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Sample records for c-o vibrational frequencies

  1. Theoretical Study of the Electrostatic and Steric Effects on the Spectroscopic Characteristics of the Metal-Ligand Unit of Heme Proteins. 2. C-O Vibrational Frequencies, 17O Isotropic Chemical Shifts, and Nuclear Quadrupole Coupling Constants

    PubMed Central

    Kushkuley, Boris; Stavrov, Solomon S.

    1997-01-01

    The quantum chemical calculations, vibronic theory of activation, and London-Pople approach are used to study the dependence of the C-O vibrational frequency, 17O isotropic chemical shift, and nuclear quadrupole coupling constant on the distortion of the porphyrin ring and geometry of the CO coordination, changes in the iron-carbon and iron-imidazole distances, magnitude of the iron displacement out of the porphyrin plane, and presence of the charged groups in the heme environment. It is shown that only the electrostatic interactions can cause the variation of all these parameters experimentally observed in different heme proteins, and the heme distortions could modulate this variation. The correlations between the theoretically calculated parameters are shown to be close to the experimentally observed ones. The study of the effect of the electric field of the distal histidine shows that the presence of the four C-O vibrational bands in the infrared absorption spectra of the carbon monoxide complexes of different myoglobins and hemoglobins can be caused by the different orientations of the different tautomeric forms of the distal histidine. The dependence of the 17O isotropic chemical shift and nuclear quadrupole coupling constant on pH and the distal histidine substitution can be also explained from the same point of view. PMID:9017215

  2. Mobile high frequency vibrator system

    SciTech Connect

    Fair, D.W.; Buller, P.L.

    1985-01-08

    A carrier mounted seismic vibrator system that is primarily adapted for generation of high force, high frequency seismic energy into an earth medium. The apparatus includes first and second vibrators as supported by first and second lift systems disposed in tandem juxtaposition generally centrally in said vehicle, and the lift systems are designed to maintain equal hold-down force on the vibrator coupling baseplates without exceeding the weight of the carrier vehicle. The juxtaposed vibrators are then energized in synchronized relationship to propagate increased amounts of higher frequency seismic energy into an earth medium.

  3. Distal and proximal ligand interactions in heme proteins: Correlations between C-O and Fe-C vibrational frequencies, oxygen-17 and carbon-13 nuclear magnetic resonance chemical shifts, and oxygen-17 nuclear quadrupole coupling constants in C sup 17 O- and sup 13 CO-labeled species

    SciTech Connect

    Ki Deok Park; Guo, K.; Adebodun, F.; Chiu, M.L.; Sligar, S.G.; Oldfield, E. )

    1991-03-05

    The authors have obtained the oxygen-17 nuclear magnetic resonance (NMR) spectra of a variety of C{sup 17}O-labeled heme proteins, including sperm whale (Physeter catodon) myoglobin, two synthetic sperm whale myoglobin mutants (His E7 {yields} Val E7; His E7 {yields} Phe E7), adult human hemoglobin, rabbit (Oryctolagus cuniculus) hemoglobin, horseradish (Cochlearia armoracia) peroxidase isoenzymes A and C, and Caldariomyces fumago chloroperoxidase, in some cases as a function of pH, and have determined their isotropic {sup 17}O NMR chemical shifts, {delta}{sub i}, and spin-lattice relaxation times, T{sub 1}. They have also obtained similar results on a picket fence prophyrin. The results show an excellent correlation between the infrared C-O vibrational frequencies, {nu}(C-O), and {delta}{sub i}, between {nu}(C-O) and the {sup 17}O nuclear quadrupole coupling constant, and as expected between e{sup 2}qQ/h and {delta}{sub i}. The results suggest the IR and NMR measurements reflect the same interaction, which is thought to be primarily the degree of {pi}-back-bonding from Fe d to CO {pi}* orbitals, as outlined previously.

  4. Modulational instabilities in acetanilide taking into account both the N H and the C=O vibrational self-trappings

    NASA Astrophysics Data System (ADS)

    Simo, Elie

    2007-02-01

    A model of crystalline acetanilide, ACN accounting for the C=O and N-H vibrational self-trappings is presented. We develop a fully discrete version of ACN. We show that ACN can be described by a set of two coupled discrete nonlinear Schrödinger (DNLS) equations. Modulational instabilities (MI) are studied both theoretically and numerically. Dispersion laws for the wavenumbers and frequencies of the linear modulation waves are determined. We also derived the criterion for the existence of MI. Numerical simulations are carried out for a variety of selected wave amplitudes in the unstable zone. It is shown that instabilities grow as the wavenumbers and amplitudes of the modulated waves increase. MI grow faster in the N-H mode than in the C=O mode. Temporal evolution of the density probabilities of the vibrational excitons are obtained by the numerical integration of the coupled DNLS equations governing the ACN molecule. These investigations confirm the generation of localized modes by the phenomenon of MI and the predominance of the N-H vibrational mode in the MI process of the ACN.

  5. Interactions of Cu(B) with Carbon Monoxide in Cytochrome c Oxidase: Origin of the Anomalous Correlation between the Fe-CO and C-O Stretching Frequencies.

    PubMed

    Egawa, Tsuyoshi; Haber, Jonah; Fee, James A; Yeh, Syun-Ru; Rousseau, Denis L

    2015-07-01

    In heme-copper oxidases, the correlation curve between the iron-CO and C-O stretching vibrational modes (ν(Fe-CO) and ν(C-O), respectively) is anomalous as compared to the correlation in other heme proteins. To extend the correlation curve, the resonance Raman (RR) and infrared (IR) spectra of the CO adducts of cytochrome ba3 (ba3) from Thermus thermophilus were measured. The RR spectrum has two strong ν(Fe-CO) lines (508 and 515 cm(-1)) and a very weak line at 526 cm(-1), and the IR spectrum has three ν(C-O) lines (1966, 1973, and 1981 cm(-1)), indicating the presence of multiple conformers. Employing photodissociation methods, the ν(Fe-CO) RR and ν(C-O) IR lines were assigned to each conformer, enabling the establishment of a reliable inverse correlation curve for the ν(Fe-CO) versus the ν(C-O) stretching frequencies. To determine the molecular basis of the correlation, a series of DFT calculations on 6-coordinate porphyrin-CO compounds and a model of the binuclear center of the heme-copper oxidases were carried out. The calculations demonstrated that the copper unit model caused significant mixing among porphyrin-CO molecular orbitals (MOs) that contribute to the Fe-C and C-O bonding interactions, and also indicated the presence of mixing between the d(z)(2) orbital of the copper and MOs that are responsible for the ν(Fe-CO) vs ν(C-O) inverse correlation. Together, the spectroscopic and DFT results clarify the origin of the anomaly of ν(Fe-CO) and ν(C-O) frequencies in the heme-copper oxidases, a long-standing issue. PMID:26056844

  6. Frequency characteristics of electro-hydraulic vibrator.

    PubMed

    Satoh, Noriaki

    2002-12-01

    Frequency characteristics of an electro-hydraulic vibrator were measured using two kinds of test signals. First, sine signals had theoretically 1.0 m/s2 (root-mean-square) in the frequency range from 1 to 16 Hz at single axis. The frequency characteristics were flat from 1 to 12 Hz, but 14, 16 Hz was considerably poor. Second, the vibrator was excited when using a complex signal consisting of 12 components in the frequency range from 1 to 12 Hz at single axis. The overall acceleration was 3 and 1 m/s2. Flat characteristics were seen in the tested frequency range. Acceleration distortion was recognized in a higher frequency than the target frequency. This second method is effective for the efficiency of experimental procedure. PMID:12506857

  7. Low-frequency vibrational modes of glutamine

    NASA Astrophysics Data System (ADS)

    Wang, Wei-Ning; Wang, Guo; Zhang, Yan

    2011-12-01

    High-resolution terahertz absorption and Raman spectra of glutamine in the frequency region 0.2 THz-2.8 THz are obtained by using THz time domain spectroscopy and low-frequency Raman spectroscopy. Based on the experimental and the computational results, the vibration modes corresponding to the terahertz absorption and Raman scatting peaks are assigned and further verified by the theoretical calculations. Spectral investigation of the periodic structure of glutamine based on the sophisticated hybrid density functional B3LYP indicates that the vibrational modes come mainly from the inter-molecular hydrogen bond in this frequency region.

  8. Vibration modes and frequencies of structures

    NASA Technical Reports Server (NTRS)

    Durling, R. J.; Kvaternik, R. G.

    1980-01-01

    SUDAN, Substructuring in Direct Analysis, analyzes natural modes and frequencies of vibration of structural systems. Based on direct method of analysis that employs substructures methodology, program is used with structures that may be represented as equivalent system of beam, springs, and rigid bodies.

  9. Energy scavenging from low frequency vibrations

    NASA Astrophysics Data System (ADS)

    Galchev, Tzeno V.

    The development of three energy conversion devices that are able to transform vibrations in their surroundings to electrical energy is discussed in this thesis. These energy harvesters are based upon a newly invented architecture called the Parametric Frequency Increased Generator (PFIG). The PFIG structure is designed to efficiently convert low frequency and non-periodic vibrations into electrical power. The three PFIG devices have a combined operating range covering two orders of magnitude in acceleration (0.54--19.6m/s 2) and a frequency range spanning up to 60Hz; making them some of the most versatile generators in existence. The PFIG utilizes a bi-stable mechanical structure to initiate high-frequency mechanical oscillations in an electromechanical scavenger. By up-converting the ambient vibration frequency to a higher internal operation frequency, the PFIG achieves better electromechanical coupling. The fixed internal displacement and dynamics of the PFIG allow it to operate more efficiently than resonant generators when the ambient vibration amplitude is higher than the internal displacement limit of the device. The PFIG structure is capable of efficiently converting mechanical vibrations with variable characteristics including amplitude and frequency, into electrical power. The first electromagnetic harvester can generate a peak power of 163microW and an average power of 13.6microW from an input acceleration of 9.8m/s 2 at 10Hz, and it can operate up to 60Hz. The internal volume of the generator is 2.12cm3 (3.75 including casing). It sets the state-of-the-art in efficiency in the <20Hz range. The volume figure of merit is 0.068%, which is a 10x improvement over other published works. It has a record high bandwidth figure of merit (0.375%). A second piezoelectric implementation generates 3.25microW of average power under the same excitation conditions, while the volume of the generator is halved (1.2cm3). A third PFIG was developed for critical

  10. Dynamic vibration absorbers for vibration control within a frequency band

    NASA Astrophysics Data System (ADS)

    Yang, Cheng; Li, Deyu; Cheng, Li

    2011-04-01

    The use of dynamic vibration absorbers to control the vibration of a structure in both narrow and broadbands is discussed in this paper. As a benchmark problem, a plate incorporating multiple vibration absorbers is formulated, leading to an analytical solution when the number of absorbers yields one. Using this analytical solution, control mechanisms of the vibration absorber in different frequency bandwidths are studied; the coupling properties due to the introduction of the absorber into the host structure are analyzed; and the control performance of the absorber in different control bandwidths is examined with respect to its damping and location. It is found that the interaction between the plate and the absorber by means of the reaction force from the absorber plays a dominant role in a narrow band control, while in a relatively broadband control the dissipation by the absorber damping governs the control performance. When control bandwidth further enlarges, the optimal locations of the absorbers are not only affected by the targeted mode, but also by the other plate modes. These locations need to be determined after establishing a trade-off between the targeted mode and other modes involved in the coupling. Finally, numerical findings are assessed based on a simply-supported plate and a fair agreement between the predicted and measured results is obtained.

  11. Vibrational frequencies and structural determination of tetrafluoroformaldazine.

    PubMed

    Jensen, James O

    2004-09-01

    The normal mode frequencies and corresponding vibrational assignments of tetrafluoroformaldazine (F(2)CNNCF(2)) are examined theoretically using the Gaussian98 set of quantum chemistry codes. Each of the vibrational modes was assigned to one of nine types of motion predicted by a group theoretical analysis (C-F stretch, C[triple bond]N stretch, N-N stretch, C=C-N bend, CF(2) wag, CF(2) rock CF(2) scissors, CF(2) twist, and C=N-N=C torsion) utilizing the C(2h) symmetry of the molecule. Uniform scaling factors was derived for each type of motion. Predicted infrared and Raman intensities are reported. PMID:15294242

  12. Vibrational solvatochromism and electrochromism of infrared probe molecules containing C≡O, C≡N, C=O, or C-F vibrational chromophore

    NASA Astrophysics Data System (ADS)

    Choi, Jun-Ho; Cho, Minhaeng

    2011-04-01

    Solvatochromic vibrational frequency shifts of a few different infrared (IR) probe molecules have been studied by carrying out quantum chemistry calculations for a number of their water clusters. We are particularly focused on the vibrational solvatochromic and electrochromic effects on the CO, CN, and CF stretch modes in carbon monoxide, acetone, 4-cyanopyridine, p-tolunitrile, fluorobenzene, and 3-fluoropyridine. Using multiple interaction site antenna model, we show that their solvatochromic vibrational frequency shifts can be successfully described by considering spatially nonuniform electrostatic potential generated by the surrounding water molecules. It turns out that the CO and CF stretch mode frequencies are approximately proportional to the solvent electric field projected onto the bond axes, whereas the vibrational frequencies of the nitrile stretch mode in 4-cyanopyridine and p-tolunitrile are not. Consequently, it is confirmed that the vibrational Stark tuning rates of the CO and CF stretching modes can be directly used to describe their solvatochromic frequency shifts in condensed phases. However, the nitrile stretch mode frequency shift induced by solvent electrostatic potential appears to be more complicated than its electrochromic phenomenon. To examine the validity of the distributed interaction site model for solvatochromic frequency shifts of these vibrational chromophores, we thus calculated the vibrational Stark tuning rates of the CO, CN, and CF stretch modes and found that they are in good agreement with the experimental results found in literatures. This confirms that a collection of properly chosen distributed interaction sites can be an excellent electric antenna sensing local electrostatics that affects on vibrational frequencies of IR probe modes.

  13. Iminopropadienones RN=C=C=C=O and bisiminopropadienes RN=C=C=C=NR: Matrix infrared spectra and anharmonic frequency calculations

    NASA Astrophysics Data System (ADS)

    Bégué, Didier; Baraille, Isabelle; Andersen, Heidi Gade; Wentrup, Curt

    2013-10-01

    Methyliminopropadienone MeN=C=C=C=O 1a was generated by flash vacuum thermolysis from four different precursors and isolated in solid argon. The matrix-isolation infrared spectrum is dominated by unusually strong anharmonic effects resulting in complex fine structure of the absorptions due to the NCCCO moiety in the 2200 cm-1 region. Doubling and tripling of the corresponding absorption bands are observed for phenyliminopropadienone PhN=C=C=C=O 1b and bis(phenylimino)propadiene PhN=C=C=C=NPh 9, respectively. Anharmonic vibrational frequency calculations allow the identification of a number of overtones and combination bands as the cause of the splittings for each molecule. This method constitutes an important tool for the characterization of reactive intermediates and unusual molecules by matrix-isolation infrared spectroscopy.

  14. Standard infralow-frequency vibration system

    SciTech Connect

    Chistyakov, V.A.; Korytko, E.P.; Pevzner, B.N.; Prosikov, A.A.

    1985-06-01

    Precision test systems working in the range 0.01-20 Hz are required to determine the metrological characteristics of seismic equipment used in seismic observations and in research on the earth's physical properties. An experimental seismometric test system (STS) has been built to produce sinusoidal oscillations in the horizontal plane in the range 0.01-20 Hz with amplitudes of 0.1-20 mm for instruments of mass up to 25 kg. The apparatus contains a computer and the programmable GZ-110 oscillator, which provide good scope for automating the processing and specifying the working modes in checking equipment with high accuracy and throughput. The STS enables one to record the frequency response, the phase response, and the amplitude characteristics for means of measuring the parameters of infralow-frequency vibrations, as well as to determine the conversion factors for seismic detectors and the metrological parameters of instruments.

  15. Driving an Active Vibration Balancer to Minimize Vibrations at the Fundamental and Harmonic Frequencies

    NASA Technical Reports Server (NTRS)

    Holliday, Ezekiel S. (Inventor)

    2014-01-01

    Vibrations of a principal machine are reduced at the fundamental and harmonic frequencies by driving the drive motor of an active balancer with balancing signals at the fundamental and selected harmonics. Vibrations are sensed to provide a signal representing the mechanical vibrations. A balancing signal generator for the fundamental and for each selected harmonic processes the sensed vibration signal with adaptive filter algorithms of adaptive filters for each frequency to generate a balancing signal for each frequency. Reference inputs for each frequency are applied to the adaptive filter algorithms of each balancing signal generator at the frequency assigned to the generator. The harmonic balancing signals for all of the frequencies are summed and applied to drive the drive motor. The harmonic balancing signals drive the drive motor with a drive voltage component in opposition to the vibration at each frequency.

  16. Multireflection sum frequency generation vibrational spectroscopy.

    PubMed

    Zhang, Chi; Jasensky, Joshua; Chen, Zhan

    2015-08-18

    We developed a multireflection data collection method in order to improve the signal-to-noise ratio (SNR) and sensitivity of sum frequency generation (SFG) spectroscopy, which we refer to as multireflection SFG, or MRSFG for short. To achieve MRSFG, a collinear laser beam propagation geometry was adopted and trapezoidal Dove prisms were used as sample substrates. An in-depth discussion on the signal and SNR in MRSFG was performed. We showed experimentally, with "m" total internal reflections in a Dove prism, MRSFG signal is ∼m times that of conventional SFG; SNR of the SFG signal-to-background is improved by a factor of >m(1/2) and vibrational signals. Surface molecular structures of adsorbed ethanol molecules, polymer films, and a lipid monolayer were characterized using both MRSFG and conventional SFG. Molecular orientation information on lipid molecules with a 9% composition in a mixed monolayer was measured using MRSFG, which showed a good agreement with that derived from 100% lipid surface coverage using conventional SFG. MRSFG can both improve the spectral quality and detection limit of SFG spectroscopy and is expected to have important applications in surface science for studying structures of molecules with a low surface coverage or less ordered molecular moieties. PMID:26176565

  17. A long-stroke horizontal electromagnetic vibrator for ultralow-frequency vibration calibration

    NASA Astrophysics Data System (ADS)

    He, Wen; Zhang, Xufei; Wang, Chunyu; Shen, Runjie; Yu, Mei

    2014-08-01

    A novel long-stroke horizontal electromagnetic vibrator with maximum stroke of 1 m is proposed. To reply to the strong nonlinearity arising from long stroke, a closed double-magnetic circuit with optimal air gap, an electro-viscoelastic-suspension device and a track following device are adopted in the vibrator. Also, a compact moving component with a higher first-order natural frequency is designed to increase the operating frequency of the vibrator. Finally, experimental results show that the vibrator could output low distortion acceleration on its working platform from 0.002 Hz to 100 Hz, which verifies the validity of the proposed technologies and the applicability of the vibrator for an ultralow-frequency vibration calibration system.

  18. Sweeping tuneable vibration absorbers for low-mid frequencies vibration control

    NASA Astrophysics Data System (ADS)

    Gardonio, P.; Zilletti, M.

    2015-10-01

    This paper presents a simulation study concerning the low-mid frequencies control of flexural vibration in a lightly damped thin plate, which is equipped with three sweeping tuneable vibration absorbers and is excited by a rain on the roof broad frequency band stationary disturbance. The sweeping tuneable vibration absorbers are semi-active mass-spring-dashpot systems whose stiffness and damping properties can be varied uniformly within given ranges. They are operated in such a way as their characteristic natural frequencies are continuously varied to control the response of flexural modes that resonate within given frequency bands. More specifically, in this study the three sweeping tuneable vibration absorbers are operated asynchronously, each within one of three sequential frequency bands comprised between 20 and 120, 120 and 220, 220 and 320 Hz. The flexural vibration control effects produced by the three sweeping tuneable vibration absorbers are compared to those produced by three classical tuneable vibration absorbers, each set to control the response of a specific flexural mode of the plate resonating in one of these three frequency bands. The study shows that the proposed sweeping tuneable vibration absorbers outperform the classical tuneable vibration absorbers and produce about 6, 5, 4 dB reduction of the plate overall flexural response in the three frequency bands of operation. Also, the study indicates that the sweeping tuneable vibration absorbers are robust to variations in the plate flexural response. For instance they still produce about 5.1, 5.3, 4.6 dB reductions of the flexural response in the three frequency bands of operation when the plate is tensioned such that the flexural natural frequencies are shifted up from about 40 percent, for the first resonance, to 7 percent, for the tenth resonance.

  19. A vibration energy harvesting device with bidirectional resonance frequency tunability

    NASA Astrophysics Data System (ADS)

    Challa, Vinod R.; Prasad, M. G.; Shi, Yong; Fisher, Frank T.

    2008-02-01

    Vibration energy harvesting is an attractive technique for potential powering of wireless sensors and low power devices. While the technique can be employed to harvest energy from vibrations and vibrating structures, a general requirement independent of the energy transfer mechanism is that the vibration energy harvesting device operate in resonance at the excitation frequency. Most energy harvesting devices developed to date are single resonance frequency based, and while recent efforts have been made to broaden the frequency range of energy harvesting devices, what is lacking is a robust tunable energy harvesting technique. In this paper, the design and testing of a resonance frequency tunable energy harvesting device using a magnetic force technique is presented. This technique enabled resonance tuning to ± 20% of the untuned resonant frequency. In particular, this magnetic-based approach enables either an increase or decrease in the tuned resonant frequency. A piezoelectric cantilever beam with a natural frequency of 26 Hz is used as the energy harvesting cantilever, which is successfully tuned over a frequency range of 22-32 Hz to enable a continuous power output 240-280 µW over the entire frequency range tested. A theoretical model using variable damping is presented, whose results agree closely with the experimental results. The magnetic force applied for resonance frequency tuning and its effect on damping and load resistance have been experimentally determined.

  20. Low-frequency vibrational modes of riboflavin and related compounds

    NASA Astrophysics Data System (ADS)

    Takahashi, Masae; Ishikawa, Yoichi; Nishizawa, Jun-ichi; Ito, Hiromasa

    2005-01-01

    The low-frequency vibrations of riboflavin and related compounds (alloxazine, lumichrome, lumiflavin as the ring system and D-mannitol as the side-chain system) were observed by far-infrared (terahertz) spectroscopy. Vibrational mode assignments in this spectrally congested range were made using high precision quantum chemical calculations. These resonance frequencies located below 200 cm -1 indicate the existence of motions important for biological reactions. The observed absorption bands in the low-frequency region of riboflavin are assigned to the in-plane and out-of-plane-ring deformations of pyrimidine and isoalloxazine, and to the torsion modes of the ribityl chain.

  1. The frequencies of cantilever wings in beam and torsional vibrations

    NASA Technical Reports Server (NTRS)

    Burgess, C P

    1940-01-01

    Methods are described for calculating the period and frequency of vibration of cantilever wings and similar structures in which the weight and moment of inertia vary along the span. Both the beam and torsional frequencies may be calculated by these methods. The procedure is illustrated by examples. It is shown that a surprisingly close approximation to the beam frequency may be obtained by a very brief calculation in which the curvature of the wing in vibration is assumed to be constant. A somewhat longer computation permits taking account of the true curvature of the beam by a series of successive approximations which are shown to be strongly convergent. Analogous methods are applied to calculations of the torsional frequency. For the first approximation it is assumed that the angle of twist varies linearly alone the semispan. True variation of the twist is computed by successive approximations which are strongly convergent, as in the case of beam vibrations.

  2. Experimental and theoretical study of absorption spectrum of the (CH3)2CO···HF complex. Influence of anharmonic interactions on the frequency and intensity of the C=O and H-F stretching bands.

    PubMed

    Bulychev, V P; Svishcheva, E A; Tokhadze, K G

    2014-01-01

    IR absorption spectra of mixtures (CH3)2CO/HF and free (CH3)2CO molecules are recorded in the region of 4000-900 cm(-1) with a Bruker IFS-125 HR vacuum Fourier spectrometer at room temperature with a resolution up to 0.02 cm(-1). Spectral characteristics of the 2ν(C=O) overtone band of free acetone are reliably measured. The ν1(HF) and ν(C=O) absorption bands of the (CH3)2CO···HF complex are obtained by subtracting the absorption bands of free HF and acetone and absorption lines of atmospheric water from the experimental spectrum of mixtures. The experimental data are compared with theoretical results obtained from variational solutions of 1D-4D vibrational Schrödinger equations. The anharmonic potential energy and dipole moment surfaces used in the calculations were computed in the MP2/6-311++G(2d,2p) approximation with corrections for the basis set superposition error. Comparison of the data derived from solutions for different combinations of vibrational degrees of freedom shows that taking the inter-mode anharmonic interactions into account has different effects on the transition frequencies and intensities. Particular attention has been given to elucidation of the influence of anharmonic coupling of the H-F and C=O stretches with the low-frequency intermolecular modes on their frequencies and intensities and the strength of resonance between the fundamental H-F and the first overtone C=O transitions. PMID:24128921

  3. Vibrational spectroscopy and conformation of S-ethyl thioacetate: CH3COSCH2CH3 and comparison with sbnd C(O)Ssbnd and sbnd C(O)Osbnd compounds

    NASA Astrophysics Data System (ADS)

    Defonsi Lestard, María Eliana; Tuttolomondo, María Eugenia; Ben Altabef, Aida

    2015-01-01

    The molecular structure and conformational properties of S-ethyl thioacetate, CH3COSCH2CH3, were determined in the gas phase by electron diffraction and vibrational spectroscopy (IR and Raman). The experimental investigations were supplemented by ab initio (MP2) and DFT quantum chemical calculations at different levels of theory. Theoretical methods reveal two structures with Cs (anti, anti) and C1 (anti, gauche) symmetries. The infrared and Raman spectra for different phases were also recorded and the bands observed assigned to the vibrational normal modes. Liquid Raman and infrared spectra in liquid and gaseous state measurements revealed the presence of two conformations anti, anti (Cs symmetry) and anti, gauche (C1 symmetry). The study was completed using natural bond orbital (NBO) analysis. We have also analyzed the internal rotation barrier about the C(O)SCC dihedral angle using a variety of computational approaches and natural bond orbital (NBO) analyses to understand the nature of the potential function and to explain the preferred conformation of the molecule.

  4. Low-frequency vibration control of floating slab tracks using dynamic vibration absorbers

    NASA Astrophysics Data System (ADS)

    Zhu, Shengyang; Yang, Jizhong; Yan, Hua; Zhang, Longqing; Cai, Chengbiao

    2015-09-01

    This study aims to effectively and robustly suppress the low-frequency vibrations of floating slab tracks (FSTs) using dynamic vibration absorbers (DVAs). First, the optimal locations where the DVAs are attached are determined by modal analysis with a finite element model of the FST. Further, by identifying the equivalent mass of the concerned modes, the optimal stiffness and damping coefficient of each DVA are obtained to minimise the resonant vibration amplitudes based on fixed-point theory. Finally, a three-dimensional coupled dynamic model of a metro vehicle and the FST with the DVAs is developed based on the nonlinear Hertzian contact theory and the modified Kalker linear creep theory. The track irregularities are included and generated by means of a time-frequency transformation technique. The effect of the DVAs on the vibration absorption of the FST subjected to the vehicle dynamic loads is evaluated with the help of the insertion loss in one-third octave frequency bands. The sensitivities of the mass ratio of DVAs and the damping ratio of steel-springs under the floating slab are discussed as well, which provided engineers with the DVA's adjustable room for vibration mitigation. The numerical results show that the proposed DVAs could effectively suppress low-frequency vibrations of the FST when tuned correctly and attached properly. The insertion loss due to the attachment of DVAs increases as the mass ratio increases, whereas it decreases with the increase in the damping ratio of steel-springs.

  5. Powerful Low-Frequency Vibrators for Active Seismology

    SciTech Connect

    Alekseev, A.S.; Chichinin, I.S.; Korneev, V.A.

    2003-12-01

    In the past two decades, active seismology studies in Russia have made use of powerful (40- and 100-ton) low-frequency vibrators. These sources create a force amplitude of up to 100 tons and function in the 1.5 3, 3 6, and 5 10 Hz frequency bands. The mobile versions of the vibrator have a force amplitude of 40 tons and a 6 12 Hz frequency band. Recording distances for the 100-ton vibrator are as large as 350 km, enabling the refracted waves to penetrate down to 50 km depths. Vibrator operation sessions are highly repeatable, having distinct summer or winter spectral patterns. A long profile of seismic records allows estimation of fault zone depths using changes in recorded spectra. Other applications include deep seismic profiling, seismic hazard mapping, structural testing, stress-induced anisotropy studies, seismic station calibration, and large-structure integrity testing. The theoretical description of the low-frequency vibrator is given in the appendices, which contain numerical examples.

  6. Multiple vibration intensities and frequencies for bone mineral density improvement.

    PubMed

    Ezenwa, Bertram; Burns, Edith; Wilson, Charles

    2008-01-01

    Devices that deliver controlled quantum vibration intensities at multiple frequencies (QVIMF) provide optimal stress to the musculoskeletal system for improved bone mineral density and muscle strength. This paper presents development of a QVIMF system and pilot study to determine device performance. Development is centered on specially-designed actuators that comprise multiple nodes of controlled and smooth, but variable rates of contact on a telescoping platform through sets of damping subsystems. The combination of specially-designed actuators and damping subsystems, powered by a DC controlled motor, delivers quantum busts of vibration at multiple frequencies resulting in whole body vibration. An initial feasibility study involved a 79 year old adult male. After IRB approval from both the University of Wisconsin-Milwaukee (UWM) and the Zablocki VA Medical Center, Milwaukee, the subject's bone mineral density (BMD) was measured by dual x-ray absorptimetry (DXA) at baseline. The subject then visited the UWM laboratory for two fifteen-minute vibration sessions per visit, three times a week for a total of 60 visits. Post-vibration BMD was again measured by DXA. Comparison pre- and post-vibration test results showed increases in BMD at the femoral neck, trochanter, total hip, forearm and lower lumbar spine (L1-4). PMID:19163635

  7. Acoustic metamaterial structures based on multi-frequency vibration absorbers

    NASA Astrophysics Data System (ADS)

    Pai, P. Frank; Peng, Hao

    2014-03-01

    This paper presents a new metamaterial beam based on multi-frequency vibration absorbers for broadband vibration absorption. The proposed metamaterial beam consists of a uniform isotropic beam and small two-mass spring-mass- damper subsystems at many locations along the beam to act as multi-frequency vibration absorbers. For an infinite metamaterial beam, governing equations of a unit cell are derived using the extended Hamilton principle. The existence of two stopbands is demonstrated using a model based on averaging material properties over a cell length and a model based on finite element modeling and the Bloch-Floquet theory for periodic structures. For a finite metamaterial beam, because these two idealized models cannot be used for finite beams and/or elastic waves having short wavelengths, a finite-element method is used for detailed modeling and analysis. The concepts of negative effective mass and effective stiffness and how the spring-mass-damper subsystem creates two stopbands are explained in detail. Numerical simulations reveal that the actual working mechanism of the proposed metamaterial beam is based on the concept of conventional mechanical vibration absorbers. For an incoming wave with a frequency in one of the two stopbands, the absorbers are excited to vibrate in their optical modes to create shear forces to straighten the beam and stop the wave propagation. For an incoming wave with a frequency outside of but between the two stopbands, it can be efficiently damped out by the damper with the second mass of each absorber. Hence, the two stopbands are connected into a wide stopband. Numerical examples validate the concept and show that the structure's boundary conditions do not have significant influence on the absorption of high-frequency waves. However, for absorption of low-frequency waves, the structure's boundary conditions and resonance frequencies and the location and spatial distribution of absorbers need to be considered in design, and it

  8. An innovative MRE absorber with double natural frequencies for wide frequency bandwidth vibration absorption

    NASA Astrophysics Data System (ADS)

    Sun, Shuaishuai; Yang, Jian; Li, Weihua; Deng, Huaxia; Du, Haiping; Alici, Gursel; Yan, Tianhong

    2016-05-01

    A new design of adaptive tuned vibration absorber was proposed in this study for vibration reduction. The innovation of the new absorber is the adoption of the eccentric mass on the top of the multilayered magnetorheological elastomer (MRE) structure so that this proposed absorber has two vibration modes: one in the torsional direction and the other in translational direction. This property enables the absorber to expand its effective bandwidth and to be more capable of reducing the vibrations especially dealing with those vibrations with multi-frequencies. The innovative MRE absorber was designed and tested on a horizontal vibration table. The test results illustrate that the MRE absorber realized double natural frequencies, both of which are controllable. Inertia’s influence on the dynamic behavior of the absorber is also investigated in order to guide the design of the innovative MRE absorber. Additionally, the experimentally obtained natural frequencies coincide with the theoretical data, which sufficiently verifies the feasibility of this new design. The last part in terms of the vibration absorption ability also proves that both of these two natural frequencies play a great role in absorbing vibration energy.

  9. Collagen and component polypeptides: Low frequency and amide vibrations

    NASA Astrophysics Data System (ADS)

    Fontaine-Vive, F.; Merzel, F.; Johnson, M. R.; Kearley, G. J.

    2009-01-01

    Collagen is a fibrous protein, which exists widely in the human body. The biomechanical properties of collagen depend on its triple helix structure and the corresponding low frequency vibrations. We use first-principles, density functional theory methods and analytical force fields to investigate the molecular vibrations of a model collagen compound, the results being validated by comparison with published, inelastic neutron scattering data. The results from these atomistic simulations are used at higher frequency to study the Amide I and V vibrations and therefore the vibrational signature of secondary and tertiary structure formation. In addition to collagen, its component homopolymers, poly-glycine and poly-proline are also studied. The Amide V vibration of glycine is strongly modified in going from the single helix of poly-glycine II to the triple helix of collagen. The collagen models are hydrated and this work allows us to discuss the relative merits of density functional theory and force field methods when tackling complex, partially crystalline systems.

  10. Enhanced shock and vibration isolator for the attenuation of low-frequency vibration and high-frequency pyroshock loads

    NASA Astrophysics Data System (ADS)

    Han, Jae-Hung; Youn, Se-Hyun; Jeong, Ho-Kyung; Jang, Young-Soon

    2011-11-01

    Launch vehicles, satellites and aircrafts often experience harsh vibration and pyroshock loads during the flight including maneuvering and separation events, which may cause the malfunction of equipped electronic devices. Furthermore, this minor malfunction can generate catastrophic failure of the whole mission. To prevent malfunction of the electronic devices from severe shock and vibration loads, elastomeric isolators are commonly applied between the electronic device and the equipment bay structure in the aerospace fields. However, this rubber type elastomeric material is vulnerable to the low-frequency vibration load which involves large amount of displacement due to its low stiffness. Recently, the present authors proposed new type of isolator, called as pseudoelastic hybrid mesh isolator. This talk introduces the key features of this new pseudoelastic hybrid mesh isolator which shows better isolation performance throughout all frequency range than conventional isolators.

  11. Enhanced shock and vibration isolator for the attenuation of low-frequency vibration and high-frequency pyroshock loads

    NASA Astrophysics Data System (ADS)

    Han, Jae-Hung; Youn, Se-Hyun; Jeong, Ho-Kyung; Jang, Young-Soon

    2012-04-01

    Launch vehicles, satellites and aircrafts often experience harsh vibration and pyroshock loads during the flight including maneuvering and separation events, which may cause the malfunction of equipped electronic devices. Furthermore, this minor malfunction can generate catastrophic failure of the whole mission. To prevent malfunction of the electronic devices from severe shock and vibration loads, elastomeric isolators are commonly applied between the electronic device and the equipment bay structure in the aerospace fields. However, this rubber type elastomeric material is vulnerable to the low-frequency vibration load which involves large amount of displacement due to its low stiffness. Recently, the present authors proposed new type of isolator, called as pseudoelastic hybrid mesh isolator. This talk introduces the key features of this new pseudoelastic hybrid mesh isolator which shows better isolation performance throughout all frequency range than conventional isolators.

  12. A Solvatochromic Model Calibrates Nitriles’ Vibrational Frequencies to Electrostatic Fields

    PubMed Central

    Bagchi, Sayan; Fried, Stephen D.; Boxer, Steven G.

    2012-01-01

    Electrostatic interactions provide a primary connection between a protein’s three-dimensional structure and its function. Infrared (IR) probes are useful because vibrational frequencies of certain chemical groups, such as nitriles, are linearly sensitive to local electrostatic field, and can serve as a molecular electric field meter. IR spectroscopy has been used to study electrostatic changes or fluctuations in proteins, but measured peak frequencies have not been previously mapped to total electric fields, because of the absence of a field-frequency calibration and the complication of local chemical effects such as H-bonds. We report a solvatochromic model that provides a means to assess the H-bonding status of aromatic nitrile vibrational probes, and calibrates their vibrational frequencies to electrostatic field. The analysis involves correlations between the nitrile’s IR frequency and its 13C chemical shift, whose observation is facilitated by a robust method for introducing isotopes into aromatic nitriles. The method is tested on the model protein Ribonuclease S (RNase S) containing a labeled p-CN-Phe near the active site. Comparison of the measurements in RNase S against solvatochromic data gives an estimate of the average total electrostatic field at this location. The value determined agrees quantitatively with MD simulations, suggesting broader potential for the use of IR probes in the study of protein electrostatics. PMID:22694663

  13. Low Frequency Vibration Energy Harvesting using Diamagnetically Stabilized Magnet Levitation

    NASA Astrophysics Data System (ADS)

    Palagummi, Sri Vikram

    Over the last decade, vibration-based energy harvesting has provided a technology push on the feasibility of self-powered portable small electronic devices and wireless sensor nodes. Vibration energy harvesters in general transduce energy by damping out the environmentally induced relative emotion through either a cantilever beam or an equivalent suspension mechanism with one of the transduction mechanisms, like, piezoelectric, electrostatic, electromagnetic or magnetostrictive. Two major challenges face the present harvesters in literature, one, they suffer from the unavoidable mechanical damping due to internal friction present in the systems, second, they cannot operate efficiently in the low frequency range (< 10 Hz), when most of the ambient vibrational energy is in this low frequency broadband range. Passive and friction free diamagnetically stabilized magnet levitation mechanisms which can work efficiently as a vibration energy harvester in the low frequency range are discussed in this work. First, a mono-stable vertical diamagnetic levitation (VDL) based vibration energy harvester (VEH) is discussed. The harvester consists of a lifting magnet (LM), a floating magnet (FM) and two diamagnetic plates (DPs). The LM balances out the weight of the FM and stability is brought about by the repulsive effect of the DPs, made of pyrolytic graphite. Two thick cylindrical coils, placed in grooves which are engraved in the DPs, are used to convert the mechanical energy into electrical energy. Experimental frequency response of the system is validated by the theoretical analysis which showed that the VEH works in a low frequency range but sufficient levitation gap was not achieved and the frequency response characteristic of the system was effectively linear. To overcome these challenges, the influence of the geometry of the FM, the LM, and the DP were parametrically studied to assess their effects on the levitation gap, size of the system and the natural frequency. For

  14. Effects of broad frequency vibration on cultured osteoblasts

    NASA Technical Reports Server (NTRS)

    Tanaka, Shigeo M.; Li, Jiliang; Duncan, Randall L.; Yokota, Hiroki; Burr, David B.; Turner, Charles H.

    2003-01-01

    Bone is subjected in vivo to both high amplitude, low frequency strain, incurred by locomotion, and to low amplitude, broad frequency strain. The biological effects of low amplitude, broad frequency strain are poorly understood. To evaluate the effects of low amplitude strains ranging in frequency from 0 to 50 Hz on osteoblastic function, we seeded MC3T3-E1 cells into collagen gels and applied the following loading protocols for 3 min per day for either 3 or 7 days: (1) sinusoidal strain at 3 Hz, with 0-3000 microstrain peak-to-peak followed by 0.33 s resting time, (2) "broad frequency vibration" of low amplitude strain (standard deviation of 300 microstrain) including frequency components from 0 to 50 Hz, and (3) sinusoidal strain combined with broad frequency vibration (S + V). The cells were harvested on day 4 or 8. We found that the S + V stimulation significantly repressed cell proliferation by day 8. Osteocalcin mRNA was up-regulated 2.6-fold after 7 days of S + V stimulation, and MMP-9 mRNA was elevated 1.3-fold after 3 days of vibration alone. Sinusoidal stimulation alone did not affect the cell responses. No differences due to loading were observed in alkaline phosphatase activity and in mRNA levels of type I collagen, osteopontin, connexin 43, MMPs-1A, -3, -13. These results suggest that osteoblasts are more sensitive to low amplitude, broad frequency strain, and this kind of strain could sensitize osteoblasts to high amplitude, low frequency strain. This suggestion implies a potential contribution of stochastic resonance to the mechanical sensitivity of osteoblasts. Copyright 2002 Elsevier Science Ltd.

  15. Frequency Identification of Vibration Signals Using Video Camera Image Data

    PubMed Central

    Jeng, Yih-Nen; Wu, Chia-Hung

    2012-01-01

    This study showed that an image data acquisition system connecting a high-speed camera or webcam to a notebook or personal computer (PC) can precisely capture most dominant modes of vibration signal, but may involve the non-physical modes induced by the insufficient frame rates. Using a simple model, frequencies of these modes are properly predicted and excluded. Two experimental designs, which involve using an LED light source and a vibration exciter, are proposed to demonstrate the performance. First, the original gray-level resolution of a video camera from, for instance, 0 to 256 levels, was enhanced by summing gray-level data of all pixels in a small region around the point of interest. The image signal was further enhanced by attaching a white paper sheet marked with a black line on the surface of the vibration system in operation to increase the gray-level resolution. Experimental results showed that the Prosilica CV640C CMOS high-speed camera has the critical frequency of inducing the false mode at 60 Hz, whereas that of the webcam is 7.8 Hz. Several factors were proven to have the effect of partially suppressing the non-physical modes, but they cannot eliminate them completely. Two examples, the prominent vibration modes of which are less than the associated critical frequencies, are examined to demonstrate the performances of the proposed systems. In general, the experimental data show that the non-contact type image data acquisition systems are potential tools for collecting the low-frequency vibration signal of a system. PMID:23202026

  16. Frequency identification of vibration signals using video camera image data.

    PubMed

    Jeng, Yih-Nen; Wu, Chia-Hung

    2012-01-01

    This study showed that an image data acquisition system connecting a high-speed camera or webcam to a notebook or personal computer (PC) can precisely capture most dominant modes of vibration signal, but may involve the non-physical modes induced by the insufficient frame rates. Using a simple model, frequencies of these modes are properly predicted and excluded. Two experimental designs, which involve using an LED light source and a vibration exciter, are proposed to demonstrate the performance. First, the original gray-level resolution of a video camera from, for instance, 0 to 256 levels, was enhanced by summing gray-level data of all pixels in a small region around the point of interest. The image signal was further enhanced by attaching a white paper sheet marked with a black line on the surface of the vibration system in operation to increase the gray-level resolution. Experimental results showed that the Prosilica CV640C CMOS high-speed camera has the critical frequency of inducing the false mode at 60 Hz, whereas that of the webcam is 7.8 Hz. Several factors were proven to have the effect of partially suppressing the non-physical modes, but they cannot eliminate them completely. Two examples, the prominent vibration modes of which are less than the associated critical frequencies, are examined to demonstrate the performances of the proposed systems. In general, the experimental data show that the non-contact type image data acquisition systems are potential tools for collecting the low-frequency vibration signal of a system. PMID:23202026

  17. Peroxyacetyl radical: Electronic excitation energies, fundamental vibrational frequencies, and symmetry breaking in the first excited state

    SciTech Connect

    Copan, Andreas V.; Wiens, Avery E.; Nowara, Ewa M.; Schaefer, Henry F.; Agarwal, Jay

    2015-02-07

    Peroxyacetyl radical [CH{sub 3}C(O)O{sub 2}] is among the most abundant peroxy radicals in the atmosphere and is involved in OH-radical recycling along with peroxyacetyl nitrate formation. Herein, the ground (X{sup ~}) and first (A{sup ~}) excited state surfaces of cis and trans peroxyacetyl radical are characterized using high-level ab initio methods. Geometries, anharmonic vibrational frequencies, and adiabatic excitation energies extrapolated to the complete basis-set limit are reported from computations with coupled-cluster theory. Excitation of the trans conformer is found to induce a symmetry-breaking conformational change due to second-order Jahn-Teller interactions with higher-lying excited states. Additional benchmark computations are provided to aid future theoretical work on peroxy radicals.

  18. A Sub-Hertz, Low-Frequency Vibration Isolation Platform

    NASA Technical Reports Server (NTRS)

    Ortiz, Gerardo, G.; Farr, William H.; Sannibale, Virginio

    2011-01-01

    One of the major technical problems deep-space optical communication (DSOC) systems need to solve is the isolation of the optical terminal from vibrations produced by the spacecraft navigational control system and by the moving parts of onboard instruments. Even under these vibration perturbations, the DSOC transceivers (telescopes) need to be pointed l000 fs of times more accurately than an RF communication system (parabolic antennas). Mechanical resonators have been extensively used to provide vibration isolation for groundbased, airborne, and spaceborne payloads. The effectiveness of these isolation systems is determined mainly by the ability of designing a mechanical oscillator with the lowest possible resonant frequency. The Low-Frequency Vibration Isolation Platform (LFVIP), developed during this effort, aims to reduce the resonant frequency of the mechanical oscillators into the sub-Hertz region in order to maximize the passive isolation afforded by the 40 dB/decade roll-off response of the resonator. The LFVIP also provides tip/tilt functionality for acquisition and tracking of a beacon signal. An active control system is used for platform positioning and for dampening of the mechanical oscillator. The basic idea in the design of the isolation platform is to use a passive isolation strut with an approximately equal to 100-mHz resonance frequency. This will extend the isolation range to lower frequencies. The harmonic oscillator is a second-order lowpass filter for mechanical disturbances. The resonance quality depends on the dissipation mechanisms, which are mainly hysteretic because of the low resonant frequency and the absence of any viscous medium. The LFVIP system is configured using the well-established Stewart Platform, which consists of a top platform connected to a base with six extensible struts (see figure). The struts are attached to the base and to the platform via universal joints, which permit the extension and contraction of the struts. The

  19. Self-mixing vibration measurement using emission frequency sinusoidal modulation

    NASA Astrophysics Data System (ADS)

    Tao, Yufeng; Wang, Ming; Guo, Dongmei; Hao, Hui; Liu, Qiang

    2015-04-01

    In this paper, a simplified phase demodulation scheme is applied to recover vibration trail on a laser self-mixing interferometer for noncontact vibration measurement. The emission of semiconductor laser diode is modulated by injecting sinusoidal wave, and corresponding interference signal is a quasi-sinusoid wave. The vibration mathematical model for semiconductor laser diode is theoretically educed from basic self-mixing theory, the variation of target is converted into phase information. The simulation of demodulation algorithm and standard deviation are presented and the reconstructed waveform displays a desirable consistence with various moving trails. Following the principle, a minimum experimental system is established and position variation of the target mirror driven by voltage signal is translated into phase shifts, feedback is controlled at weak level during experiment, Fourier transform is implemented to analyze phase information. The comparisons of both amplitude and velocity with a Germany Doppler vibrometer are performed to testify vibration model, the error of proposed demodulation method is less than 30 nm and achieve a high accuracy in vibration frequency. The experimental results indicate the traditional phase technology can be applied on complex optical power signal after adaption providing a feasible application prospects in industrial and scientific situation with an inexpensive semiconductor laser.

  20. Time frequency analyses of vibrations of wind turbine towers

    NASA Astrophysics Data System (ADS)

    Chiang, Chih-Hung; Huang, Chi-Luen; Hsu, Keng-Tseng; Cheng, Chia-Chi; Yu, Chih-Peng; Lai, Jiunnren

    2015-04-01

    Transient vibrations of the tower supporting a horizontal-axis wind turbine were recorded using a microwave interferometer. Variations in dominant frequencies have been reported in the previous study. Signal analyses aiming to uncouple different frequency components were performed using reassigned spectrogram, a time-frequency representation based on time-corrected short time Fourier transform. Optimal resolutions in both time and frequency domains were first investigated using synthetic signals. The goal was to seek out the favorable combinations of window size and overlapping portions of adjacent windows for a data sequence at a given sampling rate. The dominant frequency found in reassigned spectrogram agrees with that obtained using Fourier spectrum of the same transient measurements of the wind turbine tower under investigation.

  1. Black phosphorus nanoelectromechanical resonators vibrating at very high frequencies.

    PubMed

    Wang, Zenghui; Jia, Hao; Zheng, Xuqian; Yang, Rui; Wang, Zefang; Ye, G J; Chen, X H; Shan, Jie; Feng, Philip X-L

    2015-01-21

    We report on the experimental demonstration of a new type of nanoelectromechanical resonator based on black phosphorus crystals. Facilitated by a highly efficient dry transfer technique, crystalline black phosphorus flakes are harnessed to enable drumhead resonators vibrating at high and very high frequencies (HF and VHF bands, up to ∼100 MHz). We investigate the resonant vibrational responses from the black phosphorus crystals by devising both electrical and optical excitation schemes, in addition to measuring the undriven thermomechanical motions in these suspended nanostructures. Flakes with thicknesses from ∼200 nm down to ∼20 nm clearly exhibit elastic characteristics transitioning from the plate to the membrane regime. Both frequency- and time-domain measurements of the nanomechanical resonances show that very thin black phosphorus crystals hold interesting potential for moveable and vibratory devices and for semiconductor transducers where high-speed mechanical motions could be coupled to the attractive electronic and optoelectronic properties of black phosphorus. PMID:25385657

  2. High-frequency vibrations of sandwich plates and delamination detection

    NASA Astrophysics Data System (ADS)

    Jensen, Alf E.; Irgens, Fridtjov

    1998-06-01

    In multi-hull marine vehicles assembled by FRP sandwich composite materials problems with delamination and skin/core debonding are reported. High frequency vibrations in foam core sandwich materials are investigated to see if it was possible to apply them, together with bending vibrations, in an early damage warning system for delamination detection in marine vessels. This manuscript presents a theory for high frequency vibration in sandwich plates and beams. The core is modeled as a two parameter foundation with shearing interaction effects as well as normal stress effects in the core included. The skins are modeled as ordinary plates or beams on a foundation. Expressions for both anti-symmetric and symmetric modes are given. In addition to the theoretical development, experiments with a simply supported sandwich beam, using a TV-Holography technic, were performed and good accordance between theory and experiments were achieved. The results indicates that disappearance of symmetric modes may be used a parameter for delamination detection. The anti-symmetric modes may be interchangeable with higher bending modes by an early damage warning system. To avoid this, the theory presented may be applied to determine the anti-symmetric frequency values in forehand.

  3. Configurations of high-frequency ultrasonics complex vibration systems for packaging in microelectronics.

    PubMed

    Tsujino, Jiromaru; Harada, Yoshiki; Ihara, Shigeru; Kasahara, Kohei; Shimizu, Masanori; Ueoka, Tetsugi

    2004-04-01

    Ultrasonic high-frequency complex vibrations are effective for various ultrasonic high-power applications. Three types of ultrasonic complex vibration system with a welding tip vibrating elliptical to circular locus for packaging in microelectronics were studied. The complex vibration sources are using (1) a longitudinal-torsional vibration converter with diagonal slits that is driven only by a longitudinal vibration source, (2) a complex transverse vibration rod with several stepped parts that is driven by two longitudinal vibration source crossed at a right angle and (3) a longitudinal vibration circular disk and three longitudinal transducers that are installed at the circumference of the disk. PMID:15047273

  4. Simple posterior frequency correction for vibrational spectra from molecular dynamics

    NASA Astrophysics Data System (ADS)

    Tikhonov, Denis S.

    2016-05-01

    Vibrational spectra computed from molecular dynamics simulations with large integration time steps suffer from nonphysical frequency shifts of signals [M. Praprotnik and D. Janežič, J. Chem. Phys. 122, 174103 (2005)]. A simple posterior correction technique was developed for compensation of this behavior. It performs through replacement of abscissa in the calculated spectra using following formula: ν corrected = /√{ 2 ṡ (" separators=" 1 - cos ( 2 π ṡ Δ t ṡ ν initial ) ) } 2 π ṡ Δ t , where ν are initial and corrected frequencies and Δt is the MD simulation time step. Applicability of this method was tested on gaseous infrared spectra of hydrogen fluoride and formic acid.

  5. Calculation of mechanical vibration frequencies of stiffened superconducting cavities

    SciTech Connect

    Black, S.J.; Spalek, G.

    1992-09-01

    We calculated the frequencies of transverse and longitudinal mechanical-vibration modes of the HEPL- modified, CERN/DESY four-cell superconducting cavity, using finite-element techniques. We compared the results of these calculations, including the stiffening of the cavity with rods, with mode frequencies measured at HEPL. The correlation between data was significant. The same techniques were also used to design and optimize the stiffening scheme for the seven-cell 805-MHz superconducting cavity being developed at Los Alamos. In this report, we describe the final stiffening scheme and the results of our calculations.

  6. Calculation of mechanical vibration frequencies of stiffened superconducting cavities

    SciTech Connect

    Black, S.J.; Spalek, G.

    1992-01-01

    We calculated the frequencies of transverse and longitudinal mechanical-vibration modes of the HEPL- modified, CERN/DESY four-cell superconducting cavity, using finite-element techniques. We compared the results of these calculations, including the stiffening of the cavity with rods, with mode frequencies measured at HEPL. The correlation between data was significant. The same techniques were also used to design and optimize the stiffening scheme for the seven-cell 805-MHz superconducting cavity being developed at Los Alamos. In this report, we describe the final stiffening scheme and the results of our calculations.

  7. Low-frequency meandering piezoelectric vibration energy harvester.

    PubMed

    Berdy, David F; Srisungsitthisunti, Pornsak; Jung, Byunghoo; Xu, Xianfan; Rhoads, Jeffrey F; Peroulis, Dimitrios

    2012-05-01

    The design, fabrication, and characterization of a novel low-frequency meandering piezoelectric vibration energy harvester is presented. The energy harvester is designed for sensor node applications where the node targets a width-to-length aspect ratio close to 1:1 while simultaneously achieving a low resonant frequency. The measured power output and normalized power density are 118 μW and 5.02 μW/mm(3)/g(2), respectively, when excited by an acceleration magnitude of 0.2 g at 49.7 Hz. The energy harvester consists of a laser-machined meandering PZT bimorph. Two methods, strain-matched electrode (SME) and strain-matched polarization (SMP), are utilized to mitigate the voltage cancellation caused by having both positive and negative strains in the piezoelectric layer during operation at the meander's first resonant frequency. We have performed finite element analysis and experimentally demonstrated a prototype harvester with a footprint of 27 x 23 mm and a height of 6.5 mm including the tip mass. The device achieves a low resonant frequency while maintaining a form factor suitable for sensor node applications. The meandering design enables energy harvesters to harvest energy from vibration sources with frequencies less than 100 Hz within a compact footprint. PMID:22622969

  8. FT-IR Spectra Of The C=O And C-H Stretching Vibration Of Lauric Acid

    NASA Astrophysics Data System (ADS)

    Shifu, Weng; Jinguang, Wu; Guangxian, Xu

    1989-12-01

    FT-IR spectra of lauric acid in different media were examined. In very dilute solution of lauric acid in CC14, the two bands at 1711 and 1760 cm-1 the region 1650 to 1800 cm-1 were observed for the C=0 stretching modes of dimer and monomer of lauric acid, respectively. In n-butanol KBr pellet and fluorinated hydrocarbon media, the three bands at 1712, 1701 and 1687 cm-1 after deconvolution and curve analysis for the C=0 stretching mode can be observed. In the region of C-H stretching vibration, the wavenumber shifts of the CH2 symmetric and antisymmetric stretching bands of lauric acid in different media show that the packings of acyl chains of lauric acid in different media are not the same.

  9. Resonant frequency tuning of an industrial vibration energy harvester

    NASA Astrophysics Data System (ADS)

    Toh, T. T.; Wright, S. W.; Mitcheson, P. D.

    2014-11-01

    This paper presents preliminary results of tuning the resonant frequency of two industrial vibration energy harvesters. The VEH-450 from Ferro Solutions and the PMG17-50 from Perpetuum were tested using discrete reactive electrical loads. The former could be tuned to +0.5 Hz and -2 Hz from its natural resonant frequency of 50.5 Hz at 0.1g. The latter, however, has a broadband output power spectrum that spans ±10 Hz and its output voltage saturates at 7 Vrms, thereby rendering it un-tunable using the method presented here. A comparison of output power between a tuned VEH-450 and an un-tuned PMG17-50, normalised by harvester weight, shows that the former outperforms the latter only at a tuned frequency of 49.8 Hz. A discussion of a resonant frequency tuning circuit that can be fitted to an existing harvester without making modifications to the harvester is presented.

  10. Modeling low frequency vibrational modes of large biomolecules

    NASA Astrophysics Data System (ADS)

    Sankey, Otto; Dykeman, Eric

    2008-03-01

    Mechanical oscillations of proteins in their native state are relevant to understanding the flexibility of the protein assembly, the binding of substrates, the mechanical action involved in enzymatic activity, and the vibrational response to light scattering. Often, only the low frequency modes are of interest and coarse grained methods or other approximations are used due to the large size of the dynamical matrix. We introduce a computational approach, which exploits the methodology from electronic structure Order N methods, to find the vibrational modes below some frequency threshold (analogous to a Fermi-level in electronic structure theory). The approach allows systems to be described in atomistic detail. We use a generalized Born force field to model the interactions. Examples of normal modes for icosahedral viruses (e.g. satellite tobacco necrosis virus), tubular viruses (e.g. M13), and enzymes (e.g. lysozyme, HIV-protease, alpha-lytic protease) will be discussed. This effort is motivated by recent experimental work to produce high amplitude vibrations of viruses from impulsive stimulated Raman scattering.

  11. Vibrotactile difference thresholds: effects of vibration frequency, vibration magnitude, contact area, and body location.

    PubMed

    Forta, Nazim Gizem; Griffin, Michael J; Morioka, Miyuki

    2012-01-01

    It has not been established whether the smallest perceptible change in the intensity of vibrotactile stimuli depends on the somatosensory channel mediating the sensation. This study investigated intensity difference thresholds for vibration using contact conditions (different frequencies, magnitudes, contact areas, body locations) selected so that perception would be mediated by more than one psychophysical channel. It was hypothesized that difference thresholds mediated by the non-Pacinian I (NPI) channel and the Pacinian (P) channel would differ. Using two different contactors (1-mm diameter contactor with 1-mm gap to a fixed surround; 10-mm diameter contactor with 2-mm gap to the surround) vibration was applied to the thenar eminence and the volar forearm at two frequencies (10 and 125 Hz). The up-down-transformed-response method with a three-down-one-up rule provided absolute thresholds and also difference thresholds at various levels above the absolute thresholds of 12 subjects (i.e., sensation levels, SLs) selected to activate preferentially either single channels or multiple channels. Median difference thresholds varied from 0.20 (thenar eminence with 125-Hz vibration at 10 dB SL) to 0.58 (thenar eminence with 10-Hz vibration at 20 dB SL). Median difference thresholds tended to be lower for the P channel than the NPI channel. The NPII channel may have reduced difference thresholds with the smaller contactor at 125 Hz. It is concluded that there are large and systematic variations in difference thresholds associated with the frequency, the magnitude, the area of contact, and the location of contact with vibrotactile stimuli that cannot be explained without increased understanding of the perception of supra-threshold vibrotactile stimuli. PMID:22416802

  12. Black phosphorus nanoelectromechanical resonators vibrating at very high frequencies

    NASA Astrophysics Data System (ADS)

    Wang, Zenghui; Jia, Hao; Zheng, Xuqian; Yang, Rui; Wang, Zefang; Ye, G. J.; Chen, X. H.; Shan, Jie; Feng, Philip X.-L.

    2014-12-01

    We report on the experimental demonstration of a new type of nanoelectromechanical resonator based on black phosphorus crystals. Facilitated by a highly efficient dry transfer technique, crystalline black phosphorus flakes are harnessed to enable drumhead resonators vibrating at high and very high frequencies (HF and VHF bands, up to ~100 MHz). We investigate the resonant vibrational responses from the black phosphorus crystals by devising both electrical and optical excitation schemes, in addition to measuring the undriven thermomechanical motions in these suspended nanostructures. Flakes with thicknesses from ~200 nm down to ~20 nm clearly exhibit elastic characteristics transitioning from the plate to the membrane regime. Both frequency- and time-domain measurements of the nanomechanical resonances show that very thin black phosphorus crystals hold interesting potential for moveable and vibratory devices and for semiconductor transducers where high-speed mechanical motions could be coupled to the attractive electronic and optoelectronic properties of black phosphorus.We report on the experimental demonstration of a new type of nanoelectromechanical resonator based on black phosphorus crystals. Facilitated by a highly efficient dry transfer technique, crystalline black phosphorus flakes are harnessed to enable drumhead resonators vibrating at high and very high frequencies (HF and VHF bands, up to ~100 MHz). We investigate the resonant vibrational responses from the black phosphorus crystals by devising both electrical and optical excitation schemes, in addition to measuring the undriven thermomechanical motions in these suspended nanostructures. Flakes with thicknesses from ~200 nm down to ~20 nm clearly exhibit elastic characteristics transitioning from the plate to the membrane regime. Both frequency- and time-domain measurements of the nanomechanical resonances show that very thin black phosphorus crystals hold interesting potential for moveable and vibratory

  13. High force vibration testing with wide frequency range

    DOEpatents

    Romero, Edward F.; Jepsen, Richard A.; Gregory, Danny Lynn

    2013-04-02

    A shaker assembly for vibration testing includes first and second shakers, where the first shaker includes a piezo-electric material for generating vibration. A support structure permits a test object to be supported for vibration of the test object by both shakers. An input permits an external vibration controller to control vibration of the shakers.

  14. Simple posterior frequency correction for vibrational spectra from molecular dynamics.

    PubMed

    Tikhonov, Denis S

    2016-05-01

    Vibrational spectra computed from molecular dynamics simulations with large integration time steps suffer from nonphysical frequency shifts of signals [M. Praprotnik and D. Janežič, J. Chem. Phys. 122, 174103 (2005)]. A simple posterior correction technique was developed for compensation of this behavior. It performs through replacement of abscissa in the calculated spectra using following formula: νcorrected=2⋅1-cos(2π⋅Δt⋅νinitial)2π⋅Δt, where ν are initial and corrected frequencies and Δt is the MD simulation time step. Applicability of this method was tested on gaseous infrared spectra of hydrogen fluoride and formic acid. PMID:27155626

  15. Robust optical fiber bending sensor to measure frequency of vibration

    NASA Astrophysics Data System (ADS)

    Hernández-Serrano, Arturo Ignacio; Salceda-Delgado, Guillermo; Moreno-Hernández, David; Martínez-Ríos, Alejandro; Monzón-Hernández, David

    2013-09-01

    A simple technique for sensing the acoustic vibration of a cantilever beam, using a single-fiber Mach-Zehnder interferometer, is presented. The interferometer consists of two concatenated low-loss fused fiber tapers, with a waist diameter of 60 μm, separated by an un-tapered fiber section of 10 mm length. The interferometer transmitted signal is modulated when the device is bent under the presence of an external acoustic signal. The optical fiber device glued directly on a metallic cantilever beam is capable of measuring frequency of the resonant modes. The interrogation set-up is simple consisting of a single tunable diode laser and a photodetector. The measured frequencies of the resonating modes agree with the numerical results obtained by the Finite Element Method.

  16. Precise Measurement of Vibrational Transition Frequency of Optically Trapped Molecules

    NASA Astrophysics Data System (ADS)

    Kajita, Masatoshi; Gopakumar, Geetha; Abe, Minori; Hada, Masahiko

    2013-06-01

    We propose to measure the X^{2}Σ(v,N,F,M) =( 0,0,3/2,±3/2) →( v_{u},0,3/2,±3/2) ( v_{u}=1,2,3,4,,,,) transition frequencies of X^{6}Li molecules with the uncertainty lower than 10^{-16} (X: ^{174}Yb, ^{88}Sr, ^{40}Ca). Molecules are produced by photo-association of cold atoms and trapped in the optical lattices. Measurement with molecules in optical lattices is particularly advantageous for precision measurements because (1) the molecules and probe laser interact for a long time, (2) molecules are localized within the Lamb-Dicke region, (3) the measurement is possible with a large number of molecules, and (4) collision effects are suppressed (molecules are trapped at different positions in 2D lattices). Using the proper trap laser frequency, the Stark shift induced by the trap laser is eliminated as the Stark energy shift of the upper and lower states are equal (magic frequency). When the trap laser frequency is shifted from the magic frequency by 1 MHz, the Stark shift is less than 3×10^{-15}. The N=0→0 transition is one-photon forbidden, and it is stimulated by Raman transition using two lasers. When one of two Raman lasers is higher than the magic frequency and another is lower, the total Stark shift induced by two Raman lasers can be eliminated. Measurement of molecular vibrational transition frequencies is useful to test the variation in the proton-to-electron mass ratio. The ^{1}S_{0}-^{3}% P_{0} transition frequencies of ^{27}Al^{+} ion or ^{87}Sr atom are useful as the reference.

  17. A Study on the Vibration Frequency of Blasting Excavation in Highly Stressed Rock Masses

    NASA Astrophysics Data System (ADS)

    Yang, Jianhua; Lu, Wenbo; Jiang, Qinghui; Yao, Chi; Jiang, Shuihua; Tian, Lin

    2016-07-01

    During blasting excavation in deep-buried tunnels and mines characterized by high in situ stress, the rock vibration is attributed not only to blast loading, but also to dynamic unloading caused by transient release of the in situ stress on excavation faces in the process of rock fragmentation by blasting. Understanding the vibration frequency characteristics under these two excitation sources is of important signification to determine appropriate vibration threshold limits for structure damage in deep-buried opening excavations. With a theoretical model developed for a deep-buried circular tunnel excavation by the millisecond delay blasting sequence, frequency characteristics and their influence factors are investigated and discussed for the vibrations induced by the blast loading, the dynamic unloading and the combined effects, respectively. The results show that the rising time of blast loading, the duration of dynamic unloading and the dimension of excavation boundaries are the main factors that affect the vibration frequency of blasting excavation in highly stressed rock masses. It is found that, the blast loading with a much shorter rising time accentuates higher vibration frequency than the dynamic unloading with a long duration, and it causes the blast loading vibration to be more readily attenuated as the propagation distance increases. Thus, the unloading vibration may become the main vibration component at far distances where its low-frequency vibration may exceed the vibration limits. The vibration induced by the combined effects has two distinctly dominant frequency bands corresponding to the two vibration excitation sources. The frequency analyses of the vibration records from two underground projects excavated by blasting are presented to demonstrate this finding. The findings of this study also clearly reveal that, reducing the dimension of excavation boundaries is one of the most effective means to prevent the vibrational damage to structures as it

  18. A Miniature Surgical Drill Using Ultrasonic/Sonic Frequency Vibration

    NASA Astrophysics Data System (ADS)

    Li, Li; Mathieson, Andrew; Lucas, Margaret

    A study is presented of a miniature ultrasonic surgical drill designed for bone biopsy, based on an ultrasonic/sonic drill which converts high frequency to low frequency vibrations through a freely vibrating mass between an ultrasonic transducer-horn and a drill bit. For conventional surgical drilling using a rotary drill or an ultrasonic drill, considerable power is required to penetrate into bone and the efficiency is low. However, for ultrasonic/sonic drilling, sufficient acoustic energy is accumulated and then released through each impact to achieve precise drilling with a lower power requirement. The ultrasonic/sonic drill was originally invented for rock drilling in low gravity environments. In this study it is incorporated in a miniature ultrasonic surgical drill and the effective impulse delivered to the bone is used to evaluate the drilling performance. To develop a miniature surgical device based on maximising the effective impulse, optimisation of the ultrasonic horn and free-mass is first demonstrated. The shape and dimensions of the ultrasonic horn and free-mass are determined through FEA, which focuses on maximising the post-collision velocity of the free-mass. Then, the entire dynamic stack constituting the surgical drill device is modelled as a mass-spring-damper system to analyse the dynamic behaviour. The numerical model is validated through experiments, using a prototype drill, which record the velocity of the free-mass and the drilling force. The results of the numerical models and experiments indicate this miniature ultrasonic surgical drill can deliver sufficient impulse to penetrate bone and form the basis of an ultrasonically activated bone biopsy device.

  19. Characteristics of coated copper wire specimens using high frequency ultrasonic complex vibration welding equipments.

    PubMed

    Tsujino, J; Ihara, S; Harada, Y; Kasahara, K; Sakamaki, N

    2004-04-01

    Welding characteristic of thin coated copper wires were studied using 40, 60, 100 kHz ultrasonic complex vibration welding equipments with elliptical to circular vibration locus. The complex vibration systems consisted of a longitudinal-torsional vibration converter and a driving longitudinal vibration system. Polyurethane coated copper wires of 0.036 mm outer diameter and copper plates of 0.3 mm thickness and the other dimension wires were used as welding specimens. The copper wire part is completely welded on the copper substrate and the insulated coating material is driven from welded area to outsides of the wire specimens by high frequency complex vibration. PMID:15047272

  20. Interpretation of the water surface vibrational sum-frequency spectrum

    NASA Astrophysics Data System (ADS)

    Pieniazek, P. A.; Tainter, C. J.; Skinner, J. L.

    2011-07-01

    We propose a novel interpretation of the water liquid-vapor interface vibrational sum-frequency (VSF) spectrum in terms of hydrogen-bonding classes. Unlike an absorption spectrum, the VSF signal can be considered as a sum of signed contributions from different hydrogen-bonded species in the sample. We show that the recently observed positive feature at low frequency, in the imaginary part of the signal, is a result of cancellation between the positive contributions from four-hydrogen-bonded molecules and negative contributions from those molecules with one or two broken hydrogen bonds. Spectral densities for each of these subgroups span the entire relevant spectral range. Three-body interactions within our newly developed E3B water simulation model prove to be critical in describing the proper balance between different hydrogen-bonded species, as (two-body) SPC/E, TIP4P, and TIP4P/2005 models fail to reproduce the positive feature. The results clarify the molecular origin of the VSF signal, and highlight the importance of many-body interactions for water in heterogeneous situations.

  1. Fundamental Study on the Effect of High Frequency Vibration on Ride Comfort

    NASA Astrophysics Data System (ADS)

    Nakagawa, Chizuru; Shimamune, Ryohei; Watanabe, Ken; Suzuki, Erimitsu

    To develop a more suitable method of evaluating ride comfort of high speed trains, a fundamental study was conducted on sensitivity of passengers to various frequencies of vibration with respect to ride comfort. Experiments were performed on 55 subjects using an electrodynamic vibration system that can generate vibrations in the frequency range of 1 to 80 Hz in the vertical direction. Results of experiments indicated that the subjects tend to experience greater discomfort when exposed to high frequency vibrations than that presumed by the conventional Japanese ride comfort assessment method, the "Ride Comfort Level."

  2. Micro-scale piezoelectric vibration energy harvesting: From fixed-frequency to adaptable-frequency devices

    NASA Astrophysics Data System (ADS)

    Miller, Lindsay Margaret

    hundred milliwatts and are falling steadily as improvements are made, it is feasible to use energy harvesting to power WSNs. This research begins by presenting the results of a thorough survey of ambient vibrations in the machine room of a large campus building, which found that ambient vibrations are low frequency, low amplitude, time varying, and multi-frequency. The modeling and design of fixed-frequency micro scale energy harvesters are then presented. The model is able to take into account rotational inertia of the harvester's proof mass and it accepts arbitrary measured acceleration input, calculating the energy harvester's voltage as an output. The fabrication of the micro electromechanical system (MEMS) energy harvesters is discussed and results of the devices harvesting energy from ambient vibrations are presented. The harvesters had resonance frequencies ranging from 31 - 232 Hz, which was the lowest reported in literature for a MEMS device, and produced 24 pW/g2 - 10 nW/g2 of harvested power from ambient vibrations. A novel method for frequency modification of the released harvester devices using a dispenser printed mass is then presented, demonstrating a frequency shift of 20 Hz. Optimization of the MEMS energy harvester connected to a resistive load is then presented, finding that the harvested power output can be increased to several microwatts with the optimized design as long as the driving frequency matches the harvester's resonance frequency. A framework is then presented to allow a similar optimization to be conducted with the harvester connected to a synchronously switched pre-bias circuit. With the realization that the optimized energy harvester only produces usable amounts of power if the resonance frequency and driving frequency match, which is an unrealistic situation in the case of ambient vibrations which change over time and are not always known a priori, an adaptable-frequency energy harvester was designed. The adaptable-frequency

  3. Evaluation of influences of frequency and amplitude on image degradation caused by satellite vibrations

    NASA Astrophysics Data System (ADS)

    Nan, Yi-Bing; Tang, Yi; Zhang, Li-Jun; Zheng, Cheng; Wang, Jing

    2015-05-01

    Satellite vibrations during exposure will lead to pixel aliasing of remote sensors, resulting in the deterioration of image quality. In this paper, we expose the problem and discuss the characteristics of satellite vibrations, and then present a pixel mixing model. The idea of mean mixing ratio (MMR) is proposed. MMR computations for different frequencies are implemented. In the mixing model, a coefficient matrix is introduced to estimate each mixed pixel. Thus, the simulation of degraded image can be performed when the vibration attitudes are known. The computation of MMR takes into consideration the influences of various frequencies and amplitudes. Therefore, the roles of these parameters played in the degradation progress are identified. Computations show that under the same vibration amplitude, the influence of vibrations fluctuates with the variation of frequency. The fluctuation becomes smaller as the frequency rises. Two kinds of vibration imaging experiments are performed: different amplitudes with the same frequency and different frequencies with the same amplitude. Results are found to be in very good agreement with the theoretical results. MMR has a better description of image quality than modulation transfer function (MTF). The influence of vibrations is determined mainly by the amplitude rather than the frequency. The influence of vibrations on image quality becomes gradually stable with the increase of frequency. Project supported by the National Basic Research Program of China (Grant No. 2013CB329202) and the Basic Industrial Technology Project of China (Grant No. J312012B002).

  4. Precise Measurement of ^{40}CaH^{+} Vibrational Transition Frequency

    NASA Astrophysics Data System (ADS)

    Kajita, Masatoshi; Abe, Minori

    2013-06-01

    Small number of molecular ions in a linear trap can be sympathetically cooled with atomic ions and form a string crystal at the position, where the electric field is zero. Molecular ions in a strinc crystal are advantageous to measure the transition frequencies without Stark shift induced by the trap electric field, but it is required to localize small number of molecular ions in a single quantum state. ^{40}CaH^{+} molecular ion is advantageous to solve this problem, because (1) molecular ion with rotational constant of 141 GHz is localized in the vibrational-rotational ground state when the surrounding temperature is lower than 10 K, and (2) there is no hyperfine splitting in the J=0 state. In this presentation, we porpose to measure the ^{40}CaH^{+} X^{1}% Σ( v,N,F,M) =(0,0,1/2,±1/2) → (v_{u},0,1/2,±1/2) (v_{u}=1,2,3,,,) transition with the uncertainty lower than 10^{-16}. With these transitions, Zeeman shift is less than 10^{-16}/G (given by the slight dependence of schielding effect by electron cloud on the vibrational state) and electric quadrupole shift is zero because of F=1/2. The J=0→0 transition is one-photon forbidden, and it can be observed also by Raman transition using two lasers. Stark shift induced by Raman lasers actually dominates the measurement uncertainty. When v=0→1 transition is observed using Raman lasers in the 6000-15000 /cm, Stark shift with saturation power is of the order of 1.5×10^{-14} and it is higher for overtone transitions. With the following Raman laser frequencies, total Stark shift induced by two Raman lasers is zero. v=0→1 24527 /cm and 23079 /cm v=0→2 24600 /cm and 21745 /cm v=0→3 26237 /cm and 22017 /cm v=0→4 25354 /cm and 19814 /cm The ^{40}CaH^{+} X^{1}Σ( v,N,F,M) =(0,0,1/2,±1/2) →(v_{u},0,1/2,±1/2) (v_{u}=1,2,3,,,) transition can be measured with the uncertainty lower than 10^{-16}, and it is useful to test the variation in the proton-to-electron mass ratio.

  5. The effects of transverse shearing and anisotropy on vibration frequencies of laminated cylinders

    NASA Technical Reports Server (NTRS)

    Jegley, D. C.

    1990-01-01

    The natural vibration frequencies of orthotropic and anisotropic, simply supported right circular cylinders are predicted using a theory which takes into account higher-order transverse shear deformation effects. A comparison between results based on first-order transverse shear deformation theory and the higher-order theory indicates that an additional allowance for transverse shear deformation has a negligible effect on the predicted natural vibration frequencies associated with long wavelengths, but significantly reduces the natural vibration frequencies associated with short wavelengths. Results of a parametric study of ply orientation for two classes of laminates indicates that while stacking sequence affects natural vibration frequencies, cylinder geometry and mode shape are more important in accurately predicting transverse shear deformation effects. Transverse shearing effects are less important in predicting natural vibration frequencies associated with long wavelength than in predicting axial compressive buckling loads.

  6. Examining the impact of harmonic correlation on vibrational frequencies calculated in localized coordinates

    SciTech Connect

    Hanson-Heine, Magnus W. D.

    2015-10-28

    Carefully choosing a set of optimized coordinates for performing vibrational frequency calculations can significantly reduce the anharmonic correlation energy from the self-consistent field treatment of molecular vibrations. However, moving away from normal coordinates also introduces an additional source of correlation energy arising from mode-coupling at the harmonic level. The impact of this new component of the vibrational energy is examined for a range of molecules, and a method is proposed for correcting the resulting self-consistent field frequencies by adding the full coupling energy from connected pairs of harmonic and pseudoharmonic modes, termed vibrational self-consistent field (harmonic correlation). This approach is found to lift the vibrational degeneracies arising from coordinate optimization and provides better agreement with experimental and benchmark frequencies than uncorrected vibrational self-consistent field theory without relying on traditional correlated methods.

  7. Sum frequency generation vibrational spectroscopic studies on buried heterogeneous biointerfaces.

    PubMed

    Zhang, Chi; Jasensky, Joshua; Leng, Chuan; Del Grosso, Chelsey; Smith, Gary D; Wilker, Jonathan J; Chen, Zhan

    2014-05-01

    A sum frequency generation (SFG) vibrational micro-spectroscopy system was developed to examine buried heterogeneous biointerfaces. A compact optical microscope was constructed with total-internal reflection (TIR) SFG geometry to monitor the tightly focused SFG laser spots on interfaces, providing the capability of selectively probing different regions on heterogeneous biointerfaces. The TIR configuration ensures and enhances the SFG signal generated only from the sample/substrate interfacial area. As an example for possible applications in biointerfaces studies, the system was used to probe and compare buried interfacial structures of different biological samples attached to underwater surfaces. We studied the interface of a single mouse oocyte on a silica prism to demonstrate the feasibility of tracing and studying a single live cell and substrate interface using SFG. We also examined the interface between a marine mussel adhesive plaque and a CaF2 substrate, showing the removal of interface-bonded water molecules. This work also paves the way for future integration of other microscopic techniques such as TIR-fluorescence microscopy or nonlinear optical imaging with SFG spectroscopy for multimodal surface or interface studies. PMID:24784085

  8. Suppression of Leidenfrost effect via low frequency vibrations

    NASA Astrophysics Data System (ADS)

    Ng, Boon Thiam; Hung, Yew Mun; Tan, Ming Kwang

    2015-11-01

    Leidenfrost effect occurs when vapor layer forms in between the coolant and the hot surface above Leidenfrost point, which dramatically reduces the cooling efficiency due to low thermal conductivity of the vapor layer. To prevent surface overheating, there have been number of reported methods to suppress the Leidenfrost effect that were mainly based on functionalization of the substrate surface and application of electric field across the droplet and substrate. In this work, we induce low frequency vibrations (f ~ 100 Hz) to the heated substrate to suppress the Leidenfrost effect. Three distinct impact dynamics are observed based on different magnitudes of surface acceleration and surface temperature. In gentle film boiling regime, formation of thin spreading lamella around the periphery of the impinged droplet is observed; in film boiling regime, due to thicker vapor cushion, rebound of the impinged droplet is observed; in contact boiling regime, due to the direct contact between the impinged droplet and heated substrate, ejection of the tiny droplet is observed. Also, estimated cooling enhancement ratio for contact boiling regime shows an improvement from 95% to 105%.

  9. Investigating buried polymer interfaces using sum frequency generation vibrational spectroscopy

    PubMed Central

    Chen, Zhan

    2010-01-01

    This paper reviews recent progress in the studies of buried polymer interfaces using sum frequency generation (SFG) vibrational spectroscopy. Both buried solid/liquid and solid/solid interfaces involving polymeric materials are discussed. SFG studies of polymer/water interfaces show that different polymers exhibit varied surface restructuring behavior in water, indicating the importance of probing polymer/water interfaces in situ. SFG has also been applied to the investigation of interfaces between polymers and other liquids. It has been found that molecular interactions at such polymer/liquid interfaces dictate interfacial polymer structures. The molecular structures of silane molecules, which are widely used as adhesion promoters, have been investigated using SFG at buried polymer/silane and polymer/polymer interfaces, providing molecular-level understanding of polymer adhesion promotion. The molecular structures of polymer/solid interfaces have been examined using SFG with several different experimental geometries. These results have provided molecular-level information about polymer friction, adhesion, interfacial chemical reactions, interfacial electronic properties, and the structure of layer-by-layer deposited polymers. Such research has demonstrated that SFG is a powerful tool to probe buried interfaces involving polymeric materials, which are difficult to study by conventional surface sensitive analytical techniques. PMID:21113334

  10. An Analysis of the High Frequency Vibrations in Early Thematic Mapper Scenes

    NASA Technical Reports Server (NTRS)

    Kogut, J.; Larduinat, E.

    1984-01-01

    The potential effects of high frequency vibrations on the final Thematic Mapper (TM) image are evaluated for 26 scenes. The angular displacements of the TM detectors from their nominal pointing directions as measured by the TM Angular Displacement Sensor (ADS) and the spacecraft Dry Rotor Inertial Reference Unit (DRIRU) give data on the along scan and cross scan high frequency vibrations present in each scan of a scene. These measurements are to find the maximum overlap and underlap between successive scans, and to analyze the spectrum of the high frequency vibrations acting on the detectors. The Fourier spectrum of the along scan and cross scan vibrations for each scene also evaluated. The spectra of the scenes examined indicate that the high frequency vibrations arise primarily from the motion of the TM and MSS mirrors, and that their amplitudes are well within expected ranges.

  11. Active low-frequency vertical vibration isolation system for precision measurements

    NASA Astrophysics Data System (ADS)

    Wu, Kang; Li, Gang; Hu, Hua; Wang, Lijun

    2016-06-01

    Low-frequency vertical vibration isolation systems play important roles in precision measurements to reduce seismic and environmental vibration noise. Several types of active vibration isolation systems have been developed. However, few researches focus on how to optimize the test mass install position in order to improve the vibration transmissibility. An active low-frequency vertical vibration isolation system based on an earlier instrument, the Super Spring, is designed and implemented. The system, which is simple and compact, consists of two stages: a parallelogram-shaped linkage to ensure vertical motion, and a simple spring-mass system. The theoretical analysis of the vibration isolation system is presented, including terms erroneously ignored before. By carefully choosing the mechanical parameters according to the above analysis and using feedback control, the resonance frequency of the system is reduced from 2.3 to 0.03 Hz, a reduction by a factor of more than 75. The vibration isolation system is installed as an inertial reference in an absolute gravimeter, where it improved the scatter of the absolute gravity values by a factor of 5. The experimental results verifies the improved performance of the isolation system, making it particularly suitable for precision experiments. The improved vertical vibration isolation system can be used as a prototype for designing high-performance active vertical isolation systems. An improved theoretical model of this active vibration isolation system with beam-pivot configuration is proposed, providing fundamental guidelines for vibration isolator design and assembling.

  12. Temperature-dependent vibrational dephasing: Comparison of liquid and glassy solvents using frequency-selected vibrational echoes

    NASA Astrophysics Data System (ADS)

    Xu, Qing-Hua; Fayer, M. D.

    2002-08-01

    Frequency-selected vibrational echo experiments were used to investigate the temperature dependences of vibrational dephasing associated with the 0-1 transition of the CO stretching mode of RuTPPCOPy (TPP=5,10,15,20-tetraphenylporphyrin, Py=pyridine) in two solvents: polymethylmethacrylate (PMMA) and 2-methyltetrahydrofuran (2-MTHF). In PMMA, a glass, the echo decay is exponential at all the temperatures studied, and the dephasing rate increases linearly with increasing temperature. In 2-MTHF, there is a change in the functional form of the temperature dependence when the solvent goes through the glass transition temperature (Tg). Below Tg, the dephasing rate increases linearly with temperature, while above Tg, it rises very steeply in a nonlinear manner. In the liquid at higher temperatures, the vibrational echo decays are nonexponential. A model frequency-frequency correlation function (FFCF) is proposed in which the FFCF differs for a glass and a liquid because of the intrinsic differences in the nature of the dynamics. At least two motions, inertial and diffusive, contribute to the vibrational dephasing in the liquids. The different temperature dependences of inertial and diffusive motions are discussed. Comparison of the model calculations of the vibrational echo temperature dependence and the data show reasonable, but not quantitative agreement.

  13. Multi-frequency periodic vibration suppressing in active magnetic bearing-rotor systems via response matching in frequency domain

    NASA Astrophysics Data System (ADS)

    Jiang, Kejian; Zhu, Changsheng

    2011-05-01

    A method for multi-frequency periodic vibration suppressing in active magnetic bearing (AMB)-rotor systems is proposed, which is based on an adaptive finite-duration impulse response (FIR) filter in time domain. Firstly, the theoretic feasibility of the method is proved. However, two problems would be unavoidable, if the conventional adaptive FIR filter is adopted in practical application. One is that the convergence rate of the different frequency components may be highly disparate in multi-frequency vibration control. The other is that the computational complexity is significantly increased because the long memory FIR filter is required to match the transient response time of the AMB-rotor system. To overcome the problems above, the Fast Block Least Mean Square (FBLMS) algorithm is adopted to efficiently implement the computation in frequency domain at a computational cost far less than that of the conventional FIR filter. By the FBLMS algorithm, regardless of the number of the considered frequency components in vibration disturbance, the computational complexity would be invariable. Moreover, filter's weights in the FBLMS algorithm have the intuitional relation with signal's frequency. As a result, the convergence rate of each frequency component can be adjusted by assigning the individual step size parameter for each weight. Experiments with the reciprocating simulating disturbance test and the rotating harmonic vibration test were carried out on an AMB-rigid rotor test rig with a vertical shaft. The experiment results indicate that the proposed method with the FBLMS algorithm can achieve the good effectiveness for suppressing the multi-frequency vibration. The convergence property of each frequency component can be adjusted conveniently. Each harmonic component of the vibration can be addressed, respectively, by reconfiguring the frequency components of the reference input signal.

  14. Modeling of metallic surface topography modification by high-frequency vibration

    NASA Astrophysics Data System (ADS)

    Yao, Zhehe; Mei, Deqing; Chen, Zichen

    2016-02-01

    High-frequency vibration is capable of modifying metallic surface topography significantly, while the underlying mechanisms are still unclear. In this study, the acoustic softening effect is considered to explain and model the effects of high-frequency normal vibration on surface topography. The surface asperities can be softened by the high-frequency vibration due to acoustic softening, leading to the enhancement of surface topography modification. A theoretical model for metallic surface topography modification by high-frequency vibration is proposed based on the acoustic plasticity. Numerical predictions of surface roughness evolution were conducted under various working conditions based on the model developed. It was found that the reduction of surface roughness (RSR) after vibration-assisted forming was affected by static stress, vibration amplitude, material properties and initial specimen surface roughness. The predictions using the developed model were compared with experimental data. Results showed that the predicted RSR agreed well with the experimental results, indicating that the analytical model is able to accurately capture surface topography evolution during vibration-assisted metal forming. This study provides a basis for understanding the underlying mechanisms of surface topography modification in vibration-assisted manufacturing.

  15. TOPICAL REVIEW: Strategies for increasing the operating frequency range of vibration energy harvesters: a review

    NASA Astrophysics Data System (ADS)

    Zhu, Dibin; Tudor, Michael J.; Beeby, Stephen P.

    2010-02-01

    This review presents possible strategies to increase the operational frequency range of vibration-based micro-generators. Most vibration-based micro-generators are spring-mass-damper systems which generate maximum power when the resonant frequency of the generator matches the frequency of the ambient vibration. Any difference between these two frequencies can result in a significant decrease in generated power. This is a fundamental limitation of resonant vibration generators which restricts their capability in real applications. Possible solutions include the periodic tuning of the resonant frequency of the generator so that it matches the frequency of the ambient vibration at all times or widening the bandwidth of the generator. Periodic tuning can be achieved using mechanical or electrical methods. Bandwidth widening can be achieved using a generator array, a mechanical stopper, nonlinear (e.g. magnetic) springs or bi-stable structures. Tuning methods can be classified into intermittent tuning (power is consumed periodically to tune the device) and continuous tuning (the tuning mechanism is continuously powered). This review presents a comprehensive review of the principles and operating strategies for increasing the operating frequency range of vibration-based micro-generators presented in the literature to date. The advantages and disadvantages of each strategy are evaluated and conclusions are drawn regarding the relevant merits of each approach.

  16. Storage capacity and vibration frequencies of guest molecules in CH4 and CO2 hydrates by first-principles calculations.

    PubMed

    Cao, Xiaoxiao; Su, Yan; Liu, Yuan; Zhao, Jijun; Liu, Changling

    2014-01-01

    Using first-principle calculations at B97-D/6-311++G(2d,2p) level, we systematically explore the gas capacity of five standard water cavities (5(12), 4(3)5(6)6(3), 5(12)6(2), 5(12)6(4), and 5(12)6(8)) in clathrate hydrate and study the inclusion complexes to infer general trends in vibrational frequencies of guest molecules as a function of cage size and number of guest molecules. In addition, the Raman spectra of hydrates from CO2/CH4 gases are simulated. From our calculations, the maximum cage occupancy of the five considered cages (5(12), 4(3)5(6)6(3), 5(12)6(2), 5(12)6(4), and 5(12)6(8)) is one, one, two, three, and seven for both CH4 and CO2 guest molecules, respectively. Meanwhile, the optimum cage occupancy are one, one, one, two, and four for CO2 molecules and one, one, two, three, and five for CH4 molecules, respectively. Both the C-H stretching frequency of CH4 and the C-O stretching frequency of CO2 gradually decrease as size of the water cages increases. Meanwhile, the C-H stretching frequency gradually increases as the amount of CH4 molecules in the water cavity (e.g., 5(12)6(8)) increases. PMID:24320601

  17. Application of range imaging lidar for measurement of mechanical vibration and frequency mode distribution

    NASA Astrophysics Data System (ADS)

    Zhang, Hua A.; Zhu, Yonghao; He, Yun

    1993-05-01

    This article reports the application of laser range imaging radar in the measurement of mechanical vibration frequency and the mode distribution, and the periodic motion of the mechanical parts such as a piston rod. The principle of the laser range imaging radar is based on the phase shift of the reflected amplitude modulated laser beam. The mechanical vibration frequency up to 20 KHZ and the minimal retrieved amplitude (or the motion displacement) of 0.5 mm have been achieved with the laser modulating frequency of 40 MHZ. With appropriate modulating frequency, this laser range system can measure the mechanical vibration amplitude, or the moving displacement, from 10-1 mm up to 102 mm, or even higher to the order of meters, which will be useful to measure the vibration and the periodic motion of machines and their parts for field test.

  18. The low frequency 2D vibration sensor based on flat coil element

    SciTech Connect

    Djamal, Mitra; Sanjaya, Edi; Islahudin; Ramli

    2012-06-20

    Vibration like an earthquake is a phenomenon of physics. The characteristics of these vibrations can be used as an early warning system so as to reduce the loss or damage caused by earthquakes. In this paper, we introduced a new type of low frequency 2D vibration sensor based on flat coil element that we have developed. Its working principle is based on position change of a seismic mass that put in front of a flat coil element. The flat coil is a part of a LC oscillator; therefore, the change of seismic mass position will change its resonance frequency. The results of measurements of low frequency vibration sensor in the direction of the x axis and y axis gives the frequency range between 0.2 to 1.0 Hz.

  19. MEASUREMENT OF SMALL MECHANICAL VIBRATIONS OF BRAIN TISSUE EXPOSED TO EXTREMELY-LOW-FREQUENCY ELECTRIC FIELDS

    EPA Science Inventory

    Electromagnetic fields can interact with biological tissue both electrically and mechanically. This study investigated the mechanical interaction between brain tissue and an extremely-low-frequency (ELF) electric field by measuring the resultant vibrational amplitude. The exposur...

  20. Dual resonant structure for energy harvesting from random vibration sources at low frequency

    NASA Astrophysics Data System (ADS)

    Li, Shanshan; Peng, Zhuoteng; Zhang, Ai; Wang, Fei

    2016-01-01

    We introduce a design with dual resonant structure which can harvest energy from random vibration sources at low frequency range. The dual resonant structure consists of two spring-mass subsystems with different frequency responses, which exhibit strong coupling and broad bandwidth when the two masses collide with each other. Experiments with piezoelectric elements show that the energy harvesting device with dual resonant structure can generate higher power output than the sum of the two separate devices from random vibration sources.

  1. Effects of fundamental frequency normalization on vibration-based vehicle classification

    NASA Astrophysics Data System (ADS)

    Smith, Ashley; Goley, Steve; Vongsy, Karmon; Shaw, Arnab; Dierking, Matthew

    2015-05-01

    Vibrometry offers the potential to classify a target based on its vibration spectrum. Signal processing is necessary for extracting features from the sensing signal for classification. This paper investigates the effects of fundamental frequency normalization on the end-to-end classification process [1]. Using the fundamental frequency, assumed to be the engine's firing frequency, has previously been used successfully to classify vehicles [2, 3]. The fundamental frequency attempts to remove the vibration variations due to the engine's revolution per minute (rpm) changes. Vibration signatures with and without fundamental frequency are converted to ten features that are classified and compared. To evaluate the classification performance confusion matrices are constructed and analyzed. A statistical analysis of the features is also performed to determine how the fundamental frequency normalization affects the features. These methods were studied on three datasets including three military vehicles and six civilian vehicles. Accelerometer data from each of these data collections is tested with and without normalization.

  2. A programmable broadband low frequency active vibration isolation system for atom interferometry.

    PubMed

    Tang, Biao; Zhou, Lin; Xiong, Zongyuan; Wang, Jin; Zhan, Mingsheng

    2014-09-01

    Vibration isolation at low frequency is important for some precision measurement experiments that use atom interferometry. To decrease the vibrational noise caused by the reflecting mirror of Raman beams in atom interferometry, we designed and demonstrated a compact stable active low frequency vibration isolation system. In this system, a digital control subsystem is used to process and feedback the vibration measured by a seismometer. A voice coil actuator is used to control and cancel the motion of a commercial passive vibration isolation platform. With the help of field programmable gate array-based control subsystem, the vibration isolation system performed flexibly and accurately. When the feedback is on, the intrinsic resonance frequency of the system will change from 0.8 Hz to about 0.015 Hz. The vertical vibration (0.01-10 Hz) measured by the in-loop seismometer is reduced by an additional factor of up to 500 on the basis of a passive vibration isolation platform, and we have proved the performance by adding an additional seismometer as well as applying it in the atom interferometry experiment. PMID:25273709

  3. An analytical study of the effects of transverse shear deformation and anisotropy on natural vibration frequencies of laminated cylinders

    NASA Technical Reports Server (NTRS)

    Jegley, Dawn C.

    1988-01-01

    Natural vibration frequencies of orthotropic and anisotropic simply supported right circular cylinders are predicted using a higher-order transverse-shear deformation theory. A comparison of natural vibration frequencies predicted by first-order transverse-shear deformation theory and the higher-order theory shows that an additional allowance for transverse shear deformation has a negligible effect on the lowest predicted natural vibration frequencies of laminated cylinders but significantly reduces the higher natural vibration frequencies. A parametric study of the effects of ply orientation on the natural vibration frequencies of laminated cylinders indicates that while stacking sequence affects natural vibration frequencies, cylinder geometry is more important in predicting transverse-shear deformation effects. Interaction curves for cylinders subjected to axial compressive loadings and low natural vibration frequencies indicate that transverse shearing effects are less important in predicting low natural vibration frequencies than in predicting axial compressive buckling loads. The effects of anisotropy are more important than the effects of transverse shear deformation for most strongly anisotropic laminated cylinders in predicting natural vibration frequencies. However, transverse-shear deformation effects are important in predicting high natural vibration frequencies of thick-walled laminated cylinders. Neglecting either anisotropic effects or transverse-shear deformation effects leads to non-conservative errors in predicted natural vibration frequencies.

  4. Enhancement to Non-Contacting Stress Measurement of Blade Vibration Frequency

    NASA Technical Reports Server (NTRS)

    Platt, Michael; Jagodnik, John

    2011-01-01

    A system for turbo machinery blade vibration has been developed that combines time-of-arrival sensors for blade vibration amplitude measurement and radar sensors for vibration frequency and mode identification. The enabling technology for this continuous blade monitoring system is the radar sensor, which provides a continuous time series of blade displacement over a portion of a revolution. This allows the data reduction algorithms to directly calculate the blade vibration frequency and to correctly identify the active modes of vibration. The work in this project represents a significant enhancement in the mode identification and stress calculation accuracy in non-contacting stress measurement system (NSMS) technology when compared to time-of-arrival measurements alone.

  5. Self-powered resonant frequency tuning for Piezoelectric Vibration Energy Harvesters

    NASA Astrophysics Data System (ADS)

    Ahmed-Seddik, B.; Despesse, G.; Boisseau, S.; Defay, E.

    2013-12-01

    This paper reports on the design, fabrication and testing of an innovative 33-mode piezoelectric vibration energy harvester (VEH). This system is able to change its resonant frequency in real time to follow the main frequency of a vibration source. The system proposed in this paper enables to adapt VEH characteristics (resonant frequency, electrical damping) to vibration parameters variations (frequency and amplitude) in order to optimize the extraction of energy and then the output power at any time. This solution allows up to 40% of resonant frequency tuning ratio; moreover, the adaptation is made in real time and the consumption of the regulation electronic is less than 10% of the VEH output power (480μW@0.1g-276Hz).

  6. Estimation of the running speed and bearing defect frequencies of an induction motor from vibration data

    NASA Astrophysics Data System (ADS)

    Ocak, Hasan; Loparo, Kenneth A.

    2004-05-01

    This paper presents two separate algorithms for estimating the running speed and the bearing key frequencies of an induction motor using vibration data. Bearing key frequencies are frequencies at which roller elements pass over a defect point. Most frequency domain-based bearing fault detection and diagnosis techniques (e.g. envelope analysis) rely on vibration measurements and the bearing key frequencies. Thus, estimation of the running speed and the bearing key frequencies are required for failure detection and diagnosis. The paper also incorporates the estimation algorithms with the most commonly used bearing fault detection technique, high-frequency demodulation, to detect bearing faults. Experimental data were used to verify the validity of the algorithms. Data were collected through an accelerometer measuring the vibration from the drive-end ball bearing of an induction motor (Reliance Electric 2HP IQPreAlert)-driven mechanical system. Both inner and outer race defects were artificially introduced to the bearing using electrical discharge machining. A linear vibration model was also developed for generating simulated vibration data. The simulated data were also used to validate the performance of the algorithms. The test results proved the algorithms to be very reliable.

  7. Estimation of vibration frequency of loudspeaker diaphragm by parallel phase-shifting digital holography

    NASA Astrophysics Data System (ADS)

    Kakue, T.; Endo, Y.; Shimobaba, T.; Ito, T.

    2014-11-01

    We report frequency estimation of loudspeaker diaphragm vibrating at high speed by parallel phase-shifting digital holography which is a technique of single-shot phase-shifting interferometry. This technique records multiple phaseshifted holograms required for phase-shifting interferometry by using space-division multiplexing. We constructed a parallel phase-shifting digital holography system consisting of a high-speed polarization-imaging camera. This camera has a micro-polarizer array which selects four linear polarization axes for 2 × 2 pixels. We set a loudspeaker as an object, and recorded vibration of diaphragm of the loudspeaker by the constructed system. By the constructed system, we demonstrated observation of vibration displacement of loudspeaker diaphragm. In this paper, we aim to estimate vibration frequency of the loudspeaker diaphragm by applying the experimental results to frequency analysis. Holograms consisting of 128 × 128 pixels were recorded at a frame rate of 262,500 frames per second by the camera. A sinusoidal wave was input to the loudspeaker via a phone connector. We observed displacement of the loudspeaker diaphragm vibrating by the system. We also succeeded in estimating vibration frequency of the loudspeaker diaphragm by applying frequency analysis to the experimental results.

  8. Statistical analysis of low frequency vibrations in variable speed wind turbines

    NASA Astrophysics Data System (ADS)

    Escaler, X.; Mebarki, T.

    2013-12-01

    The spectral content of the low frequency vibrations in the band from 0 to 10 Hz measured in full scale wind turbines has been statistically analyzed as a function of the whole range of steady operating conditions. Attention has been given to the amplitudes of the vibration peaks and their dependency on rotating speed and power output. Two different wind turbine models of 800 and 2000 kW have been compared. For each model, a sample of units located in the same wind farm and operating during a representative period of time have been considered. A condition monitoring system installed in each wind turbine has been used to register the axial acceleration on the gearbox casing between the intermediate and the high speed shafts. The average frequency spectrum has permitted to identify the vibration signature and the position of the first tower natural frequency in both models. The evolution of the vibration amplitudes at the rotor rotating frequency and its multiples has shown that the tower response is amplified by resonance conditions in one of the models. So, it is concluded that a continuous measurement and control of low frequency vibrations is required to protect the turbines against harmful vibrations of this nature.

  9. The influence of vibration type, frequency, body position and additional load on the neuromuscular activity during whole body vibration.

    PubMed

    Ritzmann, Ramona; Gollhofer, Albert; Kramer, Andreas

    2013-01-01

    This study aimed to assess the influence of different whole body vibration (WBV) determinants on the electromyographic (EMG) activity during WBV in order to identify those training conditions that cause highest neuromuscular responses and therefore provide optimal training conditions. In a randomized cross-over study, the EMG activity of six leg muscles was analyzed in 18 subjects with respect to the following determinants: (1) vibration type (side-alternating vibration (SV) vs. synchronous vibration (SyV), (2) frequency (5-10-15-20-25-30 Hz), (3) knee flexion angle (10°-30°-60°), (4) stance condition (forefoot vs. normal stance) and (5) load variation (no extra load vs. additional load equal to one-third of the body weight). The results are: (1) neuromuscular activity during SV was enhanced compared to SyV (P < 0.05); (2) a progressive increase in frequency caused a progressive increase in EMG activity (P < 0.05); (3) the EMG activity was highest for the knee extensors when the knee joint was 60° flexed (P < 0.05); (4) for the plantar flexors in the forefoot stance condition (P < 0.05); and (5) additional load caused an increase in neuromuscular activation (P < 0.05). In conclusion, large variations of the EMG activation could be observed across conditions. However, with an appropriate adjustment of specific WBV determinants, high EMG activations and therefore high activation intensities could be achieved in the selected muscles. The combination of high vibration frequencies with additional load on an SV platform led to highest EMG activities. Regarding the body position, a knee flexion of 60° and forefoot stance appear to be beneficial for the knee extensors and the plantar flexors, respectively. PMID:22538279

  10. A smart and self-sufficient frequency tunable vibration energy harvester

    NASA Astrophysics Data System (ADS)

    Eichhorn, C.; Tchagsim, R.; Wilhelm, N.; Woias, P.

    2011-10-01

    We present a piezoelectric energy-harvesting system, which is able to self-tune its resonance frequency in an energy-autonomous way, in order to extend its efficient operation over a large frequency range. The system consists of a resonant and frequency-tunable piezoelectric generator and a control unit. In predefined temporal intervals, the control unit analyzes the ambient vibration frequency, decides whether an adjustment of the generator's resonance frequency is necessary or not and delivers the appropriate voltage to a piezoelectric actuator which alters the generator's mechanical stiffness to tune its resonance frequency. The control unit has been optimized to an ultralow power consumption which means that up to 90% of the harvested energy can be fed to the powered electrical load, which could be an embedded system. With frequency-tunable generators, the application range of vibration energy harvesters can be extended to environments with a non-constant vibration frequency, like e.g. the surface of an engine with a varying number of revolutions per minute. Furthermore, the presented system opens the door to off-the-shelf solutions for environments with constant but uncommon vibration frequencies. With the smart tuning algorithm presented in this work, our system is even able to compensate typical weak points of piezoelectrically tunable harvesters, like e.g. hysteresis effects, the temperature dependence of the mechanical stiffness and aging effects.

  11. Statistics and Properties of Low-Frequency Vibrational Modes in Structural Glasses

    NASA Astrophysics Data System (ADS)

    Lerner, Edan; Düring, Gustavo; Bouchbinder, Eran

    2016-07-01

    Low-frequency vibrational modes play a central role in determining various basic properties of glasses, yet their statistical and mechanical properties are not fully understood. Using extensive numerical simulations of several model glasses in three dimensions, we show that in systems of linear size L sufficiently smaller than a crossover size LD, the low-frequency tail of the density of states follows D (ω )˜ω4 up to the vicinity of the lowest Goldstone mode frequency. We find that the sample-to-sample statistics of the minimal vibrational frequency in systems of size L frequency modes are spatially quasilocalized and that their localization and associated quartic anharmonicity are largely frequency independent. The effect of preparation protocols on the low-frequency modes is elucidated, and a number of glassy length scales are briefly discussed.

  12. The effects of low-frequency vibrations on hepatic profile of blood

    NASA Astrophysics Data System (ADS)

    Damijan, Z.

    2008-02-01

    Body vibrations training has become popular in sports training, fitness activity, it is still a rare form of physical rehabilitation.. Vibrations are transmitted onto the whole body or some body parts of an exercising person via a vibration platform subjected to mechanical vertical vibrations. During the training session a participant has to maintain his body position or do exercises that engage specific muscles whilst vibrations of the platform are transmitted onto the person's body. This paper is the continuation of the earlier study covering the effects of low-frequency vibrations on selected physiological parameters of the human body. The experiments were conducted to find the answer to the question if vibration exposure (total duration of training sessions 6 hours 20 min) should produce any changes in hepatic profile of blood. Therefore a research program was undertaken at the University of Science and Technology AGH UST to investigate the effects of low-frequency vibration on selected parameters of hepatic profile of human blood. Cyclic fluctuations of bone loading were induced by the applied harmonic vibration 3.5 Hz and amplitude 0.004 m. The experiments utilizing two vibrating platforms were performed in the Laboratory of Structural Acoustics and Biomedical Engineering AGH-UST. The applied vibrations were harmless and not annoying, in accordance with the standard PN-EN ISO 130901-1, 1998. 23 women volunteers had 19 sessions on subsequent working days, at the same time of day. during the tests the participants remained in the standing position, passive. The main hypothesis has it that short-term low-frequency vibration exposure might bring about the changes of the hepatic profile of blood, including: bilirubin (BILIRUBIN), alkaline phosphatase (Alp), alanine aminotransferase (ALT), aspartate aminotransferase (AST) and albumin (ALBUMIN) levels. Research data indicate the low-frequency vibrations exposure produces statistically significant decrease of

  13. An extension of command shaping methods for controlling residual vibration using frequency sampling

    NASA Technical Reports Server (NTRS)

    Singer, Neil C.; Seering, Warren P.

    1992-01-01

    The authors present an extension to the impulse shaping technique for commanding machines to move with reduced residual vibration. The extension, called frequency sampling, is a method for generating constraints that are used to obtain shaping sequences which minimize residual vibration in systems such as robots whose resonant frequencies change during motion. The authors present a review of impulse shaping methods, a development of the proposed extension, and a comparison of results of tests conducted on a simple model of the space shuttle robot arm. Frequency shaping provides a method for minimizing the impulse sequence duration required to give the desired insensitivity.

  14. The correction of vibration in frequency scanning interferometry based absolute distance measurement system for dynamic measurements

    NASA Astrophysics Data System (ADS)

    Lu, Cheng; Liu, Guodong; Liu, Bingguo; Chen, Fengdong; Zhuang, Zhitao; Xu, Xinke; Gan, Yu

    2015-10-01

    Absolute distance measurement systems are of significant interest in the field of metrology, which could improve the manufacturing efficiency and accuracy of large assemblies in fields such as aircraft construction, automotive engineering, and the production of modern windmill blades. Frequency scanning interferometry demonstrates noticeable advantages as an absolute distance measurement system which has a high precision and doesn't depend on a cooperative target. In this paper , the influence of inevitable vibration in the frequency scanning interferometry based absolute distance measurement system is analyzed. The distance spectrum is broadened as the existence of Doppler effect caused by vibration, which will bring in a measurement error more than 103 times bigger than the changes of optical path difference. In order to decrease the influence of vibration, the changes of the optical path difference are monitored by a frequency stabilized laser, which runs parallel to the frequency scanning interferometry. The experiment has verified the effectiveness of this method.

  15. Fluid dynamic aspects of cardiovascular behavior during low-frequency whole-body vibration

    NASA Technical Reports Server (NTRS)

    Nerem, R. M.

    1973-01-01

    The behavior of the cardiovascular system during low frequency whole-body vibration, such as encountered by astronauts during launch and reentry, is examined from a fluid mechanical viewpoint. The vibration characteristics of typical manned spacecraft and other vibration environments are discussed, and existing results from in vivo studies of the hemodynamic aspects of this problem are reviewed. Recent theoretical solutions to related fluid mechanical problems are then used in the interpretation of these results and in discussing areas of future work. The results are included of studies of the effects of vibration on the work done by the heart and on pulsatile flow in blood vessels. It is shown that important changes in pulse velocity, the instantaneous velocity profile, mass flow rate, and wall shear stress may occur in a pulsatile flow due to the presence of vibration. The significance of this in terms of changes in peripheral vascular resistance and possible damage to the endothelium of blood vessels is discussed.

  16. High-frequency vibration effect on the stability of a horizontal layer of ternary fluid.

    PubMed

    Lyubimova, Tatyana

    2015-05-01

    The effect of small-amplitude high-frequency longitudinal vibrations on the stability of a horizontal layer of ternary fluid is studied in the framework of average approach. Long-wave instability is studied analytically and instability to the perturbations with finite wave numbers is studied numerically. It is found that, similar to the case when vibrations are absent, for ternary fluids there exist monotonic and oscillatory long-wave instability modes. The calculations show that the vibrations lead to destabilization in the case of heating from below and to stabilization in the case of heating from above. Additionally, vibrations influence on the parameter range where long-wave instability is most dangerous. New, vibrational, instability modes are found which leads to the existence of convection in zero-gravity conditions. PMID:25998169

  17. Protonated nitrous oxide, NNOH+: fundamental vibrational frequencies and spectroscopic constants from quartic force fields.

    PubMed

    Huang, Xinchuan; Fortenberry, Ryan C; Lee, Timothy J

    2013-08-28

    The interstellar presence of protonated nitrous oxide has been suspected for some time. Using established high-accuracy quantum chemical techniques, spectroscopic constants and fundamental vibrational frequencies are provided for the lower energy O-protonated isomer of this cation and its deuterated isotopologue. The vibrationally-averaged B0 and C0 rotational constants are within 6 MHz of their experimental values and the D(J) quartic distortion constants agree with experiment to within 3%. The known gas phase O-H stretch of NNOH(+) is 3330.91 cm(-1), and the vibrational configuration interaction computed result is 3330.9 cm(-1). Other spectroscopic constants are also provided, as are the rest of the fundamental vibrational frequencies for NNOH(+) and its deuterated isotopologue. This high-accuracy data should serve to better inform future observational or experimental studies of the rovibrational bands of protonated nitrous oxide in the interstellar medium and the laboratory. PMID:24007003

  18. An Analysis of the High Frequency Vibrations in Early Thematic Mapper Scenes

    NASA Technical Reports Server (NTRS)

    Kogut, J.; Larduinat, E.

    1985-01-01

    The motion of the mirrors in the thematic mapper (TM) and multispectral scanner (MSS) instruments, and the motion of other devices, such as the TDRSS antenna drive, and solar array drives onboard LANDSAT-4 cause vibrations to propagate through the spacecraft. These vibrations as well as nonlinearities in the scanning motion of the TM mirror can cause the TM detectors to point away from their nominal positions. Two computer programs, JITTER and SCDFT, were developed as part of the LANDSAT-D Assessment System (LAS), Products and Procedures Analysis (PAPA) program to evaluate the potential effect of high frequency vibrations on the final TM image. The maximum overlap and underlap which were observed for early TM scenes are well within specifications for the ground processing system. The cross scan and scan high frequency vibrations are also within the specifications cited for the flight system.

  19. Protonated Nitrous Oxide, NNOH(+): Fundamental Vibrational Frequencies and Spectroscopic Constants from Quartic Force Fields

    NASA Technical Reports Server (NTRS)

    Huang, Xinchuan; Fortenberry, Ryan C.; Lee, Timothy J.

    2013-01-01

    The interstellar presence of protonated nitrous oxide has been suspected for some time. Using established high-accuracy quantum chemical techniques, spectroscopic constants and fundamental vibrational frequencies are provided for the lower energy O-protonated isomer of this cation and its deuterated isotopologue. The vibrationally-averaged B0 and C0 rotational constants are within 6 MHz of their experimental values and the D(subJ) quartic distortion constants agree with experiment to within 3%. The known gas phase O-H stretch of NNOH(+) is 3330.91 cm(exp-1), and the vibrational configuration interaction computed result is 3330.9 cm(exp-1). Other spectroscopic constants are also provided, as are the rest of the fundamental vibrational frequencies for NNOH(+) and its deuterated isotopologue. This high-accuracy data should serve to better inform future observational or experimental studies of the rovibrational bands of protonated nitrous oxide in the ISM and the laboratory.

  20. Low frequency vibrations induce malformations in two aquatic species in a frequency-, waveform-, and direction-specific manner.

    PubMed

    Vandenberg, Laura N; Stevenson, Claire; Levin, Michael

    2012-01-01

    Environmental toxicants such as industrial wastes, air particulates from machinery and transportation vehicles, and pesticide run-offs, as well as many chemicals, have been widely studied for their effects on human and wildlife populations. Yet other potentially harmful environmental pollutants such as electromagnetic pulses, noise and vibrations have remained incompletely understood. Because developing embryos undergo complex morphological changes that can be affected detrimentally by alterations in physical forces, they may be particularly susceptible to exposure to these types of pollutants. We investigated the effects of low frequency vibrations on early embryonic development of two aquatic species, Xenopus laevis (frogs) and Danio rerio (zebrafish), specifically focusing on the effects of varying frequencies, waveforms, and applied direction. We observed treatment-specific effects on the incidence of neural tube defects, left-right patterning defects and abnormal tail morphogenesis in Xenopus tadpoles. Additionally, we found that low frequency vibrations altered left-right patterning and tail morphogenesis, but did not induce neural tube defects, in zebrafish. The results of this study support the conclusion that low frequency vibrations are toxic to aquatic vertebrates, with detrimental effects observed in two important model species with very different embryonic architectures. PMID:23251546

  1. Low Frequency Vibrations Induce Malformations in Two Aquatic Species in a Frequency-, Waveform-, and Direction-Specific Manner

    PubMed Central

    Vandenberg, Laura N.; Stevenson, Claire; Levin, Michael

    2012-01-01

    Environmental toxicants such as industrial wastes, air particulates from machinery and transportation vehicles, and pesticide run-offs, as well as many chemicals, have been widely studied for their effects on human and wildlife populations. Yet other potentially harmful environmental pollutants such as electromagnetic pulses, noise and vibrations have remained incompletely understood. Because developing embryos undergo complex morphological changes that can be affected detrimentally by alterations in physical forces, they may be particularly susceptible to exposure to these types of pollutants. We investigated the effects of low frequency vibrations on early embryonic development of two aquatic species, Xenopus laevis (frogs) and Danio rerio (zebrafish), specifically focusing on the effects of varying frequencies, waveforms, and applied direction. We observed treatment-specific effects on the incidence of neural tube defects, left-right patterning defects and abnormal tail morphogenesis in Xenopus tadpoles. Additionally, we found that low frequency vibrations altered left-right patterning and tail morphogenesis, but did not induce neural tube defects, in zebrafish. The results of this study support the conclusion that low frequency vibrations are toxic to aquatic vertebrates, with detrimental effects observed in two important model species with very different embryonic architectures. PMID:23251546

  2. S-shape spring sensor: Sensing specific low-frequency vibration by energy harvesting.

    PubMed

    Zhang, Lan; Lu, Jian; Takei, Ryohei; Makimoto, Natsumi; Itoh, Toshihiro; Kobayashi, Takeshi

    2016-08-01

    We have developed a Si-based microelectromechanical systems sensor with high sensitivity for specific low-frequency vibration-sensing and energy-harvesting applications. The low-frequency vibration sensor contains a disk proof mass attached to two or three lead zirconate titanate (PZT) S-shape spring flexures. To obtain a faster and less expensive prototype, the design and optimization of the sensor structure are studied via finite-element method analysis. To validate the sensor structure to detect low-frequency vibration, the effects of geometrical dimensions, including the width and diameter of the S-shape spring of the proof mass, were analyzed and measured. The functional features, including the mechanical property and electrical performance of the vibration sensor, were evaluated. The results demonstrated that a very low resonant frequency of <11 Hz and a reasonably high voltage output of 7.5 mV at acceleration of >0.2g can be typically achieved. Given a low-frequency vibration sensor with ideal performance and mass fabrication, many advanced civilian and industrial applications can be possibly realized. PMID:27587151

  3. S-shape spring sensor: Sensing specific low-frequency vibration by energy harvesting

    NASA Astrophysics Data System (ADS)

    Zhang, Lan; Lu, Jian; Takei, Ryohei; Makimoto, Natsumi; Itoh, Toshihiro; Kobayashi, Takeshi

    2016-08-01

    We have developed a Si-based microelectromechanical systems sensor with high sensitivity for specific low-frequency vibration-sensing and energy-harvesting applications. The low-frequency vibration sensor contains a disk proof mass attached to two or three lead zirconate titanate (PZT) S-shape spring flexures. To obtain a faster and less expensive prototype, the design and optimization of the sensor structure are studied via finite-element method analysis. To validate the sensor structure to detect low-frequency vibration, the effects of geometrical dimensions, including the width and diameter of the S-shape spring of the proof mass, were analyzed and measured. The functional features, including the mechanical property and electrical performance of the vibration sensor, were evaluated. The results demonstrated that a very low resonant frequency of <11 Hz and a reasonably high voltage output of 7.5 mV at acceleration of >0.2g can be typically achieved. Given a low-frequency vibration sensor with ideal performance and mass fabrication, many advanced civilian and industrial applications can be possibly realized.

  4. Computational IR spectroscopy of water: OH stretch frequencies, transition dipoles, and intermolecular vibrational coupling constants

    NASA Astrophysics Data System (ADS)

    Choi, Jun-Ho; Cho, Minhaeng

    2013-05-01

    The Hessian matrix reconstruction method initially developed to extract the basis mode frequencies, vibrational coupling constants, and transition dipoles of the delocalized amide I, II, and III vibrations of polypeptides and proteins from quantum chemistry calculation results is used to obtain those properties of delocalized O-H stretch modes in liquid water. Considering the water symmetric and asymmetric O-H stretch modes as basis modes, we here develop theoretical models relating vibrational frequencies, transition dipoles, and coupling constants of basis modes to local water configuration and solvent electric potential. Molecular dynamics simulation was performed to generate an ensemble of water configurations that was in turn used to construct vibrational Hamiltonian matrices. Obtaining the eigenvalues and eigenvectors of the matrices and using the time-averaging approximation method, which was developed by the Skinner group, to calculating the vibrational spectra of coupled oscillator systems, we could numerically simulate the O-H stretch IR spectrum of liquid water. The asymmetric line shape and weak shoulder bands were quantitatively reproduced by the present computational procedure based on vibrational exciton model, where the polarization effects on basis mode transition dipoles and inter-mode coupling constants were found to be crucial in quantitatively simulating the vibrational spectra of hydrogen-bond networking liquid water.

  5. Structure, Anharmonic Vibrational Frequencies, and Intensities of NNHNN(+).

    PubMed

    Yu, Qi; Bowman, Joel M; Fortenberry, Ryan C; Mancini, John S; Lee, Timothy J; Crawford, T Daniel; Klemperer, William; Francisco, Joseph S

    2015-11-25

    A semiglobal potential energy surface (PES) and quartic force field (QFF) based on fitting high-level electronic structure energies are presented to describe the structures and spectroscopic properties of NNHNN(+). The equilibrium structure of NNHNN(+) is linear with the proton equidistant between the two nitrogen groups and thus of D(∞h) symmetry. Vibrational second-order perturbation theory (VPT2) calculations based on the QFF fails to describe the proton "rattle" motion, i.e., the antisymmetric proton stretch, due to the very flat nature of PES around the global minimum but performs properly for other modes with sharper potential wells. Vibrational self-consistent field/virtual state configuration interaction (VSCF/VCI) calculations using a version of MULTIMODE without angular momentum terms successfully describe this motion and predict the fundamental to be at 759 cm(-1). This is in good agreement with the value of 746 cm(-1) from a fixed-node diffusion Monte Carlo calculation and the experimental Ar-tagged result of 743 cm(-1). Other VSCF/VCI energies are in good agreement with other experimentally reported ones. Both double-harmonic intensity and rigorous MULTIMODE intensity calculations show the proton-transfer fundamental has strong intensity. PMID:26529262

  6. A magnetic-spring-based, low-frequency-vibration energy harvester comprising a dual Halbach array

    NASA Astrophysics Data System (ADS)

    Salauddin, M.; Halim, M. A.; Park, J. Y.

    2016-09-01

    Energy harvesting that uses low-frequency vibrations is attractive due to the availability of such vibrations throughout the ambient environment. Significant power generation at low-frequency vibrations, however, is challenging because the power flow decreases as the frequency decreases; moreover, designing a spring-mass system that is suitable for low-frequency-vibration energy harvesting is difficult. In this work, our proposed device overcomes both of these challenges by using a dual Halbach array and magnetic springs. Each Halbach array concentrates the magnetic-flux lines on one side of the array while suppressing the flux lines on the other side; therefore, a dual Halbach array allows for an interaction between the concentrated magnetic-flux lines and the same coil so that the maximum flux linkage occurs. During the experiment, vibration was applied in a horizontal direction to reduce the gravity effect on the Halbach-array structure. To achieve an increased power generation at low-amplitude and low-frequency vibrations, the magnetic structure of the dual Halbach array and the magnetic springs were optimized in terms of the operating frequency and the power density; subsequently, a prototype was fabricated and tested. The prototype device offers a normalized power density of 133.45 μW cm‑3 g‑2 that is much higher than those of recently reported electromagnetic energy harvesters; furthermore, it is capable of delivering a maximum average power of 1093 μW to a 44 Ω optimum load, at an 11 Hz resonant frequency and under a 0.5 g acceleration.

  7. Application of coupled analysis methods for prediction of blast-induced dominant vibration frequency

    NASA Astrophysics Data System (ADS)

    Li, Haibo; Li, Xiaofeng; Li, Jianchun; Xia, Xiang; Wang, Xiaowei

    2016-03-01

    Blast-induced dominant vibration frequency (DVF) involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational analysis and dimensional analysis procedures for prediction of dominant vibration frequency are presented. Six factors are selected from extensive effect factor sequences based on grey relational analysis, and then a novel blast-induced dominant vibration frequency prediction is obtained by dimensional analysis. In addition, the prediction is simplified by sensitivity analysis with 195 experimental blast records. Validation is carried out for the proposed formula based on the site test database of the firstperiod blasting excavation in the Guangdong Lufeng Nuclear Power Plant (GLNPP). The results show the proposed approach has a higher fitting degree and smaller mean error when compared with traditional predictions.

  8. DFT Calculation of Vibrational Frequencies of FeCoB m-RAM

    NASA Astrophysics Data System (ADS)

    Ling, Lee Li; Jesudason, Christopher; Shrivastava, Keshav N.

    2010-07-01

    The present available random access memory materials are semiconductors. It is proposed to develop magnetoresistance based random access memory (m-RAM) materials. Hence, we consider an alloy of Fe, Co and B which will be strongly magnetic and work well as a memory device. We calculate the vibrational frequencies of clusters of atoms of Fe, Co and B. The larger vibrational frequencies indicate larger force constants. The result show that CoB3Fe to have the largest vibrational frequency of 1293.03 cm-1 whereas BFeCo2 has 509.59 cm-1. We identify the ratio of constituents and the structures which have large force constant. Hence, CoB3Fe is better than BFeCo2. The cluster formation depends on the method of quenching. Hence, method of preparation can be modified to achieve large force constants.

  9. The Effect of the Weight Scheme on DFT Vibrational Frequencies

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles; Ricca, Alessandra

    1999-01-01

    All-electron B3LYP harmonic frequencies of Ge2H5 and Ge2H6 are computed for several choices of grid and using both the Becke and the Stratmann, Scuseria, and Frisch atomic partition functions (weight scheme). For large grids, the results are independent of the weighting scheme. The lowest frequency mode is much more stable with respect to the number of grid points when the Stratmann, Scuseria, and Frisch weights are used.

  10. Peculiarities of the Third Natural Frequency Vibrations of a Cantilever for the Improvement of Energy Harvesting

    PubMed Central

    Ostasevicius, Vytautas; Janusas, Giedrius; Milasauskaite, Ieva; Zilys, Mindaugas; Kizauskiene, Laura

    2015-01-01

    This paper focuses on several aspects extending the dynamical efficiency of a cantilever beam vibrating in the third mode. A few ways of producing this mode stimulation, namely vibro-impact or forced excitation, as well as its application for energy harvesting devices are proposed. The paper presents numerical and experimental analyses of novel structural dynamics effects along with an optimal configuration of the cantilever beam. The peculiarities of a cantilever beam vibrating in the third mode are related to the significant increase of the level of deformations capable of extracting significant additional amounts of energy compared to the conventional harvester vibrating in the first mode. Two types of a piezoelectric vibrating energy harvester (PVEH) prototype are analysed in this paper: the first one without electrode segmentation, while the second is segmented using electrode segmentation at the strain nodes of the third vibration mode to achieve effective operation at the third resonant frequency. The results of this research revealed that the voltage generated by any segment of the segmented PVEH prototype excited at the third resonant frequency demonstrated a 3.4–4.8-fold increase in comparison with the non-segmented prototype. Simultaneously, the efficiency of the energy harvester prototype also increased at lower resonant frequencies from 16% to 90%. The insights presented in the paper may serve for the development and fabrication of advanced piezoelectric energy harvesters which would be able to generate a considerably increased amount of electrical energy independently of the frequency of kinematical excitation. PMID:26029948

  11. Verification of two methods to mitigate high frequency pipe shell vibration

    SciTech Connect

    Motriuk, R.W.

    1996-12-01

    High frequency vibration generated by centrifugal compressors can cause fatigue damage to attached compressor piping systems. In some cases, components of piping systems exposed to such vibrations experience fatigue failures only after a few hours of operation. This paper describes several approaches to mitigate compressor generated high frequency vibrations. It focuses on two passive methods which have been implemented at NOVA Gas Transmission Limited (NGTL). The first method describes how to disturb and disorganize a high frequency complex acoustical field which propagates through the compressor discharge piping thus reducing the excitation forces. The second method involves a direct piping modification which influences the piping mechanical responses. Both methods are applied to large diameter (NPS 24 and NPS 36) natural gas piping systems incorporating 16 MW and 25 MW centrifugal compressors. Vibration velocities are documented for As found systems and for systems modified by implementation of each method. Dynamic stress levels for As found systems are reported in the form of K factors. Discussion of the results is followed by brief guidelines which show how to improve the structural integrity of piping subjected to high frequency vibrations.

  12. Peculiarities of the third natural frequency vibrations of a cantilever for the improvement of energy harvesting.

    PubMed

    Ostasevicius, Vytautas; Janusas, Giedrius; Milasauskaite, Ieva; Zilys, Mindaugas; Kizauskiene, Laura

    2015-01-01

    This paper focuses on several aspects extending the dynamical efficiency of a cantilever beam vibrating in the third mode. A few ways of producing this mode stimulation, namely vibro-impact or forced excitation, as well as its application for energy harvesting devices are proposed. The paper presents numerical and experimental analyses of novel structural dynamics effects along with an optimal configuration of the cantilever beam. The peculiarities of a cantilever beam vibrating in the third mode are related to the significant increase of the level of deformations capable of extracting significant additional amounts of energy compared to the conventional harvester vibrating in the first mode. Two types of a piezoelectric vibrating energy harvester (PVEH) prototype are analysed in this paper: the first one without electrode segmentation, while the second is segmented using electrode segmentation at the strain nodes of the third vibration mode to achieve effective operation at the third resonant frequency. The results of this research revealed that the voltage generated by any segment of the segmented PVEH prototype excited at the third resonant frequency demonstrated a 3.4-4.8-fold increase in comparison with the non-segmented prototype. Simultaneously, the efficiency of the energy harvester prototype also increased at lower resonant frequencies from 16% to 90%. The insights presented in the paper may serve for the development and fabrication of advanced piezoelectric energy harvesters which would be able to generate a considerably increased amount of electrical energy independently of the frequency of kinematical excitation. PMID:26029948

  13. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    NASA Astrophysics Data System (ADS)

    Sun, Kyung Ho; Kim, Young-Cheol; Kim, Jae Eun

    2014-10-01

    While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm3, which was designed for a target frequency of as low as 100 Hz.

  14. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    SciTech Connect

    Sun, Kyung Ho; Kim, Young-Cheol; Kim, Jae Eun

    2014-10-15

    While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm{sup 3}, which was designed for a target frequency of as low as 100 Hz.

  15. Broadband electromagnetic power harvester from vibrations via frequency conversion by impact oscillations

    SciTech Connect

    Yuksek, N. S.; Almasri, M.; Feng, Z. C.

    2014-09-15

    In this paper, we propose an electromagnetic power harvester that uses a transformative multi-impact approach to achieve a wide bandwidth response from low frequency vibration sources through frequency-up conversion. The device consists of a pick-up coil, fixed at the free edge of a cantilever beam with high resonant frequency, and two cantilever beams with low excitation frequencies, each with an impact mass attached at its free edge. One of the two cantilevers is designed to resonate at 25 Hz, while the other resonates at 50 Hz within the range of ambient vibration frequency. When the device is subjected to a low frequency vibration, the two low-frequency cantilevers responded by vibrating at low frequencies, and thus their thick metallic masses made impacts with the high resonance frequency cantilever repeatedly at two locations. This has caused it along with the pick-up coil to oscillate, relative to the permanent magnet, with decaying amplitude at its resonance frequency, and results in a wide bandwidth response from 10 to 63 Hz at 2 g. A wide bandwidth response between 10–51 Hz and 10–58 Hz at acceleration values of 0.5 g and 2 g, respectively, were achieved by adjusting the impact cantilever frequencies closer to each other (25 Hz and 45 Hz). A maximum output power of 85 μW was achieved at 5 g at 30 Hz across a load resistor, 2.68 Ω.

  16. Escape conditioning and low-frequency whole-body vibration - The effects of frequency, amplitude, and controls for noise and activation.

    NASA Technical Reports Server (NTRS)

    Wike, E. L.; Wike, S. S.

    1972-01-01

    Seven experiments are reported on low-frequency whole-body vibration and rats' escape conditioning in a modified Skinner box. In the first three studies, conditioning was observed but was independent of frequency. In experiment four, the number of escape responses was directly related to vibration amplitude. Experiment five was a control for vibration noise and noise termination; experiments six and seven studied vibration-induced activation. Noise termination did not produce conditioning. In experiment six, subjects made more responses when responding led to termination than when it did not. In experiment seven, subjects preferred a bar which terminated vibration to one which did not.

  17. An ab initio investigation of the structure, vibrational frequencies, and intensities of HO2 and HOCl

    NASA Technical Reports Server (NTRS)

    Komornicki, A.; Jaffe, R. L.

    1979-01-01

    The infrared spectral intensities for HOCl and HO2 have been calculated using a new ab initio technique. Theoretical results for the geometries, vibrational frequencies, and the dipole moments of these species are also reported. All of the calculations were performed at the SCF level using near Hartree-Fock quality basis sets. The results for the molecular geometries and the vibrational frequencies are in good agreement with available experimental data. It is believed that the computed intensities are accurate to at least 50%. The results should be helpful in attempts to determine the stratospheric abundance of HOCl and HO2 by in situ infrared spectroscopic measurements.

  18. High-frequency vibrational density of states of a disordered solid.

    PubMed

    Tomaras, C; Schirmacher, W

    2013-12-11

    We investigate the high-frequency behavior of the density of vibrational states in three-dimensional elasticity theory with spatially fluctuating elastic moduli. At frequencies well above the mobility edge, instanton solutions yield an exponentially decaying density of states. The instanton solutions describe excitations, which become localized due to the disorder-induced fluctuations, which lower the sound velocity in a finite region compared to its average value. The exponentially decaying density of states (known in electronic systems as the Lifshitz tail) is governed by the statistics of a fluctuating-elasticity landscape, capable of trapping the vibrational excitations. PMID:24214818

  19. A low frequency MEMS vibration sensor for low power missile health monitoring

    NASA Astrophysics Data System (ADS)

    Horowitz, S. B.; Allen, M. S.; Fox, J. R.; Cortes, J. P.; Barkett, L.; Mathias, A. D.; Hernandez, C.; Martin, A. C.; Sanghadasa, M.; Marotta, S.

    This paper addresses the design, fabrication and characterization of a first-generation, low frequency MEMS vibration sensor. The sensor is designed specifically for applications requiring extremely low power vibration detection at only targeted frequencies. For development, lumped element and finite element modeling was performed, driving the design towards a realizable geometry that addresses the targeted performance specs. The sensors were microfabricated using conventional surface micromachining, sol-gel PZT (lead zirconate titanate) thin films, and bulk silicon etching techniques. The completed sensors were then characterized to determine electrical, mechanical and piezoelectric properties at the material and device level. Results demonstrate functional operation with performance close to predicted specifications.

  20. A resonant frequency switching scheme of a cantilever based on polyvinylidene fluoride for vibration energy harvesting

    NASA Astrophysics Data System (ADS)

    Jo, Sung-Eun; Kim, Myoung-Soo; Kim, Yong-Jun

    2012-01-01

    A mismatch between the ambient frequency and the resonant frequency of the vibrational energy harvester causes decrease of the energy transduction efficiency. Therefore, there is a great demand for the resonant frequency tuning of the vibrational energy harvester. In this paper, a flexible PVDF (polyvinylidene fluoride) cantilever, which can switch its resonant frequency automatically and maintain the switched resonant frequency without energy consumption, is proposed. The proposed energy harvester is composed of cantilever couples which are similar with a seesaw structure. When the proposed energy harvester is excited by an external vibration and the excited frequency fluctuates, the cantilever couples can be horizontally moved by using the large deflection of a flexible cantilever. So the beam length of each cantilever which corresponds to each arm of the seesaw structure can be changed and the resonant frequency of the proposed energy harvester can be switched in real time. The proposed energy harvester was realized by application of a piezoelectric polymer, PVDF. Also, it was confirmed that the proposed energy harvester can switch its resonant frequency in several seconds without an additional energy source.

  1. Higher-order vibrational mode frequency tuning utilizing fishbone-shaped microelectromechanical systems resonator

    NASA Astrophysics Data System (ADS)

    Suzuki, Naoya; Tanigawa, Hiroshi; Suzuki, Kenichiro

    2013-04-01

    Resonators based on microelectromechanical systems (MEMS) have received considerable attention for their applications for wireless equipment. The requirements for this application include small size, high frequency, wide bandwidth and high portability. However, few MEMS resonators with wide-frequency tuning have been reported. A fishbone-shaped resonator has a resonant frequency with a maximum response that can be changed according to the location and number of several exciting electrodes. Therefore, it can be expected to provide wide-frequency tuning. The resonator has three types of electrostatic forces that can be generated to deform a main beam. We evaluate the vibrational modes caused by each exciting electrodes by comparing simulated results with measured ones. We then successfully demonstrate the frequency tuning of the first to fifth resonant modes by using the algorithm we propose here. The resulting frequency tuning covers 178 to 1746 kHz. In addition, we investigate the suppression of the anchor loss to enhance the Q-factor. An experiment shows that tapered-shaped anchors provide a higher Q-factor than rectangular-shaped anchors. The Q-factor of the resonators supported by suspension beams is also discussed. Because the suspension beams cause complicated vibrational modes for higher frequencies, the enhancement of the Q-factor for high vibrational modes cannot be obtained here. At present, the tapered-anchor resonators are thought to be most suitable for frequency tuning applications.

  2. Centrifugal compressor modifications and their effect on high-frequency pipe wall vibration

    SciTech Connect

    Motriuk, R.W.; Harvey, D.P.

    1998-08-01

    High-frequency pulsation generated by centrifugal compressors, with pressure wave-lengths much smaller than the attached pipe diameter, can cause fatigue failures of the compressor internals, impair compressor performance, and damage the attached compressor piping. There are numerous sources producing pulsation in centrifugal compressors. Some of them are discussed in literature at large (Japikse, 1995; Niese, 1976). NGTL has experienced extreme high-frequency discharge pulsation and pipe wall vibration on many of its radial inlet high-flow centrifugal gas compressor facilities. These pulsations led to several piping attachment failures and compressor internal component failures while the compressor operated within the design envelope. This paper considers several pulsation conditions at an NGTL compression facility which resulted in unacceptable piping vibration. Significant vibration attenuation was achieved by modifying the compressor (pulsation source) through removal of the diffuser vanes and partial removal of the inlet guide vanes (IGV). Direct comparison of the changes in vibration, pulsation, and performance are made for each of the modifications. The vibration problem, probable causes, options available to address the problem, and the results of implementation are reviewed. The effects of diffuser vane removal on discharge pipe wall vibration as well as changes in compressor performance are described.

  3. Vibration Mode Observation of Piezoelectric Disk-type Resonator by High Frequency Laser Doppler Vibrometer

    NASA Astrophysics Data System (ADS)

    Matsumura, Takeshi; Esashi, Masayoshi; Harada, Hiroshi; Tanaka, Shuji

    For future mobile phones based on cognitive radio technology, a compact multi-band RF front-end architecture is strongly required and an integrated multi-band RF filter bank is a key component in it. Contour-mode resonators are receiving increased attention for a multi-band filter solution, because its resonant frequency is mainly determined by its size and shape, which are defined by lithography. However, spurious responses including flexural vibration are also excited due to its thin structure. To improve resonator performance and suppress spurious modes, visual observation with a laser probe system is very effective. In this paper, we have prototyped a mechanically-coupled disk-array filter, which consists of a Si disk and 2 disk-type resonators of higher-order wine-glass mode, and observed its vibration modes using a high-frequency laser-Doppler vibrometer (UHF-120, Polytec, Inc.). As a result, it was confirmed that higher order wine-glass mode vibration included a compound displacement, and that its out-of-plane vibration amplitude was much smaller than other flexural spurious modes. The observed vibration modes were compared with FEM (Finite Element Method) simulation results. In addition, it was also confirmed that the fabrication error, e.g. miss-alignment, induced asymmetric vibration.

  4. Piezoelectric-based power sources for harvesting energy from platforms with low-frequency vibration

    NASA Astrophysics Data System (ADS)

    Rastegar, J.; Pereira, C.; Nguyen, H.-L.

    2006-03-01

    This paper presents a new class of highly efficient piezoelectric based energy harvesting power sources for mounting on platforms that vibrate at very low frequencies as compared to the frequencies at which energy can be efficiently harvested using piezoelectric elements . These energy harvesting power sources have a very simple design and do not require accurate tuning for each application to match the frequency of the platform vibration. The developed method of harvesting mechanical energy and converting it to electrical energy overcomes problems that are usually encountered with harvesting energy from low frequency vibration of various platforms such as ships and other platforms with similar vibratory (rocking or translational) motions. Omnitek Partners has designed several such energy harvesting power sources and is in the process of constructing prototypes for testing. The developed designs are modular and can be used to construct power sources for various power requirements. The amount of mechanical energy available for harvesting is obviously dependent on the frequency and amplitude of vibration of the platform, and the size and mass of the power source.

  5. Detailed Vibration Analysis of Pinion Gear with Time-Frequency Methods

    NASA Technical Reports Server (NTRS)

    Mosher, Marianne; Pryor, Anna H.; Lewicki, David G.

    2003-01-01

    In this paper, the authors show a detailed analysis of the vibration signal from the destructive testing of a spiral bevel gear and pinion pair containing seeded faults. The vibration signal is analyzed in the time domain, frequency domain and with four time-frequency transforms: the Short Time Frequency Transform (STFT), the Wigner-Ville Distribution with the Choi-Williams kernel (WV-CW), the Continuous Wavelet' Transform (CWT) and the Discrete Wavelet Transform (DWT). Vibration data of bevel gear tooth fatigue cracks, under a variety of operating load levels and damage conditions, are analyzed using these methods. A new metric for automatic anomaly detection is developed and can be produced from any systematic numerical representation of the vibration signals. This new metric reveals indications of gear damage with all of the time-frequency transforms, as well as time and frequency representations, on this data set. Analysis with the CWT detects changes in the signal at low torque levels not found with the other transforms. The WV-CW and CWT use considerably more resources than the STFT and the DWT. More testing of the new metric is needed to determine its value for automatic anomaly detection and to develop fault detection methods for the metric.

  6. Potential low frequency ground vibration (<6.3 Hz) impacts from underground LRT operations

    NASA Astrophysics Data System (ADS)

    Wolf, S.

    2003-10-01

    Vibration sensitive research activities at the laboratories of the University of Washington (UW) Physics and Astronomy Building (PAB) were a critical issue for the design of the Sound Transit Link Light Rail LRT system in Seattle, Washington. A study was conducted to measure and predict low frequency ground vibration generated by the LRT operations. The University's concern was an on-going research experiment in gravity, which had sensitivity to vibration below 6.3 Hz. The experiment was located on an independent concrete slab in an area cut-out from the building foundation with no connection to the building structure. Another concern was the planned future construction of a Life Sciences Center with vibration sensitive test equipment. This paper presents the results of a study to estimate the ground displacement at these buildings using empirical measured data of a similar deep tunnel transit system and finite difference modelling analysis.

  7. Frequency weighting for vibration-induced white finger compatible with exposure-response models.

    PubMed

    Brammer, Anthony J; Pitts, Paul M

    2012-01-01

    An analysis has been performed to derive a frequency weighting for the development of vibration-induced white finger (VWF). It employs a model to compare health risks for pairs of population groups that are selected to have similar health outcomes from operating power tools or machines with markedly different acceleration spectra (rock drills, chain saws, pavement breakers and motorcycles). The model defines the Relative Risk, RR(f(trial)), which is constructed from the ratio of daily exposures and includes a trial frequency weighting that is applied to the acceleration spectra. The trial frequency weighting consists of a frequency-independent primary frequency range, and subordinate frequency ranges in which the response to vibration diminishes, with cut-off frequencies that are changed to influence the magnitude of RR(f(trial)). The frequency weighting so derived when RR(f(trial)) = 1 is similar to those obtained by other methods (W(hf), W(hT)). It consists of a frequency independent range from about 25 Hz to 500 Hz (-3 dB frequencies), with an amplitude cut-off rate of 12 dB/octave below 25 Hz and above 500 Hz. The range is compatible with studies of vasoconstriction in persons with VWF. The results provide further evidence that the ISO frequency weighting may be inappropriate for assessing the risk of developing VWF. PMID:23060253

  8. Equivalent damping and frequency change for linear and nonlinear hybrid vibrational energy harvesting systems

    NASA Astrophysics Data System (ADS)

    Karami, M. Amin; Inman, Daniel J.

    2011-11-01

    A unified approximation method is derived to illustrate the effect of electro-mechanical coupling on vibration-based energy harvesting systems caused by variations in damping ratio and excitation frequency of the mechanical subsystem. Vibrational energy harvesters are electro-mechanical systems that generate power from the ambient oscillations. Typically vibration-based energy harvesters employ a mechanical subsystem tuned to resonate with ambient oscillations. The piezoelectric or electromagnetic coupling mechanisms utilized in energy harvesters, transfers some energy from the mechanical subsystem and converts it to an electric energy. Recently the focus of energy harvesting community has shifted toward nonlinear energy harvesters that are less sensitive to the frequency of ambient vibrations. We consider the general class of hybrid energy harvesters that use both piezoelectric and electromagnetic energy harvesting mechanisms. Through using perturbation methods for low amplitude oscillations and numerical integration for large amplitude vibrations we establish a unified approximation method for linear, softly nonlinear, and bi-stable nonlinear energy harvesters. The method quantifies equivalent changes in damping and excitation frequency of the mechanical subsystem that resembles the backward coupling from energy harvesting. We investigate a novel nonlinear hybrid energy harvester as a case study of the proposed method. The approximation method is accurate, provides an intuitive explanation for backward coupling effects and in some cases reduces the computational efforts by an order of magnitude.

  9. Study of electromagnetic vibration energy harvesting with free/impact motion for low frequency operation

    NASA Astrophysics Data System (ADS)

    Haroun, Ahmed; Yamada, Ichiro; Warisawa, Shin`ichi

    2015-08-01

    This paper presents study of an electromagnetic vibration energy harvesting configuration that can work effectively at low frequencies. Unlike the conventional form of vibration energy harvesters in which the mass is directly connected to a vibrating frame with spring suspension, in the proposed configuration a permanent magnet mass is allowed to move freely within a certain distance inside a frame-carrying coil and make impacts with spring end stops. The free motion distance allows matching lower vibration frequencies with an increase in the relative amplitude at resonance. Hence, significant power could be generated at low frequencies. A nonlinear mathematical model including impact and electromagnetic induction is derived. Study of the dynamic behaviour and investigation of the system performance is carried out with the aid of case study simulation. The proposed harvester shows a unique dynamic behaviour in which different ways of response of the internal relative oscillation appear over the range of input frequencies. A mathematical condition for the response type at which the higher relative amplitude appears is derived, followed by an investigation of the system resonant frequency and relative amplitude. The resonant frequency shows a dependency on the free motion distance as well as the utilized mass and spring stiffness. Simulation and experimental comparisons are carried out between the proposed harvester and similar conventional one tuned at the same input frequency. The power generated by the proposed harvesting configuration can reach more than 12 times at 11 Hz in the simulation case and about 10 times at 10 Hz in the experimental case. Simulation comparison also shows that this power magnification increases by matching lower frequencies which emphasize the advantages of the proposed configuration for low frequency operation.

  10. Vocal fold vibrations at high soprano fundamental frequencies.

    PubMed

    Echternach, Matthias; Döllinger, Michael; Sundberg, Johan; Traser, Louisa; Richter, Bernhard

    2013-02-01

    Human voice production at very high fundamental frequencies is not yet understood in detail. It was hypothesized that these frequencies are produced by turbulences, vocal tract/vocal fold interactions, or vocal fold oscillations without closure. Hitherto it has been impossible to visually analyze the vocal mechanism due to technical limitations. Latest high-speed technology, which captures 20,000 frames/s, using transnasal endoscopy was applied. Up to 1568 Hz human vocal folds do exhibit oscillations with complete closure. Therefore, the recent results suggest that human voice production at very high F0s up to 1568 Hz is not caused by turbulence, but rather by airflow modulation from vocal fold oscillations. PMID:23363198

  11. Distributed vibration sensing with time-resolved optical frequency-domain reflectometry.

    PubMed

    Zhou, Da-Peng; Qin, Zengguang; Li, Wenhai; Chen, Liang; Bao, Xiaoyi

    2012-06-01

    The distributed vibration or dynamic strain information can be obtained using time-resolved optical frequency-domain reflectometry. Time-domain information is resolved by measuring Rayleigh backscatter spectrum in different wavelength ranges which fall in successive time sequence due to the linear wavelength sweep of the tunable laser source with a constant sweeping rate. The local Rayleigh backscatter spectrum shift of the vibrated state with respect to that of the non-vibrated state in time sequence can be used to determine dynamic strain information at a specific position along the fiber length. Standard single-mode fibers can be used as sensing head, while the measurable frequency range of 0-32 Hz with the spatial resolution of 10 cm can be achieved up to the total length of 17 m. PMID:22714342

  12. The Possible Interstellar Anion CH2CN-: Spectroscopic Constants, Vibrational Frequencies, and Other Considerations

    NASA Technical Reports Server (NTRS)

    Fortenberry, Ryan C.; Crawford, T. Daniel; Lee, Timothy J.

    2012-01-01

    The A 1B1 <-1A0 excitation into the dipole-bound state of the cyanomethyl anion (CH2CN??) has been hypothesized as the carrier for one di use interstellar band. However, this particular molecular system has not been detected in the interstellar medium even though the related cyanomethyl radical and the isoelectronic ketenimine molecule have been found. In this study we are employing the use of proven quartic force elds and second-order vibrational perturbation theory to compute accurate spectroscopic constants and fundamental vibrational frequencies for X 1A0 CH2CN?? in order to assist in laboratory studies and astronomical observations. Keywords: Astrochemistry, ISM: molecular anions, Quartic force elds, Rotational constants, Vibrational frequencies

  13. Application of analysis techniques for low frequency interior noise and vibration of commercial aircraft

    NASA Technical Reports Server (NTRS)

    Landmann, A. E.; Tillema, H. F.; Macgregor, G. R.

    1992-01-01

    Finite element analysis (FEA), statistical energy analysis (SEA), and a power flow method (computer program PAIN) were used to assess low frequency interior noise associated with advanced propeller installations. FEA and SEA models were used to predict cabin noise and vibration and evaluate suppression concepts for structure-borne noise associated with the shaft rotational frequency and harmonics (less than 100 Hz). SEA and PAIN models were used to predict cabin noise and vibration and evaluate suppression concepts for airborne noise associated with engine radiated propeller tones. Both aft-mounted and wing-mounted propeller configurations were evaluated. Ground vibration test data from a 727 airplane modified to accept a propeller engine were used to compare with predictions for the aft-mounted propeller. Similar data from the 767 airplane was used for the wing-mounted comparisons.

  14. Note: A component-level frequency tunable isolator for vibration-sensitive chips using SMA beams.

    PubMed

    Zhang, Xiaoyong; Ding, Xin; Wu, Di; Qi, Junlei; Wang, Ruixin; Lu, Siwei; Yan, Xiaojun

    2016-06-01

    This note presents a component-level frequency tunable isolator for vibration-sensitive chips. The isolator employed 8 U-shaped shape memory alloy (SMA) beams to support an isolation island (used for mounting chips). Due to the temperature-induced Young's modulus variation of SMA, the system stiffness of the isolator can be controlled through heating the SMA beams. In such a way, the natural frequency of the isolator can be tuned. A prototype was fabricated to evaluate the concept. The test results show that the natural frequency of the isolator can be tuned in the range of 64 Hz-97 Hz by applying different heating strategies. Moreover, resonant vibration can be suppressed significantly (the transmissibility decreases about 65% near the resonant frequency) using a real-time tuning method. PMID:27370507

  15. Note: A component-level frequency tunable isolator for vibration-sensitive chips using SMA beams

    NASA Astrophysics Data System (ADS)

    Zhang, Xiaoyong; Ding, Xin; Wu, Di; Qi, Junlei; Wang, Ruixin; Lu, Siwei; Yan, Xiaojun

    2016-06-01

    This note presents a component-level frequency tunable isolator for vibration-sensitive chips. The isolator employed 8 U-shaped shape memory alloy (SMA) beams to support an isolation island (used for mounting chips). Due to the temperature-induced Young's modulus variation of SMA, the system stiffness of the isolator can be controlled through heating the SMA beams. In such a way, the natural frequency of the isolator can be tuned. A prototype was fabricated to evaluate the concept. The test results show that the natural frequency of the isolator can be tuned in the range of 64 Hz-97 Hz by applying different heating strategies. Moreover, resonant vibration can be suppressed significantly (the transmissibility decreases about 65% near the resonant frequency) using a real-time tuning method.

  16. Accurate calculation of vibrational frequencies using explicitly correlated coupled-cluster theory.

    PubMed

    Rauhut, Guntram; Knizia, Gerald; Werner, Hans-Joachim

    2009-02-01

    The recently proposed explicitly correlated CCSD(T)-F12x (x = a,b) approximations [T. B. Adler, G. Knizia, and H.-J. Werner, J. Chem. Phys. 127, 221106 (2007)] are applied to compute equilibrium structures and harmonic as well as anharmonic vibrational frequencies for H(2)O, HCN, CO(2), CH(2)O, H(2)O(2), C(2)H(2), CH(2)NH, C(2)H(2)O, and the trans-isomer of 1,2-C(2)H(2)F(2). Using aug-cc-pVTZ basis sets, the CCSD(T)-F12a equilibrium geometries and harmonic vibrational frequencies are in very close agreement with CCSD(T)/aug-cc-pV5Z values. The anharmonic frequencies are evaluated using vibrational self-consistent field and vibrational configuration interaction methods based on automatically generated potential energy surfaces. The mean absolute deviation of the CCSD(T)-F12a/aug-cc-pVTZ anharmonic frequencies from experimental values amounts to only 4.0 cm(-1). PMID:19206956

  17. Low frequency internal vibrations of norbornane and its derivatives studied by IINS and quantum chemistry calculations

    SciTech Connect

    Holderna-Natkaniec, K.; Natkaniec, I.; Khavryutchenko, V. D.

    1999-06-15

    The observed and calculated INS vibrational densities of states for globular molecules of norbornane, norborneole and borneole are compared in the frequency range up to 600 cm{sup -1}. Inelastic incoherent neutron scattering (IINS) spectra were measured at ca. 20 K on the high resolution NERA spectrometer at the IBR-2 pulsed reactor. The IINS intensities were calculated by semi-empirical quantum chemistry method and the assignments of the low-frequency internal modes were proposed.

  18. Stiffness nonlinearity as a means for resonance frequency tuning and enhancing mechanical robustness of vibration power harvesters

    NASA Astrophysics Data System (ADS)

    Loverich, J.; Geiger, R.; Frank, J.

    2008-03-01

    This paper addresses a particular type of power harvesting in which energy in the periodic movement of structures is parasitically converted to stored electric charge. In such applications, tuning of the vibration power harvesters' resonance frequency is often required to match the host structures' forcing frequency. This paper presents a method of adjusting the boundary conditions of nonlinear stiffness elements as a means of tuning the resonance frequency of piezoelectric vibration power harvesters (altering the deformation mode from bending to in-plane stretching). Using this tuning method, the resonance frequency was experimentally varied between 56 and 62 Hz. For a vibration level of 2 mm/s, the harvester has a similar Q to a linear system but its Q is reduced by one third at a vibration level of 10 mm/s. This behavior is important for applications where high sensitivity is required for low vibration levels but mechanical robustness is required for high vibration levels.

  19. Vibrational frequency shifts of fluid nitrogen fundamental and hot band transitions as a function of pressure and temperature

    SciTech Connect

    Schmidt, S.C.; Schiferl, D.; Zinn, A.S.; Ragan, D.D.; Moore, D.S.

    1989-01-01

    Coherent anti-Stokes Raman scattering (CARS) and spontaneous Raman spectroscopy have been used to obtain vibrational spectra of shock-compressed and static high-pressure fluid nitrogen, respectively. Vibrational frequencies were obtained from the CARS data using a semiclassical model for these spectra. Spontaneous Raman vibrational frequencies were determined by fitting data using a Lorentz shape line. A functional form was found for the dependence of the vibrational frequency on pressure and temperature to 40 GPa and 5000 K, respectively. The result is compared to a recent theoretical model. 6 refs., 2 figs., 1 tab.

  20. Application of frequency spectrum analysis in measuring multi-vibrations by using POTDR

    NASA Astrophysics Data System (ADS)

    Wang, Xiangchuan; Zhang, Xuping; Wang, Feng; Chen, Mengmeng; Li, Cunlei

    2011-11-01

    The technology of Polarization Optical Time Domain Reflectometer (POTDR) can be used to obtain the external events' information by measuring the change of state of polarization (SOP) of the Rayleigh backscattering in fiber. When the fiber is disturbed at two different positions simultaneously, we analyze the frequency spectrums of the change of Rayleigh backscattering light which are obtained by POTDR theoretically for ideal fiber, and by numerical simulation for single mode fibers. We find that the frequency spectrums between the first and second events contain the first vibration's frequency and its frequency multiplication. The frequency components of the spectrums after the second event are the linear combination of the first and the second events' frequencies. So we can obtain the location and the frequency information of the two events by analyzing the frequency spectrums. In addition, the frequency distribution in the frequency spectrums from different positions are different because of the different initial SOPs at different positions. So all the actual frequency information can not be obtained from only one frequency spectrum. We add up the frequency spectrums from the positions within a beat length to obtain the perturbation's frequency and the method can reduce the misdiagnosis rate because the sum of the frequency spectrums contains all the initial SOP within a beat length.

  1. Eulerian frequency analysis of structural vibrations from high-speed video

    NASA Astrophysics Data System (ADS)

    Venanzoni, Andrea; De Ryck, Laurent; Cuenca, Jacques

    2016-06-01

    An approach for the analysis of the frequency content of structural vibrations from high-speed video recordings is proposed. The techniques and tools proposed rely on an Eulerian approach, that is, using the time history of pixels independently to analyse structural motion, as opposed to Lagrangian approaches, where the motion of the structure is tracked in time. The starting point is an existing Eulerian motion magnification method, which consists in decomposing the video frames into a set of spatial scales through a so-called Laplacian pyramid [1]. Each scale - or level - can be amplified independently to reconstruct a magnified motion of the observed structure. The approach proposed here provides two analysis tools or pre-amplification steps. The first tool provides a representation of the global frequency content of a video per pyramid level. This may be further enhanced by applying an angular filter in the spatial frequency domain to each frame of the video before the Laplacian pyramid decomposition, which allows for the identification of the frequency content of the structural vibrations in a particular direction of space. This proposed tool complements the existing Eulerian magnification method by amplifying selectively the levels containing relevant motion information with respect to their frequency content. This magnifies the displacement while limiting the noise contribution. The second tool is a holographic representation of the frequency content of a vibrating structure, yielding a map of the predominant frequency components across the structure. In contrast to the global frequency content representation of the video, this tool provides a local analysis of the periodic gray scale intensity changes of the frame in order to identify the vibrating parts of the structure and their main frequencies. Validation cases are provided and the advantages and limits of the approaches are discussed. The first validation case consists of the frequency content

  2. Vibrational Spectral Signatures of Crystalline Cellulose Using High Resolution Broadband Sum Frequency Generation Vibrational Spectroscopy (HR-BB-SFG-VS)

    SciTech Connect

    Zhang, Libing; Lu, Zhou; Velarde Ruiz Esparza, Luis A.; Fu, Li; Pu, Yunqiao; Ding, Shi-You; Ragauskas, Art J.; Wang, Hongfei; Yang, Bin

    2015-03-03

    Here we reported the first sub-wavenumber high-resolution broadband sum frequency generation vibrational spectroscopy (HR-BB-SFG-VS) study on both the C-H and O-H region spectra of crystalline cellulose. HR-BB-SFG-VS has about 10 times better resolution than the conventional scanning SFG-VS and is known to be able to measure the intrinsic spectral lineshape and to resolve much more spectral details. With HR-BB-SFG-VS, we found that in cellulose from different sources, including Avicel and cellulose crystals isolated from algae Valonia (Iα) and tunicates (Iβ), the spectral signatures in the OH regions were unique for different allomorphs, i.e. Iα and Iβ, while the spectral signatures in the C-H regions varied in all samples examined. Even though the origin of the different behaviors of the crystalline cellulose in the O-H and C-H vibrational frequency regions is yet to be correlated to the structure of cellulose, these results provided new spectroscopic methods and opportunities to classify and understand the basic crystalline structure, as well as variations, in polymorphism of the crystalline cellulose structure.

  3. Vibrational spectral signatures of crystalline cellulose using high resolution broadband sum frequency generation vibrational spectroscopy (HR-BB-SFG-VS)

    SciTech Connect

    Zhang, Libing; Lu, Zhou; Velarde, Luis; Fu, Li; Pu, Yunqiao; Ding, Shi-You; Ragauskas, Arthur; Wang, Hong-Fei; Yang, Bin

    2015-03-03

    Both the C–H and O–H region spectra of crystalline cellulose were studied using the sub-wavenumber high-resolution broadband sum frequency generation vibrational spectroscopy (HR-BB-SFG-VS) for the first time. The resolution of HR-BB-SFG-VS is about 10-times better than conventional scanning SFG-VS and has the capability of measuring the intrinsic spectral lineshape and revealing many more spectral details. With HR-BB-SFG-VS, we found that in cellulose samples from different sources, including Avicel and cellulose crystals isolated from algae Valonia (Iα) and tunicates (Iβ), the spectral signatures in the O–H region were unique for the two allomorphs, i.e. Iα and Iβ, while the spectral signatures in the C–H regions varied in all samples examined. Even though the origin of the different spectral signatures of the crystalline cellulose in the O–H and C–H vibrational frequency regions are yet to be correlated to the structure of cellulose, these results lead to new spectroscopic methods and opportunities to classify and to understand the basic crystalline structures, as well as variations in polymorphism of the crystalline cellulose.

  4. Vibrational spectral signatures of crystalline cellulose using high resolution broadband sum frequency generation vibrational spectroscopy (HR-BB-SFG-VS)

    DOE PAGESBeta

    Zhang, Libing; Lu, Zhou; Velarde, Luis; Fu, Li; Pu, Yunqiao; Ding, Shi-You; Ragauskas, Arthur; Wang, Hong-Fei; Yang, Bin

    2015-03-03

    Both the C–H and O–H region spectra of crystalline cellulose were studied using the sub-wavenumber high-resolution broadband sum frequency generation vibrational spectroscopy (HR-BB-SFG-VS) for the first time. The resolution of HR-BB-SFG-VS is about 10-times better than conventional scanning SFG-VS and has the capability of measuring the intrinsic spectral lineshape and revealing many more spectral details. With HR-BB-SFG-VS, we found that in cellulose samples from different sources, including Avicel and cellulose crystals isolated from algae Valonia (Iα) and tunicates (Iβ), the spectral signatures in the O–H region were unique for the two allomorphs, i.e. Iα and Iβ, while the spectral signaturesmore » in the C–H regions varied in all samples examined. Even though the origin of the different spectral signatures of the crystalline cellulose in the O–H and C–H vibrational frequency regions are yet to be correlated to the structure of cellulose, these results lead to new spectroscopic methods and opportunities to classify and to understand the basic crystalline structures, as well as variations in polymorphism of the crystalline cellulose.« less

  5. A hybrid electromagnetic energy harvesting device for low frequency vibration

    NASA Astrophysics Data System (ADS)

    Jung, Hyung-Jo; Kim, In-Ho; Min, Dong Yi; Sim, Sung-Han; Koo, Jeong-Hoi

    2013-04-01

    An electromagnetic energy harvesting device, which converts a translational base motion into a rotational motion by using a rigid bar having a moving mass pivoted on a hinged point with a power spring, has been recently developed for use of civil engineering structures having low natural frequencies. The device utilizes the relative motion between moving permanent magnets and a fixed solenoid coil in order to harvest electrical power. In this study, the performance of the device is enhanced by introducing a rotational-type generator at a hinged point. In addition, a mechanical stopper, which makes use of an auxiliary energy harvesting part to further improve the efficiency, is incorporated into the device. The effectiveness of the proposed hybrid energy harvesting device based on electromagnetic mechanism is verified through a series of laboratory tests.

  6. Temperature dependence of vibrational frequency fluctuation of N3- in D2O

    NASA Astrophysics Data System (ADS)

    Tayama, Jumpei; Ishihara, Akane; Banno, Motohiro; Ohta, Kaoru; Saito, Shinji; Tominaga, Keisuke

    2010-07-01

    We have studied the temperature dependence of the vibrational frequency fluctuation of the antisymmetric stretching mode of N3- in D2O by three-pulse infrared (IR) photon echo experiments. IR pump-probe measurements were also carried out to investigate the population relaxation and the orientational relaxation of the same band. It was found that the time-correlation function (TCF) of the frequency fluctuation of this mode is well described by a biexponential function with a quasistatic term. The faster decay component has a time constant of about 0.1 ps, and the slower component varies from 1.4 to 1.1 ps in the temperature range from 283 to 353 K. This result indicates that liquid dynamics related to the frequency fluctuation are not highly sensitive to temperature. We discuss the relationship between the temperature dependence of the vibrational frequency fluctuation and that of the molecular motion of the system to investigate the molecular origin of the frequency fluctuation of the solute. We compare the temperature dependence of the frequency fluctuation with that of other dynamics such as dielectric relaxation of water. In contrast to the Debye dielectric relaxation time of D2O, the two time constants of the TCF of the frequency fluctuation do not exhibit strong temperature dependence. We propose a simple theoretical model for the frequency fluctuation in solutions based on perturbation theory and the dipole-dipole interaction between the vibrational mode of the solute and the solvent molecules. This model suggests that the neighboring solvent molecules in the vicinity of the solute play an important role in the frequency fluctuation. We suggest that the picosecond component of the frequency fluctuation results from structural fluctuation of the hydrogen-bonding network in water.

  7. Improving harmonic vibrational frequencies calculations in density functional theory

    NASA Astrophysics Data System (ADS)

    Stratmann, R. Eric; Burant, John C.; Scuseria, Gustavo E.; Frisch, Michael J.

    1997-06-01

    Using a previously introduced weight scheme, microbatching, and grid compression [R. E. Stratmann, G. E. Scuseria and M. J. Frisch, Chem. Phys. Lett. 257, 213 (1996)], we significantly speed up the numerical integration of the exchange-correlation contribution to the Coupled-Perturbed Kohn-Sham equations. In addition, we find that the nature of the integrand is such that it is possible to employ substantially fewer grid points in the quadrature and to use the Gaussian very Fast Multipole Method (GvFMM) with very short multipole expansions for the Coulomb contribution, with negligible loss in accuracy. As a representative example, the computational demand for the exchange-correlation portion of a coronene (C24H12) frequency calculation with a 3-21G basis is reduced by more than one order of magnitude. The overall speed up achieved in this calculation is between a factor of 4 to 6, depending on the specific functional. We also present sample calculations using polarized bases, gradient-corrected functionals, and on even larger systems (C54H18 and C96H24), to illustrate the various effects and improvements that we have accomplished.

  8. Two-dimensional resonance frequency tuning approach for vibration-based energy harvesting

    NASA Astrophysics Data System (ADS)

    Dong, Lin; Prasad, M. G.; Fisher, Frank T.

    2016-06-01

    Vibration-based energy harvesting seeks to convert ambient vibrations to electrical energy and is of interest for, among other applications, powering the individual nodes of wireless sensor networks. Generally it is desired to match the resonant frequencies of the device to the ambient vibration source to optimize the energy harvested. This paper presents a two-dimensionally (2D) tunable vibration-based energy harvesting device via the application of magnetic forces in two-dimensional space. These forces are accounted for in the model separately, with the transverse force contributing to the transverse stiffness of the system while the axial force contributes to a change in axial stiffness of the beam. Simulation results from a COMSOL magnetostatic 3D model agree well with the analytical model and are confirmed with a separate experimental study. Furthermore, analysis of the three possible magnetization orientations between the fixed and tuning magnets shows that the transverse parallel magnetization orientation is the most effective with regards to the proposed 2D tuning approach. In all cases the transverse stiffness term is in general significantly larger than the axial stiffness contribution, suggesting that from a tuning perspective it may be possible to use these stiffness contributions for coarse and fine frequency tuning, respectively. This 2D resonant frequency tuning approach extends earlier 1D approaches and may be particularly useful in applications where space constraints impact the available design space of the energy harvester.

  9. Piezoelectric Instruments of High Natural Frequency Vibration Characteristics and Protection Against Interference by Mass Forces

    NASA Technical Reports Server (NTRS)

    Gohlka, Werner

    1943-01-01

    The exploration of the processes accompanying engine combustion demands quick-responding pressure-recording instruments, among which the piezoelectric type has found widespread use because of its especially propitious properties as vibration-recording instruments for high frequencies. Lacking appropriate test methods, the potential errors of piezoelectric recorders in dynamic measurements could only be estimated up to now. In the present report a test method is described by means of which the resonance curves of the piezoelectric pickup can be determined; hence an instrumental appraisal of the vibration characteristics of piezoelectric recorders is obtainable.

  10. Vibrational frequencies associated with the carbide ligand in iron butterfly clusters

    SciTech Connect

    Stanghellini, P.L.; Sailor, M.J.; Kuznesof, P.; Whitmire, K.H.; Hriljac, J.A.; Kolis, J.W.; Zheng, Y.; Shriver, D.F.

    1987-09-09

    The vibrational frequencies associated with the exposed carbon atom in several tetranuclear iron carbide clusters with a butterfly arrangement of atoms were investigated by infrared and Raman spectroscopy. Vibrational assignments were confirmed in most cases by /sup 13/C labeling of the carbide carbon atom. The characteristic feature of the iron butterfly carbides is a readily observed band in the infrared spectrum around 900 cm/sup -1/. An approximate normal-coordinate analysis on these molecules yields values of the metal-carbon force constant of about 250 N m/sup -1/. 29 references, 6 figures, 5 tables.

  11. Quantitative Sum-Frequency Generation Vibrational Spectroscopy of Molecular Surfaces and Interfaces: Lineshape, Polarization and Orientation

    SciTech Connect

    Wang, Hongfei; Velarde, Luis; Gan, Wei; Fu, Li

    2015-04-01

    Sum-frequency generation vibrational spectroscopy (SFG) can provide detailed information and understanding of molecular vibrational spectroscopy, orientational and conformational structure, and interactions of molecular surfaces and interfaces, through quantitative measurement and analysis. In this review, we present the current status and discuss the main developments on the measurement of intrinsic SFG spectral lineshape, formulations for polarization measurement and orientation analysis of the SFG-VS spectra. The main focus is to present a coherent formulation and discuss the main concepts or issues that can help to make SFG-VS a quantitative analytical and research tool in revealing the chemistry and physics of complex molecular surface and interface.

  12. Influence of low-frequency vibration on changes of biochemical parameters of living rats

    NASA Astrophysics Data System (ADS)

    Kasprzak, Cezary; Damijan, Zbigniew; Panuszka, Ryszard

    2001-05-01

    The aim of the research was to investigate how some selected biochemical parameters of living rats depend on exposure of low-frequency vibrations. Experiments were run on 30 Wistar rats randomly segregated into three groups: (I) 20 days old (before puberty), (II) 70th day after; (III) control group. The exposure was repeated seven times, for 3 h, at the same time of day. Vibrations applied during the first tests of the experiment had acceleration 1.22 m/s2 and frequency 20 Hz. At the 135th day the rats' bones were a subject of morphometric/biochemical examination. The results of biochemical tests proved decrease in LDL and HDL cholesterol levels for exposed rats as well as the Ca contents in blood plasma. There was evident increasing of Ca in blood plasma in exposed rats for frequency of exposition.

  13. Use of chaotic and random vibrations to generate high frequency test inputs

    SciTech Connect

    Gregory, D. L.; Paez, T. L.

    1990-01-01

    This paper and a companion paper show the traditional limits on amplitude and frequency that can be generated in a laboratory test on a vibration exciter can be substantially extended. This is accomplished by attaching a device to the shaker that permits controlled metal to metal impacts that generate high frequency, high acceleration environment on a test surface. A companion paper (Reference 1) shows that a sinusoidal or random shaker input can be used to generate a random vibration environment on the test surface. This paper derives the three response components that occur on the test surface due to an impact on the bottom surface and the base driven response from the shaker input. These response components are used to generate impulse response functions and frequency response functions which are used in the companion paper to derive power spectral density functions for the overall response. 9 refs., 8 figs.

  14. Low frequency collective vibrational spectra of zwitterionic glycine studied by DFT

    NASA Astrophysics Data System (ADS)

    Ma, Shi Hua; Chen, Hua; Cui, Yi Ping

    2012-12-01

    Fourier transform infrared spectrometer and THz-TDS were used to obtain the experimental spectrum of glycine below 600 cm-1, and theoretical results of one or more zwitterionic glycine were calculated by DFT at the basis set of b31yp 6- 31+g(d,p) level based on Gaussian 03 software package in FIR region. There is more reasonable qualitative agreement between the calculated data of crystalline and observed line positions. Detailed assignments of the observed vibrational frequencies are discussed and the origins of some frequencies are analyzed by contrast. The low frequency collective mode of zwitterionic glycine is affected greatly by the intermolecular interaction and hydrogen-bonding effects and their vibrational modes are collective motion.

  15. Low-frequency band gap mechanism of torsional vibration of lightweight elastic metamaterial shafts

    NASA Astrophysics Data System (ADS)

    Li, Lixia; Cai, Anjiang

    2016-07-01

    In this paper, the low-frequency band gap mechanism of torsional vibration is investigated for a kind of light elastic metamaterial (EM) shafts architecture comprised of a radial double-period element periodically as locally resonant oscillators with low frequency property. The dispersion relations are calculated by a method combining the transfer matrix and a lumped-mass method. The theoretical results agree well with finite method simulations, independent of the density of the hard material ring. The effects of the material parameters on the band gaps are further explored numerically. Our results show that in contrast to the traditional EM shaft, the weight of our proposed EM shaft can be reduced by 27% in the same band gap range while the vibration attenuation is kept unchanged, which is very convenient to instruct the potential engineering applications. Finally, the band edge frequencies of the lower band gaps for this light EM shaft are expressed analytically using physical heuristic models.

  16. Spectrum of vibrational frequencies of crystalline tungsten at temperatures of 293 and 2400 K

    NASA Astrophysics Data System (ADS)

    Semenov, V. A.; Dubovsky, O. A.; Orlov, A. V.; Savostin, D. V.; Sudarev, V. V.

    2014-01-01

    The slow neutron inelastic scattering spectra for a refractory ( T melt = 3680 K) Group VI transition metal of the Periodic Table, namely, tungsten, were measured for the first time in the range from room temperature to 2400 K. Measurements of the neutron scattering spectra of tungsten were performed on a DIN-2PI time-of-flight spectrometer installed at the IBR-2 reactor (Dubna, Russia). The sample was heated in a TS3000 K high-temperature thermostat. The spectrum of vibrational frequencies of the crystal lattice of tungsten at temperatures of 293 and 2400 K was determined from the measured neutron scattering spectra by the iterative method. A softening of the frequency spectrum of tungsten was observed with increasing temperature. This was explained by the increasing role of vibrational anharmonicity effects at high temperatures. The experimental results were compared with model calculations of the frequency spectrum of tungsten.

  17. Coupled analysis of multi-impact energy harvesting from low-frequency wind induced vibrations

    NASA Astrophysics Data System (ADS)

    Zhu, Jin; Zhang, Wei

    2015-04-01

    Energy need from off-grid locations has been critical for effective real-time monitoring and control to ensure structural safety and reliability. To harvest energy from ambient environments, the piezoelectric-based energy-harvesting system has been proven very efficient to convert high frequency vibrations into usable electrical energy. However, due to the low frequency nature of the vibrations of civil infrastructures, such as those induced from vehicle impacts, wind, and waves, the application of a traditional piezoelectric-based energy-harvesting system is greatly restrained since the output power drops dramatically with the reduction of vibration frequencies. This paper focuses on the coupled analysis of a proposed piezoelectric multi-impact wind-energy-harvesting device that can effectively up-convert low frequency wind-induced vibrations into high frequency ones. The device consists of an H-shape beam and four bimorph piezoelectric cantilever beams. The H-shape beam, which can be easily triggered to vibrate at a low wind speed, is originated from the first Tacoma Narrows Bridge, which failed at wind speeds of 18.8 m s-1 in 1940. The multi-impact mechanism between the H-shape beam and the bimorph piezoelectric cantilever beams is incorporated to improve the harvesting performance at lower frequencies. During the multi-impact process, a series of sequential impacts between the H-shape beam and the cantilever beams can trigger high frequency vibrations of the cantilever beams and result in high output power with a considerably high efficiency. In the coupled analysis, the coupled structural, aerodynamic, and electrical equations are solved to obtain the dynamic response and the power output of the proposed harvesting device. A parametric study for several parameters in the coupled analysis framework is carried out including the external resistance, wind speed, and the configuration of the H-shape beam. The average harvested power for the piezoelectric cantilever

  18. INDIVIDUAL OPTIMAL FREQUENCY IN WHOLE BODY VIBRATION: EFFECT OF PROTOCOL, JOINT ANGLE AND FATIGUING EXERCISE.

    PubMed

    Carlucci, Flaminia; Felici, Francesco; Piccinini, Alberto; Haxhi, Jonida; Sacchetti, Massimo

    2013-04-12

    Recent studies have shown the importance of individualizing the vibration intervention in order to produce greater effects on the neuromuscular system in less time. The purpose of this study was to assess theindividualoptimalvibration frequency (O.V.F.)corresponding to the highestmuscle activation (RMSmax) duringvibrationat differentfrequencies, comparing different protocols. Twenty-nine university students underwent 3 Continuous (C) and 2 Random (R) different vibrating protocols, maintaining a squat position on a vibration platform. The C protocol lasted 50 seconds and involved the succession of ascending frequencies from 20 to 55 Hz, every 5 seconds. The same protocol was performed twice, having the knee angle at 120° (C) and 90° (C90), in order to assess the effect of joint angle, and after a fatiguing squatting exercise (CF) to evaluate the influence of fatigue on O.V.F. assessment. In therandomprotocols vibration time was 20 seconds with a 2-minute (R2) and a 4-minute (R4) pauses between tested frequencies. Muscle activation and O.V.F. values did not differ significantly in the C, R2 and R4 protocols. RMSmax was higher in C90 (p< 0.001) and in CF (p = 0.04) compared to the Cprotocol. Joint angle and fatiguing exercise had no effect on optimalvibration frequency. In conclusion, the shorter C protocol produced similar myoelectrical activity in the R2 and the R4 protocols and therefore could be equally valid in identifying the O.V.F. with considerable time efficiency. Knee joint angle and fatiguing exercise had an effect on sEMG response during vibration but did not affect significantly O.V.F. identification. PMID:23588483

  19. Occurrence of fatigue induced by a whole-body vibration session is not frequency dependent.

    PubMed

    Raphael, Zory F; Wesley, Aulbrook; Daniel, Keir A; Olivier, Serresse

    2013-09-01

    The aim of this study was to determine whether neuromuscular adaptations (magnitude and location) induced by isometric exercise performed on an oscillating platform are dependent on whole-body vibration (WBV) frequency. Eleven young men performed 4 separate fatigue sessions of static squatting exercise at 3 frequencies of WBV (V20, V40, and V60) and 1 session without vibration (V0). Isometric torque and electromyographic activity of the vastus lateralis, rectus femoris, and biceps femoris were recorded during maximal voluntary and evoked contractions of the knee extensor muscles before and after each fatigue session to examine both peripheral and central adaptations. Isometric torque decreased significantly after each of the 4 frequency sessions (V0: -9.4 ± 6.1%, p = 0.003; V20: -8.1 ± 9.9%, p = 0.010; V40: -11.9 ± 12.7%, p = 0.011; and V60: -7.8 ± 9.2%, p = 0.001, respectively), but this reduction was not significantly different between frequencies. The torque produced by evoked contraction significantly decreased from pre-exercise values after each session (V0: -14.9 ± 15.6%, p = 0.012; V20: -15.8 ± 16.4%, p = 0.010; V40: -21.0 ± 14.3%, p = 0.004; and V60: -17.3 ± 11.6%, p = 0.005, respectively); however, there was no effect of vibration frequency. In both conditions, the maximal voluntary contraction torque reduction observed was mainly attributable to peripheral fatigue and was not because of central modifications of the neuromuscular system. The present study demonstrates that the frequency of vibration does not significantly influence the magnitude and location of neuromuscular fatigue, suggesting that adding WBV to static squat exercise (on a vertically oscillating platform) does not provide an additional training stimulus. PMID:23249822

  20. Frontside-micromachined planar piezoresistive vibration sensor: Evaluating performance in the low frequency test range

    SciTech Connect

    Zhang, Lan; Lu, Jian Takagi, Hideki; Maeda, Ryutaro

    2014-01-15

    Using a surface piezoresistor diffusion method and front-side only micromachining process, a planar piezoresistive vibration sensor was successfully developed with a simple structure, lower processing cost and fewer packaging difficulties. The vibration sensor had a large sector proof mass attached to a narrow flexure. Optimization of the boron diffusion piezoresistor placed on the edge of the narrow flexure greatly improved the sensitivity. Planar vibration sensors were fabricated and measured in order to analyze the effects of the sensor dimensions on performance, including the values of flexure width and the included angle of the sector. Sensitivities of fabricated planar sensors of 0.09–0.46 mV/V/g were measured up to a test frequency of 60 Hz. The sensor functioned at low voltages (<3 V) and currents (<1 mA) with a high sensitivity and low drift. At low background noise levels, the sensor had performance comparable to a commercial device.

  1. Theory and experiment research for ultra-low frequency maglev vibration sensor

    SciTech Connect

    Zheng, Dezhi; Liu, Yixuan Guo, Zhanshe; Fan, Shangchun; Zhao, Xiaomeng

    2015-10-15

    A new maglev sensor is proposed to measure ultra-low frequency (ULF) vibration, which uses hybrid-magnet levitation structure with electromagnets and permanent magnets as the supporting component, rather than the conventional spring structure of magnetoelectric vibration sensor. Since the lower measurement limit needs to be reduced, the equivalent bearing stiffness coefficient and the equivalent damping coefficient are adjusted by the sensitivity unit structure of the sensor and the closed-loop control system, which realizes both the closed-loop control and the solving algorithms. A simple sensor experimental platform is then assembled based on a digital hardware system, and experimental results demonstrate that the lower measurement limit of the sensor is increased to 0.2 Hz under these experimental conditions, indicating promising results of the maglev sensor for ULF vibration measurements.

  2. Experimental research on anti-vibration interferometry based on time-frequency-domain analysis

    NASA Astrophysics Data System (ADS)

    Hu, Yao; Hao, Qun; Zhang, Fanghua; Tian, Yuhan

    2013-10-01

    Phase-shifting interferometry is a non-contact precision precise measuring method for optical surface, but it is highly sensitive to external vibrations. A time-and-frequency-domain (TFD) anti-noise phase-shifting interferometry is proposed to eliminate the effect of vibrations and improve the precision of measurement. According to simulations and preliminary experiments, active phase-shifting speed as well as interferogram capture speed should be increased to improve the anti-vibration capability of the TFD method. In this paper, a fast phase-shifting approach based on PZT actuator and interferogram detection with high-speed camera is proposed. Preliminary experimental results are given to demonstrate the approach.

  3. Theory and experiment research for ultra-low frequency maglev vibration sensor

    NASA Astrophysics Data System (ADS)

    Zheng, Dezhi; Liu, Yixuan; Guo, Zhanshe; Zhao, Xiaomeng; Fan, Shangchun

    2015-10-01

    A new maglev sensor is proposed to measure ultra-low frequency (ULF) vibration, which uses hybrid-magnet levitation structure with electromagnets and permanent magnets as the supporting component, rather than the conventional spring structure of magnetoelectric vibration sensor. Since the lower measurement limit needs to be reduced, the equivalent bearing stiffness coefficient and the equivalent damping coefficient are adjusted by the sensitivity unit structure of the sensor and the closed-loop control system, which realizes both the closed-loop control and the solving algorithms. A simple sensor experimental platform is then assembled based on a digital hardware system, and experimental results demonstrate that the lower measurement limit of the sensor is increased to 0.2 Hz under these experimental conditions, indicating promising results of the maglev sensor for ULF vibration measurements.

  4. Theory and experiment research for ultra-low frequency maglev vibration sensor.

    PubMed

    Zheng, Dezhi; Liu, Yixuan; Guo, Zhanshe; Zhao, Xiaomeng; Fan, Shangchun

    2015-10-01

    A new maglev sensor is proposed to measure ultra-low frequency (ULF) vibration, which uses hybrid-magnet levitation structure with electromagnets and permanent magnets as the supporting component, rather than the conventional spring structure of magnetoelectric vibration sensor. Since the lower measurement limit needs to be reduced, the equivalent bearing stiffness coefficient and the equivalent damping coefficient are adjusted by the sensitivity unit structure of the sensor and the closed-loop control system, which realizes both the closed-loop control and the solving algorithms. A simple sensor experimental platform is then assembled based on a digital hardware system, and experimental results demonstrate that the lower measurement limit of the sensor is increased to 0.2 Hz under these experimental conditions, indicating promising results of the maglev sensor for ULF vibration measurements. PMID:26520975

  5. Combined Amplitude and Frequency Measurements for Non-Contacting Turbomachinery Blade Vibration

    NASA Technical Reports Server (NTRS)

    Platt, Michael J. (Inventor); Jagodnik, John J. (Inventor)

    2013-01-01

    A method and apparatus for measuring the vibration of rotating blades, such as turbines, compressors, fans, or pumps, including sensing the return signal from projected energy and/or field changes from a plurality of sensors mounted on the machine housing. One or more of the sensors has a narrow field of measurement and the data is processed to provide the referenced time of arrival of each blade, and therefore the blade tip deflection due to vibration. One or more of the sensors has a wide field of measurement, providing a time history of the approaching and receding blades, and the data is processed to provide frequency content and relative magnitudes of the active mode(s) of blade vibration. By combining the overall tip deflection magnitude with the relative magnitudes of the active modes, the total vibratory stress state of the blade can be determined.

  6. Statistics and Properties of Low-Frequency Vibrational Modes in Structural Glasses.

    PubMed

    Lerner, Edan; Düring, Gustavo; Bouchbinder, Eran

    2016-07-15

    Low-frequency vibrational modes play a central role in determining various basic properties of glasses, yet their statistical and mechanical properties are not fully understood. Using extensive numerical simulations of several model glasses in three dimensions, we show that in systems of linear size L sufficiently smaller than a crossover size L_{D}, the low-frequency tail of the density of states follows D(ω)∼ω^{4} up to the vicinity of the lowest Goldstone mode frequency. We find that the sample-to-sample statistics of the minimal vibrational frequency in systems of size Lfrequency modes are spatially quasilocalized and that their localization and associated quartic anharmonicity are largely frequency independent. The effect of preparation protocols on the low-frequency modes is elucidated, and a number of glassy length scales are briefly discussed. PMID:27472122

  7. Temperature compensation method for the resonant frequency of a differential vibrating accelerometer using electrostatic stiffness control

    NASA Astrophysics Data System (ADS)

    Lee, Jungshin; Rhim, Jaewook

    2012-09-01

    Differential vibrating accelerometer (DVA) is a resonant-type sensor which detects the change in the resonant frequency in the presence of acceleration input, i.e. inertial loading. However, the resonant frequency of micromachined silicon resonators is sensitive to the temperature change as well as the input acceleration. Therefore, to design a high-precision vibrating accelerometer, the temperature sensitivity of the resonant frequency has to be predicted and compensated accurately. In this study, a temperature compensation method for resonant frequency is proposed which controls the electrostatic stiffness of the dual-ended tuning fork (DETF) using the temperature-dependent dc voltage between the parallel plate electrodes. To do this, the electromechanical model is derived first to predict the change in the electrostatic stiffness and the resonant frequency resulting from the dc voltage between the resonator and the electrodes. Next, the temperature sensitivity of the resonant frequency is modeled, estimated and compared with the measured values. Then it is shown that the resonant frequency of the DETF can be kept constant in the operating temperature range by applying the temperature-dependent driving voltage to the parallel plate electrodes. The proposed method is validated through experiment.

  8. The calculation of the vibrational frequencies of crystalline compounds and its implementation in the CRYSTAL code.

    PubMed

    Pascale, F; Zicovich-Wilson, C M; López Gejo, F; Civalleri, B; Orlando, R; Dovesi, R

    2004-04-30

    The problem of numerical accuracy in the calculation of vibrational frequencies of crystalline compounds from the hessian matrix is discussed with reference to alpha-quartz (SiO(2)) as a case study and to the specific implementation in the CRYSTAL code. The Hessian matrix is obtained by numerical differentiation of the analytical gradient of the energy with respect to the atomic positions. The process of calculating vibrational frequencies involves two steps: the determination of the equilibrium geometry, and the calculation of the frequencies themselves. The parameters controlling the truncation of the Coulomb and exchange series in Hartree-Fock, the quality of the grid used for the numerical integration of the Exchange-correlation potential in Density Functional Theory, the SCF convergence criteria, the parameters controlling the convergence of the optimization process as well as those controlling the accuracy of the numerical calculation of the Hessian matrix can influence the obtained vibrational frequencies to some extent. The effect of all these parameters is discussed and documented. It is concluded that with relatively economical computational conditions the uncertainty related to these parameters is smaller than 2-4 cm(-1). In the case of the Local Density Approximation scheme, comparison is possible with recent calculations performed with a Density Functional Perturbation Theory method and a plane-wave basis set. PMID:15011261

  9. Wide operation frequency band magnetostrictive vibration power generator using nonlinear spring constant by permanent magnet

    NASA Astrophysics Data System (ADS)

    Furumachi, S.; Ueno, T.

    2016-04-01

    We study magnetostrictive vibration based power generator using iron-gallium alloy (Galfenol). The generator is advantages over conventional, such as piezoelectric material in the point of high efficiency highly robust and low electrical impedance. Generally, the generator exhibits maximum power when its resonant frequency matches the frequency of ambient vibration. In other words, the mismatch of these frequencies results in significant decrease of the output. One solution is making the spring characteristics nonlinear using magnetic force, which distorts the resonant peak toward higher or lower frequency side. In this paper, vibrational generator consisting of Galfenol plate of 6 by 0.5 by 13 mm wound with coil and U shape-frame accompanied with plates and pair of permanent magnets was investigated. The experimental results show that lean of resonant peak appears attributed on the non-linear spring characteristics, and half bandwidth with magnets is 1.2 times larger than that without. It was also demonstrated that the addition of proof mass is effective to increase the sensitivity but also the bandwidth. The generator with generating power of sub mW order is useful for power source of wireless heath monitoring for bridge and factory machine.

  10. The lowest frequency vibrational fundamental of disilane: A three-band analysis

    NASA Astrophysics Data System (ADS)

    Borvayeh, L.; Moazzen-Ahmadi, N.; Horneman, V.-M.

    2007-04-01

    The lowest frequency perpendicular fundamental band ν9 of disilane has been analyzed to investigate torsion mediated vibrational interactions. We report here a three-band analysis involving torsional levels built on the ground state, the ν9 vibrational fundamental, and ν3 fundamental. This analysis includes transitions from the far-infrared torsional bands, ν4, 2 ν4 - ν4, 3 ν4 - 2 ν4, two perturbation-allowed rotational series from the overtone band 3 ν4 and transitions restricted to -21 ⩽ kΔ k ⩽ 21 in the ν9 fundamental band. An excellent fit to the included data was obtained. Two interactions are identified in this fit, a resonant Coriolis interaction between the ν9 torsional stack and that of the ground vibrational state and a Fermi interaction between the ν3 fundamental and the gs. The introduction of the Fermi interaction causes a large change in the barrier height for the ground vibrational state and makes the barrier shape parameter redundant, indicating that the vibrational contributions to the experimental barrier shape are dominant. Such effects have also been observed for ethane and other similar molecules.

  11. Effect of vehicle weight on natural frequencies of bridges measured from traffic-induced vibration

    NASA Astrophysics Data System (ADS)

    Kim, Chul-Young; Jung, Dae-Sung; Kim, Nam-Sik; Kwon, Soon-Duck; Feng, Maria Q.

    2003-06-01

    Recently, ambient vibration test (AVT) is widely used to estimate dynamic characteristics of large civil structures. Dynamic characteristics can be affected by various environmental factors such as humidity, intensity of wind, and temperature. Besides these environmental conditions, the mass of vehicles may change the measured values when traffic-induced vibration is used as a source of AVT for bridges. The effect of vehicle mass on dynamic characteristics is investigated through traffic-induced vibration tests on three bridges; (1) three-span suspension bridge (128m +404m + 128m), (2) five-span continuous steel box girder bridge (59m + 3@95m + 59m), (3) simply supported plate girder bridge (46m). Acceleration histories of each measurement location under normal traffic are recorded for 30 minutes at field. These recorded histories are divided into individual vibrations and are combined into two groups according to the level of vibration ; one by heavy vehicles such as trucks and buses and the other by light vehicles such as passenger cars. Separate processing of the two groups of signals shows that, for the middle and long-span bridges, the difference can be hardly detected, but, for the short span bridges whose mass is relatively small, the measured natural frequencies can change up to 5.4%.

  12. Three-dimensional piezoelectric vibration energy harvester using spiral-shaped beam with triple operating frequencies.

    PubMed

    Zhao, Nian; Yang, Jin; Yu, Qiangmo; Zhao, Jiangxin; Liu, Jun; Wen, Yumei; Li, Ping

    2016-01-01

    This work has demonstrated a novel piezoelectric energy harvester without a complex structure and appended component that is capable of scavenging vibration energy from arbitrary directions with multiple resonant frequencies. In this harvester, a spiral-shaped elastic thin beam instead of a traditional thin cantilever beam was adopted to absorb external vibration with arbitrary direction in three-dimensional (3D) spaces owing to its ability to bend flexibly and stretch along arbitrary direction. Furthermore, multiple modes in the elastic thin beam contribute to a possibility to widen the working bandwidth with multiple resonant frequencies. The experimental results show that the harvester was capable of scavenging the vibration energy in 3D arbitrary directions; they also exhibited triple power peaks at about 16 Hz, 21 Hz, and 28 Hz with the powers of 330 μW, 313 μW, and 6 μW, respectively. In addition, human walking and water wave energies were successfully converted into electricity, proving that our harvester was practical to scavenge the time-variant or multi-directional vibration energies in our daily life. PMID:26827346

  13. Three-dimensional piezoelectric vibration energy harvester using spiral-shaped beam with triple operating frequencies

    NASA Astrophysics Data System (ADS)

    Zhao, Nian; Yang, Jin; Yu, Qiangmo; Zhao, Jiangxin; Liu, Jun; Wen, Yumei; Li, Ping

    2016-01-01

    This work has demonstrated a novel piezoelectric energy harvester without a complex structure and appended component that is capable of scavenging vibration energy from arbitrary directions with multiple resonant frequencies. In this harvester, a spiral-shaped elastic thin beam instead of a traditional thin cantilever beam was adopted to absorb external vibration with arbitrary direction in three-dimensional (3D) spaces owing to its ability to bend flexibly and stretch along arbitrary direction. Furthermore, multiple modes in the elastic thin beam contribute to a possibility to widen the working bandwidth with multiple resonant frequencies. The experimental results show that the harvester was capable of scavenging the vibration energy in 3D arbitrary directions; they also exhibited triple power peaks at about 16 Hz, 21 Hz, and 28 Hz with the powers of 330 μW, 313 μW, and 6 μW, respectively. In addition, human walking and water wave energies were successfully converted into electricity, proving that our harvester was practical to scavenge the time-variant or multi-directional vibration energies in our daily life.

  14. Low frequency vibration induced streaming in a Hele-Shaw cell

    SciTech Connect

    Costalonga, M.; Brunet, P.; Peerhossaini, H.

    2015-01-15

    When an acoustic wave propagates in a fluid, it can generate a second order flow whose characteristic time is much longer than the period of the wave. Within a range of frequency between ten and several hundred Hz, a relatively simple and versatile way to generate streaming flow is to put a vibrating object in the fluid. The flow develops vortices in the viscous boundary layer located in the vicinity of the source of vibrations, leading in turn to an outer irrotational streaming called Rayleigh streaming. Because the flow originates from non-linear time-irreversible terms of the Navier-Stokes equation, this phenomenon can be used to generate efficient mixing at low Reynolds number, for instance in confined geometries. Here, we report on an experimental study of such streaming flow induced by a vibrating beam in a Hele-Shaw cell of 2 mm span using long exposure flow visualization and particle-image velocimetry measurements. Our study focuses especially on the effects of forcing frequency and amplitude on flow dynamics. It is shown that some features of this flow can be predicted by simple scaling arguments and that this vibration-induced streaming facilitates the generation of vortices.

  15. A theoretical study of the sum frequency vibrational spectroscopy of the carbon tetrachloride/water interface

    NASA Astrophysics Data System (ADS)

    Green, Anthony J.; Perry, Angela; Moore, Preston B.; Space, Brian

    2012-03-01

    Theoretical approximations to the sum frequency vibrational spectroscopy (SFVS) of the carbon tetrachloride/water interface are constructed using the quantum-corrected time correlation functions (TCF) to aid in interpretation of experimental data and to predict novel vibrational modes. Instantaneous normal mode (INM) methods are used to characterize the observed modes leading to the TCF signal, thus providing molecular resolution of the vibrational lineshapes. Detailed comparisons of the theoretical signals are made with those obtained experimentally and show excellent agreement for the spectral peaks in the O-H stretching region of water. An intermolecular mode, unique to the interface, at 848 cm-1 is also identifiable, similar to the one seen for the water/vapor interface. INM analysis reveals the resonance is due to a wagging mode (hindered rotation) that was previously identified (Perry et al 2005 J. Chem. Phys. 123 144705) as localized on a single water molecule with both hydrogens displaced normal to the interface—generally it is found that the symmetry breaking at the interface leads to hindered translations and rotations at hydrophilic/hydrophobic interfaces that assume finite vibrational frequencies due to anchoring at the aqueous interface. Additionally, examination of the real and imaginary parts of the theoretical SFVS spectra reveal the spectroscopic species attributed the resonances and possible subspecies in the O-H region; these results are consistent with extant experimental data and associated analysis.

  16. Low frequency vibration induced streaming in a Hele-Shaw cell

    NASA Astrophysics Data System (ADS)

    Costalonga, M.; Brunet, P.; Peerhossaini, H.

    2015-01-01

    When an acoustic wave propagates in a fluid, it can generate a second order flow whose characteristic time is much longer than the period of the wave. Within a range of frequency between ten and several hundred Hz, a relatively simple and versatile way to generate streaming flow is to put a vibrating object in the fluid. The flow develops vortices in the viscous boundary layer located in the vicinity of the source of vibrations, leading in turn to an outer irrotational streaming called Rayleigh streaming. Because the flow originates from non-linear time-irreversible terms of the Navier-Stokes equation, this phenomenon can be used to generate efficient mixing at low Reynolds number, for instance in confined geometries. Here, we report on an experimental study of such streaming flow induced by a vibrating beam in a Hele-Shaw cell of 2 mm span using long exposure flow visualization and particle-image velocimetry measurements. Our study focuses especially on the effects of forcing frequency and amplitude on flow dynamics. It is shown that some features of this flow can be predicted by simple scaling arguments and that this vibration-induced streaming facilitates the generation of vortices.

  17. Frequency Response of the Sample Vibration Mode in Scanning Probe Acoustic Microscope

    NASA Astrophysics Data System (ADS)

    Zhao, Ya-Jun; Cheng, Qian; Qian, Meng-Lu

    2010-05-01

    Based on the interaction mechanism between tip and sample in the contact mode of a scanning probe acoustic microscope (SPAM), an active mass of the sample is introduced in the mass-spring model. The tip motion and frequency response of the sample vibration mode in the SPAM are calculated by the Lagrange equation with dissipation function. For the silicon tip and glass assemblage in the SPAM the frequency response is simulated and it is in agreement with the experimental result. The living myoblast cells on the glass slide are imaged at resonance frequencies of the SPAM system, which are 20kHz, 30kHz and 120kHz. It is shown that good contrast of SPAM images could be obtained when the system is operated at the resonance frequencies of the system in high and low-frequency regions.

  18. Changes in postural sway frequency and complexity in altered sensory environments following whole body vibrations.

    PubMed

    Dickin, D Clark; McClain, Matthew A; Hubble, Ryan P; Doan, Jon B; Sessford, David

    2012-10-01

    Studies assessing whole body vibration (WBV) have produced largely positive effects, with some neutral, on postural control with frequencies between 25 and 40 Hz. However no conclusive evidence indicates that 25-40 Hz elicits the optimal beneficial effects. To address this issue, a larger range of vibration intensity (10-50 Hz at peak-to-peak amplitudes of 2 and 5mm) was employed while increasing the postural complexity (altered somatosensory and/or visual information) to assess acute effects of 4-min of WBV on postural control. Twelve healthy young adults underwent postural assessment at four time intervals (prior to, immediately following and 10 and 20 min post WBV). Findings revealed both postural sway frequency and sway complexity/regularity were affected by WBV. Baseline posture demonstrated increased sway frequency (p=.04) following WBV with no changes in sway complexity. When the support surface was altered, changes in both the frequency and complexity of sway were elicited (p=.027, .002, respectively). When both somatosensory and visual information were altered delayed improvements in postural control were elicited (p=.05 and .01, for frequency and complexity, respectively). Given the differential acute effects as a function of postural task complexity, future longitudinal studies could determine the overall training effect on sway frequency and complexity. PMID:22516837

  19. Novel Euler-LaCoste linkage as a very low frequency vertical vibration isolator

    NASA Astrophysics Data System (ADS)

    Hosain, M. A.; Sirr, A.; Ju, L.; Blair, D. G.

    2012-08-01

    LaCoste linkage vibration isolators have shown excellent performance for ultra-low frequency vertical vibration isolation. However, such isolators depend on the use of conventional pre-stressed coil springs, which suffer from creep. Here, we show that compressional Euler springs can be configured to create a stable tension unit for use in a LaCoste structure. In a proof of concept experiment, we demonstrate a vertical resonance frequency of 0.15 Hz in an Euler-LaCoste configuration with 200 mm height. The system enables the use of very low creep maraging steel as spring elements to eliminate the creep while minimising spring mass and reducing the effect of parasitic resonances. Larger scale systems with optimized Euler spring boundary conditions should achieve performance suitable for applications on third generation gravitational wave detectors such as the proposed Einstein telescope.

  20. An Accurate Quartic Force Field and Vibrational Frequencies for HNO and DNO

    NASA Technical Reports Server (NTRS)

    Dateo, Christopher E.; Lee, Timothy J.; Schwenke, David W.

    1994-01-01

    An accurate ab initio quartic force field for HNO has been determined using the singles and doubles coupled-cluster method that includes a perturbational estimate of the effects of connected triple excitations, CCSD(T), in conjunction with the correlation consistent polarized valence triple zeta (cc-pVTZ) basis set. Improved harmonic frequencies were determined with the cc-pVQZ basis set. Fundamental vibrational frequencies were determined using a second-order perturbation theory analysis and also using variational calculations. The N-0 stretch and bending fundamentals are determined well from both vibrational analyses. The H-N stretch, however, is shown to have an unusually large anharmonic correction, and is not well determined using second-order perturbation theory. The H-N fundamental is well determined from the variational calculations, demonstrating the quality of the ab initio quartic force field. The zero-point energy of HNO that should be used in isodesmic reactions is also discussed.

  1. Derivatives of buckling loads and vibration frequencies with respect to stiffness and initial strain parameters

    NASA Technical Reports Server (NTRS)

    Haftka, Raphael T.; Cohen, Gerald A.; Mroz, Zenon

    1990-01-01

    A uniform variational approach to sensitivity analysis of vibration frequencies and bifurcation loads of nonlinear structures is developed. Two methods of calculating the sensitivities of bifurcation buckling loads and vibration frequencies of nonlinear structures, with respect to stiffness and initial strain parameters, are presented. A direct method requires calculation of derivatives of the prebuckling state with respect to these parameters. An adjoint method bypasses the need for these derivatives by using instead the strain field associated with the second-order postbuckling state. An operator notation is used and the derivation is based on the principle of virtual work. The derivative computations are easily implemented in structural analysis programs. This is demonstrated by examples using a general purpose, finite element program and a shell-of-revolution program.

  2. A generator with nonlinear spring oscillator to provide vibrations of multi-frequency

    NASA Astrophysics Data System (ADS)

    Yang, Bin; Liu, Jingquan; Tang, Gang; Luo, Jiangbo; Yang, Chunsheng; Li, Yigui

    2011-11-01

    A piezoelectric generator with nonlinear spring oscillator is proposed to provide multiple resonant modes for operation and improve conversion efficiency. In order to scavenge the vibration energy of multiple frequencies from a certain vibration source, two types of nonlinear springs have been employed and tested. The maximum output power of 5, 17.83, and 23.39 μW for the nonlinear spring of 8.3 N/m with 1 g acceleration has been obtained under the resonant frequency of 89, 104, and 130 Hz, respectively. Its total output power of 46.22 μW is obviously larger than the one of 28.35 μW for traditional second-order spring-mass linear system.

  3. Novel Euler-LaCoste linkage as a very low frequency vertical vibration isolator.

    PubMed

    Hosain, M A; Sirr, A; Ju, L; Blair, D G

    2012-08-01

    LaCoste linkage vibration isolators have shown excellent performance for ultra-low frequency vertical vibration isolation. However, such isolators depend on the use of conventional pre-stressed coil springs, which suffer from creep. Here, we show that compressional Euler springs can be configured to create a stable tension unit for use in a LaCoste structure. In a proof of concept experiment, we demonstrate a vertical resonance frequency of 0.15 Hz in an Euler-LaCoste configuration with 200 mm height. The system enables the use of very low creep maraging steel as spring elements to eliminate the creep while minimising spring mass and reducing the effect of parasitic resonances. Larger scale systems with optimized Euler spring boundary conditions should achieve performance suitable for applications on third generation gravitational wave detectors such as the proposed Einstein telescope. PMID:22938333

  4. Mechanism of voltage production and frequency dependence of the ultrasonic vibration potential

    NASA Astrophysics Data System (ADS)

    Nguyen, Cuong K.; Wang, Shougang; Diebold, Gerald

    2009-05-01

    Imaging with the ultrasonic vibration potential is based on voltage generation by a colloidal or ionic suspension in response to the passage of ultrasound. The polarization within a body arising from the oscillatory displacement in the ultrasonic field produces a current in a pair of external electrodes that is measured as a function of time or frequency. Existing theory gives the current in the electrodes as arising from both a time varying polarization and ionic conduction. Here, experiments are reported that show the production of the polarization current is the dominant mechanism for current generation in soft tissue. Experiments are also reported giving the frequency dependence of the ultrasonic vibration current in canine blood and in several dilutions of aqueous silica suspensions.

  5. Structures and vibrational frequencies of FOOF and FONO using density functional theory

    NASA Astrophysics Data System (ADS)

    Amos, Roger D.; Murray, Christopher W.; Handy, Nicholas C.

    1993-02-01

    Calculations of the equilibrium structure and vibrational frequencies of FOOF using the local density approximation are in good agreement with experimental results. However using a theoretically more accurate gradient corrected (non-local) density functional produces a worse structure. Three isomers of FONO are also studied. The geometry of C 2v isomer FNO 2 is predicted accurately by the local density approximation, with gradient corrected functions again giving a poorer structure, but better vibrational frequencies. The structure of the trans-isomer of FONO is in agreement with recent coupled cluster studies, however calculations on cis-FONO disagree with the coupled cluster results, but may be in better agreement with the experimental geometry.

  6. Sum-Frequency Vibrational Spectroscopic Study of a Rubbed Polymer Surface

    NASA Astrophysics Data System (ADS)

    Wei, Xing; Zhuang, Xiaowei; Hong, Seok-Cheol; Goto, Tomohisa; Shen, Y. R.

    1999-05-01

    Sum-frequency vibrational spectroscopy has been used to probe the chain orientation of polyvinyl alcohol at the surface after rubbing. The distribution function of the chain orientation is determined quantitatively. The orientational order parameter of the chains deduced from the distribution matches well with that of a liquid crystal monolayer deposited on the polymer, proving that the polymer surface can align a liquid crystal film through orientational epitaxy.

  7. Low-frequency interlayer vibration modes in two-dimensional layered materials

    NASA Astrophysics Data System (ADS)

    Ji, Jianting; Dong, Shan; Zhang, Anmin; Zhang, Qingming

    2016-06-01

    Two-dimensional (2D) layered materials have been attracted tremendous research interest because of their novel photoelectric properties. If a single atomic layer instead of individual atoms is taken as a rigid motion object, two unique interlayer vibrations, i.e. compression/breathing and shear motions, at ultra-low frequencies can be expected and actually have been observed in many layered materials. The vibrations stem from the interlayer van der Waals interaction and can be well described by a conventional linear-chain model in most cases. The vibration frequencies strongly depend on layer thickness, which enables an accurate determination of layer numbers. A quick and nondestructive determination of flake thickness is particularly important for the materials, since the physical properties can be dramatically changed in the cases of several atomic layers. As a measure of interlayer coupling, the low-frequency modes are also sensitive to the stacking methods of atomic layers and the overlapping of different kinds of 2D materials. This allows the modes to play a key role in the applications like van der Waals heterojunctions. In this paper, we will give a brief review on the experimental observations and theoretical understanding of the interlayer modes in several typical 2D systems, as well as their actual and potential applications.

  8. Turbulent boundary layer induced vibration up to high frequencies by means of local energy methods

    NASA Astrophysics Data System (ADS)

    Hardy, Pierre; Jezequel, Louis; Ichchou, Mohammed; Jacques, Yves

    2002-11-01

    The local energy method developed in the last years revealed appropriate in medium and high frequencies and supplies an accurate description of the spread of vibration and acoustic fields up to high frequencies. Our aim in the paper is to provide a complete description of the turbulent boundary layer (TBL) induced vibration by means of this method, for a simply supported thin plate. The first step in the energy method proof is the characterization of energy input from a given model of the TBL pressure interspectrum. Then, is deduced the uncoherent structural response of the panel, and the uncoherent normal mean square velocity. The latter provides, using the acoustic radiation resistance, a prediction of noise radiating by the panel up to high frequencies. Accuracy of the local energy analysis versus the usual random normal modes decomposition is demonstrated. Ultimately, a numerical parametric survey is given for various internal loss level. Precisely, the link between results provided here and SEA predictions of TBL structural induced vibration is discussed.

  9. Vibrational characteristics of FRP-bonded concrete interfacial defects in a low frequency regime

    NASA Astrophysics Data System (ADS)

    Cheng, Tin Kei; Lau, Denvid

    2014-04-01

    As externally bonded fiber-reinforced polymer (FRP) is a critical load-bearing component of strengthened or retrofitted civil infrastructures, the betterment of structural health monitoring (SHM) methodology for such composites is imperative. Henceforth the vibrational characteristics of near surface interfacial defects involving delamination and trapped air pockets at the FRP-concrete interface are investigated in this study using a finite element approach. Intuitively, due to its lower interfacial stiffness compared with an intact interface, a damaged region is expected to have a set of resonance frequencies different from an intact region when excited by acoustic waves. It has been observed that, when excited acoustically, both the vibrational amplitudes and frequency peaks in the response spectrum of the defects demonstrate a significant deviation from an intact FRP-bonded region. For a thin sheet of FRP bonded to concrete with sizable interfacial defects, the fundamental mode under free vibration is shown to be relatively low, in the order of kHz. Due to the low resonance frequencies of the defects, the use of low-cost equipment for interfacial defect detection via response spectrum analysis is highly feasible.

  10. Analysis of vibration and frequency transmission of high speed EMU with flexible model

    NASA Astrophysics Data System (ADS)

    Ren, Zun-Song; Yang, Guang; Wang, Shan-Shan; Sun, Shou-Guang

    2014-12-01

    When the operation speed of the high-speed train increases and the weight of the carbody becomes lighter, not only does the sensitivity of the wheel/rail contact get higher, but also the vibration frequency range of the vehicle system gets enlarged and more frequencies are transmitted from the wheelset to the carbody. It is important to investigate the vibration characteristics and the dynamic frequency transmission from the wheel/rail interface to the carbody of the high-speed electric multi-uint (EMU). An elastic highspeed vehicle dynamics model is established in which the carbody, bogieframes, and wheelsets are all dealt with as flexible body. A rigid high-speed vehicle dynamics model is set up to compare with the simulation results of the elastic model. In the rigid vehicle model, the carbody, bogieframes and wheelsets are treated as rigid component while the suspension and structure parameters are the same as used in the elastic model. The dynamic characteristic of the elastic high speed vehicle is investigated in time and frequency domains and the difference of the acceleration, frequency distribution and transmission of the two types of models are presented. The results show that the spectrumpower density of the vehicle decreases from the wheelset to the carbody and the acceleration transmission ratio is approximately from 1% to 10% for each suspension system. The frequency of the wheelset rotation is evident in the vibration of the flexible model and is transmitted from the wheelset to the bogieframe and to the carbody. The results of the flexible model are more reasonable than that of the rigid model. A field test data of the high speed train are presented to verify the simulation results. It shows that the simulation results are coincidentwith the field test data.

  11. Modelling the vibration of sandwich beams using frequency-dependent parameters

    NASA Astrophysics Data System (ADS)

    Backström, D.; Nilsson, A. C.

    2007-03-01

    Various types of sandwich beams with foam or honeycomb cores are currently used in the industry, indicating the need for simple methods describing the dynamics of these complex structures. By implementing frequency-dependent parameters, the vibration of sandwich composite beams can be approximated using simple fourth-order beam theory. A higher-order sandwich beam model is utilized in order to obtain estimates of the frequency-dependent bending stiffness and shear modulus of the equivalent Bernoulli-Euler and Timoshenko models. The resulting predicted eigenfrequencies and transfer accellerance functions are compared to the data obtained from the higher-order model and from measurements.

  12. A scaling approach for the prediction of high-frequency mean responses of vibrating systems.

    PubMed

    Li, Xianhui

    2010-05-01

    This analysis presents a scaling approach to predict high-frequency mean responses of vibrating systems. The basis of the approach lies in the dynamic similitude between the original systems and the scaled models. A general scaling law is formulated using Skudrzyk's mean-value theorem and its specific form is derived for the case of a flexural plate. Modal density is scaled down to reduce the computational cost in the high-frequency mean response prediction. Different scaling procedures are numerically experimented and some insights are given about the accuracy of the scaling approach as compared with a dense finite element analysis. PMID:21117716

  13. Maximum allowable low-frequency platform vibrations in high resolution satellite missions: challenges and look-up figures

    NASA Astrophysics Data System (ADS)

    Haghshenas, Javad

    2015-09-01

    Performance of high resolution remote sensing payloads is often limited due to satellite platform vibrations. Effects of Linear and high frequency vibrations on the overall MTF are known exactly in closed form but the low frequency vibration effect is a random process and must be considered statistically. It should be considered in system level payload designing to know whether or not the overall MTF is limited by the vibration blur radius. Usually the vibration MTF budget is defined based on the mission requirements and the overall MTF limitations. With a good understanding of harmful vibration frequencies and amplitudes in the system preliminary design phase, their effects could be removed totally or partially. This procedure is cost effective and let designer to just eliminate the harmful vibrations and avoids over-designing. In this paper we have analyzed the effects of low-frequency platform vibrations on the payload's modulation transfer function. We have used a statistical analysis to find the probability of imaging with a MTF greater or equal to a pre-defined budget for different missions. After some discussions on the worst and average cases, we have proposed some "look-up figures" which would help the remote sensing payload designers to avoid the vibration effects. Using these figures, designer can choose the electro-optical parameters in such a way, that vibration effects be less than its pre-defined budget. Furthermore, using the results, we can propose a damping profile based on which vibration frequencies and amplitudes must be eliminated to stabilize the payload system.

  14. Whole body vibration at different exposure frequencies: infrared thermography and physiological effects.

    PubMed

    Sonza, Anelise; Robinson, Caroline C; Achaval, Matilde; Zaro, Milton A

    2015-01-01

    The aim of this study was to investigate the effects of whole body vibration (WBV) on physiological parameters, cutaneous temperature, tactile sensitivity, and balance. Twenty-four healthy adults (25.3 ± 2.6 years) participated in four WBV sessions. They spent 15 minutes on a vibration platform in the vertical mode at four different frequencies (31, 35, 40, and 44 Hz) with 1 mm of amplitude. All variables were measured before and after WBV exposure. Pressure sensation in five anatomical regions and both feet was determined using Von Frey monofilaments. Postural sway was measured using a force plate. Cutaneous temperature was obtained with an infrared camera. WBV influences the discharge of the skin touch-pressure receptors, decreasing sensitivity at all measured frequencies and foot regions (P ≤ 0.05). Regarding balance, no differences were found after 20 minutes of WBV at frequencies of 31 and 35 Hz. At 40 and 44 Hz, participants showed higher anterior-posterior center of pressure (COP) velocity and length. The cutaneous temperature of the lower limbs decreased during and 10 minutes after WBV. WBV decreases touch-pressure sensitivity at all measured frequencies 10 min after exposure. This may be related to the impaired balance at higher frequencies since these variables have a role in maintaining postural stability. Vasoconstriction might explain the decreased lower limb temperature. PMID:25664338

  15. Whole Body Vibration at Different Exposure Frequencies: Infrared Thermography and Physiological Effects

    PubMed Central

    Sonza, Anelise; Robinson, Caroline C.; Achaval, Matilde; Zaro, Milton A.

    2015-01-01

    The aim of this study was to investigate the effects of whole body vibration (WBV) on physiological parameters, cutaneous temperature, tactile sensitivity, and balance. Twenty-four healthy adults (25.3 ± 2.6 years) participated in four WBV sessions. They spent 15 minutes on a vibration platform in the vertical mode at four different frequencies (31, 35, 40, and 44 Hz) with 1 mm of amplitude. All variables were measured before and after WBV exposure. Pressure sensation in five anatomical regions and both feet was determined using Von Frey monofilaments. Postural sway was measured using a force plate. Cutaneous temperature was obtained with an infrared camera. WBV influences the discharge of the skin touch-pressure receptors, decreasing sensitivity at all measured frequencies and foot regions (P ≤ 0.05). Regarding balance, no differences were found after 20 minutes of WBV at frequencies of 31 and 35 Hz. At 40 and 44 Hz, participants showed higher anterior-posterior center of pressure (COP) velocity and length. The cutaneous temperature of the lower limbs decreased during and 10 minutes after WBV. WBV decreases touch-pressure sensitivity at all measured frequencies 10 min after exposure. This may be related to the impaired balance at higher frequencies since these variables have a role in maintaining postural stability. Vasoconstriction might explain the decreased lower limb temperature. PMID:25664338

  16. Effects of vibration frequency on vibration-assisted nano-scratch process of mono-crystalline copper via molecular dynamics simulation

    NASA Astrophysics Data System (ADS)

    Zhu, Bo; Zhao, Hongwei; Zhao, Dan; Zhang, Peng; Yang, Yihan; Han, Lei; Kui, Hailin

    2016-03-01

    It has always been a critical issue to understand the material removal behavior of Vibration-Assisted Machining (VAM), especially on atomic level. To find out the effects of vibration frequency on material removal response, a three-dimensional molecular dynamics (MD) model has been established in this research to investigate the effects of scratched groove, crystal defects on the surface quality, comparing with the Von Mises shear strain and tangential force in simulations during nano-scratching process. Comparisons are made among the results of simulations from different vibration frequency with the same scratching feed, depth, amplitude and crystal orientation. Copper potential in this simulation is Embedded-Atom Method (EAM) potential. Interaction between copper and carbon atoms is Morse potential. Simulational results show that higher frequency can make groove smoother. Simulation with high frequency creates more dislocations to improve the machinability of copper specimen. The changing frequency does not have evident effects on Von Mises shear strain. Higher frequency can decrease the tangential force to reduce the consumption of cutting energy and tool wear. In conclusion, higher vibration frequency in VAM on mono-crystalline copper has positive effects on surface finish, machinablility and tool wear reduction.

  17. An automated fringe counting laser interferometer for low frequency vibration measurements

    NASA Astrophysics Data System (ADS)

    Payne, B. F.; Federman, Charles

    Low-frequency accelerometers and velocity transducers are widely used to investigate vibrations on structures such as buildings, bridges, aircraft, ships, power plant equipment, and in seismic applications. Previous work at NBS in this area has focused on the development of accurate calibration methods for transducers by optical methods in the frequency range of 2-100 Hz. This paper describes a computer-controlled fringe-counting interferometric system for transducer calibration. The calibration system uses digital signal analysis for accurate low-frequency voltage measurements. The measurement procedures are fully automated, with menu-driven programs using the computer soft keys for controlling the test frequencies and acceleration, setting test parameters, collecting and storing data and producing reports and graphs. An error analysis is given and experimental data are presented for a typical transducer calibrated on this system.

  18. Dual-wavelength speckle-based SI-POF sensor for frequency detection and localization of remote vibrations

    NASA Astrophysics Data System (ADS)

    Pinzón, P. J.; Montero, D. S.; Tapetado, A.; Torres, J. C.; Vázquez, C.

    2016-05-01

    A novel speckle-based method for sensing frequency vibration is demonstrated in a reflective configuration. By employing a visible dual-wavelength approach it is also possible to determine the relative spatial location of the vibrations along a plastic optical fiber lead of 8 m in a distributed scheme.

  19. Modern blast vibration monitoring, modeling and frequency control at Tara Mines, Ireland

    SciTech Connect

    Durucan, S.; Johnston, G.J.; O`Reilly, B.

    1994-12-31

    Historically vibration monitoring has dealt primarily with surface blasting or near field monitoring of underground blasts. The Situation at Tara Miens is different, blasting occurs up to 400 m underground, with a number of blasts occurring daily and occasionally with residential properties directly above the blasting site. Tara Mines, due to both its location (1.5 km from the rural town of Navan) and stringent planning conditions have always had to monitor, carefully plan and control the levels of vibration from blasting. Tara has recently upgraded it`s monitoring equipment with the purchase of eight Instantel DS-677 Blastmate Series 2 monitors, located in four permanent stations and four portable monitors around the mine. Controlled experiments and routine monitoring of production blasting aims at improving the empirical estimation methods in the short term and the results in the long term at the development of a more reliable predictive model allowing for not only the peak particle velocity of the vibration but also the frequency. This paper is based on the results of the first years research and testing within the project. This paper also deals with monitoring techniques at Tara with respect to seismometer placement, variations in readings, versatility and accuracy of the meters and compares planned vibration levels with measured levels. The paper also deals with the variation of the dominant frequencies, from the blast patterns used at Tara in relation to the delay timing sequence. Some allowances have been made for the transmission path of the frequency pulse and the geological structure around the deposit.

  20. The vibrating reed frequency meter: digital investigation of an early cochlear model

    PubMed Central

    Wit, Hero P.

    2015-01-01

    The vibrating reed frequency meter, originally employed by Békésy and later by Wilson as a cochlear model, uses a set of tuned reeds to represent the cochlea’s graded bank of resonant elements and an elastic band threaded between them to provide nearest-neighbour coupling. Here the system, constructed of 21 reeds progressively tuned from 45 to 55 Hz, is simulated numerically as an elastically coupled bank of passive harmonic oscillators driven simultaneously by an external sinusoidal force. To uncover more detail, simulations were extended to 201 oscillators covering the range 1–2 kHz. Calculations mirror the results reported by Wilson and show expected characteristics such as traveling waves, phase plateaus, and a response with a broad peak at a forcing frequency just above the natural frequency. The system also displays additional fine-grain features that resemble those which have only recently been recognised in the cochlea. Thus, detailed analysis brings to light a secondary peak beyond the main peak, a set of closely spaced low-amplitude ripples, rapid rotation of phase as the driving frequency is swept, frequency plateaus, clustering, and waxing and waning of impulse responses. Further investigation shows that each reed’s vibrations are strongly localised, with small energy flow along the chain. The distinctive set of equally spaced ripples is an inherent feature which is found to be largely independent of boundary conditions. Although the vibrating reed model is functionally different to the standard transmission line, its cochlea-like properties make it an intriguing local oscillator model whose relevance to cochlear mechanics needs further investigation. PMID:26623180

  1. Chiral Vibrational Structures of Proteins at Interfaces Probed by Sum Frequency Generation Spectroscopy

    PubMed Central

    Fu, Li; Wang, Zhuguang; Yan, Elsa C.Y.

    2011-01-01

    We review the recent development of chiral sum frequency generation (SFG) spectroscopy and its applications to study chiral vibrational structures at interfaces. This review summarizes observations of chiral SFG signals from various molecular systems and describes the molecular origins of chiral SFG response. It focuses on the chiral vibrational structures of proteins and presents the chiral SFG spectra of proteins at interfaces in the C-H stretch, amide I, and N-H stretch regions. In particular, a combination of chiral amide I and N-H stretches of the peptide backbone provides highly characteristic vibrational signatures, unique to various secondary structures, which demonstrate the capacity of chiral SFG spectroscopy to distinguish protein secondary structures at interfaces. On the basis of these recent developments, we further discuss the advantages of chiral SFG spectroscopy and its potential application in various fields of science and technology. We conclude that chiral SFG spectroscopy can be a new approach to probe chiral vibrational structures of protein at interfaces, providing structural and dynamic information to study in situ and in real time protein structures and dynamics at interfaces. PMID:22272140

  2. Application of ground vibration frequency spectrum analysis as a tool for optimizing the blast design in large open pit mines

    SciTech Connect

    Rao, K.R.

    1994-12-31

    This paper explains the methodology for assessing the efficiency of rockmass fragmentation by explosive blasting, from ground vibration frequency spectrum analysis of the blast event. Explosives are used in the mining, quarrying and construction industries for fragmenting rockmass to a suitable size. When an explosive charge is detonated, in addition to fragmenting the rockmass, it will also generate ground vibration and air vibrations. Efficiency of a blast depend upon percentage of blast energy wasted in generating ground vibrations and air vibrations. This in turn will depend upon rockmass characteristics, amount of explosive energy used per delay and spatial distribution of explosive in the rockmass. Ground vibrations and air vibrations, arising out of explosive detonation in a rockmass, could be captured by micro-computer based engineering seismograph and sound level meter. Typical frequency range indicative of efficient rockmass fragmentation for a particular rockmass can be identified from ground vibration frequency spectra analysis of the blast event on a personal computer applying Fast Fourier transforms (FFT). The typical frequency range indicative of efficient rockmass fragmentation depends upon rockmass impedance and can be estimated from rockmass characteristics and monitoring few trial blasts. Blast event efficiency is estimated by comparing the typical frequency range with the dominant frequency range of the blast event record. A large number of blast events monitored and analyzed by the author in different rockmass formations and correlation of the results with observations made while fragmented material is lifted and loaded into trucks indicated that ground vibration frequency spectrum analysis could be used as a reliable and cost effective tool for assessing the blasting efficiency and optimizing blast design in large open-pit mines.

  3. Design of piezoelectric MEMS cantilever for low-frequency vibration energy harvester

    NASA Astrophysics Data System (ADS)

    Takei, Ryohei; Makimoto, Natsumi; Okada, Hironao; Itoh, Toshihiro; Kobayashi, Takeshi

    2016-06-01

    We report the design of piezoelectric MEMS cantilevers formed on a silicon-on-insulator wafer to efficiently harvest electrical power from harmonic vibration with a frequency of approximately 30 Hz. Numerical simulation indicates that a >4-µm-thick top silicon layer and >3-µm-thick piezoelectric film are preferable to maximize the output electrical power. An in-plane structure of the cantilever is also designed retaining the footprint of the cantilever. The simulation results indicate that the output power is maximized when the length ratio of the proof mass to the cantilever beam is 1.5. To ensure the accuracy of the simulation, we fabricated and characterized cantilevers with a 10-µm-thick top silicon layer and a 1.8-µm-thick piezoelectric film, resulting in 0.21 µW at a vibration of 0.5 m/s2 and 25.1 Hz. The measured output power is in agreement with the simulated value, meaning that the design is significantly reliable for low-frequency vibration energy harvesters.

  4. Theoretical determination of parity-violating vibrational frequency differences between the enantiomers of chiral molecules.

    PubMed

    Viglione, Rosario G

    2004-11-22

    A perturbation treatment has been used to compute the leading first- and second-order parity-violating corrections to the vibrational energy levels of a chiral molecule. Assuming the molecular equilibrium geometry as expansion point of both parity-violating and parity-conserving potential-energy surfaces, it is shown that these corrections, i.e., harmonic and anharmonic contributions, are of the same order of magnitude and that none of them can be neglected for a realistic determination of vibrational frequency differences. Numerical tests based on ab initio MP2 force fields and quantum-relativistic calculations of the parity-violating potential for each normal mode of PHBrF and AsHBrF molecules confirm this conclusion. In particular, it is shown that a normal mode of AsHBrF is characterized by one of the largest vibrational frequency difference ever found--the prediction is approximately 0.1 Hz--only one order of magnitude less than the presumed resolution limit of current experimental investigations. PMID:15549870

  5. Magnetoelastic beam with extended polymer for low frequency vibration energy harvesting

    NASA Astrophysics Data System (ADS)

    Ibrahim, Alwathiqbellah; Towfighian, Shahrzad; Younis, Mohammad; Su, Quang

    2016-04-01

    Ambient energy in the form of mechanical kinetic energy is mostly considered waste energy. The process of scavenging and storing such energy is known as energy harvesting. Energy harvesting from mechanical vibration is performed using resonant energy harvesters (EH) with two major goals: enhancing the power scavenged at low frequency sources of vibrations, and increasing the efficiency of scavenging energy by increasing the bandwidth near the resonant frequency. Toward such goals, we propose a piezoelectric EH of a composite cantilever beam with a tip magnet facing another magnet at a distance. The composite cantilever consists of a piezoelectric bimorph with an extended polymer material. With the effect of the nonlinearity of the magnetic force, higher amplitude can be achieved because of the generated bi-stability oscillations of the cantilever beam under harmonic excitation. The contribution of the this paper is to demonstrate lowering the achieved resonant frequency down to 17 Hz compared to 100 Hz for the piezoelectric bimorph beam without the extended polymer. Depending on the magnetic distance, the beam responses are divided to mono and bi-stable regions, for which we investigate static and dynamic behaviors. The dynamics of the system and the frequency and voltage responses of the beam are obtained using the shooting method.

  6. Composite 3D-printed metastructures for low-frequency and broadband vibration absorption.

    PubMed

    Matlack, Kathryn H; Bauhofer, Anton; Krödel, Sebastian; Palermo, Antonio; Daraio, Chiara

    2016-07-26

    Architected materials that control elastic wave propagation are essential in vibration mitigation and sound attenuation. Phononic crystals and acoustic metamaterials use band-gap engineering to forbid certain frequencies from propagating through a material. However, existing solutions are limited in the low-frequency regimes and in their bandwidth of operation because they require impractical sizes and masses. Here, we present a class of materials (labeled elastic metastructures) that supports the formation of wide and low-frequency band gaps, while simultaneously reducing their global mass. To achieve these properties, the metastructures combine local resonances with structural modes of a periodic architected lattice. Whereas the band gaps in these metastructures are induced by Bragg scattering mechanisms, their key feature is that the band-gap size and frequency range can be controlled and broadened through local resonances, which are linked to changes in the lattice geometry. We demonstrate these principles experimentally, using advanced additive manufacturing methods, and inform our designs using finite-element simulations. This design strategy has a broad range of applications, including control of structural vibrations, noise, and shock mitigation. PMID:27410042

  7. Ultralow frequency acoustic bandgap and vibration energy recovery in tetragonal folding beam phononic crystal

    NASA Astrophysics Data System (ADS)

    Gao, Nansha; Wu, Jiu Hui; Yu, Lie; Hou, Hong

    2016-06-01

    This paper investigates ultralow frequency acoustic properties and energy recovery of tetragonal folding beam phononic crystal (TFBPC) and its complementary structure. The dispersion curve relationships, transmission spectra and displacement fields of the eigenmodes are studied with FEA in detail. Compared with the traditional three layer phononic crystal (PC) structure, this structure proposed in this paper not only unfold bandgaps (BGs) in lower frequency range (below 300 Hz), but also has lighter weight because of beam structural cracks. We analyze the relevant physical mechanism behind this phenomenon, and discuss the effects of the tetragonal folding beam geometric parameters on band structure maps. FEM proves that the multi-cell structures with different arrangements have different acoustic BGs when compared with single cell structure. Harmonic frequency response and piezoelectric properties of TFBPC are specifically analyzed. The results confirm that this structure does have the recovery ability for low frequency vibration energy in environment. These conclusions in this paper could be indispensable to PC practical applications such as BG tuning and could be applied in portable devices, wireless sensor, micro-electro mechanical systems which can recycle energy from vibration environment as its own energy supply.

  8. A low frequency vibration energy harvester using dual Halbach array suspended in magnetic springs

    NASA Astrophysics Data System (ADS)

    Salauddin, M.; Halim, M. A.; Park, J. Y.

    2015-12-01

    An electromagnetic (EM) low frequency vibration energy harvester is newly developed based on dual Halbach array which is suspended in two magnetic springs. Each Halbach array concentrates the magnetic flux lines on one side of the array while suppressing the flux lines on the other side. Dual Halbach array allows the concentrated magnetic flux lines to interact with the same coil in a way where maximum flux linkage occurs. With the goal of higher power generation in low amplitude and low frequency vibrations, the magnetic structures (both the dual Halbach array and the magnetic springs) were optimized in terms of operating frequency and power density. A prototype was fabricated and tested. It is capable of delivering maximum 1.09mW average power to 44Ω optimum load at 11Hz resonant frequency and 0.5g acceleration. The prototype device offers 33.4μWcm-3 average power density which is much higher than recently reported electromagnetic energy harvesters.

  9. An efficient low frequency horizontal diamagnetic levitation mechanism based vibration energy harvester

    NASA Astrophysics Data System (ADS)

    Palagummi, S.; Yuan, F. G.

    2016-04-01

    This article identifies and studies key parameters that characterize a horizontal diamagnetic levitation (HDL) mechanism based low frequency vibration energy harvester with the aim of enhancing performance metrics such as efficiency and volume figure of merit (FoMv). The HDL mechanism comprises of three permanent magnets and two diamagnetic plates. Two of the magnets, aka lifting magnets, are placed co-axially at a distance such that each attract a centrally located magnet, aka floating magnet, to balance its weight. This floating magnet is flanked closely by two diamagnetic plates which stabilize the levitation in the axial direction. The influence of the geometry of the floating magnet, the lifting magnet and the diamagnetic plate are parametrically studied to quantify their effects on the size, stability of the levitation mechanism and the resonant frequency of the floating magnet. For vibration energy harvesting using the HDL mechanism, a coil geometry and eddy current damping are critically discussed. Based on the analysis, an efficient experimental system is setup which showed a softening frequency response with an average system efficiency of 25.8% and a FoMv of 0.23% when excited at a root mean square acceleration of 0.0546 m/s2 and at frequency of 1.9 Hz.

  10. Stick-slip failure in granular experiments: the role of low-frequency vibrational modes

    NASA Astrophysics Data System (ADS)

    Brzinski, T., III; Daniels, K.

    2014-12-01

    The intermittent nature of strain at geological faults is a consequence of the loss of rigidity of the gouge. Due to the granular nature of the gouge, we take insight from granular physics in order to characterize the role of gouge in the generation of seismic events. In static granular packings, the loss of rigidity has been observed to be associated with an excess in low-frequency vibrational modes. The same holds true in both molecular and colloidal glasses, suggesting that excess low-frequency vibrational modes are a general feature in the failure of disordered solids. Therefore, we seek a relationship between these low-frequency modes and spatiotemporal patterns of failure by studying an experimental analog to a geological fault. Specifically, we measure the acoustic emissions from jammed, quasi-2D granular packings under shear. We use a split-bottom annular shear geometry, driven with a linear-ramp torque in order to generate stick-slip behavior, and observe intervals of both periodic and aperiodic slip. We investigate how low-frequency emissions are associated with both local and global slip events of various magnitudes and directions. Twelve piezoelectric acoustic receivers, an imaging system, and high-resolution stress/strain sensors enable direct comparison of acoustic properties as the system approaches failure. The use of photoelastic grains enables local measurement of changes to the internal stresses.

  11. Research on the key parameters influencing the anti-vibration capability of time-frequency-domain interferometer

    NASA Astrophysics Data System (ADS)

    Zhang, Fanghua; Hao, Qun; Hu, Yao; Zhu, Qiudong

    2012-11-01

    This paper introduces a time-and-frequency-domain (TFD) anti-noise phase-shifting interferometry, and designs an experimental system to test the anti-vibration ability of this method. In the system, a plane mirror is measured under the external vibrations simulated by the standard mirror propelled by PZT. During the measurement, each of the key parameters is assigned different values. By analyzing the testing results, the law of the parameters' influence on system anti-vibration capability can be obtained. According to the law, the optimization parameters can be determined so that the system has the maximum anti- vibration capability.

  12. Topology optimization and fabrication of low frequency vibration energy harvesting microdevices

    NASA Astrophysics Data System (ADS)

    Deng, Jiadong; Rorschach, Katherine; Baker, Evan; Sun, Cheng; Chen, Wei

    2015-02-01

    Topological design of miniaturized resonating structures capable of harvesting electrical energy from low frequency environmental mechanical vibrations encounters a particular physical challenge, due to the conflicting design requirements: low resonating frequency and miniaturization. In this paper structural static stiffness to resist undesired lateral deformation is included into the objective function, to prevent the structure from degenerating and forcing the solution to be manufacturable. The rational approximation of material properties interpolation scheme is introduced to deal with the problems of local vibration and instability of the low density area induced by the design dependent body forces. Both density and level set based topology optimization (TO) methods are investigated in their parameterization, sensitivity analysis, and applicability for low frequency energy harvester TO problems. Continuum based variation formulations for sensitivity analysis and the material derivative based shape sensitivity analysis are presented for the density method and the level set method, respectively; and their similarities and differences are highlighted. An external damper is introduced to simulate the energy output of the resonator due to electrical damping and the Rayleigh proportional damping is used for mechanical damping. Optimization results for different scenarios are tested to illustrate the influences of dynamic and static loads. To demonstrate manufacturability, the designs are built to scale using a 3D microfabrication method and assembled into vibration energy harvester prototypes. The fabricated devices based on the optimal results from using different TO techniques are tested and compared with the simulation results. The structures obtained by the level set based TO method require less post-processing before fabrication and the structures obtained by the density based TO method have resonating frequency as low as 100 Hz. The electrical voltage response

  13. Dynamics of liquid films exposed to high-frequency surface vibration

    NASA Astrophysics Data System (ADS)

    Manor, Ofer; Rezk, Amgad R.; Friend, James R.; Yeo, Leslie Y.

    2015-05-01

    We derive a generalized equation that governs the spreading of liquid films under high-frequency (MHz-order) substrate vibration in the form of propagating surface waves and show that this single relationship is universally sufficient to collectively describe the rich and diverse dynamic phenomena recently observed for the transport of oil films under such substrate excitation, in particular, Rayleigh surface acoustic waves. In contrast to low-frequency (Hz- to kHz-order) vibration-induced wetting phenomena, film spreading at such high frequencies arises from convective drift generated by the viscous periodic flow localized in a region characterized by the viscous penetration depth β-1≡(2μ /ρ ω ) 1 /2 adjacent to the substrate that is invoked directly by its vibration; μ and ρ are the viscosity and the density of the liquid, respectively, and ω is the excitation frequency. This convective drift is responsible for driving the spreading of thin films of thickness h ≪kl-1 , which spread self-similarly as t1 /4 along the direction of the drift corresponding to the propagation direction of the surface wave, kl being the wave number of the compressional acoustic wave that forms in the liquid due to leakage of the surface wave energy from the substrate into the liquid and t the time. Films of greater thicknesses h ˜kl-1≫β-1 , in contrast, are observed to spread with constant velocity but in a direction that opposes the drift and surface wave propagation due to the attenuation of the acoustic wave in the liquid. The universal equation derived allows for the collective prediction of the spreading of these thin and thick films in opposing directions.

  14. Dynamics of liquid films exposed to high-frequency surface vibration.

    PubMed

    Manor, Ofer; Rezk, Amgad R; Friend, James R; Yeo, Leslie Y

    2015-05-01

    We derive a generalized equation that governs the spreading of liquid films under high-frequency (MHz-order) substrate vibration in the form of propagating surface waves and show that this single relationship is universally sufficient to collectively describe the rich and diverse dynamic phenomena recently observed for the transport of oil films under such substrate excitation, in particular, Rayleigh surface acoustic waves. In contrast to low-frequency (Hz- to kHz-order) vibration-induced wetting phenomena, film spreading at such high frequencies arises from convective drift generated by the viscous periodic flow localized in a region characterized by the viscous penetration depth β(-1)≡(2μ/ρω)(1/2) adjacent to the substrate that is invoked directly by its vibration; μ and ρ are the viscosity and the density of the liquid, respectively, and ω is the excitation frequency. This convective drift is responsible for driving the spreading of thin films of thickness h≪k(l)(-1), which spread self-similarly as t(1/4) along the direction of the drift corresponding to the propagation direction of the surface wave, k(l) being the wave number of the compressional acoustic wave that forms in the liquid due to leakage of the surface wave energy from the substrate into the liquid and t the time. Films of greater thicknesses h∼k(l)(-1)≫β(-1), in contrast, are observed to spread with constant velocity but in a direction that opposes the drift and surface wave propagation due to the attenuation of the acoustic wave in the liquid. The universal equation derived allows for the collective prediction of the spreading of these thin and thick films in opposing directions. PMID:26066257

  15. Frequency-resolved optical gating technique for retrieving the amplitude of a vibrational wavepacket

    NASA Astrophysics Data System (ADS)

    Nabekawa, Yasuo; Furukawa, Yusuke; Okino, Tomoya; Amani Eilanlou, A.; Takahashi, Eiji J.; Yamanouchi, Kaoru; Midorikawa, Katsumi

    2015-06-01

    We propose a novel method to determine the complex amplitude of each eigenfunction composing a vibrational wavepacket of / molecular ions evolving with a ~10 fs time scale. We find that the two-dimensional spectrogram of the kinetic energy release (KER) of H+/D+ fragments plotted against the time delay of the probe pulse is equivalent to the spectrogram used in the frequency-resolved optical gating (FROG) technique to retrieve the complex amplitude of an ultrashort optical pulse. By adapting the FROG algorithm to the delay-KER spectrogram of the vibrational wavepacket, we have successfully reconstructed the complex amplitude. The deterioration in retrieval accuracy caused by the bandpass filter required to process actual experimental data is also discussed.

  16. Frequency-resolved optical gating technique for retrieving the amplitude of a vibrational wavepacket

    PubMed Central

    Nabekawa, Yasuo; Furukawa, Yusuke; Okino, Tomoya; Amani Eilanlou, A.; Takahashi, Eiji J.; Yamanouchi, Kaoru; Midorikawa, Katsumi

    2015-01-01

    We propose a novel method to determine the complex amplitude of each eigenfunction composing a vibrational wavepacket of / molecular ions evolving with a ~10 fs time scale. We find that the two-dimensional spectrogram of the kinetic energy release (KER) of H+/D+ fragments plotted against the time delay of the probe pulse is equivalent to the spectrogram used in the frequency-resolved optical gating (FROG) technique to retrieve the complex amplitude of an ultrashort optical pulse. By adapting the FROG algorithm to the delay-KER spectrogram of the vibrational wavepacket, we have successfully reconstructed the complex amplitude. The deterioration in retrieval accuracy caused by the bandpass filter required to process actual experimental data is also discussed. PMID:26068640

  17. An approach based on tool mode control for surface roughness reduction in high-frequency vibration cutting

    NASA Astrophysics Data System (ADS)

    Ostasevicius, V.; Gaidys, R.; Rimkeviciene, J.; Dauksevicius, R.

    2010-11-01

    The presented research work, aimed at deeper understanding of vibrational process during high-frequency vibration cutting, is accomplished by treating cutting tool as an elastic structure which is characterized by several modes of natural vibrations. An approach for surface quality improvement is proposed in this paper by taking into account that quality of machined surface is related to the intensity of tool-tip (cutting edge) vibrations. It is based on the excitation of a particular higher vibration mode of a turning tool, which leads to the reduction of deleterious vibrations in the machine-tool-workpiece system through intensification of internal energy dissipation in the tool material. The combined application of numerical analysis with accurate finite element model as well as different experimental methods during investigation of the vibration turning process allowed to determine that the most favorable is the second flexural vibration mode of the tool in the direction of vertical cutting force component. This mode is excited by means of piezoelectric transducer vibrating in axial tool direction at the corresponding natural frequency, thereby enabling minimization of surface roughness and tool wear.

  18. Investigations of the Low Frequency Modes of Ferric Cytochrome c Using Vibrational Coherence Spectroscopy

    PubMed Central

    2015-01-01

    Femtosecond vibrational coherence spectroscopy is used to investigate the low frequency vibrational dynamics of the electron transfer heme protein, cytochrome c (cyt c). The vibrational coherence spectra of ferric cyt c have been measured as a function of excitation wavelength within the Soret band. Vibrational coherence spectra obtained with excitation between 412 and 421 nm display a strong mode at ∼44 cm–1 that has been assigned to have a significant contribution from heme ruffling motion in the electronic ground state. This assignment is based partially on the presence of a large heme ruffling distortion in the normal coordinate structural decomposition (NSD) analysis of the X-ray crystal structures. When the excitation wavelength is moved into the ∼421–435 nm region, the transient absorption increases along with the relative intensity of two modes near ∼55 and 30 cm–1. The intensity of the mode near 44 cm–1 appears to minimize in this region and then recover (but with an opposite phase compared to the blue excitation) when the laser is tuned to 443 nm. These observations are consistent with the superposition of both ground and excited state coherence in the 421–435 nm region due to the excitation of a weak porphyrin-to-iron charge transfer (CT) state, which has a lifetime long enough to observe vibrational coherence. The mode near 55 cm–1 is suggested to arise from ruffling in a transient CT state that has a less ruffled heme due to its iron d6 configuration. PMID:24823442

  19. Low-Magnitude, High-Frequency Vibration Fails to Accelerate Ligament Healing but Stimulates Collagen Synthesis in the Achilles Tendon

    PubMed Central

    Thompson, William R.; Keller, Benjamin V.; Davis, Matthew L.; Dahners, Laurence E.; Weinhold, Paul S.

    2015-01-01

    Background: Low-magnitude, high-frequency vibration accelerates fracture and wound healing and prevents disuse atrophy in musculoskeletal tissues. Purpose: To investigate the role of low-magnitude, high-frequency vibration as a treatment to accelerate healing of an acute ligament injury and to examine gene expression in the intact Achilles tendon of the injured limb after low-magnitude, high-frequency vibration. Study Design: Controlled laboratory study. Methods: Complete surgical transection of the medial collateral ligament (MCL) was performed in 32 Sprague-Dawley rats, divided into control and low-magnitude, high-frequency vibration groups. Low-magnitude, high-frequency vibration started on postoperative day 2, and rats received vibration for 30 minutes a day for 12 days. All rats were sacrificed 2 weeks after the operation, and their intact and injured MCLs were biomechanically tested or used for histological analysis. Intact Achilles tendons from the injured limb were evaluated for differences in gene expression. Results: Mechanical testing revealed no differences in the ultimate tensile load or the structural stiffness between the control and vibration groups for either the injured or intact MCL. Vibration exposure increased gene expression of collagen 1 alpha (3-fold), interleukin 6 (7-fold), cyclooxygenase 2 (5-fold), and bone morphogenetic protein 12 (4-fold) in the intact Achilles tendon when compared with control tendons (P < .05). Conclusion: While no differences were observed in the mechanical or histological properties of the fully transected MCL after low-magnitude, high-frequency vibration treatment, significant enhancements in gene expression were observed in the intact Achilles tendon. These included collagen, several inflammatory cytokines, and growth factors critical for tendons. Clinical Relevance: As low-magnitude, high-frequency vibration had no negative effects on ligament healing, vibration therapy may be a useful tool to accelerate healing

  20. Effect of High Frequency, Low Magnitude Vibration on Bone and Muscle in Children with Cerebral Palsy

    PubMed Central

    Wren, Tishya A. L.; Lee, David C.; Hara, Reiko; Rethlefsen, Susan A.; Kay, Robert M.; Dorey, Frederick J.; Gilsanz, Vicente

    2010-01-01

    BACKGROUND Children with cerebral palsy (CP) have decreased strength, low bone mass, and an increased propensity to fracture. High frequency, low magnitude vibration might provide a non-invasive, non-pharmacological, home-based treatment for these musculoskeletal deficits. The purpose of this study was to examine the effects of this intervention on bone and muscle in children with CP. METHODS Thirty-one children with CP ages 6-12 years (mean 9.4, SD 1.4) stood on a vibrating platform (30 Hz, 0.3 g peak acceleration) at home for 10 min/day for 6 months and on the floor without the platform for another 6 months. The order of vibration and standing was randomized, and outcomes were measured at 0, 6, and 12 months. The outcome measures included computed tomography measurements of vertebral cancellous bone density (CBD) and cross-sectional area, CBD of the proximal tibia, geometric properties of the tibial diaphysis, and dynamometer measurements of plantarflexor strength. Outcomes were assessed using mixed model linear regression and Pearson's correlation. RESULTS The main difference between vibration and standing was greater increases in the cortical bone properties (cortical bone area and moments of inertia) during the vibration period (all p's ≤ 0.03). There was no difference in cancellous bone or muscle between vibration and standing (all p's > 0.10) and no correlation between compliance and outcome (all r's < 0.27; all p's > 0.15). The results did not depend on the order of treatment (p > 0.43) and was similar for children in GMFCS 1-2 and GMFCS 3-4. CONCLUSIONS The primary benefit of the vibration intervention in children with CP was to cortical bone in the appendicular skeleton. Increased cortical bone area and structural (strength) properties could translate into a decreased risk of long bone fractures for some patients. More research is needed to corroborate these findings, to elucidate the mechanisms of the intervention, and to determine the most effective

  1. Time-domain filtered-x-Newton narrowband algorithms for active isolation of frequency-fluctuating vibration

    NASA Astrophysics Data System (ADS)

    Li, Yan; He, Lin; Shuai, Chang-geng; Wang, Fei

    2016-04-01

    A time-domain filtered-x Newton narrowband algorithm (the Fx-Newton algorithm) is proposed to address three major problems in active isolation of machinery vibration: multiple narrowband components, MIMO coupling, and amplitude and frequency fluctuations. In this algorithm, narrowband components are extracted by narrowband-pass filters (NBPF) and independently controlled by multi-controllers, and fast convergence of the control algorithm is achieved by inverse secondary-path filtering of the extracted sinusoidal reference signal and its orthogonal component using L×L numbers of 2nd-order filters in the time domain. Controller adapting and control signal generation are also implemented in the time domain, to ensure good real-time performance. The phase shift caused by narrowband filter is compensated online to improve the robustness of control system to frequency fluctuations. A double-reference Fx-Newton algorithm is also proposed to control double sinusoids in the same frequency band, under the precondition of acquiring two independent reference signals. Experiments are conducted with an MIMO single-deck vibration isolation system on which a 200 kW ship diesel generator is mounted, and the algorithms are tested under the vibration alternately excited by the diesel generator and inertial shakers. The results of control over sinusoidal vibration excited by inertial shakers suggest that the Fx-Newton algorithm with NBPF have much faster convergence rate and better attenuation effect than the Fx-LMS algorithm. For swept, frequency-jumping, double, double frequency-swept and double frequency-jumping sinusoidal vibration, and multiple high-level harmonics in broadband vibration excited by the diesel generator, the proposed algorithms also demonstrate large vibration suppression at fast convergence rate, and good robustness to vibration with frequency fluctuations.

  2. Multiscale wireless sensor node for impedance-based SHM and low-frequency vibration data acquisition

    SciTech Connect

    Taylor, Stuart G; Farinholt, Kevin M; Park, Gyuhae; Farrar, Charles R; Todd, Michael D

    2009-01-01

    This paper presents recent developments in an extremely compact, wireless impedance sensor node (WID3, Wireless Impedance Device) at Los Alamos National Laboratory for use in impedance-based structural health monitoring (SHM), Sensor diagnostics and low-frequency vibrational data acquisition. The current generation WID3 is equipped with an Analog Devices AD5933 impedance chip that can resolve measurements up to 100 kHz, a frequency range ideal for many SHM applications. An integrated set of multiplexers allows the end user to monitor seven piezoelectric sensors from a single sensor node. The WID3 combines on-board processing using an Atmega1281 microcontroller, data storage using flash memory, wireless communications capabilities, and a series of internal and external triggering options into a single package to realize a truly comprehensive, self-contained wireless active-sensor node for SHM applications. Furthermore, we recently extended the capability of this device by implementing low-frequency analog to digital and digital and analog converters so that the same device can measure structural vibration data. The WID3 requires less than 70 mW of power to operate, and it can operate in various wireless network paradigms. The performance of this miniaturized and portable device is compared to our previous results and its broader capabilities are demonstrated.

  3. Relationship between low-frequency aircraft noise and annoyance due to rattle and vibration.

    PubMed

    Fidell, Sanford; Pearsons, Karl; Silvati, Laura; Sneddon, Matthew

    2002-04-01

    A near-replication of a study of the annoyance of rattle and vibration attributable to aircraft noise [Fidell et al., J. Acoust. Soc. Am. 106, 1408-1415 (1999)] was conducted in the vicinity of Minneapolis-St. Paul International Airport (MSP). The findings of the current study were similar to those reported earlier with respect to the types of objects cited as sources of rattle in homes, frequencies of notice of rattle, and the prevalence of annoyance due to aircraft noise-induced rattle. A reliably lower prevalence rate of annoyance (but not of complaints) with rattle and vibration was noted among respondents living in homes that had been treated to achieve a 5-dB improvement in A-weighted noise reduction than among respondents living in untreated homes. This difference is not due to any substantive increase in low-frequency noise reduction of acoustically treated homes, but may be associated with installation of nonrattling windows. Common interpretations of the prevalence of a consequential degree of annoyance attributable to low-frequency aircraft noise may be developed from the combined results of the present and prior studies. PMID:12002858

  4. The trans-HOCO radical: Quartic force fields, vibrational frequencies, and spectroscopic constants

    NASA Astrophysics Data System (ADS)

    Fortenberry, Ryan C.; Huang, Xinchuan; Francisco, Joseph S.; Crawford, T. Daniel; Lee, Timothy J.

    2011-10-01

    In the search for a full mechanism creating CO2 from OH + CO, it has been suggested that creation of the hydroxyformyl or HOCO radical may be a necessary step. This reaction and its transient intermediate may also be responsible for the regeneration of CO2 in such high quantities in the atmosphere of Mars. Past spectroscopic observations of this radical have been limited and a full gas phase set of the fundamental vibrational frequencies of the HOCO radical has not been reported. Using established, highly accurate quantum chemical coupled cluster techniques and quartic force fields, we are able to compute all six fundamental vibrational frequencies and other spectroscopic constants for trans-HOCO in the gas phase. These methods have yielded rotational constants that are within 0.01 cm-1 for A0 and 10-4 cm-1 for B0 and C0 compared with experiment as well as fundamental vibrational frequencies within 4 cm-1 of the known gas phase experimental ν1 and ν2 modes. Such results lead us to conclude that our prediction of the other four fundamental modes of trans-HOCO are also quite reliable for comparison to future experimental observation, though the discrepancy for the torsional mode may be larger since it is fairly anharmonic. With the upcoming European Space Agency/NASA ExoMars Trace Gas Orbiter, these data may help to establish whether HOCO is present in the Martian sky and what role it may play in the retention of a CO2-rich atmosphere. Furthermore, these data may also help to clear up questions built around the fundamental chemical process of how exactly the OH + CO reaction progresses.

  5. The effect of classical and quantum dynamics on vibrational frequency shifts of H{sub 2} in clathrate hydrates

    SciTech Connect

    Plattner, Nuria; Meuwly, Markus

    2014-01-14

    Vibrational frequency shifts of H{sub 2} in clathrate hydrates are important to understand the properties and elucidate details of the clathrate structure. Experimental spectra of H{sub 2} in clathrate hydrates have been measured for different clathrate compositions, temperatures, and pressures. In order to establish reliable relationships between the clathrate structure, dynamics, and observed frequencies, calculations of vibrational frequency shifts in different clathrate environments are required. In this study, a combination of classical molecular dynamics simulations, electronic structure calculations, and quantum dynamical simulation is used to calculate relative vibrational frequencies of H{sub 2} in clathrate hydrates. This approach allows us to assess dynamical effects and simulate the change of vibrational frequencies with temperature and pressure. The frequency distributions of the H{sub 2} vibrations in the different clathrate cage types agree favorably with experiment. Also, the simulations demonstrate that H{sub 2} in the 5{sup 12} cage is more sensitive to the details of the environment and to quantum dynamical effects, in particular when the cage is doubly occupied. We show that for the 5{sup 12} cage quantum effects lead to frequency increases and double occupation is unlikely. This is different for the 5{sup 12}6{sup 4} cages for which higher occupation numbers than one H{sub 2} per cage are likely.

  6. Optimal design of thin walled I beams for extreme natural frequency of torsional vibrations

    NASA Astrophysics Data System (ADS)

    Szymczak, C.

    1983-01-01

    The optimal design of thin-walled I beams so as to extremize the natural frequency of torsional vibration is considered. It is assumed that only one dimension of the cross-section, except for the web height, may be variable in given limits, along the axis of the beam. The optimality condition for the variable dimension is settled by means of Pontryagin's maximum principle. The effect of the constant, axial loads is also included. the solution of the problem formulated is generally found in an iterative way. Some numerical examples of optimization of the I beam with variable widt of flanges are given.

  7. Computational procedures for evaluating the sensitivity derivatives of vibration frequencies and Eigenmodes of framed structures

    NASA Technical Reports Server (NTRS)

    Fetterman, Timothy L.; Noor, Ahmed K.

    1987-01-01

    Computational procedures are presented for evaluating the sensitivity derivatives of the vibration frequencies and eigenmodes of framed structures. Both a displacement and a mixed formulation are used. The two key elements of the computational procedure are: (a) Use of dynamic reduction techniques to substantially reduce the number of degrees of freedom; and (b) Application of iterative techniques to improve the accuracy of the derivatives of the eigenmodes. The two reduction techniques considered are the static condensation and a generalized dynamic reduction technique. Error norms are introduced to assess the accuracy of the eigenvalue and eigenvector derivatives obtained by the reduction techniques. The effectiveness of the methods presented is demonstrated by three numerical examples.

  8. Comparison of DFT with Traditional Methods for the Calculation of Vibrational Frequencies and Bond Energies

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W.; Arnold, James O. (Technical Monitor)

    1997-01-01

    The vibrational frequencies of MO2 are computed at many levels of theory, including HF, B3LYP, BP86, CASSCF, MP2, and CCSD(T). The computed results are compared with the available experimental results. Most of the methods fail for at least one state of the systems considered. The accuracy of the results and the origin of the observed failures are discussed. The B3LYP bond energies are compared with traditional methods for a variety of systems, ranging from FeCOn+ to SiCln and its positive ions. The cases where B3LYP differs from the traditional methods are discussed.

  9. A piezoelectric pulse generator for low frequency non-harmonic vibration

    NASA Astrophysics Data System (ADS)

    Jiang, Hao; Yeatman, Eric M.

    2013-12-01

    This paper reports a new piezoelectric prototype for pulse generation by energy harvesting from low frequency non-harmonic vibration. The pulse generator presented here consists of two parts: the electromechanical part and the load circuit. A metal rolling rod is used as the proof mass, moving along the substrate to achieve both actuating of the piezoelectric cantilever by magnetic coupling and self-synchronous switching of the circuit. By using this new approach, the energy from the piezoelectric transduction mechanism is regulated simultaneously when it is extracted. This allows a series of tuneable pulses to be generated, which can be applied to self-powered RF wireless sensor network (WSN) nodes.

  10. Vibrational frequencies of anti-diabetic drug studied by terahertz time-domain spectroscopy

    NASA Astrophysics Data System (ADS)

    Du, S. Q.; Li, H.; Xie, L.; Chen, L.; Peng, Y.; Zhu, Y. M.; Li, H.; Dong, P.; Wang, J. T.

    2012-04-01

    By using terahertz time-domain spectroscopy, the absorption spectra of seven anti-diabetic pills have been investigated. For gliquidone, glipizide, gliclazide, and glimepiride, an obvious resonance peak is found at 1.37 THz. Furthermore, to overcome the limit of density functional theory that can analyze the normal mode frequencies of the ground state of organic material, we also present a method that relies on pharmacophore recognition, from which we can obtain the resonance peak at 1.37 THz can be attributed to the vibration of sulfonylurea group. The results indicate that the veracity of density functional theory can be increased by combining pharmacophore recognition.

  11. Directional algorithms for the frequency isolation problem in undamped vibrational systems

    NASA Astrophysics Data System (ADS)

    Moro, Julio; Egaña, Juan C.

    2016-06-01

    A new algorithm is presented to solve the frequency isolation problem for vibrational systems with no damping: given an undamped mass-spring system with resonant eigenvalues, the system must be re-designed, finding some close-by non-resonant system at a reasonable cost. Our approach relies on modifying masses and stiffnesses along directions in parameter space which produce a maximal variation in the resonant eigenvalues, provided the non-resonant ones do not undergo large variations. The algorithm is derived from first principles, implemented, and numerically tested. The numerical experiments show that the new algorithms are considerably faster and more robust than previous algorithms solving the same problem.

  12. Accurate vibrational frequencies using the self-consistent-charge density-functional tight-binding method

    NASA Astrophysics Data System (ADS)

    Małolepsza, Edyta; Witek, Henryk A.; Morokuma, Keiji

    2005-09-01

    An optimization technique for enhancing the quality of repulsive two-body potentials of the self-consistent-charge density-functional tight-binding (SCC-DFTB) method is presented and tested. The new, optimized potentials allow for significant improvement of calculated harmonic vibrational frequencies. Mean absolute deviation from experiment computed for a group of 14 hydrocarbons is reduced from 59.0 to 33.2 cm -1 and maximal absolute deviation, from 436.2 to 140.4 cm -1. A drawback of the new family of potentials is a lower quality of reproduced geometrical and energetic parameters.

  13. First-Principles Framework to Compute Sum-Frequency Generation Vibrational Spectra of Semiconductors and Insulators

    NASA Astrophysics Data System (ADS)

    Wan, Quan; Galli, Giulia

    2015-12-01

    We present a first-principles framework to compute sum-frequency generation (SFG) vibrational spectra of semiconductors and insulators. The method is based on density functional theory and the use of maximally localized Wannier functions to compute the response to electric fields, and it includes the effect of electric field gradients at surfaces. In addition, it includes quadrupole contributions to SFG spectra, thus enabling the verification of the dipole approximation, whose validity determines the surface specificity of SFG spectroscopy. We compute the SFG spectra of ice Ih basal surfaces and identify which spectra components are affected by bulk contributions. Our results are in good agreement with experiments at low temperature.

  14. DFT Ab initio Calculation of Vibrational Frequencies in AsSe glass

    NASA Astrophysics Data System (ADS)

    Shrivastava, Keshav; Kassim, Hasan; Nazrul Rosli, Ahmad

    2008-03-01

    By using DFT double zeta wave functions, we calculated the structure, bond length (picometer, pm), frequencies(intensities)[degeneracy] for various clusters of arsenic selenide. Our results are as follows. (i) AsSe(diatomic) bond length 216pm, 244.0(1/cm). (ii) As2Se(linear) bond length 228.5 pm, frequencies 27.6(1.9) and 387.6(4.3). (iii) As2Se(triangular) As-Se 243.4 pm, As-As 223.3 pm, frequencies 237.3(2.4) and 332.4(0.05)(1/cm). (iv) As3Se (triangular) bond length 238.4 pm, frequencies 107.5 and 296(weak)(1/cm). (v) As4Se (square) bond length 250.2 pm, 58.5(0.04), 241.3(5.9)(1/cm). (vi) AsSe3 (triangular), bond length 231.2 pm, 75.9(0.003), 103.5(1.26)[2], 350.9(33.2)[2]. From this study we identify that linear As-Se-As for which the calculated frequency is 27.6(1/cm) is in agreement with the data of Nemanich, Phys. Rev. B 16, 1655(1977), J. C. Phillips et al Phys. Rev B 21, 5724(1980). We have successfully calculated several vibrational frequencies accurately which agree with the Raman data. *V. R. Devi et al J. Non-Cryst. Solids 351, 489(2005);353,111(2007)

  15. Non-Seismology Seismology: Using QuakeCatchers to Analyze the Frequency of Bridge Vibrations

    NASA Astrophysics Data System (ADS)

    Courtier, A. M.; Constantin, C.; Wilson, C. F.

    2013-12-01

    We conducted an experiment to test the feasibility of measuring seismic waves generated by traffic near James Madison University. We used QuakeCatcher seismometers (originally designed for passive seismic measurement) to measure vibrations associated with traffic on a wooden bridge as well as a nearby concrete bridge. This experiment was a signal processing exercise for a student research project and did not draw any conclusions regarding bridge safety or security. The experiment consisted of two temporary measurement stations comprised of a laptop computer and a QuakeCatcher - a small seismometer that plugs directly into the laptop via a USB cable. The QuakeCatcher was taped to the ground at the edge of the bridge to achieve good coupling, and vibrational events were triggered repeatedly with a control vehicle to accumulate a consistent dataset of the bridge response. For the wooden bridge, the resulting 'seismograms' were converted to Seismic Analysis Code (SAC) format and analyzed in MATLAB. The concrete bridge did not generate vibrations significant enough to trigger the recording mechanism on the QuakeCatchers. We will present an overview of the experimental design and frequency content of the traffic patterns, as well as a discussion of the instructional benefits of using the QuakeCatcher sensors in this non-traditional setting.

  16. Low-frequency and wideband vibration energy harvester with flexible frame and interdigital structure

    SciTech Connect

    Li, Pengwei Wang, Yanfen; Luo, Cuixian; Li, Gang; Hu, Jie; Zhang, Wendong; Liu, Ying; Liu, Wei

    2015-04-15

    As an alternative to traditional cantilever beam structures and their evolutions, a flexible beam based, interdigital structure, vibration energy harvester has been presented and investigated. The proposed interdigital-shaped oscillator consists of a rectangular flexible frame and series of cantilever beams interdigitally bonded to it. In order to achieve low frequency and wide-bandwidth harvesting, Young’s modulus of materials, frame size and the amount of the cantilevers have been studied systematically. The measured frequency responses of the designed device (PDMS frame, quintuple piezoelectric cantilever beams) show a 460% increase in bandwidth below 80Hz. When excited at an acceleration of 1.0 g, the energy harvester achieves to a maximum open-circuit voltage of 65V, and the maximum output power 4.5 mW.

  17. High-performance, vibration-immune, fiber-laser frequency comb.

    PubMed

    Baumann, Esther; Giorgetta, Fabrizio R; Nicholson, Jeffrey W; Swann, William C; Coddington, Ian; Newbury, Nathan R

    2009-03-01

    We demonstrate an environmentally robust optical frequency comb based on a polarization-maintaining, all-fiber, figure-eight laser. The comb is phase locked to a cavity-stabilized cw laser by use of an intracavity electro-optic phase modulator yielding 1.6 MHz feedback bandwidth. This high bandwidth provides close to shot-noise-limited residual phase noise between the comb and cw reference laser of -94 dBc/Hz from 20 Hz to 200 kHz and an integrated in-loop phase noise of 32 mrad from 1 Hz to 1 MHz. Moreover, the comb remains phase locked under significant mechanical vibrations of over 1 g. This level of environmental robustness is an important step toward a fieldable fiber frequency comb. PMID:19252577

  18. A vibrating reed apparatus to measure the natural frequency of multilayered thin films

    NASA Astrophysics Data System (ADS)

    Gamboa, F.; López, A.; Avilés, F.; Corona, J. E.; Oliva, A. I.

    2016-04-01

    An apparatus for measuring the natural frequency of sub-micrometric layered films in cantilever beam configuration is presented. The instrument comprises a specially designed test rig with a sample holder, an electronic excitation source, a vibration sensor and an automated software for the excitation and data recollection. The beam is excited by means of an air pulse and the oscillation amplitude of its free end is measured through a laser diode-photosensor arrangement. The instrument provides a very low uncertainty (˜1 mHz, for frequencies of the order of tens Hz) for repeated sequential tests and the major source of uncertainty (˜0.2 Hz, corresponding to a coefficient of variation of 0.18%) arises from the difficulty of placing the sample in an exactly identical location upon clamping. This high sensitivity renders the capability of measuring very small frequency shifts upon deposition of sub-micrometric films over thicker substrates. In order to assess the reliability of the apparatus, cantilever beams of 125 μm thick neat Kapton (substrate) and thin layered films of Au/Kapton and Al/Au/Kapton of 200-250 nm film thickness were fabricated and their natural frequency and damping factor were measured. Calculations of the natural frequency of such beams by finite element analysis further support the accuracy of the experimental measurements.

  19. Energy harvesting of radio frequency and vibration energy to enable wireless sensor monitoring of civil infrastructure

    NASA Astrophysics Data System (ADS)

    Galchev, Tzeno; McCullagh, James; Peterson, Rebecca L.; Najafi, Khalil; Mortazawi, Amir

    2011-04-01

    To power distributed wireless sensor networks on bridges, traditional power cables or battery replacement are excessively expensive or infeasible. This project develops two power harvesting technologies. First, a novel parametric frequency-increased generator (PFIG) is developed. The fabricated PFIG harvests the non-periodic and unprecedentedly low frequency (DC to 30 Hz) and low acceleration (0.55-9.8 m/s2) mechanical energy available on bridges with an average power > 2 μW. Prototype power conversion and storage electronics were designed and the harvester system was used to charge a capacitor from arbitrary bridge-like vibrations. Second, an RF scavenger operating at medium and shortwave frequencies has been designed and tested. Power scavenging at MHz frequencies allows for lower antenna directivities, reducing sensitivity to antenna positioning. Furthermore, ambient RF signals at these frequencies have higher power levels away from cities and residential areas compared to the UHF and SHF bands utilized for cellular communication systems. An RF power scavenger operating at 1 MHz along with power management and storage circuitry has been demonstrated. It powers a LED at a distance of 10 km from AM radio stations.

  20. Fast vibrational calculation of anharmonic OH-stretch frequencies for two low-energy noradrenaline conformers

    NASA Astrophysics Data System (ADS)

    Benoit, David M.

    2008-12-01

    We introduce a new reduced-coupling technique to accelerate direct calculations of a selected number of vibrational frequencies in large molecular systems. Our method combines the advantages of the single-to-all correlation-corrected vibrational self-consistent field (STA-CC-VSCF) approach [D. M. Benoit, J. Chem. Phys. 125, 244110 (2006)] with those of the fast-CC-VSCF technique [D. M. Benoit, J. Chem. Phys. 120, 562 (2004)] and allows the ab initio calculation of only the relevant parts of the required potential energy surface (PES). We demonstrate, using a set of five aliphatic alcohol molecules, that the new fast-STA-CC-VSCF method is accurate and leads to very substantial time gains for the computations of the PES. We then use the fast-STA-CC-VSCF method to accelerate the computation of the OH-stretch and NH-stretch frequencies of the two lowest-energy conformers of noradrenaline, namely, AG1a and GG1a. Our new approach enables us to run the calculation 89 times faster than the standard CC-VSCF technique and makes it possible to use a high-level MP2/TZP description of the PES. We demonstrate that the influence of the strong mode-mode couplings is crucial for a realistic description of the particular OH-stretch vibrational signature of each conformer. Finally, of the two possible low-energy conformers, we identify AG1a as the one most likely to have been observed in the experiments of Snoek et al. [Mol. Phys. 101, 1239 (2003)].

  1. A new aromatic probe - The ring stretching vibration Raman spectroscopy frequency.

    PubMed

    Guo, Yan-Bo; Liu, Zi-Zhong; Liu, Hong-Xia; Zhang, Feng-Ying; Yin, Jun-Qing

    2016-07-01

    A new aromatic criterion is presented to determine the aromatic degree of the high symmetric molecules. Group theory is used to explain the correlation between the aromatic degree and the value of Ring Stretching Vibration Raman Spectroscopic Frequency (RSVRSF). The calculations of the geometrical optimization, nucleus-independent chemical shifts (NICS) and values of the Raman Spectroscopy for the aromatic molecules-LnHn (L=C, Si, Ge, n=3, 5-8) were performed using the Density Functional Theory (DFT) Method, as well as the correlations between the values of their RSVRSF and NICS values by Statistic Package for Social Science (SPSS17.0). There are high positive correlations between the theoretical calculated the NICS values and the value of the RSVRSF (A1g/A1') of the LnHn (L=C, Si, Ge, n=3, 5-8). The bigger the aromatic degree, the bigger the RSVRSF is. The value of the RSVRSF is a new probe of aromaticity. Expectedly, it is predicted that the experimental determination of the aromatic degree can be achieved by the determination of the ring stretching vibration (A1g/A1') Raman spectrum frequencies for the aromatic target molecules. PMID:27085169

  2. A Simplified Sum-Frequency Vibrational Imaging Setup Used for Imaging Lipid Bilayer Arrays

    PubMed Central

    Smith, Kathryn A.; Conboy, John C.

    2012-01-01

    Given the complexity of cell membranes, there is a need for an analytical technique which can explore the physical properties of lipid membranes in a high-throughput and noninvasive manner. A simplified sum-frequency vibrational imaging (SFVI) setup has been developed and characterized using asymmetrically prepared 1,2-distearoyl-sn-glycero-3-phosphocholine (DSPC):1,2-distearoyl(d70)-sn-glycero-3-phosphocholine (DSPC-d70) lipid bilayer arrays. Exploiting the vibrational selectivity and inherent symmetry constraints of sum-frequency generation, SFVI was successfully used to probe the transition temperature of a patterned DSPC:DSPC-d70 lipid bilayer array. SFVI was also used to study the phase behavior in a multi-component micropatterned lipid bilayer array (MLBA) prepared using three different binary lipid mixtures (1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC):DSPC, DOPC:1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) and 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC:DSPC). This paper demonstrates that a simplified SFVI setup provides the necessary chemical imaging capabilities with the spatial resolution, sensitivity and field of view required for exploring lipid membrane properties in a high-throughput array based assay. PMID:22947074

  3. A simplified sum-frequency vibrational imaging setup used for imaging lipid bilayer arrays.

    PubMed

    Smith, Kathryn A; Conboy, John C

    2012-10-01

    Given the complexity of cell membranes, there is a need for an analytical technique which can explore the physical properties of lipid membranes in a high-throughput and noninvasive manner. A simplified sum-frequency vibrational imaging (SFVI) setup has been developed and characterized using asymmetrically prepared 1,2-distearoyl-sn-glycero-3-phosphocholine (DSPC):1,2-distearoyl(d70)-sn-glycero-3-phosphocholine (DSPC-d(70)) lipid bilayer arrays. Exploiting the vibrational selectivity and inherent symmetry constraints of sum-frequency generation, SFVI was successfully used to probe the transition temperature of a patterned DSPC:DSPC-d(70) lipid bilayer array. SFVI was also used to study the phase behavior in a multicomponent micropatterned lipid bilayer array (MLBA) prepared using three different binary lipid mixtures (1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC):DSPC, DOPC:1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC), and 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC:DSPC). This paper demonstrates that a simplified SFVI setup provides the necessary chemical imaging capabilities with the spatial resolution, sensitivity, and field of view required for exploring lipid membrane properties in a high-throughput array based assay. PMID:22947074

  4. A new aromatic probe - The ring stretching vibration Raman spectroscopy frequency

    NASA Astrophysics Data System (ADS)

    Guo, Yan-bo; Liu, Zi-zhong; Liu, Hong-xia; Zhang, Feng-ying; Yin, Jun-qing

    2016-07-01

    A new aromatic criterion is presented to determine the aromatic degree of the high symmetric molecules. Group theory is used to explain the correlation between the aromatic degree and the value of Ring Stretching Vibration Raman Spectroscopic Frequency (RSVRSF). The calculations of the geometrical optimization, nucleus-independent chemical shifts (NICS) and values of the Raman Spectroscopy for the aromatic molecules-LnHn (L = C, Si, Ge, n = 3, 5-8) were performed using the Density Functional Theory (DFT) Method, as well as the correlations between the values of their RSVRSF and NICS values by Statistic Package for Social Science (SPSS17.0). There are high positive correlations between the theoretical calculated the NICS values and the value of the RSVRSF (A1g/A1‧) of the LnHn (L = C, Si, Ge, n = 3, 5-8). The bigger the aromatic degree, the bigger the RSVRSF is. The value of the RSVRSF is a new probe of aromaticity. Expectedly, it is predicted that the experimental determination of the aromatic degree can be achieved by the determination of the ring stretching vibration (A1g/A1‧) Raman spectrum frequencies for the aromatic target molecules.

  5. Comparison of frequency-domain and time-domain rotorcraft vibration control methods

    NASA Technical Reports Server (NTRS)

    Gupta, N. K.

    1984-01-01

    Active control of rotor-induced vibration in rotorcraft has received significant attention recently. Two classes of techniques have been proposed. The more developed approach works with harmonic analysis of measured time histories and is called the frequency-domain approach. The more recent approach computes the control input directly using the measured time history data and is called the time-domain approach. The report summarizes the results of a theoretical investigation to compare the two approaches. Five specific areas were addressed: (1) techniques to derive models needed for control design (system identification methods), (2) robustness with respect to errors, (3) transient response, (4) susceptibility to noise, and (5) implementation difficulties. The system identification methods are more difficult for the time-domain models. The time-domain approach is more robust (e.g., has higher gain and phase margins) than the frequency-domain approach. It might thus be possible to avoid doing real-time system identification in the time-domain approach by storing models at a number of flight conditions. The most significant error source is the variation in open-loop vibrations caused by pilot inputs, maneuvers or gusts. The implementation requirements are similar except that the time-domain approach can be much simpler to implement if real-time system identification were not necessary.

  6. Spatial and Time Variability of Ambient Vibration H/V Frequency Peak

    NASA Astrophysics Data System (ADS)

    Benkaci, Nassima; Oubaiche, El-hadi; Chatelain, Jean-luc; Bensalem, Rabah; Abbes, Khadidja

    2016-04-01

    The ambient vibration H/V technique is widely used nowadays in microzonation studies, because of its easy field handling and its low cost, compared to other geophysical methods. However, in presence of complex geology or lateral heterogeneity evidenced by more than one peak frequency in the H/V curve, it is difficult to interpret the results, especially when soil information is lacking. In this work, we focus on the construction site of the Baraki 40000=place stadium, located in the north-east side of the Mitidja basin (Algeria), to identify the seismic wave amplification zones. H/V curve analysis leads to the observation of spatial and time variability of the H/V frequency peaks. The spatial variability allows dividing the studied area into three main zones: (1) one with a predominant frequency around 1,5 Hz showing an important amplification level, (2) the second exhibits two peaks at 1,5 Hz and in the 4 Hz - 10 Hz range, and (3) the third zone is characterized by a plateau between 2 Hz and 3 Hz. These H/V curve categories reveal a consequent lateral heterogeneity dividing the stadium site roughly in the middle. Furthermore, a continuous ambient vibration recording during several weeks allows showing that the first peak at 1,5Hz in the second zone, completely disappears between 2 am and 4 am, and reaching its maximum amplitude around 12 am. Consequently, the anthropogenic noise source generating these important variations could be the Algiers Rocade Sud highway, located in the maximum amplification azimuth direction of the H/V curves. This work points out that the H/V method is an important tool to perform nano-zonation studies prior to geotechnical and geophysical investigations, and that, in some cases, the H/V technique fails to reveal the resonance frequency in the absence of strong anthropogenic source.

  7. The dispersion correction and weak-hydrogen-bond network in low-frequency vibration of solid-state salicylic acid

    NASA Astrophysics Data System (ADS)

    Takahashi, Masae; Ishikawa, Yoichi; Ito, Hiromasa

    2012-04-01

    We perform the dispersion-corrected first-principles calculations of vibrational absorption and the far-infrared (terahertz) spectroscopic experiments at different temperature to examine the effect of weak-hydrogen-bond network on the low-frequency vibrations of solid-state salicylic acid. By dispersion correction, calculated frequencies improve especially in the intermonomer torsion and interdimer translational modes which are closely related to the weak hydrogen bonds. The calculated frequencies and their relative intensities reproduce the observed spectrum in the accuracy of 10 cm-1 or less. Weak-hydrogen-bond network causes a large frequency shift of out-of-plane intermonomer modes and enhances interdimer translational modes accompanied by the O⋯H stretching vibrations.

  8. Communication: Quantitative multi-site frequency maps for amide I vibrational spectroscopy

    NASA Astrophysics Data System (ADS)

    Reppert, Mike; Tokmakoff, Andrei

    2015-08-01

    An accurate method for predicting the amide I vibrational spectrum of a given protein structure has been sought for many years. Significant progress has been made recently by sampling structures from molecular dynamics simulations and mapping local electrostatic variables onto the frequencies of individual amide bonds. Agreement with experiment, however, has remained largely qualitative. Previously, we used dipeptide fragments and isotope-labeled constructs of the protein G mimic NuG2b as experimental standards for developing and testing amide I frequency maps. Here, we combine these datasets to test different frequency-map models and develop a novel method to produce an optimized four-site potential (4P) map based on the CHARMM27 force field. Together with a charge correction for glycine residues, the optimized map accurately describes both experimental datasets, with average frequency errors of 2-3 cm-1. This 4P map is shown to be convertible to a three-site field map which provides equivalent performance, highlighting the viability of both field- and potential-based maps for amide I spectral modeling. The use of multiple sampling points for local electrostatics is found to be essential for accurate map performance.

  9. Communication: Quantitative multi-site frequency maps for amide I vibrational spectroscopy.

    PubMed

    Reppert, Mike; Tokmakoff, Andrei

    2015-08-14

    An accurate method for predicting the amide I vibrational spectrum of a given protein structure has been sought for many years. Significant progress has been made recently by sampling structures from molecular dynamics simulations and mapping local electrostatic variables onto the frequencies of individual amide bonds. Agreement with experiment, however, has remained largely qualitative. Previously, we used dipeptide fragments and isotope-labeled constructs of the protein G mimic NuG2b as experimental standards for developing and testing amide I frequency maps. Here, we combine these datasets to test different frequency-map models and develop a novel method to produce an optimized four-site potential (4P) map based on the CHARMM27 force field. Together with a charge correction for glycine residues, the optimized map accurately describes both experimental datasets, with average frequency errors of 2-3 cm(-1). This 4P map is shown to be convertible to a three-site field map which provides equivalent performance, highlighting the viability of both field- and potential-based maps for amide I spectral modeling. The use of multiple sampling points for local electrostatics is found to be essential for accurate map performance. PMID:26277120

  10. Communication: Quantitative multi-site frequency maps for amide I vibrational spectroscopy

    SciTech Connect

    Reppert, Mike; Tokmakoff, Andrei

    2015-08-14

    An accurate method for predicting the amide I vibrational spectrum of a given protein structure has been sought for many years. Significant progress has been made recently by sampling structures from molecular dynamics simulations and mapping local electrostatic variables onto the frequencies of individual amide bonds. Agreement with experiment, however, has remained largely qualitative. Previously, we used dipeptide fragments and isotope-labeled constructs of the protein G mimic NuG2b as experimental standards for developing and testing amide I frequency maps. Here, we combine these datasets to test different frequency-map models and develop a novel method to produce an optimized four-site potential (4P) map based on the CHARMM27 force field. Together with a charge correction for glycine residues, the optimized map accurately describes both experimental datasets, with average frequency errors of 2–3 cm{sup −1}. This 4P map is shown to be convertible to a three-site field map which provides equivalent performance, highlighting the viability of both field- and potential-based maps for amide I spectral modeling. The use of multiple sampling points for local electrostatics is found to be essential for accurate map performance.