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Sample records for capacitively coupled binary

  1. Capacitively-coupled inductive sensor

    DOEpatents

    Ekdahl, Carl A.

    1984-01-01

    A capacitively coupled inductive shunt current sensor which utilizes capacitive coupling between flanges having an annular inductive channel formed therein. A voltage dividing capacitor is connected between the coupling capacitor and ground to provide immediate capacitive division of the output signal so as to provide a high frequency response of the current pulse to be detected. The present invention can be used in any desired outer conductor such as the outer conductor of a coaxial transmission line, the outer conductor of an electron beam transmission line, etc.

  2. Analysis of capacitive coupling within microelectrode array.

    PubMed

    Hu, Z; Troyk, P R; Detlefsen, D E

    2006-01-01

    Capacitive coupling within high-density microelectrode arrays can degrade neural recording signal or disperse neural stimulation current. Material deterioration in a chronically implanted neural stimulation/recording system can cause such an undesired effect. We present a simple method with an iterative algorithm to quantify the cross-coupling capacitance, in-situ. PMID:17947024

  3. Capacitance-coupled wiper increases potentiometer life

    NASA Technical Reports Server (NTRS)

    Dimeff, J.

    1968-01-01

    Capacitively-coupled wiper reduces the friction between the sliding contact and the potentiometer element in conventional potentiometers. A small preamplifier employed close to the wiper reduces errors caused by output cable capacitance. The device is friction free with resultant low wear and has high speed and high resolution.

  4. Kinetic simulations of magnetized capacitively coupled discharges

    NASA Astrophysics Data System (ADS)

    Trieschmann, Jan; Shihab, Mohammed; Eremin, Denis; Brinkmann, Ralf Peter; Schulze, Julian; Mussenbrock, Thomas

    2012-10-01

    Capacitive high frequency discharges are of crucial importance in the context of plasma etching, deposition and surface modification. As these single or multiple frequency discharges are oftentimes operated at low pressures of less than a few pascal, a high plasma density is commonly achieved with the use of external magnetic fields. In this work kinetic simulations are used to investigate the effect of inhomogeneous external magnetic fields on the discharge dynamics in a strongly nonlocal pressure regime. We found that capacitively coupled discharges can be largely asymmetrized by applying strong magnetic fields in front of a given target electrode. This not only has an effect on the plasma density, but also on the ion energy distribution functions (IEDF) at the electrodes and on the acceleration of fast electrons in the plasma sheath regions. In consequence in the discharge currents a generation of higher harmonics of the driving frequency can be observed. We investigate these scenarios in terms of 1D-3V Particle in Cell simulations.

  5. Electron heating in capacitively coupled plasmas revisited

    NASA Astrophysics Data System (ADS)

    Lafleur, T.; Chabert, P.; Booth, J. P.

    2014-06-01

    We revisit the problem of electron heating in capacitively coupled plasmas (CCPs), and propose a method for quantifying the level of collisionless and collisional heating in plasma simulations. The proposed procedure, based on the electron mechanical energy conservation equation, is demonstrated with particle-in-cell simulations of a number of single and multi-frequency CCPs operated in regimes of research and industrial interest. In almost all cases tested, the total electron heating is comprised of collisional (ohmic) and pressure heating parts. This latter collisionless component is in qualitative agreement with the mechanism of electron heating predicted from the recent re-evaluation of theoretical models. Finally, in very electrically asymmetric plasmas produced in multi-frequency discharges, we observe an additional collisionless heating mechanism associated with electron inertia.

  6. Rf capacitively-coupled electrodeless light source

    DOEpatents

    Manos, Dennis M.; Diggs, Jessie; Ametepe, Joseph D.; Fugitt, Jock A.

    2000-01-01

    An rf capacitively-coupled electrodeless light source is provided. The light source comprises a hollow, elongated chamber and at least one center conductor disposed within the hollow, elongated chamber. A portion of each center conductor extends beyond the hollow, elongated chamber. At least one gas capable of forming an electronically excited molecular state is contained within each center conductor. An electrical coupler is positioned concentric to the hollow, elongated chamber and the electrical coupler surrounds the portion of each center conductor that extends beyond the hollow, elongated chamber. A rf-power supply is positioned in an operable relationship to the electrical coupler and an impedance matching network is positioned in an operable relationship to the rf power supply and the electrical coupler.

  7. Instabilities in a capacitively coupled oxygen plasma

    SciTech Connect

    Küllig, C. Wegner, Th. Meichsner, J.

    2015-04-15

    Periodic fluctuations in the frequency range from 0.3 to 3 kHz were experimentally investigated in capacitively coupled radio frequency (13.56 MHz) oxygen plasma. The Gaussian beam microwave interferometry directly provides the line integrated electron density fluctuations. A system of two Langmuir probes measured the floating potential spatially (axial, radial) and temporally resolved. Hence, the floating potential fluctuation development is mapped within the discharge volume and provides a kind of discharge breathing and no wave propagation. Finally, it was measured the optical emission pattern of atomic oxygen during the fluctuation as well as the RF phase resolved optical emission intensity at selected phase position of the fluctuation by an intensified charge-coupled device camera. The deduced excitation rate pattern reveals the RF sheath dynamics and electron heating mechanisms, which is changing between low and high electronegativity during a fluctuation cycle. A perturbation calculation was taken into account using a global model with 15 elementary collision processes in the balance equations for the charged plasma species (O{sub 2}{sup +}, e, O{sup −}, O{sub 2}{sup −}) and a harmonic perturbation. The calculated frequencies agree with the experimentally observed frequencies. Whereby, the electron attachment/detachment processes are important for the generation of this instability.

  8. Instabilities in a capacitively coupled oxygen plasma

    NASA Astrophysics Data System (ADS)

    Küllig, C.; Wegner, Th.; Meichsner, J.

    2015-04-01

    Periodic fluctuations in the frequency range from 0.3 to 3 kHz were experimentally investigated in capacitively coupled radio frequency (13.56 MHz) oxygen plasma. The Gaussian beam microwave interferometry directly provides the line integrated electron density fluctuations. A system of two Langmuir probes measured the floating potential spatially (axial, radial) and temporally resolved. Hence, the floating potential fluctuation development is mapped within the discharge volume and provides a kind of discharge breathing and no wave propagation. Finally, it was measured the optical emission pattern of atomic oxygen during the fluctuation as well as the RF phase resolved optical emission intensity at selected phase position of the fluctuation by an intensified charge-coupled device camera. The deduced excitation rate pattern reveals the RF sheath dynamics and electron heating mechanisms, which is changing between low and high electronegativity during a fluctuation cycle. A perturbation calculation was taken into account using a global model with 15 elementary collision processes in the balance equations for the charged plasma species ( O2+, e , O-, O2- ) and a harmonic perturbation. The calculated frequencies agree with the experimentally observed frequencies. Whereby, the electron attachment/detachment processes are important for the generation of this instability.

  9. Tailored Voltage Waveform Capacitively-Coupled Plasmas

    NASA Astrophysics Data System (ADS)

    Booth, Jean-Paul; Lafleur, Trevor; Delattre, Pierre-Alexandre; Johnson, Erik

    2012-10-01

    A major limitation of large-area capacitively-coupled plasmas for materials processing is the inability to increase plasma density without increasing ion bombardment energy. Heil et al. (J. Phys. D 41. 165202, (2008)) demonstrated that for a driving voltage comprising one frequency, f, and it's harmonic 2f, the symmetry of the sheaths can be broken (the Electrical Asymmetry Effect, EAE). We have investigated large-area plasmas (50cm dia) in Ar driven by arbitrary voltage waveforms. Specifically we studied waveforms comprising sharp positive pulses (10-20ns wide, 15MHz repetition frequency). The voltage waveform was measured by an HV probe close to the powered electrode edge, the electron density was measured with a microwave hairpin resonator, the ion flux was measured by an array of planar ion flux probes in the grounded counter-electrode, and the power absorbed was determined from the current and voltage waveforms measured by a derivative probe. As well as the expected EAE observed in the electrode self-bias, we were able to demonstrate a dramatic increase in electron density (and concomitant increased power absorption) with reduced pulse-width at constant amplitude, in qualitative agreement with recent PIC simulations (Lafleur et al, APL 100, 194101(2012)).

  10. Design Considerations in Capacitively Coupled Plasmas

    NASA Astrophysics Data System (ADS)

    Song, Sang-Heon; Ventzek, Peter; Ranjan, Alok

    2015-11-01

    Microelectronics industry has driven transistor feature size scaling from 10-6 m to 10-9 m during the past 50 years, which is often referred to as Moore's law. It cannot be overstated that today's information technology would not have been so successful without plasma material processing. One of the major plasma sources for the microelectronics fabrication is capacitively coupled plasmas (CCPs). The CCP reactor has been intensively studied and developed for the deposition and etching of different films on the silicon wafer. As the feature size gets to around 10 nm, the requirement for the process uniformity is less than 1-2 nm across the wafer (300 mm). In order to achieve the desired uniformity, the hardware design should be as precise as possible before the fine tuning of process condition is applied to make it even better. In doing this procedure, the computer simulation can save a significant amount of resources such as time and money which are critical in the semiconductor business. In this presentation, we compare plasma properties using a 2-dimensional plasma hydrodynamics model for different kinds of design factors that can affect the plasma uniformity. The parameters studied in this presentation include chamber accessing port, pumping port, focus ring around wafer substrate, and the geometry of electrodes of CCP.

  11. Wavelet approach to artifact noise removal from Capacitive coupled Electrocardiograph.

    PubMed

    Lee, Seung Min; Kim, Ko Keun; Park, Kwang Suk

    2008-01-01

    Capacitive coupled Electrocardiography (ECG) is introduced as non-invasive measurement technology for ubiquitous health care and appliance are spread out widely. Although it has many merits, however, capacitive coupled ECG is very weak for motion artifacts for its non-skin-contact property. There are many studies for artifact problems which treats all artifact signals below 0.8Hz. In our capacitive coupled ECG measurement system, artifacts exist not only below 0.8Hz but also over than 10Hz. Therefore, artifact noise removal algorithm using wavelet method is tested to reject artifact-wandered signal from measured signals. It is observed that using power calculation each decimation step, artifact-wandered signal is removed as low frequency artifacts as high frequency artifacts. Although some original ECG signal is removed with artifact signal, we could level the signal quality for long term measure which shows the best quality ECG signals as we can get. PMID:19163323

  12. Conductive versus capacitive coupling for cell electroporation with nanosecond pulses

    NASA Astrophysics Data System (ADS)

    French, David M.; Uhler, Michael D.; Gilgenbach, Ronald M.; Lau, Y. Y.

    2009-10-01

    Experiments and simulations were performed to determine the difference between capacitive coupling and conductive connection for the electroporation of cells. The pulses used in the experiments have a peak voltage of 24 kV, 0.6 ns rise time, and 1.6 ns full width at half maximum. Experiments performed compare the conductive connection of the cell suspension versus a capacitively coupled cell suspension. The magnitude of the electric field was 16 kV/cm in both cases; however, the pulse shape is different. For the conductively connected case the cells located between the electrodes experienced an electric field in one direction only, whereas cells located between the electrodes in the capacitive coupling case were subject to an electric field that reverses direction. For the capacitively coupled case the bipolar pulse leads to no net cell charging. The conductive connection case is different, in that cells are left with a net polarization after the pulse is applied. Experimentally, only cells subject to the pulse with conductive connection demonstrated electroporation with the drug Bleomycin.

  13. Tunable capacitive coupling between two semiconductor charge qubits.

    PubMed

    Yu, Guo-Dong; Li, Hai-Ou; Cao, Gang; Xiao, Ming; Jiang, Hong-Wen; Guo, Guo-Ping

    2016-08-12

    Strong coupling between two qubits is one of the main requirements for high fidelity two-qubit logic operations. Here we experimentally investigate the capacitive coupling between two double quantum dots. A pair of open slot confinement gates is used to enhance the coupling. We find that the coupling energy J can be conveniently tuned in a broad range. Through numerical simulations, we study the effect of J on two-qubit operations. The analysis shows that our experimentally obtained J is adequate to achieve high fidelity two-qubit entanglement and logic gates. PMID:27354414

  14. Tunable capacitive coupling between two semiconductor charge qubits

    NASA Astrophysics Data System (ADS)

    Yu, Guo-Dong; Li, Hai-Ou; Cao, Gang; Xiao, Ming; Jiang, Hong-Wen; Guo, Guo-Ping

    2016-08-01

    Strong coupling between two qubits is one of the main requirements for high fidelity two-qubit logic operations. Here we experimentally investigate the capacitive coupling between two double quantum dots. A pair of open slot confinement gates is used to enhance the coupling. We find that the coupling energy J can be conveniently tuned in a broad range. Through numerical simulations, we study the effect of J on two-qubit operations. The analysis shows that our experimentally obtained J is adequate to achieve high fidelity two-qubit entanglement and logic gates.

  15. Investigation of capacitively coupled ultrasonic transducer system for nondestructive evaluation.

    PubMed

    Zhong, Cheng Huan; Wilcox, Paul D; Croxford, Anthony J

    2013-12-01

    Capacitive coupling offers a simple solution to wirelessly probe ultrasonic transducers. This paper investigates the theory, feasibility, and optimization of such a capacitively coupled transducer system (CCTS) in the context of nondestructive evaluation (NDE) applications. The noncontact interface relies on an electric field formed between four metal plates-two plates are physically connected to the electrodes of a transducer, the other two are in a separate probing unit connected to the transmit/receive channel of the instrumentation. The complete system is modeled as an electric network with the measured impedance of a bonded piezoelectric ceramic disc representing a transducer attached to an arbitrary solid substrate. A transmission line model is developed which is a function of the physical parameters of the capacitively coupled system, such as the permittivity of the material between the plates, the size of the metal plates, and their relative positions. This model provides immediate prediction of electric input impedance, pulse-echo response, and the effect of plate misalignment. The model has been validated experimentally and has enabled optimization of the various parameters. It is shown that placing a tuning inductor and series resistor on the transmitting side of the circuit can significantly improve the system performance in terms of the signal-to-crosstalk ratio. Practically, bulk-wave CCTSs have been built and demonstrated for underwater and through-composite testing. It has been found that electrical conduction in the media between the plates limits their applications. PMID:24297024

  16. Capacitive-coupled Series Spoof Surface Plasmon Polaritons

    NASA Astrophysics Data System (ADS)

    Yin, Jia Yuan; Ren, Jian; Zhang, Hao Chi; Zhang, Qian; Cui, Tie Jun

    2016-04-01

    A novel method to realize stopband within the operating frequency of spoof surface plasmon polaritons (SPPs) is presented. The stopband is introduced by a new kind of capacitive-coupled series spoof SPPs. Two conventional H-shaped unit cells are proposed to construct a new unit cell, and every two new unit cells are separated by a gap with certain distance, which is designed to implement capacitive coupling. The original surface impedance matching is disturbed by the capacitive coupling, leading to the stopband during the transmission of SPPs. The proposed method is verified by both numerical simulations and experiments, and the simulated and measured results have good agreements. It is shown that the proposed structure exhibits a stopband in 9–9.5 GHz while the band-pass feature maintains in 5–9 GHz and 9.5–11 GHz. In the passband, the reflection coefficient is less than ‑10 dB, and the transmission loss is around 3 dB in the stopband, the reflection coefficient is ‑2 dB, and the transmission coefficient is less than ‑30 dB. The compact size, easy fabrication and good band-pass and band-stop features make the proposed structure a promising plasmonic device in SPP communication systems.

  17. Capacitive-coupled Series Spoof Surface Plasmon Polaritons

    PubMed Central

    Yin, Jia Yuan; Ren, Jian; Zhang, Hao Chi; Zhang, Qian; Cui, Tie Jun

    2016-01-01

    A novel method to realize stopband within the operating frequency of spoof surface plasmon polaritons (SPPs) is presented. The stopband is introduced by a new kind of capacitive-coupled series spoof SPPs. Two conventional H-shaped unit cells are proposed to construct a new unit cell, and every two new unit cells are separated by a gap with certain distance, which is designed to implement capacitive coupling. The original surface impedance matching is disturbed by the capacitive coupling, leading to the stopband during the transmission of SPPs. The proposed method is verified by both numerical simulations and experiments, and the simulated and measured results have good agreements. It is shown that the proposed structure exhibits a stopband in 9–9.5 GHz while the band-pass feature maintains in 5–9 GHz and 9.5–11 GHz. In the passband, the reflection coefficient is less than −10 dB, and the transmission loss is around 3 dB; in the stopband, the reflection coefficient is −2 dB, and the transmission coefficient is less than −30 dB. The compact size, easy fabrication and good band-pass and band-stop features make the proposed structure a promising plasmonic device in SPP communication systems. PMID:27089949

  18. Capacitive-coupled Series Spoof Surface Plasmon Polaritons.

    PubMed

    Yin, Jia Yuan; Ren, Jian; Zhang, Hao Chi; Zhang, Qian; Cui, Tie Jun

    2016-01-01

    A novel method to realize stopband within the operating frequency of spoof surface plasmon polaritons (SPPs) is presented. The stopband is introduced by a new kind of capacitive-coupled series spoof SPPs. Two conventional H-shaped unit cells are proposed to construct a new unit cell, and every two new unit cells are separated by a gap with certain distance, which is designed to implement capacitive coupling. The original surface impedance matching is disturbed by the capacitive coupling, leading to the stopband during the transmission of SPPs. The proposed method is verified by both numerical simulations and experiments, and the simulated and measured results have good agreements. It is shown that the proposed structure exhibits a stopband in 9-9.5 GHz while the band-pass feature maintains in 5-9 GHz and 9.5-11 GHz. In the passband, the reflection coefficient is less than -10 dB, and the transmission loss is around 3 dB; in the stopband, the reflection coefficient is -2 dB, and the transmission coefficient is less than -30 dB. The compact size, easy fabrication and good band-pass and band-stop features make the proposed structure a promising plasmonic device in SPP communication systems. PMID:27089949

  19. Superposition of Inductive and Capacitive Coupling in Superconducting LC Resonators

    NASA Astrophysics Data System (ADS)

    Gladchenko, Sergiy; Khalil, Moe; Lobb, C. J.; Wellstood, F. C.; Osborn, Kevin D.

    2011-06-01

    We present an experimental investigation of lumped-element superconducting LC resonators designed to provide different types of coupling to a transmission line. We have designed four resonator geometries including dipole and quadrupole configured inductors connected in parallel with low loss SiNx dielectric parallel-plate capacitors. The design of the resonator allows a small change in the symmetry of the inductor or grounding of the capacitor to allow LC resonators with: 1) inductive coupling, 2) capacitive coupling, 3) both types of coupling, or 4) greatly reduced coupling. We measured all four designs at a temperature of 30mK at different values of power. We compare the extracted data from the four resonator types and find that both capacitive and inductive coupling can be included and that when left off, only a minor change in the circuit design is necessary. We also find a variation in the measured loss tangent of less than a few percent, which is a test of the systematic precision of the measurement technique.

  20. Capacitively Coupled CMOS VCSEL Driver Circuits for Optical Communication

    NASA Astrophysics Data System (ADS)

    Kozlov, Victor

    This thesis presents the analysis, design and implementation of a common-cathode capacitively-coupled VCSEL driver in 65nm CMOS intended for short-reach optical interconnects. The driver consists of an AC-coupled high-frequency path and a low-frequency path that provides DC signal components. By increasing the low-frequency path bandwidth by 10 times compared to previous AC-coupled drivers allowed the on-chip coupling capacitor to be reduced to 2.1pF, occupying 3 times less area than prior art. The driver introduces capacitively-coupled two-tap emphasis to equalize the VCSEL's optical response. The VCSEL was modulated with an OMA of up to 5.1dBm and an ER of 9dB, measuring an RMS jitter of 5ps at a data rate of 15Gb/s, which represents the highest OMA and ER achieved in high-speed anode-driving LDDs. The driver could be programmed for a low-power mode, outputting 2.3dBm OMA at power consumption of only 30mW, corresponding to an energy efficiency of 2pJ/bit.

  1. Correlated Coulomb Drag in Capacitively Coupled Quantum-Dot Structures.

    PubMed

    Kaasbjerg, Kristen; Jauho, Antti-Pekka

    2016-05-13

    We study theoretically Coulomb drag in capacitively coupled quantum dots (CQDs)-a bias-driven dot coupled to an unbiased dot where transport is due to Coulomb mediated energy transfer drag. To this end, we introduce a master-equation approach that accounts for higher-order tunneling (cotunneling) processes as well as energy-dependent lead couplings, and identify a mesoscopic Coulomb drag mechanism driven by nonlocal multielectron cotunneling processes. Our theory establishes the conditions for a nonzero drag as well as the direction of the drag current in terms of microscopic system parameters. Interestingly, the direction of the drag current is not determined by the drive current, but by an interplay between the energy-dependent lead couplings. Studying the drag mechanism in a graphene-based CQD heterostructure, we show that the predictions of our theory are consistent with recent experiments on Coulomb drag in CQD systems. PMID:27232031

  2. Correlated Coulomb Drag in Capacitively Coupled Quantum-Dot Structures

    NASA Astrophysics Data System (ADS)

    Kaasbjerg, Kristen; Jauho, Antti-Pekka

    2016-05-01

    We study theoretically Coulomb drag in capacitively coupled quantum dots (CQDs)—a bias-driven dot coupled to an unbiased dot where transport is due to Coulomb mediated energy transfer drag. To this end, we introduce a master-equation approach that accounts for higher-order tunneling (cotunneling) processes as well as energy-dependent lead couplings, and identify a mesoscopic Coulomb drag mechanism driven by nonlocal multielectron cotunneling processes. Our theory establishes the conditions for a nonzero drag as well as the direction of the drag current in terms of microscopic system parameters. Interestingly, the direction of the drag current is not determined by the drive current, but by an interplay between the energy-dependent lead couplings. Studying the drag mechanism in a graphene-based CQD heterostructure, we show that the predictions of our theory are consistent with recent experiments on Coulomb drag in CQD systems.

  3. Pressure effects in multiphase binary diffusion couples

    NASA Astrophysics Data System (ADS)

    Subramanyam, Dilip; Notis, Michael R.; Goldstein, Joseph I.

    1985-04-01

    A systematic study has been carried out of the effect of pressure upon growth kinetics of intermediate phases formed in diffusion couples in the binary systems Ni-Al, U-A1, and U-Cu. Even though applied pressures greater than 100 MPa and long times were investigated little or no pressure effect was observed, in disagreement with previous literature reports. The magnitude of observed pressure effects falls within that expected by closure of Kirkendall porosity.

  4. Detection of Electrocardiogram by Electrodes with Fabrics Using Capacitive Coupling

    NASA Astrophysics Data System (ADS)

    Ueno, Akinori; Furusawa, Yoichi; Hoshino, Hiroshi; Ishiyama, Yoji

    This article reports on a novel technique for detecting electrocardiogram (ECG) at a condition where thin cloth is interpolated between sensing electrodes and the skin to which the electrodes are attached. The technique is based upon capacitive coupling composed of the electrode, the cloth and the skin, so that the electrode can lead alternating electrocardiographic current through capacitance of the coupling. The technique is also founded on impedance transforming circuit that has extremely high input impedance around 1000GΩ and low output impedance, so as to match high output impedance of the electrode to low input impedance required by subsequent circuitry. A pilot ECG measuring device was manufactured using the technique and experiments showed (1) ECG recordings using the device with silk of 240μm thickness or with cotton of 564μm thickness were quite similar to ECGs recorded from the skin using conventional system, (2) stable ECGs were observed with the silk below 600μm thickness or with the cotton below 1128μm thickness, (3) effects of long-term measurement and perspiration on ECG waveform were negligible. These results prove feasibility of the proposed technique for detecting ECG by electrodes with fabrics.

  5. Spin-Spin Coupling in Asteroidal Binaries

    NASA Astrophysics Data System (ADS)

    Batygin, Konstantin; Morbidelli, Alessandro

    2015-11-01

    Gravitationally bound binaries constitute a substantial fraction of the small body population of the solar system, and characterization of their rotational states is instrumental to understanding their formation and dynamical evolution. Unlike planets, numerous small bodies can maintain a perpetual aspheroidal shape, giving rise to a richer array of non-trivial gravitational dynamics. In this work, we explore the rotational evolution of triaxial satellites that orbit permanently deformed central objects, with specific emphasis on quadrupole-quadrupole interactions. Our analysis shows that in addition to conventional spin-orbit resonances, both prograde and retrograde spin-spin resonances naturally arise for closely orbiting, highly deformed bodies. Application of our results to the illustrative examples of (87) Sylvia and (216) Kleopatra multi-asteroid systems implies capture probabilities slightly below ~10% for leading-order spin-spin resonances. Cumulatively, our results suggest that spin-spin coupling may be consequential for highly elongated, tightly orbiting binary objects.

  6. Threshold resistive and capacitive switching behavior in binary amorphous GeSe

    NASA Astrophysics Data System (ADS)

    Jeong, Doo Seok; Lim, Hyungkwang; Park, Goon-Ho; Hwang, Cheol Seong; Lee, Suyoun; Cheong, Byung-ki

    2012-05-01

    A threshold switching (TS) event in a binary amorphous GeSe film placed between Pt top and bottom electrodes was examined. This GeSe film exhibits fast (<40 ns) TS behavior. The observed TS of the resistance was found to be accompanied with the TS of the capacitance. A mechanism for the TS of the GeSe film was suggested by revisiting the previous controversy about the thermal versus non-thermal electronic mechanism. The non-thermal electronic mechanism envisaging the double-injection of electronic carriers can qualitatively account for the measured threshold resistive and capacitive switching, whereas the TS behavior simulated using the thermal mechanism is inconsistent with the experimental observation.

  7. Improving the gate fidelity of capacitively coupled spin qubits

    NASA Astrophysics Data System (ADS)

    Wang, Xin; Barnes, Edwin

    2015-03-01

    Precise execution of quantum gates acting on two or multiple qubits is essential to quantum computation. For semiconductor spin qubits coupled via capacitive interaction, the best fidelity for a two-qubit gate demonstrated so far is around 70%, insufficient for fault-tolerant quantum computation. In this talk we present control protocols that may substantially improve the robustness of two-qubit gates against both nuclear noise and charge noise. Our pulse sequences incorporate simultaneous dynamical decoupling protocols and are simple enough for immediate experimental realization. Together with existing control protocols for single-qubit gates, our results constitute an important step toward scalable quantum computation using spin qubits. This work is done in collaboration with Sankar Das Sarma and supported by LPS-NSA-CMTC and IARPA-MQCO.

  8. Double input capacitively coupled contactless conductivity detector with phase shift.

    PubMed

    Zheng, Hao; Li, Meng; Dai, Jianyuan; Wang, Zhen; Li, Xiuting; Yuan, Hongyan; Xiao, Dan

    2014-10-21

    A double input capacitively coupled contactless conductivity detector (DIC(4)D) device which gets higher sensitivity has been described in this paper. The detector consists of two input electrodes and one output electrode. When two alternating current (AC) voltages with the same amplitude and different phases are imposed on each input electrode, the equivalent resistance of the output electrode is reduced because of the interference of the two signals with different phase angles. For a capacitively coupled contactless conductivity detector (C(4)D), the ratio of the response of KCl solution to that of distilled water is 1.6. However, for DIC(4)D, the ratio is 1.55 at a phase difference of 0° and increases to 1.8 at the phase difference of 170°, respectively. For C(4)D, the response of KCl solution is a linear function of the logarithm of concentrations from 10(-5) M to 10(-2) M, and the slope is 5.58. However, the slope of the response increases to 7.13 in DIC(4)D, and the limit of detection (LOD) of DIC(4)D is estimated to be 5 × 10(-8) M. The slope of the three-way DIC(4)D is increased to 69.78. A flow injection device is employed for the evaluation of the applicability of DIC(4)D with the same range, and good reproducibility is confirmed through flow injection of the same solution 10 times. The relative standard deviation (RSD) is 0.7%, which demonstrates a promising application to capillary electrophoresis (CE). PMID:25250534

  9. Capacitively Coupled Hot-Electron Nanobolometer with SIN Tunnel Junctions

    NASA Astrophysics Data System (ADS)

    Kuzmin, Leonid S.; Fominsky, M.; Kalabukhov, A.; Golubev, D.; Tarasov, M.

    2003-02-01

    A capacitively coupled hot-electron nanobolometer (CC-HEB) is the simplest and most effective antenna-coupled bolometer. The bolometer consists of a small absorber connected to the superconducting antenna by tunnel junctions. The tunnel junctions used for high-frequency coupling also give perfect thermal isolation of hot electrons in the small volume of the absorber. The same tunnel junctions are used for temperature measurements and electron cooling. This bolometer does not suffer from the frequency limitations in the submillimeter range due to the high potential barrier of the tunnel junctions as does the microbolometer with Andreev mirrors (A-HEB), which is limited by the superconducting gap. Theoretical analyses show that the two-junction configuration more than doubles the sensitivity of the bolometer in current-biased mode compared to the single-junction configuration used for A-HEB. Another important advantage of CC-HEB is its simple two-layer technology for sample fabrication. Samples were fabricated with an absorber made of a bilayer of Cr and Al to match the impedance of the antenna. Electrodes were made of Al and tunnel junctions were formed over the Al oxide layer. The coupling capacitances of the tunnel junctions, C ≍ 20 fF, in combination with the inductance of the 10 μm absorber create a bandpass filter with a central frequency around 300 GHz. Bolometers are integrated with log-periodic and double-dipole planar antennas made of Au. The temperature response of bolometer structures was measured at temperatures down to 256 mK. In our experiment we observed dV/dT=1.3 mV/K, corresponding to responsivity S=0.2.109 V/W. For amplifier noise Vna=3nV/Hz1/2 at 1 kHz the estimated total noise equivalent power is NEP=1.5.10-17 W/Hz1/2. The intrinsic bolometer self noise Vnbol=0.5 nV/Hz1/2 corresponds to NEP=3.10-18 W/Hz1/2. For microwave evaluation of bolometer sensitivity we used a black body radiation source comprising a thin NiCr stimulator placed on the

  10. Tightly wrapped semiconductor-axon microtubes for probing hybrid networks: Modeling the capacitive coupling strength

    NASA Astrophysics Data System (ADS)

    Diedrich, Daniel; Blick, Robert H.

    2015-02-01

    We present finite-element simulations modeling the electromagnetic interaction between axons and semiconductor microtubes. These tubes are tightly wrapped around the axons, enabling highly efficient capacitive coupling. The calculations reveal that the capacitive coupling strength is in the pA regime.

  11. Capacitively coupled hybrid pixel assemblies for the CLIC vertex detector

    NASA Astrophysics Data System (ADS)

    Tehrani, N. Alipour; Arfaoui, S.; Benoit, M.; Dannheim, D.; Dette, K.; Hynds, D.; Kulis, S.; Perić, I.; Petrič, M.; Redford, S.; Sicking, E.; Valerio, P.

    2016-07-01

    The vertex detector at the proposed CLIC multi-TeV linear e+e- collider must have minimal material content and high spatial resolution, combined with accurate time-stamping to cope with the expected high rate of beam-induced backgrounds. One of the options being considered is the use of active sensors implemented in a commercial high-voltage CMOS process, capacitively coupled to hybrid pixel ASICs. A prototype of such an assembly, using two custom designed chips (CCPDv3 as active sensor glued to a CLICpix readout chip), has been characterised both in the lab and in beam tests at the CERN SPS using 120 GeV/c positively charged hadrons. Results of these characterisation studies are presented both for single and dual amplification stages in the active sensor, where efficiencies of greater than 99% have been achieved at -60 V substrate bias, with a single hit resolution of 6.1 μm . Pixel cross-coupling results are also presented, showing the sensitivity to placement precision and planarity of the glue layer.

  12. Kinetic Effects in Low Pressure Capacitively Coupled Plasmas

    NASA Astrophysics Data System (ADS)

    Likhanskii, Alexandre; Roark, Christine; Stoltz, Peter

    2011-10-01

    We present results of particle-in-cell/Monte Carlo collision simulations of kinetic effects in low pressure capacitively coupled plasma discharge. In particular, we examine discharges of various gases (including Ar, Xe, and others) in the pressure range of 10s of mT and the frequency range of 10s of MHz. We track the formation of high energy electrons (e.g., at the ionization threshold or greater) as a marker for enhanced ionization, and look at the effects of elastic and inelastic collisions on the formation of these high energy electron bunches. We show results for 2D and 3D simulations where we include density gradient effects, and results for plasma chemistry effects on the bulk electron energy distribution function and the ion energy distribution function at a plasma surface interface. We discuss the role of the bunches on electron heating in the plasma bulk and on their presence on how electron heating is treated in fluid simulations of plasma sources.

  13. Two modes of capacitively coupled rf discharge in CF4

    NASA Astrophysics Data System (ADS)

    Proshina, O. V.; Rakhimova, T. V.; Rakhimov, A. T.; Voloshin, D. G.

    2010-12-01

    Capacitively coupled rf discharge in pure CF4 was studied using a one-dimensional self-consistent particle-in-cell Monte Carlo model. Two different discharge modes are observed depending on the discharge conditions: the regime of electronegative plasma with high-electron temperatures in the bulk, and the regime of electropositive plasma with abnormally low electron temperatures in the bulk. The characteristic features of the two discharge modes are considered. A sharp transition from the former to the latter mode is observed with an increase in applied voltage. The dependence of the transition voltage on gas pressure is analyzed. In the studied range of gas pressures, the existence of a high-temperature mode in an electronegative gas like CF4 is suggested by the balance between the ionization rate and attachment rate in the bulk region. As a result, the transition voltage increases with gas pressure because of the increased relative role of electron attachment. It is shown that the differences in the used electron cross-section sets may noticeably affect the simulation results and the discharge properties. Three different electron cross-section sets for CF4 are considered. In particular, the transition voltage between the two discharge modes differs essentially for different cross-sections used. In order to analyze the fundamental causes of this difference, a detailed comparison of three cross-section sets was done on the basis of the Monte Carlo calculation of swarm parameters in constant electric fields.

  14. Macroscopic quantum tunneling in a stack of capacitively-coupled intrinsic Josephson junctions

    NASA Astrophysics Data System (ADS)

    Koyama, Tomio; Machida, Masahiko

    2008-04-01

    A macroscopic quantum theory for the phase dynamics in capacitively-coupled intrinsic Josephson junctions (IJJ's) is constructed. We quantize the capacitively-coupled IJJ model in terms of the canonical quantization method. The multi-junction effect for the macroscopic quantum tunneling (MQT) to the first resistive branch is clarified. It is shown that the escape rate is greatly enhanced by the capacitive coupling between junctions. We also discuss the origin of the N2 -enhancement in the escape rate observed in the uniformly switching in Bi-2212 IJJ's.

  15. Charge dynamics in capacitively coupled radio frequency discharges

    NASA Astrophysics Data System (ADS)

    Schulze, J.; Schüngel, E.; Donkó, Z.; Czarnetzki, U.

    2010-06-01

    In a capacitively coupled radio frequency (CCRF) discharge the number of positive and negative charges lost to each electrode must balance within one RF period to ensure a constant total uncompensated charge in the discharge, Qtot, on time average. This balance is the result of a compensation of electron and ion fluxes at each electrode within one RF period. Although Qtot is constant on temporal average, it is time dependent on time scales shorter than one RF period, since it results from a balance of the typically constant ion flux and the strongly time dependent electron flux at each electrode. Nevertheless, Qtot is assumed to be constant in various models. Here the dynamics of Qtot is investigated in a geometrically symmetric CCRF discharge operated in argon at 13.56 and 27.12 MHz with variable phase shift θ between the driving voltages by a PIC simulation and an analytical model. Via the electrical asymmetry effect (EAE) a variable dc self-bias is generated as a function of θ. It is found that Qtot is not temporally constant within the low frequency period, but fluctuates by about 10% around its time average value. This modulation is understood by an analytical model. It is demonstrated that this charge dynamics leads to a phase shift of the dc self-bias not captured by models neglecting the charge dynamics. This dynamics is not restricted to dual frequency discharges. It is a general phenomenon in all CCRF discharges and can generally be described by the model introduced here. Finally, Qtot is split into the uncompensated charges in each sheath. The sheath charge dynamics and the self-excitation of non-linear plasma series resonance oscillations of the RF current via the EAE at low pressures of a few pascals are discussed.

  16. Electron heating in capacitively coupled RF plasmas: a unified scenario

    NASA Astrophysics Data System (ADS)

    Brinkmann, Ralf Peter

    2016-02-01

    Electron heating in radio-frequency capacitively coupled plasmas (RF-CCP) is studied from first principles. The starting points are the electron equations of continuity and motion, with ionization neglected but electric and pressure forces and elastic collisions with the neutral background taken into account. Poisson’s equation self-consistently calculates the electric field; the ion density is assumed as a given. Postulating that the Debye length {λ\\text{D}} is small compared to the sheath length scale l and the applied frequency {ω\\text{RF}} is small compared to the electron plasma frequency {ω\\text{pe}} , an asymptotic expansion in the smallness parameter ε ={λ\\text{D}}/l∼ {ω\\text{RF}}/{ω\\text{pe}} is conducted. As has been demonstrated before (Brinkmann 2015 Plasma Sources Sci. Technol. 24 064002), this ansatz gives an expression—the smooth step model (SSM)—which yields (i) the space charge field in the unipolar region, (ii) the generalized Ohmic field in the ambipolar region, and (iii) a smooth interpolation for the rapid transition in between. Using the SSM and formulas for the electron density and the electron flux, expressions for the electric force and the electric power density are established which hold up to O≤ft(ε \\right) . Integrating over the sheath and taking the phase average, a representation for the total dissipated power is found as a sum of four physically distinct contributions. All terms correspond to electron heating mechanisms which are (explicitly or implicitly) already known but were so far discussed only within mutually incompatible frameworks.

  17. Macroscopic quantum effects in capacitively- and inductively-coupled intrinsic Josephson junctions

    NASA Astrophysics Data System (ADS)

    Koyama, T.; Machida, M.

    2009-03-01

    A theory for macroscopic quantum tunneling (MQT) in intrinsic Josephson junction stacks is formulated. Both capacitive and inductive couplings between junctions are taken into account. We calculate the escape rate in the switching to the first resistive branch in the quantum regime. It is shown that the enhancement of the escape rate is caused mainly by the capacitive coupling between junctions in IJJ's with small in-plane area of ~ 1μm2.

  18. Capacitively coupled RF voltage probe having optimized flux linkage

    DOEpatents

    Moore, James A.; Sparks, Dennis O.

    1999-02-02

    An RF sensor having a novel current sensing probe and a voltage sensing probe to measure voltage and current. The current sensor is disposed in a transmission line to link all of the flux generated by the flowing current in order to obtain an accurate measurement. The voltage sensor is a flat plate which operates as a capacitive plate to sense voltage on a center conductor of the transmission line, in which the measured voltage is obtained across a resistance leg of a R-C differentiator circuit formed by the characteristic impedance of a connecting transmission line and a capacitance of the plate, which is positioned proximal to the center conductor.

  19. Spin-orbit coupling in binary asteroids

    NASA Astrophysics Data System (ADS)

    Margot, Jean-Luc; Naidu, Shantanu P.

    2016-01-01

    We use radar images with decameter resolution to measure the sizes, shapes, spin states, mutual orbits, masses, and densities of components of asteroid binaries and triples. We simulate the spin-orbit dynamics of these systems and map the possible spin configurations of the satellites on surface of section plots. The presence of chaotic regions in the phase space has important consequences for the evolution of binary asteroids. It may substantially increase spin synchronization timescales, delay BYORP-type evolution, and extend the lifetime of binaries.

  20. Mapping Capacitive Coupling Among Pixels in a Sensor Array

    NASA Technical Reports Server (NTRS)

    Seshadri, Suresh; Cole, David M.; Smith, Roger M.

    2010-01-01

    An improved method of mapping the capacitive contribution to cross-talk among pixels in an imaging array of sensors (typically, an imaging photodetector array) has been devised for use in calibrating and/or characterizing such an array. The method involves a sequence of resets of subarrays of pixels to specified voltages and measurement of the voltage responses of neighboring non-reset pixels.

  1. Low Voltage Low Power Quadrature LC Oscillator Based on Back-gate Superharmonic Capacitive Coupling

    NASA Astrophysics Data System (ADS)

    Ma, Minglin; Li, Zhijun

    2013-09-01

    This work introduces a new low voltage low power superharmonic capacitive coupling quadrature LC oscillator (QLCO) made by coupling two identical cross-connected LC oscillators without tail transistor. In each of the core oscillators, the back-gate nodes of the cross-coupled NMOS pair and PMOS pair, acting as common mode nodes, have been connected directly. Then the core oscillators are coupled together via capacitive coupling of the PMOS common mode node in one of the core oscillators to the NMOS common mode node in the other core oscillator, and vice versa. Only capacitors are used for coupling of the two core oscillators and therefore no extra noise sources are imposed on the circuit. Operation of the proposed QLCO was investigated with simulation using a commercial 0.18 µm RF CMOS technology: it shows a power dissipation of 5.2 mW from a 0.6 V supply voltage. Since the proposed core oscillator has Complementary NMOS and PMOS cross coupled pairs, and capacitive coupling method will not introduce extra phase noise, so this circuit can operate with a low phase noise as low as -126.8 dBc/Hz at 1 MHz offset from center oscillation frequency of 2.4 GHz, as confirmed with simulation.

  2. Capacitively Coupled Radio Frequency Discharge Plasmas In Hydrogen: Particle Modeling and Negative Ion Kinetics

    SciTech Connect

    Diomede, P.; Longo, S.; Capitelli, M.

    2005-05-16

    We present a 1D(r)2D(v) particle code for capacitively coupled radio frequency discharge plasmas in hydrogen, which includes a rigorous kinetic modeling of ion transport and several solutions to speed up the convergence. In a test case the effect of surface atom recombination and molecule vibrational deactivation on H- concentration is investigated.

  3. Evaluation of electrical capacitance tomography sensor based on the coupling of fluid field and electrostatic field

    NASA Astrophysics Data System (ADS)

    Ye, Jiamin; Wang, Haigang; Yang, Wuqiang

    2016-07-01

    Electrical capacitance tomography (ECT) is based on capacitance measurements from electrode pairs mounted outside of a pipe or vessel. The structure of ECT sensors is vital to image quality. In this paper, issues with the number of electrodes and the electrode covering ratio for complex liquid–solids flows in a rotating device are investigated based on a new coupling simulation model. The number of electrodes is increased from 4 to 32 while the electrode covering ratio is changed from 0.1 to 0.9. Using the coupling simulation method, real permittivity distributions and the corresponding capacitance data at 0, 0.5, 1, 2, 3, 5, and 8 s with a rotation speed of 96 rotations per minute (rpm) are collected. Linear back projection (LBP) and Landweber iteration algorithms are used for image reconstruction. The quality of reconstructed images is evaluated by correlation coefficient compared with the real permittivity distributions obtained from the coupling simulation. The sensitivity for each sensor is analyzed and compared with the correlation coefficient. The capacitance data with a range of signal-to-noise ratios (SNRs) of 45, 50, 55 and 60 dB are generated to evaluate the effect of data noise on the performance of ECT sensors. Furthermore, the SNRs of experimental data are analyzed for a stationary pipe with permittivity distribution. Based on the coupling simulation, 16-electrode ECT sensors are recommended to achieve good image quality.

  4. Control of strong light-matter coupling using the capacitance of metamaterial nanocavities

    DOE PAGESBeta

    Benz, Alexander; Campione, Salvatore; Klem, John Frederick; Sinclair, Michael B.; Brener, Igal

    2015-01-27

    Metallic nanocavities with deep subwavelength mode volumes can lead to dramatic changes in the behavior of emitters placed in their vicinity. The resulting collocation and interaction often leads to strong coupling. We present for the first time experimental evidence that the Rabi splitting is directly proportional to the electrostatic capacitance associated with the metallic nanocavity. As a result, the system analyzed consists of different metamaterial geometries with the same resonance wavelength coupled to intersubband transitions in quantum wells.

  5. Cu-Zn binary phase diagram and diffusion couples

    NASA Technical Reports Server (NTRS)

    Mccoy, Robert A.

    1992-01-01

    The objectives of this paper are to learn: (1) what information a binary phase diagram can yield; (2) how to construct and heat treat a simple diffusion couple; (3) how to prepare a metallographic sample; (4) how to operate a metallograph; (5) how to correlate phases found in the diffusion couple with phases predicted by the phase diagram; (6) how diffusion couples held at various temperatures could be used to construct a phase diagram; (7) the relation between the thickness of an intermetallic phase layer and the diffusion time; and (8) the effect of one species of atoms diffusing faster than another species in a diffusion couple.

  6. Capacitive coupling in hybrid graphene/GaAs nanostructures

    SciTech Connect

    Simonet, Pauline Rössler, Clemens; Krähenmann, Tobias; Varlet, Anastasia; Ihn, Thomas; Ensslin, Klaus; Reichl, Christian; Wegscheider, Werner

    2015-07-13

    Coupled hybrid nanostructures are demonstrated using the combination of lithographically patterned graphene on top of a two-dimensional electron gas (2DEG) buried in a GaAs/AlGaAs heterostructure. The graphene forms Schottky barriers at the surface of the heterostructure and therefore allows tuning the electronic density of the 2DEG. Conversely, the 2DEG potential can tune the graphene Fermi energy. Graphene-defined quantum point contacts in the 2DEG show half-plateaus of quantized conductance in finite bias spectroscopy and display the 0.7 anomaly for a large range of densities in the constriction, testifying to their good electronic properties. Finally, we demonstrate that the GaAs nanostructure can detect charges in the vicinity of the heterostructure's surface. This confirms the strong coupling of the hybrid device: localized states in the graphene ribbon could, in principle, be probed by the underlying confined channel. The present hybrid graphene/GaAs nanostructures are promising for the investigation of strong interactions and coherent coupling between the two fundamentally different materials.

  7. Capacitively Coupled Resistivity Survey of the Sea Ice Near Barrow, Alaska

    NASA Astrophysics Data System (ADS)

    Herman, R.; Inman, J. T.

    2006-05-01

    Capacitively coupled resistivity methods have the ability to image areas of high resistivity such as the arctic sea ice. In addition, due to their mobility, capacitive arrays typically take data faster than other resistivity methods and can thus cover a wider survey area in a given amount of time. Surveys using capacitive systems have been carried out across permafrost terrain (see, e.g., Timofeev, et al, 1994 and Calvert, 1992) using dipole-dipole spacings on the order of tens of meters, giving depths of penetration of the same magnitude and showing features on the order of meters in extent. Results of a new capacitively coupled resistivity survey carried out near Barrow, Alaska will be presented. This survey uses much smaller dipole-dipole spacings in order to image the one- to two-meter thick sea ice. The data density will be such that sub-meter-sized features within the ice may be discerned. Data will be taken along multiple closely-spaced lines so that two- and three- dimensional inversion may be done yielding a more accurate representation of the sea ice.

  8. Mathematical modeling of intrinsic Josephson junctions with capacitive and inductive couplings

    NASA Astrophysics Data System (ADS)

    Rahmonov, I. R.; Shukrinov, Yu M.; Zemlyanaya, E. V.; Sarhadov, I.; Andreeva, O.

    2012-11-01

    We investigate the current voltage characteristics (CVC) of intrinsic Josephson junctions (IJJ) with two types of couplings between junctions: capacitive and inductive. The IJJ model is described by a system of coupled sine-Gordon equations which is solved numerically by the 4th order Runge-Kutta method. The method of numerical simulation and numerical results are presented. The magnetic field distribution is calculated as the function of coordinate and time at different values of the bias current. The influence of model parameters on the CVC is studied. The behavior of the IJJ in dependence on coupling parameters is discussed.

  9. Residual capacitive coupling and the measurement of permittivity in magnetic induction tomography.

    PubMed

    Griffiths, H; Gough, W; Watson, S; Williams, R J

    2007-07-01

    In an ideal magnetic induction tomography (MIT) system, the coupling between the coils and the sample is entirely by the magnetic field. In a practical system, unwanted electric-field (capacitive) coupling can also exist and cause large errors in the MIT measurements unless the hardware is designed carefully. A series of tests was carried out to assess the magnitude of capacitive coupling present in a 10 MHz MIT system designed for biomedical use and other applications involving low-conductivity samples (capacitive coupling was very small compared with the true MIT signal. Because the contamination was small, it was demonstrated possible to derive the permittivity of the sample from the real part of the MIT signal. This was shown to work well when the conductivity of the sample was less than about 0.5 S m(-1), but for higher conductivities, when the skin depth became comparable with the width of the sample, the commonly used theoretical expression for the MIT signal began to break down. This implies that the measurement of permittivity (and permeability) in real biological tissues (which have conductivities of up to 2 S m(-1)) will require a more detailed derivation taking into account both the real and imaginary parts of the signals. PMID:17664645

  10. The role of the relative voltage and phase for frequency coupling in a dual-frequency capacitively coupled plasma

    SciTech Connect

    O'Connell, D.; Gans, T.; Semmler, E.; Awakowicz, P.

    2008-08-25

    Frequency coupling in multifrequency discharges is a complex nonlinear interaction of the different frequency components. An alpha-mode low pressure rf capacitively coupled plasma operated simultaneously with two frequencies is investigated and the coupling of the two frequencies is observed to greatly influence the excitation and ionization within the discharge. Through this, plasma production and sustainment are dictated by the corresponding electron dynamics and can be manipulated through the dual-frequency sheath. These mechanisms are influenced by the relative voltage and also the relative phase of the two frequencies.

  11. Effect of antenna capacitance on the plasma characteristics of an internal linear inductively coupled plasma system

    NASA Astrophysics Data System (ADS)

    Lim, Jong Hyeuk; Kim, Kyong Nam; Park, Jung Kyun; Yeom, Geun Young

    2008-08-01

    This study examined the effect of the antenna capacitance of an inductively coupled plasma (ICP) source, which was varied using an internal linear antenna, on the electrical and plasma characteristics of the ICP source. The inductive coupling at a given rf current increased with decreasing antenna capacitance. This was caused by a decrease in the inner copper diameter of the antenna made from coaxial copper/quartz tubing, which resulted in a higher plasma density and lower plasma potential. By decreasing the diameter of the copper tube from 25to10mm, the plasma density of a plasma source size of 2750×2350mm2 was increased from approximately 8×1010/cm3to1.5×1011/cm3 at 15mTorr Ar and 9kW of rf power.

  12. Nanocellulose coupled flexible polypyrrole@graphene oxide composite paper electrodes with high volumetric capacitance

    NASA Astrophysics Data System (ADS)

    Wang, Zhaohui; Tammela, Petter; Strømme, Maria; Nyholm, Leif

    2015-02-01

    A robust and compact freestanding conducting polymer-based electrode material based on nanocellulose coupled polypyrrole@graphene oxide paper is straightforwardly prepared via in situ polymerization for use in high-performance paper-based charge storage devices, exhibiting stable cycling over 16 000 cycles at 5 A g-1 as well as the largest specific volumetric capacitance (198 F cm-3) so far reported for flexible polymer-based electrodes.A robust and compact freestanding conducting polymer-based electrode material based on nanocellulose coupled polypyrrole@graphene oxide paper is straightforwardly prepared via in situ polymerization for use in high-performance paper-based charge storage devices, exhibiting stable cycling over 16 000 cycles at 5 A g-1 as well as the largest specific volumetric capacitance (198 F cm-3) so far reported for flexible polymer-based electrodes. Electronic supplementary information (ESI) available. See DOI: 10.1039/c4nr07251k

  13. A study on improvement of discharge characteristic by using a transformer in a capacitively coupled plasma

    SciTech Connect

    Kim, Young-Cheol; Kim, Hyun-Jun; Lee, Hyo-Chang; Chung, Chin-Wook

    2015-12-15

    In a plasma discharge system, the power loss at powered line, matching network, and other transmission line can affect the discharge characteristics such as the power transfer efficiency, voltage and current at powered electrode, and plasma density. In this paper, we propose a method to reduce power loss by using a step down transformer mounted between the matching network and the powered electrode in a capacitively coupled argon plasma. This step down transformer decreases the power loss by reducing the current flowing through the matching network and transmission line. As a result, the power transfer efficiency was increased about 5%–10% by using a step down transformer. However, the plasma density was dramatically increased compared to no transformer. This can be understood by the increase in ohmic heating and the decrease in dc-self bias. By simply mounting a transformer, improvement of discharge efficiency can be achieved in capacitively coupled plasmas.

  14. Coupling capacitance between double quantum dots tunable by the number of electrons in Si quantum dots

    SciTech Connect

    Uchida, Takafumi Arita, Masashi; Takahashi, Yasuo; Fujiwara, Akira

    2015-02-28

    Tunability of capacitive coupling in the Si double-quantum-dot system is discussed by changing the number of electrons in quantum dots (QDs), in which the QDs are fabricated using pattern-dependent oxidation (PADOX) of a Si nanowire and multi-fine-gate structure. A single QD formed by PADOX is divided into multiple QDs by additional oxidation through the gap between the fine gates. When the number of electrons occupying the QDs is large, the coupling capacitance increases gradually and almost monotonically with the number of electrons. This phenomenon is attributed to the gradual growth in the effective QD size due to the increase in the number of electrons in the QDs. On the other hand, when the number of electrons changes in the few-electron regime, the coupling capacitance irregularly changes. This irregularity can be observed even up to 40 electrons. This behavior is attributable the rough structure of Si nano-dots made by PADOX. This roughness is thought to induce complicated change in the electron wave function when an electron is added to or subtracted from a QD.

  15. Data Mechanics and Coupling Geometry on Binary Bipartite Networks

    PubMed Central

    Fushing, Hsieh; Chen, Chen

    2014-01-01

    We quantify the notion of pattern and formalize the process of pattern discovery under the framework of binary bipartite networks. Patterns of particular focus are interrelated global interactions between clusters on its row and column axes. A binary bipartite network is built into a thermodynamic system embracing all up-and-down spin configurations defined by product-permutations on rows and columns. This system is equipped with its ferromagnetic energy ground state under Ising model potential. Such a ground state, also called a macrostate, is postulated to congregate all patterns of interest embedded within the network data in a multiscale fashion. A new computing paradigm for indirect searching for such a macrostate, called Data Mechanics, is devised by iteratively building a surrogate geometric system with a pair of nearly optimal marginal ultrametrics on row and column spaces. The coupling measure minimizing the Gromov-Wasserstein distance of these two marginal geometries is also seen to be in the vicinity of the macrostate. This resultant coupling geometry reveals multiscale block pattern information that characterizes multiple layers of interacting relationships between clusters on row and on column axes. It is the nonparametric information content of a binary bipartite network. This coupling geometry is then demonstrated to shed new light and bring resolution to interaction issues in community ecology and in gene-content-based phylogenetics. Its implied global inferences are expected to have high potential in many scientific areas. PMID:25170903

  16. Quantum Fluctuations of Mesoscopic Damped Circuit Involving Capacitance-Inductance Coupling at a Finite Temperature

    NASA Astrophysics Data System (ADS)

    Xu, Xing-Lei; Xu, Shi-Min; Li, Hong-Qi

    2008-06-01

    The quantization of mesoscopic damped circuit involving capacitance-inductance coupling is proposed by the method of thrice linear transformation and damped harmonic oscillator quantization. The quantum fluctuations of the charges and current of each loop are calculated by thermo-field dynamics (TFD) in thermal vacuum state, thermal coherent state and thermal squeezed state, respectively. It is shown that the quantum fluctuations of the charges and current not only depend on circuit inherent parameter and coupled magnitude, but also rely on squeezed coefficients, squeezed angle, environmental temperature and damped resistance. And, because of influence of environmental temperature and damped resistance, the quantum fluctuations increase with increasing temperature and decrease with prolonging time.

  17. Measurements of time average series resonance effect in capacitively coupled radio frequency discharge plasma

    SciTech Connect

    Bora, B.; Bhuyan, H.; Favre, M.; Wyndham, E.; Chuaqui, H.; Kakati, M.

    2011-10-15

    Self-excited plasma series resonance is observed in low pressure capacitvely coupled radio frequency discharges as high-frequency oscillations superimposed on the normal radio frequency current. This high-frequency contribution to the radio frequency current is generated by a series resonance between the capacitive sheath and the inductive and resistive bulk plasma. In this report, we present an experimental method to measure the plasma series resonance in a capacitively coupled radio frequency argon plasma by modifying the homogeneous discharge model. The homogeneous discharge model is modified by introducing a correction factor to the plasma resistance. Plasma parameters are also calculated by considering the plasma series resonances effect. Experimental measurements show that the self-excitation of the plasma series resonance, which arises in capacitive discharge due to the nonlinear interaction of plasma bulk and sheath, significantly enhances both the Ohmic and stochastic heating. The experimentally measured total dissipation, which is the sum of the Ohmic and stochastic heating, is found to increase significantly with decreasing pressure.

  18. Photopyroelectric thermal wave detection via contactless capacitive polyvinylidene fluoride (PVDF)-metal probe-tip coupling

    NASA Astrophysics Data System (ADS)

    Mieszkowski, Marek; Leung, Kwan F.; Mandelis, Andreas

    1989-03-01

    In the past, thin-film photopyroelectric detectors have provided a simple means of measuring thermal properties of solid samples. This article presents a theoretical model and experimental results demonstrating a new contactless capacitively coupled photopyroelectric detection technique. The photopyroelectric (P2E) effect with contactless capacitance PVDF-metal probe-tip coupling was demonstrated and used to obtain thermal information from a solid. Due to the small diameter of the probe, the local values of the thermal wave field in the solid were measured. The modulated photothermal source on the surface of the sample induces an oscillating temperature field in the pyroelectric material, which produces a displacement current proportional to the temperature change. The metalized surface of the pyroelectric thin film and a metal tip electrode facing the opposite unmetalized surface form a capacitor which is charged at the same frequency as the modulated light beam. The oscillating capacitive voltage provides a noncontact mechanism to extract photothermal information, since the electric field generated in the capacitor does not require plate contact with the PVDF element.

  19. Coupled binary embedding for large-scale image retrieval.

    PubMed

    Zheng, Liang; Wang, Shengjin; Tian, Qi

    2014-08-01

    Visual matching is a crucial step in image retrieval based on the bag-of-words (BoW) model. In the baseline method, two keypoints are considered as a matching pair if their SIFT descriptors are quantized to the same visual word. However, the SIFT visual word has two limitations. First, it loses most of its discriminative power during quantization. Second, SIFT only describes the local texture feature. Both drawbacks impair the discriminative power of the BoW model and lead to false positive matches. To tackle this problem, this paper proposes to embed multiple binary features at indexing level. To model correlation between features, a multi-IDF scheme is introduced, through which different binary features are coupled into the inverted file. We show that matching verification methods based on binary features, such as Hamming embedding, can be effectively incorporated in our framework. As an extension, we explore the fusion of binary color feature into image retrieval. The joint integration of the SIFT visual word and binary features greatly enhances the precision of visual matching, reducing the impact of false positive matches. Our method is evaluated through extensive experiments on four benchmark datasets (Ukbench, Holidays, DupImage, and MIR Flickr 1M). We show that our method significantly improves the baseline approach. In addition, large-scale experiments indicate that the proposed method requires acceptable memory usage and query time compared with other approaches. Further, when global color feature is integrated, our method yields competitive performance with the state-of-the-arts. PMID:24951697

  20. Self-excited nonlinear plasma series resonance oscillations in geometrically symmetric capacitively coupled radio frequency discharges

    SciTech Connect

    Donko, Z.; Schulze, J.; Czarnetzki, U.; Luggenhoelscher, D.

    2009-03-30

    At low pressures, nonlinear self-excited plasma series resonance (PSR) oscillations are known to drastically enhance electron heating in geometrically asymmetric capacitively coupled radio frequency discharges by nonlinear electron resonance heating (NERH). Here we demonstrate via particle-in-cell simulations that high-frequency PSR oscillations can also be excited in geometrically symmetric discharges if the driving voltage waveform makes the discharge electrically asymmetric. This can be achieved by a dual-frequency (f+2f) excitation, when PSR oscillations and NERH are turned on and off depending on the electrical discharge asymmetry, controlled by the phase difference of the driving frequencies.

  1. Doppler broadening of atomic-hydrogen lines in DC and capacitively coupled RF plasmas

    NASA Astrophysics Data System (ADS)

    Akhtar, Kamran; Scharer, J. E.; Mills, R. L.

    2007-10-01

    The extraordinary broadening of Balmer lines of hydrogen admixed with Ar or He as opposed to Xe in DC glow and capacitively coupled rf discharges is studied over a wide range of pressure and gas compositions. High-resolution optical emission spectroscopy is performed parallel to (end-on) and perpendicular (side-on) to the electrode axis along with Langmuir probe measurements of plasma density and electron temperature for the RF capacitive discharge case. A broad and symmetric (Gaussian) Balmer emission line corresponding to 20-60 eV hydrogen atom temperatures is observed in Ar/H2 and He/H2 plasmas. Energy is transferred selectively to hydrogen atoms whereas the atoms of admixed He and Ar gases remain cold (<0.5 eV). In the field acceleration model [e.g., Cvetanovic et. al. J. App. Phys., Vol. 97, 033302-1, 2005] there apparently is no preferred species to which energy is coupled and according to the model one should observe enhanced temperatures of hydrogen and helium atoms in He/H2 discharges where the atomic mass is more comparable (4:1). We also briefly examine the experimental results using the Resonance Transfer Model of hydrogen heating [Mills et. al IEEE Trans. Plasma Sci., 31, 338, 2003] as the source of broadening.

  2. Numerical investigation on electrical characterization of a capacitive coupled radio-frequency plasma

    NASA Astrophysics Data System (ADS)

    Yao, H.; He, X.; Chen, J. P.; Zhang, Y. C.

    2015-05-01

    This paper presents the main electrical features of capacitive coupled radio-frequency (CCRF) discharges in gas. A two-dimensional, time-dependent fluid model was established. Capacitive coupled plasmas (CCP) were produced by applying radio-frequency voltage to a pair of parallel plate electrodes which are separated from the plasma by dielectric layers. The electron equation and the electron transport equations were solved and yielded the electron number density and electron temperature. The electrostatic field was obtained by the solution of the Poisson equation. The distribution of electron temperature and electron number density was studied under different conditions: radio-frequency applied voltages (VRF=100-2000V), frequencies (f=3.0-40.68MHz), pressures (p=0.001-1torr), and gas species (O2, Ar, He, N2). The results show that electron number density presents a minimum near the electrodes, and presents a maximum between the positive and the negative electrodes. The distinguishing feature of CCP is the presence of oscillating sheaths near electrodes where displacement current dominates conduction current. These informations will help us to analyze the characters of CCP for application.

  3. Active loaded plasmonic antennas at terahertz frequencies: Optical control of their capacitive-inductive coupling

    NASA Astrophysics Data System (ADS)

    Georgiou, G.; Tserkezis, C.; Schaafsma, M. C.; Aizpurua, J.; Gómez Rivas, J.

    2015-03-01

    We demonstrate the photogeneration of loaded dipole plasmonic antennas resonating at THz frequencies. This is achieved by the patterned optical illumination of a semiconductor surface using a spatial light modulator. Our experimental results indicate the existence of capacitive and inductive coupling of localized surface plasmon polaritons. By varying the load in the antenna gap we are able to switch between both coupling regimes. Furthermore, we determine experimentally the effective impedance of the antenna load and verify that this load can be effectively expressed as a LC resonance formed by a THz inductor and capacitor connected in a parallel circuit configuration. These findings are theoretically supported by full electrodynamic calculations and by simple concepts of lumped circuit theory. Our results open new possibilities for the design of active THz circuits for optoelectronic devices.

  4. Pneumatic switched angle spinning NMR probe with capacitively coupled double saddle coil.

    PubMed

    Litvak, Ilya M; Espinosa, Catalina A; Shapiro, Rebecca A; Oldham, Andrew N; Duong, Vincent V; Martin, Rachel W

    2010-10-01

    Switched angle spinning (SAS) experiments can be used for generating isotropic-anisotropic correlations in oriented samples in a single experiment. In order for these methods to become widespread, specialized hardware is required. Here we describe the electronic and mechanical design and performance of a double-resonance SAS probe. Unlike many previous SAS probe implementations, the focus here is on systems where the dipolar couplings are partially averaged by molecular motion. This probe has a moving double saddle coil capacitively coupled to the stationary circuit. Angle switching is accomplished by a steam engine-type pneumatic mechanism. The speed and stability of the switching hardware for SAS experiments are demonstrated using spectra of model compounds. PMID:20673643

  5. Pneumatic switched angle spinning NMR probe with capacitively coupled double saddle coil

    NASA Astrophysics Data System (ADS)

    Litvak, Ilya M.; Espinosa, Catalina A.; Shapiro, Rebecca A.; Oldham, Andrew N.; Duong, Vincent V.; Martin, Rachel W.

    2010-10-01

    Switched angle spinning (SAS) experiments can be used for generating isotropic-anisotropic correlations in oriented samples in a single experiment. In order for these methods to become widespread, specialized hardware is required. Here we describe the electronic and mechanical design and performance of a double-resonance SAS probe. Unlike many previous SAS probe implementations, the focus here is on systems where the dipolar couplings are partially averaged by molecular motion. This probe has a moving double saddle coil capacitively coupled to the stationary circuit. Angle switching is accomplished by a steam engine-type pneumatic mechanism. The speed and stability of the switching hardware for SAS experiments are demonstrated using spectra of model compounds.

  6. 2D PIC/MC simulations of electrical asymmetry effect in capacitive coupled plasma

    NASA Astrophysics Data System (ADS)

    Zhang, Quan-Zhi; Jiang, Wei; Wang, You-Nian

    2011-10-01

    Recently a so-called electrical asymmetry effect (EAE), which could achieve high-degree separate control of ion flux and energy in dual-frequency capacitively coupled plasmas, was discovered theoretically by Heil et al. and was confirmed by experiments and theory/numerical simulations later on. However, since there always is a bigger grounded surface area for experiment devices, which reduces the geometrical symmetry, and all the simulations were limited to 1D before, it is, thus, worth studying the EAE when coupling the electrically and geometrically asymmetric discharges theoretically. Here, we perform 2D PIC/MC simulations, which can include both electrically and geometrically asymmetric factors. The EAE on plasma parameters, such as dc self-bias voltage, density profiles, ion energy distribution and power absorption of electron have been examined for different pressures and geometry conditions. Recently a so-called electrical asymmetry effect (EAE), which could achieve high-degree separate control of ion flux and energy in dual-frequency capacitively coupled plasmas, was discovered theoretically by Heil et al. and was confirmed by experiments and theory/numerical simulations later on. However, since there always is a bigger grounded surface area for experiment devices, which reduces the geometrical symmetry, and all the simulations were limited to 1D before, it is, thus, worth studying the EAE when coupling the electrically and geometrically asymmetric discharges theoretically. Here, we perform 2D PIC/MC simulations, which can include both electrically and geometrically asymmetric factors. The EAE on plasma parameters, such as dc self-bias voltage, density profiles, ion energy distribution and power absorption of electron have been examined for different pressures and geometry conditions. This work was supported by the National Natural Science Foundation of China (Grant No 10635010) and the Important National Science & Technology Specific Project (Grant No

  7. Coupling of Waveguide and Resonator by Inductive and Capacitive Irises for EPR Spectroscopy.

    PubMed

    Mett, R R; Sidabras, J W; Hyde, J S

    2009-01-01

    An analytic circuit model for slot coupling from a waveguide to a loop-gap resonator (LGR) in a context of electron paramagnetic resonance (EPR) spectroscopy is presented. The physical dimensions of the waveguide, iris, LGR, and aqueous sample are transformed into circuit values of inductance, capacitance, and resistance. These values are used in a solution of circuit equations that results in a prediction of the rf currents, magnitude and phase, frequency, and magnetic and electric stored energies near critical coupling. The circuit geometry reflects magnetic flux conservation between the iris and LGR as well as modification of the outer loop LGR currents by the iris. Unlike conventional models, coupling is not explicitly based on a mutual inductance between the iris and LGR. Instead, the conducting wall high frequency rf boundary condition is used to define surface currents, regions, and circuit topology with lumped-circuit values of self-inductance, capacitance, and resistance. Match is produced by a combination of self-inductive and capacitive circuit coupling. Two conditions must be met to achieve match. First, the equivalent resistance of the LGR as seen by the iris must be transformed into the waveguide characteristic impedance. This transformation is met at a particular frequency relative to the natural LGR resonance frequency. The frequency shift magnitude is largely determined by the LGR properties, weakly dependent on iris length and placement, and independent of other iris dimensions. The second condition for match is that the iris reactance at this frequency shift must cancel the residual reactance of the LGR. This second condition is sensitive to the iris dimensions. If both conditions are not simultaneously satisfied, overcoupling or undercoupling results. A slotted iris of equal length to the size of the large dimension of the waveguide is found to have many properties opposite to a conventional iris of shorter length. Notably, the magnetic field

  8. Coupling of Waveguide and Resonator by Inductive and Capacitive Irises for EPR Spectroscopy

    PubMed Central

    Mett, R.R.; Sidabras, J.W.; Hyde, J.S.

    2009-01-01

    An analytic circuit model for slot coupling from a waveguide to a loop-gap resonator (LGR) in a context of electron paramagnetic resonance (EPR) spectroscopy is presented. The physical dimensions of the waveguide, iris, LGR, and aqueous sample are transformed into circuit values of inductance, capacitance, and resistance. These values are used in a solution of circuit equations that results in a prediction of the rf currents, magnitude and phase, frequency, and magnetic and electric stored energies near critical coupling. The circuit geometry reflects magnetic flux conservation between the iris and LGR as well as modification of the outer loop LGR currents by the iris. Unlike conventional models, coupling is not explicitly based on a mutual inductance between the iris and LGR. Instead, the conducting wall high frequency rf boundary condition is used to define surface currents, regions, and circuit topology with lumped-circuit values of self-inductance, capacitance, and resistance. Match is produced by a combination of self-inductive and capacitive circuit coupling. Two conditions must be met to achieve match. First, the equivalent resistance of the LGR as seen by the iris must be transformed into the waveguide characteristic impedance. This transformation is met at a particular frequency relative to the natural LGR resonance frequency. The frequency shift magnitude is largely determined by the LGR properties, weakly dependent on iris length and placement, and independent of other iris dimensions. The second condition for match is that the iris reactance at this frequency shift must cancel the residual reactance of the LGR. This second condition is sensitive to the iris dimensions. If both conditions are not simultaneously satisfied, overcoupling or undercoupling results. A slotted iris of equal length to the size of the large dimension of the waveguide is found to have many properties opposite to a conventional iris of shorter length. Notably, the magnetic field

  9. The electrical asymmetry effect in capacitively coupled radio-frequency discharges

    NASA Astrophysics Data System (ADS)

    Czarnetzki, U.; Schulze, J.; Schüngel, E.; Donkó, Z.

    2011-04-01

    We present an analytical model to describe capacitively coupled radio-frequency (CCRF) discharges and the electrical asymmetry effect (EAE) based on the non-linearity of the boundary sheaths. The model describes various discharge types, e.g. single and multi-frequency as well as geometrically symmetric and asymmetric discharges. It yields simple analytical expressions for important plasma parameters such as the dc self-bias, the uncompensated charge in both sheaths, the discharge current and the power dissipated to electrons. Based on the model results the EAE is understood. This effect allows control of the symmetry of CCRF discharges driven by multiple consecutive harmonics of a fundamental frequency electrically by tuning the individual phase shifts between the driving frequencies. This novel class of capacitive radio-frequency (RF) discharges has various advantages: (i) A variable dc self-bias can be generated as a function of the phase shifts between the driving frequencies. In this way, the symmetry of the sheaths in geometrically symmetric discharges can be broken and controlled for the first time. (ii) Almost ideal separate control of ion energy and flux at the electrodes can be realized in contrast to classical dual-frequency discharges driven by two substantially different frequencies. (iii) Non-linear self-excited plasma series resonance oscillations of the RF current can be switched on and off electrically even in geometrically symmetric discharges. Here, the basics of the EAE are introduced and its main applications are discussed based on experimental, simulation, and modeling results.

  10. Experimental observation of multi-layer excitation structure in capacitively coupled SF6 plasmas

    NASA Astrophysics Data System (ADS)

    Liu, Yong-Xin; Gao, Fei; Song, Yuan-Hong; Li, Xue-Chun; Wang, You-Nian

    2015-09-01

    Electron excitation dynamics in capacitively coupled SF6 plasmas driven at 9 MHz ~ 16 MHz are studied by using phase resolved optical emission spectroscopy (PROES) of trace rare gas. Multi-layer excitation structure inside the bulk plasma of capacitive discharges operating in SF6 is experimentally observed for the first time. Experimental results show that with the decrease of the rf power and/or the increase of the pressure, the multi-layer excitation structure becomes noticeable while the gap between two adjacent layers is almost kept constant. By increasing the driving frequency with a constant electrode gap, however, the number of layers increases while the layer gap decreases. The layer structure disappears at the driving frequency larger than 16 MHz. The electrode gap is found to have a negligible effect on the gap between two adjacent excitation layers, nevertheless only the number of excitation layers is increased when enlarging the electrode gap. The multi-layer formation may be due to a large modulation of the F- negative-ion density throughout the bulk plasma, and is more pronounced at intermediate and low frequencies, since F- negative ions do not respond to the time-varying electric field at high frequencies (>16 MHz). This work was supported by the National Natural Science Foundation of China (NSFC) (Grant No. 11335004) and (Grant No.11405018), and the International Science & Technology Cooperation Program of China (Grant No. 2012DFG02150).

  11. Emissive Probe Measurements in a Dual-Frequency-Confined Capacitively-Coupled-Plasma System

    NASA Astrophysics Data System (ADS)

    Linnane, Shane; Ellingboe, Albert R.

    2002-10-01

    Dual frequency confined capacitively coupled plasmas (DFC-CCP) are increasingly used in semiconductor manufacturing for dielectric etching, allowing greater (and independent) control of ion energies and ion flux on the etched substrate. The powered electrode is driven with the summation of 27MHz and 2MHz sinusoidal voltages, while the other electrode is grounded. The electrode areas are similar in size, giving an electrode aspect ratio less than 2. Because of this low aspect ratio, there are large oscillations in the plasma potential. The expectation is for sinusoidal oscillations at the higher driving frequency, due to capacitive sheaths, while a rectified oscillation is expected at the lower driving frequency.(E. Kawamura, V. Vahedi, M. A. Lieberman and C. K. Birdsall, Plasma Sources Sci. Technology. 8 (1999) R45-R64 Work Supported by EURATOM.) Measurements of rf oscillation in the plasma potential taken with a floating emissive probe will be presented. The emissive probe and circuitry allows direct realtime measurement of plasma potential oscillation at both driving frequencies and the harmonics of each, thus allowing measurement of the actual potential on the driven electrode and ion energy incident on grounded electrode.

  12. Diffusion Dynamics of Charged Dust Particles in Capacitively Coupled RF Discharge System

    SciTech Connect

    Chew, W. X.; Muniandy, S. V.; Wong, C. S.; Yap, S. L.; Tan, K. S.

    2011-03-30

    Dusty plasma is loosely defined as electron-ion plasma with additional charged components of micron-sized dust particles. In this study, we developed a particle diagnostic technique based on light scattering and particle tracking velocimetry to investigate the dynamics of micron-sized titanium oxide particles in Argon gas capacitively coupled rf-discharge. The particle trajectories are constructed from sequence of image frames and treated as sample paths of charged Brownian motion. At specific sets of plasma parameters, disordered liquid-like dust particle configuration are observed. Mean-square-displacement of the particle trajectories are determined to characterize the transport dynamics. We showed that the dust particles in disordered liquid phase exhibit anomalous diffusion with different scaling exponents for short and large time scales, indicating the presence of slow and fast modes which can be related to caging effect and dispersive transport, respectively.

  13. The electrical asymmetry effect in multi-frequency capacitively coupled radio frequency discharges

    NASA Astrophysics Data System (ADS)

    Schulze, J.; Schüngel, E.; Donkó, Z.; Czarnetzki, U.

    2011-02-01

    The electrical asymmetry effect (EAE) in geometrically symmetric capacitively coupled radio frequency discharges operated at multiple consecutive harmonics is investigated by a particle-in-cell (PIC) simulation and an analytical model. The model is based on the original EAE model, which is extended by taking into account the floating potentials, the voltage drop across the plasma bulk, and the symmetry parameter resulting from the PIC simulation. Compared with electrically asymmetric dual-frequency discharges we find that (i) a significantly stronger dc self-bias can be generated electrically and that (ii) the mean ion energies at the electrodes can be controlled separately from the ion flux over a broader range by tuning the phase shifts between the individual voltage harmonics. A recipe for the optimization of the applied voltage waveform to generate the strongest possible dc self-bias electrically and to obtain maximum control of the ion energy via the EAE is presented.

  14. Field reversals in electrically asymmetric capacitively coupled radio-frequency discharges in hydrogen

    NASA Astrophysics Data System (ADS)

    Mohr, Sebastian; Schüngel, Edmund; Schulze, Julian; Czarnetzki, Uwe

    2013-10-01

    In this paper, we present a simulation study of electrically asymmetric capacitively coupled radio-frequency hydrogen discharges using the hybrid plasma equipment model operated at the combined frequencies of 10 and 20 MHz. We find that, in such discharges, field reversals cause ionization near the electrodes during the sheath collapse. In the case of the investigated asymmetric voltage waveforms, the field reversals are asymmetrically distributed over the sheaths, which causes asymmetric ionization and density profiles. The asymmetry of these profiles can be controlled by the phase angle between the two frequencies. As a result, the possibility to control the ion energy independently from the ion flux via the electrical asymmetry effect (EAE) is reduced in discharges displaying strong field reversals, as the asymmetric field reversals compensate the electrically induced asymmetry. The reason for this is understood by an analytical model. Furthermore, we demonstrate, that the EAE can be restored by the addition of specific gases to a pure hydrogen discharge.

  15. Direct current dielectric barrier assistant discharge to get homogeneous plasma in capacitive coupled discharge

    SciTech Connect

    Du, Yinchang; Li, Yangfang; Cao, Jinxiang; Liu, Yu; Wang, Jian; Zheng, Zhe

    2014-06-15

    In this paper, we propose a method to get more homogeneous plasma in the geometrically asymmetric capacitive coupled plasma (CCP) discharge. The dielectric barrier discharge (DBD) is used for the auxiliary discharge system to improve the homogeneity of the geometrically asymmetric CCP discharge. The single Langmuir probe measurement shows that the DBD can increase the electron density in the low density volume, where the DBD electrodes are mounted, when the pressure is higher than 5 Pa. By this manner, we are able to improve the homogeneity of the plasma production and increase the overall density in the target volume. At last, the finite element simulation results show that the DC bias, applied to the DBD electrodes, can increase the homogeneity of the electron density in the CCP discharge. The simulation results show a good agreement with the experiment results.

  16. Simulation of dust particles in dual-frequency capacitively coupled silane discharges

    SciTech Connect

    Liu Xiangmei; Song Yuanhong; Xu Xiang; Wang Younian

    2010-01-15

    The behavior of nanoparticles in dual-frequency capacitively coupled silane discharges is investigated by employing a one-dimensional self-consistent fluid model. The numerical simulation tries to trace the formation, charging, growth, and transport of dust particles during the discharge, under the influences of the high- and low-frequency electric sources, as well as the gas pressure. The effects of the presence of the nanoparticles and larger anions on the plasma properties are also discussed, especially, for the bulk potential, electron temperature, and densities of various particles. The calculation results show that the nanoparticle density and charge distribution are mainly influenced by the voltage and frequency of the high-frequency source, while the voltage of the low-frequency source can also exert an effect on the nanoparticle formation, compared with the frequency. As the discharge lasts, the electric potential and electron density keep decreasing, while the electron temperature gets increasing after a sudden drop.

  17. Kinetic simulation of capacitively coupled plasmas driven by trapezoidal asymmetric voltage pulses

    SciTech Connect

    Diomede, Paola Economou, Demetre J.

    2014-06-21

    A kinetic Particle-In-Cell simulation with Monte Carlo Collisions was performed of a geometrically symmetric capacitively coupled, parallel-plate discharge in argon, driven by trapezoidal asymmetric voltage pulses with a period of 200 ns. The discharge was electrically asymmetric, making the ion energy distributions at the two electrodes different from one another. The fraction of the period (α), during which the voltage was kept at a constant (top-flat) positive value, was a critical control parameter. For the parameter range investigated, as α increased, the mean ion energy on the grounded electrode increased and the ions became more directional, whereas the opposite was found for the ions striking the powered electrode. The absolute value of the DC self-bias voltage decreased as α increased. Plasma instabilities, promoted by local double layers and electric field reversals during the time of the positive voltage excursion, were characterized by electron plasma waves launched from the sheath edge.

  18. Kinetic simulation of capacitively coupled plasmas driven by trapezoidal asymmetric voltage pulses

    NASA Astrophysics Data System (ADS)

    Diomede, Paola; Economou, Demetre J.

    2014-06-01

    A kinetic Particle-In-Cell simulation with Monte Carlo Collisions was performed of a geometrically symmetric capacitively coupled, parallel-plate discharge in argon, driven by trapezoidal asymmetric voltage pulses with a period of 200 ns. The discharge was electrically asymmetric, making the ion energy distributions at the two electrodes different from one another. The fraction of the period (α), during which the voltage was kept at a constant (top-flat) positive value, was a critical control parameter. For the parameter range investigated, as α increased, the mean ion energy on the grounded electrode increased and the ions became more directional, whereas the opposite was found for the ions striking the powered electrode. The absolute value of the DC self-bias voltage decreased as α increased. Plasma instabilities, promoted by local double layers and electric field reversals during the time of the positive voltage excursion, were characterized by electron plasma waves launched from the sheath edge.

  19. Numerical Study of a System of Long Josephson Junctions with Inductive and Capacitive Couplings

    NASA Astrophysics Data System (ADS)

    Rahmonov, I. R.; Shukrinov, Yu. M.; Plecenik, A.; Zemlyanaya, E. V.; Bashashin, M. V.

    2016-02-01

    The phase dynamics of the stacked long Josephson junctions is investigated taking into account the inductive and capacitive couplings between junctions and the diffusion current. The simulation of the current-voltage characteristics is based on the numerical solution of a system of nonlinear partial differential equations by a fourth order Runge-Kutta method and finite-difference approximation. A parallel implementation is based on the MPI technique. The effectiveness of the MPI/C++ code is confirmed by calculations on the multi-processor cluster CICC (LIT JINR, Dubna). We demonstrate the appearance of the charge traveling wave (CTW) at the boundary of the zero field step. Based on this fact, we conclude that the CTW and the fluxons coexist.

  20. Tailored-waveform excitation of capacitively coupled plasmas and the electrical asymmetry effect

    NASA Astrophysics Data System (ADS)

    Lafleur, T.

    2016-02-01

    Unequal areas of the powered and grounded electrodes in single-frequency capacitively coupled plasmas (CCPs) are well-known to generate a DC self-bias voltage and an asymmetric plasma response. By instead applying non-sinusoidal waveforms composed of multiple harmonics—referred to in the literature as arbitrary waveforms, multi-harmonic waveforms or tailored waveforms—an asymmetric plasma response and a DC self-bias can also be produced; even for perfectly geometrically symmetric systems. This electrical asymmetry effect (EAE) has opened the doors to a wide range of novel ideas and interesting new physics that could allow limitations between the control of the ion flux and ion energy in traditional CCPs to be broken; thus helping to develop next-generation industrial plasma processing reactors. This review is dedicated to the current status of the EAE, and highlights important theoretical, numerical and experimental work in the field that has contributed to our understanding.

  1. Tumor Selective Hyperthermia Induced by Short-Wave Capacitively-Coupled RF Electric-Fields

    PubMed Central

    Raoof, Mustafa; Cisneros, Brandon T.; Corr, Stuart J.; Palalon, Flavio; Curley, Steven A.; Koshkina, Nadezhda V.

    2013-01-01

    There is a renewed interest in developing high-intensity short wave capacitively-coupled radiofrequency (RF) electric-fields for nanoparticle-mediated tumor-targeted hyperthermia. However, the direct thermal effects of such high-intensity electric-fields (13.56 MHZ, 600 W) on normal and tumor tissues are not completely understood. In this study, we investigate the heating behavior and dielectric properties of normal mouse tissues and orthotopically-implanted human hepatocellular and pancreatic carcinoma xenografts. We note tumor-selective hyperthermia (relative to normal mouse tissues) in implanted xenografts that can be explained on the basis of differential dielectric properties. Furthermore, we demonstrate that repeated RF exposure of tumor-bearing mice can result in significant anti-tumor effects compared to control groups without detectable harm to normal mouse tissues. PMID:23861912

  2. Metalless electrodes for capacitively coupled contactless conductivity detection on electrophoresis microchips.

    PubMed

    Duarte Junior, Gerson F; Fracassi da Silva, José Alberto; Mendonça Francisco, Kelliton José; do Lago, Claudimir Lucio; Carrilho, Emanuel; Coltro, Wendell K T

    2015-08-01

    This paper describes the use of ionic solutions as sensing electrodes for capacitively coupled contactless conductivity detection on electrophoresis microchips. Initially, two channels were engraved in a PMMA holder by using a CO2 laser system and sealed with a thin adhesive membrane. PDMS electrophoresis chips were fabricated by soft lithography and reversibly sealed against the polymer membrane. Different ionic solutions were investigated as metalless electrodes. The electrode channels were filled with KCl solutions prepared in conductivity values from approximately 10 to 40 S/m. The best analytical response was achieved using the KCl solution with 21.9 S/m conductivity (2 mol/L). Besides KCl, we also tested NaCl and LiCl solutions for actuating as detection electrodes. Taking into account the same electrolyte concentration (2 mol/L), the best response was recorded with KCl solution due to its higher ionic conductivity. The optimum operating frequency (400 kHz) and the best sensing electrode (2 mol/L KCl) were used to monitor electrophoretic separations of a mixture containing K(+) , Na(+) , and Li(+) . The use of liquid solutions as sensing electrodes for capacitively coupled contactless conductivity detection measurements has revealed great performance to monitor separations on chip-based devices, avoiding complicated fabrication schemes to include metal deposition and encapsulation of electrodes. The LOD values were estimated to be 28, 40, and 58 μmol/L for K(+) , Na(+) , and Li(+) , respectively, what is comparable to that of conventional metal electrodes. When compared to the use metal electrodes, the proposed approach offers advantages regarding the easiness of fabrication, simplicity, and lower cost per device. PMID:25809443

  3. Capacitively coupled singlet-triplet qubits in the double charge resonant regime

    NASA Astrophysics Data System (ADS)

    Srinivasa, V.; Taylor, J. M.

    2015-12-01

    We investigate a method for entangling two singlet-triplet qubits in adjacent double quantum dots via capacitive interactions. In contrast to prior work, here we focus on a regime with strong interactions between the qubits. The interplay of the interaction energy and simultaneous large detunings for both double dots gives rise to the "double charge resonant" regime, in which the unpolarized (1111) and fully polarized (0202) four-electron states in the absence of interqubit tunneling are near degeneracy, while being energetically well separated from the partially polarized (0211 and 1102) states. A rapid controlled-phase gate may be realized by combining time evolution in this regime in the presence of intraqubit tunneling and the interqubit Coulomb interaction with refocusing π pulses that swap the singly occupied singlet and triplet states of the two qubits via, e.g., magnetic gradients. We calculate the fidelity of this entangling gate, incorporating models for two types of noise—charge fluctuations in the single-qubit detunings and charge relaxation within the low-energy subspace via electron-phonon interaction—and identify parameter regimes that optimize the fidelity. The rates of phonon-induced decay for pairs of GaAs or Si double quantum dots vary with the sizes of the dipolar and quadrupolar contributions and are several orders of magnitude smaller for Si, leading to high theoretical gate fidelities for coupled singlet-triplet qubits in Si dots. We also consider the dependence of the capacitive coupling on the relative orientation of the double dots and find that a linear geometry provides the fastest potential gate.

  4. A novel in-line frequency sensor based on coupling capacitance for X-band application

    NASA Astrophysics Data System (ADS)

    Yan, Jiabin; Liao, Xiaoping; Yi, Zhenxiang

    2016-05-01

    This paper presents a novel in-line frequency sensor, based on coupling capacitance, for X-band applications. The novel frequency sensor can achieve absolute frequency measurement with a simple structure and no DC power consumption. Fabrication of the frequency sensor is completely compatible with the GaAs monolithic microwave integrated circuit process. A well-designed metal–insulator–metal capacitor is employed to couple a certain percentage of incident power and a thermoelectric power sensor is used to measure the coupled power. The sensor design is guided by HFSS simulation and a lumped circuit model. The results validate the effectiveness of the simulation and model, and show relatively good performance of the frequency sensor with simple and reliable components. The net sensitivity of the frequency sensor is about 1.43 mV (W•GHz)‑1, and the measured S 11 and S 21 are better than  ‑14.8 dB and  ‑1.39 dB at X-band.

  5. Properties of linear arrays of Josephson junctions capacitively coupled to a diffusive metal

    NASA Astrophysics Data System (ADS)

    Lobos, Alejandro; Giamarchi, Thierry

    2011-03-01

    Josephson junctions arrays (JJAs) are strongly-correlated quantum systems showing a rich and complex behavior at low-temperatures. Besides their potential uses in applications, JJAs allow to investigate (under controlled conditions) many aspects of low-dimensional superconductivity which remain to be understood. In this work we study the phase diagram and the low-energy properties of a one-dimensional (1D) JJA capacitively coupled to a diffusive two-dimensional electron gas (2DEG) placed at a distance d , which provides dissipation. We derive an effective field-theoretical model for the 1D JJA coupled to the 2DEG, and predict a superconductor-insulator transition (SIT) at T = 0 , in agreement with former theoretical predictions. We discuss implications for transport experiments and for the observed SIT in 1DJJAs. Both in the superconducting and insulating phases, the coupling to the 2DEG produces deviations with respect to the resistivity as a function of T predicted for an isolated array. This work was supported in part by the Swiss SNF under MaNEP and division II.

  6. SOLUTION NEBULIZATION OF AQUEOUS SAMPLES INTO THE TUBULAR-ELECTRODE TORCH CAPACITATIVELY-COUPLED MICROWAVE PLASMA (JOURNAL VERSION)

    EPA Science Inventory

    The work shows the feasibility of using nebulization for introduction of aqueous samples into the tubular-torch capacitatively-coupled microwave plasma (CMP). Previously, solid electrodes were used with this type of plasma, in which analyte carrier and plasma support gases are pr...

  7. Magnetic-Field Asymmetry of Electron Wave Packet Transmission in Bent Channels Capacitively Coupled to a Metal Gate

    NASA Astrophysics Data System (ADS)

    Kalina, R.; Szafran, B.; Bednarek, S.; Peeters, F. M.

    2009-02-01

    We study the electron wave packet moving through a bent channel. We demonstrate that the packet transmission probability becomes an asymmetric function of the magnetic field when the electron packet is capacitively coupled to a metal plate. The coupling occurs through a nonlinear potential which translates a different kinetics of the transport for opposite magnetic-field orientations into a different potential felt by the scattered electron.

  8. Capacitive micromachined ultrasonic transducers based on annular cell geometry for air-coupled applications.

    PubMed

    Na, Shuai; Chen, Albert I H; Wong, Lawrence L P; Li, Zhenhao; Macecek, Mirek; Yeow, John T W

    2016-09-01

    A novel design of an air-coupled capacitive micromachined ultrasonic transducer (CMUT) with annular cell geometry (annular CMUT) is proposed. Finite element analysis shows that an annular cell has a ratio of average-to-maximum displacement (RAMD) of 0.52-0.58 which is 58-76% higher than that of a conventional circular cell. The increased RAMD leads to a larger volume displacement which results in a 48.4% improved transmit sensitivity and 127.3% improved power intensity. Single-cell annular CMUTs were fabricated with 20-μm silicon plates on 13.7-μm deep and 1.35-mm wide annular cavities using the wafer bonding technique. The measured RAMD of the fabricated CMUTs is 0.54. The resonance frequency was measured to be 94.5kHz at 170-V DC bias. The transmit sensitivity was measured to be 33.83Pa/V and 25.85Pa/V when the CMUT was excited by a continuous wave and a 20-cycle burst, respectively. The receive sensitivity at 170-V DC bias was measured to be 7.7mV/Pa for a 20-cycle burst, and 15.0mV/Pa for a continuous incident wave. The proposed annular CMUT design demonstrates a significant improvement in transmit efficiency, which is an important parameter for air-coupled ultrasonic transducers. PMID:27352025

  9. Influence of frequency on the characteristics of VHF capacitively coupled plasmas in a 300 mm chamber

    NASA Astrophysics Data System (ADS)

    Hebner, G. A.; Barnat, E. V.; Miller, P. A.; Paterson, A.; Holland, J.; Lill, T.

    2004-09-01

    We have investigated the characteristics of VHF capacitively coupled plasmas produced in a modified Applied Materials chamber. The chamber had a 14-inch diameter upper electrode (source) that was driven at 10 to 160 MHz and a 300 mm diameter electrostatic chuck with a ceramic process kit that was driven at 13.56 MHz (bias). Diagnostics employed include a microwave interferometer to measure the line-integrated electron density, a hairpin microwave resonator to measure the spatially resolved electron density, absorption spectroscopy to determine the argon metastable temperature and density, laser induced fluorescence (LIF) to determine the spatial distribution of the excited species, and spatially resolved optical emission. We found that for constant source rf power, the electron density increased with rf frequency. The argon 1s5 metastable temperature was slightly above room temperature (300 - 400K), significantly cooler than our previous measurements in inductively coupled plasmas. The metastable density was not a strong function of source frequency or rf power. The metastable spatial distribution was always peaked in the center of the chamber and had a weak dependence on frequency. Scaling of the plasma parameters with frequency, power and pressure, and implications to energy deposition models will be discussed. This work was supported by Applied Materials and Sandia National Laboratories, a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  10. High-voltage capacitively coupled contactless conductivity detection for microchip capillary electrophoresis.

    PubMed

    Tanyanyiwa, Jatisai; Hauser, Peter C

    2002-12-15

    Contactless conductivity detection was carried out on a planar electrophoresis device by capacitive coupling using an ac excitation voltage of 500 V(p-p) and a frequency of 100 kHz. It was possible to carry out detection in this way through a cover plate of 1 mm thickness. Better sensitivity is obtained, however, by placing the electrodes into troughs that allow tighter coupling to the separation channel. The 3 x S/N detection limits are 0.49, 0.41, and 0.35 microM for the small inorganic ions K+, Na+, and Mg2+. The detection of heavy metals is demonstrated with the example of Mn2+, Zn2+, and Cr3+ with detection limits of 2.1, 2.8, and 6.8 microM, respectively. The universal nature of the method is further illustrated by the detection of citric and lactic acids, which are of interest in food and beverage analysis, and detection of three antiinflammatory nonsteroid drugs, 4-acetamidophenol, ibuprofen, and salicylic acid, as examples of species of pharmaceutical interest. PMID:12510762

  11. 3-Dimensional Modeling of Capacitively and Inductively Coupled Plasma Etching Systems

    NASA Astrophysics Data System (ADS)

    Rauf, Shahid

    2008-10-01

    Low temperature plasmas are widely used for thin film etching during micro and nano-electronic device fabrication. Fluid and hybrid plasma models were developed 15-20 years ago to understand the fundamentals of these plasmas and plasma etching. These models have significantly evolved since then, and are now a major tool used for new plasma hardware design and problem resolution. Plasma etching is a complex physical phenomenon, where inter-coupled plasma, electromagnetic, fluid dynamics, and thermal effects all have a major influence. The next frontier in the evolution of fluid-based plasma models is where these models are able to self-consistently treat the inter-coupling of plasma physics with fluid dynamics, electromagnetics, heat transfer and magnetostatics. We describe one such model in this paper and illustrate its use in solving engineering problems of interest for next generation plasma etcher design. Our 3-dimensional plasma model includes the full set of Maxwell equations, transport equations for all charged and neutral species in the plasma, the Navier-Stokes equation for fluid flow, and Kirchhoff's equations for the lumped external circuit. This model also includes Monte Carlo based kinetic models for secondary electrons and stochastic heating, and can take account of plasma chemistry. This modeling formalism allows us to self-consistently treat the dynamics in commercial inductively and capacitively coupled plasma etching reactors with realistic plasma chemistries, magnetic fields, and reactor geometries. We are also able to investigate the influence of the distributed electromagnetic circuit at very high frequencies (VHF) on the plasma dynamics. The model is used to assess the impact of azimuthal asymmetries in plasma reactor design (e.g., off-center pump, 3D magnetic field, slit valve, flow restrictor) on plasma characteristics at frequencies from 2 -- 180 MHz. With Jason Kenney, Ankur Agarwal, Ajit Balakrishna, Kallol Bera, and Ken Collins.

  12. Ion flux's pressure dependence in an asymmetric capacitively coupled rf discharge in NF3

    NASA Astrophysics Data System (ADS)

    Mateev, Emil; Zhelyazkov, Ivan

    2004-03-01

    Starting from an analytical macroscopic/phenomenological model yielding the self-bias voltage as a function of the absorbed radio-frequency (rf) power of an asymmetric capacitively coupled discharge in NF3 this paper studies the dependence of the ion flux onto the powered electrode on the gas pressure. An essential feature of the model is the assumption that the ions' drift velocity in the sheath near the powered electrode is proportional to E α, where E=-ΔU (U being the self-bias potential), and α is a coefficient depending on the gas pressure and cross section of elastic ion-neutral collisions. The model also considers the role of γ-electrons, stochastic heating as well as the contribution of the active electron current to the global discharge power balance. Numerically solving the model's basic equations one can extract the magnitude of the ion flux (at three different gas pressures) in a technological etching device (Alcatel GIR 220) by using easily measurable quantities, notably the self-bias voltage and absorbed rf power.

  13. The pressure dependence of the discharge properties in a capacitively coupled oxygen discharge

    NASA Astrophysics Data System (ADS)

    Gudmundsson, J. T.; Ventéjou, Bruno

    2015-10-01

    We use the one-dimensional object-oriented particle-in-cell Monte Carlo collision code oopd1 to explore the evolution of the charged particle density profiles, electron heating mechanism, and the electron energy probability function (EEPF) in a capacitively coupled oxygen discharge with pressure in the pressure range of 10-500 mTorr. We find that at higher pressure (50-500 mTorr) the electron heating occurs mainly in the sheath region, and detachment by the metastable singlet molecule O2(a1Δg) has a significant influence on the electron heating process. At a low pressure (10 mTorr), Ohmic heating in the bulk plasma (the electronegative core) dominates, and detachment by O2(a1Δg) has only a small influence on the heating process. Thus at low pressure, the EEPF is convex and as the pressure is increased the number of low energy electrons increases and the number of higher energy electrons (>10 eV) decreases, and the EEPF develops a concave shape or becomes bi-Maxwellian.

  14. Experimental and simulation study of a capacitively coupled oxygen discharge driven by tailored voltage waveforms

    NASA Astrophysics Data System (ADS)

    Derzsi, Aranka; Lafleur, Trevor; Booth, Jean-Paul; Korolov, Ihor; Donkó, Zoltán

    2016-02-01

    We report experimental and particle-based kinetic simulation studies of low-pressure capacitively coupled oxygen plasmas driven by tailored voltage waveforms that consist of up to four harmonics of base frequency 13.56 MHz. Experimentally determined values of DC self-bias and electrical power deposition, as well as flux density and flux-energy distribution of the positive ions at the grounded electrode are compared with simulation data for a wide range of operating conditions. Very good agreement is found for self-bias and flux-energy distribution of the positive ions at the electrodes, while a fair agreement is reached for discharge power and ion flux data. The simulated spatial and temporal behaviour of the electric field, electron density, electron power absorption, ionization rate and mean electron energy shows a transition between sheath expansion heating and drift-ambipolar discharge modes, induced by changing either the number of harmonics comprising the excitation waveform or the gas pressure. The simulations indicate that under our experimental conditions the plasma operates at high electronegativity, and also reveal the crucial role of {{\\text{O}}2}≤ft({{a}1}{{Δ }g}\\right) singlet metastable molecules in establishing discharge behavior via the fast destruction of negative ions within the bulk plasma.

  15. The role of the singlet metastables in capacitively coupled oxygen discharges

    NASA Astrophysics Data System (ADS)

    Gudmundsson, Jon Tomas; Lieberman, Michael A.

    2015-09-01

    The roles of the singlet metastable molecules O2(a1Δg) and O2(b1Σg) in a capacitively coupled rf driven oxygen discharge at 50 mTorr are explored using the one-dimensional object-oriented PIC/MCC code oopd1. Earlier we have demonstrated that the metastable molecule O2(a1Δg) has a significant influence on the discharge properties such as the electronegativity, the effective electron temperature and the electron heating processes. A recent global model study indicates that the density of O2(b1Σg) state can be higher than the density of the O2(a1Δg) state. Thus the oxygen discharge model now includes the O2(b1Σg) molecule and related reactions. The singlet metastable states of the oxygen molecule have significant influence on the discharge properties. Electron heating is only observed in the sheath region and the electron energy probability function becomes even more concave or bi-Maxwellian when the O2(b1Σg) state is included in the simulation. The center electronegativity is in the range of 0.67 - 1.9.

  16. Control of plasma properties in capacitively coupled oxygen discharges via the electrical asymmetry effect

    NASA Astrophysics Data System (ADS)

    Schüngel, E.; Zhang, Q.-Z.; Iwashita, S.; Schulze, J.; Hou, L.-J.; Wang, Y.-N.; Czarnetzki, U.

    2011-07-01

    Using a combined experimental, numerical and analytical approach, we investigate the control of plasma properties via the electrical asymmetry effect (EAE) in a capacitively coupled oxygen discharge. In particular, we present the first experimental investigation of the EAE in electronegative discharges. A dual-frequency voltage source of 13.56 MHz and 27.12 MHz is applied to the powered electrode and the discharge symmetry is controlled by adjusting the phase angle θ between the two harmonics. It is found that the bulk position and density profiles of positive ions, negative ions, and electrons have a clear dependence on θ, while the peak densities and the electronegativity stay rather constant, largely due to the fact that the time-averaged power absorption by electrons is almost independent of θ. This indicates that the ion flux towards the powered electrode remains almost constant. Meanwhile, the dc self-bias and, consequently, the sheath widths and potential profile can be effectively tuned by varying θ. This enables a flexible control of the ion bombarding energy at the electrode. Therefore, our work proves the effectiveness of the EAE to realize separate control of ion flux and ion energy in electronegative discharges. At low pressure, the strength of resonance oscillations, which are found in the current of asymmetric discharges, can be controlled with θ.

  17. Electrical asymmetry effect for controlling the transport of micrometer-sized particles in capacitively coupled plasmas

    NASA Astrophysics Data System (ADS)

    Iwashita, Shinya; Schuengel, Edmund; Schulze, Julian; Uchida, Giichiro; Koga, Kazunori; Hartmann, Peter; Shiratani, Masaharu; Donko, Zoltan; Czarnetzki, Uwe

    2012-10-01

    We have developed a novel method to control the dust particle transport in capacitively coupled plasmas via the electrical asymmetry effect (EAE) [1]. At low pressures the EAE allows controlling the spatial potential profile and the ion density distribution by adjusting the phase angle between a fundamental frequency and its second harmonic, resulting in control of forces exerted on dust particles such as electrostatic and ion drag forces. We report the experimental results of this method using SiO2 particles of 1.5 μm in size, which are inserted into an argon discharge. Initially dust particles tend to be confined at the sheath edge near the bottom electrode, and the change of their equilibrium position with plasma due to the adiabatic phase shift can be well understood by the electric field profile obtained from a simple analytical model. By applying the abrupt change of phase angle from 90 to 0 dust particles are transported between both sheaths through the plasma bulk [1]. Based on the model of this transport [1] the potential profile can be obtained by experimental results.[4pt] [1] Iwashita S et al., Plasma Sources Sci. Technol. 21 (2012) 032001.

  18. Prevention of ion flux inhomogeneities in large area capacitively coupled discharges via the Electrical Asymmetry Effect

    NASA Astrophysics Data System (ADS)

    Schuengel, Edmund; Schulze, Julian; Mohr, Sebastian; Czarnetzki, Uwe

    2014-10-01

    For large area processing applications of capacitively coupled radio frequency (CCRF) discharges, the lateral uniformity of the plasma surface interaction is crucially important. The benefit of an increase in the plasma density and, therefore, in the overall deposition rate by driving the discharge at higher frequencies is accompanied with inhomogeneities caused by the presence of electromagnetic effects. Here, we propose a method based on the Electrical Asymmetry Effect (EAE) to prevent such inhomogeneities. Spatially resolved measurements of the ion flux onto the grounded electrode of a CCRF discharge operated in hydrogen show a standing wave pattern in a 81.36 MHz single-frequency discharge, strongly reducing the ion flux uniformity. However, applying a dual-frequency voltage waveform consisting of 40.68 MHz + 81.36 MHz, the lateral distribution of the ion flux can be controlled via the phase angle between the two applied harmonics. Using the EAE, a phase angle dependent DC self-bias develops in the geometrically symmetric discharge. Tuning the phase angle allows for the compensation of ion flux inhomogeneities due to the standing wave effect. Thus, a high and laterally uniform ion flux can be generated in electrically asymmetric high frequency plasmas. Funding by the German Federal Ministry for the Environment, Nature conservation, and Nuclear Safety (0325210B) is gratefully acknowledged.

  19. Numerical simulations of electrical asymmetry effect on electronegative plasmas in capacitively coupled rf discharge

    NASA Astrophysics Data System (ADS)

    Zhang, Quan-Zhi; Jiang, Wei; Hou, Lu-Jing; Wang, You-Nian

    2011-01-01

    Recently a so-called electrical asymmetry effect (EAE), which could achieve high-degree separate control of ion flux and energy in dual-frequency capacitively coupled radio-frequency (CCRF) discharges, was discovered theoretically by Heil et al. [J. Phys. D: Appl. Phys. 41, 165202 (2008)] and was confirmed by experiments and theory/numerical simulations later on for electropositive argon discharges. In this work simulations based on particle-in-cell/Monte Carlo collision are performed to study the EAE on electronegative oxygen plasmas in geometrically symmetric CCRF discharges. Dual frequency discharges operating at 13.56 and 27.12 MHz are simulated for different pressures and the results are compared with those of electropositive argon discharges at the same conditions. It is found that in general the EAE on oxygen discharges has similar behavior as on argon discharge: The self-bias voltage η increases monotonically and almost linearly with the increase in the phase angle θ between the two driving voltages in the range 0<θ<90°, and the maximum ion energy varies by a factor of 3 by adjusting θ. However, the ion flux varies with θ by ±12% for low pressure and by ±15% for higher pressure, due primarily to an enhanced plasma series resonance, which then leads to dramatic changes in plasma density, power absorption and consequently the electronegativity. This may place a limitation for achieving separate control of ion energy and flux for electronegative plasma via the EAE.

  20. Experimental and numerical investigations of the phase-shift effect in capacitively coupled discharges

    SciTech Connect

    Gao, Fei; Zhang, Yu-Ru; Zhao, Shu-Xia; Wang, You-Nian

    2014-08-15

    The phase-shift effect has been investigated by a Langmuir probe and a fluid model in Ar capacitively coupled plasmas at 50 mTorr. In the discharge, two sources with the same frequency, i.e., 27.12 MHz, are applied on the top and bottom electrodes simultaneously, and the phase shift between them varies from 0 to π. It is found that the electron density has an off-axis peak near the radial edge when the phase difference is equal to 0 due to the electrostatic edge effect, and the best radial uniformity is observed at a phase difference equal to π. Furthermore, when the voltage increases, the best radial uniformity is obtained at lower phase shift values. Moreover, the electron energy probability function has a bi-temperature structure at all the selected phase differences at r = 1–15 cm. The evolution of the plasma characteristics with the phase difference implies that the best radial uniformity can be obtained, by balancing the electrostatic edge effect and the phase shift effect.

  1. Numerical simulations of electrical asymmetry effect on electronegative plasmas in capacitively coupled rf discharge

    SciTech Connect

    Zhang Quanzhi; Jiang Wei; Wang Younian; Hou Lujing

    2011-01-01

    Recently a so-called electrical asymmetry effect (EAE), which could achieve high-degree separate control of ion flux and energy in dual-frequency capacitively coupled radio-frequency (CCRF) discharges, was discovered theoretically by Heil et al. [J. Phys. D: Appl. Phys. 41, 165202 (2008)] and was confirmed by experiments and theory/numerical simulations later on for electropositive argon discharges. In this work simulations based on particle-in-cell/Monte Carlo collision are performed to study the EAE on electronegative oxygen plasmas in geometrically symmetric CCRF discharges. Dual frequency discharges operating at 13.56 and 27.12 MHz are simulated for different pressures and the results are compared with those of electropositive argon discharges at the same conditions. It is found that in general the EAE on oxygen discharges has similar behavior as on argon discharge: The self-bias voltage {eta} increases monotonically and almost linearly with the increase in the phase angle {theta} between the two driving voltages in the range 0<{theta}<90 deg. , and the maximum ion energy varies by a factor of 3 by adjusting {theta}. However, the ion flux varies with {theta} by {+-}12% for low pressure and by {+-}15% for higher pressure, due primarily to an enhanced plasma series resonance, which then leads to dramatic changes in plasma density, power absorption and consequently the electronegativity. This may place a limitation for achieving separate control of ion energy and flux for electronegative plasma via the EAE.

  2. Effect of temperature on capacitive RF MEMS switch performance—a coupled-field analysis

    NASA Astrophysics Data System (ADS)

    Zhu, Yong; Espinosa, Horacio D.

    2004-08-01

    Three-dimensional multiphysics finite element analysis (FEA) was performed to investigate the reliability of RF MEMS switches at various operational temperatures. The investigated MEMS capacitive switch consists of a freestanding metal membrane actuated by a bottom electrode coated by a dielectric film. Coupled-field simulations between thermal, structural and electrostatic domains were performed. The simulations show that temperature significantly changes both the membrane stress state and out-of-plane geometry. In particular, the membrane buckles when temperature increase, from room temperature, takes place. The buckling temperature, i.e. the upper bound to the operational temperature, is a function of manufacturing residual stress state, membrane initial out-of-plane profile and a mismatch in materials coefficient of thermal expansion. The analysis also shows that temperature reduction, from room temperature to -40 °C, causes an increase in pull-in voltage to values that could compromise the switch reliability as a result of charge build-up in the dielectric layer. Our analyses illustrate that by proper designing of the membrane out-of-plane profile, it is possible to keep the pull-in voltage, at all operational temperatures, within allowable values. This design feature of RF MEMS switches offers an effective way to achieve reliable pull-in voltages in applications where large temperature variations are expected such as in satellites and airplane condition monitoring based on wireless communication.

  3. Capacitively coupled hydrogen plasmas sustained by tailored voltage waveforms: excitation dynamics and ion flux asymmetry

    NASA Astrophysics Data System (ADS)

    Bruneau, B.; Diomede, P.; Economou, D. J.; Longo, S.; Gans, T.; O’Connell, D.; Greb, A.; Johnson, E.; Booth, J.-P.

    2016-08-01

    Parallel plate capacitively coupled plasmas in hydrogen at relatively high pressure (~1 Torr) are excited with tailored voltage waveforms containing up to five frequencies. Predictions of a hybrid model combining a particle-in-cell simulation with Monte Carlo collisions and a fluid model are compared to phase resolved optical emission spectroscopy measurements, yielding information on the dynamics of the excitation rate in these discharges. When the discharge is excited with amplitude asymmetric waveforms, the discharge becomes electrically asymmetric, with different ion energies at each of the two electrodes. Unexpectedly, large differences in the \\text{H}2+ fluxes to each of the two electrodes are caused by the different \\text{H}3+ energies. When the discharge is excited with slope asymmetric waveforms, only weak electrical asymmetry of the discharge is observed. In this case, electron power absorption due to fast sheath expansion at one electrode is balanced by electron power absorption at the opposite electrode due to a strong electric field reversal.

  4. Analysis of ecstasy tablets using capillary electrophoresis with capacitively coupled contactless conductivity detection.

    PubMed

    Porto, Suely K S S; Nogueira, Thiago; Blanes, Lucas; Doble, Philip; Sabino, Bruno D; do Lago, Claudimir L; Angnes, Lúcio

    2014-11-01

    A method for the identification of 3,4-methylenedioxymethamphetamine (MDMA) and meta-chlorophenylpiperazine (mCPP) was developed employing capillary electrophoresis (CE) with capacitively coupled contactless conductivity detection (C(4) D). Sample extraction, separation, and detection of "Ecstasy" tablets were performed in <10 min without sample derivatization. The separation electrolyte was 20 mm TAPS/Lithium, pH 8.7. Average minimal detectable amounts for MDMA and mCPP were 0.04 mg/tablet, several orders of magnitude lower than the minimum amount encountered in a tablet. Seven different Ecstasy tablets seized in Rio de Janeiro, Brazil, were analyzed by CE-C(4) D and compared against routine gas chromatography-mass spectrometry (GC-MS). The CE method demonstrated sufficient selectivity to discriminate the two target drugs, MDMA and mCPP, from the other drugs present in seizures, namely amphepramone, fenproporex, caffeine, lidocaine, and cocaine. Separation was performed in <90 sec. The advantages of using C(4) D instead of traditional CE-UV methods for in-field analysis are also discussed. PMID:25039689

  5. Reversal of the asymmetry in a cylindrical coaxial capacitively coupled Ar/Cl2 plasma

    DOE PAGESBeta

    Upadhyay, Janardan; Im, Do; Popović, Svetozar; Vušković, Leposava; Valente-Feliciano, Anne -Marie; Phillips, Larry

    2015-10-08

    The reduction of the asymmetry in the plasma sheath voltages of a cylindrical coaxial capacitively coupled plasma is crucial for efficient surface modification of the inner surfaces of concave three-dimensional structures, including superconducting radio frequency cavities. One critical asymmetry effect is the negative dc self-bias, formed across the inner electrode plasma sheath due to its lower surface area compared to the outer electrode. The effect on the self-bias potential with the surface enhancement by geometric modification on the inner electrode structure is studied. The shapes of the inner electrodes are chosen as cylindrical tube, large and small pitch bellows, andmore » disc-loaded corrugated structure (DLCS). The dc self-bias measurements for all these shapes were taken at different process parameters in Ar/Cl2 discharge. Lastly, the reversal of the negative dc self-bias potential to become positive for a DLCS inner electrode was observed and the best etch rate is achieved due to the reduction in plasma asymmetry.« less

  6. Characteristics of VHF capacitively coupled plasmas in a 300 mm chamber

    NASA Astrophysics Data System (ADS)

    Hebner, G. A.; Miller, P. A.; Barnat, E. V.; Paterson, A.; Holland, J.; Lill, T.

    2004-09-01

    We have investigated the characteristics of VHF capacitively coupled plasmas produced in a modified Applied Materials chamber. The chamber had a 14-inch diameter upper electrode (source) that was driven at 10 to 160 MHz and a 300 mm diameter electrostatic chuck with a ceramic process kit that was driven at 13.56 MHz (bias). Diagnostics employed include rf diagnostics to measure the voltage and current, Bdot probes to measure the spatial magnetic fields, a microwave interferometer to measure the line-integrated electron density, a hairpin microwave resonator to measure the spatially resolved electron density, absorption spectroscopy to determine the argon metastable temperature and density, laser induced fluorescence (LIF) to determine the spatial distribution of the excited species, and spatially resolved optical emission. Scaling of the plasma parameters with frequency, power and pressure, and implications to energy deposition models will be discussed. This work was supported by Applied Materials and Sandia National Laboratories, a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  7. Spectroscopy diagnostic of dual-frequency capacitively coupled CHF{sub 3}/Ar plasma

    SciTech Connect

    Liu, Wen-Yao; Du, Yong-Quan; Liu, Yong-Xin; Liu, Jia; Zhao, Tian-Liang; Wang, You-Nian; Xu, Yong; Li, Xiao-Song; Zhu, Ai-Min

    2013-11-15

    A combined spectroscopic method of absorption, actinometry, and relative optical emission intensity is employed to determine the absolute CF{sub 2} density, the relative F and H densities, H atom excitation temperature and the electron density in dual-frequency (60/2 MHz) capacitively coupled CHF{sub 3}/Ar plasmas. The effects of different control parameters, such as high-frequency (HF) power, low-frequency (LF) power, gas pressure, gap length and content of CHF{sub 3}, on the concentration of radical CF{sub 2}, F, and H and excitation temperature are discussed, respectively. It is found that the concentration of CF{sub 2} is strongly dependent on the HF power, operating pressure and the proportion of CHF{sub 3} in feed gas, while it is almost independent of the LF power and the gap length. A higher concentration ratio of F to CF{sub 2} could be obtained in dual-frequency discharge case. Finally, the generation and decay mechanisms of CF{sub 2} and F were also discussed.

  8. Capacitively Coupled RF Plasmas for the Synthesis of Silicon Nanocrystals: Scaling and Mechanisms

    NASA Astrophysics Data System (ADS)

    Markosyan, Aram H.; Le Picard, Romain; Porter, David H.; Girshick, Steven L.; Kushner, Mark J.

    2015-09-01

    Silicon nanocrystals (SNCs) are of interest for light emitting electronics, photovoltaics, and biotechnology. SNCs are produced in low pressure capacitively coupled plasmas (CCPs) sustained in SiH4 containing mixtures. To optimize these applications, it is necessary to control the size distribution of the SNCs. Particles 3-5 nm diameter are typically tailored by flow rates and power, however the fundamental processes responsible for this size control are not well understood. We developed a 2-d computer model for RF powered CCPs to predict the synthesis of SNCs. An aerosol sectional model was incorporated into the Hybrid Plasma Equipment Model. The reactor is a quartz tube a few mm in diameter through which 100 sccm Ar and 15 sccm He/SiH4 = 95/5 at 2 Torr are flowed. The SNC residence time is 1-2 ms in the dense plasma region near the electrodes. We found that the distribution of plasma potential is important in determining the growth and size distribution of the SNCs. The SNCs having long residence times in the plasma, thereby enabling growth, are usually negatively charged. To ultimately allow these SNCs to flow out of the plasma, the distribution of the plasma potential must enable the particles to be entrained in the neutral gas flow without a significant potential barrier. We also found that agglomeration of particles of <1 nm is important in the rate of growth of SNCs. Work supported by DOE (DE-SC0001939) and NSF (CHE-124752).

  9. PIC/MCC simulation of capacitively coupled discharges: Effect of particle management and integration

    NASA Astrophysics Data System (ADS)

    Sun, Anbang; Becker, Markus M.; Loffhagen, Detlef

    2016-09-01

    A PIC/MCC simulation model for the analysis of low-temperature discharge plasmas is represented which takes the common leapfrog and the velocity Verlet algorithm for the particle integration, adaptive particle management as well as parallel computing using MPI into account. Main features of the model including the impact of super particle numbers, adaptive particle management and the time step size for the different integration methods are represented. The investigations are performed for low-pressure capacitively coupled radio frequency discharges in helium and argon. Besides a code verification by comparison with benchmark simulation results in helium it is shown that an adaptive particle management is particularly suitable for the simulation of discharges at elevated pressures where boundary effects and processes in the sheath regions are important. Furthermore, it is pointed out that the velocity Verlet integration scheme allows to speed up the PIC/MCC simulations compared to the leapfrog method because it makes the use of larger time steps at the same accuracy possible.

  10. Influence of nanoparticle formation on discharge properties in argon-acetylene capacitively coupled radio frequency plasmas

    NASA Astrophysics Data System (ADS)

    Wegner, Th.; Hinz, A. M.; Faupel, F.; Strunskus, T.; Kersten, H.; Meichsner, J.

    2016-02-01

    This contribution presents experimental results regarding the influence of nanoparticle formation in capacitively coupled radio frequency (13.56 MHz) argon-acetylene plasmas. The discharge is studied using non-invasive 160 GHz Gaussian beam microwave interferometry and optical emission spectroscopy. Particularly, the temporal behavior of the electron density from microwave interferometry is analyzed and compared with the changing plasma emission and self-bias voltage caused by nanoparticle formation. The periodic particle formation with a cycle duration between 30 s and 140 s starts with an electron density drop over more than one order of magnitude below the detection limit (8 × 1014 m-3). The electron density reduction is the result of electron attachment processes due to negative ions and nanoparticle formation. The onset time constant of nanoparticle formation is five times faster compared to the expulsion of the particles from the plasma due to multi-disperse size distribution. Moreover, the intensity of the argon transition lines increases and implies a rising effective electron temperature. The cycle duration of the particle formation is affected by the total gas flow rate and exhibits an inverse proportionality to the square of the total gas flow rate. The variation in the total gas flow rate influences the force balance, which determines the confinement time of the nanoparticles. As a further result, the cycle duration is dependent on the axial position of the powered electrode, which also corresponds to different distances relative to the fixed optical axis of the microwave interferometer.

  11. Review of ion energy and angular distributions in capacitively coupled RF plasma reactors

    SciTech Connect

    Kawamura, E.; Lieberman, M.A.; Birdsall, C.K.; Vahedi, V.

    1995-12-31

    The authors present a historical review and discussion of previous works on ion energy and angular distributions (IED and IAD) arriving at the target in the collisionless regime. This regime is of great interest to experimentalists and modelers studying the new generation of high density sources in which the sheath is much thinner than in the conventional RIE systems. The purpose of the review is to asses what has been done so far, and to clarify some issues about sheaths in high density systems. Having determined the important parameters, the authors show some particle-in-cell simulation results of a dually excited capacitively coupled plasma in which the sheath ions roughly see the scaling as in high density sources. The results show that when {tau}{sub ion}/{tau}{sub rf} < 1, the oscillating voltage and width of the rf sheath significantly affect the IEDs, where {tau}{sub ion} is the ion transit-time and {tau}{sub rf} is rf period.

  12. Influence of finite geometrical asymmetry of the electrodes in capacitively coupled radio frequency plasma

    SciTech Connect

    Bora, B. Soto, L.

    2014-08-15

    Capacitively coupled radio frequency (CCRF) plasmas are widely studied in last decades due to the versatile applicability of energetic ions, chemically active species, radicals, and also energetic neutral species in many material processing fields including microelectronics, aerospace, and biology. A dc self-bias is known to generate naturally in geometrically asymmetric CCRF plasma because of the difference in electrode sizes known as geometrical asymmetry of the electrodes in order to compensate electron and ion flux to each electrode within one rf period. The plasma series resonance effect is also come into play due to the geometrical asymmetry and excited several harmonics of the fundamental in low pressure CCRF plasma. In this work, a 13.56 MHz CCRF plasma is studied on the based on the nonlinear global model of asymmetric CCRF discharge to understand the influences of finite geometrical asymmetry of the electrodes in terms of generation of dc self-bias and plasma heating. The nonlinear global model on asymmetric discharge has been modified by considering the sheath at the grounded electrode to taking account the finite geometrical asymmetry of the electrodes. The ion density inside both the sheaths has been taken into account by incorporating the steady-state fluid equations for ions considering that the applied rf frequency is higher than the typical ion plasma frequency. Details results on the influences of geometrical asymmetry on the generation of dc self-bias and plasma heating are discussed.

  13. Voltage distribution over capacitively coupled plasma electrode for atmospheric-pressure plasma generation

    PubMed Central

    2013-01-01

    When capacitively coupled plasma (CCP) is used to generate large-area plasma, the standing wave effect becomes significant, which results in the hindering of the uniform plasma process such as in a plasma etcher or plasma chemical vapor deposition. In this study, the transmission line modeling method is applied to calculate the voltage distribution over atmospheric-pressure CCP electrodes with the size of 1 m × 0.2 m. The measured plasma impedance in our previous study was used in the present calculation. The results of the calculations clearly showed the effects of excitation frequency and the impedance of the plasma on the form of the voltage distribution caused by the standing wave effect. In the case of 150 MHz frequency, the standing wave effect causes a drastic change in the voltage distribution via plasma ignition; however, the change is small for 13.56 MHz. It was also clarified that the power application position is important for obtaining a uniform voltage distribution. PMID:23634893

  14. Characterisation of graphene fibres and graphene coated fibres using capacitively coupled contactless conductivity detector.

    PubMed

    Cabot, Joan M; Duffy, Emer; Currivan, Sinéad; Ruland, Andres; Jalili, Rouhollah; Mozer, Attila J; Innis, Peter C; Wallace, Gordon G; Breadmore, Michael; Paull, Brett

    2016-04-25

    The use of capacitively coupled contactless conductivity detection (C(4)D) for the characterisation of thin conductive graphene fibres, graphene composite fibres, and graphene coated fibrous materials is demonstrated for the first time. Within a few seconds, the non-destructive C(4)D detector provides a profile of the longetudinal physical homogeneity of the fibre, as well as extra information regarding fibre mophology and composition. In addition to the theoretical considerations related to the factors affect the output signal, this work evaluates the properties of graphene fibres using scanning C(4)D following the manufacturing process of wet-spinning. Furthermore, conductive graphene-coated fibrous materials and the effectiveness of the coating and reduction procedures applied could be investigated. Apart from the application of C(4)D in the monitoring of such processes, the feasibility of this small, highly sensitive and rapidly-responsive detector to monitor strain and elasticity responses of conductive and elastomeric composite fibres for applications in motion sensing, biomedical monitoring, and stretchable electronics was also demonstrated. PMID:26911662

  15. Experimental investigations of driving frequency effect in low-pressure capacitively coupled oxygen discharges

    SciTech Connect

    Liu, Jia; Liu, Yong-Xin; Liu, Gang-Hu; Gao, Fei; Wang, You-Nian

    2015-04-14

    The effect of driving frequency on the electron density is investigated in low-pressure capacitively coupled oxygen plasmas by utilizing a floating hairpin probe. The power absorbed by the plasma is investigated and it is found that the power lost in the matching network can reach 50% or higher under certain conditions. The effect of driving frequency on the electron density is studied from two aspects, i.e., constant absorbed power and electrode voltage. In the former case, the electron density increases with the driving frequency increasing from 13.56 to 40.68 MHz and slightly changes depending on the gas pressures with the frequency further increasing to 100 MHz. In the latter case, the electron density rapidly increases when the driving frequency increases from 13.56 to 40.68 MHz, and then decreases with the frequency further increasing to 100 MHz. The electron series resonance is observed at 40.68 MHz and can be attributed to the higher electron density. And the standing wave effect also plays an important role in increasing electron density at 100 MHz and 2.6 Pa.

  16. Experimental investigations of driving frequency effect in low-pressure capacitively coupled oxygen discharges

    NASA Astrophysics Data System (ADS)

    Liu, Jia; Liu, Yong-Xin; Liu, Gang-Hu; Gao, Fei; Wang, You-Nian

    2015-04-01

    The effect of driving frequency on the electron density is investigated in low-pressure capacitively coupled oxygen plasmas by utilizing a floating hairpin probe. The power absorbed by the plasma is investigated and it is found that the power lost in the matching network can reach 50% or higher under certain conditions. The effect of driving frequency on the electron density is studied from two aspects, i.e., constant absorbed power and electrode voltage. In the former case, the electron density increases with the driving frequency increasing from 13.56 to 40.68 MHz and slightly changes depending on the gas pressures with the frequency further increasing to 100 MHz. In the latter case, the electron density rapidly increases when the driving frequency increases from 13.56 to 40.68 MHz, and then decreases with the frequency further increasing to 100 MHz. The electron series resonance is observed at 40.68 MHz and can be attributed to the higher electron density. And the standing wave effect also plays an important role in increasing electron density at 100 MHz and 2.6 Pa.

  17. Heart Rate Variability Monitoring during Sleep Based on Capacitively Coupled Textile Electrodes on a Bed

    PubMed Central

    Lee, Hong Ji; Hwang, Su Hwan; Yoon, Hee Nam; Lee, Won Kyu; Park, Kwang Suk

    2015-01-01

    In this study, we developed and tested a capacitively coupled electrocardiogram (ECG) measurement system using conductive textiles on a bed, for long-term healthcare monitoring. The system, which was designed to measure ECG in a bed with no constraints of sleep position and posture, included a foam layer to increase the contact region with the curvature of the body and a cover to ensure durability and easy installation. Nine healthy subjects participated in the experiment during polysomnography (PSG), and the heart rate (HR) coverage and heart rate variability (HRV) parameters were analyzed to evaluate the system. The experimental results showed that the mean of R-peak coverage was 98.0% (95.5%–99.7%), and the normalized errors of HRV time and spectral measures between the Ag/AgCl system and our system ranged from 0.15% to 4.20%. The root mean square errors for inter-beat (RR) intervals and HR were 1.36 ms and 0.09 bpm, respectively. We also showed the potential of our developed system for rapid eye movement (REM) sleep and wake detection as well as for recording of abnormal states. PMID:26007716

  18. The capacitance and electromechanical coupling of lipid membranes close to transitions: the effect of electrostriction.

    PubMed

    Heimburg, Thomas

    2012-09-01

    Biomembranes are thin capacitors with the unique feature of displaying phase transitions in a physiologically relevant regime. We investigate the voltage and lateral pressure dependence of their capacitance close to their chain melting transition. Because the gel and the fluid membrane have different area and thickness, the capacitance of the two membrane phases is different. In the presence of external fields, charges exert forces that can influence the state of the membrane, thereby influencing the transition temperature. This phenomenon is called "electrostriction". We show that this effect allows us to introduce a capacitive susceptibility that assumes a maximum in the melting transition with an associated excess charge. As a consequence, voltage regimes exist in which a small change in voltage can lead to a large uptake of charge and a large capacitive current. Furthermore, we consider electromechanical behavior such as pressure-induced changes in capacitance, and the application of such concepts in biology. PMID:23009841

  19. Heating mode transition in a hybrid direct current/dual-frequency capacitively coupled CF{sub 4} discharge

    SciTech Connect

    Zhang, Quan-Zhi; Wang, You-Nian; Bogaerts, Annemie

    2014-06-14

    Computer simulations based on the particle-in-cell/Monte Carlo collision method are performed to study the plasma characteristics and especially the transition in electron heating mechanisms in a hybrid direct current (dc)/dual-frequency (DF) capacitively coupled CF{sub 4} discharge. When applying a superposed dc voltage, the plasma density first increases, then decreases, and finally increases again, which is in good agreement with experiments. This trend can be explained by the transition between the four main heating modes, i.e., DF coupling, dc and DF coupling, dc source dominant heating, and secondary electron dominant heating.

  20. Studies on the effect of finite geometrical asymmetry in dual capacitively coupled radio frequency plasma

    NASA Astrophysics Data System (ADS)

    Bora, B.

    2015-10-01

    In recent years, dual capacitively coupled radio frequency (CCRF) glow discharge plasma has been widely studied in the laboratory because of its simpler design and high efficiency for different material processing applications such as thin-film deposition, plasma etching, sputtering of insulating materials etc. The main objective of studies on dual frequency CCRF plasma has been the independent control of ion energy and ion flux using an electrical asymmetry effect (EAE). Most studies have been reported in electrode configurations that are either geometrically symmetric (both electrodes are equal) or completely asymmetric (one electrode is infinitely bigger than the other). However, it seems that most of the laboratory CCRF plasmas have finite electrode geometry. In addition, plasma series resonance (PSR) and electron bounce resonance (EBR) heating also come into play as a result of geometrical asymmetry as well as EAE. In this study, a dual frequency CCRF plasma has been studied in which the dual frequency CCRF has been coupled to the lumped circuit model of the plasma and the time-independent fluid model of the plasma sheath, in order to study the effect of finite geometrical asymmetry on the generation of dc-self bias and plasma heating. The dc self-bias is found to strongly depend on the ratio of the area between the electrodes. The dc self-bias is found to depend on the phase angle between the two applied voltage waveforms. The EAE and geometrical asymmetry are found to work differently in controlling the dc self-bias. It can be concluded that the phase angle between the two voltage waveforms in dual CCRF plasmas has an important role in determining the dc self-bias and may be used for controlling the plasma properties in the dual frequency CCRF plasma.

  1. Electric Field Measurements of the Capacitively Coupled Magnetized RF Sheath Utilizing Passive Optical Emission Spectroscopy

    NASA Astrophysics Data System (ADS)

    Martin, Elijah Henry

    A major challenge facing magnetic confinement fusion is the implementation of reliable plasma heating systems. Ion cyclotron resonance heating (ICRH) is a key technique utilized to achieve the ion temperatures necessary for desirable fusion reaction rates. ICRH systems are designed to couple energy into the core plasma ions through a resonant interaction with an electromagnetic wave in the radio frequency range. The interaction of the wave with the scrape off layer plasma establishes an electric field which terminates directly on the plasma facing surfaces and is referred to as the near-field. In order to bridge the gap between the theoretical and actual performance of ICRF antennas, experimental measurement of this electric field is highly desired. However, due to the large amount of power launched by ICRF antennas only non-local measurements have thus far been obtained. The research presented in this dissertation is centered on the development of a non-perturbative diagnostic to locally measure the near-field with high spatial and temporal resolution. The main objective of the research presented in this dissertation is to develop and validate a spectroscopic diagnostic capable of measuring local time periodic electric fields. The development phase of the diagnostic consisted of atomic physics formulation and was carried out in two steps. The first involved the calculation of the electronic structure of the one and two-electron atom utilizing the hydrogenic wave function. The second involved the calculation of the spectral line profile based on the electric dipole connection operator. The validate phase of the diagnostic consisted of implementation of the atomic physics to measure the electric field topology associated with the capacitively coupled magnetized RF sheath using passive OES. The experimental measurements are then compared to a simple one-dimensional analytical model providing the validation of the developed atomic physics.

  2. Estimation of Electron Temperature and Frequency Components in a Dual Frequency Capacitively-Coupled Plasma Processing Reactor

    NASA Astrophysics Data System (ADS)

    Ito, Toru; Mo, Yun; Masahiro, Horigome

    2008-10-01

    The measurement of electron temperature in RF plasma sources with Langmuir probes is difficult because of the influence of rf noise. We attempted to estimate the electron temperature in a capacitively-coupled plasma processing reactor with a Surface Wave Probe [1] which employs microwaves. We also estimated the frequency spectrum with the sensitive PAP [1, 2]. We measured the harmonics which appeared in the bulk plasma for various experimental conditions in the dual-frequency [60 MHz and 2MHz] capacitively-coupled plasma processing reactor. We estimated RF power spectra for several experimental conditions like RF power [500-2000W], gas pressure [3-20Pa], and gas species [Ar, CF4]. The measurement results suggest the existence of energy transport among several frequency spectrum. [1ex] [1] K. Nakamura, M. Ohata, and H. Sugai: J. Vac. Sci. Technol. A 21, 325 (2003). [0pt] [2] T. Shirakawa and H. Sugai : Jpn. J. Appl. Phys. 32, 5129 (1993).

  3. Single charge detection in capacitively coupled integrated single electron transistors based on single-walled carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Zhou, Xin; Ishibashi, Koji

    2012-09-01

    Single charge detection is demonstrated in the capacitively coupled integrated single electron transistors (SETs) in single-walled carbon nanotubes (SWCNTs) quantum dots. Two SETs are fabricated based on two different SWCNTs aligned in parallel, by taking advantage of the aligned growth of SWCNTs and subsequent transfer-printed techniques. In order to make both two SETs be capacitively coupled, a metal finger is fabricated on the top of them. The charge sensing is proved by the response of a detector current in one SWCNT-SET when the number of electrons in the other SWCNT-SET is changed by sweeping the corresponding gate voltages. In this integrated device, shifts of Coulomb oscillation peaks due to the single electron event are also observed.

  4. Simple in-house flow-injection capillary electrophoresis with capacitively coupled contactless conductivity method for the determination of colistin.

    PubMed

    Chaisuwan, Patcharin; Moonta, Thararat; Sangcakul, Areeporn; Nacapricha, Duangjai; Wilairat, Prapin; Uraisin, Kanchana

    2015-03-01

    An in-house flow-injection capillary electrophoresis with capacitively coupled contactless conductivity detection method was developed for the direct measurement of colistin in pharmaceutical samples. The flow injection and capillary electrophoresis systems are connected by an acrylic interface. Capillary electrophoresis separation is achieved within 2 min using a background electrolyte solution of 5 mM 2-morpholinoethanesulfonic acid and 5 mM histidine (pH 6). The flow-injection section allows for convenient filling of the capillary and sample introduction without the use of a pressure/vacuum manifold. Capacitively coupled contactless conductivity detection is employed since colistin has no chromophore but is cationic at pH 6. Calibration curve is linear from 20 to 150 mg/L, with a correlation coefficient (r(2) ) of 0.997. The limit of quantitation is 20 mg/L. The developed method provides precision, simplicity, and short analysis time. PMID:25641810

  5. Production of high-density capacitively coupled radio-frequency discharge plasma by high-secondary-electron-emission oxide

    SciTech Connect

    Ohtsu, Yasunori; Fujita, Hiroharu

    2004-11-22

    High-density capacitively coupled radio-frequency plasma with electron density n{sub e}>10{sup 10} cm{sup -3} was produced using MgO electrodes with a high secondary-electron-emission coefficient. It was found that in the case of MgO electrodes, both plasma density and optical emission intensity were about one order of magnitude higher than those in the case of Al electrodes.

  6. Geophysical characterization of the Lollie Levee near Conway, Arkansas, using capacitively coupled resistivity, coring, and direct push logging

    USGS Publications Warehouse

    Gillip, Jonathan A.; Payne, Jason D.

    2011-01-01

    A geophysical characterization of Lollie Levee near Conway, Arkansas, was conducted in February 2011. A capacitively coupled resistivity survey (using Geometric's OhmMapper) was completed along the top and toe of the 6.7-mile levee. Two-dimensional inversions were conducted on the geophysical data. As a quality-control measure, cores and direct push logs were taken at approximately 1-mile intervals along the levee. The capacitively coupled resistivity survey, the coring, and the direct push logs were used to characterize the geologic materials. Comparison of the cores and the direct push log data, along with published resistivity values, indicates that resistivity values of 200 Ohm-meters or greater represent relatively clean sand, with decreasing resistivity values occurring with increasing silt and clay content. The cores indicated that the levee is composed of a heterogeneous mixture of sand, silt, and clay. The capacitively coupled resistivity sections confirm that the levee is composed of a heterogeneous mixture of high and low resistivity materials and show that the composition of the levee varies spatially. The geologic materials underlying the levee vary spatially as a result of the geologic processes that deposited them. In general, the naturally deposited geologic materials underlying the levee contain a greater amount of low resistivity materials in the southern extent of the levee.

  7. Tailored voltage waveform capacitively coupled plasmas in electronegative gases: frequency dependence of asymmetry effects

    NASA Astrophysics Data System (ADS)

    Schüngel, E.; Korolov, I.; Bruneau, B.; Derzsi, A.; Johnson, E.; O’Connell, D.; Gans, T.; Booth, J.-P.; Donkó, Z.; Schulze, J.

    2016-07-01

    Capacitively coupled radio frequency plasmas operated in an electronegative gas (CF4) and driven by voltage waveforms composed of four consecutive harmonics are investigated for different fundamental driving frequencies using PIC/MCC simulations and an analytical model. As has been observed previously for electropositive gases, the application of peak-shaped waveforms (that are characterized by a strong amplitude asymmetry) results in the development of a DC self-bias due to the electrical asymmetry effect (EAE), which increases the energy of ions arriving at the powered electrode. In contrast to the electropositive case (Korolov et al 2012 J. Phys. D: Appl. Phys. 45 465202) the absolute value of the DC self-bias is found to increase as the fundamental frequency is reduced in this electronegative discharge, providing an increased range over which the DC self-bias can be controlled. The analytical model reveals that this increased DC self-bias is caused by changes in the spatial profile and the mean value of the net charge density in the grounded electrode sheath. The spatio-temporally resolved simulation data show that as the frequency is reduced the grounded electrode sheath region becomes electronegative. The presence of negative ions in this sheath leads to very different dynamics of the power absorption of electrons, which in turn enhances the local electronegativity and plasma density via ionization and attachment processes. The ion flux to the grounded electrode (where the ion energy is lowest) can be up to twice that to the powered electrode. At the same time, while the mean ion energies at both electrodes are quite different, their ratio remains approximately constant for all base frequencies studied here.

  8. Determination of carbethopendecinium bromide in eye drops by capillary electrophoresis with capacitively coupled contactless conductivity detection.

    PubMed

    Petrů, Klára; Jáč, Pavel; Šindelková, Martina; Polášek, Miroslav

    2011-05-01

    Antiseptic agent carbethopendecinium bromide (septonex) was determined by capillary electrophoresis with capacitively coupled contactless conductivity detection. Optimal separation of this quaternary ammonium ion was achieved in BGE of pH 7.0 containing 30 mM 2-(N-morpholino)ethanesulfonic acid, 12.5 mg/mL of 2-hydroxypropyl-β-cyclodextrin and 20% v/v of acetonitrile. The separation was performed at 25°C in an uncoated fused silica capillary (50 μm id; total length, 60.5 cm; effective length, 50 cm) at 30 kV. Samples were injected hydrodynamically at 50 mbar for 6 s. For quantitative analysis, L-arginine (500 μg/mL) was used as internal standard. The calibration curve was rectilinear for 25-400 μg/mL of septonex (y=0.0113x-0.0063; r(2)=0.9992). The LOD was 7 μg/mL of septonex (at S/N=3). The run-to-run repeatability (n=6) was characterized by the RSDs of 0.18% for the migration time and 1.96% for the analyte/internal standard peak area ratio. Accuracy tested by recovery experiments at three concentration levels gave recoveries of 100.27-104.22% with RSD ≤2.19%. The method was successfully applied to the assay of carbethopendecinium bromide in eye drops. Quaternary ammonium ions having structure and size close to that of carbethopendecinium may not be resolved from the analyte. PMID:21416604

  9. Air-coupled MUMPs capacitive micromachined ultrasonic transducers with resonant cavities.

    PubMed

    Octavio Manzanares, Alberto; Montero de Espinosa, Francisco

    2012-04-01

    This work reports performance improvements of air-coupled capacitive micromachined ultrasonic transducers (CMUTs) using resonant cavities. In order to perform this work, we have designed and manufactured a CMUT employing multi-user microelectromechanical systems (MEMS) processes (MUMPs). The transducer was designed using Helmholtz resonator principles. This was characterised by the dimensions of the cavity and several acoustic ports, which had the form of holes in the CMUT plate. The MUMPs process has the advantage of being low cost which allows the manufacture of economic prototypes. In this paper we show the effects of the resonant cavities and acoustic ports in CMUTs using laser Doppler vibrometry and acoustical measurements. We also use Finite Element (FE) simulations in order to support experimental measurements. The results show that it is possible to enhance the output pressure and bandwidth in air by tuning the resonance frequency of the plate (f(p)) with that of the Helmholtz resonator (f(H)). The experimental measurements show the plate resonance along with an additional resonance in the output pressure spectrum. This appears due to the effect of the new resonant cavities in the transducer. FE simulations show an increase of 11 dB in the output pressure with respect to that of a theoretical vacuum-sealed cavity MUMPs CMUT by properly tuning the transducer. The bandwidth has been also analyzed by calculating the mechanical Q factor of the tuned CMUT. This has been estimated as 4.5 compared with 7.75 for the vacuum-sealed cavity MUMPs CMUT. PMID:22099252

  10. Trench and hole patterning with EUV resists using dual frequency capacitively coupled plasma (CCP)

    NASA Astrophysics Data System (ADS)

    Feurprier, Yannick; Lutker-Lee, Katie; Rastogi, Vinayak; Matsumoto, Hiroie; Chiba, Yuki; Metz, Andrew; Kumar, Kaushik; Beique, Genevieve; Labonte, Andre; Labelle, Cathy; Mignot, Yann; Hamieh, Bassem; Arnold, John

    2015-03-01

    Patterning at 10 nm and sub-10 nm technology nodes is one of the key challenges for the semiconductor industry. Several patterning techniques are under investigation to enable the aggressive pitch requirements demanded by the logic technologies. EUV based patterning is being considered as a serious candidate for the sub-10nm nodes. As has been widely published, a new technology like EUV has its share of challenges. One of the main concerns with EUV resists is that it tends to have a lower etch selectivity and worse LER/LWR than traditional 193nm resists. Consequently the characteristics of the dry etching process play an increasingly important role in defining the outcome of the patterning process. In this paper, we will demonstrate the role of the dual-frequency Capacitively Coupled Plasma (CCP) in the EUV patterning process with regards to improving LER/LWR, resist selectivity and CD tunability for holes and line patterns. One of the key knobs utilized here to improve LER and LWR, involves superimposing a negative DC voltage in RF plasma at one of the electrodes. The emission of ballistic electrons, in concert with the plasma chemistry, has shown to improve LER and LWR. Results from this study along with traditional plasma curing methods will be presented. In addition to this challenge, it is important to understand the parameters needed to influence CD tunability and improve resist selectivity. Data will be presented from a systematic study that shows the role of various plasma etch parameters that influence the key patterning metrics of CD, resist selectivity and LER/LWR. This work was performed by the Research Alliance Teams at various IBM Research and Development Facilities.

  11. A parallel-architecture parametric equalizer for air-coupled capacitive ultrasonic transducers.

    PubMed

    McSweeney, Sean G; Wright, William M D

    2012-01-01

    Parametric equalization is rarely applied to ultrasonic transducer systems, for which it could be used on either the transmitter or the receiver to achieve a desired response. An optimized equalizer with both bump and cut capabilities would be advantageous for ultrasonic systems in applications in which variations in the transducer performance or the properties of the propagating medium produce a less-than-desirable signal. Compensation for non-ideal transducer response could be achieved using equalization on a device-by-device basis. Additionally, calibration of ultrasonic systems in the field could be obtained by offline optimization of equalization coefficients. In this work, a parametric equalizer for ultrasonic applications has been developed using multiple bi-quadratic filter elements arranged in a novel parallel arrangement to increase the flexibility of the equalization. The equalizer was implemented on a programmable system-on-chip (PSOC) using a small number of parallel 4th-order infinite impulse response switchedcapacitor band-pass filters. Because of the interdependency of the required coefficients for the switched capacitors, particle swarm optimization (PSO) was used to determine the optimum values. The response of a through-transmission system using air-coupled capacitive ultrasonic transducers was then equalized to idealized Hamming function or brick-wall frequencydomain responses. In each case, there was excellent agreement between the equalized signals and the theoretical model, and the fidelity of the time-domain response was maintained. The bandwidth and center frequency response of the system were significantly improved. It was also shown that the equalizer could be used on either the transmitter or the receiver, and the system could compensate for the effects of transmitterreceiver misalignment. PMID:22293739

  12. Trace determination of perchlorate using electromembrane extraction and capillary electrophoresis with capacitively coupled contactless conductivity detection.

    PubMed

    Kiplagat, Isaac K; Doan, Thi Kieu Oanh; Kubáň, Pavel; Boček, Petr

    2011-11-01

    Electromembrane extraction (EME) and CE with capacitively coupled contactless conductivity detection (CE-C(4) D) was applied to rapid and sensitive determination of perchlorate in drinking water and environmental samples. Porous polypropylene hollow fiber impregnated with 1-heptanol acted as a supported liquid membrane (SLM) and perchlorate was transported and preconcentrated in the fiber lumen on application of electric field. High selectivity of perchlorate determination and its baseline separation from major inorganic anions was achieved in CE-C(4) D using background electrolyte solution consisting of 7.5 mM L-histidine and 40 mM acetic acid at pH 4.1. The analytical method showed excellent parameters in terms of reproducibility; RSD values for migration times and peak areas at a spiked concentration of 15 μg/L of perchlorate (US EPA recommended limit for drinking water) were below 0.2 and 8.7%, respectively, in all examined water samples. Linear calibration curves were obtained for perchlorate in the concentration range 1-100 μg/L (r(2) ≥0.999) with limits of detection at 1 μg/L for tap water and at 0.25-0.35 μg/L for environmental and bottled potable water samples. Recoveries at 15 μg/L of perchlorate were between 95.9 and 106.7% with minimum and maximum recovery values for snow and bottled potable water samples, respectively. PMID:22002888

  13. Reduction of pacing output coupling capacitance for sensing the evoked response.

    PubMed

    Sperzel, J; Neuzner, J; Schwarz, T; Zhu, Q; König, A; Kay, G N

    2001-09-01

    Sensing of the intracardiac evoked response (ER) after a pacing stimulus has been used in implantable pacemakers for automatic verification of capture. Reliable detection of ER is hampered by large residual afterpotentials associated with pacing stimuli. This led to the development of various technological solutions, like the use of triphasic pacing pulses and low polarizing electrode systems. This study investigated the effect of reducing the coupling capacitance (CC) in the pacemaker output circuitry on the magnitude of afterpotential, and the ability to automate detection of ventricular evoked response. A CC of 2.2 microF and four different blanking and recharge time settings were clinically tested to evaluate its impact on sensing of the ventricular ER and pacing threshold. Using an automatic step-down threshold algorithm, 54 consecutive patients, aged 70 +/- 10 years with acutely (n = 27) or chronically (n = 27) implanted ventricular pacing leads were enrolled for measurement testing. Routine measurements, using a standard pacing system analyzer (PSA), were (mean +/- SD) impedance 569 +/- 155 omega, R wave amplitude baseline to peak 9.8 +/- 3.7 mV and threshold 0.9 +/- 0.7 V at 0.4-ms pulse width. This new capture verification scheme, based on a CC of 2.2 microF and recharge/blanking timing setting of 10/12 ms, was successful in 52 patients which is equivalent to a success rate of 96%. In a subgroup of 26 patients implanted with bipolar ventricular leads (10 chronic, 16 acute), data were collected in unipolar (UP) and bipolar (BP) pace/sense configurations. Also, ER signals were recorded with two different band-pass filters: a wider band (WB) of 6-250 Hz and a conventional narrow band (NB) of 20-100 Hz. WB sensing from UP lead configuration yielded statistically significant larger signal to artifact ratios (SAR) than the other settings (P < 0.01). A dedicated unipolar ER sensing configuration using a small output capacitor and a wider band-pass filter enables

  14. Mass dependence of shear viscosity in a binary fluid mixture: mode-coupling theory.

    PubMed

    Ali, Sk Musharaf; Samanta, Alok; Choudhury, Niharendu; Ghosh, Swapan K

    2006-11-01

    An expression for the shear viscosity of a binary fluid mixture is derived using mode-coupling theory in order to study the mass dependence. The calculated results on shear viscosity for a binary isotopic Lennard-Jones fluid mixture show good agreement with results from molecular dynamics simulation carried out over a wide range of mass ratio at different composition. Also proposed is a new generalized Stokes-Einstein relation connecting the individual diffusivities to shear viscosity. PMID:17279895

  15. Numerical simulation of strongly coupled binary ionic plasmas

    SciTech Connect

    DeWitt, H.; Slattery, W.; Chabrier, G.

    1995-11-01

    New lengthy Monte Carlo simulations of the energy equation of state of binary ionic mixture fluids in a uniform background show that deviations from the linear mixing rule are small, positive, and nearly constant as a function of {Gamma}. Deviations from linear mixing for the Helmholtz free energy are positive and behave as ln{Gamma}. Quantitative results are obtained form the correction to the thermonuclear reaction rate.

  16. Interface and permittivity simultaneous reconstruction in electrical capacitance tomography based on boundary and finite-elements coupling method.

    PubMed

    Ren, Shangjie; Dong, Feng

    2016-06-28

    Electrical capacitance tomography (ECT) is a non-destructive detection technique for imaging the permittivity distributions inside an observed domain from the capacitances measurements on its boundary. Owing to its advantages of non-contact, non-radiation, high speed and low cost, ECT is promising in the measurements of many industrial or biological processes. However, in the practical industrial or biological systems, a deposit is normally seen in the inner wall of its pipe or vessel. As the actual region of interest (ROI) of ECT is surrounded by the deposit layer, the capacitance measurements become weakly sensitive to the permittivity perturbation occurring at the ROI. When there is a major permittivity difference between the deposit and the ROI, this kind of shielding effect is significant, and the permittivity reconstruction becomes challenging. To deal with the issue, an interface and permittivity simultaneous reconstruction approach is proposed. Both the permittivity at the ROI and the geometry of the deposit layer are recovered using the block coordinate descent method. The boundary and finite-elements coupling method is employed to improve the computational efficiency. The performance of the proposed method is evaluated with the simulation tests. This article is part of the themed issue 'Supersensing through industrial process tomography'. PMID:27185960

  17. The discharge mode transition and O(5p1) production mechanism of pulsed radio frequency capacitively coupled plasma

    NASA Astrophysics Data System (ADS)

    Liu, X. Y.; Hu, J. T.; Liu, J. H.; Xiong, Z. L.; Liu, D. W.; Lu, X. P.; Shi, J. J.

    2012-07-01

    The discharge mode transition from uniform plasma across the gas gap to the α mode happens at the rising phase of the pulsed radio frequency capacitively coupled plasma (PRF CCP). This transition is attributed to the fast increasing stochastic heating at the edge of sheath. In the second stage with the stable current and voltage amplitude, the consistency between experimental and numerical spatial-temporal 777 nm emission profile suggests that He* and He2* dominate the production of O(5p1) through dissociation and excitation of O2. Finally, the sterilization efficiency of PRF CCP is found to be higher than that of plasma jet.

  18. Quantum fluctuations of mesoscopic damped double resonance RLC circuit with mutual capacitance inductance coupling in thermal excitation state

    NASA Astrophysics Data System (ADS)

    Xu, Xing-Lei; Li, Hong-Qi; Wang, Ji-Suo

    2007-08-01

    Based on the scheme of damped harmonic oscillator quantization and thermo-field dynamics (TFD), the quantization of mesoscopic damped double resonance RLC circuit with mutual capacitance-inductance coupling is proposed. The quantum fluctuations of charge and current of each loop in a squeezed vacuum state are studied in the thermal excitation case. It is shown that the fluctuations not only depend on circuit inherent parameters, but also rely on excitation quantum number and squeezing parameter. Moreover, due to the finite environmental temperature and damped resistance, the fluctuations increase with the temperature rising, and decay with time.

  19. Capacitively coupled resistivity survey of the levee surrounding the Omaha Public Power District Nebraska City Power Plant, June 2011

    USGS Publications Warehouse

    Burton, Bethany L.; Cannia, James C.

    2011-01-01

    This report is a release of digital data from a capacitively coupled resistivity survey conducted on June 13, 2011, on the flood-protection levees surrounding the Omaha Public Power District Nebraska City power plant. The U.S. Geological Survey Crustal Geophysics and Geochemistry Science Center and the Nebraska Water Science Center performed the survey in response to a flood on the Missouri River. A single line of resistivity profiling was completed along the center line of the section of levee 573 that surrounds the power plant.

  20. On the scaling of rf and dc self-bias voltages with pressure in electronegative capacitively coupled plasmas

    SciTech Connect

    Agarwal, Ankur; Dorf, Leonid; Rauf, Shahid; Collins, Ken

    2012-03-15

    Higher gas densities and lower diffusion losses at higher operating pressures typically lead to increased charged species densities (and hence flux) for a constant power deposition in capacitively coupled plasmas (CCP). As a result, one would expect that the bias radio-frequency (rf) voltage required to deposit a given power in a CCP reactor decreases with increasing operating pressure. These observations may not hold true in multiple frequency CCPs, commonly used for dielectric etching in microelectronics fabrication, due to nonlinear interactions between the rf sources. Wafer-based measurements of the rf and self-generated direct current (dc) bias voltages in a dual-frequency capacitively coupled electronegative plasma were made, which indicate that the rf and dc voltages vary nonmonotonically with pressure. These experimental results are presented in this paper and a computational plasma model is used to explain the experimental observations for varying 60 MHz and 13 MHz powers in the Ar/CF{sub 4}/CHF{sub 3} plasma over a pressure range of 25 to 400 mTorr. The authors found that while the ion density increases with pressure, the increase is most dominant near the electrode with the high frequency source (60 MHz). The rf and dc bias voltages are ultimately influenced by both charged species density magnitudes and spatial profiles.

  1. Numerical investigation on fundamental properties in capacitively-coupled methane plasmas for deposition of diamond-like carbon films

    NASA Astrophysics Data System (ADS)

    Oda, Akinori; Kousaka, Hiroyuki

    2012-10-01

    Capacitively-coupled methane (CH4) plasmas for deposition of diamond-like carbon films have been simulated using a self-consistent one-dimensional fluid model, incorporating the mass balance equations for electrons, ions, radicals and non-radicals, the electron energy balance equation, coupled with the Poisson equation. Despite of low-pressure CH4 gas condition, many positive-ion species, such as C2H4^+, CH4^+, C2H2^+, CH5^+ etc., have been found in the plasmas. The non-radical neutrals, such as C2H4, C3H8, C2H2 and C2H6, have also found with higher densities comparable to the source gas density. This result indicates that this complexity of background gas in CH4 plasmas is strongly affected to the electron energy distribution function, which is important for the determination of plasmas properties.

  2. Beyond the Binary: Trans-Negotiations in Couple and Family Therapy.

    PubMed

    Giammattei, Shawn V

    2015-09-01

    Dualistic notions about gender and sexuality have permeated the field of couple and family therapy. These binary constructions have been limiting for everyone, especially those who fall outside the male/female dichotomy. This article examines the impact of these binary notions, especially on transgender and gender-creative individuals, couples, and families. Current theory and research in the field as they relate to gender identity, sexuality, and gender minority stress in couples and families are presented. Case examples are used to illustrate affirmative approaches to treatment issues such as coming out, safety, grief and loss, redefining relationships, and social/medical transitions that may arise for transgender or gender nonconforming (TGNC) individuals, couples, and families. PMID:26250935

  3. Disc-jet-wind coupling in black hole binaries, and other stories

    NASA Astrophysics Data System (ADS)

    Fender, R.

    2016-05-01

    In this article, I briefly review our current understanding of the phenomenological connections between accretion flows, jets and winds in black hole binaries. I further highlight a couple of topical and important areas which need the attention of the community and should lead to interesting astrophysics.

  4. Experimental Observation and Computational Analysis of Striations in Electronegative Capacitively Coupled Radio-Frequency Plasmas

    NASA Astrophysics Data System (ADS)

    Liu, Yong-Xin; Schüngel, Edmund; Korolov, Ihor; Donkó, Zoltán; Wang, You-Nian; Schulze, Julian

    2016-06-01

    Self-organized spatial structures in the light emission from the ion-ion capacitive rf plasma of a strongly electronegative gas (CF4 ) are observed experimentally for the first time. Their formation is analyzed and understood based on particle-based kinetic simulations. These "striations" are found to be generated by the resonance between the driving radio frequency and the eigenfrequency of the ion-ion plasma (derived from an analytical model) that establishes a modulation of the electric field, the ion densities, as well as the energy gain and loss processes of electrons in the plasma. The growth of the instability is followed by the numerical simulations.

  5. Countersuperflow in Binary Bose-Einstein Condensates with Rabi Coupling

    NASA Astrophysics Data System (ADS)

    Takeuchi, Hiromitsu; Usui, Ayaka

    2014-05-01

    Countersuperflow instability, dynamic instability of counterflow of miscible superfluids, was observed recently for the first time by Hamner et al.. In the experiment, a countersuperflow of miscible two-component Bose-Einstein condensates (BECs) was realized in a quasi-one-dimensional trap by applying a magnetic gradient, which leads to a force in opposite directions for each component. A countersuperflow becomes dynamically unstable if the relative velocity between two superfluids exceeds a critical value and the instability causes characteristic density patterns forming solitons in quasi-one-dimensional systems. Very recently, Hamner et al. performed the experiment in a similar situation where a two-component BEC is subject to inhomogeneous Rabi oscillations between two pseudospin components under a magnetic gradient. Motivated by the experiment, we investigated stability of countersuperflow with internal Josephson coupling, namely, Rabi coupling. We reveal the stability phase diagram of countersuperflow with Rabi coupling. This work was supported by JSPS KAKENHI Grant Numbers 25887042, 26870500 and the MEXT KAKENHI (No. 22103003).

  6. Phase-shift effect in capacitively coupled plasmas with two radio frequency or very high frequency sources

    SciTech Connect

    Xu Xiang; Zhao Shuxia; Zhang Yuru; Wang Younian

    2010-08-15

    A two-dimensional fluid model was built to study the argon discharge in a capacitively coupled plasma reactor and the full set of Maxwell equations is included in the model to understand the electromagnetic effect in the capacitive discharge. Two electrical sources are applied to the top and bottom electrodes in our simulations and the phase-shift effect is focused on. We distinguish the difference of the phase-shift effect on the plasma uniformity in the traditional radio frequency discharge and in the very high frequency discharge where the standing wave effect dominates. It is found that in the discharges with frequency 13.56 MHz, the control of phase difference can less the influence of the electrostatic edge effect, and it gets the best radial uniformity of plasma density at the phase difference {pi}. But in the very high frequency discharges, the standing wave effect plays an important role. The standing wave effect can be counteracted at the phase difference 0, and be enhanced at the phase difference {pi}. The standing wave effect and the edge effect are balanced at some phase-shift value between 0 and {pi}, which is determined by discharge parameters.

  7. Capacitive deionization coupled with microbial fuel cells to desalinate low-concentration salt water.

    PubMed

    Yuan, Lulu; Yang, Xufei; Liang, Peng; Wang, Lei; Huang, Zheng-Hong; Wei, Jincheng; Huang, Xia

    2012-04-01

    A new technology (CDI-MFC) that combined capacitive deionization (CDI) and microbial fuel cell (MFC) was developed to treat low-concentration salt water with NaCl concentration of 60mg/L. The water desalination rate was 35.6mg/(Lh), meanwhile the charge efficiency was 21.8%. Two desorption modes were investigated: discharging (DC) mode and short circuit (SC) mode. The desalination rate in the DC mode was 200.6±3.1mg/(Lh), 47.8% higher than that in the SC mode [135.7±15.3mg/(Lh)]. The average current in the DC mode was also much higher than that of the SC mode. The energy stored in the CDI cell has been reused to enhance the electron production of MFC by the discharging desorption mode (DC mode), which offers an approach to recover the electrostatic energy in the CDI cell. PMID:22364771

  8. Enhancing capacitive deionization performance of electrospun activated carbon nanofibers by coupling with carbon nanotubes.

    PubMed

    Dong, Qiang; Wang, Gang; Wu, Tingting; Peng, Senpei; Qiu, Jieshan

    2015-05-15

    Capacitive deionization (CDI) is an alternative, effective and environmentally friendly technology for desalination of brackish water. The performance of the CDI device is highly determined by the electrode materials. In this paper, a composite of carbon nanotubes (CNTs) embedded in activated carbon nanofiber (ACF) was prepared by a direct co-electrospinning way and subsequent CO2 activation. The introduction of CNTs can greatly improve the conductivity while the CO2-mediated activation can render the final product with high porosity. As such, the hybrid structure can provide an excellent storage space and pathways for ion adsorption and conduction. When evaluated as electrode materials for CDI, the as-prepared CNT/ACF composites with higher electrical conductivity and mesopore ratios exhibited higher electrosorption capacity and good regeneration performance in comparison with the pure ACF. PMID:25595622

  9. Detection of viable Salmonella using microelectrode-based capacitance measurement coupled with immunomagnetic separation.

    PubMed

    Yang, Liju; Li, Yanbin

    2006-01-01

    In this study, we demonstrated the use of a general medium--brain heart infusion (BHI) broth that is not specifically formulated for impedance measurement, to achieve detectable impedance signals by using an interdigitated microelectrode (IME) with capacitance measurement at low frequencies. Anti-Salmonella antibody coated immunomagnetic beads were used to separate S. typhimurium from samples to provide the selectivity to this method. From analysis based on the equivalent circuit of the IME system, we found that the impedance change in BHI broth resulting from the growth of Salmonella was indeed the change in the double layer capacitance and could be monitored at 10 Hz using the IME. The results indicated that medium modification to improve impedance signal is not necessary with this IME system. However, effective immunological separation for the target organism is required for the selectivity when non-selective media are used. This finding provides a more flexible option of medium in impedance methods, which may provide opportunities to test those species of bacteria that have no suitable conductance growth medium. The detection time, t(d), was obtained from the impedance growth curve (impedance against bacterial growth time) at 10 Hz at the point where the impedance started to change. A linear relationship between the detection time and the logarithmic value of the initial cell number (N) was found in the Salmonella cell number ranging from 10(1) to 10(6) cfu/ml. The regression equation was t(d) = -1.22Log N + 8.90, with R2 = 0.95. The detection times for the initial cell number of 10(1) CFU/ml and 10(6) CFU/ml are 8 h and 1.5 h, respectively. This method is more sensitive than impedance methods using conventional electrodes. PMID:15936099

  10. Simulation of Main Plasma Parameters of a Cylindrical Asymmetric Capacitively Coupled Plasma Micro-Thruster using Computational Fluid Dynamics

    NASA Astrophysics Data System (ADS)

    Greig, Amelia; Charles, Christine; Boswell, Roderick

    Computational fluid dynamics (CFD) simulations of a radio-frequency (13.56 MHz) electro-thermal capacitively coupled plasma (CCP) micro-thruster have been performed using the commercial CFD-ACE+ package. Standard operating conditions of a 10 W, 1.5 Torr argon discharge were used to compare with previously obtained experimental results for validation. Results show that the driving force behind plasma production within the thruster is ion-induced secondary electrons ejected from the surface of the discharge tube, accelerated through the sheath to electron temperatures up to 33.5 eV. The secondary electron coefficient was varied to determine the effect on the discharge, with results showing that full breakdown of the discharge did not occur for coefficients coefficients less than or equal to 0.01.

  11. High frequency capacitively coupled RF plasma discharge effects on the order/disorder structure of PAN-based carbon fiber

    NASA Astrophysics Data System (ADS)

    Güngör, Ümmugül E.; Bilikmen, Sinan; Akbar, Demiral

    2014-05-01

    High-resolution confocal Raman microscopy was used to investigate the effects of nitrogen plasma on unsized high strength (HS) PAN-based carbon fiber surfaces. The fibers were treated by a high frequency (40.68 MHz) capacitively coupled single RF-PECVD reactor under different processing conditions (exposure times, RF powers and gas pressures). It was found that the order/disorder structure of the treated carbon fiber changed with different processing conditions. At low pressures, the degree of disordered structure increased with HF-RF power and process time. However, at high pressures, high-order structure () was observed and almost no observable structural effects appeared at long treatment time. Also, the first-order Raman-band peaks (D and G) of the treated carbon fibers shifted. And, FWHM (), intensity () and D-band relative integrated intensity () ratios increased with ordering whereas they decreased with disordering.

  12. Fabrication and application of a wireless inductance-capacitance coupling microsensor with electroplated high permeability material NiFe

    NASA Astrophysics Data System (ADS)

    Chen, Y. H.; Chang, H. C.; Lai, C. C.; Chang, I. N.

    2011-01-01

    A fully integrated wireless inductance-capacitance (LC) coupling microsensor was designed and fabricated by MEMS technology. The sensing loop was formed by connecting a deformable parallel-plated capacitor and a planar spiral inductor with a Ni(80)Fe(20) core. Polyimide and PMMA were used to isolate and package the devices. Typical dimension of the sensors was 5 × 5 mm2 × 0.77 mm. Different electroplated inductive coils (30, 40, and 60 turns) were fabricated to connect with a 4 × 4 mm2 plate capacitor in series. The LC sensing module for measuring liquid-level induced frequency responses was setup. Experimental results show that frequency response decreased as liquid level increased and sensitivity is about 7.01 kHz/cm with deviation less than 2%. Developed planar spiral inductor with high permeability magnetic core can provide a wide range of frequency variation in LC sensing applications.

  13. One-dimensional hybrid simulation of the dc/RF combined driven capacitively coupled CF{sub 4} plasmas

    SciTech Connect

    Wang Shuai; Xu Xiang; Wang Younian

    2012-11-15

    We developed a one-dimensional hybrid model to simulate the dc/RF combined driven capacitively coupled plasma for CF{sub 4} discharges. The numerical results show the influence of the dc source on the plasma density distribution, ion energy distributions (IEDs), and ion angle distributions (IADs) on both RF and dc electrodes. The increase of dc voltage impels more ions with high energy to the electrode applied to the dc source, which makes the IEDs at the dc electrode shift toward higher energy and the peaks in IADs shift toward the small angle region. At the same time, it also decreases ion-energy at the RF electrode and enlarges the ion-angles which strike the RF electrode.

  14. Separation and determination of degradation products of acid orange 7 by capillary electrophoresis/capacitively coupled contactless conductivity detector.

    PubMed

    Wang, Xin; Xiong, Ya; Xie, Tianyao; Sharma, Virender K; Tu, Yuting; Yang, Jiannan; Tian, Shuanghong; He, Chun

    2013-07-15

    Capillary electrophoresis (CE) with capacitively coupled contactless conductivity detector (C(4)D) was developed to separate azo-dyestuff acid orange 7 (AO7) and its six degradation products. The analyzed products were sulfamic acid, oxalic acid, benzenesulfonic acid, 4-hydroxybenzene sulfonic acid, phthalic acid, and 4-aminobenzene sulfonic acid. In developing the method, types and concentrations of running buffers, injecting voltage and time, and applied voltage were tested to obtain optimum conditions to analyze target compounds. The separation was successfully achieved within 10 min using a fused-silica capillary under the following conditions: 20 mmol L(-1) acetate acid buffer, electrokinetic injection of -12 kV × 10 s, and applied voltage of -13 kV. The developed method was applied to analyze degradation products in situ during the reaction of AO7 with Fenton reagent (Fe(II)+H2O2 at pH 4.0). PMID:23622525

  15. Kinetic interpretation of resonance phenomena in low pressure capacitively coupled radio frequency plasmas

    NASA Astrophysics Data System (ADS)

    Wilczek, Sebastian; Trieschmann, Jan; Eremin, Denis; Brinkmann, Ralf Peter; Schulze, Julian; Schuengel, Edmund; Derzsi, Aranka; Korolov, Ihor; Hartmann, Peter; Donkó, Zoltán; Mussenbrock, Thomas

    2016-06-01

    Low pressure capacitive radio frequency (RF) plasmas are often described by equivalent circuit models based on fluid approaches that predict the self-excitation of resonances, e.g., high frequency oscillations of the total current in asymmetric discharges, but do not provide a kinetic interpretation of these effects. In fact, they leave important questions open: How is current continuity ensured in the presence of energetic electron beams generated by the expanding sheaths that lead to a local enhancement of the conduction current propagating through the bulk? How do the beam electrons interact with cold bulk electrons? What is the kinetic origin of resonance phenomena? Based on kinetic simulations, we find that the energetic beam electrons interact with cold bulk electrons (modulated on a timescale of the inverse local electron plasma frequency) via a time dependent electric field outside the sheaths. This electric field is caused by the electron beam itself, which leaves behind a positive space charge, that attracts cold bulk electrons towards the expanding sheath. The resulting displacement current ensures current continuity by locally compensating the enhancement of the conduction current. The backflow of cold electrons and their interaction with the nonlinear plasma sheath cause the generation of multiple electron beams during one phase of sheath expansion and contribute to a strongly non-sinusoidal RF current. These kinetic mechanisms are the basis for a fundamental understanding of the electron power absorption dynamics and resonance phenomena in such plasmas, which are found to occur in discharges of different symmetries including perfectly symmetric plasmas.

  16. Treatment of denervation/disuse osteoporosis in the rat with a capacitively coupled electrical signal: effects on bone formation and bone resorption.

    PubMed

    Brighton, C T; Tadduni, G T; Goll, S R; Pollack, S R

    1988-01-01

    Utilizing a sciatic neurectomy model of disuse osteoporosis, the effects on rates of bone formation and bone resorption were examined when a capacitively coupled electrical signal was applied to the denervated tibia in the rat. It was found that a low-voltage, symmetrical sine wave, 60-kHz, capacitively coupled signal had no significant effect on the amount of bone resorption occurring in denervated right tibiae in rats previously labeled with [3H]tetracycline. This was true whether the signal was applied while osteoporosis was developing (prevention of osteoporosis) or after it had been established (treatment of osteoporosis). If a similar capacitively coupled signal was applied to rats in which osteoporosis was well established, and the rats were labeled with [3H]tetracycline daily during a 12-day treatment period, it was found that there was statistically significant enhancement of the amount of new bone formation (increased [3H]tetracycline incorporation) in the tibiae that received the signal as compared with that of the controls. These results indicate that prevention or amelioration of disuse osteoporosis that occurs with a capacitively coupled electrical signal is due not to a change in the rate of bone resorption, but to an increase in the rate of bone formation. PMID:3261339

  17. Current response for a single redox moiety trapped in a closed generator-collector system: the role of capacitive coupling.

    PubMed

    Feldberg, Stephen W; Edwards, Martin A

    2015-04-01

    A theoretical model is proposed to describe the steady-state average limiting current associated with a single redox moiety (ox or red) trapped in a closed generator-collector system along with excess supporting electrolyte. By "closed" we mean that neither solvent nor solutes can enter or leave the system. The potential difference, EOE - ERE, between the oxidizing electrode (OE) and the reducing electrode (RE) is maintained constant with the values of EOE and ERE chosen so that the operative faradaic electrode processes are very fast, i.e., red = ox + nETe(-) (kox = ∞) at the OE and ox + nETe(-) = red (kred = ∞) at the RE. Because there is only a single redox moiety the faradaic process occurs at only one electrode at a time while current at the other electrode is purely capacitive (we refer to this as capacitive coupling). We propose that a two-step process is required to transfer nETqe coulombs (qe is the absolute value of the elemental electronic charge). The first step is associated with diffusion (approximated as a random walk) of a single red moiety to the OE where it is oxidized to ox with a concomitant transfer of qstep1 (= nETqe/(1 + AOECOE/ARECRE)) coulombs; the second step is associated with the diffusion (random walk) of the newly formed single ox moiety to the RE with the concomitant transfer of qstep2 (= nETqe/(1 + ARECRE/AOECOE)) coulombs (ARE,AOE andCRE,COEare the areas (cm(2)) and differential capacitances (farads cm(-2)) of the corresponding electrodes). The total charge transferred in the two steps is nETqe(= qstep1 + qstep2). Transport of the redox moiety from one electrode to the other is accomplished by a random walk. The probability density function (pdf) and cumulative density function (CDF) for the duration of a full redox cycle are presented as the analytical solution to a 1-dimensional bounded random-walk problem (confirmed by numerical simulation). These show that tfull, the average time for the full redox cycle (step 1 + step 2

  18. Transition to miscibility in linearly coupled binary dipolar Bose-Einstein condensates

    NASA Astrophysics Data System (ADS)

    Gligorić, Goran; Maluckov, Aleksandra; Stepić, Milutin; Hadžievski, Ljupčo; Malomed, Boris A.

    2010-09-01

    We investigate the effects of dipole-dipole (DD) interactions on immiscibility-miscibility transitions (IMT’s) in two-component Bose-Einstein condensates (BEC’s) trapped in the harmonic-oscillator (HO) potential, with the components linearly coupled by a resonant electromagnetic field (accordingly, the components represent two different spin states of the same atom). The problem is studied by means of direct numerical simulations. Different mutual orientations of the dipolar moments in the two components are considered. It is shown that, in the binary BEC formed by dipoles with the same orientation and equal magnitudes, the IMT cannot be induced by the DD interaction alone, being possible only in the presence of the linear coupling between the components, while the miscibility threshold is affected by the DD interactions. However, in the binary condensate with the two dipolar components polarized in opposite directions, the IMT can be induced without any linear coupling. Further, we demonstrate that those miscible and immiscible localized states, formed in the presence of the DD interactions, which are unstable evolve into robust breathers, which tend to keep the original miscibility or immiscibility, respectively. An exception is the case of a very strong DD attraction, when narrow stationary modes are destroyed by the instability. The binary BEC composed of copolarized dipoles with different magnitudes are briefly considered as well.

  19. Transition to miscibility in linearly coupled binary dipolar Bose-Einstein condensates

    SciTech Connect

    Gligoric, Goran; Stepic, Milutin; Hadzievski, Ljupco; Maluckov, Aleksandra; Malomed, Boris A.

    2010-09-15

    We investigate the effects of dipole-dipole (DD) interactions on immiscibility-miscibility transitions (IMT's) in two-component Bose-Einstein condensates (BEC's) trapped in the harmonic-oscillator (HO) potential, with the components linearly coupled by a resonant electromagnetic field (accordingly, the components represent two different spin states of the same atom). The problem is studied by means of direct numerical simulations. Different mutual orientations of the dipolar moments in the two components are considered. It is shown that, in the binary BEC formed by dipoles with the same orientation and equal magnitudes, the IMT cannot be induced by the DD interaction alone, being possible only in the presence of the linear coupling between the components, while the miscibility threshold is affected by the DD interactions. However, in the binary condensate with the two dipolar components polarized in opposite directions, the IMT can be induced without any linear coupling. Further, we demonstrate that those miscible and immiscible localized states, formed in the presence of the DD interactions, which are unstable evolve into robust breathers, which tend to keep the original miscibility or immiscibility, respectively. An exception is the case of a very strong DD attraction, when narrow stationary modes are destroyed by the instability. The binary BEC composed of copolarized dipoles with different magnitudes are briefly considered as well.

  20. Ternary and coupled binary zinc tin oxide nanopowders: Synthesis, characterization, and potential application in photocatalytic processes

    SciTech Connect

    Ivetić, T.B.; Finčur, N.L.; Đačanin, Lj. R.; Abramović, B.F.; Lukić-Petrović, S.R.

    2015-02-15

    Highlights: • Mechanochemically synthesized nanocrystalline zinc tin oxide (ZTO) powders. • Photocatalytic degradation of alprazolam in the presence of ZTO water suspensions. • Coupled binary ZTO exhibits enhanced photocatalytic activity compared to ternary ZTO. - Abstract: In this paper, ternary and coupled binary zinc tin oxide nanocrystalline powders were prepared via simple solid-state mechanochemical method. X-ray diffraction, scanning electron microscopy, Raman and reflectance spectroscopy were used to study the structure and optical properties of the obtained powder samples. The thermal behavior of zinc tin oxide system was examined through simultaneous thermogravimetric-differential scanning calorimetric analysis. The efficiencies of ternary (Zn{sub 2}SnO{sub 4} and ZnSnO{sub 3}) and coupled binary (ZnO/SnO{sub 2}) zinc tin oxide water suspensions in the photocatalytic degradation of alprazolam, short-acting anxiolytic of the benzodiazepine class of psychoactive drugs, under UV irradiation were determined and compared with the efficiency of pure ZnO and SnO{sub 2}.

  1. Electron heating and the Electrical Asymmetry Effect in capacitively coupled RF discharges

    NASA Astrophysics Data System (ADS)

    Schulze, Julian

    2011-10-01

    For applications of capacitive radio frequency discharges, the control of particle distribution functions at the substrate surface is essential. Their spatio-temporal shape is the result of complex heating mechanisms of the respective species. Enhanced process control, therefore, requires a detailed understanding of the heating dynamics. There are two known modes of discharge operation: α- and γ-mode. In α-mode, most ionization is caused by electron beams generated by the expanding sheaths and field reversals during sheath collapse, while in γ-mode secondary electrons dominate the ionisation. In strongly electronegative discharges, a third heating mode is observed. Due to the low electron density in the discharge center the bulk conductivity is reduced and a high electric field is generated to drive the RF current through the discharge center. In this field, electrons are accelerated and cause significant ionisation in the bulk. This bulk heating mode is observed experimentally and by PIC simulations in CF4 discharges. The electron dynamics and mode transitions as a function of driving voltage and pressure are discussed. Based on a detailed understanding of the heating dynamics, the concept of separate control of the ion mean energy and flux in classical dual-frequency discharges is demonstrated to fail under process relevant conditions. To overcome these limitations of process control, the Electrical Asymmetry Effect (EAE) is proposed in discharges driven at multiple consecutive harmonics with adjustable phase shifts between the driving frequencies. Its concept and a recipe to optimize the driving voltage waveform are introduced. The functionality of the EAE in different gases and first applications to large area solar cell manufacturing are discussed. Finally, limitations caused by the bulk heating in strongly electronegative discharges are outlined.

  2. A capillary electrophoresis system with dual capacitively coupled contactless conductivity detection and electrospray ionization tandem mass spectrometry.

    PubMed

    Francisco, Kelliton José Mendonça; do Lago, Claudimir Lucio

    2016-07-01

    A commercial system that is comprised of a CE coupled to an ESI triple quadrupole mass spectrometer was equipped with two capacitively coupled contactless conductivity detectors (C(4) Ds). The first C(4) D was positioned inside the original cartridge, and the second C(4) D was positioned as close as possible to the ESI probe entrance by using a 3D-printed support. The C(4) Ds electropherograms were matched to the ESI-MS electropherogram by correcting their timescales by the factor LT /LD , where LT and LD are the total capillary length and the length until the C(4) D, respectively. A general approach for method development supporting the simultaneous conductivity and MS detection is discussed, while application examples are introduced. These examples include the use of C(4) D as a simple device that dismiss the use of an EOF marker, a low-selectivity detector that continuously provide information about unexpected features of the sample, and even a detector that can be more sensitive than ESI-MS. The C(4) D used in this setup proved to have a smaller contribution to the peak broadening than ESI-MS, which allowed that a C(4) D, positioned at 12 cm from the inlet of an 80-cm-long capillary, could be used to foresee position and shape of the peaks being formed 6.8 times slower at the ESI-MS electropherogram. PMID:27027468

  3. Quantum phase transition and Coulomb blockade effect in triangular quantum dots with interdot capacitive and tunnel couplings

    NASA Astrophysics Data System (ADS)

    Xiong, Yong-Chen; Wang, Wei-Zhong; Yang, Jun-Tao; Huang, Hai-Ming

    2015-02-01

    The quantum phase transition and the electronic transport in a triangular quantum dot system are investigated using the numerical renormalization group method. We concentrate on the interplay between the interdot capacitive coupling V and the interdot tunnel coupling t. For small t, three dots form a local spin doublet. As t increases, due to the competition between V and t, there exist two first-order transitions with phase sequence spin-doublet-magnetic frustration phase-orbital spin singlet. When t is absent, the evolutions of the total charge on the dots and the linear conductance are of the typical Coulomb-blockade features with increasing gate voltage. While for sufficient t, the antiferromagnetic spin correlation between dots is enhanced, and the conductance is strongly suppressed for the bonding state is almost doubly occupied. Project supported by the National Natural Science Foundation of China (Grant Nos. 10874132 and 11174228) and the Doctoral Scientific Research Foundation of HUAT (Grant No. BK201407). One of the authors (Huang Hai-Ming) supported by the Scientific Research Items Foundation of Educational Committee of Hubei Province, China (Grant No. Q20131805).

  4. New observations and new models of spin-orbit coupling in binary asteroids

    NASA Astrophysics Data System (ADS)

    Margot, Jean-Luc; Naidu, Shantanu

    2015-08-01

    The YORP-induced rotational fission hypothesis is the leading candidate for explaining the formation of binaries, triples, and pairs among small (<20 km) asteroids (e.g., Margot et al, Asteroids IV, subm., 2015). Various evolutionary paths following rotational fission have been suggested, but many important questions remain about the evolutionary mechanisms and timescales. We test hypotheses about the evolution of binary asteroids by obtaining precise descriptions of the orbits and components of binary systems with radar and by examining the system dynamics with detailed numerical simulations. Predictions for component spin states and orbital precession rates can then be compared to observables in our data sets or in other data sets to elucidate the states of various systems and their likely evolutionary paths.Accurate simulations require knowledge of the masses, shapes, and spin states of individual binary components. Because radar observations can provide exquisite data sets spanning days with spatial resolutions at the decameter level, we can invert for the component shapes and measure spin states. We can also solve for the mutual orbit by fitting the observed separations between components. In addition, the superb (10e-7--10e-8) fractional uncertainties in range allow us to measure the reflex motions directly, allowing masses of individual components to be determined.We use recently published observations of the binary 2000 DP107 (Naidu et al. AJ, subm., 2015) and that of other systems to simulate the dynamics of components in well-characterized binary systems (Naidu and Margot, AJ 149, 80, 2015). We model the coupled spin and orbital motions of two rigid, ellipsoidal bodies under the influence of their mutual gravitational potential. We use surface of section plots to map the possible spin configurations of the satellites. For asynchronous satellites, the analysis reveals large regions of phase space where the spin state of the satellite is chaotic. The

  5. Classical Spin-Orbit Coupling and Periastron Advance in a Binary Pulsar

    NASA Technical Reports Server (NTRS)

    Kaspi, V. M.; Bailes, M.; Manchester, R. N.; Stappers, B. W.; Bell, J. F.

    1996-01-01

    We report on radio timing observations of PSR J0045-7319, and eccentric pulsar/B star 51-day binary in the Small Magellanic Cloud. Significant deviations from a simple Keplerian orbit, observed as precessions of the periastron longitude and orbital plane, are identified with classical spin-orbit coupling and apsidal advance, for the fist time in a binary pulsar. Both precessions result from the B star's rotationally-induced gravitational quadropole moment, however, the orbital plane precession requires the B star's spin axis to be inclined with respect to the orbital angular momentum. We constrain this inclination angle (theta) to be 25(deg) <(theta)<41(deg). Under the conventional assumption that the pre-supernova angular momenta were aligned, our observations provide the most direct evidence yet for an asymmetric supernova.

  6. A Polarization Reconfigurable Aperture-Coupled Microstrip Antenna and Its Binary Array for MIMO

    NASA Astrophysics Data System (ADS)

    Zhong, Lei; Hong, Jin-Song; Zhou, Hong-Cheng

    2016-03-01

    In the paper, a singly fed circular patch antenna with polarization diversity is proposed, and its binary array for MIMO application is explored as well. The air substrate and aperture-coupled feed structure are adopted to increase bandwidth and simplify the bias circuit of PIN diodes. By controlling the states of four PIN diodes on the patch, the proposed antenna can produce linear polarization (LP), left- or right-hand circular polarization (LHCP or RHCP). For each polarization sense, the antenna exhibits wide impedance bandwidth, high gain and low cross-polarization. Two antennas are orthogonally placed to form a binary array for MIMO application, which has high isolation and low envelope correlation. The antenna and its array have advantages of simple biasing network, easy fabrication and adjustment, which can be widely applied in wireless communication systems.

  7. Experimental and theoretical study of RF capacitively coupled plasma in Ar-CF4-CF3I mixtures

    NASA Astrophysics Data System (ADS)

    Proshina, O. V.; Rakhimova, T. V.; Lopaev, D. V.; Šamara, V.; Baklanov, M. R.; de Marneffe, J.-F.

    2015-10-01

    Radio frequency capacitively coupled plasma (RF CCP) sustained at RF frequencies of 27 MHz in an Ar-CF4-CF3I gas mixture is studied experimentally and theoretically. The RF CCP in Ar-CF4-CF3I is simulated by using a 1D hybrid particle-in-cell-fluid numerical model. We pay special attention to the changes in plasma structure and fluxes to the electrode, negative ion and neutral radical production with admixture of CF3I in Ar-CF4 plasma. With CF3I admixture the plasma becomes strongly electronegative as a result of the high electron attachment rate to the CF3I molecule. The atomic fluorine density becomes extremely low with addition of CF3I molecules due to the large volume loss in the reaction CF3I + F  →  CF3 + IF. Optical emission spectrometry data on CF2 emission at the wavelength of 250 nm indicate the essential sources of CF2 in CF3I-containing plasma in the studied conditions, although direct dissociation channels for the CF3I molecule with CF2 production have not been studied. Evaluation of CF2 density in Ar-CF4-CF3I plasma was first carried out on the basis of the actinometry technique and numerical simulation. The possible mechanism of ultra-low-k film damage in the studied conditions is also discussed.

  8. Influence of surface conditions on plasma dynamics and electron heating in a radio-frequency driven capacitively coupled oxygen plasma

    NASA Astrophysics Data System (ADS)

    Greb, Arthur; Gibson, Andrew Robert; Niemi, Kari; O'Connell, Deborah; Gans, Timo

    2015-08-01

    The impact of changing surface condition on plasma dynamics and electron heating is investigated by means of numerical simulations, based on a semi-kinetic fluid model approach, and compared with measurements of the nanosecond electron dynamics in the plasma-surface interface region using phase resolved optical emission spectroscopy (PROES). The simulations are conducted in a one-dimensional domain and account for a geometrical asymmetry comparable to the experimental setup of a radio-frequency driven capacitively coupled plasma in a gaseous electronics conference reference cell. A simple reaction scheme is considered, including electrons, \\text{O}2+ positive ions, {{\\text{O}}-} negative ions and {{\\text{O}}2}{≤ft(1Δ\\right)} metastable singlet delta oxygen (SDO) as individual species. The role of surface loss and effective lifetime of SDO is discussed. To simulate different surface conditions, the SDO surface loss probability and the secondary electron emission coefficient were varied in the model. It is found that a change in surface condition significantly influences the metastable concentration, electronegativity, spatial particle distributions and densities as well as the ionization and electron heating dynamics. The excitation dynamics obtained from simulations are compared with PROES measurements. This allows to determine experimentally relevant SDO surface loss probabilities and secondary electron emission coefficient values in-situ and is demonstrated for two different surface materials, namely aluminum and Teflon.

  9. Separate control of ion flux and energy in capacitively coupled RF discharges via the Electrical Asymmetry Effect

    NASA Astrophysics Data System (ADS)

    Schulze, Julian; Donko, Zoltan; Heil, Brian; Czarnetzki, Uwe

    2008-10-01

    Recently a novel approach towards achieving separate control of ion flux and energy in capacitively coupled RF discharges based on the Electrical Asymmetry Effect (EAE) was proposed using fluid models. If the applied voltage waveform contains an even harmonic of its fundamental frequency, the sheaths will not be electrically symmetric. In order to balance electron and ion fluxes at each electrode a DC self bias develops. The self bias and, consequently, the ion energy can be controlled by tuning the phase between the two applied voltages. This technique works in geometrically symmetric and asymmetric discharges. Here the EAE is verified using a PIC simulation of a geometrically symmetric discharge. The self bias is found to be a nearly linear function of the phase angle. If the phase is changed, the ion flux stays constant within 5%, while the self bias reaches values of up to 80% of the applied voltage amplitude and the ion energy is changed by a factor of three. The EAE is investigated at different pressures and electrode gaps with focus on separate control of ion flux and energy.

  10. Characteristics of dual-frequency capacitively coupled SF6/O2 plasma and plasma texturing of multi-crystalline silicon

    NASA Astrophysics Data System (ADS)

    Xu, Dong-Sheng; Zou, Shuai; Xin, Yu; Su, Xiao-Dong; Wang, Xu-Sheng

    2014-06-01

    Due to it being environmentally friendly, much attention has been paid to the dry plasma texturing technique serving as an alternative candidate for multicrystalline silicon (mc-Si) surface texturing. In this paper, capacitively coupled plasma (CCP) driven by a dual frequency (DF) of 40.68 MHz and 13.56 MHz is first used for plasma texturing of mc-Si with SF6/O2 gas mixture. Using a hairpin resonant probe and optical emission techniques, DF-CCP characteristics and their influence on mc-silicon surface plasma texturing are investigated at different flow rate ratios, pressures, and radio-frequency (RF) input powers. Experimental results show that suitable plasma texturing of mc-silicon occurs only in a narrow range of plasma parameters, where electron density ne must be larger than 6.3 × 109 cm-3 and the spectral intensity ratio of the F atom to that of the O atom ([F]/[O]) in the plasma must be between 0.8 and 0.3. Out of this range, no cone-like structure is formed on the mc-silicon surface. In our experiments, the lowest reflectance of about 7.3% for mc-silicon surface texturing is obtained at an [F]/[O] of 0.5 and ne of 6.9 × 109 cm-3.

  11. 2D fluid model analysis for the effect of 3D gas flow on a capacitively coupled plasma deposition reactor

    NASA Astrophysics Data System (ADS)

    Kim, Ho Jun; Lee, Hae June

    2016-06-01

    The wide applicability of capacitively coupled plasma (CCP) deposition has increased the interest in developing comprehensive numerical models, but CCP imposes a tremendous computational cost when conducting a transient analysis in a three-dimensional (3D) model which reflects the real geometry of reactors. In particular, the detailed flow features of reactive gases induced by 3D geometric effects need to be considered for the precise calculation of radical distribution of reactive species. Thus, an alternative inclusive method for the numerical simulation of CCP deposition is proposed to simulate a two-dimensional (2D) CCP model based on the 3D gas flow results by simulating flow, temperature, and species fields in a 3D space at first without calculating the plasma chemistry. A numerical study of a cylindrical showerhead-electrode CCP reactor was conducted for particular cases of SiH4/NH3/N2/He gas mixture to deposit a hydrogenated silicon nitride (SiN x H y ) film. The proposed methodology produces numerical results for a 300 mm wafer deposition reactor which agree very well with the deposition rate profile measured experimentally along the wafer radius.

  12. Experimental and numerical investigations of electron density in low-pressure dual-frequency capacitively coupled oxygen discharges

    SciTech Connect

    Liu, Jia; Wen, De-Qi; Liu, Yong-Xin; Gao, Fei; Lu, Wen-Qi; Wang, You-Nian

    2013-11-15

    The electron density is measured in low-pressure dual-frequency (2/60 MHz) capacitively coupled oxygen discharges by utilizing a floating hairpin probe. The dependence of electron density at the discharge center on the high frequency (HF) power, low frequency (LF) power, and gas pressure are investigated in detail. A (1D) particle-in-cell/Monte Carlo method is developed to calculate the time-averaged electron density at the discharge center and the simulation results are compared with the experimental ones, and general agreements are achieved. With increasing HF power, the electron density linearly increases. The electron density exhibits different changes with the LF power at different HF powers. At low HF powers (e.g., 30 W in our experiment), the electron density increases with increasing LF power while the electron density decreases with increasing LF power at relatively high HF powers (e.g., 120 W in our experiment). With increasing gas pressure the electron density first increases rapidly to reach a maximum value and then decreases slowly due to the combined effect of the production process by the ionization and the loss processes including the surface and volume losses.

  13. Application of capacitively coupled contactless conductivity as an external detector for zone electrophoresis in poly(dimethylsiloxane) chips.

    PubMed

    Koczka, Péter I; Bodoki, Ede; Gáspár, Attila

    2016-02-01

    In this work, lab-made PDMS microfluidic chips were matched to a capacitively coupled contactless conductivity detector (C(4) D) having external in-plane electrodes (eDAQ, Australia). The advantages of this type of C(4) D are the choice to reversibly place or remove the microchip onto/from the detector and to freely variate the position of the detection (separation length) on the microchip. The thickness of the bottom layer of the PDMS chip was optimized to achieve sensitive detection during the electrophoretic separation. PDMS chips with 100 μm bottom layer used with the C(4) D platform were tested by CZE of a mixture of seven anions and different types of real samples. Using split-flow pressure sample injection and effective length of 6.5 cm, the numbers of theoretical plates were in the range of 4000-6000 (63,000-93,000/m) and the LODs amounted to 3.66-14.7 μmol/L (0.13-2.26 μg/mL) for the studied anions. PMID:26531885

  14. Mass spectrometry of positive ions in capacitively coupled low pressure RF discharges in oxygen with water impurities

    NASA Astrophysics Data System (ADS)

    Stefanović, Ilija; Stojanović, Vladimir; Boulmer-Leborgne, Chantal; Lecas, Thomas; Kovacevic, Eva; Berndt, Johannes

    2016-07-01

    A capacitively coupled RF oxygen discharge is studied by means of mass spectroscopy. Mass spectra of neutral and positive species are measured in the mid plane between the electrodes at different distances between plasma and mass-spectrometer orifice. In the case of positive ions, as expected, the largest flux originates from \\text{O}2+ . However, a significant number of impurities are detected, especially for low input powers and larger distances. The most abundant positive ions (besides \\text{O}2+ ) are \\text{N}{{\\text{O}}+}, \\text{NO}2+ , {{\\text{H}}+}≤ft({{\\text{H}}2}\\text{O}\\right) , and {{\\text{H}}+}{{≤ft({{\\text{H}}2}\\text{O}\\right)}2} . In particular, for the case of hydrated hydronium ions {{\\text{H}}+}{{≤ft({{\\text{H}}2}\\text{O}\\right)}n} (n  =  1, 2) a surprisingly large flux (for low pressure plasma conditions) is detected. Another interesting fact concerns the {{\\text{H}}2}{{\\text{O}}+} ions. Despite the relatively high ammount of water impurities {{\\text{H}}2}{{\\text{O}}+} ions are present only in traces. The reaction mechanisms leading to the production of the observed ions, especially the hydrated hydronium ions are discussed.

  15. Characterization of neutral species densities in dual frequency capacitively coupled photoresist ash plasmas by optical emission actinometry

    NASA Astrophysics Data System (ADS)

    Worsley, M. A.; Bent, S. F.; Fuller, N. C. M.; Dalton, T.

    2006-10-01

    Reactive neutral species densities for various conditions in dual frequency capacitively coupled discharges of Ar /O2, Ar /N2, and Ar /H2 were determined using optical emission spectroscopy, Kr actinometry, and modeling. The reactive neutral species probed in this work include O, O2, N, N2, H, and H2. Densities are reported as a function of pressure (5-60mTorr), percent Ar in the feed gas (1%-86%), source power (50-800W), and bias power (0W, 200W). It was found that increasing the pressure from 5to60mTorr resulted in order of magnitude increases in atomic species densities for all ash chemistries. At 30mTorr, percent dissociation is relatively low (⩽15%) for all species. Also, at 30mTorr, the addition of Ar resulted in a small decrease in N and H densities, but an order of magnitude increase in O density. Based on modeling, it is proposed that the increase in O density is due to an increasing contribution of Penning dissociation with increasing Ar density. Only the source power contributed significantly to O and N radical densities, but 200W bias power generated a significant H radical density above that generated via the source power. Details of these results are discussed in comparison with theory and literature.

  16. A simulation of a capacitively coupled oxygen discharge using the oopd1 particle-in-cell Monte Carlo code

    NASA Astrophysics Data System (ADS)

    Gudmundsson, J. T.; Lieberman, M. A.; Wang, Ying; Verboncoeur, J. P.

    2009-10-01

    The oopd1 particle-in-cell Monte Carlo (PIC-MC) code is used to simulate a capacitively coupled discharge in oxygen. oopd1 is a one-dimensional object-oriented PIC-MC code [1] in which the model system has one spatial dimension and three velocity components. It contains models for planar, cylindrical, and spherical geometries and replaces the XPDx1 series [2], which is not object-oriented. The revised oxygen model includes, in addition to electrons, the oxygen molecule in ground state, the oxygen atom in ground state, the negative ion O^-, and the positive ions O^+ and O2^+. The cross sections for the collisions among the oxygen species have been significantly revised from earlier work using the xpdp1 code [3]. Here we explore the electron energy distribution function (EEDF), the ion energy distribution function (IEDF) and the density profiles for various pressures and driving frequencies. In particular we investigate the influence of the O^+ ion on the IEDF, we explore the influence of multiple driving frequencies, and we do comparisons to the previous xpdx1 codes. [1] J. P. Verboncoeur, A. B. Langdon, and N. T. Gladd, Comp. Phys. Comm. 87 (1995) 199 [2] J. P. Verboncoeur, M. V. Alves, V. Vahedi, and C. K. Birdsall, J. Comp. Physics 104 (1993) 321 [2] V. Vahedi and M. Surendra, Comp. Phys. Comm. 87 (1995) 179

  17. Reversal of the asymmetry in a cylindrical coaxial capacitively coupled Ar/Cl2 plasma

    SciTech Connect

    Upadhyay, Janardan; Im, Do; Popović, Svetozar; Vušković, Leposava; Valente-Feliciano, Anne -Marie; Phillips, Larry

    2015-10-08

    The reduction of the asymmetry in the plasma sheath voltages of a cylindrical coaxial capacitively coupled plasma is crucial for efficient surface modification of the inner surfaces of concave three-dimensional structures, including superconducting radio frequency cavities. One critical asymmetry effect is the negative dc self-bias, formed across the inner electrode plasma sheath due to its lower surface area compared to the outer electrode. The effect on the self-bias potential with the surface enhancement by geometric modification on the inner electrode structure is studied. The shapes of the inner electrodes are chosen as cylindrical tube, large and small pitch bellows, and disc-loaded corrugated structure (DLCS). The dc self-bias measurements for all these shapes were taken at different process parameters in Ar/Cl2 discharge. Lastly, the reversal of the negative dc self-bias potential to become positive for a DLCS inner electrode was observed and the best etch rate is achieved due to the reduction in plasma asymmetry.

  18. Investigation of ion energy and angular distributions at the wafer edge in rf capacitively coupled reactors using CFD-ACE+

    NASA Astrophysics Data System (ADS)

    Bhoj, Ananth; Roy, Abhra; Jain, Kunal; Xiong, Zhongmin

    2015-09-01

    Dual frequency capacitively coupled reactors are now commonly used in microelectronics fabrication. The extent of possible independent control of ion fluxes and ion energy and angular distribution (IEADs) by varying HF and LF signals is currently a topic of great interest. In this study, we report on investigations of IEADs in single and dual frequency CCPs, including the wafer edge refinement using CFD-ACE+. The current algorithms in CFD-ACE+ allow the determination of total power at the electrode or in the discharge. To account for the presence of two or more rf sources connected to a powered electrode, the existing numerical algorithms for power targeting were enhanced to track current at the electrode as a function of time, vary voltage and determine power as a function of frequency. The Monte Carlo transport module for heavy species in CFD-ACE+ was recently enhanced to compute IEADs in rf discharges. Results for the effect of varying power and pressure on IEADs were compared to semi-analytical models and data reported in Gahan et al.. The validated model was applied to investigate the effect of details of HF and LF signals on IEADs in Argon discharges.

  19. 2-dimensional simulations of electrically asymmetric capacitively coupled RF-discharges

    NASA Astrophysics Data System (ADS)

    Mohr, Sebastian; Schulze, Julian; Schuengel, Edmund; Czarnetzki, Uwe

    2011-10-01

    Capactively coupled RF-discharges are widely used for surface treatment like the deposition of thin films. For industrial applications, the independent control of the ion flux to and the mean energy of the electrons impinging on the surfaces is desired. Experiments and 1D3v-PIC/MCC-simulations have shown that this independent control is possible by applying a fundamental frequency and its second harmonic to the powered electrode. This way, even in geometrically symmetric discharges, as they are often used in industrial reactors, a discharge asymmetry can be induced electrically, hence the name Electrical Asymmetry Effect (EAE). We performed 2D-simulations of electrically asymmetric discharges using HPEM by the group of Mark Kushner, a simulation tool suitable for simulating industrial reactors. First results are presented and compared to previously obtained experimental and simulation data. The comparison shows that for the first time, we succeeded in simulating electrically asymmetric discharges with a 2-dimensional simulation. Capactively coupled RF-discharges are widely used for surface treatment like the deposition of thin films. For industrial applications, the independent control of the ion flux to and the mean energy of the electrons impinging on the surfaces is desired. Experiments and 1D3v-PIC/MCC-simulations have shown that this independent control is possible by applying a fundamental frequency and its second harmonic to the powered electrode. This way, even in geometrically symmetric discharges, as they are often used in industrial reactors, a discharge asymmetry can be induced electrically, hence the name Electrical Asymmetry Effect (EAE). We performed 2D-simulations of electrically asymmetric discharges using HPEM by the group of Mark Kushner, a simulation tool suitable for simulating industrial reactors. First results are presented and compared to previously obtained experimental and simulation data. The comparison shows that for the first time, we

  20. Modeling of the nanoparticle coagulation in pulsed radio-frequency capacitively coupled C2H2 discharges

    NASA Astrophysics Data System (ADS)

    Liu, Xiang-Mei; Li, Qi-Nan; Li, Rui

    2015-07-01

    The role of pulse parameters on nanoparticle property is investigated self-consistently based on a couple of fluid model and aerosol dynamics model in a capacitively coupled parallel-plate acetylene (C2H2) discharge. In this model, the mass continuity equation, momentum balance equation, and energy balance equation for neutral gas are taken into account. Thus, the thermophoretic force arises when a gas temperature gradient exists. The typical results of this model are positive and negative ion densities, electron impact collisions rates, nanoparticle density, and charge distributions. The simulation is performed for duty ratio 0.4/0.7/1.0, as well as pulse modulation frequency from 40 kHz to 2.7 MHz for pure C2H2 discharges at a pressure of 500 mTorr. We find that the pulse parameters, especially the duty ratio, have a great affect on the dissociative attachment coefficient and the negative density. More importantly, by decreasing the duty ratio, nanoparticles start to diffuse to the wall. Under the action of gas flow, nanoparticle density peak is created in front of the pulse electrode, where the gas temperature is smaller. Project supported by the Natural Science Foundation of Heilongjiang Province, China (Grant Nos. A2015011 and A2015010), the Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province, China (Grant No. LBH-Q14159), the National Natural Science Foundation of China (Grant No. 11404180), and the Program for Young Teachers Scientific Research in Qiqihar University, China (Grant No. 2014k-Z11).

  1. Diffusion-stress coupling in liquid phase during rapid solidification of binary mixtures

    NASA Astrophysics Data System (ADS)

    Sobolev, S. L.

    2014-01-01

    An analytical model has been developed to describe the diffusion-viscous stress coupling in the liquid phase during rapid solidification of binary mixtures. The model starts with a set of evolution equations for diffusion flux and viscous pressure tensor, based on extended irreversible thermodynamics. It has been demonstrated that the diffusion-stress coupling leads to non-Fickian diffusion effects in the liquid phase. With only diffusive dynamics, the model results in the nonlocal diffusion equations of parabolic type, which imply the transition to complete solute trapping only asymptotically at an infinite interface velocity. With the wavelike dynamics, the model leads to the nonlocal diffusion equations of hyperbolic type and describes the transition to complete solute trapping and diffusionless solidification at a finite interface velocity in accordance with experimental data and molecular dynamic simulation.

  2. Measuring the composition-curvature coupling in binary lipid membranes by computer simulations

    SciTech Connect

    Barragán Vidal, I. A. Müller, M.; Rosetti, C. M.; Pastorino, C.

    2014-11-21

    The coupling between local composition fluctuations in binary lipid membranes and curvature affects the lateral membrane structure. We propose an efficient method to compute the composition-curvature coupling in molecular simulations and apply it to two coarse-grained membrane models—a minimal, implicit-solvent model and the MARTINI model. Both the weak-curvature behavior that is typical for thermal fluctuations of planar bilayer membranes as well as the strong-curvature regime corresponding to narrow cylindrical membrane tubes are studied by molecular dynamics simulation. The simulation results are analyzed by using a phenomenological model of the thermodynamics of curved, mixed bilayer membranes that accounts for the change of the monolayer area upon bending. Additionally the role of thermodynamic characteristics such as the incompatibility between the two lipid species and asymmetry of composition are investigated.

  3. The effect of the driving frequencies on the electrical asymmetry of dual-frequency capacitively coupled plasmas

    NASA Astrophysics Data System (ADS)

    Korolov, Ihor; Donkó, Zoltán; Czarnetzki, Uwe; Schulze, Julian

    2012-11-01

    In capacitively coupled radio frequency discharges driven by two consecutive phase-locked harmonics, the electrical asymmetry effect (EAE) allows one to generate a dc self-bias as a function of the phase shift, θ, between the driving harmonics. If the two frequencies are chosen to be 13.56 and 27.12 MHz, the mean ion energy at both electrodes can be varied by a factor of about 2 by tuning θ at nearly constant ion flux. Until now the EAE has only been investigated in discharges operated at a fundamental frequency of f = 13.56 MHz. Here, we study the effect of changing this fundamental frequency on the performance of the EAE, i.e. on the electrical generation of a dc self-bias, the control range of the mean ion energy, and on the ion flux at both electrodes as a function of θ, by kinetic particle-in-cell/Monte Carlo simulations and theoretical modelling. We use argon gas and cover a wide range of fundamental frequencies (0.5 MHz ⩽ f ⩽ 60 MHz) and secondary electron yields. We find that the performance of the EAE is significantly worse at lower frequencies, i.e. the control range of the dc self-bias and, thus, the control range of the mean ion energy are strongly reduced. Based on the analytical model (i) the enhanced charged dynamics at lower frequencies and (ii) the transition of the electron heating mode induced by changing f are found to be the reasons for this effect.

  4. Effect of driving voltages in dual capacitively coupled radio frequency plasma: A study by nonlinear global model

    NASA Astrophysics Data System (ADS)

    Bora, B.

    2015-10-01

    On the basis of nonlinear global model, a dual frequency capacitively coupled radio frequency plasma driven by 13.56 MHz and 27.12 MHz has been studied to investigate the influences of driving voltages on the generation of dc self-bias and plasma heating. Fluid equations for the ions inside the plasma sheath have been considered to determine the voltage-charge relations of the plasma sheath. Geometrically symmetric as well as asymmetric cases with finite geometrical asymmetry of 1.2 (ratio of electrodes area) have been considered to make the study more reasonable to experiment. The electrical asymmetry effect (EAE) and finite geometrical asymmetry is found to work differently in controlling the dc self-bias. The amount of EAE has been primarily controlled by the phase angle between the two consecutive harmonics waveforms. The incorporation of the finite geometrical asymmetry in the calculations shift the dc self-bias towards negative polarity direction while increasing the amount of EAE is found to increase the dc self-bias in either direction. For phase angle between the two waveforms ϕ = 0 and ϕ = π/2, the amount of EAE increases significantly with increasing the low frequency voltage, whereas no such increase in the amount of EAE is found with increasing high frequency voltage. In contrast to the geometrically symmetric case, where the variation of the dc self-bias with driving voltages for phase angle ϕ = 0 and π/2 are just opposite in polarity, the variation for the geometrically asymmetric case is different for ϕ = 0 and π/2. In asymmetric case, for ϕ = 0, the dc self-bias increases towards the negative direction with increasing both the low and high frequency voltages, but for the ϕ = π/2, the dc-self bias is increased towards positive direction with increasing low frequency voltage while dc self-bias increases towards negative direction with increasing high frequency voltage.

  5. Capacitively-Coupled Resistivity measurements to determine frequency dependent electrical parameters in periglacial environment - theoretical considerations and first field tests.

    NASA Astrophysics Data System (ADS)

    Przyklenk, A.; Hördt, A.; Radić, T.

    2016-05-01

    Capacitively-Coupled Resistivity (CCR) is conventionally used to emulate DC resistivity measurements and may provide important information about the ice content of material in periglacial areas. The application of CCR theoretically enables the determination of both electrical parameters, i.e. the resistivity and the electrical permittivity, by analyzing magnitude and phase shift spectra. The electrical permittivity may dominate the impedance, especially in periglacial areas or regions of hydrogeological interest. However, previous theoretical work suggested that the phase shift may strongly depend on electrode height above ground, implying that electrode height must be known with great accuracy to determine electrical permittivity. Here, we demonstrate with laboratory test measurements, theoretical modelling and by analysing the Jacobian matrix of the inversion, that the sensitivity towards electrode height is drastically reduced if the electrical permittivity is frequency dependent in a way that is typical for ice. For the fist time, we used a novel broadband CCR device "Chameleon" for a field test located in one of the ridge galleries beneath the crest of Mount Zugspitze. A permanently ice covered bottom of a tunnel was examined. For the inversion of the measured spectra, the frequency dependance of the electrical parameters was parameterized in 3 different ways. A Debye Model for pure ices, a Cole-Cole Model for pure ices and a dual Cole-Cole Model including interfacial water additionally. The frequency-dependent resistivity and permittivity spectra obtained from the inversion, including low and high frequency limits, agree reasonably well with laboratory and field measurements reported in the literature.

  6. Capacitively-Coupled Resistivity measurements to determine frequency dependent electrical parameters in periglacial environment - theoretical considerations and first field tests

    NASA Astrophysics Data System (ADS)

    Przyklenk, A.; Hördt, A.; Radić, T.

    2016-05-01

    Capacitively-Coupled Resistivity (CCR) is conventionally used to emulate DC resistivity measurements and may provide important information about the ice content of material in periglacial areas. The application of CCR theoretically enables the determination of both electrical parameters, i.e. the resistivity and the electrical permittivity, by analyzing magnitude and phase shift spectra. The electrical permittivity may dominate the impedance, especially in periglacial areas or regions of hydrogeological interest. However, previous theoretical work suggested that the phase shift may strongly depend on electrode height above ground, implying that electrode height must be known with great accuracy to determine electrical permittivity. Here, we demonstrate with laboratory test measurements, theoretical modelling and by analysing the Jacobian matrix of the inversion, that the sensitivity towards electrode height is drastically reduced if the electrical permittivity is frequency dependent in a way that is typical for ice. For the fist time, we used a novel broadband CCR device "Chameleon" for a field test located in one of the ridge galleries beneath the crest of Mount Zugspitze. A permanently ice covered bottom of a tunnel was examined. For the inversion of the measured spectra, the frequency dependance of the electrical parameters was parameterized in 3 different ways. A Debye Model for pure ices, a Cole-Cole Model for pure ices and a dual Cole-Cole Model including interfacial water additionally. The frequency-dependent resistivity and permittivity spectra obtained from the inversion, including low and high frequency limits, agree reasonably well with laboratory and field measurements reported in the literature.

  7. Fully parameterized model of a voltage-driven capacitive coupled micromachined ohmic contact switch for RF applications

    NASA Astrophysics Data System (ADS)

    Heeb, Peter; Tschanun, Wolfgang; Buser, Rudolf

    2012-03-01

    A comprehensive and completely parameterized model is proposed to determine the related electrical and mechanical dynamic system response of a voltage-driven capacitive coupled micromechanical switch. As an advantage over existing parameterized models, the model presented in this paper returns within few seconds all relevant system quantities necessary to design the desired switching cycle. Moreover, a sophisticated and detailed guideline is given on how to engineer a MEMS switch. An analytical approach is used throughout the modelling, providing representative coefficients in a set of two coupled time-dependent differential equations. This paper uses an equivalent mass moving along the axis of acceleration and a momentum absorption coefficient. The model describes all the energies transferred: the energy dissipated in the series resistor that models the signal attenuation of the bias line, the energy dissipated in the squeezed film, the stored energy in the series capacitor that represents a fixed separation in the bias line and stops the dc power in the event of a short circuit between the RF and dc path, the energy stored in the spring mechanism, and the energy absorbed by mechanical interaction at the switch contacts. Further, the model determines the electrical power fed back to the bias line. The calculated switching dynamics are confirmed by the electrical characterization of the developed RF switch. The fabricated RF switch performs well, in good agreement with the modelled data, showing a transition time of 7 µs followed by a sequence of bounces. Moreover, the scattering parameters exhibit an isolation in the off-state of >8 dB and an insertion loss in the on-state of <0.6 dB up to frequencies of 50 GHz. The presented model is intended to be integrated into standard circuit simulation software, allowing circuit engineers to design the switch bias line, to minimize induced currents and cross actuation, as well as to find the mechanical structure dimensions

  8. Electron heating enhancement due to plasma series resonance in a capacitively coupled RF discharge: Electrical modeling and comparison to experimental measurements

    NASA Astrophysics Data System (ADS)

    Cao, Minglu; Lu, Yijia; Cheng, Jia; Ji, Linhong

    2016-09-01

    The electron heating enhancement due to the self-excitation of the plasma series resonance in capacitively coupled plasmas is revisited by a combination of an equivalent circuit model and experiments. To improve the model accuracy, measured voltage waveforms at the powered electrode are used instead of prescribing a sinusoidal voltage supply in series with a bias capacitance. The results calculated from the electrical model are consistent with the experimental measurements performed by a Langmuir probe with verification of a microwave interferometer, at pressures of 0.2 and 0.3 Torr. High harmonics occurring in the discharge currents agree with observations in previous research. The nonlinear plasma series resonance effect is found to have a notable contribution to both ohmic and stochastic heating evaluated by the electron heating efficiencies.

  9. Effect of driving voltages in dual capacitively coupled radio frequency plasma: A study by nonlinear global model

    SciTech Connect

    Bora, B.

    2015-10-15

    On the basis of nonlinear global model, a dual frequency capacitively coupled radio frequency plasma driven by 13.56 MHz and 27.12 MHz has been studied to investigate the influences of driving voltages on the generation of dc self-bias and plasma heating. Fluid equations for the ions inside the plasma sheath have been considered to determine the voltage-charge relations of the plasma sheath. Geometrically symmetric as well as asymmetric cases with finite geometrical asymmetry of 1.2 (ratio of electrodes area) have been considered to make the study more reasonable to experiment. The electrical asymmetry effect (EAE) and finite geometrical asymmetry is found to work differently in controlling the dc self-bias. The amount of EAE has been primarily controlled by the phase angle between the two consecutive harmonics waveforms. The incorporation of the finite geometrical asymmetry in the calculations shift the dc self-bias towards negative polarity direction while increasing the amount of EAE is found to increase the dc self-bias in either direction. For phase angle between the two waveforms ϕ = 0 and ϕ = π/2, the amount of EAE increases significantly with increasing the low frequency voltage, whereas no such increase in the amount of EAE is found with increasing high frequency voltage. In contrast to the geometrically symmetric case, where the variation of the dc self-bias with driving voltages for phase angle ϕ = 0 and π/2 are just opposite in polarity, the variation for the geometrically asymmetric case is different for ϕ = 0 and π/2. In asymmetric case, for ϕ = 0, the dc self-bias increases towards the negative direction with increasing both the low and high frequency voltages, but for the ϕ = π/2, the dc-self bias is increased towards positive direction with increasing low frequency voltage while dc self-bias increases towards negative direction with increasing high frequency voltage.

  10. Modeling of dual frequency capacitively coupled plasma sources utilizing a full-wave Maxwell solver: II. Scaling with pressure, power and electronegativity

    NASA Astrophysics Data System (ADS)

    Yang, Yang; Kushner, Mark J.

    2010-10-01

    The trend in dielectric etching in microelectronics fabrication with capacitively coupled plasmas is the use of multiple frequencies where a high frequency (HF, tens to hundreds of MHz) dominates ionization and a low frequency (LF, a few to tens MHz) is used to control ion energy distributions to the wafer. Process parameters, such as pressure, gas mixture and LF and HF power deposition, are important to determining the uniformity of the plasma and properties of ions incident on the wafer. In this paper, we report on a computational investigation of the consequences of these parameters on uniformity and ion energy distributions to the wafer in a dual frequency capacitively coupled plasma reactor sustained in Ar/CF4 gas mixtures. Due to the coupling of finite wavelength, electromagnetic skin, electrostatic edge and electronegative effects, there are no simple scaling laws for plasma uniformity. The plasma uniformity is ultimately a function of conductivity and energy relaxation distance of electrons accelerated by electric fields in and near the sheath. There is a strong second-order effect on uniformity due to feedback from the electron energy distributions (EEDs) to ionization sources. The trends from our parametric study are correlated with the spatial variation of the HF electric field, to the total power deposition and to the spatial variation of EEDs and ionization sources.

  11. The influence of the secondary electron induced asymmetry on the electrical asymmetry effect in capacitively coupled plasmas

    NASA Astrophysics Data System (ADS)

    Korolov, Ihor; Derzsi, Aranka; Donkó, Zoltán; Schulze, Julian

    2013-08-01

    In geometrically symmetric capacitive radio-frequency plasmas driven by two consecutive harmonics, a dc self-bias can be generated as a function of the phase shift between the driving frequencies via the Electrical Asymmetry Effect (EAE). Recently, the Secondary Electron Asymmetry Effect (SEAE) was discovered (Lafleur et al., J. Phys. D: Appl. Phys. 46, 135201 (2013)): unequal secondary electron emission coefficients at both electrodes were found to induce an asymmetry in single-frequency capacitive plasmas. Here, we investigate the simultaneous presence of both effects, i.e., a dual-frequency plasma driven by two consecutive harmonics with different electrode materials. We find that the superposition of the EAE and the SEAE is generally non-linear, i.e., the asymmetries generated by each individual effect do not simply add up at all phases. The control ranges of the dc self-bias and the mean ion energy can be enlarged, if both effects are combined.

  12. The influence of the secondary electron induced asymmetry on the electrical asymmetry effect in capacitively coupled plasmas

    SciTech Connect

    Korolov, Ihor; Derzsi, Aranka; Donkó, Zoltán; Schulze, Julian

    2013-08-05

    In geometrically symmetric capacitive radio-frequency plasmas driven by two consecutive harmonics, a dc self-bias can be generated as a function of the phase shift between the driving frequencies via the Electrical Asymmetry Effect (EAE). Recently, the Secondary Electron Asymmetry Effect (SEAE) was discovered (Lafleur et al., J. Phys. D: Appl. Phys. 46, 135201 (2013)): unequal secondary electron emission coefficients at both electrodes were found to induce an asymmetry in single-frequency capacitive plasmas. Here, we investigate the simultaneous presence of both effects, i.e., a dual-frequency plasma driven by two consecutive harmonics with different electrode materials. We find that the superposition of the EAE and the SEAE is generally non-linear, i.e., the asymmetries generated by each individual effect do not simply add up at all phases. The control ranges of the dc self-bias and the mean ion energy can be enlarged, if both effects are combined.

  13. Effect of adding small amount of inductive fields to O2, Ar/O2 capacitively coupled plasmas

    NASA Astrophysics Data System (ADS)

    Lee, Min-Hyong; Lee, Hyo-Chang; Chung, Chin-Wook

    2012-05-01

    Electron energy distribution functions (EEDFs) of low pressure O2 plasma were measured by adding small amount of coil power in a capacitive discharge. When the plasma was generated by bias power only, the measured EEDF showed a bi-Maxwellian distribution. However, when a very small coil power (a few Watts) was added, the EEDF evolved abruptly into a Maxwellian distribution, while the electron density was decreased. In an Ar/O2 mixture discharge, this EEDF evolution to the Maxwellian was also observed at a relatively higher coil power. This abrupt change in EEDFs with a very small coil power appears to be attributed to a combined effect of collisionless heating by capacitive and induced electric fields.

  14. Comparision of Emissive Probe assisted Measurements of Plasma Density to that of a Surface Wave Probe, in a Dual Frequency Confined Capacitively Coupled Discharge

    NASA Astrophysics Data System (ADS)

    Linnane, S.; Ellingboe, A. R.

    2003-10-01

    Dual frequency confined capacitively coupled plasmas are increasingly used in semiconductor manufacturing for dielectric etching, allowing greater (and independent) control of ion energies and ion flux on the etched substrate. One electrode is driven with the summation of 27MHz and 2MHz sinusoidal voltages, while the other electrode is grounded. The electrode areas are similar in size, giving an electrode aspect ratio less than 2. Because of this low aspect ratio, there are large oscillations in the plasma potential. The expectation is for sinusoidal oscillations at the higher driving frequency, due to capacitive sheaths, while a rectified oscillation is expected at the lower driving frequency [1]. The emissive probe and circuitry allows measurement of plasma potential oscillations at both driving frequencies and their harmonics, thus allowing measurement of the actual time-varying and time-independant plasma potential. Ion saturation current is measured with a single Langmuir probe. Tuned RF filters isolated the probe tip from the external voltage supply (which otherwise acts as a high frequency ground). To further enable the Langmuir probe to follow the plasma potential oscillations, the tip is capacitively coupled to the emissive probe. These results will then be compared with a simple surface wave probe technique [2], which uses the resonant absorption of surface waves by the plasma, to determine plasma density. [1] E. Kawamura, V. Vahedi, M. A. Lieberman and C. K. Birdsall, Plasma Sources Sci. Technology. 8 (1999) R45-R64 [2] Conference proceedings, Frontiers in Low Temperature Plasma Diagnostics V, 2003 pg 30. "Novel Plasma Monitoring by Surface Wave Probe" H.Sugai and K. Nakamura

  15. Magnetic dipolar coupling and collective effects for binary information codification in cost-effective logic devices

    NASA Astrophysics Data System (ADS)

    Chiolerio, Alessandro; Allia, Paolo; Graziano, Mariagrazia

    2012-09-01

    Physical limitations foreshadow the eventual end to traditional Complementary Metal Oxide Semiconductor (CMOS) scaling. Therefore, interest has turned to various materials and technologies aimed to succeed to traditional CMOS. Magnetic Quantum dot Cellular Automata (MQCA) are one of these technologies. Working MQCA arrays require very complex techniques and an excellent control on the geometry of the nanomagnets and on the quality of the magnetic thin film, thus limiting the possibility for MQCA of representing a definite solution to cost-effective, high density and low power consumption device demand. Counter-intuitively, moving towards bigger sizes and lighter technologies it is still possible to develop multi-state logic devices, as we demonstrated, whose main advantage is cost-effectiveness. Applications may be seen in low cost logic devices where integration and computational power are not the main issue, eventually using flexible substrates and taking advantage of the intrinsic mechanical toughness of systems where long range interactions do not need wirings. We realized cobalt micrometric MQCA arrays by means of Electron Beam Lithography, exploiting cost-effective processes such as lift-off and RF sputtering that usually are avoided due to their low control on array geometry and film roughness. Information relative to the magnetic configuration of MQCA elements including their eventual magnetic interactions was obtained from Magnetic Force Microscope (MFM) images, enhanced by means of a numerical procedure and presented in differential maps. We report the existence of bi-stable magnetic patterns, as detected by MFM while sampling the z-component of magnetic induction field, arising from dipolar inter-element magnetostatic coupling, able to store and propagate binary information. This is achieved despite the array quality and element magnetic state, which are low and multi-domain, respectively. We discuss in detail shape, inter-element spacing and dot profile

  16. Nonlinear dynamics of capacitive charging and desalination by porous electrodes.

    PubMed

    Biesheuvel, P M; Bazant, M Z

    2010-03-01

    The rapid and efficient exchange of ions between porous electrodes and aqueous solutions is important in many applications, such as electrical energy storage by supercapacitors, water desalination and purification by capacitive deionization, and capacitive extraction of renewable energy from a salinity difference. Here, we present a unified mean-field theory for capacitive charging and desalination by ideally polarizable porous electrodes (without Faradaic reactions or specific adsorption of ions) valid in the limit of thin double layers (compared to typical pore dimensions). We illustrate the theory for the case of a dilute, symmetric, binary electrolyte using the Gouy-Chapman-Stern (GCS) model of the double layer, for which simple formulae are available for salt adsorption and capacitive charging of the diffuse part of the double layer. We solve the full GCS mean-field theory numerically for realistic parameters in capacitive deionization, and we derive reduced models for two limiting regimes with different time scales: (i) in the "supercapacitor regime" of small voltages and/or early times, the porous electrode acts like a transmission line, governed by a linear diffusion equation for the electrostatic potential, scaled to the RC time of a single pore, and (ii) in the "desalination regime" of large voltages and long times, the porous electrode slowly absorbs counterions, governed by coupled, nonlinear diffusion equations for the pore-averaged potential and salt concentration. PMID:20365735

  17. Capacitively coupled contactless conductivity detection as an alternative detection mode in CE for the analysis of kanamycin sulphate and its related substances.

    PubMed

    El-Attug, Mohamed N; Adams, Erwin; Hoogmartens, Jos; Van Schepdael, Ann

    2011-09-01

    A method was developed to determine simultaneously kanamycin, its related substances and sulphate in kanamycin sulphate using capacitively coupled contactless conductivity detection. Kanamycin is an aminoglycoside antibiotic that lacks a strong UV-absorbing chromophore. Due to its physicochemical properties, CE in combination with capacitively coupled contactless conductivity detection was chosen. The separation method uses a BGE composed of 40 mM 2-(N-morpholino)ethanesulphonic acid monohydrate and 40 mM L-histidine, pH 6.35. A 0.6 mM N-cetyltrimethyl ammonium bromide (CTAB) solution was added as electroosmotic flow modifier in a concentration below the critical micellar concentration (CMC). Ammonium acetate 50 mg/L was used as internal standard. In total, 30 kV was applied in reverse polarity on a fused-silica capillary (65/41 cm; 75 μm id). The optimized separation was obtained in less than 6 min with good linearity (R(2)=0.9999) for kanamycin. It shows a good precision expressed as RSD on the relative peak areas equal to 0.3 and 1.1% for intra-day and inter-day precision, respectively. The LOD and LOQ are 0.7 and 2.3 mg/L, respectively. Similarly, for sulphate, a good linearity (R(2)=0.9996) and precision (RSD 0.4 and 0.6% for intra-day and inter-day, respectively) were obtained. PMID:21796785

  18. Difference in chemical reactions in bulk plasma and sheath regions during surface modification of graphene oxide film using capacitively coupled NH3 plasma

    NASA Astrophysics Data System (ADS)

    Lee, Sung-Youp; Kim, Chan; Kim, Hong Tak

    2015-09-01

    Reduced graphene oxide (r-GO) films were obtained from capacitively coupled NH3 plasma treatment of spin-coated graphene oxide (GO) films at room temperature. Variations were evaluated according to the two plasma treatment regions: the bulk plasma region (Rbulk) and the sheath region (Rsheath). Reduction and nitridation of the GO films began as soon as the NH3 plasma was exposed to both regions. However, with the increase in treatment time, the reduction and nitridation reactions differed in each region. In the Rbulk, NH3 plasma ions reacted chemically with oxygen functional groups on the GO films, which was highly effective for reduction and nitridation. While in the Rsheath, physical reactions by ion bombardment were dominant because plasma ions were accelerated by the strong electrical field. The accelerated plasma ions reacted not only with the oxygen functional groups but also with the broken carbon chains, which caused the removal of the GO films by the formation of hydrocarbon gas species. These results showed that reduction and nitridation in the Rbulk using capacitively coupled NH3 plasma were very effective for modifying the properties of r-GO films for application as transparent conductive films.

  19. Difference in chemical reactions in bulk plasma and sheath regions during surface modification of graphene oxide film using capacitively coupled NH{sub 3} plasma

    SciTech Connect

    Lee, Sung-Youp; Kim, Chan; Kim, Hong Tak

    2015-09-14

    Reduced graphene oxide (r-GO) films were obtained from capacitively coupled NH{sub 3} plasma treatment of spin-coated graphene oxide (GO) films at room temperature. Variations were evaluated according to the two plasma treatment regions: the bulk plasma region (R{sub bulk}) and the sheath region (R{sub sheath}). Reduction and nitridation of the GO films began as soon as the NH{sub 3} plasma was exposed to both regions. However, with the increase in treatment time, the reduction and nitridation reactions differed in each region. In the R{sub bulk}, NH{sub 3} plasma ions reacted chemically with oxygen functional groups on the GO films, which was highly effective for reduction and nitridation. While in the R{sub sheath}, physical reactions by ion bombardment were dominant because plasma ions were accelerated by the strong electrical field. The accelerated plasma ions reacted not only with the oxygen functional groups but also with the broken carbon chains, which caused the removal of the GO films by the formation of hydrocarbon gas species. These results showed that reduction and nitridation in the R{sub bulk} using capacitively coupled NH{sub 3} plasma were very effective for modifying the properties of r-GO films for application as transparent conductive films.

  20. Kibble-Zurek dynamics in an array of coupled binary Bose condensates

    NASA Astrophysics Data System (ADS)

    Xu, Jun; Wu, Shuyuan; Qin, Xizhou; Huang, Jiahao; Ke, Yongguan; Zhong, Honghua; Lee, Chaohong

    2016-03-01

    Universal dynamics of spontaneous symmetry breaking is central to understanding the universal behavior of spontaneous defect formation in various systems from the early universe, condensed-matter systems to ultracold atomic systems. We explore the universal real-time dynamics in an array of coupled binary atomic Bose-Einstein condensates in optical lattices, which undergo a spontaneous symmetry breaking from the symmetric Rabi oscillation to the broken-symmetry self-trapping. In addition to Goldstone modes, there exist gapped Higgs modes whose excitation gap vanishes at the critical point. In the slow passage through the critical point, we analytically find that the symmetry-breaking dynamics obeys the Kibble-Zurek mechanism. From the scalings of bifurcation delay and domain formation, we numerically extract two Kibble-Zurek exponents, b1=ν/(1+ν z) and b2=1/(1+ν z) , which give the static correlation-length critical exponent ν and the dynamic critical exponent z. Our approach provides an efficient way for the simultaneous determination of the critical exponents ν and z for a continuous phase transition.

  1. Investigation of Interdiffusion Behavior in the Mo-Zr Binary System via Diffusion Couple Studies

    SciTech Connect

    A. Paz y Puente; J. Dickson; D.D. Keiser, Jr.; Y.H. Sohn

    2014-03-01

    Zirconium has recently garnered attention for use as a diffusion barrier between U–Mo metallic nuclear fuels and Al alloy cladding. In order to gain a fundamental understanding of the diffusional interactions, the interdiffusion behavior in the binary Mo–Zr system was investigated via solid-to-solid diffusion couples annealed in the temperature range of 750 to 1050 degrees C. A combination of scanning electron microscopy, X-ray energy dispersive spectroscopy, and electron probe microanalysis were used to examine the microstructure and concentration profiles across the interdiffusion zone. A large __-Zr (cI2) solid solution layer and a thin (approximately 1–2 um) layer of Mo2Zr (cF24) developed in all couples. Parabolic growth constants and concentration dependent interdiffusion coefficients were calculated for the Mo2Zr and Zr solid solution phases, respectively. The pre-exponential factor and activation energy for growth of the Mo2Zr phase were determined to be approximately 6.5 × 10- 15 m2/s and 90 kJ/mol, respectively. The interdiffusion coefficient in ___-Zr solid solution decreased with an increase in Mo concentration. Both the pre-exponential factors (2 × 10- 8 m2/s at 2 at.% Mo to near 5 × 10- 8 m2/s at 9 at.% Mo) and activation energies (140 kJ/mol at 2 at.% Mo to approximately 155 kJ/mol at 9 at.% Mo) of interdiffusion coefficients were determined to increase with an increase in Mo concentration.

  2. The influence of the secondary electron induced asymmetry on the Electrical Asymmetry Effect in capacitively coupled plasmas

    NASA Astrophysics Data System (ADS)

    Schulze, Julian; Korolov, Ihor; Derzsi, Aranka; Donko, Zoltan

    2013-09-01

    In geometrically symmetric capacitive radio-frequency plasmas driven by two consecutive harmonics a dc self-bias can be generated as a function of the phase shift between the driving frequencies via the Electrical Asymmetry Effect (EAE). Recently the Secondary Electron Asymmetry Effect (SEAE) was discovered (T. Lafleur, P. Chabert, and J.P. Booth J. Phys. D: Appl. Phys. 46, 135201 (2013)): unequal secondary electron emission coefficients at both electrodes were found to induce an asymmetry in single frequency capacitive plasmas. Here, we investigate the simultaneous presence of both effects by Particle in Cell simulations, i.e. a dual-frequency plasma driven by two consecutive harmonics with different electrode materials. We find, that the superposition of the EAE and the SEAE is non-linear, i.e. the asymmetries generated by each individual effect do not simply add up. The control ranges of the dc self-bias and the mean ion energy can be enlarged, if both effects are combined.

  3. A scanning microscopy technique based on capacitive coupling with a field-effect transistor integrated with the tip.

    PubMed

    Shin, Kumjae; Kang, Dae sil; Lee, Sang hoon; Moon, Wonkyu

    2015-12-01

    We propose a method for measuring the capacitance of a thin layer using a Tip-on-Gate of Field-Effect Transistor (ToGoFET) probe. A ToGoFET probe with a metal-oxide-semiconductor field-effect transistor (MOSFET) with an ion-implant channel was embedded at the end of a cantilever and a Pt tip was fabricated using micro-machining. The ToGoFET probe was used to detect an alternating electric field at the dielectric surface. A dielectric buried metal sample was prepared; a sinusoidal input signal was applied to the buried metal lines; and the ToGoFET probe detected the electric field at the tip via the dielectric. The AC signal detected by the ToGoFET probe was demodulated by a simple AC-to-DC converter. Experimentally, it was shown that an electric field could be measured at the surface of the dielectric layer above a buried metal line. This promising result shows that it is possible to measure the surface local capacitance. PMID:26231315

  4. The discharge mode transition and O({sup 5}p{sub 1}) production mechanism of pulsed radio frequency capacitively coupled plasma

    SciTech Connect

    Liu, X. Y.; Hu, J. T.; Liu, J. H.; Xiong, Z. L.; Liu, D. W.; Lu, X. P.; Shi, J. J.

    2012-07-23

    The discharge mode transition from uniform plasma across the gas gap to the {alpha} mode happens at the rising phase of the pulsed radio frequency capacitively coupled plasma (PRF CCP). This transition is attributed to the fast increasing stochastic heating at the edge of sheath. In the second stage with the stable current and voltage amplitude, the consistency between experimental and numerical spatial-temporal 777 nm emission profile suggests that He* and He{sub 2}* dominate the production of O({sup 5}p{sub 1}) through dissociation and excitation of O{sub 2}. Finally, the sterilization efficiency of PRF CCP is found to be higher than that of plasma jet.

  5. Portable integrated capillary-electrophoresis system using disposable polymer chips with capacitively coupled contactless conductivity detection for on-site analysis of foodstuff

    NASA Astrophysics Data System (ADS)

    Gärtner, Claudia; Hoffmann, Werner; Demattio, Horst; Clemens, Thomas; Klotz, Matthias; Klemm, Richard; Becker, Holger

    2009-05-01

    We present a compact portable chip-based capillary electrophoresis system that employs capacitively coupled contactless conductivity detection (C4D) operating at 4 MHz as an alternative detection method compared to the commonly used optical detection based on laser-induced fluorescence. Emphasis was put on system integration and industrial manufacturing technologies for the system. Therefore, the disposable chip for this system is fabricated out of PMMA using injection molding; the electrodes are screen-printed or thin-film electrodes. The system is designed for the measurement of small ionic species like Li+, Na+, K+, SO42- or NO3- typically present in foods like milk and mineral water as well as acids e.g. in wine.

  6. Performance Enhancement of Capacitive-Coupling Dual-gate Ion-Sensitive Field-Effect Transistor in Ultra-Thin-Body

    PubMed Central

    Jang, Hyun-June; Cho, Won-Ju

    2014-01-01

    Recently, thin-film transistor based-ISFETs with the dual-gate (DG) structures have been proposed, in order to beat the Nernst response of the standard ISFET, utilizing diverse organic or inorganic materials. The immutable Nernst response can be dramatically transformed to an ultra-sensing margin, with the capacitive-coupling arisen from the DG structure. In order to advance this platform, we here embedded the ultra-thin body (UTB) into the DG ISFET. The UTB of 4.3 nm serves to not only increase its sensitivity, but also to strongly suppress the leakage components, leading to a better stability of the DG ISFET. In addition, we first provide a comprehensive analysis of the body thickness effects especially how the thick body can render the degradation in the device performance, such as sensitivity and stability. The UTB DG ISFET will allow the ISFET-based biosensor platform to continue enhancement into the next decade. PMID:24923751

  7. Numerical investigation of ion energy distribution and ion angle distribution in a dual-frequency capacitively coupled plasma with a hybrid model

    NASA Astrophysics Data System (ADS)

    Wang, Shuai; Xu, Xiang; Wang, You-Nian

    2007-11-01

    A one-dimensional hybrid model is developed to study the characteristics of energy and angular distributions of the ions and fast neutrals impinging on the rf-biased electrode in a dual-frequency capacitively coupled Ar discharge. The hybrid model consists of a fluid model that determines the spatiotemporal evolution of the discharge, and a Monte-Carlo model that, including the electron-neutral, ion-neutral, and fast neutral-neutral collisions, predicts the energy and angular distributions of the ions and fast neutrals on the rf-biased electrode. The influence of pressure, voltage amplitude, and frequencies of the two rf sources on the energy and angular distributions is discussed. The ion energy distributions (IEDs) appear to have multiple peaks in the dual-frequency capacitively coupled rf discharge rather than bimodal shape in a conventional single-frequency rf discharge. The ion angle distributions (IADs) have a significant peak at a small angle, and most ions strike to the process surface with the angle less than 4°. With the increase of the pressure, the maximum energy of IEDs and the peaks of IADs decrease. The structures of IEDs are controlled mainly by the voltage and frequency applied to the two rf sources. By decreasing the frequency or adding the voltage applied to the low-frequency (LF) source, the width of IEDs and the maximum energy increase. More ions strike to the electrode with a small angle by increasing either the voltage of LF source or the frequency of high-frequency source. The energy and angular distributions of the fast neutrals are correlative with those of the ions. Compared with the ions, the fast neutrals have a much lower energy and the scattering effect becomes more prominent.

  8. Optimization of the electrical asymmetry effect in dual-frequency capacitively coupled radio frequency discharges: Experiment, simulation, and model

    NASA Astrophysics Data System (ADS)

    Schulze, J.; Schüngel, E.; Czarnetzki, U.; Donkó, Z.

    2009-09-01

    An electrical asymmetry in capacitive rf discharges with a symmetrical electrode configuration can be induced by driving the discharge with a fundamental frequency and its second harmonic. For equal amplitudes of the applied voltage waveforms, it has been demonstrated by modeling, simulation, and experiments that this electrical asymmetry effect (EAE) leads to the generation of a variable dc self-bias that depends almost linearly on the phase angle between the driving voltage signals. Here, the dependence of the dc self-bias generated by the EAE on the choice of the voltage amplitudes, i.e., the ratio A of high to low frequency amplitude, is investigated experimentally as well as by using an analytical model and a particle-in-cell simulation. It is found that (i) the strongest electrical asymmetry is induced for A <1 at pressures ranging from 6 to 100 Pa and that (ii) around this optimum voltage ratio the dc self-bias normalized to the sum of both voltage amplitudes is fairly insensitive to changes of A. Thus, by choosing the optimum voltage ratio, the EAE is optimized: The ion energy can be changed over a broader energy range and a high degree of process stability with respect to small changes in the applied voltages is expected.

  9. Optimization of the electrical asymmetry effect in dual-frequency capacitively coupled radio frequency discharges: Experiment, simulation, and model

    SciTech Connect

    Schulze, J.; Schuengel, E.; Czarnetzki, U.; Donko, Z.

    2009-09-15

    An electrical asymmetry in capacitive rf discharges with a symmetrical electrode configuration can be induced by driving the discharge with a fundamental frequency and its second harmonic. For equal amplitudes of the applied voltage waveforms, it has been demonstrated by modeling, simulation, and experiments that this electrical asymmetry effect (EAE) leads to the generation of a variable dc self-bias that depends almost linearly on the phase angle between the driving voltage signals. Here, the dependence of the dc self-bias generated by the EAE on the choice of the voltage amplitudes, i.e., the ratio A of high to low frequency amplitude, is investigated experimentally as well as by using an analytical model and a particle-in-cell simulation. It is found that (i) the strongest electrical asymmetry is induced for A<1 at pressures ranging from 6 to 100 Pa and that (ii) around this optimum voltage ratio the dc self-bias normalized to the sum of both voltage amplitudes is fairly insensitive to changes of A. Thus, by choosing the optimum voltage ratio, the EAE is optimized: The ion energy can be changed over a broader energy range and a high degree of process stability with respect to small changes in the applied voltages is expected.

  10. Simulation study of wave phenomena from the sheath region in single frequency capacitively coupled plasma discharges; field reversals and ion reflection

    SciTech Connect

    Sharma, S.; Turner, M. M.

    2013-07-15

    Capacitively coupled radio-frequency (RF) discharges have great significance for industrial applications. Collisionless electron heating in such discharges is important, and sometimes is the dominant mechanism. This heating is usually understood to originate in a stochastic interaction between electrons and the electric fields. However, other mechanisms may also be important. There is evidence of wave emission with a frequency near the electron plasma frequency, i.e., ω{sub pe}, from the sheath region in collisionless capacitive RF discharges. This is the result of a progressive breakdown of quasi-neutrality close to the electron sheath edge. These waves are damped in a few centimeters during their propagation from the sheath towards the bulk plasma. The damping occurs because of the Landau damping or some related mechanism. This research work reports that the emission of waves is associated with a field reversal during the expanding phase of the sheath. Trapping of electrons near to this field reversal region is observed. The amplitude of the wave increases with increasing RF current density amplitude J(tilde sign){sub 0} until some maximum is reached, beyond which the wave diminishes and a new regime appears. In this new regime, the density of the bulk plasma suddenly increases because of ion reflection, which occurs due to the presence of strong field reversal near sheath region. Our calculation shows that these waves are electron plasma waves. These phenomena occur under extreme conditions (i.e., higher J(tilde sign){sub 0} than in typical experiments) for sinusoidal current waveforms, but similar effects may occur with non-sinusoidal pulsed waveforms for conditions of experimental interest, because the rate of change of current is a relevant parameter. The effect of electron elastic collisions on plasma waves is also investigated.

  11. Capacitive Extensometer

    NASA Technical Reports Server (NTRS)

    Perusek, Gail P. (Inventor)

    2003-01-01

    The present invention provides for measurements of the principal strain magnitudes and directions, and maximum shear strain that occurs in a porous specimen, such as plastic, ceramic or porous metal, when it is loaded (or subjected to a load). In one embodiment the invention includes a capacitive delta extensometer arranged with six sensors in a three piece configuration, with each sensor of each pair spaced apart from each other by a predetermined angle, such as 120 degrees.

  12. Patterns of disc-jet-wind coupling in black hole binaries

    NASA Astrophysics Data System (ADS)

    Fender, R.

    2015-07-01

    In this talk I will present the current state of the art in our understanding of the connection between accretion state and feedback in black hole X-ray binaries. In particular I will discuss how the X-ray accretion states, defined by their spectral and temporal properties, relate to phases of the production of relativistic (radio) jets and accretion disc winds. I will furthermore discuss how these patterns of behaviour contribute to the overall kinetic and radiative feedback during an outburst, and how comparable they may be to similar behaviour in neutron star X-ray binaries and supermassive black holes in active galactic nuclei.

  13. Twin-capacitive shaft angle encoder with analog output signal

    NASA Technical Reports Server (NTRS)

    Hruby, R. J.; Wilson, R. L. (Inventor)

    1977-01-01

    A precision capacitive shaft encoder providing a dc signal corresponding to the angular position of a shaft is described. Two variable capacitances are coupled in tandem by a rotatable shaft. Each capacitor has a capacitance that varies linearly with a change in the angular position of the shaft. The sum of the two capacitances is always constant for any angular position of the shaft. Each capacitance is alternately coupled to a reference dc voltage and a discharge circuit. The capacitances are electrically coupled in series and the charge periodically acquired at the junction of the capacitance is a function of the position of the shaft. An error-compensating voltage is imposed on the junction when the capacitances are coupled to the reference voltages. The junction is coupled to sample-and-hold apparatus provided with a error-correcting circuit.

  14. Tunable Plasmonic Coupling in Self-Assembled Binary Nanocrystal Super lattices Studied by Correlated Optical Microspectrophotometry and Electron Microscopy

    SciTech Connect

    Ye, XC; Chen, J; Diroll, BT; Murray, CB

    2013-03-01

    We study the plasmonic properties of self-assembled binary nanocrystal superlattices (BNSLs) using correlated optical microspectrophotometry and electron microscopy performed on individual BNSL domains. The strength of near-field couplings between adjacent plasmonic nanocrystals (NCs) can be systematically engineered by varying the NC size, composition, and the lattice symmetry of BNSLs, leading to broadband spectral tunability of the collective plasmonic response of BNSLs across the entire visible spectrum. Self-assembled multicomponent NC superlattices represent a versatile platform for the rational design of macroscopic three-dimensional plasmonic metamaterials with emergent optical characteristics.

  15. Pattern evolution caused by dynamic coupling between wetting and phase separation in binary liquid mixture containing glass particles

    NASA Astrophysics Data System (ADS)

    Tanaka, Hajime; Lovinger, Andew J.; Davis, Don D.

    1994-04-01

    We demonstrate here that the pattern evolution in a binary liquid mixture containing glass spheres is strongly affected by the dynamic coupling between phase separation and wetting. Because of the difference in the wettability to glass between the two phases, the glass particles are preferentially included in the more wettable phase. The resulting pattern is strongly dependent on whether the spheres are mobile or immobile. For a high density of mobile particles, we find that an initially random pattern of spheres transforms into an ordered pattern because of geometrical confinement of particles into the more wettable phase.

  16. A scalable, VHF/UHF, capacitively coupled plasma source for large-area applications at high frequencies

    NASA Astrophysics Data System (ADS)

    Ellingboe, Bert; O'Farrell, David; Gaman, Cezar; Green, Fiachra; O'Hara, Neal; Michna, Tomasz

    2009-10-01

    Process results are driving both plasma etch and CVD to higher frequencies; This is incompatible with increases in wafer size to 450mm and beyond. No where is the evidence more clear than in PECVD of amorphous and microcrystalline Silicon for the photo-active layer in thin-film photovoltaic devices. Growth rates for these layers, while maintaining the necessary mechanical and electrical properties, can increase with increasing rf frequency, and in some cases yield superior film properties at the higher deposition rates (P.G. Hugger, etal, MRS 2008). However, in this industry substrate sizes are very large, exceeding 1m characteristic lengths, which puts substantial limits for a conventional plasma diode topology on using frequency as a control vector to increase deposition rate, thus increasing factory through-put and decreasing cost. In this talk we will introduce a novel plasma source topology that enables increased rf frequencies on arbitrary size plasma source without causing wavelength effects. The concept is to segment the powered electrode into discrete tiles; For example as a checkerboard. Adjacent tiles can be powered out of phase with each other. In this way the displacement current coupled by one electrode is balance by and equal and opposite current of the adjacent electrode. Thus zero net current is coupled into the plasma, zero net current is coupled through the sheath above the substrate, and no wavelength effects occur even for substrates large in comparison to the rf wavelength. Highlights of recent results in the operation and application of the plasma source to PECVD of silicon will be presented.

  17. Dissipative particle dynamics simulation study on the binary mixture phase separation coupled with polymerization.

    PubMed

    Liu, Hong; Qian, Hu-Jun; Zhao, Ying; Lu, Zhong-Yuan

    2007-10-14

    The influence of polymerization on the phase separation of binary immiscible mixtures has been investigated by the dissipative particle dynamics simulations in two dimensions. During polymerization, the bulk viscosity increases, which consequently slows down the spinodal decomposition process. The domain size growth is monitored in the simulations. The absence of 23 exponent for inertial hydrodynamic mechanism clearly reflects the suppressing effect of polymerization on the phase separation. Due to the increasing viscosity, the individual phase may be trapped in a metastable stage instead of the lamellar morphology identified for symmetric mixtures. Moreover, the polymerization induced phase separation in the binary miscible mixture has been studied. The domain growth is strongly dependent on the polymerization probability, which is naturally related to the activation energy for polymerization. The observed complex phase separation behavior is attributed to the interplay between the increasing thermodynamic driving force for phase separation and the increasing viscosity that suppresses phase separation as the polymerization proceeds. PMID:17935435

  18. Greenberger-Horne-Zeilinger generation protocol for N superconducting transmon qubits capacitively coupled to a quantum bus

    NASA Astrophysics Data System (ADS)

    Aldana, Samuel; Wang, Ying-Dan; Bruder, C.

    2011-10-01

    We propose a circuit quantum electrodynamics (QED) realization of a protocol to generate a Greenberger-Horne-Zeilinger (GHZ) state for N superconducting transmon qubits homogeneously coupled to a superconducting transmission line resonator in the dispersive limit. We derive an effective Hamiltonian with pairwise qubit exchange interactions of the XY type, g˜(XX+YY), that can be globally controlled. Starting from a separable initial state, these interactions allow us to generate a multi-qubit GHZ state within a time tGHZ˜g˜-1. We discuss how to probe the nonlocal nature and the genuine N-partite entanglement of the generated state. Finally, we investigate the stability of the proposed scheme to inhomogeneities in the physical parameters.

  19. Enhanced Macroscopic Quantum Tunneling in Capacitively Coupled BiPb2201 Single-Layered Intrinsic Josephson Junctions

    NASA Astrophysics Data System (ADS)

    Nomura, Yoshiki; Mizuno, Takaaki; Kambara, Hitoshi; Nakagawa, Yuya; Kakeya, Itsuhiro

    2015-01-01

    Macroscopic quantum tunneling (MQT) in an intrinsic Josephson junction (IJJ) stack of Bi1.9Pb0.1Sr1.39La0.63CuO6+δ (BiPb2201) has been investigated. For the first switch, from superconducting to the first resistive branch in current-voltage characteristics, the crossover between MQT and thermal activation (TA) takes place at 0.6 K. On the other hand, for the second switch, the MQT-TA crossover temperature is increased to 2.0 K. This result is interpreted as follows: the MQT rate of the second switch is enhanced by the charge coupling between adjacent IJJs as well as in Bi2Sr2CaCu2O8+δ. We consider that the enhancement of the MQT rate is a common feature among bismuth-cuprates with single and double CuO2 layers in their crystal structures.

  20. The Electrical Asymmetry Effect - A novel and simple method for separate control of ion energy and flux in capacitively coupled RF discharges

    NASA Astrophysics Data System (ADS)

    Czarnetzki, U.; Heil, B. G.; Schulze, J.; Donkó, Z.; Mussenbrock, T.; Brinkmann, R. P.

    2009-04-01

    If a temporally symmetric voltage waveform is applied to a capacitively coupled radio frequency (CCRF) discharge, that contains one or more even harmonics of the fundamental frequency, the sheaths in front of the two electrodes will necessarily be asymmetric even in a geometrically symmetric discharge. Optimally this is achieved with a dual-frequency discharge driven at a phase locked fundamental frequency and its second harmonic, e.g. 13.56 MHz and 27.12 MHz. An analytical model, a hybrid fluid/Monte-Carlo kinetic model as well as a Particle in Cell (PIC) simulation show that this Electrical Asymmetry Effect (EAE) leads to the generation of a DC self bias as a function of the phase between the applied voltage harmonics in geometrically symmetric as well as asymmetric discharges. The DC self bias depends almost linearly on the phase angle and the role of the electrodes (powered and grounded) can be reversed. At low pressures the EAE is self-amplifying due to the conservation of ion flux in the sheaths. By tuning the phase, precise and convenient control of the ion energy at the electrodes can be achieved, while the ion flux remains constant. The maximum ion energy can typically be changed by a factor of about three at both electrodes. At the same time the ion flux is constant within ±5%.

  1. FAST TRACK COMMUNICATION: The electrical asymmetry effect in capacitively coupled radio frequency discharges - measurements of dc self bias, ion energy and ion flux

    NASA Astrophysics Data System (ADS)

    Schulze, J.; Schüngel, E.; Czarnetzki, U.

    2009-05-01

    The recently theoretically predicted electrical asymmetry effect (EAE) (Heil et al 2008 IEEE Trans. Plasma Sci. 36 1404, Heil et al 2008 J. Phys. D: Appl. Phys. 41 165202, Czarnetzki et al 2009 J. Phys.: Conf. Ser. at press) in capacitively coupled radio frequency (CCRF) discharges and the related separate control of ion energy and flux via the EAE (Czarnetzki et al 2009 J. Phys.: Conf. Ser. at press, Donkó et al 2008 J. Phys. D: Appl. Phys. 42 025205) are tested experimentally for the first time. A geometrically symmetric CCRF discharge (equal electrode surface areas) operated at 13.56 and 27.12 MHz with variable phase angle between the harmonics is operated in argon at different pressures. The dc self bias, the energy as well as the flux of ions at the grounded electrode, and the space and phase resolved optical emission are measured. The results verify the predictions of models and simulations: via the EAE a dc self bias is generated as an almost linear function of the phase. This variable dc self bias allows separate control of ion energy and flux in an almost ideal way under various discharge conditions.

  2. The effect of dust on the electron heating in capacitively coupled H2/SiH4 single- and dual-frequency discharges

    NASA Astrophysics Data System (ADS)

    Schüngel, Edmund; Mohr, Sebastian; Iwashita, Shinya; Schulze, Julian; Czarnetzki, Uwe

    2013-09-01

    Hydrogen diluted silane discharges exhibit a high dust concentration under typical application conditions. Therefore, the role of dust in fundamental plasma processes needs to be understood. We study a capacitively coupled rf discharge in H2/SiH4 using Phase Resolved Emission Spectroscopy, two-dimensional laser light scattering on the dust particles as well as current and voltage measurements. The results show that the electron heating is strongly affected by the presence of dust particles. In particular, a mode transition occurs from the traditional α-mode to a bulk drift field mode (Ω-mode), if the amount of dust is increased. An analytical model of the electron dynamics in Ω-mode has been developed. An asymmetric dust particle density profile, e.g. due to a gas temperature gradient, induces an asymmetry in the electron heating and, thereby, in the ion density profile of a single frequency parallel plate discharge. In electrically asymmetric discharges, the discharge asymmetry can usually be controlled via the phase angle between the applied harmonics. It is found that the Electrical Asymmetry Effect works in discharges operated in both α- or Ω-mode, as the width of the control interval is almost independent of the dust distribution. Funded by the German Federal Ministry for the Environment (0325210B) and the Ruhr-University Research Department Plasma.

  3. Phase-shift effects on growth and transport of dust particles in VHF capacitively coupled silane discharges: Two dimensional fluid simulation

    SciTech Connect

    Liu Xiangmei; Song Yuanhong; Xu Xiang; Wang Younian

    2011-08-15

    A two-dimensional (2D) self-consistent fluid model is developed to describe the formation, subsequent growth, transport, and charging mechanisms of nanoparticles in a capacitively coupled silane discharge applied by two very high frequency (VHF) sources with phase shift. In this discharge process, large anions are produced by a series of chemical reactions of anions with silane molecules, while the lower limit of the initial nanoparticles are taken as large anions (Si{sub 12}H{sub 25}{sup -} and Si{sub 12}H{sub 24}{sup -}) to directly link the coagulation module with the nucleation module. And then, by using the coagulation module, the particle number density quickly decreases over several orders of magnitude, whereas the particle size strongly increases. We investigate in particular the growth of the nanoparticles ranging in size from {approx}1 to 50 nm in coagulation processes. The influences of controlled phase shifts between VHF (50 MHz) voltages on the electron density, electron temperature, nanoparticle uniformity, and deposition rate, are carefully studied. It is found from our simulation that the plasma density and nanoparticle density become center high and more uniform as the phase shift increases from 0 to 180 deg. Moreover, the role of phase-shift control in the silane discharge diluted with hydrogen gas is also discussed.

  4. Development and validation of a capillary electrophoresis method with capacitively coupled contactless conductivity detection (CE-C(4) D) for the analysis of amikacin and its related substances.

    PubMed

    El-Attug, Mohamed Nouri; Adams, Erwin; Van Schepdael, Ann

    2012-09-01

    Amikacin is a semisynthetic aminoglycoside antibiotic derived from kanamycin A that lacks a strong UV absorbing chromophore or fluorophore. Due to the physicochemical properties of amikacin and its related substances, CE in combination with capacitively coupled contactless conductivity detection (CE-C(4) D) was chosen. The optimized separation method uses a BGE composed of 20 mM MES adjusted to pH 6.6 by l-histidine and 0.3 mM CTAB that was added as flow modifier in a concentration below the CMC. Ammonium acetate 20 mg.L(-1) was used as internal standard. 30 kV was applied in reverse polarity on a fused silica capillary (73/48 cm; 75 μm id). The optimized separation was obtained in less than 6 min with good linearity (R(2) = 0.9996) for amikacin base. It shows a good precision expressed as RSD on relative peak areas equal to 0.1 and 0.7% for intraday and interday, respectively. The LOD and LOQ are 0.5 mg.L(-1) and 1.7 mg.L(-1) , respectively. PMID:22965725

  5. Absolute CF{sub 2} density and gas temperature measurements by absorption spectroscopy in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas

    SciTech Connect

    Liu, Wen-Yao; Xu, Yong Peng, Fei; Gong, Fa-Ping; Li, Xiao-Song; Zhu, Ai-Min; Liu, Yong-Xin; Wang, You-Nian

    2014-10-15

    Broadband ultraviolet absorption spectroscopy has been used to determine the CF{sub 2} radical density in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas, using the CF{sub 2} A{sup ~1}B{sub 1}←X{sup ~1}A{sub 1} system of absorption spectrum. The rotational temperature of ground state CF{sub 2} and excited state CF was also estimated by using A{sup ~1}B{sub 1}←X{sup ~1}A{sub 1} system and B{sup 2}Δ−X{sup 2}Π system, respectively. The translational gas temperature was deduced from the Doppler width of the Ar{sup *}({sup 3}P{sub 2}) and Ar{sup *}({sup 3}P{sub 0}) metastable atoms absorption line by using the tunable diode laser absorption spectroscopy. The rotational temperatures of the excited state CF are about 100 K higher than those of ground state CF{sub 2}, and about 200 K higher than the translational gas temperatures. The dependences of the radical CF{sub 2} density, electron density, electron temperature, rotational temperature, and gas temperature on the high frequency power and pressure have been analyzed. Furthermore, the production and loss mechanisms of CF{sub 2} radical and the gas heating mechanisms have also been discussed.

  6. Capillary ion electrophoresis-capacitively coupled contactless conductivity detection of inorganic cations in human saliva on a polyvinyl alcohol-coated capillary.

    PubMed

    Mori, Masanobu; Kaseda, Maki; Yamamoto, Tsukasa; Yamada, Sachiko; Itabashi, Hideyuki

    2012-03-01

    Capillary ion electrophoresis-capacitively coupled contactless conductivity detection (CIE-C4D) with a polyvinyl alcohol chemically coated capillary (PVA capillary) was used to analyze inorganic cations (Na(+), K(+), NH(4)(+), Mg(2+), and Ca(2+)) commonly found in human saliva. The PVA capillary, which was made by our laboratory, minimized electro-osmotic flow in the wide pH range of the background electrolyte (BGE), and the PVA layer adsorbed to capillary wall did not affect the conductimetric background level. In this study, we determined an optimized BGE of 30 mM lactic acid/histidine plus 3 mM 18-crown-6 for the CIE-C4D system using the PVA capillary, which could simultaneously improve the separation of Mg(2+) and Ca(2+) from Na(+) and that of K(+) from NH(4)(+). This system obtained highly reproducible separation of cations in human saliva samples within 8 min at 20 kV without deprotonation. The quantifiability of cations in human saliva samples on the CIE-C4D system was demonstrated through identification by ion chromatography with satisfactory results. PMID:22252656

  7. Control of electron energy distributions and plasma characteristics of dual frequency, pulsed capacitively coupled plasmas sustained in Ar and Ar/CF4/O2

    NASA Astrophysics Data System (ADS)

    Song, Sang-Heon; Kushner, Mark J.

    2012-10-01

    The fluxes of radicals and ions to the wafer during plasma processing of microelectronics devices determine the quality of the etch or deposition. These fluxes are largely controlled by controlling the electron energy distribution function f(ɛ) which determines the dissociation patterns of feedstock gases. In quasi-steady state operation, an equilibrium condition for f(ɛ) results from a real time balance between electron sources and sinks. Using pulsed power, electron sources and sinks do not need to instantaneously balance—they only need to balance over the longer pulse period. This provides additional leverage to customize f(ɛ). In this paper, the f(ɛ) in a two-frequency, pulsed capacitively coupled plasma sustained in Ar and Ar/CF4/O2 mixtures are discussed with results from a two-dimensional plasma hydrodynamics model. The f(ɛ) are obtained from a Monte Carlo simulation which includes electron-electron collisions. We found that the f(ɛ) and rate coefficients can be controlled by pulse repetition frequency (PRF) and duty cycle (DC) of the pulsed power in a manner not otherwise easily attainable using continuous excitation. The tail of the f(ɛ) is enhanced with smaller PRF and DC in order to compensate for the electron losses during the power-off portion of the cycle.

  8. A H2 very high frequency capacitively coupled plasma inactivates glyceraldehyde 3-phosphate dehydrogenase(GapDH) more efficiently than UV photons and heat combined

    NASA Astrophysics Data System (ADS)

    Stapelmann, Katharina; Lackmann, Jan-Wilm; Buerger, Ines; Bandow, Julia Elisabeth; Awakowicz, Peter

    2014-02-01

    Plasma sterilization is a promising alternative to commonly used sterilization techniques, because the conventional methods suffer from certain limitations, e.g. incompatibility with heat-sensitive materials, or use of toxic agents. However, plasma-based sterilization mechanisms are not fully understood yet. A low-pressure very high frequency capacitively coupled plasma is used to investigate the impact of a hydrogen discharge on the protein glyceraldehyde 3-phosphate dehydrogenase (GapDH). GapDH is an enzyme of glycolysis. As a part of the central metabolism, it occurs in nearly all organisms from bacteria to humans. The plasma is investigated with absolutely calibrated optical emission spectroscopy in order to identify and to quantify plasma components that can contribute to enzyme inactivation. The contribution of UV photons and heat to GapDH inactivation is investigated separately, and neither seems to be a major factor. In order to investigate the mechanisms of GapDH inactivation by the hydrogen discharge, samples are investigated for etching, induction of amino acid backbone breaks, and chemical modifications. While neither etching nor strand breaks are observed, chemical modifications occur at different amino acid residues of GapDH. Deamidations of asparagines as well as methionine and cysteine oxidations are detected after VHF-CCP treatment. In particular, oxidation of the cysteine in the active centre is known to lead to GapDH inactivation.

  9. Spatial plasma potentials and electron energy distributions in inductively and capacitively coupled plasmas under a weakly collisional and nonlocal electron kinetic regime

    NASA Astrophysics Data System (ADS)

    Lee, Hyo-Chang; Chung, Chin-Wook

    2012-10-01

    Spatial profiles of the plasma potential and electron energy distribution function (EEDF) were measured in inductively and capacitively coupled plasmas (ICP and CCP) under weakly collisional and nonlocal electron kinetic regimes [1]. The measured EEDF at the discharge center was a bi-Maxwellain distribution with low (T1) and high (T2) electron temperature groups at both the ICP and the CCP, while the EEDF at the radial boundary was closely Maxwellian distribution in the ICP due to cutting of the low energy electrons by relatively large ambipolar potential in this discharge regime. The ambipolar potential in the entire radial region was in the scale of Teff -1.5 Teff, where Teff is the effective electron temperature. At the boundary region with the ion mean free path scale, the ambipolar potential increased abruptly and was about Teff,edge/2, where the Teff,edge is the effective electron temperature at the boundary, which corresponds to the presheath scale. These results of the ICP, which are contrary to the ambipolar potential of the CCP in a nearly free-fall regime [2], are caused by relatively high T1 and a small portion of low energy electron group density to total electron density in the ICP under the weakly collisional and nonlocal electron kinetic regimes. [4pt] [1] H. C. Lee and C. W. Chung, Phys. Plasmas 19 033514 (2012).[0pt] [2] V. A. Godyak, V. P. Meytlis, and H. R. Strauss, IEEE Trans. Plasma Sci. 23 728 (1995).

  10. Investigating the formation and the properties of monoalkyl carbonates in aqueous medium using capillary electrophoresis with capacitively coupled contactless conductivity detection.

    PubMed

    Vidal, Denis Tadeu Rajh; Nogueira, Thiago; Saito, Renata Mayumi; do Lago, Claudimir Lucio

    2011-04-01

    Although alkyl carbonic acids (ACAs) and their salts are referred to as instable species in aqueous medium, we demonstrate that a monoalkyl carbonate (MAC) can in fact be easily formed from bicarbonate and an alcohol even in the presence of a high amount of water. A CE system with two capacitively coupled contactless conductivity detectors (C⁴Ds) was used to obtain different parameters about these species and their reactions. Based on the mobilities obtained for a series of alcohols ranging from 1 to 5 carbons, the coefficients of diffusion and the hydrodynamic radii were calculated. When compared with the equivalent carboxylates, MACs have radii systematically smaller. Although the precise pK(a) values of the ACAs could not be obtained, because of the fast decomposition in acid medium, it was possible, for the first time, to show that they are below 4.0. This result suggests that the acidity of an ACA is quite similar to the first hydrogen of H₂CO₃. Using a new approach to indirectly calibrate the C⁴D, the kinetic constants and the equilibrium constants of formation were also obtained. The results suggest that the increase in the chain length makes the MACs less stable and more inert. PMID:21413029

  11. Effects of fast atoms and energy-dependent secondary electron emission yields in PIC/MCC simulations of capacitively coupled plasmas

    NASA Astrophysics Data System (ADS)

    Derzsi, A.; Korolov, I.; Schüngel, E.; Donkó, Z.; Schulze, J.

    2015-05-01

    In most PIC/MCC simulations of radio frequency capacitively coupled plasmas (CCPs) several simplifications are commonly made: (i) fast neutrals are not traced, (ii) heavy particle induced excitation and ionization are neglected, (iii) secondary electron emission from boundary surfaces due to neutral particle impact is not taken into account, and (iv) the secondary electron emission coefficient is assumed to be constant, i.e. independent of the incident particle energy and the surface conditions. Here, we examine the validity of these simplifications under conditions typical for plasma processing applications. We study the effects of including fast neutrals and using realistic energy-dependent secondary electron emission coefficients for ions and fast neutrals in simulations of CCPs operated in argon at 13.56 MHz and at neutral gas pressures between 5 Pa and 100 Pa. We find an increase of the plasma density and the ion flux to the electrodes under most conditions when heavy particles are included realistically in the simulation. The sheath widths are found to be smaller and the simulations are found to diverge at high pressures for high voltage amplitudes in qualitative agreement with experimental findings. By switching individual processes on and off in the simulations we identify their individual effects on the ionization dynamics and plasma parameters. While the gas-phase effects of heavy particle processes are found to be moderate at most conditions, the self-consistent calculation of the effective secondary electron yield proves to be important in simulations of CCPs in order to yield realistic results.

  12. An investigation of Ar metastable state density in low pressure dual-frequency capacitively coupled argon and argon-diluted plasmas

    SciTech Connect

    Liu, Wen-Yao; Xu, Yong Peng, Fei; Guo, Qian; Li, Xiao-Song; Zhu, Ai-Min; Liu, Yong-Xin; Wang, You-Nian

    2015-01-14

    An tunable diode laser absorption spectroscopy has been used to determine the Ar*({sup 3}P{sub 2}) and Ar*({sup 3}P{sub 0}) metastable atoms densities in dual-frequency capacitively coupled plasmas. The effects of different control parameters, such as high-frequency power, gas pressure and content of Ar, on the densities of two metastable atoms and electron density were discussed in single-frequency and dual-frequency Ar discharges, respectively. Particularly, the effects of the pressure on the axial profile of the electron and Ar metastable state densities were also discussed. Furthermore, a simple rate model was employed and its results were compared with experiments to analyze the main production and loss processes of Ar metastable states. It is found that Ar metastable state is mainly produced by electron impact excitation from the ground state, and decayed by diffusion and collision quenching with electrons and neutral molecules. Besides, the addition of CF{sub 4} was found to significantly increase the metastable destruction rate by the CF{sub 4} quenching, especially for large CF{sub 4} content and high pressure, it becomes the dominant depopulation process.

  13. Capacitive label reader

    DOEpatents

    Arlowe, H. Duane

    1985-01-01

    A capacitive label reader includes an outer ring transmitting portion, an inner ring transmitting portion, and a plurality of insulated receiving portions. A label is the mirror-image of the reader except that identifying portions corresponding to the receiving portions are insulated from only one of two coupling elements. Positive and negative pulses applied, respectively, to the two transmitting rings biased a CMOS shift register positively to either a 1 or 0 condition. The output of the CMOS may be read as an indication of the label.

  14. Capacitive label reader

    DOEpatents

    Arlowe, H.D.

    1985-11-12

    A capacitive label reader includes an outer ring transmitting portion, an inner ring transmitting portion, and a plurality of insulated receiving portions. A label is the mirror-image of the reader except that identifying portions corresponding to the receiving portions are insulated from only one of two coupling elements. Positive and negative pulses applied, respectively, to the two transmitting rings biased a CMOS shift register positively to either a 1 or 0 condition. The output of the CMOS may be read as an indication of the label. 5 figs.

  15. Capacitive label reader

    DOEpatents

    Arlowe, H.D.

    1983-07-15

    A capacitive label reader includes an outer ring transmitting portion, an inner ring transmitting portion, and a plurality of insulated receiving portions. A label is the mirror-image of the reader except that identifying portions corresponding to the receiving portions are insulated from only one of two coupling elements. Positive and negative pulses applied, respectively, to the two transmitting rings biased a CMOS shift register positively to either a 1 or 0 condition. The output of the CMOS may be read as an indication of the label.

  16. Infinitely high selective inductively coupled plasma etching of an indium tin oxide binary mask structure for extreme ultraviolet lithography

    SciTech Connect

    Park, Y. R.; Ahn, J. H.; Kim, J. S.; Kwon, B. S.; Lee, N.-E.; Kang, H. Y.; Hwangbo, C. K.; Ahn, Jinho; Seo, Hwan Seok

    2010-07-15

    Currently, extreme ultraviolet lithography (EUVL) is being investigated for next generation lithography. Among the core EUVL technologies, mask fabrication is of considerable importance due to the use of new reflective optics with a completely different configuration than those of conventional photolithography. This study investigated the etching properties of indium tin oxide (ITO) binary mask materials for EUVL, such as ITO (absorber layer), Ru (capping/etch-stop layer), and a Mo-Si multilayer (reflective layer), by varying the Cl{sub 2}/Ar gas flow ratio, dc self-bias voltage (V{sub dc}), and etch time in inductively coupled plasmas. The ITO absorber layer needs to be etched with no loss in the Ru layer on the Mo-Si multilayer for fabrication of the EUVL ITO binary mask structure proposed here. The ITO layer could be etched with an infinitely high etch selectivity over the Ru etch-stop layer in Cl{sub 2}/Ar plasma even with a very high overetch time.

  17. A jet emission model to probe the dynamics of accretion and ejection coupling in black hole X-ray binaries

    NASA Astrophysics Data System (ADS)

    Malzac, Julien

    2016-07-01

    Compact jets are probably the most common form of jets in X-ray binaries and Active Galactic Nuclei. They seem to be present in all sources in the so-called hard X-ray spectral state. They are characterised by a nearly flat Spectral Energy Distribution (SED) extending from the radio to the infrared bands. This emission is usually interpreted as partially self absorbed synchrotron emission from relativistic leptons accelerated in the jet. The observed flat spectral shape requires energy dissipation and acceleration of particules over a wide range of distances along the jet. This distributed energy dissipation is likely to be powered by internal shocks caused by fluctuations of the outflow velocity. I will discuss such an internal shock model in the context of black hole binaries. I will show that internal shocks can produce the observed SEDs and also predict a strong, wavelength dependent, variability that resembles the observed one. The assumed velocity fluctuations of the jet must originate in the accretion flow. The model thus predicts a strong connection between the observable properties of the jet in the radio to IR bands, and the variability of the accretion flow as observed in X-rays. If the model is correct, this offers a unique possibility to probe the dynamics of the coupled accretion and ejection processes leading to the formation of compact jets.

  18. Estimation of Leakage Potential of Selected Sites in Interstate and Tri-State Canals Using Geostatistical Analysis of Selected Capacitively Coupled Resistivity Profiles, Western Nebraska, 2004

    USGS Publications Warehouse

    Vrabel, Joseph; Teeple, Andrew P.; Kress, Wade H.

    2009-01-01

    With increasing demands for reliable water supplies and availability estimates, groundwater flow models often are developed to enhance understanding of surface-water and groundwater systems. Specific hydraulic variables must be known or calibrated for the groundwater-flow model to accurately simulate current or future conditions. Surface geophysical surveys, along with selected test-hole information, can provide an integrated framework for quantifying hydrogeologic conditions within a defined area. In 2004, the U.S. Geological Survey, in cooperation with the North Platte Natural Resources District, performed a surface geophysical survey using a capacitively coupled resistivity technique to map the lithology within the top 8 meters of the near-surface for 110 kilometers of the Interstate and Tri-State Canals in western Nebraska and eastern Wyoming. Assuming that leakage between the surface-water and groundwater systems is affected primarily by the sediment directly underlying the canal bed, leakage potential was estimated from the simple vertical mean of inverse-model resistivity values for depth levels with geometrically increasing layer thickness with depth which resulted in mean-resistivity values biased towards the surface. This method generally produced reliable results, but an improved analysis method was needed to account for situations where confining units, composed of less permeable material, underlie units with greater permeability. In this report, prepared by the U.S. Geological Survey in cooperation with the North Platte Natural Resources District, the authors use geostatistical analysis to develop the minimum-unadjusted method to compute a relative leakage potential based on the minimum resistivity value in a vertical column of the resistivity model. The minimum-unadjusted method considers the effects of homogeneous confining units. The minimum-adjusted method also is developed to incorporate the effect of local lithologic heterogeneity on water

  19. Exploring the possibilities of capacitively coupled contactless conductivity detection in combination with liquid chromatography for the analysis of polar compounds using aminoglycosides as test case.

    PubMed

    Jankovics, Péter; Chopra, Shruti; El-Attug, Mohamed N; Cabooter, Deirdre; Wolfs, Kris; Noszál, Béla; Van Schepdael, Ann; Adams, Erwin

    2015-08-10

    The analysis of highly polar (often charged) compounds which lack a strong UV absorbing chromophore is really challenging. Despite the numerous analytical methods published, the demand for a simple, robust and cheap technique for their analysis still persists. Here, reversed phase (RP) liquid chromatography (LC) with capacitively coupled contactless conductivity detection (C(4)D) was explored for the first time as a possible method for separation and detection of various aminoglycoside (AMG) antibiotics which were taken as typical test compounds: tobramycin (TOB), spectinomycin, streptomycin, amikacin, kanamycin A and kanamycin B. C(4)D was performed using a commercially available as well as a laboratory made cell. As ion-pairing reagents (IPR) four perfluorinated carboxylic acids were used: pentafluoropropionic acid, heptafluorobutyric acid, nonafluoropentanoic acid (NFPA) and pentadecafluorooctanoic acid (PDFOA). 0.125 mM NFPA-acetonitrile (ACN) (90:10) or 0.125 mM PDFOA-ACN (70:30) as mobile phases were suitable to detect TOB with reasonable retention times. However, NFPA was preferred for practical reasons. Its applicable concentration range in the mobile phase was strongly restricted by loss of chromatographic performance at lower levels and excessive background conductivity at higher levels. Overall repeatability and robustness of the method were rather poor which was explained by the relatively low IPR levels. Selectivity between the tested AMGs was mainly influenced by the number of protonated amino groups per molecule making it impossible to separate compounds of equal net charges. Problems encountered with gradient elution, hydrophilic interaction liquid chromatography (HILIC) and separation at high pH without IPRs are also discussed. PMID:25549929

  20. A comparative study of capacitively coupled HBr/He, HBr/Ar plasmas for etching applications: Numerical investigation by fluid model

    SciTech Connect

    Gul, Banat; Aman-ur-Rehman

    2015-10-15

    Fluid model has been applied to perform a comparative study of hydrogen bromide (HBr)/He and HBr/Ar capacitively coupled plasma discharges that are being used for anisotropic etching process. This model has been used to identify the most dominant species in HBr based plasmas. Our simulation results show that the neutral species like H and Br, which are the key player in chemical etching, have bell shape distribution, while ions like HBr{sup +}, Br{sup +}, which play a dominant rule in the physical etching, have double humped distribution and show peaks near electrodes. It was found that the dilution of HBr by Ar and/or He results in an increase in electron density and electron temperature, which results in more ionization and dissociation and hence higher densities of neutral and charged species can be achieved. The ratio of positive ion flux to the neutral flux increases with an increase in additive gas fraction. Compare to HBr/He plasma, the HBr/Ar plasma shows a maximum change in the ion density and flux and hence the etching rate can be considered in the ion-assisted and in the ion-flux etch regime in HBr/Ar discharge. The densities of electron and other dominant species in HBr/Ar plasma are higher than those of HBr/He plasma. The densities and fluxes of the active neutrals and positive ions for etching and subsequently chemical etching versus physical sputtering in HBr/Ar and HBr/He plasmas discharge can be controlled by tuning gas mixture ratio and the desire etching can be achieved.

  1. Effects of Bias Pulsing on Etching of SiO2 Pattern in Capacitively-Coupled Plasmas for Nano-Scale Patterning of Multi-Level Hard Masks.

    PubMed

    Kim, Sechan; Choi, Gyuhyun; Chae, Heeyeop; Lee, Nae-Eung

    2016-05-01

    In order to study the effects of bias pulsing on the etching characteristics of a silicon dioxide (SiO2) layer using multi-level hard mask (MLHM) structures of ArF photoresist/bottom anti-reflected coating/SiO2/amorphous carbon layer (ACL)/SiO2, the effects of bias pulsing conditions on the etch characteristics of a SiO2 layer with an ACL mask pattern in C4F8/CH2F2/O2/Ar etch chemistries were investigated in a dual-frequency capacitively-coupled plasma (CCP) etcher. The effects of the pulse frequency, duty ratio, and pulse-bias power in the 2 MHz low-frequency (LF) power source were investigated in plasmas generated by a 27.12 MHz high-frequency (HF) power source. The etch rates of ACL and SiO2 decreased, but the etch selectivity of SiO2/ACL increased with decreasing duty ratio. When the ACL and SiO2 layers were etched with increasing pulse frequency, no significant change was observed in the etch rates and etch selectivity. With increasing LF pulse-bias power, the etch rate of ACL and SiO2 slightly increased, but the etch selectivity of SiO2/ACL decreased. Also, the precise control of the critical dimension (CD) values with decreasing duty ratio can be explained by the protection of sidewall etching of SiO2 by increased passivation. Pulse-biased etching was successfully applied to the patterning of the nano-scale line and space of SiO2 using an ACL pattern. PMID:27483889

  2. Effect of source frequency and pulsing on the SiO2 etching characteristics of dual-frequency capacitive coupled plasma

    NASA Astrophysics Data System (ADS)

    Kim, Hoe Jun; Jeon, Min Hwan; Mishra, Anurag Kumar; Kim, In Jun; Sin, Tae Ho; Yeom, Geun Young

    2015-01-01

    A SiO2 layer masked with an amorphous carbon layer (ACL) has been etched in an Ar/C4F8 gas mixture with dual frequency capacitively coupled plasmas under variable frequency (13.56-60 MHz)/pulsed rf source power and 2 MHz continuous wave (CW) rf bias power, the effects of the frequency and pulsing of the source rf power on the SiO2 etch characteristics were investigated. By pulsing the rf power, an increased SiO2 etch selectivity was observed with decreasing SiO2 etch rate. However, when the rf power frequency was increased, not only a higher SiO2 etch rate but also higher SiO2 etch selectivity was observed for both CW and pulse modes. A higher CF2/F ratio and lower electron temperature were observed for both a higher source frequency mode and a pulsed plasma mode. Therefore, when the C 1s binding states of the etched SiO2 surfaces were investigated using X-ray photoelectron spectroscopy (XPS), the increase of C-Fx bonding on the SiO2 surface was observed for a higher source frequency operation similar to a pulsed plasma condition indicating the increase of SiO2 etch selectivity over the ACL. The increase of the SiO2 etch rate with increasing etch selectivity for the higher source frequency operation appears to be related to the increase of the total plasma density with increasing CF2/F ratio in the plasma. The SiO2 etch profile was also improved not only by using the pulsed plasma but also by increasing the source frequency.

  3. Capacitively Coupled Resistivity measurements to determine frequency-dependent electrical parameters in periglacial environment—theoretical considerations and first field tests

    NASA Astrophysics Data System (ADS)

    Przyklenk, A.; Hördt, A.; Radić, T.

    2016-08-01

    Capacitively Coupled Resistivity (CCR) is conventionally used to emulate DC resistivity measurements and may provide important information about the ice content of material in periglacial areas. The application of CCR theoretically enables the determination of both electrical parameters, that is, the resistivity and the electrical permittivity, by analysing magnitude and phase shift spectra. The electrical permittivity may dominate the impedance, especially in periglacial areas or regions of hydrogeological interest. However, previous theoretical work suggested that the phase shift may strongly depend on electrode height above ground, implying that electrode height must be known with great accuracy to determine electrical permittivity. Here, we demonstrate with laboratory test measurements, theoretical modelling and by analysing the Jacobian matrix of the inversion that the sensitivity towards electrode height is drastically reduced if the electrical permittivity is frequency dependent in a way that is typical for ice. For the first time, we used a novel broad-band CCR device `Chameleon' for a field test located in one of the ridge galleries beneath the crest of Mount Zugspitze. A permanently ice covered bottom of a tunnel was examined. For the inversion of the measured spectra, the frequency dependence of the electrical parameters was parametrized in three different ways: A Debye Model for pure ices, a Cole-Cole Model for pure ices and a dual Cole-Cole Model including interfacial water additionally. The frequency-dependent resistivity and permittivity spectra obtained from the inversion, including low- and high-frequency limits, agree reasonably well with laboratory and field measurements reported in the literature.

  4. Electron–phonon coupling in Ni-based binary alloys with application to displacement cascade modeling

    NASA Astrophysics Data System (ADS)

    Samolyuk, G. D.; Béland, L. K.; Stocks, G. M.; Stoller, R. E.

    2016-05-01

    Energy transfer between lattice atoms and electrons is an important channel of energy dissipation during displacement cascade evolution in irradiated materials. On the assumption of small atomic displacements, the intensity of this transfer is controlled by the strength of electron–phonon (el–ph) coupling. The el–ph coupling in concentrated Ni-based alloys was calculated using electronic structure results obtained within the coherent potential approximation. It was found that Ni0.5Fe0.5, Ni0.5Co0.5 and Ni0.5Pd0.5 are ordered ferromagnetically, whereas Ni0.5Cr0.5 is nonmagnetic. Since the magnetism in these alloys has a Stoner-type origin, the magnetic ordering is accompanied by a decrease of electronic density of states at the Fermi level, which in turn reduces the el–ph coupling. Thus, the el–ph coupling values for all alloys are approximately 50% smaller in the magnetic state than for the same alloy in a nonmagnetic state. As the temperature increases, the calculated coupling initially increases. After passing the Curie temperature, the coupling decreases. The rate of decrease is controlled by the shape of the density of states above the Fermi level. Introducing a two-temperature model based on these parameters in 10 keV molecular dynamics cascade simulation increases defect production by 10–20% in the alloys under consideration.

  5. Electron phonon coupling in Ni-based binary alloys with application to displacement cascade modeling

    DOE PAGESBeta

    Samolyuk, German D.; Stocks, George Malcolm; Stoller, Roger E.

    2016-04-01

    Energy transfer between lattice atoms and electrons is an important channel of energy dissipation during displacement cascade evolution in irradiated materials. On the assumption of small atomic displacements, the intensity of this transfer is controlled by the strength of electron–phonon (el–ph) coupling. The el–ph coupling in concentrated Ni-based alloys was calculated using electronic structure results obtained within the coherent potential approximation. It was found that Ni0.5Fe0.5, Ni0.5Co0.5 and Ni0.5Pd0.5 are ordered ferromagnetically, whereas Ni0.5Cr0.5 is nonmagnetic. Since the magnetism in these alloys has a Stoner-type origin, the magnetic ordering is accompanied by a decrease of electronic density of states atmore » the Fermi level, which in turn reduces the el–ph coupling. Thus, the el–ph coupling values for all alloys are approximately 50% smaller in the magnetic state than for the same alloy in a nonmagnetic state. As the temperature increases, the calculated coupling initially increases. After passing the Curie temperature, the coupling decreases. The rate of decrease is controlled by the shape of the density of states above the Fermi level. Introducing a two-temperature model based on these parameters in 10 keV molecular dynamics cascade simulation increases defect production by 10–20% in the alloys under consideration.« less

  6. Electron-phonon coupling in Ni-based binary alloys with application to displacement cascade modeling.

    PubMed

    Samolyuk, G D; Béland, L K; Stocks, G M; Stoller, R E

    2016-05-01

    Energy transfer between lattice atoms and electrons is an important channel of energy dissipation during displacement cascade evolution in irradiated materials. On the assumption of small atomic displacements, the intensity of this transfer is controlled by the strength of electron-phonon (el-ph) coupling. The el-ph coupling in concentrated Ni-based alloys was calculated using electronic structure results obtained within the coherent potential approximation. It was found that Ni0.5Fe0.5, Ni0.5Co0.5 and Ni0.5Pd0.5 are ordered ferromagnetically, whereas Ni0.5Cr0.5 is nonmagnetic. Since the magnetism in these alloys has a Stoner-type origin, the magnetic ordering is accompanied by a decrease of electronic density of states at the Fermi level, which in turn reduces the el-ph coupling. Thus, the el-ph coupling values for all alloys are approximately 50% smaller in the magnetic state than for the same alloy in a nonmagnetic state. As the temperature increases, the calculated coupling initially increases. After passing the Curie temperature, the coupling decreases. The rate of decrease is controlled by the shape of the density of states above the Fermi level. Introducing a two-temperature model based on these parameters in 10 keV molecular dynamics cascade simulation increases defect production by 10-20% in the alloys under consideration. PMID:27033732

  7. Bistable Magnetoresistance Switching in Exchange-Coupled CoFe2O4-Fe3O4 Binary Nanocrystal Superlattices by Self-Assembly and Thermal Annealing

    SciTech Connect

    Chen, J; Ye, XC; Oh, SJ; Kikkawa, JM; Kagan, CR; Murray, CB

    2013-02-01

    Self-assembly of multicomponent nanocrystal superlattices provides a modular approach to the design of metamaterials by choosing constituent nanocrystal building blocks with desired physical properties and engineering the interparticle coupling. In this work, we report the self-assembly of binary nanocrystal superlattices composed of magnetically hard CoFe2O4 nanocrystals and magnetically soft Fe3O4 nanocrystals. Both NaZn13- and MgZn2-type CoFe2O4-Fe3O4 binary nanocrystal superlattices have been formed by the liquid-air interfacial assembly approach. Exchange coupling is achieved in both types of binary superlattices after thermal annealing under vacuum at 400 degrees C. The exchange-coupled CoFe2O4-Fe3O4 binary nanocrystal superlattices show single-phase magnetization switching behavior and magnetoresistance switching behavior below 200 K. The NaZn13-type CoFe2O4-Fe3O4 binary nanocrystal superlattices annealed at 500 degrees C even exhibit bistable magnetoresistance switching behavior at room temperature constituting a simple nonvolatile memory function.

  8. Disc-Jet Coupling in the Terzan 5 Neutron Star X-ray Binary EXO 1745-248

    NASA Astrophysics Data System (ADS)

    Tetarenko, A. J.; Bahramian, A.; Sivakoff, G. R.; Tremou, E.; Linares, M.; Tudor, V.; Miller-Jones, J. C. A.; Heinke, C. O.; Chomiuk, L.; Strader, J.; Altamirano, D.; Degenaar, N.; Maccarone, T.; Patruno, A.; Sanna, A.; Wijnands, R.

    2016-04-01

    We present the results of VLA, ATCA, and Swift XRT observations of the 2015 outburst of the transient neutron star X-ray binary (NSXB), EXO 1745-248, located in the globular cluster Terzan 5. Combining (near-) simultaneous radio and X-ray measurements we measure a correlation between the radio and X-ray luminosities of L_R∝ L_X^β with β =1.68^{+0.10}_{-0.09}, linking the accretion flow (probed by X-ray luminosity) and the compact jet (probed by radio luminosity). While such a relationship has been studied in multiple black hole X-ray binaries (BHXBs), this work marks only the third NSXB with such a measurement. Constraints on this relationship in NSXBs are strongly needed, as comparing this correlation between different classes of XB systems is key in understanding the properties that affect the jet production process in accreting objects. Our best fit disc-jet coupling index for EXO 1745-248 is consistent with the measured correlation in NSXB 4U 1728-34 (β = 1.5 ± 0.2) but inconsistent with the correlation we fit using the most recent measurements from the literature of NSXB Aql X-1 (β =0.76^{+0.14}_{-0.15}). While a similar disc-jet coupling index appears to hold across multiple BHXBs in the hard accretion state, this does not appear to be the case with the three NSXBs measured so far. Additionally, the normalization of the EXO 1745-248 correlation is lower than the other two NSXBs, making it one of the most radio faint XBs ever detected in the hard state. We also report the detection of a type-I X-ray burst during this outburst, where the decay timescale is consistent with hydrogen burning.

  9. Disc-jet coupling in the Terzan 5 neutron star X-ray binary EXO 1745-248

    NASA Astrophysics Data System (ADS)

    Tetarenko, A. J.; Bahramian, A.; Sivakoff, G. R.; Tremou, E.; Linares, M.; Tudor, V.; Miller-Jones, J. C. A.; Heinke, C. O.; Chomiuk, L.; Strader, J.; Altamirano, D.; Degenaar, N.; Maccarone, T.; Patruno, A.; Sanna, A.; Wijnands, R.

    2016-07-01

    We present the results of Very Large Array, Australia Telescope Compact Array, and Swift X-ray Telescope observations of the 2015 outburst of the transient neutron star X-ray binary (NSXB), EXO 1745-248, located in the globular cluster Terzan 5. Combining (near-) simultaneous radio and X-ray measurements, we measure a correlation between the radio and X-ray luminosities of L_R∝ L_X^β with β =1.68^{+0.10}_{-0.09}, linking the accretion flow (probed by X-ray luminosity) and the compact jet (probed by radio luminosity). While such a relationship has been studied in multiple black hole X-ray binaries (BHXBs), this work marks only the third NSXB with such a measurement. Constraints on this relationship in NSXBs are strongly needed, as comparing this correlation between different classes of XB systems is key in understanding the properties that affect the jet production process in accreting objects. Our best-fitting disc-jet coupling index for EXO 1745-248 is consistent with the measured correlation in NSXB 4U 1728-34 (β = 1.5 ± 0.2) but inconsistent with the correlation we fit using the most recent measurements from the literature of NSXB Aql X-1 (β =0.76^{+0.14}_{-0.15}). While a similar disc-jet coupling index appears to hold across multiple BHXBs in the hard accretion state, this does not appear to be the case with the three NSXBs measured so far. Additionally, the normalization of the EXO 1745-248 correlation is lower than the other two NSXBs, making it one of the most radio faint XBs ever detected in the hard state. We also report the detection of a type-I X-ray burst during this outburst, where the decay time-scale is consistent with hydrogen burning.

  10. Poly-(3-hexylthiophene) Aggregate Formation in Binary Solvent Mixtures: An Excitonic Coupling Analysis

    NASA Astrophysics Data System (ADS)

    Boucher, David; Johnson, Calynn

    2014-03-01

    We have studied the aggregation behavior of P3HT [Mn ~ 28.2 kDa, regioregularity >96 %, PDI ~ 1.3] in 96 solvent mixtures is studied using UV-Vis absorption spectroscopy. We used Hansen solubility parameters (HSPs) and Spano excitonic coupling analyses to identify correlations between the properties of the solvent mixtures and the extent of structural order of the aggregates. It is clear that the identity of the poor solvent used to drive aggregation has a significant impact on the excitonic coupling behavior and, hence, the structural order of the P3HT aggregates. However, solubility parameter theory does not account nor provide a predictive theory for the observed trends. Instead, qualitative arguments based on the nature of the interactions between the solvents and the polythiophene and hexyl side chain motifs are used to rationalize the kinetics of formation and the observed excitonic coupling characteristics of the P3HT aggregates.