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Sample records for chiral pion-nucleon dynamics

  1. Pion-nucleon scattering in covariant baryon chiral perturbation theory with explicit Delta resonances

    NASA Astrophysics Data System (ADS)

    Yao, De-Liang; Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A. M.; Gegelia, J.; Krebs, H.; Meißner, Ulf-G.

    2016-05-01

    We present the results of a third order calculation of the pion-nucleon scattering amplitude in a chiral effective field theory with pions, nucleons and delta resonances as explicit degrees of freedom. We work in a manifestly Lorentz invariant formulation of baryon chiral perturbation theory using dimensional regularization and the extended on-mass-shell renormalization scheme. In the delta resonance sector, the on mass-shell renormalization is realized as a complex-mass scheme. By fitting the low-energy constants of the effective Lagrangian to the S- and P -partial waves a satisfactory description of the phase shifts from the analysis of the Roy-Steiner equations is obtained. We predict the phase shifts for the D and F waves and compare them with the results of the analysis of the George Washington University group. The threshold parameters are calculated both in the delta-less and delta-full cases. Based on the determined low-energy constants, we discuss the pion-nucleon sigma term. Additionally, in order to determine the strangeness content of the nucleon, we calculate the octet baryon masses in the presence of decuplet resonances up to next-to-next-to-leading order in SU(3) baryon chiral perturbation theory. The octet baryon sigma terms are predicted as a byproduct of this calculation.

  2. Elastic pion-nucleon scattering in chiral perturbation theory: A fresh look

    NASA Astrophysics Data System (ADS)

    Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A.; Krebs, H.; Meißner, Ulf-G.

    2016-07-01

    Elastic pion-nucleon scattering is analyzed in the framework of chiral perturbation theory up to fourth order within the heavy-baryon expansion and a covariant approach based on an extended on-mass-shell renormalization scheme. We discuss in detail the renormalization of the various low-energy constants and provide explicit expressions for the relevant β functions and the finite subtractions of the power-counting breaking terms within the covariant formulation. To estimate the theoretical uncertainty from the truncation of the chiral expansion, we employ an approach which has been successfully applied in the most recent analysis of the nuclear forces. This allows us to reliably extract the relevant low-energy constants from the available scattering data at low energy. The obtained results provide clear evidence that the breakdown scale of the chiral expansion for this reaction is related to the Δ resonance. The explicit inclusion of the leading contributions of the Δ isobar is demonstrated to substantially increase the range of applicability of the effective field theory. The resulting predictions for the phase shifts are in an excellent agreement with the predictions from the recent Roy-Steiner-equation analysis of pion-nucleon scattering.

  3. Chiral representation of the πN scattering amplitude and the pion-nucleon sigma term

    NASA Astrophysics Data System (ADS)

    Alarcón, J. M.; Camalich, J. Martin; Oller, J. A.

    2012-03-01

    We present a novel analysis of the πN scattering amplitude in Lorentz covariant baryon chiral perturbation theory renormalized in the extended-on-mass-shell scheme. This amplitude, valid up to O(p3) in the chiral expansion, systematically includes the effects of the Δ(1232) in the δ-counting, has the right analytic properties, and is renormalization-scale independent. This approach overcomes the limitations that previous chiral analyses of the πN scattering amplitude had, providing an accurate description of the partial wave phase shifts of the Karlsruhe-Helsinki and George-Washington groups up to energies just below the resonance region. We also study the solution of the Matsinos group which focuses on the parameterization of the data at low energies. Once the values of the low-energy constants are determined by adjusting the center-of-mass energy dependence of the amplitude to the scattering data, we obtain predictions on different observables. In particular, we extract an accurate value for the pion-nucleon sigma term, σπN. This allows us to avoid the usual method of extrapolation to the unphysical region of the amplitude. Our study indicates that the inclusion of modern meson-factory and pionic-atom data favors relatively large values of the sigma term. We report the value σπN=59(7)MeV and comment on implications that this result may have.

  4. Axial, induced pseudoscalar, and pion-nucleon form factors in manifestly Lorentz-invariant chiral perturbation theory

    SciTech Connect

    Schindler, M. R.; Fuchs, T.; Scherer, S.; Gegelia, J.

    2007-02-15

    We calculate the nucleon form factors G{sub A} and G{sub P} of the isovector axial-vector current and the pion-nucleon form factor G{sub {pi}}{sub N} in manifestly Lorentz-invariant baryon chiral perturbation theory up to and including order O(p{sup 4}). In addition to the standard treatment including the nucleon and pions, we also consider the axial-vector meson a{sub 1} as an explicit degree of freedom. This is achieved by using the reformulated infrared renormalization scheme. We find that the inclusion of the axial-vector meson effectively results in one additional low-energy coupling constant that we determine by a fit to the data for G{sub A}. The inclusion of the axial-vector meson results in an improved description of the experimental data for G{sub A}, while the contribution to G{sub P} is small.

  5. Baryon fields with UL(3 ) ×UR(3 ) chiral symmetry. V. Pion-nucleon and kaon-nucleon Σ terms

    NASA Astrophysics Data System (ADS)

    Dmitrašinović, V.; Chen, Hua-Xing; Hosaka, Atsushi

    2016-06-01

    We have previously calculated the pion-nucleon Σπ N term in the chiral mixing approach with u ,d flavors only, and found the lower bound Σπ N≥(" close=")mu0+md0)">1 +16/3 sin2θ 3/2 (gA(0 )+gA(3 )) , where gA(0 ),gA(3 ) , are the flavor-singlet and the isovector axial couplings. With presently accepted values of current quark masses, this leads to Σπ N≥58.0 ±4.5 -6.5+11.4 MeV, which is in agreement with the values extracted from experiments, and substantially higher than most previous two-flavor calculations. The causes of this enhancement are: (1) the large, (16/3 ≃5.3 ), purely SUL(2 ) ×SUR(2 ) algebraic factor; (2) the admixture of the [(1 ,1/2 ) ⊕(1/2 ,1 ) ] chiral multiplet component in the nucleon, whose presence has been known for some time, but that had not been properly taken into account, yet. We have now extended these calculations of Σπ N to three light flavors, i.e., to SUL(3 ) ×SUR(3 ) multiplet mixing. Phenomenology of chiral SUL(3 ) ×SUR(3 ) multiplet mixing demands the presence of three chiral SUL(3 ) ×SUR(3 ) multiplets, viz. [(6 ,3 )⊕(3 ,6 )],[(3 ,3 ¯) ⊕(3 ¯,3 ) ] , and [(3 ¯,3 ) ⊕(3 ,3 ¯) ] , in order to successfully reproduce the baryons' flavor-octet and flavor-singlet axial current coupling constants, as well as the baryon anomalous magnetic moments. Here we use these previously obtained results, together with known constraints on the explicit chiral symmetry breaking in baryons to calculate the Σπ N term, but find no change of Σπ N from the above successful two-flavor result. The physical significance of these results lies in the fact that they show no need for q4q ¯ components, and in particular, no need for an s s ¯ component in the nucleon, in order to explain the large "observed" Σπ N value. We also predict the kaon-nucleon σ term ΣK N that is experimentally unknown, but may be calculable in lattice QCD.

  6. Roy-Steiner-equation analysis of pion-nucleon scattering

    NASA Astrophysics Data System (ADS)

    Hoferichter, Martin; Ruiz de Elvira, Jacobo; Kubis, Bastian; Meißner, Ulf-G.

    2016-04-01

    We review the structure of Roy-Steiner equations for pion-nucleon scattering, the solution for the partial waves of the t-channel process ππ → N ¯ N, as well as the high-accuracy extraction of the pion-nucleon S-wave scattering lengths from data on pionic hydrogen and deuterium. We then proceed to construct solutions for the lowest partial waves of the s-channel process πN → πN and demonstrate that accurate solutions can be found if the scattering lengths are imposed as constraints. Detailed error estimates of all input quantities in the solution procedure are performed and explicit parameterizations for the resulting low-energy phase shifts as well as results for subthreshold parameters and higher threshold parameters are presented. Furthermore, we discuss the extraction of the pion-nucleon σ-term via the Cheng-Dashen low-energy theorem, including the role of isospin-breaking corrections, to obtain a precision determination consistent with all constraints from analyticity, unitarity, crossing symmetry, and pionic-atom data. We perform the matching to chiral perturbation theory in the subthreshold region and detail the consequences for the chiral convergence of the threshold parameters and the nucleon mass.

  7. Backward pion-nucleon scattering

    SciTech Connect

    F. Huang; Sibirtsev, Alex; Haidenbauer, Johann; Meissner, Ulf-G.

    2010-02-01

    A global analysis of the world data on differential cross sections and polarization asymmetries of backward pion-nucleon scattering for invariant collision energies above 3 GeV is performed in a Regge model. Including the $N_\\alpha$, $N_\\gamma$, $\\Delta_\\delta$ and $\\Delta_\\beta$ trajectories, we reproduce both angular distributions and polarization data for small values of the Mandelstam variable $u$, in contrast to previous analyses. The model amplitude is used to obtain evidence for baryon resonances with mass below 3 GeV. Our analysis suggests a $G_{39}$ resonance with a mass of 2.83 GeV as member of the $\\Delta_{\\beta}$ trajectory from the corresponding Chew-Frautschi plot.

  8. Invited Parallel Talk: Forward pion-nucleon charge exchange reaction and Regge constraints

    NASA Astrophysics Data System (ADS)

    Huang, Fei; Sibirtsev, A.; Krewald, S.; Hanhart, C.; Haidenbauer, J.; Meißner, U.-G.

    2009-12-01

    We present our recent study of pion-nucleon charge exchange amplitudes above 2 GeV. We analyze the forward pion-nucleon charge exchange reaction data in a Regge model and compare the resulting amplitudes with those from the Karlsruhe-Helsinki and George-Washington-University partial-wave analyses. We explore possible high-energy constraints for theoretical baryon resonance analyses in the energy region above 2 GeV. Our results show that for the pion-nucleon charge exchange reaction, the appropriate energy region for matching meson-nucleon dynamics to diffractive scattering should be around 3 GeV for the helicity flip amplitude.

  9. Quantum-mechanical picture of peripheral chiral dynamics

    SciTech Connect

    Granados, Carlos; Weiss, Christian

    2015-08-28

    The nucleon's peripheral transverse charge and magnetization densities are computed in chiral effective field theory. The densities are represented in first-quantized form, as overlap integrals of chiral light-front wave functions describing the transition of the nucleon to soft pion-nucleon intermediate states. The orbital motion of the pion causes a large left-right asymmetry in a transversely polarized nucleon. As a result, the effect attests to the relativistic nature of chiral dynamics [pion momenta k = O(Mπ)] and could be observed in form factor measurements at low momentum transfer.

  10. Low-energy pion-nucleon scattering

    NASA Astrophysics Data System (ADS)

    Gibbs, W. R.; Ai, Li; Kaufmann, W. B.

    1998-02-01

    An analysis of low-energy charged pion-nucleon data from recent π+/-p experiments is presented. From the scattering lengths and the Goldberger-Miyazawa-Oehme (GMO) sum rule we find a value of the pion-nucleon coupling constant of f2=0.0756+/-0.0007. We also find, contrary to most previous analyses, that the scattering volumes for the P31 and P13 partial waves are equal, within errors, corresponding to a symmetry found in the Hamiltonian of many theories. For the potential models used, the amplitudes are extrapolated into the subthreshold region to estimate the value of the Σ term. Off-shell amplitudes are also provided.

  11. Low-energy pion-nucleon scattering

    SciTech Connect

    Gibbs, W.R.; Ai, L.; Kaufmann, W.B.

    1998-02-01

    An analysis of low-energy charged pion-nucleon data from recent {pi}{sup {plus_minus}}p experiments is presented. From the scattering lengths and the Goldberger-Miyazawa-Oehme (GMO) sum rule we find a value of the pion-nucleon coupling constant of f{sup 2}=0.0756{plus_minus}0.0007. We also find, contrary to most previous analyses, that the scattering volumes for the P{sub 31} and P{sub 13} partial waves are equal, within errors, corresponding to a symmetry found in the Hamiltonian of many theories. For the potential models used, the amplitudes are extrapolated into the subthreshold region to estimate the value of the {Sigma} term. Off-shell amplitudes are also provided. {copyright} {ital 1998} {ital The American Physical Society}

  12. Nuclear chiral dynamics and thermodynamics

    NASA Astrophysics Data System (ADS)

    Holt, Jeremy W.; Kaiser, Norbert; Weise, Wolfram

    2013-11-01

    This presentation reviews an approach to nuclear many-body systems based on the spontaneously broken chiral symmetry of low-energy QCD. In the low-energy limit, for energies and momenta small compared to a characteristic symmetry breaking scale of order 1 GeV, QCD is realized as an effective field theory of Goldstone bosons (pions) coupled to heavy fermionic sources (nucleons). Nuclear forces at long and intermediate distance scales result from a systematic hierarchy of one- and two-pion exchange processes in combination with Pauli blocking effects in the nuclear medium. Short distance dynamics, not resolved at the wavelengths corresponding to typical nuclear Fermi momenta, are introduced as contact interactions between nucleons. Apart from a set of low-energy constants associated with these contact terms, the parameters of this theory are entirely determined by pion properties and low-energy pion-nucleon scattering observables. This framework (in-medium chiral perturbation theory) can provide a realistic description of both isospin-symmetric nuclear matter and neutron matter, with emphasis on the isospin-dependence determined by the underlying chiral NN interaction. The importance of three-body forces is emphasized, and the role of explicit Δ(1232)-isobar degrees of freedom is investigated in detail. Nuclear chiral thermodynamics is developed and a calculation of the nuclear phase diagram is performed. This includes a successful description of the first-order phase transition from a nuclear Fermi liquid to an interacting Fermi gas and the coexistence of these phases below a critical temperature Tc. Density functional methods for finite nuclei based on this approach are also discussed. Effective interactions, their density dependence and connections to Landau Fermi liquid theory are outlined. Finally, the density and temperature dependences of the chiral (quark) condensate are investigated.

  13. Remarks on the pion-nucleon σ-term

    NASA Astrophysics Data System (ADS)

    Hoferichter, Martin; Ruiz de Elvira, Jacobo; Kubis, Bastian; Meißner, Ulf-G.

    2016-09-01

    The pion-nucleon σ-term can be stringently constrained by the combination of analyticity, unitarity, and crossing symmetry with phenomenological information on the pion-nucleon scattering lengths. Recently, lattice calculations at the physical point have been reported that find lower values by about 3σ with respect to the phenomenological determination. We point out that a lattice measurement of the pion-nucleon scattering lengths could help resolve the situation by testing the values extracted from spectroscopy measurements in pionic atoms.

  14. Isospin breaking in low-energy pion-nucleon scattering

    SciTech Connect

    Gibbs, W.R.; Ai, L.; Kaufmann, W.B.

    1995-05-08

    We have analyzed low-energy pion-nucleon data for isospin invariance by comparing charge-exchange amplitudes derived from charge-exchange data with those predicted from recent {pi}{sup {plus_minus}}{ital p} elastic data through the application of isospin invariance. A discrepancy of the order of 7% is observed beyond the contributions of the {pi}{sup {plus_minus}}{ital p} Coulomb interaction and the hadronic mass differences.

  15. Pion-nucleon scattering in the Skyrme model and the P-wave Born amplitudes

    NASA Astrophysics Data System (ADS)

    Hayashi, A.; Saito, S.; Uehara, M.

    1991-03-01

    We treat fluctuating pion fields around a rotating Skyrmion by means of Dirac's quantization method. The rotational collective motion of the Skyrmion is described by collective coordinates, and conventional gauge-fixing conditions are imposed. Taking into account all the relevant terms at the tree level appearing in the Hamiltonian, we show that pion-nucleon scattering amplitudes exhibit the P-wave Born amplitudes attributed to the Yukawa coupling of order √Nc , which is consistent with the prediction of chiral symmetry such as the Adler-Weisberger relation. This resolves the difficulty that the Skyrme model predicts a wrong Nc dependence for the coupling of order N-3/2c.

  16. Light-front representation of chiral dynamics in peripheral transverse densities

    DOE PAGESBeta

    Granados, Carlos G.; Weiss, Christian

    2015-07-31

    The nucleon's electromagnetic form factors are expressed in terms of the transverse densities of charge and magnetization at fixed light-front time. At peripheral transverse distances b = O(M_pi^{-1}) the densities are governed by chiral dynamics and can be calculated model-independently using chiral effective field theory (EFT). We represent the leading-order chiral EFT results for the peripheral transverse densities as overlap integrals of chiral light-front wave functions, describing the transition of the initial nucleon to soft pion-nucleon intermediate states and back. The new representation (a) explains the parametric order of the peripheral transverse densities; (b) establishes an inequality between the spin-independentmore » and -dependent densities; (c) exposes the role of pion orbital angular momentum in chiral dynamics; (d) reveals a large left-right asymmetry of the current in a transversely polarized nucleon and suggests a simple interpretation. The light-front representation enables a first-quantized, quantum-mechanical view of chiral dynamics that is fully relativistic and exactly equivalent to the second-quantized, field-theoretical formulation. It relates the charge and magnetization densities measured in low-energy elastic scattering to the generalized parton distributions probed in peripheral high-energy scattering processes. The method can be applied to nucleon form factors of other operators, e.g. the energy-momentum tensor.« less

  17. Light-front representation of chiral dynamics in peripheral transverse densities

    SciTech Connect

    Granados, Carlos G.; Weiss, Christian

    2015-07-31

    The nucleon's electromagnetic form factors are expressed in terms of the transverse densities of charge and magnetization at fixed light-front time. At peripheral transverse distances b = O(M_pi^{-1}) the densities are governed by chiral dynamics and can be calculated model-independently using chiral effective field theory (EFT). We represent the leading-order chiral EFT results for the peripheral transverse densities as overlap integrals of chiral light-front wave functions, describing the transition of the initial nucleon to soft pion-nucleon intermediate states and back. The new representation (a) explains the parametric order of the peripheral transverse densities; (b) establishes an inequality between the spin-independent and -dependent densities; (c) exposes the role of pion orbital angular momentum in chiral dynamics; (d) reveals a large left-right asymmetry of the current in a transversely polarized nucleon and suggests a simple interpretation. The light-front representation enables a first-quantized, quantum-mechanical view of chiral dynamics that is fully relativistic and exactly equivalent to the second-quantized, field-theoretical formulation. It relates the charge and magnetization densities measured in low-energy elastic scattering to the generalized parton distributions probed in peripheral high-energy scattering processes. The method can be applied to nucleon form factors of other operators, e.g. the energy-momentum tensor.

  18. A New Pion-Nucleon Partial Wave Analysis

    NASA Astrophysics Data System (ADS)

    Sadler, Michael; Watson, Shon; Stahov, Jugoslav

    2006-10-01

    Existing determinations of the masses, widths and decay modes of low-lying excited states of the nucleon, as compiled in the Review of Particle Physics, are determined from energy-independent partial wave analyses of pion-nucleon scattering data. For the N*(1440) and most other resonances under 2 GeV, the analyses cited are the Karlsruhe-Helsinki, Carnegie Mellon-Berkeley and Kent State analyses, the latter of which used the elastic amplitudes from the other two. The data included in these analyses were published before 1980. Other analyses, notably the recent ones from George Washington University and the Pittsburgh-Argonne group, are ``not used for averages, fits, limits, etc.'' Complete sets of measurements (differential cross sections, analyzing powers and spin rotation parameters) have been measured in the N*(1440) resonance region since 1980, culminating in the Crystal Ball program at BNL to measure all-neutral final states (charge exchange, multiple pi-zero final states, and inverse photoproduction). A new partial wave analysis of the Karlsruhe-Helsinki type has been started by Abilene Christian University, University of Tuzla, and Rudjer Boskovic Institute. The analysis is constrained by fixed-t and interior hyperbolic dispersion relations. Comparisons of the new analysis to modern experimental data and to previous analyses will be presented.

  19. Pion-nucleon charge exchange amplitudes above 2 GeV

    NASA Astrophysics Data System (ADS)

    Huang, F.; Sibirtsev, A.; Krewald, S.; Hanhart, C.; Haidenbauer, J.; Meißner, U.-G.

    2009-04-01

    The amplitudes for the pion-nucleon charge exchange reaction of the Karlsruhe-Helsinki and the George-Washington-University partial-wave analyses are compared with those of a Regge-cut model with the aim to explore the possibility to provide high-energy constraints for theoretical baryon resonance analyses in the energy region above 2GeV.

  20. Chiral Dynamics 2006

    NASA Astrophysics Data System (ADS)

    Ahmed, Mohammad W.; Gao, Haiyan; Weller, Henry R.; Holstein, Barry

    2007-10-01

    pt. A. Plenary session. Opening remarks: experimental tests of chiral symmetry breaking / A. M. Bernstein. [Double pie symbols] scattering / H. Leutwyler. Chiral effective field theory in a [Triangle]-resonance region / V. Pascalutsa. Some recent developments in chiral perturbation theory / Ulf-G. Mei ner. Chiral extrapolation and nucleon structure from the lattice / R.D. Young. Recent results from HAPPEX / R. Michaels. Chiral symmetries and low energy searches for new physics / M.J. Ramsey-Musolf. Kaon physics: recent experimental progress / M. Moulson. Status of the Cabibbo angle / V. Cirigliano. Lattice QCD and nucleon spin structure / J.W. Negele. Spin sum rules and polarizabilities: results from Jefferson lab / J-P Chen. Compton scattering and nucleon polarisabilities / Judith A. McGovern. Virtual compton scattering at MIT-bates / R. Miskimen. Physics results from the BLAST detector at the BATES accelerator / R.P. Redwine. The [Pie sympbol]NN system, recent progress / C. Hanhart. Application of chiral nuclear forces to light nuclei / A. Nogga. New results on few-body experiments at low energy / Y. Nagai. Few-body lattice calculations / M.J. Savage. Research opportunities at the upgraded HI?S facility / H.R. Weller -- pt. B. Goldstone boson dynamics. Working group summary: Goldstone Boson dynamics / G. Colangelo and S. Giovannella. Recent results on radiative Kaon decays from NA48 and NA48/2 / S.G. López. Cusps in K-->3 [Pie symbol] decays / B. Kubis. Recent KTeV results on radiative Kaon decays / M.C. Ronquest. The [Double pie symbols] scattering amplitude / J.R. Peláez. Determination of the Regge parameters in the [Double pie symbols] scattering amplitude / I. Caprini. e+e- Hadronic cross section measurement at DA[symbol]NE with the KLOE detector / P. Beltrame. Measurement of the form factors of e+e- -->2([Pie symbol]+[Pie symbol]-), pp and the resonant parameters of the heavy charmonia at BES / H. Hu. Measurement of e+e- multihadronic cross section below 4

  1. Light-front representation of chiral dynamics with Δ isobar and large- N c relations

    NASA Astrophysics Data System (ADS)

    Granados, C.; Weiss, C.

    2016-06-01

    Transverse densities describe the spatial distribution of electromagnetic current in the nucleon at fixed light-front time. At peripheral distances b = O( M π - 1 ) the densities are governed by chiral dynamics and can be calculated model-independently using chiral effective field theory (EFT). Recent work has shown that the EFT results can be represented in first-quantized form, as overlap integrals of chiral light-front wave functions describing the transition of the nucleon to soft-pion-nucleon intermediate states, resulting in a quantum-mechanical picture of the peripheral transverse densities. We now extend this representation to include intermediate states with Δ isobars and implement relations based on the large- N c limit of QCD. We derive the wave function overlap formulas for the Δ contributions to the peripheral transverse densities by way of a three-dimensional reduction of relativistic chiral EFT expressions. Our procedure effectively maintains rotational invariance and avoids the ambiguities with higher-spin particles in the light-front time-ordered approach. We study the interplay of π N and πΔ intermediate states in the quantum-mechanical picture of the densities in a transversely polarized nucleon. We show that the correct N c -scaling of the charge and magnetization densities emerges as the result of the particular combination of currents generated by intermediate states with degenerate N and Δ. The off-shell behavior of the chiral EFT is summarized in contact terms and can be studied easily. The methods developed here can be applied to other peripheral densities and to moments of the nucleon's generalized parton distributions.

  2. Polarization analysis of vector-meson production in pion-nucleon interactions

    NASA Astrophysics Data System (ADS)

    Arash, Firooz; Habibi, Mohammad F.

    1993-07-01

    In view of the growing (though still incomplete) set of data on vector-meson production in pion-nucleon interactions, the polarization structure of this reaction is presented, together with polarization tests of one-particle-exchange processes in the s and t channels, as well as polarization tests for the Skyrmion model. The amplitude-observable relations are exhibited in the helicity, transversity, and planar-transverse frames. The desirable direction of future experimental programs is also outlined.

  3. a Phenomenological Determination of the Pion-Nucleon Scattering Lengths from Pionic Hydrogen

    NASA Astrophysics Data System (ADS)

    Ericson, T. E. O.; Loiseau, B.; Wycech, S.

    A model independent expression for the electromagnetic corrections to a phenomenological hadronic pion-nucleon (πN) scattering length ah, extracted from pionic hydrogen, is obtained. In a non-relativistic approach and using an extended charge distribution, these corrections are derived up to terms of order α2 log α in the limit of a short-range hadronic interaction. We infer ahπ ^-p=0.0870(5)m-1π which gives for the πNN coupling through the GMO relation g2π ^± pn/(4π )=14.04(17).

  4. The width of the Roper resonance in baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Gegelia, Jambul; Meißner, Ulf-G.; Yao, De-Liang

    2016-09-01

    We calculate the width of the Roper resonance at next-to-leading order in a systematic expansion of baryon chiral perturbation theory with pions, nucleons, and the delta and Roper resonances as dynamical degrees of freedom. Three unknown low-energy constants contribute up to the given order. One of them can be fixed by reproducing the empirical value for the width of the Roper decay into a pion and a nucleon. Assuming that the remaining two couplings of the Roper interaction take values equal to those of the nucleon, the result for the width of the Roper decaying into a nucleon and two pions is consistent with the experimental value.

  5. A relativistic meson-exchange model of pion-nucleon scattering

    SciTech Connect

    Lee, T.S.H.; Hung, C.T.; Yang, S.N.

    1995-08-01

    Pion-nucleon scattering is investigated using the Kadshevsky three-dimensional reduction of the Bethe-Salpeter equation. The resulting potential includes the direct and crossed N and {Delta} terms, and the t-channel {sigma}- and {rho}-exchange terms. The nucleon-pole condition is imposed to define the renormalization of the nucleon mass and the {pi}NN coupling constant. A mixture of the scalar and vector {sigma}{pi}{pi} couplings is introduced to simulate the broad width of the s-wave correlated two-pion exchange mechanism. Good descriptions of the {pi}N phase shifts up to 400 MeV have been obtained in all S- and P-waves. The off-shell behavior for our model differs significantly from that obtained using different reductions. A paper describing our results was published.

  6. Pion-Nucleon Scattering and Analysis from threshold to the N*(1440) Resonance Region

    NASA Astrophysics Data System (ADS)

    Sadler, Michael; Watson, Shon; Stahov, Jugoslav

    2008-10-01

    Many measurements for pion-nucleon scattering from threshold to the N*(1440) resonance region have been made since 1980, when the landmark Karlsruhe-Helsinki (KH) and Carnegie Mellon-Berkeley (CMB) partial wave analyses (PWA) were completed. These measurements consist of differential cross sections and analyzing powers for elastic scattering and charge exchange. Spin rotation parameters for elastic scattering in the momentum interval 0.4 -- 0.7 GeV/c have also been obtained. The program culminated with measurements of π-p -> Neutrals (charge exchange, multiple pi-zero final states, eta production, and inverse photoproduction) using the Crystal Ball at BNL. Resonance parameters for the N*(1440) in the Review of Particle Physics by the Particle Data Group have been obtained from the KH and CMB analyses. The 2006 edition also includes the analysis by George Washington University (GWU) ``for averages, fits, limits, etc.'', but the parameters were unchanged. An overview of the data will be presented along with comparisons to PWA.

  7. Determination of the pion-nucleon coupling constant and scattering lengths

    NASA Astrophysics Data System (ADS)

    Ericson, T. E.; Loiseau, B.; Thomas, A. W.

    2002-07-01

    We critically evaluate the isovector Goldberger-Miyazawa-Oehme (GMO) sum rule for forward πN scattering using the recent precision measurements of π-p and π-d scattering lengths from pionic atoms. We deduce the charged-pion-nucleon coupling constant, with careful attention to systematic and statistical uncertainties. This determination gives, directly from data, g2c(GMO)/ 4π=14.11+/-0.05(statistical)+/-0.19(systematic) or f2c/4π=0.0783(11). This value is intermediate between that of indirect methods and the direct determination from backward np differential scattering cross sections. We also use the pionic atom data to deduce the coherent symmetric and antisymmetric sums of the pion-proton and pion-neutron scattering lengths with high precision, namely, (aπ-p+aπ-n)/2=[- 12+/-2(statistical)+/-8(systematic)]×10-4 m-1π and (aπ-p-aπ- n)/2=[895+/-3(statistical)+/-13 (systematic)]×10-4 m-1π. For the need of the present analysis, we improve the theoretical description of the pion-deuteron scattering length.

  8. The effective chiral Lagrangian from the theta term

    SciTech Connect

    Mereghetti, E.; Hockings, W.H.; Kolck, U. van

    2010-11-15

    We construct the effective chiral Lagrangian involving hadronic and electromagnetic interactions originating from the QCD {theta}-bar term. We impose vacuum alignment at both quark and hadronic levels, including field redefinitions to eliminate pion tadpoles. We show that leading time-reversal-violating (TV) hadronic interactions are related to isospin-violating interactions that can in principle be determined from charge-symmetry-breaking experiments. We discuss the complications that arise from TV electromagnetic interactions. Some implications of the expected sizes of various pion-nucleon TV interactions are presented, and the pion-nucleon form factor is used as an example.

  9. Including the {delta}(1232) resonance in baryon chiral perturbation theory

    SciTech Connect

    Hacker, C.; Wies, N.; Scherer, S.; Gegelia, J.

    2005-11-01

    Baryon chiral perturbation theory with explicit {delta}(1232) degrees of freedom is considered. The most general interactions of pions, nucleons, and {delta} consistent with all underlying symmetries as well as with the constraint structure of higher-spin fields are constructed. By use of the extended on-mass-shell renormalization scheme, a manifestly Lorentz-invariant effective-field theory with a systematic power counting is obtained. As applications, we discuss the mass of the nucleon, the pion-nucleon {sigma} term, and the pole of the {delta} propagator.

  10. Chiral Gauge Dynamics and Dynamical Supersymmetry Breaking

    SciTech Connect

    Poppitz, Erich; Unsal, Mithat; /SLAC /Stanford U.

    2009-05-07

    We study the dynamics of a chiral SU(2) gauge theory with a Weyl fermion in the I = 3/2 representation and of its supersymmetric generalization. In the former, we find a new and exotic mechanism of confinement, induced by topological excitations that we refer to as magnetic quintets. The supersymmetric version was examined earlier in the context of dynamical supersymmetry breaking by Intriligator, Seiberg, and Shenker, who showed that if this gauge theory confines at the origin of moduli space, one may break supersymmetry by adding a tree level superpotential. We examine the dynamics by deforming the theory on S{sup 1} x R{sup 3}, and show that the infrared behavior of this theory is an interacting CFT at small S{sup 1}. We argue that this continues to hold at large S{sup 1}, and if so, that supersymmetry must remain unbroken. Our methods also provide the microscopic origin of various superpotentials in SQCD on S{sup 1} x R{sup 3}--which were previously obtained by using symmetry and holomorphy--and resolve a long standing interpretational puzzle concerning a flux operator discovered by Affleck, Harvey, and Witten. It is generated by a topological excitation, a 'magnetic bion', whose stability is due to fermion pair exchange between its constituents. We also briefly comment on composite monopole operators as leading effects in two dimensional antiferromagnets.

  11. Measurements of observables in the pion-nucleon system, nuclear a- dependence of heavy quark production and rare decays of D and B mesons

    SciTech Connect

    Sadler, M.E.; Isenhower, L.D.

    1992-02-15

    This report discusses research on the following topics: pion-nucleon interactions; detector tomography facility; nuclear dependence of charm and beauty quark production and a study of two-prong decays of neutral D and B mesons; N* collaboration at CEBAF; and pilac experiments. (LSP)

  12. Dynamics of the chiral transition

    SciTech Connect

    Gavin, S.

    1994-07-01

    Measurements of disoriented chiral condensates (DCC) in heavy ion collisions at RHIC can yield fundamental information on the nature of the QCD phase transition. I review theoretical efforts to understand DCC formation and present work in progress on possible experimental ramifications.

  13. Dynamics of the chiral transition

    SciTech Connect

    Gavin, S.

    1995-07-10

    Measurements of disoriented chiral condensates (DCC) in heavy ion collisions at RHIC can yield fundamental information on the nature of the QCD phase transition. I review theoretical efforts to understand DCC formation and present work in progress on their possible experimental ramifications. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  14. {Lambda}* hypernuclei with chiral dynamics

    SciTech Connect

    Uchino, Toshitaka; Hyodo, Tetsuo; Oka, Makoto

    2011-10-21

    As a strangeness S = -1 and baryon number B = 2 system, the two-body bound state of {Lambda}* = {Lambda}(1405) and a nucleon is studied. To solve the {Lambda}*N system, we construct the {Lambda}*N potential by extending the Juelich model with couplings estimated in the chiral unitary approach. We have the {Lambda}*N quasi-bound state with the mass, M{sub {Lambda}}*N{approx}2366 MeV which is shallowly bound with the binding energy B{approx}9 MeV in terms of the K-barNN system. Decay width of the fall apart process, where the {Lambda}*N resonance decays to {pi}{Sigma}N with a nucleon being as a spectator, is estimated to be {Gamma}{sub F.A}{approx}49 MeV.

  15. On Gauge Independent Dynamical Chiral Symmetry Breaking

    SciTech Connect

    Bashir, A.; Raya, A.

    2006-09-25

    Schwinger-Dyson equations (SDEs) are an ideal framework to study nonperturbative phenomena such as dynamical chiral symmetry breaking (DCSB). Loss of gauge invariance is an obstacle to achieve fully reliable predictions from these equations. In addition to Ward-Green-Takahashi identity (WGTI), Landau-Khalatnikov-Fradkin transformations (LKFT) also play an important role in restoring the said invariance at the level of physical observables. On one hand, they impose useful constraints on the transverse part of the fermion-boson vertex and on the other, they govern the change in dynamically generated fermion propagator with a variation of gauge. We consider the latter in this article and study the gauge (in)dependence of chiral condensate in quantum electrodynamics in (2+1) space-time dimensions (QED3)

  16. Threshold pion production in proton-proton collisions at NNLO in chiral EFT

    NASA Astrophysics Data System (ADS)

    Baru, V.; Epelbaum, E.; Filin, A. A.; Hanhart, C.; Krebs, H.; Myhrer, F.

    2016-05-01

    The reaction NN → NN π offers a good testing ground for chiral effective field theory at intermediate energies. It challenges our understanding of the first inelastic channel in nucleon-nucleon scattering and of the charge symmetry breaking pattern in hadronic reactions. In our previous studies, we presented a complete calculation of the pion production operator for s -wave pions up-to-and-including next-to-next-to-leading order (NNLO) in the formulation of chiral effective field theory, which includes pions, nucleons and Δ(1232) degrees of freedom. In this paper we calculate the near-threshold cross section for the pp → d π+ reaction by performing the convolution of the obtained operators with nuclear wave functions based on modern phenomenological and chiral potentials. The available chiral NN wave functions are constructed with a cutoff comparable with the momentum transfer scale inherent in pion production reactions. Hence, a significant portion of the dynamical intermediate-range physics is thereby cut off by them. On the other hand, the NNLO amplitudes evaluated with phenomenological wave functions appear to be largely independent of the NN model used and give corrections to the dominant leading-order contributions as expected from dimensional analysis. The result gives support to the counting scheme used to classify the pion production operators, which is a precondition for a reliable investigation of the chirally suppressed neutral pion production. The explicit inclusion of the Δ(1232) is found to be important but smaller than expected due to cancellations.

  17. Skyrmion dynamics in chiral ferromagnets

    NASA Astrophysics Data System (ADS)

    Komineas, Stavros; Papanicolaou, Nikos

    2015-08-01

    We study the dynamics of skyrmions in Dzyaloshinskii-Moriya materials with easy-axis anisotropy. An important link between topology and dynamics is established through the construction of unambiguous conservation laws obtained earlier in connection with magnetic bubbles and vortices. In particular, we study the motion of a topological skyrmion with skyrmion number Q =1 and a nontopological skyrmionium with Q =0 under the influence of an applied field gradient. The Q =1 skyrmion undergoes Hall motion perpendicular to the direction of the field gradient with a drift velocity proportional to the gradient. In contrast, the nontopological Q =0 skyrmionium is accelerated in the direction of the field gradient, thus exhibiting ordinary Newtonian motion. When the applied field is switched off the Q =1 skyrmion is spontaneously pinned around a fixed guiding center, whereas the Q =0 skyrmionium moves with constant velocity v . We give a systematic calculation of a skyrmionium traveling with any constant velocity v that is smaller than a critical velocity vc.

  18. Pion momentum distributions in the nucleon in chiral effective theory

    SciTech Connect

    Burkardt, Matthias R.; Hendricks, K. S.; Ji, Cheung Ryong; Melnitchouk, Wally; Thomas, Anthony W.

    2013-03-01

    We compute the light-cone momentum distributions of pions in the nucleon in chiral effective theory using both pseudovector and pseudoscalar pion--nucleon couplings. For the pseudovector coupling we identify $\\delta$-function contributions associated with end-point singularities arising from the pion-nucleon rainbow diagrams, as well as from pion tadpole diagrams which are not present in the pseudoscalar model. Gauge invariance is demonstrated, to all orders in the pion mass, with the inclusion of Weinberg-Tomozawa couplings involving operator insertions at the $\\pi NN$ vertex. The results pave the way for phenomenological applications of pion cloud models that are manifestly consistent with the chiral symmetry properties of QCD.

  19. Chiral Restoration in a Nuclear Medium ---Probed by S-Wave Pion Dynamics---

    NASA Astrophysics Data System (ADS)

    Kienle, P.

    Using 500 MeV (d,^3He π^-) pion transfer reactions in recoil free kinematics, pionic 1s-states were populated in the ^{115,119,123}Sn isotopes and their binding energies and widths determined by precision missing mass spectroscopy. Using these data and corresponding ones from iso-scalar light nuclei nuclei, ^{16}O, ^{20}Ne and ^{28}Si, we determined the pion nucleus s-wave strength parameters, b_0, b_1, Re B_0, and Im B_0. By comparison of the iso-vector pion nucleon strength, determined from pionic hydrogen X-ray spectroscopy b_1^{free}, with the b_1 in a nuclear medium scaled to the density ρ(0), we deduced a scaling factor, the square of the pion decay constant in the vacuum and in nuclear medium, as R = b_1^{free} / b_1 = f^2_{π}(ρ_0)/f^2_{π} = 0.64. Thus from the observed increase of the pion s-wave iso-vector strength in a nuclear medium a reduction of f^2_{π}, the order parameter of chiral symme try breaking, is indicated in accordance with theoretical expectations. This finding is supported by recent π^+ and π^- scattering experiments. A short outlook is given on a future program at RIBF in RIKEN for precision studies of deeply bound 1s-states in heavy nuclei.

  20. Pion-nucleon correlations in finite nuclei in a relativistic framework: Effects on the shell structure

    NASA Astrophysics Data System (ADS)

    Litvinova, Elena

    2016-04-01

    The relativistic particle-vibration coupling (RPVC) model is extended by the inclusion of isospin-flip excitation modes into the phonon space, introducing a new mechanism of dynamical interaction between nucleons with different isospin in the nuclear medium. Protons and neutrons exchange by collective modes which are formed by isovector π and ρ-mesons, in turn, softened considerably because of coupling to nucleons of the medium. These modes are investigated within the proton-neutron relativistic random phase approximation (pn-RRPA) and relativistic proton-neutron time blocking approximation (pn-RTBA). The appearance of isospin-flip states with sizable transition probabilities at low energies points out that they are likely to couple to the single-particle degrees of freedom and, in addition to isoscalar low-lying phonons, to modify their spectroscopic characteristics. Such a coupling is quantified for the shell structure of 100,132Sn and found significant for the location of the dominant single-particle states.

  1. Measurements of observables in the pion-nucleon system, nuclear a- dependence of heavy quark production and rare decays of D and B mesons. Progress report, 1 December, 1990--15 February, 1992

    SciTech Connect

    Sadler, M.E.; Isenhower, L.D.

    1992-02-15

    This report discusses research on the following topics: pion-nucleon interactions; detector tomography facility; nuclear dependence of charm and beauty quark production and a study of two-prong decays of neutral D and B mesons; N* collaboration at CEBAF; and pilac experiments. (LSP)

  2. Comparison of the extended linear {sigma} model and chiral perturbation theory

    SciTech Connect

    Alvarez, W.P.; Kubodera, K.; Myhrer, F.

    2005-09-01

    The pion-nucleon-scattering amplitudes are calculated in tree approximation with the use of the extended linear sigma model (ELSM) as well as heavy-baryon chiral perturbation theory (HB{chi}PT), and the nonrelativistic forms of the ELSM results are compared with those of HB{chi}PT. We find that the amplitudes obtained in ELSM do not agree with those derived from the more fundamental effective approach, HB{chi}PT.

  3. Chiral dynamics and peripheral transverse densities

    SciTech Connect

    Granados, Carlos G.; Weiss, Christian

    2014-01-01

    In the partonic (or light-front) description of relativistic systems the electromagnetic form factors are expressed in terms of frame-independent charge and magnetization densities in transverse space. This formulation allows one to identify the chiral components of nucleon structure as the peripheral densities at transverse distances b = O(M{sub {pi}}{sup -1}) and compute them in a parametrically controlled manner. A dispersion relation connects the large-distance behavior of the transverse charge and magnetization densities to the spectral functions of the Dirac and Pauli form factors near the two--pion threshold at timelike t = 4 M{ sub {pi}}{sup 2}, which can be computed in relativistic chiral effective field theory. Using the leading-order approximation we (a) derive the asymptotic behavior (Yukawa tail) of the isovector transverse densities in the "chiral" region b = O(M{sub {pi}}{sup -1}) and the "molecular" region b = O(M{sub N}{sup 2}/M{sub {pi}}{sup 3}); (b) perform the heavy-baryon expansion of the transverse densities; (c) explain the relative magnitude of the peripheral charge and magnetization densities in a simple mechanical picture; (d) include Delta isobar intermediate states and study the peripheral transverse densities in the large-N{ sub c} limit of QCD; (e) quantify the region of transverse distances where the chiral components of the densities are numerically dominant; (f) calculate the chiral divergences of the b{sup 2}-weighted moments of the isovector transverse densities (charge and anomalous magnetic radii) in the limit M{sub {pi}} -> 0 and determine their spatial support. Our approach provides a concise formulation of the spatial structure of the nucleon's chiral component and offers new insights into basic properties of the chiral expansion. It relates the information extracted from low-t elastic form factors to the generalized parton distributions probed in peripheral high-energy scattering processes.

  4. Chiral dynamics of S -wave baryon resonances

    NASA Astrophysics Data System (ADS)

    Long, Bingwei

    2016-07-01

    As the pion mass approaches a critical value mπ⋆ from below, an S -wave resonance crosses the pion-baryon threshold and becomes a bound state with arbitrarily small binding energy, thus driving the scattering length to diverge. I explore the consequences of chiral symmetry for the values of mπ close to mπ⋆. It turns out that chiral symmetry is crucial for an S -wave resonance to be able to stand very near the threshold and in the meantime to remain narrow, provided that the mass splitting is reasonably small. The effective range of pion-baryon scattering is unexpectedly large, proportional to 4 π fπ2/mπ3 when mπ is around mπ⋆. As a result, this unexpected large length scale causes universality relations to break down much sooner than naively expected.

  5. Model of complex chiral drug metabolic systems and numerical simulation of the remaining chirality toward analysis of dynamical pharmacological activity.

    PubMed

    Ogino, Yoshiyuki; Asahi, Toru

    2015-05-21

    In this study, systems of complicated pathways involved in chiral drug metabolism were investigated. The development of chiral drugs resulted in significant improvement in the remedies available for the treatment of various severe sicknesses. Enantiopure drugs undergo various biological transformations that involve chiral inversion and thus result in the generation of multiple enantiomeric metabolites. Identification of the specific active substances determining a given drug׳s efficacy among such a mixture of different metabolites remains a challenge. To comprehend this complexity, we constructed a mathematical model representing the complicated metabolic pathways simultaneously involving chiral inversion. Moreover, this model is applied to the metabolism of thalidomide, which has recently been revived as a potentially effective prescription drug for a number of intractable diseases. The numerical simulation results indicate that retained chirality in the metabolites reflects the original chirality of the unmetabolized drug, and a higher level of enantiomeric purity is preserved during spontaneous degradation. In addition, chirality remaining after equilibration is directly related to the rate constant not only for chiral inversion but also for generation and degradation. Furthermore, the retention of chirality is quantitatively predictable using this combination of kinetic parameters. Our simulation results well explain the behavior of thalidomide in the practical biological experimental data. Therefore, this model promises a comprehensive understanding of dynamic metabolic systems involving chiral drugs that express multiple enantiospecific drug efficacies. PMID:25791284

  6. Enantiodivergent Atroposelective Synthesis of Chiral Biaryls by Asymmetric Transfer Hydrogenation: Chiral Phosphoric Acid Catalyzed Dynamic Kinetic Resolution.

    PubMed

    Mori, Keiji; Itakura, Tsubasa; Akiyama, Takahiko

    2016-09-12

    Reported herein is an enantiodivergent synthesis of chiral biaryls by a chiral phosphoric acid catalyzed asymmetric transfer hydrogenation reaction. Upon treatment of biaryl lactols with aromatic amines and a Hantzsch ester in the presence of chiral phosphoric acid, dynamic kinetic resolution (DKR) involving a reductive amination reaction proceeded smoothly to furnish both R and S isomers of chiral biaryls with excellent enantioselectivities by proper choice of hydroxyaniline derivative. This trend was observed in wide variety of substrates, and various chiral biphenyl and phenyl naphthyl adducts were synthesized with satisfactory enantioselectivities in enantiodivergent fashion. The enantiodivergent synthesis of synthetically challenging, chiral o-tetrasubstituted biaryls were also accomplished, and suggests high synthetic potential of the present method. PMID:27491630

  7. Communication: The influence of vibrational parity in chiral photoionization dynamics

    SciTech Connect

    Powis, Ivan

    2014-03-21

    A pronounced vibrational state dependence of photoelectron angular distributions observed in chiral photoionization experiments is explored using a simple, yet realistic, theoretical model based upon the transiently chiral molecule H{sub 2}O{sub 2}. The adiabatic approximation is used to separate vibrational and electronic wavefunctions. The full ionization matrix elements are obtained as an average of the electronic dipole matrix elements over the vibrational coordinate, weighted by the product of neutral and ion state vibrational wavefunctions. It is found that the parity of the vibrational Hermite polynomials influences not just the amplitude, but also the phase of the transition matrix elements, and the latter is sufficient, even in the absence of resonant enhancements, to account for enhanced vibrational dependencies in the chiral photoionization dynamics.

  8. Chiral perturbation theory with nucleons

    SciTech Connect

    Meissner, U.G.

    1991-09-01

    I review the constraints posed on the interactions of pions, nucleons and photons by the spontaneously broken chiral symmetry of QCD. The framework to perform these calculations, chiral perturbation theory, is briefly discussed in the meson sector. The method is a simultaneous expansion of the Greens functions in powers of external moments and quark masses around the massless case, the chiral limit. To perform this expansion, use is made of a phenomenological Lagrangian which encodes the Ward-identities and pertinent symmetries of QCD. The concept of chiral power counting is introduced. The main part of the lectures of consists in describing how to include baryons (nucleons) and how the chiral structure is modified by the fact that the nucleon mass in the chiral limit does not vanish. Particular emphasis is put on working out applications to show the strengths and limitations of the methods. Some processes which are discussed are threshold photopion production, low-energy compton scattering off nucleons, {pi}N scattering and the {sigma}-term. The implications of the broken chiral symmetry on the nuclear forces are briefly described. An alternative approach, in which the baryons are treated as very heavy fields, is touched upon.

  9. Hypernuclei and in-medium chiral dynamics

    NASA Astrophysics Data System (ADS)

    Finelli, P.

    2008-04-01

    A recently introduced relativistic nuclear energy density functional, constrained by features of low-energy QCD, is extended to describe the structure of hypernuclei. The density-dependent mean field and the spin-orbit potential of a Λ-hyperon in a nucleus, are consistently calculated using the SU(3) extension of in-medium chiral perturbation theory. The leading long-range ΛN interaction arises from kaon-exchange and 2π-exchange with a Σ-hyperon in the intermediate state. Scalar and vector mean fields, originating from in-medium changes of the quark condensates, produce a sizeable short-range spin-orbit interaction. The model, when applied to oxygen as a test case, provides a natural explanation for the smallness of the effective Λ spin-orbit potential: an almost complete cancellation between the background contributions (scalar and vector) and the long-range terms generated by two-pion exchange.

  10. Intrinsic transverse momentum and dynamical chiral symmetry breaking

    SciTech Connect

    Christian Weiss, Peter Schweitzer, Mark Strikman

    2013-01-01

    We study the effect of QCD vacuum structure on the intrinsic transverse momentum distribution of partons in the nucleon at a low scale. The dynamical breaking of chiral symmetry is caused by non-perturbative interactions at distances of the order rho ~ 0.2 - 0.3 fm, much smaller than the typical nucleon size R ~ 1 fm, resulting in a two-scale picture of nucleon structure. Using an effective dynamical model based on chiral constituent quark degrees of freedom and the 1/N_c expansion (chiral quark-soliton model), we calculate the transverse momentum distribution of quarks and antiquarks at a low scale. The distribution of valence quarks is localized at p_T ~ 1/R. The distribution of flavor-singlet unpolarized sea quarks exhibits a power-like tail extending up to the chiral-symmetry-breaking scale 1/{rho}. A similar tail is present in the flavor-nonsinglet polarized sea. These features are model-independent and represent the imprint of the QCD vacuum on the nucleon's partonic structure. At the level of the nucleon's light-cone wave function, we show that sea quarks partly exist in correlated pairs of transverse size {rho} << R, analogous to short-range NN correlations in nuclei. We discuss the implications of our findings for the transverse momentum distributions in hard scattering processes (semi-inclusive DIS, Drell-Yan pair production) and possible experimental tests of the non-perturbative parton correlations induced by QCD vacuum structure.

  11. The axial anomaly and the dynamical breaking of chiral symmetry

    SciTech Connect

    Gross, Franz; Ito, Hiroshi; Buck, Warren

    1991-10-01

    Using the quark triangle diagram for the Adler-Bell-Jackiw axial anomaly, we calculate the form factor for the {gamma}{sup *}{pi}{sup 0}{yields}{gamma} transition. This form factor depends on the quark mass, and we predict the right behavior with m{sub q}{approx_equal}250 MeV, the same quark mass generated by the dynamical breaking of chiral symmetry through a Nambu-Jona-Lasinio mechanism.

  12. Chiral symmetry restoration versus deconfinement in heavy-ion collisions at high baryon density

    NASA Astrophysics Data System (ADS)

    Cassing, W.; Palmese, A.; Moreau, P.; Bratkovskaya, E. L.

    2016-01-01

    We study the production of strange hadrons in nucleus-nucleus collisions from 4 to 160 A GeV within the parton-hadron-string dynamics (PHSD) transport approach that is extended to incorporate essentials aspects of chiral symmetry restoration (CSR) in the hadronic sector (via the Schwinger mechanism) on top of the deconfinement phase transition as implemented in PHSD. Especially the K+/π+ and the (Λ +Σ0) /π- ratios in central Au+Au collisions are found to provide information on the relative importance of both transitions. The modeling of chiral symmetry restoration is driven by the pion-nucleon Σ term in the computation of the quark scalar condensate that serves as an order parameter for CSR and also scales approximately with the effective quark masses ms and mq. Furthermore, the nucleon scalar density ρs, which also enters the computation of , is evaluated within the nonlinear σ -ω model which is constrained by Dirac-Brueckner calculations and low-energy heavy-ion reactions. The Schwinger mechanism (for string decay) fixes the ratio of strange to light quark production in the hadronic medium. We find that above ˜80 A GeV the reaction dynamics of heavy nuclei is dominantly driven by partonic degrees of freedom such that traces of the chiral symmetry restoration are hard to identify. Our studies support the conjecture of "quarkyonic matter" in heavy-ion collisions from about 5 to 40 A GeV and provide a microscopic explanation for the maximum in the K+/π+ ratio at about 30 A GeV, which only shows up if a transition to partonic degrees of freedom is incorporated in the reaction dynamics and is discarded in the traditional hadron-string models.

  13. Brownian dynamics simulation of the nucleosome chirality - the wrapping direction of DNA on the histone octamer

    NASA Astrophysics Data System (ADS)

    Wang, Peng-Ye

    2005-03-01

    In eukaryote nucleosome, DNA wraps around a histone octamer in a left-handed way. We study the process of chirality formation of nucleosome with Brownian dynamics simulation. We model the histone octamer with a quantitatively adjustable chirality: left-handed, right-handed or non-chiral, and simulate the dynamical wrapping process of a DNA molecule on it. We find that the chirality of a nucleosome formed is strongly dependent on that of the histone octamer, and different chiralities of the histone octamer induce its different rotation directions in the wrapping process of DNA. In addition, a very weak chirality of the histone octamer is quite enough for sustaining the correct chirality of the nucleosome formed. We also show that the chirality of a nucleosome may be broken at elevated temperature.

  14. Confinement and dynamical chiral symmetry breaking in QED3

    SciTech Connect

    Bashir, A.; Raya, A.; Cloeet, I. C.; Roberts, C. D.

    2008-11-15

    We establish that QED3 can possess a critical number of flavors, N{sub f}{sup c}, associated with dynamical chiral symmetry breaking if, and only if, the fermion wave function renormalization and photon vacuum polarization are homogeneous functions at infrared momenta when the fermion mass function vanishes. The Ward identity entails that the fermion-photon vertex possesses the same property and ensures a simple relationship between the homogeneity degrees of each of these functions. Simple models for the photon vacuum polarization and fermion-photon vertex are used to illustrate these observations. The existence and value of N{sub f}{sup c} are contingent upon the precise form of the vertex but any discussion of gauge dependence is moot. We introduce an order parameter for confinement. Chiral symmetry restoration and deconfinement are coincident owing to an abrupt change in the analytic properties of the fermion propagator when a nonzero scalar self-energy becomes insupportable.

  15. Confinement and dynamical chiral symmetry breaking in QED3.

    SciTech Connect

    Bashir, A.; Raya, A.; Cloet, I. C.; Roberts, C. D.; Univ. Michoacana de San Nicolas de Hidalgo

    2008-01-01

    We establish that QED3 can possess a critical number of flavors, Nfc, associated with dynamical chiral symmetry breaking if, and only if, the fermion wave function renormalization and photon vacuum polarization are homogeneous functions at infrared momenta when the fermion mass function vanishes. The Ward identity entails that the fermion-photon vertex possesses the same property and ensures a simple relationship between the homogeneity degrees of each of these functions. Simple models for the photon vacuum polarization and fermion-photon vertex are used to illustrate these observations. The existence and value of Nfc are contingent upon the precise form of the vertex but any discussion of gauge dependence is moot. We introduce an order parameter for confinement. Chiral symmetry restoration and deconfinement are coincident owing to an abrupt change in the analytic properties of the fermion propagator when a nonzero scalar self-energy becomes insupportable.

  16. Dynamic domain wall chirality rectification by rotating magnetic fields

    NASA Astrophysics Data System (ADS)

    Bisig, Andre; Mawass, Mohamad-Assaad; Stärk, Martin; Moutafis, Christoforos; Rhensius, Jan; Heidler, Jakoba; Gliga, Sebastian; Weigand, Markus; Tyliszczak, Tolek; Van Waeyenberge, Bartel; Stoll, Hermann; Schütz, Gisela; Kläui, Mathias

    2015-03-01

    We report on the observation of magnetic vortex domain wall chirality reversal in ferromagnetic rings that is controlled by the sense of rotation of a magnetic field. We use time-resolved X-ray microscopy to dynamically image the chirality-switching process and perform micromagnetic simulations to deduce the switching details from time-resolved snapshots. We find experimentally that the switching occurs within less than 4 ns and is observed in all samples with ring widths ranging from 0.5 μm to 2 μm, ring diameters between 2 μm and 5 μm, and a thickness of 30 nm, where a vortex domain wall is present in the magnetic onion state of the ring. From the magnetic contrast in the time-resolved images, we can identify effects of thermal activation, which plays a role for the switching process. Moreover, we find that the process is highly reproducible so that the domain wall chirality can be set with high fidelity.

  17. Toward complete pion nucleon amplitudes

    NASA Astrophysics Data System (ADS)

    Mathieu, V.; Danilkin, I. V.; Fernández-Ramírez, C.; Pennington, M. R.; Schott, D.; Szczepaniak, Adam P.; Fox, G.

    2015-10-01

    We compare the low-energy partial-wave analyses of π N scattering with high-energy data via finite-energy sum rules. We construct a new set of amplitudes by matching the imaginary part from the low-energy analysis with the high-energy, Regge parametrization and reconstruct the real parts using dispersion relations.

  18. Toward complete pion nucleon amplitudes

    DOE PAGESBeta

    Mathieu, Vincent; Danilkin, Igor V.; Fernández-Ramírez, Cesar; Pennington, Michael R.; Schott, Diane M.; Szczepaniak, Adam P.; Fox, G.

    2015-10-05

    We compare the low-energy partial wave analyses πN scattering with a high-energy data via finite energy sum rules. We also construct a new set of amplitudes by matching the imaginary part from the low-energy analysis with the high-energy, Regge parametrization and then reconstruct the real parts using dispersion relations.

  19. Dynamics of skyrmions in chiral magnets: Dynamic phase transitions and equation of motion

    SciTech Connect

    Lin, Shi-Zeng Reichhardt, Charles; Batista, Cristian D.; Saxena, Avadh

    2014-05-07

    We study the dynamics of skyrmions in a metallic chiral magnet. First, we show that skyrmions can be created dynamically by destabilizing the ferromagnetic background state through a spin polarized current. We then treat skyrmions as rigid particles and derive the corresponding equation of motion. The dynamics of skyrmions is dominated by the Magnus force, which accounts for the weak pinning of skyrmions observed in experiments. Finally, we discuss the quantum motion of skyrmions.

  20. Dynamics and energetics of emergent magnetic monopoles in chiral magnets

    NASA Astrophysics Data System (ADS)

    Schütte, Christoph; Rosch, Achim

    2014-11-01

    The formation and destruction of topologically quantized magnetic whirls, i.e., the so-called skyrmions, in chiral magnets is driven by the creation and motion of singular hedgehog defects. These Bloch points can be identified with emergent magnetic monopoles and antimonopoles. We investigate how the energetics of and forces between monopoles and antimonopoles influence their creation rate and dynamics. We study a single skyrmion line defect in the helical phase using both micromagnetic simulations and a Ginzburg-Landau analysis. Monopole-antimonopole pairs are created in a thermally activated process, largely controlled by the (core) energy of the monopole. The force between monopoles and antimonopoles is linear in distance and described by a string tension. The sign and size of the string tension determines the stability of the phases and the velocity of the monopoles.

  1. The 7th International Workshop on Chiral Dynamics

    NASA Astrophysics Data System (ADS)

    The 7th International Workshop Chiral Dynamics: Theory and Experiment (CD12) took place at Jefferson Lab, Newport News, Virginia, USA, from August 6 to 10, 2012. Following in the tradition of this triennial series of Conferences, it attracted theorists and experimentalists, who were brought together to highlight the recent progress in the field of low energy QCD, and to discuss and explore the direction for future development. The conference consisted of plenary talks and three working groups. We would like to thank the working group organizers for their dedicated effort, namely: Goldstone Bosons: Mario Antonelli, Liping Gan, Jorge Portoles and Urs Wenger; Hadron Structure: Alessandro Bacchetta, Bastian Kubis, Kostas Orginos and Karl Slifer and Few Body Physics: Andreas Nogga, Assumpta Parreno, Michele Viviani and Henry Weller. We would like to express our special thanks to our co-organizers, Patricia Solvignon, Harald Griesshammer, Rocco Schiavilla, Dinko Pocanic, Robert Edwards, and Alexandre Deur for their hard work and advice. Last but not least, we thank the International Advisory Committee for their very useful inputs to the CD12 program. The organizers thank the excellent logistic and administrative support provided by the Jefferson Lab Conference Staff, Ruth Bizot, Cynthia Lockwood, Stephanie Vermeire, Marti Hightower and MeLaina Evans, and the Conference Secretary Mary Fox, which was instrumental for the success of the organization of CD12. We thank Joanna Griffin for the poster design. CD12 was primarily sponsored by Jefferson Lab, along with generous supports from Old Dominion University and the European Physics Journal. The CD12 homepage is located at http://www.jlab.org/conference/CD12 The upcoming Chiral Dynamics Workshop will take place in Pisa, Italy, in 2015. We thank Laura Marcucci and Michele Viviani for graciously taking the baton from us. Jose Goity and Jianping Chen

  2. Chiral dynamics and partonic structure at large transverse distances

    SciTech Connect

    Mark Strikman, Christian Weiss

    2009-12-01

    We study large-distance contributions to the nucleon's parton densities in the transverse coordinate (impact parameter) representation based on generalized parton distributions (GPDs). Chiral dynamics generates a distinct component of the partonic structure, located at momentum fractions x ~< M_pi / M_N and transverse distances b ~ 1/M_pi. We calculate this component using phenomenological pion exchange with a physical lower limit in b (the transverse ``core'' radius estimated from the nucleon's axial form factor, R_core = 0.55 fm) and demonstrate its universal character. This formulation preserves the basic picture of the ``pion cloud'' model of the nucleon's sea quark distributions, while restricting its application to the region actually governed by chiral dynamics. It is found that (a) the large-distance component accounts for only ~1/3 of the measured antiquark flavor asymmetry dbar - ubar at x ~ 0.1; (b) the strange sea quarks, s and sbar, are significantly more localized than the light antiquark sea; (c) the nucleon's singlet quark size for x < 0.1 is larger than its gluonic size, average(b^2)_{q + qbar} > average(b^2)_g, as suggested by the t-slopes of deeply-virtual Compton scattering and exclusive J/psi production measured at HERA and FNAL. We show that our approach reproduces the general N_c-scaling of parton densities in QCD, thanks to the degeneracy of N and Delta intermediate states in the large-N_c limit. We also comment on the role of pionic configurations at large longitudinal distances and the limits of their applicability at small x.

  3. Flexible chiral metamaterials with dynamically optical activity and high negative refractive index

    NASA Astrophysics Data System (ADS)

    Dincer, Furkan; Karaaslan, Muharrem; Unal, Emin; Akgol, Oguzhan; Sabah, Cumali

    2015-06-01

    We demonstrate numerically and experimentally chiral metamaterials (MTMs) based on gammadion-bilayer cross-wires that uniaxially create giant optical activity and tunable circular dichroism as a result of the dynamic design. In addition, the suggested structure gives high negative refractive index due to the large chirality in order to obtain an efficient polarization converter. We also present a numerical analysis in order to show the additional features of the proposed chiral MTM in detail. Therefore, a MTM sensor application of the proposed chiral MTM is introduced and discussed. The presented chiral designs offer a much simpler geometry and more efficient outlines. The experimental results are in a good agreement with the numerical simulation. It can be seen from the results that, the suggested chiral MTM can be used as a polarization converter, sensor, etc. for several frequency regimes.

  4. Time-resolving Attosecond Chiral Dynamics in Molecules with High Harmonic Spectroscopy

    NASA Astrophysics Data System (ADS)

    Smirnova, O.; Cireasa, R.; Boguslavskiy, A.; Pons, B.; Wong, M. C. H.; Descamps, D.; Petit, S.; Ruf, H.; Thire, N.; Ferre, A.; Suarez, J.; Schmidt, B. E.; Higuet, J.; Alharbi, A. F.; Legare, F.; Blanchet, V.; Fabre, B.; Patchkovskii, S.; Mairesse, Y.; Bhardwaj, R.

    2015-05-01

    We demonstrate extreme chiral sensitivity of high harmonic generation from randomly oriented ensemble of chiral molecules in elliptical mid-infrared fields, and explain the physical mechanism underlying this very strong chiro-optical response. We also use the high harmonic spectra to follow the electronic chiral response with 0.1 femtosecond resolution. We studied two chiral molecules, epoxypropane and fenchone in 1.8 μm, 50 fs, mid-1013 W/cm2 pulses. Very small ellipticity of the incident light, about 1% in the field, is sufficient to induce several percent difference between the high harmonic response of left and right enantiomers. The origin of this effect lies in chiral-sensitive dynamics of the hole created by strong field ionization. Small differences in this dynamics between ionization and recombination are recorded and amplified by several orders of magnitude in high harmonic spectra. Using time-energy mapping we reconstruct sub-femtosecond chiral dynamics and show that the standard measure of the chiral signal is directly proportional to the recombination amplitude to the chiral-sensitive component of the hole wave-packet.

  5. Light-Directed Dynamic Chirality Inversion in Functional Self-Organized Helical Superstructures.

    PubMed

    Bisoyi, Hari Krishna; Li, Quan

    2016-02-24

    Helical superstructures are widely observed in nature, in synthetic polymers, and in supramolecular assemblies. Controlling the chirality (the handedness) of dynamic helical superstructures of molecular and macromolecular systems by external stimuli is a challenging task, but is of great fundamental significance with appealing morphology-dependent applications. Light-driven chirality inversion in self-organized helical superstructures (i.e. cholesteric, chiral nematic liquid crystals) is currently in the limelight because inversion of the handedness alters the chirality of the circularly polarized light that they selectively reflect, which has wide potential for application. Here we discuss the recent developments toward inversion of the handedness of cholesteric liquid crystals enabled by photoisomerizable chiral molecular switches or motors. Different classes of chiral photoresponsive dopants (guests) capable of conferring light-driven reversible chirality inversion of helical superstructures fabricated from different nematic hosts are discussed. Rational molecular designs of chiral molecular switches toward endowing handedness inversion to the induced helical superstructures of cholesteric liquid crystals are highlighted. This Review is concluded by throwing light on the challenges and opportunities in this emerging frontier, and it is expected to provide useful guidelines toward the development of self-organized soft materials with stimuli-directed chirality inversion capability and multifunctional host-guest systems. PMID:26764018

  6. Dynamic control of chirality in phosphine ligands for enantioselective catalysis

    PubMed Central

    Zhao, Depeng; Neubauer, Thomas M.; Feringa, Ben L.

    2015-01-01

    Chirality plays a fundamental role in biology and chemistry and the precise control of chirality in a catalytic conversion is a key to modern synthesis most prominently seen in the production of pharmaceuticals. In enantioselective metal-based catalysis, access to each product enantiomer is commonly achieved through ligand design with chiral bisphosphines being widely applied as privileged ligands. Switchable phosphine ligands, in which chirality is modulated through an external trigger signal, might offer attractive possibilities to change enantioselectivity in a catalytic process in a non-invasive manner avoiding renewed ligand synthesis. Here we demonstrate that a photoswitchable chiral bisphosphine based on a unidirectional light-driven molecular motor, can be used to invert the stereoselectivity of a palladium-catalysed asymmetric transformation. It is shown that light-induced changes in geometry and helicity of the switchable ligand enable excellent selectivity towards the racemic or individual enantiomers of the product in a Pd-catalysed desymmetrization reaction. PMID:25806856

  7. The Interplay Between Conformation and Absolute Configuration in Chiral Electron Dynamics of Small Diols.

    PubMed

    Daly, Steven; Tia, Maurice; Garcia, Gustavo A; Nahon, Laurent; Powis, Ivan

    2016-09-01

    A competition between chiral characteristics alternatively attributable to either conformation or to absolute configuration is identified. Circular dichroism associated with photoexcitation of the outer orbital of configurational enantiomers of 1,3- and 2,3-butanediols has been examined with a focus on the large changes in electron chiral asymmetry produced by different molecular conformations. Experimental gas-phase measurements offer support for the theoretical modeling of this chiroptical effect. A surprising prediction is that a conformationally produced pseudo-enantiomerism in 1,3-butanediol generates a chiral response in the frontier electron dynamics that outweighs the influence of the permanent configurational handedness established at the asymmetrically substituted carbon. Induced conformation, and specifically induced conformational chirality, may thus be a dominating factor in chiral molecular recognition in such systems. PMID:27445202

  8. Dynamic localization of electronic excitation in photosynthetic complexes revealed with chiral two-dimensional spectroscopy

    NASA Astrophysics Data System (ADS)

    Fidler, Andrew F.; Singh, Ved P.; Long, Phillip D.; Dahlberg, Peter D.; Engel, Gregory S.

    2014-02-01

    Time-resolved ultrafast optical probes of chiral dynamics provide a new window allowing us to explore how interactions with such structured environments drive electronic dynamics. Incorporating optical activity into time-resolved spectroscopies has proven challenging because of the small signal and large achiral background. Here we demonstrate that two-dimensional electronic spectroscopy can be adapted to detect chiral signals and that these signals reveal how excitations delocalize and contract following excitation. We dynamically probe the evolution of chiral electronic structure in the light-harvesting complex 2 of purple bacteria following photoexcitation by creating a chiral two-dimensional mapping. The dynamics of the chiral two-dimensional signal directly reports on changes in the degree of delocalization of the excitonic states following photoexcitation. The mechanism of energy transfer in this system may enhance transfer probability because of the coherent coupling among chromophores while suppressing fluorescence that arises from populating delocalized states. This generally applicable spectroscopy will provide an incisive tool to probe ultrafast transient molecular fluctuations that are obscured in non-chiral experiments.

  9. Chiral dynamics in the γ → p → pπ0 reaction

    NASA Astrophysics Data System (ADS)

    Hiller Blin, A. N.; Ledwig, T.; Vicente Vacas, M. J.

    2015-07-01

    We investigate the neutral pion photoproduction on the proton near threshold in covariant chiral perturbation theory with the explicit inclusion of Δ degrees of freedom. This channel is specially sensitive to chiral dynamics and the advent of very precise data from the Mainz microtron has shown the limits of the convergence of the chiral series for both the heavy baryon and the covariant approaches. We show that the inclusion of the Δ resonance substantially improves the convergence leading to a good agreement with data for a wider range of energies.

  10. Dynamics of chiral symmetry breaking in nuclear collisions

    SciTech Connect

    Gavin, S.

    1994-07-01

    Measurements of disoriented chiral condensates in heavy ion collisions at RHIC and the LHC can yield fundamental information on the nature of the QCD phase transition. I review theoretical efforts to understand the evolution of the condensate and present new results on experimental signals in the single pion spectrum and in pion interferometry.

  11. Symmetry-adapted non-equilibrium molecular dynamics of chiral carbon nanotubes under tensile loading

    NASA Astrophysics Data System (ADS)

    Aghaei, Amin; Dayal, Kaushik

    2011-06-01

    We report on non-equilibrium molecular dynamics calculations of chiral single-wall carbon nanotubes using the framework of Objective Structures. This enables us to adapt molecular dynamics to the symmetry of chiral nanotubes and efficiently simulate these systems with small unit cells. We outline the method and the adaptation of a conventional thermostat and barostat to this setting. We then apply the method in order to examine the behavior of nanotubes with various chiralities subject to a constant extensional strain rate. We examine the effects of temperature, strain rate, and pre-compression/pre-tension. We find a range of failure mechanisms, including the formation of Stone-Wales defects, the opening of voids, and the motion of atoms out of the cross-section.

  12. Can disoriented chiral condensates form A dynamical perspective

    SciTech Connect

    Boyanovsky, D. ); de Vega, H.J. , Tour 16, 1er. etage, 4, Place Jussieu 75252 Paris, Cedex 05 ); Holman, R. )

    1995-01-15

    We address the issue of whether a region of disoriented chiral condensate (DCC), in which the chiral condensate has components along the pion directions, can form. We consider a system going through the chiral phase transition via a quench, in which relaxation of the high temperature phase to the low temperature one occurs rapidly (within a time scale of order [similar to]1 fm/[ital c]). We use a density matrix based formalism that takes both thermal and quantum fluctuations into account nonperturbatively to argue that if the O(4) linear [sigma] model is the correct way to model the situation in QCD, then it is very unlikely, at least in the Hartree approximation, that a large ([gt]10 fm) DCC region will form. Typical sizes of such regions are [similar to]1--2 fm and the density of pions in such regions is at most of order [similar to]0.2/fm[sup 3]. We end with some speculations on how large DCC regions may be formed.

  13. A Study of Confinement and Dynamical Chiral Symmetry Breaking in QED3

    SciTech Connect

    Sanchez, Saul; Raya, Alfredo; Bashir, Adnan

    2009-04-20

    We study the gauge invariance of physical observables related to confinement and dynamical chiral symmetry breaking in unquenched QED3 for a simple truncation of the corresponding Schwinger-Dyson equations in arbitrary covariant gauges. An explicit implementation of Landau-Khalatnikov-Fradkin transformations renders these observables gauge independent.

  14. Pion-photon reactions and chiral dynamics in Primakoff processes at COMPASS

    NASA Astrophysics Data System (ADS)

    Friedrich, Jan Michael

    2016-01-01

    With the COMPASS experiment at CERN, pion-photon reactions are investigated via the Primakoff effect, implying that high-energetic pions react with the quasi-real photon field surrounding the target nuclei. The production of a single hard photon in such a pion scattering at lowest momentum transfer to the nucleus is related to pion Compton scattering. From the measured cross-section shape, the pion polarisability is determined. The COMPASS measurement is in contradiction to the earlier dedicated measurements, and rather in agreement with the theoretical expectation from chiral perturbation theory. In the same data taking, reactions with neutral and charged pions in the final state are measured and analyzed. At low energy in the pion-photon centre-of-momentum system, these reactions are governed by chiral dynamics and contain information relevant for chiral perturbation theory. At higher energies, resonances are produced and their radiative coupling is investigated.

  15. In-medium chiral SU (3) dynamics and hypernuclear structure

    NASA Astrophysics Data System (ADS)

    Finelli, P.; Kaiser, N.; Vretenar, D.; Weise, W.

    2007-12-01

    A previously introduced relativistic energy density functional, successfully applied to ordinary nuclei, is extended to hypernuclei. The density-dependent mean field and the spin-orbit potential are consistently calculated for a Λ hyperon in the nucleus using the SU (3) extension of in-medium chiral perturbation theory. The leading long range ΛN interaction arises from kaon-exchange and 2π-exchange with Σ hyperon in the intermediate state. Scalar and vector mean fields reflecting in-medium changes of the quark condensates are constrained by QCD sum rules. The model, applied to oxygen as a test case, describes spectroscopic data in good agreement with experiment. In particular, the smallness of the Λ spin-orbit interaction finds a natural explanation in terms of an almost complete cancellation between scalar-vector background contributions and long-range terms generated by two-pion exchange.

  16. Resonant collective dynamics of the weakly pinned soliton lattice in a monoaxial chiral helimagnet

    NASA Astrophysics Data System (ADS)

    Kishine, Jun-ichiro; Proskurin, I.; Bostrem, I. G.; Ovchinnikov, A. S.; Sinitsyn, Vl. E.

    2016-02-01

    We study the spin dynamics of a confined chiral soliton lattice whose ends are weakly held. We demonstrate that in this case the system possesses its own resonant frequency. To study features of the resonant dynamics, we analyze the collective motion of the system driven by an oscillating magnetic field directed along the chiral axis. By using the method of collective coordinates we find analytically the resonant frequency and verify the result by numerical simulation of the spin dynamics with the aid of Landau-Lifshitz-Gilbert equations. The numerical simulation shows an appearance of the asymmetric profile of the frequency response function with increasing ac field, which is typical for a nonlinear resonance. To give an explanation of this behavior, we invoke the multiple-time-scale method and predict an emergence of hysteresis phenomena. We also demonstrate that the spin-motive force is strongly amplified by the resonant oscillations.

  17. Evidence that centre vortices underpin dynamical chiral symmetry breaking in SU (3) gauge theory

    NASA Astrophysics Data System (ADS)

    Trewartha, Daniel; Kamleh, Waseem; Leinweber, Derek

    2015-07-01

    The link between dynamical chiral symmetry breaking and centre vortices in the gauge fields of pure SU (3) gauge theory is studied using the overlap-fermion quark propagator in Lattice QCD. Overlap fermions provide a lattice realisation of chiral symmetry and consequently offer a unique opportunity to explore the interplay of centre vortices, instantons and dynamical mass generation. Simulations are performed on gauge fields featuring the removal of centre vortices, identified through gauge transformations maximising the center of the gauge group. In contrast to previous results using the staggered-fermion action, the overlap-fermion results illustrate a loss of dynamical chiral symmetry breaking coincident with vortex removal. This result is linked to the overlap-fermion's sensitivity to the subtle manner in which instanton degrees of freedom are compromised through the process of centre vortex removal. Backgrounds consisting solely of the identified centre vortices are also investigated. After smoothing the vortex-only gauge fields, we observe dynamical mass generation on the vortex-only backgrounds consistent within errors with the original gauge-field ensemble following the same smoothing. Through visualizations of the instanton-like degrees of freedom in the various gauge-field ensembles, we find evidence of a link between the centre vortex and instanton structure of the vacuum. While vortex removal destabilizes instanton-like objects under O (a4)-improved cooling, vortex-only backgrounds provide gauge-field degrees of freedom sufficient to create instantons upon cooling.

  18. Sea quark transverse momentum distributions and dynamical chiral symmetry breaking

    SciTech Connect

    Schweitzer, Peter; Strikman, Mark; Weiss, Christian

    2014-01-01

    Recent theoretical studies have provided new insight into the intrinsic transverse momentum distributions of valence and sea quarks in the nucleon at a low scale. The valence quark transverse momentum distributions (q - qbar) are governed by the nucleon's inverse hadronic size R{sup -1} ~ 0.2 GeV and drop steeply at large p{sub T}. The sea quark distributions (qbar) are in large part generated by non-perturbative chiral-symmetry breaking interactions and extend up to the scale rho{sup -1} ~ 0.6 GeV. These findings have many implications for modeling the initial conditions of perturbative QCD evolution of TMD distributions (starting scale, shape of p{sub T}. distributions, coordinate-space correlation functions). The qualitative difference between valence and sea quark intrinsic p{sub T}. distributions could be observed experimentally, by comparing the transverse momentum distributions of selected hadrons in semi-inclusive deep-inelastic scattering, or those of dileptons produced in pp and pbar-p scattering.

  19. Effects of carrier gas dynamics on single wall carbon nanotube chiral distributions during laser vaporization synthesis.

    PubMed

    Landi, Brian J; Raffaelle, Ryne P

    2007-03-01

    We report on the utility of modifying the carrier gas dynamics during laser vaporization synthesis to alter the single wall carbon nanotube (SWNT) chiral distribution. SWNTs produced from an Alexandrite laser using conventional Ni/Co catalysts demonstrate marked differences in chiral distributions due to effects of helium gas and reactor chamber pressure, in comparison to conventional subambient pressures and argon gas. Optical absorption and Raman spectroscopies confirm that the SWNT diameter distribution decreases under higher pressure and with helium gas as opposed to argon. Fluorescence mapping of the raw soots in sodium dodecylbenzene sulfonate (SDBS)-D2O was used to estimate the relative (n, m)-SWNT content of the semiconducting types. A predominance of type II structures for each synthesis condition was observed. The distribution of SWNT chiral angles was observed to shift away from near-armchair configurations under higher pressure and with helium gas. These results illustrate the importance of gas type and pressure on the condensation/cooling rate, which allows for synthesis of specific SWNT chiral distributions. PMID:17450850

  20. Chiral Catalyst-Directed Dynamic Kinetic Diastereoselective Acylation of Lactols for De Novo Synthesis of Carbohydrate.

    PubMed

    Wang, Hao-Yuan; Yang, Ka; Yin, Dan; Liu, Can; Glazier, Daniel A; Tang, Weiping

    2015-11-01

    The control of the stereochemistry at the anomeric position is still one of the major challenges of synthetic carbohydrate chemistry. We have developed a new strategy consisting of a chiral catalyst-directed acylation followed by a palladium-catalyzed glycosidation to achieve high α- and β-stereoselectivity on the anomeric position. The former process involves a dynamic kinetic diastereoselective acylation of lactols derived from Achmatowicz rearrangement, while the latter is a stereospecific palladium-catalyzed allylic alkylation. PMID:26484422

  1. Laser-Induced Dynamical Chirality and Intramolecular Energy Flow in the CH Chromophore

    SciTech Connect

    Thanopulos, Ioannis

    2007-11-29

    We review the quantum dynamics of intramolecular energy flow during and after coherent infrared multiphoton excitation of the CH organic chromophore. The understanding of the underlying dynamics is of central importance for a wide range of systems in molecular physics, chemistry and biology, due to the experimentally supported assumption that the chromophore dynamics is weakly-dependent on a specific environment, in particular on sub-picosecond time scale. The excitation process due to the interaction with the laser field is studied by computationally monitoring the wave packet motion in the configuration sub-space relevant to femtosecond dynamics, using global analytical potential energy and electric dipole functions previously developed. The features of the intramolecular vibrational energy redistribution and the related dynamical time scales are investigated. In particular, we discuss the generation of dynamical chirality in methane istopomers, the corresponding stereomutation and racemization phenomena on the femtosecond time scale, and their relation to intramolecular vibrational energy redistribution.

  2. Chiral super-Tremblay-Turbiner-Winternitz Hamiltonians and their dynamical superalgebra

    NASA Astrophysics Data System (ADS)

    Quesne, C.

    2010-12-01

    The family of Tremblay-Turbiner-Winternitz (TTW) Hamiltonians Hk on a plane, corresponding to any positive real value of k, is shown to admit another {\\cal N} = 2 supersymmetric extension than that previously introduced by the present author. This new extension is of the same kind as that considered by D'Hoker and Vinet in the study of magnetic monopoles and is characterized by the fact that all the irreducible representations of the corresponding osp(2/2, \\ {R}) dynamical superalgebra are atypical lowest-weight state ones. The new supersymmetric Hamiltonians may be referred to as chiral super-TTW Hamiltonians, the role of chirality being played here by the fermion number parity operator.

  3. Dynamic Multi-Component Covalent Assembly for the Reversible Binding of Secondary Alcohols and Chirality Sensing

    PubMed Central

    You, Lei; Berman, Jeffrey S.; Anslyn, Eric V.

    2011-01-01

    Reversible covalent bonding is often employed for the creation of novel supramolecular structures, multi-component assemblies, and sensing ensembles. In spite of remarkable success of dynamic covalent systems, the reversible binding of a mono-alcohol with high strength is challenging. Here we show that a strategy of carbonyl activation and hemiaminal ether stabilization can be embodied in a four-component reversible assembly that creates a tetradentate ligand and incorporates secondary alcohols with exceptionally high affinity. Evidence is presented that the intermediate leading to binding and exchange of alcohols is an iminium ion. Further, to demonstrate the use of this assembly process we explored chirality sensing and enantiomeric excess determinations. An induced twist in the ligand by a chiral mono-ol results in large Cotton effects in the circular dichroism spectra indicative of the alcohol’s handedness. The strategy revealed in this study should prove broadly applicable for the incorporation of alcohols into supramolecular architecture construction. PMID:22109274

  4. Determination of absolute configuration in chiral solvents with nuclear magnetic resonance. A combined molecular dynamics/quantum chemical study.

    PubMed

    Kessler, Jiří; Dračínský, Martin; Bouř, Petr

    2015-05-28

    Nuclear magnetic resonance (NMR) spectroscopy is omnipresent in chemical analysis. However, chirality of a molecule can only be detected indirectly by NMR, e.g., by monitoring its interaction with another chiral object. In the present study, we investigate the spectroscopic behavior of chiral molecules placed into a chiral solvent. In this case, the solvent-solute interaction is much weaker, but the application range of such NMR analysis is wider than for a specific chemical shift agent. Two alcohols and an amine were used as model systems, and differences in NMR chemical shifts dependent on the solute-solvent chirality combination were experimentally detected. Combined quantum mechanic/molecular mechanic (QM/MM) computations were applied to reveal the underlying solute-solvent interactions. NMR shielding was calculated using the density functional theory (DFT). While the experimental observations could not be reproduced quantitatively, the modeling provided a qualitative agreement and detailed insight into the essence of solvent-solute chiral interactions. The potentials of mean force (PMF) obtained using molecular dynamics (MD) and the weighted histogram analysis method (WHAM) indicate that the chiral interaction brings about differences in conformer ratios, which are to a large extent responsible for the NMR shifts. The MD results also predicted slight changes in the solvent structure, including the radial distribution function (RDF), to depend on the solvent/solute chirality combination. Apart from the conformer distribution, an effective average solvent electrostatic field was tested as another major factor contributing to the chiral NMR effect. The possibility to simulate spectral effects of chiral solvents from the first-principles opens up the way to NMR spectroscopic determination of the absolute configuration for a larger scale of compounds, including those not forming specific complexes. PMID:25411905

  5. Dynamic Kinetic Resolution of Biaryl Lactones via a Chiral Bifunctional Amine Thiourea-Catalyzed Highly Atropo-enantioselective Transesterification.

    PubMed

    Yu, Chenguang; Huang, He; Li, Xiangmin; Zhang, Yueteng; Wang, Wei

    2016-06-01

    A solution to the unmet synthetic challenge of achieving highly atropo-enantioselective transesterification of Bringmann's lactones has been realized, employing a chiral bifunctional amine thiourea as promoter. The synergistic activation of the lactones and alcohols/phenols by the respective thiourea and amine groups is crucial for achieving the highly enantioselective, high-yielding dynamic kinetic resolution process. This protocol gives highly optically pure, axially chiral biaryl compounds with a broad substrate scope under mild reaction conditions. PMID:27218264

  6. Pion-photon reactions and chiral dynamics in Primakoff processes at COMPASS

    NASA Astrophysics Data System (ADS)

    Krämer, Markus

    2016-05-01

    At the COMPASS experiment at CERN, pion-photon reactions are investigated using the Primakoff effect, where high-energetic pions react with the quasi-real photons surrounding the target nuclei. The production of a single hard photon in such a pion scattering, at lowest momentum transfer to the nucleus, is related to pion Compton scattering. Studying the energy distribution of the outgoing photons, the pion polarizability can be extracted. In addition to the measurement with a pion beam, control measurements with a muon beam allow us to estimate the systematics. The COMPASS result is in tension with earlier dedicated measurements and rather in agreement with the theoretical expectation from chiral perturbation theory. Based on the same data set, reactions with neutral and charged pions in the final state are studied. At low invariant mass of the pion-photon system, these reactions are governed by chiral dynamics. Using partial-wave analysis techniques, the absolute cross sections for the production of π-π+π- and π-π0π0 states from π-γ interactions are measured and compared to predictions from chiral perturbation theory. At higher pion-photon masses, the production of 3π resonances is studied with the focus on their radiative couplings.

  7. Electrically Switchable and Permanently Stable Light Scattering Modes by Dynamic Fingerprint Chiral Textures.

    PubMed

    Cheng, Ko-Ting; Lee, Po-Yi; Qasim, Malik M; Liu, Cheng-Kai; Cheng, Wen-Fa; Wilkinson, Timothy D

    2016-04-27

    Negative dielectric nematic liquid crystals (LCs) doped with two azobenzene materials provide electrically switchable and permanently stable scattering mode light modulators based on dynamic fingerprint chiral textures (DFCT) with inhomogeneously helical axes. These light modulators can be switched between transparent (stable large domains of DFCT) states and scattering (stable small domains of DFCT) states by applying electric fields with different frequencies. The generation of DFCT results from the long flexible side chains of the doped chiral dopant. That is, if the DFCT can be obtained, then the large domains of DFCT reflect an intrinsically stable state. Moreover, the stabilization of the small domains of DFCT are caused by the terminal rigid restricted side chains of the other doped chiral dopant. Experimentally, the required amplitude to switch the light modulator from a scattering (transparent) state to a transparent (scattering) state decreases as the frequency of the applied electric field increases (decreases) within the set limits. This study is the first report on the advantages of the light scattering mode of DFCT, including low operating voltage, permanently stable transmission, wide viewing angle, high contrast, and polarization-independent scattering and transparency. PMID:27035635

  8. Dynamics of Dirac strings and monopolelike excitations in chiral magnets under a current drive

    DOE PAGESBeta

    Lin, Shi -Zeng; Saxena, Avadh

    2016-02-10

    Skyrmion lines in metallic chiral magnets carry an emergent magnetic field experienced by the conduction electrons. The inflow and outflow of this field across a closed surface is not necessarily equal, thus it allows for the existence of emergent monopoles. One example is a segment of skyrmion line inside a crystal, where a monopole and antimonopole pair is connected by the emergent magnetic flux line. This is a realization of Dirac stringlike excitations. Here we study the dynamics of monopoles in chiral magnets under an electric current. We show that in the process of creation of skyrmion lines, skyrmion linemore » segments are first created via the proliferation of monopoles and antimonopoles. Then these line segments join and span the whole system through the annihilation of monopoles. The skyrmion lines are destroyed via the proliferation of monopoles and antimonopoles at high currents, resulting in a chiral liquid phase. We also propose to create the monopoles in a controlled way by applying an inhomogeneous current to a crystal. Remarkably, an electric field component in the magnetic field direction proportional to the current squared in the low current region is induced by the motion of distorted skyrmion lines, in addition to the Hall and longitudinal voltage. As a result, the existence of monopoles can be inferred from transport or imaging measurements.« less

  9. Dynamics of Dirac strings and monopolelike excitations in chiral magnets under a current drive

    NASA Astrophysics Data System (ADS)

    Lin, Shi-Zeng; Saxena, Avadh

    2016-02-01

    Skyrmion lines in metallic chiral magnets carry an emergent magnetic field experienced by the conduction electrons. The inflow and outflow of this field across a closed surface is not necessarily equal, thus it allows for the existence of emergent monopoles. One example is a segment of skyrmion line inside a crystal, where a monopole and antimonopole pair is connected by the emergent magnetic flux line. This is a realization of Dirac stringlike excitations. Here we study the dynamics of monopoles in chiral magnets under an electric current. We show that in the process of creation of skyrmion lines, skyrmion line segments are first created via the proliferation of monopoles and antimonopoles. Then these line segments join and span the whole system through the annihilation of monopoles. The skyrmion lines are destroyed via the proliferation of monopoles and antimonopoles at high currents, resulting in a chiral liquid phase. We also propose to create the monopoles in a controlled way by applying an inhomogeneous current to a crystal. Remarkably, an electric field component in the magnetic field direction proportional to the current squared in the low current region is induced by the motion of distorted skyrmion lines, in addition to the Hall and longitudinal voltage. The existence of monopoles can be inferred from transport or imaging measurements.

  10. Dynamical Casimir-Polder interaction between a chiral molecule and a surface

    NASA Astrophysics Data System (ADS)

    Barcellona, Pablo; Passante, Roberto; Rizzuto, Lucia; Buhmann, Stefan Yoshi

    2016-03-01

    We develop a dynamical approach to study the Casimir-Polder force between an initially bare molecule and a magnetodielectric body at finite temperature, valid for arbitrary magnetodielectric properties and also in the presence of chiral effects. Switching on the interaction between the molecule and the field at a particular time, we study the resulting temporal evolution of the Casimir-Polder interaction. The dynamical self-dressing of the molecule and its population-induced dynamics are accounted for and discussed. In particular, we find that the Casimir-Polder force between a molecule and a surface oscillates in time with a frequency related to the molecular transition frequency. We verify that the dynamical force converges to the static result for time much larger than the inverse of the transition frequency, and it is particularly strong around the back-reaction time t =2 d /c , the time needed for the molecule to emit and reabsorb a photon reflected by the surface.

  11. Skyrmion dynamics in chiral ferromagnets under spin-transfer torque

    NASA Astrophysics Data System (ADS)

    Komineas, Stavros; Papanicolaou, Nikos

    2015-11-01

    We study the dynamics of skyrmions under spin-transfer torque in Dzyaloshinskii-Moriya materials with easy-axis anisotropy. In particular, we study the motion of a topological skyrmion with skyrmion number Q =1 and a nontopological skyrmionium with Q =0 using their linear momentum, virial relations, and numerical simulations. The nontopological Q =0 skyrmionium is accelerated in the direction of the current flow and it either reaches a steady state with constant velocity, or it is elongated to infinity. The steady-state velocity is given by a balance between current and dissipation and has an upper limit. In contrast, the topological Q =1 skyrmion converges to a steady state with constant velocity at an angle to the current flow. When the spin current stops the Q =1 skyrmion is spontaneously pinned, whereas the Q =0 skyrmionium continues propagation. Exact solutions for the propagating skyrmionium are identified as solutions of equations given numerically in a previous work. Further exact results for propagating skyrmions are given in the case of the pure exchange model. The traveling solutions provide arguments that a spin-polarized current will cause rigid motion of a skyrmion or a skyrmionium.

  12. Probing internal structure of {Lambda}(1405) in meson-baryon dynamics with chiral symmetry

    SciTech Connect

    Sekihara, Takayasu; Hyodo, Tetsuo; Jido, Daisuke

    2011-10-21

    The internal structure of the resonant {Lambda}(1405) state is investigated based on meson-baryon coupled-channels chiral dynamics, by evaluating density distributions obtained from the form factors of the {Lambda}(1405) state. The form factors are extracted from current-coupled scattering amplitudes in which the current is coupled to the constituent hadrons inside {Lambda}(1405). Using several probe interactions and channel decomposition, we find that the resonant {Lambda}(1405) state is dominantly composed of widely spread K-bar around N, with a small fraction of the escaping {pi}{Sigma} component.

  13. Excitation migration along oligophenylenevinylene-based chiral stacks: delocalization effects on transport dynamics.

    PubMed

    Beljonne, D; Hennebicq, E; Daniel, C; Herz, L M; Silva, C; Scholes, G D; Hoeben, F J M; Jonkheijm, P; Schenning, A P H J; Meskers, S C J; Phillips, R T; Friend, R H; Meijer, E W

    2005-06-01

    Atomistic models based on quantum-chemical calculations are combined with time-resolved spectroscopic investigations to explore the migration of electronic excitations along oligophenylenevinylene-based chiral stacks. It is found that the usual Pauli master equation (PME) approach relying on uncoherent transport between individual chromophores underestimates the excitation diffusion dynamics, monitored here by the time decay of the transient polarization anisotropy. A better agreement to experiment is achieved when accounting for excitation delocalization among acceptor molecules, as implemented in a modified version of the PME model. The same models are applied to study light harvesting and trapping in guest-host systems built from oligomers of different lengths. PMID:16852286

  14. Chiral Phosphoric Acid Catalyzed Asymmetric Ugi Reaction by Dynamic Kinetic Resolution of the Primary Multicomponent Adduct.

    PubMed

    Zhang, Yun; Ao, Yu-Fei; Huang, Zhi-Tang; Wang, De-Xian; Wang, Mei-Xiang; Zhu, Jieping

    2016-04-18

    Reaction of isonitriles with 3-(arylamino)isobenzofuran-1(3H)-ones in the presence of a catalytic amount of an octahydro (R)-binol-derived chiral phosphoric acid afforded 3-oxo-2-arylisoindoline-1-carboxamides in high yields with good to high enantioselectivities. An enantioselective Ugi four-center three-component reaction of 2-formylbenzoic acids, anilines, and isonitriles was subsequently developed for the synthesis of the same heterocycle. Mechanistic studies indicate that the enantioselectivity results from the dynamic kinetic resolution of the primary Ugi adduct, rather than from the C-C bond-forming process. The resulting heterocycle products are of significant medicinal importance. PMID:26997306

  15. Dynamical chiral symmetry breaking and confinement with an infrared-vanishing gluon propagator

    SciTech Connect

    Roberts, C.D.; Hawes, F.T.; Williams, A.G.

    1995-08-01

    We have studied a model Dyson-Schwinger equation for the quark propagator, constructed using an Ansatz for the gluon propagator of the form D(q) {approximately} q{sup 2}/[(q{sup 2}){sup 2} + b{sup 4}] and two Ansatze for the quark-gluon vertex: the minimal Ball-Chiu and the modified form suggested by Curtis and Pennington. The aim was to determine whether such a form of the gluon propagator, which was suggested by a number of authors and which recent lattice simulations of QCD suggest may be plausible, can support dynamical chiral symmetry breaking and ensure quark confinement. The form of the gluon propagator at small space-like momenta is crucial to the nature of the strong interaction spectrum but is presently unknown and information gathered in such studies is invaluable in supporting or invalidating given hypotheses. It was found that there is a critical value of b = b{sub c} such that the model does not support dynamical chiral symmetry breaking for b > b{sub c}. Further, it was shown that this form of gluon propagator cannot confine quarks. As a consequence this form represents a physically unreasonable model. In addition, these results formed the basis for an invited presentation at a workshop on quantum infrared physics and will be published in the proceedings.

  16. Structure and dynamics of ion clusters in linear octupole traps: Phase diagrams, chirality, and melting mechanisms

    SciTech Connect

    Yurtsever, E.; Onal, E. D.; Calvo, F.

    2011-05-15

    The stable structures and melting dynamics of clusters of identical ions bound by linear octupole radiofrequency traps are theoretically investigated by global optimization methods and molecular dynamics simulations. By varying the cluster sizes in the range of 10-1000 ions and the extent of trap anisotropy by more than one order of magnitude, we find a broad variety of stable structures based on multiple rings at small sizes evolving into tubular geometries at large sizes. The binding energy of these clusters is well represented by two contributions arising from isotropic linear and octupolar traps. The structures generally exhibit strong size effects, and chiral arrangements spontaneously emerge in many crystals. Sufficiently large clusters form nested, coaxial tubes with different thermal stabilities. As in isotropic octupolar clusters, the inner tubes melt at temperatures that are lower than the overall melting point.

  17. Structure and discrimination in chiral fluids: A molecular dynamics and integral equation study

    NASA Astrophysics Data System (ADS)

    Cann, N. M.; Das, B.

    2000-08-01

    An analysis of structure and discrimination in simple chiral fluids is presented. The chiral molecules consist of a central carbon bonded to four distinct groups. Molecular-dynamics simulations have been performed on a one-component chiral fluid and on two racemic mixtures. For the racemates, discrimination, as measured by differences in pair distribution functions, is present but found to be small. Intermolecular pair interaction energies are found to be good predictors of the magnitude and the sign (mirror-image pairs favored) of the differences observed in site-site distribution functions. For the one-component fluid, the quality of structural predictions from the reference-interaction-site method and Chandler-Silbey-Ladanyi (CSL) integral equation theories, with the hypernetted chain (HNC) and Percus-Yevick closures, has been examined. These theories generally provide a qualitatively correct description of the site-site distributions. Extensions beyond the HNC level have been explored: Two-field-point bridge diagrams have been explicitly evaluated and included in the CSL theory. The inclusion of these diagrams significantly improves the quality of the integral equation theories. Since the CSL theory has not been used extensively, and bridge diagrams have been evaluated in only a few instances, a detailed analysis of their impact is presented. For racemic mixtures, diagram evaluation is shown to be crucial. Specifically, the differences in site-site distributions for sites on identical and mirror-image molecules are found to originate from bridge diagrams which involve interactions between four-site, or larger, clusters. Discrimination cannot be predicted from an integral equation theory which neglects these diagrams.

  18. Finite volume effects in the chiral extrapolation of baryon masses

    NASA Astrophysics Data System (ADS)

    Lutz, M. F. M.; Bavontaweepanya, R.; Kobdaj, C.; Schwarz, K.

    2014-09-01

    We perform an analysis of the QCD lattice data on the baryon octet and decuplet masses based on the relativistic chiral Lagrangian. The baryon self-energies are computed in a finite volume at next-to-next-to-next-to-leading order (N3LO), where the dependence on the physical meson and baryon masses is kept. The number of free parameters is reduced significantly down to 12 by relying on large-Nc sum rules. Altogether we describe accurately more than 220 data points from six different lattice groups, BMW, PACS-CS, HSC, LHPC, QCDSF-UKQCD and NPLQCD. Values for all counterterms relevant at N3LO are predicted. In particular we extract a pion-nucleon sigma term of 39-1+2 MeV and a strangeness sigma term of the nucleon of σsN=84-4+28 MeV. The flavor SU(3) chiral limit of the baryon octet and decuplet masses is determined with (802±4) and (1103±6) MeV. Detailed predictions for the baryon masses as currently evaluated by the ETM lattice QCD group are made.

  19. Asymmetric coordination chemistry by chiral-auxiliary-mediated dynamic resolution under thermodynamic control.

    PubMed

    Lin, Zhijie; Gong, Lei; Celik, Mehmet Ali; Harms, Klaus; Frenking, Gernot; Meggers, Eric

    2011-02-01

    A method is presented for the asymmetric synthesis of chiral ruthenium polypyridyl complexes that starts from racemic cis-[Ru(pp)(2)Cl(2)] (pp=2,2'-bipyridine or 1,10-phenanthroline ligands). The chiral bidentate ligands (R)-2-(isopropylsulfinyl)phenol, (R)-SO, and preferably the more electron-rich derivative (R)-2-(isopropylsulfinyl)-4-methoxyphenol, (R)-SO', serve as convenient chiral auxiliaries for the conversion of racemic starting complexes (1a: pp=2,2'-bipyridine; 1b: pp=5,5'-dimethyl-2,2'-bipyridine; c: pp=1,10-phenanthroline) into single diastereomers Λ-[Ru(pp)(2){(R)-SO}]PF(6) (Λ-(S)-2a-c) or Λ-[Ru(pp)(2){(R)-SO'}]PF(6) (Λ-(S)-2a') under a thermodynamically controlled dynamic transformation. The complexes Λ-(S)-2a-c and Λ-(S)-2a' themselves are direct precursors for the generation of optically active ruthenium-polypyridyl complexes by trifluoroacetic-acid-induced replacement of the sulfinylphenolate auxiliaries with bidentate pp ligands under retention of configuration, thereby affording Λ-[Ru(pp)(3)](PF(6))(2) (3a-c) complexes with high enantiomeric ratios of ≥98:2. In particular, by employing the methoxy-modified chiral auxiliary (R)-SO', enantiomeric ratios of >99:1 were reached. In the strategy introduced here, the high steric crowding of an octahedral coordination sphere was exploited by placing a sulfur-based stereocenter in direct proximity to the ruthenium stereocenter, thereby leading to a large difference in the stabilities of the intermediate Λ-S and Δ-S diastereomers and thus providing the opportunity to find suitable reaction conditions for conversion of the destabilized diastereomer into the thermodynamically more-stable one. This method should be of high practical value for the asymmetric synthesis of ruthenium-polypyridyl complexes because it allows one to use readily available racemic ruthenium complexes as starting materials. PMID:21254425

  20. Determination of partial-wave inelasticities for elastic pion-nucleon scattering with the aid of experimental data on π N → ππ N processes in the beam-momentum range 300 < P beam < 500 MeV/ c

    NASA Astrophysics Data System (ADS)

    Kozhevnikov, V. A.; Sherman, S. G.

    2008-11-01

    The partial-wave inelasticity parameters of the amplitude for elastic pion-nucleon scattering are determined with the aid of the phenomenological amplitude for inelastic π N → ππ N processes in the energy range extending to the threshold for the production of two pions. The resulting inelasticity parameters are compared with their counterparts derived from modern partial-wave analyses. The largest inelastic-scattering cross section in the P11 wave is in excellent agreement with the analogous value from the analysis performed at the George Washington University in 2006. For other waves, however, the present results differ in the majority of cases from respective values given by partial-wave analyses (the distinctions are especially large for the isospin-3/2 amplitudes).

  1. Dynamical breakdown of Abelian gauge chiral symmetry by strong Yukawa interactions

    SciTech Connect

    Benes, Petr; Brauner, Tomas; Hosek, Jiri

    2007-03-01

    We consider a model with anomaly-free Abelian gauge axial-vector symmetry, which is intended to mimic the standard electroweak gauge chiral SU(2){sub L}xU(1){sub Y} theory. Within this model we demonstrate: (1) Strong Yukawa interactions between massless fermion fields and a massive scalar field carrying the axial charge generate dynamically the fermion and boson proper self-energies, which are ultraviolet-finite and chirally noninvariant. (2) Solutions of the underlying Schwinger-Dyson equations found numerically exhibit a huge amplification of the fermion mass ratios as a response to mild changes of the ratios of the Yukawa couplings. (3) The 'would-be' Nambu-Goldstone boson is a composite of both the fermion and scalar fields, and it gives rise to the mass of the axial-vector gauge boson. (4) Spontaneous breakdown of the gauge symmetry further manifests by mass splitting of the complex scalar and by new symmetry-breaking vertices, generated at one loop. In particular, we work out in detail the cubic vertex of the Abelian gauge boson.

  2. Nonequilibrium Chiral Dynamics and Two-Particle Correlations in the Time-Dependent Variational Approach with Squeezed States

    SciTech Connect

    Ikezi, N.; Asakawa, M.; Tsue, Y.

    2006-04-11

    We study the dynamics of chiral phase transition in the O(4) linear sigma model by using the time-dependent variational approach with squeezed states. Our numerical simulations show that large domains of the disoriented chiral condensate (DCC) are formed through the mode-mode correlation. We also present a result of an analysis of the two-particle correlation function for the pion fields, which reflects unique nature of the squeezed states. In particular, we will show that the chaoticity parameter is not close to zero even if DCC domains are produced.

  3. Spin dynamics under local gauge fields in chiral spin-orbit coupling systems

    NASA Astrophysics Data System (ADS)

    Tan, S. G.; Jalil, M. B. A.; Fujita, T.; Liu, X. J.

    2011-02-01

    We present a theoretical description of local spin dynamics in magnetic systems with a chiral spin texture and finite spin-orbit coupling (SOC). Spin precession about the relativistic effective magnetic field in a SOC system gives rise to a non-Abelian SU(2) gauge field reminiscent of the Yang-Mills field. In addition, the adiabatic relaxation of electron spin along the local spin yields an U(1) ⊗ U(1) topological gauge (Berry) field. We derive the corresponding equation of motion i.e. modified Landau-Lifshitz-Gilbert (LLG) equation, for the local spin under the influence of these effects. Focusing on the SU(2) gauge, we obtain the spin torque magnitude, and the amplitude and frequency of spin oscillations in this system. Our theoretical estimates indicate significant spin torque and oscillations in systems with large spin-orbit coupling, which may be utilized in technological applications such as current-induced magnetization-switching and tunable microwave oscillators.

  4. Dynamics of chiral primaries in AdS{sub 3}xS{sup 3}xT{sup 4}

    SciTech Connect

    Donos, Aristomenis; Jevicki, Antal

    2006-04-15

    We study in more detail the dynamics of chiral primaries of the D1/D5 system. From the CFT given by the S{sub N} orbifold a study of correlators resulted in an interacting (collective) theory of chiral operators. In AdS{sub 3}xS{sup 3} SUGRA we concentrate on general 1/2 BPS configurations described in terms of a fundamental string. We first establish a correspondence with the linearized field fluctuations and then present the nonlinear analysis. We evaluate in detail the symplectic form of the general degrees of freedom in SUGRA and confirm the appearance of chiral bosons. We then discuss the appearance of interactions and the cubic vertex, in correspondence with the S{sub N} collective field theory representation.

  5. Toroidal Interaction and Propeller Chirality of Hexaarylbenzenes. Dynamic Domino Inversion Revealed by Combined Experimental and Theoretical Circular Dichroism Studies.

    PubMed

    Kosaka, Tomoyo; Inoue, Yoshihisa; Mori, Tadashi

    2016-03-01

    Hexaarylbenzenes (HABs) have greatly attracted much attention due to their unique propeller-shaped structure and potential application in materials science, such as liquid crystals, molecular capsules/rotors, redox materials, nonlinear optical materials, as well as molecular wires. Less attention has however been paid to their propeller chirality. By introducing small point-chiral group(s) at the periphery of HABs, propeller chirality was effectively induced, provoking strong Cotton effects in the circular dichroism (CD) spectrum. Temperature and solvent polarity manipulate the dynamics of propeller inversion in solution. As such, whizzing toroids become more substantial in polar solvents and at an elevated temperature, where radial aromatic rings (propeller blades) prefer orthogonal alignment against the central benzene ring (C6 core), maximizing toroidal interactions. PMID:26882341

  6. Exploring Enantiospecific Ligand-Protein Interactions Using Cellular Membrane Affinity Chromatography: Chiral Recognition as a Dynamic Process

    PubMed Central

    Jozwiak, Krzysztof; Moaddel, Ruin; Ravichandran, Sarangan; Plazinska, Anita; Kozak, Joanna; Patel, Sharvil; Yamaguchi, Rika; Wainer, Irving

    2008-01-01

    The chiral recognition mechanisms responsible for the enantioselective binding on the α3β4 nicotinic acetyl choline receptor (α3β4 nAChR) and human organic cation transporter 1 (hOCT1) have been reviewed. The results indicate that chiral recognition on the α3β4 nAChR is a process involving initial tethering of dextromethorphan and levomethorphan at hydrophobic pockets within the central lumen followed by hydrogen bonding interactions favoring dextromethorphan. The second step is the defining enantioselective step. Studies with the hOCT1 indentified four binding sites within the transporter that participated in chiral recognition. Each of the enantiomers of the compounds used in the study interacted with three of these sites, while (R)-verapamil interacted with all four. Chiral recognition arose from the conformational adjustments required to produce optimum interactions. With respect to the prevailing interaction-based models, the data suggest that chiral recognition is a dynamic process and that the static point-based models should be amended to reflect this. PMID:18723411

  7. Dynamic Behavior of Clobazam on High-Performance Liquid Chromatography Chiral Stationary Phases.

    PubMed

    Sabia, Rocchina; De Martino, Michela; Cavazzini, Alberto; Villani, Claudio

    2016-01-01

    Clobazam, a 1,5-benzodiazepin-2,4-dione, is a chiral molecule because its ground state conformation features a nonplanar seven-membered ring lacking reflection symmetry elements. The two conformational enantiomers of clobazam interconvert at room temperature by a simple ring-flipping process. Variable temperature HPLC on the Pirkle type (R)-N-(3,5-dinitronenzoyl)phenylglycine and (R,R)-Whelk-O1 chiral stationary phases (CSPs) allowed us to separate for the first time the conformational enantiomers of clobazam and to observe peak coalescence-decoalescence phenomena due to concomitant separation and interconversion processes occurring on the same time scale. Clobazam showed temperature dependent dynamic high-performance liquid chromatography (HPLC) profiles with interconversion plateaus on the two CSPs indicative of on-column enantiomer interconversion. (enantiomerization) in the column temperature range between Tcol = 10°C and Tcol = 30°C, whereas on-column interconversion was absent at temperature close to or lower than Tcol = 5°C. Computer simulation of exchange-deformed HPLC profiles using a program based on the stochastic model yielded the apparent rate constants for the on-column enantiomerization and the corresponding free energy activation barriers. At Tcol = 20°C the averaged enantiomerization barriers, ΔG(‡), for clobazam were found in the range 21.08-21.53 kcal mol(-1) on the two CSPs. The experimental dynamic chromatograms and the corresponding interconversion barriers reported in this article are consistent with the literature data measured by DNMR at higher temperatures and in different solvents. PMID:26477466

  8. The quark-gluon vertex in Landau gauge QCD: Its role in dynamical chiral symmetry breaking and quark confinement

    NASA Astrophysics Data System (ADS)

    Alkofer, Reinhard; Fischer, Christian S.; Llanes-Estrada, Felipe J.; Schwenzer, Kai

    2009-01-01

    The infrared behavior of the quark-gluon vertex of quenched Landau gauge QCD is studied by analyzing its Dyson-Schwinger equation. Building on previously obtained results for Green functions in the Yang-Mills sector, we analytically derive the existence of power-law infrared singularities for this vertex. We establish that dynamical chiral symmetry breaking leads to the self-consistent generation of components of the quark-gluon vertex forbidden when chiral symmetry is forced to stay in the Wigner-Weyl mode. In the latter case the running strong coupling assumes an infrared fixed point. If chiral symmetry is broken, either dynamically or explicitly, the running coupling is infrared divergent. Based on a truncation for the quark-gluon vertex Dyson-Schwinger equation which respects the analytically determined infrared behavior, numerical results for the coupled system of the quark propagator and vertex Dyson-Schwinger equation are presented. The resulting quark mass function as well as the vertex function show only a very weak dependence on the current quark mass in the deep infrared. From this we infer by an analysis of the quark-quark scattering kernel a linearly rising quark potential with an almost mass independent string tension in the case of broken chiral symmetry. Enforcing chiral symmetry does lead to a Coulomb type potential. Therefore, we conclude that chiral symmetry breaking and confinement are closely related. Furthermore, we discuss aspects of confinement as the absence of long-range van der Waals forces and Casimir scaling. An examination of experimental data for quarkonia provides further evidence for the viability of the presented mechanism for quark confinement in the Landau gauge.

  9. Non-Markovian dynamics in chiral quantum networks with spins and photons

    NASA Astrophysics Data System (ADS)

    Ramos, Tomás; Vermersch, Benoît; Hauke, Philipp; Pichler, Hannes; Zoller, Peter

    2016-06-01

    We study the dynamics of chiral quantum networks consisting of nodes coupled by unidirectional or asymmetric bidirectional quantum channels. In contrast to familiar photonic networks where driven two-level atoms exchange photons via 1D photonic nanostructures, we propose and study a setup where interactions between the atoms are mediated by spin excitations (magnons) in 1D X X spin chains representing spin waveguides. While Markovian quantum network theory eliminates quantum channels as structureless reservoirs in a Born-Markov approximation to obtain a master equation for the nodes, we are interested in non-Markovian dynamics. This arises from the nonlinear character of the dispersion with band-edge effects, and from finite spin propagation velocities leading to time delays in interactions. To account for the non-Markovian dynamics we treat the quantum degrees of freedom of the nodes and connecting channel as a composite spin system with the surrounding of the quantum network as a Markovian bath, allowing for an efficient solution with time-dependent density matrix renormalization-group techniques. We illustrate our approach showing non-Markovian effects in the driven-dissipative formation of quantum dimers, and we present examples for quantum information protocols involving quantum state transfer with engineered elements as basic building blocks of quantum spintronic circuits.

  10. Molecular dynamics simulation and NMR investigation of the association of the β-blockers atenolol and propranolol with a chiral molecular micelle

    NASA Astrophysics Data System (ADS)

    Morris, Kevin F.; Billiot, Eugene J.; Billiot, Fereshteh H.; Hoffman, Charlene B.; Gladis, Ashley A.; Lipkowitz, Kenny B.; Southerland, William M.; Fang, Yayin

    2015-08-01

    Molecular dynamics simulations and NMR spectroscopy were used to compare the binding of two β-blocker drugs to the chiral molecular micelle poly-(sodium undecyl-(L)-leucine-valine). The molecular micelle is used as a chiral selector in capillary electrophoresis. This study is part of a larger effort to understand the mechanism of chiral recognition in capillary electrophoresis by characterizing the molecular micelle binding of chiral compounds with different geometries and charges. Propranolol and atenolol were chosen because their structures are similar, but their chiral interactions with the molecular micelle are different. Molecular dynamics simulations showed both propranolol enantiomers inserted their aromatic rings into the molecular micelle core and that (S)-propranolol associated more strongly with the molecular micelle than (R)-propranolol. This difference was attributed to stronger molecular micelle hydrogen bonding interactions experienced by (S)-propranolol. Atenolol enantiomers were found to bind near the molecular micelle surface and to have similar molecular micelle binding free energies.

  11. Effect of chirality on domain wall dynamics in molecular ferrimagnet [MnII(HL-pn)(H2O)][MnIII(CN)6]·2H2O

    NASA Astrophysics Data System (ADS)

    Mushenok, F.; Koplak, O.; Morgunov, R.

    2011-11-01

    In this paper we distinguish the contributions of switching, slide, creep and Debye relaxation modes of the domain wall dynamics to the low-frequency magnetic properties of chiral and racemic [MnII(HL-pn)(H2O)][MnIII(CN)6]·2H2O molecular ferrimagnets. We demonstrate that crystal and spin chirality affects the characteristic transition temperatures between different modes. In chiral crystals, transitions to the creep and Debye relaxation modes were observed at T = 7 K and 5 K, whereas in racemic crystals the same transitions occurred at higher temperatures T = 13 K and 9 K, respectively. Difference of the Peierls relief in chiral and racemic crystals is a possible reason of the chirality effect on the domain walls dynamics.

  12. Internal structure of the resonant {Lambda}(1405) state in chiral dynamics

    SciTech Connect

    Sekihara, Takayasu; Hyodo, Tetsuo; Jido, Daisuke

    2011-05-15

    The internal structure of the resonant {Lambda}(1405) state is investigated based on meson-baryon coupled-channels chiral dynamics by evaluating density distributions obtained from the form factors of the {Lambda}(1405) state. The form factors are defined as an extension of the ordinary stable particles and are directly evaluated from the current-coupled meson-baryon scattering amplitude, paying attention to the charge conservation of the probe interactions. For the resonant {Lambda}(1405) state we calculate the density distributions in two ways. One is on the pole position of the {Lambda}(1405) in the complex energy plane, which evaluates the resonant {Lambda}(1405) structure without contamination from nonresonant backgrounds, and another is on the real energy axis around the {Lambda}(1405) resonance energy, which may be achieved in experiments. Using several probe interactions and channel decomposition, we separate the various contributions to the internal structure of the {Lambda}(1405). As a result, we find that the resonant {Lambda}(1405) state is composed of widely spread K-bar around N, which gives dominant component inside the {Lambda}(1405), with escaping {pi}{Sigma} component. Furthermore, we consider K-barN bound state without decay channels, with which we can observe the internal structure of the bound state within real numbers. We also study the dependence of the form factors on the binding energy and meson mass. This verifies that the form factor defined through the current-coupled scattering amplitude serves as a natural generalization of the form factor for the resonance state. The relation between the interaction strength and the meson mass shows that the physical kaon mass appears to be within the suitable range to form a molecular bound state with the nucleon through the chiral SU(3) interaction.

  13. Scalar meson in dynamical and partially quenched two-flavor QCD: Lattice results and chiral loops

    SciTech Connect

    Prelovsek, S.; Dawson, C.; Izubuchi, T.; Orginos, K.; Soni, A.

    2004-11-01

    This is an exploratory study of the lightest nonsinglet scalar qq state on the lattice with two dynamical quarks. Domain wall fermions are used for both sea and valence quarks on a 16{sup 3}x32 lattice with an inverse lattice spacing of 1.7 GeV. We extract the scalar meson mass 1.58{+-}0.34 GeV from the exponential time dependence of the dynamical correlators with m{sub val}=m{sub sea} and N{sub f}=2. Since this statistical error bar from dynamical correlators is rather large, we analyze also the partially quenched lattice correlators with m{sub val}{ne}m{sub sea}. They are positive for m{sub val}{>=}m{sub sea} and negative for m{sub val}chiral perturbation theory (ChPT) and find it describes lattice correlators well. The leading unphysical contribution in partially quenched ChPT comes from the exchange of the two pseudoscalar fields and is also positive for m{sub val}{>=}m{sub sea} and negative for m{sub val}dynamical result and has an appreciably smaller error bar.

  14. Pion and Kaon Masses and Pion Form Factors from Dynamical Chiral-Symmetry Breaking with Light Constituent Quarks

    SciTech Connect

    Scadron, Michael D.; Kleefeld, Frieder; Rupp, George

    2007-02-27

    Light constituent quark masses and the corresponding dynamical quark masses are determined by data, the quark-level linear {sigma} model, and infrared QCD. This allows to define effective nonstrange and strange current quark masses, which reproduce the experimental pion and kaon masses very accurately, by simple additivity. In contrast, the usual nonstrange and strange current quarks employed by the Particle Data Group and Chiral Perturbation Theory do not allow a straightforward quantitative explanation of the pion and kaon masses.

  15. Mechanochemical Encapsulation of Fullerenes in Peptidic Containers Prepared by Dynamic Chiral Self-Sorting and Self-Assembly.

    PubMed

    Szymański, Marek; Wierzbicki, Michał; Gilski, Mirosław; Jędrzejewska, Hanna; Sztylko, Marcin; Cmoch, Piotr; Shkurenko, Aleksander; Jaskólski, Mariusz; Szumna, Agnieszka

    2016-02-24

    Molecular capsules composed of amino acid or peptide derivatives connected to resorcin[4]arene scaffolds through acylhydrazone linkers have been synthesized using dynamic covalent chemistry (DCC) and hydrogen-bond-based self-assembly. The dynamic character of the linkers and the preference of the peptides towards self-assembly into β-barrel-type motifs lead to the spontaneous amplification of formation of homochiral capsules from mixtures of different substrates. The capsules have cavities of around 800 Å(3) and exhibit good kinetic stability. Although they retain their dynamic character, which allows processes such as chiral self-sorting and chiral self-assembly to operate with high fidelity, guest complexation is hindered in solution. However, the quantitative complexation of even very large guests, such as fullerene C60 or C70 , is possible through the utilization of reversible covalent bonds or the application of mechanochemical methods. The NMR spectra show the influence of the chiral environment on the symmetry of the fullerene molecules, which results in the differentiation of diastereotopic carbon atoms for C70 , and the X-ray structures provide unique information on the modes of peptide-fullerene interactions. PMID:26808958

  16. Spin dynamics under local gauge fields in chiral spin-orbit coupling systems

    SciTech Connect

    Tan, S.G.; Jalil, M.B.A.; Fujita, T.; Liu, X.J.

    2011-02-15

    Research Highlights: > We derive a modified LLG equation in magnetic systems with spin-orbit coupling (SOC). > Our results are applied to magnetic multilayers, and DMS and magnetic Rashba systems. > SOC mediated magnetization switching is predicted in rare earth metals (large SOC). > The magnetization trajectory and frequency can be modulated by applied voltage. > This facilitates potential application as tunable microwave oscillators. - Abstract: We present a theoretical description of local spin dynamics in magnetic systems with a chiral spin texture and finite spin-orbit coupling (SOC). Spin precession about the relativistic effective magnetic field in a SOC system gives rise to a non-Abelian SU(2) gauge field reminiscent of the Yang-Mills field. In addition, the adiabatic relaxation of electron spin along the local spin yields an U(1) x U(1) topological gauge (Berry) field. We derive the corresponding equation of motion i.e. modified Landau-Lifshitz-Gilbert (LLG) equation, for the local spin under the influence of these effects. Focusing on the SU(2) gauge, we obtain the spin torque magnitude, and the amplitude and frequency of spin oscillations in this system. Our theoretical estimates indicate significant spin torque and oscillations in systems with large spin-orbit coupling, which may be utilized in technological applications such as current-induced magnetization-switching and tunable microwave oscillators.

  17. Weak solution of the non-perturbative renormalization group equation to describe dynamical chiral symmetry breaking

    NASA Astrophysics Data System (ADS)

    Aoki, Ken-Ichi; Kumamoto, Shin-Ichiro; Sato, Daisuke

    2014-04-01

    We analyze dynamical chiral symmetry breaking (Dχ SB) in the Nambu-Jona-Lasinio model by using the non-perturbative renormalization group equation. The equation takes the form of a two-dimensional partial differential equation for the multi-fermion effective interactions V(x,t) where x is the bar {ψ }ψ operator and t is the logarithm of the renormalization scale. The Dχ SB occurs due to the quantum corrections, which means it emerges at some finite tc while integrating the equation with respect to t. At t_c some singularities suddenly appear in V which is compulsory in the spontaneous symmetry breakdown. Therefore there is no solution of the equation beyond tc. We newly introduce the notion of a weak solution to get the global solution including the infrared limit t rArr ∞ and investigate its properties. The obtained weak solution is global and unique, and it perfectly describes the physically correct vacuum even in the case of the first order phase transition appearing in a finite-density medium. The key logic of deduction is that the weak solution we defined automatically convexifies the effective potential when treating the singularities.

  18. Stereolability of chiral ruthenium catalysts with frozen NHC ligand conformations investigated by dynamic-HPLC.

    PubMed

    Menta, Sergio; Pierini, Marco; Cirilli, Roberto; Grisi, Fabia; Perfetto, Alessandra; Ciogli, Alessia

    2015-10-01

    The stereolability of chiral Hoveyda-Grubbs II type ruthenium complexes bearing N-heterocyclic carbene (NHC) ligands with Syn-phenyl groups on the backbone and Syn- or Anti-oriented o-tolyl N-substituents was studied by resorting to dynamic high-performance liquid chromatography (D-HPLC). A complete chromatographic picture of the involved stereoisomers (four for Anti- and two for Syn-complexes) was achieved at very low temperatures (-53°C and -40°C respectively), at which the NHC-Ru bond rotations were frozen out. Inspection of the chromatographic profiles recorded at higher temperatures revealed the presence of plateau zones between the couples of either Syn or Anti stereoisomers, attesting to the active interconversion between the eluted species. Such dynamic chromatograms were successfully simulated through procedures based on both theoretical plate and classical stochastic models. The good superimposition achieved between experimental and simulated chromatographic profiles allowed determination of the related isomerization energy barriers (ΔGisom (#) ), all derived by rotation around the NHC-Ru bond. The obtained diastereomerization barriers between the Anti isomers were found in very good agreement with those previously measured by experimental nuclear magnetic resonance (NMR) and assessed through Density Functional Theory (DFT) calculations. With the same approach, for the first time we also determined the enantiomerization barrier of the Syn isomer. Focused changes to the structure of complex Syn, studied by a molecular modeling approach, were found suitable to strongly reduce the stereolability arising from rotation around the NHC-Ru bond. PMID:26250890

  19. Dynamic Chiral Nanoparticle Assemblies and Specific Chiroplasmonic Analysis of Cancer Cells.

    PubMed

    Zhao, Yuan; Yang, Yaxin; Zhao, Jing; Weng, Ping; Pang, Qingfeng; Song, Qijun

    2016-06-01

    Fabricated Ag@Au core-shell nanoparticle (CS NP) assemblies exhibit pronounced and reverse chiral bisignate plasmonic signals spanning 400 to 580 nm, in comparison to Ag NP assemblies. The time-dependent chiro-optical response of assemblies that shift with shell deposition is systematically recorded. Chiral Ag@Au CS NP assemblies first achieve the special discrimination of circulating tumor cells with HER2 overexpression. PMID:27115447

  20. A dynamical model for pion electroproduction on the nucleon

    SciTech Connect

    George L. Caia; Louis E. Wright; Vladimir Pascalutsa

    2005-06-01

    We develop a Lorenz- and gauge-invariant dynamical model for pion electroproduction in the resonance region. The model is based on solving of the Salpeter (instantaneous) equation for the pion-nucleon interaction with a hadron-exchange potential. We find that the one-particle-exchange kernel of the Salpeter equation for pion electroproduction develops an unphysical singularity for a finite value of Q{sup 2}. We analyze two methods of dealing with this problem. Results of our model are compared with recent single-polarization data for pion electroproduction.

  1. Chiral streamers

    SciTech Connect

    Zou, Dandan; Cao, Xin; Lu, Xinpei; Ostrikov, Kostya

    2015-10-15

    The interaction of time-varying electromagnetic fields and solid, liquid, and gaseous matter may lead to electrical breakdown phenomena through the excitation of ionization waves or streamers that control the dynamics of localized plasma propagation through the media. The streamers usually propagate along straight lines, either between random points in space or along a certain direction in a guided mode. Here, we report on a new type of plasma discharges with the regular helical propagation pattern driven by a pulsed dc voltage in nitrogen at sub-atmospheric-pressure conditions. The helical guided streamers, named chiral streamers or chi-streamers, are excited without any external magnetic fields, which commonly cause helical plasma motions. We also demonstrate a hybrid propagation mode involving the interchangeable chiral streamers and the straight-line propagating plasmas. High-speed, time-resolved optical imaging reveals that the chiral streamers and the hybrid patterns are made of spatially localized discrete plasma bullets, similar to the straight-line guided streamers. These results may enable effective control of propagation of confined plasmas and electromagnetic energy along pre-determined, potentially deterministic paths, which have important implications for the development of next-generation plasma-based radiation sources, communication devices, and medical treatments.

  2. Chiral streamers

    NASA Astrophysics Data System (ADS)

    Zou, Dandan; Cao, Xin; Lu, Xinpei; Ostrikov, Kostya Ken

    2015-10-01

    The interaction of time-varying electromagnetic fields and solid, liquid, and gaseous matter may lead to electrical breakdown phenomena through the excitation of ionization waves or streamers that control the dynamics of localized plasma propagation through the media. The streamers usually propagate along straight lines, either between random points in space or along a certain direction in a guided mode. Here, we report on a new type of plasma discharges with the regular helical propagation pattern driven by a pulsed dc voltage in nitrogen at sub-atmospheric-pressure conditions. The helical guided streamers, named chiral streamers or chi-streamers, are excited without any external magnetic fields, which commonly cause helical plasma motions. We also demonstrate a hybrid propagation mode involving the interchangeable chiral streamers and the straight-line propagating plasmas. High-speed, time-resolved optical imaging reveals that the chiral streamers and the hybrid patterns are made of spatially localized discrete plasma bullets, similar to the straight-line guided streamers. These results may enable effective control of propagation of confined plasmas and electromagnetic energy along pre-determined, potentially deterministic paths, which have important implications for the development of next-generation plasma-based radiation sources, communication devices, and medical treatments.

  3. Two-Pion Exchange Nucleon-Nucleon Potential: Relativistic Chiral Expansion

    SciTech Connect

    R. Higa; M.R. Robilotta

    2002-08-01

    We present a relativistic procedure for the chiral expansion of the two-pion exchange component of the NN potential, which emphasizes the role of intermediate pi N subamplitudes. The relationship between power counting in pi N and NN processes is discussed and results are expressed directly in terms of observable subthreshold coefficients. Interactions are determined by one and two-loop diagrams, involving pions, nucleons and other degrees of freedom, frozen into empirical subthreshold coefficients. The full evaluation of these diagrams produces amplitudes containing many different loop integrals. Their simplification by means of relations among these integrals leads to a set of intermediate results. Subsequent truncation to order(q{sup 4}) yields the relativistic potential, which depends on four loop integrals, representing bubble, triangle, crossed box and box diagrams. The bubble and triangle integrals are the same as in pi N scattering and we have shown that they also determine the chiral structures of box and crossed box integrals. Relativistic threshold effects were found to begin to contribute at order(q{sup 5}) only and our results should coincide with those of the standard heavy baryon approach. Checking this explicitly, we found differences due to the Goldberger-Treiman discrepancy and terms of order(q{sup 3}), possibly associated with the iteration of the OPEP.

  4. Calculation of doublet capture rate for muon capture in deuterium within chiral effective field theory

    NASA Astrophysics Data System (ADS)

    Adam, J.; Tater, M.; Truhlík, E.; Epelbaum, E.; Machleidt, R.; Ricci, P.

    2012-03-01

    The doublet capture rate Λ1 / 2 of the negative muon capture in deuterium is calculated employing the nuclear wave functions generated from accurate nucleon-nucleon (NN) potentials constructed at next-to-next-to-next-to-leading order of heavy-baryon chiral perturbation theory and the weak meson exchange current operator derived within the same formalism. All but one of the low-energy constants that enter the calculation were fixed from pion-nucleon and nucleon-nucleon scattering data. The low-energy constant dˆR (cD), which cannot be determined from the purely two-nucleon data, was extracted recently from the triton β-decay and the binding energies of the three-nucleon systems. The calculated values of Λ1 / 2 show a rather large spread for the used values of the dˆR. Precise measurement of Λ1 / 2 in the future will not only help to constrain the value of dˆR, but also provide a highly nontrivial test of the nuclear chiral EFT framework. Besides, the precise knowledge of the constant dˆR will allow for consistent calculations of other two-nucleon weak processes, such as proton-proton fusion and solar neutrino scattering on deuterons, which are important for astrophysics.

  5. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    DOE PAGESBeta

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the ordermore » we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.« less

  6. Chiral symmetry and chiral-symmetry breaking

    SciTech Connect

    Peskin, M.E.

    1982-12-01

    These lectures concern the dynamics of fermions in strong interaction with gauge fields. Systems of fermions coupled by gauge forces have a very rich structure of global symmetries, which are called chiral symmetries. These lectures will focus on the realization of chiral symmetries and the causes and consequences of thier spontaneous breaking. A brief introduction to the basic formalism and concepts of chiral symmetry breaking is given, then some explicit calculations of chiral symmetry breaking in gauge theories are given, treating first parity-invariant and then chiral models. These calculations are meant to be illustrative rather than accurate; they make use of unjustified mathematical approximations which serve to make the physics more clear. Some formal constraints on chiral symmetry breaking are discussed which illuminate and extend the results of our more explicit analysis. Finally, a brief review of the phenomenological theory of chiral symmetry breaking is presented, and some applications of this theory to problems in weak-interaction physics are discussed. (WHK)

  7. Enabling Light Work in Helical Self-Assembly for Dynamic Amplification of Chirality with Photoreversibility.

    PubMed

    Cai, Yunsong; Guo, Zhiqian; Chen, Jianmei; Li, Wenlong; Zhong, Liubiao; Gao, Ya; Jiang, Lin; Chi, Lifeng; Tian, He; Zhu, Wei-Hong

    2016-02-24

    Light-driven transcription and replication are always subordinate to a delicate chirality transfer. Enabling light work in construction of the helical self-assembly with reversible chiral transformation becomes attractive. Herein we demonstrate that a helical hydrogen-bonded self-assembly is reversibly photoswitched between photochromic open and closed forms upon irradiation with alternative UV and visible light, in which molecular chirality is amplified with the formation of helixes at supramolecular level. The characteristics in these superhelixes such as left-handed or right-handed twist and helical length, height, and pitch are revealed by SEM and AFM. The helical photoswitchable nanostructure provides an easily accessible route to an unprecedented photoreversible modulation in morphology, fluorescence, and helicity, with precise assembly/disassembly architectures similar to biological systems such as protein and DNA. PMID:26709946

  8. Dynamic Kinetic Resolution Approach for the Asymmetric Synthesis of Tetrahydrobenzodiazepines Using Transfer Hydrogenation by Chiral Phosphoric Acid.

    PubMed

    Horiguchi, Kosaku; Yamamoto, Eri; Saito, Kodai; Yamanaka, Masahiro; Akiyama, Takahiko

    2016-06-01

    Asymmetric synthesis of tetrahydrobenzodiazepines was achieved by transfer hydrogenation of dihydrobenzodiazepines with benzothiazoline having a hydrogen-bonding donor substituent by means of a newly synthesized chiral phosphoric acid. This method was applicable to various racemic dihydrobenzodiazepines to give the corresponding products in good yields with excellent diastereoselectivities and enantioselectivities taking advantage of the dynamic kinetic resolution. Furthermore, the effect of bulky substituent at 3,3'-position on the catalyst and hydrogen-bonding donor substituent on benzothiazoline was fully elucidated by the theoretical study. PMID:27150449

  9. Assembly of an Axially Chiral Dynamic Redox System with a Perfluorobiphenyl Skeleton into Dumbbell- or Tripod-type Electron Donors.

    PubMed

    Tamaoki, Hitomi; Katoono, Ryo; Fujiwara, Kenshu; Suzuki, Takanori

    2016-02-12

    The incorporation of F atoms endows a diethenylbiphenyl-based electron donor with configurational stability and SN Ar reactivity. The former enables the dynamic redox pair of (Rax)-1/(Rax ,R,R)-1(2+) to exhibit drastic UV/Vis and CD spectral changes upon electrolysis, whereas the latter makes it possible for (Rax)-1 to serve as a useful chiral synthon for the production of larger assemblies [(Rax ,Rax)-2 d,p,m and (Rax ,Rax ,Rax)-3] containing two or three dyrex units. These dyads and triad also exhibit a clean electrochiroptical response with isosbestic points owing to one-wave multi-electron transfer. PMID:26748461

  10. From chiral quark dynamics with Polyakov loop to the hadron resonance gas model

    SciTech Connect

    Arriola, E. R.; Salcedo, L. L.; Megias, E.

    2013-03-25

    Chiral quark models with Polyakov loop at finite temperature have been often used to describe the phase transition. We show how the transition to a hadron resonance gas is realized based on the quantum and local nature of the Polyakov loop.

  11. Electric-field-induced spin resonance in antiferromagnetic insulators: Inverse process of the dynamical chiral magnetic effect

    NASA Astrophysics Data System (ADS)

    Sekine, Akihiko; Chiba, Takahiro

    2016-06-01

    We propose a realization of the electric-field-induced antiferromagnetic resonance. We consider three-dimensional antiferromagnetic insulators with spin-orbit coupling characterized by the existence of a topological term called the θ term. By solving the Landau-Lifshitz-Gilbert equation in the presence of the θ term, we show that, in contrast to conventional methods using ac magnetic fields, the antiferromagnetic resonance state is realized by ac electric fields along with static magnetic fields. This mechanism can be understood as the inverse process of the dynamical chiral magnetic effect, an alternating current generation by magnetic fields. In other words, we propose a way to electrically induce the dynamical axion field in condensed matter. We discuss a possible experiment to observe our proposal, which utilizes the spin pumping from the antiferromagnetic insulator into a heavy metal contact.

  12. Topological Switching and Orbiting Dynamics of Colloidal Spheres Dressed with Chiral Nematic Solitons

    PubMed Central

    Porenta, T.; Čopar, S.; Ackerman, P. J.; Pandey, M. B.; Varney, M. C. M.; Smalyukh, I. I.; Žumer, S.

    2014-01-01

    Metastable configurations formed by defects, inclusions, elastic deformations and topological solitons in liquid crystals are a promising choice for building photonic crystals and metamaterials with a potential for new optical applications. Local optical modification of the director or introduction of colloidal inclusions into a moderately chiral nematic liquid crystal confined to a homeotropic cell creates localized multistable chiral solitons. Here we induce solitons that “dress” the dispersed spherical particles treated for tangential degenerate boundary conditions, and perform controlled switching of their state using focused optical beams. Two optically switchable distinct metastable states, toron and hopfion, bound to colloidal spheres into structures with different topological charges are investigated. Their structures are examined using Q-tensor based numerical simulations and compared to the profiles reconstructed from the experiments. A topological explanation of observed multistability is constructed. PMID:25477195

  13. Finite-volume effects and dynamical chiral symmetry breaking in QED{sub 3}

    SciTech Connect

    Goecke, Tobias; Williams, Richard; Fischer, Christian S.

    2009-02-01

    We investigate the impact of finite-volume effects on the critical number of flavors, N{sub f}{sup c}, for chiral symmetry restoration in QED{sub 3}. To this end we solve a set of coupled Dyson-Schwinger equations on a torus. For order parameters such as the anomalous dimension of the fermion wave function or the chiral condensate, we find substantial evidence for a large dependence on the volume. We observe a shift in N{sub f}{sup c} from values in the range of 3.61{<=}N{sub f}{sup c}{<=}3.84 in the infinite-volume and continuum limit down to values below N{sub f}{<=}1.5 at finite volumes in agreement with earlier results of Gusynin and Reenders in a simpler truncation scheme. These findings explain discrepancies in N{sub f}{sup c} between continuum and lattice studies.

  14. Spiral wave dynamics in the complex Ginzburg--Landau equation with broken chiral symmetry

    NASA Astrophysics Data System (ADS)

    Nam, Keeyeol; Ott, Edward; Gabbay, Michael; Guzdar, Parvez N.

    1998-07-01

    The effect of adding a chiral symmetry breaking term to the two-dimensional complex Ginzburg-Landau equation is investigated. We find that this term causes a shift in the frequency of the spiral wave solutions and that the sign of this shift depends on the topological charge (handedness) of the spiral. For parameters such that nearly stationary spiral domains form (called a “frozen” state), we find that, due to this charge-dependent frequency shift, the boundary between oppositely charged spiral domains moves, resulting in the domination of one domain of charge over the other. In addition, we introduce a quantity which measures the chirality of patterns and use it to characterize the transition between frozen and turbulent states. We also find that, depending on parameters, this transition occurs in two qualitatively distinct ways.

  15. Dynamic control over supramolecular handedness by selecting chiral induction pathways at the solution-solid interface.

    PubMed

    Fang, Yuan; Ghijsens, Elke; Ivasenko, Oleksandr; Cao, Hai; Noguchi, Aya; Mali, Kunal S; Tahara, Kazukuni; Tobe, Yoshito; De Feyter, Steven

    2016-07-01

    A dominant theme within the research on two-dimensional chirality is the sergeant-soldiers principle, wherein a small fraction of chiral molecules (sergeants) is used to skew the handedness of achiral molecules (soldiers) to generate a homochiral surface. Here, we have combined the sergeant-soldiers principle with temperature-dependent molecular self-assembly to unravel a peculiar chiral amplification mechanism at the solution-solid interface in which, depending on the concentration of a sergeant-soldiers solution, the majority handedness of the system can either be amplified or entirely reversed after an annealing step, furnishing a homochiral surface. Two discrete pathways that affect different stages of two-dimensional crystal growth are invoked for rationalizing this phenomenon and we present a set of experiments where the access to each pathway can be precisely controlled. These results demonstrate that a detailed understanding of subtle intermolecular and interfacial interactions can be used to induce drastic changes in the handedness of a supramolecular network. PMID:27325099

  16. Chiral quark model of nucleon spin-flavor structure with SU(3) and axial-U(1) breakings

    SciTech Connect

    Cheng, T.P.; Li, L.

    1998-01-01

    The chiral quark model with a nonet of Goldstone bosons can yield an adequate description of the observed proton flavor and spin structure. In a previous publication we have compared the results of an SU(3) symmetric calculation with the phenomenological findings based on experimental measurements and SU(3) symmetry relations. In this paper we discuss their SU(3) and axial U(1) breaking corrections. Our result demonstrates the broad consistency of the chiral quark model with the experimental observations of the proton spin-flavor structure. With two parameters, we obtain a very satifactory fit to the F/D ratios for the octet baryon masses and for their axial vector couplings, as well as the different quark flavor contributions to the proton spin. The result also can account for not only the light quark asymmetry {bar u}{minus}{bar d} but also the strange quark content {bar s} of the proton sea. SU(3) breaking is the key in reconciling the {bar s} value as measured in the neutrino charm production and that as deduced from the pion nucleon {sigma} term. {copyright} {ital 1997} {ital The American Physical Society}

  17. The liquid surface of chiral ionic liquids as seen from molecular dynamics simulations combined with intrinsic analysis.

    PubMed

    Lísal, Martin

    2013-12-01

    We present molecular-level insight into the liquid/gas interface of two chiral room-temperature ionic liquids (RTILs) derived from 1-n-butyl-3-methylimidazolium bromide ([bmim][Br]); namely, (R)-1-butyl-3-(3-hydroxy-2-methylpropyl)imidazolium bromide (hydroxypropyl) and 1-butyl-3-[(1R)-nopyl]imidazolium bromide (nopyl). We use our currently developed force field which was validated against the experimental bulk density, heat of vaporization, and surface tension of [bmim][Br]. The force field for the RTILs adopts the Chemistry at Harvard Molecular Mechanics (CHARMM) parameters for the intramolecular and repulsion-dispersion interactions along with the reduced partial atomic charges based on ab initio calculations. The net charges of the ions are around ±0.8e, which mimic the anion to cation charge transfer and many-body effects. Molecular dynamics simulations in the slab geometry combined with the intrinsic interface analysis are employed to provide a detailed description of the RTIL/gas interface in terms of the structural and dynamic properties of the interfacial, sub-interfacial, and central layers at a temperature of 300 K. The focus is on the comparison of the liquid/gas interface for the chiral RTILs with the interface for parent [bmim][Br]. The structure of the interface is elucidated by evaluating the surface roughness, intrinsic atomic density profiles, and orientation ordering of the cations. The dynamics of the ions at the interfacial region is characterized by computing the survival probability, and normal and lateral self-diffusion coefficients in the layers. PMID:24320388

  18. The liquid surface of chiral ionic liquids as seen from molecular dynamics simulations combined with intrinsic analysis

    SciTech Connect

    Lísal, Martin

    2013-12-07

    We present molecular-level insight into the liquid/gas interface of two chiral room-temperature ionic liquids (RTILs) derived from 1-n-butyl-3-methylimidazolium bromide ([bmim][Br]); namely, (R)-1-butyl-3-(3-hydroxy-2-methylpropyl)imidazolium bromide (hydroxypropyl) and 1-butyl-3-[(1R)-nopyl]imidazolium bromide (nopyl). We use our currently developed force field which was validated against the experimental bulk density, heat of vaporization, and surface tension of [bmim][Br]. The force field for the RTILs adopts the Chemistry at Harvard Molecular Mechanics (CHARMM) parameters for the intramolecular and repulsion-dispersion interactions along with the reduced partial atomic charges based on ab initio calculations. The net charges of the ions are around ±0.8e, which mimic the anion to cation charge transfer and many-body effects. Molecular dynamics simulations in the slab geometry combined with the intrinsic interface analysis are employed to provide a detailed description of the RTIL/gas interface in terms of the structural and dynamic properties of the interfacial, sub-interfacial, and central layers at a temperature of 300 K. The focus is on the comparison of the liquid/gas interface for the chiral RTILs with the interface for parent [bmim][Br]. The structure of the interface is elucidated by evaluating the surface roughness, intrinsic atomic density profiles, and orientation ordering of the cations. The dynamics of the ions at the interfacial region is characterized by computing the survival probability, and normal and lateral self-diffusion coefficients in the layers.

  19. Weak Solution Method of the Non-Perturbative Renormalization Group Equation to Describe Dynamical Chiral Symmetry Breaking and its Application to Beyond the Ladder Analysis in QCD

    NASA Astrophysics Data System (ADS)

    Aoki, Ken-Ichi; Sato, Daisuke

    The method of non-perturbative renormalization group (NPRG) is applied to the analysis of dynamical chiral symmetry breaking (DχSB) in QCD. We show that the DχSB solution of the NPRG flow equation can be obtained without the bosonization. The solution, having the singular point, can be authorized as the weak solution of partial differential equation, and can be easily evaluated using the method of the characteristic curve. Also we show that our non-ladder extended approximation improves almost perfectly the gauge dependence of the chiral condensates.

  20. Octet baryon masses and sigma terms from an SU(3) chiral extrapolation

    SciTech Connect

    Young, Ross; Thomas, Anthony

    2009-01-01

    We analyze the consequences of the remarkable new results for octet baryon masses calculated in 2+1- avour lattice QCD using a low-order expansion about the SU(3) chiral limit. We demonstrate that, even though the simulation results are clearly beyond the power-counting regime, the description of the lattice results by a low-order expansion can be significantly improved by allowing the regularisation scale of the effective field theory to be determined by the lattice data itself. The model dependence of our analysis is demonstrated to be small compared with the present statistical precision. In addition to the extrapolation of the absolute values of the baryon masses, this analysis provides a method to solve the difficult problem of fine-tuning the strange-quark mass. We also report a determination of the sigma terms for all of the octet baryons, including an accurate value of the pion-nucleon sigma term and the first determination of the strangeness sigma term based on 2+1-flavour l

  1. Interactions of vinca alkaloid subunits with chiral amido[4]resorcinarenes: a dynamic, kinetic, and spectroscopic study.

    PubMed

    Botta, Bruno; Fraschetti, Caterina; Novara, Francesca R; Tafi, Andrea; Sacco, Fabiola; Mannina, Luisa; Sobolev, Anatoli P; Mattay, Jochen; Letzel, Matthias C; Speranza, Maurizio

    2009-05-01

    The stereoselectivity of the reaction between (R)-(-)-2-butylamine and the diastereomeric proton-bound complexes of (+)-catharanthine (C) or (-)-vindoline (V) with some chiral amido[4]resorcinarenes has been investigated in the gas phase by ESI-FT-ICR-MS. The reaction stereoselectivity (0.56 < k(homo)/k(hetero) < 16.9) is found to depend critically on the functional groups present in the chiral pendants of the hosts. Rationalisation of the kinetic results is based on careful computational and spectroscopic studies of the most stable conformations of (+)-catharanthine and its protonated form in the isolated state and in water, as well as in a representative host structure. The emerging picture points to the relevant diastereomeric proton-bound complexes as quasi-degenerate, thus suggesting that their stereoselectivity in the guest exchange reaction is mostly due to kinetic factors. The results of this study may represent a starting point for a deeper comprehension of the intrinsic factors that endow these molecules, and their dimeric forms, with their biochemical properties. PMID:19590774

  2. Uncertainty Analysis and Order-by-Order Optimization of Chiral Nuclear Interactions

    NASA Astrophysics Data System (ADS)

    Carlsson, B. D.; Ekström, A.; Forssén, C.; Strömberg, D. Fahlin; Jansen, G. R.; Lilja, O.; Lindby, M.; Mattsson, B. A.; Wendt, K. A.

    2016-01-01

    Chiral effective field theory (χ EFT ) provides a systematic approach to describe low-energy nuclear forces. Moreover, χ EFT is able to provide well-founded estimates of statistical and systematic uncertainties—although this unique advantage has not yet been fully exploited. We fill this gap by performing an optimization and statistical analysis of all the low-energy constants (LECs) up to next-to-next-to-leading order. Our optimization protocol corresponds to a simultaneous fit to scattering and bound-state observables in the pion-nucleon, nucleon-nucleon, and few-nucleon sectors, thereby utilizing the full model capabilities of χ EFT . Finally, we study the effect on other observables by demonstrating forward-error-propagation methods that can easily be adopted by future works. We employ mathematical optimization and implement automatic differentiation to attain efficient and machine-precise first- and second-order derivatives of the objective function with respect to the LECs. This is also vital for the regression analysis. We use power-counting arguments to estimate the systematic uncertainty that is inherent to χ EFT , and we construct chiral interactions at different orders with quantified uncertainties. Statistical error propagation is compared with Monte Carlo sampling, showing that statistical errors are, in general, small compared to systematic ones. In conclusion, we find that a simultaneous fit to different sets of data is critical to (i) identify the optimal set of LECs, (ii) capture all relevant correlations, (iii) reduce the statistical uncertainty, and (iv) attain order-by-order convergence in χ EFT . Furthermore, certain systematic uncertainties in the few-nucleon sector are shown to get substantially magnified in the many-body sector, in particular when varying the cutoff in the chiral potentials. The methodology and results presented in this paper open a new frontier for uncertainty quantification in ab initio nuclear theory.

  3. Dynamic mechanism of the ferroelectric to antiferroelectric phase transition in chiral smectic liquid crystals.

    PubMed

    Song, Jang-Kun; Fukuda, Atsuo; Vij, J K

    2008-08-29

    The temperature-induced phase transition between the chiral smectic phases, antiferroelectric (smectic-C(A)*) and ferroelectric (smectic-C*), is found to occur through solitary wave propagation. We measure the free energy, which shows a double well shape in the entire SmC(A)* temperature range and the global minimum is found to shift from the antiferroelectric order to the ferroelectric order at the transition temperature. However, any significant supercooling is not observed and the transition cannot be described by the first order Landau-de Gennes theory, where the double well potential exists only in a narrow range of temperatures. This implies that the SmC(A)*-SmC* transition can occur only nonhomogeneously through the solitary wave propagation which overcomes the high energy barrier between the two minima. PMID:18851661

  4. Chiral superconductors.

    PubMed

    Kallin, Catherine; Berlinsky, John

    2016-05-01

    Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed. PMID:27088452

  5. Chiral squaring

    NASA Astrophysics Data System (ADS)

    Nagy, S.

    2016-07-01

    We construct the states and symmetries of N = 4 super-Yang-Mills by tensoring two N = 1 chiral multiplets and introducing two extra SUSY generators. This allows us to write the maximal N = 8 supergravity as four copies of the chiral multiplet. We extend this to higher dimensions and discuss applications to scattering amplitudes.

  6. Chiral superconductors

    NASA Astrophysics Data System (ADS)

    Kallin, Catherine; Berlinsky, John

    2016-05-01

    Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed.

  7. The pion nucleon scattering lengths from pionic hydrogen and deuterium

    NASA Astrophysics Data System (ADS)

    Schröder, H.-Ch.; Badertscher, A.; Goudsmit, P. F. A.; Janousch, M.; Leisi, H. J.; Matsinos, E.; Sigg, D.; Zhao, Z. G.; Chatellard, D.; Egger, J.-P.; Gabathuler, K.; Hauser, P.; Simons, L. M.; Rusi El Hassani, A. J.

    2001-07-01

    This is the final publication of the ETH Zurich Neuchâtel PSI collaboration on the pionic hydrogen and deuterium precision X-ray experiments. We describe the recent hydrogen 3 p 1 s measurement, report on the determination of the Doppler effect correction to the transition line width, analyze the deuterium shift measurement and discuss implications of the combined hydrogen and deuterium results. From the pionic hydrogen 3 p 1 s transition experiments we obtain the strong-interaction energy level shift \\varepsilon_{1s} = -7.108±0.013 (stat.)±0.034 (syst.) eV and the total decay width Γ_{1s} = 0.868±0.040 (stat.)±0.038 (syst.) eV of the 1s state. Taking into account the electromagnetic corrections we find the hadronic π N s-wave scattering amplitude a_{π-prightarrowπ-p} = 0.0883±0.0008 m_{π}^{-1} for elastic scattering and a_{π-prightarrowπ0n} = -0.128±0.006 m_{π} ^{-1} for single charge exchange, respectively. We then combine the pionic hydrogen results with the 1 s level shift measurement on pionic deuterium and test isospin symmetry of the strong interaction: our data are still compatible with isospin symmetry. The isoscalar and isovector π N scattering lengths (within the framework of isospin symmetry) are found to be b_0 = -0.0001^{+0.0009}_{-0.0021} m_{π}^{-1} and b1 = -0.0885^{+0.0010}_{-0.0021} m_{π} ^{-1}, respectively. Using the GMO sum rule, we obtain from b_1 a new value of the π N coupling constant (g_{π N} = 13.21_{-0.05}^{+0.11}) from which follows the Goldberger Treiman discrepancy Δ_{{GT}} =0.027_{-0.008}^{+0.012}. The new values of b_0 and g_{π N} imply an increase of the nucleon sigma term by at least 9 MeV.

  8. Delta: the First Pion Nucleon Resonance - Its Discovery and Applications

    DOE R&D Accomplishments Database

    Nagle, D. E.

    1984-07-01

    It is attempted to recapture some of the fun and excitement of the pion-scattering work that led to the discovery of what is now called the delta particle. How significant this discovery was became apparent only gradually. That the delta is alive today and thriving at Los Alamos (as well as other places) is described.

  9. Delta: the first pion nucleon resonance - its discovery and applications

    SciTech Connect

    Nagle, D.E.

    1984-07-01

    It is attempted to recapture some of the fun and excitement of the pion-scattering work that led to the discovery of what is now called the delta particle. How significant this discovery was became apparent only gradually. That the delta is alive today and thriving at Los Alamos (as well as other places) is described.

  10. Precision Measurements of Neutral Pion Electroproduction Near Threshold: A Test of Chiral QCD Dynamics

    SciTech Connect

    Lindgren, Richard A.; Chirapatpimol, Khem; Smith, Lee Cole

    2013-08-01

    Preliminary results are presented from an experiment to measure {pi}{sup 0} electroproduction at and above threshold using the p(e;e' p){pi}{sup 0} reaction. The data were taken at a beam energy of 1192 MeV using a two-spectrometer setup in Hall A at Jefferson Lab. For the first time in {pi}{sup 0} threshold electroproduction, complete coverage of the {phi}{sub {pi}}* and {theta}{sub {pi}}* angles in the center-of-mass (C.M.) was obtained for the invariant mass region up to {Delta}W=18 MeV above the {pi}{sup 0} threshold. At the same time our invariant momentum transfer squared covers the range Q{sup 2} = 0.05-0.15 (GeV/c){sup 2} with twelve bins in Q{sup 2}. The improved kinematic coverage in C.M., W and Q{sup 2} will better constrain theoretical interpretations of the data using phenomenological models and QCD-inspired models such as Heavy Baryon Chiral Perturbation Theory.

  11. Dynamic scaffold of chiral binaphthol derivatives with the alkynylplatinum(II) terpyridine moiety

    PubMed Central

    Leung, Sammual Yu-Lut; Lam, Wai Han; Yam, Vivian Wing-Wah

    2013-01-01

    Platinum(II)-containing complexes with inherently chiral binaphthol derivatives display a versatile scaffold between random coils and single-turn helical strands, in which the conformational transition is controlled by the Pt···Pt and π−π interactions of alkynylplatinum(II) terpyridine moiety upon solvent and temperature modulation. The bisignate Cotton effect in the circular dichroism spectra is indicative of the cooperative transformation from random coil state to a compact single-turn M- or P- helix. More importantly, as revealed by the appearance of new UV-vis absorption and emission bands during conformational change, the self-assembly of the platinum(II)-containing complex into a helical structure is assisted by the metal···metal and π−π interactions of the alkynylplatinum(II) terpyridine moieties. The folded structure with stabilization via metal···metal and π−π interactions has been supported by density functional theory calculations, which provide insights into the folded geometry of these kind of metallo-foldamers. PMID:23542379

  12. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    SciTech Connect

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the order we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.

  13. Delta-nucleus dynamics: proceedings of symposium

    SciTech Connect

    Lee, T.S.H.; Geesaman, D.F.; Schiffer, J.P.

    1983-10-01

    The appreciation of the role in nuclear physics of the first excited state of the nucleon, the delta ..delta..(1232), has grown rapidly in the past decade. The delta resonance dominates nuclear reactions induced by intermediate energy pions, nucleons, and electromagnetic probes. It is also the most important non-nucleonic degree of freedom needed to resolve many fundamental problems encountered in the study of low-energy nuclear phenomena. Clearly, a new phase of nuclear physics has emerged and conventional thinking must be extended to account for this new dimension of nuclear dynamics. The most challenging problem we are facing is how a unified theory can be developed to describe ..delta..-nucleus dynamics at all energies. In exploring this new direction, it is important to have direct discussions among researchers with different viewpoints. Separate entries were prepared for the 49 papers presented. (WHK)

  14. From quarks and gluons to hadrons: Chiral symmetry breaking in dynamical QCD

    NASA Astrophysics Data System (ADS)

    Braun, Jens; Fister, Leonard; Pawlowski, Jan M.; Rennecke, Fabian

    2016-08-01

    We present an analysis of the dynamics of two-flavor QCD in the vacuum. Special attention is paid to the transition from the high-energy quark-gluon regime to the low-energy regime governed by hadron dynamics. This is done within a functional renormalization group approach to QCD amended by dynamical hadronization techniques. These techniques allow us to describe conveniently the transition from the perturbative high-energy regime to the nonperturbative low-energy limit without suffering from a fine-tuning of model parameters. In the present work, we apply these techniques to two-flavor QCD with physical quark masses and show how the dynamics of the dominant low-energy degrees of freedom emerge from the underlying quark-gluon dynamics.

  15. Chiral Graphene Quantum Dots.

    PubMed

    Suzuki, Nozomu; Wang, Yichun; Elvati, Paolo; Qu, Zhi-Bei; Kim, Kyoungwon; Jiang, Shuang; Baumeister, Elizabeth; Lee, Jaewook; Yeom, Bongjun; Bahng, Joong Hwan; Lee, Jaebeom; Violi, Angela; Kotov, Nicholas A

    2016-02-23

    Chiral nanostructures from metals and semiconductors attract wide interest as components for polarization-enabled optoelectronic devices. Similarly to other fields of nanotechnology, graphene-based materials can greatly enrich physical and chemical phenomena associated with optical and electronic properties of chiral nanostructures and facilitate their applications in biology as well as other areas. Here, we report that covalent attachment of l/d-cysteine moieties to the edges of graphene quantum dots (GQDs) leads to their helical buckling due to chiral interactions at the "crowded" edges. Circular dichroism (CD) spectra of the GQDs revealed bands at ca. 210-220 and 250-265 nm that changed their signs for different chirality of the cysteine edge ligands. The high-energy chiroptical peaks at 210-220 nm correspond to the hybridized molecular orbitals involving the chiral center of amino acids and atoms of graphene edges. Diverse experimental and modeling data, including density functional theory calculations of CD spectra with probabilistic distribution of GQD isomers, indicate that the band at 250-265 nm originates from the three-dimensional twisting of the graphene sheet and can be attributed to the chiral excitonic transitions. The positive and negative low-energy CD bands correspond to the left and right helicity of GQDs, respectively. Exposure of liver HepG2 cells to L/D-GQDs reveals their general biocompatibility and a noticeable difference in the toxicity of the stereoisomers. Molecular dynamics simulations demonstrated that d-GQDs have a stronger tendency to accumulate within the cellular membrane than L-GQDs. Emergence of nanoscale chirality in GQDs decorated with biomolecules is expected to be a general stereochemical phenomenon for flexible sheets of nanomaterials. PMID:26743467

  16. Dynamical chiral symmetry breaking in Yukawa and Wess-Zumino models

    SciTech Connect

    Bashir, A.; Diaz Cruz, J. L.

    1999-10-25

    We study dynamical mass generation for fermions in the Yukawa and the supersymmetric Wess-Zumino (WZ) models. It is found that above a critical coupling fermion mass can be generated dynamically in the Yukawa model, whereas in the WZ model the fermion does not acquire mass. We also show that the supersymmetry (SUSY) preserving solution is permitted and hence the scalars may not acquire mass either.

  17. Renormalization of the low-energy constants of chiral perturbation theory from loops with dynamical vector mesons

    NASA Astrophysics Data System (ADS)

    Terschlüsen, Carla; Leupold, Stefan

    2016-07-01

    Starting from a relativistic Lagrangian for pseudoscalar Goldstone bosons and vector mesons in the antisymmetric tensor representation, a one-loop calculation is performed to pin down the divergent structures that appear for the effective low-energy action at chiral orders Q2 and Q4 . The corresponding renormalization-scale dependencies of all low-energy constants up to chiral order Q4 are determined. Calculations are carried out for both the pseudoscalar octet and the pseudoscalar nonet, the latter in the framework of chiral perturbation theory in the limit of a large number of colors.

  18. Isotopic chirality

    SciTech Connect

    Floss, H.G.

    1994-12-01

    This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.

  19. A new perspective on the Faddeev equations and the K¯NN system from chiral dynamics and unitarity in coupled channels

    NASA Astrophysics Data System (ADS)

    Oset, E.; Jido, D.; Sekihara, T.; Martinez Torres, A.; Khemchandani, K. P.; Bayar, M.; Yamagata-Sekihara, J.

    2012-05-01

    We review recent work concerning the K¯N interaction and Faddeev equations with chiral dynamics which allow us to look at the K¯NN from a different perspective and pay attention to problems that have been posed in previous studies on the subject. We then show results which provide extra experimental evidence on the existence of two Λ(1405) states. Then show the findings of a recent approach to Faddeev equations using chiral unitary dynamics, where an explicit cancellation of the two-body off-shell amplitude with three-body forces stemming from the same chiral Lagrangians takes place. This removal of the unphysical off-shell part of the amplitudes is most welcome and renders the approach unambiguous, showing that only on-shell two-body amplitudes need to be used. With this information in mind we use an approximation to the Faddeev equations within the fixed center approximation to study the K¯NN system, providing answers within this approximation to questions that have been brought before and evaluating binding energies and widths of this three-body system. As a novelty with respect to recent work on the topic we find a bound state of the system with spin S=1, like a bound state of K¯-deuteron, less bound that the one of S=0, where all recent efforts have been devoted. The width is relatively large in this case, suggesting problems in a possible experimental observation.

  20. Consequences of chirality on the dynamics of a water-soluble supramolecular polymer.

    PubMed

    Baker, Matthew B; Albertazzi, Lorenzo; Voets, Ilja K; Leenders, Christianus M A; Palmans, Anja R A; Pavan, Giovanni M; Meijer, E W

    2015-01-01

    The rational design of supramolecular polymers in water is imperative for their widespread use, but the design principles for these systems are not well understood. Herein, we employ a multi-scale (spatial and temporal) approach to differentiate two analogous water-soluble supramolecular polymers: one with and one without a stereogenic methyl. Initially aiming simply to understand the molecular behaviour of these systems in water, we find that while the fibres may look identical, the introduction of homochirality imparts a higher level of internal order to the supramolecular polymer. Although this increased order does not seem to affect the basic dimensions of the supramolecular fibres, the equilibrium dynamics of the polymers differ by almost an order of magnitude. This report represents the first observation of a structure/property relationship with regard to equilibrium dynamics in water-soluble supramolecular polymers. PMID:25698667

  1. Consequences of chirality on the dynamics of a water-soluble supramolecular polymer

    PubMed Central

    Baker, Matthew B.; Albertazzi, Lorenzo; Voets, Ilja K.; Leenders, Christianus M.A.; Palmans, Anja R.A.; Pavan, Giovanni M.; Meijer, E.W.

    2015-01-01

    The rational design of supramolecular polymers in water is imperative for their widespread use, but the design principles for these systems are not well understood. Herein, we employ a multi-scale (spatial and temporal) approach to differentiate two analogous water-soluble supramolecular polymers: one with and one without a stereogenic methyl. Initially aiming simply to understand the molecular behaviour of these systems in water, we find that while the fibres may look identical, the introduction of homochirality imparts a higher level of internal order to the supramolecular polymer. Although this increased order does not seem to affect the basic dimensions of the supramolecular fibres, the equilibrium dynamics of the polymers differ by almost an order of magnitude. This report represents the first observation of a structure/property relationship with regard to equilibrium dynamics in water-soluble supramolecular polymers. PMID:25698667

  2. Consequences of chirality on the dynamics of a water-soluble supramolecular polymer

    NASA Astrophysics Data System (ADS)

    Baker, Matthew B.; Albertazzi, Lorenzo; Voets, Ilja K.; Leenders, Christianus M. A.; Palmans, Anja R. A.; Pavan, Giovanni M.; Meijer, E. W.

    2015-02-01

    The rational design of supramolecular polymers in water is imperative for their widespread use, but the design principles for these systems are not well understood. Herein, we employ a multi-scale (spatial and temporal) approach to differentiate two analogous water-soluble supramolecular polymers: one with and one without a stereogenic methyl. Initially aiming simply to understand the molecular behaviour of these systems in water, we find that while the fibres may look identical, the introduction of homochirality imparts a higher level of internal order to the supramolecular polymer. Although this increased order does not seem to affect the basic dimensions of the supramolecular fibres, the equilibrium dynamics of the polymers differ by almost an order of magnitude. This report represents the first observation of a structure/property relationship with regard to equilibrium dynamics in water-soluble supramolecular polymers.

  3. Helical motion of chiral liquid crystal droplets

    NASA Astrophysics Data System (ADS)

    Yamamoto, Takaki; Sano, Masaki

    Artificial swimmers have been intensively studied to understand the mechanism of the locomotion and collective behaviors of cells and microorganisms. Among them, most of the artificial swimmers are designed to move along the straight path. However, in biological systems, chiral dynamics such as circular and helical motion are quite common because of the chirality of their bodies, which are made of chiral biomolecules. To understand the role of the chirality in the physics of microswimmers, we designed chiral artificial swimmers and the theoretical model for the chiral motion. We found that chiral liquid crystal droplets, when dispersed in surfactant solutions, swim in the helical path induced by the Marangoni effect. We will discuss the mechanism of the helical motion with our phenomenological model. This work is supported by Grant-in-Aid for JSPS Fellows (Grant No. 26.9814), and MEXT KAKENHI Grant No. 25103004.

  4. Chiral quark dynamics and topological charge: The role of the Ramond-Ramond U(1) gauge field in holographic QCD

    NASA Astrophysics Data System (ADS)

    Thacker, H. B.; Xiong, Chi; Kamat, Ajinkya S.

    2011-11-01

    The Witten-Sakai-Sugimoto construction of holographic QCD in terms of D4 color branes and D8 flavor branes in type IIA string theory is used to investigate the role of topological charge in the chiral dynamics of quarks in QCD. The QCD theta term arises from a compactified five-dimensional Chern-Simons term on the D4 branes. This term couples the QCD topological charge to the Ramond-Ramond (RR) U(1) gauge field of type IIA string theory. For large Nc the contribution of instantons (D0 branes) is suppressed, and the nonzero topological susceptibility of pure-glue QCD is attributed to the presence of D6 branes, which constitute magnetic sources of the RR gauge field. The topological charge of QCD is required, by an anomaly inflow argument, to coincide in space-time with the intersection of the D6 branes and the D4 color branes. This clarifies the relation between D6 branes and the coherent, codimension-one topological charge membranes observed in QCD Monte Carlo calculations. Using open-string/closed-string duality, we interpret a quark loop (represented by a D4-D8 open-string loop) in terms of closed-string exchange between color and flavor branes. The role of the RR gauge field in quark-antiquark annihilation processes is discussed. RR exchange in the s-channel generates a 4-quark contact term which produces an η' mass insertion and provides an explanation for the observed spin-parity structure of the Okubo-Zweig-Iizuka rule. The (log⁡DetU)2 form of the U(1) anomaly emerges naturally. RR exchange in the t-channel of the qq¯ scattering amplitude produces a Nambu-Jona-Lasinio interaction which may provide a mechanism for spontaneous breaking of SU(Nf)×SU(Nf).

  5. A molecular dynamics simulation study of the association of 1,1";-binaphthyl-2,2";-diyl hydrogenphosphate enantiomers with a chiral molecular micelle

    NASA Astrophysics Data System (ADS)

    Morris, Kevin F.; Billiot, Eugene J.; Billiot, Fereshteh H.; Gladis, Ashley A.; Lipkowitz, Kenny B.; Southerland, William M.; Fang, Yayin

    2014-08-01

    Molecular dynamics (MD) simulations were used to investigate the binding of 1,1";-binaphthyl-2,2";-diyl hydrogenphosphate (BNP) enantiomers to the molecular micelle poly-(sodium undecyl-(L,L)-leucine-valine) (poly(SULV)). Poly(SULV) is used as a chiral selector in capillary electrophoresis separations. Four poly(SULV) binding pockets were identified and either (R)-BNP or (S)-BNP were docked into each pocket. MD simulations were then used to identify the preferred BNP binding site. Within the preferred site, both enantiomers formed hydrogen bonds with poly(SULV) and penetrated into the poly(SULV) core. Comparisons of BNP enantiomer binding to the preferred poly(SULV) pocket showed that (S)-BNP formed stronger hydrogen bonds, moved deeper into the binding site, and had a lower poly(SULV) binding free energy than the (R) enantiomer. Finally, MD simulation results were in agreement with capillary electrophoresis and NMR experiments. Each technique showed (S)-BNP interacted more strongly with poly(SULV) than (R)-BNP and that the site of chiral recognition was near the poly(SULV) leucine chiral center.

  6. Punctuated Chirality

    NASA Astrophysics Data System (ADS)

    Gleiser, Marcelo; Thorarinson, Joel; Walker, Sara Imari

    2008-12-01

    Most biomolecules occur in mirror, or chiral, images of each other. However, life is homochiral: proteins contain almost exclusively L-amino acids, while only D-sugars appear in RNA and DNA. The mechanism behind this fundamental asymmetry of life remains an open problem. Coupling the spatiotemporal evolution of a general autocatalytic polymerization reaction network to external environmental effects, we show through a detailed statistical analysis that high intensity and long duration events may drive achiral initial conditions towards chirality. We argue that life’s homochirality resulted from sequential chiral symmetry breaking triggered by environmental events, thus extending the theory of punctuated equilibrium to the prebiotic realm. Applying our arguments to other potentially life-bearing planetary platforms, we predict that a statistically representative sampling will be racemic on average.

  7. Punctuated chirality.

    PubMed

    Gleiser, Marcelo; Thorarinson, Joel; Walker, Sara Imari

    2008-12-01

    Most biomolecules occur in mirror, or chiral, images of each other. However, life is homochiral: proteins contain almost exclusively L-amino acids, while only D-sugars appear in RNA and DNA. The mechanism behind this fundamental asymmetry of life remains an open problem. Coupling the spatiotemporal evolution of a general autocatalytic polymerization reaction network to external environmental effects, we show through a detailed statistical analysis that high intensity and long duration events may drive achiral initial conditions towards chirality. We argue that life's homochirality resulted from sequential chiral symmetry breaking triggered by environmental events, thus extending the theory of punctuated equilibrium to the prebiotic realm. Applying our arguments to other potentially life-bearing planetary platforms, we predict that a statistically representative sampling will be racemic on average. PMID:18841492

  8. Prebiotic chirality

    NASA Astrophysics Data System (ADS)

    Mekki-Berrada, Ali

    Bringing closer phospholipids each other on a bilayer of liposome, causes their rotation around their fatty acids axis, generating a force which brings closer the two sheets of the bilayer. In this theoretical study I show that for getting the greater cohesion of the liposome, by these forces, the serine in the hydrophilic head must have a L chirality. In the case where the hydrophilic head is absent amino acids with L chirality could contribute to this cohesion by taking the place of L-serine. Some coenzymes having a configuration similar to ethanolamine may also contribute. This is the case of pyridoxamine, thiamine and tetrahydrofolic acid. The grouping of amino acids of L chirality and pyridoxamine on the wall could initialize the prebiotic metabolism of these L amino acids only. This would explain the origin of the homo-chirality of amino acids in living world. Furthermore I show that in the hydrophilic head, the esterification of glycerol-phosphate by two fatty acids go through the positioning of dihydroxyacetone-phosphate and L-glyceraldehyde-3-phosphate, but not of D-glyceraldehyde-3-phosphate, prior their hydrogenation to glycerol-3- phosphate. The accumulation of D-glyceraldehyde-3-phosphate in the cytoplasm displace the thermodynamic equilibria towards the synthesis of D-dATP from D-glyceraldehyde-3-phosphate, acetaldehyde and prebiotic adenine, a reaction which does not require a coenzyme in the biotic metabolism. D-dATP and thiamine, more prebiotic metabolism of L-amino acids on the wall, would initialize D-pentoses phosphate and D-nucleotides pathways from the reaction of D-glyceraldehyde-3-phosphate + dihydroxyacetone-phosphate + prebiotic nucleic bases. The exhaustion of the prebiotic glyceraldehyde (racemic) and the nascent biotic metabolism dominated by D-glyceraldehyde-3-phosphate, would explain the origin of homo-chirality of sugars in living world. References: http://en.wikiversity.org/wiki/Prebiotic_chirality

  9. Chiral pattern formation in compact microbial colonies

    NASA Astrophysics Data System (ADS)

    Korolev, Kirill; Bino George, Ashish

    Chirality is ubiquitous in biology from single molecules to entire populations. Yet, we are still lacking a detailed understanding of how chiral patterns emerge from cell competition and growth, even in simple microbial colonies. Although many microbes grow as dense colonies with no apparent chirality, recent experiments with Escherichia coli have demonstrated that internal dynamics in such populations can be in fact chiral. We show that there is a unique way to extend the commonly-used reaction-diffusion models of colony growth to account for the emergent chirality. This new model connects microscopic and macroscopic chirality and explains the origin of logarithmic spirals separating different sub-populations in a colony. We also show that chirality is substantially enhanced by the cooperation among the cells at the expansion frontier. In heterogeneous populations composed of strains with different chiralities and growth rates, our model predicts a very rich set of possible dynamics. For example, different chiralities can result in either sharp boundaries between the strains or promote their intermixing depending on the preferred twisting directions of the strains.

  10. Two-color QCD with chiral chemical potential

    NASA Astrophysics Data System (ADS)

    Braguta, V. V.; Goy, V. A.; Ilgenfritz, E.-M.; Kotov, A. Yu.; Molochkov, A. V.; Müller-Preussker, M.; Petersson, B.; Schreiber, A.

    2016-01-01

    The phase diagram of two-color QCD with a chiral chemical potential is studied on the lattice. The focus is on the confinement/deconfinement phase transition and the breaking/restoration of chiral symmetry. The simulations are carried out with dynamical staggered fermions without rooting. The dependence of the Polyakov loop, the chiral condensate and the corresponding susceptibilities on the chiral chemical potential and the temperature are presented.

  11. Dynamic NMR and Quantum-Chemical Study of the Stereochemistry and Stability of the Chiral MoO2(acac)2 Complex in Solution.

    PubMed

    Conte, Marco; Hippler, Michael

    2016-09-01

    The stereochemistry and dynamics of MoO2(acac)2 in benzene, chloroform, and toluene were investigated by variable temperature (1)H NMR, density functional theory (SOGGA11-X, B3LYP), and ab initio (MP2) methods. In solution, an equilibrium between two chiral enantiomers with C2 symmetry was identified, Λ-cis-MoO2(acac)2 and Δ-cis-MoO2(acac)2. The two enantiomers are connected via achiral cis transition states that switch the enantiomeric conformations via a Ray-Dutt, Bailar, and a newly described racemization twisting mechanism. All three mechanisms have similar calculated activation energies. Activation parameters Ea, ΔH(‡), and ΔS(‡) were experimentally determined for the exchange process, with a small, negative ΔS(‡), and a positive ΔH(‡) of 68.1 kJ mol(-1) in benzene, 54.9 kJ mol(-1) in chloroform, and 60.6 kJ mol(-1) in toluene, in reasonable general agreement with the calculations. Trans configurations of MoO2(acac)2 are very much higher in energy than cis and are not relevant in the temperature range experimentally studied, 243-340 K. The enantiomers interconvert within seconds near room temperature and much faster at elevated temperatures. Racemization will thus prevent the use of enantiomerically pure MoO2(acac)2 for chiral catalysis under practical conditions. PMID:27510306

  12. H2 adsorption on Ag-nanocluster/single-walled carbon nanotube composites: a molecular dynamics study on the effects of nanocluster size, diameter, and chirality of nanotube.

    PubMed

    Akbarzadeh, Hamed; Shamkhali, Amir Nasser

    2015-03-15

    The H2 physisorption on AgN (with N = 32, 108, 256, 500, and 864)/carbon nanotube (CNT; in armchair and zigzag structures with diameters between 0.54 and 2.98 nm) composites were studied by molecular dynamic simulation to investigate the effect of nanocluster size, diameter, and chirality of nanotube on the adsorption phenomena. The calculations indicate that the effects of nanocluster properties are more important than those of the nanotube, in such a way that increase of nanocluster size, decreases the H2 adsorption. Also, the diameter and chirality of CNTs have considerable influence on the adsorption phenomena. As the diameter of nanotube is increased, the amount of adsorption is decreased. Moreover, H2 molecules have more tendencies to those nanoclusters located on the armchair nanotubes than the zigzag ones. Another important result is the reversibility of H2 adsorption on these materials in which the structure of composite in vacuum and after reduction of H2 pressure to zero, is not changed, considerably. PMID:25583625

  13. New chiral zinc complexes: synthesis, structure, and induction of axial chirality.

    PubMed

    Degenbeck, Helmut; Felten, Anne-Sophie; Escudero-Adán, Eduardo C; Benet-Buchholz, Jordi; Di Bari, Lorenzo; Pescitelli, Gennaro; Vidal-Ferran, Anton

    2012-08-20

    We describe an efficient methodology for the preparation of new chiral zinc complexes by assembling dynamically racemic biphenol derivatives and chiral 1,2-diamines with suitable zinc(II) precursors. Mononuclear and dinuclear zinc(II) complexes were formed from differently substituted biphenols. The solid-state and solution structural characterization of the resulting compounds allowed us to demonstrate a preferential sense of induced axial chirality for mononuclear complexes, a phenomenon that was not observed for the dinuclear ones. PMID:22862880

  14. Hydrogen-Regulated Chiral Nanoplasmonics.

    PubMed

    Duan, Xiaoyang; Kamin, Simon; Sterl, Florian; Giessen, Harald; Liu, Na

    2016-02-10

    Chirality is a highly important topic in modern chemistry, given the dramatically different pharmacological effects that enantiomers can have on the body. Chirality of natural molecules can be controlled by reconfiguration of molecular structures through external stimuli. Despite the rapid progress in plasmonics, active regulation of plasmonic chirality, particularly in the visible spectral range, still faces significant challenges. In this Letter, we demonstrate a new class of hybrid plasmonic metamolecules composed of magnesium and gold nanoparticles. The plasmonic chirality from such plasmonic metamolecules can be dynamically controlled by hydrogen in real time without introducing macroscopic structural reconfiguration. We experimentally investigate the switching dynamics of the hydrogen-regulated chiroptical response in the visible spectral range using circular dichroism spectroscopy. In addition, energy dispersive X-ray spectroscopy is used to examine the morphology changes of the magnesium particles through hydrogenation and dehydrogenation processes. Our study can enable plasmonic chiral platforms for a variety of gas detection schemes by exploiting the high sensitivity of circular dichroism spectroscopy. PMID:26745446

  15. Chiral Magnetic Effect in Hydrodynamic Approximation

    NASA Astrophysics Data System (ADS)

    Zakharov, Valentin I.

    We review derivations of the chiral magnetic effect (ChME) in hydrodynamic approximation. The reader is assumed to be familiar with the basics of the effect. The main challenge now is to account for the strong interactions between the constituents of the fluid. The main result is that the ChME is not renormalized: in the hydrodynamic approximation it remains the same as for non-interacting chiral fermions moving in an external magnetic field. The key ingredients in the proof are general laws of thermodynamics and the Adler-Bardeen theorem for the chiral anomaly in external electromagnetic fields. The chiral magnetic effect in hydrodynamics represents a macroscopic manifestation of a quantum phenomenon (chiral anomaly). Moreover, one can argue that the current induced by the magnetic field is dissipation free and talk about a kind of "chiral superconductivity". More precise description is a quantum ballistic transport along magnetic field taking place in equilibrium and in absence of a driving force. The basic limitation is the exact chiral limit while temperature—excitingly enough—does not seemingly matter. What is still lacking, is a detailed quantum microscopic picture for the ChME in hydrodynamics. Probably, the chiral currents propagate through lower-dimensional defects, like vortices in superfluid. In case of superfluid, the prediction for the chiral magnetic effect remains unmodified although the emerging dynamical picture differs from the standard one.

  16. Vector meson spectral function and dilepton rate in the presence of strong entanglement effect between the chiral and the Polyakov loop dynamics

    NASA Astrophysics Data System (ADS)

    Islam, Chowdhury Aminul; Majumder, Sarbani; Mustafa, Munshi G.

    2015-11-01

    In this work we have reexplored our earlier study on the vector meson spectral function and its spectral property in the form of dilepton rate in a two-flavor Polyakov loop extended Nambu-Jona-Lasinio (PNJL) model in the presence of a strong entanglement between the chiral and Polyakov loop dynamics. The entanglement considered here is generated through the four-quark scalar-type interaction in which the coupling strength depends on the Polyakov loop and runs with temperature and chemical potential. The entanglement effect is also considered for the four-quark vector-type interaction in the same manner. We observe that the entanglement effect relatively enhances the color degrees of freedom due to the running of both the scalar and vector couplings. This modifies the vector meson spectral function and, thus, the spectral property such as the dilepton production rate in the low invariant mass also gets modified.

  17. Chiral symmetry in rotating systems

    NASA Astrophysics Data System (ADS)

    Malik, Sham S.

    2015-08-01

    The triaxial rotating system at critical angular momentum I ≥Iband exhibits two enatiomeric (the left- and right-handed) forms. These enatiomers are related to each other through dynamical chiral symmetry. The chiral symmetry in rotating system is defined by an operator χ ˆ =Rˆy (π) T ˆ, which involves the product of two distinct symmetries, namely, continuous and discrete. Therefore, new guidelines are required for testing its commutation with the system Hamiltonian. One of the primary objectives of this study is to lay down these guidelines. Further, the possible impact of chiral symmetry on the geometrical arrangement of angular momentum vectors and investigation of observables unique to nuclear chiral-twins is carried out. In our model, the angular momentum components (J1, J2, J3) occupy three mutually perpendicular axes of triaxial shape and represent a non-planar configuration. At certain threshold energy, the equation of motion in angular momentum develops a second order phase transition and as a result two distinct frames (i.e., the left- and right-handed) are formed. These left- and right-handed states correspond to a double well system and are related to each other through chiral operator. At this critical angular momentum, the centrifugal and Coriolis interactions lower the barrier in the double well system. The tunneling through the double well starts, which subsequently lifts the degeneracy among the rotational states. A detailed analysis of the behavior of rotational energies, spin-staggering, and the electromagnetic transition probabilities of the resulting twin-rotational bands is presented. The ensuing model results exhibit similarities with many observed features of the chiral-twins. An advantage of our formalism is that it is quite simple and it allows us to pinpoint the understanding of physical phenomenon which lead to chiral-twins in rotating systems.

  18. Chiral mirrors

    SciTech Connect

    Plum, Eric; Zheludev, Nikolay I.

    2015-06-01

    Mirrors are used in telescopes, microscopes, photo cameras, lasers, satellite dishes, and everywhere else, where redirection of electromagnetic radiation is required making them arguably the most important optical component. While conventional isotropic mirrors will reflect linear polarizations without change, the handedness of circularly polarized waves is reversed upon reflection. Here, we demonstrate a type of mirror reflecting one circular polarization without changing its handedness, while absorbing the other. The polarization-preserving mirror consists of a planar metasurface with a subwavelength pattern that cannot be superimposed with its mirror image without being lifted out of its plane, and a conventional mirror spaced by a fraction of the wavelength from the metasurface. Such mirrors enable circularly polarized lasers and Fabry-Pérot cavities with enhanced tunability, gyroscopic applications, polarization-sensitive detectors of electromagnetic waves, and can be used to enhance spectroscopies of chiral media.

  19. Influence of Chirality of Crizotinib on Its MTH1 Protein Inhibitory Activity: Insight from Molecular Dynamics Simulations and Binding Free Energy Calculations

    PubMed Central

    Niu, Yuzhen; Pan, Dabo; Shi, Danfeng; Bai, Qifeng; Liu, Huanxiang; Yao, Xiaojun

    2015-01-01

    As a promising target for the treatment of lung cancer, the MutT Homolog 1 (MTH1) protein can be inhibited by crizotinib. A recent work shows that the inhibitory potency of (S)-crizotinib against MTH1 is about 20 times over that of (R)-crizotinib. But the detailed molecular mechanism remains unclear. In this study, molecular dynamics (MD) simulations and free energy calculations were used to elucidate the mechanism about the effect of chirality of crizotinib on the inhibitory activity against MTH1. The binding free energy of (S)-crizotinib predicted by the Molecular Mechanics/Generalized Born Surface Area (MM/GBSA) and Adaptive biasing force (ABF) methodologies is much lower than that of (R)-crizotinib, which is consistent with the experimental data. The analysis of the individual energy terms suggests that the van der Waals interactions are important for distinguishing the binding of (S)-crizotinib and (R)-crizotinib. The binding free energy decomposition analysis illustrated that residues Tyr7, Phe27, Phe72 and Trp117 were important for the selective binding of (S)-crizotinib to MTH1. The adaptive biasing force (ABF) method was further employed to elucidate the unbinding process of (S)-crizotinib and (R)-crizotinib from the binding pocket of MTH1. ABF simulation results suggest that the reaction coordinates of the (S)-crizotinib from the binding pocket is different from (R)-crizotinib. The results from our study can reveal the details about the effect of chirality on the inhibition activity of crizotinib to MTH1 and provide valuable information for the design of more potent inhibitors. PMID:26677850

  20. Chiral THz metamaterial with tunable optical activity

    SciTech Connect

    Zhou, Jiangfeng; Taylor, Antoinette; O' Hara, John; Chowdhury, Roy; Zhao, Rongkuo; Soukoullis, Costas M

    2010-01-01

    Optical activity in chiral metamaterials is demonstrated in simulation and shows actively tunable giant polarization rotation at THz frequencies. Electric current distributions show that pure chirality is achieved by our bi-Iayer chiral metamaterial design. The chirality can be optically controlled by illumination with near-infrared light. Optical activity, occurring in chiral materials such as DNA, sugar and many other bio-molecules, is a phenomenon of great importance to many areas of science including molecular biology, analytical chemistry, optoelectronics and display applications. This phenomenon is well understood at an effective medium level as a magnetic/electric moment excited by the electric/magnetic field of the incident electromagnetic (EM) wave. Usually, natural chiral materials exhibit very weak optical activity e.g. a gyrotropic quartz crystal. The optical activity of chiral metamaterials, however, can be five orders of magnitude stronger. Chiral metamaterials are made of sub-wavelength resonators lacking symmetry planes. The asymmetry allows magnetic moments to be excited by the electric field of the incident EM wave and vice versa. Recently, chiral metamaterials have been demonstrated and lead to prospects in giant optical activity, circular dichroism, negative refraction and reversing the Casmir force. These fascinating optical properties require strong chirality, which may be designed through the microscopic structure of chiral metamaterials. However, these metamaterials have a fixed response function, defined by the geometric structuring, which limits their ability to manipulate EM waves. Active metamaterials realize dynamic control of response functions and have produced many influential applications such as ultra-fast switching devices, frequency and phase modulation and memory devices. Introducing active designs to chiral metamaterials will give additional freedom in controlling the optical activity, and therefore enable dynamic manipulation

  1. Chiral effective field theory analysis of hadronic parity violation in few-nucleon systems

    SciTech Connect

    Viviani, Michele; Baroni, Alessandro; Girlanda, Luca; Kievsky, Alejandro; Marcucci, Laura E.; Schiavilla, Rocco

    2014-06-01

    Background: Weak interactions between quarks induce a parity-violating (PV) component in the nucleonnucleon potential, whose effects are currently being studied in a number of experiments involving few-nucleon systems. In the present work, we reconsider the derivation of this PV component within a chiral effective field theory (chiEFT) framework. Purpose: The objectives of the present work are twofold. The first is to perform a detailed analysis of the PV nucleon-nucleon potential up to next-to-next-to-leading (N2LO) order in the chiral expansion, in particular, by determining the number of independent low-energy constants (LECs) at N2LO. The second objective is to investigate PV effects in a number of few-nucleon observables, including the p-p longitudinal asymmetry, the neutron spin rotation in n-p and n-d scattering, and the longitudinal asymmetry in the {sup 3}He( {vector n},p){sup 3}H chargeexchange reaction. Methods: The chiEFT PV potential includes one-pion-exchange, two-pion-exchange, and contact terms as well as 1/M (M being the nucleon mass) nonstatic corrections. Dimensional regularization is used to renormalize pion loops. The wave functions for the A = 2–-4 nuclei are obtained by using strong two- and three-body potentials also derived, for consistency, from chiEFT. In the case of the A = 3–-4 systems, the wave functions are computed by expanding on a hyperspherical harmonics functions basis. Results: We find that the PV potential at N2LO depends on six LECs: the pion-nucleon PV coupling constant h^1_pi and five parameters multiplying contact interactions. An estimate for the range of values of the various LECs is provided by using available experimental data, and these values are used to obtain predictions for the other PV observables. Conclusions: The chiEFT approach provides a very satisfactory framework to analyze PV effects in few-nucleon systems.

  2. Chirality of Viral Capsids

    NASA Astrophysics Data System (ADS)

    Dharmavaram, Sanjay; Xie, Fangming; Bruinsma, Robijn; Klug, William; Rudnick, Joseph

    Most icosahedral viruses are classified by their T-number which identifies their capsid in terms of the number of capsomers and their relative arrangement. Certain T-numbers (T = 7 for instance) are inherently chiral (with no reflection planes) while others (e.g. T = 1) are achiral. We present a Landau-Brazovskii (LB) theory for weak crystallization in which a scalar order parameter that measures density of capsid proteins successfully predicts the various observed T-numbers and their respective chiralities. We find that chiral capsids gain stability by spontaneously breaking symmetry from an unstable chiral state. The inherently achiral LB-free energy does not preferentially select a particular chiral state from its mirror reflection. Based on the physical observation that proteins are inherently chiral molecules with directional interactions, we propose a new chiral term to the LB energy as a possible selection mechanism for chirality.

  3. Unified description of 6Li structure and deuterium-4He dynamics with chiral two- and three-nucleon forces

    DOE PAGESBeta

    Hupin, Guillaume; Quaglioni, Sofia; Navratil, Petr

    2015-05-29

    Here, we provide a unified ab initio description of the 6Li ground state and elastic scattering of deuterium (d) on 4He (α) using two- and three-nucleon forces from chiral effective field theory. We analyze the influence of the three-nucleon force and reveal the role of continuum degrees of freedom in shaping the low-lying spectrum of 6Li. The calculation reproduces the empirical binding energy of 6Li, yielding an asymptotic D- to S-state ratio of the 6Li wave function in the d+α configuration of –0.027, in agreement with a determination from 6Li–4He elastic scattering, but overestimates the excitation energy of the 3+more » state by 350 keV. The bulk of the computed differential cross section is in good agreement with data. These results endorse the application of the present approach to the evaluation of the 2H(α,γ)6Li radiative capture, responsible for the big-bang nucleosynthesis of 6Li.« less

  4. Unified description of ^{6}Li structure and deuterium-^{4}He dynamics with chiral two- and three-nucleon forces.

    PubMed

    Hupin, Guillaume; Quaglioni, Sofia; Navrátil, Petr

    2015-05-29

    We provide a unified ab initio description of the ^{6}Li ground state and elastic scattering of deuterium (d) on ^{4}He (α) using two- and three-nucleon forces from chiral effective field theory. We analyze the influence of the three-nucleon force and reveal the role of continuum degrees of freedom in shaping the low-lying spectrum of ^{6}Li. The calculation reproduces the empirical binding energy of ^{6}Li, yielding an asymptotic D- to S-state ratio of the ^{6}Li wave function in the d+α configuration of -0.027, in agreement with a determination from ^{6}Li-^{4}He elastic scattering, but overestimates the excitation energy of the 3^{+} state by 350 keV. The bulk of the computed differential cross section is in good agreement with data. These results endorse the application of the present approach to the evaluation of the ^{2}H(α,γ)^{6}Li radiative capture, responsible for the big-bang nucleosynthesis of ^{6}Li. PMID:26066431

  5. Introduction to chiral symmetry

    SciTech Connect

    Koch, V.

    1996-01-08

    These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. Effective chiral models such as the linear and nonlinear sigma model will be discussed as well as the essential ideas of chiral perturbation theory. Some applications to the physics of ultrarelativistic heavy ion collisions will be presented.

  6. Intelligent Chiral Sensing Based on Supramolecular and Interfacial Concepts

    PubMed Central

    Ariga, Katsuhiko; Richards, Gary J.; Ishihara, Shinsuke; Izawa, Hironori; Hill, Jonathan P.

    2010-01-01

    Of the known intelligently-operating systems, the majority can undoubtedly be classed as being of biological origin. One of the notable differences between biological and artificial systems is the important fact that biological materials consist mostly of chiral molecules. While most biochemical processes routinely discriminate chiral molecules, differentiation between chiral molecules in artificial systems is currently one of the challenging subjects in the field of molecular recognition. Therefore, one of the important challenges for intelligent man-made sensors is to prepare a sensing system that can discriminate chiral molecules. Because intermolecular interactions and detection at surfaces are respectively parts of supramolecular chemistry and interfacial science, chiral sensing based on supramolecular and interfacial concepts is a significant topic. In this review, we briefly summarize recent advances in these fields, including supramolecular hosts for color detection on chiral sensing, indicator-displacement assays, kinetic resolution in supramolecular reactions with analyses by mass spectrometry, use of chiral shape-defined polymers, such as dynamic helical polymers, molecular imprinting, thin films on surfaces of devices such as QCM, functional electrodes, FET, and SPR, the combined technique of magnetic resonance imaging and immunoassay, and chiral detection using scanning tunneling microscopy and cantilever technology. In addition, we will discuss novel concepts in recent research including the use of achiral reagents for chiral sensing with NMR, and mechanical control of chiral sensing. The importance of integration of chiral sensing systems with rapidly developing nanotechnology and nanomaterials is also emphasized. PMID:22163577

  7. Isospin Breaking in the Goldberger-Treiman Discrepancies

    SciTech Connect

    Jose Goity; Jordi Saez

    2002-09-01

    Effects of isospin breaking at the level of the Goldberger-Treiman discrepancies involving the neutral isotriplet axial and pion-nucleon couplings are analyzed to leading non-trivial order in chiral perturbation theory.

  8. Generation of chiral spin state by quantum simulation

    NASA Astrophysics Data System (ADS)

    Tanamoto, Tetsufumi

    2016-06-01

    Chirality of materials in nature appears when there are asymmetries in their lattice structures or interactions in a certain environment. Recent development of quantum simulation technology has enabled the manipulation of qubits. Accordingly, chirality can be realized intentionally rather than passively observed. Here we theoretically provide simple methods to create a chiral spin state in a spin-1/2 qubit system on a square lattice. First, we show that switching on and off the Heisenberg and X Y interactions produces the chiral interaction directly in the effective Hamiltonian without controlling local fields. Moreover, when initial states of spin qubits are appropriately prepared, we prove that the chirality with desirable phase is dynamically obtained. Finally, even for the case where switching on and off the interactions is infeasible and the interactions are always on, we show that, by preparing an asymmetric initial qubit state, the chirality whose phase is π /2 is dynamically generated.

  9. Broken chiral symmetry on a null plane

    SciTech Connect

    Beane, Silas R.

    2013-10-15

    On a null-plane (light-front), all effects of spontaneous chiral symmetry breaking are contained in the three Hamiltonians (dynamical Poincaré generators), while the vacuum state is a chiral invariant. This property is used to give a general proof of Goldstone’s theorem on a null-plane. Focusing on null-plane QCD with N degenerate flavors of light quarks, the chiral-symmetry breaking Hamiltonians are obtained, and the role of vacuum condensates is clarified. In particular, the null-plane Gell-Mann–Oakes–Renner formula is derived, and a general prescription is given for mapping all chiral-symmetry breaking QCD condensates to chiral-symmetry conserving null-plane QCD condensates. The utility of the null-plane description lies in the operator algebra that mixes the null-plane Hamiltonians and the chiral symmetry charges. It is demonstrated that in a certain non-trivial limit, the null-plane operator algebra reduces to the symmetry group SU(2N) of the constituent quark model. -- Highlights: •A proof (the first) of Goldstone’s theorem on a null-plane is given. •The puzzle of chiral-symmetry breaking condensates on a null-plane is solved. •The emergence of spin-flavor symmetries in null-plane QCD is demonstrated.

  10. Chirality in nonlinear optics.

    PubMed

    Haupert, Levi M; Simpson, Garth J

    2009-01-01

    The past decade has witnessed the emergence of new measurement approaches and applications for chiral thin films and materials enabled by the observations of the high sensitivity of second-order nonlinear optical measurements to chirality. In thin films, the chiral response to second harmonic generation and sum frequency generation (SFG) from a single molecular monolayer is often comparable with the achiral response. The chiral specificity also allows for symmetry-allowed SFG in isotropic chiral media, confirming predictions made approximately 50 years ago. With these experimental demonstrations in hand, an important challenge is the construction of intuitive predictive models that allow the measured chiral response to be meaningfully related back to molecular and macromolecular structure. This review defines and considers three distinct mechanisms for chiral effects in uniaxially oriented assemblies: orientational chirality, intrinsic chirality, and isotropic chirality. The role of each is discussed in experimental and computational studies of bacteriorhodopsin films, binaphthol, and collagen. Collectively, these three model systems support a remarkably simple framework for quantitatively recovering the measured chiral-specific activity. PMID:19046125

  11. Chirality in Nonlinear Optics

    NASA Astrophysics Data System (ADS)

    Haupert, Levi M.; Simpson, Garth J.

    2009-05-01

    The past decade has witnessed the emergence of new measurement approaches and applications for chiral thin films and materials enabled by the observations of the high sensitivity of second-order nonlinear optical measurements to chirality. In thin films, the chiral response to second harmonic generation and sum frequency generation (SFG) from a single molecular monolayer is often comparable with the achiral response. The chiral specificity also allows for symmetry-allowed SFG in isotropic chiral media, confirming predictions made ˜50 years ago. With these experimental demonstrations in hand, an important challenge is the construction of intuitive predictive models that allow the measured chiral response to be meaningfully related back to molecular and macromolecular structure. This review defines and considers three distinct mechanisms for chiral effects in uniaxially oriented assemblies: orientational chirality, intrinsic chirality, and isotropic chirality. The role of each is discussed in experimental and computational studies of bacteriorhodopsin films, binaphthol, and collagen. Collectively, these three model systems support a remarkably simple framework for quantitatively recovering the measured chiral-specific activity.

  12. Difference in the dynamic properties of chiral and racemic crystals of serine studied by Raman spectroscopy at 3-295 K.

    PubMed

    Kolesov, B A; Boldyreva, E V

    2007-12-27

    Single-crystal polarized Raman spectra (60-4000 cm(-1) at 3 < or = T < or = 295 K) were measured for chiral L- and racemic DL-serine, alpha-amino-beta-hydroxypropionic acid, (NH3)+CH(CH2OH)(COO)-. The Raman spectra of dl-serine do not show any striking changes with temperature or on storage. In contrast to that, the dynamical properties of L-serine change at about 140 K. These changes can be interpreted as the reorientation of the side chain -CH2OH fragments of the zwitterions with respect to the backbone C-C bonds, resulting in the positional disorder of the O-H...O intermolecular H-bonds. The redistribution in the intensities of the Raman spectra of the crystals of L-serine stored for a long time (about a year) indicates the changes in the orientation of the molecular fragments in the direction normal to the axes of the head-to-tail chains. The difference in the thermodynamic functions of L- and DL-serine reported previously [Drebushchak, V. A.; Kovalevskaya, Yu. A.; Paukov, I. E.; Boldyreva, E. V. J. Therm. Anal. Calorim. 2007, 89 (2), 649-654] is explained by the difference in the spectra of external vibrations of the crystals. PMID:18052147

  13. Staggered heavy baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Bailey, Jon A.

    2008-03-01

    Although taste violations significantly affect the results of staggered calculations of pseudoscalar and heavy-light mesonic quantities, those entering staggered calculations of baryonic quantities have not been quantified. Here I develop staggered chiral perturbation theory in the light-quark baryon sector by mapping the Symanzik action into heavy baryon chiral perturbation theory. For 2+1 dynamical quark flavors, the masses of flavor-symmetric nucleons are calculated to third order in partially quenched and fully dynamical staggered chiral perturbation theory. To this order the expansion includes the leading chiral logarithms, which come from loops with virtual decuplet-like states, as well as terms of O(mπ3), which come from loops with virtual octet-like states. Taste violations enter through the meson propagators in loops and tree-level terms of O(a2). The pattern of taste symmetry breaking and the resulting degeneracies and mixings are discussed in detail. The resulting chiral forms are appropriate to lattice results obtained with operators already in use and could be used to study the restoration of taste symmetry in the continuum limit. I assume that the fourth root of the fermion determinant can be incorporated in staggered chiral perturbation theory using the replica method.

  14. Two-color QCD with non-zero chiral chemical potential

    NASA Astrophysics Data System (ADS)

    Braguta, V. V.; Goy, V. A.; Ilgenfritz, E. M.; Kotov, A. Yu.; Molochkov, A. V.; Müller-Preussker, M.; Petersson, B.

    2015-06-01

    The phase diagram of two-color QCD with non-zero chiral chemical potential is studied by means of lattice simulation. We focus on the influence of a chiral chemical potential on the confinement/deconfinement phase transition and the breaking/restoration of chiral symmetry. The simulation is carried out with dynamical staggered fermions without rooting. The dependences of the Polyakov loop, the chiral condensate and the corresponding susceptibilities on the chiral chemical potential and the temperature are presented. The critical temperature is observed to increase with increasing chiral chemical potential.

  15. Significant Enhancement of the Chiral Correlation Length in Nematic Liquid Crystals by Gold Nanoparticle Surfaces Featuring Axially Chiral Binaphthyl Ligands.

    PubMed

    Mori, Taizo; Sharma, Anshul; Hegmann, Torsten

    2016-01-26

    Chirality is a fundamental scientific concept best described by the absence of mirror symmetry and the inability to superimpose an object onto its mirror image by translation and rotation. Chirality is expressed at almost all molecular levels, from single molecules to supramolecular systems, and present virtually everywhere in nature. Here, to explore how chirality propagates from a chiral nanoscale surface, we study gold nanoparticles functionalized with axially chiral binaphthyl molecules. In particular, we synthesized three enantiomeric pairs of chiral ligand-capped gold nanoparticles differing in size, curvature, and ligand density to tune the chirality transfer from nanoscale solid surfaces to a bulk anisotropic liquid crystal medium. Ultimately, we are examining how far the chirality from a nanoparticle surface reaches into a bulk material. Circular dichroism spectra of the gold nanoparticles decorated with binaphthyl thiols confirmed that the binaphthyl moieties form a cisoid conformation in isotropic organic solvents. In the chiral nematic liquid crystal phase, induced by dispersing the gold nanoparticles into an achiral anisotropic nematic liquid crystal solvent, the binaphthyl moieties on the nanoparticle surface form a transoid conformation as determined by imaging the helical twist direction of the induced cholesteric phase. This suggests that the ligand density on the nanoscale metal surfaces provides a dynamic space to alter and adjust the helicity of binaphthyl derivatives in response to the ordering of the surrounding medium. The helical pitch values of the induced chiral nematic phase were determined, and the helical twisting power (HTP) of the chiral gold nanoparticles calculated to elucidate the chirality transfer efficiency of the binaphthyl ligand capped gold nanoparticles. Remarkably, the HTP increases with increasing diameter of the particles, that is, the efficiency of the chirality transfer of the binaphthyl units bound to the nanoparticle

  16. Pion scattering and nuclear dynamics

    SciTech Connect

    Johnson, M.B.

    1988-01-01

    A phenomenological optical-model analysis of pion elastic scattering and single- and double-charge-exchange scattering to isobaric-analog states is reviewed. Interpretation of the optical-model parameters is briefly discussed, and several applications and extensions are considered. The applications include the study of various nuclear properties, including neutron deformation and surface-fluctuation contributions to the density. One promising extension for the near future would be to develop a microscopic approach based on powerful momentum-space methods brought to existence over the last decade. In this, the lowest-order optical potential as well as specific higher-order pieces would be worked out in terms of microscopic pion-nucleon and delta-nucleon interactions that can be determined within modern meson-theoretical frameworks. A second extension, of a more phenomenological nature, would use coupled-channel methods and shell-model wave functions to study dynamical nuclear correlations in pion double charge exchange. 35 refs., 11 figs., 1 tab.

  17. On consistency of hydrodynamic approximation for chiral media

    NASA Astrophysics Data System (ADS)

    Avdoshkin, A.; Kirilin, V. P.; Sadofyev, A. V.; Zakharov, V. I.

    2016-04-01

    We consider chiral liquids, that is liquids consisting of massless fermions and right-left asymmetric. In such media, one expects existence of electromagnetic current flowing along an external magnetic field, associated with the chiral anomaly. The current is predicted to be dissipation-free. We consider dynamics of chiral liquids, concentrating on the issues of possible instabilities and infrared sensitivity. Instabilities arise, generally speaking, already in the limit of vanishing electromagnetic constant, αel → 0. In particular, liquids with non-vanishing chiral chemical potential might decay into right-left asymmetric states containing vortices.

  18. Spontaneous 1 chiral symmetry breaking in model bacterial suspensions

    NASA Astrophysics Data System (ADS)

    Breier, Rebekka; Selinger, Robin; Ciccotti, Giovanni; Herminghaus, Stephan; Mazza, Marco G.

    2015-03-01

    Chiral symmetry breaking is ubiquitous in biological systems, from DNA to bacterial suspensions. A key unresolved problem is how chiral structures may spontaneously emerge from achiral interactions. We study a simple model of bacterial suspensions in three dimensions that effectively incorporates active motion and hydrodynamic interactions. We perform large-scale molecular dynamics simulations (up to 106 particles) and describe stable (or long-lived metastable) collective states that exhibit chiral organization although the interactions are achiral. We elucidate under which conditions these chiral states will emerge and grow to large scales. We also study a related equilibrium model that clarifies the role of orientational fluctuations.

  19. Architecture of Chiral Poly(phenylacetylene)s: From Compressed/Highly Dynamic to Stretched/Quasi-Static Helices.

    PubMed

    Rodríguez, Rafael; Quiñoá, Emilio; Riguera, Ricardo; Freire, Félix

    2016-08-01

    The remarkable consequences in elongation, dynamic character, response to external stimuli (e.g., solvent effects, metal cations), and aggregation observed in helical poly(phenylacetylene)s (PPAs) when either the type of linkage with the pendant groups (i.e., anilide, benzamide) or the aromatic substitution pattern (i.e., ortho, meta, para) of the parent phenylacetylene monomer undergo modification are analyzed in depth. Two series of PPAs substituted at the phenyl ring in ortho, meta, and para with either (S)-α-methoxy-α-phenylacetic acid (MPA) or (S)-phenylglycine methyl ester (PGME) linked through anilide or benzamide bonds were prepared (i.e., o-, m-, p-poly-1 and poly-2 series) and characterized both in solution and in the solid state (CD, UV-vis, Raman, NMR, DSC, TGA, X-ray, AFM, SEM). Para-substituted polymers (p-poly-1 and p-poly-2) present the most compressed and dynamic helices, which respond easily to external stimuli. Meta-substituted PPAs (m-poly-1 and m-poly-2) exist as a mixture in equilibrium of two different helices (compressed and stretched), both less dynamic than the para counterparts and with a weak response to external stimuli. Moreover, in the solid state, m-poly-1 and m-poly-2 show separate fields for the compressed and for the stretched helices. For its part, the ortho-substituted PPA (o-poly-1) presents a highly stretched, almost planar and practically rigid helical structure, inert to external stimuli and prone to aggregate. These structural changes (elongation/dynamic behavior) are rationalized on the basis of the increasing difficulties imposed by the meta- and ortho-substitution on the accommodation of the pendants within the helical structure. PMID:27419262

  20. Planar plasmonic chiral nanostructures.

    PubMed

    Zu, Shuai; Bao, Yanjun; Fang, Zheyu

    2016-02-21

    A strong chiral optical response induced at a plasmonic Fano resonance in a planar Au heptamer nanostructure was experimentally and theoretically demonstrated. The scattering spectra show the characteristic narrow-band feature of Fano resonances for both left and right circular polarized lights, with a chiral response reaching 30% at the Fano resonance. Specifically, we systematically investigate the chiral response of planar heptamers with gradually changing the inter-particle rotation angles and separation distance. The chiral spectral characteristics clearly depend on the strength of Fano resonances and the associated near-field optical distributions. Finite element method simulations together with a multipole expansion method demonstrate that the enhanced chirality is caused by the excitation of magnetic quadrupolar and electric toroidal dipolar modes. Our work provides an effective method for the design of 2D nanostructures with a strong chiral response. PMID:26818746

  1. Chiral solitons in a coupled double Peierls chain.

    PubMed

    Cheon, Sangmo; Kim, Tae-Hwan; Lee, Sung-Hoon; Yeom, Han Woong

    2015-10-01

    Chiral edge states are the hallmark of two- and three-dimensional topological materials, but their one-dimensional (1D) analog has not yet been found. We report that the 1D topological edge states, solitons, of the charge density wave system of indium atomic wires self-assembled on a silicon surface have chirality. The system is described by a coupled double Peierls-dimerized atomic chain, where the interchain coupling induces dynamical sublattice symmetry breaking. This changes its topological symmetry from Z₂× Z₂to Z₄ and endows solitons with a chiral degree of freedom. Chiral solitons can produce quantized charge transport across the chain that is topologically protected and controllable by the soliton's chirality. Individual right- and left-chiral solitons in indium wires are directly identified by scanning tunneling microscopy. PMID:26450206

  2. Detecting Chirality in Molecules by Linearly Polarized Laser Fields.

    PubMed

    Yachmenev, Andrey; Yurchenko, Sergei N

    2016-07-15

    A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal anisotropic contributions to the electric polarizability tensor for two enantiomers have different signs. Exploiting this property, we are able to excite a coherent unidirectional rotation of two enantiomers with a π phase difference in the molecular electric dipole moment. The approach is robust and suitable for relatively high temperatures of molecular samples, making it applicable for selective chiral analysis of mixtures, and to chiral molecules with low barriers between enantiomers. As an illustration, we present nanosecond laser-driven dynamics of a tetratomic nonrigid chiral molecule with short-lived chirality. The ultrafast time scale of the proposed technique is well suited to study parity violation in molecular systems in short-lived chiral states. PMID:27472111

  3. Chiral solitons in a coupled double Peierls chain

    NASA Astrophysics Data System (ADS)

    Cheon, Sangmo; Kim, Tae-Hwan; Lee, Sung-Hoon; Yeom, Han Woong

    2015-10-01

    Chiral edge states are the hallmark of two- and three-dimensional topological materials, but their one-dimensional (1D) analog has not yet been found. We report that the 1D topological edge states, solitons, of the charge density wave system of indium atomic wires self-assembled on a silicon surface have chirality. The system is described by a coupled double Peierls-dimerized atomic chain, where the interchain coupling induces dynamical sublattice symmetry breaking. This changes its topological symmetry from Z2×Z2 to Z4 and endows solitons with a chiral degree of freedom. Chiral solitons can produce quantized charge transport across the chain that is topologically protected and controllable by the soliton’s chirality. Individual right- and left-chiral solitons in indium wires are directly identified by scanning tunneling microscopy.

  4. Detecting Chirality in Molecules by Linearly Polarized Laser Fields

    NASA Astrophysics Data System (ADS)

    Yachmenev, Andrey; Yurchenko, Sergei N.

    2016-07-01

    A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal anisotropic contributions to the electric polarizability tensor for two enantiomers have different signs. Exploiting this property, we are able to excite a coherent unidirectional rotation of two enantiomers with a π phase difference in the molecular electric dipole moment. The approach is robust and suitable for relatively high temperatures of molecular samples, making it applicable for selective chiral analysis of mixtures, and to chiral molecules with low barriers between enantiomers. As an illustration, we present nanosecond laser-driven dynamics of a tetratomic nonrigid chiral molecule with short-lived chirality. The ultrafast time scale of the proposed technique is well suited to study parity violation in molecular systems in short-lived chiral states.

  5. Axially chiral BODIPYs.

    PubMed

    Lerrick, Reinner I; Winstanley, Thomas P L; Haggerty, Karen; Wills, Corinne; Clegg, William; Harrington, Ross W; Bultinck, Patrick; Herrebout, Wouter; Benniston, Andrew C; Hall, Michael J

    2014-05-11

    The synthesis and resolution of a class of chiral organic fluorophores, axially chiral 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes (Ax*-BODIPY), is described. Ax*-BODIPYs were prepared through a modular synthesis combined with a late stage Heck functionalisation. Resolution was achieved by preparative chiral HPLC. Absolute stereochemical assignment was performed by comparison of experimental ECD spectra with TD-DFT calculations. PMID:24676233

  6. Chiral atomically thin films

    NASA Astrophysics Data System (ADS)

    Kim, Cheol-Joo; Sánchez-Castillo, A.; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm–1) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra.

  7. Chiral atomically thin films.

    PubMed

    Kim, Cheol-Joo; Sánchez-Castillo, A; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm(-1)) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra. PMID:26900756

  8. Chiral geometry in multiple chiral doublet bands

    NASA Astrophysics Data System (ADS)

    Zhang, Hao; Chen, Qibo

    2016-02-01

    The chiral geometry of multiple chiral doublet bands with identical configuration is discussed for different triaxial deformation parameters γ in the particle rotor model with . The energy spectra, electromagnetic transition probabilities B(M1) and B(E2), angular momenta, and K-distributions are studied. It is demonstrated that the chirality still remains not only in the yrast and yrare bands, but also in the two higher excited bands when γ deviates from 30°. The chiral geometry relies significantly on γ, and the chiral geometry of the two higher excited partner bands is not as good as that of the yrast and yrare doublet bands. Supported by Plan Project of Beijing College Students’ Scientific Research and Entrepreneurial Action, Major State 973 Program of China (2013CB834400), National Natural Science Foundation of China (11175002, 11335002, 11375015, 11461141002), National Fund for Fostering Talents of Basic Science (NFFTBS) (J1103206), Research Fund for Doctoral Program of Higher Education (20110001110087) and China Postdoctoral Science Foundation (2015M580007)

  9. Baryon resonances without quarks: A chiral soliton perspective

    SciTech Connect

    Karliner, M.

    1987-03-01

    In many processes involving low momentum transfer it is fruitful to regard the nucleon as a soliton or ''monopole-like'' configuration of the pion field. In particular, within this framework it is possible to obtain detailed predictions for pion-nucleon scattering amplitudes and for properties of baryon resonances. One can also derive model-independent linear relations between scattering amplitudes, such as ..pi..N and anti KN. A short survey of some recent results is given, including comparison with experimental data.

  10. Chiral Drugs: An Overview

    PubMed Central

    Nguyen, Lien Ai; He, Hua; Pham-Huy, Chuong

    2006-01-01

    About more than half of the drugs currently in use are chiral compounds and near 90% of the last ones are marketed as racemates consisting of an equimolar mixture of two enantiomers. Although they have the same chemical structure, most isomers of chiral drugs exhibit marked differences in biological activities such as pharmacology, toxicology, pharmacokinetics, metabolism etc. Some mechanisms of these properties are also explained. Therefore, it is important to promote the chiral separation and analysis of racemic drugs in pharmaceutical industry as well as in clinic in order to eliminate the unwanted isomer from the preparation and to find an optimal treatment and a right therapeutic control for the patient. In this article, we review the nomenclature, pharmacology, toxicology, pharmacokinetics, metabolism etc of some usual chiral drugs as well as their mechanisms. Different techniques used for the chiral separation in pharmaceutical industry as well as in clinical analyses are also examined. PMID:23674971

  11. Spontaneous formation of organic helical architectures through dynamic covalent chemistry.

    PubMed

    Li, Wenfang; Dong, Zeyuan; Zhu, Junyan; Luo, Quan; Liu, Junqiu

    2014-12-01

    The spontaneous formation of organic helical structures, accompanied with an amplification of chirality, by dynamic covalent bonds between achiral and chiral building blocks is reported. PMID:25325888

  12. Dynamic chiral-at-metal stability of tetrakis(d/l-hfc)Ln(III) complexes capped with an alkali metal cation in solution.

    PubMed

    Lin, Yiji; Zou, Fang; Wan, Shigang; Ouyang, Jie; Lin, Lirong; Zhang, Hui

    2012-06-14

    Chiral tetrakis(β-diketonate) Ln(III) complexes Δ-[NaLa(d-hfc)(4)(CH(3)CN)] (1) and Λ-[NaLa(l-hfc)(4) (CH(3)CN)] (2) (d/l-hfc(-) = 3-heptafluo-robutylryl-(+)/(-)-camphorate) are a pair of enantiomers and crystallize in the same Sohncke space group (P2(1)2(1)2(1)) with dodecahedral (DD) geometry. Typically positive and negative exciton splitting patterns around 320 nm were observed in the solid-state circular dichroism (CD) spectra of complexes 1 and 2, which indicate that their shell configurational chiralities are Δ and Λ, respectively. The apparent bisignate couplets in the solid-state CD spectra of [CsLn(d-hfc)(4)(H(2)O)] [Ln = La (3), Yb (5)] and [CsLn(l-hfc)(4)(H(2)O)] [Ln = La (4), Yb (6)] show that they are a pair of enantiomers and their absolute configurations are denoted Δ and Λ, respectively. The crystallographic data of 5 reveals that its coordination polyhedron is the square antiprism (SAP) geometry and it undergoes a phase transition from triclinic (α phase, P1) to monoclinic (β phase, C2) upon cooling. The difference between the two phases is brought about by the temperature dependent behaviour of the coordination water molecules, but this did not affect the configurational chirality of the Δ-SAP-[Yb(d-hfc)(4)](-) moiety. Furthermore, time-dependent CD, UV-vis and (19)F NMR were applied to study the solution behavior of these complexes. It was found that the chiral-at-metal stability of the three pairs of complexes is different and affected by both the Ln(3+) and M(+) ion size. The results show that the Cs(+) cation can retain the metal center chirality and stablize the structures of [Ln(d/l-hfc)(4)](-) or the dissociated tris(d/l-hfc)Ln(III) species in solution for a longer time than that of the Na(+) cation, and it is important that the Cs(+) ion successfully lock the configurational chirality around the Yb(3+) center of the complex species in solution. This is reasoned by the short Cs(+)···FC, Cs(+)···O-Yb and Cs(+)···Yb(3

  13. Nuclear forces and chiral theories

    SciTech Connect

    Friar, J.L. |

    1995-09-01

    Recent successes in ab initio calculations of light nuclei (A=2-6) will be reviewed and correlated with the dynamical consequences of chiral symmetry. The tractability of nuclear physics evinced by these results is evidence for that symmetry. The relative importance of three-nucleon forces, four-nucleon forces, multi-pion exchanges, and relativistic corrections will be discussed in the context of effective field theories and dimensional power counting. Isospin violation in the nuclear force will also be discussed in this context.

  14. Chiral Perturbation Theory

    NASA Astrophysics Data System (ADS)

    Tiburzi, Brian C.

    The era of high-precision lattice QCD has led to synergy between lattice computations and phenomenological input from chiral perturbation theory. We provide an introduction to chiral perturbation theory with a bent towards understanding properties of the nucleon and other low-lying baryons. Four main topics are the basis for this chapter. We begin with a discussion of broken symmetries and the procedure to construct the chiral Lagrangian. The second topic concerns specialized applications of chiral perturbation theory tailored to lattice QCD, such as partial quenching, lattice discretization, and finite-volume effects. We describe inclusion of the nucleon in chiral perturbation theory using a heavy-fermion Euclidean action. Issues of convergence are taken up as our final topic. We consider expansions in powers of the strange-quark mass, and the appearance of unphysical singularities in the heavy-particle formulation. Our aim is to guide lattice practitioners in understanding the predictions chiral perturbation theory makes for baryons, and show how the lattice will play a role in testing the rigor of the chiral expansion at physical values of the quark masses.

  15. Applications of chiral symmetry

    SciTech Connect

    Pisarski, R.D.

    1995-03-01

    The author discusses several topics in the applications of chiral symmetry at nonzero temperature. First, where does the rho go? The answer: up. The restoration of chiral symmetry at a temperature T{sub {chi}} implies that the {rho} and a{sub 1} vector mesons are degenerate in mass. In a gauged linear sigma model the {rho} mass increases with temperature, m{sub {rho}}(T{sub {chi}}) > m{sub {rho}}(0). The author conjectures that at T{sub {chi}} the thermal {rho} - a{sub 1}, peak is relatively high, at about {approximately}1 GeV, with a width approximately that at zero temperature (up to standard kinematic factors). The {omega} meson also increases in mass, nearly degenerate with the {rho}, but its width grows dramatically with temperature, increasing to at least {approximately}100 MeV by T{sub {chi}}. The author also stresses how utterly remarkable the principle of vector meson dominance is, when viewed from the modern perspective of the renormalization group. Secondly, he discusses the possible appearance of disoriented chiral condensates from {open_quotes}quenched{close_quotes} heavy ion collisions. It appears difficult to obtain large domains of disoriented chiral condensates in the standard two flavor model. This leads to the last topic, which is the phase diagram for QCD with three flavors, and its proximity to the chiral critical point. QCD may be very near this chiral critical point, and one might thereby generated large domains of disoriented chiral condensates.

  16. Chirality control in oligothiophene through chiral wrapping.

    PubMed

    Sanji, Takanobu; Kato, Nobu; Tanaka, Masato

    2006-01-19

    [structure: see text] Mixing oligothiophenes and polysaccharides, such as amylose and schizophyllan, affords novel inclusion complexes, in which oligothiophene guests adopt twisted conformation in the chiral channel created by left- or right-handed helical wrapping with the polysaccharide host polymers, leading to optical activity. PMID:16408883

  17. Synthesis of Chiral Cyclopentenones.

    PubMed

    Simeonov, Svilen P; Nunes, João P M; Guerra, Krassimira; Kurteva, Vanya B; Afonso, Carlos A M

    2016-05-25

    The cyclopentenone unit is a very powerful synthon for the synthesis of a variety of bioactive target molecules. This is due to the broad diversity of chemical modifications available for the enone structural motif. In particular, chiral cyclopentenones are important precursors in the asymmetric synthesis of target chiral molecules. This Review provides an overview of reported methods for enantioselective and asymmetric syntheses of cyclopentenones, including chemical and enzymatic resolution, asymmetric synthesis via Pauson-Khand reaction, Nazarov cyclization and organocatalyzed reactions, asymmetric functionalization of the existing cyclopentenone unit, and functionalization of chiral building blocks. PMID:27101336

  18. The covariant chiral ring

    NASA Astrophysics Data System (ADS)

    Bourget, Antoine; Troost, Jan

    2016-03-01

    We construct a covariant generating function for the spectrum of chiral primaries of symmetric orbifold conformal field theories with N = (4 , 4) supersymmetry in two dimensions. For seed target spaces K3 and T 4, the generating functions capture the SO(21) and SO(5) representation theoretic content of the chiral ring respectively. Via string dualities, we relate the transformation properties of the chiral ring under these isometries of the moduli space to the Lorentz covariance of perturbative string partition functions in flat space.

  19. Magnetohydrodynamics of chiral relativistic fluids

    NASA Astrophysics Data System (ADS)

    Boyarsky, Alexey; Fröhlich, Jürg; Ruchayskiy, Oleg

    2015-08-01

    We study the dynamics of a plasma of charged relativistic fermions at very high temperature T ≫m , where m is the fermion mass, coupled to the electromagnetic field. In particular, we derive a magnetohydrodynamical description of the evolution of such a plasma. We show that, compared to conventional magnetohydronamics (MHD) for a plasma of nonrelativistic particles, the hydrodynamical description of the relativistic plasma involves new degrees of freedom described by a pseudoscalar field originating in a local asymmetry in the densities of left-handed and right-handed fermions. This field can be interpreted as an effective axion field. Taking into account the chiral anomaly we present dynamical equations for the evolution of this field, as well as of other fields appearing in the MHD description of the plasma. Due to its nonlinear coupling to helical magnetic fields, the axion field significantly affects the dynamics of a magnetized plasma and can give rise to a novel type of inverse cascade.

  20. New generation chiral metamaterials with small and flat chirality over a certain frequency band based on circular split ring resonators for microwave filter applications

    NASA Astrophysics Data System (ADS)

    Dincer, Furkan; Akgol, Oguzhan; Karaaslan, Muharrem; Unal, Emin; Demirel, Ekrem; Sabah, Cumali

    2016-02-01

    There are many studies in literature on chiral metamaterials (MTMs) to obtain large chiralities with dynamic optical activities. With this regard, this new generation planar chiral MTM study focuses on a small, non-dispersive (constant/flat) chirality admittance over an indicated frequency band which has not been investigated so far in literature. This new generation planar chiral MTM provides a small and a constant/fixed chirality which is mostly ignored by the scientists. This study numerically and experimentally investigates and examines these new generation MTMs based on circular split ring resonators (SRRs) with an increased capacitance in details. Obtained results show that the suggested structure can provide a small and constant/flat chirality admittance over a certain frequency band and hence it can be used to design myriad novel electromagnetic (EM) devices such as transmission and antireflection filters, polarization rotators for any desired frequency regions.

  1. Probing molecular chirality by coherent optical absorption spectra

    SciTech Connect

    Jia, W. Z.; Wei, L. F.

    2011-11-15

    We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical-absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately designed external fields is total-phase dependent. This will result in chirality-dependent absorption spectra for the probe field. As a consequence, the charality-dependent information in the spectra (such as the locations and relative heights of the characteristic absorption peaks) can be utilized to identify molecular chirality and determinate enantiomer excess (i.e., the percentages of different enantiomers). The feasibility of the proposal with chiral molecules confined in hollow-core photonic crystal fiber is also discussed.

  2. Spontaneous chiral symmetry breaking in collective active motion

    NASA Astrophysics Data System (ADS)

    Breier, Rebekka E.; Selinger, Robin L. B.; Ciccotti, Giovanni; Herminghaus, Stephan; Mazza, Marco G.

    2016-02-01

    Chiral symmetry breaking is ubiquitous in biological systems, from DNA to bacterial suspensions. A key unresolved problem is how chiral structures may spontaneously emerge from achiral interactions. We study a simple model of active swimmers in three dimensions that effectively incorporates hydrodynamic interactions. We perform large-scale molecular dynamics simulations (up to 106 particles) and find long-lived metastable collective states that exhibit chiral organization although the interactions are achiral. We elucidate under which conditions these chiral states will emerge and grow to large scales. To explore the complex phase space available to the system, we perform nonequilibrium quenches on a one-dimensional Lebwohl-Lasher model with periodic boundary conditions to study the likelihood of formation of chiral structures.

  3. Nonlinear chiral transport phenomena

    NASA Astrophysics Data System (ADS)

    Chen, Jiunn-Wei; Ishii, Takeaki; Pu, Shi; Yamamoto, Naoki

    2016-06-01

    We study the nonlinear responses of relativistic chiral matter to the external fields such as the electric field E , gradients of temperature and chemical potential, ∇T and ∇μ . Using the kinetic theory with Berry curvature corrections under the relaxation time approximation, we compute the transport coefficients of possible new electric currents that are forbidden in usual chirally symmetric matter but are allowed in chirally asymmetric matter by parity. In particular, we find a new type of electric current proportional to ∇μ ×E due to the interplay between the effects of the Berry curvature and collisions. We also derive an analog of the "Wiedemann-Franz" law specific for anomalous nonlinear transport in relativistic chiral matter.

  4. Spintronics: Chiral damping

    PubMed Central

    Kim, Kyoung-Whan; Lee, Hyun-Woo

    2016-01-01

    The analysis of the magnetic domain wall motion in a nanostructured magnetic system with strong spin-orbit coupling shows that the energy dissipation can be chiral when the inversion symmetry is broken. PMID:26906956

  5. Chiral plasma instabilities.

    PubMed

    Akamatsu, Yukinao; Yamamoto, Naoki

    2013-08-01

    We study the collective modes in relativistic electromagnetic or quark-gluon plasmas with an asymmetry between left- and right-handed chiral fermions, based on the recently formulated kinetic theory with Berry curvature corrections. We find that there exists an unstable mode, signaling the presence of a plasma instability. We argue the fate of this "chiral plasma instability" including the effect of collisions, and briefly discuss its relevance in heavy ion collisions and compact stars. PMID:23952387

  6. Chiral Vibrational Structures of Proteins at Interfaces Probed by Sum Frequency Generation Spectroscopy

    PubMed Central

    Fu, Li; Wang, Zhuguang; Yan, Elsa C.Y.

    2011-01-01

    We review the recent development of chiral sum frequency generation (SFG) spectroscopy and its applications to study chiral vibrational structures at interfaces. This review summarizes observations of chiral SFG signals from various molecular systems and describes the molecular origins of chiral SFG response. It focuses on the chiral vibrational structures of proteins and presents the chiral SFG spectra of proteins at interfaces in the C-H stretch, amide I, and N-H stretch regions. In particular, a combination of chiral amide I and N-H stretches of the peptide backbone provides highly characteristic vibrational signatures, unique to various secondary structures, which demonstrate the capacity of chiral SFG spectroscopy to distinguish protein secondary structures at interfaces. On the basis of these recent developments, we further discuss the advantages of chiral SFG spectroscopy and its potential application in various fields of science and technology. We conclude that chiral SFG spectroscopy can be a new approach to probe chiral vibrational structures of protein at interfaces, providing structural and dynamic information to study in situ and in real time protein structures and dynamics at interfaces. PMID:22272140

  7. Chirality dependent elastic properties of single-walled boron nitride nanotubes under uniaxial and torsional loading

    SciTech Connect

    Anoop Krishnan, N. M. Ghosh, Debraj

    2014-02-14

    The elastic behavior of single-walled boron nitride nanotubes is studied under axial and torsional loading. Molecular dynamics simulation is carried out with a tersoff potential for modeling the interatomic interactions. Different chiral configurations with similar diameter are considered to study the effect of chirality on the elastic and shear moduli. Furthermore, the effects of tube length on elastic modulus are also studied by considering different aspects ratios. It is observed that both elastic and shear moduli depend upon the chirality of a nanotube. For aspect ratios less than 15, the elastic modulus reduces monotonically with an increase in the chiral angle. For chiral nanotubes, the torsional response shows a dependence on the direction of loading. The difference between the shear moduli against and along the chiral twist directions is maximum for chiral angle of 15°, and zero for zigzag (0°) and armchair (30°) configurations.

  8. Chiral quirkonium decays

    NASA Astrophysics Data System (ADS)

    Fok, R.; Kribs, Graham D.

    2011-08-01

    We calculate the two-body decay rates of quirkonium states formed from quirks that acquire mass solely through electroweak symmetry breaking. We consider SU(N)ic infracolor with two flavors of quirks transforming under the electroweak group (but not QCD) of the standard model. In one case, the quirks are in a chiral representation of the electroweak group, while in the other case, a vectorlike representation. The differences in the dominant decay channels between “chiral quirkonia” versus “vectorlike quirkonia” are striking. Several chiral quirkonia states can decay into the unique two-body resonance channels WH, ZH, tt¯, tb¯/bt¯, and γH, which never dominate for vectorlike quirkonia. Additionally, the channels WW, WZ, ZZ, and Wγ, are shared among both chiral and vectorlike quirkonia. Resonances of dileptons or light quarks (dijets) can dominate for some vectorlike quirkonia states throughout their mass range, while these modes never dominate for chiral quirkonia unless the decays into pairs of gauge or Higgs bosons are kinematically forbidden.

  9. Chiral Quirkonium Decays

    SciTech Connect

    Fok, R.; Kribs, Graham D.; /Fermilab

    2011-06-01

    We calculate the two-body decay rates of quirkonium states formed from quirks that acquire mass solely through electroweak symmetry breaking. We consider SU(N){sub ic} infracolor with two flavors of quirks transforming under the electroweak group (but not QCD) of the standard model. In one case, the quirks are in a chiral representation of the electroweak group, while in the other case, a vectorlike representation. The differences in the dominant decay channels between 'chiral quirkonia' versus 'vectorlike quirkonia' are striking. Several chiral quirkonia states can decay into the unique two-body resonance channels WH, ZH, t{bar t}, t{bar b}/b{bar t}, and {gamma}H, which never dominate for vectorlike quirkonia. Additionally, the channels WW, WZ, ZZ, and W{gamma}, are shared among both chiral and vectorlike quirkonia. Resonances of dileptons or light quarks (dijets) can dominate for some vectorlike quirkonia states throughout their mass range, while these modes never dominate for chiral quirkonia unless the decays into pairs of gauge or Higgs bosons are kinematically forbidden.

  10. New Aspects of Experimental Study of the Pion-Nucleon Interaction in the Resonance Region

    SciTech Connect

    Sumachev, V.V.

    2005-06-01

    New experimental data that were obtained by the PNPI-ITEP Collaboration have resolved some discrete ambiguities in the partial-wave analysis (PWA). These results were used in the new FA02 PWA performed at George Washington University. At the same time, the FA02 PWA has revealed considerable fewer N* and {delta} resonances than those listed in the RPP tables. This circumstance aggravated the known problem of so-called missing resonances. The program for further measurements of the spin rotation parameters in elastic {pi}N scattering that are required to eliminate the remaining discrete PWA ambiguities is discussed.

  11. Spontaneous chirality in simple systems

    PubMed

    Pickett; Gross; Okuyama

    2000-10-23

    Two simple examples of spontaneous chiral symmetry breaking are presented. The first is close-packed cylindrically confined spheres. As the cylinder diameter is varied, one obtains a variety of chiral phases. The second example involves unconfined dipolar particles with an isotropic attraction, which also exhibits chiral ground states. We speculate that a dilute magnetorheological fluid film, with the addition of smaller particles to provide an attractive entropic interaction, will exhibit a chiral columnar ground state. PMID:11030973

  12. Baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Scherer, S.

    2012-03-01

    We provide a short introduction to the one-nucleon sector of chiral perturbation theory and address the issue of power counting and renormalization. We discuss the infrared regularization and the extended on-mass-shell scheme. Both allow for the inclusion of further degrees of freedom beyond pions and nucleons and the application to higher-loop calculations. As applications we consider the chiral expansion of the nucleon mass to order Script O(q6) and the inclusion of vector and axial-vector mesons in the calculation of nucleon form factors. Finally, we address the complex-mass scheme for describing unstable particles in effective field theory.

  13. Hierarchical amplification of macromolecular helicity of dynamic helical poly(phenylacetylene)s composed of chiral and achiral phenylacetylenes in dilute solution, liquid crystal, and two-dimensional crystal.

    PubMed

    Ohsawa, Sousuke; Sakurai, Shin-ichiro; Nagai, Kanji; Banno, Motonori; Maeda, Katsuhiro; Kumaki, Jiro; Yashima, Eiji

    2011-01-12

    Optically active poly(phenylacetylene) copolymers consisting of optically active and achiral phenylacetylenes bearing L-alanine decyl esters (1L) and 2-aminoisobutylic acid decyl esters (Aib) as the pendant groups (poly(1L(m)-co-Aib(n))) with various compositions were synthesized by the copolymerization of the optically active 1L with achiral Aib using a rhodium catalyst, and their chiral amplification of the macromolecular helicity in a dilute solution, a lyotropic liquid crystalline (LC) state, and a two-dimensional (2D) crystal on the substrate was investigated by measuring the circular dichroism of the copolymers, mesoscopic cholesteric twist in the LC state (cholesteric helical pitch), and high-resolution atomic force microscopy (AFM) images of the self-assembled 2D helix-bundles of the copolymer chains. We found that the macromolecular helicity of poly(1L(m)-co-Aib(n))s could be hierarchically amplified in the order of the dilute solution, LC state, and 2D crystal. In sharp contrast, almost no chiral amplification of the macromolecular helicity was observed for the homopolymer mixtures of 1L and Aib in the LC state and 2D crystal on graphite. PMID:21141965

  14. Chiral Sensitivity in the Dissociative Electron Attachment of Halocamphor Molecules

    NASA Astrophysics Data System (ADS)

    Dreiling, Joan

    2016-05-01

    We have demonstrated chirally-dependent molecular destruction when incident longitudinally-spin-polarized (chiral) electrons break bonds in chiral molecules. This chiral sensitivity was observed through an asymmetry in the dissociative electron attachment (DEA) reaction rate with chiral 3-bromocamphor (C10 H15 BrO). Such an observation provides an unambiguous demonstration of the idea underlying the Vester-Ulbricht hypothesis, which attempts to explain the origins of the homochirality that is observed in many biological systems. While the lack of inversion symmetry in these reactions allows the effects we observe to occur, their dynamic causes are poorly understood. We have further studied the asymmetries in the DEA rates for two additional halocamphor molecules, 3-iodocamphor (C10 H15 IO) and 10-iodocamphor, in a systematic effort to illuminate the mechanisms responsible for the chiral sensitivity. The DEA signal depends on the sign of the incident electron helicity for a given target handedness in all molecules, and it varies with both the atomic number and the location of the heaviest atom in the molecule. Surprisingly, the DEA asymmetries for 10-iodocamphor, in which the heaviest atom is farther from a chiral center than for the other molecules, produced the largest asymmetries. This work was performed at the University of Nebraska-Lincoln. This project was funded by NSF Grant PHY-1206067.

  15. Chiral damping of magnetic domain walls.

    PubMed

    Jué, Emilie; Safeer, C K; Drouard, Marc; Lopez, Alexandre; Balint, Paul; Buda-Prejbeanu, Liliana; Boulle, Olivier; Auffret, Stephane; Schuhl, Alain; Manchon, Aurelien; Miron, Ioan Mihai; Gaudin, Gilles

    2016-03-01

    Structural symmetry breaking in magnetic materials is responsible for the existence of multiferroics, current-induced spin-orbit torques and some topological magnetic structures. In this Letter we report that the structural inversion asymmetry (SIA) gives rise to a chiral damping mechanism, which is evidenced by measuring the field-driven domain-wall (DW) motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. The DW dynamics associated with the chiral damping and those with Dzyaloshinskii-Moriya interaction (DMI) exhibit identical spatial symmetry. However, both scenarios are differentiated by their time reversal properties: whereas DMI is a conservative effect that can be modelled by an effective field, the chiral damping is purely dissipative and has no influence on the equilibrium magnetic texture. When the DW motion is modulated by an in-plane magnetic field, it reveals the structure of the internal fields experienced by the DWs, allowing one to distinguish the physical mechanism. The chiral damping enriches the spectrum of physical phenomena engendered by the SIA, and is essential for conceiving DW and skyrmion devices owing to its coexistence with DMI (ref. ). PMID:26689141

  16. Chiral damping of magnetic domain walls

    NASA Astrophysics Data System (ADS)

    Jué, Emilie; Safeer, C. K.; Drouard, Marc; Lopez, Alexandre; Balint, Paul; Buda-Prejbeanu, Liliana; Boulle, Olivier; Auffret, Stephane; Schuhl, Alain; Manchon, Aurelien; Miron, Ioan Mihai; Gaudin, Gilles

    2016-03-01

    Structural symmetry breaking in magnetic materials is responsible for the existence of multiferroics, current-induced spin-orbit torques and some topological magnetic structures. In this Letter we report that the structural inversion asymmetry (SIA) gives rise to a chiral damping mechanism, which is evidenced by measuring the field-driven domain-wall (DW) motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. The DW dynamics associated with the chiral damping and those with Dzyaloshinskii-Moriya interaction (DMI) exhibit identical spatial symmetry. However, both scenarios are differentiated by their time reversal properties: whereas DMI is a conservative effect that can be modelled by an effective field, the chiral damping is purely dissipative and has no influence on the equilibrium magnetic texture. When the DW motion is modulated by an in-plane magnetic field, it reveals the structure of the internal fields experienced by the DWs, allowing one to distinguish the physical mechanism. The chiral damping enriches the spectrum of physical phenomena engendered by the SIA, and is essential for conceiving DW and skyrmion devices owing to its coexistence with DMI (ref. ).

  17. Guiding chiral self-propellers in a periodic potential.

    PubMed

    Nourhani, Amir; Crespi, Vincent H; Lammert, Paul E

    2015-09-11

    Ingenious suggestions continue to be made for separation of racemic mixtures according to the inert structural chirality of the constituents. Recently discovered self-motile micro- or nanoparticles express dynamical chirality, i.e., that which originates in motion, not structure. Here, we predict how dynamically chiral objects, with overdamped dynamics in a soft periodic two-dimensional potential, can display not only separation into well-defined dynamical subclasses defined by motility characteristics, but also the ability to be steered to arbitrary locations in the plane by simply changing the amplitude of the external potential. Orientational and translational diffusion produce new types of drift absent in the noise-free case. As practical implementation seems feasible with acoustic or optical fields, these phenomena can be useful for laboratory microscales manipulations, possibly including reconfigurable microfluidic circuits with complex networks of unidirectional channels. PMID:26406856

  18. Contesting the paradigm of chirality

    NASA Astrophysics Data System (ADS)

    Efrati, Efi

    2012-02-01

    In 1893 Lord Kelvin coined the term chirality, and stated what is to become the elementary paradigm of chirality: 'I call any geometrical figure, or any group of points, chiral, and say it has chirality, if its image in a plane mirror , ideally realized cannot be brought to coincide with itself'. While the notion of chirality has greatly advanced our understanding of the structures of molecules and crystals, it has been shown to be inconsistent with every pseudo-scalar quantification. In this talk I will present a tabletop demonstration of a chiral structure which is constructed through the achiral summation of identical elementary units which are symmetric under reflection. The seeming contradiction to the definition of chirality is reconciled by proposing an alternative definition, relying on the physicist interpretation of the right hand rule.

  19. Quark matter in a parallel electric and magnetic field background: Chiral phase transition and equilibration of chiral density

    NASA Astrophysics Data System (ADS)

    Ruggieri, M.; Peng, G. X.

    2016-05-01

    In this article, we study spontaneous chiral symmetry breaking for quark matter in the background of static and homogeneous parallel electric field E and magnetic field B . We use a Nambu-Jona-Lasinio model with a local kernel interaction to compute the relevant quantities to describe chiral symmetry breaking at a finite temperature for a wide range of E and B . We study the effect of this background on the inverse catalysis of chiral symmetry breaking for E and B of the same order of magnitude. We then focus on the effect of the equilibration of chiral density n5 , produced dynamically by an axial anomaly on the critical temperature. The equilibration of n5 , a consequence of chirality-flipping processes in the thermal bath, allows for the introduction of the chiral chemical potential μ5, which is computed self-consistently as a function of the temperature and field strength by coupling the number equation to the gap equation and solving the two within an expansion in E /T2 , B /T2 , and μ52/T2 . We find that even if chirality is produced and equilibrates within a relaxation time τM , it does not change drastically the thermodynamics, with particular reference to the inverse catalysis induced by the external fields, as long as the average μ5 at equilibrium is not too large.

  20. Large-N{sub C} properties of the {rho} and f{sub 0}(600) mesons from unitary resonance chiral dynamics

    SciTech Connect

    Nieves, J.; Pich, A.; Ruiz Arriola, E.

    2011-11-01

    We construct {pi}{pi} amplitudes that fulfill exact elastic unitarity, account for one-loop chiral perturbation theory contributions and include all 1/N{sub C} leading terms, with the only limitation of considering just the lowest-lying nonet of exchanged resonances. Within such a scheme, the N{sub C} dependence of {sigma} and {rho} masses and widths is discussed. Robust conclusions are drawn in the case of the {rho} resonance, confirming that it is a stable meson in the limit of a large number of QCD colors, N{sub C}. Less definitive conclusions are reached in the scalar-isoscalar sector. With the present quality of data, we cannot firmly conclude whether or not the N{sub C}=3 f{sub 0}(600) resonance completely disappears at large N{sub C} or if it has a subdominant component in its structure, which would become dominant for a number of quark colors sufficiently large.

  1. Multi-Q hexagonal spin density waves and dynamically generated spin-orbit coupling: Time-reversal invariant analog of the chiral spin density wave

    NASA Astrophysics Data System (ADS)

    Venderbos, J. W. F.

    2016-03-01

    We study hexagonal spin-channel ("triplet") density waves with commensurate M -point propagation vectors. We first show that the three Q =M components of the singlet charge density and charge-current density waves can be mapped to multicomponent Q =0 nonzero angular momentum order in three dimensions (3D) with cubic crystal symmetry. This one-to-one correspondence is exploited to define a symmetry classification for triplet M -point density waves using the standard classification of spin-orbit coupled electronic liquid crystal phases of a cubic crystal. Through this classification we naturally identify a set of noncoplanar spin density and spin-current density waves: the chiral spin density wave and its time-reversal invariant analog. These can be thought of as 3 DL =2 and 4 spin-orbit coupled isotropic β -phase orders. In contrast, uniaxial spin density waves are shown to correspond to α phases. The noncoplanar triple-M spin-current density wave realizes a novel 2 D semimetal state with three flavors of four-component spin-momentum locked Dirac cones, protected by a crystal symmetry akin to nonsymmorphic symmetry, and sits at the boundary between a trivial and topological insulator. In addition, we point out that a special class of classical spin states, defined as classical spin states respecting all lattice symmetries up to global spin rotation, are naturally obtained from the symmetry classification of electronic triplet density waves. These symmetric classical spin states are the classical long-range ordered limits of chiral spin liquids.

  2. Cavity-induced chiral states of fermionic quantum gases

    NASA Astrophysics Data System (ADS)

    Sheikhan, Ameneh; Brennecke, Ferdinand; Kollath, Corinna

    2016-04-01

    We investigate ultracold fermions placed into an optical cavity and subjected to optical lattices which confine the atoms to ladder structures. A transverse running-wave laser beam induces together with the dynamical cavity field a two-photon Raman-assisted tunneling process with spatially dependent phase imprint along the rungs of the ladders. We identify the steady states which can occur by the feedback mechanism between the cavity field and the atoms. We find the spontaneous emergence of a finite cavity field amplitude which leads to an artificial magnetic field felt by the fermionic atoms. These form a chiral insulating or chiral liquid state carrying a chiral current. We explore the rich state diagram as a function of the power of the transverse laser beam, the atomic filling, and the phase imprint during the cavity-induced tunneling. Both a sudden onset or a slow exponential activation with the transverse laser power of the self-organized chiral states can occur.

  3. Chiral phosphorus nanotubes: structure, bonding, and electronic properties.

    PubMed

    Fernández-Escamilla, H N; Quijano-Briones, J J; Tlahuice-Flores, A

    2016-05-14

    The study of black phosphorus nanotubes (PNTs) had been devoted to zigzag and armchair structures, with no consideration of chiral structures to date. In this communication, we studied the structural and electronic (band structure) properties of chiral nanotubes using a periodic plane wave-pseudopotential approach. We found that some chiral nanotubes display similar bandgaps and binding energies per atom (BEA) as armchair PNTs and Born-Oppenheimer molecular dynamics (BOMD) calculations attest their thermal stability. Interestingly, we determined that the bandgap is tuned by varying the PNTs chirality and it is not related to their diameters. This feature can be exploited in optical and electronic applications wherein a direct and sizable bandgap is required. PMID:27094567

  4. Chiral electron-chiral target scattering

    SciTech Connect

    Trantham, K.W.; Gay, T.J. Johnston, M.E.

    1996-05-01

    It is possible to have an electronic counterpart to the well known effect of optical circular dichroism: electron circular dichroism (ECD) is the preferential scattering of longitudinally polarized electrons by a chiral target. Resulting essentially from a difference in total scattering cross section for different incident electron helicities, this {open_quotes}parity-violating{close_quotes} effect is allowed by symmetry because the scattering target is handed. The authors have searched for ECD in camphor by measuring the transmitted intensity of electrons with positive (negative) helicity I{sub +({minus})} through a gas cell containing stereoisomers of camphor vapor and constructing the asymmetry A = (I{sub +} {minus} I{sub {minus}}). Within their sensitivity (2x10{sup {minus}4}) the authors were not able to detect ECD at the energies investigated (10 eV). Prospects for future investigations, particularly in light of the recent positive results measured in Muenster, will be discussed.

  5. Electron-deuteron scattering based on the Chiral Effective Field Theory

    NASA Astrophysics Data System (ADS)

    Rozpȩdzik, Dagmara

    2014-06-01

    Based on the Chiral Effective Field Theory (ChEFT) dynamical picture of the two-pion exchange (TPE) contributions to the nuclear current operator which appear at higher order chiral expansions were considered. Their role in the electron-deuteron scattering reactions was studied and chiral predictions were compared with those obtained in the conventional framework. Results for cross section and various polarization observables are presented. The bound and scattering states were calculated with five different chiral nucleon-nucleon (NN) potentials which leads to the so-called theoretical uncertainty bands for the predicted results.

  6. Distinguishability and chiral stability in solution: Effects of decoherence and intermolecular interactions

    SciTech Connect

    Han, Heekyung; Wardlaw, David M.; Frolov, Alexei M.

    2014-05-28

    We examine the effect of decoherence and intermolecular interactions (chiral discrimination energies) on the chiral stability and the distinguishability of initially pure versus mixed states in an open chiral system. Under a two-level approximation for a system, intermolecular interactions are introduced by a mean-field theory, and interaction between a system and an environment is modeled by a continuous measurement of a population difference between the two chiral states. The resultant equations are explored for various parameters, with emphasis on the combined effects of the initial condition of the system, the chiral discrimination energies, and the decoherence in determining: the distinguishability as measured by a population difference between the initially pure and mixed states, and the decoherence process; the chiral stability as measured by the purity decay; and the stationary state of the system at times long relative to the time scales of the system dynamics and of the environmental effects.

  7. Finite nuclei in relativistic models with a light chiral scalar meson

    SciTech Connect

    Serot, B.D.; Furnstahl, R.J.

    1993-10-01

    Relativistic chiral models with a light scalar, meson appear to provide an economical marriage of successful relativistic mean-field theories and chiral symmetry. In these models, the scalar meson serves as both the chiral partner of the pion and the mediator of the intermediate-range nucleon-nucleon (NN) attraction. However, while some of these models can reproduce the empirical nuclear matter saturation point, they fail to reproduce observed properties of finite nuclei, such as spin-orbit splittings, shell structure, charge densities, and surface energetics. There deficiencies imply that this realization of chiral symmetry is incorrect. An alternative scenario for chiral hadronic models, which features a heavy chiral scalar and dynamical generation of the NN attraction, is discussed.

  8. Chiral symmetry and pentaquarks

    SciTech Connect

    Dmitri Diakonov

    2004-07-01

    Spontaneous chiral symmetry breaking, mesons and baryons are illustrated in the language of the Dirac theory. Various forces acting between quarks inside baryons are discussed. I explain why the naive quark models typically overestimate pentaquark masses by some 500 MeV and why in the fully relativistic approach to baryons pentaquarks turn out to be light. I discuss briefly why it can be easier to produce pentaquarks at low than at high energies.

  9. Chiral Biomarkers in Meteorites

    NASA Technical Reports Server (NTRS)

    Hoover, Richard B.

    2010-01-01

    The chirality of organic molecules with the asymmetric location of group radicals was discovered in 1848 by Louis Pasteur during his investigations of the rotation of the plane of polarization of light by crystals of sodium ammonium paratartrate. It is well established that the amino acids in proteins are exclusively Levorotary (L-aminos) and the sugars in DNA and RNA are Dextrorotary (D-sugars). This phenomenon of homochirality of biological polymers is a fundamental property of all life known on Earth. Furthermore, abiotic production mechanisms typically yield recemic mixtures (i.e. equal amounts of the two enantiomers). When amino acids were first detected in carbonaceous meteorites, it was concluded that they were racemates. This conclusion was taken as evidence that they were extraterrestrial and produced by abiologically. Subsequent studies by numerous researchers have revealed that many of the amino acids in carbonaceous meteorites exhibit a significant L-excess. The observed chirality is much greater than that produced by any currently known abiotic processes (e.g. Linearly polarized light from neutron stars; Circularly polarized ultraviolet light from faint stars; optically active quartz powders; inclusion polymerization in clay minerals; Vester-Ulbricht hypothesis of parity violations, etc.). This paper compares the measured chirality detected in the amino acids of carbonaceous meteorites with the effect of these diverse abiotic processes. IT is concluded that the levels observed are inconsistent with post-arrival biological contamination or with any of the currently known abiotic production mechanisms. However, they are consistent with ancient biological processes on the meteorite parent body. This paper will consider these chiral biomarkers in view of the detection of possible microfossils found in the Orgueil and Murchison carbonaceous meteorites. Energy dispersive x-ray spectroscopy (EDS) data obtained on these morphological biomarkers will be

  10. A Chiral Granular Gas

    NASA Astrophysics Data System (ADS)

    Tsai, J.-C.; Ye, Fangfu; Rodriguez, Juan; Gollub, J. P.; Lubensky, T. C.

    2005-05-01

    Inspired by rattleback toys, we created small chiral wires that rotate in a preferred direction on a vertically oscillating platform and quantified their motion with experiment and simulation. We demonstrate experimentally that angular momentum of rotation about particle centers of mass is converted to collective angular momentum of center-of-mass motion in a granular gas of these wires, and we introduce a continuum model that explains our observations.