Sample records for boom clay formation

  1. Numerical investigation of the seismic detectability of carbonate thin beds in the Boom Clay formation

    NASA Astrophysics Data System (ADS)

    Carcione, José M.; Gei, Davide

    2016-07-01

    The present study evaluates the capacity of the Boom Clay as a host rock for disposal purposes, more precisely its seismic characterization, which may assess its long-term performance to store radioactive wastes. Although the formation is relatively uniform and homogeneous, there are embedded thin layers of septaria (carbonates) that may affect the integrity of the Boom Clay. Therefore, it is essential to locate these geobodies. The seismic data to characterize the Boom Clay has been acquired at the Kruibeke test site. The inversion, which allowed us to obtain the anisotropy parameters and seismic velocities of the clay, is complemented with further information such as log and laboratory data. The attenuation properties have been estimated from equivalent formations (having similar composition and seismic velocities). The inversion yields quite consistent results although the symmetry of the medium is unusual but physically possible, since the anisotropy parameter ɛ is negative. According to a time-domain calculation of the energy velocity at four frequency bands up to 900 Hz, velocity increases with frequency, a behaviour described by the Zener model. Then, we use this model to describe anisotropy and anelasticity that are implemented into the equation of motion to compute synthetic seismograms in the space-time domain. The technique is based on memory variables and the Fourier pseudospectral method. We have computed reflection coefficients of the septaria thin layer. At normal incidence, the P-wave coefficient vanishes at specific thicknesses of the layer and there is no conversion to the S wave. For example, calculations at 600 Hz show that for thicknesses of 1 m the septarium can be detected more easily since the amplitudes are higher (nearly 0.8). Converted PS waves have a high amplitude at large offsets (between 30° and 80°) and can be useful to identify the target on this basis. Moreover, we have investigated the effect of septaria embedded in the Boom

  2. In situ chemical osmosis experiment in the Boom Clay at the Mol underground research laboratory

    NASA Astrophysics Data System (ADS)

    Garavito, A. M.; De Cannière, P.; Kooi, H.

    Studies on the compatibility of Boom Clay with large amounts of nitrate- bearing bituminized radioactive waste have recently raised a particular interest for osmosis-induced effects in this reference formation in Belgium. Indeed, water flow and solute transport may be associated with several types of driving forces, or gradients (chemical, electrical, thermal), in addition to the hydraulic forces, resulting in the so-called coupled flows. Fluid flow caused by driving forces different than hydraulic gradients is referred to as osmosis. Chemical osmosis, the water flow induced by a chemical gradient across a semi-permeable membrane, can generate pressure increase. The question thus arises if there is a risk to create high pore pressures that could damage the near-field of medium-level waste (MLW) galleries, if osmotically driven water flows towards the galleries are produced by the release of large amounts of NaNO 3 (750 t) in the formation. To what extent a low-permeability clay formation such as the Boom Clay acts as an osmotic membrane is thus a key issue to assess the relevance of osmosis phenomena for the disposal of medium-level waste. An in situ osmosis experiment has been conducted at the H ADES underground research laboratory to determine the osmotic efficiency of Boom Clay at the field scale. A recently developed chemical osmosis flow continuum model has been used to design the osmosis experiment, and to interpret the water pressure measurements. Experimental data could be reproduced quite accurately by the model, and the inferred parameter values are consistent with independent determinations for Boom Clay. A rapid water pressure increase (but limited to about a 2 m water column) was observed after 12 h in the filter containing the more saline water. Then, the osmotically induced water pressure slowly decays on several months. So, the experimental results obtained in situ confirm the occurrence of non-hydraulic flow phenomena (chemical osmosis) in a low

  3. Micro-fabric damages in Boom Clay inferred from cryo-BIB-SEM experiment: recent results

    NASA Astrophysics Data System (ADS)

    Desbois, Guillaume; Schmatz, Joyce; Klaver, Jop; Urai, Janos L.

    2017-04-01

    The Boom Clay is considered as a potential host rock in Belgium for nuclear waste disposal in a deep geological formation. One of the keys to understand the long-term performance of such a host rock is the fundamental understanding of coupling between microstructural evolution, poromechanical behaviour and the state of hydration of the system. At in situ conditions, Boom Clay is a nearly water-saturated (>94%) clay-rich geomaterial. Subsequently, for measurement of mechanical and transport properties in laboratory, cores of Boom Clay are vacuum-packed in Al-coated-poly-ethylene barrier foil to be best preserved at original hydric state. Because clay microstructures are very sensitive to dehydration, the validity of investigations done on such preserved or/and dried samples is often questionable. Desbois et al. (2009, 2013, 2014) showed the possibility to image fluid-filled porosity in Boom Clay, by using the FIB-cryo-SEM (FIB: Focussed Ion Beam) and FIB-cryo-SEM (BIB: Broad Ion Beam) techniques. However, surprisingly in Desbois et al. (2014), BIB-cryo-SEM experiments on Boom Clay, shown that the majority of the pores were fluid-free, contrasting with result in Desbois et al. (2009). In Desbois et al. (2014), several reasons were discussed to explain such discrepancies. The likely ones are the sealing efficiency of the Al-barrier foil at long term and the volume expansion due to the release of in-situ stress after core extraction, contributing both to dehydration and microfabric damage. This contribution presents the newest results based on cryo-BIB-SEM. Small pieces (30 mm3) of Boom Clay were preserved in liquid nitrogen after the core extraction at the MOL/Dessel Underground Research Laboratory in Belgium. A maximum of ten minutes time span was achieved between opening the core, the sub-sample extraction and the quenching of sub-samples in liquid nitrogen. First results show that all pores visible at cryo-SEM resolution are water saturated. However, water

  4. Eogenetic siderite as an indicator for fluctuations in sedimentation rate in the Oligocene Boom Clay Formation (Belgium)

    NASA Astrophysics Data System (ADS)

    Laenen, B.; De Craen, M.

    2004-01-01

    Horizons with septarian concretions are a salient feature of the marine Boom Clay Formation. At most horizons, the concretions consist of ferroan calcite with variable amounts of pyrite, but at stratigraphic level S60 they also contain siderite. S60 is situated at the centre of an intensely bioturbated zone that is underlain by a pyrite-rich layer. Furthermore, the enclosing clay is strongly enriched in iron, manganese and phosphorous. The sedimentological and chemical zoning is indicative for low sedimentation rates, which allowed the concentration of iron in the aerobic zone of the sediment. Concentration of iron was the prerequisite for the formation of the siderite-containing concretions. The co-precipitation with pyrite is an argument for a formation in the sulphate reduction zone, and is indicative for a high rate of iron-reduction. The latter was due to the rapid burial of the iron-enriched layer below the redox boundary. The abrupt fluctuations in sedimentation rate were a response to the maximum flooding event of the second Rupelian third-order relative sea-level cycle, which caused a brief pushback of the detrital sediment wedge to its source areas. As this response is logically explained by the general sequence stratigraphic model [Spec. Publ.-Soc. Econ. Paleontol. Mineral. 42 (1988) 109], early diagenetic siderite may be widespread at maximum flooding surfaces in rapidly prograding marine mudstones.

  5. Conceptual model analysis of interaction at a concrete-Boom Clay interface

    NASA Astrophysics Data System (ADS)

    Liu, Sanheng; Jacques, Diederik; Govaerts, Joan; Wang, Lian

    In many concepts for deep disposal of high-level radioactive waste, cementitious materials are used in the engineered barriers. For example, in Belgium the engineered barrier system is based on a considerable amount of cementitious materials as buffer and backfill in the so-called supercontainer embedded in the hosting geological formation. A potential hosting formation is Boom Clay. Insight in the interaction between the high-pH pore water of the cementitious materials and neutral-pH Boom Clay pore water is required. Two problems are quite common for modeling of such a system. The first one is the computational cost due to the long timescale model assessments envisaged for the deep disposal system. Also a very fine grid (in sub-millimeter), especially at interfaces has to be used in order to accurately predict the evolution of the system. The second one is whether to use equilibrium or kinetic reaction models. The objectives of this paper are twofold. First, we develop an efficient coupled reactive transport code for this diffusion-dominated system by making full use of multi-processors/cores computers. Second, we investigate how sensitive the system is to chemical reaction models especially when pore clogging due to mineral precipitation is considered within the cementitious system. To do this, we selected two portlandite dissolution models, i.e., equilibrium (fastest) and diffusion-controlled model with precipitation of a calcite layer around portlandite particles (diffusion-controlled dissolution). The results show that with shrinking core model portlandite dissolution and calcite precipitation are much slower than with the equilibrium model. Also diffusion-controlled dissolution smooths out dissolution fronts compared to the equilibrium model. However, only a slight difference with respect to the clogging time can be found even though we use a very small diffusion coefficient (10-20 m2/s) in the precipitated calcite layer.

  6. Hollow Cylinder Tests on Boom Clay: Modelling of Strain Localization in the Anisotropic Excavation Damaged Zone

    NASA Astrophysics Data System (ADS)

    François, Bertrand; Labiouse, Vincent; Dizier, Arnaud; Marinelli, Ferdinando; Charlier, Robert; Collin, Frédéric

    2014-01-01

    Boom Clay is extensively studied as a potential candidate to host underground nuclear waste disposal in Belgium. To guarantee the safety of such a disposal, the mechanical behaviour of the clay during gallery excavation must be properly predicted. In that purpose, a hollow cylinder experiment on Boom Clay has been designed to reproduce, in a small-scale test, the Excavation Damaged Zone (EDZ) as experienced during the excavation of a disposal gallery in the underground. In this article, the focus is made on the hydro-mechanical constitutive interpretation of the displacement (experimentally obtained by medium resolution X-ray tomography scanning). The coupled hydro-mechanical response of Boom Clay in this experiment is addressed through finite element computations with a constitutive model including strain hardening/softening, elastic and plastic cross-anisotropy and a regularization method for the modelling of strain localization processes. The obtained results evidence the directional dependency of the mechanical response of the clay. The softening behaviour induces transient strain localization processes, addressed through a hydro-mechanical second grade model. The shape of the obtained damaged zone is clearly affected by the anisotropy of the materials, evidencing an eye-shaped EDZ. The modelling results agree with experiments not only qualitatively (in terms of the shape of the induced damaged zone), but also quantitatively (for the obtained displacement in three particular radial directions).

  7. Deformation mechanisms in experimentally deformed Boom Clay

    NASA Astrophysics Data System (ADS)

    Desbois, Guillaume; Schuck, Bernhard; Urai, Janos

    2016-04-01

    Bulk mechanical and transport properties of reference claystones for deep disposal of radioactive waste have been investigated since many years but little is known about microscale deformation mechanisms because accessing the relevant microstructure in these soft, very fine-grained, low permeable and low porous materials remains difficult. Recent development of ion beam polishing methods to prepare high quality damage free surfaces for scanning electron microscope (SEM) is opening new fields of microstructural investigation in claystones towards a better understanding of the deformation behavior transitional between rocks and soils. We present results of Boom Clay deformed in a triaxial cell in a consolidated - undrained test at a confining pressure of 0.375 MPa (i.e. close to natural value), with σ1 perpendicular to the bedding. Experiments stopped at 20 % strain. As a first approximation, the plasticity of the sample can be described by a Mohr-Coulomb type failure envelope with a coefficient of cohesion C = 0.117 MPa and an internal friction angle ϕ = 18.7°. After deformation test, the bulk sample shows a shear zone at an angle of about 35° from the vertical with an offset of about 5 mm. We used the "Lamipeel" method that allows producing a permanent absolutely plane and large size etched micro relief-replica in order to localize and to document the shear zone at the scale of the deformed core. High-resolution imaging of microstructures was mostly done by using the BIB-SEM method on key-regions identified after the "Lamipeel" method. Detailed BIB-SEM investigations of shear zones show the following: the boundaries between the shear zone and the host rock are sharp, clay aggregates and clastic grains are strongly reoriented parallel to the shear direction, and the porosity is significantly reduced in the shear zone and the grain size is smaller in the shear zone than in the host rock but there is no evidence for broken grains. Comparison of microstructures

  8. Constraints for estimating the future burial depth of host rocks for geological waste disposal: a case study from the Boom Clay, Campine area, Northern Belgium

    NASA Astrophysics Data System (ADS)

    Beerten, K.; De Craen, M.; Brassinnes, S.

    2012-04-01

    An important requirement for geological formations hosting a repository for radioactive waste is sufficient depth to ensure isolation of the waste for a very long time period, up to 1 Ma and beyond. Over such long timescales, the repository depth and the thickness of the overburden may vary significantly due to various geodynamic processes. In Belgium, the Boom Clay in the Campine area (NE-Belgium) is considered as reference host formation for the geological disposal of radioactive waste. First results are presented that illustrate the possible impact of future climate change (based on several scenarios studied in the BIOCLIM project (BIOCLIM, 2001)) and tectonic movements in the Campine area on the thickness of the sediment mass overlying the Boom Clay. At present, the subcrop area of Boom Clay in the Campine area is relatively flat (between ~ 0 m a.s.l. near the river Scheldt estuary in the west and ~ 60 m a.s.l. on the Campine Plateau in the east) and is occupied by several sub-basins that belong to the rivers Meuse and Scheldt. Future development of the area will heavily depend on the behaviour of these rivers and tributaries throughout the considered timeframe, in response to climatic changes and tectonic movements. The area is characterised by a long burial history, with some minor isolated uplift and erosional events during the last 30 Ma. In a global warming scenario during a long interglacial (> 50 ka AP), and/or in the case of subsidence, (relative) sea-level may rise such that various parts of the Boom Clay area will be occupied by the marine realm. This is likely to be a minimal erosion scenario because the baseline for landscape evolution will rise in the upstream parts while estuarine and marine deposition may increase the thickness of the overburden in the downstream parts. In the case of a continuation of Pleistocene glacial cycles, i.e. the alternation between warm interglacials and cold glacials, the area will be exposed to erosion and denudation

  9. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange

    As a result of the termination of the Yucca Mountain Project, the United States Department of Energy (DOE) has started to explore various alternative avenues for the disposition of used nuclear fuel and nuclear waste. The overall scope of the investigation includes temporary storage, transportation issues, permanent disposal, various nuclear fuel types, processing alternatives, and resulting waste streams. Although geologic disposal is not the only alternative, it is still the leading candidate for permanent disposal. The realm of geologic disposal also offers a range of geologic environments that may be considered, among those clay shale formations. Figure 1-1 presents themore » distribution of clay/shale formations within the USA. Clay rock/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at Mol site, Belgium (Barnichon et al., 2005) have all been under intensive scientific investigations (at both field and laboratory scales) for understanding a variety of rock properties and their relations with flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated and plastic clays (Tsang et al., 2005). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. For both clay rocks, coupled thermal, hydrological, mechanical and chemical (THMC) processes are expected to have a significant impact on the long-term safety of a clay repository

  10. Macro-scale deformation behavior and characterization of deformation mechanisms below µm-scale in experimentally deformed Boom Clay by using the combination of triaxial compression, X-ray µ-CT imaging, DIC, BIB cross sectioning, and SEM

    NASA Astrophysics Data System (ADS)

    Oelker, Anne; Desbois, Guillaume; Urai, Janos L.; Bésuelle, Pierre; Viggiani, Gioacchino; Levasseur, Séverine

    2017-04-01

    Boom Clay is one formation being studied in Belgium as a potential host rock for deep geological disposal of radioactive waste. This poorly indurated clay presents in its natural state favorable properties against the migration of radionuclides: low permeability, low solute diffusion rates, good retention and sorption capacity for many radionuclides and good self-sealing capacity. During construction of disposal galleries, stress redistribution will lead to perturbation of the clay and the formation around galleries of the so-called "Excavation disturbed Zone" (EdZ). The study of deformation mechanisms and evolution of Boom Clay properties at macro but also micro scale allows to assess in a more mechanistic way the evolution of Boom Clay properties in this EdZ. In this work, we show microstructural investigations of Boom Clay deformed in undrained triaxial compression by linking conventional stress/strain curves with Digital Image Correlation (DIC) and scanning electron microscopy (SEM) imaging of broad-ion-beam (BIB) milled cross-sections to deduce deformation mechanisms based on microstructures at sub-micron resolution. Two specimens, collected in Mol (Belgium) at the European Underground Laboratories (URL) on HADES level, were analyzed: The major principal stress σ1 was applied parallel as well as perpendicular to the bedding direction with an initial mean normal effective stress of 4.5 MPa and an initial pore water pressure of 2.3 MPa, which are equal to the in-situ values. Linking the resulting DIC-derived maps of incremental strains with the corresponding stress/strain curve give not only information about the moment of the shear band development, but also on the way strain evolves within the specimen throughout the rest. Incremental DIC analysis of X-ray tomographic scans performed during loading tests give a time evolution of the strain field, and subsequently allow to detect strain localization which appears close to the stress peak. Regions with a

  11. Ground-recorded sonic boom signatures of F-18 aircraft formation flight

    NASA Technical Reports Server (NTRS)

    Bahm, Catherine M.; Haering, Edward A., Jr.

    1995-01-01

    Two F-18 aircraft were flown, one above the other, in two formations, in order for the shock systems of the two aircraft to merge and propagate to the ground. The first formation had the canopy of the lower F-18 in the inlet shock of the upper F-18 (called inlet-canopy). The flight conditions were Mach 1.22 and an altitude of 23,500 ft. An array of five sonic boom recorders was used on the ground to record the sonic boom signatures. This paper describes the flight test technique and the ground level sonic boom signatures. The tail-canopy formation resulted in two, separated, N-wave signatures. Such signatures probably resulted from aircraft positioning error. The inlet-canopy formation yielded a single modified signature; two recorders measured an approximate flattop signature. Loudness calculations indicated that the single inlet-canopy signatures were quieter than the two, separated tail-canopy signatures. Significant loudness occurs after a sonic boom signature. Such loudness probably comes from the aircraft engines.

  12. The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments

    NASA Astrophysics Data System (ADS)

    MacDonald, D. D.; Saleh, A.; Lee, S. K.; Azizi, O.; Rosas-Camacho, O.; Al-Marzooqi, A.; Taylor, M.

    2011-04-01

    The prediction of corrosion damage of canisters to experimentally inaccessible times is vitally important in assessing various concepts for the disposal of High Level Nuclear Waste. Such prediction can only be made using deterministic models, whose predictions are constrained by the time-invariant natural laws. In this paper, we describe the measurement of experimental electrochemical data that will allow the prediction of damage to the carbon steel overpack of the super container in Belgium's proposed Boom Clay repository by using the Point Defect Model (PDM). PDM parameter values are obtained by optimizing the model on experimental, wide-band electrochemical impedance spectroscopy data.

  13. Clay-Enriched Silk Biomaterials for Bone Formation

    PubMed Central

    Mieszawska, Aneta J.; Llamas, Jabier Gallego; Vaiana, Christopher A.; Kadakia, Madhavi P.; Naik, Rajesh R.; Kaplan, David L.

    2011-01-01

    The formation of silk protein/clay composite biomaterials for bone tissue formation is described. Silk fibroin serves as an organic scaffolding material offering mechanical stability suitable for bone specific uses. Clay montmorillonite (Cloisite ® Na+) and sodium silicate are sources of osteoinductive silica-rich inorganic species, analogous to bioactive bioglass-like bone repair biomaterial systems. Different clay particle-silk composite biomaterial films were compared to silk films doped with sodium silicate as controls for support of human bone marrow derived mesenchymal stem cells (hMSCs) in osteogenic culture. The cells adhered and proliferated on the silk/clay composites over two weeks. Quantitative real-time RT-PCR analysis revealed increased transcript levels for alkaline phosphatase (ALP), bone sialoprotein (BSP), and collagen type 1 (Col I) osteogenic markers in the cells cultured on the silk/clay films in comparison to the controls. Early evidence for bone formation based on collagen deposition at the cell-biomaterial interface was also found, with more collagen observed for the silk films with higher contents of clay particles. The data suggest that the silk/clay composite systems may be useful for further study toward bone regenerative needs. PMID:21549864

  14. Comparison of the bulk geochemical features and thermal reactivity of kerogens from Mol (Boom Clay), Bure (Callovo-Oxfordian argillite) and Tournemire (Toarcian shales) underground research laboratories.

    PubMed

    Deniau, I; Devol-Brown, I; Derenne, S; Behar, F; Largeau, C

    2008-01-25

    Deep argillaceous formations are potential repositories for the long-term disposal of nuclear waste because of their low permeability and high sorption capacity with respect to radioelements and heavy metals. Such sedimentary rocks contain organic matter, mostly macromolecular and insoluble (kerogen). Upon temperature elevation related to high-level long-lived radioactive waste disposal, the kerogen may release significant quantities of gaseous and liquid effluents, especially oxygen-containing ones, which may influence the ability of the clay to retain radionuclides. The aim of the present study is to assess the global geochemical features and the thermal reactivity of the kerogens isolated from samples collected in the Bure and Tournemire sites, France (Callovo-Oxfordian Clay and Toarcian Shales, respectively) and to draw comparisons with data previously obtained for the Mol site, Belgium (Boom Clay). The study is based on a combination of elemental, spectroscopic (FTIR, solid state (13)C NMR) and pyrolytic (Rock-Eval pyrolysis, Curie point pyrolysis-gas chromatography/mass spectrometry) analyses. Different levels of maturity and resulting differences in the relative abundance of oxygen-containing groups were thus observed for the three kerogens. This is linked with differences in their ability to generate CO(2) and various oxygen-containing, low molecular weight, water-soluble compounds under thermal stress, decreasing from Mol to Bure and to Tournemire.

  15. Impact-Induced Clay Mineral Formation and Distribution on Mars

    NASA Technical Reports Server (NTRS)

    Rivera-Valentin, E. G.; Craig, P. I.

    2015-01-01

    Clay minerals have been identified in the central peaks and ejecta blankets of impact craters on Mars. Several studies have suggested these clay minerals formed as a result of impact induced hydrothermalism either during Mars' Noachian era or more recently by the melting of subsurface ice. Examples of post-impact clay formation is found in several locations on Earth such as the Mjolnir and Woodleigh Impact Structures. Additionally, a recent study has suggested the clay minerals observed on Ceres are the result of impact-induced hydrothermal processes. Such processes may have occurred on Mars, possibly during the Noachian. Distinguishing between clay minerals formed preor post-impact can be accomplished by studying their IR spectra. In fact, showed that the IR spectra of clay minerals is greatly affected at longer wavelengths (i.e. mid-IR, 5-25 micron) by impact-induced shock deformation while the near-IR spectra (1.0-2.5 micron) remains relatively unchanged. This explains the discrepancy between NIR and MIR observations of clay minerals in martian impact craters noted. Thus, it allows us to determine whether a clay mineral formed from impact-induced hydrothermalism or were pre-existing and were altered by the impact. Here we study the role of impacts on the formation and distribution of clay minerals on Mars via a fully 3-D Monte Carlo cratering model, including impact- melt production using results from modern hydrocode simulations. We identify regions that are conducive to clay formation and the location of clay minerals post-bombardment.

  16. Clay mineral formation and transformation in rocks and soils

    USGS Publications Warehouse

    Eberl, D.D.

    1983-01-01

    Three mechanisms for clay mineral formation (inheritance, neoformation, and transformation) operating in three geological environments (weathering, sedimentary, and diagenetic-hydrothermal) yield nine possibilities for the origin of clay minerals in nature. Several of these possibilities are discussed in terms of the rock cycle. The mineralogy of clays neoformed in the weathering environment is a function of solution chemistry, with the most dilute solutions favoring formation of the least soluble clays. After erosion and transportation, these clays may be deposited on the ocean floor in a lateral sequence that depends on floccule size. Clays undergo little reaction in the ocean, except for ion exchange and the neoformation of smectite; therefore, most clays found on the ocean floor are inherited from adjacent continents. Upon burial and heating, however, dioctahedral smectite reacts in the diagenetic environment to yield mixed-layer illite-smectite, and finally illite. With uplift and weathering, the cycle begins again. Refs.

  17. Transport of dissolved organic matter in Boom Clay: Size effects

    NASA Astrophysics Data System (ADS)

    Durce, D.; Aertsens, M.; Jacques, D.; Maes, N.; Van Gompel, M.

    2018-01-01

    A coupled experimental-modelling approach was developed to evaluate the effects of molecular weight (MW) of dissolved organic matter (DOM) on its transport through intact Boom Clay (BC) samples. Natural DOM was sampled in-situ in the BC layer. Transport was investigated with percolation experiments on 1.5 cm BC samples by measuring the outflow MW distribution (MWD) by size exclusion chromatography (SEC). A one-dimensional reactive transport model was developed to account for retardation, diffusion and entrapment (attachment and/or straining) of DOM. These parameters were determined along the MWD by implementing a discretisation of DOM into several MW points and modelling the breakthrough of each point. The pore throat diameter of BC was determined as 6.6-7.6 nm. Below this critical size, transport of DOM is MW dependent and two major types of transport were identified. Below MW of 2 kDa, DOM was neither strongly trapped nor strongly retarded. This fraction had an averaged capacity factor of 1.19 ± 0.24 and an apparent dispersion coefficient ranging from 7.5 × 10- 11 to 1.7 × 10- 11 m2/s with increasing MW. DOM with MW > 2 kDa was affected by both retardation and straining that increased significantly with increasing MW while apparent dispersion coefficients decreased. Values ranging from 1.36 to 19.6 were determined for the capacity factor and 3.2 × 10- 11 to 1.0 × 10- 11 m2/s for the apparent dispersion coefficient for species with 2.2 kDa < MW < 9.3 kDa. Straining resulted in an immobilisation of in average 49 ± 6% of the injected 9.3 kDa species. Our findings show that an accurate description of DOM transport requires the consideration of the size effects.

  18. Swarm Deployable Boom Assembly (DBA) Development of a Deployable Magnetometer Boom for the Swarm Spacecraft

    NASA Astrophysics Data System (ADS)

    McMahon, Paul; Jung, Hans-Juergen; Edwards, Jeff

    2013-09-01

    The Swarm programme consists of 3 magnetically clean satellites flying in close formation designed to measure the Earth's magnetic field using 2 Magnetometers mounted on a 4.3m long deployable boom.Deployment is initiated by releasing 3 HDRMs, once released the boom oscillates back and forth on a pair of pivots, similar to a restaurant kitchen door hinge, for around 120 seconds before coming to rest on 3 kinematic mounts which are used to provide an accurate reference location in the deployed position. Motion of the boom is damped through a combination of friction, spring hysteresis and flexing of the 120+ cables crossing the hinge. Considerable development work and accurate numerical modelling of the hinge motion was required to predict performance across a wide temperature range and ensure that during the 1st overshoot the boom did not damage itself, the harness or the spacecraft.Due to the magnetic cleanliness requirements of the spacecraft no magnetic materials could be used in the design of the hardware.

  19. Towards an understanding of the role of clay minerals in crude oil formation, migration and accumulation

    NASA Astrophysics Data System (ADS)

    Wu, Lin Mei; Zhou, Chun Hui; Keeling, John; Tong, Dong Shen; Yu, Wei Hua

    2012-12-01

    This article reviews progress in the understanding of the role of clay minerals in crude oil formation, migration and accumulation. Clay minerals are involved in the formation of kerogen, catalytic cracking of kerogen into petroleum hydrocarbon, the migration of crude oil, and the continued change to hydrocarbon composition in underground petroleum reservoirs. In kerogen formation, clay minerals act as catalysts and sorbents to immobilize organic matter through ligand exchange, hydrophobic interactions and cation bridges by the mechanisms of Maillard reactions, polyphenol theory, selective preservation and sorptive protection. Clay minerals also serve as catalysts in acid-catalyzed cracking of kerogen into petroleum hydrocarbon through Lewis and Brønsted acid sites on the clay surface. The amount and type of clay mineral affect the composition of the petroleum. Brønsted acidity of clay minerals is affected by the presence and state of interlayer water, and displacement of this water is a probable driver in crude oil migration from source rocks. During crude oil migration and accumulation in reservoirs, the composition of petroleum is continually modified by interaction with clay minerals. The clays continue to function as sorbents and catalysts even while they are being transformed by diagenetic processes. The detail of chemical interactions and reaction mechanisms between clay minerals and crude oil formation remains to be fully explained but promises to provide insights with broader application, including catalytic conversion of biomass as a source of sustainable energy into the future.

  20. Enhancement of peptide bond formation by polyribonucleotides on clay surfaces in fluctuating environments

    NASA Technical Reports Server (NTRS)

    White, D. H.; Erickson, J. C.

    1981-01-01

    The selective effects of polyribonucleotides on the formation of glycine peptide bonds in glycine on clay surfaces are investigated as a model for a template mechanism for the effects of polynucleotides on peptide bond formation. Free oligoglycine yields were determined for the cycling reaction of glycine in the presence and absence of clay and polyribonucleotides or polydeoxyribonucleotides. The polyribonucleotides are observed to lead to increases of up to fourfold increases in oligoglycine formed, with greater enhancements for poly-G nucleotides than for poly-A, poly-U and poly-C, indicating a codonic bias. Polydeoxyribonucleotides are found to provide no enhancement in peptide formation rates, and yields were also greatly reduced in the absence of clay. A mechanism for peptide synthesis is proposed which involves the activation of glycine on the clay surface, followed by the formation of esters between glycine and the 2-prime OH groups of the polyribonucleotide and peptide bonds between adjacent amino acyl esters. It is pointed out that if this mechanism is correct, it may provide a basis for a direct template translation process, which would produce a singlet genetic code.

  1. Bacterial interactions and transport in geological formation of alumino-silica clays.

    PubMed

    Vu, Kien; Yang, Guang; Wang, Boya; Tawfiq, Kamal; Chen, Gang

    2015-01-01

    Bacterial transport in the subsurface is controlled by their interactions with the surrounding environment, which are determined by the surface properties of the geological formation and bacterial surfaces. In this research, surface thermodynamic properties of Escherichia coli and the geological formation of alumino-silica clays were characterized based on contact angle measurements, which were utilized to quantify the distance-dependent interactions between E. coli and the geological formation according to the traditional and extended Derjaguin, Landau, Verwey and Overbeek (DLVO) theory. E. coli attachment to alumino-silica clays was evaluated in laboratory columns under saturated and steady-state flow conditions. E. coli deposition coefficient and desorption coefficient were simulated using convection-dispersion transport models against E. coli breakthrough curves, which were then linked to interactions between E. coli and the geological formation. It was discovered that E. coli deposition was controlled by the long-ranged electrostatic interaction and E. coli desorption was attributed to the short-ranged Lifshitz-van der Waals and Lewis acid-base interactions. E. coli transport in three layers of different alumino-silica clays was further examined and the breakthrough curve was simulated using E. coli deposition coefficient and desorption coefficient obtained from their individual column experiments. The well-fitted simulation confirmed that E. coli transport observations were interaction-dependent phenomena between E. coli and the geological formation. Published by Elsevier B.V.

  2. Clay-Alcohol-Water Dispersions: Anomalous Viscosity Changes Due to Network Formation of Clay Nanosheets Induced by Alcohol Clustering.

    PubMed

    Kimura, Yuji; Haraguchi, Kazutoshi

    2017-05-16

    Clay-alcohol-water ternary dispersions were compared with alcohol-water binary mixtures in terms of viscosity and optical absorbance. Aqueous clay dispersions to which lower alcohols (ethanol, 1-propanol, 2-propanol, and tert-butanol) were added exhibited significant viscosity anomalies (maxima) when the alcohol content was 30-55 wt %, as well as optical absorbance anomalies (maxima). The maximum viscosity (η max ) depended strongly on the clay content and varied between 300 and 8000 mPa·s, making it remarkably high compared with the viscosity anomalies (2 mPa·s) observed in alcohol-water binary mixtures. The alcohol content at η max decreased as the hydrophobicity of the alcohol increased. The ternary dispersions with viscosity anomalies exhibited thixotropic behaviors. The effects of other hydrophilic solvents (glycols) and other kinds of clays were also clarified. Based on these findings and the average particle size changes, the viscosity anomalies in the ternary dispersions were explained by alcohol-clustering-induced network formation of the clay nanosheets. It was estimated that 0.9, 1.7, and 2.5 H 2 O molecules per alcohol molecule were required to stabilize the ethanol, 2-propanol, and tert-butanol, respectively, in the clay-alcohol-water dispersions.

  3. GEOS axial booms

    NASA Technical Reports Server (NTRS)

    Schmidt, G. K.

    1979-01-01

    A booms and mechanisms subsystem was designed, developed, and qualified for the geostationary scientific satellite GEOS. Part of this subsystem consist of four axial booms consisting of one pair of 1 m booms and one pair of 2.5 m booms. Each of these booms is carrying one bird cage electric field sensor. Alignment accuracy requirements led to a telescopic type solution. Deployment is performed by pressurized nitrogen. At deployment in orbit two of these booms showed some anomalies and one of these two deployed only about 80%. Following this malfunction a detailed failure investigation was performed resulting in a design modification of some critical components as release mechanism, guide sleeves of the telescopic elements, and pressure system.

  4. Clay mineral formation under oxidized conditions and implications for paleoenvironments and organic preservation on Mars

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gainey, Seth R.; Hausrath, Elisabeth M.; Adcock, Christopher T.

    Clay mineral-bearing locations have been targeted for martian exploration as potentially habitable environments and as possible repositories for the preservation of organic matter. Although organic matter has been detected at Gale Crater, Mars, its concentrations are lower than expected from meteoritic and indigenous igneous and hydrothermal reduced carbon. We conducted synthesis experiments motivated by the hypothesis that some clay mineral formation may have occurred under oxidized conditions conducive to the destruction of organics. Previous work has suggested that anoxic and/or reducing conditions are needed to synthesize the Fe-rich clay mineral nontronite at low temperatures. In contrast, our experiments demonstrated themore » rapid formation of Fe-rich clay minerals of variable crystallinity from aqueous Fe3+ with small amounts of aqueous Mg2+. Our results suggest that Fe-rich clay minerals such as nontronite can form rapidly under oxidized conditions, which could help explain low concentrations of organics within some smectite-containing rocks or sediments on Mars.« less

  5. Clay mineral formation under oxidized conditions and implications for paleoenvironments and organic preservation on Mars.

    PubMed

    Gainey, Seth R; Hausrath, Elisabeth M; Adcock, Christopher T; Tschauner, Oliver; Hurowitz, Joel A; Ehlmann, Bethany L; Xiao, Yuming; Bartlett, Courtney L

    2017-11-01

    Clay mineral-bearing locations have been targeted for martian exploration as potentially habitable environments and as possible repositories for the preservation of organic matter. Although organic matter has been detected at Gale Crater, Mars, its concentrations are lower than expected from meteoritic and indigenous igneous and hydrothermal reduced carbon. We conducted synthesis experiments motivated by the hypothesis that some clay mineral formation may have occurred under oxidized conditions conducive to the destruction of organics. Previous work has suggested that anoxic and/or reducing conditions are needed to synthesize the Fe-rich clay mineral nontronite at low temperatures. In contrast, our experiments demonstrated the rapid formation of Fe-rich clay minerals of variable crystallinity from aqueous Fe 3+ with small amounts of aqueous Mg 2+ . Our results suggest that Fe-rich clay minerals such as nontronite can form rapidly under oxidized conditions, which could help explain low concentrations of organics within some smectite-containing rocks or sediments on Mars.

  6. Formation of stable nanocomposite clays from small peptides reacted with montmorillonite and illite-smectite mixed layer clays

    NASA Astrophysics Data System (ADS)

    Block, K. A.; Katz, A.; LeBlanc, J.; Peña, S.; Gottlieb, P.

    2015-12-01

    at the clay platelet edges to induce exfoliation and subsequent formation of stable nanocomposite clays.

  7. Booming Sand Dunes

    NASA Astrophysics Data System (ADS)

    Vriend, Nathalie

    "Booming" sand dunes are able to produce low-frequency sound that resembles a pure note from a music instrument. The sound has a dominant audible frequency (70-105 Hz) and several higher harmonics and may be heard from far distances away. A natural or induced avalanche from a slip face of the booming dune triggers the emission that may last for several minutes. There are various references in travel literature to the phenomenon, but to date no scientific explanation covered all field observations. This thesis introduces a new physical model that describes the phenomenon of booming dunes. The waveguide model explains the selection of the booming frequency and the amplification of the sound in terms of constructive interference in a confined geometry. The frequency of the booming is a direct function of the dimensions and velocities in the waveguide. The higher harmonics are related to the higher modes of propagation in the waveguide. The experimental validation includes quantitative field research at the booming dunes of the Mojave Desert and Death Valley National Park. Microphone and geophone recordings of the acoustic and seismic emission show a variation of booming frequency in space and time. The analysis of the sensor data quantifies wave propagation characteristics such as speed, dispersion, and nonlinear effects and allows the distinction between the source mechanism of the booming and the booming itself. The migration of sand dunes results from a complicated interplay between dune building, wind regime, and precipitation. The morphological and morphodynamical characteristics of two field locations are analyzed with various geophysical techniques. Ground-penetrating radar images the subsurface structure of the dunes and reveal a natural, internal layering that is directly related to the history of dune migration. The seismic velocity increases abruptly with depth and gradually increases with downhill position due to compaction. Sand sampling shows local

  8. Surveying Clay Mineral Diversity in the Murray Formation, Gale Crater, Mars

    NASA Technical Reports Server (NTRS)

    Bristow, T.F.; Blake, D. F..; Vaniman, D. T.; Chipera, S. J.; Rampe, E. B.; Grotzinger, J. P.; McAdam, A. C.; Ming, D. W..; Morrison, S. M.; Yen, A. S.; hide

    2017-01-01

    The CheMin XRD instrument aboard Mars Science Laboratory (MSL) has documented clay minerals in various drill samples during its traverse of Gale Crater's floor and ascent of Mt. Sharp. The most recent samples, named Marimba, Quela and Sebina were acquired from the Murray Formation in the Murray Buttes region of lower Mt. Sharp. Marimba and Quela come from a approx. 30 m package of finely laminated lacustrine mudstones. Sebina comes from an overlying package of heterolithic mudstone-sandstones. Clay minerals make up approx.15-25 wt.% of the bulk rock with similar contributions to XRD patterns in all three samples. Broad basal reflections at approx. 10deg 2(theta) CoK(alpha) indicate the presence of 2:1 group clay minerals. The 02(lambda) clay mineral band lies at approx. 22.9deg 2(theta), a region typically occupied by Fe-bearing dioctahedral 2:1 clay minerals like nontronite or Fe-illite. The low humidity within the CheMin instrument, which is open to the martian atmosphere, promotes loss of interlayer H2O and collapse of smectite interlayers making them difficult to distinguish from illites. However, based on the low K content of the bulk samples, it appears that smectitic clay minerals are dominant. Peak dehydroxylation of the Marimba sample measured by the SAM instrument on MSL occurred at 610C and 780C. Fe-bearing smectites are not consistent with these dehydroxylation temperatures. Thus, we suggest that a mixture of dioctahedral and trioctahedral smectite phases are present giving the appearance of intermediate octahedral occupancy in XRD. Dioctahedral smectites have not previously been reported in Gale Crater by MSL. Earlier in the mission, relatively clay mineral rich samples (approx. 20 wt.%) from lacustrine mudstones in Yellowknife Bay (YKB) were found to contain ferrian saponites. It is proposed that YKB saponites formed via isochemical aqueous alteration of detrital olivine close to the time of sediment deposition, under anoxic to poorly oxidizing

  9. Subsurface water and clay mineral formation during the early history of Mars.

    PubMed

    Ehlmann, Bethany L; Mustard, John F; Murchie, Scott L; Bibring, Jean-Pierre; Meunier, Alain; Fraeman, Abigail A; Langevin, Yves

    2011-11-02

    Clay minerals, recently discovered to be widespread in Mars's Noachian terrains, indicate long-duration interaction between water and rock over 3.7 billion years ago. Analysis of how they formed should indicate what environmental conditions prevailed on early Mars. If clays formed near the surface by weathering, as is common on Earth, their presence would indicate past surface conditions warmer and wetter than at present. However, available data instead indicate substantial Martian clay formation by hydrothermal groundwater circulation and a Noachian rock record dominated by evidence of subsurface waters. Cold, arid conditions with only transient surface water may have characterized Mars's surface for over 4 billion years, since the early-Noachian period, and the longest-duration aqueous, potentially habitable environments may have been in the subsurface.

  10. Investigating the behaviour of Mg isotopes during the formation of clay minerals

    NASA Astrophysics Data System (ADS)

    Wimpenny, Joshua; Colla, Christopher A.; Yin, Qing-Zhu; Rustad, James R.; Casey, William H.

    2014-03-01

    We present elemental and isotopic data detailing how the Mg isotope system behaves in natural and experimentally synthesized clay minerals. We show that the bulk Mg isotopic composition (δ26Mg) of a set of natural illite, montmorillonite and kaolinite spans a 2‰ range, and that their isotopic composition depends strongly on a balance between the relative proportions of structural and exchangeable Mg. After acid leaching, these natural clays become relatively enriched in isotopically heavy Mg by between 0.2‰ and 1.6‰. Results of exchange experiments indicate that the Mg that has adsorbed to interlayer spaces and surface charged sites is relatively enriched in isotopically light Mg compared to the residual clay. The isotopic composition of this exchangeable Mg (-1.49‰ to -2.03‰) is characteristic of the isotopic composition of Mg found in many natural waters. Further experiments with an isotopically characterized MgCl2 solution shows that the clay minerals adsorb this exchangeable Mg with little or no isotopic fractionation, although we cannot discount the possibility that the uptake of exchangeable Mg does so with a slight preference for 24Mg. To characterize the behaviour of Mg isotopes during clay mineral formation we synthesized brucite (Mg(OH)2), which we consider to be a good analogue for the incorporation of Mg into the octahedral sheet of Mg-rich clay minerals or into the brucitic layer of clays such as chlorite. In our experiment the brucite mineral becomes enriched in the heavy isotopes of Mg while the corresponding solution is always relatively enriched in isotopically light Mg. The system reaches a steady state after 10 days with a final fractionation factor (αsolid-solution) of 1.0005 at near-neutral pH. This result is consistent with the general consensus that secondary clay minerals preferentially take up isotopically heavy Mg during their formation. However our results also show that exchangeable Mg is an important component within bulk

  11. Lateral spread of sonic boom measurements from US Air Force boomfile flight tests

    NASA Technical Reports Server (NTRS)

    Downing, J. Micah

    1992-01-01

    A series of sonic boom flight tests were conducted by the US Air Force at Edwards AFB in 1987 with current supersonic DOD aircraft. These tests involved 43 flights by various aircraft at different Mach number and altitude combinations. The measured peak overpressures to predicted values as a function of lateral distance are compared. Some of the flights are combined into five groups because of the varying profiles and the limited number of sonic booms obtained during this study. The peak overpressures and the lateral distances are normalized with respect to the Carlson method predicted centerline overpressures and lateral cutoff distances, respectively, to facilitate comparisons between sonic boom data from similar flight profiles. It is demonstrated that the data agrees with sonic boom theory and previous studies and adds to the existing sonic boom database by including sonic boom signatures, tracking, and weather data in a digital format.

  12. Sonic boom acceptability studies

    NASA Technical Reports Server (NTRS)

    Shepherd, Kevin P.; Sullivan, Brenda M.; Leatherwood, Jack D.; Mccurdy, David A.

    1992-01-01

    The determination of the magnitude of sonic boom exposure which would be acceptable to the general population requires, as a starting point, a method to assess and compare individual sonic booms. There is no consensus within the scientific and regulatory communities regarding an appropriate sonic boom assessment metric. Loudness, being a fundamental and well-understood attribute of human hearing was chosen as a means of comparing sonic booms of differing shapes and amplitudes. The figure illustrates the basic steps which yield a calculated value of loudness. Based upon the aircraft configuration and its operating conditions, the sonic boom pressure signature which reaches the ground is calculated. This pressure-time history is transformed to the frequency domain and converted into a one-third octave band spectrum. The essence of the loudness method is to account for the frequency response and integration characteristics of the auditory system. The result of the calculation procedure is a numerical description (perceived level, dB) which represents the loudness of the sonic boom waveform.

  13. The effect of clay on the dissolution of nuclear waste glass

    NASA Astrophysics Data System (ADS)

    Lemmens, K.

    2001-09-01

    In a nuclear waste repository, the waste glass can interact with metals, backfill materials (if present) and natural host rock. Of the various host rocks considered, clays are often reported to delay the onset of the apparent glass saturation, where the glass dissolution rate becomes very small. This effect is ascribed to the sorption of silica or other glass components on the clay. This can have two consequences: (1) the decrease of the silica concentration in solution increases the driving force for further dissolution of glass silica, and (2) the transfer of relatively insoluble glass components (mainly silica) from the glass surface to the clay makes the alteration layer less protective. In recent literature, the latter explanation has gained credibility. The impact of the environmental materials on the glass surface layers is however not well understood. Although the glass dissolution can initially be enhanced by clay, there are arguments to assume that it will decrease to very low values after a long time. Whether this will indeed be the case, depends on the fate of the released glass components in the clay. If they are sorbed on specific sites, it is likely that saturation of the clay will occur. If however the released glass components are removed by precipitation (growth of pre-existing or new secondary phases), saturation of the clay is less likely, and the process can continue until exhaustion of one of the system components. There are indications that the latter mechanism can occur for varying glass compositions in Boom Clay and FoCa clay. If sorption or precipitation prevents the formation of protective surface layers, the glass dissolution can in principle proceed at a high rate. High silica concentrations are assumed to decrease the dissolution rate (by a solution saturation effect or by the impact on the properties of the glass alteration layer). In glass corrosion tests at high clay concentrations, silica concentrations are, however, often higher

  14. Experimental Sonic Boom Measurements on a Mach 1.6 Cruise Low-Boom Configuration

    NASA Technical Reports Server (NTRS)

    Wilcox, Floyd J., Jr.; Elmiligui, Alaa, A.; Wayman, Thomas R.; Waithe, Kenrick A.; Howe, Donald C.; Bangert, Linda S.

    2012-01-01

    A wind tunnel test has been conducted by Gulfstream Aerospace Corporation (GAC) to measure the sonic boom pressure signature of a low boom Mach 1.6 cruise business jet in the Langley Unitary Plan Wind Tunnel at Mach numbers 1.60 and 1.80. Through a cooperative agreement between GAC and the National Aeronautics and Space Administration (NASA), GAC provided NASA access to some of the experimental data and NASA is publishing these data for the sonic boom research community. On-track and off-track near field sonic boom pressure signatures were acquired at three separation distances (0.5, 1.2, and 1.7 reference body lengths) and three angles of attack (-0.26deg, 0.26deg, and 0.68deg). The model was blade mounted to minimize the sting effects on the sonic boom signatures. Although no extensive data analysis is provided, selected data are plotted to illustrate salient features of the data. All of the experimental sonic boom pressure data are tabulated. Schlieren images of the configuration are also included.

  15. Experimental and Computational Sonic Boom Assessment of Lockheed-Martin N+2 Low Boom Models

    NASA Technical Reports Server (NTRS)

    Cliff, Susan E.; Durston, Donald A.; Elmiligui, Alaa A.; Walker, Eric L.; Carter, Melissa B.

    2015-01-01

    Flight at speeds greater than the speed of sound is not permitted over land, primarily because of the noise and structural damage caused by sonic boom pressure waves of supersonic aircraft. Mitigation of sonic boom is a key focus area of the High Speed Project under NASA's Fundamental Aeronautics Program. The project is focusing on technologies to enable future civilian aircraft to fly efficiently with reduced sonic boom, engine and aircraft noise, and emissions. A major objective of the project is to improve both computational and experimental capabilities for design of low-boom, high-efficiency aircraft. NASA and industry partners are developing improved wind tunnel testing techniques and new pressure instrumentation to measure the weak sonic boom pressure signatures of modern vehicle concepts. In parallel, computational methods are being developed to provide rapid design and analysis of supersonic aircraft with improved meshing techniques that provide efficient, robust, and accurate on- and off-body pressures at several body lengths from vehicles with very low sonic boom overpressures. The maturity of these critical parallel efforts is necessary before low-boom flight can be demonstrated and commercial supersonic flight can be realized.

  16. Realism Assessment of Sonic Boom Simulators

    NASA Technical Reports Server (NTRS)

    Sullivan, Brenda M.; Davies, Patrica; Hodgdon, Kthleen K.; Salamone, Joseph A., III; Pilon, Anthony

    2008-01-01

    Developments in small supersonic aircraft design are predicted to result in low-intensity sonic booms. Booms generated by current aircraft are similar to those that led to the ban on commercial supersonic fli ght over the US, so are unsuitable for parametric studies of psychoac oustic response to low-intensity booms. Therefore, simulators have be en used to study the impact of predicted low-intensity sonic booms. H owever, simulators have been criticized because, when simulating conv entional-level booms, the sounds were observed to be unrealistic by p eople experienced in listening to sonic booms. Thus, two studies were conducted to measure the perceived realism of three sonic boom simul ators. Experienced listeners rated the realism of conventional sonic boom signatures when played in these simulators. The effects on percei ved realism of factors such as duration of post-boom noise, exclusion of very low frequency components, inclusion of ground reflections, a nd type of simulator were examined. Duration of post-boom noise was f ound to have a strong effect on perceived realism, while type of simu lator had a weak effect. It was determined that post-boom noise had t o be at least 1.5 seconds long for the sound to be rated very realist ic. Loudness level did not affect realism for the range of sounds pla yed in the tests (80-93 dB ASEL).

  17. Sonic Booms And Building Vibration Revisited

    NASA Astrophysics Data System (ADS)

    Sutherland, Louis C.; Kryter, Karl D.; Czech, Joseph

    2006-05-01

    Lessons learned from the 1960's sonic boom tests at St. Louis, Oklahoma City and at Edwards Air Force Base (EAFB) and more recently in communities near EAFB and Nellis AFB are briefly reviewed from the standpoint of building vibration and rattle response induced by the sonic boom signature. Available data on the vibro-acoustic threshold of rattle are considered along with the principal sonic boom signature parameters, peak overpressure and duration, which drive the low frequency vibration response of buildings to sonic booms. Implications for the current effort to develop an acceptable sonic boom signature are considered with this overview of current understanding of building vibration response to sonic booms. Possible gaps in this current knowledge for current technology boom signatures are considered.

  18. Mineral catalysis of the formation of the phosphodiester bond in aqueous solution - The possible role of montmorillonite clays

    NASA Technical Reports Server (NTRS)

    Ferris, James P.; Ertem, Gozen; KAMALUDDIN; Agarwal, Vipin; Hua, Lu Lin

    1989-01-01

    The possible role of montmorillonite clays in the spontaneous formation on the primitive earth of the phosphodiester bond in the presence of water was investigated in experiments measuring the binding of various nucleosides and nucleotides with Na(+)-montmorillonite 22A and the reactions of these compounds with a water-soluble carbodiimide. It was found that, at neutral pH, adenine derivatives bind stronger than the corresponding uracil derivatives, consistent with the protonation of the adenine by the acidic clay surface and a cationic binding of the protonated ring to the anionic clay surface. The reaction of the 5-prime-AMP with carbodiimide resulted in the formation of 2-prime,5-prime-pApA (18.9 percent), 3-prime,5-prime-pApA (11 percent), and AppA (4.8 percent). The yields of these oligomers obtained when poly(U) was used in place of the clay were 15.5 percent, 3.7 percent, and 14.9 percent AppA, respectively.

  19. Sonic Boom Modeling Technical Challenge

    NASA Technical Reports Server (NTRS)

    Sullivan, Brenda M.

    2007-01-01

    This viewgraph presentation reviews the technical challenges in modeling sonic booms. The goal of this program is to develop knowledge, capabilities and technologies to enable overland supersonic flight. The specific objectives of the modeling are: (1) Develop and validate sonic boom propagation model through realistic atmospheres, including effects of turbulence (2) Develop methods enabling prediction of response of and acoustic transmission into structures impacted by sonic booms (3) Develop and validate psychoacoustic model of human response to sonic booms under both indoor and outdoor listening conditions, using simulators.

  20. Trepostome and cystoporate bryozoans from the Lexington Limestone and the Clays Ferry Formation (Middle and Upper Ordovician) of Kentucky

    USGS Publications Warehouse

    Karklins, O.L.

    1984-01-01

    The Lexington Limestone and the Clays Ferry Formation of Kentucky contain an abundant and diversified fossil invertebrate fauna. This report is concerned with the trepostome and cystoporate bryozoans that constitute a major part of that fauna. The Lexington Limestone, largely a biofragmental fossiliferous limestone, rests disconformably on the Tyrone Limestone (Middle Ordovician). The Clays Ferry Formation consists of approximately equal amounts of biofragmentallimestone and shale, and it overlies conformably, or intertongues with, the upper part of the Lexington Limestone. The Clays Ferry Formation is overlain by the Garrard Siltstone (Upper Ordovician) in central Kentucky and intertongues with the Kope Formation (Upper Ordovician) in northern Kentucky. The MiddleUpper Ordovician boundary falls within the upper part of the Lexington Limestone and laterally equivalent strata of the Clays Ferry Formation. The Lexington Limestone has been divided into 12 members, consisting of calcarenites, calcisiltites, calcilutites, nodular limestones, and shales in various amounts, that intertongue complexly. Because of the great abundance of bryozoans this study is generally limited to bryozoans recovered from, in ascending order, the Grier Limestone Member, the Perryville Limestone Member, the Brannon Member, the Tanglewood Limestone Member, and the Millersburg Member of the Lexington Limestone and from the Clays Ferry Formation and its Point Pleasant Tongue. The trepostome and cystoporate bryozoans discussed are referred to 36 species belonging to 22 genera. The trepostome component includes 29 species belonging to 16 genera: Amplexopora, Atactoporella, Balticopora, Batostoma, Cyphotrypa, Dekayia, Eridotrypa, Hetero-_ trypa, Homotrypa, Homotrypella, Mesotrypa, Parvohallopora, Peronopora, Prasopora, Stigmatella, and Tarphophragma, a new genus. Five of the trepostome species are new: Balticopora arcuatilis, Cyphotrypa switzeriensis, Dekayia epetrima, Eridotrypa sadievillensis

  1. Echo Boom Impact

    ERIC Educational Resources Information Center

    Dordai, Phillipe; Rizzo, Joseph

    2006-01-01

    Like their baby-boomer parents, the echo-boom generation is reshaping the college and university landscape. At 80 million strong, this group of children and young adults born between 1980 and 1995 now is flooding the college and university system, spurring a college building boom. According to Campus Space Crunch, a Hillier Architecture survey of…

  2. Pentachlorophenol radical cations generated on Fe(III)-montmorillonite initiate octachlorodibenzo-p-dioxin formation in clays: DFT and FTIR studies

    PubMed Central

    Gu, Cheng; Liu, Cun; Johnston, Cliff T.; Teppen, Brian J.; Li, Hui; Boyd, Stephen A.

    2011-01-01

    Octachlorodibenzodioxin (OCDD) forms spontaneously from pentachlorophenol (PCP) on the surfaces of Fe(III)-saturated smectite clay (1). Here, we used in situ FTIR methods and quantum mechanical calculations to determine the mechanism by which this reaction is initiated. As the clay was dehydrated, vibrational spectra showed new peaks that grew and then reversibly disappeared as the clay rehydrated. First principle DFT calculations of hydrated Fe-PCP clusters reproduced these transient FTIR peaks when inner-sphere complexation and concomitant electron transfer produced Fe(II) and PCP radical cations. Thus, our experimental (FTIR) and theoretical (quantum mechanical) results mutually support the hypothesis that OCDD formation on Fe-smectite surfaces is initiated by the reversible formation of metastable PCP radical cations via single electron transfer from PCP to Fe(III). The negatively charged clay surface apparently selects for this reaction mechanism by stabilizing PCP radical cations. PMID:21254769

  3. Role of clay minerals in the formation of atmospheric aggregates of Saharan dust

    NASA Astrophysics Data System (ADS)

    Cuadros, Javier; Diaz-Hernandez, José L.; Sanchez-Navas, Antonio; Garcia-Casco, Antonio

    2015-11-01

    Saharan dust can travel long distances in different directions across the Atlantic and Europe, sometimes in episodes of high dust concentration. In recent years it has been discovered that Saharan dust aerosols can aggregate into large, approximately spherical particles of up to 100 μm generated within raindrops that then evaporate, so that the aggregate deposition takes place most times in dry conditions. These aerosol aggregates are an interesting phenomenon resulting from the interaction of mineral aerosols and atmospheric conditions. They have been termed "iberulites" due to their discovery and description from aerosol deposits in the Iberian Peninsula. Here, these aggregates are further investigated, in particular the role of the clay minerals in the aggregation process of aerosol particles. Iberulites, and common aerosol particles for reference, were studied from the following periods or single dust events and locations: June 1998 in Tenerife, Canary Islands; June 2001 to August 2002, Granada, Spain; 13-20 August 2012, Granada; and 1-6 June 2014, Granada. Their mineralogy, chemistry and texture were analysed using X-ray diffraction, electron microprobe analysis, SEM and TEM. The mineral composition and structure of the iberulites consists of quartz, carbonate and feldspar grains surrounded by a matrix of clay minerals (illite, smectite and kaolinite) that also surrounds the entire aggregate. Minor phases, also distributed homogenously within the iberulites, are sulfates and Fe oxides. Clays are apparently more abundant in the iberulites than in the total aerosol deposit, suggesting that iberulite formation concentrates clays. Details of the structure and composition of iberulites differ from descriptions of previous samples, which indicates dependence on dust sources and atmospheric conditions, possibly including anthropic activity. Iberulites are formed by coalescence of aerosol mineral particles captured by precursor water droplets. The concentration of

  4. Clays in prebiological chemistry

    NASA Technical Reports Server (NTRS)

    Rao, M.; Oro, J.; Odom, D. G.

    1980-01-01

    The ways in which clays have been utilized in studies of prebiological chemistry are reviewed, and an assessment is given of the possible role of clays in prebiological systems. The adsorption of organic molecules on clays has been demonstrated, as has the synthesis of bioorganic monomers in the presence of clays. For instance, amino acids, purines and pyrimidines have been obtained from carbon monoxide and nitric acid in the presence of clays at relatively high temperatures (250-325 C). The oligomerization of biochemical monomers, mediated by clays, has also been shown to result in the formation of polymer molecules basic to life. Clays have also been found to affect the condensation of mononucleotides to oligonucleotides.

  5. Surface clay formation during short-term warmer and wetter conditions on a largely cold ancient Mars

    NASA Astrophysics Data System (ADS)

    Bishop, Janice L.; Fairén, Alberto G.; Michalski, Joseph R.; Gago-Duport, Luis; Baker, Leslie L.; Velbel, Michael A.; Gross, Christoph; Rampe, Elizabeth B.

    2018-03-01

    The ancient rock record for Mars has long been at odds with climate modelling. The presence of valley networks, dendritic channels and deltas on ancient terrains points towards running water and fluvial erosion on early Mars1, but climate modelling indicates that long-term warm conditions were not sustainable2. Widespread phyllosilicates and other aqueous minerals on the Martian surface3-6 provide additional evidence that an early wet Martian climate resulted in surface weathering. Some of these phyllosilicates formed in subsurface crustal environments5, with no association with the Martian climate, while other phyllosilicate-rich outcrops exhibit layered morphologies and broad stratigraphies7 consistent with surface formation. Here, we develop a new geochemical model for early Mars to explain the formation of these clay-bearing rocks in warm and wet surface locations. We propose that sporadic, short-term warm and wet environments during a generally cold early Mars enabled phyllosilicate formation without requiring long-term warm and wet conditions. We conclude that Mg-rich clay-bearing rocks with lateral variations in mixed Fe/Mg smectite, chlorite, talc, serpentine and zeolite occurrences formed in subsurface hydrothermal environments, whereas dioctahedral (Al/Fe3+-rich) smectite and widespread vertical horizonation of Fe/Mg smectites, clay assemblages and sulphates formed in variable aqueous environments on the surface of Mars. Our model for aluminosilicate formation on Mars is consistent with the observed geological features, diversity of aqueous mineralogies in ancient surface rocks and state-of-the-art palaeoclimate scenarios.

  6. Detection and cultivation of indigenous microorganisms in Mesozoic claystone core samples from the Opalinus Clay Formation (Mont Terri Rock Laboratory)

    NASA Astrophysics Data System (ADS)

    Mauclaire, L.; McKenzie, J. A.; Schwyn, B.; Bossart, P.

    Although microorganisms have been isolated from various deep-subsurface environments, the persistence of microbial activity in claystones buried to great depths and on geological time scales has been poorly studied. The presence of in-situ microbial life in the Opalinus Clay Formation (Mesozoic claystone, 170 million years old) at the Mont Terri Rock Laboratory, Canton Jura, Switzerland was investigated. Opalinus Clay is a host rock candidate for a radioactive waste repository. Particle tracer tests demonstrated the uncontaminated nature of the cored samples, showing their suitability for microbiological investigations. To determine whether microorganisms are a consistent and characteristic component of the Opalinus Clay Formation, two approaches were used: (i) the cultivation of indigenous micoorganisms focusing mainly on the cultivation of sulfate-reducing bacteria, and (ii) the direct detection of molecular biomarkers of bacteria. The goal of the first set of experiments was to assess the presence of cultivable microorganisms within the Opalinus Clay Formation. After few months of incubation, the number of cell ranged from 0.1 to 2 × 10 3 cells ml -1 media. The microorganisms were actively growing as confirmed by the observation of dividing cells, and detection of traces of sulfide. To avoid cultivation bias, quantification of molecular biomarkers (phospholipid fatty acids) was used to assess the presence of autochthonous microorganisms. These molecules are good indicators of the presence of living cells. The Opalinus Clay contained on average 64 ng of PLFA g -1 dry claystone. The detected microbial community comprises mainly Gram-negative anaerobic bacteria as indicated by the ratio of iso/anteiso phospholipids (about 2) and the detection of large amount of β-hydroxy substituted fatty acids. The PLFA composition reveals the presence of specific functional groups of microorganisms in particular sulfate-reducing bacteria ( Desulfovibrio, Desulfobulbus, and

  7. Timing and conditions of clay fault gouge formation on the Naxos detachment (Cyclades, Greece)

    NASA Astrophysics Data System (ADS)

    Mancktelow, N.; Zwingmann, H.; Mulch, A.

    2016-10-01

    Clay fault gouge from the Naxos detachment (locally up to 1.0-1.5 m thick) is reported and dated for the first time. K-Ar ages on eight clay size fractions from the detachment and a minor fault in the immediate footwall have a narrow range, from 10.3 to 9.0 Ma, with an average of 9.7 ± 0.5 Ma (±1σ). These results are in excellent accord with regional and local age constraints, independently demonstrating the reliability of the method. Hydrogen δD values fall in the range -89 to -95‰, indicating interaction with infiltrating meteoric water during gouge formation, which is consistent with deposition of freshwater sediments in the hanging wall at the same time. Clay mineralogy in the detachment gouge is predominantly mixed layer illite-smectite with subordinate 1 M illite and kaolinite but without higher-temperature 2 M1 illite/mica. Clay fault gouge predominantly formed over a limited time and temperature range, potentially acting as a weak lubricant promoting movement on the Naxos detachment, with correspondingly rapid exhumation and cooling of the underlying footwall.

  8. Sonic Boom: Six Decades of Research

    NASA Technical Reports Server (NTRS)

    Maglieri, Domenic J.; Bobbitt, Percy J.; Plotkin, Kenneth J.; Shepherd, Kevin P.; Coen, Peter G.; Richwine, David M.

    2014-01-01

    Sonic booms generated by aircraft traveling at supersonic speeds have been the subject of extensive aeronautics research for over 60 years. Hundreds of papers have been published that document the experimental and analytical research conducted during this time period. The purpose of this publication is to assess and summarize this work and establish the state-of-the-art for researchers just entering the field, or for those interested in a particular aspect of the subject. This publication consists of ten chapters that cover the experimental and analytical aspects of sonic boom generation, propagation and prediction with summary remarks provided at the end of each chapter. Aircraft maneuvers, sonic boom minimization, simulation techniques and devices as well as human, structural, and other responses to sonic booms are also discussed. The geometry and boom characteristics of various low-boom concepts, both large civil transports and smaller business-jet concepts, are included. The final chapter presents an assessment of civilian supersonic overland flight and highlights the need for continued research and a low-boom demonstrator vehicle. Summary remarks are provided at the end of each chapter. The studies referenced in this publication have been drawn from over 500 references.

  9. Clay catalysis of oligonucleotide formation: kinetics of the reaction of the 5'-phosphorimidazolides of nucleotides with the non-basic heterocycles uracil and hypoxanthine

    NASA Technical Reports Server (NTRS)

    Kawamura, K.; Ferris, J. P.

    1999-01-01

    The montmorillonite clay catalyzed condensation of activated monocleotides to oligomers of RNA is a possible first step in the formation of the proposed RNA world. The rate constants for the condensation of the phosphorimidazolide of adenosine were measured previously and these studies have been extended to the phosphorimidazolides of inosine and uridine in the present work to determine of substitution of neutral heterocycles for the basic adenine ring changes the reaction rate or regioselectivity. The oligomerization reactions of the 5'-phosphoromidazolides of uridine (ImpU) and inosine (ImpI) on montmorillonite yield oligo(U)s and oligo(I)s as long as heptamers. The rate constants for oligonucleotide formation were determined by measuring the rates of formation of the oligomers by HPLC. Both the apparent rate constants in the reaction mixture and the rate constants on the clay surface were calculated using the partition coefficients of the oligomers between the aqueous and clay phases. The rate constants for trimer formation are much greater than those dimer synthesis but there was little difference in the rate constants for the formation of trimers and higher oligomers. The overall rates of oligomerization of the phosphorimidazolides of purine and pyrimidine nucleosides in the presence of montmorillonite clay are the same suggesting that RNA formed on the primitive Earth could have contained a variety of heterocyclic bases. The rate constants for oligomerization of pyrimidine nucleotides on the clay surface are significantly higher than those of purine nucleotides since the pyrimidine nucleotides bind less strongly to the clay than do the purine nucleotides. The differences in the binding is probably due to Van der Waals interactions between the purine bases and the clay surface. Differences in the basicity of the heterocyclic ring in the nucleotide have little effect on the oligomerization process.

  10. High-Quality Seismic Observations of Sonic Booms

    NASA Technical Reports Server (NTRS)

    Wurman, Gilead; Haering, Edward A., Jr.; Price, Michael J.

    2011-01-01

    The SonicBREWS project (Sonic Boom Resistant Earthquake Warning Systems) is a collaborative effort between Seismic Warning Systems, Inc. and NASA Dryden Flight Research Center. This project aims to evaluate the effects of sonic booms on Earthquake Warning Systems in order to prevent such systems from experiencing false alarms due to sonic booms. The airspace above the Antelope Valley, California includes the High Altitude Supersonic Corridor and the Black Mountain Supersonic Corridor. These corridors are among the few places in the US where supersonic flight is permitted, and sonic booms are commonplace in the Antelope Valley. One result of this project is a rich dataset of high-quality accelerometer records of sonic booms which can shed light on the interaction between these atmospheric phenomena and the solid earth. Nearly 100 sonic booms were recorded with low-noise triaxial MEMS accelerometers recording 1000 samples per second. The sonic booms had peak overpressures ranging up to approximately 10 psf and were recorded in three flight series in 2010 and 2011. Each boom was recorded with up to four accelerometers in various array configurations up to 100 meter baseline lengths, both in the built environment and the free field. All sonic booms were also recorded by nearby microphones. We present the results of the project in terms of the potential for sonic-boom-induced false alarms in Earthquake Warning Systems, and highlight some of the interesting features of the dataset.

  11. Sonic boom generated by a slender body aerodynamically shaded by a disk spike

    NASA Astrophysics Data System (ADS)

    Potapkin, A. V.; Moskvichev, D. Yu.

    2018-03-01

    The sonic boom generated by a slender body of revolution aerodynamically shaded by another body is numerically investigated. The aerodynamic shadow is created by a disk placed upstream of the slender body across a supersonic free-stream flow. The disk size and its position upstream of the body are chosen in such a way that the aerodynamically shaded flow is quasi-stationary. A combined method of phantom bodies is used for sonic boom calculations. The method is tested by calculating the sonic boom generated by a blunted body and comparing the results with experimental investigations of the sonic boom generated by spheres of various diameters in ballistic ranges and wind tunnels. The test calculations show that the method of phantom bodies is applicable for calculating far-field parameters of shock waves generated by both slender and blunted bodies. A possibility of reducing the shock wave intensity in the far field by means of the formation of the aerodynamic shadow behind the disk placed upstream of the body is estimated. The calculations are performed for the incoming flow with the Mach number equal to 2. The effect of the disk size on the sonic boom level is calculated.

  12. Sonic Boom Computations for a Mach 1.6 Cruise Low Boom Configuration and Comparisons with Wind Tunnel Data

    NASA Technical Reports Server (NTRS)

    Elmiligui, Alaa A.; Cliff, Susan E.; Wilcox, Floyd; Nemec, Marian; Bangert, Linda; Aftosmis, Michael J.; Parlette, Edward

    2011-01-01

    Accurate analysis of sonic boom pressure signatures using computational fluid dynamics techniques remains quite challenging. Although CFD shows accurate predictions of flow around complex configurations, generating grids that can resolve the sonic boom signature far away from the body is a challenge. The test case chosen for this study corresponds to an experimental wind-tunnel test that was conducted to measure the sonic boom pressure signature of a low boom configuration designed by Gulfstream Aerospace Corporation. Two widely used NASA codes, USM3D and AERO, are examined for their ability to accurately capture sonic boom signature. Numerical simulations are conducted for a free-stream Mach number of 1.6, angle of attack of 0.3 and Reynolds number of 3.85x10(exp 6) based on model reference length. Flow around the low boom configuration in free air and inside the Langley Unitary plan wind tunnel are computed. Results from the numerical simulations are compared with wind tunnel data. The effects of viscous and turbulence modeling along with tunnel walls on the computed sonic boom signature are presented and discussed.

  13. 33 CFR 401.8 - Landing booms.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 3 2011-07-01 2011-07-01 false Landing booms. 401.8 Section 401... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations Condition of Vessels § 401.8 Landing booms. (a) Vessels of more than 50 m in overall length shall be equipped with at least one adequate landing boom on each...

  14. 33 CFR 401.8 - Landing booms.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Landing booms. 401.8 Section 401... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations Condition of Vessels § 401.8 Landing booms. (a) Vessels of more than 50 m in overall length shall be equipped with at least one adequate landing boom on each...

  15. Review of current sonic boom studies.

    NASA Technical Reports Server (NTRS)

    Kane, E. J.

    1973-01-01

    Several aspects of the sonic boom phenomena are currently under investigation at The Boeing Co. This work, supported by the NASA and the FAA, includes an in-depth analysis of sonic boom measurements recorded at the BREN tower, a summary and evaluation of sonic boom investigations done in the last decade and a half, and configuration studies to determine practical lower bound sonic boom limits. The BREN tower test program yielded unique and valuable data because it was the first time that vertical profile measurements were made through caustics produced by maneuvers and atmospheric refraction. The objective of the second effort is to compile in a single reference an annotated abstract, including significant results, for each published sonic boom study and to provide a comprehensive review of the current state of the art to aid future researchers. The configuration work is devoted toward determining the feasibility of supersonic transport type airplanes with a primary design goal of acceptable sonic boom characteristics. Each of these investigations is briefly reviewed and significant results are discussed.

  16. Sonic-boom research: Selected bibliography with annotation

    NASA Technical Reports Server (NTRS)

    Hubbard, H. H.; Maglieri, D. J.; Stephens, D. G.

    1986-01-01

    Citations of selected documents are included which represent the state of the art of technology in each of the following subject areas: prediction, measurement, and minimization of steady-flight sonic booms; prediction and measurement of accelerating-flight sonic booms; sonic-boom propagation; the effects of sonic booms on people, communities, structures, animals, birds, and terrain; and sonic-boom simulator technology. Documents are listed in chronological order in each section of the paper, with key documents and associated annotation listed first. The sources are given along with acquisition numbers, when available, to expedite the acquisition of copies of the documents.

  17. Booms

    EPA Pesticide Factsheets

    Containment booms are used to control the spread of oil to reduce the possibility of polluting shorelines and other resources. They also concentrate oil in thicker surface layers, making recovery easier. They may also be used to divert and channel slicks.

  18. Recent Progress on Sonic Boom Research at NASA

    NASA Technical Reports Server (NTRS)

    Loubeau, Alexandra

    2012-01-01

    Sonic boom research conducted at NASA through the Supersonics Project of the Fundamental Aeronautics Program is oriented toward understanding the potential impact of sonic boom noise on communities from new low-boom supersonic aircraft designs. Encompassing research in atmospheric propagation, structural response, and human response, NASA research contributes to knowledge in key areas needed to support development of a new noise-based standard for supersonic aircraft certification. Partnerships with several industry, government, and academic institutions have enabled the recent execution of several acoustic field studies on sonic booms. An overview of recent activities funded by NASA includes: focus boom model development and experimental validation, field experiments of structural transmission of sonic booms into large buildings, and low boom community response testing.

  19. Sonic boom prediction for the Langley Mach 2 low-boom configuration

    NASA Technical Reports Server (NTRS)

    Madson, Michael D.

    1992-01-01

    Sonic boom pressure signatures and aerodynamic force data for the Langley Mach 2 low sonic boom configuration were computed using the TranAir full-potential code. A solution-adaptive Cartesian grid scheme is utilized to compute off-body flow field data. Computations were performed with and without nacelles at several angles of attack. Force and moment data were computed to measure nacelle effects on the aerodynamic characteristics and sonic boom footprints of the model. Pressure signatures were computed both on and off ground-track. Near-field pressure signature computations on ground-track were in good agreement with experimental data. Computed off ground-track signatures showed that maximum pressure peaks were located off ground-track and were significantly higher than the signatures on ground-track. Bow shocks from the nacelle inlets increased lift and drag, and also increased the magnitude of the maximum pressure both on and off ground-track.

  20. Stowage and Deployment of Slit Tube Booms

    NASA Technical Reports Server (NTRS)

    Adams, Larry (Inventor); Turse, Dana (Inventor); Richardson, Doug (Inventor)

    2016-01-01

    A system comprising a boom having a first end, a longitudinal length, and a slit that extends along the longitudinal length of the boom; a drum having an elliptic cross section and a longitudinal length; an attachment mechanism coupled with the first end of the boom and the drum such that the boom and the drum are substantially perpendicular relative to one another; an inner shaft having a longitudinal length, the inner shaft disposed within the drum, the longitudinal length of the inner shaft is aligned substantially parallel with the longitudinal length of the drum, the inner shaft at least partially rotatable relative to the drum, and the inner shaft is at least partially rotatable with the drum; and at least two cords coupled with the inner shaft and portions of the boom near the first end of the boom.

  1. Diagenesis and clay mineral formation at Gale Crater, Mars

    PubMed Central

    Bridges, J C; Schwenzer, S P; Leveille, R; Westall, F; Wiens, R C; Mangold, N; Bristow, T; Edwards, P; Berger, G

    2015-01-01

    The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to constrain the formation conditions of its secondary mineral assemblage. Building on conclusions from sedimentary observations by the Mars Science Laboratory team, we assume diagenetic, in situ alteration. The modeling shows that the mineral assemblage formed by the reaction of a CO2-poor and oxidizing, dilute aqueous solution (Gale Portage Water) in an open system with the Fe-rich basaltic-composition sedimentary rocks at 10–50°C and water/rock ratio (mass of rock reacted with the starting fluid) of 100–1000, pH of ∽7.5–12. Model alteration assemblages predominantly contain phyllosilicates (Fe-smectite, chlorite), the bulk composition of a mixture of which is close to that of saponite inferred from Chemistry and Mineralogy data and to that of saponite observed in the nakhlite Martian meteorites and terrestrial analogues. To match the observed clay mineral chemistry, inhomogeneous dissolution dominated by the amorphous phase and olivine is required. We therefore deduce a dissolving composition of approximately 70% amorphous material, with 20% olivine, and 10% whole rock component. PMID:26213668

  2. Diagenesis and clay mineral formation at Gale Crater, Mars

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bridges, J. C.; Schwenzer, S. P.; Leveille, R.

    The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to constrain the formation conditions of its secondary mineral assemblage. Building on conclusions from sedimentary observations by the Mars Science Laboratory team, we assume diagenetic, in situ alteration. The modeling shows that the mineral assemblage formed by the reaction of a CO₂-poor and oxidizing, dilute aqueous solution (Gale Portage Water)more » in an open system with the Fe-rich basaltic-composition sedimentary rocks at 10–50°C and water/rock ratio (mass of rock reacted with the starting fluid) of 100–1000, pH of ~7.5–12. Model alteration assemblages predominantly contain phyllosilicates (Fe-smectite, chlorite), the bulk composition of a mixture of which is close to that of saponite inferred from Chemistry and Mineralogy data and to that of saponite observed in the nakhlite Martian meteorites and terrestrial analogues. To match the observed clay mineral chemistry, inhomogeneous dissolution dominated by the amorphous phase and olivine is required. We therefore deduce a dissolving composition of approximately 70% amorphous material, with 20% olivine, and 10% whole rock component.« less

  3. Diagenesis and clay mineral formation at Gale Crater, Mars

    DOE PAGES

    Bridges, J. C.; Schwenzer, S. P.; Leveille, R.; ...

    2015-01-18

    The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to constrain the formation conditions of its secondary mineral assemblage. Building on conclusions from sedimentary observations by the Mars Science Laboratory team, we assume diagenetic, in situ alteration. The modeling shows that the mineral assemblage formed by the reaction of a CO₂-poor and oxidizing, dilute aqueous solution (Gale Portage Water)more » in an open system with the Fe-rich basaltic-composition sedimentary rocks at 10–50°C and water/rock ratio (mass of rock reacted with the starting fluid) of 100–1000, pH of ~7.5–12. Model alteration assemblages predominantly contain phyllosilicates (Fe-smectite, chlorite), the bulk composition of a mixture of which is close to that of saponite inferred from Chemistry and Mineralogy data and to that of saponite observed in the nakhlite Martian meteorites and terrestrial analogues. To match the observed clay mineral chemistry, inhomogeneous dissolution dominated by the amorphous phase and olivine is required. We therefore deduce a dissolving composition of approximately 70% amorphous material, with 20% olivine, and 10% whole rock component.« less

  4. Numerous nanopores developed in organo-clay complexes during the shale formations

    NASA Astrophysics Data System (ADS)

    Wang, Q.; Wang, T.; Lu, H.; Liao, J.

    2017-12-01

    Shale gas as new energy resource is either stored in nano pores and microfractures or absorbed on the surface of kerogen and clay aggregate (Chalmers et al., 2012). Nano pores developed in organic matters is very important, because these organic pores have better connectivity than inorganic pores (Loucks et al., 2012) and can form an effective pore system where shale gas flows dominantly (Curtis et al., 2010). In order to figure out how the organic pores is affected by shale compositions, we conduct in-situ FE-SEM and EDS analysis on organic-rich Longmaxi shales. The data indicate that 1) organic matter, mixed with clay minerals, can form an organo-clay complex containing many nanopores; 2)furthermore, larger organic pores are developed in organo-clay complexes with higher clay content than in those with lower clay content(Wang et al., 2017). It seems that the presence of organo-clay complex raises the heterogeneous than pure organic matters. Organo-clay complex may bring in lots of intergranular nanopores between organic matter and clay minerals. Another potential interpretation is that clay minerals may influence kerogen thermal decomposition, generation of hydrocarbons and thus the development of organic pores. The presence of numerous nanopores in organo-clay complexes may promote the connectivity of the pore network and enhance the hydrocarbon production efficiency for shale gas field.

  5. Recent advances in clay mineral-containing nanocomposite hydrogels.

    PubMed

    Zhao, Li Zhi; Zhou, Chun Hui; Wang, Jing; Tong, Dong Shen; Yu, Wei Hua; Wang, Hao

    2015-12-28

    Clay mineral-containing nanocomposite hydrogels have been proven to have exceptional composition, properties, and applications, and consequently have attracted a significant amount of research effort over the past few years. The objective of this paper is to summarize and evaluate scientific advances in clay mineral-containing nanocomposite hydrogels in terms of their specific preparation, formation mechanisms, properties, and applications, and to identify the prevailing challenges and future directions in the field. The state-of-the-art of existing technologies and insights into the exfoliation of layered clay minerals, in particular montmorillonite and LAPONITE®, are discussed first. The formation and structural characteristics of polymer/clay nanocomposite hydrogels made from in situ free radical polymerization, supramolecular assembly, and freezing-thawing cycles are then examined. Studies indicate that additional hydrogen bonding, electrostatic interactions, coordination bonds, hydrophobic interaction, and even covalent bonds could occur between the clay mineral nanoplatelets and polymer chains, thereby leading to the formation of unique three-dimensional networks. Accordingly, the hydrogels exhibit exceptional optical and mechanical properties, swelling-deswelling behavior, and stimuli-responsiveness, reflecting the remarkable effects of clay minerals. With the pivotal roles of clay minerals in clay mineral-containing nanocomposite hydrogels, the nanocomposite hydrogels possess great potential as superabsorbents, drug vehicles, tissue scaffolds, wound dressing, and biosensors. Future studies should lay emphasis on the formation mechanisms with in-depth insights into interfacial interactions, the tactical functionalization of clay minerals and polymers for desired properties, and expanding of their applications.

  6. Activities of the Boom and Chassis Group

    NASA Technical Reports Server (NTRS)

    Dell, Jason Scott; Meeks, Thomas Bayne; Merkel, Kelly; Nelson, Brent; Winchell, Tom

    1992-01-01

    Group One of the NASA Lunar Enabler Project has designed the primary chassis and boom structures for the lunar vehicle. Both components also feature V-clamps that were adapted to interface connections within the structure. The chassis features a front end, rear end section, middle cross-section, and face plate. The rear section contains an extra compartment for the engine, hydraulic pump, fuel bottles, and oil reservoir necessary for the wheel drives. Each section consists of tubular aluminum 6061-T6. The boom features four degrees of freedom system, where the minimum factor of safety of any part is 1.5 (but, normally much higher). It consists of a tapered upper boom, lower boom, and three elbows that complement the articulation joints. Each section of the boom has been constructed from aluminum 6061-T6. There are four joints and eight V-clamps in the boom assembly. The V-clamps feature support rings that prevent axial rotation. They provide easy adaptability and assembly.

  7. Lightweight Boom For Rescue Helicopter

    NASA Technical Reports Server (NTRS)

    Haslim, Leonard A.

    1993-01-01

    Telescoping boom and associated mechanisms attached to helicopter aid rescue operations by extending lifeline beyond sweep of main rotor. Pilot observes rescuee and control position of helicopter more effectively than if rescuee directly below and hidden from pilot's view. Rescuee outside downdraft of rotor, which is often powerful enough to blow away or submerge someone in water. Used for marine or land operations. Boom thin and lightweight because it need not support weight of rescuee. Lifeline pulls away from boom after secured around rescuee, who is lifted directly into cabin by winch. Potential application for in situ erection of telescopic space structures.

  8. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Panelists Peter Iosifidis, program manager, Low-Boom Flight Demonstrator, Lockheed Martin Skunk Works, left, Peter Coen, project manager, Commercial Supersonics Technology Project, Langley Research Center, NASA, center, and Dr. Ed Waggoner, program director, Integrated Aviation Systems Program, NASA, right, are seen behind a model of the Low Boom Flight Demonstrator at a briefing, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  9. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Dr. Ed Waggoner, program director, Integrated Aviation Systems Program, NASA, right, speaks on a panel with Peter Iosifidis, program manager, Low-Boom Flight Demonstrator, Lockheed Martin Skunk Works, left, and Peter Coen, project manager, Commercial Supersonics Technology Project, Langley Research Center, NASA, center, at a briefing on the Low Boom Flight Demonstrator, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  10. NASA Ames Sonic Boom Testing

    NASA Technical Reports Server (NTRS)

    Durston, Donald A.; Kmak, Francis J.

    2009-01-01

    Multiple sonic boom wind tunnel models were tested in the NASA Ames Research Center 9-by 7-Foot Supersonic Wind Tunnel to reestablish related test techniques in this facility. The goal of the testing was to acquire higher fidelity sonic boom signatures with instrumentation that is significantly more sensitive than that used during previous wind tunnel entries and to compare old and new data from established models. Another objective was to perform tunnel-to-tunnel comparisons of data from a Gulfstream sonic boom model tested at the NASA Langley Research Center 4-foot by 4-foot Unitary Plan Wind Tunnel.

  11. Status of sonic boom methodology and understanding

    NASA Technical Reports Server (NTRS)

    Darden, Christine M.; Powell, Clemans A.; Hayes, Wallace D.; George, Albert R.; Pierce, Allan D.

    1989-01-01

    In January 1988, approximately 60 representatives of industry, academia, government, and the military gathered at NASA-Langley for a 2 day workshop on the state-of-the-art of sonic boom physics, methodology, and understanding. The purpose of the workshop was to assess the sonic boom area, to determine areas where additional sonic boom research is needed, and to establish some strategies and priorities in this sonic boom research. Attendees included many internationally recognized sonic boom experts who had been very active in the Supersonic Transport (SST) and Supersonic Cruise Aircraft Research Programs of the 60's and 70's. Summaries of the assessed state-of-the-art and the research needs in theory, minimization, atmospheric effects during propagation, and human response are given.

  12. Unstructured grids for sonic-boom analysis

    NASA Technical Reports Server (NTRS)

    Fouladi, Kamran

    1993-01-01

    A fast and efficient unstructured grid scheme is evaluated for sonic-boom applications. The scheme is used to predict the near-field pressure signatures of a body of revolution at several body lengths below the configuration, and those results are compared with experimental data. The introduction of the 'sonic-boom grid topology' to this scheme make it well suited for sonic-boom applications, thus providing an alternative to conventional multiblock structured grid schemes.

  13. Cryosalt Formation in Delaminated Clays

    NASA Astrophysics Data System (ADS)

    Yeşilbaş, Merve; Boily, Jean-François

    2017-04-01

    -montmorillonite at hosting hydrohalite, the results of this study can be used to suggest that delaminated Na-montmorillonite sheets encapsulate the salt solutions and by preventing sublimation of water, promotes crystallization of hydrohalite. As delamination is not possible in Ca-montmorillonite, water more readily sublimated from the system, leaving behind a dry Ca-montmorillonite/NaCl assemblage. As such, this work identified processes through which clay minerals can affect the formation of cryosalts that are not only of importance to terrestrial environments of the cryosphere but also to atmospheric processes involving dust aerosols. [1] Yeşilbaş, M. and Boily, J.-F. (2016), Scientific Reports. 6, 32136. [2] Yeşilbaş, M. and Boily, J.-F. (2016), J. Phys. Chem. Lett. 7, 2849-2855. [3] Wagner, R., Möhler O., Schnaiter, M. (2012), 33, 8557-8571.

  14. High-Speed Research: Sonic Boom, volume 1

    NASA Technical Reports Server (NTRS)

    Darden, Christine M. (Compiler)

    1992-01-01

    A High-Speed Sonic Boom Workshop was held at LaRC of Feb. 25-27, 1992. The purpose was to make presentations on current research activities and accomplishments and to assess progress in the area of sonic boom since the program was initiated in FY-90. Twenty-nine papers were presented during the 2-1/2 day workshop. Attendees included representatives from academia, industry, and government who are actively involved in sonic-boom research. Volume 1 contains papers related to atmospheric effects on the sonic-boom signature during propagation and on acceptability studies.

  15. Silica, Alumina and Clay Catalyzed Peptide Bond Formation: Enhanced Efficiency of Alumina Catalyst

    NASA Astrophysics Data System (ADS)

    Bujdák, Juraj; Rode, Bernd M.

    1999-10-01

    Catalytic efficiencies of clay (hectorite), silica and alumina were tested in peptide bond formation reactions of glycine (Gly), alanine (Ala), proline (Pro), valine (Val) and leucine (Leu). The reactions were performed as drying/wetting (hectorite) and temperature fluctuation (silica and alumina) experiments at 85 °C. The reactivity of amino acids decreased in order Gly > Ala > Pro ~ Val ~ Leu. The highest catalytic efficiency was observed for alumina, the only catalyst producing oligopeptides in all investigated reaction systems. The peptide bond formation on alumina is probably catalyzed by the same sites and via similar reaction mechanisms as some alumina-catalyzed dehydration reactions used in industrial chemistry.

  16. USM3D Analysis of Low Boom Configuration

    NASA Technical Reports Server (NTRS)

    Carter, Melissa B.; Campbell, Richard L.; Nayani, Sudheer N.

    2011-01-01

    In the past few years considerable improvement was made in NASA's in house boom prediction capability. As part of this improved capability, the USM3D Navier-Stokes flow solver, when combined with a suitable unstructured grid, went from accurately predicting boom signatures at 1 body length to 10 body lengths. Since that time, the research emphasis has shifted from analysis to the design of supersonic configurations with boom signature mitigation In order to design an aircraft, the techniques for accurately predicting boom and drag need to be determined. This paper compares CFD results with the wind tunnel experimental results conducted on a Gulfstream reduced boom and drag configuration. Two different wind-tunnel models were designed and tested for drag and boom data. The goal of this study was to assess USM3D capability for predicting both boom and drag characteristics. Overall, USM3D coupled with a grid that was sheared and stretched was able to reasonably predict boom signature. The computational drag polar matched the experimental results for a lift coefficient above 0.1 despite some mismatch in the predicted lift-curve slope.

  17. High-Speed Research: Sonic Boom, Volume 1

    NASA Technical Reports Server (NTRS)

    Edwards, Thomas A. (Editor)

    1994-01-01

    The second High-Speed Research Program Sonic Boom Workshop was held at NASA Ames Research Center May 12-14, 1993. The workshop was organized into three sessions dealing with atmospheric propagation, acceptability, and configuration design. Volume 1 includes papers on atmospheric propagation and acceptability studies. Significant progress is noted in these areas in the time since the previous workshop a year earlier. In particular, several papers demonstrate an improved capability to model the effect of atmospheric turbulence on sonic booms. This is a key issue in determining the stability and acceptability of shaped sonic booms. In the area of acceptability, the PLdB metric has withstood considerable scrutiny and is validated as a loudness metric for a wide variety of sonic boom shapes. The differential loudness of asymmetric sonic booms is better understood, too.

  18. Affordable Housing and the Empty Nester Boom.

    ERIC Educational Resources Information Center

    Hare, Patrick H.

    One of the best ways to produce affordable housing is to address the needs of a group that has too much housing. A baby boom generation generates an empty nester boom. An empty nester boom means dramatic underutilization of the housing stock. If a small percentage of homeowners were to install an accessory apartment, they would have a significant…

  19. High-Speed Research: Sonic Boom, volume 2

    NASA Technical Reports Server (NTRS)

    Darden, Christine M. (Compiler)

    1992-01-01

    A High-Speed Sonic Boom Workshop was held at NASA Langley Research Center on February 25-27, 1992. The purpose of the workshop was to make presentations on current research activities and accomplishments and to assess progress in the area of sonic boom since the program was initiated in FY-90. Twenty-nine papers were presented during the 2-1/2 day workshop. Attendees included representatives from academia, industry, and government who are actively involved in sonic-boom research. Volume 2 contains papers related to low sonic-boom design and analysis using both linear theory and higher order computational fluid dynamics (CFD) methods.

  20. Waveforms and Sonic Boom Perception and Response (WSPR): Low-Boom Community Response Program Pilot Test Design, Execution, and Analysis

    NASA Technical Reports Server (NTRS)

    Page, Juliet A.; Hodgdon, Kathleen K.; Krecker, Peg; Cowart, Robbie; Hobbs, Chris; Wilmer, Clif; Koening, Carrie; Holmes, Theresa; Gaugler, Trent; Shumway, Durland L.; hide

    2014-01-01

    The Waveforms and Sonic boom Perception and Response (WSPR) Program was designed to test and demonstrate the applicability and effectiveness of techniques to gather data relating human subjective response to multiple low-amplitude sonic booms. It was in essence a practice session for future wider scale testing on naive communities, using a purpose built low-boom demonstrator aircraft. The low-boom community response pilot experiment was conducted in California in November 2011. The WSPR team acquired sufficient data to assess and evaluate the effectiveness of the various physical and psychological data gathering techniques and analysis methods.

  1. Development of a Strain Energy Deployable Boom for the Space Technology 5 Mission

    NASA Technical Reports Server (NTRS)

    Meyers, Stew; Sturm, James

    2004-01-01

    The Space Technology 5 (ST5) mission is one of a series of technology demonstration missions for the New Millennium Program. This mission will fly three fully functional 25-kilogram micro-class spacecraft in formation through the Earth's magnetosphere; the primary science instrument is a very sensitive magnetometer. The constraints of a 25-kg Micosat resulted in a spin stabilized, octagonal spacecraft that is 30 cm tall by 50 cm diameter and has state-of-the-art solar cells on all eight sides. A non-magnetic boom was needed to place the magnetometer as far from the spacecraft and its residual magnetic fields as possible. The ST-5 spacecraft is designed to be spun up and released from its deployer with the boom and magnetometer stowed for later release. The deployer is the topic of another paper. This paper describes the development efforts and resulting self-deploying magnetometer boom.

  2. Development of a Strain Energy Deployable Boom for the Space Technology 5 Mission

    NASA Technical Reports Server (NTRS)

    Meyers, Stew; Sturm, James

    2004-01-01

    The Space Technology 5 (ST5) mission is one of a series of technology demonstration missions for the New Millennium Program. This mission will fly three fully functional 25 kilogram micro class spacecraft in formation through the Earth s magnetosphere; the primary science instrument is a very sensitive magnetometer. The constraints of a 25 kg "Micosat" resulted in a spin stabilized, octagonal spacecraft that is 30 cm tall by 50 cm diameter and has state of the art solar cells on all eight sides. A non-magnetic boom was needed to place the magnetometer as far from the spacecraft and its residual magnetic fields as possible. The ST-5 spacecraft is designed to be spun up and released from its deployer with the boom and magnetometer stowed for later release. The deployer is the topic of another paper, This paper describes the development efforts and resulting self-deploying magnetometer boom.

  3. A Study of Reflected Sonic Booms Using Airborne Measurements

    NASA Technical Reports Server (NTRS)

    Kantor, Samuel R.; Cliatt, Larry J., II

    2017-01-01

    In support of ongoing efforts to bring commercial supersonic flight to the public, the Sonic Booms in Atmospheric Turbulence (SonicBAT) flight test was conducted at NASA Armstrong Flight Research Center. During this test, airborne sonic boom measurements were made using an instrumented TG-14 motor glider, called the Airborne Acoustic Measurement Platform (AAMP).During the flight program, the AAMP was consistently able to measure the sonic boom wave that was reflected off of the ground, in addition to the incident wave, resulting in the creation of a completely unique data set of airborne sonic boom reflection measurements. This paper focuses on using this unique data set to investigate the ability of sonic boom modeling software to calculate sonic boom reflections. Because the algorithms used to model sonic boom reflections are also used to model the secondary carpet and over the top booms, the use of actual flight data is vital to improving the understanding of the effects of sonic booms outside of the primary carpet. Understanding these effects becomes especially important as the return of commercial supersonic approaches, as well as ensuring the accuracy of mission planning for future experiments.

  4. Clay-catalyzed reactions of coagulant polymers during water chlorination

    USGS Publications Warehouse

    Lee, J.-F.; Liao, P.-M.; Lee, C.-K.; Chao, H.-P.; Peng, C.-L.; Chiou, C.T.

    2004-01-01

    The influence of suspended clay/solid particles on organic-coagulant reactions during water chlorination was investigated by analyses of total product formation potential (TPFP) and disinfection by-product (DBP) distribution as a function of exchanged clay cation, coagulant organic polymer, and reaction time. Montmorillonite clays appeared to act as a catalytic center where the reaction between adsorbed polymer and disinfectant (chlorine) was mediated closely by the exchanged clay cation. The transition-metal cations in clays catalyzed more effectively than other cations the reactions between a coagulant polymer and chlorine, forming a large number of volatile DBPs. The relative catalytic effects of clays/solids followed the order Ti-Mont > Fe-Mont > Cu-Mont > Mn-Mont > Ca-Mont > Na-Mont > quartz > talc. The effects of coagulant polymers on TPFP follow the order nonionic polymer > anionic polymer > cationic polymer. The catalytic role of the clay cation was further confirmed by the observed inhibition in DBP formation when strong chelating agents (o-phenanthroline and ethylenediamine) were added to the clay suspension. Moreover, in the presence of clays, total DBPs increased appreciably when either the reaction time or the amount of the added clay or coagulant polymer increased. For volatile DBPs, the formation of halogenated methanes was usually time-dependent, with chloroform and dichloromethane showing the greatest dependence. ?? 2003 Elsevier Inc. All rights reserved.

  5. Graphite Composite Booms with Integral Hinges

    NASA Technical Reports Server (NTRS)

    Alexander, Wes; Carlos, Rene; Rossoni, Peter; Sturm, James

    2006-01-01

    A document discusses lightweight instrument booms under development for use aboard spacecraft. A boom of this type comprises a thin-walled graphite fiber/ matrix composite tube with an integral hinge that can be bent for stowage and later allowed to spring back to straighten the boom for deployment in outer space. The boom design takes advantage of both the stiffness of the composite in tubular geometry and the flexibility of thin sections of the composite. The hinge is formed by machining windows in the tube at diametrically opposite locations so that there remain two opposing cylindrical strips resembling measuring tapes. Essential to the design is a proprietary composite layup that renders the hinge tough yet flexible enough to be bendable as much as 90 in either of two opposite directions. When the boom is released for deployment, the torque exerted by the bent hinge suffices to overcome parasitic resistance from harnesses and other equipment, so that the two sections of the hinge snap to a straight, rigid condition in the same manner as that of measuring tapes. Issues addressed in development thus far include selection of materials, out-of-plane bending, edge cracking, and separation of plies.

  6. What is that mysterious booming sound?

    USGS Publications Warehouse

    Hill, David P.

    2011-01-01

    The residents of coastal North Carolina are occasionally treated to sequences of booming sounds of unknown origin. The sounds are often energetic enough to rattle windows and doors. A recent sequence occurred in early January 2011 during clear weather with no evidence of local thunder storms. Queries by a local reporter (Colin Hackman of the NBC affiliate WETC in Wilmington, North Carolina, personal communication 2011) seemed to eliminate common anthropogenic sources such as sonic booms or quarry blasts. So the commonly asked question, “What's making these booming sounds?” remained (and remains) unanswered.

  7. Display Provides Pilots with Real-Time Sonic-Boom Information

    NASA Technical Reports Server (NTRS)

    Haering, Ed; Plotkin, Ken

    2013-01-01

    Supersonic aircraft generate shock waves that move outward and extend to the ground. As a cone of pressurized air spreads across the landscape along the flight path, it creates a continuous sonic boom along the flight track. Several factors can influence sonic booms: weight, size, and shape of the aircraft; its altitude and flight path; and weather and atmospheric conditions. This technology allows pilots to control the impact of sonic booms. A software system displays the location and intensity of shock waves caused by supersonic aircraft. This technology can be integrated into cockpits or flight control rooms to help pilots minimize sonic boom impact in populated areas. The system processes vehicle and flight parameters as well as data regarding current atmospheric conditions. The display provides real-time information regarding sonic boom location and intensity, enabling pilots to make the necessary flight adjustments to control the timing and location of sonic booms. This technology can be used on current-generation supersonic aircraft, which generate loud sonic booms, as well as future- generation, low-boom aircraft, anticipated to be quiet enough for populated areas.

  8. A loudness calculation procedure applied to shaped sonic booms

    NASA Technical Reports Server (NTRS)

    Shepherd, Kevin P.; Sullivan, Brenda M.

    1991-01-01

    Described here is a procedure that can be used to calculate the loudness of sonic booms. The procedure is applied to a wide range of sonic booms, both classical N-waves and a variety of other shapes of booms. The loudness of N-waves is controlled by overpressure and the associated rise time. The loudness of shaped booms is highly dependent on the characteristics of the initial shock. A comparison of the calculated loudness values indicates that shaped booms may have significantly reduced loudness relative to N-waves having the same peak overpressure. This result implies that a supersonic transport designed to yield minimized sonic booms may be substantially more acceptable than an unconstrained design.

  9. A Compilation of Space Shuttle Sonic Boom Measurements

    NASA Technical Reports Server (NTRS)

    Maglieri, Domenic J.; Henderson, Herbert R.; Massey, Steven J.; Stansbery, Eugene G.

    2011-01-01

    Sonic boom measurements have been obtained on 26 flights of the Space Shuttle system beginning with the launch of STS-1 on April 12, 1981, to the reentry-descent of STS-41 into EAFB on Oct. 10, 1990. A total of 23 boom measurements were acquired within the focus region off the Florida coast during 3 STS launch-ascents and 113 boom measurements were acquired during 23 STS reentry-descent to landing into Florida and California. Sonic boom measurements were made under, and lateral to, the vehicle ground track and cover the Mach-altitude range of about 1.3 to 23 and 54,000 feet to 243,000 feet, respectively. Vehicle operational data, flight profiles and weather data were also gathered during the flights. This STS boom database is contained in 26 documents, some are formal and referenceable but most internal documents. Another 38 documents, also non-referenceable, contain predicted sonic boom footprints for reentry-descent flights on which no measurements were made. The purpose of this report is to provide an overview of the STS sonic boom database and summarize the main findings.

  10. Potential for Sonic Boom Reduction of the Boeing HSCT

    NASA Technical Reports Server (NTRS)

    Haglund, George T.

    1999-01-01

    The HSR sonic boom technology program includes a goal of reducing the objectionable aspects of sonic boom. Earlier HSCT sonic boom studies considered achieving significant sonic boom reduction by the use of arrow-wing planforms and detailed shaping of the airplane to produce shaped waveforms (non N-waves) at the ground. While these design efforts were largely successful, the added risk and cost of the airplanes were judged to be unacceptable. The objective of the current work is to explore smaller configuration refinements that could lead to reduced sonic boom impact, within design and operational constraints. A somewhat modest target of 10% reduction in sonic boom maximum overpressure was selected to minimize the effect on the configuration performance. This work was a joint NASA/Industry effort, utilizing the respective strengths of team members at Boeing, NASA Langley, and NASA Ames. The approach used was to first explore a wide range of modifications and airplane characteristics for their effects on sonic boom and drag, using classical Modified Linear Theory (MLT) methods. CFD methods were then used to verify promising, modifications and to analyze modifications for which the MLT methods were not appropriate. The tea m produced a list of configuration changes with their effects on sonic boom and, in some cases, an estimate of the drag penalty. The most promising modifications were applied to produce a boom-softened derivative of the baseline Boeing High Speed Civil Transport (HSCT) configuration. This boom-softened configuration was analyzed in detail for the reduce sonic boom impact and also for the effect of the configuration modifications on drag, weight, and overall performance relative to the baseline.

  11. PARTNER Project 8: Sonic boom mitigation

    NASA Astrophysics Data System (ADS)

    Sparrow, Victor W.

    2005-09-01

    Current U.S. and international laws prohibit commercial supersonic flight over land due to the impact of conventional sonic boom noise. Aircraft manufacturers, however, now have modern computational fluid dynamics and optimization tools, unavailable when those laws were enacted, that will allow them to design and build aircraft with boom signatures that are substantially smoothed compared with traditional N-waves. One purpose of the FAA/NASA/Transport Canada PARTNER Center of Excellence Project 8 is to determine exactly which waveforms would be heard by the public if low-boom supersonic aircraft are put into service. Another purpose is to ascertain the acceptability of those waveforms. The project involves the following universities, government, and industry partners: Penn State, Purdue, Stanford, the National Aeronautics and Space Administration, the Federal Aviation Administration, Boeing, Cessna, Gulfstream, Lockheed-Martin, and Wyle Laboratories. Some of the initial project work includes studies on the propagation of sonic booms through atmospheric turbulence, on the mutual reproducibility of three sonic boom simulators, and on the realism of those simulators as determined by expert listeners. The results of all the studies are intended to provide the FAA with new data to reassess current regulations. [Work supported by NASA, the FAA, and the PARTNER industrial partners.

  12. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    A model of the first Low Boom Flight Demonstrator is seen at a briefing on Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  13. The Effect of Sonic Booms on Earthquake Warning Systems

    NASA Technical Reports Server (NTRS)

    Wurman, Gilead; Haering, Edward A, Jr.; Price, Michael J.

    2011-01-01

    Several aerospace companies are designing quiet supersonic business jets for service over the United States. These aircraft have the potential to increase the occurrence of mild sonic booms across the country. This leads to interest among earthquake warning (EQW) developers and the general seismological community in characterizing the effect of sonic booms on seismic sensors in the field, their potential impact on EQW systems, and means of discriminating their signatures from those of earthquakes. The SonicBREWS project (Sonic Boom Resistant Earthquake Warning Systems) is a collaborative effort between Seismic Warning Systems, Inc. (SWS) and NASA Dryden Flight Research Center. This project aims to evaluate the effects of sonic booms on EQW sensors. The study consists of exposing high-sample-rate (1000 sps) triaxial accelerometers to sonic booms with overpressures ranging from 10 to 600 Pa in the free field and the built environment. The accelerometers record the coupling of the sonic boom to the ground and surrounding structures, while microphones record the acoustic wave above ground near the sensor. Sonic booms are broadband signals with more high-frequency content than earthquakes. Even a 1000 sps accelerometer will produce a significantly aliased record. Thus the observed peak ground velocity is strongly dependent on the sampling rate, and increases as the sampling rate is reduced. At 1000 sps we observe ground velocities that exceed those of P-waves from ML 3 earthquakes at local distances, suggesting that sonic booms are not negligible for EQW applications. We present the results of several experiments conducted under SonicBREWS showing the effects of typical-case low amplitude sonic booms and worst-case high amplitude booms. We show the effects of various sensor placements and sensor array geometries. Finally, we suggest possible avenues for discriminating sonic booms from earthquakes for the purposes of EQW.

  14. VIS/NIR Spectroscopy to determine the spatial variation of the weathering degree in Paleogene clay soil - London Clay Formation

    NASA Astrophysics Data System (ADS)

    Nasser, Mohammed; Gibson, Andy, ,, Dr; Koor, Nick, ,, Dr; Gale, Professor Andy; Huggett, Jenny, ,, Dr; Branch, Steve

    2017-04-01

    The London Clay Formation (LCF) which underlies much of South-East England is hugely important as a construction medium. However, its geotechnical performance (shear strength, compressive strength, shrink-swell behaviour, etc. ) is greatly affected by its degree of weathering. Despite this importance, little attention has been focussed on a robust method to define and measure its degree of weathering. This is perhaps a result of a well-known colour change from bluish-grey to brown that accompanies 'weathering' and considered to be the result of oxidisation (Chandler and Apted 1988). Through wide experience, this definition is normally effective, but it is perhaps subjective and reliant on the experience of the investigator and the ability to observe samples or exposures. More objective investigation, typically using SEM is not normally economically feasible or expedient for construction works. We propose a simple, robust method to characterise the degree of weathering in the LCF using reflective or Visible-Near-InfraRed-Spectroscopy (VNIRS). 24 samples were extracted from 2 boreholes drilled in the Hampstead area of London to depths of 12 m within the uppermost Claygate Member of the LCF. VNIRS spectra (350-2500 nm) were measured from all samples and compared with XRD, XRF, SEM and PSD results on the same samples. Results show increased magnitude of absorption features related to clay mineralogy around 1400, 1900 and 2200 nm to a depth of 5 m beneath ground level. Beneath this depth, the absorption features show little variation. SEM analyses show corresponding changes in the degradation of pyrite crystals and individual clay (illite/smectite). These preliminary results show that there is a good potential for VNIRS spectroscopy to determine the variation of weathering in the LCF.

  15. Clays as possible catalysts for peptide formation in the prebiotic era

    NASA Technical Reports Server (NTRS)

    Paecht-Horowitz, M.

    1976-01-01

    From the point of view of prebiotic synthesis, clays might have performed functions of concentration, catalysis, and protection of molecules. The degrees of polymerization obtained, when amino acid adenylates are added to montmorillonite suspensions in water, are much higher than those obtained by polymerization in the absence of such a clay. In addition, they are of a discrete spectrum, usually multiples of 6 or 7, and reach values of up to 40 mers. In the absence of clay a continuous spectrum of degrees of polymerization is obtained, and usually up to 4-6 mers only. Copolymerization in the absence of clays yields mostly random copolymers, in their presence mostly block copolymers are obtained. Optical density measurements show that after adsorption has taken place on the clay, stacking of its layers occurs. Polymerization starts only after these stacked layers have been formed

  16. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    J.D. Harrington, public affairs officer, Aeronautics Mission Directorate, NASA, speaks at a briefing on the Low Boom Flight Demonstrator, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  17. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Dr. Ed Waggoner, program director, Integrated Aviation Systems Program, NASA, speaks at a briefing on the Low Boom Flight Demonstrator, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  18. Real-Time, Interactive Sonic Boom Display

    NASA Technical Reports Server (NTRS)

    Haering, Jr., Edward A. (Inventor); Plotkin, Kenneth J. (Inventor)

    2012-01-01

    The present invention is an improved real-time, interactive sonic boom display for aircraft. By using physical properties obtained via various sensors and databases, the invention determines, in real-time, sonic boom impacts locations and intensities for aircraft traveling at supersonic speeds. The information is provided to a pilot via a display that lists a selectable set of maneuvers available to the pilot to mitigate sonic boom issues. Upon selection of a maneuver, the information as to the result of the maneuver is displayed and the pilot may proceed with making the maneuver, or provide new data to the system in order to calculate a different maneuver.

  19. Experimental and Computational Sonic Boom Assessment of Boeing N+2 Low Boom Models

    NASA Technical Reports Server (NTRS)

    Durston, Donald A.; Elmiligui, Alaa; Cliff, Susan E.; Winski, Courtney S.; Carter, Melissa B.; Walker, Eric L.

    2015-01-01

    Near-field pressure signatures were measured and computational predictions made for several sonic boom models representing Boeing's Quiet Experimental Validation Concept (QEVC) supersonic transport, as well as three axisymmetric calibration models. Boeing developed the QEVC under a NASA Research Announcement (NRA) contract for Experimental Systems Validations for N+2 Supersonic Commercial Transport Aircraft, which was led by the NASA High Speed Project under the Fundamental Aeronautics Program. The concept was designed to address environmental and performance goals given in the NRA, specifically for low sonic boom loudness levels and high cruise efficiency, for an aircraft anticipated to enter service in the 2020 timeframe. Wind tunnel tests were conducted on the aircraft and calibration models during Phases I and II of the NRA contract from 2011 to 2013 in the NASA Ames 9- by 7-Foot and NASA Glenn 8- by 6-Foot Supersonic Wind Tunnels. Sonic boom pressure signatures were acquired primarily at Mach 1.6 and 1.8, and force and moment data were acquired from Mach 0.8 to 1.8. The sonic boom test data were obtained using a 2-in. flat-top pressure rail and a 14-in. round-top tapered "reflection factor 1" (RF1) pressure rail. Both rails capture an entire pressure signature in one data point, and successive signatures at varying positions along or above the rail were used to improve data quality through spatial averaging. The sonic boom data obtained by the rails were validated with high-fidelity numerical simulations of off-body pressures using the CFD codes USM3D, Cart3D, and OVERFLOW. The test results from the RF1 rail showed good agreement between the computational and experimental data when a variety of testing techniques including spatial averaging of a series of pressure signatures were employed, however, reflections off the 2-in. flat-top rail caused distortions in the signatures that did not agree with the CFD predictions. The 9 x 7 and 8 x 6 wind tunnels generally

  20. Mineral catalysis of the formation of the phosphodiester bond in aqueous solution: The possible role of montmorillonite clays

    NASA Astrophysics Data System (ADS)

    Ferris, James P.; Ertem, Gözen; Kamaluddin; Agarwal, Vipin; Hua, Lu Lin

    The binding of adenosine to Na+-montmorillonite 22A is greater than 5'-AMP, at neutral pH. Adenine derivatives bind more strongly to the clay than the corresponding uracil derivatives. These data are consistent with the protonation of the adenine by the acidic clay surface and a cationic binding of the protonated ring to the anionic clay surface. Other forces must be operative in the binding of uracil derivatives to the clay since the uracil ring system is not basic. The reaction of the 5'-AMP with water soluble carbodiimide in the presence of Na+-montmorillonite results in the formation of 2',5'-pApA (18.9%), 3',5'-pApA (11%), and AppA (4.8%). When poly(U) is used in place of the clay the product yields are 2',5',-pApA (15.5%), 3',5'-pApA (3.7%) and AppA (14.9%). The cyclic nucleotide, c(pA)2 is also formed when poly(U) is used. AppA is the principal reaction product when neither clay nor poly(U) is present in the reaction mixture. When 2'-deoxy-5'-AMP reacts with carbodiimide in the presence of Na+-montmorillonite 22A the products are dpApA (4.8%), dAppApA (4.5%) and dAppA (17.4%). Cyclic 3',5'-dAMP is the main product (14%) of the reaction of 2'-deoxy-3'-AMP.

  1. Loudness and annoyance response to simulated outdoor and indoor sonic booms

    NASA Technical Reports Server (NTRS)

    Leatherwood, Jack D.; Sullivan, Brenda M.

    1993-01-01

    The sonic boom simulator of the Langley Research Center was used to quantify subjective loudness and annoyance response to simulated indoor and outdoor sonic boom signatures. The indoor signatures were derived from the outdoor signatures by application of house filters that approximated the noise reduction characteristics of a residential structure. Two indoor listening situations were simulated: one with the windows open and the other with the windows closed. Results were used to assess loudness and annoyance as sonic boom criterion measures and to evaluate several metrics as estimators of loudness and annoyance. The findings indicated that loudness and annoyance were equivalent criterion measures for outdoor booms but not for indoor booms. Annoyance scores for indoor booms were significantly higher than indoor loudness scores. Thus, annoyance was recommended as the criterion measure of choice for general use in assessing sonic boom subjective effects. Perceived level was determined to be the best estimator of annoyance for both indoor and outdoor booms, and of loudness for outdoor booms. It was recommended as the metric of choice for predicting sonic boom subjective effects.

  2. Surveying Clay Mineral Diversity in the Murray Formation, Gale Crater, Mars

    NASA Technical Reports Server (NTRS)

    Bristow, T. F.; Blake, D. F.; Vaniman, D. T.; Chipera, S. J.; Rampe, E. B.; Grotzinger, J. P.; McAdam, A. C.; Ming, D. W.; Morrison, S. M.; Yen, A. S.; hide

    2017-01-01

    One of the primary science goals of Mars Science Laboratory (MSL) is to investigate layered clay mineral-bearing deposits outcropping in the lower NW slopes of Aeolis Mons (Mt. Sharp) detected from orbit. Martian clay mineral-bearing layered rocks are of particular interest because they are potential markers of sedimentary deposits formed in habitable aqueous environments. The CheMin X-ray diffraction (XRD) instrument aboard MSL has documented clay minerals in various drill samples during its traverse of Gale Crater's floor and ascent of Mt. Sharp. Previously, the high concentrations of clay minerals (approximately 20 wt.%) detected in drill powders of mudstone (Sheepbed member) at Yellowknife Bay (YKB) allowed their detailed characterization. Drill powders recovered from lacustrine mudstones of the Sheepbed member at YKB contain smectite clay minerals. Based on the position of 02l reflections in XRD patterns, which serve as an indicator of octahedral occupancy, the smectites are Fe-bearing, trioctahedral species analogous to ferrian saponites from terrestrial deposits. The smectites are thought to have been formed through a process of isochemical aqueous alteration of detrital olivine close to the time of sediment deposition under anoxic to poorly oxidizing conditions. The clay minerals are key indicators that the lake waters were benign and habitable at the time. Clay minerals were detected at other locations during MSL's traverse, including samples from the Pahrump Hills, but lower abundances and overlapping peaks from crystalline phases in XRD patterns hamper in-depth analysis.

  3. [Interaction of clay minerals with microorganisms: a review of experimental data].

    PubMed

    Naĭmark, E B; Eroshchev-Shak, V A; Chizhikova, N P; Kompantseva, E I

    2009-01-01

    A review of publications containing results of experiments on the interaction of microorganisms with clay minerals is presented. Bacteria are shown to be involved in all processes related to the transformation of clay minerals: formation of clays from metamorphic and sedimentary rocks, formation of clays from solutions, reversible transitions of different types of clay minerals, and consolidation of clay minerals into sedimentary rocks. Integration of these results allows to conclude that bacteria reproduced all possible abiotic reactions associated with the clay minerals, these reactions proceed much faster with the bacteria being involved. Thus, bacteria act as a living catalyst in the geochemical cycle of clay minerals. The ecological role of bacteria can be considered as a repetition of a chemical process of the abiotic world, but with the use of organic catalytic innovation.

  4. Pedogenic formation of montmorillonite from a 2:1-2:2 intergrade clay mineral

    USGS Publications Warehouse

    Malcolm, R.L.; Nettleton, W.D.; McCracken, R.J.

    1968-01-01

    Montmorillonite was found to be the dominant clay mineral in surface horizons of certain soils of the North Carolina Coastal Plain whereas a 2:1-2:2 intergrade clay mineral was dominant in subjacent horizons. In all soils where this clay mineral sequence was found, the surface horizon was low in pH (below 4⋅5) and high in organic matter content. In contrast, data from studies of other soils of this region (Weed and Nelson, 1962) show that: (1) montmorillonite occurs infrequently; (2) maximum accumulation of the 2:1-2:2 intergrade normally occurs in the surface horizon and decreases with depth in the profile; (3) organic matter contents are low; and (4) pH values are only moderately acid (pH 5-6).It is theorized that the montmorillonite in the surface horizon of the soils studied originated by pedogenic weathering of the 2:1-2:2 intergrade clay mineral. The combined effects of low pH (below 4⋅5) and high organic matter content in surface horizons are believed to be the agents responsible for this mineral transformation. The protonation and solubilization (reverse of hydrolysis) of Al-polymers in the interlayer of expansible clay minerals will occur at or below pH 4⋅5 depending on the charge and steric effects of the interlayer. A low pH alone may cause this solubilization and thus mineral transformation, but in the soils studied the organic matter is believed to facilitate and accelerage the transformation. The intermediates of organic matter decomposition provide an acid environment, a source of protons, and a source of watersoluble mobile organic substances (principally fulvic acids) which have the ability to complex the solubilized aluminum and move it down the profile. This continuous removal of solubilized aluminum would provide for a favorable gradient for aluminum solubilization.The drainage class or position in a catena is believed to be less important than the chemical factors in formation of montmorillonite from 2:1-2:2 intergrade, because

  5. Semianalytical solutions for transport in aquifer and fractured clay matrix system

    NASA Astrophysics Data System (ADS)

    Huang, Junqi; Goltz, Mark N.

    2015-09-01

    A three-dimensional mathematical model that describes transport of contaminant in a horizontal aquifer with simultaneous diffusion into a fractured clay formation is proposed. A group of semianalytical solutions is derived based on specific initial and boundary conditions as well as various source functions. The analytical model solutions are evaluated by numerical Laplace inverse transformation and analytical Fourier inverse transformation. The model solutions can be used to study the fate and transport in a three-dimensional spatial domain in which a nonaqueous phase liquid exists as a pool atop a fractured low-permeability clay layer. The nonaqueous phase liquid gradually dissolves into the groundwater flowing past the pool, while simultaneously diffusing into the fractured clay formation below the aquifer. Mass transfer of the contaminant into the clay formation is demonstrated to be significantly enhanced by the existence of the fractures, even though the volume of fractures is relatively small compared to the volume of the clay matrix. The model solution is a useful tool in assessing contaminant attenuation processes in a confined aquifer underlain by a fractured clay formation.

  6. Thermal Deformation of Very Slender Triangular Rollable and Collapsible Booms

    NASA Technical Reports Server (NTRS)

    Stohlman, Olive R.; Loper, Erik R.

    2016-01-01

    Metallic triangular rollable and collapsible (TRAC) booms have deployed two Cubesat-based solar sails in low Earth orbit, making TRAC booms the most popular solar sail deployment method in practice. This paper presents some concerns and solutions surrounding the behavior of these booms in the space thermal environment. A 3.5-cm-tall, 4-meter-long TRAC boom of Elgiloy cobalt alloy, when exposed to direct sunlight in a 1 AU deep space environment, has a predicted tip motion of as much as 0.5 meters. Such large thermal deflections could generate unacceptable distortions in the shape of a supported solar sail, making attitude control of the solar sail spacecraft difficult or impossible. As a possible means of mitigating this issue, the thermal distortion behaviors of three alternative material TRAC booms are investigated and compared with the uncoated Elgiloy baseline boom. A tenfold decrease in induced curvature is shown to be possible relative to the baseline boom. Potential thermal distortions of the LightSail-A solar sail TRAC booms are also examined and compared, although inconclusively, with available on-orbit camera imagery.

  7. Mixed-Fidelity Approach for Design of Low-Boom Supersonic Aircraft

    NASA Technical Reports Server (NTRS)

    Li, Wu; Shields, Elwood; Geiselhart, Karl

    2011-01-01

    This paper documents a mixed-fidelity approach for the design of low-boom supersonic aircraft with a focus on fuselage shaping.A low-boom configuration that is based on low-fidelity analysis is used as the baseline. The fuselage shape is modified iteratively to obtain a configuration with an equivalent-area distribution derived from computational fluid dynamics analysis that attempts to match a predetermined low-boom target area distribution and also yields a low-boom ground signature. The ground signature of the final configuration is calculated by using a state-of-the-art computational-fluid-dynamics-based boom analysis method that generates accurate midfield pressure distributions for propagation to the ground with ray tracing. The ground signature that is propagated from a midfield pressure distribution has a shaped ramp front, which is similar to the ground signature that is propagated from the computational fluid dynamics equivalent-area distribution. This result supports the validity of low-boom supersonic configuration design by matching a low-boom equivalent-area target, which is easier to accomplish than matching a low-boom midfield pressure target.

  8. Boron Enrichment in Martian Clay

    PubMed Central

    Nagashima, Kazuhide; Freeland, Stephen J.

    2013-01-01

    We have detected a concentration of boron in martian clay far in excess of that in any previously reported extra-terrestrial object. This enrichment indicates that the chemistry necessary for the formation of ribose, a key component of RNA, could have existed on Mars since the formation of early clay deposits, contemporary to the emergence of life on Earth. Given the greater similarity of Earth and Mars early in their geological history, and the extensive disruption of Earth's earliest mineralogy by plate tectonics, we suggest that the conditions for prebiotic ribose synthesis may be better understood by further Mars exploration. PMID:23762242

  9. Transport of Organic Solutes in Clay Formations

    EPA Science Inventory

    The research is a pilot investigation for the SERDP (Strategic Environmental Research and Development Program, DoD) founded project, Impact of Clay-DNAPL Interactions on Transport and Storage of Chlorinated Solvents in Low Permeability Zones, from 2010-2012. The report tries to s...

  10. Do scaly clays control seismicity on faulted shale rocks?

    NASA Astrophysics Data System (ADS)

    Orellana, Luis Felipe; Scuderi, Marco M.; Collettini, Cristiano; Violay, Marie

    2018-04-01

    One of the major challenges regarding the disposal of radioactive waste in geological formations is to ensure isolation of radioactive contamination from the environment and the population. Shales are suitable candidates as geological barriers. However, the presence of tectonic faults within clay formations put the long-term safety of geological repositories into question. In this study, we carry out frictional experiments on intact samples of Opalinus Clay, i.e. the host rock for nuclear waste storage in Switzerland. We report experimental evidence suggesting that scaly clays form at low normal stress (≤20 MPa), at sub-seismic velocities (≤300 μm/s) and is related to pre-existing bedding planes with an ongoing process where frictional sliding is the controlling deformation mechanism. We have found that scaly clays show a velocity-weakening and -strengthening behaviour, low frictional strength, and poor re-strengthening over time, conditions required to allow the potential nucleation and propagation of earthquakes within the scaly clays portion of the formation. The strong similarities between the microstructures of natural and experimental scaly clays suggest important implications for the slip behaviour of shallow faults in shales. If natural and anthropogenic perturbations modify the stress conditions of the fault zone, earthquakes might have the potential to nucleate within zones of scaly clays controlling the seismicity of the clay-rich tectonic system, thus, potentially compromising the long-term safeness of geological repositories situated in shales.

  11. Subjective Response to Simulated Sonic Booms in Homes

    NASA Technical Reports Server (NTRS)

    McCurdy, David A.; Brown, Sherilyn A.

    1996-01-01

    One of the environmental issues affecting the development of a second-generation supersonic commercial transport is the impact of sonic booms on people. Aircraft designers are attempting to design the transport to produce sonic boom signatures that will have minimum impact on the public. Current supersonic commercial aircraft produce an 'N-wave' sonic boom pressure signature that is considered unacceptable by the public. This has resulted in first-generation supersonic transports being banned from flying supersonic over land in the United States, a severe economic constraint. By tailoring aircraft volume and lift distributions, designers hope to produce sonic boom signatures having specific shapes other than 'N-wave' that may be more acceptable to the public. As part of the effort to develop a second-generation supersonic commercial transport, Langley Research Center is conducting research to study people's subjective response to sonic booms. As part of that research, a system was developed for performing studies of the subjective response of people to the occurrence of simulated sonic booms in their homes. The In-Home Noise Generation/Response System (IHONORS) provides a degree of situational realism not available in the laboratory and a degree of control over the noise exposure not found in community surveys. The computer-controlled audio system generates the simulated sonic booms, measures the noise levels, and records the subjects' ratings and can be placed and operated in individual homes for extended periods of time. The system was used to conduct an in-home study of subjective response to simulated sonic booms. The primary objective of the study was to determine the effect on annoyance of the number of sonic boom occurrences in a realistic environment. The effects on annoyance of several other parameters were also examined. Initially, data analyses were based on all the data collected. However, further analyser found that test subjects adapted to the sonic

  12. Geology and Refractory Clay Deposits of the Haldeman and Wrigley Quadrangles, Kentucky

    USGS Publications Warehouse

    Patterson, Sam H.; Hosterman, John W.; Huddle, John Warfield

    1962-01-01

    The Haldeman and Wrigley 7th-minute quadrangles are near the western edge of the eastern Kentucky coal field and cover an area of approximately 117 square miles in parts of Carter, Rowan, Elliott, and Morgan Counties, Ky. The rocks exposed in the two quadrangles are of Early and Late Mississippian and Early and Middle Pennsylvanian age. The Mississippian rocks are composed of the thick Brodhead formation, which consists of siltstone and shale, and eleven thin marine limestone and shale formations, having an aggregate thickness of about 150 feet. The Lee and Breathitt formations, of Pennsylvanian age, consist of sandstone, siltstone, and shale; they also contain thin beds of coal and several beds of underclay, including the economically important Olive Hill clay bed of Crider, 1913. Pennsylvanian rocks include beds of both continental and marine origin. The eleven thin Mississippian formations and the upper-most part of the thick Brodhead formation are truncated by a prominent unconformity on which rocks of Pennsylvanian age rest. The rocks occupy a region of gentle dips between the Cincinnati arch and the Appalachian Mountains. Refractory clay deposits are in the Olive Hill clay bed, which occurs in the lower part of the Lee formation. The Olive Hill clay bed is discontinuous and consists of a series of irregularly shaped lenses. The bed is approximately two-thirds semifiint clay and one-third flint clay, and it contains minor amounts of plastic clay. Some of the flint clay is nearly pure kaolinite, but the semi flint and plastic clay consists of mixtures of kaolinite, illite, and mixed-layer clay minerals. The structure of the kaolinite ranges from highly crystalline to very poorly crystalline 'fireclay' type. The degree of crystallinity of the kaolinite and the hardness of the clay vary inversely with the amount of illite and mixed-layer clay minerals present. The nearly pure kaolinite is believed to have formed by the removal of alkalies and some silica fram

  13. Assessment of Near-Field Sonic Boom Simulation Tools

    NASA Technical Reports Server (NTRS)

    Casper, J. H.; Cliff, S. E.; Thomas, S. D.; Park, M. A.; McMullen, M. S.; Melton, J. E.; Durston, D. A.

    2008-01-01

    A recent study for the Supersonics Project, within the National Aeronautics and Space Administration, has been conducted to assess current in-house capabilities for the prediction of near-field sonic boom. Such capabilities are required to simulate the highly nonlinear flow near an aircraft, wherein a sonic-boom signature is generated. There are many available computational fluid dynamics codes that could be used to provide the near-field flow for a sonic boom calculation. However, such codes have typically been developed for applications involving aerodynamic configuration, for which an efficiently generated computational mesh is usually not optimum for a sonic boom prediction. Preliminary guidelines are suggested to characterize a state-of-the-art sonic boom prediction methodology. The available simulation tools that are best suited to incorporate into that methodology are identified; preliminary test cases are presented in support of the selection. During this phase of process definition and tool selection, parallel research was conducted in an attempt to establish criteria that link the properties of a computational mesh to the accuracy of a sonic boom prediction. Such properties include sufficient grid density near shocks and within the zone of influence, which are achieved by adaptation and mesh refinement strategies. Prediction accuracy is validated by comparison with wind tunnel data.

  14. The colloidal chemistry of ceramic clays

    NASA Technical Reports Server (NTRS)

    Phelps, G. W.

    1984-01-01

    The colloidal chemistry and mineralogy of two argil minerals were studied. Deposits of kaolin and of ceramic clays in the United States and England are discussed for the probable mechanism of formation. The structural modifications of the bed, original material associated with the clays and the proper use of flocculants are discussed.

  15. Prediction of sonic boom at a focus

    NASA Technical Reports Server (NTRS)

    Plotkin, K. J.; Cantril, J. M.

    1976-01-01

    The behavior of sonic boom at a focus has been reviewed for the purpose of extending present sonic boom computational methods to include focal zones. The geometry of a focal zone - whether a smooth caustic, a cusped caustic, or a perfect focus to a point - determines the character of focused signatures. The seeming contradiction of various experimental data can be resolved by noting these differences. A ray acoustic analysis has been developed for quantitative determination of caustic geometry. The only reliable theory presently available for signatures at a focus is for a smooth caustic. There has been some controversy between theoretical and experimental values of a constant in the scaling law for this case. It has been found that this discrepancy can be resolved by accounting for the finite thickness of real sonic boom shock waves. These findings have been incorporated into an existing sonic boom computer program.

  16. Conceptual analyses of extensible booms to support a solar sail

    NASA Technical Reports Server (NTRS)

    Crawford, R. F.; Benton, M. D.

    1977-01-01

    Extensible booms which could function as the diagonal spars and central mast of an 800 meter square, non-rotating Solar Sailing Vehicle were conceptually designed and analyzed. The boom design concept that was investigated is an extensible lattice boom which is stowed and deployed by elastically coiling and uncoiling its continuous longerons. The seven different free-span lengths in each spar which would minimize the total weights of the spars and mast were determined. Boom weights were calculated by using a semi-empirical formulation which related the overall weight of a boom to the weight of its longerons.

  17. Stability of sonic boom metrics regarding signature distortions from atmospheric turbulence.

    PubMed

    Doebler, William J; Sparrow, Victor W

    2017-06-01

    The degree of insensitivity to atmospheric turbulence was evaluated for five metrics (A-, B-, E-weighted sound exposure level, Stevens Mark VII Perceived Level, and NASA's Indoor Sonic Boom Annoyance Predictor) that correlate to human annoyance from sonic booms. Eight N-wave shaped sonic booms from NASA's FaINT experiment and five simulated "low-boom" sonic booms were turbulized by Locey's ten atmospheric filter functions. The B-weighted sound exposure level value changed the least due to the turbulence filters for twelve of thirteen booms. This makes it the most turbulence stable metric which may be useful for quiet supersonic aircraft certification.

  18. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Peter Iosifidis, program manager, Low-Boom Flight Demonstrator, Lockheed Martin Skunk Works, speaks on a panel at a briefing after Lockheed Martin was awarded the contract to develop the first X-plane, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  19. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Dr. Jaiwon Shin, associate administrator for the Aeronautics Research Mission Directorate, NASA, announces Lockheed Martin as the winner of the contract to develop a Low Boom Flight Demonstrator at a briefing, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  20. Self-deploying boom

    NASA Technical Reports Server (NTRS)

    Tumulty, W. T.; Sours, W. P.

    1972-01-01

    Development and operation of metal ribbon which acts like self deploying boom are described. Metal ribbon is retained on two rollers for storage and extends into nonretractable tubular structure upon release. Illustration of equipment is provided.

  1. Research on Subjective Response to Simulated Sonic Booms at NASA Langley Research Center

    NASA Technical Reports Server (NTRS)

    Sullivan, Brenda M.

    2005-01-01

    Over the past 15 years, NASA Langley Research Center has conducted many tests investigating subjective response to simulated sonic booms. Most tests have used the Sonic Boom Booth, an airtight concrete booth fitted with loudspeakers that play synthesized sonic booms pre-processed to compensate for the response of the booth/loudspeaker system. Tests using the Booth have included investigations of shaped booms, booms with simulated ground reflections, recorded booms, outdoor and indoor booms, booms with differing loudness for bow and tail shocks, and comparisons of aircraft flyover recordings with sonic booms. Another study used loudspeakers placed inside people s houses, so that they could experience the booms while in their own homes. This study investigated the reactions of people to different numbers of booms heard within a 24-hour period. The most recent Booth test used predicted boom shapes from candidate low-boom aircraft. At present, a test to compare the Booth with boom simulators constructed by Gulfstream Aerospace Corporation and Lockheed Martin Aeronautics Company is underway. The Lockheed simulator is an airtight booth similar to the Langley booth; the Gulfstream booth uses a traveling wave method to create the booms. Comparison of "realism" as well as loudness and other descriptors is to be studied.

  2. A Mixed-Fidelity Approach for Design of Low-Boom Supersonic Aircraft

    NASA Technical Reports Server (NTRS)

    Li, Wu; Shields, Elwood; Geiselhart, Karl A.

    2010-01-01

    This paper documents a mixed-fidelity approach for the design of low-boom supersonic aircraft as a viable approach for designing a practical low-boom supersonic configuration. A low-boom configuration that is based on low-fidelity analysis is used as the baseline. Tail lift is included to help tailor the aft portion of the ground signature. A comparison of low- and high-fidelity analysis results demonstrates the necessity of using computational fluid dynamics (CFD) analysis in a low-boom supersonic configuration design process. The fuselage shape is modified iteratively to obtain a configuration with a CFD equivalent-area distribution that matches a predetermined low-boom target distribution. The mixed-fidelity approach can easily refine the low-fidelity low-boom baseline into a low-boom configuration with the use of CFD equivalent-area analysis. The ground signature of the final configuration is calculated by using a state-of-the-art CFD-based boom analysis method that generates accurate midfield pressure distributions for propagation to the ground with ray tracing. The ground signature that is propagated from a midfield pressure distribution has a shaped ramp front, which is similar to the ground signature that is propagated from the CFD equivalent-area distribution. This result confirms the validity of the low-boom supersonic configuration design by matching a low-boom equivalent-area target, which is easier to accomplish than matching a low-boom midfield pressure target.

  3. Formation of replicating saponite from a gel in the presence of oxalate: implications for the formation of clay minerals in carbonaceous chondrites and the origin of life.

    PubMed

    Schumann, Dirk; Hartman, Hyman; Eberl, Dennis D; Sears, S Kelly; Hesse, Reinhard; Vali, Hojatollah

    2012-06-01

    The potential role of clay minerals in the abiotic origin of life has been the subject of ongoing debate for the past several decades. At issue are the clay minerals found in a class of meteorites known as carbonaceous chondrites. These clay minerals are the product of aqueous alteration of anhydrous mineral phases, such as olivine and orthopyroxene, that are often present in the chondrules. Moreover, there is a strong correlation in the occurrence of clay minerals and the presence of polar organic molecules. It has been shown in laboratory experiments at low temperature and ambient pressure that polar organic molecules, such as the oxalate found in meteorites, can catalyze the crystallization of clay minerals. In this study, we show that oxalate is a robust catalyst in the crystallization of saponite, an Al- and Mg-rich, trioctahedral 2:1 layer silicate, from a silicate gel at 60°C and ambient pressure. High-resolution transmission electron microscopy analysis of the saponite treated with octadecylammonium (n(C)=18) cations revealed the presence of 2:1 layer structures that have variable interlayer charge. The crystallization of these differently charged 2:1 layer silicates most likely occurred independently. The fact that 2:1 layer silicates with variable charge formed in the same gel has implications for our understanding of the origin of life, as these 2:1 clay minerals most likely replicate by a mechanism of template-catalyzed polymerization and transmit the charge distribution from layer to layer. If polar organic molecules like oxalate can catalyze the formation of clay-mineral crystals, which in turn promote clay microenvironments and provide abundant adsorption sites for other organic molecules present in solution, the interaction among these adsorbed molecules could lead to the polymerization of more complex organic molecules like RNA from nucleotides on early Earth.

  4. Formation of replicating saponite from a gel in the presence of oxalate: implications for the formation of clay minerals in carbonaceous chondrites and the origin of life

    USGS Publications Warehouse

    Schumann, Dirk; Hartman, Hyman; Eberl, Dennis D.; Sears, S. Kelly; Hesse, Reinhard; Vali, Hojatollah

    2012-01-01

    The potential role of clay minerals in the abiotic origin of life has been the subject of ongoing debate for the past several decades. At issue are the clay minerals found in a class of meteorites known as carbonaceous chondrites. These clay minerals are the product of aqueous alteration of anhydrous mineral phases, such as olivine and orthopyroxene, that are often present in the chondrules. Moreover, there is a strong correlation in the occurrence of clay minerals and the presence of polar organic molecules. It has been shown in laboratory experiments at low temperature and ambient pressure that polar organic molecules, such as the oxalate found in meteorites, can catalyze the crystallization of clay minerals. In this study, we show that oxalate is a robust catalyst in the crystallization of saponite, an Al- and Mg-rich, trioctahedral 2:1 layer silicate, from a silicate gel at 60°C and ambient pressure. High-resolution transmission electron microscopy analysis of the saponite treated with octadecylammonium (n(C)=18) cations revealed the presence of 2:1 layer structures that have variable interlayer charge. The crystallization of these differently charged 2:1 layer silicates most likely occurred independently. The fact that 2:1 layer silicates with variable charge formed in the same gel has implications for our understanding of the origin of life, as these 2:1 clay minerals most likely replicate by a mechanism of template-catalyzed polymerization and transmit the charge distribution from layer to layer. If polar organic molecules like oxalate can catalyze the formation of clay-mineral crystals, which in turn promote clay microenvironments and provide abundant adsorption sites for other organic molecules present in solution, the interaction among these adsorbed molecules could lead to the polymerization of more complex organic molecules like RNA from nucleotides on early Earth.

  5. Rates and time scales of clay-mineral formation by weathering in saprolitic regoliths of the southern Appalachians from geochemical mass balance

    Treesearch

    Jason R. Price; Michael A. Velbel; Lina C. Patino

    2005-01-01

    Rates of clay formation in three watersheds located at the Coweeta Hydrologic Laboratory, western North Carolina, have been determined from solute flux-based mass balance methods. A system of mass balance equations with enough equations and unknowns to allow calculation of secondary mineral formation rates as well as the more commonly determined primary-...

  6. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Peter Coen, project manager, Commercial Supersonics Technology Project, Langley Research Center, NASA, speaks on a panel with Peter Iosifidis, Lockheed Martin, left, and Dr. Ed Waggoner, NASA, right, at a briefing on the Low Boom Flight Demonstrator, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  7. Method of Obtaining High Resolution Intrinsic Wire Boom Damping Parameters for Multi-Body Dynamics Simulations

    NASA Technical Reports Server (NTRS)

    Yew, Alvin G.; Chai, Dean J.; Olney, David J.

    2010-01-01

    The goal of NASA's Magnetospheric MultiScale (MMS) mission is to understand magnetic reconnection with sensor measurements from four spinning satellites flown in a tight tetrahedron formation. Four of the six electric field sensors on each satellite are located at the end of 60- meter wire booms to increase measurement sensitivity in the spin plane and to minimize motion coupling from perturbations on the main body. A propulsion burn however, might induce boom oscillations that could impact science measurements if oscillations do not damp to values on the order of 0.1 degree in a timely fashion. Large damping time constants could also adversely affect flight dynamics and attitude control performance. In this paper, we will discuss the implementation of a high resolution method for calculating the boom's intrinsic damping, which was used in multi-body dynamics simulations. In summary, experimental data was obtained with a scaled-down boom, which was suspended as a pendulum in vacuum. Optical techniques were designed to accurately measure the natural decay of angular position and subsequently, data processing algorithms resulted in excellent spatial and temporal resolutions. This method was repeated in a parametric study for various lengths, root tensions and vacuum levels. For all data sets, regression models for damping were applied, including: nonlinear viscous, frequency-independent hysteretic, coulomb and some combination of them. Our data analysis and dynamics models have shown that the intrinsic damping for the baseline boom is insufficient, thereby forcing project management to explore mitigation strategies.

  8. A Study of Reflected Sonic Booms Using Airborne Measurements

    NASA Technical Reports Server (NTRS)

    Kantor, Samuel R.; Cliatt, Larry J.

    2017-01-01

    In support of ongoing efforts to bring commercial supersonic flight to the public, the Sonic Booms in Atmospheric Turbulence (SonicBAT) flight test conducted at NASA Armstrong Flight Research Center. During this test, airborne sonic boom measurements were made using an instrumented TG-14 motor glider, called the Airborne Acoustic Measurement Platform (AAMP).During the flight program, the AAMP was consistently able to measure the sonic boom wave that was reflected off of the ground, in addition to the incident wave, resulting in the creation of a completely unique data set of airborne sonic boom reflection measurements.

  9. Acyl silicates and acyl aluminates as activated intermediates in peptide formation on clays

    NASA Technical Reports Server (NTRS)

    White, D. H.; Kennedy, R. M.; Macklin, J.

    1984-01-01

    Glycine reacts with heating on dried clays and other minerals to give peptides in much better yield than in the absence of mineral. This reaction was proposed to occur by way of an activated intermediate such as an acyl silicate or acyl aluminate analogous to acyl phosphates involved in several biochemical reactions including peptide bond synthesis. The proposed mechanism has been confirmed by trapping the intermediate, as well as by direct spectroscopic observation of a related intermediate. The reaction of amino acids on periodically dried mineral surfaces represents a widespead, geologically realistic setting for prebiotic peptide formation via in situ activation.

  10. Quiet Sonic Booms: A NASA and Industry Progress Report

    NASA Technical Reports Server (NTRS)

    Larson, David Nils; Martin, Roy; Haering, Edward A.

    2011-01-01

    The purpose of this Oral Presentation is to present a progress report on NASA and Industry efforts related to Quiet Sonic Boom Program activities. This presentation will review changes in aircraft shaping to produce quiet supersonic booms and associated supersonic flight test methods and results. In addition, new flight test profiles have been recently developed that have allowed for the generation of sonic booms of varying intensity. These new flight test profiles have allowed for ground testing of the response of various building structures to sonic booms and the associated public acceptability to various sonic boom intensities. The new flight test profiles and associated ground measurement test methods will be reviewed. Finally, this Oral Presentation will review the International Regulatory requirements that would be involved to change aviation regulation and allow for overland quiet supersonic flight.

  11. Human Response to Simulated Low-Intensity Sonic Booms

    NASA Technical Reports Server (NTRS)

    Sullivan, Brenda M.

    2004-01-01

    NASA's High Speed Research (HSR ) program in the 1990s was intended to develop a technology base for a future High-Speed Civil Transport (HSCT). As part of this program, the NASA Langley Research Center sonic boom simulator (SBS) was built and used for a series of tests on subjective response to sonic booms. At the end of the HSR program, an HSCT was deemed impractical, but since then interest in supersonic flight has reawakened, this time focusing on a smaller aircraft suitable for a business jet. To respond to this interest, the Langley sonic boom simulator has been refurbished. The upgraded computer-controlled playback system is based on an SGI O2 computer, in place of the previous DEC MicroVAX. As the frequency response of the booth is not flat, an equalization filter is required. Because of the changes made during the renovation (new loudspeakers), the previous equalization filter no longer performed as well as before, so a new equalization filter has been designed. Booms to be presented in the booth are preprocessed using the filter. When the preprocessed signals are presented into the booth and measured with a microphone, the results are very similar to the intended shapes. Signals with short rise times and sharp "corners" are observed to have a small amount of "ringing" in the response. During the HSR program a considerable number of subjective tests were completed in the SBS. A summary of that research is given in Leatherwood et al. (Individual reports are available at http://techreports.larc.nasa.gov/ltrs/ltrs.html.) Topics of study included shaped sonic booms, asymmetrical booms, realistic (recorded) boom waveforms, indoor and outdoor booms shapes, among other factors. One conclusion of that research was that a loudness metric, like the Stevens Perceived Level (PL), predicted human reaction much more accurately than overpressure or unweighted sound pressure level. Structural vibration and rattle were not included in these studies.

  12. Human Response to Low-Intensity Sonic Booms Heard Indoors and Outdoors

    NASA Technical Reports Server (NTRS)

    Sullivan, Brenda M.; Klos, Jacob; Buehrle, Ralph D.; McCurdy, David A.; Haering, Edward A., Jr.

    2010-01-01

    Test subjects seated inside and outside a house were exposed to low-intensity N-wave sonic booms during a 3-week test period in June 2006- The house was instrumented to measure the booms both inside and out. F-18 aircraft were flown to achieve a variety of boom overpressures from approximately .1 to .6 psf During four test days, seventy-seven test subjects heard the booms while seated inside and outside the house. Using the Magnitude Estimation methodology and artificial reference sounds ; the subjects rated the annoyance of the booms. Since the same subjects heard similar booms both inside and outside the house, comparative ratings of indoor and outdoor annoyance were obtained. For a given metric level, indoor subjects gave higher annoyance scores than outdoor subjects. For a given boom; annoyance scores inside were on average the same as those outside. In a post-test questionnaire, the majority of subjects rated the indoor booms as more annoying than the outdoor ones. These results are discussed in this paper.

  13. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Peter Coen, project manager, Commercial Supersonics Technology Project, Langley Research Center, NASA, center, speaks on a panel with Peter Iosifidis, Lockheed Martin, left, and Dr. Ed Waggoner, NASA, right, at a briefing on the Low Boom Flight Demonstrator, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  14. Experimental thermal mechanics of deployable boom structures

    NASA Technical Reports Server (NTRS)

    Predmore, R.

    1972-01-01

    An apparatus was developed for thermal distortion measurements on deployable boom structures. The calibration procedure and thermal static bending plus twist measurements are considered. The thermal mechanics test facility is described. A table is presented for several examples of spacecraft applications of thermal static distortion measurements on 3-m deployable booms.

  15. USM3D Simulations for Second Sonic Boom Workshop

    NASA Technical Reports Server (NTRS)

    Elmiligui, Alaa; Carter, Melissa B.; Nayani, Sudheer N.; Cliff, Susan; Pearl, Jason M.

    2017-01-01

    The NASA Tetrahedral Unstructured Software System with the USM3D flow solver was used to compute test cases for the Second AIAA Sonic Boom Prediction Workshop. The intent of this report is to document the USM3D results for SBPW2 test cases. The test cases included an axisymmetric equivalent area body, a JAXA wing body, a NASA low boom supersonic configuration modeled with flow through nacelles and engine boundary conditions. All simulations were conducted for a free stream Mach number of 1.6, zero degrees angle of attack, and a Reynolds number of 5.7 million per meter. Simulations were conducted on tetrahedral grids provided by the workshop committee, as well as a family of grids generated by an in-house approach for sonic boom analyses known as BoomGrid using current best practices. The near-field pressure signatures were extracted and propagated to the ground with the atmospheric propagation code, sBOOM. The USM3D near-field pressure signatures, corresponding sBOOM ground signatures, and loudness levels on the ground are compared with mean values from other workshop participants.

  16. Deformation mechanisms and resealing of damage zones in experimentally deformed cemented and un-cemented clay-rich geomaterials, at low bulk strain

    NASA Astrophysics Data System (ADS)

    Desbois, Guillaume; Urai, Janos L.; Schuck, Bernhardt; Hoehne, Nadine; Oelker, Anne; Bésuelle, Pierre; Viggiani, Gioacchino; Schmatz, Joyce; Klaver, Jop

    2017-04-01

    A microphysics-based understanding of mechanical and fluid flow properties in clay-rich geomaterials is required for extrapolating better constitutive equations beyond the laboratory's time scales, so that predictions over the long term can be made less uncertain. In this contribution, we present microstructural investigations of rocks specimens sheared in triaxial compression at low bulk strain, by using the combination of broad-ion-beam (BIB) milling and scanning electron microscopy (SEM) to infer deformation mechanisms based on microstructures imaged at sub-micron resolution. Two end-member clay-rich geomaterials from European Underground Laboratories (URL) were analysed: (i) the poorly cemented Boom Clay sediment (BC from URL at Mol/Dessel, Belgium; confining pressure [CP] = 0.375 & 1.5 MPa) and (ii) the Callovo-Oxfordian claystone (COx from the URL at Bure, France; CP = 2 & 10 MPa). Although as a first approximation the inelastic bahvior of cemented and uncemented clay-rich geomaterials can be described by similar pressure-dependent hardening plasticity models, deformed samples in this contribution show very contrasting micro-scale behaviour: microstructures reveal brittle-ductile transitional behaviour in BC, whereas deformation in COx is dominantly cataclastic. In Boom Clay, at meso-scale, shear bands exhibit characteristics that are typical of uncemented small-grained clay-rich materials deformed at high shear strains, consisting of anastomosing shears interpreted as Y- and B-shears, which bound the passively deformed microlithons. At micro- down to nano-scale, the strong shape preferential orientation of clay aggregates in the anastomosing shears is interpreted to be responsible of the shear weakness. More over, the reworking of clay aggregates during deformation contributes to the collapsing of porosity in the shear band. Ductile deformation mechanisms represented by grain-rotation, grain-sliding, bending and granular flow mechanisms are strongly involved

  17. Full-Carpet Design of a Low-Boom Demonstrator Concept

    NASA Technical Reports Server (NTRS)

    Ordaz, Irian; Wintzer, Mathias; Rallabhandi, Sriram K.

    2015-01-01

    The Cart3D adjoint-based design framework is used to mitigate the undesirable o -track sonic boom properties of a demonstrator concept designed for low-boom directly under the flight path. First, the requirements of a Cart3D design mesh are determined using a high-fidelity mesh adapted to minimize the discretization error of the CFD analysis. Low-boom equivalent area targets are then generated at the under-track and one off-track azimuthal position for the baseline configuration. The under-track target is generated using a trim- feasible low-boom target generation process, ensuring that the final design is not only low-boom, but also trimmed at the specified flight condition. The o -track equivalent area target is generated by minimizing the A-weighted loudness using an efficient adjoint-based approach. The configuration outer mold line is then parameterized and optimized to match the off-body pressure distributions prescribed by the low-boom targets. The numerical optimizer uses design gradients which are calculated using the Cart3D adjoint- based design capability. Optimization constraints are placed on the geometry to satisfy structural feasibility. The low-boom properties of the final design are verified using the adaptive meshing approach. This analysis quantifies the error associated with the CFD mesh that is used for design. Finally, an alternate mesh construction and target positioning approach offering greater computational efficiency is demonstrated and verified.

  18. Evaluation of outdoor-to-indoor response to minimized sonic booms

    NASA Technical Reports Server (NTRS)

    Brown, David; Sutherland, Louis C.

    1992-01-01

    Various studies were conducted by NASA and others on the practical limitations of sonic boom signature shaping/minimization for the High-Speed Civil Transport (HSCT) and on the effects of these shaped boom signatures on perceived loudness. This current effort is a further part of this research with emphasis on examining shaped boom signatures which are representative of the most recent investigations of practical limitations on sonic boom minimization, and on examining and comparing the expected response to these signatures when experienced indoors and outdoors.

  19. Confidence Intervals for Laboratory Sonic Boom Annoyance Tests

    NASA Technical Reports Server (NTRS)

    Rathsam, Jonathan; Christian, Andrew

    2016-01-01

    Commercial supersonic flight is currently forbidden over land because sonic booms have historically caused unacceptable annoyance levels in overflown communities. NASA is providing data and expertise to noise regulators as they consider relaxing the ban for future quiet supersonic aircraft. One deliverable NASA will provide is a predictive model for indoor annoyance to aid in setting an acceptable quiet sonic boom threshold. A laboratory study was conducted to determine how indoor vibrations caused by sonic booms affect annoyance judgments. The test method required finding the point of subjective equality (PSE) between sonic boom signals that cause vibrations and signals not causing vibrations played at various amplitudes. This presentation focuses on a few statistical techniques for estimating the interval around the PSE. The techniques examined are the Delta Method, Parametric and Nonparametric Bootstrapping, and Bayesian Posterior Estimation.

  20. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-23

    A motorized glider prepares to take off from the Shuttle Landing Facility at NASA's Kennedy Space Center in Florida. Flying with its engine off, the glider will be positioned above the 14,000-foot level to measure sonic booms created by agency F-18 jets to measure the effects of sonic booms. Several flights a day have been taking place the week of Aug. 21, 2017 as part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  1. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-23

    A motorized glider has taken off from the Shuttle Landing Facility at NASA's Kennedy Space Center in Florida. Flying with its engine off, the glider will be positioned above the 14,000-foot level to measure sonic booms created by agency F-18 jets to measure the effects of sonic booms. Several flights a day have been taking place the week of Aug. 21, 2017 as part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  2. Sonic Boom Minimization Efforts on Boeing HSCT Baseline

    NASA Technical Reports Server (NTRS)

    Cheung, Samson H.; Fouladi, Kamran; Haglund, George; Tu, Eugene

    1999-01-01

    A team was formed to tackle the sonic boom softening issues of the current Boeing HSCT design. The team consisted of personnel from NASA Ames, NASA Langley, and Boeing company. The work described in this paper was done when the first author was at NASA Ames Research Center. This paper presents the sonic boom softening work on two Boeing High Speed Civil Transport (HSCT) baseline configurations, Reference-H and Boeing-1122. This presentation can be divided into two parts: parametric studies and sonic boom minimization by CFD optimization routines.

  3. Special features of the CLUSTER antenna and radial booms design, development and verification

    NASA Technical Reports Server (NTRS)

    Gianfiglio, G.; Yorck, M.; Luhmann, H. J.

    1995-01-01

    CLUSTER is a scientific space mission to in-situ investigate the Earth's plasma environment by means of four identical spin-stabilized spacecraft. Each spacecraft is provided with a set of four rigid booms: two Antenna Booms and two Radial Booms. This paper presents a summary of the boom development and verification phases addressing the key aspects of the Radial Boom design. In particular, it concentrates on the difficulties encountered in fulfilling simultaneously the requirements of minimum torque ratio and maximum allowed shock loads at boom latching for this two degree of freedom boom. The paper also provides an overview of the analysis campaign and testing program performed to achieve sufficient confidence in the boom performance and operation.

  4. Simple atmospheric perturbation models for sonic-boom-signature distortion studies

    NASA Technical Reports Server (NTRS)

    Ehernberger, L. J.; Wurtele, Morton G.; Sharman, Robert D.

    1994-01-01

    Sonic-boom propagation from flight level to ground is influenced by wind and speed-of-sound variations resulting from temperature changes in both the mean atmospheric structure and small-scale perturbations. Meteorological behavior generally produces complex combinations of atmospheric perturbations in the form of turbulence, wind shears, up- and down-drafts and various wave behaviors. Differences between the speed of sound at the ground and at flight level will influence the threshold flight Mach number for which the sonic boom first reaches the ground as well as the width of the resulting sonic-boom carpet. Mean atmospheric temperature and wind structure as a function of altitude vary with location and time of year. These average properties of the atmosphere are well-documented and have been used in many sonic-boom propagation assessments. In contrast, smaller scale atmospheric perturbations are also known to modulate the shape and amplitude of sonic-boom signatures reaching the ground, but specific perturbation models have not been established for evaluating their effects on sonic-boom propagation. The purpose of this paper is to present simple examples of atmospheric vertical temperature gradients, wind shears, and wave motions that can guide preliminary assessments of nonturbulent atmospheric perturbation effects on sonic-boom propagation to the ground. The use of simple discrete atmospheric perturbation structures can facilitate the interpretation of the resulting sonic-boom propagation anomalies as well as intercomparisons among varied flight conditions and propagation models.

  5. Formation and Coloring Mechanism of Typical Aluminosilicate Clay Minerals for CoAl2O4 Hybrid Pigment Preparation

    PubMed Central

    Zhang, Anjie; Mu, Bin; Wang, Xiaowen; Wen, Lixin; Wang, Aiqin

    2018-01-01

    Different kinds of aluminosilicate minerals were employed to fabricate CoAl2O4 hybrid pigment for studying its formation and coloring mechanism. It revealed that the color of the obtained hybrid pigments was determined by the content of Al2O3 and lightness of clay minerals. The higher the Al2O3 content and the lightness of clay minerals, the better the color parameters of hybrid pigments. During the preparation of hybrid pigments, CoAl2O4 nanoparticles were confined to be loaded on the surface of the aluminosilicate minerals, which effectively prevented from the aggregation and the size increase of CoAl2O4 nanoparticles. What's more, aluminosilicate mineral might be an ideal natural aluminum source to compensate the aluminum loss due to the dissolution of Al(OH)3 at alkaline medium during precursor preparation, keeping an optimum molar ratio of Co2+/Al3+ for formation of spinel CoAl2O4 pigments in the process of high-temperature crystallization. PMID:29725589

  6. Formation and Coloring Mechanism of Typical Aluminosilicate Clay Minerals for CoAl2O4 Hybrid Pigment Preparation.

    PubMed

    Zhang, Anjie; Mu, Bin; Wang, Xiaowen; Wen, Lixin; Wang, Aiqin

    2018-01-01

    Different kinds of aluminosilicate minerals were employed to fabricate CoAl 2 O 4 hybrid pigment for studying its formation and coloring mechanism. It revealed that the color of the obtained hybrid pigments was determined by the content of Al 2 O 3 and lightness of clay minerals. The higher the Al 2 O 3 content and the lightness of clay minerals, the better the color parameters of hybrid pigments. During the preparation of hybrid pigments, CoAl 2 O 4 nanoparticles were confined to be loaded on the surface of the aluminosilicate minerals, which effectively prevented from the aggregation and the size increase of CoAl 2 O 4 nanoparticles. What's more, aluminosilicate mineral might be an ideal natural aluminum source to compensate the aluminum loss due to the dissolution of Al(OH) 3 at alkaline medium during precursor preparation, keeping an optimum molar ratio of Co 2+ /Al 3+ for formation of spinel CoAl 2 O 4 pigments in the process of high-temperature crystallization.

  7. Formation of metal clusters in halloysite clay nanotubes

    NASA Astrophysics Data System (ADS)

    Vinokurov, Vladimir A.; Stavitskaya, Anna V.; Chudakov, Yaroslav A.; Ivanov, Evgenii V.; Shrestha, Lok Kumar; Ariga, Katsuhiko; Darrat, Yusuf A.; Lvov, Yuri M.

    2017-12-01

    We developed ceramic core-shell materials based on abundant halloysite clay nanotubes with enhanced heavy metal ions loading through Schiff base binding. These clay tubes are formed by rolling alumosilicate sheets and have diameter of c.50 nm, a lumen of 15 nm and length 1 μm. This allowed for synthesis of metal nanoparticles at the selected position: (1) on the outer surface seeding 3-5 nm metal particles on the tubes; (2) inside the tube's central lumen resulting in 10-12 nm diameter metal cores shelled with ceramic wall; and (3) smaller metal nanoparticles intercalated in the tube's wall allowing up to 9 wt% of Ru, and Ag loading. These composite materials have high surface area providing a good support for catalytic nanoparticles, and can also be used for sorption of metal ions from aqueous solutions.

  8. Formation of metal clusters in halloysite clay nanotubes.

    PubMed

    Vinokurov, Vladimir A; Stavitskaya, Anna V; Chudakov, Yaroslav A; Ivanov, Evgenii V; Shrestha, Lok Kumar; Ariga, Katsuhiko; Darrat, Yusuf A; Lvov, Yuri M

    2017-01-01

    We developed ceramic core-shell materials based on abundant halloysite clay nanotubes with enhanced heavy metal ions loading through Schiff base binding. These clay tubes are formed by rolling alumosilicate sheets and have diameter of c .50 nm, a lumen of 15 nm and length ~1 μm. This allowed for synthesis of metal nanoparticles at the selected position: (1) on the outer surface seeding 3-5 nm metal particles on the tubes; (2) inside the tube's central lumen resulting in 10-12 nm diameter metal cores shelled with ceramic wall; and (3) smaller metal nanoparticles intercalated in the tube's wall allowing up to 9 wt% of Ru, and Ag loading. These composite materials have high surface area providing a good support for catalytic nanoparticles, and can also be used for sorption of metal ions from aqueous solutions.

  9. Reduction of the sonic boom level in supersonic aircraft flight by the method of surface cooling

    NASA Astrophysics Data System (ADS)

    Fomin, V. M.; Chirkashenko, V. F.; Volkov, V. F.; Kharitonov, A. M.

    2013-12-01

    Based on the analysis of various aspects of creating a supersonic transport aircraft of the second generation, the necessity of developing unconventional active methods of sonic boom level reduction is demonstrated. Surface cooling is shown to exert a significant effect on formation of the disturbed flow structure up to large distances from the body by an example of a supersonic flow around a body of revolution. A method of reducing the intensity of the intermediate shock wave and excess pressure momentum near the body is proposed. This method allows the length of the reduced (by 50%) sonic boom level to be increased and the bow shock wave intensity in the far zone to be reduced by 12%. A possibility of controlling the process of formation of wave structures, such as hanging pressure shocks arising near the aircraft surface, is demonstrated. The action of the cryogenic mechanism is explained.

  10. Sonic boom signature data from cruciform microphone array experiments during the 1966-1967 EAFB national sonic boom evaluation program

    NASA Technical Reports Server (NTRS)

    Hubbard, H. H.; Maglieri, D. J.

    1990-01-01

    Tables are provided of measured sonic boom signature data derived from supersonic flyover tests of the XB-70, B-58 and F-104 aircraft for ranges of altitude and Mach number. These tables represent a convenient hard copy version of available electronic files and complement preliminary information included in a reference National Sonic Boom Evaluation Office document.

  11. Review of sonic-boom simulation devices and techniques.

    NASA Technical Reports Server (NTRS)

    Edge, P. M., Jr.; Hubbard, H. H.

    1972-01-01

    Research on aircraft-generated sonic booms has led to the development of special techniques to generate controlled sonic-boom-type disturbances without the complications and expense of supersonic flight operations. This paper contains brief descriptions of several of these techniques along with the significant hardware items involved and indicates the advantages and disadvantages of each in research applications. Included are wind tunnels, ballistic ranges, spark discharges, piston phones, shock tubes, high-speed valve systems, and shaped explosive charges. Specialized applications include sonic-boom generation and propagation studies and the responses of structures, terrain, people, and animals. Situations for which simulators are applicable are shown to include both small-scale and large-scale laboratory tests and full-scale field tests. Although no one approach to simulation is ideal, the various techniques available generally complement each other to provide desired capability for a broad range of sonic-boom studies.

  12. Development in helicopter tail boom strake applications in the US

    NASA Technical Reports Server (NTRS)

    Wilson, John C.; Kelley, Henry L.; Donahue, Cynthia C.; Yenni, Kenneth R.

    1988-01-01

    The use of a strake or spoiler on a helicopter tail boom to beneficially change helicopter tail boom air loads was suggested in the United States in 1975. The anticipated benefits were a change of tail boom loads to reduce required tail rotor thrust and power and improve directional control. High tail boom air loads experienced by the YAH-64 and described in 1978 led to a wind tunnel investigation of the usefullness of strakes in altering such loads on the AH-64, UH-60, and UH-1 helicopters. The wind tunnel tests of 2-D cross sections of the tail boom of each demonstrated that a strake or strakes would be effective. Several limited test programs with the U.S. Army's OH-58A, AH-64, and UH-60A were conducted which showed the effects of strakes were modest for those helicopters. The most recent flight test program, with a Bell 204B, disclosed that for the 204B the tail boom strake or strakes would provide more than a modest improvement in directional control and reduction in tail rotor power.

  13. The influence of authigenic clay formation on the mineralogy and stable isotopic record of lacustrine carbonates

    NASA Astrophysics Data System (ADS)

    Bristow, Thomas F.; Kennedy, Martin J.; Morrison, Keith D.; Mrofka, David D.

    2012-08-01

    The mineralogical, compositional and stable isotopic variability of lacustrine carbonates are frequently used as proxies for ancient paleoenvironmental change in continental settings, under the assumption that precipitated carbonates reflect conditions and chemistry of ancient lake waters. In some saline and alkaline lake systems, however, authigenic clay minerals, forming at or near the sediment water interface, are a major sedimentary component. Often these clays are rich in Mg, influencing the geochemical budget of lake waters, and are therefore expected to influence the properties of contemporaneous authigenic carbonate precipitates (which may also contain Mg). This paper documents evidence for a systematic feedback between clay mineral and carbonate authigenesis through multiple precessionally driven, m-scale sedimentary cycles in lacustrine oil-shale deposits of the Eocene Green River Formation from the Uinta Basin (NE Utah). In the studied section, authigenic, Mg-rich, trioctahedral smectite content varies cyclically between 9 and 39 wt.%. The highest concentrations occur in oil-shales and calcareous mudstones deposited during high lake level intervals that favored sedimentary condensation, lengthening the time available for clay diagenesis and reducing dilution by other siliciclastic phases. An inverse relation between dolomite percentage of carbonate and trioctahedral smectite abundance suggests the Mg uptake during clay authigenesis provides a first order control on carbonate mineralogy that better explains carbonate mineralogical trends than the possible alternative controls of (1) variable Mg/Ca ratios in lake water and (2) degree of microbial activity in sediments. We also observe that cyclical change in carbonate mineralogy, believed to be induced by clay authigenesis, also causes isotopic covariation between δ13CPDB and δ18OPDB of bulk sediments because of differences in the equilibrium fractionation factors of dolomite and calcite (˜2‰ and ˜2

  14. Ultrasonically assisted single screw extrusion, film blowing and film casting of LLDPE/clay and PA6/clay nanocomposites

    NASA Astrophysics Data System (ADS)

    Niknezhad, Setareh

    maleic anhydride (MA) affected mechanical properties and oxygen permeability with ultrasonic treatment to higher extent. However, use of compatibilizers led to a higher die pressure and resulted in opaque cast films. The mechanical properties were in agreement with crystallinity of samples. The exfoliated structure was achieved for PA6/clay 30B nanocomposites prepared using ultrasonically assisted single screw extrusion except for untreated nanocomposites containing 10 wt% of clay 30B. Untreated 92.5/7.5 and 90/10 PA6/clay 30B blown films showed the intercalated structure, but the exfoliated structure was achieved with ultrasonic treatment. All cast films of PA6/clay 30B showed the exfoliated structure. FTIR spectroscopy along with XRD results confirmed the existence of alpha and gamma-type crystals in the cast films, with clay particles favoring the formation of gamma-type crystals, and ultrasonic treatment favoring the formation of alpha-type crystals. Both parameters increased crystallinity of cast films improving their mechanical properties and oxygen permeability.

  15. Reactions of Residents to Long-Term Sonic Boom Noise Environments

    NASA Technical Reports Server (NTRS)

    Fields, James M.

    1997-01-01

    A combined social survey and noise measurement program has been completed in 14 communities in two regions of the western United States that have been regularly exposed to sonic booms for many years. A total of 1,573 interviews were completed. Three aspects of the sonic booms are most disturbing: being startled, noticing rattles or vibrations, and being concerned about the possibility of damage from the booms. Sonic boom annoyance is greater than that in a conventional aircraft environment with the same continuous equivalent noise exposure. The reactions in the two study regions differ in severity.

  16. Formation of metal clusters in halloysite clay nanotubes

    DOE PAGES

    Vinokurov, Vladimir A.; Stavitskaya, Anna V.; Chudakov, Yaroslav A.; ...

    2017-02-16

    We developed ceramic core-shell materials based on abundant halloysite clay nanotubes with enhanced heavy metal ions loading through Schiff base binding. These clay tubes are formed by rolling alumosilicate sheets and have diameter of c.50 nm, a lumen of 15 nm and length ~1 μm. This allowed for synthesis of metal nanoparticles at the selected position: (1) on the outer surface seeding 3-5 nm metal particles on the tubes; (2) inside the tube’s central lumen resulting in 10-12 nm diameter metal cores shelled with ceramic wall; and (3) smaller metal nanoparticles intercalated in the tube’s wall allowing up to 9more » wt% of Ru, and Ag loading. These composite materials have high surface area providing a good support for catalytic nanoparticles, and can also be used for sorption of metal ions from aqueous solutions.« less

  17. Formation of metal clusters in halloysite clay nanotubes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vinokurov, Vladimir A.; Stavitskaya, Anna V.; Chudakov, Yaroslav A.

    We developed ceramic core-shell materials based on abundant halloysite clay nanotubes with enhanced heavy metal ions loading through Schiff base binding. These clay tubes are formed by rolling alumosilicate sheets and have diameter of c.50 nm, a lumen of 15 nm and length ~1 μm. This allowed for synthesis of metal nanoparticles at the selected position: (1) on the outer surface seeding 3-5 nm metal particles on the tubes; (2) inside the tube’s central lumen resulting in 10-12 nm diameter metal cores shelled with ceramic wall; and (3) smaller metal nanoparticles intercalated in the tube’s wall allowing up to 9more » wt% of Ru, and Ag loading. These composite materials have high surface area providing a good support for catalytic nanoparticles, and can also be used for sorption of metal ions from aqueous solutions.« less

  18. Formation of metal clusters in halloysite clay nanotubes

    PubMed Central

    Vinokurov, Vladimir A.; Stavitskaya, Anna V.; Chudakov, Yaroslav A.; Ivanov, Evgenii V.; Shrestha, Lok Kumar; Ariga, Katsuhiko; Darrat, Yusuf A.; Lvov, Yuri M.

    2017-01-01

    Abstract We developed ceramic core-shell materials based on abundant halloysite clay nanotubes with enhanced heavy metal ions loading through Schiff base binding. These clay tubes are formed by rolling alumosilicate sheets and have diameter of c.50 nm, a lumen of 15 nm and length ~1 μm. This allowed for synthesis of metal nanoparticles at the selected position: (1) on the outer surface seeding 3–5 nm metal particles on the tubes; (2) inside the tube’s central lumen resulting in 10–12 nm diameter metal cores shelled with ceramic wall; and (3) smaller metal nanoparticles intercalated in the tube’s wall allowing up to 9 wt% of Ru, and Ag loading. These composite materials have high surface area providing a good support for catalytic nanoparticles, and can also be used for sorption of metal ions from aqueous solutions. PMID:28458738

  19. Subjective response of people to simulated sonic booms in their homes

    NASA Technical Reports Server (NTRS)

    McCurdy, David A.; Brown, Sherilyn A.; Hilliard, R. David

    2004-01-01

    In order to determine the effect of the number of sonic boom occurrences on annoyance, a computer-based system was developed for studying the subjective response of people to the occurrence of simulated sonic booms in their homes. The system provided a degree of control over the noise exposure not found in community surveys and a degree of situational realism not available in the laboratory. A system was deployed for eight weeks in each of 33 homes. Each day from 4 to 63 sonic booms were played as the test subject went about his or her normal activities. At the end of the day, the test subjects rated their annoyance to the sonic booms heard during the day. The sonic booms consisted of different combinations of waveforms, levels, and occurrence rates. The experiment confirmed that the increase in annoyance resulting from multiple occurrences can be modeled by the addition of the term "10 * log(number of occurrences)" to the sonic boom level. Of several noise metrics considered, perceived level was the best annoyance predictor. Comparisons of the subjective responses to the different sonic boom waveforms found no differences that were not accounted for by the noise metrics.

  20. Vibration Penalty Estimates for Indoor Annoyance Caused by Sonic Boom

    NASA Technical Reports Server (NTRS)

    Rathsam, Jonathan; Klos, Jacob

    2016-01-01

    Commercial supersonic flight is currently forbidden over land because sonic booms have historically caused unacceptable annoyance levels in overflown communities. NASA is providing data and expertise to noise regulators as they consider relaxing the ban for future quiet supersonic aircraft. One key objective is a predictive model for indoor annoyance based on factors such as noise and indoor vibration levels. The current study quantified the increment in indoor sonic boom annoyance when sonic booms can be felt directly through structural vibrations in addition to being heard. A shaker mounted below each chair in the sonic boom simulator emulated vibrations transmitting through the structure to that chair. The vibration amplitudes were determined from numeric models of a large range of residential structures excited by the same sonic boom waveforms used in the experiment. The analysis yielded vibration penalties, which are the increments in sound level needed to increase annoyance as much as the vibration does. For sonic booms at acoustic levels from 75 to 84 dB Perceived Level, vibration signals with lower amplitudes (+1 sigma) yielded penalties from 0 to 5 dB, and vibration signals with higher amplitudes (+3 sigma) yielded penalties from 6 to 10 dB.

  1. Environmental Pollution: Noise Pollution - Sonic Boom

    DTIC Science & Technology

    1977-06-01

    UNCLASSIFIED AD-A041 400 DDC/BIB-77/06 ENVIRONMENTAL POLLUTION NOISE POLLUTION SONIC BOOM A DDC BIBLIOGRAPHY DDC-TAS Cameron Station Alexandria, Va...rn7Sttio 658S-A041 400 4 TITLE xand r.VuhtlVlia) 2 TA i b- 1iblog ra ph y ENVIRONMENTAL POLLUTION : --. Apr-l IM59-Jul, 7NOISE POLLUTION -SONIC BOOM. 1,976...BIBLIOGRAPHY SEARCH CONTROL NO. /2OM09 AD- 769 970 20/1 1/3 DEFENSE UOCUMENTATION CENTER ALEXANDRIA VA ENVIRONMENTAL POLLUTION : NOISE POLLUTION

  2. Interphase vs confinement in starch-clay bionanocomposites.

    PubMed

    Coativy, Gildas; Chevigny, Chloé; Rolland-Sabaté, Agnès; Leroy, Eric; Lourdin, Denis

    2015-03-06

    Starch-clay bionanocomposites containing 1-10% of natural montmorillonite were elaborated by melt processing in the presence of water. A complex macromolecular dynamics behavior was observed: depending on the clay content, an increase of the glass transition temperature and/or the presence of two overlapped α relaxation peaks were detected. Thanks to a model allowing the prediction of the average interparticle distance, and its comparison with the average size of starch macromolecules, it was possible to associate these phenomena to different populations of macromolecules. In particular, it seems that for high clay content (10%), the slowdown of segmental relaxation due to confinement of the starch macromolecules between the clay tactoïds is the predominant phenomenon. While for lower clay contents (3-5%), a significant modification of chain relaxation seems to occur, due to the formation of an interphase by the starch macromolecules in the vicinity of clay nanoparticles coexisting with the bulk polymer. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. Thermal static bending of deployable interlocked booms

    NASA Technical Reports Server (NTRS)

    Staugaitis, C. L.; Predmore, R. E.

    1973-01-01

    Metal ribbons processed with a heat-forming treatment are enabled to form tubelike structures when deployed from a roll. Deployable booms of this have been utilized for gravity-gradient stabilization on the RAE, ATS, and Nimbus D satellites. An experimental thermal-mechanics test apparatus was developed to measure the thermal static bending and twist of booms up to 3 meters long. The apparatus was calibrated by using the correlation between calculated and observed thermal bending of a seamless tube. Thermal static bending values of 16 interlocked deployable booms were observed to be within a factor of 2.5 of the values calculated from seamless-tube theory. Out-of-Sun-plane thermal bending was caused by complex heat transfer across the interlocked seam. Significant thermal static twisting was not observed.

  4. Evaluation of human response to structural vibration induced by sonic boom

    NASA Technical Reports Server (NTRS)

    Sutherland, L. C.; Czech, J.

    1992-01-01

    This paper addresses the topic of building vibration response to sonic boom and the evaluation of the associated human response to this vibration. The paper reexamines some of the issues addressed in the previous extensive coverage of the topic, primarily by NASA, and attempts to offer a fresh viewpoint for some of the problems that may assist in reassessing the potential impact of sonic boom over populated areas. The topics addressed are: (1) human response to vibration; (2) criteria for, and acoustic signature of rattle; (3) structural response to shaped booms, including definition of two new descriptors for assessing the structural response to sonic boom; and (4) a detailed review of the previous NASA/FAA Sonic Boom Test Program involving structural response measurements at Edwards AFB and an initial estimate of structural response to sonic booms from possible high speed civil transport configurations. Finally, these estimated vibration responses are shown to be substantially greater than the human response and rattle criteria developed earlier.

  5. State of the art of sonic boom modeling

    NASA Astrophysics Data System (ADS)

    Plotkin, Kenneth J.

    2002-01-01

    Based on fundamental theory developed through the 1950s and 1960s, sonic boom modeling has evolved into practical tools. Over the past decade, there have been requirements for design tools for an advanced supersonic transport, and for tools for environmental assessment of various military and aerospace activities. This has resulted in a number of advances in the understanding of the physics of sonic booms, including shock wave rise times, propagation through turbulence, and blending sonic boom theory with modern computational fluid dynamics (CFD) aerodynamic design methods. This article reviews the early fundamental theory, recent advances in theory, and the application of these advances to practical models.

  6. State of the art of sonic boom modeling.

    PubMed

    Plotkin, Kenneth J

    2002-01-01

    Based on fundamental theory developed through the 1950s and 1960s, sonic boom modeling has evolved into practical tools. Over the past decade, there have been requirements for design tools for an advanced supersonic transport, and for tools for environmental assessment of various military and aerospace activities. This has resulted in a number of advances in the understanding of the physics of sonic booms, including shock wave rise times, propagation through turbulence, and blending sonic boom theory with modern computational fluid dynamics (CFD) aerodynamic design methods. This article reviews the early fundamental theory, recent advances in theory, and the application of these advances to practical models.

  7. Sonic Boom Prediction and Minimization of the Douglas Reference OPT5 Configuration

    NASA Technical Reports Server (NTRS)

    Siclari, Michael J.

    1999-01-01

    computationally efficient Euler CFD solver (NIIM3DSB) for computing the three-dimensional near-field characteristics of the aircraft. The intent of the design system is to identify and optimize geometric design variables that have a beneficial impact on the ground sonic boom. The system uses a simple wave drag data format to specify the aircraft geometry. The geometry is internally enhanced and analytic methods are used to generate marching grids suitable for the multi-block Euler solver. The Thomas extrapolation method is integrated into this system, and hence, the aircraft's centerline ground sonic boom signature is also automatically computed for a specified cruise altitude and yields the parameters necessary to evaluate the design function. The entire design system has been automated since the gradient based optimization software requires many flow analyses in order to obtain the required sensitivity derivatives for each design variable in order to converge on an optimal solution. Hence, once the problem is defined which includes defining the objective function and geometric and aerodynamic constraints, the system will automatically regenerate the perturbed geometry, the necessary grids, the Euler solution, and finally the ground sonic boom signature at the request of the optimizer.

  8. Methodology for the regulation of boom sprayers operating in circular trajectories.

    PubMed

    Garcia-Ramos, Francisco Javier; Vidal, Mariano; Boné, Antonio; Serreta, Alfredo

    2011-01-01

    A methodology for the regulation of boom sprayers working in circular trajectories has been developed. In this type of trajectory, the areas of the plots of land treated by the outer nozzles of the boom are treated at reduced rates, and those treated by the inner nozzles are treated in excess. The goal of this study was to establish the methodology to determine the flow of the individual nozzles on the boom to guarantee that the dose of the product applied per surface unit is similar across the plot. This flow is a function of the position of the equipment (circular trajectory radius) and of the displacement velocity such that the treatment applied per surface unit is uniform. GPS technology was proposed as a basis to establish the position and displacement velocity of the tractor. The viability of this methodology was simulated considering two circular plots with radii of 160 m and 310 m, using three sets of equipment with boom widths of 14.5, 24.5 and 29.5 m. Data showed as increasing boom widths produce bigger errors in the surface dose applied (L/m(2)). Error also increases with decreasing plot surface. As an example, considering the three boom widths of 14.5, 24.5 and 29.5 m working on a circular plot with a radius of 160 m, the percentage of surface with errors in the applied surface dose greater than 5% was 30%, 58% and 65% respectively. Considering a circular plot with radius of 310 m the same errors were 8%, 22% and 31%. To obtain a uniform superficial dose two sprayer regulation alternatives have been simulated considering a 14.5 m boom: the regulation of the pressure of each nozzle and the regulation of the pressure of each boom section. The viability of implementing the proposed methodology on commercial boom sprayers using GPS antennas to establish the position and displacement velocity of the tractor was justified with a field trial in which a self-guiding commercial GPS system was used along with three precision GPS systems located in the sprayer

  9. Stress Analysis of Boom of Special Mobile Crane for Plain Region in Transmission Line

    NASA Astrophysics Data System (ADS)

    Qin, Jian; Shao, Tao; Chen, Jun; Wan, Jiancheng; Li, Zhonghuan; Jiang, Ming

    2017-10-01

    Basis of the boom force analysis of special mobile crane for plain region in transmission line, the load type of boom design is confirmed. According to the different combinations of boom sections, the composite pattern of the different boom length is obtained to suit the actual conditions of boom overlapping. The large deformation model is employed with FEM to simulate the stress distribution of boom, and the calculation results are checked. The performance curves of rated load with different arm length and different working range are obtained, which ensures the lifting capacity of special mobile crane meeting the requirement of tower erection of transmission line. The proposed FEM of boom of mobile crane would provide certain guiding and reference to the boom design.

  10. Innovative Escapement-Based Mechanism for Micro-Antenna Boom Deployment

    NASA Technical Reports Server (NTRS)

    Tokarz, Marta; Grygorczuk, Jerzy; Jarzynka, Stanislaw; Gut, Henryk

    2014-01-01

    This paper presents the prototype of a tubular boom antenna developed for the Polish BRITE-PL satellite by the Space Research Center of the Polish Academy of Sciences (CBK PAN). What is unique about our work is that we developed an original type of the tubular boom antenna deployment mechanism that can be used widely as a basic solution for compact electrical antennas, booms deploying sensitive instruments, ultra-light planetary manipulators etc. The invented electromagnetic driving unit provides a dual complementary action - it adds extra energy to the driving spring, making the system more reliable, and at the same time it moderates the deployment speed acting as a kind of damper. That distinguishing feature predetermines the mechanism to be applied wherever the dynamic nature of a spring drive introducing dangerous vibrations and inducing severe local stress in the structure needs to be mitigated. Moreover, the paper reveals a product unique in Europe - a miniature beryllium bronze tubular boom free of geometry and strain defects, which is essential for stiffness and fatigue resistance. Both the deployment mechanism and the technology of tubular boom manufacturing are protected by patent rights.

  11. Supersonic civil airplane study and design: Performance and sonic boom

    NASA Technical Reports Server (NTRS)

    Cheung, Samson

    1995-01-01

    Since aircraft configuration plays an important role in aerodynamic performance and sonic boom shape, the configuration of the next generation supersonic civil transport has to be tailored to meet high aerodynamic performance and low sonic boom requirements. Computational fluid dynamics (CFD) can be used to design airplanes to meet these dual objectives. The work and results in this report are used to support NASA's High Speed Research Program (HSRP). CFD tools and techniques have been developed for general usages of sonic boom propagation study and aerodynamic design. Parallel to the research effort on sonic boom extrapolation, CFD flow solvers have been coupled with a numeric optimization tool to form a design package for aircraft configuration. This CFD optimization package has been applied to configuration design on a low-boom concept and an oblique all-wing concept. A nonlinear unconstrained optimizer for Parallel Virtual Machine has been developed for aerodynamic design and study.

  12. Theoretical investigation of the role of clay edges in prebiotic peptide bond formation. II - Structures and thermodynamics of the activated complex species

    NASA Technical Reports Server (NTRS)

    Collins, Jack R.; Loew, Gilda H.; Luke, Brian T.; White, David H.

    1988-01-01

    Molecular orbital calculations are used to study amino acid activation by anhydride formation in neutral phosphates and in tetrahedral silicate and aluminate sites on clay edges. The results agree with previous ab initio studies of Luke et al. (1984) on the reactant species. Relative heats of formation of the anhydrides indicate the extent of anhydride formation to be the greatest for Al and the least for phosphate, which is the same order as the stability of hydrolysis.

  13. Design of the De-Orbit Sail Boom Deployment Unit

    NASA Astrophysics Data System (ADS)

    Meyer, Sebastian; Hillebrandt, Martin; Straubel, Marco; Huhne, Christian

    2014-06-01

    The design of the De-Orbit Sail boom deployment unit is strongly driven by volume constraints, which are given by the cubesat container. Four CFRP (carbon fiber reinforced polymer) booms [4] with a cross-sectional shape of a double-omega and a length of 3.6 m are reeled on one spool in the center of the unit. The deployment of the four booms are controlled by an electric motor, which acts on the boom spool. Due to the volume limitation caused by the dimensions of the cubesat deployer the deployment unit has little room for the mechanisms components. With the aim to achieve a robust design, the deployment concept of the unit has greatly changed during the development process. The history of the design as well as the mechanisms are described. Additionally the results of the flight model testing are presented.

  14. Effect of sonic boom asymmetry on subjective loudness

    NASA Technical Reports Server (NTRS)

    Leatherwood, Jack D.; Sullivan, Brenda M.

    1992-01-01

    The NASA Langley Research Center's sonic boom apparatus was used in an experimental study to quantify subjective loudness response to a wide range of asymmetrical N-wave sonic boom signatures. Results were used to assess the relative performance of several metrics as loudness estimators for asymmetrical signatures and to quantify in detail the effects on subjective loudness of varying both the degree and direction of signature loudness asymmetry. Findings of the study indicated that Perceived Level (Steven's Mark 7) and A-weighted sound exposure level were the best metrics for quantifying asymmetrical boom loudness. Asymmetrical signatures were generally rated as being less loud than symmetrical signatures of equivalent Perceived Level. The magnitude of the loudness reductions increased as the degree of boom asymmetry increased, and depended upon the direction of asymmetry. These loudness reductions were not accounted for by any of the metrics. Corrections were determined for use in adjusting calculated Perceived Level values to account for these reductions. It was also demonstrated that the subjects generally incorporated the loudness components of the complete signatures when making their subjective judgments.

  15. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-22

    NASA F-18 jets prepare for takeoff from the agency's Shuttle Landing Facility at NASA's Kennedy Space Center in Florida. Several flights a day have been taking place the week of Aug. 21, 2017 to measure the effects of sonic booms. It is part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  16. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-22

    An engineer in a control trailer at NASA's Kennedy Space Center in Florida monitors data before flights of agency F-18 jets to measure the effects of sonic booms. Several flights a day have been taking place the week of Aug. 21, 2017 as part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  17. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-22

    NASA pilots board an F-18 jet prior to take off from the agency's Shuttle Landing Facility at NASA's Kennedy Space Center in Florida. Several flights a day have been taking place the week of Aug. 21, 2017 to measure the effects of sonic booms. It is part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  18. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-22

    A NASA F-18 jet is prepared for takeoff from the agency's Shuttle Landing Facility at NASA's Kennedy Space Center in Florida. Several flights a day have been taking place the week of Aug. 21, 2017 to measure the effects of sonic booms. It is part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  19. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-22

    A NASA F-18 jet takes off from the agency's Shuttle Landing Facility at NASA's Kennedy Space Center in Florida. Several flights a day have been taking place the week of Aug. 21, 2017 to measure the effects of sonic booms. It is part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  20. Sonic Booms in Atmospheric Turbulence (SonicBAT) Testing

    NASA Image and Video Library

    2017-08-22

    A NASA pilot boards an F-18 jet prior to take off from the agency's Shuttle Landing Facility at NASA's Kennedy Space Center in Florida. Several flights a day have been taking place the week of Aug. 21, 2017 to measure the effects of sonic booms. It is part of NASA's Sonic Booms in Atmospheric Turbulence, or SonicBAT II Program. NASA at Kennedy is partnering with the agency's Armstrong Flight Research Center in California, Langley Research Center in Virginia, and Space Florida for a program in which F-18 jets will take off from the Shuttle Landing Facility and fly at supersonic speeds while agency researchers measure the effects of low-altitude turbulence caused by sonic booms.

  1. An in-home study of subjective response to simulated sonic booms

    NASA Technical Reports Server (NTRS)

    Mccurdy, David A.; Brown, Sherilyn A.; Hilliard, R. David

    1994-01-01

    The proposed development of a second-generation supersonic commercial transport has resulted in increased research efforts to provide an environmentally acceptable aircraft. One of the environmental issues is the impact of sonic booms on people. Aircraft designers are attempting to design the transport to produce sonic boom signatures that will have minimum impact on the public. Current supersonic commercial aircraft produce an 'N-wave' sonic boom pressure signature that is considered unacceptable by the public. This has resulted in first-generation supersonic transports being banned from flying supersonically over land in the United States, a severe economic constraint. By tailoring aircraft volume and lift distributions, designers hope to produce sonic boom signatures having specific shapes other than 'N-wave' that may be more acceptable to the public and could possibly permit overland supersonic flight. As part of the effort to develop a second-generation supersonic commercial transport, Langley Research Center is conducting research to study people's subjective response to sonic booms. As part of that research, a system was developed for performing studies of the subjective response of people to the occurrence of simulated sonic booms in their homes. The In-Home Noise Generation/Response System (IHONORS) provides a degree of situational realism not available in the laboratory and a degree of control over the noise exposure not found in community surveys. The computer-controlled audio system generates the simulated sonic booms, measures the noise levels, and records the subjects' rating and can be placed and operated in individuals' homes for extended periods of time. The system was used to conduct an in-home study of subjective response to simulated sonic booms. The primary objective of the study was to determine the effect on annoyance of the number of sonic boom occurrences in a realistic environment.

  2. Design and Computational/Experimental Analysis of Low Sonic Boom Configurations

    NASA Technical Reports Server (NTRS)

    Cliff, Susan E.; Baker, Timothy J.; Hicks, Raymond M.

    1999-01-01

    Recent studies have shown that inviscid CFD codes combined with a planar extrapolation method give accurate sonic boom pressure signatures at distances greater than one body length from supersonic configurations if either adapted grids swept at the approximate Mach angle or very dense non-adapted grids are used. The validation of CFD for computing sonic boom pressure signatures provided the confidence needed to undertake the design of new supersonic transport configurations with low sonic boom characteristics. An aircraft synthesis code in combination with CFD and an extrapolation method were used to close the design. The principal configuration of this study is designated LBWT (Low Boom Wing Tail) and has a highly swept cranked arrow wing with conventional tails, and was designed to accommodate either 3 or 4 engines. The complete configuration including nacelles and boundary layer diverters was evaluated using the AIRPLANE code. This computer program solves the Euler equations on an unstructured tetrahedral mesh. Computations and wind tunnel data for the LBWT and two other low boom configurations designed at NASA Ames Research Center are presented. The two additional configurations are included to provide a basis for comparing the performance and sonic boom level of the LBWT with contemporary low boom designs and to give a broader experiment/CFD correlation study. The computational pressure signatures for the three configurations are contrasted with on-ground-track near-field experimental data from the NASA Ames 9x7 Foot Supersonic Wind Tunnel. Computed pressure signatures for the LBWT are also compared with experiment at approximately 15 degrees off ground track.

  3. The 1995 NASA High-Speed Research Program Sonic Boom Workshop. Volume 1

    NASA Technical Reports Server (NTRS)

    Baize, Daniel G. (Editor)

    1996-01-01

    The High-Speed Research Program and NASA Langley Research Center sponsored the NASA High-Speed Research Program Sonic Boom Workshop on September 12-13, 1995. The workshop was designed to bring together NASAs scientists and engineers and their counterparts in industry, other Government agencies, and academia working together in the sonic boom element of NASAs High-Speed Research Program. Specific objectives of this workshop were to (1) report the progress and status of research in sonic boom propagation, acceptability, and design; (2) promote and disseminate this technology within the appropriate technical communities; (3) help promote synergy among the scientists working in the Program; and (4) identify technology pacing the development of viable reduced-boom High-Speed Civil Transport concepts. The Workshop included these sessions: Session 1 - Sonic Boom Propagation (Theoretical); Session 2 - Sonic Boom Propagation (Experimental); and Session 3 - Acceptability Studies - Human and Animal.

  4. 53. VIEW OF PASSENGER SPEEDER 04 IN FOREGROUND, BOOM SPEEDER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    53. VIEW OF PASSENGER SPEEDER 04 IN FOREGROUND, BOOM SPEEDER 75 IN BACKGROUND LEFT, AND BOOM SPEEDER 59 IN BACKGROUND RIGHT - Electron Hydroelectric Project, Along Puyallup River, Electron, Pierce County, WA

  5. Conceptual Design of Low-Boom Aircraft with Flight Trim Requirement

    NASA Technical Reports Server (NTRS)

    Ordaz, Irian; Geiselhart, Karl A.; Fenbert, James W.

    2014-01-01

    A new low-boom target generation approach is presented which allows the introduction of a trim requirement during the early conceptual design of supersonic aircraft. The formulation provides an approximation of the center of pressure for a presumed aircraft configuration with a reversed equivalent area matching a low-boom equivalent area target. The center of pressure is approximated from a surrogate lift distribution that is based on the lift component of the classical equivalent area. The assumptions of the formulation are verified to be sufficiently accurate for a supersonic aircraft of high fineness ratio through three case studies. The first two quantify and verify the accuracy and the sensitivity of the surrogate center of pressure corresponding to shape deformation of lifting components. The third verification case shows the capability of the approach to achieve a trim state while maintaining the low-boom characteristics of a previously untrimmed configuration. Finally, the new low-boom target generation approach is demonstrated through the early conceptual design of a demonstrator concept that is low-boom feasible, trimmed, and stable in cruise.

  6. Shuttle sonic boom - Technology and predictions. [environmental impact

    NASA Technical Reports Server (NTRS)

    Holloway, P. F.; Wilhold, G. A.; Jones, J. H.; Garcia, F., Jr.; Hicks, R. M.

    1973-01-01

    Because the shuttle differs significantly in both geometric and operational characteristics from conventional supersonic aircraft, estimation of sonic boom characteristics required a new technology base. The prediction procedures thus developed are reviewed. Flight measurements obtained for both the ascent and entry phases of the Apollo 15 and 16 and for the ascent phase only of the Apollo 17 missions are presented which verify the techniques established for application to shuttle. Results of extensive analysis of the sonic boom overpressure characteristics completed to date are presented which indicate that this factor of the shuttle's environmental impact is predictable, localized, of short duration and acceptable. Efforts are continuing to define the shuttle sonic boom characteristics to a fine level of detail based on the final system design.

  7. Formation and Stabilization of Environmentally Persistent Free Radicals Induced by the Interaction of Anthracene with Fe(III)-Modified Clays.

    PubMed

    Jia, Hanzhong; Nulaji, Gulimire; Gao, Hongwei; Wang, Fu; Zhu, Yunqing; Wang, Chuanyi

    2016-06-21

    Environmentally persistent free radicals (EPFRs) are occasionally detected in Superfund sites but the formation of EPFRs induced by polycyclic aromatic hydrocarbons (PAHs) is not well understood. In the present work, the formation of EPFRs on anthracene-contaminated clay minerals was quantitatively monitored via electron paramagnetic resonance (EPR) spectroscopy, and surface/interface-related environmental influential factors were systematically explored. The obtained results suggest that EPFRs are more readily formed on anthracene-contaminated Fe(III)-montmorillonite than in other tested systems. Depending on the reaction condition, more than one type of organic radicals including anthracene-based radical cations with g-factors of 2.0028-2.0030 and oxygenic carbon-centered radicals featured by g-factors of 2.0032-2.0038 were identified. The formed EPFRs are stabilized by their interaction with interlayer surfaces, and such surface-bound EPFRs exhibit slow decay with 1/e-lifetime of 38.46 days. Transformation pathway and possible mechanism are proposed on the basis of experimental results and quantum mechanical simulations. Overall, the formation of EPFRs involves single-electron-transfer from anthracene to Fe(III) initially, followed by H2O addition on formed aromatic radical cation. Because of their potential exposure in soil and atmosphere, such clay surface-associated EPFRs might induce more serious toxicity than PAHs and exerts significant impacts on human health.

  8. Booming far: the long-range vocal strategy of a lekking bird.

    PubMed

    Cornec, C; Hingrat, Y; Aubin, T; Rybak, F

    2017-08-01

    The pressures of selection acting on transmission of information by acoustic signals are particularly high in long-distance communication networks. Males of the North African houbara bustard ( Chlamydotis undulata undulata ) produce extremely low-frequency vocalizations called 'booms' as a component of their courtship displays. These displays are performed on sites separated by a distance of on average 550 m, constituting exploded leks. Here, we investigate the acoustic features of booms involved in species-specific identity. We first assessed the modifications of acoustic parameters during boom transmission at long range within the natural habitat of the species, finding that the frequency content of booms was reliably transmitted up to 600 m. Additionally, by testing males' behavioural responses to playbacks of modified signals, we found that the presence of the second harmonic and the frequency modulation are the key parameters for species identification, and also that a sequence of booms elicited stronger responses than a single boom. Thus, the coding-decoding process relies on redundant and propagation-resistant features, making the booms particularly well adapted for the long-range transmission of information between males. Moreover, by experimentally disentangling the presentation of visual and acoustic signals, we showed that during the booming phase of courtship, the two sensory modalities act in synergy. The acoustic component is dominant in the context of intra-sexual competition. While the visual component is not necessary to induce agonistic response, it acts as an amplifier and reduces the time of detection of the signaller. The utilization of these adaptive strategies allows houbara males to maximize the active space of vocalizations emitted in exploded leks.

  9. Residents' reactions to long-term sonic boom exposure: Preliminary results

    NASA Technical Reports Server (NTRS)

    Fields, James M.; Moulton, Carey; Baumgartner, Robert M.; Thomas, Jeff

    1994-01-01

    This presentation is about residents' reactions to sonic booms in a long-term sonic boom exposure environment. Although two phases of the data collection have been completed, the analysis of the data has only begun. The results are thus preliminary. The list of four authors reflects the complex multi-disciplinary character of any field study such as this one. Carey Moulton is responsible for Wyle Laboratories' acoustical data collection effort. Robert Baumgartner and Jeff Thomas of HBRS, a social science research firm, are responsible for social survey field work and data processing. The study is supported by the NASA Langley Research Center. The study has several objectives. The preliminary data addresses two of the primary objectives. The first objective is to describe the reactions to sonic booms of people who are living where sonic booms are a routine, recurring feature of the acoustical environment. The second objective is to compare these residents' reactions to the reactions of residents who hear conventional aircraft noise around airports. Here is an overview of the presentation. This study will first be placed in the context of previous community survey research on sonic booms. Next the noise measurement program will be briefly described and part of a social survey interview will be presented. Finally data will be presented on the residents' reactions and these reactions will be compared with reactions to conventional aircraft. Twelve community studies of residents' reactions to sonic booms were conducted in the United States and Europe in the 1960's and early 1970's. None of the 12 studies combined three essential ingredients that are found in the present study. Residents' long-term responses are related to a measured noise environment. Sonic booms are a permanent feature of the residential environment. The respondents' do not live on a military base. The present study is important because it provides the first dose/response relationship for sonic booms

  10. High-Speed Research: 1994 Sonic Boom Workshop. Configuration, Design, Analysis and Testing

    NASA Technical Reports Server (NTRS)

    McCurdy, David A. (Editor)

    1999-01-01

    The third High-Speed Research Sonic Boom Workshop was held at NASA Langley Research Center on June 1-3, 1994. The purpose of this workshop was to provide a forum for Government, industry, and university participants to present and discuss progress in their research. The workshop was organized into sessions dealing with atmospheric propagation; acceptability studies; and configuration design, and testing. Attendance at the workshop was by invitation only. The workshop proceedings include papers on design, analysis, and testing of low-boom high-speed civil transport configurations and experimental techniques for measuring sonic booms. Significant progress is noted in these areas in the time since the previous workshop a year earlier. The papers include preliminary results of sonic boom wind tunnel tests conducted during 1993 and 1994 on several low-boom designs. Results of a mission performance analysis of all low-boom designs are also included. Two experimental methods for measuring near-field signatures of airplanes in flight are reported.

  11. Evaluation of human response to structural vibrations induced by sonic booms

    NASA Technical Reports Server (NTRS)

    Sutherland, Louis C.; Czech, J.

    1992-01-01

    The topic is addressed of building vibration response to sonic boom and the evaluation of the associated human response to this vibration. An attempt is made to reexamine some of the issues addressed previously and to offer fresh insight that may assist in reassessing the potential impact of sonic boom over populated areas. Human response to vibration is reviewed first and a new human vibration response criterion curve is developed as a function of frequency. The difference between response to steady state versus impulsive vibration is addressed and a 'vibration exposure' or 'vibration energy' descriptor is suggested as one possible way to evaluate duration effects on response to transient vibration from sonic booms. New data on the acoustic signature of rattling objects are presented along with a review of existing data on the occurrence of rattle. Structural response to sonic boom is reviewed and a new descriptor, 'Acceleration Exposure Level' is suggested which can be easily determined from the Fourier Spectrum of a sonic boom. A preliminary assessment of potential impact from sonic booms is provided in terms of human response to vibration and detection of rattle based on a synthesis of the preceding material.

  12. USAF Flight Test Investigation of Focused Sonic Booms: Project Have Bears

    NASA Technical Reports Server (NTRS)

    Downing, Micah; Zamot, Noel; Moss, Chris; Morin, Daniel; Wolski, Ed; Chung, Sukhwan; Plotkin, Kenneth; Maglieri, Domenic

    1996-01-01

    Supersonic operations from military aircraft generate sonic booms that can affect people, animals and structures. A substantial experimental data base exists on sonic booms for aircraft in steady flight and confidence in the predictive techniques has been established. All the focus sonic boom data that are in existence today were collected during the 60's and 70's as part of the information base to the US Supersonic Transport program and the French Jericho studies for the Concorde. These experiments formed the data base to develop sonic boom propagation and prediction theories for focusing. There is a renewed interest in high-speed transports for civilian application. Moreover, today's fighter aircraft have better performance capabilities, and supersonic flights ars more common during air combat maneuvers. Most of the existing data on focus booms are related to high-speed civil operations such as transitional linear accelerations and mild turns. However, military aircraft operating in training areas perform more drastic maneuvers such as dives and high-g turns. An update and confirmation of USAF prediction capabilities is required to demonstrate the ability to predict and control sonic boom impacts, especially those produced by air combat maneuvers.

  13. Ground-based sensors for the SR-71 sonic boom propagation experiment

    NASA Technical Reports Server (NTRS)

    Norris, Stephen R.; Haering, Edward A., Jr.; Murray, James E.

    1995-01-01

    This paper describes ground-level measurements of sonic boom signatures made as part of the SR-71 sonic boom propagation experiment recently completed at NASA Dryden Flight Research Center, Edwards, California. Ground level measurements were the final stage of this experiment which also included airborne measurements at near and intermediate distances from an SR-71 research aircraft. Three types of sensors were deployed to three station locations near the aircraft ground track. Pressure data were collected for flight conditions from Mach 1.25 to Mach 1.60 at altitudes from 30,000 to 48,000 ft. Ground-level measurement techniques, comparisons of data sets from different ground sensors, and sensor system strengths and weaknesses are discussed. The well-known N-wave structure dominated the sonic boom signatures generated by the SR-71 aircraft at most of these conditions. Variations in boom shape caused by atmospheric turbulence, focusing effects, or both were observed for several flights. Peak pressure and boom event duration showed some dependence on aircraft gross weight. The sonic boom signatures collected in this experiment are being compiled in a data base for distribution in support of the High Speed Research Program.

  14. The nature of porosity in organic-rich mudstones of the Upper Jurassic Kimmeridge Clay Formation, North Sea, offshore United Kingdom

    USGS Publications Warehouse

    Fishman, Neil S.; Hackley, Paul C.; Lowers, Heather; Hill, Ronald J.; Egenhoff, Sven O.; Eberl, Dennis D.; Blum, Alex E.

    2012-01-01

    Analyses of organic-rich mudstones from wells that penetrated the Upper Jurassic Kimmeridge Clay Formation, offshore United Kingdom, were performed to evaluate the nature of both organic and inorganic rock constituents and their relation to porosity in this world-class source rock. The formation is at varying levels of thermal maturity, ranging from immature in the shallowest core samples to mature in the deepest core samples. The intent of this study was to evaluate porosity as a function of both organic macerals and thermal maturity. At least four distinct types of organic macerals were observed in petrographic and SEM analyses and they all were present across the study area. The macerals include, in decreasing abundance: 1) bituminite admixed with clays; 2) elongate lamellar masses (alginite or bituminite) with small quartz, feldspar, and clay entrained within it; 3) terrestrial (vitrinite, fusinite, semifusinite) grains; and 4) Tasmanites microfossils. Although pores in all maceral types were observed on ion-milled surfaces of all samples, the pores (largely nanopores with some micropores) vary as a function of maceral type. Importantly, pores in the macerals do not vary systematically as a function of thermal maturity, insofar as organic pores are of similar size and shape in both the immature and mature Kimmeridge rocks. If any organic pores developed during the generation of hydrocarbons, they were apparently not preserved, possibly because of the highly ductile nature of much of the rock constituents of Kimmeridge mudstones (clays and organic material). Inorganic pores (largely micropores with some nanopores) have been observed in all Kimmeridge mudstones. These pores, particularly interparticle (i.e., between clay platelets), and intraparticle (i.e., in framboidal pyrite, in partially dissolved detrital K-feldspar, and in both detrital and authigenic dolomite) are noteworthy because they compose much of the observable porosity in the shales in both

  15. Sonic boom (human response and atmospheric effects) outdoor-to-indoor response to minimized sonic booms

    NASA Technical Reports Server (NTRS)

    Brown, David; Sutherland, Louis C.

    1992-01-01

    The preferred descriptor to define the spectral content of sonic booms is the Sound Exposure Spectrum Level, LE(f). This descriptor represents the spectral content of the basic noise descriptors used for describing any single event--the Sound Exposure Level, LE. The latter is equal to ten times the logarithms, to the base ten, of the integral, over the duration of the event, of the square of the instantaneous acoustic pressure, divided by the square of the reference pressure, 20 micro-Pa. When applied to the evaluation of community response to sonic booms, it is customary to use the so-called C-Weighted Sound Exposure Level, LCE, for which the frequency content of the instantaneous acoustic pressure is modified by the C-Weighting curve.

  16. Lateral Cutoff Analysis and Results from NASA's Farfield Investigation of No-Boom Thresholds

    NASA Technical Reports Server (NTRS)

    Cliatt, Larry J., II; Haering, Edward A., Jr.; Arnac, Sarah R.; Hill, Michael A.

    2016-01-01

    In support of the ongoing effort by the National Aeronautics and Space Administration (NASA) to bring supersonic commercial travel to the public, the NASA Armstrong Flight Research Center (AFRC) and the NASA Langley Research Center (LaRC), in partnership with other industry organizations and academia, conducted a flight research experiment to analyze acoustic propagation at the lateral edge of the sonic boom carpet. The name of the effort was the Farfield Investigation of No-boom Thresholds (FaINT). The test helped to build a dataset that will go toward further understanding of the unique acoustic propagation characteristics near the sonic boom carpet extremity. The FaINT was an effort that collected finely-space sonic boom data across the entire lateral cutoff transition region. A major objective of the effort was to investigate the acoustic phenomena that occur at the audible edge of a sonic boom carpet, including the transition and shadow zones. A NASA F-18B aircraft made supersonic passes such that its sonic boom carpet transition zone would intersect a linear 60-microphone, 7500-ft long array. A TG-14 motor glider equipped with a microphone on its wing also attempted to capture the same sonic boom rays that were measured on the ground, at altitudes of 3000 - 6000 ft above ground level. This paper determined an appropriate metric for sonic boom waveforms in the transition and shadow zones called Perceived Sound Exposure Level, and established a value of 65 dB as a limit for the acoustic levels defining the lateral extent of a sonic boom's noise region; analyzed the change in sonic boom levels as a function of distance from flight path both on the ground and 4500 ft above the ground; and compared between sonic boom measurements and numerical predictions.

  17. The Prep School Boom

    ERIC Educational Resources Information Center

    Stent, Angela

    1976-01-01

    Applications to preparatory schools have risen dramatically in the past five years, as much as 500 percent at some prestigious institutions. Most educators agree that the main reason for this boom is the growing disenchantment with vast, anomic public high schools, both urban and suburban. (LBH)

  18. Feasibility of Supersonic Aircraft Concepts for Low-Boom and Flight Trim Constraints

    NASA Technical Reports Server (NTRS)

    Li, Wu

    2015-01-01

    This paper documents a process for analyzing whether a particular supersonic aircraft configuration layout and a given cruise condition are feasible to achieve a trimmed low-boom design. This process was motivated by the need to know whether a particular configuration at a given cruise condition could be reshaped to satisfy both low-boom and flight trim constraints. Without such a process, much effort could be wasted on shaping a configuration layout at a cruise condition that could never satisfy both low-boom and flight trim constraints simultaneously. The process helps to exclude infeasible configuration layouts with minimum effort and allows a designer to develop trimmed low-boom concepts more effectively. A notional low-boom supersonic demonstrator concept is used to illustrate the analysis/design process.

  19. Subjective response to sonic booms having different shapes, rise times, and durations

    NASA Technical Reports Server (NTRS)

    Mccurdy, David A.

    1994-01-01

    Two laboratory experiments were conducted to quantify the subjective response of people to simulated outdoor sonic booms having different pressure signatures. The specific objectives of the experiments were to compare subjective response to sonic booms when described in terms of 'loudness' and 'annoyance'; to determine the ability of various noise metrics to predict subjective response to sonic booms; to determine the effects on subjective response of rise time, duration, and level; and to compare the subjective response to 'N-wave' sonic boom signatures with the subjective response to 'minimized' sonic boom signatures. The experiments were conducted in a computer-controlled, man-rated sonic boom simulator capable of reproducing user-specified pressure signatures for a wide range of sonic boom parameters. One hundred and fifty sonic booms representing different combinations of two wave shapes, four rise times, seven durations, and three peak overpressures were presented to 36 test subjects in each experiment. The test subjects in the first experiment made judgments of 'loudness' while the test subjects in the second experiment judged 'annoyance.' Subjective response to sonic booms was the same whether expressed in terms of loudness or in terms of annoyance. Analyses of several different noise metrics indicated that A-weighted sound exposure level and Perceived Level were the best predictors of subjective response. Further analyses indicated that, of these two noise metrics, only Perceived Level completely accounted for the effects of wave shape, rise time, and peak overpressure. Neither metric fully accounted for the effect of duration. However, the magnitude of the duration effect was small over the very wide range of durations considered.

  20. Design and evaluation of pick-up truck mounted boom for elevation of a multiband radiometer system

    NASA Technical Reports Server (NTRS)

    Bauer, M. E. (Principal Investigator); Tsuchida, R.

    1981-01-01

    Three concepts were considered for the boom design: a one-piece boom with a trolley, a folding boom, and a telescoping boom. The telescoping boom was selected over the other two concepts because of its easy manual operation. The boom is designed to mount on the bed of a pick-up truck and elevate the radiometer system 8 meters above the ground and 4 meters away from the truck. The selection of the boom components is discussed with justification of the final choice. Results of performance tests and one season's operation of the completed boom are reported.

  1. Sonic boom predictions using a modified Euler code

    NASA Technical Reports Server (NTRS)

    Siclari, Michael J.

    1992-01-01

    The environmental impact of a next generation fleet of high-speed civil transports (HSCT) is of great concern in the evaluation of the commercial development of such a transport. One of the potential environmental impacts of a high speed civilian transport is the sonic boom generated by the aircraft and its effects on the population, wildlife, and structures in the vicinity of its flight path. If an HSCT aircraft is restricted from flying overland routes due to excessive booms, the commercial feasibility of such a venture may be questionable. NASA has taken the lead in evaluating and resolving the issues surrounding the development of a high speed civilian transport through its High-Speed Research Program (HSRP). The present paper discusses the usage of a Computational Fluid Dynamics (CFD) nonlinear code in predicting the pressure signature and ultimately the sonic boom generated by a high speed civilian transport. NASA had designed, built, and wind tunnel tested two low boom configurations for flight at Mach 2 and Mach 3. Experimental data was taken at several distances from these models up to a body length from the axis of the aircraft. The near field experimental data serves as a test bed for computational fluid dynamic codes in evaluating their accuracy and reliability for predicting the behavior of future HSCT designs. Sonic boom prediction methodology exists which is based on modified linear theory. These methods can be used reliably if near field signatures are available at distances from the aircraft where nonlinear and three dimensional effects have diminished in importance. Up to the present time, the only reliable method to obtain this data was via the wind tunnel with costly model construction and testing. It is the intent of the present paper to apply a modified three dimensional Euler code to predict the near field signatures of the two low boom configurations recently tested by NASA.

  2. Clay Minerals as Solid Acids and Their Catalytic Properties.

    ERIC Educational Resources Information Center

    Helsen, J.

    1982-01-01

    Discusses catalytic properties of clays, attributed to acidity of the clay surface. The formation of carbonium ions on montmorillonite is used as a demonstration of the presence of surface acidity, the enhanced dissociation of water molecules when polarized by cations, and the way the surface can interact with organic substances. (Author/JN)

  3. Simulated sonic booms and sleep : effects of repeated booms of 1.0 psf.

    DOT National Transportation Integrated Search

    1972-12-01

    Eight male subjects in each of three age groups (21-26, 40-45, 60-72 years) slept in pairs in the CAMI sonic boom simulation facility for 21 consecutive nights. The first five nights were used to acclimate the subjects (nights 1 and 2) and to obtain ...

  4. 76 FR 20532 - Safety Zone; Boom Days, Niagara River, Niagara Falls, NY

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-13

    ...-AA00 Safety Zone; Boom Days, Niagara River, Niagara Falls, NY AGENCY: Coast Guard, DHS. ACTION..., Niagara Falls, NY for the Boom Days Fireworks. This zone is intended to restrict vessels from La Salle Marina and a portion of the Niagara River, Niagara Falls, NY during the Boom Days Fireworks on April 16...

  5. The effect of photoelectrons on boom-satellite potential differences during electron beam ejection

    NASA Technical Reports Server (NTRS)

    Lai, Shu T.; Cohen, Herbert A.; Aggson, Thomas L.; Mcneil, William J.

    1987-01-01

    Data taken on the SCATHA satellite at geosynchronous altitudes during periods of electron beam ejection in sunlight showed that the potential difference between an electrically isolated boom and the satellite main body was a function of beam current, energy, and boom-sun angle. The potential difference decreased as the boom area illuminated by the sun increased; the maximum and minimum potential differences were measured when minimum and maximum boom areas, respectively, were exposed to the sun. It is shown that photoelectrons, created on the boom, could be engulfed in the electrostatic field of the highly charged satellite main body. Theoretical calculations made using a simple current balance model showed that these electrons could provide a substantial discharging current to the main body and cause the observed variations in the potential difference between the main body and the booms.

  6. Langley's Computational Efforts in Sonic-Boom Softening of the Boeing HSCT

    NASA Technical Reports Server (NTRS)

    Fouladi, Kamran

    1999-01-01

    NASA Langley's computational efforts in the sonic-boom softening of the Boeing high-speed civil transport are discussed in this paper. In these efforts, an optimization process using a higher order Euler method for analysis was employed to reduce the sonic boom of a baseline configuration through fuselage camber and wing dihedral modifications. Fuselage modifications did not provide any improvements, but the dihedral modifications were shown to be an important tool for the softening process. The study also included aerodynamic and sonic-boom analyses of the baseline and some of the proposed "softened" configurations. Comparisons of two Euler methodologies and two propagation programs for sonic-boom predictions are also discussed in the present paper.

  7. Effects of clay dispersion on aquifer storage and recovery in coastal aquifers

    USGS Publications Warehouse

    Konikow, Leonard F.; August, L.L.; Voss, C.I.

    2001-01-01

    Cyclic injection, storage, and withdrawal of freshwater in brackish aquifers is a form of aquifer storage and recovery (ASR) that can beneficially supplement water supplies in coastal areas. A 1970s field experiment in Norfolk, Virginia, showed that clay dispersion in the unconsolidated sedimentary aquifer occurred because of cation exchange on clay minerals as freshwater displaced brackish formation water. Migration of interstitial clay particles clogged pores, reduced permeability, and decreased recovery efficiency, but a calcium preflush was found to reduce clay dispersion and lead to a higher recovery efficiency. Column experiments were performed in this study to quantify the relations between permeability changes and clay mineralogy, clay content, and initial water salinity. The results of these experiments indicate that dispersion of montmorillonite clay is a primary contributor to formation damage. The reduction in permeability by clay dispersion may be expressed as a linear function of chloride content. Incorporating these simple functions into a radial, cross-sectional, variable-density, ground-water flow and transport model yielded a satisfactory simulation of the Norfolk field test - and represented an improvement over the model that ignored changes in permeability. This type of model offers a useful planning and design tool for ASR operations in coastal clastic aquifer systems.

  8. Preliminary airborne measurements for the SR-71 sonic boom propagation experiment

    NASA Technical Reports Server (NTRS)

    Haering, Edward A., Jr.; Ehernberger, L. J.; Whitmore, Stephen A.

    1995-01-01

    SR-71 sonic boom signatures were measured to validate sonic boom propagation prediction codes. An SR-71 aircraft generated sonic booms from Mach 1.25 to Mach 1.6, at altitudes of 31,000 to 48,000 ft, and at various gross weights. An F-16XL aircraft measured the SR-71 near-field shock waves from close to the aircraft to more than 8,000 ft below, gathering 105 signatures. A YO-3A aircraft measured the SR-71 sonic booms from 21,000 to 38,000 feet below, recording 17 passes. The sonic booms at ground level and atmospheric data were recorded for each flight. Data analysis is underway. Preliminary results show that shock wave patterns and coalescence vary with SR-71 gross weight, Mach number, and altitude. For example, noncoalesced shock wave signatures were measured by the YO-3A at 21,000 ft below the SR-71 aircraft while at a low gross weight, Mach 1.25, and 31,000-ft altitude. This paper describes the design and execution of the flight research experiment. Instrumentation and flight maneuvers of the SR-71, F-16XL, and YO-3A aircraft and sample sonic boom signatures are included.

  9. Baby Boom Equals Career Bust. Monographs on Career Education.

    ERIC Educational Resources Information Center

    Moore, Charles Guy

    Presenting the Baby Boom (1946-1965) as both a potential social problem and opportunity for American leadership, this monograph discusses the following aspects of this population concern: (1) its immediate and long-term impact on career opportunities for those college graduates who make up the baby boom generation; (2) its impact on those whose…

  10. Inlet Trade Study for a Low-Boom Aircraft Demonstrator

    NASA Technical Reports Server (NTRS)

    Heath, Christopher M.; Slater, John W.; Rallabhandi, Sriram K.

    2016-01-01

    Propulsion integration for low-boom supersonic aircraft requires careful inlet selection, placement, and tailoring to achieve acceptable propulsive and aerodynamic performance, without compromising vehicle sonic boom loudness levels. In this investigation, an inward-turning streamline-traced and axisymmetric spike inlet are designed and independently installed on a conceptual low-boom supersonic demonstrator aircraft. The airframe was pre-shaped to achieve a target ground under-track loudness of 76.4 PLdB at cruise using an adjoint-based design optimization process. Aircraft and inlet performance characteristics were obtained by solution of the steady-state Reynolds-averaged Navier-Stokes equations. Isolated cruise inlet performance including total pressure recovery and distortion were computed and compared against installed inlet performance metrics. Evaluation of vehicle near-field pressure signatures, along with under- and off-track propagated loudness levels is also reported. Results indicate the integrated axisymmetric spike design offers higher inlet pressure recovery, lower fan distortion, and reduced sonic boom. The vehicle with streamline-traced inlet exhibits lower external wave drag, which translates to a higher lift-to-drag ratio and increased range capability.

  11. Development of a Deployable Nonmetallic Boom for Reconfigurable Systems of Small Spacecraft

    NASA Technical Reports Server (NTRS)

    Rehnmark, Fredrik; Pryor, Mark; Holmes, Buck; Schaechter, David; Pedreiro, Nelson; Carrington, Connie

    2007-01-01

    In 2005, NASA commenced Phase 1 of the Modular Reconfigurable High Energy Technology Demonstrator (MRHE) program to investigate reconfigurable systems of small spacecraft. During that year, Lockheed Martin's Advanced Technology Center (ATC) led an accelerated effort to develop a 1-g MRHE concept demonstration featuring robotic spacecraft simulators equipped with docking mechanisms and deployable booms. The deployable boom built for MRHE was the result of a joint effort in which ATK was primarily responsible for developing and fabricating the Collapsible Rollable Tube (CRT patent pending) boom while Lockheed Martin designed and built the motorized Boom Deployment Mechanism (BDM) under a concurrent but separate IR&D program. Tight coordination was necessary to meet testbed integration and functionality requirements. This paper provides an overview of the CRT boom and BDM designs and presents preliminary results of integration and testing to support the MRHE demonstration.

  12. Physicians workforce: legal immigrants will extend baby boom demands.

    PubMed

    2005-10-15

    The baby boom generation will place large demands on the Medicare program and the U.S. health care system. These demands may be extended by a large legal immigrant population that will become Medicare-eligible soon after the baby boom generation does. The U.S. health care system should be prepared for sustained stress from this again population.

  13. Atomic force microscopy measurements of bacterial adhesion and biofilm formation onto clay-sized particles

    PubMed Central

    Huang, Qiaoyun; Wu, Huayong; Cai, Peng; Fein, Jeremy B.; Chen, Wenli

    2015-01-01

    Bacterial adhesion onto mineral surfaces and subsequent biofilm formation play key roles in aggregate stability, mineral weathering, and the fate of contaminants in soils. However, the mechanisms of bacteria-mineral interactions are not fully understood. Atomic force microscopy (AFM) was used to determine the adhesion forces between bacteria and goethite in water and to gain insight into the nanoscale surface morphology of the bacteria-mineral aggregates and biofilms formed on clay-sized minerals. This study yields direct evidence of a range of different association mechanisms between bacteria and minerals. All strains studied adhered predominantly to the edge surfaces of kaolinite rather than to the basal surfaces. Bacteria rarely formed aggregates with montmorillonite, but were more tightly adsorbed onto goethite surfaces. This study reports the first measured interaction force between bacteria and a clay surface, and the approach curves exhibited jump-in events with attractive forces of 97 ± 34 pN between E. coli and goethite. Bond strengthening between them occurred within 4 s to the maximum adhesion forces and energies of −3.0 ± 0.4 nN and −330 ± 43 aJ (10−18 J), respectively. Under the conditions studied, bacteria tended to form more extensive biofilms on minerals under low rather than high nutrient conditions. PMID:26585552

  14. Clays, specialty

    USGS Publications Warehouse

    Virta, R.L.

    1998-01-01

    Part of a special section on the state of industrial minerals in 1997. The state of the specialty clay industry worldwide for 1997 is discussed. The specialty clays mined in the U.S. are ball clay, fuller's earth, bentonite, fire clay, and kaolin. Sales of specialty clays in the U.S. were around 17 Mt in 1997. Approximately 53 kt of specialty clays were imported.

  15. Origins and Overview of the Shaped Sonic Boom Demonstration Program

    NASA Technical Reports Server (NTRS)

    Pawlowski, Joseph W.; Graham, David H.; Boccadoro, Charles H.; Coen, Peter G.; Maglieri, Domenic J.

    2005-01-01

    The goal of the DARPA Shaped Sonic Boom Demonstration (SSBD) Program was to demonstrate for the first time in flight that sonic booms can be substantially reduced by incorporating specialized aircraft shaping techniques. Although mitigation of the sonic boom via specialized shaping techniques was theorized decades ago, until now, this theory had never been tested with a flight vehicle subjected to actual flight conditions in a real atmosphere. The demonstrative success, which occurred on 27 August 2003 with repeat flights in the supersonic corridor at Edwards Air Force Base, is a critical milestone in the development of next generation supersonic aircraft that could one day fly unrestricted over land and help usher in a new era of time-critical air transport. Pressure measurements obtained on the ground and in the air confirmed that the specific modifications made to a Northrop Grumman F-5E aircraft not only changed the shape of the shock wave signature emanating from the aircraft, but also produced a flat-top signature whose shape persisted, as predicted, as the pressure waves propagated through the atmosphere to the ground. This accomplishment represents a major advance towards reducing the startling and potentially damaging noise of a sonic boom. This paper describes the evolution of the SSBD program, including the rationale for test article selection, and provides an overview of the history making accomplishments achieved during the SSBD effort, as well as, the follow-on NASA Shaped Sonic Boom Experiment (SSBE) Program, whose goal was to further evaluate the characteristics and robustness of shaped boom signatures.

  16. Evaluation of an Indoor Sonic Boom Subjective Test Facility at NASA Langley Research Center

    NASA Technical Reports Server (NTRS)

    Loubeau, Alexandra; Rathsam, Jonathan; Klos, Jacob

    2011-01-01

    A sonic boom simulator at NASA Langley Research Center has been constructed for research on human response to low-amplitude sonic booms heard indoors. Research in this facility will ultimately lead to development of a psychoacoustic model for single indoor booms. The first subjective test was designed to explore indoor human response to variations in sonic boom rise time and amplitude. Another goal was to identify loudness level variability across listener locations within the facility. Finally, the test also served to evaluate the facility as a laboratory research tool for studying indoor human response to sonic booms. Subjects listened to test sounds and were asked to rate their annoyance relative to a reference boom. Measurements of test signals were conducted for objective analysis and correlation with subjective responses. Results confirm the functionality of the facility and effectiveness of the test methods and indicate that loudness level does not fully describe indoor annoyance to the selected sonic boom signals.

  17. Preliminary Analysis of the 30-m UltraBoom Flight Test

    NASA Technical Reports Server (NTRS)

    Agnes, Gregory S.; Abelson, Robert D.; Miyake, Robert; Lin, John K. H.; Welsh, Joe; Watson, Judith J.

    2005-01-01

    Future NASA missions require long, ultra-lightweight booms to enable solar sails, large sunshields, and other gossamer-type spacecraft structures. The space experiment discussed in this paper will flight validate the non-traditional ultra lightweight rigidizable, inflatable, isogrid structure utilizing graphite shape memory polymer (GR/SMP) called UltraBoom(TradeMark). The focus of this paper is the analysis of the 3-m ground test article. The primary objective of the mission is to show that a combination of ground testing and analysis can predict the on-orbit performance of an ultra lightweight boom that is scalable, predictable, and thermomechanically stable.

  18. Orbiter Boom Sensor System extended

    NASA Image and Video Library

    2005-07-27

    STS114-E-5330 (28 July 2005) --- As seen from Discovery's cabin, STS-114 Remote Manipulator System (RMS) robot arm flexes above Earth. Crews of Space Station and Discovery will later use RMS and boom to study Shuttle's tiles.

  19. Large-Scale Low-Boom Inlet Test Overview

    NASA Technical Reports Server (NTRS)

    Hirt, Stefanie

    2011-01-01

    This presentation provides a high level overview of the Large-Scale Low-Boom Inlet Test and was presented at the Fundamental Aeronautics 2011 Technical Conference. In October 2010 a low-boom supersonic inlet concept with flow control was tested in the 8'x6' supersonic wind tunnel at NASA Glenn Research Center (GRC). The primary objectives of the test were to evaluate the inlet stability and operability of a large-scale low-boom supersonic inlet concept by acquiring performance and flowfield validation data, as well as evaluate simple, passive, bleedless inlet boundary layer control options. During this effort two models were tested: a dual stream inlet intended to model potential flight hardware and a single stream design to study a zero-degree external cowl angle and to permit surface flow visualization of the vortex generator flow control on the internal centerbody surface. The tests were conducted by a team of researchers from NASA GRC, Gulfstream Aerospace Corporation, University of Illinois at Urbana-Champaign, and the University of Virginia

  20. An Analysis of Measured Pressure Signatures From Two Theory-Validation Low-Boom Models

    NASA Technical Reports Server (NTRS)

    Mack, Robert J.

    2003-01-01

    Two wing/fuselage/nacelle/fin concepts were designed to check the validity and the applicability of sonic-boom minimization theory, sonic-boom analysis methods, and low-boom design methodology in use at the end of the 1980is. Models of these concepts were built, and the pressure signatures they generated were measured in the wind-tunnel. The results of these measurements lead to three conclusions: (1) the existing methods could adequately predict sonic-boom characteristics of wing/fuselage/fin(s) configurations if the equivalent area distributions of each component were smooth and continuous; (2) these methods needed revision so the engine-nacelle volume and the nacelle-wing interference lift disturbances could be accurately predicted; and (3) current nacelle-configuration integration methods had to be updated. With these changes in place, the existing sonic-boom analysis and minimization methods could be effectively applied to supersonic-cruise concepts for acceptable/tolerable sonic-boom overpressures during cruise.

  1. Analysis of Nozzle Jet Plume Effects on Sonic Boom Signature

    NASA Technical Reports Server (NTRS)

    Bui, Trong

    2010-01-01

    An axisymmetric full Navier-Stokes computational fluid dynamics (CFD) study was conducted to examine nozzle exhaust jet plume effects on the sonic boom signature of a supersonic aircraft. A simplified axisymmetric nozzle geometry, representative of the nozzle on the NASA Dryden NF-15B Lift and Nozzle Change Effects on Tail Shock (LaNCETS) research airplane, was considered. The highly underexpanded nozzle flow is found to provide significantly more reduction in the tail shock strength in the sonic boom N-wave pressure signature than perfectly expanded and overexpanded nozzle flows. A tail shock train in the sonic boom signature, similar to what was observed in the LaNCETS flight data, is observed for the highly underexpanded nozzle flow. The CFD results provide a detailed description of the nozzle flow physics involved in the LaNCETS nozzle at different nozzle expansion conditions and help in interpreting LaNCETS flight data as well as in the eventual CFD analysis of a full LaNCETS aircraft. The current study also provided important information on proper modeling of the LaNCETS aircraft nozzle. The primary objective of the current CFD research effort was to support the LaNCETS flight research data analysis effort by studying the detailed nozzle exhaust jet plume s imperfect expansion effects on the sonic boom signature of a supersonic aircraft. Figure 1 illustrates the primary flow physics present in the interaction between the exhaust jet plume shock and the sonic boom coming off of an axisymmetric body in supersonic flight. The steeper tail shock from highly expanded jet plume reduces the dip of the sonic boom N-wave signature. A structured finite-volume compressible full Navier-Stokes CFD code was used in the current study. This approach is not limited by the simplifying assumptions inherent in previous sonic boom analysis efforts. Also, this study was the first known jet plume sonic boom CFD study in which the full viscous nozzle flow field was modeled, without

  2. In-Flight Technique for Acquiring Mid- And Far-Field Sonic Boom Signatures

    NASA Technical Reports Server (NTRS)

    Stansbery, Eugene G.; Baize, Daniel G.; Maglieri, Domenic, J.

    1999-01-01

    Flight test experiments have been conducted to establish the feasibility of obtaining sonic boom signature measurements below a supersonic aircraft using the NASA Portable Automatic Triggering System (PATS) mounted in the USMC Pioneer Unmanned Aerial Vehicle (UAV). This study forms a part of the NASA sonic boom minimization activities, specifically the demonstration of persistence of modified boom signatures to very large distances in a real atmosphere. The basic objective of the measurement effort was to obtain a qualitative view of the sonic boom signature in terms of its shape, number of shocks, their locations, and their relative strength. Results suggest that the technique may very well provide quantitative information relative to mid-field and far-field boom signatures. The purpose of this presentation is to describe the arrangement and operation of this in-flight system and to present the resulting sonic boom measurements. Adaption and modification of two PATS to the UAV payload section are described and include transducer location, mounting arrangement and recording system isolation. Ground static runup, takeoff and landing, and cruise flight checkouts regarding UAV propeller and flow noise on the PATS automated triggering system and recording mode are discussed. For the proof-of-concept tests, the PATS instrumented UAV was flown under radar control in steady-level flight at the altitude of 8700 feet MSL and at a cruise speed of about 60 knots. The USN F-4N sonic boom generating aircraft was vectored over the UAV on reciprocal headings at altitudes of about 1 1,000 feet MSL and 13,000 feet MSL at about Mach 1. 15. Sonic boom signatures were acquired on both PATS for all six supersonic passes. Although the UAV propeller noise is clearly evident in all the measurements, the F-4 boom signature is clearly distinguishable and is typically N-wave in character with sharply rising shock fronts and with a mid-shock associated with the inlet-wing juncture

  3. Using CFD Surface Solutions to Shape Sonic Boom Signatures Propagated from Off-Body Pressure

    NASA Technical Reports Server (NTRS)

    Ordaz, Irian; Li, Wu

    2013-01-01

    The conceptual design of a low-boom and low-drag supersonic aircraft remains a challenge despite significant progress in recent years. Inverse design using reversed equivalent area and adjoint methods have been demonstrated to be effective in shaping the ground signature propagated from computational fluid dynamics (CFD) off-body pressure distributions. However, there is still a need to reduce the computational cost in the early stages of design to obtain a baseline that is feasible for low-boom shaping, and in the search for a robust low-boom design over the entire sonic boom footprint. The proposed design method addresses the need to reduce the computational cost for robust low-boom design by using surface pressure distributions from CFD solutions to shape sonic boom ground signatures propagated from CFD off-body pressure.

  4. Comparisons of Methods for Predicting Community Annoyance Due to Sonic Booms

    NASA Technical Reports Server (NTRS)

    Hubbard, Harvey H.; Shepherd, Kevin P.

    1996-01-01

    Two approaches to the prediction of community response to sonic boom exposure are examined and compared. The first approach is based on the wealth of data concerning community response to common transportation noises coupled with results of a sonic boom/aircraft noise comparison study. The second approach is based on limited field studies of community response to sonic booms. Substantial differences between indoor and outdoor listening conditions are observed. Reasonable agreement is observed between predicted community responses and available measured responses.

  5. Clay deposits of the Tierra Colorado district, southern Orange County, California

    USGS Publications Warehouse

    Daviess, Steven Norman; Bramlette, M.N.

    1953-01-01

    The clay of this district is being mined for fire brick by the Vitrofrax Corporation. Much of the clay contains 35 percent or more of alumina and between 1 and 2 percent of iron oxide. Production is largely from an underground mine as the best clay deposit known in the district occurs on the side of a steep hill with more than 100 feet of sandstone overlying most of it. The good clay deposits occur at the base of an Eocene sandstone formation, and overlie mottled clays with a high iron content that are residual deposits formed on an old weathered surface. Mapping indicates that the clay deposits are very lenticular, though all occur at the same stratigraphic position, and they grade laterally into sandy clay and quartz sand. Topographic relief and the dip of the strata preclude finding large areas where the clay strata have relatively little overburden.

  6. Green Clay Minerals

    NASA Astrophysics Data System (ADS)

    Velde, B.

    2003-12-01

    in the silicate (clay mineral in our case) structure, the specific bonding of these ions, and other factors. In fact, the reasons for coloration are not known completely, but it is certain that a combination of Fe2+ and Fe3+ ions is necessary to give a nice green color to clays. In the green clay minerals discussed here, the colors vary greatly as seen under the optical microscope (not always the same as the one seen in hand specimen). Yellow to blue-green hues can be found. However, for the moment, no clear relation between iron content, iron valence ratio, or other factors such as minor transition element concentrations can be found to explain the greenness of green clay minerals. The fact that a clay is green just indicates a combination of the two oxidation states of iron. The color, however, indicates the key to the formation in nature of green clay minerals.Green clay minerals are in general the product of "mixed valence" conditions of formation, most often in a situation where some iron is reduced from Fe3+ and enters into a silicate mineral structure. In general, iron would rather be an oxide when it is in the trivalent state. The moment iron is reduced to a divalent state under surface or near-surface conditions, it looks for a silicate, sulfide, or carbonate to hide in. The reverse is also true, of course. When a silicate is oxidized, Fe2+ becoming Fe3+, the iron begins to group together in oxide clumps and eventually exits the silicate structure. This is seen in thin section in altered rocks (weathering or hydrothermal action). The production of trivalent, oxidized iron usually results in a brownish or orange mineral.If the geology of the formation of green silicate minerals is relatively well defined, especially at near surface or surface conditions, the question remains how much of the iron is in a reduced oxidation state and how? In the case of reduction of iron in surface environments: if most of the iron goes to Fe2+, one mineral is formed; if only

  7. Sonic-boom-induced building structure responses including damage.

    NASA Technical Reports Server (NTRS)

    Clarkson, B. L.; Mayes, W. H.

    1972-01-01

    Concepts of sonic-boom pressure loading of building structures and the associated responses are reviewed, and results of pertinent theoretical and experimental research programs are summarized. The significance of sonic-boom load time histories, including waveshape effects, are illustrated with the aid of simple structural elements such as beams and plates. Also included are discussions of the significance of such other phenomena as three-dimensional loading effects, air cavity coupling, multimodal responses, and structural nonlinearities. Measured deflection, acceleration, and strain data from laboratory models and full-scale building tests are summarized, and these data are compared, where possible, with predicted values. Damage complaint and claim experience due both to controlled and uncontrolled supersonic flights over communities are summarized with particular reference to residential, commercial, and historic buildings. Sonic-boom-induced building responses are compared with those from other impulsive loadings due to natural and cultural events and from laboratory simulation tests.

  8. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2013-01-01

    Four companies — H.C. Spinks Clay Co., Inc., Imerys, Old Hickory Clay Co. and Unimin Corp. — mined ball clay in five U.S. states in 2012. Production, on the basis of preliminary data, was 900 kt (992,000 st), with an estimated value of $42.3 million. This was a slight increase in tonnage from 886 kt (977,000 st), with a value of $40.9 million in 2011. Tennessee was the leading ball clay producing state, with 63 percent of domestic production, followed by Texas, Mississippi, Kentucky and Indiana. Reported ball clay production from Indiana probably was fire clay rather than ball clay. About 69 percent of total ball clay production was airfloat, 20 percent was crude and 11 percent was water-slurried.

  9. Evaluation of the healing activity of therapeutic clay in rat skin wounds.

    PubMed

    Dário, Giordana Maciel; da Silva, Geovana Gomes; Gonçalves, Davi Ludvig; Silveira, Paulo; Junior, Adilson Teixeira; Angioletto, Elidio; Bernardin, Adriano Michael

    2014-10-01

    The use of clays for therapeutic practice is widespread in almost all regions of the world. In this study the physicochemical and microbiological healing characteristics of a clay from Ocara, Brazil, popularly used for therapeutic uses, were analyzed. The presence of Ca, Mg, Al, Fe, and Si was observed, which initially indicated that the clay had potential for therapeutic use. The average particle size of the clay (26.3 μm) can induce the microcirculation of the skin and the XRD analysis shows that the clay is formed by kaolinite and illite, a swelling clay. During the microbiological evaluation there was the need to sterilize the clay for later incorporation into the pharmaceutical formula. The accelerated stability test at 50°C for 3 months has showed that the pharmaceutical formula remained stable with a shelf life of two years. After the stability test the wound-healing capacity of the formulation in rats was evaluated. It was observed that the treatment made with the formulation containing the Ocara clay showed the best results since the formula allowed greater formation of collagen fibers and consequent regeneration of the deep dermis after seven days of treatment and reepithelialization and continuous formation of granulation tissue at the 14th day. Copyright © 2014 Elsevier B.V. All rights reserved.

  10. Killer clays! Natural antibacterial clay minerals

    USGS Publications Warehouse

    Williams, L.B.; Holland, M.; Eberl, D.D.; Brunet, T.; De Courrsou, L. B.

    2004-01-01

    The clay chemical properties that may be important in medicine were investigated. It was found that natural clay minerals can have striking and very specific effects on microbial populations. The effects can range from potentially enhanced microbial growth to complete sterilization. This paper presents evidence that natural clay minerals can be effective antimicrobial agents.

  11. Field trip guidebook on environmental impact of clays along the upper Texas coast

    NASA Technical Reports Server (NTRS)

    Garcia, Theron D.; Ming, Douglas W.; Tuck, Lisa Kay

    1991-01-01

    The field trip was prepared to provide an opportunity to see first hand some the environmental hazards associated with clays in the Houston, Texas area. Because of the very high clay content in area soils and underlying Beaumont Formation clay, Houston is a fitting location to host the Clay Mineral Society. Examinations were made of (1) expansive soils, (2) subsidence and surface faulting, and (3) a landfill located southeast of Houston at the Gulf Coast Waste Disposal Authority where clay is part of the liner material.

  12. Ball clay

    USGS Publications Warehouse

    Virta, Robert L.

    2010-01-01

    The article reports on the global market performance of ball clay in 2009 and presents an outlook for its 2010 performance. Several companies mined ball call in the country including Old Hickey Clay Co., Kentucky-Tennessee Clay Co., and H.C. Spinks Clay Co. Information on the decline in ball clay imports and exports is also presented.

  13. Flight test measurements and analysis of sonic boom phenomena near the shock wave extremity

    NASA Technical Reports Server (NTRS)

    Haglund, G. T.; Kane, E. J.

    1973-01-01

    The sonic boom flight test program conducted at Jackass Flats, Nevada, during the summer and fall of 1970 consisted of 121 sonic-boom-generating flights over the 1500 ft instrumented BREN tower. This test program was designed to provide information on several aspects of sonic boom, including caustics produced by longitudinal accelerations, caustics produced by steady flight near the threshold Mach number, sonic boom characteristics near lateral cutoff, and the vertical extent of shock waves attached to near-sonic airplanes. The measured test data, except for the near-sonic flight data, were analyzed in detail to determine sonic boom characteristics for these flight conditions and to determine the accuracy and the range of validity of linear sonic boom theory. The caustic phenomena observed during the threshold Mach number flights and during the transonic acceleration flights are documented and analyzed in detail. The theory of geometric acoustics is shown to be capable of predicting shock wave-ground intersections, and current methods for calculating sonic boom pressure signature away from caustics are shown to be reasonably accurate.

  14. A laboratory study of subjective response to sonic booms measured at White Sands Missile Range

    NASA Technical Reports Server (NTRS)

    Sullivan, Brenda M.; Leatherwood, Jack D.

    1993-01-01

    The Sonic Boom Simulator of the Langley Research Center was used to quantify subjective loudness response to boom signatures consisting of: (1) simulator reproductions of booms recently recorded at White Sands Missile Range; (2) idealized N-waves; and (3) idealized booms having intermediate shocks. The booms with intermediate shocks represented signatures derived from CFD predictions. The recorded booms represented those generated by F15 and T38 aircraft flyovers and represented a variety of waveforms reflecting the effects of propagation through a turbulent atmosphere. These waveforms included the following shape categories: N-waves, peaked, rounded, and U-shaped. Results showed that Perceived Level and Zwicker Loudness Level were good estimators of the loudness of turbulence modified sonic booms. No significant differences were observed between loudness responses for the several shape categories when expressed in terms of Perceived Level. Thus, Perceived Level effectively accounted for waveform differences due to turbulence. Idealized booms with intermediate shocks, however, were rated as being approximately 2.7 dB(PL) less loud than the recorded signatures. This difference was not accounted for by PL.

  15. Application of sonic-boom minimization concepts in supersonic transport design

    NASA Technical Reports Server (NTRS)

    Carlson, H. W.; Barger, R. L.; Mack, R. J.

    1973-01-01

    The applicability of sonic boom minimization concepts in the design of large supersonic transport airplanes capable of a 2500-nautical-mile range at a cruise Mach number of 2.7 is considered. Aerodynamics, weight and balance, and mission performance as well as sonic boom factors, have been taken into account. The results indicate that shock-strength nominal values of somewhat less than 48 newtons/sq m during cruise are within the realm of possibility. Because many of the design features are in direct contradiction to presently accepted design practices, further study of qualified airplane design teams is required to ascertain sonic boom shock strength levels actually attainable for practical supersonic transports.

  16. Sheath-Based Rollable Lenticular-Shaped and Low-Stiction Composite Boom

    NASA Technical Reports Server (NTRS)

    Fernandez, Juan M. (Inventor)

    2018-01-01

    Various embodiments provide rollable and deployable composite booms that may be used in a wide range of applications both for space and terrestrial structural solutions. Various embodiment composite booms may be bistable, i.e. having a stable strain energy minimum in the coiled configuration as well as the in the deployed configuration. In various embodiments, a boom may be fabricated by aligning two independent tape-springs front-to-front encircled by a durable seamless polymer sleeve. The durable seamless polymer sleeve may allow the two tape-springs to slide past each other during the coiling/deployment process so as to reduce, e.g., minimize, shear and its derived problems.

  17. Initial Results from the Variable Intensity Sonic Boom Database

    NASA Technical Reports Server (NTRS)

    Haering, Edward A., Jr.; Cliatt, Larry J., II; Gabrielson, Thomas; Sparrow, Victor W.; Locey, Lance L.; Bunce, Thomas J.

    2008-01-01

    43 sonic booms generated (a few were evanescent waves) a) Overpressures of 0.08 to 2.20 lbf/sq ft; b) Rise-times of about 0.7 to 50 ms. Objectives: a) Structural response of a house of modern construction; b) Sonic boom propagation code validation. Approach: a) Measure shockwave directionality; b) Determine effect of height above ground on acoustic level; c) Generate atmospheric turbulence filter functions.

  18. Polyethylene organo-clay nanocomposites: the role of the interface chemistry on the extent of clay intercalation/exfoliation.

    PubMed

    Mainil, Michaël; Alexandre, Michaël; Monteverde, Fabien; Dubois, Philippe

    2006-02-01

    High density polyethylene (HDPE)/clay nanocomposites have been prepared using three different functionalized polyethylene compatibilizers: an ethylene/vinyl acetate copolymer, a polyethylene grafted with maleic anhydride functions and a (styrene-b-ethylene/butylene-b-styrene) block copolymer. The nanocomposites were prepared via two different routes: (1) the dispersion in HDPE of a masterbatch prepared from the compatibilizer and the clay or (2) the direct melt blending of the three components. For each compatibilizer, essentially intercalated nanocomposites were formed as determined by X-ray diffraction and transmission electron microscopy. With the ethylene/vinyl acetate copolymer, a significant delamination of the intercalated clay in thin stacks was observed. This dispersion of thin intercalated stacks within the polymer matrix allowed increasing significantly the stiffness and the flame resistance of the nanocomposite. A positive effect of shear rate and blending time has also been put into evidence, especially for the process based on the masterbatch preparation, improving both the formation of thin stacks of intercalated clay and the mechanical properties and the flame resistance of the formed nanocomposites.

  19. Mars, clays and the origins of life

    NASA Technical Reports Server (NTRS)

    Hartman, Hyman

    1989-01-01

    To detect life in the Martian soil, tests were designed to look for respiration and photosynthesis. Both tests (labeled release, LR, and pyrolytic release, PR) for life in the Martian soils were positive. However, when the measurement for organic molecules in the soil of Mars was made, none were found. The interpretation given is that the inorganic constituents of the soil of Mars were responsible for these observations. The inorganic analysis of the soil was best fitted by a mixture of minerals: 60 to 80 percent clay, iron oxide, quartz, and soluble salts such as halite (NaCl). The minerals most successful in simulating the PR and LR experiments are iron-rich clays. There is a theory that considers clays as the first organisms capable of replication, mutation, and catalysis, and hence of evolving. Clays are formed when liquid water causes the weathering of rocks. The distribution of ions such as aluminum, magnesium, and iron play the role of bases in the DNA. The information was stored in the distribution of ions in the octahedral and tetrahedral molecules, but that they could, like RNA and DNA, replicate. When the clays replicated, each sheet of clay would be a template for a new sheet. The ion substitutions in one clay sheet would give rise to a complementary or similar pattern on the clay synthesized on its surface. It was theorized that it was on the surface of replicating iron-rich clays that carbon dioxide would be fixed in the light into organic acids such as formic or oxalic acid. If Mars had liquid water during a warm period in its past, clay formation would have been abundant. These clays would have replicated and evolved until the liquid water was removed due to cooling of Mars. It is entirely possible that the Viking mission detected life on Mars, but it was clay life that awaits the return of water to continue its evolution into life based on organic molecules.

  20. Understanding Potassium Isotope Fractionation During Authigenic Clay Formation in Pore-fluid Systems: Implications for the δ41K of Seawater

    NASA Astrophysics Data System (ADS)

    Santiago Ramos, D. P.; Higgins, J. A.

    2015-12-01

    Improvements in analytical precision on the latest generation multi-collector inductively coupled plasma mass spectrometers (MC-ICP-MS) have revealed a ~2‰ range in the ratios of stable potassium isotopes (41K/39K) in terrestrial materials (Morgan et al., in prep). Preliminary measurements of δ41K values indicate that seawater and silicate rocks are isotopically distinct reservoirs, with seawater having a δ41K value that is ~0.5‰ heavier than the silicate average (-0.5‰; Morgan et al., in prep). The heavy δ41K character of seawater might be related to 1) an isotopically enriched input flux (rivers and high-temperature hydrothermal reactions); or 2) a 41K-depleted sink associated with authigenic clay formation during low-temperature alteration of volcanic rocks. Here we present measurements of the δ41K values of pore-fluids from ODP site 1052 in order to constrain potassium isotope fractionation during secondary clay formation. We find that δ41K values and K concentrations both decline systematically with depth. Results from 1-D diffusion-advection-reaction modeling of potassium concentrations and isotopic compositions indicate that fractionation of K isotopes during diffusion (Bourg et al., 2010) can explain all of the change in δ41K values of the pore-fluid with depth. Although the size of the K sink at site 1052 is a trivial fraction of the global K sink in clay minerals, our results suggest that diffusive fractionation of K isotopes in shallow pore-fluids may be, in part, responsible for the elevated δ41K value of seawater.

  1. Phosphates in some Missouri refractory clays

    USGS Publications Warehouse

    Halley, Robert B.; Foord, Eugene E.; Keller, David J.; Keller, Walter D.

    1997-01-01

    This paper describes in detail phosphate minerals occurring in refractory clays of Missouri and their effect on the refractory degree of the clays. The minerals identified include carbonate-fluorapatite (francolite), crandallite, goyazite, wavellite, variscite and strengite. It is emphasized that these phosphates occur only in local isolated concentrations, and not generally in Missouri refractory clays.The Missouri fireclay region comprises 2 districts, northern and southern, separated by the Missouri River. In this region, clay constitutes a major part of the Lower Pennsylvanian Cheltenham Formation. The original Cheltenham mud was an argillic residue derived from leaching and dissolution of pre-Pennsylvanian carbonates. The mud accumulated on a karstic erosion surface truncating the pre-Cheltenham rocks. Fireclays of the northern district consist mainly of poorly ordered kaolinite, with variable but minor amounts of illite, chlorite and fine-grained detrital quartz. Clays of the southern district were subjected to extreme leaching that produced well-ordered kaolinite flint clays. Local desilication formed pockets of diaspore, or more commonly, kaolinite, with oolite-like nubs or burls of diaspore (“burley”" clay).The phosphate-bearing materials have been studied by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectral analysis (SEM-EDS) and chemical analysis. Calcian goyazite was identified in a sample of diaspore, and francolite in a sample of flint clay. A veinlet of wavellite occurs in flint clay at one locality, and a veinlet of variscite-strengite at another locality.The Missouri flint-clay-hosted francolite could not have formed in the same manner as marine francolite. The evidence suggests that the Cheltenham francolite precipitated from ion complexes in pore water, nearly simultaneously with crystallization of kaolinite flint clay from an alumina-silica gel. Calcian goyazite is an early diagenetic addition to its diaspore

  2. Initial Results from the Variable Intensity Sonic Boom Propagation Database

    NASA Technical Reports Server (NTRS)

    Haering, Edward A., Jr.; Cliatt, Larry J., II; Bunce, Thomas J.; Gabrielson, Thomas B.; Sparrow, Victor W.; Locey, Lance L.

    2008-01-01

    An extensive sonic boom propagation database with low- to normal-intensity booms (overpressures of 0.08 lbf/sq ft to 2.20 lbf/sq ft) was collected for propagation code validation, and initial results and flight research techniques are presented. Several arrays of microphones were used, including a 10 m tall tower to measure shock wave directionality and the effect of height above ground on acoustic level. A sailplane was employed to measure sonic booms above and within the atmospheric turbulent boundary layer, and the sailplane was positioned to intercept the shock waves between the supersonic airplane and the ground sensors. Sailplane and ground-level sonic boom recordings were used to generate atmospheric turbulence filter functions showing excellent agreement with ground measurements. The sonic boom prediction software PCBoom4 was employed as a preflight planning tool using preflight weather data. The measured data of shock wave directionality, arrival time, and overpressure gave excellent agreement with the PCBoom4-calculated results using the measured aircraft and atmospheric data as inputs. C-weighted acoustic levels generally decreased with increasing height above the ground. A-weighted and perceived levels usually were at a minimum for a height where the elevated microphone pressure rise time history was the straightest, which is a result of incident and ground-reflected shock waves interacting.

  3. Clay-Bacteria Systems and Biofilm Production

    NASA Astrophysics Data System (ADS)

    Steiner, J.; Alimova, A.; Katz, A.; Steiner, N.; Rudolph, E.; Gottlieb, P.

    2007-12-01

    Soil clots and the aerosol transport of bacteria and spores are promoted by the formation of biofilms (bacteria cells in an extracellular polymeric matrix). Biofilms protect microorganisms by promoting adhesion to both organic and inorganic surfaces. Time series experiments on bacteria-clay suspensions demonstrate that biofilm growth is catalyzed by the presence of hectorite in minimal growth media for the studied species: Gram negatives (Pseudomonas syringae and Escherichia coli,) and Gram positives (Staphylococcus aureus and Bacillus subtilis). Soil organisms (P. syringae, B. subtilis) and organisms found in the human population (E. coli, S. aureus) are both used to demonstrate the general applicability of clay involvement. Fluorescent images of the biofilms are acquired by staining with propidium iodide, a component of the BacLightTM Live/Dead bacterial viability staining kit (Molecular Probes, Eugene, OR). The evolving polysaccharide-rich biofilm reacts with the clay interlayer site causing a complex substitution of the two-water hectorite interlayer with polysaccharide. The result is often a three-peak composite of the (001) x-ray diffraction maxima resulting from polysaccharide-expanded clays and an organic-driven contraction of a subset of the clays in the reaction medium. X-ray diffractograms reveal that the expanded set creates a broad maximum with clay subsets at 1.84 nm and 1.41 nm interlayer spacings as approximated by a least squares double Lorentzian fit, and a smaller shoulder at larger 2q, deriving from a contraction of the interlayer spacing. Washing with chlorox removes organic material from the contracted clay and creates a 1-water hectorite single peak in place of the double peak. The clay response can be used as an indirect indicator of biofilm in an environmental system.

  4. Implications for high speed research: The relationship between sonic boom signature distortion and atmospheric turbulence

    NASA Technical Reports Server (NTRS)

    Sparrow, Victor W.; Gionfriddo, Thomas A.

    1994-01-01

    In this study there were two primary tasks. The first was to develop an algorithm for quantifying the distortion in a sonic boom. Such an algorithm should be somewhat automatic, with minimal human intervention. Once the algorithm was developed, it was used to test the hypothesis that the cause of a sonic boom distortion was due to atmospheric turbulence. This hypothesis testing was the second task. Using readily available sonic boom data, we statistically tested whether there was a correlation between the sonic boom distortion and the distance a boom traveled through atmospheric turbulence.

  5. Behavioral, autonomic, and subjective reactions to low- and moderate-level simulated sonic booms : a report of two experiments and a general evaluation of sonic boom startle effects.

    DOT National Transportation Integrated Search

    1974-09-01

    Two separate studies are reported. The first attempted to determine a sonic boom exposure level below which startle reactions would not occur. Subjects were exposed indoors to six simulated sonic booms having various outside overpressures. In the sec...

  6. Aerodynamic Effects of a 24-Foot, Multisegmented Telescoping Nose Boom on an F-15B Airplane

    NASA Technical Reports Server (NTRS)

    Cumming, Stephen B.; Smith, Mark S.; Frederick, Michael A.

    2007-01-01

    An experimental multisegmented telescoping nose boom has been installed on an F-15B airplane to be tested in a flight environment. The experimental nose boom is representative of one that could be used to tailor the sonic boom signature of an airplane such as a supersonic business jet. The nose boom consists of multiple sections and could be extended during flight to a length of 24 ft. The preliminary analyses indicated that the addition of the experimental nose boom could adversely affect vehicle flight characteristics and air data systems. Before the boom was added, a series of flights was flown to update the aerodynamic model and characterize the air data systems of the baseline airplane. The baseline results have been used in conjunction with estimates of the nose boom s influence to prepare for a series of research flights conducted with the nose boom installed. Data from these flights indicate that the presence of the experimental boom reduced the static pitch and yaw stability of the airplane. The boom also adversely affected the static-position error of the airplane but did not significantly affect angle-of-attack or angle-of-sideslip measurements. The research flight series has been successfully completed.

  7. Aerodynamic Effects of a 24-foot Multisegmented Telescoping Nose Boom on an F-15B Airplane

    NASA Technical Reports Server (NTRS)

    Cumming, Stephen B.; Smith, Mark S.; Frederick, Michael A.

    2008-01-01

    An experimental multisegmented telescoping nose boom has been installed on an F-15B airplane to be tested in a flight environment. The experimental nose boom is representative of one that could be used to tailor the sonic boom signature of an airplane such as a supersonic business jet. The nose boom consists of multiple sections and could be extended during flight to a length of 24 ft. The preliminary analyses indicate that the addition of the experimental nose boom could adversely affect vehicle flight characteristics and air data systems. Before the boom was added, a series of flights was conducted to update the aerodynamic model and characterize the air data systems of the baseline airplane. The baseline results have been used in conjunction with estimates of the nose boom's influence to prepare for a series of research flights conducted with the nose boom installed. Data from these flights indicate that the presence of the experimental boom reduced the static pitch and yaw stability of the airplane. The boom also adversely affected the static-position error of the airplane but did not significantly affect angle-of-attack or angle-of-sideslip measurements. The research flight series has been successfully completed.

  8. Inverse Design of Low-Boom Supersonic Concepts Using Reversed Equivalent-Area Targets

    NASA Technical Reports Server (NTRS)

    Li, Wu; Rallabhand, Sriam

    2011-01-01

    A promising path for developing a low-boom configuration is a multifidelity approach that (1) starts from a low-fidelity low-boom design, (2) refines the low-fidelity design with computational fluid dynamics (CFD) equivalent-area (Ae) analysis, and (3) improves the design with sonic-boom analysis by using CFD off-body pressure distributions. The focus of this paper is on the third step of this approach, in which the design is improved with sonic-boom analysis through the use of CFD calculations. A new inverse design process for off-body pressure tailoring is formulated and demonstrated with a low-boom supersonic configuration that was developed by using the mixed-fidelity design method with CFD Ae analysis. The new inverse design process uses the reverse propagation of the pressure distribution (dp/p) from a mid-field location to a near-field location, converts the near-field dp/p into an equivalent-area distribution, generates a low-boom target for the reversed equivalent area (Ae,r) of the configuration, and modifies the configuration to minimize the differences between the configuration s Ae,r and the low-boom target. The new inverse design process is used to modify a supersonic demonstrator concept for a cruise Mach number of 1.6 and a cruise weight of 30,000 lb. The modified configuration has a fully shaped ground signature that has a perceived loudness (PLdB) value of 78.5, while the original configuration has a partially shaped aft signature with a PLdB of 82.3.

  9. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2011-01-01

    The article discusses the latest developments in the global ball clay mining industry, particularly in the U.S., as of June 2011. It cites several firms that are involved in ball clay mining in the U.S., including HC Spins Clay Co. Inc., the Imerys Group and Old Hickory Clay Co. Among the products made from ball clay are ceramic tiles, sanitaryware, as well as fillers, extenders and binders.

  10. Sonic boom measurements from accelerating supersonic tracked sleds

    NASA Technical Reports Server (NTRS)

    Reed, J. W.

    1974-01-01

    Supersonic sled tests on the Sandia 1524-m (5000-ft) track generate sonic booms of sufficient intensity to allow some airblast measurements at distance scales not obtained from wind tunnel or flight tests. During acceleration, an emitted curved boom wave propagates to a caustic, or focus. Detailed measurements around these caustics may help to clarify the overpressure magnification which can occur from real aircraft operations. Six fixed pressure gages have been operated to document the general noise field, and a mobile array of twelve gages.

  11. Generation of Parametric Equivalent-Area Targets for Design of Low-Boom Supersonic Concepts

    NASA Technical Reports Server (NTRS)

    Li, Wu; Shields, Elwood

    2011-01-01

    A tool with an Excel visual interface is developed to generate equivalent-area (A(sub e)) targets that satisfy the volume constraints for a low-boom supersonic configuration. The new parametric Ae target explorer allows users to interactively study the tradeoffs between the aircraft volume constraints and the low-boom characteristics (e.g., loudness) of the ground signature. Moreover, numerical optimization can be used to generate the optimal A(sub e) target for given A(sub e) volume constraints. A case study is used to demonstrate how a generated low-boom Ae target can be matched by a supersonic configuration that includes a fuselage, wing, nacelle, pylon, aft pod, horizontal tail, and vertical tail. The low-boom configuration is verified by sonic-boom analysis with an off-body pressure distribution at three body lengths below the configuration

  12. Lithologic Control on Secondary Clay Mineral Formation in the Valles Caldera, New Mexico

    NASA Astrophysics Data System (ADS)

    Caylor, E.; Rasmussen, C.; Dhakal, P.

    2015-12-01

    Understanding the transformation of rock to soil is central to landscape evolution and ecosystem function. The objective of this study was to examine controls on secondary mineral formation in a forested catchment in the Catalina-Jemez CZO. We hypothesized landscape position controls the type of secondary minerals formed in that well-drained hillslopes favor Si-poor secondary phases such as kaolinite, whereas poorly drained portions of the landscape that collect solutes from surrounding areas favor formation of Si-rich secondary phases such as smectite. The study focused on a catchment in Valles Caldera in northern New Mexico where soils are derived from a mix of rhyolitic volcanic material, vegetation includes a mixed conifer forest, and climate is characterized by a mean annual precipitation of ~800 mm yr-1 and mean annual temperature of 4.5°C. Soils were collected at the soil-saprolite boundary from three landscape positions, classified as well drained hillslope, poorly drained convergent area, and poorly drained hill slope. Clay fractions were isolated and analyzed using a combination of quantitative and qualitative x-ray diffraction (XRD) analyses and thermal analysis. Quantitative XRD of random powder mounts indicated the presence of both primary phases such as quartz, and alkali and plagioclase feldspars, and secondary phases that include illite, Fe-oxyhydroxides including both goethite and hematite, kaolinite, and smectite. The clay fractions were dominated by smectite ranging from 36-42%, illite ranging from 21-35%, and kaolinite ranging from 1-8%. Qualitative XRD of oriented mounts confirmed the presence of smectite in all samples, with varying degrees of interlayering and interstratification. In contrast to our hypothesis, results indicated that secondary mineral assemblage was not strongly controlled by landscape position, but rather varied with underlying variation in lithology. The catchment is underlain by a combination of porphorytic rhyolite and

  13. Influence of clay minerals on curcumin properties: Stability and singlet oxygen generation

    NASA Astrophysics Data System (ADS)

    Gonçalves, Joyce L. S.; Valandro, Silvano R.; Poli, Alessandra L.; Schmitt, Carla C.

    2017-09-01

    Curcumin (CUR) has showed promising photophysical properties regarding to biological and chemical sciences. However, the main barrier for those applications are their low solubility and stability in aqueous solution. The effects of two different clay minerals, the montmorillonite (SWy-2) and the Laponite RD (Lap) nanoclay, on the stabilization of Curcumin were investigated. Their effects were compared with two well-established environments (acidic and neutral aqueous media). CUR/clay hybrids were prepared using a simple and fast method, where CUR solution was added into clay suspensions, to obtain well dispersed hybrids in water. The degradation process of CUR and CUR/clays hybrids was investigated using UV-Vis spectroscopic. For both studied hybrids, the CUR degradation process was suppressed by the presence of the clay particles. Furthermore, the Lap showed a great stabilization effect than SWy-2. This behavior was due to the smaller particle size and higher exfoliation ability of Lap, providing a large surface for CUR adsorption compared to SWy-2. The degradation process of CUR solutions and CUR/clay hybrids was also studied in the presence of light. CUR photodegradation process was faster not only in the aqueous solution but also in the clay suspension compared to those studied in the dark. The presence of clay particles accelerated the photodegradation of CUR due to the products formation in the reactions between CUR and oxygen radicals. Our results showed that the singlet oxygen quantum yield (ΦΔ) of CUR were about 59% higher in the clay suspensions than CUR in aqueous solution. Therefore, the formation of CUR/clay hybrids, in particularly with Lap, suppressed the degradation in absence light of CUR and increased the singlet oxygen generation, which makes this hybrids of CUR/clay a promising material to enlarge the application of CUR in the biological sciences.

  14. Nanostructures and radionuclide transport in clay formations (Invited)

    NASA Astrophysics Data System (ADS)

    Wang, Y.

    2010-12-01

    Nanostructures are widely present in geologic materials and are expected to directly affect the interactions of these materials with geologic fluids. The study of mineral-water interface chemistry as controlled by nanostructures is a necessary step to bridge the existing gap between the molecular level understanding of a geochemical process and the macro-scale laboratory and field observations. In this presentation, I will review the recent progresses in nanoscience and provide a perspective on how these progresses can potentially impact geochemical studies. My presentation will be focused the following areas: (1) the characterization of nanostructures in natural systems, (2) the study of water and chemical species in nanoconfinement, (3) the effects of nanopores on geochemical reaction and mass transfers, and (4) the use nanostructured materials for environmental remediation and cleanup. Specifically, I will demonstrate that the nanopore confinement can significantly modify geochemical reactions in porous geologic media. As the pore size is reduced to a few nanometers, the difference between surface acidity constants (pK2 - pK1) decreases, giving rise to a higher surface charge density on a nanopore surface than that on an unconfined mineral-water interface. The change in surface acidity constants results in a shift of ion sorption edges and enhances ion sorption on nanopore surfaces. This effect causes preferential enrichment of trace elements in nanopores and therefore directly impacts the bioavailability of these elements. The implication of these processes to radionuclide transport in clay formations will be discussed. This work was performed at Sandia National Laboratories, which is a multiprogram laboratory operated by Sandia Corporation, a Lockheed-Martin Company, for the DOE under contract DE-AC04-94AL8500.

  15. Noise and Sonic Boom Impact Technology. Sonic Boom Damage to Conventional Structures

    DTIC Science & Technology

    1989-02-01

    Pallant (21) reported on tests on leaded glass windows conducted in England. Tests were conducted to investigate the effect of repeated booms and to...changes can cause considerable deflections in the window due to the thermal expansion of the lead. However, Pallant also found that these...RD-775-118, July , 1975. 10. Abiassi, J.J., "The Strength of Weathered Window Glass Using Surface Characteristics," Institute For Disaster Research

  16. Vegetable Oil-Based Hyperbranched Thermosetting Polyurethane/Clay Nanocomposites

    PubMed Central

    2009-01-01

    The highly branched polyurethanes and vegetable oil-based polymer nanocomposites have been showing fruitful advantages across a spectrum of potential field of applications.Mesua ferreaL. seed oil-based hyperbranched polyurethane (HBPU)/clay nanocomposites were prepared at different dose levels by in situ polymerization technique. The performances of epoxy-cured thermosetting nanocomposites are reported for the first time. The partially exfoliated structure of clay layers was confirmed by XRD and TEM. FTIR spectra indicate the presence of H bonding between nanoclay and the polymer matrix. The present investigation outlines the significant improvement of tensile strength, scratch hardness, thermostability, water vapor permeability, and adhesive strength without much influencing impact resistance, bending, and elongation at break of the nanocomposites compared to pristine HBPU thermoset. An increment of two times the tensile strength, 6 °C of melting point, and 111 °C of thermo-stability were achieved by the formation of nanocomposites. An excellent shape recovery of about 96–99% was observed for the nanocomposites. Thus, the formation of partially exfoliated clay/vegetable oil-based hyperbranched polyurethane nanocomposites significantly improved the performance. PMID:20596546

  17. Vegetable Oil-Based Hyperbranched Thermosetting Polyurethane/Clay Nanocomposites.

    PubMed

    Deka, Harekrishna; Karak, Niranjan

    2009-04-25

    The highly branched polyurethanes and vegetable oil-based polymer nanocomposites have been showing fruitful advantages across a spectrum of potential field of applications. Mesua ferrea L. seed oil-based hyperbranched polyurethane (HBPU)/clay nanocomposites were prepared at different dose levels by in situ polymerization technique. The performances of epoxy-cured thermosetting nanocomposites are reported for the first time. The partially exfoliated structure of clay layers was confirmed by XRD and TEM. FTIR spectra indicate the presence of H bonding between nanoclay and the polymer matrix. The present investigation outlines the significant improvement of tensile strength, scratch hardness, thermostability, water vapor permeability, and adhesive strength without much influencing impact resistance, bending, and elongation at break of the nanocomposites compared to pristine HBPU thermoset. An increment of two times the tensile strength, 6 degrees C of melting point, and 111 degrees C of thermo-stability were achieved by the formation of nanocomposites. An excellent shape recovery of about 96-99% was observed for the nanocomposites. Thus, the formation of partially exfoliated clay/vegetable oil-based hyperbranched polyurethane nanocomposites significantly improved the performance.

  18. Heteroaggregation of titanium dioxide nanoparticles with natural clay colloids.

    PubMed

    Labille, Jérôme; Harns, Carrie; Bottero, Jean-Yves; Brant, Jonathan

    2015-06-02

    To better understand and predict the fate of engineered nanoparticles in the water column, we assessed the heteroaggregation of TiO2 nanoparticles with a smectite clay as analogues for natural colloids. Heteroaggregation was evaluated as a function of water salinity (10(-3) and 10(-1) M NaCl), pH (5 and 8), and selected nanoparticle concentration (0-4 mg/L). Time-resolved laser diffraction was used, coupled to an aggregation model, to identify the key mechanisms and variables that drive the heteroaggregation of the nanoparticles with colloids. Our data show that, at a relevant concentration, nanoparticle behavior is mainly driven by heteroaggregation with colloids, while homoaggregation remains negligible. The affinity of TiO2 nanoparticles for clay is driven by electrostatic interactions. Opposite surface charges and/or high ionic strength favored the formation of primary heteroaggregates via the attachment of nanoparticles to the clay. The initial shape and dispersion state of the clay as well as the nanoparticle/clay concentration ratio also affected the nature of the heteroaggregation mechanism. With dispersed clay platelets (10(-3) M NaCl), secondary heteroaggregation driven by bridging nanoparticles occurred at a nanoparticle/clay number ratio of greater than 0.5. In 10(-1) M NaCl, the clay was preaggregated into larger and more spherical units. This favored secondary heteroaggregation at lower nanoparticle concentration that correlated to the nanoparticle/clay surface area ratio. In this latter case, a nanoparticle to clay sticking efficiency could be determined.

  19. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2007-01-01

    The article offers information on ball clay. Among the companies that mine ball clay in the U.S. are H.C. Spinks Clay, Kentucky-Tennessee Clay and Old Hickory Clay. In 2006, an estimated 1.2 million tons of the mineral was sold or used domestically and exported. Forty-percent of the total sales is accounted for ceramic floor and wall tile followed by sanitaryware and miscellaneous ceramics. Its average value was $ 45 per ton in 2006.

  20. Advanced Deployable Shell-Based Composite Booms for Small Satellite Structural Applications Including Solar Sails

    NASA Technical Reports Server (NTRS)

    Fernandez, Juan M.

    2017-01-01

    State of the art deployable structures are mainly being designed for medium to large size satellites. The lack of reliable deployable structural systems for low cost, small volume, rideshare-class spacecraft severely constrains the potential for using small satellite platforms for affordable deep space science and exploration precursor missions that could be realized with solar sails. There is thus a need for reliable, lightweight, high packaging efficiency deployable booms that can serve as the supporting structure for a wide range of small satellite systems including solar sails for propulsion. The National Air and Space Administration (NASA) is currently investing in the development of a new class of advanced deployable shell-based composite booms to support future deep space small satellite missions using solar sails. The concepts are being designed to: meet the unique requirements of small satellites, maximize ground testability, permit the use of low-cost manufacturing processes that will benefit scalability, be scalable for use as elements of hierarchical structures (e.g. trusses), allow long duration storage, have high deployment reliability, and have controlled deployment behavior and predictable deployed dynamics. This paper will present the various rollable boom concepts that are being developed for 5-20 m class size deployable structures that include solar sails with the so-called High Strain Composites (HSC) materials. The deployable composite booms to be presented are being developed to expand the portfolio of available rollable booms for small satellites and maximize their length for a given packaged volume. Given that solar sails are a great example of volume and mass optimization, the booms were designed to comply with nominal solar sail system requirements for 6U CubeSats, which are a good compromise between those of smaller form factors (1U, 2U and 3U CubeSats) and larger ones (12 U and 27 U future CubeSats, and ESPA-class microsatellites). Solar

  1. Focused and Steady-State Characteristics of Shaped Sonic Boom Signatures: Prediction and Analysis

    NASA Technical Reports Server (NTRS)

    Maglieri, Domenic J.; Bobbitt, Percy J.; Massey, Steven J.; Plotkin, Kenneth J.; Kandil, Osama A.; Zheng, Xudong

    2011-01-01

    The objective of this study is to examine the effect of flight, at off-design conditions, on the propagated sonic boom pressure signatures of a small "low-boom" supersonic aircraft. The amplification, or focusing, of the low magnitude "shaped" signatures produced by maneuvers such as the accelerations from transonic to supersonic speeds, climbs, turns, pull-up and pushovers is the concern. To analyze these effects, new and/or improved theoretical tools have been developed, in addition to the use of existing methodology. Several shaped signatures are considered in the application of these tools to the study of selected maneuvers and off-design conditions. The results of these applications are reported in this paper as well as the details of the new analytical tools. Finally, the magnitude of the focused boom problem for "low boom" supersonic aircraft designs has been more accurately quantified and potential "mitigations" suggested. In general, "shaped boom" signatures, designed for cruise flight, such as asymmetric and symmetric flat-top and initial-shock ramp waveforms retain their basic shape during transition flight. Complex and asymmetric and symmetric initial shock ramp waveforms provide lower magnitude focus boom levels than N-waves or asymmetric and symmetric flat-top signatures.

  2. Exfoliation restacking route to Au nanoparticle-clay nanohybrids

    NASA Astrophysics Data System (ADS)

    Paek, Seung-Min; Jang, Jae-Up; Hwang, Seong-Ju; Choy, Jin-Ho

    2006-05-01

    A novel gold-pillared aluminosilicate (Au-PILC) were synthesized with positively charged gold nanoparticles capped by mercaptoammonium and exfoliated silicate layers. Gold nanoparticles were synthesized by NaBH4 reduction of AuCl4- in the presence of N,N,N-Trimethyl (11-mercaptoundecyl)ammonium (HS(CH2)11NMe3+) protecting ligand in an aqueous solution, and purified by dialysis. The resulting positively charged and water-soluble gold nanoparticles were hybridized with exfoliated silicate sheets by electrostatic interaction. The formation of Au clay hybrids could be easily confirmed by the powder X-ray diffraction with the increased basal spacing of clay upon insertion of Au nanoparticles. TEM image clearly revealed that the Au particles with an average size of 4 nm maintain their structure even after intercalation. The Au nanoparticles supported by clay matrix were found to be thermally more stable, suggesting that the Au nanoparticles were homogeneously protected with clay nanoplates. The present synthetic route could be further applicable to various hybrid systems between metal nanoparticles and clays.

  3. A Study in a New Test Facility on Indoor Annoyance Caused by Sonic Booms

    NASA Technical Reports Server (NTRS)

    Rathsam, Jonathan; Loubeau, Alexandra; Klos, Jacob

    2012-01-01

    A sonic-boom simulator at NASA Langley Research Center has been constructed to research the indoor human response to low-amplitude sonic booms. The research goal is the development of a psychoacoustic model for individual sonic booms to be validated by future community studies. The study in this report assessed the suitability of existing noise metrics for predicting indoor human annoyance. The test signals included a wide range of synthesized and recorded sonic-boom waveforms. Results indicated that no noise metric predicts indoor annoyance to sonic-boom sounds better than Perceived Level, PL. During the study it became apparent that structural vibrations induced by the test signals were contributing to annoyance, so the relationship between sound and vibration at levels of equivalent annoyance has been quantified.

  4. MMOC- MODIFIED METHOD OF CHARACTERISTICS SONIC BOOM EXTRAPOLATION

    NASA Technical Reports Server (NTRS)

    Darden, C. M.

    1994-01-01

    The Modified Method of Characteristics Sonic Boom Extrapolation program (MMOC) is a sonic boom propagation method which includes shock coalescence and incorporates the effects of asymmetry due to volume and lift. MMOC numerically integrates nonlinear equations from data at a finite distance from an airplane configuration at flight altitude to yield the sonic boom pressure signature at ground level. MMOC accounts for variations in entropy, enthalpy, and gravity for nonlinear effects near the aircraft, allowing extrapolation to begin nearer the body than in previous methods. This feature permits wind tunnel sonic boom models of up to three feet in length, enabling more detailed, realistic models than the previous six-inch sizes. It has been shown that elongated airplanes flying at high altitude and high Mach numbers can produce an acceptably low sonic boom. Shock coalescence in MMOC includes three-dimensional effects. The method is based on an axisymmetric solution with asymmetric effects determined by circumferential derivatives of the standard shock equations. Bow shocks and embedded shocks can be included in the near-field. The method of characteristics approach in MMOC allows large computational steps in the radial direction without loss of accuracy. MMOC is a propagation method rather than a predictive program. Thus input data (the flow field on a cylindrical surface at approximately one body length from the axis) must be supplied from calculations or experimental results. The MMOC package contains a uniform atmosphere pressure field program and interpolation routines for computing the required flow field data. Other user supplied input to MMOC includes Mach number, flow angles, and temperature. MMOC output tabulates locations of bow shocks and embedded shocks. When the calculations reach ground level, the overpressure and distance are printed, allowing the user to plot the pressure signature. MMOC is written in FORTRAN IV for batch execution and has been

  5. Integration of Off-Track Sonic Boom Analysis in Conceptual Design of Supersonic Aircraft

    NASA Technical Reports Server (NTRS)

    Ordaz, Irian; Li, Wu

    2011-01-01

    A highly desired capability for the conceptual design of aircraft is the ability to rapidly and accurately evaluate new concepts to avoid adverse trade decisions that may hinder the development process in the later stages of design. Evaluating the robustness of new low-boom concepts is important for the conceptual design of supersonic aircraft. Here, robustness means that the aircraft configuration has a low-boom ground signature at both under- and off-track locations. An integrated process for off-track boom analysis is developed to facilitate the design of robust low-boom supersonic aircraft. The integrated off-track analysis can also be used to study the sonic boom impact and to plan future flight trajectories where flight conditions and ground elevation might have a significant effect on ground signatures. The key enabler for off-track sonic boom analysis is accurate computational fluid dynamics (CFD) solutions for off-body pressure distributions. To ensure the numerical accuracy of the off-body pressure distributions, a mesh study is performed with Cart3D to determine the mesh requirements for off- body CFD analysis and comparisons are made between the Cart3D and USM3D results. The variations in ground signatures that result from changes in the initial location of the near-field waveform are also examined. Finally, a complete under- and off-track sonic boom analysis is presented for two distinct supersonic concepts to demonstrate the capability of the integrated analysis process.

  6. Clay Play

    ERIC Educational Resources Information Center

    Rogers, Liz; Steffan, Dana

    2009-01-01

    This article describes how to use clay as a potential material for young children to explore. As teachers, the authors find that their dialogue about the potential of clay as a learning medium raises many questions: (1) What makes clay so enticing? (2) Why are teachers noticing different play and conversation around the clay table as compared to…

  7. Unstructured Grids for Sonic Boom Analysis and Design

    NASA Technical Reports Server (NTRS)

    Campbell, Richard L.; Nayani, Sudheer N.

    2015-01-01

    An evaluation of two methods for improving the process for generating unstructured CFD grids for sonic boom analysis and design has been conducted. The process involves two steps: the generation of an inner core grid using a conventional unstructured grid generator such as VGRID, followed by the extrusion of a sheared and stretched collar grid through the outer boundary of the core grid. The first method evaluated, known as COB, automatically creates a cylindrical outer boundary definition for use in VGRID that makes the extrusion process more robust. The second method, BG, generates the collar grid by extrusion in a very efficient manner. Parametric studies have been carried out and new options evaluated for each of these codes with the goal of establishing guidelines for best practices for maintaining boom signature accuracy with as small a grid as possible. In addition, a preliminary investigation examining the use of the CDISC design method for reducing sonic boom utilizing these grids was conducted, with initial results confirming the feasibility of a new remote design approach.

  8. Summary of Sonic Boom Rise Times Observed During FAA Community Response Studies over a 6-Month Period in the Oklahoma City Area

    NASA Technical Reports Server (NTRS)

    Maglieri, Domenic J.; Sothcott, Victor E.

    1990-01-01

    The sonic boom signature data acquired from about 1225 supersonic flights, over a 6-month period in 1964 in the Oklahoma City area, was enhanced with the addition of data relating to rise times and total signature duration. These later parameters, not available at the time of publication of the original report on the Oklahoma City sonic boom exposures, are listed in tabular form along with overpressure, positive impulse, positive duration, and waveform category. Airplane operating information along with the surface weather observations are also included. Sonic boom rise times include readings to the 1/2, 3/4, and maximum overpressure values. Rise time relative probabilities for various lateral locations from the ground track of 0, 5, and 10 miles are presented along with the variation of rise times with flight altitude. The tabulated signature data, along with corresponding airplane operating conditions and surface and upper level atmospheric information, are also available on electronic files to provide it in the format for more efficient and effective utilization.

  9. A laboratory study of subjective annoyance response to sonic booms and aircraft flyovers

    NASA Technical Reports Server (NTRS)

    Leatherwood, Jack D.; Sullivan, Brenda M.

    1994-01-01

    Three experiments were conducted to determine subjective equivalence of aircraft subsonic flyover noise and sonic booms. Two of the experiments were conducted in a loudspeaker-driven sonic boom simulator, and the third in a large room containing conventional loudspeakers. The sound generation system of the boom simulator had a frequency response extending to very low frequencies (about 1 Hz) whereas the large room loudspeakers were limited to about 20 Hz. Subjective equivalence between booms and flyovers was quantified in terms of the difference between the noise level of a boom and that of a flyover when the two were judged equally annoying. Noise levels were quantified in terms of the following noise descriptors: Perceived Level (PL), Perceived Noise Level (PNL), C-weighted sound exposure level (SELC), and A-weighted sound exposure level (SELA). Results from the present study were compared, where possible, to similar results obtained in other studies. Results showed that noise level differences depended upon the descriptor used, specific boom and aircraft noise events being compared and, except for the PNL descriptor, varied between the simulator and large room. Comparison of noise level differences obtained in the present study with those of other studies indicated good agreement across studies only for the PNL and SELA descriptors. Comparison of the present results with assessments of community response to high-energy impulsive sounds made by Working Group 84 of the National Research Council's Committee on Hearing, Bioacoustics, and Biomechanics (CHABA) showed good agreement when boom/flyover noise level differences were based on SELA. However, noise level differences obtained by CHABA using SELA for aircraft flyovers and SELC for booms were not in agreement with results obtained in the present study.

  10. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2013-01-01

    Four companies mined fire clay in three states in 2012. Production, based on a preliminary survey of the fire clay industry, was estimated to be 230 kt (254,000 st) valued at $6.98 million, an increase from 215 kt (237,000 st) valued at $6.15 million in 2011. Missouri was the leading producing state, followed by Colorado and Texas, in decreasing order by quantity. The number of companies mining fire clay declined in 2012 because several common clay producers that occasionally mine fire clay indicated that they did not do so in 2012.

  11. Sonic Boom Ocean Penetration: Noise Metric Comparison and Initial Focusing Results

    NASA Technical Reports Server (NTRS)

    Sparrow, Victor W.

    1996-01-01

    The purpose of the present research is to determine the impact by sonic boom noise penetration into the ocean. Since the 1994 LaRC High Speed Research Program Sonic Boom Workshop several new results have been obtained. This talk reviews these results, and emphasizes the two most important findings. The first major result is an improved understanding of the noise spectra of the penetrating sonic boom. It was determined that weighted sound exposure levels decrease with deeper ocean depths significantly faster than unweighted sound exposure levels. This is because low frequencies penetrate the ocean deeper than high frequencies. Several noise metrics were used including peak, SEL, C-SEL, A-SEL, and PLdB, and results are given for all. These results are important because they show that the sonic boom noise impact on marine life a few meters below the ocean surface may be significantly lower using weighted sound levels than if one were to measure the impact using unweighted levels. The other major finding is the first estimate of the worst case peak levels produced by a penetrating sonic boom being focused by a sinusoidal ocean surface. The method of analysis chosen was computational, a time domain finite difference algorithm. The method is outlined and then example results are presented. For rounded sonic boom waveforms incident on a sinusoidal ocean surface, it is shown that the percentage increase or decrease in pressure is only occasionally larger than 10%, rarely 25%. These fluctuations indicate, under the assumptions already given, that any increase or decrease in sound level underwater due to focusing or defocusing should be small, less than 3 dB.

  12. Model System Study of Environmentally Persistent Free Radicals Formation in a Semiconducting Polymer Modified Copper Clay System at Ambient Temperature

    PubMed Central

    Nwosu, Ugwumsinachi G.; Khachatryan, Lavrent; Youm, Sang Gil; Roy, Amitava; dela Cruz, Albert Leo N.; Nesterov, Evgueni E.; Dellinger, Barry; Cook, Robert L.

    2016-01-01

    This paper systematically investigates how environmentally persistent free radicals (EPFRs) are formed in a phenol contaminated model soil. Poly-p-phenylene (PPP) modified and copper-loaded montmorillonite (MMT) clays were developed and used as models of soil organic matter and the clay mineral component, respectively, with phenol being employed as a precursor pollutant. The polymer modification of the clays was carried out via surface-confined Kumada catalyst-transfer chain-growth polymerization. The presence and location of the polymer were confirmed by a combination of thermogravimetric analysis (TGA), Raman spectroscopy, and X-ray diffraction data. EPFRs were formed by the Cu(II)-clay (Cu(II)CaMMT) and poly-p-phenylene-Cu(II)clay (PPP-Cu(II)CaMMT) composite systems under environmentally relevant conditions. The g-factor and concentration of EPFRs formed by the Cu(II)CaMMT and PPP-Cu(II)CaMMT systems were found to be 2.0034 and 1.22 × 1017 spins/g and 2.0033 and 1.58 × 1017spins/g, respectively. These g-factors are consistent with the formation of phenoxyl radicals. Extended X-Ray absorption fine structure (EXAFS) analysis shows that there are distinct differences in the local stuctures of the phenoxyl radicals associated with only the Cu(II) redox centers and those formed in the presences of the PPP polymer. X-ray absorption near edge spectroscopy (XANES) results provided evidence for the reduction of Cu(II) to Cu(I) in the EPFR forming process. The 1/e lifetimes of the formed EPFRs revealed a decay time of ~20 h for the Cu(II)CaMMT system and a two-step decay pattern for the PPP-Cu(II)CaMMT system with decay times of ~13.5 h and ~55.6 h. Finally, the generation of reactive oxygen species (hydroxyl radical; •OH) by these clay systems was also investigated, with higher concentrations of •OH detected for the phenol-dosed Cu(II)CaMMT and PPP-Cu(II)CaMMT systems, compared to the non-EPFR containing undosed PPP-Cu(II)CaMMT system. PMID:28670444

  13. Paired measurements of K and Mg isotopes and clay authigenesis in marine sediments

    NASA Astrophysics Data System (ADS)

    Santiago Ramos, D. P.; Dunlea, A. G.; Higgins, J. A.

    2016-12-01

    Despite its importance as a major sink for seawater K and Mg, estimates of clay authigenesis in marine sediments remain poorly constrained. Previous work on Mg isotope fractionation during clay formation has revealed a preferential uptake of 26Mg, yielding authigenic clay products with potentially distinct δ26Mg compared to the detrital component. In a similar manner, we aim to quantify the K isotope fractionation during authigenic clay formation and to use paired δ26Mg and δ41K measurements as proxies for the identification and quantification of authigenic clays in shallow and deep marine sedimentary systems. To better understand the behavior of paired Mg and K isotopes during authigenic clay formation in marine sediments, we measured δ26Mg and δ41K values of pore-fluids and sediments from ODP/IODP sites 1052, U1395, U1403 and U1366. We find that while pore-fluid K concentrations at sites 1052, U1395 and U1403 all decline with depth, δ41K profiles differ significantly. These differences might be a result of a complex interplay between clay authigenesis, sedimentation rate, and fractionation of K isotopes during diffusion. Results from 1-D diffusion-advection-reaction models suggest that, in contrast to Mg, diffusion may play an important role in determining the overall K isotope fractionation during clay authigenesis in sites with low-sedimentation rates. Sites with high sedimentation rates may act as close systems where diffusion is negligible. In such cases, K uptake can be modeled as a Rayleigh distillation process and K isotope fractionation can be estimated. Measurements of δ26Mg and δ41K of pore-fluids from site U1395 and bulk sediments from U1366 suggest that paired measurements of these isotopic systems in siliciclastic marine sediments can provide new insights into rates of marine clay authigenesis, a globally important but understudied component of many geochemical cycles.

  14. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2001-01-01

    Part of the 2000 annual review of the industrial minerals sector. A general overview of the ball clay industry is provided. In 2000, sales of ball clay reached record levels, with sanitary ware and tile applications accounting for the largest sales. Ball clay production, consumption, prices, foreign trade, and industry news are summarized. The outlook for the ball clay industry is also outlined.

  15. Objective evaluation of interior noise booming in a passenger car based on sound metrics and artificial neural networks.

    PubMed

    Lee, Hyun-Ho; Lee, Sang-Kwon

    2009-09-01

    Booming sound is one of the important sounds in a passenger car. The aim of the paper is to develop the objective evaluation method of interior booming sound. The development method is based on the sound metrics and ANN (artificial neural network). The developed method is called the booming index. Previous work maintained that booming sound quality is related to loudness and sharpness--the sound metrics used in psychoacoustics--and that the booming index is developed by using the loudness and sharpness for a signal within whole frequency between 20 Hz and 20 kHz. In the present paper, the booming sound quality was found to be effectively related to the loudness at frequencies below 200 Hz; thus the booming index is updated by using the loudness of the signal filtered by the low pass filter at frequency under 200 Hz. The relationship between the booming index and sound metric is identified by an ANN. The updated booming index has been successfully applied to the objective evaluation of the booming sound quality of mass-produced passenger cars.

  16. SCAMP: Rapid Focused Sonic Boom Waypoint Flight Planning Methods, Execution, and Results

    NASA Technical Reports Server (NTRS)

    Haering, Edward A., Jr.; Cliatt, Larry J., II; Delaney, Michael M., Jr.; Plotkin, Kenneth J.; Maglieri, Domenic J.; Brown, Jacob C.

    2012-01-01

    Successful execution of the flight phase of the Superboom Caustic Analysis and Measurement Project (SCAMP) required accurate placement of focused sonic booms on an array of prepositioned ground sensors. While the array was spread over a 10,000-ft-long area, this is a relatively small region when considering the speed of a supersonic aircraft and sonic boom ray path variability due to shifting atmospheric conditions and aircraft trajectories. Another requirement of the project was to determine the proper position for a microphone-equipped motorized glider to intercept the sonic boom caustic, adding critical timing to the constraints. Variability in several inputs to these calculations caused some shifts of the focus away from the optimal location. Reports of the sonic booms heard by persons positioned amongst the array were used to shift the focus closer to the optimal location for subsequent passes. This paper describes the methods and computations used to place the focused sonic boom on the SCAMP array and gives recommendations for their accurate placement by future quiet supersonic aircraft. For the SCAMP flights, 67% of the foci were placed on the ground array with measured positions within a few thousand feet of computed positions. Among those foci with large caustic elevation angles, 96% of foci were placed on the array, and measured positions were within a few hundred feet of computed positions. The motorized glider captured sonic booms on 59% of the passes when the instrumentation was operating properly.

  17. Adsorption of Dissolved Gases (CH4, CO2, H2, Noble Gases) by Water-Saturated Smectite Clay Minerals

    NASA Astrophysics Data System (ADS)

    Bourg, I. C.; Gadikota, G.; Dazas, B.

    2016-12-01

    Adsorption of dissolved gases by water-saturated clay minerals plays important roles in a range of fields. For example, gas adsorption in on clay minerals may significantly impact the formation of CH4 hydrates in fine-grained sediments, the behavior of CH4 in shale, CO2 leakage across caprocks of geologic CO2 sequestration sites, H2 leakage across engineered clay barriers of high-level radioactive waste repositories, and noble gas geochemistry reconstructions of hydrocarbon migration in the subsurface. Despite its importance, the adsorption of gases on clay minerals remains poorly understood. For example, some studies have suggested that clay surfaces promote the formation of CH4 hydrates, whereas others indicate that clay surfaces inhibit the formation of CH4 hydrates. Here, we present molecular dynamics (MD) simulations of the adsorption of a range of gases (CH4, CO2, H2, noble gases) on clay mineral surfaces. Our results indicate that the affinity of dissolved gases for clay mineral surfaces has a non-monotone dependence on the hydrated radius of the gas molecules. This non-monotone dependence arises from a combination of two effects: the polar nature of certain gas molecules (in particular, CO2) and the templating of interfacial water structure by the clay basal surface, which results in the presence of interfacial water "cages" of optimal size for intermediate-size gas molecules (such as Ne or Ar).

  18. MODEL CORRELATION STUDY OF A RETRACTABLE BOOM FOR A SOLAR SAIL SPACECRAFT

    NASA Technical Reports Server (NTRS)

    Adetona, O.; Keel, L. H.; Oakley, J. D.; Kappus, K.; Whorton, M. S.; Kim, Y. K.; Rakpczy, J. M.

    2005-01-01

    To realize design concepts, predict dynamic behavior and develop appropriate control strategies for high performance operation of a solar-sail spacecraft, we developed a simple analytical model that represents dynamic behavior of spacecraft with various sizes. Since motion of the vehicle is dominated by retractable booms that support the structure, our study concentrates on developing and validating a dynamic model of a long retractable boom. Extensive tests with various configurations were conducted for the 30 Meter, light-weight, retractable, lattice boom at NASA MSFC that is structurally and dynamically similar to those of a solar-sail spacecraft currently under construction. Experimental data were then compared with the corresponding response of the analytical model. Though mixed results were obtained, the analytical model emulates several key characteristics of the boom. The paper concludes with a detailed discussion of issues observed during the study.

  19. RMS upper boom framed by aft flight deck viewing window W10

    NASA Technical Reports Server (NTRS)

    1983-01-01

    Remote Manipulator System (RMS) upper arm boom (tear in multilayer beta cloth) deployed during dynamic interaction test using Payload Flight Test Article (PFTA) is visible outside aft viewing window W10. RMS 'Canada' insignia or logo appears on boom.

  20. Clay mineralogy of weathering profiles from the Carolina Piedmont.

    USGS Publications Warehouse

    Loferski, P.J.

    1981-01-01

    Saprolite profiles (12) that formed over various crystalline rocks from the Charlotte 1o X 2o quadrangle showed overall similarity in their clay mineralogy to depths of 6 to 45 m indicating control by weathering processes rather than by rock type. Most saprolite contained 10-25% clay, and ranged 3 to 70%. Kaolinite and halloysite composed = or >75% of the clay fraction of most samples. The ratio kaolinite:halloysite ranged widely, from 95% kaolinite to 90% halloysite, independent of depth. Clay-size mica was present in all profiles, and ranged 5-75% over a sericite schist. Mixed-layer mica-smectite and mica-vermiculite were subordinate; discrete smectite and vermiculite were rare. The abundance of halloysite indicates a continuously humid environment since the time of profile formation, because of the rapidity with which halloysite dehydrates irreversibly. -R.S.M.

  1. Laboratory Headphone Studies of Human Response to Low-Amplitude Sonic Booms and Rattle Heard Indoors

    NASA Technical Reports Server (NTRS)

    Loubeau, Alexandra; Sullivan, Brenda M.; Klos, Jacob; Rathsam, Jonathan; Gavin, Joseph R.

    2013-01-01

    Human response to sonic booms heard indoors is affected by the generation of contact-induced rattle noise. The annoyance caused by sonic boom-induced rattle noise was studied in a series of psychoacoustics tests. Stimuli were divided into three categories and presented in three different studies: isolated rattles at the same calculated Perceived Level (PL), sonic booms combined with rattles with the mixed sound at a single PL, and sonic booms combined with rattles with the mixed sound at three different PL. Subjects listened to sounds over headphones and were asked to report their annoyance. Annoyance to different rattles was shown to vary significantly according to rattle object size. In addition, the combination of low-amplitude sonic booms and rattles can be more annoying than the sonic boom alone. Correlations and regression analyses for the combined sonic boom and rattle sounds identified the Moore and Glasberg Stationary Loudness (MGSL) metric as a primary predictor of annoyance for the tested sounds. Multiple linear regression models were developed to describe annoyance to the tested sounds, and simplifications for applicability to a wider range of sounds are presented.

  2. Clays, common

    USGS Publications Warehouse

    Virta, R.L.

    1998-01-01

    Part of a special section on the state of industrial minerals in 1997. The state of the common clay industry worldwide for 1997 is discussed. Sales of common clay in the U.S. increased from 26.2 Mt in 1996 to an estimated 26.5 Mt in 1997. The amount of common clay and shale used to produce structural clay products in 1997 was estimated at 13.8 Mt.

  3. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2011-01-01

    The article discusses the latest developments in the fire clay industry, particularly in the U.S., as of June 2011. It claims that the leading fire clay producer in the U.S. is the state of Missouri. The other major producers include California, Texas and Washington. It reports that the use of heavy clay products made of fire clay like brick, cement and lightweight aggregate has increased slightly in 2010.

  4. NASA Test Flights Examine Effect of Atmospheric Turbulence on Sonic Booms

    NASA Image and Video Library

    2016-07-20

    One of three microphone arrays positioned strategically along the ground at Edwards Air Force Base, California, sits ready to collect sound signatures from sonic booms created by a NASA F/A-18 during the SonicBAT flight series. The arrays collected the sound signatures of booms that had traveled through atmospheric turbulence before reaching the ground.

  5. Raptor responses to low-level jet aircraft and sonic booms

    USGS Publications Warehouse

    Ellis, David H.; Ellis, Catherine H.; Mindell, David P.

    1991-01-01

    We estimated effects of low-level military jet aircraft and mid- to high-altitude sonic booms (actual and simulated) on nesting peregrine falcons (Falco peregrinus) and seven other raptors by observing their responses to test stimuli, determining nesting success for the test year, and evaluating site reoccupancy rates for the year following the tests. Frequent and nearby jet aircraft passes: (1) sometimes noticeably alarmed birds, (2) occasionally caused birds to fly from perches or eyries, (3) most often evoked only minimal responses, and (4) were never associated with reproductive failure. Similarly, responses to real and simulated mid- to high-altitude sonic booms were often minimal and never appeared productivity limiting. Eighteen (95%) of 19 nest sites subjected to low-level jet flights and/or simulated sonic booms in 1980 fledged young during that year. Eighteen (95%) of 19 sites disturbed in 1980 were reoccupied by pairs or lone birds of the same species in 1981.We subjected four pairs of prairie falcons (Falco mexicanus) to low-level aircraft at ad libitum levels during the courtship and incubation phases when adults were most likely to abandon: all four eyries fledged young. From heart rate (HR) data taken via a telemetering egg at another prairie falcon eyrie, we determined that stimulus-induced HR alterations were comparable to rate changes for birds settling to incubate following flight.While encouraging, our findings cannot be taken as conclusive evidence that jet flights and/or sonic booms will have no long-term negative effects for other raptor species or for other areas. In addition, we did not experiment with totally naive wild adults, rotary-winged aircraft, or low-level sonic booms.

  6. A total variation diminishing finite difference algorithm for sonic boom propagation models

    NASA Technical Reports Server (NTRS)

    Sparrow, Victor W.

    1993-01-01

    It is difficult to accurately model the rise phases of sonic boom waveforms with traditional finite difference algorithms because of finite difference phase dispersion. This paper introduces the concept of a total variation diminishing (TVD) finite difference method as a tool for accurately modeling the rise phases of sonic booms. A standard second order finite difference algorithm and its TVD modified counterpart are both applied to the one-way propagation of a square pulse. The TVD method clearly outperforms the non-TVD method, showing great potential as a new computational tool in the analysis of sonic boom propagation.

  7. Laboratory study of sonic booms and their scaling laws. [ballistic range simulation

    NASA Technical Reports Server (NTRS)

    Toong, T. Y.

    1974-01-01

    This program undertook to seek a basic understanding of non-linear effects associated with caustics, through laboratory simulation experiments of sonic booms in a ballistic range and a coordinated theoretical study of scaling laws. Two cases of superbooms or enhanced sonic booms at caustics have been studied. The first case, referred to as acceleration superbooms, is related to the enhanced sonic booms generated during the acceleration maneuvers of supersonic aircrafts. The second case, referred to as refraction superbooms, involves the superbooms that are generated as a result of atmospheric refraction. Important theoretical and experimental results are briefly reported.

  8. Airborne Shaped Sonic Boom Demonstration Pressure Measurements with Computational Fluid Dynamics Comparisons

    NASA Technical Reports Server (NTRS)

    Haering, Edward A., Jr.; Murray, James E.; Purifoy, Dana D.; Graham, David H.; Meredith, Keith B.; Ashburn, Christopher E.; Stucky, Mark

    2005-01-01

    The Shaped Sonic Boom Demonstration project showed for the first time that by careful design of aircraft contour the resultant sonic boom can maintain a tailored shape, propagating through a real atmosphere down to ground level. In order to assess the propagation characteristics of the shaped sonic boom and to validate computational fluid dynamics codes, airborne measurements were taken of the pressure signatures in the near field by probing with an instrumented F-15B aircraft, and in the far field by overflying an instrumented L-23 sailplane. This paper describes each aircraft and their instrumentation systems, the airdata calibration, analysis of the near- and far-field airborne data, and shows the good to excellent agreement between computational fluid dynamics solutions and flight data. The flights of the Shaped Sonic Boom Demonstration aircraft occurred in two phases. Instrumentation problems were encountered during the first phase, and corrections and improvements were made to the instrumentation system for the second phase, which are documented in the paper. Piloting technique and observations are also given. These airborne measurements of the Shaped Sonic Boom Demonstration aircraft are a unique and important database that will be used to validate design tools for a new generation of quiet supersonic aircraft.

  9. A Supersonic Business-Jet Concept Designed for Low Sonic Boom

    NASA Technical Reports Server (NTRS)

    Mack, Robert J.

    2003-01-01

    Ongoing human-response studies of sonic-boom noise indicated that a previous level of 1.0 psf might still be too annoying. This led to studies of a Supersonic Business Jet (SBJ), which might generate lower, more acceptable ground overpressures. To determine whether methods for designing a High Speed Civil Transport (HSCT) could be successfully applied, a SBJ concept was designed at the langley Research Center. It would cruise at Mach 2, carry 10 passengers for 4000 nautical miles, and generate a 0.50 psf or less on the ground under the flight path at start of cruise. Results indicated that a 10-passenger, low-boom SBJ design was just as technically demanding as a 300-passenger, low-boom HSCT design. In this report, the sources of these technical problems are identified, and ideas for addressing them are discussed.

  10. Review and status of sonic boom penetration into the ocean.

    PubMed

    Sparrow, Victor W

    2002-01-01

    Since the 1970 Sonic Boom Symposium, held at the ASA's 80th meeting in Houston, TX, substantial progress has been made in understanding the penetration of sonic booms into the ocean. The state of the art at that time was documented by J. C. Cook, T. Goforth, and R. K. Cook [J. Acoust. Soc. Am. 51, 729-741 (1972)]. Since then, additional experiments have been performed which corroborate Cook's and Sawyers' theory for sonic boom penetration into a flat ocean surface. In addition, computational simulations have validated that theory and extended the work to include arbitrarily shaped waveforms penetrating flat ocean surfaces. Further numerical studies have investigated realistic ocean surfaces including large-scale ocean swell. Research has also been performed on the effects of ocean inhomogeneities due to bubble plumes. This paper provides a brief overview of these developments.

  11. Vibration Control of Deployable Astromast Boom: Preliminary Experiments

    NASA Technical Reports Server (NTRS)

    Swaminadham, M.; Hamilton, David A.

    1994-01-01

    This paper deals with the dynamic characterization of a flexible aerospace solar boom. The modeling issues and sine dwell vibration testing to determine natural frequencies and mode shapes of a continuous-longer on deployable ASTROMAST lattice boom are discussed. The details of the proof-of-concept piezoelectric active vibration experiments on a simple cantilever beam to control its vibrations are presented. The control parameters like voltage to the controller crystal and its location are investigated, to determine the effectiveness of control element to suppress selected resonant vibrations of the test specimen. Details of this experiment and plans for its future adaptation to the prototype structure are also discussed.

  12. Metering Wheel-Wire Track Wire Boom Deployment Mechanism

    NASA Technical Reports Server (NTRS)

    Granoff, Mark S.

    2014-01-01

    The NASA MMS Spin Plane Double Probe (SDP) Deployer utilizes a helical path, rotating Metering Wheel and a spring loaded Wire "Holding" Track to pay out a "fixed end" 57 meter x 1.5 mm diameter Wire Boom stored between concentric storage cylinders. Unlike rotating spool type storage devices, the storage cylinders remain stationary, and the boom wire is uncoiled along the length of the cylinder via the rotation of the Metering Wheel. This uncoiling action avoids the need for slip-ring contacts since the ends of the wire can remain stationary. Conventional fixed electrical connectors (Micro-D type) are used to terminate to operational electronics.

  13. Spray Distribution of Boomless Nozzles: The Boomjet 5880, Radiarc and Boom Buster

    Treesearch

    James H. Miller

    1990-01-01

    Abstract. The patterns of spray distribution are described for three boomless nozzlesthat arc commonly used, or have promise, for forestry applications: The BoomJet5880 cluster nozzle (Spraying Systems Co.), the Radiarc (Waldrum specialties ), and the Boom Buster (Evergreen Products). Spray distribution patterns were determined using regularly...

  14. A summary of the lateral cutoff analysis and results from NASA's Farfield Investigation of No-boom Thresholds

    NASA Astrophysics Data System (ADS)

    Cliatt, Larry J.; Hill, Michael A.; Haering, Edward A.; Arnac, Sarah R.

    2015-10-01

    In support of the ongoing effort by the National Aeronautics and Space Administration (NASA) to bring supersonic commercial travel to the public, NASA, in partnership with other industry organizations, conducted a flight research experiment to analyze acoustic propagation at the lateral edge of the sonic boom carpet. The name of the effort was the Farfield Investigation of No-boom Thresholds (FaINT). The research from FaINT determined an appropriate metric for sonic boom waveforms in the transition and shadow zones called Perceived Sound Exposure Level, established a value of 65 dB as a limit for the acoustic lateral extent of a sonic boom's noise region, analyzed change in sonic boom levels near lateral cutoff, and compared between real sonic boom measurements and numerical predictions.

  15. A Summary of the Lateral Cutoff Analysis and Results from Nasa's Farfield Investigation of No-Boom Thresholds

    NASA Technical Reports Server (NTRS)

    Cliatt, Larry J., II; Hill, Michael A.; Haering, Edward A., Jr.; Arnac, Sarah R.

    2015-01-01

    In support of the ongoing effort by the National Aeronautics and Space Administration (NASA) to bring supersonic commercial travel to the public, NASA, in partnership with other industry organizations, conducted a flight research experiment to analyze acoustic propagation at the lateral edge of the sonic boom carpet. The name of the effort was the Farfield Investigation of No-boom Thresholds (FaINT). The research from FaINT determined an appropriate metric for sonic boom waveforms in the transition and shadow zones called Perceived Sound Exposure Level, established a value of 65 dB as a limit for the acoustic lateral extent of a sonic boom's noise region, analyzed change in sonic boom levels near lateral cutoff, and compared between real sonic boom measurements and numerical predictions.

  16. Flight Demonstration Of Low Overpressure N-Wave Sonic Booms And Evanescent Waves

    NASA Astrophysics Data System (ADS)

    Haering, Edward A.; Smolka, James W.; Murray, James E.; Plotkin, Kenneth J.

    2006-05-01

    The recent flight demonstration of shaped sonic booms shows the potential for quiet overland supersonic flight, which could revolutionize air transport. To successfully design quiet supersonic aircraft, the upper limit of an acceptable noise level must be determined through quantitative recording and subjective human response measurements. Past efforts have concentrated on the use of sonic boom simulators to assess human response, but simulators often cannot reproduce a realistic sonic boom sound. Until now, molecular relaxation effects on low overpressure rise time had never been compared with flight data. Supersonic flight slower than the cutoff Mach number, which generates evanescent waves, also prevents loud sonic booms from impacting the ground. The loudness of these evanescent waves can be computed, but flight measurement validation is needed. A novel flight demonstration technique that generates low overpressure N-waves using conventional military aircraft is outlined, in addition to initial quantitative flight data. As part of this demonstration, evanescent waves also will be recorded.

  17. Experimental Measurements of Sonic Boom Signatures Using a Continuous Data Acquisition Technique

    NASA Technical Reports Server (NTRS)

    Wilcox, Floyd J.; Elmiligui, Alaa A.

    2013-01-01

    A wind tunnel investigation was conducted in the Langley Unitary Plan Wind Tunnel to determine the effectiveness of a technique to measure aircraft sonic boom signatures using a single conical survey probe while continuously moving the model past the probe. Sonic boom signatures were obtained using both move-pause and continuous data acquisition methods for comparison. The test was conducted using a generic business jet model at a constant angle of attack and a single model-to-survey-probe separation distance. The sonic boom signatures were obtained at a Mach number of 2.0 and a unit Reynolds number of 2 million per foot. The test results showed that it is possible to obtain sonic boom signatures while continuously moving the model and that the time required to acquire the signature is at least 10 times faster than the move-pause method. Data plots are presented with a discussion of the results. No tabulated data or flow visualization photographs are included.

  18. Flight Demonstration Of Low Overpressure N-Wave Sonic Booms And Evanescent Waves

    NASA Technical Reports Server (NTRS)

    Haering, Edward A., Jr.; Smolka, James W.; Murray, James E.; Plotkin, Kenneth J.

    2005-01-01

    The recent flight demonstration of shaped sonic booms shows the potential for quiet overland supersonic flight, which could revolutionize air transport. To successfully design quiet supersonic aircraft, the upper limit of an acceptable noise level must be determined through quantitative recording and subjective human response measurements. Past efforts have concentrated on the use of sonic boom simulators to assess human response, but simulators often cannot reproduce a realistic sonic boom sound. Until now, molecular relaxation effects on low overpressure rise time had never been compared with flight data. Supersonic flight slower than the cutoff Mach number, which generates evanescent waves, also prevents loud sonic booms from impacting the ground. The loudness of these evanescent waves can be computed, but flight measurement validation is needed. A novel flight demonstration technique that generates low overpressure N-waves using conventional military aircraft is outlined, in addition to initial quantitative flight data. As part of this demonstration, evanescent waves also will be recorded.

  19. Summary of the 2008 NASA Fundamental Aeronautics Program Sonic Boom Prediction Workshop

    NASA Technical Reports Server (NTRS)

    Park, Michael A.; Aftosmis, Michael J.; Campbell, Richard L.; Carter, Melissa B.; Cliff, Susan; Nangert, Linda S.

    2013-01-01

    The Supersonics Project of the NASA Fundamental Aeronautics Program organized an internal sonic boom workshop to evaluate near- and mid-field sonic boom prediction capability at the Fundamental Aeronautics Annual Meeting in Atlanta, Georgia on October 8, 2008. Workshop participants computed sonic boom signatures for three non-lifting bodies and two lifting configurations. A cone-cylinder, parabolic, and quartic bodies of revolution comprised the non-lifting cases. The lifting configurations were a simple 69-degree delta wing body and a complete low-boom transport configuration designed during the High Speed Research Project in the 1990s with wing, body, tail, nacelle, and boundary layer diverter components. The AIRPLANE, Cart3D, FUN3D, and USM3D ow solvers were employed with the ANET signature propagation tool, output-based adaptation, and a priori adaptation based on freestream Mach number and angle of attack. Results were presented orally at the workshop. This article documents the workshop, results, and provides context on previously available and recently developed methods.

  20. Boom Minimization Framework for Supersonic Aircraft Using CFD Analysis

    NASA Technical Reports Server (NTRS)

    Ordaz, Irian; Rallabhandi, Sriram K.

    2010-01-01

    A new framework is presented for shape optimization using analytical shape functions and high-fidelity computational fluid dynamics (CFD) via Cart3D. The focus of the paper is the system-level integration of several key enabling analysis tools and automation methods to perform shape optimization and reduce sonic boom footprint. A boom mitigation case study subject to performance, stability and geometrical requirements is presented to demonstrate a subset of the capabilities of the framework. Lastly, a design space exploration is carried out to assess the key parameters and constraints driving the design.

  1. LAVA Simulations for the AIAA Sonic Boom Prediction Workshop

    NASA Technical Reports Server (NTRS)

    Housman, Jeffrey A.; Sozer, Emre; Moini-Yekta , Shayan; Kiris, Cetin C.

    2014-01-01

    Computational simulations using the Launch Ascent and Vehicle Aerodynamics (LAVA) framework are presented for the First AIAA Sonic Boom Prediction Workshop test cases. The framework is utilized with both structured overset and unstructured meshing approaches. The three workshop test cases include an axisymmetric body, a Delta Wing-Body model, and a complete low-boom supersonic transport concept. Solution sensitivity to mesh type and sizing, and several numerical convective flux discretization choices are presented and discussed. Favorable comparison between the computational simulations and experimental data of nearand mid-field pressure signatures were obtained.

  2. Clay alteration and gold deposition in the genesis and blue star deposits, Eureka County, Nevada

    USGS Publications Warehouse

    Drews-Armitage, S. P.; Romberger, S.B.; Whitney, C.G.

    1996-01-01

    The Genesis and Blue Star sedimentary rock-hosted gold deposits occur within the 40-mile-long Carlin trend and are located in Eureka County, Nevada. The deposits are hosted within the Devonian calcareous Popovich Formation, the siliciclastic Rodeo Creek unit and the siliciclastic Vinini Formation. The host rocks have undergone contact metamorphism, decalcification, silicification, argillization, and supergene oxidation. Detailed characterization of the alteration patterns, mineralogy, modes of occurrence, and associated geochemistry of clay minerals resulted in the following classifications: least altered rocks, found distal to the orebody, consisting of both metamorphosed and unmetamorphosed host rock that has not been completely decalcified; and altered rocks, found proximal to the orebody that have been decalcified. Altered rocks are classified further into the following groups based on clay mineral content: silicic, 1 to 10 percent clay; silicicargillic, 10 to 35 percent clay; and argillic, 35 to 80 percent clay. Clay species identified are 1M illite, 2M1 illite, kaolinite, halloysite, and dioctahedral smectite. An early hydrothermal event resulted in the precipitation of euhedral kaolinite and at least one generation of silica. This event occurred contemporaneously with decalcification which increased rock permeability and porosity. A second clay alteration event resulted in the precipitation of hydrothermal 1M illite which replaced hydrothermal kaolinite and is associated with gold deposition. Silver and silica deposition is also associated with this phase of hydrothermal alteration. Hydrothermal alteration was followed by supergene alteration which resulted in the formation of supergene kaolinite, halloysite, and smectite as well as the oxidation of iron-bearing minerals. Supergene clays are concentrated along faults, dike margins, and within rocks containing carbonate. Gold mineralization is not associated with supergene clay minerals within the Genesis and

  3. Interactive Inverse Design Optimization of Fuselage Shape for Low-Boom Supersonic Concepts

    NASA Technical Reports Server (NTRS)

    Li, Wu; Shields, Elwood; Le, Daniel

    2008-01-01

    This paper introduces a tool called BOSS (Boom Optimization using Smoothest Shape modifications). BOSS utilizes interactive inverse design optimization to develop a fuselage shape that yields a low-boom aircraft configuration. A fundamental reason for developing BOSS is the need to generate feasible low-boom conceptual designs that are appropriate for further refinement using computational fluid dynamics (CFD) based preliminary design methods. BOSS was not developed to provide a numerical solution to the inverse design problem. Instead, BOSS was intended to help designers find the right configuration among an infinite number of possible configurations that are equally good using any numerical figure of merit. BOSS uses the smoothest shape modification strategy for modifying the fuselage radius distribution at 100 or more longitudinal locations to find a smooth fuselage shape that reduces the discrepancies between the design and target equivalent area distributions over any specified range of effective distance. For any given supersonic concept (with wing, fuselage, nacelles, tails, and/or canards), a designer can examine the differences between the design and target equivalent areas, decide which part of the design equivalent area curve needs to be modified, choose a desirable rate for the reduction of the discrepancies over the specified range, and select a parameter for smoothness control of the fuselage shape. BOSS will then generate a fuselage shape based on the designer's inputs in a matter of seconds. Using BOSS, within a few hours, a designer can either generate a realistic fuselage shape that yields a supersonic configuration with a low-boom ground signature or quickly eliminate any configuration that cannot achieve low-boom characteristics with fuselage shaping alone. A conceptual design case study is documented to demonstrate how BOSS can be used to develop a low-boom supersonic concept from a low-drag supersonic concept. The paper also contains a study

  4. NASA Test Flights Examine Effect of Atmospheric Turbulence on Sonic Booms

    NASA Image and Video Library

    2016-07-20

    NASA pilot Nils Larson, and flight test engineer and pilot Wayne Ringelberg, head for a mission debrief after flying a NASA F/A-18 at Mach 1.38 to create sonic booms as part of the SonicBAT flight series at NASA’s Armstrong Flight Research Center in California, to study sonic boom signatures with and without the element of atmospheric turbulence.

  5. Design methodology for a community response questionnaire on sonic boom exposure

    NASA Technical Reports Server (NTRS)

    Farbry, John E., Jr.; Fields, James M.; Molino, John A.; Demiranda, Gwendolyn A.

    1991-01-01

    A preliminary draft questionnaire concerning community response to sonic booms was developed. Interviews were conducted in two communities that had experienced supersonic overflights of the SR-71 airplane for several years. Even though the overflights had ceased about 6 months prior to the interviews, people clearly remembered hearing sonic booms. A total of 22 people living in central Utah and 23 people living along Idaho/Washington state border took part in these interviews. The draft questionnaire was constantly modified during the study in order to evaluate different versions. Questions were developed which related to annoyance, startle, sleep disturbance, building vibration, and building damage. Based on the data collected, a proposed community response survey response instrument was developed for application in a full-scale sonic boom study.

  6. Design methodology for a community response questionnaire on sonic boom exposure

    NASA Astrophysics Data System (ADS)

    Farbry, John E., Jr.; Fields, James M.; Molino, John A.; Demiranda, Gwendolyn A.

    1991-05-01

    A preliminary draft questionnaire concerning community response to sonic booms was developed. Interviews were conducted in two communities that had experienced supersonic overflights of the SR-71 airplane for several years. Even though the overflights had ceased about 6 months prior to the interviews, people clearly remembered hearing sonic booms. A total of 22 people living in central Utah and 23 people living along Idaho/Washington state border took part in these interviews. The draft questionnaire was constantly modified during the study in order to evaluate different versions. Questions were developed which related to annoyance, startle, sleep disturbance, building vibration, and building damage. Based on the data collected, a proposed community response survey response instrument was developed for application in a full-scale sonic boom study.

  7. Application of Adjoint Methodology in Various Aspects of Sonic Boom Design

    NASA Technical Reports Server (NTRS)

    Rallabhandi, Sriram K.

    2014-01-01

    One of the advances in computational design has been the development of adjoint methods allowing efficient calculation of sensitivities in gradient-based shape optimization. This paper discusses two new applications of adjoint methodology that have been developed to aid in sonic boom mitigation exercises. In the first, equivalent area targets are generated using adjoint sensitivities of selected boom metrics. These targets may then be used to drive the vehicle shape during optimization. The second application is the computation of adjoint sensitivities of boom metrics on the ground with respect to parameters such as flight conditions, propagation sampling rate, and selected inputs to the propagation algorithms. These sensitivities enable the designer to make more informed selections of flight conditions at which the chosen cost functionals are less sensitive.

  8. Numerical Predictions of Sonic Boom Signatures for a Straight Line Segmented Leading Edge Model

    NASA Technical Reports Server (NTRS)

    Elmiligui, Alaa A.; Wilcox, Floyd J.; Cliff, Susan; Thomas, Scott

    2012-01-01

    A sonic boom wind tunnel test was conducted on a straight-line segmented leading edge (SLSLE) model in the NASA Langley 4- by 4- Foot Unitary Plan Wind Tunnel (UPWT). The purpose of the test was to determine whether accurate sonic boom measurements could be obtained while continuously moving the SLSLE model past a conical pressure probe. Sonic boom signatures were also obtained using the conventional move-pause data acquisition method for comparison. The continuous data acquisition approach allows for accurate signatures approximately 15 times faster than a move-pause technique. These successful results provide an incentive for future testing with greatly increased efficiency using the continuous model translation technique with the single probe to measure sonic boom signatures. Two widely used NASA codes, USM3D (Navier-Stokes) and CART3D-AERO (Euler, adjoint-based adaptive mesh), were used to compute off-body sonic boom pressure signatures of the SLSLE model at several different altitudes below the model at Mach 2.0. The computed pressure signatures compared well with wind tunnel data. The effect of the different altitude for signature extraction was evaluated by extrapolating the near field signatures to the ground and comparing pressure signatures and sonic boom loudness levels.

  9. A Flight Research Overview of WSPR, a Pilot Project for Sonic Boom Community Response

    NASA Technical Reports Server (NTRS)

    Cliatt, Larry James; Haering, Ed; Jones, Thomas P.; Waggoner, Erin R.; Flattery, Ashley K.; Wiley, Scott L.

    2014-01-01

    In support of NASAs ongoing effort to bring supersonic commercial travel to the public, NASA Dryden Flight Research Center and NASA Langley Research Center, in cooperation with other industry organizations, conducted a flight research experiment to identify the methods, tools, and best practices for a large-scale quiet (or low) sonic boom community human response test. The name of the effort was Waveforms and Sonic boom Perception and Response. Such tests will go towards building a dataset that governing agencies like the Federal Aviation Administration and International Civil Aviation Organization will use to establish regulations for acceptable sound levels of overland sonic booms. Until WSPR, there had never been an effort that studied the response of people in their own homes and performing daily activities to non-traditional, low sonic booms.WSPR was a NASA collaborative effort with several industry partners, in response to a NASA Aeronautics Research Mission Directorate Research Opportunities in Aeronautics. The primary contractor was Wyle. Other partners included Gulfstream Aerospace Corporation, Pennsylvania State University, Tetra Tech, and Fidell Associates, Inc.A major objective of the effort included exposing a community with the sonic boom magnitudes and occurrences expected in high-air traffic regions with a network of supersonic commercial aircraft in place. Low-level sonic booms designed to simulate those produced by the next generation of commercial supersonic aircraft were generated over a small residential community. The sonic boom footprint was recorded with an autonomous wireless microphone array that spanned the entire community. Human response data was collected using multiple survey methods. The research focused on essential elements of community response testing including subject recruitment, survey methods, instrumentation systems, flight planning and operations, and data analysis methods.This paper focuses on NASAs role in the efforts

  10. Migrant labor supply in a booming non-renewable resource economy: Cure and transmission mechanism for de-industrialization?

    NASA Astrophysics Data System (ADS)

    Nulle, Grant Mark

    This paper challenges the determinism that booming resource economies suffer from de-industrialization, the "Dutch Disease". For several decades, economists have attempted to explain how a sudden surge in mineral and energy extraction affects an economy's output and employment from an aggregate and sectoral perspective. Economic theory shows that a "boom" in mineral and energy production is welfare enhancing to the economy experiencing it. However, the phenomenon also induces inter-sectoral adjustments among non-renewable resource (NRR), traditional traded, and non-traded industries that tend to crowd out traditional export sectors such as agriculture and manufacturing. In turn, this paper asks two fundamental questions: 1) Can the inter-sectoral adjustments wrought by a boom in NRR production be mitigated in the resource-abundant economy experiencing it; 2) Can the inter-sectoral adjustments be exported to a neighboring non-resource economy by movements in migrant labor supply? The theoretical model and empirical estimation approach presented in this paper introduces an endogenous migrant labor supply response to booms in NRR output to test the extent traditional tradable sectors shrink in the NRR-abundant economy during the boom and if such effects are exported to a neighboring jurisdiction. Using data at the U.S. county level, the empirical results show that booming economies experience positive and statistically significant rates of real income and traded sector job growth during the boom, attributable to the influx of migrant labor. By contrast, little evidence is found that non-booming counties adjacent to the booming counties experience declines in income or job growth because of labor supply outflows. Instead, the results suggest the larger the number of potential "donor" counties that can supply labor to the booming economies, the more likely the transmission of booming economy effects, namely evidence of de-industrialization, is diffused across all of the

  11. Clays causing adhesion with tool surfaces during mechanical tunnel driving

    NASA Astrophysics Data System (ADS)

    Spagnoli, G.; Fernández-Steeger, T.; Stanjek, H.; Feinendegen, M.; Post, C.; Azzam, R.

    2009-04-01

    During mechanical excavation with a tunnel boring machine (TBM) it is possible that clays stick to the cutting wheel and to other metal parts. The resulting delays in the progress of construction work, cause great economic damage and often disputes between the public awarding authorities and executing companies. One of the most important factors to reduce successfully the clay adhesion is the use of special polymers and foams. But why does the clay stick to the metal parts? A first step is to recognize which kind of clay mineralogy shows serious adhesion problems. The mechanical properties of clay and clay suspensions are primarily determined by surface chemistry and charge distribution at the interfaces, which in turn affect the arrangement of the clay structure. As we know, clay is a multi-phase material and its behaviour depends on numerous parameters such as: clay mineralogy, clay fraction, silt fraction, sand fraction, water content, water saturation, Atterberg limits, sticky limit, activity, cation exchange capacity, degree of consolidation and stress state. It is therefore likely that adhesion of clay on steel is also affected by these clay parameters. Samples of clay formations, which caused problems during tunnel driving, will be analyzed in laboratory. Mineralogical analyses (diffractometry, etc.) will be carried out to observe which minerals are responsible for adherence problems. To manipulate the physical properties, batch tests will be carried out in order to eliminate or reduce the adhesion on tool surfaces through variation of the zeta potential. Second step is the performance of vane shear tests on clay samples. Different pore fluid (distilled water, pure NaCl solution, ethanol and methanol) will be used to study the variation of the mechanical behaviour of clay depending on the dielectric constant of the fluids. This project is funded by the German Federal Ministry of Education and Research (BMBF) and the DFG (German Research Foundation) in the

  12. Economic booms and risky sexual behavior: evidence from Zambian copper mining cities.

    PubMed

    Wilson, Nicholas

    2012-12-01

    Existing studies suggest that individual and household level economic shocks affect the demand for and supply of risky sex. However, little evidence exists on the effects of an aggregate shock on equilibrium risky sexual behavior. This paper examines the effects of the early twenty-first century copper boom on risky sexual behavior in Zambian copper mining cities. The results suggest that the copper boom substantially reduced rates of transactional sex and multiple partnerships in copper mining cities. These effects were partly concentrated among young adults and copper boom induced in-migration to mining cities appears to have contributed to these reductions. Copyright © 2012. Published by Elsevier B.V.

  13. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2000-01-01

    Part of the 1999 Industrial Minerals Review. The state of the ball clay industry in 1999 is presented. Record highs in the sales and use of ball clay were attained in 1999 due to the continued strength of the U.S. economy. U.S. production was estimated at 1.25 million st for the year, with more than half of that amount mined in Tennessee. Details of the consumption, price, imports, and exports of ball clay in 1999 and the outlook for ball clay over the next few years are provided.

  14. Clay for Little Fingers.

    ERIC Educational Resources Information Center

    Koster, Joan Bouza

    1999-01-01

    Discusses the renewed interest in clay as a modeling compound in early childhood programs; describes the nature of clay and presents a working vocabulary. Suggests methods of working with clay, including introducing clay to children, discovering its uses, clean up, firing clay, and finishing baked clay. Includes activity suggestions and…

  15. 1995 NASA High-Speed Research Program Sonic Boom Workshop. Volume 2; Configuration Design, Analysis, and Testing

    NASA Technical Reports Server (NTRS)

    Baize, Daniel G. (Editor)

    1999-01-01

    The High-Speed Research Program and NASA Langley Research Center sponsored the NASA High-Speed Research Program Sonic Boom Workshop on September 12-13, 1995. The workshop was designed to bring together NASAs scientists and engineers and their counterparts in industry, other Government agencies, and academia working together in the sonic boom element of NASAs High-Speed Research Program. Specific objectives of this workshop were to: (1) report the progress and status of research in sonic boom propagation, acceptability, and design; (2) promote and disseminate this technology within the appropriate technical communities; (3) help promote synergy among the scientists working in the Program; and (4) identify technology pacing, the development C, of viable reduced-boom High-Speed Civil Transport concepts. The Workshop was organized in four sessions: Sessions 1 Sonic Boom Propagation (Theoretical); Session 2 Sonic Boom Propagation (Experimental); Session 3 Acceptability Studies-Human and Animal; and Session 4 - Configuration Design, Analysis, and Testing.

  16. Influence of Chair Vibrations on Indoor Sonic Boom Annoyance

    NASA Technical Reports Server (NTRS)

    Rathsam, Jonathan; Klos, Jacob; Loubeau, Alexandra

    2015-01-01

    One goal of NASA’s Commercial Supersonic Technology Project is to identify candidate noise metrics suitable for regulating quiet sonic boom aircraft. A suitable metric must consider the short duration and pronounced low frequency content of sonic booms. For indoor listeners, rattle and creaking sounds and floor and chair vibrations may also be important. The current study examined the effect of such vibrations on the annoyance of test subjects seated indoors. The study involved two chairs exposed to nearly identical acoustic levels: one placed directly on the floor, and the other isolated from floor vibrations by pneumatic elastomeric mounts. All subjects experienced both chairs, sitting in one chair for the first half of the experiment and the other chair for the remaining half. Each half of the experiment consisted of 80 impulsive noises played at the exterior of the sonic boom simulator. When all annoyance ratings were analyzed together there appeared to be no difference in mean annoyance with isolation condition. When the apparent effect of transfer bias was removed, a subtle but measurable effect of vibration on annoyance was identified.

  17. Comparison of jet plume shape predictions and plume influence on sonic boom signature

    NASA Technical Reports Server (NTRS)

    Barger, Raymond L.; Melson, N. Duane

    1992-01-01

    An Euler shock-fitting marching code yields good agreement with semiempirically determined plume shapes, although the agreement decreases somewhat with increasing nozzle angle and the attendant increase in the nonisentropic nature of the flow. Some calculations for the low boom configuration with a simple engine indicated that, for flight at altitudes above 60,000 feet, the plume effect is dominant. This negates the advantages of a low boom design. At lower altitudes, plume effects are significant, but of the order that can be incorporated into the low boom design process.

  18. Portable tripod-mounted boom sprayer for applying herbicides on tall shrubs

    Treesearch

    Charles A. Graham; Jay R. Bentley

    1975-01-01

    A tripod-supported boom sprayer was developed and used to spray herbicides on shrubs up to 15 feet tall on experimental plots where use of other spray equipment was not feasible. A pneumatic pressurized sprayer with 10 diaphragm nozzles, geometrically spaced along the outer 20 feet (6.1 m) of a 25-foot (7.6-m) boom, distributed the spray uniformly. Brush leaves were...

  19. Sonic boom measurement test plan for Space Shuttle STS-3 reentry

    NASA Technical Reports Server (NTRS)

    Henderson, H. R.

    1982-01-01

    The lateral area from the reentry ground track affected by sonic boom overpressure levels is determined. Four data acquisition stations are deployed laterally to the STS-3 reentry flight track. These stations provide six intermediate band FM channels of sonic boom data, universal time synchronization, and voice annotation. All measurements are correlated with the vehicle reentry flight track information along with atmospheric and vehicle operation conditions.

  20. High speed civil transport: Sonic boom softening and aerodynamic optimization

    NASA Technical Reports Server (NTRS)

    Cheung, Samson

    1994-01-01

    An improvement in sonic boom extrapolation techniques has been the desire of aerospace designers for years. This is because the linear acoustic theory developed in the 60's is incapable of predicting the nonlinear phenomenon of shock wave propagation. On the other hand, CFD techniques are too computationally expensive to employ on sonic boom problems. Therefore, this research focused on the development of a fast and accurate sonic boom extrapolation method that solves the Euler equations for axisymmetric flow. This new technique has brought the sonic boom extrapolation techniques up to the standards of the 90's. Parallel computing is a fast growing subject in the field of computer science because of its promising speed. A new optimizer (IIOWA) for the parallel computing environment has been developed and tested for aerodynamic drag minimization. This is a promising method for CFD optimization making use of the computational resources of workstations, which unlike supercomputers can spend most of their time idle. Finally, the OAW concept is attractive because of its overall theoretical performance. In order to fully understand the concept, a wind-tunnel model was built and is currently being tested at NASA Ames Research Center. The CFD calculations performed under this cooperative agreement helped to identify the problem of the flow separation, and also aided the design by optimizing the wing deflection for roll trim.

  1. One of many microphones arrayed under the path of the F-5E SSBE aircraft to record sonic booms

    NASA Image and Video Library

    2004-01-13

    One of many microphones arrayed under the path of the F-5E SSBE (Shaped Sonic Boom Experiment) aircraft to record sonic booms. The SSBE (Shaped Sonic Boom Experiment) was formerly known as the Shaped Sonic Boom Demonstration, or SSBD, and is part of DARPA's Quiet Supersonic Platform (QSP) program. On August 27, 2003, the F-5E SSBD aircraft demonstrated a method to reduce the intensity of sonic booms.

  2. Effect of confining pressure on diffusion coefficients in clay-rich, low-permeability sedimentary rocks.

    PubMed

    Xiang, Y; Al, T; Mazurek, M

    2016-12-01

    The effect of confining pressure (CP) on the diffusion of tritiated-water (HTO) and iodide (I - ) tracers through Ordovician rocks from the Michigan Basin, southwestern Ontario, Canada, and Opalinus Clay from Schlattingen, Switzerland was investigated in laboratory experiments. Four samples representing different formations and lithologies in the Michigan Basin were studied: Queenston Formation shale, Georgian Bay Formation shale, Cobourg Formation limestone and Cobourg Formation argillaceous limestone. Estimated in situ vertical stresses at the depths from which the samples were retrieved range from 12.0 to 17.4MPa (Michigan Basin) and from 21 to 23MPa (Opalinus Clay). Effective diffusion coefficients (D e ) were determined in through-diffusion experiments. With HTO tracer, applying CP resulted in decreases in D e of 12.5% for the Queenston Formation shale (CP max =12MPa), 30% for the Georgian Bay Formation shale (15MPa), 34% for the Cobourg Formation limestone (17.4MPa), 31% for the Cobourg Formation argillaceous limestone (17.4MPa) and 43-46% for the Opalinus Clay (15MPa). Decreases in D e were larger for the I - tracer: 13.8% for the Queenston shale, 42% for the Georgian Bay shale, 50% for the Cobourg Formation limestone, 55% for the Cobourg Formation argillaceous limestone and 63-68% for the Opalinus Clay. The tracer-specific nature of the response is attributed to an increasing influence of anion exclusion as the pore size decreases at higher CP. Results from the shales (including Opalinus Clay) indicate that the pressure effect on D e can be represented by a linear relationship between D e and ln(CP), which provides valuable predictive capability. The nonlinearity results in a relatively small change in D e at high CP, suggesting that it is not necessary to apply the exact in situ pressure conditions in order to obtain a good estimate of the in situ diffusion coefficient. Most importantly, the CP effect on shale is reversible (±12%) suggesting that, for

  3. Clay Houses

    ERIC Educational Resources Information Center

    Pedro, Cathy

    2011-01-01

    In this article, the author describes a project designed for fourth-graders that involves making clay relief sculptures of houses. Knowing the clay houses will become a family heirloom makes this lesson even more worth the time. It takes three classes to plan and form the clay, and another two to underglaze and glaze the final products.

  4. Aerial Refueling Boom/Receptacle Guide

    DTIC Science & Technology

    2017-07-28

    Alleviation System; AR – Aerial Refueling; IDS – Independent Disconnect System; PDL – Pilot Director Lights; PSIG – Pounds per square inch gauge; TMF...proprietary, sensitive, classified or otherwise restricted information. ARSAG documents, as prepared, are not DOD, MOD or NATO standards, but provide...Boom Nozzle Disconnect Provisions, Aerial Refueling Fuel System and Tanker Aids and Cues for the Receiver Aircraft. Also included are Receiver

  5. Boom and chassis articulation joints

    NASA Technical Reports Server (NTRS)

    Murphy, Joel T., Jr.; Nguyen, Vien; Turner, Bonnie; Wheeler, Bobby; Williams, Kimberlyn

    1992-01-01

    The primary goal of our design project was to develop articulation joints for the chassis and boom of the proof-of-concept lunar vehicle. This is an ongoing project and the work of previous student groups was extensively reviewed. Some of the ideas generated are variations of past proposals. Although the project is funded by NASA/USRA, it is totally a student design effort.

  6. Babies Bottom Out--A 'Maybe Boom'

    ERIC Educational Resources Information Center

    Science News, 1977

    1977-01-01

    Data for the period September 1976 through April 1977 indicate a rise in the United States birth rate; however, the rate is still below the replacement level. It is speculated that the increase is an "echo" effect to the post-World War II baby boom which peaked in 1957. (SL)

  7. Sonic Booms in Atmospheric Turbulence (SonicBAT) Ground Measurements in a Hot Desert Climate

    NASA Technical Reports Server (NTRS)

    Haering, Edward A., Jr.

    2017-01-01

    The Sonic Booms in Atmospheric Turbulence (SonicBAT) Project flew a series of 20 F-18 flights with 69 supersonic passes at Edwards Air Force Base in July 2016 to quantify the effect of atmospheric turbulence on sonic booms. Most of the passes were at a pressure altitude of 32,000 feet and a Mach number of 1.4, yielding a nominal sonic boom overpressure of 1.6 pounds per square foot. Atmospheric sensors such as GPS sondeballoons, Sonic Detection and Ranging (SODAR) acoustic sounders, and ultrasonic anemometers were used to characterize the turbulence state of the atmosphere for each flight. Spiked signatures in excess of 7 pounds per square foot were measured at some locations, as well as rounded sonic-boom signatures with levels much lower than the nominal. This presentation will quantify the range of overpressure and Perceived Level of the sonic boom as a function of turbulence parameters, and also present the spatial variation of these quantities over the array. Comparison with historical data will also be shown.

  8. Role of microbial processes in linking sandstone diagenesis with organic-rich clays

    USGS Publications Warehouse

    McMahon, P.B.; Chapelle, F.H.; Falls, W.F.; Bradley, P.M.

    1992-01-01

    Shows that the processes of microbial organic-acid production (via fermentation) in clays and microbial organic-acid consumption (via sulfate reduction) in sands effectively link organic-rich clays to sandstone diagenesis in the Black Creek Formation of South Carolina. Diagenetic processes have resulted in the formation of 10 volume percent calcite cement, 0.1 volume percent authigenic pyrite, and 1.5 volume percent secondary porosity in Black Creek sands. However, the distribution of these diagenetic processes is not uniform, resulting in net destruction of porosity in some parts of the sand and net porosity enchancement in other parts. -from Authors

  9. Effect of Electric Field on Gas Hydrate Nucleation Kinetics: Evidence for the Enhanced Kinetics of Hydrate Nucleation by Negatively Charged Clay Surfaces.

    PubMed

    Park, Taehyung; Kwon, Tae-Hyuk

    2018-03-06

    Natural gas hydrates are found widely in oceanic clay-rich sediments, where clay-water interactions have a profound effect on the formation behavior of gas hydrates. However, it remains unclear why and how natural gas hydrates are formed in clay-rich sediments in spite of factors that limit gas hydrate formation, such as small pore size and high salinity. Herein, we show that polarized water molecules on clay surfaces clearly promote gas hydrate nucleation kinetics. When water molecules were polarized with an electric field of 10 4 V/m, gas hydrate nucleation occurred significantly faster with an induction time reduced by 5.8 times. Further, the presence of strongly polarized water layers at the water-gas interface hindered gas uptake and thus hydrate formation, when the electric field was applied prior to gas dissolution. Our findings expand our understanding of the formation habits of naturally occurring gas hydrates in clay-rich sedimentary deposits and provide insights into gas production from natural hydrate deposits.

  10. A Flight Research Overview of WSPR, a Pilot Project for Sonic Boom Community Response

    NASA Technical Reports Server (NTRS)

    Cliatt, Larry J., II; Haering, Edward A., Jr.; Jones, Thomas P.; Waggoner, Erin R.; Flattery, Ashley K.; Wiley, Scott L.

    2014-01-01

    In support of the ongoing effort by the National Aeronautics and Space Administration (NASA) to bring supersonic commercial travel to the public, the NASA Armstrong Flight Research Center and the NASA Langley Research Center, in cooperation with other industry organizations, conducted a flight research experiment to identify the methods, tools, and best practices for a large-scale quiet (or low) sonic boom community human response test. The name of the effort was Waveforms and Sonic boom Perception and Response (WSPR). Such tests will be applied to building a dataset that governing agencies such as the Federal Aviation Administration and the International Civil Aviation Organization will use to establish regulations for acceptable sound levels of overland sonic booms. The WSPR test was the first such effort that studied responses to non-traditional low sonic booms while the subject persons were in their own homes and performing daily activities.The WSPR test was a NASA collaborative effort with several industry partners, in response to a NASA Aeronautics Research Mission Directorate Research Opportunities in Aeronautics. The primary contractor was Wyle (El Segundo, California). Other partners included Gulfstream Aerospace Corporation (Savannah, Georgia); Pennsylvania State University (University Park, Pennsylvania); Tetra Tech, Inc. (Pasadena, California); and Fidell Associates, Inc. (Woodland Hills, California).A major objective of the effort included exposing a community to the sonic boom magnitudes and occurrences that would be expected to occur in high-air traffic regions having a network of supersonic commercial aircraft in place. Low-level sonic booms designed to simulate those produced by the next generation of commercial supersonic aircraft were generated over a small residential community. The sonic boom footprint was recorded with an autonomous wireless microphone array that spanned the entire community. Human response data were collected using multiple

  11. Modified clay sorbents

    DOEpatents

    Fogler, H. Scott; Srinivasan, Keeran R.

    1990-01-01

    A novel modified clay sorbent and method of treating industrial effluents to remove trace pollutants, such as dioxins, biphenyls, and polyaromatics such as benzo(a)pyrene and pentachlorophenol. The novel clay sorbent has a composite structure in which the interlayer space of an expandable clay, such as smectite, is filled with polyvalent or multivalent inorganic cations which forces weaker surfactant cations to locate on the surface of the clay in such an orientation that the resulting composite is hydrophilic in nature. A specific example is cetylpyridinium-hydroxy aluminum-montmorillonite. In certain embodiments, a non-expanding clay, such as kaolinite, is used and surfactant cations are necessarily located on an external surface of the clay. A specific example is cetylpyridinium-kaolinite.

  12. Multidisciplinary design optimization for sonic boom mitigation

    NASA Astrophysics Data System (ADS)

    Ozcer, Isik A.

    Automated, parallelized, time-efficient surface definition and grid generation and flow simulation methods are developed for sharp and accurate sonic boom signal computation in three dimensions in the near and mid-field of an aircraft using Euler/Full-Potential unstructured/structured computational fluid dynamics. The full-potential mid-field sonic boom prediction code is an accurate and efficient solver featuring automated grid generation, grid adaptation and shock fitting, and parallel processing. This program quickly marches the solution using a single nonlinear equation for large distances that cannot be covered with Euler solvers due to large memory and long computational time requirements. The solver takes into account variations in temperature and pressure with altitude. The far-field signal prediction is handled using the classical linear Thomas Waveform Parameter Method where the switching altitude from the nonlinear to linear prediction is determined by convergence of the ground signal pressure impulse value. This altitude is determined as r/L ≈ 10 from the source for a simple lifting wing, and r/L ≈ 40 for a real complex aircraft. Unstructured grid adaptation and shock fitting methodology developed for the near-field analysis employs an Hessian based anisotropic grid adaptation based on error equidistribution. A special field scalar is formulated to be used in the computation of the Hessian based error metric which enhances significantly the adaptation scheme for shocks. The entire cross-flow of a complex aircraft is resolved with high fidelity using only 500,000 grid nodes after only about 10 solution/adaptation cycles. Shock fitting is accomplished using Roe's Flux-Difference Splitting scheme which is an approximate Riemann type solver and by proper alignment of the cell faces with respect to shock surfaces. Simple to complex real aircraft geometries are handled with no user-interference required making the simulation methods suitable tools for

  13. A two cable, six link boom crane for lunar construction

    NASA Technical Reports Server (NTRS)

    Taylor, Robert M.; Mikulas, Martin M., Jr.; Hedgepeth, John M.

    1993-01-01

    This paper presents the conceptual design and analysis of a modified crane boom and cable suspension which provide contro1 over all six degrees of freedom of a payload. Two cables pass around pulleys to form six links between the payload and boom. A linearization of the pulley mechanics was derived to create finite element models of the system. The models were experimentally verified and used to explore variations of the suspension geometry. Several crane concepts which use the suspension are discussed and illustrated.

  14. Sonic-boom ground-pressure measurements from Apollo 15

    NASA Technical Reports Server (NTRS)

    Hilton, D. A.; Henderson, H. R.; Mckinney, R.

    1972-01-01

    Sonic boom pressure signatures recorded during the launch and reentry phases of the Apollo 15 mission are presented. The measurements were obtained along the vehicle ground track at 87 km and 970 km downrange from the launch site during ascent; and at 500 km, 55.6 km, and 12.9 km from the splashdown point during reentry. Tracings of the measured signatures are included along with values of the overpressure, impulse, time duration, and rise times. Also included are brief descriptions of the launch and recovery test areas in which the measurements were obtained, the sonic boom instrumentation deployment, flight profiles and operating conditions for the launch vehicle and spacecraft, surface weather information at the measuring sites, and high altitude weather information for the general measurement areas.

  15. Design for a Unitary Graphite Composite Instrument Boom

    NASA Technical Reports Server (NTRS)

    Alexander, Wes; Carlos, Rene; Sturm, James; Rossoni, Peter

    2004-01-01

    This paper describes development of a Unitary graphite composite instrument boom that incorporates carpenter-tape like hinges for stowage. While light and stiff, graphite composite is not ordinarily thought of as a flexible material. This design has taken advantage of the stiffness of the composite in tubular geometry, yet leveraged its thin- section behavior to place flexibility at the required locations. Key is the proprietary layup, which results in a tough yet flexible hinge capable of rotating over 90 degrees in each direction. When the boom deploys, there is enough torque to overcome parasitic resistance from harness, etc. It will snap to the fully extended, rigid shape. The design has addressed materials issues such as out-of-plane bending, edge cracking, and interlaminar ply separation.

  16. Characterization of clay scales forming in Philippine geothermal wells

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reyes, A.G.; Cardile, C.M.

    1989-01-01

    Smectite scales occur in 24 out of the 36 blocked wells located in Tongonan, Palinpinon and Bacon-Manito. These comprise 2-85% of the well scales and form at depths of 33-2620 m, where measured and fluid inclusion temperatures are 40-320{sup 0}C. Most, however, occur below the production casing show where temperatures are {ge}230{sup 0}C, often at depths coinciding with aquifers. The clay scales are compositionally and structurally different from the bentonite used in drilling, which is essentially sodium-rich montmorillonite. The clay deposits are expanding, generally disordered, and combine the characteristics of a montmorillonite, saponite and vermiculite in terms of reaction tomore » cationic exchange treatments, structure and composition. Six types of clay scales are identified, but the predominant one, comprising 60-100% of the clay deposits in a well, is Mg- and Fe-rich and referred to as a vermiculitic species. The crystallinity, degree of disorder, textures, optical characteristics, structure and relative amounts of structural Al, Mg and Fe vary with time, temperature and fluid composition, but not with depth and measured pressure. Despite its variance from bentonite characteristics, one of the dominant suggested mechanisms of clay scale formation uses the drilling mud in the well as a substrate, from which the Mg- and Fe-rich clay evolves.« less

  17. Comparative thermal analysis of the Space Station Freedom photovoltaic deployable boom structure using TRASYS, NEVADA, and SINDA programs

    NASA Technical Reports Server (NTRS)

    Baumeister, Joseph F.; Beach, Duane E.; Armand, Sasan C.

    1989-01-01

    The proposed Space Station Photovoltaic Deployable Boom was analyzed for operating temperatures. The boom glass/epoxy structure design needs protective shielding from environmental degradation. The protective shielding optical properties (solar absorptivity and emissivity) dictate the operating temperatures of the boom components. The Space Station Boom protective shielding must also withstand the effects of the extendible/retractable coiling acting within the mast canister. A thermal analysis method was developed for the Space Station Deployable Boom to predict transient temperatures for a variety of surface properties. The modeling procedures used to evaluate temperatures within the boom structure incorporated the TRASYS, NEVADA, and SINDA thermal analysis programs. Use of these programs led to a comparison between TRASYS and NEVADA analysis methods. Comparing TRASYS and NEVADA results exposed differences in the environmental solar flux predictions.

  18. Comparative thermal analysis of the space station Freedom photovoltaic deployable boom structure using TRASYS, NEVADA, and SINDA programs

    NASA Technical Reports Server (NTRS)

    Baumeister, Joseph F.; Beach, Duane E.; Armand, Sasan C.

    1989-01-01

    The proposed Space Station Photovoltaic Deployable Boom was analyzed for operating temperatures. The boom glass/epoxy structure design needs protective shielding from environmental degradation. The protective shielding optical properties (solar absorptivity and emissivity) dictate the operating temperatures of the boom components. The Space Station Boom protective shielding must also withstand the effects of the extendible/retractable coiling action within the mast canister. A thermal analysis method was developed for the Space Station Deployable Boom to predict transient temperatures for a variety of surface properties. The modeling procedures used to evaluate temperatures within the boom structure incorporated the TRASYS, NEVADA, and SINDA thermal analysis programs. Use of these programs led to a comparison between TRASYS and NEVADA analysis methods. Comparing TRASYS and NEVADA results exposed differences in the environmental solar flux predictions.

  19. CFD Predictions of Sonic-Boom Characteristics for Unmodified and Modified SR-71 Configurations

    NASA Technical Reports Server (NTRS)

    Fouladi, Kamran

    1999-01-01

    Shaped sonic-boom signatures refer to signatures that look something other than the typical N-waves. Shaped sonic-boom signatures such as "flat-top," "ramp-type," or "hybrid-type" waveforms have been shown to reduce the subjective loudness without requiring reductions in overpressure peaks. The shaping of sonic-boom signatures requires increasing the shock rise time and changes in frequency spectra. So far, a flat-top waveform was shown to be achievable in wind tunnels; however, the influence of long propagation distance and real atmosphere on shaped signatures should be addressed using flight tests. Two different approaches have been proposed for sonic-boom minimization flight tests. The first approach, proposed by Eagle Aerospace, is for a flight test using a modified BQM-34 "FIREBEE" remotely piloted vehicle. The 30-foot long FIREBEE has a steady state flight condition at the Mach number and altitude of interest, and it can be recovered by helicopter from the water. As an alternative approach, a modified SR-71 vehicle has been proposed by the McDonnell Douglas Corporation. Benefits of the SR-71 include its variable geometry supersonic inlets, small cockpit bulge, higher Mach number capabilities, slender design, and longer length (105 foot). The present investigation addresses the sonic-boom analysis for the second vehicle.The objective of the current investigation is to assess the feasibility of a modified SR-71 configuration, with McDonnell Douglas-designed fuselage modifications, intended to produce shaped sonic-boom signatures on the ground. The present study describes the use of a higher-order computational fluid dynamics (CFD) method to predict the sonic-boom characteristics for both unmodified and modified SR-71 configurations. An Euler unstructured grid methodology is used to predict the near-field, three-dimensional pressure patterns generated by both SR-71 models. The computed near-field pressure signatures are extrapolated to specified distances below

  20. Ball clay and bentonite deposits of the central and western Gulf of Mexico Coastal Plain, United States

    USGS Publications Warehouse

    Hosterman, John W.

    1984-01-01

    The Gulf of Mexico Coastal Plain produces approximately 85 percent of the ball clay used in the United States. The best commercial-grade clay deposits are composed of poorly crystalline kaolinite and small amounts of Md illite and (or) smectite. Sand and silt and iron oxide minerals are virtually absent, but quartz is present in the clay-size fraction. The best grade ball clays are found as lenses limited to the Wilcox Group (Paleocene and lower Eocene) and Claiborne Group (middle Eocene). Reserves of ball clay are sufficient for the present, but because of the lenticular nature of the clay bodies, close-spaced drilling, detailed sampling, mineralogic analyses, and ceramic testing are needed to prove future reserves.Approximately 11 percent of the total bentonite produced in the United States comes from the Gulf Coast region. The commercial-grade bentonites are composed primarily of smectite with little or no Md illite and kaolinite. The nonclay impurities are quartz, feldspar, muscovite, biotite, calcite, dolomite, gypsum, and heulandite. Commercial bentonites occur in the Upper Cretaceous formations in Alabama and Mississippi, in Paleocene formations in Mississippi and Tennessee, and in Eocene and Miocene formations in Texas. The demand for low-swelling bentonite of the Gulf Coastal Plain has not increased along with the demand for swelling bentonite; therefore the reserves are adequate.

  1. Effect of sonic boom on avalanches. Preparation for flight of a supersonic jet over the Lavay Valley

    NASA Technical Reports Server (NTRS)

    Schaffar, M.; Carrie, B.; Amardeil, P.

    1986-01-01

    An experiment to determine the effect of sonic booms on the stability of the snow mantle in the Lavey Valley is proposed. It includes provisions for the aircraft trajectory, line of fucus, boom zone, as well as the determination of boom intensity levels for the whole valley.

  2. Concorde sonic booms as an atmospheric probe.

    PubMed

    Balachandran, N K; Donn, W L; Rind, D H

    1977-07-01

    Infrasound generated by the sonic boom from the inbound Concorde supersonic transport is recorded at Palisades, New York (Lamont-Doherty Geological Observatory), as a series of impulses from distances varying from 165 to about 1000 kilometers. Refraction effects determined by temperature and wind conditions return the signal to the surface from both stratospheric (40 to 50 kilometers) and thermospheric (100 to 130 kilometers) levels. The frequency of the recorded signal is a function of the level of reflection; the frequency decreases from impulse stretching as the atmosphere becomes more rarified relative to the sound pressure. The horizontal trace velocity of the signal across the array of instruments is equal to the acoustic velocity at the reflection level. The sonic boom can thus be used to provide temperature-wind parameters at reflection levels estimated from the signal frequency. Daily observed signal variations have indicated significant variations in these parameters.

  3. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2006-01-01

    In 2005, six companies mined fire clay in Missouri, Ohio and South Carolina. Production was estimate to be 300 kt with a value of $8.3 million. Missouri was the leading producer state followed by Ohio and South Carolina. For the third consecutive year, sales and use of fire clays have been relatively unchanged. For the next few years, sales of fire clay is forecasted to remain around 300 kt/a.

  4. Infectivity, distribution, and persistence of the entomopathogenic nematode Steinernema carpocapsae all strain (Rhabditida: Steinernematidae) applied by sprinklers or boom sprayer to dry-pick cranberries.

    PubMed

    Hayes, A E; Fitzpatrick, S M; Webster, J M

    1999-06-01

    maximum of 45% on the 3rd d after application by boom sprayer and declined thereafter. In the fall, when assays lasted 10 d, percentage of infectivity rose to a maximum of 58% on the 7th d after application through sprinklers and remained between 20 and 58% until day 135, declining thereafter; infectivity after boom application remained between 37 and 45% on days 3 and 7, and began to decline on day 25. Nematode infectivity was not compromised in peat soil, muck, or silty clay loam, but infectivity in loam (that may have contained nematicide residues) was very low. We suggest that the inconsistent control of O. sulcatus by S. carpocapsae on British Columbia cranberry farms may be partially explained by problems associated with application and factors related to nematode entry into the soil.

  5. Detection and Assessment of Secondary Sonic Booms in New England.

    DTIC Science & Technology

    1980-05-01

    MEASUREMENT DATA During the period May 3, 1979 to September 14, 1979, infra - sonic measurements were made at Malden MA, at six other sites in the Greater...D-AO8O 160 TRANSPORTATION SYSTEMS CENTER CAMBRIDGE MA F/ 20/1 DETECTION AND ASSESSMENT OF SECONDARY SONIC BOOMS IN NEW ENGLAN--ETC(U) MAY 80 E J...CHART F AA-AEE-8O-22 DETECTION AND ASSESSMENT OF SECONDARY SONIC BOOMS IN NEW ENGLAND AD A088 160 MAY 1980 Q4 = Ci OF T R, 4 This document has been

  6. A methodology for designing aircraft to low sonic boom constraints

    NASA Technical Reports Server (NTRS)

    Mack, Robert J.; Needleman, Kathy E.

    1991-01-01

    A method for designing conceptual supersonic cruise aircraft to meet low sonic boom requirements is outlined and described. The aircraft design is guided through a systematic evolution from initial three view drawing to a final numerical model description, while the designer using the method controls the integration of low sonic boom, high supersonic aerodynamic efficiency, adequate low speed handling, and reasonable structure and materials technologies. Some experience in preliminary aircraft design and in the use of various analytical and numerical codes is required for integrating the volume and lift requirements throughout the design process.

  7. View looking north west showing the boom, top of the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View looking north west showing the boom, top of the center mast and boom angle reeving of the 175-ton derrick. Note in the background of the view, just above the center mast is the F-1 Static-Test Stand used for test firing the Saturn V engines and subsequent program's engine testing. Also in the background center is the Redstone Static Test Stand (center right) and it's cold calibration tower (center left). - Marshall Space Flight Center, Saturn V Dynamic Test Facility, East Test Area, Huntsville, Madison County, AL

  8. Primordial clays on Mars formed beneath a steam or supercritical atmosphere.

    PubMed

    Cannon, Kevin M; Parman, Stephen W; Mustard, John F

    2017-12-06

    On Mars, clay minerals are widespread in terrains that date back to the Noachian period (4.1 billion to 3.7 billion years ago). It is thought that the Martian basaltic crust reacted with liquid water during this time to form hydrated clay minerals. Here we propose, however, that a substantial proportion of these clays was formed when Mars' primary crust reacted with a dense steam or supercritical atmosphere of water and carbon dioxide that was outgassed during magma ocean cooling. We present experimental evidence that shows rapid clay formation under conditions that would have been present at the base of such an atmosphere and also deeper in the porous crust. Furthermore, we explore the fate of a primordial clay-rich layer with the help of a parameterized crustal evolution model; we find that the primordial clay is locally disrupted by impacts and buried by impact-ejected material and by erupted volcanic material, but that it survives as a mostly coherent layer at depth, with limited surface exposures. These exposures are similar to those observed in remotely sensed orbital data from Mars. Our results can explain the present distribution of many clays on Mars, and the anomalously low density of the Martian crust in comparison with expectations.

  9. Primordial clays on Mars formed beneath a steam or supercritical atmosphere

    NASA Astrophysics Data System (ADS)

    Cannon, Kevin M.; Parman, Stephen W.; Mustard, John F.

    2017-12-01

    On Mars, clay minerals are widespread in terrains that date back to the Noachian period (4.1 billion to 3.7 billion years ago). It is thought that the Martian basaltic crust reacted with liquid water during this time to form hydrated clay minerals. Here we propose, however, that a substantial proportion of these clays was formed when Mars’ primary crust reacted with a dense steam or supercritical atmosphere of water and carbon dioxide that was outgassed during magma ocean cooling. We present experimental evidence that shows rapid clay formation under conditions that would have been present at the base of such an atmosphere and also deeper in the porous crust. Furthermore, we explore the fate of a primordial clay-rich layer with the help of a parameterized crustal evolution model; we find that the primordial clay is locally disrupted by impacts and buried by impact-ejected material and by erupted volcanic material, but that it survives as a mostly coherent layer at depth, with limited surface exposures. These exposures are similar to those observed in remotely sensed orbital data from Mars. Our results can explain the present distribution of many clays on Mars, and the anomalously low density of the Martian crust in comparison with expectations.

  10. Cart3D Simulations for the Second AIAA Sonic Boom Prediction Workshop

    NASA Technical Reports Server (NTRS)

    Anderson, George R.; Aftosmis, Michael J.; Nemec, Marian

    2017-01-01

    Simulation results are presented for all test cases prescribed in the Second AIAA Sonic Boom Prediction Workshop. For each of the four nearfield test cases, we compute pressure signatures at specified distances and off-track angles, using an inviscid, embedded-boundary Cartesian-mesh flow solver with output-based mesh adaptation. The cases range in complexity from an axisymmetric body to a full low-boom aircraft configuration with a powered nacelle. For efficiency, boom carpets are decomposed into sets of independent meshes and computed in parallel. This also facilitates the use of more effective meshing strategies - each off-track angle is computed on a mesh with good azimuthal alignment, higher aspect ratio cells, and more tailored adaptation. The nearfield signatures generally exhibit good convergence with mesh refinement. We introduce a local error estimation procedure to highlight regions of the signatures most sensitive to mesh refinement. Results are also presented for the two propagation test cases, which investigate the effects of atmospheric profiles on ground noise. Propagation is handled with an augmented Burgers' equation method (NASA's sBOOM), and ground noise metrics are computed with LCASB.

  11. Effectiveness of large booms as nutation dampers for spin stabilized spacecraft

    NASA Technical Reports Server (NTRS)

    Eke, F. O.

    1991-01-01

    The issue of using long slender booms as pendulous nutation damping devices on spinning aircraft is discussed. Motivation comes from experience with the Galileo Spacecraft, whose magnetometer boom also serves as a passive nutation damper for the spacecraft. Performance analysis of a spacecraft system equipped with such systems are relatively insensitive to changes in the damping constant of the device. However, the size and arrangement of such a damper raises important questions concerning spacecraft stability in general.

  12. Sonic-boom minimization.

    NASA Technical Reports Server (NTRS)

    Seebass, R.; George, A. R.

    1972-01-01

    There have been many attempts to reduce or eliminate the sonic boom. Such attempts fall into two categories: (1) aerodynamic minimization and (2) exotic configurations. In the first category changes in the entropy and the Bernoulli constant are neglected and equivalent body shapes required to minimize the overpressure, the shock pressure rise and the impulse are deduced. These results include the beneficial effects of atmospheric stratification. In the second category, the effective length of the aircraft is increased or its base area decreased by modifying the Bernoulli constant a significant fraction of the flow past the aircraft. A figure of merit is introduced which makes it possible to judge the effectiveness of the latter schemes.

  13. A Performance Assessment of Eight Low-Boom High-Speed Civil Transport Concepts

    NASA Technical Reports Server (NTRS)

    Baize, Daniel G.; McElroy, Marcus O.; Fenbert, James A.; Coen, Peter G.; Ozoroski, Lori P.; Domack, Chris S.; Needleman, Kathy E.; Geiselhart, Karl A.

    1999-01-01

    A performance assessment of eight low-boom high speed civil transport (HSCT) configurations and a reference HSCT configuration has been performed. Although each of the configurations was designed with different engine concepts, for consistency, a year 2005 technology, 0.4 bypass ratio mixed-flow turbofan (MFTF) engine was used for all of the performance assessments. Therefore, all original configuration nacelles were replaced by a year 2005 MFRF nacelle design which corresponds to the engine deck utilized. The engine thrust level was optimized to minimize vehicle takeoff gross weight. To preserve the configuration's sonic-boom shaping, wing area was not optimized or altered from its original design value. Performance sizings were completed when possible for takeoff balanced field lengths of 11,000 ft and 12,000 ft, not considering FAR Part 36 Stage III noise compliance. Additionally, an arbitrary sizing with thrust-to-weight ratio equal to 0.25 was performed, enabling performance levels to be compared independent of takeoff characteristics. The low-boom configurations analyzed included designs from the Boeing Commercial Airplane Group, Douglas Aircraft Company, Ames Research Center, and Langley Research Center. This paper discusses the technology level assumptions, mission profile, analysis methodologies, and the results of the assessment. The results include maximum lift-to-drag ratios, total fuel consumption, number of passengers, optimum engine sizing plots, takeoff performance, mission block time, and takeoff gross weight for all configurations. Results from the low-boom configurations are also compared with a non-low-boom reference configuration. Configuration dependent advantages or deficiencies are discussed as warranted.

  14. Adjoint-Based Mesh Adaptation for the Sonic Boom Signature Loudness

    NASA Technical Reports Server (NTRS)

    Rallabhandi, Sriram K.; Park, Michael A.

    2017-01-01

    The mesh adaptation functionality of FUN3D is utilized to obtain a mesh optimized to calculate sonic boom ground signature loudness. During this process, the coupling between the discrete-adjoints of the computational fluid dynamics tool FUN3D and the atmospheric propagation tool sBOOM is exploited to form the error estimate. This new mesh adaptation methodology will allow generation of suitable meshes adapted to reduce the estimated errors in the ground loudness, which is an optimization metric employed in supersonic aircraft design. This new output-based adaptation could allow new insights into meshing for sonic boom analysis and design, and complements existing output-based adaptation techniques such as adaptation to reduce estimated errors in off-body pressure functional. This effort could also have implications for other coupled multidisciplinary adjoint capabilities (e.g., aeroelasticity) as well as inclusion of propagation specific parameters such as prevailing winds or non-standard atmospheric conditions. Results are discussed in the context of existing methods and appropriate conclusions are drawn as to the efficacy and efficiency of the developed capability.

  15. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, H.H.; Li, L.; Zheng, L.

    Clay/shale has been considered as potential host rock for geological disposal of high-level radioactive waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus Clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at the Mol site, Belgium (Barnichon and Volckaert, 2003) have all been under intensive scientific investigation (at both field and laboratory scales) for understanding amore » variety of rock properties and their relationships to flow and transport processes associated with geological disposal of radioactive waste. Figure 1-1 presents the distribution of clay/shale formations within the USA.« less

  16. High-Speed Research: 1994 Sonic Boom Workshop: Atmospheric Propagation and Acceptability Studies

    NASA Technical Reports Server (NTRS)

    Mccurdy, David A. (Editor)

    1994-01-01

    The workshop proceedings include papers on atmospheric propagation and acceptability studies. Papers discussing atmospheric effects on the sonic boom waveform addressed several issues. It has long been assumed that the effects of molecular relaxation are adequately accounted for by assuming that a steady state balance between absorption and nonlinear wave steepening exists. It was shown that the unsteadiness induced by the nonuniform atmosphere precludes attaining this steady state. Further, it was shown that the random atmosphere acts as a filter, effectively filtering out high frequency components of the distorted waveform. Several different propagation models were compared, and an analysis of the sonic boom at the edge of the primary carpet established that the levels there are bounded. Finally, a discussion of the levels of the sonic boom below the sea surface was presented.

  17. Solution of the lossy nonlinear Tricomi equation with application to sonic boom focusing

    NASA Astrophysics Data System (ADS)

    Salamone, Joseph A., III

    Sonic boom focusing theory has been augmented with new terms that account for mean flow effects in the direction of propagation and also for atmospheric absorption/dispersion due to molecular relaxation due to oxygen and nitrogen. The newly derived model equation was numerically implemented using a computer code. The computer code was numerically validated using a spectral solution for nonlinear propagation of a sinusoid through a lossy homogeneous medium. An additional numerical check was performed to verify the linear diffraction component of the code calculations. The computer code was experimentally validated using measured sonic boom focusing data from the NASA sponsored Superboom Caustic and Analysis Measurement Program (SCAMP) flight test. The computer code was in good agreement with both the numerical and experimental validation. The newly developed code was applied to examine the focusing of a NASA low-boom demonstration vehicle concept. The resulting pressure field was calculated for several supersonic climb profiles. The shaping efforts designed into the signatures were still somewhat evident despite the effects of sonic boom focusing.

  18. The influence of shale depositional fabric on the kinetics of hydrocarbon generation through control of mineral surface contact area on clay catalysis

    NASA Astrophysics Data System (ADS)

    Rahman, Habibur M.; Kennedy, Martin; Löhr, Stefan; Dewhurst, David N.; Sherwood, Neil; Yang, Shengyu; Horsfield, Brian

    2018-01-01

    Accurately assessing the temperature and hence the depth and timing of hydrocarbon generation is a critical step in the characterization of a petroleum system. Clay catalysis is a potentially significant modifier of hydrocarbon generation temperature, but experimental studies of clay catalysis show inconsistent or contradictory results. This study tests the hypothesis that source rock fabric itself is an influence on clay mineral catalysis as it controls the extent to which organic matter and clay minerals are physically associated. Two endmember clay-organic fabrics distinguish the source rocks studied: (1) a particulate fabric where organic matter is present as discrete, >5 μm particles and (2) a nanocomposite fabric in which amorphous organic matter is associated with clay mineral surfaces at sub-micron scale. High-resolution electron imaging and bulk geochemical characterisation confirm that samples of the Miocene Monterey Formation (California) are representative of the nanocomposite source rock endmember, whereas samples from the Permian Stuart Range Formation (South Australia) represent the particulate source rock endmember. Kinetic experiments are performed on paired whole rock and kerogen isolate samples from these two formations using open system, non-isothermal pyrolysis at three different heating rates (0.7, 2 and 5 K/min) to determine the effects of the different shale fabrics on hydrocarbon generation kinetics. Extrapolation to a modelled geological heating rate shows a 20 °C reduction in the onset temperature of hydrocarbon generation in Monterey Formation whole rock samples relative to paired kerogen isolates. This result is consistent with the Monterey Formations's nanocomposite fabric where clay catalysis can proceed because reactive clay minerals are intimately associated with organic matter. By contrast, there is no significant difference in the modelled hydrocarbon generation temperature of paired whole rock and kerogen isolates from the

  19. Origin and diagenesis of clay minerals in relation to sandstone paragenesis: An example in eolian dune reservoirs and associated rocks, Permian upper part of the Minnelusa Formation, Powder River basin, Wyoming

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pollastro, R.M.; Schenk, C.J.

    Eolian dune sandstones are the principal reservoir rocks in the Permian upper part of the Minnelusa Formation, Powder River basin, Wyoming. These sandstones formed as shorelines retreated and dunes migrated across siliciclastic sabkhas. Sandstones are mainly quartzarenites; on average, clay minerals constitute about 5 wt.% the whole rock. Although present in minor amounts, clay minerals play an important role in the diagenetic evolution of these sandstones. Allogenic clay minerals are present in shaly rock fragments and laminae. Early infiltration of clays into porous sabkha sands commonly form characteristic menisei or bridges between framework grains or, when more extensive, form coatingsmore » or rims on grain surfaces. Authigenic clays include nearly pure smectite, mixed-layer illite/smectite (I/S), and late diagenetic illite and corrensite; these clay minerals are present as pore-lining cements. In addition to the deposition and neoformation of clay minerals throughout sandstone paragenesis, the conversion of smectite to illite occurred as temperatures increased with progressive burial. A temperature of 103C is calculated at a present depth of 3,200 m using a geothermal gradient of 30C/km and a mean annual surface temperature of 7C. After correction for uplift and erosion (250 m), the maximum calculated temperature for the conversion of all random I/S to ordered I/S is 100C. This calculated temperature is in excellent agreement with temperatures of 100-110C implied from I/S geothermometry.« less

  20. Assessing the role of clay authigenesis in the seawater potassium cycle: A paired K and Mg isotope study of deep-sea pore fluids

    NASA Astrophysics Data System (ADS)

    Santiago Ramos, D. P.; Higgins, J. A.

    2017-12-01

    In situ formation of clays (clay authigenesis) in marine sediments and altered oceanic crust is an important sink of a number of seawater cations. In particular, clay authigenesis is a major, and yet unconstrained, flux in the global seawater potassium cycle. Potassium is the fourth most abundant cation in the ocean, which constitutes an isotopically enriched K reservoir (δ41K 0‰) compared to the solid Earth (δ41K -0.5‰). Understanding what processes control this isotopic offset is the main goal of this study. Here we use a multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS) to measure the K and Mg isotope ratios (41K/39K and 26Mg/24Mg) of deep-sea pore fluids in order to assess the effects of clay formation in the K isotope composition of seawater. Mg isotopes are used as an independent proxy for clay formation, since marine authigenic clays are isotopically distinct from their detrital counterpart, an abundant component of marine sediments. Our study sites (ODP/IODP 1052, U1378, U1395, U1403) vary in location, lithology, age and sedimentation rates; however, pore-fluids from all sites show decreasing K concentrations with depth, suggesting potassium uptake into the sediments. We find that although K concentration trends are similar across all sites, measured δ41K values vary significantly. Results from 1-D diffusion-advection-reaction models suggest that these differences in isotopic profiles arise from a complex interplay between sedimentation rate and K isotopic fractionation during clay formation, aqueous K diffusion and ion exchange reactions. Further, model simulations yield fractionation factors between 0.9980 and 1.0000 for clay formation in deep-sea sediments. Despite the minor contribution of these deep-sea pore-fluids as sinks of seawater K, the processes responsible for K isotope fractionation in our study sites (clay formation and aqueous K diffusion) are also observed at shallow marine systems (major K sinks) and are thus

  1. Vibration characteristics of a deployable controllable-geometry truss boom

    NASA Technical Reports Server (NTRS)

    Dorsey, J. T.

    1983-01-01

    An analytical study was made to evaluate changes in the fundamental frequency of a two dimensional cantilevered truss boom at various stages of deployment. The truss could be axially deployed or retracted and undergo a variety of controlled geometry changes by shortening or lengthening the telescoping diagonal members in each bay. Both untapered and tapered versions of the truss boom were modeled and analyzed by using the finite element method. Large reductions in fundamental frequency occurred for both the untapered and tapered trusses when they were uniformly retracted or maneuvered laterally from their fully deployed position. These frequency reductions can be minimized, however, if truss geometries are selected which maintain cantilever root stiffness during truss maneuvers.

  2. Mineralogical characterization of Greda clays and monitoring of their phase transformations on thermal treatment

    NASA Astrophysics Data System (ADS)

    Panduro, E. Chavez; Cabrejos, J. Bravo

    2010-01-01

    The mineralogical characterization of two clay samples from the Central Andean Region of Peru, denominated White Greda and Red Greda, is reported. These clays contain the clay minerals mica and illite respectively. Both clays were treated thermally in an oxidising atmosphere under controlled conditions up to 1,100°C with the purpose of obtaining information about structural changes that may be useful for pottery manufacture. X-ray fluorescence was used for the elemental characterization of the samples and X-ray diffractometry was used to determine the collapse and formation of the mineral phases present in the samples caused by thermal treatment. At temperatures above 1,000°C it is observed the formation of spinel in the case of White Greda and of hematite, corundum and cristobalite in the case of Red Greda. Room temperature transmission Mössbauer spectroscopy allowed the monitoring of the variation of the hyperfine parameters with the thermal treatment temperature; In the case of the evolution of the quadruple splitting of the paramagnetic Fe3 + sites with temperature, in both clays, the analyses reproduced results such as the “camel back” curve shape, found by other workers (Wagner and Wagner, Hyperfine Interact 154:35-82, 2004; Wagner and Kyek, Hyperfine Interact 154:5-33, 2004).

  3. Ground Truthing Orbital Clay Mineral Observations with the APXS Onboard Mars Exploration Rover Opportunity

    NASA Technical Reports Server (NTRS)

    Schroeder, C.; Gellert, R.; VanBommel, S.; Clark, B. C.; Ming, D. W.; Mittlefehldt, D. S.; Yen, A. S.

    2016-01-01

    NASA's Mars Exploration Rover Opportunity has been exploring approximately 22 km diameter Endeavour crater since 2011. Its rim segments predate the Hesperian-age Burns formation and expose Noachian-age material, which is associated with orbital Fe3+-Mg-rich clay mineral observations [1,2]. Moving to an orders of magnitude smaller instrumental field of view on the ground, the clay minerals were challenging to pinpoint on the basis of geochemical data because they appear to be the result of near-isochemical weathering of the local bedrock [3,4]. However, the APXS revealed a more complex mineral story as fracture fills and so-called red zones appear to contain more Al-rich clay minerals [5,6], which had not been observed from orbit. These observations are important to constrain clay mineral formation processes. More detail will be added as Opportunity is heading into her 10th extended mission, during which she will investigate Noachian bedrock that predates Endeavour crater, study sedimentary rocks inside Endeavour crater, and explore a fluid-carved gully. ESA's ExoMars rover will land on Noachian-age Oxia Planum where abundant Fe3+-Mg-rich clay minerals have been observed from orbit, but the story will undoubtedly become more complex once seen from the ground.

  4. In situ clay formation : evaluation of a proposed new technology for stable containment barriers.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nagy, Kathryn L.; DiGiovanni, Anthony Albert; Fredrich, Joanne T.

    2004-03-01

    Containment of chemical wastes in near-surface and repository environments is accomplished by designing engineered barriers to fluid flow. Containment barrier technologies such as clay liners, soil/bentonite slurry walls, soil/plastic walls, artificially grouted sediments and soils, and colloidal gelling materials are intended to stop fluid transport and prevent plume migration. However, despite their effectiveness in the short-term, all of these barriers exhibit geochemical or geomechanical instability over the long-term resulting in degradation of the barrier and its ability to contain waste. No technologically practical or economically affordable technologies or methods exist at present for accomplishing total remediation, contaminant removal, or destruction-degradationmore » in situ. A new type of containment barrier with a potentially broad range of environmental stability and longevity could result in significant cost-savings. This report documents a research program designed to establish the viability of a proposed new type of containment barrier derived from in situ precipitation of clays in the pore space of contaminated soils or sediments. The concept builds upon technologies that exist for colloidal or gel stabilization. Clays have the advantages of being geologically compatible with the near-surface environment and naturally sorptive for a range of contaminants, and further, the precipitation of clays could result in reduced permeability and hydraulic conductivity, and increased mechanical stability through cementation of soil particles. While limited success was achieved under certain controlled laboratory conditions, the results did not warrant continuation to the field stage for multiple reasons, and the research program was thus concluded with Phase 2.« less

  5. Shear Strength of Remoulding Clay Samples Using Different Methods of Moulding

    NASA Astrophysics Data System (ADS)

    Norhaliza, W.; Ismail, B.; Azhar, A. T. S.; Nurul, N. J.

    2016-07-01

    Shear strength for clay soil was required to determine the soil stability. Clay was known as a soil with complex natural formations and very difficult to obtain undisturbed samples at the site. The aim of this paper was to determine the unconfined shear strength of remoulded clay on different methods in moulding samples which were proctor compaction, hand operated soil compacter and miniature mould methods. All the samples were remoulded with the same optimum moisture content (OMC) and density that were 18% and 1880 kg/m3 respectively. The unconfined shear strength results of remoulding clay soils for proctor compaction method was 289.56kPa with the strain 4.8%, hand operated method was 261.66kPa with the strain 4.4% and miniature mould method was 247.52kPa with the strain 3.9%. Based on the proctor compaction method, the reduction percentage of unconfined shear strength of remoulded clay soil of hand operated method was 9.66%, and for miniature mould method was 14.52%. Thus, because there was no significant difference of reduction percentage of unconfined shear strength between three different methods, so it can be concluded that remoulding clay by hand operated method and miniature mould method were accepted and suggested to perform remoulding clay samples by other future researcher. However for comparison, the hand operated method was more suitable to form remoulded clay sample in term of easiness, saving time and less energy for unconfined shear strength determination purposes.

  6. Vibro-Acoustic Response of Buildings Due to Sonic Boom Exposure: July 2007 Field Test

    NASA Technical Reports Server (NTRS)

    Klos, Jacob

    2008-01-01

    During the month of July 2007, a series of structural response measurements were made on a house on Edwards Air Force Base (EAFB) property that was exposed to sonic booms of various amplitudes. The purpose of this report is to document the measurements that were made, the structure on which they were made, the conditions under which they were made, the sensors and other hardware that were used, and the data that were collected. To that end, Chapter 2 documents the house, its location, the physical layout of the house, the surrounding area, and summarizes the transducers placed in and around the house. Chapter 3 details the sensors and other hardware that were placed in the house during the experiment. In addition, day-to-day variations of hardware configurations and transducer calibrations are documented in Chapter 3. Chapter 4 documents the boom generation process, flight conditions, and ambient weather conditions during the test days. Chapter 5 includes information about sub-experiments that were performed to characterize the vibro-acoustic response of the structure, the acoustic environment inside the house, and the acoustic environment outside the house. Chapter 6 documents the data format and presents examples of reduced data that were collected during the test days.

  7. Clay with Desiccation Cracks is an Advection Dominated Environment

    NASA Astrophysics Data System (ADS)

    Baram, S.; Kurtzman, D.; Sher, Y.; Ronen, Z.; Dahan, O.

    2012-04-01

    Heavy clay sediments are regarded "safe" from the hydrological point of view due to their low hydraulic conductivities. However, the formation of desiccation cracks in dispersive clays may dramatically change their bulk hydraulic properties. The impact of desiccation cracks on water percolation, dissolved salts and contaminants transport and redox related reactions (microbial ammonium oxidation and denitrification) were investigated in 6 -12 m clay layer near a diary farm waste lagoon. The study implemented unique vadose-zone monitoring systems that enable in-situ measurements of the temporal variation of the sediment's water content along with frequent sampling of the sediment's pore water along the entire vadose zone (> 30 m). Results from four years of continuous measurements showed quick rises in sediment water content following rain events and temporal wastewater overflows. The percolation pattern indicated dominance of preferential flow through a desiccation-cracks network crossing the entire clay sediment layer. High water-propagation velocities (0.4 - 23.6 m h-1) were observed, indicating that the desiccation-crack network remains open and serves as a preferential flow pathway year-round, even at high sediment water content (~0.50 m3 m-3). The rapid percolation bypassed the most bio-geo-active parts of the soil, transporting even highly sorptive contaminants (testosterone and estrogen) in to the deep sections of the vadose zone, accelerating the underlying groundwater contamination. The ammonium and nitrate concentrations in the vadose zone and the high number of nitrifying and denitrifying bacteria (~108 gene copies gdry-sediemt-1, each) found in the sediment indicated that the entire vadose zone is aerated even at high water content conditions (~0.55 m3 m-3). The dissolved salts concentration in the pore-water and the δ2H-H2O and δ18O-H2O values of the pore-water substantially increased with depth (becoming less depleted) in the clay sediment

  8. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2011-01-01

    The article discusses the latest developments in the global common clay and shale industry, particularly in the U.S. It claims that common clay and shale is mainly used in the manufacture of heavy clay products like brick, flue tile and sewer pipe. The main producing states in the U.S. include North Carolina, New York and Oklahoma. Among the firms that manufacture clay and shale-based products are Mid America Brick & Structural Clay Products LLC and Boral USA.

  9. Microstructures and deformation mechanisms in Opalinus Clay: insights from scaly clay from the Main Fault in the Mont Terri Rock Laboratory (CH)

    NASA Astrophysics Data System (ADS)

    Laurich, Ben; Urai, Janos L.; Nussbaum, Christophe

    2017-01-01

    The Main Fault in the shaly facies of Opalinus Clay is a small reverse fault formed in slightly overconsolidated claystone at around 1 km depth. The fault zone is up to 6 m wide, with micron-thick shear zones, calcite and celestite veins, scaly clay and clay gouge. Scaly clay occurs in up to 1.5 m wide lenses, providing hand specimens for this study. We mapped the scaly clay fabric at 1 m-10 nm scale, examining scaly clay for the first time using broad-ion beam polishing combined with scanning electron microscopy (BIB-SEM). Results show a network of thin shear zones and microveins, separating angular to lensoid microlithons between 10 cm and 10 µm in diameter, with slickensided surfaces. Our results show that microlithons are only weakly deformed and that strain is accumulated by fragmentation of microlithons by newly formed shear zones, by shearing in the micron-thick zones and by rearrangement of the microlithons.The scaly clay aggregates can be easily disintegrated into individual microlithons because of the very low tensile strength of the thin shear zones. Analyses of the microlithon size by sieving indicate a power-law distribution model with exponents just above 2. From this, we estimate that only 1 vol % of the scaly clay aggregate is in the shear zones.After a literature review of the hypotheses for scaly clay generation, we present a new model to explain the progressive formation of a self-similar network of anastomosing thin shear zones in a fault relay. The relay provides the necessary boundary conditions for macroscopically continuous deformation. Localization of strain in thin shear zones which are locally dilatant, and precipitation of calcite veins in dilatant shear fractures, evolve into complex microscale re-partitioning of shear, forming new shear zones while the microlithons remain much less deformed internally and the volume proportion of the µm-thick shear zones slowly increases. Grain-scale deformation mechanisms are microfracturing

  10. Comprehensive review of geosynthetic clay liner and compacted clay liner

    NASA Astrophysics Data System (ADS)

    Shankar, M. Uma; Muthukumar, M.

    2017-11-01

    Human activity inevitably produces waste materials that must be managed. Some waste can be reused. However many wastes that cannot be used beneficially must be disposed of ensuring environmental safety. One of the common methods of disposal is landfilling. The most common problems of the landfill site are environmental degradation and groundwater contamination caused by leachate produced during the decomposition process of organic material and rainfall. Liner in a landfill is an important component which prevent leachate migration and prevent groundwater contamination. Earthen liners have been widely used to contain waste materials in landfill. Liners and covers for municipal and hazardous waste containment facilities are often constructed with the use of fine-grained, low plasticity soils. Because of low permeability geosynthetic clay liners and compacted clay liners are the main materials used in waste disposal landfills. This paper summaries the important geotechnical characteristics such as hydraulic conductivity, liquid limit and free swell index of geosynthetic clay liner and compacted clay liner based on research findings. This paper also compares geosynthetic clay liner and compacted clay liner based on certain criteria such as thickness, availability of materials, vulnerability to damage etc.

  11. Preliminary work about the reproduction of sonic boom signals for perception studies

    NASA Astrophysics Data System (ADS)

    Epain, N.; Herzog, P.; Rabau, G.; Friot, E.

    2006-05-01

    As part of a French research program, a sound restitution cabin was designed for investigating the annoyance of sonic boom signals. The first goal was to reproduce the boom spectrum and temporal waveform: this required linear generation of high pressure levels at infrasonic frequencies (110 SPL dB around 3 Hz), and response equalization over the full frequency range (1 Hz-20 kHz). At this stage the pressure inside the cabin was almost uniform around the listener, emulating an outdoor situation. A psychoacoustic study was then conducted which confirmed that the loudness (related to annoyance) of N-waves is roughly governed by the peak pressure, the rise/fall time, and the wave duration. A longer-term goal is to reproduce other aspects of an indoor situation including rattle noise, ground vibrations, and a more realistic spatial repartition of pressure. This latter point has been addressed through an Active Noise Control study aiming at monitoring the low-frequency acoustic pressure on a surface enclosing a listener. Frequency and time-domain numerical simulations of boom reproduction via ANC are given, including a sensitivity study of the coupling between a listener's head and the incident boom wave which combine into the effective sound-field to be reproduced.

  12. Clay Minerals

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mueller, Karl T.; Sanders, Rebecca L.; Washton, Nancy M.

    2014-03-14

    Clay minerals are important components of the environment and are involved or implicated in processes such as the uptake of pollutants and the release of nutrients and as potential platforms for a number of chemical reactions. Owing to their small particle sizes (typically, on the order of microns or smaller) and mixing with a variety of other minerals and soil components, advanced characterization methods are needed to study their structures, dynamics, and reactivities. In this article, we describe the use of solid-state NMR methods to characterize the structures and chemistries of clay minerals. Early one-pulse magic-angle spinning (MAS) NMR studiesmore » of 27Al and 29Si have now been enhanced and extended with new studies utilizing advanced methodologies (such as Multiple Quantum MAS) as well as studies of less-sensitive nuclei. In additional work, the issue of reactivity of clay minerals has been addressed, including studies of reactive surface area in the environment. Utilizations of NMR-sensitive nuclides within the clay minerals themselves, and in molecules that react with specific sites on the clay mineral surfaces, have aided in understanding the reactivity of these complex aluminosilicate systems.« less

  13. The marriage boom and marriage bust in the United States: An age-period-cohort analysis.

    PubMed

    Schellekens, Jona

    2017-03-01

    In the 1950s and 1960s there was an unprecedented marriage boom in the United States. This was followed in the 1970s by a marriage bust. Some argue that both phenomena are cohort effects, while others argue that they are period effects. The study reported here tested the major period and cohort theories of the marriage boom and bust, by estimating an age-period-cohort model of first marriage for the years 1925-79 using census microdata. The results of the analysis indicate that the marriage boom was mostly a period effect, although there were also cohort influences. More specifically, the hypothesis that the marriage boom was mostly a response to rising wages is shown to be consistent with the data. However, much of the marriage bust can be accounted for by unidentified cohort influences, at least until 1980.

  14. Sonic boom effect on fish: Observations

    NASA Technical Reports Server (NTRS)

    Wilkins, M. E.

    1972-01-01

    Motion pictures of fish in a small tank at the time a bullet traveling 1200 m/sec passes a few centimeters above indicate that fish sense the passage of the shock wave but suffer no ill effects. The pressure rise at the bow shock wave was 0.26 atm or 275 times that associated with a strong sonic boom, for example, from the proposed supersonic transport.

  15. Low Boom Flight Demonstrator Briefing

    NASA Image and Video Library

    2018-04-03

    Dave Richardson, director, Air Vehicle Design and Technologies, Lockheed Martin Skunk Works, speaks after the announcement that Lockheed Martin won the contract to develop the first X-plane at a briefing, Tuesday, April 3, 2018 at NASA Headquarters in Washington. This new experimental aircraft will cut cross country travel times in half by flying faster than the speed of sound without creating a sonic boom, enabling travel from New York to Los Angeles in two hours. Photo Credit: (NASA/Aubrey Gemignani)

  16. Imprinted Clay Coil Vessels

    ERIC Educational Resources Information Center

    Lohr, Tresa Rae

    2006-01-01

    The author teaches clay vessel construction in the fifth grade, and it is amazing what can be accomplished in one forty-five minute period when the expectations are clarified in the initial lesson. The author introduces clay coil vessels with a discussion of the sources of clay and how clay relates to fifth-grade science curriculum concepts such…

  17. Offshore energy boom providing opportunities outside Medicare's umbrella.

    PubMed

    Robb, N

    1998-09-08

    Physicians upset by limits imposed by the medicare system are getting a chance to spread their entrepreneurial wings on the East Coast. A boom in offshore exploration, led by Newfoundland's massive Hibernia project, has led to numerous business opportunities for physicians.

  18. NASA's F-15B testbed aircraft with Gulfstream Quiet Spike sonic boom mitigator attached

    NASA Image and Video Library

    2006-07-06

    Gulfstream Aerospace and NASA's Dryden Flight Research Center are testing the structural integrity of a telescopic 'Quiet Spike' sonic boom mitigator on the F-15B testbed. The Quiet Spike was developed as a means of controlling and reducing the sonic boom caused by an aircraft 'breaking' the sound barrier.

  19. 30 CFR 77.807-2 - Booms and masts; minimum distance from high-voltage lines.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...-voltage lines. 77.807-2 Section 77.807-2 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION... WORK AREAS OF UNDERGROUND COAL MINES Surface High-Voltage Distribution § 77.807-2 Booms and masts; minimum distance from high-voltage lines. The booms and masts of equipment operated on the surface of any...

  20. Modified Linear Theory Aircraft Design Tools and Sonic Boom Minimization Strategy Applied to Signature Freezing via F-function Lobe Balancing

    NASA Astrophysics Data System (ADS)

    Jung, Timothy Paul

    Commercial supersonic travel has strong business potential; however, in order for the Federal Aviation Administration to lift its ban on supersonic flight overland, designers must reduce aircraft sonic boom strength to an acceptable level. An efficient methodology and associated tools for designing aircraft for minimized sonic booms are presented. The computer-based preliminary design tool, RapidF, based on modified linear theory, enables quick assessment of an aircraft's sonic boom with run times less than 30 seconds on a desktop computer. A unique feature of RapidF is that it tracks where on the aircraft each segment of the of the sonic boom came from, enabling precise modifications, speeding the design process. Sonic booms from RapidF are compared to flight test data, showing that it is capability of predicting a sonic boom duration, overpressure, and interior shock locations. After the preliminary design is complete, scaled flight tests should be conducted to validate the low boom design. When conducting such tests, it is insufficient to just scale the length; thus, equations to scale the weight and propagation distance are derived. Using RapidF, a conceptual supersonic business jet design is presented that uses F-function lobe balancing to create a frozen sonic boom using lifting surfaces. The leading shock is reduced from 1.4 to 0.83 psf, and the trailing shock from 1.2 to 0.87 psf, 41% and 28% reductions respectfully. By changing the incidence angle of the surfaces, different sonic boom shapes can be created, and allowing the lobes to be re-balanced for new flight conditions. Computational fluid dynamics is conducted to validate the sonic boom predictions. Off-design analysis is presented that varies weight, altitude, Mach number, and propagation angle, demonstrating that lobe-balance is robust. Finally, the Perceived Level of Loudness metric is analyzed, resulting in a modified design that incorporates other boom minimization techniques to further reduce

  1. Uncertainty Analysis of Sonic Boom Levels Measured in a Simulator at NASA Langley

    NASA Technical Reports Server (NTRS)

    Rathsam, Jonathan; Ely, Jeffry W.

    2012-01-01

    A sonic boom simulator has been constructed at NASA Langley Research Center for testing the human response to sonic booms heard indoors. Like all measured quantities, sonic boom levels in the simulator are subject to systematic and random errors. To quantify these errors, and their net influence on the measurement result, a formal uncertainty analysis is conducted. Knowledge of the measurement uncertainty, or range of values attributable to the quantity being measured, enables reliable comparisons among measurements at different locations in the simulator as well as comparisons with field data or laboratory data from other simulators. The analysis reported here accounts for acoustic excitation from two sets of loudspeakers: one loudspeaker set at the facility exterior that reproduces the exterior sonic boom waveform and a second set of interior loudspeakers for reproducing indoor rattle sounds. The analysis also addresses the effect of pressure fluctuations generated when exterior doors of the building housing the simulator are opened. An uncertainty budget is assembled to document each uncertainty component, its sensitivity coefficient, and the combined standard uncertainty. The latter quantity will be reported alongside measurement results in future research reports to indicate data reliability.

  2. Influence of Alkali Resistant (Ar) Fibreglass in Porcelain Clay for Manufacturing Vitrified Clay Pipes

    NASA Astrophysics Data System (ADS)

    Ikhmal Hanapi, Muhammad; Ahmad, Sufizar; Taib, Hariati; Ismail, Al Emran; Nasrull Abdol Rahman, Mohd; Salleh, Salihatun Md; Sadikin, Azmahani; Mahzan, Shahruddin

    2017-10-01

    The aim of this work is to determine the characteristics of porcelain ceramic with influence of milled Alkali Resistant (AR) fiberglass for manufacturing vitrified clay pipes. In this study, raw materials consist of porcelain clay and AR fiberglass were refined into powders less than 90μm. Subsequently, these samples were compacted into cylindrical pellet for chemical analysis using X-Ray Fluorescence (XRF). The ceramic sample was produced by mixing different weight percentage of AR glass to porcelain ceramic with 3 wt%, 6 wt%, 9 wt% and 12 wt%. Subsequently, the sample was compacted with 3 ton of pressure load and sintered at 900 °C, 1000 °C, 1100 °C and 1200 °C. The phase identification by using X-Ray Diffraction (XRD) and microstructural analysis were performed for the sintered sample. Chemical analysis revealed that the significant element for all raw material are SiO2, Al2O3, Na2O and K2O. Phase identification analysis shown that sample sintered at 1000 °C produces quartz (SiO2), berlinite (AlPO4), albite (NaAlSi3O8) and calcium-magnesium-aluminum-silicate (CaMgAlSiO). The formation of primary mullite was observed in sample sintered at 1100 °C. The image of microstructural morphology denoted that the formation of glassy phase with decreasing amount of void when sintering temperature and addition of AR glass were increased, which correspond well to phase identification analysis.

  3. Aqueous clay suspensions stabilized by alginate fluid gels for coal spontaneous combustion prevention and control.

    PubMed

    Qin, Botao; Ma, Dong; Li, Fanglei; Li, Yong

    2017-11-01

    We have developed aqueous clay suspensions stabilized by alginate fluid gels (AFG) for coal spontaneous combustion prevention and control. Specially, this study aimed to characterize the effect of AFG on the microstructure, static and dynamic stability, and coal fire inhibition performances of the prepared AFG-stabilized clay suspensions. Compared with aqueous clay suspensions, the AFG-stabilized clay suspensions manifest high static and dynamic stability, which can be ascribed to the formation of a robust three-dimensional gel network by AFG. The coal acceleration oxidation experimental results show that the prepared AFG-stabilized clay suspensions can improve the coal thermal stability and effectively inhibit the coal spontaneous oxidation process by increasing crossing point temperature (CPT) and reducing CO emission. The prepared low-cost and nontoxic AFG-stabilized clay suspensions, exhibiting excellent coal fire extinguishing performances, indicate great application potentials in coal spontaneous combustion prevention and control.

  4. Design of Experiments for Both Experimental and Analytical Study of Exhaust Plume Effects on Sonic Boom

    NASA Technical Reports Server (NTRS)

    Castner, Raymond S.

    2009-01-01

    Computational fluid dynamics (CFD) analysis has been performed to study the plume effects on sonic boom signature for isolated nozzle configurations. The objectives of these analyses were to provide comparison to past work using modern CFD analysis tools, to investigate the differences of high aspect ratio nozzles to circular (axisymmetric) nozzles, and to report the effects of under expanded nozzle operation on boom signature. CFD analysis was used to address the plume effects on sonic boom signature from a baseline exhaust nozzle. Nearfield pressure signatures were collected for nozzle pressure ratios (NPRs) between 6 and 10. A computer code was used to extrapolate these signatures to a ground-observed sonic boom N-wave. Trends show that there is a reduction in sonic boom N-wave signature as NPR is increased from 6 to 10. As low boom designs are developed and improved, there will be a need for understanding the interaction between the aircraft boat tail shocks and the exhaust nozzle plume. These CFD analyses will provide a baseline study for future analysis efforts. For further study, a design of experiments has been conducted to develop a hybrid method where both CFD and small scale wind tunnel testing will validate the observed trends. The CFD and testing will be used to screen a number of factors which are important to low boom propulsion integration, including boat tail angle, nozzle geometry, and the effect of spacing and stagger on nozzle pairs. To design the wind tunnel experiment, CFD was instrumental in developing a model which would provide adequate space to observe the nozzle and boat tail shock structure without interference from the wind tunnel walls.

  5. In situ synthesis, characterization, and catalytic performance of tungstophosphoric acid encapsulated into the framework of mesoporous silica pillared clay.

    PubMed

    Li, Baoshan; Liu, Zhenxing; Han, Chunying; Ma, Wei; Zhao, Songjie

    2012-07-01

    Mesoporous silica pillared clay (SPC) incorporated with tungstophosphoric acid (HPW) has been synthesized via in situ introducing P and W source in the acidic suspension of the clay interlayer template during the formation of the silica pillared clay. The samples were characterized by XRD, XRF, FT-IR, TG-DTA, N(2) adsorption-desorption, and SEM techniques. The results showed that the HPW formed by in situ method has been effectively introduced into the framework of mesoporous silica pillared clay and its Keggin structure remained perfectly after formation of the materials. In addition, samples with similar HPW loadings were also prepared by impregnation method using SPC as the support. HPW in the incorporated samples was better dispersed into the silica pillared clay than in the impregnated samples. The results of catalytic tests indicated that the encapsulated materials demonstrated better catalytic performance than the impregnated samples in oxidative desulfurization (ODS) of dibenzothiophene (DBT). Copyright © 2012 Elsevier Inc. All rights reserved.

  6. Integration of Engine, Plume, and CFD Analyses in Conceptual Design of Low-Boom Supersonic Aircraft

    NASA Technical Reports Server (NTRS)

    Li, Wu; Campbell, Richard; Geiselhart, Karl; Shields, Elwood; Nayani, Sudheer; Shenoy, Rajiv

    2009-01-01

    This paper documents an integration of engine, plume, and computational fluid dynamics (CFD) analyses in the conceptual design of low-boom supersonic aircraft, using a variable fidelity approach. In particular, the Numerical Propulsion Simulation System (NPSS) is used for propulsion system cycle analysis and nacelle outer mold line definition, and a low-fidelity plume model is developed for plume shape prediction based on NPSS engine data and nacelle geometry. This model provides a capability for the conceptual design of low-boom supersonic aircraft that accounts for plume effects. Then a newly developed process for automated CFD analysis is presented for CFD-based plume and boom analyses of the conceptual geometry. Five test cases are used to demonstrate the integrated engine, plume, and CFD analysis process based on a variable fidelity approach, as well as the feasibility of the automated CFD plume and boom analysis capability.

  7. Slot Nozzle Effects for Reduced Sonic Boom on a Generic Supersonic Wing Section

    NASA Technical Reports Server (NTRS)

    Caster, Raymond S.

    2010-01-01

    NASA has conducted research programs to reduce or eliminate the operational restrictions of supersonic aircraft over populated areas. Restrictions are due to the disturbance from the sonic boom, caused by the coalescence of shock waves formed off the aircraft. Results from two-dimensional computational fluid dynamic (CFD) analyses (performed on a baseline Mach 2.0 nozzle in a simulated Mach 2.2 flow) indicate that over-expanded and under-expanded operation of the nozzle has an effect on the N-wave boom signature. Analyses demonstrate the feasibility of reducing the magnitude of the sonic boom N-wave by controlling the nozzle plume interaction with the nozzle boat tail shock structure. This work was extended to study the impact of integrating a high aspect ratio exhaust nozzle or long slot nozzle on the trailing edge of a supersonic wing. The nozzle is operated in a highly under-expanded condition, creating a large exhaust plume and a shock at the trailing edge of the wing. This shock interacts with and suppresses the expansion wave caused by the wing, a major contributor to the sonic boom signature. The goal was to reduce the near field pressures caused by the expansion using a slot nozzle located at the wing trailing edge. Results from CFD analysis on a simulated wing cross-section and a slot nozzle indicate potential reductions in sonic boom signature compared to a baseline wing with no propulsion or trailing edge exhaust. Future studies could investigate if this effect could be useful on a supersonic aircraft for main propulsion, auxiliary propulsion, or flow control.

  8. Offshore energy boom providing opportunities outside medicare's umbrella

    PubMed Central

    Robb, N

    1998-01-01

    Physicians upset by limits imposed by the medicare system are getting a chance to spread their entrepreneurial wings on the East Coast. A boom in offshore exploration, led by Newfoundland's massive Hibernia project, has led to numerous business opportunities for physicians. PMID:9757185

  9. Multiscale Micromechanical Modeling of Polymer/Clay Nanocomposites and the Effective Clay Particle

    NASA Astrophysics Data System (ADS)

    Sheng, Nuo; Boyce, Mary C.; Parks, David M.; Manovitch, Oleg; Rutledge, Gregory C.; Lee, Hojun; McKinley, Gareth H.

    2003-03-01

    Polymer/clay nanocomposites have been observed to exhibit enhanced mechanical properties at low weight fractions (Wp) of clay. Continuum-based composite modeling reveals that the enhanced properties are strongly dependent on particular features of the second-phase ¡°particles¡+/-; in particular, the particle volume fraction (fp), the particle aspect ratio (L/t), and the ratio of particle mechanical properties to those of the matrix. However, these important aspects of as-processed nanoclay composites have yet to be consistently and accurately defined. A multiscale modeling strategy was developed to account for the hierarchical morphology of the nanocomposite: at a lengthscale of thousands of microns, the structure is one of high aspect ratio particles within a matrix; at the lengthscale of microns, the clay particle structure is either (a) exfoliated clay sheets of nanometer level thickness or (b) stacks of parallel clay sheets separated from one another by interlayer galleries of nanometer level height. Here, quantitative structural parameters extracted from XRD patterns and TEM micrographs are used to determine geometric features of the as-processed clay ¡°particles¡+/-, including L/t and the ratio of fp to Wp. These geometric features, together with estimates of silicate lamina stiffness obtained from molecular dynamics simulations, provide a basis for modeling effective mechanical properties of the clay particle. The structure-based predictions of the macroscopic elastic modulus of the nanocomposite as a function of clay weight fraction are in excellent agreement with experimental data. The adopted methodology offers promise for study of related properties in polymer/clay nanocomposites.

  10. The research and application of electricity economic boom model under the constraint of energy conservation and emission reduction

    NASA Astrophysics Data System (ADS)

    Chen, Guangyan; Xia, Huaijian; Chen, Meiling; Wang, Dong; Jia, Sujin

    2017-10-01

    Energy saving and emission reduction policies affects the development of high power industry, thereby affecting electricity demand, so the study of the electricity industry boom helps to master the national economy. This paper analyses the influence of energy saving and emission reduction on power generation structure and pollutant emission in power industry. Through the construction of electricity market composite boom index to indicate electricity boom, using boom index to study volatility characteristics and trend of electricity market. Here we provide a method for the enterprise and the government, that it can infer the overall operation of the national economy situation from power data.

  11. 2,3,7,8-DIBENZO-P-DIOXINS IN MINED CLAY PRODUCTS ...

    EPA Pesticide Factsheets

    Ball clay was the source of dioxin contamination discovered in selected chickens analyzed as part of a joint U.S. Department of Agriculture/U.S. Environmental Protection Agency national survey of the U.S. poultry supply conducted in 1997. The affected animals, which had been raised in the southern United States, represented approximately 5% of the national poultry production . All of these chickens and other animal food sources (i.e., farm-raised catfish), similarly contaminated, were fed a diet of animal feed containing ball clay as an anti-caking additive. The clay was mined in northwestern Mississippi within a geological formation referred to as the Mississippi Embayment. Individual raw and processed ball clay samples were analyzed for the presence of the 2,3,7,8-PCDDs/PCDFs. The average toxic equivalents (TEQs) for the raw and processed samples were 1513 and 996 ppt dry weight, respectively. Other mined clay-based products used in animal feeds revealed lower TEQs. All of the products exhibited either an absence of detectable concentrations of 2,3,7,8-PCDFs or concentrations 2-3 orders of magnitude lower than the PCDDs. The isomer distribution, specific isomer identification, and congener profile of the PCDDs in the clay were established and compared to known sources of dioxin contamination. Several unique features of this isomer distribution are characteristic of the clays and are distinguishable from those other known sources. These characteristic

  12. Relaxation and turbulence effects on sonic boom signatures

    NASA Technical Reports Server (NTRS)

    Pierce, Allan D.; Sparrow, Victor W.

    1992-01-01

    The rudimentary theory of sonic booms predicts that the pressure signatures received at the ground begin with an abrupt shock, such that the overpressure is nearly abrupt. This discontinuity actually has some structure, and a finite time is required for the waveform to reach its peak value. This portion of the waveform is here termed the rise phase, and it is with this portion that this presentation is primarily concerned. Any time characterizing the duration of the rise phase is loosely called the 'rise time.' Various definitions are used in the literature for this rise time. In the present discussion the rise time can be taken as the time for the waveform to rise from 10 percent of its peak value to 90 percent of its peak value. The available data on sonic booms that appears in the open literature suggests that typical values of shock over-pressure lie in the range of 30 Pa to 200 Pa, typical values of shock duration lie in the range of 150 ms to 250 ms, and typical values of the rise time lie in the range of 1 ms to 5 ms. The understanding of the rise phase of sonic booms is important because the perceived loudness of a shock depends primarily on the structure of the rise phase. A longer rise time typically implies a less loud shock. A primary question is just what physical mechanisms are most important for the determination of the detailed structure of the rise phase.

  13. Rural North Dakota's oil boom and its impact on social services.

    PubMed

    Weber, Bret A; Geigle, Julia; Barkdull, Carenlee

    2014-01-01

    Over the last five years, North Dakota has experienced an oil boom based on high oil prices and hydraulic fracturing technologies. This has brought economic expansion and population growth to rural communities that had previously experienced decades of depopulation and economic struggle. Although the state has enjoyed many benefits--especially in juxtaposition to a sluggish national economy--the boom has also meant the arrival of economic refugees and dramatic impacts on largely rural social service systems. In the midst of a rapidly changing situation, available information tends to swing between euphoria over economic success and hysteria about rising crime and shifting cultures. In response, the authors used a primary focus group with county social service directors from across the state and a followup focus group with social workers operating on the edge of oil activity. Grounded in resilience theory, qualitative analysis of the primary focus group, and triangulation of data from other sources, this study provides a more objective report of the housing and social challenges, the benefits of the boom, and the challenges to solutions.

  14. Clay: The Forgotten Art.

    ERIC Educational Resources Information Center

    Martin, Doris Marie

    1995-01-01

    Discusses the tactile and kinesthetic areas of learning children experience when using clay. Includes practical tips for using and storing clay for preschool use and notes the differences between potters' clay and play dough. (HTH)

  15. Influence of Polymer-Clay Interfacial Interactions on the Ignition Time of Polymer/Clay Nanocomposites

    PubMed Central

    Zope, Indraneel S.; Yu, Zhong-Zhen

    2017-01-01

    Metal ions present on smectite clay (montmorillonite) platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 (PA6) thermal decomposition. This changes the decomposition pathway and negatively affects the ignition response of PA6. To restrict these interfacial interactions, high-temperature-resistant polymers such as polyetherimide (PEI) and polyimide (PI) were used to coat clay layers. PEI was deposited on clay by solution-precipitation, whereas PI was deposited through a solution-imidization-precipitation technique before melt blending with PA6. The absence of polymer-clay interfacial interactions has resulted in a similar time-to-ignition of PA6/PEI-clay (133 s) and PA6/PI-clay (139 s) composites as neat PA6 (140 s). On the contrary, PA6 with conventional ammonium-based surfactant modified clay has showed a huge drop in time-to-ignition (81 s), as expected. The experimental evidences provided herein reveal the role of the catalytic activity of clay during the early stages of polymer decomposition. PMID:28800095

  16. Influence of Polymer-Clay Interfacial Interactions on the Ignition Time of Polymer/Clay Nanocomposites.

    PubMed

    Zope, Indraneel S; Dasari, Aravind; Yu, Zhong-Zhen

    2017-08-11

    Metal ions present on smectite clay (montmorillonite) platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 (PA6) thermal decomposition. This changes the decomposition pathway and negatively affects the ignition response of PA6. To restrict these interfacial interactions, high-temperature-resistant polymers such as polyetherimide (PEI) and polyimide (PI) were used to coat clay layers. PEI was deposited on clay by solution-precipitation, whereas PI was deposited through a solution-imidization-precipitation technique before melt blending with PA6. The absence of polymer-clay interfacial interactions has resulted in a similar time-to-ignition of PA6/PEI-clay (133 s) and PA6/PI-clay (139 s) composites as neat PA6 (140 s). On the contrary, PA6 with conventional ammonium-based surfactant modified clay has showed a huge drop in time-to-ignition (81 s), as expected. The experimental evidences provided herein reveal the role of the catalytic activity of clay during the early stages of polymer decomposition.

  17. Environmental Pollution: Noise Pollution - Sonic Boom. Volume I.

    ERIC Educational Resources Information Center

    Defense Documentation Center, Alexandria, VA.

    The unclassified, annotated bibliography is Volume I of a two-volume set on Noise Pollution - Sonic Boom in a series of scheduled bibliographies on Environmental Pollution. Volume II is Confidential. Corporate author-monitoring agency, subject, title, contract, and report number indexes are included. (Author/JR)

  18. Infrared analysis of clay bricks incorporated with spent shea waste from the shea butter industry.

    PubMed

    Adazabra, A N; Viruthagiri, G; Shanmugam, N

    2017-04-15

    The peculiar challenge of effective disposing abundant spent shea waste and the excellent compositional variation tolerance of clay material offered an impetus to examine the incorporation of spent shea waste into clay material as an eco-friendly disposal route in making clay bricks. For this purpose, the chemical constituent, mineralogical compositions and thermal behavior of both clay material and spent shea waste were initially characterized from which modelled brick specimens incorporating 5-20 wt% of the waste into the clay material were prepared. The clay material showed high proportions of SiO 2 (52.97 wt%) and Al 2 O 3 (27.10 wt%) indicating their rich kaolinitic content: whereas, the inert nature of spent shea waste was exhibited by their low oxide content. The striking similarities in infrared absorption bands of pristine clay material and clay materials incorporated with 15 wt% of spent shea waste showed that the waste incorporation had no impact on bond formation of the clay bricks. Potential performance benefits of developing bricks from clay material incorporated with spent shea waste included improved fluxing agents, economic sintering and making of sustainable bricks. Consequently, the analytical results authenticate the incorporation of spent shea waste into clay materials for various desired benefits aside being an environmental correct route of its disposal. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Construction Boom Seen on Campuses over Next 5 Years.

    ERIC Educational Resources Information Center

    Evangelauf, Jean

    1987-01-01

    Campus construction is projected to boom as colleges and universities catch up on deferred maintenance and replace outdated classrooms and laboratories. Severe problems identified include roofs, heating systems, asbestos removal, and electical systems. (LB)

  20. Exploring biotic vs. abiotic controls on syngenetic carbonate and clay mineral precipitation

    NASA Astrophysics Data System (ADS)

    Nascimento, Gabriela S.; McKenzie, Judith A.; Martinez Ruiz, Francisca; Bontognali, Tomaso R. R.; Vasconcelos, Crisogono

    2016-04-01

    A possible syngenetic relationship between carbonate and clay mineral precipitation has been reported for sedimentary rocks deposited in both lacustrine and marine sedimentary environments throughout the geological record. In particular, the mineral dolomite is often found associated with Mg-rich clays, such as stevensite. It is notable that this carbonate/clay association has been recorded in numerous samples taken from modern dolomite precipitating environments; for example, the Coorong lakes, South Australia, coastal sabkhas, Abu Dhabi, UAE and coastal hypersaline lagoons (Lagoa Vermelha and Brejo do Espinho) east of Rio de Janeiro, Brazil. An HRTEM study of samples from these three locations indicates a possible physical/chemical association between the Ca-dolomite and Mg-rich clays, demonstrating a probable co-precipitation. To test this hypothesis, we have conducted a series of biotic and abiotic laboratory experiments. If this syngenesis actually occurs in nature, what, if any, are the biogeochemical processes controlling these precipitation reactions? Our experiments were designed to determine the extent of the biotic versus abiotic component influencing the mineral precipitation and, in the case of a biotic influence, to understand the mechanism through which microorganisms might mediate the formation of clay minerals. The experiments were carried out in the Geomicrobiology Laboratory of ETH Zürich using cultures of living microbes and artificial organic compounds that simulate functional groups present in natural biofilms formed under both aerobic and anaerobic conditions. In addition, pure inorganic experiments were designed to understand possible physico-chemical conditions for diagenetic processes that could induce dissolution of Mg-carbonates and precipitation of Mg-rich clays. Our results show a remarkable biotic influence during the formation of clay minerals. Specifically, extracellular polymeric substances (EPS), released by microbes in their

  1. Enhanced cellular preservation by clay minerals in 1 billion-year-old lakes.

    PubMed

    Wacey, David; Saunders, Martin; Roberts, Malcolm; Menon, Sarath; Green, Leonard; Kong, Charlie; Culwick, Timothy; Strother, Paul; Brasier, Martin D

    2014-07-28

    Organic-walled microfossils provide the best insights into the composition and evolution of the biosphere through the first 80 percent of Earth history. The mechanism of microfossil preservation affects the quality of biological information retained and informs understanding of early Earth palaeo-environments. We here show that 1 billion-year-old microfossils from the non-marine Torridon Group are remarkably preserved by a combination of clay minerals and phosphate, with clay minerals providing the highest fidelity of preservation. Fe-rich clay mostly occurs in narrow zones in contact with cellular material and is interpreted as an early microbially-mediated phase enclosing and replacing the most labile biological material. K-rich clay occurs within and exterior to cell envelopes, forming where the supply of Fe had been exhausted. Clay minerals inter-finger with calcium phosphate that co-precipitated with the clays in the sub-oxic zone of the lake sediments. This type of preservation was favoured in sulfate-poor environments where Fe-silicate precipitation could outcompete Fe-sulfide formation. This work shows that clay minerals can provide an exceptionally high fidelity of microfossil preservation and extends the known geological range of this fossilization style by almost 500 Ma. It also suggests that the best-preserved microfossils of this time may be found in low-sulfate environments.

  2. Enhanced cellular preservation by clay minerals in 1 billion-year-old lakes

    PubMed Central

    Wacey, David; Saunders, Martin; Roberts, Malcolm; Menon, Sarath; Green, Leonard; Kong, Charlie; Culwick, Timothy; Strother, Paul; Brasier, Martin D.

    2014-01-01

    Organic-walled microfossils provide the best insights into the composition and evolution of the biosphere through the first 80 percent of Earth history. The mechanism of microfossil preservation affects the quality of biological information retained and informs understanding of early Earth palaeo-environments. We here show that 1 billion-year-old microfossils from the non-marine Torridon Group are remarkably preserved by a combination of clay minerals and phosphate, with clay minerals providing the highest fidelity of preservation. Fe-rich clay mostly occurs in narrow zones in contact with cellular material and is interpreted as an early microbially-mediated phase enclosing and replacing the most labile biological material. K-rich clay occurs within and exterior to cell envelopes, forming where the supply of Fe had been exhausted. Clay minerals inter-finger with calcium phosphate that co-precipitated with the clays in the sub-oxic zone of the lake sediments. This type of preservation was favoured in sulfate-poor environments where Fe-silicate precipitation could outcompete Fe-sulfide formation. This work shows that clay minerals can provide an exceptionally high fidelity of microfossil preservation and extends the known geological range of this fossilization style by almost 500 Ma. It also suggests that the best-preserved microfossils of this time may be found in low-sulfate environments. PMID:25068404

  3. A study of the limitations of linear theory methods as applied to sonic boom calculations

    NASA Technical Reports Server (NTRS)

    Darden, Christine M.

    1990-01-01

    Current sonic boom minimization theories have been reviewed to emphasize the capabilities and flexibilities of the methods. Flexibility is important because it is necessary for the designer to meet optimized area constraints while reducing the impact on vehicle aerodynamic performance. Preliminary comparisons of sonic booms predicted for two Mach 3 concepts illustrate the benefits of shaping. Finally, for very simple bodies of revolution, sonic boom predictions were made using two methods - a modified linear theory method and a nonlinear method - for signature shapes which were both farfield N-waves and midfield waves. Preliminary analysis on these simple bodies verified that current modified linear theory prediction methods become inadequate for predicting midfield signatures for Mach numbers above 3. The importance of impulse is sonic boom disturbance and the importance of three-dimensional effects which could not be simulated with the bodies of revolution will determine the validity of current modified linear theory methods in predicting midfield signatures at lower Mach numbers.

  4. Variability of measured sonic boom signatures. Volume 2: Data report

    NASA Technical Reports Server (NTRS)

    Elmer, K. R.; Joshi, M. C.

    1994-01-01

    Sonic boom signatures from two databases, the BOOMFILE and the XB-70, were analyzed in terms of C-weighted sound exposure level (CSEL), A-weighted sound exposure level (ASEL), and Stevens Mark VII perceived level (PLdB), as well as the more traditional peak positive overpressure and rise time. The variability of these parameters due to propagation through atmosphere was analyzed for different aircraft Mach number and altitude groups. The low Mach number/low altitude group had significantly greater variation in rise time, overpressure, and loudness level than the high Mach number/high altitude group. The loudness of measured booms were found to have a variation of up to 25 dB relative to the loudness of boom predicted for a non-turbulent atmosphere. This is due primarily to the steeper ray paths of the high Mach number/high altitude group and the corresponding shorter distances traveled by these rays through the lower atmosphere resulting in reduced refraction effects. The general trend of decreased overpressure and loudness level with increasing lateral distance was also seen. Sonic boom signatures from early morning flights had less variation in rise time and overpressure than afternoon flights because of reduced turbulence. Measures of asymmetry (difference between compression and expansion portion of the signature) showed that the variability in Delta loudness level was greater than the variability in Delta overpressure due to the large influence of turbulence on rise time. Lastly, analysis of data within 50 percent of lateral cutoff showed that the mean value for overpressure and loudness level was independent of time of day but that the frequency with which it occurred was greater in the morning. This is a clear indicator of increased turbulence in the afternoon.

  5. Analysis of Oligonucleotide DNA Binding and Sedimentation Properties of Montmorillonite Clay Using Ultraviolet Light Spectroscopy

    PubMed Central

    Beall, Gary W.; Sowersby, Drew S.; Roberts, Rachel D.; Robson, Michael H.; Lewis, L. Kevin

    2009-01-01

    Smectite clays such as montmorillonite form complexes with a variety of biomolecules, including the nucleic acids DNA and RNA. Most previous studies of DNA adsorption onto clay have relied upon spectrophotometric analysis after separation of free nucleic acids from bound complexes by centrifugation. In the current work we demonstrate that such studies produce a consistent error due to (a) incomplete sedimentation of montmorillonite and (b) strong absorbance of the remaining clay at 260 nm. Clay sedimentation efficiency was strongly dependent upon cation concentration (Na+ or Mg2+) and on the level of dispersion of the original suspension. An improved clay:DNA adsorption assay was developed and utilized to assess the impact of metal counterions on binding of single-stranded DNA to montmorillonite. X-ray diffraction demonstrated, for the first time, formation of intercalated structures consistent with orientation of the DNA strands parallel to the clay surface. Observed gallery spacings were found to closely match values calculated utilizing atomistic modeling techniques. PMID:19061334

  6. An investigation into the effect of playback environment on perception of sonic booms when heard indoors

    NASA Astrophysics Data System (ADS)

    Carr, Daniel; Davies, Patricia

    2015-10-01

    Aircraft manufacturers are interested in designing and building a new generation of supersonic aircraft that produce shaped sonic booms of lower peak amplitude than booms created by current supersonic aircraft. To determine if the noise exposure from these "low"booms is more acceptable to communities, new laboratory testing to evaluate people's responses must occur. To guide supersonic aircraft design, objective measures that predict human response to modified sonic boom waveforms and other impulsive sounds are needed. The present research phase is focused on understanding people's reactions to booms when heard inside, and therefore includes consideration of the effects of house type and the indoor acoustic environment. A test was conducted in NASA Langley's Interior Effects Room (IER), with the collaboration of NASA Langley engineers. This test was focused on the effects of low-frequency content and of vibration, and subjects sat in a small living room environment. A second test was conducted in a sound booth at Purdue University, using similar sounds played back over earphones. The sounds in this test contained less very-low-frequency energy due to limitations in the playback, and the laboratory setting is a less natural environment. For the purpose of comparison, and to improve the robustness of the model, both sonic booms and other more familiar transient sounds were used in the tests. The design of the tests and the signals are briefly described, and the results of both tests will be presented.

  7. Under-Track CFD-Based Shape Optimization for a Low-Boom Demonstrator Concept

    NASA Technical Reports Server (NTRS)

    Wintzer, Mathias; Ordaz, Irian; Fenbert, James W.

    2015-01-01

    The detailed outer mold line shaping of a Mach 1.6, demonstrator-sized low-boom concept is presented. Cruise trim is incorporated a priori as part of the shaping objective, using an equivalent-area-based approach. Design work is performed using a gradient-driven optimization framework that incorporates a three-dimensional, nonlinear flow solver, a parametric geometry modeler, and sensitivities derived using the adjoint method. The shaping effort is focused on reducing the under-track sonic boom level using an inverse design approach, while simultaneously satisfying the trim requirement. Conceptual-level geometric constraints are incorporated in the optimization process, including the internal layout of fuel tanks, landing gear, engine, and crew station. Details of the model parameterization and design process are documented for both flow-through and powered states, and the performance of these optimized vehicles presented in terms of inviscid L/D, trim state, pressures in the near-field and at the ground, and predicted sonic boom loudness.

  8. Ball clay

    USGS Publications Warehouse

    Virta, R.L.

    2012-01-01

    Four companies — H.C. Spinks Clay Co., Inc., Imerys Group, Old Hickory Clay Co., and Unimin Corp. — mined ball clay in four states in 2011. Production, on the basis of preliminary data, was 940 kt (1.04 million st) with an estimated value of $44.2 million. This is a 3-percent increase in tonnage from 912 kt (1.01 million st) with a value of $41.3 million that was produced in 2010. Tennessee was the leading producing state with 63 percent of domestic production, followed by Texas, Mississippi and Kentucky. About 69 percent of production was airfloat, 20 percent was crude and 11 percent was water-slurried.

  9. To what extent clay mineralogy affects soil aggregation? Consequences for soil organic matter stabilization

    NASA Astrophysics Data System (ADS)

    Fernandez-Ugalde, O.; Barré, P.; Hubert, F.; Virto, I.; Chenu, C.; Ferrage, E.; Caner, L.

    2012-12-01

    Aggregation is a key process for soil functioning as it influences C storage, vulnerability to erosion and water holding capacity. While the influence of soil organic C on aggregation has been documented, much less is known about the role of soil mineralogy. Soils usually contain a mixture of clay minerals with contrasted surface properties, which should result on different abilities of clay minerals to aggregation. We took advantage of the intrinsic mineral heterogeneity of a temperate Luvisol to compare the role of clay minerals (illite, smectite, kaolinite, and mixed-layer illite-smectite) in aggregation. In a first step, grassland and tilled soil samples were fractionated in water in aggregate-size classes according to the hierarchical model of aggregation (Tisdall and Oades, 1982). Clay mineralogy and organic C in the aggregate-size classes were analyzed. The results showed that interstratified minerals containing swelling phases accumulated in aggregated fractions (>2 μm) compared to free clay fractions (<2 μm) in the two land-uses. The accumulation increased from large macro-aggregates (>500 μm) to micro-aggregates (50-250 μm). C concentration and C/N ratio followed the opposite trend. These results constitute a clay mineral-based evidence for the hierarchical model of aggregation, which postulates an increasing importance of the reactivity of clay minerals in the formation of micro-aggregates compared to larger aggregates. In the latter aggregates, formation relies on the physical enmeshment of particles by fungal hyphae, and root and microbial exudates. In a second step, micro-aggregates from the tilled soil samples were submitted to increasingly disaggregating treatments by sonication to evaluate the link between their water stability and clay mineralogy. Micro-aggregates with increasing stability showed an increase of interstratified minerals containing swelling phases and C concentration for low intensities of disaggregation (from 0 to 5 J mL-1

  10. Gulfstream's Quiet Spike sonic boom mitigator being installed on NASA DFRC's F-15B testbed aircraft

    NASA Image and Video Library

    2006-04-17

    Gulfstream's Quiet Spike sonic boom mitigator being installed on NASA DFRC's F-15B testbed aircraft. The project seeks to verify the structural integrity of the multi-segmented, articulating spike attachment designed to reduce and control a sonic boom.

  11. Mach Cutoff Analysis and Results from NASA's Farfield Investigation of No-Boom Thresholds

    NASA Technical Reports Server (NTRS)

    Cliatt, Larry J., II; Hill, Michael A.; Haering, Edward A., Jr.

    2016-01-01

    In support of the ongoing effort by the National Aeronautics and Space Administration (NASA) to bring supersonic commercial travel to the public, the NASA Armstrong Flight Research Center and the NASA Langley Research Center, in partnership with other industry organizations and academia, conducted a flight research experiment to analyze acoustic propagation in the Mach cutoff shadow zone. The effort was conducted in the fall of 2012 and named the Farfield Investigation of No-boom Thresholds (FaINT). The test helped to build a dataset that will go toward further understanding of the unique acoustic propagation characteristics below Mach cutoff altitude. FaINT was able to correlate sonic boom noise levels measured below cutoff altitude with precise airplane flight conditions, potentially increasing the accuracy over previous studies. A NASA F-18B airplane made supersonic passes such that its Mach cutoff caustic would be at varying distances above a linear 60-microphone, 7375-ft (2247.9 m) long array. A TG-14 motor glider equipped with a microphone on its wing-tip also attempted to capture the same sonic boom waves above ground, but below the Mach cutoff altitude. This paper identified an appropriate metric for sonic boom waveforms in the Mach cutoff shadow zone called Perceived Sound Exposure Level; derived an empirical relationship between Mach cutoff flight conditions and noise levels in the shadow zone; validated a safe cutoff altitude theory presented by previous studies; analyzed the sensitivity of flight below Mach cutoff to unsteady atmospheric conditions and realistic aircraft perturbations; and demonstrated the ability to record sonic boom measurements over 5000 ft (1524.0 m) above ground level, but below Mach cutoff altitude.

  12. Laboratory study of effects of sonic boom shaping on subjective loudness and acceptability

    NASA Technical Reports Server (NTRS)

    Leatherwood, Jack D.; Sullivan, Brenda M.

    1992-01-01

    A laboratory study was conducted to determine the effects of sonic boom signature shaping on subjective loudness and acceptability. The study utilized the sonic boom simulator at the Langley Research Center. A wide range of symmetrical, front-shock-minimized signature shapes were investigated together with a limited number of asymmetrical signatures. Subjective loudness judgments were obtained from 60 test subjects by using an 11-point numerical category scale. Acceptability judgments were obtained using the method of constant stimuli. Results were used to assess the relative predictive ability of several noise metrics, determine the loudness benefits of detailed boom shaping, and derive laboratory sonic boom acceptability criteria. These results indicated that the A-weighted sound exposure level, the Stevens Mark 7 Perceived Level, and the Zwicker Loudness Level metrics all performed well. Significant reductions in loudness were obtained by increasing front-shock rise time and/or decreasing front-shock overpressure of the front-shock minimized signatures. In addition, the asymmetrical signatures were rated to be slightly quieter than the symmetrical front-shock-minimized signatures of equal A-weighted sound exposure level. However, this result was based on a limited number of asymmetric signatures. The comparison of laboratory acceptability results with acceptability data obtained in more realistic situations also indicated good agreement.

  13. Reactive Transport Modeling and Changes in Porosity at Reactive Interfaces in a HLW repository in Clay

    NASA Astrophysics Data System (ADS)

    Samper, J.; Mon, A.; Montenegro, L.; Naves, A.; Fernández, J.

    2016-12-01

    High-level radioactive waste disposal in a deep geological repository is based on a multibarrier concept which combines natural barriers such as the geological formation and artificial barriers such as metallic containers, bentonite and concrete buffers and sealing materials. The stability and performance of the bentonite barrier could be affected by the corrosion products at the canister-bentonite interface and the hyperalkaline conditions caused by the degradation of concrete at the bentonite-concrete interface. Additionally, the host clay formation could also be affected by the hyperalkaline plume at the concrete-clay interface. Here we present a nonisothermal reactive transport model of the long-term interactions of the compacted bentonite with the corrosion products of a carbon-steel canister and the concrete liner of the engineered barrier of a high-level radioactive waste repository in clay. This problem involves large pH changes with a hyperalkaline high-pH plume, complex mineral dissolution/precipitation patterns, cation exchange reactions and proton surface complexation. These reactions lead to large changes in porosity which can even lead to pore clogging. Model results show that magnetite, the main corrosion product, precipitates and reduces significantly the porosity of the bentonite near the canister. The degradation of the concrete liner leads to the precipitation of secondary minerals and the reduction of the porosity of the bentonite and the clay formation at their interfaces with the concrete liner. The zones affected by pore clogging at the canister-bentonite, bentonite-concrete and concrete-clay interfaces at 1 Ma are equal to 10, 25 and 25 mm thick, respectively. The results of our simulations share many of the features of the models reported by others for engineered barrier systems at similar chemical conditions, including: 1) Narrow alteration zones; and 2) Pore clogging at the canister-bentonite, bentonite-concrete and concrete-clay

  14. Oil biodegradation: Interactions of artificial marine snow, clay particles, oil and Corexit.

    PubMed

    Rahsepar, Shokouh; Langenhoff, Alette A M; Smit, Martijn P J; van Eenennaam, Justine S; Murk, Albertinka J; Rijnaarts, Huub H M

    2017-12-15

    During the Deepwater Horizon (DwH) oil spill, interactions between oil, clay particles and marine snow lead to the formation of aggregates. Interactions between these components play an important, but yet not well understood, role in biodegradation of oil in the ocean water. The aim of this study is to explore the effect of these interactions on biodegradation of oil in the water. Laboratory experiments were performed, analyzing respiration and n-alkane and BTEX biodegradation in multiple conditions containing Corexit, alginate particles as marine snow, and kaolin clay. Two oil degrading bacterial pure cultures were added, Pseudomonas putida F1 and Rhodococcus qingshengii TUHH-12. Results show that the presence of alginate particles enhances oil biodegradation. The presence of Corexit alone or in combination with alginate particles and/or kaolin clay, hampers oil biodegradation. Kaolin clay and Corexit have a synergistic effect in increasing BTEX concentrations in the water and cause delay in oil biodegradation. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Common clay and shale

    USGS Publications Warehouse

    Virta, R.L.

    2000-01-01

    Part of the 1999 Industrial Minerals Review. The clay and shale market in 1999 is reviewed. In the U.S., sales or use of clay and shale increased from 26.4 million st in 1998 to 27.3 million st in 1999, with an estimated 1999 value of production of $143 million. These materials were used to produce structural clay products, lightweight aggregates, cement, and ceramics and refractories. Production statistics for clays and shales and for their uses in 1999 are presented.

  16. Selective Clay Placement Within a Silicate-Clay Epoxy Blend Nanocomposite

    NASA Technical Reports Server (NTRS)

    Miller, Sandi G (Inventor)

    2013-01-01

    A clay-epoxy nanocomposite may be prepared by dispersing a layered clay in an alkoxy epoxy, such as a polypropylene oxide based epoxide before combining the mixture with an aromatic epoxy to improve the nanocomposite's thermal and mechanical properties.

  17. Clay nanoparticles for regenerative medicine and biomaterial design: A review of clay bioactivity.

    PubMed

    Mousa, Mohamed; Evans, Nicholas D; Oreffo, Richard O C; Dawson, Jonathan I

    2018-03-01

    Clay nanoparticles, composites and hydrogels are emerging as a new class of biomaterial with exciting potential for tissue engineering and regenerative medicine applications. Clay particles have been extensively explored in polymeric nanocomposites for self-assembly and enhanced mechanical properties as well as for their potential as drug delivery modifiers. In recent years, a cluster of studies have explored cellular interactions with clay nanoparticles alone or in combination with polymeric matrices. These pioneering studies have suggested new and unforeseen utility for certain clays as bioactive additives able to enhance cellular functions including adhesion, proliferation and differentiation, most notably for osteogenesis. This review examines the recent literature describing the potential effects of clay-based nanomaterials on cell function and examines the potential role of key clay physicochemical properties in influencing such interactions and their exciting possibilities for regenerative medicine. Copyright © 2018 Elsevier Ltd. All rights reserved.

  18. Feasibility of Plasma Treated Clay in Clay/Polymer Nanocomposites Powders for use Laser Sintering (LS)

    NASA Astrophysics Data System (ADS)

    Almansoori, Alaa; Seabright, Ryan; Majewski, C.; Rodenburg, C.

    2017-05-01

    The addition of small quantities of nano-clay to nylon is known to improve mechanical properties of the resulting nano-composite. However, achieving a uniform dispersion and distribution of the clay within the base polymer can prove difficult. A demonstration of the fabrication and characterization of plasma-treated organoclay/Nylon12 nanocomposite was carried out with the aim of achieving better dispersion of clay platelets on the Nylon12 particle surface. Air-plasma etching was used to enhance the compatibility between clays and polymers to ensure a uniform clay dispersion in composite powders. Downward heat sintering (DHS) in a hot press is used to process neat and composite powders into tensile and XRD specimens. Morphological studies using Low Voltage Scanning Electron Microscopy (LV-SEM) were undertaken to characterize the fracture surfaces and clay dispersion in powders and final composite specimens. Thermogravimetric analysis (TGA) testing performed that the etched clay (EC) is more stable than the nonetched clay (NEC), even at higher temperatures. The influence of the clay ratio and the clay plasma treatment process on the mechanical properties of the nanocomposites was studied by tensile testing. The composite fabricated from (3% EC/N12) powder showed ~19 % improvement in elastic modulus while the composite made from (3% NEC/N12) powder was improved by only 14%). Most notably however is that the variation between tests is strongly reduced when etch clay is used in the composite. We attribute this to a more uniform distribution and better dispersion of the plasma treated clay within polymer powders and ultimately the composite.

  19. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zheng, Liange; Li, Lianchong; Rutqvist, Jonny

    Clay/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus Clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at the Mol site, Belgium (Barnichon and Volckaert, 2003) have all been under intensive scientific investigation (at both field and laboratorymore » scales) for understanding a variety of rock properties and their relationships to flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated or plastic clays (Tsang and Hudson, 2010). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. During the lifespan of a clay repository, the repository performance is affected by complex thermal, hydrogeological, mechanical, chemical (THMC) processes, such as heat release due to radionuclide decay, multiphase flow, formation of damage zones, radionuclide transport, waste dissolution, and chemical reactions. All these processes are related to each other. An in-depth understanding of these coupled processes is critical for the performance assessment (PA) of the repository. These coupled processes may affect radionuclide transport by changing transport paths (e.g., formation and evolution of excavation damaged zone (EDZ)) and altering flow, mineral, and mechanical properties that are related to radionuclide transport. While radionuclide transport in clay formation has been studied using laboratory tests (e,g, Appelo et al. 2010, Garcia-Gutierrez et al., 2008, Maes et al., 2008), short

  20. A comparison of measured and theoretical predictions for STS ascent and entry sonic booms

    NASA Technical Reports Server (NTRS)

    Garcia, F., Jr.; Jones, J. H.; Henderson, H. R.

    1983-01-01

    Sonic boom measurements have been obtained during the flights of STS-1 through 5. During STS-1, 2, and 4, entry sonic boom measurements were obtained and ascent measurements were made on STS-5. The objectives of this measurement program were (1) to define the sonic boom characteristics of the Space Transportation System (STS), (2) provide a realistic assessment of the validity of xisting theoretical prediction techniques, and (3) establish a level of confidence for predicting future STS configuration sonic boom environments. Detail evaluation and reporting of the results of this program are in progress. This paper will address only the significant results, mainly those data obtained during the entry of STS-1 at Edwards Air Force Base (EAFB), and the ascent of STS-5 from Kennedy Space Center (KSC). The theoretical prediction technique employed in this analysis is the so called Thomas Program. This prediction technique is a semi-empirical method that required definition of the near field signatures, detailed trajectory characteristics, and the prevailing meteorological characteristics as an input. This analytical procedure then extrapolates the near field signatures from the flight altitude to an altitude consistent with each measurement location.

  1. The gravitational potential energy regeneration system with closed-circuit of boom of hydraulic excavator

    NASA Astrophysics Data System (ADS)

    Chen, Mingdong; Zhao, Dingxuan

    2017-01-01

    Considering the disadvantage of higher throttling loss for the open-circuit hydrostatic transmission at present, a novel gravitational potential energy regeneration system (GPERS) of the boom of hydraulic excavator, namely the closed-circuit GPERS, is proposed in this paper. The closed-circuit GPERS is based on a closed-circuit hydrostatic transmission and adopts a hydraulic accumulator as main energy storage element fabricated in novel configuration to recover the entire gravitational potential energy of the boom of hydraulic excavator. The matching parameter and control system design are carried out for the proposed system, and the system is modeled based on its physical attributes. Simulation and experiments are performed to validate the employed mathematical models, and then, the velocity and the pressure performance of system are analyzed. It is observed that the closed-circuit GPERS shows better velocity control of the boom and response characteristics. After that, the average working efficiency of the closed-circuit GPERS of boom is estimated under different load conditions. The results indicate that the proposed system is highly effective and that the average working efficiency in different load conditions varied from 60% to 68.2% for the experiment platform.

  2. A Boom in Boomerangs

    NASA Technical Reports Server (NTRS)

    1992-01-01

    Ted Bailey, a highly-ranked international boomerang designer and thrower, used information from a variety of NASA technical reports on aerodynamics and low-speed airfoils to design more competitive boomerangs. Because the boomerang is essentially an airfoil like an airplane wing, the technology transferred effectively and even contributed to the 1981 American victory over Australian throwers. In 1985, using four NASA reports, Bailey designed a new MTA (maximum time aloft) boomerang that broke the one-minute barrier, enabled throwers to throw and catch in less than three minutes and allowed competitors to complete the difficult "Super Catch" - five throw/catch sequences after launching the original boom while it is still aloft. Bailey is now considering other boomerang applications.

  3. Sonic Boom Mitigation Through Aircraft Design and Adjoint Methodology

    NASA Technical Reports Server (NTRS)

    Rallabhandi, Siriam K.; Diskin, Boris; Nielsen, Eric J.

    2012-01-01

    This paper presents a novel approach to design of the supersonic aircraft outer mold line (OML) by optimizing the A-weighted loudness of sonic boom signature predicted on the ground. The optimization process uses the sensitivity information obtained by coupling the discrete adjoint formulations for the augmented Burgers Equation and Computational Fluid Dynamics (CFD) equations. This coupled formulation links the loudness of the ground boom signature to the aircraft geometry thus allowing efficient shape optimization for the purpose of minimizing the impact of loudness. The accuracy of the adjoint-based sensitivities is verified against sensitivities obtained using an independent complex-variable approach. The adjoint based optimization methodology is applied to a configuration previously optimized using alternative state of the art optimization methods and produces additional loudness reduction. The results of the optimizations are reported and discussed.

  4. Semianalytical Solutions for Transport in Aquifer and Fractured Clay Matrix System

    EPA Science Inventory

    A three-dimensional mathematical model that describes transport of contaminant in a horizontal aquifer with simultaneous diffusion into a fractured clay formation is proposed. A group of analytical solutions is derived based on specific initial and boundary conditions as well as ...

  5. Dynamics of confined reactive water in smectite clay-zeolite composites.

    PubMed

    Pitman, Michael C; van Duin, Adri C T

    2012-02-15

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300-647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)(2)·nH(2)O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  6. Uncertainty Quantification and Certification Prediction of Low-Boom Supersonic Aircraft Configurations

    NASA Technical Reports Server (NTRS)

    West, Thomas K., IV; Reuter, Bryan W.; Walker, Eric L.; Kleb, Bil; Park, Michael A.

    2014-01-01

    The primary objective of this work was to develop and demonstrate a process for accurate and efficient uncertainty quantification and certification prediction of low-boom, supersonic, transport aircraft. High-fidelity computational fluid dynamics models of multiple low-boom configurations were investigated including the Lockheed Martin SEEB-ALR body of revolution, the NASA 69 Delta Wing, and the Lockheed Martin 1021-01 configuration. A nonintrusive polynomial chaos surrogate modeling approach was used for reduced computational cost of propagating mixed, inherent (aleatory) and model-form (epistemic) uncertainty from both the computation fluid dynamics model and the near-field to ground level propagation model. A methodology has also been introduced to quantify the plausibility of a design to pass a certification under uncertainty. Results of this study include the analysis of each of the three configurations of interest under inviscid and fully turbulent flow assumptions. A comparison of the uncertainty outputs and sensitivity analyses between the configurations is also given. The results of this study illustrate the flexibility and robustness of the developed framework as a tool for uncertainty quantification and certification prediction of low-boom, supersonic aircraft.

  7. The effect of aircraft speed on the penetration of sonic boom noise into a flat ocean

    NASA Technical Reports Server (NTRS)

    Sparrow, Victor W.

    1994-01-01

    As U.S. aircraft manufacturers now have focused their HSCT efforts on overwater supersonic flight, a great deal more must be known about sonic booms propagating overwater and interacting with the ocean. For example, it is thought that atmospheric turbulence effects are often much less severe over water than over land. Another important aspect of the overwater flight problems is the penetration of the sonic boom noise into the ocean, where there could be an environmental impact on sea life. This talk will present a brief review on the penetration of sonic boom noise into a large body of water with a flat surface. It has been determined recently that faster supersonic speeds imply greater penetration of sonic boom noise into the ocean. The new theory is derived from the original Sawyers paper and from the knowledge that for level flight a boom's duration is proportional to the quantity M/(M(exp 2)-1)(exp 3/8) where M is the Mach number. It is found that for depths of 10 m or less, the peak SPL varies less than 6 dB over a wide range of M. For greater depths, 100 m for example, increased Mach numbers may increase the SPL by 15 dB or more.

  8. A Grid Sourcing and Adaptation Study Using Unstructured Grids for Supersonic Boom Prediction

    NASA Technical Reports Server (NTRS)

    Carter, Melissa B.; Deere, Karen A.

    2008-01-01

    NASA created the Supersonics Project as part of the NASA Fundamental Aeronautics Program to advance technology that will make a supersonic flight over land viable. Computational flow solvers have lacked the ability to accurately predict sonic boom from the near to far field. The focus of this investigation was to establish gridding and adaptation techniques to predict near-to-mid-field (<10 body lengths below the aircraft) boom signatures at supersonic speeds using the USM3D unstructured grid flow solver. The study began by examining sources along the body the aircraft, far field sourcing and far field boundaries. The study then examined several techniques for grid adaptation. During the course of the study, volume sourcing was introduced as a new way to source grids using the grid generation code VGRID. Two different methods of using the volume sources were examined. The first method, based on manual insertion of the numerous volume sources, made great improvements in the prediction capability of USM3D for boom signatures. The second method (SSGRID), which uses an a priori adaptation approach to stretch and shear the original unstructured grid to align the grid and pressure waves, showed similar results with a more automated approach. Due to SSGRID s results and ease of use, the rest of the study focused on developing a best practice using SSGRID. The best practice created by this study for boom predictions using the CFD code USM3D involved: 1) creating a small cylindrical outer boundary either 1 or 2 body lengths in diameter (depending on how far below the aircraft the boom prediction is required), 2) using a single volume source under the aircraft, and 3) using SSGRID to stretch and shear the grid to the desired length.

  9. Specialized CFD Grid Generation Methods for Near-Field Sonic Boom Prediction

    NASA Technical Reports Server (NTRS)

    Park, Michael A.; Campbell, Richard L.; Elmiligui, Alaa; Cliff, Susan E.; Nayani, Sudheer N.

    2014-01-01

    Ongoing interest in analysis and design of low sonic boom supersonic transports re- quires accurate and ecient Computational Fluid Dynamics (CFD) tools. Specialized grid generation techniques are employed to predict near- eld acoustic signatures of these con- gurations. A fundamental examination of grid properties is performed including grid alignment with ow characteristics and element type. The issues a ecting the robustness of cylindrical surface extrusion are illustrated. This study will compare three methods in the extrusion family of grid generation methods that produce grids aligned with the freestream Mach angle. These methods are applied to con gurations from the First AIAA Sonic Boom Prediction Workshop.

  10. Sm-Nd dating of Fig Tree clay minerals of the Barberton greenstone belt, South Africa.

    PubMed

    Toulkeridis, T; Goldstein, S L; Clauer, N; Kroner, A; Lowe, D R

    1994-03-01

    Sm-Nd isotopic data from carbonate-derived clay minerals of the 3.22-3.25 Ga Fig Tree Group, Barberton greenstone belt, South Africa, form a linear array corresponding to an age of 3102 +/- 64 Ma, making these minerals the oldest dated clays on Earth. The obtained age is 120-160 m.y. younger than the depositional age determined by zircon geochronology. Nd model ages for the clays range from approximately 3.39 to 3.44 Ga and almost cover the age variation of the Barberton greenstone belt rocks, consistent with independent evidence that the clay minerals are derived from material of the belt. The combined isotopic and mineralogical data provide evidence for a cryptic thermal overprint in the sediments of the belt. However, the highest temperature reached by the samples since the time of clay-mineral formation was <300 degrees C, lower than virtually any known early Archean supracrustal sequence.

  11. Sm-Nd dating of Fig Tree clay minerals of the Barberton greenstone belt, South Africa

    NASA Technical Reports Server (NTRS)

    Toulkeridis, T.; Goldstein, S. L.; Clauer, N.; Kroner, A.; Lowe, D. R.

    1994-01-01

    Sm-Nd isotopic data from carbonate-derived clay minerals of the 3.22-3.25 Ga Fig Tree Group, Barberton greenstone belt, South Africa, form a linear array corresponding to an age of 3102 +/- 64 Ma, making these minerals the oldest dated clays on Earth. The obtained age is 120-160 m.y. younger than the depositional age determined by zircon geochronology. Nd model ages for the clays range from approximately 3.39 to 3.44 Ga and almost cover the age variation of the Barberton greenstone belt rocks, consistent with independent evidence that the clay minerals are derived from material of the belt. The combined isotopic and mineralogical data provide evidence for a cryptic thermal overprint in the sediments of the belt. However, the highest temperature reached by the samples since the time of clay-mineral formation was <300 degrees C, lower than virtually any known early Archean supracrustal sequence.

  12. Orbital Boom Sensor System with a cloudy Earth limb

    NASA Image and Video Library

    2005-07-28

    S114-E-5712 (28 July 2005) --- This view of the Orbital Boom Sensor System, backdropped by clouds and Earth’s limb, was taken by the STS-114 crew during approach and docking operations with the international space station.

  13. Clay minerals behaviour in thin sandy clay-rich lacustrine turbidites (Lake Hazar, Turkey)

    NASA Astrophysics Data System (ADS)

    El Ouahabi, Meriam; Hubert-Ferrari, Aurelia; Lamair, Laura; Hage, Sophie

    2017-04-01

    Turbidites have been extensively studied in many different areas using cores or outcrop, which represent only an integrated snapshot of a dynamic evolving flow. Laboratory experiments provide the missing relationships between the flow characteristics and their deposits. In particular, flume experiments emphasize that the presence of clay plays a key role in turbidity current dynamics. Clay fraction, in small amount, provides cohesive strength to sediment mixtures and can damp turbulence. However, the degree of flocculation is dependent on factors such as the amount and size of clay particles, the surface of clay particles, chemistry and pH conditions in which the clay particles are dispersed. The present study focuses on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in stacked thin beds. Depositional processes and sources have been previously studied and three types were deciphered, including laminar flows dominated by cohesion, transitional, and turbulence flow regimes (Hage et al., in revision). For the purpose of determine the clay behavior in the three flow regimes, clay mineralogical, geochemical measurements on the cores allow characterising the turbidites. SEM observations provide further information regarding the morphology of clay minerals and other clasts. The study is particularly relevant given the highly alkaline and saline water of the Hazar Lake. Clay minerals in Hazar Lake sediments include kaolinite (1:1-type), illite and chlorite (2:1-type). Hazar lake water is alkaline having pH around 9.3, in such alkaline environment, a cation-exchange reaction takes place. Furthermore, in saline water (16‰), salts can act as a shield and decrease the repulsive forces between clay particle surfaces. So, pH and salt content jointly impact the behaviour of clays differently. Since the Al-faces of clay structures have a negative charge in basic solutions. At high pH, all kaolinite surfaces become negative-charged, and then kaolinite

  14. 9. PERSPECTIVE OF THE BOOMS, SHOWING THE MANNER IN WHICH ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. PERSPECTIVE OF THE BOOMS, SHOWING THE MANNER IN WHICH STONE WAS HOISTED UPON THE PIER AFTER REMOVAL OF THE DERRICKS. - Potomac Aqueduct, Spanning Potomac River, Washington, District of Columbia, DC

  15. Pilot Test of a Novel Method for Assessing Community Response to Low-Amplitude Sonic Booms

    NASA Technical Reports Server (NTRS)

    Fidell, Sanford; Horonjeff, Richard D.; Harris, Michael

    2012-01-01

    A pilot test of a novel method for assessing residents annoyance to sonic booms was performed. During a two-week period, residents of the base housing area at Edwards Air Force Base provided data on their reactions to sonic booms using Smartphone-based interviews. Noise measurements were conducted at the same time. The report presents information about data collection methods and about test participants reactions to low-amplitude sonic booms. The latter information should not be viewed as definitive for several reasons. It may not be reliably generalized to the wider U.S. residential population (because it was not derived from a representative random sample) and the sample itself was not large.

  16. Organic Control of Dioctahedral and Trioctahedral Clay Formation in an Alkaline Soil System in the Pantanal Wetland of Nhecolândia, Brazil.

    PubMed

    Barbiero, Laurent; Berger, Gilles; Rezende Filho, Ary T; Meunier, Jean-François; Martins-Silva, Elisângela R; Furian, Sonia

    2016-01-01

    Recent studies have focused on the formation of authigenic clays in an alkaline soil system surrounding lakes of the Nhecolândia region, Pantanal wetland. The presence of trioctahedral Mg-smectites (stevensite and saponite types), which requires low Al and Fe contents in the soil solution for its formation, contrasts with the neoformation of dioctahedral Fe-mica (glauconite, and Fe-illite), which instead requires solutions relatively enriched in Al and Fe. This study aims to understand the conditions of co-existence of both, Mg-smectite and Fe-mica a common clay association in former or modern alkaline soil systems and sediments. The study was carried out along an alkaline soil catena representative of the region. The soil organization revealed that Mg-smectite occur in top soil close to the lake, whereas Fe-mica dominate in the clay fraction of deeper greenish horizons a few meters apart. We propose here that this spatial distribution is controlled by the lateral transfer of Fe and Al with organic ligands. Alkaline organic rich solutions (DOC up to 738 mg L-1) collected in the watertable were centrifuged and filtered through membranes of decreasing pore size (0.45 μm, 0.2 μm, 30 KDa, 10 KDa, 3 KDa) to separate colloidal and dissolved fractions. Fe, Al, Si, Mg and K were analysed for each fraction. Although the filtration had no influence on Si and K contents, almost 90% of Fe (up to 2.3 mg L-1) and Al (up to 7 mg L-1) are retained at the first cutoff threshold of 0.45μm. The treatment of the same solutions by oxygen peroxide before filtration shows that a large proportion of Fe and Al were bonded to organic colloids in alkaline soil solution at the immediate lake border, allowing Mg-smectite precipitation. The fast mineralization of the organic matter a few meters apart from the lake favors the release of Fe and Al necessary for Fe-mica neoformation. In comparison with chemical and mineralogical characteristics of alkaline environments described in the

  17. Organic Control of Dioctahedral and Trioctahedral Clay Formation in an Alkaline Soil System in the Pantanal Wetland of Nhecolândia, Brazil

    PubMed Central

    Meunier, Jean-François; Martins-Silva, Elisângela R.; Furian, Sonia

    2016-01-01

    Recent studies have focused on the formation of authigenic clays in an alkaline soil system surrounding lakes of the Nhecolândia region, Pantanal wetland. The presence of trioctahedral Mg-smectites (stevensite and saponite types), which requires low Al and Fe contents in the soil solution for its formation, contrasts with the neoformation of dioctahedral Fe-mica (glauconite, and Fe-illite), which instead requires solutions relatively enriched in Al and Fe. This study aims to understand the conditions of co-existence of both, Mg-smectite and Fe-mica a common clay association in former or modern alkaline soil systems and sediments. The study was carried out along an alkaline soil catena representative of the region. The soil organization revealed that Mg-smectite occur in top soil close to the lake, whereas Fe-mica dominate in the clay fraction of deeper greenish horizons a few meters apart. We propose here that this spatial distribution is controlled by the lateral transfer of Fe and Al with organic ligands. Alkaline organic rich solutions (DOC up to 738 mg L-1) collected in the watertable were centrifuged and filtered through membranes of decreasing pore size (0.45 μm, 0.2 μm, 30 KDa, 10 KDa, 3 KDa) to separate colloidal and dissolved fractions. Fe, Al, Si, Mg and K were analysed for each fraction. Although the filtration had no influence on Si and K contents, almost 90% of Fe (up to 2.3 mg L-1) and Al (up to 7 mg L-1) are retained at the first cutoff threshold of 0.45μm. The treatment of the same solutions by oxygen peroxide before filtration shows that a large proportion of Fe and Al were bonded to organic colloids in alkaline soil solution at the immediate lake border, allowing Mg-smectite precipitation. The fast mineralization of the organic matter a few meters apart from the lake favors the release of Fe and Al necessary for Fe-mica neoformation. In comparison with chemical and mineralogical characteristics of alkaline environments described in the

  18. Formation of Environmentally Persistent Free Radical (EPFR) in Iron(III) Cation-Exchanged Smectite Clay

    PubMed Central

    Nwosu, Ugwumsinachi G.; Roy, Amitava; dela Cruz, Albert Leo N.; Dellinger, Barry; Cook, Robert

    2016-01-01

    Environmentally persistent free radicals (EPFRs) have been found at a number of Superfund sites, with EPFRs being formed via a proposed redox process at ambient environmental conditions. The possibility of such a redox process taking place at ambient environmental conditions is studied utilizing a surrogate soil system of phenol and iron(III)-exchanged calcium montmorillonite clay, Fe(III)CaM. Sorption of phenol by the Fe(III)CaM is demonstrated by Fourier-transformed infra-red (FT-IR) spectroscopy, as evidenced by the peaks between 1345 cm−1 and 1595 cm−1, and at lower frequencies between 694 cm−1 and 806 cm−1, as well as X-ray diffraction (XRD) spectroscopy, as shown by an increase in interlayer spacing within Fe(III)CaM. The formation and characterization of the EPFRs is determined by electron paramagnetic resonance (EPR) spectroscopy, showing phenoxyl-type radical with a g-factor of 2.0034 and ΔHp-p of 6.1 G at an average concentration of 7.5 × 1017 spins/g. EPFRs lifetime data are indicative of oxygen and water molecules being responsible for EPFR decay. The change in the oxidation state of the iron redox center is studied by X-ray absorption near-edge structure (XANES) spectroscopy, showing that 23% of the Fe(III) is reduced to Fe(II). X-ray photoemission spectroscopy (XPS) results confirm the XANES results. These findings, when combined with the EPFR concentration data, demonstrate that the stoichiometry of the EPFR formation under the conditions of this study is 1.5 × 10−2 spins/Fe(II) atom. PMID:26647158

  19. Formation of environmentally persistent free radical (EPFR) in iron(III) cation-exchanged smectite clay.

    PubMed

    Nwosu, Ugwumsinachi G; Roy, Amitava; dela Cruz, Albert Leo N; Dellinger, Barry; Cook, Robert

    2016-01-01

    Environmentally persistent free radicals (EPFRs) have been found at a number of Superfund sites, with EPFRs being formed via a proposed redox process at ambient environmental conditions. The possibility of such a redox process taking place at ambient environmental conditions is studied utilizing a surrogate soil system of phenol and iron(III)-exchanged calcium montmorillonite clay, Fe(III)CaM. Sorption of phenol by the Fe(III)CaM is demonstrated by Fourier-transformed infra-red (FT-IR) spectroscopy, as evidenced by the peaks between 1345 cm(-1) and 1595 cm(-1), and at lower frequencies between 694 cm(-1) and 806 cm(-1), as well as X-ray diffraction (XRD) spectroscopy, as shown by an increase in interlayer spacing within Fe(III)CaM. The formation and characterization of the EPFRs is determined by electron paramagnetic resonance (EPR) spectroscopy, showing phenoxyl-type radical with a g-factor of 2.0034 and ΔHP-P of 6.1 G at an average concentration of 7.5 × 10(17) spins per g. EPFRs lifetime data are indicative of oxygen and water molecules being responsible for EPFR decay. The change in the oxidation state of the iron redox center is studied by X-ray absorption near-edge structure (XANES) spectroscopy, showing that 23% of the Fe(III) is reduced to Fe(II). X-ray photoemission spectroscopy (XPS) results confirm the XANES results. These findings, when combined with the EPFR concentration data, demonstrate that the stoichiometry of the EPFR formation under the conditions of this study is 1.5 × 10(-2) spins per Fe(II) atom.

  20. Diffusional Transport of Organic Solutes in Subsurface Clay Lenses and Layers

    NASA Astrophysics Data System (ADS)

    Demond, A. H.; Ayral, D.; Goltz, M. N.

    2009-12-01

    The storage of organic solvents in clay lenses and layers in the subsurface creates long-term contaminant sources. Because of the low hydraulic conductivities of clay, it is thought that organic movement into clay lenses occurs through the process of diffusion. The ratio of the effective diffusion coefficient in the porous medium and the diffusion coefficient in bulk water is usually given by the tortuosity factor which accounts for the reduced area and the increased path length in the porous medium. However, there is field evidence which suggests that the concentrations in these lenses exceed that which can be accounted for by simple diffusion. There are reports, for example, of tortuosity factors greater than 1.0, which theoretically is not possible. Clays such as montmorillonite or bentonite shrink and swell depending on water content, and similar behavior can occur in the presence of organic solvents. In fact, research has shown that the basal spacing of bentonite can decrease by 50% when permeated with heptane. Such contraction of the clay structure can lead to the formation of cracks and macropores, with a concomitant alteration of the diffusional pathways that solutes follow. Models formulated for diffusional transport in soil are available to calculate the tortuosity factor as a function of water content. In addition, models are available to simulate phenomena in which the diffusion coefficient is concentration dependent. However, calculations of diffusional transport using such models show that they may not adequately reflect the impact of the alteration of the clay structure. However, modeling the transport of organic solutes in clay as a dual-domain system with some minimal advective transport in macropores can yield tortuosity factors greater than 1.0. Thus, it appears the cracking of clay in contact with organic solvents and a resultant advective component to transport of the solute may be an explanation of field observations.

  1. Clay particles as binder for earth buildings materials: a fresh look into rheology of dense clay suspensions

    NASA Astrophysics Data System (ADS)

    Landrou, Gnanli; Brumaud, Coralie; Habert, Guillaume

    2017-06-01

    In the ceramic industry and in many sectors, clay minerals are widely used. In earthen construction technique, clay plays a crucial role in the processing. The purpose of this research is to understand and modify the clay properties in earth material to propose an innovative strategy to develop a castable earth-based material. To do so, we focused on the modification of clay properties at fresh state with inorganic additives. As the rheological behaviour of clays is controlled by their surface charge, the addition of phosphate anion allows discussing deep the rheology of concentrated clay suspensions. We highlighted the thixotropic and shear thickening behaviour of a dispersed kaolinite clay suspensions. Indeed, by adding sodium hexametaphosphate the workability of clay paste increases and the behaviour is stable during time after a certain shear is applied. Moreover, we stress that the aging and the shift in critical strain in clay system are due to the re-arrangement of clay suspension and a decrease of deformation during time. The understanding of both effect: thixotropy and aging are crucial for better processing of clay-based material and for self-compacting clay concrete. Yet, studies need to pursue to better understand the mechanism.

  2. America's Baby Boom Generation: The Fateful Bulge. Population Bulletin. Vol. 35, No. 1. April 1980.

    ERIC Educational Resources Information Center

    Bouvier, Leon F.

    This bulletin examines the baby boom, its causes, its size, and its impact on U.S. society. Nearly 42 million births occurred in the U.S. from 1955 to 1964. Several reasons are given for this baby boom which interrupted a century long fertility decline. Demographically the primary causes were more people marrying and having at least two children…

  3. Flight investigation of the effect of tail boom strakes on helicopter directional control

    NASA Technical Reports Server (NTRS)

    Kelly, Henry L.; Crowell, Cynthia A.; Yenni, Kenneth R.; Lance, Michael B.

    1993-01-01

    A joint U.S. Army/NASA flight investigation was conducted utilizing a single-rotor helicopter to determine the effectiveness of horizontally mounted tail boom strakes on directional controllability and tail rotor power during low-speed, crosswind operating conditions. Three configurations were investigated: (1) baseline (strakes off), (2) single strake (strake at upper shoulder on port side of boom), and (3) double strake (upper strake plus a lower strake on same side of boom). The strakes were employed as a means to separate airflow over the tail boom and change fuselage yawing moments in a direction to improve the yaw control margin and reduce tail rotor power. Crosswind data were obtained in 5-knot increments of airspeed from 0 to 35 knots and in 30 deg increments of wind azimuth from 0 deg to 330 deg. At the most critical wind azimuth and airspeed in terms of tail rotor power, the strakes improved the pedal margin by 6 percent of total travel and reduced tail rotor power required by 17 percent. The increase in yaw control and reduction in tail rotor power offered by the strakes can expand the helicopter operating envelope in terms of gross weight and altitude capability. The strakes did not affect the flying qualities of the vehicle at airspeeds between 35 and 100 knots.

  4. A NASTRAN investigation of simulated projectile damage effects on a UH-1B tail boom model

    NASA Technical Reports Server (NTRS)

    Futterer, A. T.

    1980-01-01

    A NASTRAN model of a UH-1B tail boom that had been designed for another project was used to investigate the effect on structural integrity of simulated projectile damage. Elements representing skin, and sections of stringers, longerons and bulkheads were systematically deleted to represent projectile damage. The structure was loaded in a manner to represent the flight loads that would be imposed on the tail boom at a 130 knot cruise. The deflection of four points on the rear of the tail boom relative to the position of these points for the unloaded, undamaged condition of the tail boom was used as a measure of the loss of structural rigidity. The same procedure was then used with the material properties of the aluminum alloys replaced with the material properties of T300/5208 high strength graphite/epoxy fibrous composite material, (0, + or - 45, 90)s for the skin and (0, + or - 45)s for the longerons, stringers, and bulk heads.

  5. The Retirement Security of the Baby Boom Generation.

    ERIC Educational Resources Information Center

    Shoven, John B.

    1995-01-01

    The baby boom generation faces added uncertainty on their investments and perhaps lower realized rates of return on all components of their retirement savings, primarily because of their large number. Effects will be felt in the Social Security system and by pension plans and private investors. Individuals, employers, pension fund managers, and…

  6. The dynamics and optimal control of spinning spacecraft with movable telescoping appendages. Part C: Effect of flexibility during boom deployment

    NASA Technical Reports Server (NTRS)

    Bainum, P. M.; James, P. K.

    1977-01-01

    The dynamics of a spinning symmetrical spacecraft system during the deployment (or retraction) of flexible boom-type appendages were investigated. The effect of flexibility during boom deployment is treated by modelling the deployable members as compound spherical pendula of varying length (according to a control law). The orientation of the flexible booms with respect to the hub, is described by a sequence of two Euler angles. The boom members contain a flexural stiffness which can be related to an assumed effective restoring linear spring constant, and structural damping which effects the entire system. Linearized equations of motion for this system, when the boom length is constant, involve periodic coefficients with the frequency of the hub spin. A bounded transformation is found which converts this system into a kinematically equivalent one involving only constant coefficients.

  7. Investigation of quartz diagenesis in mudstones of the Spraberry and Wolfcamp Formations

    NASA Astrophysics Data System (ADS)

    Eakin, A.; Reece, J. S.

    2016-12-01

    Here we present preliminary core analysis of the diagenetic variability existing within a siliceous mudstone facies of the Permian Spraberry and Wolfcamp Formations in the Midland Basin, Texas. Within this mudstone facies, the carbonate content varies from absent in several Wolfcamp Formation samples to >40 wt. % in the Spraberry Formation. A normalized ratio of quartz to clay content with carbonate removed reveals a systematic decrease in quartz content with increasing clay content. This relationship is typical of rocks with variable amounts of detrital quartz content. However, in this siliceous mudstone facies, the abundance of detrital quartz silt grains does not vary widely. Additionally, for the same clay content, the Wolfcamp Formation shows a higher concentration of quartz than the Spraberry Formation. Scanning electron microscopy (SEM) reveals the presence of microcrystalline quartz cement that likely accounts for the increased quartz content in the Wolfcamp Formation. This research tests the hypothesis that the increased quartz cement in the Wolfcamp Formation may occur at the expense of the carbonate cement present in the overlying Spraberry Formation. Furthermore, the deviation in quartz content for the same clay concentration only occurs once the ratio of quartz to clay content increases beyond 1.2. This ratio may represent a threshold of detrital quartz in the clay matrix required to have enough porosity and nucleation surface area for authigenic quartz growth. The presence of matrix cement may impact the mechanical properties to favor fracturing and cataclasis over more ductile deformation. This would enhance development of secondary porosity, while also increasing permeability through the connection of primary pores. Acquiring a fundamental understanding of diagenesis in the Spraberry and Wolfcamp Formations will aid in better prediction of mechanical behavior during drilling and optimized resource recovery.

  8. New knowledge-based genetic algorithm for excavator boom structural optimization

    NASA Astrophysics Data System (ADS)

    Hua, Haiyan; Lin, Shuwen

    2014-03-01

    Due to the insufficiency of utilizing knowledge to guide the complex optimal searching, existing genetic algorithms fail to effectively solve excavator boom structural optimization problem. To improve the optimization efficiency and quality, a new knowledge-based real-coded genetic algorithm is proposed. A dual evolution mechanism combining knowledge evolution with genetic algorithm is established to extract, handle and utilize the shallow and deep implicit constraint knowledge to guide the optimal searching of genetic algorithm circularly. Based on this dual evolution mechanism, knowledge evolution and population evolution can be connected by knowledge influence operators to improve the configurability of knowledge and genetic operators. Then, the new knowledge-based selection operator, crossover operator and mutation operator are proposed to integrate the optimal process knowledge and domain culture to guide the excavator boom structural optimization. Eight kinds of testing algorithms, which include different genetic operators, are taken as examples to solve the structural optimization of a medium-sized excavator boom. By comparing the results of optimization, it is shown that the algorithm including all the new knowledge-based genetic operators can more remarkably improve the evolutionary rate and searching ability than other testing algorithms, which demonstrates the effectiveness of knowledge for guiding optimal searching. The proposed knowledge-based genetic algorithm by combining multi-level knowledge evolution with numerical optimization provides a new effective method for solving the complex engineering optimization problem.

  9. A study of sonic boom overpressure trends with respect to weight, altitude, Mach number, and vehicle shaping

    NASA Technical Reports Server (NTRS)

    Needleman, Kathy E.; Mack, Robert J.

    1990-01-01

    This paper presents and discusses trends in nose shock overpressure generated by two conceptual Mach 2.0 configurations. One configuration was designed for high aerodynamic efficiency, while the other was designed to produce a low boom, shaped-overpressure signature. Aerodynamic lift, sonic boom minimization, and Mach-sliced/area-rule codes were used to analyze and compute the sonic boom characteristics of both configurations with respect to cruise Mach number, weight, and altitude. The influence of these parameters on the overpressure and the overpressure trends are discussed and conclusions are given.

  10. Dinosaurs, spherules, and the “magic” layer: A new K-T boundary clay site in Wyoming

    NASA Astrophysics Data System (ADS)

    Bohor, Bruce F.; Triplehorn, Don M.; Nichols, Douglas J.; Millard, Hugh T., Jr.

    1987-10-01

    A new Cretaceous-Tertiary (K-T) boundary clay site has been found along Dogie Creek in Wyoming in the drainage of Lance Creek—the type area of the Lance Formation of latest Cretaceous age. The boundary clay was discovered in the uppermost part of the Lance Formation, 4 7 cm beneath the lowest lignite in the Paleocene Fort Union Formation and approximately 1 m above a fragmented dinosaur bone. The boundary clay consists of a basal kaolinitic claystone layer as much as 3 cm thick containing hollow goyazite spherules, overlain by a 2 3 mm smectitic layer (the “magic” layer) containing both shock-metamorphosed minerals and an iridium anomaly of 21 ppb. A palynological break coincides with the base of the claystone layer; numerous Late Cretaceous palynomorph species terminate at this boundary. The paleontological significance of this new boundary site lies in its close association with the well-studied assemblage of dinosaurs and other vertebrates and flora within the type area of the Lance Formation. The spherules at the Dogie Creek site are extremely well preserved by virtue of their replacement by the mineral goyazite. This preservation should facilitate the resolution of the origin of the spherules and of their host layer.

  11. Correlation between thermal behavior of clays and their chemical and mineralogical composition: a review

    NASA Astrophysics Data System (ADS)

    Dwi Yanti, Evi; Pratiwi, I.

    2018-02-01

    Clay's abundance has been widely used as industrial raw materials, especially ceramic and tile industries. Utilization of these minerals needs a thermal process for producing ceramic products. Two studies conducted by Septawander et al. and Chin C et al., showed the relationship between thermal behavior of clays and their chemical and mineralogical composition. Clays are characterized by XRD analysis and thermal analysis, ranging from 1100°C to 1200°C room temperature. Specimen of raw materials of clay which is used for the thermal treatment is taken from different geological conditions and formation. In raw material, Quartz is almost present in all samples. Halloysite, montmorillonite, and feldspar are present in Tanjung Morawa raw clay. KC and MC similar kaolinite and illite are present in the samples. The research illustrates the interrelationships of clay minerals and chemical composition with their heat behavior. As the temperature of combustion increases, the sample reduces a significant weight. The minerals which have undergone a transformation phase became mullite, cristobalite or illite and quartz. Under SEM analysis, the microstructures of the samples showed irregularity in shape; changes occurred due the increase of heat.

  12. Fire clay

    USGS Publications Warehouse

    Virta, R.L.

    2012-01-01

    Five companies mined fire clay in four states in 2011. Production, based on a preliminary survey of the fire clay industry, was estimated to be 240 kt (265,000 st), valued at $7.68 million, an increase from 216 kt (238,000 st), valued at $6.12 million in 2010. Missouri was the leading producing state, followed by Texas, Washington and Ohio, in decreasing order by quantity.

  13. Evaluation of Used Fuel Disposition in Clay-Bearing Rock

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jove-Colon, Carlos F.; Weck, Philippe F.; Hammond, Glenn Edward

    Deep geological disposal of nuclear waste in clay/shale/argillaceous rock formations has received much consideration given its desirable attributes such as isolation properties (low permeability), geochemically reduced conditions, slow diffusion, sorbtive mineralogy, and geologically widespread (Jové Colón et al., 2014). There is a wealth of gained scientific expertise on the behavior of clay/shale/ argillaceous rock given its focus in international nuclear waste repository programs that includes underground research laboratories (URLs) in Switzerland, France, Belgium, and Japan. Jové Colón et al. (2014) have described some of these investigative efforts in clay rock ranging from site characterization to research on the engineered barriermore » system (EBS). Evaluations of disposal options that include nuclear waste disposition in clay/shale/argillaceous rock have determined that this host media can accommodate a wide range of waste types. R&D work within the Used Fuel Disposition Campaign (UFDC) assessing thermal effects and fluid-mineral interactions for the disposition of heat-generating waste have so far demonstrated the feasibility for the EBS and clay host rock to withstand high thermal loads. This report represents the continuation of disposal R&D efforts on the advancement and refinement of coupled Thermal-Hydrological-Mechanical-Chemical (THMC), hydrothermal experiments on clay interactions, used fuel degradation (source term), and thermodynamic modeling and database development. The development and implementation of a clay/shale/argillite reference case described in Jové Colón et al. (2014) for FY15 will be documented in another report (Mariner et al. 2015) – only a brief description will be given here. This clay reference case implementation is the result of integration efforts between the GDSA PA and disposal in argillite work packages. The assessment of sacrificial zones in the EBS is being addressed through experimental work along with 1D

  14. Glowing clay: Real time tracing using a suite of novel clay based fluorescent tracers

    NASA Astrophysics Data System (ADS)

    Hardy, Robert; Quinton, John; Pates, Jackie; Coogan, Mike

    2015-04-01

    Clay is one of the most mobile fractions of soil due to its small particle size. It is also known to sorb many chemicals, such as nutrients (notably phosphorus), agrochemicals and heavy metals. The movement of clay is therefore linked with the transport and fate of these substances. A novel fluorescent clay tracing suite has been produced, together with an imaging technique. This suite consists of qualitative clay tracers, using rhodamine based fluorophores, and quantitative clay tracers, using metal based fluorophores. Efforts have also been made to allow integration of commercially available tracers, which are silt and sand sized. The clay tracers exploit the high affinity that montmorillonite has for Rhodamine B and Ru(bpy)3. This allows for an extremely thin layer of the fluorophore to be sorbed onto the clay's surface, in much that same way as materials in the natural environment will bind to clay. The tracer that is produced retains key chemical and physical properties of clay, such as size, shape and density. The retention of these micro-properties results in the retention of macro-properties, such as tendency to aggregate and cracking on drying. Imaging techniques have been developed to analyse these tracers. The imaging system uses diffused laser light to excite the tracer and a modified DSLR camera to image the soil surface. The images have been compiled into a time lapse video showing the movement of clay over the course of a rainfall event. This is the first time that the quantitative movement of clay has been recorded over a soil surface in real time. 4D data can be extracted from the images allowing the spatial location and intensity of tracer to be monitored over time, with mm precision and on the timescale of seconds. As the system can also work with a commercial tracer it is possible to investigate the movement of particles of almost any size and over a range of scales from soil box to hillside. This allows users to access this technique without

  15. The Control of Welding Deformation of the Three-Section Arm of Placing Boom of HB48B Pump Truck

    NASA Astrophysics Data System (ADS)

    Wang, Zhi-ling

    2018-02-01

    The concrete pump truck is the construction equipment of conveying concrete with self contained base plate and distributing boom. It integrates the pump transport mechanism of the concrete pump, and the hydraulic roll-folding type distributing boom used to distribute materials, and the supporting mechanism into the automobile chassis, and it is the concrete conveying equipment with high efficient and the functions of driving, pumping, and distributing materials. The placing boom of the concrete pump truck is the main force member in the pump parts with bearing great pressure, and its stress condition is complex. Taking the HB48B placing boom as an example, this paper analyzes and studies the deformation produced by placing boom of pump truck, and then obtains some main factors affecting the welding deformation. Through the riveter “joint” size, we controlled the process parameters, post-welding processing, and other aspects. These measures had some practical significance to prevent, control, and reduce the deformation of welding.

  16. Scanning electron microscopy of clays and clay minerals

    USGS Publications Warehouse

    Bohor, B.F.; Hughes, R.E.

    1971-01-01

    The scanning electron microscope (SEM) proves to be ideally suited for studying the configuration, texture, and fabric of clay samples. Growth mechanics of crystalline units—interpenetration and interlocking of crystallites, crystal habits, twinning, helical growth, and topotaxis—also are uniquely revealed by the SEM.Authigenic kaolins make up the bulk of the examples because their larger crystallite size, better crystallinity, and open texture make them more suited to examination by the SEM than most other clay mineral types.

  17. The Berkeley Out-of-Order Machine (BOOM): An Industry-Competitive, Synthesizable, Parameterized RISC-V Processor

    DTIC Science & Technology

    2015-06-13

    The Berkeley Out-of-Order Machine (BOOM): An Industry- Competitive, Synthesizable, Parameterized RISC-V Processor Christopher Celio David A...Synthesizable, Parameterized RISC-V Processor Christopher Celio, David Patterson, and Krste Asanović University of California, Berkeley, California 94720...Order Machine BOOM is a synthesizable, parameterized, superscalar out- of-order RISC-V core designed to serve as the prototypical baseline processor

  18. Comparing a spray boom to a roller-wiper system for a single-passenger four-wheeler

    Treesearch

    James D. Haywood; Richard Hallman

    1992-01-01

    The ability of spray booms and carpet-covered roller-wipers mounted on four-wheelers to apply herbicides on pine plantings sites was tested with the following treatments: spray boom application of 0.31 kg (0.69 lb) acid equivalent glyphosate with 0.08 kg (0.18 lb) active ingredient sulfometuron in 215 liters of water/ha (23 gallons/acre) and roller-wiping the...

  19. Sonic boom startle effects : report of a field study.

    DOT National Transportation Integrated Search

    1973-07-01

    The study reports the results of a sonic boom field study conducted in Sweden during October 1972. Ten female subjects were tested indoors on each of six days. Two age groups were studied: 20-35 and 50-65 years. Fighter aircraft flying at various hei...

  20. Clay Mineral Structure Similar to Clays Observed in Mudstone on Mars

    NASA Image and Video Library

    2013-12-09

    This schematic shows the atomic structure of the smallest units that make up the layers and interlayer region of clay minerals. This structure is similar to the clay mineral in drilled rock powder collected by NASA Curiosity Mars rover.

  1. The Suitable Geological Formations for Spent Fuel Disposal in Romania

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Marunteanu, C.; Ionita, G.; Durdun, I.

    2007-07-01

    Using the experience in the field of advanced countries and formerly Romanian program data, ANDRAD, the agency responsible for the disposal of radioactive wastes, started the program for spent fuel disposal in deep geological formations with a documentary analysis at the national scale. The potential geological formations properly characterized elsewhere in the world: salt, clay, volcanic tuff, granite and crystalline rocks,. are all present in Romania. Using general or specific selection criteria, we presently consider the following two areas for candidate geological formations: 1. Clay formations in two areas in the western part of Romania: (1) The Pannonian basin Socodormore » - Zarand, where the clay formation is 3000 m thick, with many bentonitic strata and undisturbed structure, and (2) The Eocene Red Clay on the Somes River, extending 1200 m below the surface. They both need a large investigation program in order to establish and select the required homogeneous, dry and undisturbed zones at a suitable depth. 2. Old platform green schist formations, low metamorphosed, quartz and feldspar rich rocks, in the Central Dobrogea structural unit, not far from Cernavoda NPP (30 km average distance), 3000 m thick and including many homogeneous, fine granular, undisturbed, up to 300 m thick layers. (authors)« less

  2. Method for Estimating the Sonic-Boom Characteristics of Lifting Canard-Wing Aircraft Concepts

    NASA Technical Reports Server (NTRS)

    Mack, Robert J.

    2005-01-01

    A method for estimating the sonic-boom overpressures from a conceptual aircraft where the lift is carried by both a canard and a wing during supersonic cruise is presented and discussed. Computer codes used for the prediction of the aerodynamic performance of the wing, the canard-wing interference, the nacelle-wing interference, and the sonic-boom overpressures are identified and discussed as the procedures in the method are discussed. A canard-wing supersonic-cruise concept was used as an example to demonstrate the application of the method.

  3. 14. Photocopy of c. 1906 photograph of 70 foot boom ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. Photocopy of c. 1906 photograph of 70 foot boom crane that unloaded the sugar cane. - Laurel Valley Sugar Plantation, Sugar Mill, 2 miles South of Thibodaux on State Route 308, Thibodaux, Lafourche Parish, LA

  4. 3. Keechelus Dam from northern shoulder, with spillway boom at ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. Keechelus Dam from northern shoulder, with spillway boom at right foreground and outlet gate tower at right background. View to south. - Keechelus Dam, Yakima River, 10 miles northwest of Easton, Easton, Kittitas County, WA

  5. Jim Driver, Panola County Oil and Gas Boom.

    ERIC Educational Resources Information Center

    Wyatt, Bobbie, Ed.

    1981-01-01

    Written by history students at Gary High School, Gary, Texas, this volume presents several diverse pictures of life in East Texas. The first article, "Jim Driver, Panola County Oil and Gas Boom," (Bobby Kelly and Billy Anderson) talks about drilling for oil and gas and the concerns of an employee of the drilling company. "When I Was…

  6. 1. Distant view of mill ruins with boom crane for ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Distant view of mill ruins with boom crane for unloading sugar cane in foreground, looking W. - Laurel Valley Sugar Plantation, Sugar Mill, 2 miles South of Thibodaux on State Route 308, Thibodaux, Lafourche Parish, LA

  7. Using FUN3D for Aeroelastic, Sonic Boom, and AeroPropulsoServoElastic (APSE) Analyses of a Supersonic Configuration

    NASA Technical Reports Server (NTRS)

    Silva, Walter A.; Sanetrik, Mark D.; Chwalowski, Pawel; Connolly, Joseph; Kopasakis, George

    2016-01-01

    An overview of recent applications of the FUN3D CFD code to computational aeroelastic, sonic boom, and aeropropulsoservoelasticity (APSE) analyses of a low-boom supersonic configuration is presented. The overview includes details of the computational models developed including multiple unstructured CFD grids suitable for aeroelastic and sonic boom analyses. In addition, aeroelastic Reduced-Order Models (ROMs) are generated and used to rapidly compute the aeroelastic response and utter boundaries at multiple flight conditions.

  8. Cart3D Analysis of Plume and Shock Interaction Effects on Sonic Boom

    NASA Technical Reports Server (NTRS)

    Castner, Raymond

    2015-01-01

    A plume and shock interaction study was developed to collect data and perform CFD on a configuration where a nozzle plume passed through the shock generated from the wing or tail of a supersonic vehicle. The wing or tail was simulated with a wedge-shaped shock generator. Three configurations were analyzed consisting of two strut mounted wedges and one propulsion pod with an aft deck from a low boom vehicle concept. Research efforts at NASA were intended to enable future supersonic flight over land in the United States. Two of these efforts provided data for regulatory change and enabled design of low boom aircraft. Research has determined that sonic boom is a function of aircraft lift and volume distribution. Through careful tailoring of these variables, the sonic boom of concept vehicles has been reduced. One aspect of vehicle tailoring involved how the aircraft engine exhaust interacted with aft surfaces on a supersonic aircraft, such as the tail and wing trailing edges. In this work, results from Euler CFD simulations are compared to experimental data collected on sub-scale components in a wind tunnel. Three configurations are studied to simulate the nozzle plume interaction with representative wing and tail surfaces. Results demonstrate how the plume and tail shock structure moves with increasing nozzle pressure ratio. The CFD captures the main features of the plume and shock interaction. Differences are observed in the plume and deck shock structure that warrant further research and investigation.

  9. Mechanism of smectic arrangement of montmorillonite and bentonite clay platelets incorporated in gels of poly(acrylamide) induced by the interaction with cationic surfactants.

    PubMed

    Starodoubtsev, S G; Lavrentyeva, E K; Khokhlov, A R; Allegra, G; Famulari, A; Meille, S V

    2006-01-03

    Structure transitions, induced by the interaction with the cationic surfactant cetylpyridinium chloride in nanocomposite gels of poly(acrylamide) with incorporated suspensions of the two closely related layered clays bentonite and montmorillonite, were studied. Unexpectedly, different behaviors were revealed. X-ray diffraction measurements confirm that, due to the interaction with the surfactant, initially disordered bentonite platelets arrange into highly ordered structures incorporating alternating clay platelets and surfactant bilayers. The formation of these smectic structures also in the cross-linked polymer gels, upon addition of the surfactant, is explained by the existence of preformed, poorly ordered aggregates of the clay platelets in the suspensions before the gel formation. In the case of montmorillonite, smectic ordering of the disordered platelets in the presence of the surfactant is observed only after drying the suspensions and the clay-gel composites. Rheology studies of aqueous suspensions of the two clays, in the absence of both surfactant and gel, evidence a much higher viscosity for bentonite than for montmorillonite, suggesting smaller clay-aggregate size in the latter case. Qualitatively consistent results are obtained from optical micrographs.

  10. Comparison of tetrachloromethane sorption to an alkylammonium-clay and an alkyldiammonium-clay

    USGS Publications Warehouse

    Smith, J.A.; Jaffe, P.R.

    1991-01-01

    The interlamellar space of Wyoming bentonite (clay) was modified by exchanging either decyltrimethyl-ammonium (DTMA) or decyltrimethyldiammonium (DTMDA) cations for inorganic ions, and tetrachloromethane sorption to the resulting two organoclays from water was studied at 10, 20, and 35??C. Only one end of the 10-carbon alkyl chain of the DTMA cation is attached to the silica surface of the clay mineral, and tetrachloromethane sorption of DTMA-clay is characterized by isotherm linearity, noncompetitive sorption, weak solute uptake, and a relatively low heat of sorption. Both ends of the 10-carbon chain of the DTMDA cation are attached to the silica surface of the clay mineral, and tetrachloromethane sorption to DTMDA-clay is characterized by nonlinear isotherms, competitive sorption, strong solute uptake, and a relatively high, exothermic heat of sorption that varies as a function of the mass of tetrachloromethane sorbed. Therefore, the attachment of both ends of the alkyl chain to the interlamellar mineral surface appears to change the sorption mechanism from a partition-dominated process to an adsorption-dominated process. ?? 1991 American Chemical Society.

  11. Progress in modeling atmospheric propagation of sonic booms

    NASA Technical Reports Server (NTRS)

    Pierce, Allan D.

    1994-01-01

    The improved simulation of sonic boom propagation through the real atmosphere requires greater understanding of how the transient acoustic pulses popularly termed sonic booms are affected by humidity and turbulence. A realistic atmosphere is invariably somewhat turbulent, and may be characterized by an ambient fluid velocity v and sound speed c that vary from point to point. The absolute humidity will also vary from point to point, although possibly not as irregularly. What is ideally desired is a relatively simple scheme for predicting the probable spreads in key sonic boom signature parameters. Such parameters could be peak amplitudes, rise times, or gross quantities obtainable by signal processing that correlate well with annoyance or damage potential. The practical desire for the prediction scheme is that it require a relatively small amount of knowledge, possibly of a statistical nature, concerning the atmosphere along, the propagation path from the aircraft to the ground. The impact of such a scheme, if developed, implemented, and verified, would be that it would give the persons who make planning decisions a tool for assessing the magnitude of environmental problems that might result from any given overflight or sequence of overflights. The technical approach that has been followed by the author and some of his colleagues is to formulate a hierarchy of simple approximate models based on fundamental physical principles and then to test these models against existing data. For propagation of sonic booms and of other types of acoustic pulses in nonturbulent model atmospheres, there exists a basic overall theoretical model that has evolved as an outgrowth of geometrical acoustics. This theoretical model depicts the sound as propagating within ray tubes in a manner analogous to sound in a waveguide of slowly varying cross-section. Propagation along the ray tube is quasi-one-dimensional, and a wave equation for unidirectional wave propagation is used. A nonlinear

  12. Long-term non-isothermal reactive transport model of compacted bentonite, concrete and corrosion products in a HLW repository in clay

    NASA Astrophysics Data System (ADS)

    Mon, Alba; Samper, Javier; Montenegro, Luis; Naves, Acacia; Fernández, Jesús

    2017-02-01

    Radioactive waste disposal in deep geological repositories envisages engineered barriers such as carbon-steel canisters, compacted bentonite and concrete liners. The stability and performance of the bentonite barrier could be affected by the corrosion products at the canister-bentonite interface and the hyper-alkaline conditions caused by the degradation of concrete at the bentonite-concrete interface. Additionally, the host clay formation could also be affected by the hyper-alkaline plume at the concrete-clay interface. Here we present a non-isothermal multicomponent reactive transport model of the long-term (1 Ma) interactions of the compacted bentonite with the corrosion products of a carbon-steel canister and the concrete liner of the engineered barrier of a high-level radioactive waste repository in clay. Model results show that magnetite is the main corrosion product. Its precipitation reduces significantly the porosity of the bentonite near the canister. The degradation of the concrete liner leads to the precipitation of secondary minerals and the reduction of the porosity of the bentonite and the clay formation at their interfaces with the concrete liner. The reduction of the porosity becomes especially relevant at t = 104 years. The zones affected by pore clogging at the canister-bentonite and concrete-clay interfaces at 1 Ma are approximately equal to 1 and 3.3 cm thick, respectively. The hyper-alkaline front (pH > 8.5) spreads 2.5 cm into the clay formation after 1 Ma. Our simulation results share the key features of the models reported by others for engineered barrier systems at similar chemical conditions, including: 1) Pore clogging at the canister-bentonite and concrete-clay interfaces; 2) Narrow alteration zones; and 3) Limited smectite dissolution after 1 Ma.

  13. Long-term non-isothermal reactive transport model of compacted bentonite, concrete and corrosion products in a HLW repository in clay.

    PubMed

    Mon, Alba; Samper, Javier; Montenegro, Luis; Naves, Acacia; Fernández, Jesús

    2017-02-01

    Radioactive waste disposal in deep geological repositories envisages engineered barriers such as carbon-steel canisters, compacted bentonite and concrete liners. The stability and performance of the bentonite barrier could be affected by the corrosion products at the canister-bentonite interface and the hyper-alkaline conditions caused by the degradation of concrete at the bentonite-concrete interface. Additionally, the host clay formation could also be affected by the hyper-alkaline plume at the concrete-clay interface. Here we present a non-isothermal multicomponent reactive transport model of the long-term (1Ma) interactions of the compacted bentonite with the corrosion products of a carbon-steel canister and the concrete liner of the engineered barrier of a high-level radioactive waste repository in clay. Model results show that magnetite is the main corrosion product. Its precipitation reduces significantly the porosity of the bentonite near the canister. The degradation of the concrete liner leads to the precipitation of secondary minerals and the reduction of the porosity of the bentonite and the clay formation at their interfaces with the concrete liner. The reduction of the porosity becomes especially relevant at t=10 4 years. The zones affected by pore clogging at the canister-bentonite and concrete-clay interfaces at 1Ma are approximately equal to 1 and 3.3cm thick, respectively. The hyper-alkaline front (pH>8.5) spreads 2.5cm into the clay formation after 1Ma. Our simulation results share the key features of the models reported by others for engineered barrier systems at similar chemical conditions, including: 1) Pore clogging at the canister-bentonite and concrete-clay interfaces; 2) Narrow alteration zones; and 3) Limited smectite dissolution after 1Ma. Copyright © 2016 Elsevier B.V. All rights reserved.

  14. CONTEXT VIEW ACROSS ORE YARD AT MODERN SELFUNLOADING BOOM IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    CONTEXT VIEW ACROSS ORE YARD AT MODERN SELF-UNLOADING BOOM IN FRONT OF HULETTS. LOOKING SOUTHWEST. - Pennsylvania Railway Ore Dock, Lake Erie at Whiskey Island, approximately 1.5 miles west of Public Square, Cleveland, Cuyahoga County, OH

  15. Simulator Study of Indoor Annoyance Caused by Shaped Sonic Boom Stimuli With and Without Rattle Augmentation

    NASA Technical Reports Server (NTRS)

    Rathsam, Jonathan; Loubeau, Alexandra; Klos, Jacob

    2013-01-01

    The National Aeronautics and Space Administration's High Speed Project is developing a predictive capability for annoyance caused by shaped sonic booms transmitted indoors. The predictive capability is intended for use by aircraft designers as well as by aircraft noise regulators who are considering lifting the current prohibition on overland civil supersonic flight. The goal of the current study is to use an indoor simulator to validate two models developed using headphone tests for annoyance caused by sonic booms with and without rattle augmentation. The predictors in the proposed models include Moore and Glasberg's Stationary Loudness Level, the time derivative of Moore and Glasberg's time-varying short-term Loudness Level, and the difference between two weighted sound exposure levels, CSEL-ASEL. The indoor simulator provides a more realistic listening environment than headphones due to lowfrequency sound reproduction down to 6 Hz, which also causes perceptible tactile vibration. The results of this study show that a model consisting of {PL + (CSEL-ASEL)} is a reliable predictor of annoyance caused by shaped sonic booms alone, rattle sounds alone, and shaped sonic booms and rattle sounds together.

  16. Clay-mineral assemblages from some levels of K-118 drill core of Maha Sarakham evaporites, northeastern Thailand

    NASA Astrophysics Data System (ADS)

    Suwanich, Parkorn

    Clay-mineral assemblages in Middle Clastic, Middle Salt, Lower Clastic, Potash Zone, and Lower Salt, totalling 13 samples from K-118 drill core, in the Maha Sarakham Formation, Khorat Basin, northeastern Thailand were studied. The clay-size particles were separated from the water-soluble salt by water leaching. Then the samples were leached again in the EDTA solution and separated into clay-size particles by using the timing sedimentation. The EDTA-clay residues were divided and analyzed by using the XRD and XRF method. The XRD peaks show that the major-clay minerals are chlorite, illite, and mixed-layer corrensite including traces of rectorite? and paragonite? The other clay-size particles are quartz and potassium feldspar. The XRF results indicate Mg-rich values and moderate MgAl atom ratio values in those clay minerals. The variable Fe, Na, and K contents in the clay-mineral assemblages can explain the environment of deposition compared to the positions of the samples from the core. Hypothetically, mineralogy and the chemistry of the residual assemblages strongly indicate that severe alteration and Mg-enrichment of normal clay detritus occurred in the evaporite environment through brine-sediment interaction. The various Mg-enrichment varies along the various members reflecting whether sedimentation is near or far from the hypersaline brine.

  17. Quantifying the clay content with borehole depth and impact on reservoir flow

    NASA Astrophysics Data System (ADS)

    Sarath Kumar, Aaraellu D.; Chattopadhyay, Pallavi B.

    2017-04-01

    This study focuses on the application of reservoir well log data and 3D transient numerical model for proper optimization of flow dynamics and hydrocarbon potential. Fluid flow through porous media depends on clay content that controls porosity, permeability and pore pressure. The pressure dependence of permeability is more pronounced in tight formations. Therefore, preliminary clay concentration analysis and geo-mechanical characterizations have been done by using wells logs. The assumption of a constant permeability for a reservoir is inappropriate and therefore the study deals with impact of permeability variation for pressure-sensitive formation. The study started with obtaining field data from available well logs. Then, the mathematical models are developed to understand the efficient extraction of oil in terms of reservoir architecture, porosity and permeability. The fluid flow simulations have been done using COMSOL Multiphysics Software by choosing time dependent subsurface flow module that is governed by Darcy's law. This study suggests that the reservoir should not be treated as a single homogeneous structure with unique porosity and permeability. The reservoir parameters change with varying clay content and it should be considered for effective planning and extraction of oil. There is an optimum drawdown for maximum production with varying permeability in a reservoir.

  18. Diffusive transport and reaction in clay rocks: A storage (nuclear waste, CO2, H2), energy (shale gas) and water quality issue

    NASA Astrophysics Data System (ADS)

    Charlet, Laurent; Alt-Epping, Peter; Wersin, Paul; Gilbert, Benjamin

    2017-08-01

    Clay rocks are low permeability sedimentary formations that provide records of Earth history, influence the quality of water resources, and that are increasingly used for the extraction or storage of energy resources and the sequestration of waste materials. Informed use of clay rock formations to achieve low-carbon or carbon-free energy goals requires the ability to predict the rates of diffusive transport processes for chemically diverse dissolved and gaseous species over periods up to thousands of years. We survey the composition, properties and uses of clay rock and summarize fundamental science challenges in developing confident conceptual and quantitative gas and solute transport models.

  19. Neoformation of clay in lateral root catchments of mallee eucalypts: a chemical perspective

    PubMed Central

    Verboom, William H.; Pate, John S.; Aspandiar, Mehrooz

    2010-01-01

    Background and Aims A previous paper (Annals of Botany 103: 673–685) described formation of clayey pavements in lateral root catchments of eucalypts colonizing a recently formed sand dune in south-west Western Australia. Here chemical and morphological aspects of their formation at the site are studied. Methods Chemical and physical examinations of soil cores through pavements and sand under adjacent heath assessed build-up of salts, clay and pH changes in or below pavements. Relationships of root morphology to clay deposition were examined and deposits subjected to scanning electron microscopy and energy-dispersive X-ray analysis. Xylem transport of mineral elements in eucalypt and non-eucalypt species was studied by analysis of xylem (tracheal) sap from lateral roots. Key Results The columns of which pavements are composed develop exclusively on lower-tier lateral roots. Such sites show intimate associations of fine roots, fungal filaments, microbiota and clay deposits rich in Si, Al and Fe. Time scales for construction of pavements by eucalypts were assessed. Cores through columns of pavemented profiles showed gross elevations of bulk density, Al, Fe and Si in columns and related increases in pH, Mg and Ca status in lower profiles. A cutting through the dune exhibited pronounced alkalinity (pH 7–10) under mallee woodland versus acidity (pH 5–6·5) under proteaceous heath. Xylem sap analyses showed unusually high concentrations of Al, Fe, Mg and Si in dry-season samples from column-bearing roots. Conclusions Deposition of Al–Fe–Si-rich clay is pivotal to pavement construction by eucalypts and leads to profound chemical and physical changes in relevant soil profiles. Microbial associates of roots are likely to be involved in clay genesis, with parent eucalypts supplying the required key mineral elements and carbon sources. Acquisition of the Al and Fe incorporated into clay derives principally from hydraulic uplift from ground water via deeply

  20. The Belterra Clay: The Last Terrestrial Connection Between the Brazilian Shield and the Guiana Shield

    NASA Astrophysics Data System (ADS)

    Campbell, K.

    2016-12-01

    The Belterra Clay is a sedimentary deposit that covers much of the eastern Amazon Basin in Brazil. It is notable in forming a very flat plain that occurs on both sides of the Amazon River, the Tapajos River, the Xingu River, and many smaller, tributary rivers east of 56° 32' W. The origin of the Belterra Clay is very controversial, with proponents of both allochthonous and autochthonous means of formation. There is little agreement as to its age. The fact that it occurs on both sides of the Amazon River indicates that its origin predates the formation of the modern Amazon River system, the timing of origin of which is itself highly controversial, with age estimates given for the river system formation that extend from the late Miocene, or 10 mya, to the late Pleistocene. From the time of origin of the Belterra Clay deposit until the modern Amazon River evolved, it formed an unbroken, terrestrial connection between the Brazilian Shield to the south and the Guiana Shield to the north, as well as east-west connections across what are today major river valleys, such as the Tapajos River and Xingu River. The formation and later severing of this once unbroken plain are predicted to have had major impacts on the distribution and evolutionary pathways of biotas inhabiting the region as once disparate communities were joined and later separated once again. Molecular clock ages for sister taxa north and south of the Amazon River have the potential of dating the time of formation of the Amazon River.

  1. GEOS-20 m cable boom mechanism

    NASA Technical Reports Server (NTRS)

    Schmidt, B. K.; Suttner, K.

    1977-01-01

    The GEOS cable boom mechanism allows the controlled deployment of a 20 m long cable in a centrifugal force field. In launch configuration the flat cable is reeled on a 240 mm diameter drum. The electrical connection between the rotating drum and the stationary housing is accomplished via a flexlead positioned inside the drum. Active motion control of this drum is achieved by a self locking worm gear, driven by a stepper motor. The deployment length of the cable is monitored by an optical length indicator, sensing black bars engraved on the cable surface.

  2. Surface Properties and Permeability of Poly(Vinylidene Fluoride)-Clays (PVDF/Clays) Composite Membranes

    NASA Astrophysics Data System (ADS)

    Pramono, E.; Ahdiat, M.; Simamora, A.; Pratiwi, W.; Radiman, C. L.; Wahyuningrum, D.

    2017-07-01

    Surface properties are important factors that determine the performance of ultrafiltration membranes. This study aimed to investigate the effects of clay addition on the surface properties and membrane permeability of PVDF (poly-vinylidene fluoride) membranes. Three types of clay with different particle size were used in this study, namely montmorillonite-MMT, bentonite-BNT and cloisite 15A-CLS. The PVDF-clay composite membranes were prepared by phase inversion method using PEG as additive. The hydrophobicity of membrane surface was characterized by contact angle. The membrane permeability was determined by dead- end ultrafiltration with a trans-membrane pressure of 2 bars. In contact angle measurement, water contact angle of composite membranes is higher than PVDF membrane. The addition of clays decreased water flux but increased of Dextran rejection. The PVDF-BNT composite membranes reach highest Dextran rejection value of about 93%. The type and particle size of clay affected the hydrophobicity of membrane surface and determined the resulting membrane structure as well as the membrane performance.

  3. Sonic Boom Assessment for the Crew Exploration Vehicle

    NASA Technical Reports Server (NTRS)

    Herron, Marissa

    2007-01-01

    The Constellation Environmental Impact Statement (Cx EIS) requires that an assessment be performed on the environmental impact of sonic booms during the reentry of the Crew Exploration Vehicle (CEV). This included an analysis of current planned vehicle trajectories for the Crew Module (CM) and the Service Module (SM) debris and the determination of the potential impact to the overflown environment.

  4. Detection and assessment of secondary sonic booms in New England

    DOT National Transportation Integrated Search

    1980-05-01

    This report documents the results of a secondary sonic boom detection and assessment program conducted by the U.S. Dept. of Transportation, Transportation Systems Center in New England during the summer of 1979. Measurements of both acoustic and infr...

  5. Columns in Clay

    ERIC Educational Resources Information Center

    Leenhouts, Robin

    2010-01-01

    This article describes a clay project for students studying Greece and Rome. It provides a wonderful way to learn slab construction techniques by making small clay column capitols. With this lesson, students learn architectural vocabulary and history, understand the importance of classical architectural forms and their influence on today's…

  6. Clay energetics in chemical evolution

    NASA Technical Reports Server (NTRS)

    Coyne, L. M.

    1986-01-01

    Clays have been implicated in the origin of terrestrial life since the 1950's. Originally they were considered agents which aid in selecting, concentrating and promoting oligomerization of the organic monomeric substituents of cellular life forms. However, more recently, it has been suggested that minerals, with particular emphasis on clays, may have played a yet more fundamental role. It has been suggested that clays are prototypic life forms in themselves and that they served as a template which directed the self-assembly of cellular life. If the clay-life theory is to have other than conceptual credibility, clays must be shown by experiment to execute the operations of cellular life, not only individually, but also in a sufficiently concerted manner as to produce some semblance of the functional attributes of living cells. Current studies are focussed on the ability of clays to absorb, store and transfer energy under plausible prebiotic conditions and to use this energy to drive chemistry of prebiotic relevance. Conclusions of the work are applicable to the role of clays either as substrates for organic chemistry, or in fueling their own life-mimetic processes.

  7. Handling Qualities Prediction of an F-16XL-Based Reduced Sonic Boom Aircraft

    NASA Technical Reports Server (NTRS)

    Cogan, Bruce; Yoo, Seung

    2010-01-01

    A major goal of the Supersonics Project under NASA s Fundamental Aeronautics program is sonic boom reduction of supersonic aircraft. An important part of this effort is development and validation of sonic boom prediction tools used in aircraft design. NASA Dryden s F- 16XL was selected as a potential testbed aircraft to provide flight validation. Part of this task was predicting the handling qualities of the modified aircraft. Due to the high cost of modifying the existing F-16XL control laws, it was desirable to find modifications that reduced the aircraft sonic boom but did not degrade baseline aircraft handling qualities allowing for the potential of flight test without changing the current control laws. This was not a requirement for the initial modification design work, but an important consideration for proceeding to the flight test option. The primary objective of this work was to determine an aerodynamic and mass properties envelope of the F-16XL aircraft. The designers could use this envelope to determine the effect of proposed modifications on aircraft handling qualities.

  8. Crystallization and textural porosity of synthetic clay minerals.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Carrado, K. A.; Csencsits, R.; Thiyagarajan, P.

    2002-12-01

    The crystallization of synthetic layered magnesium silicate hectorite clays from both silica sol and organosilane sources is compared. For the silica sol-derived clays, a templating method is employed wherein organic or polymeric molecules are included during clay crystallization that are then removed from the composites via calcination. The mechanism of silane-derived hectorite formation is followed by XRD, TGA, 29Si MAS NMR, and small angle X-ray scattering (SAXS), and results are compared to those obtained for the sol-derived hectorite. The mechanism appears to be similar but the rate is approximately doubled when the silane is used rather than silica sol. Analyticalmore » transmission electron microscopy (TEM) is exploited to glean structural morphology information towards resolving the nature of the resulting pore network structures. Results are compared with nitrogen adsorption-desorption isotherm behavior; dominant hysteresis loops are present in the type IV isotherms. Pore size distributions based on both the adsorption and desorption isotherms are compared. Small angle neutron scattering (SANS) experiments reveal that the average particle size increases as synthetic laponite < sol-derived hectorite < silane-derived hectorite < natural hectorite. Contrast matching SANS studies in aqueous and organic solvents are carried out to extract information about pore accessibility.« less

  9. Sensitive strata in Bootlegger Cove Formation

    USGS Publications Warehouse

    Olsen, Harold W.

    1989-01-01

    Sensitivity magnitudes are interpreted from remolded strength values in recent subsurface geologic, geotechnical, and geochemical data from the Bootlegger Cove Formation adjacent to the Turnagain Heights Landslide. The results show that strata composed of highly sensitive clays occur in both the middle and lower zones of the formation, and that between these strata the clays are generally of low-to-medium sensitivity. The most sensitive stratum is in the middle zone between two sand layers, and its sensitivity increases from both clay-sand interfaces to a maximum at the center of the stratum. The pore fluid chemistry of the highly sensitive materials differs from that in the materials of low to medium sensitivity only in their concentrations of organic carbon, chloride, bicarbonate, and sulfate. The total dissolved solids concentration is low, and the ratio of monovalent to divalent cations is very high throughout the middle and lower zones of the formation. Of the known causes of high and extremely high sensitivities, only organic and/or anionic dispersants are consistent with these findings.

  10. Geological modeling of a fault zone in clay rocks at the Mont-Terri laboratory (Switzerland)

    NASA Astrophysics Data System (ADS)

    Kakurina, M.; Guglielmi, Y.; Nussbaum, C.; Valley, B.

    2016-12-01

    Clay-rich formations are considered to be a natural barrier for radionuclides or fluids (water, hydrocarbons, CO2) migration. However, little is known about the architecture of faults affecting clay formations because of their quick alteration at the Earth's surface. The Mont Terri Underground Research Laboratory provides exceptional conditions to investigate an un-weathered, perfectly exposed clay fault zone architecture and to conduct fault activation experiments that allow explore the conditions for stability of such clay faults. Here we show first results from a detailed geological model of the Mont Terri Main Fault architecture, using GoCad software, a detailed structural analysis of 6 fully cored and logged 30-to-50m long and 3-to-15m spaced boreholes crossing the fault zone. These high-definition geological data were acquired within the Fault Slip (FS) experiment project that consisted in fluid injections in different intervals within the fault using the SIMFIP probe to explore the conditions for the fault mechanical and seismic stability. The Mont Terri Main Fault "core" consists of a thrust zone about 0.8 to 3m wide that is bounded by two major fault planes. Between these planes, there is an assembly of distinct slickensided surfaces and various facies including scaly clays, fault gouge and fractured zones. Scaly clay including S-C bands and microfolds occurs in larger zones at top and bottom of the Mail Fault. A cm-thin layer of gouge, that is known to accommodate high strain parts, runs along the upper fault zone boundary. The non-scaly part mainly consists of undeformed rock block, bounded by slickensides. Such a complexity as well as the continuity of the two major surfaces are hard to correlate between the different boreholes even with the high density of geological data within the relatively small volume of the experiment. This may show that a poor strain localization occurred during faulting giving some perspectives about the potential for

  11. Air Force Boom Event Analyzer Recorder (BEAR): Comparison with NASA Boom Measurement System

    DTIC Science & Technology

    1988-07-01

    Hemisphere Foam ined stee e ’/ To BEAR. V ib rat ionSeaainDsnc Isolated Nylon m icohn older 3/8ŕ - 18 Diameter Painted Steel Plate Figure 9. AAMRL...d3 0nw Fiur 2. 0 SFBom petrm omarso 38w 0 0- 0 In- WW LL. 0 In 0 to 0 to 0 to 0 to 0 N\\ N - - 0 0 m M OD D (M8 ZHII (SP) -13A3-1 vvnflNL33S 38flsOdX3...ONflos Figure 27. 8 PSF Clean Boom Spectrum Comparison 39 0 0)0LZO (0 < -r- a- U I 0 IL) zw _0 U.) (M1 to) 0 Ito 0 to) 0 to 0 to) 0 N~ N - 0 0 M ) CD O

  12. Early Pottery Making in Northern Coastal Peru. Part I: Mössbauer Study of Clays

    NASA Astrophysics Data System (ADS)

    Shimada, I.; Häusler, W.; Hutzelmann, T.; Wagner, U.

    2003-09-01

    We report on an investigation of several ancient clays which were used for pottery making in northern coastal Peru at a kiln site from the Formative period (ca. 2000-800 BC) in the Poma Canal and at a Middle Sicán pottery workshop in use between ca. AD 950 and 1050 at Huaca Sialupe in the lower La Leche valley. Neutron activation analysis, 57Fe Mössbauer spectroscopy and X-ray diffraction were used for the characterisation of the clays. The changes that occur in iron-bearing compounds in the clays depending on the kiln atmosphere and on the maximum firing temperature were studied by Mössbauer spectroscopy and X-ray diffraction. Laboratory firing series under varying controlled conditions were performed to obtain a basic understanding of the different reactions taking place in the clays during firing. The results can be used as models in the interpretation of the Mössbauer spectra observed in ancient ceramics from the same context.

  13. Reducing the Cation Exchange Capacity of Lithium Clay to Form Better Dispersed Polymer-Clay Nanocomposites

    NASA Technical Reports Server (NTRS)

    Liang, Maggie

    2004-01-01

    Polymer-clay nanocomposites have exhibited superior strength and thermo- oxidative properties as compared to pure polymers for use in air and space craft; however, there has often been difficulty completely dispersing the clay within the matrices of the polymer. In order to improve this process, the cation exchange capacity of lithium clay is first lowered using twenty-four hour heat treatments of no heat, 130 C, 150 C, or 170 C to fixate the lithium ions within the clay layers so that they are unexchangeable. Generally, higher temperatures have generated lower cation exchange capacities. An ion exchange involving dodecylamine, octadecylamine, or dimethyl benzidine (DMBZ) is then employed to actually expand the clay galleries. X-ray diffraction and transmission electron microscopy can be used to determine whether the clay has been successfully exfoliated. Finally, resins of DMBZ with clay are then pressed into disks for characterization using dynamic mechanical analyzer and oven- aging techniques in order to evaluate their glass transition, modulus strength, and thermal-oxidative stability in comparison to neat DMBZ. In the future, they may also be tested as composites for flexural and laminar shear strength.

  14. An exploratory examination of medical gas booms versus traditional headwalls in intensive care unit design.

    PubMed

    Pati, Debajyoti; Evans, Jennie; Waggener, Laurie; Harvey, Tom

    2008-01-01

    Should power, medical gases, and monitoring and communications systems be located in a headwall or a ceiling-mounted boom in intensive care unit (ICU) rooms? Often, only the financial costs could be determined for the options, whereas data regarding its potential influence on teamwork, safety, and efficiency are lacking. Hence, purchase decisions are more arbitrary than evidence based. This study simulated care delivery in settings with a traditional headwall and a ceiling boom. Observed were the way the following elements were managed and the extent either system affected flexibility, ergonomics, and teamwork: tubing for intravenous fluids, medical gases, and suction drainage; monitoring leads and equipment power cords; and the medical equipment itself. Simulation runs involving 6 scenarios were conducted with the voluntary participation of 2 physicians, 2 nurse practitioners, 2 respiratory therapists, and 4 registered nurses at a children's tertiary care center in December 2007. Analysis suggests that booms have an advantage over headwalls in case of high-acuity ICU patients and when procedures are performed inside patient rooms. However, in case of lower-acuity ICU patients, as well as when procedures are not typically conducted in the patient room, booms may not provide a proportionate level of advantage when compared with the additional cost involved in its procurement.

  15. Exhaust Plume Effects on Sonic Boom for a Delta Wing and a Swept Wing-Body Model

    NASA Technical Reports Server (NTRS)

    Castner, Raymond; Lake, Troy

    2012-01-01

    Supersonic travel is not allowed over populated areas due to the disturbance caused by the sonic boom. Research has been performed on sonic boom reduction and has included the contribution of the exhaust nozzle plume. Plume effect on sonic boom has progressed from the study of isolated nozzles to a study with four exhaust plumes integrated with a wing-body vehicle. This report provides a baseline analysis of the generic wing-body vehicle to demonstrate the effect of the nozzle exhaust on the near-field pressure profile. Reductions occurred in the peak-to-peak magnitude of the pressure profile for a swept wing-body vehicle. The exhaust plumes also had a favorable effect as the nozzles were moved outward along the wing-span.

  16. Sonic Boom Propagation Codes Validated by Flight Test

    NASA Technical Reports Server (NTRS)

    Poling, Hugh W.

    1996-01-01

    The sonic boom propagation codes reviewed in this study, SHOCKN and ZEPHYRUS, implement current theory on air absorption using different computational concepts. Review of the codes with a realistic atmosphere model confirm the agreement of propagation results reported by others for idealized propagation conditions. ZEPHYRUS offers greater flexibility in propagation conditions and is thus preferred for practical aircraft analysis. The ZEPHYRUS code was used to propagate sonic boom waveforms measured approximately 1000 feet away from an SR-71 aircraft flying at Mach 1.25 to 5000 feet away. These extrapolated signatures were compared to measurements at 5000 feet. Pressure values of the significant shocks (bow, canopy, inlet and tail) in the waveforms are consistent between extrapolation and measurement. Of particular interest is that four (independent) measurements taken under the aircraft centerline converge to the same extrapolated result despite differences in measurement conditions. Agreement between extrapolated and measured signature duration is prevented by measured duration of the 5000 foot signatures either much longer or shorter than would be expected. The duration anomalies may be due to signature probing not sufficiently parallel to the aircraft flight direction.

  17. CEC-normalized clay-water sorption isotherm

    NASA Astrophysics Data System (ADS)

    Woodruff, W. F.; Revil, A.

    2011-11-01

    A normalized clay-water isotherm model based on BET theory and describing the sorption and desorption of the bound water in clays, sand-clay mixtures, and shales is presented. Clay-water sorption isotherms (sorption and desorption) of clayey materials are normalized by their cation exchange capacity (CEC) accounting for a correction factor depending on the type of counterion sorbed on the mineral surface in the so-called Stern layer. With such normalizations, all the data collapse into two master curves, one for sorption and one for desorption, independent of the clay mineralogy, crystallographic considerations, and bound cation type; therefore, neglecting the true heterogeneity of water sorption/desorption in smectite. The two master curves show the general hysteretic behavior of the capillary pressure curve at low relative humidity (below 70%). The model is validated against several data sets obtained from the literature comprising a broad range of clay types and clay mineralogies. The CEC values, derived by inverting the sorption/adsorption curves using a Markov chain Monte Carlo approach, are consistent with the CEC associated with the clay mineralogy.

  18. Clay fractions from a soil chronosequence after glacier retreat reveal the initial evolution of organo-mineral associations

    NASA Astrophysics Data System (ADS)

    Dümig, Alexander; Häusler, Werner; Steffens, Markus; Kögel-Knabner, Ingrid

    2012-05-01

    Interactions between organic and mineral constituents prolong the residence time of organic matter in soils. However, the structural organization and mechanisms of organic coverage on mineral surfaces as well as their development with time are still unclear. We used clay fractions from a soil chronosequence (15, 75 and 120 years) in the foreland of the retreating Damma glacier (Switzerland) and from mature soils outside the proglacial area (>700 and <3000 years) to elucidate the evolution of organo-mineral associations during initial soil formation. The chemical composition of the clay-bound organic matter (OM) was assessed by solid-state 13C NMR spectroscopy while the quantities of amino acids and neutral sugar monomers were determined after acid hydrolysis. The mineral phase was characterized by X-ray diffraction, oxalate extraction, specific surface area by N2 adsorption (BET approach), and cation exchange capacity at pH 7 (CECpH7). The last two methods were applied before and after H2O2 treatment. We found pronounced shifts in quantity and quality of OM during aging of the clay fractions, especially within the first one hundred years of soil formation. The strongly increasing organic carbon (OC) loading of clay-sized particles resulted in decreasing specific surface areas (SSA) of the mineral phases and increasing CECpH7. Thus, OC accumulation was faster than the supply of mineral surfaces and cation exchange capacity was mainly determined by the OC content. Clay-bound OC of the 15-year-old soils showed high proportions of carboxyl C and aromatic C. This may point to remnants of ancient OC which were inherited from the recently exposed glacial till. With increasing age (75 and 120 years), the relative proportions of carboxyl and aromatic C decreased. This was associated with increasing O-alkyl C proportions, whereas accumulation of alkyl C was mainly detected in clay fractions from the mature soils. These findings from solid-state 13C NMR spectroscopy are in

  19. In Situ Clay Formation: Evaluation of a Proposed New Technology for Stable Containment Barriers

    DTIC Science & Technology

    2004-03-01

    situ layered double hydroxide precipitation........... 23 4.2.1 Solution preparation and column mixing...22 Table 4.2 Summary of in situ precipitation of layered double hydroxide (LDH...effect on permeability for the smallest volume precipitated is sheet silicates or layered -clay phases (hereafter called “clays”). In natural

  20. Measured Effects of Turbulence on the Loudness and Waveforms of Conventional and Shaped Minimized Sonic Booms

    NASA Technical Reports Server (NTRS)

    Plotkin, Kenneth J.; Maglieri, Domenic J.; Sullivan, Brenda M.

    2005-01-01

    Turbulence has two distinctive effects on sonic booms: there is distortion in the form of random perturbations that appear behind the shock waves, and shock rise times are increased randomly. A first scattering theory by S.C. Crow in the late 1960s quantified the random distortions, and Crow's theory was shown to agree with available flight test data. A variety of theories for the shock thickness have been presented, all supporting the role of turbulence in increasing rise time above that of a basic molecular-relaxation structure. The net effect of these phenomena on the loudness of shaped minimized booms is of significant interest. Initial analysis suggests that there would be no change to average loudness, but this had not been experimentally investigated. The January 2004 flight test of the Shaped Sonic Boom Demonstrator (SSBD), together with a reference unmodified F-5E, included a 12500- foot linear ground sensor array with 28 digitally recorded sensor sites. This data set provides an opportunity to re-test Crow's theory for the post-shock perturbations, and to examine the net effect of turbulence on the loudness of shaped sonic booms.