggested by

  20. Quantitative investigation of free radicals in bio-oil and their potential role in condensed-phase polymerization.

    PubMed

    Kim, Kwang Ho; Bai, Xianglan; Cady, Sarah; Gable, Preston; Brown, Robert C

    2015-03-01

    We report on the quantitative analysis of free radicals in bio-oils produced from pyrolysis of cellulose, organosolv lignin, and corn stover by EPR spectroscopy. Also, we investigated their potential role in condensed-phase polymerization. Bio-oils produced from lignin and cellulose show clear evidence of homolytic cleavage reactions during pyrolysis that produce free radicals. The concentration of free radicals in lignin bio-oil was 7.5×10(20)  spin g(-1), which was 375 and 138 times higher than free-radical concentrations in bio-oil from cellulose and corn stover. Pyrolytic lignin had the highest concentration in free radicals, which could be a combination of carbon-centered (benzyl radicals) and oxygen-centered (phenoxy radicals) organic species because they are delocalized in a π system. Free-radical concentrations did not change during accelerated aging tests despite increases in molecular weight of bio-oils, suggesting that free radicals in condensed bio-oils are stable. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Production of bio-hydrogenated diesel by catalytic hydrotreating of palm oil over NiMoS2/γ-Al2O3 catalyst.

    PubMed

    Srifa, Atthapon; Faungnawakij, Kajornsak; Itthibenchapong, Vorranutch; Viriya-Empikul, Nawin; Charinpanitkul, Tawatchai; Assabumrungrat, Suttichai

    2014-04-01

    Catalytic hydrotreating of palm oil (refined palm olein type) to produce bio-hydrogenated diesel (BHD) was carried out in a continuous-flow fixed-bed reactor over NiMoS2/γ-Al2O3 catalyst. Effects of dominant hydrotreating parameters: temperature: 270-420°C; H2 pressure: 15-80 bar; LHSV: 0.25-5.0 h(-1); and H2/oil ratio: 250-2000 N(cm(3)/cm(3)) on the conversion, product yield, and a contribution of hydrodeoxygenation (HDO) and decarbonylation/decarboxylation (DCO/DCO2) were investigated to find the optimal hydrotreating conditions. All calculations including product yield and the contribution of HDO and DCO/DCO2 were extremely estimated based on mole balance corresponding to the fatty acid composition in feed to fully understand deoxygenation behaviors at different conditions. These analyses demonstrated that HDO, DCO, and DCO2 reactions competitively occurred at each condition, and had different optimal and limiting conditions. The differences in the hydrotreating reactions, liquid product compositions, and gas product composition were also discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. Oxidant generation and toxicity enhancement of aged-diesel exhaust

    NASA Astrophysics Data System (ADS)

    Li, Qianfeng; Wyatt, Anna; Kamens, Richard M.

    Diesel exhaust related airborne Particulate Matter (PM) has been linked to a myriad of adverse health outcomes, ranging from cancer to cardiopulmonary disease. The underlying toxicological mechanisms are of great scientific interest. A hypothesis under investigation is that many of the adverse health effects may derive from oxidative stress, initiated by the formation of reactive oxygen species (ROS) within affected cells. In this study, the main objective was to determine whether aged-diesel exhaust PM has a higher oxidant generation and toxicity than fresh diesel exhaust PM. The diesel exhaust PM was generated from a 1980 Mercedes-Benz model 300SD, and a dual 270 m 3 Teflon film chamber was utilized to generate two test atmospheres. One side of the chamber is used to produce ozone-diesel exhaust PM system, and another side of the chamber was used to produce diesel exhaust PM only system. A newly optimized dithiothreitol (DTT) method was used to assess their oxidant generation and toxicity. The results of this study showed: (1) both fresh and aged-diesel exhaust PM had high oxidant generation and toxicity; (2) ozone-diesel exhaust PM had a higher toxicity response than diesel exhaust PM only; (3) the diesel exhaust PM toxicity increased with time; (4) the optimized DTT method could be used as a good quantitative chemical assay for oxidant generation and toxicity measurement.

  3. Analysis of the Global Warming Potential of Biogenic CO2 Emission in Life Cycle Assessments.

    PubMed

    Liu, Weiguo; Zhang, Zhonghui; Xie, Xinfeng; Yu, Zhen; von Gadow, Klaus; Xu, Junming; Zhao, Shanshan; Yang, Yuchun

    2017-01-03

    Biomass is generally believed to be carbon neutral. However, recent studies have challenged the carbon neutrality hypothesis by introducing metric indicators to assess the global warming potential of biogenic CO 2 (GWP bio ). In this study we calculated the GWP bio factors using a forest growth model and radiative forcing effects with a time horizon of 100 years and applied the factors to five life cycle assessment (LCA) case studies of bioproducts. The forest carbon change was also accounted for in the LCA studies. GWP bio factors ranged from 0.13-0.32, indicating that biomass could be an attractive energy resource when compared with fossil fuels. As expected, short rotation and fast-growing biomass plantations produced low GWP bio . Long-lived wood products also allowed more regrowth of biomass to be accounted as absorption of the CO 2 emission from biomass combustion. The LCA case studies showed that the total life cycle GHG emissions were closely related to GWP bio and energy conversion efficiency. By considering the GWP bio factors and the forest carbon change, the production of ethanol and bio-power appeared to have higher GHG emissions than petroleum-derived diesel at the highest GWP bio .

  4. Conventional engine technology. Volume 2: Status of diesel engine technology

    NASA Technical Reports Server (NTRS)

    Schneider, H. W.

    1981-01-01

    The engines of diesel cars marketed in the United States were examined. Prominent design features, performance characteristics, fuel economy and emissions data were compared. Specific problems, in particular those of NO and smoke emissions, the effects of increasing dieselization on diesel fuel price and availability, current R&D work and advanced diesel concepts are discussed. Diesel cars currently have a fuel economy advantage over gasoline engine powered cars. Diesel drawbacks (noise and odor) were reduced to a less objectionable level. An equivalent gasoline engine driveability was obtained with turbocharging. Diesel manufacturers see a growth in the diesel market for the next ten years. Uncertainties regarding future emission regulation may inhibit future diesel production investments. With spark ignition engine technology advancing in the direction of high compression ratios, the fuel economy advantages of the diesel car is expected to diminish. To return its fuel economy lead, the diesel's potential for future improvement must be used.

  5. Hydrothermal microwave processing of microalgae as a pre-treatment and extraction technique for bio-fuels and bio-products.

    PubMed

    Biller, Patrick; Friedman, Cerri; Ross, Andrew B

    2013-05-01

    Microalgae are regarded as a promising source of lipids for bio-diesel production and bio-products. The current paper investigates the processing of microalgal slurries under controlled microwave irradiation. Microwave power was applied to reach temperatures of 80, 100, 120 and 140 °C at a constant residence time of 12 min. Microwave irradiation led to disruption of the algal cell walls which facilitated lipid extraction. The influence of inorganic material on microwave heating was assessed for three strains including, Nannochloropsis occulata, Chlorogloeopsis fritschii and Pseudochoricystis ellipsoidea. Mass balances were calculated and showed that the amount of carbon, nitrogen and total mass recovered in the residue was highly dependent on process conditions and algae strain. Hydrothermal microwave processing (HMP) was found to be an effective pre-treatment for hydrothermal liquefaction and extraction of lipids and phytochemicals. Copyright © 2013 Elsevier Ltd. All rights reserved.

  6. Potential Bio-Control Agent from Rhodomyrtus tomentosa against Listeria monocytogenes

    PubMed Central

    Odedina, Grace Fiyinfoluwa; Vongkamjan, Kitiya; Voravuthikunchai, Supayang Piyawan

    2015-01-01

    Listeria monocytogenes is an important foodborne pathogen implicated in many outbreaks of listeriosis. This study aimed at screening for the potential use of Rhodomyrtus tomentosa ethanolic leaf extract as a bio-control agent against L. monocytogenes. Twenty-two L. monocytogenes isolates were checked with 16 commercial antibiotics and isolates displayed resistance to 10 antibiotics. All the tested isolates were sensitive to the extract with inhibition zones ranging from 14 to 16 mm. Minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) values ranged from 16 to 32 µg/mL and 128 to 512 µg/mL, respectively. Time-kill assay showed that the extract had remarkable bactericidal effects on L. monocytogenes. The extract at a concentration of 16 µg/mL reduced tolerance to 10% NaCl in L. monocytogenes in 4 h. Stationary phase L. monocytogenes cells were rapidly inactivated by greater than 3-log units within 30 min of contact time with R. tomentosa extract at 128 µg/mL. Electron microscopy revealed fragmentary bacteria with changes in the physical and morphological properties. Our study demonstrates the potential of the extract for further development into a bio-control agent in food to prevent the incidence of L. monocytogenes contamination. PMID:26371033

  7. Effect of Variable Compression Ratio on Performance of a Diesel Engine Fueled with Karanja Biodiesel and its Blends

    NASA Astrophysics Data System (ADS)

    Mishra, Rahul Kumar; soota, Tarun, Dr.; singh, Ranjeet

    2017-08-01

    Rapid exploration and lavish consumption of underground petroleum resources have led to the scarcity of underground fossil fuels moreover the toxic emissions from such fuels are pernicious which have increased the health hazards around the world. So the aim was to find an alternative fuel which would meet the requirements of petroleum or fossil fuels. Biodiesel is a clean, renewable and bio-degradable fuel having several advantages, one of the most important of which is being its eco-friendly and better knocking characteristics than diesel fuel. In this work the performance of Karanja oil was analyzed on a four stroke, single cylinder, water cooled, variable compression ratio diesel engine. The fuel used was 5% - 25% karanja oil methyl ester by volume in diesel. The results such obtained are compared with standard diesel fuel. Several properties i.e. Brake Thermal Efficiency, Brake Specific Fuel Consumptions, Exhaust Gas Temperature are determined at all operating conditions & at variable compression ratio 17 and 17.5.

  8. Particulate emissions from diesel engines: correlation between engine technology and emissions

    PubMed Central

    2014-01-01

    In the last 30 years, diesel engines have made rapid progress to increased efficiency, environmental protection and comfort for both light- and heavy-duty applications. The technical developments include all issues from fuel to combustion process to exhaust gas aftertreatment. This paper provides a comprehensive summary of the available literature regarding technical developments and their impact on the reduction of pollutant emission. This includes emission legislation, fuel quality, diesel engine- and exhaust gas aftertreatment technologies, as well as particulate composition, with a focus on the mass-related particulate emission of on-road vehicle applications. Diesel engine technologies representative of real-world on-road applications will be highlighted. Internal engine modifications now make it possible to minimize particulate and nitrogen oxide emissions with nearly no reduction in power. Among these modifications are cooled exhaust gas recirculation, optimized injections systems, adapted charging systems and optimized combustion processes with high turbulence. With introduction and optimization of exhaust gas aftertreatment systems, such as the diesel oxidation catalyst and the diesel particulate trap, as well as NOx-reduction systems, pollutant emissions have been significantly decreased. Today, sulfur poisoning of diesel oxidation catalysts is no longer considered a problem due to the low-sulfur fuel used in Europe. In the future, there will be an increased use of bio-fuels, which generally have a positive impact on the particulate emissions and do not increase the particle number emissions. Since the introduction of the EU emissions legislation, all emission limits have been reduced by over 90%. Further steps can be expected in the future. Retrospectively, the particulate emissions of modern diesel engines with respect to quality and quantity cannot be compared with those of older engines. Internal engine modifications lead to a clear reduction of the

  9. Particulate emissions from diesel engines: correlation between engine technology and emissions.

    PubMed

    Fiebig, Michael; Wiartalla, Andreas; Holderbaum, Bastian; Kiesow, Sebastian

    2014-03-07

    In the last 30 years, diesel engines have made rapid progress to increased efficiency, environmental protection and comfort for both light- and heavy-duty applications. The technical developments include all issues from fuel to combustion process to exhaust gas aftertreatment. This paper provides a comprehensive summary of the available literature regarding technical developments and their impact on the reduction of pollutant emission. This includes emission legislation, fuel quality, diesel engine- and exhaust gas aftertreatment technologies, as well as particulate composition, with a focus on the mass-related particulate emission of on-road vehicle applications. Diesel engine technologies representative of real-world on-road applications will be highlighted.Internal engine modifications now make it possible to minimize particulate and nitrogen oxide emissions with nearly no reduction in power. Among these modifications are cooled exhaust gas recirculation, optimized injections systems, adapted charging systems and optimized combustion processes with high turbulence. With introduction and optimization of exhaust gas aftertreatment systems, such as the diesel oxidation catalyst and the diesel particulate trap, as well as NOx-reduction systems, pollutant emissions have been significantly decreased. Today, sulfur poisoning of diesel oxidation catalysts is no longer considered a problem due to the low-sulfur fuel used in Europe. In the future, there will be an increased use of bio-fuels, which generally have a positive impact on the particulate emissions and do not increase the particle number emissions.Since the introduction of the EU emissions legislation, all emission limits have been reduced by over 90%. Further steps can be expected in the future. Retrospectively, the particulate emissions of modern diesel engines with respect to quality and quantity cannot be compared with those of older engines. Internal engine modifications lead to a clear reduction of the

  10. Fate and wetting potential of bio-refractory organics in membrane distillation for coke wastewater treatment.

    PubMed

    Ren, Jing; Li, Jianfeng; Chen, Zuliang; Cheng, Fangqin

    2018-06-02

    Membrane distillation (MD) has been hindered in industrial applications due to the potential wetting or fouling caused by complicated organic compositions. This study investigated the correlations between the fate and wetting potential of bio-refractory organics in the MD process, where three coke wastewater samples pre-treated with bio-degradation and coagulation served as feed solutions. Results showed that although most of the bio-refractory organics in coke wastewater were rejected by the hydrophobic membrane, some volatile aromatic organics including benzenes, phenols, quinolines and naphthalenes passed through the membrane during the MD process. Interestingly, membrane wetting occurred coincidently with the penetration of phenolic and heterocyclic organics. The wetting rate was obviously correlated with the feed composition and membrane surface properties. Ultimately, novel insights into the anti-wetting strategy of MD with bio-refractory organics was proposed, illustrating that the polyaluminum chloride/polyacrylamide coagulation not only removed contaminants which could accelerate membrane wetting, but also retarded membrane wetting by the complexation with organics. The deposition of these complexes on the membrane surface introduced a secondary hydrophilic layer on the hydrophobic substrate, which established a composite membrane structure with superior wetting resistance. These new findings would be beneficial to wetting control in membrane distillation for wastewater treatment. Copyright © 2018 Elsevier Ltd. All rights reserved.

  11. DEMONSTRATION OF POTENTIAL FOR SELECTIVE CATALYTIC REDUCTION AND DIESEL PARTICULATE FILTERS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McGILL,R; KHAIR, M; SHARP, C

    2003-08-24

    This project addresses the potential for Selective Catalytic Reduction (SCR) devices (using urea as reductant) together with Diesel Particulate Filters (DPF) and low-pressure loop exhaust gas recirculation (EGR) to achieve future stringent emissions standards for heavy-duty engines powering Class 8 vehicles. Two emission control systems consisting of the three technologies (EGR, SCR, and DPF) were calibrated on a Caterpillar C-12 heavy-duty diesel engine. Results of these calibrations showed good promise in meeting the 2010 heavy-duty emission standards as set forth by the Environmental Protection Agency (EPA). These two emission control systems were developed to evaluate a series of fuels thatmore » have similar formulations except for their sulfur content. Additionally, one fuel, code-named BP15, was also evaluated. This fuel was prepared by processing straight-run distillate stocks through a commercial, single stage hydrotreater employing high activity catalyst at maximum severity. An additional goal of this program is to provide data for an on-going EPA technology review that evaluates progress toward meeting 2007/2010 emission standards. These emissions levels were to be achieved not only on the transient test cycles but in other modes of operation such as the steady-state Euro-III style emission test known as the OICA (Organisation Internationale des Compagnies d'Automobiles) or the ESC (European Stationary Cycle). Additionally, hydrocarbon and carbon monoxide emissions standards are to be met.« less

  12. Biodegradation studies of selected hydrocarbons from diesel oil.

    PubMed

    Sepic, E; Trier, C; Leskovsek, H

    1996-10-01

    In-vitro biodegradation of aliphatic and aromatic hydrocarbons present in diesel oil by Pseudomonas fluorescens, Texaco was studied in an aqueous medium. Small aliquots of diesel oil and its aromatic fraction were incubated aerobically for periods of up to seven months and analysed by GC-MS. Biotic losses proved to be greater for aliphatic than aromatic compounds. Most biodegradation occurred within the first 20 d of incubation. The most rapid biodegradation, up to 65% in 8 d, was observed for n-alkanes (C14-C18). The same compounds were also shown to be less affected by abiotic losses. Biodegradation of n-alkanes from diesel oil and diesel oil itself showed first order kinetics for the initial incubation period. Aromatic compounds proved to be resistant to biodegradation and only phenanthrene had been degraded (30%) within 6 months.

  13. Investigation of the Optimum Farming Temperature for Grifola frondosa and Growth Promotion using the Bio-Electric Potential as an Index

    NASA Astrophysics Data System (ADS)

    Yanagibashi, Hideyuki; Hirama, Junji; Matsuda, Masato; Miyamoto, Toshio

    The purpose of this study was to investigate the optimum farming conditions for mushrooms from the view point of engineering field. As the bio-electric potential of mushrooms is considered to be closely related to the activation of mushroom cells, this relationship has been used to analyze the dependence of the morphogenetic characteristics of Grifola frondosa on farming temperatures (from 16 to 22 degree C). The experimental results indicated that a maximum response was exhibited, with correspondingly favorable morphogenesis obtained at 18 degree C. Based on the experimental results, including those in a previous study, it was assumed that the larger the bio-electric potential becomes, the higher the growth yield reaches. In order to support this assumption, growth promotion was conducted by intentionally activating the bio-electric potential within the mushrooms by stimulating them with short bursts of illumination. The resulting observation of growth promotion permitted the conclusion that the bio-electric potential can, indeed, be regarded as an index of growth.

  14. Diesel oil

    MedlinePlus

    ... oil is a heavy oil used in diesel engines. Diesel oil poisoning occurs when someone swallows diesel ... people trying to suck (siphon) gas from an automobile tank using their mouth and a garden hose ( ...

  15. Factorial analysis of diesel engine performance using different types of biofuels.

    PubMed

    Tashtoush, Ghassan M; Al-Widyan, Mohamad I; Albatayneh, Aiman M

    2007-09-01

    In this study, several bio-source-fuels like fresh and waste vegetable oil and waste animal fat were tested at different injector pressures (120, 140, 190, 210 bar) in a direct-injection, naturally aspirated, single-cylinder diesel engine with a design injection pressure of 190 bar. Using 2k factorial analysis, the effect of injection pressure (Pi) and fuel type on three engine parameters, namely, combustion efficiency (etac), mass fuel consumption (mf), and engine speed (N) was examined. It was found that Pi and fuel type significantly affected both etac and mf while they had a slight effect on engine speed. Moreover, with diesel and biodiesels, the etac increased to a maximum at 190 bar but declined at the higher Pi value. In contrast, higher Pi had a favorable effect on etac over the whole Pi range with all the other more viscous fuels tested. In addition, the mass fuel consumption consistently decreased with an increase in Pi for all the fuels including the baseline diesel fuel, with which the engine consistently attained higher etac and higher rpm compared to all the other fuels tested.

  16. Bio-oil based biorefinery strategy for the production of succinic acid.

    PubMed

    Wang, Caixia; Thygesen, Anders; Liu, Yilan; Li, Qiang; Yang, Maohua; Dang, Dan; Wang, Ze; Wan, Yinhua; Lin, Weigang; Xing, Jianmin

    2013-01-01

    Succinic acid is one of the key platform chemicals which can be produced via biotechnology process instead of petrochemical process. Biomass derived bio-oil have been investigated intensively as an alternative of diesel and gasoline fuels. Bio-oil could be fractionized into organic phase and aqueous phase parts. The organic phase bio-oil can be easily upgraded to transport fuel. The aqueous phase bio-oil (AP-bio-oil) is of low value. There is no report for its usage or upgrading via biological methods. In this paper, the use of AP-bio-oil for the production of succinic acid was investigated. The transgenic E. coli strain could grow in modified M9 medium containing 20 v/v% AP-bio-oil with an increase in OD from 0.25 to 1.09. And 0.38 g/L succinic acid was produced. With the presence of 4 g/L glucose in the medium, succinic acid concentration increased from 1.4 to 2.4 g/L by addition of 20 v/v% AP-bio-oil. When enzymatic hydrolysate of corn stover was used as carbon source, 10.3 g/L succinic acid was produced. The obtained succinic acid concentration increased to 11.5 g/L when 12.5 v/v% AP-bio-oil was added. However, it decreased to 8 g/L when 50 v/v% AP-bio-oil was added. GC-MS analysis revealed that some low molecular carbon compounds in the AP-bio-oil were utilized by E. coli. The results indicate that AP-bio-oil can be used by E. coli for cell growth and succinic acid production.

  17. Bio Gas Oil Production from Waste Lard

    PubMed Central

    Hancsók, Jenő; Baladincz, Péter; Kasza, Tamás; Kovács, Sándor; Tóth, Csaba; Varga, Zoltán

    2011-01-01

    Besides the second generations bio fuels, one of the most promising products is the bio gas oil, which is a high iso-paraffin containing fuel, which could be produced by the catalytic hydrogenation of different triglycerides. To broaden the feedstock of the bio gas oil the catalytic hydrogenation of waste lard over sulphided NiMo/Al2O3 catalyst, and as the second step, the isomerization of the produced normal paraffin rich mixture (intermediate product) over Pt/SAPO-11 catalyst was investigated. It was found that both the hydrogenation and the decarboxylation/decarbonylation oxygen removing reactions took place but their ratio depended on the process parameters (T = 280–380°C, P = 20–80 bar, LHSV = 0.75–3.0 h−1 and H2/lard ratio: 600 Nm3/m3). In case of the isomerization at the favourable process parameters (T = 360–370°C, P = 40 –50 bar, LHSV = 1.0 h−1 and H2/hydrocarbon ratio: 400 Nm3/m3) mainly mono-branching isoparaffins were obtained. The obtained products are excellent Diesel fuel blending components, which are practically free of heteroatoms. PMID:21403875

  18. Bio gas oil production from waste lard.

    PubMed

    Hancsók, Jeno; Baladincz, Péter; Kasza, Tamás; Kovács, Sándor; Tóth, Csaba; Varga, Zoltán

    2011-01-01

    Besides the second generations bio fuels, one of the most promising products is the bio gas oil, which is a high iso-paraffin containing fuel, which could be produced by the catalytic hydrogenation of different triglycerides. To broaden the feedstock of the bio gas oil the catalytic hydrogenation of waste lard over sulphided NiMo/Al(2)O(3) catalyst, and as the second step, the isomerization of the produced normal paraffin rich mixture (intermediate product) over Pt/SAPO-11 catalyst was investigated. It was found that both the hydrogenation and the decarboxylation/decarbonylation oxygen removing reactions took place but their ratio depended on the process parameters (T = 280-380°C, P = 20-80 bar, LHSV = 0.75-3.0  h(-1) and H(2)/lard ratio: 600  Nm(3)/m(3)). In case of the isomerization at the favourable process parameters (T = 360-370°C, P = 40-50 bar, LHSV = 1.0  h(-1) and H(2)/hydrocarbon ratio: 400  Nm(3)/m(3)) mainly mono-branching isoparaffins were obtained. The obtained products are excellent Diesel fuel blending components, which are practically free of heteroatoms.

  19. A study on synthesis of energy fuel from waste plastic and assessment of its potential as an alternative fuel for diesel engines.

    PubMed

    Kaimal, Viswanath K; Vijayabalan, P

    2016-05-01

    The demand for plastic is ever increasing and has produced a huge amount of plastic waste. The management and disposal of plastic waste have become a major concern, especially in developing cities. The idea of waste to energy recovery is one of the promising techniques used for managing the waste plastic. This paper assesses the potential of using Waste Plastic Oil (WPO), synthesized using pyrolysis of waste plastic, as an alternative for diesel fuel. In this research work, the performance and emission characteristics of a single cylinder diesel engine fuelled with WPO and its blends with diesel are studied. In addition to neat plastic oil, three blends (PO25, PO50 and PO75) were prepared on a volumetric basis and the engine was able to run on neat plastic oil. Brake thermal efficiency of blends was lower compared to diesel, but PO25 showed similar performance to that of diesel. The emissions were reduced considerably while using blends when compared to neat plastic oil. The smoke and NOX were reduced by 22% and 17.8% respectively for PO25 than that of plastic oil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. [Effects of oxygenated fuels on emissions and carbon composition of fine particles from diesel engine].

    PubMed

    Shi, Xiao-Yan; He, Ke-Bin; Zhang, Jie; Ge, Yun-Shan; Tan, Jian-Wei

    2009-06-15

    Acetal (1,1-diethoxyethane) is considered as an alternative to ethanol as bio-derived additive for diesel fuel, which is miscible in diesel fuel. Biodiesel can improve the oxygen content and flash point of the fuel blend of acetal and diesel fuel. Two oxygenated fuels were prepared: a blend of 10% acetal + 90% diesel fuel and 10% acetal + 10% biodiesel + 80% diesel fuel. The emissions of NO(x), HC and PM2.5 from oxygenated fuels were investigated on a diesel engine bench at five modes according to various loads at two steady speeds and compared with base diesel fuel. Additionally, the carbon compositions of PM2.5 were analyzed by DRI thermal/optical carbon analyzer. Oxygenated fuels have unconspicuous effect on NO(x) emission rate but HC emission rate is observed significantly increased at some modes. The emission rate of PM2.5 is decreased by using oxygenated fuels and it decreases with the increase of fuel oxygen content. The emission rates of TC (total carbon) and EC (elemental carbon) in PM2.5 are also decreased by oxygenated fuels. The emission rate of organic carbon (OC) is greatly decreased at modes of higher engine speed. The OC/EC ratios of PM2.5 from oxygenated fuels are higher than that from base diesel fuel at most modes. The carbon compositions fractions of PM2.5 from the three test fuels are similar, and OC1 and EC1 are contributed to the most fractions of OC and EC, respectively. Compared with base diesel fuel, oxygenated fuels decrease emission rate of PM2.5, and have more OC contribution to PM2.5 but have little effect on carbon composition fractions.

  1. A Power-Efficient Bio-Potential Acquisition Device with DS-MDE Sensors for Long-Term Healthcare Monitoring Applications

    PubMed Central

    Chang, Chia-Lin; Chang, Chih-Wei; Huang, Hong-Yi; Hsu, Chen-Ming; Huang, Chia-Hsuan; Chiou, Jin-Chern; Luo, Ching-Hsing

    2010-01-01

    This work describes a power-efficient bio-potential acquisition device for long-term healthcare applications that is implemented using novel microelectromechanical dry electrodes (MDE) and a low power bio-potential processing chip. Using micromachining technology, an attempt is also made to enhance the sensing reliability and stability by fabricating a diamond-shaped MDE (DS-MDE) that has a satisfactory self-stability capability and superior electric conductivity when attached onto skin without any extra skin tissue injury technology. To acquire differential bio-potentials such as ECG signals, the proposed processing chip fabricated in a standard CMOS process has a high common mode rejection ratio (C.M.R.R.) differential amplifier and a 12-bit analog-to-digital converter (ADC). Use of the proposed system and integrate simple peripheral commercial devices can obtain the ECG signal efficiently without additional skin tissue injury and ensure continuous monitoring more than 70 hours with a 400 mAh battery. PMID:22399907

  2. A power-efficient bio-potential acquisition device with DS-MDE sensors for long-term healthcare monitoring applications.

    PubMed

    Chang, Chia-Lin; Chang, Chih-Wei; Huang, Hong-Yi; Hsu, Chen-Ming; Huang, Chia-Hsuan; Chiou, Jin-Chern; Luo, Ching-Hsing

    2010-01-01

    This work describes a power-efficient bio-potential acquisition device for long-term healthcare applications that is implemented using novel microelectromechanical dry electrodes (MDE) and a low power bio-potential processing chip. Using micromachining technology, an attempt is also made to enhance the sensing reliability and stability by fabricating a diamond-shaped MDE (DS-MDE) that has a satisfactory self-stability capability and superior electric conductivity when attached onto skin without any extra skin tissue injury technology. To acquire differential bio-potentials such as ECG signals, the proposed processing chip fabricated in a standard CMOS process has a high common mode rejection ratio (C.M.R.R.) differential amplifier and a 12-bit analog-to-digital converter (ADC). Use of the proposed system and integrate simple peripheral commercial devices can obtain the ECG signal efficiently without additional skin tissue injury and ensure continuous monitoring more than 70 hours with a 400 mAh battery.

  3. Potential availability of diesel waste heat at Echo Deep Space Station (DSS 12)

    NASA Technical Reports Server (NTRS)

    Hughes, R. D.

    1982-01-01

    Energy consumption at the Goldstone Echo Deep Space Station (DSS 12) is predicted and quantified for a future station configuration which will involve implementation of proposed energy conservation modifications. Cogeneration by the utilization of diesel waste-heat to satisfy site heating and cooling requirements of the station is discussed. Scenarios involving expanded use of on-site diesel generators are presented.

  4. Ceriodaphnia dubia as a Potential Bio-Indicator for Assessing Acute Aluminum Oxide Nanoparticle Toxicity in Fresh Water Environment

    PubMed Central

    Pakrashi, Sunandan; Dalai, Swayamprava; Humayun, Ahmed; Chakravarty, Sujay; Chandrasekaran, Natarajan; Mukherjee, Amitava

    2013-01-01

    Growing nanomaterials based consumer applications have raised concerns about their potential release into the aquatic ecosystems and the consequent toxicological impacts. So environmental monitoring of the nanomaterials in aqueous systems becomes imperative. The current study reveals the potential of Ceriodaphnia dubia (C. dubia) as a bio-indicator for aluminum oxide nanoparticles in a fresh water aquatic ecosystem where it occupies an important ecological niche as a primary consumer. This study aims to investigate the aluminium oxide nanoparticle induced acute toxicity on Ceriodaphnia dubia in a freshwater system. The bioavailability of the aluminum oxide nanoparticles has been studied with respect to their aggregation behavior in the system and correlated with the toxicity endpoints. The oxidative stress generated by the particles contributed greatly toward their toxicity. The crucial role of leached aluminium ion mediated toxicity in the later phases (48 h and 72 h) in conjunction with the effects from the nano-sized particles in the initial phases (24 h) puts forth the dynamics of nanotoxicity in the test system. The internalization of nanoparticles (both gross and systemic uptake) as substantiated through the transmission electron microscopy (TEM) and inductively coupled plasma optical emission spectral (ICP-OES) analysis was another major contributor toward acute toxicity. Concluding the present study, Ceriodaphnia dubia can be a promising candidate for bio-monitoring the aluminium oxide nanoparticles in a fresh water system. PMID:24040143

  5. Ceriodaphnia dubia as a potential bio-indicator for assessing acute aluminum oxide nanoparticle toxicity in fresh water environment.

    PubMed

    Pakrashi, Sunandan; Dalai, Swayamprava; Humayun, Ahmed; Chakravarty, Sujay; Chandrasekaran, Natarajan; Mukherjee, Amitava

    2013-01-01

    Growing nanomaterials based consumer applications have raised concerns about their potential release into the aquatic ecosystems and the consequent toxicological impacts. So environmental monitoring of the nanomaterials in aqueous systems becomes imperative. The current study reveals the potential of Ceriodaphnia dubia (C. dubia) as a bio-indicator for aluminum oxide nanoparticles in a fresh water aquatic ecosystem where it occupies an important ecological niche as a primary consumer. This study aims to investigate the aluminium oxide nanoparticle induced acute toxicity on Ceriodaphnia dubia in a freshwater system. The bioavailability of the aluminum oxide nanoparticles has been studied with respect to their aggregation behavior in the system and correlated with the toxicity endpoints. The oxidative stress generated by the particles contributed greatly toward their toxicity. The crucial role of leached aluminium ion mediated toxicity in the later phases (48 h and 72 h) in conjunction with the effects from the nano-sized particles in the initial phases (24 h) puts forth the dynamics of nanotoxicity in the test system. The internalization of nanoparticles (both gross and systemic uptake) as substantiated through the transmission electron microscopy (TEM) and inductively coupled plasma optical emission spectral (ICP-OES) analysis was another major contributor toward acute toxicity. Concluding the present study, Ceriodaphnia dubia can be a promising candidate for bio-monitoring the aluminium oxide nanoparticles in a fresh water system.

  6. Overview of thermal barrier coatings in diesel engines

    NASA Technical Reports Server (NTRS)

    Yonushonis, Thomas M.

    1995-01-01

    An understanding of delamination mechanisms in thermal barrier coatings has been developed for diesel engine applications through rig tests, structural analysis modeling, nondestructive evaluation, and engine evaluation of various thermal barrier coatings. This knowledge has resulted in improved thermal barrier coatings which survive abusive cyclic fatigue tests in high output diesel engines. Although much conflicting literature now exists regarding the impact of thermal barrier coatings on engine performance and fuel consumption, the changes in fuel consumption appear to be less than a few percent and can be negative for state-of-the-art diesel engines. The ability of the thermal barrier coating to improve fuel economy tends to be dependent on a number of factors including the fuel injection system, combustion chamber design, and the initial engine fuel economy. Limited investigations on state-of-the-art diesel engines have indicated that the surface connected porosity and coating surface roughness may influence engine fuel economy. Current research efforts on thermal barrier coatings are primarily directed at reducing in-cylinder heat rejection, thermal fatigue protection of underlying metal surfaces and a possible reduction in diesel engine emissions. Significant efforts are still required to improve the plasma spray processing capability and the economics for complex geometry diesel engine components.

  7. Reducing children's exposure to school bus diesel exhaust in one school district in North Carolina.

    PubMed

    Mazer, Mary E; Vann, Julie C Jacobson; Lamanna, Beth F; Davison, Jean

    2014-04-01

    Children who are exposed to diesel exhaust from idling school buses are at increased risk of asthma exacerbation, decreased lung function, immunologic reactions, leukemia, and increased susceptibility to infections. Policies and initiatives that aim to protect school children from the harmful effects of exposure to diesel exhaust range from general environmental air quality standards to more specific legislation that targets diesel exhaust near school children. School nurse standards of practice specify that school nurses should attain current knowledge of environmental health concepts, implement environmental health strategies, and advocate for environmental health principles. This article provides a description of the professional responsibilities of school nurses in protecting children from harmful environmental exposures, provides an overview of legislative initiatives intended to protect school children from diesel exhaust exposure, and summarizes one school district's effort to reduce diesel exhaust exposure among school children.

  8. Biodegradation and surfactant-mediated biodegradation of diesel fuel by 218 microbial consortia are not correlated to cell surface hydrophobicity.

    PubMed

    Owsianiak, Mikołaj; Szulc, Alicja; Chrzanowski, Łukasz; Cyplik, Paweł; Bogacki, Mariusz; Olejnik-Schmidt, Agnieszka K; Heipieper, Hermann J

    2009-09-01

    In this study, we elucidated the role of cell surface hydrophobicity (microbial adhesion to hydrocarbons method, MATH) and the effect of anionic rhamnolipids and nonionic Triton X-100 surfactants on biodegradation of diesel fuel employing 218 microbial consortia isolated from petroleum-contaminated soils. Applied enrichment procedure with floating diesel fuel as a sole carbon source in liquid cultures resulted in consortia of varying biodegradation potential and diametrically different cell surface properties, suggesting that cell surface hydrophobicity is a conserved parameter. Surprisingly, no correlations between cell surface hydrophobicity and biodegradation of diesel fuel were found. Nevertheless, both surfactants altered cell surface hydrophobicity of the consortia in similar manner: increased for the hydrophilic and decreased for the hydrophobic cultures. In addition to this, the surfactants exhibited similar influence on diesel fuel biodegradation: Increase was observed for initially slow-degrading cultures and the opposite for fast degraders. This indicates that in the surfactant-mediated biodegradation, effectiveness of surfactants depends on the specification of microorganisms and not on the type of surfactant. In contrary to what was previously reported for pure strains, cell surface hydrophobicity, as determined by MATH, is not a good descriptor of biodegrading potential for mixed cultures.

  9. A comparative study of bio-oils from pyrolysis of microalgae and oil seed waste in a fluidized bed.

    PubMed

    Kim, Sung Won; Koo, Bon Seok; Lee, Dong Hyun

    2014-06-01

    The pyrolysis of Scenedesmus sp. and Jatropha seedshell cake (JSC) was investigated under similar operating condition in a fluidized bed reactor for comparison of pyrolytic behaviors from different species of lipids-containing biomass. Microalgae showed a narrower main peak in differential thermogravimetric curve compared to JSC due to different constituents. Pyrolysis liquid yields were similar; liquid's oil proportion of microalgae is higher than JSC. Microalgae bio-oil was characterized by similar carbon and hydrogen contents and higher H/C and O/C molar ratios compared to JSC due to compositional difference. The pyrolytic oils from microalgae and JSC contained more oxygen and nitrogen and less sulfur than petroleum and palm oils. The pyrolytic oils showed high yields of fatty oxygenates and nitrogenous compounds. The microalgae bio-oil features in high concentrations of aliphatic compounds, fatty acid alkyl ester, alcohols and nitriles. Microalgae showed potentials for alternative feedstock for green diesel, and commodity and valuable chemicals. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Diesel Mechanics: Scope and Sequence.

    ERIC Educational Resources Information Center

    Nashville - Davidson County Metropolitan Public Schools, TN.

    This scope and sequence guide, developed for a diesel mechanics vocational education program, represents an initial step in the development of a systemwide articulated curriculum sequence for all vocational programs within the Metropolitan Nashville Public School System. It was developed as a result of needs expressed by teachers, parents, and the…

  11. Bio-oil based biorefinery strategy for the production of succinic acid

    PubMed Central

    2013-01-01

    Background Succinic acid is one of the key platform chemicals which can be produced via biotechnology process instead of petrochemical process. Biomass derived bio-oil have been investigated intensively as an alternative of diesel and gasoline fuels. Bio-oil could be fractionized into organic phase and aqueous phase parts. The organic phase bio-oil can be easily upgraded to transport fuel. The aqueous phase bio-oil (AP-bio-oil) is of low value. There is no report for its usage or upgrading via biological methods. In this paper, the use of AP-bio-oil for the production of succinic acid was investigated. Results The transgenic E. coli strain could grow in modified M9 medium containing 20 v/v% AP-bio-oil with an increase in OD from 0.25 to 1.09. And 0.38 g/L succinic acid was produced. With the presence of 4 g/L glucose in the medium, succinic acid concentration increased from 1.4 to 2.4 g/L by addition of 20 v/v% AP-bio-oil. When enzymatic hydrolysate of corn stover was used as carbon source, 10.3 g/L succinic acid was produced. The obtained succinic acid concentration increased to 11.5 g/L when 12.5 v/v% AP-bio-oil was added. However, it decreased to 8 g/L when 50 v/v% AP-bio-oil was added. GC-MS analysis revealed that some low molecular carbon compounds in the AP-bio-oil were utilized by E. coli. Conclusions The results indicate that AP-bio-oil can be used by E. coli for cell growth and succinic acid production. PMID:23657107

  12. Revolutionary systems for catalytic combustion and diesel catalytic particulate traps.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stuecker, John Nicholas; Witze, Peter O.; Ferrizz, Robert Matthew

    2004-12-01

    This report is a summary of an LDRD project completed for the development of materials and structures conducive to advancing the state of the art for catalyst supports and diesel particulate traps. An ancillary development for bio-medical bone scaffolding was also realized. Traditionally, a low-pressure drop catalyst support, such as a ceramic honeycomb monolith, is used for catalytic reactions that require high flow rates of gases at high-temperatures. A drawback to the traditional honeycomb monoliths under these operating conditions is poor mass transfer to the catalyst surface in the straight-through channels. ''Robocasting'' is a unique process developed at Sandia Nationalmore » Laboratories that can be used to manufacture ceramic monoliths with alternative 3-dimensional geometries, providing tortuous pathways to increase mass transfer while maintaining low-pressure drops. These alternative 3-dimensional geometries may also provide a foundation for the development of self-regenerating supports capable of trapping and combusting soot particles from a diesel engine exhaust stream. This report describes the structures developed and characterizes the improved catalytic performance that can result. The results show that, relative to honeycomb monolith supports, considerable improvement in mass transfer efficiency is observed for robocast samples synthesized using an FCC-like geometry of alternating rods. Also, there is clearly a trade-off between enhanced mass transfer and increased pressure drop, which can be optimized depending on the particular demands of a given application. Practical applications include the combustion of natural gas for power generation, production of syngas, and hydrogen reforming reactions. The robocast lattice structures also show practicality for diesel particulate trapping. Preliminary results for trapping efficiency are reported as well as the development of electrically resistive lattices that can regenerate the structure by

  13. Monitoring diesel particulate matter and calculating diesel particulate densities using Grimm model 1.109 real-time aerosol monitors in underground mines.

    PubMed

    Kimbal, Kyle C; Pahler, Leon; Larson, Rodney; VanDerslice, Jim

    2012-01-01

    Currently, there is no Mine Safety and Health Administration (MSHA)-approved sampling method that provides real-time results for ambient concentrations of diesel particulates. This study investigated whether a commercially available aerosol spectrometer, the Grimm Portable Aerosol Spectrometer Model 1.109, could be used during underground mine operations to provide accurate real-time diesel particulate data relative to MSHA-approved cassette-based sampling methods. A subset was to estimate size-specific diesel particle densities to potentially improve the diesel particulate concentration estimates using the aerosol monitor. Concurrent sampling was conducted during underground metal mine operations using six duplicate diesel particulate cassettes, according to the MSHA-approved method, and two identical Grimm Model 1.109 instruments. Linear regression was used to develop adjustment factors relating the Grimm results to the average of the cassette results. Statistical models using the Grimm data produced predicted diesel particulate concentrations that highly correlated with the time-weighted average cassette results (R(2) = 0.86, 0.88). Size-specific diesel particulate densities were not constant over the range of particle diameters observed. The variance of the calculated diesel particulate densities by particle diameter size supports the current understanding that diesel emissions are a mixture of particulate aerosols and a complex host of gases and vapors not limited to elemental and organic carbon. Finally, diesel particulate concentrations measured by the Grimm Model 1.109 can be adjusted to provide sufficiently accurate real-time air monitoring data for an underground mining environment.

  14. Toxicological properties of emission particles from heavy duty engines powered by conventional and bio-based diesel fuels and compressed natural gas.

    PubMed

    Jalava, Pasi I; Aakko-Saksa, Päivi; Murtonen, Timo; Happo, Mikko S; Markkanen, Ari; Yli-Pirilä, Pasi; Hakulinen, Pasi; Hillamo, Risto; Mäki-Paakkanen, Jorma; Salonen, Raimo O; Jokiniemi, Jorma; Hirvonen, Maija-Riitta

    2012-09-29

    One of the major areas for increasing the use of renewable energy is in traffic fuels e.g. bio-based fuels in diesel engines especially in commuter traffic. Exhaust emissions from fossil diesel fuelled engines are known to cause adverse effects on human health, but there is very limited information available on how the new renewable fuels may change the harmfulness of the emissions, especially particles (PM). We evaluated the PM emissions from a heavy-duty EURO IV diesel engine powered by three different fuels; the toxicological properties of the emitted PM were investigated. Conventional diesel fuel (EN590) and two biodiesels were used - rapeseed methyl ester (RME, EN14214) and hydrotreated vegetable oil (HVO) either as such or as 30% blends with EN590. EN590 and 100% HVO were also operated with or without an oxidative catalyst (DOC + POC). A bus powered by compressed natural gas (CNG) was included for comparison with the liquid fuels. However, the results from CNG powered bus cannot be directly compared to the other situations in this study. High volume PM samples were collected on PTFE filters from a constant volume dilution tunnel. The PM mass emission with HVO was smaller and with RME larger than that with EN590, but both biofuels produced lower PAH contents in emission PM. The DOC + POC catalyst greatly reduced the PM emission and PAH content in PM with both HVO and EN590. Dose-dependent TNFα and MIP-2 responses to all PM samples were mostly at the low or moderate level after 24-hour exposure in a mouse macrophage cell line RAW 264.7. Emission PM from situations with the smallest mass emissions (HVO + cat and CNG) displayed the strongest potency in MIP-2 production. The catalyst slightly decreased the PM-induced TNFα responses and somewhat increased the MIP-2 responses with HVO fuel. Emission PM with EN590 and with 30% HVO blended in EN590 induced the strongest genotoxic responses, which were significantly greater than those with EN590

  15. Design and Optimisation of Electrostatic Precipitator for Diesel Exhaust

    NASA Astrophysics Data System (ADS)

    Srinivaas, A.; Sathian, Samanyu; Ramesh, Arjun

    2018-02-01

    The principle of an industrially used emission reduction technique is employed in automotive diesel exhaust to reduce the diesel particulate emission. As the Emission regulation are becoming more stringent legislations have been formulated, due to the hazardous increase in the air quality index in major cities. Initially electrostatic precipitation principle and working was investigated. The High voltage requirement in an Electrostatic precipitator is obtained by designing an appropriate circuit in MATLAB -SIMULINK. Mechanical structural design of the new model after treatment device for the specific diesel exhaust was done. Fluid flow analysis of the ESP model was carried out using ANSYS CFX for optimized fluid with a reduced back pressure. Design reconsideration was done in accordance with fluid flow analysis. Accordingly, a new design is developed by considering diesel particulate filter and catalytic converter design to ESP model.

  16. Analysis of pre-heated fuel combustion and heat-emission dynamics in a diesel engine

    NASA Astrophysics Data System (ADS)

    Plotnikov, S. A.; Kartashevich, A. N.; Buzikov, S. V.

    2018-01-01

    The article explores the feasibility of diesel fuel pre-heating. The research goal was to obtain and analyze the performance diagrams of a diesel engine fed with pre-heated fuel. The engine was tested in two modes: at rated RPMs and at maximum torque. To process the diagrams the authors used technique developed by the Central Diesel Research Institute (CDRI). The diesel engine’s heat emission curves were obtained. The authors concluded that fuel pre-heating shortened the initial phase of the combustion process and moderated the loads, thus making it possible to boost a diesel engine’s mean effective pressure.

  17. Improvement of engine emissions with conventional diesel fuel and diesel-biodiesel blends.

    PubMed

    Nabi, Md Nurun; Akhter, Md Shamim; Zaglul Shahadat, Mhia Md

    2006-02-01

    In this report combustion and exhaust emissions with neat diesel fuel and diesel-biodiesel blends have been investigated. In the investigation, firstly biodiesel from non-edible neem oil has been made by esterification. Biodiesel fuel (BDF) is chemically known as mono-alkyl fatty acid ester. It is renewable in nature and is derived from plant oils including vegetable oils. BDF is non-toxic, biodegradable, recycled resource and essentially free from sulfur and carcinogenic benzene. In the second phase of this investigation, experiment has been conducted with neat diesel fuel and diesel-biodiesel blends in a four stroke naturally aspirated (NA) direct injection (DI) diesel engine. Compared with conventional diesel fuel, diesel-biodiesel blends showed lower carbon monoxide (CO), and smoke emissions but higher oxides of nitrogen (NOx) emission. However, compared with the diesel fuel, NOx emission with diesel-biodiesel blends was slightly reduced when EGR was applied.

  18. Bio-electricity Generation using Jatropha Oil Seed Cake.

    PubMed

    Raheman, Hifjur; Padhee, Debasish

    2016-01-01

    The review of patents reveals that Handling of Jatropha seed cake after extraction of oil is essential as it contains toxic materials which create environmental pollution. The goal of this work is complete utilisation of Jatropha seeds. For this purpose, Jatropha oil was used for producing biodiesel and the byproduct Jatropha seed cake was gasified to obtain producer gas. Both biodiesel and producer gas were used to generate electricity. To achieve this, a system comprising gasifier, briquetting machine, diesel engine and generator was developed. Biodiesel was produced successfully using the method patented for biodiesel production and briquettes of Jatropha seed cake were made using a vertical extruding machine. Producer gas was obtained by gasifying these briquettes in a downdraft gasifier. A diesel engine was then run in dual fuel mode with biodiesel and producer gas instead of only diesel. Electricity was generated by coupling it to a generator. The cost of producing kilowatthour of electricity with biodiesel and diesel in dual fuel mode with producer gas was found to be 0.84 $ and 0.75 $, respectively as compared to 0.69 $ and 0.5 $ for the same fuels in single fuel mode resulting in up to 48 % saving of pilot fuel. Compared to singlefuel mode, there was 25-32 % reduction in system and brake thermal efficiency along with significantly lower NOx, higher CO and CO2 emissions when the bio-electricity generating system was operated in dual fuel mode. Overall, the developed system could produce electricity successfully by completely uti- lising Jatropha seeds without leaving any seed cake to cause environmental pollution.

  19. Screening of seaweeds in the East China Sea as potential bio-monitors of heavy metals.

    PubMed

    Pan, Yaoru; Wernberg, Thomas; de Bettignies, Thibaut; Holmer, Marianne; Li, Ke; Wu, Jiaping; Lin, Fang; Yu, Yan; Xu, Jiang; Zhou, Chaosheng; Huang, Zhixing; Xiao, Xi

    2018-06-01

    Seaweeds are good bio-monitors of heavy metal pollution and have been included in European coastal monitoring programs. However, data for seaweed species in China are scarce or missing. In this study, we explored the potential of seaweeds as bio-monitor by screening the natural occurring seaweeds in the "Kingdom of seaweed and shellfish" at Dongtou Islands, the East China Sea. Totally, 12 seaweed species were collected from six sites, with richness following the sequence of Rhodophyta > Phaeophyta > Chlorophyta. The concentration of heavy metals (Cu, Cr, Ni, Zn, Pb, Cd, As) in the seaweeds was determined, and the bioaccumulation coefficient was calculated. A combination of four seaweeds, Pachydictyon coriaceum, Gelidium divaricatum, Sargassum thunbergii, and Pterocladiella capillacea, were proposed as bio-monitors due to their high bioaccumulation capabilities of specific heavy metals in the East China Sea and hence hinted the importance of using seaweed community for monitoring of pollution rather than single species. Our results provide first-hand data for the selection of bio-monitor species for heavy metals in the East China Sea and contribute to selection of cosmopolitan bio-monitor communities over geographical large area, which will benefit the establishment of monitoring programs for coastal heavy metal contamination.

  20. Instrumental and bio-monitoring of heavy metal and nanoparticle emissions from diesel engine exhaust in controlled environment.

    PubMed

    Giordano, Simonetta; Adamo, Paola; Spagnuolo, Valeria; Vaglieco, Bianca Maria

    2010-01-01

    In the present article we characterized the emissions at the exhaust of a Common Rail (CR) diesel engine, representative of light-duty class, equipped with a catalyzed diesel particulate filter (CDPF) in controlled environment. The downstream exhausts were directly analyzed (for PM, CO, CO2, 02, HCs, NOx) by infrared and electrochemical sensors, and SEM-EDS microscope; heavy metals were chemically analyzed using mosses and lichens in bags, and glass-fibre filters all exposed at the engine exhausts. The highest particle emission value was in the 7-54 nm size range; the peak concentration rose until one order of magnitude for the highest load and speed. Particle composition was mainly carbonaceous, associated to noticeable amounts of Fe and silica fibres. Moreover, the content of Cu, Fe, Na, Ni and Zn in both moss and lichen, and of Al and Cr in moss, was significantly increased. Glass-fibre filters were significantly enriched in Al, B, Ba, Cu, Fe, Na, and Zn. The role of diesel engines as source of carbonaceous nanoparticles has been confirmed, while further investigations in controlled environment are needed to test the catalytic muffler as a possible source of silica fibres considered very hazardous for human health.

  1. [Preparation of ethanol-diesel fuel blends and exhausts emission characteristics in diesel engine].

    PubMed

    Zhang, Runduo; He, Hong; Zhang, Changbin; Shi, Xiaoyan

    2003-07-01

    The technology that diesel oil is partly substituted by ethanol can reduce diesel engine exhausts emission, especially fuel soot. This research is concentrated on preparation of ethanol-diesel blend fuel and exhausts emission characteristics using diesel engine bench. Absolute ethanol can dissolve into diesel fuel at an arbitrary ratio. However, a trace of water (0.2%) addition can lead to the phase separation of blends. Organic additive synthesized during this research can develop the ability of resistance to water and maintain the stability of ethanol-diesel-trace amounts of water system. The effects of 10%, 20%, and 30% ethanol-diesel fuel blends on exhausts emission, were compared with that of diesel fuel in direct injection (DI) diesel engine. The optimum ethanol percentage for ethanol-diesel fuel blends was 20%. Using 20% ethanol-diesel fuel blend with 2% additive of the total volume, bench diesel engine showed a large amount decrease of exhaust gas, e.g. 55% of Bosch smoke number, 70% of HC emission, and 45% of CO emission at 13 kW and 1540 r/min. Without the addition of additive, the blend of ethanol produced new organic compounds such as ethanol and acetaldehyde in tail gas. However, the addition of additive obviously reduced the emission of ethanol and acetaldehyde.

  2. Characterization of bio-oil from hydrothermal liquefaction of organic waste by NMR spectroscopy and FTICR mass spectrometry.

    PubMed

    Leonardis, Irene; Chiaberge, Stefano; Fiorani, Tiziana; Spera, Silvia; Battistel, Ezio; Bosetti, Aldo; Cesti, Pietro; Reale, Samantha; De Angelis, Francesco

    2013-01-01

    Solid wastes of organic origins are potential feedstocks for the production of liquid biofuels, which could be suitable alternatives to fossil fuels for the transport and heating sectors, as well as for industrial use. By hydrothermal liquefaction, the wet biomass is partially transformed into a water-immiscible, oil-like organic matter called bio-oil. In this study, an integrated NMR spectroscopy/mass spectrometry approach has been developed for the characterization of the hydrothermal liquefaction of bio-oil at the molecular level. (1)H and (13)C NMR spectroscopy were used for the identification of functional groups and gauging the aromatic carbon content in the mixture. GC-MS analysis revealed that the volatile fraction was rich in fatty acids, as well as in amides and esters. High-resolution Fourier-transform ion cyclotron resonance mass spectrometry (FTICR-MS) has been applied in a systematic way to fully categorize the bio-oil in terms of different classes of components, according to their molecular formulas. Most importantly, for the first time, by using this technique, and for the liquefaction bio-oil characterization in particular, FT-MS data have been used to develop a methodology for the determination of the aromatic versus aliphatic carbon and nitrogen content. It is well known that, because they resist hydrogenation and represent sources of polluting species, both aromatic molecules and nitrogen-containing species raise concerns for subsequent upgrading of bio-oil into a diesel-like fuel. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Life-cycle assessment of diesel, natural gas and hydrogen fuel cell bus transportation systems

    NASA Astrophysics Data System (ADS)

    Ally, Jamie; Pryor, Trevor

    The Sustainable Transport Energy Programme (STEP) is an initiative of the Government of Western Australia, to explore hydrogen fuel cell technology as an alternative to the existing diesel and natural gas public transit infrastructure in Perth. This project includes three buses manufactured by DaimlerChrysler with Ballard fuel cell power sources operating in regular service alongside the existing natural gas and diesel bus fleets. The life-cycle assessment (LCA) of the fuel cell bus trial in Perth determines the overall environmental footprint and energy demand by studying all phases of the complete transportation system, including the hydrogen infrastructure, bus manufacturing, operation, and end-of-life disposal. The LCAs of the existing diesel and natural gas transportation systems are developed in parallel. The findings show that the trial is competitive with the diesel and natural gas bus systems in terms of global warming potential and eutrophication. Emissions that contribute to acidification and photochemical ozone are greater for the fuel cell buses. Scenario analysis quantifies the improvements that can be expected in future generations of fuel cell vehicles and shows that a reduction of greater than 50% is achievable in the greenhouse gas, photochemical ozone creation and primary energy demand impact categories.

  4. Dual-fuel natural gas/diesel engines: Technology, performance, and emissions

    NASA Astrophysics Data System (ADS)

    Turner, S. H.; Weaver, C. S.

    1994-11-01

    An investigation of current dual-fuel natural gas/diesel engine design, performance, and emissions was conducted. The most pressing technological problems associated with dual-fuel engine use were identified along with potential solutions. It was concluded that dual-fuel engines can achieve low NO(sub x) and particulate emissions while retaining fuel-efficiency and BMEP levels comparable to those of diesel engines. The investigation also examined the potential economic impact of dual-fuel engines in diesel-electric locomotives, marine vessels, farm equipment, construction, mining, and industrial equipment, and stand-alone electricity generation systems. Recommendations for further additional funding to support research, development, and demonstration in these applications were then presented.

  5. Western Kentucky University Research Foundation Biodiesel Project

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pan, Wei-Ping; Cao, Yan

    2013-03-15

    easily fermented to create ethanol. In the United States almost all starch ethanol is mainly manufactured from corn grains. The technology for manufacturing corn ethanol can be considered mature as of the late 1980s. In 2005, 14.3 % of the U.S. corn harvest was processed to produce 1.48 x10{sup 10} liters of ethanol, energetically equivalent to 1.72 % of U.S. gasoline usage. Soybean oil is extracted from 1.5 % of the U.S. soybean harvest to produce 2.56 x 10{sup 8} liters of bio-diesel, which was 0.09 % of U.S. diesel usage. However, reaching maximum rates of bio-fuel supply from corn and soybeans is unlikely because these crops are presently major contributors to human food supplies through livestock feed and direct consumption. Moreover, there currently arguments on that the conversion of many types of many natural landscapes to grow corn for feedstock is likely to create substantial carbon emissions that will exacerbate globe warming. On the other hand, there is a large underutilized resource of cellulose biomass from trees, grasses, and nonedible parts of crops that could serve as a feedstock. One of the potentially significant new bio-fuels is so called "cellulosic ethanol", which is dependent on break-down by microbes or enzymes. Because of technological limitations (the wider variety of molecular structures in cellulose and hemicellulose requires a wider variety of microorganisms to break them down) and other cost hurdles (such as lower kinetics), cellulosic ethanol can currently remain in lab scales. Considering farm yields, commodity and fuel prices, farm energy and agrichemical inputs, production plant efficiencies, byproduct production, greenhouse gas (GHG) emissions, and other environmental effects, a life-cycle evaluation of competitive indicated that corn ethanol yields 25 % more energy than the energy invested in its production, whereas soybean bio-diesel yields 93 % more. Relative to the fossil fuels they displace, greenhouse gas emissions are reduced 12

  6. Potential reductions in ambient NO2 concentrations from meeting diesel vehicle emissions standards

    NASA Astrophysics Data System (ADS)

    von Schneidemesser, Erika; Kuik, Friderike; Mar, Kathleen A.; Butler, Tim

    2017-11-01

    Exceedances of the concentration limit value for ambient nitrogen dioxide (NO2) at roadside sites are an issue in many cities throughout Europe. This is linked to the emissions of light duty diesel vehicles which have on-road emissions that are far greater than the regulatory standards. These exceedances have substantial implications for human health and economic loss. This study explores the possible gains in ambient air quality if light duty diesel vehicles were able to meet the regulatory standards (including both emissions standards from Europe and the United States). We use two independent methods: a measurement-based and a model-based method. The city of Berlin is used as a case study. The measurement-based method used data from 16 monitoring stations throughout the city of Berlin to estimate annual average reductions in roadside NO2 of 9.0 to 23 µg m-3 and in urban background NO2 concentrations of 1.2 to 2.7 µg m-3. These ranges account for differences in fleet composition assumptions, and the stringency of the regulatory standard. The model simulations showed reductions in urban background NO2 of 2.0 µg m-3, and at the scale of the greater Berlin area of 1.6 to 2.0 µg m-3 depending on the setup of the simulation and resolution of the model. Similar results were found for other European cities. The similarities in results using the measurement- and model-based methods support our ability to draw robust conclusions that are not dependent on the assumptions behind either methodology. The results show the significant potential for NO2 reductions if regulatory standards for light duty diesel vehicles were to be met under real-world operating conditions. Such reductions could help improve air quality by reducing NO2 exceedances in urban areas, but also have broader implications for improvements in human health and other benefits.

  7. Reformulated diesel fuel

    DOEpatents

    McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

    2006-03-28

    Reformulated diesel fuels for automotive diesel engines which meet the requirements of ASTM 975-02 and provide significantly reduced emissions of nitrogen oxides (NO.sub.x) and particulate matter (PM) relative to commercially available diesel fuels.

  8. Comparative Studies of Oleaginous Fungal Strains (Mucor circinelloides and Trichoderma reesei) for Effective Wastewater Treatment and Bio-Oil Production

    PubMed Central

    Bhanja, Anshuman; Kalyanraman, V.

    2014-01-01

    Biological wastewater treatment typically requires the use of bacteria for degradation of carbonaceous and nitrogenous compounds present in wastewater. The high lipid containing biomass can be used to extract oil and the contents can be termed as bio-oil (or biodiesel or myco-diesel after transesterification). The separate experiments were conducted on actual wastewater samples with 5% v/v inoculum of Mucor circinelloides MTCC1297 and Trichoderma reesei NCIM992 strains. The observed reductions in chemical oxygen demand (COD) were 88.72% and 86.75% in 96 hrs and the observed substrate based biomass yields were 0.21 mg VSS/mg COD and 0.22 mg VSS/mg COD for M. circinelloides reactor and for T. reesei reactor, respectively. The resulted bio-oil production from wastewater treatment by M. circinelloides and T. reesei reactors was 142.2 mg/L and 74.1 mg/L, whereas biomass containing bio-oil contents (%w/w) were 22.11% and 9.82%, respectively. In this experiment, the fungal wastewater treatment was also compared with conventional bacterial process with respect to specific growth rate, biomass production, and oil content. This study suggests that wastewater can be used as a potential feedstock for bio-oil production with the use of oleaginous fungal strains and which could be a possible route of waste to energy. PMID:25530884

  9. Comparative Studies of Oleaginous Fungal Strains (Mucor circinelloides and Trichoderma reesei) for Effective Wastewater Treatment and Bio-Oil Production.

    PubMed

    Bhanja, Anshuman; Minde, Gauri; Magdum, Sandip; Kalyanraman, V

    2014-01-01

    Biological wastewater treatment typically requires the use of bacteria for degradation of carbonaceous and nitrogenous compounds present in wastewater. The high lipid containing biomass can be used to extract oil and the contents can be termed as bio-oil (or biodiesel or myco-diesel after transesterification). The separate experiments were conducted on actual wastewater samples with 5% v/v inoculum of Mucor circinelloides MTCC1297 and Trichoderma reesei NCIM992 strains. The observed reductions in chemical oxygen demand (COD) were 88.72% and 86.75% in 96 hrs and the observed substrate based biomass yields were 0.21 mg VSS/mg COD and 0.22 mg VSS/mg COD for M. circinelloides reactor and for T. reesei reactor, respectively. The resulted bio-oil production from wastewater treatment by M. circinelloides and T. reesei reactors was 142.2 mg/L and 74.1 mg/L, whereas biomass containing bio-oil contents (%w/w) were 22.11% and 9.82%, respectively. In this experiment, the fungal wastewater treatment was also compared with conventional bacterial process with respect to specific growth rate, biomass production, and oil content. This study suggests that wastewater can be used as a potential feedstock for bio-oil production with the use of oleaginous fungal strains and which could be a possible route of waste to energy.

  10. Diesel exhaust exposure, its multi-system effects, and the effect of new technology diesel exhaust.

    PubMed

    Reis, Haley; Reis, Cesar; Sharip, Akbar; Reis, Wenes; Zhao, Yong; Sinclair, Ryan; Beeson, Lawrence

    2018-05-01

    Exposure to diesel exhaust (DE) from vehicles and industry is hazardous and affects proper function of organ systems. DE can interfere with normal physiology after acute and chronic exposure to particulate matter (PM). Exposure leads to potential systemic disease processes in the central nervous, visual, hematopoietic, respiratory, cardiovascular, and renal systems. In this review, we give an overview of the epidemiological evidence supporting the harmful effects of diesel exhaust, and the numerous animal studies conducted to investigate the specific pathophysiological mechanisms behind DE exposure. Additionally, this review includes a summary of studies that used biomarkers as an indication of biological plausibility, and also studies evaluating new technology diesel exhaust (NTDE) and its systemic effects. Lastly, this review includes new approaches to improving DE emissions, and emphasizes the importance of ongoing study in this field of environmental health. Copyright © 2018 Elsevier Ltd. All rights reserved.

  11. Diesel exhaust causing low-dose irritant asthma with latency?

    PubMed

    Adewole, Femi; Moore, Vicky C; Robertson, Alastair S; Burge, P S

    2009-09-01

    Diesel exhaust exposure may cause acute irritant-induced asthma and potentiate allergen-induced asthma. There are no previous reports of occupational asthma due to diesel exhaust. To describe occupational asthma with latency in workers exposed to diesel exhaust in bus garages. The Shield database of occupational asthma notifications in the West Midlands, UK, was searched between 1990 and 2006 for workers where diesel exhaust exposure was thought to be the cause of the occupational asthma. Those without other confounding exposures whose occupational asthma was validated by serial peak expiratory flow (PEF) analysis using Oasys software were included. Fifteen workers were identified with occupational asthma attributed to diesel exhaust. Three had validated new-onset asthma with latency. All worked in bus garages where diesel exhaust exposure was the only likely cause of their occupational asthma. Occupational asthma was confirmed by measures of non-specific reactivity and serial measurements of PEF with Oasys scores of 2.9, 3.73 and 4 (positive score > 2.5). The known non-specific irritant effects of diesel exhaust suggest that this is an example of low-dose irritant-induced asthma and that exposures to diesel exhaust in at least some bus garages are at a sufficient level to cause this.

  12. Potential of Melastoma malabathricum as bio-accumulator for uranium and thorium from soil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Saat, Ahmad, E-mail: ahmad183@salam.uitm.edu.my; Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam; Kamsani, Ain Shaqina

    2015-04-29

    Uranium and Thorium are naturally occuring radionuclides. However, due to anthropogenic activities in some locations their concentrations in the soils could be elevated. This study explores the potential of Melastoma malabathricum (locally known as ‘pokok senduduk’) as bio-accumulator of uranium and thorium from soils of three different study areas, namely former tin mining, industrial and residential/commercial areas in Peninsular Malaysia. The study found elevated concentrations of uranium and thorium in former tin mining soils as compared to natural abundance. However in industral and residential/commercial areas the concentrations are within the range of natural abundance. In terms of transfer factor (TF),more » in ex-mining areas TF > 1 for uranium in the leaf, stem and roots, indicating accumulation of uranium from soil. However for thorium TF < 1, indicating the occurence of transfer from soil to root, stem and leaf, but no accumulation. For other areas only transfer of uranium and thorium were observed. The results indicated the potential of Melastoma malabathricum to be used as bio-accumulatior of uranium, especially in areas of elevated concentration.« less

  13. Performance of diesel engine using diesel B3 mixed with crude palm oil.

    PubMed

    Namliwan, Nattapong; Wongwuttanasatian, Tanakorn

    2014-01-01

    The objective of this study was to test the performance of diesel engine using diesel B3 mixed with crude palm oil in ratios of 95 : 5, 90 : 10, and 85 : 15, respectively, and to compare the results with diesel B3. According to the tests, they showed that the physical properties of the mixed fuel in the ratio of 95 : 5 were closest to those of diesel B3. The performance of the diesel engine that used mixed fuels had 5-17% lower torque and power than that of diesel B3. The specific fuel consumption of mixed fuels was 7-33% higher than using diesel B3. The components of gas emissions by using mixed fuel had 1.6-52% fewer amount of carbon monoxide (CO), carbon dioxide (CO2), sulfur dioxide (SO2), and oxygen (O2) than those of diesel B3. On the other hand, nitric oxide (NO) and nitrogen oxides (NO X ) emissions when using mixed fuels were 10-39% higher than diesel B3. By comparing the physical properties, the performance of the engine, and the amount of gas emissions of mixed fuel, we found out that the 95 : 5 ratio by volume was a suitable ratio for agricultural diesel engine (low-speed diesel engine).

  14. Performance, emission, and combustion characteristics of twin-cylinder common rail diesel engine fuelled with butanol-diesel blends.

    PubMed

    Lamani, Venkatesh Tavareppa; Yadav, Ajay Kumar; Gottekere, Kumar Narayanappa

    2017-10-01

    Nitrogen oxides and smoke are the substantial emissions for the diesel engines. Fuels comprising high-level oxygen content can have low smoke emission due to better oxidation of soot. The objective of the paper is to assess the potential to employ oxygenated fuel, i.e., n-butanol and its blends with the neat diesel from 0 to 30% by volume. The experimental and computational fluid dynamic (CFD) simulation is carried out to estimate the performance, combustion, and exhaust emission characteristics of n-butanol-diesel blends for various injection timings (9°, 12°, 15°, and 18°) using modern twin-cylinder, four-stroke, common rail direct injection (CRDI) engine. Experimental results reveal the increase in brake thermal efficiency (BTE) by ~ 4.5, 6, and 8% for butanol-diesel blends of 10% (Bu10), 20% (Bu20), and 30% (Bu30), respectively, compared to neat diesel (Bu0). Maximum BTE for Bu0 is 38.4%, which is obtained at 12° BTDC; however, for Bu10, Bu20 and Bu30 are 40.19, 40.9, and 41.7%, which are obtained at 15° BTDC, respectively. Higher flame speed of n-butanol-diesel blends burn a large amount of fuel in the premixed phase, which improves the combustion as well as emission characteristics. CFD and experimental results are compared and validated for all fuel blends for in-cylinder pressure and nitrogen oxides (NO x ), and found to be in good agreement. Both experimental and simulation results witnessed in reduction of smoke opacity, NO x , and carbon monoxide emissions with the increasing n-butanol percentage in diesel fuel.

  15. Toxicological properties of emission particles from heavy duty engines powered by conventional and bio-based diesel fuels and compressed natural gas

    PubMed Central

    2012-01-01

    Background One of the major areas for increasing the use of renewable energy is in traffic fuels e.g. bio-based fuels in diesel engines especially in commuter traffic. Exhaust emissions from fossil diesel fuelled engines are known to cause adverse effects on human health, but there is very limited information available on how the new renewable fuels may change the harmfulness of the emissions, especially particles (PM). We evaluated the PM emissions from a heavy-duty EURO IV diesel engine powered by three different fuels; the toxicological properties of the emitted PM were investigated. Conventional diesel fuel (EN590) and two biodiesels were used − rapeseed methyl ester (RME, EN14214) and hydrotreated vegetable oil (HVO) either as such or as 30% blends with EN590. EN590 and 100% HVO were also operated with or without an oxidative catalyst (DOC + POC). A bus powered by compressed natural gas (CNG) was included for comparison with the liquid fuels. However, the results from CNG powered bus cannot be directly compared to the other situations in this study. Results High volume PM samples were collected on PTFE filters from a constant volume dilution tunnel. The PM mass emission with HVO was smaller and with RME larger than that with EN590, but both biofuels produced lower PAH contents in emission PM. The DOC + POC catalyst greatly reduced the PM emission and PAH content in PM with both HVO and EN590. Dose-dependent TNFα and MIP-2 responses to all PM samples were mostly at the low or moderate level after 24-hour exposure in a mouse macrophage cell line RAW 264.7. Emission PM from situations with the smallest mass emissions (HVO + cat and CNG) displayed the strongest potency in MIP-2 production. The catalyst slightly decreased the PM-induced TNFα responses and somewhat increased the MIP-2 responses with HVO fuel. Emission PM with EN590 and with 30% HVO blended in EN590 induced the strongest genotoxic responses, which were significantly greater than

  16. Isolation and Characterization of Phenanthrene Degrading Bacteria from Diesel Fuel-Contaminated Antarctic Soils

    PubMed Central

    Gran-Scheuch, Alejandro; Fuentes, Edwar; Bravo, Denisse M.; Jiménez, Juan Cristobal; Pérez-Donoso, José M.

    2017-01-01

    Antarctica is an attractive target for human exploration and scientific investigation, however the negative effects of human activity on this continent are long lasting and can have serious consequences on the native ecosystem. Various areas of Antarctica have been contaminated with diesel fuel, which contains harmful compounds such as heavy metals and polycyclic aromatic hydrocarbons (PAH). Bioremediation of PAHs by the activity of microorganisms is an ecological, economical, and safe decontamination approach. Since the introduction of foreign organisms into the Antarctica is prohibited, it is key to discover native bacteria that can be used for diesel bioremediation. By following the degradation of the PAH phenanthrene, we isolated 53 PAH metabolizing bacteria from diesel contaminated Antarctic soil samples, with three of these isolates exhibiting a high phenanthrene degrading capacity. In particular, the Sphingobium xenophagum D43FB isolate showed the highest phenanthrene degradation ability, generating up to 95% degradation of initial phenanthrene. D43FB can also degrade phenanthrene in the presence of its usual co-pollutant, the heavy metal cadmium, and showed the ability to grow using diesel-fuel as a sole carbon source. Microtiter plate assays and SEM analysis revealed that S. xenophagum D43FB exhibits the ability to form biofilms and can directly adhere to phenanthrene crystals. Genome sequencing analysis also revealed the presence of several genes involved in PAH degradation and heavy metal resistance in the D43FB genome. Altogether, these results demonstrate that S. xenophagum D43FB shows promising potential for its application in the bioremediation of diesel fuel contaminated-Antarctic ecosystems. PMID:28894442

  17. "Diesel siphoner's lung": Exogenous lipoid pneumonia following hydrocarbon aspiration.

    PubMed

    Venkatnarayan, Kavitha; Madan, Karan; Walia, Ritika; Kumar, Jaya; Jain, Deepali; Guleria, Randeep

    2014-01-01

    Lipoid pneumonia is an unusual and uncommon form of pneumonia caused by aspiration of fatty substances. Hydrocarbon pneumonitis following aspiration of diesel is a form of exogenous lipoid pneumonia wherein, aspirated diesel reaches the alveoli rapidly without evoking any significant cough, but initiates an intense inflammatory reaction in the pulmonary parenchyma. This is a rarely described clinical scenario, although the practice of diesel siphonage from automobiles is a common practice in developing countries. We herein describe a 40-year-old male patient, in whom the diagnosis of lipoid pneumonia was delayed for a long duration and highlight the importance of taking a detailed occupational exposure history in patients with non-resolving pneumonia to rule out the underlying possibility of this rare clinical entity.

  18. Recurrence quantification as potential bio-markers for diagnosis of pre-cancer

    NASA Astrophysics Data System (ADS)

    Mukhopadhyay, Sabyasachi; Pratiher, Sawon; Barman, Ritwik; Pratiher, Souvik; Pradhan, Asima; Ghosh, Nirmalya; Panigrahi, Prasanta K.

    2017-03-01

    In this paper, the spectroscopy signals have been analyzed in recurrence plots (RP), and extract recurrence quantification analysis (RQA) parameters from the RP in order to classify the tissues into normal and different precancerous grades. Three RQA parameters have been quantified in order to extract the important features in the spectroscopy data. These features have been fed to different classifiers for classification. Simulation results validate the efficacy of the recurrence quantification as potential bio-markers for diagnosis of pre-cancer.

  19. Combinatorial Nano-Bio Interfaces.

    PubMed

    Cai, Pingqiang; Zhang, Xiaoqian; Wang, Ming; Wu, Yun-Long; Chen, Xiaodong

    2018-06-08

    Nano-bio interfaces are emerging from the convergence of engineered nanomaterials and biological entities. Despite rapid growth, clinical translation of biomedical nanomaterials is heavily compromised by the lack of comprehensive understanding of biophysicochemical interactions at nano-bio interfaces. In the past decade, a few investigations have adopted a combinatorial approach toward decoding nano-bio interfaces. Combinatorial nano-bio interfaces comprise the design of nanocombinatorial libraries and high-throughput bioevaluation. In this Perspective, we address challenges in combinatorial nano-bio interfaces and call for multiparametric nanocombinatorics (composition, morphology, mechanics, surface chemistry), multiscale bioevaluation (biomolecules, organelles, cells, tissues/organs), and the recruitment of computational modeling and artificial intelligence. Leveraging combinatorial nano-bio interfaces will shed light on precision nanomedicine and its potential applications.

  20. Exposure of miners to diesel exhaust particulates in underground nonmetal mines.

    PubMed

    Cohen, H J; Borak, J; Hall, T; Sirianni, G; Chemerynski, S

    2002-01-01

    A study was initiated to examine worker exposures in seven underground nonmetal mines and to examine the precision of the National Institute for Occupational Safety and Health (NIOSH) 5040 sampling and analytical method for diesel exhaust that has recently been adopted for compliance monitoring by the Mine Safety and Health Administration (MSHA). Approximately 1000 air samples using cyclones were taken on workers and in areas throughout the mines. Results indicated that worker exposures were consistently above the MSHA final limit of 160 micrograms/m3 (time-weighted average; TWA) for total carbon as determined by the NIOSH 5040 method and greater than the proposed American Conference of Governmental Industrial Hygienists TLV limit of 20 micrograms/m3 (TWA) for elemental carbon. A number of difficulties were documented when sampling for diesel exhaust using organic carbon: high and variable blank values from filters, a high variability (+/- 20%) from duplicate punches from the same sampling filter, a consistent positive interference (+26%) when open-faced monitors were sampled side-by-side with cyclones, poor correlation (r 2 = 0.38) to elemental carbon levels, and an interference from limestone that could not be adequately corrected by acid-washing of filters. The sampling and analytical precision (relative standard deviation) was approximately 11% for elemental carbon, 17% for organic carbon, and 11% for total carbon. An hypothesis is presented and supported with data that gaseous organic carbon constituents of diesel exhaust adsorb onto not only the submicron elemental carbon particles found in diesel exhaust, but also mining ore dusts. Such mining dusts are mostly nonrespirable and should not be considered equivalent to submicron diesel particulates in their potential for adverse pulmonary effects. It is recommended that size-selective sampling be employed, rather than open-faced monitoring, when using the NIOSH 5040 method.

  1. Performance of Diesel Engine Using Diesel B3 Mixed with Crude Palm Oil

    PubMed Central

    Namliwan, Nattapong; Wongwuttanasatian, Tanakorn

    2014-01-01

    The objective of this study was to test the performance of diesel engine using diesel B3 mixed with crude palm oil in ratios of 95 : 5, 90 : 10, and 85 : 15, respectively, and to compare the results with diesel B3. According to the tests, they showed that the physical properties of the mixed fuel in the ratio of 95 : 5 were closest to those of diesel B3. The performance of the diesel engine that used mixed fuels had 5–17% lower torque and power than that of diesel B3. The specific fuel consumption of mixed fuels was 7–33% higher than using diesel B3. The components of gas emissions by using mixed fuel had 1.6–52% fewer amount of carbon monoxide (CO), carbon dioxide (CO2), sulfur dioxide (SO2), and oxygen (O2) than those of diesel B3. On the other hand, nitric oxide (NO) and nitrogen oxides (NOX) emissions when using mixed fuels were 10–39% higher than diesel B3. By comparing the physical properties, the performance of the engine, and the amount of gas emissions of mixed fuel, we found out that the 95 : 5 ratio by volume was a suitable ratio for agricultural diesel engine (low-speed diesel engine). PMID:24688402

  2. Isolation and characterization of a hydrocarbonoclastic bacterial enrichment from total petroleum hydrocarbon contaminated sediments: potential candidates for bioaugmentation in bio-based processes.

    PubMed

    Di Gregorio, Simona; Siracusa, Giovanna; Becarelli, Simone; Mariotti, Lorenzo; Gentini, Alessandro; Lorenzi, Roberto

    2016-06-01

    Seven hydrocarbonoclastic new bacterial isolates were isolated from dredged sediments of a river estuary in Italy. The sediments were contaminated by shipyard activities since decades, mainly ascribable to the exploitation of diesel oil as the fuel for recreational and commercial navigation of watercrafts. The bacterial isolates were able to utilize diesel oil as sole carbon source. Their metabolic capacities were evaluated by GC-MS analysis, with reference to the depletion of both the normal and branched alkanes, the nC18 fatty acid methyl ester and the unresolved complex mixture of organic compounds. They were taxonomically identified as different species of Stenotrophomonas and Pseudomonas spp. by the combination of amplified ribosomal DNA restriction analysis (ARDRA) and repetitive sequence-based PCR (REP-PCR) analysis. The metabolic activities of interest were analyzed both in relation to the single bacterial strains and to the combination of the latter as a multibacterial species system. After 6 days of incubation in mineral medium with diesel oil as sole carbon source, the Stenotrophomonas sp. M1 strain depleted 43-46 % of Cn-alkane from C28 up to C30, 70 % of the nC18 fatty acid methyl ester and the 46 % of the unresolved complex mixture of organic compounds. On the other hand, the Pseudomonas sp. NM1 strain depleted the 76 % of the nC18 fatty acid methyl ester, the 50 % of the unresolved complex mixture of organic compounds. The bacterial multispecies system was able to completely deplete Cn-alkane from C28 up to C30 and to deplete the 95 % of the unresolved complex mixture of organic compounds. The isolates, either as single strains and as a bacterial multispecies system, were proposed as candidates for bioaugmentation in bio-based processes for the decontamination of dredged sediments.

  3. Anaerobic digestion of palm oil mill effluent (POME) using bio-methane potential (BMP) test

    NASA Astrophysics Data System (ADS)

    Aziz, Nur Izzah Hamna A.; Hanafiah, Marlia M.

    2018-04-01

    Biogas is a promising sustainable and renewable energy alternative to reduce the dependence on fossil fuel. In Malaysia, the conversion of palm oil mill effluent (POME) to bioenergy has recently been expanded due to its high potential in generating energy. However, without a proper treatment and management, POME could be harmful to environment because it emits greenhouse gas emissions into the atmosphere and could also pollutes the watercourses if discharge directly due to the high acidity and chemical oxygen demand (COD) content. Many initiatives have been taken by the government towards sustainable development. Therefore, more efforts need to be practiced to improve and upscale the technology for a better waste management. In this study, the anaerobic digestion of POME was carried out using Bio-methane potential (BMP) test in batch and laboratory scales. Physicochemical characteristics and the biogas production of POME were measured. The BMP test under mesophilic condition was conducted for 23 consecutive days to measure the biogas production. The POME produced 721.3 cm3 of biogas by using anaerobic sludge as inoculum. The results also found that the methane (CH4) and carbon dioxide (CO2) gases produced with 360.65 cm3 and 288.52 cm3, respectively.

  4. Effects of Aftermarket Control Technologies on Gas and Particle Phase Oxidative Potential from Diesel Engine Emissions

    EPA Science Inventory

    Particulate matter (PM) originating from diesel combustion is a public health concern due to its association with adverse effects on respiratory and cardiovascular diseases and lung cancer. This study investigated emissions from three stationary diesel engines (gensets) with var...

  5. Identification of mammalian cell genotoxins in respirable diesel exhaust particles by bioassay-directed chemical analysis.

    PubMed

    Oh, Seung-Min; Chung, Kyu-Hyuck

    2006-03-01

    A bioassay-directed chemical analysis which consists of mammalian cell bioassays (comet assay, CBMN assay and EROD-microbioassay) in conjunction with analytical measurements was performed to identify the most biologically active compounds of the diesel exhaust particulate matters (DEPs) on mutagenic activity. These bioassay systems were suitable to estimate the mammalian genotoxic potentials of pollutants present in low concentrations in limited environmental samples, as is the case with DEPEs. The results from mutagenic assay showed that the aromatic and slightly polar fraction of DEPs induced chromosomal damage and DNA breakage in a non-cytotoxic dose. It was also revealed that indirect-acting mutagens may mainly contribute to the mutagenic effect of aromatic fraction via the enzyme metabolism system. In the aromatic fraction, several indirect-acting mutagenic PAHs such as dibenzo(a,h)anthracene, chrysene, and 1,2-benzanthracene were detected by GC-MS and the complex mixture effect of this fraction was quantified in terms of its biological-TCDD equivalent concentration (bio-TEQ) which was 32.82 bio-TEQ ng/g-DEPs by EROD-microbioassay. Conclusively, we confirmed that indirect-acting mutagens contained in aromatic fraction may be important causatives of the genotoxicity of extracts of DEPs by integrating the results obtained from a mammalian cell bioassay-directed fractionation.

  6. Characterization of preservative and pesticide as potential of bio oil compound from pyrolisis of cocoa shell using gas chromatography

    NASA Astrophysics Data System (ADS)

    Mashuni, Jahiding, M.; Kurniasih, I.; Zulkaidah

    2017-03-01

    Cocoa shell is one of the plant waste that has not been widely used. Cocoa shell is potential as a producer of bio oil because it contains lignocellulose. The bio oil of Liquid volatile matter (LVM) is the products of smoke condensation from the pyrolysis reactor. The bio oil of cocoa shell from pyrolysis process can be made as raw materials for the application of pesticide and preservative. The aims of this research were to produce bio oil from cocoa shell by pyrolysis and analyzing the content using Gas Chromatography (GC). Bio oil production was done by pyrolysis with variations of temperature, i.e. 400, 500, 600 and 700 °C. Pyrolysis reaction generates three products: gas, liquid and solid. The yield of bio oil with variations of pyrolisis temperature, i.e. 400, 500, 600 and 700 °C were obtained i.e. 46, 45, 44 and 40% (v/w), respectively. The chromatogram results showed the chemical components of bio oil from the cocoa shell were ammonia, hexane, alcohol, ketone, acid and phenolic compounds which can be used as material of preservative and pesticide.

  7. Bio-oil from cassava peel: a potential renewable energy source.

    PubMed

    Ki, Ong Lu; Kurniawan, Alfin; Lin, Chun Xiang; Ju, Yi-Hsu; Ismadji, Suryadi

    2013-10-01

    In this work, liquid biofuel (bio-oil) was produced by pyrolizing cassava peel. The experiments were conducted isothermally in a fixed-bed tubular reactor at temperatures ranging from 400 to 600°C with a heating rate of 20°C/min. The chemical compositions of bio-oil were analyzed by a gas chromatography mass spectrometry (GC-MS) technique. For the optimization of liquid product, temperature was plotted to be the most decisive factor. The maximum yield of bio-oil ca. 51.2% was obtained at 525°C and the biofuel has a gross calorific value of 27.43 MJ/kg. The kinetic-based mechanistic model fitted well with experimental yield of pyrolysis products with the mean squared error (MSE) of 13.37 (R(2)=0.96) for solid (char), 16.24 (R(2)=0.95) for liquid (bio-oil), and 0.49 (R(2)=0.99) for gas. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Simulating the injection of micellar solutions to recover diesel in a sand column.

    PubMed

    Bernardez, Letícia A; Therrien, René; Lefebvre, René; Martel, Richard

    2009-01-26

    This paper presents numerical simulations of laboratory experiments where diesel, initially present at 18% residual saturation in a sand column, was recovered by injecting a micellar solution containing the surfactant Hostapur SAS-60 (SAS), and two alcohols, n-butanol (n-BuOH), and n-pentanol (n-PeOH). The micellar solution was developed and optimized for diesel recovery using phase diagrams and soil column experiments. Numerical simulations with the compositional simulator UTCHEM agree with the experimental results and show that the entire residual diesel in the sand column was recovered after the downward injection of 5 pore volumes of the micellar solution. Recovery of diesel occurs by enhanced solubility in the microemulsion phase and by mobilization. An additional series of simulations investigated the effects of phase transfer, alcohol partitioning, and component segregation on diesel recovery. These simulations indicate that diesel can be accurately represented in the model by a single component, but that the pseudo-component approach for active matter and the assumption of local phase equilibrium leads to an underestimation of diesel mobilization.

  9. Simulating the injection of micellar solutions to recover diesel in a sand column

    NASA Astrophysics Data System (ADS)

    Bernardez, Letícia A.; Therrien, René; Lefebvre, René; Martel, Richard

    2009-01-01

    This paper presents numerical simulations of laboratory experiments where diesel, initially present at 18% residual saturation in a sand column, was recovered by injecting a micellar solution containing the surfactant Hostapur SAS-60 (SAS), and two alcohols, n-butanol ( n-BuOH), and n-pentanol ( n-PeOH). The micellar solution was developed and optimized for diesel recovery using phase diagrams and soil column experiments. Numerical simulations with the compositional simulator UTCHEM agree with the experimental results and show that the entire residual diesel in the sand column was recovered after the downward injection of 5 pore volumes of the micellar solution. Recovery of diesel occurs by enhanced solubility in the microemulsion phase and by mobilization. An additional series of simulations investigated the effects of phase transfer, alcohol partitioning, and component segregation on diesel recovery. These simulations indicate that diesel can be accurately represented in the model by a single component, but that the pseudo-component approach for active matter and the assumption of local phase equilibrium leads to an underestimation of diesel mobilization.

  10. Bio-based Polymer Foam from Soyoil

    NASA Astrophysics Data System (ADS)

    Bonnaillie, Laetitia M.; Wool, Richard P.

    2006-03-01

    The growing bio-based polymeric foam industry is presently lead by plant oil-based polyols for polyurethanes and starch foams. We developed a new resilient, thermosetting foam system with a bio-based content higher than 80%. The acrylated epoxidized soybean oil and its fatty acid monomers is foamed with pressurized carbon dioxide and cured with free-radical initiators. The foam structure and pore dynamics are highly dependent on the temperature, viscosity and extent of reaction. Low-temperature cure hinds the destructive pore coalescence and the application of a controlled vacuum results in foams with lower densities ˜ 0.1 g/cc, but larger cells. We analyze the physics of foam formation and stability, as well as the structure and mechanical properties of the cured foam using rigidity percolation theory. The parameters studied include temperature, vacuum applied, and cross-link density. Additives bring additional improvements: nucleating agents and surfactants help produce foams with a high concentration of small cells and low bulk density. Hard and soft thermosetting foams with a bio content superior to 80% are successfully produced and tested. Potential applications include foam-core composites for hurricane-resistant housing, structural reinforcement for windmill blades, and tissue scaffolds.

  11. Experimental study on particulate and NOx emissions of a diesel engine fueled with ultra low sulfur diesel, RME-diesel blends and PME-diesel blends.

    PubMed

    Zhu, Lei; Zhang, Wugao; Liu, Wei; Huang, Zhen

    2010-02-01

    Ultra low sulfur diesel and two different kinds of biodiesel fuels blended with baseline diesel fuel in 5% and 20% v/v were tested in a Cummins 4BTA direct injection diesel engine, with a turbocharger and an intercooler. Experiments were conducted under five engine loads at two steady speeds (1500 rpm and 2500 rpm). The study aims at investigating the engine performance, NO(x) emission, smoke opacity, PM composition, PM size distribution and comparing the impacts of low sulfur content of biodiesel with ULSD on the particulate emission. The results indicate that, compared to base diesel fuel, the increase of biodiesel in blends could cause certain increase in both brake specific fuel consumption and brake thermal efficiency. Compared with baseline diesel fuel, the biodiesel blends bring about more NO(x) emissions. With the proportion of biodiesel increase in blends, the smoke opacity decreases, while total particle number concentration increases. Meanwhile the ULSD gives lower NO(x) emissions, smoke opacity and total number concentration than those of baseline diesel fuel. In addition, the percentages of SOF and sulfate in particulates increase with biodiesel in blends, while the dry soot friction decreases obviously. Compared with baseline diesel fuel, the biodiesel blends increase the total nucleation number concentration, while ULSD reduces the total nucleation number concentration effectively, although they all have lower sulfur content. It means that, for ULSD, the lower sulfur content is the dominant factor for suppressing nucleation particles formation, while for biodiesel blends, lower volatile, lower aromatic content and higher oxygen content of biodiesel are key factors for improving the nucleation particles formation. The results demonstrate that the higher NO(x) emission and total nucleation number concentration are considered as the big obstacles of the application of biodiesel in diesel engine. Copyright 2009 Elsevier B.V. All rights reserved.

  12. Influence of inocula with prior hydrocarbon exposure on biodegradation rates of diesel, synthetic diesel, and fish-biodiesel in soil.

    PubMed

    Horel, Agota; Schiewer, Silke

    2014-08-01

    To achieve effective bioremediation within short warm seasons of cold climates, microbial adaptation periods to the contaminant should be brief. The current study investigated growth phases for soil spiked with diesel, Syntroleum, or fish biodiesel, using microbial inocula adapted to the specific substrates. For modeling hydrocarbon degradation, multi-phase first order kinetics was assumed, comparing linear regression with nonlinear parameter optimization of rate constants and phase durations. Lag phase periods of 5 to >28d were followed by short and intense exponential growth phases with high rate constants (e.g. from kFish=0.0013±0.0002 to kSyntr=0.015±0.001d(-1)). Hydrocarbon mineralization was highest for Syntroleum contamination, where up to three times higher cumulative CO2 production was achieved than for diesel fuel, with fish biodiesel showing initially the slowest degradation. The amount of hydrocarbons recovered from the soil by GC-MS decreased in the order fish biodiesel>diesel>Syntroleum. During initial weeks, biodegradation was higher for microbial inocula adapted to a specific fuel type, whereby the main effect of the inoculum was to shorten the lag phase duration; however, the inoculum's importance diminished after daily respiration peaked. In conclusion, addition of an inoculum to increase biodegradation rates was not necessary. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Particulate matter in new technology diesel exhaust (NTDE) is quantitatively and qualitatively very different from that found in traditional diesel exhaust (TDE).

    PubMed

    Hesterberg, Thomas W; Long, Christopher M; Sax, Sonja N; Lapin, Charles A; McClellan, Roger O; Bunn, William B; Valberg, Peter A

    2011-09-01

    Diesel exhaust (DE) characteristic of pre-1988 engines is classified as a "probable" human carcinogen (Group 2A) by the International Agency for Research on Cancer (IARC), and the U.S. Environmental Protection Agency has classified DE as "likely to be carcinogenic to humans." These classifications were based on the large body of health effect studies conducted on DE over the past 30 or so years. However, increasingly stringent U.S. emissions standards (1988-2010) for particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust have helped stimulate major technological advances in diesel engine technology and diesel fuel/lubricant composition, resulting in the emergence of what has been termed New Technology Diesel Exhaust, or NTDE. NTDE is defined as DE from post-2006 and older retrofit diesel engines that incorporate a variety of technological advancements, including electronic controls, ultra-low-sulfur diesel fuel, oxidation catalysts, and wall-flow diesel particulate filters (DPFs). As discussed in a prior review (T. W. Hesterberg et al.; Environ. Sci. Technol. 2008, 42, 6437-6445), numerous emissions characterization studies have demonstrated marked differences in regulated and unregulated emissions between NTDE and "traditional diesel exhaust" (TDE) from pre-1988 diesel engines. Now there exist even more data demonstrating significant chemical and physical distinctions between the diesel exhaust particulate (DEP) in NTDE versus DEP from pre-2007 diesel technology, and its greater resemblance to particulate emissions from compressed natural gas (CNG) or gasoline engines. Furthermore, preliminary toxicological data suggest that the changes to the physical and chemical composition of NTDE lead to differences in biological responses between NTDE versus TDE exposure. Ongoing studies are expected to address some of the remaining data gaps in the understanding of possible NTDE health effects, but there is now sufficient evidence to conclude that health

  14. Green fuel utilization for diesel engine, combustion and emission analysis fuelled with CNSO diesel blends with Diethyl ether as additive

    NASA Astrophysics Data System (ADS)

    Kumar, Ashok; Rajan, K.; Senthil Kumar, K. R.; Maiyappan, K.; Rasheed, Usama Tariq

    2017-05-01

    The experimental investigation is conducted to evaluate the effects by using Diethyl ether (DEE) as an additive. The Cashew Nut Shell Oil diesel blends (CDB) are tested in a 4-stroke single cylinder DI unmodified diesel engine, rated power is 4.4 kW at a speed of 1500 rpm. The effect of combustion analysis of test fuels on net heat release rate, cylinder pressure, engine power, BSFC, BTE, EGT were observed by the performance tests. The combustion and emission characteristics of a diesel engine with an additive of high cetane number is utilized with CDB and thus investigated. The influence of blends on CO, CO2, HC, NOx and smoke opacity is investigated by emission tests. Initially, the experiment was conducted with different blends of CDB diesel blends like 10%, 20%, & 30% by volume basis in a diesel engine. Among this blends B20 shows reasonable result and heat dissipation rate at full load conditions. The BTE of B20 is 27.52% whereas base diesel fuel is 29.73%. Addition of the DEE by 5%, 10% and 15% by volume basis with B20 which is a base fuel has resulted with improved estimates. The result shows that at full load conditions BTE of B20D10 is 28.96% which is close to the base fuel i.e. B20. The emissions like CO2 shows reducing trends while HC emission rises with increase in CNSO blends. The HC in diesel corresponds to 30ppm and in B20 it is 34ppm, but addition of DEE shows a decreasing trend as in B20D5 has 29ppm and B20D15 has 23ppm respectively. NOx also shows increasing trends with CNSO blend, after addition of DEE it shows declining trend. The NOx for diesel, B20, B30, B20D5, B20D10 and B20D15 emits 1195, 1450, 1511, 1327, 1373 and 1200ppm respectively. The smoke emission is 3.96, 3.38, 3.15 FSN of B20, B20D15 and diesel respectively.

  15. Clean Diesel

    EPA Pesticide Factsheets

    The Clean Diesel Program offers DERA funding in the form of grants and rebates as well as other support for projects that protect human health and improve air quality by reducing harmful emissions from diesel engines.

  16. Dearomatization of diesel oil using Pseudomonas sp.

    PubMed

    Khan, Samiya; Gupta, Sanjay; Gupta, Nidhi

    2018-05-25

    To improve the quality of diesel fuel via removal of aromatic compounds using Pseudomonas sp. In the present study Pseudomonas sp. was able to remove 94% of fluorene, 59% of phenanthrene, 49% of anthracene, 52% of fluoranthene, 45% of pyrene and 75% carbazole present in diesel oil. Additionally, it also does not affect the aliphatic content of fuel thus maintaining the carbon backbone of the fuel. Pseudomonas sp. is a potential biocatalyst that can be used in the refining industry.

  17. Steam bottoming cycle for an adiabatic diesel engine

    NASA Technical Reports Server (NTRS)

    Poulin, E.; Demier, R.; Krepchin, I.; Walker, D.

    1984-01-01

    Steam bottoming cycles using adiabatic diesel engine exhaust heat which projected substantial performance and economic benefits for long haul trucks were studied. Steam cycle and system component variables, system cost, size and performance were analyzed. An 811 K/6.90 MPa state of the art reciprocating expander steam system with a monotube boiler and radiator core condenser was selected for preliminary design. The costs of the diesel with bottoming system (TC/B) and a NASA specified turbocompound adiabatic diesel with aftercooling with the same total output were compared, the annual fuel savings less the added maintenance cost was determined to cover the increase initial cost of the TC/B system in a payback period of 2.3 years. Steam bottoming system freeze protection strategies were developed, technological advances required for improved system reliability are considered and the cost and performance of advanced systes are evaluated.

  18. Thermal barrier coatings application in diesel engines

    NASA Technical Reports Server (NTRS)

    Fairbanks, J. W.

    1995-01-01

    Commercial use of thermal barrier coatings in diesel engines began in the mid 70's by Dr. Ingard Kvernes at the Central Institute for Industrial Research in Oslo, Norway. Dr. Kvernes attributed attack on diesel engine valves and piston crowns encountered in marine diesel engines in Norwegian ships as hot-corrosion attributed to a reduced quality of residual fuel. His solution was to coat these components to reduce metal temperature below the threshold of aggressive hot-corrosion and also provide protection. Roy Kamo introduced thermal barrier coatings in his 'Adiabatic Diesel Engine' in the late 70's. Kamo's concept was to eliminate the engine block water cooling system and reduce heat losses. Roy reported significant performance improvements in his thermally insulated engine at the SAE Congress in 1982. Kamo's work stimulates major programs with insulated engines, particularly in Europe. Most of the major diesel engine manufacturers conducted some level of test with insulated combustion chamber components. They initially ran into increased fuel consumption. The German engine consortium had Prof. Woschni of the Technical Institute in Munich. Woschni conducted testing with pistons with air gaps to provide the insulation effects. Woschni indicated the hot walls of the insulated engine created a major increase in heat transfer he refers to as 'convection vive.' Woschni's work was a major factor in the abrupt curtailment of insulated diesel engine work in continental Europe. Ricardo in the UK suggested that combustion should be reoptimized for the hot-wall effects of the insulated combustion chamber and showed under a narrow range of conditions fuel economy could be improved. The Department of Energy has supported thermal barrier coating development for diesel engine applications. In the Clean Diesel - 50 Percent Efficient (CD-50) engine for the year 2000, thermal barrier coatings will be used on piston crowns and possibly other components. The primary purpose of the

  19. Assessment of on-road emissions of four Euro V diesel and CNG waste collection trucks for supporting air-quality improvement initiatives in the city of Milan.

    PubMed

    Fontaras, Georgios; Martini, Giorgio; Manfredi, Urbano; Marotta, Alessandro; Krasenbrink, Alois; Maffioletti, Francesco; Terenghi, Roberto; Colombo, Mauro

    2012-06-01

    This paper summarizes the results of an extensive experimental study aiming to evaluate the performance and pollutant emissions of diesel and CNG waste collection trucks under realistic and controlled operating conditions in order to support a fleet renewal initiative in the city of Milan. Four vehicles (1 diesel and 3 CNG) were tested in two phases using a portable emission measurement system. The first phase included real world operation in the city of Milan while the second involved controlled conditions in a closed track. Emissions recorded from the diesel truck were on average 2.4 kg/km for CO(2), 0.21 g/km for HC, 7.4 g/km for CO, 32.3 g/km for NO(x) and 46.4 mg/km for PM. For the CNG the values were 3.6 kg/km for CO(2), 2.19 g/km for HC, 15.8 g/km for CO, 4.38 g/km for NO(x) and 11.4 mg/km for PM. CNG vehicles presented an important advantage with regards to NO(x) and PM emissions but lack the efficiency of their diesel counterparts when it comes to CO, HC and particularly greenhouse gas emissions. This tradeoff needs to be carefully analyzed prior to deciding if a fleet should be shifted towards either technology. In addition it was shown that existing emission factors, used in Europe for environmental assessment studies, reflect well the operation for CNG but were not so accurate when it came to the diesel engine truck particularly for CO(2) and NO(x). With regard to NO(x), it was also shown that the limits imposed by current emission standards are not necessarily reflected in real world operation, under which the diesel vehicle presented almost 4 times higher emissions. Regarding CO(2), appropriate use of PEMS data and vehicle information allows for accurate emission monitoring through computer simulation. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. High-alcohol microemulsion fuel performance in a diesel engine

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, B.H.; Compere, A.L.; Griffith, W.L.

    1990-01-01

    Incidence of methanol use in diesel engines is increasing rapidly due to the potential to reduce both diesel particulate emissions and petroleum consumption. Because simple alcohols and conventional diesel fuel are normally immiscible, most tests to date have used neat to near-neat alcohol, or blends incorporating surfactants or other alcohols. Alcohol's poor ignition quality usually necssitates the use of often expensive cetane enhancers, full-time glow plugs, or spark assist. Reported herein are results of screening tests of clear microemulsion and micellar fuels which contain 10 to 65% C{sub 1}--C{sub 4} alcohol. Ignition performance and NO emissions were measured for clear,more » stable fuel blends containing alcohols, diesel fuel and additives such as alkyl nitrates, acrylic acids, and several vegetable oil derivatives. Using a diesel engine calibrated with reference fuels, cetane numbers for fifty four blends were estimated. The apparent cetane numbers ranged from around 20 to above 50 with the majority between 30 and 45. Emissions of nitric oxide were measured for a few select fuels and were found to be 10 to 20% lower than No. 2 diesel fuel. 36 refs., 87 figs., 8 tabs.« less

  1. Low emissions diesel fuel

    DOEpatents

    Compere, Alicia L.; Griffith, William L.; Dorsey, George F.; West, Brian H.

    1998-01-01

    A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  2. Low emissions diesel fuel

    DOEpatents

    Compere, A.L.; Griffith, W.L.; Dorsey, G.F.; West, B.H.

    1998-05-05

    A method and matter of composition for controlling NO{sub x} emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO{sub x} produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  3. Bio-Oil Separation and Stabilization by Supercritical Fluid Fractionation. 2014 Final Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Agblevor, Foster; Petkovic, Lucia; Bennion, Edward

    -oil stabilization by near critical propane extraction had minimal impact in the overall energetics of the process with NER contributions of 0.03. Based on the LCA, the overall conversion pathways were found to be energy intensive with a NER of about 2.3 and 1.2 for catalytic pyrolysis and HTL, respectively. GHG emissions for the catalytic pyrolysis process were greater than that of petroleum diesel at 210 g CO2 eq compared to 18.9 g CO2 eq. Microalgae bio-oil based diesel with thermochemical conversion through HTL meets renewable fuel standards with favorable emission reductions of -10.8 g CO2 eq. The importance of the outcomes is that the critical fluid extraction and stabilization process improved product stability and did so with minimal energy inputs and processing costs. The LCA and GHG emission calculations point toward the HTL pathway as the more favorable thermochemical route towards upgrading algae to bio-fuels. Since the quality of the HTL oil was significantly lower than that of the catalytic pyrolysis bio-oil, the next steps point toward improving the quality of the HTL oils from algae biomass and focusing the critical fluid stabilization on that bio-oil product.« less

  4. Evaluation of factors that affect diesel exhaust toxicity. Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Norbeck, J.M.; Smith, M.R.; Arey, J.

    1998-07-01

    The scope of this project was to obtain a preliminary assessment of the potential impact of the fuel formulation on the speciation and toxic components of diesel exhaust. The test bed was a Cummins L10 engine operating over the heavy-duty transient test cycle using three diesel fuels: a pre-1993 diesel fuel, a low aromatic diesel fuel, and an alternative formulation diesel fuel. The sampling/analysis plan included: determination of the criteria pollutant emission rates (THC, CO, NOx, and PM); determination of PM(10) and PM(2.5) emission rates; collection and analysis of particulate samples for elemental, inorganic ion and elemental/organic carbon analyses; collectionmore » of bas samples for VOC speciation analyses; collection of 2,4-dinitrophenylhydrazine (DNPH) cartridges for determination of oxygenates; collection of nitrosomorpholine with Thermosorb N cartridges; collection of semi-volatiles on PF/XAD and particulate samples for PAH, nitro-PAH, and mutagenicity studies; and collection and analysis of dioxins for the pre-1993 and alternative formulation diesel fuels.« less

  5. BIODIESEL AS A SUSTAINABLE ALTERNATIVE TO PETROLEUM DIESEL IN SCHOOL BUSES

    EPA Science Inventory

    Diesel exhaust is potentially harmful to human health and is a significant air pollutant due to its composition of harmful chemical substances and impact on climate. One of the many current uses of diesel fuel in rural environments is in school buses; however, few studies hav...

  6. Emission reduction potential of using gas-to-liquid and dimethyl ether fuels on a turbocharged diesel engine.

    PubMed

    Xinling, Li; Zhen, Huang

    2009-03-15

    A study of engine performance characteristics and both of regulated (CO, HC, NO(x), and smoke) and unregulated (ultrafine particle number, mass concentrations and size distribution) emissions for a turbocharged diesel engine fueled with conventional diesel, gas-to-liquid (GTL) and dimethyl ether (DME) fuels respectively at different engine loads and speeds have been carried out. The results indicated that fuel components significantly affected the engine performance and regulated/unregulated emissions. GTL exhibited almost the same power and torque output as diesel, while improved fuel economy. GTL significantly reduced regulated emissions with average reductions of 21.2% in CO, 15.7% in HC, 15.6% in NO(x) and 22.1% in smoke in comparison to diesel, as well as average reductions in unregulated emissions of total ultrafine particle number (N(tot)) and mass (M(tot)) emissions by 85.3% and 43.9%. DME can significantly increase torque and power, compared with the original diesel engine, as well as significantly reduced regulated emissions of 40.1% in HC, 48.2% in NO(x) and smoke free throughout all the engine conditions. However, N(tot) for DME is close to that for diesel. The reason is that the accumulation mode particle number emissions for DME are very low due to the characteristics of oxygen content and no C-C bond, which promotes the processes of nucleation and condensation of the semi-volatile compounds in the exhaust gas, as a result, a lot of nucleation mode particles produce.

  7. Energy conservation and money savings through the use of diesel-powered trucks.

    DOT National Transportation Integrated Search

    1980-01-01

    This report presents an analysis of the potential energy and money savings to be achieved from the increased use of class 7, diesel-powered, 4-yard dump trucks by the Department. The technical differences between diesel and gasoline power plants are ...

  8. Reducing Children's Exposure to School Bus Diesel Exhaust in One School District in North Carolina

    ERIC Educational Resources Information Center

    Mazer, Mary E.; Jacobson Vann, Julie C.; Lamanna, Beth F.; Davison, Jean

    2014-01-01

    Children who are exposed to diesel exhaust from idling school buses are at increased risk of asthma exacerbation, decreased lung function, immunologic reactions, leukemia, and increased susceptibility to infections. Policies and initiatives that aim to protect school children from the harmful effects of exposure to diesel exhaust range from…

  9. Screw expander for light duty diesel engines

    NASA Technical Reports Server (NTRS)

    1983-01-01

    Preliminary selection and sizing of a positive displacement screw compressor-expander subsystem for a light-duty adiabatic diesel engine; development of a mathematical model to describe overall efficiencies for the screw compressor and expander; simulation of operation to establish overall efficiency for a range of design parameters and at given engine operating points; simulation to establish potential net power output at light-duty diesel operating points; analytical determination of mass moments of inertia for the rotors and inertia of the compressor-expander subsystem; and preparation of engineering layout drawings of the compressor and expander are discussed. As a result of this work, it was concluded that the screw compressor and expander designed for light-duty diesel engine applications are viable alternatives to turbo-compound systems, with acceptable efficiencies for both units, and only a moderate effect on the transient response.

  10. Comparison of Fuel Economy and Emissions for Diesel and Gasoline Powered Taxicabs

    DOT National Transportation Integrated Search

    1979-07-01

    The objective of this study was to assess potential improvements in fuel economy and exhaust emissions by dieselization of the taxi fleet in a large urban area. Sixty-six diesel powered taxicabs and an equal number of gasoline powered cabs were opera...

  11. Use of Bio-Amp, a commercial bio-additive for the treatment of grease trap wastewater containing fat, oil, and grease.

    PubMed

    Tang, Hao L; Xie, Yuefeng F; Chen, Yen-Chih

    2012-11-01

    This research investigated the application of Bio-Amp, a commercial bio-additive for the treatment of fat, oil, and grease (FOG) in a grease trap, and evaluated potential impacts of treated effluent on downstream collection system and treatment processes. Results show that after Bio-Amp treatment, FOG deposit formation was reduced by 40%, implicating a potential reduction of sewer line blockages. Chemical oxygen demand (COD), total nitrogen (TN), total phosphorus (TP) and total fatty acids were reduced by 39%, 33%, 56%, and 59%, respectively, which represents an overall loading reduction of 9% COD, 5% TN and 40% TP received by the treatment plant from all the dining halls. On the other hand, readily biodegradable COD fractions significantly increased, which implies a potential improvement on Bio-P removal. Overall, the results showed that application of Bio-Amp in grease trap provides potential reduction of sewer line blockages, and can also alleviate downstream treatment burden. Copyright © 2012 Elsevier Ltd. All rights reserved.

  12. Design and Performance of LPG Fuel Mixer for Dual Fuel Diesel Engine

    NASA Astrophysics Data System (ADS)

    Desrial; Saputro, W.; Garcia, P. P.

    2018-05-01

    Small horizontal diesel engines are commonly used for agricultural machinery, however, availability of diesel fuel become one of big problems especially in remote area. Conversely, in line with government policy for conversion of kerosene into LPG for cooking, then LPG become more popular and available even in remote area. Therefore, LPG is potential fuel to replace the shortage of diesel fuel for operating diesel engine in remote area. The purpose of this study was to design mixing device for using dual fuel i.e. LPG and diesel fuel and evaluate its performance accordingly. Simulation by using CFD was done in order to analyze mixture characteristics of LPG in air intake manifold. The performance test was done by varying the amount of LPG injected in intake air at 20%, 25%, 30%, 35%, until 40%, respectively. Result of CFD contour simulation showed the best combination when mixing 30% LPG into the intake air. Performance test of this research revealed that mixing LPG in air intake can reduce the diesel fuel consumption about 0.7 l/hour (without load) and 1.14 l/hour (with load). Diesel engine revolution increases almost 300 rpm faster than when using diesel fuel only. Based on economic analysis, using the fuel combination (diesel fuel – LPG) is not recommended in the area near SPBU where the price of diesel fuel is standard. However, using the fuel combination LPG-diesel fuel is highly recommended in the remote areas in Indonesia where price of diesel fuel is comparatively expensive which will provide cheaper total fuel cost for diesel engine operation.

  13. Diesels in combined cycle

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuehn, S.E.

    1995-03-01

    This article examines why the diesel engine is a very attractive choice for producing power in the combined-cycle configuration. The medium-speed diesel is already one of the most efficient simple cycle sources of electricity, especially with lower grade fuels. Large units have heat-rate efficiencies as high as 45%, equating to a heat rate of 7,580 Btu/k Whr, and no other power production prime mover can match this efficiency. Diesels also offer designers fuel flexibility and can burn an extreme variety of fuels without sacrificing many of its positive operating attributes. Diesels are the first building block in a highly efficientmore » combined cycle system that relies on the hot gas and oxygen in the diesel`s exhaust to combust either natural gas, light distillate oil, heavy oil or coal, in a boiler. By using a fired boiler, steam can be generated at sufficient temperature and pressure to operate a Rankine steam cycle efficiently. Diesel combined-cycle plants can be configured in much the same way a gas turbine plant would be. However, the diesel combined-cycle scheme requires supplemental firing to generate appropriate steam conditions. The most efficient cycle, therefore, would not be achieved until combustion air and supplemental fuel are minimized to levels that satisfy steam conditions, steam generation and power generation constraints.« less

  14. Trend and future of diesel engine: Development of high efficiency and low emission low temperature combustion diesel engine

    NASA Astrophysics Data System (ADS)

    Ho, R. J.; Yusoff, M. Z.; Palanisamy, K.

    2013-06-01

    Stringent emission policy has put automotive research & development on developing high efficiency and low pollutant power train. Conventional direct injection diesel engine with diffused flame has reached its limitation and has driven R&D to explore other field of combustion. Low temperature combustion (LTC) and homogeneous charge combustion ignition has been proven to be effective methods in decreasing combustion pollutant emission. Nitrogen Oxide (NOx) and Particulate Matter (PM) formation from combustion can be greatly suppressed. A review on each of method is covered to identify the condition and processes that result in these reductions. The critical parameters that allow such combustion to take place will be highlighted and serves as emphasis to the direction of developing future diesel engine system. This paper is written to explore potential of present numerical and experimental methods in optimizing diesel engine design through adoption of the new combustion technology.

  15. Application of biosurfactants, rhamnolipid, and surfactin, for enhanced biodegradation of diesel-contaminated water and soil.

    PubMed

    Whang, Liang-Ming; Liu, Pao-Wen G; Ma, Chih-Chung; Cheng, Sheng-Shung

    2008-02-28

    This study investigated potential application of two biosurfactants, surfactin (SF) and rhamnolipid (RL), for enhanced biodegradation of diesel-contaminated water and soil with a series of bench-scale experiments. The rhamnolipid used in this study, a commonly isolated glycolipid biosurfactant, was produced by Pseudomonas aeruginosa J4, while the surfactin, a lipoprotein type biosurfactant, was produced by Bacillus subtilis ATCC 21332. Both biosurfactants were able to reduce surface tension to less than 30 dynes/cm from 72 dynes/cm with critical micelle concentration (CMC) values of 45 and 50 mg/L for surfactin and rhamnolipid, respectively. In addition, the results of diesel dissolution experiments also demonstrated their ability in increasing diesel solubility with increased biosurfactant addition. In diesel/water batch experiments, an addition of 40 mg/L of surfactin significantly enhanced biomass growth (2500 mg VSS/L) as well as increased diesel biodegradation percentage (94%), compared to batch experiments with no surfactin addition (1000 mg VSS/L and 40% biodegradation percentage). Addition of surfactin more than 40 mg/L, however, decreased both biomass growth and diesel biodegradation efficiency, with a worse diesel biodegradation percentage (0%) at 400 mg/L of SF addition. Similar trends were also observed for both specific rate constants of biomass growth and diesel degradation, as surfactin addition increased from 0 to 400 mg/L. Addition of rhamnolipid to diesel/water systems from 0 to 80 mg/L substantially increased biomass growth and diesel biodegradation percentage from 1000 to 2500 mg VSS/L and 40 to 100%, respectively. Rhamnolipid addition at a concentration of 160 mg/L provided similar results to those of an 80 mg/L addition. Finally, potential application of surfactin and rhamnolipid in stimulating indigenous microorganisms for enhanced bioremediation of diesel-contaminated soil was also examined. The results confirmed their enhancing capability

  16. Diesel Vehicle Maintenance Competencies.

    ERIC Educational Resources Information Center

    Braswell, Robert; And Others

    Designed to provide a model set of competencies, this manual presents tasks which were identified by employers, employees, and teachers as important in a postsecondary diesel vehicle maintenance curriculum. The tasks are divided into seven major component areas of instruction: chassis and suspension, diesel engines, diesel fuel, electrical,…

  17. Fine urban and precursor emissions control for diesel urban transit buses.

    PubMed

    Lanni, Thomas

    2003-01-01

    Particulate emission from diesel engines is one of the most important pollutants in urban areas. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled "Clean Diesel Air Quality Demonstration Program" has been initiated by the New York City Metropolitan Transit Authority (MTA) under the supervision of New York State Department of Environmental Conservation and with active participation from Johnson Matthey, Corning, Equilon, Environment Canada and RAD Energy. Under this program, several MTA transit buses with DDC Series 50 engines were equipped with Continuously Regenerating Technology (CRTTM) particulate filter systems and have been operated with ultra low sulfur diesel (<30 ppm S) in transit service in Manhattan since February 2000. These buses were evaluated over a 9-month period for durability and maintainability of the particulate filter. In addition, an extensive emissions testing program was carried out using transient cycles on a chassis dynamometer to evaluate the emissions reductions obtained with the particle filter. In this paper, the emissions testing data from the Clean Diesel Air Quality Demonstration Program are discussed in detail.

  18. 40 CFR 80.522 - May used motor oil be dispensed into diesel motor vehicles or nonroad diesel engines?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... diesel motor vehicles or nonroad diesel engines? 80.522 Section 80.522 Protection of Environment... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Motor Vehicle Diesel Fuel Standards and Requirements § 80.522 May used motor oil be dispensed into diesel motor...

  19. 40 CFR 80.522 - May used motor oil be dispensed into diesel motor vehicles or nonroad diesel engines?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... diesel motor vehicles or nonroad diesel engines? 80.522 Section 80.522 Protection of Environment... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Motor Vehicle Diesel Fuel Standards and Requirements § 80.522 May used motor oil be dispensed into diesel motor...

  20. Effect of Alcohol on Diesel Engine Combustion Operating with Biodiesel-Diesel Blend at Idling Conditions

    NASA Astrophysics Data System (ADS)

    Mahmudul, H. M.; Hagos, Ftwi. Y.; A, M. Mukhtar N.; Mamat, Rizalman; Abdullah, A. Adam

    2018-03-01

    Biodiesel is a promising alternative fuel to run the automotive engine. However, its blends have not been properly investigated during idling as it is the main problem to run the vehicles in a big city. The purpose of this study is to evaluate the impact of alcohol additives such as butanol and ethanol on combustion parameters under idling conditions when a single cylinder diesel engine operates with diesel, diesel-biodiesel blends, and diesel biodiesel-alcohol blends. The engine combustion parameters such as peak pressure, heat release rate and ignition delay were computed. This investigation has revealed that alcohol blends with diesel and biodiesel, BU20 blend yield higher maximum peak cylinder pressure than diesel. B5 blend was found with the lowest energy release among all. B20 was slightly lower than diesel. BU20 blend was seen with the highest peak energy release where E20 blend was found advance than diesel. Among all, the blends alcohol component revealed shorter ignition delay. B5 and B20 blends were influenced by biodiesel interference and the burning fraction were found slightly slower than conventional diesel where BU20 and E20 blends was found slightly faster than diesel So, based on the result, it can be said that among the alcohol blends butanol and ethanol can be promising alternative at idling conditions and can be used without any engine modifications.

  1. An ex situ evaluation of TBA- and MTBE-baited bio-traps.

    PubMed

    North, Katharine P; Mackay, Douglas M; Annable, Michael D; Sublette, Kerry L; Davis, Greg; Holland, Reef B; Petersen, Daniel; Scow, Kate M

    2012-08-01

    Aquifer microbial communities can be investigated using Bio-traps(®) ("bio-traps"), passive samplers containing Bio-Sep(®) beads ("bio-beads") that are deployed in monitoring wells to be colonized by bacteria delivered via groundwater flow through the well. When bio-beads are "baited" with organic contaminants enriched in (13)C, stable isotope probing allows assessment of the composition and activity of the microbial community. This study used an ex situ system fed by groundwater continuously extracted from an adjacent monitoring well within an experimentally-created aerobic zone treating a tert-butyl alcohol (TBA) plume. The goal was to evaluate aspects of bio-trap performance that cannot be studied quantitatively in situ. The measured groundwater flow through a bio-trap housing suggests that such traps might typically "sample" about 1.8 L per month. The desorption of TBA or methyl tert-butyl ether (MTBE) bait from bio-traps during a typical deployment duration of 6 weeks was approximately 90% and 45%, respectively, of the total initial bait load, with initially high rate of mass loss that decreased markedly after a few days. The concentration of TBA in groundwater flowing by the TBA-baited bio-beads was estimated to be as high as 3400 mg/L during the first few days, which would be expected to inhibit growth of TBA-degrading microbes. Initial inhibition was also implied for the MTBE-baited bio-trap, but at lower concentrations and for a shorter time. After a few days, concentrations in groundwater flowing through the bio-traps dropped below inhibitory concentrations but remained 4-5 orders of magnitude higher than TBA or MTBE concentrations within the aquifer at the experimental site. Desorption from the bio-beads during ex situ deployment occurred at first as predicted by prior sorption analyses of bio-beads but with apparent hysteresis thereafter, possibly due to mass transfer limitations caused by colonizing microbes. These results suggest that TBA- or MTBE

  2. An ex situ evaluation of TBA- and MTBE-baited bio-traps

    PubMed Central

    North, Katharine P.; Mackay, Douglas M.; Annable, Michael D.; Sublette, Kerry L.; Davis, Greg; Holland, Reef B.; Petersen, Daniel; Scow, Kate M.

    2013-01-01

    Aquifer microbial communities can be investigated using Bio-traps® (“bio-traps”), passive samplers containing Bio-Sep® beads (“bio-beads”) that are deployed in monitoring wells to be colonized by bacteria delivered via groundwater flow through the well. When bio-beads are “baited” with organic contaminants enriched in 13C, stable isotope probing allows assessment of the composition and activity of the microbial community. This study used an ex situ system fed by groundwater continuously extracted from an adjacent monitoring well within an experimentally-created aerobic zone treating a tert-butyl alcohol (TBA) plume. The goal was to evaluate aspects of bio-trap performance that cannot be studied quantitatively in situ. The measured groundwater flow through a bio-trap housing suggests that such traps might typically “sample” about 1.8 L per month. The desorption of TBA or methyl tert-butyl ether (MTBE) bait from bio-traps during a typical deployment duration of 6 weeks was approximately 90% and 45%, respectively, of the total initial bait load, with initially high rate of mass loss that decreased markedly after a few days. The concentration of TBA in groundwater flowing by the TBA-baited bio-beads was estimated to be as high as 3400 mg/L during the first few days, which would be expected to inhibit growth of TBA-degrading microbes. Initial inhibition was also implied for the MTBE-baited bio-trap, but at lower concentrations and for a shorter time. After a few days, concentrations in groundwater flowing through the bio-traps dropped below inhibitory concentrations but remained 4–5 orders of magnitude higher than TBA or MTBE concentrations within the aquifer at the experimental site. Desorption from the bio-beads during ex situ deployment occurred at first as predicted by prior sorption analyses of bio-beads but with apparent hysteresis thereafter, possibly due to mass transfer limitations caused by colonizing microbes. These results suggest that

  3. COMPARATIVE STUDY ON EXHAUST EMISSIONS FROM DIESEL- AND CNG-POWERED URBAN BUSES

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    COROLLER, P; PLASSAT, G

    2003-08-24

    Couple years ago, ADEME engaged programs dedicated to the urban buses exhaust emissions studies. The measures associated with the reduction of atmospheric and noise pollution has particular importance in the sector of urban buses. In many cases, they illustrate the city's environmental image and contribute to reinforcing the attractiveness of public transport. France's fleet in service, presently put at about 14,000 units, consumes about 2 per cent of the total energy of city transport. It causes about 2 per cent of the HC emissions and from 4 to 6 per cent of the NOx emissions and particles. These vehicles typicallymore » have a long life span (about 15 years) and are relatively expensive to buy, about 150.000 euros per unit. Several technical solutions were evaluated to quantify, on a real condition cycle for buses, on one hand pollutants emissions, fuel consumption and on the other hand reliability, cost in real existing fleet. This paper presents main preliminary results on urban buses exhaust emission on two different cases: - existing Diesel buses, with fuel modifications (Diesel with low sulphur content), Diesel with water emulsion and bio-Diesel (30% oil ester in standard Diesel fuel); renovating CNG powered Euro II buses fleet, over representative driving cycles, set up by ADEME and partners. On these cycles, pollutants (regulated and unregulated) were measured as well as fuel consumption, at the beginning of a program and one year after to quantify reliability and increase/decrease of pollutants emissions. At the same time, some after-treatment technologies were tested under real conditions and several vehicles. Information such as fuel consumption, lubricant analysis, problem on the technology were following during a one year program. On the overall level, it is the combination of various action, pollution-reduction and renewal that will make it possible to meet the technological challenge of reducing emissions and fuel consumption by urban bus

  4. New perspectives for advanced automobile diesel engines

    NASA Technical Reports Server (NTRS)

    Tozzi, L.; Sekar, R.; Kamo, R.; Wood, J. C.

    1983-01-01

    Computer simulation results are presented for advanced automobile diesel engine performance. Four critical factors for performance enhancement were identified: (1) part load preheating and exhaust gas energy recovery, (2) fast heat release combustion process, (3) reduction in friction, and (4) air handling system efficiency. Four different technology levels were considered in the analysis. Simulation results are compared in terms of brake specific fuel consumption and vehicle fuel economy in km/liter (miles per gallon). Major critical performance sensitivity areas are: (1) combustion process, (2) expander and compressor efficiency, and (3) part load preheating and compound system. When compared to the state of the art direct injection, cooled, automobile diesel engine, the advanced adiabatic compound engine concept showed the unique potential of doubling the fuel economy. Other important performance criteria such as acceleration, emissions, reliability, durability and multifuel capability are comparable to or better than current passenger car diesel engines.

  5. [Bio-Resources and Database for Preemptive Medicine.

    PubMed

    Saito, Kuniaki

    2016-05-01

    Establishing a primary defense for the improvement of individual quality of life by epidemiology and various clinical studies applying bio-resources/database analysis is very important. Furthermore, recent studies on understanding the epigenetic regulatory mechanisms of developmental origins of health and diseases are attracting increasing interest. Therefore, the storing of not only bio-fluid (i.e., blood, urine) but also certain tissues (i.e., placenta, cord) is very important for research. The Resource Center for Health Science (RECHS) and Bio-databases Institute of Reproductive and Developmental Medicine (BIRD) have estab- lished Bio-bank and initiated a project based on the development and utilization of bio-resources/database, comprising personal health records (PHR), such as health/medical records including individual records of daily diet and exercise, physically consolidated with bio-resources, taken from the same individuals. These Bio-Resources/Database projects are very important for the establishment of preemptive medicine and un- derstanding the mechanisms of the developmental origins of health and diseases.

  6. Clinical application of bio ceramics

    NASA Astrophysics Data System (ADS)

    Anu, Sharma; Gayatri, Sharma

    2016-05-01

    Ceramics are the inorganic crystalline material. These are used in various field such as biomedical, electrical, electronics, aerospace, automotive and optical etc. Bio ceramics are the one of the most active areas of research. Bio ceramics are the ceramics which are biocompatible. The unique properties of bio ceramics make them an attractive option for medical applications and offer some potential advantages over other materials. During the past three decades, a number of major advances have been made in the field of bio ceramics. This review focuses on the use of these materials in variety of clinical scenarios.

  7. Clinical application of bio ceramics

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anu, Sharma, E-mail: issaranu@gmail.com; Gayatri, Sharma, E-mail: sharmagayatri@gmail.com

    Ceramics are the inorganic crystalline material. These are used in various field such as biomedical, electrical, electronics, aerospace, automotive and optical etc. Bio ceramics are the one of the most active areas of research. Bio ceramics are the ceramics which are biocompatible. The unique properties of bio ceramics make them an attractive option for medical applications and offer some potential advantages over other materials. During the past three decades, a number of major advances have been made in the field of bio ceramics. This review focuses on the use of these materials in variety of clinical scenarios.

  8. The Diesel Exhaust in Miners Study: A Nested Case–Control Study of Lung Cancer and Diesel Exhaust

    PubMed Central

    Samanic, Claudine M.; Lubin, Jay H.; Blair, Aaron E.; Stewart, Patricia A.; Vermeulen, Roel; Coble, Joseph B.; Rothman, Nathaniel; Schleiff, Patricia L.; Travis, William D.; Ziegler, Regina G.; Wacholder, Sholom; Attfield, Michael D.

    2012-01-01

    Background Most studies of the association between diesel exhaust exposure and lung cancer suggest a modest, but consistent, increased risk. However, to our knowledge, no study to date has had quantitative data on historical diesel exposure coupled with adequate sample size to evaluate the exposure–response relationship between diesel exhaust and lung cancer. Our purpose was to evaluate the relationship between quantitative estimates of exposure to diesel exhaust and lung cancer mortality after adjustment for smoking and other potential confounders. Methods We conducted a nested case–control study in a cohort of 12 315 workers in eight non-metal mining facilities, which included 198 lung cancer deaths and 562 incidence density–sampled control subjects. For each case subject, we selected up to four control subjects, individually matched on mining facility, sex, race/ethnicity, and birth year (within 5 years), from all workers who were alive before the day the case subject died. We estimated diesel exhaust exposure, represented by respirable elemental carbon (REC), by job and year, for each subject, based on an extensive retrospective exposure assessment at each mining facility. We conducted both categorical and continuous regression analyses adjusted for cigarette smoking and other potential confounding variables (eg, history of employment in high-risk occupations for lung cancer and a history of respiratory disease) to estimate odds ratios (ORs) and 95% confidence intervals (CIs). Analyses were both unlagged and lagged to exclude recent exposure such as that occurring in the 15 years directly before the date of death (case subjects)/reference date (control subjects). All statistical tests were two-sided. Results We observed statistically significant increasing trends in lung cancer risk with increasing cumulative REC and average REC intensity. Cumulative REC, lagged 15 years, yielded a statistically significant positive gradient in lung cancer risk overall

  9. The Diesel Exhaust in Miners study: a nested case-control study of lung cancer and diesel exhaust.

    PubMed

    Silverman, Debra T; Samanic, Claudine M; Lubin, Jay H; Blair, Aaron E; Stewart, Patricia A; Vermeulen, Roel; Coble, Joseph B; Rothman, Nathaniel; Schleiff, Patricia L; Travis, William D; Ziegler, Regina G; Wacholder, Sholom; Attfield, Michael D

    2012-06-06

    Most studies of the association between diesel exhaust exposure and lung cancer suggest a modest, but consistent, increased risk. However, to our knowledge, no study to date has had quantitative data on historical diesel exposure coupled with adequate sample size to evaluate the exposure-response relationship between diesel exhaust and lung cancer. Our purpose was to evaluate the relationship between quantitative estimates of exposure to diesel exhaust and lung cancer mortality after adjustment for smoking and other potential confounders. We conducted a nested case-control study in a cohort of 12 315 workers in eight non-metal mining facilities, which included 198 lung cancer deaths and 562 incidence density-sampled control subjects. For each case subject, we selected up to four control subjects, individually matched on mining facility, sex, race/ethnicity, and birth year (within 5 years), from all workers who were alive before the day the case subject died. We estimated diesel exhaust exposure, represented by respirable elemental carbon (REC), by job and year, for each subject, based on an extensive retrospective exposure assessment at each mining facility. We conducted both categorical and continuous regression analyses adjusted for cigarette smoking and other potential confounding variables (eg, history of employment in high-risk occupations for lung cancer and a history of respiratory disease) to estimate odds ratios (ORs) and 95% confidence intervals (CIs). Analyses were both unlagged and lagged to exclude recent exposure such as that occurring in the 15 years directly before the date of death (case subjects)/reference date (control subjects). All statistical tests were two-sided. We observed statistically significant increasing trends in lung cancer risk with increasing cumulative REC and average REC intensity. Cumulative REC, lagged 15 years, yielded a statistically significant positive gradient in lung cancer risk overall (P (trend) = .001); among heavily

  10. DNA adducts induced by in vitro activation of diesel and biodiesel exhaust extracts

    EPA Science Inventory

    The abstract reports the results of studies assessing the relative DNA damage potential of extracts of exhaust particles resulting from the combustion of petroleum diesel, biodiesel, and petroleum diesel-biodiesel blends. Results indicate that the commercially available B20 petr...

  11. Potential improvement to a citric wastewater treatment plant using bio-hydrogen and a hybrid energy system

    NASA Astrophysics Data System (ADS)

    Zhi, Xiaohua; Yang, Haijun; Berthold, Sascha; Doetsch, Christian; Shen, Jianquan

    Treatment of highly concentrated organic wastewater is characterized as cost-consuming. The conventional technology uses the anaerobic-anoxic-oxic process (A 2/O), which does not produce hydrogen. There is potential for energy saving using hydrogen utilization associated with wastewater treatment because hydrogen can be produced from organic wastewater using anaerobic fermentation. A 50 m 3 pilot bio-reactor for hydrogen production was constructed in Shandong Province, China in 2006 but to date the hydrogen produced has not been utilized. In this work, a technical-economic model based on hydrogen utilization is presented and analyzed to estimate the potential improvement to a citric wastewater plant. The model assesses the size, capital cost, annual cost, system efficiency and electricity cost under different configurations. In a stand-alone situation, the power production from hydrogen is not sufficient for the required load, thus a photovoltaic array (PV) is employed as the power supply. The simulated results show that the combination of solar and bio-hydrogen has a much higher cost compared with the A 2/O process. When the grid is connected, the system cost achieved is 0.238 US t -1 wastewater, which is lower than 0.257 US t -1 by the A 2/O process. The results reveal that a simulated improvement by using bio-hydrogen and a FC system is effective and feasible for the citric wastewater plant, even when compared to the current cost of the A 2/O process. In addition, lead acid and vanadium flow batteries were compared for energy storage service. The results show that a vanadium battery has lower cost and higher efficiency due to its long lifespan and energy efficiency. Additionally, the cost distribution of components shows that the PV dominates the cost in the stand-alone situation, while the bio-reactor is the main cost component in the parallel grid.

  12. Response characteristics of stable mixed-potential NH 3 sensors in diesel engine exhaust

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brosha, Eric L.; Prikhodko, Vitaly Y.; Kreller, Cortney R.

    Here, a mixed-potential, electrochemical sensor platform is extended to NH 3 sensing by the introduction of a new gold alloy working electrode. A planar, pre-commercial NH 3 sensor utilized LANL’s controlled interface approach, and a Pd-Au alloy working electrode was tested in exhaust of a GM 1.9 L diesel engine downstream of a diesel oxidation catalyst through a slipstream arrangement. A fraction of the exhaust was pulled across the sensor with a pump at 20 L/min. In order to simulate NH 3 slip inside of a full SCR emissions control system, NH 3 was injected immediately upstream of the sensormore » using a calibrated mass flow controller. The sensor response quantitatively tracked the NH 3 as measured via Fourier transform infrared (FTIR) analyzer. A calibration curve was obtained in the exhaust from an ammonia staircase response with the engine running at steady-state engine conditions resulting in low background concentrations of NO x and HC (<20 ppm) during calibration. Exhaust gas recirculation (EGR) switching and sweeps were used to evaluate the NH 3 sensor response under different amounts of total background NO x. The calibration curve was used to directly compare the [NH 3] calculated from sensor response to the gas phase composition measured via FTIR. In general, there was excellent quantitative agreement between the sensor response and the actual NH 3 in the exhaust gas, and fast response time such that transients (<5 ppm) could be easily discerned from baseline. A LANL pre-commercial NO x sensor was tested simultaneously with the NH 3 sensor and the extent of cross-sensitivity between the two sensors will be discussed.« less

  13. Response characteristics of stable mixed-potential NH 3 sensors in diesel engine exhaust

    DOE PAGES

    Brosha, Eric L.; Prikhodko, Vitaly Y.; Kreller, Cortney R.; ...

    2016-10-20

    Here, a mixed-potential, electrochemical sensor platform is extended to NH 3 sensing by the introduction of a new gold alloy working electrode. A planar, pre-commercial NH 3 sensor utilized LANL’s controlled interface approach, and a Pd-Au alloy working electrode was tested in exhaust of a GM 1.9 L diesel engine downstream of a diesel oxidation catalyst through a slipstream arrangement. A fraction of the exhaust was pulled across the sensor with a pump at 20 L/min. In order to simulate NH 3 slip inside of a full SCR emissions control system, NH 3 was injected immediately upstream of the sensormore » using a calibrated mass flow controller. The sensor response quantitatively tracked the NH 3 as measured via Fourier transform infrared (FTIR) analyzer. A calibration curve was obtained in the exhaust from an ammonia staircase response with the engine running at steady-state engine conditions resulting in low background concentrations of NO x and HC (<20 ppm) during calibration. Exhaust gas recirculation (EGR) switching and sweeps were used to evaluate the NH 3 sensor response under different amounts of total background NO x. The calibration curve was used to directly compare the [NH 3] calculated from sensor response to the gas phase composition measured via FTIR. In general, there was excellent quantitative agreement between the sensor response and the actual NH 3 in the exhaust gas, and fast response time such that transients (<5 ppm) could be easily discerned from baseline. A LANL pre-commercial NO x sensor was tested simultaneously with the NH 3 sensor and the extent of cross-sensitivity between the two sensors will be discussed.« less

  14. Pyrolysis of hornbeam (Carpinus betulus L.) sawdust: Characterization of bio-oil and bio-char.

    PubMed

    Moralı, Uğur; Yavuzel, Nazan; Şensöz, Sevgi

    2016-12-01

    Slow pyrolysis of hornbeam (Carpinus betulus L.) sawdust was performed to produce bio-oil and bio-char. The operational variables were as follows: pyrolysis temperature (400-600°C), heating rate (10-50°Cmin -1 ) and nitrogen flow rate (50-150cm 3 min -1 ). Physicochemical and thermogravimetric characterizations of hornbeam sawdust were performed. The characteristics of bio-oil and bio-char were analyzed on the basis of various spectroscopic and chromatographic techniques such as FTIR, GC-MS, 1H NMR, SEM, BET. Higher heating value, density and kinematic viscosity of the bio-oil with maximum yield of 35.28% were 23.22MJkg -1 , 1289kgm -3 and 0.6mm 2 s -1 , respectively. The bio-oil with relatively high fuel potential can be obtained from the pyrolysis of the hornbeam sawdust and the bio-char with a calorific value of 32.88MJkg -1 is a promising candidate for solid fuel applications that also contributes to the preservation of the environment. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Electrical diesel particulate filter (DPF) regeneration

    DOEpatents

    Gonze, Eugene V; Ament, Frank

    2013-12-31

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is disposed upstream of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  16. Reducing diesel NOx and PM emissions of diesel buses and trucks.

    DOT National Transportation Integrated Search

    2008-07-01

    The objective of the present investigation was development of a high efficiency : selective catalytic reduction (SCR) system for reducing diesel nitrogen oxides (NOx) and : particulate matters of diesel trucks. The investigation was divided into two ...

  17. In Vivo Assessment of the Potential for Renal Bio-Effects from the Vaporization of Perfluorocarbon Phase-Change Contrast Agents.

    PubMed

    Nyankima, A Gloria; Rojas, Juan D; Cianciolo, Rachel; Johnson, Kennita A; Dayton, Paul A

    2018-02-01

    Low-boiling-point perfluorocarbon phase-change contrast agents (PCCAs) provide an alternative to microbubble contrast agents. Although parameter ranges related to in vivo bio-effects of microbubbles are fairly well characterized, few studies have been done to evaluate the potential of bio-effects related to PCCAs. To bridge this gap, we present an assessment of biological effects (e.g., hemorrhage) related to acoustically excited PCCAs in the rodent kidney. The presence or absence of bio-effects was observed after sonication with various perfluorocarbon core PCCAs (decafluorobutane, octafluoropropane or a 1:1 mixture) and as a function of activation pulse mechanical index (MI; minimum activation threshold, which was a moderate MI of 0.81-1.35 vs. a clinical maximum of 1.9). Bio-effects on renal tissue were assessed through hematology and histology including measurement of blood creatinine levels and the quantity of red blood cell (RBC) casts present in hematoxylin and eosin-stained kidney tissue sections after sonication. Short-term (24 h) and long-term (2 and 4 wk) analyses were performed after treatment. Results indicated that bio-effects from PCCA vaporization were not observed at lower mechanical indices. At higher mechanical indices, bio-effects were observed at 24 h, although these were not observable 2 wk after treatment. Copyright © 2018. Published by Elsevier Inc.

  18. Genotoxic potential of organic extracts from particle emissions of diesel and rapeseed oil powered engines.

    PubMed

    Topinka, Jan; Milcova, Alena; Schmuczerova, Jana; Mazac, Martin; Pechout, Martin; Vojtisek-Lom, Michal

    2012-07-07

    The present study was performed to identify possible genotoxicity induced by organic extracts from particulate matter in the exhaust of two typical diesel engines run on diesel fuel and neat heated fuel-grade rapeseed oil: a Cummins ISBe4 engine tested using the World Harmonized Steady State Test Cycle (WHSC) and modified Engine Steady Cycle (ESC) and a Zetor 1505 engine tested using the Non-Road Steady State Cycle (NRSC). In addition, biodiesel B-100 (neat methylester of rapeseed oil) was tested in the Cummins engine run on the modified ESC. Diluted exhaust was sampled with high-volume samplers on Teflon coated filters. Filters were extracted with dichlormethane (DCM) and DNA adduct levels induced by extractable organic matter (EOM) in an acellular assay of calf thymus DNA coupled with (32)P-postlabeling in the presence and absence of rat liver microsomal S9 fraction were employed. Simultaneously, the chemical analysis of 12 priority PAHs in EOM, including 7 carcinogenic PAHs (c-PAHs) was performed. The results suggest that diesel emissions contain substantially more total PAHs than rapeseed oil emissions (for the ESC) or that these concentrations were comparable (for the WHSC and NRSC), while c-PAHs levels were comparable (for the ESC) or significantly higher (for the WHSC and NRSC) for rapeseed oil emissions. DNA adduct levels induced by diesel and rapeseed oil derived EOM were comparable, but consistently slightly higher for diesel than for rapeseed oil. Highly significant correlations were found between 12 priority PAHs concentrations and DNA adduct levels (0.980; p<0.001) and these correlations were even stronger for c-PAHs (0.990; p<0.001). Metabolic activation by the microsomal S9 fraction resulted in several fold higher genotoxicity, suggesting a major contribution of PAHs to genotoxicity. Directly acting compounds, other than c-PAHs, and not requiring S9 to exhibit DNA reactivity were also significant. Generally, DNA adduct levels were more dependent on

  19. Permeable bio-reactive barriers to address petroleum hydrocarbon contamination at subantarctic Macquarie Island.

    PubMed

    Freidman, Benjamin L; Terry, Deborah; Wilkins, Dan; Spedding, Tim; Gras, Sally L; Snape, Ian; Stevens, Geoffrey W; Mumford, Kathryn A

    2017-05-01

    A reliance on diesel generated power and a history of imperfect fuel management have created a legacy of petroleum hydrocarbon contamination at subantarctic Macquarie Island. Increasing environmental awareness and advances in contaminant characterisation and remediation technology have fostered an impetus to reduce the environmental risk associated with legacy sites. A funnel and gate permeable bio-reactive barrier (PRB) was installed in 2014 to address the migration of Special Antarctic Blend diesel from a spill that occurred in 2002, as well as older spills and residual contaminants in the soil at the Main Power House. The PRB gate comprised of granular activated carbon and natural clinoptilolite zeolite. Petroleum hydrocarbons migrating in the soil water were successfully captured on the reactive materials, with concentrations at the outflow of the barrier recorded as being below reporting limits. The nutrient and iron concentrations delivered to the barrier demonstrated high temporal variability with significant iron precipitation observed across the bed. The surface of the granular activated carbon was largely free from cell attachment while natural zeolite demonstrated patchy biofilm formation after 15 months following PRB installation. This study illustrates the importance of informed material selection at field scale to ensure that adsorption and biodegradation processes are utilised to manage the environmental risk associated with petroleum hydrocarbon spills. This study reports the first installation of a permeable bio-reactive barrier in the subantarctic. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Energy and Exergy Analysis of a Diesel Engine Fuelled with Diesel and Simarouba Biodiesel Blends

    NASA Astrophysics Data System (ADS)

    Panigrahi, Nabnit; Mohanty, Mahendra Kumar; Mishra, Sruti Ranjan; Mohanty, Ramesh Chandra

    2018-02-01

    This article intends to determine the available work and various losses of a diesel engine fuelled with diesel and SB20 (20 % Simarouba biodiesel by volume blended with 80 % diesel by volume). The energy and exergy analysis were carried out by using first law and second law of thermodynamics respectively. The experiments were carried out on a 3.5 kW compression ignition engine. The analysis was conducted on per mole of fuel basis. The energy analysis indicates that about 37.23 and 37.79 % of input energy is converted into the capacity to do work for diesel and SB20 respectively. The exergetic efficiency was 34.8 and 35 % for diesel and Simarouba respectively. Comparative study indicates that the energetic and exergetic performance of SB20 resembles with that of diesel fuel.

  1. 40 CFR 80.522 - May used motor oil be dispensed into diesel motor vehicles or nonroad diesel engines?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... diesel motor vehicles or nonroad diesel engines? 80.522 Section 80.522 Protection of Environment... vehicles or nonroad diesel engines? No person may introduce used motor oil, or used motor oil blended with... later nonroad diesel engines (not including locomotive or marine diesel engines), unless both of the...

  2. 40 CFR 80.522 - May used motor oil be dispensed into diesel motor vehicles or nonroad diesel engines?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... diesel motor vehicles or nonroad diesel engines? 80.522 Section 80.522 Protection of Environment... vehicles or nonroad diesel engines? No person may introduce used motor oil, or used motor oil blended with... later nonroad diesel engines (not including locomotive or marine diesel engines), unless both of the...

  3. 40 CFR 80.522 - May used motor oil be dispensed into diesel motor vehicles or nonroad diesel engines?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... diesel motor vehicles or nonroad diesel engines? 80.522 Section 80.522 Protection of Environment... vehicles or nonroad diesel engines? No person may introduce used motor oil, or used motor oil blended with... later nonroad diesel engines (not including locomotive or marine diesel engines), unless both of the...

  4. Heavy-Duty Diesel Fuel Analysis

    EPA Pesticide Factsheets

    EPA's heavy-duty diesel fuel analysis program sought to quantify the hydrocarbon, NOx, and PM emission effects of diesel fuel parameters (such as cetane number, aromatics content, and fuel density) on various nonroad and highway heavy-duty diesel engines.

  5. DIESEL ENGINE RETROFIT TECHNOLOGY VERIFICATION (POSTER)

    EPA Science Inventory

    ETV is presenting a poster at the EPA's 2005 Science Forum from May 16-18, 2005 in Washington, DC. This poster will contain a summary of the performance results realized by the six verified diesel retrofit technologies, as well as potential impacts that could be realized if sigi...

  6. 40 CFR 80.590 - What are the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... such fuel is dispensed into motor vehicles or nonroad equipment, locomotives, marine diesel engines or...) Undyed Ultra-Low Sulfur Diesel Fuel. For use in all diesel vehicles and engines.” From June 1, 2006... (maximum) Dyed Ultra-Low Sulfur Diesel Fuel. For use in all nonroad diesel engines. Not for use in highway...

  7. 40 CFR 80.590 - What are the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... such fuel is dispensed into motor vehicles or nonroad equipment, locomotives, marine diesel engines or...) Undyed Ultra-Low Sulfur Diesel Fuel. For use in all diesel vehicles and engines.” From June 1, 2006... (maximum) Dyed Ultra-Low Sulfur Diesel Fuel. For use in all nonroad diesel engines. Not for use in highway...

  8. 40 CFR 80.590 - What are the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... such fuel is dispensed into motor vehicles or nonroad equipment, locomotives, marine diesel engines or...) Undyed Ultra-Low Sulfur Diesel Fuel. For use in all diesel vehicles and engines.” From June 1, 2006... (maximum) Dyed Ultra-Low Sulfur Diesel Fuel. For use in all nonroad diesel engines. Not for use in highway...

  9. 40 CFR 80.590 - What are the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... such fuel is dispensed into motor vehicles or nonroad equipment, locomotives, marine diesel engines or...) Undyed Ultra-Low Sulfur Diesel Fuel. For use in all diesel vehicles and engines.” From June 1, 2006... (maximum) Dyed Ultra-Low Sulfur Diesel Fuel. For use in all nonroad diesel engines. Not for use in highway...

  10. 40 CFR 80.590 - What are the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... such fuel is dispensed into motor vehicles or nonroad equipment, locomotives, marine diesel engines or...) Undyed Ultra-Low Sulfur Diesel Fuel. For use in all diesel vehicles and engines.” From June 1, 2006... (maximum) Dyed Ultra-Low Sulfur Diesel Fuel. For use in all nonroad diesel engines. Not for use in highway...

  11. One dimensional modeling of a diesel-CNG dual fuel engine

    NASA Astrophysics Data System (ADS)

    Azman, Putera Adam; Fawzi, Mas; Ismail, Muammar Mukhsin; Osman, Shahrul Azmir

    2017-04-01

    Some of the previous studies have shown that the use of compressed natural gas (CNG) in diesel engines potentially produce engine performance improvement and exhaust gas emission reduction, especially nitrogen oxides, unburned hydrocarbons, and carbon dioxide. On the other hand, there are other researchers who claimed that the use of CNG increases exhaust gas emissions, particularly nitrogen oxides. In this study, a one-dimensional model of a diesel-CNG dual fuel engine was made based on a 4-cylinder 2.5L common rail direct injection diesel engine. The software used is GT-Power, and it was used to analyze the engine performance and exhaust gas emissions of several diesel-CNG dual fuel blend ratios, i.e. 100:0, 90:10, 80:20, 70:30, 60:40 and 50:50. The effect of 100%, 75%, 50% engine loads on the exhaust gas emissions were also studied. The result shows that all diesel-CNG fuel blends produces higher brake torque and brake power at engine speed of 2000-3000 rpm compared with 100% diesel. The 50:50 diesel-CNG blend produces the highest brake torque and brake power, but also has the highest brake specific fuel consumption. As a higher percentage of CNG added to the dual fuel blend, unburned hydrocarbons and carbon monoxide emission increased while carbon dioxide emission decreased. The nitrogen oxides emission concentration is generally unaffected by any change of the dual fuel ratio.

  12. Emissions and Fuel Economy of a Detroit Diesel 6-71 Engine Burning a 10-Percent Water-In-Fuel Emission

    DOT National Transportation Integrated Search

    1978-07-01

    Initial efforts with water/fuel emulsions in diesel engines were directed toward the control of NOx. More recent studies emphasized the use of emulsions to improve fuel economy. It is believed that in a diesel engine combustion process, emulsified fu...

  13. Performance of fuel system at different diesel temperature

    NASA Astrophysics Data System (ADS)

    Xu, Xiaoyong; Li, Xiaolu; Sun, Zai

    2010-08-01

    This paper presents the findings about performance of the fuel system of a diesel engine at different diesel temperature obtained through simulation and experiment. It can be seen from these findings that at the same rotational speed of fuel pump, the initial pressure in the fuel pipe remain unchanged as the fuel temperature increases, the peak pressure at the side of fuel pipe near the injector delays, and its largest value of pressure decreases. Meanwhile, at the same temperature, as the rotational speed increases, the initial pressure of fuel pipe is also essentially the same, the arrival of its peaks delays, and its largest value of pressure increases. The maximum fuel pressure at the side of fuel pipe near the injector has an increase of 28.9 %, 22.3%, and 13.9% respectively than the previous ones according to its conditions. At the same rotational speed, as the temperature increases, the injection quantity through the nozzle orifice decreases. At the same temperature, as the rotational speed increases, the injection quantity through the nozzle orifice increases. These experimental results are consistent with simulation results.

  14. Five Kilowatt Solid Oxide Fuel Cell/Diesel Reformer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dennis Witmer; Thomas Johnson

    2008-12-31

    Reducing fossil fuel consumption both for energy security and for reduction in global greenhouse emissions has been a major goal of energy research in the US for many years. Fuel cells have been proposed as a technology that can address both these issues--as devices that convert the energy of a fuel directly into electrical energy, they offer low emissions and high efficiencies. These advantages are of particular interest to remote power users, where grid connected power is unavailable, and most electrical power comes from diesel electric generators. Diesel fuel is the fuel of choice because it can be easily transportedmore » and stored in quantities large enough to supply energy for small communities for extended periods of time. This projected aimed to demonstrate the operation of a solid oxide fuel cell on diesel fuel, and to measure the resulting efficiency. Results from this project have been somewhat encouraging, with a laboratory breadboard integration of a small scale diesel reformer and a Solid Oxide Fuel Cell demonstrated in the first 18 months of the project. This initial demonstration was conducted at INEEL in the spring of 2005 using a small scale diesel reformer provided by SOFCo and a fuel cell provided by Acumentrics. However, attempts to integrate and automate the available technology have not proved successful as yet. This is due both to the lack of movement on the fuel processing side as well as the rather poor stack lifetimes exhibited by the fuel cells. Commercial product is still unavailable, and precommercial devices are both extremely expensive and require extensive field support.« less

  15. 30 CFR 57.5075 - Diesel particulate records.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Diesel particulate records. 57.5075 Section 57..., Radiation, Physical Agents, and Diesel Particulate Matter Diesel Particulate Matter-Underground Only § 57.5075 Diesel particulate records. (a) The table entitled “Diesel Particulate Matter Recordkeeping...

  16. 30 CFR 57.5075 - Diesel particulate records.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Diesel particulate records. 57.5075 Section 57..., Radiation, Physical Agents, and Diesel Particulate Matter Diesel Particulate Matter-Underground Only § 57.5075 Diesel particulate records. (a) The table entitled “Diesel Particulate Matter Recordkeeping...

  17. Biogas from bio-waste-potential for an ecological waste and energy management in resort hotels

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Steinbach, D.; Schultheis, A.

    1996-12-31

    This paper gives an overview about waste management in holiday resorts. The objective is to determine the composition of waste and the specific waste quantities per guest. This data represents the basis for planning recycling measures and corresponding treatment facilities. The sorting analyses show the great potential of organic material suitable for biological treatment. Because of the characteristics (water content, structure) of these organic materials, composting is not as suitable as fermentation. Fermentation tests with hotel bio-waste turned out a much higher rate of biogas compared with communal bio-waste. Until now, biogas as a possibility of regenerative energy, has notmore » been taken into consideration for big hotels or holiday resorts. Using biogas as an additional source of energy and the fermentation products as fertilizer would be a further step to an ecologically beneficial tourism.« less

  18. A case-control study relating railroad worker mortality to diesel exhaust exposure using a threshold regression model.

    PubMed

    Lee, Mei-Ling Ting; Whitmore, G A; Laden, Francine; Hart, Jaime E; Garshick, Eric

    2009-01-01

    A case-control study of lung cancer mortality in U.S. railroad workers in jobs with and without diesel exhaust exposure is reanalyzed using a new threshold regression methodology. The study included 1256 workers who died of lung cancer and 2385 controls who died primarily of circulatory system diseases. Diesel exhaust exposure was assessed using railroad job history from the US Railroad Retirement Board and an industrial hygiene survey. Smoking habits were available from next-of-kin and potential asbestos exposure was assessed by job history review. The new analysis reassesses lung cancer mortality and examines circulatory system disease mortality. Jobs with regular exposure to diesel exhaust had a survival pattern characterized by an initial delay in mortality, followed by a rapid deterioration of health prior to death. The pattern is seen in subjects dying of lung cancer, circulatory system diseases, and other causes. The unique pattern is illustrated using a new type of Kaplan-Meier survival plot in which the time scale represents a measure of disease progression rather than calendar time. The disease progression scale accounts for a healthy-worker effect when describing the effects of cumulative exposures on mortality.

  19. 30 CFR 75.1901 - Diesel fuel requirements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Diesel fuel requirements. 75.1901 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1901 Diesel fuel requirements. (a) Diesel-powered equipment shall be used underground only with a diesel fuel having a sulfur...

  20. 30 CFR 75.1901 - Diesel fuel requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Diesel fuel requirements. 75.1901 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1901 Diesel fuel requirements. (a) Diesel-powered equipment shall be used underground only with a diesel fuel having a sulfur...

  1. Adsorption and preconcentration of divalent metal ions in fossil fuels and biofuels: gasoline, diesel, biodiesel, diesel-like and ethanol by using chitosan microspheres and thermodynamic approach.

    PubMed

    Prado, Alexandre G S; Pescara, Igor C; Evangelista, Sheila M; Holanda, Matheus S; Andrade, Romulo D; Suarez, Paulo A Z; Zara, Luiz F

    2011-05-15

    Biodiesel and diesel-like have been obtained from soybean oil by transesterification and thermal cracking process, respectively. These biofuels were characterized as according to ANP standards by using specific ASTM methods. Ethanol, gasoline, and diesel were purchased from a gas station. Deacetylation degree of chitosan was determined by three distinct methods (conductimetry, FTIR and NMR), and the average degree was 78.95%. The chitosan microspheres were prepared from chitosan by split-coating and these spheres were crosslinked using glutaraldehyde. The surface area of microspheres was determined by BET method, and the surface area of crosslinked microspheres was 9.2m(2)g(-1). The adsorption isotherms of cooper, nickel and zinc on microspheres of chitosan were determined in petroleum derivatives (gasoline and diesel oil), as well as in biofuels (alcohol, biodiesel and diesel-like). The adsorption order in all fuels was: Cu>Ni>Zn. The elution tests presented the following preconcentration degrees: >4.5 to ethanol, >4.4 to gasoline, >4.0 to diesel, >3.8 to biodiesel and >3.6 to diesel-like. The application of chitosan microspheres in the metal ions preconcentration showed the potential of this biopolymer to enrich fuel sample in order to be analyzed by flame atomic absorption spectrometry. Copyright © 2011 Elsevier B.V. All rights reserved.

  2. Three-dimensional bio-printing.

    PubMed

    Gu, Qi; Hao, Jie; Lu, YangJie; Wang, Liu; Wallace, Gordon G; Zhou, Qi

    2015-05-01

    Three-dimensional (3D) printing technology has been widely used in various manufacturing operations including automotive, defence and space industries. 3D printing has the advantages of personalization, flexibility and high resolution, and is therefore becoming increasingly visible in the high-tech fields. Three-dimensional bio-printing technology also holds promise for future use in medical applications. At present 3D bio-printing is mainly used for simulating and reconstructing some hard tissues or for preparing drug-delivery systems in the medical area. The fabrication of 3D structures with living cells and bioactive moieties spatially distributed throughout will be realisable. Fabrication of complex tissues and organs is still at the exploratory stage. This review summarize the development of 3D bio-printing and its potential in medical applications, as well as discussing the current challenges faced by 3D bio-printing.

  3. Effect of exposure to diesel exhaust particles on the susceptibility of the lung to infection.

    PubMed

    Castranova, V; Ma, J Y; Yang, H M; Antonini, J M; Butterworth, L; Barger, M W; Roberts, J; Ma, J K

    2001-08-01

    There are at least three mechanisms by which alveolar macrophages play a critical role in protecting the lung from bacterial or viral infections: production of inflammatory cytokines that recruit and activate lung phagocytes, production of antimicrobial reactive oxidant species, and production of interferon (an antiviral agent). In this article we summarize data concerning the effect of exposure to diesel exhaust particles on these alveolar macrophage functions and the role of adsorbed organic chemicals compared to the carbonaceous core in the toxicity of diesel particles. In vitro exposure of rat alveolar macrophages to diesel exhaust particles decreased the ability of lipopolysaccharide (LPS), a bacterial product] to stimulate the production of inflammatory cytokines interleukin-1 (IL-1) and tumor necrosis factor-alpha (TNF-alpha). Methanol extract exhibited this potential but methanol-washed diesel particles did not. Exposure of rats to diesel exhaust particles by intratracheal instillation also decreased LPS-induced TNF-alpha and IL-1 production from alveolar macrophages. In contrast, carbon black did not exhibit this inhibitory effect. Exposure of rats to diesel exhaust particles by inhalation decreased the ability of alveolar macrophages to produce antimicrobial reactive oxidant species in response to zymosan (a fungal component). In contrast, exposure to coal dust increased zymosan-stimulated oxidant production. In vivo exposure to diesel exhaust particles but not to carbon black decreased the ability of the lungs to clear bacteria. Inhalation exposure of mice to diesel exhaust particles but not to coal dust depressed the ability of the lung to produce the antiviral agent interferon and increased viral multiplication in the lung. These results support the hypothesis that exposure to diesel exhaust particles increases the susceptibility of the lung to infection by depressing the antimicrobial potential of alveolar macrophages. This inhibitory effect appears

  4. Effect of exposure to diesel exhaust particles on the susceptibility of the lung to infection.

    PubMed Central

    Castranova, V; Ma, J Y; Yang, H M; Antonini, J M; Butterworth, L; Barger, M W; Roberts, J; Ma, J K

    2001-01-01

    There are at least three mechanisms by which alveolar macrophages play a critical role in protecting the lung from bacterial or viral infections: production of inflammatory cytokines that recruit and activate lung phagocytes, production of antimicrobial reactive oxidant species, and production of interferon (an antiviral agent). In this article we summarize data concerning the effect of exposure to diesel exhaust particles on these alveolar macrophage functions and the role of adsorbed organic chemicals compared to the carbonaceous core in the toxicity of diesel particles. In vitro exposure of rat alveolar macrophages to diesel exhaust particles decreased the ability of lipopolysaccharide (LPS), a bacterial product] to stimulate the production of inflammatory cytokines interleukin-1 (IL-1) and tumor necrosis factor-alpha (TNF-alpha). Methanol extract exhibited this potential but methanol-washed diesel particles did not. Exposure of rats to diesel exhaust particles by intratracheal instillation also decreased LPS-induced TNF-alpha and IL-1 production from alveolar macrophages. In contrast, carbon black did not exhibit this inhibitory effect. Exposure of rats to diesel exhaust particles by inhalation decreased the ability of alveolar macrophages to produce antimicrobial reactive oxidant species in response to zymosan (a fungal component). In contrast, exposure to coal dust increased zymosan-stimulated oxidant production. In vivo exposure to diesel exhaust particles but not to carbon black decreased the ability of the lungs to clear bacteria. Inhalation exposure of mice to diesel exhaust particles but not to coal dust depressed the ability of the lung to produce the antiviral agent interferon and increased viral multiplication in the lung. These results support the hypothesis that exposure to diesel exhaust particles increases the susceptibility of the lung to infection by depressing the antimicrobial potential of alveolar macrophages. This inhibitory effect appears

  5. Particulate morphology of waste cooking oil biodiesel and diesel in a heavy duty diesel engine

    NASA Astrophysics Data System (ADS)

    Hwang, Joonsik; Jung, Yongjin; Bae, Choongsik

    2014-08-01

    The effect of biodiesel produced from waste cooking oil (WCO) on the particulate matters (PM) of a direct injection (DI) diesel engine was experimentally investigated and compared with commercial diesel fuel. Soot agglomerates were collected with a thermophoretic sampling device installed in the exhaust pipe of the engine. The morphology of soot particles was analyzed using high resolution transmission electron microscopy (TEM). The elemental and thermogravimetric analysis (TGA) were also conducted to study chemical composition of soot particles. Based on the TEM images, it was revealed that the soot derived from WCO biodiesel has a highly graphitic shell-core arrangement compared to diesel soot. The mean size was measured from averaging 400 primary particles for WCO biodiesel and diesel respectively. The values for WCO biodiesel indicated 19.9 nm which was smaller than diesel's 23.7 nm. From the TGA results, WCO biodiesel showed faster oxidation process. While the oxidation of soot particles from diesel continued until 660°C, WCO biodiesel soot oxidation terminated at 560°C. Elemental analysis results showed that the diesel soot was mainly composed of carbon and hydrogen. On the other hand, WCO biodiesel soot contained high amount of oxygen species.

  6. Design and evaluation of fluidized bed heat recovery for diesel engine systems

    NASA Technical Reports Server (NTRS)

    Hamm, J. R.; Newby, R. A.; Vidt, E. J.; Lippert, T. E.

    1985-01-01

    The potential of utilizing fluidized bed heat exchangers in place of conventional counter-flow heat exchangers for heat recovery from adiabatic diesel engine exhaust gas streams was studied. Fluidized bed heat recovery systems were evaluated in three different heavy duty transport applications: (1) heavy duty diesel truck; (2) diesel locomotives; and (3) diesel marine pushboat. The three applications are characterized by differences in overall power output and annual utilization. For each application, the exhaust gas source is a turbocharged-adiabatic diesel core. Representative subposed exhaust gas heat utilization power cycles were selected for conceptual design efforts including design layouts and performance estimates for the fluidized bed heat recovery heat exchangers. The selected power cycles were: organic rankine with RC-1 working fluid, turbocompound power turbine with steam injection, and stirling engine. Fuel economy improvement predictions are used in conjunction with capital cost estimates and fuel price data to determine payback times for the various cases.

  7. Compound-Specific Isotope Analysis of Diesel Fuels in a Forensic Investigation

    NASA Astrophysics Data System (ADS)

    Muhammad, Syahidah; Frew, Russell; Hayman, Alan

    2015-02-01

    Compound-specific isotope analysis (CSIA) offers great potential as a tool to provide chemical evidence in a forensic investigation. Many attempts to trace environmental oil spills were successful where isotopic values were particularly distinct. However, difficulties arise when a large data set is analyzed and the isotopic differences between samples are subtle. In the present study, discrimination of diesel oils involved in a diesel theft case was carried out to infer the relatedness of the samples to potential source samples. This discriminatory analysis used a suite of hydrocarbon diagnostic indices, alkanes, to generate carbon and hydrogen isotopic data of the compositions of the compounds which were then processed using multivariate statistical analyses to infer the relatedness of the data set. The results from this analysis were put into context by comparing the data with the δ13C and δ2H of alkanes in commercial diesel samples obtained from various locations in the South Island of New Zealand. Based on the isotopic character of the alkanes, it is suggested that diesel fuels involved in the diesel theft case were distinguishable. This manuscript shows that CSIA when used in tandem with multivariate statistical analysis provide a defensible means to differentiate and source-apportion qualitatively similar oils at the molecular level. This approach was able to overcome confounding challenges posed by the near single-point source of origin i.e. the very subtle differences in isotopic values between the samples.

  8. Compound-specific isotope analysis of diesel fuels in a forensic investigation

    PubMed Central

    Muhammad, Syahidah A.; Frew, Russell D.; Hayman, Alan R.

    2015-01-01

    Compound-specific isotope analysis (CSIA) offers great potential as a tool to provide chemical evidence in a forensic investigation. Many attempts to trace environmental oil spills were successful where isotopic values were particularly distinct. However, difficulties arise when a large data set is analyzed and the isotopic differences between samples are subtle. In the present study, discrimination of diesel oils involved in a diesel theft case was carried out to infer the relatedness of the samples to potential source samples. This discriminatory analysis used a suite of hydrocarbon diagnostic indices, alkanes, to generate carbon and hydrogen isotopic data of the compositions of the compounds which were then processed using multivariate statistical analyses to infer the relatedness of the data set. The results from this analysis were put into context by comparing the data with the δ13C and δ2H of alkanes in commercial diesel samples obtained from various locations in the South Island of New Zealand. Based on the isotopic character of the alkanes, it is suggested that diesel fuels involved in the diesel theft case were distinguishable. This manuscript shows that CSIA when used in tandem with multivariate statistical analysis provide a defensible means to differentiate and source-apportion qualitatively similar oils at the molecular level. This approach was able to overcome confounding challenges posed by the near single-point source of origin, i.e., the very subtle differences in isotopic values between the samples. PMID:25774366

  9. Effects of diesel/ethanol dual fuel on emission characteristics in a heavy-duty diesel engine

    NASA Astrophysics Data System (ADS)

    Liu, Junheng; Sun, Ping; Zhang, Buyun

    2017-09-01

    In order to reduce emissions and diesel consumption, the gas emissions characteris-tics of diesel/aqueous ethanol dual fuel combustion (DFC) were carried out on a heavy-duty turbocharged and intercooled automotive diesel engine. The aqueous ethanol is prepared by a blend of anhydrous ethanol and water in certain volume proportion. In DFC mode, aqueous ethanol is injected into intake port to form homogeneous charge, and then ignited by the diesel fuel. Results show that DFC can reduce NOx emissions but increase HC and CO emissions, and this trend becomes more prominent with the increase of water blending ratio. Increased emissions of HC and CO could be efficiently cleaned by diesel oxidation catalytic converter (DOC), even better than those of diesel fuel. It is also found that DFC mode reduces smoke remarkably, while increases some unconventional emissions such as formaldehyde and acetal-dehyde. However, unconventional emissions could be reduced approximately to the level of baseline engine with a DOC.

  10. Aerosols emitted in underground mine air by diesel engine fueled with biodiesel.

    PubMed

    Bugarski, Aleksandar D; Cauda, Emanuele G; Janisko, Samuel J; Hummer, Jon A; Patts, Larry D

    2010-02-01

    Using biodiesel in place of petroleum diesel is considered by several underground metal and nonmetal mine operators to be a viable strategy for reducing the exposure of miners to diesel particulate matter. This study was conducted in an underground experimental mine to evaluate the effects of soy methyl ester biodiesel on the concentrations and size distributions of diesel aerosols and nitric oxides in mine air. The objective was to compare the effects of neat and blended biodiesel fuels with those of ultralow sulfur petroleum diesel. The evaluation was performed using a mechanically controlled, naturally aspirated diesel engine equipped with a muffler and a diesel oxidation catalyst. The effects of biodiesel fuels on size distributions and number and total aerosol mass concentrations were found to be strongly dependent on engine operating conditions. When fueled with biodiesel fuels, the engine contributed less to elemental carbon concentrations for all engine operating modes and exhaust configurations. The substantial increases in number concentrations and fraction of organic carbon (OC) in total carbon over the baseline were observed when the engine was fueled with biodiesel fuels and operated at light-load operating conditions. Size distributions for all test conditions were found to be single modal and strongly affected by engine operating conditions, fuel type, and exhaust configuration. The peak and total number concentrations as well as median diameter decreased with an increase in the fraction of biodiesel in the fuels, particularly for high-load operating conditions. The effects of the diesel oxidation catalyst, commonly deployed to counteract the potential increase in OC emissions due to use of biodiesel, were found to vary depending upon fuel formulation and engine operating conditions. The catalyst was relatively effective in reducing aerosol number and mass concentrations, particularly at light-load conditions, but also showed the potential for an

  11. Drive cycle analysis of butanol/diesel blends in a light-duty vehicle.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Miers, S. A.; Carlson, R. W.; McConnell, S. S.

    2008-10-01

    The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions,more » fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests.« less

  12. Oxidation and gum formation in diesel fuels. Interim technical report, May-December 1985

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mayo, F.R.

    1985-12-20

    This Report describes experiments on oxidation and gum formation from n-dodecane, tetralin, and several diesel fuels at 43, 60, and 100 C, with and without added initiators, t-butyl peroxide and 2,2'azobis(2-methylpropionitrile) (ABN). Experiments on gum determination and a manuscript for publication, Gum and Deposit Formation from Jet Turbine and Diesel Fuels at 100 C, are included. One objective of work on this Contract is to relate oxidations of diesel fuels at 100 and 130 C, where experiments can be performed in hours or days, to standard tests for fuel stability at ambient temperatures and 43.3 C (110 F), which requiremore » many weeks. A second objective is to devise a fast test for fuel stability.« less

  13. Geoelectrical Evidence of Microbial Degradation of Diesel Contaminated Sediments

    NASA Astrophysics Data System (ADS)

    Werkema, D. D.; Atekwana, E. A.; Rossbach, S.; Sauck, W. A.

    2003-12-01

    relative to the column with only microbes (selected as the control to be most representative of field conditions), the diesel column revealed a 2.3 fold increase and the diesel + microbe column showed a 3 fold increase in pore water conductivity. This increase was located within the diesel layer above the water saturated zone. Within the saturated zone, the no treatment column showed a 0.81 fold increase, the diesel column a 1.28, and the diesel + microbe column 1.45. We conclude from this study that microbial activity and the resultant biogeochemical changes played an important role in modifying the geoelectrical properties of aquifers and sediments rich in organic carbon and mineralized by bacteria by increasing the bulk conductivity. This conductive zone occurred within and immediately above the free-phase petroleum layer. In natural environments with high concentrations of organic compounds available as electron donors, geophysical techniques may potentially be used as indicators of microbial activity. Notice: This is an abstract of a proposed presentation and does not necessarily reflect the United States Environmental Protection Agency (EPA) policy. The actual presentation has not been peer reviewed by EPA. Mention of trade names or commercial products does not constitute endorsement or recommendation for use.

  14. Bio Diesel Cellulosic Ethanol Research Project

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hanlon, Edward A.; Capece, John C.; McAvoy, Eugene

    The objective of the project is to create the Hendry County Sustainable Biofuels Center and initiate its research, development, and education programs. The mission is to develop engineering and economic assessment methods to evaluate the natural resources impacts of biomass farming and fuel conversion systems; provide sustainability assessments of specific biofuels productions proposals; develop biomass farming and fuel conversion systems that are compatible with south Florida ecosystem restoration priorities; create ecosystem services opportunities and structures to diversify farm income; monitor the range of research and development activities necessary to the creation of sutstainable biofuels production systems in south Florida, identifymore » gaps in the regional research, and assist in the development and coordination of additional projects to fill out the required knowledge base; prepare the workforce of southwest Florida for employment in biofuels related professions; and assist businesses & governmental design and realize sustainable biofuels projects.« less

  15. Biofiltration of gasoline and diesel aliphatic hydrocarbons.

    PubMed

    Halecky, Martin; Rousova, Jana; Paca, Jan; Kozliak, Evguenii; Seames, Wayne; Jones, Kim

    2015-02-01

    The ability of a biofilm to switch between the mixtures of mostly aromatic and aliphatic hydrocarbons was investigated to assess biofiltration efficiency and potential substrate interactions. A switch from gasoline, which consisted of both aliphatic and aromatic hydrocarbons, to a mixture of volatile diesel n-alkanes resulted in a significant increase in biofiltration efficiency, despite the lack of readily biodegradable aromatic hydrocarbons in the diesel mixture. This improved biofilter performance was shown to be the result of the presence of larger size (C₉-C(12)) linear alkanes in diesel, which turned out to be more degradable than their shorter-chain (C₆-C₈) homologues in gasoline. The evidence obtained from both biofiltration-based and independent microbiological tests indicated that the rate was limited by biochemical reactions, with the inhibition of shorter chain alkane biodegradation by their larger size homologues as corroborated by a significant substrate specialization along the biofilter bed. These observations were explained by the lack of specific enzymes designed for the oxidation of short-chain alkanes as opposed to their longer carbon chain homologues.

  16. Diesel exhaust exposure and bladder cancer risk.

    PubMed

    Iyer, V; Harris, R E; Wynder, E L

    1990-03-01

    A total of 136 cases of men with urinary bladder cancer and 272 matched hospital controls were examined for potential exposure to diesel exhaust. A lifetime occupational history was obtained for all subjects in the study and assessment of exposure to diesel exhaust was based on the job titles of the subject and self-reported exposure. The risk was assessed by odds ratios, with adjustment for confounding variables, in particular cigarette smoking. There was no evidence of elevated risk in occupations with possible or probable exposure (the ORs adjusted for smoking were 1.1. and 0.9 respectively). Truck driving alone was also not associated with elevated risk (adjusted OR = 0.5). There was a weak positive crude association with any exposure, including self-reports (OR = 1.4); however after adjustment for smoking, the estimate did not retain statistical significance (OR = 1.2, 95% CI = 0.8-2.0). This study provides little to support the hypothesis of an excess of bladder cancer risk from occupational exposure to diesel exhaust.

  17. AUTOMOTIVE DIESEL MAINTENANCE. PROGRAM OUTLINE.

    ERIC Educational Resources Information Center

    Human Engineering Inst., Cleveland, OH.

    INFORMATIONAL TOPICS COVERED IN THE TEXT MATERIALS AND SELF-INSTRUCTIONAL BRANCH PROGRAMED TRAINING FILMS FOR A 2-YEAR, 55 MODULE PROGRAM IN AUTOMOTIVE DIESEL MAINTENANCE ARE GIVEN. THE 30 MODULES FOR "AUTOMOTIVE DIESEL MAINTENANCE 1" ARE AVAILABLE AS VT 005 655 - VT 005 684, AND THE 25 MODULES FOR "AUTOMOTIVE DIESEL MAINTENANCE 2" ARE AVAILABLE…

  18. 40 CFR 80.592 - What records must be kept by entities in the motor vehicle diesel fuel and diesel fuel additive...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... in the motor vehicle diesel fuel and diesel fuel additive distribution systems? 80.592 Section 80.592... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA... the motor vehicle diesel fuel and diesel fuel additive distribution systems? (a) Records that must be...

  19. 40 CFR 80.592 - What records must be kept by entities in the motor vehicle diesel fuel and diesel fuel additive...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... in the motor vehicle diesel fuel and diesel fuel additive distribution systems? 80.592 Section 80.592... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA... the motor vehicle diesel fuel and diesel fuel additive distribution systems? (a) Records that must be...

  20. 40 CFR 80.592 - What records must be kept by entities in the motor vehicle diesel fuel and diesel fuel additive...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... in the motor vehicle diesel fuel and diesel fuel additive distribution systems? 80.592 Section 80.592... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA... the motor vehicle diesel fuel and diesel fuel additive distribution systems? (a) Records that must be...

  1. 40 CFR 80.592 - What records must be kept by entities in the motor vehicle diesel fuel and diesel fuel additive...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... in the motor vehicle diesel fuel and diesel fuel additive distribution systems? 80.592 Section 80.592... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA... the motor vehicle diesel fuel and diesel fuel additive distribution systems? (a) Records that must be...

  2. 40 CFR 80.592 - What records must be kept by entities in the motor vehicle diesel fuel and diesel fuel additive...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... in the motor vehicle diesel fuel and diesel fuel additive distribution systems? 80.592 Section 80.592... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA... the motor vehicle diesel fuel and diesel fuel additive distribution systems? (a) Records that must be...

  3. Diesel Mechanics: Fundamentals.

    ERIC Educational Resources Information Center

    Foutes, William; And Others

    This publication is the first in a series of three texts for a diesel mechanics curriculum. Its purpose is to teach the basic concepts related to employment in a diesel trade. Six sections contain 29 units. Each instructional unit includes some or all of these basic components: unit and specific (performance) objectives, suggested activities for…

  4. BioC implementations in Go, Perl, Python and Ruby

    PubMed Central

    Liu, Wanli; Islamaj Doğan, Rezarta; Kwon, Dongseop; Marques, Hernani; Rinaldi, Fabio; Wilbur, W. John; Comeau, Donald C.

    2014-01-01

    As part of a communitywide effort for evaluating text mining and information extraction systems applied to the biomedical domain, BioC is focused on the goal of interoperability, currently a major barrier to wide-scale adoption of text mining tools. BioC is a simple XML format, specified by DTD, for exchanging data for biomedical natural language processing. With initial implementations in C++ and Java, BioC provides libraries of code for reading and writing BioC text documents and annotations. We extend BioC to Perl, Python, Go and Ruby. We used SWIG to extend the C++ implementation for Perl and one Python implementation. A second Python implementation and the Ruby implementation use native data structures and libraries. BioC is also implemented in the Google language Go. BioC modules are functional in all of these languages, which can facilitate text mining tasks. BioC implementations are freely available through the BioC site: http://bioc.sourceforge.net. Database URL: http://bioc.sourceforge.net/ PMID:24961236

  5. Mutagenicity of diesel exhaust particle extracts: influence of fuel composition in two diesel engines

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Clark, C.R.; Henderson, T.R.; Royer, R.E.

    The influence of diesel fuel composition on mutagenicity of exhaust particle associated organic compounds has been investigated using nine fuels varying in aromatic content and distillation properties. The tests were conducted with Oldsmobile Delta-88 and Peugot 504 diesel cars operated according to the EPA Federal Test Procedure. The particulate exhaust from each test was collected on a filter, extracted in dichloromethane and the resulting extract evaluated for mutagenicity in Salmonella strain TA-100. Mutagenicity of extracts of particles collected from the Oldsmobile were highest in the higher aromatic content fuels (> 30%) but similar for intermediate (20%) and low (13%) aromaticmore » content fuels. No influence of aromaticity on mutagenicity was observed in samples collected from the Peugeot under the same conditions. Thus, fuel aromatic content may enhance the production of mutagenic combustion products at higher concentrations, but may be dependent upon engine type. A good correlation was observed between mutagenicity of the particle extracts and the initial boiling point of the fuel (r = 0.89). Gas chromatography/mass spectrometric analysis of the aromatic fraction of the fuels showed that the fuel producing the most mutagenic combustion products was highest in phenanthrene type compounds.« less

  6. Nanostructure and burning mode of light-duty diesel particulate with conventional diesel, biodiesel, and intermediate blends

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Strzelec, Andrea; Vander Wal, Randy L.; Lewis, Samuel A.

    The nanostructure of diesel particulates has been shown to impact its oxidation rate and burnout trajectory. Additionally, this nanostructure can evolve during the oxidation process, furthering its influence on the burnout process. For this paper, exhaust particulates were generated on a light-duty diesel engine with conventional diesel fuel, biodiesel, and intermediate blends of the two at a single load-speed point. Despite the singular engine platform and operating point, the different fuels created particulates with varied nanostructure, thereby greatly expanding the window for observing nanostructure evolution and oxidation. The physical and chemical properties of the particulates in the nascent state andmore » at partial oxidation states were measured in a laboratory reactor and by high-resolution transmission electron microscopy as a function of the degree of oxidation in O 2. X-ray photoacoustic spectroscopy analysis, thermal desorption, and solvent extraction of the nascent particulate samples reveal a significant organic content in the biodiesel-derived particulates, likely accounting for differences in the nanostructure. This study reports the nanoscale structural changes in the particulate with biofuel blend level and during O 2 oxidation as observed by high-resolution transmission electron microscopy and quantitated by fringe analysis and Brunnauer–Emmet–Teller total surface area measurements. It was observed that initial fuel-related differences in the lamella lengths, spacing, and curvature disappear when the particulate reaches approximately 50% burnout. Specifically, the initial ordered, fullerenic, and amorphous nanostructures converge during the oxidation process and the surface areas of these particulates appear to grow through these complex changes in internal particle structure. The specific surface area, measured at several points along the burnout trajectory, did not match the shrinking core projection and in contrast suggested that

  7. Nanostructure and burning mode of light-duty diesel particulate with conventional diesel, biodiesel, and intermediate blends

    DOE PAGES

    Strzelec, Andrea; Vander Wal, Randy L.; Lewis, Samuel A.; ...

    2017-01-18

    The nanostructure of diesel particulates has been shown to impact its oxidation rate and burnout trajectory. Additionally, this nanostructure can evolve during the oxidation process, furthering its influence on the burnout process. For this paper, exhaust particulates were generated on a light-duty diesel engine with conventional diesel fuel, biodiesel, and intermediate blends of the two at a single load-speed point. Despite the singular engine platform and operating point, the different fuels created particulates with varied nanostructure, thereby greatly expanding the window for observing nanostructure evolution and oxidation. The physical and chemical properties of the particulates in the nascent state andmore » at partial oxidation states were measured in a laboratory reactor and by high-resolution transmission electron microscopy as a function of the degree of oxidation in O 2. X-ray photoacoustic spectroscopy analysis, thermal desorption, and solvent extraction of the nascent particulate samples reveal a significant organic content in the biodiesel-derived particulates, likely accounting for differences in the nanostructure. This study reports the nanoscale structural changes in the particulate with biofuel blend level and during O 2 oxidation as observed by high-resolution transmission electron microscopy and quantitated by fringe analysis and Brunnauer–Emmet–Teller total surface area measurements. It was observed that initial fuel-related differences in the lamella lengths, spacing, and curvature disappear when the particulate reaches approximately 50% burnout. Specifically, the initial ordered, fullerenic, and amorphous nanostructures converge during the oxidation process and the surface areas of these particulates appear to grow through these complex changes in internal particle structure. The specific surface area, measured at several points along the burnout trajectory, did not match the shrinking core projection and in contrast suggested that

  8. Generation and characterization of diesel engine combustion emissions from petroleum diesel and soybean biodiesel fuels and application for inhalation exposure studies.

    PubMed

    Mutlu, Esra; Nash, David G; King, Charly; Krantz, Todd Q; Preston, William T; Kooter, Ingeborg M; Higuchi, Mark; DeMarini, David; Linak, William P; Gilmour, M Ian

    2015-01-01

    Biodiesel made from the transesterification of plant- and animal-derived oils is an important alternative fuel source for diesel engines. Although numerous studies have reported health effects associated with petroleum diesel emissions, information on biodiesel emissions are more limited. To this end, a program at the U.S. EPA assessed health effects of biodiesel emissions in rodent inhalation models. Commercially obtained soybean biodiesel (B100) and a 20% blend with petroleum diesel (B20) were compared to pure petroleum diesel (B0). Rats and mice were exposed independently for 4 h/day, 5 days/week for up to 6 weeks. Exposures were controlled by dilution air to obtain low (50 µg/m(3)), medium (150 µg/m(3)) and high (500 µg/m(3)) diesel particulate mass (PM) concentrations, and compared to filtered air. This article provides details on facilities, fuels, operating conditions, emission factors and physico-chemical characteristics of the emissions used for inhalation exposures and in vitro studies. Initial engine exhaust PM concentrations for the B100 fuel (19.7 ± 0.7 mg/m(3)) were 30% lower than those of the B0 fuel (28.0 ± 1.5 mg/m(3)). When emissions were diluted with air to control equivalent PM mass concentrations, B0 exposures had higher CO and slightly lower NO concentrations than B100. Organic/elemental carbon ratios and oxygenated methyl esters and organic acids were higher for the B100 than B0. Both the B0 and B100 fuels produced unimodal-accumulation mode particle-size distributions, with B0 producing lower concentrations of slightly larger particles. Subsequent papers in this series will describe the effects of these atmospheres on cardiopulmonary responses and in vitro genotoxicity studies.

  9. AUTOMOTIVE DIESEL MAINTENANCE 1. UNIT I, GENERAL INTRODUCTION TO DIESEL ENGINES.

    ERIC Educational Resources Information Center

    Human Engineering Inst., Cleveland, OH.

    ONE OF A 30-MODULE COURSE DESIGNED TO UPGRADE THE JOB SKILLS AND TECHNICAL KNOWLEDGE OF DIESEL MAINTENANCE MECHANICS, THIS MATERIAL WAS DEVELOPED BY INDUSTRIAL TRAINING AND SUBJECT-MATTER SPECIALISTS AND TESTED IN INDUSTRIAL TRAINING SITUATIONS. THE PURPOSE OF THIS FIRST UNIT IS TO PROVIDE AN INTRODUCTION TO DIESEL ENGINES BY DEVELOPING AN…

  10. Clean Diesel National Grants

    EPA Pesticide Factsheets

    National Funding Assistance Program administers competitive grants for clean diesel projects. The Diesel Emissions Reduction Act (DERA) appropriates funds for these projects. Publication numbers: EPA-420-B-13-025 and EPA-420-P-11-001.

  11. Learn About Clean Diesel

    EPA Pesticide Factsheets

    The clean diesel program is designed to aggressively reduce the pollution emitted from diesel engines across the country through the implementation of varied control strategies and the aggressive involvement of national, state, and local partners.

  12. Beclometasone oral--DOR BioPharma.

    PubMed

    2007-01-01

    orBec is an oral enteric-coated tablet formulation of the corticosteroid beclometasone, which has been developed by Enteron Pharmaceuticals, a subsidiary of Corporate Technology Development (now DOR BioPharma). orBec is being developed for the treatment of gastrointestinal graft-versus-host disease (GVHD) and an NDA has been filed in the US. DOR BioPharma has also filed an MAA in Europe for the same indication.orBec is designed to reduce the need for systemic immunosuppressive drugs, thereby improving the outcome of bone marrow and stem cell transplantation.DOR BioPharma may seek a marketing partner in the US and elsewhere for orBec in GVHD and will seek a partner for other potential indications of the drug.In December 2001, Corporate Technology Development was acquired by Endorex Corporation (now DOR BioPharma). In October 1998, Enteron Pharmaceuticals (DOR BioPharma) entered into an exclusive, worldwide, royalty bearing license agreement with George B. McDonald, MD, including the right to grant sublicenses, for the rights to the intellectual property and know-how relating to orBec. In January 2007, DOR BioPharma received $US3 million under a non-binding letter of intent from Sigma-Tau Pharmaceuticals. The agreement grants Sigma-Tau an exclusive right to negotiate terms and conditions for a possible business transaction or strategic alliance regarding orBec and potentially other DOR pipeline compounds until 1 March 2007. Under the terms of the agreement, Sigma-Tau purchased $US1 million of DOR's common stock, with an additional $US2 million paid in cash. If no agreement is reached by 1 March 2007, DOR will return the $US2 million to Sigma-Tau within 60 days. DOR BioPharma received an unsolicited proposal from Cell Therapeutics, Inc. to acquire DOR BioPharma in January 2007. Because of the non-binding agreement already signed with Sigma-Tau, DOR BioPharma's board of directors cannot consider Cell Therapeutics' merger proposal at this time. orBec has been filed for

  13. Meta-analysis of human genome-microbiome association studies: the MiBioGen consortium initiative.

    PubMed

    Wang, Jun; Kurilshikov, Alexander; Radjabzadeh, Djawad; Turpin, Williams; Croitoru, Kenneth; Bonder, Marc Jan; Jackson, Matthew A; Medina-Gomez, Carolina; Frost, Fabian; Homuth, Georg; Rühlemann, Malte; Hughes, David; Kim, Han-Na; Spector, Tim D; Bell, Jordana T; Steves, Claire J; Timpson, Nicolas; Franke, Andre; Wijmenga, Cisca; Meyer, Katie; Kacprowski, Tim; Franke, Lude; Paterson, Andrew D; Raes, Jeroen; Kraaij, Robert; Zhernakova, Alexandra

    2018-06-08

    In recent years, human microbiota, especially gut microbiota, have emerged as an important yet complex trait influencing human metabolism, immunology, and diseases. Many studies are investigating the forces underlying the observed variation, including the human genetic variants that shape human microbiota. Several preliminary genome-wide association studies (GWAS) have been completed, but more are necessary to achieve a fuller picture. Here, we announce the MiBioGen consortium initiative, which has assembled 18 population-level cohorts and some 19,000 participants. Its aim is to generate new knowledge for the rapidly developing field of microbiota research. Each cohort has surveyed the gut microbiome via 16S rRNA sequencing and genotyped their participants with full-genome SNP arrays. We have standardized the analytical pipelines for both the microbiota phenotypes and genotypes, and all the data have been processed using identical approaches. Our analysis of microbiome composition shows that we can reduce the potential artifacts introduced by technical differences in generating microbiota data. We are now in the process of benchmarking the association tests and performing meta-analyses of genome-wide associations. All pipeline and summary statistics results will be shared using public data repositories. We present the largest consortium to date devoted to microbiota-GWAS. We have adapted our analytical pipelines to suit multi-cohort analyses and expect to gain insight into host-microbiota cross-talk at the genome-wide level. And, as an open consortium, we invite more cohorts to join us (by contacting one of the corresponding authors) and to follow the analytical pipeline we have developed.

  14. Clean Diesel Tribal Grants

    EPA Pesticide Factsheets

    The DERA Tribal Program awards clean diesel grants specifically for tribal nations. The Diesel Emissions Reduction Act (DERA) appropriates funds for these projects. Publication Numbers: EPA-420-B-13-025 and EPA-420-P-11-001.

  15. 78 FR 5165 - First Phase of the Forest Planning Process for the Bio-Region

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-24

    ... DEPARTMENT OF AGRICULTURE Forest Service First Phase of the Forest Planning Process for the Bio... initiating the first phase of the forest planning process for the Bio-Region. SUMMARY: Come gather 'round... phase of the Bio-Regional Assessment has begun. DATES: The Bio-Regional Assessment Report will be...

  16. Simultaneous Clostridial fermentation, lipase-catalyzed esterification, and ester extraction to enrich diesel with butyl butyrate.

    PubMed

    van den Berg, Corjan; Heeres, Arjan S; van der Wielen, Luuk A M; Straathof, Adrie J J

    2013-01-01

    The recovery of 1-butanol from fermentation broth is energy-intensive since typical concentrations in fermentation broth are below 20 g L(-1). To prevent butanol inhibition and high downstream processing costs, we aimed at producing butyl esters instead of 1-butanol. It is shown that it is possible to perform simultaneously clostridial fermentation, esterification of the formed butanol to butyl butyrate, and extraction of this ester by hexadecane. The very high partition coefficient of butyl butyrate pulls the esterification towards the product side even at fermentation pH and relatively low butanol concentrations. The hexadecane extractant is a model diesel compound and is nontoxic to the cells. If butyl butyrate enriched diesel can directly be used as car fuel, no product recovery is required. A proof-of-principle experiment for the one-pot bio-ester production from glucose led to 5 g L(-1) butyl butyrate in the hexadecane phase. The principle may be extended to a wide range of esters, especially to longer chain ones. Copyright © 2012 Wiley Periodicals, Inc.

  17. AUTOMOTIVE DIESEL MAINTENANCE 1. UNIT XX, CUMMINS DIESEL ENGINE, MAINTENANCE SUMMARY.

    ERIC Educational Resources Information Center

    Minnesota State Dept. of Education, St. Paul. Div. of Vocational and Technical Education.

    THIS MODULE OF A 30-MODULE COURSE IS DESIGNED TO PROVIDE A SUMMARY OF THE REASONS AND PROCEDURES FOR DIESEL ENGINE MAINTENANCE. TOPICS ARE WHAT ENGINE BREAK-IN MEANS, ENGINE BREAK-IN, TORQUING BEARINGS (TEMPLATE METHOD), AND THE NEED FOR MAINTENANCE. THE MODULE CONSISTS OF A SELF-INSTRUCTIONAL BRANCH PROGRAMED TRAINING FILM "CUMMINS DIESEL ENGINE…

  18. Performance and Emission Characteristics of Diesel Engine Fueled with Ethanol-Diesel Blends in Different Altitude Regions

    PubMed Central

    Lei, Jilin; Bi, Yuhua; Shen, Lizhong

    2011-01-01

    In order to investigate the effects ethanol-diesel blends and altitude on the performance and emissions of diesel engine, the comparative experiments were carried out on the bench of turbo-charged diesel engine fueled with pure diesel (as prototype) and ethanol-diesel blends (E10, E15, E20 and E30) under different atmospheric pressures (81 kPa, 90 kPa and 100 kPa). The experimental results indicate that the equivalent brake-specific fuel consumption (BSFC) of ethanol-diesel blends are better than that of diesel under different atmospheric pressures and that the equivalent BSFC gets great improvement with the rise of atmospheric pressure when the atmospheric pressure is lower than 90 kPa. At 81 kPa, both HC and CO emissions rise greatly with the increasing engine speeds and loads and addition of ethanol, while at 90 kPa and 100 kPa their effects on HC and CO emissions are slightest. The changes of atmospheric pressure and mix proportion of ethanol have no obvious effect on NOx emissions. Smoke emissions decrease obviously with the increasing percentage of ethanol in blends, especially atmospheric pressure below 90 kPa. PMID:21234367

  19. Performance and emission characteristics of diesel engine fueled with ethanol-diesel blends in different altitude regions.

    PubMed

    Lei, Jilin; Bi, Yuhua; Shen, Lizhong

    2011-01-01

    In order to investigate the effects ethanol-diesel blends and altitude on the performance and emissions of diesel engine, the comparative experiments were carried out on the bench of turbo-charged diesel engine fueled with pure diesel (as prototype) and ethanol-diesel blends (E10, E15, E20 and E30) under different atmospheric pressures (81 kPa, 90 kPa and 100 kPa). The experimental results indicate that the equivalent brake-specific fuel consumption (BSFC) of ethanol-diesel blends are better than that of diesel under different atmospheric pressures and that the equivalent BSFC gets great improvement with the rise of atmospheric pressure when the atmospheric pressure is lower than 90 kPa. At 81 kPa, both HC and CO emissions rise greatly with the increasing engine speeds and loads and addition of ethanol, while at 90 kPa and 100 kPa their effects on HC and CO emissions are slightest. The changes of atmospheric pressure and mix proportion of ethanol have no obvious effect on NO(x) emissions. Smoke emissions decrease obviously with the increasing percentage of ethanol in blends, especially atmospheric pressure below 90 kPa.

  20. Inhaled Diesel Emissions Generated with Cerium Oxide Nanoparticle Fuel Additive Induce Adverse Pulmonary and Systemic Effects

    EPA Science Inventory

    Diesel exhaust (DE) exposure induces adverse cardiopulmonary effects. Cerium oxide nanoparticles added to diesel fuel (DECe) increases fuel burning efficiency but leads to altered emission characteristics and potentially altered health effects. Here, we evaluated whether DECe res...

  1. Pyrolysis of waste animal fats in a fixed-bed reactor: Production and characterization of bio-oil and bio-char

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ben Hassen-Trabelsi, A., E-mail: aidabenhassen@yahoo.fr; Kraiem, T.; Département de Géologie, Université de Tunis, 2092, Tunis

    Highlights: • Produced bio-fuels (bio-oil and bio-char) from some animal fatty wastes. • Investigated the effects of main parameters on pyrolysis products distribution. • Determined the suitable conditions for the production of the maximum of bio-oil. • Characterized bio-oils and bio-chars obtained from several animal fatty wastes. - Abstract: Several animal (lamb, poultry and swine) fatty wastes were pyrolyzed under nitrogen, in a laboratory scale fixed-bed reactor and the main products (liquid bio-oil, solid bio-char and syngas) were obtained. The purpose of this study is to produce and characterize bio-oil and bio-char obtained from pyrolysis of animal fatty wastes. Themore » maximum production of bio-oil was achieved at a pyrolysis temperature of 500 °C and a heating rate of 5 °C/min. The chemical (GC–MS analyses) and spectroscopic analyses (FTIR analyses) of bio-oil showed that it is a complex mixture consisting of different classes of organic compounds, i.e., hydrocarbons (alkanes, alkenes, cyclic compounds…etc.), carboxylic acids, aldehydes, ketones, esters,…etc. According to fuel properties, produced bio-oils showed good properties, suitable for its use as an engine fuel or as a potential source for synthetic fuels and chemical feedstock. Obtained bio-chars had low carbon content and high ash content which make them unattractive for as renewable source energy.« less

  2. Controlled human exposures to diesel exhaust

    EPA Science Inventory

    Diesel exhaust (DE) is a complex mixture of gaseous and particulate compounds resulting from an incomplete combustion of diesel fuel. Controlled human exposures to DE and diesel exhaust particles (DEP) have contributed to understanding health effects. Such exposure studies of h...

  3. Safety Aspects of Bio-Based Nanomaterials.

    PubMed

    Catalán, Julia; Norppa, Hannu

    2017-12-01

    Moving towards a bio-based and circular economy implies a major focus on the responsible and sustainable utilization of bio-resources. The emergence of nanotechnology has opened multiple possibilities, not only in the existing industrial sectors, but also for completely novel applications of nanoscale bio-materials, the commercial exploitation of which has only begun during the last few years. Bio-based materials are often assumed not to be toxic. However, this pre-assumption is not necessarily true. Here, we provide a short overview on health and environmental aspects associated with bio-based nanomaterials, and on the relevant regulatory requirements. We also discuss testing strategies that may be used for screening purposes at pre-commercial stages. Although the tests presently used to reveal hazards are still evolving, regarding modifi-cations required for nanomaterials, their application is needed before the upscaling or commercialization of bio-based nanomaterials, to ensure the market potential of the nanomaterials is not delayed by uncertainties about safety issues.

  4. 30 CFR 72.520 - Diesel equipment inventory.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Diesel equipment inventory. 72.520 Section 72... HEALTH HEALTH STANDARDS FOR COAL MINES Diesel Particulate Matter-Underground Areas of Underground Coal Mines § 72.520 Diesel equipment inventory. (a) The operator of each mine that utilizes diesel equipment...

  5. 30 CFR 72.520 - Diesel equipment inventory.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Diesel equipment inventory. 72.520 Section 72... HEALTH HEALTH STANDARDS FOR COAL MINES Diesel Particulate Matter-Underground Areas of Underground Coal Mines § 72.520 Diesel equipment inventory. (a) The operator of each mine that utilizes diesel equipment...

  6. 30 CFR 72.520 - Diesel equipment inventory.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Diesel equipment inventory. 72.520 Section 72... HEALTH HEALTH STANDARDS FOR COAL MINES Diesel Particulate Matter-Underground Areas of Underground Coal Mines § 72.520 Diesel equipment inventory. (a) The operator of each mine that utilizes diesel equipment...

  7. 30 CFR 72.520 - Diesel equipment inventory.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Diesel equipment inventory. 72.520 Section 72... HEALTH HEALTH STANDARDS FOR COAL MINES Diesel Particulate Matter-Underground Areas of Underground Coal Mines § 72.520 Diesel equipment inventory. (a) The operator of each mine that utilizes diesel equipment...

  8. 30 CFR 72.520 - Diesel equipment inventory.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Diesel equipment inventory. 72.520 Section 72... HEALTH HEALTH STANDARDS FOR COAL MINES Diesel Particulate Matter-Underground Areas of Underground Coal Mines § 72.520 Diesel equipment inventory. (a) The operator of each mine that utilizes diesel equipment...

  9. Ice-nucleating particle emissions from photochemically aged diesel and biodiesel exhaust

    NASA Astrophysics Data System (ADS)

    Schill, G. P.; Jathar, S. H.; Kodros, J. K.; Levin, E. J. T.; Galang, A. M.; Friedman, B.; Link, M. F.; Farmer, D. K.; Pierce, J. R.; Kreidenweis, S. M.; DeMott, P. J.

    2016-05-01

    Immersion-mode ice-nucleating particle (INP) concentrations from an off-road diesel engine were measured using a continuous-flow diffusion chamber at -30°C. Both petrodiesel and biodiesel were utilized, and the exhaust was aged up to 1.5 photochemically equivalent days using an oxidative flow reactor. We found that aged and unaged diesel exhaust of both fuels is not likely to contribute to atmospheric INP concentrations at mixed-phase cloud conditions. To explore this further, a new limit-of-detection parameterization for ice nucleation on diesel exhaust was developed. Using a global-chemical transport model, potential black carbon INP (INPBC) concentrations were determined using a current literature INPBC parameterization and the limit-of-detection parameterization. Model outputs indicate that the current literature parameterization likely overemphasizes INPBC concentrations, especially in the Northern Hemisphere. These results highlight the need to integrate new INPBC parameterizations into global climate models as generalized INPBC parameterizations are not valid for diesel exhaust.

  10. The Cummins advanced turbocompound diesel engine evaluation

    NASA Technical Reports Server (NTRS)

    Hoehne, J. L.; Werner, J. R.

    1982-01-01

    An advanced turbocompound diesel engine program was initiated to improve the tank mileage of the turbocompound engine by 5% over the vehicle test engines. Engine improvements could be realized by increasing the available energy of the exhaust gas at the turbine inlet, incorporating gas turbine techniques into improving the turbomachinery efficiencies, and through refined engine system optimization. The individual and cumulative performance gains achieved with the advanced turbocompound engine improvements are presented.

  11. Bio-reinforced self-healing concrete using magnetic iron oxide nanoparticles.

    PubMed

    Seifan, Mostafa; Sarmah, Ajit K; Ebrahiminezhad, Alireza; Ghasemi, Younes; Samani, Ali Khajeh; Berenjian, Aydin

    2018-03-01

    Immobilization has been reported as an efficient technique to address the bacterial vulnerability for application in bio self-healing concrete. In this study, for the first time, magnetic iron oxide nanoparticles (IONs) are being practically employed as the protective vehicle for bacteria to evaluate the self-healing performance in concrete environment. Magnetic IONs were successfully synthesized and characterized using different techniques. The scanning electron microscope (SEM) images show the efficient adsorption of nanoparticles to the Bacillus cells. Microscopic observation illustrates that the incorporation of the immobilized bacteria in the concrete matrix resulted in a significant crack healing behavior, while the control specimen had no healing characteristics. Analysis of bio-precipitates revealed that the induced minerals in the cracks were calcium carbonate. The effect of magnetic immobilized cells on the concrete water absorption showed that the concrete specimens supplemented with decorated bacteria with IONs had a higher resistance to water penetration. The initial and secondary water absorption rates in bio-concrete specimens were 26% and 22% lower than the control specimens. Due to the compatible behavior of IONs with the concrete compositions, the results of this study proved the potential application of IONs for developing a new generation of bio self-healing concrete.

  12. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Boyd, Rodney

    The objective of this project was to define the scope and cost of a technology research and development program that will demonstrate the feasibility of using an off-the-shelf, unmodified, large bore diesel powered generator in a grid-connected application, utilizing various blends of BioDiesel as fuel. Furthermore, the objective of project was to develop an emissions control device that uses a catalytic process and BioDiesel (without the presence of Ammonia or Urea)to reduce NOx and other pollutants present in a reciprocating engine exhaust stream with the goal of redefining the highest emission reduction efficiencies possible for a diesel reciprocating generator. Process:more » Caterpillar Power Generation adapted an off-the-shelf Diesel Generator to run on BioDiesel and various Petroleum Diesel/BioDiesel blends. EmeraChem developed and installed an exhaust gas cleanup system to reduce NOx, SOx, volatile organics, and particulates. The system design and function was optimized for emissions reduction with results in the 90-95% range;« less

  13. MUTAGENIC AND CARCINOGENIC POTENCY OF EXTRACTS OF DIESEL AND RELATED ENVIRONMENTAL EMISSIONS: STUDY DESIGN, SAMPLE GENERATION, COLLECTION, AND PREPARATION (JOURNAL VERSION)

    EPA Science Inventory

    A major diesel emissions research program has been initiated by the US Environmental Protection Agency to assess the human health risk associated with increased use of diesel automobiles. This program is intended to establish the mutagenic and carcinogenic potency of complex orga...

  14. Comparison of carbonyl compounds emissions from diesel engine fueled with biodiesel and diesel

    NASA Astrophysics Data System (ADS)

    He, Chao; Ge, Yunshan; Tan, Jianwei; You, Kewei; Han, Xunkun; Wang, Junfang; You, Qiuwen; Shah, Asad Naeem

    The characteristics of carbonyl compounds emissions were investigated on a direct injection, turbocharged diesel engine fueled with pure biodiesel derived from soybean oil. The gas-phase carbonyls were collected by 2,4-dinitrophenylhydrazine (DNPH)-coated silica cartridges from diluted exhaust and analyzed by HPLC with UV detector. A commercial standard mixture including 14 carbonyl compounds was used for quantitative analysis. The experimental results indicate that biodiesel-fueled engine almost has triple carbonyls emissions of diesel-fueled engine. The weighted carbonyls emission of 8-mode test cycle of biodiesel is 90.8 mg (kW h) -1 and that of diesel is 30.7 mg (kW h) -1. The formaldehyde is the most abundant compound of carbonyls for both biodiesel and diesel, taking part for 46.2% and 62.7% respectively. The next most significant compounds are acetaldehyde, acrolein and acetone for both fuels. The engine fueled with biodiesel emits a comparatively high content of propionaldehyde and methacrolein. Biodiesel, as an alternative fuel, has lower specific reactivity (SR) caused by carbonyls compared with diesel. When fueled with biodiesel, carbonyl compounds make more contribution to total hydrocarbon emission.

  15. Functional tooth restoration by next-generation bio-hybrid implant as a bio-hybrid artificial organ replacement therapy

    PubMed Central

    Oshima, Masamitsu; Inoue, Kaoru; Nakajima, Kei; Tachikawa, Tetsuhiko; Yamazaki, Hiromichi; Isobe, Tomohide; Sugawara, Ayaka; Ogawa, Miho; Tanaka, Chie; Saito, Masahiro; Kasugai, Shohei; Takano-Yamamoto, Teruko; Inoue, Takashi; Tezuka, Katsunari; Kuboki, Takuo; Yamaguchi, Akira; Tsuji, Takashi

    2014-01-01

    Bio-hybrid artificial organs are an attractive concept to restore organ function through precise biological cooperation with surrounding tissues in vivo. However, in bio-hybrid artificial organs, an artificial organ with fibrous connective tissues, including muscles, tendons and ligaments, has not been developed. Here, we have enveloped with embryonic dental follicle tissue around a HA-coated dental implant, and transplanted into the lower first molar region of a murine tooth-loss model. We successfully developed a novel fibrous connected tooth implant using a HA-coated dental implant and dental follicle stem cells as a bio-hybrid organ. This bio-hybrid implant restored physiological functions, including bone remodelling, regeneration of severe bone-defect and responsiveness to noxious stimuli, through regeneration with periodontal tissues, such as periodontal ligament and cementum. Thus, this study represents the potential for a next-generation bio-hybrid implant for tooth loss as a future bio-hybrid artificial organ replacement therapy. PMID:25116435

  16. 30 CFR 75.1906 - Transport of diesel fuel.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Transport of diesel fuel. 75.1906 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1906 Transport of diesel fuel. (a) Diesel fuel shall be transported only by diesel fuel transportation units or in safety...

  17. 30 CFR 75.1906 - Transport of diesel fuel.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Transport of diesel fuel. 75.1906 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1906 Transport of diesel fuel. (a) Diesel fuel shall be transported only by diesel fuel transportation units or in safety...

  18. 40 CFR 80.550 - What is the definition of a motor vehicle diesel fuel small refiner or a NRLM diesel fuel small...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... vehicle diesel fuel small refiner or a NRLM diesel fuel small refiner under this subpart? 80.550 Section...) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel... vehicle diesel fuel small refiner or a NRLM diesel fuel small refiner under this subpart? (a) A motor...

  19. 40 CFR 80.550 - What is the definition of a motor vehicle diesel fuel small refiner or a NRLM diesel fuel small...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... vehicle diesel fuel small refiner or a NRLM diesel fuel small refiner under this subpart? 80.550 Section...) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel... vehicle diesel fuel small refiner or a NRLM diesel fuel small refiner under this subpart? (a) A motor...

  20. Effect of the Ethanol Injection Moment During Compression Stroke on the Combustion of Ethanol - Diesel Dual Direct Injection Engine

    NASA Astrophysics Data System (ADS)

    Liang, Yu; Zhou, Liying; Huang, Haomin; Xu, Mingfei; Guo, Mei; Chen, Xin

    2018-01-01

    A set of GDI system is installed on a F188 single-cylinder, air-cooled and direct injection diesel engine, which is used for ethanol injection, with the injection time controlled by the crank angle signal collected by AVL angle encoder. The injection of ethanol amounts to half of the thermal equivalent of an original diesel fuel. A 3D combustion model is established for the ethanol - diesel dual direct injection engine. Diesel was injected from the original fuel injection system, with a fuel supply advance angle of 20°CA. The ethanol was injected into the cylinder during compression process. Diesel injection began after the completion of ethanol injection. Ethanol injection starting point of 240°CA, 260°CA, 280°CA, 300°CA and 319.4°CA were simulated and analyzed. Due to the different timing of ethanol injection, the ignition of the ethanol mixture when diesel fires, results in non-uniform ignition distribution and flame propagation rate, since the distribution and concentration gradients of the ethanol mixture in the cylinder are different, thus affecting the combustion process. The results show that, when ethanol is injected at 319.4°CA, the combustion heat release rate and the pressure rise rate during the initial stage are the highest. Also, the maximum combustion pressure, with a relatively advance phase, is the highest. In case of later initial ethanol injection, the average temperature in the cylinder during the initial combustion period will have a faster rise. In case of initial injection at 319.4°CA, the average temperature in the cylinder is the highest, followed by 240°CA ethanol injection. In the post-combustion stage, the earlier ethanol injection will result in higher average temperature in the cylinder and more complete fuel combustion. The injection of ethanol at 319.4°CA produces earlier and highest NOX emissions.

  1. Validation of the Dynamic Direct Exposure Method for Toxicity Testing of Diesel Exhaust In Vitro

    PubMed Central

    Hayes, Amanda; Bakand, Shahnaz

    2013-01-01

    Diesel exhaust emission is a major health concern because of the complex nature of its gaseous content (e.g., NO2, NO, CO, and CO2) and high concentration of particulate matter (PM) less than 2.5 μm which allows for deeper penetration into the human pulmonary system upon inhalation. The aim of this research was to elucidate the potential toxic effects of diesel exhaust on a human pulmonary-based cellular system. Validation of a dynamic direct exposure method for both laboratory (230 hp Volvo truck engine) and field (Volkswagen Passat passenger car) diesel engines, at idle mode, was implemented. Human pulmonary type II epithelial cells (A549) grown on porous membranes were exposed to unmodified diesel exhaust at a low flow rate (37.5 mL/min). In parallel, diesel emission sampling was also conducted using real-time air monitoring techniques. Induced cellular effects were assessed using a range of in vitro cytotoxicity assays (MTS, ATP, and NRU). Reduction of cell viability was observed in a time-dependent manner following 30–60 mins of exposure with NRU as the most sensitive assay. The results suggest that the dynamic direct exposure method has the potential to be implemented for both laboratory- and field-based in vitro toxicity studies of diesel exhaust emissions. PMID:23986878

  2. BioC implementations in Go, Perl, Python and Ruby.

    PubMed

    Liu, Wanli; Islamaj Doğan, Rezarta; Kwon, Dongseop; Marques, Hernani; Rinaldi, Fabio; Wilbur, W John; Comeau, Donald C

    2014-01-01

    As part of a communitywide effort for evaluating text mining and information extraction systems applied to the biomedical domain, BioC is focused on the goal of interoperability, currently a major barrier to wide-scale adoption of text mining tools. BioC is a simple XML format, specified by DTD, for exchanging data for biomedical natural language processing. With initial implementations in C++ and Java, BioC provides libraries of code for reading and writing BioC text documents and annotations. We extend BioC to Perl, Python, Go and Ruby. We used SWIG to extend the C++ implementation for Perl and one Python implementation. A second Python implementation and the Ruby implementation use native data structures and libraries. BioC is also implemented in the Google language Go. BioC modules are functional in all of these languages, which can facilitate text mining tasks. BioC implementations are freely available through the BioC site: http://bioc.sourceforge.net. Database URL: http://bioc.sourceforge.net/ Published by Oxford University Press 2014. This work is written by US Government employees and is in the public domain in the US.

  3. Understanding Potential Air Emissions from a Cellulosic Biorefinery Producing Renewable Diesel Blendstock.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhang, Yimin; Heath, Garvin A.; Renzaglia, Jason

    2015-06-22

    The Energy Independence and Security Act of 2007, through the Renewable Fuel Standard (RFS), mandates increased use of biofuels, including cellulosic biofuels. The RFS is expected to spur the development of advanced biofuel technologies (e.g., new and innovative biofuel conversion pathways) as well as the construction of biorefineries (refineries that produce biofuels) using these technologies. To develop sustainable cellulosic biofuels, one of the goals of the Bioenergy Technologies Office (BETO) at the Department of Energy is to minimize air pollutants from the entire biofuel supply chain, as stated in their 2014 Multi-Year Program Plan (2014). Although biofuels in general havemore » been found to have lower life cycle greenhouse gas (GHG) emissions compared to petroleum fuels on an energy basis, biomass feedstock production, harvesting, transportation, processing and conversion are expected to emit a wide range of other air pollutants (e.g., criteria air pollutants, hazardous air pollutants), which could affect the environmental benefits of biofuels when displacing petroleum fuels. While it is important for policy makers, air quality planners and regulators, biofuel developers, and investors to understand the potential implications on air quality from a growing biofuel industry, there is a general lack of information and knowledge about the type, fate and magnitude of potential air pollutant emissions from the production of cellulosic biofuels due to the nascent stage of this emerging industry. This analysis assesses potential air pollutant emissions from a hypothetical biorefinery, selected by BETO for further research and development, which uses a biological conversion process of sugars to hydrocarbons to produce infrastructural-compatible renewable diesel blendstock from cellulosic biomass.« less

  4. 30 CFR 75.1906 - Transport of diesel fuel.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Transport of diesel fuel. 75.1906 Section 75... diesel fuel. (a) Diesel fuel shall be transported only by diesel fuel transportation units or in safety... fuel storage facilities. (c) Safety cans that leak must be promptly removed from the mine. (d) Diesel...

  5. Diesel Powered School Buses: An Update.

    ERIC Educational Resources Information Center

    Gresham, Robert

    1984-01-01

    Because diesel engines are more economical and longer-lasting than gasoline engines, school districts are rapidly increasing their use of diesel buses. Dependence on diesel power, however, entails vulnerability to cost increases due to the unreliability of crude oil supplies and contributes to air pollution. (MCG)

  6. Assessing exposure to diesel exhaust particles: a case study.

    PubMed

    See, Siao Wei; Balasubramanian, Rajasekhar; Yang, Tzuo Sern; Karthikeyan, Sathrugnan

    2006-11-01

    The assessment of the vehicular contributions to urban pollution levels is of particular importance given the current interest in the possible adverse health effects. This study focused on human exposure to diesel-engine-derived particulate matter. Diesel vehicles are known to emit fine particulate matter (PM2.5) containing carcinogens such as polycyclic aromatic hydrocarbons (PAHs), and have therefore received considerable attention. In this study, the physical (mass and number concentration, and size distribution) and chemical (PAHs) properties were investigated at a major bus interchange in Singapore, influenced only by diesel exhausts. Number concentration and size distribution of particles were determined in real time, while the mass concentrations of PM2.5, and PAHs were measured during operating and nonoperating hours. The average mass concentrations of PM2.5 and PAHs increased by a factor of 2.34 and 5.18, respectively, during operating hours. The average number concentration was also elevated by a factor of 5.07 during operating hours. This increase in the concentration of PM2.5 particles and their chemical constituents during operating hours was attributable to diesel emissions from in-use buses based on the particle size analysis, correlation among PAHs, and the commonly used PAHs diagnostic ratios. To evaluate the potential health threat due inhalation of air pollutants released from diesel engines, the incremental lifetime cancer risk was also calculated for a maximally exposed individual. The findings indicate that the air quality at the bus interchange poses adverse health effects.

  7. Diesel engine exhaust oxidizer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kammel, R.A.

    1992-06-16

    This patent describes a diesel engine exhaust oxidizing device. It comprises: an enclosure having an inlet for receiving diesel engine exhaust, a main flow path through the enclosure to an outlet of the enclosure, a by-ass through the enclosure, and a microprocessor control means.

  8. Prospects of pyrolysis oil from plastic waste as fuel for diesel engines: A review

    NASA Astrophysics Data System (ADS)

    Mangesh, V. L.; Padmanabhan, S.; Ganesan, S.; PrabhudevRahul, D.; Reddy, T. Dinesh Kumar

    2017-05-01

    The purpose ofthis study is to review the existing literature about chemical recycling of plastic waste and its potential as fuel for diesel engines. This is a review covering on the field of converting waste plastics into liquid hydrocarbon fuels for diesel engines. Disposal and recycling of waste plastics have become an incremental problem and environmental threat with increasing demand for plastics. One of the effective measures is by converting waste plastic into combustible hydrocarbon liquid as an alternative fuel for running diesel engines. Continued research efforts have been taken by researchers to convert waste plastic in to combustible pyrolysis oil as alternate fuel for diesel engines. An existing literature focuses on the study of chemical structure of the waste plastic pyrolysis compared with diesel oil. Converting waste plastics into fuel oil by different catalysts in catalytic pyrolysis process also reviewed in this paper. The methodology with subsequent hydro treating and hydrocracking of waste plastic pyrolysis oil can reduce unsaturated hydrocarbon bonds which would improve the combustion performance in diesel engines as an alternate fuel.

  9. 30 CFR 250.610 - Diesel engine air intakes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 2 2012-07-01 2012-07-01 false Diesel engine air intakes. 250.610 Section 250... Operations § 250.610 Diesel engine air intakes. No later than May 31, 1989, diesel engine air intakes shall be equipped with a device to shut down the diesel engine in the event of runaway. Diesel engines...

  10. 30 CFR 250.610 - Diesel engine air intakes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 2 2014-07-01 2014-07-01 false Diesel engine air intakes. 250.610 Section 250... Operations § 250.610 Diesel engine air intakes. No later than May 31, 1989, diesel engine air intakes shall be equipped with a device to shut down the diesel engine in the event of runaway. Diesel engines...

  11. Fungicidal values of bio-oils and their lignin-rich fractions obtained from wood/bark fast pyrolysis.

    PubMed

    Mohan, Dinesh; Shi, Jenny; Nicholas, Darrel D; Pittman, Charles U; Steele, Philip H; Cooper, Jerome E

    2008-03-01

    Pine wood, pine bark, oak wood and oak bark were pyrolyzed in an auger reactor. A total of 16 bio-oils or pyrolytic oils were generated at different temperatures and residence times. Two additional pine bio-oils were produced at the National Renewable Energy Laboratory in a fluidized-bed reactor at different temperatures. All these bio-oils were fractionated to obtain lignin-rich fractions which consist mainly of phenols and neutrals. The pyrolytic lignin-rich fractions were obtained by liquid-liquid extraction. Whole bio-oils and their lignin-rich fractions were studied as potential environmentally benign wood preservatives to replace metal-based CCA and copper systems that have raised environmental concerns. Each bio-oil and several lignin-rich fractions were tested for antifungal properties. Soil block tests were conducted using one brown-rot fungus (Gloeophyllum trabeum) and one white-rot fungus (Trametes versicolor). The lignin-rich fractions showed greater fungal inhibition than whole bio-oils for a impregnation solution 10% concentration level. Water repellence tests were also performed to study wood wafer swelling behavior before and after bio-oil and lignin-rich fraction treatments. In this case, bio-oil fractions did not exhibit higher water repellency than whole bio-oils. Comparison of raw bio-oils in soil block tests, with unleached wafers, at 10% and 25% bio-oil impregnation solution concentration levels showed excellent wood preservation properties at the 25% level. The good performance of raw bio-oils at higher loading levels suggests that fractionation to generate lignin-rich fractions is unnecessary. At this more effective 25% loading level in general, the raw bio-oils performed similarly. Prevention of leaching is critically important for both raw bio-oils and their fractions to provide decay resistance. Initial tests of a polymerization chemical to prevent leaching showed some success.

  12. EFFECT OF OZONE ON DIESEL EXHAUST PARTICLE TOXICITY

    EPA Science Inventory

    Ambient particulate matter (PM) concentrations have been associated with mortality and morbidity. Diesel exhaust particles (DEP) are present in ambient urban air PM. Coexisting with DEP (and PM) is ozone (O(3)), which has the potential to react with some components of DEP. Some r...

  13. Diesel fuel detergent additive performance and assessment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vincent, M.W.; Papachristos, M.J.; Williams, D.

    Diesel fuel detergent additives are increasingly linked with high quality automotive diesel fuels. Both in Europe and in the USA, field problems associated with fuel injector coking or fouling have been experienced. In Europe indirect injection (IDI) light duty engines used in passenger cars were affected, while in the USA, a direct injection (DI) engine in heavy duty truck applications experienced field problems. In both cases, a fuel additive detergent performance test has evolved using an engine linked with the original field problem, although engine design modifications employed by the manufacturers have ensured improved operation in service. Increasing awareness ofmore » the potential for injector nozzle coking to cause deterioration in engine performance is coupled with a need to meet ever more stringent exhaust emissions legislation. These two requirements indicate that the use of detergency additives will continue to be associated with high quality diesel fuels. The paper examines detergency performance evaluated in a range of IDI and DI engines and correlates performance in the two most widely recognised test engines, namely the Peugeot 1.9 litre IDI, and Cummins L10 DI engines. 17 refs., 18 figs., 5 tabs.« less

  14. pH Neutralization of Aqueous Bio-Oil from Switchgrass Intermediate Pyrolysis Using Process Intensification Devices

    DOE PAGES

    Park, Lydia Kyoung-Eun; Ren, Shoujie; Yiacoumi, Sotira; ...

    2017-07-20

    Despite the potential carbon-neutrality of switchgrass bio-oil, its high acidity and diverse chemical composition limit its utilization. The objectives of this research are to investigate pH neutralization of bio-oil by adding various alkali solutions in a batch system and then perform neutralization using process intensification devices, including a static mixer and a centrifugal contactor. The results indicate that sodium hydroxide and potassium hydroxide are more appropriate bases for pH neutralization of bio-oil than calcium hydroxide due to the limited solubility of calcium hydroxide in aqueous bio-oil. Mass and total acid number (TAN) balances were performed for both batch and continuous-flowmore » systems. Upon pH neutralization of bio-oil, the TAN values of the system increased after accounting the addition of alkali solution. A bio-oil heating experiment showed that the heat generated during pH neutralization did not cause a significant increase in the acidity of bio-oil. The formation of phenolic compounds during neutralization was initially suspected of increasing the system’s overall TAN value because some of these compounds (e.g., vanillic acid) act as polyprotic acids and have a stronger influence on the TAN value than monoprotic acids (e.g., acetic acid). The amount of phenolics in separated bio-oil phases, however, did not change significantly after pH neutralization. In conclusion, process intensification devices provided sufficient mixing and separation of the organic and aqueous phases, suggesting a scale-up route for the bio-oil pH neutralization process.« less

  15. pH Neutralization of Aqueous Bio-Oil from Switchgrass Intermediate Pyrolysis Using Process Intensification Devices

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Park, Lydia Kyoung-Eun; Ren, Shoujie; Yiacoumi, Sotira

    Despite the potential carbon-neutrality of switchgrass bio-oil, its high acidity and diverse chemical composition limit its utilization. The objectives of this research are to investigate pH neutralization of bio-oil by adding various alkali solutions in a batch system and then perform neutralization using process intensification devices, including a static mixer and a centrifugal contactor. The results indicate that sodium hydroxide and potassium hydroxide are more appropriate bases for pH neutralization of bio-oil than calcium hydroxide due to the limited solubility of calcium hydroxide in aqueous bio-oil. Mass and total acid number (TAN) balances were performed for both batch and continuous-flowmore » systems. Upon pH neutralization of bio-oil, the TAN values of the system increased after accounting the addition of alkali solution. A bio-oil heating experiment showed that the heat generated during pH neutralization did not cause a significant increase in the acidity of bio-oil. The formation of phenolic compounds during neutralization was initially suspected of increasing the system’s overall TAN value because some of these compounds (e.g., vanillic acid) act as polyprotic acids and have a stronger influence on the TAN value than monoprotic acids (e.g., acetic acid). The amount of phenolics in separated bio-oil phases, however, did not change significantly after pH neutralization. In conclusion, process intensification devices provided sufficient mixing and separation of the organic and aqueous phases, suggesting a scale-up route for the bio-oil pH neutralization process.« less

  16. A nonlinear Kalman filtering approach to embedded control of turbocharged diesel engines

    NASA Astrophysics Data System (ADS)

    Rigatos, Gerasimos; Siano, Pierluigi; Arsie, Ivan

    2014-10-01

    The development of efficient embedded control for turbocharged Diesel engines, requires the programming of elaborated nonlinear control and filtering methods. To this end, in this paper nonlinear control for turbocharged Diesel engines is developed with the use of Differential flatness theory and the Derivative-free nonlinear Kalman Filter. It is shown that the dynamic model of the turbocharged Diesel engine is differentially flat and admits dynamic feedback linearization. It is also shown that the dynamic model can be written in the linear Brunovsky canonical form for which a state feedback controller can be easily designed. To compensate for modeling errors and external disturbances the Derivative-free nonlinear Kalman Filter is used and redesigned as a disturbance observer. The filter consists of the Kalman Filter recursion on the linearized equivalent of the Diesel engine model and of an inverse transformation based on differential flatness theory which enables to obtain estimates for the state variables of the initial nonlinear model. Once the disturbances variables are identified it is possible to compensate them by including an additional control term in the feedback loop. The efficiency of the proposed control method is tested through simulation experiments.

  17. Emissions of Transport Refrigeration Units with CARB Diesel, Gas-to-Liquid Diesel, and Emissions Control Devices

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barnitt, R. A.; Chernich, D.; Burnitzki, M.

    2010-05-01

    A novel in situ method was used to measure emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. Test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. Exhaust configurations were a stock muffler and a Thermo King pDPF diesel particulate filter. The TRU engine operating speeds were high and low, controlled by the TRU user interface. Results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine speeds. Application of a Thermo King pDPF reduced regulated emissions, sometimesmore » almost entirely. The application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine speed, but showed an increase in oxides of nitrogen at low engine speed.« less

  18. Approach for energy saving and pollution reducing by fueling diesel engines with emulsified biosolution/ biodiesel/diesel blends.

    PubMed

    Lin, Yuan-Chung; Lee, Wen-Jhy; Chao, How-Ran; Wang, Shu-Li; Tsou, Tsui-Chun; Chang-Chien, Guo-Ping; Tsai, Perng-Jy

    2008-05-15

    The developments of both biodiesel and emulsified diesel are being driven by the need for reducing emissions from diesel engines and saving energy. Artificial chemical additives are also being used in diesel engines for increasing their combustion efficiencies. But the effects associated with the use of emulsified additive/biodiesel/diesel blends in diesel engines have never been assessed. In this research, the premium diesel fuel (PDF) was used as the reference fuel. A soy-biodiesel was selected as the test biodiesel. A biosolution made of 96.5 wt % natural organic enzyme-7F (NOE-7F) and 3.5 wt % water (NOE-7F water) was used as the fuel additive. By adding additional 1 vol % of surfactant into the fuel blend, a nanotechnology was used to form emulsified biosolution/soy-biodiesel/PDF blends for fueling the diesel engine. We found that the emulsified biosolution/soy-biodiesel/PDF blends did not separate after being kept motionless for 30 days. The above stability suggests that the above combinations are suitable for diesel engines as alternative fuels. Particularly, we found that the emulsified biosolution/soy-biodiesel/PDF blends did have the advantage in saving energy and reducing the emissions of both particulate matters (PM) and polycyclic aromatic hydrocarbons (PAHs) from diesel engines as compared with PDF, soy-biodiesel/PDF blends, and emulsified soy-biodiesel/ PDF blends. The results obtained from this study will provide useful approaches for reducing the petroleum reliance, pollution, and global warming. However, it should be noted that NO(x) emissions were not measured in the present study which warrants the need for future investigation.

  19. Bioelectronic platforms for optimal bio-anode of bio-electrochemical systems: From nano- to macro scopes.

    PubMed

    Kim, Bongkyu; An, Junyeong; Fapyane, Deby; Chang, In Seop

    2015-11-01

    The current trend of bio-electrochemical systems is to improve strategies related to their applicability and potential for scaling-up. To date, literature has suggested strategies, but the proposal of correlations between each research field remains insufficient. This review paper provides a correlation based on platform techniques, referred to as bio-electronics platforms (BEPs). These BEPs consist of three platforms divided by scope scale: nano-, micro-, and macro-BEPs. In the nano-BEP, several types of electron transfer mechanisms used by electrochemically active bacteria are discussed. In the micro-BEP, factors affecting the formation of conductive biofilms and transport of electrons in the conductive biofilm are investigated. In the macro-BEP, electrodes and separators in bio-anode are debated in terms of real applications, and a scale-up strategy is discussed. Overall, the challenges of each BEP are highlighted, and potential solutions are suggested. In addition, future research directions are provided and research ideas proposed to develop research interest. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Mutagenicity of diesel exhaust particle extracts: influence of fuel composition in two diesel engines

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Clark, C.R.; Henderson, T.R.; Royer, R.E.

    The influence of diesel fuel composition on mutagenicity of exhaust particle associated organic compounds has been investigated using nine fuels varying in aromatic content and distillation properties. The tests were conducted with Oldsmobile Delta-88 and Peugot 504 diesel cars operated according to the EPA Federal Test Procedure. The particulate exhaust from each test was collected on a filter, extracted in dichloromethane and the resulting extract evaluated for mutagenicity in Salmonella strain TA-100. Mutagenicity of extracts of particles collected from the Oldsmobile were highest in the higher aromatic content fuels (greater than 30%) but similar for intermediate (20%) and low (13%)more » aromatic content fuels. No influence of aromaticity on mutagenicity was observed in samples collected from the Peugeot under the same conditions. Thus, fuel aromatic content may enhance the production of mutagenic combustion products at higher concentrations, but may be dependent upon engine type. A good correlation was observed between mutagenicity of the particle extracts and the initial boiling point of the fuel (r . 0.89). Gas chromatography/mass spectrometric analysis of the aromatic fraction of the fuels showed that the fuel producing the most mutagenic combustion products was highest in phenanthrene type compounds.« less

  1. Exposure to sub-10nm particles emitted from a biodiesel-fueled diesel engine: In vitro toxicity and inflammatory potential.

    PubMed

    Malorni, Livia; Guida, Vincenzo; Sirignano, Mariano; Genovese, Giuliana; Petrarca, Claudia; Pedata, Paola

    2017-03-15

    The inflammatory effects of organic sub-10nm particles generated and emitted from a diesel engine fueled with a biodiesel and a commercial diesel oil are analyzed in this paper. Diesel combustion is the major sources of ultrafine particles (UFP) in the environment, particularly in urbanized areas. In the last years, there is an increasing use of biomass-derived fuels because they are a renewable source of energy that may mitigate climate change through the reduction of net CO 2 with respect to conventional fossil fuels. Although there is a general agreement on biofuels ability to reduce conventional pollutants, new and potentially harmful pollutants can be formed during biofuel combustion. In particular, the emission of sub-10nm particles is strongly increased with respect to that of larger soot particles. Organic sub-10nm particles are separated from larger sizes particulate matter by collection in water suspension for toxicological and inflammatory tests. After exposure to sub-10nm particles, the effects on proliferation, apoptosis and secretion of cytokines, chemokines and growth factors networks production is analyzed in immortalized non-tumorigenic human dermal keratinocyte cell line (HaCaT) and human alveolar epithelial-like cells (A549). Nanoparticles exert different cytotoxic effects in the two cell lines, suggesting that the dermal way of exposure is more sensitive than the inhalant way. These differences are most evident in the secretion of pro-inflammatory, angiogenic and proliferative cytokines and chemokines whose expression is more finely modulated in HaCaT cells compared to A-549 cells. Considering the size of these particles, it is important to promote the culture of prevention also for the dermal way in particularly exposed workers. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. AUTOMOTIVE DIESEL MAINTENANCE 1. UNIT VII, ENGINE TUNE-UP--DETROIT DIESEL ENGINE.

    ERIC Educational Resources Information Center

    Human Engineering Inst., Cleveland, OH.

    THIS MODULE OF A 30-MODULE COURSE IS DESIGNED TO DEVELOP AN UNDERSTANDING OF TUNE-UP PROCEDURES FOR DIESEL ENGINES. TOPICS ARE SCHEDULING TUNE-UPS, AND TUNE-UP PROCEDURES. THE MODULE CONSISTS OF A SELF-INSTRUCTIONAL BRANCH PROGRAMED TRAINING FILM "ENGINE TUNE-UP--DETROIT DIESEL ENGINE" AND OTHER MATERIALS. SEE VT 005 655 FOR FURTHER INFORMATION.…

  3. Diesel-powered Passenger Cars and Light Trucks

    DOT National Transportation Integrated Search

    2015-10-01

    Diesel-powered automobiles are in the news following emission concerns raised by the U.S. Environmental Protection Agency. This fact sheet contains background information on diesel-powered motor vehicles and diesel fuel.

  4. Carbonyl compounds emitted by a diesel engine fuelled with diesel and biodiesel-diesel blends: Sampling optimization and emissions profile

    NASA Astrophysics Data System (ADS)

    Guarieiro, Lílian Lefol Nani; Pereira, Pedro Afonso de Paula; Torres, Ednildo Andrade; da Rocha, Gisele Olimpio; de Andrade, Jailson B.

    Biodiesel is emerging as a renewable fuel, hence becoming a promising alternative to fossil fuels. Biodiesel can form blends with diesel in any ratio, and thus could replace partially, or even totally, diesel fuel in diesel engines what would bring a number of environmental, economical and social advantages. Although a number of studies are available on regulated substances, there is a gap of studies on unregulated substances, such as carbonyl compounds, emitted during the combustion of biodiesel, biodiesel-diesel and/or ethanol-biodiesel-diesel blends. CC is a class of hazardous pollutants known to be participating in photochemical smog formation. In this work a comparison was carried out between the two most widely used CC collection methods: C18 cartridges coated with an acid solution of 2,4-dinitrophenylhydrazine (2,4-DNPH) and impinger bottles filled in 2,4-DNPH solution. Sampling optimization was performed using a 2 2 factorial design tool. Samples were collected from the exhaust emissions of a diesel engine with biodiesel and operated by a steady-state dynamometer. In the central body of factorial design, the average of the sum of CC concentrations collected using impingers was 33.2 ppmV but it was only 6.5 ppmV for C18 cartridges. In addition, the relative standard deviation (RSD) was 4% for impingers and 37% for C18 cartridges. Clearly, the impinger system is able to collect CC more efficiently, with lower error than the C18 cartridge system. Furthermore, propionaldehyde was nearly not sampled by C18 system at all. For these reasons, the impinger system was chosen in our study. The optimized sampling conditions applied throughout this study were: two serially connected impingers each containing 10 mL of 2,4-DNPH solution at a flow rate of 0.2 L min -1 during 5 min. A profile study of the C1-C4 vapor-phase carbonyl compound emissions was obtained from exhaust of pure diesel (B0), pure biodiesel (B100) and biodiesel-diesel mixtures (B2, B5, B10, B20, B50, B

  5. Advanced automotive diesel assessment program

    NASA Technical Reports Server (NTRS)

    Sekar, R.; Tozzi, L.

    1983-01-01

    Cummins Engine Company completed an analytical study to identify an advanced automotive (light duty) diesel (AAD) power plant for a 3,000-pound passenger car. The study resulted in the definition of a revolutionary diesel engine with several novel features. A 3,000-pound car with this engine is predicted to give 96.3, 72.2, and 78.8 MPG in highway, city, and combined highway-city driving, respectively. This compares with current diesel powered cars yielding 41.7, 35.0, and 37.7 MPG. The time for 0-60 MPH acceleration is 13.9 sec. compared to the baseline of 15.2 sec. Four technology areas were identified as crucial in bringing this concept to fruition. They are: (1) part-load preheating, (2) positive displacement compounding, (3) spark assisted diesel combustion system, and (4) piston development for adiabatic, oilless diesel engine. Marketing and planning studies indicate that an aggressive program with significant commitment could result in a production car in 10 years from the date of commencement.

  6. Novel wireless health monitor with acupuncture bio-potentials obtained by using a replaceable salt-water-wetted foam-rubber cushions on RFID-tag.

    PubMed

    Lin, Jium-Ming; Lu, Hung-Han; Lin, Cheng-Hung

    2014-01-01

    This paper proposes a bio-potential measurement apparatus including a wireless device for transmitting acupuncture bio-potential information to a remote control station for health conditions analysis and monitor. The key technology of this system is to make replaceable foam-rubber cushions, double-side conducting tapes, chip and antenna on the radio frequency identification (RFID) tag. The foam-rubber cushions can be wetted with salt-water and contact with the acupuncture points to reduce contact resistance. Besides, the double-side conducting tapes are applied to fix foam-rubber cushions. Thus, one can peel the used cushions or tapes away and supply new ones quickly. Since the tag is a flexible plastic substrate, it is easy to deploy on the skin. Besides, the amplifier made by CMOS technology on RFID chip could amplify the signals to improve S/N ratio and impedance matching. Thus, cloud server can wirelessly monitor the health conditions. An example shows that the proposed system can be used as a wireless health condition monitor, the numerical method and the criteria are given to analyze eleven bio-potentials for the important acupunctures of eleven meridians on a person's hands and legs. Then a professional doctor can know the performance of an individual and the cross-linking effects of the organs.

  7. Diesel-related hydrocarbons can dominate gas phase reactive carbon in megacities

    NASA Astrophysics Data System (ADS)

    Dunmore, R. E.; Hopkins, J. R.; Lidster, R. T.; Lee, J. D.; Evans, M. J.; Rickard, A. R.; Lewis, A. C.; Hamilton, J. F.

    2015-09-01

    Hydrocarbons are key precursors to two priority air pollutants, ozone and particulate matter. Those with two to seven carbons have historically been straightforward to observe and have been successfully reduced in many developed cities through air quality policy interventions. Longer chain hydrocarbons released from diesel vehicles are not considered explicitly as part of air quality strategies and there are few direct measurements of their gaseous abundance in the atmosphere. This study describes the chemically comprehensive and continuous measurements of organic compounds in a developed megacity (London), which demonstrate that on a seasonal median basis, diesel-related hydrocarbons represent only 20-30 % of the total hydrocarbon mixing ratio but comprise more than 50 % of the atmospheric hydrocarbon mass and are a dominant local source of secondary organic aerosols. This study shows for the first time that 60 % of the winter primary hydrocarbon hydroxyl radical reactivity is from diesel-related hydrocarbons and using the maximum incremental reactivity scale, we predict that they contribute up to 50 % of the ozone production potential in London. Comparing real-world urban composition with regulatory emissions inventories in the UK and US highlights a previously unaccounted for, but very significant, under-reporting of diesel-related hydrocarbons; an underestimation of a factor ~4 for C9 species rising to a factor of over 70 for C12 during winter. These observations show that hydrocarbons from diesel vehicles can dominate gas phase reactive carbon in cities with high diesel fleet fractions. Future control of urban particulate matter and ozone in such locations requires a shift in policy focus onto gas phase hydrocarbons released from diesels as this vehicle type continues to displace gasoline world-wide.

  8. Diesel-related hydrocarbons can dominate gas phase reactive carbon in megacities

    NASA Astrophysics Data System (ADS)

    Dunmore, R. E.; Hopkins, J. R.; Lidster, R. T.; Lee, J. D.; Evans, M. J.; Rickard, A. R.; Lewis, A. C.; Hamilton, J. F.

    2015-03-01

    Hydrocarbons are key precursors to two priority air pollutants, ozone and particulate matter. Those with two to seven carbons have historically been straightforward to observe and have been successfully reduced in many developed cities through air quality policy interventions. Longer chain hydrocarbons released from diesel vehicles are not considered explicitly as part of air quality strategies and there are few direct measurements of their gaseous abundance in the atmosphere. This study describes the chemically comprehensive and continuous measurements of organic compounds in a developed megacity (London), which demonstrate that on a seasonal median basis, diesel-related hydrocarbons represent only 20-30% of the total hydrocarbon mixing ratio but comprise more than 50% of the atmospheric hydrocarbon mass and are a dominant local source of secondary organic aerosols. This study shows for the first time that, 60% of the winter primary hydrocarbon hydroxyl radical reactivity is from diesel-related hydrocarbons and using the maximum incremental reactivity scale, we predict that they contribute up to 50% of the ozone production potential in London. Comparing real-world urban composition with regulatory emissions inventories in the UK and US highlights a previously unaccounted for but, very significant under-reporting of diesel related hydrocarbons; an underestimation of a factor ~ 4 for C9 species rising to a factor of over 70 for C12 during winter. These observations show that hydrocarbons from diesel vehicles can dominate gas phase reactive carbon in cities with high diesel fleet fractions. Future control of urban particulate matter and ozone in such locations requires a shift in policy focus onto gas phase hydrocarbons released from diesels as this vehicle type continues to displace gasoline world-wide.

  9. Utilisation of Used Palm Oil as an Alternative Fuel in Thailand

    NASA Astrophysics Data System (ADS)

    Permchart, W.; Tanatvanit, S.

    2007-10-01

    This paper summarises the overview of the current situation of alternative energies in Thailand. The utilisation of bio-diesel as an alternative energy in two economic sectors (i.e. transport and industrial sectors), which have the largest energy consumption in the country, is mainly presented because it has seemed to be the most promising project among various energy conservation projects of the Thai government. Actually, there is another bio-fuel project, namely, the ethanol project for blending with gasoline to produce gasohol (E10) used in gasoline engines, which has been developed and already become to an important policy for energy conservation of the country. Due to much more large number of diesel has been utilised, the bio-diesel project has been the first priority one to solve the petroleum crisis problems. However, it is remarked that the utilisation of bio-diesel as an alternative fuel seems to be unsatisfactory because of various reasons. Some issues in terms of both government policies and technical problems have not been clearly addressed. Therefore, this paper not only presents the utilisation of bio-diesel in these two sectors but also discusses the production processes, characterisations and some experimental testing results of bio-diesel.

  10. Antibacterial and antimitotic potential of bio-fabricated zinc oxide nanoparticles of Cochlospermum religiosum (L.).

    PubMed

    Mahendra, C; Murali, M; Manasa, G; Ponnamma, Pooja; Abhilash, M R; Lakshmeesha, T R; Satish, A; Amruthesh, K N; Sudarshana, M S

    2017-09-01

    Zinc oxide nanoparticles synthesized through eco-friendly approach has gained importance among researchers due to its broad applications. In the present work, hexagonal wurtzite shape nanoparticles (below 100 nm size) were obtained using aqueous leaf extract of Cochlospermum religiosum which was confirmed through X-Ray diffraction (XRD) analysis. The synthesized ZnO-NPs showed an absorption peak at 305 nm which is one of the characteristic features of ZnO-NPs.The bio-fabricated ZnO-NPs were of high purity with an average size of ∼76 nm analyzed through Dynamic Light Scattering (DLS) analysis supporting the findings of XRD. The SEM images confirmed the same with agglomeration of smaller nanoparticles. The composition of aqueous leaf extract and ZnO-NPs was explored with Fourier Transform Infrared Spectroscopy (FT-IR). The plant extract as well as bio-fabricated ZnO-NPs offered significant inhibition against Gram-positive (B. subtilis and Staph. aureus) and Gram-negative (P. aeruginosa and E. coli) bacteria. The minimum inhibitory concentration (MIC) of bio-fabricated ZnO-NPs and plant extract was found between 4.8 and 625 μg/ml against test pathogens, which was authenticated with live and dead cell analysis. Apart from antibacterial potentiality, antimitotic activity was also observed with a mitotic index of 75.42% (ID 50 0.40 μg mL -1 ) and 61.41% (ID 50 0.58 μg mL -1 ) in ZnO-NPs and plant extract, respectively. The results affirm that plant extract and its mediated ZnO-NPs possess biological properties. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. AUTOMOTIVE DIESEL MAINTENANCE 1. UNIT XXX, I--CATERPILLAR DIESEL ENGINE MAINTENANCE SUMMARY, II--REIEWING FACTS ABOUT ALTERNATORS.

    ERIC Educational Resources Information Center

    Minnesota State Dept. of Education, St. Paul. Div. of Vocational and Technical Education.

    THIS MODULE OF A 30-MODULE COURSE IS DESIGNED TO PROVIDE A SUMMARY OF DIESEL ENGINE MAINTENANCE FACTORS AND A REVIEW OF DIESEL ENGINE ALTERNATOR OPERATION. THE SEVEN SECTIONS COVER DIESEL ENGINE TROUBLESHOOTING AND THE OPERATION, TESTING, AND ADJUSTING OF ALTERNATORS. THE MODULE CONSISTS OF A SELF-INSTRUCTIONAL BRANCH PROGRAMED TRAINING FILM…

  12. Assessments of chromium (and other metals) in vegetables and potential bio-accumulations in humans living in areas affected by tannery wastes.

    PubMed

    Chen, Hualin; Arocena, Joselito M; Li, Jianbing; Thring, Ronald W; Zhou, Jiangmin

    2014-10-01

    Chromium (Cr) commonly enters the food chain through uptake by vegetables. However, accurate prediction of plant uptake of Cr (and other metals) still remains a challenge. In this study, we evaluated 5 indices of availability for Cr (and other metals) to identify reliable predictors of metal transfer from soils to garlic, onion, bokchoy, radish and celery grown in soils impacted by tannery wastes. The potential bio-accumulation of Cr in humans was calculated from the Cr content of vegetable predicted by the best bio-availability index, amounts of vegetable consumed and recommended daily doses for Cr. Our results show that soil total Cr is the best predictor of Cr transfer from soils to onion (Cr in onion=8.51+0.005 Total Cr) while Cr extractable by Synthetic Precipitation Leaching Procedure at pH 5 correlates very well with Cr uptake by bokchoy (Cr bokchoy=5.86+7.32 SPLP-5 Cr) and garlic (Cr garlic=7.63+2.36 SPLP-5 Cr). The uptake of Cr by radish and celery could not be reliably estimated by any of the 5 indices of availability tested in this study. Potential bio-accumulation of Cr in humans (BA-Cr) increases from soils with low Cr (BA-Cr=11.5) to soil with high total Cr (BA-Cr=31.3). Due to numerous soil factors affecting the behavior of Cr in soils and the physiological differences among vegetables, we suggest that the prediction of the transfer of Cr (and other metals) from soils to plants should be specific to site, metal and vegetable. Potential bio-accumulation of Cr in humans can be derived from a transfer function of Cr from soils to plants and the human consumption of vegetables. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Fundamentals of Diesel Engines.

    ERIC Educational Resources Information Center

    Marine Corps Inst., Washington, DC.

    This student guide, one of a series of correspondence training courses designed to improve the job performance of members of the Marine Corps, deals with the fundamentals of diesel engine mechanics. Addressed in the three individual units of the course are the following topics: basic principles of diesel mechanics; principles, mechanics, and…

  14. Clean Diesel National Grants Awarded

    EPA Pesticide Factsheets

    National Funding Assistance Program administers competitive grants for clean diesel projects. The Diesel Emissions Reduction Act (DERA) appropriates funds for these projects. Publication numbers: EPA-420-B-13-025 and EPA-420-P-11-001.

  15. Water-in-diesel emulsions and related systems.

    PubMed

    Lif, Anna; Holmberg, Krister

    2006-11-16

    Water-in-diesel emulsions are fuels for regular diesel engines. The advantages of an emulsion fuel are reductions in the emissions of nitrogen oxides and particulate matters, which are both health hazardous, and reduction in fuel consumption due to better burning efficiency. An important aspect is that diesel emulsions can be used without engine modifications. This review presents the influence of water on the emissions and on the combustion efficiency. Whereas there is a decrease in emissions of nitrogen oxides and particulate matters, there is an increase in the emissions of hydrocarbons and carbon monoxide with increasing water content of the emulsion. The combustion efficiency is improved when water is emulsified with diesel. This is a consequence of the microexplosions, which facilitate atomization of the fuel. The review also covers related fuels, such as diesel-in-water-in-diesel emulsions, i.e., double emulsions, water-in-diesel microemulsions, and water-in-vegetable oil emulsions, i.e., biodiesel emulsions. A brief overview of other types of alternative fuels is also included.

  16. Russia's black carbon emissions: focus on diesel sources

    NASA Astrophysics Data System (ADS)

    Kholod, Nazar; Evans, Meredydd; Kuklinski, Teresa

    2016-09-01

    Black carbon (BC) is a significant climate forcer with a particularly pronounced forcing effect in polar regions such as the Russian Arctic. Diesel combustion is a major global source of BC emissions, accounting for 25-30 % of all BC emissions. While the demand for diesel is growing in Russia, the country's diesel emissions are poorly understood. This paper presents a detailed inventory of Russian BC emissions from diesel sources. Drawing on a complete Russian vehicle registry with detailed information about vehicle types and emission standards, this paper analyzes BC emissions from diesel on-road vehicles. We use the COPERT emission model (COmputer Programme to calculate Emissions from Road Transport) with Russia-specific emission factors for all types of on-road vehicles. On-road diesel vehicles emitted 21 Gg of BC in 2014: heavy-duty trucks account for 60 % of the on-road BC emissions, while cars represent only 5 % (light commercial vehicles and buses account for the remainder). Using Russian activity data and fuel-based emission factors, the paper also presents BC emissions from diesel locomotives and ships, off-road engines in industry, construction and agriculture, and generators. The study also factors in the role of superemitters in BC emissions from diesel on-road vehicles and off-road sources. The total emissions from diesel sources in Russia are estimated to be 49 Gg of BC and 17 Gg of organic carbon (OC) in 2014. Off-road diesel sources emitted 58 % of all diesel BC in Russia.

  17. Diesel Mechanics: Fuel Systems.

    ERIC Educational Resources Information Center

    Foutes, William

    This publication is the third in a series of three texts for a diesel mechanics curriculum. Its purpose is to teach the concepts related to fuel injection systems in a diesel trade. The text contains eight units. Each instructional unit includes some or all of these basic components: unit and specific (performance) objectives, suggested activities…

  18. Diesel Mechanics: Electrical Systems.

    ERIC Educational Resources Information Center

    Foutes, William; And Others

    This publication is the second in a series of three texts for a diesel mechanics curriculum. Its purpose is to teach the concepts related to electricity and circuitry in a diesel trade. The text contains nine units. Each instructional unit includes some or all of these basic components: unit and specific (performance) objectives, suggested…

  19. Inhalation of diesel exhaust and allergen alters human bronchial epithelium DNA methylation.

    PubMed

    Clifford, Rachel L; Jones, Meaghan J; MacIsaac, Julia L; McEwen, Lisa M; Goodman, Sarah J; Mostafavi, Sara; Kobor, Michael S; Carlsten, Chris

    2017-01-01

    Allergic disease affects 30% to 40% of the world's population, and its development is determined by the interplay between environmental and inherited factors. Air pollution, primarily consisting of diesel exhaust emissions, has increased at a similar rate to allergic disease. Exposure to diesel exhaust may play a role in the development and progression of allergic disease, in particular allergic respiratory disease. One potential mechanism underlying the connection between air pollution and increased allergic disease incidence is DNA methylation, an epigenetic process with the capacity to integrate gene-environment interactions. We sought to investigate the effect of allergen and diesel exhaust exposure on bronchial epithelial DNA methylation. We performed a randomized crossover-controlled exposure study to allergen and diesel exhaust in humans, and measured single-site (CpG) resolution global DNA methylation in bronchial epithelial cells. Exposure to allergen alone, diesel exhaust alone, or allergen and diesel exhaust together (coexposure) led to significant changes in 7 CpG sites at 48 hours. However, when the same lung was exposed to allergen and diesel exhaust but separated by approximately 4 weeks, significant changes in more than 500 sites were observed. Furthermore, sites of differential methylation differed depending on which exposure was experienced first. Functional analysis of differentially methylated CpG sites found genes involved in transcription factor activity, protein metabolism, cell adhesion, and vascular development, among others. These findings suggest that specific exposures can prime the lung for changes in DNA methylation induced by a subsequent insult. Copyright © 2016 American Academy of Allergy, Asthma & Immunology. Published by Elsevier Inc. All rights reserved.

  20. [Particulate distribution characteristics of Chinese phrase V diesel engine based on butanol-diesel blends].

    PubMed

    Lou, Di-Ming; Xu, Ning; Fan, Wen-Jia; Zhang, Tao

    2014-02-01

    With a common rail diesel engine without any modification and the engine exhaust particle number and particle size analyzer EEPS, this study used the air-fuel ratio to investigate the particulate number concentration, mass concentration and number distribution characteristics of a diesel engine fueled with butanol-diesel blends (Bu10, Bu15, Bu20, Bu30 and Bu40) and petroleum diesel. The results show: for all test fuels, the particle number distributions turn to be unimodal. With the increasing of butanol, numbers of nucleation mode particles and small accumulation mode particle decrease. At low speed and low load conditions, the number of large accumulation mode particle increases slightly, but under higher speed and load conditions, the number does not increase. When the fuels contain butanol, the total particle number concentration and mass concentration in all conditions decrease and that is more obvious at high speed load.

  1. Effects of the biodiesel blend fuel on aldehyde emissions from diesel engine exhaust

    NASA Astrophysics Data System (ADS)

    Peng, Chiung-Yu; Yang, Hsi-Hsien; Lan, Cheng-Hang; Chien, Shu-Mei

    Interest in use of biodiesel fuels derived from vegetable oils or animal fats as alternative fuels for petroleum-based diesels has increased due to biodiesels having similar properties of those of diesels, and characteristics of renewability, biodegradability and potential beneficial effects on exhaust emissions. Generally, exhaust emissions of regulated pollutants are widely studied and the results favor biodiesels on CO, HC and particulate emissions; however, limited and inconsistent data are showed for unregulated pollutants, such as carbonyl compounds, which are also important indicators for evaluating available vehicle fuels. For better understanding biodiesel, this study examines the effects of the biodiesel blend fuel on aldehyde chemical emissions from diesel engine exhausts in comparison with those from the diesel fuel. Test engines (Mitsubishi 4M40-2AT1) with four cylinders, a total displacement of 2.84 L, maximum horsepower of 80.9 kW at 3700 rpm, and maximum torque of 217.6 N m at 2000 rpm, were mounted and operated on a Schenck DyNAS 335 dynamometer. Exhaust emission tests were performed several times for each fuel under the US transient cycle protocol from mileages of 0-80,000 km with an interval of 20,000 km, and two additional measurements were carried out at 40,000 and 80,000 km after maintenance, respectively. Aldehyde samples were collected from diluted exhaust by using a constant volume sampling system. Samples were extracted and analyzed by the HPLC/UV system. Dominant aldehydes of both fuels' exhausts are formaldehyde and acetaldehyde. These compounds together account for over 75% of total aldehyde emissions. Total aldehyde emissions for B20 (20% waste cooking oil biodiesel and 80% diesel) and diesel fuels are in the ranges of 15.4-26.9 mg bhp-h -1 and 21.3-28.6 mg bhp-h -1, respectively. The effects of increasing mileages and maintenance practice on aldehyde emissions are insignificant for both fuels. B20 generates slightly less emission than

  2. Recent Developments in BMW's Diesel Technology

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Steinparzer, F

    2003-08-24

    The image of BMW is very strongly associated to high power, sports biased, luxury cars in the premium car segment, however, particularly in the United States and some parts of Asia, the combination of a car in this segment with a diesel engine was up until now almost unthinkable. I feel sure that many people in the USA are not even aware that BMW produces diesel-powered cars. In Europe there is a completely contrary situation which, driven by the relative high fuel price, and the noticeable difference between gasoline and diesel prices, there has been a continuous growth in themore » diesel market since the early eighties. During this time BMW has accumulated more then 20 years experience in developing and producing powerful diesel engines for sports and luxury cars. BMW started the production of its 1st generation diesel engine in 1983 with a 2,4 l, turbocharged IDI engine in the 5 series model range. With a specific power of 35 kW/l, this was the most powerful diesel engine on the market at this time. In 1991 BMW introduced the 2nd generation diesel engine, beginning with a 2,5 l inline six, followed in 1994 by a 1,7 l inline four. All engines of this 2nd BMW diesel engine family were turbocharged and utilized an indirect injection combustion system. With the availability of high-pressure injection systems such as the common rail system, BMW developed its 3rd diesel engine family which consists of four different engines. The first was the 4-cylinder for the 3 series car in the spring of 1998, followed by the 6-cylinder in the fall of 1998 and then in mid 1999 by the worlds first V8 passenger car diesel with direct injection. Beginning in the fall of 2001 with the 4-cylinder, BMW reworked this DI engine family fundamentally. Key elements are an improved core engine design, the use of the common rail system of the 2nd generation and a new engine control unit with even better performance. Step by step, these technological improvements were introduce d to

  3. DI Diesel Performance and Emissions Model

    DTIC Science & Technology

    1998-03-31

    Skeletal mechanism for NOx chemistry in Diesel engines ," SAE Paper 981450. Mori, K. (1997), "Worldwide...Based on the review discussed above, Mellor et al. (1998) postulate a skeletal mechanism for NO chemistry in DI Diesel engines . This mechanism is... mechanism for NOx chemistry in Diesel engines ," SAE Paper 981450. Various Internal Ford Reports, Ford Motor Company, Dearborn, MI. 29

  4. Phytotoxicity testing of diesel-contaminated water using Petunia grandiflora Juss. Mix F1 and Marigold-Nemo Mix (Tagetes patula L.).

    PubMed

    Wante, Solomon Peter; Leung, David W M

    2018-06-17

    Tagetes patula (marigold) and Petunia grandiflora (petunia) have been shown to exhibit potential in phytoremediation of environmental pollutants including heavy metals and textile dyes. To investigate their phytoremediation potential of diesel, it was necessary to evaluate diesel phytotoxicity of these two ornamental plants. Marigold and petunia seeds were incubated, for 10 and 15 days, respectively, in deionised water contaminated with 0 to 4%, v/v, diesel in Petri dishes in a growth room with continuous lighting at 25 °C. It was found that as far as seed germination was concerned, petunia was less sensitive than marigold to 4% diesel in water. In contrast, petunia exhibited poorer seedling root growth than marigold in the presence of diesel contamination. This finding of differential sensitivity of these two ornamental plants to diesel-contaminated water during germination and seedling growth has not been reported before. Therefore, the implications of phytotoxicity evaluation and comparison between different species or genotypes of plants at both seed germination and postgermination seedling growth should both be taken into consideration in screening tolerant plants for phytoremediation.

  5. MUTAGENIC AND CARCINOGENIC POTENCY OF EXTRACTS OF DIESEL AND RELATED ENVIRONMENTAL EMISSIONS: SUMMARY AND DISCUSSION OF THE RESULTS

    EPA Science Inventory

    The proposed conversion from gasoline powered automobiles to diesel powered vehicles has prompted the Environmental Protection Agency to evaluate the potential health effects associated with exposure to diesel emissions. At present, there is no direct epidemiological link between...

  6. Technical and economic study of Stirling and Rankine cycle bottoming systems for heavy truck diesel engines

    NASA Technical Reports Server (NTRS)

    Kubo, I.

    1987-01-01

    Bottoming cycle concepts for heavy duty transport engine applications were studied. In particular, the following tasks were performed: (1) conceptual design and cost data development for Stirling systems; (2) life-cycle cost evaluation of three bottoming systems - organic Rankine, steam Rankine, and Stirling cycles; and (3) assessment of future directions in waste heat utilization research. Variables considered for the second task were initial capital investments, fuel savings, depreciation tax benefits, salvage values, and service/maintenance costs. The study shows that none of the three bottoming systems studied are even marginally attractive. Manufacturing costs have to be reduced by at least 65%. As a new approach, an integrated Rankine/Diesel system was proposed. It utilizes one of the diesel cylinders as an expander and capitalizes on the in-cylinder heat energy. The concept eliminates the need for the power transmission device and a sophisticated control system, and reduces the size of the exhaust evaporator. Results of an economic evaluation indicate that the system has the potential to become an attractive package for end users.

  7. INHIBITION OF TYROSINE PHOSPHATASE ACTIVITY INITIATES RECEPTOR SIGNALING IN AIRWAY EPITHELIAL CELLS EXPOSED TO DIESEL EXHAUST PARTICLES

    EPA Science Inventory

    Exposure to particulate matter is associated with increased cardiopulmonary morbidity and mortality. Diesel exhaust particles (DEP) are a major component of PM in urban areas and may contribute to PM toxicity through a mechanism involving pulmonary inflammation. Expression of inf...

  8. Identification and quantification analysis of nonlinear dynamics properties of combustion instability in a diesel engine

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Li-Ping, E-mail: yangliping302@hrbeu.edu.cn; Ding, Shun-Liang; Song, En-Zhe

    The cycling combustion instabilities in a diesel engine have been analyzed based on chaos theory. The objective was to investigate the dynamical characteristics of combustion in diesel engine. In this study, experiments were performed under the entire operating range of a diesel engine (the engine speed was changed from 600 to 1400 rpm and the engine load rate was from 0% to 100%), and acquired real-time series of in-cylinder combustion pressure using a piezoelectric transducer installed on the cylinder head. Several methods were applied to identify and quantitatively analyze the combustion process complexity in the diesel engine including delay-coordinate embedding, recurrencemore » plot (RP), Recurrence Quantification Analysis, correlation dimension (CD), and the largest Lyapunov exponent (LLE) estimation. The results show that the combustion process exhibits some determinism. If LLE is positive, then the combustion system has a fractal dimension and CD is no more than 1.6 and within the diesel engine operating range. We have concluded that the combustion system of diesel engine is a low-dimensional chaotic system and the maximum values of CD and LLE occur at the lowest engine speed and load. This means that combustion system is more complex and sensitive to initial conditions and that poor combustion quality leads to the decrease of fuel economy and the increase of exhaust emissions.« less

  9. Identification and quantification analysis of nonlinear dynamics properties of combustion instability in a diesel engine.

    PubMed

    Yang, Li-Ping; Ding, Shun-Liang; Litak, Grzegorz; Song, En-Zhe; Ma, Xiu-Zhen

    2015-01-01

    The cycling combustion instabilities in a diesel engine have been analyzed based on chaos theory. The objective was to investigate the dynamical characteristics of combustion in diesel engine. In this study, experiments were performed under the entire operating range of a diesel engine (the engine speed was changed from 600 to 1400 rpm and the engine load rate was from 0% to 100%), and acquired real-time series of in-cylinder combustion pressure using a piezoelectric transducer installed on the cylinder head. Several methods were applied to identify and quantitatively analyze the combustion process complexity in the diesel engine including delay-coordinate embedding, recurrence plot (RP), Recurrence Quantification Analysis, correlation dimension (CD), and the largest Lyapunov exponent (LLE) estimation. The results show that the combustion process exhibits some determinism. If LLE is positive, then the combustion system has a fractal dimension and CD is no more than 1.6 and within the diesel engine operating range. We have concluded that the combustion system of diesel engine is a low-dimensional chaotic system and the maximum values of CD and LLE occur at the lowest engine speed and load. This means that combustion system is more complex and sensitive to initial conditions and that poor combustion quality leads to the decrease of fuel economy and the increase of exhaust emissions.

  10. Composition and parameters of household bio-waste in four seasons.

    PubMed

    Hanc, Ales; Novak, Pavel; Dvorak, Milan; Habart, Jan; Svehla, Pavel

    2011-07-01

    Bio-waste makes up almost half portion of municipal solid waste. The characterization of household bio-waste is important in determining the most appropriate treatment method. The differences in composition and parameters of bio-waste derived from urban settlement (U-bio-waste) and family houses (F-bio-waste) during the four climate seasons are described in this paper. Twelve components and 20 parameters for bio-waste were evaluated. The composition of U-bio-waste was almost steady over those seasons, unlike F-bio-waste. U-bio-waste was comprised mainly (58.2%) of fruit and vegetable debris. F-bio-waste was primarily made up of seasonal garden components. The amount of variation among seasons in both type of bio-waste increased in sequence: basic parameterspotentially toxic elements. Spearman's correlations among proportions of individual components and parameters of bio-waste were found out. Results of this research could be utilized to support another composition and parameters of bio-waste and be suitable for establishing bio-waste processing. Copyright © 2011 Elsevier Ltd. All rights reserved.

  11. Health effects of subchronic exposure to environmental levels of diesel exhaust.

    PubMed

    Reed, M D; Gigliotti, A P; McDonald, J D; Seagrave, J C; Seilkop, S K; Mauderly, J L

    2004-04-01

    Diesel exhaust is a public health concern and contributor to both ambient and occupational air pollution. As part of a general health assessment of multiple anthropogenic source emissions conducted by the National Environmental Respiratory Center (NERC), a series of health assays was conducted on rats and mice exposed to environmentally relevant levels of diesel exhaust. This article summarizes the study design and exposures, and reports findings on several general indicators of toxicity and carcinogenic potential. Diesel exhaust was generated from a commonly used 2000 model 5.9-L, 6-cylinder turbo diesel engine operated on a variable-load heavy-duty test cycle burning national average certification fuel. Animals were exposed to clean air (control) or four dilutions of whole emissions based on particulate matter concentration (30, 100, 300, and 1000 microg/m(3)). Male and female F344 rats and A/J mice were exposed by whole-body inhalation 6 h/day, 7 days/wk, for either 1 wk or 6 mo. Exposures were characterized in detail. Effects of exposure on clinical observations, body and organ weights, serum chemistry, hematology, histopathology, bronchoalveolar lavage, and serum clotting factors were mild. Significant exposure-related effects occurring in both male and female rats included decreases in serum cholesterol and clotting Factor VII and slight increases in serum gamma-glutamyl transferase. Several other responses met screening criteria for significant exposure effects but were not consistent between genders or exposure times and were not corroborated by related parameters. Carcinogenic potential as determined by micronucleated reticulocyte counts and proliferation of adenomas in A/J mice were unaffected by 6 mo of exposure. Parallel studies demonstrated effects on cardiac function and resistance to viral infection; however, the results reported here show few and only modest health hazards from subchronic or shorter exposures to realistic concentrations of

  12. 30 CFR 75.1905 - Dispensing of diesel fuel.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Dispensing of diesel fuel. 75.1905 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1905 Dispensing of diesel fuel. (a) Diesel-powered equipment in underground coal mines may be refueled only from safety cans...

  13. 30 CFR 75.1905 - Dispensing of diesel fuel.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Dispensing of diesel fuel. 75.1905 Section 75... HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1905 Dispensing of diesel fuel. (a) Diesel-powered equipment in underground coal mines may be refueled only from safety cans...

  14. Rahnella sp. strain EK12: Cell surface properties and diesel oil biodegradation after long-term contact with natural surfactants and diesel oil.

    PubMed

    Smułek, Wojciech; Zdarta, Agata; Guzik, Urszula; Dudzińska-Bajorek, Beata; Kaczorek, Ewa

    2015-07-01

    The changes in cell surface properties of Rahnella sp. strain EK12 and modifications in genetic material after long-term contact with saponins and rhamnolipids, were investigated. Rhamnolipids caused a decrease of hydrophobicity in liquid cultures compared with saponins. On the other hand, in cultures with rhamnolipids, the addition of diesel oil results in a rapid rise of cell surface hydrophobicity. The similar effect was not so significant in the presence of saponins. For the bacteria grown in the presence of saponins or rhamnolipids, but without diesel oil, the ratio of unsaturated to saturated fatty acids decreased, in comparison to the control culture. The differences observed in hydrophobicity, zeta potential and fatty acids profiles, indicated various mechanisms of an interaction between a surfactant and a bacterial cells. The results have also shown an impact of the long-term contact on changes in genetic material of Rahnella sp. strain EK12 cells. Moreover, the presence of saponins led to significant increase of diesel oil biodegradation. Copyright © 2015 Elsevier GmbH. All rights reserved.

  15. Russia's black carbon emissions: focus on diesel sources

    DOE PAGES

    Kholod, Nazar; Evans, Meredydd; Kuklinski, Teresa

    2016-09-12

    Black carbon (BC) is a significant climate forcer with a particularly pronounced forcing effect in polar regions such as the Russian Arctic. Diesel combustion is a major global source of BC emissions, accounting for 25–30 % of all BC emissions. While the demand for diesel is growing in Russia, the country's diesel emissions are poorly understood. This paper presents a detailed inventory of Russian BC emissions from diesel sources. Drawing on a complete Russian vehicle registry with detailed information about vehicle types and emission standards, this paper analyzes BC emissions from diesel on-road vehicles. We use the COPERT emission modelmore » (COmputer Programme to calculate Emissions from Road Transport) with Russia-specific emission factors for all types of on-road vehicles. On-road diesel vehicles emitted 21 Gg of BC in 2014: heavy-duty trucks account for 60% of the on-road BC emissions, while cars represent only 5% (light commercial vehicles and buses account for the remainder). Using Russian activity data and fuel-based emission factors, the paper also presents BC emissions from diesel locomotives and ships, off-road engines in industry, construction and agriculture, and generators. The study also factors in the role of superemitters in BC emissions from diesel on-road vehicles and off-road sources. The total emissions from diesel sources in Russia are estimated to be 49 Gg of BC and 17 Gg of organic carbon (OC) in 2014. Off-road diesel sources emitted 58% of all diesel BC in Russia.« less

  16. Russia's black carbon emissions: focus on diesel sources

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kholod, Nazar; Evans, Meredydd; Kuklinski, Teresa

    Black carbon (BC) is a significant climate forcer with a particularly pronounced forcing effect in polar regions such as the Russian Arctic. Diesel combustion is a major global source of BC emissions, accounting for 25–30 % of all BC emissions. While the demand for diesel is growing in Russia, the country's diesel emissions are poorly understood. This paper presents a detailed inventory of Russian BC emissions from diesel sources. Drawing on a complete Russian vehicle registry with detailed information about vehicle types and emission standards, this paper analyzes BC emissions from diesel on-road vehicles. We use the COPERT emission modelmore » (COmputer Programme to calculate Emissions from Road Transport) with Russia-specific emission factors for all types of on-road vehicles. On-road diesel vehicles emitted 21 Gg of BC in 2014: heavy-duty trucks account for 60% of the on-road BC emissions, while cars represent only 5% (light commercial vehicles and buses account for the remainder). Using Russian activity data and fuel-based emission factors, the paper also presents BC emissions from diesel locomotives and ships, off-road engines in industry, construction and agriculture, and generators. The study also factors in the role of superemitters in BC emissions from diesel on-road vehicles and off-road sources. The total emissions from diesel sources in Russia are estimated to be 49 Gg of BC and 17 Gg of organic carbon (OC) in 2014. Off-road diesel sources emitted 58% of all diesel BC in Russia.« less

  17. Russia's black carbon emissions: focus on diesel sources

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kholod, Nazar; Evans, Meredydd; Kuklinski, Teresa

    Black carbon (BC) is a significant climate forcer with a particularly pronounced forcing effect in polar regions such as the Russian Arctic. Diesel combustion is a major global source of BC emissions, accounting for 25–30% of all BC emissions. While the demand for diesel is growing in Russia, the country's diesel emissions are poorly understood. This paper presents a detailed inventory of Russian BC emissions from diesel sources. Drawing on a complete Russian vehicle registry with detailed information about vehicle types and emission standards, this paper analyzes BC emissions from diesel on-road vehicles. We use the COPERT emission model (COmputermore » Programme to calculate Emissions from Road Transport) with Russia-specific emission factors for all types of on-road vehicles. On-road diesel vehicles emitted 21 Gg of BC in 2014: heavy-duty trucks account for 60% of the on-road BC emissions, while cars represent only 5% (light commercial vehicles and buses account for the remainder). Using Russian activity data and fuel-based emission factors, the paper also presents BC emissions from diesel locomotives and ships, off-road engines in industry, construction and agriculture, and generators. The study also factors in the role of superemitters in BC emissions from diesel on-road vehicles and off-road sources. The total emissions from diesel sources in Russia are estimated to be 49 Gg of BC and 17 Gg of organic carbon (OC) in 2014. Off-road diesel sources emitted 58% of all diesel BC in Russia.« less

  18. Recycling of food waste for fuel precursors using an integrated bio-refinery approach.

    PubMed

    Karthikeyan, O P; Nguyen Hao, H T; Razaghi, Ali; Heimann, Kirsten

    2018-01-01

    The main aim was to integrate FW-recycling with cultivation of Rhodotorula glutinis and anaerobic digestion (AD) for bio-energy and -fuel recovery. Mixed FW was mechanically macerated (Pcon) and hydrolysed (at 250gL -1 water) via chemical (Ch), thermal (Th) and TCh (combined Ch and Th) treatments. Cleared hydrolysates from individual pre-treatment processes were used as culture medium for cultivation of R. glutinis, while the residual solids (RS) were subjected to AD. Pcon cultivation yielded maximal R. glutinis dry weight biomass (5.18gL -1 ) and total fatty acid contents (1.03gg -1 DW biomass ). Dominant fatty acid methyl esters (FAME) were Palmitic - (C 16:0 -26%); Stearic - (C 18:0 -17%) and Oleic acids (C 18:1 -38%), ideal for bio-diesel production. Highest methane yields (actual ∼0.139m 3 kg -1 volatile solids) were measured from AD of Th-derived RS. Thus integrated FW recycling approaches will be more feasible for generating energy and economic incentives. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Bio-Security Proficiencies Project for Beginning Producers in 4-H

    ERIC Educational Resources Information Center

    Smith, Martin H.; Meehan, Cheryl L.; Borba, John A.

    2014-01-01

    Improving bio-security practices among 4-H members who raise and show project animals is important. Bio-security measures can reduce the risk of disease spread and mitigate potential health and economic risks of disease outbreaks involving animal and zoonotic pathogens. Survey data provided statistical evidence that the Bio-Security Proficiencies…

  20. 40 CFR 69.52 - Non-motor vehicle diesel fuel.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... diesel vehicles and engines Its use may damage these vehicles and engines. For use in all other diesel vehicles and engines. (ii) 15 ppm sulfur diesel fuel. From June 1, 2006 through May 31, 2010. ULTRA-LOW... and engines. Recommended for use in all diesel vehicles and engines. (iii) 15 ppm sulfur diesel fuel...

  1. The Navy Biofuel Initiative Under the Defense Production Act

    DTIC Science & Technology

    2012-06-22

    Market for Biomass -Based Diesel Fuel in the Renewable Fuel Standard (RFS), by Brent D. Yacobucci, The Market for Biomass -Based Diesel Fuel in the...defense.17 During the 1970s, DOE directed a synthetic fuels program toward commercializing coal liquefaction, coal gasification , and oil shale... Biomass : Background and Policy, by Anthony Andrews and Jeffrey Logan. The Navy Biofuel Initiative Under the Defense Production Act Congressional

  2. 30 CFR 75.1901 - Diesel fuel requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ....1901 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1901 Diesel fuel... fuel purchased for use in diesel-powered equipment underground meets these requirements. (b) Flammable...

  3. 30 CFR 75.1901 - Diesel fuel requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....1901 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1901 Diesel fuel... fuel purchased for use in diesel-powered equipment underground meets these requirements. (b) Flammable...

  4. The BioC-BioGRID corpus: full text articles annotated for curation of protein–protein and genetic interactions

    PubMed Central

    Kim, Sun; Chatr-aryamontri, Andrew; Chang, Christie S.; Oughtred, Rose; Rust, Jennifer; Wilbur, W. John; Comeau, Donald C.; Dolinski, Kara; Tyers, Mike

    2017-01-01

    A great deal of information on the molecular genetics and biochemistry of model organisms has been reported in the scientific literature. However, this data is typically described in free text form and is not readily amenable to computational analyses. To this end, the BioGRID database systematically curates the biomedical literature for genetic and protein interaction data. This data is provided in a standardized computationally tractable format and includes structured annotation of experimental evidence. BioGRID curation necessarily involves substantial human effort by expert curators who must read each publication to extract the relevant information. Computational text-mining methods offer the potential to augment and accelerate manual curation. To facilitate the development of practical text-mining strategies, a new challenge was organized in BioCreative V for the BioC task, the collaborative Biocurator Assistant Task. This was a non-competitive, cooperative task in which the participants worked together to build BioC-compatible modules into an integrated pipeline to assist BioGRID curators. As an integral part of this task, a test collection of full text articles was developed that contained both biological entity annotations (gene/protein and organism/species) and molecular interaction annotations (protein–protein and genetic interactions (PPIs and GIs)). This collection, which we call the BioC-BioGRID corpus, was annotated by four BioGRID curators over three rounds of annotation and contains 120 full text articles curated in a dataset representing two major model organisms, namely budding yeast and human. The BioC-BioGRID corpus contains annotations for 6409 mentions of genes and their Entrez Gene IDs, 186 mentions of organism names and their NCBI Taxonomy IDs, 1867 mentions of PPIs and 701 annotations of PPI experimental evidence statements, 856 mentions of GIs and 399 annotations of GI evidence statements. The purpose, characteristics and possible future

  5. Production of Renewable Diesel Fuel

    DOT National Transportation Integrated Search

    2012-06-01

    Vegetable oils have been investigated as a way to provide a renewable source for diesel fuel. A successful approach to using : vegetable oils in diesel engines has been transesterification of the oils with simple alcohols to produce mono-alkyl esters...

  6. The eBioKit, a stand-alone educational platform for bioinformatics.

    PubMed

    Hernández-de-Diego, Rafael; de Villiers, Etienne P; Klingström, Tomas; Gourlé, Hadrien; Conesa, Ana; Bongcam-Rudloff, Erik

    2017-09-01

    Bioinformatics skills have become essential for many research areas; however, the availability of qualified researchers is usually lower than the demand and training to increase the number of able bioinformaticians is an important task for the bioinformatics community. When conducting training or hands-on tutorials, the lack of control over the analysis tools and repositories often results in undesirable situations during training, as unavailable online tools or version conflicts may delay, complicate, or even prevent the successful completion of a training event. The eBioKit is a stand-alone educational platform that hosts numerous tools and databases for bioinformatics research and allows training to take place in a controlled environment. A key advantage of the eBioKit over other existing teaching solutions is that all the required software and databases are locally installed on the system, significantly reducing the dependence on the internet. Furthermore, the architecture of the eBioKit has demonstrated itself to be an excellent balance between portability and performance, not only making the eBioKit an exceptional educational tool but also providing small research groups with a platform to incorporate bioinformatics analysis in their research. As a result, the eBioKit has formed an integral part of training and research performed by a wide variety of universities and organizations such as the Pan African Bioinformatics Network (H3ABioNet) as part of the initiative Human Heredity and Health in Africa (H3Africa), the Southern Africa Network for Biosciences (SAnBio) initiative, the Biosciences eastern and central Africa (BecA) hub, and the International Glossina Genome Initiative.

  7. The eBioKit, a stand-alone educational platform for bioinformatics

    PubMed Central

    Conesa, Ana; Bongcam-Rudloff, Erik

    2017-01-01

    Bioinformatics skills have become essential for many research areas; however, the availability of qualified researchers is usually lower than the demand and training to increase the number of able bioinformaticians is an important task for the bioinformatics community. When conducting training or hands-on tutorials, the lack of control over the analysis tools and repositories often results in undesirable situations during training, as unavailable online tools or version conflicts may delay, complicate, or even prevent the successful completion of a training event. The eBioKit is a stand-alone educational platform that hosts numerous tools and databases for bioinformatics research and allows training to take place in a controlled environment. A key advantage of the eBioKit over other existing teaching solutions is that all the required software and databases are locally installed on the system, significantly reducing the dependence on the internet. Furthermore, the architecture of the eBioKit has demonstrated itself to be an excellent balance between portability and performance, not only making the eBioKit an exceptional educational tool but also providing small research groups with a platform to incorporate bioinformatics analysis in their research. As a result, the eBioKit has formed an integral part of training and research performed by a wide variety of universities and organizations such as the Pan African Bioinformatics Network (H3ABioNet) as part of the initiative Human Heredity and Health in Africa (H3Africa), the Southern Africa Network for Biosciences (SAnBio) initiative, the Biosciences eastern and central Africa (BecA) hub, and the International Glossina Genome Initiative. PMID:28910280

  8. Eucalyptus biodiesel as an alternative to diesel fuel: preparation and tests on DI diesel engine.

    PubMed

    Tarabet, Lyes; Loubar, Khaled; Lounici, Mohand Said; Hanchi, Samir; Tazerout, Mohand

    2012-01-01

    Nowadays, the increasing oil consumption throughout the world induces crucial economical, security, and environmental problems. As a result, intensive researches are undertaken to find appropriate substitution to fossil fuels. In view of the large amount of eucalyptus trees present in arid areas, we focus in this study on the investigation of using eucalyptus biodiesel as fuel in diesel engine. Eucalyptus oil is converted by transesterification into biodiesel. Eucalyptus biodiesel characterization shows that the physicochemical properties are comparable to those of diesel fuel. In the second phase, a single cylinder air-cooled, DI diesel engine was used to test neat eucalyptus biodiesel and its blends with diesel fuel in various ratios (75, 50, and 25 by v%) at several engine loads. The engine combustion parameters such as peak pressure, rate of pressure rise, and heat release rate are determined. Performances and exhaust emissions are also evaluated at all operating conditions. Results show that neat eucalyptus biodiesel and its blends present significant improvements of carbon monoxide, unburned hydrocarbon, and particulates emissions especially at high loads with equivalent performances to those of diesel fuel. However, the NOx emissions are slightly increased when the biodiesel content is increased in the blend.

  9. Eucalyptus Biodiesel as an Alternative to Diesel Fuel: Preparation and Tests on DI Diesel Engine

    PubMed Central

    Tarabet, Lyes; Loubar, Khaled; Lounici, Mohand Said; Hanchi, Samir; Tazerout, Mohand

    2012-01-01

    Nowadays, the increasing oil consumption throughout the world induces crucial economical, security, and environmental problems. As a result, intensive researches are undertaken to find appropriate substitution to fossil fuels. In view of the large amount of eucalyptus trees present in arid areas, we focus in this study on the investigation of using eucalyptus biodiesel as fuel in diesel engine. Eucalyptus oil is converted by transesterification into biodiesel. Eucalyptus biodiesel characterization shows that the physicochemical properties are comparable to those of diesel fuel. In the second phase, a single cylinder air-cooled, DI diesel engine was used to test neat eucalyptus biodiesel and its blends with diesel fuel in various ratios (75, 50, and 25 by v%) at several engine loads. The engine combustion parameters such as peak pressure, rate of pressure rise, and heat release rate are determined. Performances and exhaust emissions are also evaluated at all operating conditions. Results show that neat eucalyptus biodiesel and its blends present significant improvements of carbon monoxide, unburned hydrocarbon, and particulates emissions especially at high loads with equivalent performances to those of diesel fuel. However, the NOx emissions are slightly increased when the biodiesel content is increased in the blend. PMID:22675246

  10. An In vitro Study of Bio-Control and Plant Growth Promotion Potential of Salicaceae Endophytes.

    PubMed

    Kandel, Shyam L; Firrincieli, Andrea; Joubert, Pierre M; Okubara, Patricia A; Leston, Natalie D; McGeorge, Kendra M; Mugnozza, Giuseppe S; Harfouche, Antoine; Kim, Soo-Hyung; Doty, Sharon L

    2017-01-01

    Microbial communities in the endosphere of Salicaceae plants, poplar ( Populus trichocarpa ) and willow ( Salix sitchensis ), have been demonstrated to be important for plant growth promotion, protection from biotic and abiotic stresses, and degradation of toxic compounds. Our study aimed to investigate bio-control activities of Salicaceae endophytes against various soil borne plant pathogens including Rhizoctonia solani AG-8, Fusarium culmorum, Gaeumannomyces graminis var. tritici , and Pythium ultimum . Additionally, different plant growth promoting traits such as biological nitrogen fixation (BNF), indole-3-acetic acid (IAA) biosynthesis, phosphate solubilization, and siderophore production were assessed in all bio-control positive strains. Burkholderia, Rahnella, Pseudomonas , and Curtobacterium were major endophyte genera that showed bio-control activities in the in-vitro assays. The bio-control activities of Burkholderia strains were stronger across all tested plant pathogens as compared to other stains. Genomes of sequenced Burkholderia strains WP40 and WP42 were surveyed to identify the putative genes involved in the bio-control activities. The ocf and hcnABC gene clusters responsible for biosynthesis of the anti-fungal metabolites, occidiofungin and hydrogen cyanide, are present in the genomes of WP40 and WP42. Nearly all endophyte strains showing the bio-control activities produced IAA, solubilized tricalcium phosphate, and synthesized siderophores in the culture medium. Moreover, some strains reduced acetylene into ethylene in the acetylene reduction assay, a common assay used for BNF. Salicaceae endophytes could be useful for bio-control of various plant pathogens, and plant growth promotion possibly through the mechanisms of BNF, IAA production, and nutrient acquisition.

  11. A probabilistic maintenance model for diesel engines

    NASA Astrophysics Data System (ADS)

    Pathirana, Shan; Abeygunawardane, Saranga Kumudu

    2018-02-01

    In this paper, a probabilistic maintenance model is developed for inspection based preventive maintenance of diesel engines based on the practical model concepts discussed in the literature. Developed model is solved using real data obtained from inspection and maintenance histories of diesel engines and experts' views. Reliability indices and costs were calculated for the present maintenance policy of diesel engines. A sensitivity analysis is conducted to observe the effect of inspection based preventive maintenance on the life cycle cost of diesel engines.

  12. An integrated CMOS bio-potential amplifier with a feed-forward DC cancellation topology.

    PubMed

    Parthasarathy, Jayant; Erdman, Arthur G; Redish, Aaron D; Ziaie, Babak

    2006-01-01

    This paper describes a novel technique to realize an integrated CMOS bio-potential amplifier with a feedforward DC cancellation topology. The amplifier is designed to provide substantial DC cancellation even while amplifying very low frequency signals. More than 80 dB offset rejection ratio is achieved without any external capacitors. The cancellation scheme is robust against process and temperature variations. The amplifier is fabricated through MOSIS AMI 1.5 microm technology (0.05 mm2 area). Measurement results show a gain of 43.5 dB in the pass band (<1 mHz-5 KHz), an input referred noise of 3.66 microVrms, and a current consumption of 22 microA.

  13. On the Ignition and Combustion Variances of Jet Propellant-8 and Diesel Fuel in Military Diesel Engines

    DTIC Science & Technology

    2008-09-22

    NA Displacement (cc) 1357 6468 Operating speeds (rpm) 800 – 3000 1500 – 3400 IMEP range (bar) 5 – 27 2 – 10 Boost system Shop air Turbocharger ...Council Diesel Fuel Workshop. Pickett, L.M. and Hoogterp, L., “ Fundamental Spray and Combustion Measurements of JP-8 at Diesel Conditions”, SAE...N., 1981, "Transient Performance Simulation and Analysis of Turbocharged Diesel Engines", SAE Paper 810338.

  14. Ralphs Grocery EC-Diesel Truck Fleet: Final Results

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    2003-02-01

    DOE's Office of Heavy Vehicle Technologies sponsored a research project with Ralphs Grocery Company to collect and analyze data on the performance and operation of 15 diesel trucks fueled with EC-Diesel in commercial service. These trucks were compared to 5 diesel trucks fueled with CARB diesel and operating on similar routes. This document reports this evaluation.

  15. 30 CFR 250.610 - Diesel engine air intakes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 2 2011-07-01 2011-07-01 false Diesel engine air intakes. 250.610 Section 250... Well-Workover Operations § 250.610 Diesel engine air intakes. No later than May 31, 1989, diesel engine air intakes shall be equipped with a device to shut down the diesel engine in the event of runaway...

  16. Plant tolerance to diesel minimizes its impact on soil microbial characteristics during rhizoremediation of diesel-contaminated soils.

    PubMed

    Barrutia, O; Garbisu, C; Epelde, L; Sampedro, M C; Goicolea, M A; Becerril, J M

    2011-09-01

    Soil contamination due to petroleum-derived products is an important environmental problem. We assessed the impacts of diesel oil on plants (Trifolium repens and Lolium perenne) and soil microbial community characteristics within the context of the rhizoremediation of contaminated soils. For this purpose, a diesel fuel spill on a grassland soil was simulated under pot conditions at a dose of 12,000 mg diesel kg(-1) DW soil. Thirty days after diesel addition, T. repens (white clover) and L. perenne (perennial ryegrass) were sown in the pots and grown under greenhouse conditions (temperature 25/18 °C day/night, relative humidity 60/80% day/night and a photosynthetic photon flux density of 400 μmol photon m(-2) s(-1)) for 5 months. A parallel set of unplanted pots was also included. Concentrations of n-alkanes in soil were determined as an indicator of diesel degradation. Seedling germination, plant growth, maximal photochemical efficiency of photosystem II (F(v)/F(m)), pigment composition and lipophylic antioxidant content were determined to assess the impacts of diesel on the studied plants. Soil microbial community characteristics, such as enzyme and community-level physiological profiles, were also determined and used to calculate the soil quality index (SQI). The presence of plants had a stimulatory effect on soil microbial activity. L. perenne was far more tolerant to diesel contamination than T. repens. Diesel contamination affected soil microbial characteristics, although its impact was less pronounced in the rhizosphere of L. perenne. Rhizoremediation with T. repens and L. perenne resulted in a similar reduction of total n-alkanes concentration. However, values of the soil microbial parameters and the SQI showed that the more tolerant species (L. perenne) was able to better maintain its rhizosphere characteristics when growing in diesel-contaminated soil, suggesting a better soil health. We concluded that plant tolerance is of crucial importance for the

  17. Reformulated diesel fuel and method

    DOEpatents

    McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

    2006-08-22

    A method for mathematically identifying at least one diesel fuel suitable for combustion in an automotive diesel engine with significantly reduced emissions and producible from known petroleum blendstocks using known refining processes, including the use of cetane additives (ignition improvers) and oxygenated compounds.

  18. Health Effects Associated with Inhalation Exposure to Diesel Emission Generated with and without CeO2 Nano Fuel Additive

    EPA Science Inventory

    Diesel exhaust (DE) exposure induces adverse cardiopulmonary effects. Addition of nano cerium (Ce) oxide additive to diesel fuel (DECe) increases fuel burning efficiency resulting in altered emission characteristics and potentially altered health effects. We hypothesized that inh...

  19. AUTOMOTIVE DIESEL MAINTENANCE 1. UNIT XIV, I--MAINTAINING THE AIR SYSTEM, CUMMINS DIESEL ENGINE, II--UNIT REMOVAL--TRANSMISSION.

    ERIC Educational Resources Information Center

    Human Engineering Inst., Cleveland, OH.

    THIS MODULE OF A 30-MODULE COURSE IS DESIGNED TO DEVELOP AN UNDERSTANDING OF THE OPERATING PRINCIPLES AND MAINTENANCE OF THE DIESEL ENGINE AIR SYSTEM AND THE PROCEDURES FOR TRANSMISSION REMOVAL. TOPICS ARE (1) DEFINITION OF TERMS RELATED TO THE DIESEL AIR SYSTEM, (2) PRNCIPLES OF DIESEL AIR COMPRESSORS, (3) PRINCIPLES OF AIR STARTING MOTORS, (4)…

  20. Nano-Electronics and Bio-Electronics

    NASA Technical Reports Server (NTRS)

    Srivastava, Deepak; Kwak, Dochan (Technical Monitor)

    2001-01-01

    Viewgraph presentation on Nano-Electronics and Bio-Electronics is discussed. Topics discussed include: NASA Ames nanotechnology program, Potential Carbon Nanotube (CNT) application, CNT synthesis,Computational Nanotechnology, and protein nanotubes.

  1. Emission reduction from diesel engine using fumigation methanol and diesel oxidation catalyst.

    PubMed

    Zhang, Z H; Cheung, C S; Chan, T L; Yao, C D

    2009-07-15

    This study is aimed to investigate the combined application of fumigation methanol and a diesel oxidation catalyst for reducing emissions of an in-use diesel engine. Experiments were performed on a 4-cylinder naturally-aspirated direct-injection diesel engine operating at a constant speed of 1800 rev/min for five engine loads. The experimental results show that at low engine loads, the brake thermal efficiency decreases with increase in fumigation methanol; but at high loads, it slightly increases with increase in fumigation methanol. The fumigation method results in a significant increase in hydrocarbon (HC), carbon monoxide (CO), and nitrogen dioxide (NO(2)) emissions, but decrease in nitrogen oxides (NO(x)), smoke opacity and the particulate mass concentration. For the submicron particles, the total number of particles decreases. In all cases, there is little change in geometrical mean diameter of the particles. After catalytic conversion, the HC, CO, NO(2), particulate mass and particulate number concentrations were significantly reduced at medium to high engine loads; while the geometrical mean diameter of the particles becomes larger. Thus, the combined use of fumigation methanol and diesel oxidation catalyst leads to a reduction of HC, CO, NO(x), particulate mass and particulate number concentrations at medium to high engine loads.

  2. Optimizing photo-Fenton like process for the removal of diesel fuel from the aqueous phase

    PubMed Central

    2014-01-01

    Background In recent years, pollution of soil and groundwater caused by fuel leakage from old underground storage tanks, oil extraction process, refineries, fuel distribution terminals, improper disposal and also spills during transferring has been reported. Diesel fuel has created many problems for water resources. The main objectives of this research were focused on assessing the feasibility of using photo-Fenton like method using nano zero-valent iron (nZVI/UV/H2O2) in removing total petroleum hydrocarbons (TPH) and determining the optimal conditions using Taguchi method. Results The influence of different parameters including the initial concentration of TPH (0.1-1 mg/L), H2O2 concentration (5-20 mmole/L), nZVI concentration (10-100 mg/L), pH (3-9), and reaction time (15-120 min) on TPH reduction rate in diesel fuel were investigated. The variance analysis suggests that the optimal conditions for TPH reduction rate from diesel fuel in the aqueous phase are as follows: the initial TPH concentration equals to 0.7 mg/L, nZVI concentration 20 mg/L, H2O2 concentration equals to 5 mmol/L, pH 3, and the reaction time of 60 min and degree of significance for the study parameters are 7.643, 9.33, 13.318, 15.185 and 6.588%, respectively. The predicted removal rate in the optimal conditions was 95.8% and confirmed by data obtained in this study which was between 95-100%. Conclusion In conclusion, photo-Fenton like process using nZVI process may enhance the rate of diesel degradation in polluted water and could be used as a pretreatment step for the biological removal of TPH from diesel fuel in the aqueous phase. PMID:24955242

  3. Bio-oils from biomass slow pyrolysis: a chemical and toxicological screening.

    PubMed

    Cordella, Mauro; Torri, Cristian; Adamiano, Alessio; Fabbri, Daniele; Barontini, Federica; Cozzani, Valerio

    2012-09-15

    Bio-oils were produced from bench-scale slow-pyrolysis of three different biomass samples (corn stalks, poplar and switchgrass). Experimental protocols were developed and applied in order to screen their chemical composition. Several hazardous compounds were detected in the bio-oil samples analysed, including phenols, furans and polycyclic aromatic hydrocarbons. A procedure was outlined and applied to the assessment of toxicological and carcinogenic hazards of the bio-oils. The following hazardous properties were considered: acute toxicity; ecotoxicity; chronic toxicity; carcinogenicity. Parameters related to these properties were quantified for each component identified in the bio-oils and overall values were estimated for the bio-oils. The hazard screening carried out for the three bio-oils considered suggested that: (i) hazards to human health could be associated with chronic exposures to the bio-oils; (ii) acute toxic effects on humans and eco-toxic effects on aquatic ecosystems could also be possible in the case of loss of containment; and (iii) bio-oils may present a marginal potential carcinogenicity. The approach outlined allows the collection of screening information on the potential hazards posed by the bio-oils. This can be particularly useful when limited time and analytical resources reduce the possibility to obtain detailed specific experimental data. Copyright © 2012 Elsevier B.V. All rights reserved.

  4. Application of rhamnolipid and surfactin for enhanced diesel biodegradation--effects of pH and ammonium addition.

    PubMed

    Whang, Liang-Ming; Liu, Pao-Wen G; Ma, Chih-Chung; Cheng, Sheng-Shung

    2009-05-30

    This study investigated the effects of pH and ammonium concentrations on the potential application of two biosurfactants, surfactin (SF) and rhamnolipid (RL), for enhanced diesel biodegradation with a series of bench-scale experiments. In general, compared to the experiments without biosurfactant addition, adding RL or SF to diesel-water systems at concentrations above their critical micelle concentration (CMC) values benefited diesel emulsification, and therefore enhanced diesel biodegradation. The effects of pH on RL or SF-enhanced biodegradation of diesel were in good agreement with the trends of emulsion index values for RL or SF addition, respectively, under different pH conditions, suggesting that enhanced diesel emulsification by RL or SF addition promoted biodegradation of diesel. In diesel-water systems with 50mg/L of RL addition, an optimum pH condition for microbial growth and diesel biodegradation was found to be at a pH 7.2, while decreasing pH to 5.2 or increasing it to 8.4 reduced those parameters considerably. For the cases where 40 mg/L of SF was added, the enhancing ability shared a general trend with that observed for adding 50mg/L of RL as the pH increased from 5.2 to 7.2. Further increase of pH to 8.4, however, did not seem to negatively influence biodegradation and biomass growth. With respect to the effects of ammonium concentration on diesel biodegradation in diesel-water systems with 50mg/L of RL addition, an optimum ammonium addition for microbial growth and diesel biodegradation was found between 200 and 300 mg-N/L, but a dramatic decrease in growth and biodegradation occurred at ammonium addition up to 450 mg-N/L. For the cases where 40 mg/L of SF was added, an increase of ammonium addition from 50 to 200mg-N/L substantially increased microbial growth and biodegradation of diesel. Further increase of ammonium concentration to 450 mg-N/L, however, did not further improve diesel biodegradation.

  5. Evolutionary concepts in biobanking - the BC BioLibrary

    PubMed Central

    2009-01-01

    Background Medical research to improve health care faces a major problem in the relatively limited availability of adequately annotated and collected biospecimens. This limitation is creating a growing gap between the pace of scientific advances and successful exploitation of this knowledge. Biobanks are an important conduit for transfer of biospecimens (tissues, blood, body fluids) and related health data to research. They have evolved outside of the historical source of tissue biospecimens, clinical pathology archives. Research biobanks have developed advanced standards, protocols, databases, and mechanisms to interface with researchers seeking biospecimens. However, biobanks are often limited in their capacity and ability to ensure quality in the face of increasing demand. Our strategy to enhance both capacity and quality in research biobanking is to create a new framework that repatriates the activity of biospecimen accrual for biobanks to clinical pathology. Methods The British Columbia (BC) BioLibrary is a framework to maximize the accrual of high-quality, annotated biospecimens into biobanks. The BC BioLibrary design primarily encompasses: 1) specialized biospecimen collection units embedded within clinical pathology and linked to a biospecimen distribution system that serves biobanks; 2) a systematic process to connect potential donors with biobanks, and to connect biobanks with consented biospecimens; and 3) interdisciplinary governance and oversight informed by public opinion. Results The BC BioLibrary has been embraced by biobanking leaders and translational researchers throughout BC, across multiple health authorities, institutions, and disciplines. An initial pilot network of three Biospecimen Collection Units has been successfully established. In addition, two public deliberation events have been held to obtain input from the public on the BioLibrary and on issues including consent, collection of biospecimens and governance. Conclusion The BC Bio

  6. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOEpatents

    Cortright, Randy D [Madison, WI; Dumesic, James A [Verona, WI

    2012-04-10

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  7. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOEpatents

    Cortright, Randy D.; Dumesic, James A.

    2013-04-02

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  8. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOEpatents

    Cortright, Randy D [Madison, WI; Dumesic, James A [Verona, WI

    2011-01-18

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  9. Greenhouse Gas and Noxious Emissions from Dual Fuel Diesel and Natural Gas Heavy Goods Vehicles.

    PubMed

    Stettler, Marc E J; Midgley, William J B; Swanson, Jacob J; Cebon, David; Boies, Adam M

    2016-02-16

    Dual fuel diesel and natural gas heavy goods vehicles (HGVs) operate on a combination of the two fuels simultaneously. By substituting diesel for natural gas, vehicle operators can benefit from reduced fuel costs and as natural gas has a lower CO2 intensity compared to diesel, dual fuel HGVs have the potential to reduce greenhouse gas (GHG) emissions from the freight sector. In this study, energy consumption, greenhouse gas and noxious emissions for five after-market dual fuel configurations of two vehicle platforms are compared relative to their diesel-only baseline values over transient and steady state testing. Over a transient cycle, CO2 emissions are reduced by up to 9%; however, methane (CH4) emissions due to incomplete combustion lead to CO2e emissions that are 50-127% higher than the equivalent diesel vehicle. Oxidation catalysts evaluated on the vehicles at steady state reduced CH4 emissions by at most 15% at exhaust gas temperatures representative of transient conditions. This study highlights that control of CH4 emissions and improved control of in-cylinder CH4 combustion are required to reduce total GHG emissions of dual fuel HGVs relative to diesel vehicles.

  10. Investigation of a fatality due to diesel fuel No. 2 ingestion.

    PubMed

    Martínez, María A; Ballesteros, Salomé

    2006-10-01

    This paper presents a simple, rapid, reliable, and validated analytical method suited for forensic examination of diesel fuel No. 2 in biological specimens. The proposed methodology has been applied to the investigation of a forensic case with diesel fuel No. 2 ingestion. Case history and pathological and toxicological findings are described here to illustrate the toxicity of this complex hydrocarbon mixture. The toxicological significance and the possible mechanisms leading to death are also discussed. The toxicological initial screening and quantitation were performed by means of gas chromatography with flame-ionization detection and confirmation was performed using gas chromatography-mass spectrometry in total ion chromatogram mode. n-Tetradecane peak was selected to estimate diesel fuel No. 2 in all biological samples. Diesel fuel No. 2 analytical methodology was validated at five concentration levels from 5 to 400 mg/L. The method provided extraction recoveries between 89.0% and 97.9%. The limit of detection was 1 mg/L and the limit of quantitation was 5 mg/L. The linearity of the blood calibration curves was excellent with r2 values of >0.999. Intraday and interday precisions had a coefficient of variationdiesel fuel No. 2 ingestion. Heart blood concentration was 9.1 mg/L, and concentration in the abdominal contents was 3500 mg/L (total amount 8.2 mL). Pathological findings were unusual and consisted of gastric and intestinal lesions reminiscent of effects caused by ingestion of a corrosive agent and the presence of a dark-brownish liquid with strong odor to hydrocarbons. The cause of death was attributed to intoxication with diesel fuel No. 2. The manner of death, according to the case history provided by the medical examiner, was considered suicide. Because there are no other similar references regarding analytical and toxicological data, this article provides with evidence

  11. Bio-prospecting of distillery yeasts as bio-control and bio-remediation agents.

    PubMed

    Ubeda, Juan F; Maldonado, María; Briones, Ana I; Francisco, J Fernández; González, Francisco J

    2014-05-01

    This work constitutes a preliminary study in which the capacity of non-Saccharomyces yeasts isolated from ancient distilleries as bio-control agents against moulds and in the treatment of waste waters contaminated by heavy metals-i.e. bio-remediation-is shown. In the first control assays, antagonist effect between non-Saccharomyces yeasts, their extracts and supernatants against some moulds, analysing the plausible (not exhaustive) involved factors were qualitatively verified. In addition, two enzymatic degrading properties of cell wall plant polymers, quitinolitic and pectinolitic, were screened. Finally, their use as agents of bio-remediation of three heavy metals (cadmium, chromium and lead) was analysed semi-quantitatively. The results showed that all isolates belonging to Pichia species effectively inhibited all moulds assayed. Moreover, P. kudriavzevii is a good candidate for both bio-control and bio-remediation because it inhibited moulds and accumulated the major proportion of the three tested metals.

  12. BioGraph: unsupervised biomedical knowledge discovery via automated hypothesis generation

    PubMed Central

    2011-01-01

    We present BioGraph, a data integration and data mining platform for the exploration and discovery of biomedical information. The platform offers prioritizations of putative disease genes, supported by functional hypotheses. We show that BioGraph can retrospectively confirm recently discovered disease genes and identify potential susceptibility genes, outperforming existing technologies, without requiring prior domain knowledge. Additionally, BioGraph allows for generic biomedical applications beyond gene discovery. BioGraph is accessible at http://www.biograph.be. PMID:21696594

  13. 30 CFR 75.1908 - Nonpermissible diesel-powered equipment; categories.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Nonpermissible diesel-powered equipment... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1908 Nonpermissible diesel-powered equipment; categories. (a) Heavy-duty diesel-powered...

  14. 30 CFR 75.1908 - Nonpermissible diesel-powered equipment; categories.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Nonpermissible diesel-powered equipment... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1908 Nonpermissible diesel-powered equipment; categories. (a) Heavy-duty diesel-powered...

  15. Diesel fumes do kill: a case of fatal carbon monoxide poisoning directly attributed to diesel fuel exhaust with a 10-year retrospective case and literature review*.

    PubMed

    Griffin, Sean M; Ward, Michael K; Terrell, Andrea R; Stewart, Donna

    2008-09-01

    While it is known that diesel fuel combustion engines produce much lower concentrations of carbon monoxide (CO) than gasoline engines, these emissions could certainly generate lethal ambient concentrations given a sufficient amount of time in an enclosed space and under suitable environmental conditions. The authors report a case of CO poisoning which was initially referred for autopsy as a presumed natural death of a truck driver found in the secure cab of a running diesel tractor trailer truck. Completion of the preliminary investigation ascribed death to complications of ischemic heart disease (IHD), pending toxicological analysis that included quantification of CO. When the toxicology results showed lethal blood COHbg, the cause of death was re-certified as CO intoxication secondary to inhalation of (diesel) vehicular exhaust fumes. Because of the unique source of fatal CO intoxication in this case, the contributory IHD and the possible contaminants in the putrefied blood, a 10-year retrospective review was conducted on all nonfire related CO deaths autopsied (n = 94) at the Office of the Chief Medical Examiner in Louisville, KY from 1994 to 2003. For validation of the COHbg detection method used by the Kentucky Office of Forensic Toxicology (KYOFT), blood samples from these cases along with controls were submitted to three laboratories using various analytical methods yielding no statistically significant differences. Lastly, an extensive literature review produced no scientifically reported cases of fatal CO poisoning attributed to diesel fuel exhaust.

  16. Preliminary investigation on the production of fuels and bio-char from Chlamydomonas reinhardtii biomass residue after bio-hydrogen production.

    PubMed

    Torri, Cristian; Samorì, Chiara; Adamiano, Alessio; Fabbri, Daniele; Faraloni, Cecilia; Torzillo, Giuseppe

    2011-09-01

    The aim of this work was to investigate the potential conversion of Chlamydomonas reinhardtii biomass harvested after hydrogen production. The spent algal biomass was converted into nitrogen-rich bio-char, biodiesel and pyrolysis oil (bio-oil). The yield of lipids (algal oil), obtained by solvent extraction, was 15 ± 2% w/w(dry-biomass). This oil was converted into biodiesel with a 8.7 ± 1% w/w(dry-biomass) yield. The extraction residue was pyrolysed in a fixed bed reactor at 350 °C obtaining bio-char as the principal fraction (44 ± 1% w/w(dry-biomass)) and 28 ± 2% w/w(dry-biomass) of bio-oil. Pyrolysis fractions were characterized by elemental analysis, while the chemical composition of bio-oil was fully characterized by GC-MS, using various derivatization techniques. Energy outputs resulting from this approach were distributed in hydrogen (40%), biodiesel (12%) and pyrolysis fractions (48%), whereas bio-char was the largest fraction in terms of mass. Copyright © 2011 Elsevier Ltd. All rights reserved.

  17. Health effects research and regulation of diesel exhaust: an historical overview focused on lung cancer risk.

    PubMed

    Hesterberg, Thomas W; Long, Christopher M; Bunn, William B; Lapin, Charles A; McClellan, Roger O; Valberg, Peter A

    2012-06-01

    The mutagenicity of organic solvent extracts from diesel exhaust particulate (DEP), first noted more than 55 years ago, initiated an avalanche of diesel exhaust (DE) health effects research that now totals more than 6000 published studies. Despite an extensive body of results, scientific debate continues regarding the nature of the lung cancer risk posed by inhalation of occupational and environmental DE, with much of the debate focused on DEP. Decades of scientific scrutiny and increasingly stringent regulation have resulted in major advances in diesel engine technologies. The changed particulate matter (PM) emissions in "New Technology Diesel Exhaust (NTDE)" from today's modern low-emission, advanced-technology on-road heavy-duty diesel engines now resemble the PM emissions in contemporary gasoline engine exhaust (GEE) and compressed natural gas engine exhaust more than those in the "traditional diesel exhaust" (TDE) characteristic of older diesel engines. Even with the continued publication of epidemiologic analyses of TDE-exposed populations, this database remains characterized by findings of small increased lung cancer risks and inconsistent evidence of exposure-response trends, both within occupational cohorts and across occupational groups considered to have markedly different exposures (e.g. truckers versus railroad shopworkers versus underground miners). The recently published National Institute for Occupational Safety and Health (NIOSH)-National Cancer Institute (NCI) epidemiologic studies of miners provide some of the strongest findings to date regarding a DE-lung cancer association, but some inconsistent exposure-response findings and possible effects of bias and exposure misclassification raise questions regarding their interpretation. Laboratory animal studies are negative for lung tumors in all species, except for rats under lifetime TDE-exposure conditions with durations and concentrations that lead to "lung overload." The species specificity of the

  18. Health effects research and regulation of diesel exhaust: an historical overview focused on lung cancer risk

    PubMed Central

    Hesterberg, Thomas W.; Long, Christopher M.; Bunn, William B.; Lapin, Charles A.; McClellan, Roger O.; Valberg, Peter A.

    2012-01-01

    The mutagenicity of organic solvent extracts from diesel exhaust particulate (DEP), first noted more than 55 years ago, initiated an avalanche of diesel exhaust (DE) health effects research that now totals more than 6000 published studies. Despite an extensive body of results, scientific debate continues regarding the nature of the lung cancer risk posed by inhalation of occupational and environmental DE, with much of the debate focused on DEP. Decades of scientific scrutiny and increasingly stringent regulation have resulted in major advances in diesel engine technologies. The changed particulate matter (PM) emissions in “New Technology Diesel Exhaust (NTDE)” from today's modern low-emission, advanced-technology on-road heavy-duty diesel engines now resemble the PM emissions in contemporary gasoline engine exhaust (GEE) and compressed natural gas engine exhaust more than those in the “traditional diesel exhaust” (TDE) characteristic of older diesel engines. Even with the continued publication of epidemiologic analyses of TDE-exposed populations, this database remains characterized by findings of small increased lung cancer risks and inconsistent evidence of exposure-response trends, both within occupational cohorts and across occupational groups considered to have markedly different exposures (e.g. truckers versus railroad shopworkers versus underground miners). The recently published National Institute for Occupational Safety and Health (NIOSH)-National Cancer Institute (NCI) epidemiologic studies of miners provide some of the strongest findings to date regarding a DE-lung cancer association, but some inconsistent exposure-response findings and possible effects of bias and exposure misclassification raise questions regarding their interpretation. Laboratory animal studies are negative for lung tumors in all species, except for rats under lifetime TDE-exposure conditions with durations and concentrations that lead to'lung overload."The species specificity

  19. Bio-Energy Retains Its Mitigation Potential Under Elevated CO2

    PubMed Central

    Bellassen, Valentin; Njakou Djomo, Sylvestre; Lukac, Martin; Calfapietra, Carlo; Janssens, Ivan A.; Hoosbeek, Marcel R.; Viovy, Nicolas; Churkina, Galina; Scarascia-Mugnozza, Giuseppe; Ceulemans, Reinhart

    2010-01-01

    Background If biofuels are to be a viable substitute for fossil fuels, it is essential that they retain their potential to mitigate climate change under future atmospheric conditions. Elevated atmospheric CO2 concentration [CO2] stimulates plant biomass production; however, the beneficial effects of increased production may be offset by higher energy costs in crop management. Methodology/Main Findings We maintained full size poplar short rotation coppice (SRC) systems under both current ambient and future elevated [CO2] (550 ppm) and estimated their net energy and greenhouse gas balance. We show that a poplar SRC system is energy efficient and produces more energy than required for coppice management. Even more, elevated [CO2] will increase the net energy production and greenhouse gas balance of a SRC system with 18%. Managing the trees in shorter rotation cycles (i.e., 2 year cycles instead of 3 year cycles) will further enhance the benefits from elevated [CO2] on both the net energy and greenhouse gas balance. Conclusions/Significance Adapting coppice management to the future atmospheric [CO2] is necessary to fully benefit from the climate mitigation potential of bio-energy systems. Further, a future increase in potential biomass production due to elevated [CO2] outweighs the increased production costs resulting in a northward extension of the area where SRC is greenhouse gas neutral. Currently, the main part of the European terrestrial carbon sink is found in forest biomass and attributed to harvesting less than the annual growth in wood. Because SRC is intensively managed, with a higher turnover in wood production than conventional forest, northward expansion of SRC is likely to erode the European terrestrial carbon sink. PMID:20657833

  20. Promotion of hydrogen-rich gas and phenolic-rich bio-oil production from green macroalgae Cladophora glomerata via pyrolysis over its bio-char.

    PubMed

    Norouzi, Omid; Jafarian, Sajedeh; Safari, Farid; Tavasoli, Ahmad; Nejati, Behnam

    2016-11-01

    Conversion of Cladophora glomerata (C. glomerata) as a Caspian Sea's green macroalgae into gaseous, liquid and solid products was carried out via pyrolysis at different temperatures to determine its potential for bio-oil and hydrogen-rich gas production for further industrial utilization. Non-catalytic tests were performed to determine the optimum condition for bio-oil production. The highest portion of bio-oil was retrieved at 500°C. The catalytic test was performed using the bio-char derived at 500°C as a catalyst. Effect of the addition of the algal bio-char on the composition of the bio-oil and also gaseous products was investigated. Pyrolysis derived bio-char was characterized by BET, FESEM and ICP method to show its surface area, porosity, and presence of inorganic metals on its surface, respectively. Phenols were increased from 8.5 to 20.76area% by the addition of bio-char. Moreover, the hydrogen concentration and hydrogen selectivity were also enhanced by the factors of 1.37, 1.59 respectively. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Diesel Engine Exhaust: Basis for Occupational Exposure Limit Value.

    PubMed

    Taxell, Piia; Santonen, Tiina

    2017-08-01

    Diesel engines are widely used in transport and power supply, making occupational exposure to diesel exhaust common. Both human and animal studies associate exposure to diesel exhaust with inflammatory lung effects, cardiovascular effects, and an increased risk of lung cancer. The International Agency for Research on Cancer has evaluated diesel exhaust as carcinogenic to humans. Yet national or regional limit values for controlling occupational exposure to diesel exhaust are rare. In recent decades, stricter emission regulations have led to diesel technologies evolving significantly, resulting in changes in exhaust emissions and composition. These changes are also expected to influence the health effects of diesel exhaust. This review provides an overview of the current knowledge on the health effects of diesel exhaust and the influence of new diesel technologies on the health risk. It discusses the relevant exposure indicators and perspectives for setting occupational exposure limit values for diesel exhaust, and outlines directions for future research. The review is based on a collaborative evaluation report by the Nordic Expert Group for Criteria Documentation of Health Risks from Chemicals and the Dutch Expert Committee on Occupational Safety. © The Author 2017. Published by Oxford University Press on behalf of the Society of Toxicology. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  2. Preparation and emission characteristics of ethanol-diesel fuel blends.

    PubMed

    Zhang, Run-Duo; He, Hong; Shi, Xiao-Yan; Zhang, Chang-Bin; He, Bang-Quan; Wang, Jian-Xin

    2004-01-01

    The preparation of ethanol-diesel fuel blends and their emission characteristics were investigated. Results showed the absolute ethanol can dissolve in diesel fuel at an arbitrary ratio and a small quantity of water(0.2%) addition can lead to the phase separation of blends. An organic additive was synthesized and it can develop the ability of resistance to water and maintain the stability of ethanol-diesel-trace amounts of water system. The emission characteristics of 10%, 20%, and 30% ethanol-diesel fuel blends, with or without additives, were compared with those of diesel fuel in a direct injection (DI) diesel engine. The experimental results indicated that the blend of ethanol with diesel fuel significantly reduced the concentrations of smoke, hydrocarbon (HC), and carbon monoxide (CO) in exhaust gas. Using 20% ethanol-diesel fuel blend with the additive of 2% of the total volume, the optimum mixing ratio was achieved, at which the bench diesel engine testing showed a significant decrease in exhaust gas. Bosch smoke number was reduced by 55%, HC emission by 70%, and CO emission by 45%, at 13 kW/1540 r/min. However, ethanol-diesel fuel blends produced a few ppm acetaldehydes and more ethanol in exhaust gas.

  3. Carbonyl compound emissions from a heavy-duty diesel engine fueled with diesel fuel and ethanol-diesel blend.

    PubMed

    Song, Chonglin; Zhao, Zhuang; Lv, Gang; Song, Jinou; Liu, Lidong; Zhao, Ruifen

    2010-05-01

    This paper presents an investigation of the carbonyl emissions from a direct injection heavy-duty diesel engine fueled with pure diesel fuel (DF) and blended fuel containing 15% by volume of ethanol (E/DF). The tests have been conducted under steady-state operating conditions at 1200, 1800, 2600 rpm and idle speed. The experimental results show that acetaldehyde is the most predominant carbonyl, followed by formaldehyde, acrolein, acetone, propionaldehyde and crotonaldehyde, produced from both fuels. The emission factors of total carbonyls vary in the range 13.8-295.9 mg(kWh)(-1) for DF and 17.8-380.2mg(kWh)(-1) for E/DF, respectively. The introduction of ethanol into diesel fuel results in a decrease in acrolein emissions, while the other carbonyls show general increases: at low engine speed (1200 rpm), 0-55% for formaldehyde, 4-44% for acetaldehyde, 38-224% for acetone, and 5-52% for crotonaldehyde; at medium engine speed (1800 rpm), 106-413% for formaldehyde, 4-143% for acetaldehyde, 74-113% for acetone, 114-1216% for propionaldehyde, and 15-163% for crotonaldehyde; at high engine speed (2600 rpm), 36-431% for formaldehyde, 18-61% for acetaldehyde, 22-241% for acetone, and 6-61% for propionaldehyde. A gradual reduction in the brake specific emissions of each carbonyl compound from both fuels is observed with increase in engine load. Among three levels of engine speed employed, both DF and E/DF emit most CBC emissions at high engine speed. On the whole, the presence of ethanol in diesel fuel leads to an increase in aldehyde emissions. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  4. Influence of long-term diesel fuel pollution on nitrite-oxidising activity and population size of nitrobacter spp in soil.

    PubMed

    Deni, Jamal; Penninckx, Michel J

    2004-01-01

    Previous investigations have shown that ammonia oxidation is not inhibited by diesel fuel in a soil with a long history of contamination contrary to a non-contaminated soil. As a consequence, ammonia oxidation does not constitute a Limited step in nitrification process (Appl. Environ. Microbiol. 65 (1999) 4008). Moreover, this type of soil also has had the opportunity to develop an abundant microbial population able to metabolise the diesel hydrocarbons. Whether the properties of soil with a long history of diesel fuel contamination may affect the activity of nitrite-oxidising bacteria was investigated. It was observed that re-exposure of soil to diesel fuel apparently stimulated the proliferation of nitrite-oxidising bacteria, as determined by most probable number (MPN) culture technique and MPN-polymerase chain reaction technique. The potential of nitrite-oxidising activity in soil treated with diesel fuel was about 4 times higher than in the control without addition. In the presence of diesel fuel and ammonium, the potential nitrite-oxidising activity was 40% higher than in presence of ammonium only. However, in the presence of hydrocarbon only, low proliferation of Nitrobacter was observed, probably because the heterotrophic bacteria were strongly limited by lack of nitrogen and did not produce sufficient organic metabolites that could be used by the Nitrobacter cells.

  5. Attempts to minimize nitrogen oxide emission from diesel engine by using antioxidant-treated diesel-biodiesel blend.

    PubMed

    Rashedul, Hasan Khondakar; Kalam, Md Abdul; Masjuki, Haji Hassan; Teoh, Yew Heng; How, Heoy Geok; Monirul, Islam Mohammad; Imdadul, Hassan Kazi

    2017-04-01

    The study represents a comprehensive analysis of engine exhaust emission variation from a compression ignition (CI) diesel engine fueled with diesel-biodiesel blends. Biodiesel used in this investigation was produced through transesterification procedure from Moringa oleifera oil. A single cylinder, four-stroke, water-cooled, naturally aspirated diesel engine was used for this purpose. The pollutants from the exhaust of the engine that are monitored in this study are nitrogen oxide (NO), carbon monoxide (CO), hydrocarbon (HC), and smoke opacity. Engine combustion and performance parameters are also measured together with exhaust emission data. Some researchers have reported that the reason for higher NO emission of biodiesel is higher prompt NO formation. The use of antioxidant-treated biodiesel in a diesel engine is a promising approach because antioxidants reduce the formation of free radicals, which are responsible for the formation of prompt NO during combustion. Two different antioxidant additives namely 2,6-di-tert-butyl-4-methylphenol (BHT) and 2,2'-methylenebis(4-methyl-6-tert-butylphenol) (MBEBP) were individually dissolved at a concentration of 1% by volume in MB30 (30% moringa biodiesel with 70% diesel) fuel blend to investigate and compare NO as well as other emissions. The result shows that both antioxidants reduced NO emission significantly; however, HC, CO, and smoke were found slightly higher compared to pure biodiesel blends, but not more than the baseline fuel diesel. The result also shows that both antioxidants were quite effective in reducing peak heat release rate (HRR) and brake-specific fuel consumption (BSFC) as well as improving brake thermal efficiency (BTE) and oxidation stability. Based on this study, antioxidant-treated M. oleifera biodiesel blend (MB30) can be used as a very promising alternative source of fuel in diesel engine without any modifications.

  6. 46 CFR 169.615 - Diesel fuel systems.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 7 2013-10-01 2013-10-01 false Diesel fuel systems. 169.615 Section 169.615 Shipping... Machinery and Electrical Fuel Systems § 169.615 Diesel fuel systems. (a) Except as provided in paragraph (b) each diesel fuel system must meet the requirements of § 56.50-75 of this chapter. (b) Each vessel of 65...

  7. Combination of biodiesel-ethanol-diesel fuel blend and SCR catalyst assembly to reduce emissions from a heavy-duty diesel engine.

    PubMed

    Shi, Xiaoyan; Yu, Yunbo; He, Hong; Shuai, Shijin; Dong, Hongyi; Li, Rulong

    2008-01-01

    In this study, the efforts to reduce NOx and particulate matter (PM) emissions from a diesel engine using both ethanol-selective catalytic reduction (SCR) of NOx over an Ag/Al2O3 catalyst and a biodiesel-ethanol-diesel fuel blend (BE-diesel) on an engine bench test are discussed. Compared with diesel fuel, use of BE-diesel increased PM emissions by 14% due to the increase in the soluble organic fraction (SOF) of PM, but it greatly reduced the Bosch smoke number by 60%-80% according to the results from 13-mode test of European Stationary Cycle (ESC) test. The SCR catalyst was effective in NOx reduction by ethanol, and the NOx conversion was approximately 73%. Total hydrocarbons (THC) and CO emissions increased significantly during the SCR of NOx process. Two diesel oxidation catalyst (DOC) assemblies were used after Ag/Al2O3 converter to remove CO and HC. Different oxidation catalyst showed opposite effect on PM emission. The PM composition analysis revealed that the net effect of oxidation catalyst on total PM was an integrative effect on SOF reduction and sulfate formation of PM. The engine bench test results indicated that the combination of BE-diesel and a SCR catalyst assembly could provide benefits for NOx and PM emissions control even without using diesel particle filters (DPFs).

  8. Ammonia-nitrogen and Phosphate Reduction by Bio-Filter using Factorial Design

    NASA Astrophysics Data System (ADS)

    Kasmuri, Norhafezah; Ashikin Mat Damin, Nur; Omar, Megawati

    2018-02-01

    Untreated landfill leachate is known to have endangered the environment. As such new treatment must be sought to ensure its cost-effective and sustainable treatment. Thus this paper reports the effectiveness of bio-filter to remove pollutants. In this research, the reduction of nutrients concentration was evaluated in two conditions: using bio-filter and without bio-filter. Synthetic wastewater was used in the batch culture. It was conducted within 21 days in the initial mediums of 100 mg/L ammonia-nitrogen. The nitrification medium consisted of 100 mg/L of ammonia-nitrogen while the nitrite assay had none. The petri dish experiment was also conducted to observe the existence of any colony. The results showed 22% of ammonia- nitrogen reduction and 33% phosphate in the nitrification medium with the bio-filter. The outcome showed that the bio-filter was capable to reduce the concentration of pollutants by retaining the slow growing bacteria (AOB and NOB) on the plastic carrier surface. The factorial design was applied to study the effect of the initial ammonia-nitrogen concentration and duration on nitrite-nitrogen removal. Finally, a regression equation was produced to predict the rate of nitrite-nitrogen removal without conducting extended experiments and to reduce the number of trials experiment.

  9. DNA adducts induced by in vitro activation of extracts of diesel and biodiesel exhaust particles.

    PubMed

    Ross, Jeffrey A; Nelson, Garret B; Mutlu, Esra; Warren, Sarah H; Gilmour, M Ian; DeMarini, David M

    2015-01-01

    Biodiesel and biodiesel-blend fuels offer a renewable alternative to petroleum diesel, but few data are available concerning the carcinogenic potential of biodiesel exhausts. We compared the formation of covalent DNA adducts by the in vitro metabolic activation of organic extracts of diesel-exhaust particles (DEP) from petroleum diesel and soy biodiesel and correlated DNA adduct levels and mutagenicity in Salmonella TA100. We examined two different DEP from petroleum diesel (C-DEP and B0), one from soy bean oil biodiesel (B100) and one from combustion of a blend of 20% B100 and 80% B0 (B20) for in vitro DNA adduct-forming potential under oxidative or nitroreductive conditions in the presence of calf thymus DNA as well as in vivo in Salmonella TA100. The modified DNA was hydrolyzed and analyzed by (32)P-postlabeling using either butanol extraction or nuclease P1 pre-enrichment. Multiple DNA adducts were produced with chromatographic mobilities consistent with PAH and nitro-PAH adducts. The types and quantities of DNA adducts produced by the two independent petroleum diesel DEP were similar, with both polycyclic aromatic hydrocarbon (PAH)- and nitro-PAH-derived adducts formed. Relative potencies for S9-mediated DNA adduct formation, either per mass of particulate or per MJ(th) energy consumed were B100 > B0 > B20. Soy biodiesel emissions induced DNA damage in the form of presumptive PAH and nitro-PAH DNA adducts that correlated with mutagenicity in Salmonella. B20 is the soy biodiesel used most commonly in the US, and it produced the lowest DNA adduct-emission factor, ∼50% that of petroleum diesel.

  10. Careers for the 70's in Diesel Mechanics

    ERIC Educational Resources Information Center

    Osborne, Barbara

    1974-01-01

    Increased employment outlook for diesel mechanics is probably due to the fact that most industries using diesel engines in large numbers are expected to expand their activities. The training and workday of one diesel mechanic is described. (MS)

  11. Poly(3-hydroxybutyrate)-ethyl cellulose based bio-composites with novel characteristics for infection free wound healing application.

    PubMed

    Iqbal, Hafiz M N; Kyazze, Godfrey; Locke, Ian Charles; Tron, Thierry; Keshavarz, Tajalli

    2015-11-01

    A series of bio-composites including poly3-hydroxybutyrate [P(3HB)] grafted ethyl cellulose (EC) stated as P(3HB)-EC were successfully synthesised. Furthermore, natural phenols e.g., p-4-hydroxybenzoic acid (HBA) and ferulic acid (FA) were grafted onto the newly developed P(3HB)-EC-based bio-composites under laccase-assisted environment without the use of additional initiators or crosslinking agents. The phenol grafted bio-composites were critically evaluated for their antibacterial and biocompatibility features as well as their degradability in soil. In particular, the results of the antibacterial evaluation for the newly developed bio-composites indicated that 20HBA-g-P(3HB)-EC and 15FA-g-P(3HB)-EC bio-composites exerted strong bactericidal and bacteriostatic activity against Gram(-)E. coli NTCT 10418 as compared to the Gram(+)B. subtilis NCTC 3610. This study shows further that at various phenolic concentrations the newly synthesised bio-composites remained cytocompatible with human keratinocyte-like HaCaT skin cells, as 100% cell viability was recorded, in vitro. As for the degradation, an increase in the degradation rate was recorded during the soil burial analyses over a period of 42 days. These findings suggest that the reported bio-composites have great potential for use in wound healing; covering the affected skin area which may favour tissue repair over shorter periods. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. On-road emission characteristics of VOCs from diesel trucks in Beijing, China

    NASA Astrophysics Data System (ADS)

    Yao, Zhiliang; Shen, Xianbao; Ye, Yu; Cao, Xinyue; Jiang, Xi; Zhang, Yingzhi; He, Kebin

    2015-02-01

    This paper is the first in our series of papers aimed at understanding the volatile organic compound (VOC) emissions of vehicles in Beijing by conducting on-board emission measurements. This paper focuses on diesel vehicles. In this work, 18 China III diesel vehicles, including seven light-duty diesel trucks (LDDTs), four medium-duty diesel trucks (MDDTs) and seven heavy-duty diesel trucks (HDDTs), were examined when the vehicles were driven on predesigned fixed test routes in Beijing in China using a portable emissions measurement system (PEMS). Tedlar bag sampling and 2,4-dinitrophenyhydrazine (DNPH) cartridge sampling were used to collect VOC species, and gas chromatography-mass spectrometry (GC/MS) and high-performance liquid chromatography (HPLC) were used to analyze these samples. We obtained the VOC emission factors and relative compositions for diesel trucks of different sizes under different driving patterns. In total, 64 VOC species were quantified in this study, including 25 alkanes, four alkenes, 13 aromatics, 13 carbonyls and nine other compounds. The emission factors of the total VOCs based on mileage traveled for HDDTs were higher than those of LDDTs and MDDTs. Carbonyls, aromatics and alkanes were the dominant VOC species. Carbonyls accounted for 42.7%-69.2% of the total VOCs in the three types of tested diesel trucks. The total VOC emission factors of the tested vehicles that were driven on non-highway routes were 1.5-2.0 times higher than those of the vehicles driven on the highway. As for the OFP calculation results, with increased vehicle size, the ozone formation potential presented an increasing trend. Among the VOC components, carbonyls were the primary contributor to OFP. In addition, the OFPs under non-highway driving cycles were 1.3-1.7 times those under highway driving cycles. The results of this study will be helpful in improving our understanding of VOCs emitted from on-road diesel trucks in China.

  13. 30 CFR 75.1916 - Operation of diesel-powered equipment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Operation of diesel-powered equipment. 75.1916... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1916 Operation of diesel-powered equipment. (a) Diesel-powered equipment shall be operated at a speed that is...

  14. 30 CFR 75.1916 - Operation of diesel-powered equipment.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Operation of diesel-powered equipment. 75.1916... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1916 Operation of diesel-powered equipment. (a) Diesel-powered equipment shall be operated at a speed that is...

  15. Carbonyl emissions in diesel and biodiesel exhaust

    NASA Astrophysics Data System (ADS)

    Machado Corrêa, Sérgio; Arbilla, Graciela

    With the use of biodiesel in clear growth, it is important to quantify any potential emission benefits or liabilities of this fuel. Several researches are available concerning the regulated emissions of biodiesel/diesel blends, but there is a lack of information about non-regulated emissions. In a previous paper [Corrêa, S.M., Arbilla, G., 2006. Emissões de formaldeído e acetaldeído de misturas biodiesel/diesel. Periódico Tchê Química, 3, 54-68], the emissions of aromatic hydrocarbons were reported. In this work, seven carbonyl emissions (formaldehyde, acetaldehyde, acrolein, acetone, propionaldehyde, butyraldehyde, and benzaldehyde) were evaluated by a heavy-duty diesel engine fueled with pure diesel (D) and biodiesel blends (v/v) of 2% (B2), 5% (B5), 10% (B10), and 20% (B20). The tests were conducted using a six cylinder heavy-duty engine, typical of the Brazilian fleet of urban buses, in a steady-state condition under 1000, 1500, and 2000 rpm. The exhaust gases were diluted nearly 20 times and the carbonyls were sampled with SiO 2-C18 cartridges, impregnated with acid solution of 2,4-dinitrophenylhydrazine. The chemical analyses were performed by high performance liquid chromatography using UV detection. Using average values for the three modes of operation (1000, 1500, and 2000 rpm) benzaldehyde showed a reduction on the emission (-3.4% for B2, -5.3% for B5, -5.7% for B10, and -6.9% for B20) and all other carbonyls showed a significative increase: 2.6, 7.3, 17.6, and 35.5% for formaldehyde; 1.4, 2.5, 5.4, and 15.8% for acetaldehyde; 2.1, 5.4, 11.1, and 22.0% for acrolein+acetone; 0.8, 2.7, 4.6, and 10.0% for propionaldehyde; 3.3, 7.8, 16.0, and 26.0% for butyraldehyde.

  16. Diesel exhaust exposure among adolescents in Harlem: a community-driven study.

    PubMed

    Northridge, M E; Yankura, J; Kinney, P L; Santella, R M; Shepard, P; Riojas, Y; Aggarwal, M; Strickland, P

    1999-07-01

    This study sought individual-level data on diesel exhaust exposure and lung function among adolescents in Harlem as part of a community-driven research agenda. High school students administered in-person surveys to seventh grade students to ascertain information on demographics, asthma history, and self-reported and maternal smoking. Urine samples were assayed for 1-hydroxypyrene (1-HP), a marker of diesel exhaust exposure, and cotinine, a marker of tobacco smoke exposure. Computer-assisted spirometry was used to measure lung function. Three quarters (76%) of the participating students had detectable levels of 1-HP. Three students (13%) had an FEF25-75 of less than or equal to 80% of their predicted measurements, and 4 students (17%) had results between 80% and 90% of the predicted value, all of which are suggestive of possible lung impairment. These data suggest that most adolescents in Harlem are exposed to detectable levels of diesel exhaust, a known exacerbator and possible cause of chronic lung disorders such as asthma. Community-driven research initiatives are important for empowering communities to make needed changes to improve their environments and health.

  17. Factors and Trends Affecting the Identification of a Reliable Biomarker for Diesel Exhaust Exposure

    PubMed Central

    2014-01-01

    The monitoring of human exposures to diesel exhaust continues to be a vexing problem for specialists seeking information on the potential health effects of this ubiquitous combustion product. Exposure biomarkers have yielded a potential solution to this problem by providing a direct measure of an individual's contact with key components in the exhaust stream. Spurred by the advent of new, highly sensitive, analytical methods capable of detecting substances at very low levels, there have been numerous attempts at identifying a stable and specific biomarker. Despite these new techniques, there is currently no foolproof method for unambiguously separating diesel exhaust exposures from those arising from other combustion sources. Diesel exhaust is a highly complex mixture of solid, liquid, and gaseous components whose exact composition can be affected by many variables, including engine technology, fuel composition, operating conditions, and photochemical aging. These factors together with those related to exposure methodology, epidemiological necessity, and regulatory reform can have a decided impact on the success or failure of future research aimed at identifying a suitable biomarker of exposure. The objective of this review is to examine existing information on exposure biomarkers for diesel exhaust and to identify those factors and trends that have had an impact on the successful identification of metrics for both occupational and community settings. The information will provide interested parties with a template for more thoroughly understanding those factors affecting diesel exhaust emissions and for identifying those substances and research approaches holding the greatest promise for future success. PMID:25170242

  18. Diesel Fundamentals. Teacher Edition (Revised).

    ERIC Educational Resources Information Center

    Clark, Elton; And Others

    This module is one of a series of teaching guides that cover diesel mechanics. The module contains 4 sections and 19 units. Section A--Orientation includes the following units: introduction to diesel mechanics and shop safety; basic shop tools; test equipment and service tools; fasteners; bearings; and seals. Section B--Engine Principles and…

  19. 30 CFR 75.1905-1 - Diesel fuel piping systems.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Diesel fuel piping systems. 75.1905-1 Section... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Diesel-Powered Equipment § 75.1905-1 Diesel fuel piping systems. (a) Diesel fuel piping systems from the surface must be designed and operated...

  20. Kinetic modelling of a diesel-polluted clayey soil bioremediation process.

    PubMed

    Fernández, Engracia Lacasa; Merlo, Elena Moliterni; Mayor, Lourdes Rodríguez; Camacho, José Villaseñor

    2016-07-01

    A mathematical model is proposed to describe a diesel-polluted clayey soil bioremediation process. The reaction system under study was considered a completely mixed closed batch reactor, which initially contacted a soil matrix polluted with diesel hydrocarbons, an aqueous liquid-specific culture medium and a microbial inoculation. The model coupled the mass transfer phenomena and the distribution of hydrocarbons among four phases (solid, S; water, A; non-aqueous liquid, NAPL; and air, V) with Monod kinetics. In the first step, the model simulating abiotic conditions was used to estimate only the mass transfer coefficients. In the second step, the model including both mass transfer and biodegradation phenomena was used to estimate the biological kinetic and stoichiometric parameters. In both situations, the model predictions were validated with experimental data that corresponded to previous research by the same authors. A correct fit between the model predictions and the experimental data was observed because the modelling curves captured the major trends for the diesel distribution in each phase. The model parameters were compared to different previously reported values found in the literature. Pearson correlation coefficients were used to show the reproducibility level of the model. Copyright © 2016. Published by Elsevier B.V.

  1. Effects of triethyl phosphate and nitrate on electrokinetically enhanced biodegradation of diesel in low permeability soils.

    PubMed

    Lee, G T; Ro, H M; Lee, S M

    2007-08-01

    Bench-scale experiments for electrokinetically enhanced bioremediation of diesel in low permeability soils were conducted. An electrokinetic reactor (ER) was filled with kaolin that was artificially contaminated with diesel at a level of 2500 mg kg(-1). A constant voltage gradient of 1.0 V cm(-1) was applied. In phosphorus transport experiments, KH2PO4 was not distributed homogeneously along the ER, and most of the transported phosphorus was converted to water-insoluble aluminum phosphate after 12 days of electrokinetic (EK) operation. However, the advancing P front of triethyl phosphate (TEP) progressed with time and resulted in uniform P distribution. The treatments employed in the electrokinetically enhanced bioremediation of diesel were control (no addition of nitrogen and phosphorus), NP (KNO3+ KH2PO4), NT (KNO3+ TEP), UP (urea+ KH2PO4), and UT (urea+TEP). Analysis of effluent collected during the first 12 days of EK operation showed that diesel was not removed from the kaolin. After nutrient delivery, using the EK operation, the ER was transferred into an incubator for the biodegradation process. After 60 days of biodegradation, the concentrations of diesel in the kaolin for the NP, NT, UP, UT, and control treatments were 1356, 1002, 1658, 1612, and 2003 mg kg(-1), respectively. The ratio of biodegraded diesel concentration to initial concentration (2465 mg kg(-1)) in NP, NT, UP, UT, and control were 45.0%, 59.4%, 32.7%, 34.6%, and 18.7%, respectively. This result showed that TEP, treated along with NO3-, was most effective for the biodegradation of diesel. TEP was delivered more efficiently to the target zones and with less phosphorus loss than KH2PO4. However, this facilitated phosphorus delivery was effective in biodegrading diesel under anaerobic conditions only when electron acceptors, such as NO3-, were present.

  2. Long-term Effects of Nutrient Addition and Phytoremediation on Diesel and Crude Oil Contaminated Soils in subarctic Alaska

    PubMed Central

    Leewis, Mary-Cathrine; Reynolds, Charles M.; Leigh, Mary Beth

    2014-01-01

    Phytoremediation is a potentially inexpensive method of detoxifying contaminated soils using plants and associated soil microorganisms. The remote locations and cold climate of Alaska provide unique challenges associated with phytoremediation such as finding effective plant species that can achieve successful site clean-up despite the extreme environmental conditions and with minimal site management. A long-term assessment of phytoremediation was performed which capitalized on a study established in Fairbanks in 1995. The original study sought to determine how the introduction of plants (Festuca rubra, Lolium multiflorum), nutrients (fertilizer), or their combination would affect degradation of petroleum hydrocarbon (TPH) contaminated soils (crude oil or diesel) over time. Within the year following initial treatments, the plots subjected to both planting and/or fertilization showed greater overall decreases in TPH concentrations in both the diesel and crude oil contaminated soils relative to untreated plots. We re-examined this field site after 15 years with no active site management to assess the long-term effects of phytoremediation on colonization by native and non-native plants, their rhizosphere microbial communities and on petroleum removal from soil. Native and non-native vegetation had extensively colonized the site, with more abundant vegetation found on the diesel contaminated soils than the more nutrient-poor, more coarse, and acidic crude oil contaminated soils. TPH concentrations achieved regulatory clean up levels in all treatment groups, with lower TPH concentrations correlating with higher amounts of woody vegetation (trees & shrubs). In addition, original treatment type has affected vegetation recruitment to each plot with woody vegetation and more native plants in unfertilized plots. Bacterial community structure also varies according to the originally applied treatments. This study suggests that initial treatment with native tree species in

  3. Occupational exposure to diesel and gasoline emissions and lung cancer in Canadian men.

    PubMed

    Villeneuve, Paul J; Parent, Marie-Élise; Sahni, Vanita; Johnson, Kenneth C

    2011-07-01

    The International Agency for Research on Cancer classifies diesel exhaust as a probable human carcinogen; this decision is based largely from lung cancer evidence. Gasoline exhaust is classified as a possible carcinogen. Epidemiological studies are needed that improve upon some of the limitations of previous research with respect to the characterization of exposure, and the control for the potential confounding influence of smoking and other occupational exposures. Our objective was to investigate associations between occupational exposure to diesel and gasoline engine emissions and lung cancer. We used a case-control study design that involved men 40 years of age and older at the time of interview. Analyses are based on 1681 incident cases of lung cancer and 2,053 population controls. A self-reported questionnaire elicited a lifetime occupational history, including general tasks, and information on other potential risk factors. Occupational exposures to diesel and gasoline emissions, crystalline silica, and asbestos were assigned to each job held by study subjects by industrial hygienists who were blind to case-control status. Exposure metrics for diesel and gasoline emissions that were modeled included: ever exposure, cumulative exposure, and concentration of exposure. We found a dose-response relationship between cumulative occupational exposure to diesel engine emissions and lung cancer. This association was more pronounced for the squamous and large cell subtypes with adjusted odds ratios across the three increasing tertiles of cumulative lifetime exposure relative to those with no exposure of 0.99, 1.25, and 1.32 (p=0.04) for squamous cell carcinoma, and 1.06, 1.19, 1.68 (p=0.02) for large cell carcinoma. While the association with cumulative exposure to gasoline was weakly positive, it was not statistically significant. Our findings suggest that exposure to diesel engine emissions increases the risk of lung cancer particularly for squamous and large cell

  4. 40 CFR 69.52 - Non-motor vehicle diesel fuel.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 15 2011-07-01 2011-07-01 false Non-motor vehicle diesel fuel. 69.52... (CONTINUED) SPECIAL EXEMPTIONS FROM REQUIREMENTS OF THE CLEAN AIR ACT Alaska § 69.52 Non-motor vehicle diesel... NRLM diesel fuel. (5) Exempt NRLM diesel fuel and heating oil must be segregated from motor vehicle...

  5. Effect of diesel oxidation catalysts on the diesel particulate filter regeneration process.

    PubMed

    Lizarraga, Leonardo; Souentie, Stamatios; Boreave, Antoinette; George, Christian; D'Anna, Barbara; Vernoux, Philippe

    2011-12-15

    A Diesel Particulate Filter (DPF) regeneration process was investigated during aftertreatment exhaust of a simulated diesel engine under the influence of a Diesel Oxidation Catalyst (DOC). Aerosol mass spectrometry analysis showed that the presence of the DOC decreases the Organic Carbon (OC) fraction adsorbed to soot particles. The activation energy values determined for soot nanoparticles oxidation were 97 ± 5 and 101 ± 8 kJ mol(-1) with and without the DOC, respectively; suggesting that the DOC does not facilitate elementary carbon oxidation. The minimum temperature necessary for DPF regeneration was strongly affected by the presence of the DOC in the aftertreatment. The conversion of NO to NO(2) inside the DOC induced the DPF regeneration process at a lower temperature than O(2) (ΔT = 30 K). Also, it was verified that the OC fraction, which decreases in the presence of the DOC, plays an important role to ignite soot combustion.

  6. Ceramic valve development for heavy-duty low heat rejection diesel engines

    NASA Technical Reports Server (NTRS)

    Weber, K. E.; Micu, C. J.

    1989-01-01

    Monolithic ceramic valves can be successfully operated in a heavy-duty diesel engine, even under extreme low heat rejection operating conditions. This paper describes the development of a silicon nitride valve from the initial design stage to actual engine testing. Supplier involvement, finite element analysis, and preliminary proof of concept demonstration testing played a significant role in this project's success.

  7. Nitroaromatic carcinogens in diesel soot: a review of laboratory findings.

    PubMed Central

    Wei, E T; Shu, H P

    1983-01-01

    The automobile industry plans to increase production of diesel-powered passenger cars because diesel engines provide better fuel economy than conventional gasoline engines. Diesel engines, however, produce more soot, and increased use of diesel cars will result in more discharge of diesel soot into the atmosphere. Recently, a new class of chemicals, called nitroaromatic compounds, have been identified in chemical extracts of diesel soot. Some of these nitroaromatic compounds produce mutations when tested in in vitro bacterial and mammalian cell assays, and cancer when tested in animals. Here, we review the relevance of these new laboratory findings to current deliberations over emission standards for particles from diesel cars. PMID:6192732

  8. Emissions from diesel versus biodiesel fuel used in a CRDI SUV engine: PM mass and chemical composition.

    PubMed

    Gangwar, Jitendra; Gupta, Tarun; Gupta, Sudhir; Agarwal, Avinash K

    2011-07-01

    The diesel tailpipe emissions typically undergo substantial physical and chemical transformations while traveling through the tailpipe, which tend to modify the original characteristics of the diesel exhaust. Most of the health-related attention for diesel exhaust has focused on the carcinogenic potential of inhaled exhaust components, particularly the highly respirable diesel particulate matter (DPM). In the current study, parametric investigations were made using a modern automotive common rail direct injection (CRDI) sports utility vehicle (SUV) diesel engine operated at different loads at constant engine speed (2400 rpm), employing diesel and 20% biodiesel blends (B20) produced from karanja oil. A partial flow dilution tunnel was employed to measure the mass of the primary particulates from diesel and biodiesel blend on a 47-mm quartz substrate. This was followed by chemical analysis of the particulates collected on the substrate for benzene-soluble organic fraction (BSOF) (marker of toxicity). BSOF results showed decrease in its level with increasing engine load for both diesel and biodiesel. In addition, real-time measurements for organic carbon/elemental carbon (OC/EC), and polycyclic aromatic hydrocarbons (PAHs) (marker of toxicity) were carried out on the diluted primary exhaust coming out of the partial flow dilution tunnel. PAH concentrations were found to be the maximum at 20% rated engine load for both the fuels. The collected particulates from diesel and biodiesel-blend exhaust were also analyzed for concentration of trace metals (marker of toxicity), which revealed some interesting results.

  9. The Effect of the Diesel Cetane Number on Exhaust Emissions Characteristics by Various Additives

    NASA Astrophysics Data System (ADS)

    Lim, Yunsung; Seo, Choongyeol; Lee, Jongtae; Kang, Daeil; Kim, Jeong Soo; Kim, Hyung Jun

    This paper described the effect of the diesel cetane number on exhaust emissions characteristics according to various additives. In addition, the emission characteristics of test fuels blended with three additives (GTL, biodiesel and additive for improving CN) were analyzed and the potential for uses of these additives were evaluated in this study. To achieve this purpose, the test diesel vehicle with a two-thousand cubic centimeter displacement was used to analyze the emission characteristics according to the CN. Also, the NEDC (New European Driving Cycle) was applied as the test mode which is widely used as the test method for environmental certification of diesel vehicles. To analyze the characteristics of HAPs, the VOCs and PAHs were analyzed from the BTEX and the particulate matter, respectively. The analysis results revealed that the CO emissions show the largest reduction rate while the NOx+THC emissions are reduced at a low as the CN got higher. In the NEDC mode, the PM emissions in the EUDC mode were found to be at a lower level than those in the UDC mode. As for the VOCs and PAHs characteristics, the VOCs of the CN 58 show the lowest amounts. Also, the PAHs of diesel blended with GTL show the highest level, followed by those of diesel blended with biodiesel and diesel blended with cetane additive.

  10. 30 CFR 57.4561 - Stationary diesel equipment underground.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Stationary diesel equipment underground. 57... Fire Prevention and Control Installation/construction/maintenance § 57.4561 Stationary diesel equipment underground. Stationary diesel equipment underground shall be— (a) Supported on a noncombustible base; and (b...

  11. Diesel exhaust exposures in port workers.

    PubMed

    Debia, Maximilien; Neesham-Grenon, Eve; Mudaheranwa, Oliver C; Ragettli, Martina S

    2016-07-01

    Exposure to diesel engine exhaust has been linked to increased cancer risk and cardiopulmonary diseases. Diesel exhaust is a complex mixture of chemical substances, including a particulate fraction mainly composed of ultrafine particles, resulting from the incomplete combustion of fuel. Diesel trucks are known to be an important source of diesel-related air pollution, and areas with heavy truck traffic are associated with higher air pollution levels and increased public health problems. Several indicators have been proposed as surrogates for estimating exposures to diesel exhaust but very few studies have focused specifically on monitoring the ultrafine fraction through the measurement of particle number concentrations. The aim of this study is to assess occupational exposures of gate controllers at the port of Montreal, Canada, to diesel engine emissions from container trucks by measuring several surrogates through a multimetric approach which includes the assessment of both mass and number concentrations and the use of direct reading devices. A 10-day measurement campaign was carried out at two terminal checkpoints at the port of Montreal. Respirable elemental and organic carbon, PM1, PM2.5, PMresp (PM4), PM10, PMtot (inhalable fraction), particle number concentrations, particle size distributions, and gas concentrations (NO2, NO, CO) were monitored. Gate controllers were exposed to concentrations of contaminants associated with diesel engine exhaust (elemental carbon GM = 1.6 µg/m(3); GSD = 1.6) well below recommended occupational exposure limits. Average daily particle number concentrations ranged from 16,544-67,314 particles/cm³ (GM = 32,710 particles/cm³; GSD = 1.6). Significant Pearson correlation coefficients were found between daily elemental carbon, PM fractions and particle number concentrations, as well as between total carbon, PM fractions and particle number concentrations. Significant correlation coefficients were found between particle number

  12. Biological permeable reactive barriers coupled with electrokinetic soil flushing for the treatment of diesel-polluted clay soil.

    PubMed

    Mena, Esperanza; Ruiz, Clara; Villaseñor, José; Rodrigo, Manuel A; Cañizares, Pablo

    2015-01-01

    Removal of diesel from spiked kaolin has been studied in the laboratory using coupled electrokinetic soil flushing (EKSF) and bioremediation through an innovative biological permeable reactive barriers (Bio-PRBs) positioned between electrode wells. The results show that this technology is efficient in the removal of pollutants and allows the soil to maintain the appropriate conditions for microorganism growth in terms of pH, temperature, and nutrients. At the same time, EKSF was demonstrated to be a very interesting technology for transporting pollutants, microorganisms and nutrients, although results indicate that careful management is necessary to avoid the depletion of nutrients, which are effectively transported by electro-migration. After two weeks of operation, 30% of pollutants are removed and energy consumption is under 70 kWh m(-3). Main fluxes (electroosmosis and evaporation) and changes in the most relevant parameters (nutrients, diesel, microorganisms, surfactants, moisture conductivity and pH) during treatment and in a complete post-study analysis are studied to give a comprehensive description of the most relevant processes occurring in the soil (pollutant transport and biodegradation). Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Impact of Fuel Metal Impurities on the Durability of a Light-Duty Diesel Aftertreatment System

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Williams, A.; Burton, J.; McCormick, R. L.

    2013-04-01

    Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. A set of diesel engine production exhaust systems was aged to 150,000 miles. These exhaust systems included a diesel oxidation catalyst, selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ultralow sulfur diesel containing no measureable metals, B20 (a common biodiesel blend) containing sodium, B20 containing potassium, and B20 containing calcium, which were selected to simulate the maximum allowable levels in B100 according to ASTM D6751. Analysis included Federal Test Proceduremore » emissions testing, bench-flow reactor testing of catalyst cores, electron probe microanalysis (EPMA), and measurement of thermo-mechanical properties of the DPFs. EPMA imaging found that the sodium and potassium penetrated into the washcoat, while calcium remained on the surface. Bench-flow reactor experiments were used to measure the standard nitrogen oxide (NOx) conversion, ammonia storage, and ammonia oxidation for each of the aged SCR catalysts. Vehicle emissions tests were conducted with each of the aged catalyst systems using a chassis dynamometer. The vehicle successfully passed the 0.2 gram/mile NOx emission standard with each of the four aged exhaust systems.« less

  14. Development of Canavalia ensiformis in soil contaminated with diesel oil.

    PubMed

    Balliana, A G; Moura, B B; Inckot, R C; Bona, C

    2017-01-01

    Hydrocarbons are the main components of diesel oil and are toxic for the majority of plants. A few plant species, known as phytoremediators, are tolerant of hydrocarbons and can survive the stressful conditions of soils contaminated with diesel oil. Canavalia ensiformis, a plant species that is well distributed throughout the tropics, possesses advantageous features for a potential resistance to soil contamination, such as fast growth and a deep root system. Thus, the aim of the present study was to evaluate the tolerance of C. ensiformis when it was exposed to soil contaminated with diesel oil. Seedlings were subjected to two treatments: contaminated soil (CS) (95 ml/kg of diesel oil) and non-contaminated soil (NCS) for a period of 30 days; its growth, morphology, anatomy, and physiology were analyzed. Despite the high level of toxicity, some individuals were able to survive in CS. These plants had root apical meristems with high levels of mitosis and were able to issue new roots with more developed aerenchyma tissue. Because the surviving plants presented no marks of cellular damage on the organs formed (root and leaves) during the experiment, the species capacity of growth on CS was confirmed. Although, long-term field experiments, applying different contaminant concentrations, should be considered to infer about the species resistance and use as phytoremediator.

  15. Diesel engine exhaust and lung cancer: an unproven association.

    PubMed Central

    Muscat, J E; Wynder, E L

    1995-01-01

    The risk of lung cancer associated with diesel exhaust has been calculated from 14 case-control or cohort studies. We evaluated the findings from these studies to determine whether there is sufficient evidence to implicate diesel exhaust as a human lung carcinogen. Four studies found increased risks associated with long-term exposure, although two of the four studies were based on the same cohort of railroad workers. Six studies were inconclusive due to missing information on smoking habits, internal inconsistencies, or inadequate characterization of diesel exposure. Four studies found no statistically significant associations. It can be concluded that short-term exposure to diesel engine exhaust (< 20 years) does not have a causative role in human lung cancer. There is statistical but not causal evidence that long-term exposure to diesel exhaust (> 20 years) increases the risk of lung cancer for locomotive engineers, brakemen, and diesel engine mechanics. There is inconsistent evidence on the effects of long-term exposure to diesel exhaust in the trucking industry. There is no evidence for a joint effect of diesel exhaust and cigarette smoking on lung cancer risk. Using common criteria for determining causal associations, the epidemiologic evidence is insufficient to establish diesel engine exhaust as a human lung carcinogen. Images p812-a PMID:7498093

  16. Predictable bacterial composition and hydrocarbon degradation in Arctic soils following diesel and nutrient disturbance

    PubMed Central

    Bell, Terrence H; Yergeau, Etienne; Maynard, Christine; Juck, David; Whyte, Lyle G; Greer, Charles W

    2013-01-01

    Increased exploration and exploitation of resources in the Arctic is leading to a higher risk of petroleum contamination. A number of Arctic microorganisms can use petroleum for growth-supporting carbon and energy, but traditional approaches for stimulating these microorganisms (for example, nutrient addition) have varied in effectiveness between sites. Consistent environmental controls on microbial community response to disturbance from petroleum contaminants and nutrient amendments across Arctic soils have not been identified, nor is it known whether specific taxa are universally associated with efficient bioremediation. In this study, we contaminated 18 Arctic soils with diesel and treated subsamples of each with monoammonium phosphate (MAP), which has successfully stimulated degradation in some contaminated Arctic soils. Bacterial community composition of uncontaminated, diesel-contaminated and diesel+MAP soils was assessed through multiplexed 16S (ribosomal RNA) rRNA gene sequencing on an Ion Torrent Personal Genome Machine, while hydrocarbon degradation was measured by gas chromatography analysis. Diversity of 16S rRNA gene sequences was reduced by diesel, and more so by the combination of diesel and MAP. Actinobacteria dominated uncontaminated soils with <10% organic matter, while Proteobacteria dominated higher-organic matter soils, and this pattern was exaggerated following disturbance. Degradation with and without MAP was predictable by initial bacterial diversity and the abundance of specific assemblages of Betaproteobacteria, respectively. High Betaproteobacteria abundance was positively correlated with high diesel degradation in MAP-treated soils, suggesting this may be an important group to stimulate. The predictability with which bacterial communities respond to these disturbances suggests that costly and time-consuming contaminated site assessments may not be necessary in the future. PMID:23389106

  17. Predictable bacterial composition and hydrocarbon degradation in Arctic soils following diesel and nutrient disturbance.

    PubMed

    Bell, Terrence H; Yergeau, Etienne; Maynard, Christine; Juck, David; Whyte, Lyle G; Greer, Charles W

    2013-06-01

    Increased exploration and exploitation of resources in the Arctic is leading to a higher risk of petroleum contamination. A number of Arctic microorganisms can use petroleum for growth-supporting carbon and energy, but traditional approaches for stimulating these microorganisms (for example, nutrient addition) have varied in effectiveness between sites. Consistent environmental controls on microbial community response to disturbance from petroleum contaminants and nutrient amendments across Arctic soils have not been identified, nor is it known whether specific taxa are universally associated with efficient bioremediation. In this study, we contaminated 18 Arctic soils with diesel and treated subsamples of each with monoammonium phosphate (MAP), which has successfully stimulated degradation in some contaminated Arctic soils. Bacterial community composition of uncontaminated, diesel-contaminated and diesel+MAP soils was assessed through multiplexed 16S (ribosomal RNA) rRNA gene sequencing on an Ion Torrent Personal Genome Machine, while hydrocarbon degradation was measured by gas chromatography analysis. Diversity of 16S rRNA gene sequences was reduced by diesel, and more so by the combination of diesel and MAP. Actinobacteria dominated uncontaminated soils with <10% organic matter, while Proteobacteria dominated higher-organic matter soils, and this pattern was exaggerated following disturbance. Degradation with and without MAP was predictable by initial bacterial diversity and the abundance of specific assemblages of Betaproteobacteria, respectively. High Betaproteobacteria abundance was positively correlated with high diesel degradation in MAP-treated soils, suggesting this may be an important group to stimulate. The predictability with which bacterial communities respond to these disturbances suggests that costly and time-consuming contaminated site assessments may not be necessary in the future.

  18. MSU-Northern Bio-Energy Center of Excellence

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kegel, Greg; Alcorn-Windy Boy, Jessica; Abedin, Md. Joynal

    2014-09-30

    MSU-Northern established the Bio-Energy Center (the Center) into a Regional Research Center of Excellence to address the obstacles concerning biofuels, feedstock, quality, conversion process, economic viability and public awareness. The Center built its laboratories and expertise in order to research and support product development and commercialization for the bio-energy industry in our region. The Center wanted to support the regional agricultural based economy by researching biofuels based on feedstock’s that can be grown in our region in an environmentally responsible manner. We were also interested in any technology that will improve the emissions and fuel economy performance of heavy dutymore » diesel engines. The Center had a three step approach to accomplish these goals: 1. Enhance the Center’s research and testing capabilities 2. Develop advanced biofuels from locally grown agricultural crops. 3. Educate and outreach for public understanding and acceptance of new technology. The Center was very successful in completing the tasks as outlined in the project plan. Key successes include discovering and patenting a new chemical conversion process for converting camelina oil to jet fuel, as well as promise in developing a heterogeneous Grubs catalyst to support the new chemical conversion process. The Center also successfully fragmented and deoxygenated naturally occurring lignin with a Ni-NHC catalyst, showing promise for further exploration of using lignin for fuels and fuel additives. This would create another value-added product for lignin that can be sourced from beetle kill trees or waste products from cellulose ethanol fuel facilities.« less

  19. Diesel Engine Technology Update

    DTIC Science & Technology

    1987-07-01

    AFWAL-TR-87-20 54 83-021-DET DIESEL ENGINE TECHNOLOGY UPDATE Kaupert, Andrew W., Lt. Col. USAFR Air Force Reserves Detroit Detachment 2 Ann Arbor, MI...sponsored adiabatic turbocompound diesel engine . One goal was the use of no water or air cooling for the engine to enable the minimized heat transfer from...sector with severe • impact on the stationary engine segment of the marketplace. The effect of this proposed legislation on Air Force fuel quality is

  20. Synthesis and characterization of zinc adeninate metal-organic frameworks (bioMOF1) as potential anti-inflammatory drug delivery material

    NASA Astrophysics Data System (ADS)

    Usman, Ken Aldren S.; Buenviaje, Salvador C.; Razal, Joselito M.; Conato, Marlon T.; Payawan, Leon M.

    2018-05-01

    Zn8(ad)4(BPDC)6O•2Me2NH2 (bioMOF1), a porous metal-organic framework with zinc-adeninate secondary building units (SBUs), interconnected via biphenyldicarboxylate linkers, shows great potential for drug delivery applications due to its non-toxic and biocompatible components (zinc and adenine). In this study, bioMOF1 crystals synthesized solvothermally at 130°C for 24 hours, were characterized thoroughly and loaded with a known anti-inflammatory drug, nimesulide (NIM). The crystalline nature of the material was confirmed using powder x-ray diffraction crystallography (PXRD) along with morphology assessment using focused-ion beam/field emission scanning electron microscopy (FIB/FESEM). NIM was introduced to the crystals via solvent exchange accompanied with vigorous stirring and quantified using thermogravimetric analysis (TGA) with loading saturation of ˜30% attained during the 2nd to 3rd day of drug immersion. Drug release in phosphate buffer saline and in deionized water was done to monitor the kinetic of drug release in vitro. The drug release showed a controlled discharge profile which slowed down at the 24th and 48th hour of release. Drug release in buffer showed a faster release of drug from the material, which means that the presence of cations in the solution could further trigger the release of drug. Slow drug release was observed for all of the set-ups with maximum % drug release of 24.47%, and 16.14% for the bioMOF1 in buffer and bioMOF1 in water respectively for the span of 48 hours.

  1. Further theoretical studies of modified cyclone separator as a diesel soot particulate emission arrester.

    PubMed

    Mukhopadhyay, N; Bose, P K

    2009-10-01

    Soot particulate emission reduction from diesel engine is one of the most emerging problems associated with the exhaust pollution. Diesel particulate filters (DPF) hold out the prospects of substantially reducing regulated particulate emissions but the question of the reliable regeneration of filters still remains a difficult hurdle to overcome. Many of the solutions proposed to date suffer from design complexity, cost, regeneration problem and energy demands. This study presents a computer aided theoretical analysis for controlling diesel soot particulate emission by cyclone separator--a non contact type particulate removal system considering outer vortex flow, inner vortex flow and packed ceramic fiber filter at the end of vortex finder tube. Cyclone separator with low initial cost, simple construction produces low back pressure and reasonably high collection efficiencies with reduced regeneration problems. Cyclone separator is modified by placing a continuous ceramic packed fiber filter placed at the end of the vortex finder tube. In this work, the grade efficiency model of diesel soot particulate emission is proposed considering outer vortex, inner vortex and the continuous ceramic packed fiber filter. Pressure drop model is also proposed considering the effect of the ceramic fiber filter. Proposed model gives reasonably good collection efficiency with permissible pressure drop limit of diesel engine operation. Theoretical approach is predicted for calculating the cut size diameter considering the effect of Cunningham molecular slip correction factor. The result shows good agreements with existing cyclone and DPF flow characteristics.

  2. Integrated low noise low power interface for neural bio-potentials recording and conditioning

    NASA Astrophysics Data System (ADS)

    Bottino, Emanuele; Martinoia, Sergio; Valle, Maurizio

    2005-06-01

    The recent progress in both neurobiology and microelectronics suggests the creation of new, powerful tools to investigate the basic mechanisms of brain functionality. In particular, a lot of efforts are spent by scientific community to define new frameworks devoted to the analysis of in-vitro cultured neurons. One possible approach is recording their spiking activity to monitor the coordinated cellular behaviour and get insights about neural plasticity. Due to the nature of neurons action-potentials, when considering the design of an integrated microelectronic-based recording system, a number of problems arise. First, one would desire to have a high number of recording sites (i.e. several hundreds): this poses constraints on silicon area and power consumption. In this regard, our aim is to integrate-through on-chip post-processing techniques-hundreds of bio-compatible microsensors together with CMOS standard-process low-power (i.e. some tenths of uW per channel) conditioning electronics. Each recording channel is provided with sampling electronics to insure synchronous recording so that, for example, cross-correlation between signals coming from different sites can be performed. Extra-cellular potentials are in the range of [50-150] uV, so a comparison in terms of noise-efficiency was carried out among different architectures and very low-noise pre-amplification electronics (i.e. less than 5 uVrms) was designed. As spikes measurements are made with respect to the voltage of a reference electrode, we opted for an AC-coupled differential-input preamplifier provided with band-pass filtering capability. To achieve this, we implemented large time-constant (up to seconds) integrated components in the preamp feedback path. Thus, we got rid also of random slow-drifting DC-offsets and common mode signals. The paper will present our achievements in the design and implementation of a fully integrated bio-abio interface to record neural spiking activity. In particular

  3. 7 CFR 1945.19 - Reporting potential natural disasters and initial actions.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 13 2012-01-01 2012-01-01 false Reporting potential natural disasters and initial... Assistance-General § 1945.19 Reporting potential natural disasters and initial actions. (a) Purpose. The purpose of reporting potential natural disasters is to provide a systematic procedure for rapid reporting...

  4. 7 CFR 1945.19 - Reporting potential natural disasters and initial actions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 13 2011-01-01 2009-01-01 true Reporting potential natural disasters and initial... Assistance-General § 1945.19 Reporting potential natural disasters and initial actions. (a) Purpose. The purpose of reporting potential natural disasters is to provide a systematic procedure for rapid reporting...

  5. 7 CFR 1945.19 - Reporting potential natural disasters and initial actions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 13 2010-01-01 2009-01-01 true Reporting potential natural disasters and initial... Assistance-General § 1945.19 Reporting potential natural disasters and initial actions. (a) Purpose. The purpose of reporting potential natural disasters is to provide a systematic procedure for rapid reporting...

  6. Moisture variation associated with water input and evaporation during sewage sludge bio-drying.

    PubMed

    Cai, Lu; Gao, Ding; Chen, Tong-Bin; Liu, Hong-Tao; Zheng, Guo-Di; Yang, Qi-Wei

    2012-08-01

    The variation of moisture during sewage sludge bio-drying was investigated. In situ measurements were conducted to monitor the bulk moisture and water vapor, while the moisture content, water generation, water evaporation and aeration water input of the bio-drying bulk were calculated based on the water mass balance. The moisture in the sewage sludge bio-drying material decreased from 66% to 54% in response to control technology for bio-drying. During the temperature increasing and thermophilic phases of sewage sludge bio-drying, the moisture content, water generation and water evaporation of the bulk initially increased and then decreased. The peak water generation and evaporation occurred during the thermophilic phase. During the bio-drying, water evaporation was much greater than water generation, and aeration facilitated the water evaporation. Copyright © 2012. Published by Elsevier Ltd.

  7. 30 CFR 250.510 - Diesel engine air intakes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 2 2011-07-01 2011-07-01 false Diesel engine air intakes. 250.510 Section 250.510 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, REGULATION, AND ENFORCEMENT, DEPARTMENT OF... Well-Completion Operations § 250.510 Diesel engine air intakes. Diesel engine air intakes must be...

  8. Development of vaccines for bio-warfare agents.

    PubMed

    Rosenthal, S R; Clifford, J C M

    2002-01-01

    There is a recognized need for the development of new vaccines (as well as other biologicals and drugs) to counteract the effects of a potential bio-terrorist or bio-warfare event in the U.S. domestic population and military forces. Regulation of products to protect against potential bio-warfare agents poses unique challenges since the usual measures of efficacy that require exposure to natural disease may not currently be possible, for epidemiological and ethical reasons. To help to address this issue, the FDA has published and requested comments on a proposed animal rule intended to address certain efficacy issues for new agents for use against lethal or permanently disabling toxic substances. Recent product development activity has focused on Bacillus anthracis (anthrax) and variola major (smallpox), agents that are regarded as highest priority in posing a risk to national security. FDA resources exist to assist vaccine developers with regard to the novel challenges posed in the dinical development of these products.

  9. Potential Theranostics Application of Bio-Synthesized Silver Nanoparticles (4-in-1 System)

    PubMed Central

    Mukherjee, Sudip; Chowdhury, Debabrata; Kotcherlakota, Rajesh; Patra, Sujata; B, Vinothkumar; Bhadra, Manika Pal; Sreedhar, Bojja; Patra, Chitta Ranjan

    2014-01-01

    In this report, we have designed a simple and efficient green chemistry approach for the synthesis of colloidal silver nanoparticles (b-AgNPs) that is formed by the reduction of silver nitrate (AgNO3) solution using Olax scandens leaf extract. The colloidal b-AgNPs, characterized by various physico-chemical techniques exhibit multifunctional biological activities (4-in-1 system). Firstly, bio-synthesized silver nanoparticles (b-AgNPs) shows enhanced antibacterial activity compared to chemically synthesize silver nanoparticles (c-AgNPs). Secondly, b-AgNPs show anti-cancer activities to different cancer cells (A549: human lung cancer cell lines, B16: mouse melanoma cell line & MCF7: human breast cancer cells) (anti-cancer). Thirdly, these nanoparticles are biocompatible to rat cardiomyoblast normal cell line (H9C2), human umbilical vein endothelial cells (HUVEC) and Chinese hamster ovary cells (CHO) which indicates the future application of b-AgNPs as drug delivery vehicle. Finally, the bio-synthesized AgNPs show bright red fluorescence inside the cells that could be utilized to detect the localization of drug molecules inside the cancer cells (a diagnostic approach). All results together demonstrate the multifunctional biological activities of bio-synthesized AgNPs (4-in-1 system) that could be applied as (i) anti-bacterial & (ii) anti-cancer agent, (iii) drug delivery vehicle, and (iv) imaging facilitator. To the best of our knowledge, there is not a single report of biosynthesized AgNPs that demonstrates the versatile applications (4-in-1 system) towards various biomedical applications. Additionally, a plausible mechanistic approach has been explored for the synthesis of b-AgNPs and its anti-bacterial as well as anti-cancer activity. We strongly believe that bio-synthesized AgNPs will open a new direction towards various biomedical applications in near future. PMID:24505239

  10. Cosmic meteor dust: potentially the dominant source of bio-available iron in the Southern Ocean

    NASA Astrophysics Data System (ADS)

    Dyrud, L. P.; Marsh, D. R.; Del Castillo, C. E.; Fentzke, J.; Lopez-Rosado, R.; Behrenfeld, M.

    2012-12-01

    Johnson, 2001 [Johnson, Kenneth. S. (2001), Iron supply and demand in the upper ocean: Is extraterrestrial dust a significant source of bioavailable iron?, Global Biogeochem. Cycles, 15(1), 61-63, doi:10.1029/2000GB001295], first suggested that meteoric particulate flux could be a significant source of bio-available iron, particularly in regions with little or no eolean sources, such as the Southern Ocean. While these calculations raised intriguing questions, there were many large unknowns in the input calculations between meteor flux and bio-available ocean molecular densities. There has been significant research in the intervening decade on related topics, such as the magnitude (~200 ktons per year) and composition of the meteoric flux, its atmospheric evaporation, transport, mesospheric formation of potentially soluble meteoric smoke, and extraterrestrial iron isotope identification. Paramount of these findings are recent NCAR WACCM atmosphere model results demonstrating that the majority of meteoric constituents are transported towards the winter poles and the polar vortex. This may lead to a focusing of meteoritic iron deposition towards the Southern Ocean. We present a proposed research plan involving Southern Ocean sample collection and analysis and atmospheric and biological modeling to determine both the current relevance of meteoric iron, and examine the past and future consequences of cosmic dust under a changing climate.

  11. Greener, meaner diesels sport thermal barrier coatings

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Winkler, M.F.; Parker, D.W.

    1992-05-01

    The highly reliable diesel engine has long been the workhorse of the transportation, industrial power, utility, and marine industries. Demand for diesels is expected to accelerate well into the next century, driven by the engine's ability to economically produce power in almost any environment. Increasingly stringent environmental, efficiency, and durability requirements, however, present new challenges to diesel engine manufacturers and operators. This paper reports that many of these challenges can be met entirely, or in part, by thermal barrier coatings (TBCs). Diesel engine TBCs are plasma-spray-applied ceramics, which insulate combustion system components, such as pistons, valves, and piston fire decks,more » from heat and thermal shock.« less

  12. On-road, in-use gaseous emission measurements by remote sensing of school buses equipped with diesel oxidation catalysts and diesel particulate filters.

    PubMed

    Burgard, Daniel A; Provinsal, Melissa N

    2009-12-01

    A remote sensing device was used to obtain on-road and in-use gaseous emission measurements from three fleets of schools buses at two locations in Washington State. This paper reports each fleet's carbon monoxide (CO), hydrocarbon (HC), nitric oxide (NO), and nitrogen dioxide (NO2) mean data. The fleets represent current emission retrofit technologies, such as diesel particulate filters and diesel oxidation catalysts, and a control fleet. This study shows that CO and HC emissions decrease with the use of either retrofit technology when compared with control buses of the same initial emission standards. The CO and HC emission reductions are consistent with published U.S. Environmental Protection Agency verified values. The total oxides of nitrogen (NOx), NO, and the NO2/NOx ratio all increase with each retrofit technology when compared with control buses. As was expected, the diesel particulate filters emitted significantly higher levels of NO2 than the control fleet because of the intentional conversion of NO to NO2 by these systems. Most prior research suggests that NOx emissions are unaffected by the retrofits; however, these previous studies have not included measurements from retrofit devices on-road and after nearly 5 yr of use. Two 2006 model-year buses were also measured. These vehicles did not have retrofit devices but were built to more stringent new engine standards. Reductions in HCs and NOx were observed for these 2006 vehicles in comparison to other non-retrofit earlier model-year vehicles.

  13. 40 CFR 69.51 - Motor vehicle diesel fuel.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 16 2013-07-01 2013-07-01 false Motor vehicle diesel fuel. 69.51... (CONTINUED) SPECIAL EXEMPTIONS FROM REQUIREMENTS OF THE CLEAN AIR ACT Alaska § 69.51 Motor vehicle diesel... motor vehicle diesel fuel standards and dye provisions under 40 CFR 80.520 and associated requirements...

  14. 40 CFR 69.51 - Motor vehicle diesel fuel.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 16 2012-07-01 2012-07-01 false Motor vehicle diesel fuel. 69.51... (CONTINUED) SPECIAL EXEMPTIONS FROM REQUIREMENTS OF THE CLEAN AIR ACT Alaska § 69.51 Motor vehicle diesel... motor vehicle diesel fuel standards and dye provisions under 40 CFR 80.520 and associated requirements...

  15. 30 CFR 250.610 - Diesel engine air intakes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 2 2013-07-01 2013-07-01 false Diesel engine air intakes. 250.610 Section 250.610 Mineral Resources BUREAU OF SAFETY AND ENVIRONMENTAL ENFORCEMENT, DEPARTMENT OF THE INTERIOR... Operations § 250.610 Diesel engine air intakes. No later than May 31, 1989, diesel engine air intakes shall...

  16. 30 CFR 250.510 - Diesel engine air intakes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 2 2013-07-01 2013-07-01 false Diesel engine air intakes. 250.510 Section 250.510 Mineral Resources BUREAU OF SAFETY AND ENVIRONMENTAL ENFORCEMENT, DEPARTMENT OF THE INTERIOR... Operations § 250.510 Diesel engine air intakes. Diesel engine air intakes must be equipped with a device to...

  17. 30 CFR 250.510 - Diesel engine air intakes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 2 2012-07-01 2012-07-01 false Diesel engine air intakes. 250.510 Section 250.510 Mineral Resources BUREAU OF SAFETY AND ENVIRONMENTAL ENFORCEMENT, DEPARTMENT OF THE INTERIOR... Operations § 250.510 Diesel engine air intakes. Diesel engine air intakes must be equipped with a device to...

  18. 30 CFR 250.510 - Diesel engine air intakes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 2 2014-07-01 2014-07-01 false Diesel engine air intakes. 250.510 Section 250.510 Mineral Resources BUREAU OF SAFETY AND ENVIRONMENTAL ENFORCEMENT, DEPARTMENT OF THE INTERIOR... Operations § 250.510 Diesel engine air intakes. Diesel engine air intakes must be equipped with a device to...

  19. Enhanced biodegradation of diesel oil by a newly identified Rhodococcus baikonurensis EN3 in the presence of mycolic acid.

    PubMed

    Lee, M; Kim, M K; Singleton, I; Goodfellow, M; Lee, S-T

    2006-02-01

    The aim of the present study was to isolate and characterize a bacterium, strain EN3, capable of using diesel oil as a major carbon and energy source, and to analyse the enhancement of diesel oil degradation by this organism using synthetic mycolic acid (2-hexyl-3-hydroxyldecanoic acid). An actinomycete with the ability to degrade diesel oil was isolated from oil contaminated soil and characterized. The strain had phenotypic properties consistent with its classification in the genus Rhodococcus showing a 16S rRNA gene similarity of 99.7% with Rhodococcus baikonurensis DSM 44587(T). The ability of the characterized strain to degrade diesel oil at various concentrations (1000, 5000, 10 000 and 20 000 mg l(-1)) was determined. The effect of synthetic mycolic acid on the biodegradation of diesel oil was investigated at the 20 000 mg l(-1) concentration; the surfactant was added to the flask cultures at three different concentrations (10, 50 and 100 mg l(-1)) and degradation followed over 7 days. Enhanced degradation was found at all three concentrations of the surfactant. In addition, the enhancement of diesel oil degradation by other surfactants was observed. The synthetic mycolic acid has potential for the remediation of petroleum-contaminated sites from both an economic and applied perspective as it can stimulate biodegradation at low concentrations. This study showed that the synthesized mycolic acid can be used for potential applications in the bioremediation industries, for example, in oil spill clean-up, diesel fuel remediation and biostimulation.

  20. Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of organic carbon emissions

    PubMed Central

    Gentner, Drew R.; Isaacman, Gabriel; Worton, David R.; Chan, Arthur W. H.; Dallmann, Timothy R.; Davis, Laura; Liu, Shang; Day, Douglas A.; Russell, Lynn M.; Wilson, Kevin R.; Weber, Robin; Guha, Abhinav; Harley, Robert A.; Goldstein, Allen H.

    2012-01-01

    Emissions from gasoline and diesel vehicles are predominant anthropogenic sources of reactive gas-phase organic carbon and key precursors to secondary organic aerosol (SOA) in urban areas. Their relative importance for aerosol formation is a controversial issue with implications for air quality control policy and public health. We characterize the chemical composition, mass distribution, and organic aerosol formation potential of emissions from gasoline and diesel vehicles, and find diesel exhaust is seven times more efficient at forming aerosol than gasoline exhaust. However, both sources are important for air quality; depending on a region’s fuel use, diesel is responsible for 65% to 90% of vehicular-derived SOA, with substantial contributions from aromatic and aliphatic hydrocarbons. Including these insights on source characterization and SOA formation will improve regional pollution control policies, fuel regulations, and methodologies for future measurement, laboratory, and modeling studies. PMID:23091031