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Sample records for boiling point temperature

  1. When water does not boil at the boiling point.

    PubMed

    Chang, Hasok

    2007-03-01

    Every schoolchild learns that, under standard pressure, pure water always boils at 100 degrees C. Except that it does not. By the late 18th century, pioneering scientists had already discovered great variations in the boiling temperature of water under fixed pressure. So, why have most of us been taught that the boiling point of water is constant? And, if it is not constant, how can it be used as a 'fixed point' for the calibration of thermometers? History of science has the answers. PMID:17336380

  2. The boiling point of stratospheric aerosols.

    NASA Technical Reports Server (NTRS)

    Rosen, J. M.

    1971-01-01

    A photoelectric particle counter was used for the measurement of aerosol boiling points. The operational principle involves raising the temperature of the aerosol by vigorously heating a portion of the intake tube. At or above the boiling point, the particles disintegrate rather quickly, and a noticeable effect on the size distribution and concentration is observed. Stratospheric aerosols appear to have the same volatility as a solution of 75% sulfuric acid. Chemical analysis of the aerosols indicates that there are other substances present, but that the sulfate radical is apparently the major constituent.

  3. CONTINUOUS ANALYZER UTILIZING BOILING POINT DETERMINATION

    DOEpatents

    Pappas, W.S.

    1963-03-19

    A device is designed for continuously determining the boiling point of a mixture of liquids. The device comprises a distillation chamber for boiling a liquid; outlet conduit means for maintaining the liquid contents of said chamber at a constant level; a reflux condenser mounted above said distillation chamber; means for continuously introducing an incoming liquid sample into said reflux condenser and into intimate contact with vapors refluxing within said condenser; and means for measuring the temperature of the liquid flowing through said distillation chamber. (AEC)

  4. An Analytical Approach for Relating Boiling Points of Monofunctional Organic Compounds to Intermolecular Forces

    ERIC Educational Resources Information Center

    Struyf, Jef

    2011-01-01

    The boiling point of a monofunctional organic compound is expressed as the sum of two parts: a contribution to the boiling point due to the R group and a contribution due to the functional group. The boiling point in absolute temperature of the corresponding RH hydrocarbon is chosen for the contribution to the boiling point of the R group and is a…

  5. An Analytical Approach for Relating Boiling Points of Monofunctional Organic Compounds to Intermolecular Forces

    ERIC Educational Resources Information Center

    Struyf, Jef

    2011-01-01

    The boiling point of a monofunctional organic compound is expressed as the sum of two parts: a contribution to the boiling point due to the R group and a contribution due to the functional group. The boiling point in absolute temperature of the corresponding RH hydrocarbon is chosen for the contribution to the boiling point of the R group and is a

  6. Water above its boiling point: Study of the temperature and density dependence of the partial pair correlation functions. I. Neutron diffraction experiment

    NASA Astrophysics Data System (ADS)

    Postorino, P.; Ricci, M. A.; Soper, A. K.

    1994-09-01

    Neutron diffraction data on water, employing the technique of hydrogen/deuterium isotope substitution, are reported at three thermodynamic states above the boiling point. The structural information is analyzed in terms of the partial radial distribution functions, OO, OH, and HH, which are extracted from the neutron data. It is found that temperature affects mainly the medium and longer range order in the liquid, while density plays a significant role in controlling the degree of hydrogen bonding. To understand the structure of water obtained from these data it appears that many-body cooperative interactions have to be correctly accounted for.

  7. Size-exclusion chromatography for the determination of the boiling point distribution of high-boiling petroleum fractions.

    PubMed

    Boczkaj, Grzegorz; Przyjazny, Andrzej; Kamiński, Marian

    2015-03-01

    The paper describes a new procedure for the determination of boiling point distribution of high-boiling petroleum fractions using size-exclusion chromatography with refractive index detection. Thus far, the determination of boiling range distribution by chromatography has been accomplished using simulated distillation with gas chromatography with flame ionization detection. This study revealed that in spite of substantial differences in the separation mechanism and the detection mode, the size-exclusion chromatography technique yields similar results for the determination of boiling point distribution compared with simulated distillation and novel empty column gas chromatography. The developed procedure using size-exclusion chromatography has a substantial applicability, especially for the determination of exact final boiling point values for high-boiling mixtures, for which a standard high-temperature simulated distillation would have to be used. In this case, the precision of final boiling point determination is low due to the high final temperatures of the gas chromatograph oven and an insufficient thermal stability of both the gas chromatography stationary phase and the sample. Additionally, the use of high-performance liquid chromatography detectors more sensitive than refractive index detection allows a lower detection limit for high-molar-mass aromatic compounds, and thus increases the sensitivity of final boiling point determination. PMID:25545251

  8. Method for estimating boiling temperatures of crude oils

    SciTech Connect

    Jones, R.K.

    1996-08-01

    Evaporation is often the dominant mechanism for mass loss during the first few days following an oil spill. The initial boiling point of the oil and the rate at which the boiling point changes as the oil evaporates are needed to initialize some computer models used in spill response. The lack of available boiling point data often limits the usefulness of these models in actual emergency situations. A new computational method was developed to estimate the temperature at which a crude oil boils as a function of the fraction evaporated using only standard distillation data, which are commonly available. This method employs established thermodynamic rules and approximations, and was designed to be used with automated spill-response models. Comparisons with measurements show a strong correlation between results obtained with this method and measured values.

  9. Vapor pressure and boiling point elevation of slash pine black liquors: Predictive models with statistical approach

    SciTech Connect

    Zaman, A.A.; McNally, T.W.; Fricke, A.L.

    1998-01-01

    Vapor-liquid equilibria and boiling point elevation of slash pine kraft black liquors over a wide range of solid concentrations (up to 85% solids) has been studied. The liquors are from a statistically designed pulping experiment for pulping slash pine in a pilot scale digester with four cooking variables of effective alkali, sulfidity, cooking time, and cooking temperature. It was found that boiling point elevation of black liquors is pressure dependent, and this dependency is more significant at higher solids concentrations. The boiling point elevation data at different solids contents (at a fixed pressure) were correlated to the dissolved solids (S/(1 {minus} S)) in black liquor. Due to the solubility limit of some of the salts in black liquor, a change in the slope of the boiling point elevation as a function of the dissolved solids was observed at a concentration of around 65% solids. An empirical method was developed to describe the boiling point elevation of each liquor as a function of pressure and solids mass fraction. The boiling point elevation of slash pine black liquors was correlated quantitatively to the pulping variables, using different statistical procedures. These predictive models can be applied to determine the boiling point rise (and boiling point) of slash pine black liquors at processing conditions from the knowledge of pulping variables. The results are presented, and their utility is discussed.

  10. Wall temperature patterns in nucleate boiling

    NASA Astrophysics Data System (ADS)

    Kenning, D. B. R.

    Temperature patterns on the back of a thin stainless steel heated plate during pool nucleate boiling of water are measured with thermocromic liquid crystal. It is shown that spatial variations which are large fractions of the mean wall superheat are to be expected in many experimental and industrial applications of boiling. They can cause errors on the measurement of the mean wall superheat by some conventional methods. Established mechanistic models which assume uniformity of wall superheat cannot represent correctly the processes controlling the density and intermittent activity of the bubble nucleation sites on walls of finite thermal conductivity. The essential features of a realistic model are described.

  11. Estimating the physicochemical properties of polyhalogenated aromatic and aliphatic compounds using UPPER: part 1. Boiling point and melting point.

    PubMed

    Admire, Brittany; Lian, Bo; Yalkowsky, Samuel H

    2015-01-01

    The UPPER (Unified Physicochemical Property Estimation Relationships) model uses enthalpic and entropic parameters to estimate 20 biologically relevant properties of organic compounds. The model has been validated by Lian and Yalkowsky on a data set of 700 hydrocarbons. The aim of this work is to expand the UPPER model to estimate the boiling and melting points of polyhalogenated compounds. In this work, 19 new group descriptors are defined and used to predict the transition temperatures of an additional 1288 compounds. The boiling points of 808 and the melting points of 742 polyhalogenated compounds are predicted with average absolute errors of 13.56 K and 25.85 K, respectively. PMID:25022475

  12. Optimal boiling temperature for ORC installation

    NASA Astrophysics Data System (ADS)

    Mikielewicz, Jarosław; Mikielewicz, Dariusz

    2012-09-01

    In the paper a research on cost-effective optimum design boiling temperature for Organic Rankine Cycle utilizing low-temperature heat sources is presented. The ratio of the heat exchanger area of the boiler to the power output is used as the objective function. Analytical relations for heat transfer area as well power of the cycle are formulated. Evaporation temperature and inlet temperature of the heat source medium as well its mass flow rate are varied in the optimization method. The optimization is carried out for three working fluids, i.e. R 134a, water and ethanol. The objective function (economics profitability, thermodynamic efficiency) leads to different optimal working conditions in terms of evaporating temperature. Maximum power generation in the near-critical conditions of subcritical ORC is the highest. The choice of the working fluid can greatly affect the objective function which is a measure of power plant cost. Ethanol exhibits a minimum objective function but not necessarily the maximum cycle efficiency.

  13. Boils

    MedlinePlus

    ... the boil is very bad or comes back. Antibacterial soaps and creams cannot help much once a ... following may help prevent the spread of infection: Antibacterial soaps Antiseptic (germ-killing) washes Keeping clean (such ...

  14. The Gibbs Energy Basis and Construction of Boiling Point Diagrams in Binary Systems

    ERIC Educational Resources Information Center

    Smith, Norman O.

    2004-01-01

    An illustration of how excess Gibbs energies of the components in binary systems can be used to construct boiling point diagrams is given. The underlying causes of the various types of behavior of the systems in terms of intermolecular forces and the method of calculating the coexisting liquid and vapor compositions in boiling point diagrams with…

  15. The Gibbs Energy Basis and Construction of Boiling Point Diagrams in Binary Systems

    ERIC Educational Resources Information Center

    Smith, Norman O.

    2004-01-01

    An illustration of how excess Gibbs energies of the components in binary systems can be used to construct boiling point diagrams is given. The underlying causes of the various types of behavior of the systems in terms of intermolecular forces and the method of calculating the coexisting liquid and vapor compositions in boiling point diagrams with

  16. Teaching Structure-Property Relationships: Investigating Molecular Structure and Boiling Point

    ERIC Educational Resources Information Center

    Murphy, Peter M.

    2007-01-01

    A concise, well-organized table of the boiling points of 392 organic compounds has facilitated inquiry-based instruction in multiple scientific principles. Many individual or group learning activities can be derived from the tabulated data of molecular structure and boiling point based on the instructor's education objectives and the students'

  17. Teaching Structure-Property Relationships: Investigating Molecular Structure and Boiling Point

    ERIC Educational Resources Information Center

    Murphy, Peter M.

    2007-01-01

    A concise, well-organized table of the boiling points of 392 organic compounds has facilitated inquiry-based instruction in multiple scientific principles. Many individual or group learning activities can be derived from the tabulated data of molecular structure and boiling point based on the instructor's education objectives and the students'…

  18. The Elevation of Boiling Points in H_2O and D_2O Electrolytes

    NASA Astrophysics Data System (ADS)

    Miles, M. H.; Arman, H. D.; Carrick, J. D.; Gren, C. K.; Haggerty, K. A.; Kim, H. Y.; Ky, A. G.; Markham, J. E.; Meeks, C. F.; Noga, D. E.

    2002-03-01

    The excess enthalpy effect in cold fusion experiments for Pd/D_2O systems is subject to positive feedback, i.e., increasing the cell temperature increases the excess enthalpy . Therefore, the largest excess enthalpy effects are often observed near or at the boiling point corresponding to that of the electrolyte solution in the cell(M.H. Miles, M. Fleischmann and M.A. Imam, "Calorimetric Analysis of a Heavy Water Electrolysis Experiment Using a Pd-B Alloy Cathode", Naval Research Lab Mem. Rep.,#6320-01-8526, pp. 27-30 (2001).). However, the actual boiling point increases as the D_2O content of the cell decreases. The purpose of this project will be to compare experimental values of the change in temperature ΔT obtained using H_2O and D_2O solutions with theoretical values of ΔT calculated by assuming ideal solutions. The emphasis will be on higher concentrations as well as on saturated solutions where ΔT values may be quite large. Preliminary results for LiOH in H_2O show reasonable agreement with ideal solution ΔT values up to LiOH concentrations of 1.0 molal (m).

  19. Comparative biology and chemistry of boiling point fractions from different coal liquefaction processes

    SciTech Connect

    Wright, C.W.; Chess, E.K.; Stewart, D.L.; Mahlum, D.D.; Later, D.W.; Lucke, R.B.; Pelroy, R.A.; Wilson, B.W.

    1985-11-01

    Data on the chemical composition and toxicologic activity of narrow boiling point (bp) range distillate cuts from the non-catalytic solvent refined coal-I and -II processes, as well as from the catalytic H-Coal, EDS, and integrated two-stage liquefaction processes, were compiled and compared. Results revealed that processes using catalysts contained higher concentrations of alkylated and hydrogenated polycyclic aromatic hydrocarbons (PAH). In addition, lower concentrations of nitrogen-containing polycyclic aromatic compounds (NPAC), including amino-substituted PAH, were present in those materials from processes which used some form of catalytic hydrogenation. Regardless of process, the hydrogen content decreased and the nitrogen, oxygen, and sulfur heteroatomic content of the coal liquefaction materials increased as a function of increasing distillation temperature. In addition, aliphatic hydrocarbon content decreased while the NPAC and hydroxy-substituted PAH content increased as a function of increasing bp temperature for all the coal liquefaction materials. 18 refs., 8 figs., 10 tabs.

  20. Droplet impingement dynamics: effect of surface temperature during boiling and non-boiling conditions

    NASA Astrophysics Data System (ADS)

    Shen, Jian; Liburdy, James A.; Pence, Deborah V.; Narayanan, Vinod

    2009-11-01

    This study investigates the hydrodynamic characteristics of droplet impingement on heated surfaces and compares the effect of surface temperature when using water and a nanofluid on a polished and nanostructured surface. Results are obtained for an impact Reynolds number and Weber number of approximately 1700 and 25, respectively. Three discs are used: polished silicon, nanostructured porous silicon and gold-coated polished silicon. Seven surface temperatures, including single-phase (non-boiling) and two-phase (boiling) conditions, are included. Droplet impact velocity, transient spreading diameter and dynamic contact angle are measured. Results of water and a water-based single-wall carbon-nanotube nanofluid impinging on a polished silicon surface are compared to determine the effects of nanoparticles on impinging dynamics. The nanofluid results in larger spreading velocities, larger spreading diameters and an increase in early-stage dynamic contact angle. Results of water impinging on both polished silicon and nanostructured silicon show that the nanostructured surface enhances the heat transfer for evaporative cooling at lower surface temperatures, which is indicated by a shorter evaporation time. Using a nanofluid or a nanostructured surface can reduce the total evaporation time up to 20% and 37%, respectively. Experimental data are compared with models that predict dynamic contact angle and non-dimensional maximum spreading diameter. Results show that the molecular-kinetic theory's dynamic contact angle model agrees well with current experimental data for later times, but over-predicts at early times. Predictions of maximum spreading diameter based on surface energy analyses indicate that these models over-predict unless empirical coefficients are adjusted to fit the test conditions. This is a consequence of underestimates of the dissipative energy for the conditions studied.

  1. Thermoplastic fusion bonding using a pressure-assisted boiling point control system.

    PubMed

    Park, Taehyun; Song, In-Hyouk; Park, Daniel S; You, Byoung Hee; Murphy, Michael C

    2012-08-21

    A novel thermoplastic fusion bonding method using a pressure-assisted boiling point (PABP) control system was developed to apply precise temperatures and pressures during bonding. Hot embossed polymethyl methacrylate (PMMA) components containing microchannels were sealed using the PABP system. Very low aspect ratio structures (AR = 1/100, 10 μm in depth and 1000 μm in width) were successfully sealed without collapse or deformation. The integrity and strength of the bonds on the sealed PMMA devices were evaluated using leakage and rupture tests; no leaks were detected and failure during the rupture tests occurred at pressures greater than 496 kPa. The PABP system was used to seal 3D shaped flexible PMMA devices successfully. PMID:22728966

  2. The accommodation coefficient of the liquid at temperatures below the boiling

    NASA Astrophysics Data System (ADS)

    Bulba, Elena E.

    2015-01-01

    Are carried out experimental investigation of the laws of vaporization at temperatures below the boiling point. Is determined the mass rate of evaporation of distilled water in large intervals of time at different temperatures in order to sound conclusions about the stationarity of the process of evaporation of the liquid in the conditions of the experiments performed, and also studied the effect of temperature on the rate of evaporation. Accommodation coefficient is defined in the mathematical expression of the law of Hertz-Knudsen for standart substance used in the experiments.

  3. What Is the Boiling Point and Heat of Vaporization of Sulfuric Acid?

    ERIC Educational Resources Information Center

    Myers, R. Thomas

    1983-01-01

    Discusses the values presented in various handbooks for the boiling point and heat of vaporization of sulfuric acid, noting discrepencies. Analyzes various approaches to data presentation, discussing the data on sulfuric acid in light of the Trouton constant. Points out the need for a more critical use of tables. (JM)

  4. Boiling point determination using adiabatic Gibbs ensemble Monte Carlo simulations: Application to metals described by embedded-atom potentials

    NASA Astrophysics Data System (ADS)

    Gelb, Lev D.; Chakraborty, Somendra Nath

    2011-12-01

    The normal boiling points are obtained for a series of metals as described by the "quantum-corrected Sutton Chen" (qSC) potentials [S.-N. Luo, T. J. Ahrens, T. Çağın, A. Strachan, W. A. Goddard III, and D. C. Swift, Phys. Rev. B 68, 134206 (2003)]. Instead of conventional Monte Carlo simulations in an isothermal or expanded ensemble, simulations were done in the constant-NPH adabatic variant of the Gibbs ensemble technique as proposed by Kristóf and Liszi [Chem. Phys. Lett. 261, 620 (1996)]. This simulation technique is shown to be a precise tool for direct calculation of boiling temperatures in high-boiling fluids, with results that are almost completely insensitive to system size or other arbitrary parameters as long as the potential truncation is handled correctly. Results obtained were validated using conventional NVT-Gibbs ensemble Monte Carlo simulations. The qSC predictions for boiling temperatures are found to be reasonably accurate, but substantially underestimate the enthalpies of vaporization in all cases. This appears to be largely due to the systematic overestimation of dimer binding energies by this family of potentials, which leads to an unsatisfactory description of the vapor phase.

  5. Low-boiling-point solvent additives can also enable morphological control in polymer solar cells

    SciTech Connect

    Mahadevapuram, Rakesh C.; Carr, John A.; Chen, Yuqing; Bose, Sayantan; Nalwa, Kanwar S.; Petrich, Jacob W.; Chaudhary, Sumit

    2013-11-02

    Processing organic photovoltaic (OPV) blend solutions with high-boiling-point solvent additives has recently been used for morphological control in bulk-heterojunction OPV cells. Here we show that even low-boiling-point solvents can be effective additives. When P3HT:PCBM OPV cells were processed with a low-boiling-point solvent tetrahydrafuran as an additive in parent solvent o-dichlorobenzene, charge extraction increased leading to fill factors as high as 69.5%, without low work-function cathodes, electrode buffer layers or thermal treatment. This was attributed to PCBM demixing from P3HT domains and better vertical phase separation, as indicated by photoluminescence lifetimes, hole mobilities, and shunt leakage currents. Dependence on solvent parameters and applicability beyond P3HT system was also investigated. (C) 2013 Elsevier B.V. All rights reserved.

  6. Evaluation on environment-friendly refrigerants with similar normal boiling points in ejector refrigeration system

    NASA Astrophysics Data System (ADS)

    Wang, F.; Shen, S. Q.; Li, D. Y.

    2014-12-01

    Based on the "hypothetical throat area" theory and the "constant-pressure mixing" theory, a thermodynamic model for ejector was set up by introducing the real properties of refrigerants. Refrigerants which have similar normal boiling points with each other may act as replacement to each other in substitute progress. In this paper, eight environment-friendly refrigerants were divided into 4 pairs for study according to their normal boiling point. In each refrigerant pair, the entrainment ratios of ejector, system COP, pump power et al. of refrigerants were compared and analyzed. Lastly, the performances of the transcritical and subcritical ejector refrigeration cycles with propylene were calculated and compared.

  7. Dependences between the boiling point of binary aqueous-organic mixtures and their composition

    NASA Astrophysics Data System (ADS)

    Preobrazhenskii, M. P.; Rudakov, O. B.

    2015-01-01

    The optimum three-parametric regression basis set that reflects the properties of permutation symmetry and takes into account the specificity of isobars of aqueous-organic mixtures is constructed. The optimum algorithm for the calculation of the regression parameters of the boiling point isobars is proposed. The parameters are calculated for a series of systems. The accuracy of the method proposed for the regression description of the dependence of the boiling point of binary aqueous-organic mixtures on the composition is determined by empirical inaccuracies and is sufficient for the most part of practical applications. Methods for increasing the accuracy of the regression description of equilibrium homogeneous systems are formulated.

  8. Students' Understanding of Boiling Points and Intermolecular Forces

    ERIC Educational Resources Information Center

    Schmidt, Hans-Jurgen; Kaufmann, Birgit; Treagust, David F.

    2009-01-01

    In introductory chemistry courses students are presented with the model that matter is composed of particles, and that weak forces of attraction exist between them. This model is used to interpret phenomena such as solubility and melting points, and aids in understanding the changes in states of matter as opposed to chemical reactions. We…

  9. Students' Understanding of Boiling Points and Intermolecular Forces

    ERIC Educational Resources Information Center

    Schmidt, Hans-Jurgen; Kaufmann, Birgit; Treagust, David F.

    2009-01-01

    In introductory chemistry courses students are presented with the model that matter is composed of particles, and that weak forces of attraction exist between them. This model is used to interpret phenomena such as solubility and melting points, and aids in understanding the changes in states of matter as opposed to chemical reactions. We

  10. Explaining Melting and Evaporation below Boiling Point. Can Software Help with Particle Ideas?

    ERIC Educational Resources Information Center

    Papageorgiou, George; Johnson, Philip; Fotiades, Fotis

    2008-01-01

    This paper reports the findings of a study exploring the use of a software package to help pupils understand particulate explanations for melting and evaporation below boiling point. Two matched classes in a primary school in Greece (ages 11-12, n = 16 and 19) were involved in a short intervention of six one hour lessons. Covering the same…

  11. Explaining Melting and Evaporation below Boiling Point. Can Software Help with Particle Ideas?

    ERIC Educational Resources Information Center

    Papageorgiou, George; Johnson, Philip; Fotiades, Fotis

    2008-01-01

    This paper reports the findings of a study exploring the use of a software package to help pupils understand particulate explanations for melting and evaporation below boiling point. Two matched classes in a primary school in Greece (ages 11-12, n = 16 and 19) were involved in a short intervention of six one hour lessons. Covering the same

  12. Boiling Point

    NASA Technical Reports Server (NTRS)

    Jansen, Michael C.

    2002-01-01

    The author recounts his experiences he helped to investigate the accident which destroyed the Space Shuttle Challenger. The focus was on how he used novel approaches to investigate heat transfer in the shuttle's hydrogen tank, after an expert he sought for advice proved unhelpful.

  13. Comparison of simulated distillation to true boiling point distillation of H-Coal distillates

    SciTech Connect

    Kiser, M.D.; Malone, D.P.

    1982-01-01

    A comparison of simulated distillation to true boiling point (TBP) from both actual TBP distillation and single theoretical plate distillations converted to TBP for various H-Coal distillates is presented. The TBP distillation data was obtained using a Todd distillation column having 15 theoretical plates and a 5:1 reflux ratio. The simulated data presented were obtained using a Hewlitt Packard 5731 gas chromatograph equipped with dual flame ionization detectors. Graphical comparisons of distillation curves obtained by direct weight % TBP distillation and simulated distillation for a full range H-Coal syncrude, of boiling point curves for H-Coal naphtha, H-Coal middle distillate, and H-Coal heavy distillate are included. From an examination of the distillation data, it was apparent that simulated distillation data compared favorable with weight % distillation data, whether derived from direct TBP distillation or single theoretical plate distillation data and converted to TBP data. (BLM)

  14. Preparation and properties of low boiling point of alcohol and acetone-based magnetic fluid

    NASA Astrophysics Data System (ADS)

    Fujita, T.; Miyazaki, T.; Nishiyama, H.; Jeyadevan, B.

    1999-07-01

    Ultra-fine magnetic particles are difficult to be dispersed in low boiling point solvents such as alcohol (C 1-C 4) and acetone. In this paper, we report the preparation methods of several alcohol and acetone-based magnetic fluids. The stability of magnetic fluid depended on the HLB (hydrophile-lipophile balance) of the solvent and alkyl chain lengths of organic layers. The fluid was most stable only when the HLB value of surfactant and the solvents are similar.

  15. A regression model for calculating the boiling point isobars of tetrachloromethane-based binary solutions

    NASA Astrophysics Data System (ADS)

    Preobrazhenskii, M. P.; Rudakov, O. B.

    2016-01-01

    A regression model for calculating the boiling point isobars of tetrachloromethane-organic solvent binary homogeneous systems is proposed. The parameters of the model proposed were calculated for a series of solutions. The correlation between the nonadditivity parameter of the regression model and the hydrophobicity criterion of the organic solvent is established. The parameter value of the proposed model is shown to allow prediction of the potential formation of azeotropic mixtures of solvents with tetrachloromethane.

  16. Emplacement temperatures of boiling-over pyroclastic density currents from Tungurahua and Cotopaxi volcanoes, Ecuador

    NASA Astrophysics Data System (ADS)

    Rader, E. L.; Geist, D.; Geissman, J. W.; Harpp, K. S.; Dufek, J.

    2011-12-01

    Pyroclastic density currents (PDC) can be sourced by collapsing columns, dome collapse, and boiling-over fountains. Although there are innumerable studies of the deposits produced by the first 2 mechanisms, pyroclastic deposits from boiling-over have not been well characterized. We are studying several pyroclastic flow deposits from two boiling over eruptions in Ecuador, Tungurahua, 2006 and Cotopaxi, 1877. These eruptions produced abundant cauliflower-textured, large (up to 1 m in diameter), fragile scoria clasts. Some evidence points to relatively low temperatures during transport. For example, some flows at Cotopaxi are unusually long and sinuous and probably influenced by melt water from the glacier that caps the cone. Additionally, un-charred vegetation and eyewitness reports of un-melted plastic in the path of pyroclastic flows at Tungurahua also support cool emplacement temperatures. On the other hand, some scoria clasts were ductile when deposited as evidenced by draped clasts. We cut 5 to 9 cm transects from rim to core of 36 lithic and juvenile samples, which were then thermally demagnetized and measured. Lithic samples from Tungurahua indicate only one flow was fully remagnetized above ~580°C, while another flow was only partially remagnetized below 210°C. All other lithics from both volcanoes were never heated to above 90°C. Juvenile clasts from Cotopaxi indicate three types of flows: currents that begin hot (above 580°C) but cool quickly (juveniles emplaced hot, but lithics emplaced cold); currents that deposit at ~330°C (two components of magnetization that intersect at 330°C in the juvenile clasts), and cold currents such as lahars. The majority of currents from Tungurahua are of the 2nd type, having emplacement temperatures of ~380°C-280°C, with the deformable juvenile clasts being hotter than the rest of the flow. Despite the intact nature of the fragile bombs, emplacement temperatures indicate that the majority of flow deposits at Tungurahua and Cotopaxi were emplaced at temperatures between 210°C and 380°C. The presence of abundant scoria bombs in other PDC deposits are likely indicative of flow and deposition at relatively low temperatures in currents produced by a boiling-over mechanism.

  17. Measurement of the droplets sizes of a flash boiling spray using an improved extended glare point velocimetry and sizing

    NASA Astrophysics Data System (ADS)

    Shen, Shiquan; Jia, Ming; Wang, Tianyou; Lü, Qieni; Sun, Kai

    2016-04-01

    An improved extended glare point velocimetry and sizing (EGPVS) is proposed to investigate the droplets sizes of a flash boiling spray. When a spherical droplet with a relative refractive index from 1.16 to 1.41 is illuminated by two opposite laser sheets and a charge-coupled device camera is used to collect the s-polarization light at an observation angle of 90°, the intensities of the reflected lights are much stronger than the other order scattering lights. If the intensity of incident laser is controlled appropriately, two glare points from the reflected lights for the droplet are formed at the focused plane, while the intensities of the other order scattering lights are too weak to form any glare points. Then, the droplet diameter can be derived from the distance between the two glare points. In addition, the focused image is relative small, making it possible to measure dense spray. First, the characteristics of the improved EGPVS are discussed, and a series of standard particles are measured for validating this technique. Then, the technique is applied to investigate the droplets sizes of flash boiling spray. It is found that the minimum measurable diameter of droplets is 7.1 μm, and the relative error is less than 4.7 %. The droplet size distributions of spray are different at different stages. The Sauter mean diameter (SMD) of gasoline spray decreases gradually as the fuel temperature increases, which is different from that of a single-component fuel with a sharp decrease in SMD at the flash boiling stage.

  18. Doppler signals observed during high temperature thermal ablation are the result of boiling

    PubMed Central

    NAHIRNYAK, VOLODYMYR M.; MOROS, EDUARDO G.; NOVÁK, PETR; KLIMBERG, V. SUZANNE; SHAFIRSTEIN, GAL

    2010-01-01

    Purpose To elucidate the causation mechanism of Spectral Doppler ultrasound signals (DUS) observed during high temperature thermal ablation and evaluate their potential for image-guidance. Methods Sixteen ex vivo ablations were performed in fresh turkey breast muscle, eight with radiofrequency ablation (RFA) devices, and eight with a conductive interstitial thermal therapy (CITT) device. Temperature changes in the ablation zone were measured with thermocouples located at 1 to 10mm away from the ablation probes. Concomitantly, DUS were recorded using a standard diagnostic ultrasound scanner. Retrospectively, sustained observations of DUS were correlated with measured temperatures. Sustained DUS was arbitrarily defined as the Doppler signals lasting more than 10 s as observed in the diagnostic ultrasound videos captured from the scanner. Results For RFA experiments, minimum average temperature (T1±SD) at which sustained DUS were observed was 97.2±7.3°C, while the maximum average temperature (T2±SD) at which DUS were not seen was 74.3±9.1°C. For CITT ablation, T1 and T2 were 95.7±5.9°C and 91.6±7.2°C, respectively. It was also observed, especially during CITT ablation, that temperatures remained relatively constant during Doppler activity. Conclusions The value of T1 was near the standard boiling point of water (99.61°C) while T2 was below it. Together, T1 and T2 support the conclusion that DUS during high temperature thermal ablation are the result of boiling (phase change). This conclusion is also supported by the nearly constant temperature histories maintained at locations from which DUS emanated. PMID:20569109

  19. Net vapor generation point in boiling flow of trichlorotrifluoroethane at high pressures

    NASA Technical Reports Server (NTRS)

    Dougall, R. S.; Lippert, T. E.

    1973-01-01

    The conditions at which the void in subcooled boiling starts to undergo a rapid increase were studied experimentally. The experiments were performed in a 12.7 x 9.5 mm rectangular channel. Heating was from a 3.2 mm wide strip embedded in one wall. The pressure ranged from 9.45 to 20.7 bar, mass velocity from 600 to 7000 kg/sq m sec, and subcooling from 16 to 67 C. Photographs were used to determine when detached bubbles first appeared in the bulk flow. Measurements of bubble layer thickness along the wall were also made. Results showed that the point of net vapor generation is close to the occurrence of fully-developed boiling.

  20. Estimating surface temperature in forced convection nucleate boiling - A simplified method

    NASA Technical Reports Server (NTRS)

    Hendricks, R. C.; Papell, S. S.

    1977-01-01

    A simplified expression to estimate surface temperatures in forced convection boiling was developed using a liquid nitrogen data base. Using the principal of corresponding states and the Kutateladze relation for maximum pool boiling heat flux, the expression was normalized for use with other fluids. The expression was applied also to neon and water. For the neon data base, the agreement was acceptable with the exclusion of one set suspected to be in the transition boiling regime. For the water data base at reduced pressure greater than 0.05 the agreement is generally good. At lower reduced pressures, the water data scatter and the calculated temperature becomes a function of flow rate.

  1. Numerical study on temperature distribution around a boiling bubble departing from heating surface in subcooled pool

    NASA Astrophysics Data System (ADS)

    Ose, Yasuo; Kunugi, Tomoaki

    2014-06-01

    In this paper, the transient three-dimensional numerical simulations based on the MARS (Multi-interface Advection and Reconstruction Solver) with the non-empirical boiling and condensation model have been conducted for an isolated boiling bubble behavior in a subcooled pool. The temperature distributions formed around the subcooled pool boiling bubble departing from a heating surface obtained by the numerical simulations were investigated. As the results, it was found that several thermal plumes with different temperature were formed during the bubble departure from the heating surface by using the volume rendering visualization technique.

  2. Morphological control in polymer solar cells using low-boiling-point solvent additives

    NASA Astrophysics Data System (ADS)

    Mahadevapuram, Rakesh C.

    In the global search for clean, renewable energy sources, organic photovoltaics (OPVs) have recently been given much attention. Popular modern-day OPVs are made from solution-processible, carbon-based polymers (e.g. the model poly(3-hexylthiophene) that are intimately blended with fullerene derivatives (e.g. [6,6]-phenyl-C71-butyric acid methyl ester) to form what is known as the dispersed bulk-heterojunction (BHJ). This BHJ architecture has produced some of the most efficient OPVs to date, with reports closing in on 10% power conversion efficiency. To push efficiencies further into double digits, many groups have identified the BHJ nanomorphology---that is, the phase separations and grain sizes within the polymer: fullerene composite---as a key aspect in need of control and improvement. As a result, many methods, including thermal annealing, slow-drying (solvent) annealing, vapor annealing, and solvent additives, have been developed and studied to promote BHJ self-organization. Processing organic photovoltaic (OPV) blend solutions with high-boiling-point solvent additives has recently been used for morphological control in BHJ OPV cells. Here we show that even low-boiling-point solvents can be effective additives. When P3HT:PCBM OPV cells were processed with a low-boiling-point solvent tetrahydrafuran as an additive in parent solvent o-dichlorobenzene, charge extraction increased leading to fill factors as high as 69.5%, without low work-function cathodes, electrode buffer layers or thermal treatment. This was attributed to PCBM demixing from P3HT domains and better vertical phase separation, as indicated by photoluminescence lifetimes, hole mobilities, and shunt leakage currents. Dependence on solvent parameters and applicability beyond P3HT system was also investigated.

  3. Generalized syntheses of nanocrystal-graphene hybrids in high-boiling-point organic solvents

    NASA Astrophysics Data System (ADS)

    Pang, Danny Wei-Ping; Yuan, Fang-Wei; Chang, Yan-Cheng; Li, Guo-An; Tuan, Hsing-Yu

    2012-07-01

    Nanocrystal-graphene have been proposed as a new kind of promising hybrid for a wide range of application areas including catalysts, electronics, sensors, biomedicine, and energy storage, etc. Although a variety of methods have been developed for the preparation of hybrids, a facile and general synthetic approach is still highly required. In this study, nanocrystal-graphene hybrids were successfully synthesized in high-boiling-point organic solvents. Graphene oxide (GO) nanosheets were modified by oleylamine (OLA) to form a OLA-GO complex in order to be readily incorporated into hydrophobic synthesis. A rich library of highly crystalline nanocrystals, with types including noble metal, metal oxide, magnetic material and semiconductor were successfully grown on chemically converted graphene (CCG), which is simultaneously reduced from GO during the synthesis. High boiling-point solvents afford sufficient thermal energy to assure the high-quality crystalline nature of NCs, therefore the post-annealing process is obviated. Controlled experiments revealed that OLA-GO triggers heterogeneous nucleation and serves as excellent nuclei anchorage media. The protocol developed here brings one step closer to achieve ``unity in diversity'' on the preparation of nanocrystal-graphene hybrids.Nanocrystal-graphene have been proposed as a new kind of promising hybrid for a wide range of application areas including catalysts, electronics, sensors, biomedicine, and energy storage, etc. Although a variety of methods have been developed for the preparation of hybrids, a facile and general synthetic approach is still highly required. In this study, nanocrystal-graphene hybrids were successfully synthesized in high-boiling-point organic solvents. Graphene oxide (GO) nanosheets were modified by oleylamine (OLA) to form a OLA-GO complex in order to be readily incorporated into hydrophobic synthesis. A rich library of highly crystalline nanocrystals, with types including noble metal, metal oxide, magnetic material and semiconductor were successfully grown on chemically converted graphene (CCG), which is simultaneously reduced from GO during the synthesis. High boiling-point solvents afford sufficient thermal energy to assure the high-quality crystalline nature of NCs, therefore the post-annealing process is obviated. Controlled experiments revealed that OLA-GO triggers heterogeneous nucleation and serves as excellent nuclei anchorage media. The protocol developed here brings one step closer to achieve ``unity in diversity'' on the preparation of nanocrystal-graphene hybrids. Electronic supplementary information (ESI) available: detail of experimental parameters, AFM, FTIR, XRD, XPS spectra, and other TEM images of GO, CCG and NC-CCG. See DOI: 10.1039/c2nr30915g

  4. A new procedure for the determination of distillation temperature distribution of high-boiling petroleum products and fractions.

    PubMed

    Boczkaj, Grzegorz; Przyjazny, Andrzej; Kamiński, Marian

    2011-03-01

    The distribution of distillation temperatures of liquid and semi-fluid products, including petroleum fractions and products, is an important process and practical parameter. It provides information on properties of crude oil and content of particular fractions, classified on the basis of their boiling points, as well as the optimum conditions of atmospheric or vacuum distillation. At present, the distribution of distillation temperatures is often investigated by simulated distillation (SIMDIS) using capillary gas chromatography (CGC) with a short capillary column with polydimethylsiloxane as the stationary phase. This paper presents the results of investigations on the possibility of replacing currently used CGC columns for SIMDIS with a deactivated fused silica capillary tube without any stationary phase. The SIMDIS technique making use of such an empty fused silica column allows a considerable lowering of elution temperature of the analytes, which results in a decrease of the final oven temperature while ensuring a complete separation of the mixture. This eliminates the possibility of decomposition of less thermally stable mixture components and bleeding of the stationary phase which would result in an increase of the detector signal. It also improves the stability of the baseline, which is especially important in the determination of the end point of elution, which is the basis for finding the final temperature of distillation. This is the key parameter for the safety process of hydrocracking, where an excessively high final temperature of distillation of a batch can result in serious damage to an expensive catalyst bed. This paper compares the distribution of distillation temperatures of the fraction from vacuum distillation of petroleum obtained using SIMDIS with that obtained by the proposed procedure. A good agreement between the two procedures was observed. In addition, typical values of elution temperatures of n-paraffin standards obtained by the two procedures were compared. Finally, the agreement between boiling points of polar compounds determined from their retention times and actual boiling points was investigated. PMID:21153592

  5. Experimental study of flash boiling spray vaporization through quantitative vapor concentration and liquid temperature measurements

    NASA Astrophysics Data System (ADS)

    Zhang, Gaoming; Hung, David L. S.; Xu, Min

    2014-08-01

    Flash boiling sprays of liquid injection under superheated conditions provide the novel solutions of fast vaporization and better air-fuel mixture formation for internal combustion engines. However, the physical mechanisms of flash boiling spray vaporization are more complicated than the droplet surface vaporization due to the unique bubble generation and boiling process inside a superheated bulk liquid, which are not well understood. In this study, the vaporization of flash boiling sprays was investigated experimentally through the quantitative measurements of vapor concentration and liquid temperature. Specifically, the laser-induced exciplex fluorescence technique was applied to distinguish the liquid and vapor distributions. Quantitative vapor concentration was obtained by correlating the intensity of vapor-phase fluorescence with vapor concentration through systematic corrections and calibrations. The intensities of two wavelengths were captured simultaneously from the liquid-phase fluorescence spectra, and their intensity ratios were correlated with liquid temperature. The results show that both liquid and vapor phase of multi-hole sprays collapse toward the centerline of the spray with different mass distributions under the flash boiling conditions. Large amount of vapor aggregates along the centerline of the spray to form a "gas jet" structure, whereas the liquid distributes more uniformly with large vortexes formed in the vicinity of the spray tip. The vaporization process under the flash boiling condition is greatly enhanced due to the intense bubble generation and burst. The liquid temperature measurements show strong temperature variations inside the flash boiling sprays with hot zones present in the "gas jet" structure and vortex region. In addition, high vapor concentration and closed vortex motion seem to have inhibited the heat and mass transfer in these regions. In summary, the vapor concentration and liquid temperature provide detailed information concerning the heat and mass transfer inside flash boiling sprays, which is important for the understanding of its unique vaporization process.

  6. Change points of global temperature

    NASA Astrophysics Data System (ADS)

    Cahill, Niamh; Rahmstorf, Stefan; Parnell, Andrew C.

    2015-08-01

    We aim to address the question of whether or not there is a significant recent hiatus, pause or slowdown of global temperature rise. Using a statistical technique known as change point (CP) analysis we identify the changes in four global temperature records and estimate the rates of temperature rise before and after these changes occur. For each record the results indicate that three CPs are enough to accurately capture the variability in the data with no evidence of any detectable change in the global warming trend since ?1970. We conclude that the term hiatus or pause cannot be statistically justified.

  7. Full evaporation headspace gas chromatography for sensitive determination of high boiling point volatile organic compounds in low boiling matrices.

    PubMed

    Mana Kialengila, Didi; Wolfs, Kris; Bugalama, John; Van Schepdael, Ann; Adams, Erwin

    2013-11-01

    Determination of volatile organic components (VOC's) is often done by static headspace gas chromatography as this technique is very robust and combines easy sample preparation with good selectivity and low detection limits. This technique is used nowadays in different applications which have in common that they have a dirty matrix which would be problematic in direct injection approaches. Headspace by nature favors the most volatile compounds, avoiding the less volatile to reach the injector and column. As a consequence, determination of a high boiling solvent in a lower boiling matrix becomes challenging. Determination of VOCs like: xylenes, cumene, N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), N,N-dimethylacetamide (DMA), N-methyl-2-pyrrolidone (NMP), 1,3-dimethyl-2-imidazolidinone (DMI), benzyl alcohol (BA) and anisole in water or water soluble products are an interesting example of the arising problems. In this work, a headspace variant called full evaporation technique is worked out and validated for the mentioned solvents. Detection limits below 0.1 μg/vial are reached with RSD values below 10%. Mean recovery values ranged from 92.5 to 110%. The optimized method was applied to determine residual DMSO in a water based cell culture and DMSO and DMA in tetracycline hydrochloride (a water soluble sample). PMID:24103808

  8. Experimental Research on Dryout Point of Flow Boiling in Narrow Annuli

    SciTech Connect

    Ge Ping Wu; Sui Zheng Qiu; Guang Hai Su; Dou Nan Jia

    2006-07-01

    An experimental research on the dryout point of flow boiling in narrow annuli is conducted under low mass flux with 1.5 mm and 1.0 mm gap, respectively. Distilled water is used as work fluid, the range of pressure is from 2.0 to 4.0 MPa and that of mass flux is 26.0{approx}69.0 kg/(m{sup 2}. s). The relation of CHF and critical qualities with mass flux and pressure are revealed. It is found that the critical qualities decrease with the mass flux and increase with the inlet qualities in externally heated annuli. Under the same conditions critical qualities in outer tube are always larger than that in inner tube. KyTaTeLaDe3e's correlations is cited and modified to predict the location of dryout and proved to be not a proper one. Considering in detail the effects of the geometry of annuli and heat flux on dryout, an empirical correction is finally developed to predict dryout point in narrow annuli under low mass flux condition which has a good agreement with experimental data. (authors)

  9. Method of and apparatus for determining deposition-point temperature

    DOEpatents

    Mansure, A.J.; Spates, J.J.; Martin, S.J.

    1998-10-27

    Acoustic-wave sensor apparatus and method are disclosed for analyzing a normally liquid petroleum-based composition for monitoring deposition-point temperature. The apparatus includes at least one acoustic-wave device such as SAW, QCM, FPM, TSM or APM type devices in contact with the petroleum-based composition for sensing or detecting the surface temperature at which deposition occurs and/or rate of deposition as a function of temperature by sensing an accompanying change in frequency, phase shift, damping voltage or damping current of an electrical oscillator to a known calibrated condition. The acoustic wave device is actively cooled to monitor the deposition of constituents such as paraffins by determining the point at which solids from the liquid composition begin to form on the acoustic wave device. The acoustic wave device can be heated to melt or boil off the deposits to reset the monitor and the process can be repeated. 5 figs.

  10. Method of and apparatus for determining deposition-point temperature

    DOEpatents

    Mansure, Arthur J.; Spates, James J.; Martin, Stephen J.

    1998-01-01

    Acoustic-wave sensor apparatus and method for analyzing a normally liquid petroleum-based composition for monitoring deposition-point temperature. The apparatus includes at least one acoustic-wave device such as SAW, QCM, FPM, TSM or APM type devices in contact with the petroleum-based composition for sensing or detecting the surface temperature at which deposition occurs and/or rate of deposition as a function of temperature by sensing an accompanying change in frequency, phase shift, damping voltage or damping current of an electrical oscillator to a known calibrated condition. The acoustic wave device is actively cooled to monitor the deposition of constituents such as paraffins by determining the point at which solids from the liquid composition begin to form on the acoustic wave device. The acoustic wave device can be heated to melt or boil off the deposits to reset the monitor and the process can be repeated.

  11. Boiling Heat Transfer in High Temperature Generator of Absorption Chiller/Heater

    NASA Astrophysics Data System (ADS)

    Furukawa, Masahiro; Enomoto, Eiichi; Sekoguchi, Kotohiko

    Heat transfer performance of forced convective boiling in high temperature generator was experimentally studied using an actual absorption chiller/heater. Measurements were made at six locations, three different levels on a couple of laterally separated lines, for the fluid rising along the rear wall of the high temperature generator furnace. Fluids tested were water and lithium bromide aqueous solution. System pressures were maintained at 96 and 24 kPa, and firing rates were changed from 100 to 40 % of the full load of the machine. Through the experiments, thermodynamic states of both of the fluids were in subcooled region at the lower and middle locations and in saturated region at the upper location. It can be suggested that saturated boiling occurs at comparatively narrow area, located at the upper zone of heat transfer surface of the generator, while forced convective heat transfer and subcooled boiling appear at the remaining broad area. Enhancement of heat transfer due to saturated boiling was not pronounced for lithium bromide aqueous solution than for water.

  12. Boiling Heat Transfer in High Temperature Generator of Absorption Chiller/Heater

    NASA Astrophysics Data System (ADS)

    Furukawa, Masahiro; Enomoto, Eiichi; Sekoguchi, Kotohiko

    The heat transfer performance of forced convective boiling was tested using a high temperature generator of absorption chiller/heater, the rear furnace wall of which was composed of two different surfaces; i. e., plain and sprayed heated surfaces. These two surfaces were bisymmetrically set. Wall surface temperatures of both the fire and fluid sides were measured at three locations along the upward flow direction in each heated surface for determining the heat flux and heat transfer coefficient. Nickel-chromium and alumina were employed as the spray materials. The test results show that the sprayed surface can yield a marked elevation in the heat transfer performance due to boiling on the plain surface. Therefore the level of heated surface temperature is largely reduced by means of the spraying surface treatment. This implies that the spraying would much improve a corrosive condition of the heated surface.

  13. Chemical characterization and genotoxic potential related to boiling point for fractionally distilled SRC-I coal liquids

    SciTech Connect

    Wilson, B.W.; Pelroy, R.A.; Mahlum, D.D.

    1982-07-01

    This report summarizes selected research efforts oriented toward ameliorating the genotoxic potential of direct coal liquefaction materials through modification or optimization of process conditions. The studies described were conducted to evaluate the utility of optimized distillation for coal liquids from the SRC-I process. SRC-I process solvent was distilled into 50/sup 0/F-range boiling point (bp) cuts. Analysis of amino-PAH (APAH) showed that mutagenic APAHs containing 3 or more rings were found primarily in fractions boiling above 750/sup 0/F. Three microbial tester strains were used to screen for genetically active agents in the SRC-I distillate bp cuts. Reverse mutation with the Ames tester strain TA98 demonstrated that mutagens were concentrated in the bp cuts boiling above 700/sup 0/F. For this tester strain most of the genetic activity in these distillates was attributable to chemical fractions enriched in APAH having 3 or more rings. Mutagenicity data obtained with TA98 was in good agreement with sk in carcinogenesis results from the mouse-skin initiation/promotion (in vivo) test system. The strongest response in the forward mutation assay did not occur in the most carcinogenically active fractions. Results of initiation/promotion experiments used to measure the relative potency of bp cuts as initiators of mouse skin carcinogenesis again showed that fractions boiling above 750/sup 0/F. Compounds reaching their highest concentrations in the highest boiling and most carcinogenically active cut included known carcinogens such as benzo(a)pyrene and dimethyl benzanthracene. Thus, all biomedical test results indicate that consideration should be given to conducting distillation so as to minimize, in the distillate product, the concentrations of those biologically active compounds found in cuts boiling above 700/sup 0/C.

  14. Review of magnetic properties and magnetocaloric effect in the intermetallic compounds of rare earth with low boiling point metals

    NASA Astrophysics Data System (ADS)

    Ling-Wei, Li

    2016-03-01

    The magnetocaloric effect (MCE) in many rare earth (RE) based intermetallic compounds has been extensively investigated during the last two decades, not only due to their potential applications for magnetic refrigeration but also for better understanding of the fundamental problems of the materials. This paper reviews our recent progress on studying the magnetic properties and MCE in some binary or ternary intermetallic compounds of RE with low boiling point metal(s) (Zn, Mg, and Cd). Some of them exhibit promising MCE properties, which make them attractive for low temperature magnetic refrigeration. Characteristics of the magnetic transition, origin of large MCE, as well as the potential application of these compounds are thoroughly discussed. Additionally, a brief review of the magnetic and magnetocaloric properties in the quaternary rare earth nickel boroncarbides RENi2B2C superconductors is also presented. Project supported by the National Natural Science Foundation of China (Grant Nos. 11374081 and 11004044), the Fundamental Research Funds for the Central Universities, China (Grant Nos. N150905001, L1509006, and N140901001), the Japan Society for the Promotion of Science Postdoctoral Fellowships for Foreign Researchers (Grant No. P10060), and the Alexander von Humboldt (AvH) Foundation (Research stipend to L. Li).

  15. Determination of the boiling-point distribution by simulated distillation from n-pentane through n-tetratetracontane in 70 to 80 seconds.

    PubMed

    Lubkowitz, Joaquin A; Meneghini, Roberto I

    2002-01-01

    This work presents the carrying out of boiling-point distributions by simulated distillation with direct-column heating rather than oven-column heating. Column-heating rates of 300 degrees C/min are obtained yielding retention times of 73 s for n-tetratetracontane. The calibration curves of the retention time versus the boiling point, in the range of n-pentane to n-tetratetracontane, are identical to those obtained by slower oven-heating rates. The boiling-point distribution of the reference gas oil is compared with that obtained with column oven heating at rates of 15 to 40 degrees C/min. The results show boiling-point distribution values nearly the same (1-2 degrees F) as those obtained with oven column heating from the initial boiling point to 80% distilled off. Slightly higher differences are obtained (3-4 degrees F) for the 80% distillation to final boiling-point interval. Nonetheless, allowed consensus differences are never exceeded. Precision of the boiling-point distributions (expressed as standard deviations) are 0.1-0.3% for the data obtained in the direct column-heating mode. PMID:12049156

  16. A Closer Look at Trends in Boiling Points of Hydrides: Using an Inquiry-Based Approach to Teach Intermolecular Forces of Attraction

    ERIC Educational Resources Information Center

    Glazier, Samantha; Marano, Nadia; Eisen, Laura

    2010-01-01

    We describe how we use boiling-point trends of group IV-VII hydrides to introduce intermolecular forces in our first-year general chemistry classes. Starting with the idea that molecules in the liquid state are held together by some kind of force that must be overcome for boiling to take place, students use data analysis and critical reasoning to…

  17. A Closer Look at Trends in Boiling Points of Hydrides: Using an Inquiry-Based Approach to Teach Intermolecular Forces of Attraction

    ERIC Educational Resources Information Center

    Glazier, Samantha; Marano, Nadia; Eisen, Laura

    2010-01-01

    We describe how we use boiling-point trends of group IV-VII hydrides to introduce intermolecular forces in our first-year general chemistry classes. Starting with the idea that molecules in the liquid state are held together by some kind of force that must be overcome for boiling to take place, students use data analysis and critical reasoning to

  18. Below and above boiling point comparison of microwave irradiation and conductive heating for municipal sludge digestion under identical heating/cooling profiles.

    PubMed

    Hosseini Koupaie, E; Eskicioglu, C

    2015-01-01

    This research provides a comprehensive comparison between microwave (MW) and conductive heating (CH) sludge pretreatments under identical heating/cooling profiles at below and above boiling point temperatures. Previous comparison studies were constrained to an uncontrolled or a single heating rate due to lack of a CH equipment simulating MW under identical thermal profiles. In this research, a novel custom-built pressure-sealed vessel which could simulate MW pretreatment under identical heating/cooling profiles was used for CH pretreatment. No statistically significant difference was proven between MW and CH pretreatments in terms of sludge solubilization, anaerobic biogas yield and organics biodegradation rate (p-value>0.05), while statistically significant effects of temperature and heating rate were observed (p-value<0.05). These results explain the contradictory results of previous studies in which only the final temperature (not heating/cooling rates) was controlled. PMID:25863200

  19. Water boiling inside carbon nanotubes: toward efficient drug release.

    PubMed

    Chaban, Vitaly V; Prezhdo, Oleg V

    2011-07-26

    We show using molecular dynamics simulation that spatial confinement of water inside carbon nanotubes (CNTs) substantially increases its boiling temperature and that a small temperature growth above the boiling point dramatically raises the inside pressure. Capillary theory successfully predicts the boiling point elevation down to 2 nm, below which large deviations between the theory and atomistic simulation take place. Water behaves qualitatively different inside narrow CNTs, exhibiting transition into an unusual phase, where pressure is gas-like and grows linearly with temperature, while the diffusion constant is temperature-independent. Precise control over boiling by CNT diameter, together with the rapid growth of inside pressure above the boiling point, suggests a novel drug delivery protocol. Polar drug molecules are packaged inside CNTs; the latter are delivered into living tissues and heated by laser. Solvent boiling facilitates drug release. PMID:21648482

  20. Experimental study of nucleate boiling heat transfer under low gravity conditions using TLCs for high resolution temperature measurements

    NASA Astrophysics Data System (ADS)

    Wagner, Enno; Sodtke, Christof; Schweizer, Nils; Stephan, Peter

    2006-08-01

    Heat transfer in nucleate boiling is strongly influenced by a very small circular area in the vicinity of the three phase contact line where a thin liquid film approaches the heated wall. This area is characterised by high evaporation rates which trigger a local temperature drop in the wall. The wall temperature drop can be computed using an existing nucleate boiling model. To verify the complex model and the underlying assumptions, an experiment was designed with an artificial nucleation site in a thin electrically heated wall featuring a two-dimensional, high resolution temperature measurement technique using unencapsulated thermochromic liquid crystals and a high speed colour camera. The shape of the bubble is observed simultaneously with a second high speed camera. Experiments were conducted in a low gravity environment of a parabolic flight, causing larger bubble departure diameters than in normal gravity environments. Thus, it was possible to measure the evolution of the predicted temperature drop in a transient boiling process.

  1. Phase Separation, Density Fluctuations, and Boiling Near the Liquid-Gas Critical Point

    NASA Astrophysics Data System (ADS)

    Hegseth, John; Oprisan, Ana; Roy, Arun; Nikolayev, Vadim; Beysens, Daniel; Garrabos, Yves; Lecoutre-Chabot, Carole

    2002-11-01

    A pure liquid-gas mixture is one of the simplest examples of a soft-matter system. In fact, when co-existing gas and liquid phases of pure fluid are heated to their critical point, large-scale density fluctuations make the fluid extremely compressible (to external forces), expandable (to heating), slows the diffusive transport, and decreases the surface tension. In principle these properties and others either diverge to infinity or converge to zero at the critical temperature. These properties lead to some very unusual behavior: large density gradients at the laboratory scale, a large mechanical response to heating, and perfect wetting of a solid wall by the liquid phase (zero contact-angle). We have further simplified this system by performing experiments in weightlessness (Mir spaces station). By controlling the fluid's temperature, these properties may be varied over large ranges in a single sample. When the fluid is driven out of equilibrium by a fast temperature quench from the single-phase (supercritical fluid) state into the two-phase state, we have observed universal growth laws of minority domains (gas bubbles) during phase separation. Prior to this quench we have also observed density fluctuations using optical microscopy near the critical point. When heat is applied to a liquid-gas mixture, we have observed a spectacular spreading of a gas bubble along a hot solid wall as well as gas bubble over-heating (where the interior of a gas bubble gains a higher temperature than the heating wall). Although this gas phase over-heating appears to violate the second law, it is really a transient our-of-equilibrium effect. Inside of these unusual bubbles we also have observed unusually large variations in liquid wetting film thickness that often appear to evolve into spreading contact lines on the sapphire wall when heat is applied. We have observed coarsening and growth of minority domains (gas bubbles) in SF6 near its liquid-gas critical point. Phase separation in our constant density samples was induced in our constant volume cells by temperature quenches in weightless conditions (Mir station), while visualizing density fluctuations and domain growth using optical microscopy. The optics of the formation of the density fluctuation images will be discussed. The well-known statistics of the density fluctuations provide natural space and time scales for domain growth. Previous experiments have documented two morphologies and two associated growth laws with a sharp transition between the two. This transition appears to be controlled by the minority volume fraction. While the slow, t 1/3 growth, for disconnected morphologies, is understood as a diffusion process, the fast growth, t1 growth, for connected domains, is less well-understood. We will discuss several shallow quenching sequences at the critical density (+/-0.02%) and slightly off-critical where we have observed fast linear growth.

  2. Remote temperature-set-point controller

    DOEpatents

    Burke, William F.; Winiecki, Alan L.

    1986-01-01

    An instrument for carrying out mechanical strain tests on metallic samples with the addition of an electrical system for varying the temperature with strain, the instrument including opposing arms and associated equipment for holding a sample and varying the mechanical strain on the sample through a plurality of cycles of increasing and decreasing strain within predetermined limits, circuitry for producing an output signal representative of the strain during the tests, apparatus including a set point and a coil about the sample for providing a controlled temperature in the sample, and circuitry interconnected between the strain output signal and set point for varying the temperature of the sample linearly with strain during the tests.

  3. Gas chromatographic simulated distillation-mass spectrometry for the determination of the boiling point distributions of crude oils

    PubMed

    Roussis; Fitzgerald

    2000-04-01

    The coupling of gas chromatographic simulated distillation with mass spectrometry for the determination of the distillation profiles of crude oils is reported. The method provides the boiling point distributions of both weight and volume percent amounts. The weight percent distribution is obtained from the measured total ion current signal. The total ion current signal is converted to weight percent amount by calibration with a reference crude oil of a known distillation profile. Knowledge of the chemical composition of the crude oil across the boiling range permits the determination of the volume percent distribution. The long-term repeatability is equivalent to or better than the short-term repeatability of the currently available American Society for Testing and Materials (ASTM) gas chromatographic method for simulated distillation. Results obtained by the mass spectrometric method are in very good agreement with results obtained by conventional methods of physical distillation. The compositional information supplied by the method can be used to extensively characterize crude oils. PMID:10763233

  4. Measurement of thermodynamic temperature of high temperature fixed points

    SciTech Connect

    Gavrilov, V. R.; Khlevnoy, B. B.; Otryaskin, D. A.; Grigorieva, I. A.; Samoylov, M. L.; Sapritsky, V. I.

    2013-09-11

    The paper is devoted to VNIIOFI's measurements of thermodynamic temperature of the high temperature fixed points Co-C, Pt-C and Re-C within the scope of the international project coordinated by the Consultative Committee for Thermometry working group 5 'Radiation Thermometry'. The melting temperatures of the fixed points were measured by a radiance mode radiation thermometer calibrated against a filter radiometer with known irradiance spectral responsivity via a high temperature black body. This paper describes the facility used for the measurements, the results and estimated uncertainties.

  5. Time and Space Resolved Wall Temperature Measurements during Nucleate Boiling with Constant Heat Flux Boundary Conditions

    NASA Technical Reports Server (NTRS)

    Myers, Jerry G.; Hussey, Sam W.; Yee, Glenda F.; Yerramilli, Vamsee K.; Kim, Jungho

    2005-01-01

    The lack of temporally and spatially resolved measurements under nucleate bubbles has complicated efforts to fully explain pool-boiling phenomena. The objective of this current work is to acquire time and space resolved temperature distributions under nucleate bubbles on a constant heat flux surface. This was performed using a microheater array with 100 micron resolution that allowed effectively simultaneous measurements of surface temperature while supplying a constant dissipative heat flux. This data is then correlated with high speed (> 1000Hz) visual recordings of the bubble growth and departure from the heater surface acquired from below and from the side of the heater. The data indicate that a significant source of energy during bubble nucleation and initial growth is the superheated layer around the bubble. Bubble coalescence was not observed to decrease surface temperature as significantly as bubble departure from the surface. Since bubble departure is typically followed by a sharp increase in the heater surface temperature, it is surmised that the departing bubble effectively removes the superheated layer, allowing a high local heat transfer rate with the bulk fluid through transient conduction/micro-convection during rewetting.

  6. Secondary pool boiling effects

    NASA Astrophysics Data System (ADS)

    Kruse, C.; Tsubaki, A.; Zuhlke, C.; Anderson, T.; Alexander, D.; Gogos, G.; Ndao, S.

    2016-02-01

    A pool boiling phenomenon referred to as secondary boiling effects is discussed. Based on the experimental trends, a mechanism is proposed that identifies the parameters that lead to this phenomenon. Secondary boiling effects refer to a distinct decrease in the wall superheat temperature near the critical heat flux due to a significant increase in the heat transfer coefficient. Recent pool boiling heat transfer experiments using femtosecond laser processed Inconel, stainless steel, and copper multiscale surfaces consistently displayed secondary boiling effects, which were found to be a result of both temperature drop along the microstructures and nucleation characteristic length scales. The temperature drop is a function of microstructure height and thermal conductivity. An increased microstructure height and a decreased thermal conductivity result in a significant temperature drop along the microstructures. This temperature drop becomes more pronounced at higher heat fluxes and along with the right nucleation characteristic length scales results in a change of the boiling dynamics. Nucleation spreads from the bottom of the microstructure valleys to the top of the microstructures, resulting in a decreased surface superheat with an increasing heat flux. This decrease in the wall superheat at higher heat fluxes is reflected by a "hook back" of the traditional boiling curve and is thus referred to as secondary boiling effects. In addition, a boiling hysteresis during increasing and decreasing heat flux develops due to the secondary boiling effects. This hysteresis further validates the existence of secondary boiling effects.

  7. Low Temperature Regenerators for Zero Boil-Off Liquid Hydrogen Pulse Tube Cryocoolers

    NASA Technical Reports Server (NTRS)

    Salerno, Louis J.; Kashani, Ali; Helvensteijn, Ben; Kittel, Peter; Arnoldm James O. (Technical Monitor)

    2002-01-01

    Recently, a great deal of attention has been focused on zero boil-off (ZBO) propellant storage as a means of minimizing the launch mass required for long-term exploration missions. A key component of ZBO systems is the cooler. Pulse tube coolers offer the advantage of zero moving mass at the cold head, and recent advances in lightweight, high efficiency cooler technology have paved the way for reliable liquid oxygen (LOx) temperature coolers to be developed which are suitable for flight ZBO systems. Liquid hydrogen (LH2) systems, however, are another matter. For ZBO liquid hydrogen systems, cooling powers of 1-5 watts are required at 20 K. The final development from tier for these coolers is to achieve high efficiency and reliability at lower operating temperatures. Most of the life-limiting issues of flight Stirling and pulse tube coolers are associated with contamination, drive mechanisms, and drive electronics. These problems are well in hand in the present generation coolers. The remaining efficiency and reliability issues reside with the low temperature regenerators. This paper will discuss advances to be made in regenerators for pulse tube LH2 ZBO coolers, present some historical background, and discuss recent progress in regenerator technology development using alloys of erbium.

  8. Remote temperature-set-point controller

    DOEpatents

    Burke, W.F.; Winiecki, A.L.

    1984-10-17

    An instrument is described for carrying out mechanical strain tests on metallic samples with the addition of means for varying the temperature with strain. The instrument includes opposing arms and associated equipment for holding a sample and varying the mechanical strain on the sample through a plurality of cycles of increasing and decreasing strain within predetermined limits, circuitry for producing an output signal representative of the strain during the tests, apparatus including a a set point and a coil about the sample for providing a controlled temperature in the sample, and circuitry interconnected between the strain output signal and set point for varying the temperature of the sample linearly with strain during the tests.

  9. Determination of the Latent Heats and Triple Point of Perfluorocyclobutane

    ERIC Educational Resources Information Center

    Briggs, A. G.; Strachan, A. N.

    1977-01-01

    Proposes the use of Perfluorocyclobutane in physical chemistry courses to conduct experiments on latent heat, triple point temperatures and pressures, boiling points, and entropy of vaporization. (SL)

  10. Sediment microbial communities in Great Boiling Spring are controlled by temperature and distinct from water communities

    PubMed Central

    Cole, Jessica K; Peacock, Joseph P; Dodsworth, Jeremy A; Williams, Amanda J; Thompson, Daniel B; Dong, Hailiang; Wu, Geng; Hedlund, Brian P

    2013-01-01

    Great Boiling Spring is a large, circumneutral, geothermal spring in the US Great Basin. Twelve samples were collected from water and four different sediment sites on four different dates. Microbial community composition and diversity were assessed by PCR amplification of a portion of the small subunit rRNA gene using a universal primer set followed by pyrosequencing of the V8 region. Analysis of 164 178 quality-filtered pyrotags clearly distinguished sediment and water microbial communities. Water communities were extremely uneven and dominated by the bacterium Thermocrinis. Sediment microbial communities grouped according to temperature and sampling location, with a strong, negative, linear relationship between temperature and richness at all taxonomic levels. Two sediment locations, Site A (87–80 °C) and Site B (79 °C), were predominantly composed of single phylotypes of the bacterial lineage GAL35 (p̂=36.1%), Aeropyrum (p̂=16.6%), the archaeal lineage pSL4 (p̂=15.9%), the archaeal lineage NAG1 (p̂=10.6%) and Thermocrinis (p̂=7.6%). The ammonia-oxidizing archaeon ‘Candidatus Nitrosocaldus' was relatively abundant in all sediment samples <82 °C (p̂=9.51%), delineating the upper temperature limit for chemolithotrophic ammonia oxidation in this spring. This study underscores the distinctness of water and sediment communities in GBS and the importance of temperature in driving microbial diversity, composition and, ultimately, the functioning of biogeochemical cycles. PMID:23235293

  11. Further Analysis of Boiling Points of Small Molecules, CH[subscript w]F[subscript x]Cl[subscript y]Br[subscript z

    ERIC Educational Resources Information Center

    Beauchamp, Guy

    2005-01-01

    A study to present specific hypothesis that satisfactorily explain the boiling point of a number of molecules, CH[subscript w]F[subscript x]Cl[subscript y]Br[subscript z] having similar structure, and then analyze the model with the help of multiple linear regression (MLR), a data analysis tool. The MLR analysis was useful in selecting the

  12. Investigating the effect of solvent boiling temperature on the active layer morphology of diffusive bilayer solar cells

    NASA Astrophysics Data System (ADS)

    Vohra, Varun; Dörling, Bernhard; Higashimine, Koichi; Murata, Hideyuki

    2016-01-01

    Using chlorobenzene as a base solvent for the deposition of the poly(3-hexylthiophene-2,5-diyl) (P3HT) layer in P3HT:phenyl-C61-butyric acid methyl ester diffusive bilayer solar cells, we investigate the effect of adding of small amounts of high-boiling-point solvents with similar chemical structures on the resulting active layer morphologies. The results demonstrate that the crystallinity of the P3HT films as well as the vertical donor-acceptor gradient in the active layer can be tuned by this approach. The use of high-boiling-point solvents improved all photovoltaic parameters and resulted in a 32% increase in power conversion efficiency.

  13. Enzymatic synthesis of sorbitan esters using a low-boiling-point azeotrope as a reaction solvent.

    PubMed

    Sarney, D B; Barnard, M J; Virto, M; Vulfson, E N

    1997-05-20

    Sorbitan esters were prepared by controlled dehydration of sorbitol followed by lipase-catalyzed esterification of the resulting "sorbitan." The reaction was carried out in azeotropic mixtures of tert-butanol/n-hexane. A partial phase diagram to determine the temperature required for the distillation of the azeotrope at a given ratio of the solvents was constructed. The effect of varying concentrations of the two solvents on the rate of esterification and the monoester/diester ratio of the final product was investigated in detail. (c) 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 54: 351-356, 1997. PMID:18634102

  14. Determination of boiling point of petrochemicals by gas chromatography-mass spectrometry and multivariate regression analysis of structural activity relationship.

    PubMed

    Fakayode, Sayo O; Mitchell, Breanna S; Pollard, David A

    2014-08-01

    Accurate understanding of analyte boiling points (BP) is of critical importance in gas chromatographic (GC) separation and crude oil refinery operation in petrochemical industries. This study reported the first combined use of GC separation and partial-least-square (PLS1) multivariate regression analysis of petrochemical structural activity relationship (SAR) for accurate BP determination of two commercially available (D3710 and MA VHP) calibration gas mix samples. The results of the BP determination using PLS1 multivariate regression were further compared with the results of traditional simulated distillation method of BP determination. The developed PLS1 regression was able to correctly predict analytes BP in D3710 and MA VHP calibration gas mix samples, with a root-mean-square-%-relative-error (RMS%RE) of 6.4%, and 10.8% respectively. In contrast, the overall RMS%RE of 32.9% and 40.4%, respectively obtained for BP determination in D3710 and MA VHP using a traditional simulated distillation method were approximately four times larger than the corresponding RMS%RE of BP prediction using MRA, demonstrating the better predictive ability of MRA. The reported method is rapid, robust, and promising, and can be potentially used routinely for fast analysis, pattern recognition, and analyte BP determination in petrochemical industries. PMID:24881546

  15. Highly efficient secondary dewatering of dewatered sewage sludge using low boiling point solvents.

    PubMed

    He, Chao; Chena, Chia-Lung; Xu, Zhirong; Wang, Jing-Yuan

    2014-01-01

    Secondary dewatering of dewatered sludge is imperative to make conventional drying and incineration of sludge more economically feasible. In this study, a secondary dewatering of dewatered sludge with selected solvents (i.e. acetone and ethanol) followed by vacuum filtration and nature drying was investigated to achieve in-depth dewatering. After the entire secondary dewatering process, the sludge was shown to be odourless and the organic matter content was greatly retained. Increased mean particle size of sludge after solvent contact improved solid-liquid separation. With an acetone/sludge ratio of 3:1 (mL:g) in solvent contact and subsequent nature drying at ambient temperature after 24 h, the moisture content of sludge can be reduced to a level less than 20%. It is found that the polysaccharides were mainly precipitated by acetone, whereas the release ratios of protein and DNA were increased significantly as the added acetone volumes were elevated. During nature drying, accumulated evaporation rates of the sludge after solvent contact were 5-6 times higher than original dewatered sludge. Furthermore, sludge after acetone contact had better nature drying performance than ethanol. The two-stage dewatering involves solvent contact dewatering and solvent enhanced evaporation dewatering. Through selecting an appropriate solvent/sludge ratio as well as economical solvents and minimizing the solvent loss in a closed-pilot system, this dewatering process can be competitive in industrial applications. Therefore, this solvent-aided secondary dewatering is an energy-saving technology for effective in-depth dewatering of dewatered sludge and subsequent sludge utilization. PMID:24600846

  16. Boiling radial flow in fractures of varying wall porosity

    SciTech Connect

    Barnitt, Robb Allan

    2000-06-01

    The focus of this report is the coupling of conductive heat transfer and boiling convective heat transfer, with boiling flow in a rock fracture. A series of experiments observed differences in boiling regimes and behavior, and attempted to quantify a boiling convection coefficient. The experimental study involved boiling radial flow in a simulated fracture, bounded by a variety of materials. Nonporous and impermeable aluminum, highly porous and permeable Berea sandstone, and minimally porous and permeable graywacke from The Geysers geothermal field. On nonporous surfaces, the heat flux was not strongly coupled to injection rate into the fracture. However, for porous surfaces, heat flux, and associated values of excess temperature and a boiling convection coefficient exhibited variation with injection rate. Nucleation was shown to occur not upon the visible surface of porous materials, but a distance below the surface, within the matrix. The depth of boiling was a function of injection rate, thermal power supplied to the fracture, and the porosity and permeability of the rock. Although matrix boiling beyond fracture wall may apply only to a finite radius around the point of injection, higher values of heat flux and a boiling convection coefficient may be realized with boiling in a porous, rather than nonporous surface bounded fracture.

  17. Tunable integration of absorption-membrane-adsorption for efficiently separating low boiling gas mixtures near normal temperature.

    PubMed

    Liu, Huang; Pan, Yong; Liu, Bei; Sun, Changyu; Guo, Ping; Gao, Xueteng; Yang, Lanying; Ma, Qinglan; Chen, Guangjin

    2016-01-01

    Separation of low boiling gas mixtures is widely concerned in process industries. Now their separations heavily rely upon energy-intensive cryogenic processes. Here, we report a pseudo-absorption process for separating low boiling gas mixtures near normal temperature. In this process, absorption-membrane-adsorption is integrated by suspending suitable porous ZIF material in suitable solvent and forming selectively permeable liquid membrane around ZIF particles. Green solvents like water and glycol were used to form ZIF-8 slurry and tune the permeability of liquid membrane surrounding ZIF-8 particles. We found glycol molecules form tighter membrane while water molecules form looser membrane because of the hydrophobicity of ZIF-8. When using mixing solvents composed of glycol and water, the permeability of liquid membrane becomes tunable. It is shown that ZIF-8/water slurry always manifests remarkable higher separation selectivity than solid ZIF-8 and it could be tuned to further enhance the capture of light hydrocarbons by adding suitable quantity of glycol to water. Because of its lower viscosity and higher sorption/desorption rate, tunable ZIF-8/water-glycol slurry could be readily used as liquid absorbent to separate different kinds of low boiling gas mixtures by applying a multistage separation process in one traditional absorption tower, especially for the capture of light hydrocarbons. PMID:26892255

  18. Tunable integration of absorption-membrane-adsorption for efficiently separating low boiling gas mixtures near normal temperature

    NASA Astrophysics Data System (ADS)

    Liu, Huang; Pan, Yong; Liu, Bei; Sun, Changyu; Guo, Ping; Gao, Xueteng; Yang, Lanying; Ma, Qinglan; Chen, Guangjin

    2016-02-01

    Separation of low boiling gas mixtures is widely concerned in process industries. Now their separations heavily rely upon energy-intensive cryogenic processes. Here, we report a pseudo-absorption process for separating low boiling gas mixtures near normal temperature. In this process, absorption-membrane-adsorption is integrated by suspending suitable porous ZIF material in suitable solvent and forming selectively permeable liquid membrane around ZIF particles. Green solvents like water and glycol were used to form ZIF-8 slurry and tune the permeability of liquid membrane surrounding ZIF-8 particles. We found glycol molecules form tighter membrane while water molecules form looser membrane because of the hydrophobicity of ZIF-8. When using mixing solvents composed of glycol and water, the permeability of liquid membrane becomes tunable. It is shown that ZIF-8/water slurry always manifests remarkable higher separation selectivity than solid ZIF-8 and it could be tuned to further enhance the capture of light hydrocarbons by adding suitable quantity of glycol to water. Because of its lower viscosity and higher sorption/desorption rate, tunable ZIF-8/water-glycol slurry could be readily used as liquid absorbent to separate different kinds of low boiling gas mixtures by applying a multistage separation process in one traditional absorption tower, especially for the capture of light hydrocarbons.

  19. Tunable integration of absorption-membrane-adsorption for efficiently separating low boiling gas mixtures near normal temperature

    PubMed Central

    Liu, Huang; Pan, Yong; Liu, Bei; Sun, Changyu; Guo, Ping; Gao, Xueteng; Yang, Lanying; Ma, Qinglan; Chen, Guangjin

    2016-01-01

    Separation of low boiling gas mixtures is widely concerned in process industries. Now their separations heavily rely upon energy-intensive cryogenic processes. Here, we report a pseudo-absorption process for separating low boiling gas mixtures near normal temperature. In this process, absorption-membrane-adsorption is integrated by suspending suitable porous ZIF material in suitable solvent and forming selectively permeable liquid membrane around ZIF particles. Green solvents like water and glycol were used to form ZIF-8 slurry and tune the permeability of liquid membrane surrounding ZIF-8 particles. We found glycol molecules form tighter membrane while water molecules form looser membrane because of the hydrophobicity of ZIF-8. When using mixing solvents composed of glycol and water, the permeability of liquid membrane becomes tunable. It is shown that ZIF-8/water slurry always manifests remarkable higher separation selectivity than solid ZIF-8 and it could be tuned to further enhance the capture of light hydrocarbons by adding suitable quantity of glycol to water. Because of its lower viscosity and higher sorption/desorption rate, tunable ZIF-8/water-glycol slurry could be readily used as liquid absorbent to separate different kinds of low boiling gas mixtures by applying a multistage separation process in one traditional absorption tower, especially for the capture of light hydrocarbons. PMID:26892255

  20. Application of high-speed digital holographic interferometry for the analysis of temperature distributions and velocity fields in subcooled flow boiling

    NASA Astrophysics Data System (ADS)

    Bloch, Gregor; Kuczaty, Julian; Sattelmayer, Thomas

    2014-02-01

    Holographic interferometry can be used to visualize density fields in fluids, and thus give insight into temperature distributions in flows. A fully digital reconstruction technique for holographic interferograms is presented that allows to create high-speed interferometric recordings and gives time-resolved information about heat transfer processes. The technique can also be used for a sequential (image to image) analysis of the recordings, which offers higher sensitivity and fewer errors due to optical impurities. Experiments are conducted with a vertical flow boiling channel with one heated wall, using a low boiling fluorocarbon as working liquid in regimes of steady-state nucleate boiling at critical heat flux (CHF), steady-state film boiling and CHF transient. Recording frequencies are up to 7,000 fps. The technique is used to analyze boiling processes at different fluid subcoolings with and without added turbulence. The results give enhanced insight into the temperature distributions, effects of different flow inserts and mechanisms of heat transfer in flow boiling at high heat fluxes. Furthermore, a velocimetric application of the technique is presented using cross-correlation for tracing of density gradients both in boiling and unheated flows. This application gives insight to the velocity distributions in the liquid surrounding the vapor layer. The results show good comparison to particle image velocimetry measurements for the same setup.

  1. To boil or not to boil -- A study of bubble embryo dormancy limits

    SciTech Connect

    Martin-Dominguez, I.R.; McDonald, T.W.

    1997-12-31

    In the literature, particularly for refrigerants, experimental studies on the superheat required to initiate nucleate boiling tend to be widely scattered, not only among investigators but even for repeated tests by the same investigator. This study provides an explanation of why this occurs and how to avoid such scatter in future tests. With few exceptions, only re-entrant surface cavities are capable of containing dormant vapor bubble embryos. These dormant embryos are essential to initiate nucleate boiling from a cavity. The temperature (wall superheat) range over which an embryo is stable depends upon the cavity shape, neck size, and the fluid surface tension and thermal properties. Above the upper wall-superheat limit, nucleate boiling occurs. Below the lower limit, the embryo will quench (vanish) and cannot be reactivated by increasing the wall superheat. This study makes the following points, for a given cavity shape, fluid, and pressure (1) The larger the cavity neck radius, the smaller the wall-superheat range over which an embryo can exist. (2) Upon cooling any surface, the boiling cavity with the smallest neck radius will be the first to stop boiling but will require the greatest reduction in wall superheat to quench its embryo. (3) Each site that retains a (dormant) vapor embryo will resume boiling at the same wall-superheat at which it ceased boiling. (4) Small cavities can have a shape such that their vapor embryos will always exist, regardless of the wall temperature. Boiling can always be reinitiated from them. (5) Any wall subject to boiling has a memory. The greater the past wall-subcooling, the greater will be the wall-superheat required to initiate boiling. (6) The wall memory can be erased with sufficient wall-superheat and the presence of vapor.

  2. Theory of Subcooled Boiling

    SciTech Connect

    Bankoff, S. G.; Davis, S. H.

    2002-09-15

    Subcooled boiling refers to boiling from a heated solid surface when the bulk liquid is below the saturation temperature. Particularly, when there is a bulk liquid flow past the surface, the heat fluxes thus sustained can be very large, in fact, subcooled boiling is the most efficient mode of cooling high-heat flux surfaces known, and as such is useful for cooling densely-packed computer microchips, as well as other applications, as in the heat treatment of metals. We have studied several aspects of subcooled boiling from a fundamental aspect, leading, among other things, to a resolution of a long-standing question as to the dominant mechanism of subcooled boiling: vapor transport through an ultrathin layer liquid underneath the growing bubble or stirring of the liquid surrounding the growing-and collapsing bubble.

  3. 46 CFR 154.709 - Cargo boil-off as fuel: Gas detection equipment.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... methane concentration reaches 3 percent by volume. (b) The number and arrangement of gas sampling points... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo boil-off as fuel: Gas detection equipment. 154.709... Equipment Cargo Pressure and Temperature Control § 154.709 Cargo boil-off as fuel: Gas detection...

  4. Exfoliating and Dispersing Few-Layered Graphene in Low-Boiling-Point Organic Solvents towards Solution-Processed Optoelectronic Device Applications.

    PubMed

    Zhang, Lu; Miao, Zhongshuo; Hao, Zhen; Liu, Jun

    2016-05-01

    With normal organic surfactants, graphene can only be dispersed in water and cannot be dispersed in low-boiling-point organic solvents, which hampers its application in solution-processed organic optoelectronic devices. Herein, we report the exfoliation of graphite into graphene in low-boiling-point organic solvents, for example, methanol and acetone, by using edge-carboxylated graphene quantum dots (ECGQD) as the surfactant. The great capability of ECGQD for graphene dispersion is due to its ultralarge π-conjugated unit that allows tight adhesion on the graphene surface through strong π-π interactions, its edge-carboxylated structure that diminishes the steric effects of the oxygen-containing functional groups on the basal plane of ECGQD, and its abundance of carboxylic acid groups for solubility. The graphene dispersion in methanol enables the application of graphene:ECGQD as a cathode interlayer in polymer solar cells (PSCs). Moreover, the PSC device performance of graphene:ECGQD is better than that of Ca, the state-of-the-art cathode interlayer material. PMID:26957045

  5. Pyrosequencing Reveals High-Temperature Cellulolytic Microbial Consortia in Great Boiling Spring after In Situ Lignocellulose Enrichment

    PubMed Central

    Peacock, Joseph P.; Cole, Jessica K.; Murugapiran, Senthil K.; Dodsworth, Jeremy A.; Fisher, Jenny C.; Moser, Duane P.; Hedlund, Brian P.

    2013-01-01

    To characterize high-temperature cellulolytic microbial communities, two lignocellulosic substrates, ammonia fiber-explosion-treated corn stover and aspen shavings, were incubated at average temperatures of 77 and 85°C in the sediment and water column of Great Boiling Spring, Nevada. Comparison of 109,941 quality-filtered 16S rRNA gene pyrosequences (pyrotags) from eight enrichments to 37,057 quality-filtered pyrotags from corresponding natural samples revealed distinct enriched communities dominated by phylotypes related to cellulolytic and hemicellulolytic Thermotoga and Dictyoglomus, cellulolytic and sugar-fermenting Desulfurococcales, and sugar-fermenting and hydrogenotrophic Archaeoglobales. Minor enriched populations included close relatives of hydrogenotrophic Thermodesulfobacteria, the candidate bacterial phylum OP9, and candidate archaeal groups C2 and DHVE3. Enrichment temperature was the major factor influencing community composition, with a negative correlation between temperature and richness, followed by lignocellulosic substrate composition. This study establishes the importance of these groups in the natural degradation of lignocellulose at high temperatures and suggests that a substantial portion of the diversity of thermophiles contributing to consortial cellulolysis may be contained within lineages that have representatives in pure culture. PMID:23555835

  6. Description and validation of the Little correlation for boiling zeotropic mixtures in horizontal tubes from cryogenic to room temperature

    NASA Astrophysics Data System (ADS)

    Barraza, R.; Nellis, G.; Klein, S.; Reindl, D.

    2015-12-01

    The use of mixed gas working fluids has become common in Joule-Thomson (JT) type cryocoolers for a variety of applications operating in temperatures ranging from 80 to 230 K. The thermal efficiency of mixed gas JT cryocoolers is dependent on the optimization of the gas mixture composition. Most optimization methodologies focus on thermodynamic criteria of the cycle because there are very little data or theory currently available regarding the heat transfer coefficients associated with these multi-component mixtures in two-phase regimes at cryogenic temperatures. A generally accepted correlation to predict the local heat transfer coefficient (htc) for mixtures during the boiling process does not exist. Little [1] proposed a correlation to be used on horizontal tubes that shows good agreement with Nellis et al. [2] experimental data of nitrogen-hydrocarbon mixtures. However, it is not clearly shown how the correlation is obtained and how it should be applied. This paper provides a more complete description of the Little correlation and also expands its validation using the experimental data provided by Barraza [3]. The new experimental data include measurements of the local heat transfer coefficient for mixtures comprising 2 component (binary) up to 5 components in the temperature range between 100 K and room temperature. These mixtures are formed from nitrogen-hydrocarbon and argon-fluorocarbon mixtures and evaporate in horizontal tubes with diameters from 0.5 to 3.0 mm for different heat flux, mass flux, evaporating pressure, and composition.

  7. Effects of storage temperature on tyramine production by Enterococcus faecalis R612Z1 in water-boiled salted ducks.

    PubMed

    Liu, Fang; Du, Lihui; Wu, Haihong; Wang, Daoying; Zhu, Yongzhi; Geng, Zhiming; Zhang, Muhan; Xu, Weimin

    2014-10-01

    Tyramine production by Enterococcus faecalis R612Z1 in water-boiled salted ducks was evaluated during storage at different temperatures. The results showed that E. faecalis R612Z1 could produce tyramine in meat samples when the storage temperature was no less than 4°C. The E. faecalis R612Z1 counts of the meat samples reached 10(8) CFU/g on day 7 at 4°C and on day 4 at 10°C. However, the tyramine content of the meat samples stored at 10°C increased to 23.73 μg/g (on day 10), which was greater than the level in the samples stored at 4°C (7.56 μg/g). Reverse transcription quantitative PCR detection of the expression level of the tyrDC gene in E. faecalis R612Z1 in the meat samples revealed no significant changes at different storage temperatures. Thus, the changes in tyramine production of E. faecalis R612Z1 may be due to the different enzymatic activities at different storage temperatures. PMID:25285502

  8. Boiling from small cylinders.

    NASA Technical Reports Server (NTRS)

    Bakhru, N.; Lienhard, J. H.

    1972-01-01

    Heat transfer is observed as a function of temperature on small horizontal wires in water and four organic liquids. When the wire radius is sufficiently small, the hydrodynamic transitions in the boiling curve disappear and the curve becomes monotonic. Three modes of heat removal are identified for the monotonic curve and described analytically: a natural convection mode, a mixed film boiling and natural convection mode, and a pure film boiling mode. Nucleate boiling does not occur on the small wires. The study was motivated by an interest in predicting the behavior of large heaters at low gravity. The application of the present results to such circumstances is therefore discussed. It is proposed that the peak and minimum heat fluxes will vanish at low gravity as well as on small wires.

  9. Optimizations of packed sorbent and inlet temperature for large volume-direct aqueous injection-gas chromatography to determine high boiling volatile organic compounds in water.

    PubMed

    Yu, Bofan; Song, Yonghui; Han, Lu; Yu, Huibin; Liu, Yang; Liu, Hongliang

    2014-08-22

    For the expanded application area, fast trace analysis of certain high boiling point (i.e., 150-250 °C) volatile organic compounds (HVOCs) in water, a large volume-direct aqueous injection-gas chromatography (LV-DAI-GC) method was optimized for the following parameters: packed sorbent for sample on-line pretreatment, inlet temperature and detectors configuration. Using the composite packed sorbent self-prepared with lithium chloride and a type of diatomite, the method enabled safe injection of an approximately 50-100 μL sample at an inlet temperature of 150 °C in the splitless mode and separated HVOCs from water matrix in 2 min. Coupled with a flame ionization detector (FID), an electron capture detector (ECD) and a flame photometric detector (FPD), the method could simultaneously quantify 27 HVOCs that belong to seven subclasses (i.e., halogenated aliphatic hydrocarbons, chlorobenzenes, nitrobenzenes, anilines, phenols, polycyclic aromatic hydrocarbons and organic sulfides) in 26 min. Injecting a 50 μL sample without any enrichment step, such as cryotrap focusing, the limits of quantification (LOQs) for the 27 HVOCs was 0.01-3 μg/L. Replicate analyses of the 27 HVOCs spiked source and river water samples exhibited good precision (relative standard deviations ≤ 11.3%) and accuracy (relative errors ≤ 17.6%). The optimized LV-DAI-GC was robust and applicable for fast determination and automated continuous monitoring of HVOCs in surface water. PMID:24997514

  10. Thermodynamic Temperatures of High-Temperature Fixed Points: Uncertainties Due to Temperature Drop and Emissivity

    NASA Astrophysics Data System (ADS)

    Castro, P.; Machin, G.; Bloembergen, P.; Lowe, D.; Whittam, A.

    2014-07-01

    This study forms part of the European Metrology Research Programme project implementing the New Kelvin to assign thermodynamic temperatures to a selected set of high-temperature fixed points (HTFPs), Cu, Co-C, Pt-C, and Re-C. A realistic thermal model of these HTFPs, developed in finite volume software ANSYS FLUENT, was constructed to quantify the uncertainty associated with the temperature drop across the back wall of the cell. In addition, the widely applied software package, STEEP3 was used to investigate the influence of cell emissivity. The temperature drop, , relates to the temperature difference due to the net loss of heat from the aperture of the cavity between the back wall of the cavity, viewed by the thermometer, defining the radiance temperature, and the solid-liquid interface of the alloy, defining the transition temperature of the HTFP. The actual value of can be used either as a correction (with associated uncertainty) to thermodynamic temperature evaluations of HTFPs, or as an uncertainty contribution to the overall estimated uncertainty. In addition, the effect of a range of furnace temperature profiles on the temperature drop was calculated and found to be negligible for Cu, Co-C, and Pt-C and small only for Re-C. The effective isothermal emissivity is calculated over the wavelength range from 450 nm to 850 nm for different assumed values of surface emissivity. Even when furnace temperature profiles are taken into account, the estimated emissivities change only slightly from the effective isothermal emissivity of the bare cell. These emissivity calculations are used to estimate the uncertainty in the temperature assignment due to the uncertainty in the emissivity of the blackbody.

  11. The boiling Twente Taylor-Couette (BTTC) facility: Temperature controlled turbulent flow between independently rotating, coaxial cylinders

    NASA Astrophysics Data System (ADS)

    Huisman, Sander G.; van der Veen, Roeland C. A.; Bruggert, Gert-Wim H.; Lohse, Detlef; Sun, Chao

    2015-06-01

    A new Taylor-Couette system has been designed and constructed with precise temperature control. Two concentric independently rotating cylinders are able to rotate at maximum rates of fi = ± 20 Hz for the inner cylinder and fo = ± 10 Hz for the outer cylinder. The inner cylinder has an outside radius of ri = 75 mm, and the outer cylinder has an inside radius of ro = 105 mm, resulting in a gap of d = 30 mm. The height of the gap is L = 549 mm, giving a volume of V = 9.3 L. The geometric parameters are η = ri/ro = 0.714 and Γ = L/d = 18.3. With water as working fluid at room temperature, the Reynolds numbers that can be achieved are Rei = ωiri(ro - ri)/ν = 2.8 × 105 and Reo = ωoro(ro - ri)/ν = 2 × 105 or a combined Reynolds number of up to Re = (ωiri - ωoro)(ro - ri)/ν = 4.8 × 105. If the working fluid is changed to the fluorinated liquid FC-3284 with kinematic viscosity 0.42 cSt, the combined Reynolds number can reach Re = 1.1 × 106. The apparatus features precise temperature control of the outer and inner cylinders separately and is fully optically accessible from the side and top. The new facility offers the possibility to accurately study the process of boiling inside a turbulent flow and its effect on the flow.

  12. The boiling Twente Taylor-Couette (BTTC) facility: Temperature controlled turbulent flow between independently rotating, coaxial cylinders.

    PubMed

    Huisman, Sander G; van der Veen, Roeland C A; Bruggert, Gert-Wim H; Lohse, Detlef; Sun, Chao

    2015-06-01

    A new Taylor-Couette system has been designed and constructed with precise temperature control. Two concentric independently rotating cylinders are able to rotate at maximum rates of f(i) = ± 20 Hz for the inner cylinder and f(o) = ± 10 Hz for the outer cylinder. The inner cylinder has an outside radius of r(i) = 75 mm, and the outer cylinder has an inside radius of r(o) = 105 mm, resulting in a gap of d = 30 mm. The height of the gap is L = 549 mm, giving a volume of V = 9.3 L. The geometric parameters are η = r(i)/r(o) = 0.714 and Γ = L/d = 18.3. With water as working fluid at room temperature, the Reynolds numbers that can be achieved are Re(i) = ω(i)r(i)(r(o) - r(i))/ν = 2.8 × 10(5) and Re(o) = ω(o)r(o)(r(o) - r(i))/ν = 2 × 10(5) or a combined Reynolds number of up to Re = (ω(i)r(i) - ω(o)r(o))(r(o) - r(i))/ν = 4.8 × 10(5). If the working fluid is changed to the fluorinated liquid FC-3284 with kinematic viscosity 0.42 cSt, the combined Reynolds number can reach Re = 1.1 × 10(6). The apparatus features precise temperature control of the outer and inner cylinders separately and is fully optically accessible from the side and top. The new facility offers the possibility to accurately study the process of boiling inside a turbulent flow and its effect on the flow. PMID:26133874

  13. Electron temperature difference between the o-point and x-point of a magnetic island

    SciTech Connect

    Yang Jinhong; Zhu Sizheng; Yu Qingquan; Zhuang, G.

    2009-09-15

    The electron temperature difference between the o-point and the x-point of a magnetic island is studied numerically by solving the two-dimensional energy transport equation. It is found that, even without a localized radio-frequency heating at the island's o-point, there is usually a temperature difference between these two points. This difference depends on the radial profile of the heating power deposition, the ratio between the parallel and the perpendicular heat conductivity and the island width, and it takes a minimum when the island width is about twice the local heat diffusion layer width. The effect of the temperature difference on the island growth is further studied, and the peaked heating power density profile at magnetic axis is found be destabilizing.

  14. Subcooled forced convection boiling of trichlorotrifluoroethane

    NASA Technical Reports Server (NTRS)

    Dougall, R. S.; Panian, D. J.

    1972-01-01

    Experimental heat-transfer data were obtained for the forced-convection boiling of trichlorotrifluoroethane (R-113 or Freon-113) in a vertical annular test annular test section. The 97 data points obtained covered heat transfer by forced convection, local boiling, and fully-developed boiling. Correlating methods were obtained which accurately predicted the heat flux as a function of wall superheat (boiling curve) over the range of parameters studied.

  15. Estimating surface temperature in forced convection nucleate boiling: A simplified method

    NASA Technical Reports Server (NTRS)

    Hendricks, R. C.; Papell, S. S.

    1977-01-01

    During a test program to investigate low-cycle thermal fatigue, 21 of 22 cylindrical test sections of a cylindrical rocket thrust chamber were thermally cycled to failure. Cylinder liners were fabricated from OFHC copper, Amzirc, and NARloy-Z. The cylinders were fabricated by milling cooling channels into the liner and closing out the backside with electrodeposited copper. The tests were conducted at a chamber pressure of 4.14 MN/sq m (600 psia) and an oxidant-fuel ratio of 6.0 using hydrogen-oxygen as propellants. The average throat heat flux was 54 MW/sq m (33 Btu/sq in./sec). All of the failures were characterized by a thinning of the cooling channel wall and eventual failure by tensile rupture. The 1/2-hard Amzirc material showed little improvement in cyclic life when compared with OFHC copper; while the NARloy-Z and aged Amzirc materials had the best cyclic life characteristics. One OFHC copper cylinder was thermall cycled 2044 times at a steady-state hot-gas-side wall temperature of 514 K (925 R) without failing.

  16. Characteristics of Transient Boiling Heat Transfer

    SciTech Connect

    Liu, Wei; Monde, Masanori; Mitsutake, Y.

    2002-07-01

    In this paper, one dimensional inverse heat conduction solution is used for a measurement of pool boiling curve. The experiments are performed under atmospheric pressure for copper, brass, carbon steel and gold. Boiling curves, including unsteady transition boiling region, are found can be traced fairly well from a simple experiment system by solving inverse heat conduction solution. Boiling curves for steady heating and transient heating, for heating process and cooling process are compared. Surface behavior around CHF point, transition boiling and film-boiling regions are observed by using a high-speed camera. The results show the practicability of the inverse heat conduction solution in tracing boiling curve and thereby supply us a new way in boiling heat transfer research. (authors)

  17. Alternative Methods of Blackbody Thermodynamic Temperature Measurement Above Silver Point

    NASA Astrophysics Data System (ADS)

    Prokhorov, A.; Sapritsky, V.; Khlevnoy, B.; Gavrilov, V.

    2015-03-01

    Presently, absolute radiometry is the main method of thermodynamic temperature determination above the silver point. The importance of such measurements has increased, as a large international project is underway aimed at assigning thermodynamic temperatures to high-temperature fixed points (HTFPs). All participants are using filter radiometers calibrated against an absolute cryogenic radiometer which, therefore, will be the basis of the provided thermodynamic temperatures of the fixed points. However, such a unified approach may lead to systematic errors (if any) common to all participants. There are methods, providing an alternative to absolute radiometry, which allow the determination of blackbody thermodynamic temperatures using relative measurements. Alternative methods, even if they have lower accuracy than absolute radiometry, could disclose some possible unrecognized systematic errors, or, on the contrary, could confirm the results obtained using absolute radiometry and increase confidence of the thermodynamic temperature determination. One such method, known as the method of ratios (i.e., double wavelength technique), is based on measuring the ratios of fluxes emitted by a blackbody in separate spectral ranges at two temperatures. This approach has been developed at VNIIOFI, but its realization met serious technical difficulties. Modern sensors with improved sensitivity and stability, extremely reproducible HTFP blackbodies, and significant progress in computational methods and computer performance provide a new chance to realize this approach with sufficient accuracy. Another method is based on comparing the ratio of fluxes measured at two wavelengths for a high-temperature blackbody with that measured for synchrotron radiation. This article overviews possibilities of the alternative methods for determination of blackbody thermodynamic temperatures by means of relative radiometry to attract attention of the thermometry and radiometry communities to the importance of international cooperation for realization of these methods.

  18. Carbon dioxide and R410A flow boiling heat transfer, pressure drop, and flow pattern in horizontal tubes at low temperatures

    NASA Astrophysics Data System (ADS)

    Park, Chang Yong

    Carbon dioxide (CO2) has been seriously considered as an alternate refrigerant for HCFC and HFC fluids, due to the increasing interest of environmentally safe refrigerants in air-conditioning and refrigeration systems. In this study, CO2 flow boiling heat transfer coefficients and pressure drop are measured in macro-scale (6.1 and 3.5 mm) tubes at evaporation temperatures of -15 and -30°C. The measured results show that the nucleate boiling is a main heat transfer mechanism in the 6.1 mm tube and the contribution of convective boiling becomes greater with the decrease of tube diameters and the increase of mass fluxes. The surface roughness of the 6.1 and 3.5 mm tube are presented by SEM and AFM images and surface profiles, and it is shown that the rougher surface of the 6.1 mm tube can affect the flow boiling heat transfer. The CO2 heat transfer coefficients and pressure drop are measured in a mini-scale (0.89 mm) multi-ported tube at the evaporation temperature of -30°C. Also, R410A and R22 flow boiling heat transfer coefficients and pressure drop in a macro-scale (6.1 mm) tube were measured, and they are compared with CO2. This comparison presents that the CO2 flow boiling heat transfer coefficients are higher than R410A and R22 at low vapor qualities, and CO2 pressure drop is significantly lower than R410A and R22. This advantageous characteristic for CO2 could be explained by properties such as surface tension, reduced pressure, and the density ratio of liquid to vapor. The prediction of heat transfer coefficients and pressure drop was performed by general correlations and the calculation results are compared with measured values. Two-phase flow patterns were visualized for CO2 and R410A in the 6 and 3 mm glass tubes, and they are compared with the Weisman et al. and the Wojtan et al. flow pattern maps. The flow pattern maps can determine the flow patterns relatively well, except the transition from intermittent to annular flow.

  19. ENERGY CONSERVATION THROUGH POINT SOURCE RECYCLE WITH HIGH TEMPERATURE HYPERFILTRATION

    EPA Science Inventory

    The report gives results of a study of energy conservation effects of point source recycle with high-temperature hyperfiltration (HF) in the textile industry. (HF and ultrafiltration (UF) are pressure-driven membrane processes which have potential for recycle of water, energy, an...

  20. Complex saddle points in QCD at finite temperature and density

    NASA Astrophysics Data System (ADS)

    Nishimura, Hiromichi; Ogilvie, Michael C.; Pangeni, Kamal

    2014-08-01

    The sign problem in QCD at finite temperature and density leads naturally to the consideration of complex saddle points of the action or effective action. The global symmetry CK of the finite-density action, where C is charge conjugation and K is complex conjugation, constrains the eigenvalues of the Polyakov loop operator P at a saddle point in such a way that the action is real at a saddle point, and net color charge is zero. The values of TrFP and TrFP† at the saddle point are real but not identical, indicating the different free energy cost associated with inserting a heavy quark versus an antiquark into the system. At such complex saddle points, the mass matrix associated with Polyakov loops may have complex eigenvalues, reflecting oscillatory behavior in color-charge densities. We illustrate these properties with a simple model which includes the one-loop contribution of gluons and two flavors of massless quarks moving in a constant Polyakov loop background. Confinement-deconfinement effects are modeled phenomenologically via an added potential term depending on the Polyakov loop eigenvalues. For sufficiently large temperature T and quark chemical potential μ, the results obtained reduce to those of perturbation theory at the complex saddle point. These results may be experimentally relevant for the compressed baryonic matter experiment at FAIR.

  1. Using temperature gradient gas chromatography to determine or predict vapor pressures and linear solvation energy relationship parameters of highly boiling organic compounds.

    PubMed

    Mutelet, F; Rogalski, M

    2003-02-21

    An isothermal chromatographic method allowing determination of sigmabetaH2 and sigmaalphaH2 descriptors of the linear solvation energy relationship (LSER) was tested and results obtained are presented. This method is based on the use of four stationary phases of various polarity. On the other hand, it was demonstrated that the temperature gradient chromatography may be successfully used to determine LSER descriptors. Results of piH2, sigmabetaH2 and log L16 determination are reported. This approach opens new possibilities of precise and rapid determination of LSER descriptors of high boiling compounds using a small number of phases. It was demonstrated that the log L16 descriptor may be used to estimate vapor pressures of high boiling organic compounds with a better accuracy than those usually obtained with chromatographic methods. PMID:12647826

  2. Contrast-enhanced ultrasound imaging and in vivo circulatory kinetics with low-boiling-point nanoscale phase-change perfluorocarbon agents.

    PubMed

    Sheeran, Paul S; Rojas, Juan D; Puett, Connor; Hjelmquist, Jordan; Arena, Christopher B; Dayton, Paul A

    2015-03-01

    Many studies have explored phase-change contrast agents (PCCAs) that can be vaporized by an ultrasonic pulse to form microbubbles for ultrasound imaging and therapy. However, few investigations have been published on the utility and characteristics of PCCAs as contrast agents in vivo. In this study, we examine the properties of low-boiling-point nanoscale PCCAs evaluated in vivo and compare data with those for conventional microbubbles with respect to contrast generation and circulation properties. To do this, we develop a custom pulse sequence to vaporize and image PCCAs using the Verasonics research platform and a clinical array transducer. Results indicate that droplets can produce contrast enhancement similar to that of microbubbles (7.29 to 18.24 dB over baseline, depending on formulation) and can be designed to circulate for as much as 3.3 times longer than microbubbles. This study also reports for the first time the ability to capture contrast washout kinetics of the target organ as a measure of vascular perfusion. PMID:25619781

  3. BOILING REACTORS

    DOEpatents

    Untermyer, S.

    1962-04-10

    A boiling reactor having a reactivity which is reduced by an increase in the volume of vaporized coolant therein is described. In this system unvaporized liquid coolant is extracted from the reactor, heat is extracted therefrom, and it is returned to the reactor as sub-cooled liquid coolant. This reduces a portion of the coolant which includes vaporized coolant within the core assembly thereby enhancing the power output of the assembly and rendering the reactor substantially self-regulating. (AEC)

  4. Spotlighting quantum critical points via quantum correlations at finite temperatures

    SciTech Connect

    Werlang, T.; Ribeiro, G. A. P.; Rigolin, Gustavo

    2011-06-15

    We extend the program initiated by T. Werlang et al. [Phys. Rev. Lett. 105, 095702 (2010)] in several directions. Firstly, we investigate how useful quantum correlations, such as entanglement and quantum discord, are in the detection of critical points of quantum phase transitions when the system is at finite temperatures. For that purpose we study several thermalized spin models in the thermodynamic limit, namely, the XXZ model, the XY model, and the Ising model, all of which with an external magnetic field. We compare the ability of quantum discord, entanglement, and some thermodynamic quantities to spotlight the quantum critical points for several different temperatures. Secondly, for some models we go beyond nearest neighbors and also study the behavior of entanglement and quantum discord for second nearest neighbors around the critical point at finite temperature. Finally, we furnish a more quantitative description of how good all these quantities are in spotlighting critical points of quantum phase transitions at finite T, bridging the gap between experimental data and those theoretical descriptions solely based on the unattainable absolute zero assumption.

  5. Liquid metal boiling inception

    NASA Technical Reports Server (NTRS)

    Sabin, C. M.; Poppendiek, H. F.; Mouritzen, G.; Meckel, P. T.; Cloakey, J. E.

    1972-01-01

    An experimental study of the inception of boiling in potassium in forced convection is reported. The boiler consisted of a 0.19-inch inside diameter, niobium-1% zirconium boiler tube approximately six feet long. Heating was accomplished by direct electrical tube wall conduction. Experiments were performed with both all-liquid fill and two-phase fill startup sequences and with a range of flow rates, saturation temperatures, inert gas levels, and fill liquid temperatures. Superheat of the liquid above the equilibrium saturation temperature was observed in all the experiments. Incipient boiling liquid superheat ranged from a few degrees to several hundred. Comparisons of these data with other data and with several analytical treatments are presented.

  6. Thermodynamic temperature assignment to the point of inflection of the melting curve of high-temperature fixed points.

    PubMed

    Woolliams, E R; Anhalt, K; Ballico, M; Bloembergen, P; Bourson, F; Briaudeau, S; Campos, J; Cox, M G; del Campo, D; Dong, W; Dury, M R; Gavrilov, V; Grigoryeva, I; Hernanz, M L; Jahan, F; Khlevnoy, B; Khromchenko, V; Lowe, D H; Lu, X; Machin, G; Mantilla, J M; Martin, M J; McEvoy, H C; Rougié, B; Sadli, M; Salim, S G R; Sasajima, N; Taubert, D R; Todd, A D W; Van den Bossche, R; van der Ham, E; Wang, T; Whittam, A; Wilthan, B; Woods, D J; Woodward, J T; Yamada, Y; Yamaguchi, Y; Yoon, H W; Yuan, Z

    2016-03-28

    The thermodynamic temperature of the point of inflection of the melting transition of Re-C, Pt-C and Co-C eutectics has been determined to be 2747.84 ± 0.35 K, 2011.43 ± 0.18 K and 1597.39 ± 0.13 K, respectively, and the thermodynamic temperature of the freezing transition of Cu has been determined to be 1357.80 ± 0.08 K, where the ± symbol represents 95% coverage. These results are the best consensus estimates obtained from measurements made using various spectroradiometric primary thermometry techniques by nine different national metrology institutes. The good agreement between the institutes suggests that spectroradiometric thermometry techniques are sufficiently mature (at least in those institutes) to allow the direct realization of thermodynamic temperature above 1234 K (rather than the use of a temperature scale) and that metal-carbon eutectics can be used as high-temperature fixed points for thermodynamic temperature dissemination. The results directly support the developing mise en pratique for the definition of the kelvin to include direct measurement of thermodynamic temperature. PMID:26903099

  7. Microheater Array Boiling Experiment

    NASA Technical Reports Server (NTRS)

    Kim, Jungho; McQuillen, John; Balombin, Joe

    2002-01-01

    By conducting pool boiling tests in microgravity, the effect of buoyancy on the overall boiling process and the relative magnitude of other phenomena can be assessed. Data from KC-135 and sounding rocket experiments indicate little effect of gravity on boiling heat transfer at wall superheats below 25 C, despite vast differences in bubble behavior between gravity levels. In microgravity, a large primary bubble, surrounded by smaller satellite bubbles, moved over the surface, occasionally causing nucleation. Once formed, the primary bubble size remained constant for a given superheat, indicating evaporation at the bubble base is balanced with condensation on the bubble cap. The primary bubble's size increased with wall superheat. Most heaters under the primary bubble had low heat transfer rates, suggesting liquid dryout. Strong Marangoni convection developed in microgravity, forming a 'jet' into the bulk liquid that forced the bubble onto the heater. An experiment is being designed for the. Microgravity Science Glovebox. This experiment uses two 96 element microheater arrays, 2.7 and 7.0 mm in size. These heaters are individually controlled to operate at a constant temperature, measuring local heat fluxes as a function of time and space. Most boiling experiments operate at constant wall heat flux with larger heaters, allowing only time and space-averaged measurements. Each heater is about the bubble departure size in normal gravity, but significantly smaller than the bubble departure size in reduced gravity.

  8. High temperature antenna pointing mechanism for BepiColombo mission

    NASA Astrophysics Data System (ADS)

    Mürer, Johan A.; Harper, Richard; Anderson, Mike

    2005-07-01

    This paper describes the two axis Antenna Pointing Mechanism (APM) with dual frequency (X-Ka bands) Rotary Joint (RJ) developed by Kongsberg Defence and Aerospace and BAE Systems, in the frame of the ESA BepiColombo mission to the planet Mercury. The extreme environmental conditions induced by Mercury's proximity to the Sun (up to 14.500 W/m2 direct solar fluxes, up to 5000 W/m2 infrared flux and up to 1200 W/m2 albedo shine form the planet surface), have dictated the need for a specific high temperature development of the pointing mechanism and of its integrated RF Rotary Joint. Global thermal analysis of the antenna predicts qualification temperature for the elevation stage APM between 250°C and 295°C. In addition, the mechanism shall survive extreme cold temperatures during the interplanetary cruise phase. Beside the harsh environment, the stringent pointing accuracy required by the antenna high frequency operations, and the extreme dimensional stability demanded by a radio science experiment (which is using the antenna for range and range rate measurements), have introduced additional, specific challenges to the mechanism design. Innovative solutions have been deemed necessary at system architecture level, in the design of the mechanisms critical areas and in the selection of high temperature compatible materials and processes. The very high working temperature of the mechanism ruled out use of aluminium alloys, which is replaced by Titanium alloy and stainless steels. Special heat treatments of the steel are applied for minimum loss of hardness. The structures are optimised for minimum mass. To handle thermal stresses and distortion, a very compact design of the APM was performed integrating the bearings, position sensor and drive chain within minimum structural length. The Rotary Joint is a unique design tailored to the APM using a common main bearing support. Special manufacturing processes have been tested and applied for manufacture of the very compact RJ being the first of its kind (dual X-Ka band) in European space development. The twin channels are arranged concentrically, permitting continuous 360° rotation. Maximum use of waveguide has been made to minimise the loss in the Ka-band frequency channel and this leads to an unconventional design of the X-band channel. A specific effort and extensive test program at ESTL in the UK have been put in place to identify suitable high temperature solutions for the RJ and APM bearings lubrication. The high temperature demands the use of a dry lubrication system. High working loads due to thermal stresses puts extra challenge to the life duration of the dry film lubrication. Lead lubrication was initially the preferred concept, but has later in the program been substituted by MoS2 film. A design life of 20,000 cycles at 250°C and elevated load has been demonstrated for the bearings with MoS2. Special attention has been paid to the materials in the stepper motor using high temperature solder material and MoS2 dry lubrication in the bearings and gear train. The APM is designed for use of a high accuracy inductive based position sensor with remote signal and amplifier electronics. Electrical signal transfer is via a high temperature Twist Capsule. The activity has included the design, manufacturing and testing in a respresentative environment of a breadboard model of the APM and of its integrated radio frequency RJ. The breadboard does not include a position sensor or the Twist Capsule. The breadboard tests will include functional performance tests in air, vibration tests and thermal vacuum. The thermal vacuum test will include RF testing at high temperature combined with APM pointing performance.

  9. Dissemination of thermodynamic temperature above the freezing point of silver.

    PubMed

    Sadli, M; Machin, G; Anhalt, K; Bourson, F; Briaudeau, S; del Campo, D; Diril, A; Kozlova, O; Lowe, D H; Mantilla Amor, J M; Martin, M J; McEvoy, H C; Ojanen-Saloranta, M; Pehlivan, Ö; Rougié, B; Salim, S G R

    2016-03-28

    The mise-en-pratique for the definition of the kelvin at high temperatures will formally allow dissemination of thermodynamic temperature either directly or mediated through high-temperature fixed points (HTFPs). In this paper, these two distinct dissemination methods are evaluated, namely source-based and detector-based. This was achieved by performing two distinct dissemination trials: one based on HTFPs, the other based on absolutely calibrated radiation thermometers or filter radiometers. These trials involved six national metrology institutes in Europe in the frame of the European Metrology Research Programme joint project 'Implementing the new kelvin' (InK). The results have shown that both dissemination routes are possible, with similar standard uncertainties of 1-2 K, over the range 1273-2773 K, showing that, depending on the facilities available in the laboratory, it will soon be possible to disseminate thermodynamic temperatures above 1273 K to users by either of the two methods with uncertainties comparable to the current temperature scale. PMID:26903097

  10. Finite-temperature critical point of a glass transition

    PubMed Central

    Elmatad, Yael S.; Jack, Robert L.; Chandler, David; Garrahan, Juan P.

    2010-01-01

    We generalize the simplest kinetically constrained model of a glass-forming liquid by softening kinetic constraints, allowing them to be violated with a small rate. We demonstrate that this model supports a first-order dynamical (space–time) phase transition between active (fluid) and inactive (glass) phases. The first-order phase boundary in this softened model ends in a finite-temperature dynamical critical point, which may be present in natural systems. In this case, the glass phase has a very large but finite relaxation time. We discuss links between the dynamical critical point and quantum phase transitions, showing that dynamical phase transitions in d dimensions map to quantum transitions in the same dimension, and hence to classical thermodynamic phase transitions in d + 1 dimensions. PMID:20616075

  11. Method for Measuring Collimator-Pointing Sensitivity to Temperature Changes

    NASA Technical Reports Server (NTRS)

    Abramovici, Alex; Cox, Timothy E.; Hein, Randall C.; MacDonald, Daniel R.

    2011-01-01

    For a variety of applications, it is important to measure the sensitivity of the pointing of a beam emerging from a collimator, as a function of temperature changes. A straightforward method for carrying out this measurement is based on using interferometry for monitoring the changes in beam pointing, which presents its own problems. The added temperature dependence and complexity issues relating to using an interferometer are addressed by not using an interferometer in the first place. Instead, the collimator is made part of an arrangement that uses a minimum number of low-cost, off-the-shelf materials and by using a quad diode to measure changes in beam pointing. In order to minimize the influence of the test arrangement on the outcome of the measurement, several steps are taken. The collimator assembly is placed on top of a vertical, 1-m-long, fused silica tube. The quad diode is bonded to a fused silica bar, which, in turn, is bonded to the lower end of the fused silica tube. The lower end of the tube rests on a self-aligning support piece, while the upper end of the tube is kept against two rounded setscrew tips, using a soft rubber string. This ensures that very little stress is applied to the tube as the support structure changes dimensions due to thermal expansion. Light is delivered to the collimator through a bare fiber in order to minimize variable bending torque caused by a randomly relaxing, rigid fiber jacket. In order to separate the effect of temperature on the collimator assembly from the effect temperature has on the rest of the setup, multiple measurements are taken with the collimator assembly rotated from measurement to measurement. Laboratory testing, with 1-m spacing between the collimator and the quad diode, has shown that the sensitivity of the arrangement is better than 100 nm rms, over time spans of at least one hour, if the beam path is protected from atmospheric turbulence by a tube. The equivalent sensitivity to detecting changes in pointing angle is 100 nanoradians.

  12. Experimental consequences of quantum critical points at high temperatures

    NASA Astrophysics Data System (ADS)

    Freitas, D. C.; Rodière, P.; Núñez, M.; Garbarino, G.; Sulpice, A.; Marcus, J.; Gay, F.; Continentino, M. A.; Núñez-Regueiro, M.

    2015-11-01

    We study the C r1 -xR ex phase diagram finding that its phase transition temperature towards an antiferromagnetic order TN follows a quantum [(xc-x ) /xc ] ψ law, with ψ =1 /2 , from the quantum critical point (QCP) at xc=0.25 up to TN≈600 K . We compare this system to others in order to understand why this elemental material is affected by the QCP up to such unusually high temperatures. We determine a general criterion for the crossover, as a function of an external parameter such as concentration, from the region controlled solely by thermal fluctuations to that where quantum effects become observable. The properties of materials with low coherence lengths will thus be altered far away from the QCP.

  13. Transient boiling heat transfer in saturated liquid nitrogen and F113 at standard and zero gravity

    NASA Technical Reports Server (NTRS)

    Oker, E.; Merte, H., Jr.

    1973-01-01

    Transient and steady state nucleate boiling in saturated LN2 and F113 at standard and near zero gravity conditions were investigated for the horizontal up, vertical and horizontal down orientations of the heating surface. Two distinct regimes of heat transfer mechanisms were observed during the interval from the step increase of power input to the onset of nucleate boiling: the conduction and convection dominated regimes. The time duration in each regime was considerably shorter with LN2 than with F113, and decreased as heat flux increased, as gravity was reduced, and as the orientation was changed from horizontal up to horizontal down. In transient boiling, boiling initiates at a single point following the step increase in power, and then spreads over the surface. The delay time for the inception of boiling at the first site, and the velocity of spread of boiling varies depending upon the heat flux, orientation, body force, surface roughness and liquid properties, and are a consequence of changes in boundary layer temperature levels associated with changes in natural convection. Following the step increase in power input, surface temperature overshoot and undershoot occur before the steady state boiling temperature level is established.

  14. Enhanced convective and film boiling heat transfer by surface gas injection

    NASA Astrophysics Data System (ADS)

    Duignan, M. R.; Greene, G. A.; Irvine, T. F., Jr.

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T(sub SURFACE) approximately 500 K, to T(sub SURFACE) approximately 950 K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long as it was corrected for the heat transferred by radiation. On the average, the experimental data lay within plus or minus 7 percent of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm-diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/sq m. For water-pool heights of less than 6 cm the heat transfer coefficient decreased linearly with a decrease in heights. Above 6 cm the heat transfer coefficient was unaffected. For the entire range of gas velocities which measured (0 to 8.5 cm/s), the magnitude of the heat transfer coefficient only changed by approximately 20 percent. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface.

  15. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect

    Duignan, M.R.; Greene, G.A.; Irvine, T.F., Jr.

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus_minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured [0 to 8.5 cm/s], the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  16. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect

    Duignan, M.R.; Greene, G.A. ); Irvine, T.F., Jr. . Dept. of Mechanical Engineering)

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured (0 to 8.5 cm/s), the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  17. Evaluation and Selection of High-Temperature Fixed-Point Cells for Thermodynamic Temperature Assignment

    NASA Astrophysics Data System (ADS)

    Yamada, Y.; Anhalt, K.; Battuello, M.; Bloembergen, P.; Khlevnoy, B.; Machin, G.; Matveyev, M.; Sadli, M.; Todd, A.; Wang, T.

    2015-08-01

    A multi-partner project to determine the thermodynamic temperatures of a selected set of high-temperature fixed points based on metal-carbon eutectics is underway as a working group activity within the Comité International des Poids et Mesures. The investigation focuses on four fixed-point types, namely, the three metal-carbon eutectic points of Re-C , Pt-C , and Co-C , and the Cu point . This paper describes the construction, pre-evaluation, and screening stage of the cells prior to their thermodynamic temperature determinations. The construction of the HTFP cells was undertaken by nine national metrology institutes (NMIs) according to instructions laid out in a pre-agreed protocol that ensures production of best quality cells. Four NMIs conducted the evaluation, each for a certain fixed-point type, and screened out cells that did not meet pre-determined selection criteria while assuring sufficient variety in the sources of the cells in the final selected sets. In autumn 2012, the selected cells were successfully passed on to the final stage of the project, the thermodynamic temperature measurement, and assignment.

  18. In-situ Stress Measurements on SUS316L Stainless Steel in High Temperature Water Simulated Boiling Water Reactor

    SciTech Connect

    Yamamoto, A.; Terasawa, M.; Mitamura, T.; Yamada, T.; Liu, L.; Tsubakino, H.; Nakahigashi, S.; Akiniwa, Y.; Shobu, T.

    2007-01-19

    An in-situ straining device has been developed, which enables one to apply a load of 240 N to a specimen in hot water at 561 K and a pressure of 8 MPa, simulating the environment in a boiling water reactor (BWR). The device is equipped with sapphire glass windows for a light path, that is, the device can be used for dynamic measurements of stress induced in the specimen using a synchrotron radiation facility. In-situ stress measurements have been carried out at SPring-8 (BL02B1) on a specimen prepared from SUS316L stainless steel. Inhomogeneity in stress distribution and time-dependent changes in stress were successfully measured.

  19. Local Heat Transfer and CHF for Subcooled Flow Boiling - Annual Report 1994

    SciTech Connect

    Dr. Ronald D. Boyd

    2000-07-01

    The physical phenomenon of forced convective boiling is probably one of the most interesting and complex transport phenomena. It has been under study for more than two centuries. Simply stated, forced convective subcooled boiling involves a locally boiling fluid: (1) whose mean temperature is below its saturation temperature, and (2) that flows over a surface exposed uniformly or non-uniformly to a high heat flux (HHF). The objective of this work is to assess and/or improve the present ability to predict local axial heat transfer distributions in the subcooled flow boiling regime for the case of uniformly heated coolant channels. This requires an accurate and complete representation of the boiling curve up to the CHF. The present. results will be useful for both heat transfer research and industrial design applications. Future refinements may result in the application of the results to non-uniformly heated channels or other geometries, and other fluids. Several existing heat transfer models for uniformly heated channels were examined for: (1) accurate representation of the boiling curve, and (2) characterizing the local heat transfer coefficient under high heat flux (HHF) conditions. Comparisons with HHF data showed that major correlation modifications were needed in the subcooled partial nucleate boiling (SPNB) region. Since the slope of boiling curve in this region is important to assure continuity of the HHF trends into the fully developed boiling region and up to the critical heat flux, accurate characterization in the SPNB region is essential. Approximations for the asymptotic limits for the SPNB region have been obtained and have been used to develop an improved composite correlation. The developed correlation has been compared with 363 water data points. For the local heat transfer coefficient and wall temperature, the over-all percent standard deviations with respect to the data were 19% and 3%, respectively, for the high velocity water data.

  20. TEMPERATURE VARIATION WITH TIME IN A PERENNIALLY BOILING WELL IN THE LONG VALLEY CALDERA, MONO COUNTY, CALIFORNIA; OBSERVATIONS IN CHANCE NO. 1 (1976-1983).

    USGS Publications Warehouse

    Diment, W.H.; Urban, T.C.; Nathenson, Manuel

    1985-01-01

    Chance No. 1 was drilled to a depth of 245. 4 m and cased to a depth of 72. 2 m in 1961. Temperature logs were obtained in 1976, 1982, and 1983, with the casing open to the atmosphere. Water was boiling at the surface of the fluid column on each occasion. Temperatures within the upper part of the cased interval remained virtually identical over the 7-year period. The small differences observed can be ascribed to convective motions in the large-diameter casing and the large geothermal gradient. Above a depth of 160 m in the open hole, temperatures have cooled 5 degree -7 degree C over the 7-year period of observation. The shape of the temperature profiles and their variation with time can be explained by an influx of cool water at about 160 m. The cooling rate is much larger between 1982 and 1983 than that between 1982 and 1976, which suggests that earthquake shaking may be a major contributing factor.

  1. Programmed temperature vaporizing injector to filter off disturbing high boiling and involatile material for on-line high performance liquid chromatography gas chromatography with on-column transfer.

    PubMed

    Biedermann, Maurus; Grob, Koni

    2013-03-15

    Insertion of a programmed temperature vaporizing (PTV) injector under conditions of concurrent solvent recondensation (CSR) into the on-line HPLC-GC interface for on-column transfer (such as the retention gap technique with partially concurrent eluent evaporation) enables filtering off high boiling or involatile sample constituents by a desorption temperature adjusted to the required cut-off. Details of this technique were investigated and optimized. Memory effects, observed when transferred liquid was sucked backwards between the transfer line and the wall of the injector liner, can be kept low by a small purge flow rate through the transfer line at the end of the transfer and the release of the liquid through a narrow bore capillary kept away from the liner wall. The column entrance should be within the well heated zone of the injector to prevent losses of solute material retained on the liner wall during the splitless period. The desorption temperature must be maintained until an elevated oven temperature is reached to prevent peak broadening resulting of a cool inlet section in the bottom part of the injector. PMID:23394744

  2. Fluid inclusion from drill hole DW-5, Hohi geothermal area, Japan: Evidence of boiling and procedure for estimating CO2 content

    USGS Publications Warehouse

    Sasada, M.; Roedder, E.; Belkin, H.E.

    1986-01-01

    Fluid inclusion studies have been used to derive a model for fluid evolution in the Hohi geothermal area, Japan. Six types of fluid inclusions are found in quartz obtained from the drill core of DW-5 hole. They are: (I) primary liquid-rich with evidence of boiling; (II) primary liquid-rich without evidence of boiling; (III) primary vapor-rich (assumed to have been formed by boiling); (IV) secondary liquid-rich with evidence of boiling; (V) secondary liquid-rich without evidence of boiling; (VI) secondary vapor-rich (assumed to have been formed by boiling). Homogenization temperatures (Th) range between 196 and 347??C and the final melting point of ice (Tm) between -0.2 and -4.3??C. The CO2 content was estimated semiquantitatively to be between 0 and 0.39 wt. % based on the bubble behavior on crushing. NaCl equivalent solid solute salinity of fluid inclusions was determined as being between 0 and 6.8 wt. % after minor correction for CO2 content. Fluid inclusions in quartz provide a record of geothermal activity of early boiling and later cooling. The CO2 contents and homogenization temperatures of fluid inclusions with evidence of boiling generally increase with depth; these changes, and NaCl equivalent solid solute salinity of the fluid can be explained by an adiabatic boiling model for a CO2-bearing low-salinity fluid. Some high-salinity inclusions without CO2 are presumed to have formed by a local boiling process due to a temperature increase or a pressure decrease. The liquid-rich primary and secondary inclusions without evidence of boiling formed during the cooling process. The salinity and CO2 content of these inclusions are lower than those in the boiling fluid at the early stage, probably as a result of admixture with groundwater. ?? 1986.

  3. Investigation of low-temperature fixed points by an international star intercomparison of sealed triple-point cells

    NASA Astrophysics Data System (ADS)

    Fellmuth, B.; Wolber, L.; Head, D. I.; Hermier, Y.; Hill, K. D.; Nakano, T.; Pavese, F.; Peruzzi, A.; Rusby, R. L.; Shkraba, V.; Steele, A. G.; Steur, P. P. M.; Szmyrka-Grzebyk, A.; Tew, W. L.; Wang, L.; White, D. R.

    2012-06-01

    An overview of the results of an international star intercomparison of low-temperature fixed points is given. Between 1997 and 2005, 68 sealed triple-point cells (STPCs) of the twelve laboratories represented by the authors were investigated at PTB. The STPCs are used to realize the triple points of hydrogen, neon, oxygen and argon as defining fixed points of the International Temperature Scale of 1990, ITS-90. The melting curves (MCs) of all STPCs have been measured on the same experimental equipment, adhering strictly to a single measurement program. This protocol enables separation of the effects influencing the MCs and direct comparison of the thermal behaviour of the STPCs, which are quite different with respect to design, age, gas source and filling technology. In the paper, special emphasis is given to the spread of the liquidus-point temperatures and to the uncertainty of their determination. Connections between the star intercomparison and completed and ongoing international activities are also discussed.

  4. Visualization and void fraction measurement of decompressed boiling flow in a capillary tube

    NASA Astrophysics Data System (ADS)

    Asano, H.; Murakawa, H.; Takenaka, N.; Takiguchi, K.; Okamoto, M.; Tsuchiya, T.; Kitaide, Y.; Maruyama, N.

    2011-09-01

    A capillary tube is often used as a throttle for a refrigerating cycle. Subcooled refrigerant usually flows from a condenser into the capillary tube. Then, the refrigerant is decompressed along the capillary tube. When the static pressure falls below the saturation pressure for the liquid temperature, spontaneous boiling occurs. A vapor-liquid two-phase mixture is discharged from the tube. In designing a capillary tube, it is necessary to calculate the flow rate for given boundary conditions on pressure and temperature at the inlet and exit. Since total pressure loss is dominated by frictional and acceleration losses during two-phase flow, it is first necessary to specify the boiling inception point. However, there will be a delay in boiling inception during decompressed flow. This study aimed to clarify the boiling inception point and two-phase flow characteristics of refrigerant in a capillary tube. Refrigerant flows in a coiled copper capillary tube were visualized by neutron radiography. The one-dimensional distribution of volumetric average void fraction was measured from radiographs through image processing. From the void fraction distribution, the boiling inception point was determined. Moreover, a simplified CT method was successfully applied to a radiograph for cross-sectional measurements. The experimental results show the flow pattern transition from intermittent flow to annular flow that occurred at a void fraction of about 0.45.

  5. A noninvasive human temperature screening system with multiple detection points

    NASA Astrophysics Data System (ADS)

    Sumriddetchkajorn, Sarun; Chaitavon, Kosom

    2008-04-01

    This paper introduces a non-invasive human temperature screening system for use in a large public area. Our key idea is to combine an image filtering process, an image morphology algorithm, and a particle analysis process in such a way that an individual's face in live thermal image can be located so that the skin temperature can be monitored and displayed. From our experiment, we find that the temperature measurement depends on each individual's response to the ambient temperature and on the contrast of the thermal image against the black body radiation source. This indicates that using the blackbody radiation source as our temperature reference does not totally compensate the fluctuation in human skin temperature. Our field test study at the triage section of Rajavithi Hospital, Thailand, shows that the maximum skin temperatures from people's faces can be simultaneously monitored and displayed in real time. In addition, the temperature value obtained from the thermal imaging camera has less fluctuation with respect to the true core body temperature once the disturbance from the surrounding environment is compensated. Hyperthermic patients can be identified with 100% sensitivity when the temperature threshold level and the offset temperature value are appropriately chosen.

  6. Deposition rate of suspended hematite in a boiling water system under BWR conditions

    SciTech Connect

    Mizuno, T.; Wada, K.; Iwahori, T.

    1982-01-01

    The state and rate of deposition of suspended hematite were studied on a boiling heat transfer surface under the heat flux, temperature, and pressure similar to those in BWR power plants. If the amount of deposit can be held below the break point during fuel element operation, the radioactive corrosion products level is expected to reduce in reactor water. 18 refs.

  7. Nucleation and droplet growth from supersaturated vapor at temperatures below the triple point temperature.

    PubMed

    Toxvaerd, Søren

    2016-04-28

    In 1897 Ostwald formulated his step rule for formation of the most stable crystal state for a system with crystal polymorphism. The rule describes the irreversible way a system converts to the crystal with lowest free energy. But in fact the irreversible way a supercooled gas below the triple point temperature Ttr.p. crystallizes via a liquid droplet is an example of Ostwald's step rule. The homogeneous nucleation in the supersaturated gas is not to a crystal, but to a liquid-like critical nucleus. We have for the first time performed constant energy (NVE) Molecular Dynamics (MD) of homogeneous nucleation without the use of a thermostat. The simulations of homogeneous nucleation in a Lennard-Jones system from supersaturated vapor at temperatures below Ttr.p. reveal that the nucleation to a liquid-like critical nucleus is initiated by a small cold cluster [S. Toxvaerd, J. Chem. Phys. 143, 154705 (2015)]. The release of latent heat at the subsequent droplet growth increases the temperature in the liquid-like droplet, which for not deep supercooling and/or low supersaturation, can exceed Ttr.p.. The temperature of the liquid-like droplet increases less for a low supersaturation and remains below Ttr.p., but without a crystallization of the droplet for long times. The dissipation of the latent heat into the surrounding gas is affected by a traditional MD thermostat, with the consequence that droplet growth is different for (NVE) MD and constant temperature (NVT) MD. PMID:27131552

  8. Phase relations and adiabats in boiling seafloor geothermal systems

    USGS Publications Warehouse

    Bischoff, J.L.; Pitzer, Kenneth S.

    1985-01-01

    Observations of large salinity variations and vent temperatures in the range of 380-400??C suggest that boiling or two-phase separation may be occurring in some seafloor geothermal systems. Consideration of flow rates and the relatively small differences in density between vapors and liquids at the supercritical pressures at depth in these systems suggests that boiling is occurring under closed-system conditions. Salinity and temperature of boiling vents can be used to estimate the pressure-temperature point in the subsurface at which liquid seawater first reached the two-phase boundary. Data are reviewed to construct phase diagrams of coexisting brines and vapors in the two-phase region at pressures corresponding to those of the seafloor geothermal systems. A method is developed for calculating the enthalpy and entropy of the coexisting mixtures, and results are used to construct adiabats from the seafloor to the P-T two-phase boundary. Results for seafloor vents discharging at 2300 m below sea level indicate that a 385??C vent is composed of a brine (7% NaCl equivalent) in equilibrium with a vapor (0.1% NaCl). Brine constitutes 45% by weight of the mixture, and the fluid first boiled at approximately 1 km below the seafloor at 415??C, 330 bar. A 400??C vent is primarily vapor (88 wt.%, 0.044% NaCl) with a small amount of brine (26% NaCl) and first boiled at 2.9 km below the seafloor at 500??C, 520 bar. These results show that adiabatic decompression in the two-phase region results in dramatic cooling of the fluid mixture when there is a large fraction of vapor. ?? 1985.

  9. Local jet impingement boiling heat transfer with R113

    NASA Astrophysics Data System (ADS)

    Zhou, D. W.; Ma, C. F.

    An experimental study was performed to characterize the boiling heat transfer of impinging circular submerged jets on simulated microelectronic chips with a nominal area of 5 mm × 5 mm. The heat transfer modes included natural convection, partially developed nucleate boiling, fully developed nucleate boiling and critical heat flux. The study included the effects of jet parameters and fluid subcooling on the nucleate boiling. The results showed that the nucleate boiling data varied only with fluid subcooling regardless of jet parameters and that both the pool and impingement nucleate boiling curves at the same subcooling condition were well correlated. The high heat flux portions of the boiling curves with jet exit velocities greater than 10 m/s were corrected for the elevated saturation temperature. A new expression was developed with an interpolation method to construct the partially developed nucleate boiling curve.

  10. Numerical simulation of pool boiling for steady state and transient heating

    SciTech Connect

    He, Ying; Shoji, Masahiro; Maruyama, Shigeo

    1999-07-01

    It's believed that the macrolayer plays an important role in nucleate and transition boiling heat transfer at high heat flux. Many experiments have been carried out to support the macrolayer evaporation model, however, little has been conducted in the numerical simulation of boiling heat transfer. In this study, based on the macrolayer evaporation model of Maruyama et al. (1992), a numerical simulation of pool boiling for steady state was carried out. The key points of the simulation are: (1) It is modeled that the macrolayer containing vapor stems occupies the region immediately next to the wall and that the vapor stems are formed on the active cavity sites. (2) Not only does the evaporation occur at the vapor bubble-macrolayer interface, but also at the liquid-vapor stem interface. (3) The macrolayers form periodically. No liquid is supplied to the macrolayers during the hovering period. While the vapor mass departs from the surface, the macrolayers replenish immediately despite the complicity of the transition period between the departures of two vapor masses. The major results are: (1) The boiling curves of water and FC-72 (C{sub 6}F{sub 14}) were reasonably predicted. (2) The temporal variations in surface temperature for different boiling regimes were obtained. Secondly, the simulation of transient pool boiling was conducted. It was realized with following assumptions: (1) The macrolayer evaporation model can be extended to the transient pool boiling. The macrolayer forms cyclically and its thickness is determined by the surface heat flux when the vapor mass takes off. (2) One-dimensional transient heat conduction within the heater coupled with the macrolayer model was considered. Being employed explicit FDM, the instantaneous surface temperature can be obtained. Therefore, the instantaneous heat flux can be calculated by applying the surface temperature into the macrolayer model. (3) In the transition-boiling regime, the initial thickness of macrolayer was determined by the extrapolated value of the obtained nucleate boiling curve. The simulated results showed that: (1) For lower transient heating rate, the boiling curve in the nucleate boiling regime almost remains the same as the steady-state curve. For higher transient heating rate, it deviates from the steady-state curve. (2) The critical heat flux increases with increasing heating transients. The investigation of the changes of macrolayer thickness and void fraction implies that the evaporation of macrolayer has a great effect on the increase of CHF under transient heating.

  11. Chiral interface at the finite temperature transition point of QCD

    NASA Technical Reports Server (NTRS)

    Frei, Z.; Patkos, A.

    1990-01-01

    The domain wall between coexisting chirally symmetric and broken symmetry regions is studied in a saddle point approximation to the effective three-flavor sigma model. In the chiral limit the surface tension varies in the range ((40 to -50)MeV)(exp 3). The width of the domain wall is estimated to be approximately or equal to 4.5 fm.

  12. The Transition From Nucleate Boiling Towards the Convection: Application to the Quenching of Metallic Massive Parts

    SciTech Connect

    Bourouga, Brahim; Gilles, Jerome

    2007-04-07

    In a recent study on thermal aspects of the quenching process, we developed an original device of measurement which allowed to update the competition between the heat transfer modes according to the quenching conditions and the quenched part size. One shows that, according to the range value of Biot number, the more resistive one part is, the more the boiling phases are relatively short. In order to provide relatively precise data for simulation of the quenching process in the case of strongly resistive parts from a thermal point of view, we undertook experiments on the cooling transition from nucleate boiling towards the convection. The obtained experimental results show that the temperature of transition from the nucleate boiling to the convection increases when the bath temperature decreases. We present the differences between the values of convection coefficient according to whether the bath is agitated or not. Experimental results relating are compared to some classical correlations.

  13. Evaporation, Boiling and Bubbles

    ERIC Educational Resources Information Center

    Goodwin, Alan

    2012-01-01

    Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The…

  14. Evaporation, Boiling and Bubbles

    ERIC Educational Resources Information Center

    Goodwin, Alan

    2012-01-01

    Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The

  15. Multiple-Point Temperature Gradient Algorithm for Ring Laser Gyroscope Bias Compensation

    PubMed Central

    Li, Geng; Zhang, Pengfei; Wei, Guo; Xie, Yuanping; Yu, Xudong; Long, Xingwu

    2015-01-01

    To further improve ring laser gyroscope (RLG) bias stability, a multiple-point temperature gradient algorithm is proposed for RLG bias compensation in this paper. Based on the multiple-point temperature measurement system, a complete thermo-image of the RLG block is developed. Combined with the multiple-point temperature gradients between different points of the RLG block, the particle swarm optimization algorithm is used to tune the support vector machine (SVM) parameters, and an optimized design for selecting the thermometer locations is also discussed. The experimental results validate the superiority of the introduced method and enhance the precision and generalizability in the RLG bias compensation model. PMID:26633401

  16. Multiple-Point Temperature Gradient Algorithm for Ring Laser Gyroscope Bias Compensation.

    PubMed

    Li, Geng; Zhang, Pengfei; Wei, Guo; Xie, Yuanping; Yu, Xudong; Long, Xingwu

    2015-01-01

    To further improve ring laser gyroscope (RLG) bias stability, a multiple-point temperature gradient algorithm is proposed for RLG bias compensation in this paper. Based on the multiple-point temperature measurement system, a complete thermo-image of the RLG block is developed. Combined with the multiple-point temperature gradients between different points of the RLG block, the particle swarm optimization algorithm is used to tune the support vector machine (SVM) parameters, and an optimized design for selecting the thermometer locations is also discussed. The experimental results validate the superiority of the introduced method and enhance the precision and generalizability in the RLG bias compensation model. PMID:26633401

  17. The influence of some relevant metallic impurities in the triple point of mercury temperature

    NASA Astrophysics Data System (ADS)

    Tabacaru, C.; del Campo, D.; Gómez, E.; García Izquiedo, C.; Welna, A.; Kalemci, M.; Pehlivan, Ö.

    2016-02-01

    The influence of impurities on the defined fixed points of the International Temperature Scale of 1990 is one of the most relevant sources of uncertainty in their use. Namely, the triple point of mercury is one of the fixed points most used because its assigned triple point temperature (‑39,8344 °C) is within a temperature range of high interest for science and industry. Mercury can be obtained with high purity, usually better that 8N and it is realized with a high accuracy, what makes impurities a significant contributor on the final uncertainty. The best procedure to quantify this influence is by means of doping experiments which consist of the addition of a controlled amount of an impurity, determined gravimetrically, in a fixed point cell. This paper presents a summary of the results obtained from a series of doping experiments performed with some relevant metallic impurities on the triple point of mercury temperature.

  18. Subcooled and low quality film boiling of water in vertical flow at atmospheric pressure. [PWR; BWR

    SciTech Connect

    Fung, K.K.

    1981-08-01

    Subcooled and low quality film boiling is usually encountered in safety analyses of nuclear reactors. In most of the previous subcooled film boiling studies, cryogenic fluids were used either in a stagnant pool or a forced convective set-up. These data cannot be applied to reactor safety analysis without excessive conservatism or skepticism. In this study, a unique method is used to establish flow film boiling of water in a vertical tube at atmospheric pressure. The data cover a mass flux range of 50 to 500 kg.m/sup -2/.s/sup -1/ and an inlet subcooling range of 5 to 70/sup 0/C. It is found that the heat transfer coefficient depends on the mass flux, inlet subcooling and the axial distance from the point where film boiling first starts. A physical model is developed to predict the wall temperature of a tube during inverted annular film boiling. It considers the thermal boundary layers in the subcooled liquid core and in the superheated vapor film. The predicted wall temperatures and void fractions compare well with the measurements.

  19. Conceptual design for spacelab pool boiling experiment

    NASA Technical Reports Server (NTRS)

    Lienhard, J. H.; Peck, R. E.

    1978-01-01

    A pool boiling heat transfer experiment to be incorporated with a larger two-phase flow experiment on Spacelab was designed to confirm (or alter) the results of earth-normal gravity experiments which indicate that the hydrodynamic peak and minimum pool boiling heat fluxes vanish at very low gravity. Twelve small sealed test cells containing water, methanol or Freon 113 and cylindrical heaters of various sizes are to be built. Each cell will be subjected to one or more 45 sec tests in which the surface heat flux on the heaters is increased linearly until the surface temperature reaches a limiting value of 500 C. The entire boiling process will be photographed in slow-motion. Boiling curves will be constructed from thermocouple and electric input data, for comparison with the motion picture records. The conduct of the experiment will require no more than a few hours of operator time.

  20. Boiling fluids in a region of rapid uplift, Nanga Parbat Massif, Pakistan

    NASA Astrophysics Data System (ADS)

    Craw, D.; Koons, P. O.; Winslow, D.; Chamberlain, C. P.; Zeitler, P.

    1994-12-01

    The Nanga Parbat massif of northern Pakistan is currently undergoing rapid uplift (approx. 5-10 mm/a), resulting in near-surface elevated temperatures. Numerous quartz veins cut geologically young structures (less than 2 Ma), attesting to widespread young fluid flow. Fluid inclusions in quartz veins are predominantly low density water vapor (down to 0.05 mg/cu m), with some low density carbon dioxide vapor, and the fluid is predominantly meteoric in origin. Fluid inclusions provide evidence for boiling near to the critical points for water and for 5 wt% NaCl solution (up to 410 C). Head-driven meteoric water was convecting in fracture permeability under hydrostatic pressures which followed the boiling point-depth curve and near-boiling springs emanate from the surface. Hydrostatic pressures persisted to depths of about 6 km below the topographic surface, or near to sea level, where the brittle-ductile transition is inferred to lie. Numerical modeling of conductive heat flow in an area of high relief during rapid uplift indicates that the shape of the near-surface conductive geotherm is significantly influenced by topographic relief. Reasonable approximations for topgraphy at Nanga Parbat produce a conductive geotherm which implies high, near-surface geothermal gradients (greater than 100 C/km, and the isotherms describe a giant pillar of heat. Above about 4 km, fluid temperature is greater than conductive rock temperature in permeable zones which carry convecting boiling meteoric fluid.

  1. Development of a mechanistic model for forced convection subcooled boiling

    NASA Astrophysics Data System (ADS)

    Shaver, Dillon R.

    The focus of this work is on the formulation, implementation, and testing of a mechanistic model of subcooled boiling. Subcooled boiling is the process of vapor generation on a heated wall when the bulk liquid temperature is still below saturation. This is part of a larger effort by the US DoE's CASL project to apply advanced computational tools to the simulation of light water reactors. To support this effort, the formulation of the dispersed field model is described and a complete model of interfacial forces is formulated. The model has been implemented in the NPHASE-CMFD computer code with a K-epsilon model of turbulence. The interfacial force models are built on extensive work by other authors, and include novel formulations of the turbulent dispersion and lift forces. The complete model of interfacial forces is compared to experiments for adiabatic bubbly flows, including both steady-state and unsteady conditions. The same model is then applied to a transient gas/liquid flow in a complex geometry of fuel channels in a sodium fast reactor. Building on the foundation of the interfacial force model, a mechanistic model of forced-convection subcooled boiling is proposed. This model uses the heat flux partitioning concept and accounts for condensation of bubbles attached to the wall. This allows the model to capture the enhanced heat transfer associated with boiling before the point of net generation of vapor, a phenomenon consistent with existing experimental observations. The model is compared to four different experiments encompassing flows of light water, heavy water, and R12 at different pressures, in cylindrical channels, an internally heated annulus, and a rectangular channel. The experimental data includes axial and radial profiles of both liquid temperature and vapor volume fraction, and the agreement can be considered quite good. The complete model is then applied to simulations of subcooled boiling in nuclear reactor subchannels consistent with the operating conditions of the AP1000 pressurized water reactor. The effects of both axial and lateral nonuniform power distributions inside reactor fuel elements are accounted for. Boiling flows are simulated for three different computational domains of increasing complexity: a quarter-subchannel bordering a single fuel pin, two subchannels surround by an array of 2 by 3 fuel pins, and in four subchannels surrounded by an array of 3 by 3 fuel pins. The predicted behavior is consistent with expectations. In the 3 by 3 array, the two-phase coolant is predicted to flow from the hot channels to the cold channels, enhancing heat exchange between subchannels. This, in turn, demonstrates that the new model is capable of capturing the turbulence- and buoyancy-induced coolant mixing across the neighboring channels.

  2. Comparison of Single-Point and Continuous Sampling Methods for Estimating Residential Indoor Temperature and Humidity.

    PubMed

    Johnston, James D; Magnusson, Brianna M; Eggett, Dennis; Collingwood, Scott C; Bernhardt, Scott A

    2015-01-01

    Residential temperature and humidity are associated with multiple health effects. Studies commonly use single-point measures to estimate indoor temperature and humidity exposures, but there is little evidence to support this sampling strategy. This study evaluated the relationship between single-point and continuous monitoring of air temperature, apparent temperature, relative humidity, and absolute humidity over four exposure intervals (5-min, 30-min, 24-hr, and 12-days) in 9 northern Utah homes, from March-June 2012. Three homes were sampled twice, for a total of 12 observation periods. Continuous data-logged sampling was conducted in homes for 2-3 wks, and simultaneous single-point measures (n = 114) were collected using handheld thermo-hygrometers. Time-centered single-point measures were moderately correlated with short-term (30-min) data logger mean air temperature (r = 0.76, β = 0.74), apparent temperature (r = 0.79, β = 0.79), relative humidity (r = 0.70, β = 0.63), and absolute humidity (r = 0.80, β = 0.80). Data logger 12-day means were also moderately correlated with single-point air temperature (r = 0.64, β = 0.43) and apparent temperature (r = 0.64, β = 0.44), but were weakly correlated with single-point relative humidity (r = 0.53, β = 0.35) and absolute humidity (r = 0.52, β = 0.39). Of the single-point RH measures, 59 (51.8%) deviated more than ±5%, 21 (18.4%) deviated more than ±10%, and 6 (5.3%) deviated more than ±15% from data logger 12-day means. Where continuous indoor monitoring is not feasible, single-point sampling strategies should include multiple measures collected at prescribed time points based on local conditions. PMID:26030088

  3. Odd-Boiled Eggs

    ERIC Educational Resources Information Center

    Kaminsky, Kenneth; Scheman, Naomi

    2010-01-01

    At a Shabbat lunch in Madrid not long ago, the conversation turned to the question of boiling eggs. One of the guests mentioned that a Dutch rabbi he knew had heard that in order to make it more likely that boiled eggs be kosher, you should add an egg to the pot if the number you began with was even. According to the laws of Kashruth, Jews may not…

  4. Cloud-point temperature and liquid-liquid phase separation of supersaturated lysozyme solution.

    PubMed

    Lu, Jie; Carpenter, Keith; Li, Rui-Jiang; Wang, Xiu-Juan; Ching, Chi-Bun

    2004-04-01

    The detailed understanding of the structure of biological macromolecules reveals their functions, and is thus important in the design of new medicines and for engineering molecules with improved properties for industrial applications. Although techniques used for protein crystallization have been progressing greatly, protein crystallization may still be considered an art rather than a science, and successful crystallization remains largely empirical and operator-dependent. In this work, a microcalorimetric technique has been utilized to investigate liquid-liquid phase separation through measuring cloud-point temperature T(cloud) for supersaturated lysozyme solution. The effects of ionic strength and glycerol on the cloud-point temperature are studied in detail. Over the entire range of salt concentrations studied, the cloud-point temperature increases monotonically with the concentration of sodium chloride. When glycerol is added as additive, the solubility of lysozyme is increased, whereas the cloud-point temperature is decreased. PMID:15059663

  5. Critical boiling phenomena observed in microgravity

    NASA Astrophysics Data System (ADS)

    Garrabos, Y.; Chabot, C.; Wunenburger, R.; Delville, J.-P.; Beysens, D.

    1999-06-01

    We report experimental observations of the critical boiling when co-existing gas and liquid phases of pure fluid are heated under weigthlessness through the critical point. We find that when the system's temperature T is being increased to the critical temperature Tc so that it's slightly out of equilibrium, the apparent contact angle becomes very large (up to 110 circ). The gas appears to "web" the solid surface. In addition, we detect large temperature gradients between the (hot) gas phase and the (cold) liquid phase in the interferometric cell. These unexpected results are robust: they are observed either under continuous heating (ramping) or stepping by positive temperature quenches, for various morphologies of the gas bubble and in different fluids (SF6 and CO2). The difference in isentropic thermal responses of gas and liquid during heating, due to the adiabatic heating by the "Piston Effect", is responsible for the temperature non-homogeneities. The vapour recoil force due to liquid evaporation, which is involved in the boiling crisis in heat exchangers, is presumably at the origin of the interface deformation. Nous rapportons les observations expérimentales obtenues en chaffant un fluide pur diphasique gaz-liquide en coexistence au cours de la traversée de son point critique en absence de pesanteur. Lorsque la température du système diphasique hors d'équilibre est augmentée vers la température critique, nous observons en transmission un angle de contact apparent de la vapeur très important (atteignant 110 circ), le gaz semblant "mouiller" la surface solide. De plus, d'importants gradients de température entre la phase gaz chaude et la phase liquide froide sont mesurés dans les cellules observées par interférométrie. Ces résultats inattendus sont observés pour un chauffage continu (rampe) et par trempe positive (échelon), pour différents rapports d'aspect du système diphasique, pour des cellules de CO2 et de SF6, démontrant ainsi une grande robustesse. Les réponses isentropiques différentes du gaz et du liquide lors du chauffage par effet piston sont certainement responsables des inhomogénéités de température. La force de recul de la vapeur due à l'évaporation pourrait être la cause dominante de la déformation de l'interface liquide-vapeur à l'approche de la température de transition.

  6. Loop Heat Pipe Operation Using Heat Source Temperature for Set Point Control

    NASA Technical Reports Server (NTRS)

    Ku, Jentung; Paiva, Kleber; Mantelli, Marcia

    2011-01-01

    Loop heat pipes (LHPs) have been used for thermal control of several NASA and commercial orbiting spacecraft. The LHP operating temperature is governed by the saturation temperature of its compensation chamber (CC). Most LHPs use the CC temperature for feedback control of its operating temperature. There exists a thermal resistance between the heat source to be cooled by the LHP and the LHP's CC. Even if the CC set point temperature is controlled precisely, the heat source temperature will still vary with its heat output. For most applications, controlling the heat source temperature is of most interest. A logical question to ask is: "Can the heat source temperature be used for feedback control of the LHP operation?" A test program has been implemented to answer the above question. Objective is to investigate the LHP performance using the CC temperature and the heat source temperature for feedback control

  7. On the Extended Point Defect Model in Si Crystals at High Temperature

    NASA Astrophysics Data System (ADS)

    Suezawa, Masashi; Yonenaga, Ichiro

    2008-09-01

    We herein discuss Seeger and Chik's model of extended point defects in Si crystals at high temperature based on our experimental results on the diffusion constant of vacancies at high temperature and the vacancy formation energy. We also show that the application of the extended model to the recombination of a vacancy and an interstitial is unsuitable, by pointing out the error in the interpretation of experimental results.

  8. A Concerted International Project to Establish High-Temperature Fixed Points for Primary Thermometry

    NASA Astrophysics Data System (ADS)

    Machin, G.; Bloembergen, P.; Hartmann, J.; Sadli, M.; Yamada, Y.

    2007-12-01

    Research into high-temperature fixed points above 1,100°C has made significant progress since they were first reported in 1999. In particular, it has been established that single cells are repeatable at the sub-50 mK level, and intra-cell reproducibility at the 100 mK level has been demonstrated even at temperatures as high as 2,500°C. The fixed points have been used to compare temperature and radiometry scales over a wide temperature range, and are being developed and established as secondary references for thermocouple calibrations. However, before they can be fully accepted as primary temperature references, much work remains to be done, namely: (1) Establishment of long-term stability of the fixed-point temperature; (2) Development of robust procedures for the reliable construction of the fixed-point cells (to ensure routine intra-cell reproducibility of 100 mK); (3) Demonstration of long-term robustness of the fixed-point cells; (4) Assignment of thermodynamic temperatures to a selected set of fixed points; (5) Agreement and acceptance of these temperature values by the CCT; (6) Agreed methods on how to take full utility of these new fixed points into any future International Temperature Scale (ITS)—or the current ITS-90 via an addendum to the mise en pratique for the definition of the kelvin. To ensure that this work progresses to completion in a reasonable time frame, a research project, under the auspices of the CCT-WG5, has been formulated and is currently in progress with the aim of achieving the above mentioned targets by 2012. This article will describe this project and detail partner contributions.

  9. Calibration and performance assessment of a temperature sensor prototype using a 1-point calibration procedure

    NASA Astrophysics Data System (ADS)

    Chapon, P. A.; Gauthier, A.; Bulla, J.; Moussay, S.

    2012-11-01

    This study aims to assess the relevance of 1-point calibration procedure, within the framework of the development of a new telemetric temperature sensor. The criteria used for performance assessment were the level of accuracy, and the time of inertia of the temperature sensor prototype (TSP) tested. First, the stability of the calibration bath was assessed. Then, the accuracy of 16 prototypes was evaluated for 7 target temperatures (ranging from 29 °C to 45 °C). Finally, the inertia of TSP response was evaluated while increasing and decreasing the bath temperature. The difference between prototype and target temperature increases as bath temperature moves away from 37 °C; however, the accuracy of the sensor conforms to applicable standards. Most TSP remain in the range of ±0.2 °C for each temperature level tested, but a linear, decreasing slope is observed; prototypes underestimate high temperatures and overestimate low temperatures. Data from time of inertia assessment show that probes were within the range of ±0.2 °C from the target temperature with a maximal delay of 150 s which satisfy standard norms. However, results indicate that a 1-point calibration procedure of the sensors appears non optimal, a 2-point calibration procedure should be performed to avoid the observed temperature data slope.

  10. High Temperature Gas-Cooled Test Reactor Point Design: Summary Report

    SciTech Connect

    Sterbentz, James William; Bayless, Paul David; Nelson, Lee Orville; Gougar, Hans David; Strydom, Gerhard

    2016-01-01

    A point design has been developed for a 200-MW high-temperature gas-cooled test reactor. The point design concept uses standard prismatic blocks and 15.5% enriched uranium oxycarbide fuel. Reactor physics and thermal-hydraulics simulations have been performed to characterize the capabilities of the design. In addition to the technical data, overviews are provided on the technology readiness level, licensing approach, and costs of the test reactor point design.

  11. Enhancements of Nucleate Boiling Under Microgravity Conditions

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Yang, W. J.

    2000-01-01

    This paper presents two means for enhancing nucleate boiling and critical heat flux under microgravity conditions: using micro-configured metal-graphite composites as the boiling surface and dilute aqueous solutions of long-chain alcohols as the working fluid. In the former, thermocapillary force induced by temperature difference between the graphite-fiber tips and the metal matrix plays an important role in bubble detachment. Thus boiling-heat transfer performance does not deteriorate in a reduced-gravity environment. In the latter cases, the surface tension-temperature gradient of the long-chain alcohol solutions turns positive as the temperature exceeds a certain value. Consequently, the Marangoni effect does not impede, but rather aids in bubble departure from the heating surface. This feature is most favorable in microgravity. As a result, the bubble size of departure is substantially reduced at higher frequencies. Based on the existing experimental data, and a two-tier theoretical model, correlation formulas are derived for nucleate boiling on the copper-graphite and aluminum-graphite composite surfaces, in both the isolated and coalesced bubble regimes. In addition, performance equations for nucleate boiling and critical heat flux in dilute aqueous solutions of long-chain alcohols are obtained.

  12. Study of structural break points in global and hemispheric temperature series by piecewise regression

    NASA Astrophysics Data System (ADS)

    Werner, Rolf; Valev, Dimitar; Danov, Dimitar; Guineva, Veneta

    2015-12-01

    The study of climate trends taking into consideration possible structural changes is important for understanding climate development characterized by a stochastic trend or by a determined one. In the paper global and hemisphere temperature anomalies are modeled by piecewise linear regression and break points in the temperature evolution are found. It was demonstrated that the used method allowed finding of breaks characterized by long time trends (low frequency processes) as well as abrupt changes (fast frequency processes). The obtained break points for slow temperature change are close to the ones found by other authors however additional conditions (as segment length, gradient and others) are not used here. The results for higher break point numbers are like the ones of step slope models. It was demonstrated that the successive phases of warming and cooling and most of the break points subdividing these periods in the Northern Hemisphere are introduced by the Atlantic multidecadal oscillation. Because the strong quasi periodicity of the Atlantic multidecadal oscillation the authors recommend the removal of its influence on the temperature from the temperature series before studies of trends or structural changes. The Northern Hemisphere temperature data after the removal of the Atlantic multidecadal oscillation influence show structures like the Southern Hemisphere temperatures. Model selection by the Schwarz-Bayesian Information Criterion developed by Liu, Wu and Zidek (LWZ criterion) shows that models with only one break point are to be preferred.

  13. Emergence of a Fermionic Finite-Temperature Critical Point in a Kondo Lattice

    NASA Astrophysics Data System (ADS)

    Chou, Po-Hao; Zhai, Liang-Jun; Chung, Chung-Hou; Mou, Chung-Yu; Lee, Ting-Kuo

    2016-04-01

    The underlying Dirac point is central to the profound physics manifested in a wide class of materials. However, it is often difficult to drive a system with Dirac points across the massless fermionic critical point. Here by exploiting screening of local moments under spin-orbit interactions in a Kondo lattice, we show that below the Kondo temperature, the Kondo lattice undergoes a topological transition from a strong topological insulator to a weak topological insulator at a finite temperature TD. At TD, massless Dirac points emerge and the Kondo lattice becomes a Dirac semimetal. Our analysis indicates that the emergent relativistic symmetry dictates nontrivial thermal responses over large parameter and temperature regimes. In particular, it yields critical scaling behaviors both in magnetic and transport responses near TD.

  14. Liquid crystal thermography in boiling heat transfer

    SciTech Connect

    Klausner, J.F.; Mei, R.; Chen, W.C.

    1995-12-31

    The utilization of liquid crystal thermography to study heterogeneous boiling phenomena has gained popularity in recent years. In order not to disturb the nucleation process, which occurs in the microstructure of the heating surface, the crystals are applied to the backside of a thin heater. This work critically examines the ability of liquid crystal thermography to quantitatively capture the thermal field on the boiling surface. The thermal field identified experimentally through liquid crystal thermography is compared against that computed in the vicinity of a growing vapor bubble using a simulation which considers the simultaneous heat transfer between three phases: the solid heater, the liquid microlayer, and the growing vapor bubble. The temperature history beneath a growing vapor bubble elucidates the high frequency response required to capture the transient thermal fields commonly encountered in boiling experiments. Examination of the governing equations and numerical results reveal that due to the heater thermal inertia, the temperature variation on the bottom of the heater is significantly different than that on the boiling surface. In addition, the crystals themselves have a finite spatial resolution and frequency response which filter out much of the microscale phenomenon associated with boiling heat transfer. Analysis of existing pool and flow boiling liquid crystal thermographs indicate that the typical spacial resolution is on the order of 0.25 mm and the response time is on the order of 5 ms which are insufficient to resolve the fine spacial and temporal details of the heating surface thermal field. Thus the data obtained from liquid crystal thermography applied to boiling heat transfer must be cautiously interpreted.

  15. Realization of the Temperature Scale in the Range from 234.3 K (Hg Triple Point) to 1084.62°C (Cu Freezing Point) in Croatia

    NASA Astrophysics Data System (ADS)

    Zvizdic, Davor; Veliki, Tomislav; Grgec Bermanec, Lovorka

    2008-06-01

    This article describes the realization of the International Temperature Scale in the range from 234.3 K (mercury triple point) to 1084.62°C (copper freezing point) at the Laboratory for Process Measurement (LPM), Faculty of Mechanical Engineering and Naval Architecture (FSB), University of Zagreb. The system for the realization of the ITS-90 consists of the sealed fixed-point cells (mercury triple point, water triple point and gallium melting point) and the apparatus designed for the optimal realization of open fixed-point cells which include the gallium melting point, tin freezing point, zinc freezing point, aluminum freezing point, and copper freezing point. The maintenance of the open fixed-point cells is described, including the system for filling the cells with pure argon and for maintaining the pressure during the realization.

  16. The entrance effect on subcooled boiling in heated channels

    SciTech Connect

    Kurul, N.; Podowski, M.Z. )

    1989-11-01

    One of the major problems in the analysis of diabatic two-phase flows concerns the effect of thermodynamic nonequilibrium between the phases. In particular, this effect applies to forced-convection subcooled boiling in boiling water reactors (BWRs). An approach commonly used to evaluate the void distribution along reactor coolant channels is based on one-dimensional models of combined two-phase flow and boiling heat transfer. In the subcooled boiling region, the rate of phase change is governed mainly by the lateral transport of the vapor phase toward the subcooled liquid; thus, the related processes cannot be mechanistically modeled by one-dimensional, axially dependent models. Consequently, most existing subcooled boiling models are based on experimental correlations for parameters such as the onset of nucleate boiling (ONB) and the net vapor generation rate. This paper presents the results of analysis of subcooled boiling phenomena in the developing flow region of a boiling channel, based on a mechanistic two-dimensional, two-fluid model. The effect of turbulence has been accounted for by a k-{epsilon} model. The PHOENICS code was used to solve the governing mass, momentum, and energy conservation equations in both the nonboiling and boiling regions. The parameters calculated by the model include radially and axially dependent distributions of the local void fraction, temperatures and velocities of both phases, and the axial distribution of wall temperature.

  17. Effect of Running Parameters on Flow Boiling Instabilities in Microchannels.

    PubMed

    Zong, Lu-Xiang; Xu, Jin-Liang; Liu, Guo-Hua

    2015-04-01

    Flow boiling instability (FBI) in microchannels is undesirable because they can induce the mechanical vibrations and disturb the heat transfer characteristics. In this study, the synchronous optical visualization experimental system was set up. The pure acetone liquid was used as the working fluid, and the parallel triangle silicon microchannel heat sink was designed as the experimental section. With the heat flux ranging from 0-450 kW/m2 the microchannel demand average pressure drop-heater length (Δp(ave)L) curve for constant low mass flux, and the demand pressure drop-mass flux (Δp(ave)G) curve for constant length on main heater surface were obtained and studied. The effect of heat flux (q = 188.28, 256.00, and 299.87 kW/m2), length of main heater surface (L = 4.5, 6.25, and 8.00 mm), and mass flux (G = 188.97, 283.45, and 377.94 kg/m2s) on pressure drops (Ap) and temperatures at the central point of the main heater surface (Twc) were experimentally studied. The results showed that, heat flux, length of the main heater surface, and mass flux were identified as the important parameters to the boiling instability process. The boiling incipience (TBI) and critical heat flux (CHF) were early induced for the lower mass flux or the main heater surface with longer length. With heat flux increasing, the pressure drops were linearly and slightly decreased in the single liquid region but increased sharply in the two phase flow region, in which the flow boiling instabilities with apparent amplitude and long period were more easily triggered at high heat flux. Moreover, the system pressure was increased with the increase of the heat flux. PMID:26353523

  18. Simulation study based on the single-point temperature monitoring system of LabVIEW

    NASA Astrophysics Data System (ADS)

    Wu, Yongling; Yang, Na; Liu, Shuping; Pan, Xiaohui; Wang, Wenjiang

    2014-12-01

    This paper takes LabVIEW2012 as a development platform, creating a J-type thermocouple sensor and the NI USB-6229 data acquisition card and other hardware emulation circuitry which combined with the PC designed a single-point temperature monitoring system. Through simulation experiments, the system has a collection interval, the sampling rate per channel sampling on the temperature limit set by the user function and it also has the function of real-time display the current temperature, the temperature limit alarm, maximum temperature, minimum temperature display and a temperature history data query. This system can be used for temperature monitoring of life, research, industrial control, environmental monitoring, biomedical, tobacco processing, greenhouse cultivation, livestock breeding and other fields, which has important significance and practical value.

  19. Critical heat flux and boiling heat transfer to water in a 3-mm-diameter horizontal tube.

    SciTech Connect

    Yu, W.; Wambsganss, M. W.; Hull, J. R.; France, D. M.

    2000-12-04

    Boiling of the coolant in an engine, by design or by circumstance, is limited by the critical heat flux phenomenon. As a first step in providing relevant engine design information, this study experimentally addressed both rate of boiling heat transfer and conditions at the critical point of water in a horizontal tube of 2.98 mm inside diameter and 0.9144 m heated length. Experiments were performed at system pressure of 203 kPa, mass fluxes in range of 50 to 200 kg/m{sup z}s, and inlet temperatures in range of ambient to 80 C. Experimental results and comparisons with predictive correlations are presented.

  20. Radiolysis of boiling water

    NASA Astrophysics Data System (ADS)

    Yang, Shuang; Katsumura, Yosuke; Yamashita, Shinichi; Matsuura, Chihiro; Hiroishi, Daisuke; Lertnaisat, Phantira; Taguchi, Mitsumasa

    2016-06-01

    γ-radiolysis of boiling water has been investigated. The G-value of H2 evolution was found to be very sensitive to the purity of water. In high-purity water, both H2 and O2 gases were formed in the stoichiometric ratio of 2:1; a negligible amount of H2O2 remained in the liquid phase. The G-values of H2 and O2 gas evolution depend on the dose rate: lower dose rates produce larger yields. To clarify the importance of the interface between liquid and gas phase for gas evolution, the gas evolution under Ar gas bubbling was measured. A large amount of H2 was detected, similar to the radiolysis of boiling water. The evolution of gas was enhanced in a 0.5 M NaCl aqueous solution. Deterministic chemical kinetics simulation elucidated the mechanism of radiolysis in boiling water.

  1. Electronic rhinological thermometer for three-point air temperature measurement in nasal cavity

    NASA Astrophysics Data System (ADS)

    ?nieg, Marcin; Paczesny, Daniel; Weremczuk, Jerzy

    2008-01-01

    This article describes the design and construction of diagnostic medical system for air temperature measurement in nasal cavity. Concept of three-point thermometer is connected with single point electronic thermometer for air temperature measurement in nasal cavity that was previously constructed [1]. Researches were done in Microsystems and Sensors Research Group (WUT) with cooperation of physicians and laryngologists from Otolaryngology Department, Military Medical Institute, Warsaw. Measurement system consist of microprocessor module which periodically collects samples of air temperature from different part of nasal cavity, measurement head with three temperature sensors, and computer software presenting on-line results, calculating breathing parameters and storing data in database. Air temperature is measured in nasal cavity, middle part cavity and nasopharynx during regular respiration process.

  2. Modeling of Aerobrake Ballute Stagnation Point Temperature and Heat Transfer to Inflation Gas

    NASA Technical Reports Server (NTRS)

    Bahrami, Parviz A.

    2012-01-01

    A trailing Ballute drag device concept for spacecraft aerocapture is considered. A thermal model for calculation of the Ballute membrane temperature and the inflation gas temperature is developed. An algorithm capturing the most salient features of the concept is implemented. In conjunction with the thermal model, trajectory calculations for two candidate missions, Titan Explorer and Neptune Orbiter missions, are used to estimate the stagnation point temperature and the inflation gas temperature. Radiation from both sides of the membrane at the stagnation point and conduction to the inflating gas is included. The results showed that the radiation from the membrane and to a much lesser extent conduction to the inflating gas, are likely to be the controlling heat transfer mechanisms and that the increase in gas temperature due to aerodynamic heating is of secondary importance.

  3. EVALUATION OF ROTARY KILN INCINERATOR OPERATION AT LOW TO MODERATE TEMPERATURE CONDITIONS VOLUME 1. TECHNICAL RESULTS

    EPA Science Inventory

    A test program was performed at the Environmental Protection Agency Incineration Research Facility to study the effectiveness of incineration at low-to-moderate temperatures in decontaminating soils containing organic compounds with different volatilities (boiling points). The da...

  4. Loop Heat Pipe Operation Using Heat Source Temperature for Set Point Control

    NASA Technical Reports Server (NTRS)

    Ku, Jentung; Paiva, Kleber; Mantelli, Marcia

    2011-01-01

    The LHP operating temperature is governed by the saturation temperature of its reservoir. Controlling the reservoir saturation temperature is commonly accomplished by cold biasing the reservoir and using electrical heaters to provide the required control power. Using this method, the loop operating temperature can be controlled within +/- 0.5K. However, because of the thermal resistance that exists between the heat source and the LHP evaporator, the heat source temperature will vary with its heat output even if LHP operating temperature is kept constant. Since maintaining a constant heat source temperature is of most interest, a question often raised is whether the heat source temperature can be used for LHP set point temperature control. A test program with a miniature LHP has been carried out to investigate the effects on the LHP operation when the control temperature sensor is placed on the heat source instead of the reservoir. In these tests, the LHP reservoir is cold-biased and is heated by a control heater. Tests results show that it is feasible to use the heat source temperature for feedback control of the LHP operation. Using this method, the heat source temperature can be maintained within a tight range for moderate and high powers. At low powers, however, temperature oscillations may occur due to interactions among the reservoir control heater power, the heat source mass, and the heat output from the heat source. In addition, the heat source temperature could temporarily deviate from its set point during fast thermal transients. The implication is that more sophisticated feedback control algorithms need to be implemented for LHP transient operation when the heat source temperature is used for feedback control.

  5. Temperature comparison of initial, middle and final point of polypropylene friction stir welded

    NASA Astrophysics Data System (ADS)

    Kusharjanta, Bambang; Raharjo, Wahyu P.; Triyono

    2016-03-01

    Friction Stir Welding is known as a new solid state joining process. This process is applied in thermoplastic polymers material recently. One of member thermoplastic polymer is polypropylene. Polypropylene sheet 6 mm thick was friction stir welded with a cone cut steel pin. Tool rotation, travelling speed, and plunge depth, as welding parameters were 620 rpm, 7.3 mm/minutes and 0.02 mm respectively. Temperature at the initial, middle, and final point of advance side working piece were measured and compared. Measurement were done by thermocouple and recorded by data acquisition. Based on this research, it is concluded that temperature at the initial, middle and final point of friction stir welding process are different. The highest temperature peak reach at the middle point on the advance side which affects face bending strength.

  6. A Method to Improve the Temperature Distribution of Holder Around the Fixed-Point Cell Position

    NASA Astrophysics Data System (ADS)

    Lim, S. D.; Karmalawi, A. M.; Salim, S. G. R.; Soliman, M. A.; Kim, B. H.; Lee, D. H.; Yoo, Y. S.

    2014-07-01

    The temperature profile along the furnaces used in heating high-temperature fixed points has a crucial impact on the quality and duration of melting plateaux, accordingly the accuracy of thermodynamic temperature determination of such fixed points. This paper describes a simple, yet efficient, approach for improving the temperature uniformity along a cell holder in high-temperature blackbody (HTBB) furnaces that use pyrolytic graphite rings as heating elements. The method has been applied on the KRISS' HTBB furnace. In this work, an ideal solution for arranging the heating elements inside the furnace is presented by which the temperature gradient across the cell holder can be kept as low as possible. Numerical calculations, based on a finite element method, have been carried out to find the best possible arrangement of the rings. This has been followed by measuring the temperature gradient along an empty cell holder to validate our calculations. A temperature gradient of 100 mK has been achieved at over a length of 50 mm within a cell holder of 10 cm in length. It has also been shown that for a 20 cm long holder surrounded by rings with an arbitrary resistance profile, the temperature uniformity can be improved by adding a few "hot" rings around the cell holder.

  7. A Fundamental Study of Nucleate Pool Boiling Under Microgravity

    NASA Technical Reports Server (NTRS)

    Ervin, Jamie S.; Merte, Herman, Jr.

    1996-01-01

    An experimental study of incipient boiling in short-term microgravity and with a/g = +/- 1 for pool boiling was performed. Calibrated thin gold films sputtered on a smoothly polished quartz surface were used simultaneously for thermal-resistance measurements and heating of the boiling surface. The gold films were used for both transient and quasi-steady heating surface temperature measurements. Two test vessels were constructed for precise measurement and control of fluid temperature and pressure: a laboratory pool boiling vessel for the a/g = +/- 1 experiments and a pool boiling vessel designed for the 131 m free-fall in the NASA Lewis Research Center Microgravity Research Facility for the microgravity tests. Measurements included the heater surface temperature, the pressure near the heating surface, the bulk liquid temperatures. High speed photography (up to 1,000 frames per second) was used in the experiments. With high quality microgravity and the measured initial temperature of the quiescent test fluid, R113, the temperature distribution in the liquid at the moment of boiling inception resulting from an imposed step in heat flux is known with a certainty not possible previously. The types of boiling propagation across the large flat heating surface, some observed here for the first time, are categorized; the conditions necessary for their occurrence are described. Explosive boiling propagation with a striking pattern of small scale protuberances over the entire vapor mass periphery not observed previously at low heat flux levels (on the order of 5 W/cm(exp 2)) is described. For the heater surface with a/g = -1, a step in the heater surface temperature of short duration was imposed. The resulting liquid temperature distribution at the moment of boiling inception was different from that obtained with a step in heat flux.

  8. A fundamental study of nucleate pool boiling under microgravity

    NASA Technical Reports Server (NTRS)

    Ervin, Jamie S.; Merte, Herman, Jr.

    1991-01-01

    An experimental study of incipient boiling in short-term microgravity and with a/g = +/- 1 for pool boiling was performed. Calibrated thin gold films sputtered on a smoothly polished quartz surface were used simultaneously for thermal resistance measurements and heating of the boiling surface. The gold films were used for both transient and quasi-steady heating surface temperature measurements. Two test vessels were constructed for precise measurement and control of fluid temperature and pressure: a laboratory pool boiling vessel for the a/g = +/- experiments and a pool boiling vessel designed for the 131 m free-fall in the NASA Lewis Research Center Microgravity Research Facility for the microgravity tests. Measurements included the heater surface temperature, the pressure near the heating surface, and the bulk liquid temperatures. High speed photography was used in the experiments. With high quality microgravity and the measured initial temperature of the quiescent test fluid, R113, the temperature distribution in the liquid at the moment of boiling inception resulting from an imposed step in heat flux is known with a certainty not possible previously. The types of boiling propagation across the large flat heating surface are categorized; the conditions necessary for their occurrence are described. Explosive boiling propagation with a striking pattern of small scale protuberances over the entire vapor mass periphery not observed previously at low heat flux levels is described. For the heater surface with a/g = -1, a step in the heater surface temperature of short duration was imposed. The resulting liquid temperature distribution at the moment of boiling inception was different from that obtained with a step in heat flux.

  9. Cryogenic Boil-Off Reduction System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, David W.; Johnson, Wesley L.; Feller, Jeffery

    2014-01-01

    The Cryogenic Boil-Off Reduction System was tested with LH2 and LOX in a vacuum chamber to simulate space vacuum and the temperatures of low Earth orbit. Testing was successful and results validated the scaling study model that predicts active cooling reduces upper stage cryogenic propulsion mass for loiter periods greater than 2 weeks.

  10. Stability of electric heaters in the boiling heat transfer process

    SciTech Connect

    Loeffler, R.I.

    1991-01-01

    Boiling heat transfer from electrically heated wires and composite heaters was studied in the three boiling regimes; nucleate, transition, and film. The electrical input to the heaters was controlled by the heater temperature through the use of feedback control techniques. Particular attention was paid to the transition region of the boiling curve where the slope is negative and operation is unstable without proper control. Boiling curves produced by an x-ray plotter are presented for gold-plated tungsten wires and also for platinum wires. Stability conditions and transfer functions were developed for a complete composite heater system. Steady-state operation in the transition region of the boiling curve clearly demonstrates that there are two separate transition curves depending on whether the temperature is increasing or decreasing.

  11. Estimation of dew point temperature using neuro-fuzzy and neural network techniques

    NASA Astrophysics Data System (ADS)

    Kisi, Ozgur; Kim, Sungwon; Shiri, Jalal

    2013-11-01

    This study investigates the ability of two different artificial neural network (ANN) models, generalized regression neural networks model (GRNNM) and Kohonen self-organizing feature maps neural networks model (KSOFM), and two different adaptive neural fuzzy inference system (ANFIS) models, ANFIS model with sub-clustering identification (ANFIS-SC) and ANFIS model with grid partitioning identification (ANFIS-GP), for estimating daily dew point temperature. The climatic data that consisted of 8 years of daily records of air temperature, sunshine hours, wind speed, saturation vapor pressure, relative humidity, and dew point temperature from three weather stations, Daego, Pohang, and Ulsan, in South Korea were used in the study. The estimates of ANN and ANFIS models were compared according to the three different statistics, root mean square errors, mean absolute errors, and determination coefficient. Comparison results revealed that the ANFIS-SC, ANFIS-GP, and GRNNM models showed almost the same accuracy and they performed better than the KSOFM model. Results also indicated that the sunshine hours, wind speed, and saturation vapor pressure have little effect on dew point temperature. It was found that the dew point temperature could be successfully estimated by using T mean and R H variables.

  12. Analysis of Screen Channel LAD Bubble Point Tests in Liquid Oxygen at Elevated Temperature

    NASA Technical Reports Server (NTRS)

    Hartwig, Jason; McQuillen, John

    2011-01-01

    The purpose of this paper is to examine the key parameters that affect the bubble point pressure for screen channel Liquid Acquisition Devices in cryogenic liquid oxygen at elevated pressures and temperatures. An in depth analysis of the effect of varying temperature, pressure, and pressurization gas on bubble point is presented. Testing of a 200 x 1400 and 325 x 2300 Dutch Twill screen sample was conducted in the Cryogenics Components Lab 7 facility at the NASA Glenn Research Center in Cleveland, Ohio. Test conditions ranged from 92 to 130K and 0.138 - 1.79 MPa. Bubble point is shown to be a strong function of temperature with a secondary dependence on pressure. The pressure dependence is believed to be a function of the amount of evaporation and condensation occurring at the screen. Good agreement exists between data and theory for normally saturated liquid but the model generally under predicts the bubble point in subcooled liquid. Better correlation with the data is obtained by using the liquid temperature at the screen to determine surface tension of the fluid, as opposed to the bulk liquid temperature.

  13. Microwave-Assisted Superheating and/or Microwave-Specific Superboiling (Nucleation-Limited Boiling) of Liquids Occurs under Certain Conditions but is Mitigated by Stirring.

    PubMed

    Ferrari, Anthony; Hunt, Jacob; Stiegman, Albert; Dudley, Gregory B

    2015-01-01

    Temporary superheating and sustained nucleation-limited "superboiling" of unstirred liquids above the normal atmospheric boiling point have been documented during microwave heating. These phenomena are reliably observed under prescribed conditions, although the duration (of superheating) and magnitude (of superheating and superboiling) vary according to system parameters such as volume of the liquid and the size and shape of the vessel. Both phenomena are mitigated by rapid stirring with an appropriate stir bar and/or with the addition of boiling chips, which provide nucleation sites to support the phase-change from liquid to gas. With proper experimental design and especially proper stirring, the measured temperature of typical organic reaction mixtures heated at reflux will be close to the normal boiling point temperature of the solvent, whether heated using microwave radiation or conventional convective heat transfer. These observations are important to take into consideration when comparing reaction rates under conventional and microwave heating. PMID:26690096

  14. Numerical Investigation of Boiling

    NASA Astrophysics Data System (ADS)

    Sagan, Michael; Tanguy, Sebastien; Colin, Catherine

    2012-11-01

    In this work, boiling is numerically investigated, using two phase flow direct numerical simulation based on a level set / Ghost Fluid method. Nucleate boiling implies both thermal issue and multiphase dynamics issues at different scales and at different stages of bubble growth. As a result, the different phenomena are investigated separately, considering their nature and the scale at which they occur. First, boiling of a static bubble immersed in an overheated liquid is analysed. Numerical simulations have been performed at different Jakob numbers in the case of strong density discontinuity through the interface. The results show a good agreement on bubble radius evolution between the theoretical evolution and numerical simulation. After the validation of the code for the Scriven test case, interaction of a bubble with a wall is studied. A numerical method taking into account contact angle is evaluated by comparing simulations of the spreading of a liquid droplet impacting on a plate, with experimental data. Then the heat transfer near the contact line is investigated, and simulations of nucleate boiling are performed considering different contact angles values. Finally, the relevance of including a model to take into account the evaporation of the micro layer is discussed.

  15. Temperature and Species Measurements of Combustion Produced by a 9-Point Lean Direct Injector

    NASA Technical Reports Server (NTRS)

    Tedder, Sarah A.; Hicks, Yolanda R.; Locke, Randy J.

    2013-01-01

    This paper presents measurements of temperature and relative species concentrations in the combustion flowfield of a 9-point swirl venturi lean direct injector fueled with JP-8. The temperature and relative species concentrations of the flame produced by the injector were measured using spontaneous Raman scattering (SRS). Results of measurements taken at four flame conditions are presented. The species concentrations reported are measured relative to nitrogen and include oxygen, carbon dioxide, and water.

  16. Progress report for the CCT-WG5 high temperature fixed point research plan

    SciTech Connect

    Machin, G.; Woolliams, E. R.; Anhalt, K.; Bloembergen, P.; Sadli, M.; Yamada, Y.

    2013-09-11

    An overview of the progress in High Temperature Fixed Point (HTFP) research conducted under the auspices of the CCT-WG5 research plan is reported. In brief highlights are: Provisional long term stability of HTFPs has been demonstrated. Optimum construction methods for HTFPs have been established and high quality HTFPs of Co-C, Pt-C and Re-C have been constructed for thermodynamic temperature assignment. The major sources of uncertainty in the assignment of thermodynamic temperature have been identified and quantified. The status of absolute radiometric temperature measurement has been quantified through the circulation of a set of HTFPs. The measurement campaign to assign low uncertainty thermodynamic temperatures to a selected set of HTFPs will begin in mid-2012. It is envisaged that this will be complete by 2015 leading to HTFPs becoming routine reference standards for radiometry and high temperature metrology.

  17. Experimental study on the onset of nucleate boiling in narrow channel by using grey relational analysis (GRA)

    NASA Astrophysics Data System (ADS)

    Han, Dong; Gao, Puzhen; Yan, Liming; Lv, Lulu

    2013-07-01

    The point of ONB (Onset of Nucleate Boiling) is a key point of boiling heat transfer in narrow channels. Due to the special structure and complex flow, the points of ONB in narrow channels are affected by many factors, their characteristics are not understood completely yet. In order to study relevant influence factors on ONB in narrow channel from the aspect of quantitative analysis, GRA (Grey Relational Analysis) is applied to analyze the experimental data of ONB in narrow channel by taking water as the working fluid. And then the intensity sequence of the factors that have effects on ONB are confirmed as the heat flux, outlet dryness, pressure, mass flow rate, inlet temperature and outlet temperature. Through analyzing the data of ONB of newly published literatures, the mechanisms for the main influence factors are suggested.

  18. Three-point function at finite temperature in the real-time formalism

    NASA Astrophysics Data System (ADS)

    Kobes, R.

    1991-09-01

    One-particle-irreducible amputated graphs differ qualitatively at finite temperature when calculated in the imaginary-time and real-time formalisms. Here we show within the real-time formalism for the three-point function that when external propagators are attached certain amputated functions can be inferred which have a close relation to those of the imaginary-time formalism.

  19. Measurement of Sticky Point Temperature of Coffee Powder with a Rheometer

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Sticky point temperature (Ts) measurement for hygroscopic food and biomaterial powders is traditionally performed with complex glass instruments. This property is used to characterize material stickiness, which substantially affects the flow and physical behavior of powders. In this research study w...

  20. Three-point function at finite temperature in the real-time formalism

    SciTech Connect

    Kobes, R. )

    1991-09-09

    One-particle-irreducible amputated graphs differ qualitatively at finite temperature when calculated in the imaginary-time and real-time formalisms. Here we show within the real-time formalism for the three-point function that when external propagators are attached certain amputated functions can be inferred which have a close relation to those of the imaginary-time formalism.

  1. A probe for measuring temperature and pressure at the same points in a gas stream

    NASA Technical Reports Server (NTRS)

    Krause, L. N.; Glawe, G. E.; Dudzinski, T. J.

    1972-01-01

    Design features and characteristics of a means for measuring total temperature and total pressure at a single point in a gas stream are presented. A rake that provides five such combination measurements is described. Experimental data are included for the aerodynamic recovery and time response of the temperature sensor and for the flow-angle sensitivity of both the temperature and pressure sensors. Data were obtained over a subsonic Mach number range of 0.3 to 0.9 as well as at a Mach number of 1.4.

  2. Development of a new radiometer for the thermodynamic measurement of high temperature fixed points

    SciTech Connect

    Dury, M. R.; Goodman, T. M.; Lowe, D. H.; Machin, G.; Woolliams, E. R.

    2013-09-11

    The National Physical Laboratory (NPL) has developed a new radiometer to measure the thermodynamic melting point temperatures of high temperature fixed points with ultra-low uncertainties. In comparison with the NPL's Absolute Radiation Thermometer (ART), the 'THermodynamic Optical Radiometer' (THOR) is more portable and compact, with a much lower size-of-source effect and improved performance in other parameters such as temperature sensitivity. It has been designed for calibration as a whole instrument via the radiance method, removing the need to calibrate the individual subcomponents, as required by ART, and thereby reducing uncertainties. In addition, the calibration approach has been improved through a new integrating sphere that has been designed to have greater uniformity.

  3. Analysis of Screen Channel LAD Bubble Point Tests in Liquid Methane at Elevated Temperature

    NASA Technical Reports Server (NTRS)

    Hartwig, Jason; McQuillen, John

    2012-01-01

    This paper examines the effect of varying the liquid temperature and pressure on the bubble point pressure for screen channel Liquid Acquisition Devices in cryogenic liquid methane using gaseous helium across a wide range of elevated pressures and temperatures. Testing of a 325 x 2300 Dutch Twill screen sample was conducted in the Cryogenic Components Lab 7 facility at the NASA Glenn Research Center in Cleveland, Ohio. Test conditions ranged from 105 to 160K and 0.0965 - 1.78 MPa. Bubble point is shown to be a strong function of the liquid temperature and a weak function of the amount of subcooling at the LAD screen. The model predicts well for saturated liquid but under predicts the subcooled data.

  4. Development of a new radiometer for the thermodynamic measurement of high temperature fixed points

    NASA Astrophysics Data System (ADS)

    Dury, M. R.; Goodman, T. M.; Lowe, D. H.; Machin, G.; Woolliams, E. R.

    2013-09-01

    The National Physical Laboratory (NPL) has developed a new radiometer to measure the thermodynamic melting point temperatures of high temperature fixed points with ultra-low uncertainties. In comparison with the NPL's Absolute Radiation Thermometer (ART), the "THermodynamic Optical Radiometer" (THOR) is more portable and compact, with a much lower size-of-source effect and improved performance in other parameters such as temperature sensitivity. It has been designed for calibration as a whole instrument via the radiance method, removing the need to calibrate the individual subcomponents, as required by ART, and thereby reducing uncertainties. In addition, the calibration approach has been improved through a new integrating sphere that has been designed to have greater uniformity.

  5. Improvements in the realization of the ITS-90 over the temperature range from the melting point of gallium to the freezing point of silver at NIM

    SciTech Connect

    Sun, J.; Zhang, J. T.; Ping, Q.

    2013-09-11

    The temperature primary standard over the range from the melting point of gallium to the freezing point of silver in National institute of Metrology (NIM), China, was established in the early 1990s. The performance of all of fixed-point furnaces degraded and needs to be updated due to many years of use. Nowadays, the satisfactory fixed point materials can be available with the development of the modern purification techniques. NIM plans to use a group of three cells for each defining fixed point temperature. In this way the eventual drift of individual cells can be evidenced by periodic intercomparison and this will increase the reliability in disseminating the ITS-90 in China. This article describes the recent improvements in realization of ITS-90 over temperature range from the melting point of gallium to the freezing point of silver at NIM. Taking advantages of the technological advances in the design and manufacture of furnaces, the new three-zone furnaces and the open-type fixed points were developed from the freezing point of indium to the freezing point of silver, and a furnace with the three-zone semiconductor cooling was designed to automatically realize the melting point of gallium. The reproducibility of the new melting point of gallium and the new open-type freezing points of In, Sn, Zn. Al and Ag is improved, especially the freezing points of Al and Ag with the reproducibility of 0.2mK and 0.5mK respectively. The expanded uncertainty in the realization of these defining fixed point temperatures is 0.34mK, 0.44mK, 0.54mK, 0.60mK, 1.30mK and 1.88mK respectively.

  6. Improvements in the realization of the ITS-90 over the temperature range from the melting point of gallium to the freezing point of silver at NIM

    NASA Astrophysics Data System (ADS)

    Sun, J.; Zhang, J. T.; Ping, Q.

    2013-09-01

    The temperature primary standard over the range from the melting point of gallium to the freezing point of silver in National institute of Metrology (NIM), China, was established in the early 1990s. The performance of all of fixed-point furnaces degraded and needs to be updated due to many years of use. Nowadays, the satisfactory fixed point materials can be available with the development of the modern purification techniques. NIM plans to use a group of three cells for each defining fixed point temperature. In this way the eventual drift of individual cells can be evidenced by periodic intercomparison and this will increase the reliability in disseminating the ITS-90 in China. This article describes the recent improvements in realization of ITS-90 over temperature range from the melting point of gallium to the freezing point of silver at NIM. Taking advantages of the technological advances in the design and manufacture of furnaces, the new three-zone furnaces and the open-type fixed points were developed from the freezing point of indium to the freezing point of silver, and a furnace with the three-zone semiconductor cooling was designed to automatically realize the melting point of gallium. The reproducibility of the new melting point of gallium and the new open-type freezing points of In, Sn, Zn. Al and Ag is improved, especially the freezing points of Al and Ag with the reproducibility of 0.2mK and 0.5mK respectively. The expanded uncertainty in the realization of these defining fixed point temperatures is 0.34mK, 0.44mK, 0.54mK, 0.60mK, 1.30mK and 1.88mK respectively.

  7. Evaluation of engine coolants under flow boiling conditions

    SciTech Connect

    McAssey, E.V. Jr.; Stinson, C.; Gollin, M.

    1995-12-31

    An experimental program has been conducted to evaluate the heat transfer performance of two engine coolant mixtures, propylene-glycol/water and ethylene-glycol/water. In each mixture, the concentration was 50-50 by volume. Performance in this situation is defined as the ability to maintain a lower surface temperature for a given flux. The heat transfer regimes considered covered the range from single phase forced convection through saturated flow boiling. Results show that both coolants perform satisfactorily. However, in single phase convection, ethylene-glycol/water is slightly more effective. Conversely, for sub-cooled nucleate boiling and saturated boiling, propylene-glycol/water results in slightly lower metal temperatures.

  8. Optimization of the thermogauge furnace for realizing high temperature fixed points

    SciTech Connect

    Wang, T.; Dong, W.; Liu, F.

    2013-09-11

    The thermogauge furnace was commonly used in many NMIs as a blackbody source for calibration of the radiation thermometer. It can also be used for realizing the high temperature fixed point(HTFP). According to our experience, when realizing HTFP we need the furnace provide relative good temperature uniformity to avoid the possible damage to the HTFP. To improve temperature uniformity in the furnace, the furnace tube was machined near the tube ends with a help of a simulation analysis by 'ansys workbench'. Temperature distributions before and after optimization were measured and compared at 1300 °C, 1700°C, 2500 °C, which roughly correspond to Co-C(1324 °C), Pt-C(1738 °C) and Re-C(2474 °C), respectively. The results clearly indicate that through machining the tube the temperature uniformity of the Thermogage furnace can be remarkably improved. A Pt-C high temperature fixed point was realized in the modified Thermogauge furnace subsequently, the plateaus were compared with what obtained using old heater, and the results were presented in this paper.

  9. Turning bubbles on and off during boiling using charged surfactants

    NASA Astrophysics Data System (ADS)

    Cho, H. Jeremy; Mizerak, Jordan P.; Wang, Evelyn N.

    2015-10-01

    Boiling--a process that has powered industries since the steam age--is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature or steam generation cannot be adjusted for a given heat input. Here we report the ability to turn bubbles `on and off' independent of heat input during boiling both temporally and spatially via molecular manipulation of the boiling surface. As a result, we can rapidly and reversibly alter heat transfer performance up to an order of magnitude. Our experiments show that this active control is achieved by electrostatically adsorbing and desorbing charged surfactants to alter the wettability of the surface, thereby affecting nucleation. This approach can improve performance and flexibility in existing boiling technologies as well as enable emerging or unprecedented energy applications.

  10. Little low-power boiling never hurt anybody. [LMFBR

    SciTech Connect

    Dunn, F.E.

    1985-01-01

    Failures in the shutdown heat removal system of an LMFBR might lead to flow stagnation and coolant boiling in the reactor core. At normal operating power, the onset of sodium boiling will lead to film dryout and melting of the cladding and fuel within a few seconds. On the other hand, both calculations and currently available experimental data indicate that at heat fluxes corresponding to decay heat power levels, boiling leads to improved heat removal; and it limits the temperature rise in the fuel pins. Therefore, when setting safety criteria for decay heat removal systems, there is no reason to preclude sodium boiling per se because of heat removal considerations. As an example that illustrates the beneficial impact of coolant boiling, a case involving temporary loss of feedwater and staggered pump failures in a hypothetical, 1000-MWe loop-type reactor was run in the SASSYS-1 code.

  11. Boiling on Microconfigured Composite Surfaces Enhanced

    NASA Technical Reports Server (NTRS)

    Chao, David F.

    2000-01-01

    Boiling heat transfer is one of the key technologies for the two-phase active thermal-control system used on space platforms, as well as for the dynamic power systems aboard the International Space Station. Because it is an effective heat transfer mode, boiling is integral to many space applications, such as heat exchangers and other cooling devices. Nucleate boiling near the critical heat flux (CHF) can transport very large thermal loads with a much smaller device and much lower pumping power than for single-phase heat exchangers. However, boiling performance sharply deteriorates in a reduced-gravity environment, and operation in the CHF regime is somewhat perilous because of the risk of burnout to the device surface. New materials called microconfigured metal-graphite composites can enhance boiling. The photomicrograph shows the microconfiguration (x3000) of the copper-graphite (Cu-Gr) surface as viewed by scanning electronic microscope. The graphite fiber tips appear as plateaus with rugged surfaces embedded in the copper matrix. It has been experimentally demonstrated that this type of material manifests excellent boiling heat transfer performance characteristics and an increased CHF. Nonisothermal surfaces were less sensitive to variations of wall superheat in the CHF regime. Because of the great difference in conductivity between the copper base and the graphite fiber, the composite surfaces have a nonisothermal surface characteristic and, therefore, will have a much larger "safe" operating region in the CHF regime. In addition, the thermocapillary forces induced by the temperature differences between the fiber tips and the metal matrix play an important role in bubble detachment, and may not be adversely affected in a reduced-gravity environment. All these factors indicate that microconfigured composites may improve the reliability and economy (dominant factors in all space applications) of various thermal components found on spacecraft during future missions.

  12. Liquid Oxygen Liquid Acquisition Device Bubble Point Tests with High Pressure LOX at Elevated Temperatures

    NASA Technical Reports Server (NTRS)

    Jurns, John M.; Hartwig, Jason W.

    2011-01-01

    When transferring propellant in space, it is most efficient to transfer single phase liquid from a propellant tank to an engine. In earth s gravity field or under acceleration, propellant transfer is fairly simple. However, in low gravity, withdrawing single-phase fluid becomes a challenge. A variety of propellant management devices (PMD) are used to ensure single-phase flow. One type of PMD, a liquid acquisition device (LAD) takes advantage of capillary flow and surface tension to acquire liquid. The present work reports on testing with liquid oxygen (LOX) at elevated pressures (and thus temperatures) (maximum pressure 1724 kPa and maximum temperature 122K) as part of NASA s continuing cryogenic LAD development program. These tests evaluate LAD performance for LOX stored in higher pressure vessels that may be used in propellant systems using pressure fed engines. Test data shows a significant drop in LAD bubble point values at higher liquid temperatures, consistent with lower liquid surface tension at those temperatures. Test data also indicates that there are no first order effects of helium solubility in LOX on LAD bubble point prediction. Test results here extend the range of data for LOX fluid conditions, and provide insight into factors affecting predicting LAD bubble point pressures.

  13. Point-of-care temperature and respiration monitoring sensors for smart fabric applications

    NASA Astrophysics Data System (ADS)

    Jung, Soyoun; Ji, Taeksoo; Varadan, Vijay K.

    2006-12-01

    Advances in smart sensors, miniaturization, and related technologies leading to the emergence of smart fabrics are prerequisites to the construction of a point-of-care (POC) system for continuous health monitoring and illness prevention. Low manufacturing cost, light weight, portability and flexibility are among the requirements for smart sensors when embedded into smart fabrics. Organic semiconductor technology has recently been envisioned to meet these requirements, and to encourage the development of organic semiconductor based sensors because of its low process temperature and potential for very low cost manufacturing. In this paper, we present flexible sensors based on an organic semiconductor capable of measuring physiological parameters such as strain and temperature, adopting pentacene thin film transistors (TFTs) and Wheatstone bridge structures. It is expected that these sensors, integrated into textile structures, will enable real time POC monitoring of a patient's respiration rate, skin temperature, body heat flow and body temperature at an early stage.

  14. Experimental study on subcooled flow boiling on heating surfaces with different thermal conductivities

    NASA Astrophysics Data System (ADS)

    Zou, Ling

    Subcooled flow boiling is generally characterized by high heat transfer capacity and low wall superheat, which is essential for cooling applications requiring high heat transfer rate, such as nuclear reactors and fossil boilers. In this study, subcooled flow boiling on copper and stainless steel heating surfaces was experimentally investigated from both macroscopic and microscopic points of view. Flow boiling heat flux and heat transfer coefficient were experimentally measured on both surfaces under different conditions, such as pressure, flow rate and inlet subcooling. Significant boiling heat transfer coefficient differences were found between the copper and the stainless steel heating surfaces. To explain the different flow boiling behaviors on these two heating surfaces, nucleation site density and bubble dynamics were visually observed and measured at different experimental conditions utilizing a high-speed digital video camera. These two parameters are believed to be keys in determining flow boiling heat flux. Wall superheat, critical cavity size and wall heat flux were used to correlate with nucleation site density data. Among them, wall heat flux shows the best correlation for eliminating both pressure and surface property effects. The observed nucleation site distribution shows a random distribution. When compared to the spatial Poisson distribution, similarity between them was found, while the measured nucleation site distribution is more uniform. From experimental observations, for the two surface materials investigated, which have similar surface wettability but sharply different thermal properties, bubble dynamics displayed fairly similar behavior. The obtained experimental results indicate that thermal conductivity of heating surface material plays an important role in boiling heat transfer. This is due to thermal conductivity having a significant impact on the lateral heat conduction at the heating surface and consequently temperature uniformity of the heating surface. A model was then developed and solved numerically for heat conduction at the heating surface when bubbles are present. Several key parameters which impact lateral heat conduction and surface temperature profile were studied. These parameters include material thermal conductivity, bubble size, heating surface thickness, etc. Numerical results show that, temperature profile on the heating surface tends to be more uniform and have a lower average value on a heating surface with higher thermal conductivity, which agrees well with the experimental observation.

  15. Dynamic Performance of Maximum Power Point Trackers in TEG Systems Under Rapidly Changing Temperature Conditions

    NASA Astrophysics Data System (ADS)

    Man, E. A.; Sera, D.; Mathe, L.; Schaltz, E.; Rosendahl, L.

    2016-03-01

    Characterization of thermoelectric generators (TEG) is widely discussed and equipment has been built that can perform such analysis. One method is often used to perform such characterization: constant temperature with variable thermal power input. Maximum power point tracking (MPPT) methods for TEG systems are mostly tested under steady-state conditions for different constant input temperatures. However, for most TEG applications, the input temperature gradient changes, exposing the MPPT to variable tracking conditions. An example is the exhaust pipe on hybrid vehicles, for which, because of the intermittent operation of the internal combustion engine, the TEG and its MPPT controller are exposed to a cyclic temperature profile. Furthermore, there are no guidelines on how fast the MPPT must be under such dynamic conditions. In the work discussed in this paper, temperature gradients for TEG integrated in several applications were evaluated; the results showed temperature variation up to 5°C/s for TEG systems. Electrical characterization of a calcium-manganese oxide TEG was performed at steady-state for different input temperatures and a maximum temperature of 401°C. By using electrical data from characterization of the oxide module, a solar array simulator was emulated to perform as a TEG. A trapezoidal temperature profile with different gradients was used on the TEG simulator to evaluate the dynamic MPPT efficiency. It is known that the perturb and observe (P&O) algorithm may have difficulty accurately tracking under rapidly changing conditions. To solve this problem, a compromise must be found between the magnitude of the increment and the sampling frequency of the control algorithm. The standard P&O performance was evaluated experimentally by using different temperature gradients for different MPPT sampling frequencies, and efficiency values are provided for all cases. The results showed that a tracking speed of 2.5 Hz can be successfully implemented on a TEG system to provide ˜95% MPPT efficiency when the input temperature is changing at 5°C/s.

  16. Dynamic Performance of Maximum Power Point Trackers in TEG Systems Under Rapidly Changing Temperature Conditions

    NASA Astrophysics Data System (ADS)

    Man, E. A.; Sera, D.; Mathe, L.; Schaltz, E.; Rosendahl, L.

    2015-09-01

    Characterization of thermoelectric generators (TEG) is widely discussed and equipment has been built that can perform such analysis. One method is often used to perform such characterization: constant temperature with variable thermal power input. Maximum power point tracking (MPPT) methods for TEG systems are mostly tested under steady-state conditions for different constant input temperatures. However, for most TEG applications, the input temperature gradient changes, exposing the MPPT to variable tracking conditions. An example is the exhaust pipe on hybrid vehicles, for which, because of the intermittent operation of the internal combustion engine, the TEG and its MPPT controller are exposed to a cyclic temperature profile. Furthermore, there are no guidelines on how fast the MPPT must be under such dynamic conditions. In the work discussed in this paper, temperature gradients for TEG integrated in several applications were evaluated; the results showed temperature variation up to 5°C/s for TEG systems. Electrical characterization of a calcium-manganese oxide TEG was performed at steady-state for different input temperatures and a maximum temperature of 401°C. By using electrical data from characterization of the oxide module, a solar array simulator was emulated to perform as a TEG. A trapezoidal temperature profile with different gradients was used on the TEG simulator to evaluate the dynamic MPPT efficiency. It is known that the perturb and observe (P&O) algorithm may have difficulty accurately tracking under rapidly changing conditions. To solve this problem, a compromise must be found between the magnitude of the increment and the sampling frequency of the control algorithm. The standard P&O performance was evaluated experimentally by using different temperature gradients for different MPPT sampling frequencies, and efficiency values are provided for all cases. The results showed that a tracking speed of 2.5 Hz can be successfully implemented on a TEG system to provide ˜95% MPPT efficiency when the input temperature is changing at 5°C/s.

  17. Estimation of the global average temperature with optimally weighted point gauges

    NASA Technical Reports Server (NTRS)

    Hardin, James W.; Upson, Robert B.

    1993-01-01

    This paper considers the minimum mean squared error (MSE) incurred in estimating an idealized Earth's global average temperature with a finite network of point gauges located over the globe. We follow the spectral MSE formalism given by North et al. (1992) and derive the optimal weights for N gauges in the problem of estimating the Earth's global average temperature. Our results suggest that for commonly used configurations the variance of the estimate due to sampling error can be reduced by as much as 50%.

  18. Temperature Effects of Point Sources, Riparian Shading, and Dam Operations on the Willamette River, Oregon

    USGS Publications Warehouse

    Rounds, Stewart A.

    2007-01-01

    Water temperature is an important factor influencing the migration, rearing, and spawning of several important fish species in rivers of the Pacific Northwest. To protect these fish populations and to fulfill its responsibilities under the Federal Clean Water Act, the Oregon Department of Environmental Quality set a water temperature Total Maximum Daily Load (TMDL) in 2006 for the Willamette River and the lower reaches of its largest tributaries in northwestern Oregon. As a result, the thermal discharges of the largest point sources of heat to the Willamette River now are limited at certain times of the year, riparian vegetation has been targeted for restoration, and upstream dams are recognized as important influences on downstream temperatures. Many of the prescribed point-source heat-load allocations are sufficiently restrictive that management agencies may need to expend considerable resources to meet those allocations. Trading heat allocations among point-source dischargers may be a more economical and efficient means of meeting the cumulative point-source temperature limits set by the TMDL. The cumulative nature of these limits, however, precludes simple one-to-one trades of heat from one point source to another; a more detailed spatial analysis is needed. In this investigation, the flow and temperature models that formed the basis of the Willamette temperature TMDL were used to determine a spatially indexed 'heating signature' for each of the modeled point sources, and those signatures then were combined into a user-friendly, spreadsheet-based screening tool. The Willamette River Point-Source Heat-Trading Tool allows the user to increase or decrease the heating signature of each source and thereby evaluate the effects of a wide range of potential point-source heat trades. The predictions of the Trading Tool were verified by running the Willamette flow and temperature models under four different trading scenarios, and the predictions typically were accurate to within about 0.005 degrees Celsius (?C). In addition to assessing the effects of point-source heat trades, the models were used to evaluate the temperature effects of several shade-restoration scenarios. Restoration of riparian shade along the entire Long Tom River, from its mouth to Fern Ridge Dam, was calculated to have a small but significant effect on daily maximum temperatures in the main-stem Willamette River, on the order of 0.03?C where the Long Tom River enters the Willamette River, and diminishing downstream. Model scenarios also were run to assess the effects of restoring selected 5-mile reaches of riparian vegetation along the main-stem Willamette River from river mile (RM) 176.80, just upstream of the point where the McKenzie River joins the Willamette River, to RM 116.87 near Albany, which is one location where cumulative point-source heating effects are at a maximum. Restoration of riparian vegetation along the main-stem Willamette River was shown by model runs to have a significant local effect on daily maximum river temperatures (0.046 to 0.194?C) at the site of restoration. The magnitude of the cooling depends on many factors including river width, flow, time of year, and the difference in vegetation characteristics between current and restored conditions. Downstream of the restored reach, the cooling effects are complex and have a nodal nature: at one-half day of travel time downstream, shade restoration has little effect on daily maximum temperature because water passes the restoration site at night; at 1 full day of travel time downstream, cooling effects increase to a second, diminished maximum. Such spatial complexities may complicate the trading of heat allocations between point and nonpoint sources. Upstream dams have an important effect on water temperature in the Willamette River system as a result of augmented flows as well as modified temperature releases over the course of the summer and autumn. The TMDL was formulated prior t

  19. Room Temperature Bubble Point Tests on Porous Screens: Implications for Cryogenic Liquid Acquisition Devices

    NASA Technical Reports Server (NTRS)

    Hartwig, Jason; Mann, J. Adin, Jr.

    2012-01-01

    We present experimental results for room temperature bubble point tests conducted at the Cedar Creek Road Cryogenic Complex, Cell 7 (CCL-7) at the NASA Glenn Research Center. The purpose of these tests was to investigate the performance of three different fine mesh screens in room temperature liquids to provide pretest predictions in cryogenic liquid nitrogen (LN2) and hydrogen (LH2) as part of NASA's microgravity LAD technology development program. Bench type tests based on the maximum bubble point method were conducted for a 325 x 2300, 450 x 2750, and 510 x 3600 mesh sample in pure room temperature liquid methanol, acetone, isopropyl alcohol, water, and mixtures of methanol and water to cover the intermediate to upper surface tension range. A theoretical model for the bubble point pressure is derived from the Young-LaPlace equation for the pressure drop across a curved interface. Governing equations are reduced in complexity through a set of simplifying assumptions to permit direct comparison with the experimental data. Screen pore sizes are estimated from scanning electron microscopy (SEM) to make pretest predictions. Pore sizes based on SEM analysis are compared with historical data available in the literature for the 325 x 2300 and 450 x 2750 screens as well with data obtained from bubble point tests conducted in this work. Experimental results show that bubble point pressure is proportional to the surface tension of the liquid. We show that there is excellent agreement between data and model for pure fluids when the data is corrected for non-zero contact angle measured on the screens using a modified Sessile Drop technique. SEM image analysis of the three meshes indicated that bubble point pressure would be a maximum for the finest mesh screen. The pore diameters based on SEM analysis and experimental data obtained here are in excellent agreement for the 325 x 2300 and 450 x 2750 meshes, but not for the finest 510 x 3600 mesh. Therefore the simplified model can be used to interpolate predictions for low surface tension cryogenic liquids only when pore diameters are based on room temperature bubble point tests and not SEM analysis as presently implemented.

  20. The effect of water contamination on the dew-point temperature scale realization with humidity generators

    NASA Astrophysics Data System (ADS)

    Vilbaste, M.; Heinonen, M.; Saks, O.; Leito, I.

    2013-08-01

    The purpose of this paper is to study the effect of contaminated water in the context of humidity generators. Investigation of different methods to determine the drop in dew-point temperature due to contamination and experiments on actual contamination rates are reported. Different methods for calculating the dew-point temperature effect from electrical conductivity and density measurements are studied with high-purity water and aqueous solutions of NaCl and LiCl. The outcomes of the calculation methods are compared with the results of direct humidity measurements. The results show that the often applied Raoult's law based calculation method is in good agreement with other methods. For studying actual contamination, water samples were kept in glass, plastic, copper and stainless-steel vessels for up to 13 months to investigate natural ionic and organic contamination in vessels with different wall materials. The amount of ionic contamination was found to be higher in copper and glass vessels than in stainless-steel and plastic vessels. The amount of organic contamination was found to be highest in the plastic vessel. In all the cases, however, the corresponding drop in dew-point temperature due to natural contamination was found to be below 0.1 mK. The largest rate of change of dew-point temperature was 26 µK/month. Thus, if proper cleanness is maintained in a humidity generator the effect of contamination of water in the saturator is insignificant compared with the major uncertainty components even in the most accurate generators today.

  1. Boiling incipience and convective boiling of neon and nitrogen

    NASA Technical Reports Server (NTRS)

    Papell, S. S.; Hendricks, R. C.

    1977-01-01

    Forced convection and subcooled boiling heat transfer data for liquid nitrogen and liquid neon were obtained in support of a design study for a 30 tesla cryomagnet cooled by forced convection of liquid neon. The cryogen data obtained over a range of system pressures, fluid flow rates, and applied heat fluxes were used to develop correlations for predicting boiling incipience and convective boiling heat transfer coefficients in uniformly heated flow channels. The accuracy of the correlating equations was then evaluated. A technique was also developed to calculate the position of boiling incipience in a uniformly heated flow channel. Comparisons made with the experimental data showed a prediction accuracy of + or - 15 percent.

  2. Triple point temperature of neon isotopes: Dependence on nitrogen impurity and sealed-cell model

    SciTech Connect

    Pavese, F.; Steur, P. P. M.; Giraudi, D.

    2013-09-11

    This paper illustrates a study conducted at INRIM, to further check how some quantities influence the value of the triple point temperature of the neon high-purity isotopes {sup 20}Ne and {sup 22}Ne. The influence of nitrogen as a chemical impurity in neon is critical with regard to the present best total uncertainty achieved in the measurement of these triple points, but only one determination is available in the literature. Checks are reported, performed on two different samples of {sup 22}Ne known to contain a N{sub 2} amount of 157⋅10{sup −6}, using two different models of sealed cells. The model of the cell can, in principle, have some effects on the shape of the melting plateau or on the triple point temperature observed for the sample sealed in it. This can be due to cell thermal parameters, or because the INRIM cell element mod. c contains many copper wires closely packed, which can, in principle, constrain the interface and induce a premelting-like effect. The reported results on a cell mod. Bter show no evident effect from the cell model and provide a value for the effect of N{sub 2} in Ne liquidus point of 8.6(1.9) μK ppm N{sub 2}{sup −1}, only slightly different from the literature datum.

  3. Triple point temperature of neon isotopes: Dependence on nitrogen impurity and sealed-cell model

    NASA Astrophysics Data System (ADS)

    Pavese, F.; Steur, P. P. M.; Giraudi, D.

    2013-09-01

    This paper illustrates a study conducted at INRIM, to further check how some quantities influence the value of the triple point temperature of the neon high-purity isotopes 20Ne and 22Ne. The influence of nitrogen as a chemical impurity in neon is critical with regard to the present best total uncertainty achieved in the measurement of these triple points, but only one determination is available in the literature. Checks are reported, performed on two different samples of 22Ne known to contain a N2 amount of 157ṡ10-6, using two different models of sealed cells. The model of the cell can, in principle, have some effects on the shape of the melting plateau or on the triple point temperature observed for the sample sealed in it. This can be due to cell thermal parameters, or because the INRIM cell element mod. c contains many copper wires closely packed, which can, in principle, constrain the interface and induce a premelting-like effect. The reported results on a cell mod. Bter show no evident effect from the cell model and provide a value for the effect of N2 in Ne liquidus point of 8.6(1.9) μK ppm N2-1, only slightly different from the literature datum.

  4. POINT 2011: ENDF/B-VII.1 Beta2 Temperature Dependent Cross Section Library

    SciTech Connect

    Cullen, D E

    2011-04-07

    This report is one in the series of 'POINT' reports that over the years have presented temperature dependent cross sections for the then current version of ENDF/B. In each case I have used my personal computer at home and publicly available data and codes. I have used these in combination to produce the temperature dependent cross sections used in applications and presented in this report. I should mention that today anyone with a personal computer can produce these results. The latest ENDF/B-VII.1 beta2 data library was recently and is now freely available through the National Nuclear Data Center (NNDC), Brookhaven National Laboratory. This release completely supersedes all preceding releases of ENDF/B. As distributed the ENDF/B-VII.1 data includes cross sections represented in the form of a combination of resonance parameters and/or tabulated energy dependent cross sections, nominally at 0 Kelvin temperature. For use in our applications the ENDF/B-VII.1 library has been processed into cross sections at eight neutron reactor like temperatures, between 0 and 2100 Kelvin, in steps of 300 Kelvin (the exception being 293.6 Kelvin, for exact room temperature at 20 Celsius). It has also been processed to five astrophysics like temperatures, 1, 10, 100 eV, 1 and 10 keV. For reference purposes, 300 Kelvin is approximately 1/40 eV, so that 1 eV is approximately 12,000 Kelvin. At each temperature the cross sections are tabulated and linearly interpolable in energy. All results are in the computer independent ENDF-6 character format [R2], which allows the data to be easily transported between computers. In its processed form the POINT 2011 library is approximately 16 gigabyte in size and is distributed on one compressed DVDs (see, below for the details of the contents of each DVD).

  5. Cryogenic Boil-Off Reduction System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, David W.; Johnson, Wesley L.; Feller, Jeffrey R.

    2014-01-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration due to the high specific impulse that can be achieved using engines suitable for moving 10's to 100's of metric tons of payload mass to destinations outside of low earth orbit. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for missions with durations greater than several days. The losses can be greatly reduced by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and by the integration of self-supporting multi-layer insulation. The active thermal control technology under development is the integration of the reverse turbo- Brayton cycle cryocooler to the propellant tank through a distributed cooling network of tubes coupled to a shield in the tank insulation and to the tank wall itself. Also, the self-supporting insulation technology was utilized under the shield to obtain needed tank applied LH2 performance. These elements were recently tested at NASA Glenn Research Center in a series of three tests, two that reduced LH2 boil-off and one to eliminate LO2 boil-off. This test series was conducted in a vacuum chamber that replicated the vacuum of space and the temperatures of low Earth orbit. The test results show that LH2 boil-off was reduced 60% by the cryocooler system operating at 90K and that robust LO2 zero boil-off storage, including full tank pressure control was achieved.

  6. Temperature determination of the Si-SiC eutectic fixed point using thermocouples

    NASA Astrophysics Data System (ADS)

    Suherlan; Kim, Yong-Gyoo; Joung, Wukchul; Yang, Inseok

    2015-04-01

    The temperature of the Si-SiC eutectic fixed point for use in thermocouple thermometry has been determined. Three Si-SiC cells were fabricated from pure silicon powder within separate graphite crucibles. Each of the three cells was cycled through 17 melt-freeze cycles and subjected to temperatures above 1400 °C for a period of approximately 73 h, and none showed any sign of mechanical failure. The melting transition was measured using three types of thermocouple: one type S, one type B, and two Pt/Pd thermocouples calibrated at the fixed points of Ag, Cu, Fe-C, Co-C, and Pd (only for type B). The transition temperature, measured using the type S and two Pt/Pd thermocouples, was (1410.0 ± 0.8) °C with k = 2. However, the measurement uncertainty using the type B thermocouple was as large as 1.5 °C (k = 2) due to the inhomogeneity of the thermocouple. The repeatability of the three Si-SiC cells was calculated to be 0.3 °C, and the extremes of the temperature measurement differed by 0.8 °C.

  7. Wall sticking of high water-cut crude oil transported at temperatures below the gel point

    NASA Astrophysics Data System (ADS)

    Zheng, Haimin; Huang, Qiyu; Wang, Changhui

    2015-12-01

    Some high water-cut crude oils can flow in the temperature below the oil gel point, while oil particles may adhere to the pipe wall as paste; this process is known as ‘wall sticking’. This can cause partial or even total blocking of the transportation pipe. Several experiments using a laboratory flow loop were conducted to study the wall sticking characteristics of high water-cut crude oils. The experimental results indicated that the predominant influencing factors of wall sticking included shear stress, water-cut and differences between gel point and wall temperature. The wall sticking rate and occurrence temperature decrease with the increase of water-cut and shear stress. The criterion for the wall sticking occurrence temperature (WSOT), and the regression formula of the wall sticking thickness for high water-cut crude oil were then established. Typical case studies indicated that the prediction results obtained from the WSOT criterion and the wall sticking thickness regression formula were in accordance with the measured values. The wall sticking rate and WSOT vary widely under different conditions and it is necessary to consider its non-uniformity in production.

  8. Measurement of gas-phase temperatures in flames with a point-diffraction interferometer.

    PubMed

    Goldmeer, J S; Urban, D L; Yuan, Z G

    2001-09-20

    Experiments were performed to evaluate the performance of a point-diffraction interferometry (PDI) system to measure gas-phase temperatures in flames. PDI is an interferometric technique that creates the reference beam after the laser beam passes through the test section and directly provides the index of refraction in two dimensions. PDI-based temperature measurements were compared with thermocouple measurements of two-dimensional and axisymmetric thermal boundary layers, as well as two-dimensional and axisymmetric diffusion flames. The PDI system provided excellent agreement in the measurement of thermal profiles in the boundary layers and was within the uncertainties that are due to the radiation corrections for the thermocouple-based flame temperature measurements. PMID:18360522

  9. Evaluation of local temperature around the impact points of fast ions

    NASA Astrophysics Data System (ADS)

    Hayashi, H.; Kitayama, T.; Matsuzaki, S.; Nakajima, K.; Narumi, K.; Saitoh, Y.; Tsujimoto, M.; Toulemonde, M.; Kimura, K.

    2015-12-01

    Gold and platinum nanoparticles of few-nm size were deposited on amorphous silicon nitride (a-SiN) films. These samples were irradiated with 1.1 MeV C603+ ions to a fluence of ∼5 × 1010 ions/cm2 and observed using transmission electron microscopy (TEM). The ion tracks were clearly seen as bright spots and the metal nanoparticles disappeared from a neighboring region (5-10 nm) around each ion track. The platinum-nanoparticle-cleared region is slightly smaller than that of gold nanoparticles. This trend can be reproduced by the u-TS calculations assuming that the nanoparticles are desorbed when the local temperature surpasses the melting point of nanoparticles as was predicted by molecular dynamics simulations (Anders et al., 2009). This indicates that the temperature distribution in a nanometer region can be evaluated by observing the desorption of nanoparticles of different metals having different melting temperatures.

  10. How Does Water Boil?

    NASA Astrophysics Data System (ADS)

    Zahn, Dirk

    2004-11-01

    Insight into the boiling of water is obtained from molecular dynamics simulations. The process is initiated by the spontaneous formation of small vacuum cavities in liquid water. By themselves, these defects are very short lived. If, however, several cavities occur at close distances, they are likely to merge into larger vacuum holes. At the liquid-vapor interfaces, single or small groups of water molecules tend to leave the liquid surface. Once the system is propagated beyond the transition state, these evaporation events outnumber the competing reintegration into the hydrogen-bonded network.

  11. Estimation of the temperature dependent interaction between uncharged point defects in Si

    SciTech Connect

    Kamiyama, Eiji; Vanhellemont, Jan; Sueoka, Koji

    2015-01-15

    A method is described to estimate the temperature dependent interaction between two uncharged point defects in Si based on DFT calculations. As an illustration, the formation of the uncharged di-vacancy V{sub 2} is discussed, based on the temperature dependent attractive field between both vacancies. For that purpose, all irreducible configurations of two uncharged vacancies are determined, each with their weight given by the number of equivalent configurations. Using a standard 216-atoms supercell, nineteen irreducible configurations of two vacancies are obtained. The binding energies of all these configurations are calculated. Each vacancy is surrounded by several attractive sites for another vacancy. The obtained temperature dependent of total volume of these attractive sites has a radius that is closely related with the capture radius for the formation of a di-vacancy that is used in continuum theory. The presented methodology can in principle also be applied to estimate the capture radius for pair formation of any type of point defects.

  12. Triple-Point Temperature and the Isotopic Composition of Three Commercial Neon Gases

    NASA Astrophysics Data System (ADS)

    Yang, I.; Gam, K. S.; Joung, W.; Kim, Y.-G.

    2015-08-01

    The triple-point temperature of neon, , is known to have dependence on the isotopic composition. Recently, the Technical Annex for the International Temperature Scale of 1990 was updated to specify the method of correction for the isotopic reference ratio of neon. In this study, to confirm this correction in the Technical Annex independently, the effects of the isotopic composition of neon on for three commercial neon gas sources were studied. For the measurement of the isotopic composition, a gas mass spectrometer was used to compare the sample gases with a reference neon gas whose isotopic composition was known with high precision by a gravimetric method. For the measurement of , an open-cell type cryostat for the realization of low-temperature fixed points was used. The physical cell and the thermal environment around it remained very similar for all measurements with the neon gases due to the nature of the open-cell type system. Therefore, the difference in among different samples could be measured with a relatively low uncertainty, canceling many systematic effects that are common to all measurements. Our result was consistent with the correction in the Technical Annex. Furthermore, because one of the commercial neon gases was the bottle that was used for KRISS measurements in the international comparison CCT-K2, it is now possible to correct the measurement for the reference isotopic ratio and compare it with other measurements for which isotopic composition data are available.

  13. Localized saddle-point search and application to temperature-accelerated dynamics

    SciTech Connect

    Shim, Yunsic; Amar, Jacques G.; Callahan, Nathan B.

    2013-03-07

    We present a method for speeding up temperature-accelerated dynamics (TAD) simulations by carrying out a localized saddle-point (LSAD) search. In this method, instead of using the entire system to determine the energy barriers of activated processes, the calculation is localized by only including a small chunk of atoms around the atoms directly involved in the transition. Using this method, we have obtained N-independent scaling for the computational cost of the saddle-point search as a function of system size N. The error arising from localization is analyzed using a variety of model systems, including a variety of activated processes on Ag(100) and Cu(100) surfaces, as well as multiatom moves in Cu radiation damage and metal heteroepitaxial growth. Our results show significantly improved performance of TAD with the LSAD method, for the case of Ag/Ag(100) annealing and Cu/Cu(100) growth, while maintaining a negligibly small error in energy barriers.

  14. Fundamental Boiling and RP-1 Freezing Experiments

    NASA Technical Reports Server (NTRS)

    Goode, Brian; Turner, Larry D. (Technical Monitor)

    2001-01-01

    This paper describes results from experiments performed to help understand certain aspects of the MC-1 engine prestart thermal conditioning procedure. The procedure was constrained by the fact that the engine must chill long enough to get quality LOX at the LOX pump inlet but must be short enough to prevent freezing of RP-1 in the fuel pump. A chill test of an MC-1 LOX impeller was performed in LN2 to obtain data on film boiling, transition boiling and impeller temperature histories. The transition boiling data was important to the chill time so a subsequent experiment was performed chilling simple steel plates in LOX to obtain similar data for LOX. To address the fuel freezing concern, two experiments were performed. First, fuel was frozen in a tray and its physical characteristics were observed and temperatures of the fuel were measured. The result was physical characteristics as a function of temperature. Second was an attempt to measure the frozen thickness of RP-1 on a cold wall submerged in warm RP-1 and to develop a method for calculating that thickness for other conditions.

  15. Relationship Between Ice Nucleation Temperature Depression and Equilibrium Melting Points Depression of Medaka (Oryzias latipes) Embryos

    NASA Astrophysics Data System (ADS)

    Kimizuka, Norihito; Suzuki, Toru

    We measured the ice nucleation temperature depression , ΔTf , and equilibrium melting points depression, ΔTm, of Medaka (Oryzias latipes) embryos with different cryoprotectant (ethylene glycol, 1.3-propanediol, 1.4-butanediol, glycerol aqueous solutions) treatments. Our obtained results showed the good relationship between the ΔTf ,and ΔTm all samples. In addition the value of λ , which can be obtained from the linear relationship, ΔTf =λ ΔTm, were confirmed to show correlation with the value of λ , as obtained by the W/O emulsion method.

  16. Computations of Boiling in Microgravity

    NASA Technical Reports Server (NTRS)

    Tryggvason, G.; Jacqmin, Dave

    2000-01-01

    The absence (or reduction) of gravity, can lead to major changes in boiling heat transfer. On Earth, convection has a major effect on the heat distribution ahead of an evaporation front, and buoyancy determines the motion of the growing bubbles. In microgravity, convection and buoyancy are absent or greatly reduced and the dynamics of the growing vapor bubbles can change in a fundamental way. In particular, the lack of redistribution of heat can lead to a large superheat and explosive growth of bubbles once they form. While considerable efforts have been devoted to examining boiling experimentally, including the effect of microgravity, theoretical and computational work have been limited. Here, the growth of boiling bubbles is studied by direct numerical simulations where the flow field is fully resolved and the effects of inertia, viscosity, surface deformation, heat conduction and convection, as well as the phase change, are fully accounted for. Boiling involves both fluid flow and heat transfer and thus requires the solution of the Navier-Stokes and the energy equations. The numerical method is based on writing one set of governing transport equations which is valid in both the liquid and vapor phases. This local, single-field formulation incorporates the effect of the interface in the governing equations as source terms acting only at the interface. These sources account for surface tension and latent heat in the equations for conservation of momentum and energy as well as mass transfer across the interface due to phase change. The single-field formulation naturally incorporates the correct mass, momentum and energy balances across the interface. Integration of the conservation equations across the interface directly yields the jump conditions derived in the local instant formulation for two-phase systems. In the numerical implementation, the conservation equations for the whole computational domain (both vapor and liquid) are solved using a stationary grid and the phase boundary is followed by a moving unstructured two-dimensional grid. While two-dimensional simulations have been used for preliminary studies and to examine the resolution requirement, the focus is on fully three-dimensional simulations. The numerical methodology, including the parallelization and grid refinement strategy is discussed, and preliminary results shown. For buoyancy driven flow, the heat transfer is in good agreement with experimental correlations. The changes when gravity is turned off and/or fluid shear is added are discussed, as well as the difference between simulations of a layer freely releasing bubbles versus simulations using only one wavelength initial perturbation. Figure 1 shows the early stages of the formation of a three-dimensional bubble from a thin vapor layer. The boundary conditions are periodic in the x and y direction, the bottom is a hot and the top allows a free outflow. The jagged edge of the surface close to the bottom of the computational domain is due to some of the surface elements being on the other side of the domain and some elements not plotted by our plotting routine. In the second figure, we show the temperature distribution through two perpendicular planes.

  17. Unorthodox bubbles when boiling in cold water

    NASA Astrophysics Data System (ADS)

    Parker, Scott; Granick, Steve

    2014-01-01

    High-speed movies are taken when bubbles grow at gold surfaces heated spotwise with a near-infrared laser beam heating water below the boiling point (60-70 °C) with heating powers spanning the range from very low to so high that water fails to rewet the surface after bubbles detach. Roughly half the bubbles are conventional: They grow symmetrically through evaporation until buoyancy lifts them away. Others have unorthodox shapes and appear to contribute disproportionately to heat transfer efficiency: mushroom cloud shapes, violently explosive bubbles, and cavitation events, probably stimulated by a combination of superheating, convection, turbulence, and surface dewetting during the initial bubble growth. Moreover, bubbles often follow one another in complex sequences, often beginning with an unorthodox bubble that stirs the water, followed by several conventional bubbles. This large dataset is analyzed and discussed with emphasis on how explosive phenomena such as cavitation induce discrepancies from classical expectations about boiling.

  18. Unorthodox bubbles when boiling in cold water.

    PubMed

    Parker, Scott; Granick, Steve

    2014-01-01

    High-speed movies are taken when bubbles grow at gold surfaces heated spotwise with a near-infrared laser beam heating water below the boiling point (60-70 °C) with heating powers spanning the range from very low to so high that water fails to rewet the surface after bubbles detach. Roughly half the bubbles are conventional: They grow symmetrically through evaporation until buoyancy lifts them away. Others have unorthodox shapes and appear to contribute disproportionately to heat transfer efficiency: mushroom cloud shapes, violently explosive bubbles, and cavitation events, probably stimulated by a combination of superheating, convection, turbulence, and surface dewetting during the initial bubble growth. Moreover, bubbles often follow one another in complex sequences, often beginning with an unorthodox bubble that stirs the water, followed by several conventional bubbles. This large dataset is analyzed and discussed with emphasis on how explosive phenomena such as cavitation induce discrepancies from classical expectations about boiling. PMID:24580324

  19. Tympanic thermometer performance validation by use of a body-temperature fixed point blackbody

    NASA Astrophysics Data System (ADS)

    Machin, Graham; Simpson, Robert

    2003-04-01

    The use of infrared tympanic thermometers within the medical community (and more generically in the public domain) has recently grown rapidly, displacing more traditional forms of thermometry such as mercury-in-glass. Besides the obvious health concerns over mercury the increase in the use of tympanic thermometers is related to a number of factors such as their speed and relatively non-invasive method of operation. The calibration and testing of such devices is covered by a number of international standards (ASTM1, prEN2, JIS3) which specify the design of calibration blackbodies. However these calibration sources are impractical for day-to-day in-situ validation purposes. In addition several studies (e.g. Modell et al4, Craig et al5) have thrown doubt on the accuracy of tympanic thermometers in clinical use. With this in mind the NPL is developing a practical, portable and robust primary reference fixed point source for tympanic thermometer validation. The aim of this simple device is to give the clinician a rapid way of validating the performance of their tympanic thermometer, enabling the detection of mal-functioning thermometers and giving confidence in the measurement to the clinician (and patient!) at point of use. The reference fixed point operates at a temperature of 36.3 °C (97.3 °F) with a repeatability of approximately +/- 20 mK. The fixed-point design has taken into consideration the optical characteristics of tympanic thermometers enabling wide-angled field of view devices to be successfully tested. The overall uncertainty of the device is estimated to be is less than 0.1°C. The paper gives a description of the fixed point, its design and construction as well as the results to date of validation tests.

  20. An updated global grid point surface air temperature anomaly data set: 1851--1990

    SciTech Connect

    Sepanski, R.J.; Boden, T.A.; Daniels, R.C.

    1991-10-01

    This document presents land-based monthly surface air temperature anomalies (departures from a 1951--1970 reference period mean) on a 5{degree} latitude by 10{degree} longitude global grid. Monthly surface air temperature anomalies (departures from a 1957--1975 reference period mean) for the Antarctic (grid points from 65{degree}S to 85{degree}S) are presented in a similar way as a separate data set. The data were derived primarily from the World Weather Records and the archives of the United Kingdom Meteorological Office. This long-term record of temperature anomalies may be used in studies addressing possible greenhouse-gas-induced climate changes. To date, the data have been employed in generating regional, hemispheric, and global time series for determining whether recent (i.e., post-1900) warming trends have taken place. This document also presents the monthly mean temperature records for the individual stations that were used to generate the set of gridded anomalies. The periods of record vary by station. Northern Hemisphere station data have been corrected for inhomogeneities, while Southern Hemisphere data are presented in uncorrected form. 14 refs., 11 figs., 10 tabs.

  1. The Influence of Titanium on the Aluminum Fixed-Point Temperature

    NASA Astrophysics Data System (ADS)

    Petchpong, Patchariya; Head, David I.

    2011-08-01

    This work describes the deliberate doping of high purity (99.9999 %) aluminum with titanium (99.8 %) impurity and the effect of this on the temperature of the aluminum liquid-solid phase transition (660.323 °C). The aluminum sample was in the form of an ~0.3 kg ingot (that would normally be used to realize an ITS-90 fixed point) which was doped at ~0.9 ppmw Ti and ~1.8 ppmw Ti (mass fraction in parts per million by mass). Measurements were made with procedures and equipment normally used in a metrological thermometry laboratory, rather than using special arrangements. Samples cut from the aluminum ingot were chemically analyzed by glow discharge mass spectrometry (GD-MS) before doping and after the second doping (to 1.8 ppmw). The experimental temperature offsets were compared with those calculated by interpolation from a reference book value using the mass of dopant introduced, or the chemical analysis data. The results showed that the aluminum temperature increased after adding 0.9 ppmw Ti, but apparently the temperature did not change after further doping to 1.8 ppmw Ti; which was unexpected. The first result suggested that titanium impurity increases the Al transition temperature by +5.1 mK · ppmw-1. However, using the (total) temperature offset and the GD-MS value for the (total) added Ti impurities, then one calculates a value of 3.4 mK · ppmw-1 (much closer to a reference book value). The experimental undoped liquid-solid transition curves were also compared against theoretical curves (calculated using a theoretical model "MTDATA"). This suggested that GD-MS may not be "exposing" all the active impurities (some of which may be "hidden" in the carbon background).

  2. Realization of tin freezing point using a loop heat pipe-based hydraulic temperature control technique

    NASA Astrophysics Data System (ADS)

    Joung, Wukchul; Gam, Kee Sool; Kim, Yong-Gyoo

    2015-10-01

    In this work, the freezing point of tin (Sn FP) was realized by inside nucleation where the supercooling of tin and the reheating of the sample after the nucleation were achieved without extracting the cell from an isothermal apparatus. To this end, a novel hydraulic temperature control technique, which was based on the thermo-hydraulic characteristics of a pressure-controlled loop heat pipe (LHP), was employed to provide a slow cooling of the sample for deep supercooling and fast reheating after nucleation to minimize the amount of initial freeze of the sample. The required temperature controls were achieved by the active pressure control of a control gas inside the compensation chamber of the pressure-controlled LHP, and slow cooling at  -0.05 K min-1 for the deep supercooling of tin and fast heating at 2 K min-1 for reheating the sample after nucleation was attained. Based on this hydraulic temperature control technique, the nucleation of tin was realized at supercooling of around 19 K, and a satisfactorily fast reheating of the sample to the plateau-producing temperature (i.e. 0.5 K below the Sn FP) was achieved without any temperature overshoots of the isothermal region. The inside-nucleated Sn FP showed many desirable features compared to the Sn FP realized by the conventional outside nucleation method. The longer freezing plateaus and the better immersion characteristics of the Sn FP were obtained by inside nucleation, and the measured freezing temperature of the inside-nucleated Sn FP was as much as 0.37 mK higher than the outside-nucleated Sn FP with an expanded uncertainty of 0.19 mK. Details on the experiment are provided and explanations for the observed differences are discussed.

  3. Measurements of Convection Heat Transfer Coefficients for Hydrocarbon Mixtures during Boiling in a Heated Horizontal Pipe from 100 K to Room Temperature

    NASA Astrophysics Data System (ADS)

    Barraza, Rodrigo; Nellis, Gregory; Klein, Sanford; Reindl, Douglas

    There is a scarcity of data and theory currently available regarding the heat transfer coefficients associated with two-phase, multi-component mixtures at cryogenic temperatures. This paper presents results of research aimed at measuring theconvection heat transfer coefficients for hydrocarbon mixtures (methane, ethane, propane, and nitrogen (for dilution)) during evaporation while flowing within a heated horizontal pipe over a wide range of temperatures (from 100 K to room temperature). The results show the heat transfer coefficients along with their sensitivity to parameters such as heat flux, mass flux, pressure, and composition.

  4. Boiling local heat transfer enhancement in minichannels using nanofluids

    PubMed Central

    2013-01-01

    This paper reports an experimental study on nanofluid convective boiling heat transfer in parallel rectangular minichannels of 800 μm hydraulic diameter. Experiments are conducted with pure water and silver nanoparticles suspended in water base fluid. Two small volume fractions of silver nanoparticles suspended in water are tested: 0.000237% and 0.000475%. The experimental results show that the local heat transfer coefficient, local heat flux, and local wall temperature are affected by silver nanoparticle concentration in water base fluid. In addition, different correlations established for boiling flow heat transfer in minichannels or macrochannels are evaluated. It is found that the correlation of Kandlikar and Balasubramanian is the closest to the water boiling heat transfer results. The boiling local heat transfer enhancement by adding silver nanoparticles in base fluid is not uniform along the channel flow. Better performances and highest effect of nanoparticle concentration on the heat transfer are obtained at the minichannels entrance. PMID:23506445

  5. Turning bubbles on and off during boiling using charged surfactants

    PubMed Central

    Cho, H. Jeremy; Mizerak, Jordan P.; Wang, Evelyn N.

    2015-01-01

    Boiling—a process that has powered industries since the steam age—is governed by bubble formation. State-of-the-art boiling surfaces often increase bubble nucleation via roughness and/or wettability modification to increase performance. However, without active in situ control of bubbles, temperature or steam generation cannot be adjusted for a given heat input. Here we report the ability to turn bubbles ‘on and off' independent of heat input during boiling both temporally and spatially via molecular manipulation of the boiling surface. As a result, we can rapidly and reversibly alter heat transfer performance up to an order of magnitude. Our experiments show that this active control is achieved by electrostatically adsorbing and desorbing charged surfactants to alter the wettability of the surface, thereby affecting nucleation. This approach can improve performance and flexibility in existing boiling technologies as well as enable emerging or unprecedented energy applications. PMID:26486275

  6. One-point functions in finite volume/temperature: a case study

    NASA Astrophysics Data System (ADS)

    Szécsényi, I. M.; Takács, G.; Watts, G. M. T.

    2013-08-01

    We consider finite volume (or equivalently, finite temperature) expectation values of local operators in integrable quantum field theories using a combination of numerical and analytical approaches. It is shown that the truncated conformal space approach, when supplemented with a recently proposed renormalization group, can be sufficiently extended to the low-energy regime that it can be matched with high precision by the low-temperature expansion proposed by Leclair and Mussardo. Besides verifying the consistency of the two descriptions, their combination leads to an evaluation of expectation values which is valid to a very high precision for all volume/temperature scales. As a side result of the investigation, we also discuss some unexpected singularities in the framework recently proposed by Pozsgay and Takács for the description of matrix elements of local operators in finite volume, and show that while some of these singularities are resolved by the inclusion of the class of exponential finite size corrections known as μ-terms, these latter corrections themselves lead to the appearance of new singularities. We point out that a fully consistent description of finite volume matrix elements is expected to be free of singularities, and therefore a more complete and systematic understanding of exponential finite size corrections is necessary.

  7. Lifshitz transitions and zero point lattice fluctuations in sulfur hydride showing near room temperature superconductivity

    NASA Astrophysics Data System (ADS)

    Bianconi, Antonio; Jarlborg, Thomas

    2015-11-01

    Emerets's experiments on pressurized sulfur hydride have shown that H3S metal has the highest known superconducting critical temperature Tc = 203 K. The Emerets data show pressure induced changes of the isotope coefficient between 0.25 and 0.5, in disagreement with Eliashberg theory which predicts a nearly constant isotope coefficient.We assign the pressure dependent isotope coefficient to Lifshitz transitions induced by pressure and zero point lattice fluctuations. It is known that pressure could induce changes of the topology of the Fermi surface, called Lifshitz transitions, but were neglected in previous papers on the H3S superconductivity issue. Here we propose thatH3S is a multi-gap superconductor with a first condensate in the BCS regime (located in the large Fermi surface with high Fermi energy) which coexists with second condensates in the BCS-BEC crossover regime (located on the Fermi surface spots with small Fermi energy) near the and Mpoints.We discuss the Bianconi-Perali-Valletta (BPV) superconductivity theory to understand superconductivity in H3S since the BPV theory includes the corrections of the chemical potential due to pairing and the configuration interaction between different condensates, neglected by the Eliashberg theory. These two terms in the BPV theory give the shape resonance in superconducting gaps, similar to Feshbach resonance in ultracold fermionic gases, which is known to amplify the critical temperature. Therefore this work provides some key tools useful in the search for new room temperature superconductors.

  8. Film boiling of mercury droplets

    NASA Technical Reports Server (NTRS)

    Baumeister, K. J.; Schoessow, G. J.; Chmielewski, C. E.

    1975-01-01

    Vaporization times of mercury droplets in Leidenfrost film boiling on a flat horizontal plate are measured in an air atmosphere. Extreme care was used to prevent large amplitude droplet vibrations and surface wetting; therefore, these data can be compared to film boiling theory. For these data, diffusion from the upper surface of the drop is a dominant mode of mass transfer from the drop. A closed-form analytical film boiling theory is developed to account for the diffusive evaporation. Reasonable agreement between data and theory is seen.

  9. Film boiling of mercury droplets

    NASA Technical Reports Server (NTRS)

    Baumeister, K. J.; Schoessow, G. J.; Chmielewski, C. E.

    1975-01-01

    Vaporization times of mercury droplets in Leidenfrost film boiling on a flat horizontal plate are measured in an air atmosphere. Extreme care was used to prevent large amplitude droplet vibrations and surface wetting; therefore, these data can be compared to film boiling theory. Diffusion from the upper surface of the drop appears as a dominant mode of mass transfer from the drop. A closed-form analytical film boiling theory is developed to account for the diffusive evaporation. Reasonable agreement between data and theory is seen.

  10. Pool and flow boiling in variable and microgravity

    NASA Technical Reports Server (NTRS)

    Merte, Herman, Jr.

    1994-01-01

    As is well known, boiling is an effective mode of heat transfer in that high heat flux levels are possible with relatively small temperature differences. Its optimal application requires that the process be adequately understood. A measure of the understanding of any physical event lies in the ability to predict its behavior in terms of the relevant parameters. Despite many years of research the predictability of boiling is currently possible only for quite specialized circumstances, e.g., the critical heat flux and film boiling for the pool boiling case, and then only with special geometries. Variable gravity down to microgravity provides the opportunity to test this understanding, but possibly more important, by changing the dimensional and time scales involved permits more detailed observations of elements involved in the boiling process, and perhaps discloses phenomena heretofore unknown. The focus here is on nucleate boiling although, as will be demonstrated below, under but certain circumstances in microgravity it can take place concurrently with the dryout process. In the presence of earth gravity or forced convection effects, the latter process is usually referred to as film boiling. However, no vapor film as such forms with pool boiling in microgravity, only dryout. Initial results are presented here for pool boiling in microgravity, and were made possible at such an early date by the availability of the Get-Away-Specials (GAS). Also presented here are some results of ground testing of a flow loop for the study of low velocity boiling, eventually to take place also in microgravity. In the interim, variable buoyancy normal to the heater surface is achieved by rotation of the entire loop relative to earth gravity. Of course, this is at the expense of varying the buoyancy parallel to the heater surface. Two questions which must be resolved early in the study of flow boiling in microgravity are (1) the lower limits of liquid flow velocity where buoyancy effects become significant to the boiling process (2) the effect of lower liquid flow velocities on the Critical Heat Flux when buoyancy is removed. Results of initial efforts in these directions are presented, albeit restricted currently to the ever present earth gravity.

  11. Unsteady heat transfer during subcooled film boiling

    NASA Astrophysics Data System (ADS)

    Yagov, V. V.; Zabirov, A. R.; Lexin, M. A.

    2015-11-01

    Cooling of high-temperature bodies in subcooled liquid is of importance for quenching technologies and also for understanding the processes initiating vapor explosion. An analysis of the available experimental information shows that the mechanisms governing heat transfer in these processes are interpreted ambiguously; a more clear-cut definition of the Leidenfrost temperature notion is required. The results of experimental observations (Hewitt, Kenning, and previous investigations performed by the authors of this article) allow us to draw a conclusion that there exists a special mode of intense heat transfer during film boil- ing of highly subcooled liquid. For revealing regularities and mechanisms governing intense transfer of energy in this process, specialists of Moscow Power Engineering Institute's (MPEI) Department of Engineering Thermal Physics conduct systematic works aimed at investigating the cooling of high-temperature balls made of different metals in water with a temperature ranging from 20 to 100°C. It has been determined that the field of temperatures that takes place in balls with a diameter of more than 30 mm in intense cooling modes loses its spherical symmetry. An approximate procedure for solving the inverse thermal conductivity problem for calculating the heat flux density on the ball surface is developed. During film boiling, in which the ball surface temperature is well above the critical level for water, and in which liquid cannot come in direct contact with the wall, the calculated heat fluxes reach 3-7 MW/m2.

  12. A Novel Role of Three Dimensional Graphene Foam to Prevent Heater Failure during Boiling

    NASA Astrophysics Data System (ADS)

    Ahn, Ho Seon; Kim, Ji Min; Park, Chibeom; Jang, Ji-Wook; Lee, Jae Sung; Kim, Hyungdae; Kaviany, Massoud; Kim, Moo Hwan

    2013-06-01

    We report a novel boiling heat transfer (NBHT) in reduced graphene oxide (RGO) suspended in water (RGO colloid) near critical heat flux (CHF), which is traditionally the dangerous limitation of nucleate boiling heat transfer because of heater failure. When the heat flux reaches the maximum value (CHF) in RGO colloid pool boiling, the wall temperature increases gradually and slowly with an almost constant heat flux, contrary to the rapid wall temperature increase found during water pool boiling. The gained time by NBHT would provide the safer margin of the heat transfer and the amazing impact on the thermal system as the first report of graphene application. In addition, the CHF and boiling heat transfer performance also increase. This novel boiling phenomenon can effectively prevent heater failure because of the role played by the self-assembled three-dimensional foam-like graphene network (SFG).

  13. Aspects of proximity effect in tunneling and point contact spectroscopies of high critical temperature superconductors

    SciTech Connect

    Tafuri, F.; Di Chiara, A.; Peluso, G.; Fontana, F.

    1994-12-31

    In this paper the possibility that high critical temperature superconductor (HCTS) electrodes are non homogeneous is considered. The effect of such a configuration on current vs. voltage characteristics in HCTS junctions is analyzed and modelled in significant limits. Typical features, such as the depression of gap structures and finite zero bias conductances, are explained according to the proposed model. This last is based on arguments of proximity effect between weakly coupled bilayers (superconductor-normal metal). It allows to study tunnel (TJ) and point contact (PCJ) junctions, providing results qualitatively different from classical theories on PCJ. The low transmissive nature of such an interface seems to play a fundamental role in determining current vs. voltage characteristics in HCTS junctions. The results of the presented model suggest also PCJ as a sensitive tool to evaluate the transmission probability of interfaces between a superconductor and a metal.

  14. Improvements in Predicting Void Fraction in Subcooled Boiling

    SciTech Connect

    Ha, Kwi Seok; Lee, Yong Bum; No, Hee Cheon

    2005-06-15

    A simple two-phase thermal-hydraulic tool with the drift-flux model has been used to develop a subcooled boiling model. The tool is composed of four governing equations: mixture mass, vapor mass, mixture momentum, and mixture enthalpy. Using the developed tool, various subcooled boiling models were investigated through the published experimental data. In the process of evaluation, two models were developed associated with the subcooled boiling. First, the Saha and Zuber correlation predicting the point of the net vapor generation was modified to consider the thermal and dynamic effects at the high-velocity region. Second, the pumping factor model was developed using the pi-theorem based on parameters related to the bubble generation mechanism, and it produced an additional parameter: the boiling number. The proposed models and several other models were evaluated against a series of subcooled flow boiling experiments at the pressure range of 1 to 146.8 bars. From the root-mean-square analysis for the predicted void fraction in the subcooled boiling region, the results of the proposed model presented the best predictions for the whole-pressure ranges. Also, the implementation of the developed models into RELAP5/MOD3.3 brought about improved results compared to those of the default model of the code.

  15. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity.

    PubMed

    Sigalotti, Leonardo Di G; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (T(s)≈0.96) is close to the theoretically derived value of T(s)=1 at zero ambient pressure for this vdW fluid. PMID:26274283

  16. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity

    NASA Astrophysics Data System (ADS)

    Sigalotti, Leonardo Di G.; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (Ts≈0.96 ) is close to the theoretically derived value of Ts=1 at zero ambient pressure for this vdW fluid.

  17. Boiling phenomena in near-critical SF6 observed in weightlessness

    NASA Astrophysics Data System (ADS)

    Lecoutre, Carole; Garrabos, Yves; Beysens, Daniel; Nikolayev, Vadim; Hahn, Inseob

    2014-07-01

    Boiling phenomena in the two-phase region of SF6 close to its critical point have been observed using the high-quality thermal and optical environment of the CNES dedicated facility ALI-DECLIC on board the International Space Station (ISS). The weightlessness environment of the fluid, which cancels buoyancy forces and favorites the three-dimensional spherical shape of the gas bubble, is proven to be an irreplaceable powerful tool for boiling studies. To identify each key mechanism of the boiling phenomena, the ALI-DECLIC experiments have benefited from (i) the well-adapted design of the test cells, (ii) the high-fidelity of the ALI insert teleoperation when long-duration experiment in stable thermal and microgravity environment are required and (iii) the high repeatability of the controlled thermal disturbances. These key mechanisms were observed by light transmission and interferometry technique independently with two sample cells filled with pure SF6 at a near-critical density. The fluid samples are driven away from thermal equilibrium by using a heater directly implemented in the fluid, or a surface heater on a sapphire optical window. In the interferometry cell, the bulk massive heater distinguishes two symmetrical two-phase domains. The modification of the gas bubble shape is observed during heating. In the direct observation cell, the gas bubble is separated by a liquid film from the thin layered transparent heater deposited on the sapphire window. The liquid film drying and the triple contact line motion during heating are observed using light transmission. The experiments have been performed in a temperature range of 10 K below the critical temperature Tc, with special attention to the range 0.1 mK≤T-T≤3 mK very close to the critical temperature. The unique advantage of this investigation is to provide opportunities to observe the boiling phenomena at very low heat fluxes, thanks to the fine adjustment of the liquid-vapor properties, (e.g. surface tension), by precise control of the distance to the critical point. We present the new observations of the gas bubble spreading over the heating surface which characterizes the regime where vapor bubbles nucleate separately and grow, as well as liquid drying, vapor film formation, triple contact line motion, which are the key mechanisms at the origin of the boiling crisis when the formed vapor film reduces the heat transfer drastically at the heater wall.

  18. Nanofabrication of Point Contact Junctions for Spectroscopic Studies of High-Temperature Superconductors

    NASA Astrophysics Data System (ADS)

    Zhao, Han; Mehio, Omar; Park, Wan Kyu; Eckstein, James; Greene, Laura

    Point contact spectroscopy (PCS) probes the superconducting order parameter from Andreev reflection conductance spectrum. A new method to achieve robust junctions with a precise control of the geometry of the point contact by focused ion beam (FIB) nanofabrication techniques is currently under development. Preliminary application on niobium thin films shows consistent data that is insensitive to thermal cycling. This opens the possibility to perform PCS on a series of materials as a function of external variables, including temperature, magnetic field as a function of angle, and stress. Our preliminary data as a function of junction size show the expected resistance dependence, which will help us to determine more precisely when junctions are in the ballistic, or spectroscopic regime. Our plan is to apply this newly-developed method to probe the electronic nematic state in iron-based superconductors under applied magnetic field and uniaxial stress, to further understand the origin of the nematicity. This work is carried out in part in the Materials Research Lab, University of Illinois and is supported by the Center for Emergent Superconductivity, an Energy Frontier Research Center funded by the US DOE, Office of Science, Award No. DE-AC0298CH1088.

  19. High flux film and transition boiling

    SciTech Connect

    Witte, L.C.

    1990-01-01

    This report is a bench-scale experiment on transition boiling. The author gives a detailed description on experimental apparatus and conditions. The visual observed boiling phenomena; nucleate boiling and film boiling, and the effect of heat transfer are also elucidated. 10 refs., 11 figs., 1 tab.

  20. Flow boiling test of GDP replacement coolants

    SciTech Connect

    Park, S.H.

    1995-08-01

    The tests were part of the CFC replacement program to identify and test alternate coolants to replace CFC-114 being used in the uranium enrichment plants at Paducah and Portsmouth. The coolants tested, C{sub 4}F{sub 10} and C{sub 4}F{sub 8}, were selected based on their compatibility with the uranium hexafluoride process gas and how well the boiling temperature and vapor pressure matched that of CFC-114. However, the heat of vaporization of both coolants is lower than that of CFC-114 requiring larger coolant mass flow than CFC-114 to remove the same amount of heat. The vapor pressure of these coolants is higher than CFC-114 within the cascade operational range, and each coolant can be used as a replacement coolant with some limitation at 3,300 hp operation. The results of the CFC-114/C{sub 4}F{sub 10} mixture tests show boiling heat transfer coefficient degraded to a minimum value with about 25% C{sub 4}F{sub 10} weight mixture in CFC-114 and the degree of degradation is about 20% from that of CFC-114 boiling heat transfer coefficient. This report consists of the final reports from Cudo Technologies, Ltd.

  1. POOL BOILING OF HIGH-FREQUENCY CONDUCTORS

    SciTech Connect

    Wright, S. E.; Konecni, S.; Ammerman, C. N.; Sims, J. R.

    2001-01-01

    This study presents development of a unique, powerful method for cooling high-frequency, AC conductors that can benefit end users of transformer windings, electrical machine windings, and magnet coils. This method of heat removal involves boiling a dielectric, fluorinert refrigerant that is in direct contact with litz wire conductors. A pool boiling test vessel is constructed, which provides for temperature control of the pool of fluorinert liquid. The test vessel is fitted with viewing ports so that the experiments are observed and studied with the aid of high-speed photography. Tests are performed on a variety of litz wire conductors. The boiling heat transfer coefficient is dependent on the conductor surface roughness. The size of the features on the conductor surface depends on the single-strand wire gage from which the conductor is constructed. All tests are performed with the conductors mounted horizontally. These tests are performed using a DC power supply. The results of these experiments will aid in the design of future cooling systems.

  2. 46 CFR 154.705 - Cargo boil-off as fuel: General.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... space. (c) A gas fired main propulsion boiler or combustion engine must have a fuel oil fired pilot that... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo boil-off as fuel: General. 154.705 Section 154.705... Pressure and Temperature Control § 154.705 Cargo boil-off as fuel: General. (a) Each cargo boil-off...

  3. POINT 2012: ENDF/B-VII.1 Final Temperature Dependent Cross Section Library

    SciTech Connect

    Cullen, D E

    2012-02-26

    This report is one in the series of 'POINT' reports that over the years have presented temperature dependent cross sections for the then current version of ENDF/B [R1]. In each case I have used my personal computer at home and publicly available data and codes: (1) publicly available nuclear data (the current ENDF/B data, available on-line at the National Nuclear Data Center, Brookhaven National Laboratory, http://www.nndc.bnl.gov/) and, (2) publicly available computer codes (the current PREPRO codes, available on-line at the Nuclear Data Section, IAEA, Vienna, Austria, http://www-nds.iaea.or.at/ndspub/endf/prepro/) and, (3) My own personal computer located in my home. I have used these in combination to produce the temperature dependent cross sections used in applications and described in this report. I should mention that today anyone with a personal computer can produce these results: by its very nature I consider this data to be born in the public domain.

  4. Determination of the 1%, 2.5%, and 5% occurrences of extreme dew-point temperatures and mean coincident dry-bulb temperatures

    SciTech Connect

    Colliver, D.G.; Zhang, H.; Gates, R.; Priddy, T.

    1995-12-31

    The purpose of ASHRAE Research Project RP-754 was to find the outdoor design occurrences of extreme dew-point temperature and the corresponding mean coincident dry-bulb temperature for a large number of locations in North America. Thirty years of data (1961--1990) were used for 239 US locations, and the last 30 years of hourly data available (typically 1960--1989) were used for 143 Canadian locations. Tables are given that present the 1%, 2.5%, and 5% extreme summertime occurrences of dew-point temperatures and corresponding values of humidity ratios and the mean coincident dry-bulb (MCDB) temperature for the period of record. A map that shows the general geographical trends for the spatial distribution of the design dew-point values is also presented. Comparisons are provided between interpolation techniques to fill missing data, different weather data sets, and methods of calculating different definitions of extreme design and mean coincident data. Results are also reported of a comparison to evaluate the difference in humidity ratios between that calculated from the extreme design dry-bulb temperature and mean coincident wet-bulb temperature, versus that calculated from the extreme design dew-point temperature and the MCDB. It was found that the method of extreme dew point with MCDB had a higher humidity ratio that was on the average (for the 1% case and the 239 US locations) 0.00564 lb/lb larger than the humidity ratio found with the other method.

  5. Electrical Conductivity of Molten ZnCl2 at Temperature as High as 1421 K

    NASA Astrophysics Data System (ADS)

    Salyulev, Alexander B.; Potapov, Alexei M.

    2015-02-01

    The electrical conductivity of molten ZnCl2 was measured in a wide temperature range (?T=863 K) to a temperature as high as 1421 K that is 417 degrees above the boiling point of the salt. At the temperature maximum of the own vapor pressure of the salt reached several megapascals.

  6. Droplet Impingement Boiling on Heated Superhydrophobic Surfaces

    NASA Astrophysics Data System (ADS)

    Crockett, Julie; Clavijo, Cristian; Maynes, Daniel

    2015-11-01

    When a droplet impinges on a solid surface at a temperature well above the saturation temperature, vaporization of the liquid begins immediately after contact. Different boiling regimes may result depending on the surface temperature and volatility of the liquid. The nucleate boiling regime is characterized by explosive atomization, which occurs when vapor bubbles burst causing an extravagant shower of small micro droplets as well as the well-known ``sizzling'' sound. In this work, we show that the vapor is surprisingly re-directed during impingement on a superhydrophobic surface such that atomization is completely suppressed. We hypothesize that this occurs because vapor escapes through the superhydrophobic interface such that the top of the droplet remains free of bursting vapor bubbles. We explore a wide range of surface patterning with feature spacing of 8 to 32 microns and solid area fractions of 10 to 50 percent; surface temperatures from 100 C to 400 C; and Weber numbers of 1 to 100. Atomization is found to decrease with increasing feature spacing and decreasing solid fraction, and vanishes completely for large spacing. It may be that large feature spacing promotes early transition to the Leidenfrost regime.

  7. Simultaneous neutron radiography and infrared thermography measurement of boiling processes

    SciTech Connect

    Murphy, J.H.; Glickstein, S.S.

    1997-02-01

    Boiling of water at 1 to 15 bar flowing upward within a narrow duct and a round test section was observed using both neutron radiography and infrared (IR) thermography. The IR readings of the test section outer wall temperatures show the effects of both fluid temperature and wall heat transfer coefficient variations, producing a difference between liquid and two phase regions. The IR images, in fact, appear very similar to the neutron images; both show clear indications of spatial and temporal variations in the internal fluid conditions during the boiling process.

  8. Simultaneous neutron radiography and infrared thermography measurement of boiling processes

    SciTech Connect

    Murphy, J.H.; Glickstein, S.S.

    1996-12-31

    Boiling of water at 1 to 15 bar flowing upward within a narrow duct and a round test section was observed using both neutron radiography and infrared (IR) thermography. The IR readings of the test section outer wall temperatures show the effects of both fluid temperature and wall heat transfer coefficient variations, producing a difference between liquid and two phase regions. The IR images, in fact, appear very similar to the neutron images; both show clear indications of spatial and temporal variations in the internal fluid conditions during the boiling process.

  9. Stability monitoring for boiling water reactors

    NASA Astrophysics Data System (ADS)

    Cecenas-Falcon, Miguel

    1999-11-01

    A methodology is presented to evaluate the stability properties of Boiling Water Reactors based on a reduced order model, power measurements, and a non-linear estimation technique. For a Boiling Water Reactor, the feedback reactivity imposed by the thermal-hydraulics has an important effect in the system stability, where the dominant contribution to this feedback reactivity is provided by the void reactivity. The feedback reactivity is a function of the operating conditions of the system, and cannot be directly measured. However, power measurements are relatively easy to obtain from the nuclear instrumentation and process computer, and are used in conjunction with a reduced order model to estimate the gain of the thermal-hydraulics feedback using an Extended Kalman Filter. The reduced order model is obtained by estimating the thermal-hydraulic transfer function from the frequency-domain BWR code LAPUR, and the stability properties are evaluated based on the pair of complex conjugate eigenvalues. Because of the recursive nature of the Kalman Filter, an estimate of the decay ratio is generated every sampling time, allowing continuous estimation of the stability parameters. A test platform based on a nuclear-coupled boiling channel is developed to validate the capability of the BWR stability monitoring methodology. The thermal-hydraulics for the boiling channel is modeled and coupled with neutron kinetics to analyze the non-linear dynamics of the closed-loop system. The model uses point kinetics to study core-wide oscillations, and normalized modal kinetics are introduced to study out-of-phase oscillations. The coolant flow dynamics is dominant in the power fluctuations observed by in-core nuclear instrumentation, and additive white noise is added to the solution for the channel flow in the thermal-hydraulic model to generate noisy power time series. The operating conditions of the channel can be modified to accommodate a wide range of stability conditions. Autoregressive analysis performed with the computer-generated series agrees with the stability properties of the boiling channel and with the results of the reduced order model method. Finally, a method to separate the fundamental and first harmonic modes form LPRM readings is presented and tested with computer simulations and plant data.

  10. Construction and in-situ characterisation of high-temperature fixed point cells devoted to industrial applications

    NASA Astrophysics Data System (ADS)

    Sadli, Mohamed; Bourson, Frédéric; Diril, Ahmet; Journeau, Christophe; Lowe, Dave; Parga, Clemente

    2014-08-01

    Among the activities of the European Metrology Research Programme (EMRP) project HiTeMS one work package is devoted to the development and testing of industrial solutions for long-standing temperature measurement problems at the highest temperatures. LNE-Cnam, NPL, TUBITAK-UME have worked on the design of high temperature fixed points (HTFP) suitable for in-situ temperature monitoring to be implemented in the facilities of CEA (Commissariat à l'énergie atomique et aux énergies alternatives). Several high temperature fixed point cells were constructed in these three national metrology institutes (NMIs) using a rugged version of cells based on the hybrid design of the laboratory HTFP developed and continuously improved at LNE-Cnam during the last years. The fixed points of interest were Co-C, Ru-C and Re-C corresponding to melting temperatures of 1324 °C, 1953 °C and 2474 °C respectively. The cells were characterised at the NMIs after their construction. Having proved robust enough, they were transported to CEA and tested in an induction furnace and cycled from room temperature to temperatures much above the melting temperatures (> +400 °C) with extremely high heating and cooling rates (up to 10 000 K/h). All the cells withstood the tests and the melting plateaus could be observed in all cases.

  11. Zero Boil-Off System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, D. W.; Johnson, W. L.; Feller, J. R.

    2015-01-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration plans due to their high specific impulse for rocket motors of upper stages. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for long duration missions. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler temperature to control tank pressure. The technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  12. Zero boil-off system testing

    NASA Astrophysics Data System (ADS)

    Plachta, D. W.; Johnson, W. L.; Feller, J. R.

    2016-03-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration plans due to their high specific impulse for rocket motors of upper stages. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for long duration missions. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler temperature to control tank pressure. The technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  13. 46 CFR 154.707 - Cargo boil-off as fuel: Ventilation.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo boil-off as fuel: Ventilation. 154.707 Section 154... Equipment Cargo Pressure and Temperature Control § 154.707 Cargo boil-off as fuel: Ventilation. (a) A ventilation hood or casing must be installed in areas occupied by flanges, valves, and piping at the...

  14. 46 CFR 154.709 - Cargo boil-off as fuel: Gas detection equipment.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Cargo boil-off as fuel: Gas detection equipment. 154.709 Section 154.709 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS... Equipment Cargo Pressure and Temperature Control 154.709 Cargo boil-off as fuel: Gas detection...

  15. Numerical investigation on boiling flow of liquid nitrogen in a vertical tube using bubble number density approach

    NASA Astrophysics Data System (ADS)

    Shao, Xuefeng; Li, Xiangdong; Wang, Rongshun

    2016-04-01

    An average bubble number density (ABND) model was formulated and numerically resolved for the subcooled flow boiling of liquid nitrogen. The effects of bubble coalescence and breakup were taken into account. Some new closure correlations describing bubble nucleation and departure on the heating surface were selected as well. For the purpose of comparison, flow boiling of liquid nitrogen was also numerically simulated using a modified two-fluid model. The results show that the simulations performed by using the ABND model achieve encouraging improvement in accuracy in predicting heat flux and wall temperature of a vertical tube. Moreover, the influence of the bubble coalescence and breakup is shown to be great on predicting overall pressure beyond the transition point.

  16. Numerical investigation on boiling flow of liquid nitrogen in a vertical tube using bubble number density approach

    NASA Astrophysics Data System (ADS)

    Shao, Xuefeng; Li, Xiangdong; Wang, Rongshun

    2015-06-01

    An average bubble number density (ABND) model was formulated and numerically resolved for the subcooled flow boiling of liquid nitrogen. The effects of bubble coalescence and breakup were taken into account. Some new closure correlations describing bubble nucleation and departure on the heating surface were selected as well. For the purpose of comparison, flow boiling of liquid nitrogen was also numerically simulated using a modified two-fluid model. The results show that the simulations performed by using the ABND model achieve encouraging improvement in accuracy in predicting heat flux and wall temperature of a vertical tube. Moreover, the influence of the bubble coalescence and breakup is shown to be great on predicting overall pressure beyond the transition point.

  17. Zero Boil-Off System Testing

    NASA Technical Reports Server (NTRS)

    Plachta, David W.; Johnson, Wesley L.; Feller, Jeffrey R.

    2015-01-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration due to their high specific impulse for rocket motors of upper stages suitable for transporting 10s to 100s of metric tons of payload mass to destinations outside of low earth orbit and for their return. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for missions with durations greater than several months. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler to control tank pressure. The active thermal control technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center, in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. Testing consisted of three passive tests with the active cryocooler system off, and 7 active tests, with the cryocooler powered up. The test matrix included zero boil-off tests performed at 90 full and 25 full, and several demonstrations at excess cooling capacity and reduced cooling capacity. From this, the tank pressure response with varied cryocooler power inputs was determined. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  18. The initiation of boiling during pressure transients. [water boiling on metal surfaces

    NASA Technical Reports Server (NTRS)

    Weisman, J.; Bussell, G.; Jashnani, I. L.; Hsieh, T.

    1973-01-01

    The initiation of boiling of water on metal surfaces during pressure transients has been investigated. The data were obtained by a new technique in which light beam fluctuations and a pressure signal were simultaneously recorded on a dual beam oscilloscope. The results obtained agreed with those obtained using high speed photography. It was found that, for water temperatures between 90-150 C, the wall superheat required to initiate boiling during a rapid pressure transient was significantly higher than required when the pressure was slowly reduced. This result is explained by assuming that a finite time is necessary for vapor to fill the cavity at which the bubble originates. Experimental measurements of this time are in reasonably good agreement with calculations based on the proposed theory. The theory includes a new procedure for estimating the coefficient of vaporization.

  19. Basics of temperature pulse voltammetry.

    PubMed

    Voss, T; Kirbs, A; Gründler, P

    2000-06-01

    A new electrochemical technique is presented that allows peak-shaped voltammograms to be recorded at local temperature values from room temperature to above boiling point. This new method, temperature pulse voltammetry (TPV), is analogous to differential pulse voltammetry (DPV), but makes use of temperature jumps instead of potential pulses. Fundamentals are presented and potentialities demonstrated. As an example, ferrocyanide is investigated using a new kind of heated electrode on the basis of screen-printed gold layer structures on low-temperature cofired ceramics (LTCC) substrates. PMID:11225852

  20. Heat Transfer in Boiling Dilute Emulsion with Strong Buoyancy

    NASA Astrophysics Data System (ADS)

    Freeburg, Eric Thomas

    Little attention has been given to the boiling of emulsions compared to that of boiling in pure liquids. The advantages of using emulsions as a heat transfer agent were first discovered in the 1970s and several interesting features have since been studied by few researchers. Early research focuses primarily on pool and flow boiling and looks to determine a mechanism by which the boiling process occurs. This thesis looks at the boiling of dilute emulsions in fluids with strong buoyant forces. The boiling of dilute emulsions presents many favorable characteristics that make it an ideal agent for heat transfer. High heat flux electronics, such as those seen in avionics equipment, produce high heat fluxes of 100 W/cm2 or more, but must be maintained at low temperatures. So far, research on single phase convection and flow boiling in small diameter channels have yet to provide an adequate solution. Emulsions allow the engineer to tailor the solution to the specific problem. The fluid can be customized to retain the high thermal conductivity and specific heat capacity of the continuous phase while enhancing the heat transfer coefficient through boiling of the dispersed phase component. Heat transfer experiments were carried out with FC-72 in water emulsions. FC-72 has a saturation temperature of 56 °C, far below that of water. The parameters were varied as follows: 0% ≤ epsilon ≤ 1% and 1.82 x 1012 ≤ RaH ≤ 4.42 x 1012. Surface temperatures along the heated surface reached temperature that were 20 °C in excess of the dispersed phase saturation temperature. An increase of ˜20% was seen in the average Nusselt numbers at the highest Rayleigh numbers. Holography was used to obtain images of individual and multiple FC-72 droplets in the boundary layer next to the heated surface. The droplet diameters ranged from 0.5 mm to 1.3 mm. The Magnus effect was observed when larger individual droplets were injected into the boundary layer, causing the droplets to be pushed outside the boundary layer. Vaporization of FC-72 droplets in the boundary layer next to the heated surface was not observed.

  1. Enhanced boiling heat transfer using radial fins

    NASA Astrophysics Data System (ADS)

    Razelos, P.; Das, S.; Krikkis, R. N.

    2008-04-01

    A numerical bifurcation analysis is carried out in order to determine the solution structure of radial fins subjected to multi-boiling heat transfer mode. One-dimensional conduction is employed throughout the thermal analysis. The fluid heat transfer coefficient is temperature dependent on the three regimes of phase-change of the fluid. Six fin profiles, defined in the text, are considered. Multiplicity structure is obtained to determine different types of bifurcation diagrams, which describe the dependence of a state variable of the system like the temperature or the heat dissipation on the fin design parameters, conduction convection parameter (CCP) or base temperature difference (Δ T). Specifically, the effects of Δ T, CCP and Biot number are analyzed. The results are presented graphically, showing the significant behavioral features of the heat rejection mechanism.

  2. Cryogenic temperature monitoring in superconducting power transmission line at CERN with hybrid multi-point and distributed fiber optic sensors

    NASA Astrophysics Data System (ADS)

    Chiuchiolo, A.; Palmieri, L.; Consales, M.; Giordano, M.; Bajas, H.; Galtarossa, A.; Bajko, M.; Cusano, A.

    2015-09-01

    Distributed and multi-point fiber-optic based measurements of cryogenic temperature down to 30 K are presented. Measurements have been performed along the cryostat of a superconducting power transmission line, which is currently being tested at CERN over a length of about 20 m. Multi-point measurements were based on two kinds of FBG with different coatings (epoxy and PMMA). In addition, distributed measurements exploited optical frequency-domain reflectometry to analyze the Rayleigh scattering along two concatenated fibers with different coatings (acrylate and polyimmide). Results confirm the viability of these approaches to monitor cryogenic temperatures along a superconducting transmission line.

  3. The Boiling eXperiment Facility (BXF) for the Microgravity Science Glovebox (MSG)

    NASA Technical Reports Server (NTRS)

    McQuillen, John; Chao, David; Vergilii, Frank

    2006-01-01

    Boiling is an effective means of cooling by removing heat from surfaces through vaporization of a working fluid. It is also affected by both the magnitude and direction of gravity. By conducting pool boiling tests in microgravity, the effect of buoyancy n the overall boiling process and the relative magnitude of other phenomena can be assessed. The Boiling eXperiment Facility (BXF) is being built for the Microgravity Science Glovebox. This facility will conduct two pool boiling studies. The first study the Microheater Array Boiling Experiment (MABE) uses two 96 element microheater arrays, 2.7 mm and 7.0 mm in size, to measure localized hear fluxes while operating at a constant temperature. The other experiment, the Nucleate Pool Boiling eXperiment (NPBX) uses a 85 mm diameter heater wafer that has been "seeded" with five individually-controlled nucleation sites to study bubble nucleation, growth, coalescence and departure. The BXF uses normal-perfluorohexane as the test fluid and will operate between pressures of 60 to 244 Pa. and temperatures of 35 to 60 C. Both sets of experimental heaters are highly instrumented. Pressure and bulk fluid temperature measurements will be made with standard rate video. A high speed video system will be used to visualize the boiling process through the bottom of the MABE heater arrays. The BXF is currently scheduled to fly on Utilization Flight-13A.1 to the ISS with facility integration into the MSG and operation during Increment 15

  4. Research on radiation detectors, boiling transients, and organic lubricants

    NASA Technical Reports Server (NTRS)

    1974-01-01

    The accomplishments of a space projects research facility are presented. The subjects discussed are: (1) a study of radiation resistant semiconductor devices, (2) synthesis of high temperature organic lubricants, (3) departure from phase equilibrium during boiling transients, (4) effects of neutron irradiation on defect state in tungsten, and (5) determination of photon response function of NE-213 liquid scintillation detectors.

  5. On Boiling of Crude Oil under Elevated Pressure

    NASA Astrophysics Data System (ADS)

    Pimenova, Anastasiya V.; Goldobin, Denis S.

    2016-02-01

    We construct a thermodynamic model for theoretical calculation of the boiling process of multicomponent mixtures of hydrocarbons (e.g., crude oil). The model governs kinetics of the mixture composition in the course of the distillation process along with the boiling temperature increase. The model heavily relies on the theory of dilute solutions of gases in liquids. Importantly, our results are applicable for modelling the process under elevated pressure (while the empiric models for oil cracking are not scalable to the case of extreme pressure), such as in an oil field heated by lava intrusions.

  6. Boiling effect in liquid nitrogen directly cooled Yb3+:YAG laser.

    PubMed

    Sakurai, Toshimitsu; Chosrowjan, Haik; Furuse, Hiroaki; Taniguchi, Seiji; Kitamura, Toshiyuki; Fujita, Masayuki; Ishii, Shinya; Izawa, Yasukazu

    2016-02-20

    Liquid nitrogen (LN2) behavior on the surface of excited Yb3+:YAG is investigated using fluorometry. From the time-resolved temperature variations and integrated fluorescence spectra intensity on this directly cooled Yb3+:YAG surface, we observe a phase transition of LN2 from nucleate boiling to film boiling. As a result of this pool boiling, good beam quality should occur when the temperature and heat flux at an excited surface of Yb3+:YAG are below 95 K and 15.8??W/cm2, respectively. That is, the LN2 should remain in a steady state of nucleate boiling to produce good beam quality using pool boiling. PMID:26906588

  7. Gravity and Heater Size Effects on Pool Boiling Heat Transfer

    NASA Technical Reports Server (NTRS)

    Kim, Jungho; Raj, Rishi

    2014-01-01

    The current work is based on observations of boiling heat transfer over a continuous range of gravity levels between 0g to 1.8g and varying heater sizes with a fluorinert as the test liquid (FC-72/n-perfluorohexane). Variable gravity pool boiling heat transfer measurements over a wide range of gravity levels were made during parabolic flight campaigns as well as onboard the International Space Station. For large heaters and-or higher gravity conditions, buoyancy dominated boiling and heat transfer results were heater size independent. The power law coefficient for gravity in the heat transfer equation was found to be a function of wall temperature under these conditions. Under low gravity conditions and-or for smaller heaters, surface tension forces dominated and heat transfer results were heater size dependent. A pool boiling regime map differentiating buoyancy and surface tension dominated regimes was developed along with a unified framework that allowed for scaling of pool boiling over a wide range of gravity levels and heater sizes. The scaling laws developed in this study are expected to allow performance quantification of phase change based technologies under variable gravity environments eventually leading to their implementation in space based applications.

  8. Liquid phase stability under an extreme temperature gradient.

    PubMed

    Liang, Zhi; Sasikumar, Kiran; Keblinski, Pawel

    2013-11-27

    Using nonequilibrium molecular dynamics simulations, we subject bulk liquid to a very high-temperature gradient and observe a stable liquid phase with a local temperature well above the boiling point. Also, under this high-temperature gradient, the vapor phase exhibits condensation into a liquid at a temperature higher than the saturation temperature, indicating that the observed liquid stability is not caused by nucleation barrier kinetics. We show that, assuming local thermal equilibrium, the phase change can be understood from the thermodynamic analysis. The observed elevation of the boiling point is associated with the interplay between the "bulk" driving force for the phase change and surface tension of the liquid-vapor interface that suppresses the transformation. This phenomenon is analogous to that observed for liquids in confined geometries. In our study, however, a low-temperature liquid, rather than a solid, confines the high-temperature liquid. PMID:24329454

  9. Liquid Phase Stability Under an Extreme Temperature Gradient

    NASA Astrophysics Data System (ADS)

    Liang, Zhi; Sasikumar, Kiran; Keblinski, Pawel

    2013-11-01

    Using nonequilibrium molecular dynamics simulations, we subject bulk liquid to a very high-temperature gradient and observe a stable liquid phase with a local temperature well above the boiling point. Also, under this high-temperature gradient, the vapor phase exhibits condensation into a liquid at a temperature higher than the saturation temperature, indicating that the observed liquid stability is not caused by nucleation barrier kinetics. We show that, assuming local thermal equilibrium, the phase change can be understood from the thermodynamic analysis. The observed elevation of the boiling point is associated with the interplay between the “bulk” driving force for the phase change and surface tension of the liquid-vapor interface that suppresses the transformation. This phenomenon is analogous to that observed for liquids in confined geometries. In our study, however, a low-temperature liquid, rather than a solid, confines the high-temperature liquid.

  10. Boiling heat transfer on fins - experimental and numerical procedure

    NASA Astrophysics Data System (ADS)

    Orzechowski, T.; Tyburczyk, A.

    2014-03-01

    The paper presents the research methodology, the test facility and the results of investigations into non-isothermal surfaces in water boiling at atmospheric pressure, together with a discussion of errors. The investigations were conducted for two aluminium samples with technically smooth surfaces and thickness of 4 mm and 10 mm, respectively. For the sample of lower thickness, on the basis of the surface temperature distribution measured with an infrared camera, the local heat flux and the heat transfer coefficient were determined and shown in the form of a boiling curve. For the thicker sample, for which 1-D model cannot be used, numerical calculations were conducted. They resulted in obtaining the values of the local heat flux on the surface the invisible to the infrared, camera i.e. on the side on which the boiling of the medium proceeds.

  11. Turning point temperature and competition between relativistic and ponderomotive effects in self-focusing of laser beam in plasma

    SciTech Connect

    Bokaei, B.; Niknam, A. R.; Jafari Milani, M. R.

    2013-10-15

    The propagation characters of Gaussian laser beam in collisionless plasma are investigated by considering the ponderomotive and relativistic nonlinearities. The second-order differential equation of dimensionless beam width parameter is solved numerically, taking into account the effect of electron temperature. The results show that the ponderomotive force does not facilitate the relativistic self-focusing in all intensity ranges. In fact, there exists a certain intensity value that, if below this value, the ponderomotive nonlinearity can contribute to the relativistic self-focusing, or obstruct it, if above. It is also indicated that there is a temperature interval in which self-focusing can occur, while the beam diverges outside of this region. In addition, the results represent the existence of a “turning point temperature” in the mentioned interval that the self-focusing has the strongest power. The value of the turning point is dependent on laser intensity in which higher intensities result in higher turning point.

  12. Temperature and pressure dependence of the Raman frequency shifts near the melting point in ice I.

    PubMed

    Yurtseven, H; Karaçali, H

    2006-06-01

    This study examines the validity of the spectroscopic modification of the Pippard relations for the hexagonal ice (ice I) close to the melting point. A linear variation of the specific heat CP with the frequency shifts EQUATION: SEE TEXT is obtained for ice I. This linearity is also obtained between thermal expansivity alphaP and the frequency shifts EQUATION: SEE TEXT close to the melting point in this crystal. PMID:16442839

  13. Evaluation of correlations of flow boiling heat transfer of R22 in horizontal channels.

    PubMed

    Zhou, Zhanru; Fang, Xiande; Li, Dingkun

    2013-01-01

    The calculation of two-phase flow boiling heat transfer of R22 in channels is required in a variety of applications, such as chemical process cooling systems, refrigeration, and air conditioning. A number of correlations for flow boiling heat transfer in channels have been proposed. This work evaluates the existing correlations for flow boiling heat transfer coefficient with 1669 experimental data points of flow boiling heat transfer of R22 collected from 18 published papers. The top two correlations for R22 are those of Liu and Winterton (1991) and Fang (2013), with the mean absolute deviation of 32.7% and 32.8%, respectively. More studies should be carried out to develop better ones. Effects of channel dimension and vapor quality on heat transfer are analyzed, and the results provide valuable information for further research in the correlation of two-phase flow boiling heat transfer of R22 in channels. PMID:23956695

  14. Evaluation of Correlations of Flow Boiling Heat Transfer of R22 in Horizontal Channels

    PubMed Central

    Fang, Xiande; Li, Dingkun

    2013-01-01

    The calculation of two-phase flow boiling heat transfer of R22 in channels is required in a variety of applications, such as chemical process cooling systems, refrigeration, and air conditioning. A number of correlations for flow boiling heat transfer in channels have been proposed. This work evaluates the existing correlations for flow boiling heat transfer coefficient with 1669 experimental data points of flow boiling heat transfer of R22 collected from 18 published papers. The top two correlations for R22 are those of Liu and Winterton (1991) and Fang (2013), with the mean absolute deviation of 32.7% and 32.8%, respectively. More studies should be carried out to develop better ones. Effects of channel dimension and vapor quality on heat transfer are analyzed, and the results provide valuable information for further research in the correlation of two-phase flow boiling heat transfer of R22 in channels. PMID:23956695

  15. LANDSCAPE SCALE NON-POINT SOURCE POLLUTION TEMPERATURE ASSESSMENT AND TMDL DEVELOPMENT

    EPA Science Inventory

    THIS IS AN ONGOING PROJECT. Elevated river temperature is a significant water quality issue in the Pacific Northwest. For example, over 12,000 miles of perennial streams are designated 303(d) water quality limited due to temperature violation in the State of Oregon. Over t...

  16. Boyle temperature as a point of ideal gas in gentile statistics and its economic interpretation

    NASA Astrophysics Data System (ADS)

    Maslov, V. P.; Maslova, T. V.

    2014-07-01

    Boyle temperature is interpreted as the temperature at which the formation of dimers becomes impossible. To Irving Fisher's correspondence principle we assign two more quantities: the number of degrees of freedom, and credit. We determine the danger level of the mass of money M when the mutual trust between economic agents begins to fall.

  17. Laboratory study of non-aqueous phase liquid and water co-boiling during thermal treatment.

    PubMed

    Zhao, C; Mumford, K G; Kueper, B H

    2014-08-01

    In situ thermal treatment technologies, such as electrical resistance heating and thermal conductive heating, use subsurface temperature measurements in addition to the analysis of soil and groundwater samples to monitor remediation performance. One potential indication of non-aqueous phase liquid (NAPL) removal is an increase in temperature following observations of a co-boiling plateau, during which subsurface temperatures remain constant as NAPL and water co-boil. However, observed co-boiling temperatures can be affected by the composition of the NAPL and the proximity of the NAPL to the temperature measurement location. Results of laboratory heating experiments using single-component and multi-component NAPLs showed that local-scale temperature measurements can be mistakenly interpreted as an indication of the end of NAPL-water co-boiling, and that significant NAPL saturations (1% to 9%) remain despite observed increases in temperature. Furthermore, co-boiling of multi-component NAPL results in gradually increasing temperature, rather than a co-boiling plateau. Measurements of gas production can serve as a complementary metric for assessing NAPL removal by providing a larger-scale measurement integrated over multiple smaller-scale NAPL locations. Measurements of the composition of the NAPL condensate can provide ISTT operators with information regarding the progress of NAPL removal for multi-component sources. PMID:24950371

  18. Flow regimes and mechanistic modeling of critical heat flux under subcooled flow boiling conditions

    NASA Astrophysics Data System (ADS)

    Le Corre, Jean-Marie

    Thermal performance of heat flux controlled boiling heat exchangers are usually limited by the Critical Heat Flux (CHF) above which the heat transfer degrades quickly, possibly leading to heater overheating and destruction. In an effort to better understand the phenomena, a literature review of CHF experimental visualizations under subcooled flow boiling conditions was performed and systematically analyzed. Three major types of CHF flow regimes were identified (bubbly, vapor clot and slug flow regime) and a CHF flow regime map was developed, based on a dimensional analysis of the phenomena and available data. It was found that for similar geometric characteristics and pressure, a Weber number (We)/thermodynamic quality (x) map can be used to predict the CHF flow regime. Based on the experimental observations and the review of the available CHF mechanistic models under subcooled flow boiling conditions, hypothetical CHF mechanisms were selected for each CHF flow regime, all based on a concept of wall dry spot overheating, rewetting prevention and subsequent dry spot spreading. It is postulated that a high local wall superheat occurs locally in a dry area of the heated wall, due to a cyclical event inherent to the considered CHF two-phase flow regime, preventing rewetting (Leidenfrost effect). The selected modeling concept has the potential to span the CHF conditions from highly subcooled bubbly flow to early stage of annular flow. A numerical model using a two-dimensional transient thermal analysis of the heater undergoing nucleation was developed to mechanistically predict CHF in the case of a bubbly flow regime. In this type of CHF two-phase flow regime, the high local wall superheat occurs underneath a nucleating bubble at the time of bubble departure. The model simulates the spatial and temporal heater temperature variations during nucleation at the wall, accounting for the stochastic nature of the boiling phenomena. The model has also the potential to evaluate the post-DNB heater temperature up to the point of heater melting. Validation of the proposed model was performed using detailed measured wall boiling parameters near CHF, thereby bypassing most needed constitutive relations. It was found that under limiting nucleation conditions; a peak wall temperature at the time of bubble departure can be reached at CHF preventing wall cooling by quenching. The simulations show that the resulting dry patch can survive the surrounding quenching event, preventing further nucleation and leading to a fast heater temperature increase. For more practical applications, the model was applied at known CHF conditions in simple geometry coupled with one-dimensional and three-dimensional (CFD) codes. It was found that, in the case where CHF occurs under bubbly flow conditions, the local wall superheat underneath nucleating bubbles is predicted to reach the Leidenfrost temperature. However, a better knowledge of statistical variations in wall boiling parameters would be necessary to correctly capture the CHF trends with mass flux (or Weber number). In addition, consideration of relevant parameter influences on the Leidenfrost temperature and consideration of interfacial microphysics at the wall would allow improved simulation of the wall rewetting prevention and subsequent dry patch spreading.

  19. Loop Heat Pipe Transient Behavior Using Heat Source Temperature for Set Point Control with Thermoelectric Converter on Reservoir

    NASA Technical Reports Server (NTRS)

    Ku, Jentung; Paiva, Kleber; Mantelli, Marcia

    2011-01-01

    The LHP operating temperature is governed by the saturation temperature of its reservoir. Controlling the reservoir saturation temperature is commonly done by cold biasing the reservoir and using electrical heaters to provide the required control power. With this method, the loop operating temperature can be controlled within 0.5K or better. However, because the thermal resistance that exists between the heat source and the LHP evaporator, the heat source temperature will vary with its heat output even if the LHP operating temperature is kept constant. Since maintaining a constant heat source temperature is of most interest, a question often raised is whether the heat source temperature can be used for LHP set point temperature control. A test program with a miniature LHP was carried out to investigate the effects on the LHP operation when the control temperature sensor was placed on the heat source instead of the reservoir. In these tests, the LHP reservoir was cold-biased and was heated by a control heater. Test results show that it was feasible to use the heat source temperature for feedback control of the LHP operation. In particular, when a thermoelectric converter was used as the reservoir control heater, the heat source temperature could be maintained within a tight range using a proportional-integral-derivative or on/off control algorithm. Moreover, because the TEC could provide both heating and cooling to the reservoir, temperature oscillations during fast transients such as loop startup could be eliminated or substantially reduced when compared to using an electrical heater as the control heater.

  20. Computations of Boiling in Microgravity

    NASA Technical Reports Server (NTRS)

    Tryggvason, Gretar; Jacqmin, David

    1999-01-01

    The absence (or reduction) of gravity, can lead to major changes in boiling heat transfer. On Earth, convection has a major effect on the heat distribution ahead of an evaporation front, and buoyancy determines the motion of the growing bubbles. In microgravity, convection and buoyancy are absent or greatly reduced and the dynamics of the growing vapor bubbles can change in a fundamental way. In particular, the lack of redistribution of heat can lead to a large superheat and explosive growth of bubbles once they form. While considerable efforts have been devoted to examining boiling experimentally, including the effect of microgravity, theoretical and computational work is limited to very simple models. In this project, the growth of boiling bubbles is studied by direct numerical simulations where the flow field is fully resolved and the effects of inertia, viscosity, surface deformation, heat conduction and convection, as well as the phase change, are fully accounted for. The proposed work is based on previously funded NASA work that allowed us to develop a two-dimensional numerical method for boiling flows and to demonstrate the ability of the method to simulate film boiling. While numerical simulations of multi-fluid flows have been advanced in a major way during the last five years, or so, similar capability for flows with phase change are still in their infancy. Although the feasibility of the proposed approach has been demonstrated, it has yet to be extended and applied to fully three-dimensional simulations. Here, a fully three-dimensional, parallel, grid adaptive code will be developed. The numerical method will be used to study nucleate boiling in microgravity, with particular emphasis on two aspects of the problem: 1) Examination of the growth of bubbles at a wall nucleation site and the instabilities of rapidly growing bubbles. Particular emphasis will be put on accurately capturing the thin wall layer left behind as a bubble expands along a wall, on computing instabilities on bubble surfaces as bubbles grow, and on quantifying the effects of both these phenomena on heat transfer; and 2) Examination of the effect of shear flow on bubble growth and heat transfer.

  1. 46 CFR 154.708 - Cargo boil-off as fuel: Valves.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Pressure and Temperature Control § 154.708 Cargo boil-off as fuel: Valves. (a) Gas fuel lines to the gas... valves under paragraph (a) of this section must be arranged so that loss of boiler forced draft,...

  2. 46 CFR 154.708 - Cargo boil-off as fuel: Valves.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Pressure and Temperature Control § 154.708 Cargo boil-off as fuel: Valves. (a) Gas fuel lines to the gas... valves under paragraph (a) of this section must be arranged so that loss of boiler forced draft,...

  3. 46 CFR 154.708 - Cargo boil-off as fuel: Valves.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Pressure and Temperature Control § 154.708 Cargo boil-off as fuel: Valves. (a) Gas fuel lines to the gas... valves under paragraph (a) of this section must be arranged so that loss of boiler forced draft,...

  4. 46 CFR 154.708 - Cargo boil-off as fuel: Valves.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Pressure and Temperature Control § 154.708 Cargo boil-off as fuel: Valves. (a) Gas fuel lines to the gas... valves under paragraph (a) of this section must be arranged so that loss of boiler forced draft,...

  5. Electrical effects in measurements at the silver point using high temperature SPRTs

    NASA Astrophysics Data System (ADS)

    Widiatmo, J. V.; Harada, K.; Yamazawa, K.; Tamba, J.; Arai, M.

    2013-09-01

    In this work, measurements at the silver point using various types of HTSPRT are conducted, with a focus on finding a reliable thermal and electrical condition for an HTSPRT calibration. Sodium heat pipe furnaces, operating on DC power supply, are used. A platinum wire is bound to the graphite crucible of one of silver point cells used, through which a DC voltage bias can be provided. The effect of the DC voltage bias and of the heat pipe ground-connection to the HTSPRT reading at silver point is evaluated. Cell comparisons are also performed at various ground-connection conditions. A method for estimating the uncertainty due to such effect in an HTSPRT calibration at silver point is proposed. At the request of the authors and the Proceedings Editor the above article has been amended due to errors discovered in the published paper. A corrected version of this article has now been published together with a List of Changes attached at the end of the corrected article. For reference, the original published version of the article is also attached and follows after the List of Changes. The corrected article was published on 24 September 2013.

  6. Temperature and pressure dependence of the mode Grüneisen parameters close to the melting point in hexagonal ice

    NASA Astrophysics Data System (ADS)

    Karacali, H.; Yurtseven, H.

    2007-02-01

    We reexamine the Pippard relations in this study by relating the specific heat CP to the Raman frequency shifts 1/ν∂ and the thermal expansivity αp to the 1/ν∂, when the mode Grüneisen parameter depends on the temperature and pressure close to the melting point in hexagonal ice. From linear relations between them, the values of the slope {dP}/{dT} are deduced in this crystal. Our slope values calculated here do not change significantly compared to those obtained when the mode Grüneisen parameter is taken as a constant close to the melting point in hexagonal ice.

  7. Marangoni Effects in the Boiling of Binary Fluid Mixtures

    NASA Technical Reports Server (NTRS)

    Ahmed, Sayeed; Carey, Van P.; Motil, Brian

    1996-01-01

    Results of very recent experimental studies indicate that during nucleate boiling in some binary mixture, Marangoni effects augment the gravity driven flow of liquid towards the heated surface. With gravity present, it is impossible to separate the two effects. The reduced gravity environment gives an unique opportunity to explore th role of Marangoni effects on the boiling mechanisms free of gravitational body forces that obscure the role of such effects. However, recent experimental results suggest that under reduced gravity conditions, Marangoni effects is the dominant mechanism of vapor-liquid exchange at the surface for some binary mixture. To further explore such effects, experiments have been conducted with water/2-propanol mixtures at three different concentrations under normal gravity with different orientations of the heater surface and under reduce gravity aboard the DC-9 aircraft at NASA Lewis Research Center. The system pressure was sub atmospheric (approx. 8 kP at 1g(n)) and the bulk liquid temperature varied from low subcooling to near saturation. The molar concentrations of 2-propanol tested were 0.015, 0.025, and 0.1. Boiling curves were obtained both for high gravity (approx. 2g(n)) and reduce gravity (approx. 0.01g(n)). For each concentration of 2-propanol, the critical heat flux has been determined in the flight experiments only for reduced gravity conditions. Comparison of boiling curves and CHF obtained under l-g(n) an reduced gravity indicates that boiling mechanism in this mixtures is nearly independent of gravity. The results also indicate that the Marangoni mechanism is strong enough in these mixtures to sustain the boiling under reduced gravity conditions.

  8. A hybrid Raman/EFPI/FBG sensing system for distributed temperature and key-point pressure measurements

    NASA Astrophysics Data System (ADS)

    Chen, Ke; Zhou, Xinlei; Yang, Yang; Yu, Qingxu

    2015-08-01

    We demonstrate a hybrid sensing scheme, combining the incoherent optical frequency domain reflectometry (IOFDR) based Raman distributed temperature sensor (DTS) with the extrinsic Fabry-Perot interferometer (EFPI) based pressure sensor, for down-hole monitoring. The pressure measurement is compensated by a fiber Bragg grating (FBG) based temperature sensor. By using a laser diode as the common light source, a hybrid Raman/EFPI/FBG sensing system has been developed with a single fiber. The stimulated emission light and the spontaneous emission light of the laser diode are used for DTS and EFPI-FBG interrogations respectively. There can be no overlap between the spectral range of the Raman backscattered light and the spectral range of the reflected light from the EFPI-FBG sensor. Distributed temperature and pressure can thus be measured by using wavelength-division multiplexing (WDM) technology. Experimental results show that, both the distributed temperature and the key-point pressure can be measured alternatively with little interference.

  9. ATWS Analysis with an Advanced Boiling Curve Approach within COBRA 3-CP

    SciTech Connect

    Gensler, A.; Knoll, A.; Kuehnel, K.

    2007-07-01

    In 2005 the German Reactor Safety Commission issued specific requirements on core coolability demonstration for PWR ATWS (anticipated transients without scram). Thereupon AREVA NP performed detailed analyses for all German PWRs. For a German KONVOI plant the results of an ATWS licensing analysis are presented. The plant dynamic behavior is calculated with NLOOP, while the hot channel analysis is performed with the thermal hydraulic computer code COBRA 3-CP. The application of the fuel rod model included in COBRA 3-CP is essential for this type of analysis. Since DNB (departure from nucleate boiling) occurs, the advanced post DNB model (advanced boiling curve approach) of COBRA 3-CP is used. The results are compared with those gained with the standard BEEST model. The analyzed ATWS case is the emergency power case 'loss of main heat sink with station service power supply unavailable'. Due to the decreasing coolant flow rate during the transient the core attains film boiling conditions. The results of the hot channel analysis strongly depend on the performance of the boiling curve model. The BEEST model is based on pool boiling conditions whereas typical PWR conditions - even in most transients - are characterized by forced flow for which the advanced boiling curve approach is particularly suitable. Compared with the BEEST model the advanced boiling curve approach in COBRA 3-CP yields earlier rewetting, i.e. a shorter period in film boiling. Consequently, the fuel rod cladding temperatures, that increase significantly due to film boiling, drop back earlier and the high temperature oxidation is significantly diminished. The Baker-Just-Correlation was used to calculate the value of equivalent cladding reacted (ECR), i.e. the reduction of cladding thickness due to corrosion throughout the transient. Based on the BEEST model the ECR value amounts to 0.4% whereas the advanced boiling curve only leads to an ECR value of 0.2%. Both values provide large margins to the 17% ECR limit. The maximum cladding temperature calculated with both models is almost identical. It results in approximately 830 deg. C, i.e. far below the embrittlement temperature (stipulated at 1200 deg. C). Core coolability was demonstrated with both models, with the BEEST model and with the advanced boiling curve approach. However, the advanced boiling curve approach results in more realistic values and reveals that a much higher safety margin exists. This advantage can be applied to all types of transient hot channel analyses which have to treat film boiling phases. (authors)

  10. Development of a Multi-Point Pyrometer System (MPPS) for measuring surface temperature and emissivity

    SciTech Connect

    Benton, R.D.; Jang, Ping-Rey

    1993-06-01

    In support of the US DOE MHD research program, the Diagnostic Instrumentation and Analysis Laboratory (DIAL) has been actively engaged in developing and applying advanced optical diagnostic techniques and instrumentation systems to high temperature coal-fired gas streams for over a decade. One of the earliest diagnostic systems developed by DIAL was a two color pyrometer (TCP). In this system, two commercial single-color pyrometers and a microprocessor system were used to form a TCP which can make accurate measurements of surfaces of unknown emissivity and temperature. This system has been used extensively to make measurements in support of the national MHD program. This report describes this system.

  11. Quantum point contact displacement transducer for a mechanical resonator at sub-Kelvin temperatures

    SciTech Connect

    Okazaki, Yuma; Mahboob, Imran; Onomitsu, Koji; Sasaki, Satoshi; Yamaguchi, Hiroshi

    2013-11-04

    Highly sensitive displacement transduction of a 1.67 MHz mechanical resonator with a quantum point contact (QPC) formed in a GaAs heterostructure is demonstrated. By positioning the QPC at the point of maximum mechanical strain on the resonator and operating at 80 mK, a displacement responsivity of 3.81 A/m is measured, which represents a two order of magnitude improvement on the previous QPC based devices. By further analyzing the QPC transport characteristics, a sub-Poisson-noise-limited displacement sensitivity of 25 fm/Hz{sup 1/2} is determined which corresponds to a position resolution that is 23 times the standard quantum limit.

  12. High freezing point fuels used for aviation turbine engines

    NASA Technical Reports Server (NTRS)

    Friedman, R.

    1979-01-01

    Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating.

  13. Experimental study of boiling phenomena and heat transfer performances of FC-72 over micro-pin-finned silicon chips

    NASA Astrophysics Data System (ADS)

    Wei, J. J.; Guo, L. J.; Honda, H.

    2005-06-01

    Experiments were conducted to study the effects of micro-pin-fins on boiling phenomena and heat transfer from square simulated silicon chips immersed in a pool of FC-72. Two kinds of micro-pin-fins having fin thickness of 30 μm and fin heights of 60 and 200 μm, respectively, were fabricated on the silicon chip surface with the dry etching technique. The experiments were conducted at the liquid subcoolings of 3, 25, 35 and 45 K. The effects of dissolved air in FC-72 and chip orientation were also investigated. The boiling curve of the micro-pin-finned chips was characterized by a very small increase in wall superheat with increasing heat flux, and the wall temperatures at the CHF point for all the micro-pin-finned chips were less than the upper limit for the reliable operation of LSI chips (Tw=85°C). Liquid subcooling was very effective in elevating CHF for the micro-pin-finned chips compared to the smooth surface and other treated surfaces. The enhanced boiling heat transfer mechanisms for the micro-pin-finned chips were discussed.

  14. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... sensor or thermometer required by § 153.440(a)(3) or (c). If a portable thermometer is used, it must be located as prescribed for the temperature sensor in § 153.440(a)(3). (2) A total of 2 readings must...

  15. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ..., LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Documents and Cargo Information § 153.908... sensor or thermometer required by § 153.440(a)(3) or (c). If a portable thermometer is used, it must be located as prescribed for the temperature sensor in § 153.440(a)(3). (2) A total of 2 readings must...

  16. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ..., LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Documents and Cargo Information § 153.908... sensor or thermometer required by § 153.440(a)(3) or (c). If a portable thermometer is used, it must be located as prescribed for the temperature sensor in § 153.440(a)(3). (2) A total of 2 readings must...

  17. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ..., LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Documents and Cargo Information § 153.908... sensor or thermometer required by § 153.440(a)(3) or (c). If a portable thermometer is used, it must be located as prescribed for the temperature sensor in § 153.440(a)(3). (2) A total of 2 readings must...

  18. 46 CFR 153.908 - Cargo viscosity and melting point information; measuring cargo temperature during discharge...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ..., LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Documents and Cargo Information § 153.908... sensor or thermometer required by § 153.440(a)(3) or (c). If a portable thermometer is used, it must be located as prescribed for the temperature sensor in § 153.440(a)(3). (2) A total of 2 readings must...

  19. Coherent anti-stokes Raman spectroscopy system for point temperature and major species concentration measurement

    SciTech Connect

    Singh, J.P.; Yueh, Fang-Yu

    1993-10-01

    The Coherent anti-Stokes Raman Spectroscopy system (CARS) has been developed as a laser-based, advanced, combustion-diagnostic technique to measure temperature and major species concentration. Principles of operation, description of the system and its capabilities, and operational details of this instrument are presented in this report.

  20. Rotational cars application to simultaneous and multiple-point temperature and concentration determination in a turbulent flow

    NASA Technical Reports Server (NTRS)

    Snow, J. B.; Murphy, D. V.; Chang, R. K.

    1984-01-01

    Coherent Anti-stokes Raman Scattering (CARS) from the pure rotational Raman lines of N2 is employed to measure the instantaneous rotational temperature of N2 gas at room temperature and below with good spatial resolution. A broad-bandwidth dye laser is used to obtain the entire rotational spectrum from a signal laser pulse; the CARS signal is then dispersed by a spectrograph and recorded on an optical multichannel analyzer. A best-fit temperature is found in several seconds with the aid of a computer for each experimental spectrum by a least squares comparison with calculated spectra. The model used to calculate the theoretical spectra incorporates the temperature and pressure dependence of the pressure-broadened rotational Raman lines, includes the nonresonant background susceptibility, and assumes that the pump laser has a finite linewidth. Temperatures are fit to experimental spectra recorded over the temperature range of 135 to 296K, and over the pressure range of 0.13 to 15.3 atm. In addition to the spatially resolved single point work, we have used multipoint CARS to obtain information from many spatially resolved volume elements along a cylindrical line (0.1 x 0.1 x 2.0 mm). We also obtained qualitative information on the instantaneous species concentration and temperature at 20 spatially resolved volume elements (0.1 x 0.1 x 0.1 mm) along a line.

  1. An InGaAs detector based radiation thermometer and fixed-point blackbodies for temperature scale realization at NIM

    SciTech Connect

    Hao, X.; Yuan, Z.; Wang, J.; Lu, X.

    2013-09-11

    In this paper, we describe an InGaAs detector based radiation thermometer (IRT) and new design of fixed-point blackbodies, including Sn, Zn, Al and Cu, for the establishment of a temperature scale from 200 °C to 1085 °C at the National Institute of Metrology of China. The construction and calibration of the IRT with the four fixed-point blackbodies are described. Characteristics of the IRT, such as the size-of-source effect, the amplifier performance and its stability are determined. The design of the four fixed-points, with 10 mm diameter of aperture and 0.9999 emissivity, is described. The uncertainty of the scale realization is elaborated.

  2. An InGaAs detector based radiation thermometer and fixed-point blackbodies for temperature scale realization at NIM

    NASA Astrophysics Data System (ADS)

    Hao, X.; Yuan, Z.; Wang, J.; Lu, X.

    2013-09-01

    In this paper, we describe an InGaAs detector based radiation thermometer (IRT) and new design of fixed-point blackbodies, including Sn, Zn, Al and Cu, for the establishment of a temperature scale from 200 °C to 1085 °C at the National Institute of Metrology of China. The construction and calibration of the IRT with the four fixed-point blackbodies are described. Characteristics of the IRT, such as the size-of-source effect, the amplifier performance and its stability are determined. The design of the four fixed-points, with 10 mm diameter of aperture and 0.9999 emissivity, is described. The uncertainty of the scale realization is elaborated.

  3. Nucleate pool boiling heat transfer in aqueous surfactant solutions

    NASA Astrophysics Data System (ADS)

    Wasekar, Vivek Mahadeorao

    Saturated, nucleate pool boiling in aqueous surfactant solutions is investigated experimentally. Also, the role of Marangoni convection, driven both by temperature and surfactant concentration gradients at the vapor-liquid interface of a nucleating bubble is computationally explored. Experimental measurements of dynamic and equilibrium sigma using the maximum bubble pressure method indicate dynamic sigma to be higher than the corresponding equilibrium value, both at room and elevated temperatures. Also, nonionic surfactants (Triton X-100, Triton X-305) show larger sigma depression than anionic surfactants (SDS, SLES), and a normalized representation of their dynamic adsorption isotherms is shown to be helpful in generalizing the surfactant effectiveness to reduce surface tension. The dynamic sigma has a primary role in the modification of bubble dynamics and associated heat transfer, and is dictated by the adsorption kinetics of the surfactant molecules at boiling temperatures. In general, an enhancement in heat transfer is observed, which is characterized by an early incipience and an optimum boiling performance at or around the critical micelle concentration of the surfactant. The optimum performances, typically in the fully developed boiling regime ( q''w > 100 kW/m2), show a reverse trend with respect to surfactant molecular weights M, i.e., higher molecular weight additives promote lower enhancement. Normalized boiling performance using the respective solution's dynamic sigma correlates heat transfer coefficient by M-0.5 for anionics and M 0 for nonionics. This has been shown to be brought about by the surfactant concentration and its interfacial activity in a concentration sublayer around the growing vapor bubble, which governs the bubble growth behavior through the mechanism of dynamic sigma. The ionic nature of the surfactant influences the thickness and molecular makeup of the enveloping sublayer, thereby affecting the bubble dynamics and boiling heat transfer. Finally, the computational modeling of Marangoni convection for boiling nuclei at short time transients shows similarity solutions for pure water, and reduced convection with a peak in circulation strength in the presence of surfactants. The peaking corresponds to the characteristic surfactant adsorption time, which has been shown to depend solely upon the surfactant bulk concentration. For the absence of surfactant surface convection, an enhancement in Marangoni convection is observed. Furthermore, for the investigated range of parameters and time scales, the surfactant adsorption at the interface is not characterized by the presence of a stagnant cap. (Abstract shortened by UMI.)

  4. The Physics of Boiling at Burnout

    NASA Technical Reports Server (NTRS)

    Theofanous, T. G.; Tu, J. P.; Dinh, T. N.; Salmassi, T.; Dinh, A. T.; Gasljevic, K.

    2000-01-01

    The basic elements of a new experimental approach for the investigation of burnout in pool boiling are presented. The approach consists of the combined use of ultrathin (nano-scale) heaters and high speed infrared imaging of the heater temperature pattern as a whole, in conjunction with highly detailed control and characterization of heater morphology at the nano and micron scales. It is shown that the burnout phenomenon can be resolved in both space and time. Ultrathin heaters capable of dissipating power levels, at steady-state, of over 1 MW/square m are demonstrated. A separation of scales is identified and it is used to transfer the focus of attention from the complexity of the two-phase mixing layer in the vicinity of the heater to a micron-scaled microlayer and nucleation and associated film-disruption processes within it.

  5. Subcooled flow film boiling across a horizontal cylinder. Part I. Analytical model

    SciTech Connect

    Chou, X.S.; Witte, L.C. )

    1995-02-01

    An analytical model of stable subcooled flow film boiling on the front of a horizontal cylinder and a model for the wake region downstream of the flow separation points were developed. The flow and temperature fields upstream of the separation points were represented by a 'local-similarity' solution obtained through a rigorous mathematical transformation. The transformed governing equations were solved numerically using a finite-difference scheme. Numerical solutions for the vapor layer thickness, the velocity, and the temperature fields were obtained for both the liquid and vapor layers. The results showed that the liquid boundary layer was thicker than the vapor film. Increases in the liquid subcooling and in the free-stream velocity decreased the vapor layer thickness. The influence of convection in the vapor layer is small yielding a near-linear temperature distribution. A two-dimensional vapor wake model was developed based on mass and energy balances. Numerical solutions, including the vapor layer thickness and the temperature field of the front part and the wake part, were matched at the separation points. The results showed that increases in the liquid subcooling decreased the vapor layer thickness. Heat transfer in the wake region can amount up to 20 percent of the heat transfer in the forward region and should not be neglected especially at high subcooling. 19 refs., 8 figs.

  6. Temperature effect on the build-up of exponentially growing polyelectrolyte multilayers. An exponential-to-linear transition point.

    PubMed

    Vikulina, Anna S; Anissimov, Yuri G; Singh, Prateek; Prokopović, Vladimir Z; Uhlig, Katja; Jaeger, Magnus S; von Klitzing, Regine; Duschl, Claus; Volodkin, Dmitry

    2016-03-01

    In this study, the effect of temperature on the build-up of exponentially growing polyelectrolyte multilayer films was investigated. It aims at understanding the multilayer growth mechanism as crucially important for the fabrication of tailor-made multilayer films. Model poly(l-lysine)/hyaluronic acid (PLL/HA) multilayers were assembled in the temperature range of 25-85 °C by layer-by-layer deposition using a dipping method. The film growth switches from the exponential to the linear regime at the transition point as a result of limited polymer diffusion into the film. With the increase of the build-up temperature the film growth rate is enhanced in both regimes; the position of the transition point shifts to a higher number of deposition steps confirming the diffusion-mediated growth mechanism. Not only the faster polymer diffusion into the film but also more porous/permeable film structure are responsible for faster film growth at higher preparation temperature. The latter mechanism is assumed from analysis of the film growth rate upon switching of the preparation temperature during the film growth. Interestingly, the as-prepared films are equilibrated and remain intact (no swelling or shrinking) during temperature variation in the range of 25-45 °C. The average activation energy for complexation between PLL and HA in the multilayers calculated from the Arrhenius plot has been found to be about 0.3 kJ mol(-1) for monomers of PLL. Finally, the following processes known to be dependent on temperature are discussed with respect to the multilayer growth: (i) polymer diffusion, (ii) polymer conformational changes, and (iii) inter-polymer interactions. PMID:26911320

  7. Sensing Atomic Motion from the Zero Point to Room Temperature with Ultrafast Atom Interferometry

    NASA Astrophysics Data System (ADS)

    Johnson, K. G.; Neyenhuis, B.; Mizrahi, J.; Wong-Campos, J. D.; Monroe, C.

    2015-11-01

    We sense the motion of a trapped atomic ion using a sequence of state-dependent ultrafast momentum kicks. We use this atom interferometer to characterize a nearly pure quantum state with n =1 phonon and accurately measure thermal states ranging from near the zero-point energy to n ¯˜104, with the possibility of extending at least 100 times higher in energy. The complete energy range of this method spans from the ground state to far outside of the Lamb-Dicke regime, where atomic motion is greater than the optical wavelength. Apart from thermometry, these interferometric techniques are useful for characterizing ultrafast entangling gates between multiple trapped ions.

  8. Wireless SAW sensor for high temperature applications: material point of view

    NASA Astrophysics Data System (ADS)

    Elmazria, Omar; Aubert, Thierry

    2011-06-01

    In addition to being small, simple and robust, surface acoustic wave (SAW) devices have the advantage of being passive (batteryless), remotely requestable (wireless) and inexpensive if fabricated on a large scale. The use of SAW devices as passive and wireless sensors allows them to operate in extreme conditions such as those with high levels of radiation, high temperatures up to 1000C, or electromagnetic interference, in which no other wireless sensor can operate. This is obviously conditioned by the fact that the materials constituting the device can withstand these harsh conditions. General principle of the SAW sensor in wireless configuration is developed and a review of recent works concerning the field of high temperature applications is presented with a specific attention given to the characterization of materials constituting the SAW device: piezoelectric substrate and metallic electrodes.

  9. An optical fibre sensor for combined point pressure measurement and spatially resolved temperature measurement

    NASA Astrophysics Data System (ADS)

    Duraibabu, DineshBabu; Poeggel, Sven; Lehzen, Kevin; Dooly, Gerard; Lewis, Elfed; Leen, Gabriel; Newe, Thomas

    2015-09-01

    In this paper, two optical fibre sensors are presented: 1) based on extrinsic Fabry-Perot Interferometer (EFPI) with Fibre Bragg Grating array and 2) and EFPI sensor with a chirped Fibre Bragg grating (CFBG). The CFBG with EFPI sensor fabrication technique is described and temperature response of both sensors is presented. Such sensors have many potential applications including applications in the aerospace industry and medical industry (e.g. radio frequency thermal ablation of tumors).

  10. Investigation of the effects of pressure gradient, temperature and wall temperature ratio on the stagnation point heat transfer for circular cylinders and gas turbine vanes

    NASA Technical Reports Server (NTRS)

    Nagamatsu, H. T.; Duffy, R. E.

    1984-01-01

    Low and high pressure shock tubes were designed and constructed for the purpose of obtaining heat transfer data over a temperature range of 390 to 2500 K, pressures of 0.3 to 42 atm, and Mach numbers of 0.15 to 1.5 with and without pressure gradient. A square test section with adjustable top and bottom walls was constructed to produce the favorable and adverse pressure gradient over the flat plate with heat gages. A water cooled gas turbine nozzle cascade which is attached to the high pressure shock tube was obtained to measuse the heat flux over pressure and suction surfaces. Thin-film platinum heat gages with a response time of a few microseconds were developed and used to measure the heat flux for laminar, transition, and turbulent boundary layers. The laminar boundary heat flux on the shock tube wall agreed with Mirel's flat plate theory. Stagnation point heat transfer for circular cylinders at low temperature compared with the theoretical prediction, but for a gas temperature of 922 K the heat fluxes were higher than the predicted values. Preliminary flat plate heat transfer data were measured for laminar, transition, and turbulent boundary layers with and without pressure gradients for free-stream temperatures of 350 to 2575 K and flow Mach numbers of 0.11 to 1.9. The experimental heat flux data were correlated with the laminar and turbulent theories and the agreement was good at low temperatures which was not the case for higher temperatures.

  11. A review on saturated boiling of liquids on tube bundles

    NASA Astrophysics Data System (ADS)

    Swain, Abhilas; Das, Mihir Kumar

    2014-05-01

    A review of recent investigation on boiling of saturated liquids over plain and enhanced tube bundles has been carried out taking the earlier review works as reference point. The experimental observations of various geometry and performance parameters studied by researchers are analyzed keeping current demand of industries in design and development of compact, efficient heat exchanging devices. The study shows that tube spacing plays an important role in determination of compactness of the heat exchanger.

  12. Point Defect Properties of Cd(Zn)Te and TlBr for Room-Temperature Gamma Radiation Detectors

    NASA Astrophysics Data System (ADS)

    Lordi, Vincenzo

    2013-03-01

    The effects of various crystal defects in CdTe, Cd1-xZnxTe (CZT), and TlBr are critical for their performance as room-temperature gamma radiation detectors. We use predictive first principles theoretical methods to provide fundamental, atomic scale understanding of the defect properties of these materials to enable design of optimal growth and processing conditions, such as doping, annealing, and stoichiometry. Several recent cases will be reviewed, including (i) accurate calculations of the thermodynamic and electronic properties of native point defects and point defect complexes in CdTe and CZT; (ii) the effects of Zn alloying on the native point defect properties of CZT; (iii) point defect diffusion and binding related to Te clustering in Cd(Zn)Te; (iv) the profound effect of native point defects--principally vacancies--on the intrinsic material properties of TlBr, particularly electronic and ionic conductivity; (v) tailored doping of TlBr to independently control the electronic and ionic conductivity; and (vi) the effects of metal impurities on the electronic properties and device performance of TlBr detectors. Prepared by LLNL under Contract DE-AC52-07NA27344 with support from the National Nuclear Security Administration Office of Nonproliferation and Verification Research and Development NA-22.

  13. Modeling acid-gas generation from boiling chloride brines

    PubMed Central

    2009-01-01

    Background This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Results Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150°C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. Conclusion The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150°C). PMID:19917082

  14. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

  15. Nucleate pool boiling in the long duration low gravity environment of the Space Shuttle

    NASA Technical Reports Server (NTRS)

    Hasan, M. M.; Lin, C. S.; Knoll, R. H.; Bentz, M. D.; Meserole, J. S.

    1993-01-01

    The results are presented of an experimental study of nucleate pool boiling performed in the low gravity environment of the space shuttle. Photographic observations of pool boiling in Freon 113 were obtained during the 'Tank Pressure Control Experiment,' flown on the Space Transportation System, STS-43 in August 1991. Nucleate boiling data from large (relative to bubble size) flat heating surfaces (0.1046 by 0.0742 m) was obtained at very low heat fluxes (0.22 to 1.19 kW/sq m). The system pressure and the bulk liquid subcooling varied in the range of 40 to 60 kPa and 3 to 5 C respectively. Thirty-eight boiling tests, each of 10-min duration for a given heat flux, were conducted. Measurements included the heater power, heater surface temperature, the liquid temperature and the system pressure as functions of heating time. Video data of the first 2 min of heating was recorded for each test. In some tests the video clearly shows the inception of boiling and the growth and departure of bubbles from the surface during the first 2 min of heating. In the absence of video data, the heater temperature variation during heating shows the inception of boiling and stable nucleate boiling. During the stable nucleate boiling, the wall superheat varied between 2.8 to 3.8 C for heat fluxes in the range of 0.95 to 1.19 kW/sq m. The wall superheat at the inception of boiling varied between 2 to 13 C.

  16. Acoustic noise of a boiling liquid

    SciTech Connect

    Nesis, Y.I.

    1990-01-01

    This paper presents ideas on the mechanism of the emission of noise for different regimes of convective liquid boiling. Based on the analysis of experimental data, fundamental differences in the amplitude-frequency spectra of the acoustic noise accompanying these regimes are revealed as well as the nature of elementary sound emitters in a boiling liquid. Methods are indicated which allow one in principle to diagnose the regime of boiling in large reservoirs or cylindrical channels.

  17. Reconstruction of the pressure pattern over Japan using two-point pressure/temperature datasets

    NASA Astrophysics Data System (ADS)

    Zaiki, M.; Tsukaha, T.; Konnen, G.; Mikami, T.

    2007-12-01

    The temperature and pressure differences between Tokyo and Nagasaki were applied for reconstruction of the past climate conditions. January and July in each year since the 1820's were divided into several types characterized by sea level pressure patterns. The findings indicated that the warming after 1900 (after the decline of the so-called Little Ice Age) and again after 1960 can at least partly be attributed to a increase in frequency of warm circulation types at the cost of cold types. The different nature of the shift in circulation types around 1900 and 1960 suggest that the mechanisms behind these warmings are of a different nature.

  18. Evaluation of the Long-Term Stability and Temperature Coefficient of Dew-Point Hygrometers

    NASA Astrophysics Data System (ADS)

    Benyon, R.; Vicente, T.; Hernández, P.; De Rivas, L.; Conde, F.

    2012-09-01

    The continuous quest for improved specifications of optical dew-point hygrometers has raised customer expectations on the performance of these devices. In the absence of a long calibration history, users with a limited prior experience in the measurement of humidity, place reliance on manufacturer specifications to estimate long-term stability. While this might be reasonable in the case of measurement of electrical quantities, in humidity it can lead to optimistic estimations of uncertainty. This article reports a study of the long-term stability of some hygrometers and the analysis of their performance as monitored through regular calibration. The results of the investigations provide some typical, realistic uncertainties associated with the long-term stability of instruments used in calibration and testing laboratories. Together, these uncertainties can help in establishing initial contributions in uncertainty budgets, as well as in setting the minimum calibration requirements, based on the evaluation of dominant influence quantities.

  19. Sensing Atomic Motion from the Zero Point to Room Temperature with Ultrafast Atom Interferometry.

    PubMed

    Johnson, K G; Neyenhuis, B; Mizrahi, J; Wong-Campos, J D; Monroe, C

    2015-11-20

    We sense the motion of a trapped atomic ion using a sequence of state-dependent ultrafast momentum kicks. We use this atom interferometer to characterize a nearly pure quantum state with n=1 phonon and accurately measure thermal states ranging from near the zero-point energy to n[over ¯]~10^{4}, with the possibility of extending at least 100 times higher in energy. The complete energy range of this method spans from the ground state to far outside of the Lamb-Dicke regime, where atomic motion is greater than the optical wavelength. Apart from thermometry, these interferometric techniques are useful for characterizing ultrafast entangling gates between multiple trapped ions. PMID:26636850

  20. Experimental demonstration of contaminant removal from fractured rock by boiling.

    PubMed

    Chen, Fei; Liu, Xiaoling; Falta, Ronald W; Murdoch, Lawrence C

    2010-08-15

    This study was conducted to experimentally demonstrate removal of a chlorinated volatile organic compound from fractured rock by boiling. A Berea sandstone core was contaminated by injecting water containing dissolved 1,2-DCA (253 mg/L) and sodium bromide (144 mg/L). During heating, the core was sealed except for one end, which was open to the atmosphere to simulate an open fracture. A temperature gradient toward the outlet was observed when boiling occurred in the core. This indicates that steam was generated and a pressure gradient developed toward the outlet, pushing steam vapor and liquid water toward the outlet. As boiling occurred, the concentration of 1,2-DCA in the condensed effluent peaked up to 6.1 times higher than the injected concentration. When 38% of the pore volume of condensate was produced, essentially 100% of the 1,2-DCA was recovered. Nonvolatile bromide concentration in the condensate was used as an indicator of the produced steam quality (vapor mass fraction) because it can only be removed as a solute, and not as a vapor. A higher produced steam quality corresponds to more concentrated 1,2-DCA removal from the core, demonstrating that the chlorinated volatile compound is primarily removed by partitioning into vapor phase flow. This study has experimentally demonstrated that boiling is an effective mechanism for CVOC removal from the rock matrix. PMID:20666474

  1. A study of forced convection boiling under reduced gravity

    NASA Technical Reports Server (NTRS)

    Merte, Herman, Jr.

    1992-01-01

    This report presents the results of activities conducted over the period 1/2/85-12/31/90, in which the study of forced convection boiling under reduced gravity was initiated. The study seeks to improve the understanding of the basic processes that constitute forced convection boiling by removing the buoyancy effects which may mask other phenomena. Specific objectives may also be expressed in terms of the following questions: (1) what effects, if any, will the removal of body forces to the lowest possible levels have on the forced convection boiling heat transfer processes in well-defined and meaningful circumstances? (this includes those effects and processes associated with the nucleation or onset of boiling during the transient increase in heater surface temperature, as well as the heat transfer and vapor bubble behaviors with established or steady-state conditions); and (2) if such effects are present, what are the boundaries of the relevant parameters such as heat flux, heater surface superheat, fluid velocity, bulk subcooling, and geometric/orientation relationships within which such effects will be produced?

  2. Heat Transfer Performances of Pool Boiling on Metal-Graphite Composite Surfaces

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Yang, Wen-Jei

    2000-01-01

    Nucleate boiling, especially near the critical heat flux (CHF), can provide excellent economy along with high efficiency of heat transfer. However, the performance of nucleate boiling may deteriorate in a reduced gravity environment and the nucleate boiling usually has a potentially dangerous characteristic in CHF regime. That is, any slight overload can result in burnout of the boiling surface because the heat transfer will suddenly move into the film-boiling regime. Therefore, enhancement of nucleate boiling heat transfer becomes more important in reduced gravity environments. Enhancing nucleate boiling and critical heat flux can be reached using micro-configured metal-graphite composites as the boiling surface. Thermocapillary force induced by temperature difference between the graphite-fiber tips and the metal matrix, which is independent of gravity, will play an important role in bubble detachment. Thus boiling heat transfer performance does not deteriorate in a reduced-gravity environment. Based on the existing experimental data, and a two-tier theoretical model, correlation formulas are derived for nucleate boiling on the copper-graphite and aluminum-graphite composite surfaces, in both the isolated and coalesced bubble regimes. Experimental studies were performed on nucleate pool boiling of pentane on cooper-graphite (Cu-Gr) and aluminum-graphite (Al-Gr) composite surfaces with various fiber volume concentrations for heat fluxes up to 35 W per square centimeter. It is revealed that a significant enhancement in boiling heat transfer performance on the composite surfaces is achieved, due to the presence of micro-graphite fibers embedded in the matrix. The onset of nucleate boiling (the isolated bubble regime) occurs at wall superheat of about 10 C for the Cu-Gr surface and 15 C for the Al-Gr surface, much lower than their respective pure metal surfaces. Transition from an isolated bubble regime to a coalesced bubble regime in boiling occurs at a superheat of about 14 C on Cu-Gr surface and 19 C on Al-Gr surface.

  3. Boiling significantly promotes photodegradation of perfluorooctane sulfonate.

    PubMed

    Lyu, Xian-Jin; Li, Wen-Wei; Lam, Paul K S; Yu, Han-Qing

    2015-11-01

    The application of photochemical processes for perfluorooctane sulfonate (PFOS) degradation has been limited by a low treatment efficiency. This study reports a significant acceleration of PFOS photodegradation under boiling condition compared with the non-boiling control. The PFOS decomposition rate increased with the increasing boiling intensity, but declined at a higher hydronium level or under oxygenation. These results suggest that the boiling state of solution resulted in higher effective concentrations of reactants at the gas-liquid interface and enhanced the interfacial mass transfer, thereby accelerating the PFOS decomposition. This study broadens our knowledge of PFOS photodegradation process and may have implications for development of efficient photodegradation technologies. PMID:26117498

  4. Increasing Boiling Heat Transfer using Low Conductivity Materials

    PubMed Central

    Mahamudur Rahman, Md; Pollack, Jordan; McCarthy, Matthew

    2015-01-01

    We report the counterintuitive mechanism of increasing boiling heat transfer by incorporating low-conductivity materials at the interface between the surface and fluid. By embedding an array of non-conductive lines into a high-conductivity substrate, in-plane variations in the local surface temperature are created. During boiling the surface temperature varies spatially across the substrate, alternating between high and low values, and promotes the organization of distinct liquid and vapor flows. By systematically tuning the peak-to-peak wavelength of this spatial temperature variation, a resonance-like effect is seen at a value equal to the capillary length of the fluid. Replacing ~18% of the surface with a non-conductive epoxy results in a greater than 5x increase in heat transfer rate at a given superheat temperature. This drastic and counterintuitive increase is shown to be due to optimized bubble dynamics, where ordered pathways allow for efficient removal of vapor and the return of replenishing liquid. The use of engineered thermal gradients represents a potentially disruptive approach to create high-efficiency and high-heat-flux boiling surfaces which are naturally insensitive to fouling and degradation as compared to other approaches. PMID:26281890

  5. Increasing Boiling Heat Transfer using Low Conductivity Materials

    NASA Astrophysics Data System (ADS)

    Mahamudur Rahman, Md; Pollack, Jordan; McCarthy, Matthew

    2015-08-01

    We report the counterintuitive mechanism of increasing boiling heat transfer by incorporating low-conductivity materials at the interface between the surface and fluid. By embedding an array of non-conductive lines into a high-conductivity substrate, in-plane variations in the local surface temperature are created. During boiling the surface temperature varies spatially across the substrate, alternating between high and low values, and promotes the organization of distinct liquid and vapor flows. By systematically tuning the peak-to-peak wavelength of this spatial temperature variation, a resonance-like effect is seen at a value equal to the capillary length of the fluid. Replacing ~18% of the surface with a non-conductive epoxy results in a greater than 5x increase in heat transfer rate at a given superheat temperature. This drastic and counterintuitive increase is shown to be due to optimized bubble dynamics, where ordered pathways allow for efficient removal of vapor and the return of replenishing liquid. The use of engineered thermal gradients represents a potentially disruptive approach to create high-efficiency and high-heat-flux boiling surfaces which are naturally insensitive to fouling and degradation as compared to other approaches.

  6. CHIMNEY FOR BOILING WATER REACTOR

    DOEpatents

    Petrick, M.

    1961-08-01

    A boiling-water reactor is described which has vertical fuel-containing channels for forming steam from water. Risers above the channels increase the head of water radially outward, whereby water is moved upward through the channels with greater force. The risers are concentric and the radial width of the space between them is somewhat small. There is a relatively low rate of flow of water up through the radially outer fuel-containing channels, with which the space between the risers is in communication. (AE C)

  7. Boils

    MedlinePlus

    ... Online Store Welcome Calendar of Events Find a Dermatology DO Osteopathic Medicine Disease Database Contributors Doctor Derm ... of Trustees Contact Us Ethics Foundation for Osteopathic Dermatology What is the FOD? Governance By-Laws Committees ...

  8. New flow boiling heat transfer model for hydrocarbons evaporating inside horizontal tubes

    SciTech Connect

    Chen, G. F.; Gong, M. Q.; Wu, J. F.; Zou, X.; Wang, S.

    2014-01-29

    Hydrocarbons have high thermodynamic performances, belong to the group of natural refrigerants, and they are the main components in mixture Joule-Thomson low temperature refrigerators (MJTR). New evaluations of nucleate boiling contribution and nucleate boiling suppression factor in flow boiling heat transfer have been proposed for hydrocarbons. A forced convection heat transfer enhancement factor correlation incorporating liquid velocity has also been proposed. In addition, the comparisons of the new model and other classic models were made to evaluate its accuracy in heat transfer prediction.

  9. Length Scale and Gravity Effects on Microgravity Boiling Heat Transfer

    NASA Technical Reports Server (NTRS)

    Kim, Jungho; McQuillen, John; Balombin, Joe

    2002-01-01

    Boiling is a complex phenomenon where hydrodynamics, heat transfer, mass transfer, and interfacial phenomena are tightly interwoven. An understanding of boiling and critical heat flux in microgravity environments is of importance to space based hardware and processes such as heat exchange, cryogenic fuel storage and transportation, electronic cooling, and material processing due to the large amounts of heat that can be removed with relatively little increase in temperature. Although research in this area has been performed in the past four decades, the mechanisms by which heat is removed from surfaces in microgravity are still unclear. In earth gravity, buoyancy is an important parameter that affects boiling heat transfer through the rate at which bubbles are removed from the surface. A simple model describing the bubble departure size based on a quasistatic force balance between buoyancy and surface tension is given by the Fritz [I] relation: Bo(exp 1/2) = 0.0208 theta where Bo is the ratio between buoyancy and surface tension forces. For small, rapidly growing bubbles, inertia associated with the induced liquid motion can also cause bubble departure. In microgravity, the magnitude of effects related to natural convection and buoyancy are small and physical mechanisms normally masked by natural convection in earth gravity such as Marangoni convection can substantially influence the boiling and vapor bubble dynamics. CHF (critical heat transfer) is also substantially affected by microgravity. In 1 g environments, Bo has been used as a correlating parameter for CHF. Zuber's CHF model for an infinite horizontal surface assumes that vapor columns formed by the merger of bubbles become unstable due to a Helmholtz instability blocking the supply of liquid to the surface. The jets are spaced lambda(sub D) apart, where lambda(sub D) = 2pi square root of 3[(sigma)/(g(rho(sub l) - rho(sub v)](exp 1/2) = 2pi square root of 3 L Bo(exp -1/2) = square root of 3 lambda(sub c) and is the wavelength that amplifies most rapidly. The critical wavelength, lambda(sub c), is the wavelength below which a vapor layer underneath a liquid layer is stable. For heaters with Bo smaller than about 3 (heaters smaller than lambda(sub D)), the above model is not applicable, and surface tension effects dominate. Bubble coalescence is thought to be the mechanism for CHF under these conditions. Small Bo can result by decreasing the size of a heater in earth gravity, or by operating a large heater in a lower gravity environment. In the microgravity of space, even large heaters can have low Bo, and models based on Helmholtz instability should not be applicable. The macrolayer model of Haramura and Katto is dimensionally equivalent to Zuber's model and has the same dependence on gravity, so it should not be applicable as well. The goal of this work is to determine how boiling heat transfer mechanisms in a low-g environment are altered from those at higher gravity levels. Boiling data using a microheater array was obtained under gravity environments ranging from 1.8 g to 0.02 g with heater sizes ranging from 2.7 mm to 1 mm. The boiling behavior for 2.7 mm at 0.02 g looked quite similar to boiling on the 1 mm heater at 1 g-the formation of a large primary bubble surrounded by smaller satellite bubbles was observed under both conditions. The similarity suggests that for heaters smaller than some fraction of I(sub c), coalescence and surface tension dominate boiling heat transfer. It also suggests that microgravity boiling can be studied by studying boiling on very small heaters.

  10. Handheld low-temperature plasma probe for portable "point-and-shoot" ambient ionization mass spectrometry.

    PubMed

    Wiley, Joshua S; Shelley, Jacob T; Cooks, R Graham

    2013-07-16

    We describe a handheld, wireless low-temperature plasma (LTP) ambient ionization source and its performance on a benchtop and a miniature mass spectrometer. The source, which is inexpensive to build and operate, is battery-powered and utilizes miniature helium cylinders or air as the discharge gas. Comparison of a conventional, large-scale LTP source against the handheld LTP source, which uses less helium and power than the large-scale version, revealed that the handheld source had similar or slightly better analytical performance. Another advantage of the handheld LTP source is the ability to quickly interrogate a gaseous, liquid, or solid sample without requiring any setup time. A small, 7.4-V Li-polymer battery is able to sustain plasma for 2 h continuously, while the miniature helium cylinder supplies gas flow for approximately 8 continuous hours. Long-distance ion transfer was achieved for distances up to 1 m. PMID:23721516

  11. STUDY OF THE CRITICAL POINT IN LATTICE QCD AT HIGH TEMPERATURE AND DENSITY.

    SciTech Connect

    EJIRI,S.

    2007-07-30

    We propose a method to probe the nature of phase transitions in lattice QCD at finite temperature and density, which is based on the investigation of an effective potential as a function of the average plaquette. We analyze data obtained in a simulation of two-flavor QCD using p4-improved staggered quarks with bare quark mass m/T = 0.4, and find that a first order phase transition line appears in the high density regime for {mu}{sub q}/T {approx}> 2.5. The effective potential as a function of the quark number density is also studied. We calculate the chemical potential as a function of the density from the canonical partition function and discuss the existence of the first order phase transition line.

  12. Lattice Boltzmann modeling of boiling heat transfer: The boiling curve and the effects of wettability

    DOE PAGESBeta

    Li, Q.; Kang, Q. J.; Francois, M. M.; He, Y. L.; Luo, K. H.

    2015-03-03

    A hybrid thermal lattice Boltzmann (LB) model is presented to simulate thermal multiphase flows with phase change based on an improved pseudopotential LB approach (Li et al., 2013). The present model does not suffer from the spurious term caused by the forcing-term effect, which was encountered in some previous thermal LB models for liquid–vapor phase change. Using the model, the liquid–vapor boiling process is simulated. The boiling curve together with the three boiling stages (nucleate boiling, transition boiling, and film boiling) is numerically reproduced in the LB community for the first time. The numerical results show that the basic featuresmore » and the fundamental characteristics of boiling heat transfer are well captured, such as the severe fluctuation of transient heat flux in the transition boiling and the feature that the maximum heat transfer coefficient lies at a lower wall superheat than that of the maximum heat flux. Moreover, the effects of the heating surface wettability on boiling heat transfer are investigated. It is found that an increase in contact angle promotes the onset of boiling but reduces the critical heat flux, and makes the boiling process enter into the film boiling regime at a lower wall superheat, which is consistent with the findings from experimental studies.« less

  13. Lattice Boltzmann modeling of boiling heat transfer: The boiling curve and the effects of wettability

    SciTech Connect

    Li, Q.; Kang, Q. J.; Francois, M. M.; He, Y. L.; Luo, K. H.

    2015-03-03

    A hybrid thermal lattice Boltzmann (LB) model is presented to simulate thermal multiphase flows with phase change based on an improved pseudopotential LB approach (Li et al., 2013). The present model does not suffer from the spurious term caused by the forcing-term effect, which was encountered in some previous thermal LB models for liquid–vapor phase change. Using the model, the liquid–vapor boiling process is simulated. The boiling curve together with the three boiling stages (nucleate boiling, transition boiling, and film boiling) is numerically reproduced in the LB community for the first time. The numerical results show that the basic features and the fundamental characteristics of boiling heat transfer are well captured, such as the severe fluctuation of transient heat flux in the transition boiling and the feature that the maximum heat transfer coefficient lies at a lower wall superheat than that of the maximum heat flux. Moreover, the effects of the heating surface wettability on boiling heat transfer are investigated. It is found that an increase in contact angle promotes the onset of boiling but reduces the critical heat flux, and makes the boiling process enter into the film boiling regime at a lower wall superheat, which is consistent with the findings from experimental studies.

  14. Investigations of Mechanisms Associated with Nucleate Boiling Under Microgravity Conditions

    NASA Technical Reports Server (NTRS)

    Dhir, Vijay K.; Hasan, M.; Chao, David (Technical Monitor)

    2003-01-01

    In this work a building block type of approach is used so that a basic understanding of the processes that contribute to nucleate boiling heat fluxes under microgravity conditions can be developed. This understanding will lead to development of a mechanistic model for nucleate boiling heat transfer which could eventually be used as a design tool in space applications. Task Description Task 1: Fabrication of the Experimental Setup. Under this task, the test section and liquid holding and viewing chambers will be fabricated. Artificial cylinder cavities will be formed on silicon wafers. A single cavity and two or four cavities, with a prescribed spacing and size, will be formed. The desired nucleation wall superheat will be used to determine the size of the mouth of the cavities. Task 2: Experiments. The basic experiments for flow and temperature field around single and multiple (2 or 4 separated or merged bubbles growing on downward facing or inclined surfaces) will be carried out under normal gravity conditions. The experiments will be conducted at one atmosphere pressure, but liquid subcooling will be varied from 0 to 30C. Water and PF-5050 will be used as test liquids. Task 3: Analytical/Numerical Models. In this task, transient temperature and flow field in vapor and liquid will be determined during growth of a single bubble. Analysis will include the evolution of the vapor-liquid interface and development of microlayer underneath the bubbles. For merged bubbles, detailed calculations of flow and temperature field will be carried out for transient shapes of vapor stems supporting a large bubble and the corresponding evaporation rate. Flow and temperature field for a bubble sliding along a heated wall will also be determined. Microgravity conditions will be simulated and a framework of a numerical tool for prediction of nucleate boiling heat fluxes under microgravity conditions will be developed. Task 4: Experiments in a KC-135. To understand bubble growth and detachment behavior of single or large merged bubbles, boiling experiments will be conducted under low gravity (10-2 g) conditions of the aircraft. In these experiments, 'designed' surfaces will be used. Visual observations and heat transfer data will be taken, but holography will not be used. The apparatus used for laboratory experiments will also be employed for experiments in the aircraft. Task 5: Experiments in the Space Shuttle. Effort will be devoted for defining a boiling experiment to be conducted on a 'designed' surface. The experiment will provide microgravity data on bubble growth and departure. These data are needed for development of a credible model for nucleate boiling heat fluxes under microgravity conditions. The heat transfer data will also be obtained and will be used to validate the models.

  15. Numerical analysis of contaminant removal from fractured rock during boiling.

    PubMed

    Chen, Fei; Falta, Ronald W; Murdoch, Lawrence C

    2012-06-01

    A multiphase heat transfer numerical model is used to simulate a laboratory experiment of contaminant removal at boiling temperatures from a rock core representing the matrix adjacent to a fracture. The simulated temperature, condensate production, contaminant and bromide concentrations are similar to experimental data. A key observation from the experiment and simulation is that boiling out approximately 1/2 pore volume (50 mL) of water results in the removal of essentially 100% of the dissolved volatile contaminant (1,2-DCA). A field-scale simulation using the multiple interacting continua (MINC) discretization approach is conducted to illustrate possible applications of thermal remediation of fractured geologic media, assuming uniform heating. The results show that after 28% of the pore water (including both steam vapor and liquid water) was extracted, and essentially all the 1,2-DCA mass (more than 99%) was removed. PMID:22579665

  16. Numerical analysis of contaminant removal from fractured rock during boiling

    NASA Astrophysics Data System (ADS)

    Chen, Fei; Falta, Ronald W.; Murdoch, Lawrence C.

    2012-06-01

    A multiphase heat transfer numerical model is used to simulate a laboratory experiment of contaminant removal at boiling temperatures from a rock core representing the matrix adjacent to a fracture. The simulated temperature, condensate production, contaminant and bromide concentrations are similar to experimental data. A key observation from the experiment and simulation is that boiling out approximately 1/2 pore volume (50 mL) of water results in the removal of essentially 100% of the dissolved volatile contaminant (1,2-DCA). A field-scale simulation using the multiple interacting continua (MINC) discretization approach is conducted to illustrate possible applications of thermal remediation of fractured geologic media, assuming uniform heating. The results show that after 28% of the pore water (including both steam vapor and liquid water) was extracted, and essentially all the 1,2-DCA mass (more than 99%) was removed.

  17. Predicting critical temperatures of ionic and non-ionic fluids from thermophysical data obtained near the melting point.

    PubMed

    Weiss, Volker C

    2015-10-14

    In the correlation and prediction of thermophysical data of fluids based on a corresponding-states approach, the critical temperature Tc plays a central role. For some fluids, in particular ionic ones, however, the critical region is difficult or even impossible to access experimentally. For molten salts, Tc is on the order of 3000 K, which makes accurate measurements a challenging task. Room temperature ionic liquids (RTILs) decompose thermally between 400 K and 600 K due to their organic constituents; this range of temperatures is hundreds of degrees below recent estimates of their Tc. In both cases, reliable methods to deduce Tc based on extrapolations of experimental data recorded at much lower temperatures near the triple or melting points are needed and useful because the critical point influences the fluid's behavior in the entire liquid region. Here, we propose to employ the scaling approach leading to universal fluid behavior [Román et al., J. Chem. Phys. 123, 124512 (2005)] to derive a very simple expression that allows one to estimate Tc from the density of the liquid, the surface tension, or the enthalpy of vaporization measured in a very narrow range of low temperatures. We demonstrate the validity of the approach for simple and polar neutral fluids, for which Tc is known, and then use the methodology to obtain estimates of Tc for ionic fluids. When comparing these estimates to those reported in the literature, good agreement is found for RTILs, whereas the ones for the molten salts NaCl and KCl are lower than previous estimates by 10%. The coexistence curve for ionic fluids is found to be more adequately described by an effective exponent of βeff = 0.5 than by βeff = 0.33. PMID:26472385

  18. Predicting critical temperatures of ionic and non-ionic fluids from thermophysical data obtained near the melting point

    NASA Astrophysics Data System (ADS)

    Weiss, Volker C.

    2015-10-01

    In the correlation and prediction of thermophysical data of fluids based on a corresponding-states approach, the critical temperature Tc plays a central role. For some fluids, in particular ionic ones, however, the critical region is difficult or even impossible to access experimentally. For molten salts, Tc is on the order of 3000 K, which makes accurate measurements a challenging task. Room temperature ionic liquids (RTILs) decompose thermally between 400 K and 600 K due to their organic constituents; this range of temperatures is hundreds of degrees below recent estimates of their Tc. In both cases, reliable methods to deduce Tc based on extrapolations of experimental data recorded at much lower temperatures near the triple or melting points are needed and useful because the critical point influences the fluid's behavior in the entire liquid region. Here, we propose to employ the scaling approach leading to universal fluid behavior [Román et al., J. Chem. Phys. 123, 124512 (2005)] to derive a very simple expression that allows one to estimate Tc from the density of the liquid, the surface tension, or the enthalpy of vaporization measured in a very narrow range of low temperatures. We demonstrate the validity of the approach for simple and polar neutral fluids, for which Tc is known, and then use the methodology to obtain estimates of Tc for ionic fluids. When comparing these estimates to those reported in the literature, good agreement is found for RTILs, whereas the ones for the molten salts NaCl and KCl are lower than previous estimates by 10%. The coexistence curve for ionic fluids is found to be more adequately described by an effective exponent of βeff = 0.5 than by βeff = 0.33.

  19. A nonparametric temperature controller with nonlinear negative reaction for multi-point rapid MR-guided HIFU ablation.

    PubMed

    Petrusca, Lorena; Auboiroux, Vincent; Goget, Thomas; Viallon, Magalie; Muller, Arnaud; Gross, Patrick; Becker, Christoph D; Salomir, Rares

    2014-06-01

    Magnetic resonance-guided high intensity focused ultrasound (MRgHIFU) is a noninvasive method for thermal ablation, which exploits the capabilities of magnetic resonance imaging (MRI) for excellent visualization of the target and for near real-time thermometry. Oncological quality of ablation may be obtained by volumetric sonication under automatic feedback control of the temperature. For this purpose, a new nonparametric (i.e., model independent) temperature controller, using nonlinear negative reaction, was designed and evaluated for the iterated sonication of a prescribed pattern of foci. The main objective was to achieve the same thermal history at each sonication point during volumetric MRgHIFU. Differently sized linear and circular trajectories were investigated ex vivo and in vivo using a phased-array HIFU transducer. A clinical 3T MRI scanner was used and the temperature elevation was measured in five slices simultaneously with a voxel size of 1 1 5 mm(3) and temporal resolution of 4 s. In vivo results indicated a similar thermal history of each sonicated focus along the prescribed pattern, that was 17.3 0.5 C as compared to 16 C prescribed temperature elevation. The spatio-temporal control of the temperature also enabled meaningful comparison of various sonication patterns in terms of dosimetry and near-field safety. The thermal build-up tended to drift downwards in the HIFU transducer with a circular scan. PMID:24893259

  20. Criticality in the slowed-down boiling crisis at zero gravity.

    PubMed

    Charignon, T; Lloveras, P; Chatain, D; Truskinovsky, L; Vives, E; Beysens, D; Nikolayev, V S

    2015-05-01

    Boiling crisis is a transition between nucleate and film boiling. It occurs at a threshold value of the heat flux from the heater called CHF (critical heat flux). Usually, boiling crisis studies are hindered by the high CHF and short transition duration (below 1 ms). Here we report on experiments in hydrogen near its liquid-vapor critical point, in which the CHF is low and the dynamics slow enough to be resolved. As under such conditions the surface tension is very small, the experiments are carried out in the reduced gravity to preserve the conventional bubble geometry. Weightlessness is created artificially in two-phase hydrogen by compensating gravity with magnetic forces. We were able to reveal the fractal structure of the contour of the percolating cluster of the dry areas at the heater that precedes the boiling crisis. We provide a direct statistical analysis of dry spot areas that confirms the boiling crisis at zero gravity as a scale-free phenomenon. It was observed that, in agreement with theoretical predictions, saturated boiling CHF tends to zero (within the precision of our thermal control system) in zero gravity, which suggests that the boiling crisis may be observed at any heat flux provided the experiment lasts long enough. PMID:26066249

  1. Criticality in the slowed-down boiling crisis at zero gravity

    NASA Astrophysics Data System (ADS)

    Charignon, T.; Lloveras, P.; Chatain, D.; Truskinovsky, L.; Vives, E.; Beysens, D.; Nikolayev, V. S.

    2015-05-01

    Boiling crisis is a transition between nucleate and film boiling. It occurs at a threshold value of the heat flux from the heater called CHF (critical heat flux). Usually, boiling crisis studies are hindered by the high CHF and short transition duration (below 1 ms). Here we report on experiments in hydrogen near its liquid-vapor critical point, in which the CHF is low and the dynamics slow enough to be resolved. As under such conditions the surface tension is very small, the experiments are carried out in the reduced gravity to preserve the conventional bubble geometry. Weightlessness is created artificially in two-phase hydrogen by compensating gravity with magnetic forces. We were able to reveal the fractal structure of the contour of the percolating cluster of the dry areas at the heater that precedes the boiling crisis. We provide a direct statistical analysis of dry spot areas that confirms the boiling crisis at zero gravity as a scale-free phenomenon. It was observed that, in agreement with theoretical predictions, saturated boiling CHF tends to zero (within the precision of our thermal control system) in zero gravity, which suggests that the boiling crisis may be observed at any heat flux provided the experiment lasts long enough.

  2. Challenging the distributed temperature sensing technique for estimating groundwater discharge to streams through controlled artificial point source experiment

    NASA Astrophysics Data System (ADS)

    Lauer, F.; Frede, H.-G.; Breuer, L.

    2012-04-01

    Spatially confined groundwater discharge can contribute significantly to stream discharge. Distributed fibre optic temperature sensing (DTS) of stream water has been successfully used to localize- and quantify groundwater discharge from this type "point sources" (PS) in small first-order streams. During periods when stream and groundwater temperatures differ PS appear as abrupt step in longitudinal stream water temperature distribution. Based on stream temperature observation up- and downstream of a point source and estimated or measured groundwater temperature the proportion of groundwater inflow to stream discharge can be quantified using simple mixing models. However so far this method has not been quantitatively verified, nor has a detailed uncertainty analysis of the method been conducted. The relative accuracy of this method is expected to decrease nonlinear with decreasing proportions of lateral inflow. Furthermore it depends on the temperature differences (ΔT) between groundwater and surface water and on the accuracy of temperature measurement itself. The latter could be affected by different sources of errors. For example it has been shown that a direct impact of solar radiation on fibre optic cables can lead to errors in temperature measurements in small streams due to low water depth. Considerable uncertainty might also be related to the determination of groundwater temperature through direct measurements or derived from the DTS signal. In order to directly validate the method and asses it's uncertainty we performed a set of artificial point source experiments with controlled lateral inflow rates to a natural stream. The experiments were carried out at the Vollnkirchener Bach, a small head water stream in Hessen, Germany in November and December 2011 during a low flow period. A DTS system was installed along a 1.2 km sub reach of the stream. Stream discharge was measured using a gauging flume installed directly upstream of the artificial PS. Lateral inflow was simulated using a pumping system connected to a 2 m3 water tank. Pumping rates were controlled using a magnetic inductive flowmeter and kept constant for a time period of 30 minutes to 1.5 hours depending on the simulated inflow rate. Different temperatures of lateral inflow were adjusted by heating the water in the tank (for summer experiments a cooling by ice cubes could be realized). With this setup, different proportions of lateral inflow to stream flow ranging from 2 to 20%, could be simulated for different ΔT's (2-7° C) between stream- and inflowing water. Results indicate that the estimation of groundwater discharge through DTS is working properly, but that the method is very sensitive to the determination of the PS groundwater temperature. The span of adjusted ΔT and inflow rates of the artificial system are currently used to perform a thorough uncertainty analysis of the DTS method and to derive thresholds for detection limits.

  3. Temperature and pressure dependence of the mode Grüneisen parameters close to the melting point in hexagonal ice.

    PubMed

    Karacali, H; Yurtseven, H

    2007-02-01

    We reexamine the Pippard relations in this study by relating the specific heat CP to the Raman frequency shifts 1/nu (partial differentialnu/partial differentialT) P and the thermal expansivity alphap to the 1/nu (partial differentialnu/partial differentialP) T, when the mode Grüneisen parameter depends on the temperature and pressure close to the melting point in hexagonal ice. From linear relations between them, the values of the slope dP/dT are deduced in this crystal. Our slope values calculated here do not change significantly compared to those obtained when the mode Grüneisen parameter is taken as a constant close to the melting point in hexagonal ice. PMID:16859963

  4. Influence of temperature on measurements of the CO2 compensation point: differences between the Laisk and O2-exchange methods.

    PubMed

    Walker, Berkley J; Cousins, Asaph B

    2013-04-01

    The CO2 compensation point in the absence of day respiration (?*) is a key parameter for modelling leaf CO2 exchange. ?* links the kinetics of ribulose-1,5-bisphosphate carboxylase-oxygenase (Rubisco) with the stoichiometry of CO2 released per Rubisco oxygenation from photorespiration (?), two essential components of biochemical models of photosynthesis. There are two main gas-exchange methods for measuring ?*: (i) the Laisk method, which requires estimates of mesophyll conductance to CO2 (g m) and (ii) measurements of O2 isotope exchange, which assume constant values of ? and a fixed stoichiometry between O2 uptake and Rubisco oxygenation. In this study, the temperature response of ?* measured using the Laisk and O2-exchange methods was compared under ambient (25 C) and elevated (35 C) temperatures to determine whether both methods yielded similar results. Previously published temperature responses of ?* estimated with the Laisk and O2-exchange methods in Nicotiana tabacum demonstrated that the Laisk-derived model of ?* was more sensitive to temperature compared with the O2-exchange model. Measurements in Arabidopsis thaliana indicated that the Laisk and O2-exchange methods produced similar ?* at 25 C; however, ?* values from O2 exchange were lower at 35 C compared with the Laisk method. Compared with a photorespiratory mutant (pmdh1pmdh2hpr) with increased ?, wild-type (WT) plants had lower Laisk values of ?* at 25 C but were not significantly different at 35 C. These differences between Laisk and O2 exchange values of ?* at 35 C could be explained by temperature sensitivity of ? in WT and/or errors in the assumptions of O2 exchange. The differences between ?* measured using the Laisk and O2-exchange method with temperature demonstrate that assumptions used to measure ?*, and possibly the species-specific validity of these assumptions, need to be considered when modelling the temperature response of photosynthesis. PMID:23630324

  5. Preliminary Demonstration Reactor Point Design for the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect

    Qualls, A. L.; Betzler, Benjamin R.; Brown, Nicholas R.; Carbajo, Juan; Greenwood, Michael Scott; Hale, Richard Edward; Harrison, Thomas J.; Powers, Jeffrey J.; Robb, Kevin R.; Terrell, Jerry W.

    2015-12-01

    Development of the Fluoride Salt-Cooled High-Temperature Reactor (FHR) Demonstration Reactor (DR) is a necessary intermediate step to enable commercial FHR deployment through disruptive and rapid technology development and demonstration. The FHR DR will utilize known, mature technology to close remaining gaps to commercial viability. Lower risk technologies are included in the initial FHR DR design to ensure that the reactor can be built, licensed, and operated within an acceptable budget and schedule. These technologies include tristructural-isotropic (TRISO) particle fuel, replaceable core structural material, the use of that same material for the primary and intermediate loops, and tube-and-shell heat exchangers. This report provides an update on the development of the FHR DR. At this writing, the core neutronics and thermal hydraulics have been developed and analyzed. The mechanical design details are still under development and are described to their current level of fidelity. It is anticipated that the FHR DR can be operational within 10 years because of the use of low-risk, near-term technology options.

  6. Temperature-plant pigment-optical relations in a recurrent offshore mesoscale eddy near Point Conception, California

    NASA Technical Reports Server (NTRS)

    Simpson, James J.; Pelaez, Jose; Haury, Loren R.; Wiesenhahn, David; Koblinsky, Chester J.

    1986-01-01

    The temperature-plant pigment-optical structure of a mesoscale anticyclonic eddy consistently found in shipboard surveys and satellite-sensed data several hundred kilometers southwest of Point Conception, CA, is described on three different time scales (100-day mesoscale, annual, and several-year). The satellite coastal zone color scanner (CZCS) ocean color imagery detected the near-surface chlorophyll structure of the eddy, but in situ optical and plant pigment data suggest that such imagery does not provide a good estimate of the integrated chlorophyll field of the eddy. The temperature and plant pigment boundaries of the eddy, as determined from two-dimensional gradients of advanced very high resolution radiometer (AVHRR) and CZCS imagery, do not coincide spatially. This and in situ temperature, plant pigment, and optical structure provide additional evidence that some eddy systems in the California Current are not isolated vortex systems but rather continuously entrain waters of nonlocal origin laterally into their upper layers. Within the California Current a ratio of AVHRR/CZCS data is useful for separating inshore from oceanic water masses and following their surface entrainment by offshore vortices. The historical 28-year California Cooperative Oceanic Fisheries Investigations data for the Point Conception region of the California Current and remotely sensed data over this region show that the Point Conception eddy is a recurrent feature in the offshore California Current. Moreover, the available data provide evidence that a large number of warm-core mesoscale eddies occur simultaneously in a transition zone between coastal and oceanic regimes, that these features recur at preferred locations within the transition zone, and that this family of eddies should impose a significant offshore boundary condition on the flow of the California Current.

  7. Testing for the Gaussian nature of cosmological density perturbations through the three-point temperature correlation function

    NASA Technical Reports Server (NTRS)

    Luo, Xiaochun; Schramm, David N.

    1993-01-01

    One of the crucial aspects of density perturbations that are produced by the standard inflation scenario is that they are Gaussian where seeds produced by topological defects tend to be non-Gaussian. The three-point correlation function of the temperature anisotropy of the cosmic microwave background radiation (CBR) provides a sensitive test of this aspect of the primordial density field. In this paper, this function is calculated in the general context of various allowed non-Gaussian models. It is shown that the Cosmic Background Explorer and the forthcoming South Pole and balloon CBR anisotropy data may be able to provide a crucial test of the Gaussian nature of the perturbations.

  8. Transient boiling in two-phase helium natural circulation loops

    NASA Astrophysics Data System (ADS)

    Furci, H.; Baudouy, B.; Four, A.; Meuris, C.

    2014-01-01

    Two-phase helium natural circulation loops are used for cooling large superconducting magnets, as CMS for LHC. During normal operation or in the case of incidents, transients are exerted on the cooling system. Here a cooling system of this type is studied experimentally. Sudden power changes are operated on a vertical-heated-section natural convection loop, simulating a fast increase of heat deposition on magnet cooling pipes. Mass flow rate, heated section wall temperature and pressure drop variations are measured as a function of time, to assess the time behavior concerning the boiling regime according to the values of power injected on the heated section. The boiling curves and critical heat flux (CHF) values have been obtained in steady state. Temperature evolution has been observed in order to explore the operating ranges where heat transfer is deteriorated. Premature film boiling has been observed during transients on the heated section in some power ranges, even at appreciably lower values than the CHF. A way of attenuating these undesired temperature excursions has been identified through the application of high enough initial heating power.

  9. Comparison of the triple-point temperatures of {sup 20}Ne, {sup 22}Ne and normal Ne

    SciTech Connect

    Nakano, T.; Tamura, O.; Nagao, K.

    2013-09-11

    At the National Metrology Institute of Japan (NMIJ), the triple points of {sup 20}Ne and {sup 22}Ne were realized using modular sealed cells, Ec3Ne20 and Ec8Ne22, made by the Istituto Nazionale di Ricerca Metrologica (INRiM) in Italy. The difference of the triple-point temperatures of {sup 20}Ne and {sup 22}Ne was estimated by using the sub-range of standard platinum resistance thermometers (SPRTs) calibrated by NMIJ on the International Temperature Scale of 1990 (ITS-90). The melting curves obtained with the Ec3Ne20 and Ec8Ne22 cells show narrow widths (0.1 mK) over a wide range of the inverse of the melted fraction (1/F) from 1/F=1 to 1/F=10. The liquidus point T{sub tp} estimated by the melting curves from F∼0.5 to F∼0.85 using the Ec8Ne22 is 0.146 29 (4) K higher than that using the Ec3Ne20 cell, which is in good agreement with that observed by INRiM using the same cells. After correction of the effect of impurities and other isotopes for Ec3Ne20 and Ec8Ne22 cells, the difference of T{sub tp} between pure {sup 20}Ne and pure {sup 22}Ne is estimated to be 0.146 61 (4) K, which is consistent with the recent results reported elsewhere. The sub-ranges of SPRTs computed by using the triple point of {sup 20}Ne or {sup 22}Ne realized by the Ec3Ne20 cell or the Ec8Ne22 cell in place of the triple point of Ne for the defining fixed point of the ITS-90 are in good agreement with those realized on the basis of the ITS-90 at NMIJ within 0.03 mK, which is much smaller than the non-uniqueness and the sub-range inconsistency of SPRTs.

  10. Boiling Fluids Behave Quite Differently in Space - Duration: 19 seconds.

    NASA Video Gallery

    The boiling process is really different in space, since the vapor phase of a boiling liquid does not rise via buoyancy. Spacecraft and Earth-based systems use boiling to efficiently remove large am...

  11. A dual-unit pressure sensor for on-chip self-compensation of zero-point temperature drift

    NASA Astrophysics Data System (ADS)

    Wang, Jiachou; Li, Xinxin

    2014-08-01

    A novel dual-unit piezoresistive pressure sensor, consisting of a sensing unit and a dummy unit, is proposed and developed for on-chip self-compensation for zero-point temperature drift. With an MIS (microholes inter-etch and sealing) process implemented only from the front side of single (1?1?1) silicon wafers, a pressure sensitive unit and another identically structured pressure insensitive dummy unit are compactly integrated on-chip to eliminate unbalance factors induced zero-point temperature-drift by mutual compensation between the two units. Besides, both units are physically suspended from silicon substrate to further suppress packaging-stress induced temperature drift. A simultaneously processes ventilation hole-channel structure is connected with the pressure reference cavity of the dummy unit to make it insensitive to detected pressure. In spite of the additional dummy unit, the sensor chip dimensions are still as small as 1.2?mm 1.2?mm 0.4?mm. The proposed dual-unit sensor is fabricated and tested, with the tested sensitivity being 0.104?mV?kPa-1 3.3?V-1, nonlinearity of less than 0.08% FSO and overall accuracy error of 0.18% FSO. Without using any extra compensation method, the sensor features an ultra-low temperature coefficient of offset (TCO) of 0.002%?C-1 FSO that is much better than the performance of conventional pressure sensors. The highly stable and small-sized sensors are promising for low cost production and applications.

  12. Pool Boiling Experiment Has Successful Flights

    NASA Technical Reports Server (NTRS)

    1996-01-01

    The Pool Boiling Experiment (PBE) is designed to improve understanding of the fundamental mechanisms that constitute nucleate pool boiling. Nucleate pool boiling is a process wherein a stagnant pool of liquid is in contact with a surface that can supply heat to the liquid. If the liquid absorbs enough heat, a vapor bubble can be formed. This process occurs when a pot of water boils. On Earth, gravity tends to remove the vapor bubble from the heating surface because it is dominated by buoyant convection. In the orbiting space shuttle, however, buoyant convection has much less of an effect because the forces of gravity are very small. The Pool Boiling Experiment was initiated to provide insight into this nucleate boiling process, which has many Earthbound applications, such as steam-generation power plants, petroleum, and other chemical plants. Also, by using the test fluid R-113, the Pool Boiling Experiment can provide some basic understanding of the boiling behavior of cryogenic fluids without the large cost of an experiment using an actual cryogen.

  13. Pool Boiling Experiment Has Five Successful Flights

    NASA Technical Reports Server (NTRS)

    Chiaramonte, Fran

    1997-01-01

    The Pool Boiling Experiment (PBE) is designed to improve understanding of the fundamental mechanisms that constitute nucleate pool boiling. Nucleate pool boiling is a process wherein a stagnant pool of liquid is in contact with a surface that can supply heat to the liquid. If the liquid absorbs enough heat, a vapor bubble can be formed. This process occurs when a pot of water boils. On Earth, gravity tends to remove the vapor bubble from the heating surface because it is dominated by buoyant convection. In the orbiting space shuttle, however, buoyant convection has much less of an effect because the forces of gravity are very small. The Pool Boiling Experiment was initiated to provide insight into this nucleate boiling process, which has many earthbound applications in steamgeneration power plants, petroleum plants, and other chemical plants. In addition, by using the test fluid R-113, the Pool Boiling Experiment can provide some basic understanding of the boiling behavior of cryogenic fluids without the large cost of an experiment using an actual cryogen.

  14. High-freezing-point fuels used for aviation turbine engines

    NASA Technical Reports Server (NTRS)

    Friedman, R.

    1979-01-01

    Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. The higher-freezing-point fuels can be substituted in the majority of present commercial flights, since temperature data indicate that in-flight fuel temperatures are relatively mild. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple system design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating. Both systems offer advantages that outweigh the obvious penalties.

  15. Fast and precise point spread function measurements of IR optics at extreme temperatures based on reversed imaging conditions

    NASA Astrophysics Data System (ADS)

    Melzer, Volker; Heckmann, Hans-Georg; Ritter, Christian; Barenz, Joachim; Raab, Michael

    2010-04-01

    Point Spread Function (PSF), Modulation Transfer Function (MTF) and Ensquared Energy (EE) are important performance indicators of optical systems for surveillance, imaging and target tracking applications. We report on the development of a new measurement method which facilitates fast real time measurement of the two dimensional PSF and related performance parameters of a MWIR optical module under room temperature as well as under extreme temperature conditions. Our new measurement setup uses the law of reversibility of optical paths to capture a highly resolved, magnified image of the PSF. By using of an easy add-on thermally insulating enclosure the optical module can be exposed to and measured under both variable high and low temperatures (-50°C up to 90°C) without any external impact on the measurement. Also line of sight and various off-axis measurements are possible. Common PSF and MTF measurement methods need much more correction algorithms, whilst our method requires mainly a pinhole diameter correction only and allows fast measurements of optical parameters under temperature as well as fast and easy adjustment. Additionally comparison of the captured, highly resolved PSF with optical design data enables purposeful theoretical investigation of occurring optical artifacts.

  16. Position-dependent velocity of an effective temperature point for the estimation of the thermal diffusivity of solids

    NASA Astrophysics Data System (ADS)

    Balachandar, Settu; Shivaprakash, N. C.; Kameswara Rao, L.

    2016-01-01

    A new approach is proposed to estimate the thermal diffusivity of optically transparent solids at ambient temperature based on the velocity of an effective temperature point (ETP), and by using a two-beam interferometer the proposed concept is corroborated. 1D unsteady heat flow via step-temperature excitation is interpreted as a ‘micro-scale rectilinear translatory motion’ of an ETP. The velocity dependent function is extracted by revisiting the Fourier heat diffusion equation. The relationship between the velocity of the ETP with thermal diffusivity is modeled using a standard solution. Under optimized thermal excitation, the product of the ‘velocity of the ETP’ and the distance is a new constitutive equation for the thermal diffusivity of the solid. The experimental approach involves the establishment of a 1D unsteady heat flow inside the sample through step-temperature excitation. In the moving isothermal surfaces, the ETP is identified using a two-beam interferometer. The arrival-time of the ETP to reach a fixed distance away from heat source is measured, and its velocity is calculated. The velocity of the ETP and a given distance is sufficient to estimate the thermal diffusivity of a solid. The proposed method is experimentally verified for BK7 glass samples and the measured results are found to match closely with the reported value.

  17. Temperature mapping in bread dough using SE and GE two-point MRI methods: experimental and theoretical estimation of uncertainty.

    PubMed

    Lucas, Tiphaine; Musse, Maja; Bornert, Mélanie; Davenel, Armel; Quellec, Stéphane

    2012-04-01

    Two-dimensional (2D)-SE, 2D-GE and tri-dimensional (3D)-GE two-point T(1)-weighted MRI methods were evaluated in this study in order to maximize the accuracy of temperature mapping of bread dough during thermal processing. Uncertainties were propagated throughout each protocol of measurement, and comparisons demonstrated that all the methods with comparable acquisition times minimized the temperature uncertainty to similar extent. The experimental uncertainties obtained with low-field MRI were also compared to the theoretical estimations. Some discrepancies were reported between experimental and theoretical values of uncertainties of temperature; however, experimental and theoretical trends with varying parameters agreed to a large extent for both SE and GE methods. The 2D-SE method was chosen for further applications on prefermented dough because of its lower sensitivity to susceptibility differences in porous media. It was applied for temperature mapping in prefermented dough during chilling prior to freezing and compared locally to optical fiber measurements. PMID:22227351

  18. Bubble behavior and mean diameter in subcooled flow boiling

    SciTech Connect

    Zeitoun, O.; Shoukri, M.

    1996-02-01

    Bubble behavior and mean bubble diameter in subcooled upward flow boiling in a vertical annular channel were investigated under low pressure and mass flux conditions. High-speed photographic results indicated that, contrary to the common understanding, bubbles tend to detach from the heating surface upstream of the net vapor generation point. Digital image processing technique was used to measure the mean bubble diameter along the subcooled flow boiling region. Data on the axial area-averaged void fraction distributions were also obtained using a single-beam gamma densitometer. Effects of the liquid subcooling, applied heat flux and mass flux on the mean bubble size were investigated. A correlation for the mean bubble diameter as a function of the local subcooling, heat flux, and mass flux was obtained. 28 refs., 8 figs., 1 tab.

  19. Experimental investigation of nucleate boiling and thin-film evaporation on enhanced silicon surfaces

    NASA Astrophysics Data System (ADS)

    Malla, Shailesh

    The present work consists of two major studies. The first study investigates the effects of surface energy or wettability on nucleate pool boiling and the second study investigates the thin-film evaporative cooling for near junction thermal management. For the first study, effects of surface energy or wettability on critical heat flux (CHF) and boiling heat transfer (BHT) of smooth heated surfaces was studied in saturated pool boiling of water at 1 atm. For this purpose hydrophilic and hydrophobic surfaces were created on one side of 1cm x 1cm double-side polished silicon substrates. A resistive heating layer was applied on the opposite side of each substrate. The surface energies of the created surfaces were characterized by measuring the static contact angles of water sessile drops. To provide a wide range of surface energies, surfaces were made of Teflon (hydrophobic), bare silicon (hydrophilic) and aluminum oxide (most hydrophilic). The measured contact angles on these surfaces were ˜108, ˜57 and ˜13 degrees respectively. The results of pool boiling tests on these surfaces clearly illustrate the connection between surface energy and CHF. CHF was shown to linearly decrease with contact angle increase, from ˜125 W/cm2 on aluminum oxide (most hydrophilic) to nearly one tenth of this value on Teflon (hydrophobic). The most hydrophilic surface also produced increasingly better BHT than plain silicon and Teflon as heat flux increased. However, below ˜5 W/cm2 the hydrophobic surface demonstrated better heat transfer due to earlier onset of nucleate boiling, reducing surface superheats by up to ˜5 degrees relative to the other two surfaces. Above ˜5 W/cm2 the BHT of the hydrophobic surface rapidly deteriorated as superheat increased towards the value at CHF. To further understand the effect of surface energy on pool boiling performance, the growth and departure of bubbles from single nucleating sites on each surface were analyzed from high-speed video recordings. A distinct bubble behavior was observed in the hydrophobic surface where bubble growth and departure period was extremely long compared to plain silicon and aluminum oxide surfaces. This study also investigated the performance of thin-film evaporative cooling for near-junction thermal management. A liquid delivery system capable of delivering water in small volumes ranging 20˜75 nl at frequencies of up to 600 Hz was established. On one side of the silicon chip, a resistive heating layer of 2 mm x 2 mm was fabricated to emulate the high heat flux hot-spot, and on the other side a superhydrophilic nanoporous coating (SHNC) was applied over an area of 1 cm x 1 cm. With the aid of the nanoporous coating, delivered droplets spread into thin films of thicknesses less than 10microm. With this system, evaporative tests were conducted in ambient in an effort to maximize dryout heat flux and evaporative heat transfer coefficient. During the tests, heat flux at the hot spot was varied to values above 1000 W/cm 2. Water was delivered at either given constant frequency (constant mass flow rate) or at programmed variations of frequency (variable mass flow rate), for a given nanoliter dose volume. Heat flux and hot spot surface temperatures were recorded upon reaching steady state at each applied heat flux increment. Relative to bare silicon surface, dryout heat flux of the SHNC surface was found to increase by ˜5 times at 500˜600 Hz. Tests were also conducted at various system pressures and temperatures in a micro-gap to emulate the actual embedded thermal management system. The micro-gap was made by positioning a top cover plate 500 microm above the test surface. System temperature did not influence the hotspot temperature. This was due to the formation of near saturation temperature inside the micro-gap for all cases as a result of vapor accumulation. Increase in system pressure increased the hotspot temperature. At 1500 W/cm2, hotspot temperature increased by 6oC and 24oC by increasing the system pressure by 7.32 and 14.7 psi respectively. This was due to increase in saturation point as a result of increase in pressure. On the SHNC surface a mixed mode of heat transfer comprising of thin-film boiling and thin-film evaporation was observed particularly at moderate heat flux (˜700 W/cm2). To further enhance the heat transfer coefficient, aluminum microporous coating was developed that increased the number of nucleation sites for thin-film boiling and also maintained the wettability for thin-film evaporation at higher heat fluxes. Test results showed a marginal improvement in dry-out heat flux compared to SHNC, however, significant reduction was achieved in hot-spot temperature at all heat flux levels. A net reduction of ˜ 58oC was obtained at ˜1600 W/cm2 by using aluminum based microporous coating.

  20. Correlations of velocity and temperature fluctuations in the stagnation-point flow of circular cylinder in turbulent flow

    NASA Technical Reports Server (NTRS)

    Wang, Chi R.

    1988-01-01

    Boundary layer flow and turbulence transport analyses to study the influence of the free-stream turbulence on the surface heat transfer rate and the skin friction around the stagnation point of a circular cylinder in a turbulent flow are presented. The analyses are formulated with the turbulent boundary layer equations, the Reynolds stress transport equations and the k - epsilon two-equation turbulence modeling. The analyses are used to calculate the time-averaged turbulence double correlations, the mean flow properties, the surface heat transfer rate and the skin friction with an isotropic turbulence in the freestream. The analytical results are described and compared with the existing experimental measurements. Depending on the free-stream turbulence properties, the turbulence kinetic energy can increase or decrease as the flow moves toward the surface. However, the turbulence kinetic energy induces large Reynolds normal stresses at the boundary layer edge. The Reynolds normal stresses change the boundary layer profiles of the time-averaged double correlations of the velocity and temperature fluctuations, the surface heat transfer rate and the skin friction. The free-stream turbulence dissipation rate can affect the stagnation-point heat transfer rate but the influence of the free-stream temperature fluctuation on the heat transfer rate is insignificant.

  1. The high temperature three point bend testing of proton irradiated 316L stainless steel and Mod 9Cr 1Mo

    NASA Astrophysics Data System (ADS)

    Maloy, Stuart A.; Zubelewicz, A.; Romero, T.; James, M. R.; Sommer, W. F.; Dai, Y.

    2005-08-01

    The predicted operating conditions for a lead-bismuth eutectic target to be used in an accelerator driven system for the Advanced Fuel Cycle Initiative span a temperature range of 300-600 °C while being irradiated by a high energy (˜600 MeV) proton beam. Such spallation conditions lead to high displacement rates coupled with high accumulation rates of helium and hydrogen up to 150 appm/dpa. Some candidate materials for these applications include Mod9Cr-1Mo and 316L stainless steel. To investigate the effect of irradiation on these materials, the mechanical properties are being measured through three point bend testing on Mod 9Cr-1Mo and 316L at 25, 250, 350 and 500 °C after irradiation in a high energy proton beam (500-800 MeV) to a dose of 9.8 dpa at temperatures from 200 to 320 °C. By comparing measurements made in bending to tensile measurements measured on identically irradiated materials, a measurement of 0.2% offset yield stress was obtained from 0.05% offset yield stress measured in three point bend testing. Yield stress increased by more than a factor of two after irradiation to 9.8 dpa. Observation of the outer fiber surface of 316L showed very localized deformation when tested after irradiation at 70 °C and deformation on multiple slip systems when tested after irradiation at 250-320 °C.

  2. Our Educational Melting Pot: Have We Reached the Boiling Point?

    ERIC Educational Resources Information Center

    Lauderdale, Katherine Lynn, Ed.; Bonilla, Carlos A., Ed.

    The articles and excerpts in this collection illustrate the complexity of the melting pot concept. Multiculturalism has become a watchword in American life and education, but it may be that in trying to atone for past transgressions educators and others are simply going too far. These essays illustrate some of the problems of a multicultural…

  3. On the Boiling Points of the Alkyl Halides.

    ERIC Educational Resources Information Center

    Correia, John

    1988-01-01

    Discusses the variety of explanations in organic chemistry textbooks of a physical property of organic compounds. Focuses on those concepts explaining attractive forces between molecules. Concludes that induction interactions play a major role in alkyl halides and other polar organic molecules and should be given wider exposure in chemistry texts.…

  4. Apparatus for pumping liquids at or below the boiling point

    DOEpatents

    Bingham, Dennis N. (Idaho Falls, ID)

    2002-01-01

    A pump comprises a housing having an inlet and an outlet. An impeller assembly mounted for rotation within the housing includes a first impeller piece having a first mating surface thereon and a second impeller piece having a second mating surface therein. The second mating surface of the second impeller piece includes at least one groove therein so that at least one flow channel is defined between the groove and the first mating surface of the first impeller piece. A drive system operatively associated with the impeller assembly rotates the impeller assembly within the housing.

  5. On the Boiling Points of the Alkyl Halides.

    ERIC Educational Resources Information Center

    Correia, John

    1988-01-01

    Discusses the variety of explanations in organic chemistry textbooks of a physical property of organic compounds. Focuses on those concepts explaining attractive forces between molecules. Concludes that induction interactions play a major role in alkyl halides and other polar organic molecules and should be given wider exposure in chemistry texts.

  6. Characterization of Monodispersed γ-Al2O3 Particles, Synthesized by Homogeneous Precipitation under Reflux Boiling

    NASA Astrophysics Data System (ADS)

    Haq, Ikram Ul; Akhtar, Khalida; Khan, Zia Ullah

    2015-07-01

    In this study, micron size uniform particles of aluminum compounds were synthesized by the homogeneous precipitation method under reflux boiling, using aluminum nitrate, urea and potassium sulfate as starting materials. In this method, varying amounts of the reactants were heated in a Pyrex glass round bottom flask at the boiling temperature for various periods of time, which led to the production of precipitated particles in the reactant mixtures. Scanning electron microscopic (SEM) examination of the precipitated particles revealed that uniformity in particle morphology of the precipitated particles was dependent on the applied experimental conditions. As such, the latter were extensively optimized for obtaining particles of uniform morphology and size. Some of the batches of the precipitated particles were calcined at the elevated temperature (800 and 1000 °C) for transformation into crystalline solids. Similarly, the as prepared and calcined particles were characterized by SEM, XRD, TGA/DTA and FTIR. XRD results revealed that at 1000 °C of calcinations, the as prepared amorphous alumina transformed in to crystalline state, while below this temperature, i.e. at 800 °C calcination, the powder was amorphous in nature. The point of zero charge (PZC) of the desired sample was estimated by the salt addition method.

  7. Theory of finite-temperature crossovers near quantum critical points close to,or above, their upper-critical dimension

    NASA Astrophysics Data System (ADS)

    Sachdev, Subir

    1997-01-01

    A systematic method for the computation of finite-temperature (T) crossover functions near quantum-critical points close to, or above, their upper-critical dimension is devised. We describe the physics of the various regions in the T and critical tuning parameter (t) plane. The quantum-critical point is at T=0, t=0, and in many cases there is a line of finite-temperature transitions at T=Tc(t), t<0, with Tc(0)=0. For the relativistic, n-component φ4 continuum quantum field theory [which describes lattice quantum rotor (n>=2) and transverse field Ising (n=1) models] the upper-critical dimension is d=3, and for d<3, ɛ=3-d is the control parameter over the entire phase diagram. In the region \\|T-Tc(t)\\|<0 indeed, analytic continuation in t is used to obtain results in a portion of the phase diagram. Our method also applies to a large class of other quantum-critical points and their associated continuum quantum field theories.

  8. A New Theory of Nucleate Pool Boiling in Arbitrary Gravity

    NASA Technical Reports Server (NTRS)

    Buyevich, Y. A.; Webbon, Bruce W.

    1995-01-01

    Heat transfer rates specific to nucleate pool boiling under various conditions are determined by the dynamics of vapour bubbles that are originated and grow at nucleation sites of a superheated surface. A new dynamic theory of these bubbles has been recently developed on the basis of the thermodynamics of irreversible processes. In contrast to other existing models based on empirically postulated equations for bubble growth and motion, this theory does not contain unwarrantable assumptions, and both the equations are rigorously derived within the framework of a unified approach. The conclusions of the theory are drastically different from those of the conventional models. The bubbles are shown to detach themselves under combined action of buoyancy and a surface tension force that is proven to add to buoyancy in bubble detachment, but not the other way round as is commonly presumed. The theory ensures a sound understanding of a number of so far unexplained phenomena, such as effect caused by gravity level and surface tension on the bubble growth rate and dependence of the bubble characteristics at detachment on the liquid thermophysical parameters and relevant temperature differences. The theoretical predictions are shown to be in a satisfactory qualitative and quantitative agreement with observations. When being applied to heat transfer at nucleate pool boiling, this bubble dynamic theory offers an opportunity to considerably improve the main formulae that are generally used to correlate experimental findings and to design boiling heat removal in various industrial applications. Moreover, the theory makes possible to pose and study a great deal of new problems of essential impact in practice. Two such problems are considered in detail. One problem concerns the development of a principally novel physical model for the first crisis of boiling. This model allows for evaluating critical boiling heat fluxes under various conditions, and in particular at different gravity levels, with a good agreement with experimental evidence. The other problem bears upon equilibrium shapes of a detached bubble near a heated surface in exceedingly low gravity. In low gravity or in weightlessness, the bubble can remain in the close vicinity of the surface for a long time, and its shape is greatly affected by the Marangoni effect due to both temperature and possible surfactant concentration being nonuniform along the interface. The bubble performs at these conditions like a heat pipe, with evaporation at the bubble lower boundary and condensation at its upper boundary, and ultimately ensures a substantial increase in heat removal as compared with that in normal gravity. Some other problems relevant to nucleate pool and forced convection boiling heat transfer are also discussed.

  9. Development, solar test, and evaluation of a high-temperature air receiver for point-focusing parabolic dish applications

    NASA Technical Reports Server (NTRS)

    Hanseth, E. J.

    1981-01-01

    A high temperature solar receiver was fabricated and tested in excess of 1370 C on an 11-meter-diameter test bed concentrator at the Jet Propulsion Laboratory Parabolic Dish Test Site, Edwards, California. The 60-kilowatt thermal receiver design utilizes state-of-the-art silicon carbide honeycomb matrix panels to receive and transfer the solar energy and mullite elements for thermal buffer storage. Solar tests were conducted with indicated air exit temperatures ranging from 885 C (1625 F) to 1427 C (2600 F), mass flow rates of 75 to 105 g/sec (0.16 to 0.23 lbm/sec), and pressures up to 265 kPa absolute (38.4 psia). Estimates of efficiency are 59.7% at 1120 C (2048 F) to 80.6% at 885 C (1625 F) when aperture spillage losses are considered separately. Results are presented which demonstrate the feasibility of this innovative receiver concept for point-focusing parabolic dish applications over a wide temperature range.

  10. Evolution of SF[sub 6] pressure at constant volume versus temperature between liquefaction point and +20[degree]C

    SciTech Connect

    Thuries, E.; Girodet, A.; Collet, M. . Research Center)

    1994-07-01

    Switchgear must be able to operate within a temperature range anywhere from [minus]50 C to +55 C. The practical problem of how to perform significant tests at +20 C then presents itself. It becomes mandatory to know the equivalent of the density at the lowest temperature to which the switchgear will be subjected. A perfect mathematical knowledge of SF[sub 6] evolution at constant volume versus temperature between the liquefaction point and +20 C is then very important. There exists today three main state equations used by SF[sub 6] switchgear users and manufacturers and they do not truly agree between themselves. The authors evaluate them and also describe a simple experiment as defined by E. Thuries to check these state equations. The last part of the paper describes various experimental data that drive one to establish a state equation using the new notion of fugacity. The last part of the paper compares this state equation based on fugacity and the other equations as used today against the results of the new SF[sub 6] Thuries experiment.

  11. Pool Boiling of Ethanol-Water mixture on Nano-Textured Surfaces

    NASA Astrophysics Data System (ADS)

    Yarin, Alexander; Sahu, Rakesh; Sinha-Ray, Sumit; Sinha-Ray, Suman

    2015-03-01

    An experimental and theoretical study of pool boiling of ethanol-water mixtures on nano-textured surfaces was studied. A comparison of pool boiling on bare copper surface with pool boiling on surfaces covered by copper-plated supersonically-blown nanofibers revealed a significant increase in the heat flux in the latter case. Namely, the heat flux on the nano-textured surfaces was about 3-8 times higher than that on the bare copper surfaces, while the surface temperature due to the nano-texture would be lower by about 10 °C at the same heat flux. The significant positive effect of the nano-texture is due to the fact that it facilitates bubble nucleation. Some preliminary results of numerical modeling of boiling process in the framework of the Cahn-Hilliard approach are discussed and several examples of the predictions are given. Supported by NASA, Grant No. NNX13AQ77G.

  12. Zero Boil Off Cryogen Storage for Future Launchers

    NASA Technical Reports Server (NTRS)

    Valentian, D.; Plachta, D.; Kittel, P.; Hastings, L. J.; Salerno, Louis J.; Arnold, James O. (Technical Monitor)

    2001-01-01

    Zero boil off (ZBO) cryogen storage using both cryocoolers and passive insulation technologies will enable long-term exploration missions by allowing designers to optimize tankage without the need for excess cryogen storage to account for boil off. Studies of ZBO (zero boil off) have been on-going in the USA for several years. More recently, a review of the needs of advanced space propulsion took place in Europe. This showed the interest of the European community in cryogenic propulsion for planetary missions as well as the use of liquid hydrogen for large power electric propulsion (manned Mars missions). Although natural boiling could be acceptable for single leg missions, passive insulation techniques yield roughly a I% per month cryogen loss and this would not be cost effective for robotic planetary missions involving storage times greater than one year. To make economic sense, long-term exploration missions require lower tank capacity and longer storage times. Recent advances in cryocooler technology, resulting in vast improvements in both cooler efficiency and reliability, make ZBO is a clear choice for planetary exploration missions. Other, more near term applications of ZBO include boil-off reduction or elimination applied to first and upper stages of future earth-to-orbit (ETO) launchers. This would extend launch windows and reduce infrastructure costs. Successors to vehicles like Ariane 5 could greatly benefit by implementing ZBO. Zero Boil Off will only be successful in ETO launcher applications if it makes economic sense to implement. The energy cost is only a fraction of the total cost of buying liquid cryogen, the rest being transportation and other overhead. Because of this, higher boiling point cryogens will benefit more from on-board liquefaction, thus reducing the infrastructure costs. Since hydrogen requires a liquefier with at least a 17% efficiency just to break even from a cost standpoint, one approach for implementing ZBO in upper stages would be to actively cool the shield in the hydrogen tank to reduce the parasitic losses. This would allow the use of less expensive, presently available coolers (80 K vs. 20 K) and potentially simplify the system by requiring only a single compressor on the pad amd a single disconnect line. The compressor could be a hefty commercial unit, with only the cold head requiring expensive flight development and qualification. While this is actually a reduced boil off configuration rather than a zero-boil off case, if the cryogen loss could be cut significantly, the increase in hold time and reduced need for draining and refilling the propellant tanks could meet the vehicle operations needs in the majority of instances.Bearing in mind the potential benefits of ZBO, NASA AMES and SNECMA Moteurs decided to exchange their technical views on the subject. This paper will present a preliminary analysis for a multi-mission module using a fairly low thrust cryogenic engine and ZBO during cruise. Initial mass is 5.5. tons (in ETO). The cryogenic engine will be used near each periapsis in order to minimize the AV requirement. The payload obtained by this propulsion system is compared to a classical storable bipropellant propulsion system for several cases (e. g. Mars lander, Jupiter orbiter, Saturn orbiter). For the Jupiter and Saturn cases, the power source could be an RTG or a large parabolic mirror illuminating a solar panel. It is shown -that - due to its much larger specific impulse - the cryogenic ZBO solution provides much higher payloads, especially for exploration missions involving landing on planets, asteroids, comets, or other celestial bodies.

  13. Boiling Heat Transfer to Halogenated Hydrocarbon Refrigerants

    NASA Astrophysics Data System (ADS)

    Yoshida, Suguru; Fujita, Yasunobu

    The current state of knowledge on heat transfer to boiling refrigerants (halogenated hydrocarbons) in a pool and flowing inside a horizontal tube is reviewed with an emphasis on information relevant to the design of refrigerant evaporators, and some recommendations are made for future research. The review covers two-phase flow pattern, heat transfer characteristics, correlation of heat transfer coefficient, influence of oil, heat transfer augmentation, boiling from tube-bundle, influence of return bend, burnout heat flux, film boiling, dryout and post-dryout heat transfer.

  14. Finite-temperature scaling at the quantum critical point of the Ising chain in a transverse field

    NASA Astrophysics Data System (ADS)

    Haelg, Manuel; Huvonen, Dan; Guidi, Tatiana; Quintero-Castro, Diana Lucia; Boehm, Martin; Regnault, Louis-Pierre; Zheludev, Andrey

    2015-03-01

    Inelastic neutron scattering is used to study the finite-temperature scaling behavior of spin correlations at the quantum critical point in an experimental realization of the one-dimensional Ising model in a transverse field. The target compound is the well-characterized, anisotropic and bond-alternating Heisenberg spin-1 chain material NTENP. The validity and the limitations of the dynamic structure factor scaling are tested, discussed and compared to theoretical predictions. For this purpose neutron data have been collected on the three-axes spectrometers IN14 at ILL and FLEXX at HZB as well as on the time of flight multi-chopper spectrometer LET at ISIS. In addition to the general statement about quantum criticality and universality, present study also reveals new insight into the properties of the spin chain compound NTENP in particular.

  15. Propulsion apparatus and method using boil-off gas from a cryogenic liquid

    NASA Technical Reports Server (NTRS)

    Blount, D. H. (Inventor)

    1986-01-01

    A propulsion system and method are disclosed for controlling the attitude and drag of a space vehicle. A helium dewar contains liquid helium which cools an experiment package. The helium is heated or vented to keep the temperature between 1.5 and 1.7 degrees K to maintain adequate helium boil-off gas as a propellant without adversely affecting the experiment package which is contained in the helium dewar for protection from solar heating. The apparatus includes auxiliary heater and temperature sensor for controlling the temperature of the helium. The boil-off gas propellant is delivered to thruster modules to control vehicle attutude and compensate for drag.

  16. Critical heat flux in subcooled flow boiling

    NASA Astrophysics Data System (ADS)

    Hall, David Douglas

    The critical heat flux (CHF) phenomenon was investigated for water flow in tubes with particular emphasis on the development of methods for predicting CHF in the subcooled flow boiling regime. The Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) CHF database for water flow in a uniformly heated tube was compiled from the world literature dating back to 1949 and represents the largest CHF database ever assembled with 32,544 data points from over 100 sources. The superiority of this database was proven via a detailed examination of previous databases. The PU-BTPFL CHF database is an invaluable tool for the development of CHF correlations and mechanistic models that are superior to existing ones developed with smaller, less comprehensive CHF databases. In response to the many inaccurate and inordinately complex correlations, two nondimensional, subcooled CHF correlations were formulated, containing only five adjustable constants and whose unique functional forms were determined without using a statistical analysis but rather using the parametric trends observed in less than 10% of the subcooled CHF data. The correlation based on inlet conditions (diameter, heated length, mass velocity, pressure, inlet quality) was by far the most accurate of all known subcooled CHF correlations, having mean absolute and root-mean-square (RMS) errors of 10.3% and 14.3%, respectively. The outlet (local) conditions correlation was the most accurate correlation based on local CHF conditions (diameter, mass velocity, pressure, outlet quality) and may be used with a nonuniform axial heat flux. Both correlations proved more accurate than a recent CHF look-up table commonly employed in nuclear reactor thermal hydraulic computer codes. An interfacial lift-off, subcooled CHF model was developed from a consideration of the instability of the vapor-liquid interface and the fraction of heat required for liquid-vapor conversion as opposed to that for bulk liquid heating. Severe vapor effusion in an upstream wetting front lifts the vapor-liquid interface off the surface, triggering CHF. Since the model is entirely based on physical observations, it has the potential to accurately predict CHF for other fluids and flow geometries which are beyond the conditions for which it was validated.

  17. Evolution of Skin Temperature after the Application of Compressive Forces on Tendon, Muscle and Myofascial Trigger Point

    PubMed Central

    Magalhães, Marina Figueiredo; Dibai-Filho, Almir Vieira; de Oliveira Guirro, Elaine Caldeira; Girasol, Carlos Eduardo; de Oliveira, Alessandra Kelly; Dias, Fabiana Rodrigues Cancio; Guirro, Rinaldo Roberto de Jesus

    2015-01-01

    Some assessment and diagnosis methods require palpation or the application of certain forces on the skin, which affects the structures beneath, we highlight the importance of defining possible influences on skin temperature as a result of this physical contact. Thus, the aim of the present study is to determine the ideal time for performing thermographic examination after palpation based on the assessment of skin temperature evolution. Randomized and crossover study carried out with 15 computer-user volunteers of both genders, between 18 and 45 years of age, who were submitted to compressive forces of 0, 1, 2 and 3 kg/cm2 for 30 seconds with a washout period of 48 hours using a portable digital dynamometer. Compressive forces were applied on the following spots on the dominant upper limb: myofascial trigger point in the levator scapulae, biceps brachii muscle and palmaris longus tendon. Volunteers were examined by means of infrared thermography before and after the application of compressive forces (15, 30, 45 and 60 minutes). In most comparisons made over time, a significant decrease was observed 30, 45 and 60 minutes after the application of compressive forces (p < 0.05) on the palmaris longus tendon and biceps brachii muscle. However, no difference was observed when comparing the different compressive forces (p > 0.05). In conclusion, infrared thermography can be used after assessment or diagnosis methods focused on the application of forces on tendons and muscles, provided the procedure is performed 15 minutes after contact with the skin. Regarding to the myofascial trigger point, the thermographic examination can be performed within 60 minutes after the contact with the skin. PMID:26070073

  18. Induction heating pure vapor source of high temperature melting point materials on electron cyclotron resonance ion source

    SciTech Connect

    Kutsumi, Osamu; Kato, Yushi; Matsui, Yuuki; Sato, Fuminobu; Iida, Toshiyuki; Kitagawa, Atsushi; Muramatsu, Masayuki; Uchida, Takashi; Yoshida, Yoshikazu

    2010-02-15

    Multicharged ions that are needed are produced from solid pure material with high melting point in an electron cyclotron resonance ion source. We develop an evaporator by using induction heating (IH) with multilayer induction coil, which is made from bare molybdenum or tungsten wire without water cooling and surrounding the pure vaporized material. We optimize the shapes of induction coil and vaporized materials and operation of rf power supply. We conduct experiment to investigate the reproducibility and stability in the operation and heating efficiency. IH evaporator produces pure material vapor because materials directly heated by eddy currents have no contact with insulated materials, which are usually impurity gas sources. The power and the frequency of the induction currents range from 100 to 900 W and from 48 to 23 kHz, respectively. The working pressure is about 10{sup -4}-10{sup -3} Pa. We measure the temperature of the vaporized materials with different shapes, and compare them with the result of modeling. We estimate the efficiency of the IH vapor source. We are aiming at the evaporator's higher melting point material than that of iron.

  19. Induction heating pure vapor source of high temperature melting point materials on electron cyclotron resonance ion source.

    PubMed

    Kutsumi, Osamu; Kato, Yushi; Matsui, Yuuki; Kitagawa, Atsushi; Muramatsu, Masayuki; Uchida, Takashi; Yoshida, Yoshikazu; Sato, Fuminobu; Iida, Toshiyuki

    2010-02-01

    Multicharged ions that are needed are produced from solid pure material with high melting point in an electron cyclotron resonance ion source. We develop an evaporator by using induction heating (IH) with multilayer induction coil, which is made from bare molybdenum or tungsten wire without water cooling and surrounding the pure vaporized material. We optimize the shapes of induction coil and vaporized materials and operation of rf power supply. We conduct experiment to investigate the reproducibility and stability in the operation and heating efficiency. IH evaporator produces pure material vapor because materials directly heated by eddy currents have no contact with insulated materials, which are usually impurity gas sources. The power and the frequency of the induction currents range from 100 to 900 W and from 48 to 23 kHz, respectively. The working pressure is about 10(-4)-10(-3) Pa. We measure the temperature of the vaporized materials with different shapes, and compare them with the result of modeling. We estimate the efficiency of the IH vapor source. We are aiming at the evaporator's higher melting point material than that of iron. PMID:20192343

  20. Indo-Pacific Warm Pool Area Expansion, Modoki Activity, and Tropical Cold-Point Tropopause Temperature Variations

    PubMed Central

    Xie, Fei; Li, Jianping; Tian, Wenshou; Li, Yanjie; Feng, Juan

    2014-01-01

    The tropical cold-point tropopause temperature (CPTT), a potentially important indicator of global climate change, is of particular importance for understanding changes in stratospheric water vapor levels. Since the 1980s, the tropical CPTT has shown not only interannual variations, but also a decreasing trend. However, the factors controlling the variations in the tropical CPTT since the 1980s remain elusive. The present study reveals that the continuous expansion of the area of the Indo-Pacific warm pool (IPWP) since the 1980s represents an increase in the total heat energy of the IPWP available to heat the tropospheric air, which is likely to expand as a result. This process lifts the tropical cold-point tropopause height (CPTH) and leads to the observed long-term cooling trend of the tropical CPTT. In addition, our analysis shows that Modoki activity is an important factor in modulating the interannual variations of the tropical CPTT through significant effects on overshooting convection. PMID:24686481

  1. Temperature-dependent thermal conductivities of 1D semiconducting nanowires via four-point-probe 3-ω method.

    PubMed

    Lee, Seung-Yong; Lee, Mi-Ri; Park, No-Won; Kim, Gil-Sung; Choi, Heon-Jin; Choi, Tae-Youl; Lee, Sang-Kwon

    2013-12-13

    We report on a systematic study of the thermal transport characteristics of both as-grown zinc oxide and gallium nitride nanowires (NWs) via the four-point-probe 3-ω method in the temperature range 130-300 K. Both as-grown NWs were synthesized by a vapor-liquid-solid growth mechanism, and show clear n-type semiconducting behavior without any defects, which enables both the NWs to be promising candidates for thermoelectric materials. To measure the thermal conductivities of both NWs with lower heat loss and measurement errors, the suspended structures were formed by a combination of an e-beam lithography process and a random dispersion method. The measured thermal conductivities of both NWs are greatly reduced compared to their bulk materials due to the enhanced phonon scattering via the size effect and dopants (impurities). Furthermore, we observed that the Umklapp peaks of both NWs are shifted to a higher temperature than those of their bulk counterparts, indicating that phonon-boundary scattering dominates over other phonon scattering due to the size effect. PMID:24231523

  2. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  3. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  4. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  5. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling...

  6. Analysis of boiling flat-plate collectors

    SciTech Connect

    Price, H.W.; Klein, S.A.; Beckman, W.A.

    1986-05-01

    A detailed model for use with TRNSYS, capable of modelling a wide range of boiling collector types, was used to analyze boiling flat-plate collector systems. This model can account for a subcooled liquid entering the collector, heat losses in the vapor and the liquid return line, pressure drops due to friction in the collector and piping, and pressure drops due to the hydrostatic head of the fluid. The model has been used to determine the yearly performance of boiling flat-plate solar collector systems. A simplified approach was also developed which can be used with the f-Chart method to predict yearly performance of boiling flat-plate collector systems.

  7. Electrical control and enhancement of boiling heat transfer during quenching

    NASA Astrophysics Data System (ADS)

    Shahriari, Arjang; Hermes, Mark; Bahadur, Vaibhav

    2016-02-01

    Heat transfer associated with boiling degrades at elevated temperatures due to the formation of an insulating vapor layer at the solid-liquid interface (Leidenfrost effect). Interfacial electrowetting (EW) fields can disrupt this vapor layer to promote liquid-surface wetting. We experimentally analyze EW-induced disruption of the vapor layer and measure the resulting enhanced cooling during the process of quenching. Imaging is employed to visualize the fluid-surface interactions and understand boiling patterns in the presence of an electrical voltage. It is seen that EW fields fundamentally change the boiling pattern, wherein a stable vapor layer is replaced by intermittent wetting of the surface. Heat conduction across the vapor gap is thus replaced with transient convection. This fundamental switch in the heat transfer mode significantly accelerates cooling during quenching. An order of magnitude increase in the cooling rate is observed, with the heat transfer seen approaching saturation at higher voltages. An analytical model is developed to extract voltage dependent heat transfer rates from the measured cooling curve. The results show that electric fields can alter and tune the traditional cooling curve. Overall, this study presents an ultralow power consumption concept to control the mechanical properties and metallurgy, by electrically tuning the cooling rate during quenching.

  8. SUPERHEATING IN A BOILING WATER REACTOR

    DOEpatents

    Treshow, M.

    1960-05-31

    A boiling-water reactor is described in which the steam developed in the reactor is superheated in the reactor. This is accomplished by providing means for separating the steam from the water and passing the steam over a surface of the fissionable material which is not in contact with the water. Specifically water is boiled on the outside of tubular fuel elements and the steam is superheated on the inside of the fuel elements.

  9. The Isolated Bubble Regime in Pool Nucleate Boiling

    NASA Technical Reports Server (NTRS)

    Buyevich, Y. A.; Webbon, Bruce W.; Callaway, Robert (Technical Monitor)

    1995-01-01

    We consider an isolated bubble boiling regime in which vapour bubbles are intermittently produced at a prearranged set of nucleation site on an upward facing overheated wall plane. In this boiling regime, the bubbles depart from the wall and move as separate entities. Except in the matter of rise velocity, the bubbles do not interfere and are independent of one another. However, the rise velocity is dependent on bubble volume concentration in the bulk. Heat transfer properties specific to this regime cannot be described without bubble detachment size, and we apply our previously developed dynamic theory of vapour bubble growth and detachment to determine this size. Bubble growth is presumed to be thermally controlled. Two limiting cases of bubble evolution are considered: the one in which buoyancy prevails in promoting bubble detachment and the one in which surface tension prevails. We prove termination of the isolated regime of pool nucleate boiling to result from one of the four possible causes, depending on relevant parameters values. The first cause consists in the fact that the upward flow of rising bubbles hampers the downward liquid flow, and under certain conditions, prevents the liquid from coming to the wall in an amount that would be sufficient to compensate for vapour removal from the wall. The second cause is due to the lateral coalescence of growing bubbles that are attached to their corresponding nucleation sites, with ensuing generation of larger bubbles and extended vapour patches near the wall. The other two causes involve longitudinal coalescence either 1) immediately in the wall vicinity, accompanied by the establishment of the multiple bubble boiling regime, or 2) in the bulk, with the formation of vapour columns. The longitudinal coalescence in the bulk is shown to be the most important cause. The critical wall temperature and the heat flux density associated with isolated bubble regime termination are found to be functions of the physical and operating parameters and are discussed in detail.

  10. Visualizational study on nucleate pool boiling phenomena

    NASA Astrophysics Data System (ADS)

    Kamei, Shuya

    1993-01-01

    It is important to visualize the intricate bubble behavior and the strong agitation of liquid near the heating surface to clarify the details concerning boiling mechanism. The visualization of nucleate pool boiling phenomena was confirmed by means of shadowgraphy using a still- camera (Nikon Photomic Camera) with the speed of 2000 frames per second. Illumination was provided by a photo spotlight or a stroboscope. The photographs show that the boiling phenomena and bubbles' behavior are varied for the heat flux of nucleate pool boiling based on the experiments. By considering the effect of revolving angle and the influence of a space between a tube and a tube, experiments have been carried out to investigate the nucleate pool boiling phenomena on horizontal stainless-steel-multi-tube in saturated distilled water. These experiments were performed for atmospheric pressure, for a stainless-tube diameter of 1.0 mm for a length of 80 mm, for a region of natural convection to nucleate boiling near burnout. From these results, photographs show that the successive motion and shape of bubbles during their process of detachment on the heating tube surface varied with increasing heat flux.

  11. Visualization study on pool boiling heat transfer

    NASA Astrophysics Data System (ADS)

    Kamei, Shuya; Hirata, Masaru

    1991-04-01

    The visualized boiling phenomena were observed by means of high speed photographic shadowgraphy using a rotating prism camera (nac HIGH SPEED CAMERA model-16HD) with the speed of about 3500 frames per second. The photographs show that pool boiling heat transfer phenomena are varied for the boiling curve based on the experiments. Experiments have been carried out to investigate pool boiling heat transfer phenomena on a horizontal thin filament in subcooled and saturated distilled water. The experiments were performed for atmospheric pressure,for filament diameters of about 0.3 mm, for region of natural convection to film boiling. The color-film made by high speed movie camera are converted to high speed color video-tape. It is convenient to edit and show the tape for visualization with teaching the students. The high speed color video showed that the successive motion and shape of bubbles during their process of detachment varied with increasing heat flux on the heated surface of a filament. From these results, it was confirmed that the high speed phenomena of boiling by the slow motion video pictures could be estimated clearly.

  12. Heat and mass transfer in porous media phase separation at temperatures below the lambda-point of He-4

    NASA Technical Reports Server (NTRS)

    Yuan, S. W. K.; Frederking, T. H. K.

    1986-01-01

    Newtonian fluid motion, coupled to heat transfer via latent heat of phase transition, is well known from numerous studies of condensation and boiling. Considerably less knowledge is available for vapor-liquid phase separation in the absence of gravity effect on the transport phenomena. The present studies are focused on heat and mass transfer associated with vapor-liquid phase separation required for long-term storage of the cryogen liquid He II in space vessels. Though space conditions are the dominant mode of interest in advanced equipment, e.g. IR telescopes, the systems may be operated in principle during terrestrial conditions. The latter are considered in the present work. It emphasizes the linear regime including an extrapolation based on variable thermophysical properties. Data taken with a phase separation approach show departures from the linear regime prediction. They agree with a transport equation proposed for the nonlinear, turbulent regime.

  13. Flash Points of Secondary Alcohol and n-Alkane Mixtures.

    PubMed

    Esina, Zoya N; Miroshnikov, Alexander M; Korchuganova, Margarita R

    2015-11-19

    The flash point is one of the most important characteristics used to assess the ignition hazard of mixtures of flammable liquids. To determine the flash points of mixtures of secondary alcohols with n-alkanes, it is necessary to calculate the activity coefficients. In this paper, we use a model that allows us to obtain enthalpy of fusion and enthalpy of vaporization data of the pure components to calculate the liquid-solid equilibrium (LSE) and vapor-liquid equilibrium (VLE). Enthalpy of fusion and enthalpy of vaporization data of secondary alcohols in the literature are limited; thus, the prediction of these characteristics was performed using the method of thermodynamic similarity. Additionally, the empirical models provided the critical temperatures and boiling temperatures of the secondary alcohols. The modeled melting enthalpy and enthalpy of vaporization as well as the calculated LSE and VLE flash points were determined for the secondary alcohol and n-alkane mixtures. PMID:26491811

  14. Pool boiling of water on nano-structured micro wires at sub-atmospheric conditions

    NASA Astrophysics Data System (ADS)

    Arya, Mahendra; Khandekar, Sameer; Pratap, Dheeraj; Ramakrishna, S. Anantha

    2015-10-01

    Past decades have seen active research in enhancement of boiling heat transfer by surface modifications. Favorable surface modifications are expected to enhance boiling efficiency. Several interrelated mechanisms such as capillarity, surface energy alteration, wettability, cavity geometry, wetting transitions, geometrical features of surface morphology, etc., are responsible for change in the boiling behavior of modified surfaces. Not much work is available on pool boiling at low pressures on microscale/nanoscale geometries; low pressure boiling is attractive in many applications wherein low operating temperatures are desired for a particular working fluid. In this background, an experimental setup was designed and developed to investigate the pool boiling performance of water on (a) plain aluminum micro wire (99.999 % pure) and, (b) nano-porous alumina structured aluminum micro wire, both having diameter of 250 µm, under sub-atmospheric pressure. Nano-structuring on the plain wire surface was achieved via anodization. Two samples, A and B of anodized wires, differing by the degree of anodization were tested. The heater length scale (wire diameter) was much smaller than the capillary length scale. Pool boiling characteristics of water were investigated at three different sub-atmospheric pressures of 73, 123 and 199 mbar (corresponding to T sat = 40, 50 and 60 °C). First, the boiling characteristics of plain wire were measured. It was noticed that at sub-atmospheric pressures, boiling heat transfer performance for plain wire was quite low due to the increased bubble sizes and low nucleation site density. Subsequently, boiling performance of nano-structured wires (both Sample A and Sample B) was compared with plain wire and it was noted that boiling heat transfer for the former was considerably enhanced as compared to the plain wire. This enhancement is attributed to increased nucleation site density, change in wettability and possibly due to enhanced pore scale evaporation. A preliminary estimation of the bubble growth rates, measured by high speed videography, was undertaken and compared with classical bubble growth rate correlations. It was observed that the average bubble departure sizes on Sample B were larger as compared to plain wire, due to larger surface forces holding the bubble before departure. Bubble condensation in the thermal boundary layer was also captured.

  15. Design, Construction, and Qualification of a Microscale Heater Array for Use in Boiling Heat Transfer

    NASA Technical Reports Server (NTRS)

    Rule, T. D.; Kim, J.; Kalkur, T. S.

    1998-01-01

    Boiling heat transfer is an efficient means of heat transfer because a large amount of heat can be removed from a surface using a relatively small temperature difference between the surface and the bulk liquid. However, the mechanisms that govern boiling heat transfer are not well understood. Measurements of wall temperature and heat flux near the wall would add to the database of knowledge which is necessary to understand the mechanisms of nucleate boiling. A heater array has been developed which contains 96 heater elements within a 2.5 mm square area. The temperature of each heater element is held constant by an electronic control system similar to a hot-wire anemometer. The voltage that is being applied to each heater element can be measured and digitized using a high-speed A/D converter, and this digital information can be compiled into a series of heat-flux maps. Information for up to 10,000 heat flux maps can be obtained each second. The heater control system, the A/D system and the heater array construction are described in detail. Results are presented which show that this is an effective method of measuring the local heat flux during nucleate and transition boiling. Heat flux maps are obtained for pool boiling in FC-72 on a horizontal surface. Local heat flux variations are shown to be three to six times larger than variations in the spatially averaged heat flux.

  16. Characteristics of Pool Boiling on Graphite-Copper Composite Surfaces

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Yang, Wen-Jei

    2002-01-01

    Nucleate pool boiling performance of different liquids on graphite-copper composite (Gr-Cu) surfaces has been experimentally studied and modeled. Both highly wetting fluids, such as freon-113 and pentane, and a moderately wetting fluid (water) were tested on the Gr-Cu surfaces with different graphite-fiber volume fractions to reveal the enhancement effects of the composite surfaces on the nucleate pool boiling. Results of the experiments show that the graphite-fiber volume fraction has an optimum value. The Gr-Cu composite surface with 25 percent graphite-fiber volume (f=0.25) has a maximum enhancement effect on the nucleate boiling heat transfer comparing to the pure copper surface. For the highly wetting fluid, the nucleate boiling heat transfer is generally enhanced on the Gr- Cu composite surfaces by 3 to 6 times shown. In the low heat flux region, the enhancement is over 6 times, but in the high heat flux region, the enhancement is reduced to about 40%. For the moderately wetting fluid (water), stronger enhancement of nucleate boiling heat transfer is achieved on the composite surface. It shown the experimental results in which one observes the nucleate boiling heat transfer enhancement of 5 to 10 times in the low heat flux region and an enhancement of 3 to 5 times in the high heat flux region. Photographs of bubble departure during the initial stage of nucleate boiling indicate that the bubbles detached from the composite surface are much smaller in diameter than those detached from the pure copper surface. Typical photographs are presented.It shows that the bubbles departed from the composite surface have diameters of only O(0.1) mm, while those departed from the pure copper surface have diameters of O(1) mm. It is also found that the bubbles depart from the composite surface at a much higher frequency, thus forming vapor columns. These two phenomena combined with high thermal conductivity of the graphite fiber are considered the mechanisms for such a significant augmentation in nucleate boiling heat transfer on the composite surfaces. A physical model is developed to describe the phenomenon of bubble departure from the composite surface: The preferred site of bubble nucleation is the fiber tip because of higher tip temperature than the surrounding copper base and poor wettability of the graphite tip compared with that of the base material (copper). The high evaporation rate near the contact line produces the vapor cutback due to the vapor recoil pushing the three-phase line outwards from the fiber tip, and so a neck of the bubble is formed near the bubble bottom. Evaporation and surface tension accelerate the necking process and finally result in the bubble departure while a new small bubble is formed at the tip when the surface tension pushes the three-phase line back to the tip. The process is schematically shown. The proposed model is based on and confirmed by experimental results.

  17. Microgravity experiments on boiling behavior of self-wetting fluid

    NASA Astrophysics Data System (ADS)

    Abe, Y.; Iwasaki, A.

    Although most of fluids show a decrease in the surface tension with increasing temperature, some fluids show abnormal behavior- the surface tension increases with the increase in temperature. In the case of boiling phenomena, the thermocapillary flow due t o temperature gradient at the liquid/vapor interface should induce a liquid supply to a dry patch or hot spot developed under bubble. "Self- wetting" termed in this paper came from such a behavior of spontaneous liquid supply. Aqueous solutions of high carbon alcohols have been known as a fluid with such an abnormal surface tension behavior. In addition to the thermocapillary flow induced by temperature gradient, the Marangoni effect due to concentration gradient around liquid/vapor interface should occur, since the component of vapor phase is characterized to be either alcohol-rich or water-rich by preferential evaporation, as far as non-azeotropic components are concerned. In some components, the direction of thermocapillary flow is the same as the direction of the Marangoni flow induced by concentration gradient, which should even enhance the self-wettability. The present authors have carried out a series of microgravity experiments at JAMIC to observe the fundamental boiling behavior of self-wetting fluid (1-butanol aqueous solution, in the present study), and compared with CFC -113 and ethanol aqueous solution. The flow around adjacent dual bubbles and the flow under a single bubble are discussed.

  18. Cryogenic Boil-Off Reduction System

    NASA Astrophysics Data System (ADS)

    Plachta, David W.; Guzik, Monica C.

    2014-03-01

    A computational model of the cryogenic boil-off reduction system being developed by NASA as part of the Cryogenic Propellant Storage and Transfer technology maturation project has been applied to a range of propellant storage tanks sizes for high-performing in-space cryogenic propulsion applications. This effort focuses on the scaling of multi-layer insulation (MLI), cryocoolers, broad area cooling shields, radiators, solar arrays, and tanks for liquid hydrogen propellant storage tanks ranging from 2 to 10 m in diameter. Component scaling equations were incorporated into the Cryogenic Analysis Tool, a spreadsheet-based tool used to perform system-level parametric studies. The primary addition to the evolution of this updated tool is the integration of a scaling method for reverse turbo-Brayton cycle cryocoolers, as well as the development and inclusion of Self-Supporting Multi-Layer Insulation. Mass, power, and sizing relationships are traded parametrically to establish the appropriate loiter period beyond which this boil-off reduction system application reduces mass. The projected benefit compares passive thermal control to active thermal control, where active thermal control is evaluated for reduced boil-off with a 90 K shield, zero boil-off with a single heat interception stage at the tank wall, and zero boil-off with a second interception stage at a 90 K shield. Parametric studies show a benefit over passive storage at loiter durations under one month, in addition to showing a benefit for two-stage zero boil-off in terms of reducing power and mass as compared to single stage zero boil-off. Furthermore, active cooling reduces the effect of varied multi-layer insulation performance, which, historically, has been shown to be significant.

  19. Radiance temperatures (in the wavelength range 519 906 nm) of tungsten at its melting point by a pulse-heating technique

    NASA Astrophysics Data System (ADS)

    Miiller, A. P.; Cezairliyan, A.

    1993-05-01

    Radiance temperatures (at six wavelengths in the range 519 906 nm) of tungsten at its melting point were measured by a pulse-heating technique. The method is based on rapid resistive self-heating of the specimen from room temperature to its melting point in less than 1 s; and on simultaneously measuring the specimen radiance temperatures every 0.5 ms with a high-speed six-wavelength pyrometer. Melting was manifested by a plateau in the radiance temperature versus time function for each wavelength. The melting-point radiance temperatures for a given specimen were determined by averaging the measured temperatures along the plateau at each wavelength. The melting-point radiance temperatures for tungsten were determined by averaging the results at each wavelength for 10 specimens (standard deviation in the range 0.5 1.1 K, depending on the wavelength) as follows: 3319 K at 519 nm, 3236 K at 615 nm, 3207 K at 652 nm, 3157 K at 707 nm, 3078 K at 808 nm, and 2995 K at 906 nm. Based on estimates of the random and systematic errors arising from pyrometry and specimen conditions, the total uncertainty in the reported values is about ±7 K at 653 nm and ± 8 K at the other wavelengths.

  20. Enhancement of nucleate pool boiling heat transfer to dilute binary mixtures using endothermic chemical reactions around the smoothed horizontal cylinder

    NASA Astrophysics Data System (ADS)

    Sarafraz, M. M.; Peyghambarzadeh, S. M.; Alavifazel, S. A.

    2012-10-01

    Experimental studies on enhancing the pool boiling heat transfer coefficient of binary dilute mixtures of water/glycerol, water/MEG (Mono-ethylene glycol) and water/DEG (di-ethylene glycol) have been carried out. Some particular endothermic chemical reactions related to ammonium salts were used to enhance the pool boiling heat transfer coefficient, simultaneously with occurrence of pool boiling heat transfer. Accordingly, 100 g of Ammonium nitrate, ammonium perborate and Ammonium sulfate were selected to dissolve into mixtures. High and extreme solution enthalpies of each of these ammonium salt powders are employed to reduce the surface temperature around the horizontal cylinder locally. Results demonstrated that presence of ammonium salts into the mixtures deteriorates the surface temperature of cylinder and as the result, higher pool boiling heat transfer coefficient is reported for tested solutions. Results are also reported and compared for different ammonium salts to find the influence of inducing different enthalpies of solution on pool boiling heat transfer coefficient. Obtained results also indicated that presence of endothermic reaction besides the pool boiling heat transfer enhances the heat transfer coefficients in comparison with nucleate pool boiling phenomenon solely.

  1. Experimental and analytical study of a boiling collector in thermal siphon operation

    SciTech Connect

    Silva, M. da; Eugenia, M.

    1992-01-01

    The purpose of this study is to analytically and experimentally evaluate the performance of a boiling solar collector in thermal siphon operation so that, in future work, solar collectors can be optimized for boiling operation. A new procedure, based on boiling heat transfer fundamentals, is developed to estimate the rate of energy gain in the collector. The temperature of the absorber plate is determined from the simultaneous solution of the rate of energy absorbed by the collector and the rate of energy used in boiling as a function of vapor bubble density, the energy required for bubble formation, and the volumetric flow rate through the collector. Since the volumetric flow rate could not be predicted theoretically, experimentally estimated values are used in the numerical calculation. This model is an improvement over previous models which assume that the total mass flow rate that flows through the collector boils, when in reality just a small percent of this mass flow boils and most of it is recirculated. To validate the analytical model, the thermal efficiency and the absorber plate temperature of two collector-condenser systems are experimentally determined. Measurements with both a conventional sheet with tube and a waffled flat plate collector indicate the importance of collector geometry. The two-phase thermal siphon system operates at practically the same thermal efficiency as the hydronic single-phase system, but it uses one less pump, the net rate of useful energy transfer in the two-phase system is higher than in the single-phase system. When boiling collectors are designed for two-phase operation, they may out-perform hydronic collectors.

  2. Contaminant Recovery during In-Situ Boiling in Rock

    NASA Astrophysics Data System (ADS)

    Chen, F.; Liu, X.; Falta, R. W.; Murdoch, L. C.

    2009-12-01

    In-situ boiling may be an effective mechanism for removing contaminants from tight rock matrix where they would otherwise be all but inaccessible. Heating the matrix above the boiling temperature and then depressurizing will induce boiling that leads to large gas-phase pressure gradients and a steam stripping effect that can remove the contaminants from the matrix. Despite the promise of this process, it has not yet been demonstrated in the field or laboratory, and the controlling parameters and limits of the process are poorly understood. The objective of this project is to characterize mass transfer during boiling in saturated rock. We built an experimental apparatus to heat cores (5cmx30cm) of contaminated rock in a pressurized vessel. The core was sealed in Teflon tube with metal end caps and wrapped with a strip heater. Additional heaters were located in the end caps. Sensors were placed on the surface and embedded within the core to monitor the temperature. An insulation layer covered the strip heater to minimize the heat loss. A recent test was conducted using Berea sandstone (18 millidarcy) initially saturated with de-aired water and contaminated by injecting 200ml (about 2 pore volumes) containing 200mg/L of 1,2-dichloroethane (1,2-DCA), 10 mg/L of chlorobenzene (CB), and 195 mg/L sodium bromide (NaBr). The solution was circulated and both inlet and outlet concentrations were monitored. After the contaminant injection, both the inlet and outlet valves were closed and the core was heated at a constant power of 31.3 watts. Pressure and temperature increased for 3 hours until temperatures exceeded 100 C. A valve on the outlet tube was opened and steam flow started immediately and was routed through a condenser. Concentrations of chlorinated solvents in the outflow increased abruptly to between 6 and 10 times the input concentration. The concentrations decreased after a few 10s of ml were recovered, and at least 80 to 90 percent of the contaminant masses were recovered in less than half of a pore volume of water. Interestingly, bromide was essentially absent from the recovered water containing the chlorinated solvents. These observations indicate that contaminants were stripped by a continuous steam phase that developed in the pore space of the sandstone throughout the length of the core. Volatile compounds were effectively transported to the steam-filled channels while leaving the non-volatile ionic compounds behind in the remaining water. This is significant because experimentally demonstrating this steam stripping mechanism is the first step toward developing a technique for effectively recovering contaminants from the matrix of fractured rock.

  3. Results of the DF-4 BWR (boiling water reactor) control blade-channel box test

    SciTech Connect

    Gauntt, R.O.; Gasser, R.D.

    1990-10-01

    The DF-4 in-pile fuel damage experiment investigated the behavior of boiling water reactor (BWR) fuel canisters and control blades in the high temperature environment of an unrecovered reactor accident. This experiment, which was carried out in the Annular Core Research Reactor (ACRR) at Sandia National Laboratories, was performed under the USNRC's internationally sponsored severe fuel damage (SFD) program. The DF-4 test is described herein and results from the experiment are presented. Important findings from the DF-4 test include the low temperature melting of the stainless steel control blade caused by reaction with the B{sub 4}C, and the subsequent low temperature attack of the Zr-4 channel box by the relocating molten blade components. Hydrogen generation was found to continue throughout the experiment, diminishing slightly following the relocation of molten oxidizing zircaloy to the lower extreme of the test bundle. A large blockage which was formed from this material continued to oxidize while steam was being fed into the the test bundle. The results of this test have provided information on the initial stages of core melt progression in BWR geometry involving the heatup and cladding oxidation stages of a severe accident and terminating at the point of melting and relocation of the metallic core components. The information is useful in modeling melt progression in BWR core geometry, and provides engineering insight into the key phenomena controlling these processes. 12 refs., 12 figs.

  4. The effect of surface gas injection on film boiling heat transfer

    SciTech Connect

    Duignan, M.R. ); Greene, G.A. ); Irvine, T.F. Jr. )

    1991-01-01

    A database was developed for heat transfer from a horizontal plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. At the highest superficial gas velocity measured, approximately 8.5 cm/s, and for a constant surface temperature, the heat transfer increases by a factor of two over the heat transfer with no enhancement by gas flux. Further, as the superficial gas velocity approached zero, the data approach the stable film boiling asymptote. A semi-empirical model was developed and correlated to the database. The result is an equation which represents better than 90% of all the measured data within {plus minus}15% bounds.

  5. The effect of surface gas injection on film boiling heat transfer

    SciTech Connect

    Duignan, M.R.; Greene, G.A.; Irvine, T.F. Jr.

    1991-12-31

    A database was developed for heat transfer from a horizontal plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. At the highest superficial gas velocity measured, approximately 8.5 cm/s, and for a constant surface temperature, the heat transfer increases by a factor of two over the heat transfer with no enhancement by gas flux. Further, as the superficial gas velocity approached zero, the data approach the stable film boiling asymptote. A semi-empirical model was developed and correlated to the database. The result is an equation which represents better than 90% of all the measured data within {plus_minus}15% bounds.

  6. Cautions required for the boiling test of a silver-water nanofluid

    NASA Astrophysics Data System (ADS)

    Zareshahi, Hassan; Emami-Meibodi, Majid; Behjat, Abbas

    2016-03-01

    Various experimental works have been reported on boiling of nanofluids, and some contradictory data are reported in this case in the literature. Systematic errors in experiments may be one of the factors causing a significant gap in the data. In this paper, boiling of Ag-water nanofluid is studied empirically. A NiCr wire is used for the experiments. According to UV-Vis absorption spectra data, Ag-water nanofluid changes during the tests. Since the electrical resistance-temperature relationship for the NiCr test section changes during the experiments, the wire temperature cannot be determined by this method. This can be accounted for by the presence of a porous nanoparticle layer created through particle deposition during nucleate boiling.

  7. Boiling-up of superheated water and water solutions under ultrasound influence

    NASA Astrophysics Data System (ADS)

    Perminov, S. A.; Ermakov, G. V.

    2010-03-01

    Boiling-up kinetics of superheated distilled water and sodium chloride solution in a glass cell at atmospheric pressure and low superheating of 15-35 °C has been studied far from the boundary of attainable superheating in the area of heterogeneous nucleation. Temperature dependences of average waiting time of superheated liquids boiling-up have been studied experimentally under natural conditions and in the ultrasonic field Waiting time of boiling-up at these temperatures reaches 1000 s, and average time is 600 s. Empirical distribution functions have been found with the use of the waiting time samples obtained by the method of order statistics. Omega-square goodness-of-fit test has shown that they disagree with exponential distribution describing stationary random process of supercritical embryo generation separating the system to macroscopic phases. Thus, it is shown that this random process is not stationary, consequently, nucleation rate to be depending on time.

  8. Facilitating Students' Conceptual Understanding of Boiling Using a Four-Step Constructivist Teaching Method

    ERIC Educational Resources Information Center

    Calik, Muammer

    2008-01-01

    The aim of the work presented here was to devise an activity associated with factors affecting boiling points. The intervention used a four-step constructivist-based teaching strategy, which was subsequently evaluated by a cohort of students. Data collection consisted of application of a purpose designed questionnaire consisting of four open-ended

  9. Effects of boiling on electrical resistivity of microporous rocks from the Geysers

    SciTech Connect

    Roberts, J.; Duba, A.; Bonner, B.; Kasameyer, P.

    1997-12-31

    In a laboratory study of cores from borehole SB-15-D in The Geysers geothermal area, we measured the electrical resistivity of metashale with and without pore-pressure control, with confining pressures up to 100 bars and temperatures between 20 and 150{degrees}C, to determine how the pore-size distribution and capillarity affected boiling. We observed a gradual increase in resistivity when the downstream pore pressure or confining pressure decreased below the phase boundary of free water. For the conditions of this experiment, boiling, as indicated by an increase in resistivity, is initiated at pore pressures of approximately 0.5 to 1 bar (0.05 to 0.1 MPa) below the free-water boiling curve, and it continues to increase gradually as pressure is lowered to atmospheric. A simple model of the effects of capillarity suggests that at 145{degrees}C, less than 15% of the pore water can boil in these rocks. If subsequent experiments bear out these preliminary observations, then boiling within a geothermal reservoir is controlled not just by pressure and temperature but also by pore-size distribution. Thus, it may be possible to determine reservoir characteristics by monitoring changes in electrical resistivity as reservoir conditions change.

  10. The influence of oil on nucleate pool boiling heat transfer

    NASA Astrophysics Data System (ADS)

    Spindler, Klaus; Hahne, Erich

    2009-05-01

    The influence of various oil contents in R134a is investigated for nucleate pool boiling on copper tubes either sandblasted or with enhanced heating surfaces (GEWA-B tube). Polyolester oils (POE) (Reniso Triton) with medium viscosity 55 cSt (SE55) and high viscosity 170 cSt (SE170) were used. Heat transfer coefficients were obtained for boiling temperatures between -28.6 and +20.1°C. The oil content varied from 0 to 5% mass fraction. For the sandblasted tube and the SE55 oil the heat transfer coefficients for the refrigerant/oil-mixture can be higher or lower than those for the pure refrigerant, depending on oil mass fraction, boiling temperature and heat flux. In some cases the highest heat transfer coefficients were obtained at a mass fraction of 3%. For the 170 cSt oil there is a clear decrease in heat transfer for all variations except for a heat flux 4,000 W/m2 and -10.1°C at 0.5% oil content. The heat transfer coefficients are compared to those in the literature for a smooth stainless steel tube and a platinum wire. For the enhanced tube and 55 cSt oil the heat transfer coefficients are clearly below those for pure refrigerant in all cases. The experimental results for the sandblasted tube are compared with the correlation by Jensen and Jackman. The calculated values are within +20 and -40% for the medium viscosity oil and between +50% and -40% for the high viscosity oil. A correlation for predicting oil-degradation effects on enhanced surfaces does not exist.

  11. Flow Boiling Heat Transfer to Lithium Bromide Aqueous Solution in Subcooled Region

    NASA Astrophysics Data System (ADS)

    Kaji, Masao; Furukawa, Masahiro; Nishizumi, Takeharu; Ozaki, Shinji; Sekoguchi, Kotohiko

    A theoretical prediction model of the boiling heat transfer coefficient in the subcooled region for water and lithium bromide aqueous solution flowing in a rectangular channel is proposed. In the present heat transfer model, a heat flux is assumed to consist of both the forced convective and the boiling effect components. The forced convective component is evaluated from the empirical correlation of convective heat transfer coefficient for single-phase flow considering the effect of increase of liquid velocity due to net vapor generation. Empirical correlations for determining the heat flux due to the boiling effect and the quality at the onset point of net vapor generation are obtained from the data presented in the first report1). Agreement between the present theoretical prediction and the experimental data is satisfactorily good both for water and lithium bromide aqueous solution.

  12. Determination of optimum curie point as a function of source and sink temperatures for magnetic heat pumps

    SciTech Connect

    Van Haaften, D.H.; Mills, J.I.

    1984-08-01

    Magnetic heat pump cycles are being investigated to determine their feasibility in industrial applications. This analysis has noted significant improvements in the performance of these cycles when the magnetic refrigerant's Curie temperature is 5 to 15 K above the average of the sink and load temperatures. When the magnetic cycle's operating temperatures are carefully matched with the magnetic core material's Curie temperature, cycle performance can approach Carnot efficiencies.

  13. Design and test of a compact optics system for the pool boiling experiment

    NASA Technical Reports Server (NTRS)

    Ling, Jerri S.; Laubenthal, James R.

    1990-01-01

    The experiment described seeks to improve the understanding of the fundamental mechanisms that constitute nucleate pool boiling. The vehicle for accomplishing this is an investigation, including tests to be conducted in microgravity and coupled with appropriate analyses, of the heat transfer and vapor bubble dynamics associated with nucleation, bubble growth/collapse and subsequent motion, considering the interrelations between buoyancy, momentum and surface tension which will govern the motion of the vapor and surrounding liquid, as a function of the heating rate at the heat transfer surface and the temperature level and distribution in the bulk liquid. The experiment is designed to be contained within the confines of a Get-Away-Special Canister (GAS Can) installed in the bay of the space shuttle. When the shuttle reaches orbit, the experiment will be turned on and testing will proceed automatically. In the proposed Pool Boiling Experiment a pool of liquid, initially at a precisely defined pressure and temperature, will be subjected to a step imposed heat flux from a semitransparent thin-film heater forming part of one wall of the container such that boiling is initiated and maintained for a defined period of time at a constant pressure level. Transient measurements of the heater surface and fluid temperatures near the surface will be made, noting especially the conditions at the onset of boiling, along with motion photography of the boiling process in two simultaneous views, from beneath the heating surface and from the side. The conduct of the experiment and the data acquisition will be completely automated and self-contained. For the initial flight, a total of nine tests are proposed, with three levels of heat flux and three levels of subcooling. The design process used in the development and check-out of the compact photographic/optics system for the Pool Boiling Experiment is documented.

  14. Enhanced Boiling on Micro-Configured Composite Surfaces Under Microgravity Conditions

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chai, An-Ti

    1999-01-01

    In order to accommodate the growing thermal management needs of future space platforms, several two-phase active thermal control systems (ATCSs) have evolved and were included in the designs of space stations. Compared to the pumped single-phase liquid loops used in the conventional Space Transportation System and Spacelab, ATCSs offer significant benefits that may be realized by adopting a two-phase fluid-loop system. Alternately, dynamic power systems (DPSs), based on the Rankine cycle, seem inevitably to be required to supply the electrical power requirements of expanding space activities. Boiling heat transfer is one of the key technologies for both ATCSs and DPSs. Nucleate boiling near critical heat flux (CHF) can transport very large thermal loads with much smaller device size and much lower pumping power. However, boiling performance deteriorates in a reduced gravity environment and operation in the CHF regime is precarious because any slight overload will cause the heat transfer to suddenly move to the film boiling regime, which in turn, will result in burnout of the heat transfer surfaces. New materials, such as micro-configured metal-graphite composites, can provide a solution for boiling enhancement. It has been shown experimentally that this type of material manifests outstanding boiling heat transfer performance and their CHF is also extended to higher values. Due to the high thermal conductivity of graphite fiber (up to 1,200 W/m-K in the fiber direction), the composite surfaces are non-isothermal during the boiling process. The composite surfaces are believed to have a much wider safe operating region (a more uniform boiling curve in the CHF regime) because non-isothermal surfaces have been found to be less sensitive to variations of wall superheat in the CHF regime. The thermocapillary forces formed by the temperature difference between the fiber tips and the metal matrix play a more important role than the buoyancy in the bubble detachment, for the bubble detachment manifests itself by a necking process which should not be weakened by reduced gravity. In addition, the composite surfaces introduce no extra pressure drop, no fouling and do not impose significant primary or maintenance costs. All of these suggest that this type of composite is an ideal material for the challenge of accounting for both reliability and economy of the relevant components applied in the ATCSs, the DPSs and other devices in future space missions. The aim of the proposed work is to experimentally investigate high nucleate pool boiling performance on a micro-configured metal-graphite composite surface and to determine the mechanisms of the nucleate boiling heat transfer both experimentally and theoretically. Freon-113 and water will be used as the test liquids to investigate wettability effects on boiling characteristics. The Cu-Gr and Al-Gr composites with various volume fractions of graphite fibers will be tested to obtain the heat transfer characteristic data in the nucleate boiling region and in the CHF regime. In the experiments, the bubble emission and coalescence processes will be recorded by a video camera with a magnifying borescope probe immersed in the working fluid. The temperature profile in the thermal boundary layer on the composite surfaces will be measured by a group of micro thermocouples consisting of four ultra fine micro thermocouples. This instrument was developed and successfully used to measure the temperature profile of evaporating liquid thin layers by the proposers in a study performed at the NASA/Lewis Research Center. A two tier model to explain the nucleate boiling process and the performance enhancement on the composite surfaces has been suggested by the authors. According to the model, the thicknesses of the microlayer and the macrolayer underneath the bubbles and mushrooms, can be estimated by the geometry of the composite surface. The experimental results will be compared to the predictions from the model, and in turn, to revise and improve it.

  15. Marangoni effects on near-bubble microscale transport during boiling of binary fluid mixtures

    NASA Astrophysics Data System (ADS)

    Sun, Chen-Li

    In this study, boiling experiments of 2-propanol/water mixtures in confined gap geometry under various levels of gravity were conducted to examine the Marangoni effects on near-bubble microscale transport. Full boiling curves were obtained and two boiling regimes---nucleate boiling and pseudo film boiling, and the transition condition, critical heat flux, identified. In the nucleate boiling regime, small bubbles were generated, condensed quickly in the bulk liquid, so that the agitation in the system resulted in great heat transfer performance. As the superheat level increased, the bubbles coalesced to a large vapor slug that was constrained by the gap geometry and started to blanket the heated surface. The maximum heat flux, (i.e. the critical heat flux, CHF), was then reached. The pseudo film boiling regime was reached by further increasing the superheat level, creating a slow, fluctuated bubble where boiling only occurred at its base perimeter because the heated surface was dried out. The temperature field created within the parallel plate gap resulted in evaporation over the portion of the vapor-liquid interface of the bubble near the heated surface, and condensation near the cold surface. This scenario produced a heat pipe effect inside the constrained bubble. For positive mixtures, Marangoni forces were proven to greatly enhance heat transfer under reduced and terrestrial gravity when compared with the boiling of distilled water. However, the presence of the gap geometry caused a premature occurrence of CHF conditions, and deteriorated heat transfer at high superheated temperatures. The influence of the confined space was particularly significant when greater Marangoni forces were presented under reduced gravity conditions. It caused the value of the CHF for x = 0.025, which corresponded to weaker Marangoni forces, to be greater than that of x = 0.015 with a 6.35 mm gap. This demonstrates the complex interaction that these three factors---Marangoni effects, gravity level, and gap size---have on heat transfer. A major contribution of this study is that it provides a parametric database, further expanding the knowledge in the field of heat transfer to make more optimal use of coolant composed of binary mixtures in various thermal applications.

  16. Steady state boiling crisis in a helium vertically heated natural circulation loop - Part 1: Critical heat flux, boiling crisis onset and hysteresis

    NASA Astrophysics Data System (ADS)

    Furci, H.; Baudouy, B.; Four, A.; Meuris, C.

    2016-01-01

    Experiments were conducted on a 2-m high two-phase helium natural circulation loop operating at 4.2 K and 1 atm. The same loop was used in two experiments with different heated section internal diameter (10 and 6 mm). The power applied on the heated section wall was controlled in increasing and decreasing sequences, and temperature along the section, mass flow rate and pressure drop evolutions were recorded. The values of critical heat flux (CHF) were found at different positions of the test section, and the post-CHF regime was studied. The predictions of CHF by existing correlations were good in the downstream portion of the section, however CHF anomalies have been observed near the entrance, in the low quality region. In resonance with this, the re-wetting of the surface has distinct hysteresis behavior in each of the two CHF regions. Furthermore, hydraulics effects of crisis, namely on friction, were studied (Part 2). This research is the starting point to future works addressing transients conducing to boiling crisis in helium natural circulation loops.

  17. A depletable micro-layer model for nucleate pool boiling

    NASA Astrophysics Data System (ADS)

    Sato, Yohei; Niceno, Bojan

    2015-11-01

    A depletable micro-layer model has been developed for the simulation of nucleate pool boiling within the framework of Computational Fluid Dynamics (CFD) modeling using an interface-tracking method. A micro-layer model is required for the CFD simulation to take into account vaporization from the thin liquid film - called the micro-layer - existing beneath a growing vapor bubble on a hot surface. In our model, the thickness of the micro-layer is a variable defined at each discretized fluid cell adjacent to the heat-transfer surface; the layer decreases due to vaporization, and can finally disappear. Compared to existing micro-region models, most of them based on the concept of contact-line evaporation, as originally proposed by Stephan and Busse, and by Lay and Dhir, our model incorporates simplified modeling ideas, but can nonetheless predict the temperature field beneath the growing bubble accurately. The model proposed in this paper has been validated against measurements of pool boiling in water at atmospheric pressure. Specifically, the bubble principal dimensions and the temperature distribution over the heat-transfer surface are in good agreement with experimental data.

  18. Maximum power point search method for photovoltaic panels which uses a light sensor in the conditions of real shading and temperature

    NASA Astrophysics Data System (ADS)

    Mroczka, Janusz; Ostrowski, Mariusz

    2015-06-01

    Disadvantages of photovoltaic panels are their low efficiency and non-linear current-voltage characteristic. Therefore it is necessary to apply the maximum power tracking systems which are dependent on the sun exposure and temperature. Trackers, that are used in photovoltaic systems, differ from each other in the speed and accuracy of tracking. Typically, in order to determine the maximum power point, trackers use measure of current and voltage. The perturb and observe algorithm or the incremental conductance method are frequent in the literature. The drawback of these solutions is the need to search the entire current-voltage curve, resulting in a significant loss of power in the fast-changing lighting conditions. Modern solutions use an additional measurement of temperature, short-circuit current or open circuit voltage in order to determine the starting point of one of the above methods, what decreases the tracking time. For this paper, a sequence of simulations and tests in real shading and temperature conditions for the investigated method, which uses additional light sensor to increase the speed of the perturb and observe algorithm in fast-changing illumination conditions was performed. Due to the non-linearity of the light sensor and the photovoltaic panel and the influence of temperature on the used sensor and panel characteristics, we cannot directly determine the relationship between them. For this reason, the tested method is divided into two steps. In the first step algorithm uses the correlation curve of the light sensor and current at the maximum power point and determines the current starting point with respect of which the perturb and observe algorithm is run. When the maximum power point is reached, in a second step, the difference between the starting point and the actual maximum power point is calculated and on this basis the coefficients of correlation curve are modified.

  19. An Investigation of Graduate Scientists' Understandings of Evaporation and Boiling.

    ERIC Educational Resources Information Center

    Goodwin, Alan; Orlik, Yuri

    2000-01-01

    Uses a video presentation of six situations relating to the evaporation and boiling of liquids and the escape of dissolved gases from solution and investigates graduate scientists' understanding of the concepts of boiling and evaporation. (Author/YDS)

  20. Magnetic resonance imaging of boiling induced by high intensity focused ultrasound

    PubMed Central

    Khokhlova, Tatiana D.; Canney, Michael S.; Lee, Donghoon; Marro, Kenneth I.; Crum, Lawrence A.; Khokhlova, Vera A.; Bailey, Michael R.

    2009-01-01

    Both mechanically induced acoustic cavitation and thermally induced boiling can occur during high intensity focused ultrasound (HIFU) medical therapy. The goal was to monitor the temperature as boiling was approached using magnetic resonance imaging (MRI). Tissue phantoms were heated for 20 s in a 4.7-T magnet using a 2-MHz HIFU source with an aperture and radius of curvature of 44 mm. The peak focal pressure was 27.5 MPa with corresponding beam width of 0.5 mm. The temperature measured in a single MRI voxel by water proton resonance frequency shift attained a maximum value of only 73 °C after 7 s of continuous HIFU exposure when boiling started. Boiling was detected by visual observation, by appearance on the MR images, and by a marked change in the HIFU source power. Nonlinear modeling of the acoustic field combined with a heat transfer equation predicted 100 °C after 7 s of exposure. Averaging of the calculated temperature field over the volume of the MRI voxel (0.3×0.5×2 mm3) yielded a maximum of 73 °C that agreed with the MR thermometry measurement. These results have implications for the use of MRI-determined temperature values to guide treatments with clinical HIFU systems. PMID:19354416

  1. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  2. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  3. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  4. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  5. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... atmospheric pressure. Continuous gas detection must be installed to detect leaks in the ventilated space. The... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel... must be a double-walled piping system with the annular space containing an inert gas at a...

  6. Mechanistic models for pool nucleate boiling heat transfer: input and validation

    NASA Astrophysics Data System (ADS)

    Kenning, David; Golobič, Iztok; Xing, Huijuan; Bašelj, Matej; Lojk, Vito; Hardenberg, Jost Von

    2006-04-01

    Correlations for nucleate boiling heat transfer should be improved, or in the long term possibly be replaced, by the development of mechanistic simulations that include the non-uniform spacing and variable characteristics of the nucleation sites and non-linear interactions between the sites. This paper discusses the interactions that should be included in simulations and some lessons from a first attempt to validate a particular simulation against experimental spatio-temporal data for wall temperature. Input data for nucleation site positions and characteristics are a particular problem and the prospects for obtaining this data from measurements that are independent of boiling are discussed.

  7. Nucleate pool boiling: High gravity to reduced gravity; liquid metals to cryogens

    NASA Technical Reports Server (NTRS)

    Merte, Herman, Jr.

    1988-01-01

    Requirements for the proper functioning of equipment and personnel in reduced gravity associated with space platforms and future space station modules introduce unique problems in temperature control; power generation; energy dissipation; the storage, transfer, control and conditioning of fluids; and liquid-vapor separation. The phase change of boiling is significant in all of these. Although both pool and flow boiling would be involved, research results to date include only pool boiling because buoyancy effects are maximized for this case. The effective application of forced convection boiling heat transfer in the microgravity of space will require a well grounded and cogent understanding of the mechanisms involved. Experimental results are presented for pool boiling from a single geometrical configuration, a flat surface, covering a wide range of body forces from a/g = 20 to 1 to a/g = 0 to -1 for a cryogenic liquid, and from a/g = 20 to 1 for water and a liquid metal. Similarities in behavior are noted for these three fluids at the higher gravity levels, and may reasonably be expected to continue at reduced gravity levels.

  8. Pool boiling heat transfer of deionized and degassed water in packed-perforated copper beads

    NASA Astrophysics Data System (ADS)

    Wen, Mao-Yu; Jang, Kuang-Jang; Ho, Ching-Yen

    2016-01-01

    Nucleate pool boiling with porous media made of perforated copper beads as the enhanced structure is conducted in saturated, deionized and degassed water. Data are taken at an atmospheric pressure (saturation temperature of 100 °C) and at heat fluxes from 4500 to 72,300 W/m2 while increasing the heat flux. The bead-packed structure is heated on the bottom. The layer of loose particles on the heated surface is free to move under the action of bulk liquid convection and vapor nucleation. The effects of the weight (number), size and layers of the free particles are experimentally explored using copper particles for different copper bead diameters which were 2, 3, 4 and 5 mm. The boiling enhancement is closely related to the particle weight, size and layers, and the heat flux applied. The results show that free particles are presented to have a distinct advantage in boiling heat transfer, resulting in an average increase in the heat transfer coefficient of 126 % relative to the flat plate without particles. In order to obtain insight into the fluid boiling phenomena, flow visualization is also made to observe the detailed fluid boiling characteristics of the copper particles present. The visualizations show that bubble nucleation preferentially occurs at the narrow corner cavities formed between the free particles and the heated surface.

  9. Electrohydrodynamic Pool Boiling in Reduced Gravity

    NASA Technical Reports Server (NTRS)

    Shaw, Benjamin D.; Stahl, S. L.

    1996-01-01

    This research is concerned with studying the effects of applied electric fields on pool boiling in a reduced-gravity environment. Experiments are conducted at the NASA Lewis 2.2 sec Drop tower using a drop rig constructed at UC Davis. In the experiments, a platinum wire is heated while immersed in saturated liquid refrigerants (FC-72 and FC-87), or water, causing vapor formation at the wire surface. Electric fields are applied between the wire surface and an outer screen electrode that surrounds the wire. Preliminary normal-gravity experiments with water have demonstrated that applied electric fields generated by the rig electronics can influence boiling characteristics. Reduced-gravity experiments will be performed in the summer of 1996. The experiments will provide fundamental data on electric field strengths required to disrupt film boiling (for various wire heat generation input rates) in reduced gravity for a cylindrical geometry. The experiments should also shed light on the roles of characteristic bubble generation times and charge relaxation times in determining the effects of electric fields on pool boiling. Normal-gravity comparison experiments will also be performed.

  10. The Plausibility of Boiling Geysers on Triton

    NASA Technical Reports Server (NTRS)

    Duxbury, N. S.; Brown, R. H.

    1995-01-01

    A mechanism is suggested and modeled whereby there may be boiling geysers on Triton. The geysers would be of nitrogen considering that Voyager detected cryovolcanic activity, that solid nitrogen conducts heat much less than water ice, and that there is internal heat on Triton.

  11. Big Bubbles in Boiling Liquids: Students' Views

    ERIC Educational Resources Information Center

    Costu, Bayram

    2008-01-01

    The aim of this study was to elicit students' conceptions about big bubbles in boiling liquids (water, ethanol and aqueous CuSO[subscript 4] solution). The study is based on twenty-four students at different ages and grades. The clinical interviews technique was conducted to solicit students' conceptions and the interviews were analyzed to…

  12. Classic and Hard-Boiled Detective Fiction.

    ERIC Educational Resources Information Center

    Reilly, John M.

    Through an analysis of several stories, this paper defines the similarities and differences between classic and hard-boiled detective fiction. The characters and plots of three stories are discussed: "The Red House" by A. A. Milne; "I, The Jury" by Mickey Spillane; and "League of Frightened Men" by Rex Stout. The classic detective story is defined…

  13. A new regime of nucleate boiling in microsphere mesostructures: Jumping pool boiling

    NASA Astrophysics Data System (ADS)

    Dmitriev, A. S.; Makarov, P. G.; El Bouz, M. A.

    2015-03-01

    We have studied a new regime of nucleate boiling in distilled water on substrates representing mesostructures of monodisperse and/or polydisperse microspheres made of various materials. It is experimentally established that, under some conditions of nucleate boiling, there appear "jumping pool boiling" regimes in which bubbles do not reach the surface of underheated liquid. In addition, bubbles may capture a certain number of microspheres, lift them up to some height, and then sink together down to the vessel bottom. Alternatively, microspheres may trap a certain number of bubbles, float up toward the evaporating surface, and then (without reaching the surface) sink back to the bottom layer where the nucleate bubbling takes place. Subregimes of this boiling mechanism involving microspheres of various densities and dimensions have also been observed.

  14. A comparison of the NPL and LNE-Cnam silver and copper fixed-point blackbody sources, and measurement of the silver/copper temperature interval

    NASA Astrophysics Data System (ADS)

    McEvoy, H. C.; Sadli, M.; Bourson, F.; Briaudeau, S.; Rougié, B.

    2013-12-01

    The silver and copper fixed-point blackbody sources of NPL were directly compared with those of LNE-Cnam using an IKE LP3 and an IKE LP5 at three wavelengths (650 nm, 795 nm and 903 nm). The two silver fixed points and the two copper fixed points were in excellent agreement with each other, with a difference of 11 mK for the silver and within 16 mK for the copper, with an expanded measurement uncertainty of between 10 mK and 20 mK depending on the pyrometer used. The temperature interval between the silver and copper freezing points was also measured using combinations of all four fixed points. The results with the NPL LP3 gave a value for the silver-copper temperature interval of 122.89 °C with an expanded uncertainty of 30 mK those with the LNE-Cnam LP5 gave a temperature interval of 122.87 °C also with an expanded uncertainty of 30 mK this compares with the ITS-90 value of 122.84 °C.

  15. Flow boiling with enhancement devices for cold plate coolant channel design

    NASA Technical Reports Server (NTRS)

    Boyd, Ronald D.

    1991-01-01

    Future space exploration and commercialization will require more efficient heat rejection systems. For the required heat transfer rates, such systems must use advanced heat transfer techniques. Forced two phase flow boiling heat transfer with enhancements falls in this category. However, moderate to high quality two phase systems tend to require higher pressure losses. This report is divided into two major parts: (1) Multidimensional wall temperature measurement and heat transfer enhancement for top heated horizontal channels with flow boiling; and (2) Improved analytical heat transfer data reduction for a single side heated coolant channel. Part 1 summarizes over forty experiments which involve both single phase convection and flow boiling in a horizontal channel heated externally from the top side. Part 2 contains parametric dimensionless curves with parameters such as the coolant channel radius ratio, the Biot number, and the circumferential coordinate.

  16. Impact of boiling conditions on the molecular and sensory profile of a vegetable broth.

    PubMed

    Mougin, Alice; Mauroux, Olivier; Matthey-Doret, Walter; Barcos, Eugenia Maria; Beaud, Fernand; Bousbaine, Ahmed; Viton, Florian; Smarrito-Menozzi, Candice

    2015-02-11

    Low-pressure cooking has recently been identified as an alternative to ambient and high-pressure cooking to provide food with enhanced organoleptic properties. This work investigates the impact of the cooking process at different pressures on the molecular and sensory profile of a vegetable broth. Experimental results showed similar sensory and chemical profiles of vegetable broths when boiling at 0.93 and 1.5 bar, while an enhancement of sulfur volatile compounds correlated with a greater leek content and savory aroma was observed when boiling at low pressure (80 C/0.48 bar). Thus, low-pressure cooking would allow preserving the most labile volatiles likely due to the lower water boiling temperature and the reduced level of oxygen. This study evidenced chemical and sensory impact of pressure during cooking and demonstrated that the flavor profile of culinary preparations can be enhanced by applying low-pressure conditions. PMID:25579390

  17. Thermal Design of Vapor Cooling of Flight Vehicle Structures Using LH2 Boil-Off

    NASA Technical Reports Server (NTRS)

    Wang, Xiao-Yen; Zoeckler, Joseph

    2015-01-01

    Using hydrogen boil-off vapor to cool the structure of a flight vehicle cryogenic upper stage can reduce heat loads to the stage and increase the usable propellant in the stage or extend the life of the stage. The hydrogen vapor can be used to absorb incoming heat as it increases in temperature before being vented overboard. In theory, the amount of heat leaking into the hydrogen tank from the structure will be reduced if the structure is cooled using the propellant boil-off vapor. However, the amount of boil-off vapor available to be used for cooling and the reduction in heat leak to the propellant tank are dependent to each other. The amount of heat leak reduction to the LH2 tank also depends on the total heat load on the stage and the vapor cooling configurations.

  18. Boiling sand springs, Dismal River, Nebraska: Agents for formation of vertical cylindrical structures and geomorphic change

    SciTech Connect

    Pederson, D.T. ); Guhman, A.I.

    1992-01-01

    Boiling (motion, not temperature) sand springs fed by ground water moving upward along distinct conduits occur along the Dismal River in the Nebraska Sand Hills. The cylindrical conduits are developed in alluvium and are as large as 10 m in diameter and 44 m deep. Sides of the spring conduits are firm. Boiling sand is overlain in several places by a clear layer of water in the spring. Time-varying wave patterns and boils can be observed along the interface between these layers. Sediment within the conduits is generally well sorted, although some debris is present. Because of their large size, firm sides, and persistence in time, the conduits have the potential for preservation as vertical cylindrical structures comparable to those reported in sedimentary rocks of several ages. The discovery of preserved structures is evidence of paleo-ground-water discharge, and therefore the structures are a useful mapping tool for determining position in landscape evolution.

  19. 21 CFR 872.6710 - Boiling water sterilizer.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Boiling water sterilizer. 872.6710 Section 872.6710 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is...

  20. A review of the deformation behavior of tungsten at temperatures less than 0.2 of the melting point /K/

    NASA Technical Reports Server (NTRS)

    Stephens, J. R.

    1974-01-01

    The deformation behavior of tungsten at temperatures below 0.2 times the absolute melting temperature is reviewed with primary emphasis on the temperature dependence of the yield stress and the ductile-brittle transition. It is concluded that a model based on the high Peierls stress of tungsten best accounts for the observed mechanical behavior at low temperatures. Recent research suggests an important role of electron concentration and bonding on the mechanical behavior of tungsten. Future research on tungsten should include studies to define more clearly the correlation between electron concentration and mechanical behavior of alloys of tungsten and other transition metal alloys.

  1. Muscle temperature at the point of filleting-Subsequent effect on storage quality of prerigor filleted raw- and cold-smoked Atlantic salmon.

    PubMed

    Lerfall, Jørgen; Rotabakk, Bjørn Tore

    2016-03-01

    The impact of increased muscle temperature at the point of filleting on fillet quality of raw- and cold-smoked Atlantic salmon was investigated. Commercially reared fish (5.65 kg, Kf: 1.23, pH: 7.29, muscle temperature: 6.68 ℃) were killed and immediately tempered in three different containers. Muscle temperatures after filleting (<3 h postmortem) of the three groups were 2.08 ℃ (hereafter named T-2); 9.07 ℃ (hereafter named T-9), and 14.09 ℃ (hereafter named T-14), respectively. The pH after filleting was significantly low for T-14 (6.93) followed by T-9 (7.06) and T-2 (7.22). Raised temperature at point of filleting was found to significantly alter development of rigor mortis, which subsequently affected muscle pH and the reflective properties of the fillet surface during 14 days' ice storage. Of cold-smoked fillets, however, a more distinct effect of raised temperature was observed on visual perception resulting in lighter and more yellowish cold-smoked fillets after 14 days' storage. In addition, raised temperature also affects the development of muscle pH in cold-smoked fillets during refrigerated storage. No effects of raised muscle temperature were found regarding drip loss, water-holding capacity, or fillet firmness either for raw- or cold-smoked fillets throughout the storage period. PMID:25791090

  2. Boil-off experiments with the EIR-NEPTUN Facility: Analysis and code assessment overview report

    SciTech Connect

    Aksan, S.N.; Stierli, F.; Analytis, G.T.

    1992-03-01

    The NEPTUN data discussed in this report are from core uncovery (boil-off) experiments designed to investigate the mixture level decrease and the heat up of the fuel rod simulators above the mixture level for conditions simulating core boil-off for a nuclear reactor under small break loss-of-coolant accident conditions. The first series of experiments performed in the NEPTUN test facility consisted of ten boil-off (uncovery) and one adiabatic heat-up tests. In these tests three parameters were varied: rod power, system pressure and initial coolant subcooling. The NEPTUN experiments showed that the external surface thermocouples do not cause a significant cooling influence in the rods to which they are attached under boil-off conditions. The reflooding tests performed later on indicated that the external surface thermocouples have some effect during reflooding for NEPTUN electrically heated rod bundle. Peak cladding temperatures are reduced by about 30--40C and quench times occur 20--70 seconds earlier than rods with embedded thermocouples. Additionally, the external surface-thermocouples give readings up to 20 K lower than those obtained with internal surface thermocouples (in the absence of external thermocouples) in the peak cladding temperature zone. Some of the boil-off data obtained from the NEPTUN test facility are used for the assessment of the thermal-hydraulic transient computer codes. These calculations were performed extensively using the frozen version of TRAC-BD1/MOD1 (version 22). A limited number of assessment calculations were done with RELAP5/MOD2 (version 36.02). In this report the main results and conclusions of these calculations are presented with the identification of problem areas in relation to models relevant to boil-off phenomena. On the basis of further analysis and calculations done, changing some of the models such as the bubbly/slug flow interfacial friction correlation which eliminate some of the problems are recommended.

  3. An experimental study of subcooled flow film boiling across horizontal cylinders

    NASA Astrophysics Data System (ADS)

    Warrier, Gopinath Rama

    An experimental investigation of subcooled flow film boiling of Freon-113 over horizontal cylinders was undertaken. Experiments were performed for liquid velocities ranging from 0.78 m/s to 3.05 m/s, and for liquid subcooling ranging from 55.3°C to 72.6°C. Simultaneous wall temperature measurements were recorded using five miniature thermocouples embedded in the heater. A two-dimensional nonlinear inverse heat conduction problem (IHCP) was formulated based on the well-posed hyperbolic heat conduction equation, to estimate the surface heat flux, given measured heater temperatures. Based on the transient surface heat flux estimates and the measured wall temperature fluctuations, solid-liquid and pseudo contacts were identified. Contact parameters such as duration of contact, energy removed per contact, and wall temperature depression per contact were extracted from the data. The results showed that the contacts were not periodic. No clear trend was evident in the data. Correlation of the data was impossible due to the large scatter present. Boiling curves based on both "apparent" and "corrected" heat fluxes were compared to emphasize the importance of internal heat conduction in the heater. The effect of the thermal properties of the heater was investigated using computer simulations. It showed that the lava core was unaffected by short duration contacts. The lava core acts as an energy storage medium. Analysis of the nucleate-film boiling showed that the heater was capable of sustaining simultaneous nucleate and film boiling on its surface. An analytical flow film boiling model was also developed. Though this model does not include heat transfer in the wake of the heater and the effects of solid-liquid or pseudo contact, it is still a major improvement over all existing analytical models. However, these limitations of the model resulted in poor agreement between predicted wall temperatures and those experimentally measured.

  4. Models and Stability Analysis of Boiling Water Reactors

    SciTech Connect

    John Dorning

    2002-04-15

    We have studied the nuclear-coupled thermal-hydraulic stability of boiling water reactors (BWRs) using a model that includes: space-time modal neutron kinetics based on spatial w-modes; single- and two-phase flow in parallel boiling channels; fuel rod heat conduction dynamics; and a simple model of the recirculation loop. The BR model is represented by a set of time-dependent nonlinear ordinary differential equations, and is studied as a dynamical system using the modern bifurcation theory and nonlinear dynamical systems analysis. We first determine the stability boundary (SB) - or Hopf bifurcation set- in the most relevant parameter plane, the inlet-subcooling-number/external-pressure-drop plane, for a fixed control rod induced external reactivity equal to the 100% rod line value; then we transform the SB to the practical power-flow map used by BWR operating engineers and regulatory agencies. Using this SB, we show that the normal operating point at 100% power is very stable, that stability of points on the 100% rod line decreases as the flow rate is reduced, and that operating points in the low-flow/high-power region are least stable. We also determine the SB that results when the modal kinetics is replaced by simple point reactor kinetics, and we thereby show that the first harmonic mode does not have a significant effect on the SB. However, we later show that it nevertheless has a significant effect on stability because it affects the basin of attraction of stable operating points. Using numerical simulations we show that, in the important low-flow/high-power region, the Hopf bifurcation that occurs as the SB is crossed is subcritical; hence, growing oscillations can result following small finite perturbations of stable steady-states on the 100% rod line at points in the low-flow/high-power region. Numerical simulations are also performed to calculate the decay ratios (DRs) and frequencies of oscillations for various points on the 100% rod line. It is determined that the U.S. NRC requirement of DR is not rigorously satisfied in the low-flow/high-power region; hence, this region should be avoided during normal startup and shutdown operations. The frequency of oscillation is shown to decrease as the flow rate is reduced. Moreover, the simulation frequency of 0.5Hz determined in the low-flow/high-power region is consistent with those observed during actual instability incidents. Additional numerical simulations show that in the low-flow/high-power region, for the same initial conditions, the use of point kinetics leads to damped oscillations, whereas the model that includes the modal neutron kinetics equations results in growing nonlinear oscillations.

  5. Temperature dependent dielectric function and the E{sub 0} critical points of hexagonal GaN from 30 to 690 K

    SciTech Connect

    Kim, Tae Jung Hwang, Soon Yong; Byun, Jun Seok; Barange, Nilesh S.; Park, Han Gyeol; Dong Kim, Young

    2014-02-15

    The complex dielectric function ε and the E{sub 0} excitonic and band-edge critical-point structures of hexagonal GaN are reported for temperatures from 30 to 690 K and energies from 0.74 to 6.42 eV, obtained by rotating-compensator spectroscopic ellipsometry on a 1.9 μm thick GaN film deposited on a c-plane (0001) sapphire substrate by molecular beam epitaxy. Direct inversion and B-splines in a multilayer-structure calculation were used to extract the optical properties of the film from the measured pseudodielectric function 〈ε〉. At low temperature sharp E{sub 0} excitonic and critical-point interband transitions are separately observed. Their temperature dependences were determined by fitting the data to the empirical Varshni relation and the phenomenological expression that contains the Bose-Einstein statistical factor.

  6. Tipping Points

    NASA Astrophysics Data System (ADS)

    Hansen, J.

    2007-12-01

    A climate tipping point, at least as I have used the phrase, refers to a situation in which a changing climate forcing has reached a point such that little additional forcing (or global temperature change) is needed to cause large, relatively rapid, climate change. Present examples include potential loss of all Arctic sea ice and instability of the West Antarctic and Greenland ice sheets. Tipping points are characterized by ready feedbacks that amplify the effect of forcings. The notion that these may be runaway feedbacks is a misconception. However, present "unrealized" global warming, due to the climate system's thermal inertia, exacerbates the difficulty of avoiding global warming tipping points. I argue that prompt efforts to slow CO2 emissions and absolutely reduce non-CO2 forcings are both essential if we are to avoid tipping points that would be disastrous for humanity and creation, the planet as civilization knows it.

  7. Parametric study of boiling heat transfer in porous media

    SciTech Connect

    Shi, B.; Jones, B.G.; Pan, C.

    1996-04-01

    Detailed numerical modeling and parametric variation studies were conducted on boiling heat transfer processes in porous deposits with emphasis on applications associated with light water nuclear power reactor systems. The processes of boiling heat transfer in the porous corrosion deposits typically involve phase changes in finite volumetric regions in the porous media. The study examined such processes in two porous media configurations, without chimneys (homogeneous porous structures) and with chimneys (heterogeneous porous structures). A 1-D model and a 2-D model were developed to simulate two-phase flows with phase changes, without dry-out, inside the porous media for both structural configurations. For closure of the governing equations, an empirical correlation of the evaporation rate for phase changes inside the porous media was introduced. In addition, numerical algorithms were developed to solve the coupled nonlinear equations of mass, momentum, energy, capillary pressure, and evaporation rate. The distributions of temperature, thermodynamic saturation, liquid pressure, vapor pressure, liquid velocity, and vapor velocity were predicted. Furthermore, the effects of heat flux, system pressure, porosity, particle diameter, chimney population density, chimney radius, and crud thickness on the all superheat, critical heat flux, and minimum saturation were examined. The predictions were found to be in good agreement with the available experimental results.

  8. Nucleate boiling pressure drop in an annulus: Book 5

    SciTech Connect

    Not Available

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. Nineteen test series and a total of 178 tests were performed. Testing addressed the effects of: Heat flux; pressure; helium gas; power tilt; ribs; asymmetric heat flux. This document consists solely of the plato file index from 11/87 to 11/90.

  9. Effect of superheat and electric field on saturated film boiling

    NASA Astrophysics Data System (ADS)

    Pandey, Vinod; Biswas, Gautam; Dalal, Amaresh

    2016-05-01

    The objective of this investigation is to study the influence of superheat temperature and applied uniform electric field across the liquid-vapor interface during film boiling using a coupled level set and volume of fluid algorithm. The hydrodynamics of bubble growth, detachment, and its morphological variation with electrohydrodynamic forces are studied considering the medium to be incompressible, viscous, and perfectly dielectric at near critical pressure. The transition in interfacial instability behavior occurs with increase in superheat, the bubble release being periodic both in space and time. Discrete bubble growth occurs at a smaller superheat whereas vapor columns form at the higher superheat values. Destabilization of interfacial motion due to applied electric field results in decrease in bubble separation distance and increase in bubble release rate culminating in enhanced heat transfer rate. A comparison of maximum bubble height owing to application of different intensities of electric field is performed at a smaller superheat. The change in dynamics of bubble growth due to increasing superheat at a high intensity of electric field is studied. The effect of increasing intensity of electric field on the heat transfer rate at different superheats is determined. The boiling characteristic is found to be influenced significantly only above a minimum critical intensity of the electric field.

  10. Design inputs document: Boiling behavior during flow instability

    SciTech Connect

    Coutts, D.A.

    1991-01-01

    The coolant flow in a nuclear reactor core under normal operating conditions is kept as a subcooled liquid. This coolant is evenly distributed throughout the multiple flow channels with a uniform pressure profile across each coolant flow channel. If the coolant flow is reduced, the flow through individual channels will also decrease. A decrease in coolant flow will result in higher coolant temperatures if the heat flux is not reduced. When flow is significantly decreased, localized boiling may occur. This localized boiling can restrict coolant flow and the ability to transfer heat out of the reactor system. The maximum operating power for the reactor may be limited by how the coolant system reacts to a flow instability. One of the methods to assure safe operation during a reducing flow instability, is to operate at a power level below that necessary to initiate a flow excursion. Several correlations have been used to predict the conditions which precede a flow excursion. These correlations rely on the steady state behavior of the coolant and are based on steady state testing. This task will evaluate if there are any deviations between the actual transient flow excursion behavior and the flow excursion behavior based on steady state correlations (ONB, OSV, and CHF). Correlations will be developed which will allow a comparison between the time to excursive behavior predicted using steady state techniques and the actual time to excursive behavior.

  11. Design inputs document: Boiling behavior during flow instability

    SciTech Connect

    Coutts, D.A.

    1991-12-31

    The coolant flow in a nuclear reactor core under normal operating conditions is kept as a subcooled liquid. This coolant is evenly distributed throughout the multiple flow channels with a uniform pressure profile across each coolant flow channel. If the coolant flow is reduced, the flow through individual channels will also decrease. A decrease in coolant flow will result in higher coolant temperatures if the heat flux is not reduced. When flow is significantly decreased, localized boiling may occur. This localized boiling can restrict coolant flow and the ability to transfer heat out of the reactor system. The maximum operating power for the reactor may be limited by how the coolant system reacts to a flow instability. One of the methods to assure safe operation during a reducing flow instability, is to operate at a power level below that necessary to initiate a flow excursion. Several correlations have been used to predict the conditions which precede a flow excursion. These correlations rely on the steady state behavior of the coolant and are based on steady state testing. This task will evaluate if there are any deviations between the actual transient flow excursion behavior and the flow excursion behavior based on steady state correlations (ONB, OSV, and CHF). Correlations will be developed which will allow a comparison between the time to excursive behavior predicted using steady state techniques and the actual time to excursive behavior.

  12. 6. View of first panel point from south end showing ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. View of first panel point from south end showing chord, diagonals and vertical member connection at pin - Bridge No. 2.4, Spanning Boiling Fork Creek at Railroad Milepost JC-2.4, Decherd, Franklin County, TN

  13. Prospective Chemistry Teachers' Misconceptions about Colligative Properties: Boiling Point Elevation and Freezing Point Depression

    ERIC Educational Resources Information Center

    Pinarbasi, Tacettin; Sozbilir, Mustafa; Canpolat, Nurtac

    2009-01-01

    This study aimed at identifying prospective chemistry teachers' misconceptions of colligative properties. In order to fulfill this aim, a diagnostic test composed of four open-ended questions was used. The test was administered to seventy-eight prospective chemistry teachers just before qualifying to teaching in secondary schools. Nine different…

  14. Prospective Chemistry Teachers' Misconceptions about Colligative Properties: Boiling Point Elevation and Freezing Point Depression

    ERIC Educational Resources Information Center

    Pinarbasi, Tacettin; Sozbilir, Mustafa; Canpolat, Nurtac

    2009-01-01

    This study aimed at identifying prospective chemistry teachers' misconceptions of colligative properties. In order to fulfill this aim, a diagnostic test composed of four open-ended questions was used. The test was administered to seventy-eight prospective chemistry teachers just before qualifying to teaching in secondary schools. Nine different

  15. Active control of flow boiling oscillation amplitude and frequency using a transverse jet in crossflow

    NASA Astrophysics Data System (ADS)

    Vutha, Ashwin Kumar; Rao, Sameer Raghavendra; Houshmand, Farzad; Peles, Yoav

    2016-03-01

    We demonstrate a technique to mitigate thermal oscillations in microchannel flow boiling and suppress the characteristic frequency associated with these oscillations. The method employs a transverse jet in crossflow that is fabricated along with the primary microchannel in a double-sided vinyl tape, using laser machining. Liquid at ambient temperature is injected into a flow boiling region at different momentum flux ratios to control the local temperature. A maximum reduction of 82% in temperature fluctuations was demonstrated and the dominant frequency of oscillations was completely suppressed within a particular range of momentum flux ratios. The observed phenomena are attributed to the replenishment of liquid into dryout regions, thereby preventing the large temperature rise and subsequent drop caused by dryout and rewetting, respectively.

  16. Accurate experimental determination of the isotope effects on the triple point temperature of water. II. Combined dependence on the 18O and 17O abundances

    NASA Astrophysics Data System (ADS)

    Faghihi, V.; Kozicki, M.; Aerts-Bijma, A. T.; Jansen, H. G.; Spriensma, J. J.; Peruzzi, A.; Meijer, H. A. J.

    2015-12-01

    This paper is the second of two articles on the quantification of isotope effects on the triple point temperature of water. In this second article, we address the combined effects of 18O and 17O isotopes. We manufactured five triple point cells with waters with 18O and 17O abundances exceeding widely the natural abundance range while maintaining their natural 18O/17O relationship. The 2H isotopic abundance was kept close to that of VSMOW (Vienna Standard Mean Ocean Water). These cells realized triple point temperatures ranging between  -220 μK to 1420 μK with respect to the temperature realized by a triple point cell filled with VSMOW. Our experiment allowed us to determine an accurate and reliable value for the newly defined combined 18, 17O correction parameter of AO  =  630 μK with a combined uncertainty of 10 μK. To apply this correction, only the 18O abundance of the TPW needs to be known (and the water needs to be of natural origin). Using the results of our two articles, we recommend a correction equation along with the coefficient values for isotopic compositions differing from that of VSMOW and compare the effect of this new equation on a number of triple point cells from the literature and from our own institute. Using our correction equation, the uncertainty in the isotope correction for triple point cell waters used around the world will be  <1 μK.

  17. Thermohydrodynamics of boiling in a van der Waals fluid.

    PubMed

    Laurila, T; Carlson, A; Do-Quang, M; Ala-Nissila, T; Amberg, G

    2012-02-01

    We present a modeling approach that enables numerical simulations of a boiling Van der Waals fluid based on the diffuse interface description. A boundary condition is implemented that allows in and out flux of mass at constant external pressure. In addition, a boundary condition for controlled wetting properties of the boiling surface is also proposed. We present isothermal verification cases for each element of our modeling approach. By using these two boundary conditions we are able to numerically access a system that contains the essential physics of the boiling process at microscopic scales. Evolution of bubbles under film boiling and nucleate boiling conditions are observed by varying boiling surface wettability. We observe flow patters around the three-phase contact line where the phase change is greatest. For a hydrophilic boiling surface, a complex flow pattern consistent with vapor recoil theory is observed. PMID:22463330

  18. Rotational CARS application to simultaneous and multiple-point temperature and concentration determination in a turbulent flow

    NASA Technical Reports Server (NTRS)

    Snow, J. B.; Murphy, D. V.; Chang, R. K.

    1983-01-01

    Coherent anti-Stokes Raman scattering (CARS) from the pure rotational Raman lines of N2 is employed to measure the instantaneous (approximately 10 ns) rotational temperature of N2 gas at room temperature and below with good spatial resolution (0.2 x 0.2 x 3.0 cu mm). A broad bandwidth dye laser is used to obtain the entire rotational spectrum from a single laser pulse; the CARS signal is then dispersed by a spectrograph and recorded on an optical multichannel analyzer. A best fit temperature is found in several seconds with the aid of a computer for each experimental spectrum by a least squares comparison with calculated spectra. The model used to calculate the theoretical spectra incorporates the temperature and pressure dependence of the pressure-broadened rotational Raman lines, includes the nonresonant background susceptibility, and assumes that the pump laser has a finite linewidth. Temperatures are fit to experimental spectra recorded over the temperature range of 135 to 296 K, and over the pressure range of .13 to 15.3 atm.

  19. Point mutation Gln121-Arg increased temperature optima of Bacillus lipase (1.4 subfamily) by fifteen degrees.

    PubMed

    Goomber, Shelly; Kumar, Rakesh; Singh, Ranvir; Mishra, Neelima; Kaur, Jagdeep

    2016-07-01

    Small molecular weight Bacillus lipases are industrially attractive because of its alkaline optimum pH, broad substrate specificity and production in high yield by overexpression both in Escherichia coli and Bacillus subtilis. Its major limitation of being mesophilic in nature is constantly targeted by laboratory evolution studies. Herein metagenomically isolated Bacillus LipJ was randomly evolved by error prone PCR and library of variants were screened for enhanced thermostability. Point mutant Gln121Arg was extensively characterized and it showed dramatic shift of Temp. opt to 50°C compared to 37°C for parent enzyme. Thermostability studies at 45°C and 50°C determined six fold increase in half life for point variant Gln121Arg compared to LipJ. Circular dichroism (CD) and tryptophan fluorescence study established enhanced thermostability of Gln121Arg. Specific activity of point variant Gln121Arg was comparable to wild type with increased substrate affinity (Km reduced). Reduced kcat for variant Gln121Arg infer that kinetic and catalytic efficiency of mutant was compromised. Structural implications by homolog modelling predicted Gln121 to be placed within longest loop of the structure at surface. Localization of loop due to additional polar interactions by Arg121 to protein core defines molecular basis of enhanced thermostability of random point variant Gln121Arg. PMID:27083848

  20. Scaling theory of the mott transition and breakdown of the Grüneisen scaling near a finite-temperature critical end point.

    PubMed

    Bartosch, Lorenz; de Souza, Mariano; Lang, Michael

    2010-06-18

    We discuss a scaling theory of the lattice response in the vicinity of a finite-temperature critical end point. The thermal expansivity is shown to be more singular than the specific heat such that the Grüneisen ratio diverges as the critical point is approached, except for its immediate vicinity. More generally, we express the thermal expansivity in terms of a scaling function which we explicitly evaluate for the two-dimensional Ising universality class. Recent thermal expansivity measurements on the layered organic conductor κ-(BEDT-TTF)2X close to the Mott transition are well described by our theory. PMID:20867311

  1. Point defects analysis of zinc oxide thin films annealed at different temperatures with photoluminescence, Hall mobility, and low frequency noise

    NASA Astrophysics Data System (ADS)

    Ke, Lin; Lai, Szu Cheng; Ye, Jian Dong; Kaixin, Vivian Lin; Chua, Soo Jin

    2010-10-01

    Zinc oxide (ZnO) thin films annealed at different temperatures were studied with photoluminescence (PL), electrical resistivity, Hall mobility, and 1/f noise spectroscopy. Relatively high electrical conductivity and carrier concentration in sample annealed at 400 °C suggested the presence of ZnO interstitials. Rapid reduction in electrical conductivity and carrier concentration upon increasing the annealing temperature suggested that ZnO interstitials could be eliminated by high temperature annealing. Presence of G-R noise in sample annealed at 400 °C indicated high level of electron trapping activities. Density of Zn vacancies acting as electron traps was estimated by Lorentzian fitting on the G-R noise. PL spectra exhibiting dominant green emission in all samples suggested the presence of Zn vacancies in high concentration. Yellow-orange emission in PL in samples annealed at 600 °C and below indicated the presence of O interstitials, while the same emission in samples annealed at higher temperatures were ascribed to Si impurities diffused from the substrate. Sharp reduction in mobility and surge in Hooge's parameter in sample annealed at 700 °C implied high level of electron scattering due to large extrinsic Si impurities. Gradual rise in green-yellow emission and electron concentration as annealing temperature increased from 500 to 700 °C were ascribed to the gradual formation of O vacancies.

  2. A Drosophila laboratory evolution experiment points to low evolutionary potential under increased temperatures likely to be experienced in the future.

    PubMed

    Schou, M F; Kristensen, T N; Kellermann, V; Schlötterer, C; Loeschcke, V

    2014-09-01

    The ability to respond evolutionarily to increasing temperatures is important for survival of ectotherms in a changing climate. Recent studies suggest that upper thermal limits may be evolutionary constrained. We address this hypothesis in a laboratory evolution experiment, encompassing ecologically relevant thermal regimes. To examine the potential for species to respond to climate change, we exposed replicate populations of Drosophila melanogaster to increasing temperatures (0.3 °C every generation) for 20 generations, whereas corresponding replicate control populations were held at benign thermal conditions throughout the experiment. We hypothesized that replicate populations exposed to increasing temperatures would show increased resistance to warm and dry environments compared with replicate control populations. Contrasting replicate populations held at the two thermal regimes showed (i) an increase in desiccation resistance and a decline in heat knock-down resistance in replicate populations exposed to increasing temperatures, (ii) similar egg-to-adult viability and fecundity in replicate populations from the two thermal regimes, when assessed at high stressful temperatures and (iii) no difference in nucleotide diversity between thermal regimes. The limited scope for adaptive evolutionary responses shown in this study highlights the challenges faced by ectotherms under climate change. PMID:24925446

  3. (Investigation of subcooled hydrothermal boiling in ground water flow channels as a source of harmonic tremors)

    SciTech Connect

    Not Available

    1989-01-01

    As a first step toward assessing the ability of hydrothermal boiling to explain geothermal ground noise and volcanic tremor observations, we are investigating the acoustic power spectrum of boiling (the source'' spectrum in the above model). We simulate boiling in the lab by injecting high pressure steam from a boiler into a pressure vessel filled with water. The water pressure fluctuations that result from the repeated formation and collapse of steam bubbles at the steam inlet vents are recorded by a hydrophone whose output is digitized at 2 {times} 10{sup 4} samples/second by a computer. The range of pressure and temperature conditions attainable within the pressure vessel is limited to <3.5 bars, <139{degree}C, due to the finite strength of observation windows affixed to the pressure vessel. Therefore, dimensional analysis will be used to correlate the experimental results with the pertinent experimental variables. Besides the overall shape of the boiling power spectrum, we are investigating the absolute spectral levels in frequency bands typical of geothermal ground noise and volcanic tremor (0.5 Hz-10 Hz), and the ratio of acoustic power liberated to total available power. The values of these parameters are critical to hydrothermal boiling's ability to generate ground motion amplitudes in accordance with observation. If it can be shown that the range of observed ground noise/tremor amplitudes can be accounted for by hydrothermal boiling at reasonable heat transfer rates, this knowledge would be invaluable to designers of seismic monitoring experiments who are interested in geothermal resource exploration/evaluation and volcanic eruption prediction.

  4. Bench-scale screening tests for a boiling sodium-potassium alloy solar receiver

    SciTech Connect

    Moreno, J.B.; Moss, T.A.

    1993-06-01

    Bench-scale tests were carried out in support of the design of a second-generation 75-kW{sub t} reflux pool-boiler solar receiver. The receiver will be made from Haynes Alloy 230 and will contain the sodium-potassium alloy NaK-78. The bench-scale tests used quartz-lamp-heated boilers to screen candidate boiling-stabilization materials and methods at temperatures up to 750{degree}C. Candidates that provided stable boiling were tested for hot-restart behavior. Poor stability was obtained with single 1/4-inch diameter patches of powdered metal hot-press-sintered onto the wetted side of the heat-input area. Laser-drilled and electric-discharge-machined cavities in the heated surface also performed poorly. Small additions of xenon, and heated-surface tilt out of the vertical dramatically improved poor boiling stability; additions of helium or oxygen did not. The most stable boiling was obtained when the entire heat-input area was covered by a powdered-metal coating. The effect of heated-area size was assessed for one coating: at low incident fluxes, when even this coating performed poorly, increasing the heated-area size markedly improved boiling stability. Good hot-restart behavior was not observed with any candidate, although results were significantly better with added xenon in a boiler shortened from 3 to 2 feet. In addition to the screening tests, flash-radiography imaging of metal-vapor bubbles during boiling was attempted. Contrary to the Cole-Rohsenow correlation, these bubble-size estimates did not vary with pressure; instead they were constant, consistent with the only other alkali metal measurements, but about 1/2 their size.

  5. Flow boiling in vertical down-flow

    SciTech Connect

    Dougherty, T.; Fighetti, C.; Reddy, G.; Yang, B.; Jafri, T. ); McAssey, E. ); Qureshi, Z. )

    1989-01-01

    An experimental program has been conducted to investigate the onset of Ledinegg instability in vertical down-flow. For three size uniformly heated test sections with L/D ratios from 100 to 150, the pressure drop under subcooled boiling conditions has been obtained for a wide range of operating parameters. The results are presented in non-dimensional forms which correlate the important variables and provide techniques for predicting the onset of flow instability. 3 refs.

  6. Flow boiling in vertical down-flow

    SciTech Connect

    Dougherty, T.; Fighetti, C.; Reddy, G.; Yang, B.; Jafri, T.; McAssey, E.; Qureshi, Z.

    1989-12-31

    An experimental program has been conducted to investigate the onset of Ledinegg instability in vertical down-flow. For three size uniformly heated test sections with L/D ratios from 100 to 150, the pressure drop under subcooled boiling conditions has been obtained for a wide range of operating parameters. The results are presented in non-dimensional forms which correlate the important variables and provide techniques for predicting the onset of flow instability. 3 refs.

  7. Potential risk of bisphenol A migration from polycarbonate containers after heating, boiling, and microwaving.

    PubMed

    Lim, Duck Soo; Kwack, Seung Jun; Kim, Kyu-Bong; Kim, Hyung Sik; Lee, Byung Mu

    2009-01-01

    The migration levels of bisphenol A (BPA) were analyzed in food samples by high-performance liquid chromatography (HPLC) from polycarbonate (PC) bottles subjected to simulated use by heating with microwave, heating in a boiling water bath, or filling them with boiling hot water (100 degrees C). Migration testing performed in PC bottles filled with steamed rice or hot cooked pork, standing at room temperature, or heated in a boiling water bath (100 degrees C) showed that BPA was not detected at the limit of detection (LOD) of 1 microg/L (ppb). In contrast, heating by microwaving to 100 degrees C for 9 min increased BPA migration levels from 6 to 18 ppb and from 5 to 15 ppb for steamed rice or for cooked pork, respectively. In addition, 3 different PC bottles were tested by filling them with boiling hot water (100 degrees C) and leaving them to stand at room temperature for up to 3 h. The mean BPA levels from the bottles increased in a time-dependent manner, with the range of not detected (ND) to 2.5 ppb after 60 min. However, none of the PC bottles released BPA at levels that exceed the recently established specific migration limits (SML) of 600 ppb established by European Union and Korea Food and Drug Administration (KFDA). Data suggest that the use of PC plastic bottles in our daily life is considered safe in Korea. PMID:20077198

  8. Steady State Vapor Bubble in Pool Boiling.

    PubMed

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C; Maroo, Shalabh C

    2016-01-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics. PMID:26837464

  9. Steady State Vapor Bubble in Pool Boiling

    NASA Astrophysics Data System (ADS)

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C.; Maroo, Shalabh C.

    2016-02-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics.

  10. Steady State Vapor Bubble in Pool Boiling

    PubMed Central

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C.; Maroo, Shalabh C.

    2016-01-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics. PMID:26837464

  11. Controlling Transistor Temperature During Burn-In

    NASA Technical Reports Server (NTRS)

    Scott, B. C.

    1986-01-01

    Boiling refrigerant provides simple temperature control for newly manufactured power transistors. Heat-transfer liquid is Fluorinert FC-77 (or equivalent). Liquid boils at 100 degrees C, which is specified temperature at which transistor cases should be maintained during burn-in with this technique.

  12. Pressure drop, heat transfer, critical heat flux, and flow stability of two-phase flow boiling of water and ethylene glycol/water mixtures - final report for project "Efficent cooling in engines with nucleate boiling."

    SciTech Connect

    Yu, W.; France, D. M.; Routbort, J. L.

    2011-01-19

    Because of its order-of-magnitude higher heat transfer rates, there is interest in using controllable two-phase nucleate boiling instead of conventional single-phase forced convection in vehicular cooling systems to remove ever increasing heat loads and to eliminate potential hot spots in engines. However, the fundamental understanding of flow boiling mechanisms of a 50/50 ethylene glycol/water mixture under engineering application conditions is still limited. In addition, it is impractical to precisely maintain the volume concentration ratio of the ethylene glycol/water mixture coolant at 50/50. Therefore, any investigation into engine coolant characteristics should include a range of volume concentration ratios around the nominal 50/50 mark. In this study, the forced convective boiling heat transfer of distilled water and ethylene glycol/water mixtures with volume concentration ratios of 40/60, 50/50, and 60/40 in a 2.98-mm-inner-diameter circular tube has been investigated in both the horizontal flow and the vertical flow. The two-phase pressure drop, the forced convective boiling heat transfer coefficient, and the critical heat flux of the test fluids were determined experimentally over a range of the mass flux, the vapor mass quality, and the inlet subcooling through a new boiling data reduction procedure that allowed the analytical calculation of the fluid boiling temperatures along the experimental test section by applying the ideal mixture assumption and the equilibrium assumption along with Raoult's law. Based on the experimental data, predictive methods for the two-phase pressure drop, the forced convective boiling heat transfer coefficient, and the critical heat flux under engine application conditions were developed. The results summarized in this final project report provide the necessary information for designing and implementing nucleate-boiling vehicular cooling systems.

  13. Measurements of the Electric Field of Zero-Point Optical Phonons in GaAs Quantum Wells Support the Urbach Rule for Zero-Temperature Lifetime Broadening

    NASA Astrophysics Data System (ADS)

    Bhattacharya, Rupak; Mondal, Richarj; Khatua, Pradip; Rudra, Alok; Kapon, Eli; Malzer, Stefan; Döhler, Gottfried; Pal, Bipul; Bansal, Bhavtosh

    2015-01-01

    We study a specific type of lifetime broadening resulting in the well-known exponential "Urbach tail" density of states within the energy gap of an insulator. After establishing the frequency and temperature dependence of the Urbach edge in GaAs quantum wells, we show that the broadening due to the zero-point optical phonons is the fundamental limit to the Urbach slope in high-quality samples. In rough analogy with Welton's heuristic interpretation of the Lamb shift, the zero-temperature contribution to the Urbach slope can be thought of as arising from the electric field of the zero-point longitudinal-optical phonons. The value of this electric field is experimentally measured to be 3 kV cm-1 , in excellent agreement with the theoretical estimate.

  14. Materials behavior in alternate (hydrogen) water chemistry in the Ringhals-1 boiling water reactor

    SciTech Connect

    Ljungberg, L.G.; Cubicciotti, D.; Trolle, M.

    1986-05-01

    In-plant studies on the intergranular stress corrosion cracking (IGSCC) of sensitized austenitic stainless steel (SS) have been performed at the Swedish Ringhals-1 boiling water reactor (BWR). The studies have covered the present (full-temperature (normal)) water chemistry (PWC) and the alternate (primary) water chemistry (AWC) with hydrogen addition. The test techniques applied were constant extension rate testing (CERT) and electrochemical potential (ECP) measurements. The program was covered by extensive environment monitoring. The results verify earlier laboratory studies which show that sensitized austenitic SS is susceptible to IGSCC in PWC, but not in AWC. Other pressure-bearing BWR construction materials are not adversely affected by AWC. The boundary conditions in Ringhals-1 have been established for an AWC, which is defined as an environment that does not produce IGSCC in sensitized SS. The results are compared with a similar program at Dresden-2, and the points of agreement and discordance in the results are discussed. The relevance of ECP measurements for the control of AWC is discussed.

  15. Changes of locoregional skin temperature in neonates undergoing laser needle acupuncture at the acupuncture point large intestine 4.

    PubMed

    Kurath-Koller, Stefan; Litscher, Gerhard; Gross, Anna; Freidl, Thomas; Koestenberger, Martin; Urlesberger, Berndt; Raith, Wolfgang

    2015-01-01

    Laser acupuncture bears a potential risk for the skin surface, especially in neonates whose skin has histological and physiological peculiarities. We evaluated thermal changes of skin temperature in neonates during laser acupuncture by using a thermal camera (Flir i5, Flir Systems Inc., Portland, USA). Laserneedles (Laserneedle GmbH, Glienicke/Nordbahn, Germany) were fixed to the skin at Large Intestine 4 (LI 4, Hegu), bilaterally. Before application of laser acupuncture (685 nm, 15 mW, 500 μm), as well as after 1, 5, and 10 min, thermographic pictures of both hands were taken. The measuring was carried out on the 23rd day after birth (20 neonates, mean postmenstrual gestational age 38 + 2, mean weight 2604 g). Compared to the initial temperature of 34.2°C on the right hand, the skin temperature had increased to 35.3°C (P < 0.05) after 5 min and up to 36.1°C (P < 0.05) after 10 min of stimulation. Equally, on the left hand, an increase of the skin temperature from 34.5°C to 35.9°C (P < 0.05) and 35.9°C (P < 0.05) was measured. The highest measured skin temperature after 10 min of stimulation amounted to 38.7°C, without any clinically visible changes on the skin surface. PMID:25922612

  16. Changes of Locoregional Skin Temperature in Neonates Undergoing Laser Needle Acupuncture at the Acupuncture Point Large Intestine 4

    PubMed Central

    Kurath-Koller, Stefan; Gross, Anna; Freidl, Thomas; Urlesberger, Berndt; Raith, Wolfgang

    2015-01-01

    Laser acupuncture bears a potential risk for the skin surface, especially in neonates whose skin has histological and physiological peculiarities. We evaluated thermal changes of skin temperature in neonates during laser acupuncture by using a thermal camera (Flir i5, Flir Systems Inc., Portland, USA). Laserneedles (Laserneedle GmbH, Glienicke/Nordbahn, Germany) were fixed to the skin at Large Intestine 4 (LI 4, Hegu), bilaterally. Before application of laser acupuncture (685 nm, 15 mW, 500 μm), as well as after 1, 5, and 10 min, thermographic pictures of both hands were taken. The measuring was carried out on the 23rd day after birth (20 neonates, mean postmenstrual gestational age 38 + 2, mean weight 2604 g). Compared to the initial temperature of 34.2°C on the right hand, the skin temperature had increased to 35.3°C (P < 0.05) after 5 min and up to 36.1°C (P < 0.05) after 10 min of stimulation. Equally, on the left hand, an increase of the skin temperature from 34.5°C to 35.9°C (P < 0.05) and 35.9°C (P < 0.05) was measured. The highest measured skin temperature after 10 min of stimulation amounted to 38.7°C, without any clinically visible changes on the skin surface. PMID:25922612

  17. Bubble Dynamics, Two-Phase Flow, and Boiling Heat Transfer in Microgravity

    NASA Technical Reports Server (NTRS)

    Chung, Jacob N.

    1998-01-01

    This report contains two independent sections. Part one is titled "Terrestrial and Microgravity Pool Boiling Heat Transfer and Critical heat flux phenomenon in an acoustic standing wave." Terrestrial and microgravity pool boiling heat transfer experiments were performed in the presence of a standing acoustic wave from a platinum wire resistance heater using degassed FC-72 Fluorinert liquid. The sound wave was created by driving a half wavelength resonator at a frequency of 10.15 kHz. Microgravity conditions were created using the 2.1 second drop tower on the campus of Washington State University. Burnout of the heater wire, often encountered with heat flux controlled systems, was avoided by using a constant temperature controller to regulate the heater wire temperature. The amplitude of the acoustic standing wave was increased from 28 kPa to over 70 kPa and these pressure measurements were made using a hydrophone fabricated with a small piezoelectric ceramic. Cavitation incurred during experiments at higher acoustic amplitudes contributed to the vapor bubble dynamics and heat transfer. The heater wire was positioned at three different locations within the acoustic field: the acoustic node, antinode, and halfway between these locations. Complete boiling curves are presented to show how the applied acoustic field enhanced boiling heat transfer and increased critical heat flux in microgravity and terrestrial environments. Video images provide information on the interaction between the vapor bubbles and the acoustic field. Part two is titled, "Design and qualification of a microscale heater array for use in boiling heat transfer." This part is summarized herein. Boiling heat transfer is an efficient means of heat transfer because a large amount of heat can be removed from a surface using a relatively small temperature difference between the surface and the bulk liquid. However, the mechanisms that govern boiling heat transfer are not well understood. Measurements of wall temperature and heat flux near the wall would add to the database of knowledge which is necessary to understand the mechanisms of nucleate boiling. A heater array has been developed which contains 96 heater elements within a 2.5 mm square area. The temperature of each heater element is held constant by an electronic control system similar to a hot-wire anemometer. The voltage that is being applied to each heater element can be measured and digitized using a high-speed Analog to Digital (A/D) converter, and this digital information can be compiled into a series of heat-flux maps. Information for up to 10,000 heat flux maps can be obtained each second. The heater control system, the A/D system and the heater array construction are described in detail. Results are presented which show that this is an effective method of measuring the local heat flux during nucleate and transition boiling. Heat flux maps are obtained for pool boiling in FC-72 on a horizontal surface. Local heat flux variations are shown to be three to six times larger than variations in the spatially averaged heat flux.

  18. High-intensity focused ultrasound monitoring using harmonic motion imaging for focused ultrasound (HMIFU) under boiling or slow denaturation conditions.

    PubMed

    Hou, Gary Y; Marquet, Fabrice; Wang, Shutao; Apostolakis, Iason-Zacharias; Konofagou, Elisa E

    2015-07-01

    Harmonic motion imaging for focused ultrasound (HMIFU) is a recently developed high-intensity focused ultrasound (HIFU) treatment monitoring method that utilizes an amplitude-modulated therapeutic ultrasound beam to induce an oscillatory radiation force at the HIFU focus and estimates the focal tissue displacement to monitor the HIFU thermal treatment. In this study, the performance of HMIFU under acoustic, thermal, and mechanical effects was investigated. The performance of HMIFU was assessed in ex vivo canine liver specimens (n = 13) under slow denaturation or boiling regimes. A passive cavitation detector (PCD) was used to assess the acoustic cavitation activity, and a bare-wire thermocouple was used to monitor the focal temperature change. During lesioning with slow denaturation, high quality displacements (correlation coefficient above 0.97) were observed under minimum cavitation noise, indicating the tissue initial-softening-then- stiffening property change. During HIFU with boiling, HMIFU monitored a consistent change in lesion-to-background displacement contrast (0.46 ± 0.37) despite the presence of strong cavitation noise due to boiling during lesion formation. Therefore, HMIFU effectively monitored softening-then-stiffening during lesioning under slow denaturation, and detected lesioning under boiling with a distinct change in displacement contrast under boiling in the presence of cavitation. In conclusion, HMIFU was shown under both boiling and slow denaturation regimes to be effective in HIFU monitoring and lesioning identification without being significantly affected by cavitation noise. PMID:26168177

  19. Enhancement of Pool Boiling Heat Transfer and Control of Bubble Motion in Microgravity Using Electric Fields - BCOEL

    NASA Technical Reports Server (NTRS)

    Herman, Cila; Iacona, Estelle; Acquaviva, Tom; Coho, Bill; Grant, Nechelle; Nahra, Henry; Sankaran, Subramanian; Taylor, Al; Julian, Ed; Robinson, Dale; VanZandt, Dave

    2001-01-01

    The BCOEL project focuses on improving pool boiling heat transfer and bubble control in microgravity by exposing the fluid to electric fields. The electric fields induce a body force that can replace gravity in the low gravity environment, and enhance bubble removal from thc heated surface. A better understanding of microgravity effects on boiling with and without electric fields is critical to the proper design of the phase-change-heat-removal equipment for use in space-based applications. The microgravity experiments will focus on the visualization of bubble formation and shape during boiling. Heat fluxes on the boiling surface will be measured, and, together with the measured driving temperature differences, used to plot boiling curvcs for different electric field magnitudes. Bubble formation and boiling processes were found to be extremely sensitive to g-jitter. The duration of the experimental run is critical in order to achieve steady state in microgravity experiments. The International Space Station provides conditions suitable for such experiments. The experimental appararus to be used in the study is described in the paper. The apparatus will be tested in the KC-135 first, and microgravity experiments will be conducted on board of the International Space Station using the Microgravity Science Glovebox as the experimental platform.

  20. Enhancement of Pool Boiling Heat Transfer and Control of Bubble Motion in Microgravity Using Electric Fields (BCOEL)

    NASA Technical Reports Server (NTRS)

    Herman, Cila; Iacona, Estelle; Acquaviva, Tom; Coho, Bill; Grant, Nechelle; Nahra, Henry; Taylor, Al; Julian, Ed; Robinson, Dale; VanZandt, Dave

    2001-01-01

    The BCOEL project focuses on improving pool boiling heat transfer and bubble control in microgravity by exposing the fluid to electric fields. The electric fields induce a body force that can replace gravity in the low gravity environment, and enhance bubble removal from the heated surface. A better understanding of microgravity effects on boiling with and without electric fields is critical to the proper design of the phase-change-heat-removal equipment for use in spacebased applications. The microgravity experiments will focus on the visualization of bubble formation and shape during boiling. Heat fluxes on the boiling surface will be measured, and, together with the measured driving temperature differences, used to plot boiling curves for different electric field magnitudes. Bubble formation and boiling processes were found to be extremely sensitive to g-jitter. The duration of the experimental run is critical in order to achieve steady state in microgravity experiments. The International Space Station provides conditions suitable for such experiments. The experimental apparatus to be used in the study is described in the paper. The apparatus will be tested in the KC-135 first, and microgravity experiments will be conducted on board of the International Space Station using the Microgravity Science Glovebox as the experimental platform.

  1. Cookery method and end-point temperature can affect the Warner-Bratzler shear force, cooking loss, and internal cooked color of beef longissimus steaks.

    PubMed

    Yancey, J W S; Wharton, M D; Apple, J K

    2011-05-01

    Steaks from 60 beef ribeye rolls were used to test the interactive effects of cookery method and end-point temperature on Warner-Bratzler shear force (WBSF) and internal cooked color. Pairs of longissimus thoracis (LT) steaks were assigned to combinations of 3 different end-point temperatures and 5 cookery methods. The forced-air convection oven (FAC) required the longest time and produced the reddest internal color, regardless of end-point temperature. The clam-shell grill (CLAM) required the least cooking time and resulted in the lowest cooking losses, but CLAM-cooked steaks also had the greatest WBSF values and least red internal color. Repeatability values for WBSF were acceptable (>0.60) for all degrees of doneness when steaks were cooked in the FAC and impingement oven, but steaks cooked on the CLAM were not repeatable. The relationship of myofibrillar toughening, moisture loss and cooked color changes in beef LT steaks also differed due to cookery methods. PMID:21185659

  2. A study of flow boiling phenomena using real time neutron radiography

    NASA Astrophysics Data System (ADS)

    Novog, David Raymond

    The operation and safety of both fossil-fuel and nuclear power stations depend on adequate cooling of the thermal source involved. This is usually accomplished using liquid coolants that are forced through the high temperature regions by a pumping system; this fluid then transports the thermal energy to another section of the power station. However, fluids that undergo boiling during this process create vapor that can be detrimental, and influence safe operation of other system components. The behavior of this vapor, or void, as it is generated and transported through the system is critical in predicting the operational and safety performance. This study uses two advanced penetrating radiation techniques, Real Time Neutron Radiography (RTNR), and High Speed X-Ray Tomography (HS-XCT), to examine void generation and transport behavior in a flow boiling system. The geometries studied were tube side flow boiling in a cylindrical configuration, and a similar flow channel with an internal twisted tape swirl flow generator. The heat transfer performance and pressure drop characteristics were monitored in addition to void distribution measurements, so that the impact of void distribution could be determined. The RTNR and heat transfer pipe flow studies were conducted using boiling Refrigerant 134a at pressures from 500 to 700 kPa, inlet subcooling from 3 to 12°C and mass fluxes from 55 to 170kg/m 2-s with heat fluxes up to 40 kW/m2. RTNR and HS-XCT were used to measure the distribution and size of the vapor phases in the channel for cylindrical tube-side flow boiling and swirl-flow boiling geometries. The results clearly show that the averaged void is similar for both geometries, but that there is a significant difference in the void distribution, velocity and transport behavior from one configuration to the next. Specifically, the void distribution during flow boiling in a cylindrical-tube test section showed that the void fraction was largest near the tube center and decreased with increasing radial distance. For swirling flow, the void concentration was highest in the center of each subchannel formed by the twisted tape insert, producing two local void maxima at each axial position. Furthermore, the instantaneous RTNR results show that the effects of bubble agglomeration change from one geometry to the next. To further examine the application of RTNR for void distribution measurement, both vertical and horizontal orientations were examined. These experimental results show similar cross sectional averaged axial distributions of the void fraction but significant differences in the local void behavior. The HS-XCT experiments were conducted on swirl-flow boiling of Refrigerant 123 at similar conditions as the RTNR experiments. These tests were conducted to qualitatively compare and verify the void distribution and behavior obtained using RTNR techniques. The HS-XCT results verify that during smooth flow boiling in a vertical tube the void tends to concentrate in the center of the channel and decrease outward to the channel walls. For swirl flow, the void tends to concentrate near the center of each subchannel formed by the twisted tape. Furthermore, wall region void fraction for smooth-flow boiling was significantly higher than swirling flow conditions due to the significant centrifugal forces present in swirl-flow. These centrifugal forces may improve the heat transfer and dryout behavior during swirl-flow conditions. This work contributes to the development of two-phase flow diagnostics based on penetrating radiative techniques, i.e., RTNR and HS-XCT for void distribution measurement, and enhances the knowledge of flow boiling systems. The application of HS-XCT and RTNR for the study of flow boiling phenomena using smooth and swirl-flow geometries has clearly demonstrated that differences in local void distribution result in differences in heat transfer behavior.

  3. Conserved and narrow temperature limits in alpine insects: Thermal tolerance and supercooling points of the ice-crawlers, Grylloblatta (Insecta: Grylloblattodea: Grylloblattidae).

    PubMed

    Schoville, Sean D; Slatyer, Rachel A; Bergdahl, James C; Valdez, Glenda A

    2015-07-01

    For many terrestrial species, habitat associations and range size are dependent on physiological limits, which in turn may influence large-scale patterns of species diversity. The temperature range experienced by individuals is considered to shape the breadth of the thermal niche, with species occupying temporally and/or geographically stable climates tolerating a narrow temperature range. High-elevation environments experience large temperature fluctuations, with frequent periods below 0 °C, but Grylloblatta (Grylloblattodea: Grylloblattidae) occupy climatically stable microhabitats within this region. Here we test critical thermal limits and supercooling points for five Grylloblatta populations from across a large geographic area, to examine whether the stable microhabitats of this group are associated with a narrow thermal niche and assess their capacity to tolerate cold conditions. Thermal limits are highly conserved in Grylloblatta, despite substantial genetic divergence among populations spanning 1500 m elevation and being separated by over 500 km. Further, Grylloblatta show exceptionally narrow thermal limits compared to other insect taxa with little capacity to improve cold tolerance via plasticity. In contrast, upper thermal limits were significantly depressed by cold acclimation. Grylloblatta maintain coordinated movement until they freeze, and they die upon freezing. Convergence of the critical thermal minima, supercooling point and lower lethal limits point to adaptation to a cold but, importantly, constant thermal environment. These physiological data provide an explanation for the high endemism and patchy distribution of Grylloblatta, which relies on subterranean retreats to accommodate narrow thermal limits. These retreats are currently buffered from temperature fluctuations by snow cover, and a declining snowpack thus places Grylloblatta at risk of exposure to temperatures beyond its tolerance capacity. PMID:25956197

  4. Potential profile near singularity point in kinetic Tonks-Langmuir discharges as a function of the ion sources temperature

    NASA Astrophysics Data System (ADS)

    Kos, L.; Tskhakaya, D. D.; Jelić, N.

    2011-05-01

    A plasma-sheath transition analysis requires a reliable mathematical expression for the plasma potential profile Φ(x) near the sheath edge xs in the limit ɛ ≡λD/ℓ =0 (where λD is the Debye length and ℓ is a proper characteristic length of the discharge). Such expressions have been explicitly calculated for the fluid model and the singular (cold ion source) kinetic model, where exact analytic solutions for plasma equation (ɛ =0) are known, but not for the regular (warm ion source) kinetic model, where no analytic solution of the plasma equation has ever been obtained. For the latter case, Riemann [J. Phys. D: Appl. Phys. 24, 493 (1991)] only predicted a general formula assuming relatively high ion-source temperatures, i.e., much higher than the plasma-sheath potential drop. Riemann's formula, however, according to him, never was confirmed in explicit solutions of particular models (e.g., that of Bissell and Johnson [Phys. Fluids 30, 779 (1987)] and Scheuer and Emmert [Phys. Fluids 31, 3645 (1988)]) since "the accuracy of the classical solutions is not sufficient to analyze the sheath vicinity" [Riemann, in Proceedings of the 62nd Annual Gaseous Electronic Conference, APS Meeting Abstracts, Vol. 54 (APS, 2009)]. Therefore, for many years, there has been a need for explicit calculation that might confirm the Riemann's general formula regarding the potential profile at the sheath edge in the cases of regular very warm ion sources. Fortunately, now we are able to achieve a very high accuracy of results [see, e.g., Kos et al., Phys. Plasmas 16, 093503 (2009)]. We perform this task by using both the analytic and the numerical method with explicit Maxwellian and "water-bag" ion source velocity distributions. We find the potential profile near the plasma-sheath edge in the whole range of ion source temperatures of general interest to plasma physics, from zero to "practical infinity." While within limits of "very low" and "relatively high" ion source temperatures, the potential is proportional to the space coordinate powered by rational numbers α =1/2 and α =2/3, with medium ion source temperatures. We found α between these values being a non-rational number strongly dependent on the ion source temperature. The range of the non-rational power-law turns out to be a very narrow one, at the expense of the extension of α =2/3 region towards unexpectedly low ion source temperatures.

  5. Potential profile near singularity point in kinetic Tonks-Langmuir discharges as a function of the ion sources temperature

    SciTech Connect

    Kos, L.; Tskhakaya, D. D.; Jelic, N.

    2011-05-15

    A plasma-sheath transition analysis requires a reliable mathematical expression for the plasma potential profile {Phi}(x) near the sheath edge x{sub s} in the limit {epsilon}{identical_to}{lambda}{sub D}/l=0 (where {lambda}{sub D} is the Debye length and l is a proper characteristic length of the discharge). Such expressions have been explicitly calculated for the fluid model and the singular (cold ion source) kinetic model, where exact analytic solutions for plasma equation ({epsilon}=0) are known, but not for the regular (warm ion source) kinetic model, where no analytic solution of the plasma equation has ever been obtained. For the latter case, Riemann [J. Phys. D: Appl. Phys. 24, 493 (1991)] only predicted a general formula assuming relatively high ion-source temperatures, i.e., much higher than the plasma-sheath potential drop. Riemann's formula, however, according to him, never was confirmed in explicit solutions of particular models (e.g., that of Bissell and Johnson [Phys. Fluids 30, 779 (1987)] and Scheuer and Emmert [Phys. Fluids 31, 3645 (1988)]) since ''the accuracy of the classical solutions is not sufficient to analyze the sheath vicinity''[Riemann, in Proceedings of the 62nd Annual Gaseous Electronic Conference, APS Meeting Abstracts, Vol. 54 (APS, 2009)]. Therefore, for many years, there has been a need for explicit calculation that might confirm the Riemann's general formula regarding the potential profile at the sheath edge in the cases of regular very warm ion sources. Fortunately, now we are able to achieve a very high accuracy of results [see, e.g., Kos et al., Phys. Plasmas 16, 093503 (2009)]. We perform this task by using both the analytic and the numerical method with explicit Maxwellian and ''water-bag'' ion source velocity distributions. We find the potential profile near the plasma-sheath edge in the whole range of ion source temperatures of general interest to plasma physics, from zero to ''practical infinity.'' While within limits of ''very low'' and ''relatively high'' ion source temperatures, the potential is proportional to the space coordinate powered by rational numbers {alpha}=1/2 and {alpha}=2/3, with medium ion source temperatures. We found {alpha} between these values being a non-rational number strongly dependent on the ion source temperature. The range of the non-rational power-law turns out to be a very narrow one, at the expense of the extension of {alpha}=2/3 region towards unexpectedly low ion source temperatures.

  6. Boiling inception in trichlorotrifluoroethane during forced convection at high pressures

    NASA Technical Reports Server (NTRS)

    Dougall, R. S.; Lippert, T. E.

    1972-01-01

    The inception of bubbles during forced convection was studied experimentally by using trichlorotrifluoroethane (R-113 or Freon-113). The experiments were performed in a rectangular channel, 12.7 x 9.5 mm in cross section. Heating was from a 3.2 mm wide strip embedded in the longer side of the channel. The pressures studied ranged from 3.6 to 20.7 bar, mass velocities from 700 to 600 kg/sq m/sec, and inlet subcoolings from 26 to 97 C. Photographs of the flow were used to determine when bubbles first appeared on the heated surface. These data were compared with wall temperature measurements and inception theories. A reasonable method for calculating the complete boiling curve was found to agree with these results.

  7. Temperature and field dependence of domain wall dynamics up to the Curie point of EuO

    SciTech Connect

    Flosdorff, A.; Goerlitz, D.; Koetzler, J.

    1996-04-01

    Using a broadband vectorial microwave reflectometer, the dynamic susceptibility has been measured on a EuO sphere in the range from 0.3 to 20 GHz. The data taken at zero field between 4.2 K and the Curie temperature {ital T}{sub {ital c}}=69.5 K were analyzed using a phenomenological model of a damped harmonic oscillator for the domain walls, that has been successfully applied to the early investigations on ferrites. Based on the micromagnetic Landau{endash}Lifshitz (LL) model, the temperature variation of the intrinsic resonance and damping frequencies are explained up to {ital T}=0.98 {ital T}{sub {ital c}}. The resulting LL-kinetic coefficient, {ital L}{sub {perpendicular}}=1.1{times}10{sup 11} s{sup {minus}1}, remains independent of temperature and is related to the dipolar induced relaxation rate of the longitudinal magnetization fluctuations. In fields along the easy [111] axis and the symmetric [100] direction this wall process prevails for magnetizations smaller than {ital M}{sub {ital s}}/4 and {ital M}{sub {ital s}}/{radical}3, respectively. Above these thresholds, the characteristic frequencies of the dominant process decrease with field, possibly due to rotational dynamics, and for {bold H}{parallel}[111] a second dynamics associated with the paraprocess is contributing. {copyright} {ital 1996 American Institute of Physics.}

  8. Consumers' perception and acceptance of boiled and fermented sausages from strongly boar tainted meat.

    PubMed

    Meier-Dinkel, Lisa; Gertheiss, Jan; Schnäckel, Wolfram; Mörlein, Daniel

    2016-08-01

    Characteristic off-flavours may occur in uncastrated male pigs depending on the accumulation of androstenone and skatole. Feasible processing of strongly tainted carcasses is challenging but gains in importance due to the European ban on piglet castration in 2018. This paper investigates consumers' acceptability of two sausage types: (a) emulsion-type (BOILED) and (b) smoked raw-fermented (FERM). Liking (9 point scales) and flavour perception (check-all-that-apply with both, typical and negatively connoted sensory terms) were evaluated by 120 consumers (within-subject design). Proportion of tainted boar meat (0, 50, 100%) affected overall liking of BOILED, F (2, 238)=23.22, P<.001, but not of FERM sausages, F (2, 238)=0.89, P=.414. Consumers described the flavour of BOILED-100 as strong and sweaty. In conclusion, FERM products seem promising for processing of tainted carcasses whereas formulations must be optimized for BOILED in order to eliminate perceptible off-flavours. Boar taint rejection thresholds may be higher for processed than those suggested for unprocessed meat cuts. PMID:27038338

  9. Nucleate boiling pressure drop in an annulus: Book 7

    SciTech Connect

    Not Available

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists solely of tables of temperature measurements; minima, maxima, averages and standard deviations being measured.

  10. Nucleate boiling pressure drop in an annulus: Book 3

    SciTech Connect

    Block, J.A.; Crowley, C.; Dolan, F.X.; Sam, R.G.; Stoedefalke, B.H.

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of data plots and summary files of temperature measurements.

  11. Nucleate boiling pressure drop in an annulus: Book 4

    SciTech Connect

    Block, J.A.; Crowley, C.; Dolan, F.X.; Sam, R.G.; Stoedefalke, B.H.

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of data plots and summary files of temperature measurements.

  12. Nucleate boiling pressure drop in an annulus: Book 8

    SciTech Connect

    Not Available

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of tables of temperature measurements.

  13. Nucleate boiling pressure drop in an annulus: Book 6

    SciTech Connect

    Not Available

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of a summary of temperature measurements to include recorded minima, maxima, averages and standard deviations.

  14. The Effects of Thermal Radiation on an Unsteady MHD Axisymmetric Stagnation-Point Flow over a Shrinking Sheet in Presence of Temperature Dependent Thermal Conductivity with Navier Slip

    PubMed Central

    Mondal, Sabyasachi; Haroun, Nageeb A. H.; Sibanda, Precious

    2015-01-01

    In this paper, the magnetohydrodynamic (MHD) axisymmetric stagnation-point flow of an unsteady and electrically conducting incompressible viscous fluid in with temperature dependent thermal conductivity, thermal radiation and Navier slip is investigated. The flow is due to a shrinking surface that is shrunk axisymmetrically in its own plane with a linear velocity. The magnetic field is imposed normally to the sheet. The model equations that describe this fluid flow are solved by using the spectral relaxation method. Here, heat transfer processes are discussed for two different types of wall heating; (a) a prescribed surface temperature and (b) a prescribed surface heat flux. We discuss and evaluate how the various parameters affect the fluid flow, heat transfer and the temperature field with the aid of different graphical presentations and tabulated results. PMID:26414006

  15. Measurement of temperature conductivity of pure fluids and binary mixtures with the aid of dynamic light scattering in the general region of the critical point

    NASA Astrophysics Data System (ADS)

    Reile, E.

    Pure fluid carbon dioxide, sulfur hexafluoride, and trifluoromethane, and binary mixtures of these components, were used in dynamic light scattering measurements to determine the temperature conductivity in the general area of the critical point. The measurement series was done along the coexistenc5 curve and critical isochores in the temperature range 0.9-1.1 T/T(cr). The density was determined from the index of refraction with the help of the Lorentz-Lorenz relationship. For mixtures, the gas and fluid phase concentrations were determined. It was found that the temperature conductivity in the gas phase and on the critical isochores is described by a simple power law, and that of the liquid phase by a more complex power law. For mixtures, the conductivity reaches a minimum in the liquid phase, and the difference in concentrations of coexisting phases is described by a simple power law.

  16. Point defects diagrams for pure and doped copper oxide Cu{sub 2{+-}{delta}}O in the temperature range of 873-1473 K

    SciTech Connect

    Stoklosa, A.

    2012-10-15

    Point defects diagrams for the Cu{sub 2{+-}{delta}}O, both pure and doped with M{sup 2+} metal ions with all the types of defects in the cation sublattice considered are presented in this work. The calculations of the diagrams were performed by a novel method. The calculations were based on the data from the results of the studies of the deviation from stoichiometry and the electrical conductivity in the temperature range of 873-1473 K. The values of {Delta}G{sup o} of the formation of Frenkel-type defects, of copper vacancies, and of interstitial copper atoms were determined and their temperature dependence. It was shown that character of the dependence of the sum of concentrations of electronic defects ([h{sup Bullet }]+b[e Prime ]) on p{sub O{sub 2}} is fully consistent with its dependence of the electrical conductivity. Their mobility ({mu}{sub e}/{mu}{sub h}=b), vary from 1300 to 30. The dope M{sup 2+} increases the concentration of electrons and shifts the minimum of electrical conductivity toward higher oxygen pressures. - Graphical abstract: This work presents point defects diagrams for the Cu{sub 2{+-}{delta}}O, with all the types of defects in the cation sublattice considered. Highlights: Black-Right-Pointing-Pointer The point defects diagrams. Copper oxide Cu{sub 2{+-}{delta}}O, for pure and M{sup 2+} doped. Black-Right-Pointing-Pointer The values of {Delta}G{sup o} of the formation of Frenkel-type defects were determined. Black-Right-Pointing-Pointer The values of {Delta}G{sup o} of the formation QUOTE QUOTE of singly-ionized copper vacancies were determined. Black-Right-Pointing-Pointer The values of {Delta}G{sup o} of the formation of electroneutral copper vacancies were determined. Black-Right-Pointing-Pointer The values of {Delta}G{sup o} of the formation and of interstitial copper atoms were determined.

  17. Removing the effects of temperature and of inappropriate critical point proximity on the electrical resistivity percolation exponent

    NASA Astrophysics Data System (ADS)

    Aparecido-Ferreira, A.; Ribeiro, G. M.; Sampaio, J. F.

    2015-06-01

    Percolating systems have been widely studied, but questions remain elusive: How to define the critical range where the standard percolation equation would be properly applicable, and the universal exponent t would be found? How to remove external effects, such as temperature, which would dramatically have an influence on the t determination? The lack of clear answers may be the reason for the spread of t exponents reported in the literature. Here we suggest rational methods to rule out such spurious effects and to reliably find the t exponent. We hope our work will call the readers' attention to how to carefully carry out experiments on percolating systems.

  18. The Parable of the Boiled System Safety Professional: Drift to Failure

    NASA Technical Reports Server (NTRS)

    Shivers, C. Herbert

    2011-01-01

    Recall from the Parable of the Boiled Frog, that tossing a frog into boiling water causes the frog to jump out and hop away while placing a frog in suitable temperature water and slowly bringing the water to a boil results in the frog boiling due to not being aware of the slowly increasing danger, theoretically, of course. System safety professionals must guard against allowing dangers to creep unnoticed into their projects and be ever alert to notice signs of impending problems. People have used various phrases related to the idea, most notably, latent conditions, James Reason in Managing the Risks of Organizational Accidents (1, pp 10-11), Drift to Failure, Sydney Dekker (2, pp 82-86) in Resilience Engineering: Chronicling the Emergence of Confused Consensus in Resilience Engineering: Concepts and Precepts, Hollnagel, Woods and Leveson, and normalization of deviance, Diane Vaughan in The Challenger Launch Decision: Risky Technology, Culture, and Deviance at NASA (3). Reason also said, If eternal vigilance is the price of liberty, then chronic unease is the price of safety (1, p 37). Our challenge as system safety professionals is to be aware of the emergence of signals that warn us of slowly eroding safety margins. This paper will discuss how system safety professionals might better perform in that regard.

  19. Quantifying mixing, boiling, degassing, oxidation and reactivity of thermal waters at Vonarskard, Iceland

    NASA Astrophysics Data System (ADS)

    Stefánsson, Andri; Keller, Nicole S.; Robin, Jóhann Gunnarsson; Kaasalainen, Hanna; Björnsdóttir, Snædís; Pétursdóttir, Sólveig; Jóhannesson, Haukur; Hreggvidsson, Gudmundur Óli

    2016-01-01

    The chemical composition of geothermal fluids may be altered upon ascent from the reservoir to surface by processes including boiling, degassing, mixing, oxidation and water-rock interaction. In an attempt to quantify these processes, a three step model was developed that includes: (1) defining the composition of the end-member fluid types present in the system, (2) quantifying mixing between the end-members using non-reactive elemental concentrations and enthalpy and (3) quantifying the changes of reactive elements including degassing, oxidation and water-rock interaction. The model was applied to geothermal water at Vonarskard, Iceland, for demonstration having temperatures of 3-98 °C, pH of 2.15-9.95 and TDS of 323-2250 ppm, and was thought to be produced from boiled reservoir water, condensed steam and non-thermal water. Most geothermal water represented mixture of non-thermal water and condensed steam whereas the boiled reservoir water was insignificantly mixed. CO2 and H2S degassing was found to be quantitative in steam-heated water, with oxidation of H2S to SO4 also occurred. In contrast, major rock forming elements are enriched in steam-heated water relative to their mixing ratios, suggesting water-rock interaction in the surface zone. Boiled reservoir water observed in alkaline hot springs have, however, undergone less geochemical changes upon ascent to surface and within the surface zone.

  20. Investigation into flow boiling heat transfer in a minichannel with enhanced heating surface

    NASA Astrophysics Data System (ADS)

    Piasecka, Magdalena

    2012-04-01

    The paper presents results of flow boiling in a minichannel of 1.0 mm depth. The heating element for the working fluid (FC-72) that flows along the minichannel is a single-sided enhanced alloy foil made from Haynes-230. Microrecesses were formed on the selected area of the heating foil by laser technology. The observations of the flow structure were carried out through a piece of glass. Simultaneously, owing to the liquid crystal layer placed on the opposite side of the enhanced foil surface, it was possible to measure temperature distribution on the heating wall through another piece of glass. The experimental research has been focused on the transition from single phase forced convection to nucleate boiling, i.e. the zone of boiling incipience and further development of boiling. The objective of the paper is determining of the void fraction for some cross-sections of selected images for increasing heat fluxes supplied to the heating surface. The flow structure photos were processed in Corel graphics software and binarized. The analysis of phase volumes was developed in Techystem Globe software.