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Sample records for bouri oil field

  1. Abandoned Texas oil fields

    SciTech Connect

    Not Available

    1980-12-01

    Data for Texas abandoned oil fields were primarily derived from two sources: (1) Texas Railroad Commission (TRRC), and (2) Dwight's ENERGYDATA. For purposes of this report, abandoned oil fields are defined as those fields that had no production during 1977. The TRRC OILMASTER computer tapes were used to identify these abandoned oil fields. The tapes also provided data on formation depth, gravity of oil production, location (both district and county), discovery date, and the cumulative production of the field since its discovery. In all, the computer tapes identified 9211 abandoned fields, most of which had less than 250,000 barrel cumulative production. This report focuses on the 676 abandoned onshore Texas oil fields that had cumulative production of over 250,000 barrels. The Dwight's ENERGYDATA computer tapes provided production histories for approximately two-thirds of the larger fields abandoned in 1966 and thereafter. Fields which ceased production prior to 1966 will show no production history nor abandonment date in this report. The Department of Energy hopes the general availability of these data will catalyze the private sector recovery of this unproduced resource.

  2. Oil field management system

    DOEpatents

    Fincke, James R.

    2003-09-23

    Oil field management systems and methods for managing operation of one or more wells producing a high void fraction multiphase flow. The system includes a differential pressure flow meter which samples pressure readings at various points of interest throughout the system and uses pressure differentials derived from the pressure readings to determine gas and liquid phase mass flow rates of the high void fraction multiphase flow. One or both of the gas and liquid phase mass flow rates are then compared with predetermined criteria. In the event such mass flow rates satisfy the predetermined criteria, a well control system implements a correlating adjustment action respecting the multiphase flow. In this way, various parameters regarding the high void fraction multiphase flow are used as control inputs to the well control system and thus facilitate management of well operations.

  3. Oil field geothermal waters of Wyoming

    SciTech Connect

    Hinckley, B.S.

    1983-08-01

    Over 150 million gallons of water a day are brought to the surface in the oil fields of Wyoming. The temperature of this water is nearly always greater than 90/sup 0/F, and ranges as high as 230/sup 0/F. The location, volume, temperature, and present use status of co-produced oil field thermal waters are presented briefly.

  4. Organic geochemistry of oils from Oil Spring and Florence oil field near Canon City, Colorado

    USGS Publications Warehouse

    Lillis, P.G.; Dolan, Michael P.; Warden, Augusta; King, J.D.

    1998-01-01

    Oil Spring is an oil seep located approximately 6 miles north of Ca?on City, Colorado. The purpose of this study is to determine whether the oil from Oil Spring and the oil from nearby Florence oil field share a common source. Bulk and molecular geochemical analyses show that the oil seep is most likely derived from a group of geochemically similar Cretaceous source rocks including the Carlile Shale, Greenhorn Limestone, Graneros Shale, and the Mowry Shale. The Florence oil is derived from the Sharon Springs Member of the Upper Cretaceous Pierre Shale.

  5. Classroom in the Oil Fields.

    ERIC Educational Resources Information Center

    Hammond, Jeanne

    1980-01-01

    Describes a petroleum production program created in Bradford, Pennsylvania, by oil company executives and local educators to answer the need of the regional oil industry for trained manpower. Discusses the need for the program, the search for qualified teachers, funding, and how one student feels about the program. (CT)

  6. OIL AND GAS FIELD EMISSIONS SURVEY

    EPA Science Inventory

    The report gives results of an oil and gas field emissions survey. The production segment of the oil and gas industry has been identified as a source category that requires the development of more reliable emissions inventory methodologies. The overall purpose of the project was ...

  7. Remediation of oil field wastes

    SciTech Connect

    Peters, R.W.; Wentz, C.A.

    1990-01-01

    Treatment and disposal of drilling muds and hazardous wastes has become a growing concern in the oil and gas industry. Further, past practices involving improper disposal require considerable research and cost to effectively remediate contaminated soils. This paper investigates two case histories describing the treatments employed to handle the liquid wastes involved. Both case histories describe the environmentally safe cleanup operations that were employed. 1 ref., 1 fig., 3 tabs.

  8. Methanogenic Oil Degradation in the Dagang Oil Field

    NASA Astrophysics Data System (ADS)

    Jiménez, Núria; Cai, Minmin; Straaten, Nontje; Yao, Jun; Richnow, Hans Hermann; Krüger, Martin

    2014-05-01

    Anaerobic biodegradation is one of the main in situ oil transformation processes in subsurface oil reservoirs. Recent studies have provided evidence of biodegradation of residual oil constituents under methanogenic conditions. Methane, like other biogenic gases, may contribute to reduce the viscosity of oil and enhance its flow characteristics (making it more available) but it can also be used as a energy source. So the aim of the present study was to provide reliable information on in situ biotransformation of oil under methanogenic conditions, and to assess the feasibility of implementing a MEOR strategy at this site. For this reason, chemical and isotopic analyses of injection and production fluids of the Dagang oil field (Hebei province, China) were performed. Microbial abundances were assessed by qPCR, and clone libraries were performed to study the diversity. In addition, microcosms with either oil or 13C-labelled hydrocarbons were inoculated with injection or production waters to characterize microbial processes in vitro. Geochemical and isotopic data were consistent with in situ biogenic methane production linked to aliphatic and aromatic hydrocarbon degradation: GC-MS profiles of petroleum samples were nearly devoid of n-alkanes, linear alkylbenzenes, and alkyltoluenes, and light PAH, confirming that Dagang oil is mostly highly weathered. In addition, carbon and hydrogen isotopic signatures of methane (δ13CCH4 and δDCH4, respectively), and the bulk isotopic discrimination (Δδ13C) between methane and CO2 (between 32 and 65 ) were in accordance with previously reported values for methane formation during hydrocarbon degradation. Furthermore, methane-producing Archaea and hydrocarbon-degrading Bacteria were abundant in produced oil-water samples. On the other hand, our laboratory degradation experiments revealed that autochthonous microbiota are capable of significantly degrade oil within several months, with biodegradation patterns resembling those observed in situ, and of producing heavy methane from 13C-labelled n-hexadecane or 2-methylnaphthalene (δ13C > 550 and 300, respectively). These results suggest that in situ methanogenesis may occur from the aliphatic and polyaromatic fractions of Dagang reservoir fluids. In summary, the studied areas of the Dagang oilfield may have a significant potential for the in situ conversion of oil into methane as a possible way to increase total hydrocarbon recovery.

  9. A field laboratory for improved oil recovery

    SciTech Connect

    Hildebrandt, A.F.; McDonald, J.; Claridge, E.; Killough, J.

    1992-09-01

    The purpose of Annex III of the Memorandum of Understanding, undertaken by the Houston Petroleum Research Center at the University of Houston, was to develop a field laboratory for research in improved oil recovery using a Gulf Coast reservoir in Texas. The participants: (1) make a field site selection and conducted a high resolution seismic survey in the demonstration field, (2) obtained characteristics of the reservoir (3) developed an evaluation of local flood efficiency in different parts of the demonstration reservoir, (4) used diverse methodology to evaluate the potential recovery of the remaining oil in the test reservoir, (5) developed cross-well seismic tomography, and (6) will transfer the learned technologies to oil operators through publication and workshops. This abstract is an overview of these tasks.

  10. Use of magnetic field aids oil search

    SciTech Connect

    Not Available

    1992-05-04

    Efficient oil and gas exploration requires the measurement of the earth's magnetic field with the ability to determine and remove with high accuracy that part of the signal caused by changes in the magnetic basement, and measurement of rock drill cuttings when possible, only to add confidence that the magnetic mineral body is authigenic in origin (created in place), and not detrital. This paper reports that results show that anomalous areas developed from aeromagnetic data and drill holes shown to have anomalous authigenic altered drill cuttings are both 80-85% probable of oil and natural gas discovery, and similarly those areas not anomalous in either are 10-15% probable of oil and gas discovery. The method involves the gathering of low terrain clearance high resolution data of the earth's magnetic field using the cesium vapor magnetometer or equivalent.

  11. Sacha oil field of Ecuadorian Oriente

    SciTech Connect

    Canfield, R.W.; Bonilla, G.; Robbins, R.K.

    1982-08-01

    The Sacha oil field in the Ecuadorian Oriente was discovered in early 1969. Production began in July 1972, and at the end of 1980 had exceeded 190 million bbl. Drilling through 1980 had resulted in 91 oil wells and 2 dry holes. Estimated original primary recoverable reserves surpass 632 million bbl. The field is on a very low-relief anticline about 17.5 mi (28 km) long and averaging 4 mi (6.5 km) wide. Vertical closure amounts to 200 ft (60 m) and there are 41,000 acres (16,600 ha.) of areal closure on top of the principal reservoir. The Cretaceous sandstones, at drilled depths between 9,300 and 10,100 ft (2,835 and 3,080 m) provide excellent reservoirs. The Hollin Formation, the basal Cretaceous sandstone, is the principal reservoir, having produced 80% of the oil through 1980 and containing about 68% of the original reserves.

  12. Field evaluations of marine oil spill bioremediation.

    PubMed Central

    Swannell, R P; Lee, K; McDonagh, M

    1996-01-01

    Bioremediation is defined as the act of adding or improving the availability of materials (e.g., nutrients, microorganisms, or oxygen) to contaminated environments to cause an acceleration of natural biodegradative processes. The results of field experiments and trials following actual spill incidents have been reviewed to evaluate the feasibility of this approach as a treatment for oil contamination in the marine environment. The ubiquity of oil-degrading microorganisms in the marine environment is well established, and research has demonstrated the capability of the indigenous microflora to degrade many components of petroleum shortly after exposure. Studies have identified numerous factors which affect the natural biodegradation rates of oil, such as the origin and concentration of oil, the availability of oil-degrading microorganisms, nutrient concentrations, oxygen levels, climatic conditions, and sediment characteristics. Bioremediation strategies based on the application of fertilizers have been shown to stimulate the biodegradation rates of oil in aerobic intertidal sediments such as sand and cobble. The ratio of oil loading to nitrogen concentration within the interstitial water has been identified to be the principal controlling factor influencing the success of this bioremediation strategy. However, the need for the seeding of natural environments with hydrocarbon-degrading bacteria has not been clearly demonstrated under natural environmental conditions. It is suggested that bioremediation should now take its place among the many techniques available for the treatment of oil spills, although there is still a clear need to set operational limits for its use. On the basis of the available evidence, we have proposed preliminary operational guidelines for bioremediation on shoreline environments. PMID:8801437

  13. Field evaluations of marine oil spill bioremediation.

    PubMed

    Swannell, R P; Lee, K; McDonagh, M

    1996-06-01

    Bioremediation is defined as the act of adding or improving the availability of materials (e.g., nutrients, microorganisms, or oxygen) to contaminated environments to cause an acceleration of natural biodegradative processes. The results of field experiments and trials following actual spill incidents have been reviewed to evaluate the feasibility of this approach as a treatment for oil contamination in the marine environment. The ubiquity of oil-degrading microorganisms in the marine environment is well established, and research has demonstrated the capability of the indigenous microflora to degrade many components of petroleum shortly after exposure. Studies have identified numerous factors which affect the natural biodegradation rates of oil, such as the origin and concentration of oil, the availability of oil-degrading microorganisms, nutrient concentrations, oxygen levels, climatic conditions, and sediment characteristics. Bioremediation strategies based on the application of fertilizers have been shown to stimulate the biodegradation rates of oil in aerobic intertidal sediments such as sand and cobble. The ratio of oil loading to nitrogen concentration within the interstitial water has been identified to be the principal controlling factor influencing the success of this bioremediation strategy. However, the need for the seeding of natural environments with hydrocarbon-degrading bacteria has not been clearly demonstrated under natural environmental conditions. It is suggested that bioremediation should now take its place among the many techniques available for the treatment of oil spills, although there is still a clear need to set operational limits for its use. On the basis of the available evidence, we have proposed preliminary operational guidelines for bioremediation on shoreline environments. PMID:8801437

  14. Oil field water handling: qualitative separation equals theory plus judgment

    SciTech Connect

    Bradley, B.W.

    1985-10-14

    One of the most prevalent problems in oil field operations is the coproduction of oil and formation water, and the resulting problem of qualitative separation of water and oil. This article discusses the separation and handling of oil field brines. Oil dispersions can be cleaned up by a variety of devices which use gravity as the principal separating mechanism. Acceptable practices for disposing of oil-field brine produced with the crude oil include: injection into permeable underground formations containing saline water; reuse for supplementary recovery operations; and deoiling treatment acceptable for ocean disposal.

  15. Development of Sirikit oil field, Thailand

    SciTech Connect

    Brooks, J.

    1986-07-01

    The Sirikit oil field, Thailand's first significant oil find, was discovered in late 1981 by Thai Shell Exploration and Production Company, Ltd., with its second exploration well. After deciding to develop the field (named after Thailand's queen), Thai Shell took only 1 year to design and install the production station, and organize an unconventional evacuation system (road tanker and railway) before oil came on stream in January 1983. A series of facility upgradings kept pace with the production buildup, to a plateau of about 21,000 b/d. The crude oil is waxy (pour point = about 35/sup 0/C), but it is light (40/sup 0/ API) and has an attractive refinery yield. Associated gas is sold to the nearby (specially installed) electricity generating station. Gas compression was commissioned in 1985 to increase utilization of gas, which previously was flared. The agricultural environment dictated the need for cluster drilling of deviated wells, as well as highlighting the importance of good relationships with the local population and authorities. Safety and security are of particular interest. The field is geologically complex, being very faulted in a lacustrine environment and extremely stratified and heterogeneous in reservoir quality. One of two major reservoirs has a gas cap. After some early surprises in delineating the field, a three-dimensional seismic survey was conducted, which better defined the structure and the reserve potential. Nevertheless, parallel appraisal and development continues on a careful step-by-step approach, using the latest production and pressure data to refine the reservoir geologic model. In November 1985, the Petroleum Authority of Thailand became a minority partner, with Shell remaining as operator.

  16. A model of peak production in oil fields

    NASA Astrophysics Data System (ADS)

    Abrams, Daniel M.; Wiener, Richard J.

    2010-01-01

    We developed a model for oil production on the basis of simple physical considerations. The model provides a basic understanding of Hubbert's empirical observation that the production rate for an oil-producing region reaches its maximum when approximately half the recoverable oil has been produced. According to the model, the oil production rate at a large field must peak before drilling peaks. We use the model to investigate the effects of several drilling strategies on oil production. Despite the model's simplicity, predictions for the timing and magnitude of peak production match data on oil production from major oil fields throughout the world.

  17. Assessment of remaining recoverable oil in selected major oil fields of the San Joaquin Basin, California

    USGS Publications Warehouse

    Tennyson, Marilyn E.; Cook, Troy A.; Charpentier, Ronald R.; Gautier, Donald L.; Klett, Timothy R.; Verma, Mahendra K.; Ryder, Robert T.; Attanasi, E.D.; Freeman, P.A.; Le, Phoung A.

    2012-01-01

    The U.S. Geological Survey (USGS) recently completed an estimate of volumes of technically recoverable, conventional oil that could eventually be added to reserves in nine selected major oil fields in the San Joaquin Basin in central California. The mean total volume of potential oil reserves that might be added in the nine fields using improved oil-recovery technologies was estimated to be about 6.5 billion barrels of oil.

  18. The Heidrun Field: Oil offtake system

    SciTech Connect

    Rajabi, F.D.; Breivik, K.; Syvertsen, K.

    1996-12-31

    Offtake of oil from the Heidrun field is achieved through a Direct Shuttle Loading (DSL) system. This approach eliminates the need for an intermediate storage facility, allowing continuous production and transfer of oil directly from the Heidrun TLP to shuttle tankers. Purpose-built or appropriately converted tankers with an integral bow turret locate and connect to a Submerged Turret Loading (STL) buoy which functions both as a tanker mooring point and a termination for the flexible offloading line. The system is designed to permit the tankers to remain connected during loading and to disengage from the STL buoy on completion of loading in all weather conditions up to and including the 100 year storm. This paper describes implementation of the Heidrun DSL system from conception to first oil. It gives the background for choosing the DSL system and information on the data generated to support the selection process. Design, fabrication and installation of various components are explained to give an insight into the challenges that had to be overcome for realization of this first-of-its-kind system in a record time of about one year. Installation of the complete DSL system in the summer of 1994, approximately one year ahead of the original plans, enabled full scale in situ testing of the system with a purpose-modified shuttle tanker. The two-month test program provided the equivalent of one year of operational experience with the system before first oil. The paper addresses data obtained during the full scale testing, and comparison with analytical results. The operation of the Heidrun DSL system is also described. These data together with the experience gained during realization of this bold concept will give key information on how such a concept can be effectively applied to any major or marginal field development scenario either as an offtake system or in conjunction with an FPSO/FSO.

  19. Oil and gas field code master list, 1993

    SciTech Connect

    Not Available

    1993-12-16

    This document contains data collected through October 1993 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. Other Federal and State government agencies, as well as industry, use the EIA Oil and Gas Field Code Master List as the standard for field identification. A machine-readable version of the Oil and Gas Field Code Master List is available from the National Technical Information Service.

  20. Gullfaks oil field - From challenge to success

    SciTech Connect

    Carlsen, H.; Nygaard, O. )

    1990-09-01

    The giant Gullfaks oil field was discovered in 1978. The field contains oil reserves in excess of 1.3 billion bbl. The field is located in the northeastern past of Block 34/10 in the Norwegian sector of the North Sea. Gullfaks represents the shallowest structural element of the Tampen Spur and was formed during the Late Jurassic to Early Cretaceous as a sloping high with a westerly structural dip gradually decreasing toward the east. The major north-south-striking faults, with easterly sloping fault planes, divided the field into several rotated fault blocks. Central and eastern parts of the structure have been eroded by the Early Cretaceous transgression. The reservoir sandstones are comprised of the Middle Jurassic to Early Cretaceous as a sloping high with a westerly structural dip gradually decreasing toward the east. The major north-south-striking faults, with easterly sloping fault planes, divided the field into several rotated fault blocks. Central and eastern parts of the structure have been eroded by the Early Cretaceous transgression. The reservoir sandstones are comprised of the Middle Jurassic delta-deposited Brent Group, the Lower Jurassic shallow-marine sandstones of the Cook Formation, and the Lower Jurassic shallow-marine sandstones of the Cook Formation, and the Lower Jurassic fluvial channel and delta-plain deposits of the Statfjord Formation. The presence of gas in the post-Jurassic section and a variable water depth have complicated seismic interpretation. However, the improved quality of the 1985 three dimensional seismic survey and deliberate deepening of the development wells have resulted in a more accurate and complete structural interpretation. The Brent reserves in the western part of the field currently are being developed by the Gullfaks A and B platforms. The eastern part of the field is developed by a third platform, Gulflaks C. Water injection is the major drive mechanism maintaining reservoir pressure above the bubble point.

  1. Halophilic archaebacteria from the Kalamkass oil field

    SciTech Connect

    Zvyagintseva, I.S.; Belyaev, S.S.; Borzenkov, I.A.; Kostrikina, N.A.; Milekhina, E.I.; Ivanov, M.V.

    1995-01-01

    Two strains of halophilic archaebacteria, growing in a medium containing from 10 to 25% NaCl, were isolated from the brines of the Kalamkass (Mangyshlak) oil field. Both strains are extremely halophilic archaebacteria according to the complex of their phenotypic properties. Strain M-11 was identified as Haloferax mediterranei on the basis of the composition of polar lipids and DNA-DNA homology. The composition of polar lipids and 16S rRNA sequence of strain M-18 allowed us to assign it to the genus Haloferax. This strain differs from the approved species of the genus Haloferax, H. volcanii, and H. mediterranei. However, to describe it as a new species, additional investigations are necessary. 13 refs., 3 figs.

  2. Landslide oil field, San Joaquin Valley, California

    SciTech Connect

    Collins, B.P.; March, K.A.; Caballero, J.S.; Stolle, J.M.

    1988-03-01

    The Landslide field, located at the southern margin of the San Joaquin basin, was discovered in 1985 by a partnership headed by Channel Exploration Company, on a farm out from Tenneco Oil Company. Initial production from the Tenneco San Emidio 63X-30 was 2064 BOPD, making landslide one of the largest onshore discoveries in California during the past decade. Current production is 7100 BOPD from a sandstone reservoir at 12,500 ft. Fifteen wells have been drilled in the field, six of which are water injectors. Production from the Landslide field occurs from a series of upper Miocene Stevens turbidite sandstones that lie obliquely across an east-plunging structural nose. These turbidite sandstones were deposited as channel-fill sequences within a narrowly bounded levied channel complex. Both the Landslide field and the larger Yowlumne field, located 3 mi to the northwest, comprise a single channel-fan depositional system that developed in the restricted deep-water portion of the San Joaquin basin. Information from the open-hole logs, three-dimensional surveys, vertical seismic profiles, repeat formation tester data, cores, and pressure buildup tests allowed continuous drilling from the initial discovery to the final waterflood injector, without a single dry hole. In addition, the successful application of three-dimensional seismic data in the Landslide development program has helped correctly image channel-fan anomalies in the southern Maricopa basin, where data quality and severe velocity problems have hampered previous efforts. New exploration targets are currently being evaluated on the acreage surrounding the Landslide discovery and should lead to an interesting new round of drilling activity in the Maricopa basin.

  3. Method of determining interwell oil field fluid saturation distribution

    DOEpatents

    Donaldson, Erle C.; Sutterfield, F. Dexter

    1981-01-01

    A method of determining the oil and brine saturation distribution in an oil field by taking electrical current and potential measurements among a plurality of open-hole wells geometrically distributed throughout the oil field. Poisson's equation is utilized to develop fluid saturation distributions from the electrical current and potential measurement. Both signal generating equipment and chemical means are used to develop current flow among the several open-hole wells.

  4. Tires fuel oil field cement manufacturing

    SciTech Connect

    Caveny, B.; Ashford, D.; Garcia, J.G.; Hammack, R.

    1998-08-31

    In a new process, waste automobile tires added to the fuel mix of gas, coal, and coke help fire kilns to produce API-quality oil field cement. Capital Cement uses this process in its cement-manufacturing plant in San Antonio, in which it also produces construction cement. The tires provide a lower-cost fuel and boost the temperature at a critical stage in the kiln burn process. Also, steel-belted tires add iron content to the mix. According to lab results, tire-burned cement slurries will perform the same as conventionally burned cement slurries. Actual field applications have proven that cement produced by burning tires performs no different than conventionally produced slurries. Capital`s plant uses both dry and wet processes, with separate kilns running both processes at the same time. Cement clinker is partially fired by waste tires in both kiln processes. The tires represent 12% of the fuel consumed by the plant, a number that is expected to increase. Capital burns about 200 tires/hr, or about 1.6 million tires/year.

  5. Oil and Gas Field Code Master List 1990

    SciTech Connect

    Not Available

    1991-01-04

    This is the ninth annual edition of the Energy Information Administration's (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1990 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. There are 54,963 field records in this year's Oil and Gas Field Code Master List (FCML). This amounts to 467 more than in last year's report. As it is maintained by EIA, the Master List includes: Field records for each state and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides;field records for each alias field name; fields crossing state boundaries that may be assigned different names by the respective state naming authorities.

  6. Kill fluid for oil field operations

    SciTech Connect

    Sydansk, R.D.

    1990-08-14

    This patent describes a process employing a kill fluid to substantially reduce the volumetric flow of formation fluid into a wellbore penetrating a formation containing the formation fluid below an earthen surface. It comprises: admixing components of a continuous flowing gel at the surface comprising of water-soluble carboxylate-containing polymer, a complex capable of crosslinking the polymer and formed of at least one electropositive chromium III species and at least one electronegative carboxylatespecies, and an aqueous solvent for the polymer and the complex; crosslinking the polymer and the complex to form the gel, wherein the kill fluid comprises the gel; placing a volume of the kill fluid in the wellbore sufficient to create a hydrostatic head which exerts a kill fluid pressure against the formation fluid substantially equal to or greater than the formation fluid pressure and thereby substantially reduces the volumetric flow of the formation fluid into the wellbore; performing an oil field operation after placing the volume of the kill fluid in the wellbore; and removing the gel from the wellbore to substantially restore the volumetric flow of the formation fluid into the wellbore.

  7. Coreflood assay using extremophile microorganisms for recovery of heavy oil in Mexican oil fields.

    PubMed

    Castorena-Cortés, Gladys; Roldán-Carrillo, Teresa; Reyes-Avila, Jesús; Zapata-Peñasco, Icoquih; Mayol-Castillo, Martha; Olguín-Lora, Patricia

    2012-10-01

    A considerable portion of oil reserves in Mexico corresponds to heavy oils. This feature makes it more difficult to recover the remaining oil in the reservoir after extraction with conventional techniques. Microbial enhanced oil recovery (MEOR) has been considered as a promising technique to further increase oil recovery, but its application has been developed mainly with light oils; therefore, more research is required for heavy oil. In this study, the recovery of Mexican heavy oil (11.1°API and viscosity 32,906 mPa s) in a coreflood experiment was evaluated using the extremophile mixed culture A7, which was isolated from a Mexican oil field. Culture A7 includes fermentative, thermophilic, and anaerobic microorganisms. The experiments included waterflooding and MEOR stages, and were carried out under reservoir conditions (70°C and 9.65 MPa). MEOR consisted of injections of nutrients and microorganisms followed by confinement periods. In the MEOR stages, the mixed culture A7 produced surface-active agents (surface tension reduction 27 mN m⁻¹), solvents (ethanol, 1738 mg L⁻¹), acids (693 mg L⁻¹), and gases, and also degraded heavy hydrocarbon fractions in an extreme environment. The interactions of these metabolites with the oil, as well as the bioconversion of heavy oil fractions to lighter fractions (increased alkanes in the C₈-C₃₀ range), were the mechanisms responsible for the mobility and recovery of heavy oil from the porous media. Oil recovery by MEOR was 19.48% of the residual oil in the core after waterflooding. These results show that MEOR is a potential alternative to heavy oil recovery in Mexican oil fields. PMID:22704814

  8. Using InSAR to Analyze the Effects of Oil Extraction on the Kuparuk Oil Field

    NASA Astrophysics Data System (ADS)

    Baluyut, E.; Liu, L.; Zebker, H. A.

    2012-12-01

    Ground deformation around oil fields is a major concern in regards to the impacts of this human-induced change on the environment. Interferometric synthetic aperture radar (InSAR) was used to map the ground deformation in the area of the Kuparuk Oil Field in Northern Alaska from 2007 to 2010. Data packages from the Advanced Land Observation Satellite (ALOS) and corresponding data for the digital elevation model (DEM) were used to create interferograms and the DEM. This was done using MATLAB and Python on a Linux operating system. Selected interferograms were cropped and errors from noise, topography, or atmosphere were minimized through fitting and stacking techniques. After analysis, the InSAR data yielded a chronology of a change in ground deformation around the Kuparuk Oil Field, which is correlated to a history of recovery techniques. Analysis of interferograms from before, in transition, and after application of different techniques can determine patterns of ground deformation in the field. It was found that positive ground deformation was more prevalent before the implementation of new oil recovery techniques as opposed to after implementation, with negative ground deformation occurring during the transition of the applications that allowed for more productive oil extraction. These results quantitatively demonstrate the magnitude of land subsidence that actively recovered oil fields induce. They also suggest that new methods of enhanced oil recovery are stabilizing the subterranean layers being drilled, creating a decrease in positive land deformation. This could support the continuation of research in fields of enhanced oil recovery and carbon sequestration.

  9. Environmental contamination in the oil fields of western Pennsylvania

    USGS Publications Warehouse

    Albers, P.H.; Belisle, A.A.; Swineford, D.M.; Hall, R.J.

    1985-01-01

    The effects on freshwater wildlife of chronic exposure to oil field discharges are not well known. Collections of wastewater, aquatic invertebrates, fish, salamanders, and small mammals were made in several streams in the oil fields of western Pennsylvania during 1980-81. Estimates of the petroleum content of two wastewater discharges were high (21.9 and 8.4 ppm) and one was low (0.3 ppm). Water conductivity was inversely related to aquatic invertebrate biomass. Hydrocarbons accumulated in significantly greater amounts in crayfish, fish, and small mammals from collection sites with oil extraction activity than from sites without oil extraction activity. Estimates of total petroleum in invertebrates, trout, and suckers averaged between 200 and 280 ppm for oil extraction sites and between 8 and 80 ppm for sites without oil extraction activity: Oil extraction activity did not affect metal accumulation by fish. Oil and wastewater discharges in oil fields disrupt community composition and can cause an overall reduction in stream productivity.

  10. Oil field waste disposal costs at commercial disposal facilities

    SciTech Connect

    Veil, J.A.

    1997-10-01

    The exploration and production segment of the U.S. oil and gas industry generates millions of barrels of nonhazardous oil field wastes annually. In most cases, operators can dispose of their oil fields wastes at a lower cost on-site than off site and, thus, will choose on-site disposal. However, a significant quantity of oil field wastes are still sent to off-site commercial facilities for disposal. This paper provides information on the availability of commercial disposal companies in different states, the treatment and disposal methods they employ, and how much they charge. There appear to be two major off-site disposal trends. Numerous commercial disposal companies that handle oil field wastes exclusively are located in nine oil-and gas-producing states. They use the same disposal methods as those used for on-site disposal. In addition, the Railroad Commission of Texas has issued permits to allow several salt caverns to be used for disposal of oil field wastes. Twenty-two other oil- and gas-producing states contain few or no disposal companies dedicated to oil and gas industry waste. The only off-site commercial disposal companies available handle general industrial wastes or are sanitary landfills. In those states, operators needing to dispose of oil field wastes off-site must send them to a local landfill or out of state. The cost of off-site commercial disposal varies substantially, depending on the disposal method used, the state in which the disposal company is located, and the degree of competition in the area.

  11. Oil and Gas field code master list 1995

    SciTech Connect

    1995-12-01

    This is the fourteenth annual edition of the Energy Information Administration`s (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1995 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the US. The Field Code Index, a listing of all field names and the States in which they occur, ordered by field code, has been removed from this year`s publications to reduce printing and postage costs. Complete copies (including the Field Code Index) will be available on the EIA CD-ROM and the EIA World-Wide Web Site. Future editions of the complete Master List will be available on CD-ROM and other electronic media. There are 57,400 field records in this year`s Oil and Gas Field Code Master List. As it is maintained by EIA, the Master List includes the following: field records for each State and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides; field records for each alias field name (see definition of alias below); and fields crossing State boundaries that may be assigned different names by the respective State naming authorities. Taking into consideration the double-counting of fields under such circumstances, EIA identifies 46,312 distinct fields in the US as of October 1995. This count includes fields that no longer produce oil or gas, and 383 fields used in whole or in part for oil or gas Storage. 11 figs., 6 tabs.

  12. Horizontal well taps bypassed Dundee oil in Crystal field, Mich.

    SciTech Connect

    Wood, J.R.; Allan, J.R.; Huntoon, J.E.; Pennington, W.D.; Harrison, W.B. III; Taylor, E.; Tester, C.J.

    1996-10-21

    The Dundee formation (Middle Devonian) has yielded more oil than any other producing interval in Michigan. The Dundee trend, which forms an east-west band across the central Michigan basin, consists of 137 fields which together have yielded more than 350 million bbl of oil. The first commercial Dundee production was established at Mt. Pleasant field in 1928, and most Dundee fields were discovered and brought on production during the 1930s--40s. Wells in many of the fields had very high initial production (IP) rates. IPs in excess of 1,000 b/d of oil were common, with values as high as 9,000 b/d reported. These high flow rates, combined with a thin (10--30 ft) oil column and a strong water drive, resulted in water coning that left significant volumes of oil unrecovered in some fields. One such field, Crystal field in Montcalm County, is the focus of a US Department of energy (DOE) Class 2 Reservoir Demonstration Project designed to demonstrate that horizontal drilling can recover significant volumes of this bypassed oil. The paper describes the demonstration project, regional setting, and the history of the Crystal field.

  13. Assessment of remaining recoverable oil in selected major oil fields of the Permian Basin, Texas and New Mexico

    USGS Publications Warehouse

    Tennyson, Marilyn E.; Cook, Troy A.; Charpentier, Ronald R.; Gautier, Donald L.; Klett, Timothy R.; Verma, Mahendra K.; Ryder, Robert T.; Attanasi, E.D.; Freeman, P.A.; Le, Phoung A.

    2012-01-01

    The U.S. Geological Survey (USGS) recently completed an estimate of technically recoverable, conventional oil in selected oil fields in the Permian Basin in west Texas and southeastern New Mexico. The mean total volume of potential additional oil resources that might be added using improved oil-recovery technologies was estimated to be about 2.7 billion barrels of oil.

  14. Characterizing Air Toxics from Oil Field Operations in Los Angeles

    NASA Astrophysics Data System (ADS)

    McCarthy, M. C.; Brown, S. G.; DeWinter, J. L.; Bai, S.; O'Brien, T.; Vaughn, D.; Peltier, R.; Soltis, J.; Field, R. A.; Murphy, S. M.; Roberts, P. T.

    2014-12-01

    The Inglewood Oil Field in urban Los Angeles has been in operation for more than 70 years. Neighborhoods surrounding the oil field are concerned with the potential emissions of air toxics from oil field operations. The Baldwin Hills Air Quality Study focused on (1) quantifying air toxics concentrations originating from the Inglewood Oil Field operations, including drilling and well workovers, and (2) assessing the health risk of both acute and chronic exposure to air toxics emitted from oil field operations. Key pollutants identified for characterization included diesel particulate matter (DPM), cadmium, benzene, nickel, formaldehyde, mercury, manganese, acrolein, arsenic, and lead. The field study began in November 2012 and ended in November 2013. Four types of instruments were used to characterize oil field operations: (1) Aethalometers to measure black carbon (BC; as a proxy for DPM); (2) X-ray fluorescence spectrometer (XRF) for metals; (3) Proton-Transfer-Reaction Time-of-Flight Mass Spectrometry (PTR-TOFMS) for volatile organic compounds; and (4) meteorological sensors to help assess the wind patterns, temperature, and humidity that influence pollutant concentrations. Overall concentrations of most of the species measured in the study were quite low for an urban area. We determined that there were statistically significant increases in concentrations of DPM associated with oil field operations when winds were from the west-southwest. BC concentrations increased by 0.036 to 0.056 μg/m3, on average, when winds originated from the west-southwest, compared to annual mean BC concentrations of approximately 0.67 μg/m3. West-southwest winds occurred 53% of the time during the study. No other pollutants showed strong statistical evidence of chronic or acute risk from oil field operations.

  15. Distribution of oil and gas fields in China offshore basins

    SciTech Connect

    Gong, Zaisheng; Yang Jiaming )

    1996-01-01

    China offshore basins have been explored for more than ten years by ourselves, corporation, and cooperation with foreign oil companies. Large sums of seismic data have been acquired, and several hundreds of wells have been drilled. The present daily production in these basins is 250,000 barrels of oil and 350 MMCF of gas. The activity of exploration and development in these basins makes it possible for us to have some knowledge about the distribution of oil and gas fields. The origin, classification, feature, and general petroleum geology in these oil-bearing basins have been studied according to the tectonic-thermal regime types of these basins. Hydrocarbon is heterogeneously distributed in each depression in the basins. High abundance of hydrocarbon resources are only distributed in few depressions with high richness of hydrocarbon generation. The origin and distribution of these [open quotes]rich[close quotes] depressions have been described. Different types of basins have their unique oil-pool-generating models. That the accumulation of hydrocarbon is controlled by [open quotes]rich[close quotes] oil-pool-forming systems is illustrated with the typical cases of discovered oil and gas fields. At last, the potential hydrocarbon resources, direction, and field for exploration have been pointed out in these offshore basins. The distribution of oil and gas has been described with detailed and abundant data, so that more than twenty figures and more than ten tables are contained in the paper.

  16. Distribution of oil and gas fields in China offshore basins

    SciTech Connect

    Gong, Zaisheng; Yang Jiaming

    1996-12-31

    China offshore basins have been explored for more than ten years by ourselves, corporation, and cooperation with foreign oil companies. Large sums of seismic data have been acquired, and several hundreds of wells have been drilled. The present daily production in these basins is 250,000 barrels of oil and 350 MMCF of gas. The activity of exploration and development in these basins makes it possible for us to have some knowledge about the distribution of oil and gas fields. The origin, classification, feature, and general petroleum geology in these oil-bearing basins have been studied according to the tectonic-thermal regime types of these basins. Hydrocarbon is heterogeneously distributed in each depression in the basins. High abundance of hydrocarbon resources are only distributed in few depressions with high richness of hydrocarbon generation. The origin and distribution of these {open_quotes}rich{close_quotes} depressions have been described. Different types of basins have their unique oil-pool-generating models. That the accumulation of hydrocarbon is controlled by {open_quotes}rich{close_quotes} oil-pool-forming systems is illustrated with the typical cases of discovered oil and gas fields. At last, the potential hydrocarbon resources, direction, and field for exploration have been pointed out in these offshore basins. The distribution of oil and gas has been described with detailed and abundant data, so that more than twenty figures and more than ten tables are contained in the paper.

  17. Largest US oil and gas fields, August 1993

    SciTech Connect

    Not Available

    1993-08-06

    The Largest US Oil and Gas Fields is a technical report and part of an Energy Information Administration (EIA) series presenting distributions of US crude oil and natural gas resources, developed using field-level data collected by EIA`s annual survey of oil and gas proved reserves. The series` objective is to provide useful information beyond that routinely presented in the EIA annual report on crude oil and natural gas reserves. These special reports also will provide oil and gas resource analysts with a fuller understanding of the nature of US crude oil and natural gas occurrence, both at the macro level and with respect to the specific subjects addressed. The series` approach is to integrate EIA`s crude oil and natural gas survey data with related data obtained from other authoritative sources, and then to present illustrations and analyses of interest to a broad spectrum of energy information users ranging from the general public to oil and gas industry personnel.

  18. Repair wind field in oil contaminated areas with SAR images

    NASA Astrophysics Data System (ADS)

    Guo, Jie; He, Yijun; Long, Xiao; Hou, Chawei; Liu, Xin; Meng, Junmin

    2015-03-01

    In this paper, we compared the normalized radar cross section in the cases of oil spill, biogenic slicks, and clean sea areas with image samples made from 11-pixel NRCS average, and determined their thresholds of the NRCS of the synthetic aperture radar. The results show that the thresholds of oil and biogenic slicks exhibit good consistency with the corresponding synthetic aperture radar images. In addition, we used the normalized radar cross section of clean water from adjacent patches of oil or biogenic slicks areas to replace that of oil or biogenic slicks areas, and retrieve wind field by CMOD5.n and compare wind velocity mending of oil and biogenic slicks areas with Weather Research and Forecasting modeled data, from which the root mean squares of wind speed (wind direction) inversion are 0.89 m/s (20.26°) and 0.88 m/s (7.07°), respectively. Therefore, after the occurrence of oil spill or biogenic slicks, the real wind field could be repaired using the method we introduced in this paper. We believe that this method could improve the accuracy in assessment of a real wind field on medium and small scales at sea, and enhance effectively the monitoring works on similar oil or biogenic slicks incidents at sea surface.

  19. Oil and gas field code master list 1994

    SciTech Connect

    Not Available

    1995-01-01

    This is the thirteenth annual edition of the Energy Information Administration`s (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1994 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. The master field name spellings and codes are to be used by respondents when filing the following Department of Energy (DOE) forms: Form EIA-23, {open_quotes}Annual Survey of Domestic Oil and Gas Reserves,{close_quotes} filed by oil and gas well operators (field codes are required from larger operators only); Forms FERC 8 and EIA-191, {open_quotes}Underground Gas Storage Report,{close_quotes} filed by natural gas producers and distributors who operate underground natural gas storage facilities. Other Federal and State government agencies, as well as industry, use the EIA Oil and Gas Field Code Master List as the standard for field identification. A machine-readable version of the Oil and Gas Field Code Master List is available from the National Technical Information Service, 5285 Port Royal Road, Springfield, Virginia 22161, (703) 487-4650. In order for the Master List to be useful, it must be accurate and remain current. To accomplish this, EIA constantly reviews and revises this list. The EIA welcomes all comments, corrections, and additions to the Master List. All such information should be given to the EIA Field Code Coordinator at (214) 953-1858. EIA gratefully acknowledges the assistance provides by numerous State organizations and trade associations in verifying the existence of fields and their official nomenclature.

  20. Polarimetric SAR Models for Oil Fields Monitoring in China Seas

    NASA Astrophysics Data System (ADS)

    Buono, A.; Nunziata, F.; Li, X.; Wei, Y.; Ding, X.

    2014-11-01

    In this study, physical-based models for polarimetric Synthetic Aperture Radar (SAR) oil fields monitoring are proposed. They all share a physical rationale relying on the different scattering mechanisms that characterize a free sea surface, an oil slick-covered sea surface, and a metallic target. In fact, sea surface scattering is well modeled by a Bragg-like behaviour, while a strong departure from Bragg scattering is in place when dealing with oil slicks and targets. Furthermore, the proposed polarimetric models aim at addressing simultaneously target and oil slick detection, providing useful extra information with respect to single-pol SAR data in order to approach oil discrimination and classification. Experiments undertaken over East and South China Sea from actual C-band RadarSAT-2 full-pol SAR data witness the soundness of the proposed rationale.

  1. Oil and gas field code master list 1997

    SciTech Connect

    1998-02-01

    The Oil and Gas Field Code Master List 1997 is the sixteenth annual listing of all identified oil and gas fields in the US. It is updated with field information collected through October 1997. The purpose of this publication is to provide unique, standardized codes for identification of domestic fields. Use of these field codes fosters consistency of field identification by government and industry. As a result of their widespread adoption they have in effect become a national standard. The use of field names and codes listed in this publication is required on survey forms and other reports regarding field-specific data collected by EIA. There are 58,366 field records in this year`s FCML, 437 more than last year. The FCML includes: field records for each State and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides; field records for each alias field name (definition of alias is listed); fields crossing State boundaries that may be assigned different names by the respective State naming authorities. This report also contains an Invalid Field Record List of 4 records that have been removed from the FCML since last year`s report. These records were found to be either technically incorrect or to represent field names which were never recognized by State naming authorities.

  2. Laboratory studies of oil spill bioremediation; toward understanding field behavior

    SciTech Connect

    Prince, R.C.; Hinton, S.M.; Elmendorf, D.L.; Lute, J.R.; Grossman, M.J.; Robbins, W.K.; Hsu, Chang S.; Richard, B.E.; Haith, C.E.; Senius, J.D.; Minak-Bernero, V.; Chianelli, R.R.; Bragg, J.R.; Douglas, G.S.

    1993-12-31

    Oil spill remediation aims to enhance the natural process of microbial hydrocarbon biodegradation. The microbial foundations have been studied throughout this century, but the focus of most of this work has been on the degradation of well defined compounds by well defined microbial species. This paper addresses laboratory studies on crude oil biodegradation by microbial consortia obtained from oiled beaches in Prince William Sound, Alaska following the spill from the Exxon Valdez. It demonstrates that oil degradation is indeed likely to be nitrogen-limited in Prince William Sound, the different molecular classes in crude oil that are subjected to biodegradation, the identification of conserved species in the oil that can be used for assessing biodegradation and bioremediation in the field, the effectiveness of fertilizers in stimulating sub-surface biodegradation, the role of the olephilic fertilizer Inipol EAP22, and the identification of the oil-degrading microorganisms in Prince William Sound. Together, these laboratory studies provided guidance and important insights into the microbial phenomena underlying the successful bioremediation of the oiled shorelines.

  3. Verifying a Simplified Fuel Oil Field Measurement Protocol

    SciTech Connect

    Henderson, Hugh; Dentz, Jordan; Doty, Chris

    2013-07-01

    The Better Buildings program is a U.S. Department of Energy program funding energy efficiency retrofits in buildings nationwide. The program is in need of an inexpensive method for measuring fuel oil consumption that can be used in evaluating the impact that retrofits have in existing properties with oil heat. This project developed and verified a fuel oil flow field measurement protocol that is cost effective and can be performed with little training for use by the Better Buildings program as well as other programs and researchers.

  4. Verifying a Simplified Fuel Oil Flow Field Measurement Protocol

    SciTech Connect

    Henderson, H.; Dentz, J.; Doty, C.

    2013-07-01

    The Better Buildings program is a U.S. Department of Energy program funding energy efficiency retrofits in buildings nationwide. The program is in need of an inexpensive method for measuring fuel oil consumption that can be used in evaluating the impact that retrofits have in existing properties with oil heat. This project developed and verified a fuel oil flow field measurement protocol that is cost effective and can be performed with little training for use by the Better Buildings program as well as other programs and researchers.

  5. Hydrocarbon emissions in the Bakken oil field in North Dakota

    NASA Astrophysics Data System (ADS)

    Mielke-Maday, I.; Petron, G.; Miller, B.; Frost, G. J.; Peischl, J.; Kort, E. A.; Smith, M. L.; Karion, A.; Dlugokencky, E. J.; Montzka, S. A.; Sweeney, C.; Ryerson, T. B.; Tans, P. P.; Schnell, R. C.

    2014-12-01

    Within the past five years, the production of oil and natural gas in the United States from tight formations has increased rapidly due to advances in technology, such as horizontal drilling and hydraulic fracturing. With the expansion of oil and natural gas extraction operations comes the need to better quantify their emissions and potential impacts on climate forcing and air quality. The Bakken formation within the Williston Basin in North Dakota has emerged as a large contributor to the recent growth in oil production and accounts for over 10% of domestic production. Close to 30% of associated gas co-produced with the oil is flared. Very little independent information is currently available to assess the oil and gas industry emissions and their impacts on regional air quality. In May 2014, an airborne field campaign was conducted by the National Oceanic and Atmospheric Administration's (NOAA) Earth System Research Laboratory and the University of Michigan to investigate hydrocarbon emissions from operations in the oil field. Here, we present results from the analysis for methane, several non-methane hydrocarbons and combustion tracers in 72 discrete air samples collected by the aircraft on nine different flights. Samples were obtained in the boundary layer upwind and downwind of the operations and in the free troposphere. We will show results of a multiple species analysis and compare them with field campaign data from other U.S. oil and gas fields, measurements from NOAA's Global Monitoring Division long-term observing network, and available bottom-up information on emissions from oil and gas operations.

  6. Environmental assessment of an oil field prior to redevelopment

    SciTech Connect

    Ferguson, E. Jr.; Smith, E.A.

    1995-09-01

    A statistical and directed soil sampling approach, using {open_quotes}spot trenching{close_quotes} and GeoProbe techniques, to characterize an active oil field prior to redevelopment. As land uses change, environmental characterization of the subject area is often required to assess future development opportunities. This is evident in areas that have been historically used for oil production but declining oil production in the field has produced undeveloped land available for future development. The area discussed in this paper is a 63-acre section, within an oil field in Southern California, expected to be developed in the next three to five years as a golf course. The purpose of this remedial investigation was to assess the soil conditions and determine the most advantageous remediation techniques, if needed, for future land use. The methodology of the investigation needed to complement the redevelopment goals for an effective property transfer. Use of aerial photographs to identify potential source areas combined with aggressive and innovative field sampling strategies reduced the cost and increased the effectiveness of the investigation. Spot trenching and sampling of oil sumps and tank batteries identified on aerial photographs was used to identify the crude oil and benzene, toluene, ethylbenzene and xylenes (BTEX) aspect of the oil production. Statistical sampling using a {open_quotes}GeoProbe{close_quotes},an in situ sampling method, for the remainder of the site identified chemicals not commonly associated with oil production (organic compounds and metals). These techniques of sampling achieved a 90 percent confidence level that the entire site had characterized. The results allowed the McLaren/Hart to determine impacted areas and volumes of soil affected. Thus allowing cost of development to be projected prior to development of the property.

  7. [Production of oil-processing compounds by microorganisms from the Daqing oil field, China].

    PubMed

    Nazina, T N; Sokolova, D Sh; Grigor'ian, A A; Xue, Y F; Beliaev, S S; Ivanov, M V

    2003-01-01

    Twenty pure cultures isolated from formation waters of the Daqing oil field were studied with respect to their capacity to produce surface-active compounds in media with individual hydrocarbons, lower alcohols, and fatty acids. Aerobic saprotrophic bacteria belonging to the genera Bacillus, Brevibacillus, Rhodococcus, Dietzia, Kocuria, Gordonia, Cellulomonas, Clavibacter, Pseudomonas, and Acinetobacter decreased the surface tension of cultivation media from 55-63 to 28-44 mN/m. Strains of Bacillus cereus, Rhodococcus ruber, and Bacillus licheniformis produced biosurfactants most actively. Bacteria of the genera Rhodococcus, Dietzia, Kocuria, and Gordonia produced exopolysaccharides in media with hydrocarbons. Culture liquids of the strains of R. ruber and B. licheniformis exhibited oil-releasing effect. Thus, the Daqing oil field is inhabited by aerobic bacteria capable of producing effective oil-releasing agents. PMID:12751245

  8. Distribution of Thermophilic Marine Sulfate Reducers in North Sea Oil Field Waters and Oil Reservoirs

    PubMed Central

    Nilsen, R. K.; Beeder, J.; Thorstenson, T.; Torsvik, T.

    1996-01-01

    The distribution of thermophilic marine sulfate reducers in produced oil reservoir waters from the Gullfaks oil field in the Norwegian sector of the North Sea was investigated by using enrichment cultures and genus-specific fluorescent antibodies produced against the genera Archaeoglobus, Desulfotomaculum, and Thermodesulforhabdus. The thermophilic marine sulfate reducers in this environment could mainly be classified as species belonging to the genera Archaeoglobus and Thermodesulforhabdus. In addition, some unidentified sulfate reducers were present. Culturable thermophilic Desulfotomaculum strains were not detected. Specific strains of thermophilic sulfate reducers inhabited different parts of the oil reservoir. No correlation between the duration of seawater injection and the numbers of thermophilic sulfate reducers in the produced waters was observed. Neither was there any correlation between the concentration of hydrogen sulfide and the numbers of thermophilic sulfate reducers. The results indicate that thermophilic and hyperthermophilic sulfate reducers are indigenous to North Sea oil field reservoirs and that they belong to a deep subterranean biosphere. PMID:16535321

  9. A field laboratory for improved oil recovery. Final report

    SciTech Connect

    Hildebrandt, A.F.; McDonald, J.; Claridge, E.; Killough, J.

    1992-09-01

    The purpose of Annex III of the Memorandum of Understanding, undertaken by the Houston Petroleum Research Center at the University of Houston, was to develop a field laboratory for research in improved oil recovery using a Gulf Coast reservoir in Texas. The participants: (1) make a field site selection and conducted a high resolution seismic survey in the demonstration field, (2) obtained characteristics of the reservoir (3) developed an evaluation of local flood efficiency in different parts of the demonstration reservoir, (4) used diverse methodology to evaluate the potential recovery of the remaining oil in the test reservoir, (5) developed cross-well seismic tomography, and (6) will transfer the learned technologies to oil operators through publication and workshops. This abstract is an overview of these tasks.

  10. Alkanes in shrimp from the Buccaneer Oil Field

    SciTech Connect

    Middleditch, B.S.; Basile, B.; Chang, E.S.

    1982-07-01

    A total of 36 samples of shrimp were examined from the region of the Buccaneer oil field, eighteen of which were representatives of the commercial species Penaeus aztecus and the rest were various other species: Penaeus duorarum (pink shrimp), Trachypenaeus duorarum (sugar shrimp), Squilla empusa (mantis shrimp), and Sicyonia dorsalis (chevron shrimp). The alkanes and deuteriated alkanes were completely separated by GC, so a mass spectrometer was not required for their detection and quantitation. To confirm the identities of individual compounds, however, some samples were examined by combined gas chromatography-mass spectrometry. Results show that only thirteen of the forty shrimp collected from the region of the Buccaneer oil field contained petroleum alkanes, and the majority of these were obtained from trawls immediately adjacent to the production platforms. It appears that shrimp caught in the region of the Buccaneer oil field are not appreciably tainted with hydrocarbons discharged from the production platforms. (JMT)

  11. Measuring marine oil spill extent by Markov Random Fields

    NASA Astrophysics Data System (ADS)

    Moctezuma, Miguel; Parmiggiani, Flavio; Lopez Lopez, Ludwin

    2014-10-01

    The Deepwater Horizon oil spill of the Gulf of Mexico in the spring of 2010 was the largest accidental marine oil spill in the history of the petroleum industry. An immediate request, after the accident, was to detect the oil slick and to measure its extent: SAR images were the obvious tool to be employed for the task. This paper presents a processing scheme based on Markov Random Fields (MRF) theory. MRF theory describes the global information by probability terms involving local neighborhood representations of the SAR backscatter data. The random degradation introduced by speckle noise is dealt with a pre-processing stage which applies a nonlinear diffusion filter. Spatial context attributes are structured by the Bayes equation derived from a Maximum-A-Posteriori (MAP) estimation. The probability terms define an objective function of a MRF model whose goal is to detect contours and fine structures. The markovian segmentation problem is solved with a numerical optimization method. The scheme was applied to an Envisat/ASAR image over the Gulf of Mexico of May 9, 2010, when the oil spill was already fully developed. The final result was obtained with 51 recursion cycles, where, at each step, the segmentation consists of a 3-class label field (open sea and two oil slick thicknesses). Both the MRF model and the parameters of the stochastic optimization procedure will be provided, together with the area measurement of the two kinds of oil slick.

  12. Oil-field equipment in Romania. Export trade information

    SciTech Connect

    Tinis, R.

    1991-09-01

    The Industry Sector Analyses (I.S.A.) for oil field equipment contains statistical and narrative information on projected market demand, end-users, receptivity of Romanian consumers to U.S. products, the competitive situation - Romanian production, total import market, U.S. market position, foreign competition, and competitive factors, and market access - Romanian tariffs, non-tariff barriers, standards, taxes and distribution channels. The I.S.A. provides the United States industry with meaningful information regarding the Romanian market for oil field equipment.

  13. Biodiesel Prepared From Field Pennycress Oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Field pennycress (Thlaspi arvense L., FP) is a winter annual species of the mustard family (Brassicaceae) which is widely distributed throughout temperate North America that can serve as a winter rotational crop for conventional crops, thus not displacing farm land or negatively impacting the food s...

  14. The Application Of Microbial Enhanced Oil Recovery On Unconventional Oil: A Field Specific Approach

    NASA Astrophysics Data System (ADS)

    Goodman, Sean; Millar, Andrew; Allison, Heather; McCarthy, Alan

    2014-05-01

    A substantial amount of the world's recoverable oil reserves are made from unconventional or heavy resources. However, great difficulty has been had in recovering this oil after primary and secondary recovery methods have been employed. Therefore, tertiary methods such as microbial enhanced oil recovery (MEOR) have been employed. MEOR involves the use of bacteria and their metabolic products to alter the oil properties or rock permeability within a reservoir in order to promote the flow of oil. Although MEOR has been trialed in the past with mixed outcomes, its feasibility on heavier oils has not been demonstrated. The aim of this study is to show that MEOR can be successfully applied to unconventional oils. By using an indigenous strain of bacteria isolated from a reservoir of interest and applied to field specific microcosms, we will look into the effect of these bacteria compared to variant inoculums to identify which mechanisms of action the bacteria are using to improve recovery. Using this information, we will be able to identify genes of interest and groups of bacteria that may be beneficial for MEOR and look accurately identify favorable bacteria within a reservoir.

  15. Processing of coal, oil sand and heavy oil in situ by electric and magnetic fields

    NASA Astrophysics Data System (ADS)

    Fisher, S. T.

    1980-07-01

    Improvements to a previously proposed (Fisher, 1979) means for the underground processing of coal, oil sand and heavy oil using eddy currents induced by an alternating magnetic field are presented. Consideration is given to the injection into the fuel layer by pressure from the surface of a hot, saturated high-conductivity aqueous electrolyte solution, which would allow induction heating to depend entirely on low-frequency eddy currents, and to the use of an outer tube of copper welded to an inner tube of steel for the tunnel and shaft casings and electrical conductors of the underground eddy-current heating installation. The physical and operational parameters of the proposed modifications are given, and it is shown that these improvements would increase the performance margin of the eddy-current heating method over the proposed dielectric heating method for oil shale and oil sand deposits.

  16. Extraction of Field Pennycress Seed Oil by Full Pressing

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Field pennycress (Thlasphi arvense L., Brassicaceae) is a winter annual that grows widely in the temperate North America. Its seeds contain up to 36% oil (db) with the major fatty acid as erucic acid (38%). With an estimated seed production of 1,700 – 2,200 kg/ha, pennycress can be a major source of...

  17. Carcinogenic potential of PAHs in oil-contaminated soils from the main oil fields across China.

    PubMed

    Wang, Jie; Cao, Xiaofeng; Liao, Jingqiu; Huang, Yi; Tang, Xiaoyan

    2015-07-01

    The concentrations, composition profiles, and sources of polycyclic aromatic hydrocarbons (PAHs) were analyzed in 55 surface soil samples collected from four oil fields across China (Daqing, DQ; Shengli, SL; Xinjiang, XJ; and Huabei, HB). The total 16 priority PAHs concentrations of DQ, SL, XJ, and HB ranged from 857 to 27,816; 480 to 20,625; 497 to 43,210; and 12,112 to 45,325 ng/g, respectively, with means of 9160; 6394; 13,569; and 22,954 ng/g and the seven possible carcinogenic PAHs accounted for 8-25.7 % of the total PAHs. Almost all the samples were heavily contaminated, and phenanthrene, chrysene, and pyrene were the most dominant components. The PAH isomeric ratios indicated that PAHs in oil fields mainly originated from petroleum. The toxic assessment illustrated that people living and working in oil fields would suffer low carcinogenic risk, which was somehow coincided with the results of epidemiological survey on cancer incidence. It seems essential to pay more attention to the chronic human health effects of exposure to oil fields and to focus new studies on the public health field that involves a large number of people all over the world. PMID:25772862

  18. Crosshole EM for oil field characterization and EOR monitoring: Field examples

    SciTech Connect

    Wilt, M.; Schenkel, C.; Lee, K.; Torrses-Verdin, C.; Tseng, H.

    1994-12-31

    Crosshole and surface-to-borehole electromagnetic (EM) imaging is applied to reservoir characterization and steam flood monitoring in a central California oil field. Steam was injected into 3 stacked eastward dipping unconsolidated oil sands. EM measurements were made from two fiberglass-cased observation wells straddling the steam injector on a northeast-southwest profile. Field data were collected before the initiation of a steam drive to map the distribution of the oil sands and then six months after the steam was injected to monitor the progress of the steam chest. Resistivity images derived from the collected data could clearly delineate the distribution and dipping structure on the target oil sands. Difference images from data collected before and after steam flooding indicate that the steam chest has developed only in the deeper oil sands and it has preferentially migrated eastward.

  19. Giant oil fields of the Gulf Coast area

    SciTech Connect

    Haeberle, F.R.

    1993-09-01

    The 134 giant fields in the Gulf Coastal area contain 29% of the total giant-field reserves. Cumulative production is 32% of the giant-field cumulative total and 20% of the United States cumulative production. Eighty-nine of the giant fields are offshore with 22% of the reserves, 11 fields are in east Texas with 24% of the reserves, and 1 field is in Florida with 1% of the reserves. In 106 of the giant fields the primary producing interval is Cenozoic with 65% of the reserves, and in 28 giant fields the producing interval is Mesozoic with 35% of the reserves. The primary producing interval is Mesozoic with 35% of the reserves. The primary producing interval in 124 giant fields consists of clastics with 91% of the reserves, in 7 fields the primary lithology is carbonates with 6% of the reserves, and in 3 giant fields the lithology is mixed clastics and carbonates. A total of 127 fields are in structural traps with all of the reserves, 4 fields are stratigraphic traps (3%) with 18% of the reserves, and 3 fields are combination traps with 1% of the reserves. Over 50 of the giant oil fields in structural traps are salt domes. The most prevalent types of giant fields in the Gulf Coastal area are onshore structural traps with Cenozoic clastics as the primary producing intervals.

  20. Reverse osmosis process successfully converts oil field brine into freshwater

    SciTech Connect

    Tao, F.T.; Curtice, S.; Hobbs, R.D.; Sides, J.L.; Wieser, J.D. ); Dyke, C.A.; Tuohey, D. ); Pilger, P.F. )

    1993-09-20

    A state-of-the-art process in the San Ardo oil field converted produced brine into freshwater. The conversion process used chemical clarification, softening, filtration, and reverse osmosis (RO). After extensive testing resolved RO membrane fouling problems, the pilot plant successfully handled water with about 7,000 mg/l. of total dissolved solids, 250 mg/l. silica, and 170 mg/l. soluble oil. The treated water complies with the stringent California drinking water standard. The paper describes water reclamation, the San Ardo process, stability, reverse osmosis membrane fouling, membranes at high pH, water quality, and costs.

  1. Dispersant and fluid loss additives for oil field cements

    SciTech Connect

    George, C.; Gerke, R. R.

    1985-12-10

    Dispersants and fluid loss additives for inclusion in oil field cements and methods of using the resultant compositions in oil, gas and water well cementing operations are disclosed. Such compositions incorporate a polymeric additive prepared by caustic-catalyzed condensation for formaldehyde with acetone, or a substance derived from acetone, wherein said polymer includes sodium sulfonate groups in an amount sufficient to render such polymer water soluble. A second fluid loss additive such as hydroxyethyl cellulose, carboxymethylhydroxyethyl cellulose, copolymers of N,N-dimethylacrylamide and 2-acrylamido, 2-methyl propane sulfonic acid or copolymers of acrylamide and 2-acrylamido, 2-methyl propane sulfonic acid may optionally be included.

  2. Oil mining field test to start in East Texas

    SciTech Connect

    See, M.

    1996-11-01

    Before year-end 1996, PetroTech Resources Corp. (PRC) of Fort Worth, Texas, will begin mobilizing for construction of a non-conventional quaternary-oil-recovery project in Corsicana field, in Navarro County, Texas, some 50 miles SSE of Dallas. The project will involve construction of large-diameter vertical and horizontal access shafts for people and equipment to some 70 feet below the bottom of the 820-ft deep reservoir, then upward drilling of multiple oil production boreholes into the reservoir and collection of oil moving to a subterranean manifold by gravity drainage. PRC calls the process Mining-Assisted Petroleum Development (MAPD). Project background and the developer`s objectives are explained here, along with an overview of principal features of the proprietary process and basic equipment to be used by several contractors.

  3. Bird mortality in oil field wastewater disposal facilities.

    PubMed

    Ramirez, Pedro

    2010-11-01

    Commercial and centralized oilfield wastewater disposal facilities (COWDFs) are used in the Western United States for the disposal of formation water produced from oil and natural gas wells. In Colorado, New Mexico, Utah, and Wyoming, COWDFs use large evaporation ponds to dispose of the wastewater. Birds are attracted to these large evaporation ponds which, if not managed properly, can cause wildlife mortality. The U.S. Fish and Wildlife Service (USFWS) and the U.S. Environmental Protection Agency (EPA) conducted 154 field inspections of 28 COWDFs in Wyoming from March 1998 through September 2008 and documented mortality of birds and other wildlife in 9 COWDFs. Of 269 bird carcasses recovered from COWDFs, grebes (Family Podicipedidae) and waterfowl (Anatidae) were the most frequent casualties. Most mortalities were attributed to oil on evaporation ponds, but sodium toxicity and surfactants were the suspected causes of mortality at three COWDFs. Although the oil industry and state and federal regulators have made much progress in reducing bird mortality in oil and gas production facilities, significant mortality incidents continue in COWDFs, particularly older facilities permitted in the early 1980's. Inadequate operation and management of these COWDFs generally results in the discharge of oil into the large evaporation ponds which poses a risk for birds and other wildlife. PMID:20844874

  4. Bird Mortality in Oil Field Wastewater Disposal Facilities

    NASA Astrophysics Data System (ADS)

    Ramirez, Pedro

    2010-11-01

    Commercial and centralized oilfield wastewater disposal facilities (COWDFs) are used in the Western United States for the disposal of formation water produced from oil and natural gas wells. In Colorado, New Mexico, Utah, and Wyoming, COWDFs use large evaporation ponds to dispose of the wastewater. Birds are attracted to these large evaporation ponds which, if not managed properly, can cause wildlife mortality. The U.S. Fish and Wildlife Service (USFWS) and the U.S. Environmental Protection Agency (EPA) conducted 154 field inspections of 28 COWDFs in Wyoming from March 1998 through September 2008 and documented mortality of birds and other wildlife in 9 COWDFs. Of 269 bird carcasses recovered from COWDFs, grebes (Family Podicipedidae) and waterfowl (Anatidae) were the most frequent casualties. Most mortalities were attributed to oil on evaporation ponds, but sodium toxicity and surfactants were the suspected causes of mortality at three COWDFs. Although the oil industry and state and federal regulators have made much progress in reducing bird mortality in oil and gas production facilities, significant mortality incidents continue in COWDFs, particularly older facilities permitted in the early 1980’s. Inadequate operation and management of these COWDFs generally results in the discharge of oil into the large evaporation ponds which poses a risk for birds and other wildlife.

  5. DOE tallies Class III oil recovery field projects

    SciTech Connect

    Not Available

    1994-07-25

    Here are details from midterm proposals submitted as part of the US Department of Energy's Class 3 oil recovery field demonstration candidate projects. All of the proposals emphasize dissemination of project details so that the results, if successful, can be applied widely in similar reservoirs. Project results will also be fed into a national petroleum technology transfer network. The proposals include: Gulf of Mexico, Gulf coast, offshore California, a California thermal, immiscible CO[sub 2], produced/potable water, microbial EOR, California diatomite, West Texas Spraberry field, and other Permian Basin fields.

  6. Strategies for field application of foams in heavy oil reservoirs

    SciTech Connect

    Isaacs, E.E.; Ivory, J.; Law, D.H.S.

    1995-12-31

    Steam-based processes in heavy oil reservoirs that are not stabilized by gravity have poor vertical and areal conformance. This is because gases are more mobile within the pore space than liquids and steam tends to override or channel through oil in a formation. The steam-foam process which consists of adding surfactant with or without non-condensible gas to the injected steam, was developed to improve the sweep efficiency of steam drive and cyclic steam processes. The foam-forming components injected with the steam stabilize the liquid lamellae and cause some of the steam to exist as a discontinuous phase. The steam mobility (gas relative permeability) is thereby reduced resulting in an increased pressure gradient in the steam-swept region, to divert steam to the unheated interval and displace the heated oil better. The propagation of surfactant in the reservoir is determined by its thermal stability, adsorption, precipitation, and oil partitioning behaviour. The propagation of the foam is determined by the mechanisms that generate and destroyfoam in the reservoir, including gas and liquid velocities, condensation and evaporation, non-condensible gas, and the presence of oil. Strategies were developed to minimize the chemical requirements for generating effective steam-foams. Economic steam-foam processes requires that surfactant losses are minimized, foam propagation and foam stability is maximized at surfactant concentrations lower than has hereto been used in the field. This paper, based on laboratory finding and field experience, discusses the important considerations which affect the efficient application of steam-foam in the field.

  7. Clay-oil droplet suspensions in electric fields

    NASA Astrophysics Data System (ADS)

    Rozynek, Zbigniew; Fossum, Jon Otto; Kjerstad, Knut; Mikkelsen, Alexander; Castberg, Rene

    2012-02-01

    Silicone oil droplets containing synthetic smectite clay submerged in immiscible organic oil have been studied by observing clay particle movement and oil circulation when an electric field is applied. Results show how electric field strength, dielectric and electrorheological properties as well as electrohydrodynamics determine the fluid flow and clay particle formation. In a presence of the DC electric fields the clay particles formed a ribbon-like structure onto the inner surface of the droplet. The structure consists of short chain-like clay elements orienting parallel to the electric field direction. It is suggested that a combination of two phenomena, namely the induced viscous flow (electrohydrodynamic effect) and the polarization of the clay particles (dielectric effect), contribute to the ribbon-like structure formation. -/abstract- References [1] G. Taylor, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences 291 (1966) 159--166. [2] J. R. Melcher and G. I. Taylor, Annual Review of Fluid Mechanics 1 (1969) 111--146. [3] H. Sato, N. Kaji, T. Mochizuki, and Y. H. Mori, Physics of Fluids 18 (2006) 127101. [4] D. A. Saville, Annual Review of Fluid Mechanics 29 (1997) 27--64. [5] J. O. Fossum, Y. M'eheust, K. P. S. Parmar, K. D. Knudsen, K. J. Måløy, and D. M. Fonseca Europhysics Letters 74

  8. Crosshole EM for oil field characterization and EOR monitoring: Field examples from Lost Hills, California

    SciTech Connect

    Wilt, M.; Schenkel, C.; Wratcher, M.; Lambert, I.; Torres-Verdin, C.; Tseng H.W.

    1996-07-16

    A steamflood recently initiated by Mobil Development and Production U.S. at the Lost Hills No 3 oil field in California is notable for its shallow depth and the application of electromagnetic (EM) geophysical techniques to monitor the subsurface steam flow. Steam was injected into three stacked eastward-dipping unconsolidated oil sands at depths from 60 to 120 m; the plume is expected to develop as an ellipsoid aligned with the regional northwest-southeast strike. Because of the shallow depth of the sands and the high viscosity of the heavy oil, it is important to track the steam in the unconsolidated sediments for both economic and safety reasons. Crosshole and surface-to-borehole electromagnetic imaging were applied for reservoir characterization and steamflood monitoring. The crosshole EM data were collected to map the interwell distribution of the high-resistivity oil sands and to track the injected steam and hot water. Measurements were made in two fiberglass-cased observation wells straddling the steam injector on a northeast-southwest profile. Field data were collected before the steam drive, to map the distribution of the oil sands, and then 6 and 10 months after steam was injected, to monitor the expansion of the steam chest. Resistivity images derived from the collected data clearly delineated the distribution and dipping structure of the target oil sands. Difference images from data collected before and during steamflooding indicate that the steam chest has developed only in the middle and lower oil sands, and it has preferentially migrated westward in the middle oil sand and eastward in the deeper sand. Surface-to-borehole field data sets at Lost Hills were responsive to the large-scale subsurface structure but insufficiently sensitive to model steam chest development in the middle and lower oil sands. As the steam chest develops further, these data will be of more use for process monitoring.

  9. Earthquakes in the oil field at Rangely, Colorado

    USGS Publications Warehouse

    Gibbs, James F.; Healy, John H.; Raleigh, C. Barry; Coakley, John M.

    1972-01-01

    Seven years of seismic data recorded at the Uinta Basin Observatory were searched for earthquakes originating near an oil field at Rangely, Colorado, located 65 km ESE of the observatory. Changes in the number of earthquakes recorded per year appear to correlate with changes in the quantity of fluid injected per year. Between November 1962 and January 1970, 976 earthquakes were detected near the oil field by the UBO station; 320 earthquakes were larger than magnitude 1. Richter magnitudes are estimated from both S-wave and P-wave measurements and a method based on the duration of the seismic signal is used to estimate the magnitude of the larger shocks. The two largest shocks had magnitudes of 3.4 and 3.3. The total seismic energy released was l0l7 ergs. During this same period the energy used for water injection, measured at the wellhead, was 1021 ergs.

  10. Design of gearbox for oil field hoisting equipment

    SciTech Connect

    Ibragimova, N.E.

    1995-07-01

    The kinematic diagram of the mechanical drive of oil field hoisting equipment is determined by the gear ratio for raising and lowering the down-hole equipment, the necessary hoist load capacity, and the power of the traction engine of the transport base. The choice of a rational gear ratio for raising the down-hole equipment is an important stage in the kinematic design of the transmission. The gear ratio of the gearbox of an oil-field hoist should be such as to ensure that the equipment is raised and lowered most rapidly and the utilization of the traction engine power is highest. The preferred gear train is one chosen in accordance with the geometric structure of the gear train of the gearbox. Such gearboxes are convenient to operate and easy to build. The design of these gearboxes is discussed.

  11. Performance of Electroless Nickel coatings in oil field environments

    SciTech Connect

    Duncan, R.N.

    1982-01-01

    Recent experience has shown functional Electroless Nickel to have outstanding resistance to corrosion and erosion in petroleum production facilities. Details of test programs to establish the performance of this coating in saline/CO/sub 2//H/sub 2/S environments at temperatures up to 180 C (350 F) are reported, together with actual experience with their use. Data also are presented on the effect of heat treatment and of deposit composition on the corrosion of Electroless Nickel in oil field services.

  12. Methane leaks from oil and gas fields detected from space

    NASA Astrophysics Data System (ADS)

    Rosen, Julia

    2014-11-01

    A few years ago, while poring over satellite images of the Earth at night, scientists spotted the bright glow of natural gas flares burning in the oil and gas fields that have fueled America's recent energy boom. Now they have spotted something else from space: large plumes of fugitive methane gas liberated from these formations by unconventional extraction methods like horizontal drilling and hydraulic fracturing.

  13. Niger delta oil production, reserves, field sizes assessed

    SciTech Connect

    Thomas, D.

    1995-11-13

    The article presents tables and figures showing the reserve estimates and production histories of the 252 fields in the Niger delta, then makes forecasts of the likelihood of discoveries above a given size. The paper discusses oil reserves, development programs, drilling and 3D seismic surveying, secondary and tertiary EOR, reserve incentives, production facilities, capital spending required, Nigerian export blends, and the trend in these blends.

  14. Surface reclamation of the Big Lake oil field

    SciTech Connect

    Weathers, M.L. ); Moore, K.R. ); Ford, D.L. ); Curlee, C.K. )

    1994-03-01

    Since the discovery of 1 Santa Rita in 1923, millions of barrels of salt water have been produced along with 135 million bbl of oil from the Big Lake oil field in Reagan County, Texas. Until the early 1960s, the accepted disposal method for the produced water was surface discharge to a large evaporation pond north of the field. Produced water was allowed to flow from wells to the pond via natural topographic drainage. This practice resulted in 2000 ac of eroded, barren landscape, characterized by highly saline soils incapable of supporting vegetation. In 1989, the University of Texas System, the U.S. Soil Conservation Service, and Marathon Oil Company, which acquired Big Lake field in 1962, initiated an experimental project to reclaim the affected land and restore rangeland productivity. An underground drainage system, consisting of 125,000 ft of buried drainage conduit and eight collection sumps, was installed over 205 ac of the affected area. Earthen terraces were constructed to capture and hold rain water to facilitate downward percolation and leaching of salts from the soil profile. Salts leached from the soil are captured by the drainage system and pumped to injection wells for disposal. The excellent revegetation that has occurred over the test area after three years of operations is encouraging and has shown the need for expanding and enhancing the existing system with supplemental water from fresh water wells, application of soil-amending agents, additional terracing, and selective planting with salt-tolerant species.

  15. Sulfide mineralization and magnetization, Cement oil field, Oklahoma

    USGS Publications Warehouse

    Reynolds, Richard L.; Fishman, Neil S.; Webring, Michael W.; Wanty, Richard B.; Goldhaber, Martin B.

    1989-01-01

    Geochemical, petrographic, and rock-magnetic studies were undertaken to investigate possible sources for reported positive aeromagnetic anomalies over the Cement oil field, Oklahoma. Ferrimagnetic pyrrhotite (monoclinic, Fe7S8 ), intergrown with more-abundant, nonmagnetic pyrite (FeS2), is present in well-cutting, core, and quarry samples at Cement, and it is the only identified source of possible enhanced magnetization in rocks over the field. Magnetite, found only in well cuttings from Cement, is contamination from drilling. Magnetite was considered previously by others to be the source of magnetic anomalies at Cement.

  16. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. It was hoped that the successful application of these technologies would result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs.

  17. Field observations of artificial sand and oil agglomerates

    USGS Publications Warehouse

    Dalyander, Patricia (Soupy); Long, Joseph W.; Plant, Nathaniel G.; McLaughlin, Molly R.; Mickey, Rangley C.

    2015-01-01

    Oil that comes into the surf zone following spills, such as occurred during the 2010 Deepwater Horizon (DWH) blowout, can mix with local sediment to form heavier-than-water sand and oil agglomerates (SOAs), at times in the form of mats a few centimeters thick and tens of meters long. Smaller agglomerates that form in situ or pieces that break off of larger mats, sometimes referred to as surface residual balls (SRBs), range in size from sand-sized grains to patty-shaped pieces several centimeters (cm) in diameter. These mobile SOAs can cause beach oiling for extended periods following the spill, on the scale of years as in the case of DWH. Limited research, including a prior effort by the U.S. Geological Survey (USGS) investigating SOA mobility, alongshore transport, and seafloor interaction using numerical model output, focused on the physical dynamics of SOAs. To address this data gap, we constructed artificial sand and oil agglomerates (aSOAs) with sand and paraffin wax to mimic the size and density of genuine SOAs. These aSOAs were deployed in the nearshore off the coast of St. Petersburg, Florida, during a field experiment to investigate their movement and seafloor interaction. This report presents the methodology for constructing aSOAs and describes the field experiment. Data acquired during the field campaign, including videos and images of aSOA movement in the nearshore (1.5-meter and 0.5-meter water depth) and in the swash zone, are also presented in this report.

  18. Crosshole EM for oil field characterization and EOR monitoring: Field examples

    SciTech Connect

    Wilt, M.; Schenkel, C.; Torres-Verdin, C.; Lee, Ki Ha; Tseng, Hung-Wen

    1994-09-01

    Crosshole and surface-to-borehole electromagnetic (EM) imaging is applied to reservoir characterization and steam flood monitoring in a central California oil field. Steam was injected into three stacked, eastward-dipping, unconsolidated oil sands within the upper 200 in. The steam plume is expected to develop as an ellipse aligned with the regional northwest-southeast strike. EM measurements were made from two flberglass-cased observation wells straddling the steam injector on a northeast-southwest profile. Field data were collected before the initiation of a steam drive to map the distribution of the oil sands and then six months after the steam was injected to monitor the progress of the steam chest. Resisitivity images derived from the EM data collected before steam injection clearly delineate the distribution and dipping structure on the target oil sands. Difference images from data collected before and after steam flooding indicate that the steam chest has developed only in the deeper oil sands, and it has preferentially migrated eastward. Surface-to-borehole measurements were useful in mapping the distribution of the major oil sands, but they were insensitive to resisitivity changes in the early stages of the steam flood.

  19. The prospects and development features of the oil and gas fields offshore China

    SciTech Connect

    Xu Jiaxin

    1993-12-31

    China National Offshore Oil Corporation (CNOOC) has been formed for more than 10 years. With more than 10 years exploration, 84 oil/gas fields and oil bearing structures have been discovered. The total OOIP is 1.18 billion tons and OGIP is 145 Cu.m. The oil/gas field types and characteristics and distribution regularities have been introduced in this paper. Author introduced the development method for these fields by examples.

  20. Oil gravity distribution in the diatomite at South Belridge Field, Kern County, CA: Implications for oil sourcing and migration

    SciTech Connect

    Hill, D.W.; Sande, J.J.; Doe, P.H.

    1995-04-01

    Understanding oil gravity distribution in the Belridge Diatomite has led to economic infill development and specific enhanced recovery methods for targeted oil properties. To date more than 100 wells have provided samples used to determining vertical and areal distribution of oil gravity in the field. Detailed geochemical analyses were also conducted on many of the oil samples to establish different oil types, relative maturities, and to identify transformed oils. The geochemical analysis also helped identify source rock expulsion temperatures and depositional environments. The data suggests that the Belridge diatomite has been charged by a single hydrocarbon source rock type and was generated over a relatively wide range of temperatures. Map and statistical data support two distinct oil segregation processes occurring post expulsion. Normal gravity segregation within depositional cycles of diatomite have caused lightest oils to migrate to the crests of individual cycle structures. Some data suggests a loss of the light end oils in the uppermost cycles to the Tulare Formation above, or through early biodegradation. Structural rotation post early oil expulsion has also left older, heavier oils concentrated on the east flank of the structure. With the addition of other samples from the south central San Joaquin area, we have been able to tie the Belridge diatomite hydrocarbon charge into a regional framework. We have also enhanced our ability to predict oil gravity and well primary recovery by unraveling some key components of the diatomite oil source and migration history.

  1. Qualitative identification of group composition in crude oil from different oil fields using terahertz time-domain spectroscopy

    NASA Astrophysics Data System (ADS)

    Feng, Cheng J.; Miao, Xin Y.; Li, Yi Z.; Bao, Ri M.; Zhao, Kun

    2015-11-01

    Optical properties of the group components in crude oil were studied using terahertz time-domain spectroscopy (THz-TDS) under nitrogen environment at ambient temperature. The group composition of crude oil from different oil fields were analyzed on the basis of terahertz spectra. Both time delay and amplitude of terahertz wave were modulated in accordance with group composition. The features of terahertz spectra which contain information from different parts of the crude oil group composition can be qualitatively analyzed to detect the group components of the crude oil.

  2. Floating oil production unit slated in small field off Gabon

    SciTech Connect

    Not Available

    1991-10-14

    This paper reports on the first U.S. tanker converted to a floating production, storage, and offloading (FPSO) unit which takes up station in Gombe-Beta field off Gabon by Dec. 1. FPSO Ocean Producer will work under a 3 year, day rate contract let late in 1990 by Amoco-Gabon Bombe Marin co., a unit of Amoco Production Co. (OGJ, Dec. 24, 1990, p. 27). Gombe-Beta field is in the Atlantic Ocean about 70 miles south of Port Gentil, Gabon. Ocean Producer will be moored in 50 ft of water 3.7 miles off Gabon, with Bombe-Beta's unmanned production platform about 820 ft astern. The vessel will be held in position by a disconnectable, asymmetric, six point, spread mooring system, It is owned and operated by Oceaneering International Services Ltd. (OISL). Affiliate Oceaneering Production Systems (OPS) converted the 78,061 dwt oil tanker MT Baltimore Sea at a capital cost of $25 million at Gulf Copper Manufacturing Corp.'s Port Arthur, Tex., shipyard. Both companies are units of Oceaneering International Inc., Houston. OPS the Ocean Producer's use in Gombe-Beta field is the shallowest water FPSO application in the world. Amoco-Gabon chose an FPSO production system for Gombe-Beta because it expects the remote field to have a short economic life, and the oil requires extensive processing.

  3. Genesis and formation oil and gas fields (Azerbaijan)

    NASA Astrophysics Data System (ADS)

    Poletayev, Alexander

    2010-05-01

    The large amount of material of HC isotope composition of over 330 samples allow to restore the history of oil and gas deposits formation within the South-Caspian Depression. Maps of isotope composition changes according to area extent, as well as graphs of HC distribution depending upon stratigraphic age, including rocks, graphs of isotope composition change on sampling depth were compiled for HC study and oil-gas deposits formation. Comparison of mud volcanoes gases, oil and gas fields, gas-hydrates and bottom sediments were conducted. Gases genesis according to M. Shoelle and A. James methodic were studied. Model of area paleoconstruction was studied. Two stages of formation were distinguished as a result of gases study of various forms of their manifestation (gases of mud volcanoes, oil and gas fields, gas hydrate, bottom sediments) as well as isotope gases composition distribution in area of extent including stratigraphic age of deposits, depth of sampling and application of M. Shoelle and A. James. There were determined basic ways of HC migration as well as estimated oil-gas content prospective. The first stage has begun in the underlying PS deposits and continued up to PS deposits. At this stage one various kind of tectonic fluctuations can observed. The second stage of HC formation has started from PS and characterised with a change of geodynamic conditions in region. Avalanche sedimentation, predominance of descending movements over ascending ones promoted the accumulation of thick sediments in PS age. As a result of sediments accumulation and tectonic processes (down warping) in the deep-seated basin led to the complication of thermobaric conditions in the sedimentary series. The studied chemical and HC gases isotope composition showed that basic source of oil and gas formation is located in the deep areas of central and near-flank parts of depression. HC migration has mainly occurred upward. Study of HC migration trend in time and area as well as areas of generation etc. allows to reveal some structures where there is evidence of HC accumulation with large and gigantic reserves.

  4. Microbial biodiversity in a Malaysian oil field and a systematic comparison with oil reservoirs worldwide.

    PubMed

    Li, Dongmei; Midgley, David J; Ross, Jason P; Oytam, Yalchin; Abell, Guy C J; Volk, Herbert; Daud, Wan Ata Wan; Hendry, Philip

    2012-06-01

    Microbial diversity within formation water and oil from two compartments in Bokor oil reservoir from a Malaysian petroleum oil field was examined. A total of 1,056 16S rRNA gene clones were screened from each location by amplified ribosomal DNA restriction analysis. All samples were dominated by clones affiliated with Marinobacter, some novel Deferribacteraceae genera and various clones allied to the Methanococci. In addition, either Marinobacterium- or Pseudomonas-like operational taxonomic units were detected from either compartment. A systematic comparison with the existing pertinent studies was undertaken by analysing the microbial amplicons detected and the PCR primers used. The analyses demonstrated that bacterial communities were site specific, while Archaea co-occurred more frequently. Amplicons related to Marinobacter, Marinobacterium and Pseudomonas were detected in a number of the studies examined, suggesting they may be ubiquitous members in oil reservoirs. Further analysis of primers used in those studies suggested that most primer pairs had fairly broad but low matches across the bacterial and archaeal domains, while a minority had selective matches to certain taxa or low matches to all the microbial taxa tested. Thus, it indicated that primers may play an important role in determining which taxa would be detected. PMID:22245906

  5. Archaeoglobus fulgidus Isolated from Hot North Sea Oil Field Waters

    PubMed Central

    Beeder, Janiche; Nilsen, Roald Kåre; Rosnes, Jan Thomas; Torsvik, Terje; Lien, Torleiv

    1994-01-01

    A hyperthermophilic sulfate reducer, strain 7324, was isolated from hot (75°C) oil field waters from an oil production platform in the Norwegian sector of the North Sea. It was enriched on a complex medium and isolated on lactate with sulfate. The cells were nonmotile, irregular coccoid to disc shaped, and 0.3 to 1.0 μm wide. The temperature for growth was between 60 and 85°C with an optimum of 76°C. Lactate, pyruvate, and valerate plus H2 were utilized as carbon and energy sources with sulfate as electron acceptor. Lactate was completely oxidized to CO2. The cells contained an active carbon monoxide dehydrogenase but no 2-oxoglutarate dehydrogenase activity, indicating that lactate was oxidized to CO2 via the acetyl coenzyme A/carbon monoxide dehydrogenase pathway. The cells produced small amounts of methane simultaneously with sulfate reduction. F420 was detected in the cells which showed a blue-green fluorescence at 420 nm. On the basis of morphological, physiological, and serological features, the isolate was classified as an Archaeoglobus sp. Strain 7324 showed 100% DNA-DNA homology with A. fulgidus Z, indicating that it belongs to the species A. fulgidus. Archaeoglobus sp. has been selectively enriched and immunomagnetically captured from oil field waters from three different platforms in the North Sea. Our results show that strain 7324 may grow in oil reservoirs at 70 to 85°C and contribute to hydrogen sulfide formation in this environment. Images PMID:16349231

  6. Remaining recoverable petroleum in giant oil fields of the Los Angeles Basin, southern California

    USGS Publications Warehouse

    Gautier, Donald L.; Tennyson, Marilyn E.; Cook, Troy A.; Charpentier, Ronald R.; Klett, Timothy R.

    2012-01-01

    Using a probabilistic geology-based methodology, a team of U.S. Geological Survey (USGS) scientists recently assessed the remaining recoverable oil in 10 oil fields of the Los Angeles Basin in southern California. The results of the assessment suggest that between 1.4 and 5.6 billion barrels of additional oil could be recovered from those fields with existing technology.

  7. Methanococcus thermolithotrophicus Isolated from North Sea Oil Field Reservoir Water

    PubMed Central

    Nilsen, R. K.; Torsvik, T.

    1996-01-01

    Methanococcus thermolithotrophicus ST22 was isolated from produced water of a North Sea oil field, on mineral medium with H(inf2)-CO(inf2) as the sole source of carbon and energy. The isolate grew at 17 to 62(deg)C, with an optimum at 60(deg)C. The pH range was 4.9 to 9.8, with optimal growth at pH 5.1 to 5.9; these characteristics reflected its habitat. Strain ST22 was quickly identified and distinguished from the type strain by immunoblotting. PMID:16535247

  8. Design of Temperature Controller for Heating Furnace in Oil Field

    NASA Astrophysics Data System (ADS)

    Zhenhai, Dou; Lianyun, Sun

    The temperature controller is an important part of the control system design of the crude oil heating furnace. the traditional PID control is usually used in temperature control, but it can not effectively overcome the impact by the interference, load change and the parameters change of system and other factors. Based on the relationship between rules factor α and the error E , meanwhile, taking into account the change of error r rate EC, the temperature controller is designed adaptive fuzzy control with variable slope. It greatly enhances the robustness of the system. By field application, works well.

  9. Applications of water-soluble polymers in the oil field

    SciTech Connect

    Chatterji, J.; Borchardt, J.K.

    1981-11-01

    Water-soluble polymers commonly used in the oil field are reviewed. The properties of guar, guar derivatives, cellulose derivatives, xanthan gum, locust bean gum, starches, and synthetic polymers, especially polyacrylamides, are discussed and related to chemical structures of the polymers. Original data comparing polymer solution viscosity properties under identical conditions are presented. These data include effect of polymer concentration on solution viscosity, temperature effect on solution viscosity, viscosity in acidic solution, and polymer solution viscosity in the presence of a hemicellulase enzyme. 105 refs.

  10. Geochemistry of oil-field water from the North Slope

    SciTech Connect

    Kharaka, Y.K.; Carothers, W.W.

    1989-01-01

    Knowledge of the chemical composition of oil-field water is important in understanding the origin and migration of petroleum as well as the water mineral reactions that affect the porosity and permeability of the reservoir rocks. This knowledge is essential in interpreting electric logs and in determining potential pollution, corrosion, and disposal problems of water produced with oil and gas. Finally, the chemical composition of water is an important factor in determining the conditions (temperature, pressure) for the formation of clathrates. This chapter reports detailed chemical analyses of seven formation-water samples from wells within the NPRA and one surface-and two formation-water samples from the Prudhoe Bay oil field. The authors also report {delta}D and {delta}{sup 18}O values for eight of the water samples as well as analyses for gases from six wells. The formation-water samples were obtained from depths ranging from about 700 to 2800 m and from reservoir rocks ranging in age from Mississippian (Lisburne Group) to Triassic. The reservoir rocks are sandstone except for sample 79-AK-5, which was obtained from a limestone interbedded with sandstone. Generally, the pre-Cretaceous sandstone reservoir rocks on the North Slope have a similar mineral composition. Van de Kamp (1979) gave the following description of these sandstones: Quartz (usually monocrystalline) and chert are the major components; carbonate and clay are variable. Carbonate occurs as detrital grains and as cement, siderite being the most common type. Siderite can form as much as 30 percent of the rock. Clay occurs as a common matrix, generally making up less than 10 percent of the rock. Accessory minerals include pyrite, plagioclase, microcline, glauconite, zircon, sphene, tourmaline, and muscovite.

  11. Silverthread oil field, Ventura County, California: a hydrodynamic trap

    SciTech Connect

    Hacker, R.N.; Hester, R.L.

    1987-05-01

    Silverthread oil field is located in west-central Ventura County, California. An unusual combination of Miocene turbidite sand deposition, tight folding, faulting, and hydrodynamics have created an accumulation of over 6 million bbl of oil from 33 wells. This field is also unique in that it lies beneath the convergence of several opposing major thrust faults which effectively hide any surface indication of structure at depth. Though previously and often explored by majors and other operators, the remarkable deduction and perseverance by Harry Browne and Argo Petroleum Corporation geologists led to the main area discovery in 1971. Of exceptional interest is the interaction of classic hydrodynamic flow on the distribution of fluids within the reservoir. Thirteen contour maps and numerous structure and stratigraphic sections were required to unravel the sand sequence, faulting, structure, and hydrodynamics. Because of high surface relief, most wells were directionally drilled from islands, and subsequent electric logs had to be unstretched using the Dental Dam technique to facilitate their correlation. A large, lighted, three-dimensional model consisting of thirty-six 2 x 5-ft transparent plexiglas plates was constructed to show a simple resolution of the complexities of this area and will be part of the poster session. This display, they believe, will generate considerable interest in their presentation.

  12. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies would result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs.

  13. Chemically bonded phosphate ceramic sealant formulations for oil field applications

    DOEpatents

    Wagh, Arun S.; Jeong, Seung-Young; McDaniel, Richard

    2008-10-21

    A sealant for an oil or geothermal well capable of setting within about 3 to about 6 hours at temperatures less than about 250.degree. F. for shallow wells less than about 10,000 feet and deep wells greater than about 10,000 feet having MgO present in the range of from about 9.9 to about 14.5%, KH.sub.2PO.sub.4 present in the range of from about 29.7 to about 27.2%, class C fly ash present in the range of from about 19.8 to about 36.3%, class F fly ash present in the range of from about 19.8 to about 0%, boric acid or borax present in the range of from about 0.39 to about 1.45%, and water present in the range of from about 20.3 to about 21.86% by weight of the sealant.A method of sealing wells is disclosed as are compositions for very high temperature wells is disclosed as is a composition for treating oil field wastes.

  14. Indexes of pumps for oil field pumping units

    SciTech Connect

    Ibragimov, E.S.

    1995-07-01

    As reported previously, a series of oil field pumping units has been developed with power outputs of 125, 250, 500, and 1000 kW, designed for injecting working fluids in cementing operations in oil and gas wells, hydraulic fracturing of formations, washing out sand plugs, and other production operations. The units are designed for the use of three-plunger pumps with individual power outputs of 125 or 500 kW. In the 250- and 1000-kW units, two such pumps are used. The 1000-kW pumping unit serves mainly for deep-penetration hydraulic fracturing of formations, and also for fracturing deep formations. The hydraulic fracturing process does not require the use of units with two pumps; this has been demonstrated by experience, both here and in other countries. All units intended for use in hydraulic fracturing are built with a single pump, transmission, and drive. Pumping units for well cementing must have two pumps that will give a high delivery rate. At the start of the operation, a single pump can be used to feed water into the cement mixer, with the second pump used to transfer the cement slurry to the well. Then both pumps are connected to the slurry injection line. The operation of these pumps is described.

  15. Oil field waste disposal in salt caverns: An information website

    SciTech Connect

    Tomasko, D.; Veil, J. A.

    1999-12-10

    Argonne National Laboratory has completed the construction of a Website for the US Department of Energy (DOE) that provides detailed information on salt caverns and their use for disposing of nonhazardous oil field wastes (NOW) and naturally occurring radioactive materials (NORM). Specific topics in the Website include the following: descriptions of salt deposits and salt caverns within the US, salt cavern construction methods, potential types of wastes, waste emplacement, regulatory issues, costs, carcinogenic and noncarcinogenic human health risks associated with postulated cavern release scenarios, new information on cavern disposal (e.g., upcoming meetings, regulatory issues, etc.), other studies supported by the National Petroleum Technology Office (NPTO) (e.g., considerations of site location, cavern stability, development issues, and bedded salt characterization in the Midland Basin), and links to other associated Web sites. In addition, the Website allows downloadable access to reports prepared on the topic that were funded by DOE. Because of the large quantities of NOW and NORM wastes generated annually by the oil industry, information presented on this Website is particularly interesting and valuable to project managers, regulators, and concerned citizens.

  16. Geochemical Specific Characters of the Oil and the Origin of the Oil and Gas Fields

    NASA Astrophysics Data System (ADS)

    Gottikh, Rimma; Pisotskiy, Bogdan; Plotnikova, Irina

    2010-05-01

    It is generally assumed that the fluid regime of the basement of ancient platforms is not associated with that of the sedimentary cover. This assumption is mainly due to the substantial time gap between the formation of the crystalline and sedimentary rocks as well as the evolutionary differences between the thermal regime of the interior and the redox potentials of fluid systems. The presence of loosely aggregated zones filled with salt-water solutions, oil or gas in the upper basement is explained by downward fluid flows from sedimentary rocks through tectonic faults into the disintegrated crystalline rocks. The formation of such zones is believed to be due to the crustal stratification due to Earth's pulsation, periodic variations of its rotational rate, hydrogenic deconsolidation, burial of the post-Early Proterozoic disintegration zones, etc. This pattern suggests that the matter and energy exchange between the Earth's spheres in the late stages of the platform development could only take place with the help of magmatic melts and the associated fluids during the tectonomagmatic cycles of the Earth's crust transformation. Gas and liquid hydrocarbon components mainly occur in crystalline basement rocks of ancient platforms penetrated to a depth of more than 3000 m due to deep degassing processes. The traces of the upward migration of fluids are sealed in the geological sequence, including the sedimentary cover, within secondary inclusions of rocks and minerals. The fluids are complex, reduced, multicomponent systems that transport lithophilous, chalcophilous and siderophilous elements. The presence of microelements in the bituminous phase of inclusions indicates that metals mainly occur in the complexes containing organic ligands. During the evolution of the fluid systems under new pressure and temperature conditions, low-solubility substances were separated out of the fluid to form hard bitumen, and the lighter components migrated into the overlying fractured and porous rocks. The high metal content of carbonaceous substances and their compositional variations governed by homogenisation temperatures of the inclusions suggest that they are not the products of the decomposition of oil fields. The constant presence of uranium in the fluid and its differentiation products allows the tracing of the systems' migration ways from the crystalline basement to oil-saturated reservoir zones of the sedimentary cover The known geochemical properties of bitumen and oil - high platinum content, specific distributions of rare earth elements, that are not characteristic of the upper crust formations, as well as 143Nd/144Nd and 87Sr/86Sr isotopic compounds, which are out of balance with the organic matter of sedimentary rocks - suggest that hydrocarbons are accumulated in the presence of cooling high-alkalinity mafite-ultramafite intrusions. This logically corresponds to the distribution of seismic anomalies and magnetic and gravity fields in the consolidated crust below the various petroleum fields (for example, South Tatarstan and Nepsky arches of the Romashkino and Verkhne-Chonskoye oil fields). The acquired geochemical and thermodynamic characteristics of the reduced fluids and their differentiation products from the crystalline basement and the sedimentary cover of the southern Siberian and eastern East European platforms indicate that these were formed outside of the sedimentary cover and that the migration was directed upwards. The analysis of the magmatic evolution on platforms reveals its alkaline trend due to the impeded degassing of magmatic sources at depth and the inflow of new doses of alkaline fluids or melts into them. Further evolution of the zones of partial melting of the substratum led, in the authors' view, to the generation of oil-forming fluids and their transportation into the Earth's upper crust. Their interaction with the surrounding rocks in turn led to the formation of oil accumulations. Thus, oil is the product of the interaction of deep, reduced fluids. Oil, graphite of the Archaean crystalline complexes and hard bitumens are interrelated elements of the evolution of deep, high-enthalpy systems. These large-scale reduced palaeofluid phenomena are obviously related to geodynamic and tectonomagmatic processes. The source of these fluid systems, their impact on the geological environment and its consequences can be determined through additional integrated geochemical studies using the isotopes of heavy elements and through the correlation of the observed potential fields with the structure of the consolidated crust and the sedimentary cover for the identification of geodynamic processes in geophysically inhomogeneous zones of the geological medium.

  17. FIELD TEST KIT FOR CHARACTERIZING OIL-BRINE EFFLUENTS FROM OFFSHORE DRILLING PLATFORMS

    EPA Science Inventory

    This research program was initiated to evaluate test methods for characterizing oil-brine effluents from offshore oil production platforms and to package and deliver a field test kit for on-site oil-brine analyses. After an initial laboratory evaluation and selection of test meth...

  18. Tukau Field: Finding new oil in matured and complex field after 20 years of production

    SciTech Connect

    Shariff, M.D.; Ridza, M. ); Majid, P. )

    1996-01-01

    The Tukau Field is located some 30 km offshore Sarawak, Malaysia. in water depth of about 160 ft. The field, discovered by TK-2 in 1966 found 235 ft net oil sand and 16 ft wet gas sand. After further seismic data acquisition and interpretation, six (6) appraisal wells were drilled from 1973 to 1975 before the field could be commercially developed. The Tukau structure is a structurally complex feature formed as a domal anticlinal uplift, located along the Tukau I Bakau / Baram trend. It is dissected at the shallow level by normal synthetic and antithetic faults. These fault system divide the field into seven (7) fault blocks. The major hydrocarbon accumulations are between 2400 ftss and 7500 ftss and the main prospective sequence consists of fine to very fine grained sand of the upper cycle V of late Miocene age and deposited in a deltaic, fluviomarine, coastal to near shore environment. Development drilling commenced in 1975 with a total of 23 wells. To date a total of nine (9) rounds of development activities were carried out resulting in 55 wells being drilled and nine (9) well jackets installed. In 1975, based on the seismic and well data. the field is estimated to contain some 300 MMSTB of oil. Following subsequent field reviews Incorporating some 50 odd well data and seismic reinterpretation in 1987. the field STOIIP increased to 500 MMST. 3D seismic was acquired in 1992 and field review carried out In 1995 resulted In some development potential and appraisal / exploration opportunities. The appraisal well drilled in October 1995, increased the field STOIIP by some 50 MMSTB. Preliminary evaluation based on geological, engineering and economic information indicated that Tukau field will be further developed with additional well jacket and this will boost the field production by about 50%.

  19. Tukau Field: Finding new oil in matured and complex field after 20 years of production

    SciTech Connect

    Shariff, M.D.; Ridza, M.; Majid, P.

    1996-12-31

    The Tukau Field is located some 30 km offshore Sarawak, Malaysia. in water depth of about 160 ft. The field, discovered by TK-2 in 1966 found 235 ft net oil sand and 16 ft wet gas sand. After further seismic data acquisition and interpretation, six (6) appraisal wells were drilled from 1973 to 1975 before the field could be commercially developed. The Tukau structure is a structurally complex feature formed as a domal anticlinal uplift, located along the Tukau I Bakau / Baram trend. It is dissected at the shallow level by normal synthetic and antithetic faults. These fault system divide the field into seven (7) fault blocks. The major hydrocarbon accumulations are between 2400 ftss and 7500 ftss and the main prospective sequence consists of fine to very fine grained sand of the upper cycle V of late Miocene age and deposited in a deltaic, fluviomarine, coastal to near shore environment. Development drilling commenced in 1975 with a total of 23 wells. To date a total of nine (9) rounds of development activities were carried out resulting in 55 wells being drilled and nine (9) well jackets installed. In 1975, based on the seismic and well data. the field is estimated to contain some 300 MMSTB of oil. Following subsequent field reviews Incorporating some 50 odd well data and seismic reinterpretation in 1987. the field STOIIP increased to 500 MMST. 3D seismic was acquired in 1992 and field review carried out In 1995 resulted In some development potential and appraisal / exploration opportunities. The appraisal well drilled in October 1995, increased the field STOIIP by some 50 MMSTB. Preliminary evaluation based on geological, engineering and economic information indicated that Tukau field will be further developed with additional well jacket and this will boost the field production by about 50%.

  20. Sword field, offshore California: challenges in making this giant oil field commercial

    SciTech Connect

    Ballard, J.H.

    1988-03-01

    The major obstacles and challenges involved in exploration and development of a giant deep-water low-gravity oil field are exemplified in the undeveloped Sword field of offshore southern California. In 1979, Conoco Exploration identified a northeast-southwest-trending basement high in 800-2000 ft deep federal waters 12 mi southwest of Pt. Conception at the western end of the Santa Barbara Channel. The intended reservoir was fractured Miocene Monterey chert, siliceous shales or siltstones, and dolomites that are draped over the axially faulted anticlinal structure. Drilling of the initial well in OCS P-0322 in 1982 resulted in discovering the giant Sword field. A confirmation well drilled in OCS P-0320 indicates in-place reserves of well over 1 billion bbl. Although the discovered potential is significant, the low gravity (8.5/sup 0/-10.5/sup 0/ API) of the oils discovered to date, along with water depths in excess of 1500 ft, currently pose economic challenges to successful field development. Conoco and its partners are addressing the current economic barriers on several fronts. A three-dimensional seismic survey has been conducted to delineate reservoir geometry and to define probable variations in pay thickness and fracturing. A market feasibility study will be undertaken to assess the demand for low gravity crude from offshore California. Finally, Conoco has developed proprietary technology called OCHOS (Offshore California Heavy Oil System), which uses an innovative oil and/or water emulsion technique to allow for more economic recovery of high-velocity or low-gravity crudes.

  1. Feasibility study for the development of the Karakuduk oil field. Volume 1. Export trade information

    SciTech Connect

    1996-05-01

    The study, conducted by Chaparral Resources, was funded by the U.S. Trade and Development Agency. The report shows the results of a feasibility study to better define the characteristics and extent of the Karakuduk Oil Field. The proposed project would include the reworking of four existing exploratory wells and drilling one new well. The plan also calls for the installation of a trunkline, as well as a facility with all necessary oil, has and water handling equipment according to the production needs of the Pilot through Full Production Phases. This is Volume One of a two-volume report and is divided into the following sections: (1) Project Overview and Schedule; (2) Oil Field Reserves; (3) Field Drilling Plan; (4) Field Facilities; (5) Oil Tranpsortation Plan; (6) Oil Marketing Plan; (7) Engineering, Procurement and Construction Plan; (8) Oil Field Operations and Maintenance Plan; (9) Mapping and Survey of Site; (10) Cost Estimate.

  2. Alkanes in benthic organisms from the Buccaneer oil field

    SciTech Connect

    Middleditch, B.S.; Basile, B.

    1980-06-01

    About 200 g per day of alkanes are present in brine discharged from each of two production platforms in the Buccaneer oil field in the NW Gulf of Mexico. These alkanes disperse rapidly in the water column, so that seawater concentrations of petroleum alkanes in this region are generally very low. They can be taken up to some extent by plankton, fish, and barnacles, but the petroleum alkane concentrations in these organisms are also relatively low. The largest pool of petroleum alkanes is in the surficial sediments, where concentrations of up to 25 ppM are observed, with concentration gradients extending more than 20 m from the production platforms. Organisms are examined which are exposed to these sediments and, for comparison, other specimens from control sites around structures from which there are no discharges.

  3. Cano Limon - new giant oil field in Colombia

    SciTech Connect

    Lindsay, D.R.; Kendall, G.W.

    1986-05-01

    Discovery of the billion-barrel Cano Limon field in July 1983 established the Llanos basin in eastern Colombia as a major oil-productive region. Initial production in December 1985 was 30,000 BOPD from two wells, with full production expected by mid-1986 when a pipeline to the coast is completed. The accumulation has updip closure against convergent sealing faults. The main reservoir is the Eocene Mirador formation, with average net pay of 155 ft (47 m) consisting of unconsolidated sands with up to 7 darcies in-situ core-measured permeability at an average depth of 7300 ft (2225 m). The sands were derived from the Guyana shield to the east and deposited in a westerly prograding alluvial-deltaic system. Smaller accumulations occur in Oligocene and Cretaceous sands deposited in shallow marine to deltaic environments.

  4. Magnetotelluric signature of anticlines in Iran's Sehqanat oil field

    NASA Astrophysics Data System (ADS)

    Mansoori, Isa; Oskooi, Behrooz; Pedersen, Laust B.

    2015-07-01

    The magnetotelluric (MT) method has proved to be an effective tool in hydrocarbon exploration especially in areas with geological structures/formations where seismic reflection provides neither good quality data nor images. The Sehqanat oil field located in the sedimentary zone of Zagros in SW of Iran is a typical example. It is covered by the high velocity and heterogeneous formation of Gachsaran, which is exposed at the surface and has a thickness varying from 500 m to more than 2 km in the region. Gachsaran is composed mainly of salt and evaporites overlying, as a cap rock, the Asmari limestone formation which is the main reservoir in all oil fields of Iran along the Zagros range. The main geological interface which is targeted to be imaged with the MT method is the contact between the highly conductive evaporites of the Gachsaran formation and the underlying more resistive carbonates of the Asmari formation. MT data at more than 600 stations along five parallel SW-NE profiles crossing the main geological trend of the study area and transient electromagnetic data over 400 stations to be used for static shift corrections of the MT data were available. Dimensionality and strike analysis of the MT data show dominant two-dimensional (2-D) conditions in almost all sites and periods. The 2-D resistivity models resolved the boundary between Gachsaran and Asmari formations as a transition zone from highly conductive to resistive structures. The Sehqanat anticline has also been delineated throughout the 2-D resistivity sections as a resistive dome-shaped body located in the middle part of the MT profiles. There is a considerable correlation between the 2-D resistivity models and the adjacent 2-D reflection seismic sections so that a more reliable interpretation on the hydrocarbon trap of the Sehqanat anticline can be obtained.

  5. Functional gene diversity of soil microbial communities from five oil-contaminated fields in China.

    PubMed

    Liang, Yuting; Van Nostrand, Joy D; Deng, Ye; He, Zhili; Wu, Liyou; Zhang, Xu; Li, Guanghe; Zhou, Jizhong

    2011-03-01

    To compare microbial functional diversity in different oil-contaminated fields and to know the effects of oil contaminant and environmental factors, soil samples were taken from typical oil-contaminated fields located in five geographic regions of China. GeoChip, a high-throughput functional gene array, was used to evaluate the microbial functional genes involved in contaminant degradation and in other major biogeochemical/metabolic processes. Our results indicated that the overall microbial community structures were distinct in each oil-contaminated field, and samples were clustered by geographic locations. The organic contaminant degradation genes were most abundant in all samples and presented a similar pattern under oil contaminant stress among the five fields. In addition, alkane and aromatic hydrocarbon degradation genes such as monooxygenase and dioxygenase were detected in high abundance in the oil-contaminated fields. Canonical correspondence analysis indicated that the microbial functional patterns were highly correlated to the local environmental variables, such as oil contaminant concentration, nitrogen and phosphorus contents, salt and pH. Finally, a total of 59% of microbial community variation from GeoChip data can be explained by oil contamination, geographic location and soil geochemical parameters. This study provided insights into the in situ microbial functional structures in oil-contaminated fields and discerned the linkages between microbial communities and environmental variables, which is important to the application of bioremediation in oil-contaminated sites. PMID:20861922

  6. Functional gene diversity of soil microbial communities from five oil-contaminated fields in China

    PubMed Central

    Liang, Yuting; Van Nostrand, Joy D; Deng, Ye; He, Zhili; Wu, Liyou; Zhang, Xu; Li, Guanghe; Zhou, Jizhong

    2011-01-01

    To compare microbial functional diversity in different oil-contaminated fields and to know the effects of oil contaminant and environmental factors, soil samples were taken from typical oil-contaminated fields located in five geographic regions of China. GeoChip, a high-throughput functional gene array, was used to evaluate the microbial functional genes involved in contaminant degradation and in other major biogeochemical/metabolic processes. Our results indicated that the overall microbial community structures were distinct in each oil-contaminated field, and samples were clustered by geographic locations. The organic contaminant degradation genes were most abundant in all samples and presented a similar pattern under oil contaminant stress among the five fields. In addition, alkane and aromatic hydrocarbon degradation genes such as monooxygenase and dioxygenase were detected in high abundance in the oil-contaminated fields. Canonical correspondence analysis indicated that the microbial functional patterns were highly correlated to the local environmental variables, such as oil contaminant concentration, nitrogen and phosphorus contents, salt and pH. Finally, a total of 59% of microbial community variation from GeoChip data can be explained by oil contamination, geographic location and soil geochemical parameters. This study provided insights into the in situ microbial functional structures in oil-contaminated fields and discerned the linkages between microbial communities and environmental variables, which is important to the application of bioremediation in oil-contaminated sites. PMID:20861922

  7. PVTX characteristics of oil inclusions from Asmari formation in Kuh-e-Mond heavy oil field in Iran

    NASA Astrophysics Data System (ADS)

    Shariatinia, Zeinab; Haghighi, Manouchehr; Shafiei, Ali; Feiznia, Sadat; Zendehboudi, Sohrab

    2015-04-01

    Incorporating PVT properties and compositional evolution of oil inclusions into reservoir engineering simulator protocols can enhance understanding of oil accumulation, reservoir charge history, and migration events. Microthermometry and volumetric analysis have proven to be useful tools in compositional reconstitution and PT studies of oil inclusions and were used to determine composition, thermodynamic conditions, physical properties, and gas-to-oil ratios of heavy oil samples from Asmari carbonate reservoir in Kuh-e-Mond heavy oil field in Iran. PVT properties were predicted using a PVT black-oil model, and an acceptable agreement was observed between the experiments and the simulations. Homogenization temperatures were determined using microthermometry techniques in dolomite and calcite cements of the Asmari Formation, as well. Based on the homogenization temperature data, the undersaturated hydrocarbon mixture prior to formation of the gas cap migrated with a higher gas-to-oil ratio from a source rock. According to the oil inclusion data, the onset of carbonate cementation occurred at temperatures above 45 °C and that cementation was progressive through burial diagenesis. PVT black-oil simulator results showed that the reservoir pressure and temperature were set at 100 bar and 54 °C during the initial stages of oil migration. Compositional modeling implies that primary and secondary cracking in source rocks were responsible for retention of heavy components and migration of miscible three-phase flow during hydrocarbon evolution. The PT evolution of the petroleum inclusions indicates changes in thermodynamic properties and mobility due to phenomena such as cracking, mixing, or/and transport at various stages of oil migration.

  8. Crude oil bioremediation field experiment in the Sea of Japan.

    PubMed

    Maki, Hideaki; Hirayama, Noriko; Hiwatari, Takehiko; Kohata, Kunio; Uchiyama, Hiroo; Watanabe, Masataka; Yamasaki, Fumio; Furuki, Masakazu

    2003-01-01

    Experimental bioremediation of crude oil was conducted for approximately 3 months in the intertidal zone of the Sea of Japan, Hyogo Prefecture. Artificial mixtures of weathered Arabian light crude oil and sand taken from the experimental site were wrapped in polyester net envelopes. The envelopes were placed in drum-shaped acrylic vessels with perforated sides to facilitate seawater exchange. The vessels were laid in the intertidal area. Slow release nitrogen and phosphorus synthetic fertilizer granules were added to the oil-sand mixtures in three different amounts. Some oil-sand mixtures were unfertilized controls. The oil-sand mixtures were periodically sampled and changes in the composition of the residual oils were monitored. Oil samples were subjected to gas chromatography coupled with mass spectrometry for analysis of some representative semi-volatile aliphatic and aromatic compounds. All values for each analyte were normalized against that of hopane to evaluate the extent of oil biodegradation. Significant increases in the concentrations of both nitrogen and phosphorus were found in the fertilized sections in accordance with the amounts of added fertilizers. Although significant natural attenuation of oil was observed in the unfertilized sections, fertilization stimulated the degradation rate of the oil in the early stage of the experimental term. The extent of the oil biodegradation increased as the amount of added fertilizer increased. However, the final degradation efficiencies for each oil component in the fertilized sections were not significantly different from those in the unfertilized sections, and the degradation of each oil component had almost ceased after 6 weeks. We conclude that excessive amounts of macronutrients are required to accelerate oil biodegradation and that fertilization is only effective in the early stages. PMID:12787600

  9. Evidence for a palaeo-oil column and alteration of residual oil in a gas-condensate field: Integrated oil inclusion and experimental results

    NASA Astrophysics Data System (ADS)

    Bourdet, Julien; Burruss, Robert C.; Chou, I.-Ming; Kempton, Richard; Liu, Keyu; Hung, Nguyen Viet

    2014-10-01

    In the Phuong Dong gas condensate field, Cuu Long Basin, Vietnam, hydrocarbon inclusions in quartz trapped a variety of petroleum fluids in the gas zone. Based on the attributes of the oil inclusion assemblages (fluorescence colour of the oil, bubble size, presence of bitumen), the presence of a palaeo-oil column is inferred prior to migration of gas into the reservoir. When a palaeo-oil column is displaced by gas, a residual volume fraction of oil remains in pores. If the gas does not completely mix with the oil, molecular partitioning between the residual oil and the new gas charge may change the composition and properties of the residual oil (gas stripping or gas washing). To simulate this phenomenon in the laboratory, we sealed small amounts of crude oil (42 and 30 °API) and excess pure gas (methane, ethane, or propane) in fused silica capillary capsules (FSCCs), with and without water. These mixtures were characterized with the same methods used to characterize the fluid inclusions, heating and cooling stage microscopy, fluorescence spectroscopy, synchrotron FT-IR, and Raman spectroscopy. At room temperature, mixtures of ethane and propane with the 30 °API oil formed a new immiscible fluorescent liquid phase with colour that is visually more blue than the initial oil. The fluorescence of the original oil phase shifted to yellow or disappeared with formation of semi-solid residues. The blue-shift of the fluorescence of the immiscible phases and strong CH stretching bands in FT-IR spectra are consistent with stripping of hydrocarbon molecules from the oil. In experiments in FSCCs with water solid residues are common. At elevated temperature, reproducing geologic reservoir conditions, the fluorescence changes and therefore the molecular fractionation are enhanced. However, the precipitation of solid residues is responsible of more complex changes. Mixing experiments with the 42 °API oil do not form a new immiscible hydrocarbon liquid although the fluorescence displays a similar yellow shift when gas is added. Solid residues rarely form in mixtures with 42 °API oil. FT-IR spectra suggest that the decrease of fluorescence intensity of the original oil at short wavelengths to be due to the partitioning of low molecular weight aromatic molecules into the vapour phase and/or the new immiscible liquid phase. The decrease of fluorescence intensity at long wavelengths appears to be due to loss of high molecular weight aromatics during precipitation of solid residues by desorption of aromatics and resins from asphaltenes. Desorption of low molecular weight aromatics and resins from asphaltenes during precipitation can also increase the fluorescence intensity at short wavelengths of the residual oil. Water clearly affects the precipitation of semi-solid residues from the oil phase of the lowest API gravity oil. The change of hydrocarbon phase(s) in UV-visible fluorescence and FT-IR enclosed within the FSCCs were compared with the fluorescence patterns of natural fluid inclusions at Phuong Dong gas condensate field. The experimental results support the concept of gas-washing of residual oil and are consistent with the oil inclusion attributes from the current gas zone at Phuong Dong field. The hydrocarbon charge history of the fractured granite reservoir is interpreted to result from the trapping of residual oil after drainage of a palaeo-oil column by gas.

  10. Air injection project breathes fire into aging West Hackberry oil field

    SciTech Connect

    Duey, R.

    1996-02-01

    Amoco, the DOE and LSU seek more oil from Gulf Coast salt dome fields with air injection technique. The West Hackberry Field in Louisiana is a water-driven reservoir. By injecting air into the high-pressure, high-temperature reservoir rock, the water is backed down, allowing the oil to drain off the steeply dipped rock.

  11. CUMULATIVE IMPACTS OF OIL FIELDS ON NORTHERN ALASKAN LANDSCAPES (JOURNAL VERSION)

    EPA Science Inventory

    Proposed further developments on Alaska's Arctic Coastal Plain raise questions about cumulative effects on arctic tundra ecosystems of development of multiple large oil fields. Maps of historical changes to the Prudhoe Bay Oil Field show indirect impacts can lag behind planned de...

  12. Basement reservoir in Zeit Bay oil field, Gulf of Suez

    SciTech Connect

    Zahran, I.; Askary, S.

    1988-02-01

    Fractured basement, one of the most important reservoirs of Zeit Bay field, contains nearly one-third of oil in place of the field. The flow rates per well vary from 700 to 9,000 BOPD. Due to its well-established production potential, 60% of the wells for the development of the field were drilled down to basement. The Zeit Bay basement consists of granitic rocks of pegmatitic to coarse porphyritic texture and has equal proportions of alkali feldspars. Dykes of various compositions are present, traversing the granite at different intervals. Dykes include aplite, microsyenite, diabase and lamprophyre. The last two pertain to the post-granitic dykes of late Proterozoic age. The main granitic pluton is related to one of the final stages of the tectonic-magmatic cycle of the Arabo-Nubian shield. The Zeit Bay area was a significant paleohigh until the Miocene, hence its structural picture is very complicated due to the impact of different tectonic movements from the late Precambrian to Cenozoic. The resulting structural elements were carefully investigated and statistically analyzed to decipher the influence of various tectonic events. The presence of high porosity in some intervals and low porosity in others could be tied to the presence of new fractures and the nature of cementing minerals. The relation of mineralized fractures and their depths lead to zonation of porous layers in the granitic pluton. Diagenetic processes on the granitic body and the alteration/resedimentation of the diagenetic products controlled the magnitude and amplitude of the porosity layers. A model has been constructed to illustrate the changes in the primary rock texture and structure with sequential diagenetic processes, taking into consideration the fracture distribution and their opening affinities as related to their depths.

  13. Basement reservoir in Zeit Bay oil field, Gulf of Suez

    SciTech Connect

    Zahran, I.; Askary, S.

    1988-01-01

    Fractured basement, one of the most important reservoirs of Zeit Bay field, contains nearly one-third of oil in place of the field. The flow rates per well vary from 700 to 9,000 BOPD. Due to its well-established production potential, 60% of the wells for the development of the field were drilled down to basement. The Zeit Bay basement consist of granitic rocks of pegmatitic to coarse porphyritic texture and has equal proportions of alkali feldspars. Dykes of various compositions are present, traversing the granite at different intervals. Dykes include aplite, microsyenite, diabase and lamprophyre. The last two pertain to the post-granitic dykes of later Proterozoic age. The main granitic luton is related to one of the final stages of the tectonic-magmatic cycle of the Arabo-Nubian sheild. The Zeit Bay area was a significant paleohigh until the Miocene, hence its structural picture is very complicated due to the impact of different tectonic movements from the late Precambrian to Cenozoic. The resulting structural elements were carefully investigated and statistically analyzed to decipher the influence of various tectonic events. The presence of high porosity in some intervals and low porosity in others could be tied to the presence of new fractures and the nature of cementing minerals. The relation of mineralized fractures and their depths lead to zonation of porous layers in the granitic pluton. Diagenetic processes on the granitic body and the alternation/resedimentation of the diagenetic products controlled the magnitude and amplitude of the porosity layers.

  14. Vertical magnetic field and its analytic signal applicability in oil field underground pipeline detection

    NASA Astrophysics Data System (ADS)

    Guo, Zhiyong; Liu, Dejun; Pan, Qi; Zhang, Yingying; Li, Yi; Wang, Zheng

    2015-06-01

    We propose using the vertical component of the magnetic anomaly (vertical magnetic field (VMF)) and its analytic signal (AS) to detect oil field underground pipelines. The connection between two peaks of the VMF curves or the AS curves was used to calculate the pipeline azimuth, and the peak coordinates of the AS were used to determine the horizontal position of pipelines. Then, the effect of the pipeline magnetization direction and pipeline buried depth on the horizontal locating error was analyzed. Three typical pipeline models were used for verifying this method. Results indicate that this method can be used to precisely calculate the stretch direction of the pipeline and effectively improve the identification capability in detecting parallel pipelines. The horizontal position of the pipeline axis can be accurately located by the peak of the AS and the locating error increases with the increase in pipeline buried depth, but it is not affected by pipeline outer diameter, thickness, susceptibility. The instrument design and the VMF measurement strategy are realistic and applicable. The VMF detection with its AS provides a new effective method for horizontal locating and direction calculating of oil field underground pipelines.

  15. Computer simulation of nonstationary thermal fields in design and operation of northern oil and gas fields

    NASA Astrophysics Data System (ADS)

    Vaganova, N. A.; Filimonov, M. Yu.

    2015-11-01

    A mathematical model, numerical algorithm and program code for simulation and long-term forecasting of changes in permafrost as a result of operation of a multiple well pad of northern oil and gas field are presented. In the model the most significant climatic and physical factors are taken into account such as solar radiation, determined by specific geographical location, heterogeneous structure of frozen soil, thermal stabilization of soil, possible insulation of the objects, seasonal fluctuations in air temperature, and freezing and thawing of the upper soil layer. Results of computing are presented.

  16. Driving mechanism for plunger pumps in oil field installations

    SciTech Connect

    Gazarov, R.E.; Zaslavskii, Yu.V.

    1995-07-01

    Mobile oil field pumping installations of up to 1600 kW power at a pressure up to 140 MPa are widely used in hydraulic fracturing of beds, acid treatment of the near-face zone, cementation of wells, and other flushing and pressure operations. Equipment in these installations, which include high-pressure plunger pumps of high unit capacity, are mounted on mobile bases of limited lifting capacity (KrAZ automobile chassis, T-130 tractors, etc.). Very strict demands are made on the reliability, durability, and mass/size characteristics of the pumps and on all the equipment of the mobile installations. In modern pumps, an axial load of up to 100 tons or more, which is transmitted to the crankshaft, acts on each plunger. The engine of the installation rotates the crankshaft through a multiple-speed transmission and the transmission shaft of the pump. The forces acting on the elements of the driving part of a pump with a connecting rod - crank drive and a single-reduction tooth gear are described.

  17. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2001-06-27

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies will result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs.

  18. Increasing Heavy Oil Reserves in the Wilmington Oil Field through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect

    City of Long Beach; David K.Davies and Associates; Tidelands Oil Production Company; University of Southern California

    1999-06-25

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California. This is realized through the testing and application of advanced reservoir characterization and thermal production technologies. It is hoped that the successful application of these technologies will result in their implementation throughout the Wilmington Field and through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively insufficient because of several producability problems which are common in SBC reservoir; inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves.

  19. INCREASED OIL RECOVERY FROM MATURE OIL FIELDS USING GELLED POLYMER TREATMENTS

    SciTech Connect

    G.P. Willhite; D.W. Green; C.S. McCool

    2003-05-01

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of a three-year research program aimed at reducing barriers to the widespread use of gelled polymer treatments by (1) developing methods to predict gel behavior during placement in matrix rock and fractures, (2) determining the persistence of permeability reduction after gel placement, and (3) developing methods to design production well treatments to control water production. The work focused on the gel system composed of polyacrylamide and chromium acetate. The molar mass of the polymer was about six million. Chromium(III) acetate reacted and formed crosslinks between polymer molecules. The crosslinked polymer molecules, or pre-gel aggregates, combine and grow to eventually form a 3-dimensional gel. A fundamental study to characterize the formation and growth of pre-gel aggregates was conducted. Two methods, flow field-flow fractionation (FFFF) and multi-angle laser light scattering (MALLS) were used. Studies using FFFF were inconclusive. Data taken using MALLS showed that at the gel time the average molar mass of gel aggregates increased by a factor of about three while the average size increase was approximately 50%. Increased acetate concentration in the gelant increases the gel time. The in situ performance of an added-acetate system was investigated to determine the applicability for in-depth treatments. Increased acetate concentrations delayed the development of increased flow resistance during gelant injection in short sandpacks. The development of increased flow resistance (in situ gelation) was extended from 2 to 34 days by increasing the acetate-to-chromium ratio from 38 to 153. In situ gelation occurred at a time that was approximately 22% of the bulk gelation time. When carbonate rocks are treated with gel, chromium retention in the rock may limit in-depth treatment. Chromium retention due to precipitation was investigated by flowing chromium acetate solutions through carbonate rock. Chromium precipitated faster in the rocks than in beaker experiments at similar conditions. A mathematical model previously developed fit the precipitation data reasonably well. The stability of gels when subjected to stress was investigated by experiments with gels placed in tubes and in laboratory-scale fractures. Rupture pressures for gels placed in small diameter tubes were correlated with the ratio of tube length to tube ID. In fractures, fluid leakoff from the fracture to adjacent matrix rock affected gel formation and gel stability in a positive way. Disproportionate permeability reduction (DPR) was studied in unconsolidated sandpacks and in Berea sandstone cores. A conceptual model was developed to explain the presence of DPR. The effect of a pressure gradient, imposed by injection of oil or brine, on the permeability of gel-treated cores was investigated. DPR increased significantly as the pressure gradient was decreased. The magnitude of the pressure gradient had a much larger effect on water permeability than on oil permeability.

  20. Economic evaluation on CO₂-EOR of onshore oil fields in China

    SciTech Connect

    Wei, Ning; Li, Xiaochun; Dahowski, Robert T.; Davidson, Casie L.; Liu, Shengnan; Zha, Yongjin

    2015-06-01

    Carbon dioxide enhanced oil recovery (CO₂-EOR) and sequestration in depleted oil reservoirs is a plausible option for utilizing anthropogenic CO₂ to increase oil production while storing CO₂ underground. Evaluation of the storage resources and cost of potential CO₂-EOR projects is an essential step before the commencement of large-scale deployment of such activities. In this paper, a hybrid techno-economic evaluation method, including a performance model and cost model for onshore CO₂-EOR projects, has been developed based on previous studies. Total 296 onshore oil fields, accounting for about 70% of total mature onshore oil fields in China, were evaluated by the techno-economic method. The key findings of this study are summarized as follows: (1) deterministic analysis shows there are approximately 1.1 billion tons (7.7 billion barrels) of incremental crude oil and 2.2 billion tons CO₂ storage resource for onshore CO₂-EOR at net positive revenue within the Chinese oil fields reviewed under the given operating strategy and economic assumptions. (2) Sensitivity study highlights that the cumulative oil production and cumulative CO₂ storage resource are very sensitive to crude oil price, CO₂ cost, project lifetime, discount rate and tax policy. High oil price, short project lifetime, low discount rate, low CO₂ cost, and low tax policy can greatly increase the net income of the oil enterprise, incremental oil recovery and CO₂ storage resource. (3) From this techno-economic evaluation, the major barriers to large-scale deployment of CO₂-EOR include complex geological conditions, low API of crude oil, high tax policy, and lack of incentives for the CO₂-EOR project.

  1. Economic evaluation on CO₂-EOR of onshore oil fields in China

    DOE PAGESBeta

    Wei, Ning; Li, Xiaochun; Dahowski, Robert T.; Davidson, Casie L.; Liu, Shengnan; Zha, Yongjin

    2015-06-01

    Carbon dioxide enhanced oil recovery (CO₂-EOR) and sequestration in depleted oil reservoirs is a plausible option for utilizing anthropogenic CO₂ to increase oil production while storing CO₂ underground. Evaluation of the storage resources and cost of potential CO₂-EOR projects is an essential step before the commencement of large-scale deployment of such activities. In this paper, a hybrid techno-economic evaluation method, including a performance model and cost model for onshore CO₂-EOR projects, has been developed based on previous studies. Total 296 onshore oil fields, accounting for about 70% of total mature onshore oil fields in China, were evaluated by the techno-economicmore » method. The key findings of this study are summarized as follows: (1) deterministic analysis shows there are approximately 1.1 billion tons (7.7 billion barrels) of incremental crude oil and 2.2 billion tons CO₂ storage resource for onshore CO₂-EOR at net positive revenue within the Chinese oil fields reviewed under the given operating strategy and economic assumptions. (2) Sensitivity study highlights that the cumulative oil production and cumulative CO₂ storage resource are very sensitive to crude oil price, CO₂ cost, project lifetime, discount rate and tax policy. High oil price, short project lifetime, low discount rate, low CO₂ cost, and low tax policy can greatly increase the net income of the oil enterprise, incremental oil recovery and CO₂ storage resource. (3) From this techno-economic evaluation, the major barriers to large-scale deployment of CO₂-EOR include complex geological conditions, low API of crude oil, high tax policy, and lack of incentives for the CO₂-EOR project.« less

  2. Petroleum geology of Sespe field: new oil from an old field

    SciTech Connect

    Lankford, S.M.; Pasquini, D.E.

    1986-04-01

    The Sespe field, discovered 100 years ago, is situated along the north flank of the Ventura basin on the upthrown side of the San Cayetano fault. Production zones range from Eocene to Miocene in age and include the Matilija, Coldwater, and Vaqueros Formations. The Oligocene Sespe Formation is the primary producing zone. Fractured shale of the Miocene Rincon formation also produced but is no longer considered a target. Recent developments demonstrate how additional reserves can be established and produced from an old and nearly fully developed field. A multi-tiered exploitation program ultimately should establish significant new reserves. The field has been drilled on 10-ac spacing, but several recently drilled wells demonstrated that production can be enhanced by infill drilling on 5-ac spacing. The infill wells not only decrease recovery time of proved reserves, but also increase the recoverability of in-place oil from 9% to about 14%. Waterflooding may enhance recoverability even further. After at least nine infill patterns have been drilled, a pilot waterflood project has been planned to determine if displacement can be conducted economically. The authors believe the incremental increase in recoverable reserves of the projects discussed may ultimately exceed all the petroleum produced in the past 100 years. The Sespe field serves as an example of an example of an old field that can be made to yield important new reserves at relatively low risk.

  3. Environmental effects of the Kuwaiti oil field fires

    SciTech Connect

    Hahn, J. )

    1991-09-01

    Theory suggests that the rates of smoke emission and heat generation and, consequently, the atmospheric injection height and residence time of the smoke are crucial in determining whether the environmental effects are of global or only regional importance. Confirming the results of model calculations, observations have shown that, up to now, the smoke did not rise higher than to the top of the planetary boundary layer (PBL), about 3,300 m at a maximum. The photochemistry within the smoke cloud very likely is significantly different from that of the smoke-free troposphere. Also, because there is very little precipitation in the greater Gulf region from May through October, it is difficult to predict how and where NO{sub x}, SO{sub 2}, and their oxidation products HNO{sub 3} and H{sub 2}SO{sub 4} will be deposited. Photochemical oxidation should be largely suppressed in the denser parts of the smoke cloud, so major acid deposition is likely to occur at some distance from the source area, probably as far away as 2,000 km. Results of model calculations suggest that the effect of the smoke emission in Kuwait on the Asian summer monsoon is small. In summary, one should expect severe environmental consequences of the Kuwaiti oil field fires for the territory of Kuwait and for parts of Iraq, Jordan, and Saudi Arabia. Serious effects also may be felt in Iran and the other Gulf states, and perhaps even as far away as Turkey and Afghanistan. The surface waters of the Gulf also may be severely affected by smoke deposition. Significant environmental effects on a global or even hemispheric scale, however, are not likely to occur.

  4. Composition and structure of asphalthene components of oils from the Krapivinskoye oil field

    NASA Astrophysics Data System (ADS)

    Sergun, Valery P.; Cheshkova, Tatiana V.; Sagachenko, Tatiana A.; Min, Raissa S.

    2015-10-01

    Asphaltene substances of oil are characterized via the methods of extraction, adsorption chromatography, chemical degradation, and chromatography-mass spectrometry. The data on the structure of the high- and low molecular weight asphaltenes of methane-naphthene oils and composition of the compounds adsorbed/occluded by their molecules are presented. These investigations are important for the development of efficient petroleum technologies.

  5. IMPROVED APPROACHES TO DESIGN OF POLYMER GEL TREATMENTS IN MATURE OIL FIELDS: FIELD DEMONSTRATION IN DICKMAN FIELD, NESS COUNTY, KANSAS

    SciTech Connect

    Ronald Fowler

    2004-11-30

    This report describes the results of the one-year project entitled ''Improved Approaches to Design of Polymer Gel Treatments in Mature Oil Fields: Field Demonstration in Dickman Field, Ness County, Kansas''. The project was a 12-month collaboration of Grand Mesa Operating Company (a small independent), TIORCO Inc. (a company focused on improved recovery technology) and the University of Kansas. The study undertook tasks to determine an optimum polymer gel treatment design in Mississippian reservoirs, demonstrate application, and evaluate the success of the program. The project investigated geologic and engineering parameters and cost-effective technologies required for design and implementation of effective polymer gel treatment programs in the Mississippian reservoir in the Midcontinent. The majority of Mississippian production in Kansas occurs at or near the top of the Mississippian section just below the regional sub-Pennsylvanian unconformity and karst surface. Dickman Field with the extremely high water cuts and low recovery factors is typical of Mississippian reservoirs. Producibility problems in these reservoirs include inadequate reservoir characterization, drilling and completion design problems, and most significantly extremely high water cuts and low recovery factors that place continued operations at or near their economic limits. Geologic, geophysical and engineering data were integrated to provide a technical foundation for candidate selection and treatment design. Data includes core, engineering data, and 3D seismic data. Based on technical and economic considerations a well was selected for gel-polymer treatment (Grand Mesa Operating Company Tilley No.2). The treatment was not successful due to the small amount of polymer that could be injected. Data from the initial well and other candidates in the demonstration area was analyzed using geologic, geophysical and engineering data. Based on the results of the treatment and the integrated reservoir characterization it was determined that a second polymer-gel treatment could not be justified. The Mississippian reservoir at Dickman Field is much more complex than originally anticipated with numerous reservoir compartments and potential attic oil beneath the irregular Mississippian karst. It appears that remaining oil in place could be best recovered using improved oil recovery techniques such as target infill drilling and horizontal wells.

  6. On the origin of oil-field water in the Biyang Depression of China

    NASA Astrophysics Data System (ADS)

    Fu, Yong; Zhan, Hongbin

    2009-09-01

    We have surveyed groundwater samples collected from oil and gas reservoirs in the Biyang Depression of China and quantitatively analyzed the chemical features of those samples using the proportional coefficients. Three different proportional coefficients, namely the de-calcium-magnesium, the boron-calcium-magnesium, and the chloration coefficients have been calculated. These three coefficients reflect the strength of de-calcium-magnesium reaction, the trace elements concentrations, and the degree of diagenesis of the oil-field water, respectively. The concentrations of calcium and magnesium ions are found to be very low in the groundwater of the Biyang Depression. The concentration of anion in the oil-field groundwater changes greatly with the salinity of groundwater in the Biyang Depression. In low salinity oil field, bicarbonate is generally the dominating anion; but when salinity increases, sulfate gradually replaces bicarbonate to become the dominating anion. However, in high salinity oil field, chloride is the dominating anion. Bromine, iodine, and boron are found to be relatively rich in oil-field water of Biyang Depression. The results show that extensive dolomite deposited near the center of the depression was resulted from de-calcium-magnesium reaction, and the degree of diagenesis of the oil-field water and concentrations of trace elements increase with buried depth in the reservoir.

  7. ALASKA NORTH SLOPE OIL-FIELD RESTORATION RESEARCH STRATEGY (ANSORRS)

    EPA Science Inventory

    This document provides a research strategy to support ecological restoration of disturbances related to oil and gas developments on the North Slope of Alaska that is mutually beneficial to the arctic ecorestoration research community and the arctic regulatory community (including...

  8. Chemical composition of asphaltenes of crude oil from Baradero field in Cuba

    SciTech Connect

    Platonov, V.V.; Proskuryakov, V.A.; Klyavina, O.A.; Kolyabina, N.A.

    1994-09-10

    Asphaltenes of crude oil from Baradero field in Cuba have been studied by physical and physicochemical methods. Dynamics of distribution of nitrogen, sulfur, and oxygen and also various functional groups in asphaltenes has been described. These data can be used for the proper deasphalting of crude oil and further treatment of asphaltenes.

  9. Composition and Physical Properties of Cress (Lepidium sativum L.) and Field Pennycress (Thlaspi arvense L.) Oils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The fatty acid profile and tocopherol, and phytosterol contents of crude cress (Lepidium sativum L.) and field pennycress (Thlaspi arvense L.) oils are reported, along with yields from the corresponding seeds. The physical properties of these oils were also determined, which included oxidative stab...

  10. Production and Evaluation of Biodiesel from Field Pennycress (Thlaspi Arvense L.) Oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Field pennycress (Thlaspi arvense L.) oil is evaluated for the first time as a potential feedstock for biodiesel production. Biodiesel was obtained in 82 wt % yield by a standard transesterification procedure with methanol and sodium methoxide catalyst at 60 deg C and an alcohol to oil ratio of 6:1...

  11. An Analysis of the Distribution and Economics of Oil Fields for Enhanced Oil Recovery-Carbon Capture and Storage

    NASA Astrophysics Data System (ADS)

    Hall, Kristyn Ann

    The rising carbon dioxide emissions contributing to climate change has lead to the examination of potential ways to mitigate the environmental impact. One such method is through the geological sequestration of carbon (CCS). Although there are several different forms of geological sequestration (i.e. Saline Aquifers, Oil and Gas Reservoirs, Unminable Coal Seams) the current projects are just initiating the large scale-testing phase. The lead entry point into CCS projects is to combine the sequestration with enhanced oil recovery (EOR) due to the improved economic model as a result of the oil recovery and the pre-existing knowledge of the geological structures. The potential scope of CCS-EOR projects throughout the continental United States in terms of a systematic examination of individual reservoir storage potential has not been examined. Instead the majority of the research completed has centered on either estimating the total United States storage potential or the potential of a single specific reservoir. The purpose of this paper is to examine the relationship between oil recovery, carbon dioxide storage and cost during CCS-EOR. The characteristics of the oil and gas reservoirs examined in this study from the Nehring Oil and Gas Database were used in the CCS-EOR model developed by Sean McCoy to estimate the lifting and storage costs of the different reservoirs throughout the continental United States. This allows for an examination of both technical and financial viability of CCS-EOR as an intermediate step for future CCS projects in other geological formations. One option for mitigating climate change is to store industrial CO2 emissions in geologic reservoirs as part of a process known as carbon capture and storage (CCS). There is general consensus that large-scale deployment of CCS would best be initiated by combining geologic sequestration with enhanced oil recovery (EOR), which can use CO2 to improve production from declining oil fields. Revenues from the produced oil could help offset the current high costs of CCS. The cumulative potential of CCS-EOR in the continental U.S. has been evaluated in terms of both CO2 storage capacity and additional oil production. This thesis examines the same potential, but on a reservoir-by-reservoir basis. Reservoir properties from the Nehring Oil and Gas Database are used as inputs to a CCS-EOR model developed by McCoy (YR) to estimate the storage capacity, oil production and CCS-EOR costs for over 10,000 oil reservoirs located throughout the continental United States. We find that 86% of the reservoirs could store ≤1 y or CO2 emissions from a single 500 MW coal-fired power plant (i.e., 3 Mtons CO2). Less than 1% of the reservoirs, on the other hand, appear capable of storing ≥30 y of CO2 emissions from a 500 MW plan. But these larger reservoirs are also estimated to contain 48% of the predicted additional oil that could be produced through CCS-EOR. The McCoy model also predicts that the reservoirs will on average produce 4.5 bbl of oil for each ton of sequestered CO2, a ratio known as the utilization factor. This utilization factor is 1.5 times higher that arrived at by the U.S. Department of Energy, and leads to a cumulative production of oil for all the reservoirs examined of ˜183 billion barrels along with a cumulative storage capacity of 41 Mtons CO2. This is equivalent to 26.5 y of current oil consumption by the nation, and 8.5 y of current coal plant emissions.

  12. Enhancement of the TORIS data base of Appalachian basin oil fields. Final report

    SciTech Connect

    1996-01-31

    The Tertiary Oil Recovery Information System, or TORIS, was developed by the Department of Energy in the early 1980s with a goal of accounting for 70% of the nation`s original oil in place (OOIP). More than 3,700 oil reservoirs were included in TORIS, but coverage in the Appalachian basin was poor. This TORIS enhancement project has two main objectives: to increase the coverage of oil fields in the Appalachian basin; and to evaluate data for reservoirs currently in TORIS, and to add, change or delete data as necessary. Both of these objectives have been accomplished. The geological surveys in Kentucky, Ohio, Pennsylvania and West Virginia have identified 113 fields in the Appalachian basin to be included in TORIS that collectively contained 80% of the original oil in place in the basin. Furthermore, data in TORIS at the outset of the project was checked and additional data were added to the original 20 TORIS oil fields. This final report is organized into four main sections: reservoir selection; evaluation of data already in TORIS; industry assistance; and data base creation and validation. Throughout the report the terms pool and reservoir may be used in reference to a single zone of oil accumulation and production within a field. Thus, a field is composed of one or more pools at various stratigraphic levels. These pools or reservoirs also are referred to as pay sands that may be individually named sandstones within a formation or group.

  13. Geochemistry of Eagle Ford group source rocks and oils from the first shot field area, Texas

    USGS Publications Warehouse

    Edman, Janell D.; Pitman, Janet K.

    2010-01-01

    Total organic carbon, Rock-Eval pyrolysis, and vitrinite reflectance analyses performed on Eagle Ford Group core and cuttings samples from the First Shot field area, Texas demonstrate these samples have sufficient quantity, quality, and maturity of organic matter to have generated oil. Furthermore, gas chromatography and biomarker analyses performed on Eagle Ford Group oils and source rock extracts as well as weight percent sulfur analyses on the oils indicate the source rock facies for most of the oils are fairly similar. Specifically, these source rock facies vary in lithology from shales to marls, contain elevated levels of sulfur, and were deposited in a marine environment under anoxic conditions. It is these First Shot Eagle Ford source facies that have generated the oils in the First Shot Field. However, in contrast to the generally similar source rock facies and organic matter, maturity varies from early oil window to late oil window in the study area, and these maturity variations have a pronounced effect on both the source rock and oil characteristics. Finally, most of the oils appear to have been generated locally and have not experienced long distance migration. 

  14. 37. SAR2, SHOWING OIL CIRCUIT BREAKERS (ABOVE) AND GENERATOR FIELD ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    37. SAR-2, SHOWING OIL CIRCUIT BREAKERS (ABOVE) AND GENERATOR FIELD COIL CONTROL RHEOSTATS (BELOW). SCE negative no. 10331, November 1, 1923. Photograph by G. Haven Bishop. - Santa Ana River Hydroelectric System, SAR-2 Powerhouse, Redlands, San Bernardino County, CA

  15. The space-time structure of oil and gas field growth in a complex depositional system

    USGS Publications Warehouse

    Drew, L.J.; Mast, R.F.; Schuenemeyer, J.H.

    1994-01-01

    Shortly after the discovery of an oil and gas field, an initial estimate is usually made of the ultimate recovery of the field. With the passage of time, this initial estimate is almost always revised upward. The phenomenon of the growth of the expected ultimate recovery of a field, which is known as "field growth," is important to resource assessment analysts for several reasons. First, field growth is the source of a large part of future additions to the inventory of proved reserves of crude oil and natural gas in most petroliferous areas of the world. Second, field growth introduces a large negative bias in the forecast of the future rates of discovery of oil and gas fields made by discovery process models. In this study, the growth in estimated ultimate recovery of oil and gas in fields made up of sandstone reservoirs formed in a complex depositional environment (Frio strand plain exploration play) is examined. The results presented here show how the growth of oil and gas fields is tied directly to the architectural element of the shoreline processes and tectonics that caused the deposition of the individual sand bodies hosting the producible hydrocarbon. ?? 1994 Oxford University Press.

  16. The artificial neural network for research of the recovery ratio of oil fields

    SciTech Connect

    Cai, Y.

    1994-12-31

    A typical artificial neural network model--back-propagation model was applied to establish a computer expert system for the prediction of recovery ration with the Hajiang Oil Field as the example in this paper. The results was satisfactory and the maximum relative error doesn`t exceed 4.6%. The calculation time doesn`t exceed 140 seconds. The results showed that the network method is good, and therefore it might be widely used in developing oil fields.

  17. Fabrication of superhydrophobic/superoleophilic cotton for application in the field of water/oil separation.

    PubMed

    Liu, Feng; Ma, Miaolian; Zang, Deli; Gao, Zhengxin; Wang, Chengyu

    2014-03-15

    Cotton with superhydrophobic and superoleophilic properties had been successfully fabricated for application in the field of oil/water separation by the combination of SiO2 nanoparticles on cotton fiber surface and subsequent octadecyltrichlorosilane modification. The as-prepared cotton could be used to selectively absorb various common oils and organic solvents up to above 50 times of its own weight while repelling water completely. The absorbed oils were easily collected by a simple vacuum filtration, and the recovered cotton could be reused for several cycles while still keeping high absorption capacity. Moreover, the as-prepared cotton was simply spun into cloth, which not only could be tailored to the water-repellent clothing but also could be used in the oil/water separation filter system. The results presented in this work might provide a simple, low-cost and environment friendly approach for application in the field of water/oil separation. PMID:24528757

  18. Geothermal studies in oil field districts of North China

    NASA Astrophysics Data System (ADS)

    Wang, Ji-An; Wang, Ji-Yang; Yan, Shu-Zhen; Lu, Xiu-Wen

    In North China, Tertiary sediments give the main oil-genetic series. The mean value of terrestrial heat flow density has been considered to be 60 - 65 mW/m2, and the geothermal gradient in Tertiary sediments usually ranges from 30 to 40° C/km in the region studied. Supposing that the onset of oil generation lies at about 90° C, the upper limit of the depth of oil-generation is at about 2000 to 2500 m depth. Recent paleogeothermal studies using vitrinite reflectance, clay and authigenic minerals, as well as other methods showed that in Eocene the geothermal gradient has been higher than at present. Some results were obtained and discussed.

  19. Volumetric calculations in an oil field: The basis method

    USGS Publications Warehouse

    Olea, R.A.; Pawlowsky, V.; Davis, J.C.

    1993-01-01

    The basis method for estimating oil reserves in place is compared to a traditional procedure that uses ordinary kriging. In the basis method, auxiliary variables that sum to the net thickness of pay are estimated by cokriging. In theory, the procedure should be more powerful because it makes full use of the cross-correlation between variables and forces the original variables to honor interval constraints. However, at least in our case study, the practical advantages of cokriging for estimating oil in place are marginal. ?? 1993.

  20. De-convoluting mixed crude oil in Prudhoe Bay Field, North Slope, Alaska

    USGS Publications Warehouse

    Peters, K.E.; Scott, Ramos L.; Zumberge, J.E.; Valin, Z.C.; Bird, K.J.

    2008-01-01

    Seventy-four crude oil samples from the Barrow arch on the North Slope of Alaska were studied to assess the relative volumetric contributions from different source rocks to the giant Prudhoe Bay Field. We applied alternating least squares to concentration data (ALS-C) for 46 biomarkers in the range C19-C35 to de-convolute mixtures of oil generated from carbonate rich Triassic Shublik Formation and clay rich Jurassic Kingak Shale and Cretaceous Hue Shale-gamma ray zone (Hue-GRZ) source rocks. ALS-C results for 23 oil samples from the prolific Ivishak Formation reservoir of the Prudhoe Bay Field indicate approximately equal contributions from Shublik Formation and Hue-GRZ source rocks (37% each), less from the Kingak Shale (26%), and little or no contribution from other source rocks. These results differ from published interpretations that most oil in the Prudhoe Bay Field originated from the Shublik Formation source rock. With few exceptions, the relative contribution of oil from the Shublik Formation decreases, while that from the Hue-GRZ increases in reservoirs along the Barrow arch from Point Barrow in the northwest to Point Thomson in the southeast (???250 miles or 400 km). The Shublik contribution also decreases to a lesser degree between fault blocks within the Ivishak pool from west to east across the Prudhoe Bay Field. ALS-C provides a robust means to calculate the relative amounts of two or more oil types in a mixture. Furthermore, ALS-C does not require that pure end member oils be identified prior to analysis or that laboratory mixtures of these oils be prepared to evaluate mixing. ALS-C of biomarkers reliably de-convolutes mixtures because the concentrations of compounds in mixtures vary as linear functions of the amount of each oil type. ALS of biomarker ratios (ALS-R) cannot be used to de-convolute mixtures because compound ratios vary as nonlinear functions of the amount of each oil type.

  1. Seed oil development of pennycress under field conditions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Pennycress (Thlaspi sp) has been targeted as a potential oilseed for the biofuels industry. Its seeds contain ~36% oil, where erucic acid is the major fatty acid presented with 38.1%. Additionally, the physical proprieties of the methyl esters are in the range to satisfy the needs of the biodiesel m...

  2. Oil, gas field growth projections: Wishful thinking or reality?

    USGS Publications Warehouse

    Attanasi, E.D.; Mast, R.F.; Root, D.H.

    1999-01-01

    The observed `field growth' for the period from 1992 through 1996 with the US Geological Survey's (USGS) predicted field growth for the same period are compared. Known field recovery of field size is defined as the sum of past cumulative field production and the field's proved reserves. Proved reserves are estimated quantities of hydrocarbons which geologic and engineering data demonstrate with reasonable certainty to recoverable from known fields under existing economic and operating conditions. Proved reserve estimates calculated with this definition are typically conservative. The modeling approach used by the USGS to characterize `field growth phenomena' is statistical rather that geologic in nature.

  3. [Separation of alkylphenols in oil field water by micellar electrokinetic chromatography].

    PubMed

    Liu, C; Ma, T; Zhang, B; Wang, P; Fang, X; Li, H

    1999-05-01

    The abundance of alkylphenols in the system of water, oil and rock is of great geochemistry significance. The analysis of alkylphenols in oil field water using micellar electrokinetic chromatography with UV detection is described. The different variables that affect separation were studied and optimized. The results show that better separation was obtained with the borate concentration of 47.5 mmol/L, the SDS concentration of 70.0 mmol/L, pH 9.15, separation current of 100 microA, capillary temperature 20 degrees C. The organic additive(beta-CD) could partly improve separation. Water sample was introduced into the capillary by pressure of 5 kPa for several seconds. Detection wavelength was 200 nm and reference wavelength at 350 nm for all experiments. For the oil field water sample, the reproducibility of directly injected oil field water after filtration through a membrane filter of 0.45 micron pore size was far from good and it's concentrations of alkylphenols were too low to be detected. Therefore, a method of separation and enrichment by a column packed with tributyl phosphate(TBP) extraction resin was applied for analysis of TZ4 oil field water. Qualitative analysis show that there are phenol, o-cresol, m-cresol and p-cresol in this water sample and phenol is the main component and it's quantity is more than other alkylphenols. It's recoveries from the oil field water were 91.5%-95.3%. The results were satisfactory. PMID:12549115

  4. Preliminary technical and legal evaluation of disposing of nonhazardous oil field waste into salt caverns

    SciTech Connect

    Veil, J.; Elcock, D.; Raivel, M.; Caudle, D.; Ayers, R.C. Jr.; Grunewald, B.

    1996-06-01

    Caverns can be readily formed in salt formations through solution mining. The caverns may be formed incidentally, as a result of salt recovery, or intentionally to create an underground chamber that can be used for storing hydrocarbon products or compressed air or disposing of wastes. The purpose of this report is to evaluate the feasibility, suitability, and legality of disposing of nonhazardous oil and gas exploration, development, and production wastes (hereafter referred to as oil field wastes, unless otherwise noted) in salt caverns. Chapter 2 provides background information on: types and locations of US subsurface salt deposits; basic solution mining techniques used to create caverns; and ways in which salt caverns are used. Later chapters provide discussion of: federal and state regulatory requirements concerning disposal of oil field waste, including which wastes are considered eligible for cavern disposal; waste streams that are considered to be oil field waste; and an evaluation of technical issues concerning the suitability of using salt caverns for disposing of oil field waste. Separate chapters present: types of oil field wastes suitable for cavern disposal; cavern design and location; disposal operations; and closure and remediation. This report does not suggest specific numerical limits for such factors or variables as distance to neighboring activities, depths for casings, pressure testing, or size and shape of cavern. The intent is to raise issues and general approaches that will contribute to the growing body of information on this subject.

  5. Update on cavern disposal of NORM-contaminated oil field wastes.

    SciTech Connect

    Veil, J. A.

    1998-09-22

    Some types of oil and gas production and processing wastes contain naturally occurring radioactive material (NORM). If NORM is present at concentrations above regulatory levels in oil field waste, the waste requires special disposal practices. The existing disposal options for wastes containing NORM are limited and costly. Argonne National Laboratory has previously evaluated the feasibility, legality, risk and economics of disposing of nonhazardous oil field wastes, other than NORM waste, in salt caverns. Cavern disposal of nonhazardous oil field waste, other than NORM waste, is occurring at four Texas facilities, in several Canadian facilities, and reportedly in Europe. This paper evaluates the legality, technical feasibility, economics, and human health risk of disposing of NORM-contaminated oil field wastes in salt caverns as well. Cavern disposal of NORM waste is technically feasible and poses a very low human health risk. From a legal perspective, a review of federal regulations and regulations from several states indicated that there are no outright prohibitions against NORM disposal in salt caverns or other Class II wells, except for Louisiana which prohibits disposal of radioactive wastes or other radioactive materials in salt domes. Currently, however, only Texas and New Mexico are working on disposal cavern regulations, and no states have issued permits to allow cavern disposal of NORM waste. On the basis of the costs currently charged for cavern disposal of nonhazardous oil field waste (NOW), NORM waste disposal in caverns is likely to be cost competitive with existing NORM waste disposal methods when regulatory agencies approve the practice.

  6. An overview of giant oil and gas fields of the decade: 1978-1988

    SciTech Connect

    Halbouty, M.T. )

    1990-09-01

    Scientific studies and projections of future world energy demand indicate that although alternate-energy fuel sources must be actively pursued and developed, there must be adequate petroleum supplies to bridge the gap. For the international petroleum industry, the years covered by this conference, 1978-1988, were complex. They were years of boom and bust. The world's energy consciousness was boosted sharply by the effects of the 1979 Iranian revolution and the resulting embargo that sent world oil prices to record heights. Global petroleum exploration soon surged, leading to the industry's all-time drilling high in 1981. Then came the oil price collapse in 1985, and the following years were characterized by falling oil prices and drastic budget cuts for exploration and development. Although exploration dropped sharply, there was a steady flow of giant oil and gas field discoveries. Using the giant field designation criteria of 500 million bbl of oil recoverable for fields in Asiatic Russia, North Africa, and the Middle East; 100 million bbl of oil recoverable for the fields in the remainder of the world; and 3 tcf and 1 tcf of gas reserves recoverable for the same areas, respectively, it is estimated that at least 182 oil and gas fields containing an estimated 140 billion BOE were discovered in 46 countries during the years covered by this conference. Today, exploration is slowly gaining momentum in all types of petroleum provinces-intensely explored, partially explored, moderately explored, and essentially unexplored - and as long as exploration continues in whatever area of the world, there will always be opportunities to find giant oil and gas fields.

  7. Assessment of Alaska's North Slope Oil Field Capacity to Sequester CO{sub 2}

    SciTech Connect

    Umekwe, Pascal; Mongrain, Joanna; Ahmadi, Mohabbat; Hanks, Catherine

    2013-03-15

    The capacity of 21 major fields containing more than 95% of the North Slope of Alaska's oil were investigated for CO{sub 2} storage by injecting CO{sub 2} as an enhanced oil recovery (EOR) agent. These fields meet the criteria for the application of miscible and immiscible CO{sub 2}-EOR methods and contain about 40 billion barrels of oil after primary and secondary recovery. Volumetric calculations from this study indicate that these fields have a static storage capacity of 3 billion metric tons of CO{sub 2}, assuming 100% oil recovery, re-pressurizing the fields to pre-fracturing pressure and applying a 50% capacity reduction to compensate for heterogeneity and for water invasion from the underlying aquifer. A ranking produced from this study, mainly controlled by field size and fracture gradient, identifies Prudhoe, Kuparuk, and West Sak as possessing the largest storage capacities under a 20% safety factor on pressures applied during storage to avoid over-pressurization, fracturing, and gas leakage. Simulation studies were conducted using CO{sub 2} Prophet to determine the amount of oil technically recoverable and CO{sub 2} gas storage possible during this process. Fields were categorized as miscible, partially miscible, and immiscible based on the miscibility of CO{sub 2} with their oil. Seven sample fields were selected across these categories for simulation studies comparing pure CO{sub 2} and water-alternating-gas injection. Results showed that the top two fields in each category for recovery and CO{sub 2} storage were Alpine and Point McIntyre (miscible), Prudhoe and Kuparuk (partially miscible), and West Sak and Lisburne (immiscible). The study concludes that 5 billion metric tons of CO{sub 2} can be stored while recovering 14.2 billion barrels of the remaining oil.

  8. Complete Moment Tensor Determination of Induced Seismicity in Unconventional and Conventional Oil/Gas Fields

    NASA Astrophysics Data System (ADS)

    Gu, C.; Li, J.; Toksoz, M. N.

    2013-12-01

    Induced seismicity occurs both in conventional oil/gas fields due to production and water injection and in unconventional oil/gas fields due to hydraulic fracturing. Source mechanisms of these induced earthquakes are of great importance for understanding their causes and the physics of the seismic processes in reservoirs. Previous research on the analysis of induced seismic events in conventional oil/gas fields assumed a double couple (DC) source mechanism. However, recent studies have shown a non-negligible percentage of a non-double-couple (non-DC) component of source moment tensor in hydraulic fracturing events (Šílený et al., 2009; Warpinski and Du, 2010; Song and Toksöz, 2011). In this study, we determine the full moment tensor of the induced seismicity data in a conventional oil/gas field and for hydrofrac events in an unconventional oil/gas field. Song and Toksöz (2011) developed a full waveform based complete moment tensor inversion method to investigate a non-DC source mechanism. We apply this approach to the induced seismicity data from a conventional gas field in Oman. In addition, this approach is also applied to hydrofrac microseismicity data monitored by downhole geophones in four wells in US. We compare the source mechanisms of induced seismicity in the two different types of gas fields and explain the differences in terms of physical processes.

  9. Microbial Methane Production Associated with Carbon Steel Corrosion in a Nigerian Oil Field.

    PubMed

    Mand, Jaspreet; Park, Hyung S; Okoro, Chuma; Lomans, Bart P; Smith, Seun; Chiejina, Leo; Voordouw, Gerrit

    2015-01-01

    Microbially influenced corrosion (MIC) in oil field pipeline systems can be attributed to many different types of hydrogenotrophic microorganisms including sulfate reducers, methanogens and acetogens. Samples from a low temperature oil reservoir in Nigeria were analyzed using DNA pyrotag sequencing. The microbial community compositions of these samples revealed an abundance of anaerobic methanogenic archaea. Activity of methanogens was demonstrated by incubating samples anaerobically in a basal salts medium, in the presence of carbon steel and carbon dioxide. Methane formation was measured in all enrichments and correlated with metal weight loss. Methanogens were prominently represented in pipeline solids samples, scraped from the inside of a pipeline, comprising over 85% of all pyrosequencing reads. Methane production was only witnessed when carbon steel beads were added to these pipeline solids samples, indicating that no methane was formed as a result of degradation of the oil organics present in these samples. These results were compared to those obtained for samples taken from a low temperature oil field in Canada, which had been incubated with oil, either in the presence or in the absence of carbon steel. Again, methanogens present in these samples catalyzed methane production only when carbon steel was present. Moreover, acetate production was also found in these enrichments only in the presence of carbon steel. From these studies it appears that carbon steel, not oil organics, was the predominant electron donor for acetate production and methane formation in these low temperature oil fields, indicating that the methanogens and acetogens found may contribute significantly to MIC. PMID:26793176

  10. Microbial Methane Production Associated with Carbon Steel Corrosion in a Nigerian Oil Field

    PubMed Central

    Mand, Jaspreet; Park, Hyung S.; Okoro, Chuma; Lomans, Bart P.; Smith, Seun; Chiejina, Leo; Voordouw, Gerrit

    2016-01-01

    Microbially influenced corrosion (MIC) in oil field pipeline systems can be attributed to many different types of hydrogenotrophic microorganisms including sulfate reducers, methanogens and acetogens. Samples from a low temperature oil reservoir in Nigeria were analyzed using DNA pyrotag sequencing. The microbial community compositions of these samples revealed an abundance of anaerobic methanogenic archaea. Activity of methanogens was demonstrated by incubating samples anaerobically in a basal salts medium, in the presence of carbon steel and carbon dioxide. Methane formation was measured in all enrichments and correlated with metal weight loss. Methanogens were prominently represented in pipeline solids samples, scraped from the inside of a pipeline, comprising over 85% of all pyrosequencing reads. Methane production was only witnessed when carbon steel beads were added to these pipeline solids samples, indicating that no methane was formed as a result of degradation of the oil organics present in these samples. These results were compared to those obtained for samples taken from a low temperature oil field in Canada, which had been incubated with oil, either in the presence or in the absence of carbon steel. Again, methanogens present in these samples catalyzed methane production only when carbon steel was present. Moreover, acetate production was also found in these enrichments only in the presence of carbon steel. From these studies it appears that carbon steel, not oil organics, was the predominant electron donor for acetate production and methane formation in these low temperature oil fields, indicating that the methanogens and acetogens found may contribute significantly to MIC. PMID:26793176

  11. Increased Oil Recovery from Mature Oil Fields Using Gelled Polymer Treatments

    SciTech Connect

    Willhite, G.P.; Green, D.W.; McCool, S.

    2001-03-28

    Gelled polymer treatments were applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report is aimed at reducing barriers to the widespread use of these treatments by developing methods to predict gel behavior during placement in matrix rock and fractures, determining the persistence of permeability reduction after gel placement, and by developing methods to design production well treatments to control water production. Procedures were developed to determine the weight-average molecular weight and average size of polyacrylamide samples in aqueous solutions. Sample preparation techniques were key to achieving reproducible results.

  12. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Unknown

    2001-08-08

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a novel alkaline-steam well completion technique for the containment of the unconsolidated formation sands and control of fluid entry and injection profiles. (5) Installation of a 2100 ft, 14 inch insulated, steam line beneath a harbor channel to supply steam to an island location. (6) Testing and proposed application of thermal recovery technologies to increase oil production and reserves: (a) Performing pilot tests of cyclic steam injection and production on new horizontal wells. (b) Performing pilot tests of hot water-alternating-steam (WAS) drive in the existing steam drive area to improve thermal efficiency. (7) Perform a pilot steamflood with the four horizontal injectors and producers using a pseudo steam-assisted gravity-drainage (SAGD) process. (8) Advanced reservoir management, through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring and evaluation.

  13. Rapid subsidence over oil fields measured by SAR

    NASA Technical Reports Server (NTRS)

    Fielding, E. J.; Blom, R. G.; Goldstein, R. M.

    1998-01-01

    The Lost Hills and Belridge oil felds are in the San Joaquin Valley, California. The major oil reservoir is high porosity and low permeability diatomite. Extraction of large volumes from shallow depths causes reduction in pore pressure and subsequent compaction, forming a surface subsidence bowl. We measure this subsidence from space using interferometric analysis of SAR (Synthetic Aperture Radar) data collected by the European Space Agency Remote Sensing Satellites (ERS-1 and ERS-2). Maximum subsidence rates are as high as 40 mm in 35 days or > 400 mm/yr, measured from interferograms with time separations ranging from one day to 26 months. The 8- and 26-month interferograms contain areas where the subsidence gradient exceeds the measurement possible with ERS SAR, but shows increased detail in areas of less rapid subsidence. Synoptic mapping of subsidence distribution from satellite data powerfully complements ground-based techniques, permits measurements where access is difficult, and aids identification of underlying causes.

  14. Livestock poisoning from oil field drilling fluids, muds and additives

    SciTech Connect

    Edwards, W.C.; Gregory, D.G. )

    1991-10-01

    The use and potential toxicity of various components of oil well drilling fluids, muds and additives are presented. Many components are extremely caustic resulting in rumenitis. Solvent and petroleum hydrocarbon components may cause aspiration pneumonia and rumen dysfunction. Some additives cause methemoglobinemia. The most frequently encountered heavy metals are lead, chromium, arsenic, lithium and copper. Considerations for investigating livestock poisoning cases and several typical cases are reviewed.

  15. Petroleum geology of Giant oil and gas fields in Turpan Basin Xinjiang China

    SciTech Connect

    Boliang, Hu; Jiajing, Yang,

    1995-08-01

    Turpan Basin is the smallest and the last development basin in three big basins of Xinjiang autonomous region, P.R. China. Since April, 1989, the Shanshan oilfield was discovered, the Oinling, Wenjisang, Midang, Baka, Qiudong and North Putaogou fields were discovered. In 1994, the crude oil productivity of Turpan Basin was a Million tons, with an estimated output of 3 million tons per year by 1995; obviously a key oil productive base in the west basins of China, Tarim, Jungar, Chaidam, Hexi, Erduos and Sichuan Basins. The Turpan Basin is an intermontane basin in a eugeosyncline foldbelt of the north Tianshan Mountains. The oil and gas was produced from the payzone of the Xishanyao, Sanjianfang and Qiketai Formatiosn of the Middle Jurassic series. The geochemical characteristics of the crude oil and gas indicate they derive from the Middle to Lower Jurassic coal series, in which contains the best oil-prone source rocks in the basin.

  16. Evolution of hydrodynamic field, oil-gas migration and accumulation in Songliao Basin, China

    NASA Astrophysics Data System (ADS)

    Lou, Zhanghua; Zhu, Rong; Jin, Aimin; Sun, Maoming; Cai, Xiyuan; Chi, Yuanlin

    2004-06-01

    The oil-gas migration and accumulation in the Songliao Basin were analyzed in the view of fluid dynamics by the authors. The key point of fluid dynamics is hydrodynamics. Oil-gas migration and accumulation are related closely with formation and evolution of hydrodynamic field. Based on abundant data, initial formation pressure and other parameters, such as water head were studied. They can be used to understand the present distribution of hydrodynamic field and its hydrochemical features. Generally, the hydrodynamic field in the basin is obviously asymmetrical. In its north and east part, there are the areas of centripetal flow caused by topographic relief when meteoric water permeate downwards. Its south part is an evaporation-concentration area. The central depression is an area of centrifugal flow driven by sediment compaction and its cross-formational flow area. Only at the basin margin and in the local uplified and denudated area are the meteoric water permeating downwards areas. The centrifugal flow driven by sediment compaction is the main dynamic factor that induces oil-gas migration and accumulation and its formation period corresponding to the main stage of oil-gas migration and accumulation. Moreover, the evolution of hydrodynamic field has the cyclic property, which results in phased oil-gas migration by stages, and further dominates the terraced annular oil and gas distribution, concentric with their corresponding sags.

  17. Laboratory and field observations of stress-wave induced changes in oil flow behavior

    SciTech Connect

    Roberts, P. M.; Majer, Ernest Luther; Wooden, W.; Daley, T. M.

    2001-01-01

    We present recent results of laboratory and field experiments designed to validate and quantify the phenomenon of seismically enhanced oil production in marginal reservoirs. Controlled laboratory experiments were performed where mechanical stress oscillations at 100 Hz or less were applied to sandstone cores while flowing oil and/or brine at constant flow rates. Steady-state flow and simulated flooding experiments indicated that stress stimulation causes significant changes in the ability of one fluid to displace the other and on the preference that the rock has for trapping one fluid over the other. For Berea sandstone, which is highly water wet, stress stimulation caused oil production to be impeded during water floods and caused the bulk fluid pressure drop across the core to increase during steady-state simultaneous flow of oil and brine. A possible explanation of these observations is that stimulation caused the core to become more oil wet. Field stimulation tests on producing reservoirs at Lost Hills, California were performed using a downhole fluid pressure pulsation device. Stimulation was applied in one well for 50 days total during July - November 2000. Two groups of producing wells were monitored for changes in oil cut and oil production during the test. A control group of 26 wells displayed an oil-cut increase of 29% and an oil production increase of 26% which are clearly correlated with the stimulation treatment. A larger group of 60 wells showed 11% oil-cut and 17v0 production increases. Similar increases were observed during the October 1999 Hector Mine earthquake, magnitude 7.1, in the Mojave Desert about 230 miles from Lost Hills. Downhole seismic monitoring of the stimulation wavefield is being used to help quantify the frequency range and energy threshold required for effective production enhancement.

  18. Electric field and space charge distribution measurement in transformer oil struck by impulsive high voltage

    NASA Astrophysics Data System (ADS)

    Sima, Wenxia; Guo, Hongda; Yang, Qing; Song, He; Yang, Ming; Yu, Fei

    2015-08-01

    Transformer oil is widely used in power systems because of its excellent insulation properties. The accurate measurement of electric field and space charge distribution in transformer oil under high voltage impulse has important theoretical and practical significance, but still remains challenging to date because of its low Kerr constant. In this study, the continuous electric field and space charge distribution over time between parallel-plate electrodes in high-voltage pulsed transformer oil based on the Kerr effect is directly measured using a linear array photoelectrical detector. Experimental results demonstrate the applicability and reliability of this method. This study provides a feasible approach to further study the space charge effects and breakdown mechanisms in transformer oil.

  19. Spatial variations of hydrocarbon contamination and soil properties in oil exploring fields across China.

    PubMed

    Liang, Yuting; Zhang, Xu; Wang, Jian; Li, Guanghe

    2012-11-30

    Successful site remediation is critically based on a comprehensive understanding of distribution of contaminants, soil physico-chemical and microbial properties in oil contaminated sites. One hundred and ten topsoils were sampled from seven typical oil fields in different geoclimate regions across north to south China to investigate the spatial variances of oil contaminations and soil parameters. Oil concentrations and compositions, soil geochemical properties and microbial populations were analyzed and statistic analysis methods were used to analyze the spatial pattern of soil variables. The results indicated that oil contaminations were serious in most oil exploring areas in China, especially with high levels of polycyclic aromatic hydrocarbons (PAHs) from petrogenic origin. Ordination analyses indicated a relatively distinct spatial pattern that all soil samples grouped mainly by geographic locations, instead of distributing along contamination or other geochemical variable gradient. Microbial populations were found to be statistically positively correlated with soil nitrogen, phosphorus and water content, and negatively correlated with salt pH and soluble salts (P<0.05). This study provided insights into the spatial variability of soil variables in hydrocarbon-contaminated fields across large spatial scales, which is important for the environmental protection and further remediation in oil contaminated sites according to local conditions. PMID:23069331

  20. Process and economic model of in-field heavy oil upgrading using aqueous pyrolysis

    SciTech Connect

    Thorsness, C. B., LLNL

    1997-01-21

    A process and economic model for aqueous pyrolysis in-field upgrading of heavy oil has been developed. The model has been constructed using the ASPEN PLUS chemical process simulator. The process features cracking of heavy oil at moderate temperatures in the presence of water to increase oil quality and thus the value of the oil. Calculations with the model indicate that for a 464 Mg/day (3,000 bbl/day) process, which increases the oil API gravity of the processed oil from 13.5{degree} to 22.4{degree}, the required value increase of the oil would need to be at least $2.80/Mg{center_dot}{degree}API($0.40/bbl{center_dot}{degree}API) to make the process economically attractive. This level of upgrading has been demonstrated in preliminary experiments with candidate catalysts. For improved catalysts capable of having the coke make and increasing the pyrolysis rate, a required price increase for the oil as low as $1.34/Mg{center_dot}{degree}API ($0.21/bbl{center_dot}{degree}API)has been calculated.

  1. Economic assessment of environmental impact in the course of oil field development and production

    NASA Astrophysics Data System (ADS)

    Tsibulnikova, M. R.; Kupriyanova, O. S.; Strelnikova, A. B.

    2015-11-01

    The article considers the variety of impacts that oil exploration and production operations have on the environment at different stages of the process. To provide accurate economic assessment, an oil field development project was designed, with various development options. These options being analyzed, the strategy with the minimal environmental impact was identified. This has allowed preparation of a guideline on how to prevent deterioration of the environment and to reduce the negative environmental impact

  2. Arctic National Wildlife Refuge: oil field or wilderness

    SciTech Connect

    Spitler, A.

    1987-11-01

    The second session of the 100th Congress will see continued debate over the prospect of oil and gas drilling on a 19-million-acre expanse of mountains and tundra known as the Arctic National Wildlife Refuge (ANWR). The arctic refuge, most of which lies above the Arctic Circle, is larger than any refuges in the lower 48 states. Because of its size, the area supports a broad range of linked ecosystems. Of particular concern is the 1.5-million-acre coastal plain, which may be targeted for development. The coastal plain provides a home, at least part of the year, to Alaska's porcupine caribou. The coastal plain also supports many other forms of wildlife-including the wolf, arctic fox, brown bear, polar bear, and arctic peregrine falcon, which is listed as a threatened species. The potential effects of drilling projects extend beyond loss of wildlife; they include desecration of the land itself. Although few members of Congress deny the value of protecting the amazing variety of life on the coastal plain, some insist that limited drilling could be conducted without destroying crucial habitat. Last July, the department tentatively divided some of the targeted lands among native corporations in preparation for leasing to oil companies. In response to what was felt to be an attempt to overstep congressional authority, the House passed HR 2629, banning this kind of land deal without congressional approval. In essence, the measure reiterated congressional authority provided by the Alaska National Interest Lands Conservation Act (ANILCA) of 1980. This act mandated the study of environmental threats and oil potential by the Department of Interior, while putting the ANWR coastal plain off-limits to development without an explicit congressional directive.

  3. Methane-forming bacteria of oil-fields

    SciTech Connect

    Laurinavichus, K.S.; Obraztsova, A.Ya.; Belyaev, S.S.; Ivanov, M.V.

    1983-03-01

    Pure cultures of the methanogenic bacteria, Methanobacterium bryantii and M. formicicum have been isolated, for the first time from oil deposits and their morphological, physiological and biochemical properties studied. All strains grow of H/sub 2//CO/sub 2/ and two of the three M. formicicum also utilize formate as a role source of carbon and energy. In no case could methanol, acetate, methylamine or glucose serve as an energy source for these autotrophs. All strains were resistant to penicillin and streptomycin and neither sulfate or sulfide inhibited their growth. Medium salinity inhibited the growth of M. bryantii but not that of M. formicicum.

  4. New information on disposal of oil field wastes in salt caverns

    SciTech Connect

    Veil, J.A.

    1996-10-01

    Solution-mined salt caverns have been used for many years for storing hydrocarbon products. This paper summarizes an Argonne National Laboratory report that reviews the legality, technical suitability, and feasibility of disposing of nonhazardous oil and gas exploration and production wastes in salt caverns. An analysis of regulations indicated that there are no outright regulatory prohibitions on cavern disposal of oil field wastes at either the federal level or in the 11 oil-producing states that were studied. There is no actual field experience on the long-term impacts that might arise following closure of waste disposal caverns. Although research has found that pressures will build-up in a closed cavern, none has specifically addressed caverns filled with oil field wastes. More field research on pressure build-up in closed caverns is needed. On the basis of preliminary investigations, we believe that disposal of oil field wastes in salt caverns is legal and feasible. The technical suitability of the practice depends on whether the caverns are well-sited and well-designed, carefully operated, properly closed, and routinely monitored.

  5. Observed oil and gas field size distributions: A consequence of the discovery process and prices of oil and gas

    USGS Publications Warehouse

    Drew, L.J.; Attanasi, E.D.; Schuenemeyer, J.H.

    1988-01-01

    If observed oil and gas field size distributions are obtained by random samplings, the fitted distributions should approximate that of the parent population of oil and gas fields. However, empirical evidence strongly suggests that larger fields tend to be discovered earlier in the discovery process than they would be by random sampling. Economic factors also can limit the number of small fields that are developed and reported. This paper examines observed size distributions in state and federal waters of offshore Texas. Results of the analysis demonstrate how the shape of the observable size distributions change with significant hydrocarbon price changes. Comparison of state and federal observed size distributions in the offshore area shows how production cost differences also affect the shape of the observed size distribution. Methods for modifying the discovery rate estimation procedures when economic factors significantly affect the discovery sequence are presented. A primary conclusion of the analysis is that, because hydrocarbon price changes can significantly affect the observed discovery size distribution, one should not be confident about inferring the form and specific parameters of the parent field size distribution from the observed distributions. ?? 1988 International Association for Mathematical Geology.

  6. Genomic and Genotoxic Responses to Controlled Weathered-Oil Exposures Confirm and Extend Field Studies on Impacts of the Deepwater Horizon Oil Spill on Native Killifish

    PubMed Central

    Pilcher, Whitney; Miles, Scott; Tang, Song; Mayer, Greg; Whitehead, Andrew

    2014-01-01

    To understand the ecotoxicological impacts of the Deepwater Horizon oil spill, field studies provide a context for ecological realism but laboratory-based studies offer power for connecting biological effects with specific causes. As a complement to field studies, we characterized genome-wide gene expression responses of Gulf killifish (Fundulus grandis) to oil-contaminated waters in controlled laboratory exposures. Transcriptional responses to the highest concentrations of oiled water in the laboratory were predictive of field-observed responses that coincided with the timing and location of major oiling. The transcriptional response to the low concentration (∼10-fold lower than the high concentration) was distinct from the high concentration and was not predictive of major oiling in the field. The high concentration response was characterized by activation of the molecular signaling pathway that facilitates oil metabolism and oil toxicity. The high concentration also induced DNA damage. The low concentration invoked expression of genes that may support a compensatory response, including genes associated with regulation of transcription, cell cycle progression, RNA processing, DNA damage, and apoptosis. We conclude that the gene expression response detected in the field was a robust indicator of exposure to the toxic components of contaminating oil, that animals in the field were exposed to relatively high concentrations that are especially damaging to early life stages, and that such exposures can damage DNA. PMID:25208076

  7. Genomic and genotoxic responses to controlled weathered-oil exposures confirm and extend field studies on impacts of the Deepwater Horizon oil spill on native killifish.

    PubMed

    Pilcher, Whitney; Miles, Scott; Tang, Song; Mayer, Greg; Whitehead, Andrew

    2014-01-01

    To understand the ecotoxicological impacts of the Deepwater Horizon oil spill, field studies provide a context for ecological realism but laboratory-based studies offer power for connecting biological effects with specific causes. As a complement to field studies, we characterized genome-wide gene expression responses of Gulf killifish (Fundulus grandis) to oil-contaminated waters in controlled laboratory exposures. Transcriptional responses to the highest concentrations of oiled water in the laboratory were predictive of field-observed responses that coincided with the timing and location of major oiling. The transcriptional response to the low concentration (∼ 10-fold lower than the high concentration) was distinct from the high concentration and was not predictive of major oiling in the field. The high concentration response was characterized by activation of the molecular signaling pathway that facilitates oil metabolism and oil toxicity. The high concentration also induced DNA damage. The low concentration invoked expression of genes that may support a compensatory response, including genes associated with regulation of transcription, cell cycle progression, RNA processing, DNA damage, and apoptosis. We conclude that the gene expression response detected in the field was a robust indicator of exposure to the toxic components of contaminating oil, that animals in the field were exposed to relatively high concentrations that are especially damaging to early life stages, and that such exposures can damage DNA. PMID:25208076

  8. Pilot test of alkaline surfactant polymer flooding in Daqing Oil Field

    SciTech Connect

    Wang Demin; Zhang Zhenhua; Cheng Jiecheng; Yang Jingchun; Gao Shutang; Li Lin

    1996-12-31

    After the success of polymer flooding in Daqing, two alkaline-surfactant-polymer (ASP) floods have been conducted to (1) increase oil recovery further (2) study the feasibility of ASP flooding (3) provide technical and practical experience for expanding the ASP pilots. Inverted five spot pattern is adopted in both pilots. Pilot 1 (PO) is located in the West Central area of Daqing Oil Field and consists of 4 injectors and 9 producers. Pilot 2 (XF) is located in the South area of Daqing Oil Field and has 1 injector and 4 producers. The crude oil of both pilots have high paraffin content and low acid value. Compared to PO, XF has characteristics of lower heterogeneity, lighter oil and higher recovery by water flooding. For each pilot, after extensive screening, an ASP system has been determined. The ASP systems all feature very low surfactant concentration and wide range of ultra low interfacial tension with change of concentration of any of the three components. Core flooding and numerical simulation show more than 20% OOIP incremental recovery by ASP over water flooding for both pilots. By the end of May, 1995, 100% of ASP slug and 100% of the polymer buffer have been injected in the pilots. Production wells showed good responses in terms of large decrease in water cut and increase in oil production. The performance of each pilot has followed the numerical simulation predication very well, or even a bit better. Emulsions showed up in producers, but the emulsions are easy to be broken by a special de-emulsifier. No formation damage and scaling have been detected. The ASP flood pilot tests are technically successful and, based on the preliminary evaluation, economically feasible. Therefore, in the near future, much larger scale ASP flood field tests are going to be performed at several districts in Daqing Oil Field.

  9. Mosquito (Diptera: Culicidae) repellency field tests of essential oils from plants traditionally used in Laos.

    PubMed

    Vongsombath, Chanda; Pålsson, Katinka; Björk, Lars; Borg-Karlson, Anna-Karin; Jaenson, Thomas G T

    2012-11-01

    Essential oils of Hyptis suaveolens (Lamiaceae), Croton roxburghii (Euphorbiaceae), and Litsea cubeba (Lauraceae) were tested in the field near Vientiane city, Lao PDR, on humans for repellent activity against mosquitoes. Landing mosquitoes were collected and later identified. The most abundant mosquitoes captured belonged to the genera Armigeres, Culex, and Aedes. All the plant oils tested at concentrations of 1.7 microg/cm(2), 3.3 microg/cm(2), and 6.3 microg/cm(2) were significantly more mosquito repellent than the negative control. Croton oil was significantly repellent against mosquitoes of the three genera at the highest (6.3 microg/cm(2)) concentration tested. Litsea oil was significantly repellent against Armigeres at all (1.7 microg/cm(2), 3.3 microg/cm(2), and 6.3 microg/cm(2)) concentrations tested. Hyptis oil was significantly repellent against Armigeres at 3.3 microg/cm(2) and 6.3 microg/cm(2) and against Culex at 1.7 microg/cm(2) and 6.3 microg/cm(2). The oils were analyzed for chemical content of volatiles, mainly terpenes. Main constituents were beta-pinene, sabinene, and 1,8-cineol from oils of the green parts of H. suaveolens; alpha-pinene, beta-pinene, and alpha-phellandrene from fresh bark of C. roxburghii; and alpha-pinene, beta-phellandrene, sabinene, and 1,8-cineol from fresh fruits of L. cubeba. PMID:23270168

  10. Characterising oil and water in porous media using decay due to diffusion in the internal field.

    PubMed

    Lewis, Rhiannon T; Djurhuus, Ketil; Seland, John Georg

    2015-10-01

    In the method Decay due to Diffusion in the Internal Field (DDIF), the diffusion behaviour of water molecules in the internal magnetic field makes it possible to determine a distribution of pore sizes in a sample. The DDIF experiment can also be extended to a DDIF-Carr-Purcell-Meiboom-Gill (DDIF-CPMG) experiment to measure correlations between the pore size and the transverse relaxation time, T2. In this study we have for the first time applied the DDIF experiment and the DDIF-CPMG experiment to porous materials saturated with both water and oil. Because of the large difference in diffusion rates between water and oil molecules, the DDIF experiment will act as a filter for the signal from oil, and we are left with the DDIF-signal from water only. This has been verified in model systems consisting of glass beads immersed in separate layers of water and oil, and in a sandstone sample saturated with water and oil. The results show that the DDIF and DDIF-CPMG experiments enable the determination of the confining geometry of the water phase, and how this geometry is correlated to T2. Data obtained in the sandstone sample saturated with water and oil also show that with the exception of the smallest pores there is no clear correlation between pore size and the relaxation time of water. PMID:26254732

  11. Characterising oil and water in porous media using decay due to diffusion in the internal field

    NASA Astrophysics Data System (ADS)

    Lewis, Rhiannon T.; Djurhuus, Ketil; Seland, John Georg

    2015-10-01

    In the method Decay due to Diffusion in the Internal Field (DDIF), the diffusion behaviour of water molecules in the internal magnetic field makes it possible to determine a distribution of pore sizes in a sample. The DDIF experiment can also be extended to a DDIF-Carr-Purcell-Meiboom-Gill (DDIF-CPMG) experiment to measure correlations between the pore size and the transverse relaxation time, T2 . In this study we have for the first time applied the DDIF experiment and the DDIF-CPMG experiment to porous materials saturated with both water and oil. Because of the large difference in diffusion rates between water and oil molecules, the DDIF experiment will act as a filter for the signal from oil, and we are left with the DDIF-signal from water only. This has been verified in model systems consisting of glass beads immersed in separate layers of water and oil, and in a sandstone sample saturated with water and oil. The results show that the DDIF and DDIF-CPMG experiments enable the determination of the confining geometry of the water phase, and how this geometry is correlated to T2 . Data obtained in the sandstone sample saturated with water and oil also show that with the exception of the smallest pores there is no clear correlation between pore size and the relaxation time of water.

  12. Brief introduction of Huizhou 21-1 and Huizhou 26-1 oil field facilities

    SciTech Connect

    Wang Zhusheng

    1993-12-31

    This article introduces the facility options of the earliest developed fields Huizhou 21-1 and Huizhou 26-1 in east South China Sea. It includes design data (production parameters, sea states and environments, properties of crude oil and so on), process and main facilities. The basic data used for design is fairly precise and reasonable after several years running. The facilities stand the test of typhoon and monsoon, also fully utilize the oil and gas resources of fields and gain fairly economic benefits.

  13. Cano Limon Field, Colombia: The latest giant oil reservoir in South America

    SciTech Connect

    Rivero, R.T.; Dominguez, J.G.; Slater, J.A.; Hearn, C.L.

    1986-01-01

    The recent discovery of the giant Cano Limon field in the Northern Colombian Llanos basin is the most successful result of the association type contracts instituted by the Colombian government 15 years ago. A major construction and development drilling effort resulted in production start-up in December, 1985, 2 1/2 years after discovery. As of publication date, field oil production rate is approaching a projected rate of about 200,000 STB/D. With optimum reservoir management, oil recovery is expected to reach one billion barrels.

  14. Cano Limon Field, Colombia: The latest giant oil reservoir in South America

    SciTech Connect

    Rivero, R.T.; Dominguez, J.G.; Slater, J.A.; Hearn, C.L.

    1988-06-01

    The recent discovery of the giant Cano Limon field in the northern Colombian Los Llanos basin is the most successful result of the Association-type contracts instituted by the Colombian government 15 years ago. A major construction and development drilling effort resulted in production startup in Dec. 1985, 2 1/2 years after discovery. As of publication date, the field oil production rate is about 200,000 STB/D (31.8x10/sup 3/ stock-tank m/sup 3//d). With optimum reservoir management, oil recovery is expected to reach 10/sup 9/ bbl (1.59x10/sup 9/ m/sup 3/).

  15. Effect of electric field treatment on unsaturated fatty acid in crude avocado oil.

    PubMed

    Ariza-Ortega, José Alberto; Ramírez-Moreno, Esther; Díaz-Reyes, Joel; Cruz-Cansino, Nelly del Socorro

    2014-09-01

    The objective of this study was to evaluate the stability of the fatty acids in avocado oil when the product is subjected to different conditions of electric field treatment (voltage: 5 kV cm(-1); frequency: 720 Hz; treatment time: 5, 10, 15, 20, and 25 min). Fatty acids were analyzed by Fourier transform infrared spectroscopy in the mid-infrared region. Electric field is a suitable method to preserve the oil quality and composition with minimal modifications in unsaturated fatty acids. PMID:25069856

  16. NAFTA opportunities: Oil and gas field drilling machinery and services sector

    SciTech Connect

    Not Available

    1993-01-01

    The North American Free Trade Agreement (NAFTA) significantly improves market access in Mexico and Canada for U.S. exports of oil and gas field equipment. Foreign markets account for more than 80 percent of U.S. shipments of oil and gas field machinery. Foreign markets are expected to continue their importance to this industry, in the long term. Mexico and Canada are moderate-sized markets for U.S. exports of oilfield products. In 1992, U.S. exports of this equipment amounted to about $113 million to Mexico and $11 million to Canada.

  17. Analysis of the ecological risk of opening new oil and gas fields

    SciTech Connect

    Anikiev, V.V.; Mansurov, M.N.; Fleishman, B.S.

    1995-01-01

    Practical recommendations that would ensure the ecological safety of opening new marine oil and gas fields should include analysis of ecological risk. Such an analysis should precede the studies of ecological safety and resolve a sequence of problems in evaluating the ecological risk, the probability and scale of accidents at the oil and gas extraction complex, and economic damage that could occur. This paper presents a method of evaluation of risks for fish populations incurred by marine extraction of oil and gas, calculates the required limit of probability of accidents excluding the possibility of degradation of flatfish populations, estimates expenses incurred by accidental oil spills, and presents data on level of pollution. 9 refs., 1 tab.

  18. The Italian wall lizard (Podarcis sicula) as a bioindicator of oil field activity.

    PubMed

    Marsili, L; Casini, S; Mori, G; Ancora, S; Bianchi, N; D'Agostino, A; Ferraro, M; Fossi, M C

    2009-05-15

    The aim of this study was to develop and to validate a methodology based on biomarker responses and residue analysis on the terrestrial lizard Podarcis sicula to assess the ecotoxicological effects associated with on-shore oil extraction. The oil treatment plant investigated is located in Val d'Agri (southern Italy). Italian wall lizards were sampled on four stations along a transect determined on the basis of prevailing winds downwind of the oil plant. Cytochrome P450 1A1 activities (EROD and BPMO), AChE activity, PAH bile metabolites and contaminant levels (PAHs and trace elements) were measured. Major results in the evaluation of toxicological impact of oil field activity in the Italian wall lizards were obtained for Cd, Hg, total and carcinogenic PAH levels, and PAH metabolites in bile. Results obtained validate, for the first time, P. sicula as a terrestrial bioindicator for the assessment of the toxicological impact of on-shore extraction activity. PMID:19232674

  19. Hydrocarbon charging histories of the Ordovician reservoir in the Tahe oil field, Tarim Basin, China.

    PubMed

    Li, Chun-Quan; Chen, Hong-Han; Li, Si-Tian; Zhang, Xi-Ming; Chen, Han-Lin

    2004-08-01

    The Ordovician reservoir of the Tahe oil field went through many tectonic reconstructions, and was characterized by multiple hydrocarbon chargings. The aim of this study was to unravel the complex charging histories. Systematic analysis of fluid inclusions was employed to complete the investigation. Fluorescence observation of oil inclusions under UV light, and microthermometry of both oil and aqueous inclusions in 105 core samples taken from the Ordovician reservoir indicated that the Ordovician reservoir underwent four oil chargings and a gas charging. The hydrocarbon chargings occurred at the late Hercynian, the Indo-Sinian and Yanshan, the early Himalaya, the middle Himalaya, and the late Himalaya, respectively. The critical hydrocarbon charging time was at the late Hercynian. PMID:15236484

  20. Risk assessment of nonhazardous oil-field waste disposal in salt caverns.

    SciTech Connect

    Elcock, D.

    1998-03-10

    Salt caverns can be formed in underground salt formations incidentally as a result of mining or intentionally to create underground chambers for product storage or waste disposal. For more than 50 years, salt caverns have been used to store hydrocarbon products. Recently, concerns over the costs and environmental effects of land disposal and incineration have sparked interest in using salt caverns for waste disposal. Countries using or considering using salt caverns for waste disposal include Canada (oil-production wastes), Mexico (purged sulfates from salt evaporators), Germany (contaminated soils and ashes), the United Kingdom (organic residues), and the Netherlands (brine purification wastes). In the US, industry and the regulatory community are pursuing the use of salt caverns for disposal of oil-field wastes. In 1988, the US Environmental Protection Agency (EPA) issued a regulatory determination exempting wastes generated during oil and gas exploration and production (oil-field wastes) from federal hazardous waste regulations--even though such wastes may contain hazardous constituents. At the same time, EPA urged states to tighten their oil-field waste management regulations. The resulting restrictions have generated industry interest in the use of salt caverns for potentially economical and environmentally safe oil-field waste disposal. Before the practice can be implemented commercially, however, regulators need assurance that disposing of oil-field wastes in salt caverns is technically and legally feasible and that potential health effects associated with the practice are acceptable. In 1996, Argonne National Laboratory (ANL) conducted a preliminary technical and legal evaluation of disposing of nonhazardous oil-field wastes (NOW) into salt caverns. It investigated regulatory issues; the types of oil-field wastes suitable for cavern disposal; cavern design and location considerations; and disposal operations, closure and remediation issues. It determined that if caverns are sited and designed well, operated carefully, closed properly, and monitored routinely, they could, from technical and legal perspectives, be suitable for disposing of oil-field wastes. On the basis of these findings, ANL subsequently conducted a preliminary risk assessment on the possibility that adverse human health effects (carcinogenic and noncarcinogenic) could result from exposure to contaminants released from the NOW disposed of in salt caverns. The methodology for the risk assessment included the following steps: identifying potential contaminants of concern; determining how humans could be exposed to these contaminants; assessing contaminant toxicities; estimating contaminant intakes; and estimating human cancer and noncancer risks. To estimate exposure routes and pathways, four postclosure cavern release scenarios were assessed. These were inadvertent cavern intrusion, failure of the cavern seal, failure of the cavern through cracks, failure of the cavern through leaky interbeds, and partial collapse of the cavern roof. Assuming a single, generic, salt cavern and generic oil-field wastes, potential human health effects associated with constituent hazardous substances (arsenic, benzene, cadmium, and chromium) were assessed under each of these scenarios. Preliminary results provided excess cancer risk and hazard index (for noncancer health effects) estimates that were well within the EPA target range for acceptable exposure risk levels. These results lead to the preliminary conclusion that from a human health perspective, salt caverns can provide an acceptable disposal method for nonhazardous oil-field wastes.

  1. Field experiments of multi-channel oceanographic fluorescence lidar for oil spill and chlorophyll- a detection

    NASA Astrophysics Data System (ADS)

    Li, Xiaolong; Zhao, Chaofang; Ma, Youjun; Liu, Zhishen

    2014-08-01

    A Multi-channel Oceanographic Fluorescence Lidar (MOFL), with a UV excitation at 355 nm and multiple receiving channels at typical wavelengths of fluorescence from oil spills and chlorophyll- a (Chl- a), has been developed using the Laser-induced Fluorescence (LIF) technique. The sketch of the MOFL system equipped with a compact multi-channel photomultiplier tube (MPMT) is introduced in the paper. The methods of differentiating the oil fluorescence from the background water fluorescence and evaluating the Chl- a concentration are described. Two field experiments were carried out to investigate the field performance of the system, i.e., an experiment in coastal areas for oil pollution detection and an experiment over the Yellow Sea for Chl- a monitoring. In the coastal experiment, several oil samples and other fluorescence substances were used to analyze the fluorescence spectral characteristics for oil identification, and to estimate the thickness of oil films at the water surface. The experiment shows that both the spectral shape of fluorescence induced from surface water and the intensity ratio of two channels ( I 495/ I 405) are essential to determine oil-spill occurrence. In the airborne experiment, MOFL was applied to measure relative Chl- a concentrations in the upper layer of the ocean. A comparison of relative Chl- a concentration measurements by MOFL and the Moderate Resolution Imaging Spectroradiometer (MODIS) indicates that the two datasets are in good agreement. The results show that the MOFL system is capable of monitoring oil spills and Chl- a in the upper layer of ocean water.

  2. Programed oil generation of the Zubair Formation, Southern Iraq oil fields: Results from Petromod software modeling and geochemical analysis

    USGS Publications Warehouse

    Al-Ameri, T. K.; Pitman, J.; Naser, M.E.; Zumberge, J.; Al-Haydari, H. A.

    2011-01-01

    1D petroleum system modeling was performed on wells in each of four oil fields in South Iraq, Zubair (well Zb-47), Nahr Umr (well NR-9), West Qurna (well WQ-15 and 23), and Majnoon (well Mj-8). In each of these fields, deposition of the Zubair Formation was followed by continuous burial, reaching maximum temperatures of 100??C (equivalent to 0. 70%Ro) at depths of 3,344-3,750 m of well Zb-47 and 3,081. 5-3,420 m of well WQ-15, 120??C (equivalent to 0. 78%Ro) at depths of 3,353-3,645 m of well NR-9, and 3,391-3,691. 5 m of well Mj-8. Generation of petroleum in the Zubair Formation began in the late Tertiary, 10 million years ago. At present day, modeled transformation ratios (TR) indicate that 65% TR of its generation potential has been reached in well Zb-47, 75% TR in well NR-9 and 55-85% TR in West Qurna oil field (wells WQ-15 and WQ-23) and up to 95% TR in well Mj-8, In contrast, younger source rocks are immature to early mature (<20% TR), whereas older source rocks are mature to overmature (100% TR). Comparison of these basin modeling results, in Basrah region, are performed with Kifle oil field in Hilla region of western Euphrates River whereas the Zubair Formation is immature within temperature range of 65-70??C (0. 50%Ro equivalent) with up to 12% (TR = 12%) hydrocarbon generation efficiency and hence poor generation could be assessed in this last location. The Zubair Formation was deposited in a deltaic environment and consists of interbedded shales and porous and permeable sandstones. In Basrah region, the shales have total organic carbon of 0. 5-7. 0 wt%, Tmax 430-470??C and hydrogen indices of up to 466 with S2 = 0. 4-9. 4 of kerogen type II & III and petroleum potential of 0. 4-9. 98 of good hydrocarbon generation, which is consistent with 55-95% hydrocarbon efficiency. These generated hydrocarbons had charged (in part) the Cretaceous and Tertiary reservoirs, especially the Zubair Formation itself, in the traps formed by Alpine collision that closed the Tethys Ocean between Arabian and Euracian Plates and developed folds in Mesopotamian Basin 15-10 million years ago. These traps are mainly stratigraphic facies of sandstones with the shale that formed during the deposition of the Zubair Formation in transgression and regression phases within the main structural folds of the Zubair, Nahr Umr, West Qurna and Majnoon Oil fields. Oil biomarkers of the Zubair Formation Reservoirs are showing source affinity with mixed oil from the Upper Jurassic and Lower Cretaceous strata, including Zubair Formation organic matters, based on presentation of GC and GC-MS results on diagrams of global petroleum systems. ?? 2010 Saudi Society for Geosciences.

  3. Miscibility study of carbon dioxide injection to enhance oil recovery from Abu-Dhabi oil field Thani reservoire

    NASA Astrophysics Data System (ADS)

    Aljarwan, Abdulla Humaid Saif Saeed

    The subject field in this study has been recognized among the largest offshore oil fields in the world, located in the Arabian Gulf 63 kilometers to the Northwest of Abu Dhabi, producing large quantities of crude oil and associated gas from three different carbonate reservoirs, Thani-I, II and IIII since 1963. In the early 1970's peripheral water injection scheme was adopted to maintain the reservoir pressure and sustain production. Simultaneously, partial waterflooding was applied to one sector of the field, but stopped soon after implementation shadowed by poor sweep efficiency and dramatic escalation of water-cut. Furthermore, hydrocarbon miscible gas injection was implemented in the year 2000 but stopped seven years later, due to high gas oil ratio and aspheltene deposition. In light of such recovery complications, management is considering serious recovery measures to extend plateau production and meet long-term production from this field. Post initial screening phase, it became evident that CO 2 miscible injection is the most suitable way forward. Characteristics of the Thani-III reservoir are within the favorable range for both immiscible and miscible CO2 injection criteria set by Taber, Martine and Serigh. Thani-III reservoir is considered more homogenous, less fractured and with higher production potential than Thani-I and II, hence promoted to be the target of CO2 miscible gas injection. This thesis aims to study the miscibility features of CO2 miscible injecton to enhanced oil recovery from Thani-III reservoir. Comprehensive simulation model is used to determine multi contact miscibility and suitable equation of state with CO2 as a separate pseudo component using one of the industry standard simulation software. Experimental PVT data for bottom hole and separator samples including compositional analysis, differential liberation test, separator tests, constant composition expansion, viscosity measurements and swelling tests for pure CO2 were used to generate and validate the model. In addition to that, simulation studies were conducted to produce coreflooding and slimtube experimental models, which are compared with the conclusions drawn from experimental results. Results of this study have shown comparable results with the lab experimental data in regards to minimum miscibility pressure (MMP) calculation and recovery factor estimation, where the marginal errors between both data sets were no more than 7% at its worst. For example, slimtube experimental results suggested 4230 psig as minimum miscibility pressure, where the simulation study EoS figure is 4130 psig and the slimtube simulation model results is 4180 psig. Similarly, coreflooding experimental data recovery factor at 1.2 PV injected solvent was 75% and a value of 72% recovery factor was obtained from the software single core model at same conditions of pressure and saturations. Results from this study are expected to assist the operator of this field to plan and implement a very attractive enhanced oil recovery program, giving that other factors are well accounted for such as asphaltene deposition, reservoir pressure maintenance, oil saturation, CO2 sequestering and choosing the most appropriate time to maximize the net positive value (NPV) and expected project gain.

  4. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2004-03-05

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing an 2400 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  5. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2003-09-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing an 2400 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  6. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2003-06-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing an 2400 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  7. Neutron scattering studies of crude oil viscosity reduction with electric field

    NASA Astrophysics Data System (ADS)

    Du, Enpeng

    Small-angle neutron scattering (SANS) is a very powerful laboratory technique for micro structure research which is similar to the small angle X-ray scattering (SAXS) and light scattering for microstructure investigations in various materials. In small-angle neutron scattering (SANS) technique, the neutrons are elastically scattered by changes of refractive index on a nanometer scale inside the sample through the interaction with the nuclei of the atoms present in the sample. Because the nuclei of all atoms are compact and of comparable size, neutrons are capable of interacting strongly with all atoms. This is in contrast to X-ray techniques where the X-rays interact weakly with hydrogen, the most abundant element in most samples. The SANS refractive index is directly related to the scattering length density and is a measure of the strength of the interaction of a neutron wave with a given nucleus. It can probe inhomogeneities in the nanometer scale from 1nm to 1000nm. Since the SANS technique probes the length scale in a very useful range, this technique provides valuable information over a wide variety of scientific and technological applications, including chemical aggregation, defects in materials, surfactants, colloids, ferromagnetic correlations in magnetism, alloy segregation, polymers, proteins, biological membranes, viruses, ribosome and macromolecules. Quoting the Nobel committee, when awarding the prize to C. Shull and B. Brockhouse in 1994: "Neutrons tell you where the atoms are and what the atoms do". At NIST, there is a single beam of neutrons generated from either reactor or pulsed neutron source and selected by velocity selector. The beam passes through a neutron guide then scattered by the sample. After the sample chamber, there are 2D gas detectors to collect the elastic scattering information. SANS usually uses collimation of the neutron beam to determine the scattering angle of a neutron, which results in an even lower signal-to-noise ratio for data that contains information on the properties of a sample. We can analyze the data acquisition from the detectors and get the information on size, shape, etc. This is why we choose SANS as our research tool. The world's top energy problems are security concerns, climate concerns and environmental concerns. So far, oil (37%) is still the No.1 fuel in world energy consumption (Oil 37%, Coal 25%, Bio-fuels 0.2%, Gas 23%, Nuclear 6%, Biomass 4%, Hydro 3%, Solar heat 0.5%, Wind 0.3%, Geothermal 0.2% and Solar photovoltaic 0.04%). Even more and more alternative energy: bio-fuels, nuclear and solar energy will be used in the future, but nuclear energy has a major safety issue after the Japanese Fukushima I nuclear accidents, and other energies contribute only a small percent. Thus, it is very important to improve the efficiency and reduce the population of petroleum products. There is probably one thing that we can all agree on: the world's energy reserves are not unlimited. Even though it is limited, only 30% of the oil reserves is conventional oil, so in order to produce, transport, and refine of heavy crude oil without wasting huge amounts of energy, we need to reduce the viscosity without using high temperature stream heating or diluent; As more and more off-shore oil is exploited at that we need reduce the viscosity without increasing temperature. The whole petroleum consumed in U.S. in 2009 was 18.7 million barrels per day and 35% of all the energy we consumed. Diesel is one of the very important fossil fuel which is about 20% of petroleum consumed. Most of the world's oils are non-conventional, 15 % of heavy oil, 25 % of extra heavy oil, 30 % of the oil sands and bitumen, and the conventional oil reserves is only 30%. The oil sand is closely related to the heavy crude oil, the main difference being that oil sands generally do not flow at all. For efficient energy production and conservation, how to lower the liquated fuel and crude oil viscosity is a very important topic. Dr. Tao with his group at Temple University, using his electro or magnetic rheological viscosity theory has developed a new technology, which utilizes electric or magnetic fields to change the rheology of complex fluids to reduce the viscosity, while keeping the temperature unchanged. After we successfully reduced the viscosity of crude oil with field and investigated the microstructure changing in various crude oil samples with SANS, we have continued to reduce the viscosity of heavy crude oil, bunker diesel, ultra low sulfur diesel, bio-diesel and crude oil and ultra low temperature with electric field treatment. Our research group developed the viscosity electrorheology theory and investigated flow rate with laboratory and field pipeline. But we never visualize this aggregation. The small angle neutron scattering experiment has confirmed the theoretical prediction that a strong electric field induces the suspended nano-particles inside crude oil to aggregate into short chains along the field direction. This aggregation breaks the symmetry, making the viscosity anisotropic: along the field direction, the viscosity is significantly reduced. The experiment enables us to determine the induced chain size and shape, verifies that the electric field works for all kinds of crude oils, paraffin-based, asphalt-based, and mix-based. The basic physics of such field induced viscosity reduction is applicable to all kinds of suspensions.

  8. Development of Improved Oil Field Waste Injection Disposal Techniques

    SciTech Connect

    Terralog Technologies

    2002-11-25

    The goals of this project have was to: (1) assemble and analyze a comprehensive database of past waste injection operations; (2) develop improved diagnostic techniques for monitoring fracture growth and formation changes; (3) develop operating guidelines to optimize daily operations and ultimate storage capacity of the target formation; and (4) to apply these improved models and guidelines in the field.

  9. Preliminary Technical and Legal Evaluation of Disposing of Nonhazardous Oil Field Waste into Salt Caverns

    SciTech Connect

    Ayers, Robert C.; Caudle, Dan; Elcock, Deborah; Raivel, Mary; Veil, John; and Grunewald, Ben

    1999-01-21

    This report presents an initial evaluation of the suitability, feasibility, and legality of using salt caverns for disposal of nonhazardous oil field wastes. Given the preliminary and general nature of this report, we recognize that some of our findings and conclusions maybe speculative and subject to change upon further research on this topic.

  10. FIELD MANUAL FOR PLUNGING WATER JET USE IN OIL SPILL CLEANUP

    EPA Science Inventory

    The use of plunging water jets can often make possible the control (and, as a consequence, the cleanup) of spilled oil and other floating pollutants in currents too swift for conventional equipment. This short, illustrated manual provides practical information for field and plann...

  11. The 1-AB block fields-a giant oil accumulation in Eastern Peru

    SciTech Connect

    Jarvis, H.A.; Lay, V. ); Orosco, C. )

    1993-02-01

    The 1-Ab block fields are located in the northeastern part of Peru. Geologically, the area is the sub-Andean Maranon Basin, a continuation of the Napo Basin from eastern Ecuador. During the 20 years that Occidental has operated Block 1-AB, approximately 11,500 km of seismic data has been recorded and 34 exploratory wells have been drilled, resulting in the discovery of 18 fields, or 53% exploration success. The 1-AB oil accumulation discovered in 1972 is a group of medium to small asymmetric anticlines distributed along six northwest-southeast trending structural alignments: North Capahuari-South Capahuari-Tambo, Carmen-North San Jaacinto and Bartra. This concentration of productive structures in a relative small area is unique within the Maranon basin. The controlling factors include exceptional pre-Cretaceous uplifting and the presence of very good to excellent Cretaceous sandstones reservoirs. The two major Cretaceous producing zones, the Chonta and Vivian sandstones, have been defined within the Coniacian and Campanian ages respectively. The Chonta sands are related to shelfal deposition across Block 1-AB, represented by strand plain and barrier island sediments. The Vivian formation is a massive fluvial sandstone covering all of the Maranon basin and ranging in thickness between 40 and 200 feet. After oil was accumulated, fresh water influxes into the reservoirs of the northern and eastern fields caused oil biodegradation and salinity variation of the reservoir waters, depending upon the intensity of biodegradation. Oil remigration also has been documented for the South Huayari field.

  12. Quality of field pennycress oil obtained by screw pressing and solvent extraction

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Field pennycress (Thlasphi arvense L., Brassicaceae) is a winter annual that grows widely in temperate North America. Its seeds contain up to 36% oil (dry basis, db) with the major fatty acid being erucic acid (38 %). With an estimated seed production of 1,700 – 2,200 kg/ha, pennycress can be a majo...

  13. Special ESP configurations designed to test and produce Yemen oil field. [Electric-Submersible Pump

    SciTech Connect

    Wilkie, D.I. )

    1993-09-27

    Innovative electric-submersible-pump (ESP) configurations were used in the exploration phase of a Yemen oil field discovered by Canadian Occidental Petroleum Ltd. Because of subnormal reservoir pressure, CanOxy developed the field with ESPs and had to install surface components that could operate at the high, 130 F., ambient temperatures common in Yemen. The field is in a remote area that has seen very little development. The reservoirs produce a medium-to-heavy crude with a low gas/oil ratio, typically less than 20 scf/bbl. Problems faced in evaluating the field included drilling through unconsolidated sands with high flow capacity and subnormal reservoir pressure. CanOxy had to develop the technology to test the wells during the exploration phase, and intends to use new, or at least uncommon technology, for producing the wells. The paper describes testing the wells, the electric generators and variable speed drives, and the use of these pumps on production wells.

  14. A look at Bacon Flat, Grant Canyon oil fields of Railroad Valley, Nevada

    SciTech Connect

    Johnson, E.H. )

    1993-05-17

    The prolific wells at Grant Canyon, and the puzzling geology, have intrigued explorationists and promoters. Many a Nevada prospect has been touted as 'another Grand Canyon.' But what processes formed Grant Canyon, and can others be found Last August, Equitable Resources Energy Co,'s Balcron Oil Division spudded a well at Bacon Flat, a mile west of Grant Canyon. A one well field, Bacon Flat had been abandoned in 1988. But just 900 ft north of the field opener, Balcron's well tested oil at a rate or 5,400 b/d. It turns out that Bacon Flat and Grant Canyon fields have a common geological history and, in fact, share the same faulted horst. However, they formed by an unusual combination of events that may be unique to those fields. This paper describes the geologic history, well logging interpretations, structures, the Jebco C seismic line, a geologic cross section, and the author's conclusions.

  15. Costs and indices for domestic oil and gas field equipment and production operations 1994 through 1997

    SciTech Connect

    1998-03-01

    This report presents estimated costs and cost indices for domestic oil and natural gas field equipment and production operations for 1994, 1995, 1996, and 1997. The costs of all equipment and services are those in effect during June of each year. The sums (aggregates) of the costs for representative leases by region, depth, and production rate were averaged and indexed. This provides a general measure of the increased or decreased costs from year to year for lease equipment and operations. These general measures do not capture changes in industry-wide costs exactly because of annual variations in the ratio of the total number of oil wells to the total number of gas wells. The detail provided in this report is unavailable elsewhere. The body of this report contains summary tables, and the appendices contain detailed tables. Price changes for oil and gas, changes in taxes on oil and gas revenues, and environmental factors (compliance costs and lease availability) have a significant impact on the number and cost of oil and gas wells drilled. These changes also impact the cost of oil and gas equipment and production operations.

  16. Geology of the undeveloped oil and gas fields of Central Offshore Santa Maria Basin, California

    SciTech Connect

    Milton, J.D. ); Edwards, E.B. ); Heck, R.G. )

    1996-01-01

    Two prominent subsurface structural features of the Central Offshore Santa Maria Basin are the Hosgri fault system and the associated anticlinal fold trend. Exploratory drilling and 3D seismic mapping have delineated a series of oil and gas fields along this trend which underlie four federal units and one non-unitized lease. The units are named after local geography and are called the Lion Rock, Point Sal, Purisima Point and Santa Maria Units. The individual lease, OCS P-0409, overlies the San Miguel field. The Hosgri fault system trends northwest-southeast and effectively forms the eastern boundary of the oil and gas province. Lying semi-parallel with the fault are several anticlinal culminations which have trapped large volumes of oil and gas in the fractured Montery Formation. The Monterey is both source and reservoir rock, averaging 300 meters n thickness throughout the Central Basin. Development of the Monterey Formation as a reservoir rock was through diagensis and tectonism with resulting porosities-from 15 to 20% and permeability up to one Darcy. These parameters coupled with a high geothermal gradient facilitate the inflow rates of the viscous Monterey oil. Some 24 exploration and delineation wells have been drilled in this area and tested at rates ranging from a few hundred to several thousand barrels per day. Estimated oil reserves in the Central Offshore Santa Maria Basin total approximately 1 billion barrels.

  17. Geology of the undeveloped oil and gas fields of Central Offshore Santa Maria Basin, California

    SciTech Connect

    Milton, J.D.; Edwards, E.B.; Heck, R.G.

    1996-12-31

    Two prominent subsurface structural features of the Central Offshore Santa Maria Basin are the Hosgri fault system and the associated anticlinal fold trend. Exploratory drilling and 3D seismic mapping have delineated a series of oil and gas fields along this trend which underlie four federal units and one non-unitized lease. The units are named after local geography and are called the Lion Rock, Point Sal, Purisima Point and Santa Maria Units. The individual lease, OCS P-0409, overlies the San Miguel field. The Hosgri fault system trends northwest-southeast and effectively forms the eastern boundary of the oil and gas province. Lying semi-parallel with the fault are several anticlinal culminations which have trapped large volumes of oil and gas in the fractured Montery Formation. The Monterey is both source and reservoir rock, averaging 300 meters n thickness throughout the Central Basin. Development of the Monterey Formation as a reservoir rock was through diagensis and tectonism with resulting porosities-from 15 to 20% and permeability up to one Darcy. These parameters coupled with a high geothermal gradient facilitate the inflow rates of the viscous Monterey oil. Some 24 exploration and delineation wells have been drilled in this area and tested at rates ranging from a few hundred to several thousand barrels per day. Estimated oil reserves in the Central Offshore Santa Maria Basin total approximately 1 billion barrels.

  18. Real-time oil-saturation monitoring in rock cores with low-field NMR

    NASA Astrophysics Data System (ADS)

    Mitchell, J.; Howe, A. M.; Clarke, A.

    2015-07-01

    Nuclear magnetic resonance (NMR) provides a powerful suite of tools for studying oil in reservoir core plugs at the laboratory scale. Low-field magnets are preferred for well-log calibration and to minimize magnetic-susceptibility-induced internal gradients in the porous medium. We demonstrate that careful data processing, combined with prior knowledge of the sample properties, enables real-time acquisition and interpretation of saturation state (relative amount of oil and water in the pores of a rock). Robust discrimination of oil and brine is achieved with diffusion weighting. We use this real-time analysis to monitor the forced displacement of oil from porous materials (sintered glass beads and sandstones) and to generate capillary desaturation curves. The real-time output enables in situ modification of the flood protocol and accurate control of the saturation state prior to the acquisition of standard NMR core analysis data, such as diffusion-relaxation correlations. Although applications to oil recovery and core analysis are demonstrated, the implementation highlights the general practicality of low-field NMR as an inline sensor for real-time industrial process control.

  19. Low-Salinity Waterflooding to Improve Oil Recovery - Historical Field Evidence

    SciTech Connect

    Eric P. Robertson

    2007-11-01

    Waterflooding is by far the most widely applied method of improved oil recovery. Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of wa-terfloods. Laboratory water-flood tests and single-well tracer tests have shown that injection of dilute brine can increase oil recovery, but work designed to test the method on a field scale has not yet been undertaken. Historical waterflood records could unintentionally provide some evidence of improved recovery from waterflooding with lower salinity brine. Nu-merous fields in the Powder River basin of Wyoming have been waterflooded using low salinity brine (about 500 ppm) obtained from the Madison limestone or Fox Hills sandstone. Three Minnelusa formation fields in the basin were identified as potential candidates for waterflood comparisons based on the salinity of the connate and injection water. Historical pro-duction and injection data for these fields were obtained from the public record. Field waterflood data were manipulated to be displayed in the same format as laboratory coreflood re-sults. Recovery from fields using lower salinity injection wa-ter was greater than that using higher salinity injection wa-ter—matching recovery trends for laboratory and single-well tests.

  20. Brine contamination of shallow ground water and streams in the Brookhaven Oil Field, Lincoln County, Mississippi

    USGS Publications Warehouse

    Kalkhoff, S.J.

    1986-01-01

    A hydrologic investigation to define areas of brine contamination in shallow freshwater aquifers commonly used for streams that drain the Brookhaven Oil Field, was conducted from October 1983 to September 1984. The Brookhaven Oil Field covers approximately 15 sq mi in northwestern Lincoln County, Mississippi. Since 1943, disposal of approximately 544.2 million barrels of brine pumped from the oil producing zone (lower part of the Tuscaloosa Formation) has contaminated the Citronelle aquifer, the Hattiesburg aquifers, and streams that drain the oil field. Approximately 5 sq mi of the shallow Citronelle aquifer contain water with chloride concentrations higher than normal for this area ( > 20 mg/L). Brine contamination has moved from the source laterally through the Citronelle aquifer to discharge into nearby streams and vertically into the underlying Hattiesburg aquifers. Contamination is most noticeable in Shaws Creek when streamflow originates primarily from groundwater inflow (approximately 87% of the time during the study). Additional study is required to define contaminant plumes, rates of groundwater movement and geohydrochemical reactions between the contaminant and aquifer materials. These data would allow accurate predictions of location, extent and degree of contamination in the study area. (Author 's abstract)

  1. Bluebell Field, Uinta Basin: reservoir characterization for improved well completion and oil recovery

    USGS Publications Warehouse

    Montgomery, S.L.; Morgan, C.D.

    1998-01-01

    Bluefield Field is the largest oil-producing area in the Unita basin of northern Utah. The field inclucdes over 300 wells and has produced 137 Mbbl oil and 177 bcf gas from fractured Paleocene-Eocene lacustrine and fluvial deposits of the Green River and Wasatch (Colton) formations. Oil and gas are produced at depths of 10 500-13 000 ft (3330-3940 m), with the most prolific reservoirs existing in over-pressured sandstones of the Colton Formation and the underlying Flagstaff Member of the lower Green River Formation. Despite a number of high-recovery wells (1-3 MMbbl), overall field recovery remains low, less than 10% original oil in place. This low recovery rate is interpreted to be at least partly a result of completion practices. Typically, 40-120 beds are perforated and stimulated with acid (no proppant) over intervals of up to 3000 ft (900 m). Little or no evaluation of individual beds is performed, preventing identification of good-quality reservoir zones, water-producing zones, and thief zones. As a result, detailed understanding of Bluebell reservoirs historically has been poor, inhibiting any improvements in recovery strategies. A recent project undertaken in Bluebell field as part of the U.S. Department of Energy's Class 1 (fluvial-deltaic reservoir) Oil Demonstration program has focused considerable effort on reservoir characterization. This effort has involved interdisciplinary analysis of core, log, fracture, geostatistical, production, and other data. Much valuable new information on reservoir character has resulted, with important implications for completion techniques and recovery expectations. Such data should have excellent applicability to other producing areas in the Uinta Basin withi reservoirs in similar lacustrine and related deposits.Bluebell field is the largest oil-producing area in the Uinta basin of northern Utah. The field includes over 300 wells and has produced 137 MMbbl oil and 177 bcf gas from fractured Paleocene-Eocene lacustrine and fluvial deposits of the Green River and Wasatch (Colton) formations. Oil and gas are produced at depths of 10,500-13,000 ft (3330-3940 m), with the most prolific reservoirs existing in over-pressured sandstones of the Colton Formation and the underlying Flagstaff Member of the lower Green River Formation. Despite a number of high-recovery wells (1-3 MMbbl), overall field recovery remains low, less than 10% original oil in place. This low recovery rate is interpreted to be at least partly a result of completion practices. Typically, 40-120 beds are perforated and stimulated with acid (no proppant) over intervals of up to 3000 ft (900 m). Little or no evaluation of individual beds is performed, preventing identification of good-quality reservoir zones, water-producing zones, and thief zones. As a result, detailed understanding of Bluebell reservoirs historically has been poor, inhibiting any improvements in recovery strategies. A recent project undertaken in Bluebell field as part of the U.S. Department of Energy's Class 1 (fluvial-deltaic reservoir) Oil Demonstration program has focused considerable effort on reservoir characterization. This effort has involved interdisciplinary analysis of core, log, fracture, geostatistical, production, and other data. Much valuable new information on reservoir character has resulted, with important implications for completion techniques and recovery expectations. Such data should have excellent applicability to other producing areas in the Uinta basin with reservoirs in similar lacustrine and related deposits.

  2. Tests verify advantages of horizontal wells in offshore China oil field

    SciTech Connect

    Gu, K.; Ye, Y. )

    1992-10-19

    This paper reports that for the Liuhua 11-1 oil field development, extended drill stem tests showed that horizontal wells were more suitable than either vertical or high-angle deviated wells. Advantages of horizontal wells included three to four times increased productivity over the vertical well, slower water coning from the aquifer, and greater ultimate recovery from a single well. The Liuhua 11-1 oil field is in the western part of the South China sea contract area 29.04, about 121 miles southeast of Hong Kong. To determine the field's development scheme, successively over about 1 year, extended drill stem tests were conducted on a conventional vertical, a high-angle-deviated, and a horizontal well.

  3. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2001-05-07

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through September 2000, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood projects. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone so the project team could use the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. The project team spent the fourth quarter 2000 performing well work and reservoir surveillance on the Tar II-A post-steamflood project and the Tar V horizontal well steamflood pilot. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being evaluated.

  4. Increasing heavy oil reserves in the Wilmington Oil Field through advanced reservoir characterization and thermal production technologies. Annual report, March 30, 1995--March 31, 1996

    SciTech Connect

    1997-09-01

    The objective of this project is to increase heavy oil reserves in a portion of the Wilmington Oil Field, near Long Beach, California, by implementing advanced reservoir characterization and thermal production technologies. Based on the knowledge and experience gained with this project, these technologies are intended to be extended to other sections of the Wilmington Oil Field, and, through technology transfer, will be available to increase heavy oil reserves in other slope and basin clastic (SBC) reservoirs. The project involves implementing thermal recovery in the southern half of the Fault Block II-A Tar zone. The existing steamflood in Fault Block II-A has been relatively inefficient due to several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery efficiency and reduce operating costs.

  5. Evaluation of Slime-Producing Bacteria in Oil Field Core Flood Experiments

    PubMed Central

    Geesey, G. G.; Mittelman, M. W.; Lieu, V. T.

    1987-01-01

    Epifluorescence microscopy and carbohydrate determinations indicated that the decrease in permeability of oil reservoir sand to reclaimed sewage water was partially the result of biological plugging. Filtration and biocide addition studies demonstrated that the increase in bacterial densities and slime concentrations in flooded oil field cores appeared to be due to both deposition from the reclaimed water and in situ microbial growth and slime production. Although these biological components increased throughout the cores during flooding, the region where the water entered the core exhibited the highest cell densities and slime concentrations. The approach described in this report should be useful in predicting the potential of a water source to induce biological plugging of oil reservoir sand. PMID:16347276

  6. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect

    Scott Hara

    1997-08-08

    The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. using advanced reservoir characterization and thermal production technologies. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing a 2100 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation. Summary of Technical Progress

  7. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect

    Scott Hara

    1998-03-03

    The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. using advanced reservoir characterization and thermal production technologies. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing a 2100 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  8. Subsurface stratigraphy and oil fields in the Salem Limestone and associated rocks in Indiana

    SciTech Connect

    Keller, S.J.; Becker, L.E.

    1980-01-01

    An area of 11 counties in southwestern Indiana was studied because (1) the subsurface geology of the Salem Limestone and associated rocks in the area contained numerous correlation discrepancies; (2) it was the locus of recent oil exploration and oil discoveries in these rocks; (3) the last subsurface study of this rock section was made in 1957; and (4) since that time, subsurface data from newly drilled petroleum-test wells have increased a hundredfold. Because of their abundance, geophysical logs were used extensively for correlation. Drill cuttings, where available, were also used in studying the rock units. The upper boundary of the Salem was based on geophysical-log correlations as supported by available drill cuttings. The lower boundary of the Salem was based on drill cuttings. Commercial oil is produced from porous calcarenite zones in the St. Louis and Salem Limestones and from coarsely crystalline limestone in the Harrodsburg Limestone. The lower part of the St. Louis Limestone yields oil from a porous carbonate rock that resembles Salem calcarenite and that we have formally named the Sission Member in the St. Louis. The Salem calcarenite facies ranges in thickness from a low of 10 percent of the total Salem in the southern part of the study area to a high of 80 percent in the northern part. Oil is produced from porous zones in the calcarenite. Oil production from the St. Louis, Salem, and Harrodsburg Limestones in Indiana amounted to 8,880,078 barrels as of December 31, 1978. Production in 1977 was 1,534,320 barrels, and production in 1978 was 1,157,450 barrels. About 80 percent of the 1977 and 1978 production came from Union-Bowman Consolidated and Sisson Fields in Gibson, Knox, and Pike counties and the Owensville North Consolidated and Mt. Carmel Consolidated Fields in Gibson County. 15 figures, 3 tables.

  9. Exploitation of oil in a volcanic cone by horizontal drilling in the Elaine field, south Texas

    SciTech Connect

    Martinez, P.A.; Kushner, P.L.; Harbaugh, J.W.

    1991-03-01

    The Uvalde volcanic field west and southwest of San Antonio contains many buried volcanic cones that offer attractive places to exploit with horizontal drilling. These buried cones were formed by eruption of basaltic flows and cinders during the Cretaceous when the Austin Chalk and immediately overlying strate were deposited. The cones vary in size, some being as much as 2 mi in diameter and 1000 ft in vertical dimension. During eruptions, flows and ejecta reacted with sea water, producing intermixtures of basaltic material and limestone. These cones provide attractive targets for oil exploration. The Elaine field about 90 mi southwest of San Antonio is associated with a buried volcanic cone that is now being exploited with horizontal drilling. Horizontal Drilling and Production, Inc., ('HDP') drilled the Autumn 1 as the initial horizontal well at Elaine. A vertical hole was drilled through the cone and underlying Austin Chalk, reconfirming the presence of the oil zone at the contact between volcanics and chalk. Moving back up the hole, a cement plug was set within the volcanics, and a horizontal hole was directed on a N 70W azimuth. The inclined hole's vertical angle had progressively decreased with distance to about 30{degree} from the horizontal when the oil zone was reentered. The hole's inclination continued to decrease within the oil zone, becoming horizontal after about 600 ft. With further distance, the hole passed beneath the oil zone, where its inclination was then reversed so that it climbed gradually and reentered the oil zone before reaching its terminal distance of 1500 horizontal feet. The well was completed on August 17, 1990, with an indicated initial production of 1609 BOPD.

  10. Sulfate-reducing bacteria release barium and radium from naturally occurring radioactive material in oil-field barite

    USGS Publications Warehouse

    Phillips, E.J.P.; Landa, E.R.; Kraemer, T.; Zielinski, R.

    2001-01-01

    Scale and sludge deposits formed during oil production can contain elevated levels of Ra, often coprecipitated with barium sulfate (barite). The potential for sulfate-reducing bacteria to release 226 Ra and Ba (a Ra analog) from oil-field barite was evaluated. The concentration of dissolved Ba increased when samples containing pipe scale, tank sludge, or oil-field brine pond sediment were incubated with sulfate-reducing bacteria Desulfovibrio sp., Str LZKI, isolated from an oil-field brine pond. However, Ba release was not stoichiometric with sulfide production in oil-field samples, and <0.1% of the Ba was released. Potential for the release of 226Ra was demonstrated, and the 226 Ra release associated with sulfate-reducing activity was predictable from the amount of Ba released. As with Ba, only a fraction of the 226Ra expected from the amount of sulfide produced was released, and most of the Ra remained associated with the solid material.

  11. Determination of hexaconazole in field samples of an oil palm plantation.

    PubMed

    Muhamad, Halimah; Zainol, Maznah; Sahid, Ismail; Abu Seman, Idris

    2012-08-01

    In oil palm plantations, the fungicide hexaconazole is used to control Ganoderma infection that threatens to destroy or compromisethe palm. The application of hexaconazole is usually through soil drenching, trunk injection, or a combination of these two methods. It is therefore important to have a method to determine the residual amount of hexaconazole in the field such as in samples of water, soil, and leaf to monitor the use and fate of the fungicide in oil palm plantations. This study on the behaviour of hexaconazole in oil palm agro-environment was carried out at the UKM-MPOB Research Station, Bangi Lama, Selangor. Three experimental plots in this estate with 7-year-old Dura x Pisifera (DxP) palms were selected for the field trial. One plot was sprayed with hexaconazole at the manufacturer's recommended dosage, one at double the recommended dosage, and the third plot was untreated control. Hexaconazole residues in the soil, leaf, and water were determined before and after fungicide treatment. Soil samples were randomly collected from three locations at different depths (0-50 cm) and soil collected fromthe same depth were bulked together. Soil, water, and palm leaf were collected at -1 (day before treatment), 0 (day of treatment), 1, 3, 7, 14, 21, 70, 90, and 120 days after treatment. Hexaconazole was detected in soil and oil palm leaf, but was not detected in water from the nearby stream. PMID:22851367

  12. Sedimentary style and oil-gas field distribution in Western Bohai Bay

    SciTech Connect

    Hansheng Qiao )

    1994-07-01

    Western Bohai Bay is located near Tianjing City and the Yanshan Mountains. Tectonically, it is part of the Bohai Bay rift, including the Qiku, Nanpu, and Cangdong depressions. The Paleogene strata consist of three cycles in the rift. Usually, the sublacustrine fans or basalts formed at the initial stage of every cycle. The dark shales and turbidites developed at the high level of lacustrine transgression. However, the deltas or evaporates appeared at the regressive stage. The sublacustrine fans or deltas generally distribute in the marginal part of a depression, with humic type kerogen. The dark shales of deep lacustrine facies in the inner part of it contain sapropel type kerogen. The transitional zone between them is interbedded shales and sandstones, with mixed type kerogen. The oil-gas fields mainly occur in the transitional zone around the oil-generating center. The great oil-gas fields are formed in areas where the big drape anticline coincided with the sublacustrine fan-front or delta-front sandstones and were sealed by shales or evaporates. A great number of small overpressured oil reservoirs are in the mature source rocks in the depression center.

  13. How to make a billion-barrel oil field in offshore California commercial

    SciTech Connect

    Patterson, J.C.; Ballard, J.H.

    1988-02-01

    The major obstacles and challenges involved in exploration and development of a giant deep-water low-gravity oil field are exemplified in the undeveloped Sword field of offshore southern California. In 1979, Conoco Exploration identified a northeast-southwest-trending basement high in the 800 to 2000-ft deep federal waters 12 mi southwest of Pt. Conception at the western end of the Santa Barbara Channel. The intended reservoir was fractured Miocene Monterey chert, silicic shales/siltstones, and dolomites that are draped over the axially faulted structure. Drilling of the initial well in OCS P-0322 in 1982 resulted in discovering the giant Sword field. A confirmation well drilled in OCS P-0320 indicates in-place reserves of well over 1 billion bbl. While the discovered potential is significant, the low gravity (8.5/degree/-10.5/degree/ API) of the oils discovered to date, along with water depths in excess of 1500 ft, currently pose economic challenges to successful field development. Conoco and its partners are addressing the current economic barriers on a number of fronts. Three-dimensional seismic surveys are being conducted to better delineate reservoir geometry and to define probable variations in lithology, fracturing, and oil gravity. A market feasibility study will be undertaken to assess the demand for low-gravity crude from offshore California.

  14. Oil-field wastewater purification by magnetic separation technique using a novel magnetic nanoparticle

    NASA Astrophysics Data System (ADS)

    Liu, Zhuonan; Yang, Huihui; Zhang, Hao; Huang, Chuanjun; Li, Laifeng

    2012-12-01

    In the present work, oil-field wastewater purification through superconducting magnetic separation technique using a novel magnetic nanoparticle was investigated. The magnetic nanoparticle, which has a multi-shell structure with ferroferric oxide as core, dense nonporous silica as inter layer and mesoporous silica as outer layer, was synthesized by co-precipitation method. To functionalize the magnetic nanoparticle, plasma polymerization technique was adopted and poly methyl acrylate (PMA) was formed on the surface of the nanoparticle. The multi-shell structure of the nanoparticle was confirmed by transmission electron microscope (TEM) and the characteristic is measurable by FTIR. It is found that most of the pollutants (85% by turbidity or 84% by COD value) in the oil-field wastewater are removed through the superconducting magnetic separation technique using this novel magnetic nanoparticle.

  15. Short chain aliphatic acid anions in oil field waters and their contribution to the measured alkalinity

    USGS Publications Warehouse

    Willey, L.M.; Kharaka, Y.K.; Presser, T.S.; Rapp, J.B.; Barnes, I.

    1975-01-01

    High alkalinity values found in some formation waters from Kettleman North Dome oil field are due chiefly to acetate and propionate ions, with some contribution from higher molecular weight organic acid ions. Some of these waters contain no detectable bicarbonate alkalinity. For waters such as these, high supersaturation with respect to calcite will be incorrectly indicated by thermodynamic calculations based upon carbonate concentrations inferred from traditional alkalinity measurements. ?? 1975.

  16. Risk assessment of nonhazardous oil-field waste disposal in salt caverns.

    SciTech Connect

    Elcock, D.

    1998-03-05

    In 1996, Argonne National Laboratory (ANL) conducted a preliminary technical and legal evaluation of disposing of nonhazardous oil-field wastes (NOW) into salt caverns. Argonne determined that if caverns are sited and designed well, operated carefully, closed properly, and monitored routinely, they could be suitable for disposing of oil-field wastes. On the basis of these findings, Argonne subsequently conducted a preliminary evaluation of the possibility that adverse human health effects (carcinogenic and noncarcinogenic) could result from exposure to contaminants released from the NOW disposed of in domal salt caverns. Steps used in this evaluation included the following: identifying potential contaminants of concern, determining how humans could be exposed to these contaminants, assessing contaminant toxicities, estimating contaminant intakes, and calculating human cancer and noncancer risk estimates. Five postclosure cavern release scenarios were assessed. These were inadvertent cavern intrusion, failure of the cavern seal, failure of the cavern through cracks, failure of the cavern through leaky interbeds, and a partial collapse of the cavern roof. Assuming a single, generic, salt cavern and generic oil-field wastes, potential human health effects associated with constituent hazardous substances (arsenic, benzene, cadmium, and chromium) were assessed under each of these scenarios. Preliminary results provided excess cancer risk and hazard index (referring to noncancer health effects) estimates that were well within the US Environmental Protection Agency (EPA) target range for acceptable exposure risk levels. These results led to the preliminary conclusion that from a human health perspective, salt caverns can provide an acceptable disposal method for nonhazardous oil-field wastes.

  17. Static Electric Field Mapping Using a Mosquito Racket and Baby Oil

    ERIC Educational Resources Information Center

    Rediansyah, Herfien; Khairurrijal; Viridi, Sparisoma

    2015-01-01

    The aim of this research was to design a simple experimental device to see electric field force lines using common components which are readily available in everyday life. A solution of baby oil was placed in a plastic container, 4.5 × 4.5 × 1 inches, with both ends of the electrodes (metal wire) immersed in the solution at a depth of 0.2 inches.…

  18. Estimated human health risks of disposing of nonhazardous oil field waste in salt caverns

    SciTech Connect

    Tomasko, D.; Elcock, D.; Veil, J.

    1997-09-01

    Argonne National Laboratory (ANL) has completed an evaluation of the possibility that adverse human health effects (carcinogenic and noncarcinogenic) could result from exposure to contaminants released from nonhazardous oil field wastes (NOW) disposed in domal salt caverns. In this assessment, several steps were used to evaluate potential human health risks: identifying potential contaminants of concern, determining how humans could be exposed to these contaminants, assessing the contaminants` toxicities, estimating contaminant intakes, and, finally, calculating human cancer and noncancer risks.

  19. Disposal of NORM-Contaminated Oil Field Wastes in Salt Caverns

    SciTech Connect

    Blunt, D.L.; Elcock, D.; Smith, K.P.; Tomasko, D.; Viel, J.A.; and Williams, G.P.

    1999-01-21

    In 1995, the U.S. Department of Energy (DOE), Office of Fossil Energy, asked Argonne National Laboratory (Argonne) to conduct a preliminary technical and legal evaluation of disposing of nonhazardous oil field waste (NOW) into salt caverns. That study concluded that disposal of NOW into salt caverns is feasible and legal. If caverns are sited and designed well, operated carefully, closed properly, and monitored routinely, they can be a suitable means of disposing of NOW (Veil et al. 1996). Considering these findings and the increased U.S. interest in using salt caverns for NOW disposal, the Office of Fossil Energy asked Argonne to conduct further research on the cost of cavern disposal compared with the cost of more traditional NOW disposal methods and on preliminary identification and investigation of the risks associated with such disposal. The cost study (Veil 1997) found that disposal costs at the four permitted disposal caverns in the United States were comparable to or lower than the costs of other disposal facilities in the same geographic area. The risk study (Tomasko et al. 1997) estimated that both cancer and noncancer human health risks from drinking water that had been contaminated by releases of cavern contents were significantly lower than the accepted risk thresholds. Since 1992, DOE has funded Argonne to conduct a series of studies evaluating issues related to management and disposal of oil field wastes contaminated with naturally occurring radioactive material (NORM). Included among these studies were radiological dose assessments of several different NORM disposal options (Smith et al. 1996). In 1997, DOE asked Argonne to conduct additional analyses on waste disposal in salt caverns, except that this time the wastes to be evaluated would be those types of oil field wastes that are contaminated by NORM. This report describes these analyses. Throughout the remainder of this report, the term ''NORM waste'' is used to mean ''oil field waste contaminated by NORM''.

  20. Static Electric Field Mapping Using a Mosquito Racket and Baby Oil

    ERIC Educational Resources Information Center

    Rediansyah, Herfien; Khairurrijal; Viridi, Sparisoma

    2015-01-01

    The aim of this research was to design a simple experimental device to see electric field force lines using common components which are readily available in everyday life. A solution of baby oil was placed in a plastic container, 4.5 4.5 1 inches, with both ends of the electrodes (metal wire) immersed in the solution at a depth of 0.2 inches.

  1. CO2 Storage and Enhanced Oil Recovery: Bald Unit Test Site, Mumford Hills Oil Field, Posey County, Indiana

    SciTech Connect

    Frailey, Scott M.; Krapac, Ivan G.; Damico, James R.; Okwen, Roland T.; McKaskle, Ray W.

    2012-03-30

    The Midwest Geological Sequestration Consortium (MGSC) carried out a small-scale carbon dioxide (CO2) injection test in a sandstone within the Clore Formation (Mississippian System, Chesterian Series) in order to gauge the large-scale CO2 storage that might be realized from enhanced oil recovery (EOR) of mature Illinois Basin oil fields via miscible liquid CO2 flooding.

  2. Risk analyses for disposing nonhazardous oil field wastes in salt caverns

    SciTech Connect

    Tomasko, D.; Elcock, D.; Veil, J.; Caudle, D.

    1997-12-01

    Salt caverns have been used for several decades to store various hydrocarbon products. In the past few years, four facilities in the US have been permitted to dispose nonhazardous oil field wastes in salt caverns. Several other disposal caverns have been permitted in Canada and Europe. This report evaluates the possibility that adverse human health effects could result from exposure to contaminants released from the caverns in domal salt formations used for nonhazardous oil field waste disposal. The evaluation assumes normal operations but considers the possibility of leaks in cavern seals and cavern walls during the post-closure phase of operation. In this assessment, several steps were followed to identify possible human health risks. At the broadest level, these steps include identifying a reasonable set of contaminants of possible concern, identifying how humans could be exposed to these contaminants, assessing the toxicities of these contaminants, estimating their intakes, and characterizing their associated human health risks. The contaminants of concern for the assessment are benzene, cadmium, arsenic, and chromium. These were selected as being components of oil field waste and having a likelihood to remain in solution for a long enough time to reach a human receptor.

  3. PC and mainframe computer-graphics techniques applied to volumetric evaluation of a mature oil field

    SciTech Connect

    Newell, K.D.; Schoeling, L.G.; Wong, J.C. )

    1990-11-01

    Mapping and volumetric analysis of large reservoirs are important steps in evaluating mature oil fields for secondary and tertiary development. This paper describes how a research group mapped and conducted an extensive volumetric analysis on the Zenith pool, a large, mature oil field in central Kansas, with a Data General MV20000 minicomputer with Surface III mapping software and a PC with Surfer and spreadsheet software. A step-by-step procedure was developed to generate structure, isopach, and porosity maps for the five main reservoirs in the field. Lotus 123{sup TM} spreadsheets were developed to compile locations, formation tops, and other critical data for more than 500 wells. These data were sent to the minicomputer to generate contour maps depicting structure, isopachs, and porosities with output directed to an electrostatic color plotter. Grid-to-grid manipulation and cross multiplication of these contour maps allowed construction of a porosity-foot map for each reservoir. The final contour maps incorporated the effects of oil/water contact (OWC) with a porosity cutoff determined from porosity/permeability crossplots. Integration of the porosity-foot maps facilitated volumetric and spatial comparison with historic production data.

  4. Depositional environments of Upper Triassic sandstones, El Borma oil field, southwestern Tunisia

    SciTech Connect

    Bentahar, H.; Ethridge, F.G. )

    1991-03-01

    El Borma oil field in southwestern Tunisia is located on the Algerian border and produces from five Upper Triassic sandstone reservoirs at depths ranging from 2,300 to 2,400 m. The 250 km{sup 2} field has recoverable reserves of 770 mm bbl of equivalent oil. Reservoir sandstones rest unconformably on south-dipping Lower Devonian clastic deposits. Silurian shale represents the major oil source rock and the field is capped by 550 m of shale, carbonate, and evaporite. Hercynian, topography below the reservoir sandstones comprises an 18 km wide, northeast-oriented paleovalley. Each of the four lower reservoir sandstones, bounded by a lower scour surface and a basal lag deposit, is commonly discontinuous and separated by lenticular shale beds. These 5 to 15 m thick sandstones display in channels flowing to the northeast. The overlying 12 m thick transgressive marine dolomitic shale contains carbonized bivalves and is capped by a paleosoil with root structures and siderite cement indicating subaerial exposure. The clay-rich and locally bioturbated uppermost reservoir sandstone was probably deposited in a tidally influenced estuary. Overall, the Upper Triassic reservoirs at El Borma consists of valley-fill estuary deposits that were formed during transgression of the sea from the northeast.

  5. Distribution and origin of groundwater methane in the Wattenberg oil and gas field of northern Colorado.

    PubMed

    Li, Huishu; Carlson, Kenneth H

    2014-01-01

    Public concerns over potential environmental contamination associated with oil and gas well drilling and fracturing in the Wattenberg field in northeast Colorado are increasing. One of the issues of concern is the migration of oil, gas, or produced water to a groundwater aquifer resulting in contamination of drinking water. Since methane is the major component of natural gas and it can be dissolved and transported with groundwater, stray gas in aquifers has elicited attention. The initial step toward understanding the environmental impacts of oil and gas activities, such as well drilling and fracturing, is to determine the occurrence, where it is and where it came from. In this study, groundwater methane data that has been collected in response to a relatively new regulation in Colorado is analyzed. Dissolved methane was detected in 78% of groundwater wells with an average concentration of 4.0 mg/L and a range of 0-37.1 mg/L. Greater than 95% of the methane found in groundwater wells was classified as having a microbial origin, and there was minimal overlap between the C and H isotopic characterization of the produced gas and dissolved methane measured in the aquifer. Neither density of oil/gas wells nor distance to oil/gas wells had a significant impact on methane concentration suggesting other important factors were influencing methane generation and distribution. Thermogenic methane was detected in two aquifer wells indicating a potential contamination pathway from the producing formation, but microbial-origin gas was by far the predominant source of dissolved methane in the Wattenberg field. PMID:24456231

  6. Significant role of structural fractures in Ren-Qiu buried-block oil field, eastern China

    SciTech Connect

    Fei, Q.; Xie-Pei, W.

    1983-03-01

    Ren-qui oil field is in a buried block of Sinian (upper Proterozoic) rocks located in the Ji-zhong depression of the western Bohai Bay basin in eastern China. The main reservoir consists of Sinian dolomite rocks. It is a fault block with a large growth fault on the west side which trends north-northeast with throws of up to 1 km (0.6 mi) or more. The source rocks for the oil are Paleogene age and overlie the Sinian dolomite rocks. The structural fractures are the main factor forming the reservoir of the buried-block oil field. Three structural lines, trending northeast, north-northeast, and northwest, form the regional netted fracture system. The north-northeast growth fault controlled the structural development of the buried block. The block was raised and eroded before the Tertiary sediments were deposited. In the Eocene Epoch, the Ji-zhong depression subsided, but the deposition, faulting, and related uplift of the block happened synchronously as the block was gradually submerged. At the same time, several horizontal and vertical karst zones were formed by the karst water along the netted structural fractures. The Eocene oil source rocks lapped onto the block and so the buried block, with many developed karst fractures, was surrounded by a great thickness of source rocks. As the growth fault developed, the height of the block was increased from 400 m (1300 ft) before the Oligocene to 1300 m (4250 ft) after. As the petroleum was generated, it migrated immediately into the karst fractures of the buried block along the growth fault. The karst-fractured block reservoir has an 800-m (2600-ft) high oil-bearing closure and good connections developed between the karst fractures.

  7. INCREASING WATERFLOOD RESERVES IN THE WILMINGTON OIL FIELD THROUGH IMPROVED RESERVOIR CHARACTERIZATION AND RESERVOIR MANAGEMENT

    SciTech Connect

    Scott Walker; Chris Phillips; Roy Koerner; Don Clarke; Dan Moos; Kwasi Tagbor

    2002-02-28

    This project increased recoverable waterflood reserves in slope and basin reservoirs through improved reservoir characterization and reservoir management. The particular application of this project is in portions of Fault Blocks IV and V of the Wilmington Oil Field, in Long Beach, California, but the approach is widely applicable in slope and basin reservoirs. Transferring technology so that it can be applied in other sections of the Wilmington Field and by operators in other slope and basin reservoirs is a primary component of the project. This project used advanced reservoir characterization tools, including the pulsed acoustic cased-hole logging tool, geologic three-dimensional (3-D) modeling software, and commercially available reservoir management software to identify sands with remaining high oil saturation following waterflood. Production from the identified high oil saturated sands was stimulated by recompleting existing production and injection wells in these sands using conventional means as well as a short radius redrill candidate. Although these reservoirs have been waterflooded over 40 years, researchers have found areas of remaining oil saturation. Areas such as the top sand in the Upper Terminal Zone Fault Block V, the western fault slivers of Upper Terminal Zone Fault Block V, the bottom sands of the Tar Zone Fault Block V, and the eastern edge of Fault Block IV in both the Upper Terminal and Lower Terminal Zones all show significant remaining oil saturation. Each area of interest was uncovered emphasizing a different type of reservoir characterization technique or practice. This was not the original strategy but was necessitated by the different levels of progress in each of the project activities.

  8. 77 FR 40637 - Wyatt VI, Inc., A Division of Wyatt Field Service Company, Working On-Site at Hovensa Oil...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-10

    ... was published in the Federal Register on April 19 (77 FR 23511). The workers' firm supplies...-Site at Hovensa Oil Refinery, Christiansted, St. Croix, VI; Notice of Affirmative Determination... Field Service Company, working on-site at Hovensa Oil Refinery, Christiansted, St. Croix, Virgin...

  9. Deciphering biodegradation effects on light hydrocarbons in crude oils using their stable carbon isotopic composition: A case study from the Gullfaks oil field, offshore Norway

    NASA Astrophysics Data System (ADS)

    Vieth, Andrea; Wilkes, Heinz

    2006-02-01

    Compound-specific isotope analysis has become an important tool in environmental studies and is an especially powerful way to evaluate biodegradation of hydrocarbons. Here, carbon isotope ratios of light hydrocarbons were used to characterise in-reservoir biodegradation in the Gullfaks oil field, offshore Norway. Increasing biodegradation, as characterised, for example, by increasing concentration ratios of Pr/ n-C 17 and Ph/ n-C 18, and decreasing concentrations of individual light hydrocarbons were correlated to 13C-enrichment of the light hydrocarbons. The δ13C values of C 4 to C 9n-alkanes increase by 7-3‰ within the six oil samples from the Brent Group of the Gullfaks oil field, slight changes (1-3‰) being observed for several branched alkanes and benzene, whereas no change (<1‰) in δ13C occurs for cyclohexane, methylcyclohexane, and toluene. Application of the Rayleigh equation demonstrated high to fair correlation of concentration and isotope data of i- and n-pentane, n-hexane, and n-heptane, documenting that biodegradation in reservoirs can be described by the Rayleigh model. Using the appropriate isotope fractionation factor of n-hexane, derived from laboratory experiments, quantification of the loss of this petroleum constituent due to biodegradation is possible. Toluene, which is known to be highly susceptible to biodegradation, is not degraded within the Gullfaks oil field, implying that the local microbial community exhibits rather pronounced substrate specificities. The evaluation of combined molecular and isotopic data expands our understanding of the anaerobic degradation processes within this oil field and provides insight into the degradative capabilities of the microorganisms. Additionally, isotope analysis of unbiodegraded to slightly biodegraded crude oils from several oil fields surrounding Gullfaks illustrates the heterogeneity in isotopic composition of the light hydrocarbons due to source effects. This indicates that both source and also maturity effects have to be well constrained when using compound-specific isotope analysis for the assessment of biodegradation.

  10. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2001-11-01

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through June 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Third Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. The project team ramped up well work activity from October 2000 to September 2001 to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being addressed in 2001.

  11. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2002-01-31

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through September 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Fourth Quarter 2001 performing routine well work and reservoir surveillance on the Tar II-A post-steamflood and Tar V pilot steamflood projects. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. The project team ramped up well work activity from October 2000 through November 2001 to increase production and injection. In December, water injection well FW-88 was plug and abandoned and replaced by new well FW-295 into the ''D'' sands to accommodate the Port of Long Beach at their expense. Well workovers are planned for 2002 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The steamflood operation in the Tar V pilot project is mature and profitable. Recent production performance is below projections because of wellbore mechanical limitations that were being addressed in 2001. As the fluid production is hot, the pilot steamflood was converted to a hot waterflood project in June 2001.

  12. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2001-05-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through March 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Second Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A steamflood reservoirs have been operated over fifteen months at relatively stable pressures, due in large part to the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase in January 1999. Starting in the Fourth Quarter 2000, the project team has ramped up activity to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being addressed in 2001. Much of the second quarter was spent writing DOE annual and quarterly reports to stay current with contract requirements.

  13. Increasing Waterflood Reserves in the Wilmington Oil Field Through Reservoir Characterization and Reservoir Management

    SciTech Connect

    Chris Phillips; Dan Moos; Don Clarke; John Nguyen; Kwasi Tagbor; Roy Koerner; Scott Walker

    1997-04-10

    This project is intended to increase recoverable waterflood reserves in slope and basin reservoirs through improved reservoir characterization and reservoir management. The particular application of this project is in portions of Fault Blocks IV and V of the Wilmington Oil Field, in Long Beach, California, but the approach is widely applicable in slope and basin reservoirs. Transferring technology so that it can be applied in other sections of the Wilmington Field and by operators in other slope and basin reservoirs is a primary component of the project.

  14. Field experiences with rotordynamic instability in high-performance turbomachinery. [oil and natural gas recovery

    NASA Technical Reports Server (NTRS)

    Doyle, H. E.

    1980-01-01

    Two field situations illustrate the consequences of rotordynamic instability in centrifugal compressors. One involves the reinjection of produced gas into a North Sea oil formation for the temporary extraction of crude. The other describes on-shore compressors used to deliver natural gas from off-shore wells. The problems which developed and the remedies attempted in each case are discussed. Instability problems resulted in lost production, extended construction periods and costs, and heavy maintenance expenditures. The need for effective methods to properly identify the problem in the field and in the compressor design stage is emphasized.

  15. Impact of an oil field effluent on microbial activities in a Wyoming river.

    PubMed

    Heitkamp, M A; Johnson, B T

    1984-06-01

    The survival, functions, and physiological diversity of autochthonous sediment microbiota were examined in situ at five stations along the Little Popo Agie River, WY; one station above, one at, and three below a discharge point for oil wastewater from Union Oil Company's Dallas Field. Below the oil wastewater discharge point there were increases in electron-transport activity, carbon dioxide production, and microbial populations of heterotrophs, ammonifiers, hexadecane degraders, starch hydrolyzers, protein hydrolyzers, and sulfate reducers. At a station 1420 m below the discharge point, however, overall sediment microbial activities and all of the physiological groups of bacteria, except hexadecane-degrading microbiota, were at levels comparable with those at the control station above the discharge point. Similarly, mineralization of glucose, amino acids, hexanoic acid, and hexadecane was elevated at stations directly below the discharge point, but appeared to subside rapidly. Xenobiotic biodegradation potential of the sediments varied with the chemical and the sample location and was not directly related to oil residue levels in the sediment. Microorganisms thus appeared to maintain physiological diversity and increased in numbers and activity in a riverine environment that contained petroleum hydrocarbon concentrations known to be deleterious to freshwater fish and macrobenthic communities. PMID:6488102

  16. Residual-oil-saturation-technology test, Bell Creek Field, Montana. Final report

    SciTech Connect

    Not Available

    1981-06-01

    A field test was conducted of the technology available to measure residual oil saturation following waterflood secondary oil recovery processes. The test was conducted in a new well drilled solely for that purpose, located immediately northwest of the Bell Creek Micellar Polymer Pilot. The area where the test was conducted was originally drilled during 1968, produced by primary until late 1970, and was under line drive waterflood secondary recovery until early 1976, when the area was shut in at waterflood depletion. This report presents the results of tests conducted to determine waterflood residual oil saturation in the Muddy Sandstone reservoir. The engineering techniques used to determine the magnitude and distribution of the remaining oil saturation included both pressure and sidewall cores, conventional well logs (Dual Laterolog - Micro Spherically Focused Log, Dual Induction Log - Spherically Focused Log, Borehole Compensated Sonic Log, Formation Compensated Density-Compensated Neutron Log), Carbon-Oxygen Logs, Dielectric Logs, Nuclear Magnetism Log, Thermal Decay Time Logs, and a Partitioning Tracer Test.

  17. A new reserve growth model for United States oil and gas fields

    USGS Publications Warehouse

    Verma, M.K.

    2005-01-01

    Reserve (or field) growth, which is an appreciation of total ultimate reserves through time, is a well-recognized phenomenon, particularly in mature petroleum provinces. The importance of forecasting reserve growth accurately in a mature petroleum province made it necessary to develop improved growth functions, and a critical review of the original Arrington method was undertaken. During a five-year (1992-1996), the original Arrington method gave 1.03% higher than the actual oil reserve growth, whereas the proposed modified method gave a value within 0.3% of the actual growth, and therefore it was accepted for the development for reserve growth models. During a five-year (1992-1996), the USGS 1995 National Assessment gave 39.3% higher oil and 33.6% lower gas than the actual growths, whereas the new model based on Modified Arrington method gave 11.9% higher oil and 29.8% lower gas than the actual growths. The new models forecast predict reserve growths of 4.2 billion barrels of oil (2.7%) and 30.2 trillion cubic feet of gas (5.4%) for the conterminous U.S. for the next five years (1997-2001). ?? 2005 International Association for Mathematical Geology.

  18. Methanotrophy in a Paleoproterozoic oil field ecosystem, Zaonega Formation, Karelia, Russia.

    PubMed

    Qu, Y; Crne, A E; Lepland, A; van Zuilen, M A

    2012-11-01

    Organic carbon rich rocks in the c. 2.0 Ga Zaonega Formation (ZF), Karelia, Russia, preserve isotopic characteristics of a Paleoproterozoic ecosystem and record some of the oldest known oil generation and migration. Isotopic data derived from drill core material from the ZF show a shift in δ(13) C(org) from c. -25‰ in the lower part of the succession to c. -40‰ in the upper part. This stratigraphic shift is a primary feature and cannot be explained by oil migration, maturation effects, or metamorphic overprints. The shift toward (13) C-depleted organic matter (δ(13) C(org) < -25‰) broadly coincides with lithological evidence for the generation of oil and gas in the underlying sediments and seepage onto the sea floor. We propose that the availability of thermogenic CH(4) triggered the activity of methanotrophic organisms, resulting in the production of anomalously (13) C-depleted biomass. The stratigraphic shift in δ(13) C(org) records the change from CO(2) -fixing autotrophic biomass to biomass containing a significant contribution from methanotrophy. It has been suggested recently that this shift in δ(13) C(org) reflects global forcing and progressive oxidation of the Earth. However, the lithologic indication for local thermogenic CH(4) , sourced within the oil field, is consistent with basinal methanotrophy. This indicates that regional/basinal processes can also explain the δ(13) C(org) negative isotopic shift observed in the ZF. PMID:23009699

  19. A field experiment to assess impact of chemically dispersed oil on Arabian Gulf corals

    SciTech Connect

    Le Gore, R.S.; Cuddeback, J.E.; Hofmann, J.E.; Marszalek, D.S.

    1983-03-01

    Field experiments were conducted on a coral reef at Jurayd Island (Saudi Arabia) in the Arabian Gulf to study the effects of chemically dispersed oil on local corals. Portions of the reef were exposed to predetermined concentrations of oil alone, dispersant alone, and oil-plus-dispersant mixtures. Areas of the reef not exposed to any of the toxicants were used as controls. Arabian Light Crude and Corexit 9527 dispersant were the test toxicants. Two series of experiments were conducted beginning in September 1981, one with a 24-hour exposure period and the other with a 5-day (120-hour) exposure period. Corals were stained for growth rate studies and extensively photographed to document any observed effects. Corals were examined for biological impacts immediately after the exposures, and then at 3-month intervals for 1 year. Water temperature, salinity, dissolved oxygen, and hydrocarbon content were recorded during the exposure periods. Coral growth appeared unaffected by exposure to the toxicants. Some Acropora species corals exposed to dispersed oil for 5 days exhibited delayed effects, which became apparent during the relatively cold winter season.

  20. Gas, water, and oil production from Wattenberg field in the Denver Basin, Colorado

    USGS Publications Warehouse

    Nelson, Philip H.; Santus, Stephen L.

    2011-01-01

    Gas, oil, and water production data were compiled from selected wells in two tight gas reservoirs-the Codell-Niobrara interval, comprised of the Codell Sandstone Member of the Carlile Shale and the Niobrara Formation; and the Dakota J interval, comprised mostly of the Muddy (J) Sandstone of the Dakota Group; both intervals are of Cretaceous age-in the Wattenberg field in the Denver Basin of Colorado. Production from each well is represented by two samples spaced five years apart, the first sample typically taken two years after production commenced, which generally was in the 1990s. For each producing interval, summary diagrams and tables of oil-versus-gas production and water-versus-gas production are shown with fluid-production rates, the change in production over five years, the water-gas and oil-gas ratios, and the fluid type. These diagrams and tables permit well-to-well and field-to-field comparisons. Fields producing water at low rates (water dissolved in gas in the reservoir) can be distinguished from fields producing water at moderate or high rates, and the water-gas ratios are quantified. The Dakota J interval produces gas on a per-well basis at roughly three times the rate of the Codell-Niobrara interval. After five years of production, gas data from the second samples show that both intervals produce gas, on average, at about one-half the rate as the first sample. Oil-gas ratios in the Codell-Niobrara interval are characteristic of a retrograde gas and are considerably higher than oil-gas ratios in the Dakota J interval, which are characteristic of a wet gas. Water production from both intervals is low, and records in many wells are discontinuous, particularly in the Codell-Niobrara interval. Water-gas ratios are broadly variable, with some of the variability possibly due to the difficulty of measuring small production rates. Most wells for which water is reported have water-gas ratios exceeding the amount that could exist dissolved in gas at reservoir pressure and temperature. The Codell-Niobrara interval is reported to be overpressured (that is, pressure greater than hydrostatic) whereas the underlying Dakota J interval is underpressured (less than hydrostatic), demonstrating a lack of hydraulic communication between the two intervals despite their proximity over a broad geographical area. The underpressuring in the Dakota J interval has been attributed by others to outcropping strata east of the basin. We agree with this interpretation and postulate that the gas accumulation also may contribute to hydraulic isolation from outcrops immediately west of the basin.

  1. NMR measurement of oil shale magnetic relaxation at high magnetic field

    USGS Publications Warehouse

    Seymour, Joseph D.; Washburn, Kathryn E.; Kirkland, Catherine M.; Vogt, Sarah J.; Birdwell, Justin E.; Codd, Sarah L.

    2013-01-01

    Nuclear magnetic resonance (NMR) at low field is used extensively to provide porosity and pore-size distributions in reservoir rocks. For unconventional resources, due to low porosity and permeability of the samples, much of the signal exists at very short T2 relaxation times. In addition, the organic content of many shales will also produce signal at short relaxation times. Despite recent improvements in low-field technology, limitations still exist that make it difficult to account for all hydrogen-rich constituents in very tight rocks, such as shales. The short pulses and dead times along with stronger gradients available when using high-field NMR equipment provides a more complete measurement of hydrogen-bearing phases due to the ability to probe shorter T2 relaxation times (-5 sec) than can be examined using low-field equipment. Access to these shorter T2 times allows for confirmation of partially resolved peaks observed in low-field NMR data that have been attributed to solid organic phases in oil shales. High-field (300 MHz or 7 T) NMR measurements of spin-spin T2 and spin-lattice T1 magnetic relaxation of raw and artificially matured oil shales have potential to provide data complementary to low field (2 MHz or 0.05T) measurements. Measurements of high-field T2 and T1-T2 correlations are presented. These data can be interpreted in terms of organic matter phases and mineral-bound water known to be present in the shale samples, as confirmed by Fourier transform infrared spectroscopy, and show distributions of hydrogen-bearing phases present in the shales that are similar to those observed in low field measurements.

  2. Geologic Sequestration of CO2 in a Depleted Oil Reservoir: A Field Demonstration

    NASA Astrophysics Data System (ADS)

    Westrich, H. R.; Zhang, D.; Grigg, R. B.

    2002-12-01

    Carbon dioxide (CO2) sequestration in geologic formations is the most direct carbon management strategy for long-term removal of anthropogenic CO2 from the atmosphere, and is likely to be needed for continuation of the US fossil fuel-based economy and high standard of living. Subsurface injection of CO2 into depleted oil reservoirs is a carbon sequestration strategy that might prove to be both cost effective and environmentally safe. However, there are significant R&D gaps that need to be addressed prior to sequestration of CO2 in depleted oil reservoirs, including the need of coupled physicochemical processes involving CO2, water, oil and reservoir rock, better estimates of the capacity of reservoir for long-term sequestration and ultimate fate of injected CO2, and improved geophysical monitoring technologies for accurately determining the presence and location of injected CO2. Our project is part of the DOE Carbon Sequestration program and it is directed at predicting and monitoring the migration and ultimate fate of CO2 after injection in a depleted oil reservoir. We utilize computer simulations of multiphase oil-brine-CO2 flow in the reservoir, laboratory measurements of geochemical brine-rock reactions, and geophysical surveys to monitor CO2 plume migration after injection. A principal component of this project is characterization and validation of predicted CO2 migration and fate through a field demonstration experiment. The reservoir under investigation is part of the West Pearl Queen field in southeastern New Mexico. Geologic modeling and numerical flow simulations (ECLIPSE code) have been used to study the feasibility of injection, and these techniques were used to help in designing geophysical monitoring studies to track the injected plume. Long-term static brine-rock reactions and short-term brine-CO2-oil flow through tests were performed to better understand the likely geochemical reactions that might be influence CO2 sequestration or injection. Results include identification of gypsum precipitation at high CO2 gas pressures and permeability-porosity measurements of the reservoir. Baseline geophysical surveys are in progress, with CO2 injection at the field site to begin immediately afterwards. Preliminary results of lab tests, computer simulations and geophysical imaging will be presented.

  3. A Fuzzy Feed-Forward/Feedback Control System for a Three-Phase Oil Field Centrifuge.

    SciTech Connect

    Parkinson, W. J. ,; Smith, R. E.; Mortensen, F. N.; Wantuck, P. J.; Ross, Timothy J.; Jamshidi, Mohammad; Miller, N.

    2002-01-01

    A set of fuzzy controllers was designed and applied to a commercial three-phase oil field centrifuge. This centrifuge is essentially a one of a kind unit. It is used to recover oil from tank bottoms and oil field and/or refinery sludge. It is unique because it can separate oily emulsions into three separate phases, oil, water, and solids, in one operation. The centrifuge is a large but portable device. It is moved form site to site and is used to separate a large variety of waste emulsions. The centrifuge feedstock varies significantly from site to site and often varies significantly during the daily operation. In this application, fuzzy logic was used on a class of problems not easily solved by classical control techniques. The oil field centrifuge is a highly nonlinear system, with a time varying input. We have been unable to develop a physical-mathematical model of the portion of the centrifuge operation that actually separates the oil, water, and solids. For this portion of the operation we developed a fuzzy feedback control system that modeled a skilled operator's knowledge and actions as opposed to the physical model of the centrifuge itself. Because of the variable feed we had to develop a feed-forward controller that would sense and react to feed changes prior to the time that the actual change reached the centrifuge separation unit. This portion of the control system was also a fuzzy controller designed around the knowledge of a skilled operator. In addition to the combined feed-forward and feedback control systems, we developed a soft-sensor that was used to determine the value of variables needed for the feed-forward control system. These variables could not actually be measured but were calculated from the measurement of other variables. The soft-sensor was developed with a combination of a physical model of the feed system and a skilled operator's expert knowledge. Finally the entire control system is tied together with a fuzzy-SPC (Statistical Process Control) filter, used to filter process and instrument noise and a fuzzy conflict resolution code used to keep the feed-forward and feedback control systems working well together.

  4. Weathering of field-collected floating and stranded Macondo oils during and shortly after the Deepwater Horizon oil spill.

    PubMed

    Stout, Scott A; Payne, James R; Emsbo-Mattingly, Stephen D; Baker, Gregory

    2016-04-15

    Chemical analysis of large populations of floating (n=62) and stranded (n=1174) Macondo oils collected from the northern Gulf of Mexico sea surface and shorelines during or within seven weeks of the end of the Deepwater Horizon oil spill demonstrates the range, rates, and processes affecting surface oil weathering. Oil collected immediately upon reaching the sea surface had already lost most mass below n-C8 from dissolution of soluble aliphatics, monoaromatics, and naphthalenes during the oil's ascent with further reductions extending up to n-C13 due to the onset of evaporation. With additional time, weathering of the floating and stranded oils advanced with total PAH (TPAH50) depletions averaging 69±23% for floating oils and 94±3% for stranded oils caused by the combined effects of evaporation, dissolution, and photo-oxidation, the latter of which also reduced triaromatic steroid biomarkers. Biodegradation was not evident among the coalesced floating oils studied, but had commenced in some stranded oils. PMID:26936118

  5. Recent glacial events in the Norwegian North Sea - implications towards a better understanding of charging/leakage of oil fields and its impact oil exploration

    NASA Astrophysics Data System (ADS)

    Stoddart, Daniel

    2014-05-01

    Recent drilling and appraisal on the Southern Utsira High, Norwegian North Sea, has proved several large oil/gas discoveries, including the giant Johan Sverdrup, Edvard Grieg, Draupne, Ragnarrock and Apollo oil fields, making this a prolific petroleum area. The Southern Utsira High contains a variety of hydrocarbon density fluids found at several stratigraphic levels illustrating the compartmentalized nature of accumulations and charge history. The Southern Utsira High has been in a position to receive an oil/gas charge for a considerable period of time, with the basin towards the west most likely generating petroleum from early Eocene (50M Mabp) to its maximum present day burial depth. However, reservoir temperatures on the Southern Utsira High are just above the threshold for biodegradation (80°C). The Southern Utsira High oils are non-biodegraded suggesting that the majority of the oil charged relatively late - ca.3 million years ago to present day. The effects of the glaciation on the filling history of the Southern Utsira High are currently being assessed. It is clear that several erosional surfaces in the Pliocene can be identified, as well as glacial channels and moraine deposits, indicating that significant deposition and erosion occurred in the last five million years. Importantly, the effects of glacial rebound mean that the Southern Utsira High more than likely underwent tilting and possible leakage, not just once, but several times in the last 1 million years. The effects of tilting/leakage of geological areas on oil migration have been recognized by several authors. However, the detailed integration of geological mapping and geochemical evidence has not previously been published. The implications of a detailed assessment of tilting of a ''high' through time are; 1) opening up areas where oil migration is thought to be high risk or impossible; 2) identify possible paleo-oil columns aiding the de-risking of discovery appraisal strategies. The evidence of tilting/leakage of oil accumulations through time can be recognized in several oil fields on the Utsira High. The giant Johan Sverdrup discovery oil columns contain paleo-OWC, residual oil zones/paleo-oil columns, and oil shows considerably deeper than the current OWC or residual oil columns. Lundin has performed detailed mapping of the seabed and water column in the Alvheim/Utsira High areas in order to identify areas of gas leakage and its geological manifestations on the seabed and ultimately resulting in the collection of high quality samples. Results shows that gas leakage is prominent over the Alvheim and Utsira High areas and the implications of this to oil exploration will be discussed. In summary, Lundin's approach to oil migration is to better understand the fluid/gas movement throughout the whole basin through time. The talk will focus on the role of glaciations on the timing of charge from the South Viking Graben, fill-spill directions on the Southern Utsira High, the effects of late tilting/leakage on the charge/re-distribution of oil, and seabed / water column characterization and sampling. All placed in the context of oil exploration.

  6. A fortran program for Monte Carlo simulation of oil-field discovery sequences

    USGS Publications Warehouse

    Bohling, G.C.; Davis, J.C.

    1993-01-01

    We have developed a program for performing Monte Carlo simulation of oil-field discovery histories. A synthetic parent population of fields is generated as a finite sample from a distribution of specified form. The discovery sequence then is simulated by sampling without replacement from this parent population in accordance with a probabilistic discovery process model. The program computes a chi-squared deviation between synthetic and actual discovery sequences as a function of the parameters of the discovery process model, the number of fields in the parent population, and the distributional parameters of the parent population. The program employs the three-parameter log gamma model for the distribution of field sizes and employs a two-parameter discovery process model, allowing the simulation of a wide range of scenarios. ?? 1993.

  7. Groundwater compatibility with formation water and pay zone rocks in Pervomaysk oil-gas-condensate field to maintain formation pressure

    NASA Astrophysics Data System (ADS)

    Trifonov, N.; Nazarov, A.; Alekseev, S.

    2016-03-01

    The paper describes the research results in determining the compatibility of groundwater from Aptain-Albian-Cenomanian aquifer with formation water and pay zone rocks in U1 layer sediments, Pervomaysk oil field.

  8. Effect of leachability on environmental risk assessment for naturally occurring radioactive materials in petroleum oil fields.

    PubMed

    Rajaretnam, G; Spitz, H B

    2000-02-01

    Elevated concentrations of naturally occurring radioactive material (NORM), including 238U, 232Th, and their progeny found in underground geologic deposits, are often encountered during crude oil recovery. Radium, the predominant radionuclide brought to the surface with the crude oil and produced water, co-precipitates with barium in the form of complex compounds of sulfates, carbonates, and silicates found in sludge and scale. These NORM deposits are highly stable and very insoluble under ambient conditions at the earth's surface. However, the co-precipitated radium matrix is not thermodynamically stable at reducing conditions which may enable a fraction of the radium to eventually be released to the environment. Although the fate of radium in uranium mill tailings has been studied extensively, the leachability of radium from crude oil NORM deposits exposed to acid-rain and other aging processes is generally unknown. The leachability of radium from NORM contaminated soil collected at a contaminated oil field in eastern Kentucky was determined using extraction fluids having wide range of pH reflecting different extreme environmental conditions. The average 226Ra concentration in the samples of soil subjected to leachability testing was 32.56 Bq g(-1) +/- 0.34 Bq g(-1). The average leaching potential of 226Ra observed in these NORM contaminated soil samples was 1.3% +/- 0.46% and was independent of the extraction fluid. Risk assessment calculations using the family farm scenario show that the annual dose to a person living and working on this NORM contaminated soil is mainly due to external gamma exposure and radon inhalation. However, waterborne pathways make a non-negligible contribution to the dose for the actual resident families living on farmland with the type of residual NORM contamination due to crude oil recovery operations. PMID:10647985

  9. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2002-11-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through June 2002, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V post-steamflood pilot and Tar II-A post-steamflood projects. During the Third Quarter 2002, the project team essentially completed implementing the accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project developed in March 2002 and is proceeding with additional related work. The project team has completed developing laboratory research procedures to analyze the sand consolidation well completion technique and will initiate work in the fourth quarter. The Tar V pilot steamflood project terminated hot water injection and converted to post-steamflood cold water injection on April 19, 2002. Proposals have been approved to repair two sand consolidated horizontal wells that sanded up, Tar II-A well UP-955 and Tar V well J-205, with gravel-packed inner liner jobs to be performed next quarter. Other well work to be performed next quarter is to convert well L-337 to a Tar V water injector and to recomplete vertical well A-194 as a Tar V interior steamflood pattern producer. Plans have been approved to drill and complete well A-605 in Tar V in the first quarter 2003. Plans have been approved to update the Tar II-A 3-D deterministic reservoir simulation model and run sensitivity cases to evaluate the accelerated oil recovery and reservoir cooling plan. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. Well work related to the Tar II-A accelerated oil recovery and reservoir cooling plan began in March 2002 with oil production increasing from 1009 BOPD in the first quarter to 1145 BOPD in the third quarter. Reservoir pressures have been increased during the quarter from 88% to 91% hydrostatic levels in the ''T'' sands and from 91% to 94% hydrostatic levels in the ''D'' sands. Well work during the quarter is described in the Reservoir Management section. The post-steamflood production performance in the Tar V pilot project has been below projections because of wellbore mechanical limitations and the loss of a horizontal producer a second time to sand inflow that are being addressed in the fourth quarter. As the fluid production temperatures exceeded 350 F, our self-imposed temperature limit, the pilot steamflood was converted to a hot waterflood project in June 2001 and converted to cold water injection on April 19, 2002.

  10. Microbial diversity in methanogenic hydrocarbon-degrading enrichment cultures isolated from a water-flooded oil reservoir (Dagang oil field, China)

    NASA Astrophysics Data System (ADS)

    Jiménez, Núria; Cai, Minmin; Straaten, Nontje; Yao, Jun; Richnow, Hans H.; Krüger, Martin

    2015-04-01

    Microbial transformation of oil to methane is one of the main degradation processes taking place in oil reservoirs, and it has important consequences as it negatively affects the quality and economic value of the oil. Nevertheless, methane could constitute a recovery method of carbon from exhausted reservoirs. Previous studies combining geochemical and isotopic analysis with molecular methods showed evidence for in situ methanogenic oil degradation in the Dagang oil field, China (Jiménez et al., 2012). However, the main key microbial players and the underlying mechanisms are still relatively unknown. In order to better characterize these processes and identify the main microorganisms involved, laboratory biodegradation experiments under methanogenic conditions were performed. Microcosms were inoculated with production and injection waters from the reservoir, and oil or 13C-labelled single hydrocarbons (e.g. n-hexadecane or 2-methylnaphthalene) were added as sole substrates. Indigenous microbiota were able to extensively degrade oil within months, depleting most of the n-alkanes in 200 days, and producing methane at a rate of 76 ± 6 µmol day-1 g-1 oil added. They could also produce heavy methane from 13C-labeled 2-methylnaphthalene, suggesting that further methanogenesis may occur from the aromatic and polyaromatic fractions of Dagang reservoir fluids. Microbial communities from oil and 2-methyl-naphthalene enrichment cultures were slightly different. Although, in both cases Deltaproteobacteria, mainly belonging to Syntrophobacterales (e.g. Syntrophobacter, Smithella or Syntrophus) and Clostridia, mostly Clostridiales, were among the most represented taxa, Gammaproteobacteria could be only identified in oil-degrading cultures. The proportion of Chloroflexi, exclusively belonging to Anaerolineales (e.g. Leptolinea, Bellilinea) was considerably higher in 2-methyl-naphthalene degrading cultures. Archaeal communities consisted almost exclusively of representatives of Methanomicrobia (mainly belonging to genera Methanosaeta and Methanoculleus). As both syntrophic Bacteria and methanogenic Archaea are abundant in Dagang, the studied areas of this oil field may have a significant potential to test the in situ conversion of oil into methane as a possible way to increase total hydrocarbon recovery.

  11. Reasons for production decline in the diatomite, Belridge oil field: a rock mechanics view

    SciTech Connect

    Strickland, F.G.

    1982-01-01

    This work summarized research conducted on diatomite cores from the Belridge oil field in Kern County. The study was undertaken to try to explain the rapid decline in oil production in diatomite wells. Characterization of the rock showed that the rock was composed principally of amorphous opaline silica diatoms with only a trace of crystoballite quartz or chert quartz. Physical properties tests showed the diatomite to be of low strength and plastic. Finally, it was established that long-term creep of diatomite into a propped fracture proceeds at a rate of approximately 6 x 10-5 in./day, a phenomenon which may be a primary cause of rapid production declines. The testing program also revealed a matrix stength for the formation of calculated 1325 PSI, a value to consider when depleting the reservoir. This also may help to explain the phase transformation of opal ct at calculated 2000 to 2500 ft depth.

  12. Sedimentation, zoning of reservoir rocks in W. Siberian basin oil fields

    SciTech Connect

    Kliger, J.A. )

    1994-02-07

    A line pattern of well cluster spacing was chosen in western Siberia because of taiga, marshes, etc., on the surface. The zoning of the oil pools within productive Upper Jurassic J[sub 3] intervals is complicated. This is why until the early 1990s almost each third well drilled in the Shaimsky region on the western edge of the West Siberian basin came up dry. The results of development drilling would be much better if one used some sedimentological relationships of zoning of the reservoir rocks within the oil fields. These natural phenomena are: Paleobasin bathymetry; Distances from the sources of the clastic material; and Proximity of the area of deposition. Using the diagram in this article, one can avoid drilling toward areas where the sandstone pinch out, area of argillization of sand-stones, or where the probability of their absence is high.

  13. Increased Oil Production and Reserves from Improved Completion Techniques in the Bluebell Field, Uinta Basin, Utah.

    SciTech Connect

    Morgan, C.D.

    1997-12-31

    The objective of this project is to increase oil production and reserves in the Uinta Basin by demonstrating improved completion techniques. Low productivity of Uinta Basin wells is caused by gross production intervals of several thousand feet that contain perforated thief zones, water-bearing zones, and unperforated oil-bearing intervals. Geologic and engineering characterization and computer simulation of the Green River and Wasatch Formations in the Bluebell field will determine reservoir heterogeneities related to fractures and depositional trends. This will be followed by drilling and recompletion of several wells to demonstrate improved completion techniques based on the reservoir characterization. Transfer of the project results will be an ongoing component of the project.

  14. How to make a billion-barrel oil field in offshore California commercial

    SciTech Connect

    Patterson, J.C.; Ballard, J.H.

    1988-01-01

    The major obstacles and challenges involved in exploration and development of a giant deep-water low-gravity oil field are exemplified in the undeveloped Sword field of offshore southern California. In 1979, Conoco Exploration identified a northeast-southwest-trending basement high in the 800 to 2,000-ft deep federal waters 12 mi southwest of Pt. Conception at the western end of the Santa Barbara Channel. The intended reservoir was fractured Miocene Monterey chert, silicic shales/siltstones,m and dolomites that are draped over the axially faulted structure. Drilling of the initial well in OCS P-0322 in 1982 resulted in discovering the giant Sword field. A confirmation well drilled in OCS P-0320 indicates in-place reserves of well over 1 billion bbl. while the discovered potential is significant, the low gravity (8.5/sup 0/-10.5/sup 0/ API) of the oils discovered to data, along with water depths in excess of 1,500 ft, currently pose economic challenges to successful field development.

  15. Spatial statistical analysis of basal stem root disease under natural field epidemic of oil palm

    NASA Astrophysics Data System (ADS)

    Kamu, Assis; Phin, Chong Khim; Seman, Idris Abu; Wan, Hoong Hak; Mun, Ho Chong

    2015-02-01

    Oil palm or scientifically known as Elaeis guineensis Jacq. is the most important commodity crop in Malaysia and has greatly contributed to the economy growth of the country. As far as disease is concerned in the industry, Basal Stem Rot (BSR) caused by Ganoderma boninence remains the most important disease. BSR disease is the most widely studied with information available for oil palm disease in Malaysia. However, there is still limited study on the spatial as well as temporal pattern or distribution of the disease especially under natural field epidemic condition in oil palm plantation. The objective of this study is to spatially identify the pattern of BSR disease under natural field epidemic using two geospatial analytical techniques, which are quadrat analysis for the first order properties of partial pattern analysis and nearest-neighbor analysis (NNA) for the second order properties of partial pattern analysis. Two study sites were selected with different age of tree. Both sites are located in Tawau, Sabah and managed by the same company. The results showed that at least one of the point pattern analysis used which is NNA (i.e. the second order properties of partial pattern analysis) has confirmed the disease is complete spatial randomness. This suggests the spread of the disease is not from tree to tree and the age of palm does not play a significance role in determining the spatial pattern of the disease. From the spatial pattern of the disease, it would help in the disease management program and for the industry in the future. The statistical modelling is expected to help in identifying the right model to estimate the yield loss of oil palm due to BSR disease in the future.

  16. Hydrocarbon-water interactions during brine migration: Evidence from hydrocarbon inclusions in calcite cements from Danish North Sea oil fields

    NASA Astrophysics Data System (ADS)

    Jensenius, Jørgen; Burruss, Robert C.

    1990-03-01

    Crude oils in primary and secondary fluid inclusions in calcite from fractures in seven offshore oil fields associated with diapiric salt structures in the Danish sector of the North Sea were analyzed by capillary column gas chromatography and compared with crude oils produced from the same reservoirs. Oils from fluid inclusions in all fields show evidence of biodegradation (decreased n- C17/pristane and n- C18/phytane ratios and loss of n-C 7, 2-methyl hexane, and 3-methyl hexane relative to methyl cyclohexane) and water washing (absence of benzene and depletion of toluene). Some oils in inclusions are extremely enriched in C 6 and C 7 cyclic alkanes suggesting that these samples contain hydrocarbons exsolved from ascending, hotter formation waters. Compared to inclusion oils the produced oils are less biodegraded, but are water washed, indicating that both types of oil interacted with large volumes of formation water. The carbon isotopic composition of the calcite host of the fluid inclusions in the Dagmar and Skjold fields is as light as -16.5%. PDB and the sulfur isotopic composition of pyrite in and adjacent to the calcite veins in the Skjold field is as light as -39.6%. CDT, indicating that biodegradation of the oils was a source of some of the carbon in the calcite and sulfate reduction was the source of sulfur for the pyrite. The evidence for microbial degradation of petroleum is consistent with present-day reservoir temperatures (65°-96°C) but is not consistent with previous estimates of the temperatures of calcite vein filling (95°-130°C) which are much higher than the temperatures of known occurrences of biodegraded oil.

  17. Hydrocarbon-water interactions during brine migration: Evidence from hydrocarbon inclusions in calcite cements from Danish North Sea oil fields

    USGS Publications Warehouse

    Jensenius, J.; Burruss, R.C.

    1990-01-01

    Crude oils in primary and secondary fluid inclusions in calcite from fractures in seven offshore oil fields associated with diapiric salt structures in the Danish sector of the North Sea were analyzed by capillary column gas chromatography and compared with crude oils produced from the same reservoirs. Oils from fluid inclusions in all fields show evidence of biodegradation (decreased n-C17/pristane and n-C18/phytane ratios and loss of n-C7, 2-methyl hexane, and 3-methyl hexane relative to methyl cyclohexane) and water washing (absence of benzene and depletion of toluene). Some oils in inclusions are extremely enriched in C6 and C7 cyclic alkanes suggesting that these samples contain hydrocarbons exsolved from ascending, hotter formation waters. Compared to inclusion oils the produced oils are less biodegraded, but are water washed, indicating that both types of oil interacted with large volumes of formation water. The carbon isotopic composition of the calcite host of the fluid inclusions in the Dagmar and Skjold fields is as light as -16.5%. PDB and the sulfur isotopic composition of pyrite in and adjacent to the calcite veins in the Skjold field is as light as -39.6%. CDT, indicating that biodegradation of the oils was a source of some of the carbon in the calcite and sulfate reduction was the source of sulfur for the pyrite. The evidence for microbial degradation of petroleum is consistent with present-day reservoir temperatures (65??-96??C) but is not consistent with previous estimates of the temperatures of calcite vein filling (95??-130??C) which are much higher than the temperatures of known occurrences of biodegraded oil. ?? 1990.

  18. Water rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China

    NASA Astrophysics Data System (ADS)

    Hui, Qian; Zhenghua, Yang; Yunfeng, Li; Wancai, Xu; Yaqiao, Sun

    2006-05-01

    In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na+, SiO2 and Cl-, as well as the increase of K+, Ca2+, Mg2+, SO{4/2-} and HCO{3/-}. Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO2. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water rock interaction is needed.

  19. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2000-12-06

    Through December 1999, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar (Tar II-A) Zone. Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood project. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone in order to focus the remaining time on using the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. Thermal-related formation compaction is a concern of the project team due to observed surface subsidence in the local area above the Tar II-A steamflood project. On January 12, 1999, the steamflood project lost its inexpensive steam source from the Harbor Cogeneration Plant as a result of the recent deregulation of electrical power rates in California. An operational plan was developed and implemented to mitigate the effects of the two situations by injecting cold water into the flanks of the steamflood. The purpose of flank injection has been to increase and subsequently maintain reservoir pressures at a level that would fill-up the steam chests in the ''T'' and ''D'' sands before they can collapse and cause formation compaction and to prevent the steam chests from reoccurring. A new 3-D deterministic thermal reservoir simulation model was used to provide operations with the necessary water injection rates and allowable production rates by well to minimize future surface subsidence and to accurately project reservoir steam chest fill-up by October 1999. A geomechanics study and a separate reservoir simulation study have been performed to determine the possible indicators of formation compaction, the temperatures at which specific indicators are affected and the projected temperature profiles in the over and underburden shales over a ten year period following steam injection. It was believed that once steam chest fill-up occurred, the reservoir would act more like a waterflood and production and cold water injection could be operated at lower Injection to production ratios (I/P) and net injection rates. In mid-September 1999, net water injection was reduced substantially in the ''D'' sands following steam chest fill-up. This caused reservoir pressures to plummet about 100 psi within six weeks. Starting in late-October 1999, net ''D'' sand injection was increased and reservoir pressures have slowly increased back to steam chest fill-up pressures as of the end of March 2000. When the ''T'' sands reached fill-up, net ''T'' sand injection was lowered only slightly and reservoir pressures stabilized. A more detailed discussion of the operational changes is in the Reservoir Management section of this report. A reservoir pressure monitoring program was developed as part of the poststeamflood reservoir management plan. This bi-monthly sonic fluid level program measures the static fluid levels in all idle wells an average of once a month. The fluid levels have been calibrated for liquid and gas density gradients by comparing a number of them with Amerada bomb pressures taken within a few days. This data allows engineering to respond quickly to rises or declines in reservoir pressure by either increasing injection or production or idling production. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current thermal operations in the Wilmington Field are economical with low oil prices due to the availability of inexpensive steam from an existing 50 MMBTU/hr steam generator that can utilize non-commercial low Btu produced gas. Such favorable terms for obtaining steam are not expected to be available in the future. Future expansion of thermal recovery to other parts of the Wilmington Field and other SBC reservoirs will depend on improving the efficiency and economics of heavy oil recovery, as is the intent of the project.

  20. Geology and habitat of oil in Ras Budran field, Gulf of Suez, Egypt

    SciTech Connect

    Chowdhary, L.R.; Taha, S.

    1987-05-01

    Deminex discovered the Ras Budran oil field in 1978. Discovery well EE 85-1 was drilled in about 140 ft of water, 4 km off the Sinai coast of the Gulf of Suez. Appraisal drilling (EE 85-2, 3, and 4 wells) confirmed the presence of a major field with an estimated 700 million bbl oil in place. The field, developed from three wellhead platforms, went on production in April 1983. To date, 20 development wells have been drilled. The Ras Budran structure at the deepest mappable seismic reflector, top Kareem (middle Miocene), is a broad northeast-southwest-trending anticlinal feature striking nearly at right angles to the main Gulf of Suez trend. At pre-Miocene producing horizons, the structure is complex and consists of a northeast-dipping flank (14-15) broken into several blocks by faults and limited to the south and west by major bounding faults. Oil is produced from three units of Nubian sandstone at a depth of 11,000 to 12,000 ft. The lower unit of Paleozoic age averages 10% porosity and up to 200 md in -situ permeability. The wells completed in this unit produce up to 2000 BOPD. In contrast, the sands of the upper two units of Lower Cretaceous age have a 15-20% porosity and up to 700 md permeability. The wells completed in these units produce 6000-8000 BOPD. The Ras Budran structure was primarily formed during the intra-Rudeis tectonic phase (lower Miocene). Migration of oil for accumulation in Ras Budran started late in the upper Miocene or Pliocene when the Santonian Brown Limestone and the Eocene Thebes Formation, the main source beds in the Gulf, reached the threshold of oil generation at a burial depth of about 10,000 ft (3000 m). At these depths, the organic matter in the source beds have a transformation ratio (0.10 to 0.15), increased yields of C15 + soluble organic matter and C15 + saturated hydrocarbons, a vitrinite reflectance of 0.62%, and a TTI value of 15.

  1. Integration of seismic methods with reservoir simulation, Pikes Peak heavy oil field, Saskatchewan

    NASA Astrophysics Data System (ADS)

    Zou, Ying

    The Pikes Peak heavy oil field has been operated by Husky Energy Ltd since 1981. Steam injection has been successfully employed to increase production. Efforts in geophysics and reservoir engineering have been made to improve interpretations in the mapping of reservoir conditions. This dissertation developed tools and a working flow for integrating the analysis of time-lapse seismic surveys with reservoir simulation, and applied them to the Pikes Peak field. Two time-lapse 2D seismic lines acquired in February 1991 and March 2000 in the eastern part of the field were carefully processed to produce wavelet and structure matched final sections. Reservoir simulation based on the field reservoir production history was carried out. It provided independent complementary information for the time-lapse seismic analysis. A rock physics procedure based on Gassmann's equation and Batzle and Wang's empirical relationship successfully linked the reservoir engineering to the seismic method. Based on the resultant seismic models, synthetic seismic sections were generated as the analogy of field seismic sections. The integrated interpretation for the Pikes Peak reservoir drew the following conclusions: The areas with a gas saturation difference, between two compared time steps, have seismic differences. Thicker gas zones correspond with large reflectivity changes on the top of the reservoir and larger traveltime delays in the seismic section. The thin gas zones only induce large reflectivity changes on the top of the reservoir, and do not have large time delays below the reservoir zone. High temperature regions also correlate with areas having large seismic energy differences. High temperature with thick gas (steam and methane) zones may be evidence for steam existence. The seismic differences at locations far from the production zone are due to the lower pressure that causes solution gas to evolve from the oil. Pressure changes propagate much faster (˜20 m in one month) than temperature changes (˜8 m in a year) based on the reservoir simulation results. The pressure dependence of the seismic data is due to its influences on gas saturation. The bypassed oil area and steam fronts (high temperature front) can be estimated from the temperature and oil saturation distributions from the reservoir simulation. AVO results show a steam and gas zone pattern similar to the one produced by reservoir simulation.

  2. Electrorheology of a zeolite/silicone oil suspension under dc fields

    NASA Astrophysics Data System (ADS)

    Tian, Yu; Meng, Yonggang; Wen, Shizhu

    2001-07-01

    The electrorheology of electrorheological (ER) fluids based on zeolite and silicone oil under dc fields was investigated at room temperature. ER fluids with volume fractions of 27% and 30% were prepared and tested. When a 5 kV/mm dc field was applied, shear yield stress of 26.7 kPa was obtained for the latter. The ER fluid with a higher volume fraction of zeolite had a higher current density and a higher shear yield stress under the same electric field. Compared with other ER fluids based on zeolite particles with low shear yield stress, the zeolite employed by us was found to have high dielectric constant and conductivity. The high permittivity mismatch and the high conductivity mismatch of the components of the fluids were considered responsible for the high shear yield stress.

  3. Potential biomarkers of crude oil exposure in the gastropod mollusc, Austrocochlea porcata: laboratory and manipulative field studies.

    PubMed

    Reid, D J; MacFarlane, G R

    2003-01-01

    Surveys conducted after a crude oil spill indicated that the intertidal gastropod mollusc Austrocochlea porcata may be highly sensitive to the pollutant, and therefore also valuable as a biomonitoring organism. Toxicity tests conducted in the laboratory and field established cause-effect for A. porcata mortalities on exposure to environmentally relevant concentrations of crude oil constituents. Glutathione antioxidant system components (glutathione and glutathione peroxidase, GPx) and oxidative damage (lipid peroxidation) in A. porcata were measured to determine whether any of these biochemical parameters showed potential as biomarkers of sublethal oil exposure. GPx was the most promising candidate for field-based biomarker studies after showing a dose-dependent induction to a crude oil water accommodated fraction (WAF) in laboratory assays. However, subsequent manipulative field experimentation indicated that the GPx response was not sufficiently sensitive and not necessarily predictive of population level effects when measured in situ. PMID:12927486

  4. Disposal of NORM-contaminated oil field wastes in salt caverns -- Legality, technical feasibility, economics, and risk

    SciTech Connect

    Veil, J.A.; Smith, K.P.; Tomasko, D.; Elcock, D.; Blunt, D.; Williams, G.P.

    1998-07-01

    Some types of oil and gas production and processing wastes contain naturally occurring radioactive materials (NORM). If NORM is present at concentrations above regulatory levels in oil field waste, the waste requires special disposal practices. The existing disposal options for wastes containing NORM are limited and costly. This paper evaluates the legality, technical feasibility, economics, and human health risk of disposing of NORM-contaminated oil field wastes in salt caverns. Cavern disposal of NORM waste is technically feasible and poses a very low human health risk. From a legal perspective, there are no fatal flaws that would prevent a state regulatory agency from approaching cavern disposal of NORM. On the basis of the costs charged by caverns currently used for disposal of nonhazardous oil field waste (NOW), NORM waste disposal caverns could be cost competitive with existing NORM waste disposal methods when regulatory agencies approve the practice.

  5. Chemical comparison and acute toxicity of water accommodated fraction (WAF) of source and field collected Macondo oils from the Deepwater Horizon spill.

    PubMed

    Faksness, Liv-Guri; Altin, Dag; Nordtug, Trond; Daling, Per S; Hansen, Bjørn Henrik

    2015-02-15

    Two Source oils and five field collected oil residues from the Deepwater Horizon incident were chemically characterized. Water accommodated fractions (WAFs) of the Source oils and two of the field-weathered oils were prepared to evaluate the impact of natural weathering on the chemical composition and the acute toxicity of the WAFs. Toxicity test species representing different tropic levels were used (the primary producer Skeletonema costatum (algae) and the herbivorous copepod Acartia tonsa). The results suggest that the potential for acute toxicity is higher in WAFs from non-weathered oils than WAFs from the field weathered oils. The Source oils contained a large fraction of soluble and bioavailable components (such as BTEX (benzene, toluene, ethyl benzene, xylenes) and naphthalene), whereas in the surface collected oils these components were depleted by dissolution into the water column as the oil rose to the surface and by evaporative loss after reaching the sea surface. PMID:25534626

  6. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2002-04-30

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through December 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. During the First Quarter 2002, the project team developed an accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project and began implementing the associated well work in March. The Tar V pilot steamflood project will be converted to post-steamflood cold water injection in April 2002. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. Most of the 2001 well work resulted in maintaining oil and gross fluid production and water injection rates. Reservoir pressures in the ''T'' and ''D'' sands are at 88% and 91% hydrostatic levels, respectively. Well work during the first quarter and plans for 2002 are described in the Reservoir Management section. The steamflood operation in the Tar V pilot project is mature and profitable. Recent production performance has been below projections because of wellbore mechanical limitations that have been addressed during this quarter. As the fluid production temperatures were beginning to exceed 350 F, our self-imposed temperature limit, the pilot steamflood was converted to a hot waterflood project in June 2001 and will be converted to cold water injection next quarter.

  7. Reservoir delineation by geophysical methods in the Suizhong 36-1 oil field, Bohai Gulf, China

    SciTech Connect

    Gustavson, J.B. ); Xin Shigang )

    1990-09-01

    The Suizhong 36-1 oil field was discovered in 1987 in the Bohai Gulf, Liandong Bay, People's Republic of China. Oligocene fluviodeltaic and lacustrine sandstones contain over 1 billion bbl of oil in place in a combination structural-stratigraphic trap. An international effort to delineate the reservoirs by geophysical methods was completed in June 1989. Three hundred and fifty km of seismic data was reprocessed and interpreted. Synthetic seismograms were used for correlation and for wavelet processing of the seismic data. Seismic and petrophysical analyses were done to relate the measurable seismic parameters to the subsurface rock and fluid parameters. An attempt was made to reprocess vertical seismic profile data to better relate seismic data to subsurface reservoir parameters. Unfortunately, incomplete field data and/or documentation made such an effort infeasible. Seismic data processing comprised conventional reprocessing, special processing primarily for hydrocarbon indicators, and three-dimensional velocity analysis. The reprocessing of the seismic data improved data quality over that of the original processing. Amplitude vs. offset processing revealed no obvious hydrocarbon indicators in the main reservoir zones. Velocity analysis produced a three-dimensional velocity field that was the key to the interpretation and engineering work that followed. Stratigraphic and structural interpretation was done on a GeoQuest computer workstation and iterated several times to obtain a consistent match with the wells. Seismic attribute generation and analysis were used primarily to reveal patterns associated with the depositional environments. The results suggest that accurate predictions of oil in place are possible with this methodology.

  8. Borehole gravity surveys in the Cretaceous-Tertiary Sagavanirktok Formation, Kuparuk River oil field, Alaska

    SciTech Connect

    Beyer, L.A. )

    1990-05-01

    Detailed borehole gravity surveys (sponsored by the US Department of Energy) were made in three wells in the Kuparuk River and westernmost Prudhoe Bay oil fields, Alaska from depths as shallow as 15 m to as great as 1,340 m through permafrost and underlying heavy oil bearing sandstones of the Sagavanirktok Formation. A subbituminous coal-bearing sequence and the stability field for methane hydrate occur partly within and partly below the permafrost zone, whose base, defined by the 0{degree}C isotherm, varies from 464 to 564 m. The surveys provided accurate, large-volume estimates of in-situ bulk density from which equivalent porosity was calculated using independent grain and pore-fluid density information. This density and porosity data helped to define the rock mass properties within the hydrate stability field and the thermal conductivity, seismic character, and compaction history of the permafrost. Bulk density of the unconsolidated to poorly consolidated sections ranges mostly from 1.9 to 2.3 g/cm{sup 3}. The shallow permafrost section appears to be slightly overcompacted in comparison to similar sedimentary sequences in nonpermafrost regions. The cause of this apparent overcompaction is unknown but may be due to freeze-thaw processes that have similarly affected sea floor and surficial deposits elsewhere in the Arctic. Fluctuations of bulk density appear to be controlled principally by (1) textural variations of the sediments, possibly exaggerated locally within the permafrost zone by excess ice, (2) presence or absence of carbonaceous material, and (3) type of pore-fluid (water-ice vs. water vs. hydrocarbons). As hypothetical models predict bulk-density is slightly lower opposite one interval of possible methane hydrate. Porosity may be as high as 40-45% for selected coarser grained units within the permafrost zone, and as high as 30-35% in a series of well sorted, heavy oil-bearing sandstones.

  9. Production optimization of sucker rod pumping wells producing viscous oil in Boscan field, Venezuela

    SciTech Connect

    Guirados, C.; Sandoval, J.; Rivas, O.; Troconis, H.

    1995-12-31

    Boscan field is located in the western coast of Maracaibo lake and is operated by Maraven S.A., affiliate of Petroleos de Venezuela S.A. It has 315 active wells, 252 of which are produced with sucker rod pumping. Other artificial lift methods currently applied in this field are hydraulic (piston) pumping (39 wells) and ESP (24 wells). This paper presents the results of the production optimization of two sucker rod pumping wells of Boscan field producing viscous oil. This optimization has been possible due to the development of a new production scheme and the application of system analysis in completion design. The new production scheme involves the utilization of a subsurface stuffing box assembly and a slotted housing, both designed and patented by Intevep S.A., affiliate of Petroleos de Venezuela S.A. The completion design method and software used in the optimization study were also developed by Intevep S.A. The new production scheme and design method proved to be effective in preventing the causes of the above mentioned problems, allowing the increase of oil production under better operating conditions.

  10. Development programs call for two concrete platforms in oil, gas fields off Norway

    SciTech Connect

    Not Available

    1991-12-23

    This paper reports on development plans for two fields off Norway that have given a boost to use of concrete for the construction of floating production facilities. Conoco Norway Inc. let a $350 million contract for construction of the world's first concrete hull, tension leg platform (TLP) to Norwegian Contractors, Stavanger. As part of a $3.5 billion project, it will be installed in the Conoco group's Heidrun oil and gas field in the Haltenbanken area of the Norwegian Sea off mid-Norway. In addition, a group led by Norsk Hydro Produksjon AS, Oslo, chose a concrete floating production platform as the basis for a $2.42 billion development of the oil province in Troll gas field in the North SEa. Also in the Norwegian North Sea, companies involved in the Sleipner gas development project agreed to seek approval for the $1.77 billion, first phase development phase of West Sleipner reserves beginning in 1996. This will use conventional production technology, although the possibility of a concrete treatment platform has not been ruled out.

  11. Gas injection may have triggered earthquakes in the Cogdell oil field, Texas.

    PubMed

    Gan, Wei; Frohlich, Cliff

    2013-11-19

    Between 1957 and 1982, water flooding was conducted to improve petroleum production in the Cogdell oil field north of Snyder, TX, and a contemporary analysis concluded this induced earthquakes that occurred between 1975 and 1982. The National Earthquake Information Center detected no further activity between 1983 and 2005, but between 2006 and 2011 reported 18 earthquakes having magnitudes 3 and greater. To investigate these earthquakes, we analyzed data recorded by six temporary seismograph stations deployed by the USArray program, and identified 93 well-recorded earthquakes occurring between March 2009 and December 2010. Relocation with a double-difference method shows that most earthquakes occurred within several northeast-southwest-trending linear clusters, with trends corresponding to nodal planes of regional focal mechanisms, possibly indicating the presence of previously unidentified faults. We have evaluated data concerning injection and extraction of oil, water, and gas in the Cogdell field. Water injection cannot explain the 2006-2011 earthquakes, especially as net volumes (injection minus extraction) are significantly less than in the 1957-1982 period. However, since 2004 significant volumes of gases including supercritical CO2 have been injected into the Cogdell field. The timing of gas injection suggests it may have contributed to triggering the recent seismic activity. If so, this represents an instance where gas injection has triggered earthquakes having magnitudes 3 and larger. Further modeling studies may help evaluate recent assertions suggesting significant risks accompany large-scale carbon capture and storage as a strategy for managing climate change. PMID:24191019

  12. Gas injection may have triggered earthquakes in the Cogdell oil field, Texas

    PubMed Central

    Gan, Wei; Frohlich, Cliff

    2013-01-01

    Between 1957 and 1982, water flooding was conducted to improve petroleum production in the Cogdell oil field north of Snyder, TX, and a contemporary analysis concluded this induced earthquakes that occurred between 1975 and 1982. The National Earthquake Information Center detected no further activity between 1983 and 2005, but between 2006 and 2011 reported 18 earthquakes having magnitudes 3 and greater. To investigate these earthquakes, we analyzed data recorded by six temporary seismograph stations deployed by the USArray program, and identified 93 well-recorded earthquakes occurring between March 2009 and December 2010. Relocation with a double-difference method shows that most earthquakes occurred within several northeast–southwest-trending linear clusters, with trends corresponding to nodal planes of regional focal mechanisms, possibly indicating the presence of previously unidentified faults. We have evaluated data concerning injection and extraction of oil, water, and gas in the Cogdell field. Water injection cannot explain the 2006–2011 earthquakes, especially as net volumes (injection minus extraction) are significantly less than in the 1957–1982 period. However, since 2004 significant volumes of gases including supercritical CO2 have been injected into the Cogdell field. The timing of gas injection suggests it may have contributed to triggering the recent seismic activity. If so, this represents an instance where gas injection has triggered earthquakes having magnitudes 3 and larger. Further modeling studies may help evaluate recent assertions suggesting significant risks accompany large-scale carbon capture and storage as a strategy for managing climate change. PMID:24191019

  13. Microbial Oxidation of Natural Gas in a Plume Emanating from the Coal Oil Point Seep Field

    NASA Astrophysics Data System (ADS)

    Mendes, S. D.; Valentine, D. L.; Perez, C.; Scarlett, R.

    2012-12-01

    The hydrocarbon seep field at Coal Oil Point, off the coast of Santa Barbara, California, releases > 1010 g of thermogenic natural gas each year. Gases emitted from Coal Oil Point include methane, ethane, propane, and butane, which are atmospheric pollutants and greenhouse gases. Even though the seeps are at water depths of only 5-80 m, much of the gas dissolves and contributes to a plume that is transported by ocean currents. While hydrocarbons can support bacterial respiration, resulting in the removal of hydrocarbon gas from the plume, the time-scale for the bacterial respiratory response is unconstrained. To track hydrocarbon respiration 3H-ethane, propane, and butane were synthesized using Grignard reagents and tritiated water with yields of >70% and applied as tracers to samples up- and down-current from the seeps at Coal Oil Point. Validation experiments conducted in September 2011 aboard the R/V Atlantis show that 3H-labeled tracers are an order of magnitude more sensitive than previous methods using stable carbon isotopes (Valentine et. al 2010), making this technique preferable in natural systems. Application of the tracers concurrent with plume tracking in July-August 2012 show ethane, propane, and butane consumption are readily inducible on a timescale of days.

  14. Uncovering Influences on the Form of Oil and Gas Field Size Distributions

    SciTech Connect

    Schuenemeyer, John H. Drew, Lawrence J.

    1999-03-15

    A detailed understanding of the processes that led to empirical oil and gas field size distributions, especially the dynamic character of the discovery process, is needed to improve the quality of forecasts of oil and gas resources. An empirical distribution results from a complex interaction of economic, technical, and social factors with geology in the form of a distribution of deposits. These factors may cause an empirical distribution to mutate nonrandomly through time. Changes in the price of oil, the cost of exploration and development, technology, and access to prospects influence the discovery process. Failure to recognize and account for them in the modeling process can result in serious bias in estimates of the number and volume of future discoveries. In addition, the broad range of some forecasts for a given region may be explained by differences in perspective of those involved in the process. Geologists who understand the basic processes and collect the data may be scientific determinists. Statisticians who model and analyze the data are trained to think in terms of random variables and stochastic processes.

  15. Gas, Water, and Oil Production from the Wasatch Formation, Greater Natural Buttes Field, Uinta Basin, Utah

    USGS Publications Warehouse

    Nelson, Philip H.; Hoffman, Eric L.

    2009-01-01

    Gas, oil, and water production data were compiled from 38 wells with production commencing during the 1980s from the Wasatch Formation in the Greater Natural Buttes field, Uinta Basin, Utah. This study is one of a series of reports examining fluid production from tight gas reservoirs, which are characterized by low permeability, low porosity, and the presence of clay minerals in pore space. The general ranges of production rates after 2 years are 100-1,000 mscf/day for gas, 0.35-3.4 barrel per day for oil, and less than 1 barrel per day for water. The water:gas ratio ranges from 0.1 to10 barrel per million standard cubic feet, indicating that free water is produced along with water dissolved in gas in the reservoir. The oil:gas ratios are typical of a wet gas system. Neither gas nor water rates show dependence upon the number of perforations, although for low gas-flow rates there is some dependence upon the number of sandstone intervals that were perforated. Over a 5-year time span, gas and water may either increase or decrease in a given well, but the changes in production rate do not exhibit any dependence upon well proximity or well location.

  16. Interpreting Reservoir Microseismicity Detected During CO2 Injection at the Aneth Oil Field

    NASA Astrophysics Data System (ADS)

    Rutledge, J. T.

    2009-12-01

    Microseismic monitoring is expected to be a useful tool in CO2 sequestration projects for mapping pressure fronts and detecting fault activation and potential leakage paths. Downhole microseismic monitoring and several other techniques are being tested for their efficacy in tracking movement and containment of CO2 injected at the Aneth oil field located in San Juan County, Utah. The Southwest Regional Partnership on CO2 Sequestration is conducting the monitoring activities in collaboration with Resolute Natural Resources Company, under the support of the U.S. Department of Energy’s National Energy Technology Laboratory. The CO2 injection at Aneth is associated with a field-wide enhanced oil recovery operation following decades of pressure maintenance and oil recovery by water-flood injection. A 60-level geophone string was cemented into a monitoring well equipped with both 3-component and vertical component geophones spanning from 800 to 1700 m depth. The top of the oil reservoir in the study area is at approximately 1730 m depth. Over the first year of monitoring, approximately 3800 microearthquakes have been detected within about 3 km of the geophone string. The Aneth reservoir events are relatively large with magnitudes ranging from approximately -1 to 1. For comparison, reservoir seismicity induced during hydraulic fracturing treatments typically result in events with magnitudes <-1, unless pre-existing faults are pressurized by the treatments. The Aneth events delineate two NW-SE oriented fracture zones located on opposite flanks of the reservoir. Injection activity is fairly uniform over the entire field area, and the microseismicity does not correlate either temporally or spatially with any anomalous changes in injection or production activities near the source locations. Because the activity is fairly isolated and relatively energetic, I speculate that the seismicity may be due to critically stressed structures driven by longer-term production- and/or injection-induced stress changes. Ongoing analysis includes extracting precise arrival time to improve relative source locations and looking for correlations of event occurrence and moment release with field-wide rates of injection and production.

  17. Applying the Aramid Joined v-belt high torque, low speed oil field pumping units

    SciTech Connect

    Stork, D.; Watson, J.

    1982-11-01

    This paper discusses the successful application of Aramid fiber-reinforced Torque Team Plus Joined Vbelts to low speed; (8-20 rpm) high torque, up to (320,000 in-lb); 100% belt driven oil field pumping units. Also discussed is a comparison in operating efficiency over gear or chain units, reduced initial expense, and lower overall maintenance effort. The Aramid reinforced Joined V-belts were applied to a double reduction drive (68-142:1 ratio) eliminating gear or chain reducers. Pumping units range in size from 57,000 in-lb to 320,000 in-lb.

  18. Integration of geological, geochemical, and geophysical spatial data of the Cement oil field, Oklahoma, test site

    USGS Publications Warehouse

    Termain, Patricia A.; Donovan, Terrence J.; Chavez, Pat S.

    1980-01-01

    Measurement pertaining to geology, geochemistry, and geophysics of the Cement oil field, Oklahoma, test site were collected employing both airborne sensors and ground-based data collection. The measurements include: (1) airborne gamma-ray spectrometry (supplying bismuth 214, thalium 208, and potassium 40 gamma-ray intensities); (2) aeromagnetic survey data; (3) multi-frequency airborne resistivity survey data (supplying apparent electrical resistivity of near surface materials); (4) gravity data; (5) geological and topographic maps; and (6) image data from Landsat MSS and U-2 photography.

  19. Notes on the uwainat oil rim development, Maydan Mahzam and Bul Hanine Fields, offshore Qatar

    SciTech Connect

    Hamam, K.A.

    1985-03-01

    As a result of reservoir simulation studies of the Uwainat reservoirs (Maydan Mahzam and Bul Hanine Fields), drilling to the Uwainat oil rim target became very ''tight'' with a very limited vertical tolerance. To achieve drilling to the tight target requires a precise position of the well at the top of the Lower Arab IV reservoir (a reliable marker) and an accurate isochore of the Lower Arab IV - Uwainat. The discussion shows that the level of accuracy needed in determining both the actual subsea well position and in constructing the depth contours of the reservoirs is extremely high.

  20. Investigation of ginkgo biloba leave extracts as corrosion and Oil field microorganism inhibitors.

    PubMed

    Chen, Gang; Zhang, Min; Zhao, Jingrui; Zhou, Rui; Meng, Zuchao; Zhang, Jie

    2013-01-01

    Ginkgo biloba (Ginkgoaceae), originating from China, now distributes all over the world. Wide application of Ginkgo biloba extracts is determined by the main active substances, flavonoids and terpenoids, which indicates its extracts suitable to be used as an effective corrosion inhibitor. The extracts of Ginkgo biloba leave have been investigated on the corrosion inhibition of Q235A steel with weight loss and potentiodynamic polarisation techniques. The inhibition efficiency of the extracts varies with extract concentration. The extracts inhibit corrosion mainly by adsorption mechanism. Potentiodynamic polarisation studies show that extracts are mixed type inhibitors. The antibacterial activity of the extracts against oil field microorganism (SRB, IB and TGB) was also investigated. PMID:23651921

  1. Investigation of ginkgo biloba leave extracts as corrosion and Oil field microorganism inhibitors

    PubMed Central

    2013-01-01

    Ginkgo biloba (Ginkgoaceae), originating from China, now distributes all over the world. Wide application of Ginkgo biloba extracts is determined by the main active substances, flavonoids and terpenoids, which indicates its extracts suitable to be used as an effective corrosion inhibitor. The extracts of Ginkgo biloba leave have been investigated on the corrosion inhibition of Q235A steel with weight loss and potentiodynamic polarisation techniques. The inhibition efficiency of the extracts varies with extract concentration. The extracts inhibit corrosion mainly by adsorption mechanism. Potentiodynamic polarisation studies show that extracts are mixed type inhibitors. The antibacterial activity of the extracts against oil field microorganism (SRB, IB and TGB) was also investigated. PMID:23651921

  2. Bacterial Community Features Are Shaped by Geographic Location, Physicochemical Properties, and Oil Contamination of Soil in Main Oil Fields of China.

    PubMed

    Liao, Jingqiu; Wang, Jie; Huang, Yi

    2015-08-01

    Geographic location and physicochemical properties are thought to represent major factors that shape soil bacterial community abundance and diversity. Crude oil contamination is becoming a notable concern with respect to soil property variation; however, the quantifiable influences of geographic location, physicochemical properties, and oil contamination are still poorly understood. In this study, the 16S ribosomal RNA genes of bacteria in the four oil fields in China were analyzed by using pyrosequencing. Results showed that physicochemical properties were the most dominant factor of bacterial community distribution, followed by geographical location. Oil contamination was a driving factor whose indirect influence was stronger than its direct influence. Under the impact of these three factors, different oil fields presented diversified and distinguishable bacterial community features. The soil of sites with the highest total petroleum hydrocarbon content (HB), nitrogen content (DQ), and phosphorus content (XJ) contained the largest proportion of functional groups participating in hydrocarbon degradation, nitrogen turnover, and phosphorus turnover, respectively. The first dominant phylum of the site with loam soil texture (HB) was Actinobacteria instead of Proteobacteria in other sites with sandy or sandy loam soil texture (DQ, SL, XJ). The site with the highest salinization and alkalization (SL) exhibited the largest proportion of unique local bacteria. The site that was located in the desert with extremely low precipitation (XJ) had the most diversified bacteria distribution. The bacterial community diversity was strongly influenced by soil physicochemical properties. PMID:25676171

  3. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2000-12-06

    Through March 2000, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar (Tar II-A) Zone. Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood project. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone so the project team could use the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. The project team spent the second quarter 2000 writing the 1997-2000 Annual Report, completing research for the project on the subjects mentioned above, and operating the Tar II-A post-steamflood project and the Tar V horizontal well steamflood pilot. Thermal-related formation compaction is a concern of the project team due to observed surface subsidence in the local area above the Tar II-A steamflood project. On January 12, 1999, the steamflood project lost its inexpensive steam source from the Harbor Cogeneration Plant as a result of the recent deregulation of electrical power rates in California. An operational plan was developed and implemented to mitigate the effects of the two situations by injecting cold water into the flanks of the steamflood. The purpose of flank injection has been to increase and subsequently maintain reservoir pressures at a level that would fill-up the steam chests in the ''T'' and ''D'' sands before they can collapse and cause formation compaction and to prevent the steam chests from reoccurring. A new 3-D deterministic thermal reservoir simulation model was used to provide operations with the necessary water injection rates and allowable production rates by well to minimize future surface subsidence and to accurately project reservoir steam chest fill-up by October 1999. A geomechanics study and a separate reservoir simulation study have been performed to determine the possible indicators of formation compaction, the temperatures at which specific indicators are affected and the projected temperature profiles in the over and underburden shales over a ten year period following steam injection. Further geomechanics work should be conducted. It was believed that once steam chest fill-up occurred, the reservoir would act more like a waterflood and production and cold water injection could be operated at lower Injection to production ratios (I/P) and net injection rates. In mid-September 1999, net water injection was reduced substantially in the ''D'' sands following steam chest fill-up. This caused reservoir pressures to plummet about 100 psi within six weeks. Starting in late-October 1999, net ''D'' sand injection was increased and reservoir pressures have slowly increased back to steam chest fill-up pressures as of the end of March 2000. When the ''T'' sands reached fill-up, net ''T'' sand injection remained at a high rate and reservoir pressures stabilized. A more detailed discussion of the operational changes is in the Reservoir Management section of this report. A reservoir pressure monitoring program was developed as part of the poststeamflood reservoir management plan. This bi-monthly sonic fluid level program measures the static fluid levels in all idle wells an average of once a month. The fluid levels have been calibrated for liquid and gas density gradients by comparing a number of them with Amerada bomb pressures taken within a few days. This data allows engineering to respond quickly to rises or declines in reservoir pressure by either increasing injection or production or idling production. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current thermal operations in the Wilmington Field are economical with low oil prices due to the availability of inexpensive steam from an existing 50 MMBTU/hr steam generator that can utilize non-commercial low Btu produced gas. Such favorable terms for obtaining steam are not expected to be available in the future.

  4. A surface vitrinite reflectance anomaly related to Bell Creek oil field, Montana, U.S.A.

    USGS Publications Warehouse

    Barker, C.E.; Dalziel, M.C.; Pawlewicz, M.J.

    1983-01-01

    Vitrinite reflectance measurements from surface samples of mudrock and coal show anomalously high values over the Bell Creek oil field. The average vitrinite reflectance (Rm) increases to a maximum of 0.9 percent over the field against background values of about 0.3 percent. The Rm anomaly coincides with a geochemical anomaly indicated by diagenetic magnetite in surface rocks and a geobiologic anomaly indicated by ethane-consuming bacteria. These samples were taken from the Upper Cretaceous Hell Creek and Paleocene Fort Union Formations which form an essentially conformable sequence. The depositional environment is similar in both formations, and we expect little variation in the source and composition of the organic matter. The surface R m should be approximately constant because of a uniform thermal history across the field. Temperature studies over local oil fields with similar geology suggest the expected thermal anomaly would be less than 10?C (50?F), which is too small to account for the significantly higher rank over the field. Coal clinkers are rare in the vicinity of Bell Creek and an Rm anomaly caused by burning of the thin, discontinuous coal seams is unlikely. The limited topographic relief, less than 305 m (1,000 ft), over the shallow-dipping homoclinal structure and the poor correlation between Rm and sample locality elevation (r = -0.2) indicate that the Rm anomaly is not due to burial, deformation and subsequent erosion. We conjecture that activity by petroleum-metabolizing bacteria is a possible explanation of the Rm anomaly. Microseepage from oil reservoirs supports large colonies of these organisms, some of which can produce enzymes that can cleave hydrocarbon side-chains on the kerogen molecule. The loss of these side chains causes condensation of the ring structures (Stach and others, 1982) and consequently increases its reflectance. These data indicate that vitrinite reflectance may be a useful tool to explore for stratigraphic traps in the Powder River Basin. Further, the large variation of R across the Bell Creek area suggests that vitrinite reflectance data from surface samples should be interpreted with caution.

  5. Characteristics of oil field emissions in the vicinity of Tulsa, Oklahoma

    SciTech Connect

    Viswanath, R.S.

    1994-08-01

    In 1988 a study was undertaken in the vicinity of Tulsa, Oklahoma to determine the characteristics, composition, and relative concentrations of the oil field emissions of volatile organic compounds (VOC). Forty grab samples (10-minute) using stainless steel canisters were collected from five different stages of crude oil production over an 80-day period (August-October). The samples were analyzed at the Tulsa City-County Health Department`s laboratory, using cryogenic preconcentration, gas chromatographic separation, and flame ionization detection. The six prevalent components of the field emissions were ethane, propane, 2-methylpropane, n-butane, 2-methylbutane, and n-pentane with propane predominating. The composition is unique with higher amounts of propane than ethane and is different from natural gas which has more abundant ethane. Decreases occurred in the amounts of light compounds, namely, ethane and propane from well heads through refinery tanks. The bulk of these losses appeared to be at the well heads and gathering tanks. 10 refs., 7 tabs.

  6. Water-in-oil emulsification in a non-uniform alternating electric field

    NASA Astrophysics Data System (ADS)

    Choi, Suhwan; Saveliev, Alexei

    2015-11-01

    The emulsification of a water microdroplet placed in castor oil was performed using a non-uniform alternating electric field formed in the pin-to-plate geometry. A non-uniform electric field of ~40 kV/mm alternating with a frequency of 6.7 kHz was generated near the pin electrode. The applied frequency exceeded charge relaxation frequency of castor oil (0.3 Hz) and was below charge relaxation frequency of deionized water (7.8 kHz) used in the experiments. The emulsification process was captured with a CCD camera. The emulsification process started with entrainment of the water droplet in the high electric filed region near the pin electrode under the dielectrophoretic force. Upon touching the pin, the microdroplet was disintegrated in numerous channels and secondary droplets. The process continued by entrainment of secondary droplets and continuous size reduction. Three droplet breakup mechanisms were identified: drop elongation and capillary breakup, ac electrospraying of individual droplets, chain and bridge formation and decay. The quasi-steady narrow size distribution of emulsified water droplets with diameters close to 1 μm was formed after a few minutes. The generated emulsion was confined near the needle electrode due to the dielectrophoretic force. The emulsion had a well-defined boundary with a shape resembling a pendant drop suspended on the pin electrode.

  7. Magnetic forward models of Cement oil field, Oklahoma, based on rock magnetic, geochemical, and petrologic constraints

    USGS Publications Warehouse

    Reynolds, R.L.; Webring, M.; Grauch, V.J.S.; Tuttle, M.

    1990-01-01

    Magnetic forward models of the Cement oil field, Oklahoma, were generated to assess the possibility that ferrimagnetic pyrrhotite related to hydrocarbon seepage in the upper 1 km of Permian strata contributes to aeromagnetic anomalies at Cement. Six bodies having different magnetizations were constructed for the magnetic models. Total magnetizations of the bodies of highest pyrrhotite content range from about 3 ?? 10-3 to 56 ?? 10-3 A/m in the present field direction and yield magnetic anomalies (at 120 m altitude) having amplitudes of less than 1 nT to ~6 to 7 nT, respectively. Numerous assumptions were made in the generation of the models, but nevertheless, the results suggest that pyrrhotite, formed via hydrocarbon reactions and within a range of concentrations estimated at Cement, is capable of causing magnetic anomalies. -from Authors

  8. 3-D reservoir characterization of the House Creek oil field, Powder River Basin, Wyoming

    USGS Publications Warehouse

    Higley, Debra K.; Pantea, Michael P.; Slatt, Roger M.

    1997-01-01

    This CD-ROM is intended to serve a broad audience. An important purpose is to explain geologic and geochemical factors that control petroleum production from the House Creek Field. This information may serve as an analog for other marine-ridge sandstone reservoirs. The 3-D slide and movie images are tied to explanations and 2-D geologic and geochemical images to visualize geologic structures in three dimensions, explain the geologic significance of porosity/permeability distribution across the sandstone bodies, and tie this to petroleum production characteristics in the oil field. Movies, text, images including scanning electron photomicrographs (SEM), thin-section photomicrographs, and data files can be copied from the CD-ROM for use in external mapping, statistical, and other applications.

  9. Analysis of gravity anomaly over coral-reef oil field: Wilfred Pool, Sullivan County, Indiana

    SciTech Connect

    Dana, S.W.

    1980-03-01

    To compare the measured and theoretical gravity anomaly of a typical coral-reef oil field, data were collected from the wilfred Pool, Sullivan County, Indiana. Densities of available core samples from the field were determined and the anomaly was calculated, taking into account the lateral and vertical variation of density and the geologic structure known from core studies and drilling-log records of lithologic types penetrated by the wells. Comparison of the theoretical and actual anomalies indicated a rough correspondence except for several sharp negative anomalies on the flanks of the measured gravity anomaly. Further studies indicated that the negative anomalies are possibly due to fluvial erosion that produced, on the surface of the youngest Pennsylvanian sediments, channels which were later filled with glacial till of lower density than the sediments. 13 figures.

  10. Oil-material fractionation in Gulf deep water horizontal intrusion layer: Field data analysis with chemodynamic fate model for Macondo 252 oil spill.

    PubMed

    Melvin, A T; Thibodeaux, L J; Parsons, A R; Overton, E; Valsaraj, K T; Nandakumar, K

    2016-04-15

    Among the discoveries of the Deepwater Horizon blowout was the so-called "sub-surface plume"; herein termed the "oil-trapping layer". Hydrocarbons were found positioned at ~1100-1300m with thickness ~100-150m and moving horizontally to the SW in a vertically stratified layer at the junction of the cold abyssal water and the permanent thermocline. This study focuses on its formation process and fate of the hydrocarbons within. The originality of this work to the field is two-fold, first it provides a conceptual framework which places layer origin in the context of a horizontal "intrusion" from the near-field, vertical, blow-out plume and second, it offers a theoretical model for the hydrocarbon chemicals within the horizontal layer as it moves far-afield. The model quantifies the oil-material fractionation process for the soluble and fine particle. The classical Box model, retrofitted with an internal gradient, the "G-Box", allows an approach that includes turbulent eddy diffusion coupled with droplet rise velocity and reactive decay to produce a simple, explicit, transparent, algebraic model with few parameters for the fate of the individual fractions. Computations show the soluble and smallest liquid droplets moving very slowly vertically through the layer appearing within the trapping layer at low concentration with high persistence. The larger droplets move-through this trapping zone quickly, attain high concentrations, and eventually form the sea surface slick. It impacts the field of oil spill engineering science by providing the conceptual idea and the algorithms for projecting the quantities and fractions of oil-material in a deep water, horizontal marine current being dispersed and moving far afield. In the field of oil spill modeling this work extends the current generation near-field plume source models to the far-field. The theory portrays the layer as an efficient oil-material trap. The model-forecasted concentration profiles for alkanes and aromatics against the available field data support the proposed theory and the resulting model. PMID:26947926

  11. Chemical Characterization of Brines from Selected Oil Fields, Tabasco, México

    NASA Astrophysics Data System (ADS)

    Méndez-Ortiz, B.; Carrillo-Chavez, A.; Tritlla, J.; Levresse, G.; Gonzalez-Partida, E.; Oviedo-Perez, A.; Martinez-Kepm, H.; Gonzalez-Posadas, F.; Clara-Valdes, L.

    2004-12-01

    Thirteen brine samples were recovered from nine oil-producing wells in the Agave (Cretaceous) and Saramako (Cretaceous and Tertiary) oil fields. These samples were analyzed for major and trace elements as well as O and D isotopic compositions. The goal of this study was to compare the possible links between oil-related brines enclosed within Cretaceous and Tertiary productive horizons that were thought to have similar origin oils. The salinity of the Saramako Cretaceous and Tertiary horizons is very constant, around 30000 ppm, one to six times lower than the salinities found in the Agave Cretaceous Field (from 45000 to 170000 ppm). Major ion chemistry suggests that brines are in equilibrium with the host rock. One of the main difference, besides Mg, resides in the S concentrations, were Agave samples present lower concentrations, probably related to the presence of abundant sulfides in the aquifer's rock. Halogen (Br, Cl) systematics indicates a different origin for the Saramako and Agave brines. The Saramako samples halogen composition plot near normal seawater both in the Na/Cl vs Cl/Br (molar ratios) and the Cl vs Br (ppm) plots. The Agave halogen data scatter near and underneath the seawater evaporation line in the Na/Cl vs Cl/Br (molar ratios), suggesting that these fluids could represent seawater evolved past the point of halite precipitation. The Cl vs Br (ppm) plot indicates that these fluids undergone some degree of mixing with low-salinity fluids, probably seawater. The presence of two different groups of data suggests the compartment of the aquifer. The \\deltaD and \\delta18O data show strong differences between the Saramako and Agave brines. The Saramako brine \\delta18O and \\deltaD isotopic compositions are +2.1% (VSMOW) and -13.8% respectively. The Agave samples have a \\delta18O composition from +4.3% to +6.0% and \\deltaD isotopic composition from -20.0% to -12.6%. Differences in \\delta18O compositions between Saramako and Agave brines indicate that the latter fluids were in equilibrium with the host dolostones at certain temperature. Saramako brine composition indicates a near-pristine seawater origin. Agave brines chemical composition suggests an origin related with a bittern formed after evaporation of seawater past the point of halite precipitation, subsequently mixed with seawater. Oxygen isotopic compositions reflect both different host rock and water to rock interaction phenomena, whereas hydrogen isotopic composition can be modified by diagenetic reactions.

  12. Did CO2 injection induce 2006-2011 earthquakes in the Cogdell oil field, Texas?

    NASA Astrophysics Data System (ADS)

    GAN, W.; Frohlich, C.

    2013-12-01

    Induced seismicity related to underground injection of liquids has been widely reported. However, earthquakes triggered by gas injection, particularly having magnitudes M3 and larger, haven't been observed. Davis and Pennington (1) concluded that earthquakes occurring 1974-1982 in the Cogdell oil field north of Snyder, TX were induced by water flooding for secondary recovery that took place between 1956 and 1982. Subsequently the National Earthquake Information Center (NEIC) reported no further seismicity between 1983 and 2005, but between 2006 and 2011 reported 18 earthquakes having magnitudes 3 and greater. In the present study we analyzed data recorded by six temporary seismograph stations deployed by the USArray program. We identified and carefully relocated 93 well-recorded earthquakes occurring between March 2009 and December 2010. Relocated epicenters occur within several NE-SW-trending linear clusters, with trends corresponding to nodal planes of regional focal mechanisms, possibly indicating the presence of previously unidentified subsurface faults. Moreover, both the rate and b value for the 2009-2011 activity differs from the values for earlier activity, possibly suggesting a different physical origin. We have evaluated data concerning injection and extraction of oil, water, and gas in the Cogdell field. Fluid injection doesn't explain the 2006-2011 earthquakes, especially as net volumes (injection minus extraction) are significantly less than in the 1957-1982 period, and don't appear to have undergone significant recent changes. However, since 2004 significant volumes of CO2 have been injected into the Cogdell fields. The timing of gas injection suggests it may have triggered the recent seismic activity. If so, this is the first reported instance where gas injection has triggered earthquakes having magnitudes M3 and larger. Further analysis may help to evaluate recent concerns about possible risks associated with large-scale carbon capture and storage as a strategy for managing climate change. 1. Davis SD, Pennington WD (1989) Induced seismic deformation in the Cogdell oil field of west Texas. Bull Seismol Soc Amer 79:1477-1495.

  13. Additional Reserve Recovery Using New Polymer Treatment on High Water Oil Ratio Wells in Alameda Field, Kingman County, Kansas

    SciTech Connect

    James Spillane

    2005-10-01

    The Chemical Flooding process, like a polymer treatment, as a tertiary (enhanced) oil recovery process can be a very good solution based on the condition of this field and its low cost compared to the drilling of new wells. It is an improved water flooding method in which high molecular-weight (macro-size molecules) and water-soluble polymers are added to the injection water to improve the mobility ratio by enhancing the viscosity of the water and by reducing permeability in invaded zones during the process. In other words, it can improve the sweep efficiency by reducing the water mobility. This polymer treatment can be performed on the same active oil producer well rather than on an injector well in the existence of strong water drive in the formation. Some parameters must be considered before any polymer job is performed such as: formation temperature, permeability, oil gravity and viscosity, location and formation thickness of the well, amount of remaining recoverable oil, fluid levels, well productivity, water oil ratio (WOR) and existence of water drive. This improved oil recovery technique has been used widely and has significant potential to extend reservoir life by increasing the oil production and decreasing the water cut. This new technology has the greatest potential in reservoirs that are moderately heterogeneous, contain moderately viscous oils, and have adverse water-oil mobility ratios. For example, many wells in Kansas's Arbuckle formation had similar treatments and we have seen very effective results. In addition, there were previous polymer treatments conducted by Texaco in Alameda Field on a number of wells throughout the Viola-Simpson formation in the early 70's. Most of the treatments proved to be very successful.

  14. Reservoir characterization helping to sustain oil production in Thailand's Sirikit Field

    SciTech Connect

    Shaafsma, C.E.; Phuthithammakul, S. )

    1994-07-01

    Sirikit field is located in the Phitsanulok basin of Thailand's north-central plains. The main reservoir sequence is some 400 m thick and comprises thin interbedded fluvio-lacustrine clay and sandstones. Initial oil volumes after exploration and appraisal drilling in 1981-1984 were estimated at some 180 million bbl. However, further development/appraisal drilling and the following up of new opportunities allowed a better delineation of the reservoirs, resulting in an increased STOIIP and recovery. Total in-place oil volumes were increased to 791 million bbl and the expectation of ultimate recovery to 133 million bbl. To date, 131 wells have been drilled, 65 MMstb have been produced, and production stands at 23,000 bbl/day. Extensive reservoir studies were among the techniques and methods used to assess whether water injection would be a viable further development option. A reservoir geological model was set up through (1) core studies, (2) a detailed sand correlation, and (3) reservoir quality mapping. This model showed that despite considerable heterogeneity most sands are continuous. Reservoir simulation indicated that water injection is viable in the north-central part of the field and that it will increase the Sirikit field reserves by 12 million; this is now part of Thai Shell's reserves portfolio. Injection will start in 1994. New up-to-date seismic and mapping techniques (still) using the old 3-D seismic data acquired in 1983 are being used for further reservoir delineation. This work is expected to result in a further reserve increase.

  15. Quasi-static electrorheological properties of hematite/silicone oil suspensions under DC electric fields.

    PubMed

    Espin, M J; Delgado, A V; Płocharski, J

    2005-05-24

    In this work, a modified rheometer has been used to gain information on the "start-up" of the shear flow of an electrorheological (ER) fluid consisting of hematite particles dispersed in silicone oil. The results show that unelectrified suspensions behave essentially as fluids, continuously deforming upon application of shear. However, this behavior changes in the presence of an electric field. For low fields and low volume fractions of solids, a solidlike (drastic increase in shear stress after the strain is applied) behavior is observed for small deformations. If the strain is increased, the yield starts and a transition to a viscoelastic-plastic nature is observed. Finally, a plastic behavior is characteristic of the post-yield regime. If the field strength and solids content are high, a discontinuous flow profile develops. These results, together with direct structural observations, suggest that the observed behavior is compatible with the formation of layers of particles electrophoretically deposited on the electrodes; the layers turn into rings when the shear field is applied. It is the slip of the fluid between these rings that can be considered responsible for the ER effect in these suspensions. PMID:15896029

  16. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2000-02-18

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through March 1999, project work has been completed related to data preparation, basic reservoir engineering, developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model, and a rock-log model, well drilling and completions, and surface facilities. Work is continuing on the stochastic geologic model, developing a 3-D stochastic thermal reservoir simulation model of the Fault Block IIA Tar (Tar II-A) Zone, and operational work and research studies to prevent thermal-related formation compaction. Thermal-related formation compaction is a concern of the project team due to observed surface subsidence in the local area above the steamflood project. Last quarter on January 12, the steamflood project lost its inexpensive steam source from the Harbor Cogeneration Plant as a result of the recent deregulation of electrical power rates in California. An operational plan was developed and implemented to mitigate the effects of the two situations. Seven water injection wells were placed in service in November and December 1998 on the flanks of the Phase 1 steamflood area to pressure up the reservoir to fill up the existing steam chest. Intensive reservoir engineering and geomechanics studies are continuing to determine the best ways to shut down the steamflood operations in Fault Block II while minimizing any future surface subsidence. The new 3-D deterministic thermal reservoir simulator model is being used to provide sensitivity cases to optimize production, steam injection, future flank cold water injection and reservoir temperature and pressure. According to the model, reservoir fill up of the steam chest at the current injection rate of 28,000 BPD and gross and net oil production rates of 7,700 BPD and 750 BOPD (injection to production ratio of 4) will occur in October 1999. At that time, the reservoir should act more like a waterflood and production and cold water injection can be operated at lower net injection rates to be determined. Modeling runs developed this quarter found that varying individual well injection rates to meet added production and local pressure problems by sub-zone could reduce steam chest fill-up by up to one month.

  17. Time-lapse Measurements of Scholte Wave Velocity Over a Compacting Oil Field

    NASA Astrophysics Data System (ADS)

    Wills, P. B.; Hatchell, P. J.

    2007-12-01

    Acquisition of time-lapse seismic data over producing oil and gas fields is a proven method for optimizing hydrocarbon production. Most current data have been acquired using towed-streamer seismic vessels but new systems incorporating permanent Ocean Bottom Cable (OBC) systems are gaining in popularity, both as a way to achieve better repeatability and also to reduce the cost of acquiring many time-lapse repeats of the baseline survey. Over the last three years, more than seven repeat data sets have been acquired at the permanent OBC system installed (by the operator, BP) over the Valhall oil field located offshore Norway. This system contains ~2400 four-component receiver stations that are recorded using a dense areal shot grid ("carpet" shoot) that provides high fold and has delivered excellent time-lapse signals starting from the first repeat occurring just three months after the baseline. Time-lapse OBC data are conventionally used to measure amplitude and velocity changes of body wave reflections (PP and PS) but other measurements are also possible. In particular, Scholte waves are strongly visible on records acquired everywhere in the field on appropriately processed data and, given the high fold (because of the dense shots), Scholte wave velocity and anisotropy time-lapse changes obtained with both hydrophone and geophone sensors are accurately and robustly estimated. The resulting shallow velocity maps are very sensitive to the seabed strains and show large velocity changes overlying deep production. Also, reconstruction of compressional "head wave" velocity difference measurements and vertically propagating shear wave shallow time-lapse statics produce maps that resemble the Scholte wave maps, with differences that reflect the physics of the propagation modes and effective fold. A reservoir model that includes deep reservoir volume changes together with appropriate geomechanical properties in the overburden and a shallow conversion of strain to velocity is used to successfully predict the measured velocity changes. The strain/velocity conversion requires asymmetry between crack opening and closing as well as velocity hysteresis and, in fact, the measurements provide an excellent laboratory for testing fracture-model/velocity conversion on in-situ rocks. After calibration, the model together with the data can constrain both volume changes in the reservoir, for making drilling decisions as well as the overburden geomechanical rock properties model, which itself is used for well- path selection and facilities decisions. Scholte wave velocity measurements can also be made using an oil platform as a "passive" source, removing the need for a conventional source near the seafloor. Finally, these measurements might be applicable on time- lapse controlled source measurements of greater generality in a wider geophysical context wherever an accurate measurement of a time-varying surface strain is desired.

  18. Strontium isotope detection of brine contamination in the East Poplar oil field, Montana

    USGS Publications Warehouse

    Peterman, Zell E.; Thamke, Joanna N.; Futa, Kiyoto; Oliver, Thomas A.

    2010-01-01

    Brine contamination of groundwater in the East Poplar oil field was first documented in the mid-1980s by the U.S. Geological Survey by using hydrochemistry, with an emphasis on chloride (Cl) and total dissolved solids concentrations. Supply wells for the City of Poplar are located downgradient from the oil field, are completed in the same shallow aquifers that are documented as contaminated, and therefore are potentially at risk of being contaminated. In cooperation with the Office of Environmental Protection of the Fort Peck Tribes, groundwater samples were collected in 2009 and 2010 from supply wells, monitor wells, and the Poplar River for analyses of major and trace elements, including strontium (Sr) concentrations and isotopic compositions. The ratio of strontium-87 to strontium-86 (87Sr/86Sr) is used extensively as a natural tracer in groundwater to detect mixing among waters from different sources and to study the effects of water/rock interaction. On a plot of the reciprocal strontium concentration against the 87Sr/86Sr ratio, mixtures of two end members will produce a linear array. Using this plotting method, data for samples from most of the wells, including the City of Poplar wells, define an array with reciprocal strontium values ranging from 0.08 to 4.15 and 87Sr/86Sr ratios ranging from 0.70811 to 0.70828. This array is composed of a brine end member with an average 87Sr/86Sr of 0.70822, strontium concentrations in excess of 12.5 milligrams per liter (mg/L), and chloride concentrations exceeding 8,000 mg/L mixing with uncontaminated water similar to that in USGS06-08 with 18.0 mg/L chloride, 0.24 mg/L strontium, and a 87Sr/86Sr ratio of 0.70811. The position of samples from the City of Poplar public-water supply wells within this array indicates that brine contamination has reached all three wells. Outliers from this array are EPU-4G (groundwater from the Cretaceous Judith River Formation), brine samples from disposal wells (Huber 5-D and EPU 1-D), USGS92-11 (a well with water that was considerably contaminated in 1992 and becoming less saline with time), and PNR-27 (only slightly below the defined trend with an 87Sr/86Sr ratio of 0.70793). Water samples from the City of Poplar wells are also enriched in anions and cations that are abundant in oil-field brine.

  19. RESERVOIR CHARACTERIZATION OF UPPER DEVONIAN GORDON SANDSTONE, JACKSONBURG STRINGTOWN OIL FIELD, NORTHWESTERN WEST VIRGINIA

    SciTech Connect

    S. Ameri; K. Aminian; K.L. Avary; H.I. Bilgesu; M.E. Hohn; R.R. McDowell; D.L. Matchen

    2001-07-01

    The Jacksonburg-Stringtown oil field contained an estimated 88,500,000 barrels of oil in place, of which approximately 20,000,000 barrels were produced during primary recovery operations. A gas injection project, initiated in 1934, and a pilot waterflood, begun in 1981, yielded additional production from limited portions of the field. The pilot was successful enough to warrant development of a full-scale waterflood in 1990, involving approximately 8,900 acres in three units, with a target of 1,500 barrels of oil per acre recovery. Historical patterns of drilling and development within the field suggests that the Gordon reservoir is heterogeneous, and that detailed reservoir characterization is necessary for understanding well performance and addressing problems observed by the operators. The purpose of this work is to establish relationships among permeability, geophysical and other data by integrating geologic, geophysical and engineering data into an interdisciplinary quantification of reservoir heterogeneity as it relates to production. Conventional stratigraphic correlation and core description shows that the Gordon sandstone is composed of three parasequences, formed along the Late Devonian shoreline of the Appalachian Basin. The parasequences comprise five lithofacies, of which one includes reservoir sandstones. Pay sandstones were found to have permeabilities in core ranging from 10 to 200 mD, whereas non-pay sandstones have permeabilities ranging from below the level of instrumental detection to 5 mD; Conglomeratic zones could take on the permeability characteristics of enclosing materials, or could exhibit extremely low values in pay sandstone and high values in non-pay or low permeability pay sandstone. Four electrofacies based on a linear combination of density and scaled gamma ray best matched correlations made independently based on visual comparison of geophysical logs. Electrofacies 4 with relatively high permeability (mean value > 45 mD) was determined to be equivalent to the pay sandstone within the Gordon reservoir. Three-dimensional models of the electrofacies in the pilot waterflood showed that electrofacies 4 is present throughout this area, and the other electrofacies are more disconnected. A three-layer, back-propagation artificial neural network with three slabs in the middle layer can be used to predict permeability and porosity from gamma ray and bulk density logs, the first and the second derivatives of the log data with respect to depth, well location, and log baselines. Two flow units were defined based on the stratigraphic model and geophysical logs. A three-dimensional reservoir model including the flow units, values of permeability calculated through the artificial neural network and injection pressure-rate information were then used as inputs for a reservoir simulator to predict oil production performance for the center producers in the pilot area. This description of the reservoir provided significantly better simulation results than earlier results obtained using simple reservoir models. Bulk density and gamma ray logs were used to identify flow units throughout the field. As predicted by the stratigraphic analysis, one of the flow units crosses stratigraphic units in the reservoir. A neural network was used to predict permeability values for each flow unit in producer and injection wells. The reservoir simulator was utilized to predict the performance of two flood patterns located to the north of the pilot area. Considering the simple model utilized for simulation, the results are in very good agreement with the field history.

  20. Temporal Changes in Microbial Metabolic Characteristics in Field-Scale Biopiles Composed of Aged Oil Sludge.

    PubMed

    Wang, Xiang; Li, Fasheng; Guo, Guanlin; Wang, Shijie; Boronin, Alexander; Wang, Qunhui

    2014-09-01

    Disposal of oil sludge, a hazardous waste, is currently a prevalent environmental issue. In this study, two field-scale biopiles were constructed to explore the temporal changes of microbial metabolic characteristics during the biotreatment of aged oil sludge. Bulking agent was mixed thoroughly with oily sludge to form a treated pile. The BIOLOG™ system was used to analyze the community level physiological parameters, including microbial metabolic activity, diversity, and variance. In comparison with the control, the community level physiological parameters of the treated pile were dramatically improved. Microbial metabolic activity of the treated pile was improved by 25.06% calculated from the maximums during the treatment. Microbial diversity index (Shannon index) ranges were improved from 1.64-3.02 (control pile) to 2.34-3.14 (treated pile). The numbers of petroleum-degrading bacteria and the total heterotrophic bacteria were correlated with the environmental temperature, and microbial metabolic characteristics in the treated pile revealed the distinctive carbon resources selection with the addition of cotton stalk. Temporal microbial metabolic characteristics, which have important effect on bioremediation, were revealed in this study. PMID:25228785

  1. Reasons for production decline in the diatomite, Belridge oil field: a rock mechanics view

    SciTech Connect

    Strickland, F.G.

    1985-03-01

    This paper summarizes research conducted on diatomite cores from the Belridge oil field in Kern County, CA. The study was undertaken to explain the rapid decline in oil production in diatomite wells by investigating three of six possible reasons. Characterization of the rock indicated that the rock was composed of principally amorphous opaline silica diatoms with only a trace of crystoballite quartz or chert quartz. Physical properties tests showed the diatomite to be of very low strength and plastic. It was established that longterm creep of diatomite into a propped fracture proceeds at a rate of approximately 1.5 microns/D (1.5 ..mu..m/d), a phenomenon that may contribute to rapid production declines. Also revealed was a matrix strength for the formation of about 1,325 psi (9136 kPa), a critical value to consider when depleting the reservoir. This also may help to explain the phase transformation to Opal CT around 2,000to 2,500-ft (610- to 762-m) depth.

  2. Temporal Changes in Microbial Metabolic Characteristics in Field-Scale Biopiles Composed of Aged Oil Sludge

    PubMed Central

    Wang, Xiang; Li, Fasheng; Guo, Guanlin; Wang, Shijie; Boronin, Alexander; Wang, Qunhui

    2014-01-01

    Abstract Disposal of oil sludge, a hazardous waste, is currently a prevalent environmental issue. In this study, two field-scale biopiles were constructed to explore the temporal changes of microbial metabolic characteristics during the biotreatment of aged oil sludge. Bulking agent was mixed thoroughly with oily sludge to form a treated pile. The BIOLOG™ system was used to analyze the community level physiological parameters, including microbial metabolic activity, diversity, and variance. In comparison with the control, the community level physiological parameters of the treated pile were dramatically improved. Microbial metabolic activity of the treated pile was improved by 25.06% calculated from the maximums during the treatment. Microbial diversity index (Shannon index) ranges were improved from 1.64–3.02 (control pile) to 2.34–3.14 (treated pile). The numbers of petroleum-degrading bacteria and the total heterotrophic bacteria were correlated with the environmental temperature, and microbial metabolic characteristics in the treated pile revealed the distinctive carbon resources selection with the addition of cotton stalk. Temporal microbial metabolic characteristics, which have important effect on bioremediation, were revealed in this study. PMID:25228785

  3. Low-cost FPSO for service in the Zaafarana oil field

    SciTech Connect

    1997-04-01

    The Zaafarana oilfield development, operated by Zaafarana Oil Co. (Zafco) presented a series of unique challenges, including redeployment of an internal-turret mooring system, use of a turret-based electrical-cable jumper system, and permanent use of cable-deployed electric submersible pumps in the gravel-pack well completions. Following a detailed three-dimensional (3D) seismic program, the field was discovered by the first well in December 1990. Four subsequent appraisal wells were drilled. The discovery well and two of the appraisal wells tested oil at rates ranging from 2,000 to 10,100 B/D. Initial development plans called for the use of two conventional platforms with a pipeline to a shore-based treatment and storage terminal. Data acquired from subsequent wells were incorporated into the mapping and reserve estimates resulting in a sharp downgrade of the estimated recoverable reserves. The reduced estimate, combined with a revised pricing scenario, necessitated an amended development plan with significantly lower costs. A new plan that uses a floating production, storage, and offloading (FPSO) facility and a single drilling/wellhead platform, connected by a pipeline and by electrical and control umbilicals, was approved in October 1992.

  4. Increased Oil Production and Reserves from Improved Completion Techniques in the Bluebell Field, Uinta Basin, Utah

    SciTech Connect

    Deo, M.D.; Morgan, C.D.

    1999-04-28

    The objective of the project is to increase oil production and reserves by the use of improved reservoir characterization and completion techniques in the Uinta Basin, Utah. To accomplish this objective, a two-year geologic and engineering characterization of the Bluebell field was conducted. The study evaluated surface and subsurface data, currently used completion techniques, and common production problems. It was determined that advanced case- and open-hole logs could be effective in determining productive beds and that stage-interval (about 500 ft [150 m] per stage) and bed-scale isolation completion techniques could result in improved well performance. In the first demonstration well (Michelle Ute well discussed in the previous technical report), dipole shear anisotropy (anisotropy) and dual-burst thermal decay time (TDT) logs were run before and isotope tracer log was run after the treatment. The logs were very helpful in characterizing the remaining hydrocarbon potential in the well. But, mechanical failure resulted in a poor recompletion and did not result in a significant improvement in the oil production from the well.

  5. Contracts for field projects and supporting research on enhanced oil recovery and improved drilling technology. Progress review No. 34, quarter ending March 31, 1983

    SciTech Connect

    Linville, B.

    1983-07-01

    Progress achieved for the quarter ending March 1983 are presented for field projects and supporting research for the following: chemical flooding; carbon dioxide injection; and thermal/heavy oil. In addition, progress reports are presented for: resource assessment technology; extraction technology; environmental and safety; microbial enhanced oil recovery; oil recovered by gravity mining; improved drilling technology; and general supporting research. (ATT)

  6. The 7 May 2001 induced seismic event in the Ekofisk oil field, North Sea

    NASA Astrophysics Data System (ADS)

    OttemöLler, L.; Nielsen, H. H.; Atakan, K.; Braunmiller, J.; Havskov, J.

    2005-10-01

    A moderate size seismic event on 7 May 2001 was strongly felt on platforms in the Ekofisk oil field, in the southern North Sea, but did not cause damage to platforms or wells. We combined near- and far-field observations to develop a consistent source model and to determine whether the event was induced. Seismic data placed the epicenter inside the Ekofisk field and suggested a shallow source depth based on spectral and moment tensor analysis. GPS data from the Ekofisk platforms displayed permanent vertical and horizontal movement due to the event. A topographic bulge in the sea bottom, revealed by differential bathymetry data, and overpressure in the overburden in the northeastern part of the field, detected only after the event, had been caused by unintentional water injection that started in 1999. The injection pressure and rate were sufficient to raise the overburden. Pressure gauge and compaction data ruled out that the event occurred at reservoir level, which was further supported by unaffected production rates and absence of well failure. We therefore conclude that the event occurred in the overburden, at less than 3 km depth. Initially, this appeared unlikely on account of very low shear strength of the overburden clay-rich shale and mud rocks. The seismic event was induced owing to stress changes caused by water injection. The event possibly initiated on the northern flank of the field near the water injector and may have involved flexure of the overburden into the depression bowl in the rest of the field. Moment tensor analysis is consistent with a pure double-couple source. We suggest that slip occurred on the near-horizontal rather than along the near-vertical nodal plane. Stress drop was low, and owing to the low overburden shear strength, the event released less energy than a typical stress drop event with similar source dimensions.

  7. Essential oil analysis and field evaluation of the citrosa plant "Pelargonium citrosum" as a repellent against populations of Aedes mosquitoes.

    PubMed

    Matsuda, B M; Surgeoner, G A; Heal, J D; Tucker, A O; Maciarello, M J

    1996-03-01

    A plant recently introduced into North America as the citrosa, Pelargonium citrosum ('Van Leenii'), has been marketed as a biological repellent against mosquitoes. Citrosa is claimed to repel mosquitoes within a 10 ft.2 (0.93 m2) area due to a continuous fragrant release of citronella oil. The total essential oil yield was 0.2 +/- 0.1% from fresh plant material. Chemical analysis by the authors revealed that combined essential oils of fresh greenhouse- and field-grown citrosa have 35.4 +/- 6.2% geraniol, 10.4 +/- 1.6% citronellol, 8.9 +/- 2.0% isomenthone, and 6.8 +/- 3.8% linalool. Both the morphology and essential oil of citrosa fall within the Pelargonium x asperum hybrid complex and are similar to 'Rosé', the commercial rose geranium. No character of morphology or essential oil of a Cymbopogon species yielding commercial citronella oil could be detected in the citrosa. The effectiveness of the citrosa as a repellent against field populations of spring Aedes spp. mosquitoes was evaluated and compared with a 75% deet (N,N-diethyl-3-methylbenzamide) formulation. Deet provided > 90% reduction in mosquitoes biting subjects for up to 8 h post-treatment. There was no significant difference between citrosa-treated and nontreated subjects. PMID:8723261

  8. Comparison of soft computing techniques for a three-phase oil field centrifuge.

    SciTech Connect

    Smith, R. E.; Parkinson, w; Miller, N.

    2002-01-01

    In this work we compare fuzzy techniques to neural network techniques for building a soft sensor for a three-phase oil field centrifuge. The soft sensor is used in a feed-forward control system that augments a feedback control system. Two approaches were used to develop the soft sensor. The first approach was to use a fuzzy rule based system based upon the experience of an expert operator. The expert operator's experience was supplemented using a computer model of the system. The second approach was to use a neural network to build the inverse of the computer model. The pros and cons of both techniques are discussed. KEYWORDS: fuzzy logic, neural networks, soft sensor, soft computing

  9. Biodegradation of marine surface floating crude oil in a large-scale field simulated experiment.

    PubMed

    Bao, Mutai; Sun, Peiyan; Yang, Xiaofei; Wang, Xinping; Wang, Lina; Cao, Lixin; Li, Fujuan

    2014-08-01

    Biodegradation of marine surface floating crude oil with hydrocarbon degrading bacteria, rhamnolipid biosurfactants, and nutrients was carried out by a large-scale field simulated experiment in this paper. After a 103 day experiment, for n-alkanes, the maximum biodegradation rate reached 71% and the results showed hydrocarbon degrading bacteria, rhamnolipid biosurfactants, and nutrients have a comprehensive effect. It also showed that rhamnolipid biosurfactants could shorten the biodegradation time through an emulsifying function; the nutrients could greatly increase the biodegradation rate by promoting HDB production. For PAHs, the chrysene series had higher weathering resistance. For the same series, the weathering resistance ability is C1- < C2- < C3- < C4-. After 53 days, no comprehensive effect occurred and more biodegradation was found for different n-alkanes in two pools which only had added rhamnolipid biosurfactants or nutrients, respectively. Except for C14, C15 and C16 sesquiterpanes, most of the steranes and terpanes had high antibiodegradability. PMID:24931448

  10. Turkey's largest oil field poised for CO/sub 2/ immiscible EOR project

    SciTech Connect

    Kantar, K.; Connor, T.E.

    1984-11-26

    The Bati Raman project uses some of the latest EOR technology to increase production from Turkey's largest oil field. Engineering for this challenging project has drawn upon the petroleum industry's recent experience in CO/sub 2/EOR, on laboratory testing, and on new applications of proven technology to meet the construction and operational requirements of the project facilities. Construction is now in progress and completion is scheduled for mid1985. The data obtained during operation of the facilities will be used to guide Turkish Petroleum Corp's continuing EOR program. It will also contribute to the petroleum industry's knowledge of carbon dioxide technology and the engineering community's ability to efficiently meet future EOR design challenges.

  11. Environmental impact assessment for the development of the Karakuduk oil field. Volume 2. Export trade information

    SciTech Connect

    1996-05-01

    The study, conducted by Chaparral Resources, was funded by the U.S. Trade and Development Agency. The report shows the results of a feasibility study to better define the characteristics and extent of the Karakuduk Oil Field. This portion of the study concerns the protection of the environment, worker health and safety, and contributing to the social well being of area inhabitats. The report also details regulatory and permit requirements to consider for the implementation of the project. This is Volume Two of a two-volume report and is divided into the following sections: (1) Introduction; (2) Project Description; (3) Description of Existing Environment; (4) Consequences (Impacts) of the Project and Mitigation Measures; (5) Regulatory Compliance; (6) References.

  12. Quantitative reverse sample genome probing of microbial communities and its application to oil field production waters

    SciTech Connect

    Voordouw, G.; Shen, Y.; Harrington, C.S.; Teland, A.J. ); Jack, T.R. ); Westlake, W.S. )

    1993-12-01

    This paper presents a protocol for quantitative analysis of microbial communities by reverse sample genome probing is presented in which (i) whole community DNA is isolated and labeled in the presence of a known amount of an added internal standard and (ii) the resulting spiked reverse genome probe is hybridized with a master filter on which denatured genomic DNAs from bacterial standards isolated from the target environment were spotted in large amounts (up to 1,500 ng) in order to improve detection sensitivity. This protocol allowed reproducible fingerprinting of the microbial community in oil field production waters at 19 sites from which water and biofilm samples were collected. It appeared that selected sulfate-reducing bacteria were significantly enhanced in biofilms covering the metal surfaces in contact with the production waters.

  13. Estimate of the risks of disposing nonhazardous oil field wastes into salt caverns

    SciTech Connect

    Tomasko, D.; Elcock, D.; Veil, J.

    1997-12-31

    Argonne National Laboratory (ANL) has completed an evaluation of the possibility that adverse human health effects (carcinogenic and noncarcinogenic) could result from exposure to contaminants released from nonhazardous oil field wastes (NOW) disposed in domal salt caverns. Potential human health risks associated with hazardous substances (arsenic, benzene, cadmium, and chromium) in NOW were assessed under four postclosure cavern release scenarios: inadvertent cavern intrusion, failure of the cavern seal, failure of the cavern through cracks or leaky interbeds, and a partial collapse of the cavern roof. To estimate potential human health risks for these scenarios, contaminant concentrations at the receptor were calculated using a one-dimensional solution to an advection/dispersion equation that included first order degradation. Assuming a single, generic salt cavern and generic oil-field wastes, the best-estimate excess cancer risks ranged from 1.7 {times} 10{sup {minus}12} to 1.1 {times} 10{sup {minus}8} and hazard indices (referring to noncancer health effects) ranged from 7 {times} 10{sup {minus}9} to 7 {times} 10{sup {minus}4}. Under worse-case conditions in which the probability of cavern failure is 1.0, excess cancer risks ranged from 4.9 {times} 10{sup {minus}9} to 1.7 {times} 10{sup {minus}5} and hazard indices ranged from 7.0 {times} 10{sup {minus}4} to 0.07. Even under worst-case conditions, the risks are within the US Environmental Protection Agency (EPA) target range for acceptable exposure levels. From a human health risk perspective, salt caverns can, therefore, provide an acceptable disposal method for NOW.

  14. Investigating electrokinetics application for in-situ inorganic oil field scale control

    NASA Astrophysics Data System (ADS)

    Hashaykeh, Manal A. I. Albadawi

    Oil well scale formation and deposition is an expensive problem and could be a nightmare for any production engineer if the rate of deposition is rapid as in the case of North Sea oil fields. Inorganic scales accumulate in surface and subsurface equipment causing a reduction in oil production and severe damage for production equipment. The major components of most oil field scale deposits are BaSO4, CaSO4 and SrSO4, which are formed due to incompatible mixing of reservoir formation water and sea water flooded in secondary enhanced oil recovery (EOR) processes. This work focuses on BaSO4 scale as it is one of the toughest scale components to be removed either by chemical means or mechanical means. Scale control methods usually involve complicated treatment using chemical dissolution methods as primary attempt and mechanical scrapping or jetting methods in case of failure of the chemical means. In this work, we devised a novel in-situ scale control method benefiting from the application of direct current (DC) which involves some of the electrokinetic (EK) phenomena. The applications of EK has been proved in our laboratories yielding high efficiency in capturing barium and separating it from sulfate before reaching the production well, thus preventing deposition in the production wellbore or wellbore formation. This objective was evaluated in our lab designed EK apparatus in three parts. In part-1, an 18.5 cm unconsolidated sand core was used which produced inconsistent results. This problem was overcome in part-2, where the porous media involved 46 cm consolidated sandcore. This also partly fulfilled the purpose of upscaling. In part-3, the porous media was extended to a 100 cm spatial distance between the injection and production wells. For all the experiments the reservoir models were made of 125 µm uniform sand particles and followed a final consolidation pressure of 30 psi. The EK-reservoir model contains 2 basic junctions; one of them injecting a 500 ppm SO4 2- solution, representing sulfate rich sea water and the other injecting a 500 ppm Ba2+ solution representing divalent cations rich in formation water and an outlet for water production. In part-1, there were 4 locations for the electrodes, while in part-2 and part-3 there were 5 electrode locations distributed along the spatial distance. Salinity of injection and formation water was varied within a range of 0 to 40,000 ppm. The flow rates of injection and formation water were constant throughout each experiment. In part-1 experiments, the flow rate was 1 ml/min, in part-2 this was increased to 2 ml/min, finally in part-3 this was further increased to 4.3 ml/min. 2 V/cm voltage gradient was applied for all of the experiments. On a real time basis the current, pressure, temperature, and pH of production water were all monitored. Finally, solid samples with scale deposits within were collected from different locations of the flow tubes. To be analyzed using an ICP-MS. The results have demonstrated up to 90% scale mitigation by the application of EK. In addition, there was pressure reduction in the flow tube, which could be justified due to chlorine gas generation at the locations sides creating a stimulation effect due to increased acidity. The observations from this study concluded that the application of EK will attribute to the production efficiency due to less scaling and reducing corrosion of surface equipment. This will attempt to demonstrate the world's first promising technique that could be used to replace expensive solutions which require well closure and incur production interruption loss. However, it is recommended that further extensive studies need to be done to confirm the results and finally design a pilot scale project to validate the lab work.

  15. An efficient thermotolerant and halophilic biosurfactant-producing bacterium isolated from Dagang oil field for MEOR application

    NASA Astrophysics Data System (ADS)

    Wu, Langping; Richnow, Hans; Yao, Jun; Jain, Anil

    2014-05-01

    Dagang Oil field (Petro China Company Limited) is one of the most productive oil fields in China. In this study, 34 biosurfactant-producing strains were isolated and cultured from petroleum reservoir of Dagang oil field, using haemolytic assay and the qualitative oil-displacement test. On the basis of 16S rDNA analysis, the isolates were closely related to the species in genus Pseudomonas, Staphylococcus and Bacillus. One of the isolates identified as Bacillus subtilis BS2 were selected for further study. This bacterium was able to produce a type of biosurfactant with excessive foam-forming properties at 37ºC as well as at higher temperature of 55ºC. The biosurfactant produced by the strain BS2 could reduce the surface tension of the culture broth from 70.87 mN/m to 28.97 mN/m after 8 days of incubation at 37ºC and to 36.15 mN/m after 20 days of incubation at 55ºC, respectively. The biosurfactant showed stability at high temperature (up to 120ºC), a wide range of pH (2 to 12) and salt concentrations (up to 12%) offering potential for biotechnology. Fourier transform infrared (FT-IR) spectrum of extracted biosurfactant tentatively characterized the produced biosurfactant as glycolipid derivative. Elemental analysis of the biosurfactant by energy dispersive X-ray spectroscopy (EDS) reveals that the biosurfactant was anionic in nature. 15 days of biodegradation of crude oil suggested a preferential usage of n-alkane upon microbial metabolism of BS2 as a carbon substrate and consequently also for the synthesis of biosurfactants. Core flood studies for oil release indicated 9.6% of additional oil recovery over water flooding at 37ºC and 7.2% of additional oil recovery at 55 ºC. Strain BS2 was characterized as an efficient biosurfactant-producing, thermotolerant and halophillic bacterium and has the potential for application for microbial enhanced oil recovery (MEOR) through water flooding in China's oil fields even in situ as adapted to reservoir chemistry and temperature.

  16. LOGAN WASH FIELD TREATABILITY STUDIES OF WASTEWATERS FROM OIL SHALE RETORTING PROCESSES

    EPA Science Inventory

    Treatability studies were conducted on retort water and gas condensate wastewater from modified in-situ oil shale retorts to evaluate the effectiveness of selected treatment technologies for removing organic and inorganic contaminants. At retorts operated by Occidental Oil Shale,...

  17. The role of active and ancient geothermal systems in evolution of Grant Canyon oil field, Railroad Valley, Nye County, Nevada

    SciTech Connect

    Hulen, J.B. ); Bereskin, S.R. ); Bortz, L.C.

    1991-06-01

    Since discovery in 1983, the Grant Canyon field has been among the most prolific oil producers (on a per-well basis) in the US. Production through June 1990 was 12,935,630 bbl of oil, principally from two wells which in tandem have consistently yielded more than 6,000 bbl of oil per day. The field is hosted by highly porous Devonian dolomite breccia loosely cemented with hydrothermal quartz. Results of fluid-inclusion and petrographic research in progress at Grant Canyon suggest that paleogeothermal and perhaps currently circulating geothermal systems may have played a major role in oil-reservoir evolution. For example, as previously reported, the breccia-cementing quartz hosts primary aqueous, aqueous/oil, and oil fluid inclusions which were trapped at about 120C (average homogenization temperature) and document initial oil migration and entrapment as droplets or globules dispersed in dilute (< 2.2 wt.% equivalent NaCl) aqueous solutions. Additional evidence of geothermal connection is that the horst-block trap at Grant Canyon is top and side sealed by valley-fill clastic and volcanic rocks which are locally hydrothermally altered and calcite flooded. These secondary seals are enhanced by disseminated, solid asphaltic residues locally accounting for 23% (volume) of the rock. Current reservoir temperatures at Grant Canyon (120C) and the adjacent Bacon Flat field (171C) attest to vigorous contemporary geothermal activity. Based on results of the authors' Grant Canyon work to date, they suggest that active and paleohydrothermal systems could be viable petroleum exploration targets in otherwise favorable terrain elsewhere in the Basin and Range.

  18. Time lapse seismic observations and effects of reservoir compressibility at Teal South oil field

    NASA Astrophysics Data System (ADS)

    Islam, Nayyer

    One of the original ocean-bottom time-lapse seismic studies was performed at the Teal South oil field in the Gulf of Mexico during the late 1990's. This work reexamines some aspects of previous work using modern analysis techniques to provide improved quantitative interpretations. Using three-dimensional volume visualization of legacy data and the two phases of post-production time-lapse data, I provide additional insight into the fluid migration pathways and the pressure communication between different reservoirs, separated by faults. This work supports a conclusion from previous studies that production from one reservoir caused regional pressure decline that in turn resulted in liberation of gas from multiple surrounding unproduced reservoirs. I also provide an explanation for unusual time-lapse changes in amplitude-versus-offset (AVO) data related to the compaction of the producing reservoir which, in turn, changed an isotropic medium to an anisotropic medium. In the first part of this work, I examine regional changes in seismic response due to the production of oil and gas from one reservoir. The previous studies primarily used two post-production ocean-bottom surveys (Phase I and Phase II), and not the legacy streamer data, due to the unavailability of legacy prestack data and very different acquisition parameters. In order to incorporate the legacy data in the present study, all three post-stack data sets were cross-equalized and examined using instantaneous amplitude and energy volumes. This approach appears quite effective and helps to suppress changes unrelated to production while emphasizing those large-amplitude changes that are related to production in this noisy (by current standards) suite of data. I examine the multiple data sets first by using the instantaneous amplitude and energy attributes, and then also examine specific apparent time-lapse changes through direct comparisons of seismic traces. In so doing, I identify time-delays that, when corrected for, indicate water encroachment at the base of the producing reservoir. I also identify specific sites of leakage from various unproduced reservoirs, the result of regional pressure blowdown as explained in previous studies; those earlier studies, however, were unable to identify direct evidence of fluid movement. Of particular interest is the identification of one site where oil apparently leaked from one reservoir into a "new" reservoir that did not originally contain oil, but was ideally suited as a trap for fluids leaking from the neighboring spill-point. With continued pressure drop, oil in the new reservoir increased as more oil entered into the reservoir and expanded, liberating gas from solution. Because of the limited volume available for oil and gas in that temporary trap, oil and gas also escaped from it into the surrounding formation. I also note that some of the reservoirs demonstrate time-lapse changes only in the "gas cap" and not in the oil zone, even though gas must be coming out of solution everywhere in the reservoir. This is explained by interplay between pore-fluid modulus reduction by gas saturation decrease and dry-frame modulus increase by frame stiffening. In the second part of this work, I examine various rock-physics models in an attempt to quantitatively account for frame-stiffening that results from reduced pore-fluid pressure in the producing reservoir, searching for a model that would predict the unusual AVO features observed in the time-lapse prestack and stacked data at Teal South. While several rock-physics models are successful at predicting the time-lapse response for initial production, most fail to match the observations for continued production between Phase I and Phase II. Because the reservoir was initially overpressured and unconsolidated, reservoir compaction was likely significant, and is probably accomplished largely by uniaxial strain in the vertical direction; this implies that an anisotropic model may be required. Using Walton's model for anisotropic unconsolidated sand, I successfully model the time-lapse changes for all phases of production. This observation may be of interest for application to other unconsolidated overpressured reservoirs under production.

  19. Sedimentological sand grain orientation in oil-producing U1 layer Kazan oil-gas-condensate field (Tomsk Oblast)

    NASA Astrophysics Data System (ADS)

    Krasnoshchekova, L.; Cherdansteva, D.; Vologdina, I.

    2016-03-01

    The paper describes the results in identifying the prevalent directions of elongated quartz grains being the major oil-producing layer component in sand reservoirs. Studying the orientation of quartz to its grain shapes in paleogeographical oriented core samples made it possible to identify the hydrodynamic reservoir regimes and facies type. The spatial confinement of pore spaces and cataclasis fractures in grain material to the prevalent elongated quartz grain directions was defined.

  20. Isotopic and chemical data from carbonate cements in surface rocks over and near four Oklahoma oil fields

    USGS Publications Warehouse

    Henry, Mitchell E.; Donovan, Terrence J.

    1978-01-01

    Carbonate cements in outcropping sandstones overlying the Doyle, Fox-Graham, Velma, and part of Wheeler oil fields, Oklahoma, were analyzed for their C13/ 12, 018/016, iron, and manganese compositions. The peculiar areal distribution of the values obtained is interpreted to be the direct result of hydrocarbon microseepage.

  1. FIELD STUDIES ON USBM AND TOSCO II RETORTED OIL SHALES: VEGETATION, MOISTURE, SALINITY, AND RUNOFF, 1977-1980

    EPA Science Inventory

    Field studies were initiated in 1973 to investigate the vegetative stabilization of processed oil shales and to follow moisture and soluble salt movement within the soil/shale profile. Research plots with two types of retorted shales (TOSCO II and USBM) with leaching and soil cov...

  2. 77 FR 57068 - Hours of Service of Drivers of Commercial Motor Vehicles; Regulatory Guidance for Oil Field...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-17

    ... Commercial Motor Vehicles; Regulatory Guidance for Oil Field Exception AGENCY: Federal Motor Carrier Safety..., 2010 (75 FR 82133), or you may visit www.regulations.gov . Public Participation: The www.regulations... ``oilfield operations'' exceptions in 49 CFR 395.1(d)(77 FR 33098). The regulatory guidance, effective June...

  3. 77 FR 46640 - Hours of Service of Drivers of Commercial Motor Vehicles; Regulatory Guidance for Oil Field...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-06

    ... Motor Vehicles; Regulatory Guidance for Oil Field Exceptions AGENCY: Federal Motor Carrier Safety..., 2010 (75 FR 82133), or you may visit www.regulations.gov . ] Public Participation: The www.regulations... FR 33098). The regulatory guidance, effective June 5, 2012, was issued to ensure...

  4. Borehole geophysical data for the East Poplar oil field area, Fort Peck Indian Reservation, northeastern Montana, 1993, 2004, and 2005

    USGS Publications Warehouse

    Smith, Bruce D.; Thamke, Joanna N.; Tyrrell, Christa

    2014-01-01

    Areas of high electrical conductivity in shallow aquifers in the East Poplar oil field area were delineated by the U.S. Geological Survey (USGS), in cooperation with the Fort Peck Assiniboine and Sioux Tribes, in order to interpret areas of saline-water contamination. Ground, airborne, and borehole geophysical data were collected in the East Poplar oil field area from 1992 through 2005 as part of this delineation. This report presents borehole geophysical data for thirty-two wells that were collected during, 1993, 2004, and 2005 in the East Poplar oil field study area. Natural-gamma and induction instruments were used to provide information about the lithology and conductivity of the soil, rock, and water matrix adjacent to and within the wells. The well logs were also collected to provide subsurface controls for interpretation of a helicopter electromagnetic survey flown over most of the East Poplar oil field in 2004. The objective of the USGS studies was to improve understanding of aquifer hydrogeology particularly in regard to variations in water quality.

  5. LABORATORY AND FIELD EVALUATION OF CRYSTALLIZED DOW 704 OIL ON THE PERFORMANCE OF THE PM2.5 WINS FRACTIONATOR

    EPA Science Inventory

    Subsequent to the PM2.5 FRM's 1997 promulgation, technicians at the CT Dept. of Env. Protection observed that the DOW 704 diffusion oil used in the method's WINS fractionator would occasionally crystallize during field use - particularly under wintertime conditions. While the f...

  6. Olive oil pilot-production assisted by pulsed electric field: impact on extraction yield, chemical parameters and sensory properties.

    PubMed

    Puértolas, Eduardo; Martínez de Marañón, Iñigo

    2015-01-15

    The impact of the use of pulsed electric field (PEF) technology on Arroniz olive oil production in terms of extraction yield and chemical and sensory quality has been studied at pilot scale in an industrial oil mill. The application of a PEF treatment (2 kV/cm; 11.25 kJ/kg) to the olive paste significantly increased the extraction yield by 13.3%, with respect to a control. Furthermore, olive oil obtained by PEF showed total phenolic content, total phytosterols and total tocopherols significantly higher than control (11.5%, 9.9% and 15.0%, respectively). The use of PEF had no negative effects on general chemical and sensory characteristics of the olive oil, maintaining the highest quality according to EU legal standards (EVOO; extra virgin olive oil). Therefore, PEF could be an appropriate technology to improve olive oil yield and produce EVOO enriched in human-health-related compounds, such as polyphenols, phytosterols and tocopherols. PMID:25149017

  7. Environmental assessment of Buccaneer gas and oil field in the northwestern Gulf of Mexico, 1978-1979. Volume IV. Bacterial communities. Annual report

    SciTech Connect

    Sizemore, R.K.; Olsen, K.

    1980-12-01

    Bacterial numbers and taxonomic types were found to be the same in the oil field as in the control area. No difference in bacterial diversity or biomass was noted between stations but a change did occur between seasonal samples. Members of the genera Vibrio, Pseudomonas, Aeromonas and Acinetobacter were found to predominate in the sediment and fish samples. The bacterial population of the oil field sites contained more oil degrading and sulfur oxidizing bacteria than the control site.

  8. Isotopic composition of oil-field brines from Kettleman North Dome, California, and their geologic implications

    USGS Publications Warehouse

    Kharaka, Y.K.; Berry, F.A.F.; Friedman, I.

    1973-01-01

    Deuterium and O18 analyses were made on 25 formation-water samples from Miocene (Temblor Formation) and Eocene (McAdams Formation) reservoir rocks at Kettleman North Dome oil field, California, and on three surface water samples from Reef Ridge located about three miles to the west of the field. The ??O18 values obtained generally increase with depth and most probably are due to temperature controlled exchange reactions with carbonate cement and dissolved carbonate species. The ??D values obtained seem to be controlled primarily by the membrane behavior of shales modifying the assumed original values. The contribution of isotopic exchange between water and clays cannot be evaluated at present. The isotopic data support the conclusions based on a detailed study of geology, hydrodynamics, and formation water geochemistry (Kharaka, 1971) which indicate that:. 1. The Temblor Formation waters are probably meteoric in origin concentrated chemically and isotopically by shale membranes, and 2. The McAdams Formation waters were most probably obtained by squeezing the original interstitial marine connate waters of deposition from the underlying Mesozoic sediments. ?? 1973.

  9. Analysis of AIS Data of the Recluse Oil Field, Recluse, Wyoming

    NASA Technical Reports Server (NTRS)

    Dykstra, J. D.; Segal, D. B.

    1985-01-01

    Airborne Imaging Spectrometer (AIS) data were flown over the Recluse, Wyoming oil field on September 9, 1984. Processing software was developed at Earth Satellite Corporation (EarthSat) for interactive analysis of the AIS data. EarthSat's AIS processing capabilities include destriping, solar irradiance corrections, residual calculations, geometric resampling, equal energy normalization, interactive spectral classifications and a variety of compressive algorithms to reduce the data to 8-bit format with a minimum of information loss. The in-house photolab facilities of EarthSat can routinely produce high-quality color renditions of the enhanced AIS data. A total of 80 lithologic samples were collected under the AIS flight lines. Correlation (within the atmospheric windows) between the laboratory and the AIS spectra of sample sites was generally poor. Reasonable correlation was only possible in large, freshly plowed fields. Mixed pixels and contrast between the natural and sample's surfaces were believed responsible for the poor correlation. Finally, a drift of approximately three channels was observed in the diffraction grating position within the 1.8 to 2.1 micron quadrant.

  10. Phosphoria reservoir facies exposed in the northeast Bighorn basin - an exhumed Cottonwood Creek oil field

    SciTech Connect

    Sturm, S.D.; Inden, R.F.; Dean, J.S.

    1986-08-01

    Detailed stratigraphic correlations between well-exposed outcrops and nearby oil wells permit the delineation of porous carbonate reservoir facies within the Phosphoria Formation (Guadalupian) in the northeastern part of the Bighorn basin. The most significant petroleum reservoirs in this area occur in two depositional facies defined by faunas and vertical sequences of sedimentary and biogenic structures. Effective porosity development in the peritidal facies occurs in intraclast-pellet, dolomite packstone/grainstone, and irregularly laminated, fenestral algal-boundstone. In the restricted-marine facies, reservoir development occurred in bioturbated, dolomite mudstone-wackestone, and phylloid-algal and mollusk dolomite wackestone-packstone. Based on regional analysis, fenestral algal-boundstone pods are thought to have evolved as peninsula-island complexes paralleling reactivated northwest-southeast-trending faults on the east side of the Bighorn basin. In the northeastern Bighorn basin, peninsula-island complexes accumulated on the Bighorn and Sheep Mountain paleohighs. They defined an embayment in which restricted marine rocks were deposited. Porous peritidal rocks appear to have been concentrated along the seaward flanks of the thickest algal-boundstone pods, which grade laterally into porous restricted-marine lithologies. The geologic setting of exposed peritidal and restricted-marine reservoirs in the northeastern Bighorn basin appears to be similar to that of Cottonwood Creek field. An understanding of facies relationships may be useful in the further development of Cottonwood Creek field and for exploration for similar types of carbonate stratigraphic traps along the eastern margin of the Bighorn basin.

  11. Molecular biologic techniques applied to the microbial prospecting of oil and gas in the Ban 876 gas and oil field in China.

    PubMed

    Zhang, Fan; She, Yuehui; Zheng, Yong; Zhou, Zhifeng; Kong, Shuqiong; Hou, Dujie

    2010-04-01

    Currently, molecular biologic techniques achieve a great development in studies of soil samples. The objective of this research is to improve methods for microbial prospecting of oil and gas by applying culture-independent techniques to soil sampled from above a known oil and gas field. Firstly, the community structure of soil bacteria above the Ban 876 Gas and Oil Field was analyzed based on 16S rRNA gene clone libraries. The soil bacteria communities were consistently different along the depth; however, Chloroflexi and Gemmatimonadetes were predominant and methanotrophs were minor in both bacteria libraries (DGS1 and DGS2). Secondly, the numbers of methane-oxidizing bacteria, quantified using a culture-dependent procedure and culture-independent group-specific real-time PCR (RT-PCR), respectively, were inconsistent with a quantify variance of one or two orders of magnitude. Special emphasis was given to the counting advantages of RT-PCR based on the methanotrophic pmoA gene. Finally, the diversity and distribution of methanotrophic communities in the soil samples were analyzed by constructing clone libraries of functional gene. All 508-bp inserts in clones phylogenetically belonged to the methanotrophic pmoA gene with similarities from 83% to 100%. However, most of the similarities were below 96%. Five clone libraries of methanotrophs clearly showed that the anomalous methanotrophs (Methylosinus and Methylocystis) occupy the studied area. PMID:20107985

  12. The Prestige oil spill: bacterial community dynamics during a field biostimulation assay.

    PubMed

    Jiménez, Núria; Viñas, Marc; Bayona, Josep M; Albaiges, Joan; Solanas, Anna M

    2007-12-01

    A field bioremediation assay using the oleophilic fertilizer S200 was carried out 12 months after the Prestige heavy fuel-oil spill on a beach on the Cantabrian coast (north Spain). This assay showed that S200-enhanced oil degradation, particularly of high-molecular-weight n-alkanes and alkylated PAHs, suggesting an increase in the microbial bioavailability of these compounds. The bacterial community structure was determined by cultivation-independent analysis of polymerase chain reaction-amplified 16S rDNA by denaturing gradient gel electrophoresis. Bacterial community was mainly composed of alpha-Proteobacteria (Rhodobacteriaceae and Sphingomonadaceae). Representatives of gamma-Proteobacteria (Chromatiales, Moraxellaceae, and Halomonadaceae), Bacteroidetes (Flavobacteriaceae), and Actinobacteria group (Nocardiaceae and Corynebacteriaceae) were also found. The addition of the fertilizer led to the appearance of the bacterium Mesonia algae in the early stages, with a narrow range of growth substrates, which has been associated with the common alga Achrosiphonia sonderi. The presence of Mesonia algae may be attributable to the response of the microbial community to the addition of N and P rather than indicating a role in the biodegradation process. The Rhodococcus group appeared in both assay plots, especially at the end of the experiment. It was also found at another site on the Galician coast that had been affected by the same spill. This genus has been associated with the degradation of n-alkanes up to C(36). Taking into account the high content of heavy alkanes in the Prestige fuel, these microorganisms could play a significant role in the degradation of such fuel. A similar bacterial community structure was observed at another site that showed a similar degree of fuel weathering. PMID:17943279

  13. Hackberry oil and gas fields in southeast Texas: channel/fan depositional systems and structural controls

    SciTech Connect

    Ewing, T.E.; Reed, R.S.

    1983-03-01

    Deep-water sandstones of the Hackberry Formation (Oligocene) host significant quantities of oil and gas. They remain one of the most important deep exploration targets in southeastern-most Texas; new fields producing from the Hackberry have been discovered at a steady rate from 1946 to the present. The Hackberry contains two hydrocarbon plays. The updip play is relatively shallow, oil-rich, and lies near the updip limit of deep-water deposition. The downdip play is gas rich and generally geopressured. The reservoirs lie either within or on the flanks of major channel systems and are often bounded updip by small growth faults. The Hackberry Formation is a wedge of sand and shale with bathyal fauna that separates upper Frio sandstone and shale from middle and lower Frio shale and sand. The main sandstone lies atop a channeled unconformity at the base of the formation. Topmost are proximal to medial fan deposits with slightly meandering channels and overbank turbidites. This sequence suggests that the Hackberry sands were laid down by an aggrading, onlapping submarine canyon-fan complex that eroded headward into the contemporaneous Frio barrier bar-strand plain. The early structural history of the area is obscure, but Vicksburg-age faulting associated with continental slope sedimentation is possible. Small growth faults displace the Hackberry section less than 500 ft (150 m) and extend upward into the Miocene strata. Isopach and isolith maps indicate that the Orange, Port Neches, and Fannett salt domes were active uplifts during Frio and Anahuac deposition. Near Spindletop dome, however, only a north-south trending salt-cored ridge was present.

  14. Class III Mid-Term Project, "Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies"

    SciTech Connect

    Scott Hara

    2007-03-31

    The overall objective of this project was to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involved improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective has been to transfer technology that can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The first budget period addressed several producibility problems in the Tar II-A and Tar V thermal recovery operations that are common in SBC reservoirs. A few of the advanced technologies developed include a three-dimensional (3-D) deterministic geologic model, a 3-D deterministic thermal reservoir simulation model to aid in reservoir management and subsequent post-steamflood development work, and a detailed study on the geochemical interactions between the steam and the formation rocks and fluids. State of the art operational work included drilling and performing a pilot steam injection and production project via four new horizontal wells (2 producers and 2 injectors), implementing a hot water alternating steam (WAS) drive pilot in the existing steamflood area to improve thermal efficiency, installing a 2400-foot insulated, subsurface harbor channel crossing to supply steam to an island location, testing a novel alkaline steam completion technique to control well sanding problems, and starting on an advanced reservoir management system through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation. The second budget period phase (BP2) continued to implement state-of-the-art operational work to optimize thermal recovery processes, improve well drilling and completion practices, and evaluate the geomechanical characteristics of the producing formations. The objectives were to further improve reservoir characterization of the heterogeneous turbidite sands, test the proficiency of the three-dimensional geologic and thermal reservoir simulation models, identify the high permeability thief zones to reduce water breakthrough and cycling, and analyze the nonuniform distribution of the remaining oil in place. This work resulted in the redevelopment of the Tar II-A and Tar V post-steamflood projects by drilling several new wells and converting idle wells to improve injection sweep efficiency and more effectively drain the remaining oil reserves. Reservoir management work included reducing water cuts, maintaining or increasing oil production, and evaluating and minimizing further thermal-related formation compaction. The BP2 project utilized all the tools and knowledge gained throughout the DOE project to maximize recovery of the oil in place.

  15. Brine Contamination of Ground Water and Streams in the Baxterville Oil Field Area, Lamar and Marion Counties, Mississippi

    USGS Publications Warehouse

    Kalkhoff, Stephen J.

    1993-01-01

    A hydrologic investigation to define the extent of brine contamination in ground water and streams in the Baxterville oil field area was conducted from October 1984 through November 1985. The 260-square-mile study area includes the Baxterville oil field (approximately 12.5 square miles) in southwestern Lamar and southeastern Marion Counties, Mississippi. Since 1944, disposal of more than 1 billion barrels of brine pumped from the oil- producing zones has contaminated (increased chloride to greater than background concentrations) parts of the Citronelle and shallow Miocene aquifers and some streams that drain the oil field. Many domestic wells have been abandoned because of the presence of substantial quantities of brine in the ground water. Brine has moved laterally through the shallowest aquifers and discharged into Clear Creek and its tributaries. Although the presence of brine in surface water was greatest during periods of low flow when streamflow originated primarily from ground-water inflow, brine was also detected during high-flow periods when streamflow consisted largely of precipitation runoff.

  16. Oil spill detection using satellite based SAR - Experience from a field experiment

    SciTech Connect

    Bern, T.I.; Wahl, T.; Andersen, T.; Olsen, R. Michigan Environmental Research Inst., Ann Arbor )

    1993-03-01

    During the commissioning phase of the ERS-1, C-band, synthetic aperture radar (SAR) images were obtained regularly over international waters for a range of operational, real-time uses. Among other capabilities, SAR is expected to be able to detect oil slicks on the sea surface. A project was defined with the aim of developing and demonstrating a system for early oil spill detection using satellite based SAR. During the Dedicated Oil Spill Experiment August 1991 (DOSE-91) three slicks, each 20 metric tons of stabilized crude oil, were released in phase with the passages of the ERS-1 satellite. The experiment included sea truthing, oil slick tracking using drifting buoys, and aircraft surveillance using various remote sensing techniques to compare and verify satellite observations. This paper presents the observations gathered during the experiment with emphasis on the SAR imagery of oil slicks under certain environmental conditions. Image enhancements techniques used to process the imagery are also discussed. 7 refs.

  17. Increased Oil Production and Reserves From Improved Completion Techniques in the Bluebell Field, Uinta Basin, Utah

    SciTech Connect

    Morgan, C.D.; Deo, M.D.

    1998-04-01

    The Bluebell field is productive from the Tertiary lower Green River and Colton (Wasatch) Formations of the Uinta Basin, Utah. The productive interval consists of thousands of feet of interbedded fractured clastic and carbonate beds deposited in the ancestral Lake Uinta. Wells in the Bluebell field are typically completed by perforating 40 or more beds over 1000 to 3000 vertical ft (300-900 m), then stimulating the entire interval with hydrochloric acid. This technique is often referred to as the shot gun completion. Completion techniques used in the Bluebell field were discussed in detail in the Second Annual Report (Curtice, 1996). The shot-gun technique is believed to leave many potentially productive beds damaged and/or untreated, while allowing water-bearing and low-pressure (thief) zones to communicate with the wellbore. A two-year characterization study involved detailed examination of outcrop, core, well logs, surface and subsurface fractures, produced oil-field waters, engineering parameters of the two demonstration wells, and analysis of past completion techniques and effectiveness. The study was intended to improve the geologic characterization of the producing formations and thereby develop completion techniques specific to the producing beds or facies instead of a shot gun approach to stimulating all the beds. The characterization did not identify predictable-facies or predictable-fracture trends within the vertical stratigraphic column as originally hoped. Advanced logging techniques can identify productive beds in individual wells. A field-demonstration program was developed to use cased-hole advanced logging techniques in two wells and recompletion the wells at two different scales based on the logging. The first well was going to be completed at the interval scale using a multiple stage completion technique (about 500 ft [150 m] per stage). The second well will be recompleted at the bed-scale using bridge plug and packer to isolate three or more beds for stimulation. These recompletion will show which logs are most effective in identifying productive beds and what scale of completion is most cost effective. The third demonstration will be the logging and completion of a new well using the logs and completion scale or technique, most effective in the previous demonstrations.

  18. Correlations among hydrocarbon microseepage, soil chemistry, and uptake of micronutrients by plants, Bell Creek oil field, Montana

    USGS Publications Warehouse

    Roeming, S.S.; Donovan, T.J.

    1985-01-01

    Chelate-extractable iron and manganese concentrations in soils over and around the Bell Creek oil field suggest that compared to low average background values, there are moderate amounts of these elements directly over the production area and higher concentrations distributed in an aureole pattern around the periphery of the field. Adsorbed and organically bound iron and manganese appear to be readily taken up by plants resulting in anomalously high levels of these elements in leaves and needles over the oil field and suggesting correlation with corresponding low concentrations in soils. Iron and manganese appear to have bypassed the soil formation process where, under normal oxidizing conditions, they would have ultimately precipitated as insoluble oxides and hydroxides. ?? 1985.

  19. Determination of mean droplet sizes of water-in-oil emulsions using an Earth's field NMR instrument.

    PubMed

    Fridjonsson, Einar O; Flux, Louise S; Johns, Michael L

    2012-08-01

    The use of the Earth's magnetic field (EF) to conduct nuclear magnetic resonance (NMR) experiments has a long history with a growing list of applications (e.g. ground water detection, diffusion measurements of Antarctic sea ice). In this paper we explore whether EFNMR can be used to accurately and practically measure the mean droplet size () of water-in-oil emulsions (paraffin and crude oil). We use both pulsed field gradient (PFG) measurements of restricted self-diffusion and T₂ relaxometry, as appropriate. T₂ relaxometry allows the extension of droplet sizing ability below the limits set by the available magnetic field gradient strength of the EFNMR apparatus. A commercially available bench-top NMR spectrometer is used to verify the results obtained using the EFNMR instrument, with good agreement within experimental error, seen between the two instruments. These results open the potential for further investigation of the application of EFNMR for emulsion droplet sizing. PMID:22750255

  20. Bioflocculant produced by Klebsiella sp. MYC and its application in the treatment of oil-field produced water

    NASA Astrophysics Data System (ADS)

    Yue, Lixi; Ma, Chunling; Chi, Zhenming

    2006-10-01

    Seventy-nine strains of bioflocculant-producing bacteria were isolated from 3 activated sludge samples. Among them, strain MYC was found to have the highest and stable flocculating rate for both kaolin clay suspension and oil-field produced water. The bacterial strain was identified as Klebsiella sp. MYC according to its morphological and biochemical characteristics and 16SrDNA sequence. The optimal medium for bioflocculant production by this bacterial strain was composed of cane sugar 20gL-1 KH2PO4 2g L-1, K2HPO45gL-1, (NH4)2SO4 0.2gL-1, urea 0.5 gL-1 and yeast extract 0.5 gL-1, the initial pH being 5.5. When the suspension of kaolin clay was treated with 0.5% of Klebsiella sp. MYC culture broth, the flocculating rate reached more than 90.0% in the presence of 500mgL1 CaCl2, while the flocculating rate for oil-field produced water was near 80.0% in a pH range of 7.0-9.0 with the separation of oil and suspended particles from the oil-field produced water under similar conditions. The environment-friendly nature of the bioflocculant and high flocculating rate of the strain make the bioflocculant produced by Klebsiella sp. MYC an attractive bioflocculant in oil-field produced water treatment.

  1. Super-giant oil fields and future prospects in the Middle East

    SciTech Connect

    Christian, L.; Johnston, D.

    1995-06-01

    Upper Jurassic carbonates, Lower Cretaceous sands, Lower Cretaceous carbonates and Tertiary carbonates of the Middle East contain more than 50% of the worlds oil. Our area of interest covers SE Turkey and Syria in the north to the borders of Yemen and Oman in the south, and from the Red Sea across Saudi Arabia, the Emirates and the Arabian/Persian Gulf to Iran in the East. There are over 80 fields in this region with over 1 billion barrels of recoverable reserves. Yet only around 30,000 wells have been drilled in this territory. Regional structure and stratigraphy are discussed within the context of three major plays in the region as well as a new play in the Permo-Carboniferous. Numerous opportunities are available and countries such as Iraq and Iran may one day open their doors more to the industry than is presently the case. The dramatic petroleum geology of the region will stamp its influence on the nature of business and opportunities for years to come. While fiscal systems here already offer some of the toughest terms in the world, future deals in the more prolific areas will be even tougher. But, the economies of Middle Eastern scale will provide some of the great mega-opportunities of future international exploration.

  2. Probing asphaltene aggregation in native crude oils with low-field NMR.

    PubMed

    Zielinski, Lukasz; Saha, Indrajit; Freed, Denise E; Hürlimann, Martin D; Liu, Yongsheng

    2010-04-01

    We show that low-field proton nuclear magnetic resonance (NMR) relaxation and diffusion experiments can be used to study asphaltene aggregation directly in crude oils. Relaxation was found to be multiexponential, reflecting the composition of a complex fluid. Remarkably, the relaxation data for samples with different asphaltene concentrations can be collapsed onto each other by a simple rescaling of the time dimension with a concentration-dependent factor xi, whereas the observed diffusion behavior is unaffected by asphaltene concentration. We interpret this finding in terms of a theoretical model that explains the enhanced relaxation by the transitory entanglement of solvent hydrocarbons within asphaltene clusters and their subsequent slowed motion and diffusion within the cluster. We relate the measured scaling parameters xi to cluster sizes, which we find to be on the order of 2.2-4.4 nm for an effective sphere diameter. These sizes are in agreement with the typical values reported in the literature as well as with the small-angle X-ray scattering (SAXS) experiments performed on our samples. PMID:20131761

  3. Earth stress measurements in the South Belridge oil field, Kern County, California

    SciTech Connect

    Hansen, K.S.; Purcell, W.R.

    1986-01-01

    Within Sections 33 and 34 of the South Belridge oil field, where the principal earth stresses are assumed to lie in vertical or horizontal planes, the azimuth of the greater horizontal earth stress as measured or inferred by several different techniques is N15/sup 0/E +. 15/sup 0/. This agrees with values reported in the literature for the regional stress orientation, which range from N-S to NNE-SSW. At depths of about 850 and 1300 feet, the magnitude of the vertical stress (overburden) lies between those of the greater and lesser horizontal stresses determined from open-hole microfrac tests. At about 2100 feet, however, the vertical and lesser horizontal stresses are equal, to within the limits of accuracy of the authors' measurements. If trends of stress versus depth established at the three measurement points continue downward, there is the possibility that at depths below 2100 feet the minimum stress may be vertical. The most reliable methods used for determining in-situ stress orientation at South Belridge are surface tiltmeters and orientation of out-of-round (elliptical) boreholes. Study of natural fractures in the nearby Chico-Martinez Creek outcrop provided important supporting evidence of stress orientation. Impression packers run during the microfrac tests and seismic data recorded during routine hydraulic fracturing procedures yielded much less definitive information concerning fracture and stress direction.

  4. Field development of oil palms (Elaeis guineensis jacq) originating from cryopreserved stabilized polyembryonic cultures.

    PubMed

    Konan, E K; Durand-Gasselin, T; Kouadio, Y J; Niamké, A C; Dumet, D; Duval, Y; Rival, A; Engelmann, F

    2007-01-01

    In this paper, the long term observation of plants originating from control and cryopreserved stabilized polyembryonic cultures (SPCs) of six elite oil palm clones was carried out. Survival of plantlets in the nursery was monitored, then a series of vegetative and floral characteristics of over 440 palms were studied for up to 12 years after field transfer in Côte D'Ivoire. The six clones tested showed an average recovery of 34% after freezing in liquid nitrogen. The average survival in the nursery of plantlets originating from pretreated and dehydrated and from cryopreserved SPCs was higher than that of control SPCs. Palm trees originating from control SPCs were found to flower earlier than those originating from pretreated and dehydrated and from cryopreserved SPCs. This delay in flowering disappeared progressively and all palms had flowered 3 years after planting regardless of the SPC treatment. Abnormal palms were observed in one clone only. With this clone, the percentage of abnormal palms originating from cryopreserved SPCs was significantly lower (5%) than that measured on palms originating from control SPCs (29%). PMID:18075706

  5. Subsidence rate monitoring of Aghajari oil field based on Differential SAR Interferometry

    NASA Astrophysics Data System (ADS)

    Moghaddam, N. Fouladi; Sahebi, M. R.; Matkan, A. A.; Roostaei, M.

    2013-06-01

    Land subsidence, due to natural or anthropogenic processes, causes significant costs in both economic and structural aspects. That part of subsidence observed most is the result of human activities, which relates to underground exploitation. Since the gradual surface deformation is a consequence of hydrocarbon reservoirs extraction, the process of displacement monitoring is amongst the petroleum industry priorities. Nowadays, Differential SAR Interferometry, in which satellite images are utilized for elevation change detection and analysis - in a millimetre scale, has proved to be a more real-time and cost-effective technology in contrast to the traditional surveying method. In this study, surface displacements in Aghajari oil field, i.e. one of the most industrious Iranian hydrocarbon sites, are being examined using radar observations. As in a number of interferograms, the production wells inspection reveals that surface deformation signals develop likely due to extraction in a period of several months. In other words, different subsidence or uplift rates and deformation styles occur locally depending on the geological conditions and excavation rates in place.

  6. Disposal of oil field wastes and NORM wastes into salt caverns.

    SciTech Connect

    Veil, J. A.

    1999-01-27

    Salt caverns can be formed through solution mining in the bedded or domal salt formations that are found in many states. Salt caverns have traditionally been used for hydrocarbon storage, but caverns have also been used to dispose of some types of wastes. This paper provides an overview of several years of research by Argonne National Laboratory on the feasibility and legality of using salt caverns for disposing of nonhazardous oil field wastes (NOW) and naturally occurring radioactive materials (NORM), the risk to human populations from this disposal method, and the cost of cavern disposal. Costs are compared between the four operating US disposal caverns and other commercial disposal options located in the same geographic area as the caverns. Argonne's research indicates that disposal of NOW into salt caverns is feasible and, in most cases, would not be prohibited by state agencies (although those agencies may need to revise their wastes management regulations). A risk analysis of several cavern leakage scenarios suggests that the risk from cavern disposal of NOW and NORM wastes is below accepted safe risk thresholds. Disposal caverns are economically competitive with other disposal options.

  7. Core acid treatment influence on well reservoir properties in Kazan oil-gas condensate field

    NASA Astrophysics Data System (ADS)

    Janishevskii, A.; Ezhova, A.

    2015-11-01

    The research involves investigation of the influence of hydrochloric acid (HCI-12%) and mud acid (mixture: HCl - 10% and HF - 3%) treatment on the Upper-Jurassic reservoir properties in Kazan oil-gas condensate field wells. The sample collection included three lots of core cylinders from one and the same depth (all in all 42). Two lots of core cylinders were distributed as following: first lot - reservoir properties were determined, and, then thin sections were cut off from cylinder faces; second lot- core cylinders were exposed to hydrochloric acid treatment, then, after flushing the reservoir properties were determined, and thin sections were prepared. Based on the quantitative petrographic rock analysis, involvin 42 thin sections, the following factors were determined: granulometric mineral composition, cement content, intergranular contacts and pore space structure. According to the comparative analysis of initial samples, the following was determined: content decrease of feldspar, clay and mica fragments, mica, clay and carbonate cement; increase of pore spaces while in the investigated samples- on exposure of rocks to acids effective porosity and permeability value range is ambiguous.

  8. Rethinking conventional field development: 3D shows direct detection of bypassed oil reserves

    SciTech Connect

    Sibley, D.M.; Mastoris, S.S.

    1994-12-31

    Accurate well to seismic correlations of several producing sands and detailed analyses of reservoir characteristics have revealed hidden reserves in an aging field that was previously determined to be uneconomic. The combination of a recent 3D survey shot over Eugene Island Blocks 338 and 339, Gulf of Mexico, and new interactive workstation technology was instrumental in identifying swept and unswept portions of different oil reservoirs and allowed new infill wells to pinpoint key targets. Seismic attributes were extracted along mapped horizons which showed lateral variations in reservoir properties, identifying depleted zones where the water front had passed through and areas it had missed. This observed seismic response is related to changes in water saturation associated with production and was verified by seismic modeling based on Biot-Gassman-Geertsman equations. The result was a successful drilling program for Chevron and its operating partner Texaco. Chevron was able to participate in 11 out of 14 development wells after making a turnaround decision to keep what was once thought to be a marginal property.

  9. Degradation of phenanthrene by bacterial strain isolated from soil in oil refinery fields in Shanghai China.

    PubMed

    Zhao, He-Ping; Wu, Qing-Sheng; Wang, Lei; Zhao, Xue-Tao; Gao, Hong-Wen

    2009-05-30

    A bacterial strain Pseudomonas stutzeri ZP2 was identified with phenanthrene-degrading ability based on Gram staining, oxydase reaction, biochemical tests, FAME analysis, G+C content and 16S rDNA gene sequence analysis. It is the first time that P. stutzeri is reported to process the capability for phenanthrene degradation. The strain was isolated from soil samples contaminated with polycyclic aromatic hydrocarbon (PAH)-containing waste from an oil refinery field in Shanghai, China. Strain P sp. ZP2 can utilize naphthalene, phenanthrene and Tween 80 as its sole carbon source and can degrade phenanthrene very fast, 6 days for 96% phenanthrene at 250 ppm concentration. The optimal growth conditions of strain ZP2 was determined to be at pH 8.0, 37 degrees C, respectively. The results also indicate that strain ZP2 can remove more than 90% of phenanthrene at any concentrations ranged from 250 to 1000 ppm in 6 days. It suggests that strain ZP2 can endure high concentrations of phenanthrene. Besides, the effects of non-ionic surfactants such as Brij 30, Triton X100 and Tween 80, on the phenanthrene degradation were examined. Therefore, this strain may find great application in bioremediation practices. PMID:18930349

  10. Isolation and characterization of Methanoculleus receptaculi sp. nov. from Shengli oil field, China.

    PubMed

    Cheng, Lei; Qiu, Tian-Lei; Li, Xia; Wang, Wei-Dong; Deng, Yu; Yin, Xiao-Bo; Zhang, Hui

    2008-08-01

    Three strictly anaerobic, thermophilic methanogens (ZC-2T, ZC-3 and ZC-6) were isolated from Shengli oil field, China. The 16S rRNA gene sequences of the three strains were nearly identical, possessing > 99.8% sequence similarity. They also possessed high sequence similarity, 97.4%, to Methanoculleus palmolei strain INSLUZ(T) (97.4% and 97.5%, respectively), indicating that they represented a novel species within the genus Methanoculleus. Cells of strain ZC-2T were nonmotile cocci, 0.8-1.7 microm in diameter, and always occurred singly or in pairs. The three strains used H2/CO2 or sodium formate as substrates for methanogenesis but not sodium acetate, trimethylamine, monomethylamine, ethanol, dimethyl sulfide, isopropanol, isobutanol, butan-2-ol or H2/CO. Optimum growth of strain ZC-2T occurred in the presence of 0.2 M NaCl, pH 7.5-7.8 and temperature 50-55 degrees C with a specific growth rate of 0.084 h(-1). The mol% G+C content of the genomic DNA was 55.2 mol%. Based on these phenotypic and phylogenetic characteristics, strains ZC-2T, ZC-3 and ZC-6 are proposed to represent a novel species in the genus Methanoculleus and named Methanoculleus receptaculi sp. nov. The type strain is ZC-2T (CGMCC 1.5087T=DSM 18860T). PMID:18557787

  11. Risk analyses for disposing of nonhazardous oil field wastes in salt caverns

    SciTech Connect

    Tomasko, D.; Elcock, D.; Veil, J.

    1997-09-01

    Argonne National Laboratory (ANL) has completed an evaluation of the possibility that adverse human health effects (carcinogenic and noncarcinogenic) could result from exposure to contaminants released from nonhazardous oil field wastes (NOW) disposed of in domal salt caverns. In this assessment, several steps were used to evaluate potential human health risks: identifying potential contaminants of concern; determining how humans could be exposed to these contaminants; assessing the contaminants` toxicities; estimating contaminant intakes; and, finally, calculating human cancer and noncancer risks. Potential human health risks associated with hazardous substances (arsenic, benzene, cadmium, and chromium) in NOW were assessed under four postclosure cavern release scenarios: inadvertent cavern intrusion, failure of the cavern seal, failure of the cavern through cracks or leaky interbeds, and a partial collapse of the cavern roof. To estimate potential human health risks for these scenarios, contaminant concentrations at the receptor were calculated using a one-dimensional solution to an advection/dispersion equation that included first order degradation. Even under worst-case conditions, the risks have been found to be within the US EPA target range for acceptable exposure levels. From a human health risk perspective, salt caverns can provide an acceptable disposal method for NOW.

  12. Aneth oil field, giant carbonate stratigraphic trap, Paradox basin, Utah, U. S. A

    SciTech Connect

    Petterson, J.A. )

    1991-03-01

    The Aneth oil field (approximately 400 million bbl original primary reserves) occurs within an isolated southeast-northwest-trending Pennsylvanian (Desmoinesian) algal carbonate bank buildup located approximately 25 mi (40 km) basinward of the main carbonate shelf of the Paradox basin in Utah. Desmoinesian deposition was strongly cyclic, with as many as 30 main evaporite-carbonate cycles recognized. The Aneth algal bank is part of the Desert Creek cycle, which is the first cycle above that of the most widespread salt-bearing cycle. The Desert Creek carbonate facies grades basinward to increasingly prevalent evaporite facies, dominated by thick salt beds in the basin center. Within the isolated algal-mound facies, the Desert Creek cycle is characterized by a vertical succession that includes (1) basal black, organic-rich, dolomitic, silty shale, (2) overlying dark chalky, finely crystalline dolomite, which grades upward into (3) the main carbonate mound facies, dominated by accumulations of calcareous, leafy green algae with associated brachiopods, fusulinids, small foraminifera, ostracodes, and rare corals. Mound buildups are overlain by a relatively thin, black, organic-rich shale unit, the basal bed of the succeeding mound-bearing Ismay cycle. This unit thickens markedly on the flanks of the Desert Creek and other mound buildup. Interrelated depositional processes of these various sedimentary facies have resulted in a close association between source rock, large reservoir, and seal at Aneth, and contributed significantly toward the large size of the Aneth accumulation.

  13. Aneth oil field carbonate mound reservoir - Organic-rich mudbank origin

    SciTech Connect

    Peterson, J.A. )

    1989-09-01

    The Aneth oil field (approximately 400 million bbl ultimate recovery) occurs within an isolated southeast-northwest-trending Pennsylvanian (Desmoinesian) algal carbonate bank buildup located approximately 25 mi (40 km) basinward of the main carbonate shelf of the Paradox basin in Utah. Desmoinesian deposition was strongly cyclic, with as many as 30 main evaporite-carbonate cycles recognized. The Aneth algal bank is part of the Desert Creek cycle, which is the first cycle above that of the most widespread salt-bearing cycle. The Desert Creek carbonate facies grades basinward to increasingly prevalent evaporite facies, dominated by thick salt beds in the basin center. Within the isolated algal-mound facies, the Desert Creek cycle is characterized by a vertical succession that includes (1) basal black, organic-rich, dolomitic, silty shale, and (2) overlying dark chalky, finely crystalline dolomite which grades upward into (3) the main carbonate mound facies dominated by accumulations of calcareous, leafy green algae with associated brachiopods, fusulinids, small foraminifera, ostracods, and, rarely, corals. Mound buildups are overlain by a relatively thin, black, organic-rich shale unit, the basal bed of the succeeding mound-bearing Ismay cycle. This upper shale unit thickens markedly on the flanks of the Desert Creek and other mounds.

  14. A perfluorocarbon tracer transport and dispersion experiment in the North Sea Ekofisk oil field

    SciTech Connect

    Senum, G.I.; Dietz, R.N.; D'Ottavio, T.W.; Goodrich, R.W.; Cote, E.A.; Spandau, D.J.

    1989-12-01

    A perfluorocarbon tracer (PFT) transport and dispersion experiment has been performed in the Ekofisk section of the North Sea oil fields. Fifty grams each of three PFTs were injected into a well and 28 surrounding wells were sampled for the presence of PFT. Sampling was accomplished by initially collecting bottles of reservoir hydrocarbon gas and subsequently transferring 5 liter (gas phase) aliquots onto Capillary Adsorbent Tracer (CAT) samplers. The resulting CATS samplers were analyzed for PFT in a specially configured laboratory gas chromatograph with electron capture detection. The limit of detection for PFT as determined by standard addition experiments was circa 1 to 10 femtoliters (10{sup {minus}15} L) per liter of sampled reservoir gas. Sampling was performed up to two years past the injection time; approximately two hundred samples were analyzed. PFT was performed only in four sampling wells at four different times, though the PFT analysis of earlier samples lack sufficient sensitivity to PFT detection due to a hydrocarbon interferent problem which was resolved during this experiment. The PFT concentrations observed in these four wells appeared to follow an exponential dilution law with a dilution half-life of approximately 70 days in the reservoir. Recommendations for future experiments of this nature are made based on the problems encountered in this initial study. 4 refs., 28 figs., 10 tabs.

  15. A perfluorocarbon tracer transport and dispersion experiment in the North Sea Ekofisk oil field

    SciTech Connect

    Senum, G.I.; Dietz, R.N.; D'Ottavio, T.W.; Goodrich, R.W.; Cote, E.A.; Spandau, D.J.

    1990-07-01

    A perfluorocarbon tracer (PFT) transport and dispersion experiment has been performed in the Ekofisk section of the North Sea Oil fields. Fifty grams each of three PFTs were injected into a well and 28 surrounding wells were sampled for the presence of PFT. Sampling was accomplished by initially collecting bottles of reservoir hydrocarbon gas and subsequently transferring 5 liter (gas phase) aliquots onto Capillary Adsorbent Tracer (CAT) samplers. The resulting CATS samplers were analyzed for PFT in a specially configured laboratory gas chromatograph with electron capture detection. The limit of detection for PFT as determined by standard addition experiments was circa 1 to 10 femtoliters (10{sup {minus}15} L) per liter of sampled reservoir gas. Sampling was performed up to two years past the injection time; approximately two hundred samples were analyzed. PFT was observed only in four sampling wells at four different times, though the PFT analysis of earlier samples lack sufficient sensitivity to PFT detection due to a hydrocarbon interferent problem which was resolved during this experiment. 5 refs., 28 figs.

  16. Modified vegetation indices for Ganoderma disease detection in oil palm from field spectroradiometer data

    NASA Astrophysics Data System (ADS)

    Shafri, Helmi Z. M.; Anuar, M. Izzuddin; Saripan, M. Iqbal

    2009-10-01

    High resolution field spectroradiometers are important for spectral analysis and mobile inspection of vegetation disease. The biggest challenges in using this technology for automated vegetation disease detection are in spectral signatures pre-processing, band selection and generating reflectance indices to improve the ability of hyperspectral data for early detection of disease. In this paper, new indices for oil palm Ganoderma disease detection were generated using band ratio and different band combination techniques. Unsupervised clustering method was used to cluster the values of each class resultant from each index. The wellness of band combinations was assessed by using Optimum Index Factor (OIF) while cluster validation was executed using Average Silhouette Width (ASW). 11 modified reflectance indices were generated in this study and the indices were ranked according to the values of their ASW. These modified indices were also compared to several existing and new indices. The results showed that the combination of spectral values at 610.5nm and 738nm was the best for clustering the three classes of infection levels in the determination of the best spectral index for early detection of Ganoderma disease.

  17. Activities of the Oil Implementation Task Force, reporting period March--August 1991; Contracts for field projects and supporting research on enhanced oil recovery, reporting period October--December 1990

    SciTech Connect

    Not Available

    1991-10-01

    Activities of DOE's Oil Implementation Task Force for the period March--August 1991 are reviewed. Contracts for fields projects and supporting research on enhanced oil recovery are discussed, with a list of related publications given. Enhanced recovery processes covered include chemical flooding, gas displacement, thermal recovery, and microbial recovery.

  18. Near-tip-screenout hydraulic fracturing of oil wells in the Bach Ho field, offshore Vietnam

    SciTech Connect

    Hung, L.V.; San, N.T.; Shelomentsev, A.G.; Tronov, J.A.; Lam, D.D.; Thomas, R.L.; Fox, T.; Bisdikian, C.

    1995-10-01

    The first hydraulic fracturing of wells in Vietnam were successfully performed Offshore in the Bach Ho (White Tiger) Oil Field. Near-tip-screenouts rather than tip-screenout treatments were performed. The goal of the project was to improve production from existing wells rather than drill new wells and reduce the cost per barrel produced. This case study involves wells with multiple perforated zones completed in the Oligocene sandstone. Zones were selectively fractured in order to optimize production. A detailed description candidate selection, design, execution and evaluation processes are presented. The Bach Ho field has been producing for 8 years but not at its potential due to various reasons including drilling and completion fluid damage. Although acidizing was an option for damage removal, hydraulic fracturing was selected as a way to bypass near-wellbore damage and generate a negative skin. Production simulators were used to quantify post-frac production. Due to suspected high closure stress, high strength proppant was selected and ramped in a high temperature fracturing fluid. Calibration treatments were conducted on several wells to quantify fluid leak-off, fracture height and Young`s modulus. Based on the results of the calibration treatment, fracture designs were modified. As predicted by computer simulation, near-tip-screenouts occurred as planned. The treatments were performed using a work boat with skid pumping/blending equipment, a computer monitoring/operation center and a laboratory. Strict QC procedures were followed to ensure the quality of all products. Post-frac well tests results and production data are presented. Overall, the fracturing campaign was very successful with wells showing negative skins and up to a five fold increase of production in agreement with systems analysis predictions.

  19. A Field-Scale Simulation of the Reversible Nanoparticle Adsorption for Enhancing Oil Recovery Using Hydrophilic Nanofluids

    NASA Astrophysics Data System (ADS)

    Cao, Liyuan

    In order to develop and apply nanotechnology in oil industry, nanoparticles transport in porous media has been studied in the past few years. Theoretical modeling were carried out to evaluate nanoparticle mobility and investigate nanoparticle retention mechanism. In this study, a simulator based on Ju and Fan's mathematical model was used to study nanoparticles transport in porous media on a reservoir scale. The simulator was verified with two simulation software, Eclipse from Schlumberger and MNM1D (Micro- and Nanoparticle transport Model in porous media in 1D geometry) developed by Tosco et al. Different injection scenarios were simulated: continuous injection, slug injection, and postflush. The effect of injection time, injection rate, and slug size on oil recovery were studied. The result discovered that when nanofluids flooding is used after water flooding as tertiary recovery method, early nanofluids injection will lead to higher oil recovery, but with more nanoparticle loss. Higher injection rate of nanofluids could help improve the flooding efficiency, but not the ultimate oil recovery for field development. Also, it can cause more nanoparticle loss. Brine water postflush is recommended when doing nanoflooding. It can significantly improve the recovery of nanoparticles, and for a homogeneous or heterogeneous reservoir, oil recovery is better compared to water flooding.

  20. A procedure to estimate the parent population of the size of oil and gas fields as revealed by a study of economic truncation

    USGS Publications Warehouse

    Schuenemeyer, J.H.; Drew, L.J.

    1983-01-01

    An estimation technique has been derived to predict the number of small fields in a geologic play or basin. Historically, many small oil and gas fields went unreported because they were not economical. This led to an underestimation of the number of undiscovered small fields. A study of the distributions of reported oil and gas fields in well-explored areas suggests that the large fields when grouped into log base 2 size classes are geometrically distributed. Further, the number of small fields reported is a function of the cost of exploration and development. Thus, the population field-size distribution is conjectured to be log geometric in form. ?? 1983 Plenum Publishing Corporation.

  1. ENVIRONMENTAL CHARACTERIZATION OF GEOKINETICS' IN-SITU OIL SHALE RETORTING TECHNOLOGY: FIELD AND ANALYTICAL DATA APPENDICES

    EPA Science Inventory

    Air emissions and water effluents from true in-situ oil shale retorting were physically, chemically and biologically characterized by sampling of Geokinetics Retort No. 17, a pilot-scale unit which produced 30 barrels of crude shale oil per day during testing from July 16 to July...

  2. Field Evaluation of Essential Oils for Reducing Attraction by the Japanese Beetle (Coleoptera: Scarabaeidae)

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This study evaluated 47 commercial plant-derived essential oils individually or as blends for their potential as adult Japanese beetle (Popillia japonica Newman) repellents during 2003 to 2007. A bioassay procedure used traps to evaluate whether essential oils could repel beetles from Japanese beet...

  3. Effectiveness of Zanthoxylum piperitum-derived essential oil as an alternative repellent under laboratory and field applications.

    PubMed

    Kamsuk, K; Choochote, W; Chaithong, U; Jitpakdi, A; Tippawangkosol, P; Riyong, D; Pitasawat, B

    2007-01-01

    Recently, there were considerable efforts made to promote the use of environmentally friendly and biodegradable natural insecticides and repellents, particularly from botanical sources. In this study, Zanthoxylum piperitum-derived essential oil isolated by steam distillation was investigated and compared to the standard synthetic repellent, N,N-diethyl-3-methylbenzamide (DEET), for repellency against mosquitoes under laboratory and field conditions. The oil of Z. piperitum alone and also with 5% vanillin added repelled laboratory-reared female Aedes aegypti with the median protection times of 1.5 and 2.5 h, respectively. These repellency times were proven to be significantly lower than those of DEET-based products: 25% DEET and 25% DEET + 5% vanillin demonstrating 3.5 and 5.5 h, respectively. However, when applied under field conditions, Z. piperitum oil + 5% vanillin was found to provide better protection against a wide range of natural mosquito populations than 25% DEET + 5% vanillin. While the product of DEET was effective in reducing bites with 99.7% protection, the protective effect of Z. piperitum oil product appeared complete (100%). It had a protective effect against Aedes gardnerii, Anopheles barbirostris, Armigeres subalbatus, Culex tritaeniorhynchus, Culex gelidus, Culex vishnui group, and Mansonia uniformis. The better repellency against a wide range of field mosquitoes derived from Z. piperitum oil products suggested an advantage of efficacy by providing a broad spectrum of activity. Therefore, Z. piperitum could have potential for use in the development of combined repellents as a natural active ingredient, synergist, or additive to conventional synthetic chemicals, particularly in situations when DEET is ineffective and impractical. PMID:16896651

  4. Geological emission of methane from the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China.

    PubMed

    Tang, Junhong; Bao, Zhengyu; Xiang, Wu; Gou, Qinghong

    2008-01-01

    A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry (GC/C/MS) together, the 13C/12C ratios of methane in the flux chambers were measured. The results demonstrated that methane gases were liable to migrate from deep oil/gas reservoir to the surface through microseepage and pervasion, and that a part of the migrated methane that remained unoxidized could emit into the atmosphere. Methane emission rates varied less in the oil/gas field because the whole region was homogeneous in geology and geography, with a standard deviation of less than 0.02 mg/(m2 x h). These were the differences in methane emission flux in the day and at night in the oil/gas field. The maximum methane emission flux reached 0.15 mg/(m2 x h) at 5:00-6:00 early in the morning, and then decreased gradually. The minimum was shown 0.10 mg/(m2 x h) at 17:00-18:00 in the afternoon, and then increased gradually. The daily methane released flux of the study area was 2.89 mg/(m2 x d), with a standard deviation of 0.43 mg/(m2 x d), using the average methane flux of every hour in a day for all chambers. delta13C of methane increased with the increase of methane concentration in the flux chambers, further indicating that the pyrogenetic origin of methane was come from deep oil/gas reservoirs. PMID:19143311

  5. Costs for off-site disposal of nonhazardous oil field wastes: Salt caverns versus other disposal methods

    SciTech Connect

    Veil, J.A.

    1997-09-01

    According to an American Petroleum Institute production waste survey reported on by P.G. Wakim in 1987 and 1988, the exploration and production segment of the US oil and gas industry generated more than 360 million barrels (bbl) of drilling wastes, more than 20 billion bbl of produced water, and nearly 12 million bbl of associated wastes in 1985. Current exploration and production activities are believed to be generating comparable quantities of these oil field wastes. Wakim estimates that 28% of drilling wastes, less than 2% of produced water, and 52% of associated wastes are disposed of in off-site commercial facilities. In recent years, interest in disposing of oil field wastes in solution-mined salt caverns has been growing. This report provides information on the availability of commercial disposal companies in oil-and gas-producing states, the treatment and disposal methods they employ, and the amounts they charge. It also compares cavern disposal costs with the costs of other forms of waste disposal.

  6. IMPROVED OIL RECOVERY FROM UPPER JURASSIC SMACKOVER CARBONATES THROUGH THE APPLICATION OF ADVANCED TECHNOLOGIES AT WOMACK HILL OIL FIELD, CHOCTAW AND CLARKE COUNTIES, EASTERN GULF COASTAL PLAIN

    SciTech Connect

    Ernest A. Mancini

    2003-05-20

    Pruet Production Co. and the Center for Sedimentary Basin Studies at the University of Alabama, in cooperation with Texas A&M University, Mississippi State University, University of Mississippi, and Wayne Stafford and Associates are undertaking a focused, comprehensive, integrated and multidisciplinary study of Upper Jurassic Smackover carbonates (Class II Reservoir), involving reservoir characterization and 3-D modeling and an integrated field demonstration project at Womack Hill Oil Field Unit, Choctaw and Clarke Counties, Alabama, Eastern Gulf Coastal Plain. The principal objectives of the project are: increasing the productivity and profitability of the Womack Hill Field Unit, thereby extending the economic life of this Class II Reservoir and transferring effectively and in a timely manner the knowledge gained and technology developed from this project to producers who are operating other domestic fields with Class II Reservoirs. The principal research efforts for Year 3 of the project have been recovery technology analysis and recovery technology evaluation. The research focus has primarily been on well test analysis, 3-D reservoir simulation, microbial core experiments, and the decision to acquire new seismic data for the Womack Hill Field area. Although Geoscientific Reservoir Characterization and 3-D Geologic Modeling have been completed and Petrophysical and Engineering Characterization and Microbial Characterization are essentially on schedule, a no-cost extension until September 30, 2003, has been granted by DOE so that new seismic data for the Womack Hill Field can be acquired and interpreted to assist in the determination as to whether Phase II of the project should be implemented.

  7. Enigmatic organosiliceous rocks in the 2000 Ma petrified oil field in Russian Fennoscandia

    NASA Astrophysics Data System (ADS)

    Deines, Yu.; Melezhik, V.; Lepland, A.; Filippov, M.; Romashkin, A.; Rychanchik, D.

    2009-04-01

    The c. 2000 Ma, 900 m-thick, Zaonezhskaja Formation in the Onega basin, Russian Fennoscandia, contains one of the greatest accumulations of organic matter (OM) in the Early Precambrian. It also represents a unique preservation of a supergiant petrified oil field. Zaonezhskaja Formation rocks are greenschist-facies volcaniclastic greywackes (distal turbidites), dolostone and limestones, mafic tuffs and lavas intruded by numerous mafic sills. Several sedimentary beds are enriched in OM with the overall content of total organic carbon (TOC) ranging from 0.1 to 16 wt.% whereas d13C varies between -44 and -17 per mil(V-PDB). The formation contains plentiful evidence of generation and migration of oil (now petrified) as well as oil traps. Results of geophysical surveys combined with drillcore data, including results recently obtained within the framework of the Fennoscandian Arctic Russia - Drilling Early Earth Project (FAR-DEEP), revealed numerous bodies of organosiliceous rocks (OSR) containing mainly silica (c. 57 wt.% SiO2), organic carbon (up to 40 wt.%), Al2O3 (c. 5 wt.%), S (c. 2 wt.%), and minor K, Mg, Fe, Ca and Ti. d13C of the OSR ranges between -40 and -20 per mil. The OSR form crudely stratified beds, cupola-like bodies or veins. The cupola-like bodies show cross-cutting (intrusive) contacts with the host turbiditic greywackes, reach thicknesses of 120 m with a lateral extent of several hundreds of metres. Veins are a few tens of centimetres thick. The OSR show close spatial association with gabbro sills. Although different fabrics have been recognised in the OSR, syngenetic macro- and microbreccias per se are the most common rock types. Fragments of different sedimentary rocks, as well as those with alternating C-rich and C-poor concentric lamina are present. The latter suggests precipitation from hydrothermal fluids. The nature of the OSR remains enigmatic. Several models have been advanced for explanation of origin of the OSR. However, neither of them could explain the source, and joint transport of two major components, namely silica and OM. We propose a model involving a hydrothermal system initiated by heat produced during the emplacement of numerous mafic intrusive bodies. Such heat may have created the necessary temperature gradient for earlier oil generation, thermal oil to gas cracking, and initiation of shallow-seated, sub-surface, hydrothermal circulation. The proposed result would have been the mingling of silica leached from mafic rocks with hydrocarbon, and gas (primarily CO2, CH4) extracted from the host sedimentary rocks. Such a gas-rich C-Si-H2O substance would have migrated into permeable beds. A high sedimentation rate, as expected in many turbiditic depositional environments, would have produced a high lithostatic pressure on to unlithified beds during the course of the basin subsidence. This would have forced gas-rich C-Si-H2O fluids that moved either laterally along permeable beds or vertically along zones of weakness. In the first case, sediments 'impregnated' with gas-rich C-Si-H2O fluids would have formed stratigraphic beds of OSR, whereas in the second case the result would been crosscutting veins. Beds may retain some primary layering, whereas veins do not. If veins reached the seafloor, the sediment - C-Si-H2O mush would have extruded in the form of a mud volcano / hydrothermal mound, and thus formed a cupola-like morphology. During the course of compression, the sediment - C-Si-H2O mush might have experienced several stages of partial lithification, as well as fluidisation processes leading to the formation of several generations of micro- and macro-brecciated rocks. The large d13C range of reduced carbon in the OSR suggests a complex maturation process of the biogenic OM. Further detailed microstructural, geochemical, isotopic and biomarker studies are planned for distinguishing between biological and abiological processes involved in the formation of the enigmatic OSR.

  8. Late diagenetic indicators of buried oil and gas: II, Direct detection experiment at Cement and Garza oil fields, Oklahoma and Texas, using enhanced LANDSAT I and II images

    USGS Publications Warehouse

    Donovan, Terrence J.; Termain, Patricia A.; Henry, Mitchell E.

    1979-01-01

    The Cement oil field, Oklahoma, was a test site for an experiment designed to evaluate LANDSAT's capability to detect an alteration zone in surface rocks caused by hydrocarbon microseepage. Loss of iron and impregnation of sandstone by carbonate cements and replacement of gypsum by calcite are the major alteration phenomena at Cement. The bedrock alterations are partially masked by unaltered overlying beds, thick soils, and dense natural and cultivated vegetation. Interpreters biased by detailed ground truth were able to map the alteration zone subjectively using a magnified, filtered, and sinusoidally stretched LANDSAT composite image; other interpreters, unbiased by ground truth data, could not duplicate that interpretation. Similar techniques were applied at a secondary test site (Garza oil field, Texas), where similar alterations in surface rocks occur. Enhanced LANDSAT images resolved the alteration zone to a biased interpreter and some individual altered outcrops could be mapped using higher resolution SKYLAB color and conventional black and white aerial photographs suggesting repeat experiments with LANDSAT C and D.

  9. How clean is clean enough? Maintaining thermal protective clothing under field conditions in the oil and gas sector.

    PubMed

    Crown, Elizabeth M; Feng, Aifen; Xu, Xia

    2004-01-01

    The purpose of this research was to develop practical care procedures to help maintain the protective quality of flame resistant workwear laundered by workers in the field. Based on observed field conditions, experiments were conducted that simulated domestic laundry procedures. The first experiment involved two flame resistant (FR) fabrics, contaminated or not contaminated with oil. Independent variables also included detergent type and laundry pre-treatment. Other laundry parameters were controlled. Results indicated that it is easier to maintain the FR performance of the FR-treated blend than it is for the aramid fabric. It is hypothesized that energy generated by initial ignition of oil on the specimens triggers the FR mechanism of the treatment, which in turn inhibits further combustion. A second experiment using larger specimens and a domestic washing machine also supported the hypothesized mechanism. PMID:15377409

  10. The influence of bioaugmentation and biosurfactant addition on bioremediation efficiency of diesel-oil contaminated soil: feasibility during field studies.

    PubMed

    Szulc, Alicja; Ambrożewicz, Damian; Sydow, Mateusz; Ławniczak, Łukasz; Piotrowska-Cyplik, Agnieszka; Marecik, Roman; Chrzanowski, Łukasz

    2014-01-01

    The study focused on assessing the influence of bioaugmentation and addition of rhamnolipids on diesel oil biodegradation efficiency during field studies. Initial laboratory studies (measurement of emitted CO2 and dehydrogenase activity) were carried out in order to select the consortium for bioaugmentation as well as to evaluate the most appropriate concentration of rhamnolipids. The selected consortium consisted of following bacterial taxa: Aeromonas hydrophila, Alcaligenes xylosoxidans, Gordonia sp., Pseudomonas fluorescens, Pseudomonas putida, Rhodococcus equi, Stenotrophomonas maltophilia, Xanthomonas sp. It was established that the application of rhamnolipids at 150 mg/kg of soil was most appropriate in terms of dehydrogenase activity. Based on the obtained results, four treatment methods were designed and tested during 365 days of field studies: I) natural attenuation; II) addition of rhamnolipids; III) bioaugmentation; IV) bioaugmentation and addition of rhamnolipids. It was observed that bioaugmentation contributed to the highest diesel oil biodegradation efficiency, whereas the addition of rhamnolipids did not notably influence the treatment process. PMID:24291585

  11. LANDSAT Study of Alteration Aureoles in Surface Rocks Overlying Petroleum Deposits. [Cement and Davenport oil fields, Oklahoma

    NASA Technical Reports Server (NTRS)

    Donovan, T. J. (Principal Investigator)

    1975-01-01

    The author has identified the following significant results. A series of low altitude underflight remote sensing experiments were flown at Cement and Davenport oil fields, Oklahoma. An experimental algorithm which employs a sinusoidal stretch of brightness values was developed and applied to a January 1973 scene (bands 4, 5, and 6) of Cement. The results, although not spectacular, are extremely encouraging and for the first time demonstrate that the alteration anomaly at Cement may be defined through enhanced LANDSAT images.

  12. Contracts for field projects and supporting research on enhanced oil recovery. Progress review number 86, quarter ending March 31, 1996

    SciTech Connect

    1997-05-01

    Summaries are presented for 37 enhanced oil recovery contracts being supported by the Department of Energy. The projects are grouped into gas displacement methods, thermal recovery methods, geoscience technology, reservoir characterization, and field demonstrations in high-priority reservoir classes. Each summary includes the objectives of the project and a summary of the technical progress, as well as information on contract dates, size of award, principal investigator, and company or facility doing the research.

  13. Insecticidal Potential of Clove Essential Oil and Its Constituents on Cacopsylla chinensis (Hemiptera: Psyllidae) in Laboratory and Field.

    PubMed

    Tian, Bao-Liang; Liu, Qi-Zhi; Liu, Zhi-Long; Li, Peng; Wang, Jie-Wen

    2015-06-01

    Cacopsylla chinensis (Yang and Li) (Hemiptera: Psyllidae) is an important pest of pear in China. As an alternative to conventional chemical pesticides, botanicals including essential oils and their constituents could provide an eco-friendly and nonhazardous control method. In this study, the essential oil of clove buds (Syzygium aromaticum) was obtained by hydrodistillation. Five constituents, accounting for 99.89% of the oil, were identified by gas chromatography-mass spectrometry, and the major constituents were eugenol (88.61%) and eugenol acetate (8.89%), followed by β-caryophyllene (1.89%). In a laboratory bioassay, clove essential oil, commercial eugenol (99.00%) and β-caryophyllene (98.00%) exhibited strong contact toxicity against the summerform adults of C. chinensis with LD50 values of 0.730, 0.673, and 0.708 µg/adult, and against the nymphs with LD50 values of 1.795, 1.668, and 1.770 µg/nymph, respectively. In contrast, commercial eugenol acetate (98%) had LD50 values of 9.266 µg/adult and 9.942 µg/nymph. In a field trial, clove essential oil caused significant population reductions of 73.01% (4.80 mg/ml), 66.18% (2.40 mg/ml) and 46.56% (1.20 mg/ml), respectively. Our results demonstrated that clove essential oil and its constituents have potential as a source of natural insecticides. PMID:26470216

  14. Salvaging dipmeters using an oil field {open_quotes}Dinosaur{close_quotes}

    SciTech Connect

    Breimayer, A.R.P.; Puzio, L.B.

    1996-09-01

    Although state-of-the-art methods such as 3-D seismic and formation imaging tools are widely used, the advantages of the old standard dipmeter should not be dismissed. Seismic dip is subject to velocity errors, and formation imagers cannot be run in all borehole conditions. The dipmeter offers a relatively low cost, highly effective alternative for defining geologic features. The 60{double_prime}= 100{prime} scale playback of the raw dipmeter data may be an oil field {open_quotes}dinosaur,{close_quotes} but it is also the key to assessing the reliability of a dipmeter. This playback should be used to determine CORRELATION QUALITY, critical to the accuracy of any dipmeter. Computer computation of the raw dipmeter data does not always yield reliable dip information, particularly when dipmeters are run under adverse hole conditions or in complex geology. This data can be often salvaged by optical correlation of the 60{close_quote} playback - the process of manually correlating raw dipmeter resistivity curves to determine the attitude of bedding planes in the subsurface. Problems such as tool noise, tool pulls, and poor pad contact compromise data quality. These problems can be recognized and compensated for using optical correlation. Finally, at the 60{double_prime} scale many formation textures and structural characteristics visible on the formation imaging logs are also discernible on the standard dipmeter traces. We will offer many Gulf Coast examples and some hands-on demonstrations using the 60{double_prime} data, and show improved tadpole plots which result from optical correlation.

  15. Effect of Nitrate Injection on the Microbial Community in an Oil Field as Monitored by Reverse Sample Genome Probing

    PubMed Central

    Telang, A. J.; Ebert, S.; Foght, J. M.; Westlake, D.; Jenneman, G. E.; Gevertz, D.; Voordouw, G.

    1997-01-01

    The reverse sample genome probe (RSGP) method, developed for monitoring the microbial community in oil fields with a moderate subsurface temperature, has been improved by (i) isolation of a variety of heterotrophic bacteria and inclusion of their genomes on the oil field master filter and (ii) use of phosphorimaging technology for the rapid quantitation of hybridization signals. The new master filter contains the genomes of 30 sulfate-reducing, 1 sulfide-oxidizing, and 16 heterotrophic bacteria. Most have been identified by partial 16S rRNA sequencing. Use of improved RSGP in monitoring the effect of nitrate injection in an oil field indicated that the sulfide-oxidizing, nitrate-reducing isolate CVO (a Campylobacter sp.) becomes the dominant community component immediately after injection. No significant enhancement of other community members, including the sulfate-reducing bacteria, was observed. The elevated level of CVO decayed at most sampling sites within 30 days after nitrate injection was terminated. Chemical analyses indicated a corresponding decrease and subsequent increase in sulfide concentrations. Thus, transient injection of a higher potential electron acceptor into an anaerobic subsurface system can have desirable effects (i.e., reduction of sulfide levels) without a permanent adverse influence on the resident microbial community. PMID:16535595

  16. Investigation of Diospyros Kaki L.f husk extracts as corrosion inhibitors and bactericide in oil field

    PubMed Central

    2013-01-01

    Background Hydrochloric acid is used in oil-well acidizing commonly for improving the crude oil production of the low-permeable reservoirs, while it is a great challenge for the metal instruments involved in the acidification. Developing natural products as oilfield chemicals is a straight way to find less expensive, green and eco-friendly materials. The great plant resources in Qin-ling and Ba-shan Mountain Area of Shannxi Province enable the investigating of new green oil field chemicals. Diospyros Kaki L.f (persimmon), a famous fruit tree is widely planted in Qin-ling and Ba-shan Mountain Area of Shaanxi Province. It has been found that the crude persimmon extracts are complex mixtures containing vitamins, p-coumaric acid, gallic acid, catechin, flavonoids, carotenoids and condensed tannin and so on, which indicates the extracts of persimmon husk suitable to be used as green and eco-friendly corrosion inhibitors. Findings Extracts of persimmon husk were investigated, by using weight loss and potentiodynamic polarisation techniques, as green and eco-friendly corrosion inhibitors of Q235A steel in 1M HCl. The inhibition efficiency of the extracts varied with extract concentration from 10 to 1,000 mg/L. There are some synergistic effects between the extracts and KI, KSCN and HMTA. Potentiodynamic polarization studies indicate that extracts are mixed-type inhibitors. Besides, the extracts were screened for antibacterial activity against oil field microorganisms, and they showed good to moderate activity against SRB, IB and TGB. Conclusions The inhibition efficiency of the extracts varied with extract concentration from 10 to 1,000 mg/L, and the highest reaches to 65.1% with the con concentration of 1,000 mg/L WE. KI, KSCN and HMTA they can enhance the IE of WE effectively to 97.3% at most, but not effective for KI and KSCN to AE. Tafel polarisation measurements indicate the extracts behave as mixed type inhibitor. Investigation of the antibacterial activity against oil field microorganism showed the extracts can inhibit SRB, IB and TGB with moderate to highly efficiency under 1,000 mg/L, which makes extracts potential to be used as bifunctional oil field chemicals. PMID:23816431

  17. Pacific region adds fields and technology to stretch and amplify huge oil reserves

    SciTech Connect

    Lyle, D.

    1995-12-01

    The Pacific region combines the best features of the oilpatch with three states that give operators plenty of exploration prospects and two states at the forefront of development technology. The region offers something for everyone, but it has been hamstrung by low oil prices. It looks as if the repeal on the ban on exports Alaskan oil will go a long way toward easing the low-price restriction.

  18. Increasing Waterflood Reserves in the Wilmington Oil Field through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect

    Clarke, D.; Koerner, R.; Moos D.; Nguyen, J.; Phillips, C.; Tagbor, K.; Walker, S.

    1999-04-05

    This project used advanced reservoir characterization tools, including the pulsed acoustic cased-hole logging tool, geologic three-dimensional (3-D) modeling software, and commercially available reservoir management software to identify sands with remaining high oil saturation following waterflood. Production from the identified high oil saturated sands was stimulated by recompleting existing production and injection wells in these sands using conventional means as well as a short radius redrill candidate.

  19. Sources of aeromagnetic anomalies over Cement oil field (Oklahoma), Simpson oil field (Alaska), and the Wyoming-Idaho-Utah thrust belt

    USGS Publications Warehouse

    Reynolds, R.L.; Fishman, N.S.; Hudson, M.R.

    1991-01-01

    Geochemical and rock magnetic studies, undertaken to determine the causes of magnetic anomalies have revealed different magnetic sources developed under different sedimentologic, geochemical, and structural settings. Results show that abiologic and biologic mechanisms can generate different magnetic sulfide minerals in zones of sulfide hydrocarbon seepage. More commonly, sulfidic seepage could either diminish magnetization by replacement of detrital magnetic minerals with nonmagnetic sulfide minerals, or it would have no effect on magnetization if such detrital minerals were originally absent. An important negative result is the absence of abundant secondary (diagenetic) magnetite in the seepage environments. Although secondary magnetite occurs in some biodegraded crude oils, concentrations of such magnetite capable of producing aeromagnetic anomalies have not been documented. -from Authors

  20. Increasing Waterflooding Reservoirs in the Wilmington Oil Field through Improved Reservoir Characterization and Reservoir Management, Class III

    SciTech Connect

    Koerner, Roy; Clarke, Don; Walker, Scott; Phillips, Chris; Nguyen, John; Moos, Dan; Tagbor, Kwasi

    2001-08-07

    This project was intended to increase recoverable waterflood reserves in slope and basin reservoirs through improved reservoir characterization and reservoir management. The particular application of this project is in portions of Fault Blocks IV and V of the Wilmington Oil Field, in Long Beach, California, but the approach is widely applicable in slope and basin reservoirs, transferring technology so that it can be applied in other sections of the Wilmington field and by operators in other slope and basin reservoirs is a primary component of the project.

  1. Fuzzy SPC filter for a feed-forward control system for a three-phase oil field centrifuge.

    SciTech Connect

    Parkinson, W. J. ,; Smith, R. E.; Mortensen, F. N.; Wantuck, P. J.; Jamshidi, Mohammad; Ross, Timothy J.

    2002-01-01

    In this work we describe a signal filter for a feed-forward controller based on the application of fuzzy logic combined with statistical process control (SPC), The feed-forward controller is for a three-phase oil field centrifuge. The centrifuge system is used to separate meta-stable three-phase emulsions consisting of oil and water stabilized by solids. These emulsions are considered to be unusable wastes and must be disposed of in an environmentally acceptable manner. The centrifuge is capable of turning these wastes into clean saleable oil, water that can be reused in an operating process or re-injected into oil wells and, solids that can be disposed of in landfills. The feed-forward controller is used for feed disturbance rejection. It works in conjunction with and, is capable of over-riding the actions of, a feedback controller. The measured feed variables for the feed-forward controller each exhibit reasonably large random fluctuations. It is therefore quite important to use a signal filter that truly recognizes the difference between random noise and a 'caused' event, in order to prevent overriding a perfectly good correction from the feedback controller.

  2. Open-source LCA tool for estimating greenhouse gas emissions from crude oil production using field characteristics.

    PubMed

    El-Houjeiri, Hassan M; Brandt, Adam R; Duffy, James E

    2013-06-01

    Existing transportation fuel cycle emissions models are either general and calculate nonspecific values of greenhouse gas (GHG) emissions from crude oil production, or are not available for public review and auditing. We have developed the Oil Production Greenhouse Gas Emissions Estimator (OPGEE) to provide open-source, transparent, rigorous GHG assessments for use in scientific assessment, regulatory processes, and analysis of GHG mitigation options by producers. OPGEE uses petroleum engineering fundamentals to model emissions from oil and gas production operations. We introduce OPGEE and explain the methods and assumptions used in its construction. We run OPGEE on a small set of fictional oil fields and explore model sensitivity to selected input parameters. Results show that upstream emissions from petroleum production operations can vary from 3 gCO2/MJ to over 30 gCO2/MJ using realistic ranges of input parameters. Significant drivers of emissions variation are steam injection rates, water handling requirements, and rates of flaring of associated gas. PMID:23634761

  3. External magnetic field dependent light transmission and scattered speckle pattern in a magnetically polarizable oil-in-water nanoemulsion

    NASA Astrophysics Data System (ADS)

    Brojabasi, Surajit; Lahiri, B. B.; Philip, John

    2014-12-01

    We study the magnetic field dependent light transmission and scattered speckle pattern in a magnetically polarizable oil-in-water emulsion of droplet diameter ~220 nm, where the direction of propagation of light is parallel to the direction of the external magnetic field. Up to a magnetic field of 50 Gauss, the nanoemulsion remains opaque due to intense Mie scattering. Above 50 Gauss, the transmitted light intensity increases with external magnetic field up to a critical field (BC). Further increase in the magnetic field leads to a reduction in the transmitted intensity. The BC shifts to a lower magnetic field with increasing volume fraction (ϕ) and follows a power law dependence with ϕ, indicating a disorder-order transition. The scattered light intensity at the lobe part is found to increase with external magnetic field. The analysis of the lobe part reveals that the speckle contrast increases with external magnetic field due to the coarsening of the linear chain-like aggregates formed along the direction of the external magnetic field. The angular speckle correlation coefficient is found to be symmetrical on either side of the transmitted bright spot and decays exponentially with measurement angles.

  4. Use of radium isotopes to determine the age and origin of radioactive barite at oil-field production sites

    USGS Publications Warehouse

    Zielinski, R.A.; Otton, J.K.; Budahn, J.R.

    2001-01-01

    Radium-bearing barite (radiobarite) is a common constituent of scale and sludge deposits that form in oil-field production equipment. The barite forms as a precipitate from radium-bearing, saline formation water that is pumped to the surface along with oil. Radioactivity levels in some oil-field equipment and in soils contaminated by scale and sludge can be sufficiently high to pose a potential health threat. Accurate determinations of radium isotopes (226Ra+228Ra) in soils are required to establish the level of soil contamination and the volume of soil that may exceed regulatory limits for total radium content. In this study the radium isotopic data are used to provide estimates of the age of formation of the radiobarite contaminant. Age estimates require that highly insoluble radiobarite approximates a chemically closed system from the time of its formation. Age estimates are based on the decay of short-lived 228Ra (half-life=5.76 years) compared to 226Ra (half-life=1600 years). Present activity ratios of 228Ra/226Ra in radiobarite-rich scale or highly contaminated soil are compared to initial ratios at the time of radiobarite precipitation. Initial ratios are estimated by measurements of saline water or recent barite precipitates at the site or by considering a range of probable initial ratios based on reported values in modern oil-field brines. At sites that contain two distinct radiobarite sources of different age, the soils containing mixtures of sources can be identified, and mixing proportions quantified using radium concentration and isotopic data. These uses of radium isotope data provide more description of contamination history and can possibly address liability issues. Copyright ?? 2000 .

  5. Hydrocarbons and heavy metals in fine particulates in oil field air: possible impacts on production of natural silk.

    PubMed

    Devi, Gitumani; Devi, Arundhuti; Bhattacharyya, Krishna Gopal

    2016-02-01

    Analyses of fine particulates (PM2.5) from the upper Assam oil fields of India indicated considerable presence of higher hydrocarbons (C22-C35) and heavy metals, Cd, Co, Cr, Cu, Ni, Pb, and Zn. This has raised serious concern for the sustainability of the exotic Muga (Antheraea assama) silk production, which has been a prime activity of a large number of people living in the area. The Muga worm feeds on the leaves of Machilus bombycina plant, and the impacts of air quality on its survival were further investigated by analyzing the leaves of the plant, the plantation soil, and the Muga cocoons. PM2.5 content in the air was much more during the winter due to near calm conditions and high humidity. Fourier transform infrared (FTIR), thermogravimetric analysis (TGA), and gas chromatography-mass spectrometer (GC-MS) analysis of PM2.5 showed the presence of higher alkanes (C22-C35) that could be traced to crude oil. Cr, Ni, and Zn were found in higher concentrations in PM2.5, M. bombycina leaves, and the plantation soil indicating a common origin. The winter has been the best period for production of the silk cocoons, and the unhealthy air during this period is likely to affect the production, which is already reflected in the declining yield of Muga cocoons from the area. SEM and protein analyses of the Muga silk fiber produced in the oil field area have exhibited the deteriorating quality of the silk. This is the first report from India on hydrocarbons and associated metals in PM2.5 collected from an oil field and on their possible effects on production of silk by A. assama. PMID:26490906

  6. Increasing heavy oil reservers in the Wilmington oil Field through advanced reservoir characterization and thermal production technologies, technical progress report, October 1, 1996--December 31, 1996

    SciTech Connect

    Hara, S. , Casteel, J.

    1997-05-11

    The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. using advanced reservoir characterization and thermal production technologies. The existing steamflood in the Tar zone of Fault Block (FB) 11-A has been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing a 2100 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  7. Peculiarities of the geologic structure of gigantic gas fields of the western Siberian oil and gas province

    SciTech Connect

    Belyi, N.

    1991-03-01

    The Western Siberian Oil and Gas Province is a unique one regarding the concentration of natural gas resources in Mesozoic terrigenous formations. Discovery of gigantic natural gas fields makes it possible to provide high level of gas production for future prospects. The USSR has enormous potential possibilities for discoveries of new natural gas fields onshore, as well as offshore. At present, three gigantic gas fields have been developed, namely Medvezhie, Urongoi, and Yamburg. The first one has been in operation for 18 years. In the Mesozoic section, three productive complexes can be noticed: Upper Cretaceous, Lower Cretaceous, and Jurassic. The Upper Cretaceous production complex is mostly explored, with unique gas resources containing mainly methane having been discovered. The Lower Cretaceous production complex is characterized by considerable lithofaceous uniformity of reservoirs. Gas pools of this complex contain considerable quantities of condensate quite often having oil rims. The Jurassic production complex, which is characterized by its complicated structure and considerable changeability of the filtration properties, is less studied. Study of the geological structural peculiarities of the gigantic gas fields of Western Siberia gives us the possibility to find new approval for the development and exploration of gas fields.

  8. Excito-repellency of essential oils against an Aedes aegypti (L.) field population in Thailand.

    PubMed

    Boonyuan, Wasana; Grieco, John P; Bangs, Michael J; Prabaripai, Atchariya; Tantakom, Siripun; Chareonviriyaphap, Theeraphap

    2014-06-01

    An investigation of the behavioral responses of Aedes aegypti (= Stegomyia aegypti) to various concentrations of essential oils (2.5, 5, and 10%) extracted from hairy basil (Ocimum americanum Linn), ginger (Zingiber officinale Roscoe), lemongrass (Cymbopogon citratus Stapf), citronella grass (Cymbopogon nardus Rendle), and plai (Zingiber cassumunar Roxb) were performed using an excito-repellency test chamber. Results showed that Ae. aegypti exhibited varying levels of escape response in both the contact and noncontact chambers in response to different essential oils. The magnitude of the behaviors changed in a dose-response fashion depending on the percent volume to volume concentration of oil used. A 2.5% concentration of hairy basil oil produced a significantly greater escape response compared to the other extracts at the same concentration (P< 0.05). Oils of ginger, lemongrass, and citronella produced stronger irritant and repellent responses at the median 5% concentration compared to the lowest and highest concentrations. There was marked suppression of escape for both contact and noncontact tests using 10% concentrations of hairy basil, lemongrass, and citronella, with high knockdown for all three oils after 30 min. Hairy basil and lemongrass had the highest insecticidal activity to Ae. aegypti, with LC50 values of 6.3 and 6.7 percent, respectively. We conclude that the essential oils from native plants tested, and likely many other extracts found in plants, have inherent repellent and irritant qualities that should to be screened and optimized for their behavior-modifying properties against Ae. aegypti and other biting arthropods of public health and pest importance. PMID:24820563

  9. Improved Oil Recovery from Upper Jurassic Smackover Carbonates through the Application of Advanced Technologies at Womack Hill Oil Field, Choctaw and Clarke Counties, Eastern Gulf Costal Plain

    SciTech Connect

    Ernest A. Mancini

    2006-05-31

    Pruet Production Co. and the Center for Sedimentary Basin Studies at the University of Alabama, in cooperation with Texas A&M University, Mississippi State University, University of Mississippi, and Wayne Stafford and Associates proposed a three-phase, focused, comprehensive, integrated and multidisciplinary study of Upper Jurassic Smackover carbonates (Class II Reservoir), involving reservoir characterization and 3-D modeling (Phase I) and a field demonstration project (Phases II and III) at Womack Hill Field Unit, Choctaw and Clarke Counties, Alabama, eastern Gulf Coastal Plain. Phase I of the project has been completed. The principal objectives of the project are: increasing the productivity and profitability of the Womack Hill Field Unit, thereby extending the economic life of this Class II Reservoir and transferring effectively and in a timely manner the knowledge gained and technology developed from this project to producers who are operating other domestic fields with Class II Reservoirs. The major tasks of the project included reservoir characterization, recovery technology analysis, recovery technology evaluation, and the decision to implement a demonstration project. Reservoir characterization consisted of geoscientific reservoir characterization, petrophysical and engineering property characterization, microbial characterization, and integration of the characterization data. Recovery technology analysis included 3-D geologic modeling, reservoir simulation, and microbial core experiments. Recovery technology evaluation consisted of acquiring and evaluating new high quality 2-D seismic data, evaluating the existing pressure maintenance project in the Womack Hill Field Unit, and evaluating the concept of an immobilized enzyme technology project for the Womack Hill Field Unit. The decision to implement a demonstration project essentially resulted in the decision on whether to conduct an infill drilling project in Womack Hill Field. Reservoir performance, multiwell productivity analysis, and reservoir simulation studies indicate that water injection continues to provide stable support to maintain production from wells in the western unitized area of the field and that the strong water drive present in the eastern area of the field is adequate to sustain production from this part of the field. Although the results from the microbial characterization and microbial core experiments are very promising, it is recommended that an immobilized enzyme technology project not be implemented in the Womack Hill Field Unit until live (freshly taken and properly preserved) cores from the Smackover reservoir in the field are acquired to confirm the microbial core experiments to date. From 3-D geologic modeling, reservoir performance analysis, and reservoir simulation, four areas in the Womack Hill Field were identified as prospective infill drilling sites to recover undrained oil from the field. It was determined that the two areas in the unit area probably can be effectively drained by perforating higher zones in the Smackover reservoir in currently producing wells. The two areas in the eastern (non-unitized) part of the field require the drilling of new wells. The successful drilling and testing of a well in 2003 by J. R. Pounds, Inc. has proven the oil potential of the easternmost site in the non-unitized part of the field. Pruet Production Co. acquired new 2-D seismic data to evaluate the oil potential of the westernmost site. Because of the effects of a fault shadow from the major fault bounding the southern border of the Womack Hill Field, it is difficult to evaluate conclusively this potential drill site. Pruet Production Co. has decided not to drill this new well at this time and to further evaluate the new 2-D seismic profiles after these data have been processed using a pre-stack migration technique. Pruet Production Co. has elected not to continue into Phase II of this project because they are not prepared to make a proposal to the other mineral interest owners regarding the drilling of new wells as part of an infill drilling program at this time. Pruet is integrating the reservoir characterization, 3-D geologic modeling, reservoir performance analysis, and reservoir simulation results of the project into their field-scale reservoir management strategy for the Womack Hill Field to improve field operations.

  10. Improved Oil Recovery from Upper Jurassic Smackover Carbonates through the Application of Advanced Technologies at Womack Hill Oil Field, Choctaw and Clarke Counties, Eastern Gulf Coastal Plain

    SciTech Connect

    Ernest A. Mancini

    2003-12-31

    Pruet Production Co. and the Center for Sedimentary Basin Studies at the University of Alabama, in cooperation with Texas A&M University, Mississippi State University, University of Mississippi, and Wayne Stafford and Associates proposed a three-phase, focused, comprehensive, integrated and multidisciplinary study of Upper Jurassic Smackover carbonates (Class II Reservoir), involving reservoir characterization and 3-D modeling (Phase I) and a field demonstration project (Phases II and III) at Womack Hill Field Unit, Choctaw and Clarke Counties, Alabama, eastern Gulf Coastal Plain. Phase I of the project has been completed. The principal objectives of the project are: increasing the productivity and profitability of the Womack Hill Field Unit, thereby extending the economic life of this Class II Reservoir and transferring effectively and in a timely manner the knowledge gained and technology developed from this project to producers who are operating other domestic fields with Class II Reservoirs. The major tasks of the project included reservoir characterization, recovery technology analysis, recovery technology evaluation, and the decision to implement a demonstration project. Reservoir characterization consisted of geoscientific reservoir characterization, petrophysical and engineering property characterization, microbial characterization, and integration of the characterization data. Recovery technology analysis included 3-D geologic modeling, reservoir simulation, and microbial core experiments. Recovery technology evaluation consisted of acquiring and evaluating new high quality 2-D seismic data, evaluating the existing pressure maintenance project in the Womack Hill Field Unit, and evaluating the concept of an immobilized enzyme technology project for the Womack Hill Field Unit. The decision to implement a demonstration project essentially resulted in the decision on whether to conduct an infill drilling project in Womack Hill Field. Reservoir performance, multiwell productivity analysis, and reservoir simulation studies indicate that water injection continues to provide stable support to maintain production from wells in the western unitized area of the field and that the strong water drive present in the eastern area of the field is adequate to sustain production from this part of the field. Although the results from the microbial characterization and microbial core experiments are very promising, it is recommended that an immobilized enzyme technology project not be implemented in the Womack Hill Field Unit until live (freshly taken and properly preserved) cores from the Smackover reservoir in the field are acquired to confirm the microbial core experiments to date. From 3-D geologic modeling, reservoir performance analysis, and reservoir simulation, four areas in the Womack Hill Field were identified as prospective infill drilling sites to recover undrained oil from the field. It was determined that the two areas in the unit area probably can be effectively drained by perforating higher zones in the Smackover reservoir in currently producing wells. The two areas in the eastern (non-unitized) part of the field require the drilling of new wells. The successful drilling and testing of a well in 2003 by J. R. Pounds, Inc. has proven the oil potential of the easternmost site in the non-unitized part of the field. Pruet Production Co. acquired new 2-D seismic data to evaluate the oil potential of the westernmost site. Because of the effects of a fault shadow from the major fault bounding the southern border of the Womack Hill Field, it is difficult to evaluate conclusively this potential drill site. Pruet Production Co. has decided not to drill this new well at this time and to further evaluate the new 2-D seismic profiles after these data have been processed using a pre-stack migration technique. Pruet Production Co. has elected not to continue into Phase II of this project because they are not prepared to make a proposal to the other mineral interest owners regarding the drilling of new wells as part of an infill drilling program at this time. Pruet is integrating the reservoir characterization, 3-D geologic modeling, reservoir performance analysis, and reservoir simulation results of the project into their field-scale reservoir management strategy for the Womack Hill Field to improve field operations.

  11. The Effect of Oregano and Cinnamon Essential Oils on Fermentation Quality and Aerobic Stability of Field Pea Silages.

    PubMed

    Soycan-Önenç, Sibel; Koc, Fisun; Coşkuntuna, Levent; Özdüven, M Levent; Gümüş, Tuncay

    2015-09-01

    This study was performed to determine the effect of field pea silages which were the organic acid (OA) alternative of oregano and cinnamon essential oils on fermentation quality and aerobic stability. Whole crop pea was harvested at full pod stage and wilted in the laboratory at the 48 h. The chopped pea was mixed and divided into equal portions allocated to five groups: CON (non-treated), distilled water, denoted as control group; OA group, a mixture of 60% formic acid, 20% sodium formate and 20% water applied at a rate of 5 g/kg fresh forage (Silofarm Liquid, Farmavet); origanum (ORE) group, Origanum onites essential oil at 400 mg/kg fresh forage; cinnamon (CIN) group, cinnamon essential oil at 400 mg/kg fresh forage; origanum+cinnamon (ORECIN) group, a mixture of ORE and CIN applied at an equal rate of 400 mg/kg fresh forage. Cinnamon decreased acetic acid (AA), ammonia nitrogen (NH3-N) and weight loss (WL) at the end of 60 days silage. Crude protein (CP) and dry matter (DM) increased by cinnamon essential oil. Yeasts were not detected in any treatments, including the control, after 7 days of air exposure. The CO2 amount decreased and the formation mold was inhibited in the aerobic period by the addition of cinnamon oil. Oregano did not show a similar effect, but when it was used with cinnamon, it showed synergic effect on AA and during aerobic period, it showed antagonistic effect on mold formation and DM losses. It was found in this study that cinnamon can be an alternative to organic acids. PMID:26323518

  12. The Effect of Oregano and Cinnamon Essential Oils on Fermentation Quality and Aerobic Stability of Field Pea Silages

    PubMed Central

    Soycan-Önenç, Sibel; Koc, Fisun; Coşkuntuna, Levent; Özdüven, M. Levent; Gümüş, Tuncay

    2015-01-01

    This study was performed to determine the effect of field pea silages which were the organic acid (OA) alternative of oregano and cinnamon essential oils on fermentation quality and aerobic stability. Whole crop pea was harvested at full pod stage and wilted in the laboratory at the 48 h. The chopped pea was mixed and divided into equal portions allocated to five groups: CON (non-treated), distilled water, denoted as control group; OA group, a mixture of 60% formic acid, 20% sodium formate and 20% water applied at a rate of 5 g/kg fresh forage (Silofarm Liquid, Farmavet); origanum (ORE) group, Origanum onites essential oil at 400 mg/kg fresh forage; cinnamon (CIN) group, cinnamon essential oil at 400 mg/kg fresh forage; origanum+cinnamon (ORECIN) group, a mixture of ORE and CIN applied at an equal rate of 400 mg/kg fresh forage. Cinnamon decreased acetic acid (AA), ammonia nitrogen (NH3-N) and weight loss (WL) at the end of 60 days silage. Crude protein (CP) and dry matter (DM) increased by cinnamon essential oil. Yeasts were not detected in any treatments, including the control, after 7 days of air exposure. The CO2 amount decreased and the formation mold was inhibited in the aerobic period by the addition of cinnamon oil. Oregano did not show a similar effect, but when it was used with cinnamon, it showed synergic effect on AA and during aerobic period, it showed antagonistic effect on mold formation and DM losses. It was found in this study that cinnamon can be an alternative to organic acids. PMID:26323518

  13. Increasing heavy oil reserves in the Wilmington oil field through advanced reservoir characterization and thermal production technologies. Quarterly report, July 1 - September 30, 1996

    SciTech Connect

    Hara, S.

    1996-12-01

    The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. using advanced reservoir characterization and thermal production technologies. This is the sixth quarterly technical progress report for the project. Through September 1996, the project continues to make good progress but is slightly behind schedule. Estimated costs are on budget for the work performed to date. Technical achievements accomplished during the quarter include placing the first two horizontal wells on production following cyclic steam stimulation, completing several draft technical reports and preparing presentations on the deterministic geologic model, steam channel crossing and horizontal well drilling for technical transfer. Cyclic steam injection into the first two horizontal wells was completed in June 1996 and initial oil production from the project began the same month. Work has commenced on the stochastic geologic and reservoir simulation models. High temperature core work and reservoir tracer work will commence in the First Quarter 1997.

  14. The effect of an oil drilling operation on the trace metal concentrations in offshore bottom sediments of the Campos Basin oil field, SE Brazil.

    PubMed

    Rezende, C E; Lacerda, L D; Ovalle, A R C; Souza, C M M; Gobo, A A R; Santos, D O

    2002-07-01

    The concentrations of Al, Fe, Mn, Zn, Cu, Pb, Ni, Cr, Ba, V, Sn and As in offshore bottom sediments from the Bacia de Campos oil field, SE Brazil, were measured at the beginning and at 7 months after completion of the drilling operation. Concentrations of Al, Fe, Ba, Cr, Ni and Zn were significantly higher closer to the drilling site compared to stations far from the site. Average concentrations of Al, Cu, and in particular of Ni, were significantly higher at the end of the drilling operation than at the beginning. Comparison between drilling area sediments with control sediments of the continental platform, however, showed no significant difference in trace metal concentrations. Under the operation conditions of this drilling event, the results show that while changes in some trace metal concentrations do occur during drilling operations, they are not significantly large to be distinguished from natural variability of the local background concentrations. PMID:12222892

  15. Clove oil as an anaesthetic for adult sockeye salmon: Field trials

    USGS Publications Warehouse

    Woody, C.A.; Nelson, J.; Ramstad, K.

    2002-01-01

    Wild migrating sockeye salmon Oncorhynchus nerka exposed to 20, 50 and 80 mg 1-1 of clove oil could be handled within 3 min, recovered within 10 min, and survived 15 min exposure trials. Fish tested at 110 mg 1-1 did not recover from 15 min exposure trials. Response curves developed for induction and recovery time considered the following predictors: clove oil concentration, sex, fish length and depth. A significant positive dependence was observed between induction time and fish length for 20, 50 and 80 mg 1-1 test concentrations; no dependence was observed between induction time and length at 110 and 140 mg 1-1. Recovery time differed as a function of clove oil concentration, but not fish size. A concentration of 50 mg 1-1 is recommended for anaesthetizing sockeye salmon ranging in length from 400 to 550 mm at water temperatures averaging 9-10??C.

  16. Composition and dynamics of sulfate-reducing bacteria during the waterflooding process in the oil field application.

    PubMed

    Wei, Li; Ma, Fang; Zhao, Guang

    2010-04-01

    The composition and dynamics of sulfate-reducing bacteria (SRB) during the waterflooding process of Daqing Oilfield were investigated in this study. PCR-DGGE analysis indicated that the microbial communities were significantly different in each treatment unit, and the dominant members were mainly close to Clostridium sp., Thauera sp., Hydrogenophaga sp., Pseudomonas sp., Eubacterium sp. and Arcobacter sp. However, the members belonging to SRB were relatively few and mainly consisted of Desulfovibrio sp. and Desulfovibrio profundus. According to APS (adenosine-5'-phosphosulfate reductase) gene clone library and sequence analysis, it was found that SRB mainly belonged to Proteobacteria and Deltaproteobacteria. In the library, the genus Desulfovibrio of Deltaproteobacteria was about 65.2% while genus Desulfomonas, Desulfomicrobium, Desulfohalobium, Desulfonatronum, Desulfbulbus, Desulforhopalus, Desulfnema and Desulforhopalus were occupied nearly 34.8%. It was also proved that most of SRB in the oil field were enriched in the ground treatment unit and they are not in the liquid of oil well. PMID:20005702

  17. Field establishment of fourwing saltbush in processed oil shale and disturbed native soil as influenced by vesicular-arbuscular mycorrhizae

    SciTech Connect

    Call, C.A.; McKell, C.M.

    1984-04-30

    Seedlings of fourwing saltbush (Atriplex canescens (Pursh) Nutt.) were inoculated with indigenous vesicular-arbuscular mycorrhizal (VAM) fungi in a containerized system and transplanted into processed oil shale and disturbed native soil in a semiarid rangeland environment in northwestern Colorado. After two growing seasons in the field, plants inoculated with VAM had greater aboveground biomass, cover, and height than noninoculated plants. Mycorrhizal plants were more effective in the uptake of water and phosphorus. Infection levels of inoculated plants were greatly reduced in processed shale (from 13.0 at outplanting to 3.8 at harvest), but functional VAM associations could be found after two growing seasons. Results indicate that VAM help make processed oil shale a more tractable medium for the establishment of plants representative of later successional stages by allowing these plants to make effective use of the natural resources that are limiting under conditions of high stress. 39 references, 1 figure.

  18. Litho-geophysical structure of Paleozoic-Mesozoic contact zones in North-Ostaninsk oil field (Tomsk Oblast)

    NASA Astrophysics Data System (ADS)

    Ezhova, A.; Merkulov, V.; Chekanstev, V.; Abramova, R.

    2015-02-01

    A multidiscipline seismic and gravimagnetic survey, as well as paleomagnetic and lithologic-stratigraphic analysis of pre-Jurassic formations were conducted in North- Ostaninsk oil field within south-east Western Siberian petroleum province. A multidirectional tectonic deformation network merging into the destruction zones of Paleozoic basement was identified. The material composition and age of pre-Jurassic formations within each tectonic block were determined. Fundamentally new geological structure model of the Paleozoic suite was proposed : North-Ostaninsk erosion-tectonic protrusion - a reversed and structurally-complex fracture - deformed tectonic syncline fold where the oil reservoir is confined to the dipping limb. Reversed morphostructures in the erosion-tectonic protrusions could be a prospecting indicator in evaluating the hydrocarbon potential of Paleozoic sediments.

  19. Control of hydrogen sulfide production in oil fields by managing microbial communities through nitrate or nitrite addition

    NASA Astrophysics Data System (ADS)

    Hubert, Casey R. J.

    Nitrate or nitrite injection into oil reservoirs during water flooding has the potential to control biological souring, the production of hydrogen sulfide (H2S) by sulfate-reducing bacteria (SRB). Souring control is essential because sulfide is toxic, sulfide precipitates can plug reservoir formations, souring lowers crude oil value, and SRB induce corrosion. Nitrate and nitrite can stimulate heterotrophic nitrate- or nitrite-reducing bacteria (hNRB) and nitrate- or nitrite-reducing, sulfide oxidizing bacteria (NRSOB). Nitrite also inhibits SRB activity by blocking the sulfate reduction pathway. Continuous up-flow packed-bed bioreactors were inoculated with produced water from the Coleville oil field to establish sulfide-producing biofilms similar to those found in sour reservoirs. Nitrate or nitrite addition to bioreactors indicated that the dose required for hNRB or NR-SOB to control souring depended on the concentration of oil organics. Either mechanism mediates the net removal of oil organics (lactate) with nitrate or nitrite, with lower doses of nitrate required due to its greater oxidative power. Microbial community analysis by reverse sample genome probing (RSGP) revealed that NR-SOB mediated sulfide removal at low nitrate or nitrite concentrations when lactate was still available to SRB and the redox potential was low. At high nitrate doses hNRB oxidized lactate directly, produced nitrite and maintained a high redox potential, thus excluding SRB activity. Facultatively chemolithotrophic Campylobacter sp. strains were isolated from the bioreactors and incorporated into RSGP analyses, revealing their dominance in both NR-SOB- and hNRB-containing communities. The metabolic flexibility of these strains may confer a competitive advantage over obligate chemolithotrophs like Thiomicrospira sp. strain CVO or hNRB that do not have NR-SOB activity like newly isolated Thauera sp. and Rhodobacter sp. strains. A single high dose of nitrite resulted in immediate inhibition of SRB that was independent of hNRB or NR-SOB. Examination of corrosion coupons following bioreactor experiments revealed that nitrite inhibition was the only mechanism that prevented both souring and corrosion. Sulfide elimination by hNRB or NR-SOB resulted in increased pitting corrosion in the region of greatest microbial activity. These findings are instructive for designing souring control treatments and improve understanding of oil field microbial communities.

  20. Eos modeling and reservoir simulation study of bakken gas injection improved oil recovery in the elm coulee field, Montana

    NASA Astrophysics Data System (ADS)

    Pu, Wanli

    The Bakken Formation in the Williston Basin is one of the most productive liquid-rich unconventional plays. The Bakken Formation is divided into three members, and the Middle Bakken Member is the primary target for horizontal wellbore landing and hydraulic fracturing because of its better rock properties. Even with this new technology, the primary recovery factor is believed to be only around 10%. This study is to evaluate various gas injection EOR methods to try to improve on that low recovery factor of 10%. In this study, the Elm Coulee Oil Field in the Williston Basin was selected as the area of interest. Static reservoir models featuring the rock property heterogeneity of the Middle Bakken Member were built, and fluid property models were built based on Bakken reservoir fluid sample PVT data. By employing both compositional model simulation and Todd-Longstaff solvent model simulation methods, miscible gas injections were simulated and the simulations speculated that oil recovery increased by 10% to 20% of OOIP in 30 years. The compositional simulations yielded lower oil recovery compared to the solvent model simulations. Compared to the homogeneous model, the reservoir model featuring rock property heterogeneity in the vertical direction resulted in slightly better oil recovery, but with earlier CO2 break-through and larger CO2 production, suggesting that rock property heterogeneity is an important property for modeling because it has a big effect on the simulation results. Long hydraulic fractures shortened CO2 break-through time greatly and increased CO 2 production. Water-alternating-gas injection schemes and injection-alternating-shut-in schemes can provide more options for gas injection EOR projects, especially for gas production management. Compared to CO2 injection, separator gas injection yielded slightly better oil recovery, meaning separator gas could be a good candidate for gas injection EOR; lean gas generated the worst results. Reservoir simulations also indicate that original rock properties are the dominant factor for the ultimate oil recovery for both primary recovery and gas injection EOR. Because reservoir simulations provide critical inputs for project planning and management, more effort needs to be invested into reservoir modeling and simulation, including building enhanced geologic models, fracture characterization and modeling, and history matching with field data. Gas injection EOR projects are integrated projects, and the viability of a project also depends on different economic conditions.

  1. Development and field testing of a Light Aircraft Oil Surveillance System (LAOSS)

    NASA Technical Reports Server (NTRS)

    Burns, W.; Herz, M. J.

    1976-01-01

    An experimental device consisting of a conventional TV camera with a low light level photo image tube and motor driven polarized filter arrangement was constructed to provide a remote means of discriminating the presence of oil on water surfaces. This polarized light filtering system permitted a series of successive, rapid changes between the vertical and horizontal components of reflected polarized skylight and caused the oil based substances to be more easily observed and identified as a flashing image against a relatively static water surface background. This instrument was flight tested, and the results, with targets of opportunity and more systematic test site data, indicate the potential usefulness of this airborne remote sensing instrument.

  2. Occurrence of oil in the Austin Chalk at Van field, Van Zandt County, Texas: A unique geologic setting

    SciTech Connect

    Lowe, J.T.; Carrington, D.B. )

    1990-09-01

    The Austin Chalk is buried to a depth of only 2,100-2,500 ft and has retained primary microporosity unlike the typical deep fractured chalk reservoirs. The Van structure is a complexly faulted domal anticline created by salt intrusion and is approximately 2,000 ft higher than surrounding structures in the area. A major northwest-dipping fault acts as the primary trapping mechanism. The field has produced 0.5 billion BO from thick Woodbine sands since its discovery in 1929. Occurrence of oil in the Austin Chalk has been known since the field discovery, but prior completions were low rate oil producers. Recent development of a large fracture stimulation technique has resulted in increased production rates of up to 300 BOPD. The Austin Chalk reservoir limits were determined by isopaching feet of minimum productive resistivity having porosity above a cutoff value. The resistivity/porosity isopach showed a direct correlation between Austin Chalk productivity and the Austin Chalk structure and faulting pattern. Structural evidence along with oil typing indicate that the oil in the Austin Chalk has migrated upward along fault planes and through fault juxtaposition from the Woodbine sands 200 ft below the Austin Chalk. Thin-section and scanning electron microscopy work performed on conventional cores showed that the Van Austin Chalk formation is a very fine grained limestone composed primarily of coccoliths. Various amounts of detrital illite clay are present in the coccolith matrix. All effective porosity is micro-intergranular and ranges from 15 to 35%. Based on the core analyses, the main porosity reducing agent and therefore control on reservoir quality is the amount of detrital clay present filling the micropores. Permeability is very low with values ranging from 0.01 to 1.5 md. There is no evidence of significant natural fractures in the core. Artificial fractures are therefore required to create the permeability needed to sustain commercial production rates.

  3. Floating production platforms and their applications in the development of oil and gas fields in the South China Sea

    NASA Astrophysics Data System (ADS)

    Zhang, Dagang; Chen, Yongjun; Zhang, Tianyu

    2014-03-01

    This paper studies the current available options for floating production platforms in developing deepwater oil fields and the potential development models of future oil and gas exploration in the South China Sea. A detailed review of current deepwater platforms worldwide was performed through the examples of industry projects, and the pros and cons of each platform are discussed. Four types of platforms are currently used for the deepwater development: tension leg platform, Spar, semi-submersible platform, and the floating production system offloading. Among these, the TLP and Spar can be used for dry tree applications, and have gained popularity in recent years. The dry tree application enables the extension of the drilling application for fixed platforms into floating systems, and greatly reduces the cost and complexity of the subsea operation. Newly built wet tree semi-submersible production platforms for ultra deepwater are also getting their application, mainly due to the much needed payload for deepwater making the conversion of the old drilling semi-submersible platforms impossible. These platforms have been used in different fields around the world for different environments; each has its own advantages and disadvantages. There are many challenges with the successful use of these floating platforms. A lot of lessons have been learned and extensive experience accumulated through the many project applications. Key technologies are being reviewed for the successful use of floating platforms for field development, and potential future development needs are being discussed. Some of the technologies and experience of platform applications can be well used for the development of the South China Sea oil and gas field.

  4. Environmental assessment of Buccaneer gas and oil field in the northwestern Gulf of Mexico, 1978-1979. Volume V. Effects of gas and oil field structures and effluents on fouling community production and function. Annual report

    SciTech Connect

    Howard, R.L.; Boland, G.S.; Gallaway, B.J.; Dennis, G.D.

    1980-12-01

    Research performed during 1978-79 was designed to obtain additional information about the effects of offshore platforms and effluents on biofouling communities and to obtain information about the functioning of the system. Produced water was confirmed to be characterized by a high oxygen demand and to increase the respiratory rates of the biofouling community. Stations near the produced water discharge were observed to have significantly lower biofouling biomass than other platform supports and platforms with produced water discharges had lower microalgae biomass than control structures. Sets of the small barnacle species are typically overgrown by B. tintinnabulum in the Buccaneer Oil Field.

  5. Electromagnetic oil field mapping for improved process monitoring and reservoir characterization: A poster presentation

    SciTech Connect

    Waggoner, J.R.; Mansure, A.J.

    1992-02-01

    This report is a permanent record of a poster paper presented by the authors at the Third International Reservoir Characterization Technical Conference in Tulsa, Oklahoma on November 3--5, 1991. The subject is electromagnetic (EM) techniques that are being developed to monitor oil recovery processes to improve overall process performance. The potential impact of EM surveys is very significant, primarily in the areas of locating oil, identifying oil inside and outside the pattern, characterizing flow units, and pseudo-real time process control to optimize process performance and efficiency. Since a map of resistivity alone has little direct application to these areas, an essential part of the EM technique is understanding the relationship between the process and the formation resistivity at all scales, and integrating this understanding into reservoir characterization and simulation. First is a discussion of work completed on the core scale petrophysics of resistivity changes in an oil recovery process; a steamflood is used as an example. A system has been developed for coupling the petrophysics of resistivity with reservoir simulation to simulate the formation resistivity structure arising from a recovery process. Preliminary results are given for an investigation into the effect of heterogeneity and anisotropy on the EM technique, as well as the use of the resistivity simulator to interpret EM data in terms of reservoir and process parameters. Examples illustrate the application of the EM technique to improve process monitoring and reservoir characterization.

  6. Field applications of the piscine anaphase aberration test: lessons from the Exxon Valdez oil spill.

    PubMed

    Hose, J E; Brown, E D

    1998-03-20

    Several large-scale genotoxicity assessments have been performed in coastal marine areas that have demonstrated either localized or widespread genetic effects resulting from human activity. One common assessment method is the anaphase aberration test, a measurement of abnormal chromosome division, using embryolarval fishes. It can be used to detect the presence of mutagens within a poorly characterized complex mixture or monitor specific genotoxins and is easily adapted for laboratory screening. One comprehensive marine genotoxicity assessment was conducted using Pacific herring (Clupea pallasi) following the Exxon Valdez oil spill (EVOS) in Prince William Sound (PWS), AK in late March 1989. In early May, genetic damage was detected at many sites within the oil trajectory and was correlated with concentrations of polycyclic aromatic hydrocarbons characteristic of Exxon Valdez oil (EVO) in intertidal mussels. Effects were related spatially and temporally to oil exposure. Anaphase aberration rates decreased throughout May and June 1989, and by 1991, genotoxicity was undetectable. The abundance of the 1989 herring year class in PWS is significantly reduced; this is the first reported example linking genotoxicity to subsequent population level effects. This review describes the methodology for the anaphase aberration test using fish eggs, its applications for large-scale assessments and supportive laboratory studies, and its limitations for prediction of higher level effects on populations. PMID:9672658

  7. Contracts for field projects and supporting research on enhanced oil recovery. Progress review number 87

    SciTech Connect

    1997-10-01

    Approximately 30 research projects are summarized in this report. Title of the project, contract number, company or university, award amount, principal investigators, objectives, and summary of technical progress are given for each project. Enhanced oil recovery projects include chemical flooding, gas displacement, and thermal recovery. Most of the research projects though are related to geoscience technology and reservoir characterization.

  8. Effect of the Exxon Valdez oil spill on intertidal fish: A field study

    SciTech Connect

    Barber, W.E.; McDonald, L.L.; Erickson, W.P.

    1995-07-01

    The purpose of this study was to evaluate the impact of the March 1989 Exxon Valdez oil spill and subsequent cleanup activities on density, biomass, and species diversity of intertidal fishes in Prince William Sound, Alaska. Intertidal fish were sampled in a quasi-experimental, matched-pairs (oiled-cleaned versus reference sites) design stratified by three habitat types with random selection of oiled-cleaned (O-C) sites. Site pairs were sampled twice in 1990 and in 1991. Of 21 fish taxa, 5 made up 98% and 1 made up 74% of total abundance. There were no significant differences in species diversity between reference and O-C sites. Density, however, was significantly greater at reference sites for all habitats combined for both visits in 1990. In contrast, density in 1991 was about equal at reference and O-C sites. Total biomass for all habitats combined was greater at reference than O-C sites during both visits in 1990, but differences were not statistically significant. In 1991, however, the total biomass at reference and O-C sites was about equal. Forward stepwise multiple logistic regression models indicated that presence of oil was a significant predictor of reduced density at mid-intertidal levels in 1990 but not in 1991. From the general pattern of lower density and biomass on O-C sites in 1990 followed by no significant differences in 1991 and corroborating evidence of multiple-regression modeling, we conclude that the presence of oil and subsequent cleanup activities had a negative impact on intertidal fishes in 1990 and that there was evidence that recovery was underway in 1991. 50 refs., 6 figs., 6 tabs.

  9. Geology and habitat of oil in Ras Budran field, Gulf of Suez, Egypt

    SciTech Connect

    Chowdhary, L.R.; Taha, S.

    1987-10-01

    The Ras Budran structure at the deepest mappable seismic reflector, the top of the Kareem Formation (middle Miocene), is a broad northeast-southwest-trending anticlinal feature with an anomalous strike nearly at right angles to the main Gulf of Suez trend. Oil is produced from three units of Nubian Formation sandstone from a depth of 11,000-12,000 ft (3352-3657 m). The lower unit of Paleozoic age averages 10% porosity and has up to 200 md in-situ permeability. Wells completed in this unit produce up to 2000 BOPD. In contrast, the sands to the upper two units of the Early Cretaceous have 15-20% porosity and up to 700 md permeability. Wells completed in this unit produce 6000-8000 BOPD. The Ras Budran structure was formed primarily during an intra-Rudeis tectonic phase (lower Miocene). Oil migration for accumulation in the structure started in the late Miocene or Pliocene when the Santonian Brown Limestone and the Eocene Thebes Formation, the main source beds in the Gulf of Suez, reached the threshold of oil generation at a burial depth of approximately 10,000 ft (3048 m). At this depth, the organic matter in the source beds had a high transformation ratio (0.10 to 0.15), high yields of C/sub 15+/ soluble organic matter and C/sub 15+/ saturated hydrocarbons, vitrinite reflectance (R/sub 0/) of 0.62%, and a time-temperature index (TTI) value of 15. Oil migration from mature source beds in adjoining lows into low-potential Nubian reservoirs is easily explained by fault planes that acted as conduits for oil migration. 16 figures, 3 tables.

  10. Application of denaturing high-performance liquid chromatography for monitoring sulfate-reducing bacteria in oil fields.

    PubMed

    Priha, Outi; Nyyssönen, Mari; Bomberg, Malin; Laitila, Arja; Simell, Jaakko; Kapanen, Anu; Juvonen, Riikka

    2013-09-01

    Sulfate-reducing bacteria (SRB) participate in microbially induced corrosion (MIC) of equipment and H2S-driven reservoir souring in oil field sites. Successful management of industrial processes requires methods that allow robust monitoring of microbial communities. This study investigated the applicability of denaturing high-performance liquid chromatography (DHPLC) targeting the dissimilatory sulfite reductase ß-subunit (dsrB) gene for monitoring SRB communities in oil field samples from the North Sea, the United States, and Brazil. Fifteen of the 28 screened samples gave a positive result in real-time PCR assays, containing 9 × 10(1) to 6 × 10(5) dsrB gene copies ml(-1). DHPLC and denaturing gradient gel electrophoresis (DGGE) community profiles of the PCR-positive samples shared an overall similarity; both methods revealed the same samples to have the lowest and highest diversity. The SRB communities were diverse, and different dsrB compositions were detected at different geographical locations. The identified dsrB gene sequences belonged to several phylogenetic groups, such as Desulfovibrio, Desulfococcus, Desulfomicrobium, Desulfobulbus, Desulfotignum, Desulfonatronovibrio, and Desulfonauticus. DHPLC showed an advantage over DGGE in that the community profiles were very reproducible from run to run, and the resolved gene fragments could be collected using an automated fraction collector and sequenced without a further purification step. DGGE, on the other hand, included casting of gradient gels, and several rounds of rerunning, excising, and reamplification of bands were needed for successful sequencing. In summary, DHPLC proved to be a suitable tool for routine monitoring of the diversity of SRB communities in oil field samples. PMID:23793633

  11. Effect of leachability on environmental risk assessment for naturally occurring radioactive materials (NORM) in petroleum oil fields

    SciTech Connect

    Rajaretnam, G.; Blasio, C.; Lovins, K.; Spitz, H.B.

    1996-06-01

    Elevated concentrations of NORM often occur in petroleum oil fields. The NORM generated by oil field operations comes from {sup 238}U and {sup 232}Th contained in geologic materials. The predominant NORM radionuclide brought to the surface by produced water is radium, which co-precipitates with barium in the form of complex compounds of sulfates, carbonates, and silicates in sludge and scale. These NORM deposits are highly stable and very insoluble under ambient conditions at the surface. However, the co-precipitated radium matrix is not thermodynamically stable at reducing conditions, and all of the radium trapped in it could be released to the environment. The leachability of radium from NORM deposits due to acid-rain and other aging processes are generally unknown. Experiments have been performed on soil samples collected from eastern Kentucky oil fields to find the leachability of radium due to change in pH, temperature, sulfate ion concentration, and accelerated aging of the soil. The average concentration of radium in the soil is in the order of 5.92 Bq g{sup -1}. The risk assessment for different scenarios using the RESRAD code show that the annual total dose to a person living or working on this NORM contaminated soil will be in the range of 6.4-9.6 mSv for the initial 100 years. However, as the soil ages from exposure to acid rain, ultraviolet light from the sun, irradiation from the decay of {sup 226}Ra and its progeny and other kinds of reducing conditions, the solubility of radium in the NORM also changes. Results of accelerated aging and other leaching studies with these samples of soil show that the available radium for uptake increase over time with a corresponding increase in dose to the exposed individuals.

  12. Adaptive Management and Planning Models for Cultural Resources in Oil and Gas Fields in New Mexico and Wyoming

    SciTech Connect

    Eckerle, William; Hall, Stephen

    2005-12-30

    In 2002, Gnomon, Inc., entered into a cooperative agreement with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) for a project entitled, Adaptive Management and Planning Models for Cultural Resources in Oil and Gas Fields in New Mexico and Wyoming (DE-FC26-02NT15445). This project, funded through DOE’s Preferred Upstream Management Practices grant program, examined cultural resource management practices in two major oil- and gas-producing areas, southeastern New Mexico and the Powder River Basin of Wyoming (Figure 1). The purpose of this project was to examine how cultural resources have been investigated and managed and to identify more effective management practices. The project also was designed to build information technology and modeling tools to meet both current and future management needs. The goals of the project were described in the original proposal as follows: Goal 1. Create seamless information systems for the project areas. Goal 2. Examine what we have learned from archaeological work in the southeastern New Mexico oil fields and whether there are better ways to gain additional knowledge more rapidly or at a lower cost. Goal 3. Provide useful sensitivity models for planning, management, and as guidelines for field investigations. Goal 4. Integrate management, investigation, and decision- making in a real-time electronic system. Gnomon, Inc., in partnership with the Wyoming State Historic Preservation Office (WYSHPO) and Western GeoArch Research, carried out the Wyoming portion of the project. SRI Foundation, in partnership with the New Mexico Historic Preservation Division (NMHPD), Statistical Research, Inc., and Red Rock Geological Enterprises, completed the New Mexico component of the project. Both the New Mexico and Wyoming summaries concluded with recommendations how cultural resource management (CRM) processes might be modified based on the findings of this research.

  13. Application of Denaturing High-Performance Liquid Chromatography for Monitoring Sulfate-Reducing Bacteria in Oil Fields

    PubMed Central

    Nyyssönen, Mari; Bomberg, Malin; Laitila, Arja; Simell, Jaakko; Kapanen, Anu; Juvonen, Riikka

    2013-01-01

    Sulfate-reducing bacteria (SRB) participate in microbially induced corrosion (MIC) of equipment and H2S-driven reservoir souring in oil field sites. Successful management of industrial processes requires methods that allow robust monitoring of microbial communities. This study investigated the applicability of denaturing high-performance liquid chromatography (DHPLC) targeting the dissimilatory sulfite reductase ß-subunit (dsrB) gene for monitoring SRB communities in oil field samples from the North Sea, the United States, and Brazil. Fifteen of the 28 screened samples gave a positive result in real-time PCR assays, containing 9 × 101 to 6 × 105 dsrB gene copies ml−1. DHPLC and denaturing gradient gel electrophoresis (DGGE) community profiles of the PCR-positive samples shared an overall similarity; both methods revealed the same samples to have the lowest and highest diversity. The SRB communities were diverse, and different dsrB compositions were detected at different geographical locations. The identified dsrB gene sequences belonged to several phylogenetic groups, such as Desulfovibrio, Desulfococcus, Desulfomicrobium, Desulfobulbus, Desulfotignum, Desulfonatronovibrio, and Desulfonauticus. DHPLC showed an advantage over DGGE in that the community profiles were very reproducible from run to run, and the resolved gene fragments could be collected using an automated fraction collector and sequenced without a further purification step. DGGE, on the other hand, included casting of gradient gels, and several rounds of rerunning, excising, and reamplification of bands were needed for successful sequencing. In summary, DHPLC proved to be a suitable tool for routine monitoring of the diversity of SRB communities in oil field samples. PMID:23793633

  14. Explosively produced fracture of oil shale. Progress report, July-September 1981. [Field experiments; computer models; retort stability

    SciTech Connect

    1982-04-01

    The Los Alamos National Laboratory is conducting rock fragmentation research in oil shale to develop the blasting technologies and designs required to create a rubble bed for a modified in situ retort. This report outlines our first field experiments at the Anvil Points Mine in Colorado. These experiments are part of a research program, sponsored by the Laboratory through the Department of Energy and by a Consortium of oil companies. Also included are some typical numerical calculations made in support of proposed field experiments. Two papers detail our progress in computer modeling and theory. The first presents a method for eliminating hourglassing in two-dimensional finite-difference calculations of rock fracture without altering the physical results. The second discusses the significant effect of buoyancy on tracer gas flow through the retort. A paper on retort stability details a computer application of the Schmidt graphical method for calculating fine-scale temperature gradients in a retort wall. The final paper, which describes our approach to field experiments, presents the instrumentation and diagnostic techniques used in rock fragmentation experiments at Anvil Points Mine.

  15. Activities of the Oil Implementation Task Force, December 1990--February 1991; Contracts for field projects and supporting research on enhanced oil recovery, April--June 1990

    SciTech Connect

    Tiedemann, H.A. )

    1991-03-01

    The Oil Implementation Task Force was appointed to implement the US DOE's new oil research program directed toward increasing domestic oil production by expanded research on near- or mid-term enhanced oil recovery methods. An added priority is to preserve access to reservoirs that have the largest potential for oil recovery, but that are threatened by the large number of wells abandoned each year. This report describes the progress of research activities in the following areas: chemical flooding; gas displacement; thermal recovery; resource assessment; microbial technology; geoscience technology; and environmental technology. (CK)

  16. Assessment of the potential environmental fate and effects of oil-field discharge waters containing {sup 226}radium

    SciTech Connect

    Herrera, A.W.; Hill, S.L.; Bergman, H.L.

    1994-12-31

    The naturally occurring radionuclide, radium-226, has been detected in oil production waters in all regions of the country. A produced water discharge into the Loch Katrina wetland in Park County, WY was investigated with respect to the transport and fate of radium in surface waters. The 866-acre Loch Katrina wetland complex is sustained primarily by oil-field produced waters and provides habitat for many species of aquatic birds. While the short-term benefits of this discharge are indisputable, the long-term hazards posed by the transport of radium from deep aquifers to surface waters are not well understood. Guidelines regulating the management of radium-contaminated sediments in receiving waters or settling ponds in Wyoming have yet to be established. The purpose of this study was to provide information to regional regulatory agencies and the oil and gas industry in the development of guidelines and procedures for managing radium and other naturally occurring radioactive materials. The authors will report the results of the sampling survey of produced waters, sediment and biota performed in the Loch Katrina wetland complex in Wyoming.

  17. Integrated petrophysical and lithofacies studies of lower-middle Miocene reservoirs in Belayim marine oil field, Gulf of Suez, Egypt

    NASA Astrophysics Data System (ADS)

    Ali Ali, El-Khadragy; Emad El Din Abd Elrazik, Eysa; Shebl Azam, Salah; Ahmed Hassan, Saleh

    2016-05-01

    The reservoir parameters (total gross thickness, shale volume, total porosity, effective porosity, water saturation, bulk pore volume, net pay thickness and oil in place indicator) of Kareem and Belayim formations are studied through nine wells and mapped to show the aerial distribution of these parameters. Interpretation of these maps showed that, the best locations of hydrocarbon accumulation in Belayim marine oil field are middle part, northeast and the south west directions for Kareem formation and southwest and northeast directions for Belayim formation. The petrophysical results of Belayim formation were presented in the form of 3D slicing models to exhibit the variation of these parameters in the different directions. Cross plots of Kareem formation were done using neutron, density and sonic logs which is directly influenced by the matrix composition. By using two or three porosity logs reading we determined the porosity and evaluated the matrix characteristics of Kareem formation as it is considered as a good reservoir for oil and gas and mainly composed of sand stone. Finally, facies maps for Kareem and Belayim formations which established using composite logs indicate that, the environment of deposition of Kareem formation was deep marine in the middle and northern parts and shallow in the southern parts of the study area, meanwhile in Belayim formation the environment of deposition was in lagoonal through the deposition of Baba and Feiran members and shallow to deep during the sedimentation of Sidri and Hammam Faraun members.

  18. Caribou distribution during the post-calving period in relation to infrastructure in the Prudhoe Bay oil field, Alaska

    USGS Publications Warehouse

    Cronin, M.A.; Amstrup, Steven C.; Durner, G.M.; Noel, L.E.; McDonald, T.L.; Ballard, W.B.

    1998-01-01

    There is concern that caribou (Rangifer tarandus) may avoid roads and facilities (i.e., infrastructure) in the Prudhoe Bay oil field (PBOF) in northern Alaska, and that this avoidance can have negative effects on the animals. We quantified the relationship between caribou distribution and PBOF infrastructure during the post-calving period (mid-June to mid-August) with aerial surveys from 1990 to 1995. We conducted four to eight surveys per year with complete coverage of the PBOF. We identified active oil field infrastructure and used a geographic information system (GIS) to construct ten 1 km wide concentric intervals surrounding the infrastructure. We tested whether caribou distribution is related to distance from infrastructure with a chi-squared habitat utilization-availability analysis and log-linear regression. We considered bulls, calves, and total caribou of all sex/age classes separately. The habitat utilization-availability analysis indicated there was no consistent trend of attraction to or avoidance of infrastructure. Caribou frequently were more abundant than expected in the intervals close to infrastructure, and this trend was more pronounced for bulls and for total caribou of all sex/age classes than for calves. Log-linear regression (with Poisson error structure) of numbers of caribou and distance from infrastructure were also done, with and without combining data into the 1 km distance intervals. The analysis without intervals revealed no relationship between caribou distribution and distance from oil field infrastructure, or between caribou distribution and Julian date, year, or distance from the Beaufort Sea coast. The log-linear regression with caribou combined into distance intervals showed the density of bulls and total caribou of all sex/age classes declined with distance from infrastructure. Our results indicate that during the post-calving period: 1) caribou distribution is largely unrelated to distance from infrastructure; 2) caribou regularly use habitats in the PBOF; 3) caribou often occur close to infrastructure; and 4) caribou do not appear to avoid oil field infrastructure.

  19. Increased Oil Production and Reserves from Improved Completion Techniques in the Bluebell Field, Uinta Basin, Utah, Class I

    SciTech Connect

    Morgan, Craig D.; Gwynn, Wallace; Deo, Milind D.; Jarrard, Richard; Curtice, Richard; Morris, Thomas H.; Smouse, DeForrest; Tripp, Carol N.

    2000-01-20

    The objective of this project was to increase oil production and reserves by the use of improved reservoir characterization and completion techniques in the Unita Basin Utah. To accomplish this objective, a two-year geologic and engineering characterization of the Bluebell field was conducted. The study evaluated surface and subsurface data, currently used completion techniques, and common production problems. It was determined that advanced case- and open-hole logs could be effective in determining productive beds and that staged-interval (about 500 ft [150 m] per stage) and bed-scale isolation completion techniques could result in improved well performance.

  20. Toxicology of oil field wastes. Hazards to livestock associated with the petroleum industry.

    PubMed

    Edwards, W C

    1989-07-01

    In oil-producing states, the proximity of livestock to drilling operations and production sites often results in poisoning of animals from ingestion of crude oil, condensate, salt water, heavy metals, and caustic chemicals. The heavy metals encountered most frequently are lead from pipe joint compound and arsenicals and chromates used as corrosion inhibitors. Numerous toxic and caustic chemicals are used in drilling muds and fluids. Crude oil and salt water spills are common occurrences around production sites. Pipeline breaks may result in exposure of livestock to crude oil or refined petroleum hydrocarbons. Ingestion of petroleum hydrocarbons may result in sudden death from peracute bloat. The most common cause of illness or death following exposure to petroleum hydrocarbons is aspiration pneumonia, which may cause a chronic progressive deterioration of health, with death after several days or weeks. Cases in which livestock are exposed to oil, salt water, or caustic chemicals, but do not die acutely or from aspiration pneumonia are more frustrating to diagnose. In these cases, parasitism, poor nutrition, and other debilitating diseases must be considered. Anorexia, weight loss, and decreased rumen motility may be caused by a disruption of normal rumen function. Petroleum hydrocarbons, salt water, and caustic chemicals have the potential of altering rumen flora and enzymatic processes as well as damaging the ruminal and gastrointestinal epithelium. The toxicity of petroleum hydrocarbons appears to be related more closely to the volatility and viscosity of the product than to other factors. The more volatile straight chain and aromatic petroleum hydrocarbons have a greater potential for aspiration pneumonia and may produce an anesthetic-like action if absorbed systemically. The more volatile petroleum hydrocarbons also are more irritating to skin and mucous membranes and appear to be more damaging to rumen flora. Treatment of petroleum hydrocarbon ingestion is aimed at preventing aspiration pneumonia and the animal's absorption of highly volatile components. Activated charcoal slurries and, in some instances, vegetable oil may be used to absorb the ingested petroleum or alter its viscosity to minimize absorption and aspiration. These procedures should be followed by the administration of rumenatories or saline cathartics to hasten the evacuation of the gastrointestinal tract. Chronic poor performance animals with anorexia and rumen dysfunction may respond to fresh rumen inoculant, intravenous glucose, and B-complex vitamins. Prognosis primarily hinges on whether or not aspiration pneumonia has occurred. Treatment of aspiration pneumonia rarely is effe PMID:2667711

  1. Field endurance test of diesel engines fueled with sunflower oil/diesel fuel blends

    SciTech Connect

    German, T.J.; Kaufman, K.R.; Pratt, G.L.; Derry, J.

    1985-01-01

    Four John Deere and two J.I. Case tractors were fueled with 25% or 50% blends of alkali-refined, winterized sunflower oil and No. 2 diesel fuel while in farm service. All engines were turbocharged, direct injection diesel engines and each was operated for approximately 1000 hours. No power losses were detected during the test period. However, one engine experienced camshaft/valve train failure while in service. Engine deposits were measured according to the CRC Diesel Engine Rating system after the test period was completed. Statistical analysis revealed heavier deposits in most areas of the combustion chamber of the three engines fueled with the 50% sunflower oil/50% No. 2 diesel fuel blend. No detrimental engine deposits due to differences in engine size were observed. No injector coking problems or ring sticking problems were encountered. Bearing wear was normal.

  2. Investments in oil field development by the example of Tomsk oblast

    NASA Astrophysics Data System (ADS)

    Shmidt, Ye I.; Il'ina, G. F.; Matveenko, I. A.

    2015-11-01

    The article describes the geologic structure of the formation located not far from Strezhevoy Tomsk Oblast. The formation has been poorly studied by seismic methods. The reserves categories C1 and C2 as well as hydrocarbon potential are presented. 4 exploratory and 39 production wells are designed to be drilled depending on geologic knowledge and formation conditions. The article deals with the investment plan including development, oil export expenditures and implementing cost calculation.

  3. Hydrolytically stable polymers for use in oil field cementing methods and compositions

    SciTech Connect

    Rao, S. P.; Burkhalter, J. F.

    1985-11-26

    Cementing compositions and methods of using such compositions in oil, gas and water well cementing operations to reduce fluid loss from the composition to the formation are disclosed. Such compositions incorporate certain copolymers and copolymer salts of N,N dimethylacrylamide and 2-acrylamido, 2-methyl propane sulfonic acid having mole ratios of between 1:4 and 4:1 respectively and average molecular weights of between about 75,000 and about 300,000.

  4. Increasing Waterflood Reserves in the Wilmington Oil Field Through Improved Reservoir Characterization and Reservoir Management.

    SciTech Connect

    Koerner, Roy; Clarke, Don; Walker, Scott; Phillips, Chris; Nauyen, John; Moos, Dan; Tagbor, Kwasi

    1997-07-28

    The objectives of this quarterly report are to summarize the work conducted under each task during the reporting period April - June 1997 and to report all technical data and findings as specified in the `Federal Assistance Reporting Checklist`. The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology. The identification of the sands with high remaining oil saturation will be accomplished by developing a deterministic three dimensional (3-D) geologic model and by using a state of the art reservoir management computer software. The wells identified by the geologic and reservoir engineering work as having the best potential will be logged with a pulsed acoustic cased-hole logging tool. The application of the logging tools will be optimized in the lab by developing a rock-log model. This rock-log model will allow us to convert shear wave velocity measured through casing into effective porosity and hydrocarbon saturation. The wells that are shown to have the best oil production potential will be recompleted. The recompletions will be optimized by evaluating short radius and ultra-short radius lateral recompletions as well as other techniques.

  5. Increasing Waterflood Reserves in the Wilmington Oil Field Through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect

    Chris Phillips; Dan Moos; Don Clarke; John Nguyen; Kwasi Tagbor; Roy Koerner; Scott Walker.

    1998-01-26

    The objectives of this quarterly report are to summarize the work conducted under each task during the reporting period October - December 1997 and to report all technical data and findings as specified in the Federal Assistance Reporting Checklist . The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology. The identification of the sands with high remaining oil saturation will be accomplished by developing a deterministic three dimensional (3-D) geologic model and by using a state of the art reservoir management computer software. The wells identified by the geologic and reservoir engineering work as having the best potential will be logged with cased-hole logging tools. The application of the logging tools will be optimized in the lab by developing a rock-log model. This rock-log model will allow us to translate measurements through casing into effective porosity and hydrocarbon saturation. The wells that are shown to have the best oil production potential will be recompleted. The recompletions will be optimized by evaluating short radius lateral recompletions as well as other recompletion techniques such as the sand consolidation through steam injection.

  6. Increasing Waterflood Reserves in the Wilmington Oil Field Through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect

    Chris Phillips; Dan Moos; Don Clarke; John Nguyen; Kwasi Tagbor; Roy Koerner; Scott Walker

    1998-01-26

    The objectives of this quarterly report are to summarize the work conducted under each task during the reporting period October - December 1997 and to report all technical data and findings as specified in the "Federal Assistance Reporting Checklist". The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology. The identification of the sands with high remaining oil saturation will be accomplished by developing a deterministic three dimensional (3-D) geologic model and by using a state of the art reservoir management computer software. The wells identified by the geologic and reservoir engineering work as having the best potential will be logged with cased-hole logging tools. The application of the logging tools will be optimized in the lab by developing a rock-log model. This rock-log model will allow us to translate measurements through casing into effective porosity and hydrocarbon saturation. The wells that are shown to have the best oil production potential will be recompleted. The recompletions will be optimized by evaluating short radius lateral recompletions as well as other recompletion techniques such as the sand consolidation through steam injection.

  7. Increasing Waterflood Reserves in the Wilmington Oil Field Through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect

    Chris Phillips; Dan Moos; Don Clarke; John Nguyen; Kwasi Tagbor; Roy Koerner; Scott Walker

    1998-04-22

    The objectives of this quarterly report are to summarize the work conducted under each task during the reporting period January - March 1998 and to report all technical data and findings as specified in the "Federal Assistance Reporting Checklist". The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology. The identification of the sands with high remaining oil saturation will be accomplished by developing a deterministic three dimensional (3-D) geologic model and by using a state of the art reservoir management computer software. The wells identified by the geologic and reservoir engineering work as having the best potential will be logged with cased-hole logging tools. The application of the logging tools will be optimized in the lab by developing a rock-log model. This rock-log model will allow us to translate measurements through casing into effective porosity and hydrocarbon saturation. The wells that are shown to have the best oil production potential will be recompleted. The recompletions will be optimized by evaluating short radius lateral recompletions as well as other recompletion techniques such as the sand consolidation through steam injection.

  8. Oil dispersants

    SciTech Connect

    Flaherty, L.M.

    1989-01-01

    This book contains papers presented at a symposium of the American Society for Testing and Materials. The topics covered include: The effect of elastomers on the efficiency of oil spill dispersants; planning for dispersant use; field experience with dispersants for oil spills on land; and measurements on natural dispersion.

  9. Magnetotelluric survey for exploration of a volcanic-rock reservoir in the Yurihara oil and gas field, Japan

    SciTech Connect

    Mitsuhata, Yuji; Matsuo, Koichi; Minegishi, Masato

    1999-03-01

    The Yurihara oil and gas field is located on the southern edge of Akita Prefecture, northeastern Japan. In this area, drilling, surface geological surveys and many seismic surveys have been used to investigate the geological structure. Wells drilled into the Nishikurosawa Basalt Group (NBG) of Miocene age found oil and gas reservoirs at depths of 1.5--2 km. Oil and gas are now being produced commercially and further exploration is required in the surrounding areas. However, since the neighboring areas are covered with young volcanic products from the Chokai volcano, and have a rough topography, the subsurface distribution of the NBG must be investigated using other methods in addition to seismic reflection. According to the well data, the resistivity of the NBG is comparatively higher than that of the overlying sedimentary formations, and therefore the magnetotelluric (MT) method is expected to be useful for the estimation of the distribution of the NBG. An MT survey was conducted along three survey lines in this area. Each line trended east-west, perpendicular to the regional geological strike, and was composed of about 25 measurement sites. Induction vectors evaluated from the magnetic field show that this area has a two-dimensional structure. The evaluated resistivity sections are in agreement with the log data. In conclusion, the authors were able to detect resistive layers (the NBG) below conductive layers. The results indicate that the NBG becomes gradually less resistive from north to south. In the center of the northern line, an uplifted resistive area is interpreted as corresponding to the reservoir. By comparison with a seismic section, the authors prove the effectiveness of the integration of seismic and MT surveys for the investigation of the morphology and internal structure of the NBG. On other survey lines, the resistive uplifted zones are interpreted as possible prospective areas.

  10. Investigation of high-temperature, igneous-related hydraulic fracturing as a reservoir control in the Blackburn and Grant Canyon/Bacon Flat oil fields, Nevada

    SciTech Connect

    Hulen, J.B.

    1991-01-01

    Research in progress to evaluate natural, igenous-related hydrothermal fracturing as a reservoir control in two eastern Nevada oil fields has revealed evidence of a far more comprehensive role for moderate- to high-temperature hydrothermal systems in Basin-and-Range oil-reservoir evolution. Fluid-inclusion and petrographic studies have shown that (now) oil-bearing dolomite breccias of the Blackburn field (Pine Valley, Eureka County) were formed when overpressured, magmatically-heated, high-temperature (>350{degrees}C) hydrothermal brines explosively ruptured their host rocks; similar studies of texturally identical breccias of the Grant Canyon/Bacon Flat field (Railroad Valley, Nye County) so far do not support such an explosive origin. At Grant Canyon, however, hydrothermal, breccia-cementing quartz hosts primary oil, aqueous/oil, and aqueous fluid inclusions (homogenization temperature = 120{degrees}C) which document a direct geothermal connection for oil migration and entrapment. Moreover, at both Blackburn and Grant Canyon/Bacon Flat, the oil reservoirs are top- and side-sealed by hydrothermally altered Tertiary ignimbrites and epiclastic rocks. Contemporary geothermal activity is also apparent at grant Canyon/Bacon Flat, where subsurface water temperatures reach 171{degrees}C, and at Blackburn, above which a petroleum-providing hot spring issues at a temperature of 90{degrees}C. We suggest that in the Basin and Range province, hydrothermal systems may have: (1) matured oil from otherwise submature source rocks; (2) transported oil to ultimate entrapment sites by convection in moderate-to high-temperature fluids; and (3) sealed reservoir traps through hydrothermal alteration of overlying Tertiary caprocks. 69 refs., 11 figs., 1 tab.

  11. Carbonate platform evolution, Upper Paleozoic, southern Kazakhstan, USSR: A surface analog for the super giant Tengiz oil field western Kazakhstan

    SciTech Connect

    Cook, H.E. ); Gatosvseey, Y.A.; Ponoeearenko, S.B.; Styehtsyehnka, I.G.; Styehtsyennka, V.P.; Zoran, A.E. ); Zhemchuzhnikov, V. )

    1991-08-01

    The Upper Devonian and Carboniferous carbonate platform and associated bioherms in the Bolshoi Karatau Mountains of southern Kazakhstan are similar to coeval carbonate platform and biohermal reservoir facies recently described in the Tengiz oil field of western Kazakhstan on the southeastern margin of the Pre-Caspian basin. Like Tengiz, the Bolshoi Karatau carbonate platform developed upon Devonian siliciclastics. The size of the two platforms are also similar as both the Bolshoi Karatau and the Tengiz carbonate platform are about 2-4 km thick and about 100 km wide. In the Bolshoi Karatau Mountains, the carbonate platform trends northwest-southeast, with the continental land mass to the east, and the open ocean platform margin toward Tengiz. Within the Bolshoi Karatau carbonate platform are several types of bioherms and carbonate sand bodies that may be analogous to the reservoir facies in the Tengiz oil field. Some of these facies exhibit karsting and solution voids which probably developed during sea level fluctuation. The Bolshoi Karatau carbonate sequence provides new data on the stratigraphic and sedimentologic evolution of Upper Devonian and Carboniferous carbonate platforms in southern Kazakhstan. Depositional, diagenetic, and reservoir models of this outcrop belt that are currently being developed should be useful for making subsurface predictions in the Tengiz area and other stratigraphically similar areas of the Soviet Union.

  12. Application of bioflocculating property of Pseudomonas aeruginosa strain IASST201 in treatment of oil-field formation water.

    PubMed

    Pathak, Mihirjyoti; Devi, Arundhuti; Sarma, Hridip Kumar; Lal, Banwari

    2014-07-01

    A bioflocculating activity of 89.8% was depicted by an activated sludge-borne bacteria Pseudomonas aeruginosa strain IASST201 with a yield of bioflocculant of 2.68 g L(-1) obtained from production media broth after optimization of different parameters. The highest bioflocculation efficiency was found at the pre-stationary phase of the bacterial growth period in the production media broth at 96th hour examined from a growth-flocculation kinetics study. 85.67% of bioflocculation was observed in oil-field formation water, with a separation of 68.7% of aliphatic hydrocarbon contents of the formation water after the application of the bacterial bioflocculant by entrapment mechanism with formation of flocs which was analyzed and examined comparatively through gas-chromatography. Extensive removal of heavy metal contents of the oil-field formation water due to bioflocculation was estimated by Atomic Absorption Spectrophotometer (AAS). The SEM and AFM studies declare the extracellular polymeric nature of the bioflocculant produced by this bacterium clumped within bacterial biofilm supported with FTIR study of the extracted bioflocculant. PMID:24740803

  13. An integrated approach to seismic stimulation of oil reservoirs: laboratory, field and theoretical results from DOE/industry collaborations.

    SciTech Connect

    Roberts, P. M.; Majer, Ernest Luther; Lo, W. C.; Sposito, Garrison,; Daley, T. M.

    2003-01-01

    It has been observed repeatedly that low-frequency (10-500 Hz) seismic stress waves can enhance oil production from depleted reservoirs . Until recently, the majority of these observations have been anecdotal or at the proof-of-concept level. The physics coupling stress waves to multiphase fluid flow behavior in porous media is still poorly understood, even though numerous underlying physical mechanisms have been proposed to explain the observations . Basic research on the phenomenon is being conducted through a U .S. Department of Energy funded collaboration between Lawrence Berkeley National Laboratory, the University of California at Berkeley, Los Alamos National Laboratory and the U .S . oil and gas industry . The project has focused on three main areas of research: (1) laboratory core flow experiments, (2) field seismic monitoring of downhole stimulation tests, and (3) theoretical modeling of the coupled stress/flow phenomenon . The major goal is to obtain a comprehensive scientific understanding of the seismic stimulation phenomenon so that field application technologies can be improved. Initial developments and experimental results in all three research focus areas confirm historic observations that the stimulated flow phenomenon is real and that a fundamental scientific understanding can be obtained through continued research . Examples of project results and developments are presented here.

  14. Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana, USA

    USGS Publications Warehouse

    Peterman, Zell E.; Thamke, Joanna N.; Futa, Kiyoto; Preston, Todd

    2012-01-01

    Groundwater, surface water, and soil in the Goose Lake oil field in northeastern Montana have been affected by Cl−-rich oil-field brines during long-term petroleum production. Ongoing multidisciplinary geochemical and geophysical studies have identified the degree and local extent of interaction between brine and groundwater. Fourteen samples representing groundwater, surface water, and brine were collected for Sr isotope analyses to evaluate the usefulness of 87Sr/86Sr in detecting small amounts of brine. Differences in Sr concentrations and 87Sr/86Sr are optimal at this site for the experiment. Strontium concentrations range from 0.13 to 36.9 mg/L, and corresponding 87Sr/86Sr values range from 0.71097 to 0.70828. The local brine has 168 mg/L Sr and a 87Sr/86Sr value of 0.70802. Mixing relationships are evident in the data set and illustrate the sensitivity of Sr in detecting small amounts of brine in groundwater. The location of data points on a Sr isotope-concentration plot is readily explained by an evaporation-mixing model. The model is supported by the variation in concentrations of most of the other solutes.

  15. Silurian "Clinton" Sandstone Reservoir Characterization for Evaluation of CO2-EOR Potential in the East Canton Oil Field, Ohio

    SciTech Connect

    Riley, Ronald; Wicks, John; Perry, Christopher

    2009-12-30

    The purpose of this study was to evaluate the efficacy of using CO2-enhanced oil recovery (EOR) in the East Canton oil field (ECOF). Discovered in 1947, the ECOF in northeastern Ohio has produced approximately 95 million barrels (MMbbl) of oil from the Silurian “Clinton” sandstone. The original oil-in-place (OOIP) for this field was approximately 1.5 billion bbl and this study estimates by modeling known reservoir parameters, that between 76 and 279 MMbbl of additional oil could be produced through secondary recovery in this field, depending on the fluid and formation response to CO2 injection. A CO2 cyclic test (“Huff-n-Puff”) was conducted on a well in Stark County to test the injectivity in a “Clinton”-producing oil well in the ECOF and estimate the dispersion or potential breakthrough of the CO2 to surrounding wells. Eighty-one tons of CO2 (1.39 MMCF) were injected over a 20-hour period, after which the well was shut in for a 32-day “soak” period before production was resumed. Results demonstrated injection rates of 1.67 MMCF of gas per day, which was much higher than anticipated and no CO2 was detected in gas samples taken from eight immediately offsetting observation wells. All data collected during this test was analyzed, interpreted, and incorporated into the reservoir characterization study and used to develop the geologic model. The geologic model was used as input into a reservoir simulation performed by Fekete Associates, Inc., to estimate the behavior of reservoir fluids when large quantities of CO2 are injected into the “Clinton” sandstone. Results strongly suggest that the majority of the injected CO2 entered the matrix porosity of the reservoir pay zones, where it diffused into the oil. Evidence includes: (A) the volume of injected CO2 greatly exceeded the estimated capacity of the hydraulic fracture and natural fractures; (B) there was a gradual injection and pressure rate build-up during the test; (C) there was a subsequent, gradual flashout of the CO2 within the reservoir during the ensuing monitored production period; and (D) a large amount of CO2 continually off-gassed from wellhead oil samples collected as late as 3½ months after injection. After the test well was returned to production, it produced 174 bbl of oil during a 60-day period (September 22 to November 21, 2008), which represents an estimated 58 percent increase in incremental oil production over preinjection estimates of production under normal, conditions. The geologic model was used in a reservoir simulation model for a 700-acre model area and to design a pilot to test the model. The model was designed to achieve a 1-year response time and a five-year simulation period. The reservoir simulation modeling indicated that the injection wells could enhance oil production and lead to an additional 20 percent recovery in the pilot area over a five-year period. The base case estimated that by injecting 500 MCF per day of CO2 into each of the four corner wells, 26,000 STBO would be produced by the central producer over the five-year period. This would compare to 3,000 STBO if a new well were drilled without the benefit of CO2 injection. This study has added significant knowledge to the reservoir characterization of the “Clinton” in the ECOF and succeeded in identifying a range on CO2-EOR potential. However, additional data on fluid properties (PVT and swelling test), fractures (oriented core and microseis), and reservoir characteristics (relative permeability, capillary pressure, and wet ability) are needed to further narrow the uncertainties and refine the reservoir model and simulation. After collection of this data and refinement of the model and simulation, it is recommended that a larger scale cyclic- CO2 injection test be conducted to better determine the efficacy of CO2-EOR in the “Clinton” reservoir in the ECOF.

  16. Silurian "Clinton" Sandstone Reservoir Characterization for Evaluation of CO2-EOR Potential in the East Canton Oil Field, Ohio

    SciTech Connect

    Ronald Riley; John Wicks; Christopher Perry

    2009-12-30

    The purpose of this study was to evaluate the efficacy of using CO2-enhanced oil recovery (EOR) in the East Canton oil field (ECOF). Discovered in 1947, the ECOF in northeastern Ohio has produced approximately 95 million barrels (MMbbl) of oil from the Silurian 'Clinton' sandstone. The original oil-in-place (OOIP) for this field was approximately 1.5 billion bbl and this study estimates by modeling known reservoir parameters, that between 76 and 279 MMbbl of additional oil could be produced through secondary recovery in this field, depending on the fluid and formation response to CO2 injection. A CO2 cyclic test ('Huff-n-Puff') was conducted on a well in Stark County to test the injectivity in a 'Clinton'-producing oil well in the ECOF and estimate the dispersion or potential breakthrough of the CO2 to surrounding wells. Eighty-one tons of CO2 (1.39 MMCF) were injected over a 20-hour period, after which the well was shut in for a 32-day 'soak' period before production was resumed. Results demonstrated injection rates of 1.67 MMCF of gas per day, which was much higher than anticipated and no CO2 was detected in gas samples taken from eight immediately offsetting observation wells. All data collected during this test was analyzed, interpreted, and incorporated into the reservoir characterization study and used to develop the geologic model. The geologic model was used as input into a reservoir simulation performed by Fekete Associates, Inc., to estimate the behavior of reservoir fluids when large quantities of CO2 are injected into the 'Clinton' sandstone. Results strongly suggest that the majority of the injected CO2 entered the matrix porosity of the reservoir pay zones, where it diffused into the oil. Evidence includes: (A) the volume of injected CO2 greatly exceeded the estimated capacity of the hydraulic fracture and natural fractures; (B) there was a gradual injection and pressure rate build-up during the test; (C) there was a subsequent, gradual flashout of the CO2 within the reservoir during the ensuing monitored production period; and (D) a large amount of CO2 continually off-gassed from wellhead oil samples collected as late as 3 1/2 months after injection. After the test well was returned to production, it produced 174 bbl of oil during a 60-day period (September 22 to November 21, 2008), which represents an estimated 58 percent increase in incremental oil production over preinjection estimates of production under normal, conditions. The geologic model was used in a reservoir simulation model for a 700-acre model area and to design a pilot to test the model. The model was designed to achieve a 1-year response time and a five-year simulation period. The reservoir simulation modeling indicated that the injection wells could enhance oil production and lead to an additional 20 percent recovery in the pilot area over a five-year period. The base case estimated that by injecting 500 MCF per day of CO2 into each of the four corner wells, 26,000 STBO would be produced by the central producer over the five-year period. This would compare to 3,000 STBO if a new well were drilled without the benefit of CO2 injection. This study has added significant knowledge to the reservoir characterization of the 'Clinton' in the ECOF and succeeded in identifying a range on CO2-EOR potential. However, additional data on fluid properties (PVT and swelling test), fractures (oriented core and microseis), and reservoir characteristics (relative permeability, capillary pressure, and wet ability) are needed to further narrow the uncertainties and refine the reservoir model and simulation. After collection of this data and refinement of the model and simulation, it is recommended that a larger scale cyclic-CO2 injection test be conducted to better determine the efficacy of CO2-EOR in the 'Clinton' reservoir in the ECOF.

  17. Orgin and significance of geochemical variability among oils and gas-condensates in the Tiger Shoal Field, northern Gulf of Mexico

    SciTech Connect

    Kelley, P.A.; Imbus, S.W.; McKeever, S.R.

    1995-12-31

    Geochemical data placed in geological context is key to understanding the processes controlling the variability of oils and gas-condensates in the Tiger Shoal Field, northern Gulf of Mexico. Thermal maturity at generation and phase partitioning are the principal processes accounting for variability in the bulk and molecular properties of the oils and gas-condensates. Quantification of the extent that these processes altered the oils and gas-condensates between fault blocks and among individual sands permits: (1) documentation of the most effective migration conduits, (2) inference of deeper or shallower pay zones, (3) and assessment of vertical and lateral fluid connectivity. Calibration of bulk to molecular properties will permit rapid assessment of the type and extent of alteration using basic parameters such as API gravity and gas oil ratio (GOR). Upon mass balancing with initial reserves data, a detailed risking scheme for remaining prospects within the field can be formulated.

  18. Multi-temporal environmental analysis of oil field activities in south-central Oklahoma using Landsat thematic mapper, aerial photography and GIS

    SciTech Connect

    Janks, J.S.; Edwards, G.S.; Prelat, A.E.

    1995-12-01

    Environmental assessments of oil field activities, historical and present, were made using a combination of Landsat Thematic Mapper, aerial photographic and GIS information. Landsat data was used to assess vegetation health in and around the oil fields, and aerial photography was used to document historic changes. We found no evidence of vegetation damage from the oil field activities, even though many fields are located along anticlines and drain into major waterways. GIS technology, mapping roads, wells, rivers, ponds and environmentally-sensitive areas, was used to minimize environmental effects on the placement of shotpoints and receivers. When either shotpoints or receivers were found to interfere with sensitive areas, the points were moved to nearby roads or other open locations. The application of this technology resulted in minimal environmental damage and significant cost savings.

  19. Bacterial Community Dynamics and Hydrocarbon Degradation during a Field-Scale Evaluation of Bioremediation on a Mudflat Beach Contaminated with Buried Oil

    PubMed Central

    Röling, Wilfred F. M.; Milner, Michael G.; Jones, D. Martin; Fratepietro, Francesco; Swannell, Richard P. J.; Daniel, Fabien; Head, Ian M.

    2004-01-01

    A field-scale experiment with a complete randomized block design was performed to study the degradation of buried oil on a shoreline over a period of almost 1 year. The following four treatments were examined in three replicate blocks: two levels of fertilizer treatment of oil-treated plots, one receiving a weekly application of liquid fertilizer and the other treated with a slow-release fertilizer; and two controls, one not treated with oil and the other treated with oil but not with fertilizer. Oil degradation was monitored by measuring carbon dioxide evolution and by chemical analysis of the oil. Buried oil was degraded to a significantly greater extent in fertilized plots, but no differences in oil chemistry were observed between the two different fertilizer treatments, although carbon dioxide production was significantly higher in the oil-treated plots that were treated with slow-release fertilizer during the first 14 days of the experiment. Bacterial communities present in the beach sediments were profiled by denaturing gradient gel electrophoresis (DGGE) analysis of PCR-amplified 16S rRNA gene fragments and 16S rRNA amplified by reverse transcriptase PCR. Similarities between the DGGE profiles were calculated, and similarity matrices were subjected to statistical analysis. These analyses showed that although significant hydrocarbon degradation occurred both in plots treated with oil alone and in the plots treated with oil and liquid fertilizer, the bacterial community structure in these plots was, in general, not significantly different from that in the control plots that were not treated with oil and did not change over time. In contrast, the bacterial community structure in the plots treated with oil and slow-release fertilizer changed rapidly, and there were significant differences over time, as well as between blocks and even within plots. The differences were probably related to the higher concentrations of nutrients measured in interstitial water from the plots treated with slow-release fertilizer. Bacteria with 16S rRNA sequences closely related (>99.7% identity) to Alcanivorax borkumensis and Pseudomonas stutzeri sequences dominated during the initial phase of oil degradation in the plots treated with slow-release fertilizer. Field data were compared to the results of previous laboratory microcosm experiments, which revealed significant differences. PMID:15128509

  20. Thermal and mass history of Fairway Field in east Texas: Implication for geothermal energy development in an oil and gas setting

    NASA Astrophysics Data System (ADS)

    Kweik, Ramsey Sharif

    Fairway Field is an oil field operated by Hunt Oil Company located in East Texas near the town of Poynor, Texas in Henderson County. The field was discovered in 1960 and is still producing today with the field life projected beyond 2015 (Webster et al., 2008). Hunt Oil Company granted access to over 2,900 open-hole well logs and pressure surveys for this research project. This thermal and mass history of production from a major hydrocarbon field is an especially rare opportunity, as oil and gas companies in Texas are generally not required to share pressure survey data with regulatory agencies, and thus these types of data are not typically available to the research community. This data set, coupled with fluid production and injection data, provides an opportunity to analyze temperature variations associated with fluid migration and field development as a function of time. Fairway Field was determined to have an average conductive heat flow value of 69 +/- 6 mW/m2. Using fluid production volumes, heat loss was determined to be -1.7 x 1017 Joules which represents a thermal recovery factor of -6.2% for the James Limestone Formation in Fairway Field. Given the fact that the field has been in development for over 50 years and has not exhibited a decrease but an increase in reservoir temperatures (+20 °F over 54 years), Fairway Field illustrates that sedimentary basins have considerable potential for geothermal development. An increased availability of pressure survey temperature data and fluid data from oil and gas companies provides a better understanding of such dynamic geothermal systems, helps evaluate the working life of a field, and is a tool for assessing development risk associated with future geothermal energy development in such settings.

  1. Application of 2.5D cross-hole electromagnetic inversion in Gudao Oil Field, East China

    NASA Astrophysics Data System (ADS)

    Shen, Jinsong; Sun, Wenbo; Zhao, Wenjie; Zeng, Wenchong

    2008-09-01

    In this study, we present a practical technique of transforming cross-hole EM data into the inter-well resistivity distribution. The a priori information constraint is incorporated into an iterative regularized inversion procedure and a variable roughness is added into the inversion process. Finite element approximation based on a two and a half-dimensional (2.5D) model has been developed for the forward problem and the “pseudo-forward” problem needed for constructing the sensitivity matrix and synthetic data set. The regularized least-squares inversion scheme, constrained with the a priori information obtained from well logs, was adopted to reconstruct the inter-well resistivity profile from two synthetic electromagnetic data sets and field data acquired in the Gudao Oil Field, East China. The partial derivatives of the sensitivity matrix were computed by the adjoint equation based on the reciprocity principle. Inversion results of the synthetic and field data examples suggest that our method is robust and stable in the presence of random noise in the field data and can be used for cross-hole EM field data interpretation.

  2. Increasing Waterflood Reserves in the Wilmington Oil Field Through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect

    Chris Phillips; Dan Moos; Don Clarke; Dwasi Tagbor; John Nguygen; Roy Koerner; Scott Walker

    1997-04-10

    The objectives of this quarterly report are to summarize the work conducted under each task during the reporting period January - March 1997 and to report all technical data and findings as specified in the "Federal Assistance Reporting Checklist". The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology.

  3. Oil palm water use: calibration of a sap flux method and a field measurement scheme.

    PubMed

    Niu, Furong; Röll, Alexander; Hardanto, Afik; Meijide, Ana; Köhler, Michael; Hendrayanto; Hölscher, Dirk

    2015-05-01

    Oil palm (Elaeis guineensis Jacq.) water use was assessed by sap flux density measurements with the aim to establish the method and derive water-use characteristics. Thermal dissipation probes were inserted into leaf petioles of mature oil palms. In the laboratory, we tested our set-up against gravimetric measurements and derived new parameters for the original calibration equation that are specific to oil palm petioles. In the lowlands of Jambi, Indonesia, in a 12-year-old monoculture plantation, 56 leaves on 10 palms were equipped with one sensor per leaf. A 10-fold variation in individual leaf water use among leaves was observed, but we did not find significant correlations to the variables trunk height and diameter, leaf azimuthal orientation, leaf inclination or estimated horizontal leaf shading. We thus took an un-stratified approach to determine an appropriate sampling design to estimate stand transpiration (Es, mm day(-1)) rates of oil palm. We used the relative standard error of the mean (SEn, %) as a measure for the potential estimation error of Es associated with sample size. It was 14% for a sample size of 13 leaves to determine the average leaf water use and four palms to determine the average number of leaves per palm. Increasing these sample sizes only led to minor further decreases of the SEn of Es. The observed 90-day average of Es was 1.1 mm day(-1) (error margin ± 0.2 mm day(-1)), which seems relatively low, but does not contradict Penman-Monteith-derived estimates of evapotranspiration. Examining the environmental drivers of Es on an intra-daily scale indicates an early, pre-noon maximum of Es rates (11 am) due to a very sensitive reaction of Es to increasing vapor pressure deficit in the morning. This early peak is followed by a steady decline of Es rates for the rest of the day, despite further rising levels of vapor pressure deficit and radiation; this results in pronounced hysteresis, particularly between Es and vapor pressure deficit. PMID:25787332

  4. Increasing Waterflooding Reservoirs in the Wilmington Oil Field through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect

    Koerner, Roy; Clarke, Don; Walker, Scott

    1999-11-09

    The objectives of this quarterly report was to summarize the work conducted under each task during the reporting period April - June 1998 and to report all technical data and findings as specified in the ''Federal Assistance Reporting Checklist''. The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology.

  5. Increasing Waterflooding Reservoirs in the Wilmington Oil Field through Improved Reservoir Characterization and Reservoir Management

    SciTech Connect

    Clarke, Don; Koerner, Roy; Moos, Dan; Nguyen, John; Phillips, Chris; Tagbor, Kwasi; Walker, Scott

    1999-11-09

    The objectives of this quarterly report are to summarize the work conducted under each task during the reporting period July - September 1998 and to report all technical data and findings as specified in the ''Federal Assistance Reporting Checklist''. The main objective of this project is the transfer of technologies, methodologies, and findings developed and applied in this project to other operators of Slope and Basin Clastic Reservoirs. This project will study methods to identify sands with high remaining oil saturation and to recomplete existing wells using advanced completion technology.

  6. Getty: producing oil from diatomite

    SciTech Connect

    Zublin, L.

    1981-10-01

    Getty Oil Company has developed unconventional oil production techniques which will yield oil from diatomaceous earth. They propose to mine oil-saturated diatomite using open-pit mining methods. Getty's diatomite deposit in the McKittrick field of California is unique because it is cocoa brown and saturated with crude oil. It is classified also as a tightly packed deposit, and oil cannot be extracted by conventional oil field methods.

  7. Silica phase changes: Diagenetic agent for oil entrapment, Lost Hills field, California

    SciTech Connect

    Julander, D.R.; Szymanski, D.L. )

    1991-02-01

    The siliceous shales of the Monterey Group are the primary development target at Lost Hills. Silica phase changes have influenced the distribution and entrapment of hydrocarbons. With increasing temperature, opal A phase diatomite is converted to opal CT and finally quartz phase rock. All phases are low in permeability. The opal A diatomite is characteristically high in oil saturation and productive saturation. Productivity from this phase is dependent on structural position and fieldwide variations in oil viscosity and biodegradation. The deeper chert reservoir coincides with the opal CT to quartz phase transition. Porosity is again reduced in this transition, but saturations in the quartz phase rocks increase. Tests in the chert reservoir indicate a single, low-permeability system, suggesting the importance of matric contribution. resistivity and porosity in the diatomite, and resistivity and velocity in the chert, are the physical properties which best reflect saturation. Methods exploiting these properties (FMS, BHTV, borehole, and surface shear wave studies) should be helpful in further characterizing the reservoirs and identifying future pay.

  8. Brief history of fiber optic sensing in the oil field industry

    NASA Astrophysics Data System (ADS)

    Baldwin, Christopher S.

    2014-06-01

    The use of fiber optic sensing in the oil and gas industry has greatly expanded over the past two decades. Since the first optical fiber-based pressure sensor was installed in a well in 1993, the industry has sought to use fiber sensing technology to monitor in-well parameters. Through the years, optical fiber sensing has been used in an increasing number of applications as technical advances have opened the door for new measurements. Today, fiber optic sensors are used routinely to measure temperature throughout the wellbore. Optical sensors also provide pressure measurements at key locations within the well. These measurements are used to verify the integrity of the well, provide feedback during well completion operations, including the actuation of downhole valves, and to monitor the production or injection process. Other sensors, such as seismic monitors and flowmeters, use fiber sensing technology to make in-well measurements. Various optical sensing techniques are used to make these measurements, including Bragg grating, Raman scattering, and coherent Rayleigh scattering. These measurements are made in harsh environments, which require rugged designs for optical cable systems and instrumentation systems. Some of these applications have operating temperatures of 572°F (300°C), and other applications can have pressures in excess of 20,000 psi (1,379 bar). This paper provides a historical perspective on the use of fiber optic sensing in the oil and gas industry from industry firsts to current applications.

  9. Gas, Oil, and Water Production from Grand Valley, Parachute, Rulison, and Mamm Creek Fields in the Piceance Basin, Colorado

    USGS Publications Warehouse

    Nelson, Philip H.; Santus, Stephen L.

    2010-01-01

    Gas, oil, and water production data for tight gas reservoirs were compiled from selected wells in western Colorado. These reservoir rocks-the relatively shallow Paleogene Wasatch G sandstone interval in the Parachute and Rulison fields and fluvial sandstones in the deeper Upper Cretaceous Mesaverde Group in the Grand Valley, Parachute, Rulison, and Mamm Creek fields-are characterized by low permeability, low porosity, and the presence of clay minerals in pore space. Production from each well is represented by two samples spaced five years apart, the first sample typically taken two years after production commenced, which was generally in the 1990s. For each producing interval, summary diagrams of oil-versus-gas and water-versus-gas production show fluid production rates, the change in rates during five years, the water-gas and oil-gas ratios, and the fluid type. These diagrams permit well-to-well and field-to-field comparisons. Fields producing water at low rates (water dissolved in gas in the reservoir) can be distinguished from fields producing water at moderate or high rates, and the water-gas ratios are quantified. Dry gas is produced from the Wasatch G interval and wet gas is produced from the Mesaverde Group. Production from the Wasatch G interval is also almost completely free of water, but water production commences with gas production in wells producing from the Mesaverde Group-all of these wells have water-gas ratios exceeding the amount that could exist dissolved in gas at reservoir temperature and pressure. The lack of produced water from the Wasatch G interval is attributed to expansion of the gas accumulation with uplift and erosion. The reported underpressure of the Wasatch G interval is here attributed to hydraulic connection to the atmosphere by outcrops in the Colorado River valley at an elevation lower than that of the gas fields. The amount of reduction of gas production over the five-year time span between the first and second samples is roughly one-half, with median values of second-sample to first-sample gas-production ratios ranging from 0.40 for Rulison-Mesaverde to 0.63 for Rulison-Wasatch G. Commencing with the first sample, the logarithm-of-production rate appears to decline linearly with time in many wells. However, water production is much more erratic as a function of time from an individual well and also from one well to the next within a field. Water production can either decrease or increase with time (from the first to the second sample). In this study, slightly more than half the wells producing from the Mesaverde Group show decreases in water production with time. Plots of water decline versus gas decline show little relation between the two, with only the wells in Rulison field displaying some tendency for water and gas to decline proportionately

  10. Fracture density determination using a novel hybrid computational scheme: a case study on an Iranian Marun oil field reservoir

    NASA Astrophysics Data System (ADS)

    Nouri-Taleghani, Morteza; Mahmoudifar, Mehrzad; Shokrollahi, Amin; Tatar, Afshin; Karimi-Khaledi, Mina

    2015-04-01

    Most oil production all over the world is from carbonated reservoirs. Carbonate reservoirs are abundant in the Middle East, the Gulf of Mexico and in other major petroleum fields that are regarded as the main oil producers. Due to the nature of such reservoirs that are associated with low matrix permeability, the fracture is the key parameter that governs the fluid flow in porous media and consequently oil production. Conventional methods to determine the fracture density include utilizing core data and the image log family, which are both time consuming and costly processes. In addition, the cores are limited to certain intervals and there is no image log for the well drilled before the introduction of this tool. These limitations motivate petroleum engineers to try to find appropriate alternatives. Recently, intelligent systems on the basis of machine learning have been applied to various branches of science and engineering. The objective of this study is to develop a mathematical model to predict the fracture density using full set log data as inputs based on a combination of three intelligent systems namely, the radial basis function neural network, the multilayer perceptron neural network and the least square supported vector machine. The developed committee machine intelligent system (CMIS) is the weighted average of the individual results of each expert. Proper corresponding weights are determined using a genetic algorithm (GA). The other important feature of the proposed model is its generalization capability. The ability of this model to predict data that have not been introduced during the training stage is very good.

  11. Paclobutrazol treatment as a potential strategy for higher seed and oil yield in field-grown camelina sativa L. Crantz

    PubMed Central

    2012-01-01

    Background Camelina (Camelina sativa L. Crantz) is a non-food oilseed crop which holds promise as an alternative biofuel energy resource. Its ability to grow in a variety of climatic and soil conditions and minimal requirements of agronomical inputs than other oilseed crops makes it economically viable for advanced biofuel production. We designed a study to investigate the effect of paclobutrazol [2RS, 3RS)-1-(4-Chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pentan-3-ol] (PBZ), a popular plant growth regulator, on the seed and oil yield of Camelina sativa (cv. Celine). Results A field-based micro-trial setup was established in a randomized block design and the study was performed twice within a span of five months (October 2010 to February 2011) and five different PBZ treatments (Control: T0; 25 mg l-1: T1; 50 mg l-1: T2; 75 mg l-1: T3; 100 mg l-1: T4; 125 mg l-1: T5) were applied (soil application) at the time of initiation of flowering. PBZ at 100 mg l-1 concentration (T4) resulted in highest seed and oil yield by 80% and 15%, respectively. The seed yield increment was mainly due to enhanced number of siliques per plant when compared to control. The PBZ - treated plants displayed better photosynthetic leaf gas exchange characteristics, higher chlorophyll contents and possessed dark green leaves which were photosynthetically active for a longer period and facilitated higher photoassimilation. Conclusion We report for the first time that application of optimized PBZ dose can be a potential strategy to achieve higher seed and oil yield from Camelina sativa that holds great promise as a biofuel crop in future. PMID:22410213

  12. Study on spatial variation of land subsidence over Minagish-Umm Gudair oil fields of Kuwait using synthetic aperture radar interferometry technique

    NASA Astrophysics Data System (ADS)

    Rao, Kota S.; Al Jassar, Hala K.; Kodiyan, Nevil J.; Daniel, Viju P.

    2016-01-01

    Land subsidence can be a major problem where there are large-scale underground activities such as oil extraction. This paper addresses the spatial variability of land subsidence over Minagish and Umm Gudair oil fields of Kuwait. Synthetic aperture radar interferometry (InSAR) with multiple reference scenes using a persistent scatterer InSAR toolchain was employed in this study. Twenty-nine scenes of advanced synthetic aperture radar data (for the period January 2005 to August 2009) were used to make 20 pairs of interferograms (with high coherence and low noise) of stable point-like reflectors. The output of this study is the land subsidence maps of Minagish and Umm Gudair oil fields with a spatial resolution of 40 m. The results indicate that there is land subsidence of 29.9 mm/year in the southern part of the oil field (Umm Gudair). This is the first detailed assessment of land subsidence in the Minagish-Umm Gudair oil fields; therefore, no ground-truth data are available to compare the subsidence results. The results were consistent, indicating their validity.

  13. Gupco's experience in treating Gulf of Suez seawater for waterflooding the El Morgan oil field

    SciTech Connect

    El-Hattab, M.I.

    1982-07-01

    Pressure maintenance by waterflooding in some reservoirs may be considered essential for satisfactory oil recovery. The main objective of waterflooding is to place water into a rock formation at both the desired rate and pressure with minimal expense and trouble. This objective, however, cannot be achieved unless this water has certain characteristics. The water, therefore, should be treated and conditioned before injection. This study addresses the treatment phases adopted to improve seawater quality before injection, and to control problems associated with untreated seawater. Also discussed are GUPCO'S (Gulf of Suez Petroleum Co.) experience in seawaterfloods, problems encountered, and corrective actions taken to overcome these problems. The chemical treatment programs adopted are presented along with final conclusions and recommendations that can be applied to similar floods in Egypt with (Gulf of Suez) GOS. 47 refs.

  14. Trajectory of an oil spill off Goa, eastern Arabian Sea: field observations and simulations.

    PubMed

    Vethamony, P; Sudheesh, K; Babu, M T; Jayakumar, S; Manimurali, R; Saran, A K; Sharma, L H; Rajan, B; Srivastava, M

    2007-07-01

    An oil spill occurred off Goa, west coast of India, on 23 March 2005 due to collision of two vessels. In general, fair weather with weak winds prevails along the west coast of India during March. In that case, the spill would have moved slowly and reached the coast. However, in 2005 when this event occurred, relatively stronger winds prevailed, and these winds forced the spill to move away from the coast. The spill trajectory was dominated by winds rather than currents. The MIKE21 Spill Analysis model was used to simulate the spill trajectory. The observed spill trajectory and the slick area were in agreement with the model simulations. The present study illustrates the importance of having pre-validated trajectories of spill scenarios for selecting eco-sensitive regions for preparedness and planning suitable response strategies whenever spill episodes occur. PMID:17291649

  15. Map showing geology, oil and gas fields, and geologic provinces of the Gulf of Mexico region

    USGS Publications Warehouse

    French, Christopher D., (compiler); Schenk, Christopher J.

    2006-01-01

    This map was created as part of a worldwide series of geologic maps for the U.S. Geological Survey's World Energy Project. These products are available on CD-ROM and the Internet. The goal of the project is to assess the undiscovered, technically recoverable oil and gas resources of the world. Two previously published digital geologic data sets (U.S. and Caribbean) were clipped to the map extent, while the dataset for Mexico was digitized for this project. Original attributes for all data layers were maintained, and in some cases, graphically merged with common symbology for presentation purposes. The world has been divided into geologic provinces that are used for allocation and prioritization of oil and gas assessments. For the World Energy Project, a subset of those provinces is shown on this map. Each province has a set of geologic characteristics that distinguish it from surrounding provinces. These characteristics may include dominant lithologies, the age of the strata, and/or structural type. The World Geographic Coordinate System of 1984 is used for data storage, and the data are presented in a Lambert Conformal Conic Projection on the OFR 97-470-L map product. Other details about the map compilation and data sources are provided in metadata documents in the data section on this CD-ROM. Several software packages were used to create this map including: Environmental Systems Research Institute, Inc. (ESRI) ArcGIS 8.3, ArcInfo software, Adobe Photoshop CS, Illustrator CS, and Acrobat 6.0.

  16. ADAPTIVE MANAGEMENT AND PLANNING MODELS FOR CULTURAL RESOURCES IN OIL & GAS FIELDS IN NEW MEXICO AND WYOMING

    SciTech Connect

    Peggy Robinson

    2005-07-01

    This report summarizes activities that have taken place in the last six (6) months (January 2005-June 2005) under the DOE-NETL cooperative agreement ''Adaptive Management and Planning Models for Cultural Resources in Oil and Gas Fields, New Mexico and Wyoming'' DE-FC26-02NT15445. This project examines the practices and results of cultural resource investigation and management in two different oil and gas producing areas of the United States: southeastern New Mexico and the Powder River Basin of Wyoming. The project evaluates how cultural resource investigations have been conducted in the past and considers how investigation and management could be pursued differently in the future. The study relies upon full database population for cultural resource inventories and resources and geomorphological studies. These are the basis for analysis of cultural resource occurrence, strategies for finding and evaluating cultural resources, and recommendations for future management practices. Activities can be summarized as occurring in either Wyoming or New Mexico. Gnomon as project lead, worked in both areas.

  17. [Carbon source utilization characteristics of microbial communities in a petroleum-contaminated soil in Daqing Oil Field, Northeast China].

    PubMed

    Yue, Bing-Bing; Li, Xin; Ren, Fang-Fei; Meng, Fan-Juan; Yin, Peng-Da; Zhang, Hui-Hui; Sun, Guang-Yu

    2011-12-01

    By using Biolog technique, this paper studied the carbon source utilization characteristics of microbial communities in different layers (0-10 cm, 10-20 cm, and 20-30 cm) of a petroleum-contaminated soil near an oil well having exploited for 36 years in Daqing Oil Field. Petroleum contamination enhanced the metabolic activity of the soil microbial communities obviously. In the three layers of the petroleum-contaminated soil, the metabolic activity of the microbes was higher than that of the control, and there existed significant differences between different layers of the petroleum-contaminated soil. The carbon source metabolic capacity of the microbes in different layers of the petroleum-contaminated soil was in the order of 20-30 cm > 10-20 cm > 0-10 cm. Petroleum contamination made the kinds of soil carbon source and the metabolic diversity of soil microbes increased, being more obvious in 10-20 cm and 20-30 cm soil layers but less change in 0-10 cm soil layer. In the contaminated soil, the majority of the carbon sources utilized by the microbes in 10-20 cm soil layer were carbohydrates instead of the carboxylic acids in non-contaminated soil, whereas the majority of the carbon substrates utilized in 20-30 cm soil layer were carboxylic acids. All the results suggested that petroleum-contaminated soil had its unique microbial community structure and peculiar microbial carbon source utilization characteristics. PMID:22384595

  18. Modern Processes of Hydrocarbon Migration and Re-Formation of Oil and Gas Fields (Based on the Results of Monitoring and Geochemical Studies)

    NASA Astrophysics Data System (ADS)

    Plotnikova, Irina; Salakhidinova, Gulmira; Nosova, Fidania; Pronin, Nikita; Ostroukhov, Sergey

    2015-04-01

    Special geochemical studies of oils allowed to allocate a movable migration component of oils in the industrial oil deposits. In the field the migration component of oils varies in different parts of the field. The largest percentage of the light migration component (gas condensate of the oil) was detected in the central part of the Kama-Kinel troughs system. Monitoring of the composition of water, oil and gas (condensate light oil component) in the sedimentary cover and ni crystalline basement led to the conclusion of modern migration of hydrocarbons in sedimentary cover. This proves the existence of the modern processes of formation and reformation of oil and gas fields. This presentation is dedicated to the problem of definition of geochemical criteria of selection of hydrocarbons deposit reformation zone in the sample wells of Minibaevskaya area of Romashkinskoye field. While carrying out this work we examined 11 samples of oil from the Upper Devonian Pashiysky horizon. Four oil samples were collected from wells reckoned among the "anomalous" zones that were marked out according to the results of geophysical, oil field and geological research. Geochemical studies of oils were conducted in the laboratory of geochemistry of the Kazan (Volga-region) Federal University. The wells where the signs of hydrocarbons influx from the deep zones of the crust were recorded are considered to be "anomalous". A number of scientists connect this fact to the hypothesis about periodic influx of deep hydrocarbons to the oil deposits of Romashkinskoye field. Other researchers believe that the source rocks of the adjacent valleys sedimentary cover generate gases when entering the main zone of gas formation, which then migrate up the section and passing through the previously formed deposits of oil, change and "lighten" their composition. Regardless of the point of view on the source of the hydrocarbons, the study of the process of deposits refilling with light hydrocarbons is an important fundamental task of exceptional practical importance. The reservoir water monitoring has been conducted in five wells that have penetrated the water-saturated, loosely aggregated zones of the South Tatarstan Arch's basement. The long-term testing resulted in the production of reservoir water from the basement. The sedimentary cover in these wells is blocked by the column, which prevents water cross-flowing from the sedimentary cover. The observations have shown that the levels, gas saturation, mineralisation, density, and composition of reservoir waters from the loosely aggregated zones of the basement change with time. The varying characteristics of the water include its component composition, redox potential, and amount of chlorine and some other components and trace elements. Compositional changes in gases of the loosely aggregated zones of the basement, variations in the gas saturation of reservoir waters and of their composition, the decreasing density of oil in the sedimentary cover, - all result from one cause. This cause is the movement of fluids (solutions and gases dissolved in them) through the loosely aggregated zones and faults of the Earth's crust and the sedimentary cover. The fluids mainly move vertically in an upward direction, although their migration through subhorizontal, loosely aggregated zones of the crystalline basement is also possible. Fluid migration still takes place in the Earth's crust of ancient platforms. This phenomenon indicates that some portions of the platforms - primarily, their margins - periodically resume tectonic activities. The fluid dynamic activity of the crust define the processes in the sedimentary cover. It affects the development of the sedimentary basin during the sedimentation period, and the formation of mineral deposits. The monitoring of the present-day movement of fluid systems in the loosely aggregated zones of the basement will permit the more detailed study of the present-day fluid regime in the upper portion of the Earth's crust and the sedimentary cover.

  19. Repellency of oils of lemon eucalyptus, geranium, and lavender and the mosquito repellent MyggA natural to Ixodes ricinus (Acari: Ixodidae) in the laboratory and field.

    PubMed

    Jaenson, Thomas G T; Garboui, Samira; Palsson, Katinka

    2006-07-01

    MyggA Natural (Bioglan, Lund, Sweden) is a commercially available repellent against blood-feeding arthropods. It contains 30% of lemon-scented eucalyptus, Corymbia citriodora (Hook.) K. D. Hill & L. A. S. Johnson (Myrtaceae), oil with a minimum of 50% p-menthane-3,8-diol. MyggA Natural also contains small amounts of the essential oils of lavender, Lavandula angustifolia Mill. (Lamiaceae), and geranium, Pelargonium graveolens L'Her. (Geraniaceae). In laboratory bioassays, MyggA Natural and C. citriodora oil exhibited 100% repellency against host-seeking nymphs of Ixodes ricinus (L.) (Acari: Ixodidae). Lavender oil and geranium oil, when diluted to 1% in 1,2-propanediol, had weak repellent activities on I. ricinus nymphs, but when diluted to 30% in 1,2-propanediol had 100% repellencies. 1,2-Propanediol (100%) had no significant repellent activity in comparison with that of the control. In field tests in tick-infested areas in central Sweden, tick repellency of MyggA Natural and C. citriodora oil was tested by the blanket-dragging technique for 4 d during a 6-d period. The repellencies (74 and 85%, respectively) on day 1 are similar (89%) to that of blankets treated in a similar manner with 19% diethyl-methyl-benzamide, based on previous work. Repellencies declined significantly from day 1 to day 6 (74 to 45% for MyggA Natural; 85 to 42% for C. citriodora oil). PMID:16892632

  20. Producing Light Oil from a Frozen Reservoir: Reservoir and Fluid Characterization of Umiat Field, National Petroleum Reserve, Alaska

    SciTech Connect

    Hanks, Catherine

    2012-12-31

    Umiat oil field is a light oil in a shallow, frozen reservoir in the Brooks Range foothills of northern Alaska with estimated oil-in-place of over 1 billion barrels. Umiat field was discovered in the 1940’s but was never considered viable because it is shallow, in the permafrost, and far from any transportation infrastructure. The advent of modern drilling and production techniques has made Umiat and similar fields in northern Alaska attractive exploration and production targets. Since 2008 UAF has been working with Renaissance Alaska Inc. and, more recently, Linc Energy, to develop a more robust reservoir model that can be combined with rock and fluid property data to simulate potential production techniques. This work will be used to by Linc Energy as they prepare to drill up to 5 horizontal wells during the 2012-2013 drilling season. This new work identified three potential reservoir horizons within the Cretaceous Nanushuk Formation: the Upper and Lower Grandstand sands, and the overlying Ninuluk sand, with the Lower Grandstand considered the primary target. Seals are provided by thick interlayered shales. Reserve estimates for the Lower Grandstand alone range from 739 million barrels to 2437 million barrels, with an average of 1527 million bbls. Reservoir simulations predict that cold gas injection from a wagon-wheel pattern of multilateral injectors and producers located on 5 drill sites on the crest of the structure will yield 12-15% recovery, with actual recovery depending upon the injection pressure used, the actual Kv/Kh encountered, and other geologic factors. Key to understanding the flow behavior of the Umiat reservoir is determining the permeability structure of the sands. Sandstones of the Cretaceous Nanushuk Formation consist of mixed shoreface and deltaic sandstones and mudstones. A core-based study of the sedimentary facies of these sands combined with outcrop observations identified six distinct facies associations with distinctive permeability trends. The Lower Grandstand sand consists of two coarsening-upward shoreface sands sequences while the Upper Grandstand consists of a single coarsening-upward shoreface sand. Each of the shoreface sands shows a distinctive permeability profile with high horizontal permeability at the top getting progressively poorer towards the base of the sand. In contrast, deltaic sandstones in the overlying Ninuluk are more permeable at the base of the sands, with decreasing permeability towards the sand top. These trends impart a strong permeability anisotropy to the reservoir and are being incorporated into the reservoir model. These observations also suggest that horizontal wells should target the upper part of the major sands. Natural fractures may superimpose another permeability pattern on the Umiat reservoir that need to be accounted for in both the simulation and in drilling. Examination of legacy core from Umiat field indicate that fractures are present in the subsurface, but don't provide information on their orientation and density. Nearby surface exposures of folds in similar stratigraphy indicate there are at least three possible fracture sets: an early, N/S striking set that may predate folding and two sets possibly related to folding: an EW striking set of extension fractures that are parallel to the fold axes and a set of conjugate shear fractures oriented NE and NW. Analysis of fracture spacing suggests that these natural fractures are fairly widely spaced (25-59 cm depending upon the fracture set), but could provide improved reservoir permeability in horizontal legs drilled perpendicular to the open fracture set. The phase behavior of the Umiat fluid needed to be well understood in order for the reservoir simulation to be accurate. However, only a small amount of Umiat oil was available; this oil was collected in the 1940’s and was severely weathered. The composition of this ‘dead’ Umiat fluid was characterized by gas chromatography. This analysis was then compared to theoretical Umiat composition derived using the Pedersen method with original Umiat fluid properties published in the original reports. This comparison allowed estimation of the ‘lost’ light hydrocarbon fractions. An Umiat 'dead' oil sample then could be physically created by adding the lost light ends to the weatherized Umiat dead oil sample. This recreated sample was recombined with solution gas to create a 'pseudo-live' Umiat oil sample which was then used for experimental PVT and phase behavior studies to determine fluid properties over the range of reservoir pressures and temperatures. The phase behavior of the ‘pseudo-live’ oil was also simulated using the Peng- Robinson equations of state (EOS). The EOS model was tuned with measured experimental data to accurately simulate the differential liberation tests in order to obtain the necessary data for reservoir simulation studies, including bubble point pressure and oil viscosity. The bubble point pressure of the reconstructed Umiat oil is 345 psi, suggesting that maintenance of reservoir pressures above that pressure will be important for the any proposed production technique. A major part of predicting how the Umiat reservoir will perform is determining the relative permeability of oil in the presence of ice. Early in the project, UAF work on samples of the Umiat reservoir indicated that there is a significant reduction in the relatively permeability of oil in the presence of ice. However, it was not clear as to why this reduction occurred or where the ice resided. To explore this further, additional experimental and theoretical work was conducted. Core flood experiments were performed on two clean Berea sandstone cores under permafrost conditions to determine the relative permeability to oil (kro) over a temperature range of 23ºC to - 10ºC and for a range of connate water salinities. Both cores showed maximum reduction in relative permeability to oil when saturated with deionized water and less reduction when saturated with saline water. This reduction in relative permeability can be explained by formation of ice crystals in the center of pores. Theoretically, the radius of ice formed in the center of the pore can be determined using the Kozeny–Carman Equation by assuming the pores and pore throats as a cube with ‘N’ identical parallel pipes embedded in it. Using the values of kro obtained from the experimental work as input to the Kozeny–Carman Equation at -10ºC, the radius of ice crystals dropped from 0.145 μm to 0.069 μm when flooding-water salinity is increased to 6467 ppm. This explains the reduction of relative permeability with decreasing salinity but does not take into consideration other effects such as variations in pore throat structure. In addition, fluids like deionized water, saline water, and antifreeze (a mixture of 60% ethylene or propylene glycol with 40% water) were tested to find the best flooding agent for frozen reservoirs. At 0ºC, 9% greater recovery was observed with antifreeze was used as a flooding agent as compared to using saline water. Antifreeze showed 48% recovery even at -10ºC, at which temperature the rest of the fluids failed to increase production. Preliminary evaluation of drilling fluids indicate that the brine-based muds caused significantly less swelling in the Umiat reservoir sands when compared to fresh-water based muds. However since freezing filtrate is another cause of formation damage, a simple water-based-mud may not a viable option. It is recommended that new fluids be tested, including different salts, brines, polymers and oil-based fluids. These fluids should be tested at low temperatures in order to determine the potential for formation damage, the fluid properties under these conditions and to ensure that the freezing point is below that of the reservoir. In order to reduce the surface footprint while accessing the maximum amount of the Lower Grandstand interval, simulations used development from 5 surface locations with a wagon-wheel pattern of multilateral injectors and producers. There is no active aquifer support due to small peizometric head in the area and no existing gas cap, so an alternative method of pressure support is needed. Cold gas injection was used in the simulations as it is considered the most viable means of providing pressure maintenance while maintaining wellbore stability and reducing impact on the permafrost. Saline water injection may be a viable alternative, though this may have a detrimental effect on permafrost. In the short term, the results of this work are being incorporated into Linc Energy’s drilling and development plan. This project has also provided valuable information on the rock and fluid properties of low temperature reservoirs as well as the efficacy of potential production techniques for Umiat or similar shallow frozen reservoirs in the circum-Arctic.

  1. Field trial evaluation of the accumulation of omega-3 long chain polyunsaturated fatty acids in transgenic Camelina sativa: Making fish oil substitutes in plants

    PubMed Central

    Usher, Sarah; Haslam, Richard P.; Ruiz-Lopez, Noemi; Sayanova, Olga; Napier, Johnathan A.

    2015-01-01

    The global consumption of fish oils currently exceeds one million tonnes, with the natural de novo source of these important fatty acids forming the base of marine foodwebs. Here we describe the first field-based evaluation of a terrestrial source of these essential nutrients, synthesised in the seeds of transgenic Camelina sativa plants via the heterologous reconstitution of the omega-3 long chain polyunsaturated fatty acid biosynthetic pathway. Our data demonstrate the robust nature of this novel trait, and the feasibility of making fish oils in genetically modified crops. Moreover, to our knowledge, this is the most complex example of plant genetic engineering to undergo environmental release and field evaluation. PMID:27066395

  2. Field-scale evidence for biogeophysical signatures resulting from natural attenuation of a well characterized crude oil spill

    NASA Astrophysics Data System (ADS)

    Slater, L. D.; Revil, A.; Atekwana, E. A.; Mewafy, F.; Bekins, B. A.; Cozzarelli, I.; Herkelrath, W. N.; Skold, M.; Ntarlagiannis, D.; Trost, J.; Erickson, M.; Heenan, J. W.; Lane, J. W.; Werkema, D. D.

    2012-12-01

    Recent biogeophysical research has indicated that unique geophysical signatures are associated with the long-term biodegradation of organic contaminants. However, field-scale demonstrations of the presence of these signatures at sites of organic contamination are lacking. For the last three years, we have performed geophysical measurements at the National Crude Oil Spill Fate and Natural Attenuation Research Site, a unique field laboratory situated just outside of Bemidji, MN. At this site, a ruptured pipeline spilled 1,700,000 L of crude oil into an uninhabited area in 1979. Natural attenuation of the spill has been extensively documented and a geochemical database extending back over 20 years is available to constrain interpretation of the geophysical signatures. We report compelling evidence of a transient geobattery associated with biodegradation of this mature hydrocarbon spill. Using an array of boreholes, self-potential measurements acquired from land surface, passing through the smear zone, capture a diagnostic dipole (peak to peak voltages up to 64 mV) indicating a current source centered on the smear zone, with anodic and cathodic reactions below and above the smear zone respectively. Down borehole measurements reveal that the smear zone is characterized by high magnetic susceptibility (MS); laboratory measurements show that this MS enhancement results from precipitation of iron mineral byproducts of biodegradation. These iron minerals presumably facilitate the electron transport between anode and cathode required to support a geobattery. Furthermore, laboratory and field-scale complex resistivity measurements reveal an enhancement in the complex surface conductivity within the smear zone most likely due to these biodegradation byproducts. The geobattery is not permanent, but instead periodically shuts down, presumably due to changes in the gradient of the redox species driving anodic and cathodic reactions. Gas samples show that conditions are anaerobic immediately above the iron mineral byproducts; this suggests that the geobattery is not driven by an aerobic to aerobic transition but instead requires an alternative driving redox couple excluding oxygen. Although further work is needed to fully decipher the origins of these signals, our results at this unique field laboratory indicate that strong field-scale biogeophysical signatures may be expected over mature hydrocarbon spill sites.

  3. ADAPTIVE MANAGEMENT AND PLANNING MODELS FOR CULTURAL RESOURCES IN OIL & GAS FIELDS IN NEW MEXICO AND WYOMING

    SciTech Connect

    Peggy Robinson

    2004-01-01

    This report contains a summary of activities of Gnomon, Inc. and five subcontractors that have taken place during the second six months (July 1, 2003-December 31, 2003) under the DOE-NETL cooperative agreement: ''Adaptive Management and Planning Models for Cultural Resources in Oil & Gas Fields in New Mexico and Wyoming'', DE-FC26-02NT15445. Although Gnomon and all five subcontractors completed tasks during these six months, most of the technical experimental work was conducted by the subcontractor, SRI Foundation (SRIF). SRIF created a sensitivity model for the Loco Hills area of southeastern New Mexico that rates areas as having a very good chance, a good chance, or a very poor chance of containing cultural resource sites. SRIF suggested that the results of the sensitivity model might influence possible changes in cultural resource management (CRM) practices in the Loco Hills area of southeastern New Mexico.

  4. Leaching of polycyclic aromatic hydrocarbons from oil shale processing waste deposit: a long-term field study.

    PubMed

    Jefimova, Jekaterina; Irha, Natalya; Reinik, Janek; Kirso, Uuve; Steinnes, Eiliv

    2014-05-15

    The leaching behavior of selected polycyclic aromatic hydrocarbons (PAHs) from an oil shale processing waste deposit was monitored during 2005-2009. Samples were collected from the deposit using a special device for leachate sampling at field conditions without disturbance of the upper layers. Contents of 16 priority PAHs in leachate samples collected from aged and fresh parts of the deposit were determined by GC-MS. The sum of the detected PAHs in leachates varied significantly throughout the study period: 19-315 μg/l from aged spent shale, and 36-151 μg/l from fresh spent shale. Among the studied PAHs the low-molecular weight compounds phenanthrene, naphthalene, acenaphthylene, and anthracene predominated. Among the high-molecular weight PAHs benzo[a]anthracene and pyrene leached in the highest concentrations. A spent shale deposit is a source of PAHs that could infiltrate into the surrounding environment for a long period of time. PMID:24631927

  5. ADAPTIVE MANAGEMENT AND PLANNING MODELS FOR CULTURAL RESOURCES IN OIL & GAS FIELDS IN NEW MEXICO AND WYOMING

    SciTech Connect

    Peggy Robinson

    2004-07-01

    This report contains a summary of activities of Gnomon, Inc. and five subcontractors that have taken place during the first six months of 2004 (January 1, 2004-June 30, 2004) under the DOE-NETL cooperative agreement: ''Adaptive Management and Planning Models for Cultural Resources in Oil & Gas Fields in New Mexico and Wyoming'', DE-FC26-02NT15445. Although Gnomon and all five subcontractors completed tasks during these six months, most of the technical experimental work was conducted by the subcontractor, SRI Foundation (SRIF). SRIF created a sensitivity model for the Azotea Mesa area of southeastern New Mexico that rates areas as having a very good chance, a good chance, or a very poor chance of containing cultural resource sites. SRIF suggested that the results of the sensitivity model might influence possible changes in cultural resource management (CRM) practices in the Azote Mesa area of southeastern New Mexico.

  6. Ex situ bioremediation of a soil contaminated by mazut (heavy residual fuel oil)--a field experiment.

    PubMed

    Beškoski, Vladimir P; Gojgić-Cvijović, Gordana; Milić, Jelena; Ilić, Mila; Miletić, Srdjan; Solević, Tatjana; Vrvić, Miroslav M

    2011-03-01

    Mazut (heavy residual fuel oil)-polluted soil was exposed to bioremediation in an ex situ field-scale (600 m(3)) study. Re-inoculation was performed periodically with biomasses of microbial consortia isolated from the mazut-contaminated soil. Biostimulation was conducted by adding nutritional elements (N, P and K). The biopile (depth 0.4m) was comprised of mechanically mixed polluted soil with softwood sawdust and crude river sand. Aeration was improved by systematic mixing. The biopile was protected from direct external influences by a polyethylene cover. Part (10 m(3)) of the material prepared for bioremediation was set aside uninoculated, and maintained as an untreated control pile (CP). Biostimulation and re-inoculation with zymogenous microorganisms increased the number of hydrocarbon degraders after 50 d by more than 20 times in the treated soil. During the 5 months, the total petroleum hydrocarbon (TPH) content of the contaminated soil was reduced to 6% of the initial value, from 5.2 to 0.3 g kg(-1) dry matter, while TPH reduced to only 90% of the initial value in the CP. After 150 d there were 96%, 97% and 83% reductions for the aliphatic, aromatic, and nitrogen-sulphur-oxygen and asphaltene fractions, respectively. The isoprenoids, pristane and phytane, were more than 55% biodegraded, which indicated that they are not suitable biomarkers for following bioremediation. According to the available data, this is the first field-scale study of the bioremediation of mazut and mazut sediment-polluted soil, and the efficiency achieved was far above that described in the literature to date for heavy fuel oil. PMID:21288552

  7. Using chemical and isotopic data to quantify ionic trapping of injected carbon dioxide in oil field brines

    SciTech Connect

    Mark Raistrick; Bernhard Mayer; Maurice Shevalier; Renee J. Perez; Ian Hutcheon; Ernie Perkins; Bill Gunter

    2006-11-01

    Injection of carbon dioxide into depleted oil fields or deep saline aquifers represents one of the most promising means of long-term storage of this greenhouse gas. While the ultimate goal of CO{sub 2} injection in the subsurface is mineral storage of CO{sub 2} as carbonates, short-term ({lt}50 year) storage of injected CO{sub 2} is most likely to be accomplished by ionic trapping of CO{sub 2} as bicarbonate ions (HCO{sub 3}{sup -}) and hydrogeological trapping of molecular CO{sub 2}. Here, a technique is demonstrated for quanti