Science.gov

Sample records for boiling point temperature

  1. The boiling point of stratospheric aerosols.

    NASA Technical Reports Server (NTRS)

    Rosen, J. M.

    1971-01-01

    A photoelectric particle counter was used for the measurement of aerosol boiling points. The operational principle involves raising the temperature of the aerosol by vigorously heating a portion of the intake tube. At or above the boiling point, the particles disintegrate rather quickly, and a noticeable effect on the size distribution and concentration is observed. Stratospheric aerosols appear to have the same volatility as a solution of 75% sulfuric acid. Chemical analysis of the aerosols indicates that there are other substances present, but that the sulfate radical is apparently the major constituent.

  2. Prediction of boiling points and melting points of aromatic compounds

    SciTech Connect

    Simamora, P.; Yalkowsky, S.H.

    1994-12-31

    Two transition temperatures that are most frequently measured are boiling point and melting point. These properties are environmentally of importance because they are two main factors that control the vapor pressure and solubility of organic compounds. Therefore, the ability to predict both transition temperatures would aid in the estimation of other environmentally important physico-chemical properties. In this study, simple methods are proposed to estimate the boiling points and melting points from chemical structure. The proposed predictive methods are derived from a generally known thermodynamic equation: T{sub tr} = {Delta}H{sub tr}/{Delta}S{sub tr}. The transition temperatures are determined by the estimation of both the enthalpy and the entropy of transition. The enthalpies of boiling and melting are both estimated as additive constitutive properties. The entropy of boiling of aromatic compounds is assumed to be constant as described by Trouton`s rule, while the entropy of melting is not constant. It depends on non-additive non-constitutive molecular property, rotational symmetry ({sigma}).

  3. An Analytical Approach for Relating Boiling Points of Monofunctional Organic Compounds to Intermolecular Forces

    ERIC Educational Resources Information Center

    Struyf, Jef

    2011-01-01

    The boiling point of a monofunctional organic compound is expressed as the sum of two parts: a contribution to the boiling point due to the R group and a contribution due to the functional group. The boiling point in absolute temperature of the corresponding RH hydrocarbon is chosen for the contribution to the boiling point of the R group and is a…

  4. An Analytical Approach for Relating Boiling Points of Monofunctional Organic Compounds to Intermolecular Forces

    ERIC Educational Resources Information Center

    Struyf, Jef

    2011-01-01

    The boiling point of a monofunctional organic compound is expressed as the sum of two parts: a contribution to the boiling point due to the R group and a contribution due to the functional group. The boiling point in absolute temperature of the corresponding RH hydrocarbon is chosen for the contribution to the boiling point of the R group and is a

  5. Relationships between melting point and boiling point of organic compounds

    SciTech Connect

    Yalkowsky, S.H.; Krzyzaniak, J.F.; Myrdal, P.B. . College of Pharmacy)

    1994-07-01

    Relationships between melting point and boiling point are shown to be dependent upon the molecular symmetry number and a modified count of the total number of atoms in the molecule. Using the above relationships, the boiling and melting points of nearly 1,000 non-hydrogen-bonding organic compounds have been correlated. The correlations for boiling point and melting point have root mean square errors of 28 and 36 C, respectively.

  6. Boiling of the interface between two immiscible liquids below the bulk boiling temperatures of both components.

    PubMed

    Pimenova, Anastasiya V; Goldobin, Denis S

    2014-11-01

    We consider the problem of boiling of the direct contact of two immiscible liquids. An intense vapour formation at such a direct contact is possible below the bulk boiling points of both components, meaning an effective decrease of the boiling temperature of the system. Although the phenomenon is known in science and widely employed in technology, the direct contact boiling process was thoroughly studied (both experimentally and theoretically) only for the case where one of liquids is becoming heated above its bulk boiling point. On the contrary, we address the case where both liquids remain below their bulk boiling points. In this paper we construct the theoretical description of the boiling process and discuss the actualisation of the case we consider for real systems. PMID:25403831

  7. Water above its boiling point: Study of the temperature and density dependence of the partial pair correlation functions. I. Neutron diffraction experiment

    NASA Astrophysics Data System (ADS)

    Postorino, P.; Ricci, M. A.; Soper, A. K.

    1994-09-01

    Neutron diffraction data on water, employing the technique of hydrogen/deuterium isotope substitution, are reported at three thermodynamic states above the boiling point. The structural information is analyzed in terms of the partial radial distribution functions, OO, OH, and HH, which are extracted from the neutron data. It is found that temperature affects mainly the medium and longer range order in the liquid, while density plays a significant role in controlling the degree of hydrogen bonding. To understand the structure of water obtained from these data it appears that many-body cooperative interactions have to be correctly accounted for.

  8. Boiling points of halogenated organic compounds.

    PubMed

    Horvath, A L

    2001-08-01

    The normal boiling points of a number of halogenated organic compounds have been compiled from experimental measurements over three decades. Some of these chemicals have not been reported in the literature. The substances listed are halogenated aliphatic hydrocarbons, halogenated aliphatic ethers, halogenated ring (cyclic) hydrocarbons and other related compounds. PMID:11482683

  9. Excess Heat in Heavy WATER-Pd/C Catalyst Cathode Case-Type Electrolysis at the Temperature Near the Boiling Point

    NASA Astrophysics Data System (ADS)

    Wei, Qing M.; Li, Xing Z.; Cui, Yan O.

    2005-12-01

    At high temperatures, the Pd/C catalyst cathode (Case-type) electrolysis in heavy water might produce more excess heat than at room temperature. While the "excess heat" in Case-type experiment was apparently confirmed at the higher temperature, the method raised new problems with electrolysis near boiling temperatures.

  10. Size-exclusion chromatography for the determination of the boiling point distribution of high-boiling petroleum fractions.

    PubMed

    Boczkaj, Grzegorz; Przyjazny, Andrzej; Kami?ski, Marian

    2015-03-01

    The paper describes a new procedure for the determination of boiling point distribution of high-boiling petroleum fractions using size-exclusion chromatography with refractive index detection. Thus far, the determination of boiling range distribution by chromatography has been accomplished using simulated distillation with gas chromatography with flame ionization detection. This study revealed that in spite of substantial differences in the separation mechanism and the detection mode, the size-exclusion chromatography technique yields similar results for the determination of boiling point distribution compared with simulated distillation and novel empty column gas chromatography. The developed procedure using size-exclusion chromatography has a substantial applicability, especially for the determination of exact final boiling point values for high-boiling mixtures, for which a standard high-temperature simulated distillation would have to be used. In this case, the precision of final boiling point determination is low due to the high final temperatures of the gas chromatograph oven and an insufficient thermal stability of both the gas chromatography stationary phase and the sample. Additionally, the use of high-performance liquid chromatography detectors more sensitive than refractive index detection allows a lower detection limit for high-molar-mass aromatic compounds, and thus increases the sensitivity of final boiling point determination. PMID:25545251

  11. From boiling point to glass transition temperature: transport coefficients in molecular liquids follow three-parameter scaling.

    PubMed

    Schmidtke, B; Petzold, N; Kahlau, R; Hofmann, M; Rssler, E A

    2012-10-01

    The phenomenon of the glass transition is an unresolved problem in condensed matter physics. Its prominent feature, the super-Arrhenius temperature dependence of the transport coefficients, remains a challenge to be described over the full temperature range. For a series of molecular glass formers, we combined ?(T) collected from dielectric spectroscopy and dynamic light scattering covering a range 10(-12) s < ?(T) < 10(2) s. Describing the dynamics in terms of an activation energy E(T), we distinguish a high-temperature regime characterized by an Arrhenius law with a constant activation energy E(?) and a low-temperature regime for which E(coop)(T) ? E(T)-E(?) increases exponentially while cooling. A scaling is introduced, specifically E(coop)(T)/E(?) [proportionality] exp[-?(T/T(A)-1)], where ? is a fragility parameter and T(A) a reference temperature proportional to E(?). In order to describe ?(T) still the attempt time ?(?) has to be specified. Thus, a single interaction parameter E(?) describing the high-temperature regime together with ? controls the temperature dependence of low-temperature cooperative dynamics. PMID:23214591

  12. Estimating the physicochemical properties of polyhalogenated aromatic and aliphatic compounds using UPPER: part 1. Boiling point and melting point.

    PubMed

    Admire, Brittany; Lian, Bo; Yalkowsky, Samuel H

    2015-01-01

    The UPPER (Unified Physicochemical Property Estimation Relationships) model uses enthalpic and entropic parameters to estimate 20 biologically relevant properties of organic compounds. The model has been validated by Lian and Yalkowsky on a data set of 700 hydrocarbons. The aim of this work is to expand the UPPER model to estimate the boiling and melting points of polyhalogenated compounds. In this work, 19 new group descriptors are defined and used to predict the transition temperatures of an additional 1288 compounds. The boiling points of 808 and the melting points of 742 polyhalogenated compounds are predicted with average absolute errors of 13.56 K and 25.85 K, respectively. PMID:25022475

  13. Optimal boiling temperature for ORC installation

    NASA Astrophysics Data System (ADS)

    Mikielewicz, Jarosław; Mikielewicz, Dariusz

    2012-09-01

    In the paper a research on cost-effective optimum design boiling temperature for Organic Rankine Cycle utilizing low-temperature heat sources is presented. The ratio of the heat exchanger area of the boiler to the power output is used as the objective function. Analytical relations for heat transfer area as well power of the cycle are formulated. Evaporation temperature and inlet temperature of the heat source medium as well its mass flow rate are varied in the optimization method. The optimization is carried out for three working fluids, i.e. R 134a, water and ethanol. The objective function (economics profitability, thermodynamic efficiency) leads to different optimal working conditions in terms of evaporating temperature. Maximum power generation in the near-critical conditions of subcritical ORC is the highest. The choice of the working fluid can greatly affect the objective function which is a measure of power plant cost. Ethanol exhibits a minimum objective function but not necessarily the maximum cycle efficiency.

  14. Prediction of boiling points of organic compounds by QSPR tools.

    PubMed

    Dai, Yi-min; Zhu, Zhi-ping; Cao, Zhong; Zhang, Yue-fei; Zeng, Ju-lan; Li, Xun

    2013-07-01

    The novel electro-negativity topological descriptors of YC, WC were derived from molecular structure by equilibrium electro-negativity of atom and relative bond length of molecule. The quantitative structure-property relationships (QSPR) between descriptors of YC, WC as well as path number parameter P3 and the normal boiling points of 80 alkanes, 65 unsaturated hydrocarbons and 70 alcohols were obtained separately. The high-quality prediction models were evidenced by coefficient of determination (R(2)), the standard error (S), average absolute errors (AAE) and predictive parameters (Qext(2),RCV(2),Rm(2)). According to the regression equations, the influences of the length of carbon backbone, the size, the degree of branching of a molecule and the role of functional groups on the normal boiling point were analyzed. Comparison results with reference models demonstrated that novel topological descriptors based on the equilibrium electro-negativity of atom and the relative bond length were useful molecular descriptors for predicting the normal boiling points of organic compounds. PMID:23792208

  15. Characterizing preferential groundwater discharge through boils using temperature

    NASA Astrophysics Data System (ADS)

    Vandenbohede, A.; de Louw, P. G. B.; Doornenbal, P. J.

    2014-03-01

    In The Netherlands, preferential groundwater discharge trough boils is a key process in the salinization of deep polders. Previous work showed that boils also influence the temperature in the subsurface and of surface water. This paper elaborates on this process combining field observations with numerical modeling. As is the case for salinity, a distinct anomaly in the subsurface and surface water temperature can be attributed to boils. Lines of equal temperature are distorted towards the boil, which can be considered as an upconing of the temperature profile by analogy of the upconing of a fresh-saltwater interface. The zone of this distortion is limited to the immediate vicinity of the boil, being about 5 m in the aquitard which holds the boil's conduit, or maximum a few dozens of meters in the underlying aquifer. In the aquitard, heat transport is conduction dominated whereas this is convection dominated in the aquifer. The temperature anomaly differs from the salinity anomaly by the smaller radius of influence and faster time to reach a new steady-state of the former. Boils discharge water with a temperature equal to the mean groundwater temperature. This influences the yearly and diurnal variation of ditch water temperature in the immediate vicinity of the boil importantly but also the temperature in the downstream direction. Temporary nature of the boil (e.g. stability of the conduit, discharge rate), uncertainty on the 3D construction of the conduit and heterogeneity of the subsoil make it unlikely that temperature measurements can be interpreted further than a qualitative level.

  16. Boils

    MedlinePLUS

    ... Rights Job Postings Sections of the JAOCD JAOCD Archive Published Members Online Dermatology Journals Edit This Favorite Name: Category: Share: Yes No, Keep Private Boils Share | Boils (also known as furuncles or ...

  17. Pervaporation of ethanol and acetone above normal boiling temperatures

    SciTech Connect

    Windmoeller, D.; Galembeck, F. )

    1992-08-01

    Pervaporation experiments were performed at higher than normal feed liquid boiling temperatures by applying pressure to the feed compartment. Ethanol, acetone, and aqueous ethanol solutions were pervaporated through silicone rubber dense membranes. Large increases were observed in the permeate flow as the temperature rose above the liquid boiling temperature. Separation factors in aqueous ethanol pervaporation are not affected by these increases in permeate output, and they are in the same range as those obtained in conventional pervaporation.

  18. Measurement of the absolute Quantum Efficiency of Hamamatsu model R11410-10 photomultiplier tubes at low temperatures down to liquid xenon boiling point

    NASA Astrophysics Data System (ADS)

    Lyashenko, A.; Nguyen, T.; Snyder, A.; Wang, H.; Arisaka, K.

    2014-11-01

    We report on the measurements of the absolute Quantum Efficiency(QE) for Hamamatsu model R11410-10 PMTs specially designed for the use in low background liquid xenon detectors. QE was measured for five PMTs in a spectral range between 154.5 nm to 400 nm at low temperatures down to -110C. It was shown that during the PMT cooldown from room temperature to -110C (a typical PMT operation temperature in liquid xenon detectors), the absolute QE increases by a factor of 1.1-1.15 at 175 nm. The QE growth rate with respect to temperature is wavelength dependent peaking at about 165 nm corresponding to the fastest growth of about -0.07%QE/C and at about 200 nm corresponding to slowest growth of below -0.01%QE/C. A dedicated setup and methods for PMT Quantum Efficiency measurement at low temperatures are described in details.

  19. Teaching Structure-Property Relationships: Investigating Molecular Structure and Boiling Point

    ERIC Educational Resources Information Center

    Murphy, Peter M.

    2007-01-01

    A concise, well-organized table of the boiling points of 392 organic compounds has facilitated inquiry-based instruction in multiple scientific principles. Many individual or group learning activities can be derived from the tabulated data of molecular structure and boiling point based on the instructor's education objectives and the students'…

  20. The Gibbs Energy Basis and Construction of Boiling Point Diagrams in Binary Systems

    ERIC Educational Resources Information Center

    Smith, Norman O.

    2004-01-01

    An illustration of how excess Gibbs energies of the components in binary systems can be used to construct boiling point diagrams is given. The underlying causes of the various types of behavior of the systems in terms of intermolecular forces and the method of calculating the coexisting liquid and vapor compositions in boiling point diagrams with

  1. Teaching Structure-Property Relationships: Investigating Molecular Structure and Boiling Point

    ERIC Educational Resources Information Center

    Murphy, Peter M.

    2007-01-01

    A concise, well-organized table of the boiling points of 392 organic compounds has facilitated inquiry-based instruction in multiple scientific principles. Many individual or group learning activities can be derived from the tabulated data of molecular structure and boiling point based on the instructor's education objectives and the students'

  2. Comparative biology and chemistry of boiling point fractions from different coal liquefaction processes

    SciTech Connect

    Wright, C.W.; Chess, E.K.; Stewart, D.L.; Mahlum, D.D.; Later, D.W.; Lucke, R.B.; Pelroy, R.A.; Wilson, B.W.

    1985-11-01

    Data on the chemical composition and toxicologic activity of narrow boiling point (bp) range distillate cuts from the non-catalytic solvent refined coal-I and -II processes, as well as from the catalytic H-Coal, EDS, and integrated two-stage liquefaction processes, were compiled and compared. Results revealed that processes using catalysts contained higher concentrations of alkylated and hydrogenated polycyclic aromatic hydrocarbons (PAH). In addition, lower concentrations of nitrogen-containing polycyclic aromatic compounds (NPAC), including amino-substituted PAH, were present in those materials from processes which used some form of catalytic hydrogenation. Regardless of process, the hydrogen content decreased and the nitrogen, oxygen, and sulfur heteroatomic content of the coal liquefaction materials increased as a function of increasing distillation temperature. In addition, aliphatic hydrocarbon content decreased while the NPAC and hydroxy-substituted PAH content increased as a function of increasing bp temperature for all the coal liquefaction materials. 18 refs., 8 figs., 10 tabs.

  3. Droplet impingement dynamics: effect of surface temperature during boiling and non-boiling conditions

    NASA Astrophysics Data System (ADS)

    Shen, Jian; Liburdy, James A.; Pence, Deborah V.; Narayanan, Vinod

    2009-11-01

    This study investigates the hydrodynamic characteristics of droplet impingement on heated surfaces and compares the effect of surface temperature when using water and a nanofluid on a polished and nanostructured surface. Results are obtained for an impact Reynolds number and Weber number of approximately 1700 and 25, respectively. Three discs are used: polished silicon, nanostructured porous silicon and gold-coated polished silicon. Seven surface temperatures, including single-phase (non-boiling) and two-phase (boiling) conditions, are included. Droplet impact velocity, transient spreading diameter and dynamic contact angle are measured. Results of water and a water-based single-wall carbon-nanotube nanofluid impinging on a polished silicon surface are compared to determine the effects of nanoparticles on impinging dynamics. The nanofluid results in larger spreading velocities, larger spreading diameters and an increase in early-stage dynamic contact angle. Results of water impinging on both polished silicon and nanostructured silicon show that the nanostructured surface enhances the heat transfer for evaporative cooling at lower surface temperatures, which is indicated by a shorter evaporation time. Using a nanofluid or a nanostructured surface can reduce the total evaporation time up to 20% and 37%, respectively. Experimental data are compared with models that predict dynamic contact angle and non-dimensional maximum spreading diameter. Results show that the molecular-kinetic theory's dynamic contact angle model agrees well with current experimental data for later times, but over-predicts at early times. Predictions of maximum spreading diameter based on surface energy analyses indicate that these models over-predict unless empirical coefficients are adjusted to fit the test conditions. This is a consequence of underestimates of the dissipative energy for the conditions studied.

  4. The accommodation coefficient of the liquid at temperatures below the boiling

    NASA Astrophysics Data System (ADS)

    Bulba, Elena E.

    2015-01-01

    Are carried out experimental investigation of the laws of vaporization at temperatures below the boiling point. Is determined the mass rate of evaporation of distilled water in large intervals of time at different temperatures in order to sound conclusions about the stationarity of the process of evaporation of the liquid in the conditions of the experiments performed, and also studied the effect of temperature on the rate of evaporation. Accommodation coefficient is defined in the mathematical expression of the law of Hertz-Knudsen for standart substance used in the experiments.

  5. A pilot reactor study on the effect of the naphtha boiling point properties in catalytic reforming

    SciTech Connect

    Moliord, K.; Tanem, I.; Grande, K.

    1995-12-31

    Three naphthas with different initial and three naphthas with different final boiling points were compared by testing in a pilot reactor. The pilot reactor unit consisted of isothermal, once-through 200 cm{sup 2} reactors with on-line GCs for full product analysis and octane number determination. Octane numbers, reformate yields and composition, gas and hydrogen yields were measured as function of reaction temperature at 16 bar reaction pressure and a molar H{sub 2}/HC ratio of 4.23. Catalyst deactivation was studied over 2 weeks periods at high seventy conditions, i.e. 102.4 RON and a H{sub 2}/HC ratio of 2.2. Test results, with emphasis on the yields of benzene and other aromatics, hydrogen yields as well as catalyst deactivation, are presented.

  6. Estimation of boiling points using density functional theory with polarized continuum model solvent corrections.

    PubMed

    Chan, Poh Yin; Tong, Chi Ming; Durrant, Marcus C

    2011-09-01

    An empirical method for estimation of the boiling points of organic molecules based on density functional theory (DFT) calculations with polarized continuum model (PCM) solvent corrections has been developed. The boiling points are calculated as the sum of three contributions. The first term is calculated directly from the structural formula of the molecule, and is related to its effective surface area. The second is a measure of the electronic interactions between molecules, based on the DFT-PCM solvation energy, and the third is employed only for planar aromatic molecules. The method is applicable to a very diverse range of organic molecules, with normal boiling points in the range of -50 to 500 C, and includes ten different elements (C, H, Br, Cl, F, N, O, P, S and Si). Plots of observed versus calculated boiling points gave R=0.980 for a training set of 317 molecules, and R=0.979 for a test set of 74 molecules. The role of intramolecular hydrogen bonding in lowering the boiling points of certain molecules is quantitatively discussed. PMID:21798775

  7. What Is the Boiling Point and Heat of Vaporization of Sulfuric Acid?

    ERIC Educational Resources Information Center

    Myers, R. Thomas

    1983-01-01

    Discusses the values presented in various handbooks for the boiling point and heat of vaporization of sulfuric acid, noting discrepencies. Analyzes various approaches to data presentation, discussing the data on sulfuric acid in light of the Trouton constant. Points out the need for a more critical use of tables. (JM)

  8. Low-boiling-point solvent additives can also enable morphological control in polymer solar cells

    SciTech Connect

    Mahadevapuram, Rakesh C.; Carr, John A.; Chen, Yuqing; Bose, Sayantan; Nalwa, Kanwar S.; Petrich, Jacob W.; Chaudhary, Sumit

    2013-11-02

    Processing organic photovoltaic (OPV) blend solutions with high-boiling-point solvent additives has recently been used for morphological control in bulk-heterojunction OPV cells. Here we show that even low-boiling-point solvents can be effective additives. When P3HT:PCBM OPV cells were processed with a low-boiling-point solvent tetrahydrafuran as an additive in parent solvent o-dichlorobenzene, charge extraction increased leading to fill factors as high as 69.5%, without low work-function cathodes, electrode buffer layers or thermal treatment. This was attributed to PCBM demixing from P3HT domains and better vertical phase separation, as indicated by photoluminescence lifetimes, hole mobilities, and shunt leakage currents. Dependence on solvent parameters and applicability beyond P3HT system was also investigated. (C) 2013 Elsevier B.V. All rights reserved.

  9. Dependences between the boiling point of binary aqueous-organic mixtures and their composition

    NASA Astrophysics Data System (ADS)

    Preobrazhenskii, M. P.; Rudakov, O. B.

    2015-01-01

    The optimum three-parametric regression basis set that reflects the properties of permutation symmetry and takes into account the specificity of isobars of aqueous-organic mixtures is constructed. The optimum algorithm for the calculation of the regression parameters of the boiling point isobars is proposed. The parameters are calculated for a series of systems. The accuracy of the method proposed for the regression description of the dependence of the boiling point of binary aqueous-organic mixtures on the composition is determined by empirical inaccuracies and is sufficient for the most part of practical applications. Methods for increasing the accuracy of the regression description of equilibrium homogeneous systems are formulated.

  10. Evaluation on environment-friendly refrigerants with similar normal boiling points in ejector refrigeration system

    NASA Astrophysics Data System (ADS)

    Wang, F.; Shen, S. Q.; Li, D. Y.

    2014-12-01

    Based on the "hypothetical throat area" theory and the "constant-pressure mixing" theory, a thermodynamic model for ejector was set up by introducing the real properties of refrigerants. Refrigerants which have similar normal boiling points with each other may act as replacement to each other in substitute progress. In this paper, eight environment-friendly refrigerants were divided into 4 pairs for study according to their normal boiling point. In each refrigerant pair, the entrainment ratios of ejector, system COP, pump power et al. of refrigerants were compared and analyzed. Lastly, the performances of the transcritical and subcritical ejector refrigeration cycles with propylene were calculated and compared.

  11. Students' Understanding of Boiling Points and Intermolecular Forces

    ERIC Educational Resources Information Center

    Schmidt, Hans-Jurgen; Kaufmann, Birgit; Treagust, David F.

    2009-01-01

    In introductory chemistry courses students are presented with the model that matter is composed of particles, and that weak forces of attraction exist between them. This model is used to interpret phenomena such as solubility and melting points, and aids in understanding the changes in states of matter as opposed to chemical reactions. We…

  12. Students' Understanding of Boiling Points and Intermolecular Forces

    ERIC Educational Resources Information Center

    Schmidt, Hans-Jurgen; Kaufmann, Birgit; Treagust, David F.

    2009-01-01

    In introductory chemistry courses students are presented with the model that matter is composed of particles, and that weak forces of attraction exist between them. This model is used to interpret phenomena such as solubility and melting points, and aids in understanding the changes in states of matter as opposed to chemical reactions. We

  13. Explaining Melting and Evaporation below Boiling Point. Can Software Help with Particle Ideas?

    ERIC Educational Resources Information Center

    Papageorgiou, George; Johnson, Philip; Fotiades, Fotis

    2008-01-01

    This paper reports the findings of a study exploring the use of a software package to help pupils understand particulate explanations for melting and evaporation below boiling point. Two matched classes in a primary school in Greece (ages 11-12, n = 16 and 19) were involved in a short intervention of six one hour lessons. Covering the same

  14. The effect of vapor polarity and boiling point on breakthrough for binary mixtures on respirator carbon.

    PubMed

    Robbins, C A; Breysse, P N

    1996-08-01

    This research evaluated the effect of the polarity of a second vapor on the adsorption of a polar and a nonpolar vapor using the Wheeler model. To examine the effect of polarity, it was also necessary to observe the effect of component boiling point. The 1% breakthrough time (1% tb), kinetic adsorption capacity (W(e)), and rate constant (kv) of the Wheeler model were determined for vapor challenges on carbon beds for both p-xylene and pyrrole (referred to as test vapors) individually, and in equimolar binary mixtures with the polar and nonpolar vapors toluene, p-fluorotoluene, o-dichlorobenzene, and p-dichlorobenzene (referred to as probe vapors). Probe vapor polarity (0 to 2.5 Debye) did not systematically alter the 1% tb, W(e), or kv of the test vapors. The 1% tb and W(e) for test vapors in binary mixtures can be estimated reasonably well, using the Wheeler model, from single-vapor data (1% tb +/- 30%, W(e) +/- 20%). The test vapor 1% tb depended mainly on total vapor concentration in both single and binary systems. W(e) was proportional to test vapor fractional molar concentration (mole fraction) in mixtures. The kv for p-xylene was significantly different (p < or = 0.001) when compared according to probe boiling point; however, these differences were apparently of limited importance in estimating 1% tb for the range of boiling points tested (111 to 180 degrees C). Although the polarity and boiling point of chemicals in the range tested are not practically important in predicting 1% tb with the Wheeler model, an effect due to probe boiling point is suggested, and tests with chemicals of more widely ranging boiling point are warranted. Since the 1% tb, and thus, respirator service life, depends mainly on total vapor concentration, these data underscore the importance of taking into account the presence of other vapors when estimating respirator service life for a vapor in a mixture. PMID:8765200

  15. Boiling Point

    NASA Technical Reports Server (NTRS)

    Jansen, Michael C.

    2002-01-01

    The author recounts his experiences he helped to investigate the accident which destroyed the Space Shuttle Challenger. The focus was on how he used novel approaches to investigate heat transfer in the shuttle's hydrogen tank, after an expert he sought for advice proved unhelpful.

  16. Emplacement temperatures of boiling-over pyroclastic density currents from Tungurahua and Cotopaxi volcanoes, Ecuador

    NASA Astrophysics Data System (ADS)

    Rader, E. L.; Geist, D.; Geissman, J. W.; Harpp, K. S.; Dufek, J.

    2011-12-01

    Pyroclastic density currents (PDC) can be sourced by collapsing columns, dome collapse, and boiling-over fountains. Although there are innumerable studies of the deposits produced by the first 2 mechanisms, pyroclastic deposits from boiling-over have not been well characterized. We are studying several pyroclastic flow deposits from two boiling over eruptions in Ecuador, Tungurahua, 2006 and Cotopaxi, 1877. These eruptions produced abundant cauliflower-textured, large (up to 1 m in diameter), fragile scoria clasts. Some evidence points to relatively low temperatures during transport. For example, some flows at Cotopaxi are unusually long and sinuous and probably influenced by melt water from the glacier that caps the cone. Additionally, un-charred vegetation and eyewitness reports of un-melted plastic in the path of pyroclastic flows at Tungurahua also support cool emplacement temperatures. On the other hand, some scoria clasts were ductile when deposited as evidenced by draped clasts. We cut 5 to 9 cm transects from rim to core of 36 lithic and juvenile samples, which were then thermally demagnetized and measured. Lithic samples from Tungurahua indicate only one flow was fully remagnetized above ~580C, while another flow was only partially remagnetized below 210C. All other lithics from both volcanoes were never heated to above 90C. Juvenile clasts from Cotopaxi indicate three types of flows: currents that begin hot (above 580C) but cool quickly (juveniles emplaced hot, but lithics emplaced cold); currents that deposit at ~330C (two components of magnetization that intersect at 330C in the juvenile clasts), and cold currents such as lahars. The majority of currents from Tungurahua are of the 2nd type, having emplacement temperatures of ~380C-280C, with the deformable juvenile clasts being hotter than the rest of the flow. Despite the intact nature of the fragile bombs, emplacement temperatures indicate that the majority of flow deposits at Tungurahua and Cotopaxi were emplaced at temperatures between 210C and 380C. The presence of abundant scoria bombs in other PDC deposits are likely indicative of flow and deposition at relatively low temperatures in currents produced by a boiling-over mechanism.

  17. Application of the QSPR approach to the boiling points of azeotropes.

    PubMed

    Katritzky, Alan R; Stoyanova-Slavova, Iva B; Tmm, Kaido; Tamm, Tarmo; Karelson, Mati

    2011-04-21

    CODESSA Pro derivative descriptors were calculated for a data set of 426 azeotropic mixtures by the centroid approximation and the weighted-contribution-factor approximation. The two approximations produced almost identical four-descriptor QSPR models relating the structural characteristic of the individual components of azeotropes to the azeotropic boiling points. These models were supported by internal and external validations. The descriptors contributing to the QSPR models are directly related to the three components of the enthalpy (heat) of vaporization. PMID:21449551

  18. Preparation and properties of low boiling point of alcohol and acetone-based magnetic fluid

    NASA Astrophysics Data System (ADS)

    Fujita, T.; Miyazaki, T.; Nishiyama, H.; Jeyadevan, B.

    1999-07-01

    Ultra-fine magnetic particles are difficult to be dispersed in low boiling point solvents such as alcohol (C 1-C 4) and acetone. In this paper, we report the preparation methods of several alcohol and acetone-based magnetic fluids. The stability of magnetic fluid depended on the HLB (hydrophile-lipophile balance) of the solvent and alkyl chain lengths of organic layers. The fluid was most stable only when the HLB value of surfactant and the solvents are similar.

  19. A regression model for calculating the boiling point isobars of tetrachloromethane-based binary solutions

    NASA Astrophysics Data System (ADS)

    Preobrazhenskii, M. P.; Rudakov, O. B.

    2016-01-01

    A regression model for calculating the boiling point isobars of tetrachloromethane-organic solvent binary homogeneous systems is proposed. The parameters of the model proposed were calculated for a series of solutions. The correlation between the nonadditivity parameter of the regression model and the hydrophobicity criterion of the organic solvent is established. The parameter value of the proposed model is shown to allow prediction of the potential formation of azeotropic mixtures of solvents with tetrachloromethane.

  20. Net vapor generation point in boiling flow of trichlorotrifluoroethane at high pressures

    NASA Technical Reports Server (NTRS)

    Dougall, R. S.; Lippert, T. E.

    1973-01-01

    The conditions at which the void in subcooled boiling starts to undergo a rapid increase were studied experimentally. The experiments were performed in a 12.7 x 9.5 mm rectangular channel. Heating was from a 3.2 mm wide strip embedded in one wall. The pressure ranged from 9.45 to 20.7 bar, mass velocity from 600 to 7000 kg/sq m sec, and subcooling from 16 to 67 C. Photographs were used to determine when detached bubbles first appeared in the bulk flow. Measurements of bubble layer thickness along the wall were also made. Results showed that the point of net vapor generation is close to the occurrence of fully-developed boiling.

  1. Numerical study on temperature distribution around a boiling bubble departing from heating surface in subcooled pool

    NASA Astrophysics Data System (ADS)

    Ose, Yasuo; Kunugi, Tomoaki

    2014-06-01

    In this paper, the transient three-dimensional numerical simulations based on the MARS (Multi-interface Advection and Reconstruction Solver) with the non-empirical boiling and condensation model have been conducted for an isolated boiling bubble behavior in a subcooled pool. The temperature distributions formed around the subcooled pool boiling bubble departing from a heating surface obtained by the numerical simulations were investigated. As the results, it was found that several thermal plumes with different temperature were formed during the bubble departure from the heating surface by using the volume rendering visualization technique.

  2. Estimating surface temperature in forced convection nucleate boiling - A simplified method

    NASA Technical Reports Server (NTRS)

    Hendricks, R. C.; Papell, S. S.

    1977-01-01

    A simplified expression to estimate surface temperatures in forced convection boiling was developed using a liquid nitrogen data base. Using the principal of corresponding states and the Kutateladze relation for maximum pool boiling heat flux, the expression was normalized for use with other fluids. The expression was applied also to neon and water. For the neon data base, the agreement was acceptable with the exclusion of one set suspected to be in the transition boiling regime. For the water data base at reduced pressure greater than 0.05 the agreement is generally good. At lower reduced pressures, the water data scatter and the calculated temperature becomes a function of flow rate.

  3. Morphological control in polymer solar cells using low-boiling-point solvent additives

    NASA Astrophysics Data System (ADS)

    Mahadevapuram, Rakesh C.

    In the global search for clean, renewable energy sources, organic photovoltaics (OPVs) have recently been given much attention. Popular modern-day OPVs are made from solution-processible, carbon-based polymers (e.g. the model poly(3-hexylthiophene) that are intimately blended with fullerene derivatives (e.g. [6,6]-phenyl-C71-butyric acid methyl ester) to form what is known as the dispersed bulk-heterojunction (BHJ). This BHJ architecture has produced some of the most efficient OPVs to date, with reports closing in on 10% power conversion efficiency. To push efficiencies further into double digits, many groups have identified the BHJ nanomorphology---that is, the phase separations and grain sizes within the polymer: fullerene composite---as a key aspect in need of control and improvement. As a result, many methods, including thermal annealing, slow-drying (solvent) annealing, vapor annealing, and solvent additives, have been developed and studied to promote BHJ self-organization. Processing organic photovoltaic (OPV) blend solutions with high-boiling-point solvent additives has recently been used for morphological control in BHJ OPV cells. Here we show that even low-boiling-point solvents can be effective additives. When P3HT:PCBM OPV cells were processed with a low-boiling-point solvent tetrahydrafuran as an additive in parent solvent o-dichlorobenzene, charge extraction increased leading to fill factors as high as 69.5%, without low work-function cathodes, electrode buffer layers or thermal treatment. This was attributed to PCBM demixing from P3HT domains and better vertical phase separation, as indicated by photoluminescence lifetimes, hole mobilities, and shunt leakage currents. Dependence on solvent parameters and applicability beyond P3HT system was also investigated.

  4. Experimental study of flash boiling spray vaporization through quantitative vapor concentration and liquid temperature measurements

    NASA Astrophysics Data System (ADS)

    Zhang, Gaoming; Hung, David L. S.; Xu, Min

    2014-08-01

    Flash boiling sprays of liquid injection under superheated conditions provide the novel solutions of fast vaporization and better air-fuel mixture formation for internal combustion engines. However, the physical mechanisms of flash boiling spray vaporization are more complicated than the droplet surface vaporization due to the unique bubble generation and boiling process inside a superheated bulk liquid, which are not well understood. In this study, the vaporization of flash boiling sprays was investigated experimentally through the quantitative measurements of vapor concentration and liquid temperature. Specifically, the laser-induced exciplex fluorescence technique was applied to distinguish the liquid and vapor distributions. Quantitative vapor concentration was obtained by correlating the intensity of vapor-phase fluorescence with vapor concentration through systematic corrections and calibrations. The intensities of two wavelengths were captured simultaneously from the liquid-phase fluorescence spectra, and their intensity ratios were correlated with liquid temperature. The results show that both liquid and vapor phase of multi-hole sprays collapse toward the centerline of the spray with different mass distributions under the flash boiling conditions. Large amount of vapor aggregates along the centerline of the spray to form a "gas jet" structure, whereas the liquid distributes more uniformly with large vortexes formed in the vicinity of the spray tip. The vaporization process under the flash boiling condition is greatly enhanced due to the intense bubble generation and burst. The liquid temperature measurements show strong temperature variations inside the flash boiling sprays with hot zones present in the "gas jet" structure and vortex region. In addition, high vapor concentration and closed vortex motion seem to have inhibited the heat and mass transfer in these regions. In summary, the vapor concentration and liquid temperature provide detailed information concerning the heat and mass transfer inside flash boiling sprays, which is important for the understanding of its unique vaporization process.

  5. A new procedure for the determination of distillation temperature distribution of high-boiling petroleum products and fractions.

    PubMed

    Boczkaj, Grzegorz; Przyjazny, Andrzej; Kami?ski, Marian

    2011-03-01

    The distribution of distillation temperatures of liquid and semi-fluid products, including petroleum fractions and products, is an important process and practical parameter. It provides information on properties of crude oil and content of particular fractions, classified on the basis of their boiling points, as well as the optimum conditions of atmospheric or vacuum distillation. At present, the distribution of distillation temperatures is often investigated by simulated distillation (SIMDIS) using capillary gas chromatography (CGC) with a short capillary column with polydimethylsiloxane as the stationary phase. This paper presents the results of investigations on the possibility of replacing currently used CGC columns for SIMDIS with a deactivated fused silica capillary tube without any stationary phase. The SIMDIS technique making use of such an empty fused silica column allows a considerable lowering of elution temperature of the analytes, which results in a decrease of the final oven temperature while ensuring a complete separation of the mixture. This eliminates the possibility of decomposition of less thermally stable mixture components and bleeding of the stationary phase which would result in an increase of the detector signal. It also improves the stability of the baseline, which is especially important in the determination of the end point of elution, which is the basis for finding the final temperature of distillation. This is the key parameter for the safety process of hydrocracking, where an excessively high final temperature of distillation of a batch can result in serious damage to an expensive catalyst bed. This paper compares the distribution of distillation temperatures of the fraction from vacuum distillation of petroleum obtained using SIMDIS with that obtained by the proposed procedure. A good agreement between the two procedures was observed. In addition, typical values of elution temperatures of n-paraffin standards obtained by the two procedures were compared. Finally, the agreement between boiling points of polar compounds determined from their retention times and actual boiling points was investigated. PMID:21153592

  6. Generalized syntheses of nanocrystal-graphene hybrids in high-boiling-point organic solvents

    NASA Astrophysics Data System (ADS)

    Pang, Danny Wei-Ping; Yuan, Fang-Wei; Chang, Yan-Cheng; Li, Guo-An; Tuan, Hsing-Yu

    2012-07-01

    Nanocrystal-graphene have been proposed as a new kind of promising hybrid for a wide range of application areas including catalysts, electronics, sensors, biomedicine, and energy storage, etc. Although a variety of methods have been developed for the preparation of hybrids, a facile and general synthetic approach is still highly required. In this study, nanocrystal-graphene hybrids were successfully synthesized in high-boiling-point organic solvents. Graphene oxide (GO) nanosheets were modified by oleylamine (OLA) to form a OLA-GO complex in order to be readily incorporated into hydrophobic synthesis. A rich library of highly crystalline nanocrystals, with types including noble metal, metal oxide, magnetic material and semiconductor were successfully grown on chemically converted graphene (CCG), which is simultaneously reduced from GO during the synthesis. High boiling-point solvents afford sufficient thermal energy to assure the high-quality crystalline nature of NCs, therefore the post-annealing process is obviated. Controlled experiments revealed that OLA-GO triggers heterogeneous nucleation and serves as excellent nuclei anchorage media. The protocol developed here brings one step closer to achieve ``unity in diversity'' on the preparation of nanocrystal-graphene hybrids.Nanocrystal-graphene have been proposed as a new kind of promising hybrid for a wide range of application areas including catalysts, electronics, sensors, biomedicine, and energy storage, etc. Although a variety of methods have been developed for the preparation of hybrids, a facile and general synthetic approach is still highly required. In this study, nanocrystal-graphene hybrids were successfully synthesized in high-boiling-point organic solvents. Graphene oxide (GO) nanosheets were modified by oleylamine (OLA) to form a OLA-GO complex in order to be readily incorporated into hydrophobic synthesis. A rich library of highly crystalline nanocrystals, with types including noble metal, metal oxide, magnetic material and semiconductor were successfully grown on chemically converted graphene (CCG), which is simultaneously reduced from GO during the synthesis. High boiling-point solvents afford sufficient thermal energy to assure the high-quality crystalline nature of NCs, therefore the post-annealing process is obviated. Controlled experiments revealed that OLA-GO triggers heterogeneous nucleation and serves as excellent nuclei anchorage media. The protocol developed here brings one step closer to achieve ``unity in diversity'' on the preparation of nanocrystal-graphene hybrids. Electronic supplementary information (ESI) available: detail of experimental parameters, AFM, FTIR, XRD, XPS spectra, and other TEM images of GO, CCG and NC-CCG. See DOI: 10.1039/c2nr30915g

  7. Change points of global temperature

    NASA Astrophysics Data System (ADS)

    Cahill, Niamh; Rahmstorf, Stefan; Parnell, Andrew C.

    2015-08-01

    We aim to address the question of whether or not there is a significant recent hiatus, pause or slowdown of global temperature rise. Using a statistical technique known as change point (CP) analysis we identify the changes in four global temperature records and estimate the rates of temperature rise before and after these changes occur. For each record the results indicate that three CPs are enough to accurately capture the variability in the data with no evidence of any detectable change in the global warming trend since ?1970. We conclude that the term hiatus or pause cannot be statistically justified.

  8. Boiling Heat Transfer Measurements on Highly Conductive Surfaces Using Microscale Heater and Temperature Arrays

    NASA Technical Reports Server (NTRS)

    Kim, J.; Bae, S. W.; Whitten, M. W.; Mullen, J. D.; Quine, R. W.; Kalkur, T. S.

    1999-01-01

    Two systems have been developed to study boiling heat transfer on the microscale. The first system utilizes a 32 x 32 array of diodes to measure the local temperature fluctuations during boiling on a silicon wafer heated from below. The second system utilizes an array of 96 microscale heaters each maintained at constant surface temperature using electronic feedback loops. The power required to keep each heater at constant temperature is measured, enabling the local heat transfer coefficient to be determined. Both of these systems as well as some preliminary results are discussed.

  9. Full evaporation headspace gas chromatography for sensitive determination of high boiling point volatile organic compounds in low boiling matrices.

    PubMed

    Mana Kialengila, Didi; Wolfs, Kris; Bugalama, John; Van Schepdael, Ann; Adams, Erwin

    2013-11-01

    Determination of volatile organic components (VOC's) is often done by static headspace gas chromatography as this technique is very robust and combines easy sample preparation with good selectivity and low detection limits. This technique is used nowadays in different applications which have in common that they have a dirty matrix which would be problematic in direct injection approaches. Headspace by nature favors the most volatile compounds, avoiding the less volatile to reach the injector and column. As a consequence, determination of a high boiling solvent in a lower boiling matrix becomes challenging. Determination of VOCs like: xylenes, cumene, N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), N,N-dimethylacetamide (DMA), N-methyl-2-pyrrolidone (NMP), 1,3-dimethyl-2-imidazolidinone (DMI), benzyl alcohol (BA) and anisole in water or water soluble products are an interesting example of the arising problems. In this work, a headspace variant called full evaporation technique is worked out and validated for the mentioned solvents. Detection limits below 0.1 μg/vial are reached with RSD values below 10%. Mean recovery values ranged from 92.5 to 110%. The optimized method was applied to determine residual DMSO in a water based cell culture and DMSO and DMA in tetracycline hydrochloride (a water soluble sample). PMID:24103808

  10. Boiling Lake of Dominica, West Indies: High-temperature volcanic crater lake dynamics

    NASA Astrophysics Data System (ADS)

    Fournier, N.; Witham, F.; Moreau-Fournier, M.; Bardou, L.

    2009-02-01

    The Boiling Lake of Dominica has exhibited stable high-temperature behavior for at least 150 a. This stability is punctuated by occasional crises involving rapid filling and draining of the lake and changes in water temperature. The most recent such crisis occurred in December 2004 to April 2005. Using the results of previous theoretical and experimental work on analogue models, we present a combined thermal, hydrological, and fluid mechanical model of the Boiling Lake. This reveals that the lake appears to be suspended above the local water table by a constant supply of rising steam bubbles sourced from the boiling of groundwater near an igneous intrusion. The bubbles condense in the Boiling Lake, maintaining the temperature at 90C. The geometry of the lake-conduit system provides a mechanism for instability, with a denser liquid lake overlying a bubbly fractured permeable conduit. Following a sufficiently large perturbation, the whole lake rapidly drains until the surface is at the local water table level. The persistent gas supply then reinitiates filling. We propose that local seismic activity may have caused shock nucleation of bubbles within the conduit and triggered the instability of the Boiling Lake.

  11. Topological indices based on vertex, distance, and ring: on the boiling points of paraffins and cycloalkanes.

    PubMed

    Cao, C; Yuan, H

    2001-01-01

    Vertex, distance, and ring (in cyclic compounds) are three essential structure elements of a molecular graph, based on which three new topological indices VDI, OEI, and RDI are proposed. Multiple regression analysis was carried out against the boiling points of 343 hydrocarbons(160 paraffins and 183 cycloalkanes) with VDI, OEI, RDI, and N(2/3)(N is the number of carbon atoms) together, and a good QSPR model was obtained: ln(577 - Bp) = 6.729609 - 0.154107N(2/3) + 2.285632 x 10(-2)VDI - 7.921410 x 10(-3)OEI - 1.821962 x 10(-2)RDI (F = 6455.09, r = 0.9935, rms = 6.44 degrees C, n = 343). PMID:11500103

  12. Homochirality beyond grinding: deracemizing chiral crystals by temperature gradient under boiling.

    PubMed

    Viedma, Cristbal; Cintas, Pedro

    2011-12-28

    A single-chirality solid phase can be obtained in boiling solutions containing a racemic mixture of left- and right-handed enantiomorphous crystals due to dissolution-crystallization cycles induced by a temperature gradient. This phenomenon provides further insights into asymmetric amplification mechanisms under presumably prebiotic conditions. PMID:22053323

  13. Superconducting state above the boiling point of liquid nitrogen in the GaH3 compound

    NASA Astrophysics Data System (ADS)

    Szcz??niak, R.; Durajski, A. P.

    2014-01-01

    The thermodynamic parameters of the superconducting state in the GaH3 compound under a pressure of 120 GPa have been determined. A wide range of Coulomb pseudopotential values has been taken into account: ???<0.1,0.2>. It has been shown that, for the considered values of ??, the superconducting state is characterized by a critical temperature which is higher than the boiling temperature of liquid nitrogen: TC?(122.99,89.78) K. Other parameters significantly deviate from the predictions of BCS theory. In particular, the ratio of the energy gap to the critical temperature (R? ? 2?(0)/kBTC) changes in the range from 4.15 to 4.03. The ratio of the specific heat jump to the specific heat in the normal state (RC ? ?C(TC)/CN(TC)) takes values from 1.87 to 1.58. The parameter {R}_{{H}}\\equiv {T}_{{C}}{C}^{{N}}({T}_{{C}})/{H}_{{C}}^{2}(0), where HC is the thermodynamic critical field, is characterized in the following manner: RH?<0.147,0.150>. Finally, it has been proven that the maximum value of the electron effective mass ({m}_{{e}}^{\\star }) equals 2.66me, where the symbol me denotes the electron band mass.

  14. Experimental Research on Dryout Point of Flow Boiling in Narrow Annuli

    SciTech Connect

    Ge Ping Wu; Sui Zheng Qiu; Guang Hai Su; Dou Nan Jia

    2006-07-01

    An experimental research on the dryout point of flow boiling in narrow annuli is conducted under low mass flux with 1.5 mm and 1.0 mm gap, respectively. Distilled water is used as work fluid, the range of pressure is from 2.0 to 4.0 MPa and that of mass flux is 26.0{approx}69.0 kg/(m{sup 2}. s). The relation of CHF and critical qualities with mass flux and pressure are revealed. It is found that the critical qualities decrease with the mass flux and increase with the inlet qualities in externally heated annuli. Under the same conditions critical qualities in outer tube are always larger than that in inner tube. KyTaTeLaDe3e's correlations is cited and modified to predict the location of dryout and proved to be not a proper one. Considering in detail the effects of the geometry of annuli and heat flux on dryout, an empirical correction is finally developed to predict dryout point in narrow annuli under low mass flux condition which has a good agreement with experimental data. (authors)

  15. Method of and apparatus for determining deposition-point temperature

    DOEpatents

    Mansure, A.J.; Spates, J.J.; Martin, S.J.

    1998-10-27

    Acoustic-wave sensor apparatus and method are disclosed for analyzing a normally liquid petroleum-based composition for monitoring deposition-point temperature. The apparatus includes at least one acoustic-wave device such as SAW, QCM, FPM, TSM or APM type devices in contact with the petroleum-based composition for sensing or detecting the surface temperature at which deposition occurs and/or rate of deposition as a function of temperature by sensing an accompanying change in frequency, phase shift, damping voltage or damping current of an electrical oscillator to a known calibrated condition. The acoustic wave device is actively cooled to monitor the deposition of constituents such as paraffins by determining the point at which solids from the liquid composition begin to form on the acoustic wave device. The acoustic wave device can be heated to melt or boil off the deposits to reset the monitor and the process can be repeated. 5 figs.

  16. Method of and apparatus for determining deposition-point temperature

    DOEpatents

    Mansure, Arthur J.; Spates, James J.; Martin, Stephen J.

    1998-01-01

    Acoustic-wave sensor apparatus and method for analyzing a normally liquid petroleum-based composition for monitoring deposition-point temperature. The apparatus includes at least one acoustic-wave device such as SAW, QCM, FPM, TSM or APM type devices in contact with the petroleum-based composition for sensing or detecting the surface temperature at which deposition occurs and/or rate of deposition as a function of temperature by sensing an accompanying change in frequency, phase shift, damping voltage or damping current of an electrical oscillator to a known calibrated condition. The acoustic wave device is actively cooled to monitor the deposition of constituents such as paraffins by determining the point at which solids from the liquid composition begin to form on the acoustic wave device. The acoustic wave device can be heated to melt or boil off the deposits to reset the monitor and the process can be repeated.

  17. Chemical characterization and genotoxic potential related to boiling point for fractionally distilled SRC-I coal liquids

    SciTech Connect

    Wilson, B.W.; Pelroy, R.A.; Mahlum, D.D.

    1982-07-01

    This report summarizes selected research efforts oriented toward ameliorating the genotoxic potential of direct coal liquefaction materials through modification or optimization of process conditions. The studies described were conducted to evaluate the utility of optimized distillation for coal liquids from the SRC-I process. SRC-I process solvent was distilled into 50/sup 0/F-range boiling point (bp) cuts. Analysis of amino-PAH (APAH) showed that mutagenic APAHs containing 3 or more rings were found primarily in fractions boiling above 750/sup 0/F. Three microbial tester strains were used to screen for genetically active agents in the SRC-I distillate bp cuts. Reverse mutation with the Ames tester strain TA98 demonstrated that mutagens were concentrated in the bp cuts boiling above 700/sup 0/F. For this tester strain most of the genetic activity in these distillates was attributable to chemical fractions enriched in APAH having 3 or more rings. Mutagenicity data obtained with TA98 was in good agreement with sk in carcinogenesis results from the mouse-skin initiation/promotion (in vivo) test system. The strongest response in the forward mutation assay did not occur in the most carcinogenically active fractions. Results of initiation/promotion experiments used to measure the relative potency of bp cuts as initiators of mouse skin carcinogenesis again showed that fractions boiling above 750/sup 0/F. Compounds reaching their highest concentrations in the highest boiling and most carcinogenically active cut included known carcinogens such as benzo(a)pyrene and dimethyl benzanthracene. Thus, all biomedical test results indicate that consideration should be given to conducting distillation so as to minimize, in the distillate product, the concentrations of those biologically active compounds found in cuts boiling above 700/sup 0/C.

  18. Review of magnetic properties and magnetocaloric effect in the intermetallic compounds of rare earth with low boiling point metals

    NASA Astrophysics Data System (ADS)

    Ling-Wei, Li

    2016-03-01

    The magnetocaloric effect (MCE) in many rare earth (RE) based intermetallic compounds has been extensively investigated during the last two decades, not only due to their potential applications for magnetic refrigeration but also for better understanding of the fundamental problems of the materials. This paper reviews our recent progress on studying the magnetic properties and MCE in some binary or ternary intermetallic compounds of RE with low boiling point metal(s) (Zn, Mg, and Cd). Some of them exhibit promising MCE properties, which make them attractive for low temperature magnetic refrigeration. Characteristics of the magnetic transition, origin of large MCE, as well as the potential application of these compounds are thoroughly discussed. Additionally, a brief review of the magnetic and magnetocaloric properties in the quaternary rare earth nickel boroncarbides RENi2B2C superconductors is also presented. Project supported by the National Natural Science Foundation of China (Grant Nos. 11374081 and 11004044), the Fundamental Research Funds for the Central Universities, China (Grant Nos. N150905001, L1509006, and N140901001), the Japan Society for the Promotion of Science Postdoctoral Fellowships for Foreign Researchers (Grant No. P10060), and the Alexander von Humboldt (AvH) Foundation (Research stipend to L. Li).

  19. A Closer Look at Trends in Boiling Points of Hydrides: Using an Inquiry-Based Approach to Teach Intermolecular Forces of Attraction

    ERIC Educational Resources Information Center

    Glazier, Samantha; Marano, Nadia; Eisen, Laura

    2010-01-01

    We describe how we use boiling-point trends of group IV-VII hydrides to introduce intermolecular forces in our first-year general chemistry classes. Starting with the idea that molecules in the liquid state are held together by some kind of force that must be overcome for boiling to take place, students use data analysis and critical reasoning to…

  20. A Closer Look at Trends in Boiling Points of Hydrides: Using an Inquiry-Based Approach to Teach Intermolecular Forces of Attraction

    ERIC Educational Resources Information Center

    Glazier, Samantha; Marano, Nadia; Eisen, Laura

    2010-01-01

    We describe how we use boiling-point trends of group IV-VII hydrides to introduce intermolecular forces in our first-year general chemistry classes. Starting with the idea that molecules in the liquid state are held together by some kind of force that must be overcome for boiling to take place, students use data analysis and critical reasoning to

  1. Below and above boiling point comparison of microwave irradiation and conductive heating for municipal sludge digestion under identical heating/cooling profiles.

    PubMed

    Hosseini Koupaie, E; Eskicioglu, C

    2015-01-01

    This research provides a comprehensive comparison between microwave (MW) and conductive heating (CH) sludge pretreatments under identical heating/cooling profiles at below and above boiling point temperatures. Previous comparison studies were constrained to an uncontrolled or a single heating rate due to lack of a CH equipment simulating MW under identical thermal profiles. In this research, a novel custom-built pressure-sealed vessel which could simulate MW pretreatment under identical heating/cooling profiles was used for CH pretreatment. No statistically significant difference was proven between MW and CH pretreatments in terms of sludge solubilization, anaerobic biogas yield and organics biodegradation rate (p-value>0.05), while statistically significant effects of temperature and heating rate were observed (p-value<0.05). These results explain the contradictory results of previous studies in which only the final temperature (not heating/cooling rates) was controlled. PMID:25863200

  2. Phase Separation, Density Fluctuations, and Boiling Near the Liquid-Gas Critical Point

    NASA Astrophysics Data System (ADS)

    Hegseth, John; Oprisan, Ana; Roy, Arun; Nikolayev, Vadim; Beysens, Daniel; Garrabos, Yves; Lecoutre-Chabot, Carole

    2002-11-01

    A pure liquid-gas mixture is one of the simplest examples of a soft-matter system. In fact, when co-existing gas and liquid phases of pure fluid are heated to their critical point, large-scale density fluctuations make the fluid extremely compressible (to external forces), expandable (to heating), slows the diffusive transport, and decreases the surface tension. In principle these properties and others either diverge to infinity or converge to zero at the critical temperature. These properties lead to some very unusual behavior: large density gradients at the laboratory scale, a large mechanical response to heating, and perfect wetting of a solid wall by the liquid phase (zero contact-angle). We have further simplified this system by performing experiments in weightlessness (Mir spaces station). By controlling the fluid's temperature, these properties may be varied over large ranges in a single sample. When the fluid is driven out of equilibrium by a fast temperature quench from the single-phase (supercritical fluid) state into the two-phase state, we have observed universal growth laws of minority domains (gas bubbles) during phase separation. Prior to this quench we have also observed density fluctuations using optical microscopy near the critical point. When heat is applied to a liquid-gas mixture, we have observed a spectacular spreading of a gas bubble along a hot solid wall as well as gas bubble over-heating (where the interior of a gas bubble gains a higher temperature than the heating wall). Although this gas phase over-heating appears to violate the second law, it is really a transient our-of-equilibrium effect. Inside of these unusual bubbles we also have observed unusually large variations in liquid wetting film thickness that often appear to evolve into spreading contact lines on the sapphire wall when heat is applied. We have observed coarsening and growth of minority domains (gas bubbles) in SF6 near its liquid-gas critical point. Phase separation in our constant density samples was induced in our constant volume cells by temperature quenches in weightless conditions (Mir station), while visualizing density fluctuations and domain growth using optical microscopy. The optics of the formation of the density fluctuation images will be discussed. The well-known statistics of the density fluctuations provide natural space and time scales for domain growth. Previous experiments have documented two morphologies and two associated growth laws with a sharp transition between the two. This transition appears to be controlled by the minority volume fraction. While the slow, t 1/3 growth, for disconnected morphologies, is understood as a diffusion process, the fast growth, t1 growth, for connected domains, is less well-understood. We will discuss several shallow quenching sequences at the critical density (+/-0.02%) and slightly off-critical where we have observed fast linear growth.

  3. Oxidation and formation of oxidation products of ?-carotene at boiling temperature.

    PubMed

    Zeb, Alam

    2012-04-01

    ?-Carotene is one of the most important lipid component extensively used in food industries as source of pro-vitamin A and colorant. During processing and storage ?-carotene is oxidized and degraded to various oxidation compounds. Some of these compounds are also the key aroma compounds in certain flowers, vegetables and fruits. The methods for analysis and determination of these oxidized products formed during food boiling or preparation are key to the understanding the chemistry of these compounds. This paper presents a novel analytical method incorporating high performance liquid chromatography with diode array and mass spectrometric detection for the characterization of oxidation, isomerization and oxidation products of ?-carotene in toluene at boiling temperature. HPLC and APCI-MS was optimized using oxidized sample and flow injection analysis of the standard ?-carotene respectively. ?-Carotene was oxidized in the Rancimat at 110C for 30, 60 and 90 min. The oxidized samples were than analyzed by HPLC system at 450 nm and 350 nm as well as scanning and single ion monitoring mass spectrometry. A total of ten oxidation products and three Z-isomers were reported. Extensive isomerization was observed during treatment at the control accelerated conditions. The oxidation products include five apo-carotenals, three diepoxides, one mono-epoxide and one short chain species. Results show that the method was reproducible, accurate and reliable for the separation and identification of oxidation products of ?-carotene. PMID:22387098

  4. Remote temperature-set-point controller

    DOEpatents

    Burke, William F. (Crest Hill, IL); Winiecki, Alan L. (Downers Grove, IL)

    1986-01-01

    An instrument for carrying out mechanical strain tests on metallic samples with the addition of an electrical system for varying the temperature with strain, the instrument including opposing arms and associated equipment for holding a sample and varying the mechanical strain on the sample through a plurality of cycles of increasing and decreasing strain within predetermined limits, circuitry for producing an output signal representative of the strain during the tests, apparatus including a set point and a coil about the sample for providing a controlled temperature in the sample, and circuitry interconnected between the strain output signal and set point for varying the temperature of the sample linearly with strain during the tests.

  5. Gas chromatographic simulated distillation-mass spectrometry for the determination of the boiling point distributions of crude oils

    PubMed

    Roussis; Fitzgerald

    2000-04-01

    The coupling of gas chromatographic simulated distillation with mass spectrometry for the determination of the distillation profiles of crude oils is reported. The method provides the boiling point distributions of both weight and volume percent amounts. The weight percent distribution is obtained from the measured total ion current signal. The total ion current signal is converted to weight percent amount by calibration with a reference crude oil of a known distillation profile. Knowledge of the chemical composition of the crude oil across the boiling range permits the determination of the volume percent distribution. The long-term repeatability is equivalent to or better than the short-term repeatability of the currently available American Society for Testing and Materials (ASTM) gas chromatographic method for simulated distillation. Results obtained by the mass spectrometric method are in very good agreement with results obtained by conventional methods of physical distillation. The compositional information supplied by the method can be used to extensively characterize crude oils. PMID:10763233

  6. Sediment microbial communities in Great Boiling Spring are controlled by temperature and distinct from water communities

    PubMed Central

    Cole, Jessica K; Peacock, Joseph P; Dodsworth, Jeremy A; Williams, Amanda J; Thompson, Daniel B; Dong, Hailiang; Wu, Geng; Hedlund, Brian P

    2013-01-01

    Great Boiling Spring is a large, circumneutral, geothermal spring in the US Great Basin. Twelve samples were collected from water and four different sediment sites on four different dates. Microbial community composition and diversity were assessed by PCR amplification of a portion of the small subunit rRNA gene using a universal primer set followed by pyrosequencing of the V8 region. Analysis of 164?178 quality-filtered pyrotags clearly distinguished sediment and water microbial communities. Water communities were extremely uneven and dominated by the bacterium Thermocrinis. Sediment microbial communities grouped according to temperature and sampling location, with a strong, negative, linear relationship between temperature and richness at all taxonomic levels. Two sediment locations, Site A (8780?C) and Site B (79?C), were predominantly composed of single phylotypes of the bacterial lineage GAL35 (p?=36.1%), Aeropyrum (p?=16.6%), the archaeal lineage pSL4 (p?=15.9%), the archaeal lineage NAG1 (p?=10.6%) and Thermocrinis (p?=7.6%). The ammonia-oxidizing archaeon Candidatus Nitrosocaldus' was relatively abundant in all sediment samples <82?C (p?=9.51%), delineating the upper temperature limit for chemolithotrophic ammonia oxidation in this spring. This study underscores the distinctness of water and sediment communities in GBS and the importance of temperature in driving microbial diversity, composition and, ultimately, the functioning of biogeochemical cycles. PMID:23235293

  7. Time and Space Resolved Wall Temperature Measurements during Nucleate Boiling with Constant Heat Flux Boundary Conditions

    NASA Technical Reports Server (NTRS)

    Myers, Jerry G.; Hussey, Sam W.; Yee, Glenda F.; Yerramilli, Vamsee K.; Kim, Jungho

    2005-01-01

    The lack of temporally and spatially resolved measurements under nucleate bubbles has complicated efforts to fully explain pool-boiling phenomena. The objective of this current work is to acquire time and space resolved temperature distributions under nucleate bubbles on a constant heat flux surface. This was performed using a microheater array with 100 micron resolution that allowed effectively simultaneous measurements of surface temperature while supplying a constant dissipative heat flux. This data is then correlated with high speed (> 1000Hz) visual recordings of the bubble growth and departure from the heater surface acquired from below and from the side of the heater. The data indicate that a significant source of energy during bubble nucleation and initial growth is the superheated layer around the bubble. Bubble coalescence was not observed to decrease surface temperature as significantly as bubble departure from the surface. Since bubble departure is typically followed by a sharp increase in the heater surface temperature, it is surmised that the departing bubble effectively removes the superheated layer, allowing a high local heat transfer rate with the bulk fluid through transient conduction/micro-convection during rewetting.

  8. Secondary pool boiling effects

    NASA Astrophysics Data System (ADS)

    Kruse, C.; Tsubaki, A.; Zuhlke, C.; Anderson, T.; Alexander, D.; Gogos, G.; Ndao, S.

    2016-02-01

    A pool boiling phenomenon referred to as secondary boiling effects is discussed. Based on the experimental trends, a mechanism is proposed that identifies the parameters that lead to this phenomenon. Secondary boiling effects refer to a distinct decrease in the wall superheat temperature near the critical heat flux due to a significant increase in the heat transfer coefficient. Recent pool boiling heat transfer experiments using femtosecond laser processed Inconel, stainless steel, and copper multiscale surfaces consistently displayed secondary boiling effects, which were found to be a result of both temperature drop along the microstructures and nucleation characteristic length scales. The temperature drop is a function of microstructure height and thermal conductivity. An increased microstructure height and a decreased thermal conductivity result in a significant temperature drop along the microstructures. This temperature drop becomes more pronounced at higher heat fluxes and along with the right nucleation characteristic length scales results in a change of the boiling dynamics. Nucleation spreads from the bottom of the microstructure valleys to the top of the microstructures, resulting in a decreased surface superheat with an increasing heat flux. This decrease in the wall superheat at higher heat fluxes is reflected by a "hook back" of the traditional boiling curve and is thus referred to as secondary boiling effects. In addition, a boiling hysteresis during increasing and decreasing heat flux develops due to the secondary boiling effects. This hysteresis further validates the existence of secondary boiling effects.

  9. Measurement of thermodynamic temperature of high temperature fixed points

    SciTech Connect

    Gavrilov, V. R.; Khlevnoy, B. B.; Otryaskin, D. A.; Grigorieva, I. A.; Samoylov, M. L.; Sapritsky, V. I.

    2013-09-11

    The paper is devoted to VNIIOFI's measurements of thermodynamic temperature of the high temperature fixed points Co-C, Pt-C and Re-C within the scope of the international project coordinated by the Consultative Committee for Thermometry working group 5 'Radiation Thermometry'. The melting temperatures of the fixed points were measured by a radiance mode radiation thermometer calibrated against a filter radiometer with known irradiance spectral responsivity via a high temperature black body. This paper describes the facility used for the measurements, the results and estimated uncertainties.

  10. Low Temperature Regenerators for Zero Boil-Off Liquid Hydrogen Pulse Tube Cryocoolers

    NASA Technical Reports Server (NTRS)

    Salerno, Louis J.; Kashani, Ali; Helvensteijn, Ben; Kittel, Peter; Arnoldm James O. (Technical Monitor)

    2002-01-01

    Recently, a great deal of attention has been focused on zero boil-off (ZBO) propellant storage as a means of minimizing the launch mass required for long-term exploration missions. A key component of ZBO systems is the cooler. Pulse tube coolers offer the advantage of zero moving mass at the cold head, and recent advances in lightweight, high efficiency cooler technology have paved the way for reliable liquid oxygen (LOx) temperature coolers to be developed which are suitable for flight ZBO systems. Liquid hydrogen (LH2) systems, however, are another matter. For ZBO liquid hydrogen systems, cooling powers of 1-5 watts are required at 20 K. The final development from tier for these coolers is to achieve high efficiency and reliability at lower operating temperatures. Most of the life-limiting issues of flight Stirling and pulse tube coolers are associated with contamination, drive mechanisms, and drive electronics. These problems are well in hand in the present generation coolers. The remaining efficiency and reliability issues reside with the low temperature regenerators. This paper will discuss advances to be made in regenerators for pulse tube LH2 ZBO coolers, present some historical background, and discuss recent progress in regenerator technology development using alloys of erbium.

  11. Remote temperature-set-point controller

    DOEpatents

    Burke, W.F.; Winiecki, A.L.

    1984-10-17

    An instrument is described for carrying out mechanical strain tests on metallic samples with the addition of means for varying the temperature with strain. The instrument includes opposing arms and associated equipment for holding a sample and varying the mechanical strain on the sample through a plurality of cycles of increasing and decreasing strain within predetermined limits, circuitry for producing an output signal representative of the strain during the tests, apparatus including a a set point and a coil about the sample for providing a controlled temperature in the sample, and circuitry interconnected between the strain output signal and set point for varying the temperature of the sample linearly with strain during the tests.

  12. Flow boiling heat transfer coefficients at cryogenic temperatures for multi-component refrigerant mixtures of nitrogen-hydrocarbons

    NASA Astrophysics Data System (ADS)

    Ardhapurkar, P. M.; Sridharan, Arunkumar; Atrey, M. D.

    2014-01-01

    The recuperative heat exchanger governs the overall performance of the mixed refrigerant Joule-Thomson cryocooler. In these heat exchangers, the non-azeotropic refrigerant mixture of nitrogen-hydrocarbons undergoes boiling and condensation simultaneously at cryogenic temperature. Hence, the design of such heat exchanger is crucial. However, due to lack of empirical correlations to predict two-phase heat transfer coefficients of multi-component mixtures at low temperature, the design of such heat exchanger is difficult.

  13. Determination of the Latent Heats and Triple Point of Perfluorocyclobutane

    ERIC Educational Resources Information Center

    Briggs, A. G.; Strachan, A. N.

    1977-01-01

    Proposes the use of Perfluorocyclobutane in physical chemistry courses to conduct experiments on latent heat, triple point temperatures and pressures, boiling points, and entropy of vaporization. (SL)

  14. Identification of polybrominated diphenyl ether metabolites based on calculated boiling points from COSMO-RS, experimental retention times, and mass spectral fragmentation patterns.

    PubMed

    Simpson, Scott; Gross, Michael S; Olson, James R; Zurek, Eva; Aga, Diana S

    2015-02-17

    The COnductor-like Screening MOdel for Realistic Solvents (COSMO-RS) was used to predict the boiling points of several polybrominated diphenyl ethers (PBDEs) and methylated derivatives (MeO-BDEs) of monohydroxylated BDE (OH-BDE) metabolites. The linear correlation obtained by plotting theoretical boiling points calculated by COSMO-RS against experimentally determined retention times from gas chromatography-mass spectrometry facilitated the identification of PBDEs and OH-BDEs. This paper demonstrates the applicability of COSMO-RS in identifying unknown PBDE metabolites of 2,2',4,4'-tetrabromodiphenyl ether (BDE-47) and 2,2',4,4',6-pentabromodiphenyl ether (BDE-100). Metabolites of BDE-47 and BDE-100 were formed through individual incubations of each PBDE with recombinant cytochrome P450 2B6. Using calculated boiling points and characteristic mass spectral fragmentation patterns of the MeO-BDE positional isomers, the identities of the unknown monohydroxylated metabolites were proposed to be 2'-hydroxy-2,3',4,4'-tetrabromodiphenyl ether (2'-OH-BDE-66) from BDE-47, and 2'-hydroxy-2,3',4,4',6-pentabromodiphenyl ether (2'-OH-BDE-119) and 4-hydroxy-2,2',3,4',6-pentabromodiphenyl ether (4-OH-BDE-91) from BDE-100. The collective use of boiling points predicted with COSMO-RS, and characteristic mass spectral fragmentation patterns provided a valuable tool toward the identification of isobaric compounds. PMID:25565148

  15. Further Analysis of Boiling Points of Small Molecules, CH[subscript w]F[subscript x]Cl[subscript y]Br[subscript z

    ERIC Educational Resources Information Center

    Beauchamp, Guy

    2005-01-01

    A study to present specific hypothesis that satisfactorily explain the boiling point of a number of molecules, CH[subscript w]F[subscript x]Cl[subscript y]Br[subscript z] having similar structure, and then analyze the model with the help of multiple linear regression (MLR), a data analysis tool. The MLR analysis was useful in selecting the

  16. Investigating the effect of solvent boiling temperature on the active layer morphology of diffusive bilayer solar cells

    NASA Astrophysics Data System (ADS)

    Vohra, Varun; Drling, Bernhard; Higashimine, Koichi; Murata, Hideyuki

    2016-01-01

    Using chlorobenzene as a base solvent for the deposition of the poly(3-hexylthiophene-2,5-diyl) (P3HT) layer in P3HT:phenyl-C61-butyric acid methyl ester diffusive bilayer solar cells, we investigate the effect of adding of small amounts of high-boiling-point solvents with similar chemical structures on the resulting active layer morphologies. The results demonstrate that the crystallinity of the P3HT films as well as the vertical donoracceptor gradient in the active layer can be tuned by this approach. The use of high-boiling-point solvents improved all photovoltaic parameters and resulted in a 32% increase in power conversion efficiency.

  17. Spatial and temporal variation of the surface temperature and heat flux for saturated pool nucleate boiling at lower heat fluxes

    SciTech Connect

    Unal, C.; Pasamehmetoglu, K.O.

    1993-10-01

    The spatial and temporal variations of local surface temperature and heat flux for saturated pool nucleate boiling are investigated parametrically using a numerical model. The numerical model consisted of solving the three-dimensional transient heat conduction equation within the heater subjected to nucleate boiling over its upper surface. The surface topography model to distribute the cavities over the boiling surface used a Monte Carlo scheme. All cavities were assumed to be conical in shape. The cavity radii are obtained using an exponential probability density function with a known mean value. Local surface temperatures showed significant spatial and temporal variations, depending upon the surface topography and the heater material and thickness. However, the surface-averaged temperature showed practically no temporal variation. The temporal variations in local temperatures caused the surface-averaged heat flux to vary significantly. The temporal variations in the surface-averaged heat flux were similar for smooth and rough and thick and thin copper and nickel plates. Results indicated that the use of a classical energy balance equation to evaluate the surface heat flux must consider the spatial variation of the temperature. Results also showed that any thermocouple embedded beneath the surface of the heater does not follow the temporal variations at the surface.

  18. Enzymatic synthesis of sorbitan esters using a low-boiling-point azeotrope as a reaction solvent.

    PubMed

    Sarney, D B; Barnard, M J; Virto, M; Vulfson, E N

    1997-05-20

    Sorbitan esters were prepared by controlled dehydration of sorbitol followed by lipase-catalyzed esterification of the resulting "sorbitan." The reaction was carried out in azeotropic mixtures of tert-butanol/n-hexane. A partial phase diagram to determine the temperature required for the distillation of the azeotrope at a given ratio of the solvents was constructed. The effect of varying concentrations of the two solvents on the rate of esterification and the monoester/diester ratio of the final product was investigated in detail. (c) 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 54: 351-356, 1997. PMID:18634102

  19. Determination of boiling point of petrochemicals by gas chromatography-mass spectrometry and multivariate regression analysis of structural activity relationship.

    PubMed

    Fakayode, Sayo O; Mitchell, Breanna S; Pollard, David A

    2014-08-01

    Accurate understanding of analyte boiling points (BP) is of critical importance in gas chromatographic (GC) separation and crude oil refinery operation in petrochemical industries. This study reported the first combined use of GC separation and partial-least-square (PLS1) multivariate regression analysis of petrochemical structural activity relationship (SAR) for accurate BP determination of two commercially available (D3710 and MA VHP) calibration gas mix samples. The results of the BP determination using PLS1 multivariate regression were further compared with the results of traditional simulated distillation method of BP determination. The developed PLS1 regression was able to correctly predict analytes BP in D3710 and MA VHP calibration gas mix samples, with a root-mean-square-%-relative-error (RMS%RE) of 6.4%, and 10.8% respectively. In contrast, the overall RMS%RE of 32.9% and 40.4%, respectively obtained for BP determination in D3710 and MA VHP using a traditional simulated distillation method were approximately four times larger than the corresponding RMS%RE of BP prediction using MRA, demonstrating the better predictive ability of MRA. The reported method is rapid, robust, and promising, and can be potentially used routinely for fast analysis, pattern recognition, and analyte BP determination in petrochemical industries. PMID:24881546

  20. Highly efficient secondary dewatering of dewatered sewage sludge using low boiling point solvents.

    PubMed

    He, Chao; Chena, Chia-Lung; Xu, Zhirong; Wang, Jing-Yuan

    2014-01-01

    Secondary dewatering of dewatered sludge is imperative to make conventional drying and incineration of sludge more economically feasible. In this study, a secondary dewatering of dewatered sludge with selected solvents (i.e. acetone and ethanol) followed by vacuum filtration and nature drying was investigated to achieve in-depth dewatering. After the entire secondary dewatering process, the sludge was shown to be odourless and the organic matter content was greatly retained. Increased mean particle size of sludge after solvent contact improved solid-liquid separation. With an acetone/sludge ratio of 3:1 (mL:g) in solvent contact and subsequent nature drying at ambient temperature after 24 h, the moisture content of sludge can be reduced to a level less than 20%. It is found that the polysaccharides were mainly precipitated by acetone, whereas the release ratios of protein and DNA were increased significantly as the added acetone volumes were elevated. During nature drying, accumulated evaporation rates of the sludge after solvent contact were 5-6 times higher than original dewatered sludge. Furthermore, sludge after acetone contact had better nature drying performance than ethanol. The two-stage dewatering involves solvent contact dewatering and solvent enhanced evaporation dewatering. Through selecting an appropriate solvent/sludge ratio as well as economical solvents and minimizing the solvent loss in a closed-pilot system, this dewatering process can be competitive in industrial applications. Therefore, this solvent-aided secondary dewatering is an energy-saving technology for effective in-depth dewatering of dewatered sludge and subsequent sludge utilization. PMID:24600846

  1. Boiling radial flow in fractures of varying wall porosity

    SciTech Connect

    Barnitt, Robb Allan

    2000-06-01

    The focus of this report is the coupling of conductive heat transfer and boiling convective heat transfer, with boiling flow in a rock fracture. A series of experiments observed differences in boiling regimes and behavior, and attempted to quantify a boiling convection coefficient. The experimental study involved boiling radial flow in a simulated fracture, bounded by a variety of materials. Nonporous and impermeable aluminum, highly porous and permeable Berea sandstone, and minimally porous and permeable graywacke from The Geysers geothermal field. On nonporous surfaces, the heat flux was not strongly coupled to injection rate into the fracture. However, for porous surfaces, heat flux, and associated values of excess temperature and a boiling convection coefficient exhibited variation with injection rate. Nucleation was shown to occur not upon the visible surface of porous materials, but a distance below the surface, within the matrix. The depth of boiling was a function of injection rate, thermal power supplied to the fracture, and the porosity and permeability of the rock. Although matrix boiling beyond fracture wall may apply only to a finite radius around the point of injection, higher values of heat flux and a boiling convection coefficient may be realized with boiling in a porous, rather than nonporous surface bounded fracture.

  2. Tunable integration of absorption-membrane-adsorption for efficiently separating low boiling gas mixtures near normal temperature

    PubMed Central

    Liu, Huang; Pan, Yong; Liu, Bei; Sun, Changyu; Guo, Ping; Gao, Xueteng; Yang, Lanying; Ma, Qinglan; Chen, Guangjin

    2016-01-01

    Separation of low boiling gas mixtures is widely concerned in process industries. Now their separations heavily rely upon energy-intensive cryogenic processes. Here, we report a pseudo-absorption process for separating low boiling gas mixtures near normal temperature. In this process, absorption-membrane-adsorption is integrated by suspending suitable porous ZIF material in suitable solvent and forming selectively permeable liquid membrane around ZIF particles. Green solvents like water and glycol were used to form ZIF-8 slurry and tune the permeability of liquid membrane surrounding ZIF-8 particles. We found glycol molecules form tighter membrane while water molecules form looser membrane because of the hydrophobicity of ZIF-8. When using mixing solvents composed of glycol and water, the permeability of liquid membrane becomes tunable. It is shown that ZIF-8/water slurry always manifests remarkable higher separation selectivity than solid ZIF-8 and it could be tuned to further enhance the capture of light hydrocarbons by adding suitable quantity of glycol to water. Because of its lower viscosity and higher sorption/desorption rate, tunable ZIF-8/water-glycol slurry could be readily used as liquid absorbent to separate different kinds of low boiling gas mixtures by applying a multistage separation process in one traditional absorption tower, especially for the capture of light hydrocarbons. PMID:26892255

  3. Tunable integration of absorption-membrane-adsorption for efficiently separating low boiling gas mixtures near normal temperature

    NASA Astrophysics Data System (ADS)

    Liu, Huang; Pan, Yong; Liu, Bei; Sun, Changyu; Guo, Ping; Gao, Xueteng; Yang, Lanying; Ma, Qinglan; Chen, Guangjin

    2016-02-01

    Separation of low boiling gas mixtures is widely concerned in process industries. Now their separations heavily rely upon energy-intensive cryogenic processes. Here, we report a pseudo-absorption process for separating low boiling gas mixtures near normal temperature. In this process, absorption-membrane-adsorption is integrated by suspending suitable porous ZIF material in suitable solvent and forming selectively permeable liquid membrane around ZIF particles. Green solvents like water and glycol were used to form ZIF-8 slurry and tune the permeability of liquid membrane surrounding ZIF-8 particles. We found glycol molecules form tighter membrane while water molecules form looser membrane because of the hydrophobicity of ZIF-8. When using mixing solvents composed of glycol and water, the permeability of liquid membrane becomes tunable. It is shown that ZIF-8/water slurry always manifests remarkable higher separation selectivity than solid ZIF-8 and it could be tuned to further enhance the capture of light hydrocarbons by adding suitable quantity of glycol to water. Because of its lower viscosity and higher sorption/desorption rate, tunable ZIF-8/water-glycol slurry could be readily used as liquid absorbent to separate different kinds of low boiling gas mixtures by applying a multistage separation process in one traditional absorption tower, especially for the capture of light hydrocarbons.

  4. Tunable integration of absorption-membrane-adsorption for efficiently separating low boiling gas mixtures near normal temperature.

    PubMed

    Liu, Huang; Pan, Yong; Liu, Bei; Sun, Changyu; Guo, Ping; Gao, Xueteng; Yang, Lanying; Ma, Qinglan; Chen, Guangjin

    2016-01-01

    Separation of low boiling gas mixtures is widely concerned in process industries. Now their separations heavily rely upon energy-intensive cryogenic processes. Here, we report a pseudo-absorption process for separating low boiling gas mixtures near normal temperature. In this process, absorption-membrane-adsorption is integrated by suspending suitable porous ZIF material in suitable solvent and forming selectively permeable liquid membrane around ZIF particles. Green solvents like water and glycol were used to form ZIF-8 slurry and tune the permeability of liquid membrane surrounding ZIF-8 particles. We found glycol molecules form tighter membrane while water molecules form looser membrane because of the hydrophobicity of ZIF-8. When using mixing solvents composed of glycol and water, the permeability of liquid membrane becomes tunable. It is shown that ZIF-8/water slurry always manifests remarkable higher separation selectivity than solid ZIF-8 and it could be tuned to further enhance the capture of light hydrocarbons by adding suitable quantity of glycol to water. Because of its lower viscosity and higher sorption/desorption rate, tunable ZIF-8/water-glycol slurry could be readily used as liquid absorbent to separate different kinds of low boiling gas mixtures by applying a multistage separation process in one traditional absorption tower, especially for the capture of light hydrocarbons. PMID:26892255

  5. Application of high-speed digital holographic interferometry for the analysis of temperature distributions and velocity fields in subcooled flow boiling

    NASA Astrophysics Data System (ADS)

    Bloch, Gregor; Kuczaty, Julian; Sattelmayer, Thomas

    2014-02-01

    Holographic interferometry can be used to visualize density fields in fluids, and thus give insight into temperature distributions in flows. A fully digital reconstruction technique for holographic interferograms is presented that allows to create high-speed interferometric recordings and gives time-resolved information about heat transfer processes. The technique can also be used for a sequential (image to image) analysis of the recordings, which offers higher sensitivity and fewer errors due to optical impurities. Experiments are conducted with a vertical flow boiling channel with one heated wall, using a low boiling fluorocarbon as working liquid in regimes of steady-state nucleate boiling at critical heat flux (CHF), steady-state film boiling and CHF transient. Recording frequencies are up to 7,000 fps. The technique is used to analyze boiling processes at different fluid subcoolings with and without added turbulence. The results give enhanced insight into the temperature distributions, effects of different flow inserts and mechanisms of heat transfer in flow boiling at high heat fluxes. Furthermore, a velocimetric application of the technique is presented using cross-correlation for tracing of density gradients both in boiling and unheated flows. This application gives insight to the velocity distributions in the liquid surrounding the vapor layer. The results show good comparison to particle image velocimetry measurements for the same setup.

  6. To boil or not to boil -- A study of bubble embryo dormancy limits

    SciTech Connect

    Martin-Dominguez, I.R.; McDonald, T.W.

    1997-12-31

    In the literature, particularly for refrigerants, experimental studies on the superheat required to initiate nucleate boiling tend to be widely scattered, not only among investigators but even for repeated tests by the same investigator. This study provides an explanation of why this occurs and how to avoid such scatter in future tests. With few exceptions, only re-entrant surface cavities are capable of containing dormant vapor bubble embryos. These dormant embryos are essential to initiate nucleate boiling from a cavity. The temperature (wall superheat) range over which an embryo is stable depends upon the cavity shape, neck size, and the fluid surface tension and thermal properties. Above the upper wall-superheat limit, nucleate boiling occurs. Below the lower limit, the embryo will quench (vanish) and cannot be reactivated by increasing the wall superheat. This study makes the following points, for a given cavity shape, fluid, and pressure (1) The larger the cavity neck radius, the smaller the wall-superheat range over which an embryo can exist. (2) Upon cooling any surface, the boiling cavity with the smallest neck radius will be the first to stop boiling but will require the greatest reduction in wall superheat to quench its embryo. (3) Each site that retains a (dormant) vapor embryo will resume boiling at the same wall-superheat at which it ceased boiling. (4) Small cavities can have a shape such that their vapor embryos will always exist, regardless of the wall temperature. Boiling can always be reinitiated from them. (5) Any wall subject to boiling has a memory. The greater the past wall-subcooling, the greater will be the wall-superheat required to initiate boiling. (6) The wall memory can be erased with sufficient wall-superheat and the presence of vapor.

  7. Numerical modelling of temperature fields in the flow boiling liquid through a vertical minichannel with an enhanced heating surface

    NASA Astrophysics Data System (ADS)

    Ho?ejowska, Sylwia; Piasecka, Magdalena

    2014-03-01

    The paper presents results of heat transfer research on flow boiling in a rectangular minichannel positioned vertically, with an enhanced surface. One of the channel walls was made of thin foil powered by direct current. This foil is enhanced on the side contacting fluid in the minichannel. It is possible to observe both surfaces of the minichannel through two openings covered with glass panes. One allows detecting temperature of the plain side of the foil by liquid crystal thermography. The opposite surface of the minichannel (from the enhanced side of the foil) can be observed through the other glass pane. The observations of the flow structures allowed to calculate the void fraction for some cross-sections of selected two phase flow images. In mathematical modelling of the considered process stationary heat transfer in a glass pane, heating foil and boiling liquid can be described with Laplace equation, Poisson equation and energy equation, respectively. For completeness of the model a corresponding system of boundary conditions was given. The two-dimensional temperature fields of glass pane, heating foil and fluid was computed with the Trefftz method. The equalizing calculus used to smooth the measured data has reduced errors.

  8. Pyrosequencing Reveals High-Temperature Cellulolytic Microbial Consortia in Great Boiling Spring after In Situ Lignocellulose Enrichment

    PubMed Central

    Peacock, Joseph P.; Cole, Jessica K.; Murugapiran, Senthil K.; Dodsworth, Jeremy A.; Fisher, Jenny C.; Moser, Duane P.; Hedlund, Brian P.

    2013-01-01

    To characterize high-temperature cellulolytic microbial communities, two lignocellulosic substrates, ammonia fiber-explosion-treated corn stover and aspen shavings, were incubated at average temperatures of 77 and 85°C in the sediment and water column of Great Boiling Spring, Nevada. Comparison of 109,941 quality-filtered 16S rRNA gene pyrosequences (pyrotags) from eight enrichments to 37,057 quality-filtered pyrotags from corresponding natural samples revealed distinct enriched communities dominated by phylotypes related to cellulolytic and hemicellulolytic Thermotoga and Dictyoglomus, cellulolytic and sugar-fermenting Desulfurococcales, and sugar-fermenting and hydrogenotrophic Archaeoglobales. Minor enriched populations included close relatives of hydrogenotrophic Thermodesulfobacteria, the candidate bacterial phylum OP9, and candidate archaeal groups C2 and DHVE3. Enrichment temperature was the major factor influencing community composition, with a negative correlation between temperature and richness, followed by lignocellulosic substrate composition. This study establishes the importance of these groups in the natural degradation of lignocellulose at high temperatures and suggests that a substantial portion of the diversity of thermophiles contributing to consortial cellulolysis may be contained within lineages that have representatives in pure culture. PMID:23555835

  9. Description and validation of the Little correlation for boiling zeotropic mixtures in horizontal tubes from cryogenic to room temperature

    NASA Astrophysics Data System (ADS)

    Barraza, R.; Nellis, G.; Klein, S.; Reindl, D.

    2015-12-01

    The use of mixed gas working fluids has become common in Joule-Thomson (JT) type cryocoolers for a variety of applications operating in temperatures ranging from 80 to 230 K. The thermal efficiency of mixed gas JT cryocoolers is dependent on the optimization of the gas mixture composition. Most optimization methodologies focus on thermodynamic criteria of the cycle because there are very little data or theory currently available regarding the heat transfer coefficients associated with these multi-component mixtures in two-phase regimes at cryogenic temperatures. A generally accepted correlation to predict the local heat transfer coefficient (htc) for mixtures during the boiling process does not exist. Little [1] proposed a correlation to be used on horizontal tubes that shows good agreement with Nellis et al. [2] experimental data of nitrogen-hydrocarbon mixtures. However, it is not clearly shown how the correlation is obtained and how it should be applied. This paper provides a more complete description of the Little correlation and also expands its validation using the experimental data provided by Barraza [3]. The new experimental data include measurements of the local heat transfer coefficient for mixtures comprising 2 component (binary) up to 5 components in the temperature range between 100 K and room temperature. These mixtures are formed from nitrogen-hydrocarbon and argon-fluorocarbon mixtures and evaporate in horizontal tubes with diameters from 0.5 to 3.0 mm for different heat flux, mass flux, evaporating pressure, and composition.

  10. Effects of storage temperature on tyramine production by Enterococcus faecalis R612Z1 in water-boiled salted ducks.

    PubMed

    Liu, Fang; Du, Lihui; Wu, Haihong; Wang, Daoying; Zhu, Yongzhi; Geng, Zhiming; Zhang, Muhan; Xu, Weimin

    2014-10-01

    Tyramine production by Enterococcus faecalis R612Z1 in water-boiled salted ducks was evaluated during storage at different temperatures. The results showed that E. faecalis R612Z1 could produce tyramine in meat samples when the storage temperature was no less than 4°C. The E. faecalis R612Z1 counts of the meat samples reached 10(8) CFU/g on day 7 at 4°C and on day 4 at 10°C. However, the tyramine content of the meat samples stored at 10°C increased to 23.73 μg/g (on day 10), which was greater than the level in the samples stored at 4°C (7.56 μg/g). Reverse transcription quantitative PCR detection of the expression level of the tyrDC gene in E. faecalis R612Z1 in the meat samples revealed no significant changes at different storage temperatures. Thus, the changes in tyramine production of E. faecalis R612Z1 may be due to the different enzymatic activities at different storage temperatures. PMID:25285502

  11. Boiling from small cylinders.

    NASA Technical Reports Server (NTRS)

    Bakhru, N.; Lienhard, J. H.

    1972-01-01

    Heat transfer is observed as a function of temperature on small horizontal wires in water and four organic liquids. When the wire radius is sufficiently small, the hydrodynamic transitions in the boiling curve disappear and the curve becomes monotonic. Three modes of heat removal are identified for the monotonic curve and described analytically: a natural convection mode, a mixed film boiling and natural convection mode, and a pure film boiling mode. Nucleate boiling does not occur on the small wires. The study was motivated by an interest in predicting the behavior of large heaters at low gravity. The application of the present results to such circumstances is therefore discussed. It is proposed that the peak and minimum heat fluxes will vanish at low gravity as well as on small wires.

  12. Optimizations of packed sorbent and inlet temperature for large volume-direct aqueous injection-gas chromatography to determine high boiling volatile organic compounds in water.

    PubMed

    Yu, Bofan; Song, Yonghui; Han, Lu; Yu, Huibin; Liu, Yang; Liu, Hongliang

    2014-08-22

    For the expanded application area, fast trace analysis of certain high boiling point (i.e., 150-250 °C) volatile organic compounds (HVOCs) in water, a large volume-direct aqueous injection-gas chromatography (LV-DAI-GC) method was optimized for the following parameters: packed sorbent for sample on-line pretreatment, inlet temperature and detectors configuration. Using the composite packed sorbent self-prepared with lithium chloride and a type of diatomite, the method enabled safe injection of an approximately 50-100 μL sample at an inlet temperature of 150 °C in the splitless mode and separated HVOCs from water matrix in 2 min. Coupled with a flame ionization detector (FID), an electron capture detector (ECD) and a flame photometric detector (FPD), the method could simultaneously quantify 27 HVOCs that belong to seven subclasses (i.e., halogenated aliphatic hydrocarbons, chlorobenzenes, nitrobenzenes, anilines, phenols, polycyclic aromatic hydrocarbons and organic sulfides) in 26 min. Injecting a 50 μL sample without any enrichment step, such as cryotrap focusing, the limits of quantification (LOQs) for the 27 HVOCs was 0.01-3 μg/L. Replicate analyses of the 27 HVOCs spiked source and river water samples exhibited good precision (relative standard deviations ≤ 11.3%) and accuracy (relative errors ≤ 17.6%). The optimized LV-DAI-GC was robust and applicable for fast determination and automated continuous monitoring of HVOCs in surface water. PMID:24997514

  13. Measurement of cloud point temperature in polymer solutions.

    PubMed

    Mannella, G A; La Carrubba, V; Brucato, V

    2013-07-01

    A temperature-controlled turbidity measurement apparatus for the characterization of polymer solutions has been instrumented and set up. The main features are the coupled temperature-light transmittance measurement and the accurate temperature control, achieved by means of peltier cells. The apparatus allows to measure cloud point temperatures by adopting different cooling protocols: low rate for quasi-equilibrium measurements and high rate for detect kinetic effects. A ternary polymeric solution was adopted as case study system showing that cooling rate affects the measured cloud point temperature. PMID:23902117

  14. The boiling Twente Taylor-Couette (BTTC) facility: Temperature controlled turbulent flow between independently rotating, coaxial cylinders.

    PubMed

    Huisman, Sander G; van der Veen, Roeland C A; Bruggert, Gert-Wim H; Lohse, Detlef; Sun, Chao

    2015-06-01

    A new Taylor-Couette system has been designed and constructed with precise temperature control. Two concentric independently rotating cylinders are able to rotate at maximum rates of f(i) = ± 20 Hz for the inner cylinder and f(o) = ± 10 Hz for the outer cylinder. The inner cylinder has an outside radius of r(i) = 75 mm, and the outer cylinder has an inside radius of r(o) = 105 mm, resulting in a gap of d = 30 mm. The height of the gap is L = 549 mm, giving a volume of V = 9.3 L. The geometric parameters are η = r(i)/r(o) = 0.714 and Γ = L/d = 18.3. With water as working fluid at room temperature, the Reynolds numbers that can be achieved are Re(i) = ω(i)r(i)(r(o) - r(i))/ν = 2.8 × 10(5) and Re(o) = ω(o)r(o)(r(o) - r(i))/ν = 2 × 10(5) or a combined Reynolds number of up to Re = (ω(i)r(i) - ω(o)r(o))(r(o) - r(i))/ν = 4.8 × 10(5). If the working fluid is changed to the fluorinated liquid FC-3284 with kinematic viscosity 0.42 cSt, the combined Reynolds number can reach Re = 1.1 × 10(6). The apparatus features precise temperature control of the outer and inner cylinders separately and is fully optically accessible from the side and top. The new facility offers the possibility to accurately study the process of boiling inside a turbulent flow and its effect on the flow. PMID:26133874

  15. The boiling Twente Taylor-Couette (BTTC) facility: Temperature controlled turbulent flow between independently rotating, coaxial cylinders

    NASA Astrophysics Data System (ADS)

    Huisman, Sander G.; van der Veen, Roeland C. A.; Bruggert, Gert-Wim H.; Lohse, Detlef; Sun, Chao

    2015-06-01

    A new Taylor-Couette system has been designed and constructed with precise temperature control. Two concentric independently rotating cylinders are able to rotate at maximum rates of fi = ± 20 Hz for the inner cylinder and fo = ± 10 Hz for the outer cylinder. The inner cylinder has an outside radius of ri = 75 mm, and the outer cylinder has an inside radius of ro = 105 mm, resulting in a gap of d = 30 mm. The height of the gap is L = 549 mm, giving a volume of V = 9.3 L. The geometric parameters are η = ri/ro = 0.714 and Γ = L/d = 18.3. With water as working fluid at room temperature, the Reynolds numbers that can be achieved are Rei = ωiri(ro - ri)/ν = 2.8 × 105 and Reo = ωoro(ro - ri)/ν = 2 × 105 or a combined Reynolds number of up to Re = (ωiri - ωoro)(ro - ri)/ν = 4.8 × 105. If the working fluid is changed to the fluorinated liquid FC-3284 with kinematic viscosity 0.42 cSt, the combined Reynolds number can reach Re = 1.1 × 106. The apparatus features precise temperature control of the outer and inner cylinders separately and is fully optically accessible from the side and top. The new facility offers the possibility to accurately study the process of boiling inside a turbulent flow and its effect on the flow.

  16. Subcooled forced convection boiling of trichlorotrifluoroethane

    NASA Technical Reports Server (NTRS)

    Dougall, R. S.; Panian, D. J.

    1972-01-01

    Experimental heat-transfer data were obtained for the forced-convection boiling of trichlorotrifluoroethane (R-113 or Freon-113) in a vertical annular test annular test section. The 97 data points obtained covered heat transfer by forced convection, local boiling, and fully-developed boiling. Correlating methods were obtained which accurately predicted the heat flux as a function of wall superheat (boiling curve) over the range of parameters studied.

  17. Estimating surface temperature in forced convection nucleate boiling: A simplified method

    NASA Technical Reports Server (NTRS)

    Hendricks, R. C.; Papell, S. S.

    1977-01-01

    During a test program to investigate low-cycle thermal fatigue, 21 of 22 cylindrical test sections of a cylindrical rocket thrust chamber were thermally cycled to failure. Cylinder liners were fabricated from OFHC copper, Amzirc, and NARloy-Z. The cylinders were fabricated by milling cooling channels into the liner and closing out the backside with electrodeposited copper. The tests were conducted at a chamber pressure of 4.14 MN/sq m (600 psia) and an oxidant-fuel ratio of 6.0 using hydrogen-oxygen as propellants. The average throat heat flux was 54 MW/sq m (33 Btu/sq in./sec). All of the failures were characterized by a thinning of the cooling channel wall and eventual failure by tensile rupture. The 1/2-hard Amzirc material showed little improvement in cyclic life when compared with OFHC copper; while the NARloy-Z and aged Amzirc materials had the best cyclic life characteristics. One OFHC copper cylinder was thermall cycled 2044 times at a steady-state hot-gas-side wall temperature of 514 K (925 R) without failing.

  18. Electron temperature difference between the o-point and x-point of a magnetic island

    SciTech Connect

    Yang Jinhong; Zhu Sizheng; Yu Qingquan; Zhuang, G.

    2009-09-15

    The electron temperature difference between the o-point and the x-point of a magnetic island is studied numerically by solving the two-dimensional energy transport equation. It is found that, even without a localized radio-frequency heating at the island's o-point, there is usually a temperature difference between these two points. This difference depends on the radial profile of the heating power deposition, the ratio between the parallel and the perpendicular heat conductivity and the island width, and it takes a minimum when the island width is about twice the local heat diffusion layer width. The effect of the temperature difference on the island growth is further studied, and the peaked heating power density profile at magnetic axis is found be destabilizing.

  19. Change point detection of the Persian Gulf sea surface temperature

    NASA Astrophysics Data System (ADS)

    Shirvani, A.

    2015-09-01

    In this study, the Student's t parametric and Mann-Whitney nonparametric change point models (CPMs) were applied to detect change point in the annual Persian Gulf sea surface temperature anomalies (PGSSTA) time series for the period 1951-2013. The PGSSTA time series, which were serially correlated, were transformed to produce an uncorrelated pre-whitened time series. The pre-whitened PGSSTA time series were utilized as the input file of change point models. Both the applied parametric and nonparametric CPMs estimated the change point in the PGSSTA in 1992. The PGSSTA follow the normal distribution up to 1992 and thereafter, but with a different mean value after year 1992. The estimated slope of linear trend in PGSSTA time series for the period 1951-1992 was negative; however, that was positive after the detected change point. Unlike the PGSSTA, the applied CPMs suggested no change point in the Nio3.4SSTA time series.

  20. Characteristics of Transient Boiling Heat Transfer

    SciTech Connect

    Liu, Wei; Monde, Masanori; Mitsutake, Y.

    2002-07-01

    In this paper, one dimensional inverse heat conduction solution is used for a measurement of pool boiling curve. The experiments are performed under atmospheric pressure for copper, brass, carbon steel and gold. Boiling curves, including unsteady transition boiling region, are found can be traced fairly well from a simple experiment system by solving inverse heat conduction solution. Boiling curves for steady heating and transient heating, for heating process and cooling process are compared. Surface behavior around CHF point, transition boiling and film-boiling regions are observed by using a high-speed camera. The results show the practicability of the inverse heat conduction solution in tracing boiling curve and thereby supply us a new way in boiling heat transfer research. (authors)

  1. Carbon dioxide and R410A flow boiling heat transfer, pressure drop, and flow pattern in horizontal tubes at low temperatures

    NASA Astrophysics Data System (ADS)

    Park, Chang Yong

    Carbon dioxide (CO2) has been seriously considered as an alternate refrigerant for HCFC and HFC fluids, due to the increasing interest of environmentally safe refrigerants in air-conditioning and refrigeration systems. In this study, CO2 flow boiling heat transfer coefficients and pressure drop are measured in macro-scale (6.1 and 3.5 mm) tubes at evaporation temperatures of -15 and -30°C. The measured results show that the nucleate boiling is a main heat transfer mechanism in the 6.1 mm tube and the contribution of convective boiling becomes greater with the decrease of tube diameters and the increase of mass fluxes. The surface roughness of the 6.1 and 3.5 mm tube are presented by SEM and AFM images and surface profiles, and it is shown that the rougher surface of the 6.1 mm tube can affect the flow boiling heat transfer. The CO2 heat transfer coefficients and pressure drop are measured in a mini-scale (0.89 mm) multi-ported tube at the evaporation temperature of -30°C. Also, R410A and R22 flow boiling heat transfer coefficients and pressure drop in a macro-scale (6.1 mm) tube were measured, and they are compared with CO2. This comparison presents that the CO2 flow boiling heat transfer coefficients are higher than R410A and R22 at low vapor qualities, and CO2 pressure drop is significantly lower than R410A and R22. This advantageous characteristic for CO2 could be explained by properties such as surface tension, reduced pressure, and the density ratio of liquid to vapor. The prediction of heat transfer coefficients and pressure drop was performed by general correlations and the calculation results are compared with measured values. Two-phase flow patterns were visualized for CO2 and R410A in the 6 and 3 mm glass tubes, and they are compared with the Weisman et al. and the Wojtan et al. flow pattern maps. The flow pattern maps can determine the flow patterns relatively well, except the transition from intermittent to annular flow.

  2. BOILING REACTORS

    DOEpatents

    Untermyer, S.

    1962-04-10

    A boiling reactor having a reactivity which is reduced by an increase in the volume of vaporized coolant therein is described. In this system unvaporized liquid coolant is extracted from the reactor, heat is extracted therefrom, and it is returned to the reactor as sub-cooled liquid coolant. This reduces a portion of the coolant which includes vaporized coolant within the core assembly thereby enhancing the power output of the assembly and rendering the reactor substantially self-regulating. (AEC)

  3. Contrast-enhanced ultrasound imaging and in vivo circulatory kinetics with low-boiling-point nanoscale phase-change perfluorocarbon agents.

    PubMed

    Sheeran, Paul S; Rojas, Juan D; Puett, Connor; Hjelmquist, Jordan; Arena, Christopher B; Dayton, Paul A

    2015-03-01

    Many studies have explored phase-change contrast agents (PCCAs) that can be vaporized by an ultrasonic pulse to form microbubbles for ultrasound imaging and therapy. However, few investigations have been published on the utility and characteristics of PCCAs as contrast agents in vivo. In this study, we examine the properties of low-boiling-point nanoscale PCCAs evaluated in vivo and compare data with those for conventional microbubbles with respect to contrast generation and circulation properties. To do this, we develop a custom pulse sequence to vaporize and image PCCAs using the Verasonics research platform and a clinical array transducer. Results indicate that droplets can produce contrast enhancement similar to that of microbubbles (7.29 to 18.24 dB over baseline, depending on formulation) and can be designed to circulate for as much as 3.3 times longer than microbubbles. This study also reports for the first time the ability to capture contrast washout kinetics of the target organ as a measure of vascular perfusion. PMID:25619781

  4. ENERGY CONSERVATION THROUGH POINT SOURCE RECYCLE WITH HIGH TEMPERATURE HYPERFILTRATION

    EPA Science Inventory

    The report gives results of a study of energy conservation effects of point source recycle with high-temperature hyperfiltration (HF) in the textile industry. (HF and ultrafiltration (UF) are pressure-driven membrane processes which have potential for recycle of water, energy, an...

  5. Complex saddle points in QCD at finite temperature and density

    NASA Astrophysics Data System (ADS)

    Nishimura, Hiromichi; Ogilvie, Michael C.; Pangeni, Kamal

    2014-08-01

    The sign problem in QCD at finite temperature and density leads naturally to the consideration of complex saddle points of the action or effective action. The global symmetry CK of the finite-density action, where C is charge conjugation and K is complex conjugation, constrains the eigenvalues of the Polyakov loop operator P at a saddle point in such a way that the action is real at a saddle point, and net color charge is zero. The values of TrFP and TrFP at the saddle point are real but not identical, indicating the different free energy cost associated with inserting a heavy quark versus an antiquark into the system. At such complex saddle points, the mass matrix associated with Polyakov loops may have complex eigenvalues, reflecting oscillatory behavior in color-charge densities. We illustrate these properties with a simple model which includes the one-loop contribution of gluons and two flavors of massless quarks moving in a constant Polyakov loop background. Confinement-deconfinement effects are modeled phenomenologically via an added potential term depending on the Polyakov loop eigenvalues. For sufficiently large temperature T and quark chemical potential ?, the results obtained reduce to those of perturbation theory at the complex saddle point. These results may be experimentally relevant for the compressed baryonic matter experiment at FAIR.

  6. Liquid metal boiling inception

    NASA Technical Reports Server (NTRS)

    Sabin, C. M.; Poppendiek, H. F.; Mouritzen, G.; Meckel, P. T.; Cloakey, J. E.

    1972-01-01

    An experimental study of the inception of boiling in potassium in forced convection is reported. The boiler consisted of a 0.19-inch inside diameter, niobium-1% zirconium boiler tube approximately six feet long. Heating was accomplished by direct electrical tube wall conduction. Experiments were performed with both all-liquid fill and two-phase fill startup sequences and with a range of flow rates, saturation temperatures, inert gas levels, and fill liquid temperatures. Superheat of the liquid above the equilibrium saturation temperature was observed in all the experiments. Incipient boiling liquid superheat ranged from a few degrees to several hundred. Comparisons of these data with other data and with several analytical treatments are presented.

  7. Microheater Array Boiling Experiment

    NASA Technical Reports Server (NTRS)

    Kim, Jungho; McQuillen, John; Balombin, Joe

    2002-01-01

    By conducting pool boiling tests in microgravity, the effect of buoyancy on the overall boiling process and the relative magnitude of other phenomena can be assessed. Data from KC-135 and sounding rocket experiments indicate little effect of gravity on boiling heat transfer at wall superheats below 25 C, despite vast differences in bubble behavior between gravity levels. In microgravity, a large primary bubble, surrounded by smaller satellite bubbles, moved over the surface, occasionally causing nucleation. Once formed, the primary bubble size remained constant for a given superheat, indicating evaporation at the bubble base is balanced with condensation on the bubble cap. The primary bubble's size increased with wall superheat. Most heaters under the primary bubble had low heat transfer rates, suggesting liquid dryout. Strong Marangoni convection developed in microgravity, forming a 'jet' into the bulk liquid that forced the bubble onto the heater. An experiment is being designed for the. Microgravity Science Glovebox. This experiment uses two 96 element microheater arrays, 2.7 and 7.0 mm in size. These heaters are individually controlled to operate at a constant temperature, measuring local heat fluxes as a function of time and space. Most boiling experiments operate at constant wall heat flux with larger heaters, allowing only time and space-averaged measurements. Each heater is about the bubble departure size in normal gravity, but significantly smaller than the bubble departure size in reduced gravity.

  8. Thermodynamic temperature assignment to the point of inflection of the melting curve of high-temperature fixed points.

    PubMed

    Woolliams, E R; Anhalt, K; Ballico, M; Bloembergen, P; Bourson, F; Briaudeau, S; Campos, J; Cox, M G; del Campo, D; Dong, W; Dury, M R; Gavrilov, V; Grigoryeva, I; Hernanz, M L; Jahan, F; Khlevnoy, B; Khromchenko, V; Lowe, D H; Lu, X; Machin, G; Mantilla, J M; Martin, M J; McEvoy, H C; Rougié, B; Sadli, M; Salim, S G R; Sasajima, N; Taubert, D R; Todd, A D W; Van den Bossche, R; van der Ham, E; Wang, T; Whittam, A; Wilthan, B; Woods, D J; Woodward, J T; Yamada, Y; Yamaguchi, Y; Yoon, H W; Yuan, Z

    2016-03-28

    The thermodynamic temperature of the point of inflection of the melting transition of Re-C, Pt-C and Co-C eutectics has been determined to be 2747.84 ± 0.35 K, 2011.43 ± 0.18 K and 1597.39 ± 0.13 K, respectively, and the thermodynamic temperature of the freezing transition of Cu has been determined to be 1357.80 ± 0.08 K, where the ± symbol represents 95% coverage. These results are the best consensus estimates obtained from measurements made using various spectroradiometric primary thermometry techniques by nine different national metrology institutes. The good agreement between the institutes suggests that spectroradiometric thermometry techniques are sufficiently mature (at least in those institutes) to allow the direct realization of thermodynamic temperature above 1234 K (rather than the use of a temperature scale) and that metal-carbon eutectics can be used as high-temperature fixed points for thermodynamic temperature dissemination. The results directly support the developing mise en pratique for the definition of the kelvin to include direct measurement of thermodynamic temperature. PMID:26903099

  9. An International Star Intercomparison of Low-Temperature Fixed Points Using Sealed Triple-Point Cells

    NASA Astrophysics Data System (ADS)

    Fellmuth, B.; Berger, D.; Wolber, L.; de Groot, M.; Head, D.; Hermier, Y.; Mao, Y. Z.; Nakano, T.; Pavese, F.; Shkraba, V.; Steele, A. G.; Steur, P. P. M.; Szmyrka-Grzebyk, A.; Tew, W. L.; Wang, L.; White, D. R.

    2003-09-01

    An overview of the main results of an international star intercomparison of low-temperature fixed points is given. Between 1997 and 2002, 52 sealed triple-point cells (STPCs) of the thirteen laboratories represented by the authors have been investigated at PTB. The STPCs are used to realise the triple points of hydrogen, neon, oxygen, and argon, respectively, as defining fixed points of the International Temperature Scale of 1990, ITS-90. The melting curves of all STPCs have been measured on the same experimental equipment, adhering strictly to a single measurement program. This protocol enables separation of the effects influencing the melting curves and direct comparison of the thermal behaviour of the STPCs, which are quite different with respect to design, age, gas source, and filling technology. In the paper, emphasis is given to the typical properties of the four fixed-point substances and to the spread of the STPC parameters. Connections between the star intercomparison and completed and on-going international activities, including the CIPM Key Comparisons, are also discussed.

  10. High temperature antenna pointing mechanism for BepiColombo mission

    NASA Astrophysics Data System (ADS)

    Mrer, Johan A.; Harper, Richard; Anderson, Mike

    2005-07-01

    This paper describes the two axis Antenna Pointing Mechanism (APM) with dual frequency (X-Ka bands) Rotary Joint (RJ) developed by Kongsberg Defence and Aerospace and BAE Systems, in the frame of the ESA BepiColombo mission to the planet Mercury. The extreme environmental conditions induced by Mercury's proximity to the Sun (up to 14.500 W/m2 direct solar fluxes, up to 5000 W/m2 infrared flux and up to 1200 W/m2 albedo shine form the planet surface), have dictated the need for a specific high temperature development of the pointing mechanism and of its integrated RF Rotary Joint. Global thermal analysis of the antenna predicts qualification temperature for the elevation stage APM between 250C and 295C. In addition, the mechanism shall survive extreme cold temperatures during the interplanetary cruise phase. Beside the harsh environment, the stringent pointing accuracy required by the antenna high frequency operations, and the extreme dimensional stability demanded by a radio science experiment (which is using the antenna for range and range rate measurements), have introduced additional, specific challenges to the mechanism design. Innovative solutions have been deemed necessary at system architecture level, in the design of the mechanisms critical areas and in the selection of high temperature compatible materials and processes. The very high working temperature of the mechanism ruled out use of aluminium alloys, which is replaced by Titanium alloy and stainless steels. Special heat treatments of the steel are applied for minimum loss of hardness. The structures are optimised for minimum mass. To handle thermal stresses and distortion, a very compact design of the APM was performed integrating the bearings, position sensor and drive chain within minimum structural length. The Rotary Joint is a unique design tailored to the APM using a common main bearing support. Special manufacturing processes have been tested and applied for manufacture of the very compact RJ being the first of its kind (dual X-Ka band) in European space development. The twin channels are arranged concentrically, permitting continuous 360 rotation. Maximum use of waveguide has been made to minimise the loss in the Ka-band frequency channel and this leads to an unconventional design of the X-band channel. A specific effort and extensive test program at ESTL in the UK have been put in place to identify suitable high temperature solutions for the RJ and APM bearings lubrication. The high temperature demands the use of a dry lubrication system. High working loads due to thermal stresses puts extra challenge to the life duration of the dry film lubrication. Lead lubrication was initially the preferred concept, but has later in the program been substituted by MoS2 film. A design life of 20,000 cycles at 250C and elevated load has been demonstrated for the bearings with MoS2. Special attention has been paid to the materials in the stepper motor using high temperature solder material and MoS2 dry lubrication in the bearings and gear train. The APM is designed for use of a high accuracy inductive based position sensor with remote signal and amplifier electronics. Electrical signal transfer is via a high temperature Twist Capsule. The activity has included the design, manufacturing and testing in a respresentative environment of a breadboard model of the APM and of its integrated radio frequency RJ. The breadboard does not include a position sensor or the Twist Capsule. The breadboard tests will include functional performance tests in air, vibration tests and thermal vacuum. The thermal vacuum test will include RF testing at high temperature combined with APM pointing performance.

  11. Transient boiling heat transfer in saturated liquid nitrogen and F113 at standard and zero gravity

    NASA Technical Reports Server (NTRS)

    Oker, E.; Merte, H., Jr.

    1973-01-01

    Transient and steady state nucleate boiling in saturated LN2 and F113 at standard and near zero gravity conditions were investigated for the horizontal up, vertical and horizontal down orientations of the heating surface. Two distinct regimes of heat transfer mechanisms were observed during the interval from the step increase of power input to the onset of nucleate boiling: the conduction and convection dominated regimes. The time duration in each regime was considerably shorter with LN2 than with F113, and decreased as heat flux increased, as gravity was reduced, and as the orientation was changed from horizontal up to horizontal down. In transient boiling, boiling initiates at a single point following the step increase in power, and then spreads over the surface. The delay time for the inception of boiling at the first site, and the velocity of spread of boiling varies depending upon the heat flux, orientation, body force, surface roughness and liquid properties, and are a consequence of changes in boundary layer temperature levels associated with changes in natural convection. Following the step increase in power input, surface temperature overshoot and undershoot occur before the steady state boiling temperature level is established.

  12. Dissemination of thermodynamic temperature above the freezing point of silver.

    PubMed

    Sadli, M; Machin, G; Anhalt, K; Bourson, F; Briaudeau, S; Del Campo, D; Diril, A; Kozlova, O; Lowe, D H; Mantilla Amor, J M; Martin, M J; McEvoy, H C; Ojanen-Saloranta, M; Pehlivan, Ö; Rougié, B; Salim, S G R

    2016-03-28

    The mise-en-pratique for the definition of the kelvin at high temperatures will formally allow dissemination of thermodynamic temperature either directly or mediated through high-temperature fixed points (HTFPs). In this paper, these two distinct dissemination methods are evaluated, namely source-based and detector-based. This was achieved by performing two distinct dissemination trials: one based on HTFPs, the other based on absolutely calibrated radiation thermometers or filter radiometers. These trials involved six national metrology institutes in Europe in the frame of the European Metrology Research Programme joint project 'Implementing the new kelvin' (InK). The results have shown that both dissemination routes are possible, with similar standard uncertainties of 1-2 K, over the range 1273-2773 K, showing that, depending on the facilities available in the laboratory, it will soon be possible to disseminate thermodynamic temperatures above 1273 K to users by either of the two methods with uncertainties comparable to the current temperature scale. PMID:26903097

  13. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect

    Duignan, M.R.; Greene, G.A. ); Irvine, T.F., Jr. . Dept. of Mechanical Engineering)

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured (0 to 8.5 cm/s), the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  14. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect

    Duignan, M.R.; Greene, G.A.; Irvine, T.F., Jr.

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus_minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured [0 to 8.5 cm/s], the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  15. Enhanced convective and film boiling heat transfer by surface gas injection

    NASA Astrophysics Data System (ADS)

    Duignan, M. R.; Greene, G. A.; Irvine, T. F., Jr.

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T(sub SURFACE) approximately 500 K, to T(sub SURFACE) approximately 950 K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long as it was corrected for the heat transferred by radiation. On the average, the experimental data lay within plus or minus 7 percent of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm-diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/sq m. For water-pool heights of less than 6 cm the heat transfer coefficient decreased linearly with a decrease in heights. Above 6 cm the heat transfer coefficient was unaffected. For the entire range of gas velocities which measured (0 to 8.5 cm/s), the magnitude of the heat transfer coefficient only changed by approximately 20 percent. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface.

  16. Method for Measuring Collimator-Pointing Sensitivity to Temperature Changes

    NASA Technical Reports Server (NTRS)

    Abramovici, Alex; Cox, Timothy E.; Hein, Randall C.; MacDonald, Daniel R.

    2011-01-01

    For a variety of applications, it is important to measure the sensitivity of the pointing of a beam emerging from a collimator, as a function of temperature changes. A straightforward method for carrying out this measurement is based on using interferometry for monitoring the changes in beam pointing, which presents its own problems. The added temperature dependence and complexity issues relating to using an interferometer are addressed by not using an interferometer in the first place. Instead, the collimator is made part of an arrangement that uses a minimum number of low-cost, off-the-shelf materials and by using a quad diode to measure changes in beam pointing. In order to minimize the influence of the test arrangement on the outcome of the measurement, several steps are taken. The collimator assembly is placed on top of a vertical, 1-m-long, fused silica tube. The quad diode is bonded to a fused silica bar, which, in turn, is bonded to the lower end of the fused silica tube. The lower end of the tube rests on a self-aligning support piece, while the upper end of the tube is kept against two rounded setscrew tips, using a soft rubber string. This ensures that very little stress is applied to the tube as the support structure changes dimensions due to thermal expansion. Light is delivered to the collimator through a bare fiber in order to minimize variable bending torque caused by a randomly relaxing, rigid fiber jacket. In order to separate the effect of temperature on the collimator assembly from the effect temperature has on the rest of the setup, multiple measurements are taken with the collimator assembly rotated from measurement to measurement. Laboratory testing, with 1-m spacing between the collimator and the quad diode, has shown that the sensitivity of the arrangement is better than 100 nm rms, over time spans of at least one hour, if the beam path is protected from atmospheric turbulence by a tube. The equivalent sensitivity to detecting changes in pointing angle is 100 nanoradians.

  17. Experimental consequences of quantum critical points at high temperatures

    NASA Astrophysics Data System (ADS)

    Freitas, D. C.; Rodire, P.; Nez, M.; Garbarino, G.; Sulpice, A.; Marcus, J.; Gay, F.; Continentino, M. A.; Nez-Regueiro, M.

    2015-11-01

    We study the C r1 -xR ex phase diagram finding that its phase transition temperature towards an antiferromagnetic order TN follows a quantum [(xc-x ) /xc ] ? law, with ? =1 /2 , from the quantum critical point (QCP) at xc=0.25 up to TN?600 K . We compare this system to others in order to understand why this elemental material is affected by the QCP up to such unusually high temperatures. We determine a general criterion for the crossover, as a function of an external parameter such as concentration, from the region controlled solely by thermal fluctuations to that where quantum effects become observable. The properties of materials with low coherence lengths will thus be altered far away from the QCP.

  18. Experimental Study of Heat Transfer from Stainless Steel Foil in He II during Film Boiling State

    SciTech Connect

    Zhang, P.; Murakami, M.

    2004-06-23

    He II film boiling is of both academic and applied interests. However, the information about film boiling heat transfer in He II is still insufficient and needs further investigation. In the present study, a thin stainless steel foil heater (10 {mu} m thick) is used to cause boiling in He II. The heater temperature is measured to evaluate the heat transfer performance of He II film boiling under different thermal conditions. The pressure and the heater surface temperature oscillations induced by the film boiling are also simultaneously measured. The heat transfer coefficients of three kinds of boiling states: noisy film boiling, transition boiling and silent film boiling, are obtained in the present study.

  19. In-situ Stress Measurements on SUS316L Stainless Steel in High Temperature Water Simulated Boiling Water Reactor

    NASA Astrophysics Data System (ADS)

    Yamamoto, A.; Nakahigashi, S.; Terasawa, M.; Mitamura, T.; Akiniwa, Y.; Yamada, T.; Liu, L.; Shobu, T.; Tsubakino, H.

    2007-01-01

    An in-situ straining device has been developed, which enables one to apply a load of 240 N to a specimen in hot water at 561 K and a pressure of 8 MPa, simulating the environment in a boiling water reactor (BWR). The device is equipped with sapphire glass windows for a light path, that is, the device can be used for dynamic measurements of stress induced in the specimen using a synchrotron radiation facility. In-situ stress measurements have been carried out at SPring-8 (BL02B1) on a specimen prepared from SUS316L stainless steel. Inhomogeneity in stress distribution and time-dependent changes in stress were successfully measured.

  20. Evaluation and Selection of High-Temperature Fixed-Point Cells for Thermodynamic Temperature Assignment

    NASA Astrophysics Data System (ADS)

    Yamada, Y.; Anhalt, K.; Battuello, M.; Bloembergen, P.; Khlevnoy, B.; Machin, G.; Matveyev, M.; Sadli, M.; Todd, A.; Wang, T.

    2015-08-01

    A multi-partner project to determine the thermodynamic temperatures of a selected set of high-temperature fixed points based on metal-carbon eutectics is underway as a working group activity within the Comité International des Poids et Mesures. The investigation focuses on four fixed-point types, namely, the three metal-carbon eutectic points of Re-C , Pt-C , and Co-C , and the Cu point . This paper describes the construction, pre-evaluation, and screening stage of the cells prior to their thermodynamic temperature determinations. The construction of the HTFP cells was undertaken by nine national metrology institutes (NMIs) according to instructions laid out in a pre-agreed protocol that ensures production of best quality cells. Four NMIs conducted the evaluation, each for a certain fixed-point type, and screened out cells that did not meet pre-determined selection criteria while assuring sufficient variety in the sources of the cells in the final selected sets. In autumn 2012, the selected cells were successfully passed on to the final stage of the project, the thermodynamic temperature measurement, and assignment.

  1. Scaling of high heat flux flow boiling flow systems

    SciTech Connect

    Castrogiovanni, A.; Sforza, P.M.

    1996-12-31

    The scaling of high heat flux boiling flow systems is examined using a computational technique newly developed by the present authors. The current work is an extension of previously reported two-dimensional scaling technique to include flow development along the axis of a cooling channel. The new approach involves the solution of the energy equation for a pipe flow subjected to a step change in wall heat flux assuming a fully developed turbulent velocity profile at the point of initial heating. A boiling-induced turbulent eddy diffusivity term is used with an adaptive genetic algorithm closure scheme to predict both the transition to, and development of, the partial nucleate boiling regime based on a postulated minimization of the local wall temperature. Examination of the constitutive equations in non-dimensional form in conjunction with the use of previously established fluid-property scaling tools, leads to the development of a scaling procedure. Reasonable similarity between a high heat flux boiling flow system utilizing water, and a lower heat flux boiling flow system using R-12 is demonstrated. A numerical experiment is carried out to illustrate the scaling technique.

  2. Local Heat Transfer and CHF for Subcooled Flow Boiling - Annual Report 1994

    SciTech Connect

    Dr. Ronald D. Boyd

    2000-07-01

    The physical phenomenon of forced convective boiling is probably one of the most interesting and complex transport phenomena. It has been under study for more than two centuries. Simply stated, forced convective subcooled boiling involves a locally boiling fluid: (1) whose mean temperature is below its saturation temperature, and (2) that flows over a surface exposed uniformly or non-uniformly to a high heat flux (HHF). The objective of this work is to assess and/or improve the present ability to predict local axial heat transfer distributions in the subcooled flow boiling regime for the case of uniformly heated coolant channels. This requires an accurate and complete representation of the boiling curve up to the CHF. The present. results will be useful for both heat transfer research and industrial design applications. Future refinements may result in the application of the results to non-uniformly heated channels or other geometries, and other fluids. Several existing heat transfer models for uniformly heated channels were examined for: (1) accurate representation of the boiling curve, and (2) characterizing the local heat transfer coefficient under high heat flux (HHF) conditions. Comparisons with HHF data showed that major correlation modifications were needed in the subcooled partial nucleate boiling (SPNB) region. Since the slope of boiling curve in this region is important to assure continuity of the HHF trends into the fully developed boiling region and up to the critical heat flux, accurate characterization in the SPNB region is essential. Approximations for the asymptotic limits for the SPNB region have been obtained and have been used to develop an improved composite correlation. The developed correlation has been compared with 363 water data points. For the local heat transfer coefficient and wall temperature, the over-all percent standard deviations with respect to the data were 19% and 3%, respectively, for the high velocity water data.

  3. Are there optimum temperature and humidity set points for supermarkets?

    SciTech Connect

    Orphelin, M.; Marchio, D.; D'Alanzo, S.L.

    1999-07-01

    Electricity consumption in large supermarkets represents a substantial share of the national electric energy use, about 4% in both the US and France. Display cases and air-conditioning systems consume a considerable amount of electricity, varying from 50% to 70% of the store total. Minimizing this energy consumption is advantageous since the corresponding consumption is advantageous since the corresponding consumption is about 400 kWh/(m{sup 2}{center{underscore}dot}yr) (37 kWh/(ft{sup 2}{center{underscore}dot}year)). Reducing energy consumption remains quite a challenge. This paper discusses a new approach to estimate impacts of temperature and humidity set points on the total energy balance of supermarkets. it takes into account the model of the cold aisle effect and the occurrence of thermal coupling between supermarket display cases and the air-conditioning system. Results are given for a typical French supermarket.

  4. Boiling heat transfer from an excavated fin

    NASA Astrophysics Data System (ADS)

    Liaw, S. P.; Yeh, R. H.

    1992-04-01

    A single pin fin with excavation at base is proposed to enhance boiling heat transfer. The temperature distribution in the fin is obtained numerically by solving a 2D heat conduction equation. A copper fin boiling in isopropyl alcohol is taken as an example. When the operating temperature exceeds a specific value, the heat duty decreases drastically, and the whole fin is governed by film boiling. This highest operating temperature limit is raised by digging a hole at the fin base. Two distinct solutions are found by using different initial guesses into the code. This hysteresis effect becomes noticeable for a bigger hole. A model is also developed to predict the burnout temperatures.

  5. Reduced Boil-Off System Sizing

    NASA Technical Reports Server (NTRS)

    Guzik, Monica C.; Plachta, David W.; Feller, Jeffrey R.

    2015-01-01

    NASA is currently developing cryogenic propellant storage and transfer systems for future space exploration and scientific discovery missions by addressing the need to raise the technology readiness level of cryogenic fluid management technologies. Cryogenic propellants are baselined in many propulsion systems due to their inherently high specific impulse; however, their low boiling points can cause substantial boil-off losses over time. Recent efforts such as the Reduced Boil-off Testing and the Active Thermal Control Scaling Study provide important information on the benefit of an active cooling system applied to LH2 propellant storage. Findings show that zero-boil off technologies can reduce overall mass in LH2 storage systems when low Earth orbit loiter periods extend beyond two months. A significant part of this mass reduction is realized by integrating two stages of cooling: a 20 K stage to intercept heat at the tank surface, and a 90 K stage to reduce the heat entering the less efficient 20 K stage. A missing element in previous studies, which is addressed in this paper, is the development of a direct method for sizing the 90 K cooling stage. Such a method requires calculation of the heat entering both the 90 K and 20 K stages as compared to the overall system masses, and is reliant upon the temperature distribution, performance, and unique design characteristics of the system in question. By utilizing the known conductance of a system without active thermal control, the heat being intercepted by a 90 K stage can be calculated to find the resultant lift and mass of each active thermal control stage. Integral to this is the thermal conductance of the cooling straps and the broad area cooling shield, key parts of the 90 K stage. Additionally, a trade study is performed to show the ability of the 90 K cooling stage to reduce the lift on the 20 K cryocooler stage, which is considerably less developed and efficient than 90 K cryocoolers.

  6. TEMPERATURE VARIATION WITH TIME IN A PERENNIALLY BOILING WELL IN THE LONG VALLEY CALDERA, MONO COUNTY, CALIFORNIA; OBSERVATIONS IN CHANCE NO. 1 (1976-1983).

    USGS Publications Warehouse

    Diment, W.H.; Urban, T.C.; Nathenson, Manuel

    1985-01-01

    Chance No. 1 was drilled to a depth of 245. 4 m and cased to a depth of 72. 2 m in 1961. Temperature logs were obtained in 1976, 1982, and 1983, with the casing open to the atmosphere. Water was boiling at the surface of the fluid column on each occasion. Temperatures within the upper part of the cased interval remained virtually identical over the 7-year period. The small differences observed can be ascribed to convective motions in the large-diameter casing and the large geothermal gradient. Above a depth of 160 m in the open hole, temperatures have cooled 5 degree -7 degree C over the 7-year period of observation. The shape of the temperature profiles and their variation with time can be explained by an influx of cool water at about 160 m. The cooling rate is much larger between 1982 and 1983 than that between 1982 and 1976, which suggests that earthquake shaking may be a major contributing factor.

  7. Programmed temperature vaporizing injector to filter off disturbing high boiling and involatile material for on-line high performance liquid chromatography gas chromatography with on-column transfer.

    PubMed

    Biedermann, Maurus; Grob, Koni

    2013-03-15

    Insertion of a programmed temperature vaporizing (PTV) injector under conditions of concurrent solvent recondensation (CSR) into the on-line HPLC-GC interface for on-column transfer (such as the retention gap technique with partially concurrent eluent evaporation) enables filtering off high boiling or involatile sample constituents by a desorption temperature adjusted to the required cut-off. Details of this technique were investigated and optimized. Memory effects, observed when transferred liquid was sucked backwards between the transfer line and the wall of the injector liner, can be kept low by a small purge flow rate through the transfer line at the end of the transfer and the release of the liquid through a narrow bore capillary kept away from the liner wall. The column entrance should be within the well heated zone of the injector to prevent losses of solute material retained on the liner wall during the splitless period. The desorption temperature must be maintained until an elevated oven temperature is reached to prevent peak broadening resulting of a cool inlet section in the bottom part of the injector. PMID:23394744

  8. Fluid inclusion from drill hole DW-5, Hohi geothermal area, Japan: Evidence of boiling and procedure for estimating CO2 content

    USGS Publications Warehouse

    Sasada, M.; Roedder, E.; Belkin, H.E.

    1986-01-01

    Fluid inclusion studies have been used to derive a model for fluid evolution in the Hohi geothermal area, Japan. Six types of fluid inclusions are found in quartz obtained from the drill core of DW-5 hole. They are: (I) primary liquid-rich with evidence of boiling; (II) primary liquid-rich without evidence of boiling; (III) primary vapor-rich (assumed to have been formed by boiling); (IV) secondary liquid-rich with evidence of boiling; (V) secondary liquid-rich without evidence of boiling; (VI) secondary vapor-rich (assumed to have been formed by boiling). Homogenization temperatures (Th) range between 196 and 347??C and the final melting point of ice (Tm) between -0.2 and -4.3??C. The CO2 content was estimated semiquantitatively to be between 0 and 0.39 wt. % based on the bubble behavior on crushing. NaCl equivalent solid solute salinity of fluid inclusions was determined as being between 0 and 6.8 wt. % after minor correction for CO2 content. Fluid inclusions in quartz provide a record of geothermal activity of early boiling and later cooling. The CO2 contents and homogenization temperatures of fluid inclusions with evidence of boiling generally increase with depth; these changes, and NaCl equivalent solid solute salinity of the fluid can be explained by an adiabatic boiling model for a CO2-bearing low-salinity fluid. Some high-salinity inclusions without CO2 are presumed to have formed by a local boiling process due to a temperature increase or a pressure decrease. The liquid-rich primary and secondary inclusions without evidence of boiling formed during the cooling process. The salinity and CO2 content of these inclusions are lower than those in the boiling fluid at the early stage, probably as a result of admixture with groundwater. ?? 1986.

  9. Visualization and void fraction measurement of decompressed boiling flow in a capillary tube

    NASA Astrophysics Data System (ADS)

    Asano, H.; Murakawa, H.; Takenaka, N.; Takiguchi, K.; Okamoto, M.; Tsuchiya, T.; Kitaide, Y.; Maruyama, N.

    2011-09-01

    A capillary tube is often used as a throttle for a refrigerating cycle. Subcooled refrigerant usually flows from a condenser into the capillary tube. Then, the refrigerant is decompressed along the capillary tube. When the static pressure falls below the saturation pressure for the liquid temperature, spontaneous boiling occurs. A vapor-liquid two-phase mixture is discharged from the tube. In designing a capillary tube, it is necessary to calculate the flow rate for given boundary conditions on pressure and temperature at the inlet and exit. Since total pressure loss is dominated by frictional and acceleration losses during two-phase flow, it is first necessary to specify the boiling inception point. However, there will be a delay in boiling inception during decompressed flow. This study aimed to clarify the boiling inception point and two-phase flow characteristics of refrigerant in a capillary tube. Refrigerant flows in a coiled copper capillary tube were visualized by neutron radiography. The one-dimensional distribution of volumetric average void fraction was measured from radiographs through image processing. From the void fraction distribution, the boiling inception point was determined. Moreover, a simplified CT method was successfully applied to a radiograph for cross-sectional measurements. The experimental results show the flow pattern transition from intermittent flow to annular flow that occurred at a void fraction of about 0.45.

  10. Investigation of low-temperature fixed points by an international star intercomparison of sealed triple-point cells

    NASA Astrophysics Data System (ADS)

    Fellmuth, B.; Wolber, L.; Head, D. I.; Hermier, Y.; Hill, K. D.; Nakano, T.; Pavese, F.; Peruzzi, A.; Rusby, R. L.; Shkraba, V.; Steele, A. G.; Steur, P. P. M.; Szmyrka-Grzebyk, A.; Tew, W. L.; Wang, L.; White, D. R.

    2012-06-01

    An overview of the results of an international star intercomparison of low-temperature fixed points is given. Between 1997 and 2005, 68 sealed triple-point cells (STPCs) of the twelve laboratories represented by the authors were investigated at PTB. The STPCs are used to realize the triple points of hydrogen, neon, oxygen and argon as defining fixed points of the International Temperature Scale of 1990, ITS-90. The melting curves (MCs) of all STPCs have been measured on the same experimental equipment, adhering strictly to a single measurement program. This protocol enables separation of the effects influencing the MCs and direct comparison of the thermal behaviour of the STPCs, which are quite different with respect to design, age, gas source and filling technology. In the paper, special emphasis is given to the spread of the liquidus-point temperatures and to the uncertainty of their determination. Connections between the star intercomparison and completed and ongoing international activities are also discussed.

  11. Phase relations and adiabats in boiling seafloor geothermal systems

    USGS Publications Warehouse

    Bischoff, J.L.; Pitzer, Kenneth S.

    1985-01-01

    Observations of large salinity variations and vent temperatures in the range of 380-400??C suggest that boiling or two-phase separation may be occurring in some seafloor geothermal systems. Consideration of flow rates and the relatively small differences in density between vapors and liquids at the supercritical pressures at depth in these systems suggests that boiling is occurring under closed-system conditions. Salinity and temperature of boiling vents can be used to estimate the pressure-temperature point in the subsurface at which liquid seawater first reached the two-phase boundary. Data are reviewed to construct phase diagrams of coexisting brines and vapors in the two-phase region at pressures corresponding to those of the seafloor geothermal systems. A method is developed for calculating the enthalpy and entropy of the coexisting mixtures, and results are used to construct adiabats from the seafloor to the P-T two-phase boundary. Results for seafloor vents discharging at 2300 m below sea level indicate that a 385??C vent is composed of a brine (7% NaCl equivalent) in equilibrium with a vapor (0.1% NaCl). Brine constitutes 45% by weight of the mixture, and the fluid first boiled at approximately 1 km below the seafloor at 415??C, 330 bar. A 400??C vent is primarily vapor (88 wt.%, 0.044% NaCl) with a small amount of brine (26% NaCl) and first boiled at 2.9 km below the seafloor at 500??C, 520 bar. These results show that adiabatic decompression in the two-phase region results in dramatic cooling of the fluid mixture when there is a large fraction of vapor. ?? 1985.

  12. A noninvasive human temperature screening system with multiple detection points

    NASA Astrophysics Data System (ADS)

    Sumriddetchkajorn, Sarun; Chaitavon, Kosom

    2008-04-01

    This paper introduces a non-invasive human temperature screening system for use in a large public area. Our key idea is to combine an image filtering process, an image morphology algorithm, and a particle analysis process in such a way that an individual's face in live thermal image can be located so that the skin temperature can be monitored and displayed. From our experiment, we find that the temperature measurement depends on each individual's response to the ambient temperature and on the contrast of the thermal image against the black body radiation source. This indicates that using the blackbody radiation source as our temperature reference does not totally compensate the fluctuation in human skin temperature. Our field test study at the triage section of Rajavithi Hospital, Thailand, shows that the maximum skin temperatures from people's faces can be simultaneously monitored and displayed in real time. In addition, the temperature value obtained from the thermal imaging camera has less fluctuation with respect to the true core body temperature once the disturbance from the surrounding environment is compensated. Hyperthermic patients can be identified with 100% sensitivity when the temperature threshold level and the offset temperature value are appropriately chosen.

  13. Microchannel flow boiling mechanisms leading to burnout

    SciTech Connect

    Landram, C.S.

    1994-03-01

    The boiling mechanisms for microchannel flow are investigated when the channel cross-section in height to width is large (of order 10/1), near its single-phase optimum. A separated flow model was developed which allowed for saturated boiling near the heated base and single-phase flow elsewhere within the channel cross-section. In these high aspect ratio heat sinks, the role of subcooled boiling was found to be insignificant relative to that of saturated boiling, the latter allowing for a doubling of the applied heat load from single-phase operation before burnout was experienced. As the exit mass quality of the saturated region approached one for increasing heat flux, both the model and the experimental case indicated a burnout condition had also been approached. The model underpredicted the measured base temperature, which has been generally noted for saturated boiling in annular two-phase flow.

  14. Chiral interface at the finite temperature transition point of QCD

    NASA Technical Reports Server (NTRS)

    Frei, Z.; Patkos, A.

    1990-01-01

    The domain wall between coexisting chirally symmetric and broken symmetry regions is studied in a saddle point approximation to the effective three-flavor sigma model. In the chiral limit the surface tension varies in the range ((40 to -50)MeV)(exp 3). The width of the domain wall is estimated to be approximately or equal to 4.5 fm.

  15. The Transition From Nucleate Boiling Towards the Convection: Application to the Quenching of Metallic Massive Parts

    SciTech Connect

    Bourouga, Brahim; Gilles, Jerome

    2007-04-07

    In a recent study on thermal aspects of the quenching process, we developed an original device of measurement which allowed to update the competition between the heat transfer modes according to the quenching conditions and the quenched part size. One shows that, according to the range value of Biot number, the more resistive one part is, the more the boiling phases are relatively short. In order to provide relatively precise data for simulation of the quenching process in the case of strongly resistive parts from a thermal point of view, we undertook experiments on the cooling transition from nucleate boiling towards the convection. The obtained experimental results show that the temperature of transition from the nucleate boiling to the convection increases when the bath temperature decreases. We present the differences between the values of convection coefficient according to whether the bath is agitated or not. Experimental results relating are compared to some classical correlations.

  16. Hydrogenation of high boiling hydrocarbons

    SciTech Connect

    Unger, H.; Sze, M.C.; Van Driesen, R.P.

    1983-10-25

    In a hydrogenation operation employing an ebullated catalytic bed, recycle is recovered from the hydrogenated product with at least 25%, by volume, of the recycle boiling above 950/sup 0/ F. The recycle is cooled to a temperature of from 350/sup 0/ to 600/sup 0/ F. to separate coke precursors, prior to recycle to the hydrogenation. Higher conversion levels can be achieved by effecting recycle in such manner.

  17. Evaporation, Boiling and Bubbles

    ERIC Educational Resources Information Center

    Goodwin, Alan

    2012-01-01

    Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The

  18. Subcooled and low quality film boiling of water in vertical flow at atmospheric pressure. [PWR; BWR

    SciTech Connect

    Fung, K.K.

    1981-08-01

    Subcooled and low quality film boiling is usually encountered in safety analyses of nuclear reactors. In most of the previous subcooled film boiling studies, cryogenic fluids were used either in a stagnant pool or a forced convective set-up. These data cannot be applied to reactor safety analysis without excessive conservatism or skepticism. In this study, a unique method is used to establish flow film boiling of water in a vertical tube at atmospheric pressure. The data cover a mass flux range of 50 to 500 kg.m/sup -2/.s/sup -1/ and an inlet subcooling range of 5 to 70/sup 0/C. It is found that the heat transfer coefficient depends on the mass flux, inlet subcooling and the axial distance from the point where film boiling first starts. A physical model is developed to predict the wall temperature of a tube during inverted annular film boiling. It considers the thermal boundary layers in the subcooled liquid core and in the superheated vapor film. The predicted wall temperatures and void fractions compare well with the measurements.

  19. Multiple-Point Temperature Gradient Algorithm for Ring Laser Gyroscope Bias Compensation.

    PubMed

    Li, Geng; Zhang, Pengfei; Wei, Guo; Xie, Yuanping; Yu, Xudong; Long, Xingwu

    2015-01-01

    To further improve ring laser gyroscope (RLG) bias stability, a multiple-point temperature gradient algorithm is proposed for RLG bias compensation in this paper. Based on the multiple-point temperature measurement system, a complete thermo-image of the RLG block is developed. Combined with the multiple-point temperature gradients between different points of the RLG block, the particle swarm optimization algorithm is used to tune the support vector machine (SVM) parameters, and an optimized design for selecting the thermometer locations is also discussed. The experimental results validate the superiority of the introduced method and enhance the precision and generalizability in the RLG bias compensation model. PMID:26633401

  20. Multiple-Point Temperature Gradient Algorithm for Ring Laser Gyroscope Bias Compensation

    PubMed Central

    Li, Geng; Zhang, Pengfei; Wei, Guo; Xie, Yuanping; Yu, Xudong; Long, Xingwu

    2015-01-01

    To further improve ring laser gyroscope (RLG) bias stability, a multiple-point temperature gradient algorithm is proposed for RLG bias compensation in this paper. Based on the multiple-point temperature measurement system, a complete thermo-image of the RLG block is developed. Combined with the multiple-point temperature gradients between different points of the RLG block, the particle swarm optimization algorithm is used to tune the support vector machine (SVM) parameters, and an optimized design for selecting the thermometer locations is also discussed. The experimental results validate the superiority of the introduced method and enhance the precision and generalizability in the RLG bias compensation model. PMID:26633401

  1. The influence of some relevant metallic impurities in the triple point of mercury temperature

    NASA Astrophysics Data System (ADS)

    Tabacaru, C.; del Campo, D.; Gómez, E.; García Izquiedo, C.; Welna, A.; Kalemci, M.; Pehlivan, Ö.

    2016-02-01

    The influence of impurities on the defined fixed points of the International Temperature Scale of 1990 is one of the most relevant sources of uncertainty in their use. Namely, the triple point of mercury is one of the fixed points most used because its assigned triple point temperature (‑39,8344 °C) is within a temperature range of high interest for science and industry. Mercury can be obtained with high purity, usually better that 8N and it is realized with a high accuracy, what makes impurities a significant contributor on the final uncertainty. The best procedure to quantify this influence is by means of doping experiments which consist of the addition of a controlled amount of an impurity, determined gravimetrically, in a fixed point cell. This paper presents a summary of the results obtained from a series of doping experiments performed with some relevant metallic impurities on the triple point of mercury temperature.

  2. Conceptual design for spacelab pool boiling experiment

    NASA Technical Reports Server (NTRS)

    Lienhard, J. H.; Peck, R. E.

    1978-01-01

    A pool boiling heat transfer experiment to be incorporated with a larger two-phase flow experiment on Spacelab was designed to confirm (or alter) the results of earth-normal gravity experiments which indicate that the hydrodynamic peak and minimum pool boiling heat fluxes vanish at very low gravity. Twelve small sealed test cells containing water, methanol or Freon 113 and cylindrical heaters of various sizes are to be built. Each cell will be subjected to one or more 45 sec tests in which the surface heat flux on the heaters is increased linearly until the surface temperature reaches a limiting value of 500 C. The entire boiling process will be photographed in slow-motion. Boiling curves will be constructed from thermocouple and electric input data, for comparison with the motion picture records. The conduct of the experiment will require no more than a few hours of operator time.

  3. Boiling heat transfer from an excavated fin

    SciTech Connect

    Liaw, S.P.; Yeh, R.H. )

    1992-03-01

    In this paper a single pin fin with excavation at base is proposed to enhance boiling heat transfer. The temperature distribution in the fin is obtained numerically by solving a two-dimensional heat conduction equation. A copper fin boiling in isopropyl alcohol is taken as an example. When the operating temperature exceeds a specific value, the heat duty decreases drastically, and the whole fin is governed by film boiling. This highest operating temperature limit (burnout) is raised by digging a hole at the fin base. Two distinct solutions are found by using different initial guesses into the code. This hysteresis effect becomes noticeable for a bigger hole. A model is also developed to predict the burnout temperatures.

  4. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... cargo temperature during discharge: Categories A, B, and C. 153.908 Section 153.908 Shipping COAST GUARD... Cargo viscosity and melting point information; measuring cargo temperature during discharge: Categories... in mPa.s and, if the cargo's viscosity exceeds 25 mPa.s at 20 °C, the temperature at which...

  5. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... cargo temperature during discharge: Categories A, B, and C. 153.908 Section 153.908 Shipping COAST GUARD... Cargo viscosity and melting point information; measuring cargo temperature during discharge: Categories... in mPa.s and, if the cargo's viscosity exceeds 25 mPa.s at 20 °C, the temperature at which...

  6. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... cargo temperature during discharge: Categories A, B, and C. 153.908 Section 153.908 Shipping COAST GUARD... Cargo viscosity and melting point information; measuring cargo temperature during discharge: Categories... in mPa.s and, if the cargo's viscosity exceeds 25 mPa.s at 20 °C, the temperature at which...

  7. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... cargo temperature during discharge: Categories A, B, and C. 153.908 Section 153.908 Shipping COAST GUARD... Cargo viscosity and melting point information; measuring cargo temperature during discharge: Categories... in mPa.s and, if the cargo's viscosity exceeds 25 mPa.s at 20 °C, the temperature at which...

  8. Development of a mechanistic model for forced convection subcooled boiling

    NASA Astrophysics Data System (ADS)

    Shaver, Dillon R.

    The focus of this work is on the formulation, implementation, and testing of a mechanistic model of subcooled boiling. Subcooled boiling is the process of vapor generation on a heated wall when the bulk liquid temperature is still below saturation. This is part of a larger effort by the US DoE's CASL project to apply advanced computational tools to the simulation of light water reactors. To support this effort, the formulation of the dispersed field model is described and a complete model of interfacial forces is formulated. The model has been implemented in the NPHASE-CMFD computer code with a K-epsilon model of turbulence. The interfacial force models are built on extensive work by other authors, and include novel formulations of the turbulent dispersion and lift forces. The complete model of interfacial forces is compared to experiments for adiabatic bubbly flows, including both steady-state and unsteady conditions. The same model is then applied to a transient gas/liquid flow in a complex geometry of fuel channels in a sodium fast reactor. Building on the foundation of the interfacial force model, a mechanistic model of forced-convection subcooled boiling is proposed. This model uses the heat flux partitioning concept and accounts for condensation of bubbles attached to the wall. This allows the model to capture the enhanced heat transfer associated with boiling before the point of net generation of vapor, a phenomenon consistent with existing experimental observations. The model is compared to four different experiments encompassing flows of light water, heavy water, and R12 at different pressures, in cylindrical channels, an internally heated annulus, and a rectangular channel. The experimental data includes axial and radial profiles of both liquid temperature and vapor volume fraction, and the agreement can be considered quite good. The complete model is then applied to simulations of subcooled boiling in nuclear reactor subchannels consistent with the operating conditions of the AP1000 pressurized water reactor. The effects of both axial and lateral nonuniform power distributions inside reactor fuel elements are accounted for. Boiling flows are simulated for three different computational domains of increasing complexity: a quarter-subchannel bordering a single fuel pin, two subchannels surround by an array of 2 by 3 fuel pins, and in four subchannels surrounded by an array of 3 by 3 fuel pins. The predicted behavior is consistent with expectations. In the 3 by 3 array, the two-phase coolant is predicted to flow from the hot channels to the cold channels, enhancing heat exchange between subchannels. This, in turn, demonstrates that the new model is capable of capturing the turbulence- and buoyancy-induced coolant mixing across the neighboring channels.

  9. Odd-Boiled Eggs

    ERIC Educational Resources Information Center

    Kaminsky, Kenneth; Scheman, Naomi

    2010-01-01

    At a Shabbat lunch in Madrid not long ago, the conversation turned to the question of boiling eggs. One of the guests mentioned that a Dutch rabbi he knew had heard that in order to make it more likely that boiled eggs be kosher, you should add an egg to the pot if the number you began with was even. According to the laws of Kashruth, Jews may not

  10. Boiling enhancement by microgrooves

    SciTech Connect

    Barron, R.F.; Baig, M.A.

    1996-12-31

    Several techniques have been proposed to improve the boiling heat transfer process, including surfaces with re-entrant holes, porous sintered metal coatings, etc. The purpose of this work was to examine the effect of circumferential microgrooves, produced by diamond-bit machining, on the film boiling heat transfer from a horizontal cylinder immersed in liquid nitrogen. The depth of the grooves was varied from 25 to 75 micrometers, and the width of the grooves was varied from 25 to 50 micrometers. Auxiliary tests were run using a cylinder with a smooth (polished) surface and one run was conducted with a cylinder having both circumferential microgrooves and longitudinal microgrooves. The boiling heat transfer coefficients were measured using a transient cool-down method. The results of the film boiling tests indicated that the use of microgrooves resulted in an improvement in the cool-down time and an enhancement of the boiling heat transfer coefficient by a factor of approximately 1.25. The cool-down time for the sample with no microgrooves was approximately 130 seconds; whereas, the sample having 50 pm deep by 25 pm wide microgrooves has a cool-down time of approximately 100 seconds. The improvement of the boiling heat transfer coefficient due to longitudinal microgrooves was insignificant, in comparison with that for the circumferential grooves.

  11. Boiling Temperature and Reversed Deliquescence Relative Humidity Measurements for Mineral Assemblages in the NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O System

    SciTech Connect

    Rard, J A; Staggs, K J; Day, S D; Carroll, S A

    2005-12-01

    Boiling temperature measurements have been made at ambient pressure for saturated ternary solutions of NaCl + KNO{sub 3} + H{sub 2}O, NaNO{sub 3} + KNO{sub 3} + H{sub 2}O, and NaCl + Ca(NO{sub 3}){sub 2} + H{sub 2}O over the full composition range, along with those of the single salt systems. Boiling temperatures were also measured for the four component NaCl + NaNO{sub 3} + KNO{sub 3} + H{sub 2}O and five component NaCl + NaNO{sub 3} + KNO{sub 3} + Ca(NO{sub 3}){sub 2} + H{sub 2}O mixtures, where the solute mole fraction of Ca(NO{sub 3}){sub 2}, x(Ca(NO{sub 3}){sub 2}), was varied between 0 and 0.25. The maximum boiling temperature found for the NaCl + KNO{sub 3} + H{sub 2}O system is {approx} 134.9 C; for the NaNO{sub 3} + KNO{sub 3} + H{sub 2}O system is {approx} 165.1 C at x(NaNO{sub 3}) {approx} 0.46 and x(KNO{sub 3}) {approx} 0.54; and for the NaCl + Ca(NO{sub 3}){sub 2} + H{sub 2}O system is 164.7 {+-} 0.6 C at x(NaCl) {approx} 0.25 and x(Ca(NO{sub 3}){sub 2}) {approx} 0.75. The NaCl + NaNO{sub 3} + KNO{sub 3} + Ca(NO{sub 3}){sub 2} + H{sub 2}O system forms molten salts below their maximum boiling temperatures, and the temperatures corresponding to the cessation of boiling (dry out temperatures) of these liquid mixtures were determined. These dry out temperatures range from {approx} 300 C when x(Ca(NO{sub 3}){sub 2}) = 0 to {ge} 400 C when x(Ca(NO{sub 3}){sub 2}) = 0.20 and 0.25. Mutual deliquescence/efflorescence relative humidity (MDRH/MERH) measurements were also made for the NaNO{sub 3} + KNO{sub 3} and NaCl + NaNO{sub 3} + KNO{sub 3} salt mixture from 120 to 180 C at ambient pressure. The NaNO{sub 3} and NaCl + NaNO{sub 3} + KNO{sub 3} salt mixture has a MDRH of 26.4% at 120 C and 20.0% at 150 C. This salt mixture also absorbs water at 180 C, which is higher than expected from the boiling temperature experiments. The NaCl + NaNO{sub 3} + KNO{sub 3} salt mixture was found to have a MDRH of 25.9% at 120 C and 10.5% at 180 C. The investigated mixture compositions correspond to some of the major mineral assemblages that are predicted to control brine composition due to the deliquescence of salts formed in dust deposited on waste canisters in the proposed nuclear repository at Yucca Mountain, Nevada.

  12. Critical boiling phenomena observed in microgravity

    NASA Astrophysics Data System (ADS)

    Garrabos, Y.; Chabot, C.; Wunenburger, R.; Delville, J.-P.; Beysens, D.

    1999-06-01

    We report experimental observations of the critical boiling when co-existing gas and liquid phases of pure fluid are heated under weigthlessness through the critical point. We find that when the system's temperature T is being increased to the critical temperature Tc so that it's slightly out of equilibrium, the apparent contact angle becomes very large (up to 110 circ). The gas appears to "web" the solid surface. In addition, we detect large temperature gradients between the (hot) gas phase and the (cold) liquid phase in the interferometric cell. These unexpected results are robust: they are observed either under continuous heating (ramping) or stepping by positive temperature quenches, for various morphologies of the gas bubble and in different fluids (SF6 and CO2). The difference in isentropic thermal responses of gas and liquid during heating, due to the adiabatic heating by the "Piston Effect", is responsible for the temperature non-homogeneities. The vapour recoil force due to liquid evaporation, which is involved in the boiling crisis in heat exchangers, is presumably at the origin of the interface deformation. Nous rapportons les observations expérimentales obtenues en chaffant un fluide pur diphasique gaz-liquide en coexistence au cours de la traversée de son point critique en absence de pesanteur. Lorsque la température du système diphasique hors d'équilibre est augmentée vers la température critique, nous observons en transmission un angle de contact apparent de la vapeur très important (atteignant 110 circ), le gaz semblant "mouiller" la surface solide. De plus, d'importants gradients de température entre la phase gaz chaude et la phase liquide froide sont mesurés dans les cellules observées par interférométrie. Ces résultats inattendus sont observés pour un chauffage continu (rampe) et par trempe positive (échelon), pour différents rapports d'aspect du système diphasique, pour des cellules de CO2 et de SF6, démontrant ainsi une grande robustesse. Les réponses isentropiques différentes du gaz et du liquide lors du chauffage par effet piston sont certainement responsables des inhomogénéités de température. La force de recul de la vapeur due à l'évaporation pourrait être la cause dominante de la déformation de l'interface liquide-vapeur à l'approche de la température de transition.

  13. Comparison of Single-Point and Continuous Sampling Methods for Estimating Residential Indoor Temperature and Humidity.

    PubMed

    Johnston, James D; Magnusson, Brianna M; Eggett, Dennis; Collingwood, Scott C; Bernhardt, Scott A

    2015-01-01

    Residential temperature and humidity are associated with multiple health effects. Studies commonly use single-point measures to estimate indoor temperature and humidity exposures, but there is little evidence to support this sampling strategy. This study evaluated the relationship between single-point and continuous monitoring of air temperature, apparent temperature, relative humidity, and absolute humidity over four exposure intervals (5-min, 30-min, 24-hr, and 12-days) in 9 northern Utah homes, from March-June 2012. Three homes were sampled twice, for a total of 12 observation periods. Continuous data-logged sampling was conducted in homes for 2-3 wks, and simultaneous single-point measures (n = 114) were collected using handheld thermo-hygrometers. Time-centered single-point measures were moderately correlated with short-term (30-min) data logger mean air temperature (r = 0.76, β = 0.74), apparent temperature (r = 0.79, β = 0.79), relative humidity (r = 0.70, β = 0.63), and absolute humidity (r = 0.80, β = 0.80). Data logger 12-day means were also moderately correlated with single-point air temperature (r = 0.64, β = 0.43) and apparent temperature (r = 0.64, β = 0.44), but were weakly correlated with single-point relative humidity (r = 0.53, β = 0.35) and absolute humidity (r = 0.52, β = 0.39). Of the single-point RH measures, 59 (51.8%) deviated more than ±5%, 21 (18.4%) deviated more than ±10%, and 6 (5.3%) deviated more than ±15% from data logger 12-day means. Where continuous indoor monitoring is not feasible, single-point sampling strategies should include multiple measures collected at prescribed time points based on local conditions. PMID:26030088

  14. Enhancements of Nucleate Boiling Under Microgravity Conditions

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Yang, W. J.

    2000-01-01

    This paper presents two means for enhancing nucleate boiling and critical heat flux under microgravity conditions: using micro-configured metal-graphite composites as the boiling surface and dilute aqueous solutions of long-chain alcohols as the working fluid. In the former, thermocapillary force induced by temperature difference between the graphite-fiber tips and the metal matrix plays an important role in bubble detachment. Thus boiling-heat transfer performance does not deteriorate in a reduced-gravity environment. In the latter cases, the surface tension-temperature gradient of the long-chain alcohol solutions turns positive as the temperature exceeds a certain value. Consequently, the Marangoni effect does not impede, but rather aids in bubble departure from the heating surface. This feature is most favorable in microgravity. As a result, the bubble size of departure is substantially reduced at higher frequencies. Based on the existing experimental data, and a two-tier theoretical model, correlation formulas are derived for nucleate boiling on the copper-graphite and aluminum-graphite composite surfaces, in both the isolated and coalesced bubble regimes. In addition, performance equations for nucleate boiling and critical heat flux in dilute aqueous solutions of long-chain alcohols are obtained.

  15. Loop Heat Pipe Operation Using Heat Source Temperature for Set Point Control

    NASA Technical Reports Server (NTRS)

    Ku, Jentung; Paiva, Kleber; Mantelli, Marcia

    2011-01-01

    Loop heat pipes (LHPs) have been used for thermal control of several NASA and commercial orbiting spacecraft. The LHP operating temperature is governed by the saturation temperature of its compensation chamber (CC). Most LHPs use the CC temperature for feedback control of its operating temperature. There exists a thermal resistance between the heat source to be cooled by the LHP and the LHP's CC. Even if the CC set point temperature is controlled precisely, the heat source temperature will still vary with its heat output. For most applications, controlling the heat source temperature is of most interest. A logical question to ask is: "Can the heat source temperature be used for feedback control of the LHP operation?" A test program has been implemented to answer the above question. Objective is to investigate the LHP performance using the CC temperature and the heat source temperature for feedback control

  16. Study of structural break points in global and hemispheric temperature series by piecewise regression

    NASA Astrophysics Data System (ADS)

    Werner, Rolf; Valev, Dimitar; Danov, Dimitar; Guineva, Veneta

    2015-12-01

    The study of climate trends taking into consideration possible structural changes is important for understanding climate development characterized by a stochastic trend or by a determined one. In the paper global and hemisphere temperature anomalies are modeled by piecewise linear regression and break points in the temperature evolution are found. It was demonstrated that the used method allowed finding of breaks characterized by long time trends (low frequency processes) as well as abrupt changes (fast frequency processes). The obtained break points for slow temperature change are close to the ones found by other authors however additional conditions (as segment length, gradient and others) are not used here. The results for higher break point numbers are like the ones of step slope models. It was demonstrated that the successive phases of warming and cooling and most of the break points subdividing these periods in the Northern Hemisphere are introduced by the Atlantic multidecadal oscillation. Because the strong quasi periodicity of the Atlantic multidecadal oscillation the authors recommend the removal of its influence on the temperature from the temperature series before studies of trends or structural changes. The Northern Hemisphere temperature data after the removal of the Atlantic multidecadal oscillation influence show structures like the Southern Hemisphere temperatures. Model selection by the Schwarz-Bayesian Information Criterion developed by Liu, Wu and Zidek (LWZ criterion) shows that models with only one break point are to be preferred.

  17. The entrance effect on subcooled boiling in heated channels

    SciTech Connect

    Kurul, N.; Podowski, M.Z. )

    1989-11-01

    One of the major problems in the analysis of diabatic two-phase flows concerns the effect of thermodynamic nonequilibrium between the phases. In particular, this effect applies to forced-convection subcooled boiling in boiling water reactors (BWRs). An approach commonly used to evaluate the void distribution along reactor coolant channels is based on one-dimensional models of combined two-phase flow and boiling heat transfer. In the subcooled boiling region, the rate of phase change is governed mainly by the lateral transport of the vapor phase toward the subcooled liquid; thus, the related processes cannot be mechanistically modeled by one-dimensional, axially dependent models. Consequently, most existing subcooled boiling models are based on experimental correlations for parameters such as the onset of nucleate boiling (ONB) and the net vapor generation rate. This paper presents the results of analysis of subcooled boiling phenomena in the developing flow region of a boiling channel, based on a mechanistic two-dimensional, two-fluid model. The effect of turbulence has been accounted for by a k-{epsilon} model. The PHOENICS code was used to solve the governing mass, momentum, and energy conservation equations in both the nonboiling and boiling regions. The parameters calculated by the model include radially and axially dependent distributions of the local void fraction, temperatures and velocities of both phases, and the axial distribution of wall temperature.

  18. Effect of Running Parameters on Flow Boiling Instabilities in Microchannels.

    PubMed

    Zong, Lu-Xiang; Xu, Jin-Liang; Liu, Guo-Hua

    2015-04-01

    Flow boiling instability (FBI) in microchannels is undesirable because they can induce the mechanical vibrations and disturb the heat transfer characteristics. In this study, the synchronous optical visualization experimental system was set up. The pure acetone liquid was used as the working fluid, and the parallel triangle silicon microchannel heat sink was designed as the experimental section. With the heat flux ranging from 0-450 kW/m2 the microchannel demand average pressure drop-heater length (Δp(ave)L) curve for constant low mass flux, and the demand pressure drop-mass flux (Δp(ave)G) curve for constant length on main heater surface were obtained and studied. The effect of heat flux (q = 188.28, 256.00, and 299.87 kW/m2), length of main heater surface (L = 4.5, 6.25, and 8.00 mm), and mass flux (G = 188.97, 283.45, and 377.94 kg/m2s) on pressure drops (Ap) and temperatures at the central point of the main heater surface (Twc) were experimentally studied. The results showed that, heat flux, length of the main heater surface, and mass flux were identified as the important parameters to the boiling instability process. The boiling incipience (TBI) and critical heat flux (CHF) were early induced for the lower mass flux or the main heater surface with longer length. With heat flux increasing, the pressure drops were linearly and slightly decreased in the single liquid region but increased sharply in the two phase flow region, in which the flow boiling instabilities with apparent amplitude and long period were more easily triggered at high heat flux. Moreover, the system pressure was increased with the increase of the heat flux. PMID:26353523

  19. Sand boils without earthquakes

    USGS Publications Warehouse

    Holzer, T.L.; Clark, M.M.

    1993-01-01

    Sedimentary deformation caused by liquefaction has become a popular means for inferring prehistoric strong earthquakes. This report describes a new mechanism for generating such features in the absence of earthquakes. Sand boils and a 180-m-long sand dike formed in Fremont Valley, California, when sediment-laden surface runoff was intercepted along the upslope part of a 500-m-long preexisting ground crack, flowed subhorizonally in the crack, and then flowed upward in the downslope part of the crack where it discharged as sand boils on the land surface. If the sand boils and their feeder dike were stratigraphically preserved, they could be misinterpreted as evidence for earthquake-induced liquefaction. -Authors

  20. Curie point, susceptibility, and temperature measurements of rapidly heated ferromagnetic wires

    NASA Astrophysics Data System (ADS)

    Anwar, Muhammad Sabieh; Zia, Wasif

    2010-12-01

    This article describes a technique to measure the temperature of a resistively heated ferromagnetic wire. The wire's temperature rapidly increases, a scenario in which a thermocouple or thermistor's thermal inertia prevents it from keeping up with the rapid temperature variation. The temperature is derived from electrical measurands (voltage and current) and time, as well as thermophysical data such as heat losses and emissivity, and is based on a dynamical thermal-electrical energy conservation principle. We go on to use our technique for the quantitative determination of the Curie point as well as the magnetic susceptibility at elevated temperatures. The results are in good agreement with accepted values.

  1. Simple fabrication method for point temperature sensor probes using erbium ytterbium-coated optical fibres

    NASA Astrophysics Data System (ADS)

    Schartner, Erik P.; Monro, Tanya M.

    2014-05-01

    We report on the development of a point temperature sensor, based on coating tellurite onto the tips of optical fibres. By doping the tellurite glass with rare earth ions such as erbium the tip of the fibre can act as a localized temperature sensor by monitoring the upconversion emission from the ions. This sensing geometry allows the temperature to be measured with good spatial resolution, while the strong response of the rare earth ions to changing temperature provides a temperature precision of 0.1-0.3 C over the measured range.

  2. Changes in skin surface temperature at an acupuncture point with moxibustion

    PubMed Central

    Lin, Li-Mei; Wang, Shu-Fang; Lee, Ru-Ping; Hsu, Bang-Gee; Tsai, Nu-Man; Peng, Tai-Chu

    2013-01-01

    Objective This study evaluates the thermographic changes associated with moxa burner moxibustion at the SP6 acupuncture point to establish an appropriate, safe distance of efficacy for moxibustion. Methods Baseline temperature changes using a moxa burner were obtained for a paper substrate at various distances and times, and the tested with volunteers in a pilot study. A single-group trial was then conducted with 36 healthy women to monitor temperature changes on the body surface at the acupuncture point (SP6). Results Based on the temperature changes seen for the paper substrate and in the pilot study, a distance of 3?cm was chosen as the intervention distance. Moxibustion significantly increased the SP6 point skin surface temperature, with a peak increase of 11C at 4?min (p?<0.001). This study also found that during moxibustion the temperature of the moxa burner's rubber layer and moxa cautery were 56.90.9C and 65.81.2C, as compared to baseline values of 35.1C and 43.8C (p<0.001). Conclusions We determined 3?cm was a safe distance between the moxa burner and acupuncture point. Moxibustion can increase the skin surface temperature at the SP6 point. This data will aid traditional Chinese medicine (TCM) practitioners in gauging safer treatment distances when using moxibustion treatments. PMID:23598824

  3. Realization of the Temperature Scale in the Range from 234.3 K (Hg Triple Point) to 1084.62C (Cu Freezing Point) in Croatia

    NASA Astrophysics Data System (ADS)

    Zvizdic, Davor; Veliki, Tomislav; Grgec Bermanec, Lovorka

    2008-06-01

    This article describes the realization of the International Temperature Scale in the range from 234.3 K (mercury triple point) to 1084.62C (copper freezing point) at the Laboratory for Process Measurement (LPM), Faculty of Mechanical Engineering and Naval Architecture (FSB), University of Zagreb. The system for the realization of the ITS-90 consists of the sealed fixed-point cells (mercury triple point, water triple point and gallium melting point) and the apparatus designed for the optimal realization of open fixed-point cells which include the gallium melting point, tin freezing point, zinc freezing point, aluminum freezing point, and copper freezing point. The maintenance of the open fixed-point cells is described, including the system for filling the cells with pure argon and for maintaining the pressure during the realization.

  4. Critical heat flux and boiling heat transfer to water in a 3-mm-diameter horizontal tube.

    SciTech Connect

    Yu, W.; Wambsganss, M. W.; Hull, J. R.; France, D. M.

    2000-12-04

    Boiling of the coolant in an engine, by design or by circumstance, is limited by the critical heat flux phenomenon. As a first step in providing relevant engine design information, this study experimentally addressed both rate of boiling heat transfer and conditions at the critical point of water in a horizontal tube of 2.98 mm inside diameter and 0.9144 m heated length. Experiments were performed at system pressure of 203 kPa, mass fluxes in range of 50 to 200 kg/m{sup z}s, and inlet temperatures in range of ambient to 80 C. Experimental results and comparisons with predictive correlations are presented.

  5. Simulation study based on the single-point temperature monitoring system of LabVIEW

    NASA Astrophysics Data System (ADS)

    Wu, Yongling; Yang, Na; Liu, Shuping; Pan, Xiaohui; Wang, Wenjiang

    2014-12-01

    This paper takes LabVIEW2012 as a development platform, creating a J-type thermocouple sensor and the NI USB-6229 data acquisition card and other hardware emulation circuitry which combined with the PC designed a single-point temperature monitoring system. Through simulation experiments, the system has a collection interval, the sampling rate per channel sampling on the temperature limit set by the user function and it also has the function of real-time display the current temperature, the temperature limit alarm, maximum temperature, minimum temperature display and a temperature history data query. This system can be used for temperature monitoring of life, research, industrial control, environmental monitoring, biomedical, tobacco processing, greenhouse cultivation, livestock breeding and other fields, which has important significance and practical value.

  6. EVALUATION OF ROTARY KILN INCINERATOR OPERATION AT LOW TO MODERATE TEMPERATURE CONDITIONS VOLUME 1. TECHNICAL RESULTS

    EPA Science Inventory

    A test program was performed at the Environmental Protection Agency Incineration Research Facility to study the effectiveness of incineration at low-to-moderate temperatures in decontaminating soils containing organic compounds with different volatilities (boiling points). The da...

  7. Electronic rhinological thermometer for three-point air temperature measurement in nasal cavity

    NASA Astrophysics Data System (ADS)

    ?nieg, Marcin; Paczesny, Daniel; Weremczuk, Jerzy

    2008-01-01

    This article describes the design and construction of diagnostic medical system for air temperature measurement in nasal cavity. Concept of three-point thermometer is connected with single point electronic thermometer for air temperature measurement in nasal cavity that was previously constructed [1]. Researches were done in Microsystems and Sensors Research Group (WUT) with cooperation of physicians and laryngologists from Otolaryngology Department, Military Medical Institute, Warsaw. Measurement system consist of microprocessor module which periodically collects samples of air temperature from different part of nasal cavity, measurement head with three temperature sensors, and computer software presenting on-line results, calculating breathing parameters and storing data in database. Air temperature is measured in nasal cavity, middle part cavity and nasopharynx during regular respiration process.

  8. Modeling of Aerobrake Ballute Stagnation Point Temperature and Heat Transfer to Inflation Gas

    NASA Technical Reports Server (NTRS)

    Bahrami, Parviz A.

    2012-01-01

    A trailing Ballute drag device concept for spacecraft aerocapture is considered. A thermal model for calculation of the Ballute membrane temperature and the inflation gas temperature is developed. An algorithm capturing the most salient features of the concept is implemented. In conjunction with the thermal model, trajectory calculations for two candidate missions, Titan Explorer and Neptune Orbiter missions, are used to estimate the stagnation point temperature and the inflation gas temperature. Radiation from both sides of the membrane at the stagnation point and conduction to the inflating gas is included. The results showed that the radiation from the membrane and to a much lesser extent conduction to the inflating gas, are likely to be the controlling heat transfer mechanisms and that the increase in gas temperature due to aerodynamic heating is of secondary importance.

  9. Loop Heat Pipe Operation Using Heat Source Temperature for Set Point Control

    NASA Technical Reports Server (NTRS)

    Ku, Jentung; Paiva, Kleber; Mantelli, Marcia

    2011-01-01

    The LHP operating temperature is governed by the saturation temperature of its reservoir. Controlling the reservoir saturation temperature is commonly accomplished by cold biasing the reservoir and using electrical heaters to provide the required control power. Using this method, the loop operating temperature can be controlled within +/- 0.5K. However, because of the thermal resistance that exists between the heat source and the LHP evaporator, the heat source temperature will vary with its heat output even if LHP operating temperature is kept constant. Since maintaining a constant heat source temperature is of most interest, a question often raised is whether the heat source temperature can be used for LHP set point temperature control. A test program with a miniature LHP has been carried out to investigate the effects on the LHP operation when the control temperature sensor is placed on the heat source instead of the reservoir. In these tests, the LHP reservoir is cold-biased and is heated by a control heater. Tests results show that it is feasible to use the heat source temperature for feedback control of the LHP operation. Using this method, the heat source temperature can be maintained within a tight range for moderate and high powers. At low powers, however, temperature oscillations may occur due to interactions among the reservoir control heater power, the heat source mass, and the heat output from the heat source. In addition, the heat source temperature could temporarily deviate from its set point during fast thermal transients. The implication is that more sophisticated feedback control algorithms need to be implemented for LHP transient operation when the heat source temperature is used for feedback control.

  10. Cryogenic Boil-Off Reduction System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, David W.; Johnson, Wesley L.; Feller, Jeffery

    2014-01-01

    The Cryogenic Boil-Off Reduction System was tested with LH2 and LOX in a vacuum chamber to simulate space vacuum and the temperatures of low Earth orbit. Testing was successful and results validated the scaling study model that predicts active cooling reduces upper stage cryogenic propulsion mass for loiter periods greater than 2 weeks.

  11. A Fundamental Study of Nucleate Pool Boiling Under Microgravity

    NASA Technical Reports Server (NTRS)

    Ervin, Jamie S.; Merte, Herman, Jr.

    1996-01-01

    An experimental study of incipient boiling in short-term microgravity and with a/g = +/- 1 for pool boiling was performed. Calibrated thin gold films sputtered on a smoothly polished quartz surface were used simultaneously for thermal-resistance measurements and heating of the boiling surface. The gold films were used for both transient and quasi-steady heating surface temperature measurements. Two test vessels were constructed for precise measurement and control of fluid temperature and pressure: a laboratory pool boiling vessel for the a/g = +/- 1 experiments and a pool boiling vessel designed for the 131 m free-fall in the NASA Lewis Research Center Microgravity Research Facility for the microgravity tests. Measurements included the heater surface temperature, the pressure near the heating surface, the bulk liquid temperatures. High speed photography (up to 1,000 frames per second) was used in the experiments. With high quality microgravity and the measured initial temperature of the quiescent test fluid, R113, the temperature distribution in the liquid at the moment of boiling inception resulting from an imposed step in heat flux is known with a certainty not possible previously. The types of boiling propagation across the large flat heating surface, some observed here for the first time, are categorized; the conditions necessary for their occurrence are described. Explosive boiling propagation with a striking pattern of small scale protuberances over the entire vapor mass periphery not observed previously at low heat flux levels (on the order of 5 W/cm(exp 2)) is described. For the heater surface with a/g = -1, a step in the heater surface temperature of short duration was imposed. The resulting liquid temperature distribution at the moment of boiling inception was different from that obtained with a step in heat flux.

  12. A fundamental study of nucleate pool boiling under microgravity

    NASA Technical Reports Server (NTRS)

    Ervin, Jamie S.; Merte, Herman, Jr.

    1991-01-01

    An experimental study of incipient boiling in short-term microgravity and with a/g = +/- 1 for pool boiling was performed. Calibrated thin gold films sputtered on a smoothly polished quartz surface were used simultaneously for thermal resistance measurements and heating of the boiling surface. The gold films were used for both transient and quasi-steady heating surface temperature measurements. Two test vessels were constructed for precise measurement and control of fluid temperature and pressure: a laboratory pool boiling vessel for the a/g = +/- experiments and a pool boiling vessel designed for the 131 m free-fall in the NASA Lewis Research Center Microgravity Research Facility for the microgravity tests. Measurements included the heater surface temperature, the pressure near the heating surface, and the bulk liquid temperatures. High speed photography was used in the experiments. With high quality microgravity and the measured initial temperature of the quiescent test fluid, R113, the temperature distribution in the liquid at the moment of boiling inception resulting from an imposed step in heat flux is known with a certainty not possible previously. The types of boiling propagation across the large flat heating surface are categorized; the conditions necessary for their occurrence are described. Explosive boiling propagation with a striking pattern of small scale protuberances over the entire vapor mass periphery not observed previously at low heat flux levels is described. For the heater surface with a/g = -1, a step in the heater surface temperature of short duration was imposed. The resulting liquid temperature distribution at the moment of boiling inception was different from that obtained with a step in heat flux.

  13. Numerical Investigation of Boiling

    NASA Astrophysics Data System (ADS)

    Sagan, Michael; Tanguy, Sebastien; Colin, Catherine

    2012-11-01

    In this work, boiling is numerically investigated, using two phase flow direct numerical simulation based on a level set / Ghost Fluid method. Nucleate boiling implies both thermal issue and multiphase dynamics issues at different scales and at different stages of bubble growth. As a result, the different phenomena are investigated separately, considering their nature and the scale at which they occur. First, boiling of a static bubble immersed in an overheated liquid is analysed. Numerical simulations have been performed at different Jakob numbers in the case of strong density discontinuity through the interface. The results show a good agreement on bubble radius evolution between the theoretical evolution and numerical simulation. After the validation of the code for the Scriven test case, interaction of a bubble with a wall is studied. A numerical method taking into account contact angle is evaluated by comparing simulations of the spreading of a liquid droplet impacting on a plate, with experimental data. Then the heat transfer near the contact line is investigated, and simulations of nucleate boiling are performed considering different contact angles values. Finally, the relevance of including a model to take into account the evaporation of the micro layer is discussed.

  14. Stability of electric heaters in the boiling heat transfer process

    SciTech Connect

    Loeffler, R.I.

    1991-01-01

    Boiling heat transfer from electrically heated wires and composite heaters was studied in the three boiling regimes; nucleate, transition, and film. The electrical input to the heaters was controlled by the heater temperature through the use of feedback control techniques. Particular attention was paid to the transition region of the boiling curve where the slope is negative and operation is unstable without proper control. Boiling curves produced by an x-ray plotter are presented for gold-plated tungsten wires and also for platinum wires. Stability conditions and transfer functions were developed for a complete composite heater system. Steady-state operation in the transition region of the boiling curve clearly demonstrates that there are two separate transition curves depending on whether the temperature is increasing or decreasing.

  15. Microwave-Assisted Superheating and/or Microwave-Specific Superboiling (Nucleation-Limited Boiling) of Liquids Occurs under Certain Conditions but is Mitigated by Stirring.

    PubMed

    Ferrari, Anthony; Hunt, Jacob; Stiegman, Albert; Dudley, Gregory B

    2015-01-01

    Temporary superheating and sustained nucleation-limited "superboiling" of unstirred liquids above the normal atmospheric boiling point have been documented during microwave heating. These phenomena are reliably observed under prescribed conditions, although the duration (of superheating) and magnitude (of superheating and superboiling) vary according to system parameters such as volume of the liquid and the size and shape of the vessel. Both phenomena are mitigated by rapid stirring with an appropriate stir bar and/or with the addition of boiling chips, which provide nucleation sites to support the phase-change from liquid to gas. With proper experimental design and especially proper stirring, the measured temperature of typical organic reaction mixtures heated at reflux will be close to the normal boiling point temperature of the solvent, whether heated using microwave radiation or conventional convective heat transfer. These observations are important to take into consideration when comparing reaction rates under conventional and microwave heating. PMID:26690096

  16. Natural saltwater upconing by boils: field measurements and numerical modeling

    NASA Astrophysics Data System (ADS)

    de Louw, Perry; Vandenbohede, Alexander; Werner, Adrian; Oude Essink, Gualbert

    2013-04-01

    In this study, natural saltwater upconing by boils was investigated using field measurements and numerical simulations. As one-quarter of The Netherlands lies below mean sea level, the upward flow of saline groundwater leads to the salinization of surface waters for large areas, impacting on agriculture and aquatic ecosystems. The largest seepage fluxes are found in deep polders with surface water levels maintained as low as 6 to 8 m below sea level. Recent studies showed that preferential groundwater discharge through boils is the dominant salinization source in these deep polders. Boils occur as conduits in the upper aquitard that connect the underlying aquifer to the surface through which groundwater discharges at high velocities. Groundwater preferentially discharging through boils contains up to hundred times more salt than diffuse forms of groundwater discharge. The upconing of deep saline groundwater induced by the localized, high-velocity flow through boils is the mechanism that leads to the high boil water salinities. The local boil system and associated natural salt water upconing were explored in the field in three different hydrogeological settings. Measurements of the aquifer salinity distribution, temperature, boil discharge, boil salinity and aquifer heads showed that the preferential flow through boils creates localized and narrow saltwater upconing spikes. The possibility to seal the boil at its source vent as a measure to abate surface water salinization was explored in the field. Numerical modeling with the code SEAWAT was applied to investigate the upconing processes in more detail. The field measurements were largely reproduced by the numerical model. 56 different cases, which differ in aquifer properties, salinity distribution, boil discharge and lateral regional flow,were defined to determine the most important boil salinity controlling factors. For each upconing case the sources of boil water, i.e. the contribution to boil discharge from different aquifer depths, were derived from the model results. The contributing depth distributions showed a form opposite to the aquifer salinity distribution, with higher contributions from shallower and less saline groundwater. This illustrates the importance of the density distribution in the aquifer on the saltwater upconing mechanism. The numerical results showed that the most important factors controlling the contributing depths and boil salinity are boil discharge, the horizontal hydraulic conductivity of the aquifer, the depth of the interface and the salinity (and therefore density) contrast within the aquifer. Within a small area of clustered boils, boil salinity varies between individual boils and is determined by the combination of its discharge and its position within the boil area, whereas the total discharge of boil clusters is the principal factor that controls natural saltwater upconing and total salt loads. Regional lateral flow had a large impact on the upconing mechanism in terms of flow patterns but had a minor effect on both the contribution of saline and fresh groundwater to boil discharge and boil salinity. Both measurements and model results will be presented at the EGU.

  17. Stability of cobalt-carbon high temperature fixed points doped with iron and platinum

    NASA Astrophysics Data System (ADS)

    K?azovick, L.; Lowe, D.; Machin, G.; Davies, H.; Rani, A.

    2015-04-01

    High temperature fixed points (HTFPs) are stable and repeatable and make comparison of temperature scales possible at a level of uncertainty not previously possible. However, they potentially lack objectivity if the fixed-point temperature is known. Five HTFPs were constructed, one pure Co-C, two Co-C doped with Fe and two Co-C doped with Pt of differing concentrations. The candidate dopants were identified through thermochemical modelling as likely to give maximum temperature shift with minimum increase in melting range. The temperature differences of the doped systems from the pure system were determined and it was found that the addition of Fe depressed the melting temperature and the addition of Pt elevated the melting temperature, qualitatively in line with the thermochemical modelling. The higher concentration doped HTFPs were then aged for approximately 100?h with continuous melting-freezing cycles and the difference to the undoped Co-C HTFP remeasured. These differences were found to agree with those of the unaged results within the measurement uncertainties, confirming artefact stability. It is clear that the doping of HTFPs is a powerful way of constructing stable and reliable high temperature scale comparison artefacts of unknown temperature.

  18. A Method to Improve the Temperature Distribution of Holder Around the Fixed-Point Cell Position

    NASA Astrophysics Data System (ADS)

    Lim, S. D.; Karmalawi, A. M.; Salim, S. G. R.; Soliman, M. A.; Kim, B. H.; Lee, D. H.; Yoo, Y. S.

    2014-07-01

    The temperature profile along the furnaces used in heating high-temperature fixed points has a crucial impact on the quality and duration of melting plateaux, accordingly the accuracy of thermodynamic temperature determination of such fixed points. This paper describes a simple, yet efficient, approach for improving the temperature uniformity along a cell holder in high-temperature blackbody (HTBB) furnaces that use pyrolytic graphite rings as heating elements. The method has been applied on the KRISS' HTBB furnace. In this work, an ideal solution for arranging the heating elements inside the furnace is presented by which the temperature gradient across the cell holder can be kept as low as possible. Numerical calculations, based on a finite element method, have been carried out to find the best possible arrangement of the rings. This has been followed by measuring the temperature gradient along an empty cell holder to validate our calculations. A temperature gradient of 100 mK has been achieved at over a length of 50 mm within a cell holder of 10 cm in length. It has also been shown that for a 20 cm long holder surrounded by rings with an arbitrary resistance profile, the temperature uniformity can be improved by adding a few "hot" rings around the cell holder.

  19. Measurement of Al Freezing-Point Temperature: Effect of Initiation Process

    NASA Astrophysics Data System (ADS)

    Abasov, M. Y.; Gerasimov, S. F.; Ivanova, A. G.; Pokhodun, A. I.; Shulgat, O. S.

    2010-09-01

    In CCT documents it is stated that "...for the freezing curves of the metallic fixed points, the maximum observed temperature on the plateau should be taken as the best approximation of the liquidus temperature. The fixed points should be realized with the inner and outer liquid-solid interfaces and extend past the maximum by 10 % to 20 % of the fraction frozen, to clearly establish the value of the maximum and the resolution of its determination." Also, it is accepted that "...the inner interface is essentially static. It is the temperature of the inner liquid/solid interface that is measured by the thermometer." The analysis of freezing curves obtained by the standard method of fixed-point realization shows that the parameters of the initial part of the freezing curve, the mean temperature value of which is usually taken as the liquidus temperature, depend on how the inner interface is initiated. Variations in the duration and intensity of initiation cause changes in the initial part of the freezing curve and in the resulting SPRT measurement. Moreover, the relation between the duration of the initial section of the plateau with a minor temperature change and the duration of its final section with a significant slope also depend on the initiation method used and on the furnace temperature. The effect of freezing initiation conditions on the measurement result is individual for each fixed point because of the differences in thermophysical properties of metals and in conditions of the heat transfer from the liquid-solid interface to the thermometer. Aluminum has a maximum value of the melting specific heat in comparison with other metals used in ITS-90 fixed points; in the present study, the effect of the intensity and duration of the inner liquid-solid interface initiation was investigated both experimentally and through calculation.

  20. Analysis of Screen Channel LAD Bubble Point Tests in Liquid Oxygen at Elevated Temperature

    NASA Technical Reports Server (NTRS)

    Hartwig, Jason; McQuillen, John

    2011-01-01

    The purpose of this paper is to examine the key parameters that affect the bubble point pressure for screen channel Liquid Acquisition Devices in cryogenic liquid oxygen at elevated pressures and temperatures. An in depth analysis of the effect of varying temperature, pressure, and pressurization gas on bubble point is presented. Testing of a 200 x 1400 and 325 x 2300 Dutch Twill screen sample was conducted in the Cryogenics Components Lab 7 facility at the NASA Glenn Research Center in Cleveland, Ohio. Test conditions ranged from 92 to 130K and 0.138 - 1.79 MPa. Bubble point is shown to be a strong function of temperature with a secondary dependence on pressure. The pressure dependence is believed to be a function of the amount of evaporation and condensation occurring at the screen. Good agreement exists between data and theory for normally saturated liquid but the model generally under predicts the bubble point in subcooled liquid. Better correlation with the data is obtained by using the liquid temperature at the screen to determine surface tension of the fluid, as opposed to the bulk liquid temperature.

  1. 46 CFR 154.705 - Cargo boil-off as fuel: General.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo boil-off as fuel: General. 154.705 Section 154.705... Pressure and Temperature Control 154.705 Cargo boil-off as fuel: General. (a) Each cargo boil-off fuel system under 154.703(c) must meet 154.706 through 154.709. (b) The piping in the cargo boil-off...

  2. 46 CFR 154.705 - Cargo boil-off as fuel: General.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Cargo boil-off as fuel: General. 154.705 Section 154.705... Pressure and Temperature Control 154.705 Cargo boil-off as fuel: General. (a) Each cargo boil-off fuel system under 154.703(c) must meet 154.706 through 154.709. (b) The piping in the cargo boil-off...

  3. 46 CFR 154.705 - Cargo boil-off as fuel: General.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Cargo boil-off as fuel: General. 154.705 Section 154.705... Pressure and Temperature Control 154.705 Cargo boil-off as fuel: General. (a) Each cargo boil-off fuel system under 154.703(c) must meet 154.706 through 154.709. (b) The piping in the cargo boil-off...

  4. 46 CFR 154.705 - Cargo boil-off as fuel: General.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo boil-off as fuel: General. 154.705 Section 154.705... Pressure and Temperature Control 154.705 Cargo boil-off as fuel: General. (a) Each cargo boil-off fuel system under 154.703(c) must meet 154.706 through 154.709. (b) The piping in the cargo boil-off...

  5. Experimental study on the onset of nucleate boiling in narrow channel by using grey relational analysis (GRA)

    NASA Astrophysics Data System (ADS)

    Han, Dong; Gao, Puzhen; Yan, Liming; Lv, Lulu

    2013-07-01

    The point of ONB (Onset of Nucleate Boiling) is a key point of boiling heat transfer in narrow channels. Due to the special structure and complex flow, the points of ONB in narrow channels are affected by many factors, their characteristics are not understood completely yet. In order to study relevant influence factors on ONB in narrow channel from the aspect of quantitative analysis, GRA (Grey Relational Analysis) is applied to analyze the experimental data of ONB in narrow channel by taking water as the working fluid. And then the intensity sequence of the factors that have effects on ONB are confirmed as the heat flux, outlet dryness, pressure, mass flow rate, inlet temperature and outlet temperature. Through analyzing the data of ONB of newly published literatures, the mechanisms for the main influence factors are suggested.

  6. Temperature and Species Measurements of Combustion Produced by a 9-Point Lean Direct Injector

    NASA Technical Reports Server (NTRS)

    Tedder, Sarah A.; Hicks, Yolanda R.; Locke, Randy J.

    2013-01-01

    This paper presents measurements of temperature and relative species concentrations in the combustion flowfield of a 9-point swirl venturi lean direct injector fueled with JP-8. The temperature and relative species concentrations of the flame produced by the injector were measured using spontaneous Raman scattering (SRS). Results of measurements taken at four flame conditions are presented. The species concentrations reported are measured relative to nitrogen and include oxygen, carbon dioxide, and water.

  7. Progress report for the CCT-WG5 high temperature fixed point research plan

    SciTech Connect

    Machin, G.; Woolliams, E. R.; Anhalt, K.; Bloembergen, P.; Sadli, M.; Yamada, Y.

    2013-09-11

    An overview of the progress in High Temperature Fixed Point (HTFP) research conducted under the auspices of the CCT-WG5 research plan is reported. In brief highlights are: Provisional long term stability of HTFPs has been demonstrated. Optimum construction methods for HTFPs have been established and high quality HTFPs of Co-C, Pt-C and Re-C have been constructed for thermodynamic temperature assignment. The major sources of uncertainty in the assignment of thermodynamic temperature have been identified and quantified. The status of absolute radiometric temperature measurement has been quantified through the circulation of a set of HTFPs. The measurement campaign to assign low uncertainty thermodynamic temperatures to a selected set of HTFPs will begin in mid-2012. It is envisaged that this will be complete by 2015 leading to HTFPs becoming routine reference standards for radiometry and high temperature metrology.

  8. Microbiological Effectiveness of Disinfecting Water by Boiling in Rural Guatemala

    PubMed Central

    Rosa, Ghislaine; Miller, Laura; Clasen, Thomas

    2010-01-01

    Boiling is the most common means of treating water in the home and the benchmark against which alternative point-of-use water treatment options must be compared. In a 5-week study in rural Guatemala among 45 households who claimed they always or almost always boiled their drinking water, boiling was associated with a 86.2% reduction in geometric mean thermotolerant coliforms (TTC) (N = 206, P < 0.0001). Despite consistent levels of fecal contamination in source water, 71.2% of stored water samples from self-reported boilers met the World Health Organization guidelines for safe drinking water (0 TTC/100 mL), and 10.7% fell within the commonly accepted low-risk category of (110 TTC/100 mL). As actually practiced in the study community, boiling significantly improved the microbiological quality of drinking water, though boiled and stored drinking water is not always free of fecal contaminations. PMID:20207876

  9. Ultra-high temperature isothermal furnace liners (IFLS) for copper freeze point cells

    NASA Astrophysics Data System (ADS)

    Dussinger, P. M.; Tavener, J. P.

    2013-09-01

    Primary Laboratories use large fixed-point cells in deep calibration furnaces utilizing heat pipes to achieve temperature uniformity. This combination of furnace, heat pipe, and cell gives the smallest of uncertainties. The heat pipe, also known as an isothermal furnace liner (IFL), has typically been manufactured with Alloy 600/601 as the envelope material since the introduction of high temperature IFLs over 40 years ago. Alloy 600/601 is a widely available high temperature material, which is compatible with Cesium, Potassium, and Sodium and has adequate oxidation resistance and reasonable high temperature strength. Advanced Cooling Technologies, Inc. (ACT) Alloy 600/Sodium IFLs are rated to 1100C for approximately 1000 hours of operation (based on creep strength). Laboratories interested in performing calibrations and studies around the copper freezing point (1084.62C) were frustrated by the 1000 hours at 1100C limitation and the fact that expensive freeze-point cells were getting stuck and/or crushed inside the IFL. Because of this growing frustration/need, ACT developed an Ultra High Temperature IFL to take advantage of the exceptional high temperature strength properties of Haynes 230.

  10. Study of the initiation of subcooled boiling during power transients

    SciTech Connect

    VanVleet, R.J.

    1985-01-01

    An experimental investigation of boiling initiation during power transients has been conducted for horizontal-cylinder heating elements in degassed distilled water. Platinum elements, 0.127 and 0.250 mm in diameter, were internally heated electrically at a controlled superficial heat flux (power applied divided by surface area) increasing linearly with time at rates of 0.035 and 0.35 MW/m/sup 2/s and corresponding test durations of 20 and 2 seconds. Tests were carried out at saturation temperatures from 100 to 195/sup 0/C with bulk fluid subcooling from 0 to 30 K. During the course of a power transient, element temperature and superficial heat flux were measured electrically and the boiling initiation time was determined optically. It was found that the conditions for boiling initiation depended strongly on the pressure-temperature history of the heating element and surround fluid prior to the transient. Boiling initiation times were found to agree qualitatively with predictions of a model based on the contact-angle hysteresis concept. Brief prepressurization prior to a transient was found to increase dramatically the temperature and heat flux required for boiling initiation because of deactivation of boiling initiation sites. However, sites were re-activated during the transient and, in subsequent tests without prepressurization, no elevation in boiling initiation conditions was observed and results were in quantitative agreement with predictions of the model.

  11. Measurement of Sticky Point Temperature of Coffee Powder with a Rheometer

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Sticky point temperature (Ts) measurement for hygroscopic food and biomaterial powders is traditionally performed with complex glass instruments. This property is used to characterize material stickiness, which substantially affects the flow and physical behavior of powders. In this research study w...

  12. Drilling efficiency and temperature elevation of three types of Kirschner-wire point.

    PubMed

    Piska, M; Yang, L; Reed, M; Saleh, M

    2002-01-01

    An innovative Kirschner (K-) wire point was developed and compared in fresh pig femora in terms of drilling efficiency and temperature elevation with the trochar and diamond points currently used in clinical practice. The tips of thermal couples were machined to the defined geometry and the temperature measured during drilling. Using the same drill speed (rev/min) and feed rate, the new K-wire point produced the lowest thrust force and torque as measured by a Kistler dynamometer. Drill point temperatures were highest with the trochar geometry (129 +/- 6 degrees C), followed by the diamond (98 +/- 7 degrees C). The lowest temperatures were recorded with the Medin K-wire (66 +/- 2 degrees C). On repeated drilling it could be used for up to 30 holes before reaching the less satisfactory drill performance of the diamond tip. The new K-wire provides a better alternative as it requires less effort for insertion, generates less heat and may be re-used. PMID:11837819

  13. Evaluation of engine coolants under flow boiling conditions

    SciTech Connect

    McAssey, E.V. Jr.; Stinson, C.; Gollin, M.

    1995-12-31

    An experimental program has been conducted to evaluate the heat transfer performance of two engine coolant mixtures, propylene-glycol/water and ethylene-glycol/water. In each mixture, the concentration was 50-50 by volume. Performance in this situation is defined as the ability to maintain a lower surface temperature for a given flux. The heat transfer regimes considered covered the range from single phase forced convection through saturated flow boiling. Results show that both coolants perform satisfactorily. However, in single phase convection, ethylene-glycol/water is slightly more effective. Conversely, for sub-cooled nucleate boiling and saturated boiling, propylene-glycol/water results in slightly lower metal temperatures.

  14. A probe for measuring temperature and pressure at the same points in a gas stream

    NASA Technical Reports Server (NTRS)

    Krause, L. N.; Glawe, G. E.; Dudzinski, T. J.

    1972-01-01

    Design features and characteristics of a means for measuring total temperature and total pressure at a single point in a gas stream are presented. A rake that provides five such combination measurements is described. Experimental data are included for the aerodynamic recovery and time response of the temperature sensor and for the flow-angle sensitivity of both the temperature and pressure sensors. Data were obtained over a subsonic Mach number range of 0.3 to 0.9 as well as at a Mach number of 1.4.

  15. Ductile-Brittle Transition Temperature testing of tungsten using the three-point bend test

    SciTech Connect

    Lassila, D.H.; Magness, F.; Freeman, D.

    1991-03-05

    Three-point bend tests were performed to determine the Ductile-Brittle Transition Temperatures (DBTTs) of forged and chemical vapor deposition (CVD) tungsten. Testing was performed under quasi-static conditions at temperatures between 23{degrees}C and 450{degrees}C using a forced-air environmental chamber. Load-displacement data from the three-point bend tests indicated that the constitutive behavior of the materials tested varied considerably. Finite element modeling of the three-point bend test was performed to investigate plastic strains induced in the samples during testing as a function of constitutive behavior. The modeling assumed plane stress conditions in the sample and simple bi-linear elastic-plastic constitutive behavior of the test material. The strains induced in the samples were found to be functions of both the yield stress and work hardening behavior of the materials. The use of the three-point bend test to determine DBTT, and the DBTTs reported for the test materials, are discussed relative to the modeling results. It is concluded that the three-point bend test has some utility in the determination of DBTTs if some caution is used in the selection of test parameters and fixture geometries. However, the three-point bed test does not provide a complete picture of the nature of the ductile-brittle transition. 12 refs., 9 figs.

  16. Boiling on Microconfigured Composite Surfaces Enhanced

    NASA Technical Reports Server (NTRS)

    Chao, David F.

    2000-01-01

    Boiling heat transfer is one of the key technologies for the two-phase active thermal-control system used on space platforms, as well as for the dynamic power systems aboard the International Space Station. Because it is an effective heat transfer mode, boiling is integral to many space applications, such as heat exchangers and other cooling devices. Nucleate boiling near the critical heat flux (CHF) can transport very large thermal loads with a much smaller device and much lower pumping power than for single-phase heat exchangers. However, boiling performance sharply deteriorates in a reduced-gravity environment, and operation in the CHF regime is somewhat perilous because of the risk of burnout to the device surface. New materials called microconfigured metal-graphite composites can enhance boiling. The photomicrograph shows the microconfiguration (x3000) of the copper-graphite (Cu-Gr) surface as viewed by scanning electronic microscope. The graphite fiber tips appear as plateaus with rugged surfaces embedded in the copper matrix. It has been experimentally demonstrated that this type of material manifests excellent boiling heat transfer performance characteristics and an increased CHF. Nonisothermal surfaces were less sensitive to variations of wall superheat in the CHF regime. Because of the great difference in conductivity between the copper base and the graphite fiber, the composite surfaces have a nonisothermal surface characteristic and, therefore, will have a much larger "safe" operating region in the CHF regime. In addition, the thermocapillary forces induced by the temperature differences between the fiber tips and the metal matrix play an important role in bubble detachment, and may not be adversely affected in a reduced-gravity environment. All these factors indicate that microconfigured composites may improve the reliability and economy (dominant factors in all space applications) of various thermal components found on spacecraft during future missions.

  17. Turning bubbles on and off during boiling using charged surfactants.

    PubMed

    Cho, H Jeremy; Mizerak, Jordan P; Wang, Evelyn N

    2015-01-01

    Boiling--a process that has powered industries since the steam age--is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature or steam generation cannot be adjusted for a given heat input. Here we report the ability to turn bubbles 'on and off' independent of heat input during boiling both temporally and spatially via molecular manipulation of the boiling surface. As a result, we can rapidly and reversibly alter heat transfer performance up to an order of magnitude. Our experiments show that this active control is achieved by electrostatically adsorbing and desorbing charged surfactants to alter the wettability of the surface, thereby affecting nucleation. This approach can improve performance and flexibility in existing boiling technologies as well as enable emerging or unprecedented energy applications. PMID:26486275

  18. Turning bubbles on and off during boiling using charged surfactants

    NASA Astrophysics Data System (ADS)

    Cho, H. Jeremy; Mizerak, Jordan P.; Wang, Evelyn N.

    2015-10-01

    Boiling--a process that has powered industries since the steam age--is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature or steam generation cannot be adjusted for a given heat input. Here we report the ability to turn bubbles `on and off' independent of heat input during boiling both temporally and spatially via molecular manipulation of the boiling surface. As a result, we can rapidly and reversibly alter heat transfer performance up to an order of magnitude. Our experiments show that this active control is achieved by electrostatically adsorbing and desorbing charged surfactants to alter the wettability of the surface, thereby affecting nucleation. This approach can improve performance and flexibility in existing boiling technologies as well as enable emerging or unprecedented energy applications.

  19. Analysis of Screen Channel LAD Bubble Point Tests in Liquid Methane at Elevated Temperature

    NASA Technical Reports Server (NTRS)

    Hartwig, Jason; McQuillen, John

    2012-01-01

    This paper examines the effect of varying the liquid temperature and pressure on the bubble point pressure for screen channel Liquid Acquisition Devices in cryogenic liquid methane using gaseous helium across a wide range of elevated pressures and temperatures. Testing of a 325 x 2300 Dutch Twill screen sample was conducted in the Cryogenic Components Lab 7 facility at the NASA Glenn Research Center in Cleveland, Ohio. Test conditions ranged from 105 to 160K and 0.0965 - 1.78 MPa. Bubble point is shown to be a strong function of the liquid temperature and a weak function of the amount of subcooling at the LAD screen. The model predicts well for saturated liquid but under predicts the subcooled data.

  20. Development of a new radiometer for the thermodynamic measurement of high temperature fixed points

    NASA Astrophysics Data System (ADS)

    Dury, M. R.; Goodman, T. M.; Lowe, D. H.; Machin, G.; Woolliams, E. R.

    2013-09-01

    The National Physical Laboratory (NPL) has developed a new radiometer to measure the thermodynamic melting point temperatures of high temperature fixed points with ultra-low uncertainties. In comparison with the NPL's Absolute Radiation Thermometer (ART), the "THermodynamic Optical Radiometer" (THOR) is more portable and compact, with a much lower size-of-source effect and improved performance in other parameters such as temperature sensitivity. It has been designed for calibration as a whole instrument via the radiance method, removing the need to calibrate the individual subcomponents, as required by ART, and thereby reducing uncertainties. In addition, the calibration approach has been improved through a new integrating sphere that has been designed to have greater uniformity.

  1. Development of a new radiometer for the thermodynamic measurement of high temperature fixed points

    SciTech Connect

    Dury, M. R.; Goodman, T. M.; Lowe, D. H.; Machin, G.; Woolliams, E. R.

    2013-09-11

    The National Physical Laboratory (NPL) has developed a new radiometer to measure the thermodynamic melting point temperatures of high temperature fixed points with ultra-low uncertainties. In comparison with the NPL's Absolute Radiation Thermometer (ART), the 'THermodynamic Optical Radiometer' (THOR) is more portable and compact, with a much lower size-of-source effect and improved performance in other parameters such as temperature sensitivity. It has been designed for calibration as a whole instrument via the radiance method, removing the need to calibrate the individual subcomponents, as required by ART, and thereby reducing uncertainties. In addition, the calibration approach has been improved through a new integrating sphere that has been designed to have greater uniformity.

  2. Improvements in the realization of the ITS-90 over the temperature range from the melting point of gallium to the freezing point of silver at NIM

    NASA Astrophysics Data System (ADS)

    Sun, J.; Zhang, J. T.; Ping, Q.

    2013-09-01

    The temperature primary standard over the range from the melting point of gallium to the freezing point of silver in National institute of Metrology (NIM), China, was established in the early 1990s. The performance of all of fixed-point furnaces degraded and needs to be updated due to many years of use. Nowadays, the satisfactory fixed point materials can be available with the development of the modern purification techniques. NIM plans to use a group of three cells for each defining fixed point temperature. In this way the eventual drift of individual cells can be evidenced by periodic intercomparison and this will increase the reliability in disseminating the ITS-90 in China. This article describes the recent improvements in realization of ITS-90 over temperature range from the melting point of gallium to the freezing point of silver at NIM. Taking advantages of the technological advances in the design and manufacture of furnaces, the new three-zone furnaces and the open-type fixed points were developed from the freezing point of indium to the freezing point of silver, and a furnace with the three-zone semiconductor cooling was designed to automatically realize the melting point of gallium. The reproducibility of the new melting point of gallium and the new open-type freezing points of In, Sn, Zn. Al and Ag is improved, especially the freezing points of Al and Ag with the reproducibility of 0.2mK and 0.5mK respectively. The expanded uncertainty in the realization of these defining fixed point temperatures is 0.34mK, 0.44mK, 0.54mK, 0.60mK, 1.30mK and 1.88mK respectively.

  3. Improvements in the realization of the ITS-90 over the temperature range from the melting point of gallium to the freezing point of silver at NIM

    SciTech Connect

    Sun, J.; Zhang, J. T.; Ping, Q.

    2013-09-11

    The temperature primary standard over the range from the melting point of gallium to the freezing point of silver in National institute of Metrology (NIM), China, was established in the early 1990s. The performance of all of fixed-point furnaces degraded and needs to be updated due to many years of use. Nowadays, the satisfactory fixed point materials can be available with the development of the modern purification techniques. NIM plans to use a group of three cells for each defining fixed point temperature. In this way the eventual drift of individual cells can be evidenced by periodic intercomparison and this will increase the reliability in disseminating the ITS-90 in China. This article describes the recent improvements in realization of ITS-90 over temperature range from the melting point of gallium to the freezing point of silver at NIM. Taking advantages of the technological advances in the design and manufacture of furnaces, the new three-zone furnaces and the open-type fixed points were developed from the freezing point of indium to the freezing point of silver, and a furnace with the three-zone semiconductor cooling was designed to automatically realize the melting point of gallium. The reproducibility of the new melting point of gallium and the new open-type freezing points of In, Sn, Zn. Al and Ag is improved, especially the freezing points of Al and Ag with the reproducibility of 0.2mK and 0.5mK respectively. The expanded uncertainty in the realization of these defining fixed point temperatures is 0.34mK, 0.44mK, 0.54mK, 0.60mK, 1.30mK and 1.88mK respectively.

  4. Optimization of the thermogauge furnace for realizing high temperature fixed points

    SciTech Connect

    Wang, T.; Dong, W.; Liu, F.

    2013-09-11

    The thermogauge furnace was commonly used in many NMIs as a blackbody source for calibration of the radiation thermometer. It can also be used for realizing the high temperature fixed point(HTFP). According to our experience, when realizing HTFP we need the furnace provide relative good temperature uniformity to avoid the possible damage to the HTFP. To improve temperature uniformity in the furnace, the furnace tube was machined near the tube ends with a help of a simulation analysis by 'ansys workbench'. Temperature distributions before and after optimization were measured and compared at 1300 °C, 1700°C, 2500 °C, which roughly correspond to Co-C(1324 °C), Pt-C(1738 °C) and Re-C(2474 °C), respectively. The results clearly indicate that through machining the tube the temperature uniformity of the Thermogage furnace can be remarkably improved. A Pt-C high temperature fixed point was realized in the modified Thermogauge furnace subsequently, the plateaus were compared with what obtained using old heater, and the results were presented in this paper.

  5. Liquid Oxygen Liquid Acquisition Device Bubble Point Tests with High Pressure LOX at Elevated Temperatures

    NASA Technical Reports Server (NTRS)

    Jurns, John M.; Hartwig, Jason W.

    2011-01-01

    When transferring propellant in space, it is most efficient to transfer single phase liquid from a propellant tank to an engine. In earth s gravity field or under acceleration, propellant transfer is fairly simple. However, in low gravity, withdrawing single-phase fluid becomes a challenge. A variety of propellant management devices (PMD) are used to ensure single-phase flow. One type of PMD, a liquid acquisition device (LAD) takes advantage of capillary flow and surface tension to acquire liquid. The present work reports on testing with liquid oxygen (LOX) at elevated pressures (and thus temperatures) (maximum pressure 1724 kPa and maximum temperature 122K) as part of NASA s continuing cryogenic LAD development program. These tests evaluate LAD performance for LOX stored in higher pressure vessels that may be used in propellant systems using pressure fed engines. Test data shows a significant drop in LAD bubble point values at higher liquid temperatures, consistent with lower liquid surface tension at those temperatures. Test data also indicates that there are no first order effects of helium solubility in LOX on LAD bubble point prediction. Test results here extend the range of data for LOX fluid conditions, and provide insight into factors affecting predicting LAD bubble point pressures.

  6. Boiling incipience and convective boiling of neon and nitrogen

    NASA Technical Reports Server (NTRS)

    Papell, S. S.; Hendricks, R. C.

    1977-01-01

    Forced convection and subcooled boiling heat transfer data for liquid nitrogen and liquid neon were obtained in support of a design study for a 30 tesla cryomagnet cooled by forced convection of liquid neon. The cryogen data obtained over a range of system pressures, fluid flow rates, and applied heat fluxes were used to develop correlations for predicting boiling incipience and convective boiling heat transfer coefficients in uniformly heated flow channels. The accuracy of the correlating equations was then evaluated. A technique was also developed to calculate the position of boiling incipience in a uniformly heated flow channel. Comparisons made with the experimental data showed a prediction accuracy of + or - 15 percent.

  7. Measurement of the in freezing-point temperature: Effect of the liquid-solid interface structure

    NASA Astrophysics Data System (ADS)

    Ivanova, A. G.; Abasov, M. Yu.; Gerasimov, S. F.; Pokhodun, A. I.

    2013-09-01

    The results of the experimental study of the inner interface formation process under different conditions of its initiation for the indium freezing point showed that, depending on the initiation intensity, both the planar structure of the interface on the thermometer well and a noticeable intergrowth of dendrites could be obtained. However, under some specific initiation conditions dendrites disappeared partly or completely in the process of crystallization. The value of the indium freezing point temperature was measured under realization conditions corresponding to different inner interface structure.

  8. Point-of-care temperature and respiration monitoring sensors for smart fabric applications

    NASA Astrophysics Data System (ADS)

    Jung, Soyoun; Ji, Taeksoo; Varadan, Vijay K.

    2006-12-01

    Advances in smart sensors, miniaturization, and related technologies leading to the emergence of smart fabrics are prerequisites to the construction of a point-of-care (POC) system for continuous health monitoring and illness prevention. Low manufacturing cost, light weight, portability and flexibility are among the requirements for smart sensors when embedded into smart fabrics. Organic semiconductor technology has recently been envisioned to meet these requirements, and to encourage the development of organic semiconductor based sensors because of its low process temperature and potential for very low cost manufacturing. In this paper, we present flexible sensors based on an organic semiconductor capable of measuring physiological parameters such as strain and temperature, adopting pentacene thin film transistors (TFTs) and Wheatstone bridge structures. It is expected that these sensors, integrated into textile structures, will enable real time POC monitoring of a patient's respiration rate, skin temperature, body heat flow and body temperature at an early stage.

  9. Dynamic Performance of Maximum Power Point Trackers in TEG Systems Under Rapidly Changing Temperature Conditions

    NASA Astrophysics Data System (ADS)

    Man, E. A.; Sera, D.; Mathe, L.; Schaltz, E.; Rosendahl, L.

    2015-09-01

    Characterization of thermoelectric generators (TEG) is widely discussed and equipment has been built that can perform such analysis. One method is often used to perform such characterization: constant temperature with variable thermal power input. Maximum power point tracking (MPPT) methods for TEG systems are mostly tested under steady-state conditions for different constant input temperatures. However, for most TEG applications, the input temperature gradient changes, exposing the MPPT to variable tracking conditions. An example is the exhaust pipe on hybrid vehicles, for which, because of the intermittent operation of the internal combustion engine, the TEG and its MPPT controller are exposed to a cyclic temperature profile. Furthermore, there are no guidelines on how fast the MPPT must be under such dynamic conditions. In the work discussed in this paper, temperature gradients for TEG integrated in several applications were evaluated; the results showed temperature variation up to 5°C/s for TEG systems. Electrical characterization of a calcium-manganese oxide TEG was performed at steady-state for different input temperatures and a maximum temperature of 401°C. By using electrical data from characterization of the oxide module, a solar array simulator was emulated to perform as a TEG. A trapezoidal temperature profile with different gradients was used on the TEG simulator to evaluate the dynamic MPPT efficiency. It is known that the perturb and observe (P&O) algorithm may have difficulty accurately tracking under rapidly changing conditions. To solve this problem, a compromise must be found between the magnitude of the increment and the sampling frequency of the control algorithm. The standard P&O performance was evaluated experimentally by using different temperature gradients for different MPPT sampling frequencies, and efficiency values are provided for all cases. The results showed that a tracking speed of 2.5 Hz can be successfully implemented on a TEG system to provide ˜95% MPPT efficiency when the input temperature is changing at 5°C/s.

  10. Dynamic Performance of Maximum Power Point Trackers in TEG Systems Under Rapidly Changing Temperature Conditions

    NASA Astrophysics Data System (ADS)

    Man, E. A.; Sera, D.; Mathe, L.; Schaltz, E.; Rosendahl, L.

    2016-03-01

    Characterization of thermoelectric generators (TEG) is widely discussed and equipment has been built that can perform such analysis. One method is often used to perform such characterization: constant temperature with variable thermal power input. Maximum power point tracking (MPPT) methods for TEG systems are mostly tested under steady-state conditions for different constant input temperatures. However, for most TEG applications, the input temperature gradient changes, exposing the MPPT to variable tracking conditions. An example is the exhaust pipe on hybrid vehicles, for which, because of the intermittent operation of the internal combustion engine, the TEG and its MPPT controller are exposed to a cyclic temperature profile. Furthermore, there are no guidelines on how fast the MPPT must be under such dynamic conditions. In the work discussed in this paper, temperature gradients for TEG integrated in several applications were evaluated; the results showed temperature variation up to 5°C/s for TEG systems. Electrical characterization of a calcium-manganese oxide TEG was performed at steady-state for different input temperatures and a maximum temperature of 401°C. By using electrical data from characterization of the oxide module, a solar array simulator was emulated to perform as a TEG. A trapezoidal temperature profile with different gradients was used on the TEG simulator to evaluate the dynamic MPPT efficiency. It is known that the perturb and observe (P&O) algorithm may have difficulty accurately tracking under rapidly changing conditions. To solve this problem, a compromise must be found between the magnitude of the increment and the sampling frequency of the control algorithm. The standard P&O performance was evaluated experimentally by using different temperature gradients for different MPPT sampling frequencies, and efficiency values are provided for all cases. The results showed that a tracking speed of 2.5 Hz can be successfully implemented on a TEG system to provide ˜95% MPPT efficiency when the input temperature is changing at 5°C/s.

  11. Cryogenic Boil-Off Reduction System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, David W.; Johnson, Wesley L.; Feller, Jeffrey R.

    2014-01-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration due to the high specific impulse that can be achieved using engines suitable for moving 10's to 100's of metric tons of payload mass to destinations outside of low earth orbit. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for missions with durations greater than several days. The losses can be greatly reduced by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and by the integration of self-supporting multi-layer insulation. The active thermal control technology under development is the integration of the reverse turbo- Brayton cycle cryocooler to the propellant tank through a distributed cooling network of tubes coupled to a shield in the tank insulation and to the tank wall itself. Also, the self-supporting insulation technology was utilized under the shield to obtain needed tank applied LH2 performance. These elements were recently tested at NASA Glenn Research Center in a series of three tests, two that reduced LH2 boil-off and one to eliminate LO2 boil-off. This test series was conducted in a vacuum chamber that replicated the vacuum of space and the temperatures of low Earth orbit. The test results show that LH2 boil-off was reduced 60% by the cryocooler system operating at 90K and that robust LO2 zero boil-off storage, including full tank pressure control was achieved.

  12. Determining the structural phase transition point from the temperature of 40Ca+ Coulomb crystal

    NASA Astrophysics Data System (ADS)

    Chen, Ting; Du, Li-Jun; Song, Hong-Fang; Liu, Pei-Liang; Huang, Yao; Tong, Xin; Guan, Hua; Gao, Ke-Lin

    2014-12-01

    We observed the linear-to-zigzag structural phase transition of a 40Ca+ crystal in a homemade linear Paul trap. The values of the total temperature of the ion crystals during the phase transition are derived using the molecular-dynamics (MD) simulation method. A series of simulations revealed that the ratio of the radial to axial secular frequencies has a dependence on the total temperature that obeys different functional forms for linear and zigzag structures, and the transition point occurs where these functions intersect; thus, the critical value of the ratio of secular frequencies that drives the structure phase transition can be derived.

  13. Room Temperature Bubble Point Tests on Porous Screens: Implications for Cryogenic Liquid Acquisition Devices

    NASA Technical Reports Server (NTRS)

    Hartwig, Jason; Mann, J. Adin, Jr.

    2012-01-01

    We present experimental results for room temperature bubble point tests conducted at the Cedar Creek Road Cryogenic Complex, Cell 7 (CCL-7) at the NASA Glenn Research Center. The purpose of these tests was to investigate the performance of three different fine mesh screens in room temperature liquids to provide pretest predictions in cryogenic liquid nitrogen (LN2) and hydrogen (LH2) as part of NASA's microgravity LAD technology development program. Bench type tests based on the maximum bubble point method were conducted for a 325 x 2300, 450 x 2750, and 510 x 3600 mesh sample in pure room temperature liquid methanol, acetone, isopropyl alcohol, water, and mixtures of methanol and water to cover the intermediate to upper surface tension range. A theoretical model for the bubble point pressure is derived from the Young-LaPlace equation for the pressure drop across a curved interface. Governing equations are reduced in complexity through a set of simplifying assumptions to permit direct comparison with the experimental data. Screen pore sizes are estimated from scanning electron microscopy (SEM) to make pretest predictions. Pore sizes based on SEM analysis are compared with historical data available in the literature for the 325 x 2300 and 450 x 2750 screens as well with data obtained from bubble point tests conducted in this work. Experimental results show that bubble point pressure is proportional to the surface tension of the liquid. We show that there is excellent agreement between data and model for pure fluids when the data is corrected for non-zero contact angle measured on the screens using a modified Sessile Drop technique. SEM image analysis of the three meshes indicated that bubble point pressure would be a maximum for the finest mesh screen. The pore diameters based on SEM analysis and experimental data obtained here are in excellent agreement for the 325 x 2300 and 450 x 2750 meshes, but not for the finest 510 x 3600 mesh. Therefore the simplified model can be used to interpolate predictions for low surface tension cryogenic liquids only when pore diameters are based on room temperature bubble point tests and not SEM analysis as presently implemented.

  14. Cryogenic Propellant Boil-Off Reduction System

    NASA Astrophysics Data System (ADS)

    Plachta, D. W.; Christie, R. J.; Carlberg, E.; Feller, J. R.

    2008-03-01

    Lunar missions under consideration would benefit from incorporation of high specific impulse propellants such as LH2 and LO2, even with their accompanying boil-off losses necessary to maintain a steady tank pressure. This paper addresses a cryogenic propellant boil-off reduction system to minimize or eliminate boil-off. Concepts to do so were considered under the In-Space Cryogenic Propellant Depot Project. Specific to that was an investigation of cryocooler integration concepts for relatively large depot sized propellant tanks. One concept proved promisingit served to efficiently move heat to the cryocooler even over long distances via a compressed helium loop. The analyses and designs for this were incorporated into NASA Glenn Research Center's Cryogenic Analysis Tool. That design approach is explained and shown herein. Analysis shows that, when compared to passive only cryogenic storage, the boil-off reduction system begins to reduce system mass if durations are as low as 40 days for LH2, and 14 days for LO2. In addition, a method of cooling LH2 tanks is presented that precludes development issues associated with LH2 temperature cryocoolers.

  15. Relationship Between Ice Nucleation Temperature Depression and Equilibrium Melting Points Depression of Medaka (Oryzias latipes) Embryos

    NASA Astrophysics Data System (ADS)

    Kimizuka, Norihito; Suzuki, Toru

    We measured the ice nucleation temperature depression , ?Tf , and equilibrium melting points depression, ?Tm, of Medaka (Oryzias latipes) embryos with different cryoprotectant (ethylene glycol, 1.3-propanediol, 1.4-butanediol, glycerol aqueous solutions) treatments. Our obtained results showed the good relationship between the ?Tf ,and ?Tm all samples. In addition the value of ? , which can be obtained from the linear relationship, ?Tf =? ?Tm, were confirmed to show correlation with the value of ? , as obtained by the W/O emulsion method.

  16. How Does Water Boil?

    NASA Astrophysics Data System (ADS)

    Zahn, Dirk

    2004-11-01

    Insight into the boiling of water is obtained from molecular dynamics simulations. The process is initiated by the spontaneous formation of small vacuum cavities in liquid water. By themselves, these defects are very short lived. If, however, several cavities occur at close distances, they are likely to merge into larger vacuum holes. At the liquid-vapor interfaces, single or small groups of water molecules tend to leave the liquid surface. Once the system is propagated beyond the transition state, these evaporation events outnumber the competing reintegration into the hydrogen-bonded network.

  17. Triple point temperature of neon isotopes: Dependence on nitrogen impurity and sealed-cell model

    SciTech Connect

    Pavese, F.; Steur, P. P. M.; Giraudi, D.

    2013-09-11

    This paper illustrates a study conducted at INRIM, to further check how some quantities influence the value of the triple point temperature of the neon high-purity isotopes {sup 20}Ne and {sup 22}Ne. The influence of nitrogen as a chemical impurity in neon is critical with regard to the present best total uncertainty achieved in the measurement of these triple points, but only one determination is available in the literature. Checks are reported, performed on two different samples of {sup 22}Ne known to contain a N{sub 2} amount of 157?10{sup ?6}, using two different models of sealed cells. The model of the cell can, in principle, have some effects on the shape of the melting plateau or on the triple point temperature observed for the sample sealed in it. This can be due to cell thermal parameters, or because the INRIM cell element mod. c contains many copper wires closely packed, which can, in principle, constrain the interface and induce a premelting-like effect. The reported results on a cell mod. Bter show no evident effect from the cell model and provide a value for the effect of N{sub 2} in Ne liquidus point of 8.6(1.9) ?K ppm N{sub 2}{sup ?1}, only slightly different from the literature datum.

  18. Comparison of the triple-point temperatures of 20Ne, 22Ne and normal Ne

    NASA Astrophysics Data System (ADS)

    Nakano, T.; Tamura, O.; Nagao, K.

    2013-09-01

    At the National Metrology Institute of Japan (NMIJ), the triple points of 20Ne and 22Ne were realized using modular sealed cells, Ec3Ne20 and Ec8Ne22, made by the Istituto Nazionale di Ricerca Metrologica (INRiM) in Italy. The difference of the triple-point temperatures of 20Ne and 22Ne was estimated by using the sub-range of standard platinum resistance thermometers (SPRTs) calibrated by NMIJ on the International Temperature Scale of 1990 (ITS-90). The melting curves obtained with the Ec3Ne20 and Ec8Ne22 cells show narrow widths (0.1 mK) over a wide range of the inverse of the melted fraction (1/F) from 1/F=1 to 1/F=10. The liquidus point Ttp estimated by the melting curves from F0.5 to F0.85 using the Ec8Ne22 is 0.146 29 (4) K higher than that using the Ec3Ne20 cell, which is in good agreement with that observed by INRiM using the same cells. After correction of the effect of impurities and other isotopes for Ec3Ne20 and Ec8Ne22 cells, the difference of Ttp between pure 20Ne and pure 22Ne is estimated to be 0.146 61 (4) K, which is consistent with the recent results reported elsewhere. The sub-ranges of SPRTs computed by using the triple point of 20Ne or 22Ne realized by the Ec3Ne20 cell or the Ec8Ne22 cell in place of the triple point of Ne for the defining fixed point of the ITS-90 are in good agreement with those realized on the basis of the ITS-90 at NMIJ within 0.03 mK, which is much smaller than the non-uniqueness and the sub-range inconsistency of SPRTs.

  19. POINT 2011: ENDF/B-VII.1 Beta2 Temperature Dependent Cross Section Library

    SciTech Connect

    Cullen, D E

    2011-04-07

    This report is one in the series of 'POINT' reports that over the years have presented temperature dependent cross sections for the then current version of ENDF/B. In each case I have used my personal computer at home and publicly available data and codes. I have used these in combination to produce the temperature dependent cross sections used in applications and presented in this report. I should mention that today anyone with a personal computer can produce these results. The latest ENDF/B-VII.1 beta2 data library was recently and is now freely available through the National Nuclear Data Center (NNDC), Brookhaven National Laboratory. This release completely supersedes all preceding releases of ENDF/B. As distributed the ENDF/B-VII.1 data includes cross sections represented in the form of a combination of resonance parameters and/or tabulated energy dependent cross sections, nominally at 0 Kelvin temperature. For use in our applications the ENDF/B-VII.1 library has been processed into cross sections at eight neutron reactor like temperatures, between 0 and 2100 Kelvin, in steps of 300 Kelvin (the exception being 293.6 Kelvin, for exact room temperature at 20 Celsius). It has also been processed to five astrophysics like temperatures, 1, 10, 100 eV, 1 and 10 keV. For reference purposes, 300 Kelvin is approximately 1/40 eV, so that 1 eV is approximately 12,000 Kelvin. At each temperature the cross sections are tabulated and linearly interpolable in energy. All results are in the computer independent ENDF-6 character format [R2], which allows the data to be easily transported between computers. In its processed form the POINT 2011 library is approximately 16 gigabyte in size and is distributed on one compressed DVDs (see, below for the details of the contents of each DVD).

  20. Enhanced Droplet Control by Transition Boiling

    PubMed Central

    Grounds, Alex; Still, Richard; Takashina, Kei

    2012-01-01

    A droplet of water on a heated surface can levitate over a film of gas produced by its own evaporation in the Leidenfrost effect. When the surface is prepared with ratchet-like saw-teeth topography, these droplets can self-propel and can even climb uphill. However, the extent to which the droplets can be controlled is limited by the physics of the Leidenfrost effect. Here, we show that transition boiling can be induced even at very high surface temperatures and provide additional control over the droplets. Ratchets with acute protrusions enable droplets to climb steeper inclines while ratchets with sub-structures enable their direction of motion to be controlled by varying the temperature of the surface. The droplets' departure from the Leidenfrost regime is assessed by analysing the sound produced by their boiling. We anticipate these techniques will enable the development of more sophisticated methods for controlling small droplets and heat transfer. PMID:23056912

  1. Wall sticking of high water-cut crude oil transported at temperatures below the gel point

    NASA Astrophysics Data System (ADS)

    Zheng, Haimin; Huang, Qiyu; Wang, Changhui

    2015-12-01

    Some high water-cut crude oils can flow in the temperature below the oil gel point, while oil particles may adhere to the pipe wall as paste; this process is known as wall sticking. This can cause partial or even total blocking of the transportation pipe. Several experiments using a laboratory flow loop were conducted to study the wall sticking characteristics of high water-cut crude oils. The experimental results indicated that the predominant influencing factors of wall sticking included shear stress, water-cut and differences between gel point and wall temperature. The wall sticking rate and occurrence temperature decrease with the increase of water-cut and shear stress. The criterion for the wall sticking occurrence temperature (WSOT), and the regression formula of the wall sticking thickness for high water-cut crude oil were then established. Typical case studies indicated that the prediction results obtained from the WSOT criterion and the wall sticking thickness regression formula were in accordance with the measured values. The wall sticking rate and WSOT vary widely under different conditions and it is necessary to consider its non-uniformity in production.

  2. Evaluation of local temperature around the impact points of fast ions

    NASA Astrophysics Data System (ADS)

    Hayashi, H.; Kitayama, T.; Matsuzaki, S.; Nakajima, K.; Narumi, K.; Saitoh, Y.; Tsujimoto, M.; Toulemonde, M.; Kimura, K.

    2015-12-01

    Gold and platinum nanoparticles of few-nm size were deposited on amorphous silicon nitride (a-SiN) films. These samples were irradiated with 1.1 MeV C603+ ions to a fluence of ?5 1010 ions/cm2 and observed using transmission electron microscopy (TEM). The ion tracks were clearly seen as bright spots and the metal nanoparticles disappeared from a neighboring region (5-10 nm) around each ion track. The platinum-nanoparticle-cleared region is slightly smaller than that of gold nanoparticles. This trend can be reproduced by the u-TS calculations assuming that the nanoparticles are desorbed when the local temperature surpasses the melting point of nanoparticles as was predicted by molecular dynamics simulations (Anders et al., 2009). This indicates that the temperature distribution in a nanometer region can be evaluated by observing the desorption of nanoparticles of different metals having different melting temperatures.

  3. Rotational and vibrational temperatures in a hydrogen discharge with a magnetic X-point

    SciTech Connect

    Tsankov, Tsanko V.; Czarnetzki, Uwe; Toko, Kaoru

    2012-12-15

    A novel plasma source with a magnetic X-point has been developed to probe an alternative for cesium-free negative hydrogen ion production. This study presents first results for the gas and vibrational temperatures in the source at 1 Pa and various RF powers. The temperatures are obtained from analysis of the intensity distribution of the molecular Fulcher-{alpha} bands. The gas temperature increases with the RF power, while the vibrational temperature remains constant in the studied range of RF powers. Both quantities show no appreciable spatial dependence. The obtained high values of the vibrational temperatures indicate a high population of the vibrational levels, favourable for the volume negative ion production. A theoretical concept indicates the presence of an optimum value for the vibrational temperature at which the negative hydrogen ion yield by volume processes has a maximum. Coincidently, the measured value is close to this optimum. This indicates that the novel concept can provide certain advantages compared to other sources based on volume production.

  4. Fundamental Boiling and RP-1 Freezing Experiments

    NASA Technical Reports Server (NTRS)

    Goode, Brian; Turner, Larry D. (Technical Monitor)

    2001-01-01

    This paper describes results from experiments performed to help understand certain aspects of the MC-1 engine prestart thermal conditioning procedure. The procedure was constrained by the fact that the engine must chill long enough to get quality LOX at the LOX pump inlet but must be short enough to prevent freezing of RP-1 in the fuel pump. A chill test of an MC-1 LOX impeller was performed in LN2 to obtain data on film boiling, transition boiling and impeller temperature histories. The transition boiling data was important to the chill time so a subsequent experiment was performed chilling simple steel plates in LOX to obtain similar data for LOX. To address the fuel freezing concern, two experiments were performed. First, fuel was frozen in a tray and its physical characteristics were observed and temperatures of the fuel were measured. The result was physical characteristics as a function of temperature. Second was an attempt to measure the frozen thickness of RP-1 on a cold wall submerged in warm RP-1 and to develop a method for calculating that thickness for other conditions.

  5. Triops (Entomostraca) eggs killed only by boiling.

    PubMed

    Carlisle, D B

    1968-07-19

    Temporary rainpools near Khartoum, Sudan, are inhabited by the notostracan crustacean Triops which completes its life cycle within 4 weeks. The annual rains fall in late summer, and throughout the winter and early summer the eggs of Triops remain in the dried mud or dust where they may be exposed to temperatures up to 80 degrees C. Laboratory experiments show that they can withstand temperatures up to within 1 degrees C of boiling, but are killed in partial vacuum by 70 degrees C, at atmospheric pressure by 100 degrees C, or under pressure by 105 degrees C. Exposure to high temperature seems to be necessary to break the egg diapause. PMID:5690518

  6. Computations of Boiling in Microgravity

    NASA Technical Reports Server (NTRS)

    Tryggvason, G.; Jacqmin, Dave

    2000-01-01

    The absence (or reduction) of gravity, can lead to major changes in boiling heat transfer. On Earth, convection has a major effect on the heat distribution ahead of an evaporation front, and buoyancy determines the motion of the growing bubbles. In microgravity, convection and buoyancy are absent or greatly reduced and the dynamics of the growing vapor bubbles can change in a fundamental way. In particular, the lack of redistribution of heat can lead to a large superheat and explosive growth of bubbles once they form. While considerable efforts have been devoted to examining boiling experimentally, including the effect of microgravity, theoretical and computational work have been limited. Here, the growth of boiling bubbles is studied by direct numerical simulations where the flow field is fully resolved and the effects of inertia, viscosity, surface deformation, heat conduction and convection, as well as the phase change, are fully accounted for. Boiling involves both fluid flow and heat transfer and thus requires the solution of the Navier-Stokes and the energy equations. The numerical method is based on writing one set of governing transport equations which is valid in both the liquid and vapor phases. This local, single-field formulation incorporates the effect of the interface in the governing equations as source terms acting only at the interface. These sources account for surface tension and latent heat in the equations for conservation of momentum and energy as well as mass transfer across the interface due to phase change. The single-field formulation naturally incorporates the correct mass, momentum and energy balances across the interface. Integration of the conservation equations across the interface directly yields the jump conditions derived in the local instant formulation for two-phase systems. In the numerical implementation, the conservation equations for the whole computational domain (both vapor and liquid) are solved using a stationary grid and the phase boundary is followed by a moving unstructured two-dimensional grid. While two-dimensional simulations have been used for preliminary studies and to examine the resolution requirement, the focus is on fully three-dimensional simulations. The numerical methodology, including the parallelization and grid refinement strategy is discussed, and preliminary results shown. For buoyancy driven flow, the heat transfer is in good agreement with experimental correlations. The changes when gravity is turned off and/or fluid shear is added are discussed, as well as the difference between simulations of a layer freely releasing bubbles versus simulations using only one wavelength initial perturbation. Figure 1 shows the early stages of the formation of a three-dimensional bubble from a thin vapor layer. The boundary conditions are periodic in the x and y direction, the bottom is a hot and the top allows a free outflow. The jagged edge of the surface close to the bottom of the computational domain is due to some of the surface elements being on the other side of the domain and some elements not plotted by our plotting routine. In the second figure, we show the temperature distribution through two perpendicular planes.

  7. Acoustic measurements of the thermodynamic temperature between the triple point of mercury and 380 K

    NASA Astrophysics Data System (ADS)

    Benedetto, G.; Gavioso, R. M.; Spagnolo, R.; Marcarino, P.; Merlone, A.

    2004-02-01

    We have measured the differences between the Kelvin thermodynamic temperature and the temperature of the International Temperature Scale of 1990 on nine isotherms between the triple point of mercury and 380 K, by means of a primary acoustic thermometer. For the present measurements the standard uncertainty of (T - T90) ranges from 0.9 mK at 234 K to 1.7 mK at 380 K. The experimental method is based on the measurement of the acoustic resonance frequencies of an argon-filled spherical cavity and the microwave resonance frequencies of the same cavity when evacuated. The present results agree within the remarkably small combined uncertainties with both NIST acoustic thermometry ([1] Moldover M R et al 1999 J. Res. Natl Inst. Stand. Technol. 104 11-46 [2] Strouse G F et al 2002 Progress in primary acoustic thermometry at NIST: 273 K to 505 K 8th Temperature Symp. (Chicago, 21-24 October 2002)) and UCL acoustic thermometry ([3] Ewing M B and Trusler J P M 2000 J. Chem. Thermodyn. 32 1229-55) in the overlapping temperature range.

  8. Estimation of the temperature dependent interaction between uncharged point defects in Si

    SciTech Connect

    Kamiyama, Eiji; Vanhellemont, Jan; Sueoka, Koji

    2015-01-15

    A method is described to estimate the temperature dependent interaction between two uncharged point defects in Si based on DFT calculations. As an illustration, the formation of the uncharged di-vacancy V{sub 2} is discussed, based on the temperature dependent attractive field between both vacancies. For that purpose, all irreducible configurations of two uncharged vacancies are determined, each with their weight given by the number of equivalent configurations. Using a standard 216-atoms supercell, nineteen irreducible configurations of two vacancies are obtained. The binding energies of all these configurations are calculated. Each vacancy is surrounded by several attractive sites for another vacancy. The obtained temperature dependent of total volume of these attractive sites has a radius that is closely related with the capture radius for the formation of a di-vacancy that is used in continuum theory. The presented methodology can in principle also be applied to estimate the capture radius for pair formation of any type of point defects.

  9. Triple-Point Temperature and the Isotopic Composition of Three Commercial Neon Gases

    NASA Astrophysics Data System (ADS)

    Yang, I.; Gam, K. S.; Joung, W.; Kim, Y.-G.

    2015-08-01

    The triple-point temperature of neon, , is known to have dependence on the isotopic composition. Recently, the Technical Annex for the International Temperature Scale of 1990 was updated to specify the method of correction for the isotopic reference ratio of neon. In this study, to confirm this correction in the Technical Annex independently, the effects of the isotopic composition of neon on for three commercial neon gas sources were studied. For the measurement of the isotopic composition, a gas mass spectrometer was used to compare the sample gases with a reference neon gas whose isotopic composition was known with high precision by a gravimetric method. For the measurement of , an open-cell type cryostat for the realization of low-temperature fixed points was used. The physical cell and the thermal environment around it remained very similar for all measurements with the neon gases due to the nature of the open-cell type system. Therefore, the difference in among different samples could be measured with a relatively low uncertainty, canceling many systematic effects that are common to all measurements. Our result was consistent with the correction in the Technical Annex. Furthermore, because one of the commercial neon gases was the bottle that was used for KRISS measurements in the international comparison CCT-K2, it is now possible to correct the measurement for the reference isotopic ratio and compare it with other measurements for which isotopic composition data are available.

  10. Localized saddle-point search and application to temperature-accelerated dynamics

    SciTech Connect

    Shim, Yunsic; Amar, Jacques G.; Callahan, Nathan B.

    2013-03-07

    We present a method for speeding up temperature-accelerated dynamics (TAD) simulations by carrying out a localized saddle-point (LSAD) search. In this method, instead of using the entire system to determine the energy barriers of activated processes, the calculation is localized by only including a small chunk of atoms around the atoms directly involved in the transition. Using this method, we have obtained N-independent scaling for the computational cost of the saddle-point search as a function of system size N. The error arising from localization is analyzed using a variety of model systems, including a variety of activated processes on Ag(100) and Cu(100) surfaces, as well as multiatom moves in Cu radiation damage and metal heteroepitaxial growth. Our results show significantly improved performance of TAD with the LSAD method, for the case of Ag/Ag(100) annealing and Cu/Cu(100) growth, while maintaining a negligibly small error in energy barriers.

  11. Pressure dependence of the critical temperature of microemulsions near a critical end point

    NASA Astrophysics Data System (ADS)

    Goyette, J.; Bose, T. K.; Thoen, J.; Lalanne, J. R.

    1989-10-01

    Experimental data for the pressure dependence of the critical temperature (dTc/dP) are reported for several microemulsions of n-dodecane, water, n-pentanol, and sodium dodecylsulfate, with critical points along a critical line ending at a critical end point (CEP). Negative dTc/dP values, substantially decreasing near the CEP, are obtained for all the microemulsions investigated. Using two-scale-factor universality and combining dTc/dP with correlation-length critical-amplitude ?0 values, we also find that a density anomaly is very likely unobservable experimentally. From the negative sign of dTc/dP it can also be concluded that if there is any critical contribution of the density anomaly to the refractive index n, it must be opposite to the anomaly recently reported for n by Rebbouh and Lalanne [J. Chem. Phys. 90, 1175 (1989)].

  12. Measurements of Convection Heat Transfer Coefficients for Hydrocarbon Mixtures during Boiling in a Heated Horizontal Pipe from 100 K to Room Temperature

    NASA Astrophysics Data System (ADS)

    Barraza, Rodrigo; Nellis, Gregory; Klein, Sanford; Reindl, Douglas

    There is a scarcity of data and theory currently available regarding the heat transfer coefficients associated with two-phase, multi-component mixtures at cryogenic temperatures. This paper presents results of research aimed at measuring theconvection heat transfer coefficients for hydrocarbon mixtures (methane, ethane, propane, and nitrogen (for dilution)) during evaporation while flowing within a heated horizontal pipe over a wide range of temperatures (from 100 K to room temperature). The results show the heat transfer coefficients along with their sensitivity to parameters such as heat flux, mass flux, pressure, and composition.

  13. Multi-point abnormal-temperature warning sensor system with different thresholds

    NASA Astrophysics Data System (ADS)

    Sun, Q.; Liu, D.; Wang, J.; Liu, H.; Xia, L.; Shum, P.

    2009-09-01

    We propose and experimentally demonstrate a time-division-multiplexing-based (TDM-based) multi-point abnormal-temperature warning sensor system with different thresholds. A multi-channel fiber Bragg grating (FBG) serving as the wavelength selector is employed in the fiber ring laser to generate a multi-wavelength pulsed light source. The sensor array is composed of multiple uniform sensing FBGs at different positions and with different nominal wavelengths. The warning signal is obtained by only monitoring the time slot between the injected pulse and the reflected pulse. The measurement range and resolution are theoretically discussed and experimentally demonstrated.

  14. Temperature evolution of subharmonic gap structures in MgB 2/Nb point-contacts

    NASA Astrophysics Data System (ADS)

    Giubileo, F.; Bobba, F.; Scarfato, A.; Piano, S.; Aprili, M.; Cucolo, A. M.

    2007-09-01

    We have performed point-contact spectroscopy experiments on superconducting micro-constrictions between Nb tips and high quality MgB2 pellets. We measured the temperature evolution (between 4.2 K and 300 K) of the current-voltage (I-V) and of the dynamical conductance (dI/dV-V) characteristics. Above the Nb critical temperature TCNb , the conductance of the constrictions behaves as predicted by the BTK model for S/N contacts being Nb in its normal state below TCNb , the contacts show Josephson current and subharmonic gap structures, due to multiple Andreev reflections. These observations clearly indicate the coupling of the MgB2 3D ?-band with the Nb superconducting order parameter. We found ?? = 2.4 0.2 meV for the three-dimensional gap of MgB2.

  15. Effects of temperature variation among droplets in an evaporating fuel spray

    SciTech Connect

    Choudhury, R.R.; Gerstein, M.

    1984-10-01

    It is well known that the boiling point of a typical fuel blend is different from those of the pure components. For an ideal mixture of liquids at a given state, the new boiling point can be calculated either theoretically or can be obtained from experimental data (e.g. ASTM distillation curve). The ASTM distillation data for JP-4, for example, show that the boiling point can change by about 250 C depending upon the degree of evaporation. Droplets of different diameters in a spray undergo different degrees of evaporation and hence have different boiling temperatures. The purpose of the present paper is to investigate the effects of temperature distribution in the spray on the local overall fuel-air ratio. Sprays of both JP-8 and JP-4 (ASTM distillation data) are used as examples in a flowing, one-dimensional stream at 20 atm and 680 K. The droplets undergo an initial phase of unsteady heating and finally steady evaporation follows when the wet-bulb temperature is reached. The results of this study show that operating conditions the temperature distribution in a fuel spray can have a significant effect on the local fuel-air mixture and hence on the performance of an air breathing propulsion system. The use of a constant mean boiling temperature rather than the variable boiling temperature will result in significant errors.

  16. CFD simulation of DEBORA boiling experiments

    NASA Astrophysics Data System (ADS)

    Rzehak, Roland; Krepper, Eckhard

    2012-08-01

    In this work we investigate the present capabilities of computational fluid dynamics for wall boiling. The computational model used combines the Euler/Euler two-phase flow description with heat flux partitioning. This kind of modeling was previously applied to boiling water under high pressure conditions relevant to nuclear power systems. Similar conditions in terms of the relevant non-dimensional numbers have been realized in the DEBORA tests using dichlorodifluoromethane (R12) as the working fluid. This facilitated measurements of radial profiles for gas volume fraction, gas velocity, bubble size and liquid temperature as well as axial profiles of wall temperature. After reviewing the theoretical and experimental basis of correlations used in the ANSYS CFX model used for the calculations, we give a careful assessment of the necessary recalibrations to describe the DEBORA tests. The basic CFX model is validated by a detailed comparison to the experimental data for two selected test cases. Simulations with a single set of calibrated parameters are found to give reasonable quantitative agreement with the data for several tests within a certain range of conditions and reproduce the observed tendencies correctly. Several model refinements are then presented each of which is designed to improve one of the remaining deviations between simulation and measurements. Specifically we consider a homogeneous MUSIG model for the bubble size, modified bubble forces, a wall function for turbulent boiling flow and a partial slip boundary condition for the liquid phase. Finally, needs for further model developments are identified and promising directions discussed.

  17. An updated global grid point surface air temperature anomaly data set: 1851--1990

    SciTech Connect

    Sepanski, R.J.; Boden, T.A.; Daniels, R.C.

    1991-10-01

    This document presents land-based monthly surface air temperature anomalies (departures from a 1951--1970 reference period mean) on a 5{degree} latitude by 10{degree} longitude global grid. Monthly surface air temperature anomalies (departures from a 1957--1975 reference period mean) for the Antarctic (grid points from 65{degree}S to 85{degree}S) are presented in a similar way as a separate data set. The data were derived primarily from the World Weather Records and the archives of the United Kingdom Meteorological Office. This long-term record of temperature anomalies may be used in studies addressing possible greenhouse-gas-induced climate changes. To date, the data have been employed in generating regional, hemispheric, and global time series for determining whether recent (i.e., post-1900) warming trends have taken place. This document also presents the monthly mean temperature records for the individual stations that were used to generate the set of gridded anomalies. The periods of record vary by station. Northern Hemisphere station data have been corrected for inhomogeneities, while Southern Hemisphere data are presented in uncorrected form. 14 refs., 11 figs., 10 tabs.

  18. Realization of tin freezing point using a loop heat pipe-based hydraulic temperature control technique

    NASA Astrophysics Data System (ADS)

    Joung, Wukchul; Gam, Kee Sool; Kim, Yong-Gyoo

    2015-10-01

    In this work, the freezing point of tin (Sn FP) was realized by inside nucleation where the supercooling of tin and the reheating of the sample after the nucleation were achieved without extracting the cell from an isothermal apparatus. To this end, a novel hydraulic temperature control technique, which was based on the thermo-hydraulic characteristics of a pressure-controlled loop heat pipe (LHP), was employed to provide a slow cooling of the sample for deep supercooling and fast reheating after nucleation to minimize the amount of initial freeze of the sample. The required temperature controls were achieved by the active pressure control of a control gas inside the compensation chamber of the pressure-controlled LHP, and slow cooling at??-0.05 K min-1 for the deep supercooling of tin and fast heating at 2 K min-1 for reheating the sample after nucleation was attained. Based on this hydraulic temperature control technique, the nucleation of tin was realized at supercooling of around 19 K, and a satisfactorily fast reheating of the sample to the plateau-producing temperature (i.e. 0.5 K below the Sn FP) was achieved without any temperature overshoots of the isothermal region. The inside-nucleated Sn FP showed many desirable features compared to the Sn FP realized by the conventional outside nucleation method. The longer freezing plateaus and the better immersion characteristics of the Sn FP were obtained by inside nucleation, and the measured freezing temperature of the inside-nucleated Sn FP was as much as 0.37 mK higher than the outside-nucleated Sn FP with an expanded uncertainty of 0.19 mK. Details on the experiment are provided and explanations for the observed differences are discussed.

  19. The Influence of Titanium on the Aluminum Fixed-Point Temperature

    NASA Astrophysics Data System (ADS)

    Petchpong, Patchariya; Head, David I.

    2011-08-01

    This work describes the deliberate doping of high purity (99.9999 %) aluminum with titanium (99.8 %) impurity and the effect of this on the temperature of the aluminum liquid-solid phase transition (660.323 C). The aluminum sample was in the form of an ~0.3 kg ingot (that would normally be used to realize an ITS-90 fixed point) which was doped at ~0.9 ppmw Ti and ~1.8 ppmw Ti (mass fraction in parts per million by mass). Measurements were made with procedures and equipment normally used in a metrological thermometry laboratory, rather than using special arrangements. Samples cut from the aluminum ingot were chemically analyzed by glow discharge mass spectrometry (GD-MS) before doping and after the second doping (to 1.8 ppmw). The experimental temperature offsets were compared with those calculated by interpolation from a reference book value using the mass of dopant introduced, or the chemical analysis data. The results showed that the aluminum temperature increased after adding 0.9 ppmw Ti, but apparently the temperature did not change after further doping to 1.8 ppmw Ti; which was unexpected. The first result suggested that titanium impurity increases the Al transition temperature by +5.1 mK ppmw-1. However, using the (total) temperature offset and the GD-MS value for the (total) added Ti impurities, then one calculates a value of 3.4 mK ppmw-1 (much closer to a reference book value). The experimental undoped liquid-solid transition curves were also compared against theoretical curves (calculated using a theoretical model "MTDATA"). This suggested that GD-MS may not be "exposing" all the active impurities (some of which may be "hidden" in the carbon background).

  20. Boiling local heat transfer enhancement in minichannels using nanofluids.

    PubMed

    Chehade, Ali Ahmad; Gualous, Hasna Louahlia; Le Masson, Stephane; Fardoun, Farouk; Besq, Anthony

    2013-01-01

    This paper reports an experimental study on nanofluid convective boiling heat transfer in parallel rectangular minichannels of 800 ?m hydraulic diameter. Experiments are conducted with pure water and silver nanoparticles suspended in water base fluid. Two small volume fractions of silver nanoparticles suspended in water are tested: 0.000237% and 0.000475%. The experimental results show that the local heat transfer coefficient, local heat flux, and local wall temperature are affected by silver nanoparticle concentration in water base fluid. In addition, different correlations established for boiling flow heat transfer in minichannels or macrochannels are evaluated. It is found that the correlation of Kandlikar and Balasubramanian is the closest to the water boiling heat transfer results. The boiling local heat transfer enhancement by adding silver nanoparticles in base fluid is not uniform along the channel flow. Better performances and highest effect of nanoparticle concentration on the heat transfer are obtained at the minichannels entrance. PMID:23506445

  1. Boiling local heat transfer enhancement in minichannels using nanofluids

    PubMed Central

    2013-01-01

    This paper reports an experimental study on nanofluid convective boiling heat transfer in parallel rectangular minichannels of 800 ?m hydraulic diameter. Experiments are conducted with pure water and silver nanoparticles suspended in water base fluid. Two small volume fractions of silver nanoparticles suspended in water are tested: 0.000237% and 0.000475%. The experimental results show that the local heat transfer coefficient, local heat flux, and local wall temperature are affected by silver nanoparticle concentration in water base fluid. In addition, different correlations established for boiling flow heat transfer in minichannels or macrochannels are evaluated. It is found that the correlation of Kandlikar and Balasubramanian is the closest to the water boiling heat transfer results. The boiling local heat transfer enhancement by adding silver nanoparticles in base fluid is not uniform along the channel flow. Better performances and highest effect of nanoparticle concentration on the heat transfer are obtained at the minichannels entrance. PMID:23506445

  2. Boiling local heat transfer enhancement in minichannels using nanofluids

    NASA Astrophysics Data System (ADS)

    Chehade, Ali Ahmad; Gualous, Hasna Louahlia; Le Masson, Stephane; Fardoun, Farouk; Besq, Anthony

    2013-03-01

    This paper reports an experimental study on nanofluid convective boiling heat transfer in parallel rectangular minichannels of 800 ?m hydraulic diameter. Experiments are conducted with pure water and silver nanoparticles suspended in water base fluid. Two small volume fractions of silver nanoparticles suspended in water are tested: 0.000237% and 0.000475%. The experimental results show that the local heat transfer coefficient, local heat flux, and local wall temperature are affected by silver nanoparticle concentration in water base fluid. In addition, different correlations established for boiling flow heat transfer in minichannels or macrochannels are evaluated. It is found that the correlation of Kandlikar and Balasubramanian is the closest to the water boiling heat transfer results. The boiling local heat transfer enhancement by adding silver nanoparticles in base fluid is not uniform along the channel flow. Better performances and highest effect of nanoparticle concentration on the heat transfer are obtained at the minichannels entrance.

  3. Turning bubbles on and off during boiling using charged surfactants

    PubMed Central

    Cho, H. Jeremy; Mizerak, Jordan P.; Wang, Evelyn N.

    2015-01-01

    Boiling—a process that has powered industries since the steam age—is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature or steam generation cannot be adjusted for a given heat input. Here we report the ability to turn bubbles ‘on and off' independent of heat input during boiling both temporally and spatially via molecular manipulation of the boiling surface. As a result, we can rapidly and reversibly alter heat transfer performance up to an order of magnitude. Our experiments show that this active control is achieved by electrostatically adsorbing and desorbing charged surfactants to alter the wettability of the surface, thereby affecting nucleation. This approach can improve performance and flexibility in existing boiling technologies as well as enable emerging or unprecedented energy applications. PMID:26486275

  4. Thermal radiative transport through LiF for temperatures near the melting point

    SciTech Connect

    Williams, P.T.

    1988-06-01

    As a part of NASA's Advanced Solar Dynamics Program, lithium fluoride (LiF) is being studied as a phase-change material for energy storage in a solar receiver. This report investigates thermal radiation in LiF at temperatures near the melting point. Using a simple, one-dimensional model problem, scoping calculations are carried out to estimate the relative importance of radiation as a mode of heat transfer through a 1.35-cm layer of LiF. When compared with conduction in the solid phase and buoyancy-driven convection in the liquid phase, radiation plays a significant but not dominant role for temperatures near the melting point. The theory of radiant heat transfer through an absorbing/emitting medium with nonunity index of refraction is reviewed, and a two-band energy approximation is proposed as a modeling approach for LiF. This method is prompted by the nature of a single crystal spectral absorption coefficient distribution for LiF. For the wavelength band from 0--5.5 ..mu..m, it is recommended that LiF be treated as a fully transparent, nonparticipating medium. Above 5.5 ..mu..m LiF is assumed to be optically thick, and the diffusion method can then be applied in the solution of the energy equation for the material. 23 refs., 15 figs.

  5. Effects of turbulence and secondary flows on subcooled flow boiling

    NASA Astrophysics Data System (ADS)

    Bloch, Gregor; Sattelmayer, Thomas

    2014-03-01

    Experiments are conducted on the influence of turbulence and longitudinal vortices on subcooled flow boiling in a vertical, rectangular channel. Different flow inserts are used to create turbulence and vortices in the channel. Studied boiling regimes range from the onset of nucleate boiling over the critical heat flux up to fully developed film boiling. A wide range of measuring techniques is applied: time averaged particle image velocimetry (PIV) is used in cold flows for the evaluation of the effects the inserts have on the flow, high speed PIV and photography are used to determine the effects on the fluid and vapor movement in boiling experiments. Digital Holographic Interferometry is used for the evaluation of temperature distributions in the boiling flow. Furthermore, optical microprobes are used to obtain pointwise measurements in areas inaccessible to the imaging techniques. The experiments show that the flow inserts can have considerable impact on the heat fluxes and the distribution of vapor and temperature along the channel. All used inserts lead to an increase in critical heat flux, which is more pronounced for stronger turbulence and higher flow rates and fluid subcoolings. The measuring techniques reveal both a better transport of vapor from the heater surface as well as an increase in mixing in the liquid phase with flow inserts.

  6. Estimating the Contribution of Impurities to the Uncertainty of Metal Fixed-Point Temperatures

    NASA Astrophysics Data System (ADS)

    Hill, K. D.

    2014-04-01

    The estimation of the uncertainty component attributable to impurities remains a central and important topic of fixed-point research. Various methods are available for this estimation, depending on the extent of the available information. The sum of individual estimates method has considerable appeal where there is adequate knowledge of the sensitivity coefficients for each of the impurity elements and sufficiently low uncertainty regarding their concentrations. The overall maximum estimate (OME) forsakes the behavior of the individual elements by assuming that the cryoscopic constant adequately represents (or is an upper bound for) the sensitivity coefficients of the individual impurities. Validation of these methods using melting and/or freezing curves is recommended to provide confidence. Recent investigations of indium, tin, and zinc fixed points are reported. Glow discharge mass spectrometry was used to determine the impurity concentrations of the metals used to fill the cells. Melting curves were analyzed to derive an experimental overall impurity concentration (assuming that all impurities have a sensitivity coefficient equivalent to that of the cryoscopic constant). The two values (chemical and experimental) for the overall impurity concentrations were then compared. Based on the data obtained, the pragmatic approach of choosing the larger of the chemical and experimentally derived quantities as the best estimate of the influence of impurities on the temperature of the freezing point is suggested rather than relying solely on the chemical analysis and the OME method to derive the uncertainty component attributable to impurities.

  7. Film boiling of mercury droplets

    NASA Technical Reports Server (NTRS)

    Baumeister, K. J.; Schoessow, G. J.; Chmielewski, C. E.

    1975-01-01

    Vaporization times of mercury droplets in Leidenfrost film boiling on a flat horizontal plate are measured in an air atmosphere. Extreme care was used to prevent large amplitude droplet vibrations and surface wetting; therefore, these data can be compared to film boiling theory. Diffusion from the upper surface of the drop appears as a dominant mode of mass transfer from the drop. A closed-form analytical film boiling theory is developed to account for the diffusive evaporation. Reasonable agreement between data and theory is seen.

  8. Pool and flow boiling in variable and microgravity

    NASA Technical Reports Server (NTRS)

    Merte, Herman, Jr.

    1994-01-01

    As is well known, boiling is an effective mode of heat transfer in that high heat flux levels are possible with relatively small temperature differences. Its optimal application requires that the process be adequately understood. A measure of the understanding of any physical event lies in the ability to predict its behavior in terms of the relevant parameters. Despite many years of research the predictability of boiling is currently possible only for quite specialized circumstances, e.g., the critical heat flux and film boiling for the pool boiling case, and then only with special geometries. Variable gravity down to microgravity provides the opportunity to test this understanding, but possibly more important, by changing the dimensional and time scales involved permits more detailed observations of elements involved in the boiling process, and perhaps discloses phenomena heretofore unknown. The focus here is on nucleate boiling although, as will be demonstrated below, under but certain circumstances in microgravity it can take place concurrently with the dryout process. In the presence of earth gravity or forced convection effects, the latter process is usually referred to as film boiling. However, no vapor film as such forms with pool boiling in microgravity, only dryout. Initial results are presented here for pool boiling in microgravity, and were made possible at such an early date by the availability of the Get-Away-Specials (GAS). Also presented here are some results of ground testing of a flow loop for the study of low velocity boiling, eventually to take place also in microgravity. In the interim, variable buoyancy normal to the heater surface is achieved by rotation of the entire loop relative to earth gravity. Of course, this is at the expense of varying the buoyancy parallel to the heater surface. Two questions which must be resolved early in the study of flow boiling in microgravity are (1) the lower limits of liquid flow velocity where buoyancy effects become significant to the boiling process (2) the effect of lower liquid flow velocities on the Critical Heat Flux when buoyancy is removed. Results of initial efforts in these directions are presented, albeit restricted currently to the ever present earth gravity.

  9. Unsteady heat transfer during subcooled film boiling

    NASA Astrophysics Data System (ADS)

    Yagov, V. V.; Zabirov, A. R.; Lexin, M. A.

    2015-11-01

    Cooling of high-temperature bodies in subcooled liquid is of importance for quenching technologies and also for understanding the processes initiating vapor explosion. An analysis of the available experimental information shows that the mechanisms governing heat transfer in these processes are interpreted ambiguously; a more clear-cut definition of the Leidenfrost temperature notion is required. The results of experimental observations (Hewitt, Kenning, and previous investigations performed by the authors of this article) allow us to draw a conclusion that there exists a special mode of intense heat transfer during film boil- ing of highly subcooled liquid. For revealing regularities and mechanisms governing intense transfer of energy in this process, specialists of Moscow Power Engineering Institute's (MPEI) Department of Engineering Thermal Physics conduct systematic works aimed at investigating the cooling of high-temperature balls made of different metals in water with a temperature ranging from 20 to 100°C. It has been determined that the field of temperatures that takes place in balls with a diameter of more than 30 mm in intense cooling modes loses its spherical symmetry. An approximate procedure for solving the inverse thermal conductivity problem for calculating the heat flux density on the ball surface is developed. During film boiling, in which the ball surface temperature is well above the critical level for water, and in which liquid cannot come in direct contact with the wall, the calculated heat fluxes reach 3-7 MW/m2.

  10. Lifshitz transitions and zero point lattice fluctuations in sulfur hydride showing near room temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Bianconi, Antonio; Jarlborg, Thomas

    2015-11-01

    Emerets's experiments on pressurized sulfur hydride have shown that H3S metal has the highest known superconducting critical temperature Tc = 203 K. The Emerets data show pressure induced changes of the isotope coefficient between 0.25 and 0.5, in disagreement with Eliashberg theory which predicts a nearly constant isotope coefficient.We assign the pressure dependent isotope coefficient to Lifshitz transitions induced by pressure and zero point lattice fluctuations. It is known that pressure could induce changes of the topology of the Fermi surface, called Lifshitz transitions, but were neglected in previous papers on the H3S superconductivity issue. Here we propose thatH3S is a multi-gap superconductor with a first condensate in the BCS regime (located in the large Fermi surface with high Fermi energy) which coexists with second condensates in the BCS-BEC crossover regime (located on the Fermi surface spots with small Fermi energy) near the and Mpoints.We discuss the Bianconi-Perali-Valletta (BPV) superconductivity theory to understand superconductivity in H3S since the BPV theory includes the corrections of the chemical potential due to pairing and the configuration interaction between different condensates, neglected by the Eliashberg theory. These two terms in the BPV theory give the shape resonance in superconducting gaps, similar to Feshbach resonance in ultracold fermionic gases, which is known to amplify the critical temperature. Therefore this work provides some key tools useful in the search for new room temperature superconductors.

  11. A Novel Role of Three Dimensional Graphene Foam to Prevent Heater Failure during Boiling

    NASA Astrophysics Data System (ADS)

    Ahn, Ho Seon; Kim, Ji Min; Park, Chibeom; Jang, Ji-Wook; Lee, Jae Sung; Kim, Hyungdae; Kaviany, Massoud; Kim, Moo Hwan

    2013-06-01

    We report a novel boiling heat transfer (NBHT) in reduced graphene oxide (RGO) suspended in water (RGO colloid) near critical heat flux (CHF), which is traditionally the dangerous limitation of nucleate boiling heat transfer because of heater failure. When the heat flux reaches the maximum value (CHF) in RGO colloid pool boiling, the wall temperature increases gradually and slowly with an almost constant heat flux, contrary to the rapid wall temperature increase found during water pool boiling. The gained time by NBHT would provide the safer margin of the heat transfer and the amazing impact on the thermal system as the first report of graphene application. In addition, the CHF and boiling heat transfer performance also increase. This novel boiling phenomenon can effectively prevent heater failure because of the role played by the self-assembled three-dimensional foam-like graphene network (SFG).

  12. Experimental study of surfactant effects on pool boiling heat transfer

    SciTech Connect

    Ying Liang Tzan; Yu Min Yang )

    1990-02-01

    In the first part of this work, nucleate boiling of aqueous solutions of sodium lauryl sulfate (SLS) over relatively wide ranges of concentration and heat flux was carried out in a pool boiling apparatus. The experimental results show that a small amount of surface active additive makes the nucleate boiling heat transfer coefficient h considerably higher, and that there is an optimum additive concentration for higher heat fluxes. Beyond this optimum point, further increase in additive concentration makes h lower. In the second part of this work, nucleate boiling heat transfer rate for n-propanol-water binary mixtures with various amounts of sodium lauryl sulfate were measured in the same pool boiling apparatus. The importance of the mass diffusion effect, which is caused by preferential evaporation of the more volatile component at the vapor-liquid interface on the boiling of the binary mixture, has been confirmed. However, it is shown that the effect exerted by the addition of a surfactant dominates over the mass diffusion effect in dilute binary mixtures.

  13. Improvements in Predicting Void Fraction in Subcooled Boiling

    SciTech Connect

    Ha, Kwi Seok; Lee, Yong Bum; No, Hee Cheon

    2005-06-15

    A simple two-phase thermal-hydraulic tool with the drift-flux model has been used to develop a subcooled boiling model. The tool is composed of four governing equations: mixture mass, vapor mass, mixture momentum, and mixture enthalpy. Using the developed tool, various subcooled boiling models were investigated through the published experimental data. In the process of evaluation, two models were developed associated with the subcooled boiling. First, the Saha and Zuber correlation predicting the point of the net vapor generation was modified to consider the thermal and dynamic effects at the high-velocity region. Second, the pumping factor model was developed using the pi-theorem based on parameters related to the bubble generation mechanism, and it produced an additional parameter: the boiling number. The proposed models and several other models were evaluated against a series of subcooled flow boiling experiments at the pressure range of 1 to 146.8 bars. From the root-mean-square analysis for the predicted void fraction in the subcooled boiling region, the results of the proposed model presented the best predictions for the whole-pressure ranges. Also, the implementation of the developed models into RELAP5/MOD3.3 brought about improved results compared to those of the default model of the code.

  14. High flux film and transition boiling

    SciTech Connect

    Witte, L.C.

    1990-01-01

    This report is a bench-scale experiment on transition boiling. The author gives a detailed description on experimental apparatus and conditions. The visual observed boiling phenomena; nucleate boiling and film boiling, and the effect of heat transfer are also elucidated. 10 refs., 11 figs., 1 tab.

  15. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity

    NASA Astrophysics Data System (ADS)

    Sigalotti, Leonardo Di G.; Troconis, Jorge; Sira, Eloy; Pea-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (Ts?0.96 ) is close to the theoretically derived value of Ts=1 at zero ambient pressure for this vdW fluid.

  16. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity.

    PubMed

    Sigalotti, Leonardo Di G; Troconis, Jorge; Sira, Eloy; Pea-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (T(s)?0.96) is close to the theoretically derived value of T(s)=1 at zero ambient pressure for this vdW fluid. PMID:26274283

  17. Boiling phenomena in near-critical SF6 observed in weightlessness

    NASA Astrophysics Data System (ADS)

    Lecoutre, Carole; Garrabos, Yves; Beysens, Daniel; Nikolayev, Vadim; Hahn, Inseob

    2014-07-01

    Boiling phenomena in the two-phase region of SF6 close to its critical point have been observed using the high-quality thermal and optical environment of the CNES dedicated facility ALI-DECLIC on board the International Space Station (ISS). The weightlessness environment of the fluid, which cancels buoyancy forces and favorites the three-dimensional spherical shape of the gas bubble, is proven to be an irreplaceable powerful tool for boiling studies. To identify each key mechanism of the boiling phenomena, the ALI-DECLIC experiments have benefited from (i) the well-adapted design of the test cells, (ii) the high-fidelity of the ALI insert teleoperation when long-duration experiment in stable thermal and microgravity environment are required and (iii) the high repeatability of the controlled thermal disturbances. These key mechanisms were observed by light transmission and interferometry technique independently with two sample cells filled with pure SF6 at a near-critical density. The fluid samples are driven away from thermal equilibrium by using a heater directly implemented in the fluid, or a surface heater on a sapphire optical window. In the interferometry cell, the bulk massive heater distinguishes two symmetrical two-phase domains. The modification of the gas bubble shape is observed during heating. In the direct observation cell, the gas bubble is separated by a liquid film from the thin layered transparent heater deposited on the sapphire window. The liquid film drying and the triple contact line motion during heating are observed using light transmission. The experiments have been performed in a temperature range of 10 K below the critical temperature Tc, with special attention to the range 0.1 mK?T-T?3 mK very close to the critical temperature. The unique advantage of this investigation is to provide opportunities to observe the boiling phenomena at very low heat fluxes, thanks to the fine adjustment of the liquid-vapor properties, (e.g. surface tension), by precise control of the distance to the critical point. We present the new observations of the gas bubble spreading over the heating surface which characterizes the regime where vapor bubbles nucleate separately and grow, as well as liquid drying, vapor film formation, triple contact line motion, which are the key mechanisms at the origin of the boiling crisis when the formed vapor film reduces the heat transfer drastically at the heater wall.

  18. Flow boiling test of GDP replacement coolants

    SciTech Connect

    Park, S.H.

    1995-08-01

    The tests were part of the CFC replacement program to identify and test alternate coolants to replace CFC-114 being used in the uranium enrichment plants at Paducah and Portsmouth. The coolants tested, C{sub 4}F{sub 10} and C{sub 4}F{sub 8}, were selected based on their compatibility with the uranium hexafluoride process gas and how well the boiling temperature and vapor pressure matched that of CFC-114. However, the heat of vaporization of both coolants is lower than that of CFC-114 requiring larger coolant mass flow than CFC-114 to remove the same amount of heat. The vapor pressure of these coolants is higher than CFC-114 within the cascade operational range, and each coolant can be used as a replacement coolant with some limitation at 3,300 hp operation. The results of the CFC-114/C{sub 4}F{sub 10} mixture tests show boiling heat transfer coefficient degraded to a minimum value with about 25% C{sub 4}F{sub 10} weight mixture in CFC-114 and the degree of degradation is about 20% from that of CFC-114 boiling heat transfer coefficient. This report consists of the final reports from Cudo Technologies, Ltd.

  19. Film boiling behavior of a pressurized water reactor type fuel bundle

    SciTech Connect

    Gunnerson, F.S.; Sparks, D.T.; Kerwin, D.K.

    1981-01-01

    An in-pile power-cooling-mismatch (PCM) test designed to investigate the behavior of a nine-rod PWR-type fuel bundle under intermittent and sustained periods of high temperature film boiling operation was recently conducted. Emphasis was placed on departure from nucleate boiling (DNB) and return to nucleate boiling (RNB), rod-to-rod interactions, and fuel rod failure. 23 refs.

  20. Spin glass in a field: a new zero-temperature fixed point in finite dimensions.

    PubMed

    Angelini, Maria Chiara; Biroli, Giulio

    2015-03-01

    By using real-space renormalization group (RG) methods, we show that spin glasses in a field display a new kind of transition in high dimensions. The corresponding critical properties and the spin-glass phase are governed by two nonperturbative zero-temperature fixed points of the RG flow. We compute the critical exponents and discuss the RG flow and its relevance for three-dimensional systems. The new spin-glass phase we discovered has unusual properties, which are intermediate between the ones conjectured by droplet and full replica symmetry-breaking theories. These results provide a new perspective on the long-standing debate about the behavior of spin glasses in a field. PMID:25793828

  1. The Effect of Low Level Antimony on the Tin Temperature Fixed Point

    NASA Astrophysics Data System (ADS)

    Petchpong, Patchariya; Head, David I.

    2011-08-01

    Impurities are a major source of uncertainty in the temperature of a thermometry metal fixed point (of the order of 1 mK). A better understanding of the impurity effect is required to improve top-level metrological thermometry. This investigation reports on some unusual effects of antimony doped into a high-purity (99.9999%) tin sample. The change in temperature and shape of the melting and freezing curves of the tin, caused by low concentrations of the Sb dopant, were measured in order to test the interpolation of previous data. Most historical experiments have worked at much higher impurity concentrationssay of the order of 100 ppmand in arrangements that are not used on a day-to-day basis in a metrology laboratory. These measurements on the tin were done after doping at mass fractions of approximately (1 and 25) parts per million by weight (ppmw) of antimony. Repeated melting and freezing curves, before and after doping, confirmed the reproducibility of the temperature measurements in this tin cell. The freezing temperature of the tin after adding antimony was higher than for "pure" tin. However, the temperature change was less than expected, being an average (+0.060.03) mK ppmw-1. Samples from the tin were analyzed by glow discharge mass spectrometry (GD-MS) before and after doping to detect the distribution of all the impurity elements. If the dopant level detected by GD-MS was used, then a value of (0.18 or 0.29) mK ppmw-1 was calculated (much closer to the value interpolated from earlier works). There was evidence that the thermal history of metal phase transitions can cause considerable segregation of some impurities and that the effects of this segregation can be clearly seen on the shape of the melting curves of tin doped with Sb. (The segregation might be more pronounced as Sb forms a peritectic in tin, i.e., a "positive" impurity which increase the phase transition temperature).

  2. Transient nucleate pool boiling in microgravity: Some initial results

    NASA Technical Reports Server (NTRS)

    Merte, Herman, Jr.; Lee, H. S.; Ervin, J. S.

    1994-01-01

    Variable gravity provides an opportunity to test the understanding of phenomena which are considered to depend on buoyancy, such as nucleate pool boiling. The active fundamental research in nucleate boiling has sought to determine the mechanisms or physical processes responsible for its high effectiveness, manifested by the high heat flux levels possible with relatively low temperature differences. Earlier research on nucleate pool boiling at high gravity levels under steady conditions demonstrated quantitatively that the heat transfer is degraded as the buoyancy normal to the heater surfaced increases. Correspondingly, it was later shown, qualitatively for short periods of time only, that nucleate boiling heat transfer is enhanced as the buoyancy normal to the heater surface is reduced. It can be deduced that nucleate pool boiling can be sustained as a quasi-steady process provided that some means is available to remove the vapor generated from the immediate vicinity of the heater surface. One of the objectives of the research, the initial results of which are presented here, is to quantify the heat transfer associated with boiling in microgravity. Some quantitative results of nucleate pool boiling in high quality microgravity (a/g approximately 10(exp -5)) of 5s duration, obtained in an evacuated drop tower, are presented here. These experiments were conducted as precursors of longer term space experiments. A transient heating technique is used, in which the heater surface is a transparent gold film sputtered on a qua rtz substrate, simultaneously providing the mean surface temperature from resistance thermometry and viewing of the boiling process both from beneath and across the surface. The measurement of the transient mean heater surface temperature permits the computation, by numerical means, of the transient mean heat transfer coefficient. The preliminary data obtained demonstrates that a quasi-steady boiling process can occur in microgravity if the bulk liquid subcooling is sufficiently high and if the imposed heat flux is sufficiently low. This is attributed to suface tension effects at the liquid-vapor-solid junction causing rewetting to take place, sustaining the nucleate boiling. Otherwise, dryout at the heater surface will occur, as observed.

  3. POINT 2012: ENDF/B-VII.1 Final Temperature Dependent Cross Section Library

    SciTech Connect

    Cullen, D E

    2012-02-26

    This report is one in the series of 'POINT' reports that over the years have presented temperature dependent cross sections for the then current version of ENDF/B [R1]. In each case I have used my personal computer at home and publicly available data and codes: (1) publicly available nuclear data (the current ENDF/B data, available on-line at the National Nuclear Data Center, Brookhaven National Laboratory, http://www.nndc.bnl.gov/) and, (2) publicly available computer codes (the current PREPRO codes, available on-line at the Nuclear Data Section, IAEA, Vienna, Austria, http://www-nds.iaea.or.at/ndspub/endf/prepro/) and, (3) My own personal computer located in my home. I have used these in combination to produce the temperature dependent cross sections used in applications and described in this report. I should mention that today anyone with a personal computer can produce these results: by its very nature I consider this data to be born in the public domain.

  4. Electrical Conductivity of Molten ZnCl2 at Temperature as High as 1421 K

    NASA Astrophysics Data System (ADS)

    Salyulev, Alexander B.; Potapov, Alexei M.

    2015-02-01

    The electrical conductivity of molten ZnCl2 was measured in a wide temperature range (?T=863 K) to a temperature as high as 1421 K that is 417 degrees above the boiling point of the salt. At the temperature maximum of the own vapor pressure of the salt reached several megapascals.

  5. Determination of the 1%, 2.5%, and 5% occurrences of extreme dew-point temperatures and mean coincident dry-bulb temperatures

    SciTech Connect

    Colliver, D.G.; Zhang, H.; Gates, R.; Priddy, T.

    1995-12-31

    The purpose of ASHRAE Research Project RP-754 was to find the outdoor design occurrences of extreme dew-point temperature and the corresponding mean coincident dry-bulb temperature for a large number of locations in North America. Thirty years of data (1961--1990) were used for 239 US locations, and the last 30 years of hourly data available (typically 1960--1989) were used for 143 Canadian locations. Tables are given that present the 1%, 2.5%, and 5% extreme summertime occurrences of dew-point temperatures and corresponding values of humidity ratios and the mean coincident dry-bulb (MCDB) temperature for the period of record. A map that shows the general geographical trends for the spatial distribution of the design dew-point values is also presented. Comparisons are provided between interpolation techniques to fill missing data, different weather data sets, and methods of calculating different definitions of extreme design and mean coincident data. Results are also reported of a comparison to evaluate the difference in humidity ratios between that calculated from the extreme design dry-bulb temperature and mean coincident wet-bulb temperature, versus that calculated from the extreme design dew-point temperature and the MCDB. It was found that the method of extreme dew point with MCDB had a higher humidity ratio that was on the average (for the 1% case and the 239 US locations) 0.00564 lb/lb larger than the humidity ratio found with the other method.

  6. Simultaneous neutron radiography and infrared thermography measurement of boiling processes

    SciTech Connect

    Murphy, J.H.; Glickstein, S.S.

    1997-02-01

    Boiling of water at 1 to 15 bar flowing upward within a narrow duct and a round test section was observed using both neutron radiography and infrared (IR) thermography. The IR readings of the test section outer wall temperatures show the effects of both fluid temperature and wall heat transfer coefficient variations, producing a difference between liquid and two phase regions. The IR images, in fact, appear very similar to the neutron images; both show clear indications of spatial and temporal variations in the internal fluid conditions during the boiling process.

  7. Simultaneous neutron radiography and infrared thermography measurement of boiling processes

    SciTech Connect

    Murphy, J.H.; Glickstein, S.S.

    1996-12-31

    Boiling of water at 1 to 15 bar flowing upward within a narrow duct and a round test section was observed using both neutron radiography and infrared (IR) thermography. The IR readings of the test section outer wall temperatures show the effects of both fluid temperature and wall heat transfer coefficient variations, producing a difference between liquid and two phase regions. The IR images, in fact, appear very similar to the neutron images; both show clear indications of spatial and temporal variations in the internal fluid conditions during the boiling process.

  8. Nonlinear dynamics in horizontal film boiling

    NASA Astrophysics Data System (ADS)

    Panzarella, Charles Henry

    1998-11-01

    This work focuses on the thin vapor film which develops between an evaporating liquid and a solid heating surface during horizontal film boiling. In the absence of evaporative effects, the film is Rayleigh-Taylor unstable and releases a vapor bubble as it collapses. This instability is suppressed by evaporation. Two solution methods are used to study this problem. First, the long- wave approximation results in a strongly-nonlinear evolution equation which retains the leading-order effects of gravity, surface tension, van der Waals forces, evaporation and viscous flow in the vapor. When this simpler equation is no longer valid, a boundary element method follows the dynamics up to the point where the vapor bubble pinches-off from the film. In the isothermal case, the film is always unstable, and the minimum film thickness tends to zero. In saturated film boiling, the film is still unstable, but its thickness never drops below a minimum value, and liquid-solid contact is suppressed during the entire bubble-release cycle. In subcooled film boiling, there is a simple steady-state solution, a constant-thickness vapor film determined by a simple heat-conduction balance. This is linearly stable for large subcooling, and a bifurcation analysis determines a supercritical branch of stable, spatially-periodic solutions for weak van der Waals forces. Numerical methods extend this solution branch into the strongly-nonlinear regime revealing a hysteresis loop near the bifurcation point and a secondary bifurcation to a branch of travelling waves which is stable under certain conditions. For less subcooling, vapor bubbles develop, but their growth is slower, and the total heat transfer is higher than in the saturated case.

  9. Multi-mode methanol flow boiling under atmospheric and subatmospheric pressures

    SciTech Connect

    Lin, W.W.; Liao, Y.C.; Lee, D.J.

    1996-12-31

    This is a continuation work of Lin and Lee (1996 National Heat Transfer Conference, Houston) while reporting the experimental results of multi-mode methanol flow boiling under atmospheric and subatmospheric pressures. An axial (discrete) heat flux distribution with neutral stability at which nucleate and film boiling can coexist steadily is identified under various system pressures and crossflow rates. Below this heat flux distribution, nucleate boiling mode is more stable. Above this distribution, film boiling becomes the more stable mode. An equal-area criterion based on the difference between bottom heat flux and surface boiling heat flux, and the wall superheat temperature relationship is employed for interpreting the experimental data. Effects of system pressure, mass flowrate, liquid subcooling and bottom heat flux on the relative stability of nucleate and film boiling modes are discussed.

  10. Computational fluid dynamics simulations of jet fuel flow near the freeze point temperature

    NASA Astrophysics Data System (ADS)

    Assudani, Rajee

    2006-12-01

    Under low-temperature environmental conditions, the cooling of aircraft fuel results in reduced fluidity with the potential for freezing. Therefore, it is important to study the flow and heat transfer phenomena that occur in an aircraft fuel tank near the freeze point temperature of jet fuels. The purpose of this dissertation is to study the effects of low temperatures on the flow, heat transfer and freezing of commercial and military jet fuels. The research is accomplished with the help of computational models of a thermal simulator tank and a quartz duct. Experimental results with the thermal simulator tank show that fuel flowability and pumpability decrease substantially as temperature is reduced. Time-dependent temperature and velocity distributions were numerically simulated for static cooling. Measured properties were used in all the computational fluid dynamics simulations. The calculations show that stringers, ribs, and other structures strongly promote fuel cooling. Also, the cooler, denser fuel resides near the bottom surface of the fuel tank simulator. The presence of an ullage space within the tank was found to strongly influence the fuel temperature profile by sometimes reducing cooling from the upper surface. Moreover, since the presence of ullage space is an explosion risk, some military aircraft fuel tanks are fitted with explosion suppressant polyurethane foam. To study the effect of foam on the flowability and heat transfer inside the simulator tank, the wing tank thermal simulator was filled with military specified polyurethane foam. The tank was simultaneously drained and cooled and the mass flow rate results showed that flowability of the fuel is not affected by the presence of foam. However, the presence of foam certainly affected the heat transfer phenomenon inside the fuel tank when the simulator tank was cooled and drained simultaneously. To study the freezing behavior of jet fuel under forced flow conditions, a quartz duct was fabricated. The duct walls were cooled below the solidification temperatures of JP-8 and JPTS fuel samples. Freezing was also simulated using computational fluid dynamics, and the validity of the calculations was established by comparing them with experimental measurements. This work demonstrates that computational fluid dynamics techniques can potentially be used to predict fuel hold-up in aircraft fuel tanks. The effect of flow rate on solidification was also simulated, and it was found that lower flow rates result in relatively more solidification of the fuel than do higher flow rates. The simulations of the freezing behaviors of JP-8 and JPTS samples were found to have essentially the same value of morphology constant. However, the crystal structures of these two fuels were studied in experiments and were found to be very different. This shows the inability of the model to capture small-scale details like the crystal microstructure. However, this limitation is not fatal here because the focus is on the overall flow and freezing behavior of jet fuels. The model was successful in predicting the freezing behavior by comparing the calculated frozen area obtained by the model with the measured area.

  11. Heat Transfer Coefficient Measurement Study of Several Film Boiling Modes in Subcooled He II

    SciTech Connect

    Takada, S.; Murakami, M.; Nozawa, M.; Kimura, N.

    2006-04-27

    This study was carried out for more detailed information about film boiling heat transfer in subcooled superfluid helium (He II). A number of film boiling modes were experimentally investigated in a wide range of the pressure from the atmospheric pressure down to the saturated vapor pressure. A thin stainless steel foil heater was used to cause film boiling and as a temperature sensor to measure the heater surface temperature. The results drawn from the heat transfer coefficient measurement give a support to the previous conclusion reached by visualization and pressure measurement studies that two film boiling modes appear in subcooled He II, that is the strongly subcooled film boiling mode and the weakly subcooled film boiling mode. It is, however, found that the dependence of the heat transfer coefficient on pressure was much different from those of conventional fluids. The heat transfer coefficient weakly decrease with the pressure in the weakly subcooled film boiling, and on the other hand it is almost independent of the pressure in the strongly film boiling. The peak of heat transfer coefficient appears at about 8 kPa in the transition region between the weakly subcooled and the noisy film boiling modes.

  12. Zero Boil-Off System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, D. W.; Johnson, W. L.; Feller, J. R.

    2015-01-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration plans due to their high specific impulse for rocket motors of upper stages. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for long duration missions. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler temperature to control tank pressure. The technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  13. Zero boil-off system testing

    NASA Astrophysics Data System (ADS)

    Plachta, D. W.; Johnson, W. L.; Feller, J. R.

    2016-03-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration plans due to their high specific impulse for rocket motors of upper stages. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for long duration missions. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler temperature to control tank pressure. The technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  14. 46 CFR 154.707 - Cargo boil-off as fuel: Ventilation.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo boil-off as fuel: Ventilation. 154.707 Section 154.707 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES... Equipment Cargo Pressure and Temperature Control 154.707 Cargo boil-off as fuel: Ventilation. (a)...

  15. 46 CFR 154.707 - Cargo boil-off as fuel: Ventilation.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Cargo boil-off as fuel: Ventilation. 154.707 Section 154... Equipment Cargo Pressure and Temperature Control 154.707 Cargo boil-off as fuel: Ventilation. (a) A ventilation hood or casing must be installed in areas occupied by flanges, valves, and piping at the...

  16. 46 CFR 154.707 - Cargo boil-off as fuel: Ventilation.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo boil-off as fuel: Ventilation. 154.707 Section 154... Equipment Cargo Pressure and Temperature Control 154.707 Cargo boil-off as fuel: Ventilation. (a) A ventilation hood or casing must be installed in areas occupied by flanges, valves, and piping at the...

  17. 46 CFR 154.709 - Cargo boil-off as fuel: Gas detection equipment.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Cargo boil-off as fuel: Gas detection equipment. 154.709 Section 154.709 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS... Equipment Cargo Pressure and Temperature Control 154.709 Cargo boil-off as fuel: Gas detection...

  18. 46 CFR 154.709 - Cargo boil-off as fuel: Gas detection equipment.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Cargo boil-off as fuel: Gas detection equipment. 154.709 Section 154.709 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS... Equipment Cargo Pressure and Temperature Control 154.709 Cargo boil-off as fuel: Gas detection...

  19. 46 CFR 154.709 - Cargo boil-off as fuel: Gas detection equipment.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo boil-off as fuel: Gas detection equipment. 154.709 Section 154.709 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS... Equipment Cargo Pressure and Temperature Control 154.709 Cargo boil-off as fuel: Gas detection...

  20. 46 CFR 154.709 - Cargo boil-off as fuel: Gas detection equipment.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Cargo boil-off as fuel: Gas detection equipment. 154.709 Section 154.709 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS... Equipment Cargo Pressure and Temperature Control 154.709 Cargo boil-off as fuel: Gas detection...

  1. 46 CFR 154.709 - Cargo boil-off as fuel: Gas detection equipment.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo boil-off as fuel: Gas detection equipment. 154.709 Section 154.709 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS... Equipment Cargo Pressure and Temperature Control 154.709 Cargo boil-off as fuel: Gas detection...

  2. Zero Boil-Off System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, David W.; Johnson, Wesley L.; Feller, Jeffrey R.

    2015-01-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration due to their high specific impulse for rocket motors of upper stages suitable for transporting 10s to 100s of metric tons of payload mass to destinations outside of low earth orbit and for their return. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for missions with durations greater than several months. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler to control tank pressure. The active thermal control technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center, in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. Testing consisted of three passive tests with the active cryocooler system off, and 7 active tests, with the cryocooler powered up. The test matrix included zero boil-off tests performed at 90 full and 25 full, and several demonstrations at excess cooling capacity and reduced cooling capacity. From this, the tank pressure response with varied cryocooler power inputs was determined. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  3. The initiation of boiling during pressure transients. [water boiling on metal surfaces

    NASA Technical Reports Server (NTRS)

    Weisman, J.; Bussell, G.; Jashnani, I. L.; Hsieh, T.

    1973-01-01

    The initiation of boiling of water on metal surfaces during pressure transients has been investigated. The data were obtained by a new technique in which light beam fluctuations and a pressure signal were simultaneously recorded on a dual beam oscilloscope. The results obtained agreed with those obtained using high speed photography. It was found that, for water temperatures between 90-150 C, the wall superheat required to initiate boiling during a rapid pressure transient was significantly higher than required when the pressure was slowly reduced. This result is explained by assuming that a finite time is necessary for vapor to fill the cavity at which the bubble originates. Experimental measurements of this time are in reasonably good agreement with calculations based on the proposed theory. The theory includes a new procedure for estimating the coefficient of vaporization.

  4. Numerical investigation on boiling flow of liquid nitrogen in a vertical tube using bubble number density approach

    NASA Astrophysics Data System (ADS)

    Shao, Xuefeng; Li, Xiangdong; Wang, Rongshun

    2015-06-01

    An average bubble number density (ABND) model was formulated and numerically resolved for the subcooled flow boiling of liquid nitrogen. The effects of bubble coalescence and breakup were taken into account. Some new closure correlations describing bubble nucleation and departure on the heating surface were selected as well. For the purpose of comparison, flow boiling of liquid nitrogen was also numerically simulated using a modified two-fluid model. The results show that the simulations performed by using the ABND model achieve encouraging improvement in accuracy in predicting heat flux and wall temperature of a vertical tube. Moreover, the influence of the bubble coalescence and breakup is shown to be great on predicting overall pressure beyond the transition point.

  5. Thermohydrodynamics of boiling in binary compressible fluids.

    PubMed

    Liu, Jiewei; Do-Quang, Minh; Amberg, Gustav

    2015-10-01

    We numerically study the thermohydrodynamics of boiling for a CO(2) + ethanol mixture on lyophilic and lyophobic surfaces in both closed and open systems, based on a diffuse interface model for a two-component system. The corresponding wetting boundary conditions for an isothermal system are proposed and verified in this paper. New phenomena due to the addition of another component, mainly the preferential evaporation of the more volatile component, are observed. In the open system and the closed system, the physical process shows very different characteristics. In the open system, except for the movement of the contact line, the qualitative features are rather similar for lyophobic and lyophilic surfaces. In the closed system, the vortices that are observed on a lyophobic surface are not seen on a lyophilic surface. More sophisticated wetting boundary conditions for nonisothermal, two-component systems might need to be further developed, taking into account the variations of density, temperature, and surface tension near the wall, while numerical results show that the boundary conditions proposed here also work well even in boiling, where the temperature is nonuniform. PMID:26565342

  6. Surface energy effect on boiling heat transfer

    NASA Astrophysics Data System (ADS)

    Patil, Atul P.; Vittala, Vijaya C. B.

    2005-10-01

    Boiling is a complex phenomenon and depends upon many factors like liquid properties, liquid pressure and temperature, temperature of the heating surface, orientation of the heating surface, surface chemistry, etc. Study of the effect of surface energy, one such factor, on boiling heat transfer is carried out and presented here. Data for various fluids viz. water, different types of alcohols and for various surfaces has been collected from the open literature and analysed with regard of effect of surface energy. The results of the investigations along with the recommendations have been presented in this paper. The investigations have shown that the increase in surface energy has resulted in increase in the heat transfer coefficient for distilled water, while the increase in surface energy has resulted in decrease in the heat transfer coefficient for alcohols. There is scarcity of relevant data available for further investigation and in this regard, need for benchmark data has been raised. Also need for establishment of a standard for comparison and analysis of different experimental results has been put forth.

  7. Thermohydrodynamics of boiling in binary compressible fluids

    NASA Astrophysics Data System (ADS)

    Liu, Jiewei; Do-Quang, Minh; Amberg, Gustav

    2015-10-01

    We numerically study the thermohydrodynamics of boiling for a CO2 + ethanol mixture on lyophilic and lyophobic surfaces in both closed and open systems, based on a diffuse interface model for a two-component system. The corresponding wetting boundary conditions for an isothermal system are proposed and verified in this paper. New phenomena due to the addition of another component, mainly the preferential evaporation of the more volatile component, are observed. In the open system and the closed system, the physical process shows very different characteristics. In the open system, except for the movement of the contact line, the qualitative features are rather similar for lyophobic and lyophilic surfaces. In the closed system, the vortices that are observed on a lyophobic surface are not seen on a lyophilic surface. More sophisticated wetting boundary conditions for nonisothermal, two-component systems might need to be further developed, taking into account the variations of density, temperature, and surface tension near the wall, while numerical results show that the boundary conditions proposed here also work well even in boiling, where the temperature is nonuniform.

  8. The Boiling eXperiment Facility (BXF) for the Microgravity Science Glovebox (MSG)

    NASA Technical Reports Server (NTRS)

    McQuillen, John; Chao, David; Vergilii, Frank

    2006-01-01

    Boiling is an effective means of cooling by removing heat from surfaces through vaporization of a working fluid. It is also affected by both the magnitude and direction of gravity. By conducting pool boiling tests in microgravity, the effect of buoyancy n the overall boiling process and the relative magnitude of other phenomena can be assessed. The Boiling eXperiment Facility (BXF) is being built for the Microgravity Science Glovebox. This facility will conduct two pool boiling studies. The first study the Microheater Array Boiling Experiment (MABE) uses two 96 element microheater arrays, 2.7 mm and 7.0 mm in size, to measure localized hear fluxes while operating at a constant temperature. The other experiment, the Nucleate Pool Boiling eXperiment (NPBX) uses a 85 mm diameter heater wafer that has been "seeded" with five individually-controlled nucleation sites to study bubble nucleation, growth, coalescence and departure. The BXF uses normal-perfluorohexane as the test fluid and will operate between pressures of 60 to 244 Pa. and temperatures of 35 to 60 C. Both sets of experimental heaters are highly instrumented. Pressure and bulk fluid temperature measurements will be made with standard rate video. A high speed video system will be used to visualize the boiling process through the bottom of the MABE heater arrays. The BXF is currently scheduled to fly on Utilization Flight-13A.1 to the ISS with facility integration into the MSG and operation during Increment 15

  9. Polarized optical properties of forsterite from room temperature up to the melting point

    NASA Astrophysics Data System (ADS)

    Eckes, M.; Gibert, B.; De Sousa Meneses, D.; Malki, M.; Echegut, P.

    2012-12-01

    Olivines are the most abundant phases of the Earth's upper mantle. Determining their optical properties under extreme conditions is essential to investigate their lattice dynamics and related structural evolution and to quantify their thermophysical properties. Optical properties of forsterite were determined by acquiring infrared emittance spectra from room temperature up to the melting point along the [100], [010] and [001] polarization directions and over a wide spectral range, from 50 to 15000 cm-1. The fitting of the experimental data by using a semi-quantum dielectric function model provides new results on lattice vibrations and phonon-phonon interactions in forsterite. In particular, a sudden enhancement of anharmonicity at high temperature is observed and is concomitant with the disappearance or brutal change of some modes around 1000K. The normal modes involving Mg1 cation motions are the more impacted and some of them vanish around 1200K. The polarization along [001] direction is more specifically impacted and this change can be linked to the magnesium mobility within M1 sites. This result is consistent with ab initio calculations1 and experimental data on tracer diffusion2 in forsterite that show the presence of an enhanced diffusion of magnesium via M1 sites along [001] direction. These data contribute to explain literature results that show evidences of a change of vibrational behaviour around 1000K, and in particular a strenghtening of lattice anharmonicity 3,4. This vibrational change may impact some important geophysical properties that depends on ionic diffusion, such as creep or electrical conductivity, were magnesium diffusion plays a key role. Finally, absorption coefficient has been calculated over the whole IR range from optical indices, allowing for the evaluation of the contribution of heat transport by radiation in forsterite. 1. J. Brodholt, Am. Mineral. 82, 1049-1053 (1997). 2. S. Chakraborty, J. R. Farver, R. A. Yund, D. C. Rubie, Phys. Chem. Miner. 21, 489-500 (1994). 3. P. Gillet, P. Richet, F. Guyot, G. Fiquet, J. Geophys. Research. B7, 96: 11805-11816 (1991). 4. F. Guyot, Y. Wang, P. Gillet, Y. Ricard, Phys. Earth. Planet. Inter. 98, 17-29 (1996).

  10. Assessment of RETRAN-3D Boiling Models Against Experimental Subcooled Boiling Tube Data

    SciTech Connect

    Macian, Rafael; Coddington, Paul; Stangroom, Paul

    2003-04-15

    Subcooled and saturated nucleate boiling are important physical processes in boiling water reactors (BWRs) under operating and transient conditions and in pressurized water reactors (PWRs) under transient conditions. Good predictions of such processes by system codes such as RETRAN-3D are, therefore, important from a safety and operational point of view.For this reason, and continuing the validation efforts carried out in the STARS Project at Paul Scherrer Institute, data from experiments in a uniformly heated tube carried out by Bartolomey et al. have been used to assess the subcooled and saturated nucleate boiling models in RETRAN-3D. These experiments were performed at high ({approx}15-MPa) and medium ({approx}7-, 4-, and 3-MPa) pressures. The heat flux (2210 to 420 kW/m{sup 2}) and mass flux (2123 to 405 kg/s m{sup 2}) were selected to cover a range of values spanning operating and transient situations in both BWRs and PWRs.This paper reports on the results obtained with both the four- and five-equation RETRAN-3D flow models. The results show that both models used in RETRAN-3D provide good estimates of subcooled and saturated nucleate boiling in heated tubes. The four-equation model, which makes use of the Electric Power Research Institute void fraction profile fitting model for the reactivity feedback only, shows the best performance for high mass fluxes, whereas the five-equation model, which directly computes the vaporization rate, performs better at low mass fluxes and relatively high heat fluxes.In addition to the results from RETRAN-3D, results obtained with the system code RELAP-5 are included in the plots and used to support the conclusions and to perform a comparative analysis of the methods used by the codes.

  11. Research on radiation detectors, boiling transients, and organic lubricants

    NASA Technical Reports Server (NTRS)

    1974-01-01

    The accomplishments of a space projects research facility are presented. The subjects discussed are: (1) a study of radiation resistant semiconductor devices, (2) synthesis of high temperature organic lubricants, (3) departure from phase equilibrium during boiling transients, (4) effects of neutron irradiation on defect state in tungsten, and (5) determination of photon response function of NE-213 liquid scintillation detectors.

  12. On Boiling of Crude Oil under Elevated Pressure

    NASA Astrophysics Data System (ADS)

    Pimenova, Anastasiya V.; Goldobin, Denis S.

    2016-02-01

    We construct a thermodynamic model for theoretical calculation of the boiling process of multicomponent mixtures of hydrocarbons (e.g., crude oil). The model governs kinetics of the mixture composition in the course of the distillation process along with the boiling temperature increase. The model heavily relies on the theory of dilute solutions of gases in liquids. Importantly, our results are applicable for modelling the process under elevated pressure (while the empiric models for oil cracking are not scalable to the case of extreme pressure), such as in an oil field heated by lava intrusions.

  13. Boiling effect in liquid nitrogen directly cooled Yb3+:YAG laser.

    PubMed

    Sakurai, Toshimitsu; Chosrowjan, Haik; Furuse, Hiroaki; Taniguchi, Seiji; Kitamura, Toshiyuki; Fujita, Masayuki; Ishii, Shinya; Izawa, Yasukazu

    2016-02-20

    Liquid nitrogen (LN2) behavior on the surface of excited Yb3+:YAG is investigated using fluorometry. From the time-resolved temperature variations and integrated fluorescence spectra intensity on this directly cooled Yb3+:YAG surface, we observe a phase transition of LN2 from nucleate boiling to film boiling. As a result of this pool boiling, good beam quality should occur when the temperature and heat flux at an excited surface of Yb3+:YAG are below 95 K and 15.8??W/cm2, respectively. That is, the LN2 should remain in a steady state of nucleate boiling to produce good beam quality using pool boiling. PMID:26906588

  14. Gravity and Heater Size Effects on Pool Boiling Heat Transfer

    NASA Technical Reports Server (NTRS)

    Kim, Jungho; Raj, Rishi

    2014-01-01

    The current work is based on observations of boiling heat transfer over a continuous range of gravity levels between 0g to 1.8g and varying heater sizes with a fluorinert as the test liquid (FC-72/n-perfluorohexane). Variable gravity pool boiling heat transfer measurements over a wide range of gravity levels were made during parabolic flight campaigns as well as onboard the International Space Station. For large heaters and-or higher gravity conditions, buoyancy dominated boiling and heat transfer results were heater size independent. The power law coefficient for gravity in the heat transfer equation was found to be a function of wall temperature under these conditions. Under low gravity conditions and-or for smaller heaters, surface tension forces dominated and heat transfer results were heater size dependent. A pool boiling regime map differentiating buoyancy and surface tension dominated regimes was developed along with a unified framework that allowed for scaling of pool boiling over a wide range of gravity levels and heater sizes. The scaling laws developed in this study are expected to allow performance quantification of phase change based technologies under variable gravity environments eventually leading to their implementation in space based applications.

  15. Characterization of Monodispersed ?-Al2O3 Particles, Synthesized by Homogeneous Precipitation under Reflux Boiling

    NASA Astrophysics Data System (ADS)

    Haq, Ikram Ul; Akhtar, Khalida; Khan, Zia Ullah

    2015-07-01

    In this study, micron size uniform particles of aluminum compounds were synthesized by the homogeneous precipitation method under reflux boiling, using aluminum nitrate, urea and potassium sulfate as starting materials. In this method, varying amounts of the reactants were heated in a Pyrex glass round bottom flask at the boiling temperature for various periods of time, which led to the production of precipitated particles in the reactant mixtures. Scanning electron microscopic (SEM) examination of the precipitated particles revealed that uniformity in particle morphology of the precipitated particles was dependent on the applied experimental conditions. As such, the latter were extensively optimized for obtaining particles of uniform morphology and size. Some of the batches of the precipitated particles were calcined at the elevated temperature (800 and 1000 C) for transformation into crystalline solids. Similarly, the as prepared and calcined particles were characterized by SEM, XRD, TGA/DTA and FTIR. XRD results revealed that at 1000 C of calcinations, the as prepared amorphous alumina transformed in to crystalline state, while below this temperature, i.e. at 800 C calcination, the powder was amorphous in nature. The point of zero charge (PZC) of the desired sample was estimated by the salt addition method.

  16. Cryogenic temperature monitoring in superconducting power transmission line at CERN with hybrid multi-point and distributed fiber optic sensors

    NASA Astrophysics Data System (ADS)

    Chiuchiolo, A.; Palmieri, L.; Consales, M.; Giordano, M.; Bajas, H.; Galtarossa, A.; Bajko, M.; Cusano, A.

    2015-09-01

    Distributed and multi-point fiber-optic based measurements of cryogenic temperature down to 30 K are presented. Measurements have been performed along the cryostat of a superconducting power transmission line, which is currently being tested at CERN over a length of about 20 m. Multi-point measurements were based on two kinds of FBG with different coatings (epoxy and PMMA). In addition, distributed measurements exploited optical frequency-domain reflectometry to analyze the Rayleigh scattering along two concatenated fibers with different coatings (acrylate and polyimmide). Results confirm the viability of these approaches to monitor cryogenic temperatures along a superconducting transmission line.

  17. Evaluation of correlations of flow boiling heat transfer of R22 in horizontal channels.

    PubMed

    Zhou, Zhanru; Fang, Xiande; Li, Dingkun

    2013-01-01

    The calculation of two-phase flow boiling heat transfer of R22 in channels is required in a variety of applications, such as chemical process cooling systems, refrigeration, and air conditioning. A number of correlations for flow boiling heat transfer in channels have been proposed. This work evaluates the existing correlations for flow boiling heat transfer coefficient with 1669 experimental data points of flow boiling heat transfer of R22 collected from 18 published papers. The top two correlations for R22 are those of Liu and Winterton (1991) and Fang (2013), with the mean absolute deviation of 32.7% and 32.8%, respectively. More studies should be carried out to develop better ones. Effects of channel dimension and vapor quality on heat transfer are analyzed, and the results provide valuable information for further research in the correlation of two-phase flow boiling heat transfer of R22 in channels. PMID:23956695

  18. Evaluation of Correlations of Flow Boiling Heat Transfer of R22 in Horizontal Channels

    PubMed Central

    Fang, Xiande; Li, Dingkun

    2013-01-01

    The calculation of two-phase flow boiling heat transfer of R22 in channels is required in a variety of applications, such as chemical process cooling systems, refrigeration, and air conditioning. A number of correlations for flow boiling heat transfer in channels have been proposed. This work evaluates the existing correlations for flow boiling heat transfer coefficient with 1669 experimental data points of flow boiling heat transfer of R22 collected from 18 published papers. The top two correlations for R22 are those of Liu and Winterton (1991) and Fang (2013), with the mean absolute deviation of 32.7% and 32.8%, respectively. More studies should be carried out to develop better ones. Effects of channel dimension and vapor quality on heat transfer are analyzed, and the results provide valuable information for further research in the correlation of two-phase flow boiling heat transfer of R22 in channels. PMID:23956695

  19. Overcoming the Limitations of the SIE and OME Methods in Assessing the Effects of Impurities in Temperature Fixed Points

    NASA Astrophysics Data System (ADS)

    Fahr, M.; Cundy, D. S.

    2015-08-01

    Impurities are still among the primary concerns regarding the realization of many fixed points of the International Temperature Scale (ITS-90). Several methods have been suggested to correct for these effects. The most promising strategy, with regard to the achievable uncertainty level, is the `sum of the individual estimates' (SIE) method. It involves a chemical analysis of the material and a calculation of each of the detected chemical species' effect on the phase-transition temperature of the fixed-point substance. This correction can be accurate only if all the detected impurities are completely dissolved. Given the recent evidence for insoluble impurities in metal fixed points, this strategy needs to be modified; otherwise, it may lead to an inaccurate estimation of the impurity-related effect on the fixed-point temperature. In this article, a correction method is set out that reflects the crucial distinction between soluble, insoluble, and partially soluble impurities. This `sum of the individual estimates for the dissolved species' (SIEDS) method starts from a chemical analysis but takes into account only the dissolved particles. For this purpose, different types of substances are considered as possible dissolved impurities and are discussed from a chemical point of view. For those impurities where data are insufficient, only an uncertainty estimation is possible. For this purpose, the `overall maximum estimate of the dissolved species' (OMEDS) method is derived from the SIEDS method as the new counterpart to the well-known `overall maximum estimate' (OME) method.

  20. Laboratory study of non-aqueous phase liquid and water co-boiling during thermal treatment.

    PubMed

    Zhao, C; Mumford, K G; Kueper, B H

    2014-08-01

    In situ thermal treatment technologies, such as electrical resistance heating and thermal conductive heating, use subsurface temperature measurements in addition to the analysis of soil and groundwater samples to monitor remediation performance. One potential indication of non-aqueous phase liquid (NAPL) removal is an increase in temperature following observations of a co-boiling plateau, during which subsurface temperatures remain constant as NAPL and water co-boil. However, observed co-boiling temperatures can be affected by the composition of the NAPL and the proximity of the NAPL to the temperature measurement location. Results of laboratory heating experiments using single-component and multi-component NAPLs showed that local-scale temperature measurements can be mistakenly interpreted as an indication of the end of NAPL-water co-boiling, and that significant NAPL saturations (1% to 9%) remain despite observed increases in temperature. Furthermore, co-boiling of multi-component NAPL results in gradually increasing temperature, rather than a co-boiling plateau. Measurements of gas production can serve as a complementary metric for assessing NAPL removal by providing a larger-scale measurement integrated over multiple smaller-scale NAPL locations. Measurements of the composition of the NAPL condensate can provide ISTT operators with information regarding the progress of NAPL removal for multi-component sources. PMID:24950371

  1. Computations of Boiling in Microgravity

    NASA Technical Reports Server (NTRS)

    Tryggvason, Gretar; Jacqmin, David

    1999-01-01

    The absence (or reduction) of gravity, can lead to major changes in boiling heat transfer. On Earth, convection has a major effect on the heat distribution ahead of an evaporation front, and buoyancy determines the motion of the growing bubbles. In microgravity, convection and buoyancy are absent or greatly reduced and the dynamics of the growing vapor bubbles can change in a fundamental way. In particular, the lack of redistribution of heat can lead to a large superheat and explosive growth of bubbles once they form. While considerable efforts have been devoted to examining boiling experimentally, including the effect of microgravity, theoretical and computational work is limited to very simple models. In this project, the growth of boiling bubbles is studied by direct numerical simulations where the flow field is fully resolved and the effects of inertia, viscosity, surface deformation, heat conduction and convection, as well as the phase change, are fully accounted for. The proposed work is based on previously funded NASA work that allowed us to develop a two-dimensional numerical method for boiling flows and to demonstrate the ability of the method to simulate film boiling. While numerical simulations of multi-fluid flows have been advanced in a major way during the last five years, or so, similar capability for flows with phase change are still in their infancy. Although the feasibility of the proposed approach has been demonstrated, it has yet to be extended and applied to fully three-dimensional simulations. Here, a fully three-dimensional, parallel, grid adaptive code will be developed. The numerical method will be used to study nucleate boiling in microgravity, with particular emphasis on two aspects of the problem: 1) Examination of the growth of bubbles at a wall nucleation site and the instabilities of rapidly growing bubbles. Particular emphasis will be put on accurately capturing the thin wall layer left behind as a bubble expands along a wall, on computing instabilities on bubble surfaces as bubbles grow, and on quantifying the effects of both these phenomena on heat transfer; and 2) Examination of the effect of shear flow on bubble growth and heat transfer.

  2. Turning point temperature and competition between relativistic and ponderomotive effects in self-focusing of laser beam in plasma

    SciTech Connect

    Bokaei, B.; Niknam, A. R.; Jafari Milani, M. R.

    2013-10-15

    The propagation characters of Gaussian laser beam in collisionless plasma are investigated by considering the ponderomotive and relativistic nonlinearities. The second-order differential equation of dimensionless beam width parameter is solved numerically, taking into account the effect of electron temperature. The results show that the ponderomotive force does not facilitate the relativistic self-focusing in all intensity ranges. In fact, there exists a certain intensity value that, if below this value, the ponderomotive nonlinearity can contribute to the relativistic self-focusing, or obstruct it, if above. It is also indicated that there is a temperature interval in which self-focusing can occur, while the beam diverges outside of this region. In addition, the results represent the existence of a “turning point temperature” in the mentioned interval that the self-focusing has the strongest power. The value of the turning point is dependent on laser intensity in which higher intensities result in higher turning point.

  3. Progress Towards the Determination of the Relationship of Triple-Point Temperature versus Isotopic Composition of Neon

    NASA Astrophysics Data System (ADS)

    Pavese, F.; Fellmuth, B.; Hill, K. D.; Head, D.; Hermier, Y.; Lipinski, L.; Nakano, T.; Peruzzi, A.; Sakurai, H.; Szmyrka-Grzebyk, A.; Steele, A. G.; Steur, P. P. M.; Tamura, O.; Tew, W. L.; Valkiers, S.; Wolber, L.

    2008-02-01

    Following the finalization of the work performed to establish the triple-point temperature versus isotopic composition relationship for protium (Metrologia 42, 171 (2005)) adopted into the ITS-90 definition by the International Committee for Weights and Measures (CIPM) in 2005, and a preliminary exploration of the variability in the triple-point temperature of neon gas samples arising from differences in isotopic composition (Anal. Chem. 77, 5076 (2005)), this article reports further progress toward the determination of a similar comprehensive relationship for neon, to be included in a future revision of the Technical Annexe to the mise en pratique of the kelvin. This progress article mainly concerns a set of gas samples used for the neon triple-point measurements during CCT-K2, and subsequently, others for which the isotopic compositions were recently measured. Recent high accuracy measurements of the corresponding thermal data are now available for many of these samples, but not yet for all of them.

  4. Corresponding states correlation for temperature dependent surface tension of normal saturated liquids

    NASA Astrophysics Data System (ADS)

    Yi, Huili; Tian, Jianxiang

    2014-07-01

    A new simple correlation based on the principle of corresponding state is proposed to estimate the temperature-dependent surface tension of normal saturated liquids. The correlation is a linear one and strongly stands for 41 saturated normal liquids. The new correlation requires only the triple point temperature, triple point surface tension and critical point temperature as input and is able to represent the experimental surface tension data for these 41 saturated normal liquids with a mean absolute average percent deviation of 1.26% in the temperature regions considered. For most substances, the temperature covers the range from the triple temperature to the one beyond the boiling temperature.

  5. Boyle temperature as a point of ideal gas in gentile statistics and its economic interpretation

    NASA Astrophysics Data System (ADS)

    Maslov, V. P.; Maslova, T. V.

    2014-07-01

    Boyle temperature is interpreted as the temperature at which the formation of dimers becomes impossible. To Irving Fisher's correspondence principle we assign two more quantities: the number of degrees of freedom, and credit. We determine the danger level of the mass of money M when the mutual trust between economic agents begins to fall.

  6. LANDSCAPE SCALE NON-POINT SOURCE POLLUTION TEMPERATURE ASSESSMENT AND TMDL DEVELOPMENT

    EPA Science Inventory

    THIS IS AN ONGOING PROJECT. Elevated river temperature is a significant water quality issue in the Pacific Northwest. For example, over 12,000 miles of perennial streams are designated 303(d) water quality limited due to temperature violation in the State of Oregon. Over t...

  7. Loop Heat Pipe Transient Behavior Using Heat Source Temperature for Set Point Control with Thermoelectric Converter on Reservoir

    NASA Technical Reports Server (NTRS)

    Ku, Jentung; Paiva, Kleber; Mantelli, Marcia

    2011-01-01

    The LHP operating temperature is governed by the saturation temperature of its reservoir. Controlling the reservoir saturation temperature is commonly done by cold biasing the reservoir and using electrical heaters to provide the required control power. With this method, the loop operating temperature can be controlled within 0.5K or better. However, because the thermal resistance that exists between the heat source and the LHP evaporator, the heat source temperature will vary with its heat output even if the LHP operating temperature is kept constant. Since maintaining a constant heat source temperature is of most interest, a question often raised is whether the heat source temperature can be used for LHP set point temperature control. A test program with a miniature LHP was carried out to investigate the effects on the LHP operation when the control temperature sensor was placed on the heat source instead of the reservoir. In these tests, the LHP reservoir was cold-biased and was heated by a control heater. Test results show that it was feasible to use the heat source temperature for feedback control of the LHP operation. In particular, when a thermoelectric converter was used as the reservoir control heater, the heat source temperature could be maintained within a tight range using a proportional-integral-derivative or on/off control algorithm. Moreover, because the TEC could provide both heating and cooling to the reservoir, temperature oscillations during fast transients such as loop startup could be eliminated or substantially reduced when compared to using an electrical heater as the control heater.

  8. Marangoni Effects in the Boiling of Binary Fluid Mixtures

    NASA Technical Reports Server (NTRS)

    Ahmed, Sayeed; Carey, Van P.; Motil, Brian

    1996-01-01

    Results of very recent experimental studies indicate that during nucleate boiling in some binary mixture, Marangoni effects augment the gravity driven flow of liquid towards the heated surface. With gravity present, it is impossible to separate the two effects. The reduced gravity environment gives an unique opportunity to explore th role of Marangoni effects on the boiling mechanisms free of gravitational body forces that obscure the role of such effects. However, recent experimental results suggest that under reduced gravity conditions, Marangoni effects is the dominant mechanism of vapor-liquid exchange at the surface for some binary mixture. To further explore such effects, experiments have been conducted with water/2-propanol mixtures at three different concentrations under normal gravity with different orientations of the heater surface and under reduce gravity aboard the DC-9 aircraft at NASA Lewis Research Center. The system pressure was sub atmospheric (approx. 8 kP at 1g(n)) and the bulk liquid temperature varied from low subcooling to near saturation. The molar concentrations of 2-propanol tested were 0.015, 0.025, and 0.1. Boiling curves were obtained both for high gravity (approx. 2g(n)) and reduce gravity (approx. 0.01g(n)). For each concentration of 2-propanol, the critical heat flux has been determined in the flight experiments only for reduced gravity conditions. Comparison of boiling curves and CHF obtained under l-g(n) an reduced gravity indicates that boiling mechanism in this mixtures is nearly independent of gravity. The results also indicate that the Marangoni mechanism is strong enough in these mixtures to sustain the boiling under reduced gravity conditions.

  9. Microscale Heaters Detailed Boiling Behavior in Normal Gravity and Microgravity

    NASA Technical Reports Server (NTRS)

    McQuillen, John B.

    2002-01-01

    Pool boiling in microgravity is an area of both scientific and practical interest. Conducting tests in microgravity, as well as lunar and Martian gravity, makes it possible to assess the effect of the density difference between the vapor and liquid phases on the overall boiling process and to assess the relative magnitude of these effects in comparison to other "forces" and phenomena, such as surface tension forces, liquid momentum forces, and microlayer evaporation. The microscale heater developed under a NASA Glenn Research Center grant serves as a unique tool to probe the fundamental mechanisms associated with pool boiling. An experimental package was designed and built by the University of Maryland and tested on the NASA Johnson Space Center KC-135 experimental aircraft and a NASA WFF Terrier Orion Sounding Rocket under NASA Grants NAG3-2228 and NCC3-783. A square array of 96 microscale heaters was constructed and installed into a special boiling chamber. A fluorinert, FC-72, was used as the test fluid. A variety of tests were conducted at different pressures, heater wall temperatures, bulk fluid temperatures, and gravity levels.

  10. ATWS Analysis with an Advanced Boiling Curve Approach within COBRA 3-CP

    SciTech Connect

    Gensler, A.; Knoll, A.; Kuehnel, K.

    2007-07-01

    In 2005 the German Reactor Safety Commission issued specific requirements on core coolability demonstration for PWR ATWS (anticipated transients without scram). Thereupon AREVA NP performed detailed analyses for all German PWRs. For a German KONVOI plant the results of an ATWS licensing analysis are presented. The plant dynamic behavior is calculated with NLOOP, while the hot channel analysis is performed with the thermal hydraulic computer code COBRA 3-CP. The application of the fuel rod model included in COBRA 3-CP is essential for this type of analysis. Since DNB (departure from nucleate boiling) occurs, the advanced post DNB model (advanced boiling curve approach) of COBRA 3-CP is used. The results are compared with those gained with the standard BEEST model. The analyzed ATWS case is the emergency power case 'loss of main heat sink with station service power supply unavailable'. Due to the decreasing coolant flow rate during the transient the core attains film boiling conditions. The results of the hot channel analysis strongly depend on the performance of the boiling curve model. The BEEST model is based on pool boiling conditions whereas typical PWR conditions - even in most transients - are characterized by forced flow for which the advanced boiling curve approach is particularly suitable. Compared with the BEEST model the advanced boiling curve approach in COBRA 3-CP yields earlier rewetting, i.e. a shorter period in film boiling. Consequently, the fuel rod cladding temperatures, that increase significantly due to film boiling, drop back earlier and the high temperature oxidation is significantly diminished. The Baker-Just-Correlation was used to calculate the value of equivalent cladding reacted (ECR), i.e. the reduction of cladding thickness due to corrosion throughout the transient. Based on the BEEST model the ECR value amounts to 0.4% whereas the advanced boiling curve only leads to an ECR value of 0.2%. Both values provide large margins to the 17% ECR limit. The maximum cladding temperature calculated with both models is almost identical. It results in approximately 830 deg. C, i.e. far below the embrittlement temperature (stipulated at 1200 deg. C). Core coolability was demonstrated with both models, with the BEEST model and with the advanced boiling curve approach. However, the advanced boiling curve approach results in more realistic values and reveals that a much higher safety margin exists. This advantage can be applied to all types of transient hot channel analyses which have to treat film boiling phases. (authors)

  11. The effects of freezing, boiling and degreasing on the microstructure of bone.

    PubMed

    Lander, S L; Brits, D; Hosie, M

    2014-04-01

    The histology of bone has been a useful tool in research. It is commonly used to estimate the age of an individual at death, to assess if the bone is of human or non-human origin and in trauma analysis. Factors that affect the histology of bone include age, sex, population affinity and burning to name but a few. Other factors expected to affect bone histology are freezing, boiling and degreasing but very little information is available for freezing and the effect thereof, and it is unknown if boiling and degreasing affects bone histology. The aim of this study was to assess the effects of freezing, freezing and boiling, and freezing, boiling and degreasing on the histological structure of compact bone. Five cadaver tibiae were frozen at -20C for 21 days followed by segments being boiled in water for three days and degreased in trichloroethylene at 82C for three days. Anterior midshaft sections were prepared as ground sections and for Scanning Electron Microscopy (SEM). Quantitatively, there were no significant differences between freezing, boiling and degreasing; however, qualitative differences were observed using SEM. After being frozen the bone displayed cracks and after boiling the bones displayed erosion pits on the surface. It is suggested that further research, using different durations and temperatures for boiling and freezing be undertaken on bone samples representing different ages and various skeletal elements. PMID:24331160

  12. The Physics of Boiling at Burnout

    NASA Technical Reports Server (NTRS)

    Theofanous, T. G.; Tu, J. P.; Dinh, T. N.; Salmassi, T.; Dinh, A. T.; Gasljevic, K.

    2000-01-01

    The basic elements of a new experimental approach for the investigation of burnout in pool boiling are presented. The approach consists of the combined use of ultrathin (nano-scale) heaters and high speed infrared imaging of the heater temperature pattern as a whole, in conjunction with highly detailed control and characterization of heater morphology at the nano and micron scales. It is shown that the burnout phenomenon can be resolved in both space and time. Ultrathin heaters capable of dissipating power levels, at steady-state, of over 1 MW/square m are demonstrated. A separation of scales is identified and it is used to transfer the focus of attention from the complexity of the two-phase mixing layer in the vicinity of the heater to a micron-scaled microlayer and nucleation and associated film-disruption processes within it.

  13. A hybrid Raman/EFPI/FBG sensing system for distributed temperature and key-point pressure measurements

    NASA Astrophysics Data System (ADS)

    Chen, Ke; Zhou, Xinlei; Yang, Yang; Yu, Qingxu

    2015-08-01

    We demonstrate a hybrid sensing scheme, combining the incoherent optical frequency domain reflectometry (IOFDR) based Raman distributed temperature sensor (DTS) with the extrinsic Fabry-Perot interferometer (EFPI) based pressure sensor, for down-hole monitoring. The pressure measurement is compensated by a fiber Bragg grating (FBG) based temperature sensor. By using a laser diode as the common light source, a hybrid Raman/EFPI/FBG sensing system has been developed with a single fiber. The stimulated emission light and the spontaneous emission light of the laser diode are used for DTS and EFPI-FBG interrogations respectively. There can be no overlap between the spectral range of the Raman backscattered light and the spectral range of the reflected light from the EFPI-FBG sensor. Distributed temperature and pressure can thus be measured by using wavelength-division multiplexing (WDM) technology. Experimental results show that, both the distributed temperature and the key-point pressure can be measured alternatively with little interference.

  14. Subcooled flow film boiling across a horizontal cylinder. Part I. Analytical model

    SciTech Connect

    Chou, X.S.; Witte, L.C. )

    1995-02-01

    An analytical model of stable subcooled flow film boiling on the front of a horizontal cylinder and a model for the wake region downstream of the flow separation points were developed. The flow and temperature fields upstream of the separation points were represented by a 'local-similarity' solution obtained through a rigorous mathematical transformation. The transformed governing equations were solved numerically using a finite-difference scheme. Numerical solutions for the vapor layer thickness, the velocity, and the temperature fields were obtained for both the liquid and vapor layers. The results showed that the liquid boundary layer was thicker than the vapor film. Increases in the liquid subcooling and in the free-stream velocity decreased the vapor layer thickness. The influence of convection in the vapor layer is small yielding a near-linear temperature distribution. A two-dimensional vapor wake model was developed based on mass and energy balances. Numerical solutions, including the vapor layer thickness and the temperature field of the front part and the wake part, were matched at the separation points. The results showed that increases in the liquid subcooling decreased the vapor layer thickness. Heat transfer in the wake region can amount up to 20 percent of the heat transfer in the forward region and should not be neglected especially at high subcooling. 19 refs., 8 figs.

  15. High freezing point fuels used for aviation turbine engines

    NASA Technical Reports Server (NTRS)

    Friedman, R.

    1979-01-01

    Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating.

  16. Development of a Multi-Point Pyrometer System (MPPS) for measuring surface temperature and emissivity

    SciTech Connect

    Benton, R.D.; Jang, Ping-Rey

    1993-06-01

    In support of the US DOE MHD research program, the Diagnostic Instrumentation and Analysis Laboratory (DIAL) has been actively engaged in developing and applying advanced optical diagnostic techniques and instrumentation systems to high temperature coal-fired gas streams for over a decade. One of the earliest diagnostic systems developed by DIAL was a two color pyrometer (TCP). In this system, two commercial single-color pyrometers and a microprocessor system were used to form a TCP which can make accurate measurements of surfaces of unknown emissivity and temperature. This system has been used extensively to make measurements in support of the national MHD program. This report describes this system.

  17. Performance of the NO{sub x} emissions advisor and advanced steam temperature control at Possum Point Station

    SciTech Connect

    Leigh, M.; Labbe, D.

    1995-10-01

    Virginia Power installed Stone and Webster`s NO{sub x} Emissions Advisor and Advanced Steam Temperature Control Systems on Possum Point Units 3 and 4 during the Spring of 1995 to achieve near-term NO{sub x} compliance objectives and improve thermal performance. The installation of the advanced control and automation systems was integrated into the existing control system using standard hardware and software. The advanced control systems operate under Windows-NT on a Pentium personal computer (PC) in a multi-process environment, exchanging data with the distributed control system (DCS) through a dedicated serial link. Testing has demonstrated NO, reductions of greater than 20 percent through the application of the NO{sub x} Emissions Advisor on these units, while maintaining steam temperatures and unit efficiency. Possum Point Power Station Units 3 and 4 are pulverized coal, tangentially fired boilers, producing 107 and 232 MW, respectively.

  18. A review on saturated boiling of liquids on tube bundles

    NASA Astrophysics Data System (ADS)

    Swain, Abhilas; Das, Mihir Kumar

    2014-05-01

    A review of recent investigation on boiling of saturated liquids over plain and enhanced tube bundles has been carried out taking the earlier review works as reference point. The experimental observations of various geometry and performance parameters studied by researchers are analyzed keeping current demand of industries in design and development of compact, efficient heat exchanging devices. The study shows that tube spacing plays an important role in determination of compactness of the heat exchanger.

  19. Finite-temperature scaling of spin correlations in an experimental realization of the one-dimensional Ising quantum critical point

    NASA Astrophysics Data System (ADS)

    Hlg, M.; Hvonen, D.; Guidi, T.; Quintero-Castro, D. L.; Boehm, M.; Regnault, L. P.; Hagiwara, M.; Zheludev, A.

    2015-07-01

    Inelastic neutron scattering is used to study the finite-temperature scaling behavior of the local dynamic structure factor in the quasi-one-dimensional quantum antiferromagnet Ni[N ,N'-bis(3-aminopropyl)propane-1,3-diamine] (? -NO2) ClO4 (NTENP), at its field-induced Ising quantum critical point. The validity and the limitations of the theoretically predicted scaling relations are tested.

  20. An InGaAs detector based radiation thermometer and fixed-point blackbodies for temperature scale realization at NIM

    SciTech Connect

    Hao, X.; Yuan, Z.; Wang, J.; Lu, X.

    2013-09-11

    In this paper, we describe an InGaAs detector based radiation thermometer (IRT) and new design of fixed-point blackbodies, including Sn, Zn, Al and Cu, for the establishment of a temperature scale from 200 °C to 1085 °C at the National Institute of Metrology of China. The construction and calibration of the IRT with the four fixed-point blackbodies are described. Characteristics of the IRT, such as the size-of-source effect, the amplifier performance and its stability are determined. The design of the four fixed-points, with 10 mm diameter of aperture and 0.9999 emissivity, is described. The uncertainty of the scale realization is elaborated.

  1. An InGaAs detector based radiation thermometer and fixed-point blackbodies for temperature scale realization at NIM

    NASA Astrophysics Data System (ADS)

    Hao, X.; Yuan, Z.; Wang, J.; Lu, X.

    2013-09-01

    In this paper, we describe an InGaAs detector based radiation thermometer (IRT) and new design of fixed-point blackbodies, including Sn, Zn, Al and Cu, for the establishment of a temperature scale from 200 °C to 1085 °C at the National Institute of Metrology of China. The construction and calibration of the IRT with the four fixed-point blackbodies are described. Characteristics of the IRT, such as the size-of-source effect, the amplifier performance and its stability are determined. The design of the four fixed-points, with 10 mm diameter of aperture and 0.9999 emissivity, is described. The uncertainty of the scale realization is elaborated.

  2. Rotational cars application to simultaneous and multiple-point temperature and concentration determination in a turbulent flow

    NASA Technical Reports Server (NTRS)

    Snow, J. B.; Murphy, D. V.; Chang, R. K.

    1984-01-01

    Coherent Anti-stokes Raman Scattering (CARS) from the pure rotational Raman lines of N2 is employed to measure the instantaneous rotational temperature of N2 gas at room temperature and below with good spatial resolution. A broad-bandwidth dye laser is used to obtain the entire rotational spectrum from a signal laser pulse; the CARS signal is then dispersed by a spectrograph and recorded on an optical multichannel analyzer. A best-fit temperature is found in several seconds with the aid of a computer for each experimental spectrum by a least squares comparison with calculated spectra. The model used to calculate the theoretical spectra incorporates the temperature and pressure dependence of the pressure-broadened rotational Raman lines, includes the nonresonant background susceptibility, and assumes that the pump laser has a finite linewidth. Temperatures are fit to experimental spectra recorded over the temperature range of 135 to 296K, and over the pressure range of 0.13 to 15.3 atm. In addition to the spatially resolved single point work, we have used multipoint CARS to obtain information from many spatially resolved volume elements along a cylindrical line (0.1 x 0.1 x 2.0 mm). We also obtained qualitative information on the instantaneous species concentration and temperature at 20 spatially resolved volume elements (0.1 x 0.1 x 0.1 mm) along a line.

  3. Measurements and calculations of the fuel temperature coefficient of reactivity for the Hinkley Point 'B' advanced gas-cooled reactor

    SciTech Connect

    Richard, A.; Telford, R.

    1982-01-01

    Tests have been carried out on one of the advanced gas-cooled reactors (AGRs) at Hinkley Point to determine the fuel temperature coefficient of reactivity, an important safety-related parameter. Reactor neutron flux was measured during transients induced by movement of a bank of control rods from one steady position to another. An inverse kinetics analysis was applied to the recorded flux transient to determine the reactivity change as the fuel temperature changed, and the variation of mean fuel temperature was derived from the flux transient by a multiplane thermal-hydraulics code representing an AGR fuel channel. The fuel temperature coefficient was then obtained from the slope of a plot of core reactivity against fuel temperature. The uncertainty to be applied to the derived temperature coefficient has been shown to be approximately + or - 10% at the one standard deviation level. The experimental technique has been found to be simple to apply on a commericial reactor and has given consistent results over a range of reactor operating conditions. Calculations of fuel temperature coefficients of reactivity (based on the lattice code, ARGOSY) have been carried out and reactor averaged values deduced for comparison with experiment. The calculated and measured coefficients agree to within one standard deviation over a range of core irradiations and power levels.

  4. Coherent anti-stokes Raman spectroscopy system for point temperature and major species concentration measurement

    SciTech Connect

    Singh, J.P.; Yueh, Fang-Yu

    1993-10-01

    The Coherent anti-Stokes Raman Spectroscopy system (CARS) has been developed as a laser-based, advanced, combustion-diagnostic technique to measure temperature and major species concentration. Principles of operation, description of the system and its capabilities, and operational details of this instrument are presented in this report.

  5. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... sensor or thermometer required by § 153.440(a)(3) or (c). If a portable thermometer is used, it must be located as prescribed for the temperature sensor in § 153.440(a)(3). (2) A total of 2 readings must...

  6. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

  7. Modeling acid-gas generation from boiling chloride brines

    PubMed Central

    2009-01-01

    Background This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Results Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150°C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. Conclusion The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150°C). PMID:19917082

  8. Temperature effect on the build-up of exponentially growing polyelectrolyte multilayers. An exponential-to-linear transition point.

    PubMed

    Vikulina, Anna S; Anissimov, Yuri G; Singh, Prateek; Prokopović, Vladimir Z; Uhlig, Katja; Jaeger, Magnus S; von Klitzing, Regine; Duschl, Claus; Volodkin, Dmitry

    2016-03-01

    In this study, the effect of temperature on the build-up of exponentially growing polyelectrolyte multilayer films was investigated. It aims at understanding the multilayer growth mechanism as crucially important for the fabrication of tailor-made multilayer films. Model poly(l-lysine)/hyaluronic acid (PLL/HA) multilayers were assembled in the temperature range of 25-85 °C by layer-by-layer deposition using a dipping method. The film growth switches from the exponential to the linear regime at the transition point as a result of limited polymer diffusion into the film. With the increase of the build-up temperature the film growth rate is enhanced in both regimes; the position of the transition point shifts to a higher number of deposition steps confirming the diffusion-mediated growth mechanism. Not only the faster polymer diffusion into the film but also more porous/permeable film structure are responsible for faster film growth at higher preparation temperature. The latter mechanism is assumed from analysis of the film growth rate upon switching of the preparation temperature during the film growth. Interestingly, the as-prepared films are equilibrated and remain intact (no swelling or shrinking) during temperature variation in the range of 25-45 °C. The average activation energy for complexation between PLL and HA in the multilayers calculated from the Arrhenius plot has been found to be about 0.3 kJ mol(-1) for monomers of PLL. Finally, the following processes known to be dependent on temperature are discussed with respect to the multilayer growth: (i) polymer diffusion, (ii) polymer conformational changes, and (iii) inter-polymer interactions. PMID:26911320

  9. Nucleate pool boiling in the long duration low gravity environment of the Space Shuttle

    NASA Technical Reports Server (NTRS)

    Hasan, M. M.; Lin, C. S.; Knoll, R. H.; Bentz, M. D.; Meserole, J. S.

    1993-01-01

    The results are presented of an experimental study of nucleate pool boiling performed in the low gravity environment of the space shuttle. Photographic observations of pool boiling in Freon 113 were obtained during the 'Tank Pressure Control Experiment,' flown on the Space Transportation System, STS-43 in August 1991. Nucleate boiling data from large (relative to bubble size) flat heating surfaces (0.1046 by 0.0742 m) was obtained at very low heat fluxes (0.22 to 1.19 kW/sq m). The system pressure and the bulk liquid subcooling varied in the range of 40 to 60 kPa and 3 to 5 C respectively. Thirty-eight boiling tests, each of 10-min duration for a given heat flux, were conducted. Measurements included the heater power, heater surface temperature, the liquid temperature and the system pressure as functions of heating time. Video data of the first 2 min of heating was recorded for each test. In some tests the video clearly shows the inception of boiling and the growth and departure of bubbles from the surface during the first 2 min of heating. In the absence of video data, the heater temperature variation during heating shows the inception of boiling and stable nucleate boiling. During the stable nucleate boiling, the wall superheat varied between 2.8 to 3.8 C for heat fluxes in the range of 0.95 to 1.19 kW/sq m. The wall superheat at the inception of boiling varied between 2 to 13 C.

  10. Simulation of low-power, low-flow sodium boiling with a transparent, atmospheric pressure water loop

    SciTech Connect

    Levin, A.E.; Montgomery, B.H.; Carbajo, J.J.; Wantland, J.L.

    1984-03-01

    Experiments have been performed in a transparent, single-tube boiling loop, using water as the working fluid, to simulate sodium boiling behavior in a similar geometry. Testing has been performed over a wide range of flows, powers, and temperatures to examine the onset of boiling, flow regimes, oscillatory flow behavior, and dryout. Analysis of experimental data has been aided by the use of high-speed motion pictures. Instrument data from selected tests are presented and discussed, as well as results from computer simulations of the experiments. The computer model is presented, and scaling laws for the comparison of water and sodium oscillatory boiling are discussed. Comparison of the data from this loop with sodium boiling data has shown that an atmospheric pressure, two-phase water system is a good simulant for boiling liquid sodium. 11 refs., 91 figs., 2 tabs.

  11. A study of forced convection boiling under reduced gravity

    NASA Technical Reports Server (NTRS)

    Merte, Herman, Jr.

    1992-01-01

    This report presents the results of activities conducted over the period 1/2/85-12/31/90, in which the study of forced convection boiling under reduced gravity was initiated. The study seeks to improve the understanding of the basic processes that constitute forced convection boiling by removing the buoyancy effects which may mask other phenomena. Specific objectives may also be expressed in terms of the following questions: (1) what effects, if any, will the removal of body forces to the lowest possible levels have on the forced convection boiling heat transfer processes in well-defined and meaningful circumstances? (this includes those effects and processes associated with the nucleation or onset of boiling during the transient increase in heater surface temperature, as well as the heat transfer and vapor bubble behaviors with established or steady-state conditions); and (2) if such effects are present, what are the boundaries of the relevant parameters such as heat flux, heater surface superheat, fluid velocity, bulk subcooling, and geometric/orientation relationships within which such effects will be produced?

  12. Sensing Atomic Motion from the Zero Point to Room Temperature with Ultrafast Atom Interferometry

    NASA Astrophysics Data System (ADS)

    Johnson, K. G.; Neyenhuis, B.; Mizrahi, J.; Wong-Campos, J. D.; Monroe, C.

    2015-11-01

    We sense the motion of a trapped atomic ion using a sequence of state-dependent ultrafast momentum kicks. We use this atom interferometer to characterize a nearly pure quantum state with n =1 phonon and accurately measure thermal states ranging from near the zero-point energy to n 104, with the possibility of extending at least 100 times higher in energy. The complete energy range of this method spans from the ground state to far outside of the Lamb-Dicke regime, where atomic motion is greater than the optical wavelength. Apart from thermometry, these interferometric techniques are useful for characterizing ultrafast entangling gates between multiple trapped ions.

  13. Heat Transfer Performances of Pool Boiling on Metal-Graphite Composite Surfaces

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Yang, Wen-Jei

    2000-01-01

    Nucleate boiling, especially near the critical heat flux (CHF), can provide excellent economy along with high efficiency of heat transfer. However, the performance of nucleate boiling may deteriorate in a reduced gravity environment and the nucleate boiling usually has a potentially dangerous characteristic in CHF regime. That is, any slight overload can result in burnout of the boiling surface because the heat transfer will suddenly move into the film-boiling regime. Therefore, enhancement of nucleate boiling heat transfer becomes more important in reduced gravity environments. Enhancing nucleate boiling and critical heat flux can be reached using micro-configured metal-graphite composites as the boiling surface. Thermocapillary force induced by temperature difference between the graphite-fiber tips and the metal matrix, which is independent of gravity, will play an important role in bubble detachment. Thus boiling heat transfer performance does not deteriorate in a reduced-gravity environment. Based on the existing experimental data, and a two-tier theoretical model, correlation formulas are derived for nucleate boiling on the copper-graphite and aluminum-graphite composite surfaces, in both the isolated and coalesced bubble regimes. Experimental studies were performed on nucleate pool boiling of pentane on cooper-graphite (Cu-Gr) and aluminum-graphite (Al-Gr) composite surfaces with various fiber volume concentrations for heat fluxes up to 35 W per square centimeter. It is revealed that a significant enhancement in boiling heat transfer performance on the composite surfaces is achieved, due to the presence of micro-graphite fibers embedded in the matrix. The onset of nucleate boiling (the isolated bubble regime) occurs at wall superheat of about 10 C for the Cu-Gr surface and 15 C for the Al-Gr surface, much lower than their respective pure metal surfaces. Transition from an isolated bubble regime to a coalesced bubble regime in boiling occurs at a superheat of about 14 C on Cu-Gr surface and 19 C on Al-Gr surface.

  14. CHIMNEY FOR BOILING WATER REACTOR

    DOEpatents

    Petrick, M.

    1961-08-01

    A boiling-water reactor is described which has vertical fuel-containing channels for forming steam from water. Risers above the channels increase the head of water radially outward, whereby water is moved upward through the channels with greater force. The risers are concentric and the radial width of the space between them is somewhat small. There is a relatively low rate of flow of water up through the radially outer fuel-containing channels, with which the space between the risers is in communication. (AE C)

  15. Boils

    MedlinePLUS

    ... They are most often caused by the bacteria Staphylococcus aureus. They can also be caused by other types of bacteria or fungi found on the skin's surface. Damage to the hair follicle allows the infection ...

  16. Investigation of the effects of pressure gradient, temperature and wall temperature ratio on the stagnation point heat transfer for circular cylinders and gas turbine vanes

    NASA Technical Reports Server (NTRS)

    Nagamatsu, H. T.; Duffy, R. E.

    1984-01-01

    Low and high pressure shock tubes were designed and constructed for the purpose of obtaining heat transfer data over a temperature range of 390 to 2500 K, pressures of 0.3 to 42 atm, and Mach numbers of 0.15 to 1.5 with and without pressure gradient. A square test section with adjustable top and bottom walls was constructed to produce the favorable and adverse pressure gradient over the flat plate with heat gages. A water cooled gas turbine nozzle cascade which is attached to the high pressure shock tube was obtained to measuse the heat flux over pressure and suction surfaces. Thin-film platinum heat gages with a response time of a few microseconds were developed and used to measure the heat flux for laminar, transition, and turbulent boundary layers. The laminar boundary heat flux on the shock tube wall agreed with Mirel's flat plate theory. Stagnation point heat transfer for circular cylinders at low temperature compared with the theoretical prediction, but for a gas temperature of 922 K the heat fluxes were higher than the predicted values. Preliminary flat plate heat transfer data were measured for laminar, transition, and turbulent boundary layers with and without pressure gradients for free-stream temperatures of 350 to 2575 K and flow Mach numbers of 0.11 to 1.9. The experimental heat flux data were correlated with the laminar and turbulent theories and the agreement was good at low temperatures which was not the case for higher temperatures.

  17. Wireless SAW sensor for high temperature applications: material point of view

    NASA Astrophysics Data System (ADS)

    Elmazria, Omar; Aubert, Thierry

    2011-06-01

    In addition to being small, simple and robust, surface acoustic wave (SAW) devices have the advantage of being passive (batteryless), remotely requestable (wireless) and inexpensive if fabricated on a large scale. The use of SAW devices as passive and wireless sensors allows them to operate in extreme conditions such as those with high levels of radiation, high temperatures up to 1000C, or electromagnetic interference, in which no other wireless sensor can operate. This is obviously conditioned by the fact that the materials constituting the device can withstand these harsh conditions. General principle of the SAW sensor in wireless configuration is developed and a review of recent works concerning the field of high temperature applications is presented with a specific attention given to the characterization of materials constituting the SAW device: piezoelectric substrate and metallic electrodes.

  18. Point defects in crystalline SiO2 - Thermally stimulated luminescence above room temperature

    NASA Astrophysics Data System (ADS)

    Jani, M. G.; Halliburton, L. E.; Kohnke, E. E.

    1983-11-01

    The thermally stimulated luminescence (TSL) response above room temperature is reported for two synthetic stones and one natural stone. Comparisons are made between the TSL obtained from swept and unswept samples cut from adjacent positions in the three stones. For each sample, data were taken with three different initial irradiation temperatures in order to make direct comparisons with the known behavior of defects in quartz. Electron spin resonance and infrared absorption data were also obtained from the samples. A number of TSL peaks were found in the 60-130 C region and have been tentatively associated with hydrogen in the crystal. More intense peaks were found in the 200-300 C region, but only in unswept samples after an ice bath or ice bath plus 77 K irradiation. These peaks are attributed to electron-hole recombination at (AlO4) exp 0 centers as a result of electron release from alkali-associated electron traps.

  19. An optical fibre sensor for combined point pressure measurement and spatially resolved temperature measurement

    NASA Astrophysics Data System (ADS)

    Duraibabu, DineshBabu; Poeggel, Sven; Lehzen, Kevin; Dooly, Gerard; Lewis, Elfed; Leen, Gabriel; Newe, Thomas

    2015-09-01

    In this paper, two optical fibre sensors are presented: 1) based on extrinsic Fabry-Perot Interferometer (EFPI) with Fibre Bragg Grating array and 2) and EFPI sensor with a chirped Fibre Bragg grating (CFBG). The CFBG with EFPI sensor fabrication technique is described and temperature response of both sensors is presented. Such sensors have many potential applications including applications in the aerospace industry and medical industry (e.g. radio frequency thermal ablation of tumors).

  20. Increasing Boiling Heat Transfer using Low Conductivity Materials

    PubMed Central

    Mahamudur Rahman, Md; Pollack, Jordan; McCarthy, Matthew

    2015-01-01

    We report the counterintuitive mechanism of increasing boiling heat transfer by incorporating low-conductivity materials at the interface between the surface and fluid. By embedding an array of non-conductive lines into a high-conductivity substrate, in-plane variations in the local surface temperature are created. During boiling the surface temperature varies spatially across the substrate, alternating between high and low values, and promotes the organization of distinct liquid and vapor flows. By systematically tuning the peak-to-peak wavelength of this spatial temperature variation, a resonance-like effect is seen at a value equal to the capillary length of the fluid. Replacing ~18% of the surface with a non-conductive epoxy results in a greater than 5x increase in heat transfer rate at a given superheat temperature. This drastic and counterintuitive increase is shown to be due to optimized bubble dynamics, where ordered pathways allow for efficient removal of vapor and the return of replenishing liquid. The use of engineered thermal gradients represents a potentially disruptive approach to create high-efficiency and high-heat-flux boiling surfaces which are naturally insensitive to fouling and degradation as compared to other approaches. PMID:26281890

  1. Increasing Boiling Heat Transfer using Low Conductivity Materials

    NASA Astrophysics Data System (ADS)

    Mahamudur Rahman, Md; Pollack, Jordan; McCarthy, Matthew

    2015-08-01

    We report the counterintuitive mechanism of increasing boiling heat transfer by incorporating low-conductivity materials at the interface between the surface and fluid. By embedding an array of non-conductive lines into a high-conductivity substrate, in-plane variations in the local surface temperature are created. During boiling the surface temperature varies spatially across the substrate, alternating between high and low values, and promotes the organization of distinct liquid and vapor flows. By systematically tuning the peak-to-peak wavelength of this spatial temperature variation, a resonance-like effect is seen at a value equal to the capillary length of the fluid. Replacing ~18% of the surface with a non-conductive epoxy results in a greater than 5x increase in heat transfer rate at a given superheat temperature. This drastic and counterintuitive increase is shown to be due to optimized bubble dynamics, where ordered pathways allow for efficient removal of vapor and the return of replenishing liquid. The use of engineered thermal gradients represents a potentially disruptive approach to create high-efficiency and high-heat-flux boiling surfaces which are naturally insensitive to fouling and degradation as compared to other approaches.

  2. Length Scale and Gravity Effects on Microgravity Boiling Heat Transfer

    NASA Technical Reports Server (NTRS)

    Kim, Jungho; McQuillen, John; Balombin, Joe

    2002-01-01

    Boiling is a complex phenomenon where hydrodynamics, heat transfer, mass transfer, and interfacial phenomena are tightly interwoven. An understanding of boiling and critical heat flux in microgravity environments is of importance to space based hardware and processes such as heat exchange, cryogenic fuel storage and transportation, electronic cooling, and material processing due to the large amounts of heat that can be removed with relatively little increase in temperature. Although research in this area has been performed in the past four decades, the mechanisms by which heat is removed from surfaces in microgravity are still unclear. In earth gravity, buoyancy is an important parameter that affects boiling heat transfer through the rate at which bubbles are removed from the surface. A simple model describing the bubble departure size based on a quasistatic force balance between buoyancy and surface tension is given by the Fritz [I] relation: Bo(exp 1/2) = 0.0208 theta where Bo is the ratio between buoyancy and surface tension forces. For small, rapidly growing bubbles, inertia associated with the induced liquid motion can also cause bubble departure. In microgravity, the magnitude of effects related to natural convection and buoyancy are small and physical mechanisms normally masked by natural convection in earth gravity such as Marangoni convection can substantially influence the boiling and vapor bubble dynamics. CHF (critical heat transfer) is also substantially affected by microgravity. In 1 g environments, Bo has been used as a correlating parameter for CHF. Zuber's CHF model for an infinite horizontal surface assumes that vapor columns formed by the merger of bubbles become unstable due to a Helmholtz instability blocking the supply of liquid to the surface. The jets are spaced lambda(sub D) apart, where lambda(sub D) = 2pi square root of 3[(sigma)/(g(rho(sub l) - rho(sub v)](exp 1/2) = 2pi square root of 3 L Bo(exp -1/2) = square root of 3 lambda(sub c) and is the wavelength that amplifies most rapidly. The critical wavelength, lambda(sub c), is the wavelength below which a vapor layer underneath a liquid layer is stable. For heaters with Bo smaller than about 3 (heaters smaller than lambda(sub D)), the above model is not applicable, and surface tension effects dominate. Bubble coalescence is thought to be the mechanism for CHF under these conditions. Small Bo can result by decreasing the size of a heater in earth gravity, or by operating a large heater in a lower gravity environment. In the microgravity of space, even large heaters can have low Bo, and models based on Helmholtz instability should not be applicable. The macrolayer model of Haramura and Katto is dimensionally equivalent to Zuber's model and has the same dependence on gravity, so it should not be applicable as well. The goal of this work is to determine how boiling heat transfer mechanisms in a low-g environment are altered from those at higher gravity levels. Boiling data using a microheater array was obtained under gravity environments ranging from 1.8 g to 0.02 g with heater sizes ranging from 2.7 mm to 1 mm. The boiling behavior for 2.7 mm at 0.02 g looked quite similar to boiling on the 1 mm heater at 1 g-the formation of a large primary bubble surrounded by smaller satellite bubbles was observed under both conditions. The similarity suggests that for heaters smaller than some fraction of I(sub c), coalescence and surface tension dominate boiling heat transfer. It also suggests that microgravity boiling can be studied by studying boiling on very small heaters.

  3. Film Boiling of Saturated Nitrogen in Horizontal Tubes of Double Pipe Heat Exchangers

    SciTech Connect

    Chen, X.L.; Sutton, W.H.; Sanchez, M.A.

    2002-07-01

    The data of a nitrogen film boiling experiment in horizontal tubes are presented in the paper. The experiment condition was the same as the actual application, which is neither a uniform heat flux nor a uniform wall temperature condition. The purpose is trying to find a good method to calculate the heat transfer coefficient for actual film boiling applications. The experiment data are carefully analyzed and compared with some current available correlations. A combined method is recommended in this paper for average heat transfer coefficient of film boiling in horizontal tubes based on the understanding of flow regimes. (authors)

  4. New flow boiling heat transfer model for hydrocarbons evaporating inside horizontal tubes

    SciTech Connect

    Chen, G. F.; Gong, M. Q.; Wu, J. F.; Zou, X.; Wang, S.

    2014-01-29

    Hydrocarbons have high thermodynamic performances, belong to the group of natural refrigerants, and they are the main components in mixture Joule-Thomson low temperature refrigerators (MJTR). New evaluations of nucleate boiling contribution and nucleate boiling suppression factor in flow boiling heat transfer have been proposed for hydrocarbons. A forced convection heat transfer enhancement factor correlation incorporating liquid velocity has also been proposed. In addition, the comparisons of the new model and other classic models were made to evaluate its accuracy in heat transfer prediction.

  5. Pervaporation investigation of recovery of volatile compounds from brown crab boiling juice.

    PubMed

    Martnez, Rodrigo; Sanz, M Teresa; Beltrn, Sagrario

    2014-10-01

    Pervaporation has been used to obtain aroma concentrates from brown crab boiling juice. The boiling juice and the obtained permeate have been analysed by Headspace Solid Phase Dynamic Extraction Gas Chromatography/Mass Spectrometry. The effect of feed temperature on the pervaporation performance of the membrane has been analysed. The permeate aroma profile, at 25 ? and 40 ?, was different from that of the boiling juice. Enrichment factors for some of the volatile compounds were much lower than those obtained in model aqueous dilute solutions. Pervaporation performance can be significantly improved by modifying the permeant circuit to include two condensation stages. PMID:23897977

  6. New flow boiling heat transfer model for hydrocarbons evaporating inside horizontal tubes

    NASA Astrophysics Data System (ADS)

    Chen, G. F.; Gong, M. Q.; Wang, S.; Wu, J. F.; Zou, X.

    2014-01-01

    Hydrocarbons have high thermodynamic performances, belong to the group of natural refrigerants, and they are the main components in mixture Joule-Thomson low temperature refrigerators (MJTR). New evaluations of nucleate boiling contribution and nucleate boiling suppression factor in flow boiling heat transfer have been proposed for hydrocarbons. A forced convection heat transfer enhancement factor correlation incorporating liquid velocity has also been proposed. In addition, the comparisons of the new model and other classic models were made to evaluate its accuracy in heat transfer prediction.

  7. Steady State Film Boiling Heat Transfer Simulated With Trace V4.160

    SciTech Connect

    Audrius Jasiulevicius; Rafael Macian-Juan

    2006-07-01

    This paper presents the results of the assessment and analysis of TRACE v4.160 heat transfer predictions in the post-CHF (critical heat flux) region and discusses the possibilities to improve the TRACE v4.160 code predictions in the film boiling heat transfer when applying different film boiling correlations. For this purpose, the TRACE v4.160-calculated film boiling heat flux and the resulting maximum inner wall temperatures during film boiling in single tubes were compared with experimental data obtained at the Royal Institute of Technology (KTH) in Stockholm, Sweden. The experimental database included measurements for pressures ranging from 30 to 200 bar and coolant mass fluxes from 500 to 3000 kg/m{sup 2}s. It was found that TRACE v4.160 does not produce correct predictions of the film boiling heat flux, and consequently of the maximum inner wall temperature in the test section, under the wide range of conditions documented in the KTH experiments. In particular, it was found that the standard TRACE v4.160 under-predicts the film boiling heat transfer coefficient at low pressure-low mass flux and high pressure-high mass flux conditions. For most of the rest of the investigated range of parameters, TRACE v4.160 over-predicts the film boiling heat transfer coefficient, which can lead to non-conservative predictions in applications to nuclear power plant analyses. Since no satisfactory agreement with the experimental database was obtained with the standard TRACE v4.160 film boiling heat transfer correlations, we have added seven film boiling correlations to TRACE v4.160 in order to investigate the possibility to improve the code predictions for the conditions similar to the KTH tests. The film boiling correlations were selected among the most commonly used film boiling correlations found in the open literature, namely Groeneveld 5.7, Bishop (2 correlations), Tong, Konkov, Miropolskii and Groeneveld-Delorme correlations. The only correlation among the investigated, which resulted in a significant improvement of TRACE predictions, was the Groeneveld 5.7. It was found, that replacing the current film boiling correlation (Dougall-Rohsenow) for the wall-togas heat transfer with Groeneveld 5.7 improves the code predictions for the film boiling heat transfer at high qualities in single tubes in the entire range of pressure and coolant mass flux considered. (authors)

  8. Lattice Boltzmann modeling of boiling heat transfer: The boiling curve and the effects of wettability

    SciTech Connect

    Li, Q.; Kang, Q. J.; Francois, M. M.; He, Y. L.; Luo, K. H.

    2015-03-03

    A hybrid thermal lattice Boltzmann (LB) model is presented to simulate thermal multiphase flows with phase change based on an improved pseudopotential LB approach (Li et al., 2013). The present model does not suffer from the spurious term caused by the forcing-term effect, which was encountered in some previous thermal LB models for liquid–vapor phase change. Using the model, the liquid–vapor boiling process is simulated. The boiling curve together with the three boiling stages (nucleate boiling, transition boiling, and film boiling) is numerically reproduced in the LB community for the first time. The numerical results show that the basic features and the fundamental characteristics of boiling heat transfer are well captured, such as the severe fluctuation of transient heat flux in the transition boiling and the feature that the maximum heat transfer coefficient lies at a lower wall superheat than that of the maximum heat flux. Moreover, the effects of the heating surface wettability on boiling heat transfer are investigated. It is found that an increase in contact angle promotes the onset of boiling but reduces the critical heat flux, and makes the boiling process enter into the film boiling regime at a lower wall superheat, which is consistent with the findings from experimental studies.

  9. Lattice Boltzmann modeling of boiling heat transfer: The boiling curve and the effects of wettability

    DOE PAGESBeta

    Li, Q.; Kang, Q. J.; Francois, M. M.; He, Y. L.; Luo, K. H.

    2015-03-03

    A hybrid thermal lattice Boltzmann (LB) model is presented to simulate thermal multiphase flows with phase change based on an improved pseudopotential LB approach (Li et al., 2013). The present model does not suffer from the spurious term caused by the forcing-term effect, which was encountered in some previous thermal LB models for liquid–vapor phase change. Using the model, the liquid–vapor boiling process is simulated. The boiling curve together with the three boiling stages (nucleate boiling, transition boiling, and film boiling) is numerically reproduced in the LB community for the first time. The numerical results show that the basic featuresmore » and the fundamental characteristics of boiling heat transfer are well captured, such as the severe fluctuation of transient heat flux in the transition boiling and the feature that the maximum heat transfer coefficient lies at a lower wall superheat than that of the maximum heat flux. Moreover, the effects of the heating surface wettability on boiling heat transfer are investigated. It is found that an increase in contact angle promotes the onset of boiling but reduces the critical heat flux, and makes the boiling process enter into the film boiling regime at a lower wall superheat, which is consistent with the findings from experimental studies.« less

  10. Investigations of Mechanisms Associated with Nucleate Boiling Under Microgravity Conditions

    NASA Technical Reports Server (NTRS)

    Dhir, Vijay K.; Hasan, M.; Chao, David (Technical Monitor)

    2003-01-01

    In this work a building block type of approach is used so that a basic understanding of the processes that contribute to nucleate boiling heat fluxes under microgravity conditions can be developed. This understanding will lead to development of a mechanistic model for nucleate boiling heat transfer which could eventually be used as a design tool in space applications. Task Description Task 1: Fabrication of the Experimental Setup. Under this task, the test section and liquid holding and viewing chambers will be fabricated. Artificial cylinder cavities will be formed on silicon wafers. A single cavity and two or four cavities, with a prescribed spacing and size, will be formed. The desired nucleation wall superheat will be used to determine the size of the mouth of the cavities. Task 2: Experiments. The basic experiments for flow and temperature field around single and multiple (2 or 4 separated or merged bubbles growing on downward facing or inclined surfaces) will be carried out under normal gravity conditions. The experiments will be conducted at one atmosphere pressure, but liquid subcooling will be varied from 0 to 30C. Water and PF-5050 will be used as test liquids. Task 3: Analytical/Numerical Models. In this task, transient temperature and flow field in vapor and liquid will be determined during growth of a single bubble. Analysis will include the evolution of the vapor-liquid interface and development of microlayer underneath the bubbles. For merged bubbles, detailed calculations of flow and temperature field will be carried out for transient shapes of vapor stems supporting a large bubble and the corresponding evaporation rate. Flow and temperature field for a bubble sliding along a heated wall will also be determined. Microgravity conditions will be simulated and a framework of a numerical tool for prediction of nucleate boiling heat fluxes under microgravity conditions will be developed. Task 4: Experiments in a KC-135. To understand bubble growth and detachment behavior of single or large merged bubbles, boiling experiments will be conducted under low gravity (10-2 g) conditions of the aircraft. In these experiments, 'designed' surfaces will be used. Visual observations and heat transfer data will be taken, but holography will not be used. The apparatus used for laboratory experiments will also be employed for experiments in the aircraft. Task 5: Experiments in the Space Shuttle. Effort will be devoted for defining a boiling experiment to be conducted on a 'designed' surface. The experiment will provide microgravity data on bubble growth and departure. These data are needed for development of a credible model for nucleate boiling heat fluxes under microgravity conditions. The heat transfer data will also be obtained and will be used to validate the models.

  11. Numerical analysis of contaminant removal from fractured rock during boiling.

    PubMed

    Chen, Fei; Falta, Ronald W; Murdoch, Lawrence C

    2012-06-01

    A multiphase heat transfer numerical model is used to simulate a laboratory experiment of contaminant removal at boiling temperatures from a rock core representing the matrix adjacent to a fracture. The simulated temperature, condensate production, contaminant and bromide concentrations are similar to experimental data. A key observation from the experiment and simulation is that boiling out approximately 1/2 pore volume (50 mL) of water results in the removal of essentially 100% of the dissolved volatile contaminant (1,2-DCA). A field-scale simulation using the multiple interacting continua (MINC) discretization approach is conducted to illustrate possible applications of thermal remediation of fractured geologic media, assuming uniform heating. The results show that after 28% of the pore water (including both steam vapor and liquid water) was extracted, and essentially all the 1,2-DCA mass (more than 99%) was removed. PMID:22579665

  12. Control of the boiling crisis: analysis of a model system

    NASA Astrophysics Data System (ADS)

    Pumir, A.; Barelko, V. V.; Buryak, E. V.

    2007-11-01

    Controlling the transition between the low (nucleate) and high temperature (film) regimes of boiling is a serious challenge for a number of technological applications. Based on the theoretical analysis of a simplified reaction-diffusion model, it has recently been shown [A. Pumir, V.V. Barelko, Chaos 12, 610 (2002)] that the transition towards the dangerous situation where the high temperature phase tends to invade the whole system requires a higher power in a periodically spatially modulated system than in an homogeneous system. We show here that the transition mechanisms between the various boiling regimes depend on the ratio between the periodicity length along the wire and the characteristic thermal diffusion length. We analyse theoretically a simple experimental setup aimed at testing these ideas. The heater consists of a thin wire, with an applied electric current, with alternatively low resistance and high resistance sections. We determine the gain in stability for a set of realistic values of the parameters.

  13. Sensing Atomic Motion from the Zero Point to Room Temperature with Ultrafast Atom Interferometry.

    PubMed

    Johnson, K G; Neyenhuis, B; Mizrahi, J; Wong-Campos, J D; Monroe, C

    2015-11-20

    We sense the motion of a trapped atomic ion using a sequence of state-dependent ultrafast momentum kicks. We use this atom interferometer to characterize a nearly pure quantum state with n=1 phonon and accurately measure thermal states ranging from near the zero-point energy to n[over ]?10^{4}, with the possibility of extending at least 100 times higher in energy. The complete energy range of this method spans from the ground state to far outside of the Lamb-Dicke regime, where atomic motion is greater than the optical wavelength. Apart from thermometry, these interferometric techniques are useful for characterizing ultrafast entangling gates between multiple trapped ions. PMID:26636850

  14. Criticality in the slowed-down boiling crisis at zero gravity

    NASA Astrophysics Data System (ADS)

    Charignon, T.; Lloveras, P.; Chatain, D.; Truskinovsky, L.; Vives, E.; Beysens, D.; Nikolayev, V. S.

    2015-05-01

    Boiling crisis is a transition between nucleate and film boiling. It occurs at a threshold value of the heat flux from the heater called CHF (critical heat flux). Usually, boiling crisis studies are hindered by the high CHF and short transition duration (below 1 ms). Here we report on experiments in hydrogen near its liquid-vapor critical point, in which the CHF is low and the dynamics slow enough to be resolved. As under such conditions the surface tension is very small, the experiments are carried out in the reduced gravity to preserve the conventional bubble geometry. Weightlessness is created artificially in two-phase hydrogen by compensating gravity with magnetic forces. We were able to reveal the fractal structure of the contour of the percolating cluster of the dry areas at the heater that precedes the boiling crisis. We provide a direct statistical analysis of dry spot areas that confirms the boiling crisis at zero gravity as a scale-free phenomenon. It was observed that, in agreement with theoretical predictions, saturated boiling CHF tends to zero (within the precision of our thermal control system) in zero gravity, which suggests that the boiling crisis may be observed at any heat flux provided the experiment lasts long enough.

  15. Criticality in the slowed-down boiling crisis at zero gravity.

    PubMed

    Charignon, T; Lloveras, P; Chatain, D; Truskinovsky, L; Vives, E; Beysens, D; Nikolayev, V S

    2015-05-01

    Boiling crisis is a transition between nucleate and film boiling. It occurs at a threshold value of the heat flux from the heater called CHF (critical heat flux). Usually, boiling crisis studies are hindered by the high CHF and short transition duration (below 1 ms). Here we report on experiments in hydrogen near its liquid-vapor critical point, in which the CHF is low and the dynamics slow enough to be resolved. As under such conditions the surface tension is very small, the experiments are carried out in the reduced gravity to preserve the conventional bubble geometry. Weightlessness is created artificially in two-phase hydrogen by compensating gravity with magnetic forces. We were able to reveal the fractal structure of the contour of the percolating cluster of the dry areas at the heater that precedes the boiling crisis. We provide a direct statistical analysis of dry spot areas that confirms the boiling crisis at zero gravity as a scale-free phenomenon. It was observed that, in agreement with theoretical predictions, saturated boiling CHF tends to zero (within the precision of our thermal control system) in zero gravity, which suggests that the boiling crisis may be observed at any heat flux provided the experiment lasts long enough. PMID:26066249

  16. Experimental study of temperature effect on the growth and collapse of cavitation bubbles near a rigid boundary

    NASA Astrophysics Data System (ADS)

    Liu, Xiu-mei; Long, Zheng; He, Jie; Li, Bei-bei; Liu, Xin-hua; Zhao, Ji-yun; Lu, Jian; Ni, Xiao-wu

    2013-07-01

    The effect of temperature on the dynamics of a laser-induced cavitation bubble is studied experimentally. The growth and collapse of the cavitation bubble are measured by two sensitive fiber-optic sensors based on optical beam deflection (OBD). Cavitation bubble tests are performed in water at different temperatures, and the temperature ranges from freezing point (0C) to near boiling point. The results indicate that both the maximum bubble radius and bubble lifetime are increased with the increase of temperature. During the stage of bubble rapidly collapsing in the vicinity of a solid surface, besides laser ablation effect, both the first and second liquid-jet-induced impulses are also observed. They are both increased with liquid temperature increasing, and then reach a peak, followed by a decrease. The peak appears at the temperature which is approximately the average of freezing and boiling points. The mechanism of liquid temperature influence on cavitation erosion is also discussed.

  17. Handheld low-temperature plasma probe for portable "point-and-shoot" ambient ionization mass spectrometry.

    PubMed

    Wiley, Joshua S; Shelley, Jacob T; Cooks, R Graham

    2013-07-16

    We describe a handheld, wireless low-temperature plasma (LTP) ambient ionization source and its performance on a benchtop and a miniature mass spectrometer. The source, which is inexpensive to build and operate, is battery-powered and utilizes miniature helium cylinders or air as the discharge gas. Comparison of a conventional, large-scale LTP source against the handheld LTP source, which uses less helium and power than the large-scale version, revealed that the handheld source had similar or slightly better analytical performance. Another advantage of the handheld LTP source is the ability to quickly interrogate a gaseous, liquid, or solid sample without requiring any setup time. A small, 7.4-V Li-polymer battery is able to sustain plasma for 2 h continuously, while the miniature helium cylinder supplies gas flow for approximately 8 continuous hours. Long-distance ion transfer was achieved for distances up to 1 m. PMID:23721516

  18. Predicting critical temperatures of ionic and non-ionic fluids from thermophysical data obtained near the melting point.

    PubMed

    Weiss, Volker C

    2015-10-14

    In the correlation and prediction of thermophysical data of fluids based on a corresponding-states approach, the critical temperature Tc plays a central role. For some fluids, in particular ionic ones, however, the critical region is difficult or even impossible to access experimentally. For molten salts, Tc is on the order of 3000 K, which makes accurate measurements a challenging task. Room temperature ionic liquids (RTILs) decompose thermally between 400 K and 600 K due to their organic constituents; this range of temperatures is hundreds of degrees below recent estimates of their Tc. In both cases, reliable methods to deduce Tc based on extrapolations of experimental data recorded at much lower temperatures near the triple or melting points are needed and useful because the critical point influences the fluid's behavior in the entire liquid region. Here, we propose to employ the scaling approach leading to universal fluid behavior [Romn et al., J. Chem. Phys. 123, 124512 (2005)] to derive a very simple expression that allows one to estimate Tc from the density of the liquid, the surface tension, or the enthalpy of vaporization measured in a very narrow range of low temperatures. We demonstrate the validity of the approach for simple and polar neutral fluids, for which Tc is known, and then use the methodology to obtain estimates of Tc for ionic fluids. When comparing these estimates to those reported in the literature, good agreement is found for RTILs, whereas the ones for the molten salts NaCl and KCl are lower than previous estimates by 10%. The coexistence curve for ionic fluids is found to be more adequately described by an effective exponent of ?eff = 0.5 than by ?eff = 0.33. PMID:26472385

  19. Predicting critical temperatures of ionic and non-ionic fluids from thermophysical data obtained near the melting point

    NASA Astrophysics Data System (ADS)

    Weiss, Volker C.

    2015-10-01

    In the correlation and prediction of thermophysical data of fluids based on a corresponding-states approach, the critical temperature Tc plays a central role. For some fluids, in particular ionic ones, however, the critical region is difficult or even impossible to access experimentally. For molten salts, Tc is on the order of 3000 K, which makes accurate measurements a challenging task. Room temperature ionic liquids (RTILs) decompose thermally between 400 K and 600 K due to their organic constituents; this range of temperatures is hundreds of degrees below recent estimates of their Tc. In both cases, reliable methods to deduce Tc based on extrapolations of experimental data recorded at much lower temperatures near the triple or melting points are needed and useful because the critical point influences the fluid's behavior in the entire liquid region. Here, we propose to employ the scaling approach leading to universal fluid behavior [Román et al., J. Chem. Phys. 123, 124512 (2005)] to derive a very simple expression that allows one to estimate Tc from the density of the liquid, the surface tension, or the enthalpy of vaporization measured in a very narrow range of low temperatures. We demonstrate the validity of the approach for simple and polar neutral fluids, for which Tc is known, and then use the methodology to obtain estimates of Tc for ionic fluids. When comparing these estimates to those reported in the literature, good agreement is found for RTILs, whereas the ones for the molten salts NaCl and KCl are lower than previous estimates by 10%. The coexistence curve for ionic fluids is found to be more adequately described by an effective exponent of βeff = 0.5 than by βeff = 0.33.

  20. Transient boiling in two-phase helium natural circulation loops

    NASA Astrophysics Data System (ADS)

    Furci, H.; Baudouy, B.; Four, A.; Meuris, C.

    2014-01-01

    Two-phase helium natural circulation loops are used for cooling large superconducting magnets, as CMS for LHC. During normal operation or in the case of incidents, transients are exerted on the cooling system. Here a cooling system of this type is studied experimentally. Sudden power changes are operated on a vertical-heated-section natural convection loop, simulating a fast increase of heat deposition on magnet cooling pipes. Mass flow rate, heated section wall temperature and pressure drop variations are measured as a function of time, to assess the time behavior concerning the boiling regime according to the values of power injected on the heated section. The boiling curves and critical heat flux (CHF) values have been obtained in steady state. Temperature evolution has been observed in order to explore the operating ranges where heat transfer is deteriorated. Premature film boiling has been observed during transients on the heated section in some power ranges, even at appreciably lower values than the CHF. A way of attenuating these undesired temperature excursions has been identified through the application of high enough initial heating power.

  1. A nonparametric temperature controller with nonlinear negative reaction for multi-point rapid MR-guided HIFU ablation.

    PubMed

    Petrusca, Lorena; Auboiroux, Vincent; Goget, Thomas; Viallon, Magalie; Muller, Arnaud; Gross, Patrick; Becker, Christoph D; Salomir, Rares

    2014-06-01

    Magnetic resonance-guided high intensity focused ultrasound (MRgHIFU) is a noninvasive method for thermal ablation, which exploits the capabilities of magnetic resonance imaging (MRI) for excellent visualization of the target and for near real-time thermometry. Oncological quality of ablation may be obtained by volumetric sonication under automatic feedback control of the temperature. For this purpose, a new nonparametric (i.e., model independent) temperature controller, using nonlinear negative reaction, was designed and evaluated for the iterated sonication of a prescribed pattern of foci. The main objective was to achieve the same thermal history at each sonication point during volumetric MRgHIFU. Differently sized linear and circular trajectories were investigated ex vivo and in vivo using a phased-array HIFU transducer. A clinical 3T MRI scanner was used and the temperature elevation was measured in five slices simultaneously with a voxel size of 1 1 5 mm(3) and temporal resolution of 4 s. In vivo results indicated a similar thermal history of each sonicated focus along the prescribed pattern, that was 17.3 0.5 C as compared to 16 C prescribed temperature elevation. The spatio-temporal control of the temperature also enabled meaningful comparison of various sonication patterns in terms of dosimetry and near-field safety. The thermal build-up tended to drift downwards in the HIFU transducer with a circular scan. PMID:24893259

  2. Microscale schlieren visualization of near-bubble mass transport during boiling of 2-propanol/water mixtures in a square capillary

    NASA Astrophysics Data System (ADS)

    Sun, Chen-li; Huang, Chien-Yuan

    2014-07-01

    In this study, we successfully utilize the microscale schlieren method to visualize the microscale mass transport near the vapor-liquid interface during boiling of 2-propanol/water mixtures in a square capillary. Because the variation in the refractive index with composition is much greater than that with temperature, the microscale schlieren method proves to be a powerful tool for investigating the solutocapillary convection without the interference of thermocapillarity. When the difference between the equilibrium vapor and liquid mole fractions is large, we observe high concentration gradients near the vapor-liquid interface due to both mass diffusion and the solutocapillary effects. Although the solutocapillary convection is decidedly affected by the eruptive nature of the boiling process, the near-bubble mass transport still plays a vital role in boiling heat transfer. In a square capillary of d = 900 ?m, mass diffusion dominates and the depletion of 2-propanol near the vapor-liquid interface increases. This leads to an increase in the local bubble point causing the deterioration of heat transfer for 2-propanol/water mixtures. However, in the smaller square capillary of d = 500 ?m, the solutocapillary effect becomes more important. The induced convection near the contact line helps to augment the boiling heat transfer at x = 0.015, despite the fact that mass diffusion tends to cause a higher concentration gradient normal to the bubble front during the boiling process. Herein, we prove that the microscale schlieren method is able to provide valuable insight into the leverage between different mechanisms in heat transfer during the vaporization process of 2-propanol/water mixtures in a square capillary.

  3. Boiling Fluids Behave Quite Differently in Space - Duration: 19 seconds.

    NASA Video Gallery

    The boiling process is really different in space, since the vapor phase of a boiling liquid does not rise via buoyancy. Spacecraft and Earth-based systems use boiling to efficiently remove large am...

  4. Boiling Heat Transfer from a Dike

    SciTech Connect

    Cheng, P.; Verma, A.K.

    1980-12-16

    Recectly, we have obtained an analytical solution for boiling heat transfer from a vertical isothermal surface in a porous medium filled with a subcooled liquid. In this paper we shall briefly summarize the results obtained, and carry out numerical computations of boiling heat transfer from a dike.

  5. Pool Boiling Experiment Has Successful Flights

    NASA Technical Reports Server (NTRS)

    1996-01-01

    The Pool Boiling Experiment (PBE) is designed to improve understanding of the fundamental mechanisms that constitute nucleate pool boiling. Nucleate pool boiling is a process wherein a stagnant pool of liquid is in contact with a surface that can supply heat to the liquid. If the liquid absorbs enough heat, a vapor bubble can be formed. This process occurs when a pot of water boils. On Earth, gravity tends to remove the vapor bubble from the heating surface because it is dominated by buoyant convection. In the orbiting space shuttle, however, buoyant convection has much less of an effect because the forces of gravity are very small. The Pool Boiling Experiment was initiated to provide insight into this nucleate boiling process, which has many Earthbound applications, such as steam-generation power plants, petroleum, and other chemical plants. Also, by using the test fluid R-113, the Pool Boiling Experiment can provide some basic understanding of the boiling behavior of cryogenic fluids without the large cost of an experiment using an actual cryogen.

  6. Pool Boiling Experiment Has Five Successful Flights

    NASA Technical Reports Server (NTRS)

    Chiaramonte, Fran

    1997-01-01

    The Pool Boiling Experiment (PBE) is designed to improve understanding of the fundamental mechanisms that constitute nucleate pool boiling. Nucleate pool boiling is a process wherein a stagnant pool of liquid is in contact with a surface that can supply heat to the liquid. If the liquid absorbs enough heat, a vapor bubble can be formed. This process occurs when a pot of water boils. On Earth, gravity tends to remove the vapor bubble from the heating surface because it is dominated by buoyant convection. In the orbiting space shuttle, however, buoyant convection has much less of an effect because the forces of gravity are very small. The Pool Boiling Experiment was initiated to provide insight into this nucleate boiling process, which has many earthbound applications in steamgeneration power plants, petroleum plants, and other chemical plants. In addition, by using the test fluid R-113, the Pool Boiling Experiment can provide some basic understanding of the boiling behavior of cryogenic fluids without the large cost of an experiment using an actual cryogen.

  7. Indo-Pacific Warm Pool Area Expansion, Modoki Activity, and Tropical Cold-Point Tropopause Temperature Variations

    NASA Astrophysics Data System (ADS)

    Xie, F.

    2014-12-01

    The tropical cold-point tropopause temperature (CPTT), a potentially important indicator of global climate change, is of particular importance for understanding changes in stratospheric water vapor levels. Since the 1980s, the tropical CPTT has shown not only interannual variations, but also a decreasing trend. However, the factors controlling the variations in the tropical CPTT since the 1980s remain elusive. The present study reveals that the continuous expansion of the area of the Indo-Pacific warm pool (IPWP) since the 1980s represents an increase in the total heat energy of the IPWP available to heat the tropospheric air, which is likely to expand as a result. This process lifts the tropical cold-point tropopause height (CPTH) and leads to the observed long-term cooling trend of the tropical CPTT. In addition, our analysis shows that Modoki activity is an important factor in modulating the interannual variations of the tropical CPTT through significant effects on overshooting convection.

  8. Relationships between membrane water molecules and Patman equilibration kinetics at temperatures far above the phosphatidylcholine melting point.

    PubMed

    Vaughn, Alexandra R; Bell, Thomas A; Gibbons, Elizabeth; Askew, Caitlin; Franchino, Hannabeth; Hirsche, Kelsey; Kemsley, Linea; Melchor, Stephanie; Moulton, Emma; Schwab, Morgan; Nelson, Jennifer; Bell, John D

    2015-04-01

    The naphthalene-based fluorescent probes Patman and Laurdan detect bilayer polarity at the level of the phospholipid glycerol backbone. This polarity increases with temperature in the liquid-crystalline phase of phosphatidylcholines and was observed even 90C above the melting temperature. This study explores mechanisms associated with this phenomenon. Measurements of probe anisotropy and experiments conducted at 1M NaCl or KCl (to reduce water permittivity) revealed that this effect represents interactions of water molecules with the probes without proportional increases in probe mobility. Furthermore, comparison of emission spectra to Monte Carlo simulations indicated that the increased polarity represents elevation in probe access to water molecules rather than increased mobility of relevant bilayer waters. Equilibration of these probes with the membrane involves at least two steps which were distinguished by the membrane microenvironment reported by the probe. The difference in those microenvironments also changed with temperature in the liquid-crystalline phase in that the equilibrium state was less polar than the initial environment detected by Patman at temperatures near the melting point, more polar at higher temperatures, and again less polar as temperature was raised further. Laurdan also displayed this level of complexity during equilibration, although the relationship to temperature differed quantitatively from that experienced by Patman. This kinetic approach provides a novel way to study in molecular detail basic principles of what happens to the membrane environment around an individual amphipathic molecule as it penetrates the bilayer. Moreover, it provides evidence of unexpected and interesting membrane behaviors far from the phase transition. PMID:25559316

  9. Influence of temperature on measurements of the CO2 compensation point: differences between the Laisk and O2-exchange methods.

    PubMed

    Walker, Berkley J; Cousins, Asaph B

    2013-04-01

    The CO2 compensation point in the absence of day respiration (?*) is a key parameter for modelling leaf CO2 exchange. ?* links the kinetics of ribulose-1,5-bisphosphate carboxylase-oxygenase (Rubisco) with the stoichiometry of CO2 released per Rubisco oxygenation from photorespiration (?), two essential components of biochemical models of photosynthesis. There are two main gas-exchange methods for measuring ?*: (i) the Laisk method, which requires estimates of mesophyll conductance to CO2 (g m) and (ii) measurements of O2 isotope exchange, which assume constant values of ? and a fixed stoichiometry between O2 uptake and Rubisco oxygenation. In this study, the temperature response of ?* measured using the Laisk and O2-exchange methods was compared under ambient (25 C) and elevated (35 C) temperatures to determine whether both methods yielded similar results. Previously published temperature responses of ?* estimated with the Laisk and O2-exchange methods in Nicotiana tabacum demonstrated that the Laisk-derived model of ?* was more sensitive to temperature compared with the O2-exchange model. Measurements in Arabidopsis thaliana indicated that the Laisk and O2-exchange methods produced similar ?* at 25 C; however, ?* values from O2 exchange were lower at 35 C compared with the Laisk method. Compared with a photorespiratory mutant (pmdh1pmdh2hpr) with increased ?, wild-type (WT) plants had lower Laisk values of ?* at 25 C but were not significantly different at 35 C. These differences between Laisk and O2 exchange values of ?* at 35 C could be explained by temperature sensitivity of ? in WT and/or errors in the assumptions of O2 exchange. The differences between ?* measured using the Laisk and O2-exchange method with temperature demonstrate that assumptions used to measure ?*, and possibly the species-specific validity of these assumptions, need to be considered when modelling the temperature response of photosynthesis. PMID:23630324

  10. Influence of temperature on measurements of the CO2 compensation point: differences between the Laisk and O2-exchange methods

    PubMed Central

    Walker, Berkley J.; Cousins, Asaph B.

    2013-01-01

    The CO2 compensation point in the absence of day respiration (?*) is a key parameter for modelling leaf CO2 exchange. ?* links the kinetics of ribulose-1,5-bisphosphate carboxylase-oxygenase (Rubisco) with the stoichiometry of CO2 released per Rubisco oxygenation from photorespiration (?), two essential components of biochemical models of photosynthesis. There are two main gas-exchange methods for measuring ?*: (i) the Laisk method, which requires estimates of mesophyll conductance to CO2 (g m) and (ii) measurements of O2 isotope exchange, which assume constant values of ? and a fixed stoichiometry between O2 uptake and Rubisco oxygenation. In this study, the temperature response of ?* measured using the Laisk and O2-exchange methods was compared under ambient (25 C) and elevated (35 C) temperatures to determine whether both methods yielded similar results. Previously published temperature responses of ?* estimated with the Laisk and O2-exchange methods in Nicotiana tabacum demonstrated that the Laisk-derived model of ?* was more sensitive to temperature compared with the O2-exchange model. Measurements in Arabidopsis thaliana indicated that the Laisk and O2-exchange methods produced similar ?* at 25 C; however, ?* values from O2 exchange were lower at 35 C compared with the Laisk method. Compared with a photorespiratory mutant (pmdh1pmdh2hpr) with increased ?, wild-type (WT) plants had lower Laisk values of ?* at 25 C but were not significantly different at 35 C. These differences between Laisk and O2 exchange values of ?* at 35 C could be explained by temperature sensitivity of ? in WT and/or errors in the assumptions of O2 exchange. The differences between ?* measured using the Laisk and O2-exchange method with temperature demonstrate that assumptions used to measure ?*, and possibly the species-specific validity of these assumptions, need to be considered when modelling the temperature response of photosynthesis. PMID:23630324

  11. Bubble behavior and mean diameter in subcooled flow boiling

    SciTech Connect

    Zeitoun, O.; Shoukri, M.

    1996-02-01

    Bubble behavior and mean bubble diameter in subcooled upward flow boiling in a vertical annular channel were investigated under low pressure and mass flux conditions. High-speed photographic results indicated that, contrary to the common understanding, bubbles tend to detach from the heating surface upstream of the net vapor generation point. Digital image processing technique was used to measure the mean bubble diameter along the subcooled flow boiling region. Data on the axial area-averaged void fraction distributions were also obtained using a single-beam gamma densitometer. Effects of the liquid subcooling, applied heat flux and mass flux on the mean bubble size were investigated. A correlation for the mean bubble diameter as a function of the local subcooling, heat flux, and mass flux was obtained. 28 refs., 8 figs., 1 tab.

  12. Ellipsometric study of the temperature dependences of the dielectric function and the critical points of AlSb at temperatures from 300 to 803 K

    NASA Astrophysics Data System (ADS)

    Park, Han Gyeol; Kim, Tae Jung; Hwang, Soon Yong; Kim, Jun Young; Choi, Junho; Kim, Young Dong; Shin, Sang Hoon; Song, Jin Dong

    2014-08-01

    We report the complex pseudodielectric function < ? > = < ? 1 > + i < ? 2 > of an oxide-free AlSb film for energies from 0.7 to 5.0 eV and temperatures from 300 to 803 K. The 1.5- ?m-thick film was grown on a (001) GaAs substrate by using molecular beam epitaxy. We maintained the film in an ultrahigh vacuum to prevent oxidation artifacts and used a rotating-compensator ellipsometer to obtain the optical properties. Critical-point (CP) energies were obtained by numerically calculating second energy derivatives of the data. Blue shifts of the CP energies and sharper structures were observed with decreasing temperature. The calculated CP energies were fit to a linear equation.

  13. Preparation of low HD contamination cells for the measurement of the triple point temperature of n-D/sub 2/

    SciTech Connect

    McConville, G.T.; Menke, D.A.; Pavese, F.

    1985-01-01

    An effort is under way to produce deuterium triple point sealed cells for a 18.7 K temperature reference point. Stability with time of impurity content in cells, namely HD, was found to be good from measurements made at IMGC since 1978, but nearly all commercially produced ''chemical pure'' D/sub 2/ contains approximately 0.5% HD. To reduce the HD content in the D/sub 2/ cell, two steps have been taken: (1) The stainless steel cell was chemically etched and then vacuum baked to remove Fe from the surface and to diffuse protium out of the cell. (2) The cell was flushed and filled to 70 bar with D/sub 2/ directly obtained from a thermal diffusion column with HD <70 ppM. Triple point measurements with the cell show an initial drift due to para-ortho conversion of 0.4 mK per hour decreasing to 0.7 mK per hour after 130 hours of conversion. The initial triple point temperature on NBS-IPTS-68 was found to be 18.732 +- 0.001 K; this agrees with the value found in the earlier IMGC cells, filled with commercial D/sub 2/, when the latter are corrected for a 0.4 +- 0.1 HD content, but the conversion in this cell was 10 times faster than in 304 stainless steel IMGC cells. Further measurements have been made using the clean n-D/sub 2/ in an unetched 304 stainless steel cell which has been flushed with D/sub 2/O vapor.

  14. Preliminary Demonstration Reactor Point Design for the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect

    Qualls, A. L.; Betzler, Benjamin R.; Brown, Nicholas R.; Carbajo, Juan; Greenwood, Michael Scott; Hale, Richard Edward; Harrison, Thomas J.; Powers, Jeffrey J.; Robb, Kevin R.; Terrell, Jerry W.

    2015-12-01

    Development of the Fluoride Salt-Cooled High-Temperature Reactor (FHR) Demonstration Reactor (DR) is a necessary intermediate step to enable commercial FHR deployment through disruptive and rapid technology development and demonstration. The FHR DR will utilize known, mature technology to close remaining gaps to commercial viability. Lower risk technologies are included in the initial FHR DR design to ensure that the reactor can be built, licensed, and operated within an acceptable budget and schedule. These technologies include tristructural-isotropic (TRISO) particle fuel, replaceable core structural material, the use of that same material for the primary and intermediate loops, and tube-and-shell heat exchangers. This report provides an update on the development of the FHR DR. At this writing, the core neutronics and thermal hydraulics have been developed and analyzed. The mechanical design details are still under development and are described to their current level of fidelity. It is anticipated that the FHR DR can be operational within 10 years because of the use of low-risk, near-term technology options.

  15. Temperature-plant pigment-optical relations in a recurrent offshore mesoscale eddy near Point Conception, California

    NASA Technical Reports Server (NTRS)

    Simpson, James J.; Pelaez, Jose; Haury, Loren R.; Wiesenhahn, David; Koblinsky, Chester J.

    1986-01-01

    The temperature-plant pigment-optical structure of a mesoscale anticyclonic eddy consistently found in shipboard surveys and satellite-sensed data several hundred kilometers southwest of Point Conception, CA, is described on three different time scales (100-day mesoscale, annual, and several-year). The satellite coastal zone color scanner (CZCS) ocean color imagery detected the near-surface chlorophyll structure of the eddy, but in situ optical and plant pigment data suggest that such imagery does not provide a good estimate of the integrated chlorophyll field of the eddy. The temperature and plant pigment boundaries of the eddy, as determined from two-dimensional gradients of advanced very high resolution radiometer (AVHRR) and CZCS imagery, do not coincide spatially. This and in situ temperature, plant pigment, and optical structure provide additional evidence that some eddy systems in the California Current are not isolated vortex systems but rather continuously entrain waters of nonlocal origin laterally into their upper layers. Within the California Current a ratio of AVHRR/CZCS data is useful for separating inshore from oceanic water masses and following their surface entrainment by offshore vortices. The historical 28-year California Cooperative Oceanic Fisheries Investigations data for the Point Conception region of the California Current and remotely sensed data over this region show that the Point Conception eddy is a recurrent feature in the offshore California Current. Moreover, the available data provide evidence that a large number of warm-core mesoscale eddies occur simultaneously in a transition zone between coastal and oceanic regimes, that these features recur at preferred locations within the transition zone, and that this family of eddies should impose a significant offshore boundary condition on the flow of the California Current.

  16. Experimental investigation of nucleate boiling and thin-film evaporation on enhanced silicon surfaces

    NASA Astrophysics Data System (ADS)

    Malla, Shailesh

    The present work consists of two major studies. The first study investigates the effects of surface energy or wettability on nucleate pool boiling and the second study investigates the thin-film evaporative cooling for near junction thermal management. For the first study, effects of surface energy or wettability on critical heat flux (CHF) and boiling heat transfer (BHT) of smooth heated surfaces was studied in saturated pool boiling of water at 1 atm. For this purpose hydrophilic and hydrophobic surfaces were created on one side of 1cm x 1cm double-side polished silicon substrates. A resistive heating layer was applied on the opposite side of each substrate. The surface energies of the created surfaces were characterized by measuring the static contact angles of water sessile drops. To provide a wide range of surface energies, surfaces were made of Teflon (hydrophobic), bare silicon (hydrophilic) and aluminum oxide (most hydrophilic). The measured contact angles on these surfaces were ˜108, ˜57 and ˜13 degrees respectively. The results of pool boiling tests on these surfaces clearly illustrate the connection between surface energy and CHF. CHF was shown to linearly decrease with contact angle increase, from ˜125 W/cm2 on aluminum oxide (most hydrophilic) to nearly one tenth of this value on Teflon (hydrophobic). The most hydrophilic surface also produced increasingly better BHT than plain silicon and Teflon as heat flux increased. However, below ˜5 W/cm2 the hydrophobic surface demonstrated better heat transfer due to earlier onset of nucleate boiling, reducing surface superheats by up to ˜5 degrees relative to the other two surfaces. Above ˜5 W/cm2 the BHT of the hydrophobic surface rapidly deteriorated as superheat increased towards the value at CHF. To further understand the effect of surface energy on pool boiling performance, the growth and departure of bubbles from single nucleating sites on each surface were analyzed from high-speed video recordings. A distinct bubble behavior was observed in the hydrophobic surface where bubble growth and departure period was extremely long compared to plain silicon and aluminum oxide surfaces. This study also investigated the performance of thin-film evaporative cooling for near-junction thermal management. A liquid delivery system capable of delivering water in small volumes ranging 20˜75 nl at frequencies of up to 600 Hz was established. On one side of the silicon chip, a resistive heating layer of 2 mm x 2 mm was fabricated to emulate the high heat flux hot-spot, and on the other side a superhydrophilic nanoporous coating (SHNC) was applied over an area of 1 cm x 1 cm. With the aid of the nanoporous coating, delivered droplets spread into thin films of thicknesses less than 10microm. With this system, evaporative tests were conducted in ambient in an effort to maximize dryout heat flux and evaporative heat transfer coefficient. During the tests, heat flux at the hot spot was varied to values above 1000 W/cm 2. Water was delivered at either given constant frequency (constant mass flow rate) or at programmed variations of frequency (variable mass flow rate), for a given nanoliter dose volume. Heat flux and hot spot surface temperatures were recorded upon reaching steady state at each applied heat flux increment. Relative to bare silicon surface, dryout heat flux of the SHNC surface was found to increase by ˜5 times at 500˜600 Hz. Tests were also conducted at various system pressures and temperatures in a micro-gap to emulate the actual embedded thermal management system. The micro-gap was made by positioning a top cover plate 500 microm above the test surface. System temperature did not influence the hotspot temperature. This was due to the formation of near saturation temperature inside the micro-gap for all cases as a result of vapor accumulation. Increase in system pressure increased the hotspot temperature. At 1500 W/cm2, hotspot temperature increased by 6oC and 24oC by increasing the system pressure by 7.32 and 14.7 psi respectively. This was due to increase in saturation point as a result of increase in pressure. On the SHNC surface a mixed mode of heat transfer comprising of thin-film boiling and thin-film evaporation was observed particularly at moderate heat flux (˜700 W/cm2). To further enhance the heat transfer coefficient, aluminum microporous coating was developed that increased the number of nucleation sites for thin-film boiling and also maintained the wettability for thin-film evaporation at higher heat fluxes. Test results showed a marginal improvement in dry-out heat flux compared to SHNC, however, significant reduction was achieved in hot-spot temperature at all heat flux levels. A net reduction of ˜ 58oC was obtained at ˜1600 W/cm2 by using aluminum based microporous coating.

  17. Modeling and analysis of low heat flux natural convection sodium boiling in LMFBRs

    SciTech Connect

    Khatib-Rahbar, M.; Cazzoli, E.G.

    1982-09-01

    Flow excursion induced dryout at low heat flux natural convection boiling, typical of liquid metal fast breeder reactor, is addressed. Steady state calculations indicate that low quality boiling is possible up to the point of Ledinegg instability leading to flow excursion and subsequent dryout in agreement with experimental data. A flow regime-dependent dryout heat flux relationship based upon saturated boiling criterion is also presented. Transient analysis indicates that premature flow excursion can not be ruled out and sodium boiling is highly transient dependent. Analysis of a high heat flux forced convection, loss-of-flow transient shows a significantly faster flow excursion leading to dryout in excellent agreement with parallel calculations using the two-dimensional THORAX code. 31 refs., 25 figs., 6 tabs.

  18. Comparison of the triple-point temperatures of {sup 20}Ne, {sup 22}Ne and normal Ne

    SciTech Connect

    Nakano, T.; Tamura, O.; Nagao, K.

    2013-09-11

    At the National Metrology Institute of Japan (NMIJ), the triple points of {sup 20}Ne and {sup 22}Ne were realized using modular sealed cells, Ec3Ne20 and Ec8Ne22, made by the Istituto Nazionale di Ricerca Metrologica (INRiM) in Italy. The difference of the triple-point temperatures of {sup 20}Ne and {sup 22}Ne was estimated by using the sub-range of standard platinum resistance thermometers (SPRTs) calibrated by NMIJ on the International Temperature Scale of 1990 (ITS-90). The melting curves obtained with the Ec3Ne20 and Ec8Ne22 cells show narrow widths (0.1 mK) over a wide range of the inverse of the melted fraction (1/F) from 1/F=1 to 1/F=10. The liquidus point T{sub tp} estimated by the melting curves from F∼0.5 to F∼0.85 using the Ec8Ne22 is 0.146 29 (4) K higher than that using the Ec3Ne20 cell, which is in good agreement with that observed by INRiM using the same cells. After correction of the effect of impurities and other isotopes for Ec3Ne20 and Ec8Ne22 cells, the difference of T{sub tp} between pure {sup 20}Ne and pure {sup 22}Ne is estimated to be 0.146 61 (4) K, which is consistent with the recent results reported elsewhere. The sub-ranges of SPRTs computed by using the triple point of {sup 20}Ne or {sup 22}Ne realized by the Ec3Ne20 cell or the Ec8Ne22 cell in place of the triple point of Ne for the defining fixed point of the ITS-90 are in good agreement with those realized on the basis of the ITS-90 at NMIJ within 0.03 mK, which is much smaller than the non-uniqueness and the sub-range inconsistency of SPRTs.

  19. A dual-unit pressure sensor for on-chip self-compensation of zero-point temperature drift

    NASA Astrophysics Data System (ADS)

    Wang, Jiachou; Li, Xinxin

    2014-08-01

    A novel dual-unit piezoresistive pressure sensor, consisting of a sensing unit and a dummy unit, is proposed and developed for on-chip self-compensation for zero-point temperature drift. With an MIS (microholes inter-etch and sealing) process implemented only from the front side of single (1?1?1) silicon wafers, a pressure sensitive unit and another identically structured pressure insensitive dummy unit are compactly integrated on-chip to eliminate unbalance factors induced zero-point temperature-drift by mutual compensation between the two units. Besides, both units are physically suspended from silicon substrate to further suppress packaging-stress induced temperature drift. A simultaneously processes ventilation hole-channel structure is connected with the pressure reference cavity of the dummy unit to make it insensitive to detected pressure. In spite of the additional dummy unit, the sensor chip dimensions are still as small as 1.2?mm 1.2?mm 0.4?mm. The proposed dual-unit sensor is fabricated and tested, with the tested sensitivity being 0.104?mV?kPa-1 3.3?V-1, nonlinearity of less than 0.08% FSO and overall accuracy error of 0.18% FSO. Without using any extra compensation method, the sensor features an ultra-low temperature coefficient of offset (TCO) of 0.002%?C-1 FSO that is much better than the performance of conventional pressure sensors. The highly stable and small-sized sensors are promising for low cost production and applications.

  20. High-freezing-point fuels used for aviation turbine engines

    NASA Technical Reports Server (NTRS)

    Friedman, R.

    1979-01-01

    Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. The higher-freezing-point fuels can be substituted in the majority of present commercial flights, since temperature data indicate that in-flight fuel temperatures are relatively mild. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple system design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating. Both systems offer advantages that outweigh the obvious penalties.

  1. Apparatus for pumping liquids at or below the boiling point

    DOEpatents

    Bingham, Dennis N. (Idaho Falls, ID)

    2002-01-01

    A pump comprises a housing having an inlet and an outlet. An impeller assembly mounted for rotation within the housing includes a first impeller piece having a first mating surface thereon and a second impeller piece having a second mating surface therein. The second mating surface of the second impeller piece includes at least one groove therein so that at least one flow channel is defined between the groove and the first mating surface of the first impeller piece. A drive system operatively associated with the impeller assembly rotates the impeller assembly within the housing.

  2. On the Boiling Points of the Alkyl Halides.

    ERIC Educational Resources Information Center

    Correia, John

    1988-01-01

    Discusses the variety of explanations in organic chemistry textbooks of a physical property of organic compounds. Focuses on those concepts explaining attractive forces between molecules. Concludes that induction interactions play a major role in alkyl halides and other polar organic molecules and should be given wider exposure in chemistry texts.

  3. Our Educational Melting Pot: Have We Reached the Boiling Point?

    ERIC Educational Resources Information Center

    Lauderdale, Katherine Lynn, Ed.; Bonilla, Carlos A., Ed.

    The articles and excerpts in this collection illustrate the complexity of the melting pot concept. Multiculturalism has become a watchword in American life and education, but it may be that in trying to atone for past transgressions educators and others are simply going too far. These essays illustrate some of the problems of a multicultural

  4. Position-dependent velocity of an effective temperature point for the estimation of the thermal diffusivity of solids

    NASA Astrophysics Data System (ADS)

    Balachandar, Settu; Shivaprakash, N. C.; Kameswara Rao, L.

    2016-01-01

    A new approach is proposed to estimate the thermal diffusivity of optically transparent solids at ambient temperature based on the velocity of an effective temperature point (ETP), and by using a two-beam interferometer the proposed concept is corroborated. 1D unsteady heat flow via step-temperature excitation is interpreted as a ‘micro-scale rectilinear translatory motion’ of an ETP. The velocity dependent function is extracted by revisiting the Fourier heat diffusion equation. The relationship between the velocity of the ETP with thermal diffusivity is modeled using a standard solution. Under optimized thermal excitation, the product of the ‘velocity of the ETP’ and the distance is a new constitutive equation for the thermal diffusivity of the solid. The experimental approach involves the establishment of a 1D unsteady heat flow inside the sample through step-temperature excitation. In the moving isothermal surfaces, the ETP is identified using a two-beam interferometer. The arrival-time of the ETP to reach a fixed distance away from heat source is measured, and its velocity is calculated. The velocity of the ETP and a given distance is sufficient to estimate the thermal diffusivity of a solid. The proposed method is experimentally verified for BK7 glass samples and the measured results are found to match closely with the reported value.

  5. Temperature mapping in bread dough using SE and GE two-point MRI methods: experimental and theoretical estimation of uncertainty.

    PubMed

    Lucas, Tiphaine; Musse, Maja; Bornert, Mélanie; Davenel, Armel; Quellec, Stéphane

    2012-04-01

    Two-dimensional (2D)-SE, 2D-GE and tri-dimensional (3D)-GE two-point T(1)-weighted MRI methods were evaluated in this study in order to maximize the accuracy of temperature mapping of bread dough during thermal processing. Uncertainties were propagated throughout each protocol of measurement, and comparisons demonstrated that all the methods with comparable acquisition times minimized the temperature uncertainty to similar extent. The experimental uncertainties obtained with low-field MRI were also compared to the theoretical estimations. Some discrepancies were reported between experimental and theoretical values of uncertainties of temperature; however, experimental and theoretical trends with varying parameters agreed to a large extent for both SE and GE methods. The 2D-SE method was chosen for further applications on prefermented dough because of its lower sensitivity to susceptibility differences in porous media. It was applied for temperature mapping in prefermented dough during chilling prior to freezing and compared locally to optical fiber measurements. PMID:22227351

  6. Dirac point and transconductance of top-gated graphene field-effect transistors operating at elevated temperature

    SciTech Connect

    Hopf, T.; Vassilevski, K. V. Escobedo-Cousin, E.; King, P. J.; Wright, N. G.; O'Neill, A. G.; Horsfall, A. B.; Goss, J. P.; Wells, G. H.; Hunt, M. R. C.

    2014-10-21

    Top-gated graphene field-effect transistors (GFETs) have been fabricated using bilayer epitaxial graphene grown on the Si-face of 4H-SiC substrates by thermal decomposition of silicon carbide in high vacuum. Graphene films were characterized by Raman spectroscopy, Atomic Force Microscopy, Scanning Tunnelling Microscopy, and Hall measurements to estimate graphene thickness, morphology, and charge transport properties. A 27?nm thick Al?O? gate dielectric was grown by atomic layer deposition with an e-beam evaporated Al seed layer. Electrical characterization of the GFETs has been performed at operating temperatures up to 100?C limited by deterioration of the gate dielectric performance at higher temperatures. Devices displayed stable operation with the gate oxide dielectric strength exceeding 4.5 MV/cm at 100?C. Significant shifting of the charge neutrality point and an increase of the peak transconductance were observed in the GFETs as the operating temperature was elevated from room temperature to 100?C.

  7. A New Theory of Nucleate Pool Boiling in Arbitrary Gravity

    NASA Technical Reports Server (NTRS)

    Buyevich, Y. A.; Webbon, Bruce W.

    1995-01-01

    Heat transfer rates specific to nucleate pool boiling under various conditions are determined by the dynamics of vapour bubbles that are originated and grow at nucleation sites of a superheated surface. A new dynamic theory of these bubbles has been recently developed on the basis of the thermodynamics of irreversible processes. In contrast to other existing models based on empirically postulated equations for bubble growth and motion, this theory does not contain unwarrantable assumptions, and both the equations are rigorously derived within the framework of a unified approach. The conclusions of the theory are drastically different from those of the conventional models. The bubbles are shown to detach themselves under combined action of buoyancy and a surface tension force that is proven to add to buoyancy in bubble detachment, but not the other way round as is commonly presumed. The theory ensures a sound understanding of a number of so far unexplained phenomena, such as effect caused by gravity level and surface tension on the bubble growth rate and dependence of the bubble characteristics at detachment on the liquid thermophysical parameters and relevant temperature differences. The theoretical predictions are shown to be in a satisfactory qualitative and quantitative agreement with observations. When being applied to heat transfer at nucleate pool boiling, this bubble dynamic theory offers an opportunity to considerably improve the main formulae that are generally used to correlate experimental findings and to design boiling heat removal in various industrial applications. Moreover, the theory makes possible to pose and study a great deal of new problems of essential impact in practice. Two such problems are considered in detail. One problem concerns the development of a principally novel physical model for the first crisis of boiling. This model allows for evaluating critical boiling heat fluxes under various conditions, and in particular at different gravity levels, with a good agreement with experimental evidence. The other problem bears upon equilibrium shapes of a detached bubble near a heated surface in exceedingly low gravity. In low gravity or in weightlessness, the bubble can remain in the close vicinity of the surface for a long time, and its shape is greatly affected by the Marangoni effect due to both temperature and possible surfactant concentration being nonuniform along the interface. The bubble performs at these conditions like a heat pipe, with evaporation at the bubble lower boundary and condensation at its upper boundary, and ultimately ensures a substantial increase in heat removal as compared with that in normal gravity. Some other problems relevant to nucleate pool and forced convection boiling heat transfer are also discussed.

  8. Growth responses of male broilers subjected to increasing air velocities at high ambient temperatures and a high dew point.

    PubMed

    Dozier, W A; Lott, B D; Branton, S L

    2005-06-01

    This study examined live performance responses of male broilers to increasing air velocity of 120 and 180 m/min reared under high cyclic temperatures (25-35-25 degrees C) with a 23 degrees C dew point from 21 to 49 d. Birds were reared in an environmental facility containing 2 wind tunnels (4 pens/tunnel) and 6 floor pens (control). At 21 d, 53 birds were placed in each pen of the wind tunnels and control group, respectively, and growth performance was determined weekly. Increasing air velocity from 120 to 180 m/min improved BW and BW gain from 29 to 35, 36 to 42, and 43 to 49 d of age leading to a cumulative advantage of 287 g in BW gain and a 10-point difference in feed conversion from 21 to 49 d of age. Subjecting birds to air velocity improved growth rate, feed consumption, and feed conversion at each weekly interval from 28 to 49 d over the control birds. These results indicate that male broilers approximating 2.0 to 3.0 kg respond to an air velocity of 180 m/min when exposed to high cyclic temperatures. PMID:15971539

  9. Correlations of velocity and temperature fluctuations in the stagnation-point flow of circular cylinder in turbulent flow

    NASA Technical Reports Server (NTRS)

    Wang, Chi R.

    1988-01-01

    Boundary layer flow and turbulence transport analyses to study the influence of the free-stream turbulence on the surface heat transfer rate and the skin friction around the stagnation point of a circular cylinder in a turbulent flow are presented. The analyses are formulated with the turbulent boundary layer equations, the Reynolds stress transport equations and the k - epsilon two-equation turbulence modeling. The analyses are used to calculate the time-averaged turbulence double correlations, the mean flow properties, the surface heat transfer rate and the skin friction with an isotropic turbulence in the freestream. The analytical results are described and compared with the existing experimental measurements. Depending on the free-stream turbulence properties, the turbulence kinetic energy can increase or decrease as the flow moves toward the surface. However, the turbulence kinetic energy induces large Reynolds normal stresses at the boundary layer edge. The Reynolds normal stresses change the boundary layer profiles of the time-averaged double correlations of the velocity and temperature fluctuations, the surface heat transfer rate and the skin friction. The free-stream turbulence dissipation rate can affect the stagnation-point heat transfer rate but the influence of the free-stream temperature fluctuation on the heat transfer rate is insignificant.

  10. Considerations in predicting burnout of cylinders in flow boiling

    SciTech Connect

    Sadasivan, P.; Lienhard, J.H. )

    1992-02-01

    Previous investigations of the critical heat flux in flow boiling have resulted in widely different hydrodynamic mechanisms for the occurrence of burnout. Results of the present study indicate that existing models are not completely realistic representations of the process. The present study sorts out the influences of the far-wake bubble breakoff and vapor sheet characteristics, gravity, surface wettability, and heater surface temperature distribution on the peak heat flux in flow boiling on cylindrical heaters. The results indicate that burnout is dictated by near-surface effects. The controlling factor appears to be the vapor escape pattern close to the heater surface. It is also shown that a deficiency of liquid at the downstream end of the heater surface is not the cause of burnout.

  11. Pool Boiling of Ethanol-Water mixture on Nano-Textured Surfaces

    NASA Astrophysics Data System (ADS)

    Yarin, Alexander; Sahu, Rakesh; Sinha-Ray, Sumit; Sinha-Ray, Suman

    2015-03-01

    An experimental and theoretical study of pool boiling of ethanol-water mixtures on nano-textured surfaces was studied. A comparison of pool boiling on bare copper surface with pool boiling on surfaces covered by copper-plated supersonically-blown nanofibers revealed a significant increase in the heat flux in the latter case. Namely, the heat flux on the nano-textured surfaces was about 3-8 times higher than that on the bare copper surfaces, while the surface temperature due to the nano-texture would be lower by about 10 C at the same heat flux. The significant positive effect of the nano-texture is due to the fact that it facilitates bubble nucleation. Some preliminary results of numerical modeling of boiling process in the framework of the Cahn-Hilliard approach are discussed and several examples of the predictions are given. Supported by NASA, Grant No. NNX13AQ77G.

  12. Communication: High speed optical investigations of a character of boiling-up onset

    NASA Astrophysics Data System (ADS)

    Gurashkin, A. L.; Starostin, A. A.; Ermakov, G. V.; Skripov, P. V.

    2012-01-01

    In this communication, we discuss the phenomenon of attainable superheat of liquid and the peculiarities of its release by spontaneous boiling-up. We have combined the apparatus for superheating, namely, bubble chamber, with a high speed micro-optical method for detailed monitoring of the initial stage of boiling-up. In experiments on the isothermal pressure drop, it was found that the boiling-up onset of n-hexane is accompanied by characteristic step signal. The signal has proved to be typical of the heterogeneous character of boiling-up onset in a whole range of superheating degrees. The performance of the method for investigation of the refractive index and density for superheated liquids as functions of temperature and pressure has been revealed. The experimental error is estimated to be 0.1%.

  13. Communication: High speed optical investigations of a character of boiling-up onset.

    PubMed

    Gurashkin, A L; Starostin, A A; Ermakov, G V; Skripov, P V

    2012-01-14

    In this communication, we discuss the phenomenon of attainable superheat of liquid and the peculiarities of its release by spontaneous boiling-up. We have combined the apparatus for superheating, namely, bubble chamber, with a high speed micro-optical method for detailed monitoring of the initial stage of boiling-up. In experiments on the isothermal pressure drop, it was found that the boiling-up onset of n-hexane is accompanied by characteristic step signal. The signal has proved to be typical of the heterogeneous character of boiling-up onset in a whole range of superheating degrees. The performance of the method for investigation of the refractive index and density for superheated liquids as functions of temperature and pressure has been revealed. The experimental error is estimated to be 0.1%. PMID:22260557

  14. Zero Boil Off Cryogen Storage for Future Launchers

    NASA Technical Reports Server (NTRS)

    Valentian, D.; Plachta, D.; Kittel, P.; Hastings, L. J.; Salerno, Louis J.; Arnold, James O. (Technical Monitor)

    2001-01-01

    Zero boil off (ZBO) cryogen storage using both cryocoolers and passive insulation technologies will enable long-term exploration missions by allowing designers to optimize tankage without the need for excess cryogen storage to account for boil off. Studies of ZBO (zero boil off) have been on-going in the USA for several years. More recently, a review of the needs of advanced space propulsion took place in Europe. This showed the interest of the European community in cryogenic propulsion for planetary missions as well as the use of liquid hydrogen for large power electric propulsion (manned Mars missions). Although natural boiling could be acceptable for single leg missions, passive insulation techniques yield roughly a I% per month cryogen loss and this would not be cost effective for robotic planetary missions involving storage times greater than one year. To make economic sense, long-term exploration missions require lower tank capacity and longer storage times. Recent advances in cryocooler technology, resulting in vast improvements in both cooler efficiency and reliability, make ZBO is a clear choice for planetary exploration missions. Other, more near term applications of ZBO include boil-off reduction or elimination applied to first and upper stages of future earth-to-orbit (ETO) launchers. This would extend launch windows and reduce infrastructure costs. Successors to vehicles like Ariane 5 could greatly benefit by implementing ZBO. Zero Boil Off will only be successful in ETO launcher applications if it makes economic sense to implement. The energy cost is only a fraction of the total cost of buying liquid cryogen, the rest being transportation and other overhead. Because of this, higher boiling point cryogens will benefit more from on-board liquefaction, thus reducing the infrastructure costs. Since hydrogen requires a liquefier with at least a 17% efficiency just to break even from a cost standpoint, one approach for implementing ZBO in upper stages would be to actively cool the shield in the hydrogen tank to reduce the parasitic losses. This would allow the use of less expensive, presently available coolers (80 K vs. 20 K) and potentially simplify the system by requiring only a single compressor on the pad amd a single disconnect line. The compressor could be a hefty commercial unit, with only the cold head requiring expensive flight development and qualification. While this is actually a reduced boil off configuration rather than a zero-boil off case, if the cryogen loss could be cut significantly, the increase in hold time and reduced need for draining and refilling the propellant tanks could meet the vehicle operations needs in the majority of instances.Bearing in mind the potential benefits of ZBO, NASA AMES and SNECMA Moteurs decided to exchange their technical views on the subject. This paper will present a preliminary analysis for a multi-mission module using a fairly low thrust cryogenic engine and ZBO during cruise. Initial mass is 5.5. tons (in ETO). The cryogenic engine will be used near each periapsis in order to minimize the AV requirement. The payload obtained by this propulsion system is compared to a classical storable bipropellant propulsion system for several cases (e. g. Mars lander, Jupiter orbiter, Saturn orbiter). For the Jupiter and Saturn cases, the power source could be an RTG or a large parabolic mirror illuminating a solar panel. It is shown -that - due to its much larger specific impulse - the cryogenic ZBO solution provides much higher payloads, especially for exploration missions involving landing on planets, asteroids, comets, or other celestial bodies.

  15. Wear Properties of UHMWPE Orientedunder Uniaxial Compression during the Molten State and at Lower Temperatures than the Melting Point

    NASA Astrophysics Data System (ADS)

    Ohta, Makoto; Hyon, Suong-Hyu; Kang, Yu-Bong; Oka, Masanori; Tsutsumi, Sadami; Murakami, Syozo; Kohjiya, Shinzo

    Ultra high molecular weight polyethylene (UHMWPE) has been used as a bearing material for artificial joints since the 1960's, and experience has shown that its wear is one of the limiting factors for long term use in such prosthetic implants. For improving wear resistance, we studied the influence of uniaxial compression on molecule orientation obtained by processing UHMWPE above (Sample A) and below (Sample B) its melting point, respectively. We then compared the wear properties of both UHMWPE samples. Using a slightly cross-linked UHMWPE, sample A was compressed during the molten state. Sample B UHMWPE was compressed at a temperature below the melting point. X-ray refraction tests revealed the (200) crystalline plane of Sample A and B to be oriented parallel to the compression surface. Further tests showed the heat of fusion and the density of Sample A to be higher than Sample B. The storage modulus of Sample A was always higher than in the original untreated UHMWPE (Sample C), while in Sample B it rapidly collapsed with increasing temperature. The ?c-peak of Sample A was shifted to about 5C higher, while the ?c-peak of Sample B was shifted to the lower temperature side and the ?-peak disappeared, compared with Sample C. Reciprocating wear tests carried out over 2106 cycles, showed that the wear resistance of the sample A was enhanced by a factor of 10 when compared to Sample C. UHMWPE compressed during the molten state exhibits superior wear characteristics and has the potential to improve implant technology for artificial joints, potentially providing a longer lifetime.

  16. VLA Shows "Boiling" in Atmosphere of Betelgeuse

    NASA Astrophysics Data System (ADS)

    1998-04-01

    A team of astronomers says that observations with the National Science Foundation's Very Large Array (VLA) radio telescope show that a neighboring bloated star has giant convective plumes propelling gas from its surface (photosphere) up into the star's atmosphere. This new information contradicts long-held ideas that such stellar atmospheres are more uniform, and may resolve questions about how the star's atmosphere attains its enormous size as well as how dust and gas is driven away from the star. Jeremy Lim of the Academia Sinica Institute of Astronomy & Astrophysics in Taiwan; Chris Carilli, Anthony Beasley, and Ralph Marson of the National Radio Astronomy Observatory (NRAO) in Socorro, NM; and Stephen White of the University of Maryland studied the red-supergiant star Betelgeuse, about 430 light-years away in the constellation Orion. They reported their findings in the April 9 issue of the scientific journal Nature. "These radio-telescope images confirm that Betelgeuse -- already more than 600 times larger than our Sun -- has a dense atmosphere that extends to many times larger still than the star itself," said Lim. "The highest-resolution image shows the star's atmosphere to have a remarkably complex structure." "To our surprise," added White, "the images also show that most of the gas in the atmosphere is only about as hot as that on the surface. Previously, all of it was thought to be very much hotter." The astronomers used the VLA to make images of Betelgeuse at a variety of radio frequencies. The series of radio observations measured the temperature of the star's atmosphere at different heights. Previous observations with the Hubble Space Telescope (HST) at ultraviolet wavelengths showed that the star's atmosphere contains very hot gas at about twice the surface temperature. The VLA images showed that there also is lower-temperature gas throughout the atmosphere. This gas is near the surface temperature at low heights and decreases in temperature progressively outwards. Although its existence was not previously suspected, this lower-temperature gas turns out to be the most abundant constituent of Betelgeuse's atmosphere. "This alters our basic understanding of red-supergiant star atmospheres," explains Lim. "Instead of the star's atmosphere expanding uniformly because of gas heated to very high temperatures near its surface, it now appears that several giant convection cells propel gas from the star's surface into its atmosphere. This creates the complex structure we observe for Betelgeuse's atmosphere." Betelgeuse can be likened to an enormous "boiling" ball of gas heated by the release of energy from nuclear fusion in its core. The circulating boiling pattern -- convection -- appears as large regions of hot upwelling gas on the star's surface. "The idea that red-supergiant stars have enormous convection cells is not new," noted Marson. "This was suggested by Martin Schwarzschild more than 20 years ago, and was seen in optical images of Betelgeuse's surface in 1990." The new picture of Betelgeuse's atmosphere also helps resolve the mystery of how massive amounts of dust and gas are expelled from red supergiant stars, an important source of enrichment for the interstellar medium. If their atmospheres were entirely very hot at lower levels, dust grains would not be able to condense there. Dust grains could possibly condense at higher levels, but there they would not get enough "push" from the star's radiation to explain their outward movement. In the new picture, the relatively cool environment at lower levels allows dust grains to condense effectively; here they can be strongly propelled by the more-intense starlight, carrying gas with them. Indeed, dust has previously been inferred to form sporadically near Betelgeuse's surface, but its presence there was difficult to reconcile with the old picture. "This method for propelling the mass outflows of red giant and supergiant stars was proposed by Sun Kwok i

  17. Boiling Heat Transfer to Halogenated Hydrocarbon Refrigerants

    NASA Astrophysics Data System (ADS)

    Yoshida, Suguru; Fujita, Yasunobu

    The current state of knowledge on heat transfer to boiling refrigerants (halogenated hydrocarbons) in a pool and flowing inside a horizontal tube is reviewed with an emphasis on information relevant to the design of refrigerant evaporators, and some recommendations are made for future research. The review covers two-phase flow pattern, heat transfer characteristics, correlation of heat transfer coefficient, influence of oil, heat transfer augmentation, boiling from tube-bundle, influence of return bend, burnout heat flux, film boiling, dryout and post-dryout heat transfer.

  18. Evolution of SF[sub 6] pressure at constant volume versus temperature between liquefaction point and +20[degree]C

    SciTech Connect

    Thuries, E.; Girodet, A.; Collet, M. . Research Center)

    1994-07-01

    Switchgear must be able to operate within a temperature range anywhere from [minus]50 C to +55 C. The practical problem of how to perform significant tests at +20 C then presents itself. It becomes mandatory to know the equivalent of the density at the lowest temperature to which the switchgear will be subjected. A perfect mathematical knowledge of SF[sub 6] evolution at constant volume versus temperature between the liquefaction point and +20 C is then very important. There exists today three main state equations used by SF[sub 6] switchgear users and manufacturers and they do not truly agree between themselves. The authors evaluate them and also describe a simple experiment as defined by E. Thuries to check these state equations. The last part of the paper describes various experimental data that drive one to establish a state equation using the new notion of fugacity. The last part of the paper compares this state equation based on fugacity and the other equations as used today against the results of the new SF[sub 6] Thuries experiment.

  19. Development, solar test, and evaluation of a high-temperature air receiver for point-focusing parabolic dish applications

    NASA Technical Reports Server (NTRS)

    Hanseth, E. J.

    1981-01-01

    A high temperature solar receiver was fabricated and tested in excess of 1370 C on an 11-meter-diameter test bed concentrator at the Jet Propulsion Laboratory Parabolic Dish Test Site, Edwards, California. The 60-kilowatt thermal receiver design utilizes state-of-the-art silicon carbide honeycomb matrix panels to receive and transfer the solar energy and mullite elements for thermal buffer storage. Solar tests were conducted with indicated air exit temperatures ranging from 885 C (1625 F) to 1427 C (2600 F), mass flow rates of 75 to 105 g/sec (0.16 to 0.23 lbm/sec), and pressures up to 265 kPa absolute (38.4 psia). Estimates of efficiency are 59.7% at 1120 C (2048 F) to 80.6% at 885 C (1625 F) when aperture spillage losses are considered separately. Results are presented which demonstrate the feasibility of this innovative receiver concept for point-focusing parabolic dish applications over a wide temperature range.

  20. Synthesis and physical properties of novel perfluorinated methylene oxide oligomers. The ultimate low temperature fluids

    SciTech Connect

    Sung, K.; Lagow, R.J.

    1995-04-19

    Perfluorinated polyethers are a class of substances which are extremely inert and have both extraordinary high temperature stability and low temperature properties. The synthesis of perfluorinated polyformaldehydes with the highest oxygen content was designed to give the maximum liquid range and low temperature properties. Novel low molecular weight perfluorinated polyformaldehydes with stable and unreactive perfluoro-n-butyl end groups were prepared by liquid-phase direct fluorination. The boiling point of these compounds increases by approximately 20{degree}C with the addition of each difluoromethylene oxide unit. This trend does not continue for longer chain lengths (n > 4) where the increase in boiling point per CF{sub 2}O unit diminishes. The average increase of melting temperature is approximately 1-2{degree}C as the perfluorinated polyformaldehyde chain increases one difluoromethylene oxide unit. The new perfluoropolyether fluids produced have melting points ranging from -145 to -152{degree}C. 33 refs., 3 tabs.

  1. Critical heat flux in subcooled flow boiling

    NASA Astrophysics Data System (ADS)

    Hall, David Douglas

    The critical heat flux (CHF) phenomenon was investigated for water flow in tubes with particular emphasis on the development of methods for predicting CHF in the subcooled flow boiling regime. The Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) CHF database for water flow in a uniformly heated tube was compiled from the world literature dating back to 1949 and represents the largest CHF database ever assembled with 32,544 data points from over 100 sources. The superiority of this database was proven via a detailed examination of previous databases. The PU-BTPFL CHF database is an invaluable tool for the development of CHF correlations and mechanistic models that are superior to existing ones developed with smaller, less comprehensive CHF databases. In response to the many inaccurate and inordinately complex correlations, two nondimensional, subcooled CHF correlations were formulated, containing only five adjustable constants and whose unique functional forms were determined without using a statistical analysis but rather using the parametric trends observed in less than 10% of the subcooled CHF data. The correlation based on inlet conditions (diameter, heated length, mass velocity, pressure, inlet quality) was by far the most accurate of all known subcooled CHF correlations, having mean absolute and root-mean-square (RMS) errors of 10.3% and 14.3%, respectively. The outlet (local) conditions correlation was the most accurate correlation based on local CHF conditions (diameter, mass velocity, pressure, outlet quality) and may be used with a nonuniform axial heat flux. Both correlations proved more accurate than a recent CHF look-up table commonly employed in nuclear reactor thermal hydraulic computer codes. An interfacial lift-off, subcooled CHF model was developed from a consideration of the instability of the vapor-liquid interface and the fraction of heat required for liquid-vapor conversion as opposed to that for bulk liquid heating. Severe vapor effusion in an upstream wetting front lifts the vapor-liquid interface off the surface, triggering CHF. Since the model is entirely based on physical observations, it has the potential to accurately predict CHF for other fluids and flow geometries which are beyond the conditions for which it was validated.

  2. Photonically enhanced flow boiling in a channel coated with carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Kousalya, Arun S.; Hunter, Chad N.; Putnam, Shawn A.; Miller, Timothy; Fisher, Timothy S.

    2012-02-01

    High heat dissipation rates are enabled by multi-phase cooling schemes owing to latent heat uptake. We demonstrate enhanced flow boiling from a carbon nanotube (CNT)-coated copper surface exposed to low-intensity ultraviolet (UV)-visible excitation. Compared to non-illuminated results, the average boiling incipience temperature decreased by 4.6 C and heat transfer coefficients improved by 41.5% with light exposure. These improved results are attributed to augmented hydrophilicity upon exposure to UV light and possible nanoscale opto-thermal effects, and suggest opportunities for active temperature control of temperature-sensitive devices.

  3. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  4. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  5. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  6. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  7. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  8. Finite-temperature scaling at the quantum critical point of the Ising chain in a transverse field

    NASA Astrophysics Data System (ADS)

    Haelg, Manuel; Huvonen, Dan; Guidi, Tatiana; Quintero-Castro, Diana Lucia; Boehm, Martin; Regnault, Louis-Pierre; Zheludev, Andrey

    2015-03-01

    Inelastic neutron scattering is used to study the finite-temperature scaling behavior of spin correlations at the quantum critical point in an experimental realization of the one-dimensional Ising model in a transverse field. The target compound is the well-characterized, anisotropic and bond-alternating Heisenberg spin-1 chain material NTENP. The validity and the limitations of the dynamic structure factor scaling are tested, discussed and compared to theoretical predictions. For this purpose neutron data have been collected on the three-axes spectrometers IN14 at ILL and FLEXX at HZB as well as on the time of flight multi-chopper spectrometer LET at ISIS. In addition to the general statement about quantum criticality and universality, present study also reveals new insight into the properties of the spin chain compound NTENP in particular.

  9. Evolution of Skin Temperature after the Application of Compressive Forces on Tendon, Muscle and Myofascial Trigger Point

    PubMed Central

    Magalhes, Marina Figueiredo; Dibai-Filho, Almir Vieira; de Oliveira Guirro, Elaine Caldeira; Girasol, Carlos Eduardo; de Oliveira, Alessandra Kelly; Dias, Fabiana Rodrigues Cancio; Guirro, Rinaldo Roberto de Jesus

    2015-01-01

    Some assessment and diagnosis methods require palpation or the application of certain forces on the skin, which affects the structures beneath, we highlight the importance of defining possible influences on skin temperature as a result of this physical contact. Thus, the aim of the present study is to determine the ideal time for performing thermographic examination after palpation based on the assessment of skin temperature evolution. Randomized and crossover study carried out with 15 computer-user volunteers of both genders, between 18 and 45 years of age, who were submitted to compressive forces of 0, 1, 2 and 3 kg/cm2 for 30 seconds with a washout period of 48 hours using a portable digital dynamometer. Compressive forces were applied on the following spots on the dominant upper limb: myofascial trigger point in the levator scapulae, biceps brachii muscle and palmaris longus tendon. Volunteers were examined by means of infrared thermography before and after the application of compressive forces (15, 30, 45 and 60 minutes). In most comparisons made over time, a significant decrease was observed 30, 45 and 60 minutes after the application of compressive forces (p < 0.05) on the palmaris longus tendon and biceps brachii muscle. However, no difference was observed when comparing the different compressive forces (p > 0.05). In conclusion, infrared thermography can be used after assessment or diagnosis methods focused on the application of forces on tendons and muscles, provided the procedure is performed 15 minutes after contact with the skin. Regarding to the myofascial trigger point, the thermographic examination can be performed within 60 minutes after the contact with the skin. PMID:26070073

  10. SUPERHEATING IN A BOILING WATER REACTOR

    DOEpatents

    Treshow, M.

    1960-05-31

    A boiling-water reactor is described in which the steam developed in the reactor is superheated in the reactor. This is accomplished by providing means for separating the steam from the water and passing the steam over a surface of the fissionable material which is not in contact with the water. Specifically water is boiled on the outside of tubular fuel elements and the steam is superheated on the inside of the fuel elements.

  11. Electrical control and enhancement of boiling heat transfer during quenching

    NASA Astrophysics Data System (ADS)

    Shahriari, Arjang; Hermes, Mark; Bahadur, Vaibhav

    2016-02-01

    Heat transfer associated with boiling degrades at elevated temperatures due to the formation of an insulating vapor layer at the solid-liquid interface (Leidenfrost effect). Interfacial electrowetting (EW) fields can disrupt this vapor layer to promote liquid-surface wetting. We experimentally analyze EW-induced disruption of the vapor layer and measure the resulting enhanced cooling during the process of quenching. Imaging is employed to visualize the fluid-surface interactions and understand boiling patterns in the presence of an electrical voltage. It is seen that EW fields fundamentally change the boiling pattern, wherein a stable vapor layer is replaced by intermittent wetting of the surface. Heat conduction across the vapor gap is thus replaced with transient convection. This fundamental switch in the heat transfer mode significantly accelerates cooling during quenching. An order of magnitude increase in the cooling rate is observed, with the heat transfer seen approaching saturation at higher voltages. An analytical model is developed to extract voltage dependent heat transfer rates from the measured cooling curve. The results show that electric fields can alter and tune the traditional cooling curve. Overall, this study presents an ultralow power consumption concept to control the mechanical properties and metallurgy, by electrically tuning the cooling rate during quenching.

  12. Indo-Pacific Warm Pool Area Expansion, Modoki Activity, and Tropical Cold-Point Tropopause Temperature Variations

    PubMed Central

    Xie, Fei; Li, Jianping; Tian, Wenshou; Li, Yanjie; Feng, Juan

    2014-01-01

    The tropical cold-point tropopause temperature (CPTT), a potentially important indicator of global climate change, is of particular importance for understanding changes in stratospheric water vapor levels. Since the 1980s, the tropical CPTT has shown not only interannual variations, but also a decreasing trend. However, the factors controlling the variations in the tropical CPTT since the 1980s remain elusive. The present study reveals that the continuous expansion of the area of the Indo-Pacific warm pool (IPWP) since the 1980s represents an increase in the total heat energy of the IPWP available to heat the tropospheric air, which is likely to expand as a result. This process lifts the tropical cold-point tropopause height (CPTH) and leads to the observed long-term cooling trend of the tropical CPTT. In addition, our analysis shows that Modoki activity is an important factor in modulating the interannual variations of the tropical CPTT through significant effects on overshooting convection. PMID:24686481

  13. Induction heating pure vapor source of high temperature melting point materials on electron cyclotron resonance ion source

    SciTech Connect

    Kutsumi, Osamu; Kato, Yushi; Matsui, Yuuki; Sato, Fuminobu; Iida, Toshiyuki; Kitagawa, Atsushi; Muramatsu, Masayuki; Uchida, Takashi; Yoshida, Yoshikazu

    2010-02-15

    Multicharged ions that are needed are produced from solid pure material with high melting point in an electron cyclotron resonance ion source. We develop an evaporator by using induction heating (IH) with multilayer induction coil, which is made from bare molybdenum or tungsten wire without water cooling and surrounding the pure vaporized material. We optimize the shapes of induction coil and vaporized materials and operation of rf power supply. We conduct experiment to investigate the reproducibility and stability in the operation and heating efficiency. IH evaporator produces pure material vapor because materials directly heated by eddy currents have no contact with insulated materials, which are usually impurity gas sources. The power and the frequency of the induction currents range from 100 to 900 W and from 48 to 23 kHz, respectively. The working pressure is about 10{sup -4}-10{sup -3} Pa. We measure the temperature of the vaporized materials with different shapes, and compare them with the result of modeling. We estimate the efficiency of the IH vapor source. We are aiming at the evaporator's higher melting point material than that of iron.

  14. Induction heating pure vapor source of high temperature melting point materials on electron cyclotron resonance ion source.

    PubMed

    Kutsumi, Osamu; Kato, Yushi; Matsui, Yuuki; Kitagawa, Atsushi; Muramatsu, Masayuki; Uchida, Takashi; Yoshida, Yoshikazu; Sato, Fuminobu; Iida, Toshiyuki

    2010-02-01

    Multicharged ions that are needed are produced from solid pure material with high melting point in an electron cyclotron resonance ion source. We develop an evaporator by using induction heating (IH) with multilayer induction coil, which is made from bare molybdenum or tungsten wire without water cooling and surrounding the pure vaporized material. We optimize the shapes of induction coil and vaporized materials and operation of rf power supply. We conduct experiment to investigate the reproducibility and stability in the operation and heating efficiency. IH evaporator produces pure material vapor because materials directly heated by eddy currents have no contact with insulated materials, which are usually impurity gas sources. The power and the frequency of the induction currents range from 100 to 900 W and from 48 to 23 kHz, respectively. The working pressure is about 10(-4)-10(-3) Pa. We measure the temperature of the vaporized materials with different shapes, and compare them with the result of modeling. We estimate the efficiency of the IH vapor source. We are aiming at the evaporator's higher melting point material than that of iron. PMID:20192343

  15. Induction heating pure vapor source of high temperature melting point materials on electron cyclotron resonance ion sourcea)

    NASA Astrophysics Data System (ADS)

    Kutsumi, Osamu; Kato, Yushi; Matsui, Yuuki; Kitagawa, Atsushi; Muramatsu, Masayuki; Uchida, Takashi; Yoshida, Yoshikazu; Sato, Fuminobu; Iida, Toshiyuki

    2010-02-01

    Multicharged ions that are needed are produced from solid pure material with high melting point in an electron cyclotron resonance ion source. We develop an evaporator by using induction heating (IH) with multilayer induction coil, which is made from bare molybdenum or tungsten wire without water cooling and surrounding the pure vaporized material. We optimize the shapes of induction coil and vaporized materials and operation of rf power supply. We conduct experiment to investigate the reproducibility and stability in the operation and heating efficiency. IH evaporator produces pure material vapor because materials directly heated by eddy currents have no contact with insulated materials, which are usually impurity gas sources. The power and the frequency of the induction currents range from 100to900W and from 48to23kHz, respectively. The working pressure is about 10-4-10-3Pa. We measure the temperature of the vaporized materials with different shapes, and compare them with the result of modeling. We estimate the efficiency of the IH vapor source. We are aiming at the evaporator's higher melting point material than that of iron.

  16. Visualizational study on nucleate pool boiling phenomena

    NASA Astrophysics Data System (ADS)

    Kamei, Shuya

    1993-01-01

    It is important to visualize the intricate bubble behavior and the strong agitation of liquid near the heating surface to clarify the details concerning boiling mechanism. The visualization of nucleate pool boiling phenomena was confirmed by means of shadowgraphy using a still- camera (Nikon Photomic Camera) with the speed of 2000 frames per second. Illumination was provided by a photo spotlight or a stroboscope. The photographs show that the boiling phenomena and bubbles' behavior are varied for the heat flux of nucleate pool boiling based on the experiments. By considering the effect of revolving angle and the influence of a space between a tube and a tube, experiments have been carried out to investigate the nucleate pool boiling phenomena on horizontal stainless-steel-multi-tube in saturated distilled water. These experiments were performed for atmospheric pressure, for a stainless-tube diameter of 1.0 mm for a length of 80 mm, for a region of natural convection to nucleate boiling near burnout. From these results, photographs show that the successive motion and shape of bubbles during their process of detachment on the heating tube surface varied with increasing heat flux.

  17. Enhanced Heat Rejection of Microscale Geometries in Convective Flow Boiling Evaporators

    NASA Astrophysics Data System (ADS)

    Safford Smith, L. M.; Connacher, W. J.; Cheng, J. C.; Pisano, A. P.

    2013-12-01

    Four surfaces have been designed, fabricated and tested under convective flow boiling (CFB) conditions in an open loop configuration. They contain features in the 10 micron range and were tested with flow velocities under 3 mm/s. To accomplish these flow rates, this work utilizes a constant pressure potential driving flow, instead of the constant flow rate imposed with a syringe pump. This limited device flooding. The evaporation surfaces were tested to the point of dry-out at three different pressure potentials: 150, 650, and 1150 Pa, across a range of powers from 25 W/cm2 to 50 W/cm2. Temperature data was collected from an IR Camera and showed that fluctuations in the wall temperatures exceed 5 C in more than 50% of the tests and reached differences as high as 23 C. The wall temperature instabilities in CFB indicate that one temperature may be inaccurate and that by including time as a variable a better understanding of the behaviour at this scale may be revealed.

  18. Vortex expansion devices for high temperature cryogenics

    NASA Astrophysics Data System (ADS)

    Nash, J. M.

    The authors describe several promising methods which use vortex expansion devices. The author presents an analysis of the thermodynamics of vortex expansion, evaluation of design limitations of vortex tube devices and resulting design enhancements, and results of experiments using the enhanced designs including applications in both high and low temperature cryogenic refrigeration systems. The term high temperature cryogenic describes temperatures ranging from above the boiling point of liquid nitrogen, -320 F (-195 C) up to -58 F (-50 C), the generally defined upper limit of study referred to as cryogenics.

  19. Effect of temperature of CO2 injection on the pH and freezing point of milks and creams.

    PubMed

    Ma, Y; Barbano, D M

    2003-05-01

    The objectives of this study were to measure the impact of CO2 injection temperature (0 degree C and 40 degrees C) on the pH and freezing point (FP) of (a) milks with different fat contents (i.e., 0, 15, 30%) and (b) creams with 15% fat but different fat characteristics. Skim milk and unhomogenized creams containing 15 and 30% fat were prepared from the same batch of whole milk and were carbonated at 0 and 40 degrees C in a continuous flow CO2 injection unit (230 ml/min). At 0 degree C, milk fat was mostly solid; at 40 degrees C, milk fat was liquid. At the same total CO2 concentration with CO2 injection at 0 degree C, milk with a higher fat content had a lower pH and FP, while with CO2 injection at 40 degrees C, milks with 0%, 15%, and 30% fat had the same pH. This indicated that less CO2 was dissolved in the fat portion of the milk when the CO2 was injected at 0 degree C than when it was injected at 40 degrees C. Three creams, 15% unhomogenized cream, 15% butter oil emulsion in skim milk, and 15% vegetable oil emulsion in skim milk were also carbonated and analyzed as described above. Vegetable oil was liquid at both 0 and 40 degrees C. At a CO2 injection temperature of 0 degree C, the 15% vegetable oil emulsion had a slightly higher pH than the 15% butter oil emulsion and the 15% unhomogenized cream, indicating that the liquid vegetable oil dissolved more CO2 than the mostly solid milk fat and butter oil. No difference in the pH or FP of the 15% unhomogenized cream and 15% butter oil emulsion was observed when CO2 was injected at 0 degree C, suggesting that homogenization or physical dispersion of milk fat globules did not influence the amount of CO2 dissolved in milk fat at a CO2 injection temperature of 0 degree C. At a CO2 injection temperature of 40 degrees C and at the same total CO2 concentration, the 15% unhomogenized cream, 15% vegetable oil emulsion, and 15% butter oil emulsion had similar pH. At the same total concentration of CO2 in cream, injection of CO2 at low temperature (i.e., < 4 degrees C) may produce a better antimicrobial effect during refrigerated shelf life due to the higher concentration of CO2 in the skim portion of the cream. PMID:12778568

  20. Pool boiling of water on nano-structured micro wires at sub-atmospheric conditions

    NASA Astrophysics Data System (ADS)

    Arya, Mahendra; Khandekar, Sameer; Pratap, Dheeraj; Ramakrishna, S. Anantha

    2015-10-01

    Past decades have seen active research in enhancement of boiling heat transfer by surface modifications. Favorable surface modifications are expected to enhance boiling efficiency. Several interrelated mechanisms such as capillarity, surface energy alteration, wettability, cavity geometry, wetting transitions, geometrical features of surface morphology, etc., are responsible for change in the boiling behavior of modified surfaces. Not much work is available on pool boiling at low pressures on microscale/nanoscale geometries; low pressure boiling is attractive in many applications wherein low operating temperatures are desired for a particular working fluid. In this background, an experimental setup was designed and developed to investigate the pool boiling performance of water on (a) plain aluminum micro wire (99.999 % pure) and, (b) nano-porous alumina structured aluminum micro wire, both having diameter of 250 µm, under sub-atmospheric pressure. Nano-structuring on the plain wire surface was achieved via anodization. Two samples, A and B of anodized wires, differing by the degree of anodization were tested. The heater length scale (wire diameter) was much smaller than the capillary length scale. Pool boiling characteristics of water were investigated at three different sub-atmospheric pressures of 73, 123 and 199 mbar (corresponding to T sat = 40, 50 and 60 °C). First, the boiling characteristics of plain wire were measured. It was noticed that at sub-atmospheric pressures, boiling heat transfer performance for plain wire was quite low due to the increased bubble sizes and low nucleation site density. Subsequently, boiling performance of nano-structured wires (both Sample A and Sample B) was compared with plain wire and it was noted that boiling heat transfer for the former was considerably enhanced as compared to the plain wire. This enhancement is attributed to increased nucleation site density, change in wettability and possibly due to enhanced pore scale evaporation. A preliminary estimation of the bubble growth rates, measured by high speed videography, was undertaken and compared with classical bubble growth rate correlations. It was observed that the average bubble departure sizes on Sample B were larger as compared to plain wire, due to larger surface forces holding the bubble before departure. Bubble condensation in the thermal boundary layer was also captured.

  1. Design, Construction, and Qualification of a Microscale Heater Array for Use in Boiling Heat Transfer

    NASA Technical Reports Server (NTRS)

    Rule, T. D.; Kim, J.; Kalkur, T. S.

    1998-01-01

    Boiling heat transfer is an efficient means of heat transfer because a large amount of heat can be removed from a surface using a relatively small temperature difference between the surface and the bulk liquid. However, the mechanisms that govern boiling heat transfer are not well understood. Measurements of wall temperature and heat flux near the wall would add to the database of knowledge which is necessary to understand the mechanisms of nucleate boiling. A heater array has been developed which contains 96 heater elements within a 2.5 mm square area. The temperature of each heater element is held constant by an electronic control system similar to a hot-wire anemometer. The voltage that is being applied to each heater element can be measured and digitized using a high-speed A/D converter, and this digital information can be compiled into a series of heat-flux maps. Information for up to 10,000 heat flux maps can be obtained each second. The heater control system, the A/D system and the heater array construction are described in detail. Results are presented which show that this is an effective method of measuring the local heat flux during nucleate and transition boiling. Heat flux maps are obtained for pool boiling in FC-72 on a horizontal surface. Local heat flux variations are shown to be three to six times larger than variations in the spatially averaged heat flux.

  2. Characteristics of Pool Boiling on Graphite-Copper Composite Surfaces

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Yang, Wen-Jei

    2002-01-01

    Nucleate pool boiling performance of different liquids on graphite-copper composite (Gr-Cu) surfaces has been experimentally studied and modeled. Both highly wetting fluids, such as freon-113 and pentane, and a moderately wetting fluid (water) were tested on the Gr-Cu surfaces with different graphite-fiber volume fractions to reveal the enhancement effects of the composite surfaces on the nucleate pool boiling. Results of the experiments show that the graphite-fiber volume fraction has an optimum value. The Gr-Cu composite surface with 25 percent graphite-fiber volume (f=0.25) has a maximum enhancement effect on the nucleate boiling heat transfer comparing to the pure copper surface. For the highly wetting fluid, the nucleate boiling heat transfer is generally enhanced on the Gr- Cu composite surfaces by 3 to 6 times shown. In the low heat flux region, the enhancement is over 6 times, but in the high heat flux region, the enhancement is reduced to about 40%. For the moderately wetting fluid (water), stronger enhancement of nucleate boiling heat transfer is achieved on the composite surface. It shown the experimental results in which one observes the nucleate boiling heat transfer enhancement of 5 to 10 times in the low heat flux region and an enhancement of 3 to 5 times in the high heat flux region. Photographs of bubble departure during the initial stage of nucleate boiling indicate that the bubbles detached from the composite surface are much smaller in diameter than those detached from the pure copper surface. Typical photographs are presented.It shows that the bubbles departed from the composite surface have diameters of only O(0.1) mm, while those departed from the pure copper surface have diameters of O(1) mm. It is also found that the bubbles depart from the composite surface at a much higher frequency, thus forming vapor columns. These two phenomena combined with high thermal conductivity of the graphite fiber are considered the mechanisms for such a significant augmentation in nucleate boiling heat transfer on the composite surfaces. A physical model is developed to describe the phenomenon of bubble departure from the composite surface: The preferred site of bubble nucleation is the fiber tip because of higher tip temperature than the surrounding copper base and poor wettability of the graphite tip compared with that of the base material (copper). The high evaporation rate near the contact line produces the vapor cutback due to the vapor recoil pushing the three-phase line outwards from the fiber tip, and so a neck of the bubble is formed near the bubble bottom. Evaporation and surface tension accelerate the necking process and finally result in the bubble departure while a new small bubble is formed at the tip when the surface tension pushes the three-phase line back to the tip. The process is schematically shown. The proposed model is based on and confirmed by experimental results.

  3. Heat and mass transfer in porous media phase separation at temperatures below the lambda-point of He-4

    NASA Technical Reports Server (NTRS)

    Yuan, S. W. K.; Frederking, T. H. K.

    1986-01-01

    Newtonian fluid motion, coupled to heat transfer via latent heat of phase transition, is well known from numerous studies of condensation and boiling. Considerably less knowledge is available for vapor-liquid phase separation in the absence of gravity effect on the transport phenomena. The present studies are focused on heat and mass transfer associated with vapor-liquid phase separation required for long-term storage of the cryogen liquid He II in space vessels. Though space conditions are the dominant mode of interest in advanced equipment, e.g. IR telescopes, the systems may be operated in principle during terrestrial conditions. The latter are considered in the present work. It emphasizes the linear regime including an extrapolation based on variable thermophysical properties. Data taken with a phase separation approach show departures from the linear regime prediction. They agree with a transport equation proposed for the nonlinear, turbulent regime.

  4. Microgravity experiments on boiling behavior of self-wetting fluid

    NASA Astrophysics Data System (ADS)

    Abe, Y.; Iwasaki, A.

    Although most of fluids show a decrease in the surface tension with increasing temperature, some fluids show abnormal behavior- the surface tension increases with the increase in temperature. In the case of boiling phenomena, the thermocapillary flow due t o temperature gradient at the liquid/vapor interface should induce a liquid supply to a dry patch or hot spot developed under bubble. "Self- wetting" termed in this paper came from such a behavior of spontaneous liquid supply. Aqueous solutions of high carbon alcohols have been known as a fluid with such an abnormal surface tension behavior. In addition to the thermocapillary flow induced by temperature gradient, the Marangoni effect due to concentration gradient around liquid/vapor interface should occur, since the component of vapor phase is characterized to be either alcohol-rich or water-rich by preferential evaporation, as far as non-azeotropic components are concerned. In some components, the direction of thermocapillary flow is the same as the direction of the Marangoni flow induced by concentration gradient, which should even enhance the self-wettability. The present authors have carried out a series of microgravity experiments at JAMIC to observe the fundamental boiling behavior of self-wetting fluid (1-butanol aqueous solution, in the present study), and compared with CFC -113 and ethanol aqueous solution. The flow around adjacent dual bubbles and the flow under a single bubble are discussed.

  5. Flash Points of Secondary Alcohol and n-Alkane Mixtures.

    PubMed

    Esina, Zoya N; Miroshnikov, Alexander M; Korchuganova, Margarita R

    2015-11-19

    The flash point is one of the most important characteristics used to assess the ignition hazard of mixtures of flammable liquids. To determine the flash points of mixtures of secondary alcohols with n-alkanes, it is necessary to calculate the activity coefficients. In this paper, we use a model that allows us to obtain enthalpy of fusion and enthalpy of vaporization data of the pure components to calculate the liquid-solid equilibrium (LSE) and vapor-liquid equilibrium (VLE). Enthalpy of fusion and enthalpy of vaporization data of secondary alcohols in the literature are limited; thus, the prediction of these characteristics was performed using the method of thermodynamic similarity. Additionally, the empirical models provided the critical temperatures and boiling temperatures of the secondary alcohols. The modeled melting enthalpy and enthalpy of vaporization as well as the calculated LSE and VLE flash points were determined for the secondary alcohol and n-alkane mixtures. PMID:26491811

  6. Natural saltwater upconing by preferential groundwater discharge through boils

    NASA Astrophysics Data System (ADS)

    de Louw, P. G. B.; Vandenbohede, A.; Werner, A. D.; Oude Essink, G. H. P.

    2013-05-01

    Natural saltwater upconing caused by the preferential groundwater discharge of boils is a key process in the salinization of Dutch deep polders. The factors controlling upconing by boil discharge and boil water salinities are poorly constrained and have not been previously documented. We addressed this knowledge gap by investigating upconing mechanisms using field measurements and numerical simulations of simplified situations. Boils occur as conduits in the upper aquitard connecting the underlying aquifer to the surface and allowing groundwater to discharge at rates up to 100 m3 d-1 with Cl concentrations up to 5 g L-1. Boils are found as isolated features or clustered in small areas of 20-100 m2. Field observations show that preferential flow through boils creates localized and narrow saltwater upconing spikes, causing the elevated boil water salinities. Modeling results indicate that boil water in Dutch polders comprises mixtures of groundwater from a wide range of depths and salinities with larger contributions from shallower and less saline groundwater than from the deeper and more saline water. Similar to previous numerical studies of pumping-induced upconing, the numerical results show that the most important factors controlling the boil salinity in Dutch polders are boil discharge, the horizontal hydraulic conductivity of the aquifer, the depth of the transition zone and the salinity (or density) contrast within the aquifer. When boils are clustered, natural saltwater upconing is a function of the total discharge of a boil cluster, whereas the boil-to-boil salinity variations within a cluster are determined by the discharge of individual boils and their position relative to neighboring boils. Regional lateral flow significantly modifies flow patterns by dividing the groundwater flow system into a local boil system overlying the regional flow system. Despite this, regional flow has only a minor effect on the relative contributions of saline and fresh groundwater to boil discharge and thus on boil salinity as well.

  7. Effects of Temperature and pH on Reduction of Bacteria in a Point-of-Use Drinking Water Treatment Product for Emergency Relief

    PubMed Central

    Marois-Fiset, Jean-Thomas; Carabin, Anne; Lavoie, Audrey

    2013-01-01

    The effects of temperature and pH on the water treatment performance of a point-of-use (POU) coagulant/disinfectant product were evaluated. Cold temperatures (?5C) reduced the bactericidal efficiency of the product with regard to Escherichia coli and total coliform log10 reductions. PMID:23335762

  8. Cryogenic Boil-Off Reduction System

    NASA Astrophysics Data System (ADS)

    Plachta, David W.; Guzik, Monica C.

    2014-03-01

    A computational model of the cryogenic boil-off reduction system being developed by NASA as part of the Cryogenic Propellant Storage and Transfer technology maturation project has been applied to a range of propellant storage tanks sizes for high-performing in-space cryogenic propulsion applications. This effort focuses on the scaling of multi-layer insulation (MLI), cryocoolers, broad area cooling shields, radiators, solar arrays, and tanks for liquid hydrogen propellant storage tanks ranging from 2 to 10 m in diameter. Component scaling equations were incorporated into the Cryogenic Analysis Tool, a spreadsheet-based tool used to perform system-level parametric studies. The primary addition to the evolution of this updated tool is the integration of a scaling method for reverse turbo-Brayton cycle cryocoolers, as well as the development and inclusion of Self-Supporting Multi-Layer Insulation. Mass, power, and sizing relationships are traded parametrically to establish the appropriate loiter period beyond which this boil-off reduction system application reduces mass. The projected benefit compares passive thermal control to active thermal control, where active thermal control is evaluated for reduced boil-off with a 90 K shield, zero boil-off with a single heat interception stage at the tank wall, and zero boil-off with a second interception stage at a 90 K shield. Parametric studies show a benefit over passive storage at loiter durations under one month, in addition to showing a benefit for two-stage zero boil-off in terms of reducing power and mass as compared to single stage zero boil-off. Furthermore, active cooling reduces the effect of varied multi-layer insulation performance, which, historically, has been shown to be significant.

  9. Contaminant Recovery during In-Situ Boiling in Rock

    NASA Astrophysics Data System (ADS)

    Chen, F.; Liu, X.; Falta, R. W.; Murdoch, L. C.

    2009-12-01

    In-situ boiling may be an effective mechanism for removing contaminants from tight rock matrix where they would otherwise be all but inaccessible. Heating the matrix above the boiling temperature and then depressurizing will induce boiling that leads to large gas-phase pressure gradients and a steam stripping effect that can remove the contaminants from the matrix. Despite the promise of this process, it has not yet been demonstrated in the field or laboratory, and the controlling parameters and limits of the process are poorly understood. The objective of this project is to characterize mass transfer during boiling in saturated rock. We built an experimental apparatus to heat cores (5cmx30cm) of contaminated rock in a pressurized vessel. The core was sealed in Teflon tube with metal end caps and wrapped with a strip heater. Additional heaters were located in the end caps. Sensors were placed on the surface and embedded within the core to monitor the temperature. An insulation layer covered the strip heater to minimize the heat loss. A recent test was conducted using Berea sandstone (18 millidarcy) initially saturated with de-aired water and contaminated by injecting 200ml (about 2 pore volumes) containing 200mg/L of 1,2-dichloroethane (1,2-DCA), 10 mg/L of chlorobenzene (CB), and 195 mg/L sodium bromide (NaBr). The solution was circulated and both inlet and outlet concentrations were monitored. After the contaminant injection, both the inlet and outlet valves were closed and the core was heated at a constant power of 31.3 watts. Pressure and temperature increased for 3 hours until temperatures exceeded 100 C. A valve on the outlet tube was opened and steam flow started immediately and was routed through a condenser. Concentrations of chlorinated solvents in the outflow increased abruptly to between 6 and 10 times the input concentration. The concentrations decreased after a few 10s of ml were recovered, and at least 80 to 90 percent of the contaminant masses were recovered in less than half of a pore volume of water. Interestingly, bromide was essentially absent from the recovered water containing the chlorinated solvents. These observations indicate that contaminants were stripped by a continuous steam phase that developed in the pore space of the sandstone throughout the length of the core. Volatile compounds were effectively transported to the steam-filled channels while leaving the non-volatile ionic compounds behind in the remaining water. This is significant because experimentally demonstrating this steam stripping mechanism is the first step toward developing a technique for effectively recovering contaminants from the matrix of fractured rock.

  10. Results of the DF-4 BWR (boiling water reactor) control blade-channel box test

    SciTech Connect

    Gauntt, R.O.; Gasser, R.D.

    1990-10-01

    The DF-4 in-pile fuel damage experiment investigated the behavior of boiling water reactor (BWR) fuel canisters and control blades in the high temperature environment of an unrecovered reactor accident. This experiment, which was carried out in the Annular Core Research Reactor (ACRR) at Sandia National Laboratories, was performed under the USNRC's internationally sponsored severe fuel damage (SFD) program. The DF-4 test is described herein and results from the experiment are presented. Important findings from the DF-4 test include the low temperature melting of the stainless steel control blade caused by reaction with the B{sub 4}C, and the subsequent low temperature attack of the Zr-4 channel box by the relocating molten blade components. Hydrogen generation was found to continue throughout the experiment, diminishing slightly following the relocation of molten oxidizing zircaloy to the lower extreme of the test bundle. A large blockage which was formed from this material continued to oxidize while steam was being fed into the the test bundle. The results of this test have provided information on the initial stages of core melt progression in BWR geometry involving the heatup and cladding oxidation stages of a severe accident and terminating at the point of melting and relocation of the metallic core components. The information is useful in modeling melt progression in BWR core geometry, and provides engineering insight into the key phenomena controlling these processes. 12 refs., 12 figs.

  11. Flow boiling inside enhanced heat transfer tubes

    SciTech Connect

    Xiang, G.M.; Hu, H.Y.; Peng, X.F.; Wang, B.X.

    1996-12-31

    A tube with longitudinal microchannels on the inside wall was developed to enhance flow boiling heat transfer. The experimental investigation was conducted to identify the flow boiling heat transfer performance of liquid through the enhanced tubes. The flow boiling heat transfer in the enhanced tubes is greatly intensified, especially for the fully-developed nucleate boiling regime. The heat transfer coefficient in microchanneled tubes with smaller diameter is increased with a magnitude of 170% compared with the identical smooth tubes. The geometric configuration of microchannels and tubes would have significant effect of the flow boiling inside microchanneled tubes. The heat transfer performance of the microchanneled tubes is as good as or even better than that of other existing enhanced tubes. Liquid-vapor phase change heat and mass transport phenomenon is frequently encountered in many practical applications, such as in chemical and petrochemical industry, power generation, air conditioning and refrigeration. Phase change heat exchangers and equipment, including evaporators, condenser and reboilers, are widely used in these cases.

  12. The effect of surface gas injection on film boiling heat transfer

    SciTech Connect

    Duignan, M.R.; Greene, G.A.; Irvine, T.F. Jr.

    1991-12-31

    A database was developed for heat transfer from a horizontal plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. At the highest superficial gas velocity measured, approximately 8.5 cm/s, and for a constant surface temperature, the heat transfer increases by a factor of two over the heat transfer with no enhancement by gas flux. Further, as the superficial gas velocity approached zero, the data approach the stable film boiling asymptote. A semi-empirical model was developed and correlated to the database. The result is an equation which represents better than 90% of all the measured data within {plus_minus}15% bounds.

  13. The effect of surface gas injection on film boiling heat transfer

    SciTech Connect

    Duignan, M.R. ); Greene, G.A. ); Irvine, T.F. Jr. )

    1991-01-01

    A database was developed for heat transfer from a horizontal plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. At the highest superficial gas velocity measured, approximately 8.5 cm/s, and for a constant surface temperature, the heat transfer increases by a factor of two over the heat transfer with no enhancement by gas flux. Further, as the superficial gas velocity approached zero, the data approach the stable film boiling asymptote. A semi-empirical model was developed and correlated to the database. The result is an equation which represents better than 90% of all the measured data within {plus minus}15% bounds.

  14. Facilitating Students' Conceptual Understanding of Boiling Using a Four-Step Constructivist Teaching Method

    ERIC Educational Resources Information Center

    Calik, Muammer

    2008-01-01

    The aim of the work presented here was to devise an activity associated with factors affecting boiling points. The intervention used a four-step constructivist-based teaching strategy, which was subsequently evaluated by a cohort of students. Data collection consisted of application of a purpose designed questionnaire consisting of four open-ended

  15. Radiance Temperatures (in the Wavelength Range 530 to 1500 nm) of Nickel at Its Melting Point by a Pulse-Heating Technique

    NASA Astrophysics Data System (ADS)

    Kaschnitz, E.; McClure, J. L.; Cezairliyan, A.

    1998-11-01

    The radiance temperatures (at seven wavelengths in the range 530 to 1500 nm) of nickel at its melting point were measured by a pulse-heating technique. The method is based on rapid resistive self-heating of the specimen from room temperature to its melting point in less than 1 s and on simultaneously measuring specimen radiance temperatures every 0.5 ms. Melting of the specimen was manifested by a plateau in the radiance temperature-versus-time function for each wavelength. The melting-point radiance temperatures for a given specimen were determined by averaging the measured temperatures along the plateau at each wavelength. The melting-point radiance temperatures for nickel, as determined by averaging the results at each wavelength for 25 specimens, are: 1641 K at 530 nm, 1615 K at 627 nm, 1606 K at 657 nm, 1589 K at 722 nm, 1564 K at 812 nm, 1538 K at 908 nm, and 1381 K at 1500 nm. Based on uncertainties arising from pyrometry and specimen conditions, the combined uncertainty (two standard-deviation level) is about 6 K for the reported values in the range 530 to 900 nm and is about 8 K for the reported value at 1500 nm.

  16. A polymer electrolyte for operation at temperatures up to 200 C

    SciTech Connect

    Savinell, R.; Yeager, E.; Tryk, D.; Landau, U.; Wainright, J.; Weng, D.; Lux, K.; Litt, M.; Rogers, C. . Case Center for Electrochemical Sciences)

    1994-04-01

    In developing advanced fuel cells and other electrochemical reactors, it is desirable to combine the advantages of solid polymer electrolytes with the enhanced catalytic activity associated with temperatures above 100 C. This will require polymer electrolytes which retain high ionic conductivity at temperatures above the boiling point of water. One possibility is to equilibrate standard perfluorosulfonic acid polymer electrolytes such as Nafion, with a high boiling point Bronsted base such as phosphoric acid. The Nafion/H[sub 3]PO[sub 4] electrolyte has been evaluated with respect to water content, ionic conductivity and transport of oxygen, and methanol vapor. The results show that at elevated temperatures reasonably high conductivity (>0.05 [Omega][sup [minus]1] cm[sup [minus]1]) can be obtained. Methanol permeability is shown to be proportional to the methanol vapor activity and thus decreases with increasing temperature for a given partial pressure. Comparisons and distinctions between this electrolyte and pure phosphoric acid are also considered.

  17. How does surface wettability influence nucleate boiling?

    NASA Astrophysics Data System (ADS)

    Phan, Hai Trieu; Caney, Nadia; Marty, Philippe; Colasson, Stphane; Gavillet, Jrme

    2009-05-01

    Although the boiling process has been a major subject of research for several decades, its physics still remain unclear and require further investigation. This study aims at highlighting the effects of surface wettability on pool boiling heat transfer. Nanocoating techniques were used to vary the water contact angle from 20 to 110 by modifying nanoscale surface topography and chemistry. The experimental results obtained disagree with the predictions of the classical models. A new approach of nucleation mechanism is established to clarify the nexus between the surface wettability and the nucleate boiling heat transfer. In this approach, we introduce the concept of macro- and micro-contact angles to explain the observed phenomenon. To cite this article: H.T. Phan et al., C. R. Mecanique 337 (2009).

  18. The influence of oil on nucleate pool boiling heat transfer

    NASA Astrophysics Data System (ADS)

    Spindler, Klaus; Hahne, Erich

    2009-05-01

    The influence of various oil contents in R134a is investigated for nucleate pool boiling on copper tubes either sandblasted or with enhanced heating surfaces (GEWA-B tube). Polyolester oils (POE) (Reniso Triton) with medium viscosity 55 cSt (SE55) and high viscosity 170 cSt (SE170) were used. Heat transfer coefficients were obtained for boiling temperatures between -28.6 and +20.1C. The oil content varied from 0 to 5% mass fraction. For the sandblasted tube and the SE55 oil the heat transfer coefficients for the refrigerant/oil-mixture can be higher or lower than those for the pure refrigerant, depending on oil mass fraction, boiling temperature and heat flux. In some cases the highest heat transfer coefficients were obtained at a mass fraction of 3%. For the 170 cSt oil there is a clear decrease in heat transfer for all variations except for a heat flux 4,000 W/m2 and -10.1C at 0.5% oil content. The heat transfer coefficients are compared to those in the literature for a smooth stainless steel tube and a platinum wire. For the enhanced tube and 55 cSt oil the heat transfer coefficients are clearly below those for pure refrigerant in all cases. The experimental results for the sandblasted tube are compared with the correlation by Jensen and Jackman. The calculated values are within +20 and -40% for the medium viscosity oil and between +50% and -40% for the high viscosity oil. A correlation for predicting oil-degradation effects on enhanced surfaces does not exist.

  19. Boiling as household water treatment in Cambodia: a longitudinal study of boiling practice and microbiological effectiveness.

    PubMed

    Brown, Joseph; Sobsey, Mark D

    2012-09-01

    This paper focuses on the consistency of use and microbiological effectiveness of boiling as it is practiced in one study site in peri-urban Cambodia. We followed 60 randomly selected households in Kandal Province over 6 months to collect longitudinal data on water boiling practices and effectiveness in reducing Escherichia coli in household drinking water. Despite > 90% of households reporting that they used boiling as a means of drinking water treatment, an average of only 31% of households had boiled water on hand at follow-up visits, suggesting that actual use may be lower than self-reported use. We collected 369 matched untreated and boiled water samples. Mean reduction of E. coli was 98.5%; 162 samples (44%) of boiled samples were free of E. coli (< 1 colony-forming unit [cfu]/100 mL), and 270 samples (73%) had < 10 cfu/100 mL. Storing boiled water in a covered container was associated with safer product water than storage in an uncovered container. PMID:22826487

  20. Boiling as Household Water Treatment in Cambodia: A Longitudinal Study of Boiling Practice and Microbiological Effectiveness

    PubMed Central

    Brown, Joseph; Sobsey, Mark D.

    2012-01-01

    This paper focuses on the consistency of use and microbiological effectiveness of boiling as it is practiced in one study site in peri-urban Cambodia. We followed 60 randomly selected households in Kandal Province over 6 months to collect longitudinal data on water boiling practices and effectiveness in reducing Escherichia coli in household drinking water. Despite > 90% of households reporting that they used boiling as a means of drinking water treatment, an average of only 31% of households had boiled water on hand at follow-up visits, suggesting that actual use may be lower than self-reported use. We collected 369 matched untreated and boiled water samples. Mean reduction of E. coli was 98.5%; 162 samples (44%) of boiled samples were free of E. coli (< 1 colony-forming unit [cfu]/100 mL), and 270 samples (73%) had < 10 cfu/100 mL. Storing boiled water in a covered container was associated with safer product water than storage in an uncovered container. PMID:22826487

  1. Boiling behavior of sodium-potassium alloy in a bench-scale solar receiver

    NASA Astrophysics Data System (ADS)

    Moreno, J. B.; Andraka, C. E.; Moss, T. A.

    During 1989-90, a 75-kW(sub t) sodium reflux pool-boiler solar receiver was successfully demonstrated at Sandia National Laboratories. Significant features of this receiver include the following: (1) boiling sodium as the heat transfer medium, and (2) electric-discharge-machined (EDM) cavities as artificial nucleation sites to stabilize boiling. Since this first demonstration, design of a second-generation pool-boiler receiver that will bring the concept closer to commercialization has begun. For long life, the new receiver uses Haynes Alloy 230. For increased safety factors against film boiling and flooding, it has a refined shape and somewhat larger dimensions. To eliminate the need for trace heating, the receiver will boil the sodium-potassium alloy NaK-78 instead of sodium. To reduce manufacturing costs, it will use one of a number of alternatives to EDM cavities for stabilization of boiling. To control incipient-boiling superheats, especially during hot restarts, it will contain a small amount of inert gas. Before the new receiver design could be finalized, bench-scale tests of some of the proposed changes were necessary. A series of bench-scale pool boilers were built from Haynes Alloy 230 and filled with NaK-78. Various boiling-stabilizer candidates were incorporated into them, including laser-drilled cavities and a number of different sintered-powder-metal coatings. These bench-scale pool boilers have been operated at temperatures up to 750 C, heated by quartz lamps with incident radiant fluxes up to 95 W/sq cm. The effects of various orientations and added gases have been studied. Results of these studies are presented.

  2. Enhanced Boiling on Micro-Configured Composite Surfaces Under Microgravity Conditions

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chai, An-Ti

    1999-01-01

    In order to accommodate the growing thermal management needs of future space platforms, several two-phase active thermal control systems (ATCSs) have evolved and were included in the designs of space stations. Compared to the pumped single-phase liquid loops used in the conventional Space Transportation System and Spacelab, ATCSs offer significant benefits that may be realized by adopting a two-phase fluid-loop system. Alternately, dynamic power systems (DPSs), based on the Rankine cycle, seem inevitably to be required to supply the electrical power requirements of expanding space activities. Boiling heat transfer is one of the key technologies for both ATCSs and DPSs. Nucleate boiling near critical heat flux (CHF) can transport very large thermal loads with much smaller device size and much lower pumping power. However, boiling performance deteriorates in a reduced gravity environment and operation in the CHF regime is precarious because any slight overload will cause the heat transfer to suddenly move to the film boiling regime, which in turn, will result in burnout of the heat transfer surfaces. New materials, such as micro-configured metal-graphite composites, can provide a solution for boiling enhancement. It has been shown experimentally that this type of material manifests outstanding boiling heat transfer performance and their CHF is also extended to higher values. Due to the high thermal conductivity of graphite fiber (up to 1,200 W/m-K in the fiber direction), the composite surfaces are non-isothermal during the boiling process. The composite surfaces are believed to have a much wider safe operating region (a more uniform boiling curve in the CHF regime) because non-isothermal surfaces have been found to be less sensitive to variations of wall superheat in the CHF regime. The thermocapillary forces formed by the temperature difference between the fiber tips and the metal matrix play a more important role than the buoyancy in the bubble detachment, for the bubble detachment manifests itself by a necking process which should not be weakened by reduced gravity. In addition, the composite surfaces introduce no extra pressure drop, no fouling and do not impose significant primary or maintenance costs. All of these suggest that this type of composite is an ideal material for the challenge of accounting for both reliability and economy of the relevant components applied in the ATCSs, the DPSs and other devices in future space missions. The aim of the proposed work is to experimentally investigate high nucleate pool boiling performance on a micro-configured metal-graphite composite surface and to determine the mechanisms of the nucleate boiling heat transfer both experimentally and theoretically. Freon-113 and water will be used as the test liquids to investigate wettability effects on boiling characteristics. The Cu-Gr and Al-Gr composites with various volume fractions of graphite fibers will be tested to obtain the heat transfer characteristic data in the nucleate boiling region and in the CHF regime. In the experiments, the bubble emission and coalescence processes will be recorded by a video camera with a magnifying borescope probe immersed in the working fluid. The temperature profile in the thermal boundary layer on the composite surfaces will be measured by a group of micro thermocouples consisting of four ultra fine micro thermocouples. This instrument was developed and successfully used to measure the temperature profile of evaporating liquid thin layers by the proposers in a study performed at the NASA/Lewis Research Center. A two tier model to explain the nucleate boiling process and the performance enhancement on the composite surfaces has been suggested by the authors. According to the model, the thicknesses of the microlayer and the macrolayer underneath the bubbles and mushrooms, can be estimated by the geometry of the composite surface. The experimental results will be compared to the predictions from the model, and in turn, to revise and improve it.

  3. Design and test of a compact optics system for the pool boiling experiment

    NASA Technical Reports Server (NTRS)

    Ling, Jerri S.; Laubenthal, James R.

    1990-01-01

    The experiment described seeks to improve the understanding of the fundamental mechanisms that constitute nucleate pool boiling. The vehicle for accomplishing this is an investigation, including tests to be conducted in microgravity and coupled with appropriate analyses, of the heat transfer and vapor bubble dynamics associated with nucleation, bubble growth/collapse and subsequent motion, considering the interrelations between buoyancy, momentum and surface tension which will govern the motion of the vapor and surrounding liquid, as a function of the heating rate at the heat transfer surface and the temperature level and distribution in the bulk liquid. The experiment is designed to be contained within the confines of a Get-Away-Special Canister (GAS Can) installed in the bay of the space shuttle. When the shuttle reaches orbit, the experiment will be turned on and testing will proceed automatically. In the proposed Pool Boiling Experiment a pool of liquid, initially at a precisely defined pressure and temperature, will be subjected to a step imposed heat flux from a semitransparent thin-film heater forming part of one wall of the container such that boiling is initiated and maintained for a defined period of time at a constant pressure level. Transient measurements of the heater surface and fluid temperatures near the surface will be made, noting especially the conditions at the onset of boiling, along with motion photography of the boiling process in two simultaneous views, from beneath the heating surface and from the side. The conduct of the experiment and the data acquisition will be completely automated and self-contained. For the initial flight, a total of nine tests are proposed, with three levels of heat flux and three levels of subcooling. The design process used in the development and check-out of the compact photographic/optics system for the Pool Boiling Experiment is documented.

  4. Steady state boiling crisis in a helium vertically heated natural circulation loop - Part 1: Critical heat flux, boiling crisis onset and hysteresis

    NASA Astrophysics Data System (ADS)

    Furci, H.; Baudouy, B.; Four, A.; Meuris, C.

    2016-01-01

    Experiments were conducted on a 2-m high two-phase helium natural circulation loop operating at 4.2 K and 1 atm. The same loop was used in two experiments with different heated section internal diameter (10 and 6 mm). The power applied on the heated section wall was controlled in increasing and decreasing sequences, and temperature along the section, mass flow rate and pressure drop evolutions were recorded. The values of critical heat flux (CHF) were found at different positions of the test section, and the post-CHF regime was studied. The predictions of CHF by existing correlations were good in the downstream portion of the section, however CHF anomalies have been observed near the entrance, in the low quality region. In resonance with this, the re-wetting of the surface has distinct hysteresis behavior in each of the two CHF regions. Furthermore, hydraulics effects of crisis, namely on friction, were studied (Part 2). This research is the starting point to future works addressing transients conducing to boiling crisis in helium natural circulation loops.

  5. An Investigation of Graduate Scientists' Understandings of Evaporation and Boiling.

    ERIC Educational Resources Information Center

    Goodwin, Alan; Orlik, Yuri

    2000-01-01

    Uses a video presentation of six situations relating to the evaporation and boiling of liquids and the escape of dissolved gases from solution and investigates graduate scientists' understanding of the concepts of boiling and evaporation. (Author/YDS)

  6. Accurate experimental determination of the isotope effects on the triple point temperature of water. II. Combined dependence on the 18O and 17O abundances

    NASA Astrophysics Data System (ADS)

    Faghihi, V.; Kozicki, M.; Aerts-Bijma, A. T.; Jansen, H. G.; Spriensma, J. J.; Peruzzi, A.; Meijer, H. A. J.

    2015-12-01

    This paper is the second of two articles on the quantification of isotope effects on the triple point temperature of water. In this second article, we address the combined effects of 18O and 17O isotopes. We manufactured five triple point cells with waters with 18O and 17O abundances exceeding widely the natural abundance range while maintaining their natural 18O/17O relationship. The 2H isotopic abundance was kept close to that of VSMOW (Vienna Standard Mean Ocean Water). These cells realized triple point temperatures ranging between???220 ?K to 1420 ?K with respect to the temperature realized by a triple point cell filled with VSMOW. Our experiment allowed us to determine an accurate and reliable value for the newly defined combined 18, 17O correction parameter of AO??=??630 ?K with a combined uncertainty of 10 ?K. To apply this correction, only the 18O abundance of the TPW needs to be known (and the water needs to be of natural origin). Using the results of our two articles, we recommend a correction equation along with the coefficient values for isotopic compositions differing from that of VSMOW and compare the effect of this new equation on a number of triple point cells from the literature and from our own institute. Using our correction equation, the uncertainty in the isotope correction for triple point cell waters used around the world will be??<1 ?K.

  7. 46 CFR 154.705 - Cargo boil-off as fuel: General.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Cargo boil-off as fuel: General. 154.705 Section 154.705 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control...

  8. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  9. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  10. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  11. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  12. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  13. The effect of water subcooling on film boiling heat transfer from vertical cylinders

    SciTech Connect

    Greene, G.A.; Irvine, T.F. Jr.

    1994-03-01

    The effect of subcooling on the film boiling heat transfer of water from vertical copper cylinders has been investigated experimentally using a transient quench technique. A lumped parameter model was utilized since the Blot numbers were always less than 0.05. The amount of subcooling varied from 0 K to 70 K and the initial cylinder wall temperatures were of the order of 1100 K. Heat transfer coefficient were measured at the midpoint of the cylinders and were obtained over quench times in which they were verified to be constant. Subcooling had a significant effect on both the film boiling heat transfer coefficient and the minimum film boiling temperature. As the subcooling varied from 0 K to 70 K, the h transfer coefficient increased by a factor of five. As the subcooling varied from 0 K to 60 K, the minimum film boiling temperature increased from approximately 600 K to 1000 K. An attempt to correlate the heat transfer coefficient data with a method recently proposed by Sakurai et al. was only successful at subcooled temperature differences less than 10 K. A modified correlation is presented using the Sakurai et al. parameters which better represents the data over the complete subcooling range.

  14. Apparatus to measure liquid helium boil-off from low-loss superconducting current leads

    SciTech Connect

    Cha, Y.S.; Niemann, R.C.; Hull, J.R.

    1995-06-01

    A low-loss liquid helium dewar was constructed to measure the liquid helium boil-off rate from high-temperature superconducting current leads. The dewar has a measured background heat leakage rate of 12 mW. Equations calculating the heat leakage rate from the measured vapor mass flow rate in liquid helium boil-off experiments are derived. Parameters that affect the experiments, such as density ratio, absolute pressure, and rate of pressure variation, are discussed. This study is important as superconducting current leads may be used in superconducting magnetic energy storage systems.

  15. Big Bubbles in Boiling Liquids: Students' Views

    ERIC Educational Resources Information Center

    Costu, Bayram

    2008-01-01

    The aim of this study was to elicit students' conceptions about big bubbles in boiling liquids (water, ethanol and aqueous CuSO[subscript 4] solution). The study is based on twenty-four students at different ages and grades. The clinical interviews technique was conducted to solicit students' conceptions and the interviews were analyzed to…

  16. Electrohydrodynamic Pool Boiling in Reduced Gravity

    NASA Technical Reports Server (NTRS)

    Shaw, Benjamin D.; Stahl, S. L.

    1996-01-01

    This research is concerned with studying the effects of applied electric fields on pool boiling in a reduced-gravity environment. Experiments are conducted at the NASA Lewis 2.2 sec Drop tower using a drop rig constructed at UC Davis. In the experiments, a platinum wire is heated while immersed in saturated liquid refrigerants (FC-72 and FC-87), or water, causing vapor formation at the wire surface. Electric fields are applied between the wire surface and an outer screen electrode that surrounds the wire. Preliminary normal-gravity experiments with water have demonstrated that applied electric fields generated by the rig electronics can influence boiling characteristics. Reduced-gravity experiments will be performed in the summer of 1996. The experiments will provide fundamental data on electric field strengths required to disrupt film boiling (for various wire heat generation input rates) in reduced gravity for a cylindrical geometry. The experiments should also shed light on the roles of characteristic bubble generation times and charge relaxation times in determining the effects of electric fields on pool boiling. Normal-gravity comparison experiments will also be performed.

  17. The Plausibility of Boiling Geysers on Triton

    NASA Technical Reports Server (NTRS)

    Duxbury, N. S.; Brown, R. H.

    1995-01-01

    A mechanism is suggested and modeled whereby there may be boiling geysers on Triton. The geysers would be of nitrogen considering that Voyager detected cryovolcanic activity, that solid nitrogen conducts heat much less than water ice, and that there is internal heat on Triton.

  18. Classic and Hard-Boiled Detective Fiction.

    ERIC Educational Resources Information Center

    Reilly, John M.

    Through an analysis of several stories, this paper defines the similarities and differences between classic and hard-boiled detective fiction. The characters and plots of three stories are discussed: "The Red House" by A. A. Milne; "I, The Jury" by Mickey Spillane; and "League of Frightened Men" by Rex Stout. The classic detective story is defined…

  19. Big Bubbles in Boiling Liquids: Students' Views

    ERIC Educational Resources Information Center

    Costu, Bayram

    2008-01-01

    The aim of this study was to elicit students' conceptions about big bubbles in boiling liquids (water, ethanol and aqueous CuSO[subscript 4] solution). The study is based on twenty-four students at different ages and grades. The clinical interviews technique was conducted to solicit students' conceptions and the interviews were analyzed to

  20. A new regime of nucleate boiling in microsphere mesostructures: Jumping pool boiling

    NASA Astrophysics Data System (ADS)

    Dmitriev, A. S.; Makarov, P. G.; El Bouz, M. A.

    2015-03-01

    We have studied a new regime of nucleate boiling in distilled water on substrates representing mesostructures of monodisperse and/or polydisperse microspheres made of various materials. It is experimentally established that, under some conditions of nucleate boiling, there appear "jumping pool boiling" regimes in which bubbles do not reach the surface of underheated liquid. In addition, bubbles may capture a certain number of microspheres, lift them up to some height, and then sink together down to the vessel bottom. Alternatively, microspheres may trap a certain number of bubbles, float up toward the evaporating surface, and then (without reaching the surface) sink back to the bottom layer where the nucleate bubbling takes place. Subregimes of this boiling mechanism involving microspheres of various densities and dimensions have also been observed.

  1. Pool boiling heat transfer of deionized and degassed water in packed-perforated copper beads

    NASA Astrophysics Data System (ADS)

    Wen, Mao-Yu; Jang, Kuang-Jang; Ho, Ching-Yen

    2016-01-01

    Nucleate pool boiling with porous media made of perforated copper beads as the enhanced structure is conducted in saturated, deionized and degassed water. Data are taken at an atmospheric pressure (saturation temperature of 100 °C) and at heat fluxes from 4500 to 72,300 W/m2 while increasing the heat flux. The bead-packed structure is heated on the bottom. The layer of loose particles on the heated surface is free to move under the action of bulk liquid convection and vapor nucleation. The effects of the weight (number), size and layers of the free particles are experimentally explored using copper particles for different copper bead diameters which were 2, 3, 4 and 5 mm. The boiling enhancement is closely related to the particle weight, size and layers, and the heat flux applied. The results show that free particles are presented to have a distinct advantage in boiling heat transfer, resulting in an average increase in the heat transfer coefficient of 126 % relative to the flat plate without particles. In order to obtain insight into the fluid boiling phenomena, flow visualization is also made to observe the detailed fluid boiling characteristics of the copper particles present. The visualizations show that bubble nucleation preferentially occurs at the narrow corner cavities formed between the free particles and the heated surface.

  2. Nucleate pool boiling: High gravity to reduced gravity; liquid metals to cryogens

    NASA Technical Reports Server (NTRS)

    Merte, Herman, Jr.

    1988-01-01

    Requirements for the proper functioning of equipment and personnel in reduced gravity associated with space platforms and future space station modules introduce unique problems in temperature control; power generation; energy dissipation; the storage, transfer, control and conditioning of fluids; and liquid-vapor separation. The phase change of boiling is significant in all of these. Although both pool and flow boiling would be involved, research results to date include only pool boiling because buoyancy effects are maximized for this case. The effective application of forced convection boiling heat transfer in the microgravity of space will require a well grounded and cogent understanding of the mechanisms involved. Experimental results are presented for pool boiling from a single geometrical configuration, a flat surface, covering a wide range of body forces from a/g = 20 to 1 to a/g = 0 to -1 for a cryogenic liquid, and from a/g = 20 to 1 for water and a liquid metal. Similarities in behavior are noted for these three fluids at the higher gravity levels, and may reasonably be expected to continue at reduced gravity levels.

  3. Thermal Design of Vapor Cooling of Flight Vehicle Structures Using LH2 Boil-Off

    NASA Technical Reports Server (NTRS)

    Wang, Xiao-Yen; Zoeckler, Joseph

    2015-01-01

    Using hydrogen boil-off vapor to cool the structure of a flight vehicle cryogenic upper stage can reduce heat loads to the stage and increase the usable propellant in the stage or extend the life of the stage. The hydrogen vapor can be used to absorb incoming heat as it increases in temperature before being vented overboard. In theory, the amount of heat leaking into the hydrogen tank from the structure will be reduced if the structure is cooled using the propellant boil-off vapor. However, the amount of boil-off vapor available to be used for cooling and the reduction in heat leak to the propellant tank are dependent to each other. The amount of heat leak reduction to the LH2 tank also depends on the total heat load on the stage and the vapor cooling configurations.

  4. Enhancing flow boiling heat transfer in microchannels for thermal management with monolithically-integrated silicon nanowires.

    PubMed

    Li, D; Wu, G S; Wang, W; Wang, Y D; Liu, Dong; Zhang, D C; Chen, Y F; Peterson, G P; Yang, Ronggui

    2012-07-11

    Thermal management has become a critical issue for high heat flux electronics and energy systems. Integrated two-phase microchannel liquid-cooling technology has been envisioned as a promising solution, but with great challenges in flow instability. In this work, silicon nanowires were synthesized in situ in parallel silicon microchannel arrays for the first time to suppress the flow instability and to augment flow boiling heat transfer. Significant enhancement in flow boiling heat transfer performance was demonstrated for the nanowire-coated microchannel heat sink, such as an early onset of nucleate boiling, a delayed onset of flow oscillation, suppressed oscillating amplitudes of temperature and pressure drop, and an increased heat transfer coefficient. PMID:22694316

  5. Sodium boiling experiments in bundle geometries under fast transient and steady state conditions

    NASA Astrophysics Data System (ADS)

    Peppler, F. W.

    Flow loss experiments were carried out in tubular and 7 pin test-sections and in a sodium cooled 37 pin bundle with sinusoidal axial heat flux profile. Thermohydraulic behavior under fast loss of flow conditions, particularly three-dimensional phenomena such as the development of the temperature distribution, the boiling region, the onset and extension of dryout, and the flow regimes related to different boiling periods were studied. The experimental results provide data for the validation of three-dimensional two-phase hydrodynamic codes. Stationary boiling tests provide information on two-phase pressure drop in bundles, the flow regimes and the conditions prevailing during the approach to critical heat flux conditions.

  6. Boiling sand springs, Dismal River, Nebraska: Agents for formation of vertical cylindrical structures and geomorphic change

    SciTech Connect

    Pederson, D.T. ); Guhman, A.I.

    1992-01-01

    Boiling (motion, not temperature) sand springs fed by ground water moving upward along distinct conduits occur along the Dismal River in the Nebraska Sand Hills. The cylindrical conduits are developed in alluvium and are as large as 10 m in diameter and 44 m deep. Sides of the spring conduits are firm. Boiling sand is overlain in several places by a clear layer of water in the spring. Time-varying wave patterns and boils can be observed along the interface between these layers. Sediment within the conduits is generally well sorted, although some debris is present. Because of their large size, firm sides, and persistence in time, the conduits have the potential for preservation as vertical cylindrical structures comparable to those reported in sedimentary rocks of several ages. The discovery of preserved structures is evidence of paleo-ground-water discharge, and therefore the structures are a useful mapping tool for determining position in landscape evolution.

  7. Impact of boiling conditions on the molecular and sensory profile of a vegetable broth.

    PubMed

    Mougin, Alice; Mauroux, Olivier; Matthey-Doret, Walter; Barcos, Eugenia Maria; Beaud, Fernand; Bousbaine, Ahmed; Viton, Florian; Smarrito-Menozzi, Candice

    2015-02-11

    Low-pressure cooking has recently been identified as an alternative to ambient and high-pressure cooking to provide food with enhanced organoleptic properties. This work investigates the impact of the cooking process at different pressures on the molecular and sensory profile of a vegetable broth. Experimental results showed similar sensory and chemical profiles of vegetable broths when boiling at 0.93 and 1.5 bar, while an enhancement of sulfur volatile compounds correlated with a greater leek content and savory aroma was observed when boiling at low pressure (80 C/0.48 bar). Thus, low-pressure cooking would allow preserving the most labile volatiles likely due to the lower water boiling temperature and the reduced level of oxygen. This study evidenced chemical and sensory impact of pressure during cooking and demonstrated that the flavor profile of culinary preparations can be enhanced by applying low-pressure conditions. PMID:25579390

  8. Flow boiling with enhancement devices for cold plate coolant channel design

    NASA Technical Reports Server (NTRS)

    Boyd, Ronald D.

    1991-01-01

    Future space exploration and commercialization will require more efficient heat rejection systems. For the required heat transfer rates, such systems must use advanced heat transfer techniques. Forced two phase flow boiling heat transfer with enhancements falls in this category. However, moderate to high quality two phase systems tend to require higher pressure losses. This report is divided into two major parts: (1) Multidimensional wall temperature measurement and heat transfer enhancement for top heated horizontal channels with flow boiling; and (2) Improved analytical heat transfer data reduction for a single side heated coolant channel. Part 1 summarizes over forty experiments which involve both single phase convection and flow boiling in a horizontal channel heated externally from the top side. Part 2 contains parametric dimensionless curves with parameters such as the coolant channel radius ratio, the Biot number, and the circumferential coordinate.

  9. Enhanced hydrogenation and acceptor passivation in Si by pressurized water boiling

    NASA Astrophysics Data System (ADS)

    Ohmura, Y.; Otomo, Y.; Tago, Y.; Terakado, N.; Satoh, T.

    1995-07-01

    It has been shown that a pressurized water boiling (PWB) at 2 atmospheric pressures and 120 C in an autoclave vessel accelerates significantly hydrogenation and neutralization of B acceptors in Si. Compared with boiling at atmospheric pressure, PWB reduces more the free-hole IR absorption and increases more the sheet resistivity in B implanted p+ layer on n-type substrate. An IR absorption of B-H stretching vibration (1907 cm-1) has been detected at 16 K for a p+ layer which was PWB processed for only 6 h. Concentration increase of H-related species in water and faster diffusion of H in Si at higher temperature may be the cause. In contrast with other hydrogenation techniques, water boiling hardly passivates donors in Si even for 10 h PWB.

  10. Maximum power point search method for photovoltaic panels which uses a light sensor in the conditions of real shading and temperature

    NASA Astrophysics Data System (ADS)

    Mroczka, Janusz; Ostrowski, Mariusz

    2015-06-01

    Disadvantages of photovoltaic panels are their low efficiency and non-linear current-voltage characteristic. Therefore it is necessary to apply the maximum power tracking systems which are dependent on the sun exposure and temperature. Trackers, that are used in photovoltaic systems, differ from each other in the speed and accuracy of tracking. Typically, in order to determine the maximum power point, trackers use measure of current and voltage. The perturb and observe algorithm or the incremental conductance method are frequent in the literature. The drawback of these solutions is the need to search the entire current-voltage curve, resulting in a significant loss of power in the fast-changing lighting conditions. Modern solutions use an additional measurement of temperature, short-circuit current or open circuit voltage in order to determine the starting point of one of the above methods, what decreases the tracking time. For this paper, a sequence of simulations and tests in real shading and temperature conditions for the investigated method, which uses additional light sensor to increase the speed of the perturb and observe algorithm in fast-changing illumination conditions was performed. Due to the non-linearity of the light sensor and the photovoltaic panel and the influence of temperature on the used sensor and panel characteristics, we cannot directly determine the relationship between them. For this reason, the tested method is divided into two steps. In the first step algorithm uses the correlation curve of the light sensor and current at the maximum power point and determines the current starting point with respect of which the perturb and observe algorithm is run. When the maximum power point is reached, in a second step, the difference between the starting point and the actual maximum power point is calculated and on this basis the coefficients of correlation curve are modified.

  11. High temperature exposure of in-situ thermocouple fixed-point cells: stability with up to three months of continuous use

    NASA Astrophysics Data System (ADS)

    Elliott, C. J.; Greenen, A.; Lowe, D.; Pearce, J. V.; Machin, G.

    2015-04-01

    To categorise thermocouples in batches, manufacturers state an expected operating tolerance for when the thermocouples are as-new. In use, thermocouple behaviour can rapidly change and the tolerance becomes invalid, especially when used at high temperatures (i.e. above 1000?C) as the processes leading to de-calibration, such as oxidation and contamination, can be very fast and lead to erroneous readings. In-situ thermocouple self-validation provides a method to track the drift and correct the thermocouple reading in real-time, but it must be shown to be reliable. Two miniature temperature fixed-point cells designed at NPL for in-situ thermocouple self-validation, the first containing a Pt-C eutectic alloy and the second containing a Ru-C eutectic alloy, have been exposed to temperatures close to their melting point for 2200?h and 1570?h, respectively, and continuously, for up to three months. Recalibration after this long-term high-temperature exposure, where a tantalum-sheathed thermocouple was always in place, is used to show that no significant change of the temperature reference point (the melting temperature) has occurred in either the Pt-C ingot or the Ru-C ingot, over timescales far longer than previously demonstrated and approaching that required by industry for practical use of the device.

  12. Genetic toxicity of high-boiling petroleum substances.

    PubMed

    McKee, Richard H; Schreiner, Ceinwen A; Nicolich, Mark J; Gray, Thomas M

    2013-11-01

    There are several specific types of high-boiling petroleum substances (HBPS) having final boiling points >343C), in which genetic toxicity can be related to the content of polycyclic aromatic compounds (PACs), specifically crude oils, gas oils, heavy fuel oils, lubricant base oils, waxes and aromatic extracts. Evaluation of optimized Salmonella tests covering over 250 samples from 43 types of HBPS revealed that gene mutation can be determined for these substances using a protocol optimized for the detection of mutagenic PAC. The outcomes of modified Salmonella assays can be predicted using HBPS compositional information as input to a newly developed statistical model. The general outcome of the optimized Salmonella assay can be predicted for an untested substance based on its Aromatic Ring Class (ARC) profile. Review of the results from numerous cytogenetic tests showed that although a few positive study results have been reported, most HBPS do not produce chromosomal effects when tested in rodent bone marrow assays or in in vitro chromosomal aberration assays. Results of both bacterial and cytogenetic studies can be used to satisfy genetic toxicity endpoints for the HBPS category substances. PMID:23685115

  13. Boil-off experiments with the EIR-NEPTUN Facility: Analysis and code assessment overview report

    SciTech Connect

    Aksan, S.N.; Stierli, F.; Analytis, G.T.

    1992-03-01

    The NEPTUN data discussed in this report are from core uncovery (boil-off) experiments designed to investigate the mixture level decrease and the heat up of the fuel rod simulators above the mixture level for conditions simulating core boil-off for a nuclear reactor under small break loss-of-coolant accident conditions. The first series of experiments performed in the NEPTUN test facility consisted of ten boil-off (uncovery) and one adiabatic heat-up tests. In these tests three parameters were varied: rod power, system pressure and initial coolant subcooling. The NEPTUN experiments showed that the external surface thermocouples do not cause a significant cooling influence in the rods to which they are attached under boil-off conditions. The reflooding tests performed later on indicated that the external surface thermocouples have some effect during reflooding for NEPTUN electrically heated rod bundle. Peak cladding temperatures are reduced by about 30--40C and quench times occur 20--70 seconds earlier than rods with embedded thermocouples. Additionally, the external surface-thermocouples give readings up to 20 K lower than those obtained with internal surface thermocouples (in the absence of external thermocouples) in the peak cladding temperature zone. Some of the boil-off data obtained from the NEPTUN test facility are used for the assessment of the thermal-hydraulic transient computer codes. These calculations were performed extensively using the frozen version of TRAC-BD1/MOD1 (version 22). A limited number of assessment calculations were done with RELAP5/MOD2 (version 36.02). In this report the main results and conclusions of these calculations are presented with the identification of problem areas in relation to models relevant to boil-off phenomena. On the basis of further analysis and calculations done, changing some of the models such as the bubbly/slug flow interfacial friction correlation which eliminate some of the problems are recommended.

  14. Models and Stability Analysis of Boiling Water Reactors

    SciTech Connect

    John Dorning

    2002-04-15

    We have studied the nuclear-coupled thermal-hydraulic stability of boiling water reactors (BWRs) using a model that includes: space-time modal neutron kinetics based on spatial w-modes; single- and two-phase flow in parallel boiling channels; fuel rod heat conduction dynamics; and a simple model of the recirculation loop. The BR model is represented by a set of time-dependent nonlinear ordinary differential equations, and is studied as a dynamical system using the modern bifurcation theory and nonlinear dynamical systems analysis. We first determine the stability boundary (SB) - or Hopf bifurcation set- in the most relevant parameter plane, the inlet-subcooling-number/external-pressure-drop plane, for a fixed control rod induced external reactivity equal to the 100% rod line value; then we transform the SB to the practical power-flow map used by BWR operating engineers and regulatory agencies. Using this SB, we show that the normal operating point at 100% power is very stable, that stability of points on the 100% rod line decreases as the flow rate is reduced, and that operating points in the low-flow/high-power region are least stable. We also determine the SB that results when the modal kinetics is replaced by simple point reactor kinetics, and we thereby show that the first harmonic mode does not have a significant effect on the SB. However, we later show that it nevertheless has a significant effect on stability because it affects the basin of attraction of stable operating points. Using numerical simulations we show that, in the important low-flow/high-power region, the Hopf bifurcation that occurs as the SB is crossed is subcritical; hence, growing oscillations can result following small finite perturbations of stable steady-states on the 100% rod line at points in the low-flow/high-power region. Numerical simulations are also performed to calculate the decay ratios (DRs) and frequencies of oscillations for various points on the 100% rod line. It is determined that the U.S. NRC requirement of DR is not rigorously satisfied in the low-flow/high-power region; hence, this region should be avoided during normal startup and shutdown operations. The frequency of oscillation is shown to decrease as the flow rate is reduced. Moreover, the simulation frequency of 0.5Hz determined in the low-flow/high-power region is consistent with those observed during actual instability incidents. Additional numerical simulations show that in the low-flow/high-power region, for the same initial conditions, the use of point kinetics leads to damped oscillations, whereas the model that includes the modal neutron kinetics equations results in growing nonlinear oscillations.

  15. Enthalpic switch-points and temperature dependencies of DNA binding and nucleotide incorporation by Pol I DNA polymerases.

    PubMed

    Brown, Hiromi S; Licata, Vince J

    2013-10-01

    This study examines the relationship between the DNA binding thermodynamics and the enzymatic activity of the Klenow and Klentaq Pol I DNA polymerases from Escherichia coli and Thermus aquaticus. Both polymerases bind DNA with nanomolar affinity at temperatures down to at least 5C, but have lower than 1% enzymatic activity at these lower temperatures. For both polymerases it is found that the temperature of onset of significant enzymatic activity corresponds with the temperature where the enthalpy of binding (?Hbinding) crosses zero (TH) and becomes favorable (negative). This TH/activity upshift temperature is 15C for Klenow and 30C for Klentaq. The results indicate that a negative free energy of DNA binding alone is not sufficient to proceed to catalysis, but that the enthalpic versus entropic balance of binding may be a modulator of the temperature dependence of enzymatic function. Analysis of the temperature dependence of the catalytic activity of Klentaq polymerase using expanded Eyring theory yields thermodynamic patterns for ?G(), ?H(), and T?S() that are highly analogous to those commonly observed for direct DNA binding. Eyring analysis also finds a significant ?Cp() of formation of the activated complex, which in turn indicates that the temperature of maximal activity, after which incorporation rate slows with increasing temperature, will correspond with the temperature where the activation enthalpy (?H()) switches from positive to negative. PMID:23851145

  16. Muscle temperature at the point of filleting-Subsequent effect on storage quality of prerigor filleted raw- and cold-smoked Atlantic salmon.

    PubMed

    Lerfall, Jørgen; Rotabakk, Bjørn Tore

    2016-03-01

    The impact of increased muscle temperature at the point of filleting on fillet quality of raw- and cold-smoked Atlantic salmon was investigated. Commercially reared fish (5.65 kg, Kf: 1.23, pH: 7.29, muscle temperature: 6.68 ℃) were killed and immediately tempered in three different containers. Muscle temperatures after filleting (<3 h postmortem) of the three groups were 2.08 ℃ (hereafter named T-2); 9.07 ℃ (hereafter named T-9), and 14.09 ℃ (hereafter named T-14), respectively. The pH after filleting was significantly low for T-14 (6.93) followed by T-9 (7.06) and T-2 (7.22). Raised temperature at point of filleting was found to significantly alter development of rigor mortis, which subsequently affected muscle pH and the reflective properties of the fillet surface during 14 days' ice storage. Of cold-smoked fillets, however, a more distinct effect of raised temperature was observed on visual perception resulting in lighter and more yellowish cold-smoked fillets after 14 days' storage. In addition, raised temperature also affects the development of muscle pH in cold-smoked fillets during refrigerated storage. No effects of raised muscle temperature were found regarding drip loss, water-holding capacity, or fillet firmness either for raw- or cold-smoked fillets throughout the storage period. PMID:25791090

  17. A review of the deformation behavior of tungsten at temperatures less than 0.2 of the melting point /K/

    NASA Technical Reports Server (NTRS)

    Stephens, J. R.

    1974-01-01

    The deformation behavior of tungsten at temperatures below 0.2 times the absolute melting temperature is reviewed with primary emphasis on the temperature dependence of the yield stress and the ductile-brittle transition. It is concluded that a model based on the high Peierls stress of tungsten best accounts for the observed mechanical behavior at low temperatures. Recent research suggests an important role of electron concentration and bonding on the mechanical behavior of tungsten. Future research on tungsten should include studies to define more clearly the correlation between electron concentration and mechanical behavior of alloys of tungsten and other transition metal alloys.

  18. Design inputs document: Boiling behavior during flow instability

    SciTech Connect

    Coutts, D.A.

    1991-01-01

    The coolant flow in a nuclear reactor core under normal operating conditions is kept as a subcooled liquid. This coolant is evenly distributed throughout the multiple flow channels with a uniform pressure profile across each coolant flow channel. If the coolant flow is reduced, the flow through individual channels will also decrease. A decrease in coolant flow will result in higher coolant temperatures if the heat flux is not reduced. When flow is significantly decreased, localized boiling may occur. This localized boiling can restrict coolant flow and the ability to transfer heat out of the reactor system. The maximum operating power for the reactor may be limited by how the coolant system reacts to a flow instability. One of the methods to assure safe operation during a reducing flow instability, is to operate at a power level below that necessary to initiate a flow excursion. Several correlations have been used to predict the conditions which precede a flow excursion. These correlations rely on the steady state behavior of the coolant and are based on steady state testing. This task will evaluate if there are any deviations between the actual transient flow excursion behavior and the flow excursion behavior based on steady state correlations (ONB, OSV, and CHF). Correlations will be developed which will allow a comparison between the time to excursive behavior predicted using steady state techniques and the actual time to excursive behavior.

  19. Design inputs document: Boiling behavior during flow instability

    SciTech Connect

    Coutts, D.A.

    1991-12-31

    The coolant flow in a nuclear reactor core under normal operating conditions is kept as a subcooled liquid. This coolant is evenly distributed throughout the multiple flow channels with a uniform pressure profile across each coolant flow channel. If the coolant flow is reduced, the flow through individual channels will also decrease. A decrease in coolant flow will result in higher coolant temperatures if the heat flux is not reduced. When flow is significantly decreased, localized boiling may occur. This localized boiling can restrict coolant flow and the ability to transfer heat out of the reactor system. The maximum operating power for the reactor may be limited by how the coolant system reacts to a flow instability. One of the methods to assure safe operation during a reducing flow instability, is to operate at a power level below that necessary to initiate a flow excursion. Several correlations have been used to predict the conditions which precede a flow excursion. These correlations rely on the steady state behavior of the coolant and are based on steady state testing. This task will evaluate if there are any deviations between the actual transient flow excursion behavior and the flow excursion behavior based on steady state correlations (ONB, OSV, and CHF). Correlations will be developed which will allow a comparison between the time to excursive behavior predicted using steady state techniques and the actual time to excursive behavior.

  20. Boiling in particle beds in a two dimensional configuration

    NASA Astrophysics Data System (ADS)

    Zeisberger, A.

    The work presented here concentrates on the boiling heat transfer from a porous bed with internal heat sources. This configuration can occur, when in the progress of a hypothetical accident the core melt relocates to the lower plenum of a nuclear reactor pressure vessel and gets partially fragmented. The coolability and the boiling heat transfer are experimentally investigated for two- dimensional particle beds. Experiments are discussed with particles of an uniform diameter of 2mm as well as mixtures of 4mm and 1mm particles. The bed was placed in a glass container with an inclined bottom to represent a section of the lower plenum of a reactor pressure vessel. The refrigerant R134a was used for tests with a pressure up to 1.8MPa. The particle bed was equipped with thermocouples and capacitive local void fraction probes to map the temperatures and the distribution of liquid and steam. In the following the basic effects and the parameters influencing the coolability of such a configuration will be discussed.

  1. Nucleate boiling pressure drop in an annulus: Book 5

    SciTech Connect

    Not Available

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. Nineteen test series and a total of 178 tests were performed. Testing addressed the effects of: Heat flux; pressure; helium gas; power tilt; ribs; asymmetric heat flux. This document consists solely of the plato file index from 11/87 to 11/90.

  2. Temperature dependent dielectric function and the E{sub 0} critical points of hexagonal GaN from 30 to 690 K

    SciTech Connect

    Kim, Tae Jung Hwang, Soon Yong; Byun, Jun Seok; Barange, Nilesh S.; Park, Han Gyeol; Dong Kim, Young

    2014-02-15

    The complex dielectric function ? and the E{sub 0} excitonic and band-edge critical-point structures of hexagonal GaN are reported for temperatures from 30 to 690 K and energies from 0.74 to 6.42 eV, obtained by rotating-compensator spectroscopic ellipsometry on a 1.9 ?m thick GaN film deposited on a c-plane (0001) sapphire substrate by molecular beam epitaxy. Direct inversion and B-splines in a multilayer-structure calculation were used to extract the optical properties of the film from the measured pseudodielectric function ???. At low temperature sharp E{sub 0} excitonic and critical-point interband transitions are separately observed. Their temperature dependences were determined by fitting the data to the empirical Varshni relation and the phenomenological expression that contains the Bose-Einstein statistical factor.

  3. Tipping Points

    NASA Astrophysics Data System (ADS)

    Hansen, J.

    2007-12-01

    A climate tipping point, at least as I have used the phrase, refers to a situation in which a changing climate forcing has reached a point such that little additional forcing (or global temperature change) is needed to cause large, relatively rapid, climate change. Present examples include potential loss of all Arctic sea ice and instability of the West Antarctic and Greenland ice sheets. Tipping points are characterized by ready feedbacks that amplify the effect of forcings. The notion that these may be runaway feedbacks is a misconception. However, present "unrealized" global warming, due to the climate system's thermal inertia, exacerbates the difficulty of avoiding global warming tipping points. I argue that prompt efforts to slow CO2 emissions and absolutely reduce non-CO2 forcings are both essential if we are to avoid tipping points that would be disastrous for humanity and creation, the planet as civilization knows it.

  4. Prospective Chemistry Teachers' Misconceptions about Colligative Properties: Boiling Point Elevation and Freezing Point Depression

    ERIC Educational Resources Information Center

    Pinarbasi, Tacettin; Sozbilir, Mustafa; Canpolat, Nurtac

    2009-01-01

    This study aimed at identifying prospective chemistry teachers' misconceptions of colligative properties. In order to fulfill this aim, a diagnostic test composed of four open-ended questions was used. The test was administered to seventy-eight prospective chemistry teachers just before qualifying to teaching in secondary schools. Nine different…

  5. Prospective Chemistry Teachers' Misconceptions about Colligative Properties: Boiling Point Elevation and Freezing Point Depression

    ERIC Educational Resources Information Center

    Pinarbasi, Tacettin; Sozbilir, Mustafa; Canpolat, Nurtac

    2009-01-01

    This study aimed at identifying prospective chemistry teachers' misconceptions of colligative properties. In order to fulfill this aim, a diagnostic test composed of four open-ended questions was used. The test was administered to seventy-eight prospective chemistry teachers just before qualifying to teaching in secondary schools. Nine different

  6. 6. View of first panel point from south end showing ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. View of first panel point from south end showing chord, diagonals and vertical member connection at pin - Bridge No. 2.4, Spanning Boiling Fork Creek at Railroad Milepost JC-2.4, Decherd, Franklin County, TN

  7. Flow boiling in vertical down-flow

    SciTech Connect

    Dougherty, T.; Fighetti, C.; Reddy, G.; Yang, B.; Jafri, T. ); McAssey, E. ); Qureshi, Z. )

    1989-01-01

    An experimental program has been conducted to investigate the onset of Ledinegg instability in vertical down-flow. For three size uniformly heated test sections with L/D ratios from 100 to 150, the pressure drop under subcooled boiling conditions has been obtained for a wide range of operating parameters. The results are presented in non-dimensional forms which correlate the important variables and provide techniques for predicting the onset of flow instability. 3 refs.

  8. Flow boiling in vertical down-flow

    SciTech Connect

    Dougherty, T.; Fighetti, C.; Reddy, G.; Yang, B.; Jafri, T.; McAssey, E.; Qureshi, Z.

    1989-12-31

    An experimental program has been conducted to investigate the onset of Ledinegg instability in vertical down-flow. For three size uniformly heated test sections with L/D ratios from 100 to 150, the pressure drop under subcooled boiling conditions has been obtained for a wide range of operating parameters. The results are presented in non-dimensional forms which correlate the important variables and provide techniques for predicting the onset of flow instability. 3 refs.

  9. Bench-scale screening tests for a boiling sodium-potassium alloy solar receiver

    SciTech Connect

    Moreno, J.B.; Moss, T.A.

    1993-06-01

    Bench-scale tests were carried out in support of the design of a second-generation 75-kW{sub t} reflux pool-boiler solar receiver. The receiver will be made from Haynes Alloy 230 and will contain the sodium-potassium alloy NaK-78. The bench-scale tests used quartz-lamp-heated boilers to screen candidate boiling-stabilization materials and methods at temperatures up to 750{degree}C. Candidates that provided stable boiling were tested for hot-restart behavior. Poor stability was obtained with single 1/4-inch diameter patches of powdered metal hot-press-sintered onto the wetted side of the heat-input area. Laser-drilled and electric-discharge-machined cavities in the heated surface also performed poorly. Small additions of xenon, and heated-surface tilt out of the vertical dramatically improved poor boiling stability; additions of helium or oxygen did not. The most stable boiling was obtained when the entire heat-input area was covered by a powdered-metal coating. The effect of heated-area size was assessed for one coating: at low incident fluxes, when even this coating performed poorly, increasing the heated-area size markedly improved boiling stability. Good hot-restart behavior was not observed with any candidate, although results were significantly better with added xenon in a boiler shortened from 3 to 2 feet. In addition to the screening tests, flash-radiography imaging of metal-vapor bubbles during boiling was attempted. Contrary to the Cole-Rohsenow correlation, these bubble-size estimates did not vary with pressure; instead they were constant, consistent with the only other alkali metal measurements, but about 1/2 their size.

  10. Bench-scale screening tests for a boiling sodium-potassium alloy solar receiver

    NASA Astrophysics Data System (ADS)

    Moreno, J. B.; Moss, T. A.

    1993-06-01

    Bench-scale tests were carried out in support of the design of a second-generation 75-kW(sub t) reflux pool-boiler solar receiver. The receiver will be made from Haynes Alloy 230 and will contain the sodium-potassium alloy NaK-78. The bench-scale tests used quartz lamp heated boilers to screen candidate boiling stabilization materials and methods at temperatures up to 750 degree C. Candidates that provided stable boiling were tested for hot-restart behavior. Poor stability was obtained with single 1/4-inch diameter patches of powdered metal hot press sintered onto the wetted side of the heat-input area. Laser-drilled and electric discharge machined cavities in the heated surface also performed poorly. Small additions of xenon, and heated-surface tilt out of the vertical, dramatically improved poor boiling stability; additions of helium or oxygen did not. The most stable boiling was obtained when the entire heat-input area was covered by a powdered-metal coating. The effect of heated-area size was assessed for one coating: at low incident fluxes, when even this coating performed poorly, increasing the heated-area size markedly improved boiling stability. Good hot-restart behavior was not observed with any candidate, although results were significantly better with added xenon in a boiler shortened from 3 to 2 feet. In addition to the screening tests, flash-radiography imaging of metal-vapor bubbles during boiling was attempted. Contrary to the Cole-Rohsenow correlation, these bubble-size estimates did not vary with pressure; instead they were constant, consistent with the only other alkali metal measurements, but about 1/2 their size.

  11. (Investigation of subcooled hydrothermal boiling in ground water flow channels as a source of harmonic tremors)

    SciTech Connect

    Not Available

    1989-01-01

    As a first step toward assessing the ability of hydrothermal boiling to explain geothermal ground noise and volcanic tremor observations, we are investigating the acoustic power spectrum of boiling (the source'' spectrum in the above model). We simulate boiling in the lab by injecting high pressure steam from a boiler into a pressure vessel filled with water. The water pressure fluctuations that result from the repeated formation and collapse of steam bubbles at the steam inlet vents are recorded by a hydrophone whose output is digitized at 2 {times} 10{sup 4} samples/second by a computer. The range of pressure and temperature conditions attainable within the pressure vessel is limited to <3.5 bars, <139{degree}C, due to the finite strength of observation windows affixed to the pressure vessel. Therefore, dimensional analysis will be used to correlate the experimental results with the pertinent experimental variables. Besides the overall shape of the boiling power spectrum, we are investigating the absolute spectral levels in frequency bands typical of geothermal ground noise and volcanic tremor (0.5 Hz-10 Hz), and the ratio of acoustic power liberated to total available power. The values of these parameters are critical to hydrothermal boiling's ability to generate ground motion amplitudes in accordance with observation. If it can be shown that the range of observed ground noise/tremor amplitudes can be accounted for by hydrothermal boiling at reasonable heat transfer rates, this knowledge would be invaluable to designers of seismic monitoring experiments who are interested in geothermal resource exploration/evaluation and volcanic eruption prediction.

  12. Steady State Vapor Bubble in Pool Boiling

    NASA Astrophysics Data System (ADS)

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C.; Maroo, Shalabh C.

    2016-02-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics.

  13. Steady State Vapor Bubble in Pool Boiling.

    PubMed

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C; Maroo, Shalabh C

    2016-01-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics. PMID:26837464

  14. Steady State Vapor Bubble in Pool Boiling

    PubMed Central

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C.; Maroo, Shalabh C.

    2016-01-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics. PMID:26837464

  15. Potential risk of bisphenol A migration from polycarbonate containers after heating, boiling, and microwaving.

    PubMed

    Lim, Duck Soo; Kwack, Seung Jun; Kim, Kyu-Bong; Kim, Hyung Sik; Lee, Byung Mu

    2009-01-01

    The migration levels of bisphenol A (BPA) were analyzed in food samples by high-performance liquid chromatography (HPLC) from polycarbonate (PC) bottles subjected to simulated use by heating with microwave, heating in a boiling water bath, or filling them with boiling hot water (100 degrees C). Migration testing performed in PC bottles filled with steamed rice or hot cooked pork, standing at room temperature, or heated in a boiling water bath (100 degrees C) showed that BPA was not detected at the limit of detection (LOD) of 1 microg/L (ppb). In contrast, heating by microwaving to 100 degrees C for 9 min increased BPA migration levels from 6 to 18 ppb and from 5 to 15 ppb for steamed rice or for cooked pork, respectively. In addition, 3 different PC bottles were tested by filling them with boiling hot water (100 degrees C) and leaving them to stand at room temperature for up to 3 h. The mean BPA levels from the bottles increased in a time-dependent manner, with the range of not detected (ND) to 2.5 ppb after 60 min. However, none of the PC bottles released BPA at levels that exceed the recently established specific migration limits (SML) of 600 ppb established by European Union and Korea Food and Drug Administration (KFDA). Data suggest that the use of PC plastic bottles in our daily life is considered safe in Korea. PMID:20077198

  16. Rotational CARS application to simultaneous and multiple-point temperature and concentration determination in a turbulent flow

    NASA Technical Reports Server (NTRS)

    Snow, J. B.; Murphy, D. V.; Chang, R. K.

    1983-01-01

    Coherent anti-Stokes Raman scattering (CARS) from the pure rotational Raman lines of N2 is employed to measure the instantaneous (approximately 10 ns) rotational temperature of N2 gas at room temperature and below with good spatial resolution (0.2 x 0.2 x 3.0 cu mm). A broad bandwidth dye laser is used to obtain the entire rotational spectrum from a single laser pulse; the CARS signal is then dispersed by a spectrograph and recorded on an optical multichannel analyzer. A best fit temperature is found in several seconds with the aid of a computer for each experimental spectrum by a least squares comparison with calculated spectra. The model used to calculate the theoretical spectra incorporates the temperature and pressure dependence of the pressure-broadened rotational Raman lines, includes the nonresonant background susceptibility, and assumes that the pump laser has a finite linewidth. Temperatures are fit to experimental spectra recorded over the temperature range of 135 to 296 K, and over the pressure range of .13 to 15.3 atm.

  17. Pressure drop, heat transfer, critical heat flux, and flow stability of two-phase flow boiling of water and ethylene glycol/water mixtures - final report for project "Efficent cooling in engines with nucleate boiling."

    SciTech Connect

    Yu, W.; France, D. M.; Routbort, J. L.

    2011-01-19

    Because of its order-of-magnitude higher heat transfer rates, there is interest in using controllable two-phase nucleate boiling instead of conventional single-phase forced convection in vehicular cooling systems to remove ever increasing heat loads and to eliminate potential hot spots in engines. However, the fundamental understanding of flow boiling mechanisms of a 50/50 ethylene glycol/water mixture under engineering application conditions is still limited. In addition, it is impractical to precisely maintain the volume concentration ratio of the ethylene glycol/water mixture coolant at 50/50. Therefore, any investigation into engine coolant characteristics should include a range of volume concentration ratios around the nominal 50/50 mark. In this study, the forced convective boiling heat transfer of distilled water and ethylene glycol/water mixtures with volume concentration ratios of 40/60, 50/50, and 60/40 in a 2.98-mm-inner-diameter circular tube has been investigated in both the horizontal flow and the vertical flow. The two-phase pressure drop, the forced convective boiling heat transfer coefficient, and the critical heat flux of the test fluids were determined experimentally over a range of the mass flux, the vapor mass quality, and the inlet subcooling through a new boiling data reduction procedure that allowed the analytical calculation of the fluid boiling temperatures along the experimental test section by applying the ideal mixture assumption and the equilibrium assumption along with Raoult's law. Based on the experimental data, predictive methods for the two-phase pressure drop, the forced convective boiling heat transfer coefficient, and the critical heat flux under engine application conditions were developed. The results summarized in this final project report provide the necessary information for designing and implementing nucleate-boiling vehicular cooling systems.

  18. Conjugate thermal and hydrodynamic analyses of saturated film boiling from a horizontal surface

    SciTech Connect

    Banerjee, D.; Son, G.; Dhir, V.K.

    1996-12-31

    Film boiling is characterized by the existence of a continuous vapor layer between a heated solid surface and a liquid layer. The evolution of the vapor-liquid interface during film boiling on a horizontal surface is determined by Rayleigh-Taylor instability. To predict the heat transfer rates in film boiling, many studies have been reported in literature. Early attempts to model this phenomenon had used semi-empirical correlations. Recent work on simulation of the evolution of vapor-liquid interface without assuming any empirical vapor-liquid interface shape and by assuming the solid surface temperature to be constant has shown that the convective heat transfer coefficients, associated with the interface, vary both spatially and temporally. Consequently, the assumption of constant solid surface temperature in film boiling is not strictly valid. In this work, saturated film boiling on a horizontal surface is simulated numerically. Finite difference method is used to simultaneously solve the equations governing conservation of mass, momentum and energy in the vapor and liquid layers. The equations for the two fluid phases are coupled through matching of normal and tangential stresses and continuity of mass and energy at the liquid vapor interface. Second order projection method is used along with numerical grid generation to construct a grid system which is aligned with the vapor-liquid interface. The heat conduction equation is solved separately in the solid, to obtain the wall temperature. The results show that for most surfaces little coupling takes place between thermal response of the solid substrate and hydrodynamics of evolution of the interface. However, for thin plate heaters of relatively low thermal conductivity materials, the thermal response of the solid can significantly affect the hydrodynamics of the interface and in turn the local heat transfer.

  19. A Drosophila laboratory evolution experiment points to low evolutionary potential under increased temperatures likely to be experienced in the future.

    PubMed

    Schou, M F; Kristensen, T N; Kellermann, V; Schlötterer, C; Loeschcke, V

    2014-09-01

    The ability to respond evolutionarily to increasing temperatures is important for survival of ectotherms in a changing climate. Recent studies suggest that upper thermal limits may be evolutionary constrained. We address this hypothesis in a laboratory evolution experiment, encompassing ecologically relevant thermal regimes. To examine the potential for species to respond to climate change, we exposed replicate populations of Drosophila melanogaster to increasing temperatures (0.3 °C every generation) for 20 generations, whereas corresponding replicate control populations were held at benign thermal conditions throughout the experiment. We hypothesized that replicate populations exposed to increasing temperatures would show increased resistance to warm and dry environments compared with replicate control populations. Contrasting replicate populations held at the two thermal regimes showed (i) an increase in desiccation resistance and a decline in heat knock-down resistance in replicate populations exposed to increasing temperatures, (ii) similar egg-to-adult viability and fecundity in replicate populations from the two thermal regimes, when assessed at high stressful temperatures and (iii) no difference in nucleotide diversity between thermal regimes. The limited scope for adaptive evolutionary responses shown in this study highlights the challenges faced by ectotherms under climate change. PMID:24925446

  20. Bubble Dynamics, Two-Phase Flow, and Boiling Heat Transfer in Microgravity

    NASA Technical Reports Server (NTRS)

    Chung, Jacob N.

    1998-01-01

    This report contains two independent sections. Part one is titled "Terrestrial and Microgravity Pool Boiling Heat Transfer and Critical heat flux phenomenon in an acoustic standing wave." Terrestrial and microgravity pool boiling heat transfer experiments were performed in the presence of a standing acoustic wave from a platinum wire resistance heater using degassed FC-72 Fluorinert liquid. The sound wave was created by driving a half wavelength resonator at a frequency of 10.15 kHz. Microgravity conditions were created using the 2.1 second drop tower on the campus of Washington State University. Burnout of the heater wire, often encountered with heat flux controlled systems, was avoided by using a constant temperature controller to regulate the heater wire temperature. The amplitude of the acoustic standing wave was increased from 28 kPa to over 70 kPa and these pressure measurements were made using a hydrophone fabricated with a small piezoelectric ceramic. Cavitation incurred during experiments at higher acoustic amplitudes contributed to the vapor bubble dynamics and heat transfer. The heater wire was positioned at three different locations within the acoustic field: the acoustic node, antinode, and halfway between these locations. Complete boiling curves are presented to show how the applied acoustic field enhanced boiling heat transfer and increased critical heat flux in microgravity and terrestrial environments. Video images provide information on the interaction between the vapor bubbles and the acoustic field. Part two is titled, "Design and qualification of a microscale heater array for use in boiling heat transfer." This part is summarized herein. Boiling heat transfer is an efficient means of heat transfer because a large amount of heat can be removed from a surface using a relatively small temperature difference between the surface and the bulk liquid. However, the mechanisms that govern boiling heat transfer are not well understood. Measurements of wall temperature and heat flux near the wall would add to the database of knowledge which is necessary to understand the mechanisms of nucleate boiling. A heater array has been developed which contains 96 heater elements within a 2.5 mm square area. The temperature of each heater element is held constant by an electronic control system similar to a hot-wire anemometer. The voltage that is being applied to each heater element can be measured and digitized using a high-speed Analog to Digital (A/D) converter, and this digital information can be compiled into a series of heat-flux maps. Information for up to 10,000 heat flux maps can be obtained each second. The heater control system, the A/D system and the heater array construction are described in detail. Results are presented which show that this is an effective method of measuring the local heat flux during nucleate and transition boiling. Heat flux maps are obtained for pool boiling in FC-72 on a horizontal surface. Local heat flux variations are shown to be three to six times larger than variations in the spatially averaged heat flux.