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Sample records for blast furnace stove

  1. Blast furnace stove control

    SciTech Connect

    Muske, K.R.; Hansen, G.A.; Howse, J.W.; Cagliostro, D.J.; Chaubal, P.C.

    1998-12-31

    This paper outlines the process model and model-based control techniques implemented on the hot blast stoves for the No. 7 Blast Furnace at the Inland Steel facility in East Chicago, Indiana. A detailed heat transfer model of the stoves is developed. It is then used as part of a predictive control scheme to determine the minimum amount of fuel necessary to achieve the blast air requirements. The controller also considers maximum and minimum temperature constraints within the stove.

  2. 47. No. 4 hot blast stove, furnace "A", showing checkerwork ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    47. No. 4 hot blast stove, furnace "A", showing checkerwork askew after collapse of support posts. Note pattern of checkerwork refractories. looking west - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  3. 11. Photocopied June 1978. HOT BLAST STOVE ON 'NEW' FURNACE. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. Photocopied June 1978. HOT BLAST STOVE ON 'NEW' FURNACE. NOTE DOWNCOMER ON LEFT AND DAMPERS ON CHIMNEYS. CA. 1906. SOURCE: MACINTYRE DEVELOPMENT, NL INDUSTRIES, TAHAWUS, N.Y. - Adirondack Iron & Steel Company, New Furnace, Hudson River, Tahawus, Essex County, NY

  4. GENERAL VIEW OF TURBOBLOWER BUILDING (LEFT), BLAST FURNACE (CENTER), AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    GENERAL VIEW OF TURBO-BLOWER BUILDING (LEFT), BLAST FURNACE (CENTER), AND HOT BLAST STOVES (RIGHT). - Republic Iron & Steel Company, Youngstown Works, Haselton Blast Furnaces, West of Center Street Viaduct, along Mahoning River, Youngstown, Mahoning County, OH

  5. Hot blast stove process model and model-based controller

    SciTech Connect

    Muske, K.R.; Howse, J.W.; Hansen, G.A.; Cagliostro, D.J.; Chaubal, P.C.

    1998-12-31

    This paper describes the process model and model-based control techniques implemented on the hot blast stoves for the No. 7 Blast Furnace at the Inland Steel facility in East Chicago, Indiana. A detailed heat transfer model of the stoves is developed and verified using plant data. This model is used as part of a predictive control scheme to determine the minimum amount of fuel necessary to achieve the blast air requirements. The model is also used to predict maximum and minimum temperature constraint violations within the stove so that the controller can take corrective actions while still achieving the required stove performance.

  6. 116. View looking southeast at stoves 2124 showing hot blast ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    116. View looking southeast at stoves 21-24 showing hot blast main to No. 2 Furnace leading off to the right and gas main running in front of stoves. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  7. 3. DETAIL, 3/4 VIEW OF HOT BLAST STOVE ON TOP ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. DETAIL, 3/4 VIEW OF HOT BLAST STOVE ON TOP OF FURNACE SHOWING CAST-IRON RETORTS AND TURNED HEAD (WHERE RAW MATERIALS WERE LOADED INTO FURNACE). - Nassawango Iron Furnace, Furnace Road, 1.2 miles west of Maryland Route 12, Snow Hill, Worcester County, MD

  8. VIEW FROM THE SOUTH OF THE #2 BLAST FURNACE AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW FROM THE SOUTH OF THE #2 BLAST FURNACE AND CASTING SEED ON THE LEFT, THE #1 BLAST FURNACE AND CASTING SHED ON THE RIGHT, AND THE STOVES, BOILERS, AND AUXILIARY EQUIPMENT IN THE CENTER. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  9. General view of blast furnace plant, with blast furnace "A" ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    General view of blast furnace plant, with blast furnace "A" (built in 1907) to the left; in the foreground is the turbo-blower and blast furnace gas-powered electric generating station (built in 1919), looking northwest - Bethlehem Steel Corporation, South Bethlehem Works, Blast Furnace "A", Along Lehigh River, North of Fourth Street, West of Minsi Trail Bridge, Bethlehem, Northampton County, PA

  10. GENERAL VIEW FROM THE SOUTHWEST, SHOWING THE #2 BLAST FURNACE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    GENERAL VIEW FROM THE SOUTHWEST, SHOWING THE #2 BLAST FURNACE IN THE RIGHT; THE CENTRAL COMPLEX WITH STOVES IN THE CENTER. ELECTRICAL POWER HOUSE IS ON THE LEFT BEYOND THE CONVEYOR LIFT. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  11. EXTERIOR VIEW, BLAST FURNACE NO. 3 (JANE FURNACE) CENTER, NO. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    EXTERIOR VIEW, BLAST FURNACE NO. 3 (JANE FURNACE) CENTER, NO. 3 CAST HOUSE TO THE LEFT, WEST ORE BRIDGE TO THE RIGHT. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 3, Donner Avenue, Monessen, Westmoreland County, PA

  12. Rebuilding and modernization of blast furnace B'' at Cockerill-Sambre Ougree

    SciTech Connect

    Neuville, J.; Lecomte, P.; Massin, J.P.; Drimmer, D. )

    1993-01-01

    Blown in for the first time in 1962, the B blast furnace of Cockerill-Sambre was relined for the fourth time in 1989. The furnace produced 8,649,000 tons during the last campaign (1980 - 1989). Gunning repairs were carried out in 1985 and 1987. The blast furnace was blow down on June 30 and the burden level was lowered to the tuyere level. Afterwards a salamander of 350 tons was cast in open ladles. The relining of the blast furnace was performed on schedule and the furnace was blown in on the 4th of December 1989. The paper describes the relining goals and the main modifications. The specifications of the blast furnace are listed. Then the paper describes the modifications to the following systems: the charging computer system; the cooling system; the refractory materials; the hot stoves; blast furnace gas system; instrumentation and regulation; the blast furnace computer system; the pollution control equipment; and the cast floor.

  13. Inland Steel's No. 7 blast furnace third reline

    SciTech Connect

    Lowrance, K.F. II ); Johansson, J.; Carter, W.L. )

    1994-09-01

    The background information, investigation and benchmarking that led to a decision by Inland Steel to partially reline No. 7 blast furnace is covered. This approach reduced actual downtime on the furnace and extended the current campaign. This alternative allowed for the rebalancing of the physical plant of No. 7 blast furnace. Areas of scope covered are hearth, stack, stoves, gas cleaning and furnace top. Included are highlights of the execution of the project including schedules, blowdown, salamander tap, quench, dig out/descale, scaffolding used and brick installation. A summary of the actual results of the work is presented along with information on production planned, blow-in and the first 20 days of production.

  14. Reline and modernization of AHMSA No. 5 blast furnace

    SciTech Connect

    Garcia, J.C.; Gamez, O.; Bean, R.M.

    1995-07-01

    No. 5 blast furnace (11.2 meter hearth dia and 2,210 cu meter working volume) was commissioned in 1976, relined in 1985 and then modernized with state of the art technology in 1994. The modernization project objective was for a campaign life of 10 years and 19 million tons of hot metal, and included: integrated furnace lining and intensified cooling design, including new bosh cooling tower system; complete shell replacement from the top of the hearth jacket up to mid-stack, including major furnace walkway replacement; replacement of internal ceramic stove burners, including a portion of checkers; gas cleaning system upgrade; and new process control and instrumentation systems--distributed control system (DCS), PLC-based stove changing system, level 2 (VAX) computer system and new field instrumentation. The paper will concentrate on the installation of the furnace lining and cooling system including shell replacement, internal ceramic burner rebuild combined with checker replacement, and the new furnace and stove control systems upgrade. Problems encountered during the design, manufacturing and installation stages, and subsequent solutions will be discussed. Operating data before and after the rebuild will be compared.

  15. Optimization of the Number of Burner Nozzles in a Hot Blast Stove by the Way of Simulation

    NASA Astrophysics Data System (ADS)

    Guo, Hongwei; Yan, Bingji; Zhang, Jianliang; Liu, Feng; Pei, Yi

    2014-07-01

    The structure of the burner nozzles in a blast furnace hot stove including their number, location, and angle has a vital effect on the flow field, temperature distribution, combustion efficiency, etc. In this article, simulation models were established for the hot stove located at Shougang Qianan. The model, eddy dissipation model, and P-1 model were used for the modeling of turbulence, combustion, and radiative heat transfer, respectively. The effect of different number of burner nozzles on the flow field and temperature distribution in the combustion chamber was investigated. The results indicated that 19 or 21 burner nozzles were preferred to obtain the optimum flow field and temperature distribution.

  16. Partial reline of Inland`s No. 7 blast furnace

    SciTech Connect

    Lowrance, K.F. II; Johansson, J.; Carter, W.L.

    1995-10-01

    The background for the decision to partially reline No. 7 blast furnace that would achieve the same results as a complete reline is discussed. This approach was designed to reduce actual downtime on the furnace at a critical production period. Areas of work included the hearth, stack, stoves, gas cleaning and furnace top. Highlights of the project execution were: schedules; blowdown; salamander tap; quench; dig out/descale; scaffolding used; and brick installation. The furnace was blown-in 29 days after the blowdown and producing in excess of 9,000 tons/day after 12 days of operation. Inland has adopted a new definition for establishing campaign life based on refractory wear that includes a hearth monitoring system.

  17. INTERIOR VIEW LOOKING WEST, CAST HOUSE OF BLAST FURNACE NO. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW LOOKING WEST, CAST HOUSE OF BLAST FURNACE NO. 1 AND BLAST FURNACE NO. 2. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 1 & No. 2, Donner Avenue, Monessen, Westmoreland County, PA

  18. Looking southwest at blast furnaces no. 5 and no. 6 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking southwest at blast furnaces no. 5 and no. 6 with blast furnace trestle and Gondola Railroad cars in foreground. - U.S. Steel Edgar Thomson Works, Blast Furnace Plant, Along Monongahela River, Braddock, Allegheny County, PA

  19. Looking southeast at blast furnaces no. 5 and no. 6 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking southeast at blast furnaces no. 5 and no. 6 with blast furnace trestle and Gondola Railroad cars in foreground. - U.S. Steel Edgar Thomson Works, Blast Furnace Plant, Along Monongahela River, Braddock, Allegheny County, PA

  20. Existing and prospective blast-furnace conditions

    SciTech Connect

    I.G. Tovarovskii; V.I. Bol'shakov; V.P. Lyalyuk; A.E. Merkulov; D. V. Pinchuk

    2009-07-15

    Blast-furnace conditions are investigated by means of a multizone model. The expected performance of prospective technologies is assessed, as well as the trends in blast-furnace processes. The model permits the identification of means of overcoming practical difficulties.

  1. Energy aspects of a lead blast furnace

    NASA Astrophysics Data System (ADS)

    Cowperthwaite, Janice E.; Dugdale, Peter J.; Landry, Christian J. F.; R. Morris, David; Steward, Frank R.; Wilson, Timothy C. W.

    1980-06-01

    The energy effects accompanying the processing of the feed material to a lead blast furnace are considered in terms of a reversible model. Relative to this model the efficiencies of operating furnaces are found to be in the range 18 to 35 pct. The effects of the effluent gas CO2/CO ratio and temperature and oxygen enrichment of the blast air in the thermodynamic efficiency are quantified. Improvements in efficiency achieved in industrial furnaces as a result of oxygen enrichment of the blast air are substantially greater than those predicted. Mass and enthalpy balances on an industrial lead blast furnace are presented from which it is estimated that approximately 9 pct of the carbon charged to the furnace is lost due to the solution loss reaction in the upper regions of the furnace.

  2. 3. VIEW OF DUQUESNE'S RAIL LINES AND BLAST FURNACE PLANT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. VIEW OF DUQUESNE'S RAIL LINES AND BLAST FURNACE PLANT LOOKING NORTH. DOROTHY SIX IS THE CLOSEST FURNACE IN THE PHOTOGRAPH. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  3. 56. LOOKING NORTH AT DOROTHY SIX BLAST FURNACE WITH CAST ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    56. LOOKING NORTH AT DOROTHY SIX BLAST FURNACE WITH CAST HOUSE IN FOREGROUND AND DUSTCATCHER AT RIGHT OF FURNACE (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  4. Blast furnace repairs, relines and modernizations

    SciTech Connect

    Carpenter, J.A.; Swanson, D.E; Chango, R.F. . Burns Harbor Div.)

    1994-09-01

    Bethlehem Steel's Burns Harbor Div. operates two 89,000-cu ft blast furnaces, D and C, built in 1969 and 1972. These furnaces have been in the forefront of blast furnace performance since they were blown-in. To maintain a credible operation throughout the past 25 years their performance has been improved continuously. Production was increased approximately 3%/year while fuel rate decreased 1%/year. This presentation summarizes the early repairs, relines and improvements that have sustained and enhanced the furnace's performance. The fourth reline of both furnaces will be discussed in detail. As part of the 1991 reline of D furnace its lines were improved and modern penstocks installed. The bosh, tuyere jacket, hearth jacket and both cast floors were replaced. The furnace now has a larger hearth making it easier to control and, liquid level is no longer a problem when pulling the wind to shut down. The new cast floor with its increased trough length has much improved separation of slag from iron and lowered refractory consumption. Since the cast floors on D furnace were changed, there has been a reduction in accidents and absenteeism. This may be related to the change in work practices on the new cast floors. The 1994 reline of C furnace incorporates those improvements made on D furnace in 1991. In addition, C furnace will have high-density cooling which is expected to double its campaign from 6 to 12 years, without interim repairs.

  5. Optimization of a Steel Plant with Multiple Blast Furnaces Under Biomass Injection

    NASA Astrophysics Data System (ADS)

    Wiklund, Carl-Mikael; Pettersson, Frank; Saxén, Henrik

    2013-04-01

    The allocation of resources between several blast furnaces in an integrated steelmaking plant is studied with the aim of finding the lowest specific operation cost for steel production. In order to reduce the use of fossil fuels, biomass was considered as an auxiliary reductant in the furnace after partial pyrolysis in an external unit, as a complement to heavy fuel oil. The optimization considers raw material, energy, and emission costs and a possible credit for sold power and heat. To decrease computational requirements and to guarantee that the global optimum is found, a piecewise linearized model of the blast furnace was used in combination with linear models of the sinter-, coke-, and power plants, hot stoves, and basic oxygen furnace. The optimization was carried out under different constraints on the availability of some raw materials as well as for different efficiencies of the hot stoves of the blast furnaces. The results indicate that a non-uniform distribution of the production between the furnaces can be advantageous, and some surprising findings concerning the optimal resource allocation under constrained operation are reported.

  6. Stove

    SciTech Connect

    Wallasvaara, J.

    1983-03-08

    The invention concerns a stove comprising a burner, a combustion chamber, transport and exit ducts for the combustion gases, and at least one heating unit, such as a hearth plate or an oven. According to the invention, the stove comprises warm air duct with inlet and outlet and a blower, arranged to circulate air into said warm air duct to be heated by the heating unit and out from said duct. The stove may consist for instance of a lid lowerable over the hearth plate so that the warm air duct becomes confined between the lid and the hearth plate. When the stove comprises an oven, the warm air duct may conduct the air to be heated on the other hand into the oven and on the other hand into the intermediate space confined between the outer surface of the transport duct for the combustion gases.

  7. Blast furnace injection developments in British Steel

    SciTech Connect

    Jukes, M.H.

    1996-12-31

    British Steel has four integrated steel works, i.e., Llanwern, Port Talbot, Scunthorpe, Teesside, with a total of ten blast furnaces, nine of which are currently operating. The furnaces range in size from the 14 meters (45 feet 11 inches) hearth diameter Redcar No. 1 furnace at Teesside (a single furnace works) to the 8.33 meters (27 feet 4 inches) hearth Queen Mary and Queen Bess furnaces at Schunthorpe, with a total of four furnaces at that works. All have injection systems installed, those at Scunthorpe being equipped with granular coal injection and all others currently working with oil injection. The driving force behind the development of blast furnace injection has been as a means for introducing reducing agents (British Steel now refers to coke plus hydrocarbon injectants as total reductants) into the process as a part substitute/supplement for top charged coke and the technology is still being developed and used for that purpose. By utilizing practical experience and observing the work of others, British Steel has been assessing blast furnace injection technology experimentally for purposes other than the introduction of reducing agents.

  8. 6. Photocopy of a drawing of the lead blast furnace ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Photocopy of a drawing of the lead blast furnace from J.L. Bray, The Principles of Metallurgy, Ginn & Co. New York, 1929. - International Smelting & Refining Company, Tooele Smelter, Blast Furnace Building, State Route 178, Tooele, Tooele County, UT

  9. Enriching blast furnace gas by removing carbon dioxide.

    PubMed

    Zhang, Chongmin; Sun, Zhimin; Chen, Shuwen; Wang, Baohai

    2013-12-01

    Blast furnace gas (BF gas) produced in the iron making process is an essential energy resource for a steel making work. As compared with coke oven gas, the caloric value of BF gas is too low to be used alone as fuel in hot stove because of its high concentrations of carbon dioxide and nitrogen. If the carbon dioxide in BF gas could be captured efficiently, it would meet the increasing need of high caloric BF gas, and develop methods to reusing and/or recycling the separated carbon dioxide further. Focused on this, investigations were done with simple evaluation on possible methods of removing carbon dioxide from BF gas and basic experiments on carbon dioxide capture by chemical absorption. The experimental results showed that in 100 minutes, the maximum absorbed doses of carbon dioxide reached 20 g/100 g with ionic liquid as absorbent. PMID:25078829

  10. VIEW LOOKING NORTH, VIEW OF BLAST FURNACE NO. 2 (LEFT) ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW LOOKING NORTH, VIEW OF BLAST FURNACE NO. 2 (LEFT) SHARING THE SAME CAST HOUSE WITH BLAST FURNACE NO. 1. ORE BRIDGE & BLOWER HOUSE TO RIGHT, HULETT CAR DUMPER IS IN LEFT FOREGROUND. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 1 & No. 2, Donner Avenue, Monessen, Westmoreland County, PA

  11. Blast Furnace Granulated Coal Injection

    SciTech Connect

    1998-09-30

    Production levels on each furnace exceeded 7000 NTHM/day during July. The combined production of 14,326 was a result of lower coke rates and below average delay rates on both furnaces, The combined production was at its highest level since September 1997. In August, the combined productivity declined to less than 13,500 NTHM/day. Although D furnace maintained a production rate in excess of 7000 NTHM/day, C furnace was lower because of a castfloor breakout and subsequent five day repair from August 26-30. Despite the lower productivity in August, injected coal and furnace coke rates were very good during the month. During September, the operation was difficult as a result of higher delays on both furnaces. The combined average monthly delay rate was considerably above the twenty-month average of 113 minutes per day and the combined average monthly production was less than 14,000 NTHM/day. Higher furnace coke rates at lower coal injection levels also contributed to the decrease. Additionally, the coke rate on both furnaces was increased substantially and the injected coal rate was decreased in preparation for the high volatile Colorado coal trial that started on September 28. The furnace process results for this quarter are shown in Tables 1A and 1B. In addition, the last twelve months of injected coal and coke rates for each furnace are shown in Figures 1 and 2.

  12. Blast furnace on-line simulation model

    NASA Astrophysics Data System (ADS)

    Saxén, Henrik

    1990-10-01

    A mathematical model of the ironmaking blast furnace (BF) is presented. The model describes the steady-state operation of the furnace in one spatial dimension using real process data sampled at the steelworks. The measurement data are reconciled by an interface routine which yields boundary conditions obeying the conservation laws of atoms and energy. The simulation model, which provides a picture of the internal conditions of the BF, can be used to evaluate the current state of the process and to predict the effect of operating actions on the performance of the furnace.

  13. Process control techniques for the Sidmar blast furnaces

    SciTech Connect

    Vandenberghe, D.; Bonte, L.; Nieuwerburgh, H. van

    1995-12-01

    The major challenge for modern blast furnace operation is the achievement of a very high productivity, excellent hot metal quality, low fuel consumption and longer blast furnace campaigns. The introduction of predictive models, decision supporting software and expert systems has reduced the standard deviation of the hot metal silicon content. The production loss due to the thermal state of the blast furnace has decreased three times since 1990. An appropriate control of the heat losses with high pulverized coal injection rates, is of the utmost importance for the life of the blast furnace. Different rules for the burden distribution of both blast furnaces are given. At blast furnace A, a peripheral gas flow is promoted, while at blast furnace B a more central gas flow is promoted.

  14. Coke oven gas injection to blast furnaces

    SciTech Connect

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L.

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  15. 1. GENERAL VIEW OF BLAST FURNACE PLANT, KNOWN AS THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. GENERAL VIEW OF BLAST FURNACE PLANT, KNOWN AS THE CARRIE FURNACES, FROM THE TOP OF WATER TOWER. CARRIE FURNACES No. 6 AND No. 7 ARE ON THE LEFT, AND FURNACES No. 3 AND No. 4 ARE ON THE RIGHT. THE TOWN OF RANKIN IS IN THE BACKGROUND. Jet Lowe, Photographer, 1989. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  16. EXTERIOR VIEW, NO. 3 CAST HOUSE CENTER AND BLAST FURNACE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    EXTERIOR VIEW, NO. 3 CAST HOUSE CENTER AND BLAST FURNACE NO. 3 (JANE FURNACE)/ORE BRIDGE TO THE RIGHT, WITH SINTERING PLANT CONVEYORS & TRANSFER HOUSE IN FOREGROUND. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 3, Donner Avenue, Monessen, Westmoreland County, PA

  17. Modelling ironmaking blast furnace: Solid flow and thermochemical behaviours

    NASA Astrophysics Data System (ADS)

    Shen, Yansong; Guo, Baoyu; Yu, Aibing; Chew, Sheng; Austin, Peter

    2013-06-01

    Ironmaking blast furnace is a counter-, co-, cross-current moving bed reactor, where solid particles are charged at the furnace top forming a downward moving bed while gas are introduced at the lower part of furnace and travels upward through the solid bed of varying porosity, reducing solid ore to liquid iron at the cohesive zone. These three phases interact intensely. In this paper, a three-dimensional mathematical model is developed. The model describes the motion of solid and gas, based on continuum approach, and implements the so-called force balance model for the liquid flow. The model is applied to a blast furnace, where raceway cavity is considered explicitly. The results demonstrate and characterize the key multiphase flow patterns of solid-gas-liquid at different regions inside the blast furnace, in particular solid flow and associated thermochemical behaviours of solid particles. This model offers a costeffective tool to understand and optimize blast furnace operation.

  18. Durability of Alkali Activated Blast Furnace Slag

    NASA Astrophysics Data System (ADS)

    Ellis, K.; Alharbi, N.; Matheu, P. S.; Varela, B.; Hailstone, R.

    2015-11-01

    The alkali activation of blast furnace slag has the potential to reduce the environmental impact of cementitious materials and to be applied in geographic zones where weather is a factor that negatively affects performance of materials based on Ordinary Portland Cement. The scientific literature provides many examples of alkali activated slag with high compressive strengths; however research into the durability and resistance to aggressive environments is still necessary for applications in harsh weather conditions. In this study two design mixes of blast furnace slag with mine tailings were activated with a potassium based solution. The design mixes were characterized by scanning electron microscopy, BET analysis and compressive strength testing. Freeze-thaw testing up to 100 freeze-thaw cycles was performed in 10% road salt solution. Our findings included compressive strength of up to 100 MPa after 28 days of curing and 120 MPa after freeze-thaw testing. The relationship between pore size, compressive strength, and compressive strength after freeze-thaw was explored.

  19. 29. Blast furnace plant, looking southeast. The Machine Shop and ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    29. Blast furnace plant, looking southeast. The Machine Shop and Turbo Blower Building are at left, the pig-casting machine and Furnace A at center right. In foregound are the 50-ton ladle cars used to transport hot metal to Valley Mould & Iron Co. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  20. Comprehensive Numerical Modeling of the Blast Furnace Ironmaking Process

    NASA Astrophysics Data System (ADS)

    Zhou, Chenn; Tang, Guangwu; Wang, Jichao; Fu, Dong; Okosun, Tyamo; Silaen, Armin; Wu, Bin

    2016-05-01

    Blast furnaces are counter-current chemical reactors, widely utilized in the ironmaking industry. Hot reduction gases injected from lower regions of the furnace ascend, reacting with the descending burden. Through this reaction process, iron ore is reduced into liquid iron that is tapped from the furnace hearth. Due to the extremely harsh environment inside the blast furnace, it is difficult to measure or observe internal phenomena during operation. Through the collaboration between steel companies and the Center for Innovation through Visualization and Simulation, multiple computational fluid dynamics (CFD) models have been developed to simulate the complex multiphase reacting flow in the three regions of the furnace, the shaft, the raceway, and the hearth. The models have been used effectively to troubleshoot and optimize blast furnace operations. In addition, the CFD models have been integrated with virtual reality. An interactive virtual blast furnace has been developed for training purpose. This paper summarizes the developments and applications of blast furnace CFD models and the virtual blast furnace.

  1. Mercury in dumped blast furnace sludge

    NASA Astrophysics Data System (ADS)

    Földi, Corinna

    2014-05-01

    Blast furnace sludge (BFS) is a waste generated in the production of pig iron and was dumped in sedimentation ponds. As these wastes often contain high contents of zinc, lead, cadmium, and arsenic, significant hazards to environmental surroundings may arise from former BFS sedimentation ponds. Sixty-five samples from seven BFS locations in Europe were investigated regarding the toxic element mercury (Hg) for the first time. The charge material of the blast furnace operations (coke, iron ores, and additives such as olivine, bauxite, ilmenite and gravels) revealed Hg contents from 0.015 to 0.093 mg kg-1. In comparison, the Hg content of BFS varied between 0.006 and 20.8 mg kg-1 with a median of 1.63 mg kg-1, which indicates enrichment with Hg. For one site with a larger sample set (n = 31), Hg showed a stronger correlation with the total non-calcareous carbon (C) including coke and graphite (r = 0.695; n = 31; p < 0.001). It can be assumed that these C-rich compounds are hosting phases for Hg. The solubility of Hg was rather low and did not exceed 0.43% of total Hg. The correlation between the total Hg concentration and total amount of NH4NO3-soluble Hg was relatively poor (r = 0.496; n = 27; p = 0.008) indicating varying hazard potentials of the different BFS. Consequently, BFS is a mercury-containing waste and dumped BFS should be regarded as potentially mercury-contaminated sites.

  2. 15-Year blast furnace campaign concept for the reline of blast furnace C at Iscor

    SciTech Connect

    Noska, T.G.L.

    1995-07-01

    Since the 1970`s, when blast furnace campaigns of 3 to 5 years were experienced at the Vanderbijlpark Works, consequent improvements of cooling and refractory concepts as well as the development of a hot guniting practice for belly and lower shaft resulted in campaigns of 10 years and more. Having mastered the problems in belly and lower shaft, the furnace hearth became the ultimate limit and two hearth breakouts were experienced in the last 5 years in South Africa. After analyzing the causes for these breakouts, the requirements for a hearth refractory design, aimed at a 15-year plus campaign life, were formulated. A refractory design concept, which satisfies these requirements were developed based on European, American and Japanese philosophies.

  3. Modelling of multiphase flow in ironmaking blast furnace

    SciTech Connect

    Dong, X.F.; Yu, A.B.; Burgess, J.M.; Pinson, D.; Chew, S.; Zulli, P.

    2009-01-15

    A mathematical model for the four-phase (gas, powder, liquid, and solids) flow in a two-dimensional ironmaking blast furnace is presented by extending the existing two-fluid flow models. The model describes the motion of gas, solid, and powder phases, based on the continuum approach, and implements the so-called force balance model for the flow of liquids, such as metal and slag in a blast furnace. The model results demonstrate a solid stagnant zone and dense powder hold-up region, as well as a dense liquid flow region that exists in the lower part of a blast furnace, which are consistent with the experimental observations reported in the literature. The simulation is extended to investigate the effects of packing properties and operational conditions on the flow and the volume fraction distribution of each phase in a blast furnace. It is found that solid movement has a significant effect on powder holdup distribution. Small solid particles and low porosity distribution are predicted to affect the fluid flow considerably, and this can cause deterioration in bed permeability. The dynamic powder holdup in a furnace increases significantly with the increase of powder diameter. The findings should be useful to better understand and control blast furnace operations.

  4. Triple-activated blast furnace slag

    SciTech Connect

    Clarke, W.J.

    1995-12-31

    The current shortage of portland cement in the world will require the use of Ground Granulated Blast Furnace Slag (GGBFS) to fill demands in many industrialized countries. Therefore, an extensive series of triple-activated slag experiments have been undertaken to optimize an economical combination of mechanical properties for alkali-activated slags. Na{sub 2}OSiO{sub 2} (N Grade), Ca(OH){sub 2}, H{sub 2}O and Na{sub 2}CO{sub 3} have been added as activators in 5 to 10, 0 to 5 and 0 to 5 weight percentages of water and slag in a mix with a water:cement ratio of 1:1. Silica Fume and Sika 10 superplasticizer have been added as 1 and 10 weight percent of slag. Set times, initial hardening times and compressive strengths at percentages of the mix to identify more refined formulations. Finally, the resulting aggregate to develop a triple-activated slag formulation with the ultimate objective of contributing toward satisfying the world shortage of high performance concrete.

  5. A General Viscosity Model for Molten Blast Furnace Slag

    NASA Astrophysics Data System (ADS)

    Gan, Lei; Lai, Chaobin

    2014-06-01

    Blast furnace slag is the most abundant slag in the steel industry. Its metallurgical properties are determined to a great extent by its viscosity. Therefore, it is necessary to establish a reliable viscosity model for blast furnace slag. In the current work, a simple, accurate, and physically meaningful viscosity model for a wide composition range of blast furnace slags is developed based on the Vogel-Fulcher-Tammann (VFT) equation: log η = A + B/( T - C). The model is calibrated by a database containing 365 compositions and 1233 measurements of synthetic and industrial slags. The parameter A has a value of -3.10. The parameters B and C are related to the mass fraction ratio of (CaO + MgO) to (SiO2 + Al2O3) and liquidus temperature of the slag, respectively. Present viscosity model accurately predicts the viscosity of blast furnace slag with relative average error (Δ) of 0.211 (±0.180) and root mean square error (RMSE) of 0.239 Pa·s. A slight modification of this model can also predict the glass transition temperature of blast furnace slag satisfactorily.

  6. Blow-down and blow-in of Inland`s No. 7 blast furnace

    SciTech Connect

    Ricketts, J.; Quisenberry, P.; Carter, W.

    1995-12-01

    After extensive and detailed planning, a mini-reline of the 13.7 meter No. 7 Blast Furnace was executed in November 1993. The furnace lining had 18 million metric tons of production and the bosh, belly and lower stack lining were being maintained through a scheduled grouting practice. The mini-reline was planned for 33 days and the reline work included (a) replacing the bosh, belly and lower stack alumina lining with graphite brick, (b) gunning the middle and upper stack, (c) rebuilding the furnace top, stove burners and tapholes and (d) minor repairs to other auxiliary equipment. During this 33 day reline period the two 8 meter furnaces could only produce 40% of the normal production requirement, therefore the blow-down, quench, salamander tap and blow-in activities were critical to meeting the planned schedule. The planning of these activities was started in the spring of 1993 and included review of Inland`s past blow-down and blow-in performance as well as bench marking the performance of other large blast furnaces in North America, Japan and Europe. The development of the 1993 procedures focused on opportunities to accelerate the blow-down, quench, salamander tap and blow-in as well as having a clean hearth and stack which could also save time during the demolition phase of the reline. Any time that could be saved in these activities directly translated to an early start-up and more plantwide production. This paper will cover the successful planning and implementation of these activities which resulted in a 2 day reduction in the reline schedule, an accelerated production curve and an earlier than planned use of PCI during blow-in.

  7. An update on blast furnace granular coal injection

    SciTech Connect

    Hill, D.G.; Strayer, T.J.; Bouman, R.W.

    1997-12-31

    A blast furnace coal injection system has been constructed and is being used on the furnace at the Burns Harbor Division of Bethlehem Steel. The injection system was designed to deliver both granular (coarse) and pulverized (fine) coal. Construction was completed on schedule in early 1995. Coal injection rates on the two Burns Harbor furnaces were increased throughout 1995 and was over 200 lbs/ton on C furnace in September. The injection rate on C furnace reached 270 lbs/ton by mid-1996. A comparison of high volatile and low volatile coals as injectants shows that low volatile coal replaces more coke and results in a better blast furnace operation. The replacement ratio with low volatile coal is 0.96 lbs coke per pound of coal. A major conclusion of the work to date is that granular coal injection performs very well in large blast furnaces. Future testing will include a processed sub-bituminous coal, a high ash coal and a direct comparison of granular versus pulverized coal injection.

  8. Thermal valorisation of automobile shredder residue: injection in blast furnace.

    PubMed

    Mirabile, Daphne; Pistelli, Maria Ilaria; Marchesini, Marina; Falciani, Roberta; Chiappelli, Lisa

    2002-01-01

    Wastes with residual heating value, according to the trend of the world legislation, could be thermally reused. The present study is conducted to verify the possibility of thermal valorisation of a waste, denominated fluff, by injection in blast furnace. The fluff, arising from the automobile shredder operations, is a waste characterised by a high organic matrix and is potentially dangerous due to the heavy metals, oils filter and halogenated plastics content. The first step of the work is the chemical, physical and toxicological characterisation of this material. Then the fluff injection in a blast furnace tuyere is theoretically analysed with a mathematical model. Finally, experimental trials are conducted in a pilot plant, simulating the most important part of the blast furnace: the raceway, in order to analyse process and industrial aspects. In view of an industrial application a first economical evaluation is carried out on the basis of model and experimental results. PMID:12423043

  9. A dynamic simulation of a lead blast furnace

    NASA Astrophysics Data System (ADS)

    Chao, John T.

    1981-06-01

    A dynamic model has been developed to simulate the operation of the stack zone of a lead blast furnace. The mathematical formulation of the governing equations of change leads to a system of 2nd order partial differential equations, which is solved by finite difference methods. A reduction model of ash-layer diffusion controlled mechanism, which allows the stepwise reduction to the lowest oxide or metal thermodynamically possible for the local gas composition within the sinter, is employed in this model. The surface reaction and the internal diffusion in the porous solid particles are taken into account in the coke gasification reaction. The profiles of the temperatures of gases and solids, solid compositions, and gas compositions and pressure in both radial and axial directions are predicted by the model. The results provide a good representation of the experimental data obtained for the blast furnace at Brunswick Mining and Smelting Corp., Ltd., New Brunswick, Canada and also of the less extensive data available for the Cominco blast furnace at Trail, British Columbia, Canada. In addition to the modelling of the stack, a mass and energy balance for the bosh zone is also included in the present calculation. The improvement of coke efficiency due to oxygen enrichment in the blast air for the Brunswick Furnace were interpreted semiquantitatively. The effect of sinter size distribution on the furnace performance has also been studied.

  10. 13. Blast furnace plant embraces the east bank of the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    13. Blast furnace plant embraces the east bank of the Cuyahoga River. Plant was established in 1881 by the Cleveland Rolling Mill Co. It was absorbed by the American Steel and Wire Co. in 1899 and, two years later, by the U.S. Steel Corp., which closed it in 1978. View looking north. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  11. Numerical Study of the Reduction Process in an Oxygen Blast Furnace

    NASA Astrophysics Data System (ADS)

    Zhang, Zongliang; Meng, Jiale; Guo, Lei; Guo, Zhancheng

    2016-02-01

    Based on computational fluid dynamics, chemical reaction kinetics, principles of transfer in metallurgy, and other principles, a multi-fluid model for a traditional blast furnace was established. The furnace conditions were simulated with this multi-fluid mathematical model, and the model was verified with the comparison of calculation and measurement. Then a multi-fluid model for an oxygen blast furnace in the gasifier-full oxygen blast furnace process was established based on this traditional blast furnace model. With the established multi-fluid model for an oxygen blast furnace, the basic characteristics of iron ore reduction process in the oxygen blast furnace were summarized, including the changing process of the iron ore reduction degree and the compositions of the burden, etc. The study found that compared to the traditional blast furnace, the magnetite reserve zone in the furnace shaft under oxygen blast furnace condition was significantly reduced, which is conducive to the efficient operation of blast furnace. In order to optimize the oxygen blast furnace design and operating parameters, the iron ore reduction process in the oxygen blast furnace was researched under different shaft tuyere positions, different recycling gas temperatures, and different allocation ratios of recycling gas between the hearth tuyere and the shaft tuyere. The results indicate that these three factors all have a substantial impact on the ore reduction process in the oxygen blast furnace. Moderate shaft tuyere position, high recycling gas temperature, and high recycling gas allocation ratio between hearth and shaft could significantly promote the reduction of iron ore, reduce the scope of the magnetite reserve zone, and improve the performance of oxygen blast furnace. Based on the above findings, the recommendations for improvement of the oxygen blast furnace design and operation were proposed.

  12. Coke quality for blast furnaces with coal-dust fuel

    SciTech Connect

    Y.A. Zolotukhin; N.S. Andreichikov

    2009-07-01

    Recently, plans have been developed for the introduction of pulverized coal injection (PCI) at various Russian metallurgical enterprises. The main incentive for switching to PCI is the recent price rises for Russian natural gas. The paper discusses the quality of coke for PCI into blast furnaces.

  13. Coke mineral transformations in the experimental blast furnace

    SciTech Connect

    Kelli Kazuberns; Sushil Gupta; Mihaela Grigore; David French; Richard Sakurovs; Mats Hallin; Bo Lindblom; Veena Sahajwalla

    2008-09-15

    Blast furnace efficiency may be improved by optimizing coke reactivity. Some but not all forms of mineral matter in the coke modify its reactivity, but changes in mineral matter that occur within coke while in the blast furnace have not been fully quantified. To determine changes in mineral matter forms in the blast furnace, coke samples from a dissection study in the LKAB experimental blast furnace (EBF) were characterized using SEM/EDS analysis, EPMA (microprobe), and low-temperature ashing/quantitative XRD analysis. Variations in alkali concentration, particularly potassium, dominated the compositional changes. At high concentrations of potassium, the mineral matter was largely potassium-bearing but even more potassium was diffused throughout the coke and not associated with mineral matter. There was little difference in potassium concentration between the core and surface of the coke pieces, suggesting that potassium diffused rapidly through the whole coke. Iron, calcium, silicon, and aluminum concentrations were relatively constant in comparison, although the mineralogy of all elements changed significantly with changing temperature. 23 refs., 20 figs., 9 tabs.

  14. INTERIOR VIEW SHOWING DISPLAY OF INSIDE OF BLAST FURNACE AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW SHOWING DISPLAY OF INSIDE OF BLAST FURNACE AND MACHINERY AND ARTIFACTS INCLUDING A STEAM ENGINE HUB MADE AT THE BRIERFIELD ROLLING MILL (INSCRIBED C.C. HUCKABEE AND DATED 1863) AND OTHER STEAM ENGINES. - Iron & Steel Museum of Alabama, 12632 Confederate Pkwy., Bucksville, Tuscaloosa County, AL

  15. 20. TAKING A CAST AT BLAST FURNACE NO. 1. WORKERS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. TAKING A CAST AT BLAST FURNACE NO. 1. WORKERS, LIKE THE ONE STANDING ON THE BRIDGE ABOVE THE 'BOTTLE' INTO WHICH THE HOT IRON FLOWS, ARE PROTECTED BY HEAVY FIREPROOF GARMENTS. - Corrigan, McKinney Steel Company, 3100 East Forty-fifth Street, Cleveland, Cuyahoga County, OH

  16. CYANIDE REMOVAL FROM COKE MAKING AND BLAST FURNACE WASTE WATERS

    EPA Science Inventory

    The report gives results of a study to determine the feasibility of removing cyanide from coke making and blast furnace waste waters by ion flotation or column precipitate flotation of iron ferrocyanides. Ion flotation was reasonably effective on ferricyanide, but not on cyanide ...

  17. VIEW FROM THE SOUTH OF THE #1 BLAST FURNACE WITH ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW FROM THE SOUTH OF THE #1 BLAST FURNACE WITH SKIP HOIST AND DUST CATCHER. STOCK BINS FOR RAW MATERIALS ARE IN THE FOREGROUND, THE #2 CASTING SHED BEYOND. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  18. VIEW FROM THE EAST, SHOWING THE #2 BLAST FURNACE WITH ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW FROM THE EAST, SHOWING THE #2 BLAST FURNACE WITH SKIP HOIST, DUST CATCHER AND STOCK BINS FOR RAW MATERIALS IN THE FOREGROUND. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  19. CLOSEUP AERIAL VIEW OF BLAST FURNACES 1 & 2. SHARED ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    CLOSE-UP AERIAL VIEW OF BLAST FURNACES 1 & 2. SHARED CAST HOUSE LIES IN BETWEEN TWO SKIP INCLINES. HIP ROOF AT RIGHT COVERS BLOWING ENGINE HOUSE. VIEW FACING NORTH. - Pittsburgh Steel Company, Monessen Works, Donner Avenue, Monessen, Westmoreland County, PA

  20. A 3D CFD simulation of liquid flow in an ironmaking blast furnace

    NASA Astrophysics Data System (ADS)

    Shen, Yansong; Guo, Baoyu; Chew, Sheng; Austin, Peter; Yu, Aibing

    2013-07-01

    A three-dimensional CFX-based mathematical model is developed to describe the flow-heat transfer-chemical reactions behaviours of gas-solid-liquid phases in an ironmaking blast furnace (BF), where the raceway cavity is considered explicitly. The typical in-furnace phenomena of an operating blast furnace, in particular, the liquid flow in the lower part of a blast furnace is simulated in aspects of velocity and volume fraction. This model offers a cost-effective tool to understand and optimize blast furnace operation.

  1. Blast furnace coal injection system design for high rates

    SciTech Connect

    Snowden, B.

    1994-12-31

    Coal injection into blast furnaces is now well established as a basic technology. However, high rates of coal injection between 300 and 500 lb/thm (160 to 250 kg/thm) are a rarity. Special consideration must be given to the overall concept regarding strategic coal storage, expected equipment reliability, and back-up available to prevent furnace problems, should any of the coal feeding systems fail. British Steel and Simon Macawber now have considerable operational experience at high rates for sustained periods. The paper will discuss the points to be considered and describe the ATSI-Simon Macawber approach to providing a high level of confidence in the coal injection system.

  2. Thermal Spray Coatings for Blast Furnace Tuyere Application

    NASA Astrophysics Data System (ADS)

    Pathak, A.; Sivakumar, G.; Prusty, D.; Shalini, J.; Dutta, M.; Joshi, S. V.

    2015-12-01

    The components in an integrated steel plant are invariably exposed to harsh working environments involving exposure to high temperatures, corrosive gases, and erosion/wear conditions. One such critical component in the blast furnace is the tuyere, which is prone to thermal damage by splashing of molten metal/slag, erosive damage by falling burden material, and corrosion from the ensuing gases. All the above, collectively or independently, accelerate tuyere failure, which presents a potential explosion hazard in a blast furnace. Recently, thermal spray coatings have emerged as an effective solution to mitigate such severe operational challenges. In the present work, five different coatings deposited using detonation spray and air plasma spray techniques were comprehensively characterized. Performance evaluation involving thermal cycling, hot corrosion, and erosion tests was also carried out. Based on the studies, a coating system was suggested for possible tuyere applications and found to yield substantial improvement in service life during actual field trials.

  3. Energy Conservation for Granular Coal Injection into a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Guo, Hongwei; Su, Buxin; Zhang, Jianliang; Shao, Jiugang; Zuo, Haibin; Ren, Shan

    2012-08-01

    Due to the lack of knowledge regarding the combustion of granular coal injected into a blast furnace, injection characteristics of granular coal were first studied through proximate analysis, element analysis, and research of explosivity, ignition point, meltability of ash, grindability, calorific value, etc. Using a sampling device in the raceway combined with petrographic analysis, during the combustion process of granular coal with high crystal water and volatile in raceway, cracks and bursts were found, leading to a reduction of particle size. Based on a model of mass control and dynamic theory of particle combustion, the transition dynamic model for cracking in combustion of granular coal was found, and the critical value of cracking ratio (ΩP) for granular coal combustion in the raceway was calculated. Finally, the utilization ratio and energy efficiency of granular coal used in the blast furnace were discussed, offering theoretical foundation and technical support for intensifying granular coal combustion and promoting granular coal injection.

  4. Modelling the combustion of charcoal in a model blast furnace

    NASA Astrophysics Data System (ADS)

    Shen, Yansong; Shiozawa, Tomo; Yu, Aibing; Austin, Peter

    2013-07-01

    The pulverized charcoal (PCH) combustion in ironmaking blast furnaces is abstracting remarkable attention due to various benefits such as lowering CO2 emission. In this study, a three-dimensional CFD model is used to simulate the flow and thermo-chemical behaviours in this process. The model is validated against the experimental results from a pilot-scale combustion test rig for a range of conditions. The typical flow and thermo-chemical phenomena is simulated. The effect of charcoal type, i.e. VM content is examined, showing that the burnout increases with VM content in a linear relationship. This model provides an effective way for designing and optimizing PCH operation in blast furnace practice.

  5. Coke Reactivity in Simulated Blast Furnace Shaft Conditions

    NASA Astrophysics Data System (ADS)

    Haapakangas, Juho; Suopajärvi, Hannu; Iljana, Mikko; Kemppainen, Antti; Mattila, Olli; Heikkinen, Eetu-Pekka; Samuelsson, Caisa; Fabritius, Timo

    2016-08-01

    Despite the fact that H2 and H2O are always present in the gas atmosphere of a blast furnace shaft, their role in the solution-loss reactions of coke has not been thoroughly examined. This study focuses on how H2 and H2O affect the reaction behavior and whether a strong correlation can be found between reactivity in the conditions of the CRI test (Coke Reactivity Index) and various simulated blast furnace shaft gas atmospheres. Partial replacement of CO/CO2 with H2/H2O was found to significantly increase the reactivity of all seven coke grades at 1373 K (1100 °C). H2 and H2O, however, did not have a significant effect on the threshold temperature of gasification. The reactivity increasing effect was found to be temperature dependent and clearly at its highest at 1373 K (1100 °C). Mathematical models were used to calculate activation energies for the gasification, which were notably lower for H2O gasification compared to CO2 indicating the higher reactivity of H2O. The reactivity results in gas atmospheres with CO2 as the sole gasifying component did not directly correlate with reactivity results in gases also including H2O, which suggests that the widely used CRI test is not entirely accurate for estimating coke reactivity in the blast furnace.

  6. Coke Reactivity in Simulated Blast Furnace Shaft Conditions

    NASA Astrophysics Data System (ADS)

    Haapakangas, Juho; Suopajärvi, Hannu; Iljana, Mikko; Kemppainen, Antti; Mattila, Olli; Heikkinen, Eetu-Pekka; Samuelsson, Caisa; Fabritius, Timo

    2016-04-01

    Despite the fact that H2 and H2O are always present in the gas atmosphere of a blast furnace shaft, their role in the solution-loss reactions of coke has not been thoroughly examined. This study focuses on how H2 and H2O affect the reaction behavior and whether a strong correlation can be found between reactivity in the conditions of the CRI test (Coke Reactivity Index) and various simulated blast furnace shaft gas atmospheres. Partial replacement of CO/CO2 with H2/H2O was found to significantly increase the reactivity of all seven coke grades at 1373 K (1100 °C). H2 and H2O, however, did not have a significant effect on the threshold temperature of gasification. The reactivity increasing effect was found to be temperature dependent and clearly at its highest at 1373 K (1100 °C). Mathematical models were used to calculate activation energies for the gasification, which were notably lower for H2O gasification compared to CO2 indicating the higher reactivity of H2O. The reactivity results in gas atmospheres with CO2 as the sole gasifying component did not directly correlate with reactivity results in gases also including H2O, which suggests that the widely used CRI test is not entirely accurate for estimating coke reactivity in the blast furnace.

  7. Minimization of Blast furnace Fuel Rate by Optimizing Burden and Gas Distribution

    SciTech Connect

    Dr. Chenn Zhou

    2012-08-15

    The goal of the research is to improve the competitive edge of steel mills by using the advanced CFD technology to optimize the gas and burden distributions inside a blast furnace for achieving the best gas utilization. A state-of-the-art 3-D CFD model has been developed for simulating the gas distribution inside a blast furnace at given burden conditions, burden distribution and blast parameters. The comprehensive 3-D CFD model has been validated by plant measurement data from an actual blast furnace. Validation of the sub-models is also achieved. The user friendly software package named Blast Furnace Shaft Simulator (BFSS) has been developed to simulate the blast furnace shaft process. The research has significant benefits to the steel industry with high productivity, low energy consumption, and improved environment.

  8. DESTRUCTION AND REMOVAL OF POHCS (PRINCPAL ORGANIC HAZARDOUS CONSTITUENTS) IN IRON MAKING BLAST FURNACES

    EPA Science Inventory

    At least one steel company utilizes organic waste liquids as a heat and carbon content source to partially replace the coke that is used to charge the blast furnaces. The waste liquids fed to the blast furnace are likely to contain hazardous constituents. Temperature and residenc...

  9. BLAST FURNACE SLIPS AND ACCOMPANYING EMISSIONS AS AN AIR POLLUTION SOURCE

    EPA Science Inventory

    The report gives results of a study to ascertain the severity of blast-furnace slips and their accompanying bleeder-valve emissions as a source of air pollution. It describes factors contributing to the occurrence of hangs and slips in the blast furnace. It discusses the mechanic...

  10. Production of blast furnace coke via novel briquetting system

    SciTech Connect

    Theodore, F.W.; Wasson, G.E.

    1982-12-07

    A method of making high strength coke briquettes suitable for use as blast furnace coke comprising, (A) providing coal, (B) heating the coal at a temperature at or above the softening point of the coal to form partially carbonized char, (C) cooling the partially carbonized char below the softening point of the coal, (D) mixing the cooled partially carbonized char and tar to form a mixture of tar and partially carbonized char, (E) briquetting the mixture of tar and partially carbonized char to form briquettes of tar and partially carbonized char, (F) calcinating the briquettes to form high strength briquettes.

  11. Marble-type glass based on blast furnace slag

    SciTech Connect

    Sarkisov, P.D.; Smirnov, V.G.; Trifonova, T.E.; Sergeev, Yu.N.

    1987-01-01

    This paper discusses the recovery and use of blast furnace wastes as coloring agents in the manufacture of imitation marble glass. The slags consist of a series of metal oxides each of which is tested for the color it generates when reacted and annealed with the molten glass. Comparative tests were also run against non-waste coloring agents and it was found that the waste-derived colorants were equal or superior both in process behavior and in generating the appropriate optical properties in the finished glass.

  12. The limitation of hearth sidewall wear at Redcar blast furnace

    SciTech Connect

    Parratt, J.E.

    1996-12-31

    The Redcar blast furnace with 14m hearth diameter was blown-in for its second campaign in August 1996. It is currently in its 10th year of operation and to date has produced just over 30 million tonnes. Current plans are to continue the second campaign to the year 2000 and beyond, producing over 40 million tonnes. In order to achieve this objective, any further wear on the lining, and in particular the hearth sidewall, needs to be minimized. This paper describes the present hearth design, the monitoring of hearth wear, the predicted wear profile, and the protection measures that have been taken or are being considered.

  13. Theoretical and experimental foundations for preparing coke for blast-furnace smelting

    SciTech Connect

    A.L. Podkorytov; A.M. Kuznetsov; E.N. Dymchenko; V.P. Padalka; S.L. Yaroshevskii; A.V. Kuzin

    2009-05-15

    This article examines the preparation of coke for blast-furnace smelting by a method that most fully meets the requirements of blast-furnace technology: screening of the -36 mm fraction, the separation of nut coke of the 15-36 mm fraction, and its charging into the furnace in a mixture with the iron-ore-bearing charge components. An analysis is made of trial use of coke of the Premium class on blast furnace No. 5 at the Enakievo Metallurgical Plant. Use of this coke makes it possible to reduce the consumption of skip coke by 3.2-4.1%.

  14. Torrefied biomasses in a drop tube furnace to evaluate their utility in blast furnaces.

    PubMed

    Chen, Wei-Hsin; Du, Shan-Wen; Tsai, Chien-Hsiung; Wang, Zhen-Yu

    2012-05-01

    Torrefaction and burning characteristics of bamboo, oil palm, rice husk, bagasse, and Madagascar almond were studied and compared with a high-volatile bituminous coal using a drop tube furnace to evaluate the potential of biomass consumed in blast furnaces. Torrefaction at 250 and 300°C for 1h duration was carried out. Analysis using the ash tracer method indicated that the extent of atomic carbon reduction in the biomasses was less than that of atomic hydrogen and oxygen. Torrefaction also lowered the sulfur content in bamboo and oil palm over 33%. An examination of the R-factor and burnout of the samples suggests that more volatiles were released and a higher burnout was achieved with raw and torrefied biomasses at 250°C than at 300°C; however, torrefaction at 300°C is a feasible operating condition to transform biomass into a solid fuel resembling a high-volatile bituminous coal used for blast furnaces. PMID:22386202

  15. Preparation of Ceramic-Bonded Carbon Block for Blast Furnace

    NASA Astrophysics Data System (ADS)

    Li, Yiwei; Li, Yawei; Sang, Shaobai; Chen, Xilai; Zhao, Lei; Li, Yuanbing; Li, Shujing

    2014-01-01

    Traditional carbon blocks for blast furnaces are mainly produced with electrically calcined anthracite owing to its good hot metal corrosion resistance. However, this kind of material shows low thermal conductivity and does not meet the demands for cooling of the hearth and the bottom of blast furnaces. In this article, a new kind of a high-performance carbon block has been prepared via ceramic-bonded carbon (CBC) technology in a coke bed at 1673 K (1400 °C) using artificial graphite aggregate, alumina, metallic aluminum, and silicon powders as starting materials. The results showed that artificial graphite aggregates were strongly bonded by the three-dimensional network of ceramic phases in carbon blocks. In this case, the good resistance of the CBC blocks against erosion/corrosion by the hot metal is provided by the ceramic matrix and the high thermal conductivity by the graphite aggregates. The microstructure of this carbon block resembles that of CBC composites with a mean pore size of less than 0.1 μm, and up to 90 pct of the porosity shows a pore size <1 μm. Its thermal conductivity is higher than 30 W · m-1 · K-1 [293 K (20 °C)]. Meanwhile, its hot metal corrosion resistance is better than that of traditional carbon blocks.

  16. Carbothermic Reduction of Titanium-Bearing Blast Furnace Slag

    NASA Astrophysics Data System (ADS)

    Zhen, Yu-Lan; Zhang, Guo-Hua; Chou, Kuo-Chih

    2016-03-01

    The carbothermic reduction experiments were carried out for titanium-bearing blast furnace slag in Panzhihua Iron and Steel Company in argon atmosphere at high temperatures. The effects of reduction temperature, isothermal treatment time and carbon content on the formation of TiC were studied by X-ray diffraction (XRD) and scanning electron microscope (SEM). The XRD pattern results showed that MgAl2O4 phase disappeared and the main phase of the reduced sample was TiC when the reduction temperature was higher than 1,773 K. The SEM pictures showed that the reduction rate of the titanium-bearing blast furnace slag could be increased by enhancing the temperature and the C content (carbon ratio ≤1.0). Furthermore, it was also found that TiC had the tendency of concentrating around the iron. The effects of additives such as Fe and CaCl2 on the formation of TiC were also studied in the present study.

  17. Modeling of Blast Furnace with Layered Cohesive Zone

    NASA Astrophysics Data System (ADS)

    Dong, X. F.; Yu, A. B.; Chew, S. J.; Zulli, P.

    2010-04-01

    An ironmaking blast furnace (BF) is a moving bed reactor involving counter-, co-, and cross-current flows of gas, powder, liquids, and solids, coupled with heat exchange and chemical reactions. The behavior of multiple phases directly affects the stability and productivity of the furnace. In the present study, a mathematical model is proposed to describe the behavior of fluid flow, heat and mass transfer, as well as chemical reactions in a BF, in which gas, solid, and liquid phases affect each other through interaction forces, and their flows are competing for the space available. Process variables that characterize the internal furnace state, such as reduction degree, reducing gas and burden concentrations, as well as gas and condensed phase temperatures, have been described quantitatively. In particular, different treatments of the cohesive zone (CZ), i.e., layered, isotropic, and anisotropic nonlayered, are discussed, and their influence on simulation results is compared. The results show that predicted fluid flow and thermochemical phenomena within and around the CZ and in the lower part of the BF are different for different treatments. The layered CZ treatment corresponds to the layered charging of burden and naturally can predict the CZ as a gas distributor and liquid generator.

  18. Waste Heat Recovery from Blast Furnace Slag by Chemical Reactions

    NASA Astrophysics Data System (ADS)

    Qin, Yuelin; Lv, Xuewei; Bai, Chenguang; Qiu, Guibao; Chen, Pan

    2012-08-01

    Blast furnace (BF) slag, which is the main byproduct in the ironmaking process, contains large amounts of sensible heat. To recover the heat, a new waste heat-recovery system—granulating molten BF slag by rotary multinozzles cup atomizer and pyrolyzing printed circuited board with obtained hot BF slag particle—was proposed in this study. The feasibility of the waste heat-recovery system was verified by dry granulation and pyrolyzation experiments. The energy of hot BF slag could be converted to chemical energy through the pyrolysis reaction, and a large amount of combustible gas like CO, H2, C m H n , and CH4 can be generated during the process.

  19. Greener durable concretes through geopolymerisation of blast furnace slag

    NASA Astrophysics Data System (ADS)

    Rajamane, N. P.; Nataraja, M. C.; Jeyalakshmi, R.; Nithiyanantham, S.

    2015-05-01

    The eco-friendliness of concrete is quantified by parameters such as ‘embodied energy’ (EE) and ‘embodied CO2 emission’ (ECO2e), besides duration of designed ‘service life’. It may be noted that ECO2e is also referred as carbon footprint (CF) in the literature. Geopolymer (GP) is an inorganic polymeric gel, a type of amorphous alumino-silicate product, which can be synthesised by polycondensation reactions. The concrete reported in this paper was prepared using industrial wastes in the form of blast furnace slag, fly ash as geopolymeric source materials and sodium silicate and sodium hydroxide as activators. Many mechanical properties such as compressive strength, chloride diffusion, steel corrosion, rapid chloride permeability test and rapid migration test are compared with Portland cement.

  20. Nuclear techniques for the inspection of blast furnaces

    SciTech Connect

    Schweitzer, J. S.; Lanza, R. C.

    1999-06-10

    Carbon hearth wall failures in blast furnaces create safety risks and require a large expense to repair. To avoid failures they are replaced early, incurring costs in wasted hearth wall use. Two non-invasive measurements provide realtime analysis of wall integrity. The two major failure modes are erosion of carbon thickness and iron-filled cracks in the bricks. Measurements of backscattered gamma-ray spectra and thermal neutron decay rate can identify both phenomena. Gamma-ray spectra from a compact Linac beam primarily respond to average carbon thickness. Neutron decay time, using a pulsed neutron source, is sensitive to iron in the carbon volume. Each measurement is sensitive to the other failure made, but the combination permits each phenomenon to be resolved. These techniques can detect a high atomic number and thermal neutron absorption cross section material behind one of low atomic number and thermal neutron absorption cross section.

  1. Laser sensing in the iron-making blast furnace

    NASA Astrophysics Data System (ADS)

    Scott, J. Chris

    1991-03-01

    The measurement of parameters such as distance and temperature in the Ironmaking Blast Furnace is crucial to the performance of the furnace. A series of instruments has been designed, built and tested by BHP which perform these tasks optically requiring no physical intrusion into the harsh environment of the furnace. The problem of coupling high peak power Nd:YAG and ultra violet laser radiation into environments consisting of very high water vapour level, acidic, high aerosol loading, and high temperature environments is considered. The performance of two systems enabling distance measurement with sub-pulse length range resolution under the above conditions is discussed in detail. The use of optical fibres to deliver the pulsed energy to and from the environment together with specific window design parameters are also described. A major problem in making time of flight range measurements in very high density aerosol conditions is the signal processing required to extract the target return pulse position from the complex aerosol return signal. Incoherent detection techniques used to achieve this discrimination where target temperatures can exceed 2000°C are discussed. The selection of operating laser wavelength and repetition rate were based on an analysis of the optical characteristics of gases and aerosol forming the measurement environment together with the dynamic behaviour of the high temperature target. The extension of laser radar techniques to optical fibres is discussed and a distributed temperature sensing system is described which measures temperatures up to 250°C with a spatial resolution better than O.Sm.

  2. PHYSICAL/CHEMICAL TREATMENT OF BLAST FURNACE WASTEWATERS USING MOBILE PILOT UNITS

    EPA Science Inventory

    The report documents an in-depth pilot-plant investigation of the applicability of advanced waste treatment methods for upgrading ironmaking blast furnace wastewaters to Best Available Technology Economically Achievable (BATEA) levels. Mobile treatments facilities, designed to op...

  3. Cold bonded briquettes with high temperature properties for blast furnace burdens

    SciTech Connect

    Vogel, R.; Auslander, E.; Rankin, R.

    1997-12-31

    A combination briquetting process and proprietary binder system, that combines numerous revert materials into a productive blast furnace feed material, has been developed by Ferrous Environmental Recycling Corporation (FERCO). It has been proven that, when used at 5% of the blast furnace burden, these briquettes yield a coke savings of 40 lbs./NTHM and a production rate increase of approximately 4%. Residual elements in the briquettes are controlled through chemical analysis and careful blending, so that there are no adverse effects in steelmaking. The process combines several revert materials, including coke breeze and blast furnace flue dust, with a proprietary binder to produce a briquette with excellent high temperature properties. The briquette is designed to consume waste stream reverts with the significant added benefits of lower blast furnace fuel rates and increased hot metal production. Since 1988, nearly 750,000 tons of these briquettes have been produced and consumed.

  4. Titanium addition practice, and maintenance for the hearths in AHMSA`s blast furnaces

    SciTech Connect

    Boone, A.G.; Jimenez, G.; Castillo, J.

    1997-12-31

    Altos Hornos de Mexico (AHMSA) is a steel company located in Northern Mexico, in the state of Coahuila. Currently there are three blast furnaces in operation and one more about to finish its general repair. This last one is to remain as a back-up unit. Because of blast furnace hearth wear outs AHMSA has developed some maintenance procedures. These procedures are based on titanium ore additions and hearth thermic control monitoring. There are also some other maintenance practices adopted to the working operations to assure that such operations detect and avoid in time hearth wear outs that place personnel and/or the unit in danger (due to hearth leaks). This paper describes titanium ore addition to No. 2 blast furnace during the final campaign and it also illustrates maintenance practices and continuous monitoring of temperature trends both of which were implemented at AHMSA`s No. 5 blast furnace.

  5. BLAST FURNACE GRANULAR COAL INJECTION SYSTEM. Final Report Volume 2: Project Performance and Economics

    SciTech Connect

    Unknown

    1999-10-01

    Bethlehem Steel Corporation (BSC) requested financial assistance from the Department of Energy (DOE), for the design, construction and operation of a 2,800-ton-per-day blast furnace granulated coal injection (BFGCI) system for two existing iron-making blast furnaces. The blast furnaces are located at BSC's facilities in Burns Harbor, Indiana. The demonstration project proposal was selected by the DOE and awarded to Bethlehem in November 1990. The design of the project was completed in December 1993 and construction was completed in January 1995. The equipment startup period continued to November 1995 at which time the operating and testing program began. The blast furnace test program with different injected coals was completed in December 1998.

  6. Coal-oil mixture combustion program: injection into a blast furnace

    SciTech Connect

    Jansto, S.G.; Mertdogan, A.; Marlin, L.A.; Beaucaire, V.D.

    1982-04-30

    A chemically stabilized coal-oil mixture (COM) was made and used as an auxiliary fuel in a blast furnace for 44 days. Approximately 485,000 gallons of COM were produced at an on-site COM plant. Composition was 47.9% coal, 47.6% No. 6 oil, 4.0% water, and 0.5% emulsifier. Average injection rates were 3.8 to 13.0 gpm during different periods of the trial. Coal handling equipment, mixing and processing equipment, pumps, piping, fuel lances, and instrumentation are discussed. The blast furnace performance during the trial is compared to a Base Period of injecting No. 6 oil. Blast furnace performance was satisfactory, with one pound of COM replacing one pound of coke or 0.8 pound of No. 6 oil. The production of COM and its usage in a blast furnace is economical and feasible.

  7. Hearth monitoring experiences at Dofasco`s No. 4 blast furnace

    SciTech Connect

    Stothart, D.W.; Chaykowski, R.D.; Donaldson, R.J.; Pomeroy, D.H.

    1997-12-31

    As a result of a 1994 taphole breakout at Dofasco`s No. 4 Blast Furnace, extensive effort has gone into monitoring, understanding and controlling hearth wear. This paper reviews the hearth monitoring system developed and the various hearth operating and maintenance techniques used to ensure No. 4 Blast Furnace safely reaches its 1998 reline date. The impact of changes in coke quality, productivity, casting practice and leaking cooling members on hearth refractory temperature fluctuations will also be examined.

  8. Coal combustion under conditions of blast furnace injection. Final technical report, September 1, 1992--August 31, 1993

    SciTech Connect

    Crelling, J.C.; Case, E.R.

    1993-12-31

    A potentially new use for Illinois coal is as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. During the first phase of this project a number of the objectives were realized, specifically: (1) a blast furnace sampling system was developed and used successfully to collect samples inside an active furnace; (2) two sets of blast furnace samples were collected and petrographic analysis showed that char derived from injected coal is entering the reduction zone of the furnace; (3) a coal/char sampling probe was designed and fabricated; (4) the completion of a program of reactivity experiments on the injected coal char, blast furnace coke and Herrin No. 6 char. The results of the reactivity experiments indicate that Herrin No. 6 coal is similar or even superior to coals now being used in blast furnace injection and that additional testing is warranted.

  9. Sequential extraction of inorganic mercury in dumped blast furnace sludge.

    PubMed

    Földi, Corinna; Andrée, Corlin-Anna; Mansfeldt, Tim

    2015-10-01

    Blast furnace sludge (BFS) is an industrial waste with elevated mercury (Hg) contents due to the enrichment during the production process of pig iron. To investigate the potential pollution status of dumped BFS, 14 samples with total Hg contents ranging from 3.91 to 20.8 mg kg(-1) from five different locations in Europe were sequentially extracted. Extracts used included demineralized water (fraction 1, F1), 0.1 mol L(-1) CH3COOH + 0.01 mol L(-1) HCl (F2), 1 mol L(-1) KOH (F3), 7.9 mol L(-1) HNO3 (F4), and aqua regia (F5). The total recovery ranged from 72.3 to 114 %, indicating that the procedure was reliable when adapted to this industrial waste. Mercury mainly resided in the fraction of "elemental" Hg (48.5-98.8 %) rather being present as slightly soluble Hg species associated with sludge particles. Minor amounts were found as mercuric sulfide (F5; 0.725-37.3 %) and Hg in crystalline metal ores and silicates (F6; 2.21-15.1 %). The ecotoxically relevant fractions (F1 and F2) were not of significance (F1,

  10. Vanadium bioavailability in soils amended with blast furnace slag.

    PubMed

    Larsson, Maja A; Baken, Stijn; Smolders, Erik; Cubadda, Francesco; Gustafsson, Jon Petter

    2015-10-15

    Blast furnace (BF) slags are commonly applied as soil amendments and in road fill material. In Sweden they are also naturally high in vanadium. The aim of this study was to assess the vanadium bioavailability in BF slags when applied to soil. Two soils were amended with up to 29% BF slag (containing 800 mg V kg(-1)) and equilibrated outdoors for 10 months before conducting a barley shoot growth assay. Additional soil samples were spiked with dissolved vanadate(V) for which assays were conducted two weeks (freshly spiked) and 10 months (aged) after spiking. The BF slag vanadium was dominated by vanadium(III) as shown by V K-edge XANES spectroscopy. In contrast, results obtained by HPLC-ICP-MS showed that vanadium(V), the most toxic vanadium species, was predominant in the soil solution. Barley shoot growth was not affected by the BF slag additions. This was likely due to limited dissolution of vanadium from the BF slag, preventing an increase of dissolved vanadium above toxic thresholds. The difference in vanadium bioavailability among treatments was explained by the vanadium concentration in the soil solution. It was concluded that the vanadium in BF slag is sparingly available. These findings should be of importance in environmental risk assessment. PMID:25917693

  11. Preparation of calcium silicate absorbent from iron blast furnace slag.

    PubMed

    Brodnax, L F; Rochelle, G T

    2000-09-01

    Calcium silicate hydrate (CSH) solids were prepared from hydrated lime and iron blast furnace slag in an aqueous agitated slurry at 92 degrees C. While it was hoped a minimal lime/slag ratio could be used to create near-amorphous CSH, the surface area of the product improved by increasing the lime/slag weight ratio to 2. The addition of gypsum to the lime/slag system dramatically improved the formation of surface area, creating solids with 139 m2/g after 30 hr of reaction when only a minimal amount of lime was present. The SO2 reactivity of solids prepared with gypsum greatly exceeded that of hydrated lime, achieving greater than 70-80% conversion of the alkalinity after 1 hr of reaction with SO2. The use of CaCl2 as an additive to the lime/slag system, in lieu of gypsum, also produced high-surface-area solids, 115 m2/g after 21 hr of reaction. However, the SO2 reactivity of these sorbents was relatively low given the high surface area. This emphasized that the correlation between surface area and SO2 reactivity was highly dependent on the solid phase, which was subsequently dependent on slurry composition. PMID:11055162

  12. An Integrated Model of Coal/Coke Combustion in a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Shen, Y. S.; Guo, B. Y.; Yu, A. B.; Austin, P.; Zulli, P.

    2010-03-01

    A three-dimensional integrated mathematical model of the combustion of pulverized coal and coke is developed. The model is applied to the region of lance-blowpipe-tuyere-raceway-coke bed to simulate the operation of pulverized coal injection in an ironmaking blast furnace. The model integrates two parts: pulverized coal combustion model in the blowpipe-tuyere-raceway-coke bed and the coke combustion model in the coke bed. The model is validated against the measurements in terms of coal burnout and gas composition, respectively. The comprehensive in-furnace phenomena are simulated in the raceway and coke bed, in terms of flow, temperature, gas composition, and coal burning characteristics. In addition, underlying mechanisms for the in-furnace phenomena are analyzed. The model provides a cost-effective tool for understanding and optimizing the in-furnace flow-thermo-chemical characteristics of the PCI process in full-scale blast furnaces.

  13. Evaluation on chemical stability of lead blast furnace (LBF) and imperial smelting furnace (ISF) slags.

    PubMed

    Yin, Nang-Htay; Sivry, Yann; Guyot, François; Lens, Piet N L; van Hullebusch, Eric D

    2016-09-15

    The leaching behavior of Pb and Zn from lead blast furnace (LBF) and imperial smelting furnace (ISF) slags sampled in the North of France was studied as a function of pHs and under two atmospheres (open air and nitrogen). The leaching of major elements from the slags was monitored as a function of pH (4, 5.5, 7, 8.5 and 10) under both atmospheres for different slag-water interaction times (1 day and 9 days). The leaching results were coupled with a geochemical model; Visual MINTEQ version 3.0, and a detailed morphological and mineralogical analysis was performed on the leached slags by scanning and transmission electron microscopy (SEM and TEM). Significant amounts of Ca, Fe and Zn were released under acidic conditions (pH 4) with a decrease towards the neutral to alkaline conditions (pH 7 and 10) for both LBF and ISF slags. On the other hand, Fe leachability was limited at neutral to alkaline pH for both slags. The concentrations of all elements increased gradually after 216 h compared to initial 24 h of leaching period. The presence of oxygen under open-air atmosphere not only enhanced oxidative weathering but also encouraged formation of secondary oxide and carbonate phases. Formation of carbonates and clay minerals was suggested by Visual MINTEQ which was further confirmed by SEM & TEM. The hydration and partial dissolution of hardystonite, as well as the destabilization of amorphous glassy matrix mainly contributed to the release of major elements, whereas the spinel related oxides were resistant against pH changes and atmospheres within the time frame concerned for both LBF and ISF slags. The total amount of Pb leached out at pH 7 under both atmospheres suggested that both LBF and ISF slags are prone to weathering even at neutral environmental conditions. PMID:27240207

  14. Multiscale dynamic analysis of blast furnace system based on intensive signal processing

    NASA Astrophysics Data System (ADS)

    Chu, Yanxu; Gao, Chuanhou; Liu, Xiangguan

    2010-09-01

    In this paper, the Hilbert-Huang transform method and time delay embedding method are applied to multiscale dynamic analysis on the time series of silicon content in hot metal collected from a medium-sized blast furnace with the inner volume of 2500 m3. The results provide clear evidence of multiscale features in blast furnace ironmaking process. Ten intrinsic mode functions (IMFs) are decomposed from the silicon content time series; the presence of noninteger fractal dimension, positive finite Kolmogorov entropy, and positive finite maximum Lyapunov exponent are found in some IMF components. In addition, the coupling of subscale structures of blast furnace system is studied using the dimension of interaction dynamics and a robust algorithm for detecting interdependence. It is found that IMF(3) is the main driver in the coupling system IMF(2) and IMF(3) while for the coupling system IMF(3) and IMF(4) neither subsystem can act as the driver. All these provide a guideline for studying blast furnace ironmaking process with multiscale theory and methods, and may open way for more candidate tools to model and control blast furnace system in the future.

  15. Multiscale dynamic analysis of blast furnace system based on intensive signal processing.

    PubMed

    Chu, Yanxu; Gao, Chuanhou; Liu, Xiangguan

    2010-09-01

    In this paper, the Hilbert-Huang transform method and time delay embedding method are applied to multiscale dynamic analysis on the time series of silicon content in hot metal collected from a medium-sized blast furnace with the inner volume of 2500 m3. The results provide clear evidence of multiscale features in blast furnace ironmaking process. Ten intrinsic mode functions (IMFs) are decomposed from the silicon content time series; the presence of noninteger fractal dimension, positive finite Kolmogorov entropy, and positive finite maximum Lyapunov exponent are found in some IMF components. In addition, the coupling of subscale structures of blast furnace system is studied using the dimension of interaction dynamics and a robust algorithm for detecting interdependence. It is found that IMF(3) is the main driver in the coupling system IMF(2) and IMF(3) while for the coupling system IMF(3) and IMF(4) neither subsystem can act as the driver. All these provide a guideline for studying blast furnace ironmaking process with multiscale theory and methods, and may open way for more candidate tools to model and control blast furnace system in the future. PMID:20887042

  16. Coal combustion under conditions of blast furnace injection; [Quarterly] technical report, September 1--November 30, 1993

    SciTech Connect

    Crelling, J.C.

    1993-12-31

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. steel company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals f or such use.

  17. A Feasibility Study for Recycling Used Automotive Oil Filters In A Blast Furnace

    SciTech Connect

    Ralph M. Smailer; Gregory L. Dressel; Jennifer Hsu Hill

    2002-01-21

    This feasibility study has indicated that of the approximately 120,000 tons of steel available to be recycled from used oil filters (UOF's), a maximum blast furnace charge of 2% of the burden may be anticipated for short term use of a few months. The oil contained in the most readily processed UOF's being properly hot drained and crushed is approximately 12% to 14% by weight. This oil will be pyrolized at a rate of 98% resulting in additional fuel gas of 68% and a condensable hydrocarbon fraction of 30%, with the remaining 2% resulting as carbon being added into the burden. Based upon the writer's collected information and assessment, there appears to be no operational problems relating to the recycling of UOF's to the blast furnace. One steel plant in the US has been routinely charging UOF's at about 100 tons to 200 tons per month for many years. Extensive analysis and calculations appear to indicate no toxic consideration as a result of the pyrolysis of the small contained oil ( in the 'prepared' UOFs) within the blast furnace. However, a hydrocarbon condensate in the ''gasoline'' fraction will condense in the blast furnace scrubber water and may require additional processing the water treatment system to remove benzene and toluene from the condensate. Used oil filters represent an additional source of high quality iron units that may be effectively added to the charge of a blast furnace for beneficial value to the operator and to the removal of this resource from landfills.

  18. Recovery Act: ArcelorMittal USA Blast Furnace Gas Flare Capture

    SciTech Connect

    Seaman, John

    2013-01-14

    The U.S. Department of Energy (DOE) awarded a financial assistance grant under the American Recovery and Reinvestment Act of 2009 (Recovery Act) to ArcelorMittal USA, Inc. (ArcelorMittal) for a project to construct and operate a blast furnace gas recovery boiler and supporting infrastructure at ArcelorMittal’s Indiana Harbor Steel Mill in East Chicago, Indiana. Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when iron ore is reduced with coke to create metallic iron. BFG has a very low heating value, about 1/10th the heating value of natural gas. BFG is commonly used as a boiler fuel; however, before installation of the gas recovery boiler, ArcelorMittal flared 22 percent of the blast furnace gas produced at the No. 7 Blast Furnace at Indiana Harbor. The project uses the previously flared BFG to power a new high efficiency boiler which produces 350,000 pounds of steam per hour. The steam produced is used to drive existing turbines to generate electricity and for other requirements at the facility. The goals of the project included job creation and preservation, reduced energy consumption, reduced energy costs, environmental improvement, and sustainability.

  19. Recent improvements in blast furnace operation within the AHMSA/GAN, Monclova Mexico works

    SciTech Connect

    Morales, J.M.; Dominguez, H.; Geerdes, M.

    1993-01-01

    Following the privatization of Altos Hornos de Mexico in November 1991 four areas were chosen to improve blast furnace performance and hot metal costs. These areas included improvement of pellet quality, start of oil-gas co-injection in the blast furnace, improved control of gas flow in the blast furnace and start of monitoring program to predict the remaining life of the hearth of the major blast furnace at AHMSA. The efforts resulted in the following improvements in the first half of 1992: production level increased to 2.4 ton/m[sup 3]/24 hrs; moreover, the annual production record of blast furnace 5 (hearth diameter 11.2 m, 37 ft) set in 1992, was 1.639 mln tonnes; coke rates decreased by 60 kg/tonne, half of which was due to process improvements and the other half to injection of oil; silicon standard deviations decreased from 0.22% in 1991 to 0.20% in 1992; hot metal costs decreased with 10.6%; and the major reline of BF 5 can be postponed by at least 1.5 year.

  20. Recent improvements in blast furnace operation at the Ahmsa Monclova Works

    SciTech Connect

    Morales-Yanez, J.M.; Dominguez-Lara, H.; Geerdes, M. )

    1993-07-01

    Following the privatization of Altos Hornos de Mexico in Nov. 1991, four areas were selected to improve blast furnace performance and hot metal costs. These areas included: improvements of pellet quality; start of oil-gas coinjection; improved control of gas flow in the blast furnace; and start of monitoring program to predict the remaining life of the hearth of the major blast furnace. The efforts resulted in the following improvements in the first half of 1992: (1) Production level increased to 2.4 tonnes/cu meter/24 hr. Annual production record of blast furnace No. 5 (hearth diameter 11.2 meter), set in 1992, was 1,639 million tonnes. (2) Coke rates decreased by 60 kg/tonne, half of which was due to process improvements and the other half to injection of oil. (3) Silicon standard deviations decreased from 0.22% in 1991 to 0.20% in 1992. (4) Hot metal costs decreased by 10.6%. (5) The major reline of blast furnace No. 5 can be postponed by at least 1.5 years.

  1. Blast furnace hearth life: Models for assessing the wear and understanding the transient thermal states

    SciTech Connect

    Leprince, G.; Steiler, J.M.; Sert, D. ); Libralesso, J.M. )

    1993-01-01

    Nowadays, the hearth is the most critical part of the blast furnace when aiming at a long campaign life. Consequently, a better understanding of refractories wear as well as flow mechanisms has become primordial for determining and, if possible, preventing the erosion process. Efforts of measurements have therefore been made during the blast furnace repairs, with the implementation of numerous thermocouples in the carbon bricks. Hence, it becomes possible to monitor and model continuously the internal state of the hearth in accordance with the measured temperature field. Since 1990, different numerical models have been developed and used with two principal aims: - to assess regularly the internal erosion line of the blast furnace hearth all along the campaign life, and - to simulate and if possible, to explain the important transient thermal states observed on some large blast furnaces. This paper describes the content of the two models used nowadays on most of the French blast furnaces and presents the main results obtained in accordance with the industrial variations of temperatures.

  2. Model for Fast Evaluation of Charging Programs in the Blast Furnace

    NASA Astrophysics Data System (ADS)

    Mitra, Tamoghna; Saxén, Henrik

    2014-12-01

    A mathematical model for fast evaluation of charging programs in bell-less top blast furnaces is presented. The model describes the burden formation and descent procedures in the blast furnace, and can be used for designing charging programs. Experimental results in small scale were used to validate the model. The model was applied to a real charging program from a reference blast furnace. Through comparison between the estimated burden distribution and gas temperatures from an above-burden probe it was concluded that the model has captured the main features of the distribution of coke and pellets. The potential of using the model for the design of new charging programs was finally illustrated by analyzing the effect of small changes in the positions of the rings on the arising burden distribution.

  3. Coal combustion under conditions of blast furnace injection. Technical report, March 1, 1994--May 31, 1994

    SciTech Connect

    Crelling, J.C.

    1994-09-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This proposal is a follow-up to one funded for the 1992-93 period. It is intended to complete the study already underway with the Armco Inc. Steel Company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals for such use. During this quarter samples of two feed coals and the IBCSP 112 (Herrin No. 6) were prepared for reactivity testing and compared to blast furnace coke, and char fines taken from an active blast furnace. As the initial part of a broad reactivity analysis program, these same samples were also analyzed on a thermogravimetric analyzer (TGA) to determine their combustion and reactivity properties.

  4. Detection and Quantification of the Dead Man Floating State in the Blast Furnace

    NASA Astrophysics Data System (ADS)

    Brännbacka, Johnny; Saxén, Henrik; Pomeroy, Dave

    2007-06-01

    The lower part, the hearth, is a crucial region of the ironmaking blast furnace. The life length of it often determines the campaign length of the furnace and the thermal state and permeability of the hearth exert strong influence on liquids drainage and hot metal chemistry. In order to operate the furnace efficiently, the hearth state should be controlled, but the conditions in the hearth are extremely hostile with little possibility to carry out direct measurements. This article presents a set of methods and models through which the floating of the hearth coke bed, the dead man, can be assessed. Data from three industrial blast furnaces illustrate how a systematic analysis of available measurements, in combination with results of mathematical models of the phenomena in the hearth, can successfully detect and quantify the dead man floating state.

  5. Clean Coal III Project: Blast Furnace Granular Coal Injection Project Trail 1 Report - Blast Furnace Granular Coal Injection - Results with Low Volatile Coal

    SciTech Connect

    None, None

    1997-11-01

    This report describes the first coal trial test conducted with the Blast Furnace Granular Coal Injection System at Bethlehem Steel Corporation's Burns Harbor Plant. This demonstration project is divided into three phases: Phase I - Design Phase II - Construction Phase III - Operation The design phase was conducted in 1991-1993, Construction of the facility began in August 1993 and was completed in late 1994. The coal injection facility began operating in January 1995 and Phase III began in November 1995. The Trial 1 base test on C furnace was carried out in October 1996 as a comparison period for the analysis of the operation during subsequent coal trials.

  6. Development and application of new techniques for blast furnace process control at SSAB Tunnplaat, Luleaa Works

    SciTech Connect

    Braemming, M.; Hallin, M.; Zuo, G.

    1995-12-01

    SSAB Tunnplaat AB operates two blast furnaces (M1 and M2) in Luleaa. In recent years research efforts have to a great extent been aimed at the development of new techniques for blast furnace process control. An example is the installation of a burden profile measurement system, which was useful in the development of a new burden distribution praxis on the big furnace (M2), equipped with a bell-less-top. Hearth level detection and continuous measurement of the hot metal temperature in the runner are under evaluation. The purpose of these techniques is to give earlier information concerning the state of the blast furnace process. Parallel to this work, models for prediction of silicon in hot metal, the position and shape of the cohesive zone and slip-warning are being developed and tested off-line. These new models and information from new measuring techniques will be integrated into a new Operating Guidance System, hopefully resulting in a powerful tool in the efforts to stabilize blast furnace operations.

  7. Monitoring lining and hearth conditions at Inland`s No. 7 blast furnace

    SciTech Connect

    Quisenberry, P.; Grant, M.; Carter, W.

    1997-12-31

    The paper describes: furnace statistics; mini-reline undertaken in November, 1993; the stack condition; throat gunning; stabilizing the graphite bricks; the hearth condition; reactions to temperature excursions; future instrumentation; and hot blast system areas of concern. The present data from monitoring systems and inspections indicate that the furnace should be able to operate well beyond the expectation for the 1993 mini-reline (3--5 years) with: (1) consistent, high quality raw materials; (2) instrumentation, diagnostic, remedial, and preventative techniques developed; and (3) stopping quickly any water leaks into the furnace. The longevity of this campaign has undoubtedly been a result of this monitoring program.

  8. Calculation and Analysis of Liquid Holdup in Lower Blast Furnace by Model Experiments

    NASA Astrophysics Data System (ADS)

    Xiong, Wei; Bi, Xue-Gong; Wang, Guo-Qiang; Yang, Fu

    2012-06-01

    A hydromechanics experiment on the countercurrent flow of gas and liquid simulating the flow conditions in the lower blast furnace was carried out. A cold model of a packed bed with various packing materials and liquids was used to study the holdup of liquid. Correlations for static holdup, dynamic holdup, and total holdup were obtained. A good agreement was found between the calculated and experimental data. A mathematical model simulating the flow fields was applied to study the effect of liquid holdup in blast furnace. The results of the model calculation show that static holdup is the determinant of the total holdup of molten materials when the blast furnace works in stable condition. The slag phase generally reaches flooding holdup ahead of the hot metal. The radial distribution of gas flow is almost not influenced by the holdup of molten materials, but it has a greater influence on the pressure drop. The size of coke has far greater influence on static holdup than liquid properties does. The study is useful for acquiring a deeper understanding of the complex phenomena in the blast furnace and for determining appropriate operational actions under different production conditions.

  9. AIR POLLUTION IMPACTS WHEN QUENCHING BLAST FURNACE SLAG WITH CONTAMINATED WATER

    EPA Science Inventory

    The report gives results of an effort to determine if a potential alternative to treatment prior to discharge of coke plant wastewater will result in a significant increase in emissions to the atmosphere. The alternative is using the wastewater, untreated, to quench blast furnace...

  10. Blast Furnace Granulated Coal Injection System Demonstration Project public design report. Topical report

    SciTech Connect

    1995-03-01

    The public design report describes the Blast Furnace Granulated Coal Injection (BFGCI) project under construction at Bethlehem Steel Corporation`s (BSC) Burns Harbor, Indiana, plant. The project is receiving cost-sharing from the U.S. Department of Energy (DOE), and is being administrated by the Morgantown Energy Technology Center in accordance with the DOE Cooperative Agreement No. DE-FC21-91MC27362. The project is the first installation in the United States for the British Steel technology using granular coal in blast furnaces. The objective is to demonstrate that granular coal is an economic and reliable fuel which can successfully be applied to large North American blast furnaces. These include: coal grind size, coal injection rate, coal source (type) and blast furnace conversion method. To achieve the program objectives, the demonstration project is divided into the following three Phases: Phase I-Design; Phase II-Procurement & Construction; and Phase III-Operation. Preliminary design (Phase I) began in 1991 with detailed design commencing in April 1993. Construction at Burns Harbor (Phase II) began August 1993. Construction is expected to be complete in the first quarter of 1995 which will be followed by a demonstration test program (Phase III).

  11. Graphitization of Coke and Its Interaction with Slag in the Hearth of a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Li, Kejiang; Zhang, Jianliang; Liu, Yanxiang; Barati, Mansoor; Liu, Zhengjian; Zhong, Jianbo; Su, Buxin; Wei, Mengfang; Wang, Guangwei; Yang, Tianjun

    2016-04-01

    Coke reaction behavior in the blast furnace hearth has yet to be fully understood due to limited access to the high temperature zone. The graphitization of coke and its interaction with slag in the hearth of blast furnace were investigated with samples obtained from the center of the deadman of a blast furnace during its overhaul period. All hearth coke samples from fines to lumps were confirmed to be highly graphitized, and the graphitization of coke in the high temperature zone was convinced to start from the coke surface and lead to the formation of coke fines. It will be essential to perform further comprehensive investigations on graphite formation and its evolution in a coke as well as its multi-effect on blast furnace performance. The porous hearth cokes were found to be filled up with final slag. Further research is required about the capability of coke to fill final slag and the attack of final slag on the hearth bottom refractories since this might be a new degradation mechanism of refractories located in the hearth bottom.

  12. Study on blast furnace cooling stave for various refractory linings based on numerical modeling

    NASA Astrophysics Data System (ADS)

    Mohanty, T. R.; Sahoo, S. K.; Moharana, M. K.

    2016-02-01

    Cooling technology for refractory lining of blast furnace is very important for the metallurgical industry, because it can substantially increase output and operation life of furnaces. A three dimensional mathematical model for the temperature field of the blast furnace stave cooler with refractory lining has been developed and analyzed. The temperature and heat dissipated by stave cooler is examined by using the finite element method. The cast steel stave is studied and computational analysis is made to know the effect of the cooling water velocity, temperature, and the lining material on the maximum temperature of the stave hot surface. The refractory lining materials, which are used in this experiment, are high alumina bricks with different stave materials (copper, aluminum and cast iron). The obtained numerical calculations are compared with that obtained from experiments performed at Rourkela Steel Plant, Odisha taking a stave in belly zone having maximum heat load shows very good agreement.

  13. Operational results of shaft repair by installing stave type cooler at Kimitsu Nos. 3 and 4 blast furnaces

    SciTech Connect

    Oda, Hiroshi; Amano, Shigeru; Sakamoto, Aiichiro; Anzai, Osamu; Nakagome, Michiru; Kuze, Toshisuke; Imuta, Akira

    1997-12-31

    Nos. 3 and 4 blast furnaces in Nippon Steel Corporation Kimitsu Works were both initially fitted with cooling plate systems. With the aging of each furnace, the damage to their respective inner-shaft profiles had become serious. Thus, in order to prevent operational change and prolong the furnace life, the inner-shaft profile of each furnace was repaired by replacing the former cooling plate system with the stave type cooler during the two-week-shutdowns. With this repair, stability of burden descent and gas flow near the wall part of the furnace have been achieved. Thus the prolongation of the furnace life is naturally expected.

  14. Using coal-dust fuel in Ukrainian and Russian blast furnaces

    SciTech Connect

    A.A. Minaev; A.N. Ryzhenkov; Y.G. Banninkov; S.L. Yaroshevskii; Y.V. Konovalov; A.V. Kuzin

    2008-02-15

    Ukrainian and Russian blast-furnace production falls short of the best global practices. It is no secret that, having switched to oxygen and natural gas in the 1960s, the blast-furnace industries have improved the batch and technological conditions and have attained a productivity of 2.5 and even 3 t/(m{sup 3} day), but have not been able to reduce coke consumption below 400 kg/t, which was the industry standard 40 years ago. The situation is particularly bad in Ukraine: in 2007, furnace productivity was 1.5-2 t/m{sup 3}, with a coke consumption of 432-530 kg/t. Theoretical considerations and industrial experience over the last 20 years show that the large-scale introduction of pulverized fuel, with simultaneous improvement in coke quality and in batch and technological conditions, is the only immediately available means of reducing coke consumption considerably (by 20-40%). By this means, natural-gas consumption is reduced or eliminated, and the efficiency of blast-furnace production and ferrous metallurgy as a whole is increased.

  15. The Iron Blast Furnace: A Study in Chemical Thermodynamics.

    ERIC Educational Resources Information Center

    Treptow, Richard S.; Jean, Luckner

    1998-01-01

    Discusses the furnace from a chemical thermodynamics perspective. Examines the enthalpy, entropy, and free energy change for each reaction of importance. These properties are interpreted on the molecular level then used to deduce the conditions necessary for each reaction to occur in its intended direction. Chemical kinetics is also discussed.…

  16. Mechanism Research on Melting Loss of Coppery Tuyere Small Sleeve in Blast Furnace

    NASA Astrophysics Data System (ADS)

    Chai, Yi-Fan; Zhang, Jian-Liang; Ning, Xiao-Jun; Wei, Guang-Yun; Chen, Yu-Ting

    2016-01-01

    The tuyere small sleeve in blast furnace works under poor conditions. The abnormal damage of it will severely affect the performance of the blast furnace, thus it should be replaced during the damping down period. So it is of great significance that we study and reduce the burnout of tuyere small sleeve. Melting loss is one case of its burnout. This paper studied the reasons of tuyere small sleeve's melting loss, through computational simulation and microscopic analysis of the melting section. The research shows that the temperature of coppery tuyere small sleeve is well distributed when there is no limescale in the lumen, and the temperature increases with the thickness of limescale. In addition, the interruption of circulating water does great harm to the tuyere small sleeve. The melting loss of tuyere small sleeve is caused by iron-slag erosion, with the occurrence of the melt metallurgical bonding and diffusion metallurgical combination.

  17. Extracting the core indicators of pulverized coal for blast furnace injection based on principal component analysis

    NASA Astrophysics Data System (ADS)

    Guo, Hong-wei; Su, Bu-xin; Zhang, Jian-liang; Zhu, Meng-yi; Chang, Jian

    2013-03-01

    An updated approach to refining the core indicators of pulverized coal used for blast furnace injection based on principal component analysis is proposed in view of the disadvantages of the existing performance indicator system of pulverized coal used in blast furnaces. This presented method takes into account all the performance indicators of pulverized coal injection, including calorific value, igniting point, combustibility, reactivity, flowability, grindability, etc. Four core indicators of pulverized coal injection are selected and studied by using principal component analysis, namely, comprehensive combustibility, comprehensive reactivity, comprehensive flowability, and comprehensive grindability. The newly established core index system is not only beneficial to narrowing down current evaluation indices but also effective to avoid previous overlapping problems among indicators by mutually independent index design. Furthermore, a comprehensive property indicator is introduced on the basis of the four core indicators, and the injection properties of pulverized coal can be overall evaluated.

  18. AISI/DOE Technology Roadmap Program Hot Oxygen Injection Into The Blast Furnace

    SciTech Connect

    Michael F. Riley

    2002-10-21

    Increased levels of blast furnace coal injection are needed to further lower coke requirements and provide more flexibility in furnace productivity. The direct injection of high temperature oxygen with coal in the blast furnace blowpipe and tuyere offers better coal dispersion at high local oxygen concentrations, optimizing the use of oxygen in the blast furnace. Based on pilot scale tests, coal injection can be increased by 75 pounds per ton of hot metal (lb/thm), yielding net savings of $0.84/tm. Potential productivity increases of 15 percent would yield another $1.95/thm. In this project, commercial-scale hot oxygen injection from a ''thermal nozzle'' system, patented by Praxair, Inc., has been developed, integrated into, and demonstrated on two tuyeres of the U.S. Steel Gary Works no. 6 blast furnace. The goals were to evaluate heat load on furnace components from hot oxygen injection, demonstrate a safe and reliable lance and flow control design, and qualitatively observe hot oxygen-coal interaction. All three goals have been successfully met. Heat load on the blowpipe is essentially unchanged with hot oxygen. Total heat load on the tuyere increases about 10% and heat load on the tuyere tip increases about 50%. Bosh temperatures remained within the usual operating range. Performance in all these areas is acceptable. Lance performance was improved during testing by changes to lance materials and operating practices. The lance fuel tip was changed from copper to a nickel alloy to eliminate oxidation problems that severely limited tip life. Ignition flow rates and oxygen-fuel ratios were changed to counter the effects of blowpipe pressure fluctuations caused by natural resonance and by coal/coke combustion in the tuyere and raceway. Lances can now be reliably ignited using the hot blast as the ignition source. Blowpipe pressures were analyzed to evaluate ht oxygen-coal interactions. The data suggest that hot oxygen increases coal combustion in the blow pipe and

  19. POLLUTION EFFECTS OF ABNORMAL OPERATIONS IN IRON AND STEEL MAKING. VOLUME III. BLAST FURNACE IRONMAKING, MANUAL OF PRACTICE

    EPA Science Inventory

    The report is one in a six-volume series considering abnormal operating conditions (AOCs) in the primary section (sintering, blast furnace ironmaking, open hearth, electric furnace, and basic oxygen steelmaking) of an integrated iron and steel plant. Pollution standards, generall...

  20. Desulphurization and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge

    SciTech Connect

    Li, S.L.; Feng, Q.B.; Li, L.; Xie, C.L.; Zhen, L.P.

    2009-03-15

    Laboratory tests were conducted for removal of SO{sub 2} from simulated flue gas and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge. Tests were conducted for the flue gas flow from 12 to 18 Nm{sup 3}/h, the simulated gas temperature from 80 to 120 {sup o}C, the inlet flux of wastewater from 33 to 57 L/h, applied voltage from 0 to 27 kV, and SO{sub 2} initial concentration was about 1,430 mg/m{sup 3}. Results showed that wastewater from blast furnace has an excellent ability of desulphurization (about 90%) and pulsed corona discharge can enhance the desulphurization efficiency. Meanwhile, it was observed that the SO{sub 2} removal ratio decreased along with increased cycle index, while it increased as the flux of flue gas was reduced, and increased when the flux of wastewater from blast furnace was increased. In addition, results demonstrated that the content of sulfate radical produced in wastewater increase with an increment of applied pulsed voltage, cycle index, or the flux of flue gas. Furthermore, the results indicated that the higher the inlet content of cyanide the better removal effect of it, and the removal rate can reach 99.9% with a residence time of 2.1 s in the pulsed corona zone during the desulphurization process when the inlet content was higher, whereas there was almost no removal effect when the inlet content was lower. This research may attain the objective of waste control, and can provide a new way to remove SO{sub 2} from flue gas and simultaneously degrade wastewater from blast furnace for integrated steel plants.

  1. Hydrolyzed Portland cement clinker and air-cooled blast furnace slag SO{sub 2} sorbents

    SciTech Connect

    Hays, M.D.; Kenney, M.E.

    1999-07-01

    The preparation, morphologies, densities, mean particle sizes, surface areas, compositions, SO{sub 2}-uptakes, calcium utilizations and 100% SO{sub 2} capture times of SO{sub 2} flue gas sorbents derived by the hydrolysis of cement clinker and of air-cooled blast furnace slag are described and discussed. The hydrolyzed clinker sorbent is highly effective. While it is less effective, the slag sorbent, because it is so much cheaper, is the more attractive of the two.

  2. Strength and pore structure of ternary blended cement mortars containing blast furnace slag and silica fume

    SciTech Connect

    Bagel, L.

    1998-07-01

    Blended cement mortars with fixed workability and incorporating blast furnace slag and silica fume, were tested for compressive strength and mercury intrusion, with a view to comparing their performance with that of plain Portland cement mortar and/or slag-cement mortar. The obtained results showed that with high portions of slag and silica fume in the binding system, the mortars reached relatively satisfactory level of compressive strength and contributed to the significantly denser pore structure.

  3. Blast furnace granular coal injection project. Annual report, January--December 1994

    SciTech Connect

    1995-07-01

    This annual report describes the Blast Furnace Granular Coal Injection project being implemented at Bethlehem Steel Corporation`s (BSC) Burns Harbor Plant. The project is receiving cost-sharing from the US Department of Energy (DOE), and is being administrated by the Morgantown Energy Technology Center in accordance with the DOE Cooperative Agreement No. DE-FC21-91MC27362. This installation is the first in the United States to employ British Steel technology that uses granular coal to provide part of the fuel requirement of blast furnaces. The project will demonstrate/assess a broad range of technical/economic issues associated with the use of coal for this purpose. These include: coal grind size, coal injection rate, coal source (type) and blast furnace conversion method. To achieve the program objectives, the demonstration project is divided into the following three Phases: Phase I -- design; Phase II -- construction; and Phase III -- operation. Preliminary design (Phase I) began in 1991 with detailed design commencing in 1993. Construction at Burns Harbor (Phase II) began in August 1993 and was completed at the end of 1994. A 100% construction review meeting was held in December and attended by representatives of DOE, Fluor Daniel and Bethlehem Steel. The coal preparation mills were started up in December, 1994, and the first coal was injected into ``D`` blast furnace on December 19, 1994. Near the end of the year, the grinding mills and injection facility were being prepared for performance testing during the first quarter of 1995. The demonstration test program (phase III) will start in the fourth quarter of 1995.

  4. Pilot plant testing of Illinois coal for blast furnace injection. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect

    Crelling, J.C.

    1995-12-31

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of Illinois coal in the blast furnace injection process in a new and unique pilot plant test facility. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it is the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1993--94 period. It is intended to complete the study already underway with the Armco and Inland steel companies and to demonstrate quantitatively the suitability of both the Herrin No. 6 and Springfield No. 5 coals for blast furnace injection. The main feature of the current work is the testing of Illinois coals at CANMET`s (Canadian Centre for Mineral and Energy Technology) pilot plant coal combustion facility. This facility simulates blowpipe-tuyere conditions in an operating blast furnace, including blast temperature (900{degrees}C), flow pattern (hot velocity 200 m/s), geometry, gas composition, coal injection velocity (34 m/s) and residence time (20 ms). The facility is fully instrumented to measure air flow rate, air temperature, temperature in the reactor, wall temperature, preheater coil temperature and flue gas analysis. During this quarter there were two major accomplishments.

  5. Use of high-performance instrumentation in blast furnace computer monitoring

    SciTech Connect

    Lueckers, J.; Ramelot, D.; Desplanques, C.; Dodet, C. )

    1993-01-01

    Computerized monitoring and control systems are part of the tools commonly in use to improve the stability of the blast furnace operation and to minimize the hot metal cost. The rapidly increasing power of these systems is used to execute growing numbers of specific monitoring and management tasks. More and more sophisticated mathematical models that better describe the complexity of the phenomena involved in the blast furnace process are being run on-line. This evolution, has two very practical consequences: (1) improved software tools are required to ease the use of all the models and functions implemented in the computer systems. In particular, the massive amount of data available has to be converted into a practical diagnostic tool for the operator. Expert systems recently have been shown to provide the basis for a solution to this problem. (2) more and better instrumentation has to be implemented in order to supply the data required by the models. The integrity of these data is a major issue. As the sensors have to operate under extreme hostile environmental conditions, their performances have to be closely monitored. The only practical solution to this problem is a computer monitoring with automatic drift and failure diagnostics (maintenance assistant). Extensive research and development efforts have resulted in instrumentation systems and software tools that are well adapted to the assessment of the measurement quality and are currently in commercial operation on several blast furnaces around the world.

  6. Investigation on Carbon-Deposition Behavior from Heating Cycle Gas in Oxygen Blast Furnace Process

    NASA Astrophysics Data System (ADS)

    Liu, Jinzhou; Wang, Jingsong; She, Xuefeng; Zhang, Shiyang; Xue, Qingguo

    2015-02-01

    Among the different ways to study carbon deposition in the ironmaking process, not much attention was paid to that of heating the gas mixture, especially cycle gas in an oxygen blast furnace. In this work, the carbon-deposition characteristics of heating 100 pct CO, CO-H2 gas mixture, and cycle gas in the oxygen blast furnace process were, respectively, experimentally and theoretically investigated. First, the thermodynamics on carbon-deposition reactions were calculated. Then, the impacts of discharging operation temperature, the proportion of CO/H2 in heating the CO-H2 gas mixture, and the CO2 concentration in heating the cycle gas of an oxygen blast furnace on the carbon deposition were tested and investigated. Furthermore, the carbon-deposition behaviors in heating the CO-H2 gas mixture were compared with the thermodynamic calculation results for discussing the role of H2. In addition, carbon deposition in heating cycle gas includes CO decomposition and a carbon-deposition reaction by hybrid of CO and H2; the possible roles of each were analyzed by comparing thermodynamic calculation and experimental results. The deposited carbon was characterized by scanning electron microscope (SEM) to analyze the deposited carbon microstructure.

  7. Interfaces Between Coke, Slag, and Metal in the Tuyere Level of a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Li, Kejiang; Zhang, Jianliang; Liu, Zhengjian; Barati, Mansoor; Zhong, Jianbo; Wei, Mengfang; Wang, Guangwei; Jiao, Kexin; Yang, Tianjun

    2015-04-01

    An in-depth understanding about the reactions in the high-temperature zone of a blast furnace is significant to optimize both the current and future blast furnace process. The interfaces between coke, slag, and metal were observed using scanning electronic microscope with samples obtained from the tuyere level of a blast furnace. Two types of slag phases were identified, one originating from coke ash and the other from the bosh slag. Slag formed by coke ash was seen to cover the coke surface, which may hinder the reaction of coke with both gas and liquid iron. The reduction of FeO from the bosh slag (originated from the primary slag) occurs in the coke/slag interface with the reduced iron forming a metal layer surrounding the coke surface. The reduction of SiO2 occurs both in and outside the coke, and the reduced silicon reacts with iron to form iron silicide if the two species come into contact. Further study is proposed based on the results of this study.

  8. Probing the inner structure of blast furnaces by cosmic-ray muon radiography

    NASA Astrophysics Data System (ADS)

    Nagamine, K.; Tanaka, H. K. M.; Nakamura, S. N.; Ishida, K.; Hashimoto, M.; Shinotake, A.; Naito, M.; Hatanaka, A.

    By using the detection system of the near-horizontal cosmic-ray radiography originally developed for probing inner structure of volcanic mountains, a measurement was conducted to probe the inner structure and its time-dependent change of the blast furnace for iron-making. Precise determination (+/-5 cm) of the thickness of brick used for both base-plate and side-wall was made in 45 days; a crucial information to predict a life-time of the furnace. Also, the local density of iron-rich part was determined in +/-0.2 g/cm2 in 45 days; static structure as well as time-dependent behavior can be monitored for the iron-rich part of the furnace during operation.

  9. Variation in coke properties within the blast-furnace shop

    SciTech Connect

    E.N. Stepanov; I.I. Mel'nikov; V.P. Gridasov; A.A. Stepanova

    2009-04-15

    In active production at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), samples of melt materials were taken during shutdown and during planned repairs at furnaces 1 and 8. In particular, coke was taken from the tuyere zone at different distances from the tuyere tip. The mass of the point samples was 2-15 kg, depending on the sampling zone. The material extracted from each zone underwent magnetic separation and screening by size class. The resulting coke sample was averaged out and divided into parts: one for determining the granulometric composition and mechanical strength; and the other for technical analysis and determination of the physicochemical properties of the coke.

  10. Coal combustion under conditions of blast furnace injection. [Quarterly] technical report, 1 March 1993--31 May 1993

    SciTech Connect

    Crelling, J.C.; Case, E.R.

    1993-09-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. The basic program is designed to determine the reactivity of both coal and its derived char under blast furnace conditions and to compare the results to similar properties of blast furnace coke. The results of the first two experiments in which coal char pyrolyzed in nitrogen at 1000{degrees}C in an EPR were reacted isothermally in air at 1000{degrees}C and 1200{degrees}C. The reactivity values of the same char in these two experiments were different by an order of magnitude. The char reactivity at 1000{degrees}C was 9.7 {times} 10{sup {minus}4} grams per minute while the reactivity. of the char at 1200{degrees}C was 1.6 {times} 10{sup {minus}3} grams per minute. These results suggest that the temperature of the blast air in the tuyere may be critical in achieving complete carbon burnout.

  11. Coal combustion under conditions of blast furnace injection. Technical report, 1 December 1992--28 February 1993

    SciTech Connect

    Crelling, J.C.; Case, E.R.

    1993-05-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This proposed study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. The Amanda furnace of Armco is the only one in North America currently using coal injection and is, therefore, the only full scale testing facility available. During this quarter complete petrographic analyses of all of the samples so far collected were completed.

  12. Production and blast-furnace smelting of boron-alloyed iron-ore pellets

    SciTech Connect

    A.A. Akberdin; A.S. Kim

    2008-08-15

    Industrial test data are presented regarding the production (at Sokolovsk-Sarbaisk mining and enrichment enterprise) and blast-furnace smelting (at Magnitogorsk metallurgical works) of boron-alloyed iron-ore pellets (500000 t). It is shown that, thanks to the presence of boron, the compressive strength of the roasted pellets is increased by 18.5%, while the strength in reduction is doubled; the limestone consumption is reduced by 11%, the bentonite consumption is halved, and the dust content of the gases in the last section of the roasting machines is reduced by 20%. In blast-furnace smelting, the yield of low-sulfur (<0.02%) hot metal is increased from 65-70 to 85.1% and the furnace productivity from 2.17-2.20 to 2.27 t/(m{sup 3} day); coke consumption is reduced by 3-8 kg/t of hot metal. The plasticity and stamping properties of 08IO auto-industry steel are improved by microadditions of boron.

  13. Pilot plant testing of Illinois coal for blast furnace injection. Technical report, September 1--November 30, 1994

    SciTech Connect

    Crelling, J.C.

    1994-12-31

    The purpose of this study is to evaluate the combustion of Illinois coal in the blast furnace injection process in a new and unique pilot plant test facility. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it is the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. It is intended to complete the study already underway with the Armco and Inland steel companies and to demonstrate quantitatively the suitability of both the Herrin No. 6 and Springfield No. 5 coals for blast furnace injection. The main feature of the current work is the testing of Illinois coals at CANMET`s (Canadian Centre for Mineral and Energy Technology) pilot plant coal combustion facility. This facility simulates blowpipe-tuyere conditions in an operating blast furnace, including blast temperature (900 C), flow pattern (hot velocity 200 m/s), geometry, gas composition, coal injection velocity (34 m/s) and residence time (20 ms). The facility is fully instrumented to measure air flow rate, air temperature, temperature in the reactor, wall temperature, preheater coil temperature and flue gas analysis. During this quarter a sample of the Herrin No. 6 coal (IBCSP 112) was delivered to the CANMET facility and testing is scheduled for the week of 11 December 1994. Also at this time, all of the IBCSP samples are being evaluated for blast furnace injection using the CANMET computer model.

  14. Woodburning stove

    SciTech Connect

    Hawkins, B.C.; Mckay, J.

    1981-11-17

    A woodburning stove is described having an inner housing and an outer housing spaced therefrom providing air passages therebetween. A blower circulates air through the air passages for absorbing heat from the walls of the housing and exhausting the heated air into the room where the stove is located. A substantially horizontal plate is spaced below the top wall of the inner housing defining an afterburner space. A duct extends between the passages extending between the two housings and the afterburner space. The duct is provided with a valve so that fresh air can be controllably applied to the afterburner space for causing combustion of gases flowing through the afterburner space. A fresh air duct extends along the side of the stove and connects with the blower for supplying fresh air from the front of the stove to the blower.

  15. Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace

    SciTech Connect

    Dr. Chenn Zhou

    2008-10-15

    Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

  16. Novel Recognition Method of Blast Furnace Dust Composition by Multifeature Analysis Based on Comprehensive Image-Processing Techniques

    NASA Astrophysics Data System (ADS)

    Guo, Hongwei; Su, Buxin; Bai, Zhenlong; Zhang, Jianliang; Li, Xinyu

    2014-11-01

    The traditional artificial recognition methods for the blast furnace dust composition have several disadvantages, including a great deal of information to dispose, complex operation, and low working efficiency. In this article, a multifeature analysis method based on comprehensive image-processing techniques was proposed to automatically recognize the blast furnace dust composition. First, the artificial recognition and feature analysis, which included image preprocessing, Harris corner feature, Canny edge feature, and Ruffle feature analysis, was designed to build the template image, so that any unknown dust digital image could be tested. Second, the composition of coke, microvariation pulverized coal, vitric, ash, and iron from dust would be distinguished according to their different range of values based on the multifeature analysis. The method is valid for recognizing the blast furnace dust composition automatically, and it is fast and has a high recognition accuracy.

  17. Novel Recognition Method of Blast Furnace Dust Composition by Multifeature Analysis Based on Comprehensive Image-Processing Techniques

    NASA Astrophysics Data System (ADS)

    Guo, Hongwei; Su, Buxin; Bai, Zhenlong; Zhang, Jianliang; Li, Xinyu

    2014-09-01

    The traditional artificial recognition methods for the blast furnace dust composition have several disadvantages, including a great deal of information to dispose, complex operation, and low working efficiency. In this article, a multifeature analysis method based on comprehensive image-processing techniques was proposed to automatically recognize the blast furnace dust composition. First, the artificial recognition and feature analysis, which included image preprocessing, Harris corner feature, Canny edge feature, and Ruffle feature analysis, was designed to build the template image, so that any unknown dust digital image could be tested. Second, the composition of coke, microvariation pulverized coal, vitric, ash, and iron from dust would be distinguished according to their different range of values based on the multifeature analysis. The method is valid for recognizing the blast furnace dust composition automatically, and it is fast and has a high recognition accuracy.

  18. Effects of Carbo-Nitridation Process of Ti-Bearing Blast Furnace Slag on Iron Content

    NASA Astrophysics Data System (ADS)

    Shi, Z.; Zhang, X. M.; Xu, Y.

    In order to prepare corrosion-resistant refractory material, experiment chooses Ti-bearing Blast Furnace Slag as raw materials which were treated by the method of carbo-nitridation. Finally, the corrosion resistance properties of the material can be improved by this method. The carbo-nitridation process affects the iron content of the slag in the study, which have a beneficial effect on the synthesis of Ti (C. N). The results indicated that the iron content of the slag significantly increased in process of Ti (C. N) synthesis: and the iron content of slag showed an upward trend with the increase of holding time.

  19. Study on the early warning mechanism for the security of blast furnace hearths

    NASA Astrophysics Data System (ADS)

    Zhao, Hong-bo; Huo, Shou-feng; Cheng, Shu-sen

    2013-04-01

    The campaign life of blast furnace (BF) hearths has become the limiting factor for safety and high efficiency production of modern BFs. However, the early warning mechanism of hearth security has not been clear. In this article, based on heat transfer calculations, heat flux and erosion monitoring, the features of heat flux and erosion were analyzed and compared among different types of hearths. The primary detecting elements, mathematical models, evaluating standards, and warning methods were discussed. A novel early warning mechanism with the three-level quantificational standards was proposed for BF hearth security.

  20. Dofasco`s No. 4 blast furnace hearth breakout, repair and rescue

    SciTech Connect

    Donaldson, R.J.; Fischer, A.J.; Sharp, R.M.; Stothart, D.W.

    1995-12-01

    On May 5, 1994, after producing 9.5 million metric tons of iron, Dofasco`s No. 4 Blast Furnace experienced a hearth breakout 250 millimeters below the west taphole. The hot metal spill caused a fire resulting in severe damage and 33 days of lost production. During a 26-day period, electrical wiring, water drainage systems and both tapholes were repaired. Recovery from an unprepared furnace stop of this length, with the deadman depleted is difficult. To aid with the rescue Hoogovens-designed oxygen/fuel lances were commissioned. The furnace recovery began with a lance in each taphole and all tuyeres plugged. Six days after startup the furnace was casting into torpedo cars, and after nine days operation had returned to normal. This incident prompted Dofasco to expand the hearth monitoring system to detect and prevent similar occurrences. During the repair, 203 new thermocouples were installed in the hearth, concentrating on the tapholes and elephant foot areas. These thermocouples were installed at various depths and locations to allow heat flux calculations. This hearth monitoring system has already identified other problem areas and provided valuable information about hearth drainage patterns. This information has allowed them to develop control strategies to manage localized problem areas.

  1. Modeling of Internal State and Performance of an Ironmaking Blast Furnace: Slot vs Sector Geometries

    NASA Astrophysics Data System (ADS)

    Shen, Yansong; Guo, Baoyu; Chew, Sheng; Austin, Peter; Yu, Aibing

    2016-04-01

    Mathematical modeling is a cost-effective method to understand internal state and predict performance of ironmaking blast furnace (BF) for improving productivity and maintaining stability. In the past studies, both slot and sector geometries were used for BF modeling. In this paper, a mathematical model is described for simulating the complex behaviors of solid, gas and liquid multiphase flow, heat and mass transfers, and chemical reactions in a BF. Then the model is used to compare different model configurations, viz. slot and sector geometries by investigating their effects on predicted behaviors, in terms of two aspects: (i) internal state including cohesive zone, velocity, temperature, components concentration, reduction degree, gas utilization, and (ii) performance indicators including liquid output at the bottom and gas utilization rate at the furnace top. The comparisons show that on one hand, predictions of internal state of the furnace such as fluid flow and thermo-chemical phenomena using the slot and sector geometries are qualitatively comparable but quantitatively different. Both sector and slot geometries give a similar cohesive zone shape but the sector geometry gives a higher cohesive zone near the wall and faster reduction. On the other hand, the two geometries can produce similar performance indicators including gas utilization at the furnace top and liquid output at the bottom. Such a study is useful in selecting geometry for numerically examining BF operation with respect to different needs.

  2. A new direct steel making process based upon the blast furnace (Including scrap processing with recovery of tramp elements)

    SciTech Connect

    Nabi, G.

    1996-12-31

    Steel is produced from raw materials containing iron and alloying elements with direct elimination of oxygen and impurities in the blast furnace process. The blast furnace shaft is modified to take off load from the liquid bath and carbon is prevented from going into the liquid steel. In the gas purification system sulphur and CO{sub 2} removal facilities are included and purified reducing gases so obtained are combusted in the hearth with oxygen to produce heat for smelting. Scrap can be charged as raw material with the recovery of tramp elements with continuous production of liquid steel.

  3. Process Simulation and Control Optimization of a Blast Furnace Using Classical Thermodynamics Combined to a Direct Search Algorithm

    NASA Astrophysics Data System (ADS)

    Harvey, Jean-Philippe; Gheribi, Aïmen E.

    2013-12-01

    Several numerical approaches have been proposed in the literature to simulate the behavior of modern blast furnaces: finite volume methods, data-mining models, heat and mass balance models, and classical thermodynamic simulations. Despite this, there is actually no efficient method for evaluating quickly optimal operating parameters of a blast furnace as a function of the iron ore composition, which takes into account all potential chemical reactions that could occur in the system. In the current study, we propose a global simulation strategy of a blast furnace, the 5-unit process simulation. It is based on classical thermodynamic calculations coupled to a direct search algorithm to optimize process parameters. These parameters include the minimum required metallurgical coke consumption as well as the optimal blast chemical composition and the total charge that simultaneously satisfy the overall heat and mass balances of the system. Moreover, a Gibbs free energy function for metallurgical coke is parameterized in the current study and used to fine-tune the simulation of the blast furnace. Optimal operating conditions and predicted output stream properties calculated by the proposed thermodynamic simulation strategy are compared with reference data found in the literature and have proven the validity and high precision of this simulation.

  4. Volatilization of elemental mercury from fresh blast furnace sludge mixed with basic oxygen furnace sludge under different temperatures.

    PubMed

    Földi, Corinna; Dohrmann, Reiner; Mansfeldt, Tim

    2015-11-01

    Blast furnace sludge (BFS) is a waste with elevated mercury (Hg) content due to enrichment during the production process of pig iron. To investigate the volatilization potential of Hg, fresh samples of BFS mixed with basic oxygen furnace sludge (BOFS; a residue of gas purification from steel making, processed simultaneously in the cleaning devices of BFS and hence mixed with BFS) were studied in sealed column experiments at different temperatures (15, 25, and 35 °C) for four weeks (total Hg: 0.178 mg kg(-1)). The systems were regularly flushed with ambient air (every 24 h for the first 100 h, followed by every 72 h) for 20 min at a flow rate of 0.25 ± 0.03 L min(-1) and elemental Hg vapor was trapped on gold coated sand. Volatilization was 0.276 ± 0.065 ng (x m: 0.284 ng) at 15 °C, 5.55 ± 2.83 ng (x m: 5.09 ng) at 25 °C, and 2.37 ± 0.514 ng (x m: 2.34 ng) at 35 °C. Surprisingly, Hg fluxes were lower at 35 than 25 °C. For all temperature variants, an elevated Hg flux was observed within the first 100 h followed by a decrease of volatilization thereafter. However, the background level of ambient air was not achieved at the end of the experiments indicating that BFS mixed with BOFS still possessed Hg volatilization potential. PMID:26444147

  5. Mass and elemental distributions of atmospheric particles nearby blast furnace and electric arc furnace operated industrial areas in Australia.

    PubMed

    Mohiuddin, Kazi; Strezov, Vladimir; Nelson, Peter F; Stelcer, Eduard; Evans, Tim

    2014-07-15

    The improved understanding of mass and elemental distributions of industrial air particles is important due to their heterogeneous atmospheric behaviour and impact on human health and the environment. In this study, particles of different size ranges were collected from three sites in Australia located in the vicinity of iron and steelmaking industries and one urban background site with very little industrial influence. In order to determine the importance of the type of industrial activity on the urban atmospheric quality, the industrial sites selected in this study were in the close proximity to two blast furnace operated and one electric arc furnace based steelmaking sites. The chemical compositions of the collected air particles were analysed using the proton induced X-ray emission (PIXE) technique. This study revealed significantly higher metal concentrations in the atmospheric particles collected in the industrial sites, comparing to the background urban site, demonstrating local influence of the industrial activities to the air quality. The modality types of the particles were found to be variable between the mass and elements, and among elements in the urban and industrial areas indicating that the elemental modal distribution is as important as particle mass for particle pollution modelling. The highest elemental number distribution at all studied sites occurred with particle size of 0.1 μm. Iron was found as the main dominant metal at the industrial atmosphere in each particle size range. The industrial Fe fraction in the submicron and ultrafine size particles was estimated at up to 95% which may be released from high temperature industrial activities with the iron and steelmaking industries being one of the major contributors. Hence, these industrial elemental loadings can highly influence the atmospheric pollution at local urban and regional levels and are required to consider in the atmospheric modelling settings. PMID:24793329

  6. Numerical analysis for the multi-phase flow of pulverized coal injection inside blast furnace tuyere

    SciTech Connect

    Chen, C.W.

    2005-09-01

    The pulverized coal injection (PCI) system was modified from single lance injection into double lance injection at No. 3 Blast Furnace of CSC. It is beneficial to reduce the cost of coke. However, the injected coal was found very close to the inner wall of the tuyere during the operation, such as to cause the possibility of erosion for the tuyere. In this study a three-dimensional mathematical model has been developed based on a computational fluid dynamics software PHOENICS to simulate the fluid flow phenomena inside blast furnace tuyere. The model was capable of handling steady-state, three-dimensional multi-phase flow of pulverized coal injection. The model was applied to simulate the flow patterns of the injection coal inside the tuyere with two kinds of lance design for the PCI system. The distribution of injection coal was simulated such as to estimate the possibility of erosion for the tuyere. The calculated results agreed with the operating experience of CSC plant and the optimum design of double lance was suggested. The model was also applied to simulate the oxygen concentration distribution with these different oxygen enrichments for the coal/oxygen lance system. The calculated results agreed with the experimental measurement. These test results demonstrate that the model is both reasonably reliable and efficient.

  7. Improved CFD Model to Predict Flow and Temperature Distributions in a Blast Furnace Hearth

    NASA Astrophysics Data System (ADS)

    Komiyama, Keisuke M.; Guo, Bao-Yu; Zughbi, Habib; Zulli, Paul; Yu, Ai-Bing

    2014-10-01

    The campaign life of a blast furnace is limited by the erosion of hearth refractories. Flow and temperature distributions of the liquid iron have a significant influence on the erosion mechanism. In this work, an improved three-dimensional computational fluid dynamics model is developed to simulate the flow and heat transfer phenomena in the hearth of BlueScope's Port Kembla No. 5 Blast Furnace. Model improvements feature more justified input parameters in turbulence modeling, buoyancy modeling, wall boundary conditions, material properties, and modeling of the solidification of iron. The model is validated by comparing the calculated temperatures with the thermocouple data available, where agreements are established within ±3 pct. The flow distribution in the hearth is discussed for intact and eroded hearth profiles, for sitting and floating coke bed states. It is shown that natural convection affects the flow in several ways: for example, the formation of (a) stagnant zones preventing hearth bottom from eroding or (b) the downward jetting of molten liquid promoting side wall erosion, or (c) at times, a vortex-like peripheral flow, promoting the "elephant foot" type erosion. A significant influence of coke bed permeability on the macroscopic flow pattern and the refractory temperature is observed.

  8. Blast furnace granular coal injection project. Annual report, January--December 1995

    SciTech Connect

    1995-05-01

    This annual report describes the Blast Furnace Granular Coal Injection project being implemented at Bethlehem Steel Corporation`s (BSC) Burns Harbor Plant. The project is receiving cost-sharing from the U.S. Department of Energy (DOE), and is being administrated by the Morgantown Energy Technology Center in accordance with the DOE Cooperative Agreement No. DE-FC21-91MC27362. This installation is the first in the United States to employ British Steel technology that uses granular coal to provide part of the fuel requirement of blast furnaces. The project will demonstrate/assess a broad range of technical/economic issues associated with the use of coal for this purpose. To achieve the program objectives, the demonstration project is divided into the following three Phases: (1) Phase I - Design. (2) Phase II - Construction. (3) Phase III - Operation. Preliminary Design (Phase I) began in 1991 with detailed design commencing in 1993. Construction at Burns Harbor (Phase II) began in August 1993 and was completed at the end of 1994. The demonstration test program (Phase III) started in the fourth quarter of 1995.

  9. A Novel Technique for Making Cold Briquettes for Charging in Blast Furnace

    NASA Astrophysics Data System (ADS)

    Mohanty, M. K.; Mishra, S.; Mishra, B.; Sarkar, S.; Samal, S. K.

    2016-02-01

    Different metallurgical wastes are generated during pyro processing of iron ore, which is used for making sponge iron or hot metal and for producing steel. Apart from these wastes, coke fines are generated during the coke making, and iron ore fines are generated during mining of iron ore. Although iron ore fines are used for making pellet after beneficiation still, it generates a huge quantity of iron ore waste during beneficiation with comparatively lower iron content. In the present study, briquettes are made by a stiff extrusion process from metallurgical waste like iron ore fines and coke fines with the addition of Portland cement as a binder and clay as a rheology modifier. Physical properties of the briquettes are evaluated, and reducibility of the briquettes is studied in comparison to lumpy iron ore. Phase analysis and microstructural analysis of the briquettes and lumpy iron ore are carried out after firing at different temperatures in the simulated blast furnace condition. Physical and mineralogical properties are correlated with the reducibility of the briquettes and lumpy iron ore. Briquettes made by a stiff extrusion process show a better mechanical strength fired at a different temperature to take the load of burden and better reducibility than lumpy iron ore. The briquettes after self-curing are charged to a 23 mt3 blast furnace which shows encouraging results.

  10. Chromium stabilization chemistry of paint removal wastes in Portland cement and blast furnace slag

    SciTech Connect

    Boy, J.H.; Race, T.D.; Reinbold, K.A.

    1995-12-31

    The use of cement based systems for solidification and stabilization of hazardous wastes has been proposed. The stabilization of Cr contaminated paint removal wastes in ordinary Portland cement and in a Portland cement and blast furnace slag matrix was investigated. A loading by volume of 75% waste and 25% cement (or cement + slag) was used. The expression of pore solution was utilized to determine the chemical environment encountered by the waste species in the cement matrix. The highly alkaline conditions of ordinary Portland cement determined the stability of the metal species, with Cr being highly soluble. The replacement of 25% of the Portland cement by blast furnace slag was found to decrease the [OH-] of the pore solution resulting in a decrease of the Cr concentration. For cement wastes forms hydrated for 28 days, the Cr concentration decreased in the expressed pore solution. During the TCLP tests the cement waste form and extraction solution were found to react, changing the chemistry of the extraction solution. The expression of pore solution was found to give a direct measure of the chemistry of the waste species in the cement matrix. This avoids the reaction of the TCLP extraction solution with the cement matrix which changes the solubility of the hazardous metals. 15 refs., 4 figs., 6 tabs.

  11. Application of Granulated Blast Furnace Slag in Cement Composites Exposed to Biogenic Acid Attack

    NASA Astrophysics Data System (ADS)

    Kovalcikova, M.; Estokova, A.; Luptakova, A.

    2015-11-01

    The deterioration of cement-based materials used for the civil infrastructure has led to the realization that cement-based materials, such as concrete, must be improved in terms of their properties and durability. Leaching of calcium ions increases the porosity of cement- based materials, consequently resulting in a negative effect on durability since it provides an entry for aggressive harmful ions, causing corrosion of concrete. The use supplementary cementing composite materials have been reported to improve the resistance of concrete to deterioration by aggressive chemicals. The paper is focused on the investigation of the influence of biogenic acid attack on the cement composites affected by bacteria Acidithiobacillus thiooxidans. The concrete specimens with 65 wt. % addition of antimicrobial activated granulated blast furnace slag as durability increasing factor as well as without any addition were studied. The experiments proceeded during 150 days under model laboratory conditions. The pH values and chemical composition of leachates were measured after each 30- day cycle. The calcium and silicon contents in leachates were evaluated using X - ray fluorescence method (XRF). Summarizing the results, the 65% wt. addition of antimicrobial activated granulated blast furnace slag was not confirmed to be more resistant.

  12. Discrete element simulation of charging and mixed layer formation in the ironmaking blast furnace

    NASA Astrophysics Data System (ADS)

    Mitra, Tamoghna; Saxén, Henrik

    2015-11-01

    The burden distribution in the ironmaking blast furnace plays an important role for the operation as it affects the gas flow distribution, heat and mass transfer, and chemical reactions in the shaft. This work studies certain aspects of burden distribution by small-scale experiments and numerical simulation by the discrete element method (DEM). Particular attention is focused on the complex layer-formation process and the problems associated with estimating the burden layer distribution by burden profile measurements. The formation of mixed layers is studied, and a computational method for estimating the extent of the mixed layer, as well as its voidage, is proposed and applied on the results of the DEM simulations. In studying a charging program and its resulting burden distribution, the mixed layers of coke and pellets were found to show lower voidage than the individual burden layers. The dynamic evolution of the mixed layer during the charging process is also analyzed. The results of the study can be used to gain deeper insight into the complex charging process of the blast furnace, which is useful in the design of new charging programs and for mathematical models that do not consider the full behavior of the particles in the burden layers.

  13. Model of Draining of the Blast Furnace Hearth with an Impermeable Zone

    NASA Astrophysics Data System (ADS)

    Saxén, Henrik

    2015-02-01

    Due to demands of lower costs and higher productivity in the steel industry, the volume of operating blast furnaces has grown during the last decades. As the height is limited by the allowable pressure drop, the hearth diameter has grown considerably and, along with this, also draining-related problems. In this paper a mathematical model is developed for simulating the drainage in the case where an impermeable region exists in the blast furnace hearth. The model describes the quasi-stationary drainage process of a hearth with two operating tapholes, where the communication between the two pools of molten slag and iron can be controlled by parameterized expressions. The model also considers the case where the buoyancy of the liquids is sufficient for lifting the coke bed. The implications of different size of the liquid pools, communication between the pools, bed porosity, etc. are studied by simulation, and conclusions concerning their effect on the drainage behavior and evolution of the liquid levels in the hearth are drawn. The simulated liquid levels are finally demonstrated to give rise to a pressure profile acting on the hearth which agrees qualitatively with signals from strain gauges mounted in the hearth wall of an industrial ironmaking process.

  14. Sulphate removal over barium-modified blast-furnace-slag geopolymer.

    PubMed

    Runtti, Hanna; Luukkonen, Tero; Niskanen, Mikko; Tuomikoski, Sari; Kangas, Teija; Tynjälä, Pekka; Tolonen, Emma-Tuulia; Sarkkinen, Minna; Kemppainen, Kimmo; Rämö, Jaakko; Lassi, Ulla

    2016-11-01

    Blast-furnace slag and metakaolin were geopolymerised, modified with barium or treated with a combination of these methods in order to obtain an efficient SO4(2-) sorbent for mine water treatment. Of prepared materials, barium-modified blast-furnace slag geopolymer (Ba-BFS-GP) exhibited the highest SO4(2-) maximum sorption capacity (up to 119mgg(-1)) and it compared also favourably to materials reported in the literature. Therefore, Ba-BFS-GP was selected for further studies and the factors affecting to the sorption efficiency were assessed. Several isotherms were applied to describe the experimental results of Ba-BFS-GP and the Sips model showed the best fit. Kinetic studies showed that the sorption process follows the pseudo-second-order kinetics. In the dynamic removal experiments with columns, total SO4(2-) removal was observed initially when treating mine effluent. The novel modification method of geopolymer material proved to be technically suitable in achieving extremely low concentrations of SO4(2-) (<2mgL(-1)) in mine effluents. PMID:27318734

  15. A Model to Simulate Titanium Behavior in the Iron Blast Furnace Hearth

    NASA Astrophysics Data System (ADS)

    Guo, Bao-Yu; Zulli, Paul; Maldonado, Daniel; Yu, Ai-Bing

    2010-08-01

    The erosion of hearth refractory is a major limitation to the campaign life of a blast furnace. Titanium from titania addition in the burden or tuyere injection can react with carbon and nitrogen in molten pig iron to form titanium carbonitride, giving the so-called titanium-rich scaffold or buildup on the hearth surface, to protect the hearth from subsequent erosion. In the current article, a mathematical model based on computational fluid dynamics is proposed to simulate the behavior of solid particles in the liquid iron. The model considers the fluid/solid particle flow through a packed bed, conjugated heat transfer, species transport, and thermodynamic of key chemical reactions. A region of high solid concentration is predicted at the hearth bottom surface. Regions of solid formation and dissolution can be identified, which depend on the local temperature and chemical equilibrium. The sensitivity to the key model parameters for the solid phase is analyzed. The model provides an insight into the fundamental mechanism of solid particle formation, and it may form a basic model for subsequent development to study the formation of titanium scaffold in the blast furnace hearth.

  16. Formation mechanism of the graphite-rich protective layer in blast furnace hearths

    NASA Astrophysics Data System (ADS)

    Jiao, Ke-xin; Zhang, Jian-liang; Liu, Zheng-jian; Liu, Feng; Liang, Li-sheng

    2016-01-01

    A long campaign life of blast furnaces is heavily linked to the existence of a protective layer in their hearths. In this work, we conducted dissection studies and investigated damage in blast furnace hearths to estimate the formation mechanism of the protective layer. The results illustrate that a significant amount of graphite phase was trapped within the hearth protective layer. Furthermore, on the basis of the thermodynamic and kinetic calculations of the graphite precipitation process, a precipitation potential index related to the formation of the graphite-rich protective layer was proposed to characterize the formation ability of this layer. We determined that, under normal operating conditions, the precipitation of graphite phase from hot metal was thermodynamically possible. Among elements that exist in hot metal, C, Si, and P favor graphite precipitation, whereas Mn and Cr inhibit this process. Moreover, at the same hot-face temperature, an increase of carbon concentration in hot metal can shorten the precipitation time. Finally, the results suggest that measures such as reducing the hot-face temperature and increasing the degree of carbon saturation in hot metal are critically important to improve the precipitation potential index.

  17. Modeling coal combustion behavior in an ironmaking blast furnace raceway: model development and applications

    SciTech Connect

    Maldonado, D.; Austin, P.R.; Zulli, P.; Guo B.

    2009-03-15

    A numerical model has been developed and validated for the investigation of coal combustion phenomena under blast furnace operating conditions. The model is fully three-dimensional, with a broad capacity to analyze significant operational and equipment design changes. The model was used in a number of studies, including: Effect of cooling gas type in coaxial lance arrangements. It was found that oxygen cooling improves coal burnout by 7% compared with natural gas cooling under conditions that have the same amount of oxygen enrichment in the hot blast. Effect of coal particle size distribution. It was found that during two similar periods of operation at Port Kembla's BF6, a difference in PCI capability could be attributed to the difference in coal size distribution. Effect of longer tuyeres. Longer tuyeres were installed at Port Kembla's BF5, leading to its reline scheduled for March 2009. The model predicted an increase in blast velocity at the tuyere nose due to the combustion of volatiles within the tuyere, with implications for tuyere pressure drop and PCI capability. Effect of lance tip geometry. A number of alternate designs were studied, with the best-performing designs promoting the dispersion of the coal particles. It was also found that the base case design promoted size segregation of the coal particles, forcing smaller coal particles to one side of the plume, leaving larger coal particles on the other side. 11 refs., 15 figs., 4 tabs.

  18. Three-Dimensional Modeling of Flow and Thermochemical Behavior in a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Shen, Yansong; Guo, Baoyu; Chew, Sheng; Austin, Peter; Yu, Aibing

    2015-02-01

    An ironmaking blast furnace (BF) is a complex high-temperature moving bed reactor involving counter-, co- and cross-current flows of gas, liquid and solid, coupled with heat and mass exchange and chemical reactions. Two-dimensional (2D) models were widely used for understanding its internal state in the past. In this paper, a three-dimensional (3D) CFX-based mathematical model is developed for describing the internal state of a BF in terms of multiphase flow and the related thermochemical behavior, as well as process indicators. This model considers the intense interactions between gas, solid and liquid phases, and also their competition for the space. The model is applied to a BF covering from the burden surface at the top to the liquid surface in the hearth, where the raceway cavity is considered explicitly. The results show that the key in-furnace phenomena such as flow/temperature patterns and component distributions of solid, gas and liquid phases can be described and characterized in different regions inside the BF, including the gas and liquids flow circumferentially over the 3D raceway surface. The in-furnace distributions of key performance indicators such as reduction degree and gas utilization can also be predicted. This model offers a cost-effective tool to understand and control the complex BF flow and performance.

  19. CFD study of ejector flow behavior in a blast furnace gas galvanizing plant

    NASA Astrophysics Data System (ADS)

    Besagni, Giorgio; Mereu, Riccardo; Inzoli, Fabio

    2015-02-01

    In recent years, there has been a growing interest toward Blast Furnace Gas (BFG) as a low-grade energy source for industrial furnaces. This paper considers the revamping of a galvanic plant furnace converted to BFG from natural gas. In the design of the new system, the ejector on the exhaust line is a critical component. This paper studies the flow behavior of the ejector using a Computational Fluid Dynamics (CFD) analysis. The CFD model is based on a 3D representation of the ejector, using air and exhaust gases as working fluids. This paper is divided in three parts. In the first part, the galvanic plant used as case study is presented and discussed, in the second part the CFD approach is outlined, and in the third part the CFD approach is validated using experimental data and the numerical results are presented and discussed. Different Reynolds-Averaged Navier-Stokes (RANS) turbulence models ( k-ω SST and k-ɛ Realizable) are evaluated in terms of convergence capability and accuracy in predicting the pressure drop along the ejector. Suggestions for future optimization of the system are also provided.

  20. Effectiveness of the reconstruction of a 3000-m/sup 3/ blast furnace

    SciTech Connect

    Vasyura, G.G.; Anishchenko, Yu.V.; Polevoi, V.I.; Uzhva, G.G.; Globa, N.I.; Ivanchenko, V.I.

    1988-03-01

    The authors discuss the effectiveness of an overhaul done on a 3000-m/sup 3/ blast furnace with previous design deficiencies. During the overhaul, the diameter of the reinforcement of the bottom was enlarged from 14,330 to 15,130 mm. Other changes included replacing the lining in the region of the joint between the hearth and bottom by a single block, lengthening and widening the main troughs, and increasing the thickness of the shell of the bustle pipe. During the overhaul the bustle pipe was lined with refractories ShLB-1.0 and KL-1.3 and two courses of MKV-72. The reconstruction made it possible to alter the operating parameters of the furnace. The authors aimed to minimize heat loss with the coolant water from the stack and top and to maximize the gas permeability of the stock. Productivity of the furnace in the post-overhaul period increased 5432 tons/day at a coke consumption of 483 kg/ton pig.

  1. Pilot plant testing of Illinois coal for blast furnace injection. Technical report, March 1--May 31, 1995

    SciTech Connect

    Crelling, J.C.

    1995-12-31

    A new use for Illinois coal is as fuel injected into a blast furnace to produce molten iron as first step in steel production. Because of cost and decreasing availability, metallurgical coke is being replaced by coal injected at the tuyere area of the furnace where the blast air enters. Purpose of this study is to evaluate combustion of Illinois coal in the blast furnace injection process in a pilot plant test facility. (Limited research to date suggests that coals of low fluidity and moderate to high S and Cl contents are suitable for blast furnace injection.) This proposal is intended to complete the study under way with Armco and Inland and to demonstrate quantitatively the suitability of Herrin No. 6 and Springfield No. 5 coals for injection. Main feature of current work is testing of Illinois coals at CANMET`s pilot plant coal combustion facility. During this quarter, two additional 300-pound samples of coal (IBCSP-110 Springfield No. 5 and an Appalachian coal) were delivered. Six Illinois Basin coals were analyzed with the CANMET model and compared with other bituminous coals from the Appalachians, France, Poland, South Africa, and Colombia. Based on computer modeling, lower rank bituminous coals, including coal from the Illinois Basin, compare well in injection with a variety of other bituminous coals.

  2. Coal combustion under conditions of blast furnace injection. [Quarterly] technical report, 1 December 1993--28 February 1994

    SciTech Connect

    Crelling, J.C.

    1994-06-01

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. Steel Company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals for such use. During this quarter a sample of the feed coal that is being used for injection into the No. 7 Blast Furnace of Inland Steel has been analyzed petrographically and compared to both the Herrin No. 6 coal and Armco feed coal. Additional characterization is underway and an advanced program of pyrolysis and reactivity testing has been initiated.

  3. Chemical acceleration of a neutral granulated blast-furnace slag activated by sodium carbonate

    SciTech Connect

    Kovtun, Maxim Kearsley, Elsabe P. Shekhovtsova, Julia

    2015-06-15

    This paper presents results of a study on chemical acceleration of a neutral granulated blast-furnace slag activated using sodium carbonate. As strength development of alkali-activated slag cements containing neutral GBFS and sodium carbonate as activator at room temperature is known to be slow, three accelerators were investigated: sodium hydroxide, ordinary Portland cement and a combination of silica fume and slaked lime. In all cements, the main hydration product is C–(A)–S–H, but its structure varies between tobermorite and riversideite depending on the accelerator used. Calcite and gaylussite are present in all systems and they were formed due to either cation exchange reaction between the slag and the activator, or carbonation. With accelerators, compressive strength up to 15 MPa can be achieved within 24 h in comparison to 2.5 MPa after 48 h for a mix without an accelerator.

  4. A study on the flow of molten iron in the hearth of blast furnace

    SciTech Connect

    Suh, Y.K.; Lee, Y.J.; Baik, C.Y.

    1996-12-31

    The flow of molten iron in the hearth of blast furnace was investigated by using a water model test and a numerical simulation. The water model apparatus was set up in order to evaluate the effects of coke size, coke bed structure, drain rate, and coke free space on the fluidity of molten iron through measurement of residence time and visualization of flow pattern. In addition, the flow was calculated by solving momentum equation in porous media using finite element method. The residence time increased with the coke size decrease, but decreased with the drain rate increase. If small coke was placed in the center of deadman, peripheral flow was enhanced. The flow path was changed due to the coke free space.

  5. Fe-Si droplets associated with graphite on blast furnace coke

    NASA Astrophysics Data System (ADS)

    Gornostayev, Stanislav S.; Fabritius, Timo M. J.; Kerkkonen, Olavi; Härkki, Jouko J.

    2012-06-01

    Fe-Si droplets on the surface of blast furnace (BF) coke from 25 to 50 cm at the tuyere level are mostly composed of Fe3Si, which has various shapes (round, elongated, and irregular) and penetration degrees into the BF coke matrix. The shapes and penetration degrees may depend on the saturation of molten iron by silicon during interaction with the coke matrix. The droplets are covered by a tiny shell of carbon. Graphite observed inside the droplets can be divided into two categories: well-formed tabular crystals with relatively large size and flakes with structures similar as those in cast iron. The textures of the droplets reflect composition, interaction with the coke matrix, and cooling conditions.

  6. Characterization of tuyere-level core-drill coke samples from blast furnace operation

    SciTech Connect

    S. Dong; N. Paterson; S.G. Kazarian; D.R. Dugwell; R. Kandiyoti

    2007-12-15

    A suite of tuyere-level coke samples have been withdrawn from a working blast furnace during coal injection, using the core-drilling technique. The samples have been characterized by size exclusion chromatography (SEC), Fourier transform Raman spectroscopy (FT-RS), and X-ray powder diffraction (XRD) spectroscopy. The 1-methyl-2-pyrrolidinone (NMP) extracts of the cokes sampled from the 'bosh', the rear of the 'bird's nest', and the 'dead man' zones were found by SEC to contain heavy soot-like materials (ca. 10{sup 7}-10{sup 8} apparent mass units). In contrast, NMP extracts of cokes taken from the raceway and the front of the 'bird's nest' only contained a small amount of material of relatively lower apparent molecular mass (up to ca. 10{sup 5} u). Since the feed coke contained no materials extractable by the present method, the soot-like materials are thought to have formed during the reactions of volatile matter released from the injectant coal, probably via dehydrogenation and repolymerization of the tars. The Raman spectra of the NMP-extracted core-drilled coke samples showed variations reflecting their temperature histories. Area ratios of D-band to G-band decreased as the exposure temperature increased, while intensity ratios of D to G band and those of 2D to G bands increased with temperature. The graphitic (G), defect (D), and random (R) fractions of the carbon structure of the cokes were also derived from the Raman spectra. The R fractions decreased with increasing temperature, whereas G fractions increased, while the D fractions showed a more complex variation with temperature. These data appear to give clues regarding the graphitization mechanism of tuyere-level cokes in the blast furnace. 41 refs., 9 figs., 6 tabs.

  7. Compare pilot-scale and industry-scale models of pulverized coal combustion in an ironmaking blast furnace

    NASA Astrophysics Data System (ADS)

    Shen, Yansong; Yu, Aibing; Zulli, Paul

    2013-07-01

    In order to understand the complex phenomena of pulverized coal injection (PCI) process in blast furnace (BF), mathematical models have been developed at different scales: pilot-scale model of coal combustion and industry-scale model (in-furnace model) of coal/coke combustion in a real BF respectively. This paper compares these PCI models in aspects of model developments and model capability. The model development is discussed in terms of model formulation, their new features and geometry/regions considered. The model capability is then discussed in terms of main findings followed by the model evaluation on their advantages and limitations. It is indicated that these PCI models are all able to describe PCI operation qualitatively. The in-furnace model is more reliable for simulating in-furnace phenomena of PCI operation qualitatively and quantitatively. These models are useful for understanding the flow-thermo-chemical behaviors and then optimizing the PCI operation in practice.

  8. Metal retention on pine bark and blast furnace slag--on-site experiment for treatment of low strength landfill leachate.

    PubMed

    Nehrenheim, Emma; Waara, Sylvia; Johansson Westholm, Lena

    2008-03-01

    Treatment of landfill leachate using blast furnace slag and pine bark as reactive sorbents was studied in an in situ column experiment at the Lilla Nyby landfill site in Eskilstuna, Sweden. The columns were filled with approximately 101 of each sorbent and leachate was supplied at three different flow rates during a period of 4 months. Samples of inflow and outflow were collected three times a week and were analyzed for physical and chemical parameters, including concentrations of some metals, and toxicity. It was found that pine bark removed metals more efficiently than did the blast furnace slags; that Zn was most efficiently retained in the filters and that both retention time and initial concentration played an important role in the sorption process. It was also observed that the pine bark column did not release COD. No toxicity of the untreated or the treated leachate was found with the test organisms and test responses used. PMID:17462882

  9. Mechanism of physical transformations of mineral matter in the blast furnace coke with reference to its reactivity and strength

    SciTech Connect

    Stanislav S. Gornostayev; Jouko J. Haerkki

    2006-12-15

    Examinations of polished and dry cut sections of feed and tuyere coke revealed some possible mechanisms for the physical influence of mineral compounds on the reactivity and strength of coke. It was observed that rounded particles of mineral phases that are exposed to the pore walls and surface of coke at high temperature create an inorganic cover, thus reducing the surface available for gas-solid reactions. The particles of mineral matter that have a low melting point and viscosity can affect the coke at earlier stages in the blast furnace process, acting in the upper parts of the blast furnace (BF). The temperature-driven redistribution of mineral phases within the coke matrix probably leads to the creation of weak spots and in general to anisotropy in its properties, thus reducing its strength. 9 refs., 2 figs., 1 tab.

  10. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki

    2007-09-15

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  11. Blast furnace slag-modified grouts for in situ stabilization of chromium-contaminated soil

    SciTech Connect

    Allan, M.L.; Kukacka, L.E.

    1995-12-01

    Blast furnace slag-modified grouts were used to stabilize soils contaminated with trivalent and hexavalent chromium. Slag content, grout/soil ratio and water/cementitious material ratio were varied to determine the effects on leachability of chromium, permeability and compressive strength. Slag-modified grouts successfully stabilized Cr(VI)-contaminated soil to give low leachability, thereby allowing omission of the pretreatment stage to reduce Cr(VI) to Cr(III) necessary with lime and ordinary Portland cement stabilization procedures. Leachability of both Cr(III) and Cr(VI) decreased with increasing slag content. The permanence of leach resistance is enhanced by higher slag levels in grout. Compressive strength of grout-treated soil ranges from 6 to 36 MPa and permeability is of the order of 10{sup {minus}11} to 10{sup {minus}7} cm/s, depending on mix proportions. Slag-modified grouts have potential for in situ stabilization of Cr(III)- or Cr(VI)-contaminated landfills.

  12. Preparation of nanometer-sized black iron oxide pigment by recycling of blast furnace flue dust.

    PubMed

    Shen, Lazhen; Qiao, Yongsheng; Guo, Yong; Tan, Junru

    2010-05-15

    Blast furnace (BF) flue dust is one of pollutants emitted by iron and steel plants. The recycling of BF flue dust can not only reduce pollution but also bring social and environmental benefits. In this study, leaching technique was employed to the treatment of BF flue dust at first. A mixed solution of ferrous and ferric sulfate was obtained and used as raw material to prepare nanometer-sized black iron oxide pigment (Fe(3)O(4), magnetite) with NaOH as precipitant. The optimal technological conditions including total iron ion concentration, Fe(3+)/Fe(2+) mole ratio, precipitant concentration and reaction temperature were studied and discussed carefully. The spectral reflectance and oil absorption were used as major parameters to evaluate performance of pigment. Furthermore, Fe(3)O(4) particles were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Under optimized conditions obtained pigment has low average spectral reflectance (<4%), good oil absorption ( approximately 23%), high black intensity, and narrow size distribution 60-70 nm. PMID:20064689

  13. on the Structure and Viscous Behavior of Ti-Bearing Blast Furnace Slags

    NASA Astrophysics Data System (ADS)

    Sun, Yongqi; Liao, Junlin; Zheng, Kai; Wang, Xidong; Zhang, Zuotai

    2014-10-01

    This study provided a fundamental analysis of the viscous behavior and structure of Ti-bearing blast furnace slags modified by different B2O3 additions with a basicity (CaO/SiO2) range of 0.5-0.9. The viscosity of slag melts was measured by rotating cylinder method, and the results showed that both slag viscosity and apparent activation energy for viscous flow remarkably decreased with B2O3 addition. To connect the viscosity variation of slags to the melt structure, Fourier transformation infrared spectroscopy analysis was performed. The results indicated that B2O3 acted as a typical network forming oxide, which was introduced into the network and existed dominantly as a two-dimensional structure, BO3 triangular. With the increase of B2O3 content, the stretching vibration of BO3 triangular gradually became more pronounced, which resulted in a simpler and less complex structure and caused the decrease of slag viscosity.

  14. Characterisation of magnesium potassium phosphate cements blended with fly ash and ground granulated blast furnace slag

    SciTech Connect

    Gardner, Laura J.; Bernal, Susan A.; Walling, Samuel A.; Corkhill, Claire L.; Provis, John L.; Hyatt, Neil C.

    2015-08-15

    Magnesium potassium phosphate cements (MKPCs), blended with 50 wt.% fly ash (FA) or ground granulated blast furnace slag (GBFS) to reduce heat evolution, water demand and cost, were assessed using compressive strength, X-ray diffraction (XRD), scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) spectroscopy on {sup 25}Mg, {sup 27}Al, {sup 29}Si, {sup 31}P and {sup 39}K nuclei. We present the first definitive evidence that dissolution of the glassy aluminosilicate phases of both FA and GBFS occurred under the pH conditions of MKPC. In addition to the main binder phase, struvite-K, an amorphous orthophosphate phase was detected in FA/MKPC and GBFS/MKPC systems. It was postulated that an aluminium phosphate phase was formed, however, no significant Al–O–P interactions were identified. High-field NMR analysis of the GBFS/MKPC system indicated the potential formation of a potassium-aluminosilicate phase. This study demonstrates the need for further research on these binders, as both FA and GBFS are generally regarded as inert fillers within MKPC.

  15. Preparation of glass-forming materials from granulated blast furnace slag

    NASA Astrophysics Data System (ADS)

    Alonso, M.; Sáinz, E.; Lopez, F. A.

    1996-10-01

    Glass precursor materials, to be used for the vitrification of hazardous wastes, have been prepared from blast furnace slag powder through a sol-gel route. The slag is initially reacted with a mixture of alcohol (ethanol or methanol) and mineral acid (HNO3 or H2SO4) to give a sol principally consisting of Si, Ca, Al, and Mg alkoxides. Gelation is carried out with variable amounts of either ammonia or water. The gelation rate can be made as fast as desired by adding excess hydrolizing agent or else by distilling the excess alcohol out of the alkoxide solution. The resulting gel is first dried at low temperature and ground. The powder thus obtained is then heat treated at several temperatures. The intermediate and final materials are characterized by thermal analysis, infrared (IR) spectroscopy, X-ray diffraction, scanning electron microscopy (SEM), and chemical analysis. From the results, the operating conditions yielding a variety of glass precursors differing in their composition are established. The method, in comparison with direct vitrification of slag, presents a number of advantages: (1) the glass precursor obtained devitrifies at higher temperatures; (2) it enables the adjustment, to a certain extent, of the chemical composition of the glass precursor; and (3) it permits recovering marketable materials at different stages of the process.

  16. Formation mechanism of the protective layer in a blast furnace hearth

    NASA Astrophysics Data System (ADS)

    Jiao, Ke-xin; Zhang, Jian-liang; Liu, Zheng-jian; Xu, Meng; Liu, Feng

    2015-10-01

    A variety of techniques, such as chemical analysis, scanning electron microscopy-energy dispersive spectroscopy, and X-ray diffraction, were applied to characterize the adhesion protective layer formed below the blast furnace taphole level when a certain amount of titanium- bearing burden was used. Samples of the protective layer were extracted to identify the chemical composition, phase assemblage, and distribution. Furthermore, the formation mechanism of the protective layer was determined after clarifying the source of each component. Finally, a technical strategy was proposed for achieving a stable protective layer in the hearth. The results show that the protective layer mainly exists in a bilayer form in the sidewall, namely, a titanium-bearing layer and a graphite layer. Both the layers contain the slag phase whose major crystalline phase is magnesium melilite (Ca2MgSi2O7) and the main source of the slag phase is coke ash. It is clearly determined that solid particles such as graphite, Ti(C,N) and MgAl2O4 play an important role in the formation of the protective layer, and the key factor for promoting the formation of a stable protective layer is reasonable control of the evolution behavior of coke.

  17. Effect of blast furnace slag on self-healing of microcracks in cementitious materials

    SciTech Connect

    Huang, Haoliang; Ye, Guang; Damidot, Denis

    2014-06-01

    The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH)₂ solution as activator, it was found that the reaction products formed in cracks are composed of C-S-H, ettringite, hydrogarnet and OH–hydrotalcite. The fraction of C-S-H in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO₄⁻² ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50 h and then slows down. According to thermodynamic modeling, when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high. Highlights: • Self-healing reaction products in slag cement paste were characterized. • Self-healing reaction products formed in time were quantified with image analysis. • Self-healing in slag cement paste was simulated with a reactive transport model. • Effect of carbonation on self-healing was investigated by thermodynamic modeling. • Effect of slag on self-healing was discussed based on experiments and simulation.

  18. Iron blast furnace slag/hydrated lime sorbents for flue gas desulfurization.

    PubMed

    Liu, Chiung-Fang; Shih, Shin-Min

    2004-08-15

    Sorbents prepared from iron blast furnace slag (BFS) and hydrated lime (HL) through the hydration process have been studied with the aim to evaluate their reactivities toward SO2 under the conditions prevailing in dry or semidry flue gas desulfurization processes. The BFS/HL sorbents, having large surface areas and pore volumes due to the formation of products of hydration, were highly reactive toward SO2, as compared with hydrated lime alone (0.24 in Ca utilization). The sorbent reactivity increased as the slurrying temperature and time increased and as the particle size of BFS decreased; the effects of the liquid/solid ratio and the sorbent drying conditions were negligible. The structural properties and the reactivity of sorbent were markedly affected by the BFS/HL ratio; the sorbent with 30/70 ratio had the highest 1 h utilization of Ca, 0.70, and SO2 capture, 0.45 g SO2/g sorbent. The reactivity of a sorbent was related to its initial specific surface area (Sg0) and molar content of Ca (M(-1)); the 1 h utilization of Ca increased almost linearly with increasing Sg0/M. The results of this study are useful to the preparation of BFS/HL sorbents with high reactivity for use in the dry and semidry processes to remove SO2 from the flue gas. PMID:15382877

  19. Ultrasonic-Assisted Acid Leaching of Indium from Blast Furnace Sludge

    NASA Astrophysics Data System (ADS)

    Shen, Xingmei; Li, Liaosha; Wu, Zhaojin; Lü, Huihong; Lü, Jia

    2013-12-01

    Ultrasonic-assisted acid leaching was used to improve extraction of indium from blast furnace sludge. The effects of solid-liquid ratio, leaching temperature, and leaching time on extraction of indium were investigated and three leaching methods of high temperature acid leaching (HL), ultrasonic acid leaching (UL), and high temperature-ultrasonic acid leaching (HUL) were compared. The results show that extraction of indium increases with leaching time for all the methods. UL exhibits the lowest indium extraction. For HL, extraction of indium reaches 32.6 pct when the leaching time is 4 hours, and after 4 hours, the extraction increases slowly. Leaching temperature has a more positive effect on extraction of indium than ultrasonic. HUL can lead to a higher extraction of indium than high temperature acid leaching and UL, and extraction of indium reaches 40.4 pct when the leaching time is 2 hours. After 2 hours, no obvious increase occurs. HUL not only increases extraction of indium but also reduces the leaching time which can improve production efficiency.

  20. Thermodynamic Analysis of Blast Furnace Slag Waste Heat-Recovery System Integrated with Coal Gasification

    NASA Astrophysics Data System (ADS)

    Duan, W. J.; Li, P.; Lei, W.; Chen, W.; Yu, Q. B.; Wang, K.; Qin, Q.

    2015-05-01

    The blast furnace (BF) slag waste heat was recovered by an integrated system stage by stage, which combined a physical and chemical method. The water and coal gasification reactions were used to recover the heat in the system. Based on the first and second law of thermodynamics, the thermodynamic analysis of the system was carried out by the enthalpy-exergy diagram. The results showed that the concept of the "recovery-temperature countercurrent, energy cascade utilization" was realized by this system to recover and use the high-quality BF slag waste heat. In this system, the high-temperature waste heat was recovered by coal gasification and the relatively low-temperature waste heat was used to produce steam. The system's exergy and thermal recycling efficiency were 52.6% and 75.4%, respectively. The exergy loss of the integrated system was only 620.0 MJ/tslag. Compared with the traditional physical recycling method producing steam, the exergy and thermal efficiencies of the integrated system were improved significantly. Meanwhile, approximately 182.0 m3/tslag syngas was produced by coal gasification. The BF slag waste heat will be used integrally and efficiently by the integrated system. The results provide the theoretical reference for recycling and using the BF slag waste heat.

  1. Study of a blast-furnace smelting technology which involves the injection of pulverized-coal fuel, natural gas, and an oxygen-enriched blast into the hearth

    SciTech Connect

    Ryzhenkov, A.N.; Yaroshevskii, S.L.; Zamuruev, V.P.; Popov, V.E.; Afanas'eva, Z.K.

    2006-05-15

    Studies were made of features of a blast-furnace smelting technology that involves the injection of natural gas (NG), oxygen (O{sub 2}) and pulverized-coal fuel (PCF) into the hearth. The technology has been implemented in the compensation and overcompensation regimes, which has made it possible to maintain or improve the gas dynamics of the furnace, the conditions for the reduction of iron oxides, the heating of the charge, and PCF combustion in the tuyere zone as PCF consumption is increased and coke use is decreased. Under the given conditions, with the blast having an oxygen content of 25.64-25.7%, the hearth injection of 131-138 kg PCF and 65-69 m{sup 3} NG for each ton of pig iron has made it possible to reduce coke consumption by 171-185 kg/ton pig (30.2-32.7%), reduce the consumption of comparison fuel by 36-37 kg/ton (5.2-5.3%), and lower the production cost of the pig iron by 43-49 hryvnas/ton (3.7-6.4%). Here, furnace productivity has increased 3.8-6.5%, while the quality of the conversion pig iron remains the same as before. Measures are being implemented to further increase the level and efficiency of PCF use.

  2. Ceramic stove

    SciTech Connect

    Goetz, M.

    1984-12-24

    A ceramic stove that may be supplied in kit form includes a base frame, a cast iron firebox secured on the base frame, a top frame attached to and surrounding the top of the firebox, and ceramic panels extending between and held by the frames in spaced relation from the firebox. The ceramic panels are ''ship-lapped'' relative to each other and are not cemented or otherwise positively attached to each other. Logs may be fed as fuel into the fire box door from one side of the stove allowing longer logs to be burned. The logs rest on a grate which includes a ''shakable'' portion for shaking ashes onto an ash pan located below the grate. A separate, small door into the firebox is provided for starting the fire and that door is covered by another, safety door which also closes the scape through whic the ash pan is removed for emptying. An outer screen gate is provided to overlie the firebox doors and the entire side of the firebos. Products of combustion rise in the firebox and are guided by a baffle in a desired serpentine path prolonging their containment, until they reach an outlet at the top of the fire box where they are then carried downwardly by a flue formed in part by a portion of the back wall of the firebox. A heat shield covers the back wall of the firebox including the flue whose outlet extends through the heat shield at mid elevation. Other features and advantages are also disclosed.

  3. Structure, Growth Process, and Growth Mechanism of Perovskite in High-Titanium-Bearing Blast Furnace Slag

    NASA Astrophysics Data System (ADS)

    Liu, Lu; Hu, Meilong; Xu, Yuzhou; Bai, Chenguang; Gan, Yunhua

    2015-08-01

    The isothermal crystallization of perovskite in TiO2-CaO-SiO2-Al2O3-MgO high-titanium-bearing blast furnace slag was observed in situ at 1698 K (1425 °C) using a confocal scanning laser microscope. The dendrite structure of perovskite (CaTiO3) thus obtained showed vividly the primary dendrite trunks and secondary dendrite arms. Furthermore, the dendritic growth of perovskite in liquid slag was clearly observed on line. The results showed that the dendrite arrays in which the primary dendrite trunks observed on slag surface were parallel with each other grew toward the same direction. The secondary dendrite arms grew in the perpendicular direction with the primary trucks and stopped growing when they encounter. The perovskite dendrites showed a linear growth at two stages. The dendrites grew faster at early stage at about 5 to 7 μm/s and grew with a lower growth rate at about 1 to 2 μm/s in later stage. Finally, the growth mechanism of perovskite in melt was analyzed with the solidification theory. Based on the theoretical calculation of equilibrium phases in slag, the initial slag could be considered as a binary component system. One component was perovskite and the other component was the sum of all the other species that did not attend the crystallization of perovskite (included SiO2, Al2O3, and MgO, as well as CaO and TiO2 that were not involved in the solid formation). The formation of perovskite required the diffusion of CaO and TiO2 to the solid/liquid interface and the rejection of the other species from the interface. The solid/liquid equilibrium schematic diagram was made based on the calculation.

  4. Characteristics and settling behaviour of particles from blast furnace flue gas washing.

    PubMed

    Kiventerä, Jenni; Leiviskä, Tiina; Keski-Ruismäki, Kirsi; Tanskanen, Juha

    2016-05-01

    A lot of particles from iron-making are removed with blast furnace off-gas and routed to the gas cleaning system. As water is used for cleaning the gas, the produced wash water contains a large amount of particles such as valuable Fe and C. However, the presence of zinc prevents recycling. In addition, the high amount of calcium results in uncontrolled scaling. Therefore, the properties of the wash water from scrubber and sludge, from the Finnish metal industry (SSAB Raahe), were evaluated in this study. Size fractionation of wash water revealed that Fe, Zn, Al, Mn, V, Cr and Cd appeared mainly in the larger fractions (>1.2 μm) and Na, Mg, Si, Ni, K, Cu and As appeared mainly in the smaller fractions (<1.2 μm) or in dissolved form. Calcium was found both in the larger fractions and dissolved (∼60 mg/L). Most of the particles in wash water were included in the 1.2-10 μm particle size and were settled effectively. However, a clear benefit was observed when using a chemical to enhance particle settling. In comparison to 2.5 h of settling without chemical, the turbidity was further decreased by about 94%, iron 85% and zinc 50%. Coagulation-flocculation experiments indicated that both low and high molecular weight cationic polymers could provide excellent purification results in terms of turbidity. Calcium should be removed by other methods. The particles in sludge were mostly in the 2-4 μm or 10-20 μm fractions. Further sludge settling resulted in high solids removal. PMID:26945188

  5. Recycling of blast furnace sludge by briquetting with starch binder: Waste gas from thermal treatment utilizable as a fuel.

    PubMed

    Drobíková, Klára; Plachá, Daniela; Motyka, Oldřich; Gabor, Roman; Kutláková, Kateřina Mamulová; Vallová, Silvie; Seidlerová, Jana

    2016-02-01

    Steel plants generate significant amounts of wastes such as sludge, slag, and dust. Blast furnace sludge is a fine-grained waste characterized as hazardous and affecting the environment negatively. Briquetting is one of the possible ways of recycling of this waste while the formed briquettes serve as a feed material to the blast furnace. Several binders, both organic and inorganic, had been assessed, however, only the solid product had been analysed. The aim of this study was to assess the possibilities of briquetting using commonly available laundry starch as a binder while evaluating the possible utilization of the waste gas originating from the thermal treatment of the briquettes. Briquettes (100g) were formed with the admixture of starch (UNIPRET) and their mechanical properties were analysed. Consequently, they were subjected to thermal treatment of 900, 1000 and 1100°C with retention period of 40min during which was the waste gas collected and its content analysed using gas chromatography. Dependency of the concentration of the compounds forming the waste gas on the temperature used was determined using Principal component analysis (PCA) and correlation matrix. Starch was found to be a very good binder and reduction agent, it was confirmed that metallic iron was formed during the thermal treatment. Approximately 20l of waste gas was obtained from the treatment of one briquette; main compounds were methane and hydrogen rendering the waste gas utilizable as a fuel while the greatest yield was during the lowest temperatures. Preparation of blast furnace sludge briquettes using starch as a binder and their thermal treatment represents a suitable method for recycling of this type of metallurgical waste. Moreover, the composition of the resulting gas is favourable for its use as a fuel. PMID:26684056

  6. Study of mass attenuation coefficients and effective atomic numbers of bismuth-ground granulated blast furnace slag concretes

    NASA Astrophysics Data System (ADS)

    Kumar, Sandeep; Singh, Sukhpal

    2016-05-01

    Five samples of Bismuth-Ground granulated blast furnace slag (Bi-GGBFS) concretes were prepared using composition (0.6 cement + x Bi2O3 + (0.4-x) GGBFS, x = 0.05, 0.10, 0.15, 0.20 and 0.25) by keeping constant water (W) cement (C) ratio. Mass attenuation coefficients (μm) of these prepared samples were calculated using a computer program winXCOM at different gamma ray energies, whereas effective atomic numbers (Zeff) is calculated using mathematical formulas. The radiation shielding properties of Bi-GGBFS concrete has been compared with standard radiation shielding concretes.

  7. Process for producing blast furnace grade coke, a distillable product and fuel gases from a heavy, high sulfur, crude oil

    SciTech Connect

    Boyer, L.D.; Sooter, M.C.; Theodore, F.W.; Wasson, G.E.

    1983-06-14

    A process for producing a distillable hydrocarbonaceous stream, fuel gases and blast furnace grade coke from a heavy, high sulfur, crude oil by producing delayed coke from at least a portion of the crude oil; crushing at least a portion of the coke to provide a finely divided coke feedstock to a briquetting operation where the finely divided coke is briquetted using crude oil or topped crude oil as a binder to produce briquettes of a size from about 3/4 inch to about 3 inches with the resulting briquettes being passed to a high temperature vertical calciner where the solids are desulfurized to produce a strong blast furnace grade coke. The distillable stream and fuel gas stream are recovered from the delayed coking operation, the vertical calciner and optionally a crude oil topping operation. In some instances coke particles in the size range from about 3/4 inch to about 3 inches may be passed directly to the calciner without crushing and briquetting. However, it is preferred to crush and briquette substantially all of the coke.

  8. The Evolution of Structural Order as a Measure of Thermal History of Coke in the Blast Furnace

    NASA Astrophysics Data System (ADS)

    Lundgren, Maria; Khanna, Rita; Ökvist, Lena Sundqvist; Sahajwalla, Veena; Björkman, Bo

    2014-04-01

    Investigations were carried out on cokes heat treated in the laboratory and on cokes extracted from the experimental blast furnace (EBF) raceway and hearth. X-ray diffraction (XRD) measurements were performed to investigate changes in structural order ( L c), chemical transformations in coke ash along with comparative thermodynamic equilibrium studies and the influence of melt. Three data processing approaches were used to compute L c values as a function of temperature and time and linear correlations were established between L c and heat treatment temperatures during laboratory investigations. These were used to estimate temperatures experienced by coke in various regions of EBF and estimated raceway temperatures were seen to follow the profile of combustion peak. The MgAl2O4 spinel was observed in coke submerged in slag during laboratory studies and in cokes found further into the raceway. Coke in contact with hot metal showed XRD peaks corresponding to presence of Fe3Si. The intensity of SiO2 peak in coke ash was seen to decrease with increasing temperature and disappeared at around 1770 K (1500 °C) due to the formation of SiC. This study has shown that the evolution of structural order and chemical transformations in coke could be used to estimate its thermal history in blast furnaces.

  9. Fe-Si particles on the surface of blast furnace coke

    NASA Astrophysics Data System (ADS)

    Gornostayev, Stanislav S.; Heikkinen, Eetu-Pekka; Heino, Jyrki J.; Fabritius, Timo M. J.

    2015-07-01

    This study investigates the surface of unpolished samples of blast furnace (BF) coke drilled from the tuyere zone, which hosts Fe-Si particles (mostly Fe3Si) that vary in size, shape, depth of submersion (penetration) into the coke matrix, and contact features with the surface. Based on the shape of the particles and the extent of their contact with the coke matrix, they have been grouped into three major types: (I) sphere-like droplets with limited contact area, (II) semi-spheres with a larger contact area, and (III) irregular segregations with a spherical surface, which exhibit the largest contact area among the three types of particles. Considering the ratio between the height ( h) of the particles and half of their length at the surface level ( l) along the cross-section, these three types can be characterized as follows: (I) h > l, (II) h ≈ l, and (III) h < l. All the three types of particles can be found near each other. The shape and the extent of the contact depend on the degree of penetration of the material into the matrix, which is a function of the composition of the particles. Type (I) particles were initially saturated with Si at an earlier stage and, for that reason, they can react less with carbon in the coke matrix than type (II) and (III), thereby moving faster through the coke cone. Thermodynamic calculations have shown that the temperature interval of 1250-1300°C can be considered the starting point for Si entering into molten iron under quartz-dominated coke ash. Accordingly, the initial pick-up of Si by molten iron can be assumed to be mineral-related. In terms of BF practice, better conditions for sliding Fe-Si droplets through the coke cone are available when they come into contact with free SiO2 concentrated into small grains, and when the SiO2/ΣMe x O y mass ratio in the coke ash is high.

  10. Long life hearth in blast furnace -- Kokura No. 2 B.F. of Sumitomo Metals

    SciTech Connect

    Yamamoto, Takaiku; Sunahara, Kouhei; Inada, Takanobu; Takatani, Kouji; Miyahara, Mitsuo; Sato, Yasusi; Hatano, Yasuhiko; Takata, Kouzo

    1997-12-31

    The factors elongating hearth life of Sumitomo Kokura No. 2 B.F. were investigated by use of an estimation system of the furnace hearth condition, which consisted of four mathematical simulation models. Lowered heat load operation together with integrated design of both refractories and cooling enabled the furnace life to be extended for over 16 years without severe damage in the hearth.

  11. Development of an Operation Support System for the Blast Furnace in the Ironmaking Process: Large-scale Database-based Online Modeling and Integrated Simulators

    NASA Astrophysics Data System (ADS)

    Ogai, Harutoshi; Ogawa, Masatoshi; Uchida, Kenko; Matsuzaki, Shinroku; Ito, Masahiro

    In the pig-ironmaking process, factors that cause operation malfunctions have increased with both the enlargement of the blast furnace and the increasing use of low quality ore. Therefore, an operation support system that predicts blast furnace performance is demanded. This paper reports the development of a blast furnace operation support system with an integrated simulator and “Large-scale database-based Online Modeling (LOM).” To develop the integrated simulator, a sophisticated burden distribution model is integrated with a two-dimensional total internal phenomenon model for the stationary state by using Java technology. Moreover, an integrated simulator for the partial non-stationary state is developed by modifying the two-dimensional total internal phenomenon model for the stationary state. To incorporate the LOM system into the operation support system, a cross-platform LOM system with general versatility is rebuilt by an existing LOM system. The operation support system is realized by the simulator of the physical modeling method and the LOM of the local modeling method. As a result, the operation support system predicts a dynamic molten pig-iron temperature in the blast furnace. The operation support system is expected to provide staff with useful information.

  12. TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies during Pulverized Coal Injection (PCI) at High Rates

    SciTech Connect

    Veena Sahajwalla; Sushil Gupta

    2005-04-15

    Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

  13. Studies on the corrosion resistance of reinforced steel in concrete with ground granulated blast-furnace slag--An overview.

    PubMed

    Song, Ha-Won; Saraswathy, Velu

    2006-11-16

    The partial replacement of clinker, the main constituent of ordinary Portland cement by pozzolanic or latent hydraulic industrial by-products such as ground granulated blast furnace slag (GGBFS), effectively lowers the cost of cement by saving energy in the production process. It also reduces CO2 emissions from the cement plant and offers a low priced solution to the environmental problem of depositing industrial wastes. The utilization of GGBFS as partial replacement of Portland cement takes advantage of economic, technical and environmental benefits of this material. Recently offshore, coastal and marine concrete structures were constructed using GGBFS concrete because high volume of GGBFS can contribute to the reduction of chloride ingress. In this paper, the influence of using GGBFS in reinforced concrete structures from the durability aspects such as chloride ingress and corrosion resistance, long term durability, microstructure and porosity of GGBFS concrete has been reviewed and discussed. PMID:16930831

  14. Effect of the content of the crystalline and vitreous phases of blast-furnace slags on their properties

    SciTech Connect

    Gindis, Ya.P.

    1987-10-01

    Studies carried out on the hydrochannel granulation plant with a variety of blast-furnace slag from the southern Ukraine determined that, depending on their cooling conditions, it was possible to obtain materials with differing contents of the crystalline and glassy phases which have different porosities. These studies showed that, depending on the changes in these features, ordinary (solid) or porous granulated slag or slag pumice with different properties was obtained. The dependence of the hydraulic activity of the materials obtained (and cements based on them) on the cooling conditions of the melts (specific flow rates of water) has been shown to have an extremum and a maximum. The maximum value of the hydraulic activity has been determined to correspond to granulated slag which has a porous structure and contains 6-26% crystalline phase (mainly melilite), while the remainder consists of amorphous and devitrified glass, the content of the latter being of the order of 20-40%.

  15. The radiation stability of ground granulated blast furnace slag/ordinary Portland cement grouts containing organic admixtures

    SciTech Connect

    Palmer, J.D.; Fairhall, G.A.

    1993-12-31

    At the British Nuclear Fuels (BNFL) Sellafield reprocessing plant in the United Kingdom, cement grouts based on ground granulated blast-furnace slag (BFS) and ordinary Portland cement (OPC) are used extensively for immobilizing radioactive wastes. These grouts have excluded organic admixtures in order to reduce process complexity and uncertainties, regarding the performance of organic admixtures with BFS/OPC grouts, particularly under irradiation. This study has investigated the effects of sulfonated melamine formaldehyde and naphthalene condensates on grout properties. The results show grout settlement and strengths increase on addition of additives, with the additives remaining largely in the pore solution. Under irradiation the additives breakdown liberating hydrogen and carbon dioxide. Strength and product dimensions are unaffected by irradiation.

  16. Use of Artificial Neural Network for the Simulation of Radon Emission Concentration of Granulated Blast Furnace Slag Mortar.

    PubMed

    Jang, Hong-Seok; Xing, Shuli; Lee, Malrey; Lee, Young-Keun; So, Seung-Young

    2016-05-01

    In this study, an artificial neural networks study was carried out to predict the quantity of radon of Granulated Blast Furnace Slag (GBFS) cement mortar. A data set of a laboratory work, in which a total of 3 mortars were produced, was utilized in the Artificial Neural Networks (ANNs) study. The mortar mixture parameters were three different GBFS ratios (0%, 20%, 40%). Measurement radon of moist cured specimens was measured at 3, 10, 30, 100, 365 days by sensing technology for continuous monitoring of indoor air quality (IAQ). ANN model is constructed, trained and tested using these data. The data used in the ANN model are arranged in a format of two input parameters that cover the cement, GBFS and age of samples and, an output parameter which is concentrations of radon emission of mortar. The results showed that ANN can be an alternative approach for the predicting the radon concentration of GBFS mortar using mortar ingredients as input parameters. PMID:27483913

  17. [Evaluation of the migration of contaminants from building materials produced on the base of blast-furnace slags].

    PubMed

    Pugin, K G; Vaysman, Ya I

    2014-01-01

    There is experimentally established the change of the migratory activity of pollutants from building materials produced from blast furnace slag throughout their life cycle in the form of a nonlinear wave-like nature as there are appeared newly opened surfaces of a contact with aggressive waters in the process of gradual crushing of materials as a result of destructive mechanical effects on him and corrosive waters with varying pH values. There are established regularities of the migration activity ofpollutants (on the example of heavy metals) as directly dependent on the newly opening surface of the contact of the material with water having a various pH value. There is shown an expediency of introduction of alterations in the procedure for sanitary hygienic assessment of building materials with the addition of industrial waste (Methodical Instructions 2.1.674-97), allowing to take into account the migration of contaminants from them throughout the life cycle. PMID:25842493

  18. Trace metals related to historical iron smelting at Hopewell Furnace National Historic Site, Berks and Chester Counties, Pennsylvania

    USGS Publications Warehouse

    Sloto, Ronald A.

    2011-01-01

    Iron ore containing elevated concentrations of trace metals was smelted at Hopewell Furnace during its 113 years of operation (1771-1883). The ore used at Hopewell Furnace was obtained from iron mines within 5 miles of the furnace. The iron-ore deposits were formed about 200 million years ago and contain abundant magnetite, the primary iron mineral, and accessory minerals enriched in arsenic, cobalt, copper, lead, and other metals. Hopewell Furnace, built by Mark Bird during 1770-71, was one of the last of the charcoal-burning, cold-blast iron furnaces operated in Pennsylvania. The most productive years for Hopewell Furnace were from 1830 to 1837. Castings were the most profitable product, especially the popular Hopewell Stove. More than 80,000 stoves were cast at Hopewell, which produced as many as 23 types and sizes of cooking and heating stoves. Beginning in the 1840s, the iron industry shifted to large-scale, steam-driven coke and anthracite furnaces. Independent rural enterprises like Hopewell could no longer compete when the iron and steel industries consolidated in urban manufacturing centers. The furnace ceased operation in 1883 (Kurjack, 1954). The U.S. Geological Survey (USGS), in cooperation with the National Park Service, completed a study at Hopewell Furnace National Historic Site (NHS) in Berks and Chester Counties, Pennsylvania, to determine the fate of toxic trace metals, such as arsenic, cobalt, and lead, released into the environment during historical iron-smelting operations. The results of the study, conducted during 2008-10, are presented in this fact sheet.

  19. Sulfur Transfer via Gas Phase in Iron-making Blast Furnace under Intensive Coal Injection

    NASA Astrophysics Data System (ADS)

    Yoshiyuki, Matsui; Rikizou, Tadai; Kenji, Ito; Tadasu, Matsuo; Korehito, Kadoguchi; Reiji, Ono

    The steel industry will move toward more value additive products in the future. In order to support the value additive steel products, iron sources have to be secured with stable operation of furnaces and control of furnace have to be evolved. Environment consciousness including CO2 reduction leads more toward lower reducing agents ratio operation. It is common technical issue on both the more value additive products the environment consciousness to control the sulfur in the hot metal, slag and gas phase.In the present study, the amount of sulfur gasification was measured by combustion experiments with the attention on the simultaneous gasification of sulfur with carbon. By description of sulfurization from gas to burden materials based on the temperature distribution measured in actual furnace, the amount of sulfur transferred to gas was evaluated.

  20. Wood-burning stove

    SciTech Connect

    Hicks, A.W.; Jolicoeur, G.D.

    1981-05-19

    A wood stove is of all welded steel plate construction except for the door which is of heavy cast iron. When the door is closed, the only source of combustion air is through an adjustable air inlet on the face of the door. The door is hollow and serves to preheat the incoming air. The inner wall of the door divides the incoming air into lower and upper, primary and secondary, respectively, combustion air flows. The stove has an internal upper baffle running from rear to front which helps to promote air flow and combustion efficiency and to knock out entrained matter from the products of combustion. The flue connection is in the rear of the stove above the baffle and is stepped into the back of the stove to allow the stove to be fitted against a wall.

  1. Simultaneous removal of Ni(II), As(III), and Sb(III) from spiked mine effluent with metakaolin and blast-furnace-slag geopolymers.

    PubMed

    Luukkonen, Tero; Runtti, Hanna; Niskanen, Mikko; Tolonen, Emma-Tuulia; Sarkkinen, Minna; Kemppainen, Kimmo; Rämö, Jaakko; Lassi, Ulla

    2016-01-15

    The mining industry is a major contributor of various toxic metals and metalloids to the aquatic environment. Efficient and economical water treatment methods are therefore of paramount importance. The application of natural or low-cost sorbents has attracted a great deal of interest due to the simplicity of its process and its potential effectiveness. Geopolymers represent an emerging group of sorbents. In this study, blast-furnace-slag and metakaolin geopolymers and their raw materials were tested for simultaneous removal of Ni(II), As(III) and Sb(III) from spiked mine effluent. Blast-furnace-slag geopolymer proved to be the most efficient of the studied materials: the experimental maximum sorption capacities for Ni, As and, Sb were 3.74 mg/g, 0.52 mg/g, and 0.34 mg/g, respectively. Although the capacities were relatively low due to the difficult water matrix, 90-100% removal of Ni, As, and Sb was achieved when the dose of sorbent was increased appropriately. Removal kinetics fitted well with the pseudo-second-order model. Our results indicate that geopolymer technology could offer a simple and effective way to turn blast-furnace slag to an effective sorbent with a specific utilization prospect in the mining industry. PMID:26598283

  2. Determination of the state of the hearth of BHP Steel's blast furnaces

    SciTech Connect

    Rex, A.; Skimmings, T.; Jelenich, L. . Rod and Bar Products Division); Zulli, P. . Newcastle Laboratories); Plat, P.; Tanzil, W.F. . Slab and Plate Products Division)

    1993-01-01

    A computer model has been developed which calculates the internal profile of the hearth from thermocouples placed in the bottom and side walls. The model accounts for both erosion of the refractory material, and the formation of skull on the refractory surfaces. Analysis of the hearth on a regular basis, by visualizing the three-dimensional hearth profile and by calculating the effective hearth liquid volume, has proved to be an effective means of evaluating the influence of feedstock (e.g. coke mean size) and operating practices on the hearth performance, and hence impacts on the furnace life.

  3. Thermal treatment of simulant plutonium contaminated materials from the Sellafield site by vitrification in a blast-furnace slag

    NASA Astrophysics Data System (ADS)

    Hyatt, N. C.; Schwarz, R. R.; Bingham, P. A.; Stennett, M. C.; Corkhill, C. L.; Heath, P. G.; Hand, R. J.; James, M.; Pearson, A.; Morgan, S.

    2014-01-01

    Four waste simulants, representative of Plutonium Contaminated Materials (PCMs) at the Sellafield site, were vitrified through additions of Ground Granulated Blast-furnace Slag (GGBS). Ce (as a Pu surrogate) was effectively partitioned into the slag product, enriched in an amorphous CaO-Fe2O3-Al2O3-SiO2 phase when other crystalline phases were also present. Ce L3 edge XANES data demonstrated Ce to be present as trivalent species in the slag fraction, irrespective of the waste type. Estimated volume reductions of ca. 80-95% were demonstrated, against a baseline of uncompacted 200 L PCM waste drums. The dissolution behaviour of PCM slag wasteforms was investigated at 50 °C in saturated Ca(OH)2 solution under N2 atmosphere, to simulate the hyperalkaline anoxic environment of a cementitious UK Geological Disposal Facility for Intermediate Level Waste (ILW). These experiments demonstrated the performance of the slag wasteforms to be comparable to that of other vitrified ILW materials considered potentially suitable for geological disposal.

  4. Multiscale and Fractal Analysis of Silicon Content Time Series Observed in Blast Furnace Hot Metal Using Hurst Exponent Chain

    NASA Astrophysics Data System (ADS)

    Luo, Shihua; Guo, Fan; Lai, Dejian; Yan, Fang; Tang, Feilai

    2015-09-01

    Hurst exponent is an important measure of nonlinearity of dynamical time series. In this paper, using rescaled-range (R/S) analysis, multi-fractal detrended fluctuation analysis (MF-DFA) methods, the multiscale Hurst exponent (MHE) and the multiscale generalized Hurst exponent (MGHE) of coarse-grained silicon content ([Si]) time series in blast furnace (BF) hot metal were calculated. First, we collected these [Si] time series from No. 1 BF of Nanchang Iron and Steel Co. and No. 10 BF of Xinyu Iron and Steel Co. in Jiangxi Province, China. Then, we analyzed and compared the estimated Hurst exponents and the generalized Hurst exponent of these observed time series with some simulated time series. Our results show that the observed time series from these BFs have negative correlation with the Hurst exponent less than 0.5, the generalized Hurst exponent H(q) is a nonlinear function of q, and such negative correlation and local various structure persist in their moving averages of the observed time series up to lag 5 or 10.

  5. Analysis on the Oversize Blast Furnace Desulfurization and a Sulfide Capacity Prediction Model Based on Congregated Electron Phase

    NASA Astrophysics Data System (ADS)

    Zhenyang, Wang; Jianliang, Zhang; Gang, An; Zhengjian, Liu; Zhengming, Cheng; Junjie, Huang; Jingwei, Zhang

    2016-02-01

    Through analyzed and regressed the actual productive desulfurization data from the oversize blast furnace (5500 m3) in north China, the relationship between the sulfur distribution parameters and the slag composition in actual production situation was investigated. As the slag and hot metal phases have their own balance sulfur content or sulfur partial pressure in gas phase, respectively, the non-equilibrium of sulfur among gas, slag, and metal phases leads to the transmission and distribution of sulfur. Combined with sulfur transmission reactions between gas, slag and metal phases, C/CO pairs equilibrium, and Wagner model, the measured sulfide capacity can be acquired using sulfur distribution ratio, sulfur activity coefficient, and oxygen activity in hot metal. Based on the theory of congregated electron phase, a new sulfide capacity prediction model (CEPM) has been developed, which has a good liner relationship with the measured sulfide capacity. Thus, using the burden structure for BF, the ironmaking slag composition can be obtained simply and can be used to reliably predict the ironmaking slag desulfurization ability a few hours later after charging under a certain temperature by CEPM.

  6. Recycling ground granulated blast furnace slag as cold bonded artificial aggregate partially used in self-compacting concrete.

    PubMed

    Gesoğlu, Mehmet; Güneyisi, Erhan; Mahmood, Swara Fuad; Öz, Hatice Öznur; Mermerdaş, Kasım

    2012-10-15

    Ground granulated blast furnace slag (GGBFS), a by-product from iron industry, was recycled as artificial coarse aggregate through cold bonding pelletization process. The artificial slag aggregates (ASA) replaced partially the natural coarse aggregates in production of self-compacting concrete (SCC). Moreover, as being one of the most widely used mineral admixtures in concrete industry, fly ash (FA) was incorporated as a part of total binder content to impart desired fluidity to SCCs. A total of six concrete mixtures having various ASA replacement levels (0%, 20%, 40%, 60%, and 100%) were designed with a water-to-binder (w/b) ratio of 0.32. Fresh properties of self-compacting concretes (SCC) were observed through slump flow time, flow diameter, V-funnel flow time, and L-box filling height ratio. Compressive strength of hardened SCCs was also determined at 28 days of curing. It was observed that increasing the replacement level of ASA resulted in decrease in the amount of superplasticizer to achieve a constant slump flow diameter. Moreover, passing ability and viscosity of SCC's enhanced with increasing the amount of ASA in the concrete. The maximum compressive strength was achieved for the SCC having 60% ASA replacement. PMID:22951223

  7. Preparation of a new sorbent with hydrated lime and blast furnace slag for phosphorus removal from aqueous solution.

    PubMed

    Gong, Guozhuo; Ye, Shufeng; Tian, Yajun; Wang, Qi; Ni, Jiandi; Chen, Yunfa

    2009-07-30

    The removal of dissolvable inorganic phosphate (H(2)PO(4)(-)) by sorbents prepared from hydrated lime (HL) and blast furnace slag (BFS) was fundamentally studied by an orthogonal experiment design. Based on statistic analysis, it is revealed that the weight ratio of BFS/HL is the most significant variable, and an optimized preparation condition is figured out. With the increase of HL content, the adsorption capacity increases, suggesting that the HL plays the important role in the removal process in the gross. However, in the lower HL content, it is interesting that the adsorption capacity of as-prepared sorbents exceed the sum of the capacities of the same ratio of BFS and HL. The further analysis indicate the excess capacities linearly depend on the specific surface area of sorbents, suggesting that the removal of H(2)PO(4)(-) is closely related with the microstructure of sorbents in the lower HL content, according to the characterization with SEM, XRD and pore analysis. Additionally, an adsorption model and kinetic are discussed in this paper. PMID:19124194

  8. Effect of TiO2 Content on the Crystallization Behavior of Titanium-Bearing Blast Furnace Slag

    NASA Astrophysics Data System (ADS)

    Hu, Meilong; Wei, Ruirui; Yin, Fangqing; Liu, Lu; Deng, Qingyu

    2016-07-01

    The content of TiO2 has an important influence on both the basic structure and the crystallization behavior of titanium-bearing blast furnace (BF) slag. The results of thermodynamic calculations show that, when the mass content of TiO2 is smaller than 25%, CaTiO3 increases as the content of TiO2 increases. However, when the TiO2 content is more than 25%, the CaTiO3 content decreases and TiO2 gradually increases. The results of a confocal laser scanning microscopy (CLSM) experiment show that, when the TiO2 mass content is 10%, Ca2MgSi2O7 and Ca2Al2SiO7 are the main crystallized phases resulting from the molten slag. Furthermore, when the TiO2 mass content is 20%, CaMgSi2O6, Ca(Ti,Mg,Al)(Si,Al)2O7 and dendrite CaTiO3 are the crystallized phases, while when the TiO2 mass content increases to 30%, CaTiO3 is the sole phase. The discrepancy between the CLSM results and the thermodynamic calculations occurs mainly due to the high melting point of the titanium-bearing BF slag. During the cooling process for the molten slag, CaTiO3 is crystallized first, due to its high crystallization temperature. Furthermore, the molten slag is solidified in its entirety before the other phases crystallize.

  9. Effect of Al2O3 Addition on the Precipitated Phase Transformation in Ti-Bearing Blast Furnace Slags

    NASA Astrophysics Data System (ADS)

    Li, Zhongmin; Li, Jinfu; Sun, Yongqi; Seetharaman, Seshadri; Liu, Lili; Wang, Xidong; Zhang, Zuotai

    2016-04-01

    The present paper aims to provide a fundamental understanding on phase change of Ti-enriched crystalline phase induced by Al2O3 addition in Ti-bearing blast furnace slags with different basicities using Single Hot Thermocouple Technique and X-ray Diffraction. The results showed that an increase in the Al2O3 content led to phase change from rutile or perovskite to Mg3Al4Ti8O25 and prompted crystallization of the slags with basicity of 0.60 and 0.75, whereas only CaTiO3 was precipitated at a basicity of 0.95. Both thermodynamic and kinetic analyses were conducted to study the slag crystallization, which would throw light on phase change and enhanced crystallization. To further reveal the relationship with Al2O3 addition on slag structure and crystallization, Fourier transform infrared spectroscopy and magic angle spinning-nuclear magnetic resonance were adopted, with AlO4 tetrahedra and AlO6 octahedra observed in the slag. For slags with the basicity of 0.60 and 0.75, AlO6 octahedron, which was suggested to induce the phase change from TiO2 or CaTiO3 to Mg3Al4Ti8O25, was detected at high Al2O3 content. On the other hand, in slags with the basicity of 0.95, abundant Ca2+ may be connected to TiO6 octahedra, resulting in CaTiO3 formation.

  10. Novel blast furnace operation process involving charging with low-titanium vanadium-titanium magnetite carbon composite hot briquette

    NASA Astrophysics Data System (ADS)

    Zhao, Wei; Chu, Man-sheng; Wang, Hong-tao; Liu, Zheng-gen; Tang, Ya-ting

    2016-05-01

    An innovative process of blast furnace (BF) operation involving charging with low-titanium vanadium-titanium magnetite carbon composite hot briquette (LVTM-CCB) was proposed for utilizing LVTM and conserving energy. In this study, the effect of LVTM-CCB charging ratio on the softening, melting, and dripping behaviors of the mixed burden was explored systemically, and the migration of valuable elements V and Cr was extensively investigated. The results show that with increasing LVTM-CCB charging ratio, the softening interval T 40 - T 4 increases from 146.1°C to 266.1°C, and the melting interval T D - T S first decreases from 137.2°C to 129.5°C and then increases from 129.5°C to 133.2°C. Moreover, the cohesive zone becomes narrower and then wider, and its location shifts slightly downward. In addition, the recovery ratios of V and Cr in dripped iron first increase and then decrease, reaching maximum values of 14.552% and 28.163%, respectively, when the charging ratio is 25%. A proper LVTM-CCB charging ratio would improve the softening-melting behavior of the mixed burden; however, Ti(C,N) would be generated rapidly in slag when the charging ratio exceeds 25%, which is not favorable for BF operation. When considering the comprehensive softening-melting behavior of the mixed burden and the recovery ratios of V and Cr, the recommended LVTM-CCB charging ratio is 20%.

  11. Properties of mortars made by uncalcined FGD gypsum-fly ash-ground granulated blast furnace slag composite binder.

    PubMed

    Zhong, Shiyun; Ni, Kun; Li, Jinmei

    2012-07-01

    A series of novel mortars were developed from composite binder of uncalcined FGD gypsum, fly ash (FA) and ground granulated blast furnace slag (GGBFS) for the good utilization of flue gas desulphurization (FGD) gypsum. At a fixed ratio (20%) of GGBFS to the composite binder, keeping consistency of the mortar between 9.5 and 10.0 cm, the properties of the composite mortar were studied. The results show that higher water/binder (W/B) is required to keep the consistency when increasing the percentage of FGD gypsum. No obvious influences of the W/B and content of FGD gypsum on the bleeding of paste were observed which keeps lower than 2% under all experimental conditions tried. The highest compressive and flexural strengths (ratio is 20% FGD gypsum, 20% GGBFS and 60% FA) are 22.6 and 4.3 MPa at 28 days, respectively. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) results indicate that massive ettringite crystals and C-S-H gels exist in the hydration products. At 90 days the mortars with FGD gypsum is dramatically smaller drying shrinkage (563-938 micro strain) than that without FGD gypsum (about 2250 micro strain). The release of the SO(4)(2-) from the mortar was analyzed, indicating that the dissolution of sulfate increases with FGD gypsum. The concentration of SO(4)(2-) releasing from the mortar with 10% FGD gypsum is almost equal to that obtained from the mortar without FGD gypsum. The release of SO(4)(2-) from the mortar with 20% FGD gypsum is 9200 mg·m(-2), which is lower than that from the mortar with 95% cement clinker and 5% FGD gypsum. PMID:22440404

  12. Properties of mortars made by uncalcined FGD gypsum-fly ash-ground granulated blast furnace slag composite binder

    SciTech Connect

    Zhong Shiyun; Ni Kun; Li Jinmei

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer The mortar with uncalcined FGD gypsum has suitable workability. Black-Right-Pointing-Pointer The strength of mortar with uncalcined FGD gypsum is higher than that of mortar without uncalcined FGD gypsum. Black-Right-Pointing-Pointer The dry shrinkage of mortar with uncalcined FGD gypsum is lower than that of mortar without uncalcined FGD gypsum. Black-Right-Pointing-Pointer The leaching of sulfate ion of mortar is studied. - Abstract: A series of novel mortars were developed from composite binder of uncalcined FGD gypsum, fly ash (FA) and ground granulated blast furnace slag (GGBFS) for the good utilization of flue gas desulphurization (FGD) gypsum. At a fixed ratio (20%) of GGBFS to the composite binder, keeping consistency of the mortar between 9.5 and 10.0 cm, the properties of the composite mortar were studied. The results show that higher water/binder (W/B) is required to keep the consistency when increasing the percentage of FGD gypsum. No obvious influences of the W/B and content of FGD gypsum on the bleeding of paste were observed which keeps lower than 2% under all experimental conditions tried. The highest compressive and flexural strengths (ratio is 20% FGD gypsum, 20% GGBFS and 60% FA) are 22.6 and 4.3 MPa at 28 days, respectively. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) results indicate that massive ettringite crystals and C-S-H gels exist in the hydration products. At 90 days the mortars with FGD gypsum is dramatically smaller drying shrinkage (563-938 micro strain) than that without FGD gypsum (about 2250 micro strain). The release of the SO{sub 4}{sup 2-} from the mortar was analyzed, indicating that the dissolution of sulfate increases with FGD gypsum. The concentration of SO{sub 4}{sup 2-} releasing from the mortar with 10% FGD gypsum is almost equal to that obtained from the mortar without FGD gypsum. The release of SO{sub 4}{sup 2-} from the mortar with 20% FGD gypsum is 9200 mg

  13. 38. 8 sisters and powerhouse, pulverizer building for powerhouse, coal ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    38. 8 sisters and powerhouse, pulverizer building for powerhouse, coal conveyor, blast stoves, "A" furnace, stoves, "B" furnace, stoves, "C" furnace, bottle cars. Looking south - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  14. Stove-hearth combinations

    SciTech Connect

    Nesje, A.

    1980-08-26

    Stove-hearth combinations are described that are comprised of a combustion chamber having a pair of side walls supported on a base in opposing relation and joined by a rear wall. A cover or hood defines with the base and front edges of the side walls an opening to the chamber. Two doors are each hingedly associated with upper and lower pivot pins which when the door is in a closed position are disposed adjacent but outside a respective side wall front edge. Along upper and lower side edges of each side wall are formed parallel grooves adapted to be engaged slidably by the upper and lower pivot pins. As the door is opened from a stove to a hearth position the pivot pins are displaced along the grooves causing the door to be led gradually into a position along the outer side of its side wall.

  15. 50. Taken from highline; "B" furnace slag pots, pipe is ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    50. Taken from high-line; "B" furnace slag pots, pipe is main blast furnace gas line from "C" furnace dust catcher; levy, slag hauler, removing slag. Looking east - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  16. Quantitative metrics of stove adoption using Stove Use Monitors (SUMs)

    PubMed Central

    Ruiz-Mercado, Ilse; Canuz, Eduardo; Walker, Joan L.; Smith, Kirk R.

    2014-01-01

    The sustained use of cookstoves that are introduced to reduce fuel use or air pollution needs to be objectively monitored to verify the sustainability of these benefits. Quantifying stove adoption requires affordable tools, scalable methods and validated metrics of usage. We quantified the longitudinal patterns of chimney-stove use of 80 households in rural Guatemala, monitored with Stove Use Monitors (SUMs) during 32 months. We counted daily meals and days in use at each monitoring period and defined metrics like the percent stove-days in use (the fraction of days in use from all stoves and days monitored). Using robust Poisson regressions we detected small seasonal variations in stove usage, with peaks in the warm-dry season at 92% stove-days (95%CI: 87%,97%) and 2.56 average daily meals (95%CI: 2.40,2.74). With respect to these values, the percent stove-days in use decreased by 3% and 4% during the warm-rainy and cold-dry periods respectively, and the daily meals by 5% and 12% respectively. Cookstove age and household size at baseline did not affect usage. Qualitative indicators of use from recall questionnaires were consistent with SUMs measurements, indicating stable sustained use and questionnaire accuracy. These results reflect optimum conditions for cookstove adoption and for monitoring in this project, which may not occur in disseminations undertaken elsewhere. The SUMs measurements suggests that 90% stove-days is a more realistic best-case for sustained use than the 100% often assumed. Half of sample reported continued use of open-cookfires, highlighting the critical need to verify reduction of open-fire practices in stove disseminations. PMID:25258474

  17. 102. Giullotine type gate (inclosed position to regulate furnace exhaust ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    102. Giullotine type gate (inclosed position to regulate furnace exhaust gases to stoves during heating cycle. - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  18. Performance of polish home stoves

    SciTech Connect

    Jaszczur, T.; Lewandowski, M.; Szewczyk, W.; Zaczkowski, A.; Butcher, T.

    1994-06-01

    Most of the city of Krakow, Poland is heated by either the central district heating system or single-building boilers, gas or coal-fired. In addition, concentrated in the older, central part of the city, there are many traditional, coal-fired tile stoves. It is currently estimated that there are 100,000 such stoves in Krakow with an annual coal consumption of 130,000 metric tons. These are felt to be important contributors to Krakow`s air quality problems. It his been estimated that there are about 7 million of these stoves throughout the country of Poland.These are very large masonry stoves with ornate file exterior. They are built in place by specialized craftsmen and often two or more stoves will be used to heat a single flat. During the heating season these stoves are fired once or twice each day. For each firing the owner will carry a bucket of coal up from a basement storage area. light a new fire, and then tend it occasionally for about one hour. During this time the masonry is heated and this stored heat keeps the flat warm for the next 12 hours. A testing effort on these tile stoves has been conducted as part of the Krakow lean Fossil Fuels and Energy Efficiency Program, sponsored by the US Government through the Agency for International Development (AID) and the US Department of Energy (DOE). One of the objectives of this testing program was to provide baseline thermal efficiency and emissions data as input to evaluations of costs and benefits of alternative options for heating these flats. The second Primary objective was to provide at least a preliminary assessment of the possibility of reducing emissions by using improved fuels in these stoves.

  19. Phase Equilibrium Studies of CaO-SiO2-MgO-Al2O3 System with Binary Basicity of 1.5 Related to Blast Furnace Slag

    NASA Astrophysics Data System (ADS)

    Kou, Mingyin; Wu, Shengli; Ma, Xiaodong; Wang, Laixin; Chen, Mao; Cai, Qingwu; Zhao, Baojun

    2016-04-01

    Slags play an important role in blast furnace operation, and their compositions are based on the CaO-SiO2-MgO-Al2O3 quaternary system in many steel companies. The binary basicity (CaO/SiO2 weight ratio) of blast furnace slags, especially primary slag and bosh slag, can be as high as 1.5 or higher. Phase equilibria and liquidus temperatures in the CaO-SiO2-MgO-Al2O3 system with binary basicity of 1.50 are experimentally determined for temperatures in the range 1723 K to 1823 K (1450 °C to 1550 °C). High temperature equilibration, quenching, and electron probe X-ray microanalysis techniques have been used in the present study. The isotherms are obtained in the primary phase fields of Ca2SiO4, melilite, spinel, periclase, and merwinite related to blast furnace slags. Effects of Al2O3, MgO, and binary basicity on liquidus temperatures have been discussed. In addition, extensive solid solutions have been measured for different primary phases and will be used for development and optimization of the thermodynamic database.

  20. Improved Biomass Cooking Stoves and Improved Stove Emission Equipment

    SciTech Connect

    HATFIELD, MICHAEL; Still, Dean

    2013-04-15

    In developing countries, there is an urgent need for access to safe, efficient, and more affordable cooking technologies. Nearly 2.5 billion people currently use an open fire or traditional cookstove to prepare their meals, and recent models predict that use of biomass for cooking will continue to be the dominant energy use in rural, resource-poor households through 2030. For these families, cooking poses serious risks to health, safety, and income. An alarming 4 million people, primarily women and children, die prematurely each year from indoor and outdoor exposure to the harmful emissions released by solid fuel combustion. Use of traditional stoves can also have a significant impact on deforestation and climate change. This dire situation creates a critical need for cookstoves that significantly and verifiably reduce fuel use and emissions in order to reach protective levels for human health and the environment. Additionally, advances in the scientific equipment needed to measure and monitor stove fuel use and emissions have not kept pace with the significant need within the industry. While several testing centers in the developed world may have hundred thousand-dollar emissions testing systems, organizations in the field have had little more than a thermometer, a scale, and subjective observations to quantify the performance of stove designs. There is an urgent need for easy-to-use, inexpensive, accurate, and robust stove testing equipment for use by laboratory and field researchers around the world. ASAT and their research partner, Aprovecho Research Center (ARC), have over thirty years of experience addressing these two needs, improved cookstoves and emissions monitoring equipment, with expertise spanning the full spectrum of development from conceptual design to product manufacturing and dissemination. This includes: 1) research, design, and verification of clean biomass cookstove technology and emissions monitoring equipment; 2) mass production of quality

  1. [Solidification/Stabilization of Chromite Ore Processing Residue (COPR) Using Zero-Valent Iron and Lime-Activated Ground Granulated Blast Furnace Slag].

    PubMed

    Chen, Zhong-lin; Li, Jin-chunzi; Wang, Bin-yuan; Fan, Lei-tao; Shen, Ji-min

    2015-08-01

    The solidification/stabilization (S/S) of chromite ore processing residue (COPR) was performed using zero-valent iron (ZVI) and lime-activated ground granulated blast furnace slag (GGBFS). The degree of Cr immobilization was evaluated using the leaching procedure, mineral composition analysis and morphology analysis. Semi-dynamic leaching tests were implemented to investigate the potential for reusing the final treatment product as a readily available construction material. The results showed that after reduction, all of the S/S treated COPR samples met the pollution control limit of bricks and building block products (Chinese standard HJ/T 301-2007) produced with COPR for total Cr (0.3 mg x L(-1)), the compressive strength of all the S/S samples could meet the compressive strength standard (15 MPa) for producing clay bricks, and Cr existed as the specie that bound to Fe/Mn oxides in the S/S samples. At the same time, all of the S/S treated specimens tested were suitable for utilization at certain levels. PMID:26592036

  2. The enhancement effect of pre-reduction using zero-valent iron on the solidification of chromite ore processing residue by blast furnace slag and calcium hydroxide.

    PubMed

    Li, Jinchunzi; Chen, Zhonglin; Shen, Jimin; Wang, Binyuan; Fan, Leitao

    2015-09-01

    A bench scale study was performed to assess the effectiveness of the solidification of chromite ore processing residue (COPR) by blast furnace slag and calcium hydroxide, and investigate the enhancement effect of pre-reduction using zero-valent iron (ZVI) on the solidification treatment. The degree of Cr immobilization was evaluated using the Toxicity Characteristic Leaching Procedure (TCLP) as well as the solid waste-extraction procedure for leaching toxicity-sulfuric acid & nitric acid method (Chinese standard HJ/T299-2007). Strength tests and semi-dynamic leaching tests were implemented to investigate the potential for reusing the final treatment product as a readily available construction material. The experimental results showed that the performance of pre-reduction/solidification (S/S) was superior to that of solidification alone. After pre-reduction, all of the S/S treated COPR samples met the TCLP limit for total Cr (5 mg L(-1)), whereas the samples with a COPR content below 40% met the pollution control limit of bricks and building block products (Chinese standard HJ/T 301-2007) produced with COPR for total Cr (0.3 mg L(-1)). At the same time, all of the S/S treated specimens tested were suitable for utilization at certain levels. PMID:25929874

  3. Influence of aluminium nitride as a foaming agent on the preparation of foam glass-ceramics from high-titanium blast furnace slag

    NASA Astrophysics Data System (ADS)

    Shi, Huan; Feng, Ke-qin; Wang, Hai-bo; Chen, Chang-hong; Zhou, Hong-ling

    2016-05-01

    To effectively reuse high-titanium blast furnace slag (TS), foam glass-ceramics were successfully prepared by powder sintering at 1000°C. TS and waste glass were used as the main raw materials, aluminium nitride (AlN) as the foaming agent, and borax as the fluxing agent. The influence of the amount of AlN added (1wt%-5wt%) on the crystalline phases, microstructure, and properties of the produced foam glass-ceramics was studied. The results showed that the main crystal phases were perovskite, diopside, and augite. With increasing AlN content, a transformation from diopside to augite occurred and the crystallinity of the pyroxene phases slightly decreased. Initially, the average pore size and porosity of the foam glass-ceramics increased and subsequently decreased; similarly, their bulk density and compressive strength decreased and subsequently increased. The optimal properties were obtained when the foam glass-ceramics were prepared by adding 4wt% AlN.

  4. Improvement of ground granulated blast furnace slag on stabilization/solidification of simulated mercury-doped wastes in chemically bonded phosphate ceramics.

    PubMed

    Liu, Zhongzhe; Qian, Guangren; Zhou, Jizhi; Li, Chuanhua; Xu, Yunfeng; Qin, Zhe

    2008-08-30

    This paper investigated the effectiveness of (ground granulated blast furnace slag) GGBFS-added chemically bonded phosphate ceramic (CBPC) matrix on the stabilization/solidification (S/S) of mercury chloride and simulated mercury-bearing light bulbs (SMLB). The results showed that the maximal compressive strength was achieved when 15% and 10% ground GGBFS was added for HgCl(2)-doped and SMLB-doped CBPC matrices, respectively. The S/S performances of GGBFS-added matrices were significantly better than non-additive matrices. As pore size was reduced, the leaching concentration of Hg(2+) from GGBFS-added CBPC matrix could be reduced from 697 microg/L to about 3 microg/L when treating HgCl(2). Meanwhile, the main hydrating product of GGBFS-added matrices was still MgKPO(4).6H(2)O. The improvement of S/S effectiveness was mainly due to physical filling of fine GGBFS particles and microencapsulation of chemical cementing gel. PMID:18289781

  5. Hopewell Furnace National Historic Site. Teacher's Guide.

    ERIC Educational Resources Information Center

    National Park Service (Dept. of Interior), Washington, DC.

    This teacher's guide contains activities to use in conjunction with a site visit to the Hopewell Furnace National Historic Site (Elverson, Pennsylvania). The guide provides diagrams of the furnace, a cold-blast smelting operation, and the furnace operation. It presents a timeline of iron production from ancient times through contemporary times.…

  6. [Death on a sauna stove].

    PubMed

    Guddat, Saskia Sabrina; Tsokos, Michael

    2007-01-01

    A 67-year-old woman noticed a strange smell from the cellar of her house. When she followed the smell, she found her 64-year-old husband with the face and upper part of his body lying on the stove of the private sauna. He was dead when the emergency doctor arrived. The autopsy revealed upper gastrointestinal bleeding from mucosal lesions in the esophagus with an agonal fall on the sauna stove as the cause of death. In addition, there were signs of chronic alcohol and drug abuse. PMID:18020143

  7. Use of CaO as an activator for producing a price-competitive non-cement structural binder using ground granulated blast furnace slag

    SciTech Connect

    Kim, Min Sik; Jun, Yubin; Lee, Changha Oh, Jae Eun

    2013-12-15

    The use of calcium oxide (CaO) demonstrates a superior potential for the activation of ground granulated blast furnace slag (GGBFS), and it produces a higher mechanical strength than calcium hydroxide [Ca(OH){sub 2}]. The mechanical strength differences between CaO- and Ca(OH){sub 2}-activated GGBFS binders are explored using isothermal calorimetry, powder X-ray diffraction, thermogravimetric and differential thermal analysis (TGA and DTA) as well as compressive strength testing. Calcium silicate hydrate (C–S–H), Ca(OH){sub 2} and a hydrotalcite-like phase are found as reaction products in all samples. The TGA and DTA results indicate that the use of CaO produces more C–S–H, although this is not likely to be the primary cause of higher strength development in the CaO-activated GGBFS. Rather, other factors such as porosity may govern the strength at a higher order of magnitude. Significant reduction of Ca(OH){sub 2} occurs only with the use of Ca(OH){sub 2}, followed by the formation of carbonate (CaCO{sub 3}), indicating carbonation. -- Highlights: •CaO showed a better potential for the activation of GGBFS than Ca(OH){sub 2}. •Strength test, XRD, TGA/DTA and isothermal calorimetry are used. •C-S-H, Ca(OH){sub 2}, and a hydrotalcite-like phase are found in all samples. •The use of Ca(OH){sub 2} causes some degree of carbonation.

  8. Research on coke-oven heating technology and the properties of coke as a blast-furnace fuel. [UKhIN

    SciTech Connect

    Vasil'ev, Yu.S.; Semisalov, L.P.

    1980-01-01

    A fundamentally novel coke-oven system was designed at Giprokoks (underjet, with bottom gas and air regulation) on the basis of data from model experiments. In particular, when batteries of 41.6 m/sup 3/ coke ovens were developed, the results of model tests led to major modifications to the original designs for the regenerator zones, sloping ducts and flues. UKhIN investigations on hot and hydraulic models, using modern mathematical procedures and computers, were used to study the details of heat exchange and gas flow in the regenerator packings under coke ovens. Criterial equations were derived for the coefficients of heat transfer by convection and of hydraulic resistance, covering the specific features of regenerator performance in coke-oven heating systems. Much useful information for the advance of coke-oven technology has been obtained from laboratory, pilot and fullscale plant studies of the thermal properties of coals and blends. Investigations (including blast-furnace trials) in connection with the commercial adoption of dry coke cooling established that during its soaking in the storage chamber the coke undergoes changes in molecular structure, to an extent dependent on the time and temperature. Recommendations based on this research significantly improve the coke strength properties and extended the range of usable coal supplies. Traditionally, the Institute is greatly interested in the problem of coke yields, which has now become very urgent in connection with the use of higher proportions of grade G and other coals with high volatile matters. Detailed studies have been made of the effects of various processing factors on the yields of saleable and metallurgical coke.

  9. 21. Photocopy of ca. 1951 view (when furnaces were still ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    21. Photocopy of ca. 1951 view (when furnaces were still in blast) looking north at central furnace complex with railroad cars of furnace charging materials in foreground and No. 2 Furnace at left. Photo marked on back 'David W. Corson from A. Devaney, N.Y.' - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  10. Afterburner for a wood stove

    SciTech Connect

    Dorach, E.H.; Dorsch, H.

    1984-08-21

    An afterburner for a wood stove for use as a retrofit assembly comprises a rectangular housing having openings in the upper and lower surfaces provided with cylindrical collars for cooperation with the flue duct and with the opening in the top of the wood stove respectively. The openings are positioned at the rear of the housing so as to provide a forward section spaced from the openings. A catalytic combuster mounted in a cylindrical support is movable from a position directly above the opening in the bottom surface into the front section by a manually operable handle extending through the front face of the housing. A baffle mounted on the support and arranged at a shallow angle to the horizontal overlies the major part of the combuster so as to direct gases into the front section of the housing for heat exchange contact with the walls thereof.

  11. Characterisation of Ba(OH){sub 2}–Na{sub 2}SO{sub 4}–blast furnace slag cement-like composites for the immobilisation of sulfate bearing nuclear wastes

    SciTech Connect

    Mobasher, Neda; Bernal, Susan A.; Hussain, Oday H.; Apperley, David C.; Kinoshita, Hajime; Provis, John L.

    2014-12-15

    Soluble sulfate ions in nuclear waste can have detrimental effects on cementitious wasteforms and disposal facilities based on Portland cement. As an alternative, Ba(OH){sub 2}–Na{sub 2}SO{sub 4}–blast furnace slag composites are studied for immobilisation of sulfate-bearing nuclear wastes. Calcium aluminosilicate hydrate (C–A–S–H) with some barium substitution is the main binder phase, with barium also present in the low solubility salts BaSO{sub 4} and BaCO{sub 3}, along with Ba-substituted calcium sulfoaluminate hydrates, and a hydrotalcite-type layered double hydroxide. This reaction product assemblage indicates that Ba(OH){sub 2} and Na{sub 2}SO{sub 4} act as alkaline activators and control the reaction of the slag in addition to forming insoluble BaSO{sub 4}, and this restricts sulfate availability for further reaction as long as sufficient Ba(OH){sub 2} is added. An increased content of Ba(OH){sub 2} promotes a higher degree of reaction, and the formation of a highly cross-linked C–A–S–H gel. These Ba(OH){sub 2}–Na{sub 2}SO{sub 4}–blast furnace slag composite binders could be effective in the immobilisation of sulfate-bearing nuclear wastes.

  12. Solid fuel cooking stoves: International directory

    SciTech Connect

    Not Available

    1981-02-01

    Optimal design and promotion of the use of fuel efficient cooking stoves demand continued interaction and exchange of information between researchers, extension workers, policy makers and others concerned with stove projects. The directory is aimed at listing all the known organisations in this area.

  13. Hopewell Furnace: A Pennsylvania Iron-Making Plantation. Teaching with Historic Places.

    ERIC Educational Resources Information Center

    Koman, Rita G.

    The rhythmic noises of the turning water wheel and the roar of the furnace blast never stopped at Hopewell Furnace (Pennsylvania) during its years of operation (1771-1883). As long as the furnace was in blast, the ironworkers' jobs were safe. In case of trouble, they could escape to the woods, fields, and creeks of rural Pennsylvania. Now a…

  14. 57. GENERAL VIEW OF FURNACES No. 3 AND No. 4 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    57. GENERAL VIEW OF FURNACES No. 3 AND No. 4 TO THE LEFT OF THE FURNACES IS THE ORE BRIDGE, THE TURBO-GENERATOR BUILDING, AND THE WATER FILTER TANKS. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  15. 56. GENERAL VIEW OF FURNACES No. 3 AND No. 4 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    56. GENERAL VIEW OF FURNACES No. 3 AND No. 4 TO THE LEFT OF THE FURNACES IS THE ORE BRIDGE, THE TURBO-GENERATOR BUILDING, AND THE WATER FILTER TANKS. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  16. 6. GENERAL VIEW OF FURNACES No. 3 AND No. 4 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. GENERAL VIEW OF FURNACES No. 3 AND No. 4 TO THE LEFT OF THE FURNACES ARE THE ORE BRIDGE, THE TURBO-GENERATOR BUILDING, AND THE WATER FILTER TANKS. Jet Lowe, Photographer, 1989. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  17. Update on EPA Stove Testing, Focus on Batch-Fueled Stoves

    EPA Science Inventory

    A webinar, entitled Update on EPA Stove Testing, Focus on Batch-Fueled Stoves, will be presented by Jim Jetter, EPA, and will be hosted by the Global Alliance for Clean Cookstoves on August 20, 2013. The purpose of this webinar is to (1) provide an update on the EPA cookstove te...

  18. Self-priming alcohol stove

    SciTech Connect

    Rafford, C.R.; Hoehn, W.

    1988-12-27

    This patent describes an alcohol stove consisting of a burner cup having a base and side walls for storage of liquid alcohol; a main burner assembly attached to the burner cup at a location where the main burner assembly will consume alcohol evaporating from within the burner cup when the main burner assembly is ignited, a top plate having upper and lower surfaces, wherein the main burner assembly is defined on the upper surface of the top plate and the burner cup is attached to the lower surface of to place, wherein the main burner assembly comprises a perimetrical surface, defined by an inner edge and an outer edge, and openings between the inner and outer edges from which alcohol escapes; an outer wall extending downwardly from the lower surface of the top plate in alignment with the outer edge; and an inner wall extending downwardly from the lower surface of the top plate in alignment with the inner edge, at least one screen located in the outer chimney which extends outwardly from the inner wall; and a metallic disc positioned within and near the base of the burner cup and in contact with the base or side walls of the burner cup which are also metallic for cooling the liquid alcohol in the burner cup the base and sidewalls being metallic, thereby preventing excessive alcohol evaporation and consequent uncontrolled combustion of alcohol at the main burner assembly.

  19. CONTROL OF WOOD STOVE EMISSIONS USING IMPROVED SECONDARY COMBUSTION

    EPA Science Inventory

    The report gives results of the operation of two wood stoves in the laboratory with simultaneous on-line chemical analysis of the gases entering the secondary combustion zone and those leaving the stove. (NOTE: Self-initiating secondary combustion in wood stoves is encouraged by ...

  20. ANALYSIS OF RESIDENTIAL COAL STOVE EMISSIONS

    EPA Science Inventory

    The report gives results of an evaluation, in cooperation with the State of Vermont's Agency of Environmental Conservation, of emissions generated by anthracite and bituminous coal used for residential heating. A residential coal stove was operated with both coals, while comparin...

  1. Tube furnace

    DOEpatents

    Foster, Kenneth G.; Frohwein, Eugene J.; Taylor, Robert W.; Bowen, David W.

    1991-01-01

    A vermiculite insulated tube furnace is heated by a helically-wound resistance wire positioned within a helical groove on the surface of a ceramic cylinder, that in turn is surroundingly disposed about a doubly slotted stainless steel cylindrical liner. For uniform heating, the pitch of the helix is of shorter length over the two end portions of the ceramic cylinder. The furnace is of large volume, provides uniform temperature, offers an extremely precise programmed heating capability, features very rapid cool-down, and has a modest electrical power requirement.

  2. Tube furnace

    SciTech Connect

    Foster, K.G.; Frohwein, E.J.; Taylor, R.W.; Bowen, D.W.

    1990-12-31

    A vermiculite insulated tube furnace is heated by a helically-wound resistance wire positioned within a helical groove on the surface of a ceramic cylinder, that in turn is surroundingly disposed about a doubly slotted stainless steel cylindrical liner. For uniform heating, the pitch of the helix is of shorter length over the two end portions of the ceramic cylinder. The furnace is of large volume, provides uniform temperature, offers an extremely precise programmed heating capability, features very rapid cool-down, and has a modest electrical power requirement.

  3. Tube furnace

    SciTech Connect

    Foster, K.G.; Frohwein, E.J.; Taylor, R.W.; Bowen, D.W.

    1990-01-01

    A vermiculite insulated tube furnace is heated by a helically-wound resistance wire positioned within a helical groove on the surface of a ceramic cylinder, that in turn is surroundingly disposed about a doubly slotted stainless steel cylindrical liner. For uniform heating, the pitch of the helix is of shorter length over the two end portions of the ceramic cylinder. The furnace is of large volume, provides uniform temperature, offers an extremely precise programmed heating capability, features very rapid cool-down, and has a modest electrical power requirement.

  4. Kinetics of the reaction of iron blast furnace slag/hydrated lime sorbents with SO{sub 2} at low temperatures: effects of the presence of CO{sub 2}, O{sub 2}, and NOx

    SciTech Connect

    Liu, C.F.; Shih, S.M.

    2009-09-15

    The effects of the presence of CO{sub 2}, O{sub 2}, and NOx in the flue gas on the kinetics of the sulfation of blast furnace slag/hydrated lime sorbents at low temperatures were studied using a differential fixed-bed reactor. When O{sub 2} and NOx were not present simultaneously, the reaction kinetics was about the same as that under the gas mixtures containing SO{sub 2}, H{sub 2}O, and N{sub 2} only, being affected mainly by the relative humidity. The sulfation of sorbents can be described by the surface coverage model and the model equations derived for the latter case. When both O{sub 2} and NOx, were present, the sulfation of sorbents was greatly enhanced, forming a great amount of sulfate in addition to sulfite. The surface coverage model is still valid in this case, but the model equations obtained show a more marked effect of relative humidity and negligible effects of SO{sub 2} concentration and temperature on the reaction. The effect of sorbent composition on the reaction kinetics was entirely represented by the effects of the initial specific surface area (S{sub g0}) and the Ca molar content (M{sup -1}) of sorbent. The initial conversion rate of sorbent increased linearly with increasing S{sub g0}, and the ultimate conversion increased linearly with increasing S{sub g0}M{sup -1}. The model equations obtained in this work are applicable to describe the kinetics of the sulfation of the sorbents in the low-temperature dry and semidry fine gas desulfurization processes either with an upstream NOx, removal unit or without.111

  5. Furnace assembly

    DOEpatents

    Panayotou, Nicholas F.; Green, Donald R.; Price, Larry S.

    1985-01-01

    A method of and apparatus for heating test specimens to desired elevated temperatures for irradiation by a high energy neutron source. A furnace assembly is provided for heating two separate groups of specimens to substantially different, elevated, isothermal temperatures in a high vacuum environment while positioning the two specimen groups symmetrically at equivalent neutron irradiating positions.

  6. Furnace assembly

    DOEpatents

    Panayotou, N.F.; Green, D.R.; Price, L.S.

    A method of and apparatus for heating test specimens to desired elevated temperatures for irradiation by a high energy neutron source. A furnace assembly is provided for heating two separate groups of specimens to substantially different, elevated, isothermal temperatures in a high vacuum environment while positioning the two specimen groups symmetrically at equivalent neutron irradiating positions.

  7. Fuel efficient stoves for the poorest two billion

    NASA Astrophysics Data System (ADS)

    Gadgil, Ashok

    2012-03-01

    About 2 billion people cook their daily meals on generally inefficient, polluting, biomass cookstoves. The fuels include twigs and leaves, agricultural waste, animal dung, firewood, and charcoal. Exposure to resulting smoke leads to acute respiratory illness, and cancers, particularly among women cooks, and their infant children near them. Resulting annual mortality estimate is almost 2 million deaths, higher than that from malaria or tuberculosis. There is a large diversity of cooking methods (baking, boiling, long simmers, brazing and roasting), and a diversity of pot shapes and sizes in which the cooking is undertaken. Fuel-efficiency and emissions depend on the tending of the fire (and thermal power), type of fuel, stove characteristics, and fit of the pot to the stove. Thus, no one perfect fuel-efficient low-emitting stove can suit all users. Affordability imposes a further severe constraint on the stove design. For various economic strata within the users, a variety of stove designs may be appropriate and affordable. In some regions, biomass is harvested non-renewably for cooking fuel. There is also increasing evidence that black carbon emitted from stoves is a significant contributor to atmospheric forcing. Thus improved biomass stoves can also help mitigate global climate change. The speaker will describe specific work undertaken to design, develop, test, and disseminate affordable fuel-efficient stoves for internally displaced persons (IDPs) of Darfur, Sudan, where the IDPs face hardship, humiliation, hunger, and risk of sexual assault owing to their dependence on local biomass for cooking their meals.

  8. Retrofit catalytic converter for wood-burning stoves

    SciTech Connect

    1983-01-01

    The major purpose of this project was to design, fabricate, test, and evaluate a retrofit catalytic converter for woodburning stoves. In the interim between our date of application March 5, 1981 and the beginning of the grant period December 1, 1981, several such devices became commercially available. Therefore, we decided to modify the purpose and direction of our project. In summary, we designed and constructed a calorimeter room in a building located on the campus of Northern Kentucky University. We equipped this room with a woodburning stove and a metal chimney extending through the roof. We designed and constructed the appropriate instrumentation for monitoring the heat output of the stove. We observed and recorded the operating characteristics of this stove over a period of several days. We then equipped the stove with a barometric damper and repeated the experiment. We are now in the process of equipping the stove with a catalytic converter. Thus the major emphasis of the project currently is to test and evaluate several commercial retrofit devices which are purported to reduce creosote and/or increase the efficiency of a woodburning stove.

  9. Primus stove burns: a persisting problem in developing countries

    PubMed Central

    McGlone, Emma Rose; Goutos, Ioannis; Nelson, Rebecca A; Pandya, Ankur

    2011-01-01

    Primus stoves account for a large proportion of burn injuries in the developing world. The mechanism of these injuries is closely linked with factors relating to stove design, fuel characteristics and the socioeconomic profile of victims. We review the current literature on these injuries with particular attention to the injury mechanisms and epidemiological data available. We additionally summarize the initiatives so far developed worldwide for their prevention and define directions for further research into reducing the burden associated with Primus stove burn injuries. PMID:22928153

  10. Furnace afterburner

    SciTech Connect

    Angelo, J.F. II

    1987-01-13

    An afterburner is described for the exhaust effluvia of a furnace, which exhaust contains combustible material, the afterburner comprising: a. an elongated, generally cylindrical combustion chamber having an inlet for the exhaust at or adjacent one end thereof, and an outlet at or adjacent its other end, b. means operable to induce a draft through the combustion chamber from its inlet to its outlet, c. a series of air nozzles disposed to direct jets of air into the interior of the combustion chamber. Certain nozzles are arranged to direct air jets into the combustion chamber substantially tangentially thereto in a clockwise direction, and the remainder of the nozzles and arranged to direct air jets into the chamber substantially tangentially thereto in a counter-clockwise direction, whereby to induce turbulence within the chamber to intermix the air and the exhaust thoroughly, and d. means operable to deliver air to the air nozzles.