Science.gov

Sample records for bulk solids handling

  1. Understanding particulate solids: Five classifications represent the first step in specifying bulk solids handling equipment

    SciTech Connect

    Kolatac, R.P.

    1996-04-01

    Guidelines for the classification of bulk solids are presented, and considered with respect to the development of equipment specifications for processing and conveying. The broad-based classifications are for particulate solids considered ready for processing. The main properties considered for classification are directly related to particle size and shape and to adhesive/cohesive tendencies. Equipment and system design considerations due to static and dynamic bulk density, compressibility, particle size distribution, angle of repose, and angle of slide are also outlined. 2 tabs.

  2. Bulk material handling system

    DOEpatents

    Kleysteuber, William K.; Mayercheck, William D.

    1979-01-01

    This disclosure relates to a bulk material handling system particularly adapted for underground mining and includes a monorail supported overhead and carrying a plurality of conveyors each having input and output end portions with the output end portion of a first of the conveyors positioned above an input end portion of a second of the conveyors, a device for imparting motion to the conveyors to move the material from the input end portions toward the output end portions thereof, a device for supporting at least one of the input and output end portions of the first and second conveyors from the monorail, and the supporting device including a plurality of trolleys rollingly supported by the monorail whereby the conveyors can be readily moved therealong.

  3. ROTARY BULK SOLIDS DIVIDER

    DOEpatents

    Maronde, Carl P.; Killmeyer JR., Richard P.

    1992-03-03

    An apparatus for the disbursement of a bulk solid sample comprising, a gravity hopper having a top open end and a bottom discharge end, a feeder positioned beneath the gravity hopper so as to receive a bulk solid sample flowing from the bottom discharge end, and a conveyor receiving the bulk solid sample from the feeder and rotating on an axis that allows the bulk solid sample to disperse the sample to a collection station.

  4. Rotary bulk solids divider

    DOEpatents

    Maronde, Carl P.; Killmeyer, Jr., Richard P.

    1992-01-01

    An apparatus for the disbursement of a bulk solid sample comprising, a gravity hopper having a top open end and a bottom discharge end, a feeder positioned beneath the gravity hopper so as to receive a bulk solid sample flowing from the bottom discharge end, and a conveyor receiving the bulk solid sample from the feeder and rotating on an axis that allows the bulk solid sample to disperse the sample to a collection station.

  5. Solid handling valve

    DOEpatents

    Williams, William R.

    1979-01-01

    The present invention is directed to a solids handling valve for use in combination with lock hoppers utilized for conveying pulverized coal to a coal gasifier. The valve comprises a fluid-actuated flow control piston disposed within a housing and provided with a tapered primary seal having a recessed seat on the housing and a radially expandable fluid-actuated secondary seal. The valve seals are highly resistive to corrosion, erosion and abrasion by the solids, liquids, and gases associated with the gasification process so as to minimize valve failure.

  6. Solid waste handling

    SciTech Connect

    Parazin, R.J.

    1995-05-31

    This study presents estimates of the solid radioactive waste quantities that will be generated in the Separations, Low-Level Waste Vitrification and High-Level Waste Vitrification facilities, collectively called the Tank Waste Remediation System Treatment Complex, over the life of these facilities. This study then considers previous estimates from other 200 Area generators and compares alternative methods of handling (segregation, packaging, assaying, shipping, etc.).

  7. 46 CFR 97.12-1 - Definition of a bulk solid cargo.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Definition of a bulk solid cargo. 97.12-1 Section 97.12... OPERATIONS Bulk Solid Cargoes § 97.12-1 Definition of a bulk solid cargo. (a) A bulk solid cargo— (1.... (b) Additional requirements for bulk solid materials needing special handling are contained in...

  8. 46 CFR 97.12-1 - Definition of a bulk solid cargo.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Definition of a bulk solid cargo. 97.12-1 Section 97.12... OPERATIONS Bulk Solid Cargoes § 97.12-1 Definition of a bulk solid cargo. (a) A bulk solid cargo— (1.... (b) Additional requirements for bulk solid materials needing special handling are contained in...

  9. 46 CFR 97.12-1 - Definition of a bulk solid cargo.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Definition of a bulk solid cargo. 97.12-1 Section 97.12... OPERATIONS Bulk Solid Cargoes § 97.12-1 Definition of a bulk solid cargo. (a) A bulk solid cargo— (1.... (b) Additional requirements for bulk solid materials needing special handling are contained in...

  10. 46 CFR 97.12-1 - Definition of a bulk solid cargo.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Definition of a bulk solid cargo. 97.12-1 Section 97.12... OPERATIONS Bulk Solid Cargoes § 97.12-1 Definition of a bulk solid cargo. (a) A bulk solid cargo— (1.... (b) Additional requirements for bulk solid materials needing special handling are contained in...

  11. 76 FR 8658 - Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-02-15

    ...), 1974, as amended, that carry bulk solid cargoes other than grain. The final rule (75 FR 64586) allows... SECURITY Coast Guard 46 CFR Part 148 RIN 1625-AB47 Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes (IMSBC) Code AGENCY: Coast Guard, DHS. ACTION: Rule;...

  12. 75 FR 34682 - Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-18

    ... SECURITY Coast Guard 46 CFR Parts 97 and 148 RIN 1625-AB47 Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes (IMSBC) Code; Correction AGENCY: Coast Guard, DHS... proposed rule published in the Federal Register on June 17, 2010, entitled ``Bulk Solid Hazardous...

  13. 49 CFR 176.72 - Handling of break-bulk hazardous materials.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false Handling of break-bulk hazardous materials. 176.72... VESSEL General Handling and Stowage § 176.72 Handling of break-bulk hazardous materials. (a) A metal bale... to lift or move cargo by means of pressure exerted on the packages may not be used for handling...

  14. 75 FR 64585 - Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-19

    ...The Coast Guard is harmonizing its regulations with amendments to Chapter VI and Chapter VII of the International Maritime Organization (IMO) International Convention for the Safety of Life at Sea, 1974, as amended, (SOLAS) that make the International Maritime Solid Bulk Cargoes (IMSBC) Code mandatory. The amendments require that all vessels subject to SOLAS, and carrying bulk solid cargoes......

  15. APPARATUS FOR HANDLING MIXTURES OF SOLID MATERIALS

    DOEpatents

    Hubbell, J.P.

    1959-08-25

    An apparatus is described for handling either a mixture of finely subdivided materials or a single material requiring a compacting action thereon preparatory to a chemical reducing process carried out in a crucible container. The apparatus is designed to deposit a mixture of dust-forming solid materials in a container while confining the materials against escape into the surrounding atmosphere. A movable filling tube, having a compacting member, is connected to the container and to a covered hopper receiving the mixture of materials. The filling tube is capable of reciprocating in the container and their relative positions are dependent upon the pressure established upon the material by the compacting member.

  16. Estimates of atmospheric particle emissions from bulk handling of dusty materials in Spanish Harbours

    NASA Astrophysics Data System (ADS)

    Martín, F.; Pujadas, M.; Artiñano, B.; Gómez-Moreno, F.; Palomino, I.; Moreno, N.; Alastuey, A.; Querol, X.; Basora, J.; Luaces, J. A.; Guerra, A.

    The objective of this paper is to show the methodology developed to estimate particle emissions from several typical activities of bulk handling in harbours. It is based on several field experiments carried out in the Harbour of Tarragona, where high time resolution monitors were deployed close to different areas of bulk solids handling operations. Monitors recorded particle concentrations and meteorological variables. A high-resolution dispersion model is used to estimate the emission rates that best fits the observations. Results were comparable to those obtained with the AP-42 (EPA). The new emission estimates are used as input for an emission model called EMIPORT. The model also employs AP-42 (EPA) emission factors as a complement. This work is one of the activities of the LIFE project called HADA (Herramienta Automática de Diagnóstico Ambiental or in English Automatic Tool for Environmental Diagnostic).

  17. 14 CFR 420.65 - Handling of solid propellants.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ....65 Handling of solid propellants. (a) A launch site operator shall determine the maximum total quantity of solid propellants and other solid explosives by class and division, in accordance with 49 CFR... 14 Aeronautics and Space 4 2012-01-01 2012-01-01 false Handling of solid propellants....

  18. 14 CFR 420.65 - Handling of solid propellants.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ....65 Handling of solid propellants. (a) A launch site operator shall determine the maximum total quantity of solid propellants and other solid explosives by class and division, in accordance with 49 CFR... 14 Aeronautics and Space 4 2011-01-01 2011-01-01 false Handling of solid propellants....

  19. 49 CFR 176.72 - Handling of break-bulk hazardous materials.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Handling of break-bulk hazardous materials. 176.72 Section 176.72 Transportation Other Regulations Relating to Transportation PIPELINE AND HAZARDOUS... VESSEL General Handling and Stowage § 176.72 Handling of break-bulk hazardous materials. (a) A metal...

  20. 49 CFR 176.72 - Handling of break-bulk hazardous materials.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false Handling of break-bulk hazardous materials. 176.72 Section 176.72 Transportation Other Regulations Relating to Transportation PIPELINE AND HAZARDOUS... VESSEL General Handling and Stowage § 176.72 Handling of break-bulk hazardous materials. (a) A metal...

  1. 49 CFR 176.72 - Handling of break-bulk hazardous materials.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 2 2014-10-01 2014-10-01 false Handling of break-bulk hazardous materials. 176.72 Section 176.72 Transportation Other Regulations Relating to Transportation PIPELINE AND HAZARDOUS... VESSEL General Handling and Stowage § 176.72 Handling of break-bulk hazardous materials. (a) A metal...

  2. Solid State Processing of Bulk Metallic Glasses

    NASA Astrophysics Data System (ADS)

    Eckert, Jurgen

    1998-03-01

    Glasses are generally produced from the undercooled liquid state by rapid quenching methods or quasi-statically at slow cooling by the effective control of heterogeneous nucleation. For metallic systems, the latter method has recently led to the development of multicomponent metallic glasses with large glass forming ability and a wide supercooled liquid region before crystallization. Large-scale bulk samples can now be produced by conventional casting techniques. These materials exhibit advanced engineering properties such as excellent wear behavior, almost theoretical strength and good corrosion resistance, and are highly processable at temperatures above the glass transition temperature. As an alternative to quenching or casting techniques, glass formation can also be achieved by solid state processing without passing through the liquid state. Therefore, mechanical alloying as a special form of solid state reaction technique and subsequent consolidation of the resulting powders above the glass transition temperature can be used to prepare bulk metallic glasses through the powder metallurgy route. This paper surveys results of studies regarding the factors governing glass formation by solid state processing. The thermal stability of mechanically alloyed powders is compared with data for melt quenched samples, showing that basically the same glassy state can be reached approaching it from the liquid or the solid state. Special emphasis is given to the glass forming ranges achievable by the different techniques, and to preparation of nanostructured composite materials based on glassy alloys. The results are discussed with respect to the influence of processing conditions, impurity effects and heterogeneous nucleation of crystalline phases. Examples for consolidated bulk samples from mechanically alloyed powders are presented and compared with data for cast bulk specimens.

  3. Bulk solitary waves in elastic solids

    NASA Astrophysics Data System (ADS)

    Samsonov, A. M.; Dreiden, G. V.; Semenova, I. V.; Shvartz, A. G.

    2015-10-01

    A short and object oriented conspectus of bulk solitary wave theory, numerical simulations and real experiments in condensed matter is given. Upon a brief description of the soliton history and development we focus on bulk solitary waves of strain, also known as waves of density and, sometimes, as elastic and/or acoustic solitons. We consider the problem of nonlinear bulk wave generation and detection in basic structural elements, rods, plates and shells, that are exhaustively studied and widely used in physics and engineering. However, it is mostly valid for linear elasticity, whereas dynamic nonlinear theory of these elements is still far from being completed. In order to show how the nonlinear waves can be used in various applications, we studied the solitary elastic wave propagation along lengthy wave guides, and remarkably small attenuation of elastic solitons was proven in physical experiments. Both theory and generation for strain soliton in a shell, however, remained unsolved problems until recently, and we consider in more details the nonlinear bulk wave propagation in a shell. We studied an axially symmetric deformation of an infinite nonlinearly elastic cylindrical shell without torsion. The problem for bulk longitudinal waves is shown to be reducible to the one equation, if a relation between transversal displacement and the longitudinal strain is found. It is found that both the 1+1D and even the 1+2D problems for long travelling waves in nonlinear solids can be reduced to the Weierstrass equation for elliptic functions, which provide the solitary wave solutions as appropriate limits. We show that the accuracy in the boundary conditions on free lateral surfaces is of crucial importance for solution, derive the only equation for longitudinal nonlinear strain wave and show, that the equation has, amongst others, a bidirectional solitary wave solution, which lead us to successful physical experiments. We observed first the compression solitary wave in the

  4. Review of Solids Handling. Instructor's Guide. Biological Treatment Process Control.

    ERIC Educational Resources Information Center

    Carnegie, John W.

    This unit (which consists of a single lesson) summarizes and reviews most of the solids handling processes in common use in municipal treatment plants. The instructor's guide for the unit includes: (1) an overview of the lesson; (2) lesson plan; (3) lecture outline (keyed to a set of 72 slides); (4) student worksheet (with answers); and (5) two…

  5. Review of Solids Handling. Student Manual. Biological Treatment Process Control.

    ERIC Educational Resources Information Center

    Carnegie, John W.

    This student manual contains the textual material for a single-lesson unit which summarizes and reviews most of the solids handling processes in common use in municipal treatment plants. No attempt is made to detail the theory and operation of the processes. Topics discussed include: (1) sources of sludge; (2) the importance of sludge management;…

  6. A multigrid fluid pressure solver handling separating solid boundary conditions.

    PubMed

    Chentanez, Nuttapong; Müller-Fischer, Matthias

    2012-08-01

    We present a multigrid method for solving the linear complementarity problem (LCP) resulting from discretizing the Poisson equation subject to separating solid boundary conditions in an Eulerian liquid simulation’s pressure projection step. The method requires only a few small changes to a multigrid solver for linear systems. Our generalized solver is fast enough to handle 3D liquid simulations with separating boundary conditions in practical domain sizes. Previous methods could only handle relatively small 2D domains in reasonable time, because they used expensive quadratic programming (QP) solvers. We demonstrate our technique in several practical scenarios, including nonaxis-aligned containers and moving solids in which the omission of separating boundary conditions results in disturbing artifacts of liquid sticking to solids. Our measurements show, that the convergence rate of our LCP solver is close to that of a standard multigrid solver. PMID:22411885

  7. Measurement of particulate concentrations produced during bulk material handling at the Tarragona harbor

    NASA Astrophysics Data System (ADS)

    Artíñano, B.; Gómez-Moreno, F. J.; Pujadas, M.; Moreno, N.; Alastuey, A.; Querol, X.; Martín, F.; Guerra, A.; Luaces, J. A.; Basora, J.

    Bulk material handling can be a significant source of particles in harbor areas. The atmospheric impact of a number of loading/unloading activities of diverse raw materials has been assessed from continuous measurements of ambient particle concentrations recorded close to the emission sources. Two experimental campaigns have been carried out in the Tarragona port to document the impact of specific handling operations and bulk materials. Dusty bulk materials such as silica-manganese powder, tapioca, coal, clinker and lucerne were dealt with during the experiments. The highest impacts on ambient particle concentrations were recorded during handling of clinker. For this material and silica-manganese powder, high concentrations were recorded in the fine grain size (<2.5 μm). The lowest impacts on particulate matter concentrations were recorded during handling of tapioca and lucerne, mainly in the coarse grain size (2-5-10 μm). The effectiveness of several emission abatement measures, such as ground watering to diminish coal particle resuspension, was demonstrated to reduce ambient concentrations by up to two orders of magnitude. The importance of other good practices in specific handling operations, such as controlling the height of the shovel discharge, was also evidenced by these experiments. The results obtained can be further utilized as a useful experimental database for emission factor estimations.

  8. Gas handling systems using titanium-sponge and uranium bulk getters

    SciTech Connect

    Kherani, N.P.; Shmayda, W.T.

    1985-09-01

    A protium gas handling system using titanium and uranium bulk getters was designed, constructed and tested. Numerous process operations were carried out on this system to aid in the design of a tritium gas handling system four times the experimental scale. Experimental results have shown that high percentages of tritium on long-term titanium storage beds can be recovered in a relatively short period of time and be transferred to uranium bed(s) in direct (pump-less) and pump-aided transfers. An optimum storage time after which the rate of interstitial /sup 3/He evolution would be prohibitive to conduct direct tritium transfers is estimated.

  9. Radioactive solid waste handling at the Plutonium Finishing Plant

    SciTech Connect

    Manthos, E.J.

    1990-05-01

    The Plutonium Finishing Plant is located on the Hanford Site in the southeast section of Washington State. It has been in operation since 1949. The mission of the plant is to produce plutonium metal and related products for the US Department of Energy defense programs. Solid transuranic, low-level, and mixed wastes are generated at the plant, the radioactive contaminants in the waste being primarily alpha emitting. This paper discusses present waste-handling methods at the plant and recent changes that were made to improve waste characterization. 2 refs.

  10. ENVIRONMENTAL SAMPLING USING LOCATION SPECIFIC AIR MONITORING IN BULK HANDLING FACILITIES

    SciTech Connect

    Sexton, L.; Hanks, D.; Degange, J.; Brant, H.; Hall, G.; Cable-Dunlap, P.; Anderson, B.

    2011-06-07

    Since the introduction of safeguards strengthening measures approved by the International Atomic Energy Agency (IAEA) Board of Governors (1992-1997), international nuclear safeguards inspectors have been able to utilize environmental sampling (ES) (e.g. deposited particulates, air, water, vegetation, sediments, soil and biota) in their safeguarding approaches at bulk uranium/plutonium handling facilities. Enhancements of environmental sampling techniques used by the IAEA in drawing conclusions concerning the absence of undeclared nuclear materials or activities will soon be able to take advantage of a recent step change improvement in the gathering and analysis of air samples at these facilities. Location specific air monitoring feasibility tests have been performed with excellent results in determining attribute and isotopic composition of chemical elements present in an actual test-bed sample. Isotopic analysis of collected particles from an Aerosol Contaminant Extractor (ACE) collection, was performed with the standard bulk sampling protocol used throughout the IAEA network of analytical laboratories (NWAL). The results yielded bulk isotopic values expected for the operations. Advanced designs of air monitoring instruments such as the ACE may be used in gas centrifuge enrichment plants (GCEP) to detect the production of highly enriched uranium (HEU) or enrichments not declared by a State. Researchers at Savannah River National Laboratory in collaboration with Oak Ridge National Laboratory are developing the next generation of ES equipment for air grab and constant samples that could become an important addition to the international nuclear safeguards inspector's toolkit. Location specific air monitoring to be used to establish a baseline environmental signature of a particular facility employed for comparison of consistencies in declared operations will be described in this paper. Implementation of air monitoring will be contrasted against the use of smear ES

  11. Liquid-solid joining of bulk metallic glasses.

    PubMed

    Huang, Yongjiang; Xue, Peng; Guo, Shu; Wu, Yang; Cheng, Xiang; Fan, Hongbo; Ning, Zhiliang; Cao, Fuyang; Xing, Dawei; Sun, Jianfei; Liaw, Peter K

    2016-01-01

    Here, we successfully welded two bulk metallic glass (BMG) materials, Zr51Ti5Ni10Cu25Al9 and Zr50.7Cu28Ni9Al12.3 (at. %), using a liquid-solid joining process. An atomic-scale metallurgical bonding between two BMGs can be achieved. The interface has a transition layer of ~50 μm thick. The liquid-solid joining of BMGs can shed more insights on overcoming their size limitation resulting from their limited glass-forming ability and then promoting their applications in structural components. PMID:27471073

  12. Liquid-solid joining of bulk metallic glasses

    PubMed Central

    Huang, Yongjiang; Xue, Peng; Guo, Shu; Wu, Yang; Cheng, Xiang; Fan, Hongbo; Ning, Zhiliang; Cao, Fuyang; Xing, Dawei; Sun, Jianfei; Liaw, Peter K.

    2016-01-01

    Here, we successfully welded two bulk metallic glass (BMG) materials, Zr51Ti5Ni10Cu25Al9 and Zr50.7Cu28Ni9Al12.3 (at. %), using a liquid-solid joining process. An atomic-scale metallurgical bonding between two BMGs can be achieved. The interface has a transition layer of ~50 μm thick. The liquid-solid joining of BMGs can shed more insights on overcoming their size limitation resulting from their limited glass-forming ability and then promoting their applications in structural components. PMID:27471073

  13. Liquid-solid joining of bulk metallic glasses

    NASA Astrophysics Data System (ADS)

    Huang, Yongjiang; Xue, Peng; Guo, Shu; Wu, Yang; Cheng, Xiang; Fan, Hongbo; Ning, Zhiliang; Cao, Fuyang; Xing, Dawei; Sun, Jianfei; Liaw, Peter K.

    2016-07-01

    Here, we successfully welded two bulk metallic glass (BMG) materials, Zr51Ti5Ni10Cu25Al9 and Zr50.7Cu28Ni9Al12.3 (at. %), using a liquid-solid joining process. An atomic-scale metallurgical bonding between two BMGs can be achieved. The interface has a transition layer of ~50 μm thick. The liquid-solid joining of BMGs can shed more insights on overcoming their size limitation resulting from their limited glass-forming ability and then promoting their applications in structural components.

  14. 49 CFR 175.900 - Handling requirements for carbon dioxide, solid (dry ice).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Handling requirements for carbon dioxide, solid (dry ice). 175.900 Section 175.900 Transportation Other Regulations Relating to Transportation PIPELINE....900 Handling requirements for carbon dioxide, solid (dry ice). Carbon dioxide, solid (dry ice)...

  15. 49 CFR 175.900 - Handling requirements for carbon dioxide, solid (dry ice).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false Handling requirements for carbon dioxide, solid (dry ice). 175.900 Section 175.900 Transportation Other Regulations Relating to Transportation PIPELINE....900 Handling requirements for carbon dioxide, solid (dry ice). Carbon dioxide, solid (dry ice)...

  16. 49 CFR 175.900 - Handling requirements for carbon dioxide, solid (dry ice).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false Handling requirements for carbon dioxide, solid (dry ice). 175.900 Section 175.900 Transportation Other Regulations Relating to Transportation PIPELINE....900 Handling requirements for carbon dioxide, solid (dry ice). Carbon dioxide, solid (dry ice)...

  17. 49 CFR 175.900 - Handling requirements for carbon dioxide, solid (dry ice).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 2 2014-10-01 2014-10-01 false Handling requirements for carbon dioxide, solid (dry ice). 175.900 Section 175.900 Transportation Other Regulations Relating to Transportation PIPELINE....900 Handling requirements for carbon dioxide, solid (dry ice). Carbon dioxide, solid (dry ice)...

  18. 49 CFR 175.900 - Handling requirements for carbon dioxide, solid (dry ice).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false Handling requirements for carbon dioxide, solid (dry ice). 175.900 Section 175.900 Transportation Other Regulations Relating to Transportation PIPELINE....900 Handling requirements for carbon dioxide, solid (dry ice). Carbon dioxide, solid (dry ice)...

  19. 46 CFR 97.12-5 - Bulk solid cargoes that may liquefy.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Bulk solid cargoes that may liquefy. 97.12-5 Section 97... VESSELS OPERATIONS Bulk Solid Cargoes § 97.12-5 Bulk solid cargoes that may liquefy. If the information provided in § 97.12-3(a) or (b) indicates that the bulk solid cargo to be carried is prone to...

  20. 46 CFR 97.12-5 - Bulk solid cargoes that may liquefy.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Bulk solid cargoes that may liquefy. 97.12-5 Section 97... VESSELS OPERATIONS Bulk Solid Cargoes § 97.12-5 Bulk solid cargoes that may liquefy. If the information provided in § 97.12-3(a) or (b) indicates that the bulk solid cargo to be carried is prone to...

  1. 46 CFR 97.12-5 - Bulk solid cargoes that may liquefy.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Bulk solid cargoes that may liquefy. 97.12-5 Section 97... VESSELS OPERATIONS Bulk Solid Cargoes § 97.12-5 Bulk solid cargoes that may liquefy. If the information provided in § 97.12-3(a) or (b) indicates that the bulk solid cargo to be carried is prone to...

  2. 46 CFR 97.12-5 - Bulk solid cargoes that may liquefy.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Bulk solid cargoes that may liquefy. 97.12-5 Section 97... VESSELS OPERATIONS Bulk Solid Cargoes § 97.12-5 Bulk solid cargoes that may liquefy. If the information provided in § 97.12-3(a) or (b) indicates that the bulk solid cargo to be carried is prone to...

  3. Compression-Driven Mass Flow in Bulk Solid 4He

    NASA Astrophysics Data System (ADS)

    Cheng, Zhi Gang; Beamish, John

    2016-07-01

    Mass flow has been observed in solid 4He coexisting with superfluid confined in Vycor, but its physical mechanism remains an open question. Here we report observations of flow in experiments in which Vycor has been eliminated, allowing us to study the intrinsic flow in solid 4He without the complications introduced by the presence of superfluid and the associated solid-liquid interfaces. By growing crystals with 3He concentration as low as x3=5 ×10-12, we also avoided the low temperature flow suppression observed in previous experiments and found that the flow rate continued to increase down to at least 28 mK without saturation. In addition, 3He concentrations of 120 ppb, which suppressed most of the low temperature flow in previous experiments, had no effect in our samples. The larger 3He concentrations needed to block the bulk solid flow suggest that the mass flow involves a larger area, such as disordered liquid layer on solid surface and grain boundaries.

  4. Compression-Driven Mass Flow in Bulk Solid ^{4}He.

    PubMed

    Cheng, Zhi Gang; Beamish, John

    2016-07-01

    Mass flow has been observed in solid ^{4}He coexisting with superfluid confined in Vycor, but its physical mechanism remains an open question. Here we report observations of flow in experiments in which Vycor has been eliminated, allowing us to study the intrinsic flow in solid ^{4}He without the complications introduced by the presence of superfluid and the associated solid-liquid interfaces. By growing crystals with ^{3}He concentration as low as x_{3}=5×10^{-12}, we also avoided the low temperature flow suppression observed in previous experiments and found that the flow rate continued to increase down to at least 28 mK without saturation. In addition, ^{3}He concentrations of 120 ppb, which suppressed most of the low temperature flow in previous experiments, had no effect in our samples. The larger ^{3}He concentrations needed to block the bulk solid flow suggest that the mass flow involves a larger area, such as disordered liquid layer on solid surface and grain boundaries. PMID:27447513

  5. Bulk-density distributions of solids in the freeboard of a gas-solid fluidized bed

    SciTech Connect

    Shen, B.C.; Fan, L.T.; Walawender, W.P.

    1995-05-01

    The freeboard region above the bubbling zone of a gas-solid fluidized bed provides the space not only for the disengagement of particles but also for additional contact and reaction between the particles and gas. The flow pattern and behavior of particles as well as their bulk-density distribution in the freeboard have a significant impact on the efficiency of fluidization. The results of numerous previous experimental studies indicate that the bulk density of solids essentially decreases exponentially as a function of the height of the freeboard. In the present work, this distribution has been obtained by first derived the Fokker-Planck equation from the linearized equation of motion of a single particle and then transforming this Fokker-Planck equation into that for the bulk-density distribution of solids. Its simplification to the one-dimensional case readily gives rise to an exponential distribution and agrees well with the available experimental data.

  6. 14 CFR 420.65 - Handling of solid propellants.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... quantity of solid propellants and other solid explosives by class and division, in accordance with 49 CFR... only of a public highway or railroad line. (4) A launch site operator may use linear interpolation...

  7. DEVELOPMENT OF A TAMPER RESISTANT/INDICATING AEROSOL COLLECTION SYSTEM FOR ENVIRONMENTAL SAMPLING AT BULK HANDLING FACILITIES

    SciTech Connect

    Sexton, L.

    2012-06-06

    Environmental sampling has become a key component of International Atomic Energy Agency (IAEA) safeguards approaches since its approval for use in 1996. Environmental sampling supports the IAEA's mission of drawing conclusions concerning the absence of undeclared nuclear material or nuclear activities in a Nation State. Swipe sampling is the most commonly used method for the collection of environmental samples from bulk handling facilities. However, augmenting swipe samples with an air monitoring system, which could continuously draw samples from the environment of bulk handling facilities, could improve the possibility of the detection of undeclared activities. Continuous sampling offers the opportunity to collect airborne materials before they settle onto surfaces which can be decontaminated, taken into existing duct work, filtered by plant ventilation, or escape via alternate pathways (i.e. drains, doors). Researchers at the Savannah River National Laboratory and Oak Ridge National Laboratory have been working to further develop an aerosol collection technology that could be installed at IAEA safeguarded bulk handling facilities. The addition of this technology may reduce the number of IAEA inspector visits required to effectively collect samples. The principal sample collection device is a patented Aerosol Contaminant Extractor (ACE) which utilizes electrostatic precipitation principles to deposit particulates onto selected substrates. Recent work has focused on comparing traditional swipe sampling to samples collected via an ACE system, and incorporating tamper resistant and tamper indicating (TRI) technologies into the ACE system. Development of a TRI-ACE system would allow collection of samples at uranium/plutonium bulk handling facilities in a manner that ensures sample integrity and could be an important addition to the international nuclear safeguards inspector's toolkit. This work was supported by the Next Generation Safeguards Initiative (NGSI), Office

  8. 49 CFR 173.240 - Bulk packaging for certain low hazard solid materials.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; and sift-proof non... 49 Transportation 2 2013-10-01 2013-10-01 false Bulk packaging for certain low hazard solid... Than Class 1 and Class 7 § 173.240 Bulk packaging for certain low hazard solid materials. When §...

  9. 49 CFR 173.240 - Bulk packaging for certain low hazard solid materials.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; and sift-proof non... 49 Transportation 2 2014-10-01 2014-10-01 false Bulk packaging for certain low hazard solid... Than Class 1 and Class 7 § 173.240 Bulk packaging for certain low hazard solid materials. When §...

  10. 49 CFR 173.240 - Bulk packaging for certain low hazard solid materials.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; and sift-proof non... 49 Transportation 2 2012-10-01 2012-10-01 false Bulk packaging for certain low hazard solid... Than Class 1 and Class 7 § 173.240 Bulk packaging for certain low hazard solid materials. When §...

  11. Method of altering the effective bulk density of solid material and the resulting product

    DOEpatents

    Kool, Lawrence B.; Nolen, Robert L.; Solomon, David E.

    1983-01-01

    A method of adjustably tailoring the effective bulk density of a solid material in which a mixture comprising the solid material, a film-forming polymer and a volatile solvent are sprayed into a drying chamber such that the solvent evaporates and the polymer dries into hollow shells having the solid material captured within the shell walls. Shell density may be varied as a function of solid/polymer concentration, droplet size and drying temperature.

  12. Methods for the Safe Storage, Handling, and Disposal of Pyrophoric Liquids and Solids in the Laboratory

    SciTech Connect

    Alnajjar, Mikhail S.; Quigley, David; Kuntamukkula, Murty; Simmons, Fred; Freshwater, David; Bigger, Samuel

    2011-01-01

    Due to the inherent nature of pyrophoric substances to ignite spontaneously upon exposure to air, special precautions must be taken to ensure their safe handling and use. Pyrophoric gases (such as diborane, dichloroborane, phosphine, etc.) are typically the easiest class of pyrophoric substances to handle since the gas can be plumbed directly to the application and used remotely. Pyrophoric solids and liquids, however, require the user to physically manipulate them when transferring them from one container to another. Failure to follow proper safety precautions could result in serious injury or unintended consequences to laboratory personnel.12 Because of this danger, pyrophorics should be handled only by experienced personnel. Users with limited experience must be trained on how to handle pyrophoric reagents and consult with a knowledgeable staff member prior to performing the experimental task. The purpose of this article is three fold: 1) to provide guidelines and general safety precautions to avoid accidents, 2) describe proper techniques on how to successfully handle, store, and dispose of pyrophoric liquids and solids, and 3) illustrate best practices for working with this class of reactants in a laboratory environment.

  13. A multiscale coarse-grained polarizable solvent model for handling long tail bulk electrostatics.

    PubMed

    Masella, Michel; Borgis, Daniel; Cuniasse, Philippe

    2013-05-15

    A multiscale coarse-grained approach able to handle efficiently the solvation of microscopic solutes in extended chemical environment is described. That approach is able to compute readily and efficiently very long-range solute/solvent electrostatic microscopic interactions, up to the 1-μm scale, by considering a reduced amount of computational resources. All the required parameters are assigned to reproduce available data concerning the solvation of single ions. Such a strategy makes it possible to reproduce with good accuracy the solvation properties concerning simple ion pairs in solution (in particular, the asymptotic behavior of the ion pair potentials of mean force). This new method represents an extension of the polarizable pseudoparticle solvent model, which has been recently improved to account for the main features of hydrophobic effects in liquid water (Masella et al., J. Comput. Chem. 2011, 32, 2664). This multiscale approach is well suited to be used for computing the impact of charge changes in free energy computations, in terms of both accuracy and efficiency. PMID:23382002

  14. Comparison of Customer Preference for Bulk Material Handling Equipment through Fuzzy-AHP Approach

    NASA Astrophysics Data System (ADS)

    Sen, Kingshuk; Ghosh, Surojit; Sarkar, Bijan

    2016-06-01

    In the present study, customer's perception has played one of the important roles for selection of the exact equipment out of available alternatives. The present study is dealt with the method of optimization of selection criteria of a material handling equipment, based on the technical specifications considered to be available at the user end. In this work, the needs of customers have been identified and prioritized, that lead to the selection of number of criteria, which have direct effect upon the performance of the equipment. To check the consistency of selection criteria, first of all an AHP based methodology is adopted with the identified criteria and available product categories, based upon which, the judgments of the users are defined to derive the priority scales. Such judgments expressed the relative strength or intensity of the impact of the elements of the hierarchy. Subsequently, all the alternatives have ranked for each identified criteria with subsequent constitution of weighted matrices. The same has been compared with the normalized values of approximate selling prices of the equipments to determine individual cost-benefit ratio. Based on the cost-benefit ratio, the equipment is ranked. With same conditions, the study is obtained again with a Fuzzy AHP concept, where a fuzzy linguistic approach has reduced the amount of uncertainty in decision making, caused by conventional AHP due to lack of deterministic approach. The priority vectors of category and criteria are determined separately and multiplied to obtain composite score. Subsequently, the average of fuzzy weights was determined and the preferences of equipment are ranked.

  15. Crucial role of quantum entanglement in bulk properties of solids

    SciTech Connect

    Brukner, Caslav; Vedral, Vlatko; Zeilinger, Anton

    2006-01-15

    We demonstrate that two well-established experimental techniques of condensed-matter physics, neutron-diffraction scattering and measurement of magnetic susceptibility, can be used to detect and quantify macroscopic entanglement in solids. Specifically, magnetic susceptibility of copper nitrate (CN) measured in 1963 cannot be described without presence of entanglement. A detailed analysis of the spin correlations in CN as obtained from neutron-scattering experiment from 2000 provides microscopic support for this interpretation and gives the value for the amount of entanglement. We present a quantitative analysis resulting in the critical temperature of 5 K in both, completely independent, experiments below which entanglement exists.

  16. Optical Characterization of Bulk ZnSeTe Solid Solutions

    NASA Technical Reports Server (NTRS)

    Su, Ching-Hua; Feth, S.; Zhu, Shen; Lehoczky, S. L.; Wang, Ling Jun

    2000-01-01

    Optical characterization was performed on wafers sliced from crystals of ZnSe, ZnTe, and ZnSe(1-x)Te(x)(0 less than x less than 0.4) grown by physical vapor transport. Energy band gaps at room temperature were determined from optical transmission measurements on 11 wafers. A best fit curve to the band gap versus composition x data gives a bowing parameter of 1.45. This number lies between the value of 1.23 determined previously on ZnSeTe bulk crystals and the value of 1.621 reported on ZnSeTe epilayers. Low-temperature photoluminescence (PL) spectra were measured on six samples. The spectra of ZnSe and ZnTe were dominated by near band edge emissions and no deep donor-acceptor pairs were observed. The PL spectrum exhibited a broad emission for each of the ZnSe(1-x)Te(x) samples, 0.09 less than x less than 0.39. For x=0.09, this emission energy is about 0.2 eV lower than the band gap energy measured at low temperature. As x increases the energy discrepancy gradually decreases and reduces to almost zero at x=0.4. The single broad PL emission spectra and the spectra measured as a function of temperature were interpreted as being associated with the exciton bound to Te clusters because of the high Te content in these samples.

  17. Optical Characterization of Bulk ZnSeTe Solid Solutions

    NASA Technical Reports Server (NTRS)

    Su, Ching-Hua; Feth, S.; Zhu, Shen; Lehoczky, S. L.; Wang, Ling Jun

    2000-01-01

    Optical characterization was performed on wafers sliced from crystals of ZnSe, ZnTe and ZnSe (sub 1-x) Te (sub x) (0 less than x less than 0.4) grown by physical vapor transport technique. The energy band gaps at room temperature were determined from optical transmission measurements on 11 wafers. The best fit to the band gap vs. composition, x, data gives a bowing parameter of 1.336 which is between the value of 1.23 determined previously on ZnSeTe bulk crystals by reflectivity and the value of 1.621 reported on epilayers by photoconductivity. Low-temperature photoluminescence (PL) spectra were measured on 6 samples. The spectra of ZnSe and ZnTe were dominated by near band edge emissions and no deep donor-acceptor pairs were observed. The PL spectrum exhibited a broad emission for each of the ZnSe (sub 1-x) Te (sub x) samples, 0.09 less than x less than 0.39. For x = 0.09, this emission energy is about 0.2eV lower than the band gap energy measured at low temperature. As x increases the energy discrepancy gradually decreases and reduces to almost zero at x = 0.4. The single broad PL emission spectra and the spectra measured as a function of temperature were interpreted to be associated with the exciton bound to Te clusters because of the high Te content in these samples.

  18. Optically engineered quantum interference of delocalized wave functions in a bulk solid: The example of solid para-hydrogen

    NASA Astrophysics Data System (ADS)

    Katsuki, Hiroyuki; Kayanuma, Yosuke; Ohmori, Kenji

    2013-07-01

    Local excitations of indistinguishable particles in a solid are quantum-mechanically superposed to give delocalized wave functions. Their interference is often so short-lived that it eludes observation and manipulation. Here we have actively controlled interference of delocalized vibrational wave functions in solid para-hydrogen produced by a pair of ultrashort laser pulses. The ultrafast evolution of their interference changes from almost completely constructive (amplification by a factor of ˜4) to destructive when we change the timing of those two laser pulses by only 4 fs. This active control serves as an experimental tool to investigate the spatiotemporal evolution of a wave function in a bulk solid.

  19. 49 CFR 173.241 - Bulk packagings for certain low hazard liquid and solid materials.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... portable tanks; marine portable tanks conforming to 46 CFR part 64; and non-DOT Specification portable... solid materials. 173.241 Section 173.241 Transportation Other Regulations Relating to Transportation... Other Than Class 1 and Class 7 § 173.241 Bulk packagings for certain low hazard liquid and...

  20. 49 CFR 173.241 - Bulk packagings for certain low hazard liquid and solid materials.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... portable tanks; marine portable tanks conforming to 46 CFR part 64; and non-DOT Specification portable... solid materials. 173.241 Section 173.241 Transportation Other Regulations Relating to Transportation... Other Than Class 1 and Class 7 § 173.241 Bulk packagings for certain low hazard liquid and...

  1. 49 CFR 173.241 - Bulk packagings for certain low hazard liquid and solid materials.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... portable tanks; marine portable tanks conforming to 46 CFR part 64; and non-DOT Specification portable... solid materials. 173.241 Section 173.241 Transportation Other Regulations Relating to Transportation... Other Than Class 1 and Class 7 § 173.241 Bulk packagings for certain low hazard liquid and...

  2. METHODS FOR THE SAFE STORAGE, HANDLING, AND DISPOSAL OF PYROPHORIC LIQUIDS AND SOLIDS IN THE LABORATORY

    SciTech Connect

    Simmons, F.; Kuntamukkula, M.; Alnajjar, M.; Quigley, D.; Freshwater, D.; Bigger, S.

    2010-02-02

    Pyrophoric reagents represent an important class of reactants because they can participate in many different types of reactions. They are very useful in organic synthesis and in industrial applications. The Occupational Safety and Health Administration (OSHA) and the National Fire Protection Association (NFPA) define Pyrophorics as substances that will self-ignite in air at temperatures of 130 F (54.4 C) or less. However, the U.S. Department of Transportation (DOT) uses criteria different from the auto-ignition temperature criterion. The DOT defines a pyrophoric material as a liquid or solid that, even in small quantities and without an external ignition source, can ignite within five minutes after coming in contact with air when tested according to the United Nations Manual of Tests and Criteria. The Environmental Protection Agency has adopted the DOT definition. Regardless of which definition is used, oxidation of the pyrophoric reagents by oxygen or exothermic reactions with moisture in the air (resulting in the generation of a flammable gas such as hydrogen) is so rapid that ignition occurs spontaneously. Due to the inherent nature of pyrophoric substances to ignite spontaneously upon exposure to air, special precautions must be taken to ensure their safe handling and use. Pyrophoric gases (such as diborane, dichloroborane, phosphine, etc.) are typically the easiest class of pyrophoric substances to handle since the gas can be plumbed directly to the application and used remotely. Pyrophoric solids and liquids, however, require the user to physically manipulate them when transferring them from one container to another. Failure to follow proper safety precautions could result in serious injury or unintended consequences to laboratory personnel. Because of this danger, pyrophorics should be handled only by experienced personnel. Users with limited experience must be trained on how to handle pyrophoric reagents and consult with a knowledgeable staff member prior

  3. A solid target system with remote handling of irradiated targets for PET cyclotrons.

    PubMed

    Siikanen, J; Tran, T A; Olsson, T G; Strand, S-E; Sandell, A

    2014-12-01

    A solid target system was developed for a PET cyclotron. The system is compatible with many different target materials in the form of foils and electroplated/sputtered targets which makes it useful for production of a wide variety of different PET radionuclides. The target material is manually loaded into the system. Remote handling of irradiated target material is managed with a pneumatic piston and a vacuum technique which allows the targets to be dropped into a shielded transport container. To test the target performance, proton irradiations (12.8 MeV, 45 μA) of monoisotopic yttrium foils (0.64 mm, direct water cooling) were performed to produce 89Zr. The yields were 2200±200 MBq (1 h, n=13) and 6300±65 MBq (3 h, n=3). PMID:25265518

  4. Dynamics of bulk electron heating and ionization in solid density plasmas driven by ultra-short relativistic laser pulses

    NASA Astrophysics Data System (ADS)

    Huang, L. G.; Kluge, T.; Cowan, T. E.

    2016-06-01

    The dynamics of bulk heating and ionization is investigated both in simulations and theory, which determines the crucial plasma parameters such as plasma temperature and density in ultra-short relativistic laser-solid target interactions. During laser-plasma interactions, the solid density plasma absorbs a fraction of laser energy and converts it into kinetic energy of electrons. A portion of the electrons with relativistic kinetic energy goes through the solid density plasma and transfers energy into the bulk electrons, which results in bulk electron heating. The bulk electron heating is finally translated into the processes of bulk collisional ionization inside the solid target. A simple model based on the Ohmic heating mechanism indicates that the local and temporal profile of bulk return current is essential to determine the temporal evolution of bulk electron temperature. A series of particle-in-cell simulations showing the local heating model is robust in the cases of target with a preplasma and without a preplasma. Predicting the bulk electron heating is then benefit for understanding the collisional ionization dynamics inside the solid targets. The connection of the heating and ionization inside the solid target is further studied using Thomas-Fermi model.

  5. Short time proton dynamics in bulk ice and in porous anode solid oxide fuel cell materials

    SciTech Connect

    Basoli, Francesco; Senesi, Roberto; Kolesnikov, Alexander I; Licoccia, Silvia

    2014-01-01

    Oxygen reduction and incorporation into solid electrolytes and the reverse reaction of oxygen evolution play a cru-cial role in Solid Oxide Fuel Cell (SOFC) applications. However a detailed un derstanding of the kinetics of the cor-responding reactions, i.e. on reaction mechanisms, rate limiting steps, reaction paths, electrocatalytic role of materials, is still missing. These include a thorough characterization of the binding potentials experienced by protons in the lattice. We report results of Inelastic Neutron Scattering (INS) measurements of the vibrational state of the protons in Ni- YSZ highly porous composites (75% to 90% ), a ceramic-metal material showing a high electrical conductivity and ther mal stability, which is known to be most effectively used as anodes for solid ox ide fuel cells. The results are compared with INS and Deep Inelastic Neutron Scattering (DINS) experiments on the proton binding states in bulk ice.

  6. Bulk synthesis of silicon nanowires using a low-temperature vapor-liquid-solid method

    NASA Astrophysics Data System (ADS)

    Sunkara, M. K.; Sharma, S.; Miranda, R.; Lian, G.; Dickey, E. C.

    2001-09-01

    Silicon nanowires will find applications in nanoscale electronics and optoelectronics both as active and passive components. Here, we demonstrate a low-temperature vapor-liquid-solid synthesis method that uses liquid-metal solvents with low solubility for silicon and other elemental semiconductor materials. This method eliminates the usual requirement of quantum-sized droplets in order to obtain quantum-scale one-dimensional structures. Specifically, we synthesized silicon nanowires with uniform diameters distributed around 6 nm using gallium as the molten solvent, at temperatures less than 400 °C in hydrogen plasma. The potential exists for bulk synthesis of silicon nanowires at temperatures significantly lower than 400 °C. Gallium forms a eutectic with silicon near room temperature and offers a wide temperature range for bulk synthesis of nanowires. These properties are important for creating monodispersed one-dimensional structures capable of yielding sharp hetero- or homointerfaces.

  7. Solid Waste Treatment Technology

    ERIC Educational Resources Information Center

    Hershaft, Alex

    1972-01-01

    Advances in research and commercial solid waste handling are offering many more processing choices. This survey discusses techniques of storage and removal, fragmentation and sorting, bulk reduction, conversion, reclamation, mining and mineral processing, and disposal. (BL)

  8. Observation of Non-Classical Rotational Inertia in Bulk Solid 4He

    NASA Astrophysics Data System (ADS)

    Kondo, Motoshi; Takada, Shunichi; Shibayama, Yoshiyuki; Shirahama, Keiya

    2007-09-01

    In recent torsional oscillator experiments by Kim and Chan (KC), a decrease of rotational inertia has been observed in solid 4He in porous materials (Kim, E., Chan, M.H.W. in Nature 427:225, 2004; J. Low Temp. Phys. 138:859, 2005) and in a bulk annular channel (Kim, E., Chan, M.H.W. in Science 305:1941, 2004). This observation strongly suggests the existence of “non-classical rotational inertia” (NCRI), i.e. superflow, in solid 4He. In order to study such a possible “supersolid” phase, we perform torsional oscillator experiments for cylindrical solid 4He samples. We have observed decreases in rotational inertia below 200 mK for two solid samples (pressures P=4.1 and 3.0 MPa). The observed NCRI fraction at 70 mK is 0.14%, which is about 1/3 of the fraction observed in the annulus by KC. Our observation is the first experimental confirmation of the possible supersolid finding by KC.

  9. Surface and bulk crystallization of amorphous solid water films: Confirmation of “top-down” crystallization

    DOE PAGESBeta

    Yuan, Chunqing; Smith, R. Scott; Kay, Bruce D.

    2016-01-11

    Here, the crystallization kinetics of nanoscale amorphous solid water (ASW) films are investigated using temperature-programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS). TPD measurements are used to probe surface crystallization and RAIRS measurements are used to probe bulk crystallization. Isothermal TPD results show that surface crystallization is independent of the film thickness (from 100 to 1000 ML). Conversely, the RAIRS measurements show that the bulk crystallization time increases linearly with increasing film thickness. These results suggest that nucleation and crystallization begin at the ASW/vacuum interface and then the crystallization growth front propagates linearly into the bulk. This mechanism wasmore » confirmed by selective placement of an isotopic layer (5% D2O in H2O) at various positions in an ASW (H2O) film. In this case, the closer the isotopic layer was to the vacuum interface, the earlier the isotopic layer crystallized. These experiments provide direct evidence to confirm that ASW crystallization in vacuum proceeds by a “top-down” crystallization mechanism.« less

  10. Uniform-Format Solid Feedstock Supply System: A Commodity-Scale Design to Produce an Infrastructure-Compatible Bulk Solid from Lignocellulosic Biomass -- Executive Summary

    SciTech Connect

    J. Richard Hess; Christopher T. Wright; Kevin L. Kenney; Erin M. Searcy

    2009-04-01

    This report, Uniform-Format Solid Feedstock Supply System: A Commodity-Scale Design to Produce an Infrastructure-Compatible Bulk Solid from Lignocellulosic Biomass, prepared by Idaho National Laboratory (INL), acknowledges the need and provides supportive designs for an evolutionary progression from present day conventional bale-based supply systems to a uniform-format, bulk solid supply system that transitions incrementally as the industry launches and matures. These designs couple to and build from current state of technology and address science and engineering constraints that have been identified by rigorous sensitivity analyses as having the greatest impact on feedstock supply system efficiencies and costs.

  11. Mesoscale Modeling of Heterogeneous Materials Systems: From Solid Oxide Fuel Cells to Bulk Metallic Glasses

    NASA Astrophysics Data System (ADS)

    Abdeljawad, Fadi F.

    Heterogeneous materials systems hold the key to the future development of a broad range of increasingly complex technological applications. For example, multi-phase and/or multi-component materials are at the forefront research on the development of efficient energy devices, and the future generation of structural materials with optimal mechanical properties. In this dissertation, we focus on two materials systems, namely, solid oxide fuel cells (SOFCs) and bulk metallic glasses (BMGs), where we investigate, through theoretical and mesoscale computational models, the role of microstructure on the properties of these heterogeneous systems. For the solid oxide fuel cell project, a computational framework is developed to investigate the topological evolution of Ni phase in SOFC porous anodes, and the accompanying changes to a wide range of microstructural attributes that affect electrochemical performance. Additionally, with the aid of this framework, we study the reduction-oxidation instability, mechanical deformation and damage accumulation in SOFC anodes. In particular, the SOFC project is focused on the role of anode microstructure, characterized by particle size and ratio, on the microstructural stability and mechanical durability of SOFC anodes. For the bulk metallic glass project, a mesoscale model is introduced that accounts for the structural heterogeneity of monolithic BMGs and BMG composites, and captures the fundamental aspects of plastic deformation in such systems. We examine the effect of internal structure, characterized by rigid/soft short range order (SRO), on the deformation behavior of monolithic BMGs, while for BMG composites, we study the role of ductile phase microstructure, particle size, morphology and area fraction, on the mechanical properties and overall ductility of these systems.

  12. Laser-matter interaction in the bulk of a transparent solid: Confined microexplosion and void formation

    NASA Astrophysics Data System (ADS)

    Gamaly, Eugene G.; Juodkazis, Saulius; Nishimura, Koichi; Misawa, Hiroaki; Luther-Davies, Barry; Hallo, Ludovic; Nicolai, Philippe; Tikhonchuk, Vladimir T.

    2006-06-01

    We present here the experimental and theoretical studies of a single femtosecond laser pulse interaction inside a bulk of transparent media (sapphire, glass, polymer). This interaction leads to the drastic transformations in a solid resulting in a void formation inside a dielectric. The laser pulse energy is absorbed within a volume of approximately 0.15μm3 creating a pressure and temperature comparable to that in the core of a strong multi-kilo-tons explosion. The material within this volume is rapidly atomized, ionized, and converted into a tiny super-hot dense cloud of expanding plasma that generates strong shock and rarefaction waves which result in the formation of a void, whose diameter is ˜200nm (for a 100nJ pulse in sapphire). The way this structure forms can be understood from high-temperature plasma hydrodynamics. We demonstrate that unique states of matter characterized by temperatures ˜105K , heating rates up to the 1018K/s , and pressures more than 100 times the strength of any material were created using a standard table-top laser in well-controlled laboratory conditions. We discuss the properties of the laser-affected solid and possible routes of laser-affected material transformation to the final state long after the pulse end. These studies will find application for the design of new materials and three-dimensional optical memory devices, and for formation of photonic band-gap crystals.

  13. Prediction and improvement of the solid particles transfer rate for the bulk handing system design of offshore drilling vessels

    NASA Astrophysics Data System (ADS)

    Ryu, Mincheol; Jeon, Dong Soo; Kim, Yooil

    2015-11-01

    Numerous experiments with a scaled pilot facility were carried out to compare the relative bulk transfer performance of three special devices for applications to drilling systems. The pipe diameter for bulk transportation was 3 in., which corresponds to around half of the actual system dimensions. Two different pressures, 3 and 4 bar, were considered to check the relative performance under different pressure conditions at a bulk storage tank. And to make a practical estimation method of the bulk transfer rate at the early design stages of the bulk handling system, a series of experiments were conducted for real scaled bulk handing systems of two drilling vessels. The pressure drops at each pipe element as well as the bulk transfer rates were measured under different operating conditions. Using the measured results, the friction factor for each pipe element was calculated and a procedure for transfer rate estimation was developed. Compared to the measured transfer rate results for other drilling vessels, the estimated transfer rates were within a maximum 15% error bound.

  14. 49 CFR 173.242 - Bulk packagings for certain medium hazard liquids and solids, including solids with dual hazards.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Hazardous Materials Table for a specific hazardous material; and marine portable tanks conforming to 46 CFR... and solids, including solids with dual hazards. 173.242 Section 173.242 Transportation Other... medium hazard liquids and solids, including solids with dual hazards. When § 172.101 of this...

  15. 49 CFR 173.242 - Bulk packagings for certain medium hazard liquids and solids, including solids with dual hazards.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Hazardous Materials Table for a specific hazardous material; and marine portable tanks conforming to 46 CFR... and solids, including solids with dual hazards. 173.242 Section 173.242 Transportation Other... medium hazard liquids and solids, including solids with dual hazards. When § 172.101 of this...

  16. 49 CFR 173.242 - Bulk packagings for certain medium hazard liquids and solids, including solids with dual hazards.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Hazardous Materials Table for a specific hazardous material; and marine portable tanks conforming to 46 CFR... and solids, including solids with dual hazards. 173.242 Section 173.242 Transportation Other... medium hazard liquids and solids, including solids with dual hazards. When § 172.101 of this...

  17. Bulk deposition close to a Municipal Solid Waste incinerator: one source among many.

    PubMed

    Venturini, Elisa; Vassura, Ivano; Ferroni, Laura; Raffo, Simona; Passarini, Fabrizio; Beddows, David C S; Harrison, Roy M

    2013-07-01

    In order to assess the contribution of a Municipal Solid Waste incinerator to the area's total contamination, metals and soluble ions have been determined in bulk deposition collected at sites affected by different levels of plant emissions, according to the results of the Calpuff air dispersion model. Results show that in general fluxes monitored at the different sites during the same period are quite similar for each analyte. Deposition fluxes of nitrite and ammonium are significantly lower at the more distant site, while copper is significantly higher at this site, possibly because of copper fungicide used on the nearby agriculture land. The presence of sea spray and resuspended soil dust can be inferred from Pearson correlation coefficients, while enrichment factors indicate that Cu, Pb and Zn have a probable anthropogenic origin. A more complete evaluation of the sources affecting the area was obtained with PMF analysis. The sources associated with each factor were identified from the source profile and temporal trends. Six factors were identified, three sources associate with natural matrices, while three factors represent anthropogenic sources. The greatest contribution of heavy metals, the most toxic and persistent components determined, is associated with resuspended soil dust, especially when weighted according to their toxicity. The anthropogenic source contribution is similar at all sites, and therefore the incinerator's relative contribution to the total pollutant load appears to be negligible compared to other sources affecting the area. PMID:23639865

  18. Improvement of propeller blades used for handling liquids containing fibrous solids

    NASA Astrophysics Data System (ADS)

    Bernauer, Jan; Wittekindt, Widu; Stark, Mathias

    1987-03-01

    The entrapment of long fibrous solids on the leading edge of axial centrifugal pump impeller blades was studied. These materials may increase the power drawn from the pump to the extent that, for example, a flood control pumping station may have to be shut down. Experiments studied the parameters fostering the entrapment of fibrous solids. A propeller blade eliminating entrapment was designed. The effectiveness of the design is demonstrated by experiments and field application.

  19. Alignment of a model amyloid Peptide fragment in bulk and at a solid surface.

    PubMed

    Hamley, Ian W; Castelletto, Valeria; Moulton, Claire M; Rodríguez-Pérez, José; Squires, Adam M; Eralp, Tugce; Held, Georg; Hicks, Matthew R; Rodger, Alison

    2010-06-24

    The alignment of model amyloid peptide YYKLVFFC is investigated in bulk and at a solid surface using a range of spectroscopic methods employing polarized radiation. The peptide is based on a core sequence of the amyloid beta (Abeta) peptide, KLVFF. The attached tyrosine and cysteine units are exploited to yield information on alignment and possible formation of disulfide or dityrosine links. Polarized Raman spectroscopy on aligned stalks provides information on tyrosine orientation, which complements data from linear dichroism (LD) on aqueous solutions subjected to shear in a Couette cell. LD provides a detailed picture of alignment of peptide strands and aromatic residues and was also used to probe the kinetics of self-assembly. This suggests initial association of phenylalanine residues, followed by subsequent registry of strands and orientation of tyrosine residues. X-ray diffraction (XRD) data from aligned stalks is used to extract orientational order parameters from the 0.48 nm reflection in the cross-beta pattern, from which an orientational distribution function is obtained. X-ray diffraction on solutions subject to capillary flow confirmed orientation in situ at the level of the cross-beta pattern. The information on fibril and tyrosine orientation from polarized Raman spectroscopy is compared with results from NEXAFS experiments on samples prepared as films on silicon. This indicates fibrils are aligned parallel to the surface, with phenyl ring normals perpendicular to the surface. Possible disulfide bridging leading to peptide dimer formation was excluded by Raman spectroscopy, whereas dityrosine formation was probed by fluorescence experiments and was found not to occur except under alkaline conditions. Congo red binding was found not to influence the cross-beta XRD pattern. PMID:20509614

  20. Automated, Ultra-Sterile Solid Sample Handling and Analysis on a Chip

    NASA Technical Reports Server (NTRS)

    Mora, Maria F.; Stockton, Amanda M.; Willis, Peter A.

    2013-01-01

    There are no existing ultra-sterile lab-on-a-chip systems that can accept solid samples and perform complete chemical analyses without human intervention. The proposed solution is to demonstrate completely automated lab-on-a-chip manipulation of powdered solid samples, followed by on-chip liquid extraction and chemical analysis. This technology utilizes a newly invented glass micro-device for solid manipulation, which mates with existing lab-on-a-chip instrumentation. Devices are fabricated in a Class 10 cleanroom at the JPL MicroDevices Lab, and are plasma-cleaned before and after assembly. Solid samples enter the device through a drilled hole in the top. Existing micro-pumping technology is used to transfer milligrams of powdered sample into an extraction chamber where it is mixed with liquids to extract organic material. Subsequent chemical analysis is performed using portable microchip capillary electrophoresis systems (CE). These instruments have been used for ultra-highly sensitive (parts-per-trillion, pptr) analysis of organic compounds including amines, amino acids, aldehydes, ketones, carboxylic acids, and thiols. Fully autonomous amino acid analyses in liquids were demonstrated; however, to date there have been no reports of completely automated analysis of solid samples on chip. This approach utilizes an existing portable instrument that houses optics, high-voltage power supplies, and solenoids for fully autonomous microfluidic sample processing and CE analysis with laser-induced fluorescence (LIF) detection. Furthermore, the entire system can be sterilized and placed in a cleanroom environment for analyzing samples returned from extraterrestrial targets, if desired. This is an entirely new capability never demonstrated before. The ability to manipulate solid samples, coupled with lab-on-a-chip analysis technology, will enable ultraclean and ultrasensitive end-to-end analysis of samples that is orders of magnitude more sensitive than the ppb goal given

  1. Bulk materials handling equipment roundup

    SciTech Connect

    Fiscor, S.

    2007-07-15

    The article reports recent product developments in belt conveyors. Flexco Steel Lancing Co. (Flexco) has a range of light, portable maintenance tools and offers training modules on procedures for belt conveyor maintenance on its website www.flexcosafe.com. Siemens recently fitted a 19 km long conveyor belt drive system at a Texan aluminium plant with five 556-kW Simovent Masterdrive VC drives. Voith recently launched the TPKL-T turbo coupling for users who want an alignment-free drive solution. Belt cleaners newly on the market include the RemaClean SGB brush and ASGCO Manufacturing's Razor-Back with Spray bar. Continental Conveyor has introduced a new line of dead-shaft pulleys offering increased bearing protection. 6 photos.

  2. The range of options for handling plane angle and solid angle within a system of units

    NASA Astrophysics Data System (ADS)

    Quincey, Paul

    2016-04-01

    The radian and steradian are unusual units within the SI, originally belonging to their own category of ‘supplementary units’, with this status being changed to dimensionless ‘derived units’ in 1995. Recent papers have suggested that angles could be handled in two different ways within the SI, both differing from the present system. The purpose of this paper is to provide a framework for putting such suggestions into context, outlining the range of options that is available, together with the advantages and disadvantages of these options. Although less rigorously logical than some alternatives, the present SI approach is generally supported, but with some changes to the SI brochure to make the position clearer, in particular with regard to the designation of the radian and steradian as derived units.

  3. 49 CFR 173.242 - Bulk packagings for certain medium hazard liquids and solids, including solids with dual hazards.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Hazardous Materials Table for a specific hazardous material; and marine portable tanks conforming to 46 CFR..., Packaging Group II materials must conform to the following: (1) Minimum design pressure. Each tank must have... Packaging for Hazardous Materials Other Than Class 1 and Class 7 § 173.242 Bulk packagings for...

  4. Infectious Risk Assessment of Unsafe Handling Practices and Management of Clinical Solid Waste

    PubMed Central

    Hossain, Md. Sohrab; Rahman, Nik Norulaini Nik Ab; Balakrishnan, Venugopal; Puvanesuaran, Vignesh R.; Sarker, Md. Zaidul Islam; Kadir, Mohd Omar Ab

    2013-01-01

    The present study was undertaken to determine the bacterial agents present in various clinical solid wastes, general waste and clinical sharp waste. The waste was collected from different wards/units in a healthcare facility in Penang Island, Malaysia. The presence of bacterial agents in clinical and general waste was determined using the conventional bacteria identification methods. Several pathogenic bacteria including opportunistic bacterial agent such as Pseudomonas aeruginosa, Salmonella spp., Klebsiella pneumoniae, Serratia marcescens, Acinetobacter baumannii, Staphylococcus aureus, Staphylococcus epidermidis, Enterococcus faecalis, Streptococcus pyogenes were detected in clinical solid wastes. The presence of specific pathogenic bacterial strains in clinical sharp waste was determined using 16s rDNA analysis. In this study, several nosocomial pathogenic bacteria strains of Escherichia coli, Klebsiella pneumoniae, Proteus mirabilis, Lysinibacillus sphaericus, Serratia marcescens, and Staphylococcus aureus were detected in clinical sharp waste. The present study suggests that waste generated from healthcare facilities should be sterilized at the point of generation in order to eliminate nosocomial infections from the general waste or either of the clinical wastes. PMID:23435587

  5. EUDAT strategies for handling dynamic data in the solid Earth Sciences

    NASA Astrophysics Data System (ADS)

    Michelini, Alberto; Evans, Peter; Kemps-Snijder, Mark; Heikkinen, Jani; Buck, Justin; Misutka, Jozef; Drude, Sebastian; Fares, Massimo; Cacciari, Claudio; Fiameni, Giuseppe

    2014-05-01

    Some dynamic data is generated by sensors which produce data streams that may be temporarily incomplete (owing to latencies or temporary interruptions of the transmission lines between the field sensors and the data acquisition centres) and that may consequently fill up over time (automatically or after manual intervention). Dynamic data can also be generated by massive crowd sourcing where, for example, experimental collections of data can be filled up at random moments. The nature of dynamic data makes it difficult to handle for various reasons: a) establishing valid policies that guide early replication for data preservation and access optimization is not trivial, b) identifying versions of such data - thus making it possible to check their integrity - and referencing the versions is also a challenging task, and c) performance issues are extremely important since all these activities must be performed fast enough to keep up with the incoming data stream. There is no doubt that both applications areas (namely data from sensors and crowdsourcing) are growing in their relevance for science, and that appropriate infrastructure support (by initiatives such as EUDAT) is vital to handle these challenges. In addition, data must be citeable to encourage transparent, reproducible science, and to provide clear metrics for assessing the impact of research, which also drives funding choices. Data stream in real time often undergo changes/revisions while they are still growing, as new data arrives, and they are revised as missing data is recovered, or as new calibration values are applied. We call these "dynamic" data sets, DDS. A common form of DDS is time series data in which measurements are obtained on a regular schedule, with a well-defined sample rate. Examples include the hourly temperature in Barcelona, and the displacement (a 3-D vector quantity) of a seismograph from its rest position, which may record at a rate of 100 or more samples per second. These form streams

  6. Self-trapping of optical beams in a self-written channel in a solid bulk photopolymer material

    NASA Astrophysics Data System (ADS)

    Li, Haoyu; Qi, Yue; Malallah, Ra'ed; Ryle, James P.; Sheridan, John T.

    2015-05-01

    We demonstrate theoretically and experimentally that the light can be self-focused and self-trapped in a self-written optical waveguide in a bulk acrylamide/polyvinyl alcohol (AA/PVA) solid photopolymer material volume. The manufacture method, i.e., how to prepare the AA/PVA photopolymer material is detailed. In our experimental observation the refractive index changes induced are permanent. The resulting optical waveguide channel has good physical stability and can be integrated with optoelectronic devices as part of integrated optical systems. The theoretical model developed predicts the formation/evolution of the observed self-written waveguides inside the bulk material. The model involves appropriately discretizing and then numerically solving the paraxial wave equation in Fourier space and the material equation in time space.

  7. Bulk and surface acoustic waves in solid-fluid Fibonacci layered materials.

    PubMed

    Quotane, I; El Boudouti, E H; Djafari-Rouhani, B; El Hassouani, Y; Velasco, V R

    2015-08-01

    We study theoretically the propagation and localization of acoustic waves in quasi-periodic structures made of solid and fluid layers arranged according to a Fibonacci sequence. We consider two types of structures: either a given Fibonacci sequence or a periodic repetition of a given sequence called Fibonacci superlattice. Various properties of these systems such as: the scaling law and the self-similarity of the transmission spectra or the power law behavior of the measure of the energy spectrum have been highlighted for waves of sagittal polarization in normal and oblique incidence. In addition to the allowed modes which propagate along the system, we study surface modes induced by the surface of the Fibonacci superlattice. In comparison with solid-solid layered structures, the solid-fluid systems exhibit transmission zeros which can break the self-similarity behavior in the transmission spectra for a given sequence or induce additional gaps other than Bragg gaps in a periodic structure. PMID:25819878

  8. New solid-state fermentation chamber for bulk production of aerial conidia of fungal biocontrol agents on rice.

    PubMed

    Ye, S D; Ying, S H; Chen, C; Feng, M G

    2006-06-01

    A novel solid-state fermentation apparatus, namely an upright multi-tray conidiation chamber, was developed to facilitate the production of aerial conidia of fungal biocontrol agents, such as Beauveria bassiana. The chamber with 25 bottom-meshed metal trays had a capacity of > or =50 kg rice with each tray holding > or =2 kg. In repeated trials, a mean yield of 2.4 (1.8-2.7) x 10(12) conidia kg(-1) rice was harvested from the 7-day cultures of B. bassiana in a fully loaded chamber. The new apparatus has a high potential for bulk production of fungal conidia. PMID:16786244

  9. Assessment of the Municipal Solid Waste & Status of Implementation of Municipal Solid Waste (Management & Handling), Rules, 2000 in the State of Madhya Pradesh, 2008 - a case study.

    PubMed

    Lal Patel, Munna; Jain, Rajnikant; Saxena, Alok

    2011-05-01

    The municipal solid waste (MSW), generated from different activities in the township and city areas is a subject of deep concern for its proper management. The improper management of the MSW is a major cause for water, air and soil pollution. The population explosion and sustained drive for economic progress and development have resulted in a remarkable increase/ change in quantity and characteristics of MSW generation over the last 20 years. The local bodies are responsible for the management of the MSW in the State. The Municipal Solid Waste (Management & Handling), Rules, 2000 came into force from the date of its publication in the official Gazette of India and are applicable to every local body responsible for the proper management of the MSW in the State. The status report of the implementation of the Municipal Solid Waste (Management & Handling), Rules, 2000 in the State of Madhya Pradesh, is prepared as per the MOU signed by the State Pollution Control Board with the Central Pollution Control Board, New Delhi. The necessary data for the preparation of the report, collected from the respective local bodies through the regional offices of the Board during the period February to December 2008. There are 342 local bodies (municipal corporations, 14; municipal committees or municipalities, 86; Nagar Panchyats, 237; and cantonment boards, 5) responsible for the implementation of the MSW, in the State. It is estimated that around 4500 Mt day(-1) MSW is generated from all the 342 local bodies. The local bodies of the State are not well equipped for the proper management of the MSW. A total of 323 local bodies has identified land for the development of the landfill sites as per the provisions of the Rules but only 90 local bodies acquired the same. As an outcome of this assessment, the local bodies are not financially and technically capable for the proper implementation of the Rules. The collection of the waste is around 60-70%. This status report will serve as an

  10. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect

    Unemoto, Atsushi Ikeshoji, Tamio; Yasaku, Syun; Matsuo, Motoaki; Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu; Orimo, Shin-ichi

    2014-08-25

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  11. Development of a Bulk-Format System to Harvest, Handle, Store, and Deliver High-Tonnage Low-Moisture Switchgrass Feedstock

    SciTech Connect

    Womac, Alvin; Groothuis, Mitch; Westover, Tyler; Phanphanich, Manunya; Webb, Erin; Sokhansanj, Shahab; Turhollow, Anthony

    2013-09-24

    This project evaluates and compares comprehensive feedstock logistics systems (FLS), where a FLS is defined to comprehensively span from biomass material standing in a field to conveyance of a uniform, industrial-milled product into the throat of a biomass conversion facility (BCF). Elements of the bulk-format FLS evaluated in this project include: field-standing switchgrass dry chopped into bulk format on the farm, hauled (either loose or bulk compacted) to storage, stored with confining overburden in a protective facility, reclaimed and conveyed to bulk-format discharge, bulk compacted into an ejector trailer, and conveyed as bulk flow into the BCF. In this FLS evaluation, bulk storage bins served as a controlled and sensored proxy for large commercial stacks protected from moisture with a membrane cover.

  12. Solid-liquid interfaces of ionic liquid solutions—Interfacial layering and bulk correlations

    NASA Astrophysics Data System (ADS)

    Mezger, Markus; Roth, Roland; Schröder, Heiko; Reichert, Peter; Pontoni, Diego; Reichert, Harald

    2015-04-01

    The influence of the polar, aprotic solvent propylene carbonate on the interfacial structure of the ionic liquid (IL) 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate on sapphire was investigated by high-energy x-ray reflectivity. Experiments at solvent concentrations between 17 mol. % and 83 mol. % bridge the gap between diluted electrolytes described by the classical Gouy-Chapman theory and pure ionic liquids. Analysis of our experimental data revealed interfacial profiles comprised of alternating anion and cation enriched regions decaying gradually into the bulk liquid. With increasing solvent concentration, we observed a decrease in correlation length of the interfacial layering structure. At high ion concentrations, solvent molecules were found to accumulate laterally within the layers. By separating like-charged ions, they reduce their Coulomb repulsion. The results are compared with the bulk structure of IL/solvent blends probed by x-ray scattering and predictions from fundamental fluid theory.

  13. Femtosecond laser surface ablation of transparent solids: understanding the bulk filamentation damage

    NASA Astrophysics Data System (ADS)

    Kudryashov, Sergey I.; Joglekar, A.; Mourou, G.; Ionin, A. A.; Zvorykin, V. D.; Hunt, A. J.

    2007-06-01

    Direct SEM examination reveals a complex nanoscale structure of deep narrow central channels within shallow wide external craters produced by single-shot high-intensity femtosecond laser radiation on Corning 0211 glass and sapphire surfaces. These internal narrow channels are not expected from ordinary surface melt spallation and expulsion processes characteristic of the external surface nanocraters, but exhibit nearly the same appearance threshold. Surprisingly, the nanochannel radiuses rapidly saturate versus incident laser intensity indicating bulk rather than surface character of laser energy deposition, in contrast to the external craters extending versus laser intensity in a regular manner. These facts may be explained by channeling of electromagnetic radiation by near-surface ablative filamentary propagation of intense femtosecond laser pulses in the highly electronically excited dielectrics, by spherical aberrations in the surface layer, or deep drilling of the samples by short-wavelength Bremsstrahlung radiation of relatively hot surface electron-hole or electron-ion plasma. The double structure of ablated surface nano-features is consistent with similar structures observed for bulk damage features fabricated by femtosecond laser pulses at supercritical laser powers, but much lower laser intensities.

  14. Tunable Quantum Dot Solids: Impact of Interparticle Interactions on Bulk Properties

    SciTech Connect

    Sinclair, Michael B.; Fan, Hongyou; Brener, Igal; Liu, Sheng; Luk, Ting S.; Li, Binsong

    2015-09-01

    QD-solids comprising self-assembled semiconductor nanocrystals such as CdSe are currently under investigation for use in a wide array of applications including light emitting diodes, solar cells, field effect transistors, photodetectors, and biosensors. The goal of this LDRD project was develop a fundamental understanding of the relationship between nanoparticle interactions and the different regimes of charge and energy transport in semiconductor quantum dot (QD) solids. Interparticle spacing was tuned through the application of hydrostatic pressure in a diamond anvil cell, and the impact on interparticle interactions was probed using x-ray scattering and a variety of static and transient optical spectroscopies. During the course of this LDRD, we discovered a new, previously unknown, route to synthesize semiconductor quantum wires using high pressure sintering of self-assembled quantum dot crystals. We believe that this new, pressure driven synthesis approach holds great potential as a new tool for nanomaterials synthesis and engineering.

  15. Strong-Field Perspective on High-Harmonic Radiation from Bulk Solids

    NASA Astrophysics Data System (ADS)

    Higuchi, Takuya; Stockman, Mark I.; Hommelhoff, Peter

    2014-11-01

    Mechanisms of high-harmonic generation from crystals are described by treating the electric field of a laser as a quasistatic strong field. Under the quasistatic electric field, electrons in periodic potentials form dressed states, known as Wannier-Stark states. The energy differences between the dressed states determine the frequencies of the radiation. The radiation yield is determined by the magnitudes of the interband and intraband current matrix elements between the dressed states. The generation of attosecond pulses from solids is predicted. Ramifications for strong-field physics are discussed.

  16. From monomer to bulk: appearance of the structural motif of solid iodine in small clusters.

    PubMed

    Hulkko, Eero; Kiljunen, Toni; Kiviniemi, Tiina; Pettersson, Mika

    2009-01-28

    Formation of iodine clusters in a solid krypton matrix was studied using resonance Raman spectroscopy with a 1 cm(-1) resolution. The clusters were produced by annealing of the solid and recognized by appearance of additional spectral transitions. Two distinct regions, red-shifted from the fundamental vibrational wavenumber of the isolated I(2) at 211 cm(-1), were observed in the signal. The intermediate region spans the range 196-208 cm(-1), and the ultimate region consists of two peaks at 181 and 190 cm(-1) nearly identical to crystalline I(2). The experimental results were compared to DFT-D level electronic structure calculations of planar (I(2))(n) clusters (n = 1-7). The dimer, trimer, and tetramer structures, where the I(2) molecule is complexed from one end, were found to exhibit vibrational shifts corresponding to the intermediate size clusters. The larger, bulklike shift appears when the iodine molecule is coordinated from two opposite directions as in the case of a pentamer and higher clusters. Starting from the pentamer, the structural motif of crystalline iodine is clearly recognized in the clusters. PMID:19123809

  17. Breakdown in a bulk of transparent solids under irradiation of a nanosecond laser pulse

    NASA Astrophysics Data System (ADS)

    Rehman, Z. U.; Grigorov, Y. V.; Tran, K. A.; Janulewicz, K. A.

    2014-10-01

    A single pulse of a nanosecond laser was tightly focused in the bulk of transparent materials (soda lime glass, borosilicate glass, fused silica , sapphire and Gorilla Glass) to a beam spot diameter of ~ 2.1μm. A value of the total energy absorbed in the materials was measured with corrections for the transmitted, scattered and reflected components of the incident energy. It was found that 3-11% of the incident radiation was scattered but the total absorption still achieved a very high level of up to 88%. Absorptance dependence on the incident fluence was reasonably approximated by the sigmoidal Hill function. Here we suggest using this analytical description to identify empirical intrinsic laser-induced breakdown threshold (LIBT). Optical damage threshold (ODT) was identified by optical inspection. The results for some materials suggest significantly lower breakdown threshold than that reported earlier for more loosely focused beams. A study of the damage area morphology with a scanning electron microscope (SEM) and a high resolution transmission microscope (HRTEM) revealed existence of the shock waves-affected area with a localized nano-crystallization. Spectroscopic study of the light emission accompanying breakdown showed typical quasi-continuum emission with temperature as high as 8917K (0.8 eV).

  18. Simple Rules for Solid-state Design: From Bulk to Interface

    NASA Astrophysics Data System (ADS)

    Butler, Keith; Walsh, Aron; Jackson, Adam; Davies, Dan; Oba, Fumiyasu; Kumagai, Yu; Walsh Materials Design Team; JSPS Collaboration

    High-throughput screening enterprises such as Materials Project and the OQMD are well suited to the application of density functional theory for assessing the merits of known bulk materials. The blind exploration of the new combinations and permutations of the periodic table is a daunting task, to paraphrase Samuel Beckett we feel lost before the confusion of innumerable prospects. Centuries of research have provided us with myriad rules for assessing the feasibility of a given stoichiometry and the likelihood of particular crystal arrangements. We explore the ways in which chemical knowledge and state-of-the-art computational physics can be combined to accelerate materials design. We present the SMACT (Semiconducting Materials by Analogy and Chemical Theory) package, which combines these rules with searching of chemical space to predict plausible and heretofore unknown compounds. I will then provide some illustrative examples of materials' design focusing on several important issues: (i) designing new photovoltaic materials, (ii) the role of surfaces and polymorphism in controlling electronic properties, and (iii) the design of porous materials.

  19. Thermoelectric properties of bulk MoSi2 synthesized by solid state microwave heating

    NASA Astrophysics Data System (ADS)

    Lan, Yu; Xie, Mianyu; Ouyang, Ting; Yue, Song

    2016-07-01

    In this research, single phase α-MoSi2 was prepared by solid state hybrid microwave heating within 90 min at relatively low temperature 1273 K. Such precursor powders were then ball milled and sintered by microwave heating at different temperatures. The thermoelectric (TE) properties of MoSi2 bulks were investigated in the temperature range of 300-673 K. When the sintering temperature increases from 973 K to 1273 K, the electrical resistivity decreases significantly and the Seebeck coefficients increase obviously, leading to the maximum TE powder factor of 6.2 × 10‑6Wm‑1K‑2 at 673 K. These results demonstrate the feasibility of high efficient and economical synthesis of MoSi2 by microwave heating technique, with the final products having comparable TE performance in comparison to those from typical methods with long duration and energy-extensive consumption.

  20. Separation of solids by varying the bulk density of a fluid separating medium

    DOEpatents

    Peterson, Palmer L.; Duffy, James B.; Tokarz, Richard D.

    1978-01-01

    A method and apparatus for separating objects having a density greater than a selected density value from objects having a density less than said selected density value. The method typically comprises: (a) providing a separation vessel having an upper and lower portion, said vessel containing a liquid having a density exceeding said selected density value; (b) reducing the apparent density of the liquid to said selected density value by introducing solid, bubble-like bodies having a density less than that of the liquid into the lower portion of the vessel and permitting them to rise therethrough; (c) introducing the objects to be separated into the separation vessel and permitting the objects having a density greater than the apparent density of the liquid to sink to the lower portion of the vessel, while the objects having a density less than said selected density value float in the upper portion of the vessel; and (d) separately removing the higher density objects in the lower portion and the lower density objects in the upper portion from the separation vessel. The apparatus typically comprises: (a) a vessel containing a liquid having a density such that at least part of said objects having a density exceeding said selected density value will float therein; (b) means to place said objects into said vessel; (c) means to reduce the effective density of at least a portion of said liquid to said selected density value, whereby said objects having a density exceeding said selected density value sink into said liquid and said objects having a density less than said selected density value remain afloat, said means to adjust the effective density comprising solid, bubble-like bodies having a density less than said selected density value and means for introducing said bodies into said liquid; and (d) means for separately removing said objects having a density exceeding said selected density value and said objects having a density less than said selected density value

  1. Full-solid-angle photoelectron diffraction from bulk and surface atoms of clean W(110)

    SciTech Connect

    Ynzunza, R. X.; Tober, E. D.; Palomares, F. J.; Wang, Z.; Daimon, H.; Chen, Y.; Hussain, Z.; Van Hove, M. A.; Fadley, C. S.

    1997-04-01

    The authors have studied the atomic structure of the clean W(110) surface by means of site-resolved scanned-angle W4f{sub 7/2} photoelectron diffraction (PD) data obtained over nearly the full 2{pi} solid angle above the surface. Prior to the availability of high-brightness sources such as the Advanced Light Source, such large high-resolution data sets were prohibitively time consuming to obtain. The well characterized W(110) system was used as a reference case to check the accuracy of structure determinations from such scanned-angle data via R-factor comparisons of experiment with theoretical multiple scattering calculations. The photoelectron kinetic energy of {approximately}40 eV used was also lower than in many prior PD studies, providing further challenges to theory. The influence of various non-structural theoretical input parameters (e.g., scattering phase shifts, electron inelastic attenuation length, and inner potential) was thus also assessed. A final optimized structure is presented, together with comments on the future applications of this method.

  2. Local structure controls the nonaffine shear and bulk moduli of disordered solids.

    PubMed

    Schlegel, M; Brujic, J; Terentjev, E M; Zaccone, A

    2016-01-01

    Paradigmatic model systems, which are used to study the mechanical response of matter, are random networks of point-atoms, random sphere packings, or simple crystal lattices; all of these models assume central-force interactions between particles/atoms. Each of these models differs in the spatial arrangement and the correlations among particles. In turn, this is reflected in the widely different behaviours of the shear (G) and compression (K) elastic moduli. The relation between the macroscopic elasticity as encoded in G, K and their ratio, and the microscopic lattice structure/order, is not understood. We provide a quantitative analytical connection between the local orientational order and the elasticity in model amorphous solids with different internal microstructure, focusing on the two opposite limits of packings (strong excluded-volume) and networks (no excluded-volume). The theory predicts that, in packings, the local orientational order due to excluded-volume causes less nonaffinity (less softness or larger stiffness) under compression than under shear. This leads to lower values of G/K, a well-documented phenomenon which was lacking a microscopic explanation. The theory also provides an excellent one-parameter description of the elasticity of compressed emulsions in comparison with experimental data over a broad range of packing fractions. PMID:26732406

  3. Local structure controls the nonaffine shear and bulk moduli of disordered solids

    NASA Astrophysics Data System (ADS)

    Schlegel, M.; Brujic, J.; Terentjev, E. M.; Zaccone, A.

    2016-01-01

    Paradigmatic model systems, which are used to study the mechanical response of matter, are random networks of point-atoms, random sphere packings, or simple crystal lattices; all of these models assume central-force interactions between particles/atoms. Each of these models differs in the spatial arrangement and the correlations among particles. In turn, this is reflected in the widely different behaviours of the shear (G) and compression (K) elastic moduli. The relation between the macroscopic elasticity as encoded in G, K and their ratio, and the microscopic lattice structure/order, is not understood. We provide a quantitative analytical connection between the local orientational order and the elasticity in model amorphous solids with different internal microstructure, focusing on the two opposite limits of packings (strong excluded-volume) and networks (no excluded-volume). The theory predicts that, in packings, the local orientational order due to excluded-volume causes less nonaffinity (less softness or larger stiffness) under compression than under shear. This leads to lower values of G/K, a well-documented phenomenon which was lacking a microscopic explanation. The theory also provides an excellent one-parameter description of the elasticity of compressed emulsions in comparison with experimental data over a broad range of packing fractions.

  4. Solid-state NMR investigations of bulk and nanocrystalline indium phosphide

    NASA Astrophysics Data System (ADS)

    de Graw, David Thomas

    Second-rank indirect couplings in bulk InP. The heteronuclear J-coupling tensor between nearest neighbor 31P and 113In spins in undoped InP is investigated by means of 113 In → 31P polarization transfer under rapid magic angle spinning (MAS). The scalar contribution can be measured directly and is found to have the value |Jiso(31 P-113,115In)| = (225 +/- 10) Hz. The principal value of the traceless anisotropic J-coupling tensor (pseudodipolar coupling) is determined to be Janiso(31P- 113,115In) = 2/3(J∥|(31P- 113,115In)-J⊥(31P- 113,115In)) = (813 +/- 50) Hz or (1733 +/- 50) Hz, assuming axial symmetry with the principal axis parallel to the In-P bond. Our values deviate from those reported previously (Phys. Rev. B 5, 3395, 1972), (based on a moment analysis of the 31P resonance |J iso(31P-113,115In)| = 350 Hz and Janiso(31P-113,115 In) = 1273 Hz), but confirm the that the nearest neighbor 31P-113,115In magnetic dipolar and pseudodipolar interactions are of the same order of magnitude and partially cancel each other out. Surface structure and size effects in nanocrystalline InP. The assignment of 31P NMR spectra on trioctylphosphine oxide (TOPO) passivated InP quantum dots is made using 2D correlation and multinuclear (1H → 13C → 31P) polarization transfer techniques. The spectra show distinct surface-capping sites as well as two crystallite In31P surface components, implying a manifold of crystal-ligand bonding configurations and electronic environments. In a previous NMR study (Phys. Rev. Lett. 60, 2673, 1988) on Cd 77Se nanocrystals it was shown that the first moment of the resonance line showed an upfield shift with decreasing particle size. However, the resonance line also displayed a significant amount of inhomogeneous broadening. We have shown that with decreasing size, the nanocrystal core resonance displays an increasing upfield chemical shift related to the overall size dependence of the InP electronic structure.

  5. Why is the bulk modulus of jammed solids and granular packings much larger than the shear modulus?

    NASA Astrophysics Data System (ADS)

    Zaccone, Alessio; Weaire, Denis

    2013-03-01

    In granular packings and metallic glasses, the rigidity to compression is much more pronounced than with respect to shear, resulting in the bulk modulus being much larger than the shear modulus. This state of affairs becomes dramatic in marginal jammed solids which are solid-like to compression but not to shear (Ellenbroek, Zeravcic, van Saarloos, van Hecke, EPL 87, 34004 (2009)). For metallic glasses, it was argued by Weaire et al. some time ago (Acta Metall. 19, 779 (1971)) that this effect might be due to the nonaffinity of the particle displacements. These arise because the force acting on a particle upon strain as a result of the strain-induced motion of its neighbors is not balanced in the absence of local order. Hence the particles undergo nonaffine displacements to relax these forces to the expense of the elastic storage energy, leading to lower values of the elastic moduli. Using the nonaffine theory of Zaccone and Scossa-Romano (PRB, 83, 184205 (2011)) we found a conclusive solution to this long standing problem. We show that in packings and related materials the excluded volume between neighbors induces geometric correlations which significantly reduce the nonaffinity under compression but leave the nonaffinity in shear substantially unaltered.

  6. Integrated Solid/Nanoporous Copper/Oxide Hybrid Bulk Electrodes for High-performance Lithium-Ion Batteries

    PubMed Central

    Hou, Chao; Lang, Xing-You; Han, Gao-Feng; Li, Ying-Qi; Zhao, Lei; Wen, Zi; Zhu, Yong-Fu; Zhao, Ming; Li, Jian-Chen; Lian, Jian-She; Jiang, Qing

    2013-01-01

    Nanoarchitectured electroactive materials can boost rates of Li insertion/extraction, showing genuine potential to increase power output of Li-ion batteries. However, electrodes assembled with low-dimensional nanostructured transition metal oxides by conventional approach suffer from dramatic reductions in energy capacities owing to sluggish ion and electron transport kinetics. Here we report that flexible bulk electrodes, made of three-dimensional bicontinuous nanoporous Cu/MnO2 hybrid and seamlessly integrated with Cu solid current collector, substantially optimizes Li storage behavior of the constituent MnO2. As a result of the unique integration of solid/nanoporous hybrid architecture that simultaneously enhances the electron transport of MnO2, facilitates fast ion diffusion and accommodates large volume changes on Li insertion/extraction of MnO2, the supported MnO2 exhibits a stable capacity of as high as ~1100 mA h g−1 for 1000 cycles, and ultrahigh charge/discharge rates. It makes the environmentally friendly and low-cost electrode as a promising anode for high-performance Li-ion battery applications. PMID:24096928

  7. Bulk Fuel Man.

    ERIC Educational Resources Information Center

    Marine Corps Inst., Washington, DC.

    This student guide, one of a series of correspondence training courses designed to improve the job performance of members of the Marine Corps, deals with the skills needed by bulk fuel workers. Addressed in the four individual units of the course are the following topics: bulk fuel equipment, bulk fuel systems, procedures for handling fuels, and…

  8. Determination of the main solid-state form of albendazole in bulk drug, employing Raman spectroscopy coupled to multivariate analysis.

    PubMed

    Calvo, Natalia L; Arias, Juan M; Altabef, Aída Ben; Maggio, Rubén M; Kaufman, Teodoro S

    2016-09-10

    Albendazole (ALB) is a broad-spectrum anthelmintic, which exhibits two solid-state forms (Forms I and II). The Form I is the metastable crystal at room temperature, while Form II is the stable one. Because the drug has poor aqueous solubility and Form II is less soluble than Form I, it is desirable to have a method to assess the solid-state form of the drug employed for manufacturing purposes. Therefore, a Partial Least Squares (PLS) model was developed for the determination of Form I of ALB in its mixtures with Form II. For model development, both solid-state forms of ALB were prepared and characterized by microscopic (optical and with normal and polarized light), thermal (DSC) and spectroscopic (ATR-FTIR, Raman) techniques. Mixtures of solids in different ratios were prepared by weighing and mechanical mixing of the components. Their Raman spectra were acquired, and subjected to peak smoothing, normalization, standard normal variate correction and de-trending, before performing the PLS calculations. The optimal spectral region (1396-1280cm(-1)) and number of latent variables (LV=3) were obtained employing a moving window of variable size strategy. The method was internally validated by means of the leave one out procedure, providing satisfactory statistics (r(2)=0.9729 and RMSD=5.6%) and figures of merit (LOD=9.4% and MDDC=1.4). Furthermore, the method's performance was also evaluated by analysis of two validation sets. Validation set I was used for assessment of linearity and range and Validation set II, to demonstrate accuracy and precision (Recovery=101.4% and RSD=2.8%). Additionally, a third set of spiked commercial samples was evaluated, exhibiting excellent recoveries (94.2±6.4%). The results suggest that the combination of Raman spectroscopy with multivariate analysis could be applied to the assessment of the main crystal form and its quantitation in samples of ALB bulk drug, in the routine quality control laboratory. PMID:27429368

  9. Metastability of Au-Ge liquid nanocatalysts: Ge vapor-liquid-solid nanowire growth far below the bulk eutectic temperature.

    PubMed

    Adhikari, Hemant; Marshall, Ann F; Goldthorpe, Irene A; Chidsey, Christopher E D; McIntyre, Paul C

    2007-12-01

    The vapor-liquid-solid mechanism of nanowire (NW) growth requires the presence of a liquid at one end of the wire; however, Au-catalyzed Ge nanowire growth by chemical vapor deposition can occur at approximately 100 degrees C below the bulk Au-Ge eutectic. In this paper, we investigate deep sub-eutectic stability of liquid Au-Ge catalysts on Ge NWs quantitatively, both theoretically and experimentally. We construct a binary Au-Ge phase diagram that is valid at the nanoscale and show that equilibrium arguments, based on capillarity, are inconsistent with stabilization of Au-Ge liquid at deep sub-eutectic temperatures, similar to those used in Ge NW growth. Hot-stage electron microscopy and X-ray diffraction are used to test the predictions of nanoscale phase equilibria. In addition to Ge supersaturation of the Au-Ge liquid droplet, which has recently been invoked as an explanation for deep sub-eutectic Ge NW growth, we find evidence of a substantial kinetic barrier to Au solidification during cooling below the nanoscale Au-Ge eutectic temperature. PMID:19206662

  10. Temperature and volumetric water content petrophysical relationships in municipal solid waste for the interpretation of bulk electrical resistivity data

    NASA Astrophysics Data System (ADS)

    Pilawski, Tamara; Dumont, Gaël; Nguyen, Frédéric

    2015-04-01

    Landfills pose major environmental issues including long-term methane emissions, and local pollution of soil and aquifers but can also be seen as potential energy resources and mining opportunities. Water content in landfills determine whether solid fractions can be separated and recycled, and controls the existence and efficiency of natural or enhanced biodegradation. Geophysical techniques, such as electrical and electromagnetic methods have proven successful in the detection and qualitative investigation of sanitary landfills. However, their interpretation in terms of quantitative water content estimates makes it more challenging due to the influence of parameters such as temperature, compaction, waste composition or pore fluid. To improve the confidence given to bulk electrical resistivity data and to their interpretation, we established temperature and volumetric water content petrophysical relationships that we tested on field and laboratory electrical resistivity measurements. We carried out two laboratory experiments on leachates and waste samples from a landfill located in Mont-Saint-Guibert, Belgium. We determined a first relationship between temperature and electrical resistivity with pure and diluted leachates by progressively increasing the temperature from 5°C to 65°C, and then cooling down to 5°C. The second relationship was obtained by measuring electrical resistivity on waste samples of different volumetric water contents. First, we used the correlations obtained from the experiments to compare electrical resistivity measurements performed in a landfill borehole and on reworked waste samples excavated at different depths. Electrical resistivities were measured every 20cm with an electromagnetic logging device (EM39) while a temperature profile was acquired with optic fibres. Waste samples were excavated every 2m in the same borehole. We filled experimental columns with these samples and measured electrical resistivities at laboratory temperature

  11. Environmental and health impacts of household solid waste handling and disposal practices in third world cities: the case of the Accra Metropolitan Area, Ghana.

    PubMed

    Boadi, Kwasi Owusu; Kuitunen, Markku

    2005-11-01

    Inadequate provision of solid waste management facilities in Third World cities results in indiscriminate disposal and unsanitary environments, which threatens the health of urban residents. The study reported here examined household-level waste management and disposal practices in the Accra Metropolitan Area, Ghana. The residents of Accra currently generate large amounts of solid waste, beyond the management capabilities of the existing waste management system. Because the solid waste infrastructure is inadequate, over 80 percent of the population do not have home collection services. Only 13.5 percent of respondents are served with door-to-door collection of solid waste, while the rest dispose of their waste at communal collection points, in open spaces, and in waterways. The majority of households store their waste in open containers and plastic bags in the home. Waste storage in the home is associated with the presence of houseflies in the kitchen (r = .17, p < .0001). The presence of houseflies in the kitchen during cooking is correlated with the incidence of childhood diarrhea (r = .36, p < .0001). Inadequate solid waste facilities result in indiscriminate burning and burying of solid waste. There is an association between waste burning and the incidence of respiratory health symptoms among adults (r = .25, p < .0001) and children (r = .22, p < .05). Poor handling and disposal of waste are major causes of environmental pollution, which creates breeding grounds for pathogenic organisms, and the spread of infectious diseases. Improving access to solid waste collection facilities and services will help achieve sound environmental health in Accra. PMID:16334095

  12. Bisphenol A in Solid Waste Materials, Leachate Water, and Air Particles from Norwegian Waste-Handling Facilities: Presence and Partitioning Behavior.

    PubMed

    Morin, Nicolas; Arp, Hans Peter H; Hale, Sarah E

    2015-07-01

    The plastic additive bisphenol A (BPA) is commonly found in landfill leachate at levels exceeding acute toxicity benchmarks. To gain insight into the mechanisms controlling BPA emissions from waste and waste-handling facilities, a comprehensive field and laboratory campaign was conducted to quantify BPA in solid waste materials (glass, combustibles, vehicle fluff, waste electric and electronic equipment (WEEE), plastics, fly ash, bottom ash, and digestate), leachate water, and atmospheric dust from Norwegian sorting, incineration, and landfill facilities. Solid waste concentrations varied from below 0.002 mg/kg (fly ash) to 188 ± 125 mg/kg (plastics). A novel passive sampling method was developed to, for the first time, establish a set of waste-water partition coefficients, KD,waste, for BPA, and to quantify differences between total and freely dissolved concentrations in waste-facility leachate. Log-normalized KD,waste (L/kg) values were similar for all solid waste materials (from 2.4 to 3.1), excluding glass and metals, indicating BPA is readily leachable. Leachate concentrations were similar for landfills and WEEE/vehicle sorting facilities (from 0.7 to 200 μg/L) and dominated by the freely dissolved fraction, not bound to (plastic) colloids (agreeing with measured KD,waste values). Dust concentrations ranged from 2.3 to 50.7 mg/kgdust. Incineration appears to be an effective way to reduce BPA concentrations in solid waste, dust, and leachate. PMID:26055751

  13. Correlation between hereditary structures and properties of an Fe50Cr15Mo14C15B6 bulk-amorphous alloy in the solid and liquid states

    NASA Astrophysics Data System (ADS)

    Filippov, K. S.

    2010-05-01

    An attempt is made to find the effect of a hereditary structure on the physicochemical and structural properties of a solid and liquid Fe50Cr15Mo14C15B6 bulk-amorphous alloy in order to evaluate the possibility of using a precursor, i.e., a solid metal that has a genetic relation to the liquid phase, as an the initial metal of a heat involved in the formation of an amorphous structure. The structural state of the melt is estimated from the temperature dependence of the structural parameters, density, and surface tension with allowance for the validation criterion of the approximation of experimental points R 2.

  14. Superconducting and mechanical properties of the bulk Bi(pb)SCCO system prepared via solid state and ammonium nitrate precipitation methods

    NASA Astrophysics Data System (ADS)

    Safran, S.; Kılıçarslan, E.; Ozturk, H.; Alp, M.; Akdogan, M.; Asikuzun, E.; Ozturk, O.; Kılıç, A.

    2015-09-01

    We have investigated the effect of preparation method on superconducting and mechanical properties of Bi(Pb)-2223 bulk samples using Bi1.85Pb0.35Sr2Ca2Cu3O10±y stoichiometry. Solid-state reaction and ammonium nitrate precipitation methods have been used for fabrication of the bulk samples. In addition, the effect of annealing time on BSCCO samples have been studied. Structural, electrical, magnetic and microhardness analyses of samples are performed by the X-ray powder diffraction (XRD), the Scanning Electron Microscopy (SEM), DC resistivity, AC susceptibility and Vickers microhardness test. The critical transition temperature, phase purity, surface morphology and crystallinity of the prepared bulk samples are compared with each other. Elasticity (E), brittleness (Bi), fracture toughness (KIC) and yield strength (Y) values are also determined according to annealing time, applied load and production parameters of materials.

  15. Note: All solid-state high repetitive sub-nanosecond risetime pulse generator based on bulk gallium arsenide avalanche semiconductor switches

    NASA Astrophysics Data System (ADS)

    Hu, Long; Su, Jiancang; Ding, Zhenjie; Hao, Qingsong; Fan, Yajun; Liu, Chunliang

    2016-08-01

    An all solid-state high repetitive sub-nanosecond risetime pulse generator featuring low-energy-triggered bulk gallium arsenide (GaAs) avalanche semiconductor switches and a step-type transmission line is presented. The step-type transmission line with two stages is charged to a potential of 5.0 kV also biasing at the switches. The bulk GaAs avalanche semiconductor switch closes within sub-nanosecond range when illuminated with approximately 87 nJ of laser energy at 905 nm in a single pulse. An asymmetric dipolar pulse with peak-to-peak amplitude of 9.6 kV and risetime of 0.65 ns is produced on a resistive load of 50 Ω. A technique that allows for repetition-rate multiplication of pulse trains experimentally demonstrated that the parallel-connected bulk GaAs avalanche semiconductor switches are triggered in sequence. The highest repetition rate is decided by recovery time of the bulk GaAs avalanche semiconductor switch, and the operating result of 100 kHz of the generator is discussed.

  16. Note: All solid-state high repetitive sub-nanosecond risetime pulse generator based on bulk gallium arsenide avalanche semiconductor switches.

    PubMed

    Hu, Long; Su, Jiancang; Ding, Zhenjie; Hao, Qingsong; Fan, Yajun; Liu, Chunliang

    2016-08-01

    An all solid-state high repetitive sub-nanosecond risetime pulse generator featuring low-energy-triggered bulk gallium arsenide (GaAs) avalanche semiconductor switches and a step-type transmission line is presented. The step-type transmission line with two stages is charged to a potential of 5.0 kV also biasing at the switches. The bulk GaAs avalanche semiconductor switch closes within sub-nanosecond range when illuminated with approximately 87 nJ of laser energy at 905 nm in a single pulse. An asymmetric dipolar pulse with peak-to-peak amplitude of 9.6 kV and risetime of 0.65 ns is produced on a resistive load of 50 Ω. A technique that allows for repetition-rate multiplication of pulse trains experimentally demonstrated that the parallel-connected bulk GaAs avalanche semiconductor switches are triggered in sequence. The highest repetition rate is decided by recovery time of the bulk GaAs avalanche semiconductor switch, and the operating result of 100 kHz of the generator is discussed. PMID:27587178

  17. Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy

    SciTech Connect

    Meemken, Fabian; Müller, Philipp; Hungerbühler, Konrad; Baiker, Alfons

    2014-08-15

    Design and performance of a reactor set-up for attenuated total reflection infrared (ATR-IR) spectroscopy suitable for simultaneous reaction monitoring of bulk liquid and catalytic solid-liquid-gas interfaces under working conditions are presented. As advancement of in situ spectroscopy an operando methodology for gas-liquid-solid reaction monitoring was developed that simultaneously combines catalytic activity and molecular level detection at the catalytically active site of the same sample. Semi-batch reactor conditions are achieved with the analytical set-up by implementing the ATR-IR flow-through cell in a recycle reactor system and integrating a specifically designed gas feeding system coupled with a bubble trap. By the use of only one spectrometer the design of the new ATR-IR reactor cell allows for simultaneous detection of the bulk liquid and the catalytic interface during the working reaction. Holding two internal reflection elements (IRE) the sample compartments of the horizontally movable cell are consecutively flushed with reaction solution and pneumatically actuated, rapid switching of the cell (<1 s) enables to quasi simultaneously follow the heterogeneously catalysed reaction at the catalytic interface on a catalyst-coated IRE and in the bulk liquid on a blank IRE. For a complex heterogeneous reaction, the asymmetric hydrogenation of 2,2,2-trifluoroacetophenone on chirally modified Pt catalyst the elucidation of catalytic activity/enantioselectivity coupled with simultaneous monitoring of the catalytic solid-liquid-gas interface is shown. Both catalytic activity and enantioselectivity are strongly dependent on the experimental conditions. The opportunity to gain improved understanding by coupling measurements of catalytic performance and spectroscopic detection is presented. In addition, the applicability of modulation excitation spectroscopy and phase-sensitive detection are demonstrated.

  18. Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Meemken, Fabian; Müller, Philipp; Hungerbühler, Konrad; Baiker, Alfons

    2014-08-01

    Design and performance of a reactor set-up for attenuated total reflection infrared (ATR-IR) spectroscopy suitable for simultaneous reaction monitoring of bulk liquid and catalytic solid-liquid-gas interfaces under working conditions are presented. As advancement of in situ spectroscopy an operando methodology for gas-liquid-solid reaction monitoring was developed that simultaneously combines catalytic activity and molecular level detection at the catalytically active site of the same sample. Semi-batch reactor conditions are achieved with the analytical set-up by implementing the ATR-IR flow-through cell in a recycle reactor system and integrating a specifically designed gas feeding system coupled with a bubble trap. By the use of only one spectrometer the design of the new ATR-IR reactor cell allows for simultaneous detection of the bulk liquid and the catalytic interface during the working reaction. Holding two internal reflection elements (IRE) the sample compartments of the horizontally movable cell are consecutively flushed with reaction solution and pneumatically actuated, rapid switching of the cell (<1 s) enables to quasi simultaneously follow the heterogeneously catalysed reaction at the catalytic interface on a catalyst-coated IRE and in the bulk liquid on a blank IRE. For a complex heterogeneous reaction, the asymmetric hydrogenation of 2,2,2-trifluoroacetophenone on chirally modified Pt catalyst the elucidation of catalytic activity/enantioselectivity coupled with simultaneous monitoring of the catalytic solid-liquid-gas interface is shown. Both catalytic activity and enantioselectivity are strongly dependent on the experimental conditions. The opportunity to gain improved understanding by coupling measurements of catalytic performance and spectroscopic detection is presented. In addition, the applicability of modulation excitation spectroscopy and phase-sensitive detection are demonstrated.

  19. Handling the influence of chemical shift in amplitude-modulated heteronuclear dipolar recoupling solid-state NMR.

    PubMed

    Basse, Kristoffer; Shankar, Ravi; Bjerring, Morten; Vosegaard, Thomas; Nielsen, Niels Chr; Nielsen, Anders B

    2016-09-01

    We present a theoretical analysis of the influence of chemical shifts on amplitude-modulated heteronuclear dipolar recoupling experiments in solid-state NMR spectroscopy. The method is demonstrated using the Rotor Echo Short Pulse IRrAdiaTION mediated Cross-Polarization ((RESPIRATION)CP) experiment as an example. By going into the pulse sequence rf interaction frame and employing a quintuple-mode operator-based Floquet approach, we describe how chemical shift offset and anisotropic chemical shift affect the efficiency of heteronuclear polarization transfer. In this description, it becomes transparent that the main attribute leading to non-ideal performance is a fictitious field along the rf field axis, which is generated from second-order cross terms arising mainly between chemical shift tensors and themselves. This insight is useful for the development of improved recoupling experiments. We discuss the validity of this approach and present quaternion calculations to determine the effective resonance conditions in a combined rf field and chemical shift offset interaction frame transformation. Based on this, we derive a broad-banded version of the (RESPIRATION)CP experiment. The new sequence is experimentally verified using SNNFGAILSS amyloid fibrils where simultaneous (15)N → (13)CO and (15)N → (13)Cα coherence transfer is demonstrated on high-field NMR instrumentation, requiring great offset stability. PMID:27608995

  20. Enhanced plane wave expansion analysis for the band structure of bulk modes in two-dimensional high-contrast solid-solid phononic crystals

    NASA Astrophysics Data System (ADS)

    Baboly, Mohammadhosein Ghasemi; Soliman, Yasser; Su, Mehmet F.; Reinke, Charles M.; Leseman, Zayd C.; El-Kady, Ihab

    2014-11-01

    Plane wave expansion analyses that use the inverse rule to obtain the Fourier coefficients of the elastic tensor instead of the more conventional Laurent's rule, exhibit faster convergence rates for solid-solid phononic crystals. In this work, the band structure convergence of calculations using the inverse rule is investigated and applied to the case of high acoustic impedance contrast solid-solid phononic crystals, previously known for convergence difficulties. Results are contrasted to those obtained with the conventional plane wave expansion method. The inverse rule is found to converge at a much rate for all ranges of impedance contrast, and the ratio between the computational times needed to obtain a convergent band structure for a high-contrast solid-solid phononic crystal with the conventional plane wave expansion method using 1369 reciprocal lattice vectors is as large as 6800:1. This ratio decreases for material sets with lower impedance contrast; however, the inverse rule is still faster for a given error threshold for even the lowest impedance contrast phononic crystals reported in the literature. This convergence enhancement is a major factor in reconsidering the plane wave expansion method as an important tool in obtaining propagating elastic modes in phononic crystals.

  1. Structure, optical and phonon properties of bulk and nanocrystalline Al2-xScx(WO4)3 solid solutions doped with Cr3+

    NASA Astrophysics Data System (ADS)

    Mączka, M.; Hermanowicz, K.; Pietraszko, A.; Yordanova, A.; Koseva, I.

    2014-01-01

    Pure and Cr3+ doped nanosized Al2-xScx(WO4)3 solid solutions were prepared by co-precipitation method as well as Al2-xScx(WO4)3 single crystals were grown by high-temperature flux method. The obtained samples were characterized by X-ray, Raman, IR, absorption and luminescence methods. Single crystal X-ray diffraction showed that AlSc(WO4)3 is orthorhombic at room temperature with space group Pnca and trivalent cations are statistically distributed. Raman and IR studies showed that Al2-xScx(WO4)3 solid solutions show "two mode" behavior. They also showed that vibrational properties of nanosized samples have been weakly modified in comparison with the bulk materials. The luminescence and absorption spectra revealed that chromium ions occupy two sites of weak and strong crystal field strength.

  2. Analysis of matching conditions at the boundary surface of a fluid-saturated porous solid and a bulk fluid: the use of Lagrange multipliers

    NASA Astrophysics Data System (ADS)

    Kubik, J.; Cieszko, M.

    2005-12-01

    The compatibility conditions matching macroscopic mechanical fields at the contact surface between a fluid-saturated porous solid and an adjacent bulk fluid are considered. The general form of balance equations at that discontinuity surface are analyzed to obtain the compatibility conditions for the tangent and normal components of the velocity and the stress vector fields. Considerations are based on the procedure similar to that used in the phenomenological thermodynamics for derivation of constitutive relations, where the entropy inequality and the concept of Lagrange multipliers are applied. This procedure made possible to derive the compatibility conditions for the viscous fluid flowing tangentially and perpendicularly to the boundary surface of the porous solid and to formulate the generalized form of the so called slip condition for the fluid velocity field, postulated earlier by Beavers and Joseph, J. Fluid. Mech. 30, 197-207 (1967).

  3. Rungs 1 to 4 of DFT Jacob's ladder: Extensive test on the lattice constant, bulk modulus, and cohesive energy of solids.

    PubMed

    Tran, Fabien; Stelzl, Julia; Blaha, Peter

    2016-05-28

    A large panel of old and recently proposed exchange-correlation functionals belonging to rungs 1 to 4 of Jacob's ladder of density functional theory are tested (with and without a dispersion correction term) for the calculation of the lattice constant, bulk modulus, and cohesive energy of solids. Particular attention will be paid to the functionals MGGA_MS2 [J. Sun et al., J. Chem. Phys. 138, 044113 (2013)], mBEEF [J. Wellendorff et al., J. Chem. Phys. 140, 144107 (2014)], and SCAN [J. Sun et al., Phys. Rev. Lett. 115, 036402 (2015)] which are meta-generalized gradient approximations (meta-GGA) and are developed with the goal to be universally good. Another goal is also to determine for which semilocal functionals and groups of solids it is beneficial (or not necessary) to use the Hartree-Fock exchange or a dispersion correction term. It is concluded that for strongly bound solids, functionals of the GGA, i.e., rung 2 of Jacob's ladder, are as accurate as the more sophisticated functionals of the higher rungs, while it is necessary to use dispersion corrected functionals in order to expect at least meaningful results for weakly bound solids. If results for finite systems are also considered, then the meta-GGA functionals are overall clearly superior to the GGA functionals. PMID:27250292

  4. Rungs 1 to 4 of DFT Jacob's ladder: Extensive test on the lattice constant, bulk modulus, and cohesive energy of solids

    NASA Astrophysics Data System (ADS)

    Tran, Fabien; Stelzl, Julia; Blaha, Peter

    2016-05-01

    A large panel of old and recently proposed exchange-correlation functionals belonging to rungs 1 to 4 of Jacob's ladder of density functional theory are tested (with and without a dispersion correction term) for the calculation of the lattice constant, bulk modulus, and cohesive energy of solids. Particular attention will be paid to the functionals MGGA_MS2 [J. Sun et al., J. Chem. Phys. 138, 044113 (2013)], mBEEF [J. Wellendorff et al., J. Chem. Phys. 140, 144107 (2014)], and SCAN [J. Sun et al., Phys. Rev. Lett. 115, 036402 (2015)] which are meta-generalized gradient approximations (meta-GGA) and are developed with the goal to be universally good. Another goal is also to determine for which semilocal functionals and groups of solids it is beneficial (or not necessary) to use the Hartree-Fock exchange or a dispersion correction term. It is concluded that for strongly bound solids, functionals of the GGA, i.e., rung 2 of Jacob's ladder, are as accurate as the more sophisticated functionals of the higher rungs, while it is necessary to use dispersion corrected functionals in order to expect at least meaningful results for weakly bound solids. If results for finite systems are also considered, then the meta-GGA functionals are overall clearly superior to the GGA functionals.

  5. Simulation study of a chaotic cavity transducer based virtual phased array used for focusing in the bulk of a solid material.

    PubMed

    Delrue, Steven; Van Den Abeele, Koen; Matar, Olivier Bou

    2016-04-01

    In acoustic and ultrasonic non-destructive testing techniques, it is sometimes beneficial to concentrate sound energy at a chosen location in space and at a specific instance in time, for example to improve the signal-to-noise ratio or activate the nonlinearity of damage features. Time Reversal (TR) techniques, taking advantage of the reversible character of the wave equation, are particularly suited to focus ultrasonic waves in time and space. The characteristics of the energy focusing in solid media using principles of time reversed acoustics are highly influenced by the nature and dimensions of the medium, the number of transducers and the length of the received signals. Usually, a large number of transducers enclosing the domain of interest is needed to improve the quality of the focusing. However, in the case of highly reverberant media, the number of transducers can be reduced to only one (single-channel TR). For focusing in a non-reverberant medium, which is impossible when using only one source, an adaptation of the single-channel reciprocal TR procedure has been recently suggested by means of a Chaotic Cavity Transducer (CCT), a single element transducer glued on a cavity of chaotic shape. In this paper, a CCT is used to focus elastic energy, at different times, in different points along a predefined line on the upper surface of a thick solid sample. Doing so, all focusing points can act as a virtual phased array transducer, allowing to focus in any point along the depth direction of the sample. This is impossible using conventional reciprocal TR, as you need to have access to all points in the bulk of the material for detecting signals to be used in the TR process. To asses and provide a better understanding of this concept, a numerical study has been developed, allowing to verify the basic concepts of the virtual phased array and to illustrate multi-component time reversal focusing in the bulk of a solid material. PMID:26845370

  6. Modeling target bulk heating resulting from ultra-intense short pulse laser irradiation of solid density targets

    SciTech Connect

    Antici, P.; INRS-EMT, Varennes, Québec; Istituto Nazionale di Fisica Nucleare, Via E. Fermi, 40-00044 Frascati; LULI, École Polytechnique, CNRS, CEA, UPMC, route de Saclay, 91128 Palaiseau ; Gremillet, L.; Grismayer, T.; Audebert, P.; Mančic, A.; Fuchs, J.; Borghesi, M.; Cecchetti, C. A.

    2013-12-15

    Isochoric heating of solid-density matter up to a few tens of eV is of interest for investigating astrophysical or inertial fusion scenarios. Such ultra-fast heating can be achieved via the energy deposition of short-pulse laser generated electrons. Here, we report on experimental measurements of this process by means of time- and space-resolved optical interferometry. Our results are found in reasonable agreement with a simple numerical model of fast electron-induced heating.

  7. Bulk pesticide storage - state perspective

    SciTech Connect

    Buzicky, G.

    1994-12-31

    State bulk pesticide storage regulations continue to evolve differentially due, in large part, to the absence of federal regulations. This is about to change because of the pending promulgation of 40 CFR Part 165, as amended in 1988 by the Environmental Protection Agency (EPA) rules regarding storage, handling and disposal. Until final adoption of the rules by EPA, states continue to address bulk pesticide storage and handling according to individual state statute, rules and guidelines.

  8. Pseudo-binary electrolyte, LiBH4-LiCl, for bulk-type all-solid-state lithium-sulfur battery.

    PubMed

    Unemoto, Atsushi; Chen, ChunLin; Wang, Zhongchang; Matsuo, Motoaki; Ikeshoji, Tamio; Orimo, Shin-Ichi

    2015-01-26

    The ionic conduction and electrochemical and thermal stabilities of the LiBH4-LiCl solid-state electrolyte were investigated for use in bulk-type all-solid-state lithium-sulfur batteries. The LiBH4-LiCl solid-state electrolyte exhibiting a lithium ionic conductivity of [Formula: see text] at 373 K, forms a reversible interface with a lithium metal electrode and has a wide electrochemical potential window up to 5 V. By means of the high-energy mechanical ball-milling technique, we prepared a composite powder consisting of elemental sulfur and mixed conductive additive, i.e., Ketjen black and Maxsorb. In that composite powder, homogeneous dispersion of the materials is achieved on a nanometer scale, and thereby a high concentration of the interface among them is induced. Such nanometer-scale dispersals of both elemental sulfur and carbon materials play an important role in enhancing the electrochemical reaction of elemental sulfur. The highly deformable LiBH4-LiCl electrolyte assists in the formation of a high concentration of tight interfaces with the sulfur-carbon composite powder. The LiBH4-LiCl electrolyte also allows the formation of the interface between the positive electrode and the electrolyte layers, and thus the Li-ion transport paths are established at that interface. As a result, our battery exhibits high discharge capacities of 1377, 856, and 636 mAh g(-1) for the 1st, 2nd, and 5th discharges, respectively, at 373 K. These results imply that complex hydride-based solid-state electrolytes that contain Cl-ions in the crystal would be integrated into rechargeable batteries. PMID:26041380

  9. Pseudo-binary electrolyte, LiBH4-LiCl, for bulk-type all-solid-state lithium-sulfur battery

    NASA Astrophysics Data System (ADS)

    Unemoto, Atsushi; Chen, ChunLin; Wang, Zhongchang; Matsuo, Motoaki; Ikeshoji, Tamio; Orimo, Shin-ichi

    2015-06-01

    The ionic conduction and electrochemical and thermal stabilities of the LiBH4-LiCl solid-state electrolyte were investigated for use in bulk-type all-solid-state lithium-sulfur batteries. The LiBH4-LiCl solid-state electrolyte exhibiting a lithium ionic conductivity of log ≤ft( σ /S c{{m}-1} \\right)=-3.3 at 373 K, forms a reversible interface with a lithium metal electrode and has a wide electrochemical potential window up to 5 V. By means of the high-energy mechanical ball-milling technique, we prepared a composite powder consisting of elemental sulfur and mixed conductive additive, i.e., Ketjen black and Maxsorb. In that composite powder, homogeneous dispersion of the materials is achieved on a nanometer scale, and thereby a high concentration of the interface among them is induced. Such nanometer-scale dispersals of both elemental sulfur and carbon materials play an important role in enhancing the electrochemical reaction of elemental sulfur. The highly deformable LiBH4-LiCl electrolyte assists in the formation of a high concentration of tight interfaces with the sulfur-carbon composite powder. The LiBH4-LiCl electrolyte also allows the formation of the interface between the positive electrode and the electrolyte layers, and thus the Li-ion transport paths are established at that interface. As a result, our battery exhibits high discharge capacities of 1377, 856, and 636 mAh g-1 for the 1st, 2nd, and 5th discharges, respectively, at 373 K. These results imply that complex hydride-based solid-state electrolytes that contain Cl-ions in the crystal would be integrated into rechargeable batteries.

  10. Development and validation of TLC-densitometric method for determination of lipid A adjuvant as a bulk and in solid fat nanoemulsions.

    PubMed

    Minz, Sunita; Kaurav, Monika; Sahu, Kantrol Kumar; Mandal, Vivekananda; Pandey, Ravi Shankar

    2015-10-01

    A simple, sensitive, selective and precise high-performance thin-layer chromatographic method was developed for determination of lipid A (MPLA) adjuvant as a bulk and in solid fat nanoemulsions. Chromatographic separations were performed on thin-layer chromatography aluminum plates precoated with silica gel 60 F-254 as stationary phase and chloroform-methanol-ethyl acetate solution (10:2:4, v/v/v) as mobile phase. With this solvent system, compact spots for MPLA at Rf value 0.80 ± 0.02 were obtained. Densitometric analysis of MPLA was carried out in absorbance mode at 357 nm. Linear regression analysis for the calibration plots showed good linear relationship with r = 0.9996 in the concentration range of 20-100 ng/spot. The mean values (±SD) of slope and intercept were found to be 7.355 ± 0.006 and 109.52 ± 0.170, respectively. Limits of detection (LOD) and quantitation (LOQ) were observed at 3.096 and 9.382 ng/spot, respectively.The method was validated for precision, accuracy, robustness and recovery as per the International Conference on Harmonization guidelines. Statistical analysis proved that the developed method for quantification of MPLA as a bulk and in solid fat nanoemulsions is reproducible, selective and economical. This method could be applied for quantitative assay of MPLA in lipid-based vaccine formulations. PMID:25708181

  11. Solid state synthesis and characterization of bulk FeTe0.5Se0.5 superconductors

    NASA Astrophysics Data System (ADS)

    Onar, K.; Yakinci, M. E.

    2016-01-01

    FeTe0.5Se0.5 polycrystalline superconductor samples were synthesized by solid- state reaction method at different heating temperatures. The morphological and structural characterization of FeTe0 5Se0.5 samples were carried out by X-rays Diffraction, Scanning Electron Microscope and Energy Dispersive X-ray Spectroscopy. The electrical, magnetic and thermal transport properties were investigated up to 8 T by using physical property measurement system. The results reveal that the sensitivity of electrical and magnetic properties strongly depends on the heat treatment cycles. The upper critical field, Hc2(0), was determined with the magnetic field parallel to the sample surface. It gives a maximum value of 36.3 T. The lower critical field, Hc1(T), was obtained as 210, 140 and 70 Oe at 5, 8 and 12 K, respectively. The coherence length, ξ, at the zero field, was calculated to be 1.94 nm and suggested a transparent intergrain boundaries peculiarity. The μ0Hc2(0)/kBTc rate shows higher value (3.36 T/K) than the Pauli limit (1.84 T/K) which suggests unconventional nature of superconductivity for the polycrystalline FeTe0.5Se0.5 superconducting samples.

  12. Thermodynamics of Fe3O4-Co3O4 and Fe3O4-Mn3O4 spinel solid solutions at the bulk and nanoscale.

    PubMed

    Sahu, Sulata K; Huang, Baiyu; Lilova, Kristina; Woodfield, Brian F; Navrotsky, Alexandra

    2015-09-14

    High temperature oxide melt solution calorimetry has been performed to investigate the enthalpies of mixing (ΔmixH) of bulk and nanophase (1 -x)Fe3O4-xM3O4 (M = Co, Mn) spinel solid solutions. The entropies of mixing (ΔmixS) were calculated from the configurational entropies based on cation distributions, and the Gibbs free energies of mixing (ΔmixG) were obtained. The ΔmixH and ΔmixG for the (1 -x)Fe3O4-xCo3O4 system are negative over the complete solid solution range, for both macroscopic and nanoparticulate materials. In (1 -x)Fe3O4-xMn3O4, the formation enthalpies of cubic Fe3O4 (magnetite) and tetragonal Mn3O4 (hausmannite) are negative for Mn3O4 mole fractions less than 0.67 and slightly positive for higher manganese content. Relative to cubic Fe3O4 and cubic Mn3O4 (stable at high temperature), the enthalpies and Gibbs energies of mixing are negative over the entire composition range. A combination of measured mixing enthalpies and reported Gibbs energies in the literature provides experimental entropies of mixing. The experimental entropies of mixing are consistent with those calculated from cation distributions for x > 0.3 but are smaller than those predicted for x < 0.3. This discrepancy may be related to the calculations, having treated Fe(2+) and Fe(3+) as distinguishable species. The measured surface energies of the (1 -x)Fe3O4-xM3O4 solid solutions are in the range of 0.6-0.9 J m(-2), similar to those of many other spinels. Because the surface energies are relatively constant, the thermodynamics of mixing at a given particle size throughout the solid solution can be considered independent of the particular particle size, thus confirming and extending the conclusions of a recent study on iron spinels. PMID:26245233

  13. Dynamic measurement of bulk modulus

    NASA Technical Reports Server (NTRS)

    Dowler, W. L.; Strand, L. D.

    1979-01-01

    Technique based on measuring phase difference between microwave reference and test signals and has been used to determine change in bulk modulus of solid-fuel rocket propellants should be useful in studying other dielectric materials.

  14. Occupational vitiligo due to unsuspected presence of phenolic antioxidant byproducts in commercial bulk rubber

    SciTech Connect

    O'Malley, M.A.; Mathias, C.G.; Priddy, M.; Molina, D.; Grote, A.A.; Halperin, W.E.

    1988-06-01

    We investigated the occurrence of cutaneous depigmentation (vitiligo) among employees of a company that manufactured hydraulic pumps. The interiors of these pumps were injection-molded with rubber. We identified a small but significant cluster of vitiligo cases among a group of employees who frequently handled the rubber used in this injection molding process. Although none of the additives specified in the rubber formulations was a phenolic or catecholic derivative, known to be potential causes of chemically induced vitiligo, gas chromatographic analysis identified a para-substituted phenol (2,4-di-tert-butylphenol, DTBP) in solid samples of the most frequently used rubber. Surface wipe analysis confirmed that workers could be exposed to DTBP from simple handling of the rubber. We subsequently established that the solid bulk rubber used as the base in these stock rubber formulations contained both DTBP and smaller quantities of p-tert-butylphenol. Both had formed as unsuspected byproducts during chemical synthesis of two antioxidants added to the solid bulk rubber by a major rubber supplier. We conclude that the unsuspected presence of potential chemical depigmenting agents in solid bulk rubber, from which industrial rubber products are formulated, may contribute to the occurrence of occupational vitiligo, and that a simple review of ingredients in rubber formulations is inadequate to detect their presence.

  15. Bulk density of wet and dry wheat straw and switchgrass particles

    SciTech Connect

    Sokhansanj, Shahabaddine; Bi, X.T.; Naimi, L.J.; Hoque, M.; Mani, Sudhagar; Narayan, S.

    2008-05-01

    ABSTRACT. Bulk density is a major physical property in designing the logistic system for biomass handling. The size, shape, moisture content, individual particle density, and surface characteristics are few factors affecting the bulk density. This research investigates the effects of true particle lengths ranging from 6 to 50 mm and moisture contents ranging from 8% to 60% wet basis (wb) on the bulk density of wheat straw and switchgrass. Three types of particle densities of straw and switchgrass measured were: a hollow particle density assuming a hollow cylindrical geometry, a solid particle density assuming a solid cylindrical geometry, and a particle density measured using a gas pycnometer at a gas pressure of 40 kPa. The bulk density of both loose fill and packed fill biomass samples was examined. The calculated wet and dry bulk density ranged from 24 to 111 kg m 3 for straw and from 49 to 266 kg m 3 for switchgrass. The corresponding tapped bulk density ranged from 34 to 130 kg m 3 for straw and 68 to 323 kg m 3 for switchgrass. The increase in bulk density due to tapping the container was from 10% for short 6 mm particles to more than 50% for long 50 mm particles. An equation relating the bulk density of stems as a function of moisture content, dry bulk density, and particle size was developed. After the validation of this bulk density equation, the relationship would be highly useful in designing the logistics system for large scale transport of biomass to a biorefinery. The bulk density and particle density data of uniform particles would be important, if straw and switchgrass is used for pulping and paper making.

  16. 33 CFR 127.313 - Bulk storage.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) WATERFRONT FACILITIES WATERFRONT FACILITIES HANDLING LIQUEFIED NATURAL GAS AND LIQUEFIED HAZARDOUS GAS Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator... other fuels in the amount used for one day's operations and maintenance. (b) Flammable liquids must...

  17. 33 CFR 127.313 - Bulk storage.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) WATERFRONT FACILITIES WATERFRONT FACILITIES HANDLING LIQUEFIED NATURAL GAS AND LIQUEFIED HAZARDOUS GAS Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator... other fuels in the amount used for one day's operations and maintenance. (b) Flammable liquids must...

  18. 33 CFR 127.313 - Bulk storage.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) WATERFRONT FACILITIES WATERFRONT FACILITIES HANDLING LIQUEFIED NATURAL GAS AND LIQUEFIED HAZARDOUS GAS Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.313 Bulk storage. (a) The operator... other fuels in the amount used for one day's operations and maintenance. (b) Flammable liquids must...

  19. Precision of the all-glass impinger and the andersen microbial impactor for air sampling in solid-waste handling facilities.

    PubMed Central

    Lembke, L L; Kniseley, R N; van Nostrand, R C; Hale, M D

    1981-01-01

    A method was devised to determine the precision of the all-glass impinger and the Andersen six-stage microbial impactor over a wide range of aerosol concentrations like those found in facilities which process solid waste. Simultaneous samples were collected inside a municipal solid-waste recovery system, and the data were treated statistically to estimate the precision of each air-sampling device. All-glass impingers yielded colony counts which indicated a linear relationship between samplers over an observed aerosol concentration of 1.1 X 10(3) to 2.8 X 10(7) colony-forming units per m3 of air. Impactors also yielded colony counts which indicated a linear relationship over an observed aerosol concentration range of 3.9 X 10(3) to 1.9 X 10(5) colony-forming units per m3 of air. The coefficients of variation for the all-glass impinger and the six-stage impactor in an environment with a high and variable dust level were determined to be 0.38 and 0.23, respectively. PMID:7025757

  20. 324 Building Compliance Project: Selection and evaluation of alternatives for the removal of solid remote-handled mixed wastes from the 324 Building

    SciTech Connect

    Ross, W.A.; Bierschbach, M.C.; Dukelow, J.S. Jr.

    1995-06-01

    Six alternatives for the interim storage of remote-handled mixed wastes from the 324 Building on the Hanford Site have been identified and evaluated. The alternatives focus on the interim storage facility and include use of existing facilities in the 200 Area, the construction of new facilities, and the vitrification of the wastes within the 324 Building to remove the majority of the wastes from under RCRA regulations. The six alternatives are summarized in Table S.1, which identifies the primary facilities to be utilized, the anticipated schedule for removal of the wastes, the costs of the transfer from 324 Building to the interim storage facility (including any capital costs), and an initial risk comparison of the alternatives. A recently negotiated Tri-Party Agreement (TPA) change requires the last of the mixed wastes to be removed by May 1999. The ability to use an existing facility reduces the costs since it eliminates the need for new capital construction. The basic regulatory approvals for the storage of mixed wastes are in place for the PUREX facility, but the Form HI permit will need some minor modifications since the 324 Building wastes have some additional characteristic waste codes and the current permit limits storage of wastes to those from the facility itself. Regulatory reviews have indicated that it will be best to use the tunnels to store the wastes. The PUREX alternatives will only provide storage for about 65% of the wastes. This results from the current schedule of the B-Cell Clean Out Project, which projects that dispersible debris will continue to be collected in small quantities until the year 2000. The remaining fraction of the wastes will then be stored in another facility. Central Waste Complex (CWC) is currently proposed for that residual waste storage; however, other options may also be available.

  1. Bulk undercooling

    NASA Technical Reports Server (NTRS)

    Kattamis, T. Z.

    1984-01-01

    Bulk undercooling methods and procedures will first be reviewed. Measurement of various parameters which are necessary to understand the solidification mechanism during and after recalescence will be discussed. During recalescence of levitated, glass-encased large droplets (5 to 8 mm diam) high speed temperature sensing devices coupled with a rapid response oscilloscope are now being used at MIT to measure local thermal behavior in hypoeutectic and eutectic binary Ni-Sn alloys. Dendrite tip velocities were measured by various investigators using thermal sensors or high speed cinematography. The confirmation of the validity of solidification models of bulk-undercooled melts is made difficult by the fineness of the final microstructure, the ultra-rapid evolution of the solidifying system which makes measurements very awkward, and the continuous modification of the microstructure which formed during recalescence because of precipitation, remelting and rapid coarsening.

  2. Unravelling Li-Ion Transport from Picoseconds to Seconds: Bulk versus Interfaces in an Argyrodite Li6PS5Cl-Li2S All-Solid-State Li-Ion Battery.

    PubMed

    Yu, Chuang; Ganapathy, Swapna; de Klerk, Niek J J; Roslon, Irek; van Eck, Ernst R H; Kentgens, Arno P M; Wagemaker, Marnix

    2016-09-01

    One of the main challenges of all-solid-state Li-ion batteries is the restricted power density due to the poor Li-ion transport between the electrodes via the electrolyte. However, to establish what diffusional process is the bottleneck for Li-ion transport requires the ability to distinguish the various processes. The present work investigates the Li-ion diffusion in argyrodite Li6PS5Cl, a promising electrolyte based on its high Li-ion conductivity, using a combination of (7)Li NMR experiments and DFT based molecular dynamics simulations. This allows us to distinguish the local Li-ion mobility from the long-range Li-ion motional process, quantifying both and giving a coherent and consistent picture of the bulk diffusion in Li6PS5Cl. NMR exchange experiments are used to unambiguously characterize Li-ion transport over the solid electrolyte-electrode interface for the electrolyte-electrode combination Li6PS5Cl-Li2S, giving unprecedented and direct quantitative insight into the impact of the interface on Li-ion charge transport in all-solid-state batteries. The limited Li-ion transport over the Li6PS5Cl-Li2S interface, orders of magnitude smaller compared with that in the bulk Li6PS5Cl, appears to be the bottleneck for the performance of the Li6PS5Cl-Li2S battery, quantifying one of the major challenges toward improved performance of all-solid-state batteries. PMID:27511442

  3. Achieving high capacity in bulk-type solid-state lithium ion battery based on Li6.75La3Zr1.75Ta0.25O12 electrolyte: Interfacial resistance

    NASA Astrophysics Data System (ADS)

    Liu, Ting; Ren, Yaoyu; Shen, Yang; Zhao, Shi-Xi; Lin, Yuanhua; Nan, Ce-Wen

    2016-08-01

    A bulk-type all-solid-state lithium ion battery based on Ta-doped Li6.75La3Zr1.75Ta0.25O12 (LLZ-Ta) is prepared by a simple solid state process with high capacity of 279.0 μAh cm-2 at 80 °C. However, severe polarization is discovered during charging/discharging cycles at room temperature (RT) for battery with a higher active cathode loading. Large interfacial resistance due to the poor contact at the interfaces between cathode and LLZ-Ta solid electrolyte and at the interfaces within the composite cathode layer is proven to be the main reason for the poor electrochemical performance of the battery at RT. The polarization could be suppressed at elevated temperature, which is attributed to the decreased interfacial resistance as indicated by the results of impedance measurements and gives rise to much enhanced performance of the all-solid-state battery.

  4. Bench-scale testing of DOE/PETC`s GranuFlow Process for fine coal dewatering and handling. 1: Results using a high-gravity solid-bowl centrifuge

    SciTech Connect

    Wen, W.W.; Killmeyer, R.P.; Lowman, R.H.; Elstrodt, R.

    1995-12-31

    Most advanced fine-coal cleaning processes involve the use of water. Utility companies are concerned not only with the lower Btu content of the resulting wet, cleaned coal, but more importantly with its handleability problems. Solutions to these problems would enhance the utilization of fine-coal cleaning processes in the utility industry. This paper describes testing of the GranuFlow Process, developed and patented by the Pittsburgh Energy Technology Center (PETC) of the US Department of Energy, using a high-gravity solid bowl centrifuge for dewatering and reconstitution of fine-cleaned-coal slurry at 300 lb per hour in PETC`s Coal Preparation Process Research Facility. Fine-cleaned-coal slurry was treated with a bitumen emulsion before dewatering in a high-gravity solid-bowl centrifuge. The treated products appeared to be dry and in a free-flowing granular form, while the untreated products were wet, lumpy, sticky, and difficult to handle. Specifically, test results indicated that the moisture content, handleability, and dust reduction of the dewatered coal product improved as the addition of emulsion increased from 2% to 8%. The improvement in handleability was most visible for the 200 mesh (75 micron) x 0 coal, when compared with 150 mesh (106 micron) x 0, 65 mesh (212 micron) x 0 or 28 mesh (600 micron) x 0 coals. Test results also showed that the moisture content was dramatically reduced (26--37% reduction) for the four different sizes of coals at 6 or 8% emulsion addition. Because of the moisture reduction and the granular form of the product, the freezing problem was also alleviated.

  5. Bulk Stable Isotope Analysis of Carbon from Solids and Liquids using an Elemental Analyzer Coupled to a Wavelength-Scanned Cavity Ring-Down Spectrophotometer

    NASA Astrophysics Data System (ADS)

    Saad, N.; Rella, C.; van Pelt, A.

    2009-04-01

    We report here on the novel employment of a small footprint Wavelength-Scanned Cavity Ring-Down Spectrometer (WS-CRDS) interfaced to an elemental analyzer for the measurement of the bulk isotopic carbon signature in plants and food products. The current system provides an inexpensive alternative with unparalleled ease-of-use as compared to standard methods using the more complex analytical instrumentation of isotope ratio mass spectrometry. A precision of carbon isotopic ratio measurements of less than 1 permil was achieved in minutes of measurement time. Such precision readily distinguishes the isotopic carbon signatures of a variety of environmental and agricultural products from different origins, providing information about food authenticity and climate changes effect on plant physiology.

  6. 46 CFR 151.25-2 - Cargo handling space.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo handling space. 151.25-2 Section 151.25-2 Shipping... BULK LIQUID HAZARDOUS MATERIAL CARGOES Environmental Control § 151.25-2 Cargo handling space. Pump rooms, compressor rooms, refrigeration rooms, heating rooms, instrument rooms or other closed...

  7. 46 CFR 151.25-2 - Cargo handling space.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo handling space. 151.25-2 Section 151.25-2 Shipping... BULK LIQUID HAZARDOUS MATERIAL CARGOES Environmental Control § 151.25-2 Cargo handling space. Pump rooms, compressor rooms, refrigeration rooms, heating rooms, instrument rooms or other closed...

  8. 46 CFR 151.25-2 - Cargo handling space.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Cargo handling space. 151.25-2 Section 151.25-2 Shipping... BULK LIQUID HAZARDOUS MATERIAL CARGOES Environmental Control § 151.25-2 Cargo handling space. Pump rooms, compressor rooms, refrigeration rooms, heating rooms, instrument rooms or other closed...

  9. 46 CFR 151.25-2 - Cargo handling space.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Cargo handling space. 151.25-2 Section 151.25-2 Shipping... BULK LIQUID HAZARDOUS MATERIAL CARGOES Environmental Control § 151.25-2 Cargo handling space. Pump rooms, compressor rooms, refrigeration rooms, heating rooms, instrument rooms or other closed...

  10. 46 CFR 151.25-2 - Cargo handling space.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Cargo handling space. 151.25-2 Section 151.25-2 Shipping... BULK LIQUID HAZARDOUS MATERIAL CARGOES Environmental Control § 151.25-2 Cargo handling space. Pump rooms, compressor rooms, refrigeration rooms, heating rooms, instrument rooms or other closed...

  11. Early diagenesis of mangrove leaves in a tropical estuary: Bulk chemical characterization using solid-state 13C NMR and elemental analyses

    NASA Astrophysics Data System (ADS)

    Benner, Ronald; Hatcher, Patrick G.; Hedges, John I.

    1990-07-01

    Changes in the chemical composition of mangrove ( Rhizophora mangle) leaves during decomposition in tropical estuarine waters were characterized using solid-state 13C nuclear magnetic resonance (NMR) and elemental (CHNO) analysis. Carbohydrates were the most abundant components of the leaves accounting for about 50 wt% of senescent tissues. Tannins were estimated to account for about 20 wt% of leaf tissues, and lipid components, cutin, and possibly other aliphatic biopolymers in leaf cuticles accounted for about 15 wt%. Carbohydrates were generally less resistant to decomposition than the other constituents and decreased in relative concentration during decomposition. Tannins were of intermediate resistance to decomposition and remained in fairly constant proportion during decomposition. Paraffinic components were very resistant to decomposition and increased in relative concentration as decomposition progressed. Lignin was a minor component of all leaf tissues. Standard methods for the colorimetric determination of tannins (Folin-Dennis reagent) and the gravimetric determination of lignin (Klason lignin) were highly inaccurate when applied to mangrove leaves. The N content of the leaves was particularly dynamic with values ranging from 1.27 wt% in green leaves to 0.65 wt% in senescent yellow leaves attached to trees. During decomposition in the water the N content initially decreased to 0.51 wt% due to leaching, but values steadily increased thereafter to 1.07 wt% in the most degraded leaf samples. The absolute mass of N in the leaves increased during decomposition indicating that N immobilization was occurring as decomposition progressed.

  12. Early diagenesis of mangrove leaves in a tropical estuary: Bulk chemical characterization using solid-state 13C NMR and elemental analyses

    USGS Publications Warehouse

    Benner, R.; Hatcher, P.G.; Hedges, J.I.

    1990-01-01

    Changes in the chemical composition of mangrove (Rhizophora mangle) leaves during decomposition in tropical estuarine waters were characterized using solid-state 13C nuclear magnetic resonance (NMR) and elemental (CHNO) analysis. Carbohydrates were the most abundant components of the leaves accounting for about 50 wt% of senescent tissues. Tannins were estimated to account for about 20 wt% of leaf tissues, and lipid components, cutin, and possibly other aliphatic biopolymers in leaf cuticles accounted for about 15 wt%. Carbohydrates were generally less resistant to decomposition than the other constituents and decreased in relative concentration during decomposition. Tannins were of intermediate resistance to decomposition and remained in fairly constant proportion during decomposition. Paraffinic components were very resistant to decomposition and increased in relative concentration as decomposition progressed. Lignin was a minor component of all leaf tissues. Standard methods for the colorimetric determination of tannins (Folin-Dennis reagent) and the gravimetric determination of lignin (Klason lignin) were highly inaccurate when applied to mangrove leaves. The N content of the leaves was particularly dynamic with values ranging from 1.27 wt% in green leaves to 0.65 wt% in senescent yellow leaves attached to trees. During decomposition in the water the N content initially decreased to 0.51 wt% due to leaching, but values steadily increased thereafter to 1.07 wt% in the most degraded leaf samples. The absolute mass of N in the leaves increased during decomposition indicating that N immobilization was occurring as decomposition progressed. ?? 1990.

  13. Temporal soil bulk density following tillage

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soil is the medium for air, energy, water, and chemical transport between the atmosphere and the solid earth. Soil bulk density is a key variable impacting the rate at which this transport occurs. Typically, soil bulk density is measured by the gravimetric method, where a sample of known volume is t...

  14. Grain Handling and Storage.

    ERIC Educational Resources Information Center

    Harris, Troy G.; Minor, John

    This text for a secondary- or postecondary-level course in grain handling and storage contains ten chapters. Chapter titles are (1) Introduction to Grain Handling and Storage, (2) Elevator Safety, (3) Grain Grading and Seed Identification, (4) Moisture Control, (5) Insect and Rodent Control, (6) Grain Inventory Control, (7) Elevator Maintenance,…

  15. Bulk Data Mover

    SciTech Connect

    2011-01-03

    Bulk Data Mover (BDM) is a high-level data transfer management tool. BDM handles the issue of large variance in file sizes and a big portion of small files by managing the file transfers with optimized transfer queue and concurrency management algorithms. For example, climate simulation data sets are characterized by large volume of files with extreme variance in file sizes. The BDN achieves high performance using a variety of techniques, including multi-thraded concurrent transfer connections, data channel caching, load balancing over multiple transfer servers, and storage i/o pre-fetching. Logging information from the BDM is collected and analyzed to study the effectiveness of the transfer management algorithms. The BDM can accept a request composed of multiple files or an entire directory. The request also contains the target site and directory where the replicated files will reside. If a directory is provided at the source, then the BDM will replicate the structure of the source directory at the target site. The BDM is capable of transferring multiple files concurrently as well as using parallel TCP streams. The optimal level of concurrency or parallel streams depends on the bandwidth capacity of the storage systems at both ends of the transfer as well as achievable bandwidth of the wide-area network. Hardware req.-PC, MAC, Multi-platform & Workstation; Software req.: Compile/version-Java 1.50_x or ablove; Type of files: source code, executable modules, installation instructions other, user guide; URL: http://sdm.lbl.gov/bdm/

  16. Omnidirectional Actuator Handle

    NASA Technical Reports Server (NTRS)

    Moetteli, John B.

    1995-01-01

    Proposed actuator handle comprises two normally concentric rings, cables, and pulleys arranged such that relative displacement of rings from concentricity results in pulling of cable and consequent actuation of associated mechanism. Unlike conventional actuator handles like levers on farm implements, actuated from one or two directions only, proposed handle reached from almost any direction and actuated by pulling or pushing inner ring in any direction with respect to outer ring. Flanges installed on inner ring to cover gap between inner ring and housing to prevent clothing from being caught.

  17. Handling Pyrophoric Reagents

    SciTech Connect

    Alnajjar, Mikhail S.; Haynie, Todd O.

    2009-08-14

    Pyrophoric reagents are extremely hazardous. Special handling techniques are required to prevent contact with air and the resulting fire. This document provides several methods for working with pyrophoric reagents outside of an inert atmosphere.

  18. Helicopter Handling Qualities

    NASA Technical Reports Server (NTRS)

    1982-01-01

    Helicopters are used by the military and civilian communities for a variety of tasks and must be capable of operating in poor weather conditions and at night. Accompanying extended helicopter operations is a significant increase in pilot workload and a need for better handling qualities. An overview of the status and problems in the development and specification of helicopter handling-qualities criteria is presented. Topics for future research efforts by government and industry are highlighted.

  19. Bulk entanglement spectrum in gapped spin ladders

    NASA Astrophysics Data System (ADS)

    Santos, Raul A.; Jian, Chao-Ming; Lundgren, Rex

    2016-06-01

    We study the bulk entanglement of a series of gapped ground states of spin ladders, representative of the Haldane phase. These ground states of spin S /2 ladders generalize the valence bond solid ground state. In the case of spin 1/2 ladders, we study a generalization of the Affleck-Kennedy-Lieb-Tasaki and Nersesyan-Tsvelik states and fully characterize the bulk entanglement Hamiltonian. In the case of general spin S , we argue that in the Haldane phase the bulk entanglement spectrum of a half-integer ladder is either gapless or possess a degenerate ground state. For ladders with integer valued spin particles, the generic bulk entanglement spectrum should have an entanglement gap. Finally, we give an example of a series of trivial states of higher spin S >1 in which the bulk entanglement Hamiltonian is critical, signaling that the relation between topological states and a critical bulk entanglement Hamiltonian is not unique to topological systems.

  20. SPAR data handling utilities

    NASA Technical Reports Server (NTRS)

    Giles, G. L.; Haftka, R. T.

    1978-01-01

    The SPAR computer software system is a collection of processors that perform particular steps in the finite-element structural analysis procedure. The data generated by each processor are stored on a data base complex residing on an auxiliary storage device, and these data are then used by subsequent processors. The SPAR data handling utilities use routines to transfer data between the processors and the data base complex. A detailed description of the data base complex organization is presented. A discussion of how these SPAR data handling utilities are used in an application program to perform desired user functions is given with the steps necessary to convert an existing program to a SPAR processor by incorporating these utilities. Finally, a sample SPAR processor is included to illustrate the use of the data handling utilities.

  1. Bulk Data Mover

    Energy Science and Technology Software Center (ESTSC)

    2011-01-03

    Bulk Data Mover (BDM) is a high-level data transfer management tool. BDM handles the issue of large variance in file sizes and a big portion of small files by managing the file transfers with optimized transfer queue and concurrency management algorithms. For example, climate simulation data sets are characterized by large volume of files with extreme variance in file sizes. The BDN achieves high performance using a variety of techniques, including multi-thraded concurrent transfer connections,more » data channel caching, load balancing over multiple transfer servers, and storage i/o pre-fetching. Logging information from the BDM is collected and analyzed to study the effectiveness of the transfer management algorithms. The BDM can accept a request composed of multiple files or an entire directory. The request also contains the target site and directory where the replicated files will reside. If a directory is provided at the source, then the BDM will replicate the structure of the source directory at the target site. The BDM is capable of transferring multiple files concurrently as well as using parallel TCP streams. The optimal level of concurrency or parallel streams depends on the bandwidth capacity of the storage systems at both ends of the transfer as well as achievable bandwidth of the wide-area network. Hardware req.-PC, MAC, Multi-platform & Workstation; Software req.: Compile/version-Java 1.50_x or ablove; Type of files: source code, executable modules, installation instructions other, user guide; URL: http://sdm.lbl.gov/bdm/« less

  2. SLUG HANDLING DEVICES

    DOEpatents

    Gentry, J.R.

    1958-09-16

    A device is described for handling fuel elements of a neutronic reactor. The device consists of two concentric telescoped contalners that may fit about the fuel element. A number of ratchet members, equally spaced about the entrance to the containers, are pivoted on the inner container and spring biased to the outer container so thnt they are forced to hear against and hold the fuel element, the weight of which tends to force the ratchets tighter against the fuel element. The ratchets are released from their hold by raising the inner container relative to the outer memeber. This device reduces the radiation hazard to the personnel handling the fuel elements.

  3. FUEL HANDLING MECHANISM

    DOEpatents

    Koch, L.J.; Hutter, E.

    1960-02-01

    A remotely operable handling device specifically adapted for the handling of vertically disposed fuel rods in a nuclear reactor was developed. The device consists essentially of an elongated tubular member having a gripping device at the lower end of the pivoted jaw type adapted to grip an enlarged head on the upper end of the workpiece. The device includes a sensing element which engages the enlarged head and is displaced to remotely indicate when the workpiece is in the proper position to be engaged by the jaws.

  4. Safe Handling Practices

    NASA Technical Reports Server (NTRS)

    1980-01-01

    In 1977 Compugraphic Corporation was experiencing an unacceptable failure rate on microelectronic chips. Company engineers suspected that static electricity was causing the trouble because some electronic components are highly susceptible to damage by electrostatic charge. From a NASA Tech Brief, they learned that Rockwell International had prepared a report on safe handling practices for electronic components. NASA provided a Technical Support Package detailing 50 safe handling procedures affecting workers, work areas, equipment and packaging materials. Where poor practices were discovered, re-education of employees and other corrective measures were undertaken.

  5. Grain Grading and Handling.

    ERIC Educational Resources Information Center

    Rendleman, Matt; Legacy, James

    This publication provides an introduction to grain grading and handling for adult students in vocational and technical education programs. Organized in five chapters, the booklet provides a brief overview of the jobs performed at a grain elevator and of the techniques used to grade grain. The first chapter introduces the grain industry and…

  6. Microforms in Information Handling.

    ERIC Educational Resources Information Center

    Williams, B. J. S.

    In an attempt to identify some of the factors which influence the utility of microforms as a medium for information handling, this report first traces some of the landmarks in the evolution of microforms since their invention in 1893. It next provides a factual account of current microform media and formats. The last section of the report contains…

  7. Self-heating study of bulk acoustic wave resonators under high RF power.

    PubMed

    Ivira, Brice; Fillit, René-Yves; Ndagijimana, Fabien; Benech, Philippe; Parat, Guy; Ancey, Pascal

    2008-01-01

    The present work first provides an experimental technique to study self-heating of bulk acoustic wave (BAW) resonators under high RF power in the gigahertz range. This study is specially focused on film bulk acoustic wave resonators and solidly mounted resonators processed onto silicon wafers and designed for wireless systems. Precisely, the reflection coefficient of a one-port device is measured while up to several watts are applied and power leads to electrical drifts of impedances. In the following, we describe how absorbed power can be determined from the incident one in real time. Therefore, an infrared camera held over the radio frequency micro electromechanical system (RF-MEMS) surface with an exceptional spatial resolution reaching up to 2 microm/pixels gives accurate temperature mapping of resonators after emissivity correction. From theoretical point of view, accurate three-dimensional (3-D) structures for finite-element modeling analyses are carried out to know the best materials and architectures to use for enhancing power handling. In both experimental and theoretical investigations, comparison is made between film bulk acoustic wave resonators and solidly mounted resonators. Thus, the trend in term of material, architecture, and size of device for power application such as in transmission path of a transceiver is clearly identified. PMID:18334320

  8. System for handling and storing radioactive waste

    DOEpatents

    Anderson, J.K.; Lindemann, P.E.

    1982-07-19

    A system and method are claimed for handling and storing spent reactor fuel and other solid radioactive waste, including canisters to contain the elements of solid waste, storage racks to hold a plurality of such canisters, storage bays to store these racks in isolation by means of shielded doors in the bays. This system also includes means for remotely positioning the racks in the bays and an access tunnel within which the remotely operated means is located to position a rack in a selected bay. The modular type of these bays will facilitate the construction of additional bays and access tunnel extension.

  9. System for handling and storing radioactive waste

    DOEpatents

    Anderson, John K.; Lindemann, Paul E.

    1984-01-01

    A system and method for handling and storing spent reactor fuel and other solid radioactive waste, including canisters to contain the elements of solid waste, storage racks to hold a plurality of such canisters, storage bays to store these racks in isolation by means of shielded doors in the bays. This system also includes means for remotely positioning the racks in the bays and an access tunnel within which the remotely operated means is located to position a rack in a selected bay. The modular type of these bays will facilitate the construction of additional bays and access tunnel extension.

  10. 19 CFR 149.4 - Bulk and break bulk cargo.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 2 2010-04-01 2010-04-01 false Bulk and break bulk cargo. 149.4 Section 149.4... TREASURY (CONTINUED) IMPORTER SECURITY FILING § 149.4 Bulk and break bulk cargo. (a) Bulk cargo exempted.... (b) Break bulk cargo exempted from time requirement. For break bulk cargo that is exempt from...

  11. 19 CFR 149.4 - Bulk and break bulk cargo.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 19 Customs Duties 2 2012-04-01 2012-04-01 false Bulk and break bulk cargo. 149.4 Section 149.4... TREASURY (CONTINUED) IMPORTER SECURITY FILING § 149.4 Bulk and break bulk cargo. (a) Bulk cargo exempted.... (b) Break bulk cargo exempted from time requirement. For break bulk cargo that is exempt from...

  12. 19 CFR 149.4 - Bulk and break bulk cargo.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 19 Customs Duties 2 2014-04-01 2014-04-01 false Bulk and break bulk cargo. 149.4 Section 149.4... TREASURY (CONTINUED) IMPORTER SECURITY FILING § 149.4 Bulk and break bulk cargo. (a) Bulk cargo exempted.... (b) Break bulk cargo exempted from time requirement. For break bulk cargo that is exempt from...

  13. 19 CFR 149.4 - Bulk and break bulk cargo.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 19 Customs Duties 2 2011-04-01 2011-04-01 false Bulk and break bulk cargo. 149.4 Section 149.4... TREASURY (CONTINUED) IMPORTER SECURITY FILING § 149.4 Bulk and break bulk cargo. (a) Bulk cargo exempted.... (b) Break bulk cargo exempted from time requirement. For break bulk cargo that is exempt from...

  14. 19 CFR 149.4 - Bulk and break bulk cargo.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 19 Customs Duties 2 2013-04-01 2013-04-01 false Bulk and break bulk cargo. 149.4 Section 149.4... TREASURY (CONTINUED) IMPORTER SECURITY FILING § 149.4 Bulk and break bulk cargo. (a) Bulk cargo exempted.... (b) Break bulk cargo exempted from time requirement. For break bulk cargo that is exempt from...

  15. Development of liquid handling techniques in microgravity

    NASA Technical Reports Server (NTRS)

    Antar, Basil N.

    1995-01-01

    A large number of experiments dealing with protein crystal growth and also with growth of crystals from solution require complicated fluid handling procedures including filling of empty containers with liquids, mixing of solutions, and stirring of liquids. Such procedures are accomplished in a straight forward manner when performed under terrestrial conditions in the laboratory. However, in the low gravity environment of space, such as on board the Space Shuttle or an Earth-orbiting space station, these procedures sometimes produced entirely undesirable results. Under terrestrial conditions, liquids usually completely separate from the gas due to the buoyancy effects of Earth's gravity. Consequently, any gas pockets that are entrained into the liquid during a fluid handling procedure will eventually migrate towards the top of the vessel where they can be removed. In a low gravity environment any folded gas bubble will remain within the liquid bulk indefinitely at a location that is not known a priori resulting in a mixture of liquid and vapor.

  16. Search continues for coal handling solutions

    SciTech Connect

    Not Available

    1981-03-01

    The marine industry's short-term solutions to coal-handling problems are considered. New York's potential for coal export, a bill to authorize channel-dredging to accommodate large colliers, and the reasons to upgrade mines, inland transportation and ports to meet growing world coal demand are discussed. Inland coal handling facilities such as the high-speed rail-to-barge coal transfer terminal on the Mississippi River at Cora, Illinois, facilities on the Great Lakes and the St. Lawrence Seaway, and the Port of Quebec are discussed, as well as the Public Bulk Terminal at New Orleans and a facility in Baltimore. Information on self-contained portable terminals, i.e., loader-unloaders mounted on ships, is given along with the types of ships and barges used for transportation.

  17. Plutonium Immobilization Puck Handling

    SciTech Connect

    Kriikku, E.

    1999-01-26

    The Plutonium Immobilization Project (PIP) will immobilize excess plutonium and store the plutonium in a high level waste radiation field. To accomplish these goals, the PIP will process various forms of plutonium into plutonium oxide, mix the oxide powder with ceramic precursors, press the mixture into pucks, sinter the pucks into a ceramic puck, load the pucks into metal cans, seal the cans, load the cans into magazines, and load the magazines into a Defense Waste Processing Facility (DPWF) canister. These canisters will be sent to the DWPF, an existing Savannah River Site (SRS) facility, where molten high level waste glass will be poured into the canisters encapsulating the ceramic pucks. Due to the plutonium radiation, remote equipment will perform these operations in a contained environment. The Plutonium Immobilization Project is in the early design stages and the facility will begin operation in 2005. This paper will discuss the Plutonium Immobilization puck handling conceptual design and the puck handling equipment testing.

  18. A PARENTAL HANDLING QUESTIONNAIRE

    PubMed Central

    Malhotra, Savita

    1990-01-01

    SUMMMARY Parental Care and Control, which are two major parental handling, variables are significantly related to psychological morbidity in children where high care-low control is associated with healthy development and low care-high control is related to psychiatric disorder. Parents by & large do not differ in their patterns of handling with regard to age and sex of the child, rural-urban living and SES except that younger children are given more care and those from high SES exercise less control among normal children. However, low care for younger children, high control for older children; low care and high control for males, rural background and higher SES families was associated with psychiatric morbidity in children. PMID:21927469

  19. Space shuttle handling qualities

    NASA Technical Reports Server (NTRS)

    Gilbert, D. W.

    1985-01-01

    The initial Orbiter handling qualities requirements, their effect on the vehicle design, and how it all turned out through the first six orbital missions are reviewed. Specific areas consisting of hand controller considerations and the wheelie problem are discussed. The requirements for the pitch axis subsonic flight control system are reviewed. Results of recent simulator evaluations to compare the existing system at landing with several other configurations are presented.

  20. Uranium hexafluoride handling. Proceedings

    SciTech Connect

    Not Available

    1991-12-31

    The United States Department of Energy, Oak Ridge Field Office, and Martin Marietta Energy Systems, Inc., are co-sponsoring this Second International Conference on Uranium Hexafluoride Handling. The conference is offered as a forum for the exchange of information and concepts regarding the technical and regulatory issues and the safety aspects which relate to the handling of uranium hexafluoride. Through the papers presented here, we attempt not only to share technological advances and lessons learned, but also to demonstrate that we are concerned about the health and safety of our workers and the public, and are good stewards of the environment in which we all work and live. These proceedings are a compilation of the work of many experts in that phase of world-wide industry which comprises the nuclear fuel cycle. Their experience spans the entire range over which uranium hexafluoride is involved in the fuel cycle, from the production of UF{sub 6} from the naturally-occurring oxide to its re-conversion to oxide for reactor fuels. The papers furnish insights into the chemical, physical, and nuclear properties of uranium hexafluoride as they influence its transport, storage, and the design and operation of plant-scale facilities for production, processing, and conversion to oxide. The papers demonstrate, in an industry often cited for its excellent safety record, continuing efforts to further improve safety in all areas of handling uranium hexafluoride. Selected papers were processed separately for inclusion in the Energy Science and Technology Database.

  1. DEVELOPMENT OF THE BULK TRITIUM SHIPPING PACKAGING

    SciTech Connect

    Blanton, P.; Eberl, K.

    2008-09-14

    A new radioactive shipping packaging for transporting bulk quantities of tritium, the Bulk Tritium Shipping Package (BTSP), has been designed for the Department of Energy (DOE) as a replacement for a package designed in the early 1970s. This paper summarizes significant design features and describes how the design satisfies the regulatory safety requirements of the Code of Federal Regulations and the International Atomic Energy Agency. The BTSP design incorporates many improvements over its predecessor by implementing improved testing, handling, and maintenance capabilities, while improving manufacturability and incorporating new engineered materials. This paper also discusses the results from testing of the BTSP to 10 CFR 71 Normal Conditions of Transport and Hypothetical Accident Condition events. The programmatic need of the Department of Energy (DOE) to ship bulk quantities of tritium has been satisfied since the late 1970s by the UC-609 shipping package. The current Certificate of Conformance for the UC-609, USA/9932/B(U) (DOE), will expire in late 2011. Since the UC-609 was not designed to meet current regulatory requirements, it will not be recertified and thereby necessitates a replacement Type B shipping package for continued DOE tritium shipments in the future. A replacement tritium packaging called the Bulk Tritium Shipping Package (BTSP) is currently being designed and tested by Savannah River National Laboratory (SRNL). The BTSP consists of two primary assemblies, an outer Drum Assembly and an inner Containment Vessel Assembly (CV), both designed to mitigate damage and to protect the tritium contents from leaking during the regulatory Hypothetical Accident Condition (HAC) events and during Normal Conditions of Transport (NCT). During transport, the CV rests on a silicone pad within the Drum Liner and is covered with a thermal insulating disk within the insulated Drum Assembly. The BTSP packaging weighs approximately 500 lbs without contents and is 50

  2. An Analysis of the Terminal Materials Handling Occupation.

    ERIC Educational Resources Information Center

    Mascio, Joseph W.; O'Connor, Patrick J.

    The general purpose of the occupational analysis is to provide workable, basic information dealing with the many and varied duties performed in the terminal materials handling occupation. The document opens with a brief introduction followed by a job description. The bulk of the document is presented in table form. Five duties are broken down into…

  3. Aircraft handling qualities data

    NASA Technical Reports Server (NTRS)

    Heffley, R. K.; Jewell, W. F.

    1972-01-01

    Available information on weight and inertia, aerodynamic derivatives, control characteristics, and stability augmentation systems is documented for 10 representative contemporary airplanes. Data sources are given for each airplane. Flight envelopes are presented and dimensional derivatives, transfer functions for control inputs, and several selected handling qualities parameters have been computed and are tabulated for 10 different flight conditions including the power approach configuration. The airplanes documented are the NT-33A, F-104A, F-4C, X-15, HL-10, Jetstar, CV-880M, B-747, C-5A, and XB-70A.

  4. Universality relationships in condensed matter - Bulk modulus and sound velocity

    NASA Technical Reports Server (NTRS)

    Schlosser, Herbert; Ferrante, John

    1988-01-01

    New forms for the bulk modulus and sound velocity of solids under compression, based on the universal equation of state of Vinet, Ferrante, Smith, and Rose (1987) are presented. These expressions are compared with a number of bulk modulus formulas previously utilized in high-pressure studies. It is demonstrated that this form yields a superior fit to experimental data to very high compressions, for a very wide range of solids. These solids cover the entire range of values of the pressure derivative of the bulk modulus which has been observed in high-pressure measurements.

  5. Students' Strategies for Exception Handling

    ERIC Educational Resources Information Center

    Rashkovits, Rami; Lavy, Ilana

    2011-01-01

    This study discusses and presents various strategies employed by novice programmers concerning exception handling. The main contributions of this paper are as follows: we provide an analysis tool to measure the level of assimilation of exception handling mechanism; we present and analyse strategies to handle exceptions; we present and analyse…

  6. Sectional device handling tool

    DOEpatents

    Candee, Clark B.

    1988-07-12

    Apparatus for remotely handling a device in an irradiated underwater environment includes a plurality of tubular sections interconnected end-to-end to form a handling structure, the bottom section being adapted for connection to the device. A support section is connected to the top tubular section and is adapted to be suspended from an overhead crane. Each section is flanged at its opposite ends. Axially retractable bolts in each bottom flange are threadedly engageable with holes in the top flange of an adjacent section, each bolt being biased to its retracted position and retained in place on the bottom flange. Guide pins on each top flange cooperate with mating holes on adjacent bottom flanges to guide movement of the parts to the proper interconnection orientation. Each section carries two hydraulic line segments provided with quick-connect/disconnect fittings at their opposite ends for connection to the segments of adjacent tubular sections upon interconnection thereof to form control lines which are connectable to the device and to an associated control console.

  7. Handling difficult materials: Household appliances

    SciTech Connect

    Woods, R.

    1994-05-01

    At last count in 1990, the US EPA reported that 2.8 million tons of household appliances (often called ''white goods'') were discarded -- about 2% of the municipal solid waste (MSW) stream. These figures may not seem particularly epic, but, considering the potentially harmful coolants, lubricants, and insulating materials left behind in these machines, the amount may be cause for concern. Management of these items is, of course, not impossible, just difficult. As more and more landfills turn white goods away, recycling is becoming the hot'' option. According to a study by the Steel Recycling Institute, about 4 million of the 8 million units discarded in the US were recycled in 1992. Recycling figures like these are impressive for any secondary material, demonstrating the strides appliance recycling has made in recent years. Implemented in May 1993, EPA's final rule on household appliance handling mandates that 80%--90% of all CFC or HCFC coolants must be recovered with certified equipment by a certified technician, who must record how the refrigerant is removed and where it is sent for recovery.

  8. 75 FR 34573 - Bulk Solid Hazardous Materials: Harmonization With the International Maritime Solid Bulk Cargoes...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-17

    ... FR 3316). D. Public Meeting We do not now plan to hold a public meeting. You may submit a request for... Environmental Protection Agency FR Federal Register HMR Hazardous Materials Regulations, 49 CFR Parts 171-180... transported without special permit from the Coast Guard; the list was last revised in 1984 (49 FR 16794)....

  9. Acoustophoretic contactless transport and handling of matter

    NASA Astrophysics Data System (ADS)

    Foresti, Daniele; Nabavi, Majid; Klingauf, Mirko; Ferrari, Aldo; Poulikakos, Dimos

    2013-11-01

    Levitation and controlled motion of matter in air, has a wealth of potential applications ranging from materials processing to biochemistry and pharmaceuticals. We present a novel acoustophoretic concept, for the contactless transport and handling of matter in air. Spatiotemporal modulation of the levitation acoustic field allows continuous planar transport and processing of multiple objects (volume 0.1-10 μl) . The independence of the handling principle from special material properties (magnetic, optical or electrical) is illustrated with a wide palette of application experiments, such as contactless droplet coalescence and mixing, solid-liquid encapsulation, absorption, dissolution, and DNA transfection. The dynamics of droplets and particles collision is studied numerically and experimentally. The findings show that the secondary acoustic force gives a significant contribution to the samples impact velocity. We thank the Swiss National Science Foundation (Grant 144397) for financial support.

  10. Handling hunger strikers.

    PubMed

    1992-04-01

    Hunger strikes are being used increasingly and not only by those with a political point to make. Whereas in the past, hunger strikes in the United Kingdom seemed mainly to be started by terrorist prisoners for political purposes, the most recent was begun by a Tamil convicted of murder, to protest his innocence. In the later stages of his strike, before calling it off, he was looked after at the Hammersmith Hospital. So it is not only prison doctors who need to know how to handle a hunger strike. The following guidelines, adopted by the 43rd World Medical Assembly in Malta in November 1991, are therefore a timely reminder of the doctor's duties during a hunger strike. PMID:16144144

  11. Coal handling and distribution: An overview

    SciTech Connect

    Lema, J.E.

    1998-12-31

    Reliable, timely and efficient transportation service for distribution of coal from mines and processing plants to power producers, industrial facilities, and port terminals is a key factor in achieving full utilization of US coal in domestic and international markets. Transportation service must meet standards of performance which not only cover the amount of coal traffic to be handled, but also the quality of the service, especially as expressed in units of time, e.g. train arrival times at mines and processing plants, transit times for coal shipments, and cycle times for trains in dedicated coal transportation service. Although the focus of this presentation is handling and distribution of coal, an important commodity produced by the mining industry, what is said will apply likewise to other mined commodities which, similar to coal, often must be transported as heavy bulk freight in large amounts utilizing railroad and marine services. Turning now to handling and distribution of coal, in particular, five major points will be addressed: (1) coal traffic flows have changed significantly since 1980; (2) the railroad network is under severe pressure with regard to the adequacy of transportation service experienced since 1997; (3) a fresh look is needed to determine what steps are needed to ensure adequate railroad service today and in years ahead; (4) the nation`s inland waterways system is a vital component of the bulk freight distribution network that should be upgraded; (5) intermodalism is a hallmark of coal distribution which should be enhanced by focusing on improving short-line and regional railroad/Class 1 railroad, railroad/barge line, truck/railroad, and truck/barge line connectivity and access to coal terminals.

  12. Cascaded second-harmonic generation, summation of the wave vectors of the bulk defect-deformation waves, and generation of multimode micro- and nanostructures by laser irradiation of solids

    SciTech Connect

    Emel'yanov, Vladimir I

    2011-02-28

    We consider for the first time three-wave interactions of bulk quasi-static defect-deformation (DD) waves (generation of the second DD harmonic and summation of the wave vectors), similar to three-wave interactions in nonlinear optics and acoustics, leading to cascaded broadening of the spectrum of spatial DD harmonics. Based on the theory developed, we interpret the recently observed effect of laser-induced generation of the bulk periodic structure of silver nanoparticles with a discrete spatial spectrum, extending from micro- to nanometres. (nonlinear optical phenomena)

  13. Cascaded second-harmonic generation, summation of the wave vectors of the bulk defect-deformation waves, and generation of multimode micro- and nanostructures by laser irradiation of solids

    NASA Astrophysics Data System (ADS)

    Emel'yanov, Vladimir I.

    2011-02-01

    We consider for the first time three-wave interactions of bulk quasi-static defect-deformation (DD) waves (generation of the second DD harmonic and summation of the wave vectors), similar to three-wave interactions in nonlinear optics and acoustics, leading to cascaded broadening of the spectrum of spatial DD harmonics. Based on the theory developed, we interpret the recently observed effect of laser-induced generation of the bulk periodic structure of silver nanoparticles with a discrete spatial spectrum, extending from micro- to nanometres.

  14. Unvented Drum Handling Plan

    SciTech Connect

    MCDONALD, K.M.

    2000-08-01

    This drum-handling plan proposes a method to deal with unvented transuranic drums encountered during retrieval of drums. Finding unvented drums during retrieval activities was expected, as identified in the Transuranic (TRU) Phase I Retrieval Plan (HNF-4781). However, significant numbers of unvented drums were not expected until excavation of buried drums began. This plan represents accelerated planning for management of unvented drums. A plan is proposed that manages unvented drums differently based on three categories. The first category of drums is any that visually appear to be pressurized. These will be vented immediately, using either the Hanford Fire Department Hazardous Materials (Haz. Mat.) team, if such are encountered before the facilities' capabilities are established, or using internal capabilities, once established. To date, no drums have been retrieved that showed signs of pressurization. The second category consists of drums that contain a minimal amount of Pu isotopes. This minimal amount is typically less than 1 gram of Pu, but may be waste-stream dependent. Drums in this category are assayed to determine if they are low-level waste (LLW). LLW drums are typically disposed of without venting. Any unvented drums that assay as TRU will be staged for a future venting campaign, using appropriate safety precautions in their handling. The third category of drums is those for which records show larger amounts of Pu isotopes (typically greater than or equal to 1 gram of Pu). These are assumed to be TRU and are not assayed at this point, but are staged for a future venting campaign. Any of these drums that do not have a visible venting device will be staged awaiting venting, and will be managed under appropriate controls, including covering the drums to protect from direct solar exposure, minimizing of container movement, and placement of a barrier to restrict vehicle access. There are a number of equipment options available to perform the venting. The

  15. REMOTE HANDLING ARRANGEMENTS

    DOEpatents

    Ginns, D.W.

    1958-04-01

    A means for handling remotely a sample pellet to be irradiated in a nuclear reactor is proposed. It is comprised essentially of an inlet tube extending through the outer shield of the reactor and being inclined so that its outer end is at a higher elevation than its inner end, an outlet tube extending through the outer shield being inclined so that its inner end is at a higher elevation than its outer end, the inner ends of these two tubes being interconnected, and a straight tube extending through the outer shield and into the reactor core between the inlet and outlet tubes and passing through the juncture of said inner ends. A rod-like member is rotatably and slidely operated within the central straight tube and has a receptacle on its inner end for receiving a sample pellet from the inlet tube. The rod member is operated to pick up a sample pellet from the inlet tube, carry the sample pellet into the irradiating position within the core, and return to the receiving position where it is rotated to dump the irradiated pellet into the outlet tube by which it is conveyed by gravity to the outside of the reactor. Stop members are provided in the inlet tube, and electrical operating devices are provided to control the sequence of the operation automatically.

  16. IC handling robot

    SciTech Connect

    Law, D.O.

    1986-09-01

    Allied Corporation, Bendix Kansas City Division uses many integrated circuits (ICs) which are 100% tested by receiving inspection prior to installation into the next assemblies. Testing includes functional testing followed by a burn-in cycle then additional functional testing. Before an IC can be functionally tested, it must be inserted into a custom plastic carrier which is placed into a metal magazine that fits the functional tester. The ICs are removed from both tester magazines and carriers prior to being placed into connectors mounted on a printed wiring board for burn-in. Then they are removed from the burn-in board and re-inserted into carriers and magazines for additional functional testing. Each device is handled manually a minimum of 12 times before it is accepted. This project established a robotic workcell which automatically prepares a dual in-line packaged (DIP) integrated circuit for several types of inspection operations performed by Receiving Inspection. Specific activities required to accomplish this goal included definition of the work cell, preparation of the robot and other equipment specifications, installation planning, establishment of programming routines and logic, design of operator safeguards, and development of the work cell concept into an operational unit capable of supporting production.

  17. Waste coal: how to avoid flow stoppages during storage and handling

    SciTech Connect

    Hossfeld, R.J.; Barnum, R.A.

    2007-10-15

    Typically, waste coals are reclaimed from uncovered piles or ponds and transported to a power plant either to sit in another exposed pile or in a large storage silo before being conveyed into feed bunkers to feed the power boilers. The article explains how best to avoid problems related to flow stoppages such as spontaneous combustion when handling gob (bituminous and subbituminous) and culm (anthracite). Common problems are no-flow, due to arching (when an arch-shaped obstruction forms and prevents discharge) and rat-holing (when flow occurs in a channel above the outlet). To achieve mass flow, the sloping hopper walls must be steep enough and sufficiently low in friction for a particle to slide along them and the hopper outlet must be large enough to prevent arching. Equipment is best designed to satisfy flow properties of the particular materials being handled but if the plant is already built, problems can be solved by changing the bulk solid (by minimising moisture, increasing particle size etc.), changing the operating procedures or changing/modifying the equipment (hopper, chute or feeder). 1 ref., 4 figs.

  18. Handling difficult materials: Textiles

    SciTech Connect

    Polk, T.

    1994-07-01

    As recyclable materials, textiles are a potentially valuable addition to community collection programs. They make up a fairly substantial fraction--about 4%--of the residential solid waste stream, a higher figure than corrugated cardboard or magazines. Textiles have well-established processing and marketing infrastructures, with annual sales of over $1 billion in the US And buyers are out there, willing to pay $40 to $100 per ton. There doesn't seem to be any cumbersome government regulations standing in the way, either. So why are so few municipalities and waste haulers currently attempting to recover textiles The answers can be found in the properties of the material itself and a lack of knowledge about the existing textile recycling industry. There are three main end markets that come from waste textiles. In descending order of market share, they are: used clothing, fiber for paper and re-processing, and industrial wiping and polishing cloths.

  19. Fluid handling equipment: A compilation

    NASA Technical Reports Server (NTRS)

    1976-01-01

    Devices and techniques used in fluid-handling and vacuum systems are described. Section 1 presents several articles on fluid lines and tubing. Section 2 describes a number of components such as valves, filters, and regulators. The last section contains descriptions of a number of innovative fluid-handling systems.

  20. Ion conduction in crystalline superionic solids and its applications

    NASA Astrophysics Data System (ADS)

    Chandra, Angesh

    2014-06-01

    Superionic solids an area of multidisciplinary research activity, incorporates to study the physical, chemical and technological aspects of rapid ion movements within the bulk of the special class of ionic materials. It is an emerging area of materials science, as these solids show tremendous technological scopes to develop wide variety of solid state electrochemical devices such as batteries, fuel cells, supercapacitors, sensors, electrochromic displays (ECDs), memories, etc. These devices have wide range of applicabilities viz. power sources for IC microchips to transport vehicles, novel sensors for controlling atmospheric pollution, new kind of memories for computers, smart windows/display panels, etc. The field grew with a rapid pace since then, especially with regards to designing new materials as well as to explore their device potentialities. Amongst the known superionic solids, fast Ag+ ion conducting crystalline solid electrolytes are attracted special attention due to their relatively higher room temperature conductivity as well as ease of materials handling/synthesis. Ion conduction in these electrolytes is very much interesting part of today. In the present review article, the ion conducting phenomenon and some device applications of crystalline/polycrystalline superionic solid electrolytes have been reviewed in brief. Synthesis and characterization tools have also been discussed in the present review article.

  1. Waste Handling Practices for the Plutonium Immobilization Plant

    SciTech Connect

    Severynse, T.F.

    2000-08-04

    Solid waste handling operations refers to all activities associated with the segregation, collection, packaging, assay, storage, and removal of solid radioactive waste from radiological facilities. The Plutonium Immobilization Plant (PIP) is expected to generate the following types of radiological waste, as defined in WSRC Manual 1S, ''Waste Acceptance Criteria'': Low level waste; Mixed hazardous waste; TRU waste; and Mixed TRU waste. Historically, waste handling activities have been demanding proportionately larger amounts of labor, time, and space to effectively manage waste in accordance with increasing regulatory requirements. Since the PIP will be designed for an annual throughput of five metric tonnes plutonium, the facility waste handling operations can be expected to have at least twice the impact of such operations at existing facilities.

  2. Theoretical Insights for Practical Handling of Pressurized Fluids

    ERIC Educational Resources Information Center

    Aranda, Alfonso; Rodriguez, Maria del Prado

    2006-01-01

    The practical scenarios discussed in a chemistry or chemical engineering course that use solid or liquid reactants are presented. Important ideas to be considered when handling pressurized fluids are provided and three typical examples are described to enable students develop secondary skills such as the selective search of data, identification of…

  3. Hydrogels: DNA bulks up

    NASA Astrophysics Data System (ADS)

    Labean, Thom

    2006-10-01

    Since the 1940s DNA has been known as the genetic material connected to heredity, and from the early 1980s it has also been considered as a potential structural material for nanoscale construction. Now, a hydrogel made entirely of DNA brings this molecule into the realm of bulk materials.

  4. Remote handling devices in MLF

    NASA Astrophysics Data System (ADS)

    Kinoshita, Hidetaka; Teshigawara, Makoto; Ito, Manabu; Takagiwa, Katsunori; Meigo, Shinichiro; Maekawa, Fujio; Kaminaga, Masanori; Futakawa, Masatoshi

    2009-02-01

    The experimental facilities at J-PARC (Japan Proton Accelerator Research Complex) include the Materials and Life science Facility (MLF) with a JSNS (Japan Spallation Neutron Source). The main components of the JSNS need to be exchanged because of material damage due to proton and neutron irradiation. The irradiated components must be remotely maintained. Several kinds of areas, such as a hot-cell, are provided for remote handling operations. Several remote handling devices, such as a power manipulator (PM), master-slave manipulators (MSMs), a target exchange truck, a cutting device, a moderator exchange device, etc. have been installed. The commissioning tests for the remote handling devices are almost complete.

  5. HAND TRUCK FOR HANDLING EQUIPMENT

    DOEpatents

    King, D.W.

    1959-02-24

    A truck is described for the handling of large and relatively heavy pieces of equipment and particularly for the handling of ion source units for use in calutrons. The truck includes a chassis and a frame pivoted to the chassis so as to be operable to swing in the manner of a boom. The frame has spaced members so arranged that the device to be handled can be suspended between or passed between these spaced members and also rotated with respect to the frame when the device is secured to the spaced members.

  6. Information Handling is the Problem

    NASA Technical Reports Server (NTRS)

    Malin, Jane T.

    2001-01-01

    This slide presentation reviews the concerns surrounding the automation of information handling. There are two types of decision support software that supports most Space Station Flight Controllers. one is very simple, and the other is very complex. A middle ground is sought. This is the reason for the Human Centered Autonomous and Assistant Systems Testbed (HCAAST) Project. The aim is to study flight controllers at work, and in the bigger picture, with particular attention to how they handle information and how coordination of multiple teams is performed. The focus of the project is on intelligent assistants to assist in handling information for the flight controllers.

  7. Municipal solid wastes and their disposal.

    PubMed Central

    Stone, R

    1978-01-01

    A brief overview is given of the sources, characteristics, and toxic constituents of municipal solid wastes. Several methods are presented for handling, treating, and disposal of solid wastes. Monitoring the landfill site is necessary; there has been a trend to recognize that municipal solid wastes may be hazardous and to provide separate secure handling, treatment, and disposal for their dangerous constituents. Under current state and Federal regulations, permits are being required to assure that proper handling of conventional solid wastes and more hazardous constituents are carefully managed. PMID:738240

  8. Ergonomic material-handling device

    DOEpatents

    Barsnick, Lance E.; Zalk, David M.; Perry, Catherine M.; Biggs, Terry; Tageson, Robert E.

    2004-08-24

    A hand-held ergonomic material-handling device capable of moving heavy objects, such as large waste containers and other large objects requiring mechanical assistance. The ergonomic material-handling device can be used with neutral postures of the back, shoulders, wrists and knees, thereby reducing potential injury to the user. The device involves two key features: 1) gives the user the ability to adjust the height of the handles of the device to ergonomically fit the needs of the user's back, wrists and shoulders; and 2) has a rounded handlebar shape, as well as the size and configuration of the handles which keep the user's wrists in a neutral posture during manipulation of the device.

  9. Tritium handling in vacuum systems

    SciTech Connect

    Gill, J.T.; Coffin, D.O.

    1986-10-01

    This report provides a course in Tritium handling in vacuum systems. Topics presented are: Properties of Tritium; Tritium compatibility of materials; Tritium-compatible vacuum equipment; and Tritium waste treatment.

  10. Solid rocket motors

    NASA Technical Reports Server (NTRS)

    Carpenter, Ronn L.

    1993-01-01

    Structural requirements, materials and, especially, processing are critical issues that will pace the introduction of new types of solid rocket motors. Designers must recognize and understand the drivers associated with each of the following considerations: (1) cost; (2) energy density; (3) long term storage with use on demand; (4) reliability; (5) safety of processing and handling; (6) operability; and (7) environmental acceptance.

  11. Technologies and logistics for handling, transport and distribution of animal manures

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Organizing and managing the whole manure handling chain from the animal house through transport to the point of use (e.g. in the field) is a challenging task requiring consideration of manure type and operating conditions. Solid and liquid manure must be handled differently, using very different tec...

  12. Bulk Email Forensics

    NASA Astrophysics Data System (ADS)

    Cohen, Fred

    Legal matters related to unsolicited commercial email often involve several hundred thousand messages. Manual examination and interpretation methods are unable to deal with such large volumes of evidence. Furthermore, as the actors gain experience, it is increasingly difficult to show evidence of spoliation and detect intentional evidence construction. This paper presents improved automated techniques for bulk email analysis and presentation to aid in evidence interpretation.

  13. Thermal dryer dewaters solids

    SciTech Connect

    DiMascio, F.J.; Burrowes, P.A.

    1993-09-01

    Solids incineration is traditionally an energy-intensive solids handling process at wastewater treatment plants. To reduce energy costs, the Buffalo (N.Y.) Sewer Authority has added an indirect thermal dryer to its treatment plant to dewater solids before incineration. In the first 3 months of operation, the authority reduced its solids inventory from 634,400 to 227,300 kg. Solids processed in the plant`s multiple-hearth incinerators varied from 11 to 12.75 wet Mg/hr at feed concentrations averaging 21% total solids. And, the dryer was operated with less than 5% downtime. The cost of this indirect thermal dryer system, including construction and equipment, was $995,000. 1 fig., 2 tabs.

  14. 7 CFR 58.443 - Whey handling.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Procedures § 58.443 Whey handling. (a) Adequate sanitary facilities shall be provided for the handling of... sanitary manner in accordance with the procedures of this subpart as specified for handling milk and...

  15. 7 CFR 58.443 - Whey handling.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... Procedures § 58.443 Whey handling. (a) Adequate sanitary facilities shall be provided for the handling of... sanitary manner in accordance with the procedures of this subpart as specified for handling milk and...

  16. U.S. Department of Energy, National Energy Technology Laboratory Solid-State Lighting Core Technologies Light Emitting Diodes on Semipolar Bulk GaN Substrate with IQE > 80% at 150 A/cm2 and 100 0C

    SciTech Connect

    Chakraborty, Arpan; David, Aurelien; Grundmann, Michael; Tyagi, Anurag; Craven, Michael; Hurni, Christophe; Cich, Michael

    2015-03-31

    GaN is a crucial material for light-emitting diodes (LEDs) emitting in the violet-to-green range. Despite its good performance, it still suffers from significant technical limitations. In particular, the efficiency of GaN-based LEDs decreases at high current (“current droop”) and high temperature (“temperature droop”). This is problematic in some lighting applications, where a high-power operation is required. This program studied the use of particular substrates to improve the efficiency of GaN-based LEDs: bulk semipolar (SP) GaN substrates. These substrates possess a very high material quality, and physical properties which are distinctly different from legacy substrates currently used in the LED industry. The program focused on the development of accurate metrology to quantify the performance of GaN-based LEDs, and on improvement to LED quality and design on SP substrates. Through a thorough optimization process, we demonstrated violet LEDs with very high internal quantum efficiency, exceeding 85% at high temperature and high current. We also investigated longer-wavelength blue emitters, but found that the limited strain budget was a key limitation.

  17. Safe handling of large animals.

    PubMed

    Grandin, T

    1999-01-01

    The major causes of accidents with cattle, horses, and other grazing animals are: panic due to fear, male dominance aggression, or the maternal aggression of a mother protecting her newborn. Danger is inherent when handling large animals. Understanding their behavior patterns improves safety, but working with animals will never be completely safe. Calm, quiet handling and non-slip flooring are beneficial. Rough handling and excessive use of electric prods increase chances of injury to both people and animals, because fearful animals may jump, kick, or rear. Training animals to voluntarily cooperate with veterinary procedures reduces stress and improves safety. Grazing animals have a herd instinct, and a lone, isolated animal can become agitated. Providing a companion animal helps keep an animal calm. PMID:10329901

  18. Bulk-barrier transistor

    NASA Astrophysics Data System (ADS)

    Mader, H.; Mueller, R.; Beinvogl, W.

    1983-10-01

    Experimental and theoretical results are presented on a bulk-barrier transistor (BBT). In this device the charge-carrier transportation is determined by an energy barrier, which is located inside a semiconductor. The barrier is the result of a space-charge region in a three-layered n-p-n or p-n-p structure with a very thin middle layer. The height of the energy barrier, which is adjustable by technological parameters, can be controlled by an external voltage.

  19. Euclid Data Handling Design Solutions

    NASA Astrophysics Data System (ADS)

    Bogiatto, Roberto; Tramutola, Antonio; Maddaleno, Corrado; Maiorano, Elena; Colombo, Cyril

    2014-08-01

    Euclid is the next medium-class mission of ESA's Science Programme, to be launched by 2020. The objective of Euclid is to investigate dark energy and dark matter, essential but mysterious components of today's standard model of cosmology. The complete survey will comprise hundreds of thousands of images and several tens of Petabytes of data. The significant amount of scientific data to be stored on-board and transmitted to Ground, imposes some challenging spacecraft requirements leading to innovative design solutions for the data handling and on-board communications. After the mission presentation, the paper provides an overview of the Spacecraft avionics architecture and deepens the Euclid data handling design concept.

  20. Compositional ordering and stability in nanostructured, bulk thermoelectric alloys.

    SciTech Connect

    Hekmaty, Michelle A.; Faleev, S.; Medlin, Douglas L.; Leonard, F.; Lensch-Falk, J.; Sharma, Peter Anand; Sugar, J. D.

    2009-09-01

    Thermoelectric materials have many applications in the conversion of thermal energy to electrical power and in solid-state cooling. One route to improving thermoelectric energy conversion efficiency in bulk material is to embed nanoscale inclusions. This report summarize key results from a recently completed LDRD project exploring the science underpinning the formation and stability of nanostructures in bulk thermoelectric and the quantitative relationships between such structures and thermoelectric properties.

  1. 49 CFR 174.82 - General requirements for the handling of placarded rail cars, transport vehicles, freight...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... rail cars, transport vehicles, freight containers, and bulk packages. 174.82 Section 174.82... Placarded Rail Cars, Transport Vehicles and Freight Containers § 174.82 General requirements for the handling of placarded rail cars, transport vehicles, freight containers, and bulk packages. (a)...

  2. 46 CFR 153.1102 - Handling and disposal of NLS residue: Cateqories A, B, C, and D.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Handling and disposal of NLS residue: Cateqories A, B, C, and D. 153.1102 Section 153.1102 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Approval of Surveyors...

  3. 46 CFR 153.1102 - Handling and disposal of NLS residue: Categories A, B, C, and D.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Handling and disposal of NLS residue: Categories A, B, C, and D. 153.1102 Section 153.1102 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Operations Approval of Surveyors...

  4. Assessment of bioburden encapsulated in bulk materials

    NASA Astrophysics Data System (ADS)

    Schubert, Wayne W.; Newlin, Laura; Chung, Shirley Y.; Ellyin, Raymond

    2016-05-01

    The National Aeronautics and Space Administration (NASA) imposes bioburden limitations on all spacecraft destined for solar system bodies that might harbor evidence of extant or extinct life. The subset of microorganisms trapped within solid materials during manufacture and assembly is referred to as encapsulated bioburden. In the absence of spacecraft-specific data, NASA relies on specification values to estimate total spacecraft encapsulated bioburden, typically 30 endospores/cm3 or 300 viable cells/cm3 in non-electronic materials. Specification values for endospores have been established conservatively, and represent no less than an order of magnitude greater abundance than that derived from empirical assessments of actual spacecraft materials. The goal of this study was to generate data germane to determining whether revised bulk encapsulated material values (lower than those estimated by historical specifications) tailored specifically to the materials designated in modern-day spacecraft design could be used, on a case-by-case basis, to comply with planetary protection requirements. Organic materials having distinctly different chemical properties and configurations were selected. This required more than one experimental and analytical approach. Filtration was employed for liquid electrolytes, lubricants were suspended in an aqueous solution and solids (wire and epoxy sealant) were cryogenically milled. The final data characteristic for all bioburden estimates was microbial colony formation in rich agar growth medium. To assess survival potential, three non-spore-forming bacterial cell lines were systematically encapsulated in an epoxy matrix, liberated via cryogenic grinding, and cultured. Results suggest that bulk solid materials harbor significantly fewer encapsulated microorganisms than are estimated by specification values. Lithium-ion battery electrolyte reagents housed fewer than 1 CFU/cm3. Results also demonstrated that non-spore-forming microorganisms

  5. Expert Systems and Document Handling.

    ERIC Educational Resources Information Center

    Edmonds, Ernest

    1987-01-01

    Describes significant attributes of expert systems, contrasts them to conventional computer systems, and provides an overview of the R1 expert system used by Digital Equipment Corporation (DEC) to put together operational systems that meet customers' requirements. Document handling, particularly pictures and images in documents, is also briefly…

  6. [Hygienic handling in cardiac surgery].

    PubMed

    Shimasaki, T; Masaoka, T; Hirooka, S; Abe, H; Watanabe, T; Washio, M

    1993-04-01

    Some points regarding the hygienic handling in cardiac surgery are mentioned. The sternal infection or mediastinitis is still one of the most important complications after cardiac operation especially when ITA is used for CABG. After we paid much attention to these points, the postoperative sternal infection has decreased obviously. PMID:8468855

  7. Non-contact handling device

    DOEpatents

    Reece, Mark; Knorovsky, Gerald A.; MacCallum, Danny O.

    2007-05-15

    A pressurized fluid handling nozzle has a body with a first end and a second end, a fluid conduit and a recess at the second end. The first end is configured for connection to a pressurized fluid source. The fluid conduit has an inlet at the first end and an outlet at the recess. The nozzle uses the Bernoulli effect for lifting a part.

  8. Portable vacuum object handling device

    DOEpatents

    Anderson, Gordon H.

    1983-08-09

    The disclosure relates to a portable device adapted to handle objects which are not to be touched by hand. A piston and bore wall form a vacuum chamber communicating with an adaptor sealably engageable with an object to be lifted. The piston is manually moved and set to establish vacuum. A valve is manually actuatable to apply the vacuum to lift the object.

  9. Foamed Bulk Metallic Glass (Foam) Investigation

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This soldering iron has an evacuated copper capsule at the tip that contains a pellet of Bulk Metallic Glass (BMG) aboard the International Space Station (ISS). Prior to flight, researchers sealed a pellet of bulk metallic glass mixed with microscopic gas-generating particles into the copper ampoule under vacuum. Once heated in space, such as in this photograph, the particles generated gas and the BMG becomes a viscous liquid. The released gas made the sample foam within the capsule where each microscopic particle formed a gas-filled pore within the foam. The inset image shows the oxidation of the sample after several minutes of applying heat. Although hidden within the brass sleeve, the sample retained the foam shape when cooled, because the viscosity increased during cooling until it was solid.

  10. Bulk amorphous materials

    SciTech Connect

    Schwarz, R.B.; Archuleta, J.I.; Sickafus, K.E.

    1998-12-01

    This is the final report for a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this work was to develop the competency for the synthesis of novel bulk amorphous alloys. The authors researched their synthesis methods and alloy properties, including thermal stability, mechanical, and transport properties. The project also addressed the development of vanadium-spinel alloys for structural applications in hostile environments, the measurement of elastic constants and thermal expansion in single-crystal TiAl from 300 to 750 K, the measurement of elastic constants in gallium nitride, and a study of the shock-induced martensitic transformations in NiTi alloys.

  11. Bulk muscles, loose cables.

    PubMed

    Liyanage, Chamari R D G; Kodali, Venkata

    2014-01-01

    The accessibility and usage of body building supplements is on the rise with stronger internet marketing strategies by the industry. The dangers posed by the ingredients in them are underestimated. A healthy young man came to the emergency room with palpitations and feeling unwell. Initial history and clinical examination were non-contributory to find the cause. ECG showed atrial fibrillation. A detailed history for any over the counter or herbal medicine use confirmed that he was taking supplements to bulk muscle. One of the components in these supplements is yohimbine; the onset of symptoms coincided with the ingestion of this product and the patient is symptom free after stopping it. This report highlights the dangers to the public of consuming over the counter products with unknown ingredients and the consequential detrimental impact on health. PMID:25326558

  12. Creating bulk nanocrystalline metal.

    SciTech Connect

    Fredenburg, D. Anthony; Saldana, Christopher J.; Gill, David D.; Hall, Aaron Christopher; Roemer, Timothy John; Vogler, Tracy John; Yang, Pin

    2008-10-01

    Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties across the feature.

  13. Explosive bulk charge

    DOEpatents

    Miller, Jacob Lee

    2015-04-21

    An explosive bulk charge, including: a first contact surface configured to be selectively disposed substantially adjacent to a structure or material; a second end surface configured to selectively receive a detonator; and a curvilinear side surface joining the first contact surface and the second end surface. The first contact surface, the second end surface, and the curvilinear side surface form a bi-truncated hemispherical structure. The first contact surface, the second end surface, and the curvilinear side surface are formed from an explosive material. Optionally, the first contact surface and the second end surface each have a substantially circular shape. Optionally, the first contact surface and the second end surface consist of planar structures that are aligned substantially parallel or slightly tilted with respect to one another. The curvilinear side surface has one of a smooth curved geometry, an elliptical geometry, and a parabolic geometry.

  14. SITE GENERATED RADIOLOGICAL WASTE HANDLING SYSTEM DESCRIPTION DOCUMENT

    SciTech Connect

    S. C. Khamankar

    2000-06-20

    The Site Generated Radiological Waste Handling System handles radioactive waste products that are generated at the geologic repository operations area. The waste is collected, treated if required, packaged for shipment, and shipped to a disposal site. Waste streams include low-level waste (LLW) in solid and liquid forms, as-well-as mixed waste that contains hazardous and radioactive constituents. Liquid LLW is segregated into two streams, non-recyclable and recyclable. The non-recyclable stream may contain detergents or other non-hazardous cleaning agents and is packaged for shipment. The recyclable stream is treated to recycle a large portion of the water while the remaining concentrated waste is packaged for shipment; this greatly reduces the volume of waste requiring disposal. There will be no liquid LLW discharge. Solid LLW consists of wet solids such as ion exchange resins and filter cartridges, as-well-as dry active waste such as tools, protective clothing, and poly bags. Solids will be sorted, volume reduced, and packaged for shipment. The generation of mixed waste at the Monitored Geologic Repository (MGR) is not planned; however, if it does come into existence, it will be collected and packaged for disposal at its point of occurrence, temporarily staged, then shipped to government-approved off-site facilities for disposal. The Site Generated Radiological Waste Handling System has equipment located in both the Waste Treatment Building (WTB) and in the Waste Handling Building (WHB). All types of liquid and solid LLW are processed in the WTB, while wet solid waste from the Pool Water Treatment and Cooling System is packaged where received in the WHB. There is no installed hardware for mixed waste. The Site Generated Radiological Waste Handling System receives waste from locations where water is used for decontamination functions. In most cases the water is piped back to the WTB for processing. The WTB and WHB provide staging areas for storing and shipping LLW

  15. New weight-handling device for commercial oil pressure balances

    NASA Astrophysics Data System (ADS)

    Woo, S. Y.; Choi, I. M.; Kim, B. S.

    2005-12-01

    This paper presents a new device to automatically handle a large number of weights for the calibration of a pressure gauge. This newly invented weight-handling device is made for use in conjunction with a commercial oil pressure balance. Although the pressure balance is essential as a calibration tool, its use has been generally tedious and labour intensive for a long time. In particular, the process of loading a different combination of weights on the top of a piston requires repetitious manual handling for every new measurement. This inevitably leaves the operator fatigued, and sometimes causes damage to the weights due to careless handling. The newly invented automatic weight-handling device can eliminate such tedious, error-prone and wear-inducing manual weight manipulation. The device consists of a stepping motor, a drive belt, a solenoid valve, three weight-lifting assemblies and three linear-motion guide assemblies. The weight-lifting assembly is composed of a pneumatic actuator, a solid-state switch and a metal finger. It has many advantages compared with the commercial automatic weight-handling device. Firstly, it is not necessary to lift all the weights off the piston in the weight selection process, as it is in the case of the commercial device. Thus it can prevent a permanent deformation of the weight carrier. Secondly, this new device can handle a larger number of weights than the commercial one. This is because the new device adopts a different method in retaining the remaining weights in place. Another advantage of this new device is that there is no possibility of the fingers touching the surface of the weights due to the oscillation of weights. Moreover it uses the general technology of a stepping motor, and is also made up of components that are easily obtainable in the market, thereby being very economical.

  16. Observing the interplay between surface and bulk optical nonlinearities in thin van der Waals crystals

    PubMed Central

    Deckoff-Jones, Skylar; Zhang, Jingjing; Petoukhoff, Christopher E.; Man, Michael K.L.; Lei, Sidong; Vajtai, Robert; Ajayan, Pulickel M.; Talbayev, Diyar; Madéo, Julien; Dani, Keshav M.

    2016-01-01

    Van der Waals materials, existing in a range of thicknesses from monolayer to bulk, allow for interplay between surface and bulk nonlinearities, which otherwise dominate only at atomically-thin or bulk extremes, respectively. Here, we observe an unexpected peak in intensity of the generated second harmonic signal versus the thickness of Indium Selenide crystals, in contrast to the quadratic increase expected from thin crystals. We explain this by interference effects between surface and bulk nonlinearities, which offer a new handle on engineering the nonlinear optical response of 2D materials and their heterostructures. PMID:26936437

  17. Observing the interplay between surface and bulk optical nonlinearities in thin van der Waals crystals

    NASA Astrophysics Data System (ADS)

    Deckoff-Jones, Skylar; Zhang, Jingjing; Petoukhoff, Christopher E.; Man, Michael K. L.; Lei, Sidong; Vajtai, Robert; Ajayan, Pulickel M.; Talbayev, Diyar; Madéo, Julien; Dani, Keshav M.

    2016-03-01

    Van der Waals materials, existing in a range of thicknesses from monolayer to bulk, allow for interplay between surface and bulk nonlinearities, which otherwise dominate only at atomically-thin or bulk extremes, respectively. Here, we observe an unexpected peak in intensity of the generated second harmonic signal versus the thickness of Indium Selenide crystals, in contrast to the quadratic increase expected from thin crystals. We explain this by interference effects between surface and bulk nonlinearities, which offer a new handle on engineering the nonlinear optical response of 2D materials and their heterostructures.

  18. Observing the interplay between surface and bulk optical nonlinearities in thin van der Waals crystals.

    PubMed

    Deckoff-Jones, Skylar; Zhang, Jingjing; Petoukhoff, Christopher E; Man, Michael K L; Lei, Sidong; Vajtai, Robert; Ajayan, Pulickel M; Talbayev, Diyar; Madéo, Julien; Dani, Keshav M

    2016-01-01

    Van der Waals materials, existing in a range of thicknesses from monolayer to bulk, allow for interplay between surface and bulk nonlinearities, which otherwise dominate only at atomically-thin or bulk extremes, respectively. Here, we observe an unexpected peak in intensity of the generated second harmonic signal versus the thickness of Indium Selenide crystals, in contrast to the quadratic increase expected from thin crystals. We explain this by interference effects between surface and bulk nonlinearities, which offer a new handle on engineering the nonlinear optical response of 2D materials and their heterostructures. PMID:26936437

  19. Portable vacuum object handling device

    DOEpatents

    Anderson, G.H.

    1983-08-09

    The disclosure relates to a portable device adapted to handle objects which are not to be touched by hand. A piston and bore wall form a vacuum chamber communicating with an adaptor sealably engageable with an object to be lifted. The piston is manually moved and set to establish vacuum. A valve is manually actuatable to apply the vacuum to lift the object. 1 fig.

  20. Comparing coal handling system costs

    SciTech Connect

    Lehto, J.M.

    1996-03-01

    Good maintenance practices and proactive planning are essential to ensure coal handling equipment performance, but a look at the entire cost of handling coal has yielded some surprising conclusions. Optimizing a given system can be challenging and requires a close analysis of the total cost. This article addresses the cost analysis of the coal handling system at the Northern States Power Co. (NSP) Sherburne County Plant (Sherco); the largest coal-fired plant in Minnesota. Sherco consists of two Combustion Engineering 750-MW tangentially fired boilers and one 850-MW Babcock and Wilcox wall-fired unit. The two 750-MW units are fitted with wet limestone scrubbers to control both particulates and sulfur. The 850-MW unit, on the other hand, is connected to a Joy Niro dry scrubber and baghouse. All of the coal consumed by Sherco is sub-bituminous Powder River Basin Coal from Montana and Wyoming. The coal is purchased from half a dozen mines including Westmoreland, Colestrip, Black Thunder, Antelope and Rochelle. Although quite similar in heating value and moisture content, these coals differ markedly in ash content, sulfur content, dustiness and spontaneous heating characteristics.

  1. Orion Entry Handling Qualities Assessments

    NASA Technical Reports Server (NTRS)

    Bihari, B.; Tiggers, M.; Strahan, A.; Gonzalez, R.; Sullivan, K.; Stephens, J. P.; Hart, J.; Law, H., III; Bilimoria, K.; Bailey, R.

    2011-01-01

    The Orion Command Module (CM) is a capsule designed to bring crew back from the International Space Station (ISS), the moon and beyond. The atmospheric entry portion of the flight is deigned to be flown in autopilot mode for nominal situations. However, there exists the possibility for the crew to take over manual control in off-nominal situations. In these instances, the spacecraft must meet specific handling qualities criteria. To address these criteria two separate assessments of the Orion CM s entry Handling Qualities (HQ) were conducted at NASA s Johnson Space Center (JSC) using the Cooper-Harper scale (Cooper & Harper, 1969). These assessments were conducted in the summers of 2008 and 2010 using the Advanced NASA Technology Architecture for Exploration Studies (ANTARES) six degree of freedom, high fidelity Guidance, Navigation, and Control (GN&C) simulation. This paper will address the specifics of the handling qualities criteria, the vehicle configuration, the scenarios flown, the simulation background and setup, crew interfaces and displays, piloting techniques, ratings and crew comments, pre- and post-fight briefings, lessons learned and changes made to improve the overall system performance. The data collection tools, methods, data reduction and output reports will also be discussed. The objective of the 2008 entry HQ assessment was to evaluate the handling qualities of the CM during a lunar skip return. A lunar skip entry case was selected because it was considered the most demanding of all bank control scenarios. Even though skip entry is not planned to be flown manually, it was hypothesized that if a pilot could fly the harder skip entry case, then they could also fly a simpler loads managed or ballistic (constant bank rate command) entry scenario. In addition, with the evaluation set-up of multiple tasks within the entry case, handling qualities ratings collected in the evaluation could be used to assess other scenarios such as the constant bank angle

  2. Phobos: Observed bulk properties

    NASA Astrophysics Data System (ADS)

    Pätzold, Martin; Andert, Tom; Jacobson, Robert; Rosenblatt, Pascal; Dehant, Véronique

    2014-11-01

    This work is a review of the mass determinations of the Mars moon Phobos by spacecraft close flybys, by solving for the Martian gravity field and by the analysis of secular orbit perturbations. The absolute value and accuracy is sensitive on the knowledge and accuracy of the Phobos ephemeris, of the spacecraft orbit, other perturbing forces acting on the spacecraft and the resolution of the Martian gravity field besides the measurement accuracy of the radio tracking data. The mass value and its error improved from spacecraft mission to mission or from the modern analysis of “old” tracking data but these solutions depend on the accuracy of the ephemeris at the time of observation. The mass value seems to settle within the range of GMPh=(7.11±0.09)×10-4 km3 s-2 which covers almost all mass values from close flybys and “distant” encounters within its 3-σ error (1.5%). Using the volume value determined from MEX HRSC imaging, the bulk density is (1873±31) kg m-3 (3-σ error or 1.7%), a low value which suggests that Phobos is either highly porous, is composed partially of light material or both. The determination of the gravity coefficients C20 and C22 from the Mars Express 2010 close flyby does not allow to draw conclusion on the internal structure. The large errors do not distinguish whether Phobos is homogeneous or not. In view of theories of the Phobos' origin, one possibility is that Phobos is not a captured asteroid but accreted from a debris disk in Mars orbit as a second generation solar system object.

  3. Perovskite oxides: Oxygen electrocatalysis and bulk structure

    NASA Technical Reports Server (NTRS)

    Carbonio, R. E.; Fierro, C.; Tryk, D.; Scherson, D.; Yeager, Ernest

    1987-01-01

    Perovskite type oxides were considered for use as oxygen reduction and generation electrocatalysts in alkaline electrolytes. Perovskite stability and electrocatalytic activity are studied along with possible relationships of the latter with the bulk solid state properties. A series of compounds of the type LaFe(x)Ni1(-x)O3 was used as a model system to gain information on the possible relationships between surface catalytic activity and bulk structure. Hydrogen peroxide decomposition rate constants were measured for these compounds. Ex situ Mossbauer effect spectroscopy (MES), and magnetic susceptibility measurements were used to study the solid state properties. X ray photoelectron spectroscopy (XPS) was used to examine the surface. MES has indicated the presence of a paramagnetic to magnetically ordered phase transition for values of x between 0.4 and 0.5. A correlation was found between the values of the MES isomer shift and the catalytic activity for peroxide decomposition. Thus, the catalytic activity can be correlated to the d-electron density for the transition metal cations.

  4. Porous silicon bulk acoustic wave resonator with integrated transducer

    PubMed Central

    2012-01-01

    We report that porous silicon acoustic Bragg reflectors and AlN-based transducers can be successfully combined and processed in a commercial solidly mounted resonator production line. The resulting device takes advantage of the unique acoustic properties of porous silicon in order to form a monolithically integrated bulk acoustic wave resonator. PMID:22776697

  5. 7 CFR 1205.312 - Handle.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... AND ORDERS; MISCELLANEOUS COMMODITIES), DEPARTMENT OF AGRICULTURE COTTON RESEARCH AND PROMOTION Cotton Research and Promotion Order Definitions § 1205.312 Handle. Handle means to harvest, gin, warehouse, compress, purchase, market, transport, or otherwise acquire ownership or control of cotton....

  6. 7 CFR 1205.312 - Handle.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... AND ORDERS; MISCELLANEOUS COMMODITIES), DEPARTMENT OF AGRICULTURE COTTON RESEARCH AND PROMOTION Cotton Research and Promotion Order Definitions § 1205.312 Handle. Handle means to harvest, gin, warehouse, compress, purchase, market, transport, or otherwise acquire ownership or control of cotton....

  7. Fertilizer use by class: Bag, bulk, fluid

    SciTech Connect

    Hargett, N.L.; Berry, J.T.; McKinney, S.L.

    1989-01-01

    US fertilizer consumption (excluding natural organic, secondary, and micronutrient materials) increased slightly from 42.7 million tons in 1987--1988 to 42.8 million tons in 1988--1989-a gain of less than one percent. In 1988--1989, dry bulk materials represented 52.1 percent of total consumption, fluid fertilizers accounted for 38.9 percent, and bagged materials the remaining 9.0 percent. Both dry and fluid fertilizers increased in tonnage over last year but market shares of each remained essentially the same. Bagged fertilizer continued to drop in tonnage as well as in market share. Fluid fertilizer use (including anhydrous ammonia) exceeded 16.6 million tons. Solid materials accounted for 26.2 million tons. TVA estimates that total dry bulk fertilizer distribution was 22.3 million tons, representing 85 percent of all solid materials. Estimated fertilizer sales of bagged products was 3.9 million tons compared to 4.1 million tons in 1987--1988. Multiple-nutrient fertilizer consumption was 17.5 million tons in 1988--1989. Class distribution of these materials was 60.1 percent dry bulk form, 22.4 percent fluid, and 17.5 percent bagged. Fluid multiple-nutrient materials consumption remained about the same as for 1987--1988 but increased in total market share from 9.1 percent to 9.2 percent. This report is compiled annually from individual State fertilizer tonnage reports. Forty States provided complete breakdown by class in 1988-1989. Only numerical data is included.

  8. Zero g manual cargo handling

    NASA Technical Reports Server (NTRS)

    Spady, A. A., Jr.; Beasley, G. P.

    1972-01-01

    A series of studies were conducted utilizing a water-immersion simulator facility to better define the cargo that can realistically be handled by man. The initial phase of the program was a parametric study to define man's intravehicular (IV) cargo transfer capabilities, and its results are reported. Additional phases of the study, deal with: (1) man's ability to perform extravehicular (EV) cargo transfer, (2) the ability to transfer cargo through a 1.5 m (5-foot) diameter tunnel (IV), and (3) the utilization of electroadhesive/electromagnetic mobility aids for both IV and EV self-locomotion and cargo transfer.

  9. 7 CFR 985.8 - Handle.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Definitions § 985.8 Handle. Handle means to prepare oil for market, acquire oil from a producer, use oil commercially of own production, or sell, transport, or ship (except as a common or contract carrier of oil owned by another), or otherwise place...

  10. 7 CFR 985.8 - Handle.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Definitions § 985.8 Handle. Handle means to prepare oil for market, acquire oil from a producer, use oil commercially of own production, or sell, transport, or ship (except as a common or contract carrier of oil owned by another), or otherwise place...